National Library of Energy BETA

Sample records for determination differential absorption

  1. Apparatus and method for quantitative measurement of small differences in optical absorptivity between two samples using differential interferometry and the thermooptic effect

    DOE Patents [OSTI]

    Cremers, D.A.; Keller, R.A.

    1984-05-08

    An apparatus and method for the measurement of small differences in optical absorptivity of weakly absorbing solutions using differential interferometry and the thermooptic effect have been developed. Two sample cells are placed in each arm of an interferometer and are traversed by colinear probe and heating laser beams. The interrogation probe beams are recombined forming a fringe pattern, the intensity of which can be related to changes in optical path length of these laser beams through the cells. This in turn can be related to small differences in optical absorptivity which results in different amounts of sample heating when the heating laser beams are turned on, by the fact that the index of refraction of a liquid is temperature dependent. A critical feature of this invention is the stabilization of the optical path of the probe beams against drift. Background (solvent) absorption can then be suppressed by a factor of approximately 400. Solute absorptivities of about 10[sup [minus]5] cm[sup [minus]1] can then be determined in the presence of background absorptions in excess of 10[sup [minus]3] cm[sup [minus]1]. In addition, the smallest absorption measured with the instant apparatus and method is about 5 [times] 10[sup [minus]6] cm[sup [minus]1]. 6 figs.

  2. Apparatus and method for quantitative measurement of small differences in optical absorptivity between two samples using differential interferometry and the thermooptic effect

    DOE Patents [OSTI]

    Cremers, David A. (Los Alamos, NM); Keller, Richard A. (Los Alamos, NM)

    1984-01-01

    An apparatus and method for the measurement of small differences in optical absorptivity of weakly absorbing solutions using differential interferometry and the thermooptic effect has been developed. Two sample cells are placed in each arm of an interferometer and are traversed by colinear probe and heating laser beams. The interrogation probe beams are recombined forming a fringe pattern, the intensity of which can be related to changes in optical pathlength of these laser beams through the cells. This in turn can be related to small differences in optical absorptivity which results in different amounts of sample heating when the heating laser beams are turned on, by the fact that the index of refraction of a liquid is temperature dependent. A critical feature of this invention is the stabilization of the optical path of the probe beams against drift. Background (solvent) absorption can then be suppressed by a factor of approximately 400. Solute absorptivities of about 10.sup.-5 cm.sup.-1 can then be determined in the presence of background absorptions in excess of 10.sup.-3 cm.sup.-1. In addition, the smallest absorption measured with the instant apparatus and method is about 5.times. 10.sup.-6 cm.sup.-1.

  3. Apparatus and method for quantitative measurement of small differences in optical absorptivity between two samples using differential interferometry and the thermooptic effect

    DOE Patents [OSTI]

    Cremers, D.A.; Keller, R.A.

    1982-06-08

    An apparatus and method for the measurement of small differences in optical absorptivity of weakly absorbing solutions using differential interferometry and the thermooptic effect has been developed. Two sample cells are placed in each arm of an interferometer and are traversed by colinear probe and heating laser beams. The interrogation probe beams are recombined forming a fringe pattern, the intensity of which can be related to changes in optical pathlength of these laser beams through the cells. This in turn can be related to small differences in optical absorptivity which results in different amounts of sample heating when the heating laser beams are turned on, by the fact that the index of refraction of a liquid is temperature dependent. A critical feature of this invention is the stabilization of the optical path of the probe beams against drift. Background (solvent) absorption can then be suppressed by a factor of approximately 400. Solute absorptivities of about 10/sup -5/ cm/sup -1/ can then be determined in the presence of background absorptions in excess of 10/sup -3/ cm/sup -1/. In addition, the smallest absorption measured with the instant apparatus and method is about 5 x 10/sup -6/ cm/sup -1/.

  4. Halo mass dependence of H I and O VI absorption: evidence for differential kinematics

    SciTech Connect (OSTI)

    Mathes, Nigel L.; Churchill, Christopher W.; Nielsen, Nikole M.; Trujillo-Gomez, Sebastian [New Mexico State University, Las Cruces, NM 88003 (United States); Kacprzak, Glenn G. [Swinburne University of Technology, Victoria 3122 (Australia); Charlton, Jane; Muzahid, Sowgat [The Pennsylvania State University, University Park, PA 16802 (United States)

    2014-09-10

    We studied a sample of 14 galaxies (0.1 < z < 0.7) using HST/WFPC2 imaging and high-resolution HST/COS or HST/STIS quasar spectroscopy of Ly?, Ly?, and O VI ??1031, 1037 absorption. The galaxies, having 10.8 ? log (M {sub h}/M {sub ?}) ? 12.2, lie within D = 300 kpc of quasar sightlines, probing out to D/R {sub vir} = 3. When the full range of M {sub h} and D/R {sub vir} of the sample are examined, ?40% of the H I absorbing clouds can be inferred to be escaping their host halo. The fraction of bound clouds decreases as D/R {sub vir} increases such that the escaping fraction is ?15% for D/R {sub vir} < 1, ?45% for 1 ? D/R {sub vir} < 2, and ?90% for 2 ? D/R {sub vir} < 3. Adopting the median mass log M {sub h}/M {sub ?} = 11.5 to divide the sample into 'higher' and 'lower' mass galaxies, we find a mass dependency for the hot circumgalactic medium kinematics. To our survey limits, O VI absorption is found in only ?40% of the H I clouds in and around lower mass halos as compared to ?85% around higher mass halos. For D/R {sub vir} < 1, lower mass halos have an escape fraction of ?65%, whereas higher mass halos have an escape fraction of ?5%. For 1 ? D/R {sub vir} < 2, the escape fractions are ?55% and ?35% for lower mass and higher mass halos, respectively. For 2 ? D/R {sub vir} < 3, the escape fraction for lower mass halos is ?90%. We show that it is highly likely that the absorbing clouds reside within 4R {sub vir} of their host galaxies and that the kinematics are dominated by outflows. Our finding of 'differential kinematics' is consistent with the scenario of 'differential wind recycling' proposed by Oppenheimer et al. We discuss the implications for galaxy evolution, the stellar to halo mass function, and the mass-metallicity relationship of galaxies.

  5. Light absorption from particulate impurities in snow and ice determined by spectrophotometric analysis of filters

    SciTech Connect (OSTI)

    Grenfell, Thomas C.; Doherty, Sarah J.; Clarke, Antony D.; Warren, Stephen G.

    2011-05-10

    Light absorption by particulate impurities in snow and ice can affect the surface albedo and is important for the climate. The absorption properties of these particles can be determined by collecting and melting snow samples and extracting the particulate material by filtration of the meltwater. This paper describes the optical design and testing of a new instrument to measure the absorption spectrum from 400 to 750 nm wavelength of the particles collected on filters using an ''integrating-sandwich'' configuration. The measured absorption is shown to be unaffected by scattering of light from the deposited particulates. A set of calibration standards is used to derive an upper limit for the concentration of black carbon (BC) in the snow. The wavelength dependence of the absorption spectra from 450 to 600 nm is used to calculate an absorption Angstrom exponent for the aerosol. This exponent is used to estimate the actual BC concentration in the snow samples as well as the relative contributions of BC and non-BC constituents to the absorption of solar radiation integrated over the wavelength band 300 to 750 nm.

  6. Determination of cadmium, chromium, nickel, and lead in urine using Graphite Furnace Atomic Absorption spectrophotometry

    SciTech Connect (OSTI)

    Hamilton, L.G.; Farrar, R.B.

    1980-12-01

    Procedures using graphite furnace atomic absorption spectrophotometry for the determination of cadmium, chromium, nickel, and lead are described in this report. The lowest concentrations reported using the procedure are 5 ..mu..g/l for cadmium, chromium, and nickel and 10 ..mu..g/l for lead.

  7. Absorption of solar radiation by the atmosphere as determined using satellite, aircraft, and surface data during the

    E-Print Network [OSTI]

    Dong, Xiquan

    Absorption of solar radiation by the atmosphere as determined using satellite, aircraft of 0.33 0.04 for the total atmosphere (surface to top). The absorptance of solar radiation estimated more solar radiation than is predicted by theory [e.g., Stephens and Tsay 1990]. Recently, and nearly

  8. The determination of the bioavailability and the site of absorption in lambs fed different sources of magnesium 

    E-Print Network [OSTI]

    Hurley, Leigh Anne

    1988-01-01

    of the animal influences Ng avail- ability. Grace (1972) found that older cows exhibited a sharper decrease in plasma Ng than did younger cows in the early stages of lactation. Magnesium Supplementation The adequacy of dietary Mg levels is probably...THE DETERMINATION OF THE BIOAVAILABILITY AND THE SITE OF ABSORPTION IN LAMBS FED DIFFERENT SOURCES OF MAGNESIUM A Thesis I, EIGH ANNE HURLEY Submitted to the Of f ice of Graduate Studies Texas AAM UniversitY in partial fulfillment...

  9. The determination of the moisture absorption characteristics of lightweight concrete aggregates 

    E-Print Network [OSTI]

    Bryant, Julian Stephen

    1959-01-01

    " ], 2 120 " 1. 3 1 dey 2, 9 3, 6 3 II 4. 2 3 II 4. 1 3 tl 4. 0 APPENDIX B STANDARD METHOD OF TEST FOR SPECIFIC GRAVITY AND ABSORPTION OF COARSE AGGREGATE ASTM Designation: C 127 - 42 ~Sco e l. (a) This method of test is intended for use... gravity as defined in the Standard Defini- tions of Terms Relating to Specific Gravity (ASTM Designation: E 12) of the American Society for Testing Materials, shall be calculated from the following formula: A Apparent sp. gr. . ~ . A - C 46. A~bt1...

  10. Standard test method for graphite furnace atomic absorption spectrometric determination of lead and cadmium extracted from ceramic foodware

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2000-01-01

    1.1 This test method covers procedures for using graphite furnace atomic absorption spectroscopy (GFAAS) to quantitatively determine lead and cadmium extracted by acetic acid at room temperature from the food-contact surface of foodware. The method is applicable to food-contact surfaces composed of silicate-based materials (earthenware, glazed ceramicware, decorated ceramicware, decorated glass, and lead crystal glass) and is capable of determining lead concentrations greater than 0.005 to 0.020 g/mL and cadmium concentrations greater than 0.0005 to 0.002 g/mL, depending on instrument design. 1.2 This test method also describes quality control procedures to check for contamination and matrix interference during GFAAS analyses and a specific sequence of analytical measurements that demonstrates proper instrument operation during the time period in which sample solutions are analyzed. 1.3 Cleaning and other contamination control procedures are described in this test method. Users may modify contamination cont...

  11. Determining Orientational Structure of Diamondoid Thiols Attached to Silver Using Near Edge X-ray Absorption Fine Structure Spectroscopy

    SciTech Connect (OSTI)

    Willey, T M; Lee, J I; Fabbri, J D; Wang, D; Nielsen, M; Randel, J C; Schreiner, P R; Fokin, A A; Tkachenko, B A; Fokina, N A; Dahl, J P; Carlson, R K; Terminello, L J; Melosh, N A; van Buuren, T

    2008-10-07

    Near-edge x-ray absorption fine structure spectroscopy (NEXAFS) is a powerful tool for determination of molecular orientation in self-assembled monolayers and other surface-attached molecules. A general framework for using NEXAFS to simultaneously determine molecular tilt and twist of rigid molecules attached to surfaces is presented. This framework is applied to self-assembled monolayers of higher diamondoid, hydrocarbon molecules with cubic-diamond-cage structures. Diamondoid monolayers chemisorbed on metal substrates are known to exhibit interesting electronic and surface properties. This work compares molecular orientation in monolayers prepared on silver substrates using two different thiol positional isomers of [121]tetramantane, and thiols derived from two different pentamantane structural isomers, [1212]pentamantane and [1(2,3)4]pentamantane. The observed differences in monolayer structure demonstrate the utility and limitations of NEXAFS spectroscopy and the framework. The results also demonstrate the ability to control diamondoid assembly, in particular the molecular orientational structure, providing a flexible platform for the modification of surface properties with this exciting new class of nanodiamond materials.

  12. Magnetic Field Clumping in Massive Star-Forming Regions as Determined from Excited-State OH Absorption and Maser Emission

    E-Print Network [OSTI]

    Vincent L. Fish; Mark J. Reid; Karl M. Menten

    2005-01-10

    We have observed six high-mass star-forming regions in the 2 Pi 3/2, J = 7/2 lines of OH using the GBT in order to investigate whether the magnetic field, and hence the density, measured in absorption differs from that implied by maser Zeeman splitting. We detect absorption in both the 13441 and 13434 MHz main lines in all six sources. Zeeman splitting in the F = 3-3 absorption line in W3(OH) implies a line-of-sight magnetic field strength of 3.0 +/- 0.3 mG. This is significantly less than full magnetic field strengths detected from OH maser Zeeman splitting, suggesting that OH maser regions may be denser than the non-masing OH material by a factor of several. Zeeman splitting is not detected in other sources, but we are able to place upper limits on B_parallel of 1.2 mG in G10.624-0.385 and 2.9 mG in K3-50. These results are consistent with a density enhancement of the masers, but other explanations for the lower magnetic field in absorption compared to maser emission are possible for these two sources. Absorption in one or both of the 13442 and 13433 MHz satellite lines is also seen in four sources. This is the very first detection of the 2 Pi 3/2, J = 7/2 satellite lines. Ratios of satellite-line to main-line absorption suggest enhancement of the satellite lines from local thermodynamic equilibrium values. Masers are seen in the F = 4-4 and 3-3 transitions of W3(OH) and the 4-4 transition of ON 1. A previously undetected 4-4 maser is seen near -44.85 km/s in W3(OH).

  13. X-ray absorption fine structure spectroscopic determination of plutonium speciation at the Rocky Flats environmental technology

    SciTech Connect (OSTI)

    Lezama-pacheco, Juan S; Conradson, Steven D; Clark, David L

    2008-01-01

    X-ray Absorption Fine Structure spectroscopy was used to probe the speciation of the ppm level Pu in thirteen soil and concrete samples from the Rocky Flats Environmental Technology Site in support of the site remediation effort that has been successfully completed since these measurements. In addition to X-ray Absorption Near Edge Spectra, two of the samples yielded Extended X-ray Absorption Fine Structure spectra that could be analyzed by curve-fits. Most of these spectra exhibited features consistent with PU(IV), and more specificaJly, PuO{sub 2+x}-type speciation. Two were ambiguous, possibly indicating that Pu that was originally present in a different form was transforming into PuO{sub 2+x}, and one was interpreted as demonstrating the presence of an unusual Pu(VI) compound, consistent with its source being spills from a PUREX purification line onto a concrete floor and the resultant extreme conditions. These experimental results therefore validated models that predicted that insoluble PuO{sub 2+x} would be the most stable form of Pu in equilibrium with air and water even when the source terms were most likely Pu metal with organic compounds or a Pu fire. A corollary of these models' predictions and other in situ observations is therefore that the minimal transport of Pu that occurred on the site was via the resuspension and mobilization of colloidal particles. Under these conditions, the small amounts of diffusely distributed Pu that were left on the site after its remediation pose only a negligible hazard.

  14. Band Gap Energy of Chalcopyrite Thin Film Solar Cell Absorbers Determined by Soft X-Ray Emission and Absorption Spectroscopy

    E-Print Network [OSTI]

    Bar, M.

    2010-01-01

    OF CHALCOPYRITE THIN FILM SOLAR CELL ABSORBERS DETERMINED BYchalcopyrite thin film solar cell absorbers significantlyof chalcopyrite thin film solar cell absorbers. excitation

  15. I. Determination of chemical reaction rate constants by numerical nonlinear analysis: differential methods

    E-Print Network [OSTI]

    Christopher G. Jesudason

    2011-01-26

    The primary emphasis of this work on kinetics is to illustrate the a posteriori approach to applications, where focus on data leads to novel outcomes, rather than the a priori tendencies of applied analysis which imposes constructs on the nature of the observable. The secondary intention is the development of appropriate methods consonant with experimental definitions. By focusing on gradients, it is possible to determine both the average and instantaneous rate constants that can monitor changes in the rate constant with concentration changes as suggested by this theory. Here, methods are developed and discussed utilizing nonlinear analysis which does not require exact knowledge of initial concentrations. These methods are compared with those derived from standard methodology. These gradient methods are shown to be consistent with the ones from standard methods and could readily serve as alternatives for studies where there are limits or unknowns in the initial conditions, such as in the burgeoning fields of astrophysics and astrochemistry, forensics, archeology and biology . All four reactions studied exhibited semi sinusoidal-like change with reactant concentration change which standard methods cannot detect, which seems to constitute the observation of a new effect that is not predicted by current formulations, where the possibility that the observations are due to artifacts from instrumental errors or the optimization method is reasoned as unlikely since the experiments were conducted by different groups at very different times with different classes of reactions.

  16. Development and Deployment of a Compact Eye-Safe Scanning Differential absorption Lidar (DIAL) for Spatial Mapping of Carbon Dioxide for Monitoring/Verification/Accounting at Geologic Sequestration Sites

    SciTech Connect (OSTI)

    Repasky, Kevin

    2014-03-31

    A scanning differential absorption lidar (DIAL) instrument for monitoring carbon dioxide has been developed. The laser transmitter uses two tunable discrete mode laser diodes (DMLD) operating in the continuous wave (cw) mode with one locked to the online absorption wavelength and the other operating at the offline wavelength. Two in-line fiber optic switches are used to switch between online and offline operation. After the fiber optic switch, an acousto- optic modulator (AOM) is used to generate a pulse train used to injection seed an erbium doped fiber amplifier (EDFA) to produce eye-safe laser pulses with maximum pulse energies of 66 {micro}J, a pulse repetition frequency of 15 kHz, and an operating wavelength of 1.571 {micro}m. The DIAL receiver uses a 28 cm diameter Schmidt-Cassegrain telescope to collect that backscattered light, which is then monitored using a photo-multiplier tube (PMT) module operating in the photon counting mode. The DIAL instrument has been operated from a laboratory environment on the campus of Montana State University, at the Zero Emission Research Technology (ZERT) field site located in the agricultural research area on the western end of the Montana State University campus, and at the Big Sky Carbon Sequestration Partnership site located in north-central Montana. DIAL data has been collected and profiles have been validated using a co-located Licor LI-820 Gas Analyzer point sensor.

  17. Direct determination of {sup 90}Sr and {sup 147}Pm in Chernobyl hot particles collected in Kiev using beta absorption method

    SciTech Connect (OSTI)

    Papp, Z.; Bolyos, A.; Dezso, Z.; Daroczy, S. [Kossuth Univ., Debrecen (Hungary)

    1997-12-01

    59 hot particles were collected in Kiev, Ukraine, in 1987. All but one were prepared from a moss carpet of 360 cm{sup 2} area. Radionuclide composition of the hot particles was investigated by gamma-spectrometry and beta absorption method. Pure beta emitters {sup 90}Sr and {sup 147}Pm were determined in 25 hot particles measuring the beta absorption curves of the hot particles with an end-window Geiger-Mueller counter and decomposing the curves in order to obtain the contributions of {sup 90}Sr and {sup 147}Pm to the total beta counting rate. All but one of the hot particles were found to be the debris of the fuel. The activity ratio {sup 90}Sr:{sup 144}Ce was 0.078 which is half of the theoretical result. Although {sup 147}Pm is considered to be a refractory nuclide, it seems that significant part of {sup 147}Pm went to the homogeneous fraction of the general fallout. The surface density of hot particles (of higher than about 50 Bq activity) was about 1,600 m{sup -2} and that of the activities of the nuclides {sup 90}Sr, {sup 106}Ru, {sup 134}Cs, {sup 137}Cs, {sup 144}Ce and {sup 147}Pm as components of hot particles was 12.2, 54.3, 5.9, 9.7, 234 and 18.3 kBq m{sup -2} (activity values counted for 26 April 1986), respectively, in downtown Kiev city in 1987.

  18. Mass fractal characteristics of wet sonogels as determined by small-angle x-ray scattering and differential scanning calorimetry

    SciTech Connect (OSTI)

    Vollet, D. R.; Donatti, D. A.; Ibanez Ruiz, A.; Gatto, F. R. [Departamento de Fisica, Unesp-Univerisdade Estadual Paulista, IGCE, P.O. Box 178 CEP 13500-970 Rio Claro, SP (Brazil)

    2006-07-01

    Low density silica sonogels were prepared from acid sonohydrolysis of tetraethoxysilane. Wet gels were studied by small-angle x-ray scattering (SAXS) and differential scanning calorimetry (DSC). The DSC tests were carried out under a heating rate of 2 deg. C/min from -120 deg. C up to 30 deg. C. Aerogels were obtained by CO{sub 2} supercritical extraction and characterized by nitrogen adsorption and SAXS. The DSC thermogram displays two distinct endothermic peaks. The first, a broad peak extending from about -80 deg. C up to practically 0 deg. C, was associated to the melting of ice nanocrystals with a crystal size distribution with 'pore' diameter ranging from 1 or 2 nm up to about 60 nm, as estimated from Thomson's equation. The second, a sharp peak with onset temperature close to 0 deg. C, was attributed to the melting of macroscopic crystals. The DSC incremental 'nanopore' volume distribution is in reasonable agreement with the incremental pore volume distribution of the aerogel as determined from nitrogen adsorption. No macroporosity was detected by nitrogen adsorption, probably because the adsorption method applies stress on the sample during measurement, leading to a underestimation of pore volume, or because often positive curvature of the solid surface is in aerogels, making the nitrogen condensation more difficult. According to the SAXS results, the solid network of the wet gels behaves as a mass fractal structure with mass fractal dimension D=2.20{+-}0.01 in a characteristic length scale below {xi}=7.9{+-}0.1 nm. The mass fractal characteristics of the wet gels have also been probed from DSC data by means of an earlier applied modeling for generation of a mass fractal from the incremental ''pore'' volume distribution curves. The results are shown to be in interesting agreement with the results from SAXS.

  19. Measuring fast electron spectra and laser absorption in relativistic...

    Office of Scientific and Technical Information (OSTI)

    Measuring fast electron spectra and laser absorption in relativistic laser-solid interactions using differential bremsstrahlung photon detectors Citation Details In-Document Search...

  20. Evaluation of beta partical densitometry for determination of self-absorption factors in gross alpha and gross beta radioactivity measurements on air particulate filter samples 

    E-Print Network [OSTI]

    Breida, Margaret A

    1994-01-01

    Alpha and beta particles emitted from radioactive material collected on an air filter may be significantly attenuated by the mass (thickness) of collected dust. In this study, we determined the mass or thickness of the simulated dust deposit...

  1. Method of and apparatus for determining the similarity of a biological analyte from a model constructed from known biological fluids

    DOE Patents [OSTI]

    Robinson, Mark R. (Albuquerque, NM); Ward, Kenneth J. (Albuquerque, NM); Eaton, Robert P. (Albuquerque, NM); Haaland, David M. (Albuquerque, NM)

    1990-01-01

    The characteristics of a biological fluid sample having an analyte are determined from a model constructed from plural known biological fluid samples. The model is a function of the concentration of materials in the known fluid samples as a function of absorption of wideband infrared energy. The wideband infrared energy is coupled to the analyte containing sample so there is differential absorption of the infrared energy as a function of the wavelength of the wideband infrared energy incident on the analyte containing sample. The differential absorption causes intensity variations of the infrared energy incident on the analyte containing sample as a function of sample wavelength of the energy, and concentration of the unknown analyte is determined from the thus-derived intensity variations of the infrared energy as a function of wavelength from the model absorption versus wavelength function.

  2. Absorption of carbonyl sulfide in aqueous methyldiethanolamine

    SciTech Connect (OSTI)

    Al-Ghawas, H.A.; Ruiz-Ibanez, G.; Sandall, O.C. (Dept. of Chemical and Nuclear Engineering, Univ. of California, Santa Barbara, CA (US))

    1988-01-01

    The absorption of carbonyl sulfide in aqueous methyldiethanolamine (MDEA) was studied over a range of temperatures and MDEA concentrations. MDEA is commonly used for selective absorption of hydrogen sulfide in the presence of carbon dioxide. However, sulfur in the form of COS may also be present and it is necessary that estimates of absorption rates of this compound be made. The objective of this study is to determine the physiochemical properties needed to predict COS absorption rates in aqueous MDEA. Free gas solubility and the diffusivity of COS in MDEA solutions were measured over the temperature range 15 to 40{sup 0}C for MDEA concentrations up to 30 weight per cent using the nitrous oxide analogy method. Solubilities were measured volumetrically in an equilibrium cell and diffusivities were measured using a laminar liquid jet absorber. The kinetics of the reaction between COS and MDEA were studied by measuring absorption rates in a single wetted-sphere absorber.

  3. Residential Absorption Water Heater

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Residential Absorption Water Heater 2014 Building Technologies Office Peer Review Kyle Gluesenkamp, gluesenkampk@ornl.gov Oak Ridge National Laboratory Project Summary Timeline:...

  4. Solar absorption surface panel

    DOE Patents [OSTI]

    Santala, Teuvo J. (Attleboro, MA)

    1978-01-01

    A composite metal of aluminum and nickel is used to form an economical solar absorption surface for a collector plate wherein an intermetallic compound of the aluminum and nickel provides a surface morphology with high absorptance and relatively low infrared emittance along with good durability.

  5. Determining Relative f and d Orbital Contributions to M?Cl Covalency in MCl62– (M = Ti, Zr, Hf, U) and UOCl5 Using Cl K-Edge X-ray Absorption Spectroscopy and Time-Dependent Density Functional Theory

    SciTech Connect (OSTI)

    Minasian, Stefan G.; Keith, Jason M.; Batista, Enrique R.; Boland, Kevin S.; Clark, David L.; Conradson, Steven D.; Kozimor, Stosh A.; Martin, Richard L.; Schwarz, Daniel E.; Shuh, David K.; Wagner, Gregory L.; Wilkerson, Marianne P.; Wolfsberg, Laura E.; Yang, Ping

    2012-03-09

    Chlorine K-edge X-ray absorption spectroscopy (XAS) and ground-state and time-dependent hybrid density functional theory (DFT) were used to probe electronic structure for O{sub h}-MCl{sub 6}{sup 2-}(M = Ti, Zr, Hf, U) and C{sub 4v}-UOCl{sub 5}{sup -}, and to determine the relative contributions of valence 3d, 4d, 5d, 6d, and 5f orbitals in M-Cl bonding. Spectral interpretations were guided by time-dependent DFT calculated transition energies and oscillator strengths, which agree well with the experimental XAS spectra. The data provide new spectroscopic evidence for the involvement of both 5f and 6d orbitals in actinide-ligand bonding in UCl{sub 6}{sup 2-}. For the MCl{sub 6}{sup 2-}, where transitions into d orbitals of t{sub 2g} symmetry are spectroscopically resolved for all four complexes, the experimentally determined Cl 3p character per M-Cl bond increases from 8.3(4)% (TiCl{sub 6}{sup 2-}) to 10.3(5)% (ZrCl{sub 6}{sup 2-}), 12(1)% (HfCl{sub 6}{sup 2-}), and 26 18(1)% (UCl{sub 6}{sup 2-}). Chlorine K-edge XAS spectra of UOCl{sub 5}{sup -} provide additional insights into the transition assignments by 27 lowering the symmetry to C{sub 4v}, where five pre-edge transitions into both 5f and 6d orbitals are observed. For UCl{sub 6}{sup 2-}, the XAS data 28 suggest that orbital mixing associated with the U 5f orbitals is considerably lower than that of the U 6d orbitals. For both UCl{sub 6}{sup 2-}29 and UOCl{sub 5}{sup -}, the ground-state DFT calculations predict a larger 5f contribution to bonding than is determined experimentally. 30 These findings are discussed in the context of conventional theories of covalent bonding for d- and f-block metal complexes.

  6. Formaldehyde Absorption toward W51

    E-Print Network [OSTI]

    Kogut, A.; Smoot, G.F.; Bennett, C.L.; Petuchowski, S.J.

    1988-01-01

    to Astrophysical Journal Formaldehyde Absorption toward W51Number DE-AC03-76SF00098. FORMALDEHYDE ABSORPTION TOWARD W51We have measured formaldehyde (H2CO) absorption toward the

  7. Absorption heat pump system

    DOE Patents [OSTI]

    Grossman, G.

    1982-06-16

    The efficiency of an absorption heat pump system is improved by conducting liquid from a second stage evaporator thereof to an auxiliary heat exchanger positioned downstream of a primary heat exchanger in the desorber of the system.

  8. Absorption heat pump system

    DOE Patents [OSTI]

    Grossman, Gershon (Oak Ridge, TN)

    1984-01-01

    The efficiency of an absorption heat pump system is improved by conducting liquid from a second stage evaporator thereof to an auxiliary heat exchanger positioned downstream of a primary heat exchanger in the desorber of the system.

  9. Solar selective absorption coatings

    DOE Patents [OSTI]

    Mahoney, Alan R. (Albuquerque, NM); Reed, Scott T. (Albuquerque, NM); Ashley, Carol S. (Albuquerque, NM); Martinez, F. Edward (Horseheads, NY)

    2003-10-14

    A new class of solar selective absorption coatings are disclosed. These coatings comprise a structured metallic overlayer such that the overlayer has a sub-micron structure designed to efficiently absorb solar radiation, while retaining low thermal emissivity for infrared thermal radiation. A sol-gel layer protects the structured metallic overlayer from mechanical, thermal, and environmental degradation. Processes for producing such solar selective absorption coatings are also disclosed.

  10. Solar selective absorption coatings

    DOE Patents [OSTI]

    Mahoney, Alan R. (Albuquerque, NM); Reed, Scott T. (Albuquerque, NM); Ashley, Carol S. (Albuquerque, NM); Martinez, F. Edward (Horseheads, NY)

    2004-08-31

    A new class of solar selective absorption coatings are disclosed. These coatings comprise a structured metallic overlayer such that the overlayer has a sub-micron structure designed to efficiently absorb solar radiation, while retaining low thermal emissivity for infrared thermal radiation. A sol-gel layer protects the structured metallic overlayer from mechanical, thermal, and environmental degradation. Processes for producing such solar selective absorption coatings are also disclosed.

  11. Seven-effect absorption refrigeration

    DOE Patents [OSTI]

    DeVault, R.C.; Biermann, W.J.

    1989-05-09

    A seven-effect absorption refrigeration cycle is disclosed utilizing three absorption circuits. In addition, a heat exchanger is used for heating the generator of the low absorption circuit with heat rejected from the condenser and absorber of the medium absorption circuit. A heat exchanger is also provided for heating the generator of the medium absorption circuit with heat rejected from the condenser and absorber of the high absorption circuit. If desired, another heat exchanger can also be provided for heating the evaporator of the high absorption circuit with rejected heat from either the condenser or absorber of the low absorption circuit. 1 fig.

  12. Absorption heat pump system

    DOE Patents [OSTI]

    Grossman, Gershon (Oak Ridge, TN); Perez-Blanco, Horacio (Knoxville, TN)

    1984-01-01

    An improvement in an absorption heat pump cycle is obtained by adding adiabatic absorption and desorption steps to the absorber and desorber of the system. The adiabatic processes make it possible to obtain the highest temperature in the absorber before any heat is removed from it and the lowest temperature in the desorber before heat is added to it, allowing for efficient utilization of the thermodynamic availability of the heat supply stream. The improved system can operate with a larger difference between high and low working fluid concentrations, less circulation losses, and more efficient heat exchange than a conventional system.

  13. Exciton diffusion in semiconducting single-walled carbon nanotubes studied by transient absorption microscopy

    E-Print Network [OSTI]

    Ruzicka, Brian Andrew; Wang, Rui; Lohrman, Jessica; Ren, Shenqiang; Zhao, Hui

    2012-11-09

    Spatiotemporal dynamics of excitons in isolated semiconducting single-walled carbon nanotubes are studied using transient absorption microscopy. Differential reflection and transmission of an 810-nm probe pulse after excitation by a 750-nm pump...

  14. Oral Drug Absorption

    E-Print Network [OSTI]

    Yamashita, Shinji

    2006-10-26

    Stability 0 20 40 60 80 100 25 10 5 1 0.5 size? r 0 (?m) Fr action absor b ed in hum an (% ) Peff =5.0 Peff =3.0 Peff =1.0 Peff =0.5 Peff =0.1 Solubility? Cs = 1.0 (?g/ml) Effect of micronization on intestinal absorption of poorly soluble drugs Peff... ?? permeability to human intestine? (cm/sec x 10 -4 ) 8 Effect of Solubility on intestinal absorption of poorly soluble drugs Cs (?g/ml) 0 5 10 15 50 Fr action absor b ed in hum an (% ) 0 20 40 60 80 100 Peff =5.0 Peff =3.0 Peff =1.0 Peff =0.5 Peff =0.1 r 0 = 1...

  15. Absorption in dielectric models

    E-Print Network [OSTI]

    Churchill, R J

    2015-01-01

    We develop a classical microscopic model of a dielectric. The model features nonlinear interaction terms between polarizable dipoles and lattice vibrations. The lattice vibrations are found to act as a pseudo-reservoir, giving broadband absorption of electromagnetic radiation without the addition of damping terms in the dynamics. The effective permittivity is calculated using a perturbative iteration method and is found to have the form associated with real dielectrics. Spatial dispersion is naturally included in the model and we also calculate the wavevector dependence of the permittivity.

  16. Optical absorption of silicon nanowires

    SciTech Connect (OSTI)

    Xu, T. [Key Laboratory of Advanced Display and System Application, Shanghai University, 149 Yanchang Road, Shanghai 200072 (China); Institut d'Electronique et de Microelectronique et de Nanotechnologies, IEMN (CNRS, UMR 8520), Groupe de Physique, Cite scientifique, avenue Poincare, 59652 Villeneuve d'Ascq (France); Lambert, Y.; Krzeminski, C.; Grandidier, B.; Stievenard, D.; Leveque, G.; Akjouj, A.; Pennec, Y.; Djafari-Rouhani, B. [Institut d'Electronique et de Microelectronique et de Nanotechnologies, IEMN (CNRS, UMR 8520), Groupe de Physique, Cite scientifique, avenue Poincare, 59652 Villeneuve d'Ascq (France)

    2012-08-01

    We report on simulations and measurements of the optical absorption of silicon nanowires (NWs) versus their diameter. We first address the simulation of the optical absorption based on two different theoretical methods: the first one, based on the Green function formalism, is useful to calculate the scattering and absorption properties of a single or a finite set of NWs. The second one, based on the finite difference time domain (FDTD) method, is well-adapted to deal with a periodic set of NWs. In both cases, an increase of the onset energy for the absorption is found with increasing diameter. Such effect is experimentally illustrated, when photoconductivity measurements are performed on single tapered Si nanowires connected between a set of several electrodes. An increase of the nanowire diameter reveals a spectral shift of the photocurrent intensity peak towards lower photon energies that allow to tune the absorption onset from the ultraviolet radiations to the visible light spectrum.

  17. Differential Equations Lectures INF2320 p. 1/6

    E-Print Network [OSTI]

    Stølen, Ketil

    of Calculus, we get the solution r(t) = r(0)+ t 0 f(s)ds (3) · The integral can then be calculated as accurateDifferential Equations Lectures INF2320 ­ p. 1/6 #12;Differential equations · A differential be determined · In practice, differential equations typically describe quantities that changes in relation

  18. Polaron absorption in amorphous tungsten oxide films

    SciTech Connect (OSTI)

    Berggren, Lars; Azens, Andris; Niklasson, Gunnar A.

    2001-08-15

    Amorphous thin films of tungsten oxide were deposited by sputtering onto glass substrates covered by conductive indium--tin oxide. The density and stoichiometry were determined by Rutherford backscattering spectrometry. Lithium ions were intercalated electrochemically into the films. The optical reflectance and transmittance were measured in the wavelength range from 0.3 to 2.5 {mu}m, at a number of intercalation levels. The polaron absorption peak becomes more symmetric and shifts to higher energies until an intercalation level of 0.25 to 0.3 Li{sup +}/W, where a saturation occurs. The shape of the polaron peak is in very good agreement with the theory of Bryksin [Fiz. Tverd. Tela 24, 1110 (1982)]. Within this model, the shift of the absorption peak is interpreted as an increase in the Fermi level of the material as more Li ions are inserted. {copyright} 2001 American Institute of Physics.

  19. Absorption Heat Pumps | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Absorption Heat Pumps Absorption Heat Pumps June 24, 2012 - 2:11pm Addthis Absorption heat pumps are essentially air-source heat pumps driven not by electricity, but by a heat...

  20. Differential Equations: Page 1 Differential equations

    E-Print Network [OSTI]

    Hogg, Andrew

    ) is a nth order differential equation. The aim is calculate the unknown function y(x). A linear differential First order differential equations 1.1 Direct integration If dy dx = g(x) subject to y(b) = y0 then y and is to be downloaded or copied for your private study only. #12;Differential Equations: Page 2 1.3 Integrating factor

  1. Method for processing seismic data to identify anomalous absorption zones

    DOE Patents [OSTI]

    Taner, M. Turhan

    2006-01-03

    A method is disclosed for identifying zones anomalously absorptive of seismic energy. The method includes jointly time-frequency decomposing seismic traces, low frequency bandpass filtering the decomposed traces to determine a general trend of mean frequency and bandwidth of the seismic traces, and high frequency bandpass filtering the decomposed traces to determine local variations in the mean frequency and bandwidth of the seismic traces. Anomalous zones are determined where there is difference between the general trend and the local variations.

  2. Effect of nonlinear absorption on electric field applied lead chloride by Z-scan technique

    SciTech Connect (OSTI)

    Rejeena, I. [International School of Photonics, Cochin University of Science and Technology, Cochin Kerala, India and M.S.M. College, Kayamkulam, Kerala (India); Lillibai,; Nampoori, V. P. N.; Radhakrishnan, P. [International School of Photonics, Cochin University of Science and Technology, Cochin Kerala (India); Rahimkutty, M. H. [M.S.M. College, Kayamkulam, Kerala (India)

    2014-10-15

    The preparation, spectral response and optical nonlinearity of gel grown lead chloride single crystals subjected to electric field of 20V using parallel plate arrangements have been investigated. Optical band gap of the samples were determined using linear absorption spectra. Open aperture z-scan was employed for the determination of nonlinear absorption coefficient of PbCl{sub 2} solution. The normalized transmittance curve exhibits a valley shows reverse saturable absorption. The non linear absorption at different input fluences were recorded using a single Gaussian laser beam in tight focus geometry. The RSA nature of the sample makes it suitable for optical limiting applications.

  3. Transient absorption spectroscopy of laser shocked explosives

    SciTech Connect (OSTI)

    Mcgrane, Shawn D; Dang, Nhan C; Whitley, Von H; Bolome, Cindy A; Moore, D S

    2010-01-01

    Transient absorption spectra from 390-890 nm of laser shocked RDX, PETN, sapphire, and polyvinylnitrate (PVN) at sub-nanosecond time scales are reported. RDX shows a nearly linear increase in absorption with time after shock at {approx}23 GPa. PETN is similar, but with smaller total absorption. A broad visible absorption in sapphire begins nearly immediately upon shock loading but does not build over time. PVN exhibits thin film interference in the absorption spectra along with increased absorption with time. The absorptions in RDX and PETN are suggested to originate in chemical reactions happening on picosecond time scales at these shock stresses, although further diagnostics are required to prove this interpretation.

  4. Absorption-heat-pump system

    DOE Patents [OSTI]

    Grossman, G.; Perez-Blanco, H.

    1983-06-16

    An improvement in an absorption heat pump cycle is obtained by adding adiabatic absorption and desorption steps to the absorber and desorber of the system. The adiabatic processes make it possible to obtain the highest temperature in the absorber before any heat is removed from it and the lowest temperature in the desorber before heat is added to it, allowing for efficient utilization of the thermodynamic availability of the heat supply stream. The improved system can operate with a larger difference between high and low working fluid concentrations, less circulation losses, and more efficient heat exchange than a conventional system.

  5. Method and apparatus for aerosol particle absorption spectroscopy

    DOE Patents [OSTI]

    Campillo, Anthony J. (Nesconset, NY); Lin, Horn-Bond (Manorville, NY)

    1983-11-15

    A method and apparatus for determining the absorption spectra, and other properties, of aerosol particles. A heating beam source provides a beam of electromagnetic energy which is scanned through the region of the spectrum which is of interest. Particles exposed to the heating beam which have absorption bands within the band width of the heating beam absorb energy from the beam. The particles are also illuminated by light of a wave length such that the light is scattered by the particles. The absorption spectra of the particles can thus be determined from an analysis of the scattered light since the absorption of energy by the particles will affect the way the light is scattered. Preferably the heating beam is modulated to simplify the analysis of the scattered light. In one embodiment the heating beam is intensity modulated so that the scattered light will also be intensity modulated when the particles absorb energy. In another embodiment the heating beam passes through an interferometer and the scattered light reflects the Fourier Transform of the absorption spectra.

  6. Quantitative determination of the absorption spectraof chromophores in strongly scattering

    E-Print Network [OSTI]

    Fantini, Sergio

    : a light-emitting-diode based technique Sergio Fantini, Maria and Enrico Gratton Angela Franceschini in the spectral range from 620 to 700 nm. We conduct the measurements in the frequency domain by using a light-emitting diode(LED) whose intensity is modulated at a frequency of 60 MHz. We derive an analytical expression

  7. Measurement of Water Vapor Concentration using Tunable Diode Laser Absorption Spectroscopy 

    E-Print Network [OSTI]

    Barrett, Alexander B.

    2010-07-14

    Tunable diode laser spectroscopy and the Beer-Lambert relation has been used to measure the absorption of water vapor both in an absorption cell and in a shock tube. The purpose of this thesis is to develop a laser diagnostic capable of determining...

  8. Results of Self-Absorption Study on the Versapor 3000 Filters for Radioactive Particulate Air Sampling

    SciTech Connect (OSTI)

    Barnett, J. M.; Cullinan, Valerie I.; Barnett, Debra S.; Trang-Le, Truc LT; Bliss, Mary; Greenwood, Lawrence R.; Ballinger, Marcel Y.

    2009-02-17

    Since the mid-1980s, Pacific Northwest National Laboratory (PNNL) has used a value of 0.85 as the correction factor for self absorption of activity for particulate radioactive air samples collected from building exhaust for environmental monitoring. This value accounts for activity that cannot be detected by direct counting of alpha and beta particles. Emissions can be degraded or blocked by filter fibers for particles buried in the filter material or by inactive dust particles collected with the radioactive particles. These filters are used for monitoring air emissions from PNNL stacks for radioactive particles. This paper describes an effort to re-evaluate self-absorption effects in particulate radioactive air sample filters (Versapor® 3000, 47 mm diameter) used at PNNL. There were two methods used to characterize the samples. Sixty samples were selected from the archive for acid digestion to compare the radioactivity measured by direct gas-flow proportional counting of filters to the results obtained after acid digestion of the filter and counting again by gas-flow proportional detection. Thirty different sample filters were selected for visible light microscopy to evaluate filter loading and particulate characteristics. Mass-loading effects were also considered. Filter ratios were calculated by dividing the initial counts by the post-digestion counts with the expectation that post-digestion counts would be higher because digestion would expose radioactivity embedded in the filter in addition to that on top of the filter. Contrary to expectations, the post digestion readings were almost always lower than initial readings and averaged approximately half the initial readings for both alpha and beta activity. Before and after digestion readings appeared to be related to each other, but with a low coefficient of determination (R^2) value. The ratios had a wide range of values indicating that this method did not provide sufficient precision to quantify self-absorption effects. The microscopy analysis compares different filter loadings and shows that smaller particle sizes (under 10 micron) can readily be seen on the more lightly loaded filters. At higher loadings, however, the particle size is harder to differentiate. This study provides data on actual stack emission samples showing a range of mass loading conditions and visual evidence of particle size and distribution and also presents the difficulties in quantifying self-absorption effects using actual samples.

  9. Differential Wiener process

    E-Print Network [OSTI]

    Penny, Will

    Stochastic Processes Will Penny Stochastic Differential Equations Wiener process Sample Paths OU rates References Stochastic Processes Will Penny 19th May 2011 #12;Stochastic Processes Will Penny on Hierarchical Dynamic Models #12;Stochastic Processes Will Penny Stochastic Differential Equations Wiener

  10. Measurement of the inclusive 3-jet production differential cross section in proton–proton collisions at 7 TeV and determination of the strong coupling constant in the TeV range

    E-Print Network [OSTI]

    Apyan, Aram

    This paper presents a measurement of the inclusive 3-jet production differential cross section at a proton–proton centre-of-mass energy of 7 TeV using data corresponding to an integrated luminosity of 5 fb[superscript ?1] ...

  11. Microlensing induced absorption line variability

    E-Print Network [OSTI]

    Geraint F. Lewis; Rodrigo A. Ibata

    2002-12-02

    Gravitational microlensing has proven to be a powerful probe of both the structure at the heart of quasars and the mass function of compact objects in foreground lenses. This paper examines the potential of gravitational microlensing in probing the scale of structure in absorbing material within the lensing galaxy. We find that, in this high optical depth regime, significant variations in the equivalent width of absorption features can be induced, although the details of these are dependent upon the scale of structure of the absorbing material. The paper concludes with an examination of the absorption line variability observed in the gravitationally lensed quasar PKS1830-211, demonstrating how this may indicate the presence of small scale structure in the cold molecular gas present within the lensing galaxy.

  12. Backscatter absorption gas imaging systems and light sources therefore

    DOE Patents [OSTI]

    Kulp, Thomas Jan (Livermore, CA); Kliner, Dahv A. V. (San Ramon, CA); Sommers, Ricky (Oakley, CA); Goers, Uta-Barbara (Campbell, NY); Armstrong, Karla M. (Livermore, CA)

    2006-12-19

    The location of gases that are not visible to the unaided human eye can be determined using tuned light sources that spectroscopically probe the gases and cameras that can provide images corresponding to the absorption of the gases. The present invention is a light source for a backscatter absorption gas imaging (BAGI) system, and a light source incorporating the light source, that can be used to remotely detect and produce images of "invisible" gases. The inventive light source has a light producing element, an optical amplifier, and an optical parametric oscillator to generate wavelength tunable light in the IR. By using a multi-mode light source and an amplifier that operates using 915 nm pump sources, the power consumption of the light source is reduced to a level that can be operated by batteries for long periods of time. In addition, the light source is tunable over the absorption bands of many hydrocarbons, making it useful for detecting hazardous gases.

  13. Photodetector with enhanced light absorption

    DOE Patents [OSTI]

    Kane, James (Lawrenceville, NJ)

    1985-01-01

    A photodetector including a light transmissive electrically conducting layer having a textured surface with a semiconductor body thereon. This layer traps incident light thereby enhancing the absorption of light by the semiconductor body. A photodetector comprising a textured light transmissive electrically conducting layer of SnO.sub.2 and a body of hydrogenated amorphous silicon has a conversion efficiency about fifty percent greater than that of comparative cells. The invention also includes a method of fabricating the photodetector of the invention.

  14. Moisture absorption in hybrid composites 

    E-Print Network [OSTI]

    Clark, Dan Laro

    1983-01-01

    Moisture Analysis for Steady State Boundary Conditions", Journal of Com osite Materials, Vol. 15, March 1981, pp. 142-152. 7. Weitsman, Y. , Priorate Communication, Texas A&M University, January 1983. 8. Wirth, Patricia E. and Rodin, Ervin Y. , "A... of Department) December 1983 111. ABSTRACT Moisture Absorption in Hybrid Composites (December 1983) Dan Laro Clark, B. S. Aerospace Engineering Texas A&M University Co-Chairmen of Advisory Comnittee: Dr. Y. Weitsman Dr. W. J. Horn This thesis presents...

  15. Proportional Differentiated Services: Delay Differentiation and Packet Scheduling

    E-Print Network [OSTI]

    Dovrolis, Constantinos

    Proportional Differentiated Services: Delay Differentiation and Packet Scheduling Constantinos propose the proportional differ­ entiation model as a way to refine and quantify this basic premise of relative differentiated services. The proportional differentiation model aims to provide the network

  16. Absolute differential cross sections for elastic scattering of electrons from pyrimidine

    SciTech Connect (OSTI)

    Maljkovic, J. B.; Milosavljevic, A. R.; Sevic, D.; Marinkovic, B. P.; Blanco, F.

    2009-05-15

    Differential cross sections (DCSs) for elastic scattering of electrons from pyrimidine (C{sub 4}H{sub 4}N{sub 2}) are presented for incident energies from 50 to 300 eV. The measurements were performed using a cross beam technique, for scattering angles from 20 deg. to 110 deg. The relative DCSs were measured as a function of both the angle and incident energy and the absolute DCSs were determined using the relative flow method. The calculations of electron interaction cross sections are based on a corrected form of the independent-atom method, known as the screen corrected additivity rule procedure and using an improved quasifree absorption model. Calculated results agree very well with the experiment.

