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Note: This page contains sample records for the topic "determination catalytic transformation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Catalytic Transformation of Waste Carbon Dioxide into Valuable Products  

NLE Websites -- All DOE Office Websites (Extended Search)

Catalytic Transformation of Waste Catalytic Transformation of Waste Carbon Dioxide into Valuable Products Background Many industrial processes contribute large amounts of carbon dioxide (CO 2 ) to the earth's atmosphere. In an effort to reduce the amount of CO 2 released to the atmosphere, the U.S. Department of Energy (DOE) is funding efforts to develop CO 2 capture and storage technologies. In addition to permanent storage of CO 2 in underground reservoirs, some

2

Catalytic transformation of cellulose into platform chemicals  

Science Journals Connector (OSTI)

Conversion of biomass to renewable and valuable chemicals has attracted global interest in order to build up sustainable societies. Cellulose is the most abundant and non-food biomass; however, the low reactivity of cellulose has prevented its use in chemical industry except for the paper manufacturing. The heterogeneous catalysis for the conversion of cellulose has been expected to overcome this issue, because various types of heterogeneous catalysts can be designed and applied in a wide range of reaction conditions. Furthermore, solid catalysts are easily recovered and reused. In this review article, we show the present situation and perspective of heterogeneous catalysis for the transformation of cellulose into useful platform chemicals.

Mizuho Yabushita; Hirokazu Kobayashi; Atsushi Fukuoka

2014-01-01T23:59:59.000Z

3

Catalytic transformations of cellulose and its derived carbohydrates into 5-hydroxymethylfurfural, levulinic acid, and lactic acid  

Science Journals Connector (OSTI)

The catalytic transformation of cellulose into key building-block or platform chemicals such as 5-hydoxymethylfurfural (HMF), levulinic acid, and lactic acid under mild conditions, has attracted much attention...

Weiping Deng; Qinghong Zhang; Ye Wang

2014-12-01T23:59:59.000Z

4

Hydrodeoxygenation processes: Advances on catalytic transformations of biomass-derived platform chemicals into hydrocarbon fuels  

Science Journals Connector (OSTI)

Abstract Lignocellulosic biomass provides an attractive source of renewable carbon that can be sustainably converted into chemicals and fuels. Hydrodeoxygenation (HDO) processes have recently received considerable attention to upgrade biomass-derived feedstocks into liquid transportation fuels. The selection and design of HDO catalysts plays an important role to determine the success of the process. This review has been aimed to emphasize recent developments on HDO catalysts in effective transformations of biomass-derived platform molecules into hydrocarbon fuels with reduced oxygen content and improved H/C ratios. Liquid hydrocarbon fuels can be obtained by combining oxygen removal processes (e.g. dehydration, hydrogenation, hydrogenolysis, decarbonylation etc.) as well as by increasing the molecular weight via C–C coupling reactions (e.g. aldol condensation, ketonization, oligomerization, hydroxyalkylation etc.). Fundamentals and mechanistic aspects of the use of HDO catalysts in deoxygenation reactions will also be discussed.

Sudipta De; Basudeb Saha; Rafael Luque

2014-01-01T23:59:59.000Z

5

Principles of water oxidation and O2-based hydrocarbon transformation by multinuclear catalytic sites  

SciTech Connect

Abstract The central thrust of this integrated experimental and computational research program was to obtain an atomistic-level understanding of the structural and dynamic factors underlying the design of catalysts for water oxidation and selective reductant-free O2-based transformations. The focus was on oxidatively robust polyoxometalate (POM) complexes in which a catalytic active site interacts with proximal metal centers in a synergistic manner. Thirty five publications in high-impact journals arose from this grant. I. Developing an oxidatively and hydrolytically stable and fast water oxidation catalyst (WOC), a central need in the production of green fuels using water as a reductant, has proven particularly challenging. During this grant period we have designed and investigated several carbon-free, molecular (homogenous), oxidatively and hydrolytically stable WOCs, including the Rb8K2[{Ru4O4(OH)2(H2O)4}(?-SiW10O36)2]·25H2O (1) and [Co4(H2O)2(?-PW9O34)2]10- (2). Although complex 1 is fast, oxidatively and hydrolytically stable WOC, Ru is neither abundant nor inexpensive. Therefore, development of a stable and fast carbon-free homogenous WOC, based on earth-abundant elements became our highest priority. In 2010, we reported the first such catalyst, complex 2. This complex is substantially faster than 1 and stable under homogeneous conditions. Recently, we have extended our efforts and reported a V2-analog of the complex 2, i.e. [Co4(H2O)2(?-VW9O34)2]10- (3), which shows an even greater stability and reactivity. We succeeded in: (a) immobilizing catalysts 1 and 2 on the surface of various electrodes, and (b) elucidating the mechanism of O2 formation and release from complex 1, as well as the Mn4O4L6 “cubane” cluster. We have shown that the direct O-O bond formation is the most likely pathway for O2 formation during water oxidation catalyzed by 1. II. Oxo transfer catalysts that contain two proximal and synergistically interacting redox active metal centers in the active site form another part of considerable interest of our grant because species with such sites [including methane monooxygenase (MMO) and more] are some of the most effective oxygenase catalysts known. Our team conducted the following research on ?-M2-Keggin complexes: (a) investigated stability of the trimer [{Fe3(OH)3(H2O)2}3(?-SiW10O36)3]15-, 4, in water, and developed the chemistry and catalysis of the di-iron centered POM, [?(1,2)-SiW10{Fe(OH)}2O38]6-, 5, in organic solvents (Figure 2). We also study the thermodynamic and structural stability of ?-M2-Keggin in aqueous media for different M’s (d-electron metals). We have defined two structural classes of POMs with proximally bound d-electron metal centers. We refer to these structural isomers of the {?-M2SiW10} family of POMs as “in-pocket” and “out-of pocket”. We have elucidated the factors controlling the structure and stability of the V, Fe, Ru, Tc, Mo and Rh derivatives of [(SiO4)M2(OH)2W10O32]4- using a range of computational tools. We have: (a) demonstrated that heteroatom X in these polyanions may function as an “internal switch” for defining the ground electronic states and, consequently, the reactivity of the ?-M2-Keggin POM complexes; (b) elucidated reactivity of divacant lacunary species and polyperoxotungstates (PPTs), {Xn+O4[WO(O2)2]4}n-, which could be degradation products of ?-M2-Keggin complexes in aqueous media; (c) elucidated the role of the POM ligand in stabilization of {Ru2} and {(Ru-oxo)2} fragments in the reactant and product of the reaction of {?-[(Xn+O4)Ru2(OH)2W10O32]}(8-n)- (where X = Si4+, P5+ and S6+) with O2, and (d) the mechanisms of olefin epoxidation catalyzed by these di-d-transition metal substituted and divacant lacunary ?-M2-Keggin complexes. III. Complementing the efforts presented above was the development of less time-consuming but reasonably accurate computational methods allowing one to explore more deeply large catalytic systems. We developed Reactive Force Field (ReaxFF) to study interaction of the targeted POMs with water, pro

Musaev, Djamaladdin G [Chemistry, Emory University; Hill, Craig L [Chemistry, Emory University; Morokuma, Keiji [Chemistry, Emory University

2014-10-28T23:59:59.000Z

6

Determination analysis of energy conservation standards for distribution transformers  

SciTech Connect

This report contains information for US DOE to use in making a determination on proposing energy conservation standards for distribution transformers as required by the Energy Policy Act of 1992. Potential for saving energy with more efficient liquid-immersed and dry-type distribution transformers could be significant because these transformers account for an estimated 140 billion kWh of the annual energy lost in the delivery of electricity. Objective was to determine whether energy conservation standards for distribution transformers would have the potential for significant energy savings, be technically feasible, and be economically justified from a national perspective. It was found that energy conservation for distribution transformers would be technically and economically feasible. Based on the energy conservation options analyzed, 3.6-13.7 quads of energy could be saved from 2000 to 2030.

Barnes, P.R.; Van Dyke, J.W.; McConnell, B.W.; Das, S.

1996-07-01T23:59:59.000Z

7

A VSP transformation technique for the determination of subsurface structure  

E-Print Network (OSTI)

is the dominant wavelength. With the surface reflection profiling technique, resolution typically ranges from tens to hundreds of meters. With this degree of resolution, a detailed understanding of the subsurface is hard to achieve, In a vertical seismic... Chairman of Advisory Committee: Dr. Terry W. Spencer An algorithm was developed which transforms a vertical seismic profile (VSP) from the time-depth domain into the offset-time domain. The procedure operates by calculating the dips of the reflectors...

Malloy, Jeffrey Edward

2012-06-07T23:59:59.000Z

8

Shear Transformation Zones: State Determined or Protocol Dependent?  

E-Print Network (OSTI)

The concept of a Shear Transformation Zone (STZ) refers to a region in an amorphous solid that undergoes a plastic event when the material is put under an external mechanical load. An important question that had accompanied the development of the theory of plasticity in amorphous solids for many years now is whether an STZ is a {\\em region} existing in the material (which can be predicted by analyzing the unloaded material), or is it an {\\em event} that depends on the loading protocol (i.e., the event cannot be predicted without following the protocol itself). In this Letter we present strong evidence that the latter is the case. Infinitesimal changes of protocol result in macroscopically big jumps in the positions of plastic events, meaning that these can never be predicted from considering the unloaded material.

Oleg Gendelman; Prabhat K. Jaiswal; Itamar Procaccia; Bhaskar Sen Gupta; Jacques Zylberg

2014-08-18T23:59:59.000Z

9

CSD: Research: Catalytic Science  

NLE Websites -- All DOE Office Websites (Extended Search)

Catalytic Science Catalytic Science The DOE Chemical Energy program supports basic research in the area of chemical transformations or conversions which are fundamental to new or existing concepts of energy production and storage. A further goal of the program is to identify and develop environmentally benign approaches to the synthesis of chemicals via routes requiring a minimal consumption of energy. These objectives lead naturally to an emphasis on catalysis. Novel homogeneous and heterogeneous catalysts are constantly being sought to enable the synthesis of desired products from nontraditional reactants, often with the aim of minimizing the production of toxic intermediates or byproducts, or to enable the more efficient production of products via existing reaction pathways. To this end, efforts are undertaken to

10

Catalytic dehydromethylation of methylcyclohexane and the simultaneous transformation of fractions of straight-run gasoline and methanol with modified forms of mordenite and pentasil  

Science Journals Connector (OSTI)

Results are presented from studies of the dehydromethylation (DHM) of methylcyclohexane (MCH) and the simultaneous transformation of straight-run gasoline fractions and methanol on modified forms of...2, CO2). Hi...

Kh. M. Alimardanov; F. M. Velieva; S. I. Abasov; N. M. Ragimova

2014-07-01T23:59:59.000Z

11

CATALYTIC BIOMASS LIQUEFACTION  

E-Print Network (OSTI)

LBL-11 019 UC-61 CATALYTIC BIOMASS LIQUEFACTION Sabri Ergun,Catalytic Liquefaction of Biomass,n M, Seth, R. Djafar, G.of California. CATALYTIC BIOMASS LIQUEFACTION QUARTERLY

Ergun, Sabri

2013-01-01T23:59:59.000Z

12

Supplement to the ``determination analysis`` (ORNL-6847) and analysis of the NEMA efficiency standard for distribution transformers  

SciTech Connect

This report contains additional information for use by the US Department of Energy in making a determination on proposing energy conservation standards for distribution transformers as required by the Energy Policy Act of 1992. An earlier determination study by the Oak Ridge National Laboratory determined that cost-effective, technically feasible energy savings could be achieved by distribution transformer standards and that these savings are significant relative to other product conservation standards. This study was documented in a final report, ``Determination Analysis of Energy Conservation Standards for Distribution Transformers`` (ORNL-6847, July 1996). The energy conservation options analyzed in this study were estimated to save 5.2 to 13.7 quads from 2000--2030. The energy savings for the determination study cases have been revised downward for a number of reasons. The transformer market, both present and future, was overestimated in the previous study, particularly for dry-type transformers, which have the greatest energy-saving potential. Moreover, a revision downwards of the effective annual loads for utility owned transformers also results in lower energy savings. The present study assesses four of the five conservation cases from the earlier determination study as well as the National Electrical Manufacturers Association energy efficiency standard NEMA TP 1-1996 using the updated data and a more accurate disaggregated analysis model. According to these new estimates, the savings ranged from 2.5 to 10.7 quads of primary energy for the 30-year period 2004 to 2034. For the TP-1 case, data were available to calculate the payback period required to recover the extra cost from the value of the energy saved. The average payback period based on the average national cost of electricity is 2.76 years. 15 figs., 23 tabs.

Barnes, P.R.; Das, S.; McConnell, B.W.; Van Dyke, J.W.

1997-09-01T23:59:59.000Z

13

Catalytic reactor  

DOE Patents (OSTI)

A catalytic reactor is provided with one or more reaction zones each formed of set(s) of reaction tubes containing a catalyst to promote chemical reaction within a feed stream. The reaction tubes are of helical configuration and are arranged in a substantially coaxial relationship to form a coil-like structure. Heat exchangers and steam generators can be formed by similar tube arrangements. In such manner, the reaction zone(s) and hence, the reactor is compact and the pressure drop through components is minimized. The resultant compact form has improved heat transfer characteristics and is far easier to thermally insulate than prior art compact reactor designs. Various chemical reactions are contemplated within such coil-like structures such that as steam methane reforming followed by water-gas shift. The coil-like structures can be housed within annular chambers of a cylindrical housing that also provide flow paths for various heat exchange fluids to heat and cool components.

Aaron, Timothy Mark (East Amherst, NY); Shah, Minish Mahendra (East Amherst, NY); Jibb, Richard John (Amherst, NY)

2009-03-10T23:59:59.000Z

14

Catalytic Coherence  

Science Journals Connector (OSTI)

Because of conservation of energy we cannot directly turn a quantum system with a definite energy into a superposition of different energies. However, if we have access to an additional resource in terms of a system with a high degree of coherence, as for standard models of laser light, we can overcome this limitation. The question is to what extent coherence gets degraded when utilized. Here it is shown that coherence can be turned into a catalyst, meaning that we can use it repeatedly without ever diminishing its power to enable coherent operations. This finding stands in contrast to the degradation of other quantum resources and has direct consequences for quantum thermodynamics, as it shows that latent energy that may be locked into superpositions of energy eigenstates can be released catalytically.

Johan Åberg

2014-10-07T23:59:59.000Z

15

Can the Wigner function be determined by properties for translation and parity transformation on lattice phase space?  

E-Print Network (OSTI)

We show that the Fano operator for one dimensional quantum system is uniquely determined by assuming the reasonable behavior under translation and parity transformation on phase space. Contrarily, for the system with lattice phase space the same procedure does not work.

Minoru Horibe; Takaaki Hashimoto; Akihisa Hayashi

2002-08-07T23:59:59.000Z

16

Flow-Through Fourier Transform Infrared Sensor for Total Hydrocarbons Determination in Water  

Science Journals Connector (OSTI)

A new flow-through Fourier transform infrared (FT-IR) sensor for oil in water analysis based on solid-phase spectroscopy on octadecyl (C18) silica particles has been developed. The C18...

Pérez-Palacios, David; Armenta, Sergio; Lendl, Bernhard

2009-01-01T23:59:59.000Z

17

Determining angular frequency from images of rotating objects via a generalized fast Fourier transform  

Science Journals Connector (OSTI)

In certain real-world applications, one needs to estimate the angular frequency of a spinning object. We consider the image processing problem of estimating this rate of rotation from a video of the object taken by a camera aligned with the axis of rotation. ... Keywords: Angular frequency, Fast fourier transform, Rate of rotation

Lindsay N. Smith; Matthew Fickus

2014-02-01T23:59:59.000Z

18

CATALYTIC LIQUEFACTION OF BIOMASS  

E-Print Network (OSTI)

liquid Fuels from Biomass: "Catalyst Screening and KineticUC-61 (l, RCO osn CDL or BIOMASS CATALYTIC LIQUEFACTION ManuCATALYTIC LIQUEFACTION OF BIOMASS Manu Seth, Roger Djafar,

Seth, Manu

2012-01-01T23:59:59.000Z

19

CATALYTIC BIOMASS LIQUEFACTION  

E-Print Network (OSTI)

Solvent Systems Catalystic Biomass Liquefaction Investigatereactor Product collection Biomass liquefaction process12-13, 1980 CATALYTIC BIOMASS LIQUEFACTION Sabri Ergun,

Ergun, Sabri

2013-01-01T23:59:59.000Z

20

Catalytic Transformation of Biomass in Ionic Liquids  

Science Journals Connector (OSTI)

5-Hydroxymethylfurfural (HMF) can be produced from poly- and monohexoses and is a valuable platform chemical that can be used to make polymers, fuels, and commodity chemicals (Fig. 8.7). HMF is the product of the...

Blair J. Cox; John G. Ekerdt

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "determination catalytic transformation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Rich catalytic injection  

DOE Patents (OSTI)

A gas turbine engine includes a compressor, a rich catalytic injector, a combustor, and a turbine. The rich catalytic injector includes a rich catalytic device, a mixing zone, and an injection assembly. The injection assembly provides an interface between the mixing zone and the combustor. The injection assembly can inject diffusion fuel into the combustor, provides flame aerodynamic stabilization in the combustor, and may include an ignition device.

Veninger, Albert (Coventry, CT)

2008-12-30T23:59:59.000Z

22

Cumene by catalytic distillation  

SciTech Connect

Catalytic distillation, a combination of catalytic reaction and distillation in a single column, has several advantages when used in a process to make cumene from benzene and propylene. An extremely high purity cumene is obtained in high yield. The catalytic distillation principle was used in an earlier process to make MTBE. A unit, started up up in Houston refinery in 1981, operated successfully for four years. Since then, three other MTBE units of this design have gone into service.

Shoemaker, J.D.; Jones, E.M. Jr.

1987-06-01T23:59:59.000Z

23

Determination of Asphaltenes in Petroleum Crude Oils by Fourier Transform Infrared Spectroscopy  

Science Journals Connector (OSTI)

Marathon-Ashland Petroleum L.L.C., Research, Applications, and Development, P.O. ... The FT-IR asphaltene absorption bands were determined by analyzing the asphaltene fraction, the deasphalted oil (DAO), and a 50% asphaltene/50% DAO sample for each of 5 crude oils (MES, MYA, EIC, CTX, STF) used in the calibration set. ...

Brian K. Wilt; William T. Welch; J. Graham Rankin

1998-08-13T23:59:59.000Z

24

Catalytic distillation structure  

SciTech Connect

Catalytic distillation structure for use in reaction distillation columns, a providing reaction sites and distillation structure and consisting of a catalyst component and a resilient component intimately associated therewith. The resilient component has at least about 70 volume % open space and being present with the catalyst component in an amount such that the catalytic distillation structure consist of at least 10 volume % open space.

Smith, Jr., Lawrence A. (Bellaire, TX)

1984-01-01T23:59:59.000Z

25

Categorical Exclusion Determinations: American Recovery and Reinvestment  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

22, 2010 22, 2010 CX-000710: Categorical Exclusion Determination Virginia Revision 3 - Economic Development Market Title CX(s) Applied: A9, A11, B5.1 Date: 01/22/2010 Location(s): Virginia Office(s): Energy Efficiency and Renewable Energy, National Energy Technology Laboratory January 22, 2010 CX-000735: Categorical Exclusion Determination Catalytic Transformation of Waste Carbon Dioxide into Valuable Products CX(s) Applied: A9, B3.6 Date: 01/22/2010 Location(s): Newtown Square, Pennsylvania Office(s): Fossil Energy, National Energy Technology Laboratory January 22, 2010 CX-000736: Categorical Exclusion Determination Catalytic Transformation of Waste Carbon Dioxide into Valuable Products CX(s) Applied: A9, B3.6 Date: 01/22/2010 Location(s): Cincinnati, Ohio Office(s): Fossil Energy, National Energy Technology Laboratory

26

Catalytic distillation process  

DOE Patents (OSTI)

A method is described for conducting chemical reactions and fractionation of the reaction mixture comprising feeding reactants to a distillation column reactor into a feed zone and concurrently contacting the reactants with a fixed bed catalytic packing to concurrently carry out the reaction and fractionate the reaction mixture. For example, a method for preparing methyl tertiary butyl ether in high purity from a mixed feed stream of isobutene and normal butene comprising feeding the mixed feed stream to a distillation column reactor into a feed zone at the lower end of a distillation reaction zone, and methanol into the upper end of said distillation reaction zone, which is packed with a properly supported cationic ion exchange resin, contacting the C[sub 4] feed and methanol with the catalytic distillation packing to react methanol and isobutene, and concurrently fractionating the ether from the column below the catalytic zone and removing normal butene overhead above the catalytic zone.

Smith, L.A. Jr.

1982-06-22T23:59:59.000Z

27

Catalytic distillation process  

DOE Patents (OSTI)

A method for conducting chemical reactions and fractionation of the reaction mixture comprising feeding reactants to a distillation column reactor into a feed zone and concurrently contacting the reactants with a fixed bed catalytic packing to concurrently carry out the reaction and fractionate the reaction mixture. For example, a method for preparing methyl tertiary butyl ether in high purity from a mixed feed stream of isobutene and normal butene comprising feeding the mixed feed stream to a distillation column reactor into a feed zone at the lower end of a distillation reaction zone, and methanol into the upper end of said distillation reaction zone, which is packed with a properly supported cationic ion exchange resin, contacting the C.sub.4 feed and methanol with the catalytic distillation packing to react methanol and isobutene, and concurrently fractionating the ether from the column below the catalytic zone and removing normal butene overhead above the catalytic zone.

Smith, Jr., Lawrence A. (Bellaire, TX)

1982-01-01T23:59:59.000Z

28

Catalytic Combustion Processes  

Science Journals Connector (OSTI)

This work presents experimental data on the effect of catalytic additives on the combustion characteristics of ammonium nitrate and perchlorate and the explosives of different classes. Burning rates are determ...

A. P. Glaskova

1991-01-01T23:59:59.000Z

29

Catalytic distillation structure  

DOE Patents (OSTI)

Catalytic distillation structure is described for use in reaction distillation columns, and provides reaction sites and distillation structure consisting of a catalyst component and a resilient component intimately associated therewith. The resilient component has at least about 70 volume % open space and is present with the catalyst component in an amount such that the catalytic distillation structure consists of at least 10 volume % open space. 10 figs.

Smith, L.A. Jr.

1984-04-17T23:59:59.000Z

30

Regenerative catalytic oxidation  

SciTech Connect

Currently Regenerative Thermal Oxidizers (R.T.O.`s) are an accepted technology for the control of volatile organic compounds (VOC`s) and hazardous air pollutants (HAP`s). This control technology, when introduced, offered substantial reductions in operating costs, especially auxiliary fuel requirements when compared to existing control technologies such as recuperative thermal and recuperative catalytic oxidizers. While these savings still exist, there is a demand for control of new and/or hybrid technologies, one of which is Regenerative Catalytic Oxidizers (R.C.O.`s). This paper will explore the development of regenerative catalytic oxidation from the theoretical stage through pilot testing through a commercial installation. The operating cost of R.C.O.`s will be compared to R.T.O.`s to verify the savings that are achievable through the use of regenerative catalytic oxidation. In the development of this technology, which is a combination of two (2) existing technologies, R.T.O.`s and catalysis, a second hybrid technology was explored and pilot tested. This is a combination R.C.O. for VOC and HAP control and simultaneous SCR (Selective Catalytic Reduction) for NOx (Oxides of Nitrogen) control. Based on the pilot and full scale testing, both regenerative catalytic oxidizers and systems which combine R.C.O. with SCR for both VOC and NOx reduction are economically viable and are in fact commercially available. 6 figs., 2 tabs.

Gribbon, S.T. [Engelhard Process Emission Systems, South Lyon, MI (United States)

1996-12-31T23:59:59.000Z

31

Catalytic nanoporous membranes  

DOE Patents (OSTI)

A nanoporous catalytic membrane which displays several unique features Including pores which can go through the entire thickness of the membrane. The membrane has a higher catalytic and product selectivity than conventional catalysts. Anodic aluminum oxide (AAO) membranes serve as the catalyst substrate. This substrate is then subjected to Atomic Layer Deposition (ALD), which allows the controlled narrowing of the pores from 40 nm to 10 nm in the substrate by deposition of a preparatory material. Subsequent deposition of a catalytic layer on the inner surfaces of the pores reduces pore sizes to less than 10 nm and allows for a higher degree of reaction selectivity. The small pore sizes allow control over which molecules enter the pores, and the flow-through feature can allow for partial oxidation of reactant species as opposed to complete oxidation. A nanoporous separation membrane, produced by ALD is also provided for use in gaseous and liquid separations. The membrane has a high flow rate of material with 100% selectivity. Also provided is a method for producing a catalytic membrane having flow-through pores and discreet catalytic clusters adhering to the inside surfaces of the pores.

Pellin, Michael J; Hryn, John N; Elam, Jeffrey W

2013-08-27T23:59:59.000Z

32

Catalytic Solutions Inc CSI | Open Energy Information  

Open Energy Info (EERE)

Developer of the breakthrough catalytic coating technology and the Mixed Phase Catalyst (MPCTM), and also manufacturer of catalytic converters. References: Catalytic...

33

Catalytic Coal Gasification Process  

NLE Websites -- All DOE Office Websites (Extended Search)

Catalytic Coal Gasification Process Catalytic Coal Gasification Process for the Production of Methane-Rich Syngas Opportunity Research is active on the patent pending technology, titled "Production of Methane-Rich Syngas from Fuels Using Multi-functional Catalyst/Capture Agent." This technology is available for licensing and/or further collaborative research from the U.S. Department of Energy's National Energy Technology Laboratory. Overview Reducing pollution emitted by coal and waste power plants in an economically viable manner and building power plants that co-generate fuels and chemicals during times of low electricity demand are pressing goals for the energy industry. One way to achieve these goals in an economically viable manner is through the use of a catalytic gasifier that

34

VOC Destruction by Catalytic Combustion Microturbine  

SciTech Connect

This project concerned the application of a catalytic combustion system that has been married to a micro-turbine device. The catalytic combustion system decomposes the VOC's and transmits these gases to the gas turbine. The turbine has been altered to operate on very low-level BTU fuels equivalent to 1.5% methane in air. The performance of the micro-turbine for VOC elimination has some flexibility with respect to operating conditions, and the system is adaptable to multiple industrial applications. The VOC source that was been chosen for examination was the emissions from coal upgrading operations. The overall goal of the project was to examine the effectiveness of a catalytic combustion based system for elimination of VOCs while simultaneously producing electrical power for local consumption. Project specific objectives included assessment of the feasibility for using a Flex-Microturbine that generates power from natural gas while it consumes VOCs generated from site operations; development of an engineering plan for installation of the Flex-Microturbine system; operation of the micro-turbine through various changes in site and operation conditions; measurement of the VOC destruction quantitatively; and determination of the required improvements for further studies. The micro-turbine with the catalytic bed worked effectively to produce power on levels of fuel much lower than the original turbine design. The ability of the device to add or subtract supplemental fuel to augment the amount of VOC's in the inlet air flow made the device an effective replacement for a traditional flare. Concerns about particulates in the inlet flow and the presence of high sulfur concentrations with the VOC mixtures was identified as a drawback with the current catalytic design. A new microturbine design was developed based on this research that incorporates a thermal oxidizer in place of the catalytic bed for applications where particulates or contamination would limit the lifetime of the catalytic bed.

Tom Barton

2009-03-10T23:59:59.000Z

35

Transform Analysis Using the definition of the Laplace transform, Laplace transform properties, and the integral  

E-Print Network (OSTI)

Transform Analysis QUESTION 1 Using the definition of the Laplace transform, Laplace transform properties, and the integral tables on the course website, determine the Laplace transforms of the functions - = (3) QUESTION 2 Determine the inverse Laplace transform for the functions in equations (1)­(4). ( ) 3

Landers, Robert G.

36

Effect of thermal treatment on coke reactivity and catalytic iron mineralogy  

SciTech Connect

Iron minerals in coke can catalyze its gasification and may affect coke behavior in the blast furnace. The catalytic behavior of iron depends largely upon the nature of the iron-bearing minerals. To determine the mineralogical changes that iron could undergo in the blast furnace, cokes made from three coals containing iron present in different mineral forms (clays, carbonates, and pyrite) were examined. All coke samples were heat-treated in a horizontal furnace at 1373, 1573, and 1773 K and then gasified with CO{sub 2} at 1173 K in a fixed bed reactor (FBR). Coke mineralogy was characterized using quantitative X-ray diffraction (XRD) analysis of coke mineral matter prepared by low-temperature ashing (LTA) and field emission scanning electron microscopy combined with energy dispersive X-ray analysis (FESEM/EDS). The mineralogy of the three cokes was most notably distinguished by differing proportions of iron-bearing phases. During heat treatment and subsequent gasification, iron-containing minerals transformed to a range of minerals but predominantly iron-silicides and iron oxides, the relative amounts of which varied with heat treatment temperature and gasification conditions. The relationship between initial apparent reaction rate and the amount of catalytic iron minerals - pyrrhotite, metallic iron, and iron oxides - was linear and independent of heat treatment temperature at total catalyst levels below 1 wt %. The study showed that the coke reactivity decreased with increasing temperature of heat treatment due to decreased levels of catalytic iron minerals (largely due to formation of iron silicides) as well as increased ordering of the carbon structure. The study also showed that the importance of catalytic mineral matter in determining reactivity declines as gasification proceeds. 37 refs., 13 figs., 7 tabs.

Byong-chul Kim; Sushil Gupta; David French; Richard Sakurovs; Veena Sahajwalla [University of New South Wales, Sydney, NSW (Australia). Centre for Sustainable Materials Research and Technology

2009-07-15T23:59:59.000Z

37

Modeling Transformation  

E-Print Network (OSTI)

Modeling Transformation What does each step do? #12;Transformation Procedure #12;Transformation Procedure #12;Building Your Model Yarn = chromosomal DNA Beads - - - - - - - - - - - - - - Ribosomes #12;Add transformation solution Tube CaCl2 #12;Transformation solution: CaCl2

Rose, Michael R.

38

Challenges in the Selective Transformation of Biomass to Useful Chemical Intermediates and Materials  

E-Print Network (OSTI)

highly hydroxylated biomass feedstocks into new chemical intermediates and thermoplastics. New scientific. We have developed new catalytic methods for transforming biomass feedstocks into new monomers

Abolmaesumi, Purang

39

Catalytic distillation : design and application of a catalytic distillation column.  

E-Print Network (OSTI)

??Catalytic Distillation (CD) is a hybrid technology that utilizes the dynamics of si- multaneous reaction and separation in a single process unit to achieve a… (more)

Nieuwoudt, Josias Jakobus (Jako)

2005-01-01T23:59:59.000Z

40

transformation restrictions  

E-Print Network (OSTI)

Integration of Graph Transformation and Temporal Logic for the Speci#12;cation of Distributed, namely distributed graph transformation and temporal logic. Distributed graph transformation is intended

Lyuu, Yuh-Dauh

Note: This page contains sample records for the topic "determination catalytic transformation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Cumene by Catalytic Distillation  

SciTech Connect

The novel concept of Catalytic Distillation has been commercialized in the CRandL MTBE process, in which combined reaction and distillation provide energy savings over conventional processes. This concept has now been extended to production of cumene from benzene and propylene. In this case the advantages of the technique are not only energy savings but significant reductions in by-product losses and capital requirements. In this paper the development of the process is discussed and the economics of commercial operation are presented.

Jones, E.M.; Mawer, J.

1986-01-01T23:59:59.000Z

42

Transformation Telepresence  

E-Print Network (OSTI)

Business Transformation through Telepresence Gaining Value with Enterprise Video Collaboration-based research and April, 2011 Business Transformation through Telepresence: Gaining Value with Enterprise Video be used to transform organizations. Why Does Your Business Need to Transform? Traditionally, organizations

Fisher, Kathleen

43

Novel Catalytic Membrane Reactors  

SciTech Connect

There are many industrial catalytic organic reversible reactions with amines or alcohols that have water as one of the products. Many of these reactions are homogeneously catalyzed. In all cases removal of water facilitates the reaction and produces more of the desired chemical product. By shifting the reaction to right we produce more chemical product with little or no additional capital investment. Many of these reactions can also relate to bioprocesses. Given the large number of water-organic compound separations achievable and the ability of the Compact Membrane Systems, Inc. (CMS) perfluoro membranes to withstand these harsh operating conditions, this is an ideal demonstration system for the water-of-reaction removal using a membrane reactor. Enhanced reaction synthesis is consistent with the DOE objective to lower the energy intensity of U.S. industry 25% by 2017 in accord with the Energy Policy Act of 2005 and to improve the United States manufacturing competitiveness. The objective of this program is to develop the platform technology for enhancing homogeneous catalytic chemical syntheses.

Stuart Nemser, PhD

2010-10-01T23:59:59.000Z

44

Method and apparatus for monitoring a hydrocarbon-selective catalytic reduction device  

DOE Patents (OSTI)

A method for monitoring a hydrocarbon-selective catalytic reactor device of an exhaust aftertreatment system of an internal combustion engine operating lean of stoichiometry includes injecting a reductant into an exhaust gas feedstream upstream of the hydrocarbon-selective catalytic reactor device at a predetermined mass flowrate of the reductant, and determining a space velocity associated with a predetermined forward portion of the hydrocarbon-selective catalytic reactor device. When the space velocity exceeds a predetermined threshold space velocity, a temperature differential across the predetermined forward portion of the hydrocarbon-selective catalytic reactor device is determined, and a threshold temperature as a function of the space velocity and the mass flowrate of the reductant is determined. If the temperature differential across the predetermined forward portion of the hydrocarbon-selective catalytic reactor device is below the threshold temperature, operation of the engine is controlled to regenerate the hydrocarbon-selective catalytic reactor device.

Schmieg, Steven J; Viola, Michael B; Cheng, Shi-Wai S; Mulawa, Patricia A; Hilden, David L; Sloane, Thompson M; Lee, Jong H

2014-05-06T23:59:59.000Z

45

Transformations ENGINEERING  

E-Print Network (OSTI)

On the Complexity of the Discrete Fourier Transform and Related Linear Transforms Preliminary straight line program that computes an encoding of the Hadamard Transform. The transform itself can transforms, like the DFT. 1 Introduction The complexity of special linear transformations (computations

Gales, Mark

46

5, 35333559, 2005 Catalytic conversion  

E-Print Network (OSTI)

measurement technique, employing selective gas- phase catalytic conversion of methanol to formaldehyde it the second most abundant organic trace gas after methane. Methanol can play an important role in upper tropoACPD 5, 3533­3559, 2005 Catalytic conversion of methanol to formaldehyde S. J. Solomon et al. Title

Paris-Sud XI, Université de

47

CX-004964: Categorical Exclusion Determination  

Energy.gov (U.S. Department of Energy (DOE))

Catalytic Transformation of Waste Carbon Dioxide into Valuable MaterialsCX(s) Applied: A11, B3.6Date: 12/29/2010Location(s): Orangeburg, South CarolinaOffice(s): Fossil Energy, National Energy Technology Laboratory

48

CX-004967: Categorical Exclusion Determination  

Energy.gov (U.S. Department of Energy (DOE))

Catalytic Transformation of Waste Carbon Dioxide into Valuable MaterialsCX(s) Applied: A11, B3.6Date: 12/30/2010Location(s): Rochester, New YorkOffice(s): Fossil Energy, National Energy Technology Laboratory

49

CX-000592: Categorical Exclusion Determination | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

92: Categorical Exclusion Determination 92: Categorical Exclusion Determination CX-000592: Categorical Exclusion Determination 25A3400 - Catalytic Biocrude Production in a Novel, Short-contact Time Reactor CX(s) Applied: B3.6 Date: 12/15/2009 Location(s): North Carolina Office(s): Advanced Research Projects Agency - Energy The goal of this early stage research and development project is to develop a novel single-step catalytic biomass pyrolysis process with high carbon conversion efficiency to produce stable bio-crude with low oxygen content (less than 10 percent). Integrating this transformational technology in the existing domestic petroleum refining infrastructure can be an economically attractive option for second generation biofuels production because hydrogen demand for hydroprocessing would be significantly lower. This

50

Transforming development  

E-Print Network (OSTI)

Transforming Java Bytecode Laurie Hendren, Patrick Lam, Jennifer for Analyzing and Transforming Java Bytecode -- p. 1/148 #12; ,Feng,Jennifer) Conclusion, Further Reading & Homework (Laurie) Soot, a Tool for Analyzing and Transforming Java Bytecode

Verbrugge, Clark

51

Transformations for densities Linear transformations  

E-Print Network (OSTI)

' & $ % Lecture 28 Transformations for densities Linear transformations 1-1 differentiable functions General transformations Expectation of a function 1 #12;' & $ % Transformations for discrete transformation of a U[0, 1] · Take X U[0, 1], so that fX(x) = 1 0 0 and set Y

Adler, Robert J.

52

Catalytic steam gasification of coals  

Science Journals Connector (OSTI)

Catalytic steam gasification of coals ... Steam–Coal Gasification Using CaO and KOH for in Situ Carbon and Sulfur Capture ... Steam–Coal Gasification Using CaO and KOH for in Situ Carbon and Sulfur Capture ...

