National Library of Energy BETA

Sample records for determination coupled high

  1. Determination of formate in natural waters by a coupled enzymatic/high-performance liquid chromatographic technique

    SciTech Connect (OSTI)

    Kieber, D.J.; Vaughan, G.M.; Mopper, K.

    1988-09-01

    An enzymatic method was developed to quantify formic acid in natural water samples at submicromolar concentrations. The method is based on the oxidation of formate by formate dehydrogenase with corresponding reduction of ..beta..-nicotinamide adenine dinucleotide (..beta..-NAD/sup +/) to reduced ..beta..-NAD/sup +/ (..beta..-NADH); ..beta..-NADH is quantified by reversed-phase high-performance liquid chromatography with fluorometric detection. An important feature of this method is that the enzymatic reaction occurs directly in aqueous media, even sea water, and does not require sample pretreatment other than sample filtration. The reaction proceeds at room temperature at a slightly alkaline pH (7.5 - 8.5) and is specific for formate with a detection limit of 0.5 ..mu..M (S/N = 4) for a 200-..mu..L injection. The precision of the method was 4.6% relative standard deviation (n = 6) for a 0.6 ..mu..M standard addition of formate to Sargasso sea water. Average recoveries of 2 ..mu..M additions of formate to sea water, pore water, or rain were 103, 103, and 87%, respectively. Intercalibration with a Dionex ion chromatographic system showed an excellent agreement of 98%. Concentrations of formate present in natural samples ranged from 0.2 to 0.8 ..mu..M for Biscayne Bay sea water, 0.4 to 10.0 ..mu..M for Miami rain, and 0.9 to 8.4 ..mu..M for Biscayne Bay sediment pore water.

  2. Highly damped kinematic coupling for precision instruments

    DOE Patents [OSTI]

    Hale, Layton C.; Jensen, Steven A.

    2001-01-01

    A highly damped kinematic coupling for precision instruments. The kinematic coupling provides support while causing essentially no influence to its nature shape, with such influences coming, for example, from manufacturing tolerances, temperature changes, or ground motion. The coupling uses three ball-cone constraints, each combined with a released flexural degree of freedom. This arrangement enables a gain of higher load capacity and stiffness, but can also significantly reduce the friction level in proportion to the ball radius divided by the distance between the ball and the hinge axis. The blade flexures reduces somewhat the stiffness of the coupling and provides an ideal location to apply constrained-layer damping which is accomplished by attaching a viscoelastic layer and a constraining layer on opposite sides of each of the blade flexures. The three identical ball-cone flexures provide a damped coupling mechanism to kinematically support the projection optics system of the extreme ultraviolet lithography (EUVL) system, or other load-sensitive apparatus.

  3. Determining the microwave coupling and operational efficiencies of a microwave plasma assisted chemical vapor deposition reactor under high pressure diamond synthesis operating conditions

    SciTech Connect (OSTI)

    Nad, Shreya; Gu, Yajun; Asmussen, Jes

    2015-07-15

    The microwave coupling efficiency of the 2.45 GHz, microwave plasma assisted diamond synthesis process is investigated by experimentally measuring the performance of a specific single mode excited, internally tuned microwave plasma reactor. Plasma reactor coupling efficiencies (η) > 90% are achieved over the entire 100–260 Torr pressure range and 1.5–2.4 kW input power diamond synthesis regime. When operating at a specific experimental operating condition, small additional internal tuning adjustments can be made to achieve η > 98%. When the plasma reactor has low empty cavity losses, i.e., the empty cavity quality factor is >1500, then overall microwave discharge coupling efficiencies (η{sub coup}) of >94% can be achieved. A large, safe, and efficient experimental operating regime is identified. Both substrate hot spots and the formation of microwave plasmoids are eliminated when operating within this regime. This investigation suggests that both the reactor design and the reactor process operation must be considered when attempting to lower diamond synthesis electrical energy costs while still enabling a very versatile and flexible operation performance.

  4. Experimental determination of the effective strong coupling constant

    SciTech Connect (OSTI)

    Alexandre Deur; Volker Burkert; Jian-Ping Chen; Wolfgang Korsch

    2007-07-01

    We extract an effective strong coupling constant from low Q{sup 2} data on the Bjorken sum. Using sum rules, we establish its Q{sup 2}-behavior over the complete Q{sup 2}-range. The result is compared to effective coupling constants extracted from different processes and to calculations based on Schwinger-Dyson equations, hadron spectroscopy or lattice QCD. Although the connection between the experimentally extracted effective coupling constant and the calculations is not clear, the results agree surprisingly well.

  5. High precision tune and coupling measurements and tune/coupling feedback in RHIC

    SciTech Connect (OSTI)

    Minty, M.; Curcio, A.; Dawson, C.; Degen, C.; Luo, Y.; Marr, G.; Martin, B.; Marusic, A.; Mernick, K.; Oddo, P.; Russo, T.; Schoefer, V.; Schroeder, R.; Schulthiess, C.; Wilinski, M.

    2010-08-01

    Precision measurement and control of the betatron tunes and betatron coupling in RHIC are required for establishing and maintaining both good operating conditions and, particularly during the ramp to high beam energies, high proton beam polarization. While the proof-of-principle for simultaneous tune and coupling feedback was successfully demonstrated earlier, routine application of these systems has only become possible recently. Following numerous modifications for improved measurement resolution and feedback control, the time required to establish full-energy beams with the betatron tunes and coupling regulated by feedback was reduced from several weeks to a few hours. A summary of these improvements, select measurements benefitting from the improved resolution and a review of system performance are the subject of this report.

  6. High ethylene to ethane processes for oxidative coupling

    DOE Patents [OSTI]

    Chafin, Richard B.; Warren, Barbara K.

    1991-01-01

    Oxidative coupling of lower alkane to higher hydrocarbon is conducted using catalyst comprising barium and/or strontium component and a metal oxide combustion promoter in the presence of vapor phase halogen component. High ethylene to ethane mole ratios in the product can be obtained over extended operating periods.

  7. High ethylene to ethane processes for oxidative coupling

    DOE Patents [OSTI]

    Chafin, R.B.; Warren, B.K.

    1991-12-17

    Oxidative coupling of lower alkane to higher hydrocarbon is conducted using a catalyst comprising barium and/or strontium component and a metal oxide combustion promoter in the presence of vapor phase halogen component. High ethylene to ethane mole ratios in the product can be obtained over extended operating periods.

  8. Antenna-coupled high T.sub.c superconducting microbolometer

    DOE Patents [OSTI]

    Hu, Qing (Boston, MA)

    1992-01-01

    A device is provided for measuring radiant energy, the device comprising a substrate; a bolometer formed from a high T.sub.c superconducting material disposed on the substrate in an area that is about 1.times.5 .mu.m.sup.2 and about 0.02 .mu.m in depth; and a planar antenna disposed on the substrate and coupled to receive radiation and to impart the received radiation to the bolometer.

  9. Antenna-coupled high T[sub c] superconducting microbolometer

    DOE Patents [OSTI]

    Hu, Q.

    1992-12-15

    A device is provided for measuring radiant energy, the device comprising a substrate; a bolometer formed from a high T[sub c] superconducting material disposed on the substrate in an area that is about 1[times]5 [mu]m[sup 2] and about 0.02 [mu]m in depth; and a planar antenna disposed on the substrate and coupled to receive radiation and to impart the received radiation to the bolometer. 5 figs.

  10. Mile High: Noncompliance Determination (2012-SE-4501)

    Broader source: Energy.gov [DOE]

    DOE issued a Notice of Noncompliance Determination to Mile High Equipment, LLC finding that Ice-O-Matic brand automatic commercial ice maker basic model ICE2106 FW, HW does not comport with the energy conservation standards.

  11. Determination of the Z` Mass and Couplings Below Threshold at the NLC

    SciTech Connect (OSTI)

    Rizzo, Thomas G.

    1996-12-31

    We investigate the capability of the NLC to indirectly determine both the mass as well as the couplings to leptons and b-quarks of a new neutral gauge boson below direct production threshold. By using data collected at several different values of the collide center of mass energy, we demonstrate how this can be done in an anonymous and model- independent manner. The procedure can be easily extended to the top and charm quark couplings.

  12. COUPLING

    DOE Patents [OSTI]

    Frisch, E.; Johnson, C.G.

    1962-05-15

    A detachable coupling arrangement is described which provides for varying the length of the handle of a tool used in relatively narrow channels. The arrangement consists of mating the key and keyhole formations in the cooperating handle sections. (AEC)

  13. Exploration of below threshold Z{sup {prime}} mass and coupling determinations at the NLC

    SciTech Connect (OSTI)

    Rizzo, T.G.

    1997-05-01

    We examine of the capability of the Next Linear Collider to determine the mass as well as the couplings to leptons and b quarks of a new neutral gauge boson Z{sup {prime}} below direct production threshold. By using simulated data collected at several different values of {radical}(s), we demonstrate how this can be done in a model-independent manner via an anonymous case approach. The importance of beam polarization to the success of this program is discussed. The procedure is shown to be easily extended to the case of top and charm quark couplings. {copyright} {ital 1997} {ital The American Physical Society}

  14. Determination of trace amounts of cerium in paint by inductively coupled plasma atomic emission spectrometry

    SciTech Connect (OSTI)

    Wong, K.L.

    1981-11-01

    The determination of Ce in paint by inductively coupled plasma atomic emission spectrometry (ICP-OES) is described, and the detection limit of ICP-OES of 0.0004 ppM is compared with that of other methods. The effects of the major elemental components of paint, Si, Pb, Cr, and Na on the ICP-OES determination of Ce were studied. The interference of 400 ppM of the other ions on the determination of 10 ppM Ce was small (0 to 3% error). The method is applicable to the range of 0.2 to 700 ppM Ce. (BLM)

  15. A comparison of light-coupling into high and low index nanostructured photovoltaic thin films

    SciTech Connect (OSTI)

    Pfadler, T.; Stärk, M.; Zimmermann, E.; Putnik, M.; Boneberg, J.; Weickert, J. E-mail: lukas.schmidt-mende@uni-konstanz.de; Schmidt-Mende, L. E-mail: lukas.schmidt-mende@uni-konstanz.de

    2015-06-01

    Periodically structured electrodes are typically introduced to thin-film photovoltaics for the purpose of light management. Highly effective light-trapping and optimal in-coupling of light is crucial to enhance the overall device performance in such thin-film systems. Here, wavelength-scale structures are transferred via direct laser interference patterning to electron-selective TiO{sub 2} electrodes. Two representative thin-film solar cell architectures are deposited on top: an organic solar cell featuring blended P3HT:PCBM as active material, and a hybrid solar cell with Sb{sub 2}S{sub 3} as inorganic active material. A direct correlation in the asymmetry in total absorption enhancement and in structure-induced light in-coupling is spectroscopically observed for the two systems. The structuring is shown to be beneficial for the total absorption enhancement if a high n active material is deposited on TiO{sub 2}, but detrimental for a low n material. The refractive indices of the employed materials are determined via spectroscopic ellipsometry. The study outlines that the macroscopic Fresnel equations can be used to investigate the spectroscopically observed asymmetry in light in-coupling at the nanostructured TiO{sub 2} active material interfaces by visualizing the difference in reflectivity caused by the asymmetry in refractive indices.

  16. Coupled Model for Heat and Water Transport in a High Level Waste Repository in Salt

    Broader source: Energy.gov [DOE]

    This report summarizes efforts to simulate coupled thermal-hydrological-chemical (THC) processes occurring within a generic hypothetical high-level waste (HLW) repository in bedded salt.

  17. High-accuracy coupled cluster calculations of atomic properties

    SciTech Connect (OSTI)

    Borschevsky, A.; Yakobi, H.; Eliav, E.; Kaldor, U.

    2015-01-22

    The four-component Fock-space coupled cluster and intermediate Hamiltonian methods are implemented to evaluate atomic properties. The latter include the spectra of nobelium and lawrencium (elements 102 and 103) in the range 20000-30000 cm{sup −1}, the polarizabilities of elements 112-114 and 118, required for estimating their adsorption enthalpies on surfaces used to separate them in accelerators, and the nuclear quadrupole moments of some heavy atoms. The calculations on superheavy elements are supported by the very good agreement with experiment obtained for the lighter homologues.

  18. High Resolution Studies of the Origins of Polyatomic Ions in Inductively Coupled Plasma-Mass Spectrometry

    SciTech Connect (OSTI)

    Jill Wisnewski Ferguson

    2006-08-09

    The inductively coupled plasma (ICP) is an atmospheric pressure ionization source. Traditionally, the plasma is sampled via a sampler cone. A supersonic jet develops behind the sampler, and this region is pumped down to a pressure of approximately one Torr. A skimmer cone is located inside this zone of silence to transmit ions into the mass spectrometer. The position of the sampler and skimmer cones relative to the initial radiation and normal analytical zones of the plasma is key to optimizing the useful analytical signal [1]. The ICP both atomizes and ionizes the sample. Polyatomic ions form through ion-molecule interactions either in the ICP or during ion extraction [l]. Common polyatomic ions that inhibit analysis include metal oxides (MO{sup +}), adducts with argon, the gas most commonly used to make up the plasma, and hydride species. While high resolution devices can separate many analytes from common interferences, this is done at great cost in ion transmission efficiency--a loss of 99% when using high versus low resolution on the same instrument [2]. Simple quadrupole devices, which make up the bulk of ICP-MS instruments in existence, do not present this option. Therefore, if the source of polyatomic interferences can be determined and then manipulated, this could potentially improve the figures of merit on all ICP-MS devices, not just the high resolution devices often utilized to study polyatomic interferences.

  19. Determining Cloud Ice Water Path from High-Frequency Microwave...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Determining Cloud Ice Water Path from High-Frequency Microwave Measurements G. Liu ... A better understanding of cloud water content and its large-scale distribution ...

  20. Characterization of the Li(Si)/CoS(2) couple for a high-voltage, high-power thermal battery

    SciTech Connect (OSTI)

    GUIDOTTI,RONALD A.; REINHARDT,FREDERICK W.

    2000-02-01

    In order to determined the capabilities of a thermal battery with high-voltage and high-power requirements, a detailed characterization of the candidate LiSi/LiCl-LiBr-LiF/CoS{sub 2} electrochemical couple was conducted. The rate capability of this system was investigated using 0.75 inch-dia. and 1.25 inch-dia. single and multiple cells under isothermal conditions, where the cells were regularly pulsed at increasingly higher currents. Limitations of the electronic loads and power supplies necessitated using batteries to obtain the desired maximum current densities possible for this system. Both 1.25 inch-dia. and 3 inch-dia. stacks were used with the number of cells ranging from 5 to 20. Initial tests involved 1.25 inch-dia. cells, where current densities in excess of 15 A/cm{sup 2} (>200 W/cm{sup 2}) were attained with 20-cell batteries during 1-s pulses. In subsequent follow-up tests with 3 inch-dia., 10-cell batteries, ten 400-A 1-s pulses were delivered over an operating period often minutes. These tests formed the foundation for subsequent full-sized battery tests with 125 cells with this chemistry.

  1. Modeling Coupled THM Processes and Brine Migration in Salt at High Temperatures

    SciTech Connect (OSTI)

    Rutqvist, Jonny; Blanco-Martin, Laura; Molins, Sergi; Trebotich, David; Birkholzer, Jens

    2015-09-01

    In this report, we present FY2015 progress by Lawrence Berkeley National Laboratory (LBNL) related to modeling of coupled thermal-hydrological-mechanical-chemical (THMC) processes in salt and their effect on brine migration at high temperatures. This is a combined milestone report related to milestone Salt R&D Milestone “Modeling Coupled THM Processes and Brine Migration in Salt at High Temperatures” (M3FT-15LB0818012) and the Salt Field Testing Milestone (M3FT-15LB0819022) to support the overall objectives of the salt field test planning.

  2. High-energy jet quenching in weakly coupled quark-gluon plasmas

    SciTech Connect (OSTI)

    Arnold, Peter; Xiao Wei

    2008-12-15

    q is the average squared transverse momentum transfer per unit length to a high-energy particle traversing a QCD medium such as a quark-gluon plasma. We find the (UV-regulated) value of q to leading order in the weak coupling limit, {alpha}{sub s}(T)<<1. We then use this value to generalize previous analytic results on the gluon bremsstrahlung and pair production rates for massless high-energy particles in a weakly coupled quark-gluon plasma, at next-to-leading logarithmic order.

  3. A literature review of coupled thermal-hydrologic-mechanical-chemical processes pertinent to the proposed high-level nuclear waste repository at Yucca Mountain

    SciTech Connect (OSTI)

    Manteufel, R.D.; Ahola, M.P.; Turner, D.R.; Chowdhury, A.H.

    1993-07-01

    A literature review has been conducted to determine the state of knowledge available in the modeling of coupled thermal (T), hydrologic (H), mechanical (M), and chemical (C) processes relevant to the design and/or performance of the proposed high-level waste (HLW) repository at Yucca Mountain, Nevada. The review focuses on identifying coupling mechanisms between individual processes and assessing their importance (i.e., if the coupling is either important, potentially important, or negligible). The significance of considering THMC-coupled processes lies in whether or not the processes impact the design and/or performance objectives of the repository. A review, such as reported here, is useful in identifying which coupled effects will be important, hence which coupled effects will need to be investigated by the US Nuclear Regulatory Commission in order to assess the assumptions, data, analyses, and conclusions in the design and performance assessment of a geologic reposit``. Although this work stems from regulatory interest in the design of the geologic repository, it should be emphasized that the repository design implicitly considers all of the repository performance objectives, including those associated with the time after permanent closure. The scope of this review is considered beyond previous assessments in that it attempts with the current state-of-knowledge) to determine which couplings are important, and identify which computer codes are currently available to model coupled processes.

  4. High Precision Tune and Coupling Feedback and Beam Transfer Function Measurements in RHIC

    SciTech Connect (OSTI)

    Minty, M.; Curcio, A.; Dawson, C.; Degen, C.; Luo, Y.; Marr, G.; Martin, B.; Marusic, A.; Mernick, K.; Oddo, P.; Russo, T.; Schoefer, V.; Schroeder, R.; Schultheiss, C.; Wilinski, M.

    2010-05-23

    Precision measurement and control of the betatron tunes and betatron coupling in the Relativistic Heavy Ion Collider (RHIC) are required for establishing and maintaining both good operating conditions and, particularly during the ramp to high beam energies, high proton beam polarization. While the proof-of-principle for simultaneous tune and coupling feedback was successfully demonstrated earlier, routine application of these systems has only become possible recently. Following numerous modifications for improved measurement resolution and feedback control, the time required to establish full-energy beams with the betatron tunes and coupling regulated by feedback was reduced from several weeks to a few hours. A summary of these improvements, select measurements benefitting from the improved resolution and a review of system performance are the subject of this report.

  5. Stopping distance for high energy jets in weakly coupled quark-gluon plasmas

    SciTech Connect (OSTI)

    Arnold, Peter; Cantrell, Sean; Xiao Wei

    2010-02-15

    We derive a simple formula for the stopping distance for a high-energy quark traveling through a weakly coupled quark-gluon plasma. The result is given to next-to-leading order in an expansion in inverse logarithms ln(E/T), where T is the temperature of the plasma. We also define a stopping distance for gluons and give a leading-log result. Discussion of stopping distance has a theoretical advantage over discussion of energy loss rates in that stopping distances can be generalized to the case of strong coupling, where one may not speak of individual partons.

  6. Direct Drive Heavy-Ion-Beam Inertial Fusion at High Coupling Efficiency

    SciTech Connect (OSTI)

    Logan, B. Grant; Logan, B. Grant; Perkins, L.J.; Barnard, J.J.

    2007-06-25

    Issues with coupling efficiency, beam illumination symmetry and Rayleigh Taylor (RT) instability are discussed for spherical heavy-ion-beam-driven targets with and without hohlraums. Efficient coupling of heavy ion beams to compress direct-drive inertial fusion targets without hohlraums is found to require ion range increasing several-fold during the drive pulse. One-dimensional implosion calculations using the LASNEX ICF target physics code shows the ion range increasing four-fold during the drive pulse to keep ion energy deposition following closely behind the imploding ablation front, resulting in high coupling efficiencies (shell kinetic energy/incident beam energy of 16 to 18%). Ways to increase beam ion range while mitigating Rayleigh-Taylor instabilities are discussed for future work.

  7. Tune Determination of Strongly Coupled Betatron Oscillations in a Fast-Ramping Synchrotron

    SciTech Connect (OSTI)

    Alexahin, Y.; Gianfelice-Wendt, E.; Marsh, W; Triplett, K.; /Fermilab

    2012-05-01

    Tune identification -- i.e. attribution of the spectral peak to a particular normal de of oscillations -- can present a significant difficulty in the presence of strong transverse coupling when the normal mode with a lower damping rate dominates spectra of Turn-by-Turn oscillations in both planes. The introduced earlier phased sum algorithm helped to recover the weaker normal mode signal from the noise, but by itself proved to be insufficient for automatic peak identification in the case of close phase advance distribution in both planes. To resolve this difficulty we modified the algorithm by taking and analyzing Turn-by-Turn data for two different ramps with the beam oscillation excited in each plane in turn. Comparison of relative amplitudes of Fourier components allows for correct automatic tune identification. The proposed algorithm was implemented in the Fermilab Booster B38 console application and successfully used for tune, coupling and chromaticity measurements.

  8. Lattice coupling to electronic and magnetic instabilities in high magnetic fields

    SciTech Connect (OSTI)

    Thompson, J.D.; Graf, T.; Hundley, M.; Neumeier, J. [Los Alamos National Lab., NM (United States); Lacerda, A. [National High Magnetic Field Lab., Tallahassee, FL (United States); Lawrence, J. [California Univ., Irvine, CA (United States); Phillips, N. [California Univ., Berkeley, CA (United States)

    1996-04-01

    This is the final report of a three-year, Laboratory-Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL). The project focused on understanding electronic and magnetic instabilities in broad classes of materials in which the instabilities are coupled to the underlying crystallographic structure. Explaining these properties of materials poses outstanding theoretical and experimental challenges that are at the forefront of materials science/condensed matter physics. Very high magnetic fields available at the Los Alamos National High Magnetic Field Laboratory (NHMFL) are a key parameter in helping to provide this understanding. We have developed new experimental capabilities (thermal- expansion/magnetostriction, uniaxial stress and high-field heat capacity) needed to characterize how structure couples to the instabilities.

  9. Inductively coupled plasma-atomic emission spectroscopy: a computer controlled, scanning monochromator system for the rapid determination of the elements

    SciTech Connect (OSTI)

    Floyd, M.A.

    1980-03-01

    A computer controlled, scanning monochromator system specifically designed for the rapid, sequential determination of the elements is described. The monochromator is combined with an inductively coupled plasma excitation source so that elements at major, minor, trace, and ultratrace levels may be determined, in sequence, without changing experimental parameters other than the spectral line observed. A number of distinctive features not found in previously described versions are incorporated into the system here described. Performance characteristics of the entire system and several analytical applications are discussed.

  10. Simulating High Flux Isotope Reactor Core Thermal-Hydraulics via Interdimensional Model Coupling

    SciTech Connect (OSTI)

    Travis, Adam R

    2014-05-01

    A coupled interdimensional model is presented for the simulation of the thermal-hydraulic characteristics of the High Flux Isotope Reactor core at Oak Ridge National Laboratory. The model consists of two domains a solid involute fuel plate and the surrounding liquid coolant channel. The fuel plate is modeled explicitly in three-dimensions. The coolant channel is approximated as a twodimensional slice oriented perpendicular to the fuel plate s surface. The two dimensionally-inconsistent domains are linked to one another via interdimensional model coupling mechanisms. The coupled model is presented as a simplified alternative to a fully explicit, fully three-dimensional model. Involute geometries were constructed in SolidWorks. Derivations of the involute construction equations are presented. Geometries were then imported into COMSOL Multiphysics for simulation and modeling. Both models are described in detail so as to highlight their respective attributes in the 3D model, the pursuit of an accurate, reliable, and complete solution; in the coupled model, the intent to simplify the modeling domain as much as possible without affecting significant alterations to the solution. The coupled model was created with the goal of permitting larger portions of the reactor core to be modeled at once without a significant sacrifice to solution integrity. As such, particular care is given to validating incorporated model simplifications. To the greatest extent possible, the decrease in solution time as well as computational cost are quantified versus the effects such gains have on the solution quality. A variant of the coupled model which sufficiently balances these three solution characteristics is presented alongside the more comprehensive 3D model for comparison and validation.

  11. Advances in coupled safety modeling using systems analysis and high-fidelity methods.

    SciTech Connect (OSTI)

    Fanning, T. H.; Thomas, J. W.; Nuclear Engineering Division

    2010-05-31

    The potential for a sodium-cooled fast reactor to survive severe accident initiators with no damage has been demonstrated through whole-plant testing in EBR-II and FFTF. Analysis of the observed natural protective mechanisms suggests that they would be characteristic of a broad range of sodium-cooled fast reactors utilizing metal fuel. However, in order to demonstrate the degree to which new, advanced sodium-cooled fast reactor designs will possess these desired safety features, accurate, high-fidelity, whole-plant dynamics safety simulations will be required. One of the objectives of the advanced safety-modeling component of the Reactor IPSC is to develop a science-based advanced safety simulation capability by utilizing existing safety simulation tools coupled with emerging high-fidelity modeling capabilities in a multi-resolution approach. As part of this integration, an existing whole-plant systems analysis code has been coupled with a high-fidelity computational fluid dynamics code to assess the impact of high-fidelity simulations on safety-related performance. With the coupled capabilities, it is possible to identify critical safety-related phenomenon in advanced reactor designs that cannot be resolved with existing tools. In this report, the impact of coupling is demonstrated by evaluating the conditions of outlet plenum thermal stratification during a protected loss of flow transient. Outlet plenum stratification was anticipated to alter core temperatures and flows predicted during natural circulation conditions. This effect was observed during the simulations. What was not anticipated, however, is the far-reaching impact that resolving thermal stratification has on the whole plant. The high temperatures predicted at the IHX inlet due to thermal stratification in the outlet plenum forces heat into the intermediate system to the point that it eventually becomes a source of heat for the primary system. The results also suggest that flow stagnation in the

  12. Modeling Coupled THMC Processes and Brine Migration in Salt at High Temperatures

    SciTech Connect (OSTI)

    Rutqvist, Jonny; Blanco Martin, Laura; Mukhopadhyay, Sumit; Houseworth, Jim; Birkholzer, Jens

    2014-08-14

    In this report, we present FY2014 progress by Lawrence Berkeley National Laboratory (LBNL) related to modeling of coupled thermal-hydrological-mechanical-chemical (THMC) processes in salt and their effect on brine migration at high temperatures. LBNL’s work on the modeling of coupled THMC processes in salt was initiated in FY2012, focusing on exploring and demonstrating the capabilities of an existing LBNL modeling tool (TOUGH-FLAC) for simulating temperature-driven coupled flow and geomechanical processes in salt. This work includes development related to, and implementation of, essential capabilities, as well as testing the model against relevant information and published experimental data related to the fate and transport of water. we provide more details on the FY2014 work, first presenting updated tools and improvements made to the TOUGH-FLAC simulator, and the use of this updated tool in a new model simulation of long-term THM behavior within a generic repository in a salt formation. This is followed by the description of current benchmarking and validations efforts, including the TSDE experiment. We then present the current status in the development of constitutive relationships and the dual-continuum model for brine migration. We conclude with an outlook for FY2015, which will be much focused on model validation against field experiments and on the use of the model for the design studies related to a proposed heater experiment.

  13. Raman spectroscopy of graphite in high magnetic fields: Electron-phonon coupling and magnetophonon resonance

    SciTech Connect (OSTI)

    Kim, Younghee; Smirnov, Dmitry; Kalugin, Nikolai G.; Lombardo, Antonio; Ferrari, Andrea C.

    2013-12-04

    The magneto-Raman measurements of graphite were performed in a back-scattering Faraday geometry at temperature 10 K in magnetic fields up to 45 T. The experimental data reveal the rich structure of Raman-active excitations dominated by K-point massive electrons. At high magnetic fields the graphite E{sub 2g} Raman line shows complex multi- component behavior interpreted as magnetophonon resonance coupled electron-phonon modes at graphite’s K-point. Also we found the clear signature of the fundamental, strongly dumped, n=0 magnetophonon resonance associated with H point massless holes.