  17. Advanced regenerative absorption refrigeration cycles

    DOE Patents [OSTI]

    Dao, Kim (14 Nace Ave., Piedmont, CA 94611)

    1990-01-01

    Multi-effect regenerative absorption cycles which provide a high coefficient of performance (COP) at relatively high input temperatures. An absorber-coupled double-effect regenerative cycle (ADR cycle) (10) is provided having a single-effect absorption cycle (SEA cycle) (11) as a topping subcycle and a single-effect regenerative absorption cycle (1R cycle) (12) as a bottoming subcycle. The SEA cycle (11) includes a boiler (13), a condenser (21), an expansion device (28), an evaporator (31), and an absorber (40), all operatively connected together. The 1R cycle (12) includes a multistage boiler (48), a multi-stage resorber (51), a multisection regenerator (49) and also uses the condenser (21), expansion device (28) and evaporator (31) of the SEA topping subcycle (11), all operatively connected together. External heat is applied to the SEA boiler (13) for operation up to about 500 degrees F., with most of the high pressure vapor going to the condenser (21) and evaporator (31) being generated by the regenerator (49). The substantially adiabatic and isothermal functioning of the SER subcycle (12) provides a high COP. For higher input temperatures of up to 700 degrees F., another SEA cycle (111) is used as a topping subcycle, with the absorber (140) of the topping subcycle being heat coupled to the boiler (13) of an ADR cycle (10). The 1R cycle (12) itself is an improvement in that all resorber stages (50b-f) have a portion of their output pumped to boiling conduits (71a-f) through the regenerator (49), which conduits are connected to and at the same pressure as the highest pressure stage (48a) of the 1R multistage boiler (48).

  18. Separable Differential Equations

    E-Print Network [OSTI]

    PRETEX (Halifax NS) #1 1054 1999 Mar 05 10:59:16

    2010-01-20

    Feb 16, 2007 ... preceding differential equation and several mem- bers of the given family of curves. Describe the family of orthogonal trajectories. 34. Consider ...

  19. Introduction to differential forms

    E-Print Network [OSTI]

    2015-03-09

    Mar 9, 2015 ... The calculus of differential forms give an alternative to vector calculus ..... suggests, for the work we would now need to calculate the integral. ?.

  20. Monitoring PVD metal vapors using laser absorption spectroscopy

    SciTech Connect (OSTI)

    Braun, D.G.; Anklam, T.M.; Berzins, L.V.; Hagans, K.G.

    1994-04-01

    Laser absorption spectroscopy (LAS) has been used by the Atomic Vapor Laser Isotope Separation (AVLIS) program for over 10 years to monitor the co-vaporization of uranium and iron in its separators. During that time, LAS has proven to be an accurate and reliable method to monitor both the density and composition of the vapor. It has distinct advantages over other rate monitors, in that it is completely non-obtrusive to the vaporization process and its accuracy is unaffected by the duration of the run. Additionally, the LAS diagnostic has been incorporated into a very successful process control system. LAS requires only a line of sight through the vacuum chamber, as all hardware is external to the vessel. The laser is swept in frequency through an absorption line of interest. In the process a baseline is established, and the line integrated density is determined from the absorption profile. The measurement requires no hardware calibration. Through a proper choice of the atomic transition, a wide range of elements and densities have been monitored (e.g. nickel, iron, cerium and gadolinium). A great deal of information about the vapor plume can be obtained from the measured absorption profiles. By monitoring different species at the same location, the composition of the vapor is measured in real time. By measuring the same density at different locations, the spatial profile of the vapor plume is determined. The shape of the absorption profile is used to obtain the flow speed of the vapor. Finally, all of the above information is used evaluate the total vaporization rate.

  1. Olefin recovery via chemical absorption

    SciTech Connect (OSTI)

    Barchas, R.

    1998-06-01

    The recovery of fight olefins in petrochemical plants has generally been accomplished through cryogenic distillation, a process which is very capital and energy intensive. In an effort to simplify the recovery process and reduce its cost, BP Chemicals has developed a chemical absorption technology based on an aqueous silver nitrate solution. Stone & Webster is now marketing, licensing, and engineering the technology. The process is commercially ready for recovering olefins from olefin derivative plant vent gases, such as vents from polyethylene, polypropylene, ethylene oxide, and synthetic ethanol units. The process can also be used to debottleneck C{sub 2} or C{sub 3} splinters, or to improve olefin product purity. This paper presents the olefin recovery imp technology, discusses its applications, and presents economics for the recovery of ethylene and propylene.

  2. Progress toward high-Q perfect absorption: A Fano antilaser

    E-Print Network [OSTI]

    Yu, Sunkyu; Hong, Jiho; Park, Namkyoo

    2015-01-01

    Here we propose a route to the high-Q perfect absorption of light by introducing the concept of a Fano anti-laser. Based on the drastic spectral variation of the optical phase in a Fano-resonant system, a spectral singularity for scatter-free perfect absorption can be achieved with an order of magnitude smaller material loss. By applying temporal coupled mode theory to a Fano-resonant waveguide platform, we reveal that the required material loss and following absorption Q-factor are ultimately determined by the degree of Fano spectral asymmetry. The feasibility of the Fano anti-laser is confirmed using a photonic crystal platform, to demonstrate spatio-spectrally selective heating. Our results utilizing the phase-dependent control of device bandwidths derive a counterintuitive realization of high-Q perfect conversion of light into internal energy, and thus pave the way for a new regime of absorption-based devices, including switches, sensors, thermal imaging, and opto-thermal emitters.

  3. Combining Feedback Absorption Spectroscopy, Amplified Resonance...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    On-Board Measurement of Ammonia and Nitrous Oxide Using Feedback Absorption Laser Spectroscopy Combined with Amplified Resonance and Low Pressure Sampling Cummins...

  4. Advanced Low Temperature Absorption Chiller Module Integrated...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Low Temperature Absorption Chiller Module Integrated with a CHP System at a Distributed Data Center - Presentation by Exergy Partners Corp., June 2011 Advanced Low Temperature...

  5. Direct and quantitative absorptive spectroscopy of nanowires

    E-Print Network [OSTI]

    Tong, Jonathan Kien-Kwok

    2012-01-01

    Photonic nanostructures exhibit unique optical properties that are attractive in many different applications. However, measuring the optical properties of individual nanostructures, in particular the absorptive properties, ...

  6. Solids mass flow determination

    DOE Patents [OSTI]

    Macko, Joseph E. (Hempfield Township, Westmoreland County, PA)

    1981-01-01

    Method and apparatus for determining the mass flow rate of solids mixed with a transport fluid to form a flowing mixture. A temperature differential is established between the solids and fluid. The temperature of the transport fluid prior to mixing, the temperature of the solids prior to mixing, and the equilibrium temperature of the mixture are monitored and correlated in a heat balance with the heat capacities of the solids and fluid to determine the solids mass flow rate.

  7. High Energy Astrophysics: Emission and Absorption 1/114 Emission and Absorption

    E-Print Network [OSTI]

    Bicknell, Geoff

    High Energy Astrophysics: Emission and Absorption 1/114 Emission and Absorption 1 Motivation and the jet. #12;High Energy Astrophysics: Emission and Absorption 2/114 HST optical image of 3C273 Note the very strong cen- tral point source and the less luminous jet. Objects such as 3C273 radiate as much

  8. Computational Differentiation in Global Optimization

    E-Print Network [OSTI]

    Neumaier, Arnold

    Computational Differentiation in Global Optimization Software This talk will present: 1. The general problem framework in optimization software. 2. An example of effectiveness of computational differentiation in optimization packages. 3. Particular importance of computational differentiation verified

  9. Cross section for charmonium absorption by nucleons 

    E-Print Network [OSTI]

    Liu, W.; Ko, Che Ming; Lin, ZW.

    2002-01-01

    The cross section for J/psi absorption by nucleons is studied using a gauged SU(4) hadronic Lagrangian but with empirical particle masses, which has been used previously to study the cross sections for J/psi absorption by pion and rho meson...

  10. INCREASED LEAD ABSORPTION AND LEAD POISONING

    E-Print Network [OSTI]

    INCREASED LEAD ABSORPTION AND LEAD POISONING IN YOUNG CHILDREN A STATDIE:"IT BY THE CEJde slnt:t! the Surgeon GenerJi's Statement. "~edicJI Aspects of Childhood Lead POisoning," was issued:ld absorption Jnd lead poisoning. Such JCtivities for children will continue to be necessary until sources

  11. Measurement of the inclusive 3-jet production differential cross section in proton-proton collisions at 7 TeV and determination of the strong coupling constant in the TeV range

    SciTech Connect (OSTI)

    Khachatryan, Vardan

    2015-05-01

    This paper presents a measurement of the inclusive 3-jet production differential cross section at a proton-proton centre-of-mass energy of 7 TeV using data corresponding to an integrated luminosity of 5 fb$^{-1}$ collected with the CMS detector. The analysis is based on the three jets with the highest transverse momenta. The cross section is measured as a function of the invariant mass of the three jets in a range of 445-3270 GeV and in two bins of the maximum rapidity of the jets up to a value of 2. A comparison between the measurement and the prediction from perturbative QCD at next-to-leading order is performed. Within uncertainties, data and theory are in agreement. The sensitivity of the observable to parameters of the theory such as the parton distribution functions of the proton and the strong coupling constant $\\alpha_S$ is studied. A fit to all data points with 3-jet masses larger than 664 GeV gives a value of the strong coupling constant of $\\alpha_S(M_\\mathrm{Z})$ = 0.1171 $\\pm$ 0.0013 (exp) $^{+0.0073}_{-0.0047}$ (theo).

  12. Measurement of the inclusive 3-jet production differential cross section in proton-proton collisions at 7 TeV and determination of the strong coupling constant in the TeV range

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Khachatryan, Vardan

    2015-05-01

    This paper presents a measurement of the inclusive 3-jet production differential cross section at a proton-proton centre-of-mass energy of 7 TeV using data corresponding to an integrated luminosity of 5 fb$^{-1}$ collected with the CMS detector. The analysis is based on the three jets with the highest transverse momenta. The cross section is measured as a function of the invariant mass of the three jets in a range of 445-3270 GeV and in two bins of the maximum rapidity of the jets up to a value of 2. A comparison between the measurement and the prediction from perturbative QCD atmore »next-to-leading order is performed. Within uncertainties, data and theory are in agreement. The sensitivity of the observable to parameters of the theory such as the parton distribution functions of the proton and the strong coupling constant $\\alpha_S$ is studied. A fit to all data points with 3-jet masses larger than 664 GeV gives a value of the strong coupling constant of $\\alpha_S(M_\\mathrm{Z})$ = 0.1171 $\\pm$ 0.0013 (exp) $^{+0.0073}_{-0.0047}$ (theo).« less

  13. Differential pressure sensing system for airfoils usable in turbine engines

    DOE Patents [OSTI]

    Yang, Wen-Ching; Stampahar, Maria E.

    2005-09-13

    A detection system for identifying airfoils having a cooling systems with orifices that are plugged with contaminants or with showerheads having a portion burned off. The detection system measures pressures at different locations and calculates or measures a differential pressure. The differential pressure may be compared with a known benchmark value to determine whether the differential pressure has changed. Changes in the differential pressure may indicate that one or more of the orifices in a cooling system of an airfoil are plugged or that portions of, or all of, a showerhead has burned off.

  14. Absorptive Recycle of Distillation Waste Heat 

    E-Print Network [OSTI]

    Erickson, D. C.; Lutz, E. J., Jr.

    1982-01-01

    condenser operates above ambient temperature, the rejected heat also contains unused availability. By incorporating an absorption heat pump (AHP) into the distillation process, these sources of unused availability can be tapped so as to recycle (and hence...

  15. Energy Saving with Absorption Refrigeration Technologies 

    E-Print Network [OSTI]

    Davis, R. C.

    1984-01-01

    generally been overlooked by the process industry. This paper will address the application of the lithium bromide-water cycle in various energy saving modes. A waste heat powered absorption chiller producing chilled water can reduce energy consumption in a...

  16. Absorption Heat Pumps | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    an ammonia-water absorption cycle to provide heating and cooling. As in a standard heat pump, the refrigerant (in this case, ammonia) is condensed in one coil to release its...

  17. Absorption chillers: Part of the solution

    SciTech Connect (OSTI)

    Occhionero, A.J. (American Gas Cooling Center, Arlington, VA (United States)); Hughes, P.J. (Oak Ridge National Lab., TN (United States)); Reid, E.A. (Columbia Gas Distribution Co., Columbus, OH (United States))

    1991-01-01

    Acid rain, ozone depletion, global warming, and implementation economics are considered as they relate to the advisability of expanding the application of absorption chillers. Introductory and background information are provided to put the discussion in the proper context. Then all four issues are discussed separately as they relate to absorption chillers. Acid rain and ozone depletion concerns, and implementation economics, are found to support the expanded use of absorption chillers. The global warming concern is found to be more of a gray area, but the areas of benefit correspond well with the conditions of greatest economic advantage. All things considered, absorption chillers are believed to be part of the environmental and economic solution. It is further believed that integrated resource planning (IRP) processes that consider electric and gas technologies on an equal footing would come to the same conclusion for many regions of the United States. 9 refs., 3 tabs.

  18. Absorption Heat Pumping- Have You Tried It? 

    E-Print Network [OSTI]

    Davis, R. C.

    1985-01-01

    The concept of a thermal powered absorption heat pump is not a new or revolutionary idea. It has been successfully demonstrated in the lab and prototypes have been installed in the field. Units have been successfully applied in a number...

  19. PROMINENCE PLASMA DIAGNOSTICS THROUGH EXTREME-ULTRAVIOLET ABSORPTION

    SciTech Connect (OSTI)

    Landi, E.; Reale, F.

    2013-07-20

    In this paper, we introduce a new diagnostic technique that uses EUV and UV absorption to determine the electron temperature and column emission measure, as well as the He/H relative abundance of the absorbing plasma. If a realistic assumption on the geometry of the latter can be made and a spectral code such as CHIANTI is used, then this technique can also yield the absorbing plasma hydrogen and electron density. This technique capitalizes on the absorption properties of hydrogen and helium at different wavelength ranges and temperature regimes. Several cases where this technique can be successfully applied are described. This technique works best when the absorbing plasma is hotter than 15,000 K. We demonstrate this technique on AIA observations of plasma absorption during a coronal mass ejection eruption. This technique can be easily applied to existing observations of prominences and cold plasmas in the Sun from almost all space missions devoted to the study of the solar atmosphere, which we list.

  20. Regional respiratory tract absorption of inhaled reactive gases

    SciTech Connect (OSTI)

    Miller, F.J.; Overton, J.H.; Kimbell, J.S.; Russell, M.L.

    1992-06-29

    Highly reactive gases present unique problems due to the number of factors which must be taken into account to determine regional respiratory tract uptake. The authors reviewed some of the physical, chemical, and biological factors that affect dose and that must be understood to interpret toxicological data, to evaluate experimental dosimetry studies, and to develop dosimetry models. Selected dosimetry experiments involving laboratory animals and humans were discussed, showing the variability and uptake according to animal species and respiratory tract region for various reactive gases. New experimental dosimetry approaches, such as those involving isotope ratio mass spectroscopy and cyclotron generation reactive gases, were discussed that offer great promise for improving the ability to study regional respiratory tract absorption of reactive gases. Various dosimetry modeling applications were discussed which demonstrate: the importance of airflow patterns for site-specific dosimetry in the upper respiratory tract, the influence of the anatomical model used to make inter- and intraspecies dosimetric comparisons, the influence of tracheobronchial path length on predicted dose curves, and the implications of ventilatory unit structure and volume on dosimetry and response. Collectively, these examples illustrate important aspects of regional respiratory tract absorption of inhaled reactive gases. Given the complex nature of extent and pattern of injury in the respiratory tract from exposure to reactive gases, understanding interspecies differences in the absorption of reactive gases will continue to be an important area for study.

  1. DNA Concentration By UV Spectrophotometry Measure Absorption

    E-Print Network [OSTI]

    Aris, John P.

    DNA Concentration By UV Spectrophotometry Measure Absorption: 1. Dilute DNA to 0.5 to 50 µg/ml in TE buffer or dH2O. Plan to use a quartz cuvette or a UV-transparent plastic (disposable) cuvette (1 2. Measure absorption at 260 nm (A260). Start by zeroing instrument with TE buffer or dH2O alone

  2. Spectroscopic study of low-temperature hydrogen absorption in...

    Office of Scientific and Technical Information (OSTI)

    Spectroscopic study of low-temperature hydrogen absorption in palladium Citation Details In-Document Search Title: Spectroscopic study of low-temperature hydrogen absorption in...

  3. Effects of hydrogen/deuterium absorption on the magnetic properties...

    Office of Scientific and Technical Information (OSTI)

    Effects of hydrogendeuterium absorption on the magnetic properties of CoPd multilayers Citation Details In-Document Search Title: Effects of hydrogendeuterium absorption on the...

  4. A Chandra Survey of Broad Absorption Line Quasars

    E-Print Network [OSTI]

    Paul J. Green; Thomas L. Aldcroft; Smita Mathur; Belinda J. Wilkes; Martin Elvis

    2001-05-21

    We have carried out a survey with the Chandra X-ray Observatory of a sample of 10 optically bright broad absorption line (BAL) QSOs. Eight out of ten sources are detected. The 6 brightest X-ray sources have only high ionization BALs (hiBALs), while the 4 faintest all show low ionization BALs (loBALs). We perform a combined spectral fit for hiBAL QSOs to determine the mean spectral parameters of this sample. We derive an underlying best-fit power-law slope Gamma=1.8+/-0.35, consistent with the mean slope for radio-quiet quasars from ASCA, but BALQSOs require a (restframe) absorbing column of 6.5e22, with a partial covering fraction of 80%. Removing the absorption component from our best-fit spectral model yields a range of alphaOX from 1.55 to 2.28. All 6 hiBAL QSOs have de-absorbed X-ray emission consistent with non-BAL QSOs of similar luminosity. The spectral energy distributions of the hiBAL QSOs - both the underlying power-law slope and alphaOX provide the first conclusive evidence that BALQSOs have appeared to be X-ray weak because of intrinsic absorption, and that their underlying emission is consistent with non-BAL QSOs. By contrast, removal of the best-fit absorption column detected in the hiBAL QSOs still leaves the 4 loBAL QSOs as unusually X-ray faint for their optical luminosities.

  5. Measuring optical absorption coefficient of pure water in UV using the integrating cavity absorption meter. 

    E-Print Network [OSTI]

    Wang, Ling

    2008-10-10

    that have been used for absorption in the visible and UV regions. 7 The most intuitive technique to measure absorption of water is the conventional transmission type measurement. Hulburt et. al. used a long path length tube of distilled pure water... deflection spectroscopy [26]. Because the optical absorption of water in the visible and UV regions is very low (less than 0.01 m-1 at its minimum), accurate measurements are difficult. Careful examination of measurement results shows...

  6. Image Charge Differential

    E-Print Network [OSTI]

    Weston, Ken

    Image Charge Differential Amplifier FT 0 Crude Oil Time (s) 543210 Frequency (kHz) m/z m q B f organic molecules such as heavy crude oils. Heavy crudes are some of the most complex organic mixtures found in nature. As the crude oil industry grows in size and demand for crude oil increases, techniques

  7. Functional gene screening in embryonic stem cell implicates Wnt antagonism in neural differentiation

    E-Print Network [OSTI]

    Aubert, Jerome; Dunstan, Hannah; Chambers, Ian; Smith, Austin G

    2002-01-01

    The multilineage differentiation capacity of mouse embryonic stem (ES) cells offers a potential testing platform for gene products that mediate mammalian lineage determination and cellular specialization. Identification ...

  8. Differential transimpedance amplifier circuit for correlated differential amplification

    SciTech Connect (OSTI)

    Gresham, Christopher A.; Denton, M. Bonner; Sperline, Roger P.

    2008-07-22

    A differential transimpedance amplifier circuit for correlated differential amplification. The amplifier circuit increase electronic signal-to-noise ratios in charge detection circuits designed for the detection of very small quantities of electrical charge and/or very weak electromagnetic waves. A differential, integrating capacitive transimpedance amplifier integrated circuit comprising capacitor feedback loops performs time-correlated subtraction of noise.

  9. Differential homogeneous immunosensor device

    DOE Patents [OSTI]

    Malmros, Mark K. (Newton, PA); Gulbinski, III, Julian (Jamison, PA)

    1990-04-10

    There is provided a novel method of testing for the presence of an analyte in a fluid suspected of containing the same. In this method, in the presence of the analyte, a substance capable of modifying certain characteristics of the substrate is bound to the substrate and the change in these qualities is measured. While the method may be modified for carrying out quantitative differential analyses, it eliminates the need for washing analyte from the substrate which is characteristic of prior art methods.

  10. Differentiation Self-renewal

    E-Print Network [OSTI]

    Glyde, Henry R.

    Off state Ras Ras­GAP PI3K ERK1 ERK2 Differentiation SC1 SC1 Self-renewal Ras On state GDP GTP N NN the kinase enzyme Figure 1 | Chemically induced stem-cell self-renewal. Chen et al.2 have discovered, which promotes stem-cell self-renewal. Activated Ras also switches on the enzymes ERK1 and ERK2, which

  11. Reionization and high-redshift galaxies: the view from quasar absorption lines

    E-Print Network [OSTI]

    Becker, George D; Lidz, Adam

    2015-01-01

    Determining when and how the first galaxies reionized the intergalactic medium (IGM) promises to shed light on both the nature of the first objects and the cosmic history of baryons. Towards this goal, quasar absorption lines play a unique role by probing the properties of diffuse gas on galactic and intergalactic scales. In this review we examine the multiple ways in which absorption lines trace the connection between galaxies and the IGM near the reionization epoch. We first describe how the Ly$\\alpha$ forest is used to determine the intensity of the ionizing ultraviolet background and the global ionizing emissivity budget. Critically, these measurements reflect the escaping ionizing radiation from all galaxies, including those too faint to detect directly. We then discuss insights from metal absorption lines into reionization-era galaxies and their surroundings. Current observations suggest a buildup of metals in the circumgalactic environments of galaxies over $z \\sim 6$ to 5, although changes in ionizati...

  12. Temperature differential detection device

    DOE Patents [OSTI]

    Girling, Peter M. (Allentown, PA)

    1986-01-01

    A temperature differential detection device for detecting the temperature differential between predetermined portions of a container wall is disclosed as comprising a Wheatstone bridge circuit for detecting resistance imbalance with a first circuit branch having a first elongated wire element mounted in thermal contact with a predetermined portion of the container wall, a second circuit branch having a second elongated wire element mounted in thermal contact with a second predetermined portion of a container wall with the wire elements having a predetermined temperature-resistant coefficient, an indicator interconnected between the first and second branches remote from the container wall for detecting and indicating resistance imbalance between the first and second wire elements, and connector leads for electrically connecting the wire elements to the remote indicator in order to maintain the respective resistance value relationship between the first and second wire elements. The indicator is calibrated to indicate the detected resistance imbalance in terms of a temperature differential between the first and second wall portions.

  13. Neutral hydrogen absorption towards Fast Radio Bursts

    E-Print Network [OSTI]

    Fender, Rob

    2015-01-01

    If Fast Radio Bursts (FRBs) are truly at astronomical, in particular cosmological, distances, they represent one of the most exciting discoveries in astrophysics of the past decade. However, the distance to FRBs has, to date, been estimated purely from their excess dispersion, and has not been corroborated by any independent means. In this paper we discuss the possibility of detecting neutral hydrogen absorption against FRBs both from spiral arms within our own galaxy, or from intervening extragalactic HI clouds. In either case a firm lower limit on the distance to the FRB would be established. Absorption against galactic spiral arms may already be detectable for bright low-latitude bursts with existing facilities, and should certainly be so by the Square Kilometre Array (SKA). Absorption against extragalactic HI clouds, which would confirm the cosmological distances of FRBs, should also be detectable with the SKA, and maybe also Arecibo. Quantitatively, we estimate that SKA1-MID should be able to detect extr...

  14. Plasmon absorption modulator systems and methods

    DOE Patents [OSTI]

    Kekatpure, Rohan Deodatta; Davids, Paul

    2014-07-15

    Plasmon absorption modulator systems and methods are disclosed. A plasmon absorption modulator system includes a semiconductor substrate, a plurality of quantum well layers stacked on a top surface of the semiconductor substrate, and a metal layer formed on a top surface of the stack of quantum well layers. A method for modulating plasmonic current includes enabling propagation of the plasmonic current along a metal layer, and applying a voltage across the stack of quantum well layers to cause absorption of a portion of energy of the plasmonic current by the stack of quantum well layers. A metamaterial switching system includes a semiconductor substrate, a plurality of quantum well layers stacked on a top surface of the semiconductor substrate, and at least one metamaterial structure formed on a top surface of the stack of quantum well layers.

  15. Dynamics of femtosecond laser absorption of fused silica in the ablation regime

    SciTech Connect (OSTI)

    Lebugle, M., E-mail: lebugle@lp3.univ-mrs.fr; Sanner, N.; Varkentina, N.; Sentis, M.; Utéza, O. [Aix Marseille Université, CNRS, LP3 UMR 7341, 13288 Marseille (France)

    2014-08-14

    We investigate the ultrafast absorption dynamics of fused silica irradiated by a single 500?fs laser pulse in the context of micromachining applications. A 60-fs-resolution pump-probe experiment that measures the reflectivity and transmissivity of the target under excitation is developed to reveal the evolution of plasma absorption. Above the ablation threshold, an overcritical plasma with highly non-equilibrium conditions is evidenced in a thin layer at the surface. The maximum electron density is reached at a delay of 0.5?ps after the peak of the pump pulse, which is a strong indication of the occurrence of electronic avalanche. The results are further analyzed to determine the actual feedback of the evolution of the optical properties of the material on the pump pulse. We introduce an important new quantity, namely, the duration of absorption of the laser by the created plasma, corresponding to the actual timespan of laser absorption by inverse Bremsstrahlung. Our results indicate an increasing contribution of plasma absorption to the total material absorption upon raising the excitation fluence above the ablation threshold. The role of transient optical properties during the energy deposition stage is characterized and our results emphasize the necessity to take it into account for better understanding and control of femtosecond laser-dielectrics interaction.

  16. Thermal emission and absorption of radiation in finite inverted-opal photonic crystals

    SciTech Connect (OSTI)

    Florescu, Marian; Stimpson, Andrew J.; Lee, Hwang; Dowling, Jonathan

    2005-09-15

    We study theoretically the optical properties of a finite inverted-opal photonic crystal. The light-matter interaction is strongly affected by the presence of the three-dimensional photonic crystal and the alterations of the light emission and absorption processes can be used to suppress or enhance the thermal emissivity and absorptivity of the dielectric structure. We investigate the influence of the absorption present in the system on the relevant band edge frequencies that control the optical response of the photonic crystal. Our study reveals that the absorption processes cause spectral broadening and shifting of the band edge optical resonances, and determine a strong reduction of the photonic band gap spectral range. Using the angular and spectral dependence of the band edge frequencies for stop bands along different directions, we argue that by matching the blackbody emission spectrum peak with a prescribed maximum of the absorption coefficient, it is possible to achieve an angle-sensitive enhancement of the thermal emission/absorption of radiation. This result opens a way to realize a frequency-sensitive and angle-sensitive photonic crystal absorbers/emitters.

  17. Multi-plasmon absorption in graphene

    E-Print Network [OSTI]

    Marinko Jablan; Darrick E. Chang

    2015-01-21

    We show that graphene possesses a strong nonlinear optical response in the form of multi-plasmon absorption, with exciting implications in classical and quantum nonlinear optics. Specifically, we predict that graphene nano-ribbons can be used as saturable absorbers with low saturation intensity in the far-infrared and terahertz spectrum. Moreover, we predict that two-plasmon absorption and extreme localization of plasmon fields in graphene nano-disks can lead to a plasmon blockade effect, in which a single quantized plasmon strongly suppresses the possibility of exciting a second plasmon.

  18. Absorption and scattering in ground-penetrating radar: Analysis of the Bishop Tuff

    E-Print Network [OSTI]

    Grimm, Robert E.

    coefficients were computed from profiles that showed distributed scattering: the semilogarithmic signal decay is directly analogous to seismic coda. The absorption (intrinsic loss) was determined to be $1 dB/m from low- frequency vertical-electric soundings. The residual attenuation (that is, the attenuation in the absence

  19. Corrosion inhibitor for aqueous ammonia absorption system

    DOE Patents [OSTI]

    Phillips, B.A.; Whitlow, E.P.

    1998-09-22

    A method is described for inhibiting corrosion and the formation of hydrogen and thus improving absorption in an ammonia/water absorption refrigeration, air conditioning or heat pump system by maintaining the hydroxyl ion concentration of the aqueous ammonia working fluid within a selected range under anaerobic conditions at temperatures up to 425 F. This hydroxyl ion concentration is maintained by introducing to the aqueous ammonia working fluid an inhibitor in an amount effective to produce a hydroxyl ion concentration corresponding to a normality of the inhibitor relative to the water content ranging from about 0.015 N to about 0.2 N at 25 C. Also, working fluids for inhibiting the corrosion of carbon steel and resulting hydrogen formation and improving absorption in an ammonia/water absorption system under anaerobic conditions at up to 425 F. The working fluids may be aqueous solutions of ammonia and a strong base or aqueous solutions of ammonia, a strong base, and a specified buffer. 5 figs.

  20. Coupled dual loop absorption heat pump

    DOE Patents [OSTI]

    Sarkisian, Paul H. (Watertown, MA); Reimann, Robert C. (Lafayette, NY); Biermann, Wendell J. (Fayetteville, NY)

    1985-01-01

    A coupled dual loop absorption system which utilizes two separate complete loops. Each individual loop operates at three temperatures and two pressures. This low temperature loop absorber and condenser are thermally coupled to the high temperature loop evaporator, and the high temperature loop condenser and absorber are thermally coupled to the low temperature generator.

  1. Corrosion inhibitor for aqueous ammonia absorption system

    DOE Patents [OSTI]

    Phillips, Benjamin A. (Benton Harbor, MI); Whitlow, Eugene P. (St. Joseph, MI)

    1998-09-22

    A method of inhibiting corrosion and the formation of hydrogen and thus improving absorption in an ammonia/water absorption refrigeration, air conditioning or heat pump system by maintaining the hydroxyl ion concentration of the aqueous ammonia working fluid within a selected range under anaerobic conditions at temperatures up to 425.degree. F. This hydroxyl ion concentration is maintained by introducing to the aqueous ammonia working fluid an inhibitor in an amount effective to produce a hydroxyl ion concentration corresponding to a normality of the inhibitor relative to the water content ranging from about 0.015 N to about 0.2 N at 25.degree. C. Also, working fluids for inhibiting the corrosion of carbon steel and resulting hydrogen formation and improving absorption in an ammonia/water absorption system under anaerobic conditions at up to 425.degree. F. The working fluids may be aqueous solutions of ammonia and a strong base or aqueous solutions of ammonia, a strong base, and a specified buffer.

  2. ABSORPTION HEAT PUMP IN THE DISTRICT HEATING

    E-Print Network [OSTI]

    Oak Ridge National Laboratory

    #12;ABSORPTION HEAT PUMP IN THE DISTRICT HEATING PLANT Dr.sc.ing. Agnese Lickrastina M.Sc. Normunds European Heat Pump Summit 2013, Nuremberg, 15-16.10.2013 · Riga District Heating company · Operation of the DH plant Imanta · Selection of the heat pump/chiller · Operation of the heat pump/chiller · Summary

  3. Polymer microcantilevers fabricated via multiphoton absorption polymerization

    E-Print Network [OSTI]

    Teich, Malvin C.

    Polymer microcantilevers fabricated via multiphoton absorption polymerization Z. Bayindir, Y. Sun polymer cantilevers. Atomic force microscopy has been used to characterize the mechanical properties orders of magnitude smaller than would be predicted from the properties of the bulk polymer.6 If correct

  4. Absorption of solar radiation by solar neutrinos

    E-Print Network [OSTI]

    G. Duplancic; P. Minkowski; J. Trampetic

    2004-03-22

    We calculate the absorption probability of photons radiated from the surface of the Sun by a left-handed neutrino with definite mass and a typical momentum for which we choose |p_1|=0.2 MeV, producing a heavier right-handed antineutrino. Considering two transitions the \

  5. Differential homogeneous immunosensor device

    DOE Patents [OSTI]

    Malmros, M.K.; Gulbinski, J. III.

    1990-04-10

    There is provided a novel method of testing for the presence of an analyte in a fluid suspected of containing the same. In this method, in the presence of the analyte, a substance capable of modifying certain characteristics of the substrate is bound to the substrate and the change in these qualities is measured. While the method may be modified for carrying out quantitative differential analyses, it eliminates the need for washing the analyte from the substrate which is characteristic of prior art methods. 12 figs.

  6. Quantitative broadband absorption and scattering spectroscopy in turbid media by combined frequency-domain and steady state methodologies

    DOE Patents [OSTI]

    Tromberg, Bruce J. (Irvine, CA); Berger, Andrew J. (Rochester, NY); Cerussi, Albert E. (Lake Forest, CA); Bevilacqua, Frederic (Costa Mesa, CA); Jakubowski, Dorota (Irvine, CA)

    2008-09-23

    A technique for measuring broadband near-infrared absorption spectra of turbid media that uses a combination of frequency-domain and steady-state reflectance methods. Most of the wavelength coverage is provided by a white-light steady-state measurement, whereas the frequency-domain data are acquired at a few selected wavelengths. Coefficients of absorption and reduced scattering derived from the frequency-domain data are used to calibrate the intensity of the steady-state measurements and to determine the reduced scattering coefficient at all wavelengths in the spectral window of interest. The absorption coefficient spectrum is determined by comparing the steady-state reflectance values with the predictions of diffusion theory, wavelength by wavelength. Absorption spectra of a turbid phantom and of human breast tissue in vivo, derived with the combined frequency-domain and steady-state technique, agree well with expected reference values.

  7. Absolute Earthquake Locations with Differential Data By William Menke and David Schaff

    E-Print Network [OSTI]

    Menke, William

    Absolute Earthquake Locations with Differential Data By William Menke and David Schaff Lamont the commonly-held wisdom that "you can't determine the absolute location of earthquakes using the double differential arrival time data can, in principle, be used to determine the absolute locations of earthquakes

  8. Mapping the Dynamics of Cold Gas around Sgr A* through 21 cm Absorption

    E-Print Network [OSTI]

    Christian, Pierre

    2015-01-01

    The presence of a circumnuclear stellar disk around Sgr A* and megamaser systems near other black holes indicates that dense neutral disks can be found in galactic nuclei. We show that depending on their inclination angle, optical depth, and spin temperature, these disks could be observed spectroscopically through 21 cm absorption. Related spectroscopic observations of Sgr A* can determine its HI disk parameters and the possible presence of gaps in the disk. Clumps of dense gas similar to the G2 could could also be detected in 21 cm absorption against the Sgr A* radio emission.

  9. Absorption probability of neutrino fields and Hawking radiation

    E-Print Network [OSTI]

    Koray Düzta?

    2015-05-14

    We analyse the scattering of neutrino fields (massless spin 1/2 fields) from Kerr black holes. Adopting the notation of Teukolsky and Press, we derive the connection relation between the normalizations of ingoing and outgoing waves at the horizon and at infinity. It turns out that the connection relation for neutrino waves neither depends on the frequency $\\omega$ and angular momentum quantum numbers $l,m$ of the wave, nor on the black hole parameters $M,a$. As a result of that the absorption probability of neutrino fields $\\Gamma_{lm}(\\omega)$ which determines the average number of neutrinos emitted in the mode $(\\omega,l,m)$ in Hawking radiation, does not explicitly depend on the frequency $\\omega$ and angular momentum quantum numbers $l,m$. The form of $\\Gamma$ only in terms of Teukolsky's normalizations at infinity and at the horizon is derived. This is another aspect in which neutrino fields are essentially different than bosonic fields. The independence of the absorption probability of all parameters, also implies a violation of cosmic censorship since an extremal Kerr black hole can absorb modes carrying less energy than angular momentum. This is in accord with a recent work of the author evaluating the classical interaction of Kerr black holes with neutrino fields.

  10. THE ABSORPTION OF HYDROGEN ON LOW PRESSURE HYDRIDE MATERIALS

    SciTech Connect (OSTI)

    Morgan, G.; Korinko, P.

    2012-04-03

    For this study, hydrogen getter materials (Zircaloy-4 and pure zirconium) that have a high affinity for hydrogen (and low overpressure) have been investigated to determine the hydrogen equilibrium pressure on Zircaloy-4 and pure zirconium. These materials, as with most getter materials, offered significant challenges to overcome given the low hydrogen equilibrium pressure for the temperature range of interest. Hydrogen-zirconium data exists for pure zirconium at 500 C and the corresponding hydrogen overpressure is roughly 0.01 torr. This manuscript presents the results of the equilibrium pressures for the absorption and desorption of hydrogen on zirconium materials at temperatures ranging from 400 C to 600 C. The equilibrium pressures in this temperature region range from 150 mtorr at 600 C to less than 0.1 mtorr at 400 C. It has been shown that the Zircaloy-4 and zirconium samples are extremely prone to surface oxidation prior to and during heating. This oxidation precludes the hydrogen uptake, and therefore samples must be heated under a minimum vacuum of 5 x 10{sup -6} torr. In addition, the Zircaloy-4 samples should be heated at a sufficiently low rate to maintain the system pressure below 0.5 mtorr since an increase in pressure above 0.5 mtorr could possibly hinder the H{sub 2} absorption kinetics due to surface contamination. The results of this study and the details of the testing protocol will be discussed.

  11. Hydrogen Absorption in Pd-based Nanostructures - Final Report

    SciTech Connect (OSTI)

    David Lederman

    2012-10-22

    Pd is known to absorb hydrogen. Molecules are normally chemisorbed at the surface in a process where the molecule breaks into two hydrogen atoms, and the protons are then absorbed into the bulk. This process consists of electron filling holes in the Pd 4d band near the Fermi energy, which due to the high density of states at the Fermi energy, is an energetically favorable process. Our aim with this project was to determine possible changes in magnetic properties with Pd nm-length-scale thick layers intercalated by magnetic materials. Before the start of this work, the literature indicated that there were several possible scenarios by which this could happen: i) the Pd will be magnetized due to a proximity effect with nearby magnetic layers, resulting in changes in the magnetization due to H2 absorption; ii) some H will be absorbed into the magnetic layers, causing a change in the magnetic exchange interactions; or iii) absorption of H2 will cause an expansion of the lattice, resulting in a magnetoelastic effect which changes the magnetic properties.

  12. Integrated vacuum absorption steam cycle gas separation

    DOE Patents [OSTI]

    Chen, Shiaguo (Champaign, IL); Lu, Yonggi (Urbana, IL); Rostam-Abadi, Massoud (Champaign, IL)

    2011-11-22

    Methods and systems for separating a targeted gas from a gas stream emitted from a power plant. The gas stream is brought into contact with an absorption solution to preferentially absorb the targeted gas to be separated from the gas stream so that an absorbed gas is present within the absorption solution. This provides a gas-rich solution, which is introduced into a stripper. Low pressure exhaust steam from a low pressure steam turbine of the power plant is injected into the stripper with the gas-rich solution. The absorbed gas from the gas-rich solution is stripped in the stripper using the injected low pressure steam to provide a gas stream containing the targeted gas. The stripper is at or near vacuum. Water vapor in a gas stream from the stripper is condensed in a condenser operating at a pressure lower than the stripper to concentrate the targeted gas. Condensed water is separated from the concentrated targeted gas.

  13. Radiation absorption properties of different plaster samples

    SciTech Connect (OSTI)

    Akkurt, Iskender; Guenoglu, Kadir; Mavi, Betuel; K Latin-Small-Letter-Dotless-I l Latin-Small-Letter-Dotless-I ncarslan, Semsettin; Seven, Aysun

    2012-09-06

    Although the plaster is one of the oldest known synthetic building materials, nowadays, it is used as interior coating of walls and ceilings of buildings. Thus measuring its radiation shielding properties is vital. For this purpose, radiation absorption properties of different plaster samples in this study. The measurements have been performed using gamma spectrometer system which connected to 3'' Multiplication-Sign 3''NaI (TI) detector.

  14. Simultaneous photon absorption as a probe of molecular interaction and hydrogen-bond correlation in liquids

    E-Print Network [OSTI]

    Sander Woutersen

    2007-03-06

    We have investigated the simultaneous absorption of near-infrared photons by pairs of neighboring molecules in liquid methanol. Simultaneous absorption by two OH-stretching modes is found to occur at an energy higher than the sum of the two absorbing modes. This frequency shift arises from interaction between the modes, and its value has been used to determine the average coupling between neighboring methanol molecules. We find a rms coupling strength of 46+/-1 cm-1, much larger than can be explained from transition-dipole coupling, suggesting that hydrogen-bond mediated interactions between neighboring molecules play an important role in liquid methanol. The most important aspect of simultaneous vibrational absorption is that it allows for a quantitative investigation of hydrogen-bond cooperativity. We derive the extent to which the hydrogen-bond strengths of neighboring molecules are correlated by comparing the line shape of the absorption band caused by simultaneous absorption with that of the fundamental transition. Surprisingly, neighboring hydrogen bonds in methanol are found to be strongly correlated, and from the data we obtain a hydrogen-bond correlation coefficient of 0.69+/-0.12.

  15. A Computational Model for Sound Field Absorption by Acoustic Arrays

    E-Print Network [OSTI]

    . We then formulate the acoustic wave equation with the absorption boundary coeÆcient in the frequency the sound absorption property of arrays of micro-acoustic actuators at a control surface. We use the waveA Computational Model for Sound Field Absorption by Acoustic Arrays H. T. Banks #3; D. G. Cole z K

  16. Split-flow regeneration in absorptive air separation

    DOE Patents [OSTI]

    Weimer, R.F.

    1987-11-24

    A chemical absorptive separation of air in multiple stage of absorption and desorption is performed with partial recycle of absorbent between stages of desorption necessary to match equilibrium conditions in the various stages of absorption. This allows reduced absorbent flow, reduced energy demand and reduced capital costs. 4 figs.

  17. Chukwuemeka I. Okoye Carbon Dioxide Solubility and Absorption Rate in

    E-Print Network [OSTI]

    Rochelle, Gary T.

    Copyright by Chukwuemeka I. Okoye 2005 #12;Carbon Dioxide Solubility and Absorption Rate _______________________ Nicholas A. Peppas #12;Carbon Dioxide Solubility and Absorption Rate in Monoethanolamine/Piperazine/H2O for. #12;iii Carbon Dioxide Solubility and Absorption Rate in Monoethanolamine/Piperazine/H2O

  18. Quantum of optical absorption in two-dimensional semiconductors

    E-Print Network [OSTI]

    California at Berkeley, University of

    . Absorptance quantization appears to be universal in 2D systems including III­V quantum wells and graphene quantitative examination of the intrinsic absorption properties of free-standing 2D semiconductor thin films work has shown that graphene, a 2D semimetal, has a universal value of light absorption, namely , where

  19. Split-flow regeneration in absorptive air separation

    DOE Patents [OSTI]

    Weimer, Robert F. (Allentown, PA)

    1987-01-01

    A chemical absorptive separation of air in multiple stage of absorption and desorption is performed with partial recycle of absorbent between stages of desorption necessary to match equilibrium conditions in the various stages of absorption. This allows reduced absorbent flow, reduced energy demand and reduced capital costs.

  20. Improvement of the Performance for an Absorption Refrigeration System with Lithium bromide-water as Refrigerant by Increasing Absorption Pressure 

    E-Print Network [OSTI]

    Xie, G.; Sheng, G.; Li, G.; Pan, S.

    2006-01-01

    , the low COP of the absorption machine was limited seriously to compete with the refrigeration machine that is drove by electricity. Therefore, most researchers focus their attention on the improvement of performance of the absorption system through many...

  1. Geometric Differential Evolution Alberto Moraglio

    E-Print Network [OSTI]

    Togelius, Julian

    formal generalization of traditional Par- ticle Swarm Optimization (PSO) that applies naturally to both continuous and combinatorial spaces. Differential Evo- lution (DE) is similar to PSO but it uses different for the traditional PSO algorithm. Using this formal algorithm, Geometric Differential Evolution (GDE), we formally

  2. Absorption of solar radiation by the cloudy atmosphere: Further interpretations of collocated aircraft measurements

    E-Print Network [OSTI]

    1999-01-01

    J. Vitko Jr. , Absorption of solar radiation by the cloudyet al. , Absorption of solar radiation by clouds: Observa-1999 Absorption of solar radiation by the cloudy atmosphere:

  3. Ammonia and ammonium hydroxide sensors for ammonia/water absorption machines: Literature review and data compilation

    SciTech Connect (OSTI)

    Anheier, N.C. Jr.; McDonald, C.E.; Cuta, J.M.; Cuta, F.M.; Olsen, K.B.

    1995-05-01

    This report describes an evaluation of various sensing techniques for determining the ammonia concentration in the working fluid of ammonia/water absorption cycle systems. The purpose of this work was to determine if any existing sensor technology or instrumentation could provide an accurate, reliable, and cost-effective continuous measure of ammonia concentration in water. The resulting information will be used for design optimization and cycle control in an ammonia-absorption heat pump. PNL researchers evaluated each sensing technology against a set of general requirements characterizing the potential operating conditions within the absorption cycle. The criteria included the physical constraints for in situ operation, sensor characteristics, and sensor application. PNL performed an extensive literature search, which uncovered several promising sensing technologies that might be applicable to this problem. Sixty-two references were investigated, and 33 commercial vendors were identified as having ammonia sensors. The technologies for ammonia sensing are acoustic wave, refractive index, electrode, thermal, ion-selective field-effect transistor (ISFET), electrical conductivity, pH/colormetric, and optical absorption. Based on information acquired in the literature search, PNL recommends that follow-on activities focus on ISFET devices and a fiber optic evanescent sensor with a colormetric indicator. The ISFET and fiber optic evanescent sensor are inherently microminiature and capable of in situ measurements. Further, both techniques have been demonstrated selective to the ammonium ion (NH{sub 4}{sup +}). The primary issue remaining is how to make the sensors sufficiently corrosion-resistant to be useful in practice.

  4. 44th Annual Anomalous Absorption Conference

    SciTech Connect (OSTI)

    Beg, Farhat

    2014-03-03

    Conference Grant Report July 14, 2015 Submitted to the U. S. Department of Energy Attn: Dr. Sean Finnegan By the University of California, San Diego 9500 Gilman Drive La Jolla, California 92093 On behalf of the 44th Annual Anomalous Absorption Conference 8-13 June 2014, in Estes Park, Colorado Support Requested: $10,100 Amount expended: $3,216.14 Performance Period: 1 March 20 14 to 28 February 20 15 Principal Investigator Dr. Farhat Beg Center for Energy Research University of California, San Diego 9500 Gilman Drive La Jolla, California 92093-0417 858-822-1266 (telephone) 858-534-4543 (fax) fbeg@ucsd.edu Administrative Point of Contact: Brandi Pate, 858-534-0851, blpate®ucsd.edu I. Background The forty-fourth Anomalous Absorption Conference was held in Estes Park, Colorado from June 5-8, 2014 (aac2014.ucsd.edu). The first Anomalous Absorption Conference was held in 1971 to assemble experts in the poorly understood area of laser-plasma absorption. The goal of that conference was to address the anomalously large laser absorption seen in plasma experiments with respect to the laser absorption predicted by linear plasma theory. Great progress in this research area has been made in the decades since that first meeting, due in part to the scientific interactions that have occurred annually at this conference. Specifically, this includes the development of nonlinear laser-plasma theory and the simulation of laser interactions with plasmas. Each summer since that first meeting, this week-long conference has been held at unique locations in North America as a scientific forum for intense scientific exchanges relevant to the interaction of laser radiation with plasmas. Responsibility for organizing the conference has traditional rotated each year between the major Inertial Confinement Fusion (ICF) laboratories and universities including LANL, LLNL, LLE, UCLA UC Davis and NRL. As the conference has matured over the past four decades, its technical footprint has expanded beyond ICF-related laser-plasma interactions to encompass closely related technical areas including laser particle acceleration, high-intensity laser effects, short­ pulse laser interactions, PIC and Vlasov/rad-hydro modeling, inertial and magnetic fusion plasmas, advanced plasma diagnostics, alternate ignition schemes, EOS/transport/opacity, and this year, x­ ray free-electron lasers and their applications. The conference continues to be a showcase for the presentation and discussion of the latest developments in these areas. II. Meeting Report The conference was extremely successful with more than one hundred participants. There were ninety-nine (99) abstracts submitted. There were forty-four (44) presentations including eleven (11) invited talks. The following topics were covered: a) Radiation Hydrodynamics b) Implosion Plasma Kinetic Effects c) Alternate Ignition Schemes d) Astrophysical Phenomena e) Opacity/Transport/EOS f) High Power Lasers and Facilities g) High-Intensity Laser-Matter Interactions h) Hydrodynamics and Hydro-instabilities i) Hot Dense Plasma Atomic Processes j) High Energy Density Physics k) Laser Particle Acceleration Physics l) Advanced Plasma Diagnostics m) Advanced light sources and applications Despite significant advertising, there were two students who applied for the travel grants: Charlie Jarrott and Joohwan Kim. The total funds expended were $3,216.14.