P. Pereira; G. A. Somorjai; H. Heinemann

1992-07-01T23:59:59.000Z

53

The catalytic oxidation of propane  

E-Print Network (OSTI)

THE CATALYTIC OXIDATION OP PROPANE A Thesis By Charles Frederick Sandersont * * June 1949 Approval as to style and content recommended: Head of the Department of Chemical Engineering THE CATALYTICi OXIDATTON OF PROPANE A Thesis By Charles... Frederick ;Sandersonit * June 1949 THE CATALYTIC OXIDATION OP PROPANE A Thesis Submitted to the Faculty of the Agricultural and Mechanical College of Texas in Partial Fulfillment of the Requirements for the Degree of Doctor of Philosophy Major...

Sanderson, Charles Frederick

2013-10-04T23:59:59.000Z

54

Appell Transformation and Canonical Transforms  

E-Print Network (OSTI)

The interpretation of the optical Appell transformation, as previously elaborated in relation to the free-space paraxial propagation under both a rectangular and a circular cylindrical symmetry, is reviewed. Then, the caloric Appell transformation, well known in the theory of heat equation, is shown to be amenable for a similar interpretation involving the Laplace transform rather than the Fourier transform, when dealing with the 1D heat equation. Accordingly, when considering the radial heat equation, suitably defined Hankel-type transforms come to be involved in the inherent Appell transformation. The analysis is aimed at outlining the link between the Appell transformation and the canonical transforms.

Amalia Torre

2011-07-19T23:59:59.000Z

55

Exploring Functional Mellin Transforms  

E-Print Network (OSTI)

We define functional Mellin transforms within a scheme for functional integration proposed in [1]. Functional Mellin transforms can be used to define functional traces, logarithms, and determinants. The associated functional integrals are useful tools for probing function spaces in general and $C^\\ast$-algebras in particular. Several interesting aspects are explored.

J. LaChapelle

2015-01-08T23:59:59.000Z

56

Lorentz Transformations  

E-Print Network (OSTI)

This paper describes a particularly didactic and transparent derivation of basic properties of the Lorentz group. The generators for rotations and boosts along an arbitrary direction, as well as their commutation relations, are written as functions of the unit vectors that define the axis of rotation or the direction of the boost (an approach that can be compared with the one that in electrodynamics, works with the electric and magnetic fields instead of the Maxwell stress tensor). For finite values of the angle of rotation or the boost's velocity, collectively denoted by V, the existence of an exponential expansion for the coordinate transformation's matrix, M (in terms of GV where G is the generator) requires that the matrix's derivative with respect to V, be equal to GM. This condition can only be satisfied if the transformation is additive as it is indeed the case for rotations, but not for velocities. If it is assumed, however, that for boosts such an expansion exists, with V = V(v), v being the velocity, and if the above condition is imposed on the boost's matrix then its expression in terms of hyperbolic cosh(V) and sinh(V} is recovered, and the expression for V(= arc tanh(v)) is determined. A general Lorentz transformation can be written as an exponential containing the sum of a rotation and a boost, which to first order is equal to the product of a boost with a rotation. The calculations of the second and third order terms show that the equations for the generators used in this paper, allow to reliably infer the expressions for the higher order generators, without having recourse to the commutation relations. The transformationmatrices for Weyl spinors are derived for finite values of the rotation and velocity, and field representations, leading to the expression for the angular momentum operator, are studied.

Bernard R. Durney

2011-12-09T23:59:59.000Z

57

Integral transformation and Darboux transformation  

E-Print Network (OSTI)

We review Darboux-Crum transformation of Heun's differential equation. By rewriting an integral transformation of Heun's differential equation into a form of elliptic functions, we see that the integral representation is a generalization of Darboux-Crum transformation. We also consider conservation of monodromy with respect to the transformations.

Kouichi Takemura

2009-11-11T23:59:59.000Z

58

Catalytic distillation extends its reach  

SciTech Connect

Since the early 1980s, catalytic distillation processes have been selected by more than a hundred operators for various applications. Since such a unit performs both reaction and distillation simultaneously, a combined column can replace a separate, fixed-bed reactor and distillation column, thereby eliminating equipment and reducing capital costs. And, compared to the conventional approach, catalytic distillation may also improve other factors, such as reactant conversion, selectivity, mass transfer, operating pressure, oligomer formation and catalyst fouling. The constant washing of the catalyst by liquid flowing down the column and the distillation of high-boiling foulants results in extended catalyst life. Four selective hydrogenation applications of catalytic distillation are discussed: Butadiene selective hydrogenation combined within an MTBE unit; Pentadiene selective hydrogenation; C{sub 4} acetylene conversion; and Benzene saturation.

Rock, K.; McGuirk, T. [Catalytic Distillation Technologies, Houston, TX (United States); Gildert, G.R. [Catalytic Distillation Technologies, Pasadena, TX (United States)

1997-07-01T23:59:59.000Z

59

Market Transformation  

SciTech Connect

Summarizes the goals and activities of the DOE Solar Energy Technologies Program efforts within its market transformation subprogram.

Not Available

2008-09-01T23:59:59.000Z

60

Chemical Transformations | U.S. DOE Office of Science (SC)  

Office of Science (SC) Website

Chemical Transformations Chemical Transformations Chemical Sciences, Geosciences, & Biosciences (CSGB) Division CSGB Home About Research Areas Energy Frontier Research Centers (EFRCs) DOE Energy Innovation Hubs Scientific Highlights Reports & Activities Principal Investigators' Meetings BES Home Research Areas Chemical Transformations Print Text Size: A A A RSS Feeds FeedbackShare Page Research themes include the characterization, control, and optimization of chemistry in many forms. Catalysis science underpins the design of new catalytic methods for the clean and efficient production of fuels and chemicals and emphasizes inorganic and organic complexes; interfacial chemistry, nanostructured and supramolecular catalysts, photocatalysis and electrochemistry, and bio-inspired catalytic processes. Heavy element

Note: This page contains sample records for the topic "determination catalytic transformation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

transformations: representations  

E-Print Network (OSTI)

Overview 1. Number transformations: from one base to another 2. Integer representations 3. Real rate, caches... #12; ECS 50, Discussion on 4/25 2 Integer Transformation: From Decimal to Binary Let, Discussion on 4/25 3 Integer Transformation: From Binary to Decimal Compute the weight of each digit position

Nguyen, Dat H.

62

Transformation Composition  

E-Print Network (OSTI)

Proc. AGTIVE'99, to appear in LNCS Graph Transformation Modules and their Composition ? Frank,knirsch,kreo,kuskeg@informatik.uni-bremen.de Abstract. In this paper, we investigate the notion of transformation modules as a structuring principle. Based on the notion of transformation units, a concept that allows to specify binary relations on graphs

Drewes, Frank

63

Transforming IMAGINATION  

E-Print Network (OSTI)

Our CAMPAIGN: Transforming MEDICINE Beyond IMAGINATION Endowed Professorships and Chairs #12;As, I know firsthand the many ways that endowed professorships can be transformative. Receiving the John. In the following pages, you can learn more about establishing your legacy by participating in the "Transforming

Weber, David J.

64

Transforming IMAGINATION  

E-Print Network (OSTI)

Our CAMPAIGN: Transforming MEDICINE Beyond IMAGINATION The School of Medicine Research Building in the Transforming Medicine Beyond Imagination Campaign, and to learn more about the specific needs, relative and translational research and help drive medical breakthroughs that will transform the health and well

Weber, David J.

65

Understanding ammonia selective catalytic reduction kinetics...  

NLE Websites -- All DOE Office Websites (Extended Search)

temperature programmed reduction (TPR), and electron paramagnetic resonance (EPR) spectroscopy. Catalytic properties are examined using NO oxidation, ammonia oxidation,...

66

Acidity and catalytic activity of zeolite catalysts bound with silica and alumina  

E-Print Network (OSTI)

. Micropore surface area and micropore volume are reduced by about 19% and 18%, respectively, indicating some micropores of ZSM-5 are blocked on binding with silica. SiO2-bound ZSM-5 catalysts have less catalytic activity for butane transformation (cracking...

Wu, Xianchun

2004-09-30T23:59:59.000Z

67

Catalytic Device International LLC | Open Energy Information  

Open Energy Info (EERE)

Catalytic Device International LLC Catalytic Device International LLC Jump to: navigation, search Name Catalytic Device International LLC Place Pleasanton, California Product California-based, firm focused on portable, heat-on-demand products. References Catalytic Device International LLC[1] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. Catalytic Device International LLC is a company located in Pleasanton, California . References ↑ "Catalytic Device International LLC" Retrieved from "http://en.openei.org/w/index.php?title=Catalytic_Device_International_LLC&oldid=343285" Categories: Clean Energy Organizations Companies Organizations Stubs What links here Related changes Special pages

68

Categorical Exclusion Determinations: Ohio | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

January 27, 2010 January 27, 2010 CX-000646: Categorical Exclusion Determination An Experimental and Theoretical Investigation of Micropitting in Wind Turbine Gears and Bearings CX(s) Applied: B3.6 Date: 01/27/2010 Location(s): Ohio Office(s): Energy Efficiency and Renewable Energy, Golden Field Office January 27, 2010 CX-000745: Categorical Exclusion Determination Beneficial Carbon Dioxide Capture in an Integrated Algal Biorefinery for Renewable Generation and Transportation Fuels CX(s) Applied: A11, B3.6 Date: 01/27/2010 Location(s): Cleveland, Ohio Office(s): Fossil Energy, National Energy Technology Laboratory January 22, 2010 CX-000736: Categorical Exclusion Determination Catalytic Transformation of Waste Carbon Dioxide into Valuable Products CX(s) Applied: A9, B3.6 Date: 01/22/2010

69

TRANSFORME Dpartement  

E-Print Network (OSTI)

GEODESIE et TRANSFORMATIONS GEODESIQUES Serge BEUCHER CMM ­ Mines ParisTech Novembre 2013 #12;Cours transformation a la propriété suivante: dX,l+m = dX,l [ dX,m] · d est croissante et extensive · d est également croissante lorsqu'on la considère comme une transformation appliquée à l'espace géodésique X (Y fixé) YY

Mignotte, Max

70

Market Transformation  

Fuel Cell Technologies Publication and Product Library (EERE)

This Fuel Cell Technologies Program fact sheet outlines current status and challenges in the market transformation of hydrogen and fuel cell technologies.

71

TRANSFORME Dpartement  

E-Print Network (OSTI)

transformers of kind #3; ! #3;: NatF : #3; ! #3; NatF := #21;X: 1 +X Nat : #3; Nat := #22; NatF #15; Works also

Mignotte, Max

72

Data Transformation  

Science Journals Connector (OSTI)

Data transformation is applied when there is a... normal distribution ...or realize some other assumption about the distribution prior to carrying out certain stati...

2008-01-01T23:59:59.000Z

73

Functional Mellin Transforms  

E-Print Network (OSTI)

Functional integrals are defined in terms of locally compact topological groups and their associated Banach-valued Haar integrals. This approach generalizes the functional integral scheme of Cartier and DeWitt-Morette. The definition allows a construction of functional Mellin transforms. In turn, the functional Mellin transforms can be used to define functional traces, logarithms, and determinants. The associated functional integrals are useful tools for probing function spaces in general and $C^\\ast$-algebras in particular. Several interesting aspects are explored.

J. LaChapelle

2015-01-07T23:59:59.000Z

74

Chiral Transformations  

Science Journals Connector (OSTI)

Chiral transformations are discussed phenomenologically, beginning with the known properties of the low-energy ?N system. The treatment of ?? scattering emphasizes the ambiguity in the connection between mathematical structures and the physical ? field. The unitary generalization of the meson chiral transformation is applied to the strong-interaction decay ?*??+2?. The predicted energy asymmetry of the ? is consistent with observation.

Julian Schwinger

1968-03-25T23:59:59.000Z

75

Engineering Molecular Transformations for Sustainable Energy Conversion  

SciTech Connect

Future strategies for sustainable energy production will undoubtedly require processes and materials that can efficiently convert renewable resources into fuels. Nature’s enzymes can exquisitely integrate highly active catalytic centers within flexible environments that can adaptively guide reactants to products with very high activities and selectivities. They are limited, however, by their stability and ability to integrate into large scale production processes. The design of more robust heterogeneous catalytic materials that mimic the performance of enzymes, however, has been hindered by our limited understanding of how such transformations proceed. The tremendous advances in ab initio quantum mechanical methods, atomistic simulations, and high performance computing that have occurred over the past two decades, however, provide unprecedented ability to track molecular transformations and how they proceed at specific sites and within particular environments. This information together with the advances in in situ spectroscopic methods that follow such transformations can begin to enable the design of atomic surface ensembles and nanoscale reaction environments. This paper provides the author’s perspective on how theory and simulation can be used to move from current onedimensional design efforts based on catalytic descriptors to the design of two-dimensional surfaces, threedimensional reaction environments, and proton-coupled electron transfer systems that mimic enzymes in the transformation of molecules.

Neurock, Matthew

2010-12-03T23:59:59.000Z

76

Bifunctional Catalysts for the Selective Catalytic Reduction...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

for the Selective Catalytic Reduction of NO by Hydrocarbons Development of Optimal Catalyst Designs and Operating Strategies for Lean NOx Reduction in Coupled LNT-SCR Systems...

77

Synthesis, Characterization, and Catalytic Function of Novel...  

NLE Websites -- All DOE Office Websites (Extended Search)

Function of Novel Highly Dispersed Tungsten Oxide Catalysts on Mesoporous Silica . Synthesis, Characterization, and Catalytic Function of Novel Highly Dispersed Tungsten Oxide...

78

Project TRACS: Empirically Investigating Transformation through Relatedness, Autonomy, and Competence Support Logic Model Rooted in Self-Determination Theory (Deci & Ryan, 2000)  

E-Print Network (OSTI)

Project TRACS: Empirically Investigating Transformation through Relatedness, Autonomy appointments toolkit (R, A , C) Project TRACS PI/Director Co-Director & Manager Project Leads & Team MSU&T and hiring procedures -Modern sexism is reduced -Women faculty feel improved job satisfaction -Women intend

Dyer, Bill

79

TRANSFORMATIONS GEODESIQUES  

E-Print Network (OSTI)

to A if there is a transformation R which for every input x of B yields an equivalent input R(x) of A. { The answer to x for B

Beucher, Serge

80

Transformative copy  

E-Print Network (OSTI)

The ability to create an unlimited number of identical copies is a privilege of digital documents. What if that would not be the case, if each copy of a digital file would go along with some sort of transformation? This ...

Offenhuber, Dietmar

2008-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "determination catalytic transformation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Catalytic steam reforming of hydrocarbons  

SciTech Connect

The hot effluent from the catalytic steam reforming of a major portion of a fluid hydrocarbon feed stream in the reformer tubes of a primary reformer, or said effluent after secondary reforming thereof, is mixed with the hot effluent from the catalytic steam reforming of the remaining portion of the feed discharged from the reformer tubes of a primary reformer-exchanger. The combined gas steam is passed on the shell side of the reformer-exchanger countercurrently to the passage of feed in the reformer tubes thereof, thus supplying the heat for the reforming of the portion of the feed passed through the reformer tubes of the reformerexchanger. At least about 2/3 of the hydrocarbon feed stream is passed to the reformer tubes of said primary reformer, heated by radiant heat transfer and/or by contact with combustion gases, at a steam/hydrocarbon mole ratio of about 2-4/1. The remainder of said feed stream is passed to the reformer tubes of said reformer -exchanger at a steam/hydrocarbon mole ratio of about 3-6/1. The reformer shell of the reformer-exchanger is internally insulated by a refractory lining or by use of a double shell with passage of water or a portion of the feed material between the inner and outer shells. There is no significant difference between the pressure inside and outside of the reformer tubes of said primary reformer-exchanger.

Fuderer, A.

1982-06-29T23:59:59.000Z

82

Utilization of char from biomass gasification in catalytic applications  

E-Print Network (OSTI)

Utilization of char from biomass gasification in catalytic applications Naomi Klinghoffer Submitted Utilization of char from biomass gasification in catalytic applications Naomi Klinghoffer Utilization takes place during catalytic decomposition. This thesis focuses on the utilization of char as a catalyst

83

SPATIAL TRANSFORMATIONS 1 Running head: Spatial transformations  

E-Print Network (OSTI)

SPATIAL TRANSFORMATIONS 1 Running head: Spatial transformations Multiple Systems for Spatial Imagery: Transformations of Objects and Bodies Jeffrey M. Zacks* and Barbara Tversky * Washington COGNITION & COMPUTATION #12;SPATIAL TRANSFORMATIONS 2 Abstract Problem-solving often requires imagining

Zacks, Jeffrey M.

84

Categorical Exclusion Determinations: A9 | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

4, 2011 4, 2011 CX-004857: Categorical Exclusion Determination Building Operations Certification License CX(s) Applied: A9, A11, B5.1 Date: 01/04/2011 Location(s): Kansas Office(s): Energy Efficiency and Renewable Energy, Golden Field Office January 4, 2011 CX-004854: Categorical Exclusion Determination Missouri-City-St. Peters CX(s) Applied: A1, A9, B2.5, B5.1 Date: 01/04/2011 Location(s): St. Peters, Missouri Office(s): Energy Efficiency and Renewable Energy January 3, 2011 CX-004853: Categorical Exclusion Determination Louisiana-County-St. Landry CX(s) Applied: A9, A11, B2.5, B5.1 Date: 01/03/2011 Location(s): St. Landry Parish, Louisiana Office(s): Energy Efficiency and Renewable Energy December 30, 2010 CX-004966: Categorical Exclusion Determination Catalytic Transformation of Waste Carbon Dioxide into Valuable Materials

85

Fourier Transform Pairs The Fourier transform transforms a function of  

E-Print Network (OSTI)

Fourier Transform Pairs The Fourier transform transforms a function of time, f(t), into a function of frequency, F(s): F {f(t)}(s) = F(s) = Z - f(t)e- j2st dt. The inverse Fourier transform transforms a func. The inverse Fourier transform of the Fourier trans- form is the identity transform: f(t) = Z - Z - f()e- j2s

Masci, Frank

86

transform your thinking transform your environment  

E-Print Network (OSTI)

MBA #12;transform your thinking 2 transform your environment 18 transform your career 26 start your transformation now 34 transform yourself www.olin.wustl.edu/MBA #12;What distinguishes Washington University. But a great business school transforms the way you think, lead and give back to the world community. #12

Subramanian, Venkat

87

Passive Catalytic Approach to Low Temperature NOx Emission Abatement...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Catalytic Approach to Low Temperature NOx Emission Abatement Passive Catalytic Approach to Low Temperature NOx Emission Abatement Numerically evaluated and optimized proposed...

88

Measurement of diesel solid nanoparticle emissions using a catalytic...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

diesel solid nanoparticle emissions using a catalytic stripper for comparison with Europe's PMP protocol Measurement of diesel solid nanoparticle emissions using a catalytic...

89

TCS 2014 Symposium on Thermal and Catalytic Sciences for Biofuels...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

TCS 2014 Symposium on Thermal and Catalytic Sciences for Biofuels and Biobased Products TCS 2014 Symposium on Thermal and Catalytic Sciences for Biofuels and Biobased Products...

90

Fuel-Flexible, Low-Emissions Catalytic Combustor for Opportunity...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Flexible, Low-Emissions Catalytic Combustor for Opportunity Fuels Fuel-Flexible, Low-Emissions Catalytic Combustor for Opportunity Fuels This fact sheet provides an overview of the...

91

Natural Transformation of Myxococcus xanthus  

Science Journals Connector (OSTI)

...transformants. Transformation of cell extract (CFE)-modified pSWU19 (see below) was confirmed...xanthus SW810 (deltaepsA). Cell extracts (CFE) were prepared from M. xanthus cultures...below). Protein concentrations of the CFE were determined with the bicinchoninic acid...

Jing Wang; Wei Hu; Renate Lux; Xuesong He; Yuezhong Li; Wenyuan Shi

2011-03-04T23:59:59.000Z

92

Substantial Transformation  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

4 4 Recovery Act/Buy American Information Related to Substantial Transformation GUIDANCE ON MANUFACTURED GOODS AND SUBSTANTIAL TRANSFORMATION FOR FINANCIAL ASSISTANCE AWARDS Section 1605 of the Recovery Act states, "None of the funds appropriated or otherwise made available by this Act may be used for a project for the construction, alteration, maintenance, or repair of a public building or public work unless all of the iron, steel, and manufactured goods used in the project are produced in the United States." The Office of Management and Budget's (OMB) guidance on implementing this section defines "manufactured good" as a "good brought to the construction site for incorporation into

93

Catalytic Hydrothermal Gasification of Biomass  

SciTech Connect

A recent development in biomass gasification is the use of a pressurized water processing environment in order that drying of the biomass can be avoided. This paper reviews the research undertaken developing this new option for biomass gasification. This review does not cover wet oxidation or near-atmospheric-pressure steam-gasification of biomass. Laboratory research on hydrothermal gasification of biomass focusing on the use of catalysts is reviewed here, and a companion review focuses on non-catalytic processing. Research includes liquid-phase, sub-critical processing as well as super-critical water processing. The use of heterogeneous catalysts in such a system allows effective operation at lower temperatures, and the issues around the use of catalysts are presented. This review attempts to show the potential of this new processing concept by comparing the various options under development and the results of the research.

Elliott, Douglas C.

2008-05-06T23:59:59.000Z

94

Catalytic converter with thermoelectric generator  

SciTech Connect

The unique design of an electrically heated catalyst (EHC) and the inclusion of an ECO valve in the exhaust of an internal combustion engine will meet the strict new emission requirements, especially at vehicle cold start, adopted by several states in this country as well as in Europe and Japan. The catalytic converter (CC) has been a most useful tool in pollution abatement for the automobile. But the emission requirements are becoming more stringent and, along with other improvements, the CC must be improved to meet these new standards. Coupled with the ECO valve, the EHC can meet these new emission limits. In an internal combustion engine vehicle (ICEV), approximately 80% of the energy consumed leaves the vehicle as waste heat: out the tail pipe, through the radiator, or convected/radiated off the engine. Included with the waste heat out the tail pipe are the products of combustion which must meet strict emission requirements. The design of a new CC is presented here. This is an automobile CC that has the capability of producing electrical power and reducing the quantity of emissions at vehicle cold start, the Thermoelectric Catalytic Power Generator. The CC utilizes the energy of the exothermic reactions that take place in the catalysis substrate to produce electrical energy with a thermoelectric generator. On vehicle cold start, the thermoelectric generator is used as a heat pump to heat the catalyst substrate to reduce the time to catalyst light-off. Thus an electrically heated catalyst (EHC) will be used to augment the abatement of tail pipe emissions. Included with the EHC in the exhaust stream of the automobile is the ECO valve. This valve restricts the flow of pollutants out the tail pipe of the vehicle for a specified amount of time until the EHC comes up to operating temperature. Then the ECO valve opens and allows the full exhaust, now treated by the EHC, to leave the vehicle.

Parise, R.J.

1998-07-01T23:59:59.000Z

95

The Laplace Transform 1 Laplace transform and inverse transform  

E-Print Network (OSTI)

The Laplace Transform Name: 1 Laplace transform and inverse transform Definition. Let f(t) be a function defined for t 0. Then the integral L {f(t)} = 0 e-st f(t)dt is said to be the Laplace transform of f provided the integral converges. Fill in the following Laplace transforms. L {tn } = L {eat } = L

Yengulalp, Lynne

96

The Laplace Transform 1 Laplace transform and inverse transform  

E-Print Network (OSTI)

The Laplace Transform Name: 1 Laplace transform and inverse transform Definition. Let f be a function defined for t 0. Then the integral L {f(t)} = 0 e-st f(t)dt is said to be the Laplace transform of f provided the integral converges. Fill in the following Laplace transforms. L {tn } = n! sn+1 L

Yengulalp, Lynne

97

CX-004968: Categorical Exclusion Determination  

Energy.gov (U.S. Department of Energy (DOE))

Catalytic Transformation of Waste Carbon Dioxide into Valuable MaterialsCX(s) Applied: A9, A11, B3.6Date: 12/29/2010Location(s): Baton Rogue, LouisianaOffice(s): Fossil Energy, National Energy Technology Laboratory

98

CX-004966: Categorical Exclusion Determination  

Energy.gov (U.S. Department of Energy (DOE))

Catalytic Transformation of Waste Carbon Dioxide into Valuable MaterialsCX(s) Applied: A9, A11, B3.6Date: 12/30/2010Location(s): Ithaca, New YorkOffice(s): Fossil Energy, National Energy Technology Laboratory

99

Lattice Boltzmann simulation of catalytic reactions  

Science Journals Connector (OSTI)

A lattice Boltzmann model is developed to simulate finite-rate catalytic surface chemistry. Diffusive wall boundary conditions are established to account for catalytic reactions in multicomponent mixtures. Implementation of wall boundary conditions with chemical reactions is based on a general second-order accurate interpolation scheme. Results of lattice Boltzmann simulations for a four-component mixture with a global catalytic methane oxidation reaction in a straight channel are in excellent agreement with a finite volume Navier-Stokes solver in terms of both the flow field and species concentrations.

S. Arcidiacono; J. Mantzaras; I. V. Karlin

2008-10-28T23:59:59.000Z

100

Chapter 10 - Regenerative catalytic oxidizer technology for VOC control  

Science Journals Connector (OSTI)

Publisher Summary The regenerative catalytic oxidizer (RCO) technology has evolved significantly as an efficient method to control volatile organic compounds. The RCO technology favors using oxide catalysts because it allows for easy compensation of lower activity by an increase in the catalyst amount or temperature. Heat transfer and accumulation properties of ceramic packing material strongly influence RCO performance. The rate of heat transfer affects the temperature gradients along the bed length that, in turn, determine the volume of material required to preheat the gas to the temperature of catalytic or thermal oxidation. During the catalyst operation, it gradually becomes less active and must be eventually replaced. The factors affecting the catalyst lifetime include high temperature, catalytic poisons, and masking agents. Compounds of halogens and sulfur are the most common catalyst poisons. Temperature control, poison tolerant catalysts, and gas-flow pretreatment are used to reduce the impact of catalyst deactivation. This chapter also presents the behavior of an RCO when the catalyst deactivates, and proposes strategies ensuring the required performance during the entire catalyst lifetime.

V.O. Strots; G.A. Bunimovich; C.R. Roach; Yu.Sh. Matros

2000-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "determination catalytic transformation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Categorical Exclusion Determinations: B3.6 | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

3, 2011 3, 2011 CX-005094: Categorical Exclusion Determination Dissolution, Valence Adjustment, and Precipitation of Actinides CX(s) Applied: B3.6 Date: 01/03/2011 Location(s): Aiken, South Carolina Office(s): Savannah River Operations Office January 3, 2011 CX-005093: Categorical Exclusion Determination Development of Cooling Towers as Non-Traditional Collectors of Particles, Biological Agents: Concentration, and Detection CX(s) Applied: B3.6 Date: 01/03/2011 Location(s): Aiken, South Carolina Office(s): Savannah River Operations Office December 30, 2010 CX-004967: Categorical Exclusion Determination Catalytic Transformation of Waste Carbon Dioxide into Valuable Materials CX(s) Applied: A11, B3.6 Date: 12/30/2010 Location(s): Rochester, New York Office(s): Fossil Energy, National Energy Technology Laboratory

102

Categorical Exclusion Determinations: A9 | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

2, 2010 2, 2010 CX-000737: Categorical Exclusion Determination Catalytic Transformation of Waste Carbon Dioxide into Valuable Products CX(s) Applied: A9, B3.6 Date: 01/22/2010 Location(s): Ithaca, New York Office(s): Fossil Energy, National Energy Technology Laboratory January 22, 2010 CX-000739: Categorical Exclusion Determination Site Characterization of the Highest-Priority Geologic Formations for Carbon Dioxide storage in Wyoming CX(s) Applied: A1, A9, B3.6 Date: 01/22/2010 Location(s): Laramie, Wyoming Office(s): Fossil Energy, National Energy Technology Laboratory January 22, 2010 CX-000740: Categorical Exclusion Determination Site Characterization for Carbon Dioxide Storage from Coal-fired Power Facilities in the Black Warrior Basin of Alabama CX(s) Applied: A9, B3.1

103

Categorical Exclusion (CX) Determinations By Date | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

2, 2010 2, 2010 CX-000737: Categorical Exclusion Determination Catalytic Transformation of Waste Carbon Dioxide into Valuable Products CX(s) Applied: A9, B3.6 Date: 01/22/2010 Location(s): Ithaca, New York Office(s): Fossil Energy, National Energy Technology Laboratory January 22, 2010 CX-000738: Categorical Exclusion Determination Site Characterization of the Highest-Priority Geologic Formations for Carbon Dioxide storage in Wyoming CX(s) Applied: B3.1, B3.7, B3.8 Date: 01/22/2010 Location(s): Sweetwater County, Wyoming Office(s): Fossil Energy, National Energy Technology Laboratory January 22, 2010 CX-000739: Categorical Exclusion Determination Site Characterization of the Highest-Priority Geologic Formations for Carbon Dioxide storage in Wyoming CX(s) Applied: A1, A9, B3.6

104

Categorical Exclusion Determinations: B3.6 | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

22, 2010 22, 2010 CX-000737: Categorical Exclusion Determination Catalytic Transformation of Waste Carbon Dioxide into Valuable Products CX(s) Applied: A9, B3.6 Date: 01/22/2010 Location(s): Ithaca, New York Office(s): Fossil Energy, National Energy Technology Laboratory January 22, 2010 CX-000739: Categorical Exclusion Determination Site Characterization of the Highest-Priority Geologic Formations for Carbon Dioxide storage in Wyoming CX(s) Applied: A1, A9, B3.6 Date: 01/22/2010 Location(s): Laramie, Wyoming Office(s): Fossil Energy, National Energy Technology Laboratory January 21, 2010 CX-002154: Categorical Exclusion Determination Recovery Act: DeepCwind Consortium National Research Program: Validation of Coupled Models and Optimization of Materials for Offshore Wind Structures

105

Transformers Transformer device used to raise (for  

E-Print Network (OSTI)

Transformers Transformer ­ device used to raise (for transmission) and lower (for use) the ac with different #s of turns #12;Transformers Alternating primary current induces alternating magnetic flux in iron dt d NV B PP -= dt d NV B SS -= S S P P N V N V = #12;Transformers Transformation of voltage

Bertulani, Carlos A. - Department of Physics and Astronomy, Texas A&M University

106

Introduction to Image Transform Fourier Transform  

E-Print Network (OSTI)

Monad Transformers as Monoid Transformers Mauro Jaskelioff CIFASIS/Universidad Nacional de Rosario monadic semantics constructs complex monads by using monad transformers to add computational features transformers to monoid transformers. The generalization brings more simplicity and clarity, and opens the way

Chen, Chaur-Chin

107

Hough Transform Common Names: Hough transform  

E-Print Network (OSTI)

Hough Transform Common Names: Hough transform Brief Description The Hough transform is a technique that the desired features be specified in some parametric form, the classical Hough transform is most commonly used for the detection of regular curves such as lines, circles, ellipses, etc. A generalized Hough transform can

Masci, Frank

108

Glycoside hydrolases: Catalytic base/nucleophile diversity  

NLE Websites -- All DOE Office Websites (Extended Search)

Glycoside Glycoside Hydrolases: Catalytic Base/Nucleophile Diversity Thu V. Vuong, David B. Wilson Department of Molecular Biology and Genetics, Cornell University, 458 Biotechnology Building, Ithaca, New York 14850; telephone: 607-255-5706; fax: 607-255-2428; e-mail: dbw3@cornell.edu Received 1 April 2010; revision received 27 May 2010; accepted 2 June 2010 Published online 15 June 2010 in Wiley Online Library (wileyonlinelibrary.com). DOI 10.1002/bit.22838 ABSTRACT: Recent studies have shown that a number of glycoside hydrolase families do not follow the classical catalytic mechanisms, as they lack a typical catalytic base/ nucleophile. A variety of mechanisms are used to replace this function, including substrate-assisted catalysis, a network of several residues, and the use of non-carboxylate residues or exogenous nucleophiles. Removal of the catalytic base/ nucleophile

109

Preparation, Characterization, and Catalytic Properties of Tungsten...  

NLE Websites -- All DOE Office Websites (Extended Search)

Abstract: The structure and catalytic activity of tungsten oxide clusters formed via sublimation of monodispersed cyclic (WO3)3 onto FeO(111)Pt(111) surface has been studied...

110

Bifunctional Catalysts for the Selective Catalytic Reduction...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Reduction of NO by Hydrocarbons Selectlive Catalytic Reducution of NOx wilth Diesel-Based Fuels as Reductants Engine and Reactor Evaluations of HC-SCR for Diesel NOx Reduction...

111

Microsecond Catalytic Partial Oxidation of Alkanes  

Science Journals Connector (OSTI)

...HICKMAN A. D. , PRODUCTION OF SYNGAS BY DIRECT CATALYTIC-OXIDATION OF METHANE...PFEFFERLE D. L. , CATALYSIS IN COMBUSTION , CATALYSIS...a-alu-mina monoliths coated with Rh (for syngas) (1, 2) or with Pt (for olefins...

Duane A. Goetsch; Lanny D. Schmidt

1996-03-15T23:59:59.000Z

112

Vacuum-insulated catalytic converter  

DOE Patents (OSTI)

A catalytic converter has an inner canister that contains catalyst-coated substrates and an outer canister that encloses an annular, variable vacuum insulation chamber surrounding the inner canister. An annular tank containing phase-change material for heat storage and release is positioned in the variable vacuum insulation chamber a distance spaced part from the inner canister. A reversible hydrogen getter in the variable vacuum insulation chamber, preferably on a surface of the heat storage tank, releases hydrogen into the variable vacuum insulation chamber to conduct heat when the phase-change material is hot and absorbs the hydrogen to limit heat transfer to radiation when the phase-change material is cool. A porous zeolite trap in the inner canister absorbs and retains hydrocarbons from the exhaust gases when the catalyst-coated substrates and zeolite trap are cold and releases the hydrocarbons for reaction on the catalyst-coated substrate when the zeolite trap and catalyst-coated substrate get hot.

Benson, David K. (Golden, CO)

2001-01-01T23:59:59.000Z

113

Transformation and Quantization  

E-Print Network (OSTI)

Transformation and Quantization Shih-Hsuan Yang CSIE Department, NTUT #12;Contents Quantization and Distortion Analysis Lloyd Quantizer Vector Quantization Block Transforms Transform Kernels JPEG Other

Yang, Shih-Hsuan

114

Recruitment interactions can override catalytic interactions in determining the functional  

E-Print Network (OSTI)

* by Mark Ptashne, Memorial Sloan Kettering Cancer Center, New York, NY, and approved May 4, 2011 (received for review November 3, 2010) The yeast Saccharomyces cerevisae has four distinct mitogen- activated protein- mining the specificity of kinases through recruitment to specific partners and complexes. Here we probe

Lim, Wendell

115

Testability Transformation --Program Transformation to Improve Testability  

E-Print Network (OSTI)

Testability Transformation -- Program Transformation to Improve Testability Mark Harman1 , Andr, 26 Richmond Street, Glasgow G1 1XH, UK. Corresponding Author. Abstract. Testability transformation. The goal is to improve the testing process by transforming a program to one that is more amenable

Binkley, David W.

116

Testability Transformation: Program Transformation to Improve Testability  

E-Print Network (OSTI)

Testability Transformation: Program Transformation to Improve Testability An Overview of Recent Author. Abstract. Testability transformation is a new form of program transfor- mation in which the goal to some chosen test adequacy criterion. The goal is to improve the testing process by transforming

Singer, Jeremy

117

Transformation Transformation Sommersemester 2012 1 / 121  

E-Print Network (OSTI)

Testability Transformation: Program Transformation to Improve Testability An Overview of Recent Author. Abstract. Testability transformation is a new form of program transfor- mation in which the goal to some chosen test adequacy criterion. The goal is to improve the testing process by transforming

Snelting, Gregor

118

Catalytic Combustor for Fuel-Flexible Turbine  

SciTech Connect

Under the sponsorship of the U.S. Department of Energy's National Energy Technology Laboratory, Siemens Westinghouse is conducting a three-year program to develop an ultra low NOx, fuel flexible catalytic combustor for gas turbine application in IGCC. The program is defined in three phases: Phase 1-Implementation Plan, Phase 2-Validation Testing and Phase 3-Field Testing. The Phase 1 program has been completed. Phase II was initiated in October 2004. In IGCC power plants, the gas turbine must be capable of operating on syngas as a primary fuel and an available back-up fuel such as natural gas. In this program the Rich Catalytic Lean (RCL{trademark}) technology is being developed as an ultra low NOx combustor. In this concept, ultra low NOx is achieved by stabilizing a lean premix combustion process by using a catalytic reactor to react part of the fuel, increasing the fuel/air mixture temperature. In Phase 1, the feasibility of the catalytic concept for syngas application has been evaluated and the key technology issues identified. In Phase II the catalytic concept will be demonstrated through subscale testing. Phase III will consist of full-scale combustor basket testing on natural gas and syngas.

W. R. Laster; E. Anoshkina; P. Szedlacsek

2006-03-31T23:59:59.000Z

119

Catalytic Combustor for Fuel-Flexible Turbine  

SciTech Connect

Under the sponsorship of the U. S. Department of Energy's National Energy Technology Laboratory, Siemens Westinghouse has conducted a three-year program to develop an ultra low NOx, fuel flexible catalytic combustor for gas turbine application in IGCC. The program is defined in three phases: Phase 1 - Implementation Plan, Phase 2 - Validation Testing and Phase 3 - Field Testing. Both Phase 1 and Phase 2 of the program have been completed. In IGCC power plants, the gas turbine must be capable of operating on syngas as a primary fuel and an available back-up fuel such as natural gas. In this program the Rich Catalytic Lean (RCLTM) technology is being developed as an ultra low NOx combustor. In this concept, ultra low NOx is achieved by stabilizing a lean premix combustion process by using a catalytic reactor to oxidize a portion of the fuel, increasing the temperature of fuel/air mixture prior to the main combustion zone. In Phase 1, the feasibility of the catalytic concept for syngas application has been evaluated and the key technology issues identified. In Phase II the technology necessary for the application of the catalytic concept to IGCC fuels was developed through detailed design and subscale testing. Phase III (currently not funded) will consist of full-scale combustor basket testing on natural gas and syngas.