  14. Determination of total chlorine and bromine in solid wastes by sintering and inductively coupled plasma-sector field mass spectrometry

    SciTech Connect (OSTI)

    Osterlund, Helene Rodushkin, Ilia; Ylinenjaervi, Karin; Baxter, Douglas C.

    2009-04-15

    A sample preparation method based on sintering, followed by analysis by inductively coupled plasma-sector field mass spectrometry (ICP-SFMS) for the simultaneous determination of chloride and bromide in diverse and mixed solid wastes, has been evaluated. Samples and reference materials of known composition were mixed with a sintering agent containing Na{sub 2}CO{sub 3} and ZnO and placed in an oven at 560 deg. C for 1 h. After cooling, the residues were leached with water prior to a cation-exchange assisted clean-up. Alternatively, a simple microwave-assisted digestion using only nitric acid was applied for comparison. Thereafter the samples were prepared for quantitative analysis by ICP-SFMS. The sintering method was evaluated by analysis of certified reference materials (CRMs) and by comparison with US EPA Method 5050 and ion chromatography with good agreement. Median RSDs for the sintering method were determined to 10% for both chlorine and bromine, and median recovery to 96% and 97%, respectively. Limits of detection (LODs) were 200 mg/kg for chlorine and 20 mg/kg for bromine. It was concluded that the sintering method is suitable for chlorine and bromine determination in several matrices like sewage sludge, plastics, and edible waste, as well as for waste mixtures. The sintering method was also applied for determination of other elements present in anionic forms, such as sulfur, arsenic, selenium and iodine.

  15. Interplanar coupling-dependent magnetoresistivity in high-purity layered metals

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kikugawa, N.; Goswami, P.; Kiswandhi, A.; Choi, E. S.; Graf, D.; Baumbach, R. E.; Brooks, J. S.; Sugii, K.; Iida, Y.; Nishio, M.; et al

    2016-03-29

    The magnetic field-induced changes in the conductivity of metals are the subject of intense interest, both for revealing new phenomena and as a valuable tool for determining their Fermi surface. Here we report a hitherto unobserved magnetoresistive effect in ultra-clean layered metals, namely a negative longitudinal magnetoresistance that is capable of overcoming their very pronounced orbital one. This effect is correlated with the interlayer coupling disappearing for fields applied along the so-called Yamaji angles where the interlayer coupling vanishes. Therefore, it is intrinsically associated with the Fermi points in the field-induced quasi-one-dimensional electronic dispersion, implying that it results from themore » axial anomaly among these Fermi points. In its original formulation, the anomaly is predicted to violate separate number conservation laws for left- and right-handed chiral (for example, Weyl) fermions. Furthermore, its observation in PdCoO2, PtCoO2 and Sr2RuO4 suggests that the anomaly affects the transport of clean conductors, in particular near the quantum limit.« less

  16. Strong exciton-photon coupling with colloidal quantum dots in a high-Q bilayer microcavity

    SciTech Connect (OSTI)

    Giebink, Noel C; Wiederrecht, Gary P.; Wasielewski, Michael R

    2011-01-01

    We demonstrate evanescently coupled bilayer microcavities with Q -factors exceeding 250 fabricated by a simple spin-coating process. The cavity architecture consists of a slab waveguide lying upon a low refractive index spacer layer supported by a glass substrate. For a lossless guide layer, the cavity Q depends only on the thickness of the low index spacer and in principle can reach arbitrarily high values. We demonstrate the versatility of this approach by constructing cavities with a guide layer incorporating CdSe/ZnS core/shell quantum dots, where we observe strong coupling and hybridization between the 1S(e)-1S{sub 3/2} (h) and 1S(e)-2S{sub 3/2} (h) exciton states mediated by the cavity photon. This technique greatly simplifies the fabrication of high-Q planar microcavities for organic and inorganic quantum dot thin films and opens up new opportunities for the study of nonlinear optical phenomena in these materials.

  17. High-performance parallel processors based on star-coupled wavelength division multiplexing optical interconnects

    DOE Patents [OSTI]

    Deri, Robert J.; DeGroot, Anthony J.; Haigh, Ronald E.

    2002-01-01

    As the performance of individual elements within parallel processing systems increases, increased communication capability between distributed processor and memory elements is required. There is great interest in using fiber optics to improve interconnect communication beyond that attainable using electronic technology. Several groups have considered WDM, star-coupled optical interconnects. The invention uses a fiber optic transceiver to provide low latency, high bandwidth channels for such interconnects using a robust multimode fiber technology. Instruction-level simulation is used to quantify the bandwidth, latency, and concurrency required for such interconnects to scale to 256 nodes, each operating at 1 GFLOPS performance. Performance scales have been shown to .apprxeq.100 GFLOPS for scientific application kernels using a small number of wavelengths (8 to 32), only one wavelength received per node, and achievable optoelectronic bandwidth and latency.

  18. Piezoelectricity above the Curie temperature? Combining flexoelectricity and functional grading to enable high-temperature electromechanical coupling

    SciTech Connect (OSTI)

    Mbarki, R.; Baccam, N.; Dayal, Kaushik; Sharma, P.

    2014-03-24

    Most technologically relevant ferroelectrics typically lose piezoelectricity above the Curie temperature. This limits their use to relatively low temperatures. In this Letter, exploiting a combination of flexoelectricity and simple functional grading, we propose a strategy for high-temperature electromechanical coupling in a standard thin film configuration. We use continuum modeling to quantitatively demonstrate the possibility of achieving apparent piezoelectric materials with large and temperature-stable electromechanical coupling across a wide temperature range that extends significantly above the Curie temperature. With Barium and Strontium Titanate, as example materials, a significant electromechanical coupling that is potentially temperature-stable up to 900 °C is possible.

  19. Impact of surface coupling grids on tropical cyclone extremes in high-resolution atmospheric simulations

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zarzycki, Colin M.; Reed, Kevin A.; Bacmeister, Julio T.; Craig, Anthony P.; Bates, Susan C.; Rosenbloom, Nan A.

    2016-02-25

    This article discusses the sensitivity of tropical cyclone climatology to surface coupling strategy in high-resolution configurations of the Community Earth System Model. Using two supported model setups, we demonstrate that the choice of grid on which the lowest model level wind stress and surface fluxes are computed may lead to differences in cyclone strength in multi-decadal climate simulations, particularly for the most intense cyclones. Using a deterministic framework, we show that when these surface quantities are calculated on an ocean grid that is coarser than the atmosphere, the computed frictional stress is misaligned with wind vectors in individual atmospheric gridmore » cells. This reduces the effective surface drag, and results in more intense cyclones when compared to a model configuration where the ocean and atmosphere are of equivalent resolution. Our results demonstrate that the choice of computation grid for atmosphere–ocean interactions is non-negligible when considering climate extremes at high horizontal resolution, especially when model components are on highly disparate grids.« less

  20. DETERMINATION OF 237NP AND PU ISOTOPES IN LARGE SOIL SAMPLES BY INDUCTIVELY COUPLED PLASMA MASS SPECTROMETRY

    SciTech Connect (OSTI)

    Maxwell, S.

    2010-07-26

    A new method for the determination of {sup 237}Np and Pu isotopes in large soil samples has been developed that provides enhanced uranium removal to facilitate assay by inductively coupled plasma mass spectrometry (ICP-MS). This method allows rapid preconcentration and separation of plutonium and neptunium in large soil samples for the measurement of {sup 237}Np and Pu isotopes by ICP-MS. {sup 238}U can interfere with {sup 239}Pu measurement by ICP-MS as {sup 238}UH{sup +} mass overlap and {sup 237}Np via {sup 238}U peak tailing. The method provides enhanced removal of uranium by separating Pu and Np initially on TEVA Resin, then transferring Pu to DGA resin for additional purification. The decontamination factor for removal of uranium from plutonium for this method is greater than 1 x 10{sup 6}. Alpha spectrometry can also be applied so that the shorter-lived {sup 238}Pu isotope can be measured successfully. {sup 239}Pu, {sup 242}Pu and {sup 237}Np were measured by ICP-MS, while {sup 236}Pu and {sup 238}Pu were measured by alpha spectrometry.

  1. One-dimensional time-dependent fluid model of a very high density low-pressure inductively coupled plasma

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chaplin, Vernon H.; Bellan, Paul M.

    2015-12-28

    A time-dependent two-fluid model has been developed to understand axial variations in the plasma parameters in a very high density (peak ne~ > 5x1019 m–3) argon inductively coupled discharge in a long 1.1 cm radius tube. The model equations are written in 1D, with radial losses to the tube walls accounted for by the inclusion of effective particle and energy sink terms. The ambipolar diffusion equation and electron energy equation are solved to find the electron density ne(z,t) and temperature Te(z,t), and the populations of the neutral argon 4s metastable, 4s resonant, and 4p excited state manifolds are calculated inmore » order to determine the stepwise ionization rate and calculate radiative energy losses. The model has been validated through comparisons with Langmuir probe ion saturation current measurements; close agreement between the simulated and measured axial plasma density profiles and the initial density rise rate at each location was obtained at pAr = 30-60 mTorr. Lastly, we present detailed results from calculations at 60 mTorr, including the time-dependent electron temperature, excited state populations, and energy budget within and downstream of the radiofrequency (RF) antenna.« less

  2. One-dimensional time-dependent fluid model of a very high density low-pressure inductively coupled plasma

    SciTech Connect (OSTI)

    Chaplin, Vernon H.; Bellan, Paul M.

    2015-12-28

    A time-dependent two-fluid model has been developed to understand axial variations in the plasma parameters in a very high density (peak ne~ > 5x1019 m–3) argon inductively coupled discharge in a long 1.1 cm radius tube. The model equations are written in 1D, with radial losses to the tube walls accounted for by the inclusion of effective particle and energy sink terms. The ambipolar diffusion equation and electron energy equation are solved to find the electron density ne(z,t) and temperature Te(z,t), and the populations of the neutral argon 4s metastable, 4s resonant, and 4p excited state manifolds are calculated in order to determine the stepwise ionization rate and calculate radiative energy losses. The model has been validated through comparisons with Langmuir probe ion saturation current measurements; close agreement between the simulated and measured axial plasma density profiles and the initial density rise rate at each location was obtained at pAr = 30-60 mTorr. Lastly, we present detailed results from calculations at 60 mTorr, including the time-dependent electron temperature, excited state populations, and energy budget within and downstream of the radiofrequency (RF) antenna.

  3. Quantitative determination of mass-resolved ion densities in H{sub 2}-Ar inductively coupled radio frequency plasmas

    SciTech Connect (OSTI)

    Sode, M.; Schwarz-Selinger, T.; Jacob, W.

    2013-03-07

    Inductively coupled H{sub 2}-Ar plasmas are characterized by an energy-dispersive mass spectrometer (plasma monitor), a retarding field analyzer, optical emission spectroscopy, and a Langmuir probe. A procedure is presented that allows determining quantitatively the absolute ion densities of Ar{sup +}, H{sup +}, H{sub 2}{sup +}, H{sub 3}{sup +}, and ArH{sup +} from the plasma monitor raw signals. The calibration procedure considers the energy and mass-dependent transmission of the plasma monitor. It is shown that an additional diagnostic like a Langmuir probe or a retarding field analyzer is necessary to derive absolute fluxes with the plasma monitor. The conversion from fluxes into densities is based on a sheath and density profile model. Measurements were conducted for a total gas pressure of 1.0 Pa. For pure H{sub 2} plasmas, the dominant ion is H{sub 3}{sup +}. For mixed H{sub 2}-Ar plasmas, the ArH{sup +} molecular ion is the most dominant ion species in a wide parameter range. The electron density, n{sub e}, is around 3 Multiplication-Sign 10{sup 16} m{sup -3} and the electron temperature, T{sub e}, decreases from 5 to 3 eV with increasing Ar content. The dissociation degree was measured by actinometry. It is around 1.7% nearly independent on Ar content. The gas temperature, estimated by the rotational distribution of the Q-branch lines of the H{sub 2} Fulcher-{alpha} diagonal band (v Prime =v Double-Prime =2) is estimated to (540 {+-} 50) K.

  4. On equivalence of high temperature series expansion and coupling parameter series expansion in thermodynamic perturbation theory of fluids

    SciTech Connect (OSTI)

    Sai Venkata Ramana, A.

    2014-04-21

    The coupling parameter series expansion and the high temperature series expansion in the thermodynamic perturbation theory of fluids are shown to be equivalent if the interaction potential is pairwise additive. As a consequence, for the class of fluids with the potential having a hardcore repulsion, if the hard-sphere fluid is chosen as reference system, the terms of coupling parameter series expansion for radial distribution function, direct correlation function, and Helmholtz free energy follow a scaling law with temperature. The scaling law is confirmed by application to square-well fluids.

  5. RAPID DETERMINATION OF ACTINIDES IN URINE BY INDUCTIVELY-COUPLED PLASMA MASS SPECTROMETRY AND ALPHA SPECTROMETRY: A HYBRID APPROACH

    SciTech Connect (OSTI)

    Maxwell, S.; Jones, V.

    2009-05-27

    A new rapid separation method that allows separation and preconcentration of actinides in urine samples was developed for the measurement of longer lived actinides by inductively coupled plasma mass spectrometry (ICP-MS) and short-lived actinides by alpha spectrometry; a hybrid approach. This method uses stacked extraction chromatography cartridges and vacuum box technology to facilitate rapid separations. Preconcentration, if required, is performed using a streamlined calcium phosphate precipitation. Similar technology has been applied to separate actinides prior to measurement by alpha spectrometry, but this new method has been developed with elution reagents now compatible with ICP-MS as well. Purified solutions are split between ICP-MS and alpha spectrometry so that long- and short-lived actinide isotopes can be measured successfully. The method allows for simultaneous extraction of 24 samples (including QC samples) in less than 3 h. Simultaneous sample preparation can offer significant time savings over sequential sample preparation. For example, sequential sample preparation of 24 samples taking just 15 min each requires 6 h to complete. The simplicity and speed of this new method makes it attractive for radiological emergency response. If preconcentration is applied, the method is applicable to larger sample aliquots for occupational exposures as well. The chemical recoveries are typically greater than 90%, in contrast to other reported methods using flow injection separation techniques for urine samples where plutonium yields were 70-80%. This method allows measurement of both long-lived and short-lived actinide isotopes. 239Pu, 242Pu, 237Np, 243Am, 234U, 235U and 238U were measured by ICP-MS, while 236Pu, 238Pu, 239Pu, 241Am, 243Am and 244Cm were measured by alpha spectrometry. The method can also be adapted so that the separation of uranium isotopes for assay is not required, if uranium assay by direct dilution of the urine sample is preferred instead

  6. Determination of the magnetoelectric coupling coefficient from temperature dependences of the dielectric permittivity for multiferroic ceramics Bi{sub 5}Ti{sub 3}FeO{sub 15}

    SciTech Connect (OSTI)

    Bartkowska, J. A. Dercz, J.

    2013-11-15

    In the multiferroic materials, the dielectric and magnetic properties are closely correlated through the coupling interaction between the ferroelectric and magnetic order. We attempted to determine the magnetoelectric coupling coefficient from the temperature dependences of the dielectric permittivity for multiferroic Bi{sub 5}Ti{sub 3}FeO{sub 15}. Multiferroic ceramics Bi{sub 5}Ti{sub 3}FeO{sub 15} belong to materials of the Aurivillius-type structure. Multiferroic ceramics Bi{sub 5}Ti{sub 3}FeO{sub 15} was synthesized via sintering the Bi{sub 2}O{sub 3} and Fe{sub 2}O{sub 3} mixture and TiO{sub 2} oxides. The precursor material was ground in a high-energy attritorial mill for 5 hours. This material was obtained by a solid-state reaction process at T = 1313 K. We investigated the temperature dependences of the dielectric permittivity for the different frequencies. From the dielectric measurements, we determined the temperature of phase transition of the ferroelectric-to-paraelectric type at about 1013 K. Based on dielectric measurements and theoretical considerations, the values of the magnetoelectric coupling coefficient were specified.

  7. Evidence of resonant mode coupling and the relationship between low and high frequencies in a rapidly rotating a star

    SciTech Connect (OSTI)

    Breger, M.; Montgomery, M. H.

    2014-03-10

    In the theory of resonant mode coupling, the parent and child modes are directly related in frequency and phase. The oscillations present in the fast rotating δ Sct star KIC 8054146 allow us to test the most general and generic aspects of such a theory. The only direct way to separate the parent and coupled (child) modes is to examine the correlations in amplitude variability between the different frequencies. For the dominant family of related frequencies, only a single mode and a triplet are the origins of nine dominant frequency peaks ranging from 2.93 to 66.30 cycles day{sup –1} (as well as dozens of small-amplitude combination modes and a predicted and detected third high-frequency triplet). The mode-coupling model correctly predicts the large amplitude variations of the coupled modes as a product of the amplitudes of the parent modes, while the phase changes are also correctly modeled. This differs from the behavior of 'normal' combination frequencies in that the amplitudes are three orders of magnitude larger and may exceed even the amplitudes of the parent modes. We show that two dominant low frequencies at 5.86 and 2.93 cycles day{sup –1} in the gravity-mode region are not harmonics of each other, and their properties follow those of the almost equidistant high-frequency triplet. We note that the previously puzzling situation of finding two strong peaks in the low-frequency region related by nearly a factor of two in frequency has been seen in other δ Sct stars as well.

  8. Relaxed active space: Fixing tailored-CC with high order coupled cluster. II

    SciTech Connect (OSTI)

    Melnichuk, Ann Bartlett, Rodney J.

    2014-02-14

    Due to the steep increase in computational cost with the inclusion of higher-connected cluster operators in coupled-cluster applications, it is usually not practical to use such methods for larger systems or basis sets without an active space partitioning. This study generates an active space subject to unambiguous statistical criteria to define a space whose size permits treatment at the CCSDT level. The automated scheme makes it unnecessary for the user to judge whether a chosen active space is sufficient to correctly solve the problem. Two demanding applications are presented: twisted ethylene and the transition states for the bicyclo[1,1,0]butane isomerization. As bi-radicals both systems require at least a CCSDT level of theory for quantitative results, for the geometries and energies.

  9. Measurement of the Muon Capture Rate in Hydrogen Gas and Determination of the Proton's Pseudoscalar Coupling g{sub P}

    SciTech Connect (OSTI)

    Andreev, V. A.; Ganzha, V. A.; Kravtsov, P. A.; Krivshich, A. G.; Maev, E. M.; Maev, O. E.; Petrov, G. E.; Schapkin, G. N.; Semenchuk, G. G.; Soroka, M. A.; Vasilyev, A. A.; Vorobyov, A. A.; Vznuzdaev, M. E.; Banks, T. I.; Case, T. A.; Crowe, K. M.; Freedman, S. J.; Gray, F. E.; Lauss, B.; Chitwood, D. B.

    2007-07-20

    The rate of nuclear muon capture by the proton has been measured using a new technique based on a time projection chamber operating in ultraclean, deuterium-depleted hydrogen gas, which is key to avoiding uncertainties from muonic molecule formation. The capture rate from the hyperfine singlet ground state of the {mu}p atom was obtained from the difference between the {mu}{sup -} disappearance rate in hydrogen and the world average for the {mu}{sup +} decay rate, yielding {lambda}{sub S}=725.0{+-}17.4 s{sup -1}, from which the induced pseudoscalar coupling of the nucleon, g{sub P}(q{sup 2}=-0.88m{sub {mu}}{sup 2})=7.3{+-}1.1, is extracted.

  10. RAPID DETERMINATION OF 237 NP AND PU ISOTOPES IN WATER BY INDUCTIVELY COUPLED PLASMA MASS SPECTROMETRY AND ALPHA SPECTROMETRY

    SciTech Connect (OSTI)

    Maxwell, S.; Jones, V.; Culligan, B.; Nichols, S.; Noyes, G.

    2010-06-23

    A new method that allows rapid preconcentration and separation of plutonium and neptunium in water samples was developed for the measurement of {sup 237}Np and Pu isotopes by inductively-coupled plasma mass spectrometry (ICP-MS) and alpha spectrometry; a hybrid approach. {sup 238}U can interfere with {sup 239}Pu measurement by ICP-MS as {sup 238}UH{sup +} mass overlap and {sup 237}Np via peak tailing. The method provide enhanced removal of uranium by separating Pu and Np initially on TEVA Resin, then moving Pu to DGA resin for additional removal of uranium. The decontamination factor for uranium from Pu is almost 100,000 and the decontamination factor for U from Np is greater than 10,000. This method uses stacked extraction chromatography cartridges and vacuum box technology to facilitate rapid separations. Preconcentration is performed using a streamlined calcium phosphate precipitation method. Purified solutions are split between ICP-MS and alpha spectrometry so that long and short-lived Pu isotopes can be measured successfully. The method allows for simultaneous extraction of 20 samples (including QC samples) in 4 to 6 hours, and can also be used for emergency response. {sup 239}Pu, {sup 242}Pu and {sup 237}Np were measured by ICP-MS, while {sup 236}Pu, {sup 238}Pu, and {sup 239}Pu were measured by alpha spectrometry.

  11. Vehicle Technologies Office Merit Review 2014: New High-Energy Electrochemical Couple for Automotive Applications

    Broader source: Energy.gov [DOE]

    Presentation given by [company name] at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about a new high-energy...

  12. Vehicle Technologies Office Merit Review 2015: New High-Energy Electrochemical Couple for Automotive Applications

    Broader source: Energy.gov [DOE]

    Presentation given by Argonne National Laboratory at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about new high-energy...

  13. High performance AlScN thin film based surface acoustic wave devices with large electromechanical coupling coefficient

    SciTech Connect (OSTI)

    Wang, Wenbo; He, Xingli; Ye, Zhi E-mail: jl2@bolton.ac.uk; Wang, Xiaozhi; Mayrhofer, Patrick M.; Gillinger, Manuel; Bittner, Achim; Schmid, Ulrich

    2014-09-29

    AlN and AlScN thin films with 27% scandium (Sc) were synthesized by DC magnetron sputtering deposition and used to fabricate surface acoustic wave (SAW) devices. Compared with AlN-based devices, the AlScN SAW devices exhibit much better transmission properties. Scandium doping results in electromechanical coupling coefficient, K{sup 2}, in the range of 2.0% ∼ 2.2% for a wide normalized thickness range, more than a 300% increase compared to that of AlN-based SAW devices, thus demonstrating the potential applications of AlScN in high frequency resonators, sensors, and high efficiency energy harvesting devices. The coupling coefficients of the present AlScN based SAW devices are much higher than that of the theoretical calculation based on some assumptions for AlScN piezoelectric material properties, implying there is a need for in-depth investigations on the material properties of AlScN.

  14. Determination of total and isotopic uranium by inductively coupled plasma-mass spectrometry at the Fernald Environmental Management Project

    SciTech Connect (OSTI)

    Miller, F.L.; Bolin, R.N.; Feller, M.T.; Danahy, R.J.

    1995-04-01

    At the Fernald Environmental Management Project (FEMP) in southwestern Ohio, ICP-mass spectrometry (ICP-MS), with sample introduction by peristaltic pumping, is used to determine total and isotopic uranium (U-234, U-235, U-236 and U-238) in soil samples. These analyses are conducted in support of the environmental cleanup of the FEMP site. Various aspects of the sample preparation and instrumental analysis will be discussed. Initial sample preparation consists of oven drying to determine moisture content, and grinding and rolling to homogenize the sample. This is followed by a nitric/hydrofluoric acid digestion to bring the uranium in the sample into solution. Bismuth is added to the sample prior to digestion to monitor for losses. The total uranium (U-238) content of this solution and the U{sup 235}/U{sup 238} ratio are measured on the first pass through the ICP-MS. To determine the concentration of the less abundant U{sup 234} and U{sup 236} isotopes, the digestate is further concentrated by using Eichrom TRU-Spec extraction columns before the second pass through the ICP-MS. Quality controls for both the sample preparation and instrumental protocols will also be discussed. Finally, an explanation of the calculations used to report the data in either weight percent or activity units will be given.

  15. A novel assay method for the trace determination of Th and U in copper and lead using inductively coupled plasma mass spectrometry

    SciTech Connect (OSTI)

    LaFerriere, Brian D.; Maiti, Tapas C.; Arnquist, Isaac J.; Hoppe, Eric W.

    2015-03-01

    This study describes a novel sample preparation and assay method developed in support of the MAJORANA DEMONSTRATOR experiment for the determination of thorium and uranium levels in copper and lead shielding components. Meticulously clean sample preparation methods combined with novel anion exchange separations for analyte pre-concentration and matrix removal were developed. Quantification was performed by inductively coupled plasma mass spectrometry. Detection limits of 0.0084 pg 232Th/g and 0.0106 pg 238U/g were determined for copper, while detection limits of 0.23 pg 232Th/g and 0.46 pg 238U/g were achieved for lead. These methods allow the Majorana Collaboration to accurately assay detector components and ensure that the experiment’s stringent radiopurity requirements are met.

  16. Application of Gamma code coupled with turbomachinery models for high temperature gas-cooled reactors

    SciTech Connect (OSTI)

    Chang Oh

    2008-02-01

    The very high-temperature gas-cooled reactor (VHTR) is envisioned as a single- or dual-purpose reactor for electricity and hydrogen generation. The concept has average coolant temperatures above 9000C and operational fuel temperatures above 12500C. The concept provides the potential for increased energy conversion efficiency and for high-temperature process heat application in addition to power generation. While all the High Temperature Gas Cooled Reactor (HTGR) concepts have sufficiently high temperature to support process heat applications, such as coal gasification, desalination or cogenerative processes, the VHTR’s higher temperatures allow broader applications, including thermochemical hydrogen production. However, the very high temperatures of this reactor concept can be detrimental to safety if a loss-ofcoolant accident (LOCA) occurs. Following the loss of coolant through the break and coolant depressurization, air will enter the core through the break by molecular diffusion and ultimately by natural convection, leading to oxidation of the in-core graphite structure and fuel. The oxidation will accelerate heatup of the reactor core and the release of a toxic gas, CO, and fission products. Thus, without any effective countermeasures, a pipe break may lead to significant fuel damage and fission product release. Prior to the start of this Korean/United States collaboration, no computer codes were available that had been sufficiently developed and validated to reliably simulate a LOCA in the VHTR. Therefore, we have worked for the past three years on developing and validating advanced computational methods for simulating LOCAs in a VHTR. GAMMA code is being developed to implement turbomachinery models in the power conversion unit (PCU) and ultimately models associated with the hydrogen plant. Some preliminary results will be described in this paper.

  17. Determination

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Determinants of Household Use of Selected Energy Star Appliances May 2016 Independent Statistics & Analysis www.eia.gov U.S. Department of Energy Washington, DC 20585 U.S. Energy Information Administration | Determinants of Household Use of Selected Energy Star Appliances i This report was prepared by the U.S. Energy Information Administration (EIA), the statistical and analytical agency within the U.S. Department of Energy. By law, EIA's data, analyses, and forecasts are independent of

  18. Coupled high fidelity thermal hydraulics and neutronics for reactor safety simulations

    SciTech Connect (OSTI)

    Vincent A. Mousseau; Hongbin Zhang; Haihua Zhao

    2008-09-01

    This work is a continuation of previous work on the importance of accuracy in the simulation of nuclear reactor safety transients. This work is qualitative in nature and future work will be more quantitative. The focus of this work will be on a simplified single phase nuclear reactor primary. The transient of interest investigates the importance of accuracy related to passive (inherent) safety systems. The transient run here will be an Unprotected Loss of Flow (ULOF) transient. Here the coolant pump is turned off and the unSCRAMed reactor transitions from forced to free convection (Natural circulation). Results will be presented that show the difference that the first order in time truncation physics makes on the transient. The purpose of this document is to illuminate a possible problem in traditional reactor simulation approaches. Detailed studies need to be done on each simulation code for each transient analyzed to determine if the first order truncation physics plays an important role.

  19. Highly frustrated spin-lattice models of magnetism and their quantum phase transitions: A microscopic treatment via the coupled cluster method

    SciTech Connect (OSTI)

    Bishop, R. F.; Li, P. H. Y.; Campbell, C. E.