  5. Distributed Bragg Reflectors With Reduced Optical Absorption

    DOE Patents [OSTI]

    Klem, John F. (Albuquerque, NM)

    2005-08-16

    A new class of distributed Bragg reflectors has been developed. These distributed Bragg reflectors comprise interlayers positioned between sets of high-index and low-index quarter-wave plates. The presence of these interlayers is to reduce photon absorption resulting from spatially indirect photon-assisted electronic transitions between the high-index and low-index quarter wave plates. The distributed Bragg reflectors have applications for use in vertical-cavity surface-emitting lasers for use at 1.55 .mu.m and at other wavelengths of interest.

  6. Absorption Cooling Basics | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i n c i p a l De p u t y A s sconveyance(EPACT 2005) and the EnergyAbsorption

  7. Revision of absorption corrections for the $p p \\to p p ?^{+} ?^{-}$ process

    E-Print Network [OSTI]

    Piotr Lebiedowicz; Antoni Szczurek

    2015-05-11

    We include new additional absorption corrections into the Lebiedowicz-Szczurek (non-resonant) model for $p p \\to p p \\pi^+ \\pi^-$ or $p \\bar p \\to p \\bar p \\pi^+ \\pi^-$ processes. They are related to the $\\pi N$ nonperturbative interaction in the final state of the reaction. The role of the absorption corrections is quantified for several differential distributions for $\\sqrt{s}$ = 0.2, 1.96, 7, and 8 TeV. The new absorption corrections lead to further decrease of the cross section by about a factor of two. They change the shape of some distributions ($d \\sigma / dt$, $d \\sigma / dp_{t,p}$, $d \\sigma/d \\phi_{pp}$) but leave almost unchanged shape of other distributions ($d \\sigma / dM_{\\pi \\pi}$, $d \\sigma / dy_{\\pi}$, $d \\sigma /dp_{t,\\pi}$, $d \\sigma/ d \\phi_{\\pi \\pi}$). The effect may have important impact on the interpretation of the recent STAR and CDF data as well as the forthcoming data of the ALICE, ATLAS + ALFA and CMS + TOTEM collaborations.

  8. Method and apparatus for measuring butterfat and protein content using microwave absorption techniques

    DOE Patents [OSTI]

    Fryer, Michael O. (Roberts, ID); Hills, Andrea J. (Iowa City, IA); Morrison, John L. (Idaho Falls, ID)

    2000-01-01

    A self calibrating method and apparatus for measuring butterfat and protein content based on measuring the microwave absorption of a sample of milk at several microwave frequencies. A microwave energy source injects microwave energy into the resonant cavity for absorption and reflection by the sample undergoing evaluation. A sample tube is centrally located in the resonant cavity passing therethrough and exposing the sample to the microwave energy. A portion of the energy is absorbed by the sample while another portion of the microwave energy is reflected back to an evaluation device such as a network analyzer. The frequency at which the reflected radiation is at a minimum within the cavity is combined with the scatter coefficient S.sub.11 as well as a phase change to calculate the butterfat content in the sample. The protein located within the sample may also be calculated in a likewise manner using the frequency, S.sub.11 and phase variables. A differential technique using a second resonant cavity containing a reference standard as a sample will normalize the measurements from the unknown sample and thus be self-calibrating. A shuttered mechanism will switch the microwave excitation between the unknown and the reference cavities. An integrated apparatus for measuring the butterfat content in milk using microwave absorption techniques is also presented.

  9. Nash equilibrium in differential games and the construction of the programmed iteration method

    SciTech Connect (OSTI)

    Averboukh, Yurii V [Institute of Mathematics and Mechanics, Urals Branch of the Russian Academy of Sciences, Ekaterinburg (Russian Federation)

    2011-05-31

    This work is devoted to the study of nonzero-sum differential games. The set of payoffs in a situation of Nash equilibrium is examined. It is shown that the set of payoffs in a situation of Nash equilibrium coincides with the set of values of consistent functions which are fixed points of the program absorption operator. A condition for functions to be consistent is given in terms of the weak invariance of the graph of the functions under a certain differential inclusion. Bibliography: 18 titles.

  10. Effect of vitrification temperature upon the solar average absorptance properties of Pyromark Series 2500 black paint

    SciTech Connect (OSTI)

    Nelson, C.; Mahoney, A.R.

    1986-06-01

    A significant drop in production efficiency has occurred over time at the Solar One facility at Barstow, California, primarily as a result of the degradation of the Pyromark Series 2500 black paint used as the absorptive coating on the receiver panels. As part of the investigation of the problem, the solar-averaged adsorptance properties of the paint were determined as a function of vitrification temperature, since it is known that a significant amount of the panel surface area at Solar One was vitrified at temperatures below those recommended by the paint manufacturer (540/sup 0/C, 1000/sup 0/F). Painted samples initially vitrified at 230/sup 0/C (450/sup 0/F), 315/sup 0/C (600/sup 0/F), 371/sup 0/C (700/sup 0/F), and 480/sup 0/C (900/sup 0/F) exhibited significantly lower solar-averaged absorptance values (0.02 absorptance units) compared to samples vitrified at 540/sup 0/C (1000/sup 0/F). Thus, Solar One began its service life below optimal levels. After 140 h of thermal aging at 370/sup 0/C (700/sup 0/F) and 540/sup 0/C (1000/sup 0/F), all samples regardless of their initial vitrification temperatures, attained the same solar-averaged absorptance value (..cap alpha../sub s/ = 0.973). Therefore, both the long-term low-temperature vitrification and the short-term high-temperature vitrification can be used to obtain optimal or near-optimal absorptance of solar flux. Futher thermal aging of vitrified samples did not result in paint degradation, clearly indicating that high solar flux is required to produce this phenomenon. The panels at Solar One never achieved optimal absorptance because their exposure to high solar flux negated the effect of long-term low-temperature vitrification during operation. On future central receiver projects, every effort should be made to properly vitrify the Pyromark coating before its exposure to high flux conditions.

  11. NON-DIFFERENTIABLE EMBEDDING OF LAGRANGIAN SYSTEMS AND PARTIAL DIFFERENTIAL EQUATIONS

    E-Print Network [OSTI]

    NON-DIFFERENTIABLE EMBEDDING OF LAGRANGIAN SYSTEMS AND PARTIAL DIFFERENTIAL EQUATIONS by Jacky-differentiable embedding of Lagrangian systems and coherence principle . . . . . . . . 16 1. Non-differentiable embedding Euler du 17 Mai 1756 Abstract. -- We develop the non-differentiable embedding theory of differential

  12. Viral oncogenesis and cell differentiation

    SciTech Connect (OSTI)

    Diamond, L.; Wolman, S.R.

    1989-01-01

    This book covers the following topics: Retroviruses, Human lymphotropic viruses, Oncogenes, Hematopoiesis: Normal and Abnormal, Growth and differentiation of normal and malignant cells, Molecular and genetic control of cell proliferation.

  13. Total absorption {gamma}-ray spectroscopy of beta delayed neutron emitters

    SciTech Connect (OSTI)

    Valencia, E.; Algora, A.; Tain, J. L.; Agramunt, J.; Jordan, M. D.; Molina, F.; Estevez, E.; Rubio, B.; Perez, A. [IFIC, CSIC - Univ. Valencia, Valencia (Spain); Rice, S.; Bowry, M.; Gelletly, W.; Podolyak, Zs.; Regan, P. H.; Farrelly, G. F. [Univ. Surrey, Guildford (United Kingdom); Zakari-Issoufou, A.-A.; Porta, A.; Fallot, M.; Bui, V. M. [Subatech, CNRS/INP2P3, Nantes, EMN, Nantes (France); Caballero-Folch, R. [Univ. Pol. Catalunya, Barcelona (Spain); and others

    2013-06-10

    Preliminary results of the data analysis of the beta decay of {sup 94}Rb using a novel - segmented- total absorption spectrometer are shown in this contribution. This result is part of a systematic study of important contributors to the decay heat problem in nuclear reactors. In this particular case the goal is to determine the beta intensity distribution below the neutron separation energy and the gamma/beta competition above.

  14. GNSS Spoofing Detection using Two-Antenna Differential Carrier Phase

    E-Print Network [OSTI]

    Psiaki, Mark L.

    GNSS Spoofing Detection using Two-Antenna Differential Carrier Phase Mark L. Psiaki, Brady W. O'Hanlon, Sea ID, 06320, Cap d'Ail, France BIOGRAPHIES Mark L. Psiaki is a Professor of Mechanical and Aerospace, spacecraft attitude and orbit determination, and general estimation, filtering, and detection. Brady W. O'Hanlon

  15. Galactic Scale Absorption Outflow in the Low Luminosity Quasar IRAS~F04250-5718: HST/COS Observations

    E-Print Network [OSTI]

    Edmonds, Doug; Arav, Nahum; Dunn, Jay P; Penton, Steve; Kriss, Gerard A; Korista, Kirk; Costantini, Elisa; Steenbrugge, Katrien; Gonzalez-Serrano, J Ignacio; Aoki, Kentaro; Bautista, Manuel; Behar, Ehud; Benn, Chris; Crenshaw, D Micheal; Everett, John; Gabel, Jack; Kaastra, Jelle; Moe, Maxwell; Scott, Jennifer

    2011-01-01

    We present absorption line analysis of the outflow in the quasar IRAS F04250-5718. Far-ultraviolet data from the Cosmic Origins Spectrograph onboard the Hubble Space Telescope reveal intrinsic narrow absorption lines from high ionization ions (e.g., C IV, N V, and O VI) as well as low ionization ions (e.g., C II and Si III). We identify three kinematic components with central velocities ranging from ~-50 to ~-230 km/s. Velocity dependent, non-black saturation is evident from the line profiles of the high ionization ions. From the non-detection of absorption from a metastable level of C II, we are able to determine that the electron number density in the main component of the outflow is 3 kpc. Due to the large distance determined for the main kinematic component, we discuss the possibility that this outflow is part of a galactic wind.

  16. Ash Determinations 

    E-Print Network [OSTI]

    Unknown

    2011-08-17

    Germination of Ashe juniper seed were compared in a controlled environment at different levels of fruit maturation, lengths of storage, and seed stratification to determine potential germination. Annual mean germination varied by an order...

  17. Enhanced light absorption of solar cells and photodetectors by diffraction

    DOE Patents [OSTI]

    Zaidi, Saleem H.; Gee, James M.

    2005-02-22

    Enhanced light absorption of solar cells and photodetectors by diffraction is described. Triangular, rectangular, and blazed subwavelength periodic structures are shown to improve performance of solar cells. Surface reflection can be tailored for either broadband, or narrow-band spectral absorption. Enhanced absorption is achieved by efficient optical coupling into obliquely propagating transmitted diffraction orders. Subwavelength one-dimensional structures are designed for polarization-dependent, wavelength-selective absorption in solar cells and photodetectors, while two-dimensional structures are designed for polarization-independent, wavelength-selective absorption therein. Suitable one and two-dimensional subwavelength periodic structures can also be designed for broadband spectral absorption in solar cells and photodetectors. If reactive ion etching (RIE) processes are used to form the grating, RIE-induced surface damage in subwavelength structures can be repaired by forming junctions using ion implantation methods. RIE-induced surface damage can also be removed by post RIE wet-chemical etching treatments.

  18. Performance bound for quantum absorption refrigerators

    E-Print Network [OSTI]

    Luis A. Correa; José P. Palao; Gerardo Adesso; Daniel Alonso

    2013-04-29

    An implementation of quantum absorption chillers with three qubits has been recently proposed, that is ideally able to reach the Carnot performance regime. Here we study the working efficiency of such self-contained refrigerators, adopting a consistent treatment of dissipation effects. We demonstrate that the coefficient of performance at maximum cooling power is upper bounded by 3/4 of the Carnot performance. The result is independent of the details of the system and the equilibrium temperatures of the external baths. We provide design prescriptions that saturate the bound in the limit of a large difference between the operating temperatures. Our study suggests that delocalized dissipation, which must be taken into account for a proper modelling of the machine-baths interaction, is a fundamental source of irreversibility which prevents the refrigerator from approaching the Carnot performance arbitrarily closely in practice. The potential role of quantum correlations in the operation of these machines is also investigated.

  19. Counterflow absorber for an absorption refrigeration system

    DOE Patents [OSTI]

    Reimann, Robert C. (Lafayette, NY)

    1984-01-01

    An air-cooled, vertical tube absorber for an absorption refrigeration system is disclosed. Strong absorbent solution is supplied to the top of the absorber and refrigerant vapor is supplied to the bottom of the absorber to create a direct counterflow of refrigerant vapor and absorbent solution in the absorber. The refrigeration system is designed so that the volume flow rate of refrigerant vapor in the tubes of the absorber is sufficient to create a substantially direct counterflow along the entire length of each tube in the absorber. This provides several advantages for the absorber such as higher efficiency and improved heat transfer characteristics, and allows improved purging of non-condensibles from the absorber.

  20. Gas separation using ultrasound and light absorption

    DOE Patents [OSTI]

    Sinha, Dipen N. (Los Alamos, NM)

    2012-07-31

    An apparatus and method for separating a chosen gas from a mixture of gases having no moving parts and utilizing no chemical processing is described. The separation of particulates from fluid carriers thereof has been observed using ultrasound. In a similar manner, molecular species may be separated from carrier species. It is also known that light-induced drift may separate light-absorbing species from carrier species. Therefore, the combination of temporally pulsed absorption of light with ultrasonic concentration is expected to significantly increase the efficiency of separation by ultrasonic concentration alone. Additionally, breaking the spatial symmetry of a cylindrical acoustic concentrator decreases the spatial distribution of the concentrated particles, and increases the concentration efficiency.

  1. Multi-stage quantum absorption heat pumps

    E-Print Network [OSTI]

    Luis A. Correa

    2014-01-16

    It is well known that heat pumps, while being all limited by the same basic thermodynamic laws, may find realization on systems as "small" and "quantum" as a three-level maser. In order to quantitatively assess how the performance of these devices scales with their size, we design generalized $N$-dimensional ideal heat pumps by merging $N-2$ elementary three-level stages. We set them to operate in the absorption chiller mode between given hot and cold baths, and study their maximum achievable cooling power and the corresponding efficiency as a function of $N$. While the efficiency at maximum power is roughly size-independent, the power itself slightly increases with the dimension, quickly saturating to a constant. Thus, interestingly, scaling up autonomous quantum heat pumps does not render a significant enhancement beyond the optimal double-stage configuration.

  2. Commercialization of Industrialized Absorption Heat Pumps in the US 

    E-Print Network [OSTI]

    Pettigrew, M. G.

    1987-01-01

    OF INDUSTRIAL ABSORPTION HEAT PUMPS IN THE US MALCOLM G. PETTIGREW LITWIN ENGINEERS &CONSTRUCTORS, INC. HOUSTON, ABSTRACT The recovery of waste heat through absorption heat pumping is quite appeal ing to U.S. industry. However, although... this technology has been successfully applied in Europe and Japan, a cauti ous atmosphere wi 11 continue to prevail in the U.S. until the first absorption heat pump is built and successfully demonstrates it's viability for industrial applications...

  3. Continuous Light Absorption Photometer (CLAP) Final Campaign Report

    SciTech Connect (OSTI)

    Jefferson, Anne

    2014-05-01

    The Continuous Light Absorption Photometer (CLAP) measures the aerosol absorption of radiation at three visible wavelengths; 461, 522, and 653 nanometers (nm). Data from this measurement is used in radiative forcing calculations, atmospheric heating rates, and as a prediction of the amount of equivalent black carbon in atmospheric aerosol and in models of aerosol semi-direct forcing. Aerosol absorption measurements are essential to modeling the energy balance of the atmosphere.

  4. Pipeline integrity design for differential settlement in discontinuous permafrost areas

    SciTech Connect (OSTI)

    Zhou, Z.J.; Boivin, R.P.; Glover, A.G.; Kormann, P.J.

    1996-12-31

    The NOVA Gas Transmission Ltd. (NGTL) gas pipeline system is expanding northwards as the producers search for and find new gas reserves. This growth has taken the system into the discontinuous permafrost zone, and also into new design problems. One such problem is the structural integrity of a pipeline subjected to the settlement differentials that occur between frozen and unfrozen soils. Adequate integrity design for differential settlement is required by design codes, such as CSA Z662, but the procedures and criteria must be established by the pipeline designers. This paper presents the methodology of pipeline integrity design for differential settlements used on a number of pipeline projects in Northwest Alberta. Outlined in the paper are the procedures, rationales and models used to: (a) locate discontinuous permafrost; (b) quantify the potential differential settlement; (c) predict pipeline stresses and strains; (d) establish strain limits; and (e) determine the pipe wall thickness to withstand those potential differential settlements. Several design options are available and are briefly discussed. For the projects mentioned, the heavy wall pipe option was identified as a cost effective design for medium to large differential settlements.

  5. Use of radial symmetry for the calculation of cylindrical absorption coefficients and optimal capillary loadings

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Khalifah, Peter [Stony Brook Univ., NY (United States); Brookhaven National Lab., Upton, NY (United States)

    2015-02-01

    The problem of numerically evaluating absorption correction factors for cylindrical samples has been revisited using a treatment that fully takes advantage of the sample symmetry. It is shown that the path lengths for all points within the sample at all possible diffraction angles can be trivially determined once the angle-dependent distance distribution for a single line of points is calculated. This provides advantages in both computational efficiency and in gaining an intuitive understanding of the effects of absorption on diffraction data. A matrix of absorption coefficients calculated for µR products between 0 and 20 for diffraction angles ?D of 0° to 90° were used to examine the influence of (1) capillary diameter and of (2) sample density on the overall scattered intensity as a function of diffraction angle, where µ is the linear absorption coefficient for the sample and R is the capillary radius. Based on this analysis, the optimal sample loading for a capillary experiment to maximize diffraction at angles of 0 – 50° is in general expected to be achieved when the maximum radius capillary compatible with the beam is used, and when the sample density is adjusted to be 3/(4µR) of its original density.

  6. Two Photon Absorption And Refraction in Bulk of the Semiconducting Materials

    SciTech Connect (OSTI)

    Kumari, Vinay [Department of Physics, BMIET Sonepat, Haryana (India); Department of Physics, DCRUST Murthal, Haryana (India); Kumar, Vinod [Department of Physics, Gurukula Kangri University, Haridwar (India); Malik, B. P. [Department of Physics, DCRUST Murthal, Haryana (India); Mohan, Devendra [Department of Applied Physics, GJUS and T, Hisar, Haryana (India); Gaur, Arun [Department of Physics, Hindu PG College (Sonepat), Haryana (India)

    2011-10-20

    Fast electronic detection systems have opened up a number of new fields like nonlinear optics, optical communication, coherent optics, optical bistability, two/four wave mixing. The interest in this field has been stimulated by the importance of multiphoton processes in many fundamental aspects of physics. It has proved to be an invaluable tool for determining the optical and electronic properties of the solids because of the fact that one gets the information about the bulk of the material rather than the surface one. In this paper we report, the measurement of the nonlinear absorption and refraction from the band gap to half-band gap region of bulk of semiconductors in the direct and indirect band gap crystals with nanosecond laser. The measured theoretical calculated values of two-photon absorption coefficients ({beta}) and nonlinear refraction n{sub 2}({omega}) of direct band gap crystal match the earlier reported theoretical predictions. By making use of these theoretical calculated values, we have estimated {beta} and n{sub 2}({omega}) in the case of indirect band gap crystals. Low value of absorption coefficient in case of indirect band gap crystals have been attributed to phonon assisted transition while reduction in nonlinear refraction is due to the rise in saturation taking place in the absorption.

  7. Use of radial symmetry for the calculation of cylindrical absorption coefficients and optimal capillary loadings

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Khalifah, Peter

    2015-02-01

    The problem of numerically evaluating absorption correction factors for cylindrical samples has been revisited using a treatment that fully takes advantage of the sample symmetry. It is shown that the path lengths for all points within the sample at all possible diffraction angles can be trivially determined once the angle-dependent distance distribution for a single line of points is calculated. This provides advantages in both computational efficiency and in gaining an intuitive understanding of the effects of absorption on diffraction data. A matrix of absorption coefficients calculated for µR products between 0 and 20 for diffraction angles ?D of 0°more »to 90° were used to examine the influence of (1) capillary diameter and of (2) sample density on the overall scattered intensity as a function of diffraction angle, where µ is the linear absorption coefficient for the sample and R is the capillary radius. Based on this analysis, the optimal sample loading for a capillary experiment to maximize diffraction at angles of 0 – 50° is in general expected to be achieved when the maximum radius capillary compatible with the beam is used, and when the sample density is adjusted to be 3/(4µR) of its original density.« less

  8. Rich magneto-absorption spectra in AAB-stacked trilayer graphene

    E-Print Network [OSTI]

    Do, Thi-Nga; Chang, Cheng-Pong; Lin, Chiun-Yan; Lin, Ming-Fa

    2015-01-01

    The generalized tight-binding model is developed to investigate the feature-rich magneto-optical properties of AAB-stacked trilayer graphene. Three intragroup and six intergroup inter-Landau-level (inter-LL) optical excitations largely enrich the magneto-absorption peaks. In general, the former are much higher than the latter, depending on the phases and amplitudes of LL wavefunctions. The absorption spectra exhibit the single- or twin-peak structures which are determined by the quantum modes, LL energy spectra and Fermion distribution. The splitting LLs, with different localization centers (2/6 and 4/6 positions in a unit cell), can generate very distinct absorption spectra. There exist extra single peaks because of LL anticrosings. AAB, AAA, ABA, and ABC stackings quite differ from one another in terms of the inter-LL category, frequency, intensity, and structure of absorption peaks. The main characteristics of LL wavefunctions and energy spectra and the Fermi-Dirac function are responsible for the configur...

  9. Ab initio calculation of the electronic absorption spectrum of liquid water

    SciTech Connect (OSTI)

    Martiniano, Hugo F. M. C.; Galamba, Nuno; Cabral, Benedito J. Costa; Departamento de Química e Bioquímica, Faculdade de Ciências, Universidade de Lisboa, 1749-016 Lisboa; Instituto de Física da Universidade de São Paulo, CP 66318, 05314-970 São Paulo, SP

    2014-04-28

    The electronic absorption spectrum of liquid water was investigated by coupling a one-body energy decomposition scheme to configurations generated by classical and Born-Oppenheimer Molecular Dynamics (BOMD). A Frenkel exciton Hamiltonian formalism was adopted and the excitation energies in the liquid phase were calculated with the equation of motion coupled cluster with single and double excitations method. Molecular dynamics configurations were generated by different approaches. Classical MD were carried out with the TIP4P-Ew and AMOEBA force fields. The BLYP and BLYP-D3 exchange-correlation functionals were used in BOMD. Theoretical and experimental results for the electronic absorption spectrum of liquid water are in good agreement. Emphasis is placed on the relationship between the structure of liquid water predicted by the different models and the electronic absorption spectrum. The theoretical gas to liquid phase blue-shift of the peak positions of the electronic absorption spectrum is in good agreement with experiment. The overall shift is determined by a competition between the O–H stretching of the water monomer in liquid water that leads to a red-shift and polarization effects that induce a blue-shift. The results illustrate the importance of coupling many-body energy decomposition schemes to molecular dynamics configurations to carry out ab initio calculations of the electronic properties in liquid phase.

  10. Absorption of Foliar-Applied Nitrogen by Cotton

    E-Print Network [OSTI]

    Oosterhuis, Derrick M

    2009-01-01

    on the epicuticular wax composition and ultrastructure ofleaf age, epicuticular wax, and nitrogen-15 absorption. Cropleaf cuticle and epicuticular wax as described by Oosterhuis

  11. The Future of Absorption Technology in America: A Critical Look...

    Broader source: Energy.gov (indexed) [DOE]

    Building, Cooling, Heating, and Power (BCHP) and innovation in order to understand the future of absorption technology in America. absorptionfuture.pdf More Documents &...

  12. Electronic structure of titania aerogels: Soft x-ray absorption...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Electronic structure of titania aerogels: Soft x-ray absorption study Citation Details In-Document Search Title: Electronic structure of titania aerogels: Soft...

  13. Size Dependence of Two-Photon Absorption in Semiconductor Quantum...

    Office of Scientific and Technical Information (OSTI)

    absorption spectroscopy by probing the pump-induced bleaching at the first exciton transition energy. was also calculated using a model based on the multiband...

  14. Inverse differential kinematics Statics and force transformations

    E-Print Network [OSTI]

    De Luca, Alessandro

    ;Damped Least Squares method ! inversion of differential kinematics as an optimization problem ! function

  15. Forster resonance energy transfer, absorption and emission spectra in multichromophoric systems: III. Exact stochastic path integral evaluation

    E-Print Network [OSTI]

    Jeremy Moix; Jian Ma; Jianshu Cao

    2015-01-22

    A numerically exact path integral treatment of the absorption and emission spectra of open quantum systems is presented that requires only the straightforward solution of a stochastic differential equation. The approach converges rapidly enabling the calculation of spectra of large excitonic systems across the complete range of system parameters and for arbitrary bath spectral densities. With the numerically exact absorption and emission operators one can also immediately compute energy transfer rates using the multi-chromophoric Forster resonant energy transfer formalism. Benchmark calculations on the emission spectra of two level systems are presented demonstrating the efficacy of the stochastic approach. This is followed by calculations of the energy transfer rates between two weakly coupled dimer systems as a function of temperature and system-bath coupling strength. It is shown that the recently developed hybrid cumulant expansion is the only perturbative method capable of generating uniformly reliable energy transfer rates and spectra across a broad range of system parameters.

  16. AEROSOL ABSORPTION IN CLOUDY SCENES USING PASSIVE SATELLITE INSTRUMENTS

    E-Print Network [OSTI]

    Graaf, Martin de

    AEROSOL ABSORPTION IN CLOUDY SCENES USING PASSIVE SATELLITE INSTRUMENTS M. de Graaf, L.G. Tilstra information has become available from active space-based sensors and some dedicated field campaigns on aerosol-absorption, is the Absorbing Aerosol Index (AAI), which can indicate absorbing aerosols overlying clouds. The AAI is available

  17. Laser Locking with Doppler-free Saturated Absorption Spectroscopy

    E-Print Network [OSTI]

    Novikova, Irina

    - 1 - Laser Locking with Doppler-free Saturated Absorption Spectroscopy Paul L. Stubbs, Advisor the frequency of a 795 nm diode laser using a saturated absorption spectroscopy method. Laser locking in AMO physics is done to stabilize the frequency of lasers used in the laboratory in order to make results more

  18. Absorption of Carbon Dioxide in Aqueous Piperazine/Methyldiethanolamine

    E-Print Network [OSTI]

    Rochelle, Gary T.

    Absorption of Carbon Dioxide in Aqueous Piperazine/Methyldiethanolamine Sanjay Bishnoi and Gary T. Rochelle Dept. of Chemical Engineering, The University of Texas at Austin, Austin, TX 78712 ( )Carbon dioxide absorption in 0.6 M piperazine PZ r4 M methyldiethanolamine ( )MDEA was measured in a wetted wall

  19. Pressure Calibration by the Infrared Absorption Spectrum of Mineral Oil

    E-Print Network [OSTI]

    Collins, Gary S.

    Pressure Calibration by the Infrared Absorption Spectrum of Mineral Oil H. Child, Kenyon College effect is seen in the infrared absorption spectrum of mineral oil. The frequency of two peaks increases as pressure is applied to the mineral oil. At a pressure of about 1 kbar (100 MPa), both peaks are distinct

  20. The role of solar absorption in climate and climate change

    E-Print Network [OSTI]

    1 The role of solar absorption in climate and climate change William Collins UC Berkeley · Changes to surface and atmosphere by aerosols · Climate sensitivity to changes in aerosols and CO2 Research Boulder, Colorado, USA #12;2 Prior Research on Absorption and Climate Field Experiments: · Central

  1. CO2 Capture by Absorption with Potassium Carbonate

    E-Print Network [OSTI]

    Rochelle, Gary T.

    CO2 Capture by Absorption with Potassium Carbonate Second Quarterly Report 2006 Quarterly Progress of this work is to improve the process for CO2 capture by alkanolamine absorption/stripping by developing% inlet CO2. A rate-based model demonstrates that the stripper is primarily controlled by liquid film mast

  2. CO2 Capture by Absorption with Potassium Carbonate

    E-Print Network [OSTI]

    Rochelle, Gary T.

    CO2 Capture by Absorption with Potassium Carbonate First Quarterly Report 2007 Quarterly Progress of this work is to improve the process for CO2 capture by alkanolamine absorption/stripping by developing, requires equivalent work of 31.8 kJ/mole CO2 when used with a double matrix stripper and an intercooled

  3. CO2 Capture by Absorption with Potassium Carbonate

    E-Print Network [OSTI]

    Rochelle, Gary T.

    CO2 Capture by Absorption with Potassium Carbonate First Quarterly Report 2006 Quarterly Progress the process for CO2 capture by alkanolamine absorption/stripping by developing an alternative solvent, aqueous. Uninhibited 5 m KHCO3/2.5 m PZ corrodes 5 to 6 times faster that 30% MEA with 0.2 mol CO2/mol MEA. #12

  4. CO2 Capture by Absorption with Potassium Carbonate

    E-Print Network [OSTI]

    Rochelle, Gary T.

    CO2 Capture by Absorption with Potassium Carbonate Third Quarterly Report 2006 Quarterly Progress of this work is to improve the process for CO2 capture by alkanolamine absorption/stripping by developing use. Extensive measurements of CO2 solubility in 7 m MEA at 40 and 60o C have confirmed the work

  5. CO2 Capture by Absorption with Potassium Carbonate

    E-Print Network [OSTI]

    Rochelle, Gary T.

    CO2 Capture by Absorption with Potassium Carbonate Fourth Quarterly Report 2006 Quarterly Progress of this work is to improve the process for CO2 capture by alkanolamine absorption/stripping by developing 20% of the power output from a 500 MW power plant with 90% CO2 removal. The stripper rate model shows

  6. Absorption media for irreversibly gettering thionyl chloride

    DOE Patents [OSTI]

    Buffleben, George (Tracy, CA); Goods, Steven H. (Livermore, CA); Shepodd, Timothy (Livermore, CA); Wheeler, David R. (Albuquerque, NM); Whinnery, Jr., LeRoy (Danville, CA)

    2002-01-01

    Thionyl chloride is a hazardous and reactive chemical used as the liquid cathode in commercial primary batteries. Contrary to previous thinking, ASZM-TEDA.RTM. carbon (Calgon Corporation) reversibly absorbs thionyl chloride. Thus, several candidate materials were examined as irreversible getters for thionyl chloride. The capacity, rate and effect of temperature were also explored. A wide variety of likely materials were investigated through screening experiments focusing on the degree of heat generated by the reaction as well as the material absorption capacity and irreversibility, in order to help narrow the group of possible getter choices. More thorough, quantitative measurements were performed on promising materials. The best performing getter was a mixture of ZnO and ASZM-TEDA.RTM. carbon. In this example, the ZnO reacts with thionyl chloride to form ZnCl.sub.2 and SO.sub.2. The SO.sub.2 is then irreversibly gettered by ASZM-TEDA.RTM. carbon. This combination of ZnO and carbon has a high capacity, is irreversible and functions effectively above -20.degree. C.

  7. Cost reduction in absorption chillers: Phase 2

    SciTech Connect (OSTI)

    Leigh, R.W.

    1989-02-01

    A research program at Brookhaven National Laboratory (BNL) has addressed the possibility of dramatically lowering the first costs of absorption chillers through lowered material intensity and the use of lower cost materials, primarily in the heat exchangers which make up the bulk of the operating components of these systems. This must be done while retaining the best performance characteristics available today, a gross design point coefficient of performance (COP) of 1.3 and a net design (seasonal) average COP of 1.0 (0.90) in a directly fired, double effect unit. We have investigated several possible routes to these goals, and here report on these findings, focusing on the areas that appear most promising. The candidate technologies include the use of polymer film heat exchangers in several applications, the use of thin strips of new, corrosion resistant alloys to replace thicker, less impervious metals in applications exposed to gas flames, and copper or cupro-nickel foils in contact with system water. The use of such materials is only possible in the context of new heat exchanger and system designs, which are also discussed. To lend focus, we have concentrated on a directly fired double effect system providing capacity only. If successful, these techniques will also find wide applicability in heat pumps, cogeneration systems, solar cooling, heat recovery and chemical process heat transfer. 46 refs., 24 figs., 22 tabs.

  8. Moisture absorption and bakeout characteristics of rigid-flexible multilayer printed wiring boards

    SciTech Connect (OSTI)

    Lula, J.W.

    1991-01-01

    Moisture absorption and bakeout characteristics of Allied-Signal Inc., Kansas City Division (KCD) rigid-flexible printed wiring boards were determined. It was found that test specimens had absorbed 0.95 weight percent moisture when equilibrated to a 50 percent RH, 25{degree}C environment. Heating those equilibrated specimens in a 120{degree}C static air oven removed 92 percent of this absorbed moisture in 24 h. Heating the samples in a 80{degree}C static air oven removed only 64 percent of the absorbed moisture at the end of 24 h. A 120{degree}C vacuum bake removed moisture at essentially the same rate with parylene slowed the absorption rate by approximately 50 percent but did not appreciably affect the equilibrium moisture content or the drying rate.

  9. Development of a mathematical model for determining drug absorption parameters in Caco-2 cell monolayers

    E-Print Network [OSTI]

    Blaser, David

    2006-10-27

    C /**/** max ++??= BBabCabBab VSmCCPdt dC /*)(* ?= SmCCPSmMK MvSmCCPdtdM BabCab Cab CabCabAabCab *)(****)(* max ?? +??= A Cba CbaAAbaCbaAba VSm MK MvVSmCCP dt dC /**/*)(* max ++?= BCbaBbaBba VSmCCPdt dC /*)(* ??= SmMK MvSmCCPSmCCPdtdM Cba CbaAbaCbaCbaBbaCba...C /**/** max ++??= BBabCabBab VSmCCPdt dC /*)(* ?= SmCCPSmMK MvSmCCPdtdM BabCab Cab CabCabAabCab *)(****)(* max ?? +??= A Cba CbaAAbaCbaAba VSm MK MvVSmCCP dt dC /**/*)(* max ++?= BCbaBbaBba VSmCCPdt dC /*)(* ??= SmMK MvSmCCPSmCCPdtdM Cba CbaAbaCbaCbaBbaCba...

  10. Light absorption from particulate impurities in snow and ice determined by spectrophotometric

    E-Print Network [OSTI]

    Warren, Stephen

    of solar radiation integrated over the wavelength band 300 to 750 nm. © 2011 Optical Society of America a large fraction of black carbon (BC), are produced by incomplete combustion in diesel en- gines, coal-6935/11/142037-12$15.00/0 © 2011 Optical Society of America 10 May 2011 / Vol. 50, No. 14 / APPLIED OPTICS 2037 #12;the single

  11. Novel CO2 Binding Mechanism Determined via in-situ Absorption Spectroscopy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.Theory ofDid you notHeatMaRIEdioxideUser Work Featured onNewsNewsNotice to Users&

  12. Stochastic Parameterization for Light Absorption by Internally Mixed BC/dust in Snow Grains for Application to Climate Models

    SciTech Connect (OSTI)

    Liou, K. N.; Takano, Y.; He, Cenlin; Yang, P.; Leung, Lai-Yung R.; Gu, Y.; Lee, W- L.

    2014-06-27

    A stochastic approach to model the positions of BC/dust internally mixed with two snow-grain types has been developed, including hexagonal plate/column (convex) and Koch snowflake (concave). Subsequently, light absorption and scattering analysis can be followed by means of an improved geometric-optics approach coupled with Monte Carlo photon tracing to determine their single-scattering properties. For a given shape (plate, Koch snowflake, spheroid, or sphere), internal mixing absorbs more light than external mixing. The snow-grain shape effect on absorption is relatively small, but its effect on the asymmetry factor is substantial. Due to a greater probability of intercepting photons, multiple inclusions of BC/dust exhibit a larger absorption than an equal-volume single inclusion. The spectral absorption (0.2 – 5 um) for snow grains internally mixed with BC/dust is confined to wavelengths shorter than about 1.4 um, beyond which ice absorption predominates. Based on the single-scattering properties determined from stochastic and light absorption parameterizations and using the adding/doubling method for spectral radiative transfer, we find that internal mixing reduces snow albedo more than external mixing and that the snow-grain shape plays a critical role in snow albedo calculations through the asymmetry factor. Also, snow albedo reduces more in the case of multiple inclusion of BC/dust compared to that of an equal-volume single sphere. For application to land/snow models, we propose a two-layer spectral snow parameterization containing contaminated fresh snow on top of old snow for investigating and understanding the climatic impact of multiple BC/dust internal mixing associated with snow grain metamorphism, particularly over mountains/snow topography.

  13. Molecular shock response of explosives: electronic absorption spectroscopy

    SciTech Connect (OSTI)

    Mcgrne, Shawn D; Moore, David S; Whitley, Von H; Bolme, Cindy A; Eakins, Daniel E

    2009-01-01

    Electronic absorption spectroscopy in the range 400-800 nm was coupled to ultrafast laser generated shocks to begin addressing the question of the extent to which electronic excitations are involved in shock induced reactions. Data are presented on shocked polymethylmethacrylate (PMMA) thin films and single crystal pentaerythritol tetranitrate (PETN). Shocked PMMA exhibited thin film interference effects from the shock front. Shocked PETN exhibited interference from the shock front as well as broadband increased absorption. Relation to shock initiation hypotheses and the need for time dependent absorption data (future experiments) is briefly discussed.

  14. Absorption-induced transparency metamaterials in the terahertz regime

    E-Print Network [OSTI]

    Rodrigo, Sergio G

    2015-01-01

    Contrary to what might be expected, when an organic dye is sputtered onto an opaque holey metal film, transmission bands can be observed at the absorption energies of the molecules. This phenomenon, known as absorption-induced transparency, is aided by a strong modification of the propagation properties of light inside the holes when filled by the molecules. Despite having been initially observed in metallic structures in the optical regime, new routes for investigation and applications at different spectral regimes can be devised. Here, in order to illustrate the potential use of absorption induced transparency at terahertz, a method for molecular detection is presented, supported by a theoretical analysis.

  15. Unveiling the distribution of absorption in the AGN population

    E-Print Network [OSTI]

    Tom Dwelly; Mathew J. Page

    2005-11-15

    We use the very deep XMM-Newton observations in the CDF-S to measure the distribution of absorption in the AGN population. We describe the Monte Carlo method used to unveil the intrinsic properties of the AGN using their multi-band X-ray colours. The measured distribution of AGN in z, L_X and N_H space is compared with the distributions predicted by a number of XLFs and absorption models. In contrast to other studies, we do not find any evidence that the absorption distribution is dependent on redshift or intrinsic luminosity.

  16. Differential growth of wrinkled biofilms

    E-Print Network [OSTI]

    Espeso, D R; Einarsson, B

    2015-01-01

    Biofilms are antibiotic-resistant bacterial aggregates that grow on moist surfaces and can trigger hospital-acquired infections. They provide a classical example in biology where the dynamics of cellular communities may be observed and studied. Gene expression regulates cell division and differentiation, which affect the biofilm architecture. Mechanical and chemical processes shape the resulting structure. We gain insight into the interplay between cellular and mechanical processes during biofilm development on air-agar interfaces by means of a hybrid model. Cellular behavior is governed by stochastic rules informed by a cascade of concentration fields for nutrients, waste and autoinducers. Cellular differentiation and death alter the structure and the mechanical properties of the biofilm, which is deformed according to Foppl-Von Karman equations informed by cellular processes and the interaction with the substratum. Stiffness gradients due to growth and swelling produce wrinkle branching. We are able to repr...

  17. 18.03 Differential Equations, Spring 2006

    E-Print Network [OSTI]

    Miller, Haynes

    Differential Equations are the language in which the laws of nature are expressed. Understanding properties of solutions of differential equations is fundamental to much of contemporary science and engineering. Ordinary ...

  18. Differential Equations of Mathematical Physics

    E-Print Network [OSTI]

    Max Lein

    2015-08-16

    These lecture notes for the course APM 351 at the University of Toronto are aimed at mathematicians and physicists alike. It is not meant as an introductory course to PDEs, but rather gives an overview of how to view and solve differential equations that are common in physics. Among others, I cover Hamilton's equations, variations of the Schr\\"odinger equation, the heat equation, the wave equation and Maxwells equations.

  19. Operation Synopsis of Gas-Fired Double-Effect Absorption Chillers 

    E-Print Network [OSTI]

    Phillips, J.

    1986-01-01

    Absorption refrigeration systems are one of the oldest systems available. The fundamentals of absorption refrigeration were formulated about 1777, and the first successful absorption machine was developed in 1850. The first U.S. patent...

  20. Charge-transfer absorption and emission in polymer: fullerene...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Charge-transfer absorption and emission in polymer: fullerene solar cells April 13, 2010 at 3pm36-428 Koen Vandewal Linkping University vandewal-small abstract: For an efficient...

  1. Standoff alpha radiation detection via excited state absorption of air

    E-Print Network [OSTI]

    Yao, Jimmy; Brenizer, Jack; Hui, Rongqing; Yin, Stuart (Shizhuo)

    2013-06-24

    A standoff alpha radiation detection technique based on the physical mechanism of excited state absorption of air molecules was explored and is presented in this paper. Instead of directly detecting the radiation via measuring the intensity...

  2. Optical control of nuclear resonant absorption: theory and experiment 

    E-Print Network [OSTI]

    Kolesov, Roman L.

    2004-09-30

    Modification of nuclear resonant absorption by means of laser radiation is analyzed both theoretically and experimentally. Theoretical analysis is done on the basis of four-level model of atom. This model includes both ...

  3. Observation of suppressed terahertz absorption in photoexcited graphene

    E-Print Network [OSTI]

    Frenzel, Alex James

    When light is absorbed by a semiconductor, photoexcited charge carriers enhance the absorption of far-infrared radiation due to intraband transitions. We observe the opposite behavior in monolayer graphene, a zero-gap ...

  4. Present and Future Uses of Industrial Absorption Heat Pumps 

    E-Print Network [OSTI]

    Erickson, D. C.; Davidson, W. F.

    1985-01-01

    This paper examines the present and projects the future uses of industrial absorption heat pumping. AHP technology is seen as an increasingly important component of plant and process heat integration for energy conservation. Existing installations...

  5. Onsite Wastewater Treatment Systems: Septic Tank/Soil Absorption Field 

    E-Print Network [OSTI]

    Lesikar, Bruce J.

    2008-10-23

    For septic tank and soil absorption systems to work properly, homeowners must choose the right kind of system for their household size and soil type, and they must maintain them regularly. This publication explains the treatment, design, operation...

  6. Overview of Resources for Geothermal Absorption Cooling for Buildings

    SciTech Connect (OSTI)

    Liu, Xiaobing; Gluesenkamp, Kyle R; Mehdizadeh Momen, Ayyoub

    2015-06-01

    This report summarizes the results of a literature review in three areas: available low-temperature/coproduced geothermal resources in the United States, energy use for space conditioning in commercial buildings, and state of the art of geothermal absorption cooling.

  7. Optical absorption of pure water in the blue and ultraviolet 

    E-Print Network [OSTI]

    Lu, Zheng

    2007-09-17

    The key feature of the Integrating Cavity Absorption Meter (ICAM) is that it produces an isotropic illumination of the liquid sample and thereby dramatically minimizes scattering effects. The ICAM can produce an ...

  8. Absorption Cycle Fundamentals and Applications Guidelines for Distillation Energy Savings 

    E-Print Network [OSTI]

    Erickson, D. C.; Davidson, W. F.

    1984-01-01

    of applications, embody characteristics that inherently make them economic candidates for absorption cycle heat upgrading. Practical applications to current U.S. distillations could save 30 trillion BTU per year, at payback periods ranging from 1 to 3 years. So...

  9. Collision--induced absorption in dense atmospheres of cool stars

    SciTech Connect (OSTI)

    Borysow, Aleksandra; Joergensen, Uffe Graae

    1999-04-01

    In the atmosphere of the Sun the major interaction between the matter and the radiation is through light absorption by ions (predominantly the negative ion of hydrogen atoms), neutral atoms and a small amount of polar molecules. The majority of stars in the universe are, however, cooler and denser than our Sun, and for a large fraction of these, the above absorption processes are very weak. Here, collision-induced absorption (CIA) becomes the dominant opacity source. The radiation is absorbed during very short mutual passages ('collisions') of two non-polar molecules (and/or atoms), while their electric charge distributions are temporarily distorted which gives rise to a transient dipole moment. We present here a review of the present-day knowledge about the impact of collision-induced absorption processes on the structure and the spectrum of such stars.

  10. Numerical Differentiation of Noisy, Nonsmooth Data

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chartrand, Rick

    2011-01-01

    We consider the problem of differentiating a function specified by noisy data. Regularizing the differentiation process avoids the noise amplification of finite-difference methods. We use total-variation regularization, which allows for discontinuous solutions. The resulting simple algorithm accurately differentiates noisy functions, including those which have a discontinuous derivative.

  11. PROPORTIONAL DIFFERENTIATED SERVICES FOR THE INTERNET

    E-Print Network [OSTI]

    Dovrolis, Constantinos

    PROPORTIONAL DIFFERENTIATED SERVICES FOR THE INTERNET by Konstantinos Dovrolis #12; PROPORTIONAL ­ MADISON 2000 #12; i To my family M ffae'šo& , Kff'øj, Ašš fflø ff, T ffoeo& #12; ii PROPORTIONAL develop the Proportional Differentiated Services (PDS) architecture. In PDS, the differentiation between

  12. Broad Absorption Line Quasar catalogues with Supervised Neural Networks

    E-Print Network [OSTI]

    Simone Scaringi; Christopher E. Cottis; Christian Knigge; Michael R. Goad

    2008-10-24

    We have applied a Learning Vector Quantization (LVQ) algorithm to SDSS DR5 quasar spectra in order to create a large catalogue of broad absorption line quasars (BALQSOs). We first discuss the problems with BALQSO catalogues constructed using the conventional balnicity and/or absorption indices (BI and AI), and then describe the supervised LVQ network we have trained to recognise BALQSOs. The resulting BALQSO catalogue should be substantially more robust and complete than BI- or AI-based ones.

  13. Lyman alpha Absorption Systems and the Intergalactic Medium

    E-Print Network [OSTI]

    George Efstathiou; Joop Schaye; Tom Theuns

    2000-04-10

    The last few years have seen a dramatic improvement in our understanding of the origin of Lyman alpha absorption systems. Hydrodynamic numerical simulations of cold dark matter dominated universes have shown that the many properties of the Lyman alpha absorption systems can be explained by a photoionized, space-filling, intergalactic medium. Lyman alpha lines offer promising probes of the photoionizing background, the amplitude of the mass fluctuations at high redshift and the evolution of the equation of state of the intergalactic medium.

  14. Modelling aging effects on a thermal cycling absorption process column

    SciTech Connect (OSTI)

    Laquerbe, C.; Contreras, S.; Demoment, J.

    2008-07-15

    Palladium coated on alumina is used in hydrogen separation systems operated at CEA/Valduc, and more particularly in Thermal Cycling Absorption Process columns. With such materials, tritium decay is known to induce aging effects which have direct side effects on hydrogen isotopes absorption isotherms. Furthermore in a TCAP column, aging occurs in an heterogeneous way. The possible impacts of these intrinsic material evolutions on the separation performances are investigated here through a numerical approach. (authors)

  15. Near-infrared free carrier absorption in heavily doped silicon

    SciTech Connect (OSTI)

    Baker-Finch, Simeon C.; McIntosh, Keith R.; Yan, Di; Fong, Kean Chern; Kho, Teng C.

    2014-08-14

    Free carrier absorption in heavily doped silicon can have a significant impact on devices operating in the infrared. In the near infrared, the free carrier absorption process can compete with band to band absorption processes, thereby reducing the number of available photons to optoelectronic devices such as solar cells. In this work, we fabricate 18 heavily doped regions by phosphorus and boron diffusion into planar polished silicon wafers; the simple sample structure facilitates accurate and precise measurement of the free carrier absorptance. We measure and model reflectance and transmittance dispersion to arrive at a parameterisation for the free carrier absorption coefficient that applies in the wavelength range between 1000 and 1500?nm, and the range of dopant densities between ?10{sup 18} and 3?×?10{sup 20}?cm{sup ?3}. Our measurements indicate that previously published parameterisations underestimate the free carrier absorptance in phosphorus diffusions. On the other hand, published parameterisations are generally consistent with our measurements and model for boron diffusions. Our new model is the first to be assigned uncertainty and is well-suited to routine device analysis.