W. R. Laster; E. Anoshkina

2008-01-31T23:59:59.000Z

120

Catalytic Combustor for Fuel-Flexible Turbine  

SciTech Connect

Under the sponsorship of the U. S. Department of Energy’s National Energy Technology Laboratory, Siemens Westinghouse has conducted a three-year program to develop an ultra low NOx, fuel flexible catalytic combustor for gas turbine application in IGCC. The program is defined in three phases: Phase 1- Implementation Plan, Phase 2- Validation Testing and Phase 3 – Field Testing. Both Phase 1 and Phase 2 of the program have been completed. In IGCC power plants, the gas turbine must be capable of operating on syngas as a primary fuel and an available back-up fuel such as natural gas. In this program the Rich Catalytic Lean (RCLTM) technology is being developed as an ultra low NOx combustor. In this concept, ultra low NOx is achieved by stabilizing a lean premix combustion process by using a catalytic reactor to oxidize a portion of the fuel, increasing the temperature of fuel/air mixture prior to the main combustion zone. In Phase 1, the feasibility of the catalytic concept for syngas application has been evaluated and the key technology issues identified. In Phase II the technology necessary for the application of the catalytic concept to IGCC fuels was developed through detailed design and subscale testing. Phase III (currently not funded) will consist of full-scale combustor basket testing on natural gas and syngas.

Laster, W. R.; Anoshkina, E.

2008-01-31T23:59:59.000Z

Note: This page contains sample records for the topic "determination catalytic transformation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Transformer modeling in power systems  

SciTech Connect

A practical and accurate method of modeling various transformers in power systems using a general circuit model approach is described in this paper. The advantage of the new approach is that it can model transformers along with a complex circuit network, while avoiding the use of symmetrical components, unlike other approaches. The transformer modeling technique introduced in this paper is very useful to accurately determine fault current distribution in a power system and electromagnetic interference on pipelines and communication lines installed in a right-of-way consisting of transmission lines operating at different voltages.

Ma, J.; Dawalibi, F.P. [Safe Engineering Services and Technologies Ltd., Montreal, Quebec (Canada)

1999-11-01T23:59:59.000Z

122

Catalytically Assisted Self-Propagating High-Temperature Synthesis of Tantalum Carbide Powders  

E-Print Network (OSTI)

) that are otherwise difficult to produce (e.g., transition metal/borides, carbides, and nitrides).1,2 Many earlierCatalytically Assisted Self-Propagating High-Temperature Synthesis of Tantalum Carbide Powders Troy/carbon/tantalum carbide combustion synthesis system has been examined to determine the effects of transport agents

Wooldridge, Margaret S.

123

Preparation of Cu nanoparticle loaded SBA-15 and their excellent catalytic activity in reduction of variety of dyes  

Science Journals Connector (OSTI)

Abstract In this paper, we report a simple aqueous solution based chemical method for preparation of Cu nanoparticle loaded mesoporous silica SBA-15 (Cu@SBA-15) catalysts. Synthesized catalysts were characterized by powder X-ray diffraction (XRD), atomic absorption spectroscopy (AAS), Fourier transform infrared spectroscopy (FTIR), high resolution transmission electron microscope (HRTEM), N2 adsorption–desorption surface area and pore size analyzer, and particle size analyzer. Catalytic activity of Cu nanoparticle loaded SBA-15 towards reduction of various dyes, such as 4-nitrophenol, Methyl Orange, Congo Red, Rhodamine B, Methylene Blue and mixture of dyes were investigated in the presence of excess NaBH4. Catalysis reactions were monitored by employing UV–vis spectroscopy. Catalysis reactions followed pseudo-first order rate equation. These catalysts exhibited excellent catalytic activity and convenient recycling. The high catalytic activity, cost effectiveness and simple preparation methodology make 12.5Cu@SBA-15 an attractive catalyst for decolorization of organic dyes.

Barun Kumar Ghosh; Subhenjit Hazra; Bhanudas Naik; Narendra Nath Ghosh

2015-01-01T23:59:59.000Z

124

Catalytic gasification of tars from a dumping site  

Science Journals Connector (OSTI)

The work deals with catalytic gasification, pyrolysis and non-catalytic gasification of tar from an industrial dumping site. ... were carried out in a vertical stainless steel gasification reactor at 800 °C. Crus...

LukᚠGašparovi?; LukᚠŠugár…

2013-10-01T23:59:59.000Z

125

Institute for Atom-Efficient Chemical Transformations Energy Frontier  

NLE Websites -- All DOE Office Websites (Extended Search)

Institute for Atom-Efficient Chemical Transformations DOE Logo Institute for Atom-Efficient Chemical Transformations DOE Logo Focus Areas Reaction Mechanisms Controlled Active Metals Materials Synthesis Search Argonne ... Search Argonne Home > Institute for Atom-Efficient Chemical Transformations > IACT Home IACT News IACT Partners IACT Staff IACT Awards Publications & Presentations Jobs at IACT Energy Frontier Research Centers at Argonne Strategic Alliances Research Facilities & Tools Institute for Atom-Efficient Chemical Transformations - an Energy Frontier Research Center The Institute for Atom-Efficient Chemical Transformations (IACT) employs a multidisciplinary approach to address key catalytic conversions that could improve the efficiency of producing fuels from biomass. IACT focuses on advancing the science of catalysis for the efficient conversion of energy resources into usable forms. IACT's goal is to find ways to achieve control and efficiency of chemical conversions comparable to those in nature.

126

Analyzing Signals Fourier transform  

E-Print Network (OSTI)

Page 1 1 Analyzing Signals Fourier transform s frequency content s linear combination of sin frequency analysis s windowed Fourier transform 6 #12;Page 4 7 Gabor Transform function to analyze window Gabor Transform Spatial domain Gabor domain b #12;Page 5 9 Gabor Transform Problems s discrete version

Sweldens, Wim

127

Rapid Deployment of Rich Catalytic Combustion  

SciTech Connect

The overall objective of this research under the Turbines Program is the deployment of fuel flexible rich catalytic combustion technology into high-pressure ratio industrial gas turbines. The resulting combustion systems will provide fuel flexibility for gas turbines to burn coal derived synthesis gas or natural gas and achieve NO{sub x} emissions of 2 ppmvd or less (at 15 percent O{sub 2}), cost effectively. This advance will signify a major step towards environmentally friendly electric power generation and coal-based energy independence for the United States. Under Phase 1 of the Program, Pratt & Whitney (P&W) performed a system integration study of rich catalytic combustion in a small high-pressure ratio industrial gas turbine with a silo combustion system that is easily scalable to a larger multi-chamber gas turbine system. An implementation plan for this technology also was studied. The principal achievement of the Phase 1 effort was the sizing of the catalytic module in a manner which allowed a single reactor (rather than multiple reactors) to be used by the combustion system, a conclusion regarding the amount of air that should be allocated to the reaction zone to achieve low emissions, definition of a combustion staging strategy to achieve low emissions, and mechanical integration of a Ceramic Matrix Composite (CMC) combustor liner with the catalytic module.

Richard S. Tuthill

2004-06-10T23:59:59.000Z

128

Catalytic wet oxidation of phenolic wastes  

E-Print Network (OSTI)

Possible catalyst deactivation problems High capital, low operating Supercritical water oxidation (SCWO) Feasible only at high organic concentra- tions High Fast reaction, complete oxidation Severe reaction conditions, canosion problems... of milder reaction conditions and is much less energy intensive. Thus, catalytic wet oxidation would be an alternative to solvent extraction, supercritical water oxidation, homogeneous oxidation, and incineration. It should also be feasible at low...

Thomas, Brook James

1995-01-01T23:59:59.000Z

129

Catalytic Partial Oxidation Pilot Plant Study  

Science Journals Connector (OSTI)

Foster Wheeler Corporation, 585 North Dairy Ashford Street, Houston, Texas 77079 ... This is accomplished in this study with a new reactor system named the catalytic hot oxygen reactor (CHOR). ... Studying the integration of the reactor with the rest of the plant and developing detailed process economics in parallel with the system development are necessary. ...

Vasilis Papavassiliou; Perry Pacouloute; KT Wu; Raymont Drnevich; Dionisios Vlachos; John Hemmings; Leo Bonnel

2009-11-24T23:59:59.000Z

130

Remediation of water contamination using catalytic technologies  

Science Journals Connector (OSTI)

Remediation of contaminated ground and underground water is becoming a critical issue in Europe and worldwide. We discuss here the role of catalysis in water remediation, with reference to two specific examples of catalytic water remediation technologies: (i) the elimination of nitrate and pesticides from water contaminated as a result of agricultural practices and (ii) the conversion of methyl tert-butyl ether (MTBE) in contaminated underground water. Of particular interest is a technology based on catalytic membranes for remediation of water contaminated by nitrate, which offers various advantages with respect to conventional technologies. Using a Pd-Cu-based catalytic membrane, a reaction temperature below 15 °C, a mixed 4:1 CO2:H2 feed and controlling bulk solution pH by \\{HCl\\} addition, it is possible to obtain a nitrate conversion higher than 80% even with ammonium ion formation below 0.5 ppm, i.e. the maximum concentration allowed to meet the requirements for drinking water quality. In MTBE conversion in contaminated underground water, acid zeolites with suitable pore structures (channel structure and pore openings) such as H-ZSM-5 and H-BEA can be used as catalytic permeable reactive barriers for in situ remediation. These zeolites not only act as adsorbents for both MTBE and its reaction products, but also effectively catalyze the hydrolysis of MTBE to t-butyl alcohol (TBA) and methanol (MeOH) which then can be rapidly biodegraded by indigenous microorganisms.

Gabriele Centi; Siglinda Perathoner

2003-01-01T23:59:59.000Z

131

Monad Transformers as Monoid Transformers Mauro Jaskelioff  

E-Print Network (OSTI)

Monad Transformers as Monoid Transformers Mauro Jaskelioff CIFASIS/Universidad Nacional de Rosario@cifasis-conicet.gov.ar (Mauro Jaskelioff), moggi@disi.unige.it (Eugenio Moggi) 1Partially supported by Italian PRIN 2008 "Metodi

Moggi, Eugenio

132

Pillared clays as superior catalysts for selective catalytic reduction of nitric oxide. Second semiannual report, 1996  

SciTech Connect

During the first six months of the program, the work has progressed as planned. We have constructed a reactor system and assembled all laboratory essentials for conducting the three-year project. First, the catalytic activities of the Cu(2+) ion exchanged alumina-pillared clay for the selective catalytic reduction of NO by ethylene were measured. The temperature range was 250-500{degrees}C. The activities of this catalyst were substantially higher than the catalyst that has been extensively studied in the literature, Cu-ZSM-5. Fourier Transform Infrared Spectroscopy (FTIR) was used to study the acidity of the catalyst. The second part of the work was an in-depth FTIR study of the NO decomposition mechanism on the catalyst. This was planned as the first and the key step to obtain an understanding of the reaction mechanism. Key surface intermediates were identified from the FTIR spectra, and a redox type Eley-Rideal mechanism was proposed for the NO decomposition on this catalyst. This report will be divided into two parts. In Part One, we report results on the catalytic activities of the Cu-alumina-pillared clay and a direct comparison with other known catalysts. In Part two, we focus on the FTIR study and from the results, we propose a NO decomposition mechanism on this new catalyst. Plans for the next six months include tests of different pillared clays as well as the catalytic mechanism. The micro reactor will continue to be the key equipment for measuring the catalytic activities. FTIR will continue to be the major technique for identifying surface species and hence understanding the reaction mechanism.

Yang, R.T.; Li, W.B.; Sirilumpen, M.; Tharapiwattananon, N.

1997-08-01T23:59:59.000Z

133

GIS TRANSFORMATIONS Conference Presentation  

E-Print Network (OSTI)

GIS TRANSFORMATIONS Conference Presentation Waldo Tobler Geography Department University, line, area, or field phenomena, then the sixteen common classes of transformation are: point -> point (scalar, vector, tensor) data, to obtain eighty distinct possible classes of transformation. The common

Tobler, Waldo

134

Transformations KolahdouzRahimi  

E-Print Network (OSTI)

An Incremental XSLT Transformation Processor for XML Document Manipulation Lionel Villard ­ Nabil;Outline Motivation Incremental transformations Principles Static Analysis Incremental execution Conclusion presentation architecture NegotiationNegotiation Result of negotiation (Transformation Sheets) Result

Lano, Kevin Charles

135

Evaluating Transformer Losses  

E-Print Network (OSTI)

and replacing them with low loss units. Today few industrials evaluate losses on either power or distribution transformers. TRANSFORMER LOSSES Transformer losses are divided 'nto load losses and no-load losses. Load losses are due to the winding resista... therefore are a function of the load squared. No-load losses occur from energizing the transformer steel and fore are continuous regardless of the transformer load. TRANSFORMER DESIGN Both types of losses are a fun ce here ion of design. If losses...

Grun, R. L. Jr.

136

Catalytic ignition of fuel/oxygen/nitrogen mixtures over platinum  

SciTech Connect

Ignition of fuel/oxygen/nitrogen mixtures over platinum wire is experimentally studied by using microcalorimetry and by restricting the flow to the low Reynolds number range so that axisymmetry prevails. The fuels studied are propane, butane, propylene, ethylene, carbon monoxide, and hydrogen. Parameters investigated include flow velocity, fuel type and concentration, and oxygen concentration. The catalytic ignition temperatures of the various fuels are accurately determined over extensive ranges of fuel/oxygen/nitrogen concentrations. Results show two distinctly opposite ignition trends depending on the nature of the fuel. That is, the ignition temperature of lean propane/air and butane/air mixtures decreases as their fuel concentration is increased, while the reverse trend is observed for lean mixtures of propylene, ethylene, carbon monoxide, and hydrogen with air. Furthermore, the ignition of propane depends primarily on fuel concentration, while the ignition of carbon monoxide depends on fuel and oxygen concentrations to a comparable extent. These results are explained on the basis of hierarchical surface adsorption strengths of the different reactants in effecting catalytic ignition. Additional phenomena of interest are observed and discussed.

Cho, P.; Law, C.K.

1986-11-01T23:59:59.000Z

137

Catalytic deactivation of methane steam reforming catalysts. I. Activation  

SciTech Connect

An alumina-supported catalyst was studied both in its original state and after activation and sintering. Chemical composition and textural properties were determined, and crystalline compounds were identified. Active-phase and support transformations occurring during activation were determined by differential thermoanalysis (DTA), temperature-programmed reduction (TPR), and X-ray diffraction. The catalyst activated by means of various procedures was characterized by measuring crystallite size.

Agnelli, M.E.; Demicheli, M.C.; Ponzi, E.N.

1987-08-01T23:59:59.000Z

138

Transformations | Open Energy Information  

Open Energy Info (EERE)

Transformations Transformations Jump to: navigation, search Name Transformations Place Townsend, MA Website http://transformations-inc.com References Transformations[1] Information About Partnership with NREL Partnership with NREL Yes Partnership Type Test & Evaluation Partner Partnering Center within NREL Electricity Resources & Building Systems Integration LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! Transformations is a company located in Townsend, MA. References ↑ "Transformations" Retrieved from "http://en.openei.org/w/index.php?title=Transformations&oldid=381743" Categories: Clean Energy Organizations Companies Organizations What links here Related changes Special pages Printable version Permanent link Browse properties

139

Method and apparatus for a catalytic firebox reactor  

DOE Patents (OSTI)

A catalytic firebox reactor employing an exothermic catalytic reaction channel and multiple cooling conduits for creating a partially reacted fuel/oxidant mixture. An oxidation catalyst is deposited on the walls forming the boundary between the multiple cooling conduits and the exothermic catalytic reaction channel, on the side of the walls facing the exothermic catalytic reaction channel. This configuration allows the oxidation catalyst to be backside cooled by any fluid passing through the cooling conduits. The heat of reaction is added to both the fluid in the exothermic catalytic reaction channel and the fluid passing through the cooling conduits. After discharge of the fluids from the exothermic catalytic reaction channel, the fluids mix to create a single combined flow. A further innovation in the reactor incorporates geometric changes in the exothermic catalytic reaction channel to provide streamwise variation of the velocity of the fluids in the reactor.

Smith, Lance L. (North Haven, CT); Etemad, Shahrokh (Trumbull, CT); Ulkarim, Hasan (Hamden, CT); Castaldi, Marco J. (Bridgeport, CT); Pfefferle, William C. (Madison, CT)

2001-01-01T23:59:59.000Z

140

Behavior of chars from Bursa Mustafa Kemal Pasa Alpagut and Balkesir Dursunbey Cakiirca Lignite (Turkey) during non-catalytic and catalytic gasification  

SciTech Connect

The reactivities of chars obtained by pyrolysis of Bursa Mustafa Kemal Pasa Alpagut lignite and Balkesir Dursunbey Cakiirca lignite (Turkey) at different temperatures were determined by CO{sub 2} gasification and by combustion with O{sub 2}. Catalytic effect of Na{sub 2}CO{sub 3} on the CO{sub 2} and O{sub 2} gasification reactivity of chars was investigated. Gasification tests were performed in the fixed bed reactors operating at ambient pressure. Reactivity of chars during the CO{sub 2} gasification reactions was determined by calculating the reaction rate constants and reactivity of chars during the O{sub 2} gasification was determined by using ignition temperatures of the samples. Activation energies and Arrhenius constants of the chars on the CO{sub 2} gasification reactions were also calculated by the help of Arrhenius curves. The activation energy for CO{sub 2} gasification was generally decreased with pyrolysis temperature, due to the different surface characteristics and different nature of carbon atoms gasified as the gasification reactions proceed. Generally, the increase in pyrolysis temperature leads to an increase in gasification reactivity with CO{sub 2}. The reactivity of chars in catalytic gasification was higher than the corresponding non-catalytic reactivity of the same chars. Ignition temperature increased with increasing pyrolysis temperature.

Bozkurt, Y.; Misirlioglu, Z.; Sinag, A.; Tekes, A.T.; Canel, M. [Ankara University, Ankara (Turkey). Dept. of Chemistry

2008-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "determination catalytic transformation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Plasma catalytic reforming of methane  

Science Journals Connector (OSTI)

Thermal plasma technology can be efficiently used in the production of hydrogen and hydrogen-rich gases from methane and a variety of fuels. This article describes progress in plasma reforming experiments and calculations of high temperature conversion of methane using heterogeneous processes. The thermal plasma is a highly energetic state of matter that is characterized by extremely high temperatures (several thousand degrees Celsius), and a high degree of dissociation and a substantial degree of ionization. The high temperatures accelerate the reactions involved in the reforming process. Hydrogen-rich gas (40% H2, 17% CO2 and 33% N2, for partial oxidation/water shifting) can be efficiently made in compact plasma reformers. Experiments have been carried out in a small device (2–3 kW) and without the use of efficient heat regeneration. For partial oxidation/water shifting, it was determined that the specific energy consumption in the plasma reforming processes is 16 MJ/kg H2 with high conversion efficiencies. Larger plasmatrons, better reactor thermal insulation, efficient heat regeneration and improved plasma catalysis could also play a major role in specific energy consumption reduction and increasing the methane conversion. A system has been demonstrated for hydrogen production with low CO content (?1.5%) with power densities of ?30 kW (H2 HHV)/l of reactor, or ?10 m3/h H2 per liter of reactor. Power density should further increase with increased power and improved design.

L Bromberg; D.R Cohn; A Rabinovich; N Alexeev

1999-01-01T23:59:59.000Z

142

On the broken ray transform  

E-Print Network (OSTI)

This PhD thesis studies the broken ray transform, a generalization of the geodesic X-ray transform where geodesics are replaced with broken rays that reflect on a part of the boundary. The fundamental question is whether this transform is injective. We employ four different methods to approach this question, and each of them gives interesting results. Direct calculation can be used in a ball, where the geometry is particularly simple. If the reflecting part of the boundary is (piecewise) flat, a reflection argument can be used to reduce the problem to the usual X-ray transform. In some geometries one can use broken rays near the boundary to determine the values of the unknown function at the reflector, and even construct its Taylor series. One can also use energy estimates -- which in this context are known as Pestov identities -- to show injectivity in the presence of one convex reflecting obstacle. Many of these methods work also on Riemannian manifolds. We also discuss the periodic broken ray transform, where the integrals are taken over periodic broken rays. The broken ray transform and its periodic version have applications in other inverse problems, including Calder\\'on's problem and problems related to spectral geometry. A more detailed abstract can be found in the PDF file. This version only contains the introductory parts of the thesis. The full thesis also contains five articles.

Joonas Ilmavirta

2014-09-26T23:59:59.000Z

143

Catalytic fast pyrolysis of lignocellulosic biomass  

SciTech Connect

Increasing energy demand, especially in the transportation sector, and soaring CO2 emissions necessitate the exploitation of renewable sources of energy. Despite the large variety of new energy Q3 carriers, liquid hydrocarbon still appears to be the most attractive and feasible form of transportation fuel taking into account the energy density, stability and existing infrastructure. Biomass is an abundant, renewable source of energy; however, utilizing it in a cost-effective way is still a substantial challenge. Lignocellulose is composed of three major biopolymers, namely cellulose, hemicellulose and lignin. Fast pyrolysis of biomass is recognized as an efficient and feasible process to selectively convert lignocellulose into a liquid fuel—bio-oil. However bio-oil from fast pyrolysis contains a large amount of oxygen, distributed in hundreds of oxygenates. These oxygenates are the cause of many negative properties, such as low heating values, high corrosiveness, high viscosity, and instability; they also greatly Q4 limit the application of bio-oil particularly as transportation fuel. Hydrocarbons derived from biomass are most attractive because of their high energy density and compatibility with the existing infrastructure. Thus, converting lignocellulose into transportation fuels via catalytic fast pyrolysis has attracted much attention. Many studies related to catalytic fast pyrolysis of biomass have been published. The main challenge of this process is the development of active and stable catalysts that can deal with a large variety of decomposition intermediates from lignocellulose. This review starts with the current understanding of the chemistry in fast pyrolysis of lignocellulose and focuses on the development of catalysts in catalytic fast pyrolysis. Recent progress in the experimental studies on catalytic fast pyrolysis of biomass is also summarized with the emphasis on bio-oil yields and quality.

Liu, Changjun; Wang, Huamin; Karim, Ayman M.; Sun, Junming; Wang, Yong

2014-11-21T23:59:59.000Z

144

transformation languages Introduction  

E-Print Network (OSTI)

transformation languages Introduction Transformation languages are widely used for to process can I change / transform the design of a certain task without changing it's logic The common/and hierarchical or/and abstract set of information. It can even be a stream of data. · The transformation engine

Nierstrasz, Oscar

145

TRANSFORMATIONAL GOALS FOR THE  

E-Print Network (OSTI)

TRANSFORMATIONAL GOALS FOR THE 21ST CENTURY PROGRESS REPORT FALL 2014 #12;CONTENTS EXECUTIVE Transformational Goals progress report Fall 2014 #12;Transformational Goals Progress Report | FALL 20142 In 2010 Island Build a community at URI that values and embraces equity and diversity #12;Transformational Goals

Rhode Island, University of

146

Plasma catalytic reforming of methane  

SciTech Connect

Thermal plasma technology can be efficiently used in the production of hydrogen and hydrogen-rich gases from methane and a variety of fuels. This paper describes progress in plasma reforming experiments and calculations of high temperature conversion of methane using heterogeneous processes. The thermal plasma is a highly energetic state of matter that is characterized by extremely high temperatures (several thousand degrees Celsius) and high degree of dissociation and substantial degree of ionization. The high temperatures accelerate the reactions involved in the reforming process. Hydrogen-rich gas (50% H{sub 2}, 17% CO and 33% N{sub 2}, for partial oxidation/water shifting) can be efficiently made in compact plasma reformers. Experiments have been carried out in a small device (2--3 kW) and without the use of efficient heat regeneration. For partial oxidation/water shifting, it was determined that the specific energy consumption in the plasma reforming processes is 16 MJ/kg H{sub 2} with high conversion efficiencies. Larger plasmatrons, better reactor thermal insulation, efficient heat regeneration and improved plasma catalysis could also play a major role in specific energy consumption reduction and increasing the methane conversion. A system has been demonstrated for hydrogen production with low CO content ({approximately} 1.5%) with power densities of {approximately} 30 kW (H{sub 2} HHV)/liter of reactor, or {approximately} 10 m{sup 3}/hr H{sub 2} per liter of reactor. Power density should further increase with increased power and improved design.

Bromberg, L.; Cohn, D.R.; Rabinovich, A. [Massachusetts Inst. of Technology, Cambridge, MA (United States). Plasma Science and Fusion Center; Alexeev, N. [Russian Academy of Sciences, Moscow (Russian Federation). Baikov Inst. of Metallurgy

1998-08-01T23:59:59.000Z

147

Perfect NOT transformation and conjugate transformation  

E-Print Network (OSTI)

The perfect NOT transformation, probabilistic perfect NOT transformation and conjugate transformation are studied. Perfect NOT transformation criteria on a quantum state set $S$ of a qubit are obtained. Two necessary and sufficient conditions for realizing a perfect NOT transformation on $S$ are derived. When these conditions are not satisfied we discuss a probabilistic perfect NOT transformation (gate). We construct a probabilistic perfect NOT machine (gate) by a general unitary-reduction operation. With a postselection of the measurement outcomes, the probabilistic NOT gate yields perfectly complements of the input states. We prove that one can realize probabilistically the NOT gate of the input states secretly chosen from a certain set $S=\\{|\\Psi_1>, |\\Psi_2>,..., |\\Psi_n>\\}$ if and only if $|\\Psi_1>, |\\Psi_2>,...,$ and $|\\Psi_n>$ are linearly independent. We also generalize the probabilistic NOT transformation to the conjugate transformation in the multi-level quantum system. The lower bound of the best possible efficiencies attained by a probabilistic perfect conjugate transformation are obtained.

Fengli Yan; Ting Gao; Zhichao Yan

2012-03-15T23:59:59.000Z

148

Enhancement of catalytic activities of serine proteases by tripeptides compounds  

Science Journals Connector (OSTI)

The tripeptide compounds, Glu-Arg-Pro-amide (ERPm), d-Pro-Thr-Trp-amide (dPTWm) and thioproline-Thr-Trp (tPTW), were obtained by screening of synthetic peptides for growth-inhibitory activity toward cultured transformed cells. The effects of these peptide compounds on proteases were investigated and the results showed that these compounds enhanced the amidolytic activity of serine proteases despite the fact that each reaction was carried out under optimal conditions. \\{ERPm\\} stimulated the activities of trypsin, chymotrypsin, thrombin, plasmin urokinase and elastase. dPTWm also showed similar effects except that toward chymotrypsin. tPTW elevated the activity only of trypsin, chymotrypsin and thrombin. Stimulation of trypsin activity by these compounds was also confirmed by using casein as a substrate. None of these compounds affected the amidolytic activities of metalloproteinases (MMP-1 and MMP-9), cysteine proteinases (m- and ?-calpains, cathepsin B and papain) or an exopeptidase (leucine aminopeptidase). The activation was at least partly due to the stabilization of the catalytic activity of proteases as well as prevention of autolysis.

Takaki Hiwasa; Sachiko Ogawa; Hisashi Kobayashi; Yoshimasa Ike

1996-01-01T23:59:59.000Z

149

On the positivity of Fourier transforms  

E-Print Network (OSTI)

Characterizing in a constructive way the set of real functions whose Fourier transforms are positive appears to be yet an open problem. Some sufficient conditions are known but they are far from being exhaustive. We propose two constructive sets of necessary conditions for positivity of the Fourier transforms and test their ability of constraining the positivity domain. One uses analytic continuation and Jensen inequalities and the other deals with Toeplitz determinants and the Bochner theorem. Applications are discussed, including the extension to the two-dimensional Fourier-Bessel transform and the problem of positive reciprocity, i.e. positive functions with positive transforms.

Bertrand G. Giraud; Robi Peschanski

2014-05-13T23:59:59.000Z

150

Gauge transformations are canonical transformations, redux  

E-Print Network (OSTI)

In this short note we return to the old paper by Tai L. Chow (Eur. J. Phys. 18 (1997), 467-468) and correct its erroneous final part. We also note that the main result of that paper, that gauge transformations of mechanics are canonical transformations, was known much earlier.

Z. K. Silagadze

2014-09-02T23:59:59.000Z

151

Selective Catalytic Reduction and Exhaust Gas Recirculation Systems...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Catalytic Reduction and Exhaust Gas Recirculation Systems Optimization A patented EGR-SCR approach was shown to readily meet the 2010 EPA requirments for NOx and PM emisisons...

152

Selectlive Catalytic Reducution of NOx wilth Diesel-Based Fuels...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

of NO by Hydrocarbons Bifunctional Catalysts for the Selective Catalytic Reduction of NO by Hydrocarbons Progress on Acidic Zirconia Mixed Oxides for Efficient NH3-SCR Catalysis...

153

Printing 3D Catalytic Devices | The Ames Laboratory  

NLE Websites -- All DOE Office Websites (Extended Search)

Printing 3D Catalytic Devices Ames Laboratory scientist Igor Slowing discusses using 3D printers to create new materials, including catalysts...

154

Catalytic Conversion of Biomass-derived Feedstock (HMF) into...  

NLE Websites -- All DOE Office Websites (Extended Search)

Industrial Technologies Industrial Technologies Biomass and Biofuels Biomass and Biofuels Find More Like This Return to Search Catalytic Conversion of Biomass-derived Feedstock...

155

Catalytic distillation for the synthesis of tertiary butyl alcohol.  

E-Print Network (OSTI)

??Catalytic Distillation for the synthesis of tertiary butyl alcohol (TBA) is investigated in this thesis. The solvent, ethylene glycol, is proposed as a means of… (more)

Safinski, Tomasz

2005-01-01T23:59:59.000Z

156

Single Supported Atoms Participate in Catalytic Processes | ornl...  

NLE Websites -- All DOE Office Websites (Extended Search)

Functional Materials for Energy Single Supported Atoms Participate in Catalytic Processes December 04, 2014 Pathways for NO oxidation on single Pt atoms supported on the (010)...

157

3D Printing of nanostructured catalytic materials | The Ames...  

NLE Websites -- All DOE Office Websites (Extended Search)

3D Printing of nanostructured catalytic materials Over the last couple of decades, scientists have been able to develop a tremendous control over the synthesis and properties of...

158

The Effects of Trace Contaminants on Catalytic Processing of...  

NLE Websites -- All DOE Office Websites (Extended Search)

Processing of Biomass-Derived Feedstocks . Abstract: Trace components in biomass feedstocks are potential catalyst poisons when catalytically processing these materials to...

159

Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

the catalytic conversion of solubilized carbohydrate streams to hydrocarbon biofuels, utilizing data from recent efforts within the National Advanced Biofuels Consortium...

160

Passive Catalytic Approach to Low Temperature NOx Emission Abatement  

Energy.gov (U.S. Department of Energy (DOE))

Numerically evaluated and optimized proposed state-of-the-art passive catalytic technology designed to reduce NOx released during vehicle cold start portion of the FTP-75 cycle

Note: This page contains sample records for the topic "determination catalytic transformation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Kinetic study on the catalytic performance of Rh/TiO/sub 2/ reduced at different temperatures in the CO-H/sub 2/ reaction  

SciTech Connect

Catalytic CO-H/sub 2/ reaction on Rh/TiO/sub 2/ reduced at 200, 400, and 500/sup 0/C (Cat-200, -400, -500) for 2 h was kinetically studied at 250/sup 0/C using a circulating reactor and Fourier transform-infrared (FT-IR) spectroscopy to determine how Cat-400 exhibited the highest activity. The rate equation distinguished the best catalyst with zero and first orders in CO and H/sub 2/, respectively, from other catalysts with negative order in CO. The adsorption ability of the catalyst at 200/sup 0/C was comparable to that of Cat-200, and two to three times larger than that of Cat-500, although the ability of Cat-200 was much larger at room temperature. Carbon monoxide adsorbed on the catalysts reversibly as well as irreversibly. IR spectroscopy revealed that the major form of irreversibly adsorbed CO was linear on Cat-200, whereas similar amounts of linear and bridge forms were observed on Cat-400 and Cat-500. These latter forms were highly reactive against hydrogen molecules when no carbon monoxide was present in the gas phase. Based on these results, the highest activity of Cat-400 is ascribed to rhodium metal modified by properly reduced TiO/sub 2/ to show the appropriate adsorption ability of carbon monoxide which least retards the activation of hydrogen according to first-order kinetics. Typical strong metal-support interaction decreases the catalytic activity by decreasing the active sites and strengthening the CO adsorption too much.

Fujitsu, H.; Ikeyama, N.; Mochida, I.

1986-08-01T23:59:59.000Z

162

Metrics for enterprise transformation  

E-Print Network (OSTI)

The objective of this thesis is to depict the role of metrics in the evolving journey of enterprise transformation. To this end, three propositions are explored: (i) metrics and measurement systems drive transformation, ...

Blackburn, Craig D. (Craig David), S. M. Massachusetts Institute of Technology

2009-01-01T23:59:59.000Z

163

The Patch Transform  

E-Print Network (OSTI)

The patch transform represents an image as a bag of overlapping patches sampled on a regular grid. This representation allows users to manipulate images in the patch domain, which then seeds the inverse patch transform to ...

Avidan, Shai

164

Transformations Ordered set of  

E-Print Network (OSTI)

Modeling Transformations Michael Kazhdan (600.357 / 600.457) HB Ch. 5 FvDFH Ch. 5 #12;Anouncements · Assignment 2 has been posted! #12;Overview · Ray-Tracing so far · Modeling transformations #12;Ray Casting

Jacobs, David

165

Euclidean Gauge Transformation  

Science Journals Connector (OSTI)

The Green's function gauge transformation induced by the elimination of the longitudinal field in Euclidean electrodynamics is discussed.

Julian Schwinger

1960-03-01T23:59:59.000Z

166

TRANSFORMED DSM TARGETS GROWTH  

Science Journals Connector (OSTI)

TRANSFORMED DSM TARGETS GROWTH ... DSM CHIEF Executive Officer Feike Sijbesma refers to Charles Darwin when talking about his company’s transformation. ... In the past 10 years, DSM has transformed itself, shifting its portfolio from petrochemicals and specialties to life sciences and materials. ...

PAIGE MARIE MORSE

2011-03-14T23:59:59.000Z

167

LAPPED TRANSFORMS COMPRESSION  

E-Print Network (OSTI)

Chapter 6 LAPPED TRANSFORMS FOR IMAGE COMPRESSION Ricardo L. de Queiroz Digital Imaging Technology aspects of lapped transforms and their applications to image compression. It is a subject that has been extensively studied mainly because lapped transforms are closely related to filter banks, wavelets, and time

de Queiroz, Ricardo L.

168

TRANSFORMATIONAL GOALS FOR THE  

E-Print Network (OSTI)

TRANSFORMATIONAL GOALS FOR THE 21ST CENTURY The presidenT's 21sT cenTury fund for excellence #12;TRANSFORMATIONAL GOALS FOR THE 21ST CENTURY 1 THE UNIVERSITY OF RHODE ISLAND The University of Rhode Island and transform our approaches to teaching, research, and service so that we can prepare students for a rapidly

Rhode Island, University of

169

Transforming Health Research  

E-Print Network (OSTI)

Transforming Health Research the first two years National Institute for Health Research Progress For Information R OCR R ef: 0 Gateway R ef: 9298 Title Transforming Health Research the first two years. Health Institute for Health Research Progress Report i Transforming Health Research the first two years National

Diggle, Peter J.

170

transform e Construction  

E-Print Network (OSTI)

Abstraction by Symbolic Indexing Transformations Thomas F. Melham1 and Robert B. Jones2 1 describes some logical machinery aimed at bridging these gaps. We present an algorithm to transform ordinary-conditions that must hold for this transformation to be sound. We also describe how the algorithm can be applied

Csürös, Miklós

171

Transformation and Quantization  

E-Print Network (OSTI)

' & $ % Linear Transformations (Yet Again!!) Mark Gales CAMBRIDGE UNIVERSITY ENGINEERING DEPARTMENT mjfg@eng.cam.ac.uk 1 #12; ' & $ % Introduction Linear transformations within HMM systems have been shown to be very useful. ffl Adaptation: MLLR, SAT, CAT, Cluster Transform etc etc. ffl Feature space

Yang, Shih-Hsuan

172

Transforming Anxiety into ENERGYTM  

E-Print Network (OSTI)

Transforming Anxiety into ENERGYTM How to Prevent Panic and Promote Productivity in Turbulent Times By Wendy Mack with contributions from Meredith Kimbell and Myron Radio #12;Transforming Anxiety into Energy, consultants, and researchers who shared their stories and expertise. 1 #12;Transforming Anxiety into Energy

Maryland, Baltimore County, University of

173

Spacetime transformation acoustics  

E-Print Network (OSTI)

A recently proposed analogue transformation method has allowed the extension of transformation acoustics to general spacetime transformations. We analyze here in detail the differences between this new analogue transformation acoustics (ATA) method and the standard one (STA). We show explicitly that STA is not suitable for transformations that mix space and time. ATA takes as starting point the acoustic equation for the velocity potential, instead of that for the pressure as in STA. This velocity-potential equation by itself already allows for some transformations mixing space and time, but not all of them. We explicitly obtain the entire set of transformations that do not leave its form invariant. It is in these cases that ATA shows its true potential, allowing for building a transformation acoustics method that enables the full range of spacetime transformations. We provide an example of an important transformation which cannot be achieved with STA. Using this transformation, we design and simulate an acoustic frequency converter via the ATA approach. Furthermore, in those cases in which one can apply both the STA and ATA approaches, we study the different transformational properties of the corresponding physical quantities.