    2014-10-15

    We outline how the coupled cluster method of microscopic quantum many-body theory can be utilized in practice to give highly accurate results for the ground-state properties of a wide variety of highly frustrated and strongly correlated spin-lattice models of interest in quantum magnetism, including their quantum phase transitions. The method itself is described, and it is shown how it may be implemented in practice to high orders in a systematically improvable hierarchy of (so-called LSUBm) approximations, by the use of computer-algebraic techniques. The method works from the outset in the thermodynamic limit of an infinite lattice at all levels of approximation, and it is shown both how the 'raw' LSUBm results are themselves generally excellent in the sense that they converge rapidly, and how they may accurately be extrapolated to the exact limit, m ? ?, of the truncation index m, which denotes the only approximation made. All of this is illustrated via a specific application to a two-dimensional, frustrated, spin-half J{sub 1}{sup XXZ}?J{sub 2}{sup XXZ} model on a honeycomb lattice with nearest-neighbor and next-nearest-neighbor interactions with exchange couplings J{sub 1} > 0 and J{sub 2} ? ?J{sub 1} > 0, respectively, where both interactions are of the same anisotropic XXZ type. We show how the method can be used to determine the entire zero-temperature ground-state phase diagram of the model in the range 0 ? ? ? 1 of the frustration parameter and 0 ? ? ? 1 of the spin-space anisotropy parameter. In particular, we identify a candidate quantum spin-liquid region in the phase space.

  20. Thermal-Hydraulic Analyses of Heat Transfer Fluid Requirements and Characteristics for Coupling A Hydrogen Production Plant to a High-Temperature Nuclear Reactor

    SciTech Connect (OSTI)

    C. B. Davis; C. H. Oh; R. B. Barner; D. F. Wilson

    2005-06-01

    The Department of Energy is investigating the use of high-temperature nuclear reactors to produce hydrogen using either thermochemical cycles or high-temperature electrolysis. Although the hydrogen production processes are in an early stage of development, coupling either of these processes to the hightemperature reactor requires both efficient heat transfer and adequate separation of the facilities to assure that off-normal events in the production facility do not impact the nuclear power plant. An intermediate heat transport loop will be required to separate the operations and safety functions of the nuclear and hydrogen plants. A next generation high-temperature reactor could be envisioned as a single-purpose facility that produces hydrogen or a dual-purpose facility that produces hydrogen and electricity. Early plants, such as the proposed Next Generation Nuclear Plant, may be dual-purpose facilities that demonstrate both hydrogen and efficient electrical generation. Later plants could be single-purpose facilities. At this stage of development, both single- and dual-purpose facilities need to be understood. Seven possible configurations for a system that transfers heat between the nuclear reactor and the hydrogen and/or electrical generation plants were identified. These configurations included both direct and indirect cycles for the production of electricity. Both helium and liquid salts were considered as the working fluid in the intermediate heat transport loop. Methods were developed to perform thermalhydraulic and cycle-efficiency evaluations of the different configurations and coolants. The thermalhydraulic evaluations estimated the sizes of various components in the intermediate heat transport loop for the different configurations. The relative sizes of components provide a relative indication of the capital cost associated with the various configurations. Estimates of the overall cycle efficiency of the various configurations were also determined. The

  1. ISSUANCE 2015-12-02: Energy Conservation Program: Energy Conservation Standards for High-Intensity Discharge Lamps, Final Determination

    Broader source: Energy.gov [DOE]

    Energy Conservation Program: Energy Conservation Standards for High-Intensity Discharge Lamps, Final Determination

  2. High-resolution rovibrational study of the Coriolis-coupled nu(12) and nu(15) modes of [1.1.1]propellane

    SciTech Connect (OSTI)

    Kirkpatrick, Robynne W.; Masiello, Tony; Jariyasopit, Narumol; Nibler, Joseph W.; Maki, Arthur G.; Blake, Thomas A.; Weber, Alfons

    2009-01-02

    Infrared spectra of the small strained cage molecule [1.1.1]propellane have been obtained at high resolution (0.0015 cm-1) and the J and K, l rovibrational structure has been resolved for the first time. We recently used combination-differences to obtain ground state parameters for propellane; over 4,100 differences from five fundamental and four combination bands were used in this process. The combination-difference approach eliminated errors due to localized perturbations in the upper state levels of the transitions and gave well-determined ground state parameters. In the current work, these ground state parameters were used in a determination of the upper state parameters for the v12(e?) perpendicular and v15(a2?) parallel bands. Over 4000 infrared transitions were fitted for each band, with J, K values ranging up to 71, 51 and 92, 90 respectively. While the transition frequencies for both bands can be fit nicely using separate analyses for each band, the strong intensity perturbations observed in the weaker v12 band indicated that Coriolis coupling between the two modes was significant and should be included. Due to correlations with other parameters, the Coriolis coupling parameter Zy15z,12x for the v15 and v12 interaction is poorly determined by a transition frequency fit alone. However, by combining the frequency fit with a fit of experimental intensities, a value of -0.42 was obtained, quite close to that predicted from the ab initio calculation (-0.44). This intensity fit also yielded a (dz/dQ15z)/(dx/dQ12x) dipole derivative ratio of 36.5, in reasonable agreement with a value of 29.2 predicted by Gaussian ab initio density functional calculations using a cc-pVTZ basis. This ratio is unusually high due to large charge movement as the novel central Caxial-Caxial bond is displaced along the symmetry axis of the molecule for the v15 mode.

  3. Method and apparatus for digitally based high speed x-ray spectrometer for direct coupled use with continuous discharge preamplifiers

    DOE Patents [OSTI]

    Warburton, W.K.

    1998-06-30

    A high speed, digitally based, signal processing system is disclosed which accepts directly coupled input data from a detector with a continuous discharge type preamplifier and produces a spectral analysis of the x-rays illuminating the detector. The system`s principal elements are an analog signal conditioning section, a combinatorial logic section which implements digital triangular filtering and pileup inspection, and a microprocessor which accepts values captured by the logic section and uses them to compute x-ray energy values. Operating without pole-zero correction, the system achieves high resolution by capturing, in conjunction with each peak value from the digital filter, an associated value of the unfiltered signal, and using this latter signal to correct the former for errors which arise from its local slope terms. This correction greatly reduces both energy resolution degradation and peak centroid shifting in the output spectrum as a function of input count rate. When the noise of this correction is excessive, a modification allows two filtered averages of the signal to be captured and a corrected peak amplitude computed therefrom. 14 figs.

  4. Method and apparatus for digitally based high speed x-ray spectrometer for direct coupled use with continuous discharge preamplifiers

    DOE Patents [OSTI]

    Warburton, William K.

    1998-01-01

    A high speed, digitally based, signal processing system which accepts directly coupled input data from a detector with a continuous discharge type preamplifier and produces a spectral analysis of the x-rays illuminating the detector. The system's principal elements are an analog signal conditioning section, a combinatorial logic section which implements digital triangular filtering and pileup inspection, and a microprocessor which accepts values captured by the logic section and uses them to compute x-ray energy values. Operating without pole-zero correction, the system achieves high resolution by capturing, in conjunction with each peak value from the digital filter, an associated value of the unfiltered signal, and using this latter signal to correct the former for errors which arise from its local slope terms. This correction greatly reduces both energy resolution degradation and peak centroid shifting in the output spectrum as a function of input count rate. When the noise of this correction is excessive, a modification allows two filtered averages of the signal to be captured and a corrected peak amplitude computed therefrom.

  5. Recent Progress in the Structure Determination of GPCRs, a Membrane Protein Family with High Potential as Pharmaceutical Targets

    SciTech Connect (OSTI)

    Cherezov, Vadim; Abola, Enrique; Stevens, Raymond C.

    2015-11-30

    G protein-coupled receptors (GPCRs) constitute a highly diverse and ubiquitous family of integral membrane proteins, transmitting signals inside the cells in response to an assortment of disparate extra-cellular stimuli. Their strategic location on the cell surface and their involvement in crucial cellular and physiological processes turn these receptors into highly important pharmaceutical targets. Recent technological developments aimed at stabilization and crystallization of these receptors have led to significant breakthroughs in GPCR structure determination efforts. One of the successful approaches involved receptor stabilization with the help of a fusion partner combined with crystallization in lipidic cubic phase (LCP). The success of using an LCP matrix for crystallization is generally attributed to the creation of a more native, membrane-like stabilizing environment for GPCRs just prior to nucleation and to the formation of type I crystal lattices, thus generating highly ordered and strongly diffracting crystals. Here they describe protocols for reconstituting purified GPCRs in LCP, performing pre-crystallization assays, setting up crystallization trials in manual mode, detecting crystallization hits, optimizing crystallization conditions, harvesting, and collecting crystallographic data. The protocols provide a sensible framework for approaching crystallization of stabilized GPCRs in LCP, however, as in any crystallization experiment, extensive screening and optimization of crystallization conditions as well as optimization of protein construct and purification steps are required. The process remains risky and these protocols do not necessarily guarantee success.

  6. Spin-lattice coupling in uranium dioxide probed by magnetostriction measurements at high magnetic fields (P08358-E001-PF)

    SciTech Connect (OSTI)

    Gofryk, K.; Jaime, M.

    2014-12-01

    Our preliminary magnetostriction measurements have already shown a strong interplay of lattice dynamic and magnetism in both antiferromagnetic and paramagnetic states, and give unambiguous evidence of strong spin- phonon coupling in uranium dioxide. Further studies are planned to address the puzzling behavior of UO2 in magnetic and paramagnetic states and details of the spin-phonon coupling.

  7. Optimization of a coupling scheme between MCNP5 and SUBCHANFLOW for high fidelity modeling of LWR reactors

    SciTech Connect (OSTI)

    Ivanov, A.; Sanchez, V.; Imke, U.; Ivanov, K.

    2012-07-01

    In order to increase the accuracy and the degree of spatial resolution of core design studies, coupled Three-Dimensional (3D) neutronics (deterministic and Monte Carlo) and 3D thermal hydraulics (CFD and sub-channel) codes are being developed worldwide. In this paper the optimization of a coupling between MCNP5 code and an in-house development thermal-hydraulics code SUBCHANFLOW is presented. Various improvements of the coupling methodology are presented. With the help of novel interpolation tool a consistent methodology for the preparation of thermal scattering data library have been developed, ensuring that inelastic scattering from bound nuclei is treated at the correct moderator temperature. Trough the utilization of a hybrid coupling with discrete energy Monte-Carlo code KENO a methodology for acceleration of the coupled calculation is being demonstrated. In this approach an additional coupling between KENO and SUBCHANFLOW was developed, the converged results of which are used as initial conditions for the MCNP-SUBCHANFLOW coupling. Acceleration of fission source distribution convergence, by sampling fission source distribution from the power distribution obtained by KENO is also demonstrated. (authors)

  8. Kinetic Characterization of Strongly Coupled Systems

    SciTech Connect (OSTI)

    Knapek, C. A.; Ivlev, A. V.; Klumov, B. A.; Morfill, G. E.; Samsonov, D.

    2007-01-05

    We propose a simple method to determine the local coupling strength {gamma} experimentally, by linking the individual particle dynamics with the local density and crystal structure of a 2D plasma crystal. By measuring particle trajectories with high spatial and temporal resolution we obtain the first maps of {gamma} and temperature at individual particle resolution. We employ numerical simulations to test this new method, and discuss the implications to characterize strongly coupled systems.

  9. Thermoacoustic couple

    DOE Patents [OSTI]

    Wheatley, J.C.; Swift, G.W.; Migliori, A.

    1983-10-04

    An apparatus and method for determining acoustic power density level and its direction in a fluid using a single sensor are disclosed. The preferred embodiment of the apparatus, which is termed a thermoacoustic couple, consists of a stack of thin, spaced apart polymeric plates, selected ones of which include multiple bimetallic thermocouple junctions positioned along opposite end edges thereof. The thermocouple junctions are connected in series in the nature of a thermopile, and are arranged so as to be responsive to small temperature differences between the opposite edges of the plates. The magnitude of the temperature difference, as represented by the magnitude of the electrical potential difference generated by the thermopile, is found to be directly related to the level of acoustic power density in the gas.

  10. High-precision determination of low-energy effective parameters for a two-dimensional Heisenberg quantum antiferromagnet

    SciTech Connect (OSTI)

    Jiang, F.-J.; Wiese, U.-J.

    2011-04-15

    The two-dimensional (2D) spin-(1/2) Heisenberg antiferromagnet with exchange coupling J is investigated on a periodic square lattice of spacing a at very small temperatures using the loop-cluster algorithm. Monte Carlo data for the staggered and uniform susceptibilities are compared with analytic results obtained in the systematic low-energy effective field theory for the staggered magnetization order parameter. The low-energy parameters of the effective theory, i.e., the staggered magnetization density M{sub s}=0.307 43(1)/a{sup 2}, the spin stiffness {rho}{sub s}=0.180 81(11)J, and the spin wave velocity c=1.6586(3)Ja, are determined with very high precision. Our study may serve as a test case for the comparison of lattice quantum chromodynamics Monte Carlo data with analytic predictions of the chiral effective theory for pions and nucleons, which is vital for the quantitative understanding of the strong interaction at low energies.

  11. Couples Magnetic and Structural Transitions in High-Purity Dy and Gd5SbxGe4-x

    SciTech Connect (OSTI)

    Alexander S. Chernyshov

    2006-08-09

    Magnetic materials exhibiting magnetic phase transitions simultaneously with structural rearrangements of their crystal lattices hold a promise for numerous applications including magnetic refrigeration, magnetomechanical devices and sensors. We undertook a detailed study of a single crystal of dysprosium metal, which is a classical example of a system where magnetic and crystallographic sublattices can be either coupled or decoupled from one another. Magnetocaloric effect, magnetization, ac magnetic susceptibility, and heat capacity of high purity single crystals of dysprosium have been investigated over broad temperature and magnetic field intervals with the magnetic field vector parallel to either the a- or c-axes of the crystal. Notable differences in the behavior of the physical properties when compared to Dy samples studied in the past have been observed between 110 K and 125 K, and between 178 K and {approx}210 K. A plausible mechanism based on the formation of antiferromagnetic clusters in the impure Dy has been suggested in order to explain the reduction of the magnetocaloric effect in the vicinity of the Neel point. Experimental and theoretical investigations of the influence of commensurability effects on the magnetic phase diagram and the value of the magnetocaloric effect have been conducted. The presence of newly found anomalies in the physical properties has been considered as evidence of previously unreported states of Dy. The refined magnetic phase diagram of dysprosium with the magnetic field vector parallel to the a-axis of a crystal has been constructed and discussed. The magnetic and crystallographic properties of Gd{sub 5}Sb{sub x}Ge{sub 4-x} pseudo-binary system were studied by x-ray diffraction (at room temperature), heat capacity, ac-magnetic susceptibility, and magnetization in the temperature interval 5-320 K in magnetic fields up to 100 kOe. The magnetic properties of three composition (x = 0.5, 1,2) were examined in detail. The Gd{sub 5

  12. Physics and dynamics coupling across scales in the next generation CESM: Meeting the challenge of high resolution. Final report

    SciTech Connect (OSTI)

    Larson, Vincent E.

    2015-02-21

    This is a final report for a SciDAC grant supported by BER. The project implemented a novel technique for coupling small-scale dynamics and microphysics into a community climate model. The technique uses subcolumns that are sampled in Monte Carlo fashion from a distribution of subgrid variability. The resulting global simulations show several improvements over the status quo.

  13. A miniaturized, high frequency mechanical scanner for high speed atomic force microscope using suspension on dynamically determined points

    SciTech Connect (OSTI)

    Herfst, Rodolf; Dekker, Bert; Witvoet, Gert; Crowcombe, Will; Lange, Dorus de; Sadeghian, Hamed E-mail: h.sadeghianmarnani@tudelft.nl

    2015-11-15

    One of the major limitations in the speed of the atomic force microscope (AFM) is the bandwidth of the mechanical scanning stage, especially in the vertical (z) direction. According to the design principles of “light and stiff” and “static determinacy,” the bandwidth of the mechanical scanner is limited by the first eigenfrequency of the AFM head in case of tip scanning and by the sample stage in terms of sample scanning. Due to stringent requirements of the system, simply pushing the first eigenfrequency to an ever higher value has reached its limitation. We have developed a miniaturized, high speed AFM scanner in which the dynamics of the z-scanning stage are made insensitive to its surrounding dynamics via suspension of it on specific dynamically determined points. This resulted in a mechanical bandwidth as high as that of the z-actuator (50 kHz) while remaining insensitive to the dynamics of its base and surroundings. The scanner allows a practical z scan range of 2.1 μm. We have demonstrated the applicability of the scanner to the high speed scanning of nanostructures.

  14. High-pressure behavior of TiO[subscript 2] as determined by experiment and theory

    SciTech Connect (OSTI)

    Al-Khatatbeh, Yahya; Lee, Kanani K.M.; Kiefer, Boris; New Mexico State

    2009-06-30

    Using high-resolution synchrotron x-ray powder diffraction we have investigated the structural phase transitions and equations of state of titanium dioxide (TiO{sub 2}) under high pressure before and after heating at high temperature. The phase sequence we observe experimentally is as follows: rutile (RT){yields}columbite (CB){yields}baddeleyite (MI){yields}orthorhombic I (OI){yields}orthorhombic II (OII). The equations of state as determined from our experiments are consistent with previous measurements and computations. The only exception is the OII phase for which we find a significantly lower room-pressure bulk modulus (K{sup 0}) of 312 ({+-}34) GPa and room-pressure volume (V{sub 0}) of 25.28 ({+-}0.35) {angstrom}{sup 3} as compared to previous experiments. We find that the volume decreases across the OI{yields}OII phase transition at room temperature by -8.3%, in very good agreement with our static first-principles calculations which predict volume changes of 8.2% and 7.6% for local-density approximation and generalized gradient approximation, respectively. This volume collapse is significantly higher than previously determined but consistent with the volume decrease observed in other dioxides across this transition.

  15. High resolution biomedical imaging system with direct detection of x-rays via a charge coupled device

    DOE Patents [OSTI]

    Atac, Muzaffer; McKay, Timothy A.

    1998-01-01

    An imaging system is provided for direct detection of x-rays from an irradiated biological tissue. The imaging system includes an energy source for emitting x-rays toward the biological tissue and a charge coupled device (CCD) located immediately adjacent the biological tissue and arranged transverse to the direction of irradiation along which the x-rays travel. The CCD directly receives and detects the x-rays after passing through the biological tissue. The CCD is divided into a matrix of cells, each of which individually stores a count of x-rays directly detected by the cell. The imaging system further includes a pattern generator electrically coupled to the CCD for reading a count from each cell. A display device is provided for displaying an image representative of the count read by the pattern generator from the cells of the CCD.

  16. High resolution biomedical imaging system with direct detection of x-rays via a charge coupled device

    DOE Patents [OSTI]

    Atac, M.; McKay, T.A.

    1998-04-21

    An imaging system is provided for direct detection of x-rays from an irradiated biological tissue. The imaging system includes an energy source for emitting x-rays toward the biological tissue and a charge coupled device (CCD) located immediately adjacent the biological tissue and arranged transverse to the direction of irradiation along which the x-rays travel. The CCD directly receives and detects the x-rays after passing through the biological tissue. The CCD is divided into a matrix of cells, each of which individually stores a count of x-rays directly detected by the cell. The imaging system further includes a pattern generator electrically coupled to the CCD for reading a count from each cell. A display device is provided for displaying an image representative of the count read by the pattern generator from the cells of the CCD. 13 figs.

  17. Precise determination of the mass of the Higgs boson and tests of compatibility of its couplings with the standard model predictions using proton collisions at 7 and 8 TeV

    SciTech Connect (OSTI)

    Khachatryan, Vardan

    2015-05-14

    Properties of the Higgs boson with mass near 125 GeV are measured in proton-proton collisions with the CMS experiment at the LHC. Comprehensive sets of production and decay measurements are combined. The decay channels include ??, ZZ, WW, ??, bb, and ?? pairs. The data samples were collected in 2011 and 2012 and correspond to integrated luminosities of up to 5.1 fb? at 7 TeV and up to 19.7 fb? at 8 TeV. From the high-resolution ?? and ZZ channels, the mass of the Higgs boson is determined to be 125.02\\,+0.26-0.27(stat)+0.14-0.15(syst) GeV. For this mass value, the event yields obtained in the different analyses tagging specific decay channels and production mechanisms are consistent with those expected for the standard model Higgs boson. The combined best-fit signal relative to the standard model expectation is 1.00 0.09 (stat), +0.08 -0.07 (theo) 0.07 (syst) at the measured mass. The couplings of the Higgs boson are probed for deviations in magnitude from the standard model predictions in multiple ways, including searches for invisible and undetected decays. No significant deviations are found.

  18. Precise determination of the mass of the Higgs boson and tests of compatibility of its couplings with the standard model predictions using proton collisions at 7 and 8 $$\\,\\text {TeV}$$

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Khachatryan, Vardan

    2015-05-14

    Properties of the Higgs boson with mass near 125GeV are measured in proton-proton collisions with the CMS experiment at the LHC. Comprehensive sets of production and decay measurements are combined. The decay channels include γγ, ZZ, WW, ττ, bb, and μμ pairs. The data samples were collected in 2011 and 2012 and correspond to integrated luminosities of up to 5.1fb-1 at 7TeV and up to 19.7fb-1 at 8TeV. From the high-resolution γγ and ZZ channels, the mass of the Higgs boson is determined to be 125.02+0.26–0.27 (stat) +0.14–0.15 (syst) GeV. For this mass value, the event yields obtained in themore » different analyses tagging specific decay channels and production mechanisms are consistent with those expected for the standard model Higgs boson. The combined best-fit signal relative to the standard model expectation is 1.00 ± 0.09(stat)+0.08–0.07 (theo) ± 0.07(syst) at the measured mass. The couplings of the Higgs boson are probed for deviations in magnitude from the standard model predictions in multiple ways, including searches for invisible and undetected decays. As a result, no significant deviations are found.« less

  19. Precise determination of the mass of the Higgs boson and tests of compatibility of its couplings with the standard model predictions using proton collisions at 7 and 8 TeV

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Khachatryan, Vardan

    2015-05-14

    Properties of the Higgs boson with mass near 125 GeV are measured in proton-proton collisions with the CMS experiment at the LHC. Comprehensive sets of production and decay measurements are combined. The decay channels include ??, ZZ, WW, ??, bb, and ?? pairs. The data samples were collected in 2011 and 2012 and correspond to integrated luminosities of up to 5.1 fb? at 7 TeV and up to 19.7 fb? at 8 TeV. From the high-resolution ?? and ZZ channels, the mass of the Higgs boson is determined to be 125.02\\,+0.26-0.27(stat)+0.14-0.15(syst) GeV. For this mass value, the event yields obtainedmorein the different analyses tagging specific decay channels and production mechanisms are consistent with those expected for the standard model Higgs boson. The combined best-fit signal relative to the standard model expectation is 1.00 0.09 (stat), +0.08 -0.07 (theo) 0.07 (syst) at the measured mass. The couplings of the Higgs boson are probed for deviations in magnitude from the standard model predictions in multiple ways, including searches for invisible and undetected decays. No significant deviations are found.less

  20. Determinants of the Price of High-Tech Metals: An Event Study

    SciTech Connect (OSTI)

    Wanner, Markus Gaugler, Tobias; Gleich, Benedikt; Rathgeber, Andreas

    2015-06-15

    The growing demand for high-tech products has resulted in strong growth in demand for certain minor metals. In combination with production concentrated in China, this caused strong and unpredicted price movements in recent years. As a result, manufacturing companies have to cope with additional risks. However, the detailed reasons for the price development are only partially understood. Therefore, we analyzed empirically which determinants can be assigned to price movements and performed an event study on the high-tech metals neodymium, indium, and gallium. Based on our dataset of news items, we were able to find coinciding events to almost 90% of all price jumps (recall). We showed that if any information about these events occurred with a probability of over 50% there would also be a price jump within 10 days (precision). However, the classical set of price determinants has to be extended for these specific markets, as we found unorthodox factors like holidays or weather that may be indicators for price movements. Therefore, we hope that our study supports industry for instance in performing more informed short-term planning of metals purchasing based on information about specific events.

  1. Accurate determination of Curium and Californium isotopic ratios by inductively coupled plasma quadrupole mass spectrometry (ICP-QMS) in 248Cm samples for transmutation studies

    SciTech Connect (OSTI)

    Gourgiotis, A.; Isnard, H.; Aubert, M.; Dupont, E.; AlMahamid, I.; Cassette, P.; Panebianco, S.; Letourneau, A.; Chartier, F.; Tian, G.; Rao, L.; Lukens, W.

    2011-02-01

    The French Atomic Energy Commission has carried out several experiments including the mini-INCA (INcineration of Actinides) project for the study of minor-actinide transmutation processes in high intensity thermal neutron fluxes, in view of proposing solutions to reduce the radiotoxicity of long-lived nuclear wastes. In this context, a Cm sample enriched in {sup 248}Cm ({approx}97 %) was irradiated in thermal neutron flux at the High Flux Reactor (HFR) of the Laue-Langevin Institute (ILL). This work describes a quadrupole ICP-MS (ICP-QMS) analytical procedure for precise and accurate isotopic composition determination of Cm before sample irradiation and of Cm and Cf after sample irradiation. The factors that affect the accuracy and reproducibility of isotopic ratio measurements by ICP-QMS, such as peak centre correction, detector dead time, mass bias, abundance sensitivity and hydrides formation, instrumental background, and memory blank were carefully evaluated and corrected. Uncertainties of the isotopic ratios, taking into account internal precision of isotope ratio measurements, peak tailing, and hydrides formations ranged from 0.3% to 1.3%. This uncertainties range is quite acceptable for the nuclear data to be used in transmutation studies.

  2. Helix coupling

    DOE Patents [OSTI]

    Ginell, William S.

    1989-04-25

    A coupling for connecting helix members in series, which consists of a pair of U-shaped elements, one of which is attached to each helix end with the "U" sections of the elements interlocked. The coupling is particularly beneficial for interconnecting helical Nitinol elements utilized in thermal actuators or engines. Each coupling half is attached to the associated helix at two points, thereby providing axial load while being easily removed from the helix, and reusable.

  3. Helix coupling

    DOE Patents [OSTI]

    Ginell, W.S.

    1982-03-17

    A coupling for connecting helix members in series, which consists of a pair of U-shaped elements, one of which is attached to each helix end with the U sections of the elements interlocked. The coupling is particularly beneficial for interconnecting helical Nitinol elements utilized in thermal actuators or engines. Each coupling half is attached to the associated helix at two points, thereby providing axial load while being easily removed from the helix, and reusable.

  4. Translation-coupling systems

    DOE Patents [OSTI]

    Pfleger, Brian; Mendez-Perez, Daniel

    2013-11-05

    Disclosed are systems and methods for coupling translation of a target gene to a detectable response gene. A version of the invention includes a translation-coupling cassette. The translation-coupling cassette includes a target gene, a response gene, a response-gene translation control element, and a secondary structure-forming sequence that reversibly forms a secondary structure masking the response-gene translation control element. Masking of the response-gene translation control element inhibits translation of the response gene. Full translation of the target gene results in unfolding of the secondary structure and consequent translation of the response gene. Translation of the target gene is determined by detecting presence of the response-gene protein product. The invention further includes RNA transcripts of the translation-coupling cassettes, vectors comprising the translation-coupling cassettes, hosts comprising the translation-coupling cassettes, methods of using the translation-coupling cassettes, and gene products produced with the translation-coupling cassettes.

  5. Translation-coupling systems

    DOE Patents [OSTI]

    Pfleger, Brian; Mendez-Perez, Daniel

    2015-05-19

    Disclosed are systems and methods for coupling translation of a target gene to a detectable response gene. A version of the invention includes a translation-coupling cassette. The translation-coupling cassette includes a target gene, a response gene, a response-gene translation control element, and a secondary structure-forming sequence that reversibly forms a secondary structure masking the response-gene translation control element. Masking of the response-gene translation control element inhibits translation of the response gene. Full translation of the target gene results in unfolding of the secondary structure and consequent translation of the response gene. Translation of the target gene is determined by detecting presence of the response-gene protein product. The invention further includes RNA transcripts of the translation-coupling cassettes, vectors comprising the translation-coupling cassettes, hosts comprising the translation-coupling cassettes, methods of using the translation-coupling cassettes, and gene products produced with the translation-coupling cassettes.