  16. Quasi-static energy absorption of hollow microlattice structures

    SciTech Connect (OSTI)

    Liu, YL; Schaedler, TA; Jacobsen, AJ; Chen, X

    2014-12-01

    We present a comprehensive modeling and numerical study focusing on the energy quasi-static crushing behavior and energy absorption characteristics of hollow tube microlattice structures. The peak stress and effective plateau stress of the hollow microlattice structures are deduced for different geometrical parameters which gives volume and mass densities of energy absorption, D-v and D-m, scale with the relative density, (rho) over bar, as D-v similar to (rho) over bar (1) (5) and D-m similar to (rho) over bar (0 5), respectively, fitting very well to the experimental results of both 60 degrees inclined and 90 degrees predominately microlattices. Then the strategies for energy absorption enhancement are proposed for the engineering design of microlattice structures. By introducing a gradient in the thickness or radius of the lattice members, the buckle propagation can be modulated resulting in an increase in energy absorption density that can exceed 40%. Liquid filler is another approach to improve energy absorption by strengthening the microtruss via circumference expansion, and the gain may be over 100% in terms of volume density. Insight into the correlations between microlattice architecture and energy absorption performance combined with the high degree of architecture control paves the way for designing high performance microlattice structures for a range of impact and impulse mitigation applications for vehicles and structures. (C) 2014 Elsevier Ltd. All rights reserved.

  17. Use Low-Grade Waste Steam to Power Absorption Chillers, Energy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    4 Use Low-Grade Waste Steam to Power Absorption Chillers Absorption chillers use heat, instead of mechanical energy, to provide cooling. The mechanical vapor compressor is replaced...

  18. An analysis of a reversed absorption heat pump for low temperature waste heat utilization 

    E-Print Network [OSTI]

    Wade, Glenn William

    1979-01-01

    E. Jenkins A simu'lation program based on a First Law analysis was developed to provide the analysis of a reversed ammonia-water absorption heat pump for various operating temperature requi re- ments. The program was used to determine... 22 33 35 14 t k - t t h t diagram for an output tempera- sink waste heat ture = 210 F 37 15 output temperature = 210'F 39 16 Concentration - enthalpy path of aqueous phase in example problem 45 17 Pressure - enthalpy path of ammonia...

  19. Emission and Absorption Spectroscopy of Carbon Arc Plasma during Formation of Carbon Magnetic Encapsulates

    SciTech Connect (OSTI)

    Lange, H.; Labedz, O.; Huczko, A.; Bystrzejewski, M.

    2011-11-29

    Plasma diagnostics of carbon arc discharge under conditions of carbon magnetic encapsulates formation was performed by emission and absorption spectroscopy. Content of C{sub 2} and Fe species, rotational temperatures of excited (d {sup 3} product {sub g}) and non-excited (a {sup 3} product {sub u}) states, and excitation temperatures of a {sup 5}F and a {sup 3}F levels relatively to the a {sup 5}D level of Fe atoms were determined. The results pointed to a non-equilibrium state of carbon arc plasma under prevailing discharge conditions.

  20. Self-similar solutions for reversing interfaces in the nonlinear diffusion equation with constant absorption

    E-Print Network [OSTI]

    Jamie M. Foster; Dmitry E. Pelinovsky

    2015-06-16

    We consider the slow nonlinear diffusion equation subject to a constant absorption rate and construct local self-similar solutions for reversing (and anti-reversing) interfaces, where an initially advancing (receding) interface gives way to a receding (advancing) one. We use an approach based on invariant manifolds, which allows us to determine the required asymptotic behaviour for small and large values of the concentration. We then `connect' the requisite asymptotic behaviours using a robust and accurate numerical scheme. By doing so, we are able to furnish a rich set of self-similar solutions for both reversing and anti-reversing interfaces.

  1. Crystal face temperature determination means

    DOE Patents [OSTI]

    Nason, D.O.; Burger, A.

    1994-11-22

    An optically transparent furnace having a detection apparatus with a pedestal enclosed in an evacuated ampule for growing a crystal thereon is disclosed. Temperature differential is provided by a source heater, a base heater and a cold finger such that material migrates from a polycrystalline source material to grow the crystal. A quartz halogen lamp projects a collimated beam onto the crystal and a reflected beam is analyzed by a double monochromator and photomultiplier detection spectrometer and the detected peak position in the reflected energy spectrum of the reflected beam is interpreted to determine surface temperature of the crystal. 3 figs.

  2. Nonlinear system identification employing automatic differentiation

    E-Print Network [OSTI]

    Jan Schumann-Bischoff; Stefan Luther; Ulrich Parlitz

    2015-07-09

    An optimization based state and parameter estimation method is presented where the required Jacobian matrix of the cost function is computed via automatic differentiation. Automatic differentiation evaluates the programming code of the cost function and provides exact values of the derivatives. In contrast to numerical differentiation it is not suffering from approximation errors and compared to symbolic differentiation it is more convenient to use, because no closed analytic expressions are required. Furthermore, we demonstrate how to generalize the parameter estimation scheme to delay differential equations, where estimating the delay time requires attention.

  3. Carbon Dioxide Separation from Flue Gas by Phase Enhanced Absorption

    SciTech Connect (OSTI)

    Tim Fout

    2007-06-30

    A new process, phase enhanced absorption, was invented. The method is carried out in an absorber, where a liquid carrier (aqueous solution), an organic mixture (or organic compound), and a gas mixture containing a gas to be absorbed are introduced from an inlet. Since the organic mixture is immiscible or at least partially immiscible with the liquid carrier, the organic mixture forms a layer or small parcels between the liquid carrier and the gas mixture. The organic mixture in the absorber improves mass transfer efficiency of the system and increases the absorption rate of the gas. The organic mixture serves as a transportation media. The gas is finally accumulated in the liquid carrier as in a conventional gas-liquid absorption system. The presence of the organic layer does not hinder the regeneration of the liquid carrier or recovery of the gas because the organic layer is removed by a settler after the absorption process is completed. In another aspect, the system exhibited increased gas-liquid separation efficiency, thereby reducing the costs of operation and maintenance. Our study focused on the search of the organic layer or transportation layer to enhance the absorption rate of carbon dioxide. The following systems were studied, (1) CO{sub 2}-water system and CO{sub 2}-water-organic layer system; (2) CO{sub 2}-Potassium Carbonate aqueous solution system and CO{sub 2}-Potassium Carbonate aqueous solution-organic layer system. CO{sub 2}-water and CO{sub 2}-Potassium Carbonate systems are the traditional gas-liquid absorption processes. The CO{sub 2}-water-organic layer and CO{sub 2}-Potassium Carbonate-organic layer systems are the novel absorption processes, phase enhanced absorption. As we mentioned early, organic layer is used for the increase of absorption rate, and plays the role of transportation of CO{sub 2}. Our study showed that the absorption rate can be increased by adding the organic layer. However, the enhanced factor is highly depended on the liquid mass transfer coefficients for the CO{sub 2}-water-organic layer system. For the CO{sub 2}-Potassium Carbonate aqueous solution-organic layer system, the enhanced factor is not only dependent on the liquid mass transfer coefficients, but also the chemical reaction rates.

  4. Deviation differential equations. Jacobi fields

    E-Print Network [OSTI]

    G. Sardanashvily

    2013-04-02

    Given a differential equation on a smooth fibre bundle Y, we consider its canonical vertical extension to that, called the deviation equation, on the vertical tangent bundle VY of Y. Its solutions are Jacobi fields treated in a very general setting. In particular, the deviation of Euler--Lagrange equations of a Lagrangian L on a fibre bundle Y are the Euler-Lagrange equations of the canonical vertical extension of L onto VY. Similarly, covariant Hamilton equations of a Hamiltonian form H are the Hamilton equations of the vertical extension VH of H onto VY.

  5. Development of an Ionic-Liquid Absorption Heat Pump

    SciTech Connect (OSTI)

    Holcomb, Don

    2011-03-29

    Solar Fueled Products (SFP) is developing an innovative ionic-liquid absorption heat pump (ILAHP). The development of an ILAHP is extremely significant, as it could result in annual savings of more than 190 billion kW h of electrical energy and $19 billion. This absorption cooler uses about 75 percent less electricity than conventional cooling and heating units. The ILAHP also has significant environmental sustainability benefits, due to reduced CO2 emissions. Phase I established the feasibility and showed the economic viability of an ILAHP with these key accomplishments: • Used the breakthrough capabilities provided by ionic liquids which overcome the key difficulties of the common absorption coolers. • Showed that the theoretical thermodynamic performance of an ILAHP is similar to existing absorption-cooling systems. • Established that the half-effect absorption cycle reduces the peak generator temperature, improving collector efficiency and reducing collector area. • Component testing demonstrated that the most critical components, absorber and generator, operate well with conventional heat exchangers. • Showed the economic viability of an ILAHP. The significant energy savings, sustainability benefits, and economic viability are compelling reasons to continue the ILAHP development.

  6. PI3K/AKT and ERK regulate retinoic acid-induced neuroblastoma cellular differentiation

    SciTech Connect (OSTI)

    Qiao, Jingbo [Department of Pediatric Surgery, Vanderbilt University Medical Center, Nashville, TN 37232 (United States)] [Department of Pediatric Surgery, Vanderbilt University Medical Center, Nashville, TN 37232 (United States); Paul, Pritha; Lee, Sora [Department of Pediatric Surgery, Vanderbilt University Medical Center, Nashville, TN 37232 (United States) [Department of Pediatric Surgery, Vanderbilt University Medical Center, Nashville, TN 37232 (United States); Department of Cancer Biology, Vanderbilt University Medical Center, Nashville, TN 37232 (United States); Qiao, Lan; Josifi, Erlena; Tiao, Joshua R. [Department of Pediatric Surgery, Vanderbilt University Medical Center, Nashville, TN 37232 (United States)] [Department of Pediatric Surgery, Vanderbilt University Medical Center, Nashville, TN 37232 (United States); Chung, Dai H., E-mail: dai.chung@vanderbilt.edu [Department of Pediatric Surgery, Vanderbilt University Medical Center, Nashville, TN 37232 (United States); Department of Cancer Biology, Vanderbilt University Medical Center, Nashville, TN 37232 (United States)

    2012-08-03

    Highlights: Black-Right-Pointing-Pointer Retinoic acid (RA) induces neuroblastoma cells differentiation, which is accompanied by G0/G1 cell cycle arrest. Black-Right-Pointing-Pointer RA resulted in neuroblastoma cell survival and inhibition of DNA fragmentation; this is regulated by PI3K pathway. Black-Right-Pointing-Pointer RA activates PI3K and ERK1/2 pathway; PI3K pathway mediates RA-induced neuroblastoma cell differentiation. Black-Right-Pointing-Pointer Upregulation of p21 is necessary for RA-induced neuroblastoma cell differentiation. -- Abstract: Neuroblastoma, the most common extra-cranial solid tumor in infants and children, is characterized by a high rate of spontaneous remissions in infancy. Retinoic acid (RA) has been known to induce neuroblastoma differentiation; however, the molecular mechanisms and signaling pathways that are responsible for RA-mediated neuroblastoma cell differentiation remain unclear. Here, we sought to determine the cell signaling processes involved in RA-induced cellular differentiation. Upon RA administration, human neuroblastoma cell lines, SK-N-SH and BE(2)-C, demonstrated neurite extensions, which is an indicator of neuronal cell differentiation. Moreover, cell cycle arrest occurred in G1/G0 phase. The protein levels of cyclin-dependent kinase inhibitors, p21 and p27{sup Kip}, which inhibit cell proliferation by blocking cell cycle progression at G1/S phase, increased after RA treatment. Interestingly, RA promoted cell survival during the differentiation process, hence suggesting a potential mechanism for neuroblastoma resistance to RA therapy. Importantly, we found that the PI3K/AKT pathway is required for RA-induced neuroblastoma cell differentiation. Our results elucidated the molecular mechanism of RA-induced neuroblastoma cellular differentiation, which may be important for developing novel therapeutic strategy against poorly differentiated neuroblastoma.

  7. Integrated simulation of ELM Triggered by Pellet Through Energy Absorption and Transport Enhancement

    E-Print Network [OSTI]

    Integrated simulation of ELM Triggered by Pellet Through Energy Absorption and Transport Enhancement

  8. Integrated Simulation of ELM Triggered by Pellet through Energy Absorption and Transport Enhancement

    E-Print Network [OSTI]

    Integrated Simulation of ELM Triggered by Pellet through Energy Absorption and Transport Enhancement

  9. Integral Field Spectroscopy of AGN Absorption Outflows: Mrk 509 and IRAS F04250-5718

    E-Print Network [OSTI]

    Liu, Guilin; Rupke, David S N

    2015-01-01

    Ultravoilet (UV) absorption lines provide abundant spectroscopic information enabling the probe of the physical conditions in AGN outflows, but the outflow radii (and the energetics consequently) can only be determined indirectly. In this paper, we present the first direct test of these determinations using integral field unit (IFU) spectroscopy. We have conducted Gemini IFU mapping of the ionized gas nebulae surrounding two AGNs, whose outflow radii have been constrained by UV absorption line analyses. In Mrk 509, we find a quasi-spherical outflow with a radius of 1.2 kpc and a velocity of $\\sim290$ km s$^{-1}$, while IRAS F04250$-$5718 is driving a biconical outflow extending out to 2.9 kpc, with a velocity of $\\sim580$ km s$^{-1}$ and an opening angle of $\\sim70^{\\circ}$. The derived mass flow rate is $\\sim5$ and $>1$ M$_{\\odot}$ yr$^{-1}$, respectively, and the kinetic luminosity is $\\gtrsim1\\times10^{41}$ erg s$^{-1}$ for both. Adopting the outflow radii and geometric parameters measured from IFU, absorp...

  10. Propagation and absorption of high-intensity femtosecond laser radiation in diamond

    SciTech Connect (OSTI)

    Kononenko, V V; Konov, V I; Gololobov, V M; Zavedeev, E V [A M Prokhorov General Physics Institute, Russian Academy of Sciences, Moscow (Russian Federation)

    2014-12-31

    Femtosecond interferometry has been used to experimentally study the photoexcitation of the electron subsystem of diamond exposed to femtosecond laser pulses of intensity 10{sup 11} to 10{sup 14} W cm{sup -2}. The carrier concentration has been determined as a function of incident intensity for three harmonics of a Ti : sapphire laser (800, 400 and 266 nm). The results demonstrate that, in a wide range of laser fluences (up to those resulting in surface and bulk graphitisation), a well-defined multiphoton absorption prevails. We have estimated nonlinear absorption coefficients for pulsed radiation at ? = 800 nm (four-photon transition) and at 400 and 266 nm (indirect and direct two-photon transitions, respectively). It has also been shown that, at any considerable path length of a femtosecond pulse in diamond (tens of microns or longer), the laser beam experiences a severe nonlinear transformation, determining the amount of energy absorbed by the lattice, which is important for the development of technology for diamond photostructuring by ultrashort pulses. The competition between wave packet self-focusing and the plasma defocusing effect is examined as a major mechanism governing the propagation of intense laser pulses in diamond. (interaction of laser radiation with matter. laser plasma)

  11. Heating from free-free absorption and the mass-loss rate of the progenitor stars to supernovae

    SciTech Connect (OSTI)

    Björnsson, C.-I.; Lundqvist, P. E-mail: peter@astro.su.se

    2014-06-01

    An accurate determination of the mass-loss rate of the progenitor stars to core-collapse supernovae is often limited by uncertainties pertaining to various model assumptions. It is shown that under conditions when the temperature of the circumstellar medium is set by heating due to free-free absorption, observations of the accompanying free-free optical depth allow a direct determination of the mass-loss rate from observed quantities in a rather model-independent way. The temperature is determined self-consistently, which results in a characteristic time dependence of the free-free optical depth. This can be used to distinguish free-free heating from other heating mechanisms. Since the importance of free-free heating is quite model dependent, this also makes possible several consistency checks of the deduced mass-loss rate. It is argued that the free-free absorption observed in SN 1993J is consistent with heating from free-free absorption. The deduced mass-loss rate of the progenitor star is, approximately, 10{sup –5} M {sub ?} yr{sup –1} for a wind velocity of 10 km s{sup –1}.

  12. Fundamentals of PV Efficiency: Limits for Light Absorption

    E-Print Network [OSTI]

    M. Ryyan Khan; Xufeng Wang; Muhammad A. Alam

    2012-12-13

    A simple thermodynamic argument related to a (weakly absorbing) finite dielectric slab illuminated by sunlight- originally suggested by Yablonovich- leads to the conclusion that the absorption in a dielectric can at best be increased by a factor 4n2. Therefore, the absorption in these materials is always imperfect; the Shockley-Queisser limit can be achieved only asymptotically. In this paper, we make the connection between the degradation in efficiency and the Yablonovich limit explicit and re-derive the 4n2 limit by intuitive geometrical arguments based on Snell's law and elementary rules of probability. Remarkably, the re-derivation suggests strategies of breaking the traditional limit and improving PV efficiency by enhanced light absorption.

  13. System for measuring multiphase flow using multiple pressure differentials

    DOE Patents [OSTI]

    Fincke, James R. (Idaho Falls, ID)

    2003-01-01

    An improved method and system for measuring a multi-phase flow in a pressure flow meter. An extended throat venturi is used and pressure of the multi-phase flow is measured at three or more positions in the venturi, which define two or more pressure differentials in the flow conduit. The differential pressures are then used to calculate the mass flow of the gas phase, the total mass flow, and the liquid phase. The system for determining the mass flow of the high void fraction fluid flow and the gas flow includes taking into account a pressure drop experienced by the gas phase due to work performed by the gas phase in accelerating the liquid phase.

  14. Quantum Differential and Linear Cryptanalysis

    E-Print Network [OSTI]

    Marc Kaplan; Gaëtan Leurent; Anthony Leverrier; María Naya-Plasencia

    2015-10-20

    Quantum computers, that may become available one day, will impact many scientific fields. Cryptography is certainly one of them since many asymmetric primitives would become insecure against an adversary with quantum capabilities. Cryptographers are already anticipating this threat by proposing and studying a number of potentially quantum-safe alternatives for those primitives. On the other hand, the situation of symmetric primitives which seem less vulnerable against quantum computing, has received much less attention. We need to prepare symmetric cryptography for the eventual arrival of the post-quantum world, as it is done with other cryptography branches. Cryptanalysis and security analysis are the only proper way to evaluate the security of symmetric primitives: our trust in specific ciphers relies on their ability to resist all known cryptanalysis tools. This requires a proper investigation of the toolkit of quantum cryptanalysis, that might include radically new attacks. This toolkit has not been much developed so far. In this paper, we study how some of the main cryptanalytic attacks behave in the post-quantum world. More specifically, we consider here quantum versions of differential and linear cryptanalysis. While running Grover's search algorithm on a quantum computer brings a quadratic speedup for brute-force attacks, we show that the situation is more subtle when considering specific cryptanalysis techniques. In particular, we give the quantum version of various classes of differential and linear attacks and show that the best attacks in the classical world do not necessarily lead to the best quantum ones. Some non-intuitive examples of application on ciphers LAC and KLEIN are provided.

  15. Observation of scattering and absorption centers in lead fluoride crystals

    E-Print Network [OSTI]

    Patrick Achenbach

    2006-06-22

    For the first time, lead fluoride is used as a fast and compact material in electromagnetic calorimetry. Excellent optical and mechanical properties of the pure Cherenkov crystals are necessary for the A4 collaboration to perform a measurement of the nucleon's strange form factors. Visible scattering and absorption centers as well as surface damages have been investigated to characterize the quality of more than one thousand crystals. Besides, transmittance measurements have been performed on all crystals to reveal absorption bands produced by intrinsic or impurity related point-structure defects. As a consequence, 89 crystals had to be replaced by the Chinese manufacturer SICCAS.

  16. Broadband Coherent Enhancement of Transmission and Absorption in Disordered Media

    E-Print Network [OSTI]

    Hsu, Chia Wei; Bromberg, Yaron; Stone, A Douglas; Cao, Hui

    2015-01-01

    We study the optimal diffusive transmission and absorption of broadband or polychromatic light in a disordered medium. By introducing matrices describing broadband transmission and reflection, we formulate an extremal eigenvalue problem where the optimal input wavefront is given by the corresponding eigenvector. We show analytically that a single wavefront can exhibit strongly enhanced total transmission or total absorption across a bandwidth that is orders of magnitude broader than the spectral correlation width of the medium, due to long-range correlations in coherent diffusion. We find excellent agreement between the analytic theory and numerical simulations.

  17. Absorption and emission properties of photonic crystals and metamaterials

    SciTech Connect (OSTI)

    Peng, Lili

    2007-08-03

    We study the emission and absorption properties of photonic crystals and metamaterials using Comsol Multiphysics and Ansoft HFSS as simulation tools. We calculate the emission properties of metallic designs using drude model and the results illustrate that an appropriate termination of the surface of the metallic structure can significantly increase the absorption and therefore the thermal emissivity. We investigate the spontaneous emission rate modifications that occur for emitters inside two-dimensional photonic crystals and find the isotropic and directional emissions with respect to different frequencies as we have expected.

  18. Detection of OH absorption against PSR B1718-35

    E-Print Network [OSTI]

    Anthony H. Minter

    2008-01-05

    OH absorption against PSR B1718-35 at (l,b) =351.688,+0.671 has been discovered at 1665 and 1667 MHz using the Green Bank Telescope. The absorption appears to arise at the interface of an HII region and a molecular cloud which are likely associated with the high mass star forming region NGC 6334. Beam dilution is found to be the cause of differences in the opacity of the OH against the Galactic background continuum emission and against the pulsar. The OH cloud is approximately 3 by 1.3 pc and is located behind the HII region.

  19. Effect of level of dietary calcium and phosphorus on the site of absorption and utilization of phosphorus in gestating and lactating ruminants 

    E-Print Network [OSTI]

    Barrett, Robert Clay

    2002-01-01

    Two digestion trials were conducted to determine the effect of level of Ca and P on the site and extent of absorption of P in gestating and lactating ruminants. Gestating Nubian dairy nannies (n=8; 41-55 kg) with abomasal ...

  20. Mechanism involved in enhancement of osteoblast differentiation by hyaluronic acid

    SciTech Connect (OSTI)

    Kawano, Michinao [Division of Maxillofacial Diagnostic and Surgical Science, Department of Oral and Maxillofacial Surgery, Kyushu Dental College, Kitakyushu 803-8580 (Japan) [Division of Maxillofacial Diagnostic and Surgical Science, Department of Oral and Maxillofacial Surgery, Kyushu Dental College, Kitakyushu 803-8580 (Japan); Division of Infections and Molecular Biology, Department of Health Promotion, Kyushu Dental College, Kitakyushu 803-8580 (Japan); Ariyoshi, Wataru [Division of Infections and Molecular Biology, Department of Health Promotion, Kyushu Dental College, Kitakyushu 803-8580 (Japan)] [Division of Infections and Molecular Biology, Department of Health Promotion, Kyushu Dental College, Kitakyushu 803-8580 (Japan); Iwanaga, Kenjiro [Division of Maxillofacial Diagnostic and Surgical Science, Department of Oral and Maxillofacial Surgery, Kyushu Dental College, Kitakyushu 803-8580 (Japan)] [Division of Maxillofacial Diagnostic and Surgical Science, Department of Oral and Maxillofacial Surgery, Kyushu Dental College, Kitakyushu 803-8580 (Japan); Okinaga, Toshinori [Division of Infections and Molecular Biology, Department of Health Promotion, Kyushu Dental College, Kitakyushu 803-8580 (Japan)] [Division of Infections and Molecular Biology, Department of Health Promotion, Kyushu Dental College, Kitakyushu 803-8580 (Japan); Habu, Manabu [Division of Maxillofacial Diagnostic and Surgical Science, Department of Oral and Maxillofacial Surgery, Kyushu Dental College, Kitakyushu 803-8580 (Japan)] [Division of Maxillofacial Diagnostic and Surgical Science, Department of Oral and Maxillofacial Surgery, Kyushu Dental College, Kitakyushu 803-8580 (Japan); Yoshioka, Izumi [Division of Oral and Maxillofacial Surgery, Department of Medicine of Sensory and Motor Organs, University of Miyazaki, Kiyotake, Miyazaki 889-1692 (Japan)] [Division of Oral and Maxillofacial Surgery, Department of Medicine of Sensory and Motor Organs, University of Miyazaki, Kiyotake, Miyazaki 889-1692 (Japan); Tominaga, Kazuhiro [Division of Maxillofacial Diagnostic and Surgical Science, Department of Oral and Maxillofacial Surgery, Kyushu Dental College, Kitakyushu 803-8580 (Japan) [Division of Maxillofacial Diagnostic and Surgical Science, Department of Oral and Maxillofacial Surgery, Kyushu Dental College, Kitakyushu 803-8580 (Japan); Oral Bioresearch Center, Kyushu Dental College, Kitakyushu 803-8580 (Japan); Nishihara, Tatsuji, E-mail: tatsujin@kyu-dent.ac.jp [Division of Infections and Molecular Biology, Department of Health Promotion, Kyushu Dental College, Kitakyushu 803-8580 (Japan) [Division of Infections and Molecular Biology, Department of Health Promotion, Kyushu Dental College, Kitakyushu 803-8580 (Japan); Oral Bioresearch Center, Kyushu Dental College, Kitakyushu 803-8580 (Japan)

    2011-02-25

    Research highlights: {yields} In this study was to investigate the effects of HA on osteoblast differentiation induced by BMP-2. {yields} MG63 cells were incubated with BMP-2 and HA for various time periods. {yields} Phosphorylation of Smad 1/5/8, p38, and ERK proteins was determined by western blot analysis. To elucidate the nuclear translocation of phosphorylated Smad 1/5/8, stimulated cells were subjected to immunofluorescence microscopy. {yields} HA enhanced BMP-2 induces osteoblastic differentiation in MG63 cells via down-regulation of BMP-2 antagonists and ERK phosphorylation. -- Abstract: Objectives: Bone morphogenetic protein-2 (BMP-2) is expected to be utilized to fill bone defects and promote healing of fractures. However, it is unable to generate an adequate clinical response for use in bone regeneration. Recently, it was reported that glycosaminoglycans, including heparin, heparan sulfate, keratan sulfate, dermatan sulfate, chondroitin-4-sulfate, chondroitin-6-sulfate, and hyaluronic acid (HA), regulate BMP-2 activity, though the mechanism by which HA regulates osteogenic activities has not been fully elucidated. The aim of this study was to investigate the effects of HA on osteoblast differentiation induced by BMP-2. Materials and methods: Monolayer cultures of osteoblastic lineage MG63 cells were incubated with BMP-2 and HA for various time periods. To determine osteoblastic differentiation, alkaline phosphatase (ALP) activity in the cell lysates was quantified. Phosphorylation of Smad 1/5/8, p38, and ERK proteins was determined by Western blot analysis. To elucidate the nuclear translocation of phosphorylated Smad 1/5/8, stimulated cells were subjected to immunofluorescence microscopy. To further elucidate the role of HA in enhancement of BMP-2-induced Smad signaling, mRNA expressions of the BMP-2 receptor antagonists noggin and follistatin were detected using real-time RT-PCR. Results: BMP-2-induced ALP activation, Smad 1/5/8 phosphorylation, and nuclear translocation were up-regulated when MG63 cells were cultured with both BMP-2 and HA. Western blot analysis revealed that phosphorylation of ERK protein was diminished by HA. Furthermore, the mRNA expressions of noggin and follistatin induced by BMP-2 were preferentially blocked by HA. Conclusions: These results indicate that HA enhanced BMP-2 induces osteoblastic differentiation in MG63 cells via down-regulation of BMP-2 antagonists and ERK phosphorylation.

  1. Standard test method for non-destructive assay of nuclear material in waste by passive and active neutron counting using a differential Die-away system

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2009-01-01

    1.1 This test method covers a system that performs nondestructive assay (NDA) of uranium or plutonium, or both, using the active, differential die-away technique (DDT), and passive neutron coincidence counting. Results from the active and passive measurements are combined to determine the total amount of fissile and spontaneously-fissioning material in drums of scrap or waste. Corrections are made to the measurements for the effects of neutron moderation and absorption, assuming that the effects are averaged over the volume of the drum and that no significant lumps of nuclear material are present. These systems are most widely used to assay low-level and transuranic waste, but may also be used for the measurement of scrap materials. The examples given within this test method are specific to the second-generation Los Alamos National Laboratory (LANL) passive-active neutron assay system. 1.1.1 In the active mode, the system measures fissile isotopes such as 235U and 239Pu. The neutrons from a pulsed, 14-MeV ne...

  2. HI emission and absorption in nearby, gas-rich galaxies

    E-Print Network [OSTI]

    Reeves, S N; Allison, J R; Koribalski, B S; Curran, S J; Pracy, M B

    2015-01-01

    We present the results of a targeted search for intervening HI absorption in six nearby, gas-rich galaxies using the Australia Telescope Compact Array (ATCA). The sightlines searched have impact parameters of 10-20 kpc. By targeting nearby galaxies we are also able to map their HI emission, allowing us to directly relate the absorption-line detection rate to the extended HI distribution. The continuum sightlines intersect the HI disk in four of the six galaxies, but no intervening absorption was detected. Of these four galaxies, we find that three of the non-detections are the result of the background source being too faint. In the fourth case we find that the ratio of the spin temperature to the covering factor ($T_{\\mathrm{S}}/f$) must be much higher than expected ($\\gtrsim$5700 K) in order to explain the non-detection. We discuss how the structure of the background continuum sources may have affected the detection rate of HI absorption in our sample, and the possible implications for future surveys. Future...

  3. Carbon Dioxide Capture by Chemical Absorption: A Solvent Comparison Study

    E-Print Network [OSTI]

    of the requirements of the Degree of Doctor of Philosophy in Chemical Engineering Practice Abstract In the light1 Carbon Dioxide Capture by Chemical Absorption: A Solvent Comparison Study by Anusha Kothandaraman B. Chem. Eng. Institute of Chemical Technology, University of Mumbai, 2005 M.S. Chemical Engineering

  4. WEATHER MODIFICATION BY CARBON DUST ABSORPTION OF SOLAR ENERGY

    E-Print Network [OSTI]

    Gray, William

    WEATHER MODIFICATION BY CARBON DUST ABSORPTION OF SOLAR ENERGY by WM. M. GRAY, WM. M. FRANK, M OF SOLAR ENERGY by w. M. Gray, W. M. Frank, M. L. Corrin and C. A. Stokes Department of Atmospheric Science interception of solar energy. Growing population pressures and predicted future global food shortages dictate

  5. Quantum delocalization directs antenna absorption to photosynthetic reaction centers

    E-Print Network [OSTI]

    Felipe Caycedo-Soler; Chris A. Schroeder; Caroline Autenrieth; Robin Ghosh; Susana F. Huelga; Martin B. Plenio

    2015-04-22

    Photosynthesis -- the conversion of sunlight to chemical energy -- is fundamental for supporting life on our planet. Despite its importance, the physical principles that underpin the primary steps of photosynthesis, from photon absorption to electronic charge separation, remain to be understood in full. Previously, electronic coherence within tightly-packed light-harvesting (LH) units or within individual reaction centers (RCs) has been recognized as an important ingredient for a complete understanding of the excitation energy transfer dynamics. However, the electronic coherence across RC and LH units has been consistently neglected as it does not play a significant role during these relatively slow transfer processes. Here, we turn our attention to the absorption process, which occurs on much shorter timescales. We demonstrate that the - often overlooked - spatially extended but short-lived excitonic delocalization across RC and LH units plays a relevant role in general photosynthetic systems, as it causes a redistribution of direct absorption towards the charge separation unit. Using the complete core complex of Rhodospirillum rubrum, we verify experimentally an 80 % increase in the direct optical absorption of the RC in situ as compared to isolated RCs. Numerical calculations reveal that similar enhancements can be expected for a wide variety of photosynthetic units in both plant and bacterial systems, suggesting that this mechanism is conserved across species and providing a clear new design principle for light-harvesting nanostructures

  6. An Economic Analysis of Industrial Absorption Heat Pumps 

    E-Print Network [OSTI]

    Kaplan, S. I.; Huntley, W. R.; Perez-Blanco, H.

    1985-01-01

    OF INDUSlRIAL ABSORPl'ION HEAT PUMPS- Horacio Perez-Blanco S. I. Kaplan W. R. Huntley Oak Ridge National Laboratory Oak Ridge, Tennessee ABSlRAcr The interest in industrial absorption heat pumps in Japan raises a number of important qnes...

  7. Absorptive separation of NO from dilute off-gas

    SciTech Connect (OSTI)

    Zapfel, W.; Marr, R.; Siebenhofer, M.

    1999-04-01

    With regard to its negligible absorption properties, the separation of nitrogen monoxide from dilute off-gas is limited to bench-scale experiments. Investigation has been centered on improving the rate of absorption by the use of complex-forming additives based on iron(II) compounds. Further efforts have been made to improve the separation efficiency by the use of reactive additives. Due to the low reactivity of nitrogen monoxide, these attempts did not succeed. The oxidation of moderately concentrated off-gas with ozone and the absorption of the so-formed nitrogen dioxide have been reported. Technical as well as economical considerations do not permit the application of the process to the treatment of dilute off-gas. The principle underlying this process led to the investigation of direct oxidation of the off-gas under electrical discharge followed by absorption with aqueous diamide solution. Temperature and moisture of the off-gas have been considered, in addition to various feed contents of nitrogen monoxide. The results of this investigation show that direct oxidation of nitrogen monoxide by corona discharge is possible. The rate of conversion increases with increasing gas velocity, accompanied by a decreasing specific energy consumption. Applied to tunnel off-gas purification, the direct oxidation route seems to offer promising technical boundaries as it is accompanied by efficient particle separation.

  8. Constraining FeLoBAL outflows from absorption line variability

    E-Print Network [OSTI]

    McGraw, S M; Hamann, F W; Capellupo, D M; Gallagher, S C; Brandt, W N

    2015-01-01

    FeLoBALs are a rare class of quasar outflows with low-ionization broad absorption lines (BALs), large column densities, and potentially large kinetic energies that might be important for `feedback' to galaxy evolution. In order to probe the physical properties of these outflows, we conducted a multiple-epoch, absorption line variability study of 12 FeLoBAL quasars spanning a redshift range between 0.7 and 1.9 over rest frame time-scales of approximately 10 d to 7.6 yr. We detect absorption line variability with greater than 8 sigma confidence in 3 out of the 12 sources in our sample over time-scales of 0.6 to 7.6 yr. Variable wavelength intervals are associated with ground and excited state Fe II multiplets, the Mg II 2796, 2803 doublet, Mg I 2852, and excited state Ni II multiplets. The observed variability along with evidence of saturation in the absorption lines favors transverse motions of gas across the line of sight (LOS) as the preferred scenario, and allows us to constrain the outflow distance from th...

  9. Atomic Absorption Spectrometry Perkin Elmer 500, Chemistry & Biochemistry

    E-Print Network [OSTI]

    Gruner, Daniel S.

    Atomic Absorption Spectrometry · Perkin Elmer 500, Chemistry & Biochemistry · Perkin Elmer 560 AA calorimeter, Chemistry & Biochemistry Cell Sorting and Harvesting · B-D FacsCalibur - cell sorter, CBMG · Cell Ultracentrifuge with Scanning UV/Vis Absorbance and Rayleigh Interference, Chemistry & Biochemistry · Beckman J-6B

  10. Atomistic Models for the absorption of Oil Production Chemicals on

    E-Print Network [OSTI]

    Goddard III, William A.

    Atomistic Models for the absorption of Oil Production Chemicals on Clay minerals Sungu Hwang, Mario The atomistic simulation of the minerals in oil production Prediction of the performance of the oil production: a model for oil -19 -18 -17 -16 -15 -14 0 0.2 0.4 0.6 0.8 1 Coverage Bindingenergyper adsorbate

  11. Methods for deacidizing gaseous mixtures by phase enhanced absorption

    DOE Patents [OSTI]

    Hu, Liang

    2012-11-27

    An improved process for deacidizing a gaseous mixture using phase enhanced gas-liquid absorption is described. The process utilizes a multiphasic absorbent that absorbs an acid gas at increased rate and leads to reduced overall energy costs for the deacidizing operation.

  12. The Influence of Dust on the Absorptivity of Radiant Barriers 

    E-Print Network [OSTI]

    Noboa, Homero L.

    1993-01-01

    The purpose of this project was to model and quantify the increase of the absorptivity of radiant barriers caused by the accumulation of dust on the surface of radiant barriers. This research was the continuation of a previous work by the author...

  13. CO2 Capture by Absorption with Potassium Carbonate

    E-Print Network [OSTI]

    Rochelle, Gary T.

    CO2 Capture by Absorption with Potassium Carbonate Third Quarterly Report 2005 Quarterly Progress. #12;3 Abstract The objective of this work is to improve the process for CO2 capture by alkanolamine transfer area as IMTP#40 dumped packing. Independent measurements of CO2 solubility give a CO2 loading

  14. XRAY LINES AND ABSORPTION EDGES IN GRBS AND THEIR AFTERGLOWS

    E-Print Network [OSTI]

    Boettcher, Markus

    of Physics and Astronomy, Ohio University, Athens, OH 45701, USA ABSTRACT Absorption and Reprocessing of the reprocessing and/or absorbing material. To date, there have been only rather few detections of such features those results impose on isotropy, homogeneity, and location of the reprocessing material with respect

  15. Simulations of solar cell absorption enhancement using resonant modes

    E-Print Network [OSTI]

    Grandidier, Jonathan

    for enhancing the absorption of thin-film amorphous silicon solar cells using periodic arrangements of resonant,7 Dielectric nanospheres are promising structures for light trapping in planar, thin-film solar cells. It has a thin-film a-Si solar cell structure featuring back reflector and optimized anti-reflection coating. We

  16. Switched differential algebraic equations Stephan Trenn

    E-Print Network [OSTI]

    Trenn, Stephan

    Switched differential algebraic equations Stephan Trenn Abstract In this chapter an electrical circuit with switches is modeled as a switched differential algebraic equation (switched DAE), i.e. each is the input. The resulting time-variance follows from the action of the switches present in the circuit

  17. Model solution State variable model: differential equation

    E-Print Network [OSTI]

    Limburg, Karin E.

    2/26/2014 1 Model solution State variable model: differential equation Models a rate of change equation General solution: the antiderivative Particular solution: require initial and boundary conditions up the general solution to a differential equation in a book Solve for initial and boundary

  18. Differential Addition in generalized Edwards Coordinates

    E-Print Network [OSTI]

    International Association for Cryptologic Research (IACR)

    and Corollary 1, as explained at the end of section 3. Table 1. Some coordinate choices with fast arithmeticDifferential Addition in generalized Edwards Coordinates Benjamin Justus and Daniel Loebenberger (1 + dx2 y2 ) that omit the x- coordinate. The first parametrization leads to a differential addition

  19. The twin spot generator for differential Drosophila

    E-Print Network [OSTI]

    Cai, Long

    The twin spot generator for differential Drosophila lineage analysis Ruth Griffin1, Anne Sustar2­ based strategies generate mosaic flies with positive readout for only one daughter cell after division. To differentially label both daughter cells, we developed the twin spot generator (TSG) technique, which through

  20. On production costs in vertical differentiation models

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    EA 4272 On production costs in vertical differentiation models Dorothée BRECARD(*) 2009,version1-1Oct2009 #12;1 On production costs in vertical differentiation models Dorothée Brécard production cost beside a fixed cost of quality improvement in a duopoly model of vertical product

  1. Measurement of the absorption coefficient for light laterally propagating in light-emitting diode structures with In{sub 0.2}Ga{sub 0.8}N/GaN quantum wells

    SciTech Connect (OSTI)

    Lelikov, Yu. S.; Bochkareva, N. I.; Gorbunov, R. I.; Martynov, I. A.; Rebane, Yu. T.; Tarkin, D. V.; Shreter, Yu. G. [Russian Academy of Sciences, Ioffe Physicotechnical Institute (Russian Federation)], E-mail: YShreter@mail.ioffe.ru

    2008-11-15

    A procedure for measuring the absorption coefficient for light propagating parallel to the surface of a GaN-based light emitting diode chip on a sapphire substrate is suggested. The procedure implies the study of emission from one end face of the chip as the opposite end face is illuminated with a light emitting diode. The absorption coefficient is calculated from the ratio between the intensities of emission emerging from the end faces of the sapphire substrate and the epitaxial layer. From the measurements for chips based on p-GaN/In{sub 0.2}Ga{sub 0.8}N/n-GaN structures, the lateral absorption coefficient is determined at a level of (23 {+-} 3)cm{sup -1} at a wavelength of 465 nm. Possible causes for the discrepancy between the absorption coefficients determined in the study and those reported previously are analyzed.

  2. Facilely preparation and microwave absorption properties of Fe{sub 3}O{sub 4} nanoparticles

    SciTech Connect (OSTI)

    Wang, Guiqin, E-mail: wanggq@dlut.edu.cn [School of Materials Science and Engineering, Dalian University of Technology, Dalian 116085 (China); Chang, Yongfeng; Wang, Lifang; Liu, Lidong; Liu, Chao [School of Materials Science and Engineering, Dalian University of Technology, Dalian 116085 (China)

    2013-03-15

    Highlights: ? A bran-new method is firstly used to fabricate Fe{sub 3}O{sub 4} nanoparticles. ? The detailed analysis of formation mechanism is discussed. ? The electromagnetic absorption properties are defined. ? The effect of nanometer-sized is considered for the excellent microwave absorption. - Abstract: The Fe{sub 3}O{sub 4} nanoparticles were prepared by a novel wet-chemical method which shows its highly synthesizing efficiency and controllability. A possible formation mechanism was also proposed to explain the synthesizing process. X-ray diffraction (XRD) and transmission electron microscope (TEM) were employed and yielded an examination of an average diameter of 77 nm of the as-synthesized Fe{sub 3}O{sub 4} nanoparticles with face-centered cubic structure. Vibrating sample magnetometer (VSM) and vector network analyzer were employed to measure the magnetic property and electromagnetic parameters of the nanoparticles, then reflection losses (RL (dB)) were calculated in the frequency range of 2–18 GHz. A large saturation magnetization (72.36 emu/g) and high coercivity (95 Oe) were determined and indicated that the Fe{sub 3}O{sub 4} nanoparticles own strong magnetic performance. Following simulation results showed that the lowest reflection loss of the sample was ?21.2 dB at 5.6 GHz with layer thickness of 6 mm. Effect of nanometer-sized further provided an explanation for the excellent microwave absorption behavior shown by the Fe{sub 3}O{sub 4} nanoparticles.

  3. Novel insight into the hydrogen absorption mechanism at the Pd(110) surface

    SciTech Connect (OSTI)

    Ohno, Satoshi E-mail: wilde@iis.u-tokyo.ac.jp; Wilde, Markus E-mail: wilde@iis.u-tokyo.ac.jp; Fukutani, Katsuyuki

    2014-04-07

    The microscopic mechanism of low-temperature (80 K < T < 160 K) hydrogen (H) ingress into the H{sub 2} (<2.66 × 10{sup ?3} Pa) exposed Pd(110) surface is explored by H depth profiling with {sup 15}N nuclear reaction analysis (NRA) and thermal desorption spectroscopy (TDS) with isotope (H, D) labeled surface hydrogen. NRA and TDS reveal two types of absorbed hydrogen states of distinctly different depth distributions. Between 80 K and ?145 K a near-surface hydride phase evolving as the TDS ?{sub 1} feature at 160 K forms, which initially extends only several nanometers into depth. On the other hand, a bulk-absorbed hydrogen state develops between 80 K and ?160 K which gives rise to a characteristic ?{sub 3} TDS feature above 190 K. These two absorbed states are populated at spatially separated surface entrance channels. The near-surface hydride is populated through rapid penetration at minority sites (presumably defects) while the bulk-absorbed state forms at regular terraces with much lower probability per site. In both cases, absorption of gas phase hydrogen transfers pre-adsorbed hydrogen atoms below the surface and replaces them at the chemisorption sites by post-dosed hydrogen in a process that requires much less activation energy (<100 meV) than monatomic diffusion of chemisorbed H atoms into subsurface sites. This small energy barrier suggests that the rate-determining step of the absorption process is either H{sub 2} dissociation on the H-saturated Pd surface or a concerted penetration mechanism, where excess H atoms weakly bound to energetically less favorable adsorption sites stabilize themselves in the chemisorption wells while pre-chemisorbed H atoms simultaneously transit into the subsurface. The peculiarity of absorption at regular Pd(110) terraces in comparison to Pd(111) and Pd(100) is discussed.

  4. Calculation of the spatial resolution in two-photon absorption spectroscopy applied to plasma diagnosis

    SciTech Connect (OSTI)

    Garcia-Lechuga, M.; Fuentes, L. M.; Grützmacher, K.; Pérez, C. Rosa, M. I. de la

    2014-10-07

    We report a detailed characterization of the spatial resolution provided by two-photon absorption spectroscopy suited for plasma diagnosis via the 1S-2S transition of atomic hydrogen for optogalvanic detection and laser induced fluorescence (LIF). A precise knowledge of the spatial resolution is crucial for a correct interpretation of measurements, if the plasma parameters to be analysed undergo strong spatial variations. The present study is based on a novel approach which provides a reliable and realistic determination of the spatial resolution. Measured irradiance distribution of laser beam waists in the overlap volume, provided by a high resolution UV camera, are employed to resolve coupled rate equations accounting for two-photon excitation, fluorescence decay and ionization. The resulting three-dimensional yield distributions reveal in detail the spatial resolution for optogalvanic and LIF detection and related saturation due to depletion. Two-photon absorption profiles broader than the Fourier transform-limited laser bandwidth are also incorporated in the calculations. The approach allows an accurate analysis of the spatial resolution present in recent and future measurements.

  5. H I 21 cm ABSORPTION AND UNIFIED SCHEMES OF ACTIVE GALACTIC NUCLEI

    SciTech Connect (OSTI)

    Curran, S. J.; Whiting, M. T.

    2010-03-20

    In a recent study of z >= 0.1 active galactic nuclei (AGNs), we found that 21 cm absorption has never been detected in objects in which the ultraviolet luminosity exceeds L{sub UV} {approx} 10{sup 23} W Hz{sup -1}. In this paper, we further explore the implications that this has for the currently popular consensus that it is the orientation of the circumnuclear obscuring torus, invoked by unified schemes of AGNs, which determines whether absorption is present along our sight line. The fact that at L{sub UV} {approx}< 10{sup 23} W Hz{sup -1}, both type-1 and type-2 objects exhibit a 50% probability of detection, suggests that this is not the case and that the bias against detection of H I absorption in type-1 objects is due purely to the inclusion of the L{sub UV} {approx}> 10{sup 23} W Hz{sup -1} sources. Similarly, the ultraviolet luminosities can also explain why the presence of 21 cm absorption shows a preference for radio galaxies over quasars and the higher detection rate in compact sources, such as compact steep spectrum or gigahertz peaked spectrum sources, may also be biased by the inclusion of high-luminosity sources. Being comprised of all 21 cm searched sources at z >= 0.1, this is a necessarily heterogeneous sample, the constituents of which have been observed by various instruments. By this same token, however, the dependence on the UV luminosity may be an all encompassing effect, superseding the unified schemes model, although there is the possibility that the exclusive 21 cm non-detections at high UV luminosities could be caused by a bias toward gas-poor ellipticals. Additionally, the high UV fluxes could be sufficiently exciting/ionizing the H I above 21 cm detection thresholds, although the extent to which this is related to the neutral gas deficit in ellipticals is currently unclear. Examining the moderate UV luminosity (L{sub UV} {approx}< 10{sup 23} W Hz{sup -1}) sample further, from the profile widths and offsets from the systemic velocities, we find no discernible differences between the two AGN types. This may suggest that the bulk of the absorption generally occurs in the galactic disk, which must therefore be randomly orientated with respect to the circumnuclear torus. Furthermore, we see no difference in the reddening between the two AGN types, indicating, like the 21 cm absorption, that the orientation of the torus has little bearing on this. We also find a correlation between 21 cm line strength and the optical-near-infrared color, which suggests that the reddening is caused by dust located in the large-scale, H I absorbing disk which intervenes the sight line to the AGN.