C. García-Meca; S. Carloni; C. Barceló; G. Jannes; J. Sánchez-Dehesa; A. Martínez

2014-07-08T23:59:59.000Z

174

TRANSFORM a electronics  

E-Print Network (OSTI)

THE DISCRETE FRACTIONAL FOURIER TRANSFORM a thesis submitted to the department of electrical TRANSFORM C ¸a~ gatay Candan M.S. in Electrical and Electronics Engineering Supervisor: Haldun M. ¨ Ozakta Transform (FrFT) is proposed, discussed and consolidated. The discrete trans­ form generalizes the Discrete

Candan, Cagatay

175

Transformation haskell-Programs  

E-Print Network (OSTI)

On the Transformation of Control Flow between Block-Oriented and Graph-Oriented Process Modeling E-mail: zdun@acm.org Abstract: Much recent research work discusses the transformation between differ. In this article, we aim to abstract from concrete transformations by distinguishing two major paradigms

Ábrahám, Erika

176

The Tunneling Transform  

E-Print Network (OSTI)

We supplement the Lorentz transform $L(v)$ with a new "Tunneling" transform $T(v)$. Application of this new transform to elementary quantum mechanics offers a novel, intuitive insight into the nature of quantum tunneling; in particular, the so called "Klein Paradox" is discussed.

Robert Hipple

2014-11-10T23:59:59.000Z

177

Transforming Data into Knowledge  

E-Print Network (OSTI)

The Application Of Correctness Preserving Transformations To Software Maintenance J. Paul Gibson transformation (CPT), to a real software engineering prob- lem: the need for optimization during the maintenance of code. We present four program transformations and a model that forms a framework for proof

Giles, C. Lee

178

Transforming our information systems  

E-Print Network (OSTI)

Transforming our information systems and technology Information Systems Development Framework #12 university. In support of this position we are transforming our information systems, servicesDonald Principal and Vice-Chancellor #12;Strategy for transformation Tactical Delivering the services and tools our

Strathclyde, University of

179

Catalytic bromine recovery from HBr waste  

SciTech Connect

Waste HBr is formed during the bromination of many organic molecules, such as flame retardants, pharmaceuticals, and agricultural chemicals. For over 50 years attempts to recover the bromine from waste HBr by catalytic oxidation have been unsuccessful due to low catalyst activity and stability. The discovery of a new high-activity catalysts with excellent long-term stability and life capable of high HBr conversion below 300{degrees}C has made catalytic oxidation of waste HBr commercially feasible. The oxidation of anhydrous HBr using oxygen is highly exothermic, giving an adiabatic temperature rise of 2000{degrees}C. Use of 48 wt% HBr in the oxidation reduces the adiabatic temperature rise to only 300{degrees}C. A multitubular heat exchanger type of reactor can then be used to manage the heat. A 5,000 kg/yr pilot plant was built to verify the performance of the catalyst, the suitability of the reactor materials of construction, and the multibular reactor concept. The pilot unit has a single full-scale reactor tube 4 m long and 2.54 cm in diameter with a hot oil jacket for heat management. Excellent catalyst stability was observed during a 600 h catalyst-life test. HBr conversion of 99% was maintained throughout the run, and over 360 kg of bromine was produced. The temperature at a localized hot spot near the reactor inlet was only 15-20{degrees}C above the reactor inlet temperature, indicating efficient heat management.

Schubert, P.F.; Beatty, R.D.; Mahajan, S. [Catalytica Inc., Mountain View, CA (United States)

1993-12-31T23:59:59.000Z

180

Catalytic reactor for low-Btu fuels  

DOE Patents (OSTI)

An improved catalytic reactor includes a housing having a plate positioned therein defining a first zone and a second zone, and a plurality of conduits fabricated from a heat conducting material and adapted for conducting a fluid therethrough. The conduits are positioned within the housing such that the conduit exterior surfaces and the housing interior surface within the second zone define a first flow path while the conduit interior surfaces define a second flow path through the second zone and not in fluid communication with the first flow path. The conduit exits define a second flow path exit, the conduit exits and the first flow path exit being proximately located and interspersed. The conduits define at least one expanded section that contacts adjacent conduits thereby spacing the conduits within the second zone and forming first flow path exit flow orifices having an aggregate exit area greater than a defined percent of the housing exit plane area. Lastly, at least a portion of the first flow path defines a catalytically active surface.

Smith, Lance (North Haven, CT); Etemad, Shahrokh (Trumbull, CT); Karim, Hasan (Simpsonville, SC); Pfefferle, William C. (Madison, CT)

2009-04-21T23:59:59.000Z

Note: This page contains sample records for the topic "determination catalytic transformation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Transforming a Transformative School | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

You are here You are here Home » Transforming a Transformative School Transforming a Transformative School October 11, 2012 - 10:14am Addthis During a yearlong renovation, Harding Charter Preparatory school upgraded lighting fixtures, installed a new heating and cooling system, and replaced the entry doors. The new doors allow daylight into the school and restore the historical building envelope. | Photo courtesy of John Winkel, Energy Department. During a yearlong renovation, Harding Charter Preparatory school upgraded lighting fixtures, installed a new heating and cooling system, and replaced the entry doors. The new doors allow daylight into the school and restore the historical building envelope. | Photo courtesy of John Winkel, Energy Department. Julie McAlpin

182

Differences in the catalytic mechanisms of mesophilic and thermophilic indole-3-glycerol phosphate synthase enzymes at their adaptive temperatures  

SciTech Connect

Highlights: Black-Right-Pointing-Pointer Catalytic mechanisms of thermophilic-mesophilic enzymes may differ. Black-Right-Pointing-Pointer Product release is rate-determining for thermophilic IGPS at low temperatures. Black-Right-Pointing-Pointer But at higher temperatures, proton transfer from the general acid is rate-limiting. Black-Right-Pointing-Pointer Rate-determining step is different still for mesophilic IGPS. Black-Right-Pointing-Pointer Both chemical and physical steps of catalysis are important for temperature adaptation. -- Abstract: Thermophilic enzymes tend to be less catalytically-active at lower temperatures relative to their mesophilic counterparts, despite having very similar crystal structures. An often cited hypothesis for this general observation is that thermostable enzymes have evolved a more rigid tertiary structure in order to cope with their more extreme, natural environment, but they are also less flexible at lower temperatures, leading to their lower catalytic activity under mesophilic conditions. An alternative hypothesis, however, is that complementary thermophilic-mesophilic enzyme pairs simply operate through different evolutionary-optimized catalytic mechanisms. In this communication, we present evidence that while the steps of the catalytic mechanisms for mesophilic and thermophilic indole-3-glycerol phosphate synthase (IGPS) enzymes are fundamentally similar, the identity of the rate-determining step changes as a function of temperature. Our findings indicate that while product release is rate-determining at 25 Degree-Sign C for thermophilic IGPS, near its adaptive temperature (75 Degree-Sign C), a proton transfer event, involving a general acid, becomes rate-determining. The rate-determining steps for thermophilic and mesophilic IGPS enzymes are also different at their respective, adaptive temperatures with the mesophilic IGPS-catalyzed reaction being rate-limited before irreversible CO{sub 2} release, and the thermophilic IGPS-catalyzed reaction being rate limited afterwards.

Zaccardi, Margot J.; Mannweiler, Olga [Department of Chemistry, The Pennsylvania State University, University Park, PA 16802 (United States)] [Department of Chemistry, The Pennsylvania State University, University Park, PA 16802 (United States); Boehr, David D., E-mail: ddb12@psu.edu [Department of Chemistry, The Pennsylvania State University, University Park, PA 16802 (United States)

2012-02-10T23:59:59.000Z

183

Invertible Darboux Transformations  

E-Print Network (OSTI)

For operators of many different kinds it has been proved that (generalized) Darboux transformations can be built using so called Wronskian formulae. Such Darboux transformations are not invertible in the sense that the corresponding mappings of the operator kernels are not invertible. The only known invertible ones were Laplace transformations (and their compositions), which are special cases of Darboux transformations for hyperbolic bivariate operators of order 2. In the present paper we find a criteria for a bivariate linear partial differential operator of an arbitrary order d to have an invertible Darboux transformation. We show that Wronkian formulae may fail in some cases, and find sufficient conditions for such formulae to work.

Ekaterina Shemyakova

2013-01-04T23:59:59.000Z

184

CX-007858: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Exclusion Determination CX-007858: Categorical Exclusion Determination Southwest Solar Transformation Initiative CX(s) Applied: A9, A11 Date: 01272012 Location(s):...

185

CX-011102: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Exclusion Determination CX-011102: Categorical Exclusion Determination American Solar Transformation Initiative CX(s) Applied: A11 Date: 08092013 Location(s):...

186

CX-007153: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Determination CX-007153: Categorical Exclusion Determination Glen Canyon substation Transformer Addition CX(s) Applied: B4.6 Date: 05052011 Location(s): Coconino County, Arizona...

187

CX-005116: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Determination CX-005116: Categorical Exclusion Determination Lusk Substation Transformer Replacement, Lusk, Niobrara County, Wyoming CX(s) Applied: B4.6 Date: 01242011...

188

CX-010546: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Determination CX-010546: Categorical Exclusion Determination Liberty Substation Transformer Replacement Project, Maricopa County, Arizona CX(s) Applied: B4.11 Date: 06062013...

189

CX-005114: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Determination CX-005114: Categorical Exclusion Determination Fleming Substation Transformer Replacement, Fleming, Logan County, Colorado CX(s) Applied: B4.6 Date: 12202010...

190

Catalytic Membrane Reactor for Extraction of Hydrogen from Bioethanol Reforming  

E-Print Network (OSTI)

-gas-shift catalytic membrane reactor, and (2) a multi-layer design for bioethanol reforming. A two-dimensional model is developed to describe reaction and diffusion in the catalytic membrane coupled with plug-flow equations in the retentate and permeate volumes using...

Kuncharam, Bhanu Vardhan

2013-11-26T23:59:59.000Z

191

Transformation Nets -A Runtime Model for Transformation Languages  

E-Print Network (OSTI)

Transformation Nets - A Runtime Model for Transformation Languages Johannes Schoenboeck Institute transformation languages. Although numerous approaches are available, they lack convenient facilities for supporting debugging and understand- ing of the transformation logic. This is not least because

Hochreiter, Sepp

192

Study of immobilized catalysts. XVI. Study of structural features and catalytic properties of immobilized mono-and binuclear cobalt complexes  

SciTech Connect

A series of polymeric carriers with chelate-forming groups of diacylamine and aminovinyl ketone types and also mono- and binuclear Co (II) complexes based on them were obtained by methods of polymer-analogous transformations, startting from polyethylene (PE)-grafted (rgr-) polyacetylonitrile (PE-gr-PAN), PE-gr-polyacrylamide (PE-gr-PAA), or PE-gr-poly(methyl vinyl ketone) CPE-grPMVK). From the data of spectral and magnetic studies, a conclusion was made on the chelate structure of the Co (II) complexes synthesized with a tetrahedral configuration of the coordination unit. It was found that the immobilized Co (II) chelates have a high and stable catalytic activity in the sterospecific 1,4-cispolymerization of butadiene. It was shown that an increase in the number of Co (II) ions in the complex molecule leads to a decrease in the specific activity of the catalytic systems based on them.

Pomogailo, A.D.; Golubeva, N.D.; Uflyand, I.E.

1986-06-01T23:59:59.000Z

193

The reaction kinetics of gasoline sulfur compounds: Catalytic mechanisms for sulfur reduction  

SciTech Connect

One of the key elements of reformulated gasoline is the reduction of the sulfur compounds produced by fluid catalytic cracking. This paper probes the reaction kinetics of refractory gasoline-range thiophene derivatives (thiophene, tetrahydrothiophene, and alkylthiophenes) in an effort to determine the mechanisms of sulfur compound cracking in the FCC unit. The gasoline-range sulfur compounds were analyzed using gas chromatography with an atomic emission detector. The authors` results show that the FCC catalysts affects the cracking of sulfur compounds through both hydrogen transfer and zeolite pore restriction mechanisms. An experimental FCC catalyst is shown to reduce gasoline sulfur content in the Davidson Circulating Riser (DCR{sup TM}) pilot unit. Model compound tests show that the activity of the catalyst is due to both its catalytic and adsorptive properties. Tetrahydrothiophene, which is produced from thiophenes by hydrogen transfer, is completely removed by the experimental catalyst.

Harding, R.H.; Gatte, R.R.; Albro, T.G.; Wormsbecher, R.F. [W.R. Grace & Co. Conn, Columbia, MD (United States)

1993-12-31T23:59:59.000Z

194

Production of algae-based biodiesel using the continuous catalytic Mcgyan® process  

Science Journals Connector (OSTI)

This study demonstrates the production of algal biodiesel from Dunaliella tertiolecta, Nannochloropsis oculata, wild freshwater microalgae, and macroalgae lipids using a highly efficient continuous catalytic process. The heterogeneous catalytic process uses supercritical methanol and porous titania microspheres in a fixed bed reactor to catalyze the simultaneous transesterification and esterification of triacylglycerides and free fatty acids, respectively, to fatty acid methyl esters (biodiesel). Triacylglycerides and free fatty acids were converted to alkyl esters with up to 85% efficiency as measured by 300 MHz 1H NMR spectroscopy. The lipid composition of the different algae was studied gravimetrically and by gas chromatography. The analysis showed that even though total lipids comprised upwards of 19% of algal dry weight the saponifiable lipids, and resulting biodiesel, comprised only 1% of dry weight. Thus highlighting the need to determine the triacylglyceride and free fatty acid content when considering microalgae for biodiesel production.

Brian J. Krohn; Clayton V. McNeff; Bingwen Yan; Daniel Nowlan

2011-01-01T23:59:59.000Z

195

Fluid catalytic cracking of heavy petroleum fractions  

SciTech Connect

A process is claimed for fluid catalytic cracking of residuum and other heavy oils comprising of gas oil, petroleum residue, reduced and whole crudes and shale oil to produce gasoline and other liquid products which are separated in various streams in a fractionator and associated vapor recovery equipment. The heat from combustion of coke on the coked catalyst is removed by reacting sulfur-containing coke deposits with steam and oxygen in a separate stripper-gasifier to produce a low btu gas stream comprising of sulfur compounds, methane, carbon monoxide, hydrogen, and carbon dioxide at a temperature of from about 1100/sup 0/F. To about 2200/sup 0/F. The partially regenerated catalyst then undergoes complete carbon removal in a regeneration vessel. The regenerated catalyst is recycled for re-use in the cracking of heavy petroleum fractions. The liquid products are gasoline, distillates, heavy fuel oil, and light hydrocarbons.

McHenry, K.W.

1981-06-30T23:59:59.000Z

196

Contact structure for use in catalytic distillation  

DOE Patents (OSTI)

A method is described for conducting catalytic chemical reactions and fractionation of the reaction mixture comprising feeding reactants into a distillation column reactor, contracting said reactant in liquid phase with a fixed bed catalyst in the form of a contact catalyst structure consisting of closed porous containers containing the catalyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column. 7 figs.

Jones, E.M. Jr.

1984-03-27T23:59:59.000Z

197

Contact structure for use in catalytic distillation  

DOE Patents (OSTI)

A method and apparatus are disclosed for conducting catalytic chemical reactions and fractionation of the reaction mixture, comprising and feeding reactants into a distillation column reactor contracting said reactant in a liquid phase with a fixed bed catalyst in the form of a contact catalyst structure, consisting of closed porous containers containing the catalyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column. 7 figs.

Jones, E.M. Jr.

1985-08-20T23:59:59.000Z

198

Contact structure for use in catalytic distillation  

DOE Patents (OSTI)

A method for conducting catalytic chemical reactions and fractionation of the reaction mixture comprising feeding reactants into a distillation column reactor contracting said reactant in liquid phase with a fixed bed catalyst in the form of a contact catalyst structure consisting of closed porous containers containing the catatlyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column.

Jones, Jr., Edward M. (Friendswood, TX)

1984-01-01T23:59:59.000Z

199

Contact structure for use in catalytic distillation  

DOE Patents (OSTI)

A method and apparatus for conducting catalytic chemical reactions and fractionation of the reaction mixture, comprising and feeding reactants into a distillation column reactor contracting said reactant in a liquid phase with a fixed bed catalyst in the form of a contact catalyst structure, consisting of closed porous containers containing the catalyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column.

Jones, Jr., Edward M. (Friendswood, TX)

1985-01-01T23:59:59.000Z

200

Catalytic cartridge SO/sub 3/ decomposer  

DOE Patents (OSTI)

A catalytic cartridge surrounding a heat pipe driven by a heat source is utilized as a SO/sub 3/ decomposer for thermochemical hydrogen production. The cartridge has two embodiments, a cross-flow cartridge and an axial flow cartridge. In the cross-flow cartridge, SO/sub 3/ gas is flowed through a chamber and incident normally to a catalyst coated tube extending through the chamber, the catalyst coated tube surrounding the heat pipe. In the axial-flow cartridge, SO/sub 3/ gas is flowed through the annular space between concentric inner and outer cylindrical walls, the inner cylindrical wall being coated by a catalyst and surrounding the heat pipe. The modular cartridge decomposer provides high thermal efficiency, high conversion efficiency, and increased safety. A fusion reactor may be used as the heat source.

Galloway, T.R.

1980-11-18T23:59:59.000Z

Note: This page contains sample records for the topic "determination catalytic transformation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Catalytic Transformations of Biomass-Derived Materials into Value-Added Chemicals  

Science Journals Connector (OSTI)

This manuscript reviews recent literatures on synthesis of furfurals (5-hydroxymethylfurfural, furfural, 5-methyl-2-furaldehyde) from...d-galactose, d-arabinose, xylose, l-rhamnose, lactose, cellobiose, sucrose) ...

Atsushi Takagaki; Shun Nishimura; Kohki Ebitani

2012-09-01T23:59:59.000Z

202

Li?0? in Li-0? batteries : catalytic enhancement of electrochemical oxidation and thermophysical transformations  

E-Print Network (OSTI)

Electrification of transportation in the United States is of importance in reducing dependence on foreign oil and curtailing global warming. However, optimal market penetration of electric vehicles is confronted with the ...

Yao, Koffi Pierre (Koffi Pierre Claver)

2013-01-01T23:59:59.000Z

203

Transforming Commercial Building Operations  

NLE Websites -- All DOE Office Websites (Extended Search)

Transforming Commercial Building Operations Transforming Commercial Building Operations Transforming Commercial Building Operations Ron Underhill Pacific Northwest National Laboratory ronald.underhill@pnnl.gov (509)375-9765 April 4, 2013 2 | Building Technologies Office eere.energy.gov * Most buildings are not commissioned (Cx) before occupancy, including HVAC and lighting systems * Buildings often are poorly operated and maintained leading to significant energy waste of 5 to 20%, even when they have building automation systems (BASs)

204

Transforming Commercial Building Operations  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Transforming Commercial Building Operations Transforming Commercial Building Operations Transforming Commercial Building Operations Ron Underhill Pacific Northwest National Laboratory ronald.underhill@pnnl.gov (509)375-9765 April 4, 2013 2 | Building Technologies Office eere.energy.gov * Most buildings are not commissioned (Cx) before occupancy, including HVAC and lighting systems * Buildings often are poorly operated and maintained leading to significant energy waste of 5 to 20%, even when they have building automation systems (BASs)

205

Electronic Waste Transformation  

Science Journals Connector (OSTI)

Electronic Waste Transformation ... Instead, entrepreneurial individuals and small businesses recover valuable metals such as copper from obsolete equipment through activities such as burning. ...

CHERYL HOGUE

2012-04-01T23:59:59.000Z

206

Spherical Harmonic Transform Algorithms  

SciTech Connect

A collection of MATLAB classes for computing spherical harmonic transforms are presented and used to solve simple partial differential equations on the sphere. The spectral synthesis and analysis using fast Fourier transforms and Legendre transforms with the associated Legendre functions are presented in depth. A set of methods associated with a spectral\\_field class provides spectral approximation to the $\\DIV$, $\\CURL$, $\\GRAD$, and $\\LAPL$ in spherical geometr y. Laplace inversion and Helmholtz equation solvers are also methods for this clas s. Investigation of algorithms and analysis for spherical harmonic transform optio ns for parallel high performance computers are discussed in the context of global climate and weather models.

Drake, John B [ORNL; Worley, Patrick H [ORNL; D'Azevedo, Eduardo [ORNL

2008-01-01T23:59:59.000Z

207

Engineering Molecular Transformations  

NLE Websites -- All DOE Office Websites (Extended Search)

Engineering Molecular Transformations for Sustainable Energy Conversion Matthew Neurock* Departments of Chemical Engineering and Chemistry, UniVersity of Virginia, CharlottesVille,...

208

Market Transformation Fact Sheet  

Energy.gov (U.S. Department of Energy (DOE))

This fact sheet describes the Fuel Cell Technologies Office's Market Transformation strategies and activities, which are aimed at accelerating early market adoption and advancing pre-competitive technologies.

209

Superluminal transformations in complex Minkowski spaces  

SciTech Connect

We calculate the mixing of real and imaginary components of space and time under the influence of superluminal boots in the x direction. A unique mixing is determined for this superluminal Lorentz transformation when we consider the symmetry properties afforded by the inclusion of three temporal directions. Superluminal transformations in complex six-dimensional space exhibit unique tachyonic connections which have both remote and local space--time event connections.

Ramon, C.; Rauscher, E.A.

1980-08-01T23:59:59.000Z

210

Sequential tasks performed by catalytic pumps for colloidal crystallization  

E-Print Network (OSTI)

Gold-platinum catalytic pumps immersed in a chemical fuel are used to manipulate silica colloids. The manipulation relies on the electric field and the fluid flow generated by the pump. Catalytic pumps perform various tasks, such as the repulsion of colloids, the attraction of colloids, and the guided crystallization of colloids. We demonstrate that catalytic pumps can execute these tasks sequentially over time. Switching from one task to the next is related to the local change of the proton concentration, which modifies the colloid zeta potential and consequently the electric force acting on the colloids.

Ali Afshar Farniya; Maria J. Esplandiu; Adrian Bachtold

2014-10-20T23:59:59.000Z

211

Fourier transform infrared cell for surface studies at controlled temperatures and in controlled atmospheres with time resolution and spatial resolution  

Science Journals Connector (OSTI)

A new micro?Fourier transform infrared cell has been constructed and evaluated using (i) the transformation of aurichalcite crystals at 298–475 K (ii) the adsorption/desorption of pyridine on a Cu2O/ZnO junction and (iii) the adsorption of CO on Pt/alumina pellets; it enables spatial and time resolution of processes in such diverse samples held at known thermal and baric conditions. The potential of this cell in catalytic and analytical science is considered.

V. A. Self; P. A. Sermon

1996-01-01T23:59:59.000Z

212

Final Technical Report [Development of Catalytic Alkylation and Fluoroalkylation Methods  

SciTech Connect

In the early stages of this DOE-funded research project, we sought to prepare and study a well-defined nickel-alkyl complex containing tridentate nitrogen donor ligands. We found that reaction of (TMEDA)NiMe2 (1) with terpyridine ligand cleanly led to the formation of (terpyridyl)NiMe (2), which we also determined to be an active alkylation catalyst. The thermal stability of 2 was unlike that seen for any of the active pybox ligands, and enabled a number of key studies on alkyl transfer reactions to be performed, providing new insights into the mechanism of nickel-mediated alkyl-alkyl cross-coupling reactions. In addition to the mechanistic studies, we showed that the terpyridyl nickel compounds can catalytically cross-couple alkyl iodides in yields up to 98% and bromides in yields up to 46 %. The yields for the bromides can be increased up to 67 % when the new palladium catalyst [(tpy’)Pd-Ph]I is used. The best route to the targeted [(tpy)NiBr] (1) was found to involve the comproportionation reaction of [(dme)NiBr{sub 2}] and [Ni(COD){sub 2}] in the presence of two equivalents of terpyridine. This reaction was driven to high yields of product formation (72 % isolated) by the precipitation of 1 from THF solvent.

Vicic, David A.

2014-05-01T23:59:59.000Z

213

Deployment & Market Transformation (Brochure)  

SciTech Connect

NREL's deployment and market transformation (D and MT) activities encompass the laboratory's full range of technologies, which span the energy efficiency and renewable energy spectrum. NREL staff educates partners on how they can advance sustainable energy applications and also provides clients with best practices for reducing barriers to innovation and market transformation.

Not Available

2012-04-01T23:59:59.000Z

214

TRANSFORMATION FOURIER--BOREL  

E-Print Network (OSTI)

LA TRANSFORMATION DE FOURIER--BOREL : â?? â?? de Hilbert est duale de celle de Gel'fond, tandis que la z e , t h d dz t dont la transforme â??e de Fourier--Borel est #(u) = q th u t e h#u . 0 1 #(## 0 # 1

Waldschmidt, Michel

215

Transforming Education at Einstein  

E-Print Network (OSTI)

Transforming Education at Einstein EinstEin Winter/spring 2012 The Magazine for Alumni and Friends trANsfOrMiNg eDuCAtiON At eiNsteiN Education at Albert Einstein College of Medicine is undergoing

Yates, Andrew

216

Amplified Quantum Transforms  

E-Print Network (OSTI)

In this thesis we investigate two new Amplified Quantum Transforms. In particular we create and analyze the Amplified Quantum Fourier Transform (Amplified-QFT) and the Amplified-Haar Wavelet Transform. First, we provide a brief history of quantum mechanics and quantum computing. Second, we examine the Amplified-QFT in detail and compare it against the Quantum Fourier Transform (QFT) and Quantum Hidden Subgroup (QHS) algorithms for solving the Local Period Problem. We calculate the probabilities of success of each algorithm and show the Amplified-QFT is quadratically faster than the QFT and QHS algorithms. Third, we examine the Amplified-QFT algorithm for solving The Local Period Problem with an Error Stream. Fourth, we produce an uncertainty relation for the Amplified-QFT algorithm. Fifth, we show how the Amplified-Haar Wavelet Transform can solve the Local Constant or Balanced Signal Decision Problem which is a generalization of the Deutsch-Jozsa algorithm.

David Cornwell

2014-06-01T23:59:59.000Z

217

Program Transformation Mechanics A Classification of Mechanisms for Program Transformation  

E-Print Network (OSTI)

Program Transformation Mechanics A Classification of Mechanisms for Program Transformation with a Survey of Existing Transformation Systems Jonne van Wijngaarden Eelco Visser UU-CS-2003-048 Institute Transformation Mechanics A Classification of Mechanisms for Program Transformation with a Survey of Existing

Utrecht, Universiteit

218

Logarithmic transformation of response Logarithmic transformation of response  

E-Print Network (OSTI)

Logarithmic transformation of response Logarithmic transformation of response Often, support S of Y is S = (0, ). Logarithm is then one of transformations to consider when trying to obtain a correct (wrong. Model Building 1. Transformation of response #12;Logarithmic transformation of response When does

Komarek, Arnost

219

IMAGINED TRANSFORMATIONS 1 Running head: IMAGINED TRANSFORMATION OF BODIES  

E-Print Network (OSTI)

IMAGINED TRANSFORMATIONS 1 Running head: IMAGINED TRANSFORMATION OF BODIES Imagined Transformations TRANSFORMATIONS 2 Abstract A number of spatial reasoning problems can be solved by performing an imagined transformation of one's egocentric perspective. A series of experiments were carried out to characterize

Zacks, Jeffrey M.

220

Laplace Transforms (Ch. 7) LAPLACE TRANSFORMS (Ch. 7)  

E-Print Network (OSTI)

Laplace Transforms (Ch. 7) LAPLACE TRANSFORMS (Ch. 7) ? restart; ? with( plots ): ? with( DEtools ): The Laplace transform is a very common, and useful, technique for solving and analyz­ ing the solution of the Laplace transform is that derivatives are transformed into powers; thus, the differential equation

Meade, Douglas B.

Note: This page contains sample records for the topic "determination catalytic transformation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

CATALYTIC MICROWAVE PYROLYSIS OF BIOMASS FOR RENEWABLE PHENOLS AND FUELS .  

E-Print Network (OSTI)

??Bio-oil is an unstable intermediate and needs to be upgraded before its use. This study focused on improving the selectivity of bio-oilby catalytic pyrolysis of… (more)

[No author

2013-01-01T23:59:59.000Z

222

Energy Recovery System for Fluid Catalytic Cracking Units  

E-Print Network (OSTI)

This paper describes the power and heat recovery processes and equipment for modern fluid catalytic cracking (FCC) units made possible by improvements in catalyst fines removal technology and the availability of erosion resistant high temperature...

Wen, H.; Lou, S. C.

1982-01-01T23:59:59.000Z

223

Catalyst Cartography: 3D Super-Resolution Mapping of Catalytic...  

NLE Websites -- All DOE Office Websites (Extended Search)

Catalyst Cartography: 3D Super-Resolution Mapping of Catalytic Activity Thanks to a groundbreaking new method, scientists have created the first 3D super-resolution maps of...

224

In situ XAS Characterization of Catalytic Nano-Materials with...  

NLE Websites -- All DOE Office Websites (Extended Search)

XAS Characterization of Catalytic Nano-Materials with Applications to Fuel Cells and Batteries Friday, July 12, 2013 - 11:00am SLAC, Conference Room 137-322 Presented by Qingying...

225

Catalytic Reactor For Oxidizing Mercury Vapor  

DOE Patents (OSTI)

A catalytic reactor (10) for oxidizing elemental mercury contained in flue gas is provided. The catalyst reactor (10) comprises within a flue gas conduit a perforated corona discharge plate (30a, b) having a plurality of through openings (33) and a plurality of projecting corona discharge electrodes (31); a perforated electrode plate (40a, b, c) having a plurality of through openings (43) axially aligned with the through openings (33) of the perforated corona discharge plate (30a, b) displaced from and opposing the tips of the corona discharge electrodes (31); and a catalyst member (60a, b, c, d) overlaying that face of the perforated electrode plate (40a, b, c) opposing the tips of the corona discharge electrodes (31). A uniformly distributed corona discharge plasma (1000) is intermittently generated between the plurality of corona discharge electrode tips (31) and the catalyst member (60a, b, c, d) when a stream of flue gas is passed through the conduit. During those periods when corona discharge (1000) is not being generated, the catalyst molecules of the catalyst member (60a, b, c, d) adsorb mercury vapor contained in the passing flue gas. During those periods when corona discharge (1000) is being generated, ions and active radicals contained in the generated corona discharge plasma (1000) desorb the mercury from the catalyst molecules of the catalyst member (60a, b, c, d), oxidizing the mercury in virtually simultaneous manner. The desorption process regenerates and activates the catalyst member molecules.

Helfritch, Dennis J. (Baltimore, MD)

1998-07-28T23:59:59.000Z

226

Catalytic pyrolysis using UZM-39 aluminosilicate zeolite  

SciTech Connect

A new family of coherently grown composites of TUN and IMF zeotypes has been synthesized and shown to be effective catalysts for catalytic pyrolysis of biomass. These zeolites are represented by the empirical formula. Na.sub.nM.sub.m.sup.n+R.sub.rQ.sub.qAl.sub.1-xE.sub.xSi.sub.yO.s- ub.z where M represents zinc or a metal or metals from Group 1, Group 2, Group 3 or the lanthanide series of the periodic table, R is an A,.OMEGA.-dihalosubstituted paraffin such as 1,4-dibromobutane, Q is a neutral amine containing 5 or fewer carbon atoms such as 1-methylpyrrolidine and E is a framework element such as gallium. The process involves contacting a carbonaceous biomass feedstock with UZM-39 at pyrolysis conditions to produce pyrolysis gases comprising hydrocarbons. The catalyst catalyzes a deoxygenation reaction converting oxygenated hydrocarbons into hydrocarbons and removing the oxygen as carbon oxides and water. A portion of the pyrolysis gases is condensed to produce low oxygen biomass-derived pyrolysis oil.

Nicholas, Christopher P; Boldingh, Edwin P

2014-10-07T23:59:59.000Z

227

Microchannel Reactor System for Catalytic Hydrogenation  

SciTech Connect

We successfully demonstrated a novel process intensification concept enabled by the development of microchannel reactors, for energy efficient catalytic hydrogenation reactions at moderate temperature, and pressure, and low solvent levels. We designed, fabricated, evaluated, and optimized a laboratory-scale microchannel reactor system for hydrogenation of onitroanisole and a proprietary BMS molecule. In the second phase of the program, as a prelude to full-scale commercialization, we designed and developed a fully-automated skid-mounted multichannel microreactor pilot plant system for multiphase reactions. The system is capable of processing 1 – 10 kg/h of liquid substrate, and an industrially relevant immiscible liquid-liquid was successfully demonstrated on the system. Our microreactor-based pilot plant is one-of-akind. We anticipate that this process intensification concept, if successfully demonstrated, will provide a paradigm-changing basis for replacing existing energy inefficient, cost ineffective, environmentally detrimental slurry semi-batch reactor-based manufacturing practiced in the pharmaceutical and fine chemicals industries.

Adeniyi Lawal; Woo Lee; Ron Besser; Donald Kientzler; Luke Achenie

2010-12-22T23:59:59.000Z

228

Catalytic pyrolysis using UZM-39 aluminosilicate zeolite  

DOE Patents (OSTI)

A new family of coherently grown composites of TUN and IMF zeotypes has been synthesized and show to be effective catalysts for catalytic pyrolysis of biomass. These zeolites are represented by the empirical formula. Na.sub.nM.sub.m.sup.n+R.sub.rQ.sub.qAl.sub1-xE.sub.xSi.sub.yO.s- ub.z where M represents zinc or a metal or metals from Group 1, Group 2, Group 3 or the lanthanide series of the periodic table, R is an A,.OMEGA.-dihalosubstituted paraffin such as 1,4-dibromobutane, Q is a neutral amine containing 5 or fewer carbon atoms such as 1-methylpyrrolidine and E is a framework element such as gallium. The process involves contacting a carbonaceous biomass feedstock with UZM-39 at pyrolysis conditions to produce pyrolysis gases comprising hydrocarbons. The catalyst catalyzes a deoxygenation reaction converting oxygenated hyrdocarbons into hydrocarbons removing the oxygen as carbon oxides and water. A portion of the pyrolysis gases is condensed to produce low oxygen biomass-derived pyrolysis oil.

Nicholas, Christpher P; Boldingh, Edwin P

2013-12-17T23:59:59.000Z

229

Northwestern University Facility for Clean Catalytic Process Research  

SciTech Connect

Northwestern University with DOE support created a Facility for Clean Catalytic Process Research. This facility is designed to further strengthen our already strong catalysis research capabilities and thus to address these National challenges. Thus, state-of-the art instrumentation and experimentation facility was commissioned to add far greater breadth, depth, and throughput to our ability to invent, test, and understand catalysts and catalytic processes, hence to improve them via knowledge-based design and evaluation approaches.

Marks, Tobin Jay [Northwestern University

2013-05-08T23:59:59.000Z

230

Chapter 15 - Catalytic Thermochemical Processes for Biomass Conversion to Biofuels and Chemicals  

Science Journals Connector (OSTI)

Abstract Biomass is the most abundant and biorenewable resource with great potential for sustainable production of chemicals and fuels. Thermochemical conversion technologies (pyrolysis, gasification and hydrothermal liquefaction) are a promising option for transforming biomass feedstocks into liquid oils and chemicals. In the article, for the thermal process of biomass for biofuels and chemicals, the effect of reaction conditions, reactors, solvents and catalysts on the yield and distribution of the products are reviewed. Fast pyrolysis of cellulose is primarily conducted over catalysts with proper acidity/basicity and has undergone many pilot tests. Gasification is typically conducted over supported noble metal catalysts and has been profiled as being CO2-neutral, having a high potential to provide power, chemicals and fuels. Catalytically hydrothermal liquefaction of biomass produces a very complex mixture of liquid products; therefore, novel technology for separation and extraction of downstream products from hydrothermal liquefaction of lignocellulosic biomass need to be developed.

Lin Mei Wu; Chun Hui Zhou; Dong Shen Tong; Wei Hua Yu

2014-01-01T23:59:59.000Z

231

Catalytic and physicochemical properties of aluminoplatinum catalysts modified with indium and gallium  

SciTech Connect

Aluminoplatinum catalysts (APC) are widely used in transformations of hydrocarbons, particularly in reforming of gasoline fractions and dehydrogenation of higher normal paraffins. Promotion of APC with indium and gallium increases their activity and stability in the dehydrogenation of paraffins. Introduction of group III elements in APC inhibits coke formation during dehydrogenation and prevents blocking of the surface of the Pt. The change in the catalytic properties of APC modified with In is due to the partial transfer of the electron density from Pt to In. Both APC with In and Ga additives and monometallic catalysts were studied in the present article by the methods of IR spectroscopy and adsorption. In addition to traditional transmission IR spectroscopy, IR spectroscopy in diffusely scattered light was used, which permits conducting both spectral and adsorption measurements on the same samples.