  6. Structure of Low-Lying Excited States of Guanine in DNA and Solution: Combined Molecular Mechanics and High-Level Coupled Cluster Studies

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kowalski, Karol; Valiev, Marat

    2007-01-01

    High-level ab-initio equation-of-motion coupled-cluster methods with singles, doubles, and noniterative triples are used, in conjunction with the combined quantum mechanical molecular mechanics approach, to investigate the structure of low-lying excited states of the guanine base in DNA and solvated environments. Our results indicate that while the excitation energy of the first excited state is barely changed compared to its gas-phase counterpart, the excitation energy of the second excited state is blue-shifted by 0.24 eV.

  7. The model coupling toolkit.

    SciTech Connect (OSTI)

    Larson, J. W.; Jacob, R. L.; Foster, I.; Guo, J.

    2001-04-13

    The advent of coupled earth system models has raised an important question in parallel computing: What is the most effective method for coupling many parallel models to form a high-performance coupled modeling system? We present our solution to this problem--The Model Coupling Toolkit (MCT). We explain how our effort to construct the Next-Generation Coupler for NCAR Community Climate System Model motivated us to create this toolkit. We describe in detail the conceptual design of the MCT and explain its usage in constructing parallel coupled models. We present preliminary performance results for the toolkit's parallel data transfer facilities. Finally, we outline an agenda for future development of the MCT.

  8. Oxidative homo-coupling reactions of aryl boronic acids using a porous copper metal-organic framework as a highly efficient heterogeneous catalyst

    DOE Patents [OSTI]

    Yaghi, Omar M.; Czaja, Alexander U.; Wang, Bo; Lu, Zheng

    2015-06-02

    The disclosure provides methods for the use of open metal frameworks to catalyze coupling reactions.

  9. TRITIUM PERMEATION AND TRANSPORT IN THE GASOLINE PRODUCTION SYSTEM COUPLED WITH HIGH TEMPERATURE GAS-COOLED REACTORS (HTGRS)

    SciTech Connect (OSTI)

    Chang H. Oh; Eung S. Kim; Mike Patterson

    2011-05-01

    This paper describes scoping analyses on tritium behaviors in the HTGR-integrated gasoline production system, which is based on a methanol-to-gasoline (MTG) plant. In this system, the HTGR transfers heat and electricity to the MTG system. This system was analyzed using the TPAC code, which was recently developed by Idaho National Laboratory. The global sensitivity analyses were performed to understand and characterize tritium behaviors in the coupled HTGR/MTG system. This Monte Carlo based random sampling method was used to evaluate maximum 17,408 numbers of samples with different input values. According to the analyses, the average tritium concentration in the product gasoline is about 3.05×10-3 Bq/cm3, and 62 % cases are within the tritium effluent limit (= 3.7x10-3 Bq/cm3[STP]). About 0.19% of released tritium is finally transported from the core to the gasoline product through permeations. This study also identified that the following four parameters are important concerning tritium behaviors in the HTGR/MTG system: (1) tritium source, (2) wall thickness of process heat exchanger, (3) operating temperature, and (4) tritium permeation coefficient of process heat exchanger. These four parameters contribute about 95 % of the total output uncertainties. This study strongly recommends focusing our future research on these four parameters to improve modeling accuracy and to mitigate tritium permeation into the gasol ine product. If the permeation barrier is included in the future study, the tritium concentration will be significantly reduced.

  10. Determination of plutonium in spent nuclear fuel using high resolution X-ray

    SciTech Connect (OSTI)

    McIntosh, Kathryn G.; Reilly, Sean D.; Havrilla, George J.

    2015-05-30

    Characterization of Pu is an essential aspect of safeguards operations at nuclear fuel reprocessing facilities. A novel analysis technique called hiRX (high resolution X-ray) has been developed for the direct measurement of Pu in spent nuclear fuel dissolver solutions. hiRX is based on monochromatic wavelength dispersive X-ray fluorescence (MWDXRF), which provides enhanced sensitivity and specificity compared with conventional XRF techniques. A breadboard setup of the hiRX instrument was calibrated using spiked surrogate spent fuel (SSF) standards prepared as dried residues. Samples of actual spent fuel were utilized to evaluate the performance of the hiRX. The direct detection of just 39 ng of Pu is demonstrated. Initial quantitative results, with error of 4–27% and precision of 2% relative standard deviation (RSD), were obtained for spent fuel samples. The limit of detection for Pu (100 s) within an excitation spot of 200 μm diameter was 375 pg. This study demonstrates the potential for the hiRX technique to be utilized for the rapid, accurate, and precise determination of Pu. Moreover, the results highlight the analytical capability of hiRX for other applications requiring sensitive and selective nondestructive analyses.

  11. Determination of plutonium in spent nuclear fuel using high resolution X-ray

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    McIntosh, Kathryn G.; Reilly, Sean D.; Havrilla, George J.

    2015-05-30

    Characterization of Pu is an essential aspect of safeguards operations at nuclear fuel reprocessing facilities. A novel analysis technique called hiRX (high resolution X-ray) has been developed for the direct measurement of Pu in spent nuclear fuel dissolver solutions. hiRX is based on monochromatic wavelength dispersive X-ray fluorescence (MWDXRF), which provides enhanced sensitivity and specificity compared with conventional XRF techniques. A breadboard setup of the hiRX instrument was calibrated using spiked surrogate spent fuel (SSF) standards prepared as dried residues. Samples of actual spent fuel were utilized to evaluate the performance of the hiRX. The direct detection of just 39more » ng of Pu is demonstrated. Initial quantitative results, with error of 4–27% and precision of 2% relative standard deviation (RSD), were obtained for spent fuel samples. The limit of detection for Pu (100 s) within an excitation spot of 200 μm diameter was 375 pg. This study demonstrates the potential for the hiRX technique to be utilized for the rapid, accurate, and precise determination of Pu. Moreover, the results highlight the analytical capability of hiRX for other applications requiring sensitive and selective nondestructive analyses.« less

  12. FLEXIBLE COUPLING

    DOE Patents [OSTI]

    Babelay, E.F.

    1962-02-13

    A flexible shaft coupling for operation at speeds in excess of 14,000 rpm is designed which requires no lubrication. A driving sleeve member and a driven sleeve member are placed in concentric spaced relationship. A torque force is transmitted to the driven member from the driving member through a plurality of nylon balls symmetrically disposed between the spaced sleeves. The balls extend into races and recesses within the respective sleeve members. The sleeve members have a suitable clearance therebetween and the balls have a suitable radial clearance during operation of the coupling to provide a relatively loose coupling. These clearances accommodate for both parallel and/or angular misalignments and avoid metal-tometal contact between the sleeve members during operation. Thus, no lubrication is needed, and a minimum of vibrations is transmitted between the sleeve members. (AEC)

  13. High-precision method for determining the position of laser beam focal plane

    SciTech Connect (OSTI)

    Malashko, Ya I; Kleimenov, A N; Potemkin, I B; Khabibulin, V M

    2013-12-31

    The method of wavefront doubled-frequency spherical modulation for determining the laser beam waist position has been simulated and experimentally studied. The error in determining the focal plane position is less than 10{sup -5} D. The amplitude of the control doubled-frequency electric signal is experimentally found to correspond to 12% of the total radiation power. (laser beams)

  14. Determination of trace lanthanides and yttrium in seawater by inductively coupled plasma mass spectrometry after preconcentration with solvent extraction and back-extraction

    SciTech Connect (OSTI)

    Shabani, M.B.; Akagi, Tasuku; Shimizu, Hiroshi; Masuda, Akimasa )

    1990-12-15

    A method for the analysis of sub parts per trillion levels of rare-earth elements (REEs) and yttrium (Y) in seawater after preconcentration with solvent extraction and back-extraction has been developed. Almost perfect extraction and back-extraction of all REE and Y were achieved by single extraction, and most of the matrix elements were removed during the extraction procedure. Even after 200-fold preconcentration, matrix problems by ICP-MS measurement were negligible. Contamination from reagents and water used during the pretreatment was below 1% of the concentration of REE and Y in seawater. The standard deviation obtained for triplicate separation of 100- and 1,000-mL samples of the same seawater was better than 5% for all REE. The average precision of the measurement for all REE and Y after preconcentration of 1,000 mL of raw seawater to 5 mL of final measurement solution was calculated to be less than 2.5%. Since there is no standard seawater sample for REE and Y, in order to evaluate this novel technique, the analytical results obtained by this method were compared with those obtained by isotope dilution mass spectrometry coupled with Fe coprecipitation.

  15. A Measurement of the Rate of Muon Capture in Hydrogen Gas andDetermination of the Proton's Induced Pseudoscalar Coupling gP

    SciTech Connect (OSTI)

    Banks, Thomas Ira

    2007-07-10

    This dissertation describes a measurement of the rate ofnuclear muon capture by the proton, performed by the MuCap Collaborationusing a new technique based on a time projection chamber operating inultraclean, deuterium-depleted hydrogen gas at room temperature and 1 MPapressure. The hydrogen target's low gas density of 1 percent compared toliquid hydrogen is key to avoiding uncertainties that arise from theformation of muonic molecules. The capture rate was obtained from thedifference between the mu- disappearance rate in hydrogen--as determinedfrom data collected in the experiment's first physics run in fall2004--and the world averagefor the mu+ decay rate. After combining theresults of my analysis with the results from another independent analysisof the 2004 data, the muon capture rate from the hyperfine singlet groundstate of the mu-p atom is found to be Lambda_S = 725.0 +- 17.4 1/s, fromwhich the induced pseudoscalar coupling of the nucleon, gP(q2 = -0.88m2mu)= 7.3 +- 1.1, is extracted. This result for gP is consistent withtheoretical predictions that are based on the approximate chiral symmetryof QCD.

  16. New generation NMR bioreactor coupled with high-resolution NMR spectroscopy leads to novel discoveries in Moorella thermoaceticum metabolic profiles

    SciTech Connect (OSTI)

    Xue, Junfeng; Isern, Nancy G.; Ewing, R James; Liyu, Andrey V.; Sears, Jesse A.; Knapp, Harlan; Iversen, Jens; Sisk, Daniel R.; Ahring, Birgitte K.; Majors, Paul D.

    2014-06-20

    An in-situ nuclear magnetic resonance (NMR) bioreactor was developed and employed to monitor microbial metabolism under batch-growth conditions in real time. We selected Moorella thermoacetica ATCC 49707 as a test case. M. thermoacetica (formerly Clostridium thermoaceticum) is a strictly anaerobic, thermophilic, acetogenic, gram-positive bacterium with potential for industrial production of chemicals. The metabolic profiles of M. thermoacetica were characterized during growth in batch mode on xylose (a component of lignocellulosic biomass) using the new generation NMR bioreactor in combination with high-resolution, high sensitivity NMR (HR-NMR) spectroscopy. In-situ NMR measurements were performed using water-suppressed H-1 NMR spectroscopy at an NMR frequency of 500 MHz, and aliquots of the bioreactor contents were taken for 600 MHz HR-NMR spectroscopy at specific intervals to confirm metabolite identifications and expand metabolite coverage. M. thermoacetica demonstrated the metabolic potential to produce formate, ethanol and methanol from xylose, in addition to its known capability of producing acetic acid. Real-time monitoring of bioreactor conditions showed a temporary pH decrease, with a concomitant increase in formic acid during exponential growth. Fermentation experiments performed outside of the magnet showed that the strong magnetic field employed for NMR detection did not significantly affect cell metabolism. Use of the in-situ NMR bioreactor facilitated monitoring of the fermentation process in real time, enabling identification of intermediate and end-point metabolites and their correlation with pH and biomass produced during culture growth. Real-time monitoring of culture metabolism using the NMR bioreactor in combination with the HR-NMR spectroscopy will allow optimization of the metabolism of microorganisms producing valuable bioproducts.

  17. Relativistic general-order coupled-cluster method for high-precision calculations: Application to the Al{sup +} atomic clock

    SciTech Connect (OSTI)

    Kallay, Mihaly; Nataraj, H. S.; Sahoo, B. K.; Das, B. P.; Visscher, Lucas

    2011-03-15

    We report the implementation of a general-order relativistic coupled-cluster method for performing high-precision calculations of atomic and molecular properties. As a first application, the black-body radiation shift of the Al{sup +} clock has been estimated precisely. The computed shift relative to the frequency of the 3s{sup 2} {sup 1}S{sub 0}{sup e}{yields}3s3p {sup 3}P{sub 0}{sup o} clock transition given by (-3.66{+-}0.60)x10{sup -18} calls for an improvement over the recent measurement with a reported result of (-9{+-}3)x10{sup -18}[Phys. Rev. Lett. 104, 070802 (2010)].

  18. Chemical Characterization of Crude Petroleum Using Nanospray Desorption Electrospray Ionization Coupled with High-Resolution Mass Spectrometry

    SciTech Connect (OSTI)

    Eckert, Peter A.; Roach, Patrick J.; Laskin, Alexander; Laskin, Julia

    2012-02-07

    Nanospray desorption electrospray ionization (nano-DESI) combined with high-resolution mass spectrometry was used for the first time for the analysis of liquid petroleum crude oil samples. The analysis was performed in both positive and negative ionization modes using three solvents one of which (acetonitrile/toluene mixture) is commonly used in petroleomics studies while two other polar solvents (acetonitrile/water and methanol/water mixtures) are generally not compatible with petroleum characterization using mass spectrometry. The results demonstrate that nano-DESI analysis efficiently ionizes petroleum constituents soluble in a particular solvent. When acetonitrile/toluene is used as a solvent, nano-DESI generates electrospray-like spectra. In contrast, strikingly different spectra were obtained using acetonitrile/water and methanol/water. Comparison with the literature data indicates that these solvents selectively extract water-soluble constituents of the crude oil. Water-soluble compounds are predominantly observed as sodium adducts in nano-DESI spectra indicating that addition of sodium to the solvent may be a viable approach for efficient ionization of water-soluble crude oil constituents. Nano-DESI enables rapid screening of different classes of compounds in crude oil samples using solvents that are rarely used for petroleum characterization.

  19. Determination of High-Frequency Current Distribution Using EMTP-Based Transmission Line Models with Resulting Radiated Electromagnetic Fields

    SciTech Connect (OSTI)

    Mork, B; Nelson, R; Kirkendall, B; Stenvig, N

    2009-11-30

    Application of BPL technologies to existing overhead high-voltage power lines would benefit greatly from improved simulation tools capable of predicting performance - such as the electromagnetic fields radiated from such lines. Existing EMTP-based frequency-dependent line models are attractive since their parameters are derived from physical design dimensions which are easily obtained. However, to calculate the radiated electromagnetic fields, detailed current distributions need to be determined. This paper presents a method of using EMTP line models to determine the current distribution on the lines, as well as a technique for using these current distributions to determine the radiated electromagnetic fields.

  20. Determination of the Average Aromatic Cluster Size of Fossil Fuels by Solid-State NMR at High Magnetic Field

    SciTech Connect (OSTI)

    Mao, Kanmi; Kennedy, Gordon J.; Althaus, Stacey M.; Pruski, Marek

    2013-01-07

    We show that the average aromatic cluster size in complex carbonaceous materials can be accurately determined using fast magic-angle spinning (MAS) NMR at a high magnetic field. To accurately quantify the nonprotonated aromatic carbon, we edited the 13C spectra using the recently reported MAS-synchronized spinecho, which alleviated the problem of rotational recoupling of 1H-13C dipolar interactions associated with traditional dipolar dephasing experiments. The dependability of this approach was demonstrated on selected Argonne Premium coal standards, for which full sets of basic structural parameters were determined with high accuracy.

  1. An Integrated Method for Accurate Determination of Melting in High-Pressure Laser Heating Experiments

    SciTech Connect (OSTI)

    Benedetti, L R; Antonangeli, D; Farber, D L; Mezouar, M

    2007-11-19

    We present an integrated approach for melting determination by monitoring several criteria simultaneously. In particular we combine x-ray diffraction observations with the detection of discontinuities in the optical properties by spectroradiometric measurements. This approach significantly increases the confidence of melt identification, especially with low-Z samples. We demonstrate the method with observations of melt in oxygen at 47 and 55 gigapascals.

  2. Sealing coupling

    DOE Patents [OSTI]

    Pardini, John A. (Brookfield, IL); Brubaker, Robert C. (Naperville, IL); Rusnak, John J. (Orland Park, IL)

    1985-01-01

    Disclosed is a remotely operable releasable sealing coupling which provides fluid-tight joinder of upper and a lower conduit sections. Each conduit section has a concave conical sealing surface adjacent its end portion. A tubular sleeve having convex spherical ends is inserted between the conduit ends to form line contact with the concave conical end portions. An inwardly projecting lip located at one end of the sleeve cooperates with a retaining collar formed on the upper pipe end to provide swivel capture for the sleeve. The upper conduit section also includes a tapered lower end portion which engages the inside surface of the sleeve to limit misalignment of the connected conduit sections.

  3. Grid Inertial Response-Based Probabilistic Determination of Energy Storage System Capacity Under High Solar Penetration

    SciTech Connect (OSTI)

    Yue, Meng; Wang, Xiaoyu

    2015-07-01

    It is well-known that responsive battery energy storage systems (BESSs) are an effective means to improve the grid inertial response to various disturbances including the variability of the renewable generation. One of the major issues associated with its implementation is the difficulty in determining the required BESS capacity mainly due to the large amount of inherent uncertainties that cannot be accounted for deterministically. In this study, a probabilistic approach is proposed to properly size the BESS from the perspective of the system inertial response, as an application of probabilistic risk assessment (PRA). The proposed approach enables a risk-informed decision-making process regarding (1) the acceptable level of solar penetration in a given system and (2) the desired BESS capacity (and minimum cost) to achieve an acceptable grid inertial response with a certain confidence level.

  4. Grid Inertial Response-Based Probabilistic Determination of Energy Storage System Capacity Under High Solar Penetration

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yue, Meng; Wang, Xiaoyu

    2015-07-01

    It is well-known that responsive battery energy storage systems (BESSs) are an effective means to improve the grid inertial response to various disturbances including the variability of the renewable generation. One of the major issues associated with its implementation is the difficulty in determining the required BESS capacity mainly due to the large amount of inherent uncertainties that cannot be accounted for deterministically. In this study, a probabilistic approach is proposed to properly size the BESS from the perspective of the system inertial response, as an application of probabilistic risk assessment (PRA). The proposed approach enables a risk-informed decision-making processmore » regarding (1) the acceptable level of solar penetration in a given system and (2) the desired BESS capacity (and minimum cost) to achieve an acceptable grid inertial response with a certain confidence level.« less

  5. Determination of the relative resistance to ignition of selected turbopump materials in high-pressure, high-temperature, oxygen environments, volume 1. Interim report

    SciTech Connect (OSTI)

    Stoltzfus, J.M.; Benz, F.J.

    1986-07-01

    Advances in the design of the liquid oxygen, liquid hydrogen engines for the Space Transportation System call for the use of warm, high-pressure oxygen as the driving gas in the liquid oxygen turbopump. The NASA Lewis Research Center requested the NASA White Sands Test Facility (WSTF) to design a test program to determine the relative resistance to ignition of nine selected turbopump materials: Hastelloy X, Inconel 600, Invar 36, Monel K-500, nickel 200, silicon carbide, stainless steel 316, and zirconium copper. The materials were subjected to particle impact and to frictional heating in high-pressure oxygen.

  6. Design of Low-Noise Output Amplifiers for P-channel Charge-Coupled Devices Fabricated on High-Resistivity Silicon

    SciTech Connect (OSTI)

    Haque, S; Frost, F Dion R.; Groulx, R; Holland, S E; Karcher, A; Kolbe, W F; Roe, N A; Wang, G; Yu, Y

    2011-12-22

    We describe the design and optimization of low-noise, single-stage output amplifiers for p-channel charge-coupled devices (CCDs) used for scientific applications in astronomy and other fields. The CCDs are fabricated on high-resistivity, 4000–5000 -cm, n-type silicon substrates. Single-stage amplifiers with different output structure designs and technologies have been characterized. The standard output amplifier is designed with an n{sup +} polysilicon gate that has a metal connection to the sense node. In an effort to lower the output amplifier readout noise by minimizing the capacitance seen at the sense node, buried-contact technology has been investigated. In this case, the output transistor has a p{sup +} polysilicon gate that connects directly to the p{sup +} sense node. Output structures with buried-contact areas as small as 2 μm × 2 μm are characterized. In addition, the geometry of the source-follower transistor was varied, and we report test results on the conversion gain and noise of the various amplifier structures. By use of buried-contact technology, better amplifier geometry, optimization of the amplifier biases and improvements in the test electronics design, we obtain a 45% reduction in noise, corresponding to 1.7 e{sup -} rms at 70 kpixels/sec.

  7. Determination of Band Offsets between the High-k Dielectric LaAlO3 Film and

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the In0.53Ga0.47As Substrate Determination of Band Offsets between the High-k Dielectric LaAlO3 Film and the In0.53Ga0.47As Substrate Scaling of conventional silicon based metal-oxide-semiconductor (MOS) transistors requires thinner and thinner SiO2 films. However, the figure 1 Figure 1: Intel 45 nm SRAM chip and IntelrCoreTM2 family processor. Hafnium-based high-k dielectric materials are used in the fabrication of those chips. increase of leakage current through thinner SiO2 films puts a

  8. Experimental Determination of DT Yield in High Current DD Dense Plasma Focii

    SciTech Connect (OSTI)

    Lowe, D. R.; Hagen, E. C.; Meehan, B. T.; Springs, R. K.; O'Brien, R. J.

    2013-06-18

    Dense Plasma Focii (DPF), which utilize deuterium gas to produce 2.45 MeV neutrons, may in fact also produce DT fusion neutrons at 14.1 MeV due to the triton production in the DD reaction. If beam-target fusion is the primary producer of fusion neutrons in DPFs, it is possible that ejected tritons from the first pinch will interact with the second pinch, and so forth. The 2 MJ DPF at National Security Technologies Losee Road Facility is able to, and has produced, over 1E12 DD neutrons per pulse, allowing an accurate measurement of the DT/DD ratio. The DT/DD ratio was experimentally verified by using the (n,2n) reaction in a large piece of praseodymium metal, which has a threshold reaction of 8 MeV, and is widely used as a DT yield measurement system1. The DT/DD ratio was experimentally determined for over 100 shots, and then compared to independent variables such as tube pressure, number of pinches per shot, total current, pinch current and charge voltage.

  9. Experimental determination of lead carbonate solubility at high ionic strengths: A Pitzer model description

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Xiong, Yongliang

    2015-05-06

    In this article, solubility measurements of lead carbonate, PbCO3(cr), cerussite, as a function of total ionic strengths are conducted in the mixtures of NaCl and NaHCO3 up to I = 1.2 mol•kg–1 and in the mixtures of NaHCO3 and Na2CO3 up to I = 5.2 mol•kg–1, at room temperature (22.5 ± 0.5 °C). The solubility constant (log Ksp) for cerussite, PbCO3(cr) = Pb2+ + CO32- was determined as –13.76 ± 0.15 (2σ) with a set of Pitzer parameters describing the specific interactions of PbCO3(aq), Pb(CO3)22-, and Pb(CO3)Cl– with the bulk-supporting electrolytes, based on the Pitzer model. The model developed inmore » this work can reproduce the experimental results including model-independent solubility values from the literature over a wide range of ionic strengths with satisfactory accuracy. The model is expected to find applications in numerous fields, including the accurate description of chemical behavior of lead in geological repositories, the modeling of formation of oxidized Pb–Zn ore deposits, and the environmental remediation of lead contamination.« less

  10. Coupled dual loop absorption heat pump

    DOE Patents [OSTI]

    Sarkisian, Paul H.; Reimann, Robert C.; Biermann, Wendell J.

    1985-01-01

    A coupled dual loop absorption system which utilizes two separate complete loops. Each individual loop operates at three temperatures and two pressures. This low temperature loop absorber and condenser are thermally coupled to the high temperature loop evaporator, and the high temperature loop condenser and absorber are thermally coupled to the low temperature generator.

  11. Determination of uranium and thorium in semiconductor memory materials by high fluence neutron activation analysis

    SciTech Connect (OSTI)

    Dyer, F.F.; Emery, J.F.; Northcutt, K.J.; Scott, R.M.

    1981-01-01

    Uranium and thorium were measured by absolute neutron activation analysis in high-purity materials used to manufacture semiconductor memories. The main thrust of the study concerned aluminum and aluminum alloys used as sources for thin film preparation, evaporated metal films, and samples from the Czochralski silicon crystal process. Average levels of U and Th were found for the source alloys to be approx. 65 and approx. 45 ppB, respectively. Levels of U and Th in silicon samples fell in the range of a few parts per trillion. Evaporated metal films contained about 1 ppB U and Th, but there is some question about these results due to the possibility of contamination.

  12. Experimental determination of lead carbonate solubility at high ionic strengths: A Pitzer model description

    SciTech Connect (OSTI)

    Xiong, Yongliang

    2015-05-06

    In this article, solubility measurements of lead carbonate, PbCO3(cr), cerussite, as a function of total ionic strengths are conducted in the mixtures of NaCl and NaHCO3 up to I = 1.2 mol•kg–1 and in the mixtures of NaHCO3 and Na2CO3 up to I = 5.2 mol•kg–1, at room temperature (22.5 ± 0.5 °C). The solubility constant (log Ksp) for cerussite, PbCO3(cr) = Pb2+ + CO32- was determined as –13.76 ± 0.15 (2σ) with a set of Pitzer parameters describing the specific interactions of PbCO3(aq), Pb(CO3)22-, and Pb(CO3)Cl with the bulk-supporting electrolytes, based on the Pitzer model. The model developed in this work can reproduce the experimental results including model-independent solubility values from the literature over a wide range of ionic strengths with satisfactory accuracy. The model is expected to find applications in numerous fields, including the accurate description of chemical behavior of lead in geological repositories, the modeling of formation of oxidized Pb–Zn ore deposits, and the environmental remediation of lead contamination.

  13. Determination of the top-quark pole mass and strong coupling constant from the t t-bar production cross section in pp collisions at $$\\sqrt{s}$$ = 7 TeV

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chatrchyan, Serguei

    2014-08-21

    The inclusive cross section for top-quark pair production measured by the CMS experiment in proton-proton collisions at a center-of-mass energy of 7 TeV is compared to the QCD prediction at next-to-next-to-leading order with various parton distribution functions to determine the top-quark pole mass,more » $$m_t^{pole}$$, or the strong coupling constant, $$\\alpha_S$$. With the parton distribution function set NNPDF2.3, a pole mass of 176.7$$^{+3.0}_{-2.8}$$ GeV is obtained when constraining $$\\alpha_S$$ at the scale of the Z boson mass, $m_Z$, to the current world average. Alternatively, by constraining $$m_t^{pole}$$ to the latest average from direct mass measurements, a value of $$\\alpha_S(m_Z)$$ = 0.1151$$^{+0.0028}_{-0.0027}$$ is extracted. This is the first determination of $$\\alpha_S$$ using events from top-quark production.« less

  14. Coupling apparatus for a metal vapor laser

    DOE Patents [OSTI]

    Ball, D.G.; Miller, J.L.

    1993-02-23

    Coupling apparatus for a large bore metal vapor laser is disclosed. The coupling apparatus provides for coupling high voltage pulses (approximately 40 KV) to a metal vapor laser with a high repetition rate (approximately 5 KHz). The coupling apparatus utilizes existing thyratron circuits and provides suitable power input to a large bore metal vapor laser while maintaining satisfactory operating lifetimes for the existing thyratron circuits.

  15. Coupling apparatus for a metal vapor laser

    DOE Patents [OSTI]

    Ball, Don G.; Miller, John L.

    1993-01-01

    Coupling apparatus for a large bore metal vapor laser is disclosed. The coupling apparatus provides for coupling high voltage pulses (approximately 40 KV) to a metal vapor laser with a high repetition rate (approximately 5 KHz). The coupling apparatus utilizes existing thyratron circuits and provides suitable power input to a large bore metal vapor laser while maintaining satisfactory operating lifetimes for the existing thyratron circuits.