  6. 74 MHz Discrete HII Absorption Regions Towards The Inner Galaxy

    E-Print Network [OSTI]

    Michael E. Nord; P. A. Henning; R. J. Rand; T. Joseph W. Lazio; Namir E. Kassim

    2006-03-02

    At low radio frequencies ( 1) and can be observed as discrete absorption regions against the Galactic nonthermal background emission created by Galactic cosmic ray electrons spiraling around magnetic fields. In this work we present 74 MHz observations in the region 26>l>-15, -5absorption features associated with known HII regions, and derive the brightness temperature of the Galactic cosmic ray electron synchrotron emission emanating from the column behind these regions. For the 42 HII regions with known distances, the average emissivity of the column behind the HII region is derived. 74 MHz emissivity values range between 0.3 and 1.0 Kelvin per parsec for a model assuming uniform distribution of emissivity. Methods for utilizing this type of data to model the 3-dimensional distribution of cosmic ray emissivity and the possibility of using this method to break the HII region kinematic distance degeneracy are discussed.

  7. Graphene plasmonics for light trapping and absorption engineering

    E-Print Network [OSTI]

    Zhang, Jianfa; Liu, Wei; Yuan, Xiaodong; Qin, Shiqiao

    2015-01-01

    Plasmonics can be used to improve absorption in optoelectronic devices and has been intensively studied for solar cells and photodetectors. Graphene has recently emerged as a powerful plasmonic material. It shows significantly less losses compared to traditional plasmonic materials such as gold and silver and its plasmons can be tuned by changing the Fermi energy with chemical or electrical doping. Here we propose the usage of graphene plasmonics for light trapping in optoelectronic devices and show that the excitation of localized plasmons in doped, nanostructured graphene can enhance optical absorption in its surrounding media including both bulky and two-dimensional materials by tens of times, which may lead to a new generation of highly efficient, spectrally selective photodetectors in mid-infrared and THz ranges. The proposed concept could even revolutionize the field of plasmonic solar cells if graphene plasmons in the visible and near-infrared are realized.

  8. Broadband reflectionless metasheets: Frequency-selective transmission and perfect absorption

    E-Print Network [OSTI]

    Asadchy, V S; Ra'di, Y; Khakhomov, S A; Semchenko, I V; Tretyakov, S A

    2015-01-01

    Energy of propagating electromagnetic waves can be fully absorbed in a thin lossy layer, but only in a narrow frequency band, as follows from the causality principle. On the other hand, it appears that there are no fundamental limitations on broadband matching of thin absorbing layers. However, known thin absorbers produce significant reflections outside of the resonant absorption band. In this paper we explore possibilities to realize a thin absorbing layer which produces no reflected waves in a very wide frequency range, while the transmission coefficient has a narrow peak of full absorption. Here we show, both theoretically and experimentally, that a wide-band-matched thin resonant absorber, invisible in reflection, can be realized if one and the same resonant mode of the absorbing array unit cells is utilized to create both electric and magnetic responses. We test this concept using chiral particles in each unit cells, arranged in a periodic planar racemic array, utilizing chirality coupling in each unit ...

  9. Method for making a photodetector with enhanced light absorption

    DOE Patents [OSTI]

    Kane, James (Lawrenceville, NJ)

    1987-05-05

    A photodetector including a light transmissive electrically conducting layer having a textured surface with a semiconductor body thereon. This layer traps incident light thereby enhancing the absorption of light by the semiconductor body. A photodetector comprising a textured light transmissive electrically conducting layer of SnO.sub.2 and a body of hydrogenated amorphous silicon has a conversion efficiency about fifty percent greater than that of comparative cells. The invention also includes a method of fabricating the photodetector of the invention.

  10. The resonance absorption probability function for neutron and multiplicative integral

    E-Print Network [OSTI]

    V. D. Rusov; V. A. Tarasov; S. I. Kosenko; S. A. Chernegenko

    2012-08-05

    The analytical approximations for the moderating neutrons flux density like Fermi spectra, widely used in reactor physics, involve the probability function for moderating neutron to avoid the resonant absorption obtained using some restrictive assumptions regarding the acceptable resonances width. By means of multiplicative integral (Volterra integral) theory for a commutative algebra an analytical expression for the probability function is obtained rigorously without any restrictive assumptions.

  11. Quantum fluctuations and saturable absorption in mesoscale lasers

    SciTech Connect (OSTI)

    Roy-Choudhury, Kaushik [Department of Physics and Astronomy, University of Southern California, Los Angeles, California 90089-0484 (United States); Levi, A. F. J. [Department of Physics and Astronomy, University of Southern California, Los Angeles, California 90089-0484 (United States); Department of Electrical Engineering, University of Southern California, Los Angeles, California 90089-2533 (United States)

    2011-04-15

    We present a quantum-mechanical treatment of fluctuations and saturable absorption in mesoscale lasers. The time evolution of the density matrix is obtained from numerical integration and field-field and intensity-intensity correlations are calculated to obtain steady-state linewidth and photon statistics. Inclusion of a saturable absorber in the otherwise homogeneous medium is shown to suppress lasing, increase fluctuations, and enhance spontaneous emission near threshold.

  12. Demand Side Management (DSM) Through Absorption Refrigeration Systems 

    E-Print Network [OSTI]

    Chao, P. Y.; Shukla, D.; Amarnath, A.; Mergens, E.

    1992-01-01

    will be illustrated by two recent case studies. INTRODUCTION This paper deals with a Demand Side Management (DSM) option of using waste heat for refrigeration. Absorption Refrigeration from waste heat offers a viable option for DSM. This can profitably either... years. The potential for avoided cost through DSM will approach $45 billion over the next decade(1,2). Waste Energy And Pollutants The U.S. industry consumes more than 30 quads (quadrillion Btu) of energy each year. About one third...

  13. High redshift star-forming galaxies in absorption and emission

    E-Print Network [OSTI]

    Quider, Anna Marie

    2011-07-12

    galaxy spectra. An alternative to investigating galaxies by collecting their light is to study them as seen in absorption against a cosmic backlight, such as a quasar. The Sloan Digital Sky Survey, an imaging and spectroscopic survey which covers about... Processing 23 2.1 Keck Telescopes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 23 2.1.1 Echellette Spectrograph and Imager (ESI) . . . . . . . . . . . . . 23 2.1.2 DEep Imaging Multi-Object Spectrograph (DEIMOS) . . . . . . . 32 2.2 Sloan...

  14. Active Reflection Absorption for a Three Dimensional Multidirectional Wave Generator 

    E-Print Network [OSTI]

    Cruz Castro, Oscar

    2010-10-12

    set of independent wave paddles (flume wave makers) working together in parallel, using 2D ARA (1D filters) to create a multidirectional wavemaker with wave absorption capability. Therefore, no information on directionality of reflected waves... in considerable damping of the reflected waves is achieved compared to not using anything at all in a multidirectional wavemaker. Also the use of electronic analog filters, for the ARA loop, support these approaches. On the other hand, Fully-3D ARA systems...

  15. CO2 Capture by Absorption with Potassium Carbonate

    E-Print Network [OSTI]

    Rochelle, Gary T.

    CO2 Capture by Absorption with Potassium Carbonate Fourth Quarterly Report 2005 Quarterly Progress. #12;3 Abstract The objective of this work is to improve the process for CO2 capture by alkanolamine from 0.06 to 0.01 mol/(m3 .s.kPa) as the rich loading increased from 0.45 to 0.6 mol CO2/ mol MEA

  16. Collision-induced vibrational absorption in molecular hydrogens

    SciTech Connect (OSTI)

    Reddy, S.P.

    1993-05-01

    Collision induced absorption (CIA) spectra of the first overtone bands of H{sub 2}, D{sub 2}, and HD have been recorded for gas densities up to 500 amagat at 77-300 K. Analyses of these spectra reveal that (1) contrary to the observations in the fundamental bands, the contribution of the isotropic overlap interaction to the first overtone bands is negligible, (2) the squares of the matrix elements B{sub 32}(R)/ea{sub o} [= {lambda}{sub 32} exp(-(R-{sigma})/{rho}{sub 32}) + 3 (R/a{sub o}){sup -4}] where the subscripts 3 and 2 represent L and {lambda}, respectively, account for the absorption intensity of the bands and (3) the mixed term, 2,3 {lambda}{sub 32} exp (-(R-{sigma})/{rho}{sub 32}) <{vert_bar}Q{vert_bar}> <{alpha}> (R/a){sup -4}, gives a negative contribution. In the CIA spectra of H{sub 2} in its second overtone region recorded at 77, 201 and 298 K for gas densities up to 1000 amagat, a dip in the Q branch with characteristic Q{sub p} and Q{sub R} components has been observed. The analysis of the absorption profiles reveals, in addition to the previously known effects, the occurrence of the triple-collision transitions of H{sub 2} of the type Q{sub 1}(J) + Q{sub 1}(J) + Q{sub 1}(J) for the first time. From the profile analysis the absorption coefficient of these transitions is obtained.

  17. Links among Impossible Differential, Integral and Zero Correlation Linear Cryptanalysis

    E-Print Network [OSTI]

    International Association for Cryptologic Research (IACR)

    Links among Impossible Differential, Integral and Zero Correlation Linear Cryptanalysis Bing Sun1 cryptanalytic methods, impossible differential cryptanalysis and integral cryptanalysis have attracted much this gap and establish links between impossible differential cryptanalysis and integral cryptanalysis

  18. USE OF ZEEMAN ATOMIC ABSORPTION SPECTROSCOPY FOR THE MEASUREMENT OF MERCURY IN OIL SHALE GASES

    E-Print Network [OSTI]

    Girvin, D.G.

    2011-01-01

    is heated to 900°C in the furnace-absorption tube assemblybackground correction; a furnace-absorption tube assemblyo) / II Linear polarizer a furnace I I I Lightpath~~/---,

  19. Design Considerations, Installation and Operation of the Two-Stage Parallel Flow Absorption Chiller 

    E-Print Network [OSTI]

    Hufford, P. E.

    1984-01-01

    process heat recovery. The high performance (COP = 1.14), and reduced maintenance cost of the two-stage parallel flow absorption chiller provides a notable improvement over the conventional single stage absorption chillers (COP = .6). The infamous...

  20. A Study on the Durability of Flexible Pavement Materials: Asphalt Absorption and Oxidation Kinetics 

    E-Print Network [OSTI]

    Liu, Guanlan

    2015-08-10

    affecting pavement durability are the absorption of asphalt into porous aggregates and the hardening of asphalt due to oxidation. Asphalt absorption reduces the effective binder content in the pavement. Meanwhile, the oxidative hardening of asphalt...

  1. Comparison of solvents for post-combustion capture of CO2 by chemical absorption

    E-Print Network [OSTI]

    Kothandaraman, Anusha

    Post combustion absorption technologies represent one of the most commercially ready technologies for CO2 capture. Solvent selection is the critical consideration in post-combustion absorption capture technology. In order ...

  2. Guide to Developing Air-Cooled Lithium Bromide (LiBr) Absorption...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Guide to Developing Air-Cooled Lithium Bromide (LiBr) Absorption for CHP Applications, April 2005 Guide to Developing Air-Cooled Lithium Bromide (LiBr) Absorption for CHP...

  3. Investigation of sub-bandgap absorption in iron pyrite : optical and electrical measurements

    E-Print Network [OSTI]

    Chakraborty, Rupak

    2014-01-01

    We investigate sub-bandgap absorption in pyrite FeS? single-crystals, using both natural and synthetic crystals. Both types of crystals show non-negligible magnitudes of sub-bandgap absorption. To test whether the origin ...

  4. Optically stimulated differential impedance spectroscopy

    DOE Patents [OSTI]

    Maxey, Lonnie C; Parks, II, James E; Lewis, Sr., Samuel A; Partridge, Jr., William P

    2014-02-18

    Methods and apparatuses for evaluating a material are described. Embodiments typically involve use of an impedance measurement sensor to measure the impedance of a sample of the material under at least two different states of illumination. The states of illumination may include (a) substantially no optical stimulation, (b) substantial optical stimulation, (c) optical stimulation at a first wavelength of light, (d) optical stimulation at a second wavelength of light, (e) a first level of light intensity, and (f) a second level of light intensity. Typically a difference in impedance between the impedance of the sample at the two states of illumination is measured to determine a characteristic of the material.

  5. Waste Heat Powered Ammonia Absorption Refrigeration Unit for LPG Recovery

    SciTech Connect (OSTI)

    Donald C, Energy Concepts Co.; Lauber, Eric, Western Refining Co.

    2008-06-20

    An emerging DOE-sponsored technology has been deployed. The technology recovers light ends from a catalytic reformer plant using waste heat powered ammonia absorption refrigeration. It is deployed at the 17,000 bpd Bloomfield, New Mexico refinery of Western Refining Company. The technology recovers approximately 50,000 barrels per year of liquefied petroleum gas that was formerly being flared. The elimination of the flare also reduces CO2 emissions by 17,000 tons per year, plus tons per year reductions in NOx, CO, and VOCs. The waste heat is supplied directly to the absorption unit from the Unifiner effluent. The added cooling of that stream relieves a bottleneck formerly present due to restricted availability of cooling water. The 350oF Unifiner effluent is cooled to 260oF. The catalytic reformer vent gas is directly chilled to minus 25oF, and the FCC column overhead reflux is chilled by 25oF glycol. Notwithstanding a substantial cost overrun and schedule slippage, this project can now be considered a success: it is both profitable and highly beneficial to the environment. The capabilities of directly-integrated waste-heat powered ammonia absorption refrigeration and their benefits to the refining industry have been demonstrated.

  6. A cryogenic circulating advective multi-pass absorption cell

    SciTech Connect (OSTI)

    Stockett, M. H.; Lawler, J. E. [Department of Physics, University of Wisconsin, 1150 University Avenue, Madison, Wisconsin 53706 (United States)

    2012-03-15

    A novel absorption cell has been developed to enable a spectroscopic survey of a broad range of polycyclic aromatic hydrocarbons (PAH) under astrophysically relevant conditions and utilizing a synchrotron radiation continuum to test the still controversial hypothesis that these molecules or their ions could be carriers of the diffuse interstellar bands. The cryogenic circulating advective multi-pass absorption cell resembles a wind tunnel; molecules evaporated from a crucible or injected using a custom gas feedthrough are entrained in a laminar flow of cryogenically cooled buffer gas and advected into the path of the synchrotron beam. This system includes a multi-pass optical White cell enabling absorption path lengths of hundreds of meters and a detection sensitivity to molecular densities on the order of 10{sup 7} cm{sup -3}. A capacitively coupled radio frequency dielectric barrier discharge provides ionized and metastable buffer gas atoms for ionizing the candidate molecules via charge exchange and the Penning effect. Stronger than expected clustering of PAH molecules has slowed efforts to record gas phase PAH spectra at cryogenic temperatures, though such clusters may play a role in other interstellar phenomena.

  7. Heat exchanger bypass system for an absorption refrigeration system

    DOE Patents [OSTI]

    Reimann, Robert C. (Lafayette, NY)

    1984-01-01

    A heat exchanger bypass system for an absorption refrigeration system is disclosed. The bypass system operates to pass strong solution from the generator around the heat exchanger to the absorber of the absorption refrigeration system when strong solution builds up in the generator above a selected level indicative of solidification of strong solution in the heat exchanger or other such blockage. The bypass system includes a bypass line with a gooseneck located in the generator for controlling flow of strong solution into the bypass line and for preventing refrigerant vapor in the generator from entering the bypass line during normal operation of the refrigeration system. Also, the bypass line includes a trap section filled with liquid for providing a barrier to maintain the normal pressure difference between the generator and the absorber even when the gooseneck of the bypass line is exposed to refrigerant vapor in the generator. Strong solution, which may accumulate in the trap section of the bypass line, is diluted, to prevent solidification, by supplying weak solution to the trap section from a purge system for the absorption refrigeration system.

  8. Optimized Superconducting Nanowire Single Photon Detectors to Maximize Absorptance

    E-Print Network [OSTI]

    Csete, Maria; Szenes, Andras; Banhelyi, Balazs; Csendes, Tibor; Szabo, Gabor

    2015-01-01

    Dispersion characteristics of four types of superconducting nanowire single photon detectors, nano-cavity-array- (NCA-), nano-cavity-deflector-array- (NCDA-), nano-cavity-double-deflector-array- (NCDDA-) and nano-cavity-trench-array- (NCTA-) integrated (I-A-SNSPDs) devices was optimized in three periodicity intervals commensurate with half-, three-quarter- and one SPP wavelength. The optimal configurations capable of maximizing NbN absorptance correspond to periodicity dependent tilting in S-orientation (90{\\deg} azimuthal orientation). In NCAI-A-SNSPDs absorptance maxima are reached at the plasmonic Brewster angle (PBA) due to light tunneling. The absorptance maximum is attained in a wide plasmonic-pass-band in NCDAI_1/2*lambda-A, inside a flat-plasmonic-pass-band in NCDAI_3/4*lambda-A and inside a narrow plasmonic-band in NCDAI_lambda-A. In NCDDAI_1/2*lambda-A bands of strongly-coupled cavity and plasmonic modes cross, in NCDDAI_3/4*lambda-A an inverted-plasmonic-band-gap develops, while in NCDDAI_lambda-A ...

  9. Electromechanically induced absorption in a circuit nano-electromechanical system

    E-Print Network [OSTI]

    Fredrik Hocke; Xiaoqing Zhou; Albert Schliesser; Tobias J. Kippenberg; Hans Huebl; Rudolf Gross

    2012-09-20

    A detailed analysis of electromechanically induced absorption (EMIA) in a circuit nano-electromechanical hybrid system consisting of a superconducting microwave resonator coupled to a nanomechanical beam is presented. By performing two-tone spectroscopy experiments we have studied EMIA as a function of the drive power over a wide range of drive and probe tone detunings. We find good quantitative agreement between experiment and theoretical modeling based on the Hamiltonian formulation of a generic electromechanical system. We show that the absorption of microwave signals in an extremely narrow frequency band (\\Delta\\omega/2\\pi <5 Hz) around the cavity resonance of about 6 GHz can be adjusted over a range of more than 25 dB on varying the drive tone power by a factor of two. Possible applications of this phenomenon include notch filters to cut out extremely narrow frequency bands (< Hz) of a much broader band of the order of MHz defined by the resonance width of the microwave cavity. The amount of absorption as well as the filtered frequency is tunable over the full width of the microwave resonance by adjusting the power and frequency of the drive field. At high drive power we observe parametric microwave amplification with the nanomechanical resonator. Due to the very low loss rate of the nanomechanical beam the drive power range for parametric amplification is narrow, since the beam rapidly starts to perform self-oscillations.

  10. New formulae for the $(-2)$ moment of the photo-absorption cross section, $?_{_{-2}}$

    E-Print Network [OSTI]

    Nico Orce

    2015-10-14

    Two new formulae for the $(-2)$ moment of the photo-absorption cross section, $\\sigma_{_{-2}}$, have been determined, respectively, from the 1988 compilation of Dietrich and Berman and a mass-dependent symmetry energy coefficient, $a_{sym}(A)$. The data for $A\\gtrsim50$ follow, with a {\\small $RMS$} deviation of 6\\%, the power-law $\\sigma_{_{-2}}=2.4 A^{5/3}$$\\mu$b/MeV, which is in agreement with Migdal's calculation of $\\sigma_{_{-2}}=2.25A^{5/3}$$\\mu$b/MeV based on the hydrodynamic model and the $\\sigma_{_{-2}}$ sum rule. The additional inclusion of $a_{sym}(A)$ provides a deeper insight to the nuclear polarization of $A\\geqq10$ nuclei.

  11. New formulae for the $(-2)$ moment of the photo-absorption cross section, $\\sigma_{_{-2}}$

    E-Print Network [OSTI]

    Orce, Nico

    2015-01-01

    Two new formulae for the $(-2)$ moment of the photo-absorption cross section, $\\sigma_{_{-2}}$, have been determined, respectively, from the 1988 compilation of Dietrich and Berman and a mass-dependent symmetry energy coefficient, $a_{sym}(A)$. The data for $A\\gtrsim50$ follow, with a {\\small $RMS$} deviation of 6\\%, the power-law $\\sigma_{_{-2}}=2.4 A^{5/3}$$\\mu$b/MeV, which is in agreement with Migdal's calculation of $\\sigma_{_{-2}}=2.25A^{5/3}$$\\mu$b/MeV based on the hydrodynamic model and the $\\sigma_{_{-2}}$ sum rule. The additional inclusion of $a_{sym}(A)$ provides a deeper insight to the nuclear polarization of $A\\geqq10$ nuclei.

  12. Inoculating Multivariate Schemes Against Differential Attacks

    E-Print Network [OSTI]

    International Association for Cryptologic Research (IACR)

    Inoculating Multivariate Schemes Against Differential Attacks Jintai Ding and Jason E. Gower scheme the Perturbed Matsumoto-Imai-Plus (PMI+) cryptosystem. Keywords: multivariate, public key resources. Multivariate public key cryptography provides one alternative since computations in small finite

  13. MATH 411 SPRING 2001 Ordinary Differential Equations

    E-Print Network [OSTI]

    Alekseenko, Alexander

    MATH 411 SPRING 2001 Ordinary Differential Equations Schedule # 749025 TR 01:00-02:15 316 Boucke Instructor: Alexander Alekseenko, 328 McAllister, 865-1984, alekseen@math.psu.edu The course

  14. New packing in absorption systems for trapping benzene from coke-oven gas

    SciTech Connect (OSTI)

    V.V. Grabko; V.M. Li; T.A. Shevchenko; M.A. Solov'ev

    2009-07-15

    The efficiency of benzene removal from coke-oven gas in absorption units OAO Alchevskkoks with new packing is assessed.

  15. Effect of dietary fat on plasma glutathione peroxidase levels and intestinal absorption of /sup 75/Se-labeled sodium selenite in chicks

    SciTech Connect (OSTI)

    Mutanen, M.L.; Mykkaenen, H.M.

    1984-05-01

    The effect of dietary fat on the availability of selenium was investigated in chicks fed either 4 or 20% butter, olive oil, rape oil, corn oil or sunflower oil in the diet for 3 weeks after hatching. Plasma glutathione peroxidase (GSH-Px) activity was used as an indicator of the body selenium status. In addition, the intestinal absorption of sodium selenite (/sup 75/Se-labeled) was determined by using both the in vivo ligated loop procedure and oral administration of the isotope. The plasma GSH-Px levels increased with increasing proportion of the polyunsaturated fatty acids in the diet. Increasing the amount of fat from 4 to 20% significantly enhanced the GSH-Px activity in the groups receiving butter or olive oil, but had no effect in animals fed the unsaturated fats. The absorption of (/sup 75/Se)selenite from the ligated duodenal loops tended to be reduced in chicks fed corn oil or sunflower oil as compared to the animals receiving butter in their diet. On the other hand, the type of dietary fat did not appear to affect the absorption of the orally administered selenite. The present study demonstrates that the type of dietary fat can affect the plasma GSH-Px levels in chicks without altering the intestinal absorption of selenite. However, the results on the absorption of the intraduodenally injected sodium selenite suggest that dietary fat plays some role in the intestinal transport of selenium.

  16. Americium characterization by X-ray fluorescence and absorption spectroscopy in plutonium uranium mixed oxide

    SciTech Connect (OSTI)

    Degueldre, Claude Cozzo, Cedric; Martin, Matthias; Grolimund, Daniel; Mieszczynski, Cyprian

    2013-06-01

    Plutonium uranium mixed oxide (MOX) fuels are currently used in nuclear reactors. The actinides in these fuels need to be analyzed after irradiation for assessing their behaviour with regard to their environment and the coolant. In this work the study of the atomic structure and next-neighbour environment of Am in the (Pu,U)O? lattice in an irradiated (60 MW d kg?¹) MOX sample was performed employing micro-X-ray fluorescence (µ-XRF) and micro-X-ray absorption fine structure (µ-XAFS) spectroscopy. The chemical bonds, valences and stoichiometry of Am (~0.66 wt%) are determined from the experimental data gained for the irradiated fuel material examined in its peripheral zone (rim) of the fuel. In the irradiated sample Am builds up as Am³? species within an [AmO?]¹³? coordination environment (e.g. >90%) and no (<10%) Am(IV) or (V) can be detected in the rim zone. The occurrence of americium dioxide is avoided by the redox buffering activity of the uranium dioxide matrix. - Graphical abstract: Americium LIII XAFS spectra recorded for the irradiated MOX sub-sample in the rim zone for a 300 ?m×300 ?m beam size area investigated over six scans of 4 h. The records remain constant during multi-scan. The analysis of the XAFS signal shows that Am is found as trivalent in the UO? matrix. This analytical work shall open the door of very challenging analysis (speciation of fission product and actinides) in irradiated nuclear fuels. - Highlights: • Americium was characterized by microX-ray absorption spectroscopy in irradiated MOX fuel. • The americium redox state as determined from XAS data of irradiated fuel material was Am(III). • In the sample, the Am³? face an AmO?¹³?coordination environment in the (Pu,U)O? matrix. • The americium dioxide is reduced by the uranium dioxide matrix.

  17. An Iterated, Multipoint Differential Transform Method for Numerically...

    Office of Scientific and Technical Information (OSTI)

    Differential Transform Method for Numerically Evolving Partial Differential Equation Initial-Value Problems Citation Details In-Document Search Title: An Iterated,...

  18. Use of Simulation To Optimize NOx Abatement by Absorption and Selective Catalytic Reduction

    E-Print Network [OSTI]

    Liu, Y. A.

    Use of Simulation To Optimize NOx Abatement by Absorption and Selective Catalytic Reduction Andrew involving both absorption and selective catalytic reduction (SCR). The model helps identify operator The system under analysis involves two key pro- cesses: absorption and selective catalytic reduction (SCR

  19. Efficiency of pump absorption in double-clad fiber amplifiers. I. Fiber with circular symmetry

    E-Print Network [OSTI]

    Kouznetsov, Dmitrii

    Efficiency of pump absorption in double-clad fiber amplifiers. I. Fiber with circular symmetry with an absorbing core is treated as a model for pump absorption in a double-clad optical fiber amplifier. Mode the pump absorption and is analyzed in the speckle-mode approximation for the example of a Kerr

  20. Low level absorptance measurements and scans of high performance optical coatings for atomic vapor laser isotope separation applications

    SciTech Connect (OSTI)

    Chow, R.; Taylor, J.R.; Wu, Z.L.; Krupka, R.; Yang, T.

    1998-01-24

    A surface thermal lensing and a radiometric technique was used to characterize the absorptance dependence on time, power, site, and technique of low absorptance optical multilayered coatings.

  1. Two Type Ia Supernovae at Redshift ~2 : Improved Classification and Redshift Determination with Medium-band Infrared Imaging

    E-Print Network [OSTI]

    Rodney, Steven A; Scolnic, Daniel M; Jones, David O; Hemmati, Shoubaneh; Molino, Alberto; McCully, Curtis; Mobasher, Bahram; Strolger, Louis-Gregory; Graur, Or; Hayden, Brian; Casertano, Stefano

    2015-01-01

    We present two supernovae (SNe) discovered with the Hubble Space Telescope (HST) in the Cosmic Assembly Near-infrared Deep Extragalactic Legacy Survey (CANDELS), an HST multi-cycle treasury program. We classify both objects as Type Ia SNe and find redshifts of z = 1.80+-0.02 and 2.26 +0.02 -0.10, the latter of which is the highest redshift Type Ia SN yet seen. Using light curve fitting we determine luminosity distances and find that both objects are consistent with a standard Lambda-CDM cosmological model. These SNe were observed using the HST Wide Field Camera 3 infrared detector (WFC3-IR), with imaging in both wide- and medium-band filters. We demonstrate that the classification and redshift estimates are significantly improved by the inclusion of single-epoch medium-band observations. This medium-band imaging approximates a very low resolution spectrum (lambda/delta lambda ~ 100) which can isolate broad spectral absorption features that differentiate Type Ia SNe from their most common core collapse cousins...

  2. Bandgap widening in thermochromic Mg-doped VO{sub 2} thin films: Quantitative data based on optical absorption

    SciTech Connect (OSTI)

    Li, Shu-Yi; Niklasson, Gunnar A.; Granqvist, Claes G.; Mlyuka, Nuru R.; Department of Physics, University of Dar es Salaam, P.O. Box 35063, Dar es Salaam ; Primetzhofer, Daniel; Possnert, Göran; Hallén, Anders

    2013-10-14

    Thermochromic Mg-doped VO{sub 2} films were deposited by reactive direct current magnetron sputtering onto heated glass and carbon substrates. Elemental compositions were inferred from Rutherford backscattering. Optical bandgaps were obtained from spectral transmittance and reflectance measurements—from both the film side and the back side of the samples—and ensuing determination of absorption coefficients. The bandgap of Mg-doped films was found to increase by 3.9 ± 0.5 eV per unit of atom ratio Mg/(Mg + V) for 0 < Mg/(Mg + V) < 0.21. The presence of ?0.45 at. % Si enhanced the bandgap even more.

  3. Concentration-dependent gene expression responses to flusilazole in embryonic stem cell differentiation cultures

    SciTech Connect (OSTI)

    Dartel, Dorien A.M. van; Pennings, Jeroen L.A.; Fonteyne, Liset J.J. de la; Brauers, Karen J.J.; Claessen, Sandra; Delft, Joost H. van; Kleinjans, Jos C.S.; Piersma, Aldert H.

    2011-03-01

    The murine embryonic stem cell test (EST) is designed to evaluate developmental toxicity based on compound-induced inhibition of embryonic stem cell (ESC) differentiation into cardiomyocytes. The addition of transcriptomic evaluation within the EST may result in enhanced predictability and improved characterization of the applicability domain, therefore improving usage of the EST for regulatory testing strategies. Transcriptomic analyses assessing factors critical for risk assessment (i.e. dose) are needed to determine the value of transcriptomic evaluation in the EST. Here, using the developmentally toxic compound, flusilazole, we investigated the effect of compound concentration on gene expression regulation and toxicity prediction in ESC differentiation cultures. Cultures were exposed for 24 h to multiple concentrations of flusilazole (0.54-54 {mu}M) and RNA was isolated. In addition, we sampled control cultures 0, 24, and 48 h to evaluate the transcriptomic status of the cultures across differentiation. Transcriptomic profiling identified a higher sensitivity of development-related processes as compared to cell division-related processes in flusilazole-exposed differentiation cultures. Furthermore, the sterol synthesis-related mode of action of flusilazole toxicity was detected. Principal component analysis using gene sets related to normal ESC differentiation was used to describe the dynamics of ESC differentiation, defined as the 'differentiation track'. The concentration-dependent effects on development were reflected in the significance of deviation of flusilazole-exposed cultures from this transcriptomic-based differentiation track. Thus, the detection of developmental toxicity in EST using transcriptomics was shown to be compound concentration-dependent. This study provides further insight into the possible application of transcriptomics in the EST as an improved alternative model system for developmental toxicity testing.

  4. Absorption Features in Spectra of Magnetized Neutron Stars

    SciTech Connect (OSTI)

    Suleimanov, V.; Hambaryan, V.; Neuhaeuser, R.; Potekhin, A. Y.; Pavlov, G. G.; Adelsberg, M. van; Werner, K.

    2011-09-21

    The X-ray spectra of some magnetized isolated neutron stars (NSs) show absorption features with equivalent widths (EWs) of 50-200 eV, whose nature is not yet well known.To explain the prominent absorption features in the soft X-ray spectra of the highly magnetized (B{approx}10{sup 14} G) X-ray dim isolated NSs (XDINSs), we theoretically investigate different NS local surface models, including naked condensed iron surfaces and partially ionized hydrogen model atmospheres, with semi-infinite and thin atmospheres above the condensed surface. We also developed a code for computing light curves and integral emergent spectra of magnetized neutron stars with various temperature and magnetic field distributions over the NS surface. We compare the general properties of the computed and observed light curves and integral spectra for XDINS RBS 1223 and conclude that the observations can be explained by a thin hydrogen atmosphere above the condensed iron surface, while the presence of a strong toroidal magnetic field component on the XDINS surface is unlikely.We suggest that the harmonically spaced absorption features in the soft X-ray spectrum of the central compact object (CCO) 1E 1207.4-5209 (hereafter 1E 1207) correspond to peaks in the energy dependence of the free-free opacity in a quantizing magnetic field, known as quantum oscillations. To explore observable properties of these quantum oscillations, we calculate models of hydrogen NS atmospheres with B{approx}10{sup 10}-10{sup 11} G(i.e., electron cyclotron energy E{sub c,e}{approx}0.1-1 keV) and T{sub eff} = 1-3 MK. Such conditions are thought to be typical for 1E 1207. We show that observable features at the electron cyclotron harmonics with EWs {approx_equal}100-200 eV can arise due to these quantum oscillations.

  5. Infrared absorption spectroscopy and chemical kinetics of free radicals

    SciTech Connect (OSTI)

    Curl, R.F.; Glass, G.P. [Rice Univ., Houston, TX (United States)

    1993-12-01

    This research is directed at the detection, monitoring, and study of chemical kinetic behavior by infrared absorption spectroscopy of small free radical species thought to be important intermediates in combustion. During the last year, infrared kinetic spectroscopy using excimer laser flash photolysis and color-center laser probing has been employed to study the high resolution spectrum of HCCN, the rate constant of the reaction between ethynyl (C{sub 2}H) radical and H{sub 2} in the temperature region between 295 and 875 K, and the recombination rate of propargyl (CH{sub 2}CCH) at room temperature.

  6. Absorption-emission optrode and methods of use thereof

    DOE Patents [OSTI]

    Hirschfeld, T.B.

    1990-05-29

    A method and apparatus are described for monitoring the physical and chemical properties of a sample fluid by measuring an optical signal generated by a fluorescent substance and modulated by an absorber substance. The emission band of the fluorescent substance overlaps the absorption band of the absorber substance, and the degree of overlap is dependent on the physical and chemical properties of the sample fluid. The fluorescent substance and absorber substance are immobilized on a substrate so that an effective number of molecules thereof are sufficiently close for resonant energy transfer to occur, thereby providing highly efficient modulation of the fluorescent emissions of the fluorescent substance by the absorber substance. 4 figs.

  7. Quantitative infrared absorption cross sections of isoprene for atmospheric measurements

    SciTech Connect (OSTI)

    Brauer, Carolyn S.; Blake, Thomas A.; Guenther, Alex B.; Sharpe, Steven W.; Sams, Robert L.; Johnson, Timothy J.

    2014-11-19

    The OH- and O3- initiated oxidations of isoprene, which is one of the primary volatile organic compounds produced by vegetation, are a major source of atmospheric formaldehyde and other oxygenated organics, yet little quantitative IR data exists for isoprene. We thus report absorption coefficients and integrated band intensities for isoprene in the 600 - 6500 cm-1 region. The pressure-broadened (1 atmosphere N2) spectra were recorded at 278, 298 and 323 K in a 19.96 cm path length cell at 0.112 cm-1 resolution, using a Bruker 66V FTIR. Composite spectra are derived from a minimum of seven pressures at each temperature.

  8. Full light absorption in single arrays of spherical nanoparticles

    E-Print Network [OSTI]

    Ra'di, Y; Kosulnikov, S U; Omelyanovich, M M; Morits, D; Osipov, A V; Simovski, C R; Tretyakov, S A

    2015-01-01

    In this paper we show that arrays of core-shell nanoparticles function as effective thin absorbers of light. In contrast to known metamaterial absorbers, the introduced absorbers are formed by single planar arrays of spherical inclusions and enable full absorption of light incident on either or both sides of the array. We demonstrate possibilities for realizing different kinds of symmetric absorbers, including resonant, ultra-broadband, angularly selective, and all-angle absorbers. The physical principle behind these designs is explained considering balanced electric and magnetic responses of unit cells. Photovoltaic devices and thermal emitters are the two most important potential applications of the proposed designs.

  9. IHT: Tools for Computing Insolation Absorption by Particle Laden Flows

    SciTech Connect (OSTI)

    Grout, R. W.

    2013-10-01

    This report describes IHT, a toolkit for computing radiative heat exchange between particles. Well suited for insolation absorption computations, it is also has potential applications in combustion (sooting flames), biomass gasification processes and similar processes. The algorithm is based on the 'Photon Monte Carlo' approach and implemented in a library that can be interfaced with a variety of computational fluid dynamics codes to analyze radiative heat transfer in particle-laden flows. The emphasis in this report is on the data structures and organization of IHT for developers seeking to use the IHT toolkit to add Photon Monte Carlo capabilities to their own codes.

  10. Absorption-emission optrode and methods of use thereof

    DOE Patents [OSTI]

    Hirschfeld, Tomas B. (Livermore, CA)

    1990-01-01

    A method and apparatus for monitoring the physical and chemical properties of a sample fluid by measuring an optical signal generated by a fluorescent substance and modulated by an absorber substance. The emission band of the fluorescent substance overlaps the absorption band of the absorber substance, and the degree of overlap is dependent on the physical and chemical properties of the sample fluid. The fluorescent substance and absorber substance are immobilized on a substrate so that an effective number of molecules thereof are sufficiently close for resonant energy transfer to occur, thereby providing highly efficient modulation of the fluorescent emissions of the fluorescent substance by the absorber substance.

  11. High Energy Absorption Top Nozzle For A Nuclaer Fuel Assembly

    DOE Patents [OSTI]

    Sparrow, James A. (Irmo, SC); Aleshin, Yuriy (Columbia, SC); Slyeptsov, Aleksey (Columbia, SC)

    2004-05-18

    A high energy absorption top nozzle for a nuclear fuel assembly that employs an elongated upper tubular housing and an elongated lower tubular housing slidable within the upper tubular housing. The upper and lower housings are biased away from each other by a plurality of longitudinally extending springs that are restrained by a longitudinally moveable piston whose upward travel is limited within the upper housing. The energy imparted to the nozzle by a control rod scram is mostly absorbed by the springs and the hydraulic affect of the piston within the nozzle.

  12. Electromagnetically induced absorption in metastable 83Kr atoms

    E-Print Network [OSTI]

    Kale, Y B; Mishra, S R; Singh, S; Rawat, H S

    2015-01-01

    We report electromagnetically induced absorption (EIA) resonances of sub-natural linewidth (FWHM) in metastable noble gas 83Kr* atoms using degenerate two level schemes (DTLSs). This is the first observation of EIA effect in a metastable noble gas atoms. Using these spectrally narrow EIA signals obtained corresponding to the closed hyperfine transition from 4p55s[3/2]2 to 4p55p[5/2]3 hyperfine manifolds of 83Kr* atoms, we have measured the Lande's g-factor (gF) for the lower level (F = 13/2) of the closed transition accurately with small applied magnetic fields of few Gauss.

  13. Size selective absorption of DNA tetrahedra in ATO nanomaterials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home RoomPreservation ofAlbuquerque|Sensitive Species3 OutlookSize selective absorption of DNA

  14. Differential Equations I Lab #8: Differential Equations and Linear Algebra with Mathematica

    E-Print Network [OSTI]

    Peckham, Bruce B.

    and NDSolve for differential equations, and LinearSolve, Eigenvector, Eigen- value, NullSpace, Inverse/instructor each output line generated by Mathematica. If you elect to write a report, your report should include an analytical solution to y + 3y + 2y = 3e4t. #12;2. The logistic differential equation (again). Consider

  15. Total absorption spectroscopy study of ?²Rb decay: A major contributor to reactor antineutrino spectrum shape [Total absorption spectroscopy study of ?²Rb: A major contributor to reactor antineutrino flux

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sonzogni, A.; Zakari-Issoufou, A. -A.; Fallot, M.; Porta, A.; Algora, A.; Tain, J. L.; Valencia, E.; Rice, S.; Bui, V. M.; Cormon, S.; et al

    2015-03-09

    The accurate determination of the emitted reactor antineutrino flux is still a major challenge for actual and future neutrino experiments at reactors, especially after the evidence of a disagreement between the measured antineutrino energy spectrum by Double Chooz, Daya Bay, and Reno and calculated antineutrino spectra obtained from the conversion of the unique integral beta spectra measured at the ILL reactor. Using nuclear data to compute reactor antineutrino spectra may help understanding this bias, with the study of the underlying nuclear physics. Summation calculations allow identifying a list of nuclei that contribute importantly to the antineutrino energy spectra emitted aftermore »the fission of ²³?,²?¹Pu and ²³?,²³?U, and whose beta decay properties might deserve new measurements. Among these nuclei, ?²Rb exhausts by itself about 16% of of the antineutrino energy spectrum emitted by Pressurized Water Reactors in the 5 to 8 MeV range. In this Letter, we report new Total Absorption Spectroscopy (TAS) results for this important contributor. The obtained beta feeding from ?²Rb shows beta intensity unobserved before in the 4.5 to 5.5 MeV energy region and gives a ground state to ground state branch of 87.5 % ± 3%. These new data induce a dramatic change in recent summation calculations where a 51% GS to GS branch was considered for ?²Rb, increasing the summation antineutrino spectrum in the region nearby the observed bias.The new data still have an important impact on other summation calculations in which more recent data were considered« less

  16. Effective Differentiated Instructional Elements for Improving Student Performance as Perceived by Secondary Principals in Exemplary Public High Schools in Texas: A Delphi Study 

    E-Print Network [OSTI]

    Durrett, Teresa Ann

    2011-10-21

    The primary purpose of this Delphi study was to determine which of the research-identified differentiated instructional elements are the most effective for improving student performance as perceived by secondary principals ...

  17. On obliquely magnetized and differentially rotating stars

    E-Print Network [OSTI]

    Wei, Xing

    2015-01-01

    We investigate the interaction of differential rotation and a misaligned magnetic field. The incompressible magnetohydrodynamic equations are solved numerically for a free-decay problem. In the kinematic limit, differential rotation annihilates the non-axisymmetric field on a timescale proportional to the cube root of magnetic Reynolds number ($Rm$), as predicted by R\\"adler. Nonlinearly, the outcome depends upon the initial energy in the non-axisymmetric part of the field. Sufficiently weak fields approach axisymmetry as in the kinematic limit; some differential rotation survives across magnetic surfaces, at least on intermediate timescales. Stronger fields enforce uniform rotation and remain non-axisymmetric. The initial field strength that divides these two regimes does not follow the scaling $Rm^{-1/3}$ predicted by quasi-kinematic arguments, perhaps because our $Rm$ is never sufficiently large or because of reconnection. We discuss the possible relevance of these results to tidal synchronization and tida...

  18. Effects of thermal motion on electromagnetically induced absorption

    SciTech Connect (OSTI)

    Tilchin, E.; Wilson-Gordon, A. D.; Firstenberg, O. [Department of Chemistry, Bar-Ilan University, Ramat Gan IL-52900 (Israel); Department of Physics, Technion-Israel Institute of Technology, Haifa IL-32000 (Israel)

    2011-05-15

    We describe the effect of thermal motion and buffer-gas collisions on a four-level closed N system interacting with strong pump(s) and a weak probe. This is the simplest system that experiences electromagnetically induced absorption (EIA) due to transfer of coherence via spontaneous emission from the excited state to the ground state. We investigate the influence of Doppler broadening, velocity-changing collisions (VCC), and phase-changing collisions (PCC) with a buffer gas on the EIA spectrum of optically active atoms. In addition to exact expressions, we present an approximate solution for the probe absorption spectrum, which provides physical insight into the behavior of the EIA peak due to VCC, PCC, and the wave-vector difference between the pump and probe beams. VCC are shown to produce a wide pedestal at the base of the EIA peak, which is scarcely affected by the pump-probe angular deviation, whereas the sharp central EIA peak becomes weaker and broader due to the residual Doppler-Dicke effect. Using diffusionlike equations for the atomic coherences and populations, we construct a spatial-frequency filter for a spatially structured probe beam and show that Ramsey narrowing of the EIA peak is obtained for beams of finite width.

  19. Triple loop heat exchanger for an absorption refrigeration system

    DOE Patents [OSTI]

    Reimann, Robert C. (Lafayette, NY)

    1984-01-01

    A triple loop heat exchanger for an absorption refrigeration system is disclosed. The triple loop heat exchanger comprises portions of a strong solution line for conducting relatively hot, strong solution from a generator to a solution heat exchanger of the absorption refrigeration system, conduit means for conducting relatively cool, weak solution from the solution heat exchanger to the generator, and a bypass system for conducting strong solution from the generator around the strong solution line and around the solution heat exchanger to an absorber of the refrigeration system when strong solution builds up in the generator to an undesirable level. The strong solution line and the conduit means are in heat exchange relationship with each other in the triple loop heat exchanger so that, during normal operation of the refrigeration system, heat is exchanged between the relatively hot, strong solution flowing through the strong solution line and the relatively cool, weak solution flowing through the conduit means. Also, the strong solution line and the bypass system are in heat exchange relationship in the triple loop heat exchanger so that if the normal flow path of relatively hot, strong solution flowing from the generator to an absorber is blocked, then this relatively, hot strong solution which will then be flowing through the bypass system in the triple loop heat exchanger, is brought into heat exchange relationship with any strong solution which may have solidified in the strong solution line in the triple loop heat exchanger to thereby aid in desolidifying any such solidified strong solution.

  20. Passive millimeter wave differential interference contrast polarimetry

    DOE Patents [OSTI]

    Bernacki, Bruce E; Kelly, James F; Sheen, David M; Tedeschi, Jonathan R; Hall, Thomas E; Hatchell, Brian K; Valdez, Patrick; McMakin, Douglas L

    2014-04-29

    Differential polarization imaging systems include an axicon configured to provide a displacement of ray bundles associated with different image patches. The displaced ray bundles are directed to antenna horns and orthomode transducers so as to provide outputs correspond to orthogonal linear states of polarization (SOPs). The outputs are directed to a differential radiometer so that Stokes parameter differences between image patches can be obtained. The ray bundle displacements can be selected to correspond to a mechanical spacing of antenna horns. In some examples, ray bundle displacement corresponds to a displacement less than the diffraction limit.

  1. Complexation of Lactate with Nd(III) and Eu(III) at Variable Temperatures: Studies by Potentiometry, Microcalorimetry, Optical Absorption and Luminescence Spectroscopy

    SciTech Connect (OSTI)

    Tian, Guoxin; Martin, Leigh R.; Rao, Linfeng

    2010-10-01

    Complexation of neodymium(III) and europium(III) with lactate was studied at variable temperatures by potentiometry, absorption spectrophotometry, luminescence spectroscopy and microcalorimetry. Stability constants of three successive lactate complexes (ML{sup 2+}, ML{sup 2+} and ML{sub 3}(aq), where M stands for Nd and Eu, and L stands for lactate) at 10, 25, 40, 55 and 70 C were determined. The enthalpies of complexation at 25 C were determined by microcalorimetry. Thermodynamic data show that the complexation of trivalent lanthanides (Nd{sup 3+} and Eu{sup 3+}) with lactate is exothermic, and the complexation becomes weaker at higher temperatures. Results from optical absorption and luminescence spectroscopy suggest that the complexes are inner-sphere chelate complexes in which the protonated {alpha}-hydroxyl group of lactate participates in the complexation.

  2. Characterization of the Electronic Structure of Silicon Nanoparticles Using X-ray Absorption and Emission

    SciTech Connect (OSTI)

    Vaverka, A M

    2008-07-15

    Resolving open questions regarding transport in nanostructures can have a huge impact on a broad range of future technologies such as light harvesting for energy. Silicon has potential to be used in many of these applications. Understanding how the band edges of nanostructures move as a function of size, surface termination and assembly is of fundamental importance in understanding the transport properties of these materials. In this thesis work I have investigated the change in the electronic structure of silicon nanoparticle assemblies as the surface termination is changed. Nanoparticles are synthesized using a thermal evaporation technique and sizes are determined using atomic force microscopy (AFM). By passivating the particles with molecules containing alcohol groups we are able to modify the size dependent band edge shifts. Both the valence and conduction bands are measured using synchrotron based x-ray absorption spectroscopy (XAS) and soft x-ray fluorescence (SXF) techniques. Particles synthesized via recrystallization of amorphous silicon/SiO{sub 2} multilayers of thicknesses below 10 nm are also investigated using the synchrotron techniques. These samples also show quantum confinement effects but the electronic structure is different from those synthesized via evaporation methods. The total bandgap is determined for all samples measured. The origins of these differences in the electronic structures are discussed.

  3. Solar differential rotation and properties of magnetic clouds

    E-Print Network [OSTI]

    K. Georgieva; B. Kirov; E. Gavruseva; J. Javaraiah

    2005-11-09

    The most geoeffective solar drivers are magnetic clouds - a subclass of coronal mass ejections (CME's) distinguished by the smooth rotation of the magnetic field inside the structure. The portion of CME's that are magnetic clouds is maximum at sunspot minimum and mimimum at sunspot maximum. This portion is determined by the amount of helicity carried away by CME's which in turn depends on the amount of helicity transferred from the solar interior to the surface, and on the surface differential rotation. The latter can increase or reduce, or even reverse the twist of emerging magnetic flux tubes, thus increasing or reducing the helicity in the corona, or leading to the violation of the hemispheric helicity rule, respectively. We investigate the CME's associated with the major geomagnetic storms in the last solar cycle whose solar sources have been identified, and find that in 10 out of 12 cases of violation of the hemispheric helicity rule or of highly geoeffective CME's with no magnetic field rotation, they originate from regions with "anti-solar" type of surface differential rotation.