Zaitsev, A.V.; Tyupaev, A.P.; Borovkov, V.Yu.; Timofeeva, E.A.; Isatulyants, G.V.; Kazanskii, B.B.

1986-10-10T23:59:59.000Z

232

Catalytic Reforming Downstream Processing of Fresh Feed Input  

U.S. Energy Information Administration (EIA) Indexed Site

Process: Catalytic Reforming Catalytic Cracking Catalytic Hydrocracking Delayed and Fluid Coking Period-Unit: Monthly-Thousand Barrels per Day Annual-Thousand Barrels per Day Process: Catalytic Reforming Catalytic Cracking Catalytic Hydrocracking Delayed and Fluid Coking Period-Unit: Monthly-Thousand Barrels per Day Annual-Thousand Barrels per Day Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Process Area Apr-13 May-13 Jun-13 Jul-13 Aug-13 Sep-13 View History U.S. 2,563 2,667 2,739 2,807 2,705 2,609 2010-2013 PADD 1 176 178 180 173 156 167 2010-2013 East Coast 166 164 163 161 140 153 2010-2013 Appalachian No. 1 9 14 16 12 15 14 2010-2013 PADD 2 642 638 668 695 677 615 2010-2013 Ind., Ill. and Ky. 426 411 426 460 450 399 2010-2013 Minn., Wis., N. Dak., S. Dak. 67 62 70 72 72 57 2010-2013 Okla., Kans., Mo.

233

A discrete fractional random transform  

E-Print Network (OSTI)

We propose a discrete fractional random transform based on a generalization of the discrete fractional Fourier transform with an intrinsic randomness. Such discrete fractional random transform inheres excellent mathematical properties of the fractional Fourier transform along with some fantastic features of its own. As a primary application, the discrete fractional random transform has been used for image encryption and decryption.

Zhengjun Liu; Haifa Zhao; Shutian Liu

2006-05-20T23:59:59.000Z

234

Transformer Abdullah Al-Otaibi  

E-Print Network (OSTI)

Transformer Abdullah Al-Otaibi ID#242374 Section#2 Abstract- this is a brief description for transformer and how it works. I. DEFINITION A transformer is a device that transfers electrical energy from of the transformer in 1831. The transformer is used by Faraday only to demonstrate the principle of electromagnetic

Masoudi, Husain M.

235

Effects of dispersion and support on adsorption, catalytic and electronic properties of cobalt/alumina CO hydrogenation catalysts: (Technical progress report)  

SciTech Connect

The continued investigation of dispersion and metal-support interactions and their effects upon the adsorption, activity/selectivity, and electronic properties of the metal in cobalt/alumina (and to a lesser extent on iron/alumina) catalysts is proposed. The objectives of this research are to determine the effects of surface structure and metal dispersion on the adsorption and catalytic properties of cobalt, and determine the effects of metal-support interactions, i.e., effects of decorating support species on metal crystallites and of direct electronic interactions between metal clusters and the support, on the adsoprtion, catalytic and electronic properties of cobalt supported on alumina.

Bartholomew, C.H. Jr.

1986-12-22T23:59:59.000Z

236

Lorentz transformation by mimicking the Lorentz transformation  

E-Print Network (OSTI)

We show that starting with the fact that special relativity theory is concerned with a distortion of the observed length of a moving rod, without mentioning if it is a "contraction" or "dilation", we can derive the Lorentz transformations for the spacetime coordinates of the same event. This derivation is based on expressing the length of the moving rod as a sum of components with all the lengths involved in this summation being measured by the observers of the same inertial reference frame.

Bernhard Rothenstein; Stefan Popescu

2007-09-24T23:59:59.000Z

237

Market Transformation Fact Sheet  

NLE Websites -- All DOE Office Websites (Extended Search)

Transformation Market Transformation is based on the concept that federal support can catalyze a market to achieve economic and environmental benefits that can reduce costs through economies of scale. Adoption of fuel cells in emerging markets expands the growth of green jobs, with new opportunities in manufacturing, fuel cell maintenance and support systems, and domestic hydrogen fuel production and delivery. By providing reliable field operations data and increasing user confidence, early market deployments help overcome non-technical challenges like developing appropriate safety codes and standards and reducing high insurance costs. Strategies Market Transformation's primary goal is to accelerate the expansion of hydrogen and fuel cell use by lowering the life

238

Synthesis and characterization of supported heteropolymolybdate nanoparticles between silicate layers of Bentonite with enhanced catalytic activity for epoxidation of alkenes  

SciTech Connect

Highlights: {yields} The PVMo and nanocomposite catalyst (PVMo/Bentonite) as catalyst for epoxidation of alkenes. {yields} The composite catalyst showed higher catalytic activity than parent heteropolymolybdate (PVMo). {yields}The use of ultrasonic irradiation increased the conversions and reduced the reaction times. {yields} The H{sub 2}O{sub 2} is a green and eco-friendly oxidant in this catalytic system. -- Abstract: A new heterogeneous catalyst (PVMo/Bentonite) consisting of vanadium substituted heteropolymolybdate with Keggin-type structure Na{sub 5}[PV{sub 2}Mo{sub 10}O{sub 40}].14H{sub 2}O (PVMo) supported between silicate layers of bentonite has been synthesized by impregnation method and characterized using X-ray diffraction, Fourier-transformed infrared spectroscopy, scanning electron microscopy, UV-vis diffuse reflectance spectroscopy, transmission electron microscopy and elemental analysis. X-ray diffraction and scanning electron microscopy analysis indicated that PVMo was finely dispersed into layers of bentonite as support. The PVMo/Bentonite used as an efficient heterogeneous catalyst for epoxidation of alkenes. Various cyclic and linear alkenes were oxidized into the corresponding epoxides in high yields and selectivity with 30% aqueous H{sub 2}O{sub 2}. The catalyst was reused several times, without observable loss of activity and selectivity. The obtained results showed that the catalytic activity of the PVMo/Bentonite was higher than that of pure heteropolyanion (PVMo).

Salavati, Hossein, E-mail: hosseinsalavati@yahoo.com [Department of Chemistry, Payame Noor University (PNU), 19395-4697, Tehran, Islamic Republic of Iran (Iran, Islamic Republic of)] [Department of Chemistry, Payame Noor University (PNU), 19395-4697, Tehran, Islamic Republic of Iran (Iran, Islamic Republic of); Rasouli, Nahid [Department of Chemistry, Payame Noor University (PNU), 19395-4697, Tehran, Islamic Republic of Iran (Iran, Islamic Republic of)] [Department of Chemistry, Payame Noor University (PNU), 19395-4697, Tehran, Islamic Republic of Iran (Iran, Islamic Republic of)

2011-11-15T23:59:59.000Z

239

TRANSFORMATIONS 4.1 TRANSFORMATIONS, ISOMETRIES. The term transformation has several  

E-Print Network (OSTI)

1 Chapter 4 TRANSFORMATIONS 4.1 TRANSFORMATIONS, ISOMETRIES. The term transformation has several. On the other hand, in linear algebra courses a linear transformation maps vectors to vectors and subspaces to subspaces. When we use the term transformation in geometry, however, we have all of these interpretations

240

Linear Transformer Ideal Transformer Consider linear and ideal transformers attached to Circuit 1 and Circuit 2.  

E-Print Network (OSTI)

Linear Transformer Ideal Transformer I1 + V2 _ + V1 _ Consider linear and ideal transformers in linear transformer equations for :MLL ,, 21 ( ) ( ) ( ) ( ) ( ) ( ) 12212212 2 1 112 2 12 2 1 2212 2 PP Now solve the linear transformer equations for the currents: 1 212 2 22 2 1 2 1 212 2 22 12 2 2 2

Kozick, Richard J.

Note: This page contains sample records for the topic "determination catalytic transformation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Transforming California's Freight Transport System  

E-Print Network (OSTI)

Transforming California's Freight Transport System Policy Forum on the Role of Freight Transport Standard #12;2050 Vision- Key Conceptual Outcomes Technology Transformation Early Action Cleaner Combustion Multiple Strategies Federal Action Efficiency Gains Energy Transformation 9 #12;Further reduce localized

California at Davis, University of

242

Energy systems transformation  

Science Journals Connector (OSTI)

Energy systems transformation 10...associated with the incumbent energy economy that is unlikely to...its gatekeepers, such as auditors, analysts, debt-rating...problems generated by the energy system became more visible...

A. T. C. Jérôme Dangerman; Hans Joachim Schellnhuber

2013-01-01T23:59:59.000Z

243

The Quantum Mellin transform  

E-Print Network (OSTI)

We uncover a new type of unitary operation for quantum mechanics on the half-line which yields a transformation to ``Hyperbolic phase space''. We show that this new unitary change of basis from the position x on the half line to the Hyperbolic momentum $p_\\eta$, transforms the wavefunction via a Mellin transform on to the critial line $s=1/2-ip_\\eta$. We utilise this new transform to find quantum wavefunctions whose Hyperbolic momentum representation approximate a class of higher transcendental functions, and in particular, approximate the Riemann Zeta function. We finally give possible physical realisations to perform an indirect measurement of the Hyperbolic momentum of a quantum system on the half-line.

J. Twamley; G. J. Milburn

2007-02-12T23:59:59.000Z

244

Transformation inverse design  

E-Print Network (OSTI)

We present a new technique for the design of transformation-optics devices based on large-scale optimization to achieve the optimal effective isotropic dielectric materials within prescribed index bounds, which is ...

Liu, David

245

Series Transmission Line Transformer  

DOE Patents (OSTI)

A series transmission line transformer is set forth which includes two or more of impedance matched sets of at least two transmissions lines such as shielded cables, connected in parallel at one end ans series at the other in a cascading fashion. The cables are wound about a magnetic core. The series transmission line transformer (STLT) which can provide for higher impedance ratios and bandwidths, which is scalable, and which is of simpler design and construction.

Buckles, Robert A. (Livermore, CA); Booth, Rex (Livermore, CA); Yen, Boris T. (El Cerrito, CA)

2004-06-29T23:59:59.000Z

246

Ionic Liquids as Solvents for Catalytic Conversion of Lignocellulosic Feedstocks  

E-Print Network (OSTI)

attractive platforms for synthesis of chemicals, fuels, andchemical transformation of biorenewable feedstocks to platform

Dee, Sean Joseph

2012-01-01T23:59:59.000Z

247

APPENDIX F. TRANSFORMS, COMPLEX ANALYSIS 1 Transforms, Complex  

E-Print Network (OSTI)

APPENDIX F. TRANSFORMS, COMPLEX ANALYSIS 1 Appendix F Transforms, Complex Analysis This appendix discusses Fourier and Laplace transforms as they are used in plasma physics and this book. Also, key properties of complex variable theory that are needed for understanding and inverting these transforms

Callen, James D.

248

From transformation traces to transformation rules: Assisting Model Driven Engineering  

E-Print Network (OSTI)

From transformation traces to transformation rules: Assisting Model Driven Engineering approach. In this paper we are interested in semi-automatically gen- erating labelled graph (model) transformations conform to a particu- lar syntax (meta-model). Those transformations are basic operations in model driven

Paris-Sud XI, Université de

249

Optical transformation from chirplet to fractional Fourier transformation kernel  

E-Print Network (OSTI)

We find a new integration transformation which can convert a chirplet function to fractional Fourier transformation kernel, this new transformation is invertible and obeys Parseval theorem. Under this transformation a new relationship between a phase space function and its Weyl-Wigner quantum correspondence operator is revealed.

Hong-yi Fan; Li-yun Hu

2009-02-11T23:59:59.000Z

250

Laplace Transforms An integral transform is an operator  

E-Print Network (OSTI)

9­28­1998 Laplace Transforms An integral transform is an operator F (s) = Z b a K(s; t)f(t) dt: The input to the transform is the function f(t); the output is the function F (s). (By convention, small letters denote the inputs to a transform, and the corresponding capital letters denote the corresponding

Ikenaga, Bruce

251

Transform Coding: Past, Present, and Future Transforms are perva-  

E-Print Network (OSTI)

Transform Coding: Past, Present, and Future Transforms are perva- sive in signal process- ing) and wavelets are part of the widely used JPEG standards, transforms are at the heart of the compression engine of transforms in compression, and the flurry of activ- ity in both research and applications around signal

Vetterli, Martin

252

Development of a catalytically assisted combustor for a gas turbine  

Science Journals Connector (OSTI)

A catalytically assisted low \\{NOx\\} combustor has been developed which has the advantage of catalyst durability. This combustor is composed of a burner section and a premixed combustion section behind the burner section. The burner system consists of six catalytic combustor segments and six premixing nozzles, which are arranged alternately and in parallel. Fuel flow rate for the catalysts and the premixing nozzles are controlled independently. The catalytic combustion temperature is maintained under 1000°C, additional premixed gas is injected from the premixing nozzles into the catalytic combustion gas, and lean premixed combustion at 1300°C is carried out in the premixed combustion section. This system was designed to avoid catalytic deactivation at high temperature and thermal or mechanical shock fracture of the honeycomb monolith. In order to maintain the catalyst temperature under 1000°C, the combustion characteristics of catalysts at high pressure were investigated using a bench scale reactor and an improved catalyst was selected for the combustor test. A combustor for a 20 MW class multi-can type gas turbine was designed and tested under high pressure conditions using LNG fuel. Measurements of NOx, CO and unburned hydrocarbon were made and other measurements were made to evaluate combustor performance under various combustion temperatures and pressures. As a result of the tests, it was proved that \\{NOx\\} emission was lower than 10 ppm converted at 16% O2, combustion efficiency was almost 100% at 1300°C of combustor outlet temperature and 13.5 ata of combustor inlet pressure.

Yasushi Ozawa; Tomoharu Fujii; Mikio Sato; Takaaki Kanazawa; Hitoshi Inoue

1999-01-01T23:59:59.000Z

253

CATALYTIC GASIFICATION OF COAL USING EUTECTIC SALT MIXTURES  

SciTech Connect

The Gas Research Institute (GRI) estimates that by the year 2010, 40% or more of U.S. gas supply will be provided by supplements including substitute natural gas (SNG) from coal. These supplements must be cost competitive with other energy sources. The first generation technologies for coal gasification e.g. the Lurgi Pressure Gasification Process and the relatively newer technologies e.g. the KBW (Westinghouse) Ash Agglomerating Fluidized-Bed, U-Gas Ash Agglomerating Fluidized-Bed, British Gas Corporation/Lurgi Slagging Gasifier, Texaco Moving-Bed Gasifier, and Dow and Shell Gasification Processes, have several disadvantages. These disadvantages include high severities of gasification conditions, low methane production, high oxygen consumption, inability to handle caking coals, and unattractive economics. Another problem encountered in catalytic coal gasification is deactivation of hydroxide forms of alkali and alkaline earth metal catalysts by oxides of carbon (CO{sub x}). To seek solutions to these problems, a team consisting of Clark Atlanta University (CAU, a Historically Black College and University, HBCU), the University of Tennessee Space Institute (UTSI) and Georgia Institute of Technology (Georgia Tech) proposed to identify suitable low melting eutectic salt mixtures for improved coal gasification. The research objectives of this project were to: Identify appropriate eutectic salt mixture catalysts for coal gasification; Assess agglomeration tendency of catalyzed coal; Evaluate various catalyst impregnation techniques to improve initial catalyst dispersion; Determine catalyst dispersion at high carbon conversion levels; Evaluate effects of major process variables (such as temperature, system pressure, etc.) on coal gasification; Evaluate the recovery, regeneration and recycle of the spent catalysts; and Conduct an analysis and modeling of the gasification process to provide better understanding of the fundamental mechanisms and kinetics of the process.

Dr. Yaw D. Yeboah; Dr. Yong Xu; Dr. Atul Sheth; Dr. Pradeep Agrawal

2001-12-01T23:59:59.000Z

254

Enhanced thermal and gas flow performance in a three-way catalytic converter through use of insulation within the ceramic monolith  

Energy.gov (U.S. Department of Energy (DOE))

Emissions performance comparison of conventional catalytic converter with multi-channel catalytic converter (ceramic fiber insulation layers introduced into ceramic monolith of three-way catalytic converter)

255

DOE - Office of Legacy Management -- Catalytic Co - PA 40  

NLE Websites -- All DOE Office Websites (Extended Search)

Catalytic Co - PA 40 Catalytic Co - PA 40 FUSRAP Considered Sites Site: Catalytic Co. (PA.40 ) Eliminated from further consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: Philadelphia , Pennsylvania PA.40-1 Evaluation Year: 1991 PA.40-1 Site Operations: Prime contractor for construction of the Fernald facility. Records indicate one time shipment of a very small quantity (4 lbs) of uranium metal to this site. PA.40-1 Site Disposition: Eliminated - Construction contractor - Potential for residual contamination from the very small quantity of uranium shipped to this site is considered remote PA.40-2 Radioactive Materials Handled: None - as a construction contractor Primary Radioactive Materials Handled: Uranium Metal - Believed to be a Souvenier. PA.40-1

256

Imaging Catalytic Surfaces by Multiplexed Capillary Electrophoresis With Absorption Detection  

SciTech Connect

A new technique for in situ imaging and screening heterogeneous catalysts by using multiplexed capillary electrophoresis with absorption detection was developed. By bundling the inlets of a large number of capillaries, an imaging probe can be created that can be used to sample products formed directly from a catalytic surface with high spatial resolution. In this work, they used surfaces made of platinum, iron or gold wires as model catalytic surfaces for imaging. Various shapes were recorded including squares and triangles. Model catalytic surfaces consisting of both iron and platinum wires in the shape of a cross were also imaged successfully. Each of the two wires produced a different electrochemical product that was separated by capillary electrophoresis. Based on the collected data they were able to distinguish the products from each wire in the reconstructed image.

Michael Christodoulou

2002-08-27T23:59:59.000Z

257

Test results of a catalytic combustor for a gas turbine  

Science Journals Connector (OSTI)

A catalytically assisted low \\{NOx\\} combustor has been developed which has the advantage of catalyst durability. Combustion characteristics of catalysts at high pressure were investigated using a bench scale reactor and an improved catalyst was selected. A combustor for multi-can type gas turbine of 10 MW class was designed and tested at high-pressure conditions using liquefied natural gas (LNG) fuel. This combustor is composed of a burner system and a premixed combustion zone in a ceramic type liner. The burner system consists of catalytic combustor segments and premixing nozzles. Catalyst bed temperature is controlled under 1000°C, premixed gas is injected from the premixing nozzles to catalytic combustion gas and lean premixed combustion is carried out in the premixed combustion zone. As a result of the combustion tests, \\{NOx\\} emission was lower than 5 ppm converted at 16% O2 at a combustor outlet temperature of 1350°C and a combustor inlet pressure of 1.33 MPa.

Y Ozawa; T Fujii; Y Tochihara; T Kanazawa; K Sagimori

1998-01-01T23:59:59.000Z

258

CX-010981: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Determination High-Throughput Study of Diffusion and Phase Transformation Kinetics of Magnesium-Based Systems... CX(s) Applied: A9 Date: 09132013 Location(s): Wisconsin...

259

CX-011647: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

CX-011647: Categorical Exclusion Determination Replacement of Big Hill TX-14 Transformer, Government Furnished Equipment CX(s) Applied: B1.3 Date: 10312013 Location(s):...

260

CX-000554: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

CX-000554: Categorical Exclusion Determination Ogallala Substation KY1A Transformer Replacement CX(s) Applied: B4.6 Date: 11162009 Location(s): Ogallala, Nebraska...

Note: This page contains sample records for the topic "determination catalytic transformation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

CX-009224: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

CX-009224: Categorical Exclusion Determination Project L-718, Electrical Utilities Transformer Management Support Facility CX(s) Applied: B1.15 Date: 09042012 Location(s):...

262

CX-008826: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Categorical Exclusion Determination Remanufacture, Transport, and Install BHTX-29 Transformer CX(s) Applied: B1.3 Date: 07172012 Location(s): Texas Offices(s): Strategic...

263

CX-010741: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

CX-010741: Categorical Exclusion Determination Smart Market Advance Retrofit Transformer Program (SMART Scale) CX(s) Applied: A9, B5.1 Date: 08092013 Location(s):...

264

Transformer design and application considerations for nonsinusoidal load currents  

SciTech Connect

The use of adjustable-speed drives requires transformers capable of withstanding high levels of harmonic currents under normal operating conditions. Experience has been that overheating problems are much more common with dry-type transformers than with liquid-filled transformers. Transformer insulation life is determined by the hot spot temperature but confirmation of hot spot temperature rise is one performance characteristic which is ignored in industry standards. This is especially important for transformers rated for nonsinusoidal load currents. Hot spot allowances used in IEEE standards for ventilated dry-type transformers were developed in 1944 and recent data indicates that revisions are required. The design of transformers for nonsinusoidal load currents should include an analysis of the eddy loss distribution in the windings and calculation of the hot spot temperature rise. Calculations and thermal tests giving only average winding temperature rises are not sufficient. Thermal tests with nonsinusoidal currents and measurements of hot spot temperature rises are extremely difficult on large transformers. The combination of testing and analysis may be the only economically practical approach. Analysis indicates that the dry type transformer hot spot temperature is very sensitive to the eddy loss magnitude and distribution. The Underwriters Laboratories Inc. (UL) K-factor rated dry type transformer and the recommended practices given in ANSI/IEEE C57.110 are reviewed. When purchasing transformers subject to nonsinusoidal load currents, considerations should be given to the manufacturer`s development program and capability to calculate the eddy loss distribution and hot spot temperatures.

Pierce, L.W. [General Electric Co., Rome, GA (United States)] [General Electric Co., Rome, GA (United States)

1996-05-01T23:59:59.000Z

265

Fuel Flexible, Low Emission Catalytic Combustor for Opportunity Fuel Applications  

SciTech Connect

Limited fuel resources, increasing energy demand and stringent emission regulations are drivers to evaluate process off-gases or process waste streams as fuels for power generation. Often these process waste streams have low energy content and/or highly reactive components. Operability of low energy content fuels in gas turbines leads to issues such as unstable and incomplete combustion. On the other hand, fuels containing higher-order hydrocarbons lead to flashback and auto-ignition issues. Due to above reasons, these fuels cannot be used directly without modifications or efficiency penalties in gas turbine engines. To enable the use of these wide variety of fuels in gas turbine engines a rich catalytic lean burn (RCL®) combustion system was developed and tested in a subscale high pressure (10 atm.) rig. The RCL® injector provided stability and extended turndown to low Btu fuels due to catalytic pre-reaction. Previous work has shown promise with fuels such as blast furnace gas (BFG) with LHV of 85 Btu/ft3 successfully combusted. This program extends on this work by further modifying the combustor to achieve greater catalytic stability enhancement. Fuels containing low energy content such as weak natural gas with a Lower Heating Value (LHV) of 6.5 MJ/m3 (180 Btu/ft3 to natural gas fuels containing higher hydrocarbon (e.g ethane) with LHV of 37.6 MJ/m3 (1010 Btu/ft3) were demonstrated with improved combustion stability; an extended turndown (defined as the difference between catalytic and non-catalytic lean blow out) of greater than 250oF was achieved with CO and NOx emissions lower than 5 ppm corrected to 15% O2. In addition, for highly reactive fuels the catalytic region preferentially pre-reacted the higher order hydrocarbons with no events of flashback or auto-ignition allowing a stable and safe operation with low NOx and CO emissions.

Eteman, Shahrokh

2013-06-30T23:59:59.000Z

266

Categorical Exclusion Determinations: Kentucky | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Kentucky Kentucky Categorical Exclusion Determinations: Kentucky Location Categorical Exclusion Determinations issued for actions in Kentucky. DOCUMENTS AVAILABLE FOR DOWNLOAD September 23, 2013 CX-010919: Categorical Exclusion Determination Advanced Catalytic Solvent for Carbon Dioxide (CO2) Capture CX(s) Applied: B3.6 Date: 09/23/2013 Location(s): Kentucky Offices(s): National Energy Technology Laboratory September 23, 2013 CX-010921: Categorical Exclusion Determination Advanced Catalytic Solvent for Carbon Dioxide (CO2) Capture CX(s) Applied: A9 Date: 09/23/2013 Location(s): Kentucky Offices(s): National Energy Technology Laboratory July 25, 2013 CX-010606: Categorical Exclusion Determination Development of Subsurface Brine Disposal Framework in the Northern Appalachian Basin

267

Structures of the Ca2+-regulated photoprotein obelin Y138F mutant before and after bioluminescence support the catalytic function of a water molecule in the reaction  

Science Journals Connector (OSTI)

Crystal structures of the Y138F obelin mutant before and after bioluminescence have been determined at 1.72 and 1.30 ? resolution, respectively. Their spatial structures support the catalytic function of a water molecule found in an internal cavity in the light-emission reaction of Ca2+-regulated photoproteins.

Natashin, P.V.

2014-02-15T23:59:59.000Z

268

Novel Fast Pyrolysis/Catalytic Technology for the Production of Stable Upgraded Liquids  

SciTech Connect

The objective of the proposed research is the demonstration and development of a novel biomass pyrolysis technology for the production of a stable bio-oil. The approach is to carry out catalytic hydrodeoxygenation (HDO) and upgrading together with pyrolysis in a single fluidized bed reactor with a unique two-level design that permits the physical separation of the two processes. The hydrogen required for the HDO will be generated in the catalytic section by the water-gas shift reaction employing recycled CO produced from the pyrolysis reaction itself. Thus, the use of a reactive recycle stream is another innovation in this technology. The catalysts will be designed in collaboration with BASF Catalysts LLC (formerly Engelhard Corporation), a leader in the manufacture of attrition-resistant cracking catalysts. The proposed work will include reactor modeling with state-of-the-art computational fluid dynamics in a supercomputer, and advanced kinetic analysis for optimization of bio-oil production. The stability of the bio-oil will be determined by viscosity, oxygen content, and acidity determinations in real and accelerated measurements. A multi-faceted team has been assembled to handle laboratory demonstration studies and computational analysis for optimization and scaleup.

Ted Oyama, Foster Agblevor, Francine Battaglia, Michael Klein

2013-01-18T23:59:59.000Z

269

Research Councils UK Transforming  

E-Print Network (OSTI)

research is helping to accelerate the use of green energy technologies. RCUK has played a key role to help combat climate change, accelerate the deployment of green energy technologies and create newResearch Councils UK Transforming our energy future #12;Research funded by the Research Councils

Berzins, M.

270

TO TRANSFORM BIOMEDICAL ENGINEERING  

E-Print Network (OSTI)

IT'S TIME TO TRANSFORM BIOMEDICAL ENGINEERING EDUCATION #12;Charles H. & Bettye Barclay Professor Head, Department of Biomedical Engineering Texas A&M University We're dedicated to solving the world in biomedical engineering research and education ­ and we're well on our way. Our faculty continues to engineer

271

Use of Pd membranes in catalytic reactors for steam methane reforming for pure hydrogen production  

Science Journals Connector (OSTI)

This review analyzes publications on experimental studies and mathematical modeling in the field of development of a catalytic reformer (mainly, steam methane conversion) with a fixed catalytic bed. The specif...

A. B. Shigarov; V. D. Meshcheryakov…

2011-10-01T23:59:59.000Z

272

Impact of Biodiesel-Based Na on the Selective Catalytic Reduction...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Impact of Biodiesel-Based Na on the Selective Catalytic Reduction (SCR) of NOx Using Cu-zeolite Impact of Biodiesel-Based Na on the Selective Catalytic Reduction (SCR) of NOx Using...

273

E-Print Network 3.0 - atpase catalytic domain Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

impressive progress has been made in understanding of the catalytic mechanism of F-type ATP synthase, which is the key enzyme in the energy metabolism of Summary: of the catalytic...

274

Enhanced thermal and gas flow performance in a three-way catalytic...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

flow performance in a three-way catalytic converter through use of insulation within the ceramic monolith Enhanced thermal and gas flow performance in a three-way catalytic...

275

Utilization and Mitigation of VAM/CMM Emissions by a Catalytic Combustion Gas Turbine  

Science Journals Connector (OSTI)

A system configured with a catalytic combustion gas turbine generator unit is introduced. The system has ... Heavy Industries, Ltd., such as small gas turbines, recuperators and catalytic combustors, and catalyti...

K. Tanaka; Y. Yoshino; H. Kashihara; S. Kajita

2013-01-01T23:59:59.000Z

276

Process analysis of syngas production by non-catalytic POX of oven gas  

Science Journals Connector (OSTI)

A non-catalytic POX of oven gas is proposed to solve the problem of secondary pollution due to solid wastes produced from the great amount of organic sulfur contained in oven gas in the traditional catalytic p...

Fuchen Wang; Xinwen Zhou; Wenyuan Guo…

2009-03-01T23:59:59.000Z

277

Student Preferences for Academic Advisors as Transformational Leaders  

E-Print Network (OSTI)

A quantitative study was conducted to determine the preferences of undergraduate students for academic advisors as transformational leaders. A questionnaire was developed and distributed to undergraduate students enrolled in leadership classes at a...

Drozd, Deborah Suzanne

2011-02-22T23:59:59.000Z

278

Final Report: Catalytic Hydrocarbon Reactions over Supported Metal Oxides, August 1, 1995 - July 31, 1999  

SciTech Connect

The research program focused on the catalysis of hydrodesulfurization (HDS) over molybdenum-based catalysts and how catalyst composition, redox ability, structure and neighboring sites control the catalytic properties of metal oxides. We sought to understand the catalytic features/sites that control hydrogenation, hydrogenolysis, and isomerization during HDS. Unprompted silica-supported molybdenum oxides and molybdenum sulfides were studied. Model catalyst systems were prepared from organometallic precursors or cluster compounds to generate supported structures that feature Mo(II) and Mo(IV) cations that are isolated or in ensembles and that have either Mo-O or Mo-S bonds. Conventional MOS{sub 2} catalysts, which contain both edge and rim sites, were be studied. Finally, single-layer MOS{sub 2} structures were also prepared from 2H-MoS{sub 2} powder so that the model systems could be compared against a disulfide catalyst that only involves rim sites. Catalytic reactions for thiophene and tetrahydrothione were studied over the various catalysts. Oxidation states were determined using X-ray photoelectron spectroscopy. X-ray crystallography was used to characterize and follow changes in the MOS{sub 2} structures. The program on metal oxides prepared supported oxides that have a specific structure and oxidation state to serve as model templates for the more complex commercial catalysts and then employed these structures in reaction studies. This focus area examined the relationships between structure and cation redox characteristics in oxidation catalysis. Infrared and Raman spectroscopy were used to characterize the cations and reaction intermediates.

Ekerdt, John G.

1999-07-31T23:59:59.000Z

279

Aluminosilicates as controlled molecular environments for selective photochemical and catalytic reactions  

SciTech Connect

This dissertation concerns research that involves photochemical, catalytic and spectroscopic studies of clays, pillared clays and zeolites. Incorporation of uranyl ions into hectorite, montmorillonite, bentonite and vermiculite clays was monitored by XRD and luminescence methods. Excitation and emission characteristics were studied in order to understand the behavior of uranyl ions in clays after various thermal treatments. Luminescence lifetime measurements elucidated the number of uranyl sites. Uranyl-exchanged clays were found to absorb light at lower energies (445-455nm) than analogous uranyl-exchanged zeolites (425nm). Each uranyl-exchanged clay was tested as a catalyst for the photoassisted oxidation of isopropyl alcohol. Energy transfer (ET) between uranyl and Eu(III) ions in different zeolite framework systems was examined. The efficiency of ET (eta/sub t/) was found to be affected by the type of framework present. Pillared bentonites were examined in the hydrocracking of decane. A catalytically and spectroscopically active dopant ion, Cr(III), was introduced into the clays in both pillared and unpillared forms depending upon synthetic conditions. EPR and DRS were employed to monitor the environment of Cr(III) for determination of its location - whether in the micropore structure or associated with alumina pillars. Catalytic behavior based upon this variability of location was examined. Incorporation of Cr(III) ions into an alumina pillar was found to increase the stability and activity with respect to an alumina PILC catalyst. The results of these studies suggest that selective, efficient catalysts can be designed around inorganic ions in aluminosilicate supports.

Carrado, K.A.

1986-01-01T23:59:59.000Z

280

High Performance Catalytic Heat Exchanger for SOFC Systems - FuelCell Energy  

NLE Websites -- All DOE Office Websites (Extended Search)

Catalytic Heat Catalytic Heat Exchanger for SOFC Systems-FuelCell Energy Background In a typical solid oxide fuel cell (SOFC) power generation system, hot (~900 °C) effluent gas from a catalytic combustor serves as the heat source within a high-temperature heat exchanger, preheating incoming fresh air for the SOFC's cathode. The catalytic combustor and the cathode air heat exchanger together represent the largest opportunity for cost

Note: This page contains sample records for the topic "determination catalytic transformation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Fuel-Flexible, Low-Emissions Catalytic Combustor for Opportunity Fuels  

Energy.gov (U.S. Department of Energy (DOE))

Factsheet overview of how project will develop a unique, feul-flexible catalytic combustor for gas turbines

282

The Biodiversity of Catalytic Super-Brownian Motion Klaus Fleischmann  

E-Print Network (OSTI)

The Biodiversity of Catalytic Super-Brownian Motion Klaus Fleischmann WeierstraÃ?-Institut f that the reactant has an infinite local biodiversity or genetic abundance. This contrasts the finite local biodiversity of the equilibrium of classical super-Brownian motion. Another question we address

Klenke, Achim

283

Short Communication Catalytic coal gasification: use of calcium versus potassium*  

E-Print Network (OSTI)

Short Communication Catalytic coal gasification: use of calcium versus potassium* Ljubisa R on the gasification in air and 3.1 kPa steam of North Dakota lignitic chars prepared under slow and rapid pyrolysis of calcium is related to its sintering via crystallite growth. (Keywords: coal; gasification; catalysis

284

Catalytic Domain of Phosphoinositide-specific Phospholipase C (PLC)  

E-Print Network (OSTI)

Catalytic Domain of Phosphoinositide-specific Phospholipase C (PLC) MUTATIONAL ANALYSIS OF RESIDUES WITHIN THE ACTIVE SITE AND HYDROPHOBIC RIDGE OF PLC 1* (Received for publication, November 20, 1997 Institute, University of Dundee, Dundee DD1 4HN, United Kingdom Structural studies of phospholipase C 1 (PLC

Williams, Roger L.

285

Catalytic gasification of automotive shredder residues with hydrogen generation  

Science Journals Connector (OSTI)

Hydrogen is a clean and new energy carrier to generate power through the Proton exchange membrane fuel cell (PEMFC) system. Hydrogen can be effectively turned out through the catalytic gasification of organic material such as automotive shredder residues (ASR). The main objective of this manuscript is to present an analysis of the catalytic gasification of ASR for the generation of high-purity hydrogen in a lab-scale fixed-bed downdraft gasifier using 15 wt.% NiO/Al2O3 catalysts at 760–900 K. In the catalytic gasification process, reduction of Ni(II) catalyst into Ni(0) has been confirmed through XANES spectra and consequently EXAFS data shows that the central Ni atoms have Ni–O and Ni–Ni bonds with bond distances of 2.03 ± 0.05 and 2.46 ± 0.05 Å, respectively. ASR is partially oxidized and ultimately converts into hydrogen rich syngas (CO and H2) and increases of the reaction temperature are favored the generation of hydrogen with decomposition of the CO. As well, approximately 220 kg h?1 of ASR would be catalytically gasified at 760–900 K and 46.2 atm with the reactor volume 0.27 m3 to obtain approximately 3.42 × 105 kcal h?1 of thermal energy during over 87% syngas generation with the generation of 100 kW electric powers.

Kuen-Song Lin; Sujan Chowdhury; Ze-Ping Wang

2010-01-01T23:59:59.000Z

286

Production of Syngas by Direct Catalytic Oxidation of Methane  

Science Journals Connector (OSTI)

...DESORPTION AT HIGH-TEMPERATURES...of abundant natural gas into liquid...a 50-mI high-pressure Autoclave...atmospheric pressure, and the...with very high CH4 yields...Contact times of gases within the...catalytic combustors and reactors...

D. A. Hickman; L. D. Schmidt

1993-01-15T23:59:59.000Z

287

Ex-Situ Catalytic Fast Pyrolysis Technology Pathway  

SciTech Connect

This technology pathway case investigates converting woody biomass using ex-situ catalytic fast pyrolysis followed by upgrading to gasoline-, diesel-, and jet-range hydrocarbon blendstocks. Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified.

Biddy, M.; Dutta, A.; Jones, S.; Meyer, A.

2013-03-01T23:59:59.000Z

288

In-Situ Catalytic Fast Pyrolysis Technology Pathway  

SciTech Connect

This technology pathway case investigates converting woody biomass using in-situ catalytic fast pyrolysis followed by upgrading to gasoline-, diesel-, and jet-range hydrocarbon blendstocks. Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified.

Biddy, M.; Dutta, A.; Jones, S.; Meyer, A.

2013-03-01T23:59:59.000Z

289

Scaling behavior of optimally structured catalytic microfluidic reactors  

E-Print Network (OSTI)

In this study of catalytic microfluidic reactors we show that, when optimally structured, these reactors share underlying scaling properties. The scaling is predicted theoretically and verified numerically. Furthermore, we show how to increase the reaction rate significantly by distributing the active porous material within the reactor using a high-level implementation of topology optimization.