  16. SU-C-16A-02: A Beryllium Oxide (BeO) Fibre-Coupled Luminescence Dosimeter for High Dose Rate Brachytherapy

    SciTech Connect (OSTI)

    Santos, A; Mohammadi, M; Afshar, V.S.

    2014-06-15

    Purpose: Beryllium oxide (BeO) ceramics have an effective atomic number, zeff ∼7.1, closely matched to water, zeff ∼7.4. The purpose of this study was to evaluate the use of a beryllium oxide (BeO) ceramic fibrecoupled luminescence dosimeter, named RL/OSL BeO FOD, for high dose rate (HDR) brachytherapy dosimetry. In our dosimetry system the radioluminescence (RL) of BeO ceramics is utilized for dose-rate measurements, and the optically stimulated luminescence (OSL) can be read post exposure for accumulated dose measurements. Methods: The RL/OSL BeO FOD consists of a 1 mm diameter × 1 mm long cylinder of BeO ceramic coupled to a 15 m long silica-silica optical fibre. The optical fibre is connected to a custom developed portable RL and OSL reader, located outside of the treatment suite. The x-ray energy response was evaluated using superficial x-rays, an Ir-192 source and high energy linear accelerators. The RL/OSL BeO FOD was then characterised for an Ir-192 source, investigating the dose response and angular dependency. A depth dose curve for the Ir-192 source was also measured. Results: The RL/OSL BeO FOD shows an under-response at low energy x-rays as expected. Though at higher x-ray energies, the OSL response continued to increase, while the RL response remained relatively constant. The dose response for the RL is found to be linear up to doses of 15 Gy, while the OSL response becomes more supralinear to doses above 15 Gy. Little angular dependency is observed and the depth dose curve measured agreed within 4% of that calculated based on TG-43. Conclusion: This works shows that the RL/OSL BeO FOD can be useful in HDR dosimetry. With the RL/OSL BeO FODs current size, it is capable of being inserted into intraluminal catheters and interstitial needles to verify HDR treatments.

  17. Quick torque coupling

    DOE Patents [OSTI]

    Luft, Peter A.

    2009-05-12

    A coupling for mechanically connecting modular tubular struts of a positioning apparatus or space frame, comprising a pair of toothed rings (10, 12) attached to separate strut members (16), the teeth (18, 20) of the primary rings (10, 12) mechanically interlocking in both an axial and circumferential manner, and a third part comprising a sliding, toothed collar (14) the teeth (22) of which interlock the teeth (18, 20) of the primary rings (10, 12), preventing them from disengaging, and completely locking the assembly together. A secondary mechanism provides a nesting force for the collar, and/or retains it. The coupling is self-contained and requires no external tools for installation, and can be assembled with gloved hands in demanding environments. No gauging or measured torque is required for assembly. The assembly can easily be visually inspected to determine a "go" or "no-go" status. The coupling is compact and relatively light-weight. Because of it's triply interlocking teeth, the connection is rigid. The connection does not primarily rely on clamps, springs or friction based fasteners, and is therefore reliable in fail-safe applications.

  18. Capacitively-coupled inductive sensor

    DOE Patents [OSTI]

    Ekdahl, Carl A.

    1984-01-01

    A capacitively coupled inductive shunt current sensor which utilizes capacitive coupling between flanges having an annular inductive channel formed therein. A voltage dividing capacitor is connected between the coupling capacitor and ground to provide immediate capacitive division of the output signal so as to provide a high frequency response of the current pulse to be detected. The present invention can be used in any desired outer conductor such as the outer conductor of a coaxial transmission line, the outer conductor of an electron beam transmission line, etc.

  19. Lateral transport and far-infrared radiation of electrons in In{sub x}Ga{sub 1-x}As/GaAs heterostructures with the double tunnel-coupled quantum wells in a high electric field

    SciTech Connect (OSTI)

    Baidus, N. V.; Belevskii, P. A.; Biriukov, A. A.; Vainberg, V. V.; Vinoslavskii, M. N.; Ikonnikov, A. V.; Zvonkov, B. N.; Pylypchuk, A. S.; Poroshin, V. N.

    2010-11-15

    It is shown that the far-infrared radiation of electrons in the selectively doped heterostructures with double tunnel-coupled quantum wells in high lateral electric fields strongly depends on the level of doping of the wells. At a high impurity concentration in a narrow well, higher than (1-2) x 10{sup 11} cm{sup -2}, the radiation is caused only by indirect intrasubband electron transitions. At a lower concentration, along with the indirect transitions, the direct intersubband transitions also contribute to the radiation. These transitions become possible in high electric fields due to the real-space electron transfer between the quantum wells.

  20. Determination of gene expression patterns using high-throughput RNA in situ hybridizaion to whole-mount Drosophila embryos

    SciTech Connect (OSTI)

    Weiszmann, R.; Hammonds, A.S.; Celniker, S.E.

    2009-04-09

    We describe a high-throughput protocol for RNA in situ hybridization (ISH) to Drosophila embryos in a 96-well format. cDNA or genomic DNA templates are amplified by PCR and then digoxigenin-labeled ribonucleotides are incorporated into antisense RNA probes by in vitro transcription. The quality of each probe is evaluated before ISH using a RNA probe quantification (dot blot) assay. RNA probes are hybridized to fixed, mixed-staged Drosophila embryos in 96-well plates. The resulting stained embryos can be examined and photographed immediately or stored at 4oC for later analysis. Starting with fixed, staged embryos, the protocol takes 6 d from probe template production through hybridization. Preparation of fixed embryos requires a minimum of 2 weeks to collect embryos representing all stages. The method has been used to determine the expression patterns of over 6,000 genes throughout embryogenesis.

  1. Unambiguous determination of H-atom positions: comparing results from neutron and high-resolution X-ray crystallography

    SciTech Connect (OSTI)

    Gardberg, Anna S.; Del Castillo, Alexis R.; Weiss, Kevin L.; Meilleur, Flora; Blakeley, Matthew P.; Myles, Dean A.A.

    2010-11-19

    The locations of H atoms in biological structures can be difficult to determine using X-ray diffraction methods. Neutron diffraction offers a relatively greater scattering magnitude from H and D atoms. Here, 1.65 {angstrom} resolution neutron diffraction studies of fully perdeuterated and selectively CH{sub 3}-protonated perdeuterated crystals of Pyrococcus furiosus rubredoxin (D-rubredoxin and HD-rubredoxin, respectively) at room temperature (RT) are described, as well as 1.1 {angstrom} resolution X-ray diffraction studies of the same protein at both RT and 100 K. The two techniques are quantitatively compared in terms of their power to directly provide atomic positions for D atoms and analyze the role played by atomic thermal motion by computing the {sigma} level at the D-atom coordinate in simulated-annealing composite D-OMIT maps. It is shown that 1.65 {angstrom} resolution RT neutron data for perdeuterated rubredoxin are {approx}8 times more likely overall to provide high-confidence positions for D atoms than 1.1 {angstrom} resolution X-ray data at 100 K or RT. At or above the 1.0{sigma} level, the joint X-ray/neutron (XN) structures define 342/378 (90%) and 291/365 (80%) of the D-atom positions for D-rubredoxin and HD-rubredoxin, respectively. The X-ray-only 1.1 {angstrom} resolution 100 K structures determine only 19/388 (5%) and 8/388 (2%) of the D-atom positions above the 1.0{sigma} level for D-rubredoxin and HD-rubredoxin, respectively. Furthermore, the improved model obtained from joint XN refinement yielded improved electron-density maps, permitting the location of more D atoms than electron-density maps from models refined against X-ray data only.

  2. Long-Gradient Separations Coupled with Selected Reaction Monitoring for Highly Sensitive, Large Scale Targeted Protein Quantification in a Single Analysis

    SciTech Connect (OSTI)

    Shi, Tujin; Fillmore, Thomas L.; Gao, Yuqian; Zhao, Rui; He, Jintang; Schepmoes, Athena A.; Nicora, Carrie D.; Wu, Chaochao; Chambers, Justin L.; Moore, Ronald J.; Kagan, Jacob; Srivastava, Sudhir; Liu, Alvin Y.; Rodland, Karin D.; Liu, Tao; Camp, David G.; Smith, Richard D.; Qian, Weijun

    2013-10-01

    Long-gradient separations coupled to tandem MS were recently demonstrated to provide a deep proteome coverage for global proteomics; however, such long-gradient separations have not been explored for targeted proteomics. Herein, we investigate the potential performance of the long-gradient separations coupled with selected reaction monitoring (LG-SRM) for targeted protein quantification. Direct comparison of LG-SRM (5 h gradient) and conventional LC-SRM (45 min gradient) showed that the long-gradient separations significantly reduced background interference levels and provided an 8- to 100-fold improvement in LOQ for target proteins in human female serum. Based on at least one surrogate peptide per protein, an LOQ of 10 ng/mL was achieved for the two spiked proteins in non-depleted human serum. The LG-SRM detection of seven out of eight endogenous plasma proteins expressed at ng/mL or sub-ng/mL levels in clinical patient sera was also demonstrated. A correlation coefficient of >0.99 was observed for the results of LG-SRM and ELISA measurements for prostate-specific antigen (PSA) in selected patient sera. Further enhancement of LG-SRM sensitivity was achieved by applying front-end IgY14 immunoaffinity depletion. Besides improved sensitivity, LG-SRM offers at least 3 times higher multiplexing capacity than conventional LC-SRM due to ~3-fold increase in average peak widths for a 300-min gradient compared to a 45-min gradient. Therefore, LG-SRM holds great potential for bridging the gap between global and targeted proteomics due to its advantages in both sensitivity and multiplexing capacity.

  3. A method to determine fault vectors in 4H-SiC from stacking sequences observed on high resolution transmission electron microscopy images

    SciTech Connect (OSTI)

    Wu, Fangzhen; Wang, Huanhuan; Raghothamachar, Balaji; Dudley, Michael; Mueller, Stephan G.; Chung, Gil; Sanchez, Edward K.; Hansen, Darren; Loboda, Mark J.; Zhang, Lihua; Su, Dong; Kisslinger, Kim; Stach, Eric

    2014-09-14

    A new method has been developed to determine the fault vectors associated with stacking faults in 4H-SiC from their stacking sequences observed on high resolution TEM images. This method, analogous to the Burgers circuit technique for determination of dislocation Burgers vector, involves determination of the vectors required in the projection of the perfect lattice to correct the deviated path constructed in the faulted material. Results for several different stacking faults were compared with fault vectors determined from X-ray topographic contrast analysis and were found to be consistent. This technique is expected to applicable to all structures comprising corner shared tetrahedra.

  4. Vehicle Technologies Office Merit Review 2015: New High Energy Electrochemical Couple for Automotive Application: ANL IC3P Research Focus on Diagnostic Studies at BNL

    Broader source: Energy.gov [DOE]

    Presentation given by Brookhaven National Laboratory at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about new high...

  5. Inductively coupled helium plasma torch

    DOE Patents [OSTI]

    Montaser, Akbar; Chan, Shi-Kit; Van Hoven, Raymond L.

    1989-01-01

    An inductively coupled plasma torch including a base member, a plasma tube and a threaded insert member within the plasma tube for directing the plasma gas in a tangential flow pattern. The design of the torch eliminates the need for a separate coolant gas tube. The torch can be readily assembled and disassembled with a high degree of alignment accuracy.

  6. Determination of the relative resistance to ignition of selected turbopump materials in high-pressure, high-temperature, oxygen environments, volume 4. Interim report

    SciTech Connect (OSTI)

    Stoltzfus, J.M.; Benz, F.J.

    1986-07-01

    Results from frictional heating tests to determine the effects of oxygen pressure on the Pv production required for igntion are presented. Materials tested include: Monel K-500 and 1015 carbon steels at pressures varied from 100 to 3000 PSIG).

  7. ARPES Provides Direct Evidence of Spin-Wave Coupling

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ARPES Provides Direct Evidence of Spin-Wave Coupling Print The electronic properties of a metal are determined by the dynamical behavior of its conduction electrons. Conventional...

  8. Three tooth kinematic coupling

    DOE Patents [OSTI]

    Hale, Layton C. (Livermore, CA)

    2000-01-01

    A three tooth kinematic coupling based on having three theoretical line contacts formed by mating teeth rather than six theoretical point contacts. The geometry requires one coupling half to have curved teeth and the other coupling half to have flat teeth. Each coupling half has a relieved center portion which does not effect the kinematics, but in the limit as the face width approaches zero, three line contacts become six point contacts. As a result of having line contact, a three tooth coupling has greater load capacity and stiffness. The kinematic coupling has application for use in precision fixturing for tools or workpieces, and as a registration device for a work or tool changer or for optics in various products.

  9. Measurement of the inclusive 3-jet production differential cross section in proton-proton collisions at 7 TeV and determination of the strong coupling constant in the TeV range

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Khachatryan, Vardan

    2015-05-01

    This paper presents a measurement of the inclusive 3-jet production differential cross section at a proton-proton centre-of-mass energy of 7 TeV using data corresponding to an integrated luminosity of 5 fb$^{-1}$ collected with the CMS detector. The analysis is based on the three jets with the highest transverse momenta. The cross section is measured as a function of the invariant mass of the three jets in a range of 445-3270 GeV and in two bins of the maximum rapidity of the jets up to a value of 2. A comparison between the measurement and the prediction from perturbative QCD atmorenext-to-leading order is performed. Within uncertainties, data and theory are in agreement. The sensitivity of the observable to parameters of the theory such as the parton distribution functions of the proton and the strong coupling constant $\\alpha_S$ is studied. A fit to all data points with 3-jet masses larger than 664 GeV gives a value of the strong coupling constant of $\\alpha_S(M_\\mathrm{Z})$ = 0.1171 $\\pm$ 0.0013 (exp) $^{+0.0073}_{-0.0047}$ (theo).less

  10. Measurement of the inclusive 3-jet production differential cross section in proton-proton collisions at 7 TeV and determination of the strong coupling constant in the TeV range

    SciTech Connect (OSTI)

    Khachatryan, Vardan

    2015-05-01

    This paper presents a measurement of the inclusive 3-jet production differential cross section at a proton-proton centre-of-mass energy of 7 TeV using data corresponding to an integrated luminosity of 5 fb$^{-1}$ collected with the CMS detector. The analysis is based on the three jets with the highest transverse momenta. The cross section is measured as a function of the invariant mass of the three jets in a range of 445-3270 GeV and in two bins of the maximum rapidity of the jets up to a value of 2. A comparison between the measurement and the prediction from perturbative QCD at next-to-leading order is performed. Within uncertainties, data and theory are in agreement. The sensitivity of the observable to parameters of the theory such as the parton distribution functions of the proton and the strong coupling constant $\\alpha_S$ is studied. A fit to all data points with 3-jet masses larger than 664 GeV gives a value of the strong coupling constant of $\\alpha_S(M_\\mathrm{Z})$ = 0.1171 $\\pm$ 0.0013 (exp) $^{+0.0073}_{-0.0047}$ (theo).

  11. Measurement of the inclusive 3-jet production differential cross section in proton–proton collisions at 7 TeV and determination of the strong coupling constant in the TeV range

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Khachatryan, Vardan

    2015-05-01

    This article presents a measurement of the inclusive 3-jet production differential cross section at a proton–proton centre-of-mass energy of 7 TeV using data corresponding to an integrated luminosity of 5fb–1 collected with the CMS detector. The analysis is based on the three jets with the highest transverse momenta. The cross section is measured as a function of the invariant mass of the three jets in a range of 445–3270 GeV and in two bins of the maximum rapidity of the jets up to a value of 2. A comparison between the measurement and the prediction from perturbative QCD at next-to-leadingmore » order is performed. Within uncertainties, data and theory are in agreement. The sensitivity of the observable to the strong coupling constant αS is studied. A fit to all data points with 3-jet masses larger than 664 GeV gives a value of the strong coupling constant of αS(MZ) = 0.1171 ± 0.0013(exp)+0.0073–0.0047(theo).« less

  12. Measurement of the inclusive 3-jet production differential cross section in proton–proton collisions at 7 TeV and determination of the strong coupling constant in the TeV range

    SciTech Connect (OSTI)

    Khachatryan, Vardan

    2015-05-01

    This article presents a measurement of the inclusive 3-jet production differential cross section at a proton–proton centre-of-mass energy of 7 TeV using data corresponding to an integrated luminosity of 5fb–1 collected with the CMS detector. The analysis is based on the three jets with the highest transverse momenta. The cross section is measured as a function of the invariant mass of the three jets in a range of 445–3270 GeV and in two bins of the maximum rapidity of the jets up to a value of 2. A comparison between the measurement and the prediction from perturbative QCD at next-to-leading order is performed. Within uncertainties, data and theory are in agreement. The sensitivity of the observable to the strong coupling constant αS is studied. A fit to all data points with 3-jet masses larger than 664 GeV gives a value of the strong coupling constant of αS(MZ) = 0.1171 ± 0.0013(exp)+0.0073–0.0047(theo).

  13. Improving Best Air Conditioner Efficiency by 20-30% through a High Efficiency Fan and Diffuser Stage Coupled with an Evaporative Condenser Pre-Cooler

    SciTech Connect (OSTI)

    Parker, Danny S; Sherwin, John R; Raustad, Richard

    2014-04-10

    The Florida Solar Energy Center (FSEC) conducted a research project to improve the best residential air conditioner condenser technology currently available on the market by retrofitting a commercially-available unit with both a high efficiency fan system and an evaporative pre-cooler. The objective was to integrate these two concepts to achieve an ultra-efficient residential air conditioner design. The project produced a working prototype that was 30% more efficient compared to the best currently-available technologies; the peak the energy efficiency ratio (EER) was improved by 41%. Efficiency at the Air-Conditioning and Refrigeration Institute (ARI) standard B-condition which is used to estimate seasonal energy efficiency ratio (SEER), was raised from a nominal 21 Btu/Wh to 32 Btu/Wh.

  14. Pipeline coating impedance effects on powerline fault current coupling

    SciTech Connect (OSTI)

    Dabkowski, J.

    1989-12-01

    Prior research leading to the development of predictive electromagnetic coupling computer codes has shown that the coating conductance is the principal factor in determining the response of a pipeline to magnetic induction from an overhead power transmission line. Under power line fault conditions, a high voltage may stress the coating causing a significant change in its conductance, and hence, the coupling response. Based upon laboratory experimentation and analysis, a model has been developed which allows prediction of the modified coating characteristics when subjected to high voltage during fault situations. Another program objective was the investigation of a method to determine the high voltage behavior of an existing coating from low voltage in situ field measurements. Such a method appeared conceptually feasible for non-porous coatings whose conductance is primarily a result of current leakage through existing holidays. However, limited testing has shown that difficulties in determining the steel-electrolyte capacitance limit the application of the method Methods for field measurement of the pipeline coating conductance were also studied for both dc ad ac signal excitation. Ac techniques offer the advantage that cathodic protection current interruption is not required, thus eliminating depolarization effects. However, ac field measurement techniques need additional refinement before these methods can be generally applied. 53 figs.

  15. Earth coupled cooling techniques

    SciTech Connect (OSTI)

    Grondzik, W.T.; Boyer, L.L.; Johnston, T.L.

    1981-01-01

    Earth coupled cooling is an important consideration for residential and commercial designers, owners, and builders in many regions of the country. The potential benefits which can be expected from passive earth contact cooling are reviewed. Recommendations for the design of earth sheltered structures incorporating earth coupled cooling strategies are also presented.

  16. Evaluation of coupling approaches for thermomechanical simulations

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Novascone, S. R.; Spencer, B. W.; Hales, J. D.; Williamson, R. L.

    2015-08-10

    Many problems of interest, particularly in the nuclear engineering field, involve coupling between the thermal and mechanical response of an engineered system. The strength of the two-way feedback between the thermal and mechanical solution fields can vary significantly depending on the problem. Contact problems exhibit a particularly high degree of two-way feedback between those fields. This paper describes and demonstrates the application of a flexible simulation environment that permits the solution of coupled physics problems using either a tightly coupled approach or a loosely coupled approach. In the tight coupling approach, Newton iterations include the coupling effects between all physics,more » while in the loosely coupled approach, the individual physics models are solved independently, and fixed-point iterations are performed until the coupled system is converged. These approaches are applied to simple demonstration problems and to realistic nuclear engineering applications. The demonstration problems consist of single and multi-domain thermomechanics with and without thermal and mechanical contact. Simulations of a reactor pressure vessel under pressurized thermal shock conditions and a simulation of light water reactor fuel are also presented. Here, problems that include thermal and mechanical contact, such as the contact between the fuel and cladding in the fuel simulation, exhibit much stronger two-way feedback between the thermal and mechanical solutions, and as a result, are better solved using a tight coupling strategy.« less

  17. Evaluation of coupling approaches for thermomechanical simulations

    SciTech Connect (OSTI)

    Novascone, S. R.; Spencer, B. W.; Hales, J. D.; Williamson, R. L.

    2015-08-10

    Many problems of interest, particularly in the nuclear engineering field, involve coupling between the thermal and mechanical response of an engineered system. The strength of the two-way feedback between the thermal and mechanical solution fields can vary significantly depending on the problem. Contact problems exhibit a particularly high degree of two-way feedback between those fields. This paper describes and demonstrates the application of a flexible simulation environment that permits the solution of coupled physics problems using either a tightly coupled approach or a loosely coupled approach. In the tight coupling approach, Newton iterations include the coupling effects between all physics, while in the loosely coupled approach, the individual physics models are solved independently, and fixed-point iterations are performed until the coupled system is converged. These approaches are applied to simple demonstration problems and to realistic nuclear engineering applications. The demonstration problems consist of single and multi-domain thermomechanics with and without thermal and mechanical contact. Simulations of a reactor pressure vessel under pressurized thermal shock conditions and a simulation of light water reactor fuel are also presented. Here, problems that include thermal and mechanical contact, such as the contact between the fuel and cladding in the fuel simulation, exhibit much stronger two-way feedback between the thermal and mechanical solutions, and as a result, are better solved using a tight coupling strategy.

  18. Insidious vapors: infrared determination of NO/sub 2/ generated in a high-voltage electric arc

    SciTech Connect (OSTI)

    Carlson, E.M.; LeFevre, P.G.; Williams, R.C.

    1984-11-01

    A study of the quantities of nitrogen dioxide generated by a high-voltage electric discharge was conducted. The amount of nitrogen dioxide present was measured using infrared spectroscopy. Paraffin was used to protect the KBr sample cell from damage and NO/sub 2/. The relative toxicities of phosgene and NO/sub 2/, both generated by arcing of electrical equipment, are presented. 10 references, 2 figures, 2 tables.

  19. Coupling in the Tevatron

    SciTech Connect (OSTI)

    Gelfand, N.M.

    1994-12-01

    The performance of the Fermilab Tevatron Collider at the commencement of run Ib was far below expectations. After a frustrating period of several months, a low-{beta} quad downstream of the interaction point at B0 was found to be rolled. This rolled quadrupole coupled the horizontal and vertical motion of the Tevatron beams. It also made matching the beam from the Main Ring to the Tevatron impossible, resulting in emittance blow up on injection. The net result of the roll was a significant reduction in the Tevatron luminosity. When the roll in the quadrupole was corrected the performance of the Tevatron improved dramatically. This note will discuss the experimental data indicating the presence of coupling and subsequent calculations which show how coupling an affect the luminosity. It is not intended to exhaust a discussion of coupling, which hopefully will be understood well enough to be discussed in a subsequent note.

  20. Ultrasonic transducer with laminated coupling wedge

    DOE Patents [OSTI]

    Karplus, Henry H. B.

    1976-08-03

    An ultrasonic transducer capable of use in a high-temperature environment incorporates a laminated metal coupling wedge including a reflecting edge shaped as a double sloping roof and a transducer crystal backed by a laminated metal sound absorber disposed so as to direct sound waves through the coupling wedge and into a work piece, reflections from the interface between the coupling wedge and the work piece passing to the reflecting edge. Preferably the angle of inclination of the two halves of the reflecting edge are different.

  1. Pair extended coupled cluster doubles

    SciTech Connect (OSTI)

    Henderson, Thomas M.; Scuseria, Gustavo E.; Bulik, Ireneusz W.

    2015-06-07

    The accurate and efficient description of strongly correlated systems remains an important challenge for computational methods. Doubly occupied configuration interaction (DOCI), in which all electrons are paired and no correlations which break these pairs are permitted, can in many cases provide an accurate account of strong correlations, albeit at combinatorial computational cost. Recently, there has been significant interest in a method we refer to as pair coupled cluster doubles (pCCD), a variant of coupled cluster doubles in which the electrons are paired. This is simply because pCCD provides energies nearly identical to those of DOCI, but at mean-field computational cost (disregarding the cost of the two-electron integral transformation). Here, we introduce the more complete pair extended coupled cluster doubles (pECCD) approach which, like pCCD, has mean-field cost and reproduces DOCI energetically. We show that unlike pCCD, pECCD also reproduces the DOCI wave function with high accuracy. Moreover, pECCD yields sensible albeit inexact results even for attractive interactions where pCCD breaks down.

  2. Experiments and Simulations of the Use of Time-Correlated Thermal Neutron Counting to Determine the Multiplication of an Assembly of Highly Enriched Uranium

    SciTech Connect (OSTI)

    David L. Chichester; Mathew T. Kinlaw; Scott M. Watson; Jeffrey M. Kalter; Eric C. Miller; William A. Noonan

    2014-11-01

    A series of experiments and numerical simulations using thermal-neutron time-correlated measurements has been performed to determine the neutron multiplication, M, of assemblies of highly enriched uranium available at Idaho National Laboratory. The experiments used up to 14.4 kg of highly-enriched uranium, including bare assemblies and assemblies reflected with high-density polyethylene, carbon steel, and tungsten. A small 252Cf source was used to initiate fission chains within the assembly. Both the experiments and the simulations used 6-channel and 8-channel detector systems, each consisting of 3He proportional counters moderated with polyethylene; data was recorded in list mode for analysis. 'True' multiplication values for each assembly were empirically derived using basic neutron production and loss values determined through simulation. A total of one-hundred and sixteen separate measurements were performed using fifty-seven unique measurement scenarios, the multiplication varied from 1.75 to 10.90. This paper presents the results of these comparisons and discusses differences among the various cases.

  3. Closed inductively coupled plasma cell

    DOE Patents [OSTI]

    Manning, T.J.; Palmer, B.A.; Hof, D.E.

    1990-11-06

    A closed inductively coupled plasma cell generates a relatively high power, low noise plasma for use in spectroscopic studies is disclosed. A variety of gases can be selected to form the plasma to minimize spectroscopic interference and to provide a electron density and temperature range for the sample to be analyzed. Grounded conductors are placed at the tube ends and axially displaced from the inductive coil, whereby the resulting electromagnetic field acts to elongate the plasma in the tube. Sample materials can be injected in the plasma to be excited for spectroscopy. 1 fig.

  4. Closed inductively coupled plasma cell

    DOE Patents [OSTI]

    Manning, Thomas J.; Palmer, Byron A.; Hof, Douglas E.

    1990-01-01

    A closed inductively coupled plasma cell generates a relatively high power, low noise plasma for use in spectroscopic studies. A variety of gases can be selected to form the plasma to minimize spectroscopic interference and to provide a electron density and temperature range for the sample to be analyzed. Grounded conductors are placed at the tube ends and axially displaced from the inductive coil, whereby the resulting electromagnetic field acts to elongate the plasma in the tube. Sample materials can be injected in the plasma to be excited for spectroscopy.

  5. Magnetically Coupled Adjustable Speed Motor Drives

    Broader source: Energy.gov [DOE]

    Alternating current electric motors rotate at a nearly constant speed that is determined by motor design and line frequency. Energy savings of 50% or more may be available when fixed speed systems are modified to allow the motor speed to match variable load requirements of a centrifugal fan or pump. This tip sheet describes the advantages of magnetically coupled ASDs and provides suggested actions.