  4. Sphingosine 1-phosphate receptor activation enhances BMP-2-induced osteoblast differentiation

    SciTech Connect (OSTI)

    Sato, Chieri [Division of Rheumatology, Department of Internal Medicine, Hyogo College of Medicine, 1-1 Mukogawa-cho, Nishinomiya, Hyogo 663-8501 (Japan)] [Division of Rheumatology, Department of Internal Medicine, Hyogo College of Medicine, 1-1 Mukogawa-cho, Nishinomiya, Hyogo 663-8501 (Japan); Iwasaki, Tsuyoshi, E-mail: tsuyo-i@huhs.ac.jp [Division of Pharmacotherapy, Department of Pharmacy, School of Pharmacy, Hyogo University of Health Sciences, 1-3-6 Minatojima, Chuo-ku, Kobe 650-8530 (Japan)] [Division of Pharmacotherapy, Department of Pharmacy, School of Pharmacy, Hyogo University of Health Sciences, 1-3-6 Minatojima, Chuo-ku, Kobe 650-8530 (Japan); Kitano, Sachie; Tsunemi, Sachi; Sano, Hajime [Division of Rheumatology, Department of Internal Medicine, Hyogo College of Medicine, 1-1 Mukogawa-cho, Nishinomiya, Hyogo 663-8501 (Japan)] [Division of Rheumatology, Department of Internal Medicine, Hyogo College of Medicine, 1-1 Mukogawa-cho, Nishinomiya, Hyogo 663-8501 (Japan)

    2012-06-22

    Highlights: Black-Right-Pointing-Pointer We investigated the role of S1P signaling for osteoblast differentiation. Black-Right-Pointing-Pointer Both S1P and FTY enhanced BMP-2-stimulated osteoblast differentiation by C2C12 cells. Black-Right-Pointing-Pointer S1P signaling enhanced BMP-2-stimulated Smad and ERK phosphorylation by C2C12 cells. Black-Right-Pointing-Pointer MEK/ERK signaling is a pathway underlying S1P signaling for osteoblast differentiation. -- Abstract: We previously demonstrated that sphingosine 1-phosphate (S1P) receptor-mediated signaling induced proliferation and prostaglandin productions by synovial cells from rheumatoid arthritis (RA) patients. In the present study we investigated the role of S1P receptor-mediated signaling for osteoblast differentiation. We investigated osteoblast differentiation using C2C12 myoblasts, a cell line derived from murine satellite cells. Osteoblast differentiation was induced by the treatment of bone morphogenic protein (BMP)-2 in the presence or absence of either S1P or FTY720 (FTY), a high-affinity agonist of S1P receptors. Osteoblast differentiation was determined by osteoblast-specific transcription factor, Runx2 mRNA expression, alkaline phosphatase (ALP) activity and osteocalcin production by the cells. Smad1/5/8 and extracellular signal-regulated kinase (ERK) 1/2 phosphorylation was examined by Western blotting. Osteocalcin production by C2C12 cells were determined by ELISA. Runx2 expression and ALP activity by BMP-2-stimulated C2C12 cells were enhanced by addition of either S1P or FTY. Both S1P and FTY enhanced BMP-2-induced ERK1/2 and Smad1/5/8 phosphorylation. The effect of FTY was stronger than that of S1P. S1P receptor-mediated signaling on osteoblast differentiation was inhibited by addition of mitogen-activated protein kinase/ERK kinase (MEK) 1/2 inhibitor, indicating that the S1P receptor-mediated MEK1/2-ERK1/2 signaling pathway enhanced BMP-2-Smad signaling. These results indicate that S1P receptor-mediated signaling plays a crucial role for osteoblast differentiation.

  5. Differential Equations Math 125 Name Quiz Section

    E-Print Network [OSTI]

    Burdzy, Krzysztof "Chris"

    -trivial applications of Differential Equations. Forensic Mathematics A detective discovers a murder victim in a hotel the murder took place. Let u(t) be the temperature of the body after t hours. By Newton's Law of Cooling we = 98.6 F and solve for t. At what time did the murder take place? #12;Spread of a Rumor The Xylocom

  6. Differential Privacy and Robust Statistics Cynthia Dwork

    E-Print Network [OSTI]

    Lei, Jing

    for differentially private mechanisms, which we call Propose-Test-Release (PTR), and for which we give a formal, the design of insensitive algorithms can require considerable re-thinking of existing algorithms. Much. Most well-known elementary statistical methods are para- metric. For example, given data samples x1

  7. Maternal Anesthesia via Isoflurane or Ether Differentially

    E-Print Network [OSTI]

    Maternal Anesthesia via Isoflurane or Ether Differentially Affects Pre-and Postnatal Behavior Program in Occupational Therapy Washington University School of Medicine St. Louis, MO 63108 Jeffrey R: Our understanding of prenatal behavior has been significantly advanced by techniques for direct

  8. The general solution of Schrodigers differential equation

    E-Print Network [OSTI]

    Nikos Bagis

    2009-10-31

    In this note we solve theoretically the Schrodingers differential equation using results based on our previous work which concern semigroup operators. Our method does not use eigenvectors or eigenvalues and the solution depends only from the selected base of the Hilbert space.

  9. Differential-Equation Based Absorbing Boundary Conditions

    E-Print Network [OSTI]

    Schneider, John B.

    Chapter 6 Differential-Equation Based Absorbing Boundary Conditions 6.1 Introduction A simple in the analysis of a wide range of FDTD-related topics. 6.2 The Advection Equation The wave equation that governs.2) The second form represents the equation in terms of an operator operating on Ez where the operator

  10. Partial Differential Equations of Electrostatic MEMS

    E-Print Network [OSTI]

    Fournier, John J.F.

    Partial Differential Equations of Electrostatic MEMS by Yujin Guo B.Sc., China Three Gorges) The University of British Columbia July 2007 c Yujin Guo 2007 #12;Abstract Micro-Electromechanical Systems (MEMS their initial development in the 1980s, MEMS has revolutionized numerous branches of science and industry

  11. Relational Differential Prediction Houssam Nassif1

    E-Print Network [OSTI]

    Page Jr., C. David

    (and vice versa). Differential prediction has been studied extensively in the context of multi linking calcification to in situ breast cancer in older women. Keywords: Uplift modeling, relational data among women, with a 12% probability of incidence in a lifetime [3]. Breast cancer has two basic stages

  12. USAGE-BASED PRICING DIFFERENTIATION FOR

    E-Print Network [OSTI]

    Huang, Jianwei

    cost, complex pricing schemes are not "customer- friendly" and discourage customers from usingCHAPTER 1 USAGE-BASED PRICING DIFFERENTIATION FOR COMMUNICATION NETWORKS: INCOMPLETE INFORMATION AND LIMITED PRICING CHOICES Shuqin Li, Ph.D.1 and Jianwei Huang, Ph.D.2 1 Research and Innovation, Alcatel

  13. Four-Hair Relations for Differentially Rotating Neutron Stars in the Weak-Field Limit

    E-Print Network [OSTI]

    Joseph Bretz; Kent Yagi; Nicolas Yunes

    2015-07-08

    The opportunity to study physics at supra-nuclear densities through X-ray observations of neutron stars has led to in-depth investigations of certain approximately universal relations that can remove degeneracies in pulse profile models. One such set of relations determines all of the multipole moments of a neutron star just from the first three (the mass monopole, the current dipole and the mass quadrupole moment) approximately independently of the equation of state. These three-hair relations were found to hold in neutron stars that rotate rigidly, as is the case in old pulsars, but neutron stars can also rotate differentially, as is the case for proto-neutron stars and hypermassive transient remnants of binary mergers. We here extend the three-hair relations to differentially rotating stars for the first time with a generic rotation law using two approximations: a weak-field scheme (an expansion in powers of the neutron star compactness) and a perturbative differential rotation scheme (an expansion about rigid rotation). These approximations allow us to analytically derive approximately universal relations that allow us to determine all of the multipole moments of a (perturbative) differentially rotating star in terms of only the first four moments. These new four-hair relations for differentially rotating neutron stars are found to be approximately independent of the equation of state to a higher degree than the three-hair relations for uniformly rotating stars. Our results can be instrumental in the development of four-hair relations for rapidly differentially rotating stars in full General Relativity using numerical simulations.

  14. Four-Hair Relations for Differentially Rotating Neutron Stars in the Weak-Field Limit

    E-Print Network [OSTI]

    Joseph Bretz; Kent Yagi; Nicolas Yunes

    2015-10-09

    The opportunity to study physics at supra-nuclear densities through X-ray observations of neutron stars has led to in-depth investigations of certain approximately universal relations that can remove degeneracies in pulse profile models. One such set of relations determines all of the multipole moments of a neutron star just from the first three (the mass monopole, the current dipole and the mass quadrupole moment) approximately independently of the equation of state. These three-hair relations were found to hold in neutron stars that rotate rigidly, as is the case in old pulsars, but neutron stars can also rotate differentially, as is the case for proto-neutron stars and hypermassive transient remnants of binary mergers. We here extend the three-hair relations to differentially rotating stars for the first time with a generic rotation law using two approximations: a weak-field scheme (an expansion in powers of the neutron star compactness) and a perturbative differential rotation scheme (an expansion about rigid rotation). These approximations allow us to analytically derive approximately universal relations that allow us to determine all of the multipole moments of a (perturbative) differentially rotating star in terms of only the first four moments. These new four-hair relations for differentially rotating neutron stars are found to be approximately independent of the equation of state to a higher degree than the three-hair relations for uniformly rotating stars. Our results can be instrumental in the development of four-hair relations for rapidly differentially rotating stars in full General Relativity using numerical simulations.

  15. Method of trivalent chromium concentration determination by atomic spectrometry

    DOE Patents [OSTI]

    Reheulishvili, Aleksandre N. (Tbilisi, 0183, GE); Tsibakhashvili, Neli Ya. (Tbilisi, 0101, GE)

    2006-12-12

    A method is disclosed for determining the concentration of trivalent chromium Cr(III) in a sample. The addition of perchloric acid has been found to increase the atomic chromium spectrometric signal due to Cr(III), while leaving the signal due to hexavalent chromium Cr(VI) unchanged. This enables determination of the Cr(III) concentration without pre-concentration or pre-separation from chromium of other valences. The Cr(III) concentration may be measured using atomic absorption spectrometry, atomic emission spectrometry or atomic fluorescence spectrometry.

  16. Multi-spectral optical absorption in substrate-free nanowire arrays

    SciTech Connect (OSTI)

    Zhang, Junpeng; Chia, Andrew; Boulanger, Jonathan; LaPierre, Ray; Dhindsa, Navneet; Khodadad, Iman; Saini, Simarjeet

    2014-09-22

    A method is presented of fabricating gallium arsenide (GaAs) nanowire arrays of controlled diameter and period by reactive ion etching of a GaAs substrate containing an indium gallium arsenide (InGaP) etch stop layer, allowing the precise nanowire length to be controlled. The substrate is subsequently removed by selective etching, using the same InGaP etch stop layer, to create a substrate-free GaAs nanowire array. The optical absorptance of the nanowire array was then directly measured without absorption from a substrate. We directly observe absorptance spectra that can be tuned by the nanowire diameter, as explained with rigorous coupled wave analysis. These results illustrate strong optical absorption suitable for nanowire-based solar cells and multi-spectral absorption for wavelength discriminating photodetectors. The solar-weighted absorptance above the bandgap of GaAs was 94% for a nanowire surface coverage of only 15%.

  17. Thermally Induced Nonlinear Optical Absorption in Metamaterial Perfect Absorbers

    E-Print Network [OSTI]

    Guddala, Sriram; Ramakrishna, S Anantha

    2015-01-01

    A metamaterial perfect absorber consisting of a tri-layer (Al/ZnS/Al) metal-dielectric-metal system with top aluminium nano-disks is fabricated by laser-interference lithography and lift-off processing. The metamaterial absorber had peak resonant absorbance at 1090 nm and showed nonlinear absorption for 600ps laser pulses at 1064 nm wavelength. A nonlinear saturation of reflectance was measured to be dependent on the average laser power incident and not the peak laser intensity. The nonlinear behaviour is shown to arise from the heating due to the absorbed radiation and photo-thermal changes in the dielectric properties of aluminium. The metamaterial absorber is seen to be damage resistant at large laser intensities of 25 MW/cm2.

  18. CO2 Capture by Absorption with Potassium Carbonate

    SciTech Connect (OSTI)

    Gary T. Rochelle; Marcus Hilliard; Eric Chen; Babatunde Oyenekan; Ross Dugas; John McLees; Andrew Sexton; Daniel Ellenberger

    2005-10-26

    The objective of this work is to improve the process for CO{sub 2} capture by alkanolamine absorption/stripping by developing an alternative solvent, aqueous K{sub 2}CO{sub 3} promoted by piperazine. Modeling of stripper performance suggests that vacuum stripping may be an attractive configuration for all solvents. Flexipac 1Y structured packing performs in the absorber as expected. It provides twice as much mass transfer area as IMTP No.40 dumped packing. Independent measurements of CO{sub 2} solubility give a CO{sub 2} loading that is 20% lower than that Cullinane's values with 3.6 m PZ at 100-120 C. The effective mass transfer coefficient (K{sub G}) in the absorber with 5 m K/2.5 m PZ appears to be 0 to 30% greater than that of 30 wt% MEA.

  19. Light absorption cell combining variable path and length pump

    DOE Patents [OSTI]

    Prather, W.S.

    1993-12-07

    A device is described for use in making spectrophotometric measurements of fluid samples. In particular, the device is a measurement cell containing a movable and a fixed lens with a sample of the fluid there between and through which light shines. The cell is connected to a source of light and a spectrophotometer via optic fibers. Movement of the lens varies the path length and also pumps the fluid into and out of the cell. Unidirectional inlet and exit valves cooperate with the movable lens to assure a one-way flow of fluid through the cell. A linear stepper motor controls the movement of the lens and cycles it from a first position closer to the fixed lens and a second position farther from the fixed lens, preferably at least 10 times per minute for a nearly continuous stream of absorption spectrum data. 2 figures.

  20. Light absorption cell combining variable path and length pump

    DOE Patents [OSTI]

    Prather, William S. (2419 Dickey Rd., Augusta, GA 30906)

    1993-01-01

    A device for use in making spectrophotometric measurements of fluid samples. In particular, the device is a measurement cell containing a movable and a fixed lens with a sample of the fluid therebetween and through which light shines. The cell is connected to a source of light and a spectrophotometer via optic fibers. Movement of the lens varies the path length and also pumps the fluid into and out of the cell. Unidirectional inlet and exit valves cooperate with the movable lens to assure a one-way flow of fluid through the cell. A linear stepper motor controls the movement of the lens and cycles it from a first position closer to the fixed lens and a second position farther from the fixed lens, preferably at least 10 times per minute for a nearly continuous stream of absorption spectrum data.

  1. CX-010839: Categorical Exclusion Determination

    Office of Energy Efficiency and Renewable Energy (EERE)

    Raman and Absorption Spectroscopy CX(s) Applied: B3.6 Date: 07/31/2013 Location(s): South Carolina Offices(s): Savannah River Operations Office

  2. CX-010838: Categorical Exclusion Determination

    Office of Energy Efficiency and Renewable Energy (EERE)

    Raman and Absorption Spectroscopy CX(s) Applied: B3.6 Date: 07/31/2013 Location(s): South Carolina Offices(s): Savannah River Operations Office

  3. Broad Absorption Line QSOs Observed by the ROSAT PSPC

    E-Print Network [OSTI]

    Paul J. Green; Smita Mathur

    1995-12-06

    Recent results from the ROSAT All-Sky Survey (RASS) have shown that broad absorption line (BAL) QSOs are either highly absorbed or underluminous in the soft X-ray bandpass. Here, we extend this work by analyzing all known bona fide BALQSOs observed within the inner 20' of the ROSAT PSPC. This sample includes both targeted and serendipitous exposures ranging from 8 to 75 ksec. Despite these deep exposures, most of the BALQSOs are undetected, and have unusually weak X-ray emission, as evidenced by large optical-to-X-ray slopes (AOX). Large values of AOX ($\\gapprox$1.8) may prove to be a defining characteristic of BALQSOs. We predict that samples of QSO candidates with large AOX will yield a higher percentage of BALQSOs, particularly at low redshift. As a corollary, X-ray-selected QSO samples should yield The optical/UV emission line spectra of BAL and non-BAL QSOs are quite similar, suggesting that their intrinsic spectral energy distributions are similar as well. Absorption thus seems the likely reason for the X-ray quiet nature of BALQSOs. To constrain the total absorbing column of the BAL clouds, we compare our measured soft X-ray fluxes or upper limits to those expected from normal radio quiet QSOs of comparable optical continuum magnitude and redshift. From sensitive X-ray observations, we derive column densities of greater than about 2 times 10^22 cm-2, for intrinsic cold absorbers of solar metallicity. These new results suggest columns {\\em at least} an order of magnitude larger than the columns previously estimated from optical/UV spectra alone.

  4. Tracking Living Cells as They Differentiate in Real Time

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    absorption spectra. Phosphorylating enzymes add one or more phosphate groups to three amino-acid residues common in proteins - serine, threonine, or tyrosine - which activates...

  5. Absolute CF{sub 2} density and gas temperature measurements by absorption spectroscopy in dual-frequency capacitively coupled CF{sub 4}/Ar plasmas

    SciTech Connect (OSTI)

    Liu, Wen-Yao; Xu, Yong, E-mail: yongxu@dlut.edu.cn; Peng, Fei; Gong, Fa-Ping; Li, Xiao-Song; Zhu, Ai-Min [Key Laboratory of Materials Modification by Laser, Ion, and Electron Beams (Ministry of Education), School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 (China); Laboratory of Plasma Physical Chemistry, Dalian University of Technology, Dalian 116024 (China); Liu, Yong-Xin; Wang, You-Nian [Key Laboratory of Materials Modification by Laser, Ion, and Electron Beams (Ministry of Education), School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 (China)

    2014-10-15

    Broadband ultraviolet absorption spectroscopy has been used to determine the CF{sub 2} radical density in dual-frequency capacitively coupled CF{sub 4}/Ar plasmas, using the CF{sub 2} A{sup ~1}B{sub 1}?X{sup ~1}A{sub 1} system of absorption spectrum. The rotational temperature of ground state CF{sub 2} and excited state CF was also estimated by using A{sup ~1}B{sub 1}?X{sup ~1}A{sub 1} system and B{sup 2}??X{sup 2}? system, respectively. The translational gas temperature was deduced from the Doppler width of the Ar{sup *}({sup 3}P{sub 2}) and Ar{sup *}({sup 3}P{sub 0}) metastable atoms absorption line by using the tunable diode laser absorption spectroscopy. The rotational temperatures of the excited state CF are about 100?K higher than those of ground state CF{sub 2}, and about 200?K higher than the translational gas temperatures. The dependences of the radical CF{sub 2} density, electron density, electron temperature, rotational temperature, and gas temperature on the high frequency power and pressure have been analyzed. Furthermore, the production and loss mechanisms of CF{sub 2} radical and the gas heating mechanisms have also been discussed.

  6. A new method of determining the inclination angle in interacting binaries

    E-Print Network [OSTI]

    Tariq Shahbaz

    1998-03-25

    We describe a method of determining the system parameters in non-eclipsing interacting binaries. We find that the extent to which an observer sees the shape of the Roche-lobe of the secondary star governs the amount of distortion of the absorption line profiles. The width and degree of asymmetry of the phase-resolved absorption line profiles show a characteristic shape, which depends primarily on the binary inclination and gravity darkening exponent. We show that, in principle, by obtaining high spectral and time resolution spectra of quiescent cataclysmic variables or low mass X-ray binaries in which the mass-losing star is visible, fitting the shape of absorption line profiles will allow one to determine not only the mass function of the binary, but also the binary inclination and hence the mass of the binary components.

  7. Guide to Developing Air-Cooled Lithium Bromide (LiBr) Absorption...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Future of Absorption Technology in America: A Critical Look at the Impact of Building, Cooling, Heating, and Power (BCHP) and Innovation, June 2000 Review of Thermally Activated...

  8. Dielectric Core-shell Optical Antennas for Strong Solar Absorption Enhancement

    E-Print Network [OSTI]

    Yu, Yiling

    2014-01-01

    Basic  Research  Needs  for  Solar  Energy  Utilization,  Nelson,  J.   Physics  of  Solar  Cell;  Imperial  College  Optical Antennas for Strong Solar Absorption Enhancement

  9. Efficient solar cooling: first ever non-tracking solar collectors powering a double effect absorption chiller

    E-Print Network [OSTI]

    Poiry, Heather Marie

    2011-01-01

    Based Performance Analysis of a Solar Absorption Cooling andExperimental Investigation of a Solar Adsorption ChillerKreith, Jan F. Kreider. "Solar Cooling." Principles of Solar

  10. The determination of some anions using ion chromatography and ion chromatography-graphite furnace atomic absorption spectrometry 

    E-Print Network [OSTI]

    Hillman, Daniel C

    1981-01-01

    with a fluoride ion selective electrode. The fluorine concentration in the Texas lignite core sample ranged from 50 to 95 ppm F. Ion chromatography alone was shown not to be useful in the deter- mination of selenite and selenate in natural water... Analys1s of Selenite and Selenate . Parameter s for IC-GFAA Analysis of Selen1te and Selenate 10 IV Coeffic1ents of the L1near Least Square Equations for Fluoride Cal1brat1on Curves 1n Figures 3, 4, and 5 (p. 14, 15, 16) Fluorine Determ1nat1on...

  11. Determination of the hydrogen absorption sites in Zn4O(1,4-benzenedicarboxylate) by single crystal neutron diffraction

    E-Print Network [OSTI]

    Yaghi, Omar M.

    in the form of fuel cells to convert stored chemical energy, in the form of hydrogen gas, directly within hydrogen-loaded Zn4O(1,4-benzenedicarboxylate) have been located. The technology already exists into electrical energy with high efficiency.1 The crucial factor that is hindering progress towards the commercial

  12. Absorption of chromium and reduction of chromate by subterranean clover 

    E-Print Network [OSTI]

    Howe, Julie Ann

    1999-01-01

    of complication in plants grown in different Cr sources by EPR spectroscopy, (3) determine the distribution of Cr in plant tissues using synchrotron x-ray fluorescent (SXRF) microphone spectroscopy, and (4) determine the effect of root plasma membrane bound ferric...

  13. Integral data analysis for resonance parameters determination

    SciTech Connect (OSTI)

    Larson, N.M.; Leal, L.C.; Derrien, H.

    1997-09-01

    Neutron time-of-flight experiments have long been used to determine resonance parameters. Those resonance parameters have then been used in calculations of integral quantities such as Maxwellian averages or resonance integrals, and results of those calculations in turn have been used as a criterion for acceptability of the resonance analysis. However, the calculations were inadequate because covariances on the parameter values were not included in the calculations. In this report an effort to correct for that deficiency is documented: (1) the R-matrix analysis code SAMMY has been modified to include integral quantities of importance, (2) directly within the resonance parameter analysis, and (3) to determine the best fit to both differential (microscopic) and integral (macroscopic) data simultaneously. This modification was implemented because it is expected to have an impact on the intermediate-energy range that is important for criticality safety applications.

  14. High Bandwidth Differential Amplifier for Shock Experiments

    SciTech Connect (OSTI)

    Ross, P. W., Tran, V., Chau, R.

    2012-04-30

    We developed a high bandwidth differential amplifier for gas gun shock experiments/applications. The circuit has a bandwidth > 1 GHz, and is capable of measuring signals of ?1.5 V with a common mode rejection of 250 V. Conductivity measurements of gas gun targets are measured by flowing high currents through the targets. The voltage is measured across the target using a technique similar to a four-point probe. Because of the design of the current source and load, the target voltage is approximately 250 V relative to ground. Since the expected voltage change in the target is < 1 V, the differential amplifier must have a large common mode rejection. High pass filters suppress internal ringing of operational amplifiers. Results of bench tests are shown.

  15. Stochastic partial differential equations with singular terminal condition

    E-Print Network [OSTI]

    Popier, Alexandre

    Stochastic partial differential equations with singular terminal condition A Matoussi, Lambert Piozin, A Popier To cite this version: A Matoussi, Lambert Piozin, A Popier. Stochastic partial differential equations with singular terminal condition. 2015. HAL Id: hal-01152687 https

  16. Derived Differential Geometry Prof Joyce 14 lectures TT 2015 Overview

    E-Print Network [OSTI]

    Burton, Geoffrey R.

    1 Derived Differential Geometry Prof Joyce 14 lectures TT 2015 Overview Derived Differential Geometry is the study of derived smooth manifolds and orbifolds, where "derived" is in the sense

  17. Validation and determination of ice water content-radar reflectivity relationships during CRYSTAL-

    E-Print Network [OSTI]

    by the absorption and scattering of solar and terrestrial radiation [Norris, 2000]. The extent to which clouds, and the radiative budget of the atmosphere. However, to date cloud processes represent one of the largest uncertain. Introduction [2] Clouds play a critical role in determining the radiative budget of the atmosphere and surface

  18. Differential thermal analysis of the reaction properties of raw and retorted oil shale with air

    SciTech Connect (OSTI)

    Wang, T.F.

    1984-01-01

    The results of a study to determine the kinetics of combustion of oil shale and its char by using differential thermal analysis are reported. The study indicates that Colorado oil shale and its char combustion rate is the fastest while Fushun oil shale and its char combustion rate is the slowest among the six oil shales used in this work. Oil shale samples used were Fushun oil shale, Maoming oil shale, Huang county oil shale, and Colorado oil shale.

  19. California Policy Should Distinguish Biofuels by Differential Global Warming Effects

    E-Print Network [OSTI]

    Kammen, Daniel M.

    California Policy Should Distinguish Biofuels by Differential Global Warming Effects by Richard J: _______________________________________ Date #12;California Policy Should Distinguish Biofuels by Differential Global Warming Effects Richard J, 2006 #12;#12;ABSTRACT California Policy Should Distinguish Biofuels by Differential Global Warming

  20. Security Evaluation against Differential Cryptanalysis for Block Cipher Structures

    E-Print Network [OSTI]

    International Association for Cryptologic Research (IACR)

    Security Evaluation against Differential Cryptanalysis for Block Cipher Structures Shengbao Wu1 lower bound of the minimal differential active S-boxes for various block cipher structures, but also provides an efficient way to select new structures with good properties against differential cryptanalysis

  1. French-Chinese School on Differential and Functional Equations

    E-Print Network [OSTI]

    Pouyanne, Nicolas

    French-Chinese School on Differential and Functional Equations Wuhan University Wuhan, China, April 16th-27th, 2012 #12;French-Chinese School on Differential and Functional Equations, Wuhan, China, April 16th-27th, 2012 French-Chinese School on Differential and Functional Equations Wuhan, China, April

  2. Pseudo Differential Operators and Integrable Systems in AXIOM

    E-Print Network [OSTI]

    Seiler, Werner M.

    Pseudo Differential Operators and Integrable Systems in AXIOM Werner M. Seiler ? Institut f: Depends on complexity of calculation No. of lines: ca. 1800 Keywords: Pseudo differential operators differential operators) are a useful tool in the theory of integrable system [1]. It is easily possible

  3. Dataset used to improve liquid water absorption models in the microwave

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Turner, David

    2015-12-14

    Two datasets, one a compilation of laboratory data and one a compilation from three field sites, are provided here. These datasets provide measurements of the real and imaginary refractive indices and absorption as a function of cloud temperature. These datasets were used in the development of the new liquid water absorption model that was published in Turner et al. 2015.

  4. Oxygen production by molten alkali metal salts using multiple absorption-desorption cycles

    DOE Patents [OSTI]

    Cassano, A.A.

    1985-07-02

    A continuous chemical air separation is performed wherein oxygen is recovered with a molten alkali metal salt oxygen acceptor in a series of absorption zones which are connected to a plurality of desorption zones operated in separate parallel cycles with the absorption zones. A greater recovery of high pressure oxygen is achieved at reduced power requirements and capital costs. 3 figs.

  5. PHYSICAL REVIEW A 88, 043428 (2013) Transient absorption spectra of the laser-dressed hydrogen atom

    E-Print Network [OSTI]

    Chu, Shih-I

    2013-01-01

    -dressed hydrogen atoms, based on numerical solutions of the time-dependent Schr¨odinger equation. The timing absorption spectra of hydrogen atoms based on numerical solutions of the time-dependent Schr¨odinger equationPHYSICAL REVIEW A 88, 043428 (2013) Transient absorption spectra of the laser-dressed hydrogen atom

  6. CFCl3 (CFC-11): UV absorption spectrum temperature dependence measurements and the impact on its

    E-Print Network [OSTI]

    Jackman, Charles H.

    CFCl3 (CFC-11): UV absorption spectrum temperature dependence measurements and the impact on its, the CFC-11 UV absorption spectrum was measured over a range of wavelength (184.95­230nm) and temperature that is removed primarily via stratospheric UV photolysis. Uncertainty in the temperature dependence of its UV

  7. Human vitamin B12 absorption measurement by accelerator mass spectrometry using specifically

    E-Print Network [OSTI]

    Roth, John R.

    Human vitamin B12 absorption measurement by accelerator mass spectrometry using specifically to assimilate dietary vitamin B12. Assaying and understanding absorption and uptake of B12 is important because and showed plasma appearance and clearance curves consistent with the predicted behavior of the pure vitamin

  8. Optical imaging of non-fluorescent nanodiamonds in live cells using transient absorption microscopy

    E-Print Network [OSTI]

    Huang, Yanyi

    Optical imaging of non-fluorescent nanodiamonds in live cells using transient absorption microscopy non-fluorescent nanodiamonds in living cells using transient absorption microscopy. This label of nanodiamonds under various conditions, confirming the endocytosis mechanism. Optical probes for live cell

  9. Near-Infrared Laser Absorption of Poly(vinyl chloride) at Elevated Temperatures

    E-Print Network [OSTI]

    Van de Ven, James D.

    Near-Infrared Laser Absorption of Poly(vinyl chloride) at Elevated Temperatures James D. Van de Ven, Arthur G. Erdman Mechanical Engineering Department, University of Minnesota, Minneapolis, Minnesota 55305 yields that little work has been done analyzing the relationship between light absorption and temperature

  10. Spin-dependent scattering and absorption of thermal neutrons on dynamically polarized nuclei

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    957 Spin-dependent scattering and absorption of thermal neutrons on dynamically polarized nuclei H neutrons and polarized nuclei have been used to measure spin-dependent scattering lengths and absorption cross sections of slow (S-wave) neutrons on nuclei. In order to obtain those scattering lengths

  11. Optimization of the absorption efficiency of an amorphous-silicon thin-film tandem solar cell

    E-Print Network [OSTI]

    to bring down the cost of photovoltaic (PV) solar cells has gained huge momentum, and many strategiesOptimization of the absorption efficiency of an amorphous-silicon thin-film tandem solar cell-wave approach was used to compute the plane-wave absorptance of a thin-film tandem solar cell with a metallic

  12. Electronic absorption spectra of linear and cyclic Cn in a neon matrix

    E-Print Network [OSTI]

    Maier, John Paul

    Electronic absorption spectra of linear and cyclic Cn + n=7­9 in a neon matrix Jan Fulara, and their electronic absorption spectra in 6 K neon matrices recorded. The linear and cyclic isomers of C7 + and C8 at 371 nm. Linear C8 + shows five dipole-allowed electronic transitions from the X~ 2 g ground state

  13. Theoretical Studiesof Transannular Interactions. 111. The Absorption and Emission Spectra of a

    E-Print Network [OSTI]

    Glass, Leon

    5063 Theoretical Studiesof Transannular Interactions. 111. The Absorption and Emission Spectra June 13, 1966 Abstract: An interpretationof the absorption and emission spectra of a multilayered and emission spectra of the paracyclophanes.2a In these compounds the sepa- ration of the aromatic rings, which

  14. Efficiency of pump absorption in double-clad fiber amplifiers. III. Calculation of modes

    E-Print Network [OSTI]

    Kouznetsov, Dmitrii

    Efficiency of pump absorption in double-clad fiber amplifiers. III. Calculation of modes Dmitrii us to calculate the efficiency of an incoherent pump in general-geometry double-clad fibers. This approach yields accurate estimates of the absorption rate of each mode of the pump in the first order

  15. Absorption free superluminal light propagation in a three level pump-probe system

    E-Print Network [OSTI]

    M. Mahmoudi; S. Worya Rabiei; L. Ebrahimi Zohravi; M. Sahrai

    2007-11-21

    We investigate the dispersion and the absorption properties of a weak probe field in a three-level pump-probe atomic system. It is shown that the slope of dispersion changes from positive to negative just with the intensity of the coherent or indirect incoherent pumping fields. It is demonstrated that the absorption free superluminal light propagation is appeared in this system.

  16. Structural Detuning of Pump Absorption Rate in Doped Fiber for the Enhancement of Power Conversion Efficiency

    E-Print Network [OSTI]

    Park, Namkyoo

    Structural Detuning of Pump Absorption Rate in Doped Fiber for the Enhancement of Power Conversion Doped Fiber Amplifier. With proper adjustments on doping profiles for the reduction of pump absorption rate, it becomes possible to optimize pump evolution map inside the doped fiber to get better power

  17. Effect of morphology and solvent on two-photon absorption of nano zinc oxide

    SciTech Connect (OSTI)

    Kavitha, M.K. [Department of Chemistry, Indian Institute of Space Science and Technology, Valiamala, Thiruvananthapuram 695547, Kerala (India); Haripadmam, P.C.; Gopinath, Pramod; Krishnan, Bindu [Department of Physics, Indian Institute of Space Science and Technology, Valiamala, Thiruvananthapuram 695547, Kerala (India); John, Honey, E-mail: honey@iist.ac.in [Department of Chemistry, Indian Institute of Space Science and Technology, Valiamala, Thiruvananthapuram 695547, Kerala (India)

    2013-05-15

    Highlights: ? ZnO nanospheres and triangular structures synthesis by novel precipitation technique. ? The effect of precursor concentration on the size and shape of nano ZnO. ? Open aperture Z-scan measurements of the ZnO nanoparticle dispersions. ? Nanospheres exhibit higher two photon absorption coefficient than triangular nanostructures. ? Nanospheres dispersed in water exhibit higher two photon absorption coefficient than its dispersion in 2-propanol. - Abstract: In this paper, we report the effect of morphology and solvent on the two-photon absorption of nano zinc oxide. Zinc oxide nanoparticles in two different morphologies like nanospheres and triangular nanostructures are synthesized by novel precipitation technique and their two-photon absorption coefficient is measured using open aperture Z-scan technique. Experimental results show that the zinc oxide nanospheres exhibit higher two-photon absorption coefficient than the zinc oxide triangular nanostructures. The zinc oxide nanospheres dispersed in water exhibit higher two-photon absorption coefficient than that of its dispersion in 2-propanol. The zinc oxide nanospheres dispersed in water shows a decrease in two-photon absorption coefficient with an increase in on-axis irradiance. The result confirms the dependence of shape and solvent on the two-photon absorption of nano zinc oxide.

  18. PHYSICAL REVIEW B 88, 195422 (2013) Cavity-enhanced absorption and Fano resonances in graphene nanoribbons

    E-Print Network [OSTI]

    2013-01-01

    graphene, is its ability to behave as a semiconductor whose band gap can be tuned in a wide frequency rangePHYSICAL REVIEW B 88, 195422 (2013) Cavity-enhanced absorption and Fano resonances in graphene 2013) We analyze the absorption of a graphene nanoribbon placed into an optical cavity. We demonstrate

  19. Oxygen production by molten alkali metal salts using multiple absorption-desorption cycles

    DOE Patents [OSTI]

    Cassano, Anthony A. (Allentown, PA)

    1985-01-01

    A continuous chemical air separation is performed wherein oxygen is recovered with a molten alkali metal salt oxygen acceptor in a series of absorption zones which are connected to a plurality of desorption zones operated in separate parallel cycles with the absorption zones. A greater recovery of high pressure oxygen is achieved at reduced power requirements and capital costs.

  20. Pseudopotential calculations and photothermal lensing measurements of two-photon absorption in solids

    SciTech Connect (OSTI)

    White, W.T. III

    1985-11-04

    We have studied two-photon absorption in solids theoretically and experimentally. We have shown that it is possible to use accurate band structure techniques to compute two-photon absorption spectra within 15% of measured values in a wide band-gap material, ZnS. The empirical pseudopotential technique that we used is significantly more accurate than previous models of two-photon absorption in zinc blende materials, including present tunneling theories (which are essentially parabolic-band results in disguise) and the nonparabolic-band formalism of Pidgeon et al. and Weiler. The agreement between our predictions and previous measurements allowed us to use ZnS as a reference material in order to validate a technique for measuring two-photon absorption that was previously untried in solids, pulsed dual-beam thermal lensing. With the validated technique, we examined nonlinear absorption in one other crystal (rutile) and in several glasses, including silicates, borosilicates, and one phosphate glass. Initially, we believed that the absorption edges of all the materials were comparable; however, subsequent evidence suggested that the effective band-gap energies of the glasses were above the energy of two photons in our measurement. Therefore, we attribute the nonlinear absorption that we observed in glasses to impurities or defects. The measured nonlinear absorption coefficients were of the order of a few cm/TW in the glasses and of the order of 10 cm/GW in the crystals, four orders of magnitude higher than in glasses. 292 refs.

  1. Ultra-Fast Absorption of Amorphous Pure Drug Aerosols Via Deep Lung Inhalation

    E-Print Network [OSTI]

    Rabinowitz, Joshua D.

    Ultra-Fast Absorption of Amorphous Pure Drug Aerosols Via Deep Lung Inhalation JOSHUA D. RABINOWITZ. A promising means of accelerating drug action is through rapid systemic drug administration via deep lung inhalation. The speed of pulmonary drug absorption depends on the site of aerosol deposition within the lung

  2. Non-Markovian quantum state diffusion for absorption spectra of molecular Jan Roden,1

    E-Print Network [OSTI]

    Eisfeld, Alexander

    with an efficient but abstract approximation was recently applied to calculate energy transfer and absorption the calculated (approximative) absorption spectra with exact results. These are obtained from the method aspects like the detailed shapes of Electronic address: eisfeld@mpipks-dresden.mpg.de the J-band [34

  3. Metal binding in proteins: machine learning complements X-ray absorption spectroscopy

    E-Print Network [OSTI]

    Passerini, Andrea

    Metal binding in proteins: machine learning complements X-ray absorption spectroscopy Marco Lippi1 for the identification of metalloproteins and metal binding sites on a genome scale. An extensive evaluation conducted in combination with X- ray absorption spectroscopy shows the great potentiality of the approach. 1 Metal binding

  4. Wafer-scale metasurface for total power absorption, local field enhancement and

    E-Print Network [OSTI]

    with near-complete absorption and record areas (4 inch wafers, i.e. ,80 cm2 ) using standard sputtering the silver nanoparticle island morphology. We discuss the physical interpretation of the perfect absorption phenomenon in terms of equivalent electric and magnetic surface currents. These are enabled by the SIOM

  5. Using observations of deep convective systems to constrain atmospheric column absorption of solar radiation in the

    E-Print Network [OSTI]

    Dong, Xiquan

    column absorption of solar radiation (Acol) is a fundamental part of the Earth's energy cycle.e., the Acol values at both regions converge to the same value ($0.27 of the total incoming solar radiation to constrain atmospheric column absorption of solar radiation in the optically thick limit, J. Geophys. Res

  6. Near-Edge X-Ray Absorption Fine Structure Spectroscopy of Diamondoid Thiol Monolayers on Gold

    SciTech Connect (OSTI)

    Willey, T.M.; Fabbri, J.D.; Lee, J.R.I.; Schreiner, P.R.; Fokin, A.A.; Tkachenko, B.A.; Fokina, N.A.; Dahl, J.E.P.; Carlson, R.M.K.; Vance, A.L.; Yang, W.; Terminello, L.J.; Buuren, T.van; Melosh, N.A.

    2009-05-26

    Diamondoids, hydrocarbon molecules with cubic-diamond-cage structures, have unique properties with potential value for nanotechnology. The availability and ability to selectively functionalize this special class of nanodiamond materials opens new possibilities for surface modification, for high-efficiency field emitters in molecular electronics, as seed crystals for diamond growth, or as robust mechanical coatings. The properties of self-assembled monolayers (SAMs) of diamondoids are thus of fundamental interest for a variety of emerging applications. This paper presents the effects of thiol substitution position and polymantane order on diamondoid SAMs on gold using near-edge X-ray absorption fine structure spectroscopy (NEXAFS) and X-ray photoelectron spectroscopy (XPS). A framework to determine both molecular tilt and twist through NEXAFS is presented and reveals highly ordered diamondoid SAMs, with the molecular orientation controlled by the thiol location. C 1s and S 2p binding energies are lower in adamantane thiol than alkane thiols on gold by 0.67 {+-} 0.05 and 0.16 {+-} 0.04 eV, respectively. These binding energies vary with diamondoid monolayer structure and thiol substitution position, consistent with different degrees of steric strain and electronic interaction with the substrate. This work demonstrates control over the assembly, in particular the orientational and electronic structure, providing a flexible design of surface properties with this exciting new class of diamond nanoparticles.

  7. Near-Edge X-ray Absorption Fine Structure Spectroscopy of Diamondoid Thiol Monolayers on Gold

    SciTech Connect (OSTI)

    Willey, T M; Fabbri, J; Lee, J I; Schreiner, P; Fokin, A A; Tkachenko, B A; Fokina, N A; Dahl, J; Carlson, B; Vance, A L; Yang, W; Terminello, L J; van Buuren, T; Melosh, N

    2007-11-27

    Diamondoids, hydrocarbon molecules with cubic-diamond-cage structures, have unique properties with potential value for nanotechnology. The availability and ability to selectively functionalize this special class of nanodiamond materials opens new possibilities for surface-modification, for high-efficiency field emitters in molecular electronics, as seed crystals for diamond growth, or as robust mechanical coatings. The properties of self-assembled monolayers (SAMs) of diamondoids are thus of fundamental interest for a variety of emerging applications. This paper presents the effects of thiol substitution position and polymantane order on diamondoid SAMs on gold using near-edge X-ray absorption fine structure spectroscopy (NEXAFS) and X-ray photoelectron spectroscopy (XPS). A framework to determine both molecular tilt and twist through NEXAFS is presented and reveals highly ordered diamondoid SAMs, with the molecular orientation controlled by the thiol location. C 1s and S 2p binding energies are lower in adamantane thiol than alkane thiols on gold by 0.67 {+-} 0.05 eV and 0.16 {+-} 0.04 eV respectively. These binding energies vary with diamondoid monolayer structure and thiol substitution position, consistent with different amounts of steric strain and electronic interaction with the substrate. This work demonstrates control over the assembly, in particular the orientational and electronic structure, providing a flexible design of surface properties with this exciting new class of diamond clusters.

  8. Gallium Solar Neutrino Experiments: Absorption Cross sections, Neutrino spectra, and Predicted Event Rates

    E-Print Network [OSTI]

    John N. Bahcall

    1997-10-28

    Neutrino absorption cross sections for 71Ga are calculated for all solar neutrino sources with standard energy spectra, and for laboratory sources of 51Cr and 37Ar; the calculations include, where appropriate, the thermal energy of fusing solar ions and use improved nuclear and atomic data. The ratio, R, of measured (in GALLEX and SAGE) to calculated 51Cr capture rate is R = 0.95 +/- 0.07 (exp)} + ^{+0.04}_{-0.03} (theory). Cross sections are also calculated for specific neutrino energies chosen so that a spline fit determines accurately the event rates in a gallium detector even if new physics changes the energy spectrum of solar neutrinos. Theoretical uncertainties are estimated for cross sections at specific energies and for standard neutrino energy spectra. Standard energy spectra are presented for pp and CNO neutrino sources in the appendices. Neutrino fluxes predicted by standard solar models, corrected for diffusion, have been in the range 120 SNU to 141 SNU since 1968.

  9. Absorption lines from magnetically-driven winds in X-ray binaries

    E-Print Network [OSTI]

    Chakravorty, S; Ferreira, J; Henri, G; Belmont, R; Clavel, M; Corbel, S; Rodriguez, J; Coriat, M; Drappeau, S; Malzac, J

    2016-01-01

    High resolution X-ray spectra of black hole X-ray binaries (BHBs) show blueshifted absorption lines from disk winds which seem to be equatorial. Winds occur in the Softer (disk-dominated) states of the outburst and are less prominent or absent in the Harder (power-law dominated) states. We use self-similar magneto-hydrodynamic (MHD) accretion-ejection models to explain the disk winds in BHBs. In our models, the density at the base of the outflow from the accretion disk is not a free parameter, but is determined by solving the full set of dynamical MHD equations. Thus the physical properties of the outflow are controlled by the global structure of the disk. We studied different MHD solutions characterized by different values of (a) the disk aspect ratio ($\\varepsilon$) and (b) the ejection efficiency ($p$). We use two kinds of MHD solutions depending on the absence (cold solution) or presence (warm solution) of heating at the disk surface. Such heating could be from e.g. dissipation of energy due to MHD turbul...

  10. Development of a gas-fired absorption heat pump

    SciTech Connect (OSTI)

    Ohuchi, Y.

    1985-01-01

    A new absorbent-refrigerant pair suitable for heat pump heating and air-cooled cooling has been developed. Water has been selected as the refrigerant, mainly from the viewpoint of high cycle efficiency and safety, while a 1:1 mixture of lithium bromide (LiBr) and zinc chloride (ZnCl/sub 2/) by weight has been chosen as the absorbent in view of its higher solubility and affinity for water. Based on thermodynamic analysis with experimental data on properties, the new absorbent solution will give a heating COP of 1.57 and a cooling COP of 1.00 as gross values of double-effect absorption cycles, including a boiler efficiency of 80%. As a result of an experimental investigation on corrosiveness and corrosion inhibitors, promising equipment materials and inhibitors have been discovered. Prototypical units of 3.5kw (1-ton) and 35kw (10-ton) have been installed and are undergoing demonstration testing in the laboratory.

  11. Constraining the reionization history with QSO absorption spectra

    E-Print Network [OSTI]

    S. Gallerani; T. Roy Choudhury; A. Ferrara

    2006-05-15

    We use a semi-analytical approach to simulate absorption spectra of QSOs at high redshifts with the aim of constraining the cosmic reionization history. We consider two physically motivated and detailed reionization histories: (i) an Early Reionization Model (ERM) in which the intergalactic medium is reionized by PopIII stars at $z\\approx 14$, and (ii) a more standard Late Reionization Model (LRM) in which overlapping, induced by QSOs and normal galaxies, occurs at $z\\approx 6$. From the analysis of current Ly$\\alpha$ forest data at $z 6$, however, clear differences start to emerge which are best quantified by the dark gap and peak width distributions. We find that 35 (zero) per cent of the lines of sight within $5.750$ Angstrom in the rest frame of the QSO if reionization is not (is) complete at $z \\gtrsim 6$. Similarly, the ERM predicts peaks of width $\\sim 1$ Angstrom in 40 per cent of the lines of sight in the redshift range $6.0-6.6$; in the same range, LRM predicts no peaks of width $>0.8$ Angstrom. We conclude that the dark gap and peak width statistics represent superb probes of cosmic reionization if about ten QSOs can be found at $z > 6$. We finally discuss strengths and limitations of our method.

  12. Quantitative infrared absorption cross sections of isoprene for atmospheric measurements

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Brauer, C. S.; Blake, T. A.; Guenther, A. B.; Sharpe, S. W.; Sams, R. L.; Johnson, T. J.

    2014-11-19

    Isoprene (C5H8, 2-methyl-1,3-butadiene) is a volatile organic compound (VOC) and is one of the primary contributors to annual global VOC emissions. Isoprene is produced primarily by vegetation as well as anthropogenic sources, and its OH- and O3-initiated oxidations are a major source of atmospheric oxygenated organics. Few quantitative infrared studies have been reported for isoprene, limiting the ability to quantify isoprene emissions via remote or in situ infrared detection. We thus report absorption cross sections and integrated band intensities for isoprene in the 600–6500 cm-1 region. The pressure-broadened (1 atmosphere N2) spectra were recorded at 278, 298, and 323 Kmore »in a 19.94 cm path-length cell at 0.112 cm-1 resolution, using a Bruker IFS 66v/S Fourier transform infrared (FTIR) spectrometer. Composite spectra are derived from a minimum of seven isoprene sample pressures, each at one of three temperatures, and the number densities are normalized to 296 K and 1 atm.« less

  13. High power laser heating of low absorption materials

    SciTech Connect (OSTI)

    Olson, K.; Talghader, J.; Ogloza, A.; Thomas, J.