Okkels, F; Bruus, Henrik; Okkels, Fridolin

2006-01-01T23:59:59.000Z

290

Nanostructured Molybdenum Carbide: Sonochemical Synthesis and Catalytic Properties  

E-Print Network (OSTI)

to be a useful technique to generate nanophase transition metals.7,8 Recently, molybdenum and tungsten carbides of metal salts.5,6 Sonochemical decomposition of transition metal carbonyl compounds has also been provenNanostructured Molybdenum Carbide: Sonochemical Synthesis and Catalytic Properties Taeghwan Hyeon

Suslick, Kenneth S.

291

Catalytically upgraded landfill gas as a cost-effective alternative for fuel cells  

Science Journals Connector (OSTI)

The potential use of landfill gas as feeding fuel for the so-called molten carbonate fuel cells (MCFC) imposes the need for new upgrading technologies in order to meet the much tougher feed gas specifications of this type of fuel cells in comparison to gas engines. Nevertheless, MCFC has slightly lower purity demands than low temperature fuel cells. This paper outlines the idea of a new catalytic purification process for landfill gas conditioning, which may be supposed to be more competitive than state-of-the-art technologies and summarises some lab-scale results. This catalytic process transforms harmful landfill gas minor compounds into products that can be easily removed from the gas stream by a subsequent adsorption step. The optimal process temperature was found to be in the range 250–400 °C. After a catalyst screening, two materials were identified, which have the ability to remove all harmful minor compounds from landfill gas. The first material was a commercial alumina that showed a high activity towards the removal of organic silicon compounds. The alumina protects both a subsequent catalyst for the removal of other organic minor compounds and the fuel cell. Due to gradual deactivation caused by silica deposition, the activated alumina needs to be periodically replaced. The second material was a commercial V2O5/TiO2-based catalyst that exhibited a high activity for the total oxidation of a broad spectrum of other harmful organic minor compounds into a simpler compound class “acid gases (HCl, HF and SO2)”, which can be easily removed by absorption with, e.g. alkalised alumina. The encouraging results obtained allow the scale-up of this LFG conditioning process to test it under real LFG conditions.

W. Urban; H. Lohmann; J.I. Salazar Gómez

2009-01-01T23:59:59.000Z

292

Linear Transformations, Canonoid Transformations and BiHamiltonian Structures  

E-Print Network (OSTI)

We give a characterization of linear canonoid transformations on symplectic manifolds and we use it to generate biHamiltonian structures for some mechanical systems. Utilizing this characterization we also study the behavior of quadratic superintegrable systems under canonoid transformations. We present a description of canonoid transformations due to E.T. Whittaker, and we show that it leads, in a natural way, to the modern, coordinate-independent definition of canonoid transformations. We also generalize canonoid transformations to Poisson manifolds by introducing Poissonoid transformations. We give examples of such transformations for Euler's equations of the rigid body (on $ \\mathfrak{ so}^\\ast (3) $ and $ \\mathfrak{ so}^\\ast (4)$) and for an integrable case of Kirchhoff's equations for the motion of a rigid body immersed in an ideal fluid. We study the relationship between biHamiltonian structures and Poissonoid transformations for these examples.

Giovanni Rastelli; Manuele Santoprete

2014-07-19T23:59:59.000Z

293

Chapter 22 - Heterogeneous Catalytic Reduction for Water Purification: Nanoscale Effects on Catalytic Activity, Selectivity, and Sustainability  

Science Journals Connector (OSTI)

Reductive catalysis is a promising water treatment technology that employs heterogeneous metal catalysts (e.g., Pd nanoparticles on a support) to convert dihydrogen to adsorbed atomic hydrogen in order to promote reactions with functional groups in various contaminants. Reductive catalysis has several potential advantages, including high selectivity for a given target, fast rates under mild conditions, and low production of harmful by-products. The technology has been applied mostly for remediation of groundwater contaminated with halogenated hydrocarbons and for treatment of nitrate, but recent studies have expanded the range of target contaminants to include perchlorate and N-nitrosamines. Palladium-based catalysts hold tremendous promise for their ability to selectively destroy several drinking water contaminants, and some compounds that exhibit slow reaction kinetics with Pd alone are rapidly degraded when a second, promoter metal is added to the catalyst. However, there is a lack of information about the long-term sustainability of these catalytic treatment processes, which is a major consideration in their possible adoption for remediation applications. Recent research has focused on the nanoscale characterization of these heterogeneous catalysts in order to develop an improved understanding of their mechanisms of deactivation and the pathways for regeneration. Two examples of studies from the authors’ laboratories, involving (i) hydrodehalogenation of iodinated X-ray contrast media with Ni or Pd catalysts and (ii) selective reduction of nitrate with a regenerable Pd-In/alumina catalyst, are discussed in this chapter.

Timothy J. Strathmann; Charles J. Werth; John R. Shapley

2014-01-01T23:59:59.000Z

294

Transformations of polynomial ensembles  

E-Print Network (OSTI)

A polynomial ensemble is a probability density function for the position of $n$ real particles of the form $\\frac{1}{Z_n} \\, \\prod_{jtransformations that preserve the structure of a polynomial ensemble. These transformations include the restriction of a Hermitian matrix by removing one row and one column, a rank-one modification of a Hermitian matrix, and the extension of a Hermitian matrix by adding an extra row and column with complex Gaussians.

Arno B. J. Kuijlaars

2015-01-30T23:59:59.000Z

295

Transformative Wave Technologies Kent, Washington  

E-Print Network (OSTI)

Transformative Wave Technologies Kent, Washington www.transformativewave.com #12;#12;North America are shifted to off peak times #12;#12;Transformative Wave Technologies www.transformativewave.com #12

California at Davis, University of

296

Transforming Parks and Protected Areas  

E-Print Network (OSTI)

Transforming Parks and Protected Areas Policy and governance in a changing world Edited by Kevin S from the British Library Library of Congress Cataloging In Publication Data Transforming parks

Bolch, Tobias

297

Catalytic oxidation of ethyl acetate over La-Co and La-Cu oxides  

Science Journals Connector (OSTI)

Abstract Lanthanum-containing mixed oxides (La-Co and La-Cu) were synthesized by several methods: exotemplating, evaporation, glycine-nitrate and glycine-nitrate-exotemplating. Samples were characterized by thermogravimetry and differential scanning calorimetry, N2 adsorption, temperature programmed reduction, scanning electron microscopy and X-ray diffraction. The materials obtained were tested as catalysts for ethyl acetate oxidation, as a model volatile organic compound. La-Cu samples showed poor catalytic performance, but La-Co materials were much more active than the individual components. Catalytic activity seems to be mainly determined by the easiness of reduction of the catalysts, which is related to the availability of oxygen from the lattice. Catalysts containing Co or Cu in excess of La (on a molar base) were more active than the corresponding mixed oxides consisting of equal amounts of La and the transition metal. Samples prepared by the evaporation method were more active than those prepared by exotemplating, for the same molar ratio. Samples prepared by evaporation and glycine-nitrate methods calcined at 600 °C had a better performance than the corresponding oxides calcined at 300 °C. The most active sample found in this study was the La-Co mixed oxide prepared by the glycine nitrate method and calcined at 600 °C, 100% conversion of ethyl acetate to H2O and CO2 being achieved at 230 °C.

X. Chen; S.A.C. Carabineiro; P.B. Tavares; J.J.M. Órfão; M.F.R. Pereira; J.L. Figueiredo

2014-01-01T23:59:59.000Z

298

CX-012081: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Determination CX-012081: Categorical Exclusion Determination Kimball Substation KY1A Transformer Replacement and Road Maintenance CX(s) Applied: B1.3 Date: 02102014 Location(s):...

299

Nonlocal conservation laws and related Bäcklund transformations via reciprocal transformations  

E-Print Network (OSTI)

A set of infinitely many nonlocal conservation laws are revealed for (1+1)-dimensional evolution equations. For some special known integrable systems, say, the KdV and Dym equations, it is found that different nonlocal conservation laws can lead to same new integrable systems via reciprocal transformation. On the other hand, it can be considered as one solution of the new model obtained via reciprocal transformation(s) can be changed to different solutions of the original model. The fact indicates also that two or more different (local and nonlocal) conservation laws can be used to find implicit auto-B\\"acklund transformations via reciprocal transformation to other systems.

Sen-Yue Lou

2014-06-08T23:59:59.000Z

300

Generalized Transforms and Special Functions  

E-Print Network (OSTI)

We study the properties of different type of transforms by means of operational methods and discuss the relevant interplay with many families of special functions. We consider in particular the binomial transform and its generalizations. A general method, based on the use of the Fourier transform technique, is proposed for the study of the properties of functions of operators.

G. Dattoli; E. Sabia

2010-10-08T23:59:59.000Z

Note: This page contains sample records for the topic "determination catalytic transformation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

VLA Antenna Pad Transformer Breaker  

E-Print Network (OSTI)

NRAO VLA Antenna Pad Transformer Breaker Survey B-Array, November 22nd , 2013 Summary: None connections in the cabinet and may be indicating a problem inside the transformer. If the heating on these bushings continues the transformer may need service. NOTE: The low ambient temperature and good conductance

Groppi, Christopher

302

VLA Antenna Pad Transformer Breaker  

E-Print Network (OSTI)

NRAO VLA Antenna Pad Transformer Breaker Survey D-Array, April 5th 2013 #12;VLA Antenna Pad Transformer Breaker Survey D-Array, April 2013, Bob Broilo 2 Summary: No action needed. Inspected by: Bob2 Visible Light Image Notes: #12;VLA Antenna Pad Transformer Breaker Survey D-Array, April 2013, Bob

Groppi, Christopher

303

VLA Antenna Pad Transformer Breaker  

E-Print Network (OSTI)

NRAO VLA Antenna Pad Transformer Breaker Survey A-Array, July 2011, Bob Broilo #12;A-Array Antenna Pad Transformer Survey July 2011, Bob Broilo 2 Inspected by: Bob Broilo Inspection Date: 6/16/2011 2 Transformer Survey July 2011, Bob Broilo 3 Inspected by: Bob Broilo Inspection Date: 6/16/2011 1:58:06 PM

Groppi, Christopher

304

VLA Antenna Pad Transformer Breaker  

E-Print Network (OSTI)

NRAO VLA Antenna Pad Transformer Breaker Survey C-Array, August 20th 2013 #12;VLA Antenna Pad Transformer Breaker Survey C-Array, August 2013, Bob Broilo 2 Summary: Breaker at CE7 needs to be replaced transformer can be shut down with the switch at DE9. Inspected by: Bob Broilo Inspection Date: 8/16/2013 2

Groppi, Christopher

305

VLA Antenna Pad Transformer Breaker  

E-Print Network (OSTI)

NRAO VLA Antenna Pad Transformer Breaker Survey D-Array, October 2011, Bob Broilo #12;D-Array Antenna Pad Transformer Survey October 2011, Bob Broilo 2 Inspected by: Bob Broilo Inspection Date: 10-hand) feeds DE2. #12;D-Array Antenna Pad Transformer Survey October 2011, Bob Broilo 3 Inspected by: Bob

Groppi, Christopher

306

The Transformer By Aaron Lo  

E-Print Network (OSTI)

(3) Transforming lambda-expressions with several patterns n pat 1 : : : pat n -> exp n pat 1 -> (n pat 2 -> : : : (n pat n -> exp) : : :) where n #21; 2 (4) Transforming lambda-patterns into case n pat -> exp n var -> case var of pat -> exp where pat is no variable, var is new (5) Transforming case

Treuille, Adrien

307

VLA Antenna Pad Transformer Breaker  

E-Print Network (OSTI)

NRAO VLA Antenna Pad Transformer Breaker Survey C-Array, April 2012, Bob Broilo #12;C-Array Antenna Pad Transformer Survey April 2012, Bob Broilo 2 Inspected by: Bob Broilo Inspection Date: 4/4/2012 2 Pad Transformer Survey April 2012, Bob Broilo 3 Inspected by: Bob Broilo Inspection Date: 4/4/2012 2

Groppi, Christopher

308

VLA Antenna Pad Transformer Breaker  

E-Print Network (OSTI)

NRAO VLA Antenna Pad Transformer Breaker Survey A-Array, May 20, 2014 Summary: The breakers at AN5 Transformer Breaker Survey A-Array, May 2014, Bob Broilo 2 Inspected by: Bob Broilo Inspection Date: 5 Notes: #12;VLA Antenna Pad Transformer Breaker Survey A-Array, May 2014, Bob Broilo 3 Inspected by: Bob

Groppi, Christopher

309

TRANSFORMING MEDICINE October 1, 2009  

E-Print Network (OSTI)

TRANSFORMING MEDICINE October 1, 2009 Strategic Plan #12;ABOUT THE KECK SCHOOL OF MEDICINE OF USC Century for the benefit of humankind. This is an exciting time of great transformation as we endeavor of Medicine is undergoing a major transformation. It was sparked by the expansion of biomedical research

Valero-Cuevas, Francisco

310

VLA Antenna Pad Transformer Breaker  

E-Print Network (OSTI)

NRAO VLA Antenna Pad Transformer Breaker Survey B-Array, May 2011, Bob Broilo #12;B-array Antenna Pad Transformer Breaker Survey May 2011, Bob Broilo 2 Inspected by: Bob Broilo Inspection Date: 5 Transformer Breaker Survey May 2011, Bob Broilo 3 Inspected by: Bob Broilo Inspection Date: 5/5/2011 3

Groppi, Christopher

311

Formation and control of fuel-nitrogen pollutants in catalytic combustion of coal-derived gases. Final report  

SciTech Connect

The objective of this program has been the elucidation of the mechanism of high temperature catalytic oxidation of coal-derived gases, including their individual constituents,and the effects of sulfur and nitrogen impurities. Detailed experimental data were obtained and a two-dimensional model is being developed and tested by comparison with the experimental data. When complete, the model can be used to optimize designs of catalytic combustors. The model at present includes axial and radial diffusion and gas and surface chemical reactions. Measured substrate temperatures are input in lieu of complete coupling of gas and solid energy conservation equations and radiative heat transfer. Axial and radial gas temperature and composition profiles inside a catalyst channel were computed and compared with experimental measurements at the catalyst outlet. Experimental investigations were made of carbon monoxide and medium-Btu gas combustion in the presence of platinum supported on a monolithic Cordierite substrate. Axial profiles of substrate temperature, gas temperature, and gas composition were determined at different gas velocities and equivalence ratios. The effects of H/sub 2/S and NH/sub 3/ in the medium-Btu gas were also investigated. Systems were proposed for making resonance absorption and Raman scattering measurements of gas temperature and/or species concentrations in a catalytic reactor. A new pulsed multipass Raman scattering technique for increasing photon yield from a scattering volume was developed.

Walsh, P. M.; Bruno, C.; Santavicca, D. A.; Bracco, F. V.

1980-02-01T23:59:59.000Z

312

Tripartite entanglement transformations and tensor rank  

E-Print Network (OSTI)

Understanding the nature of multipartite entanglement is a central mission of quantum information theory. To this end, we investigate the question of tripartite entanglement convertibility. We find that there exists no easy criterion to determine whether a general tripartite transformation can be performed with a nonzero success probability and in fact, the problem is NP-hard. Our results are based on the connections between multipartite entanglement and tensor rank (also called Schmidt rank), a key concept in algebraic complexity theory. Not only does this relationship allow us to characterize the general difficulty in determining possible entanglement transformations, but it also enables us to observe the previously overlooked fact that {\\em the Schmidt rank is not an additive entanglement measure}. As a result, we improve some best known transformation rates between specific tripartite entangled states. In addition, we find obtaining the most efficient algorithm for matrix multiplication to be precisely equivalent to determining the optimal rate of conversion between the Greenberger-Horne-Zeilinger state and a triangular distribution of three Einstein-Podolsky-Rosen states.

Eric Chitambar; Runyao Duan; Yaoyun Shi

2008-05-19T23:59:59.000Z

313

Catalytic destruction of groundwater contaminants in reactive extraction wells  

DOE Patents (OSTI)

A system for remediating groundwater contaminated with halogenated solvents, certain metals and other inorganic species based on catalytic reduction reactions within reactive well bores. The groundwater treatment uses dissolved hydrogen as a reducing agent in the presence of a metal catalyst, such a palladium, to reduce halogenated solvents (as well as other substituted organic compounds) to harmless species (e.g., ethane or methane) and immobilize certain metals to low valence states. The reactive wells function by removing water from a contaminated water-bearing zone, treating contaminants with a well bore using catalytic reduction, and then reinjecting the treated effluent into an adjacent water-bearing zone. This system offers the advantages of a compact design with a minimal surface footprint (surface facilities) and the destruction of a broad suite of contaminants without generating secondary waste streams.

McNab, Jr., Walt W. (Concord, CA); Reinhard, Martin (Stanford, CA)

2002-01-01T23:59:59.000Z

314

Catalytic production of metal carbonyls from metal oxides  

DOE Patents (OSTI)

This invention relates to the formation of metal carbonyls from metal oxides and specially the formation of molybdenum carbonyl and iron carbonyl from their respective oxides. Copper is used here in admixed form or used in chemically combined form as copper molybdate. The copper/metal oxide combination or combined copper is utilized with a solvent, such as toluene and subjected to carbon monoxide pressure of 25 atmospheres or greater at about 150 to 260/sup 0/C. The reducing metal copper is employed in catalytic concentrations or combined concentrations as CuMoO/sub 4/ and both hydrogen and water present serve as promoters. It has been found that the yields by this process have been salutary and that additionally the catalytic metal may be reused in the process to good effect. 3 tables.

Sapienza, R.S.; Slegeir, W.A.; Foran, M.T.

1984-01-06T23:59:59.000Z

315

The Role of Carbon in Catalytically Stabilized Transition Metal Sulfides  

SciTech Connect

Since WWII considerable progress has been made in understanding the basis for the activity and the selectivity of molybdenum and tungsten based hydrotreating catalysts. Recently, the focus of investigation has turned to the structure of the catalytically stabilized active catalyst. The surface of the catalytically stabilized MoS2 has been shown to be carbided with the formula MoSxCy under hydrotreating conditions. In this paper we review the basis for this finding and present new data extending the concept to the promoted TMS (transition metal sulfides) systems CoMoC and NiMoC. Freshly sulfided CoMoS and NiMoS catalyst have a strong tendency to form the carbided surface phases from any available carbon source.

Kelty,S.; Berhault, G.; Chianelli, R.

2007-01-01T23:59:59.000Z

316

Small catalytic RNA: Structure, function and application  

SciTech Connect

We have utilized a combination of photochemical cross-linking techniques and site-directed mutagenesis to obtain secondary and tertiary structure information for the self-cleaving, self-ligating subsequence of RNA from the negative strand of Satellite Tobacco Ringspot Virus. We have found that the helical regions fold about a hinge to promoting four different possible tertiary interactions, creating a molecular of similar shape to a paperclip. A model suggesting that the paperclip'' and hammerhead'' RNAs share a similar three dimensional structure is proposed. We have used a self-cleaving RNA molecule related to a subsequence of plant viroids, a hammerhead,'' to study the length-dependent folding of RNA produced during transcription by RNA polymerase. We have used this method to determine the length of RNA sequestered within elongating E. coli and T7 RNA polymerase complexes. The data show that for E. coli RNA polymerase 12{plus minus}1 nucleotides are sequestered within the ternary complex, which is consistent with the presence of an RNA-DNA hybrid within the transcription bubble, as proposed by others. The result for T7 RNA polymerase differs from E. coli RNA polymerase, with only 10{plus minus}1 nucleotides sequestered within the ternary complex, setting a new upper limit for the minimum RNA-DNA required for a stable elongating complex. Comparisons between E. coli and T7 RNA polymerase are made. The relevance of the results to models or transcription termination, abortive initiation, and initiation to elongation mode transitions are discussed.

Monforte, J.A.

1991-04-01T23:59:59.000Z

317

Catalytic Hydrothermal Conversion of Triglycerides to Non-ester Biofuels  

Science Journals Connector (OSTI)

Catalytic Hydrothermal Conversion of Triglycerides to Non-ester Biofuels ... Results derived from soybean oil, jatropha oil, and tung oil show that certain biofuel fractions met JP-8 specifications and Navy distillate specifications. ... Therefore, tung-oil-derived CH biofuel will have added value as a blend stock for existing FT jet fuels and emerging biofuels such as those produced from the UOP/ENI EcofiningTM process to meet fuel specifications by increasing density and aromatic content. ...

Lixiong Li; Edward Coppola; Jeffrey Rine; Jonathan L. Miller; Devin Walker

2010-01-13T23:59:59.000Z

318

Micro-Scale Catalytic Reactor for Syngas Production  

Science Journals Connector (OSTI)

Micro-Scale Catalytic Reactor for Syngas Production ... The H2 yield (?H2) was evaluated as moles of H2 produced per mole of CH4 converted in the reforming channel. ... In particular, the maximum temperature moves from a location close to the reactor center (for MCH4-sr/MCH4-co = 2) toward the reactor inlet producing in the case of MCH4-sr/MCH4-co =2.75 decreasing temperature profiles without a maximum. ...

S. Vaccaro; L. Malangone; P. Ciambelli

2010-07-01T23:59:59.000Z

319

Catalytic Graphitization of Carbon Aerogels by Transition Metals  

Science Journals Connector (OSTI)

Catalytic Graphitization of Carbon Aerogels by Transition Metals ... Carbon aerogels and Cr-, Fe-, Co-, and Ni-containing carbon aerogels were obtained by pyrolysis, at temperatures between 500 and 1800 °C, of the corresponding aerogels prepared by the sol?gel method from polymerization of resorcinol with formaldehyde. ... Results obtained show that carbon aerogels are, essentially, macroporous materials that maintain large pore volumes even after pyrolysis at 1800 °C. ...

F. J. Maldonado-Hódar; C. Moreno-Castilla; J. Rivera-Utrilla; Y. Hanzawa; Y. Yamada

2000-03-24T23:59:59.000Z

320

Effects of Current upon Electrochemical Catalytic Reforming of Anisole  

Science Journals Connector (OSTI)

The reforming of anisole (as model compound of bio-oil) was performed over the NiCuZn-Al2O3 catalyst, using a recently-developed electrochemical catalytic reforming (ECR). The influence of the current on the anisole reforming in the ECR process has been investigated. It was observed that anisole reforming was significantly enhanced by the current approached over the catalyst in the electrochemical catalytic process, which was due to the non-uniform temperature distribution in the catalytic bed and the role of the thermal electrons originating from the electrified wire. The maximum hydrogen yield of 88.7% with a carbon conversion of 98.3% was obtained through the ECR reforming of anisole at 700°C and 4 A. X-ray diffraction was employed to characterize catalyst features and their alterations in the anisole reforming. The apparent activation energy for the anisole reforming is calculated as 99.54 kJ/mol, which is higher than ethanol, acetic acid, and light fraction of bio-oil. It should owe to different physical and chemical properties and reforming mechanism for different hydrocarbons.

Jia-xing Xiong; Tao Kan; Xing-long Li; Tong-qi Ye; Quan-xin Li

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "determination catalytic transformation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Small catalytic RNA: Structure, function and application  

SciTech Connect

We have utilized a combination of photochemical cross-linking techniques and site-directed mutagenesis to obtain secondary and tertiary structure information for the self-cleaving, self-ligating subsequence of RNA from the negative strand of Satellite Tobacco Ringspot Virus. We have found that the helical regions fold about a hinge to promoting four different possible tertiary interactions, creating a molecular of similar shape to a paperclip. A model suggesting that the ``paperclip`` and ``hammerhead`` RNAs share a similar three dimensional structure is proposed. We have used a self-cleaving RNA molecule related to a subsequence of plant viroids, a ``hammerhead,`` to study the length-dependent folding of RNA produced during transcription by RNA polymerase. We have used this method to determine the length of RNA sequestered within elongating E. coli and T7 RNA polymerase complexes. The data show that for E. coli RNA polymerase 12{plus_minus}1 nucleotides are sequestered within the ternary complex, which is consistent with the presence of an RNA-DNA hybrid within the transcription bubble, as proposed by others. The result for T7 RNA polymerase differs from E. coli RNA polymerase, with only 10{plus_minus}1 nucleotides sequestered within the ternary complex, setting a new upper limit for the minimum RNA-DNA required for a stable elongating complex. Comparisons between E. coli and T7 RNA polymerase are made. The relevance of the results to models or transcription termination, abortive initiation, and initiation to elongation mode transitions are discussed.

Monforte, J.A.

1991-04-01T23:59:59.000Z

322

NO removal by reducing agents and additives in the selective non-catalytic reduction (SNCR) process  

Science Journals Connector (OSTI)

The effect of the additives on the selective non-catalytic reduction (SNCR) reaction has been determined in a three-stage laboratory scale reactor. The optimum reaction temperature is lowered and the reaction temperature window is widened with increasing concentrations of the gas additives (CO, CH4). The optimum reaction temperature is lowered and the maximum NO removal efficiency decreases with increasing the concentration of alcohol additives (CH3OH, C2H5OH). The addition of phenol lowers the optimum reaction temperature about 100–150 °C similar to that of the toluene addition. The volatile organic compounds (VOCs: C6H5OH, C7H8) can be utilized in the SNCR process to enhance NO reduction and removed at the same time. A previously proposed simple kinetic model can successfully apply the NO reduction by NH3 and the present additives.

Sang Wook Bae; Seon Ah Roh; Sang Done Kim

2006-01-01T23:59:59.000Z

323

Kinetics of liquid phase catalytic dehydration of methanol to dimethyl ether  

SciTech Connect

This paper reports the kinetics of the liquid phase catalytic dehydration of methanol to dimethyl ether investigated. The experiments were carried out under low concentrations of feed in a 1-L stirred autoclave, according to a statistical experimental design. The inert liquid phase used for this investigation was a 78:22 blend of paraffinic and naphthenic mineral oils. A complete thermodynamic analysis was carried out in order to determine the liquid phase concentrations of the dissolved species. A global kinetic model was developed for the rate of dimethyl ether synthesis in terms of the liquid phase concentration of methanol. The activation energy of the reaction was found to be 18,830 cal/gmol. Based on a step-wise linear regression analysis of the kinetic data, the order of the reaction which gave the best fit was 0.28 with respect to methanol.

Gogate, M.R.; Lee, B.G.; Lee, S. (Akron Univ., OH (USA). Dept. of Chemical Engineering); Kulik, C.J. (Electric Power Research Inst., Palo Alto, CA (USA))

1990-01-01T23:59:59.000Z

324

Diverse Levels of Sequence Selectivity and Catalytic Efficiency of Protein-Tyrosine Phosphatases  

Science Journals Connector (OSTI)

The structure was determined by molecular replacement with MOLREP of the CCP4 suite using the structure of the free PTP1B catalytic domain [Protein Data Bank (PDB) entry 1PTY] as the search model. ... Library I contains five random residues N-terminal to pY, ASXXXXXpYAABBRM-resin [where B is ?-alanine and X is F2Y (used as a Tyr surrogate), norleucine (Nle or M, used as a replacement of Met), or any of the 19 proteinogenic amino acids except for Tyr, Met, or Cys]. ... From the home page, users can launch simple or complex searches and browse high-throughput data sets by disease, tissue or cell line. ...

Nicholas G. Selner; Rinrada Luechapanichkul; Xianwen Chen; Benjamin G. Neel; Zhong-Yin Zhang; Stefan Knapp; Charles E. Bell; Dehua Pei

2013-12-20T23:59:59.000Z

325

Study of catalytic effects of mineral matter level on coal reactivity  

SciTech Connect

Coal liquefaction experiments using a 400-lb/day bubble-column reactor tested the catalytic effects of added mineral matter level on coal conversion, desulfurization, and distillate yields in continuous operation under recycle conditions, with specific emphasis on the use of a disposable pyrite catalyst indigenous to the feed coal. Western Kentucky No. 11 run-of-mine (ROM) and washed coals were used as feedstocks to determine the effects of levels of mineral matter, specifically iron compounds. Liquefaction reactivity as characterized by total distillate yield was lower for washed coal, which contained less mineral matter. Liquefaction reactivity was regained when pyrite concentrate was added as a disposable catalyst to the washed coal feed in sufficient quantity to match the feed iron concentration of the run-of-mine coal liquefaction test run.

Mazzocco, Nestor J.; Klunder, Edgar B.; Krastman, Donald

1981-03-01T23:59:59.000Z

326

LU transformation invariant operators and LU transformation invariant  

E-Print Network (OSTI)

We proposed a concept of LU transformation invariant operators. By using this operator, arbitrary multi-qubit states LU transformation invariant and SLOCC invariant could be easily obtained. And we find that presences two kinds of invariant operators and corresponding invariants. One kind of operators yields LU invariants and the other operators results in SLOCC invariants. For three-qubit states, all independence LU transformation invariant are obtained. Furthermore, by this system method, arbitrary multi-qubit states invariants can be given.

Xin-wei Zha; Chun-min Zhang

2007-02-06T23:59:59.000Z

327

Selective catalytic reduction of NO{sub 2} with urea in nanocrystalline NaY zeolite  

SciTech Connect

In this study, the selective catalytic reduction (SCR) of NO{sub 2} with urea in nanocrystalline NaY zeolite was investigated with in situ transmission Fourier transform infrared (FTIR) spectroscopy and solid-state nuclear magnetic resonance spectroscopy. At T=473 K, the reaction rate for urea-SCR of NO{sub 2} in nanocrystalline NaY zeolite was significantly greater than that in commercial NaY zeolite with a larger crystal size. In addition, a dramatic decrease in the concentration of undesirable surface species, including biuret and cyanuric acid, was observed in nanocrystalline NaY compared with commercial NaY after urea-SCR of NO{sub 2} at T=473 K. The increased reactivity for urea-SCR of NO{sub 2} was attributed to silanol groups and extra-framework aluminum species located on the external surface of nanocrystalline NaY. Specifically, NOx storage as nitrate and nitrite on the internal zeolite surface was coupled to reactive deNOx sites on the external surface. Isotopic labeling combined with IR analysis suggest that NN bond formation involved both an N-atom originating from NO{sub 2} and an N-atom originating from urea. This is the first clear example demonstrating that the increased external surface area (up to 40% of total surface area) of nanocrystalline zeolites can be used as a reactive surface with unique active sites for catalysis.

Gonghu Li; Conrad A. Jones; Vicki H. Grassian; Sarah C. Larsen [University of Iowa, Iowa City, IA (United States). Department of Chemistry

2005-09-10T23:59:59.000Z

328

Catalytic synthesis of bamboo-like multiwall BN nanotubes via SHS-annealing process  

SciTech Connect

Bamboo-like multiwall boron nitride (BN) nanotubes were synthesized via annealing porous precursor prepared by self-propagation high temperature synthesis (SHS) method. The as-synthesized BN nanotubes were characterized by the field emission scanning electron microscopy (FE-SEM), transmission electron microscope (TEM), high-resolution TEM (HRTEM), X-ray diffraction (XRD), Raman and Fourier transform infrared (FTIR) spectroscopy. These nanotubes have uniform diameters of about 60 nm and an average length of about 10 {mu}m. Four growth models, including tip, base, based tip and base-tip growth models, are proposed based on the catalytic vapor-liquid-solid (VLS) growth mechanism for explaining the formation of the as-synthesized bamboo-like BN nanotubes. Chemical reactions and annealing mechanism are also discussed. -- Graphical Abstract: A novel and effective annealing porous precursor route to bulk synthesis of bamboo-like multiwall BN nanotubes. Four growth models of VLS growth mechanism for these nanotubes are proposed. Display Omitted Research highlights: {yields} Bulk bamboo-like BN nanotubes were synthesized by SHS-annealing method. {yields} Boron-containing, porous precursor played a crucial role in bulk synthesis process. {yields} Four possible growth models were proposed to explain the formation of the bamboo-like BN nanotubes.

Zhang, L.P. [School of Material Science and Engineering, Wuhan Institute of Technology, Wuhan 430073 (China); Gu, Y.L., E-mail: ncm@mail.wit.edu.c [School of Material Science and Engineering, Wuhan Institute of Technology, Wuhan 430073 (China); Nano and Ceramic Materials Research Center, Wuhan Institute of Technology, Wuhan 430073 (China); Wang, J.L.; Zhao, G.W.; Qian, Q.L.; Li, J.; Pan, X.Y. [School of Material Science and Engineering, Wuhan Institute of Technology, Wuhan 430073 (China); Zhang, Z.H. [School of Material Science and Engineering, Wuhan Institute of Technology, Wuhan 430073 (China); Nano and Ceramic Materials Research Center, Wuhan Institute of Technology, Wuhan 430073 (China)

2011-03-15T23:59:59.000Z

329

PCB (polychlorinated biphenyl) residues in transformer carcasses: Final report  

SciTech Connect

This project had three objectives. The first was to assess the population of PCB-containing transformers remaining in service in the US in 1988. While this could not be done with great precision, it appears that the population of oil-filled transformers containing > 50 /mu/g PCB/g oil has decreased by some 15% since 1982 and that the population of askarel-filled transformers has decreased by some 40% in the same time period. This progress could be continued and accelerated if additional reliable and accepted routes for disposal of PCBs contained in transformers would be developed. The second and third objectives of this project have been to examine two simplified approaches to this end. The second objective was to determine if, by draining PCB-containing oil from transformers and refilling with PCB-free oil, a level of PCBs below 50 ppM (/mu/g/g oil) could be reached with assurance. It appears that reclassification of ''PCB-contaminated'' oil-filled transformers (50--500 /mu/g PCB/g oil) of all ratings by draining and refilling could be done routinely. The third objective was to determine the level of residual PCBs left on the metallic surfaces of askarel-filled transformers which, if these units were refilled with PCB-free mineral transformer oil, would have resulted in concentrations of <50 /mu/g PCB/g oil. It appears that cleaning the surfaces of the metallic components, after careful separation and disposal of the liquid and impregnated solid insulations, to a level of 400 /mu/gPCB/100 cm/sup 2/ would result in transformer carcasses of all sizes which would contain less PCBs than would be found were these transformers to have contained oil at the level of 50 /mu/gPCB/g oil. 7 refs., 6 figs., 9 tabs.

Rouse, T.O.; Raymond, C.T.; Fessler, W.A.

1989-08-01T23:59:59.000Z

330

z Transform Chapter Intended Learning Outcomes  

E-Print Network (OSTI)

z Transform Chapter Intended Learning Outcomes: (i) Understanding the relationship between transform and the Fourier transform for discrete-time signals (ii) Understanding the characteristics and properties of transform (iii) Ability to compute transform and inverse transform (iv) Ability to apply

So, Hing-Cheung

331

Transformations of Ising Models  

Science Journals Connector (OSTI)

The "star-triangle" and "decoration" transformations are generalized so as to apply to arbitrary mechanical systems coupled to the spins of a standard Ising net. This leads to exact solutions for further plane Ising nets and also for lattices in which the spins on alternate sites have a magnitude greater than S=12. A general class of antiferromagnetic Ising models is constructed; exact closed expressions can be derived for all the thermodynamic and magnetic properties of these models in an arbitrary magnetic field.The magnetizations and susceptibilities of Ising nets in which different spins have different magnetic moments are investigated and a valuable relation between the susceptibilities of the honeycomb and triangular lattices is derived. It is shown how correlation functions involving a given spin can be expressed in terms of correlations involving the nearest-neighbor spins instead.

Michael E. Fisher

1959-02-15T23:59:59.000Z

332

Definition: Transformer | Open Energy Information  

Open Energy Info (EERE)

Transformer Transformer Jump to: navigation, search Dictionary.png Transformer An electromagnetic device that changes the voltage of alternating current electricity.[1] View on Wikipedia Wikipedia Definition View on Reegle Reegle Definition A transformer consists of a primary- and secondary coil, coupled by a magnetic field. The primary coil induces the voltage in the secondary coil. The voltage transformation depends on the number of windings. Related Terms Electricity, Transmission, Electric grid, transmission lines, electricity generation, transmission line, alternating current References ↑ http://www1.eere.energy.gov/site_administration/glossary.html#T Retrieved LikeLike UnlikeLike You like this.Sign Up to see what your friends like. from "http://en.openei.org/w/index.php?title=Definition:Transformer&oldid=502565

333

Gauge Transformations as Spacetime Symmetries  

SciTech Connect

Weinberg has shown that massless fields of helicity {+-}1(vector fields) do not transform homogeneously under Unitary Lorentz Transformations (LT). We calculate explicitly the inhomogeneous term. We show that imposing strict invariance of the Lagrangian under LT for an iteracting Dirac field requires the fermion field to transform with a space-time (and photon creation and annihilation operators) dependent phase and dictates the interaction terms as those arising from the conventional gauge principle.

Angeles, Rene; Napsuciale, Mauro [Division de Ciencias e Ingenierias, Universidad de Guanajuato, Lomas del Bosque 103, Fraccionamiento Lomas del Campestre, Leon Guanajuato, 37150 (Mexico)

2009-04-20T23:59:59.000Z

334

Particle Detector / Beam Current Transformer  

E-Print Network (OSTI)

Particle Detector / Beam Current Transformer Analysis December 8, 2009 Harold G. Kirk #12;ShotSignal,A.U. Proton Bunch Number Beam Current Transformer - 17011 0 2 4 6 8 0 2 4 6 8 10 12 14 16 18 20 Integrated Transformer Pump 187829 (au) Probe 196504 (au) Ratios: Beam Current 1.046 SF 1.019 2.9% difference #12;Shot

McDonald, Kirk

335

Market Transformation | Department of Energy  

Energy Savers (EERE)

Transformation Significant research and development progress has paved the way for fuel cells to enter today's commercial marketplace for a variety of applications, including...

336

PRESENTATION: TRANSFORMATION OF THE GRID  

Energy.gov (U.S. Department of Energy (DOE))

A briefing to the Secretary's Energy Advisory Board on the transformation of the grid delivered by Patricia Hoffman, U.S. Department of Energy.