  6. ARPES Provides Direct Evidence of Spin-Wave Coupling

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ARPES Provides Direct Evidence of Spin-Wave Coupling ARPES Provides Direct Evidence of Spin-Wave Coupling Print Wednesday, 30 March 2005 00:00 The electronic properties of a metal are determined by the dynamical behavior of its conduction electrons. Conventional band theory accounts for the interaction of the electrons with the static ion lattice. However, coupling to further microscopic degrees of freedom can alter the electron dynamics considerably. For example, "conventional"

  7. Coupling the inflaton to an expanding aether

    SciTech Connect (OSTI)

    Donnelly, William; Jacobson, Ted

    2010-09-15

    We consider a Lorentz-violating theory of inflation consisting of Einstein-aether theory with a scalar inflaton coupled bilinearly to the expansion of the aether. We determine the conditions for linearized stability, positive energy, and vanishing of preferred-frame post-Newtonian parameters, and find that all these conditions can be met. In homogeneous and isotropic cosmology, the inflaton-aether expansion coupling leads to a driving force on the inflaton that is proportional to the Hubble parameter. This force affects the slow-roll dynamics, but still allows for a natural end to inflation.

  8. Magnetic coupling device

    DOE Patents [OSTI]

    Nance, Thomas A.

    2009-08-18

    A quick connect/disconnect coupling apparatus is provided in which a base member is engaged by a locking housing through a series of interengagement pins. The pins maintain the shaft in a locked position. Upon exposure to an appropriately positioned magnetic field, pins are removed a sufficient distance such that the shaft may be withdrawn from the locking housing. The ability to lock and unlock the connector assembly requires no additional tools or parts apart from a magnetic key.

  9. COAXIAL TUBE COUPLING

    DOE Patents [OSTI]

    Niemoth, H.R.

    1963-02-26

    BS>This patent shows a device for quickly coupling coaxial tubes in metal-to-metal fashion, so as to be suitable for use in a nuclear reactor. A threaded coliar urges a tapered metal extension on the outer coaxial tube into a tapered seat in the device and simultaneously exerts pressure through a coaxial helical spring so that a similar extension on the inner tube seats in a similar seat near the other end. (AEC)

  10. Delineating parton distributions and the strong coupling

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jimenez-Delgado, P.; Reya, E.

    2014-04-29

    In this study, global fits for precision determinations of parton distributions, together with the highly correlated strong coupling αs, are presented up to next-to-next-to- leading order (NNLO) of QCD utilizing most world data (charm and jet production data are used where theoretically possible), except Tevatron gauge boson production data and LHC data which are left for genuine predictions. This is done within the 'dynamical' (valencelike input at Q02 = 0.8 GeV2 ) and 'standard' (input at Q02 = 2 GeV2) approach. The stability and reliability of the results are ensured by including nonperturbative higher-twist terms, nuclear corrections as well asmore » target mass corrections, and by applying various (Q2, W2) cuts on available data. In addition, the Q02 dependence of the results is studied in detail. Predictions are given, in particular for LHC, on gauge and Higgs boson as well as for top-quark pair production. At NNLO the dynamical approach results in αs(MZ2) = 0.1136 ± 0.0004, whereas the somewhat less constrained standard fit gives αs(MZ2) = 0.1162 ± 0.0006.« less

  11. Low-level measuring techniques for neutrons: High accuracy neutron source strength determination and fluence rate measurement at an underground laboratory

    SciTech Connect (OSTI)

    Zimbal, Andreas; Reginatto, Marcel; Schuhmacher, Helmut; Wiegel, Burkhard; Degering, Detlev; Zuber, Kai

    2013-08-08

    We report on measuring techniques for neutrons that have been developed at the Physikalisch-Technische Bundesanstalt (PTB), the German National Metrology Institute. PTB has characterized radioactive sources used in the BOREXINO and XENON100 experiments. For the BOREXINO experiment, a {sup 228}Th gamma radiation source was required which would not emit more than 10 neutrons per second. The determination of the neutron emission rate of this specially designed {sup 228}Th source was challenging due to the low neutron emission rate and because the ratio of neutron to gamma radiation was expected to be extremely low, of the order of 10{sup −6}. For the XENON100 detector, PTB carried out a high accuracy measurement of the neutron emission rate of an AmBe source. PTB has also done measurements in underground laboratories. A two month measurement campaign with a set of {sup 3}He-filled proportional counters was carried out in PTB's former UDO underground laboratory at the Asse salt mine. The aim of the campaign was to determine the intrinsic background of detectors, which is needed for the analysis of data taken in lowintensity neutron fields. At a later time, PTB did a preliminary measurement of the neutron fluence rate at the underground laboratory Felsenkeller operated by VKTA. By taking into account data from UDO, Felsenkeller, and detector calibrations made at the PTB facility, it was possible to estimate the neutron fluence rate at the Felsenkeller underground laboratory.

  12. Determination of the effect of different additives in coking blends using a combination of in situ high-temperature {sup 1}H NMR and rheometry

    SciTech Connect (OSTI)

    Miguel C. Diaz; Karen M. Steel; Trevor C. Drage; John W. Patrick; Colin E. Snape

    2005-12-01

    High-temperature {sup 1}H NMR and rheometry measurements were carried out on 4:1 wt/wt blends of a medium volatile bituminous coal with two anthracites, two petroleum cokes, charcoal, wood, a low-temperature coke breeze, tyre crumb, and active carbon to determine the effects on fluidity development to identify the parameters responsible for these effects during pyrolysis and to study possible relationships among the parameters derived from these techniques. Positive, negative, and neutral effects were identified on the concentration of fluid material. Small positive effects (ca. 5-6%) were caused by blending the coal with petroleum cokes. Charcoal, wood, and active carbon all exerted negative effects on concentration (18-27% reduction) and mobility (12-25% reduction in T2) of the fluid phase, which have been associated with the inert character and high surface areas of these additives that adsorb the fluid phase of the coal. One of the anthracites and the low-temperature coke breeze caused deleterious effects to a lesser extent on the concentration (7-12%) and mobility (13-17%) of the fluid material, possibly due to the high concentration of metals in these additives (ca. 11% ash). Despite the high fluid character of tyre crumb at the temperature of maximum fluidity of the coal (73%), the mobility of the fluid phase of the blend was lower than expected. The comparison of {sup 1}H NMR and rheometry results indicated that to account for the variations in minimum complex viscosity for all the blends, both the maximum concentration of fluid phase and the maximum mobility of the fluid material had to be considered. For individual blends, two exponential relationships have been found between the complex viscosity and the concentration of solid phase in both the softening and resolidification stages but the parameters are different for each blend. 30 refs., 8 figs., 5 tabs.

  13. Galvanic currents and hydrogen permeation currents caused by galvanic coupling

    SciTech Connect (OSTI)

    Armacanquil, M.E. ); Harasyn, D.E. )

    1990-05-01

    This paper reports on galvanic coupling and hydrogen permeation experiments performed in a Devanathan-Stachurski cell to measure simultaneously the galvanic currents and the hydrogen permeation currents in an attempt to determine the extent of hydrogen charging into noble metals as a result of galvanic coupling. Large amounts of hydrogen permeated through the more noble element of the couple. The magnitude of the hydrogen permeation flux varied depending on the galvanic coupling conditions. No simple direct relationship between galvanic currents and hydrogen permeation currents was observed, although large hydrogen permeation currents were usually developed whenever large galvanic currents were established.

  14. Nuclear reactor remote disconnect control rod coupling indicator

    DOE Patents [OSTI]

    Vuckovich, Michael

    1977-01-01

    A coupling indicator for use with nuclear reactor control rod assemblies which have remotely disengageable couplings between the control rod and the control rod drive shaft. The coupling indicator indicates whether the control rod and the control rod drive shaft are engaged or disengaged. A resistive network, utilizing magnetic reed switches, senses the position of the control rod drive mechanism lead screw and the control rod position indicating tube, and the relative position of these two elements with respect to each other is compared to determine whether the coupling is engaged or disengaged.

  15. Wear simulation of sucker rod couplings

    SciTech Connect (OSTI)

    Schumacher, W.J. )

    1991-09-01

    This paper reports that sucker rod strings are devices used to actuate pumps located at the bottom of oil wells. The individual rods are connected together by threaded couplings. Since the couplings have a larger diameter than the rods, they sometimes contact the inside diameter of the tubing during the up and down pumping cycle. Usually, this is not problem unless buckling occurs in the downstroke; however, this can lead to accelerated wear of the coupling and tubing. In nonvertical wells (offset, deviated, or slanted), the contact is more severe and rapid wear takes place. Couplings are more easily replaced during shutdowns; it is very important to minimize wear to tubing since it is virtually impossible to replace. TRIBONIC 20, an iron-based alloy containing approximately 13% Mn, 5% Si, 5.5% Cr, and 5% Ni, was laboratory evaluated to determine whether or not it could solve the sucker rod coupling-production tubing wear problem. The alloy demonstrated outstanding wear resistance both to itself and in protecting type 1019 steel.

  16. Sealing coupling. [LMFBR

    DOE Patents [OSTI]

    Pardini, J.A.; Brubaker, R.C.; Rusnak, J.J.

    1982-09-20

    Disclosed is a remotely operable releasable sealing coupling which provides fluid-tight joinder of upper and a lower conduit sections. Each conduit section has a concave conical sealing surface adjacent its end portion. A tubular sleeve having convex spherical ends is inserted between the conduit ends to form line contact with the concave conical end portions. An inwardly projecting lip located at one end of the sleeve cooperates with a retaining collar formed on the upper pipe end to provide swivel capture for the sleeve. The upper conduit section also includes a tapered lower end portion which engages the inside surface of the sleeve to limit misalignment of the connected conduit sections.

  17. Determination of the strong coupling constant ({alpha}{sub s...

    Office of Scientific and Technical Information (OSTI)

    a jet minimum Esub T of 25 GeV. A quantitative test of perturbative QCD has been made ... Resource Relation: Other Information: TH: Thesis (Ph.D); PBD: Aug 1993 Research Org: State ...

  18. Multiphysics Application Coupling Toolkit

    Energy Science and Technology Software Center (OSTI)

    2013-12-02

    This particular consortium implementation of the software integration infrastructure will, in large part, refactor portions of the Rocstar multiphysics infrastructure. Development of this infrastructure originated at the University of Illinois DOE ASCI Center for Simulation of Advanced Rockets (CSAR) to support the center's massively parallel multiphysics simulation application, Rocstar, and has continued at IllinoisRocstar, a small company formed near the end of the University-based program. IllinoisRocstar is now licensing these new developments as free, openmore » source, in hopes to help improve their own and others' access to infrastructure which can be readily utilized in developing coupled or composite software systems; with particular attention to more rapid production and utilization of multiphysics applications in the HPC environment. There are two major pieces to the consortium implementation, the Application Component Toolkit (ACT), and the Multiphysics Application Coupling Toolkit (MPACT). The current development focus is the ACT, which is (will be) the substrate for MPACT. The ACT itself is built up from the components described in the technical approach. In particular, the ACT has the following major components: 1.The Component Object Manager (COM): The COM package provides encapsulation of user applications, and their data. COM also provides the inter-component function call mechanism. 2.The System Integration Manager (SIM): The SIM package provides constructs and mechanisms for orchestrating composite systems of multiply integrated pieces.« less

  19. On coupling impedances of pumping holes

    SciTech Connect (OSTI)

    Kurennoy, S.

    1993-04-01

    Coupling impedances of a single small hole in vacuum-chamber walls have been calculated at low frequencies. To generalize these results for higher frequencies and/or larger holes one needs to solve coupled integral equations for the effective currents. These equations are solved for two specific hole shapes. The effects of many holes at high frequencies where the impedances are not additive are studied using a perturbation-theory method. The periodic versus random distributions of the pumping holes in the Superconducting Super Collider liner are compared.

  20. Coupled-cavity drift-tube linac

    DOE Patents [OSTI]

    Billen, J.H.

    1996-11-26

    A coupled-cavity drift-tube linac (CCDTL) combines features of the Alvarez drift-tube linac (DTL) and the {pi}-mode coupled-cavity linac (CCL). In one embodiment, each accelerating cavity is a two-cell, 0-mode DTL. The center-to-center distance between accelerating gaps is {beta}{lambda}, where {lambda} is the free-space wavelength of the resonant mode. Adjacent accelerating cavities have oppositely directed electric fields, alternating in phase by 180 degrees. The chain of cavities operates in a {pi}/2 structure mode so the coupling cavities are nominally unexcited. The CCDTL configuration provides an rf structure with high shunt impedance for intermediate velocity charged particles, i.e., particles with energies in the 20-200 MeV range. 5 figs.

  1. Coupled-cavity drift-tube linac

    DOE Patents [OSTI]

    Billen, James H.

    1996-01-01

    A coupled-cavity drift-tube linac (CCDTL) combines features of the Alvarez drift-tube linac (DTL) and the .pi.-mode coupled-cavity linac (CCL). In one embodiment, each accelerating cavity is a two-cell, 0-mode DTL. The center-to-center distance between accelerating gaps is .beta..lambda., where .lambda. is the free-space wavelength of the resonant mode. Adjacent accelerating cavities have oppositely directed electric fields, alternating in phase by 180 degrees. The chain of cavities operates in a .pi./2 structure mode so the coupling cavities are nominally unexcited. The CCDTL configuration provides an rf structure with high shunt impedance for intermediate velocity charged particles, i.e., particles with energies in the 20-200 MeV range.

  2. Status report on SHARP coupling framework.

    SciTech Connect (OSTI)

    Caceres, A.; Tautges, T. J.; Lottes, J.; Fischer, P.; Rabiti, C.; Smith, M. A.; Siegel, A.; Yang, W. S.; Palmiotti, G.

    2008-05-30

    This report presents the software engineering effort under way at ANL towards a comprehensive integrated computational framework (SHARP) for high fidelity simulations of sodium cooled fast reactors. The primary objective of this framework is to provide accurate and flexible analysis tools to nuclear reactor designers by simulating multiphysics phenomena happening in complex reactor geometries. Ideally, the coupling among different physics modules (such as neutronics, thermal-hydraulics, and structural mechanics) needs to be tight to preserve the accuracy achieved in each module. However, fast reactor cores in steady state mode represent a special case where weak coupling between neutronics and thermal-hydraulics is usually adequate. Our framework design allows for both options. Another requirement for SHARP framework has been to implement various coupling algorithms that are parallel and scalable to large scale since nuclear reactor core simulations are among the most memory and computationally intensive, requiring the use of leadership-class petascale platforms. This report details our progress toward achieving these goals. Specifically, we demonstrate coupling independently developed parallel codes in a manner that does not compromise performance or portability, while minimizing the impact on individual developers. This year, our focus has been on developing a lightweight and loosely coupled framework targeted at UNIC (our neutronics code) and Nek (our thermal hydraulics code). However, the framework design is not limited to just using these two codes.

  3. Magnetoelastic Coupling and Symmetry Breaking in the Frustrated Antiferromagnet {alpha}-NaMnO{sub 2}

    SciTech Connect (OSTI)

    Giot, Maud; Chapon, Laurent C.; Radaelli, Paolo G.; Androulakis, John; Lappas, Alexandros; Green, Mark A.

    2007-12-14

    The magnetic and crystal structures of the {alpha}-NaMnO{sub 2} have been determined by high-resolution neutron powder diffraction. The system maps out a frustrated triangular spin lattice with anisotropic interactions that displays two-dimensional spin correlations below 200 K. Magnetic frustration is lifted through magneto-elastic coupling, evidenced by strong anisotropic broadening of the diffraction profiles at high temperature and ultimately by a structural phase transition at 45 K. In this low-temperature regime a three-dimensional antiferromagnetic state is observed with a propagation vector k=((1/2),(1/2),0)

  4. Black hole temperature: Minimal coupling vs conformal coupling

    SciTech Connect (OSTI)

    Fazel, Mohamadreza; Mirza, Behrouz; Mansoori, Seyed Ali Hosseini

    2014-05-15

    In this article, we discuss the propagation of scalar fields in conformally transformed spacetimes with either minimal or conformal coupling. The conformally coupled equation of motion is transformed into a one-dimensional Schrödinger-like equation with an invariant potential under conformal transformation. In a second stage, we argue that calculations based on conformal coupling yield the same Hawking temperature as those based on minimal coupling. Finally, it is conjectured that the quasi normal modes of black holes are invariant under conformal transformation.

  5. CX-007561: Categorical Exclusion Determination | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    561: Categorical Exclusion Determination CX-007561: Categorical Exclusion Determination A High Performance Computing "Cyber Wind Facility" Incorporating Fully-Coupled CFD/CSD for Turbine-Platform-Wake Interactions with the Atmosphere and Ocean CX(s) Applied: A9, A11 Date: 01/18/2012 Location(s): Pennsylvania Offices(s): Golden Field Office Pennsylvania State University (PSU) would utilize DOE and cost share funds to develop and integrate central modules of the PSU Cyber Wind Facility

  6. Mobility platform coupling device and method for coupling mobility platforms

    DOE Patents [OSTI]

    Shirey, David L.; Hayward, David R.; Buttz, James H.

    2002-01-01

    A coupling device for connecting a first mobility platform to a second mobility platform in tandem. An example mobility platform is a robot. The coupling device has a loose link mode for normal steering conditions and a locking position, tight link mode for navigation across difficult terrain and across obstacles, for traversing chasms, and for navigating with a reduced footprint in tight steering conditions.

  7. Weak-coupling of the neutron hole in {sup 207}Pb to dipole excitations of {sup 208}Pb

    SciTech Connect (OSTI)

    Fritzsche, M.; Pietralla, N.; Savran, D.; Zweidinger, M.; Ahmed, M. W.; Rusev, G.; Tonchev, A. P.; Weller, H. R.

    2009-01-28

    With the nearly monochromatic, linearly polarized photon beam at the High Intensity {gamma}-ray source (HI{gamma}S) at DFELL photon scattering experiments on {sup 206,207,208}pb have been performed. With these experiments Pb({yields}{gamma},{gamma}') photon scattering reactions could be used to determine spin and parity quantum numbers and therefore study the v(3p{sub 1/2}{sup -1}-hole coupling of {sup 207}Pb to dipole excitations in {sup 208}Pb.

  8. Effects of the running of the QCD coupling on the energy loss in the quark-gluon plasma

    SciTech Connect (OSTI)

    Braun, Jens; Pirner, Hans-Juergen

    2007-03-01

    Finite temperature modifies the running of the QCD coupling {alpha}{sub s}(k,T) with resolution k. After calculating the thermal quark and gluon masses self-consistently, we determine the quark-quark and quark-gluon cross sections in the plasma based on the running coupling. We find that the running coupling enhances these cross sections by factors of two to four depending on the temperature. We also compute the energy loss (dE/dx) of a high-energy quark in the plasma as a function of temperature. Our study suggests that, beside t-channel processes, inverse Compton scattering is a relevant process for a quantitative understanding of the energy loss of an incident quark in a hot plasma.

  9. Simulation Study of Near-Surface Coupling of Nuclear Devices...

    Office of Scientific and Technical Information (OSTI)

    Simulation Study of Near-Surface Coupling of Nuclear Devices vs. Equivalent High-Explosive Charges Citation Details In-Document Search Title: Simulation Study of Near-Surface ...

  10. Simulation Study of Near-Surface Coupling of Nuclear Devices...

    Office of Scientific and Technical Information (OSTI)

    Title: Simulation Study of Near-Surface Coupling of Nuclear Devices vs. Equivalent High-Explosive Charges Authors: Fournier, K B ; Walton, O R ; Benjamin, R ; Dunlop, W H ...

  11. QCD coupling constants and VDM

    SciTech Connect (OSTI)

    Erkol, G.; Ozpineci, A.; Zamiralov, V. S.

    2012-10-23

    QCD sum rules for coupling constants of vector mesons with baryons are constructed. The corresponding QCD sum rules for electric charges and magnetic moments are also derived and with the use of vector-meson-dominance model related to the coupling constants. The VDM role as the criterium of reciprocal validity of the sum rules is considered.

  12. ARPES Provides Direct Evidence of Spin-Wave Coupling

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ARPES Provides Direct Evidence of Spin-Wave Coupling Print The electronic properties of a metal are determined by the dynamical behavior of its conduction electrons. Conventional band theory accounts for the interaction of the electrons with the static ion lattice. However, coupling to further microscopic degrees of freedom can alter the electron dynamics considerably. For example, "conventional" superconductivity emerges as a result of the electrons' interaction with lattice

  13. ARPES Provides Direct Evidence of Spin-Wave Coupling

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ARPES Provides Direct Evidence of Spin-Wave Coupling Print The electronic properties of a metal are determined by the dynamical behavior of its conduction electrons. Conventional band theory accounts for the interaction of the electrons with the static ion lattice. However, coupling to further microscopic degrees of freedom can alter the electron dynamics considerably. For example, "conventional" superconductivity emerges as a result of the electrons' interaction with lattice

  14. ARPES Provides Direct Evidence of Spin-Wave Coupling

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ARPES Provides Direct Evidence of Spin-Wave Coupling Print The electronic properties of a metal are determined by the dynamical behavior of its conduction electrons. Conventional band theory accounts for the interaction of the electrons with the static ion lattice. However, coupling to further microscopic degrees of freedom can alter the electron dynamics considerably. For example, "conventional" superconductivity emerges as a result of the electrons' interaction with lattice

  15. ARPES Provides Direct Evidence of Spin-Wave Coupling

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ARPES Provides Direct Evidence of Spin-Wave Coupling Print The electronic properties of a metal are determined by the dynamical behavior of its conduction electrons. Conventional band theory accounts for the interaction of the electrons with the static ion lattice. However, coupling to further microscopic degrees of freedom can alter the electron dynamics considerably. For example, "conventional" superconductivity emerges as a result of the electrons' interaction with lattice

  16. Combined application of normal and reversed-phase high-performance liquid chromatography to determining the group composition of aromatic hydrocarbons in petroleum products

    SciTech Connect (OSTI)

    Belous, E.F.; Lanin, S.N.; Nikitin, Yu.S.

    1995-01-01

    The quality and working characteristics of motor fuels essentially depend on the concentration of aromatic hydrocarbons (AHs). Therefore, the development of procedures for the group determination of aromatic hydrocarbons is an important and topical problem in the processing and quality control of petroleum products. The aim of this work was to improve the group separation and quantitative determination of monocyclic and bicyclic aromatic hydrocarbons (MAH and BAH) in light-end products.

  17. CX-100363 Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Exclusion Determination CX-100363 Categorical Exclusion Determination Marine Algae Industrialization Consortium (MAGIC): Combining biofuel and high-value bioproducts to...

  18. A Multiscale Bidirectional Coupling Framework

    SciTech Connect (OSTI)

    Kabilan, Senthil; Kuprat, Andrew P.; Hlastala, Michael P.; Corley, Richard A.; Einstein, Daniel R.

    2011-12-01

    The lung is geometrically articulated across multiple scales from the trachea to the alveoli. A major computational challenge is to tightly link ODEs that describe lower scales to 3D finite element or finite volume models of airway mechanics using iterative communication between scales. In this study, we developed a novel multiscale computational framework for bidirectionally coupling 3D CFD models and systems of lower order ODEs. To validate the coupling framework, a four and eight generation Weibel lung model was constructed. For the coupled CFD-ODE simulations, the lung models were truncated at different generations and a RL circuit represented the truncated portion. The flow characteristics from the coupled models were compared to untruncated full 3D CFD models at peak inhalation and peak exhalation. Results showed that at no time or simulation was the difference in mass flux and/or pressure at a given location between uncoupled and coupled models was greater than 2.43%. The flow characteristics at prime locations for the coupled models showed good agreement to uncoupled models. Remarkably, due to reuse of the Krylov subspace, the cost of the ODE coupling is not much greater than uncoupled full 3D-CFD computations with simple prescribed pressure values at the outlets.

  19. Heralding efficiency and correlated-mode coupling of near-IR fiber-coupled photon pairs

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dixon, P. Ben; Rosenberg, Danna; Stelmakh, Veronika; Grein, Matthew E.; Bennink, Ryan S.; Dauler, Eric A.; Kerman, Andrew J.; Molnar, Richard J.; Wong, Franco N. C.

    2014-10-06

    We report on a systematic experimental study of heralding efficiency and generation rate of telecom-band infrared photon pairs generated by spontaneous parametric down-conversion and coupled to single mode optical fibers. We define the correlated-mode coupling efficiency--an inherent source efficiency--and explain its relation to heralding efficiency. For our experiment, we developed a reconfigurable computer controlled pump-beam and collection-mode optical apparatus which we used to measure the generation rate and correlated-mode coupling efficiency. The use of low-noise, high-efficiency superconducting-nanowire single-photon-detectors in this setup allowed us to explore focus configurations with low overall photon flux. The measured data agree well with theory andmore » we demonstrated a correlated-mode coupling efficiency of 97%±2%, which is the highest efficiency yet achieved for this type of system. These results confirm theoretical treatments and demonstrate that very high overall heralding efficiencies can, in principle, be achieved in quantum optical systems. We expect that these results and techniques will be widely incorporated into future systems that require, or benefit from, a high heralding efficiency.« less

  20. Heralding efficiency and correlated-mode coupling of near-IR fiber-coupled photon pairs

    SciTech Connect (OSTI)

    Dixon, P. Ben; Rosenberg, Danna; Stelmakh, Veronika; Grein, Matthew E.; Bennink, Ryan S.; Dauler, Eric A.; Kerman, Andrew J.; Molnar, Richard J.; Wong, Franco N. C.

    2014-10-06

    We report on a systematic experimental study of heralding efficiency and generation rate of telecom-band infrared photon pairs generated by spontaneous parametric down-conversion and coupled to single mode optical fibers. We define the correlated-mode coupling efficiency--an inherent source efficiency--and explain its relation to heralding efficiency. For our experiment, we developed a reconfigurable computer controlled pump-beam and collection-mode optical apparatus which we used to measure the generation rate and correlated-mode coupling efficiency. The use of low-noise, high-efficiency superconducting-nanowire single-photon-detectors in this setup allowed us to explore focus configurations with low overall photon flux. The measured data agree well with theory and we demonstrated a correlated-mode coupling efficiency of 97%±2%, which is the highest efficiency yet achieved for this type of system. These results confirm theoretical treatments and demonstrate that very high overall heralding efficiencies can, in principle, be achieved in quantum optical systems. We expect that these results and techniques will be widely incorporated into future systems that require, or benefit from, a high heralding efficiency.

  1. Heralding efficiency and correlated-mode coupling of near-IR fiber coupled photon pairs

    SciTech Connect (OSTI)

    Dixon, P. Ben; Rosenberg, Danna; Stelmakh, Veronika; Grein, Matthew E.; Bennink, Ryan S; Dauler, Eric A.; Kerman, Andrew J.; Molnar, Richard J.; Wong, Franco N. C.

    2014-01-01

    We report on a systematic experimental study of heralding efficiency and generation rate of telecom-band infrared photon pairs generated by spontaneous parametric down-conversion and coupled to single mode optical fibers. We define the correlated-mode coupling efficiency--an inherent source efficiency--and explain its relation to heralding efficiency. For our experiment, we developed a reconfigurable computer controlled pump-beam and collection-mode optical apparatus which we used to measure the generation rate and correlated-mode coupling efficiency. The use of low-noise, high-efficiency superconducting-nanowire single-photon-detectors in this setup allowed us to explore focus configurations with low overall photon flux. The measured data agree well with theory and we demonstrated a correlated-mode coupling efficiency of 97 +-2%, which is the highest efficiency yet achieved for this type of system. These results confirm theoretical treatments and demonstrate that very high overall heralding efficiencies can, in principle, be achieved in quantum optical systems. It is expected that these results and techniques will be widely incorporated into future systems that require, or benefit from, a high heralding efficiency.

  2. ANTENNA-COUPLED LIGHT-MATTER INTERACTIONS

    SciTech Connect (OSTI)

    NOVOTNY, LUKAS

    2014-01-10

    This project is focused on antenna-coupled photon emission from single quantum emitters. The properties of optical antennas are tailored to control different photophysical parameters, such as the excited state lifetime, the saturation intensity, and the quantum yield [3]. Using a single molecule coupled to an optical antenna whose position and properties can be controllably adjusted we established a detailed and quantitative understanding of light-matter interactions in nanoscale environments. We have studied various quantum emitters: single molecules [11], quantum dots [7], rareearth ions [2], and NV centers in diamond [19]. We have systematically studied the interaction of these emitters with optical antennas. The overall objective was to establish a high-level of control over the light-matter interaction. In order to eliminate the coupling to the environment, we have taken a step further and explored the possibility of levitating the quantum emitter in high vacuum. What started as a side-project soon became a main activity in our research program and led us to the demonstration of vacuum trapping and cooling of a nanoscale particle [14].