    2014-09-28

    A model is presented and confirmed experimentally that explains the anomalous behavior observed in continuous wave (CW) excitation of thermally isolated optics. Distributed Bragg Reflector (DBR) high reflective optical thin film coatings of HfO? and SiO?were prepared with a very low absorption, about 7 ppm, measured by photothermal common-path interferometry. When illuminated with a 17 kW CW laser for 30 s, the coatings survived peak irradiances of 13 MW/cm², on 500 ?m diameter spot cross sections. The temperature profile of the optical surfaces was measured using a calibrated thermal imaging camera for illuminated spot sizes ranging from 500 ?m to 5 mm; about the same peak temperatures were recorded regardless of spot size. This phenomenon is explained by solving the heat equation for an optic of finite dimensions and taking into account the non-idealities of the experiment. An analytical result is also derived showing the relationship between millisecond pulse to CW laser operation where (1) the heating is proportional to the laser irradiance (W/m²) for millisecond pulses, (2) the heating is proportional to the beam radius (W/m) for CW, and (3) the heating is proportional to W/m? tan?¹(?(t)/m) in the transition region between the two.

  14. Model for J/psi absorption in hadronic matter 

    E-Print Network [OSTI]

    Lin, ZW; Ko, Che Ming.

    2000-01-01

    M 1inlD e2ne3l , ~14! with 034903- M 1anl52gpDD*gcDD~22p11p3!l 3S 1 t2mD 2 D ~p12p31p4!n, M 1bnl5gpDD*gcD*D*~2p12p4!aS 1 u2mD* 2 D 3F gab2 ~p12p4!a~p12p4!b mD* 2 G 3@~2p22p3!bgnl1~2p11p21p4!lgbn 1~p11p32p4!ngbl# , M 1cnl52gpc...- tions for J/c absorption by p and r mesons are then evalu- ated. The amplitudes for the coherent sum of individual dia- grams are checked to ensure that the hadronic currentis conserved in the limit of zero vector meson masses. We then show in Sec...

  15. Ultracompact Field Effect Electro-Absorption Plasmonic Modulator

    E-Print Network [OSTI]

    Shi, Kaifeng

    2015-01-01

    One of the technical barriers impeding the wide applications of integrated photonic circuits is the lack of ultracompact, high speed, broadband electro-optical (EO) modulators, which up-convert electronic signals into high bit-rate photonic data. In addition to direct modulation of lasers, EO modulators can be classified into (i) phase modulation based on EO effect or free-carrier injection, or (ii) absorption modulation based on Franz-Keldysh effect or quantum-confined Stark effect. Due to the poor EO properties of regular materials, a conventional EO modulator has a very large footprint. Based on high-Q resonators, recent efforts have advanced EO modulators into microscale footprints, which have nearly reached their physical limits restricted by the materials. On-chip optical interconnects require ultrafast EO modulators at the nanoscale. The technical barrier may not be well overcome based on conventional approaches and well-known materials. Herein, we report an EO modulator, more specifically electro-abso...

  16. Laser absorption spectroscopy system for vaporization process characterization and control

    SciTech Connect (OSTI)

    Galkowski, J.; Hagans, K.

    1993-09-07

    In support of the Lawrence Livermore National Laboratory`s (LLNL`s) Uranium Atomic Vapor Laser Isotope Separation (U-AVLIS) Program, a laser atomic absorption spectroscopy (LAS) system has been developed. This multi-laser system is capable of simultaneously measuring the line densities of {sup 238}U ground and metastable states, {sup 235}U ground and metastable states, iron, and ions at up to nine locations within the separator vessel. Supporting enrichment experiments that last over one hundred hours, this laser spectroscopy system is employed to diagnose and optimize separator system performance, control the electron beam vaporizer and metal feed systems, and provide physics data for the validation of computer models. As a tool for spectroscopic research, vapor plume characterization, vapor deposition monitoring, and vaporizer development, LLNL`s LAS laboratory with its six argon-ion-pumped ring dye lasers and recently added Ti:Sapphire and external-cavity diode-lasers has capabilities far beyond the requirements of its primary mission.

  17. Photodetector with absorbing region having resonant periodic absorption between reflectors

    DOE Patents [OSTI]

    Bryan, R.P.; Olbright, G.R.; Brennan, T.M.; Tsao, J.Y.

    1995-02-14

    A photodetector is disclosed that is responsive to a wavelength or wavelengths of interest which have heretofore been unrealized. The photodetector includes a resonant cavity structure bounded by first and second reflectors, the resonant cavity structure being resonant at the wavelength or wavelengths of interest for containing a plurality of standing waves therein. The photodetector further includes a radiation absorbing region disposed within the resonant cavity structure, the radiation absorbing region including a plurality of radiation absorbing layers spaced apart from one another by a distance substantially equal to a distance between antinodes of adjacent ones of the standing waves. Each of radiation absorbing layers is spatially positioned at a location of one of the antinodes of one of the standing waves such that radiation absorption is enhanced. The radiation absorbing layers may be either bulk layers or quantum wells includes a plurality of layers, each of which is comprised of a strained layer of InGaAs. Individual ones of the InGaAs layers are spaced apart from one another by a GaAs barrier layer. 11 figs.

  18. Photodetector with absorbing region having resonant periodic absorption between reflectors

    DOE Patents [OSTI]

    Bryan, Robert P. (Boulder, CO); Olbright, Gregory R. (Boulder, CO); Brennan, Thomas M. (Albuquerque, NM); Tsao, Jeffrey Y. (Albuquerque, NM)

    1995-02-14

    A photodetector that is responsive to a wavelength or wavelengths of interest which have heretofore been unrealized. The photodetector includes a resonant cavity structure bounded by first and second reflectors, the resonant cavity structure being resonant at the wavelength or wavelengths of interest for containing a plurality of standing waves therein. The photodetector further includes a radiation absorbing region disposed within the resonant cavity structure, the radiation absorbing region including a plurality of radiation absorbing layers spaced apart from one another by a distance substantially equal to a distance between antinodes of adjacent ones of the standing waves. Each of radiation absorbing layers is spatially positioned at a location of one of the antinodes of one of the standing waves such that radiation absorption is enhanced. The radiation absorbing layers may be either bulk layers or quantum wells includes a plurality of layers, each of which is comprised of a strained layer of InGaAs. Individual ones of the InGaAs layers are spaced apart from one another by a GaAs barrier layer.

  19. Parameterized algorithms for quantitative differentials in spectrally equivalent medical diagnostic x-ray beams

    SciTech Connect (OSTI)

    Okunade, Akintunde Akangbe [Department of Physics, Obafemi Awolowo University, Ile-Ife, Osun State (Nigeria)

    2005-06-15

    Qualitative and quantitative equivalence of spectra transmitted by two different elemental filters require a good match in terms of shape and size over the entire energy range of 0-150 keV used in medical diagnostic radiology. However, the photoelectric absorptions and Compton scattering involved in the interaction of x rays with matter at these relatively low photon energies differ in a nonuniform manner with energy and atomic number. By careful choice of thicknesses for filter materials with an atomic number between 12 and 39, when compared with aluminum, it is possible to obtain transmitted beams of the same shape (quality) but not of the same size (quantity). In this paper, calculations have been carried out for the matching of the shapes and sizes of beams transmitted through specified thicknesses of aluminium filter and spectrally equivalent thicknesses of other filter materials (different from aluminium) using FORTRAN source codes traceable to the American Association of Physics in Medicine (AAPM), College Park, MD, USA. Parametrized algorithms for the evaluation of quantitative differentials (deficit or surplus) in radiation output (namely, photon fluence, exposure, kerma, energy imparted, absorbed dose, and effective dose) from these transmitted spectrally equivalent beams were developed. These differentials range between 1%, and 4% at 1 mm Al filtration and between 8%, and 25% for filtration of 6 mm Al for different filter materials in comparison with aluminum. Also developed were models for factors for converting measures of photon fluence, exposure-area product, (EAP), and kerma-area product (KAP) to risk related quantities such as energy imparted, absorbed dose, and effective dose from the spectrally equivalent beams. The thicknesses of other filter materials that are spectrally equivalent to given thicknesses of aluminum filter were characterized using polynomial functions. The fact that the use of equivalent spectra in radiological practice can provide means of ranking the differentials in radiographic image quality and stochastic risk is discussed.

  20. Control of acoustic absorption in 1D scattering by indirect coupled resonant scatterers

    E-Print Network [OSTI]

    Merkel, A; Richoux, O; Romero-García, V; Pagneux, V

    2015-01-01

    We experimentally report perfect acoustic absorption through the interplay of the inherent losses and transparent modes with high $Q$ factor. These modes are generated in a two-port, one-dimensional waveguide which is side-loaded by isolated resonators of moderate $Q$ factor. In symmetric structures, we show that in the presence of small inherent losses, these modes lead to coherent perfect absorption associated with one-sided absorption slightly larger than 0.5. In asymmetric structures, near perfect one-sided absorption is possible (96 \\%) with a deep sub-wavelength sample ($\\lambda/28$). The control of strong absorption by the proper tuning of few resonators with weak losses will open new possibilities in various wave-control devices.

  1. DETERMINING INTERSTELLAR CARBON ABUNDANCES FROM STRONG-LINE TRANSITIONS

    SciTech Connect (OSTI)

    Sofia, U. J. [Physics Department, American University, Washington, DC 20016 (United States); Parvathi, V. S.; Babu, B. R. S. [Physics Department, University of Calicut, Kerala (India); Murthy, J. [Indian Institute of Astrophysics, Kormangala, Bengaluru (India)

    2011-01-15

    Carbon is arguably the most important element in the interstellar medium, yet its abundance in gas and dust is poorly understood due to a paucity of data. We explore the possibility of substantially increasing our knowledge of interstellar carbon by applying and assessing a new method for determining the column density of the dominant ion of interstellar carbon in diffuse neutral lines of sight. The method relies on profile fitting of the strong transition of C II at 1334 A in spectra continuum normalized with stellar models. We apply our method to six sight lines for which the carbon abundance has previously been determined with a weak intersystem absorption transition. Our strong-line method consistently shows a significantly lower gas-phase C abundance than the measurements from the weak lines. This result implies that more carbon could reside in dust than was previously thought. This has implications for dust models, which often suffer from a lack of sufficient carbon to plausibly explain extinction. There is no immediately clear explanation for the difference found between the strong- and weak-line C II determinations, but there are indications that the results from the method presented here have advantages over the weak-line column densities. If this is the case, then the reported oscillator strength for the C II transition at 2325 A may be too small. Our findings further suggest that damping wings modeled with a single absorption component may not produce accurate abundances. This problem could affect a large number of H I abundances determined through absorption line analysis that are reported in the literature.

  2. Investigation of free charge carrier dynamics in single-crystalline CVD diamond by two-photon absorption

    SciTech Connect (OSTI)

    Ivakin, E V; Kisialiou, I G [B.I. Stepanov Institute of Physics, National Academy of Sciences of Belarus, Minsk (Belarus); Ralchenko, V G; Bolshakov, A P; Ashkinazi, E E [A M Prokhorov General Physics Institute, Russian Academy of Sciences, Moscow (Russian Federation); Sharonov, G V [A.N. Sevchenko Research Institute of Applied Physics Problems, Belarusian State University, Minsk (Belarus)

    2014-11-30

    By using the methods of transient gratings (TGs) and induced absorption, we have studied the kinetics of plasma of free charge carriers (FCCs) created by the action of a picosecond laser pulse in two high-purity diamond single crystals synthesised from the gas phase. The gratings with different spatial periods have been excited at the wavelengths of 266 or 213 nm (above and below the fundamental absorption edge in diamond) and probed with continuous-wave radiation in the visible region. At the moderate FCC concentrations (?7 × 10{sup 17} cm{sup -3}), the coefficient of ambipolar diffusion and the carrier recombination time of two crystals are 20.3 and 18.9 cm{sup 2} s{sup -1} and 30 and 190 ns, respectively. The increase in the carrier concentration up to 5 × 10{sup 19} cm{sup -3} reduces the TG lifetime. We have determined the conditions under which the relaxation of the grating of carriers leads to the formation of a thermal grating, with the amplitude sufficient for its experimental observation. (interaction of laser radiation with matter. laser plasma)

  3. MAGIICAT III. Interpreting Self-Similarity of the Circumgalactic Medium with Virial Mass using MgII Absorption

    E-Print Network [OSTI]

    Churchill, Christopher W; Nielsen, Nikole M; Kacprzak, Glenn G

    2013-01-01

    In Churchill et al., we used halo abundance matching applied to 182 galaxies in the MAGIICAT MgII Absorption-Galaxy Catalog (Nielsen et al.) and showed that the mean MgII 2796 equivalent width follows a tight inverse-square power law, W_r(2796) ~ (D/R_vir)^-2, with projected location relative to the galaxy virial radius and that the MgII absorption covering fraction is invariant with galaxy virial mass, M_h, over the range 10.7 impact parameter, virial radius, and the theoretical cooling radius that further elucidate self-similarity in the cool/warm (T=10^{4-4.5} K) circumgalactic medium (CGM) with virial mass. We show that virial mass determines the extent and strength of the MgII absorbing gas such that the mean W_r(2796) increases with virial mass at fixed distance while decreasing with galactocentric distance for fixed virial mass. The majority of the absorbing gas resides within D ~ 0.3 R_vir, ...

  4. Backscattering and absorption coefficients for electrons: Solutions of invariant embedding transport equations using a method of convergence

    SciTech Connect (OSTI)

    Figueroa, C.; Brizuela, H.; Heluani, S. P.

    2014-05-21

    The backscattering coefficient is a magnitude whose measurement is fundamental for the characterization of materials with techniques that make use of particle beams and particularly when performing microanalysis. In this work, we report the results of an analytic method to calculate the backscattering and absorption coefficients of electrons in similar conditions to those of electron probe microanalysis. Starting on a five level states ladder model in 3D, we deduced a set of integro-differential coupled equations of the coefficients with a method know as invariant embedding. By means of a procedure proposed by authors, called method of convergence, two types of approximate solutions for the set of equations, namely complete and simple solutions, can be obtained. Although the simple solutions were initially proposed as auxiliary forms to solve higher rank equations, they turned out to be also useful for the estimation of the aforementioned coefficients. In previous reports, we have presented results obtained with the complete solutions. In this paper, we present results obtained with the simple solutions of the coefficients, which exhibit a good degree of fit with the experimental data. Both the model and the calculation method presented here can be generalized to other techniques that make use of different sorts of particle beams.

  5. Temperature determination using pyrometry

    DOE Patents [OSTI]

    Breiland, William G. (Albuquerque, NM); Gurary, Alexander I. (Bridgewater, NJ); Boguslavskiy, Vadim (Princeton, NJ)

    2002-01-01

    A method for determining the temperature of a surface upon which a coating is grown using optical pyrometry by correcting Kirchhoff's law for errors in the emissivity or reflectance measurements associated with the growth of the coating and subsequent changes in the surface thermal emission and heat transfer characteristics. By a calibration process that can be carried out in situ in the chamber where the coating process occurs, an error calibration parameter can be determined that allows more precise determination of the temperature of the surface using optical pyrometry systems. The calibration process needs only to be carried out when the physical characteristics of the coating chamber change.

  6. An Interesting Class of Partial Differential Equations

    E-Print Network [OSTI]

    Wen-an Yong

    2007-08-28

    This paper presents an observation that under reasonable conditions, many partial differential equations from mathematical physics possess three structural properties. One of them can be understand as a variant of the celebrated Onsager reciprocal relation in Modern Thermodynamics. It displays a direct relation of irreversible processes to the entropy change. We show that the properties imply various entropy dissipation conditions for hyperbolic relaxation problems. As an application of the observation, we propose an approximation method to solve relaxation problems. Moreover, the observation is interpreted physically and verified with eight (sets of) systems from different fields.

  7. Reducing differential equations for multiloop master integrals

    E-Print Network [OSTI]

    Roman N. Lee

    2015-04-21

    We present an algorithm of the reduction of the differential equations for master integrals the Fuchsian form with the right-hand side matrix linearly depending on dimensional regularization parameter $\\epsilon$. We consider linear transformations of the functions column which are rational in the variable and in $\\epsilon$. Apart from some degenerate cases described below, the algorithm allows one to obtain the required transformation or to ascertain irreducibility to the form required. Degenerate cases are quite anticipated and likely to correspond to irreducible systems.

  8. Integration of PDEs by differential geometric means

    E-Print Network [OSTI]

    Naghmana Tehseen; Geoff Prince

    2013-02-22

    We use Vessiot theory and exterior calculus to solve partial differential equations(PDEs) of the type uyy = F(x, y,u,ux,uy,uxx,uxy) and associated evolution equations. These equations are represented by the Vessiot distribution of vector fields. We develop and apply an algorithm to find the largest integrable sub-distributions and hence solutions of the PDEs. We then apply the integrating factor technique [19] to integrate this integrable Vessiot sub-distribution. The method is successfully applied to a large class of linear and non-linear PDEs.

  9. CO2 Capture by Absorption with Potassium Carbonate

    SciTech Connect (OSTI)

    Gary T. Rochelle; Eric Chen; Babatunde Oyenekan; Andrew Sexton; Jason Davis; Marus Hiilliard; Qing Xu; David Van Wagener; Jorge M. Plaza

    2006-12-31

    The objective of this work is to improve the process for CO{sub 2} capture by alkanolamine absorption/stripping by developing an alternative solvent, aqueous K{sub 2}CO{sub 3} promoted by piperazine. The best solvent and process configuration, matrix with MDEA/PZ, offers 22% and 15% energy savings over the baseline and improved baseline, respectively, with stripping and compression to 10 MPa. The energy requirement for stripping and compression to 10 MPa is about 20% of the power output from a 500 MW power plant with 90% CO{sub 2} removal. The stripper rate model shows that a ''short and fat'' stripper requires 7 to 15% less equivalent work than a ''tall and skinny'' one. The stripper model was validated with data obtained from pilot plant experiments at the University of Texas with 5m K{sup +}/2.5m PZ and 6.4m K{sup +}/1.6m PZ under normal pressure and vacuum conditions using Flexipac AQ Style 20 structured packing. Experiments with oxidative degradation at low gas rates confirm the effects of Cu{sup +2} catalysis; in MEA/PZ solutions more formate and acetate is produced in the presence of Cu{sup +2}. At 150 C, the half life of 30% MEA with 0.4 moles CO{sub 2}/mole amine is about 2 weeks. At 100 C, less than 3% degradation occurred in two weeks. The solubility of potassium sulfate in MEA solution increases significantly with CO{sub 2} loading and decreases with MEA concentration. The base case corrosion rate in 5 M MEA/1,2M PZ is 22 mpy. With 1 wt% heat stable salt, the corrosion rate increases by 50% to 160% in the order: thiosulfate< oxalate

  10. NEPA Determination Complete

    Broader source: Energy.gov [DOE]

    DOE has determined that this proposed project is a major Federal action that may significantly affect the quality of the human environment. To comply with the National Environmental Policy Act ...

  11. Method for Operating a Sensor to Differentiate Between Analytes in a Sample

    DOE Patents [OSTI]

    Kunt, Tekin; Cavicchi, Richard E.; Semancik, Stephen; McAvoy, Thomas J.

    1998-07-28

    Disclosed is a method for operating a sensor to differentiate between first and second analytes in a sample. The method comprises the steps of determining a input profile for the sensor which will enhance the difference in the output profiles of the sensor as between the first analyte and the second analyte; determining a first analyte output profile as observed when the input profile is applied to the sensor; determining a second analyte output profile as observed when the temperature profile is applied to the sensor; introducing the sensor to the sample while applying the temperature profile to the sensor, thereby obtaining a sample output profile; and evaluating the sample output profile as against the first and second analyte output profiles to thereby determine which of the analytes is present in the sample.

  12. SIGNATURE OF DIFFERENTIAL ROTATION IN SUN-AS-A-STAR Ca II K MEASUREMENTS

    SciTech Connect (OSTI)

    Bertello, L.; Pietarila, A.; Pevtsov, A. A. E-mail: apietarila@nso.edu

    2012-12-10

    The characterization of solar surface differential rotation (SDR) from disk-integrated chromospheric measurements has important implications for the study of differential rotation and dynamo processes in other stars. Some chromospheric lines, such as Ca II K, are very sensitive to the presence of activity on the disk and are an ideal choice for investigating SDR in Sun-as-a-star observations. Past studies indicate that when the activity is low, the determination of Sun's differential rotation from integrated-sunlight measurements becomes uncertain. However, our study shows that using the proper technique, SDR can be detected from these type of measurements even during periods of extended solar minima. This paper describes results from the analysis of the temporal variations of Ca II K line profiles observed by the Integrated Sunlight Spectrometer during the declining phase of Cycle 23 and the rising phase of Cycle 24, and discusses the signature of SDR in the power spectra computed from time series of parameters derived from these profiles. The methodology described is quite general, and could be applied to photometric time series of other main-sequence stars for detecting differential rotation.

  13. Sensitivity analysis of the MM5 weather model using automatic differentiation

    SciTech Connect (OSTI)

    Bischof, C.H. [Mathematics and Computer Science Division, Argonne National Laboratory, Argonne, Illinois 60439 (United States)] [Mathematics and Computer Science Division, Argonne National Laboratory, Argonne, Illinois 60439 (United States); Pusch, G.D. [Physics Department, Michigan State University, East Lansing, Michigan 48842 (United States)] [Physics Department, Michigan State University, East Lansing, Michigan 48842 (United States); Knoesel, R. [Mathematics and Computer Science Division, Argonne National Laboratory, Argonne, Illinois 60439 (United States)] [Mathematics and Computer Science Division, Argonne National Laboratory, Argonne, Illinois 60439 (United States)

    1996-11-01

    We present a general method for using automatic differentiation to facilitate model sensitivity analysis. Automatic differentiation techniques augment, in a completely mechanical fashion, an existing code such that it also simultaneously and efficiently computes derivatives. Our method allows the sensitivities of the code{close_quote}s outputs to its parameters and inputs to be determined with minimal human effort by exploiting the relationship between differentiation and formal perturbation theory. Employing this methodology, we performed a sensitivity study of the MM5 code, a mesoscale weather model jointly developed by Penn State University and the National Center for Atmospheric Research, that is composed of roughly 40,000 lines of Fortran 77 code. Our results show that automatic differentiation-computed sensitivities exhibit superior accuracy compared to divided difference approximations computed from finite-amplitude perturbations. We also comment on a numerically induced precursor wave that would almost certainly have been undetectable if one used a divided difference method. {copyright} {ital 1996 American Institute of Physics.}

  14. AUTOMATIC DIFFERENTIATION OF AN EULERIAN HYDROCODE

    SciTech Connect (OSTI)

    R. HENNINGER; A. CARLE; P. MAUDLIN

    2000-11-01

    Automatic differentiation (AD) is applied to a two-dimensional Eulerian hydrodynamics computer code (hydrocode) to provide gradients that will be used for design optimization and uncertainty analysis. We examine AD in both the forward and adjoint (reverse) mode using Automatic Differentiation of Fortran (ADIFOR, version 3.0). Setup time, accuracy, and run times are described for three problems. The test set consists of a one-dimensional shock-propagation problem, a two-dimensional metal-jet-formation problem and a two-dimensional shell-collapse problem. Setup time for ADIFOR was approximately one month starting from a simplified, fixed-dimension version of the original code. ADIFOR produced accurate (as compared to finite difference) gradients in both modes for all of the problems. These test problems had 17 independent variables. We find that the forward mode is up to 39% slower and the adjoint mode is at least 11% faster than finding the gradient by means of finite differences. Problems of real interest will certainly have more independent variables. The adjoint mode is thus favored since the computational time increases only slightly for additional independent variables.

  15. Differential white cell count by centrifugal microfluidics.

    SciTech Connect (OSTI)

    Sommer, Gregory Jon; Tentori, Augusto M.; Schaff, Ulrich Y.

    2010-07-01

    We present a method for counting white blood cells that is uniquely compatible with centrifugation based microfluidics. Blood is deposited on top of one or more layers of density media within a microfluidic disk. Spinning the disk causes the cell populations within whole blood to settle through the media, reaching an equilibrium based on the density of each cell type. Separation and fluorescence measurement of cell types stained with a DNA dye is demonstrated using this technique. The integrated signal from bands of fluorescent microspheres is shown to be proportional to their initial concentration in suspension. Among the current generation of medical diagnostics are devices based on the principle of centrifuging a CD sized disk functionalized with microfluidics. These portable 'lab on a disk' devices are capable of conducting multiple assays directly from a blood sample, embodied by platforms developed by Gyros, Samsung, and Abaxis. [1,2] However, no centrifugal platform to date includes a differential white blood cell count, which is an important metric complimentary to diagnostic assays. Measuring the differential white blood cell count (the relative fraction of granulocytes, lymphocytes, and monocytes) is a standard medical diagnostic technique useful for identifying sepsis, leukemia, AIDS, radiation exposure, and a host of other conditions that affect the immune system. Several methods exist for measuring the relative white blood cell count including flow cytometry, electrical impedance, and visual identification from a stained drop of blood under a microscope. However, none of these methods is easily incorporated into a centrifugal microfluidic diagnostic platform.

  16. Direct Exoplanet Detection with Binary Differential Imaging

    E-Print Network [OSTI]

    Rodigas, Timothy J; Mamajek, Eric E; Males, Jared R; Close, Laird M; Morzinski, Katie; Hinz, Philip M; Kaib, Nathan

    2015-01-01

    Binaries are typically excluded from direct imaging exoplanet surveys. However, the recent findings of Kepler and radial velocity programs show that planets can and do form in binary systems. Here, we suggest that visual binaries offer unique advantages for direct imaging. We show that Binary Differential Imaging (BDI), whereby two stars are imaged simultaneously at the same wavelength within the isoplanatic patch at high Strehl ratio, offers improved point spread function (PSF) subtraction that can result in increased sensitivity to planets close to each star. We demonstrate this by observing a young visual binary separated by 4\\asec ~with MagAO/Clio-2 at 3.9 \\microns, where the Strehl ratio is high, the isoplanatic patch is large, and giant planets are bright. Comparing BDI to angular differential imaging (ADI), we find that BDI's 5$\\sigma$ contrast is \\about 0.5 mags better than ADI's within \\about 1\\asec ~for the particular binary we observed. Because planets typically reside close to their host stars, BD...

  17. Standard practice for evaluating absorptive solar receiver materials when exposed to conditions simulating stagnation in solar collectors with cover plates

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    1986-01-01

    Standard practice for evaluating absorptive solar receiver materials when exposed to conditions simulating stagnation in solar collectors with cover plates

  18. Low differential pressure and multiphase flow measurements by means of differential pressure devices 

    E-Print Network [OSTI]

    Justo, Hernandez Ruiz,

    2004-11-15

    The response of slotted plate, Venturi meter and standard orifice to the presence of two phase, three phase and low differential flows was investigated. Two mixtures (air-water and air-oil) were used in the two-phase analysis while a mixture of air...

  19. Effect of electron density profile on power absorption of high frequency electromagnetic waves in plasma

    SciTech Connect (OSTI)

    Xi Yanbin; Liu Yue [MOE Key Laboratory of Materials Modification by Laser, Electron, and Ion Beams, School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 (China)

    2012-07-15

    Considering different typical electron density profiles, a multi slab approximation model is built up to study the power absorption of broadband (0.75-30 GHz) electromagnetic waves in a partially ionized nonuniform magnetized plasma layer. Based on the model, the power absorption spectra for six cases are numerically calculated and analyzed. It is shown that the absorption strongly depends on the electron density fluctuant profile, the background electron number density, and the collision frequency. A potential optimum profile is also analyzed and studied with some particular parameters.

  20. Multi-channel Absorption of Photons at Energies above 1 TeV

    E-Print Network [OSTI]

    A. Subramanian

    2006-07-24

    It is shown that the absorption of photons at energies > 1 TeV (much higher than the mass of the Higgs boson ~ 100 GeV) is a multi-channel one as opposed to the purely electron pair like absorption at lower energies. The observation on muons and gamma rays from Cygnus X-3 point source at these energies (1 TeV to 10 TeV) is quantitatively accounted for. The expected multi-channel cross-sections of photons in air as a function of energy is given both for Coulomb dissociation and nuclear absorption upto limiting energies of 10^9 GeV.

  1. Fiducial and differential cross sections of Higgs boson production measured in the four-lepton decay channel in pp collisions at ?s = 8 TeV with the ATLAS detector

    E-Print Network [OSTI]

    Taylor, Frank E.

    Measurements of fiducial and differential cross sections of Higgs boson production in the H?ZZ*?4? decay channel are presented. The cross sections are determined within a fiducial phase space and corrected for detection ...

  2. Colostral immunoglobulins and their absorption by newborn beef calves 

    E-Print Network [OSTI]

    Vann, Rhonda Carol

    1993-01-01

    Brahman (B;n=20) and Angus (A;n=l 9) cows bred to B or A bulls to produce BxB (n=l 1), AxB (n=9), BxA(n=l 1) and AxA (n=8) calves were used to determine the oW of breed of service sire (Sire), breed of dam (Dam) and sex of calf (Sex...

  3. Improvement of infrared single-photon detectors absorptance by integrated plasmonic structures

    E-Print Network [OSTI]

    Najafi, Faraz

    Plasmonic structures open novel avenues in photodetector development. Optimized illumination configurations are reported to improve p-polarized light absorptance in superconducting-nanowire single-photon detectors (SNSPDs) ...

  4. Efficient solar cooling: first ever non-tracking solar collectors powering a double effect absorption chiller

    E-Print Network [OSTI]

    Poiry, Heather Marie

    2011-01-01

    of a Solar Absorption Cooling and Heating System in CarnegieUsed for Grain Depot Cooling." Applied Thermal EngineeringKreith, Jan F. Kreider. "Solar Cooling." Principles of Solar

  5. Enhanced Gas Absorption in the Ionic Liquid 1-n-Hexyl-3-methylimidazol...

    Office of Scientific and Technical Information (OSTI)

    Enhanced Gas Absorption in the Ionic Liquid 1-n-Hexyl-3-methylimidazolium Bis(trifluoromethylsulfonyl)amide (hmimTfsub 2N) Confined in Silica Slit Pores: A Molecular...

  6. Use Low-Grade Waste Steam to Power Absorption Chillers - Steam Tip Sheet #14

    SciTech Connect (OSTI)

    2012-01-31

    This revised AMO tip sheet on waste steam to power absorption chillers provides how-to advice for improving the system using low-cost, proven practices and technologies.

  7. Ultrafast photodetection in an all-silicon chip enabled by two-photon absorption

    E-Print Network [OSTI]

    Bravo-Abad, Jorge

    In this letter we theoretically demonstrate that by dramatically enhancing two-photon absorption, all-silicon optical microresonators can act as efficient photodetectors for light at telecom wavelengths. We illustrate this ...

  8. Effects of (Multi)branching of Dipolar Chromophores on Photophysical Properties and Two-Photon Absorption

    E-Print Network [OSTI]

    Tretiak, Sergei

    the synthesis on knowledge- based materials. Among the many questions that are still debated, coherent coupling may be either enhanced or suppressed.44 Among the many NLO effects, two-photon absorption (TPA) has

  9. Water Vapour Absorption in the Clear Atmosphere of an exo-Neptune

    E-Print Network [OSTI]

    Fraine, Jonathan; Benneke, Björn; Knutson, Heather; Jordán, Andrés; Espinoza, Néstor; Madhusudhan, Nikku; Wilkins, Ashlee; Todorov, Kamen

    2014-01-01

    Transmission spectroscopy to date has detected atomic and molecular absorption in Jupiter-sized exoplanets, but intense efforts to measure molecular absorption in the atmospheres of smaller (Neptune-sized) planets during transits have revealed only featureless spectra. From this it was concluded that the majority of small, warm planets evolve to sustain high mean molecular weights, opaque clouds, or scattering hazes in their atmospheres, obscuring our ability to observe the composition of these atmospheres. Here we report observations of the transmission spectrum of HAT-P-11b (~4 Earth radii) from the optical to the infrared. We detected water vapour absorption at 1.4 micrometre wavelength. The amplitude of the water absorption (approximately 250 parts-per- million) indicates that the planetary atmosphere is predominantly clear down to ~1 mbar, and sufficiently hydrogen-rich to exhibit a large scale height. The spectrum is indicative of a planetary atmosphere with an upper limit of ~700 times the abundance of...

  10. Photovoltaic device with increased light absorption and method for its manufacture

    DOE Patents [OSTI]

    Glatfelter, Troy (Royal Oak, MI); Vogeli, Craig (New Baltimore, MI); Call, Jon (Royal Oak, MI); Hammond, Ginger (Imlay City, MI)

    1993-07-20

    A photovoltaic cell having a light-directing optical element integrally formed in an encapsulant layer thereof. The optical element redirects light to increase the internal absorption of light incident on the photovoltaic device.

  11. The Effect of Moisture Absorption on the Physical Properties of Polyurethane Shape Memory Polymer Foams 

    E-Print Network [OSTI]

    Yu, Ya-Jen

    2012-07-16

    The effect of moisture absorption on the glass transition temperature (Tg) and stress/strain behavior of network polyurethane shape memory polymer (SMP) foams has been investigated. With our ultimate goal of engineering polyurethane SMP foams...

  12. Electrospun Polyurethane Fibers for Absorption of Volatile Organic Compounds from Air

    E-Print Network [OSTI]

    Scholten, Elke

    Electrospun polyurethane fibers for removal of volatile organic compounds (VOC) from air with rapid VOC absorption and desorption have been developed. Polyurethanes based on 4,4-methylenebis(phenylisocyanate) (MDI) and ...

  13. Energy absorption of reticulated foams filled with shear-thickening silica suspensions

    E-Print Network [OSTI]

    Bettin, Giorgia

    2005-01-01

    The need for smarter and adaptive, energy absorption materials especially for human protection applications has fueled the interest in new and alternative energy absorbing composites. In this thesis a 'novel' energy absorbing ...

  14. Direct and quantitative broadband absorptance micro/nano spectroscopy using FTIR and bilayer cantilever probes

    E-Print Network [OSTI]

    Hsu, Wei-Chun

    2012-01-01

    Optical properties of micro/nano materials are important for many applications in biology, optoelectronics, and energy. In this thesis, a method is described to directly measure the quantitative absorptance spectra of ...

  15. The development of a solid-state laser-based sensor for absorption detection of OH 

    E-Print Network [OSTI]

    Ray, Gustavo Jose?

    2002-01-01

    measurements are taken for a hydrogen-air flame in a Hencken burner. The OH absorption profile is resolved in the (2,0) band of the A²[]? - X²[] electronic transition....

  16. Narrow-Band Absorption-Enhanced Quantum Dot/J-Aggregate Conjugates

    E-Print Network [OSTI]

    Walker, Brian J.

    We report narrow-band absorption enhancement of semiconductor nanocrystals via Förster resonance energy transfer from cyanine J-aggregates. These J-aggregated dyes associate electrostatically with short quantum-dot (QD) ...

  17. The development and application of a diode-laser-based ultraviolet absorption sensor for nitric oxide 

    E-Print Network [OSTI]

    Anderson, Thomas Nathan

    2004-09-30

    This thesis describes the development of a new type of sensor for nitric oxide (NO) that can be used in a variety of combustion diagnostics and control applications. The sensor utilizes the absorption of ultraviolet (UV) ...

  18. Cost reductions in absorption chillers. Final report, June 1984-May 1985

    SciTech Connect (OSTI)

    Leigh, R.W.

    1986-05-01

    Absorption chillers have great difficulty competing with the electric-driven compression alternative, due in part to modest operating efficiencies and largely to high first costs. This project is an assessment of the possibility of lowering the costs of absorption chillers dramatically by the use of low material intensity in the design of a new generation of these machines. Breakeven costs for absorption chillers, their heat exchangers and heat exchanger materials were established which will allow commercial success. Polymeric and metallic materials appropriate to particular components and which meet the cost goals were identified. A subset of these materials were tested and ordered by success in tolerating conditions and materials found in absorption chiller applications. Conceptual designs which indicate the practicality of the low material intensity approach were developed. The work reported here indicates that there is a high probability that this apporach will be successful.

  19. QUASARS PROBING QUASARS. VI. EXCESS H I ABSORPTION WITHIN ONE PROPER Mpc OF z ~ 2 QUASARS

    E-Print Network [OSTI]

    Prochaska, J. Xavier

    With close pairs of quasars at different redshifts, a background quasar sightline can be used to study a foreground quasar's environment in absorption. We use a sample of 650 projected quasar pairs to study the H I Ly? ...

  20. Revisiting the total ion yield x-ray absorption spectra of liquid water microjets

    E-Print Network [OSTI]

    Cappa, Chris D.

    2008-01-01

    the “free” –OH bond. The water molecule of interest is shownAbsorption Spectra of Liquid Water Microjets Christopher D.spectrum (XAS) of liquid water by Wilson et al. [J. Phys.

  1. Electronic structure of liquid water from polarization-dependent two-photon absorption spectroscopy

    E-Print Network [OSTI]

    Elles, Christopher G.; Rivera, Christopher A.; Zhang, Yuyuan; Pieniazek, Piotr A.; Bradforth, Stephen E.

    2009-02-26

    and connects the 2PA spectrum with previous one-photon absorption, photoelectron, and x-ray absorptionspectroscopy measurements of liquid water. Previously unresolved, overlapping transitions are assigned for the first time. Finally, the electronic character...

  2. Enhanced absorption of thin-film photovoltaic cells using an optical cavity

    E-Print Network [OSTI]

    Hsu, Wei-Chun

    We show via numerical simulations that the absorption and solar energy conversion efficiency of a thin-film photovoltaic (PV) cell can be significantly enhanced by embedding it into an optical cavity. A reflective ...

  3. Life Cycle cost Analysis of Waste Heat Operated Absorption Cooling Systems for Building HVAC Applications 

    E-Print Network [OSTI]

    Saravanan, R.; Murugavel, V.

    2010-01-01

    In this paper, life cycle cost analysis (LCCA) of waste heat operated vapour absorption air conditioning system (VARS) incorporated in a building cogeneration system is presented and discussed. The life cycle cost analysis (LCCA) based on present...

  4. First-Order Linear Differential Equations

    E-Print Network [OSTI]

    PRETEX (Halifax NS) #1 1054 1999 Mar 05 10:59:16

    2010-01-20

    Feb 16, 2007 ... (b) Determine the logistic model corresponding to the given data. (c) On the same set of axes, plot the solution curves obtained in (a) and (b).

  5. Noncommutative Galois Extension and Graded q-Differential Algebra

    E-Print Network [OSTI]

    Abramov, Viktor

    2015-01-01

    We show that a semi-commutative Galois extension of a unital associative algebra can be endowed with the structure of a graded q-differential algebra. We study the first and higher order noncommutative differential calculus of semi-commutative Galois extension induced by the graded q-differential algebra. As an example we consider the quaternions which can be viewed as the semi-commutative Galois extension of complex numbers.

  6. Sensor for detecting and differentiating chemical analytes

    DOE Patents [OSTI]

    Yi, Dechang (Metuchen, NJ); Senesac, Lawrence R. (Knoxville, TN); Thundat, Thomas G. (Knoxville, TN)

    2011-07-05

    A sensor for detecting and differentiating chemical analytes includes a microscale body having a first end and a second end and a surface between the ends for adsorbing a chemical analyte. The surface includes at least one conductive heating track for heating the chemical analyte and also a conductive response track, which is electrically isolated from the heating track, for producing a thermal response signal from the chemical analyte. The heating track is electrically connected with a voltage source and the response track is electrically connected with a signal recorder. The microscale body is restrained at the first end and the second end and is substantially isolated from its surroundings therebetween, thus having a bridge configuration.

  7. Case study of the 19 October 1989 polar-cap-absorption event using the imaging riometer for ionospheric studies. Master's thesis

    SciTech Connect (OSTI)

    Davis, T.C.

    1990-01-01

    A polar cap absorption (PCA) event, beginning on 19 October 1989, is examined using the Imaging Riometer for Ionospheric Studies (IRIS) developed at the Univ. of Maryland. IRIS is a 49-beam (7 x 7) phased-array 38.2 MHz radiowave imaging system and operating at Amundsen-Scott South Pole Station, Antarctica. After applying a low-pass (>10 minute) filter, we perform a cross-correlation between the central beam and the other beams in the array. From the cross-correlation analysis, we attempt to determine whether there is any delay of effects during event onset and early main phase (plateau) within the array. For most of the period studied, no delay was detected; i.e. features of each beam's absorption time series were essentially simultaneous. However, significant delays (approx. 2 minutes) occurred at the equatorward edge during a local absorption peak occurring just prior to magnetic local noon. The peak is coincident with short-term energetic particle flux enhancements detected by GOES-7. Two possible mechanisms are proposed: a local time variation of cutoff rigidities possibly associated with the relative position of the dayside cusp, and a short-term change in energetic particle rigidity spectrum.

  8. Measurements of the total and differential cross sections of Higgs boson production

    E-Print Network [OSTI]

    ATLAS Collaboration; The ATLAS collaboration

    2015-01-01

    We present measurements of the total and differential cross sections of Higgs boson production that were performed using 20.3 fb$^{-1}$ of $pp$ collisions produced by the Large Hadron Collider at a center-of-mass energy of $\\sqrt{s} = 8$ TeV and recorded by the ATLAS detector. Cross sections are obtained from measured $H \\to \\gamma\\gamma$ and $H \\to ZZ \\to 4 \\ell$ event yields, which are combined accounting for detector efficiencies, fiducial acceptances and branching fractions. Differential cross sections are reported as a function of Higgs boson transverse momentum, Higgs boson rapidity, number of jets in the event, and transverse momentum of the leading jet. The total production cross section is determined to be: $\\sigma_{pp \\to H} = 33.0 \\pm 5.3 \\, (\\text{stat}) \\pm 1.6 \\, (\\text{sys})$ pb. The measurements are then compared to state-of-the-art predictions.

  9. Vibrating Cantilever Transducer Incorporated in Dual Diaphragms Structure for Sensing Differential Pneumatic Pressure

    E-Print Network [OSTI]

    Cellatoglu, Akin; 10.5121/ijsc.2011.2409

    2012-01-01

    Pneumatic pressure cells with thin metallic spherical diaphragm of shallow spherical shell configuration linked with vibrating wire pickup or vibrating cantilever pickup were reported in the past. In order to enhance the sensitivity of the pressure cell this work considers dual diaphragm structure fitted with cantilever pickup. The design and development of the pressure cell with this dual diaphragm structure having cantilever pickup is presented here. The geometrical design is optimally made as to sense either mono pressure or differential pressure resources. The cantilevers of the two diaphragms are excited to produce vibrations and the frequencies of vibrations are determined by picking up signals from orthogonally arranged opto-coupler links. With the computed frequency a lookup table is referred to obtain the pressure acting on the concerned diaphragm. In the external circuits, the average pressure and the differential pressure acting on two diaphragms are computed. Furthermore transmitting circuits taki...

  10. Differential inhibition of organic cations by the renal tubule of the chicken: relationship to Tm

    SciTech Connect (OSTI)

    Springate, J.; Hasan, M.; Rennick, B.; Acara, M.

    1986-03-01

    The ability of organic cations to differentially inhibit the renal excretion of two prototypical organic cations, tetraethylammonium (TEA) and N/sup 1/-methylnicotinamide (NMN), was investigated using the Sperber technique in chickens. /sup 3/H-TEA and /sup 14/C-NMN were infused simultaneously into the renal portal circulation and their transport efficiencies (TE) determined to be 106 +/- 11% and 81 +/- 13% respectively. Quinine, unlabelled NMN or TEA, added in increasing amounts, produced differential inhibition of TEA, NMN, or cimetidine (infused in separate experiments). Data using other competing organic cations (guinidine, ranitidine, triethylcholine) indicated that TEA was never more susceptible to inhibition than NMN. These results suggest that the magnitude of T/sub m/ is directly related to susceptibility to inhibition and indirectly to inhibitory potency.

  11. Analysis of recent G experiments by a differential version of MOND theory

    E-Print Network [OSTI]

    Klein, Norbert

    2015-01-01

    The discrepancy between two recently reported experimental values of the gravitational constant G was analysed within a differential version of MOND theory. In contrast to the most commonly accepted interpretation of MOND theory, it is assumed that only the relative gravitational acceleration between a test mass and an array of source masses determines the magnitude of post Newtonian corrections at small magnitudes of acceleration. The analysis was applied to one of the most recent Cavendish-type gravitational force experiments, which showed a significant deviation of the measured gravitational constant from the current CODATA value. A remarkable agreement between the observed G discrepancy and MOND fits to galaxy rotation curves was revealed by a consistent extrapolation within the framework of this model. The differential approach suggests that gravity-induced alterations of the space-time-curvature may define the magnitude of corrections to Newton's law.

  12. An investigation of the cadmium absorption of resonance neutrons in cadmium covered indium foils 

    E-Print Network [OSTI]

    Powell, James Edward

    1963-01-01

    AN INVESTIGATION OF THE CADMIUM ABSORPTION OF RESONANCE NEUTRONS IN CADMIUM COVERED INDIUM FOILS A Thesis by JAMES EDWARD POWELL Submitted to the Graduate School of the Agricultural and Mechanical College of Texas in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE August 1963 Major Subject Nuclear Engineering AN INVESTIGATION OF THE CADMIUM ABSORPTION OF RESONANCE NEUTRONS IN CADMIUM COVERED INDIUM FOILS A Thesis by JAMES EDWARD POWELL Approved as to style...

  13. Relative radiant heat absorption characteristics of two types of mirror shields and a polished aluminum shield 

    E-Print Network [OSTI]

    Herron, Steven Douglas

    1973-01-01

    RELATIVE RADIANT HEAT ABSORPTION CHARACTERISTICS OF TWO TYPES OF MIRROR SHIELDS AND A POLISHED ALUMINUM SHIELD A Thesis by STEVEN DOUGLAS HERRON Submitted to the Graduate College of Texas A&M University in partial fulfillment... of the requirement for the degree of MASTER OF SCIENCE August 1973 Major Subject: Industrial Hygiene RELATIVE RADIANT HEAT ABSORPTION CHARACTERISTICS OF TWO TYPES OF MIRROR SHIELDS AND A POLISHED ALUMINUM SHIELD A Thesis by STEVEN DOUGLAS HERRON Approved...

  14. Differential Dynamic Microscopy to characterize Brownian motion and bacteria motility

    E-Print Network [OSTI]

    David Germain; Mathieu Leocmach; Thomas Gibaud

    2015-11-03

    We have developed a lab work module where we teach undergraduate students how to quantify the dynamics of a suspension of microscopic particles, measuring and analyzing the motion of those particles at the individual level or as a group. Differential Dynamic Microscopy (DDM) is a relatively recent technique that precisely does that and constitutes an alternative method to more classical techniques such as dynamics light scattering (DLS) or video particle tracking (VPT). DDM consists in imaging a particle dispersion with a standard light microscope and a camera. The image analysis requires the students to code and relies on digital Fourier transform to obtain the intermediate scattering function, an autocorrelation function that characterizes the dynamics of the dispersion. We first illustrate DDM on the textbook case of colloids where we measure the diffusion coefficient. Then we show that DDM is a pertinent tool to characterize biologic systems such as motile bacteria i.e.bacteria that can self propel, where we not only determine the diffusion coefficient but also the velocity and the fraction of motile bacteria. Finally, so that our paper can be used as a tutorial to the DDM technique, we have joined to this article movies of the colloidal and bacterial suspensions and the DDM algorithm in both Matlab and Python to analyze the movies.

  15. CONSTRAINING SOLAR FLARE DIFFERENTIAL EMISSION MEASURES WITH EVE AND RHESSI

    SciTech Connect (OSTI)

    Caspi, Amir [Laboratory for Atmospheric and Space Physics, University of Colorado, Boulder, CO 80303 (United States); McTiernan, James M. [Space Sciences Laboratory University of California, Berkeley, CA 94720 (United States); Warren, Harry P. [Space Science Division, Naval Research Laboratory, Washington, DC 20375 (United States)

    2014-06-20

    Deriving a well-constrained differential emission measure (DEM) distribution for solar flares has historically been difficult, primarily because no single instrument is sensitive to the full range of coronal temperatures observed in flares, from ?2 to ?50 MK. We present a new technique, combining extreme ultraviolet (EUV) spectra from the EUV Variability Experiment (EVE) onboard the Solar Dynamics Observatory with X-ray spectra from the Reuven Ramaty High Energy Solar Spectroscopic Imager (RHESSI), to derive, for the first time, a self-consistent, well-constrained DEM for jointly observed solar flares. EVE is sensitive to ?2-25 MK thermal plasma emission, and RHESSI to ?10 MK; together, the two instruments cover the full range of flare coronal plasma temperatures. We have validated the new technique on artificial test data, and apply it to two X-class flares from solar cycle 24 to determine the flare DEM and its temporal evolution; the constraints on the thermal emission derived from the EVE data also constrain the low energy cutoff of the non-thermal electrons, a crucial parameter for flare energetics. The DEM analysis can also be used to predict the soft X-ray flux in the poorly observed ?0.4-5 nm range, with important applications for geospace science.