337

Power transformers - Part 11: Dry-type transformers  

E-Print Network (OSTI)

Applies to dry-type power transformers (including auto-transformers) having values of highest voltage for equipment up to and including 36 kV and at least one winding operating at greater than 1,1 kV. Applies to all construction technologies.

International Electrotechnical Commission. Geneva

2004-01-01T23:59:59.000Z

338

Definition: Line Transformer Monitors | Open Energy Information  

Open Energy Info (EERE)

Transformer Monitors Transformer Monitors Jump to: navigation, search Dictionary.png Line Transformer Monitors Transformer Monitoring System can monitor different aspects of transformers, including oil levels and multiple temperatures within the transformer. This allows for analysis of the health of either individual key power transformers or multiple power transformers networked in the system. For example, the transformer monitors provide transformer oil dissolved gas analysis (DGA), oil temperature, ambient temperature, and moisture in oil measurements. These measurements are made in relation to transformer load.[1] Related Terms transformer, system, transformer References ↑ https://www.smartgrid.gov/category/technology/line_transformer_monitors [[Cat LikeLike UnlikeLike You like this.Sign Up to see what your friends like.

339

Bioenergy Technologies Office R&D Pathways: Ex-Situ Catalytic Fast Pyrolysis  

Energy.gov (U.S. Department of Energy (DOE))

In ex-situ catalytic fast pyrolysis, biomass is heated with catalysts to create bio-oils, which are then used to produce biofuel blendstocks.

340

E-Print Network 3.0 - automobile catalytic converters Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

Search Powered by Explorit Topic List Advanced Search Sample search results for: automobile catalytic converters Page: << < 1 2 3 4 5 > >> 1 IEEE International Symposium on...

Note: This page contains sample records for the topic "determination catalytic transformation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Catalytic ozonation of phenol in water with natural brucite and magnesia  

Science Journals Connector (OSTI)

Natural brucite and magnesia were applied as catalysts in catalytic ozonation of phenol in this work. It was found that both brucite and magnesia had remarkable accelerations on degradation of phenol and removal of COD in water. On this basis, effective and feasible routes for catalytic ozonation of phenol in water were proposed. The influence of initial pH value, radical scavengers and reaction temperature were investigated. The results revealed that there were different ozonation mechanisms in two systems: molecular ozone direct oxidation mechanism was proved in catalytic ozonation with brucite, and hydroxyl radical mechanism was demonstrated to play a main role in catalytic ozonation with magnesia.

Kun He; Yu Ming Dong; Zhen Li; Lin Yin; Ai Min Zhang; Yi Chun Zheng

2008-01-01T23:59:59.000Z

342

Catalytic microwave torrefaction and pyrolysis of Douglas fir pellet to improve biofuel quality .  

E-Print Network (OSTI)

??The aims of this dissertation were to understand the effects of torrefaction as pretreatment on biomass pyrolysis and catalytic pyrolysis for improving biofuel quality, and… (more)

[No author

2012-01-01T23:59:59.000Z

343

E-Print Network 3.0 - apparent catalytic site Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

Yeshiva University Collection: Materials Science 11 Chemo-Mechanical Coupling in F1-ATPase Revealed by Catalytic Site Occupancy during Catalysis Summary: Chemo-Mechanical...

344

Solid state oxygen anion and electron mediating membrane and catalytic membrane reactors containing them  

DOE Patents (OSTI)

A process for production of synthesis gas employing a catalytic membrane reactor wherein the membrane comprises a mixed metal oxide material.

Schwartz, Michael (Boulder, CO); White, James H. (Boulder, CO); Sammells, Anthony F. (Boulder, CO)

2001-01-01T23:59:59.000Z

345

Atomic Hydrogen in Condensed Form Produced by a Catalytic Process:? A Future Energy-Rich Fuel?  

Science Journals Connector (OSTI)

Atomic Hydrogen in Condensed Form Produced by a Catalytic Process:? A Future Energy-Rich Fuel? ... Energy Fuels, 2005, 19 (6), ...

Shahriar Badiei; Leif Holmlid

2005-10-04T23:59:59.000Z

346

Problems in Catalytic Oxidation of Hydrocarbons and Detailed Simulation of Combustion Processes.  

E-Print Network (OSTI)

??This dissertation research consists of two parts, with Part I on the kinetics of catalytic oxidation of hydrocarbons and Part II on aspects on the… (more)

Xin, Yuxuan

2014-01-01T23:59:59.000Z

347

Production of high-octane gasoline on a semi-industrial catalytic reforming plant  

Science Journals Connector (OSTI)

Experiments have been carried out on the catalytic reforming at a pressure of 20 atm of a wide, straight-run gasoline fraction on an experimental industrial plant.

A. P. Fedorov; G. N. Maslyanskii…

1967-01-01T23:59:59.000Z

348

E-Print Network 3.0 - advanced catalytic materials--1996 Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

Ecology 44 Surface Science Perspectives The unhappy marriage of transition and noble metal atoms: A new Summary: to enhance catalytic activity? (A perspective on: When adding...

349

Measurement of diesel solid nanoparticle emissions using a catalytic stripper for comparison with Europe's PMP protocol  

Energy.gov (U.S. Department of Energy (DOE))

Evaluation and comparison of the measurements of diesel solid nanoparticle emissions using the European Particle Measurement Programme (PMP) system and catalytic stripper

350

New Tandem Catalytic Cycles take to the Rhod(ium) | The Ames...  

NLE Websites -- All DOE Office Websites (Extended Search)

New Tandem Catalytic Cycles take to the Rhod(ium) Light, combined with a novel rhodium catalyst, enables greener production of chemical feedstocks from biorenewables. A key...

351

Gas Chromatographic Determination of the Products from the Catalytic Oxidation of Propylene to Acrolein  

Science Journals Connector (OSTI)

......dioxide, propylene, water, acetaldehyde, and...CATHODE AND HYDROGEN GENERATOR Figure 9. Conceptual...dioxide, propylene, water, acetaldehyde, and...been investigated at atmospheric pressure and in a tempera...acetaldehyde, and water. The formation of propional......

L. A. Th. Verhaar; S. P. Lankhuijzen

1970-08-01T23:59:59.000Z

352

Gas Chromatographic Determination of the Products from the Catalytic Oxidation of Propylene to Acrolein  

Science Journals Connector (OSTI)

......chromatograph: (1) The palladium cathode is the source and means of controlling...volume connected between the cathode and the column and with a single...comparison with that of the more active standard support materials probably used in the experiments......

L. A. Th. Verhaar; S. P. Lankhuijzen

1970-08-01T23:59:59.000Z

353

Catalytic process for converting 2-oxazolidinones to their corresponding alkanolamines  

SciTech Connect

This invention provides a process for recovering alkanolamines, e.g. diisopropanolamine, from their corresponding cyclic reaction products (e.g., oxazolidinones), which products are the result of the reaction of CO/sub 2/ and the alkanolamine, a situation commonly encountered in acid gas removal processes employing the alkanolamines alone or in combination with other liquids such as sulfolane (tetrahydrothiophene-1,1 -dioxide). The process involves hydrolyzing the oxazolidinones in the presence of a small but catalytically effective amount of an amine, preferably from about 2 to 10 weight percent, based on 2-oxazolidinones. Preferably, the amine is the alkanolamine precursor of the corresponding 2-oxazolidinone.

Miller, A. E.

1985-04-30T23:59:59.000Z

354

Plasma-assisted catalytic ionization using porous nickel plate  

SciTech Connect

Hydrogen atomic pair ions, i.e., H{sup +} and H{sup -} ions, are produced by plasma-assisted catalytic ionization using a porous nickel plate. Positive ions in a hydrogen plasma generated by dc arc discharge are irradiated to the porous plate, and pair ions are produced from the back of the irradiation plane. It becomes clear that the production quantity of pair ions mainly depends on the irradiation current of positive ions and the irradiation energy affects the production efficiency of H{sup -} ions.

Oohara, W.; Maeda, T.; Higuchi, T. [Department of Electronic Device Engineering, Yamaguchi University, Ube 755-8611 (Japan)

2011-09-15T23:59:59.000Z

355

Development of a Sustainable Catalytic Ester Amidation Process  

Science Journals Connector (OSTI)

Development of a Sustainable Catalytic Ester Amidation Process ... In this paper, and as part of our ongoing interests in the advancement and uptake of green synthesis in a discovery chemistry setting,(17-19) we report our efforts to develop a significantly more sustainable process and demonstrate its applicability to the synthesis of a range of lead-like substrates. ... Overall, consideration of the isolated yields obtained with this new and sustainable coupling protocol indicates that the current method is an extremely viable alternative compared to the previously developed approach. ...

Nicola Caldwell; Craig Jamieson; Iain Simpson; Allan J. B. Watson

2013-07-30T23:59:59.000Z

356

Recent Advances in Catalytic Conversion of Ethanol to Chemicals  

SciTech Connect

With increased availability and decreased cost, ethanol is potentially a promising platform molecule for the production of a variety of value-added chemicals. In this review, we provide a detailed summary of recent advances in catalytic conversion of ethanol to a wide range of chemicals and fuels. We particularly focus on catalyst advances and fundamental understanding of reaction mechanisms involved in ethanol steam reforming (ESR) to produce hydrogen, ethanol conversion to hydrocarbons ranging from light olefins to longer chain alkenes/alkanes and aromatics, and ethanol conversion to other oxygenates including 1-butanol, acetaldehyde, acetone, diethyl ether, and ethyl acetate.

Sun, Junming; Wang, Yong

2014-04-30T23:59:59.000Z

357

Inversion of the star transform  

E-Print Network (OSTI)

We define the star transform as a generalization of the broken ray transform introduced by us in previous work. The advantages of using the star transform include the possibility to reconstruct the absorption and the scattering coefficients of the medium separately and simultaneously (from the same data) and the possibility to utilize scattered radiation which, in the case of the conventional X-ray tomography, is discarded. In this paper, we derive the star transform from physical principles, discuss its mathematical properties and analyze numerical stability of inversion. In particular, it is shown that stable inversion of the star transform can be obtained only for configurations involving odd number of rays. Several computationally-efficient inversion algorithms are derived and tested numerically.

Fan Zhao; John C. Schotland; Vadim A. Markel

2014-05-06T23:59:59.000Z

358

Different process schemes for converting light straight run and fluid catalytic cracking naphthas in a FCC unit for maximum propylene production  

Science Journals Connector (OSTI)

Light straight run (LSR) and fluid catalytic cracking (FCCN) naphthas were cracked in a transported bed reactor (MicroDowner) and in a fixed bed reactor (MAT) over a commercial Y zeolite based catalyst, over a commercial ZSM-5 zeolite based additive, and over a mixture of both at selected conditions. Based on the mechanisms through which naphtha hydrocarbons are converted, we evaluated the best alternatives for processing these streams to produce light olefins and/or to reduce olefins content in commercial gasoline. The experimental set-up allowed us to simulate the cracking behaviour of the different naphtha streams in a fluid catalytic cracking (FCC) unit by different processing schemes. Results indicate that LSR only cracks at high severity, yielding large amounts of dry gas. Despite its high olefins content, FCCN practically does not crack when it is fed together with gas oil feed. When cracking FCCN alone at typical gas oil cracking conditions, olefins are transformed preferentially into naphtha-range isoparaffins and aromatics, and when cracking FCCN at high severity, olefins are transformed preferentially into propylene and butylenes. Finally, cracking naphtha in the stripper produces some propylene and increases the aromatics in the remaining gasoline.

Avelino Corma; FranciscoV Melo; Laurent Sauvanaud; F.J Ortega

2004-01-01T23:59:59.000Z

359

Catalytic combustor for integrated gasification combined cycle power plant  

DOE Patents (OSTI)

A gasification power plant 10 includes a compressor 32 producing a compressed air flow 36, an air separation unit 22 producing a nitrogen flow 44, a gasifier 14 producing a primary fuel flow 28 and a secondary fuel source 60 providing a secondary fuel flow 62 The plant also includes a catalytic combustor 12 combining the nitrogen flow and a combustor portion 38 of the compressed air flow to form a diluted air flow 39 and combining at least one of the primary fuel flow and secondary fuel flow and a mixer portion 78 of the diluted air flow to produce a combustible mixture 80. A catalytic element 64 of the combustor 12 separately receives the combustible mixture and a backside cooling portion 84 of the diluted air flow and allows the mixture and the heated flow to produce a hot combustion gas 46 provided to a turbine 48. When fueled with the secondary fuel flow, nitrogen is not combined with the combustor portion.

Bachovchin, Dennis M. (Mauldin, SC); Lippert, Thomas E. (Murrysville, PA)

2008-12-16T23:59:59.000Z

360

HYBRID SELECTIVE NON-CATALYTIC REDUCTION (SNCR)/SELECTIVE CATALYTIC REDUCTION (SCR) DEMONSTRATION FOR THE REMOVAL OF NOx FROM BOILER FLUE GASES  

SciTech Connect

The U. S. Department of Energy (DOE), Electric Power Research Institute (EPRI), Pennsylvania Electric Energy Research Council, (PEERC), New York State Electric and Gas and GPU Generation, Inc. jointly funded a demonstration to determine the capabilities for Hybrid SNCR/SCR (Selective Non-Catalytic Reduction/Selective Catalytic Reduction) technology. The demonstration site was GPU Generation's Seward Unit No.5 (147MW) located in Seward Pennsylvania. The demonstration began in October of 1997 and ended in December 1998. DOE funding was provided through Grant No. DE-FG22-96PC96256 with T. J. Feeley as the Project Manager. EPRI funding was provided through agreements TC4599-001-26999 and TC4599-002-26999 with E. Hughes as the Project Manager. This project demonstrated the operation of the Hybrid SNCR/SCR NO{sub x} control process on a full-scale coal fired utility boiler. The hybrid technology was expected to provide a cost-effective method of reducing NO{sub x} while balancing capital and operation costs. An existing urea based SNCR system was modified with an expanded-duct catalyst to provide increased NO{sub x} reduction efficiency from the SNCR while producing increased ammonia slip levels to the catalyst. The catalyst was sized to reduce the ammonia slip to the air heaters to less than 2 ppm while providing equivalent NO{sub x} reductions. The project goals were to demonstrate hybrid technology is capable of achieving at least a 55% reduction in NO{sub x} emissions while maintaining less than 2ppm ammonia slip to the air heaters, maintain flyash marketability, verify the cost benefit and applicability of Hybrid post combustion technology, and reduce forced outages due to ammonium bisulfate (ABS) fouling of the air heaters. Early system limitations, due to gas temperature stratification, restricted the Hybrid NO{sub x} reduction capabilities to 48% with an ammonia slip of 6.1 mg/Nm{sup 3} (8 ppm) at the catalyst inlet. After resolving the stratification problem, the catalyst did not have sufficient activity in order to continue the planned test program. Arsenic poisoning was found to be the cause of premature catalyst deactivation.

Jerry B. Urbas

1999-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "determination catalytic transformation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Formal Transformations and WSL Martin Ward  

E-Print Network (OSTI)

Formal Transformations and WSL Part Two Martin Ward STRL Senior Research Fellow Royal Society of Transformations #12;Types of Transformations A Syntactic Transformation changes the syntax of the program but preserves the exact sequence of operations carried out by the program. Many restructuring transformations

Singer, Jeremy

362

A new perspective on renormalization: the scattering transformation  

E-Print Network (OSTI)

The scattering transformation developed by Mallat is put into the perspective of field theory. It is shown to be a simultaneous transformation of the field and the "time" parameter explicitly used in the definition of path integrals central to the Lagrangian approach and in the definition of the "time" ordered products used in the Hamiltonian (or canonical) approach. This transformation preserves the form of the S-matrix as "time" ordered products. The transformed "time" coordinate is the inverse "time" scale. This is traditionally the UV cutoff or renormalization parameter in standard approaches to renormalization. The critical calculation will be the determination of the form of the effective action in this transformed coordinate system. This action will now be expressed as an integral of a Lagrangian density that is a function of the renormalization parameter or transformed "time". Other symmetries of the action can be explicitly built into the transformation. It will be demonstrated on a simple 1D $\\phi^4$ field theory. This non-perturbative approach has great potential in possibly being used to renormalize quantum gravity and obtaining expressions for the strongly coupled limit of QCD.

Michael E. Glinsky

2014-06-28T23:59:59.000Z

363

New insights into the catalytic mechanism of Bombyx mori prostaglandin E synthase gained from structure–function analysis  

SciTech Connect

Highlights: •Structure of Bombyx mori prostaglandin E synthase is determined. •Bound glutathione sulfonic acid is located at the glutathione-binding site. •Electron-sharing network is present in this protein. •This network includes Asn95, Asp96, and Arg98. •Site-directed mutagenesis reveals that the residues contribute to the catalytic activity. -- Abstract: Prostaglandin E synthase (PGES) catalyzes the isomerization of PGH{sub 2} to PGE{sub 2}. We previously reported the identification and structural characterization of Bombyx mori PGES (bmPGES), which belongs to Sigma-class glutathione transferase. Here, we extend these studies by determining the structure of bmPGES in complex with glutathione sulfonic acid (GTS) at a resolution of 1.37 Å using X-ray crystallography. GTS localized to the glutathione-binding site. We found that electron-sharing network of bmPGES includes Asn95, Asp96, and Arg98. Site-directed mutagenesis of these residues to create mutant forms of bmPGES mutants indicate that they contribute to catalytic activity. These results are, to our knowledge, the first to reveal the presence of an electron-sharing network in bmPGES.

Yamamoto, Kohji, E-mail: yamamok@agr.kyushu-u.ac.jp [Faculty of Agriculture, Kyushu University Graduate School, 6-10-1 Hakozaki, Higashi-ku, Fukuoka 812-8581 (Japan)] [Faculty of Agriculture, Kyushu University Graduate School, 6-10-1 Hakozaki, Higashi-ku, Fukuoka 812-8581 (Japan); Suzuki, Mamoru; Higashiura, Akifumi [Institute for Protein Research, Osaka University, Suita 565-0871 (Japan)] [Institute for Protein Research, Osaka University, Suita 565-0871 (Japan); Aritake, Kosuke; Urade, Yoshihiro; Uodome, Nobuko [Department of Molecular Behavioral Biology, Osaka Bioscience Institute, 6-2-4 Furuedai, Suita, Osaka 565-0874 (Japan)] [Department of Molecular Behavioral Biology, Osaka Bioscience Institute, 6-2-4 Furuedai, Suita, Osaka 565-0874 (Japan); Hossain, MD. Tofazzal [Faculty of Agriculture, Kyushu University Graduate School, 6-10-1 Hakozaki, Higashi-ku, Fukuoka 812-8581 (Japan)] [Faculty of Agriculture, Kyushu University Graduate School, 6-10-1 Hakozaki, Higashi-ku, Fukuoka 812-8581 (Japan); Nakagawa, Atsushi [Institute for Protein Research, Osaka University, Suita 565-0871 (Japan)] [Institute for Protein Research, Osaka University, Suita 565-0871 (Japan)

2013-11-01T23:59:59.000Z

364

Characterization and catalytic performance of vanadium supported on sulfated Ti-PILC catalysts issued from different Ti-precursors in selective catalytic reduction of nitrogen oxide by ammonia  

Science Journals Connector (OSTI)

Vanadium supported on sulfated Ti-pillared clay catalysts (STi-PILCs) issued from different Ti-precursors were investigated for selective catalytic reduction (SCR) of NO by NH3 in the presence of O2. The STi-PILC...

J. Arfaoui; L. Khalfallah Boudali; A. Ghorbel; G. Delahay

2009-12-01T23:59:59.000Z

365

Transformational Manufacturing | Argonne National Laboratory  

NLE Websites -- All DOE Office Websites (Extended Search)

Transformational Manufacturing Transformational Manufacturing Argonne's new Advanced Battery Materials Synthesis and Manufacturing R&D Program focuses on scalable process R&D to produce advanced battery materials in sufficient quantity for industrial testing. The U.S. manufacturing industry consumes more than 30 quadrillion Btu of energy per year, directly employs about 12 million people and generates another 7 million jobs in related businesses. Argonne is working with industry to develop innovative and transformational technology to improve the efficiency and competitiveness of domestic manufacturing while reducing its carbon footprint. The lab's efforts concentrate on sustainable manufacturing, applied nanotechnology and distributed energy, with an emphasis on transitioning science discoveries to the market.

366

DNA UPTAKE BY TRANSFORMABLE BACTERIA  

SciTech Connect

The various processes of DNA uptake by cells can be categorized as: viral DNA entry, conjugation, or transformation. Within each category, a variety of mechanisms have been found. However, considerable similarities occur among the different mechanisms of conjugation and, especially, transformation. All of these natural mechanisms of DNA transfer are quite elaborate and involve multiple protein components, as the case may be, of the virus, the donor cell, and the recipient cell. The mechanisms of viral infection and conjugation will be discussed mainly with respect to their relevance to transformation.

LACKS,S.A.

1999-09-07T23:59:59.000Z

367

Production of renewable jet fuel range alkanes and commodity chemicals from integrated catalytic  

E-Print Network (OSTI)

, carbohydrate hydrolysis and dehydration, and catalytic upgrading of platform chemicals. The technology centersProduction of renewable jet fuel range alkanes and commodity chemicals from integrated catalytic and subsequently upgrading these two platforms into a mixture of branched, linear, and cyclic alkanes of molecular

California at Riverside, University of

368

Evolution of Domain Architectures and Catalytic Functions of Enzymes in Metabolic Systems  

E-Print Network (OSTI)

Evolution of Domain Architectures and Catalytic Functions of Enzymes in Metabolic Systems Summit architectures and catalytic functions of enzymes constitute the centerpieces of a metabolic network. These types. In contrast, prokaryotic enzymes become more versatile by catalyzing multiple reactions with similar chemical

Yeang, Chen-Hsiang

369

Control of Natural Gas Catalytic Partial Oxidation for Hydrogen Generation in Fuel Cell Applications1  

E-Print Network (OSTI)

Control of Natural Gas Catalytic Partial Oxidation for Hydrogen Generation in Fuel Cell Ghosh3 , Huei Peng2 Abstract A fuel processor that reforms natural gas to hydrogen-rich mixture to feed of the hydrogen in the fuel processor is based on catalytic partial oxidation of the methane in the natural gas

Peng, Huei

370

Effect of the Catalyst Load on Syngas Production in Short Contact Time Catalytic Partial Oxidation Reactors  

Science Journals Connector (OSTI)

Effect of the Catalyst Load on Syngas Production in Short Contact Time Catalytic Partial Oxidation Reactors ... For safety and environmental protection reasons (to avoid syngas release into the atmosphere), after the analysis section, the reacted gas stream was completely oxidized by forced air in a catalytic honeycomb burner (Figure 2). ...

S. Specchia; L. D. Vella; B. Lorenzut; T. Montini; V. Specchia; P. Fornasiero

2009-07-22T23:59:59.000Z

371

An atomic-scale analysis of catalytically-assisted chemical vapor deposition of carbon nanotubes  

E-Print Network (OSTI)

An atomic-scale analysis of catalytically-assisted chemical vapor deposition of carbon nanotubes M Growth of carbon nanotubes during transition-metal particles catalytically-assisted thermal decomposition of various nanotube surface and edge reactions (e.g. adsorption of hydrocarbons and hydrogen onto the surface

Grujicic, Mica

372

Micro Catalytic Combustor with Pd/Nano-porous Alumina for High-Temperature Application  

E-Print Network (OSTI)

, the mixture temperature at the combustor inlet is set to 630 o C. Thermal conductivity of the ceramic wall Keywords: Catalytic combustion, Pd/nano-porous alumina, Ceramic tape casting, Thermophotovoltaic Abstract: A micro-scale catalytic combustor using high-precision ceramic tape-casting technology has been developed

Kasagi, Nobuhide

373

Catalytic study of SOFC electrode materials in engine exhaust gas Pauline Briaulta  

E-Print Network (OSTI)

cathode materials, besides LSCF demonstrated a lower catalytic activity towards hydrocarbon partial corresponding to a composition of exhaust gas. A screening of four cathode materials was done, some well selected as the electrolyte material. Chemical stability tests and catalytic activity studies in the gas

Paris-Sud XI, Université de

374

Catalytic Conversion of Ethanol to Hydrogen Using Combinatorial Shici Duan and Selim Senkan*  

E-Print Network (OSTI)

the single component catalytic materials explored. Introduction Due to their high energy conversionCatalytic Conversion of Ethanol to Hydrogen Using Combinatorial Methods Shici Duan and Selim Senkan using a feed gas composition of 2% C2H5OH and 12% H2O in a helium carrier gas. This systematic

Senkan, Selim M.

375

Engineering a Unimolecular DNA-Catalytic Probe for Single Lead Ion Monitoring  

E-Print Network (OSTI)

Engineering a Unimolecular DNA-Catalytic Probe for Single Lead Ion Monitoring Hui Wang, Youngmi Kim reactions. These catalytic DNAs, or DNAzymes, can be activated by metal ions. In this paper, we take advantage of DNA molecular engineering to improve the properties of DNAzymes by designing a unimolecular

Tan, Weihong

376

Scaling behavior of optimally structured catalytic microfluidic reactors Fridolin Okkels and Henrik Bruus  

E-Print Network (OSTI)

Scaling behavior of optimally structured catalytic microfluidic reactors Fridolin Okkels and Henrik of catalytic microfluidic reactors we show that, when optimally structured, these reactors share underlying the reactor using a high-level implementation of topology optimization. DOI: 10.1103/PhysRevE.75.016301 PACS

377

The Catalytic Chemistry of HCN+NO over Na- and Ba-Y, FAU: An...  

NLE Websites -- All DOE Office Websites (Extended Search)

The Catalytic Chemistry of HCN+NO over Na- and Ba-Y, FAU: An In Situ FTIR and TPDTPR Study. The Catalytic Chemistry of HCN+NO over Na- and Ba-Y, FAU: An In Situ FTIR and TPDTPR...

378

Mineral Transformation and Biomass Accumulation Associated With  

E-Print Network (OSTI)

Mineral Transformation and Biomass Accumulation Associated With Uranium Bioremediation at Rifle transformation and biomass accumulation, both of which can alter the flow field and potentially bioremediation to understand the biogeochemical processes and to quantify the biomass and mineral transformation/ accumulation

Hubbard, Susan

379

Transforms for the Motion Compensation Residual  

E-Print Network (OSTI)

The Discrete-Cosine-Transform (DCT) is the most widely used transform in image and video compression. Its use in image compression is often justified by the notion that it is the statistically optimal transform for first-order ...

Kamisli, Fatih

380

TRANSFORMING ACADEMIA Historical Developments, Contemporary Perspectives and  

E-Print Network (OSTI)

ISyE 8803A TRANSFORMING ACADEMIA Historical Developments, Contemporary Perspectives independence and this organizational structure represent the first major transformation of academia. These characteristics of academia have persisted for over 900 years and seem immutable. Yet, notable transformations

Li, Mo

Note: This page contains sample records for the topic "determination catalytic transformation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Phase transformations in engineering materials  

SciTech Connect

Phase transformations in engineering materials are inevitably related to mechanical behavior and are often precursors to residual stress and distortion. Neutron scattering in general is a valuable tool for studying their effects, and pulsed neutrons are of special value, because of the inherently comprehensive crystallographic coverage they provide in each measurement. At the Manuel Lujan neutron scattering center several different research programs have addressed the relationships between phase transformation/mechanical behavior and residual strains. Three disparate examples are presented; (1) stress induced transformation in a NiTi shape memory alloy, (2) cryogenically induced transformation in a quenched 5180 steel, and (3) time resolved evolution of strain induced martensite in 304 stainless steel. In each case a brief description of the principle result will be discussed in the context of using neutrons for the measurement.

Bourke, M.A.M.; Lawson, A.C. [Los Alamos National Lab., NM (United States); Dunand, D.C. [Massachusetts Inst. of Tech., Cambridge, MA (United States). Dept. of Materials Science and Engineering; Priesmeyer, H.G. [GKSS-Forschungszentrum Geesthacht GmbH (Germany)

1996-06-01T23:59:59.000Z

382

National Symposium on Market Transformation  

Energy.gov (U.S. Department of Energy (DOE))

Hosted by the American Council for an Energy-Efficient Economy (ACEEE) and the Consortium for Energy Efficiency (CEE), this three-day conference features speakers covering topics within the scope of market transformation.

383

Ancilla Approximable Quantum State Transformations  

E-Print Network (OSTI)

We consider the transformations of quantum states obtainable by a process of the following sort. Combine the given input state with a specially prepared initial state of an auxiliary system. Apply a unitary transformation to the combined system. Measure the state of the auxiliary subsystem. If (and only if) it is in a specified final state, consider the process successful, and take the resulting state of the original (principal) system as the result of the process. We review known information about exact realization of transformations by such a process. Then we present results about approximate realization of finite partial transformations. We consider primarily the issue of approximation to within a specified positive epsilon, but we also address the question of arbitrarily close approximation.

Andreas Blass; Yuri Gurevich

2014-03-30T23:59:59.000Z

384

Energy requirements for nuclear transformations  

Science Journals Connector (OSTI)

Energy requirements for nuclear transformations ... There are several conservation requirements that must be met in nuclear reactions, including the conservation of energy (E = mc2), charge, angular and linear momentum. ... Nuclear / Radiochemistry ...

Benjamin Carrol; Peter F. E. Marapodi

1951-01-01T23:59:59.000Z

385

CX-010683: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Categorical Exclusion Determination "Glen Canyon Substation Stage 09- 50MVA 23069KV Transformer addition CX(s) Applied: B4.11 Date: 07022013 Location(s): Arizona, Arizona...

386

CX-008351: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Categorical Exclusion Determination Transport and Perform TD&I on Big Hill TX-29 Transformer CX(s) Applied: B1.3 Date: 03282012 Location(s): Texas Offices(s): Strategic...

387

CX-010715: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

CX-010715: Categorical Exclusion Determination Replace Bayou Choctaw 500 KVA Power Transformer CX(s) Applied: B1.3 Date: 07092013 Location(s): Louisiana Offices(s): Strategic...

388

CX-010543: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

CX-010543: Categorical Exclusion Determination Repair of Big Hill Texas-14 Transformer CX(s) Applied: B1.3 Date: 06242013 Location(s): Texas Offices(s): Strategic...

389

CX-002435: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

CX-002435: Categorical Exclusion Determination Redmond Substation 230-115-Kilovolt Transformer Addition CX(s) Applied: B4.6 Date: 05072010 Location(s): Deschutes County, Oregon...

390

Mild Catalytic methods for Alkyl-Alkyl Bond Formation  

SciTech Connect

Overview of Research Goals and Accomplishments for the Period 07/01/06 – 06/30/07: Our overall research goal is to transform the rapidly emerging synthetic chemistry involving alkyl-alkyl cross-couplings into more of a mechanism-based field so that that new, rationally-designed catalysts can be performed under energy efficient conditions. Our specific objectives for the previous year were 1) to obtain a proper electronic description of an active catalyst for alkyl-alkyl cross-coupling reactions and 2) to determine the effect of ligand structure on the rate, scope, selectivity, and functional group compatibility of C(sp3)-C(sp3) cross-coupling catalysis. We have completed both of these initial objectives and established a firm base for further studies. The specific significant achievements of the current grant period include: 1) we have performed magnetic and computational studies on (terpyridine)NiMe, an active catalyst for alkyl-alkyl cross couplings, and have discovered that the unpaired electron resides heavily on the terpyridine ligand and that the proper electronic description of this nickel complex is a Ni(II)-methyl cation bound to a reduced terpyridine ligand; 2) we have for the first time shown that alkyl halide reduction by terpyridyl nickel catalysts is substantially ligand based; 3) we have shown by isotopic labeling studies that the active catalyst (terpyridine)NiMe is not produced via a mechanism that involves the formation of methyl radicals when (TMEDA)NiMe2 is used as the catalyst precursor; 4) we have performed an extensive ligand survey for the alkyl-alkyl cross-coupling reactions and have found that electronic factors only moderately influence reactivity in the terpyridine-based catalysis and that the most dramatic effects arise from steric and solubility factors; 5) we have found that the use of bis(dialkylphosphino)methanes as ligands for nickel does not produce active catalysts for cross-coupling but rather leads to bridging hydride complexes of varying geometries; 6) we have determined that the geometry of aforementioned bridging hydride complexes is largely determined by external forces such as hydrogen bonding interactions and crystal packing forces; 7) we have found that the rate of reductive elimination of alkane from a (pyridyl-2-pyrrolide)AuMe2 complex is severely inhibited due to the rigid geometry of the pyridyl-2-pyrrolide ligand; 8) we have prepared, structurally characterized, and explored the reactivity of 1-adamantylzinc reagents as model nucleophiles for sterically challenging alkyl-alkyl cross-coupling reactions. The continued success of this work will lead to alkyl-alkyl cross-coupling catalysts with broad scope and selectivities. The work has potential to significantly impact science and technologies of interest to the DOE as the chemistry is focused on developing useful reactions using reagents that can be directly prepared from petroleum and natural gas feedstocks. Moreover, the developing synthetic chemistry can profoundly affect the way materials, fine chemicals, and drugs are made. Since the methodology we are developing can shorten existing synthetic protocols, proceed at room temperature, and operate under environmentally benign conditions, it can greatly reduce energy expenditures, especially considering the contribution of the chemical manufacturing field to the gross domestic product.

David A Vicic

2009-08-10T23:59:59.000Z

391

CX-003621: Categorical Exclusion Determination | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

21: Categorical Exclusion Determination 21: Categorical Exclusion Determination CX-003621: Categorical Exclusion Determination Hayden Substation Transformer Replacement CX(s) Applied: B4.6 Date: 08/23/2010 Location(s): Routt County, Colorado Office(s): Western Area Power Administration-Rocky Mountain Region Western Area Power Administration proposes to replace the existing 100 megavolt-amphere (MVA) three phase transformer, KZ1A, at the Hayden Substation with a new three phase transformer. This project is required to remedy a temporary transformer configuration due to the failure of one of the windings of the original transformer. It is proposed that the temporary 230/138 kilovolt, 1000 MVA KZ1A transformer at Western's Hayden Substation be replaced with a new transformer having greater capacity so that existing

392

Microsoft Word - 41891_SWPC_Catalytic Combustor_Factsheet_Rev01_04-24.doc  

NLE Websites -- All DOE Office Websites (Extended Search)

891_SWPC_CATALYTIC COMBUSTOR_FACTSHEET_REV01_04-24.DOC 891_SWPC_CATALYTIC COMBUSTOR_FACTSHEET_REV01_04-24.DOC Facts Sheet: Catalytic Combustor for Fuel Flexible Gas Turbine (DE-FC26-03NT41891) I. PROJECT PARTICIPANTS A. Siemens Westinghouse Power Corporation B. Caterpillar/Solar Turbine C. Penn State University D. Southern Company Services II. PROJECT DESCRIPTION A. Objective: To develop and demonstrate a cost effective, fuel flexible (syngas/natural gas) catalytic combustor that will achieve ultra low NOx emissions (2ppm) at the exit of the gas turbine and without the use of backend cleanup in Integrated Gasification Combined Cycle (IGCC) application. B. Background/Relevancy 1. Background: Catalytic combustion has been shown to achieve lowest emissions in conventional gas turbine application (natural gas only). Available technical data indicate that it can be effective

393

Amendment 1 - Dry-type power transformers  

E-Print Network (OSTI)

Specifies requirements for dry-type power transformers (including auto-transformers) having values of highest voltage for equipment up to and including 36 kV. The following small and special dry-type transformers are not covered by this standard: -instrument transformers (covered by IEC 60185 and 60186); -transformers for static convertors (covered by IEC 60084, 60119 and 60146). Where IEC standards do not exist for other special transformers, this standard may be applicable as a whole or in part.

International Electrotechnical Commission. Geneva

1986-01-01T23:59:59.000Z

394

Categorical Exclusion (CX) Determination  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Movement of the Shirley Pump substation to a new site away from Movement of the Shirley Pump substation to a new site away from Yellowstone River and replacement of the Shirley Pump substation transformer. Description of Proposed Action: Move the existing Shirley Pump substation approximately 200 meters to the southeast away from its current location and the Yellowstone River as well as replace the aging transformer with a new one. Number and Title of Categorical Exclusions Being Applied: 10 CPR 1021.410 Subpart D, Appendix B, B4.11: Construction of electric power substations ... or modification of existing substations and support facilities. Regulatory Requirements for CX Determination: The DOE Guidelines for Compliance with the Regulatory Requirements for the National Environmental Policy Act at 10 CPR 1021.41 O(b),

395

Hydrogen transfer in transformations of olefin and thiophene compounds for the refining of gasoline fractions  

Science Journals Connector (OSTI)

Abstract Hydrogen transfer reactions in the transformations of mixtures of model hydrocarbons (hydrogen donors and acceptors) on zeolite catalysts were studied. Hydrogen donors were represented by various classes of hydrocarbons, and acceptors—by unsaturated (olefin) and thiophene compounds. The [H]-donor activity series of hydrocarbons was revealed. Strong differences in the transformation pathways of 1-hexene and 1-octene under the conditions of catalytic refining were demonstrated. A new method for the refining of low-rank gasoline fractions was proposed. The method is based on the hydrogen transfer reactions between hydrogen donor hydrocarbons and hydrogen acceptor hydrocarbons, which proceed without molecular hydrogen. The proposed method allows the simultaneous removal of sulfur (more than 95%) and unsaturated (more than 90%) compounds.