  3. Few Electron Quantum Dot coupling ...

    Office of Scientific and Technical Information (OSTI)

    Electron Quantum Dot coupling to Donor Implanted Electron Spins Martin Rudolph1. P. Harvey-Collard12, E. Nielson1, J.K. Gamble1, R. Muller1, T. Jacobson1, G. Ten-Eyck1, J. ...

  4. DRIFT COMPENSATED DIRECT COUPLED AMPLIFIER

    DOE Patents [OSTI]

    Windsor, A.A.

    1959-05-01

    An improved direct-coupled amplifier having zerolevel drift correction is described. The need for an auxiliary corrective-potential amplifier is eliminated thereby giving protection against overload saturation of the zero- level drift correcting circuit. (T.R.H.)

  5. Coupling MM5 with ISOLSM:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Yun (Helen) He 1 Coupling MM5 with ISOLSM: Development, Testing, and Application W.J. Riley, H.S. Cooley, Y. He*, M.S. Torn Lawrence Berkeley National Laboratory June 2003 Yun (Helen) He 2 Outline ! Introduction ! Model Integration ! Model Configuration ! Model Testing ! Simulation and Impacts of Winter Wheat Harvest ! Conclusions ! Observations and Future Work June 2003 Yun (Helen) He 3 Introduction ! CO 2 fluxes and other trace-gas exchanges are tightly coupled to the surface water and energy

  6. Full counting statistics as a probe of quantum coherence in a side-coupled double quantum dot system

    SciTech Connect (OSTI)

    Xue, Hai-Bin

    2013-12-15

    We study theoretically the full counting statistics of electron transport through side-coupled double quantum dot (QD) based on an efficient particle-number-resolved master equation. It is demonstrated that the high-order cumulants of transport current are more sensitive to the quantum coherence than the average current, which can be used to probe the quantum coherence of the considered double QD system. Especially, quantum coherence plays a crucial role in determining whether the super-Poissonian noise occurs in the weak inter-dot hopping coupling regime depending on the corresponding QD-lead coupling, and the corresponding values of super-Poissonian noise can be relatively enhanced when considering the spins of conduction electrons. Moreover, this super-Poissonian noise bias range depends on the singly-occupied eigenstates of the system, which thus suggests a tunable super-Poissonian noise device. The occurrence-mechanism of super-Poissonian noise can be understood in terms of the interplay of quantum coherence and effective competition between fast-and-slow transport channels. -- Highlights: The FCS can be used to probe the quantum coherence of side-coupled double QD system. Probing quantum coherence using FCS may permit experimental tests in the near future. The current noise characteristics depend on the quantum coherence of this QD system. The super-Poissonian noise can be enhanced when considering conduction electron spin. The side-coupled double QD system suggests a tunable super-Poissonian noise device.

  7. The dynamic response of the westward auroral electrojet and polar-cap currents to solar wind-magnetosphere coupling

    SciTech Connect (OSTI)

    Bargatze, L.F.

    1991-01-01

    Results are presented of studies using high-time resolution data to determine the response of magnetospheric currents to coupling with the solar wind. In the first study, the author applies the concept of dimensional analysis to the problem of solar wind-magnetosphere coupling in order to find the dependence of the coupling rate on solar-wind variables. He finds that energy input to the magnetosphere and as represented by the AE indices occurs at a rate proportional to p{sup 1/6}EG({theta}), where p is the solar-wind dynamic pressure, E is the solar-wind motional electric field, and G({theta}) is a leaky' gating function which expresses coupling-rate dependence on the interplanetary magnetic field (IMF) orientation. In the second study, he determines the temporal relationship between the solar wind motional electric field (VB{sub s}) and the westward auroral-electrojet index, AL, by using the linear prediction technique. He finds that the VB{sub s}-AL response filters are composed of two response pulses. He suggests that one response pulse corresponds to AL index activity driven directly by solar wind-magnetosphere interaction, while the other corresponds to activity driven by energy loading and unloading from the magnetotail.

  8. Novel Coupled Thermochronometric and Geochemical Investigation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Novel Coupled Thermochronometric and Geochemical Investigation of Blind Geothermal Resources in Fault-Controlled Dilational Corners Novel Coupled Thermochronometric and Geochemical ...

  9. Suppression of Rayleigh Taylor instability in strongly coupled plasmas

    SciTech Connect (OSTI)

    Das, Amita; Kaw, Predhiman [Institute for Plasma Research, Bhat, Gandhinagar 382428 (India)

    2014-06-15

    The Rayleigh Taylor instability in a strongly coupled plasma medium has been investigated using the equations of generalized hydrodynamics. It is demonstrated that the visco-elasticity of the strongly coupled medium due to strong inter particle correlations leads to a suppression of the Rayleigh Taylor instability unless certain threshold conditions are met. The relevance of these results to experiments on laser compression of matter to high densities including those related to inertial confinement fusion using lasers has also been shown.

  10. Extremely high frequency RF effects on electronics.

    SciTech Connect (OSTI)

    Loubriel, Guillermo Manuel; Vigliano, David; Coleman, Phillip Dale; Williams, Jeffery Thomas; Wouters, Gregg A.; Bacon, Larry Donald; Mar, Alan

    2012-01-01

    The objective of this work was to understand the fundamental physics of extremely high frequency RF effects on electronics. To accomplish this objective, we produced models, conducted simulations, and performed measurements to identify the mechanisms of effects as frequency increases into the millimeter-wave regime. Our purpose was to answer the questions, 'What are the tradeoffs between coupling, transmission losses, and device responses as frequency increases?', and, 'How high in frequency do effects on electronic systems continue to occur?' Using full wave electromagnetics codes and a transmission-line/circuit code, we investigated how extremely high-frequency RF propagates on wires and printed circuit board traces. We investigated both field-to-wire coupling and direct illumination of printed circuit boards to determine the significant mechanisms for inducing currents at device terminals. We measured coupling to wires and attenuation along wires for comparison to the simulations, looking at plane-wave coupling as it launches modes onto single and multiconductor structures. We simulated the response of discrete and integrated circuit semiconductor devices to those high-frequency currents and voltages, using SGFramework, the open-source General-purpose Semiconductor Simulator (gss), and Sandia's Charon semiconductor device physics codes. This report documents our findings.

  11. Determination of active doping in highly resistive boron doped silicon nanocrystals embedded in SiO{sub 2} by capacitance voltage measurement on inverted metal oxide semiconductor structure

    SciTech Connect (OSTI)

    Zhang, Tian Puthen-Veettil, Binesh; Wu, Lingfeng; Jia, Xuguang; Lin, Ziyun; Yang, Terry Chien-Jen; Conibeer, Gavin; Perez-Wurfl, Ivan

    2015-10-21

    We investigate the Capacitance-Voltage (CV) measurement to study the electrically active boron doping in Si nanocrystals (ncSi) embedded in SiO{sub 2}. The ncSi thin films with high resistivity (200–400 Ω cm) can be measured by using an inverted metal oxide semiconductor (MOS) structure (Al/ncSi (B)/SiO{sub 2}/Si). This device structure eliminates the complications from the effects of lateral current flow and the high sheet resistance in standard lateral MOS structures. The characteristic MOS CV curves observed are consistent with the effective p-type doping. The CV modeling method is presented and used to evaluate the electrically active doping concentration. We find that the highly boron doped ncSi films have electrically active doping of 10{sup 18}–10{sup 19 }cm{sup −3} despite their high resistivity. The saturation of doping at about 1.4 × 10{sup 19 }cm{sup −3} and the low doping efficiency less than 5% are observed and discussed. The calculated effective mobility is in the order of 10{sup −3} cm{sup 2}/V s, indicating strong impurity/defect scattering effect that hinders carriers transport.

  12. Planar slot coupled microwave hybrid

    DOE Patents [OSTI]

    Petter, Jeffrey K.

    1991-01-01

    A symmetrical 180.degree. microwave hybrid is constructed by opening a slot line in a ground plane below a conducting strip disposed on a dielectric substrate, creating a slot coupled conductor. Difference signals propagating on the slot coupled conductor are isolated on the slot line leaving sum signals to propagate on the microstrip. The difference signal is coupled from the slot line onto a second microstrip line for transmission to a desired location. The microstrip branches in a symmetrical fashion to provide the input/output ports of the 180.degree. hybrid. The symmetry of the device provides for balance and isolation between sum and difference signals, and provides an advantageous balance between the power handling capabilities and the bandwidth of the device.

  13. Starter for inductively coupled plasma tube

    DOE Patents [OSTI]

    Hull, D.E.; Bieniewski, T.M.

    1988-08-23

    A starter assembly is provided for use with an inductively coupled plasma (ICP) tube to reliably initiate a plasma at internal pressures above about 30 microns. A conductive probe is inserted within the inductor coil about the tube and insulated from the tube shield assembly. A capacitive circuit is arranged for momentarily connecting a high voltage radio-frequency generator to the probe while simultaneously energizing the coil. When the plasma is initiated the probe is disconnected from the generator and electrically connected to the shield assembly for operation. 1 fig.

  14. Starter for inductively coupled plasma tube

    DOE Patents [OSTI]

    Hull, Donald E.; Bieniewski, Thomas M.

    1988-01-01

    A starter assembly is provided for use with an inductively coupled plasma (ICP) tube to reliably initate a plasma at internal pressures above about 30 microns. A conductive probe is inserted within the inductor coil about the tube and insulated from the tube shield assembly. A capacitive circuit is arranged for momentarily connecting a high voltage radio-frequency generator to the probe while simultaneously energizing the coil. When the plasma is initiated the probe is disconnected from the generator and electrically connected to the shield assembly for operation.

  15. Perovskite catalysts for oxidative coupling

    DOE Patents [OSTI]

    Campbell, Kenneth D.

    1991-01-01

    Perovskites of the structure A.sub.2 B.sub.2 C.sub.3 O.sub.10 are useful as catalysts for the oxidative coupling of lower alkane to heavier hydrocarbons. A is alkali metal; B is lanthanide or lanthanum, cerium, neodymium, samarium, praseodymium, gadolinium or dysprosium; and C is titanium.

  16. Magnetically coupled system for mixing

    DOE Patents [OSTI]

    Miller, III, Harlan; Meichel, George; Legere, Edward; Malkiel, Edwin; Woods, Robert Paul; Ashley, Oliver; Katz, Joseph; Ward, Jason; Petersen, Paul

    2015-09-22

    The invention provides a mixing system comprising a magnetically coupled drive system and a foil for cultivating algae, or cyanobacteria, in an open or enclosed vessel. The invention provides effective mixing, low energy usage, low capital expenditure, and ease of drive system component maintenance while maintaining the integrity of a sealed mixing vessel.

  17. Magnetically coupled system for mixing

    SciTech Connect (OSTI)

    Miller, III, Harlan; Meichel, George; Legere, Edward; Malkiel, Edwin; Woods, Robert Paul; Ashley, Oliver; Katz, Joseph; Ward, Jason; Petersen, Paul

    2014-04-01

    The invention provides a mixing system comprising a magnetically coupled drive system and a foil for cultivating algae, or cyanobacteria, in an open or enclosed vessel. The invention provides effective mixing, low energy usage, low capital expenditure, and ease of drive system component maintenance while maintaining the integrity of a sealed mixing vessel.

  18. Perovskite catalysts for oxidative coupling

    DOE Patents [OSTI]

    Campbell, K.D.

    1991-06-25

    Perovskites of the structure A[sub 2]B[sub 2]C[sub 3]O[sub 10] are useful as catalysts for the oxidative coupling of lower alkane to heavier hydrocarbons. A is alkali metal; B is lanthanide or lanthanum, cerium, neodymium, samarium, praseodymium, gadolinium or dysprosium; and C is titanium.

  19. Determination of the effects caused by different polymers on coal fluidity during carbonization using high-temperature {sup 1}H NMR and rheometry

    SciTech Connect (OSTI)

    Miguel Castro Diaz; Lucky Edecki; Karen M. Steel; John W. Patrick; Colin E. Snape

    2008-01-15

    The effects of blending polyethylene (PE), polystyrene (PS), poly(ethyleneterephthalate) (PET), a flexible polyurethane (FPU), and a car shredded fluff waste (CSF) on fluidity development of a bituminous coal during carbonization have been studied by means of high-torque, small-amplitude controlled-strain rheometry and in situ high-temperature {sup 1}H NMR spectroscopy. The most detrimental effects were caused by PET and PS, which completely destroyed the fluidity of the coal. The CSF had a deleterious effect on coal fluidity similar to that of PET, although the deleterious effect on the viscoelastic properties of the coal were less pronounced than those of PET and PS. On the contrary, the addition of 10 wt % PE caused a slight reduction in the concentration of fluid hydrogen and an increase in the minimum complex viscosity, and the addition of 10 wt % FPU reduced the concentration of fluid hydrogen without changing the viscoelastic properties of the coal. Although these results suggest that these two plastics could potentially be used as additives in coking blends without compromising coke porosity, it was found that the semicoke strengths were reduced by adding 2 wt % FPU and 5 wt % PE. Therefore, it is unlikely that more than 2 wt % of a plastic waste could be added to a coal blend without deterioration in coke quality. 35 refs., 11 figs., 3 tabs.

  20. Evidence for a J/psi p anti-p Pauli Strong Coupling?

    SciTech Connect (OSTI)

    Ted Barnes; Winston Roberts

    2008-03-01

    The couplings of charmonia and charmonium hybrids (generically $\\Psi$) to $p\\bar p$ are of great interest in view of future plans to study these states using an antiproton storage ring at GSI. These low to moderate energy $\\Psi p\\bar p$ couplings are not well understood theoretically, and must currently be determined from experiment. In this letter we note that the two independent $p\\bar p$ couplings $\\gamma_{\\mu}$ and $\\sigma_{\\mu\

  1. Nonlinear coupling network to simulate the development of the r-mode instability in neutron stars. I. Construction

    SciTech Connect (OSTI)

    Brink, Jeandrew; Teukolsky, Saul A.; Wasserman, Ira

    2004-12-15

    R-modes of a rotating neutron star are unstable because of the emission of gravitational radiation. We explore the saturation amplitudes of these modes determined by nonlinear mode-mode coupling. Modelling the star as incompressible allows the analytic computation of the coupling coefficients. All couplings up to n=30 are obtained, and analytic values for the shear damping and mode normalization are presented. In a subsequent paper we perform numerical simulations of a large set of coupled modes.

  2. Additive Manufacturing/Diagnostics via the High Frequency Induction Heating of Metal Powders: The Determination of the Power Transfer Factor for Fine Metallic Spheres

    SciTech Connect (OSTI)

    Rios, Orlando; Radhakrishnan, Balasubramaniam; Caravias, George; Holcomb, Matthew

    2015-03-11

    Grid Logic Inc. is developing a method for sintering and melting fine metallic powders for additive manufacturing using spatially-compact, high-frequency magnetic fields called Micro-Induction Sintering (MIS). One of the challenges in advancing MIS technology for additive manufacturing is in understanding the power transfer to the particles in a powder bed. This knowledge is important to achieving efficient power transfer, control, and selective particle heating during the MIS process needed for commercialization of the technology. The project s work provided a rigorous physics-based model for induction heating of fine spherical particles as a function of frequency and particle size. This simulation improved upon Grid Logic s earlier models and provides guidance that will make the MIS technology more effective. The project model will be incorporated into Grid Logic s power control circuit of the MIS 3D printer product and its diagnostics technology to optimize the sintering process for part quality and energy efficiency.

  3. Atomic arrangement at ZnTe/CdSe interfaces determined by high resolution scanning transmission electron microscopy and atom probe tomography

    SciTech Connect (OSTI)

    Bonef, Bastien; Rouvire, Jean-Luc; Jouneau, Pierre-Henri; Bellet-Amalric, Edith; Grard, Lionel; Mariette, Henri; Andr, Rgis; Bougerol, Catherine; Grenier, Adeline

    2015-02-02

    High resolution scanning transmission electron microscopy and atom probe tomography experiments reveal the presence of an intermediate layer at the interface between two binary compounds with no common atom, namely, ZnTe and CdSe for samples grown by Molecular Beam Epitaxy under standard conditions. This thin transition layer, of the order of 1 to 3 atomic planes, contains typically one monolayer of ZnSe. Even if it occurs at each interface, the direct interface, i.e., ZnTe on CdSe, is sharper than the reverse one, where the ZnSe layer is likely surrounded by alloyed layers. On the other hand, a CdTe-like interface was never observed. This interface knowledge is crucial to properly design superlattices for optoelectronic applications and to master band-gap engineering.

  4. Verification of Multiphysics software: Space and time convergence studies for nonlinearly coupled applications

    SciTech Connect (OSTI)

    Jean C. Ragusa; Vijay Mahadevan; Vincent A. Mousseau

    2009-05-01

    High-fidelity modeling of nuclear reactors requires the solution of a nonlinear coupled multi-physics stiff problem with widely varying time and length scales that need to be resolved correctly. A numerical method that converges the implicit nonlinear terms to a small tolerance is often referred to as nonlinearly consistent (or tightly coupled). This nonlinear consistency is still lacking in the vast majority of coupling techniques today. We present a tightly coupled multiphysics framework that tackles this issue and present code-verification and convergence analyses in space and time for several models of nonlinear coupled physics.

  5. Method for determining gene knockouts

    DOE Patents [OSTI]

    Maranas, Costas D.; Burgard, Anthony R.; Pharkya, Priti

    2011-09-27

    A method for determining candidates for gene deletions and additions using a model of a metabolic network associated with an organism, the model includes a plurality of metabolic reactions defining metabolite relationships, the method includes selecting a bioengineering objective for the organism, selecting at least one cellular objective, forming an optimization problem that couples the at least one cellular objective with the bioengineering objective, and solving the optimization problem to yield at least one candidate.

  6. Method for determining gene knockouts

    DOE Patents [OSTI]

    Maranas, Costa D; Burgard, Anthony R; Pharkya, Priti

    2013-06-04

    A method for determining candidates for gene deletions and additions using a model of a metabolic network associated with an organism, the model includes a plurality of metabolic reactions defining metabolite relationships, the method includes selecting a bioengineering objective for the organism, selecting at least one cellular objective, forming an optimization problem that couples the at least one cellular objective with the bioengineering objective, and solving the optimization problem to yield at least one candidate.

  7. Spin-phonon coupling and high-pressure phase transitions of RMnO3 (R=Ca and Pr): An inelastic neutron scattering and first-principles study

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mishra, S. K.; Gupta, M. K.; Mittal, R.; Kolesnikov, Alexander I.; Chaplot, S. L.

    2016-06-22

    Here, we report inelastic neutron scattering measurements over 7–1251 K in CaMnO3 covering various phase transitions, and over 6–150 K in PrMnO3 covering the magnetic transition. The excitations around 20 meV in CaMnO3 and at 17 meV in PrMnO3 at low temperatures are found to be associated with magnetic origin. We observe coherent magnetic neutron scattering in localized regions in reciprocal space and show it to arise from long-range correlated magnetic spin-waves below the magnetic transition temperature (TN) and short-range stochastic spin-spin fluctuations above TN. In spite of the similarity of the structure of the two compounds, the neutron inelasticmore » spectrum of PrMnO3 exhibits broad features at 150 K unlike well-defined peaks in the spectrum of CaMnO3. This might result from the difference in the nature of interactions in the two compounds (magnetic and Jahn-Teller distortion). Ab initio phonon calculations have been used to interpret the observed phonon spectra. The ab initio calculations at high pressures show that the variations of Mn-O distances are isotropic for CaMnO3 and highly anisotropic for PrMnO3. The calculation in PrMnO3 shows the suppression of Jahn-Teller distortion and simultaneous insulator-to-metal transition. It appears that this transition may not be associated with the occurrence of the tetragonal phase above 20 GPa as reported in the literature, since the tetragonal phase is found to be dynamically unstable, although it is found to be energetically favored over the orthorhombic phase above 20 GPa. CaMnO3 does not show any phase transition up to 60 GPa.« less

  8. Coupling for a fuel manifold

    SciTech Connect (OSTI)

    Elsworth, J.K.; Nownahal, A.; Wilson, K.

    1987-11-24

    A coupling is described for a fuel manifold defining a fuel line passageway, comprising a tube connector which extends between the ends of two manifold segments to connect the fuel line passageway. The tube connector sealingly fits within end portions of the fuel line passageway at the ends of respective manifold segments; a retractable sleeve sealingly engages over the ends of the respective manifold segments, thus enclosing the tube connector and defining a space therewith. Locking means are provided between the tube and sleeve such that any sliding movement of the sleeve will cause corresponding sliding movement of the tube. The end portions of the fuel line passageway accommodate the tube connector in axial sliding relationship and the length of the tube connector is such as to allow connecting or disconnecting of the coupling by sliding the sleeve and the tube connector without moving the manifold segments.

  9. Rotational and translational temperature equilibrium in an inductively coupled plasma

    SciTech Connect (OSTI)

    Shimada, Masashi; Tynan, George R.; Cattolica, Robert

    2006-09-15

    Rotational temperature has been used widely as neutral gas temperature measurement in different types of plasmas (electron cyclotron resonance, inductively coupled plasma, helicon, hollow cathode, etc.), and has been assumed to be in equilibrium with translational temperature. The direct experimental comparison of rotational and translational temperature in low-temperature plasmas has not been reported. In this research, optical emission spectroscopy is used to measure the neutral gas rotational temperature, T{sub rot}, from the second-positive band of a nitrogen molecule (380 nm). The results are compared with the Doppler-broadened translational temperature, T{sub trans}, of Ar (750 nm) and He (587 nm), determined with a high-resolution spectrometer at various partial pressures of N{sub 2} in Ar/N{sub 2} and He/N{sub 2} plasmas. The results demonstrated that T{sub rot} and T{sub trans} are in equilibrium in the conditions [10{sup 10}

  10. High temperature aqueous stress corrosion testing device

    DOE Patents [OSTI]

    Bornstein, A.N.; Indig, M.E.

    1975-12-01

    A description is given of a device for stressing tensile samples contained within a high temperature, high pressure aqueous environment, thereby permitting determination of stress corrosion susceptibility of materials in a simple way. The stressing device couples an external piston to an internal tensile sample via a pull rod, with stresses being applied to the sample by pressurizing the piston. The device contains a fitting/seal arrangement including Teflon and weld seals which allow sealing of the internal system pressure and the external piston pressure. The fitting/seal arrangement allows free movement of the pull rod and the piston.

  11. North Pacific Mesoscale Coupled Air-Ocean Simulations Compared with Observations

    SciTech Connect (OSTI)

    Koracin, Darko; Cerovecki, Ivana; Vellore, Ramesh; Mejia, John; Hatchett, Benjamin; McCord, Travis; McLean, Julie; Dorman, Clive

    2013-04-11

    Executive summary The main objective of the study was to investigate atmospheric and ocean interaction processes in the western Pacific and, in particular, effects of significant ocean heat loss in the Kuroshio and Kuroshio Extension regions on the lower and upper atmosphere. It is yet to be determined how significant are these processes are on climate scales. The understanding of these processes led us also to development of the methodology of coupling the Weather and Research Forecasting model with the Parallel Ocean Program model for western Pacific regional weather and climate simulations. We tested NCAR-developed research software Coupler 7 for coupling of the WRF and POP models and assessed its usability for regional-scale applications. We completed test simulations using the Coupler 7 framework, but implemented a standard WRF model code with options for both one- and two-way mode coupling. This type of coupling will allow us to seamlessly incorporate new WRF updates and versions in the future. We also performed a long-term WRF simulation (15 years) covering the entire North Pacific as well as high-resolution simulations of a case study which included extreme ocean heat losses in the Kuroshio and Kuroshio Extension regions. Since the extreme ocean heat loss occurs during winter cold air outbreaks (CAO), we simulated and analyzed a case study of a severe CAO event in January 2000 in detail. We found that the ocean heat loss induced by CAOs is amplified by additional advection from mesocyclones forming on the southern part of the Japan Sea. Large scale synoptic patterns with anomalously strong anticyclone over Siberia and Mongolia, deep Aleutian Low, and the Pacific subtropical ridge are a crucial setup for the CAO. It was found that the onset of the CAO is related to the breaking of atmospheric Rossby waves and vertical transport of vorticity that facilitates meridional advection. The study also indicates that intrinsic parameterization of the surface fluxes

  12. CX-003520: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    20: Categorical Exclusion Determination CX-003520: Categorical Exclusion Determination Pontiac High School Geothermal CX(s) Applied: B5.1 Date: 08262010 Location(s): Pontiac, ...

  13. CX-100635 Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    5 Categorical Exclusion Determination CX-100635 Categorical Exclusion Determination Enabling Automation for <0.10W High-Efficiency Kerfless Wafers Manufactured in the U.S. Award ...

  14. CX-004024: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    24: Categorical Exclusion Determination CX-004024: Categorical Exclusion Determination Backside Contact Multijunction Solar Cells for High Concentration Applications CX(s) Applied: ...

  15. CX-100275 Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    75 Categorical Exclusion Determination CX-100275 Categorical Exclusion Determination High Performance Building Envelope Assemblies Award Number: DE- EE0007054, 7059, 7060 CX(s) ...

  16. Instabilities in a capacitively coupled oxygen plasma

    SciTech Connect (OSTI)

    Küllig, C. Wegner, Th. Meichsner, J.

    2015-04-15

    Periodic fluctuations in the frequency range from 0.3 to 3 kHz were experimentally investigated in capacitively coupled radio frequency (13.56 MHz) oxygen plasma. The Gaussian beam microwave interferometry directly provides the line integrated electron density fluctuations. A system of two Langmuir probes measured the floating potential spatially (axial, radial) and temporally resolved. Hence, the floating potential fluctuation development is mapped within the discharge volume and provides a kind of discharge breathing and no wave propagation. Finally, it was measured the optical emission pattern of atomic oxygen during the fluctuation as well as the RF phase resolved optical emission intensity at selected phase position of the fluctuation by an intensified charge-coupled device camera. The deduced excitation rate pattern reveals the RF sheath dynamics and electron heating mechanisms, which is changing between low and high electronegativity during a fluctuation cycle. A perturbation calculation was taken into account using a global model with 15 elementary collision processes in the balance equations for the charged plasma species (O{sub 2}{sup +}, e, O{sup −}, O{sub 2}{sup −}) and a harmonic perturbation. The calculated frequencies agree with the experimentally observed frequencies. Whereby, the electron attachment/detachment processes are important for the generation of this instability.

  17. The Challenges to Coupling Dynamic Geospatial Models

    SciTech Connect (OSTI)

    Goldstein, N

    2006-06-23

    Many applications of modeling spatial dynamic systems focus on a single system and a single process, ignoring the geographic and systemic context of the processes being modeled. A solution to this problem is the coupled modeling of spatial dynamic systems. Coupled modeling is challenging for both technical reasons, as well as conceptual reasons. This paper explores the benefits and challenges to coupling or linking spatial dynamic models, from loose coupling, where information transfer between models is done by hand, to tight coupling, where two (or more) models are merged as one. To illustrate the challenges, a coupled model of Urbanization and Wildfire Risk is presented. This model, called Vesta, was applied to the Santa Barbara, California region (using real geospatial data), where Urbanization and Wildfires occur and recur, respectively. The preliminary results of the model coupling illustrate that coupled modeling can lead to insight into the consequences of processes acting on their own.