  16. Detection of ocean glint and ozone absorption using LCROSS Earth observations

    SciTech Connect (OSTI)

    Robinson, Tyler D.; Ennico, Kimberly; Meadows, Victoria S.; Sparks, William; Schwieterman, Edward W.; Bussey, D. Ben J.; Breiner, Jonathan

    2014-06-01

    The Lunar CRater Observation and Sensing Satellite (LCROSS) observed the distant Earth on three occasions in 2009. These data span a range of phase angles, including a rare crescent phase view. For each epoch, the satellite acquired near-infrared and mid-infrared full-disk images, and partial-disk spectra at 0.26-0.65 ?m (?/?? ? 500) and 1.17-2.48 ?m (?/?? ? 50). Spectra show strong absorption features due to water vapor and ozone, which is a biosignature gas. We perform a significant recalibration of the UV-visible spectra and provide the first comparison of high-resolution visible Earth spectra to the NASA Astrobiology Institute's Virtual Planetary Laboratory three-dimensional spectral Earth model. We find good agreement with the observations, reproducing the absolute brightness and dynamic range at all wavelengths for all observation epochs, thus validating the model to within the ?10% data calibration uncertainty. Data-model comparisons reveal a strong ocean glint signature in the crescent phase data set, which is well matched by our model predictions throughout the observed wavelength range. This provides the first observational test of a technique that could be used to determine exoplanet habitability from disk-integrated observations at visible and near-infrared wavelengths, where the glint signal is strongest. We examine the detection of the ozone 255 nm Hartley and 400-700 nm Chappuis bands. While the Hartley band is the strongest ozone feature in Earth's spectrum, false positives for its detection could exist. Finally, we discuss the implications of these findings for future exoplanet characterization missions.

  17. Total Absorption Gamma-ray Spectrometer (TAGS) Intensity Distributions from INL's Gamma-Ray Spectrometry Center

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Greenwood, R. E.

    A 252Cf fission-product source and the INL on-line isotope separator were used to supply isotope-separated fission-product nuclides to a total absorption -ray spectrometer. This spectrometer consisted of a large (25.4-cm diameter x 30.5-cm long) NaI(Tl) detector with a 20.3-cm deep axial well in which is placed a 300-mm2 x 1.0-mm Si detector. The spectra from the NaI(Tl) detector are collected both in the singles mode and in coincidence with the B-events detected in the Si detector. Ideally, this detector would sum all the energy of the B- rays in each cascade following the population of daughter level by B- decay, so that the event could be directly associated with a particular daughter level. However, there are losses of energy from attenuation of the rays before they reach the detector, transmission of rays through the detector, escape of secondary photons from Compton scattering, escape of rays through the detector well, internal conversion, etc., and the measured spectra are thus more complicated than the ideal case and the analysis is more complex. Analysis methods have been developed to simulate all of these processes and thus provide a direct measure of the B- intensity distribution as a function of the excitation energy in the daughter nucleus. These data yield more accurate information on the B- distribution than conventional decay-scheme studies for complex decay schemes with large decay energies, because in the latter there are generally many unobserved and observed but unplaced rays. The TAGS data have been analyzed and published [R. E. Greenwood et al., Nucl Instr. and metho. A390(1997)] for 40 fission product-nuclides to determine the B- intensity distributions. [Copied from the TAGS page at http://www.inl.gov/gammaray/spectrometry/tags.shtml]. Those values are listed on this page for quick reference.

  18. Design, construction, and testing of the direct absorption receiver panel research experiment

    SciTech Connect (OSTI)

    Chavez, J.M.; Rush, E.E.; Matthews, C.W.; Stomp, J.M.; Imboden, J.; Dunkin, S.

    1990-01-01

    A panel research experiment (PRE) was designed, built, and tested as a scaled-down model of a direct absorption receiver (DAR). The PRE is a 3-MW{sub t}DAR experiment that will allow flow testing with molten nitrate salt and provide a test bed for DAR testing with actual solar heating. In a solar central receiver system DAR, the heat absorbing fluid (a blackened molten nitrate salt) flows in a thin film down a vertical panel (rather than through tubes as in conventional receiver designs) and absorbs the concentrated solar flux directly. The ability of the flowing salt film to absorb flux directly. The ability of the flowing salt film to absorb the incident solar flux depends on the panel design, hydraulic and thermal fluid flow characteristics, and fluid blackener properties. Testing of the PRE is being conducted to demonstrate the engineering feasibility of the DAR concept. The DAR concept is being investigated because it offers numerous potential performance and economic advantages for production of electricity when compared to other solar receiver designs. The PRE utilized a 1-m wide by 6-m long absorber panel. The salt flow tests are being used to investigate component performance, panel deformations, and fluid stability. Salt flow testing has demonstrated that all the DAR components work as designed and that there are fluid stability issues that need to be addressed. Future solar testing will include steady-state and transient experiments, thermal loss measurements, responses to severe flux and temperature gradients and determination of peak flux capability, and optimized operation. In this paper, we describe the design, construction, and some preliminary flow test results of the Panel Research Experiment. 11 refs., 8 figs., 2 tabs.

  19. Software for Numerical Methods for Partial Differential Equations

    E-Print Network [OSTI]

    Software for Numerical Methods for Partial Differential Equations. This software was developed for and by the students in CS 615, Numerical Methods for Partial

  20. Differential analysis of high-throughput quantitative genetic interaction data

    E-Print Network [OSTI]

    Bean, Gordon J; Ideker, Trey

    2012-01-01

    DNA damage response (DDR)). Other biological networks, suchespecially in context of the DDR. Thus, differentialThese gene pairs indicate DDR- relevant interactions that

  1. Exterior Differential Systems for Yang-Mills Theories

    E-Print Network [OSTI]

    Frank B. Estabrook

    2008-12-05

    Exterior differential systems are given, and their Cartan characters calculated, for Maxwell and SU(2)-Yang-Mills equations in dimensions from three to six.

  2. A Nonmonotone Approach without Differentiability Test for Gradient ...

    E-Print Network [OSTI]

    Elias S. Helou

    2015-03-18

    Mar 18, 2015 ... A Nonmonotone Approach without Differentiability Test for Gradient Sampling Methods. Elias S. Helou(elias ***at*** icmc.usp.br) Sandra A.

  3. Heat diode effect and negative differential thermal conductance...

    Office of Scientific and Technical Information (OSTI)

    Heat diode effect and negative differential thermal conductance across nanoscale metal-dielectric interfaces Citation Details In-Document Search Title: Heat diode effect and...

  4. MATH 262 Linear Algebra And Differential Equations Spring 2014 ...

    E-Print Network [OSTI]

    2014-01-13

    Instructor: Peijun Li, MATH 440, (765) 494-0846, lipeijun@math.purdue.edu ... Textbook: Differential Equations and Linear Algebra by Stephen Goode and Scott

  5. The polarization dependence of ?? absorption—implications for ?-ray bursts and blazars

    SciTech Connect (OSTI)

    Böttcher, M.

    2014-11-01

    This paper presents an analysis of the dependence of the opacity for high-energy ?-rays to ?? absorption by low-energy photons on the polarization of the ?-ray and target photons. This process has so far only been considered using the polarization-averaged ?? absorption cross section. It is demonstrated that in the case of polarized ?-ray emission, subject to source-intrinsic ?? absorption by polarized target photons, this may lead to a slight overestimation of the ?? opacity by up to ?10% in the case of a perfectly ordered magnetic field. Thus, for realistic astrophysical scenarios with partially ordered magnetic fields, the use of the polarization-averaged ?? cross section is justified for practical purposes, such as estimates of minimum Doppler factors inferred for ?-ray bursts and blazars, based on ?? transparency arguments; this paper quantifies the small error incurred by the unpolarized-radiation approximation. Furthermore, it is shown that polarization-dependent ?? absorption of initially polarized ?-rays can lead to a slight increase in the polarization beyond the spectral break caused by ?? absorption. This amount is distinctly different from the change in polarization expected if the same spectral break were produced by a break in the underlying electron distribution. This may serve as a diagnostic of whether ?? absorption is relevant in sources such as ?-ray bursts and blazars where the ?-ray emission may be intrinsically highly polarized.

  6. Determination of the Exciton Binding Energy in CdSe Quantum Dots

    SciTech Connect (OSTI)

    Meulenberg, R; Lee, J; Wolcott, A; Zhang, J; Terminello, L; van Buuren, T

    2009-10-27

    The exciton binding energy (EBE) in CdSe quantum dots (QDs) has been determined using x-ray spectroscopy. Using x-ray absorption and photoemission spectroscopy, the conduction band (CB) and valence band (VB) edge shifts as a function of particle size have been determined and combined to obtain the true band gap of the QDs (i.e. without and exciton). These values can be compared to the excitonic gap obtained using optical spectroscopy to determine the EBE. The experimental EBE results are compared with theoretical calculations on the EBE and show excellent agreement.

  7. Two Different Approaches to Nonzero-Sum Stochastic Differential Games

    SciTech Connect (OSTI)

    Rainer, Catherine [Departement de Mathematiques, Universite de Bretagne Occidentale, 6 avenue Victor-le-Gorgeu - CS 93837 (France)], E-mail: Catherine.Rainer@univ-brest.fr

    2007-06-15

    We make the link between two approaches to Nash equilibria for nonzero-sum stochastic differential games: the first one using backward stochastic differential equations and the second one using strategies with delay. We prove that, when both exist, the two notions of Nash equilibria coincide.

  8. Student (Mis)application of Partial Differentiation to Material Properties

    E-Print Network [OSTI]

    Maine, University of

    Student (Mis)application of Partial Differentiation to Material Properties 1 19 1 Brandon R. Bucy. Keywords: Thermal physics, mathematics, partial differentiation, material properties, thermal expansivity derivatives of the isothermal compressibility and the thermal expansivity of a substance. Both these material

  9. ARTICULATORY SYNTHESIS: NUMERICAL SOLUTION OF A HYPERBOLIC DIFFERENTIAL EQUATION

    E-Print Network [OSTI]

    into the context of finite-difference approximations to a differential equation describing acoustic wave-that of solving the differ- ential equation describing acoustic (small amplitude), one-dimensional propagationARTICULATORY SYNTHESIS: NUMERICAL SOLUTION OF A HYPERBOLIC DIFFERENTIAL EQUATION Richard S. Mc

  10. From Petri Nets to Differential Equations -an Integrative Approach

    E-Print Network [OSTI]

    Gilbert, David

    From Petri Nets to Differential Equations - an Integrative Approach for Biochemical Network report on the results of an investigation into the inte- gration of Petri nets and ordinary differential equations (ODEs) for the modelling and analysis of biochemical networks, and the application of our approach

  11. FOURTH ORDER PARTIAL DIFFERENTIAL EQUATIONS ON GENERAL GEOMETRIES

    E-Print Network [OSTI]

    FOURTH ORDER PARTIAL DIFFERENTIAL EQUATIONS ON GENERAL GEOMETRIES By John B. Greer Andrea L­0436 Phone: 612/624-6066 Fax: 612/626-7370 URL: http://www.ima.umn.edu #12;Fourth Order Partial Differential (Bertalm´io, Cheng, Osher, and Sapiro 2001) to fourth order PDEs including the Cahn- Hilliard equation

  12. Fractional embedding of differential operators and Lagrangian systems

    E-Print Network [OSTI]

    Fractional embedding of differential operators and Lagrangian systems Jacky CRESSON Institut des/30 #12;FRACTIONAL EMBEDDING OF DIFFERENTIAL OPERATORS AND LAGRANGIAN SYSTEMS by Jacky CRESSON Abstract. -- This paper is a contribution to the general program of embedding theories of dynamical systems. Following our

  13. Differentiation factors between free and premium among different cloud computing

    E-Print Network [OSTI]

    Vellekoop, Michel

    Differentiation factors between free and premium among different cloud computing services Author for consumers among various cloud computing services. The design is a comparative case study by which Spotify, Freemium, Differentiation, Cloud computing services Permission to make digital or hard copies of all

  14. Achieving Differential Privacy of Data Disclosure in the Smart Grid

    E-Print Network [OSTI]

    Li, Xiang-Yang

    Achieving Differential Privacy of Data Disclosure in the Smart Grid Jing Zhao Taeho Jung Yu Wang-- The smart grid introduces new privacy implications to individuals and their family due to the fine of the proposed method over existing BLH methods. Index Terms--Smart Grid, Smart Meter, Privacy, Differential

  15. Geometric Integration: Numerical Solution of Differential Equations on Manifolds

    E-Print Network [OSTI]

    Scheichl, Robert

    and the solar system. Conserved quantities of a Hamiltonian system, such as energy, linear and angular momentumGeometric Integration: Numerical Solution of Differential Equations on Manifolds C.J. Budd 1 & A riches. Psalms 104:24 Since their introduction by Sir Isaac Newton, differential equations have played

  16. The Optimal Mechanism in Differential Privacy: Multidimensional Setting

    E-Print Network [OSTI]

    Viswanath, Pramod

    1 The Optimal Mechanism in Differential Privacy: Multidimensional Setting Quan Geng, and Pramod Email: {geng5, pramodv}@illinois.edu Abstract We derive the optimal -differentially private mechanism multidimensional staircase-shaped probability density function. Compared with the Laplacian mechanism, we show

  17. Adaptive Calculation of Variable Coefficients Elliptic Differential Equations via Wavelets

    E-Print Network [OSTI]

    Averbuch, Amir

    Adaptive Calculation of Variable Coefficients Elliptic Differential Equations via Wavelets Amir in numerical solution of differential and integral equations. Classical methods for discretization lead-based multiplication is af- fected by different input parameters for the algorithm. We integrated a sparse

  18. CELL TYPES, DIFFERENTIAL CELL COUNTS, AND BLOOD CELL MEASUREMENTS OF

    E-Print Network [OSTI]

    examined under oil immersion at 800 and 1200 power. Cells were measured at 800 power. Cell classificationCELL TYPES, DIFFERENTIAL CELL COUNTS, AND BLOOD CELL MEASUREMENTS OF A PORTUGUESE SHARK describe the cell types, differential cell counts, and measurements of both the erythrocytes and leukocytes

  19. Automatic Search for Differential Trails in ARX Ciphers (extended version)

    E-Print Network [OSTI]

    International Association for Cryptologic Research (IACR)

    Automatic Search for Differential Trails in ARX Ciphers (extended version) Alex Biryukov {Alex.Biryukov,Vesselin.Velichkov}@uni.lu Abstract. We propose a tool 1 for automatic search. Keywords: symmetric-key, differential trail, tools for cryptanalysis, automatic search, ARX, TEA, XTEA

  20. GRworkbench: A Computational System Based on Differential Geometry

    E-Print Network [OSTI]

    Susan M Scott; Benjamin J K Evans; Antony C Searle

    2001-11-19

    We have developed a new tool for numerical work in General Relativity: GRworkbench. While past tools have been ad hoc, GRworkbench closely follows the framework of Differential Geometry to provide a robust and general way of computing on analytically defined space-times. We discuss the relationship between Differential Geometry and C++ classes in GRworkbench, and demonstrate their utility.

  1. Differentiation in sex investment by clones and populations of Daphnia

    E-Print Network [OSTI]

    Cáceres, Carla E.

    REPORT Differentiation in sex investment by clones and populations of Daphnia Alan J. Tessier1, conditions that favour dormancy are predicted to select for more sex, which should increase clonal diversity-round, and quantified the extent to which they have differentiated in their investment in dormancy and sex

  2. Stochastic differential equations and numerical simulation for pedestrians

    SciTech Connect (OSTI)

    Garrison, J.C.

    1993-07-27

    The mathematical foundation of the Ito interpretation of stochastic ordinary and partial differential equations is briefly explained. This provides the basis for a review of simple difference approximations to stochastic differential equations. An example arising in the theory of optical switching is discussed.

  3. Jet spaces of varieties over differential and difference fields

    E-Print Network [OSTI]

    Ziegler, Martin

    Jet spaces of varieties over differential and difference fields Anand Pillay University of Illinois¨at zu Berlin December 5, 2001 Abstract We give elementary proofs, using suitable jet spaces, of some old case, using differential and difference analogues of jet spaces. The main result, stated in model

  4. Jet spaces of varieties over differential and difference fields

    E-Print Network [OSTI]

    Ziegler, Martin

    Jet spaces of varieties over differential and difference fields Anand Pillay \\Lambda University Universit¨at zu Berlin December 5, 2001 Abstract We give elementary proofs, using suitable jet spaces in the characteristic zero case, using differential and difference analogues of jet spaces. The main result, stated

  5. MATH 225 Fall 2011 Differential Equations Course Syllabus

    E-Print Network [OSTI]

    MATH 225 Fall 2011 Differential Equations Course Syllabus Instructor Info Instructor: Phone: Office: Email: Office Hours: Section Website: Course Website: http://mcs.mines.edu/Courses/math225/ Grading sciences. Prerequisites: MATH213 or MATH223 Text Differential Equations with Boundary-Value Problems, 7th

  6. Proceedings Article Differential Pricing with inequity aversion in social networks

    E-Print Network [OSTI]

    Shamir, Ron

    Proceedings Article Differential Pricing with inequity aversion in social networks Noga Alon, Tel the algorithmic problem of maximizing revenue in a network using differential pricing, where the prices offered pricing can be computed efficiently, even for arbitrary revenue functions. In contrast, we show

  7. Force-controlled absorption in a fully-nonlinear numerical wave tank

    SciTech Connect (OSTI)

    Spinneken, Johannes Christou, Marios; Swan, Chris

    2014-09-01

    An active control methodology for the absorption of water waves in a numerical wave tank is introduced. This methodology is based upon a force-feedback technique which has previously been shown to be very effective in physical wave tanks. Unlike other methods, an a-priori knowledge of the wave conditions in the tank is not required; the absorption controller being designed to automatically respond to a wide range of wave conditions. In comparison to numerical sponge layers, effective wave absorption is achieved on the boundary, thereby minimising the spatial extent of the numerical wave tank. In contrast to the imposition of radiation conditions, the scheme is inherently capable of absorbing irregular waves. Most importantly, simultaneous generation and absorption can be achieved. This is an important advance when considering inclusion of reflective bodies within the numerical wave tank. In designing the absorption controller, an infinite impulse response filter is adopted, thereby eliminating the problem of non-causality in the controller optimisation. Two alternative controllers are considered, both implemented in a fully-nonlinear wave tank based on a multiple-flux boundary element scheme. To simplify the problem under consideration, the present analysis is limited to water waves propagating in a two-dimensional domain. The paper presents an extensive numerical validation which demonstrates the success of the method for a wide range of wave conditions including regular, focused and random waves. The numerical investigation also highlights some of the limitations of the method, particularly in simultaneously generating and absorbing large amplitude or highly-nonlinear waves. The findings of the present numerical study are directly applicable to related fields where optimum absorption is sought; these include physical wavemaking, wave power absorption and a wide range of numerical wave tank schemes.

  8. Self-correcting differential global positioning system 

    E-Print Network [OSTI]

    Schreiber, Randal Alfred

    1993-01-01

    The Global Positioning System (GPS) is a satellite based system that can accurately determine a user's position in terms of latitude, longitude, and height or in terms of X, Y, and Z. The X, Y, and Z coordinate system is an Earth Centered Earth...

  9. Nitrogen control of chloroplast differentiation. Final report

    SciTech Connect (OSTI)

    Schmidt, G.W.

    1998-05-01

    This project was directed toward understanding at the physiological, biochemical and molecular levels of how photosynthetic organisms adapt to long-term nitrogen-deficiency conditions is quite incomplete even though limitation of this nutrient is the most commonly restricts plant growth and development. For our work on this problem, the unicellular green alga, Chlamydomonas reinhardtii, was grown in continuous cultures in which steady-state levels of nitrogen can be precisely controlled. N-limited cells exhibit the classical symptoms of deficiency of this nutrient, chlorosis and slow growth rates, and respond to nitrogen provision by rapid greening and chloroplast differentiation. We have addressed three aspects of this problem: (1) the regulation of pigment synthesis; (2) control of expression of nuclear genes encoding photosynthetic proteins; (3) changes in metabolic and electron transport pathways that enable sustained CO{sub 2} fixation even though they cannot be readily converted into amino and nucleic acids. For the last, principle components are: (a) enhanced mitochondrial respiratory activity intimately associated with photosynthates, and (b) the occurrence in thylakoids of a supplemental electron transport pathway that facilitates reduction of the plastoquinone pool. Together, these distinguishing features of N-limited cells are likely to enable cell survival, especially under conditions of high irradiance stress.

  10. Optical hydrogen absorption consistent with a thin bow shock leading the hot Jupiter HD 189733b

    E-Print Network [OSTI]

    Cauley, P Wilson; Jensen, Adam G; Barman, Travis; Endl, Michael; Cochran, William D

    2015-01-01

    Bow shocks are ubiquitous astrophysical phenomena resulting from the supersonic passage of an object through a gas. Recently, pre-transit absorption in UV metal transitions of the hot Jupiter exoplanets HD 189733b and WASP12-b have been interpreted as being caused by material compressed in a planetary bow shock. Here we present a robust detection of a time-resolved pre-transit, as well as in-transit, absorption signature around the hot Jupiter exoplanet HD 189733b using high spectral resolution observations of several hydrogen Balmer lines. The line shape of the pre-transit feature and the shape of the time series absorption provide the strongest constraints on the morphology and physical characteristics of extended structures around an exoplanet. The in-transit measurements confirm the previous exospheric H-alpha detection although the absorption depth measured here is ~50% lower. The pre-transit absorption feature occurs 125 minutes before the predicted optical transit, a projected linear distance from the ...

  11. Four-Hair Relations for Differentially Rotating Neutron Stars in the Weak-Field Limit

    E-Print Network [OSTI]

    Bretz, Joseph; Yunes, Nicolas

    2015-01-01

    The opportunity to study physics at supra-nuclear densities through X-ray observations of neutron stars has led to in-depth investigations of certain approximately universal relations that can remove degeneracies in pulse profile models. One such set of relations determines all of the multipole moments of a neutron star just from the first three (the mass monopole, the current dipole and the mass quadrupole moment) approximately independently of the equation of state. These three-hair relations were found to hold in neutron stars that rotate rigidly, as is the case in old pulsars, but neutron stars can also rotate differentially, as is the case for proto-neutron stars and hypermassive transient remnants of binary mergers. We here extend the three-hair relations to differentially rotating stars for the first time with a generic rotation law using two approximations: a weak-field scheme (an expansion in powers of the neutron star compactness) and a perturbative differential rotation scheme (an expansion about r...

  12. Near-UV absorption in very cool DA white dwarfs

    SciTech Connect (OSTI)

    Saumon, D.; Holberg, J. B.; Kowalski, P. M. E-mail: holberg@argus.lpl.arizona.edu

    2014-07-20

    The atmospheres of very cool, hydrogen-rich white dwarfs (WDs) (T{sub eff} < 6000 K) are challenging to model because of the increased complexity of the equation of state, chemical equilibrium, and opacity sources in a low-temperature, weakly ionized dense gas. In particular, many models that assume relatively simple models for the broadening of atomic levels and mostly ideal gas physics overestimate the flux in the blue part of their spectra. A solution to this problem that has met with some success is that additional opacity at short wavelengths comes for the extreme broadening of the Lyman ? line of atomic H by collisions primarily with H{sub 2}. For the purpose of validating this model more rigorously, we acquired Hubble Space Telescope STIS spectra of eight very cool WDs (five DA and three DC stars). Combined with their known parallaxes, BVRIJHK, and Spitzer IRAC photometry, we analyze their entire spectral energy distribution (from 0.24 to 9.3 ?m) with a large grid of model atmospheres and synthetic spectra. We find that the red wing of the Lyman ? line reproduces the rapidly decreasing near-UV flux of these very cool stars very well. We determine better constrained values of T{sub eff} and gravity as well as upper limits to the helium abundance in their atmospheres.

  13. Composition of the nuclear periphery from antiproton absorption

    E-Print Network [OSTI]

    P. Lubinski; J. Jastrzebski; A. Trzcinska; W. Kurcewicz; F. J. Hartmann; W. Schmid; T. von Egidy; R. Smolanczuk; S. Wycech

    1998-08-25

    Thirteen targets with mass numbers from 58 to 238 were irradiated with the antiproton beam from the Low Energy Antiproton Ring facility at CERN leading to the formation of antiprotonic atoms of these heavy elements. The antiproton capture at the end of an atomic cascade results in the production of more or less excited residual nuclei. The targets were selected with the criterion that both reaction products with one nucleon less than the proton and neutron number of the target be radioactive. The yield of these radioactive products after stopped-antiproton annihilation was determined using gamma-ray spectroscopy techniques. This yield is related to the proton and neutron density in the target nucleus at a radial distance corresponding to the antiproton annihilation site. The experimental data clearly indicate the existence of a neutron-rich nuclear periphery, a "neutron halo", strongly correlated with the target neutron separation energy Bn and observed for targets with Bn energies, a proton-rich nuclear periphery was observed. Most of the experimental data are in reasonable agreement with calculations based on current antiproton-nucleus and pion-nucleus interaction potentials and on nuclear densities deduced with the help of the Hartree-Fock-Bogoliubov approach. This approach was, however, unable to account for the 106Cd and 144Sm results.

  14. Deciphering Ni sequestration in soil ferromanganese nodules by combining x-ray fluorescence, absorption and diffraction at micrometer scales of resolution

    SciTech Connect (OSTI)

    Manceau, Alain; Tamura, Nobumichi; Marcus, Matthew A.; MacDowell, Alastair A.; Celestre, Richard S.; Sublett, Robert E.; Sposito, Garrison; Padmore, Howard A.

    2002-11-06

    X-ray microprobes are among the most important new analytical techniques to emerge from third generation synchrotron facilities. Here we show how X-ray fluorescence, diffraction, and absorption can be used in parallel to determine the structural form of trace elements in heterogeneous matrices at the micrometer-scale of resolution. Scanning X-ray microfluorescence (microSXRF) and microdiffraction (microSXRD) first are used to identify the host solid phase by mapping the distributions of elements and solid species, respectively. Micro-extended X-ray absorption fine structure (microEXAFS) spectroscopy is then used to determine the mechanism of trace element binding by the host phase at the molecular scale. To illustrate the complementary application of these three techniques, we studied how nickel is sequestered in soil ferromanganese nodules, an overwhelmingly complex natural matrix consisting of submicrometer to nanometer sized particles with varying structures and chemical composition s. We show that nickel substitutes for Mn3+ in the manganese layer of the MnO2-Al(OH)3 mixed-layer oxide lithiophorite. The affinity of Ni for lithiophorite was characteristic of micromodules sampled from soils across the U.S.A. and Europe. Since many natural and synthetic materials are heterogeneous at nanometer to micrometer scales, the synergistic use of microSXRF, microSXRD and microEXAFS is expected to have broad applications to earth and materials science.

  15. Ascher, U.M. & Petzold, L.R., 1998. Computer Methods for Ordinary Differential Equations and Differential-Algebraic Equations, SIAM, Philadelphia.

    E-Print Network [OSTI]

    Hanyk, Ladislav

    and Differential-Algebraic Equations, SIAM, Philadelphia. Backus, G.E., 1967. Converting vector and tensor

  16. Ascher, U.M. & Petzold, L.R., 1998. Computer Methods for Ordinary Differential Equations and DifferentialAlgebraic Equations, SIAM, Philadelphia.

    E-Print Network [OSTI]

    Hanyk, Ladislav

    and Differential­Algebraic Equations, SIAM, Philadelphia. Backus, G.E., 1967. Converting vector and tensor

  17. Reversible differentiation of myofibroblasts by MyoD

    SciTech Connect (OSTI)

    Hecker, Louise; Jagirdar, Rajesh; Jin, Toni; Thannickal, Victor J., E-mail: vjthan@uab.edu

    2011-08-01

    Myofibroblasts participate in tissue repair processes in diverse mammalian organ systems. The deactivation of myofibroblasts is critical for termination of the reparative response and restoration of tissue structure and function. The current paradigm on normal tissue repair is the apoptotic clearance of terminally differentiated myofibroblasts; while, the accumulation of activated myofibroblasts is associated with progressive human fibrotic disorders. The capacity of myofibroblasts to undergo de-differentiation as a potential mechanism for myofibroblast deactivation has not been examined. In this report, we have uncovered a role for MyoD in the induction of myofibroblast differentiation by transforming growth factor-{beta}1 (TGF-{beta}1). Myofibroblasts demonstrate the capacity for de-differentiation and proliferation by modulation of endogenous levels of MyoD. We propose a model of reciprocal signaling between TGF-{beta}1/ALK5/MyoD and mitogen(s)/ERK-MAPK/CDKs that regulate myofibroblast differentiation and de-differentiation, respectively. Our studies provide the first evidence for MyoD in controlling myofibroblast activation and deactivation. Restricted capacity for de-differentiation of myofibroblasts may underlie the progressive nature of recalcitrant human fibrotic disorders.

  18. LiCl Dehumidifier LiBr absorption chiller hybrid air conditioning system with energy recovery

    DOE Patents [OSTI]

    Ko, Suk M. (Huntsville, AL)

    1980-01-01

    This invention relates to a hybrid air conditioning system that combines a solar powered LiCl dehumidifier with a LiBr absorption chiller. The desiccant dehumidifier removes the latent load by absorbing moisture from the air, and the sensible load is removed by the absorption chiller. The desiccant dehumidifier is coupled to a regenerator and the desiccant in the regenerator is heated by solar heated hot water to drive the moisture therefrom before being fed back to the dehumidifier. The heat of vaporization expended in the desiccant regenerator is recovered and used to partially preheat the driving fluid of the absorption chiller, thus substantially improving the overall COP of the hybrid system.

  19. Water Absorption from Gas Very Near the Massive Protostar AFGL 2136 IRS 1

    E-Print Network [OSTI]

    Indriolo, Nick; Seifahrt, A; Richter, M J

    2013-01-01

    We present ground-based observations of the nu_1 and nu_3 fundamental bands of H2O toward the massive protostar AFGL 2136 IRS 1, identifying absorption features due to 47 different ro-vibrational transitions between 2.468 micron and 2.561 micron. Analysis of these features indicates the absorption arises in warm (T=506+-25 K), very dense (n(H2)>5*10^9 cm^-3) gas, suggesting an origin close to the central protostar. The total column density of warm water is estimated to be N(H2O)=(1.02+-0.02)*10^19 cm^-2, giving a relative abundance of N(H2O)/N(H2)~10^-4. Our study represents the first extensive use of water vapor absorption lines in the near infrared, and demonstrates the utility of such observations in deriving physical parameters.

  20. Effective Absorption Enhancement in Small Molecule Organic Solar Cells by Employing Trapezoid Gratings

    E-Print Network [OSTI]

    Chun-Ping, Xiang; Yu, Jin; Bin-Zong, Xu; Wei-Min, Wang; Xin, Wei; Guo-Feng, Song; Yun, Xu

    2013-01-01

    We demonstrate the optical absorption has been enhanced in the small molecule organic solar cells by employing trapezoid grating structure. The enhanced absorption is mainly attributed to both waveguide modes and surface plasmon modes, which has been simulated by using finite-difference time-domain method. The simulated results show that the surface plasmon along the semitransparent metallic Ag anode is excited by introducing the periodical trapezoid gratings, which induce high intensity field increment in the donor layer. Meanwhile, the waveguide modes result a high intensity field in acceptor layer. The increment of field improves the absorption of organic solar cells, significantly, which has been demonstrated by simulating the electrical properties. The simulated results exhibiting 31 % increment of the short-circuit current has been achieved in the optimized device, which is supported by the experimental measurement. The power conversion efficiency of the grating sample obtained in experiment exhibits an...

  1. On the dynamic and static manifestation of molecular absorption in thin films probed by a microcantilever

    SciTech Connect (OSTI)

    Finot, Eric; Fabre, Arnaud; Passian, Ali; Thundat, Thomas

    2014-03-01

    Mechanical resonators shaped like microcantilevers have been demonstrated as a platform for very sensitive detection of chemical and biological analytes. However, its use as an analytical tool will require fundamental understanding of the molecular absorption-induced effects in the static and dynamic sensor response. The effect of absorption-induced surface stress on the microcantilever response is here investigated using palladium hydride formation. It is shown that the resonance and deformation states of the cantilever monitored simultaneously exhibit excellent correlation with the phase of the hydride formation. However, the associated frequency shifts and quasistatic bending are observed to be independent during solid solution phase. Importantly, absorption-induced changes in the elastic parameters of the palladium film are found to play a dominant role in the static and dynamic response. The presented results help in discerning the parameters that control the cantilever response as well as the relationships between these parameters.

  2. Universality of high-energy absorption cross sections for black holes

    SciTech Connect (OSTI)

    Decanini, Yves [Equipe Physique Theorique, SPE, UMR 6134 du CNRS et de l'Universite de Corse, Universite de Corse, Faculte des Sciences, B.P. 52, F-20250 Corte (France); Esposito-Farese, Gilles [GReCO, Institut d'Astrophysique de Paris, UMR 7095 du CNRS et de l'Universite Pierre et Marie Curie-Paris 6, 98bis boulevard Arago, F-75014 Paris (France); Folacci, Antoine [Equipe Physique Theorique, SPE, UMR 6134 du CNRS et de l'Universite de Corse, Universite de Corse, Faculte des Sciences, B.P. 52, F-20250 Corte (France); Centre de Physique Theorique, UMR 6207 du CNRS et des Universites Aix-Marseille 1 et 2 et de l'Universite du Sud Toulon-Var, CNRS-Luminy Case 907, F-13288 Marseille (France)

    2011-02-15

    We consider the absorption problem for a massless scalar field propagating in static and spherically symmetric black holes of arbitrary dimension endowed with a photon sphere. For this wide class of black holes, we show that the fluctuations of the high-energy absorption cross section are totally and very simply described from the properties (dispersion relation and damping) of the waves trapped near the photon sphere and therefore, in the eikonal regime, from the characteristics (orbital period and Lyapunov exponent) of the null unstable geodesics lying on the photon sphere. This is achieved by using Regge pole techniques. They permit us to make an elegant and powerful resummation of the absorption cross section and to extract then all the physical information encoded in the sum over the partial wave contributions. Our analysis induces moreover some consequences concerning Hawking radiation which we briefly report.

  3. X-ray absorption study of the electronic structure of Mn-doped amorphous Si

    SciTech Connect (OSTI)

    Arenholz, Elke; Zeng, Li; Huegel, A.; Helgren, E.; Hellman, F.; Piamonteze, C.; Arenholz, E.

    2008-03-08

    The electronic structure of Mn in amorphous Si (a-Mn{sub x}Si{sub 1?x}) is studied by X-ray absorption spectroscopy at the Mn L{sub 3,2} edges for x = 0.005-0.18. Except the x = 0.005 sample, which shows a slight signature of Mn{sup 2+} atomic multiplets associated with a local Mn moment, all samples have broad and featureless L{sub 3,2} absorption peaks, corresponding to an itinerant state for all 3d electrons. The broad X-ray absorption spectra exclude the possibility of a localized 3d moment and explain the unexpectedly quenched Mn moment in this magnetically-doped amorphous semiconductor. Such a fully delocalized d state of Mn dopant in Si has not been previously suggested.

  4. Mode conversion and absorption of fast waves at high ion cyclotron harmonics in inhomogeneous magnetic fields

    SciTech Connect (OSTI)

    Cho, Suwon; Kwak, Jong-Gu

    2014-04-15

    The propagation and absorption of high harmonic fast waves is of interest for non-inductive current drives in fusion experiments. The fast wave can be coupled with the ion Bernstein wave that propagates in the high magnetic field side of an ion cyclotron harmonic resonance layer. This coupling and the absorption are analyzed using the hot plasma dispersion relation and a wave equation that was converted from an approximate dispersion relation for the case where ?{sub i}=k{sub ?}{sup 2}?{sub i}{sup 2}/2?1 (where k{sub ?} is the perpendicular wave number and ?{sub i} is the ion Larmor radius). It is found that both reflection and conversion may occur near the harmonic resonance layer but that they decrease rapidly, giving rise to a sharp increase in the absorption as the parallel wave number increases.

  5. Suppression of the four-wave mixing amplification via Raman absorption

    E-Print Network [OSTI]

    Romanov, Gleb; Novikova, I

    2015-01-01

    We propose a method to controllably suppress the effect of the four-wave mixing caused by the coupling of the strong control optical field to both optical transitions in the $\\Lambda$ system under the conditions of electromagnetically induced transparency. At sufficiently high atomic density, this process leads to amplification of a weak optical signal field, that is detrimental for the fidelity of any EIT-based quantum information applications. Here we show that an additional absorption resonance centered around the idler field frequency, generated in such a four-wave mixing process, may efficiently suppress the unwanted signal amplification without affecting properties of the EIT interaction. We discuss the possibility of creating such tunable absorption using two-photon Raman absorption resonances in the other Rb isotope, and present some preliminary experimental results.

  6. VUV-absorption cross section of CO2 at high temperatures and impact on exoplanet atmospheres

    E-Print Network [OSTI]

    Venot, Olivia; Bénilan, Yves; Gazeau, Marie-Claire; Hébrard, Eric; Larcher, Gwenaelle; Schwell, Martin; Dobrijevic, Michel; Selsis, Franck

    2015-01-01

    Ultraviolet (UV) absorption cross sections are an essential ingredient of photochemical atmosphere models. Exoplanet searches have unveiled a large population of short-period objects with hot atmospheres, very different from what we find in our solar system. Transiting exoplanets whose atmospheres can now be studied by transit spectroscopy receive extremely strong UV fluxes and have typical temperatures ranging from 400 to 2500 K. At these temperatures, UV photolysis cross section data are severely lacking. Our goal is to provide high-temperature absorption cross sections and their temperature dependency for important atmospheric compounds. This study is dedicated to CO2, which is observed and photodissociated in exoplanet atmospheres. We performed these measurements for the 115 - 200 nm range at 300, 410, 480, and 550 K. In the 195 - 230 nm range, we worked at seven temperatures between 465 and 800 K. We found that the absorption cross section of CO2 is very sensitive to temperature, especially above 160 nm....

  7. Using laser absorption spectroscopy to monitor composition and physical properties of metal vapors

    SciTech Connect (OSTI)

    Berzins, L.V.

    1993-09-03

    The Atomic Vapor Laser Isotope Separation (AVLIS) program has been using laser absorption spectroscopy to monitor vapor densities for over 15 years. Laser absorption spectroscopy has proven itself to be an accurate and reliable method to monitor both density and composition. During this time the diagnostic has moved from a research tool toward a robust component of a process control system. The hardware used for this diagnostic is discussed elsewhere at this symposium. This paper describes how the laser absorption spectroscopy diagnostic is used as a component of a process control system as well as supplying detailed measurements on vapor densities, composition, flow velocity, internal and kinetic temperatures, and constituent distributions. Examples will be drawn from the uranium AVLIS program. In addition potential applications such as composition control in the production of metal matrix composites or aircraft alloys will be discussed.

  8. Systems having optical absorption layer for mid and long wave infrared and methods for making the same

    SciTech Connect (OSTI)

    Kuzmenko, Paul J

    2013-10-01

    An optical system according to one embodiment includes a substrate; and an optical absorption layer coupled to the substrate, wherein the optical absorption layer comprises a layer of diamond-like carbon, wherein the optical absorption layer absorbs at least 50% of mid wave infrared light (3-5 .mu.m wavelength) and at least 50% of long wave infrared light (8-13 .mu.m wavelength). A method for applying an optical absorption layer to an optical system according to another embodiment includes depositing a layer of diamond-like carbon of an optical absorption layer above a substrate using plasma enhanced chemical vapor deposition, wherein the optical absorption layer absorbs at least 50% of mid wave infrared light (3-5 .mu.m wavelength) and at least 50% of long wave infrared light (8-13 .mu.m wavelength). Additional systems and methods are also presented.

  9. Application of WLS strips for position determination in Strip PET tomograph based on plastic scintillators

    E-Print Network [OSTI]

    Smyrski, J; Bednarski, T; Bia?as, P; Czerwi?ski, E; Kap?on, ?; Kochanowski, A; Korcyl, G; Kowal, J; Kowalski, P; Kozik, T; Krzemie?, W; Molenda, M; Nied?wiecki, Sz; Pa?ka, M; Pawlik, M; Raczy?ski, L; Rudy, Z; Salabura, P; Sharma, N G; Silarski, M; S?omski, A; Strzelecki, A; Wi?licki, W; Zieli?ski, M; Zo?, N

    2013-01-01

    A method of determination of a gamma quantum absorption point in a plastic scintillator block using a matrix of wavelength-shifting (WLS) strips is proposed. Application of this method for improvement of position resolution in newly proposed PET detectors based on plastic scintillators is presented. The method enables to reduce parallax errors in reconstruction of images which occurs in the presently used Positron Emission Tomography scanners.

  10. Application of WLS strips for position determination in Strip PET tomograph based on plastic scintillators

    E-Print Network [OSTI]

    J. Smyrski; P. Moskal; T. Bednarski; P. Bia?as; E. Czerwi?ski; ?. Kap?on; A. Kochanowski; G. Korcyl; J. Kowal; P. Kowalski; T. Kozik; W. Krzemie?; M. Molenda; Sz. Nied?wiecki; M. Pa?ka; M. Pawlik; L. Raczy?ski; Z. Rudy; P. Salabura; N. G. Sharma; M. Silarski; A. S?omski; A. Strzelecki; W. Wi?licki; M. Zieli?ski; N. Zo?

    2013-11-24

    A method of determination of a gamma quantum absorption point in a plastic scintillator block using a matrix of wavelength-shifting (WLS) strips is proposed. Application of this method for improvement of position resolution in newly proposed PET detectors based on plastic scintillators is presented. The method enables to reduce parallax errors in reconstruction of images which occurs in the presently used Positron Emission Tomography scanners.

  11. Determination of the transient electron temperature in a femtosecond-laser-induced air plasma filament

    SciTech Connect (OSTI)

    Sun Zhanliang; Chen Jinhai; Rudolph, Wolfgang

    2011-04-15

    The transient electron temperature in a weakly ionized femtosecond-laser-produced air plasma filament was determined from optical absorption and diffraction experiments. The electron temperature and plasma density decay on similar time scales of a few hundred picoseconds. Comparison with plasma theory reveals the importance of inelastic collisions that lead to energy transfer to vibrational degrees of freedom of air molecules during the plasma cooling.

  12. On coaxial minors of determinants

    E-Print Network [OSTI]

    Babcock, Wealthy Consuelo

    1922-01-01

    . Approved by: ROOlOb SlSb^ Contents Page I. Introduction 1 II. Independence of Coaxial Minors of Special Determinants 9 A. Symmetric Determinant 9 B. Skew-symmetric Determinant ...14 C. Circulant 17 D. Hankel's Determinant 19 III... Introduction The work on coaxial minors of a deter­ minant has centered about the problems of deter­ mining the number of independent coaxial minors, of finding independent sets, and of expressing the determinant in terms of the minors of an independent set...

  13. A Unified Differential Evolution Algorithm for Global Optimization

    SciTech Connect (OSTI)

    Qiang, Ji; Mitchell, Chad

    2014-06-24

    Abstract?In this paper, we propose a new unified differential evolution (uDE) algorithm for single objective global optimization. Instead of selecting among multiple mutation strategies as in the conventional differential evolution algorithm, this algorithm employs a single equation as the mutation strategy. It has the virtue of mathematical simplicity and also provides users the flexbility for broader exploration of different mutation strategies. Numerical tests using twelve basic unimodal and multimodal functions show promising performance of the proposed algorithm in comparison to convential differential evolution algorithms.

  14. Optimal homotopy perturbation method for nonlinear differential equations governing MHD Jeffery-Hamel flow with heat transfer problem

    E-Print Network [OSTI]

    Marinca, Vasile

    2015-01-01

    In this paper, Optimal Homotopy Perturbation Method (OHPM) is employed to determine an analytic approximate solutions for nonlinear MHD Jeffery-Hamel flow and heat transfer problem. The Navier-Stokes equations, taking into account Maxwell's electromagnetism and heat transfer lead to two nonlinear ordinary differential equations. The obtained results by means of OHPM show a very good agreement in comparison with the numerical results and with Homotopy Perturbation Method (HPM).

  15. Peculiarities of the Light Absorption and Emission by Free Electrons in Multivalley Semiconductors

    E-Print Network [OSTI]

    P. M. Tomchuk

    2008-11-18

    General expressions are obtained for the coefficient of light absorption by free carriers as well as the intensity of the spontaneous light emission by hot electrons in multivalley semiconductors. These expressions depend on the electron concentration and electron temperature in the individual valleys. An anisotropy of the dispersion law and electron scattering mechanisms is taken into account. Impurity-related and acoustic scattering mechanisms are analyzed. Polarization dependence of the spontaneous emission by hot electrons is found out. At unidirectional pressure applied or high irradiation intensities, the polarization dependence also appears in the coefficient of light absorption by free electrons.

  16. Optical absorption in B{sub 13} cluster: A time-dependent density functional approach

    SciTech Connect (OSTI)

    Shinde, Ravindra; Tayade, Meenakshi

    2013-02-05

    The linear optical absorption spectra of three isomers of planar boron cluster B{sub 13} are calculated using time-dependent spin-polarized density functional approach. The geometries of these cluster are optimized at the B3LYP/6-311+G* level of theory. Even though the isomers are almost degenerate, the calculated spectra are quite different, indicating a strong structure-property relationship. Therefore, these computed spectra can be used in the photo-absorption experiments to distinguish between different isomers of a cluster.

  17. Non-degenerate two-photon absorption in silicon waveguides. Analytical and experimental study

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhang, Yanbing; Husko, Chad; Lefrancois, Simon; Rey, Isabella H.; Krauss, Thomas F.; Schröder, Jochen; Eggleton, Benjamin J.

    2015-06-22

    We theoretically and experimentally investigate the nonlinear evolution of two optical pulses in a silicon waveguide. We provide an analytic solution for the weak probe wave undergoing non-degenerate two-photon absorption (TPA) from the strong pump. At larger pump intensities, we employ a numerical solution to study the interplay between TPA and photo-generated free carriers. We develop a simple and powerful approach to extract and separate out the distinct loss contributions of TPA and free-carrier absorption from readily available experimental data. Our analysis accounts accurately for experimental results in silicon photonic crystal waveguides.

  18. Enhanced anomalous photo-absorption from TiO{sub 2} nanostructures

    SciTech Connect (OSTI)

    Solanki, Vanaraj; Majumder, Subrata; Mishra, Indrani; Varma, Shikha; Dash, P.; Singh, C.; Kanjilal, D.

    2014-03-28

    Two dimensional nanostructures have been created on the rutile TiO{sub 2} (110) surfaces via ion irradiation technique. Enhanced anomalous photo- absorption response is displayed, where nanostructures of 15?nm diameter with 0.5?nm height, and not the smaller nanostructures with larger surface area, delineate highest absorbance. Comprehensive investigations of oxygen vacancy states, on ion- irradiated surfaces, display a remarkable result that the number of vacancies saturates for higher fluences. A competition between the number of vacancy sites on the nanostructure in conjunction with its size is responsible for the observed anomalous photo-absorption.

  19. Enhancement of near-infrared absorption in graphene with metal gratings

    SciTech Connect (OSTI)

    Zhao, B.; Zhang, Z. M., E-mail: zhuomin.zhang@me.gatech.edu [G.W. Woodruff School of Mechanical Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332 (United States); Zhao, J. M. [G.W. Woodruff School of Mechanical Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332 (United States); School of Energy Science and Engineering, Harbin Institute of Technology, Harbin (China)

    2014-07-21

    Graphene has been demonstrated as a good candidate for ultrafast optoelectronic devices. However, graphene is essentially transparent in the visible and near infrared with an absorptivity of 2.3%, which has largely limited its application in photon detection. This Letter demonstrates that the absorptance in a monatomic graphene layer can be greatly enhanced to nearly 70%, thanks to the localized strong electric field resulting from magnetic resonances in deep metal gratings. Furthermore, the resonance frequency is essentially not affected by the additional graphene layer. The method presented here may benefit the design of next-generation graphene-based optical and optoelectronic devices.

  20. Method for measuring changes in light absorption of highly scattering media

    DOE Patents [OSTI]

    Bigio, Irving J. (Los Alamos, NM); Johnson, Tamara M. (Los Alamos, NM); Mourant, Judith R. (Los Alamos, NM)

    2002-01-01

    The noninvasive measurement of variations in absorption that are due to changes in concentrations of biochemically relevant compounds in tissue is important in many clinical settings. One problem with such measurements is that the pathlength traveled by the collected light through the tissue depends on the scattering properties of the tissue. It is demonstrated, using both Monte Carlo simulations and experimental measurements, that for an appropriate separation between light-delivery and light-collection fibers, the pathlength of the collected photons is insensitive to scattering parameters for the range of parameters typically found in tissue. This is important for developing rapid, noninvasive, inexpensive, and accurate methods for measuring absorption changes in tissue.