  18. Polarity of annealing and structural analysis of the RNase H resistant alpha-5'-d(TACACA). beta-5'-r(AUGUGU) hybrid determined by high-field sup 1 H, sup 13 C, and sup 31 P NMR analysis

    SciTech Connect (OSTI)

    Gmeiner, W.H.; Rao, K.E.; Rayner, B.; Vasseur, J.J.; Morvan, F.; Imbach, J.L.; Lown, J.W. )

    1990-11-13

    The novel hybrid duplex alpha-5'-d(TACACA)-3'.beta-5'-r(AUGUGU)-3' was analyzed extensively by 1D and 2D NMR methods. Two forms of the duplex exist in about an 80:20 ratio. Analysis of the exchangeable imino protons of the major component revealed that three AU and one AT base pair are present in addition to two GC base pairs, confirming that the duplex anneals in parallel orientation. The presence of the AT base pair, which can only be accounted for by a parallel duplex, was confirmed by a selective INEPT experiment, which correlated the thymidine imino proton to its C5 carbon. The lesser antiparallel form could be detected by exchangeable and nonexchangeable proton resonances in both strands. An exchange peak was observed in the NOESY spectrum for the thymidine methyl group resonance in both the predominant and lesser conformations, indicating the lifetime of the individual structures was on the millisecond time scale. The nonexchangeable protons of the predominant duplex were assigned by standard methods. The sugar pucker of the ribonucleosides was determined to be of the S type by a pseudorotation analysis according to Altona, with the J-couplings measured from the multiplet components of the phase-sensitive COSY experiment. The NOE pattern observed for the alpha-deoxynucleosides also suggested an S-type sugar pucker. The adoption of an S-type sugar pucker for both strands indicates that, in contrast to RNA.DNA duplexes formed exclusively from beta-nucleotides, the alpha-DNA.beta-RNA duplex may form a B-type helix. The 31P resonances of the alpha and beta strands have very different chemical shifts in the hybrid duplex and the difference persists above the helix melting temperature, indicating an intrinsic difference in 31P chemical shift for nucleotides differing only in the configuration about the glycosidic bond.

  19. Vapor phase modifiers for oxidative coupling

    DOE Patents [OSTI]

    Warren, Barbara K.

    1991-01-01

    Volatilized metal compounds retard vapor phase alkane conversion reactions in oxidative coupling processes that convert lower alkanes to higher hydrocarbons.

  20. Dynamical coupled-channel analysis at EBAC

    SciTech Connect (OSTI)

    T.-S. H. Lee

    2007-08-01

    The status and progress of the dynamical coupled-channel analysis at the Excited Baryon Analysis Center (EBAC) is reported.

  1. Coupling device for pressurized fluid connections

    DOE Patents [OSTI]

    van Boxtel, R.P.; Yayanos, A.A.

    1984-01-01

    Quick-coupling device for high pressure connections, comprising a cylindrical adapter member, closed at an outer end thereof, the opposite end being attachable to a pressure fitting, and an aperture therein spaced from the closed end of the adapter member. The device also comprises a coupler body having a first passageway therein for slidably receiving the outer end of the adapter, a central portion of said passageway being in communication with the adapter aperture, a pair of seal members disposed on opposite sides of the central portion of the passageway to provide a seal between the coupler body and the adapter member, and a second passageway in said coupler body in communication with said central portion.

  2. Strong-Coupling Resistivity in the Kondo Model

    SciTech Connect (OSTI)

    Lesage, F.; Saleur, H.

    1999-05-01

    By applying methods of integrable quantum field theory to the Kondo problem, we develop a systematic perturbation expansion near the IR (strong coupling) fixed point. This requires knowledge of an infinity of irrelevant operators and their couplings, which we determine exactly. A low temperature expansion (i.e., all the corrections to Fermi liquid theory) of the resistivity follows, extending the well-known Nozi{grave e}res T{sup 2} result in the exactly screened case to arbitrary order. The example of the ordinary Kondo model is worked out in detail: We determine {rho} up to order T{sup 6} and compare the result with available numerical data. {copyright} {ital 1999} {ital The American Physical Society}

  3. Erratum to: Constraining couplings of top quarks to the Z boson in $$ t\\overline{t} $$ + Z production at the LHC

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Röntsch, Raoul; Schulze, Markus

    2015-09-21

    We study top quark pair production in association with a Z boson at the Large Hadron Collider (LHC) and investigate the prospects of measuring the couplings of top quarks to the Z boson. To date these couplings have not been constrained in direct measurements. Such a determination will be possible for the first time at the LHC. Our calculation improves previous coupling studies through the inclusion of next-to-leading order (NLO) QCD corrections in production and decays of all unstable particles. We treat top quarks in the narrow-width approximation and retain all NLO spin correlations. To determine the sensitivity of amore » coupling measurement we perform a binned log-likelihood ratio test based on normalization and shape information of the angle between the leptons from the Z boson decay. The obtained limits account for statistical uncertainties as well as leading theoretical systematics from residual scale dependence and parton distribution functions. We use current CMS data to place the first direct constraints on the ttbZ couplings. We also consider the upcoming high-energy LHC run and find that with 300 inverse fb of data at an energy of 13 TeV the vector and axial ttbZ couplings can be constrained at the 95% confidence level to C_V=0.24^{+0.39}_{-0.85} and C_A=-0.60^{+0.14}_{-0.18}, where the central values are the Standard Model predictions. This is a reduction of uncertainties by 25% and 42%, respectively, compared to an analysis based on leading-order predictions. We also translate these results into limits on dimension-six operators contributing to the ttbZ interactions beyond the Standard Model.« less

  4. Coupling effects in inductive discharges with radio frequency substrate biasing

    SciTech Connect (OSTI)

    Schulze, J.; Schuengel, E.; Czarnetzki, U.

    2012-01-09

    Low pressure inductively coupled plasmas (ICP) operated in neon at 27.12 MHz with capacitive substrate biasing (CCP) at 13.56 MHz are investigated by phase resolved optical emission spectroscopy, voltage, and current measurements. Three coupling mechanisms are found potentially limiting the separate control of ion energy and flux: (i) Sheath heating due to the substrate biasing affects the electron dynamics even at high ratios of ICP to CCP power. At fixed CCP power, (ii) the substrate sheath voltage and (iii) the amplitude as well as frequency of plasma series resonance oscillations of the RF current are affected by the ICP power.

  5. Investigation of Coupled Processes and Impact of High Temperature...

    Office of Scientific and Technical Information (OSTI)

    APA Chicago Bibtex Export Metadata Endnote Excel CSV XML Save to My Library Send to Email Send to Email Email address: Content: Close Send Cite: MLA Format Close Cite: APA ...

  6. Two photon couplings of the lightest isoscalars from BELLE data

    SciTech Connect (OSTI)

    Dai, Ling -Yun; Pennington, Michael R.

    2014-07-07

    Amplitude Analysis of two photon production of ππ and K¯K, using S-matrix constraints and fitting all available data, including the latest precision results from Belle, yields a single partial wave solution up to 1.4 GeV. The two photon couplings of the σ/f0(500), f0(980) and f2(1270) are determined from the residues of the resonance poles.

  7. Two photon couplings of the lightest isoscalars from BELLE data

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dai, Ling -Yun; Pennington, Michael R.

    2014-07-07

    Amplitude Analysis of two photon production of ππ and K¯K, using S-matrix constraints and fitting all available data, including the latest precision results from Belle, yields a single partial wave solution up to 1.4 GeV. The two photon couplings of the σ/f0(500), f0(980) and f2(1270) are determined from the residues of the resonance poles.

  8. A multilingual programming model for coupled systems.

    SciTech Connect (OSTI)

    Ong, E. T.; Larson, J. W.; Norris, B.; Tobis, M.; Steder, M.; Jacob, R. L.; Mathematics and Computer Science; Univ. of Wisconsin; Univ. of Chicago; The Australian National Univ.

    2008-01-01

    Multiphysics and multiscale simulation systems share a common software requirement-infrastructure to implement data exchanges between their constituent parts-often called the coupling problem. On distributed-memory parallel platforms, the coupling problem is complicated by the need to describe, transfer, and transform distributed data, known as the parallel coupling problem. Parallel coupling is emerging as a new grand challenge in computational science as scientists attempt to build multiscale and multiphysics systems on parallel platforms. An additional coupling problem in these systems is language interoperability between their constituent codes. We have created a multilingual parallel coupling programming model based on a successful open-source parallel coupling library, the Model Coupling Toolkit (MCT). This programming model's capabilities reach beyond MCT's native Fortran implementation to include bindings for the C++ and Python programming languages. We describe the method used to generate the interlanguage bindings. This approach enables an object-based programming model for implementing parallel couplings in non-Fortran coupled systems and in systems with language heterogeneity. We describe the C++ and Python versions of the MCT programming model and provide short examples. We report preliminary performance results for the MCT interpolation benchmark. We describe a major Python application that uses the MCT Python bindings, a Python implementation of the control and coupling infrastructure for the community climate system model. We conclude with a discussion of the significance of this work to productivity computing in multidisciplinary computational science.

  9. Robust, High-Throughput Analysis of Protein Structures

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Robust, High-Throughput Analysis of Protein Structures Print Scientists have developed a fast and efficient way to determine the structure of proteins, shortening a process that often takes years into a matter of days. The Structurally Integrated BiologY for Life Sciences (SIBYLS) beamline at the ALS has implemented the world's highest-throughput biological-solution x-ray scattering beamline enabling genomic-scale protein-structure characterization. Coupling brilliant x rays from one of the

  10. Robust, High-Throughput Analysis of Protein Structures

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Robust, High-Throughput Analysis of Protein Structures Print Scientists have developed a fast and efficient way to determine the structure of proteins, shortening a process that often takes years into a matter of days. The Structurally Integrated BiologY for Life Sciences (SIBYLS) beamline at the ALS has implemented the world's highest-throughput biological-solution x-ray scattering beamline enabling genomic-scale protein-structure characterization. Coupling brilliant x rays from one of the

  11. Robust, High-Throughput Analysis of Protein Structures

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Robust, High-Throughput Analysis of Protein Structures Print Scientists have developed a fast and efficient way to determine the structure of proteins, shortening a process that often takes years into a matter of days. The Structurally Integrated BiologY for Life Sciences (SIBYLS) beamline at the ALS has implemented the world's highest-throughput biological-solution x-ray scattering beamline enabling genomic-scale protein-structure characterization. Coupling brilliant x rays from one of the

  12. Robust, High-Throughput Analysis of Protein Structures

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Robust, High-Throughput Analysis of Protein Structures Print Scientists have developed a fast and efficient way to determine the structure of proteins, shortening a process that often takes years into a matter of days. The Structurally Integrated BiologY for Life Sciences (SIBYLS) beamline at the ALS has implemented the world's highest-throughput biological-solution x-ray scattering beamline enabling genomic-scale protein-structure characterization. Coupling brilliant x rays from one of the

  13. Robust, High-Throughput Analysis of Protein Structures

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Robust, High-Throughput Analysis of Protein Structures Print Scientists have developed a fast and efficient way to determine the structure of proteins, shortening a process that often takes years into a matter of days. The Structurally Integrated BiologY for Life Sciences (SIBYLS) beamline at the ALS has implemented the world's highest-throughput biological-solution x-ray scattering beamline enabling genomic-scale protein-structure characterization. Coupling brilliant x rays from one of the

  14. Circuit electromechanics with single photon strong coupling

    SciTech Connect (OSTI)

    Xue, Zheng-Yuan Yang, Li-Na; Zhou, Jian

    2015-07-13

    In circuit electromechanics, the coupling strength is usually very small. Here, replacing the capacitor in circuit electromechanics by a superconducting flux qubit, we show that the coupling among the qubit and the two resonators can induce effective electromechanical coupling which can attain the strong coupling regime at the single photon level with feasible experimental parameters. We use dispersive couplings among two resonators and the qubit while the qubit is also driven by an external classical field. These couplings form a three-wave mixing configuration among the three elements where the qubit degree of freedom can be adiabatically eliminated, and thus results in the enhanced coupling between the two resonators. Therefore, our work constitutes the first step towards studying quantum nonlinear effect in circuit electromechanics.

  15. Rapid determination of actinides in seawater samples

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Maxwell, Sherrod L.; Culligan, Brian K.; Hutchison, Jay B.; Utsey, Robin C.; McAlister, Daniel R.

    2014-03-09

    A new rapid method for the determination of actinides in seawater samples has been developed at the Savannah River National Laboratory. The actinides can be measured by alpha spectrometry or inductively-coupled plasma mass spectrometry. The new method employs novel pre-concentration steps to collect the actinide isotopes quickly from 80 L or more of seawater. Actinides are co-precipitated using an iron hydroxide co-precipitation step enhanced with Ti+3 reductant, followed by lanthanum fluoride co-precipitation. Stacked TEVA Resin and TRU Resin cartridges are used to rapidly separate Pu, U, and Np isotopes from seawater samples. TEVA Resin and DGA Resin were used tomore » separate and measure Pu, Am and Cm isotopes in seawater volumes up to 80 L. This robust method is ideal for emergency seawater samples following a radiological incident. It can also be used, however, for the routine analysis of seawater samples for oceanographic studies to enhance efficiency and productivity. In contrast, many current methods to determine actinides in seawater can take 1–2 weeks and provide chemical yields of ~30–60 %. This new sample preparation method can be performed in 4–8 h with tracer yields of ~85–95 %. By employing a rapid, robust sample preparation method with high chemical yields, less seawater is needed to achieve lower or comparable detection limits for actinide isotopes with less time and effort.« less

  16. Transverse Mode Coupling Instability with Space Charge (Journal...

    Office of Scientific and Technical Information (OSTI)

    Transverse Mode Coupling Instability with Space Charge Citation Details In-Document Search Title: Transverse Mode Coupling Instability with Space Charge Transverse mode coupling ...

  17. Mobile inductively coupled plasma system

    DOE Patents [OSTI]

    D'Silva, Arthur P. (Ames, IA); Jaselskis, Edward J. (Ames, IA)

    1999-03-30

    A system for sampling and analyzing a material located at a hazardous site. A laser located remote from the hazardous site is connected to an optical fiber, which directs laser radiation proximate the material at the hazardous site. The laser radiation abates a sample of the material. An inductively coupled plasma is located remotely from the material. An aerosol transport system carries the ablated particles to a plasma, where they are dissociated, atomized and excited to provide characteristic optical reduction of the elemental constituents of the sample. An optical spectrometer is located remotely from the site. A second optical fiber is connected to the optical spectrometer at one end and the plasma source at the other end to carry the optical radiation from the plasma source to the spectrometer.

  18. Welding shield for coupling heaters

    DOE Patents [OSTI]

    Menotti, James Louis

    2010-03-09

    Systems for coupling end portions of two elongated heater portions and methods of using such systems to treat a subsurface formation are described herein. A system may include a holding system configured to hold end portions of the two elongated heater portions so that the end portions are abutted together or located near each other; a shield for enclosing the end portions, and one or more inert gas inlets configured to provide at least one inert gas to flush the system with inert gas during welding of the end portions. The shield may be configured to inhibit oxidation during welding that joins the end portions together. The shield may include a hinged door that, when closed, is configured to at least partially isolate the interior of the shield from the atmosphere. The hinged door, when open, is configured to allow access to the interior of the shield.

  19. Mobile inductively coupled plasma system

    DOE Patents [OSTI]

    D`Silva, A.P.; Jaselskis, E.J.

    1999-03-30

    A system is described for sampling and analyzing a material located at a hazardous site. A laser located remotely from the hazardous site is connected to an optical fiber, which directs laser radiation proximate the material at the hazardous site. The laser radiation abates a sample of the material. An inductively coupled plasma is located remotely from the material. An aerosol transport system carries the ablated particles to a plasma, where they are dissociated, atomized and excited to provide characteristic optical reduction of the elemental constituents of the sample. An optical spectrometer is located remotely from the site. A second optical fiber is connected to the optical spectrometer at one end and the plasma source at the other end to carry the optical radiation from the plasma source to the spectrometer. 10 figs.

  20. CAN COUPLED DARK ENERGY SPEED UP THE BULLET CLUSTER?

    SciTech Connect (OSTI)

    Lee, Jounghun; Baldi, Marco E-mail: marco.baldi@universe-cluster.de

    2012-03-01

    It has been recently shown that the observed morphological properties of the Bullet Cluster can be accurately reproduced in hydrodynamical simulations only when the infall pairwise velocity V{sub c} of the system exceeds 3000 km s{sup -1} (or at least possibly 2500 km s{sup -1}) at the pair separation of 2R{sub vir}, where R{sub vir} is the virial radius of the main cluster, and that the probability of finding such a bullet-like system is extremely low in the standard {Lambda} cold dark matter ({Lambda}CDM) cosmology. We suggest here the fifth force mediated by coupled dark energy (cDE) as a possible velocity-enhancing mechanism and investigate its effect on the infall velocities of bullet-like systems from the Coupled Dark Energy Cosmological Simulations public database. Five different cDE models are considered: three with constant coupling and exponential potential, one with exponential coupling and exponential potential, and one with constant coupling and supergravity potential. For each model, after identifying the bullet-like systems, we determine the probability density distribution of their infall velocities at pair separations of (2-3)R{sub vir}. Approximating each probability density distribution as a Gaussian, we calculate the cumulative probability of finding a bullet-like system with V{sub c} {>=} 3000 km s{sup -1} or V{sub c} {>=} 2500 km s{sup -1}. Our results show that in all of the five cDE models the cumulative probabilities increase compared to the {Lambda}CDM case and that in the model with exponential coupling P(V{sub c} {>=} 2500 km s{sup -1}) exceeds 10{sup -4}. The physical interpretations and cosmological implications of our results are provided.

  1. Coupled Fluid Energy Solute Transport

    Energy Science and Technology Software Center (OSTI)

    1992-02-13

    CFEST is a Coupled Fluid, Energy, and Solute Transport code for the study of a multilayered, nonisothermal ground-water system. It can model discontinuous as well as continuous layers, time-dependent and constant source/sinks, and transient as well as steady-state flow. The finite element method is used for analyzing isothermal and nonisothermal events in a confined aquifer system. Only single-phase Darcian flow is considered. In the Cartesian coordinate system, flow in a horizontal plane, in a verticalmore » plane, or in a fully three-dimensional region can be simulated. An option also exists for the axisymmetric analysis of a vertical cross section. The code employs bilinear quadrilateral elements in all two dimensional analyses and trilinear quadrilateral solid elements in three dimensional simulations. The CFEST finite element formulation can approximate discontinuities, major breaks in slope or thickness, and fault zones in individual hydrogeologic units. The code accounts for heterogeneity in aquifer permeability and porosity and accommodates anisotropy (collinear with the Cartesian coordinates). The variation in the hydraulic properties is described on a layer-by-layer basis for the different hydrogeologic units. Initial conditions can be prescribed hydraulic head or pressure, temperature, or concentration. CFEST can be used to support site, repository, and waste package subsystem assessments. Some specific applications are regional hydrologic characterization; simulation of coupled transport of fluid, heat, and salinity in the repository region; consequence assessment due to natural disruption or human intrusion scenarios in the repository region; flow paths and travel-time estimates for transport of radionuclides; and interpretation of well and tracer tests.« less

  2. Graphene-coated coupling coil for AC resistance reduction

    DOE Patents [OSTI]

    Miller, John M

    2014-03-04

    At least one graphene layer is formed to laterally surround a tube so that the basal plane of each graphene layer is tangential to the local surface of the tube on which the graphene layer is formed. An electrically conductive path is provided around the tube for providing high conductivity electrical path provided by the basal plane of each graphene layer. The high conductivity path can be employed for high frequency applications such as coupling coils for wireless power transmission to overcome skin depth effects and proximity effects prevalent in high frequency alternating current paths.

  3. Approaching total absorption at near infrared in a large area monolayer graphene by critical coupling

    SciTech Connect (OSTI)

    Liu, Yonghao; Chadha, Arvinder; Zhao, Deyin; Shuai, Yichen; Menon, Laxmy; Yang, Hongjun; Zhou, Weidong; Piper, Jessica R.; Fan, Shanhui; Jia, Yichen; Xia, Fengnian; Ma, Zhenqiang

    2014-11-03

    We demonstrate experimentally close to total absorption in monolayer graphene based on critical coupling with guided resonances in transfer printed photonic crystal Fano resonance filters at near infrared. Measured peak absorptions of 35% and 85% were obtained from cavity coupled monolayer graphene for the structures without and with back reflectors, respectively. These measured values agree very well with the theoretical values predicted with the coupled mode theory based critical coupling design. Such strong light-matter interactions can lead to extremely compact and high performance photonic devices based on large area monolayer graphene and other twodimensional materials.

  4. Dense strongly coupled plasma in double laser pulse ablation of lithium: Experiment and simulation

    SciTech Connect (OSTI)

    Kumar, Ajai; Sivakumaran, V.; Ganesh, R.; Joshi, H. C. [Institute for Plasma Research, Bhat, Gandhinagar-382428 (India)] [Institute for Plasma Research, Bhat, Gandhinagar-382428 (India); Ashwin, J. [Weizmann Institute of Science, Rehovot - 76100 (Israel)] [Weizmann Institute of Science, Rehovot - 76100 (Israel)

    2013-08-15

    In a simple method of low power nano-second double pulsed laser ablation experiment in collinear geometry, formation of high density strongly coupled plasma is demonstrated. Using time-resolved measurements of the Stark broadened line width and line intensity ratio of the emission lines, the density and temperature of the plasma were estimated respectively. In this experiment, it is shown that ions are strongly coupled (ion-ion coupling parameter comes out to be >4). For comparison, both single and double pulsed laser ablations are presented. For the estimated experimental plasma parameters, first principle Langevin dynamics simulation corroborates the existence of a strongly coupled regime.

  5. Strong Local-Nonlocal Coupling for Integrated Fracture Modeling

    SciTech Connect (OSTI)

    Littlewood, David John; Silling, Stewart A.; Mitchell, John A.; Seleson, Pablo D.; Bond, Stephen D.; Parks, Michael L.; Turner, Daniel Z.; Burnett, Damon J.; Ostien, Jakob; Gunzburger, Max

    2015-09-01

    Peridynamics, a nonlocal extension of continuum mechanics, is unique in its ability to capture pervasive material failure. Its use in the majority of system-level analyses carried out at Sandia, however, is severely limited, due in large part to computational expense and the challenge posed by the imposition of nonlocal boundary conditions. Combined analyses in which peridynamics is em- ployed only in regions susceptible to material failure are therefore highly desirable, yet available coupling strategies have remained severely limited. This report is a summary of the Laboratory Directed Research and Development (LDRD) project "Strong Local-Nonlocal Coupling for Inte- grated Fracture Modeling," completed within the Computing and Information Sciences (CIS) In- vestment Area at Sandia National Laboratories. A number of challenges inherent to coupling local and nonlocal models are addressed. A primary result is the extension of peridynamics to facilitate a variable nonlocal length scale. This approach, termed the peridynamic partial stress, can greatly reduce the mathematical incompatibility between local and nonlocal equations through reduction of the peridynamic horizon in the vicinity of a model interface. A second result is the formulation of a blending-based coupling approach that may be applied either as the primary coupling strategy, or in combination with the peridynamic partial stress. This blending-based approach is distinct from general blending methods, such as the Arlequin approach, in that it is specific to the coupling of peridynamics and classical continuum mechanics. Facilitating the coupling of peridynamics and classical continuum mechanics has also required innovations aimed directly at peridynamic models. Specifically, the properties of peridynamic constitutive models near domain boundaries and shortcomings in available discretization strategies have been addressed. The results are a class of position-aware peridynamic constitutive laws for

  6. Advanced multiphysics coupling for LWR fuel performance analysis

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hales, J. D.; Tonks, M. R.; Gleicher, F. N.; Spencer, B. W.; Novascone, S. R.; Williamson, R. L.; Pastore, G.; Perez, D. M.

    2015-10-01

    Even the most basic nuclear fuel analysis is a multiphysics undertaking, as a credible simulation must consider at a minimum coupled heat conduction and mechanical deformation. The need for more realistic fuel modeling under a variety of conditions invariably leads to a desire to include coupling between a more complete set of the physical phenomena influencing fuel behavior, including neutronics, thermal hydraulics, and mechanisms occurring at lower length scales. This paper covers current efforts toward coupled multiphysics LWR fuel modeling in three main areas. The first area covered in this paper concerns thermomechanical coupling. The interaction of these two physics,more » particularly related to the feedback effect associated with heat transfer and mechanical contact at the fuel/clad gap, provides numerous computational challenges. An outline is provided of an effective approach used to manage the nonlinearities associated with an evolving gap in BISON, a nuclear fuel performance application. A second type of multiphysics coupling described here is that of coupling neutronics with thermomechanical LWR fuel performance. DeCART, a high-fidelity core analysis program based on the method of characteristics, has been coupled to BISON. DeCART provides sub-pin level resolution of the multigroup neutron flux, with resonance treatment, during a depletion or a fast transient simulation. Two-way coupling between these codes was achieved by mapping fission rate density and fast neutron flux fields from DeCART to BISON and the temperature field from BISON to DeCART while employing a Picard iterative algorithm. Finally, the need for multiscale coupling is considered. Fission gas production and evolution significantly impact fuel performance by causing swelling, a reduction in the thermal conductivity, and fission gas release. The mechanisms involved occur at the atomistic and grain scale and are therefore not the domain of a fuel performance code. However, it is

  7. Advanced multiphysics coupling for LWR fuel performance analysis

    SciTech Connect (OSTI)

    Hales, J. D.; Tonks, M. R.; Gleicher, F. N.; Spencer, B. W.; Novascone, S. R.; Williamson, R. L.; Pastore, G.; Perez, D. M.

    2015-10-01

    Even the most basic nuclear fuel analysis is a multiphysics undertaking, as a credible simulation must consider at a minimum coupled heat conduction and mechanical deformation. The need for more realistic fuel modeling under a variety of conditions invariably leads to a desire to include coupling between a more complete set of the physical phenomena influencing fuel behavior, including neutronics, thermal hydraulics, and mechanisms occurring at lower length scales. This paper covers current efforts toward coupled multiphysics LWR fuel modeling in three main areas. The first area covered in this paper concerns thermomechanical coupling. The interaction of these two physics, particularly related to the feedback effect associated with heat transfer and mechanical contact at the fuel/clad gap, provides numerous computational challenges. An outline is provided of an effective approach used to manage the nonlinearities associated with an evolving gap in BISON, a nuclear fuel performance application. A second type of multiphysics coupling described here is that of coupling neutronics with thermomechanical LWR fuel performance. DeCART, a high-fidelity core analysis program based on the method of characteristics, has been coupled to BISON. DeCART provides sub-pin level resolution of the multigroup neutron flux, with resonance treatment, during a depletion or a fast transient simulation. Two-way coupling between these codes was achieved by mapping fission rate density and fast neutron flux fields from DeCART to BISON and the temperature field from BISON to DeCART while employing a Picard iterative algorithm. Finally, the need for multiscale coupling is considered. Fission gas production and evolution significantly impact fuel performance by causing swelling, a reduction in the thermal conductivity, and fission gas release. The mechanisms involved occur at the atomistic and grain scale and are therefore not the domain of a fuel performance code. However, it is possible to use

  8. Interface effect in coupled quantum wells

    SciTech Connect (OSTI)

    Hao, Ya-Fei

    2014-06-28

    This paper intends to theoretically investigate the effect of the interfaces on the Rashba spin splitting of two coupled quantum wells. The results show that the interface related Rashba spin splitting of the two coupled quantum wells is both smaller than that of a step quantum well which has the same structure with the step quantum well in the coupled quantum wells. And the influence of the cubic Dresselhaus spin-orbit interaction of the coupled quantum wells is larger than that of a step quantum well. It demonstrates that the spin relaxation time of the two coupled quantum wells will be shorter than that of a step quantum well. As for the application in the spintronic devices, a step quantum well may be better than the coupled quantum wells, which is mentioned in this paper.

  9. Joint used for coupling long heaters

    DOE Patents [OSTI]

    Menottie, James Louis

    2013-02-26

    Systems for coupling ends of elongated heaters and methods of using such systems to treat a subsurface formation are described herein. A system may include two elongated heaters with an end portion of one heater abutted or near to an end portion of the other heater and a core coupling material. The core coupling material may extend between the two elongated heaters. The elongated heaters may include cores and at least one conductor substantially concentrically surrounds the cores. The cores may have a lower melting point than the conductors. At least one end portion of the conductor may have a beveled edge. The gap formed by the beveled edge may be filled with a coupling material for coupling the one or more conductors. One end portion of at least one core may have a recessed opening and the core coupling material may be partially inside the recessed opening.

  10. CX-011104: Categorical Exclusion Determination | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Coupled Thermo-Mechanical and Photo-Chemical Degradation Mechanisms that Determine the Reliability and Operational Lifetimes for Concentrated Photovoltaic Technologies CX(s) Applied: A9, B3.6 Date: 08/29/2013 Location(s): California Offices(s): Golden Field Office The U.S. Department of Energy (DOE) is proposing to provide federal funding to Stanford University to develop coupled thermo-mechanical and photo-chemical degradation mechanisms that determine the reliability and operational lifetimes