Oleg V. Potapenko; Vladimir P. Doronin; Tatyana P. Sorokina; Vladimir A. Likholobov

2014-01-01T23:59:59.000Z

396

Energy Department Finalizes Loan Guarantee for Transformational...  

Office of Environmental Management (EM)

for Transformational Rooftop Solar Project Energy Department Finalizes Loan Guarantee for Transformational Rooftop Solar Project September 30, 2011 - 3:37pm Addthis Washington D.C....

397

Investigation of Mineral Transformations in Wet Supercritical...  

NLE Websites -- All DOE Office Websites (Extended Search)

Mineral Transformations in Wet Supercritical CO2 by Electron Microscopy. Investigation of Mineral Transformations in Wet Supercritical CO2 by Electron Microscopy. Abstract: The...

398

Organizational assessment processes for enterprise transformation  

E-Print Network (OSTI)

Enterprise transformation is a dynamic process that builds upon and affects organizational processes. Organizational assessment plays critical role in planning and execution of enterprise transformation. It allows the ...

Abdimomunova, Leyla (Leyla M.)

2010-01-01T23:59:59.000Z

399

Marketing and Market Transformation | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

and Market Transformation Marketing and Market Transformation Presents how going green will grow your business, as well as how programs can overcome appraisal challenges....

400

Sandia National Laboratories: Solar Market Transformation  

NLE Websites -- All DOE Office Websites (Extended Search)

Transformation * photovoltaic * Photovoltaics * PV * Renewable Energy * SAND 2011-4654W * Solar Energy * Solar Market Transformation * Solar Research Comments are closed. Renewable...

Note: This page contains sample records for the topic "determination catalytic transformation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Deactivation and regeneration of ZSM-5 zeolite in catalytic pyrolysis of plastic wastes  

SciTech Connect

Highlights: > Pyrolysis transforms plastic wastes in valuable liquids and gases useful as fuels or source of chemicals. > The use of ZSM-5 zeolite in pyrolysis favours the production of gases and of lighter and more aromatic liquids. > ZSM-5 zeolite is almost completely deactivated after one plastics pyrolysis experiment. > ZSM-5 zeolite used in plastic wastes pyrolysis can be regenerated by burning the deposited coke in an air stream. > Regenerated ZSM-5 recovers its activity and produces liquids and gases equivalent to those obtained with fresh catalyst. - Abstract: In this work, a study of the regeneration and reuse of ZSM-5 zeolite in the pyrolysis of a plastic mixture has been carried out in a semi-batch reactor at 440 deg. C. The results have been compared with those obtained with fresh-catalyst and in non-catalytic experiments with the same conditions. The use of fresh catalyst produces a significant change in both the pyrolysis yields and the properties of the liquids and gases obtained. Gases more rich in C3-C4 and H{sub 2} are produced, as well as lower quantities of aromatic liquids if compared with those obtained in thermal decomposition. The authors have proved that after one pyrolysis experiment the zeolite loses quite a lot of its activity, which is reflected in both the yields and the products quality; however, this deactivation was found to be reversible since after regeneration heating at 550 deg. C in oxygen atmosphere, this catalyst recovered its initial activity, generating similar products and in equivalent proportions as those obtained with fresh catalyst.

Lopez, A., E-mail: alex.lopez@ehu.es [Chemical and Environmental Engineering Department, School of Engineering of Bilbao, Alameda Urquijo s/n, 48013 Bilbao (Spain); Marco, I. de; Caballero, B.M.; Adrados, A.; Laresgoiti, M.F. [Chemical and Environmental Engineering Department, School of Engineering of Bilbao, Alameda Urquijo s/n, 48013 Bilbao (Spain)

2011-08-15T23:59:59.000Z

402

Coal hydrogenation and deashing in ebullated bed catalytic reactor  

DOE Patents (OSTI)

An improved process for hydrogenation of coal containing ash with agglomeration and removal of ash from an ebullated bed catalytic reactor to produce deashed hydrocarbon liquid and gas products. In the process, a flowable coal-oil slurry is reacted with hydrogen in an ebullated catalyst bed reaction zone at elevated temperature and pressure conditions. The upward velocity and viscosity of the reactor liquid are controlled so that a substantial portion of the ash released from the coal is agglomerated to form larger particles in the upper portion of the reactor above the catalyst bed, from which the agglomerated ash is separately withdrawn along with adhering reaction zone liquid. The resulting hydrogenated hydrocarbon effluent material product is phase separated to remove vapor fractions, after which any ash remaining in the liquid fraction can be removed to produce substantially ash-free coal-derived liquid products.

Huibers, Derk T. A. (Pennington, NJ); Johanson, Edwin S. (Princeton, NJ)

1983-01-01T23:59:59.000Z

403

Development of a Methane Premixed Catalytic Burner for Household Applications  

Science Journals Connector (OSTI)

The catalytic combustion of methane is currently investigated in a variety of international research programs, thanks to its numerous potential applications (e.g., boilers, process heaters, reciprocating engines, gas-turbine cycles, etc.). ... At low surface heat powers (Q) and excesses of air (Ea), the combustion mostly occurs in a thin layer within the permeable panel (radiant or flameless regime, Figure 1b); the burner outlet surface (burner deck) reaches temperatures varying from 700 to 900 °C, depending on both Q and Ea values, and glows flamelessly. ... The goal is to assemble a boiler capable of coping with variable hot water requests:? from about 2?3 kW (160?240 kW/m2) for apartment heating up to 25 kW (2000 kW/m2) for sanitary purposes, so as to produce hot water with time delays compatible with the users' comfort. ...

Isotta Cerri; Guido Saracco; Francesco Geobaldo; Vito Specchia

2000-01-04T23:59:59.000Z

404

Tantalum pillard montmorillonite: II. Acidic and catalytic properties  

SciTech Connect

The acidic and catalytic properties of a series of Ta-PILCs synthesized with a different initial tantalum content were characterized by adsorption of gaseous probe molecules (TPD of ammonia and FTIR spectra of absorbed pyridine) and by the test reaction of 1-butanol dehydration. A large increase of acidity was noted in Ta-PILCs compared to Na-montmorillonite or tantalum oxide. Cross-linking pillars and silica layers of the clay induce stronger Lewis and new Bronsted sites. The lack of basic sites formation is evidenced by the dehydration of 1-butanol to butene selectivity (100%). The incorporation of the tantalum oxide between the montmorillonite sheets produce, within Ta-PILC, acid centers of the same nature as observed for the silicon-tantalum mixed oxides. 32 refs., 4 figs., 5 tabs.

Guiu, G.; Grange, P. [Universite Catholique de Louvain, Louvain-la-Neuve (Belgium)] [Universite Catholique de Louvain, Louvain-la-Neuve (Belgium)

1997-06-01T23:59:59.000Z

405

Ex-Situ Catalytic Fast Pyrolysis Technology Pathway  

SciTech Connect

In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to hydrocarbon fuels to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This pathway case investigates converting woody biomass using ex-situ catalytic fast pyrolysis followed by upgrading to gasoline , diesel and jet range blendstocks . Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified.

Biddy, Mary J.; Dutta, Abhijit; Jones, Susanne B.; Meyer, Pimphan A.

2013-03-31T23:59:59.000Z

406

In-Situ Catalytic Fast Pyrolysis Technology Pathway  

SciTech Connect

In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to hydrocarbon fuels to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This pathway case investigates converting woody biomass using in-situ catalytic fast pyrolysis followed by upgrading to gasoline, diesel, and jet range blendstocks. Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified.

Biddy, Mary J.; Dutta, Abhijit; Jones, Susanne B.; Meyer, Pimphan A.

2013-03-31T23:59:59.000Z

407

Treating isopropyl alcohol by a regenerative catalytic oxidizer  

Science Journals Connector (OSTI)

Regenerative catalytic oxidizer (RCO) can be conveniently used to control emissions of volatile organic compounds (VOCs), because of their thermal recovery efficiency (TRE), low fuel cost and high oxidation. In this work, catalysts with various metal weight loadings were prepared by deposition–precipitation, wet impregnation and incipient impregnation to treat isopropyl alcohol (IPA). We used the excellent catalytic performance in a pilot RCO to test IPA oxidation performance under various conditions. The best catalyst was selected and its TRE, bed temperature variations, pressure drops and selectivity of the catalyst were more widely discussed. The results demonstrate that the optimal catalyst was prepared by wet impregnation with 20 wt.% metal on ceramic honeycomb (CH). 20 wt.% Cu–Co/(CH) catalyst was the best catalyst used in a RCO because it was effective in treating IPA, with a CO2 yield of up to 95% at a heating zone temperature (Tset) = 400 °C under various conditions. It also had the largest tolerance of variations in inlet IPA concentration and gas velocity (Ug). This 20 wt.% Cu–Co/(CH) catalyst in a RCO performed well in terms of TRE, pressure drop and selectivity to CO2. The TRE range in a RCO was from 87.8 to 91.2% under various conditions, and decreased as Ug increased in a fixed Tset. The pressure drop increased with Ug and Tset. The selectivity to CO2 increased to over 95% at 300 °C, and that to propene remained at 2–5% from 200 to 400 °C. Finally, the stability test results indicated that the 20 wt.% Cu–Co/(CH) catalyst was very stable at various CO2 yields and temperatures.

Jie-Chung Lou; Shih-Wei Huang

2008-01-01T23:59:59.000Z

408

STATIONARY MEASURES FOR PROJECTIVE TRANSFORMATIONS: THE BLACKWELL AND  

E-Print Network (OSTI)

STATIONARY MEASURES FOR PROJECTIVE TRANSFORMATIONS: THE BLACKWELL AND FURSTENBERG MEASURES B. B´AR´ANY, M. POLLICOTT AND K. SIMON Abstract. In this paper we study the Blackwell and Furstenberg measures. For the Blackwell measure we determine parameter domains of singularity and give upper bounds for the Hausdorff

Pollicott, Mark

409

Solar reforming of methane in a direct absorption catalytic reactor on a parabolic dish: 2, Modeling and analysis  

SciTech Connect

The CAtalytically Enhanced Solar Absorption Receiver (CAESAR) experiment was conducted to determine the thermal, chemical, and mechanical performance of a commercial-scale, dish-mounted, direct catalytic absorption receiver (DCAR) reactor over a range of steady state and transient (cloud) operating conditions. The focus of the experiment is on global performance such as receiver efficiencies and overall methane conversion; it was not intended to provide data for code validation. A numerical model was previously developed to provide guidance in the design of the absorber. The one-dimensional, planar and steady-state model incorporates, the following energy transfer mechanisms: solar and infrared radiation, heterogeneous chemical reaction, conduction in the solid phase, and convection between the fluid and solid phases. A number of upgrades to the model and improved property values are presented here. Model predictions are shown to bound the experimental axial thermocouple data when experimental uncertainties are included. Global predictions are made using a technique in which the incident solar flux distribution is subdivided into flux contour bands. Model predictions for each band are then spatially integrated to provide global predictions such as reactor efficiencies and methane conversions. Global predictions are shown to compare well with experimental data. Reactor predictions for anticipated operating conditions suggest a further decrease in optical density at the front of the absorber inner disk may be beneficial. The need to conduct code-validation experiments is identified as essential to improve the confidence in the capability to predict large-scale reactor operation.

Skocypec, R.D.; Hogan, R.E. Jr.; Muir, J.F.

1991-01-01T23:59:59.000Z

410

CX-006289: Categorical Exclusion Determination | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

289: Categorical Exclusion Determination 289: Categorical Exclusion Determination CX-006289: Categorical Exclusion Determination Willow Creek Substation -Transformer Replacement and Substation Modifications CX(s) Applied: B4.6 Date: 07/26/2011 Location(s): Grand County, Colorado Office(s): Western Area Power Administration-Rocky Mountain Region Western Area Power Administration (Western) proposes to make modifications to the Willow Creek Substation, near Grand Lake, Grand County, Colorado. The project includes removing two existing transformers and replacing them with one larger transformer. DOCUMENT(S) AVAILABLE FOR DOWNLOAD CX-006289.pdf More Documents & Publications CX-009235: Categorical Exclusion Determination CX-006280: Categorical Exclusion Determination EIS-0400: Draft Environmental Impact Statement

411

The Ideal Transformer Description and Circuit Symbol  

E-Print Network (OSTI)

The Ideal Transformer Description and Circuit Symbol As with all the other circuit elements, there is a physical transformer commonly used in circuits whose behavior can be discussed in great detail. However, in many cases the practical transformer can be adequately approximated by the "ideal transformer," which

King, Roger

412

Transform Solar | Open Energy Information  

Open Energy Info (EERE)

Transform Solar Transform Solar Jump to: navigation, search Name Transform Solar Place Boise, Idaho Product Idaho-based PV module maker and joint venture between Micron and Origin Energy. Coordinates 43.60698°, -116.193409° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":43.60698,"lon":-116.193409,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

413

Phase Transformations in Confined Nanosystems  

SciTech Connect

This project discovered that non-equilibrium structures, including chemically ordered structures not observed in bulk systems, form in isolated nanoscale systems. Further, a generalized model was developed that effectively explained the suppression of equilibrium phase transformations. This thermodynamic model considered the free energy decrease associated with the phase transformation was less than the increase in energy associated with the formation of an interphase interface, therefore inhibiting the phase transformation. A critical diameter exists where the system transitions to bulk behavior, and a generalized equation was formulated that successfully predicted this transition in the Fe-Au system. This provided and explains a new route to novel structures not possible in bulk systems. The structural characterization was accomplished using transmission electron microscopy in collaboration with Matthew Kramer of Ames Laboratory. The PI and graduate student visited Ames Laboratory several times a year to conduct the experiments.

Shield, Jeffrey E. [Department of Mechanical & Materials Engineering] [Department of Mechanical & Materials Engineering; Belashchenko, Kirill [Department of Physics & Astronomy] [Department of Physics & Astronomy

2014-04-29T23:59:59.000Z

414

,"Catalytic Reforming Downstream Processing of Fresh Feed Input"  

U.S. Energy Information Administration (EIA) Indexed Site

Catalytic Reforming Downstream Processing of Fresh Feed Input" Catalytic Reforming Downstream Processing of Fresh Feed Input" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Catalytic Reforming Downstream Processing of Fresh Feed Input",16,"Monthly","9/2013","1/15/2010" ,"Release Date:","11/27/2013" ,"Next Release Date:","Last Week of December 2013" ,"Excel File Name:","pet_pnp_dwns_a_(na)_ydr_mbblpd_m.xls" ,"Available from Web Page:","http://www.eia.gov/dnav/pet/pet_pnp_dwns_a_(na)_ydr_mbblpd_m.htm" ,"Source:","Energy Information Administration"

415

Categorical Exclusion Determinations: Pennsylvania | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Pennsylvania Pennsylvania Categorical Exclusion Determinations: Pennsylvania Location Categorical Exclusion Determinations issued for actions in Pennsylvania. DOCUMENTS AVAILABLE FOR DOWNLOAD September 25, 2013 CX-010912: Categorical Exclusion Determination B-922 Sprinkler System Replacement CX(s) Applied: B1.15, B2.2, B2.5 Date: 09/25/2013 Location(s): Pennsylvania Offices(s): National Energy Technology Laboratory September 24, 2013 CX-010913: Categorical Exclusion Determination Replace B920 Fire Wall Line: Phase Two CX(s) Applied: B1.3 Date: 09/24/2013 Location(s): Pennsylvania Offices(s): National Energy Technology Laboratory September 23, 2013 CX-010920: Categorical Exclusion Determination Advanced Catalytic Solvent for Carbon Dioxide (CO2) Capture CX(s) Applied: A9 Date: 09/23/2013

416

Conformal transformations and accelerated cosmologies  

Science Journals Connector (OSTI)

A cosmological theory that predicts a late-time accelerated attractor with a constant dark matter to dark energy ratio can be said to solve the coincidence problem. Such cosmologies are naturally generated in the context of nonstandard gravity theories under conformal transformation because of the resulting couplings between scalar fields and matter. The present work examines four classes of these transformed theories and finds that only a small subset-those with a single scalar field-are capable of solving the coincidence problem.

James L. Crooks and Paul H. Frampton

2006-06-09T23:59:59.000Z

417

The transformations of the electromagnetic potentials under translations  

E-Print Network (OSTI)

I consider infinitesimal translations $x'^{\\alpha}=x^{\\alpha}+\\delta x^{\\alpha}$ and demand that Noether's approach gives a symmetric electromagnetic energy-momentum tensor as it is required for gravitational sources. This argument determines the transformations of the electromagnetic potentials under infinitesimal translations to be $A'_{\\gamma} (x') = A_{\\gamma}(x)+\\partial_{\\gamma} [\\delta x_{\\beta} A^{\\beta}(x)]$, which differs from the usually assumed invariance $A'_{\\gamma} (x') = A_{\\gamma}(x)$, by the gauge transformation $\\partial_{\\gamma} [\\delta x_{\\beta} A^{\\beta}(x)]$.

Bernd A. Berg

2000-06-05T23:59:59.000Z

418

The transformations of non-abelian gauge fields under translations  

E-Print Network (OSTI)

I consider infinitesimal translations $x'^{\\alpha}=x^{\\alpha}+\\delta x^{\\alpha}$ and demand that Noether's approach gives a symmetric energy-momentum tensor as it is required for gravitational sources. This argument determines the transformations of non-abelian gauge fields under infinitesimal translations to differ from the usually assumed invariance by the gauge transformation, $A'^a_{\\gamma} (x') - A^a_{\\gamma}(x) = \\partial_{\\gamma} [ \\delta x_{\\beta} A^{a \\beta}(x)] + C^a_{bc} \\delta x_{\\beta} A^{c \\beta}(x) A^{b}_{\\gamma}(x)$ where the $C^a_{bc}$ are the structure constants of the gauge group.

Bernd A. Berg

2000-06-06T23:59:59.000Z

419

On the equivalence of state transformer semantics and predicate transformer semantics  

E-Print Network (OSTI)

On the equivalence of state transformer semantics and predicate transformer semantics Dedicated and the author [13] have worked out the equivalence between state transformer semantics and predicate transformer the last section, where the equivalence of predicate and state transformer semantics is finally put

Keimel, Klaus

420

Model Transformations? Transformation Models! Jean Bezivin (A) , Fabian Buttner (B) , Martin Gogolla (B) ,  

E-Print Network (OSTI)

Model Transformations? Transformation Models! Jean Bezivin (A) , Fabian BË?uttner (B) , Martin of the current work on model transformations seems essentially operational and executable in nature. Executable, transformations can also be viewed as descriptive models by stating only the properties a transformation has

Gogolla, Martin - Fachbereich 3

Note: This page contains sample records for the topic "determination catalytic transformation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

ENGI 2422 Laplace Transforms Page 5-01 5.01 Transforms  

E-Print Network (OSTI)

ENGI 2422 Laplace Transforms Page 5-01 5.01 Transforms In some situations, a difficult problem can be transformed into an easier problem, whose solution can be transformed back into the solution of the original problem. For example, an integrating factor can sometimes be found to transform a non-exact first order

George, Glyn

422

Transformation techniques for OCL constraints  

Science Journals Connector (OSTI)

Constraints play a key role in the definition of conceptual schemas. In the UML, constraints are usually specified by means of invariants written in the OCL. However, due to the high expressiveness of the OCL, the designer has different syntactic alternatives ... Keywords: Integrity constraints, OCL, Transformation

J. Cabot; E. Teniente

2007-10-01T23:59:59.000Z

423

Induced geometry from disformal transformation  

E-Print Network (OSTI)

In this note, we use the disformal transformation to induce a geometry from the manifold which is originally Riemannian. The new geometry obtained here can be considered as a generalization of Weyl integrable geometry. Based on these results, we further propose a geometry which is naturally a generalization of Weyl geometry.

Yuan, Fang-Fang

2015-01-01T23:59:59.000Z

424

Induced geometry from disformal transformation  

E-Print Network (OSTI)

In this note, we use the disformal transformation to induce a geometry from the manifold which is originally Riemannian. The new geometry obtained here can be considered as a generalization of Weyl integrable geometry. Based on these results, we further propose a geometry which is naturally a generalization of Weyl geometry.

Fang-Fang Yuan; Peng Huang

2015-02-08T23:59:59.000Z

425

Image capture system colors transforms  

Science Journals Connector (OSTI)

The goal of this paper is to simulate the colors transforms of the reflected light from an illuminated object that passes trough an image capture system. We are interested to see the colors differences at the output of each component from which the light ... Keywords: CIE standards, human eye response, lenses and filters transmittance, spectral images

Toadere Florin

2010-02-01T23:59:59.000Z

426

Higher Order BLG Supersymmetry Transformations from 10-Dimensional Super Yang Mills  

E-Print Network (OSTI)

We study a Simple Route for constructing the higher order Bagger-Lambert-Gustavsson theory - both supersymmetry transformations and Lagrangian - starting from knowledge of only the $10$-dimensional Super Yang Mills Fermion Supersymmetry transformation. We are able to uniquely determine the four-derivative order corrected supersymmetry transformations, to lowest non-trivial order in Fermions, for the most general three-algebra theory. For the special case of Euclidean three-algbera, we reproduce the result presented in arXiv:$1207.1208$, with significantly less labour. In addition, we apply our method to calculate the quadratic fermion terms in the higher order BLG fermion supersymmetry transformation.

John Hall; Andrew Low

2014-03-28T23:59:59.000Z

427

Geek-Up[3.18.2011]: Catalytically Active Material and BELLA | Department of  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

8.2011]: Catalytically Active Material and BELLA 8.2011]: Catalytically Active Material and BELLA Geek-Up[3.18.2011]: Catalytically Active Material and BELLA March 18, 2011 - 3:54pm Addthis PNNL scientists Grant Johnson and Julia Laskin | Photo Courtesy of the Pacific Northwest National Laboratory PNNL scientists Grant Johnson and Julia Laskin | Photo Courtesy of the Pacific Northwest National Laboratory Niketa Kumar Niketa Kumar Public Affairs Specialist, Office of Public Affairs What are the key facts? PNL researchers produced catalytically active material that may help advance fuel cell and solar energy storage applications. In just one meter a single BELLA stage -- with a "boosted-frame" method -- will accelerate an electron beam to 10 billion electron volts. Thanks to an innovative approach from Pacific Northwest National Laboratory

428

Catalytic Hydrodeoxygenation of Methyl-Substituted Phenols: Correlations of Kinetic Parameters with Molecular Properties  

E-Print Network (OSTI)

. Introduction As a result of increasing environmental concerns, catalytic hydrotreating has become an important, oil shale, and tar sands would render the hydrotreating of oxygen-containing com- pounds, mostly

Simons, Jack

429

Catalytic roles of Co0 and Co2+ during steam reforming of ethanol...  

NLE Websites -- All DOE Office Websites (Extended Search)

roles of Co0 and Co2+ during steam reforming of ethanol on CoMgO catalysts . Catalytic roles of Co0 and Co2+ during steam reforming of ethanol on CoMgO catalysts . Abstract:...

430

Thermally Coupled Catalytic Reactor for Steam Reforming of Methane and Liquid Hydrocarbons: Experiment and Mathematical Modeling  

Science Journals Connector (OSTI)

An energy-efficient catalytic reactor for producing synthesis gas from methane and liquid hydrocarbons is proposed that is ... on the coupling of an endothermic reaction (steam reforming of methane, hexane, or is...

V. A. Kirillov; N. A. Kuzin; A. V. Kulikov…

2003-05-01T23:59:59.000Z

431

Chemical-Catalytic Approaches to the Production of Furfurals and Levulinates from Biomass  

Science Journals Connector (OSTI)

The synthesis and chemistry of 5-(hydroxymethyl)furfural (HMF), 5-(chloromethyl)furfural (CMF), ... levulinic acid (LA), three carbohydrate-derived platform molecules produced by the chemical-catalytic processing...

Mark Mascal; Saikat Dutta

2014-01-01T23:59:59.000Z

432

Center for Catalytic Science and Technology Recent Highlights from the Center for  

E-Print Network (OSTI)

for Catalytic Science and Technology CCST Research Areas Electrocatalysts and hydrogen processing for PEM fuel cells Selective oxidation and selective hydrogenation Biomass to fuels and chemicals phosphates prepared in ionic liquids A straightforward, cost-effective and scalable synthesis

Firestone, Jeremy

433

Catalytic Conversion of Tars, Carbon Black and Methane from Pyrolysis/Gasification of Biomass  

Science Journals Connector (OSTI)

The use of catalysts in biomass gasification has been suggested for a long time.1 Fung and Graham found that potassium carbonate and calcium oxide have catalytic influences on the gasification rate and the produc...

Clas Ekström; Nils Lindman; Rune Pettersson

1985-01-01T23:59:59.000Z

434

Catalytic Activity of Alkali Metals on the Thermochemical Conversion of Biomass Materials  

Science Journals Connector (OSTI)

The first reaction in the thermal decomposition of cellulose is very sensitive to the existence of mineral impurities such as alkali metals and iron at concentrations as low as 0.5%. The catalytic reaction app...

Mahmood M. Barbooti

1986-01-01T23:59:59.000Z

435

E-Print Network 3.0 - atp catalytic domain Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

domain Search Powered by Explorit Topic List Advanced Search Sample search results for: atp catalytic domain Page: << < 1 2 3 4 5 > >> 1 Encyclopedia of Molecular Biology Thomas E....

436

E-Print Network 3.0 - atp catalytic cycle Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

cycle Search Powered by Explorit Topic List Advanced Search Sample search results for: atp catalytic cycle Page: << < 1 2 3 4 5 > >> 1 Encyclopedia of Molecular Biology Thomas E....

437

CO-CATALYTIC ABSORPTION LAYERS FOR CONTROLLED LASER-INDUCED CHEMICAL VAPOR DEPOSITION OF CARBON NANOTUBES  

E-Print Network (OSTI)

The concept of co-catalytic layer structures for controlled laser-induced chemical vapor deposition of carbon nanotubes is established, in which a thin Ta support layer chemically aids the initial Fe catalyst reduction. This enables a significant...

Michaelis, F.B.; Weatherup, R.S.; Bayer, B.C.; Bock, M.C.D; Sugime, H.; Caneva, S.; Robertson, J.; Baumberg, J.J.; Hofmann, S.

2014-02-24T23:59:59.000Z

438

Oxygen transport membrane system and method for transferring heat to catalytic/process reactors  

DOE Patents (OSTI)

A method and apparatus for producing heat used in a synthesis gas production is provided. The disclosed method and apparatus include a plurality of tubular oxygen transport membrane elements adapted to separate oxygen from an oxygen containing stream contacting the retentate side of the membrane elements. The permeated oxygen is combusted with a hydrogen containing synthesis gas stream contacting the permeate side of the tubular oxygen transport membrane elements thereby generating a reaction product stream and radiant heat. The present method and apparatus also includes at least one catalytic reactor containing a catalyst to promote the stream reforming reaction wherein the catalytic reactor is surrounded by the plurality of tubular oxygen transport membrane elements. The view factor between the catalytic reactor and the plurality of tubular oxygen transport membrane elements radiating heat to the catalytic reactor is greater than or equal to 0.5.

Kelly, Sean M; Kromer, Brian R; Litwin, Michael M; Rosen, Lee J; Christie, Gervase Maxwell; Wilson, Jamie R; Kosowski, Lawrence W; Robinson, Charles

2014-01-07T23:59:59.000Z

439

Catalytic converter applications for two stroke, spark-ignited marine engines  

SciTech Connect

When catalytic converters are used for cleansing of exhaust gas from two-stroke marine engines, new issues must be brought up in combination with prior technology. Therefore, a study was made of V6, 2600cc engine having a large volume of hydrocarbon emissions with respect to three issues: (1) To what degree seawater effects catalytic converter performance and possible countermeasures; (2) Effects attained on cleansing level and catalyst temperature; (3) Finding abatement levels for catalyst deterioration and exhaust emission output in the marine mode. It was found that physical adsorption was a significant factor in catalytic degradation resulting from direct contact with seawater. The cleansing levels obtained when a marine engine is equipped with a catalyst converter were found by clarifying the extent of effects of catalyst volume, performance and temperature. The reduction obtained in exhaust emission allowing for a deterioration factor, is shown in a catalytic converter heated to the maximum temperature of 960 C.

Fujimoto, Hiroaki; Isogawa, Atsushi; Matsumoto, Naoto

1995-12-31T23:59:59.000Z

440

A resource recycling technique of hydrogen production from the catalytic degradation of organics in wastewater  

Science Journals Connector (OSTI)

A resource recycling technique of hydrogen production from the catalytic degradation of organics in wastewater by aqueous phase reforming (APR) has...N,N-dimethylformamide (DMF) and cyclohexanol) in water could b...

XiaoNian Li; LingNiao Kong; YiZhi Xiang; YaoMing Ju…

2008-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "determination catalytic transformation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Effects of copper catalytic reactions on the development of supersonic hydrogen flames  

SciTech Connect

Copper species are present in hydrogen flames in arc heated supersonic ramjet testing facilities. Homogeneous and heterogeneous copper catalytic reactions may affect the flame development by enhancing the recombination of hydrogen atoms. Computer simulation is used to investigate the effects of the catalytic reactions on the reaction and ignition times of the flames. The simulation uses a modified general chemical kinetics computer program to simulate the development of copper-contaminated hydrogen flames under scramjet testing conditions. Reaction times of hydrogen flames are found to be reduced due to the copper catalytic effects, but ignition times are much less sensitive to such effects. The reduction of reaction time depends on copper concentration, particle size (if copper is in the condensed phase), and Mach number (or initial temperature and pressure). As copper concentration increases or the particle size decreases, reaction time decreases. As Mach number increases (or pressure and temperature decrease), the copper catalytic effects are greater.

Chang, S.L.; Lottes, S.A.; Berry, G.F.

1992-10-01T23:59:59.000Z

442

Catalytic steam gasification of carbon: Final report, 3/1/84-2/28/87  

SciTech Connect

Work for this grant period covers two areas: formation of coke on the platinum surface of reforming catalysts, and the preparation, surface reactivity, and catalytic activity of high specific surface area molybdenum and tungsten carbides.

Boudart, M.

1987-01-01T23:59:59.000Z

443

E-Print Network 3.0 - active catalytic sites Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

interface to the active site andor a macromolecular substrate-binding site.21... (IXegf1)a-TF. The active site is depicted by superimposing the catalytic domains of the nal...

444

E-Print Network 3.0 - acrylamide catalytically inhibits Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

for non-commercial research and Summary: that ADP was not essential suggesting that MgVi-F1 complex inhibited the catalytic activity to the same... :www.elsevier.comcopyright...

445

Reaction kinetics of olefin saturation in the hydrodesulfurization of fluid catalytic cracked naphtha  

E-Print Network (OSTI)

U.S. governmental agencies are calling for strict environmental regulations on the quality of gasoline. Fluid catalytic cracked naphtha is an important blending component of the gasoline pool. The majority of the sulfur in the gasoline pool comes...

Schumann, Brian Herbert

2012-06-07T23:59:59.000Z

446

Comparison of Gas Catalytic and Electric Infrared Performance for Industrial Applications  

E-Print Network (OSTI)

A study was conducted to evaluate the performance of gas catalytic and electric infrared for industrial applications. The project focused on fabric drying, paper drying, metal heating, and plastic forming as target industrial applications. Tests...

Eshraghi, R. R.; Welch, D. E.

447

E-Print Network 3.0 - advanced catalytic science Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

science Search Powered by Explorit Topic List Advanced Search Sample search results for: advanced catalytic science Page: << < 1 2 3 4 5 > >> 1 Synthesis of single-walled carbon...

448

Biomass gasification using a horizontal entrained-flow gasifier and catalytic processing of the product gas.  

E-Print Network (OSTI)

??A novel study on biomass-air gasification using a horizontal entrained-flow gasifier and catalytic processing of the product gas has been conducted. The study was designed… (more)

Legonda, Isack Amos

2012-01-01T23:59:59.000Z

449

Natural catalytic activity in a marine shale for generating natural gas  

Science Journals Connector (OSTI)

...natural catalytic activity in marine shales. Gas is generated at ambient temperatures...differences are in degree. Mowry shale generates gas compositions that are quite different...probably a major source of natural gas. Mowry shale generates gas at thermodynamic...

2010-01-01T23:59:59.000Z

450

Application of a cw quantum cascade laser CO2 analyser to catalytic oxidation reaction monitoring  

Science Journals Connector (OSTI)

Catalytic oxidation reaction monitoring has been performed for the first time with a trace gas carbon dioxide analyser based on a continuous wave (cw), thermoelectrically cooled (TEC), distributed feedback (DFB)

V. L. Kasyutich; D. Poulidi; M. Jalil; I. S. Metcalfe; P. A. Martin

2013-02-01T23:59:59.000Z

451

Regional catalytic economic impacts and noise-damage costs of aviation growth  

E-Print Network (OSTI)

There is growing recognition that transportation or infrastructure improvements can have longer-term catalytic impacts economic productivity, which are in addition to the direct, indirect, or induced household spending ...

Tam, Ryan Aung Min, 1973-

2008-01-01T23:59:59.000Z

452

Activation energy of ignition for catalytic oxidation of ethanol in oscillatory regime  

Science Journals Connector (OSTI)

Activation energies of ignition for the thermokinetic oscillations obtained during the heterogeneous catalytic oxidation of ethanol on Pd/Al2O3...in a dynamic calorimeter were obtained using the minimum values of...

N. I. Ionescu; N. I. Jaeger; P. J. Plath…

2008-02-01T23:59:59.000Z

453

NMR Sensor for Onboard Ship Detection of Catalytic Fines in Marine Fuel Oils  

Science Journals Connector (OSTI)

NMR Sensor for Onboard Ship Detection of Catalytic Fines in Marine Fuel Oils ... Vermeire, M. B. Everything You Need to Know About Marine Fuels; Chevron Global Marine Products: Ghent, Belgium, 2007. ...

Morten K. Sørensen; Mads S. Vinding; Oleg N. Bakharev; Tomas Nesgaard; Ole Jensen; Niels Chr. Nielsen

2014-07-02T23:59:59.000Z

454

Study of biomass combustion characteristics for the development of a catalytic combustor/gasifier.  

E-Print Network (OSTI)

??The research reported here explored, a "new" approach to biomass energy conversion for small-scale process heat-applications. The conversion process uses close-coupled catalytic. combustion to burn… (more)

Dody, Joseph W.

2012-01-01T23:59:59.000Z

455

Physicochemical and catalytic properties of iron- and indium-containing zeolites  

Science Journals Connector (OSTI)

The influence of the preparation procedure of Fe- and In-containing zeolites on their physicochemical and catalytic properties in methanol conversion to hydrocarbons and the upgrading of the straight-run gasoline

L. M. Velichkina; L. L. Korobitsyna; B. Ulzii; A. V. Vosmerikov…

2013-03-01T23:59:59.000Z

456

Year/PAD District Cokers Catalytic Crackers Hydrocrackers Capacity  

U.S. Energy Information Administration (EIA) Indexed Site

Cokers Catalytic Crackers Hydrocrackers Capacity Inputs Capacity Inputs Capacity Inputs Table 8. Capacity and Fresh Feed Input to Selected Downstream Units at U.S. Refineries, 2011 - 2013 (Barrels per Calendar Day) Reformers Capacity Inputs 2011 2,396,787 5,794,214 1,687,745 2,093,849 4,952,455 1,466,627 2,570,970 3,346,457 93,700 673,300 41,500 37,932 490,729 18,030 PADD I 188,389 266,950 373,897 1,176,972 254,000 350,063 1,017,616 223,751 PADD II 664,852 812,244 1,318,440 2,933,842 841,285 1,183,318 2,570,348 744,638 PADD III 1,243,427 1,629,967 80,350 185,800 28,200 63,362 158,192 18,214 PADD IV 96,649 120,190 530,400 824,300 522,760 459,175 715,570 461,995 PADD V 377,652 517,106 2012 2,499,293 5,611,191 1,706,540 2,173,336 4,901,284 1,528,708 2,614,571 3,246,874 74,900 489,300 20,000

457

Diesel emission control: Catalytic filters for particulate removal  

Science Journals Connector (OSTI)

The European diesel engine industry represents a vital sector across the Continent, with more than 2 million direct work positions and a turnover of over 400 billion Euro. Diesel engines provide large paybacks to society since they are extensively used to transport goods, services and people. In recent years increasing attention has been paid to the emissions from diesel engines which, like gasoline engine emissions, include carbon monoxide (CO), hydrocarbons (HC) and oxides of nitrogen (NOx). Diesel engines also produce significant levels of particulate matter (PM), which consists mostly of carbonaceous soot and a soluble organic fraction (SOF) of hydrocarbons that have condensed on the soot.Meeting the emission levels imposed for NOx and PM by legislation (Euro IV in 2005 and, in the 2008 perspective, Euro V) requires the development of a number of critical technologies to fulfill these very stringent emission limits (e.g. 0.005 g/km for PM). This review is focused on these innovative technologies with special reference to catalytic traps for diesel particulate removal.

Debora Fino

2007-01-01T23:59:59.000Z

458

Effect of severity on catalytic hydroprocessed shale oil jet fuels  

SciTech Connect

Catalytic hydroprocessed shale oil jet fuels in the USA were characterized and compared with petroleum jet fuel to demonstrate their possibility as a conventional jet fuel substitute. The shale oils (Geokinetics, Occidental, Paraho and Tosco II) were hydrotreated in a 0.0508m ID by K1.524m long reactor containing Ni/Mo/Al/sub 2/O/sub 3/ catalyst. The fractionated hydrogenated shale oils at jet fuel ranges (120-300/degree/C) were analyzed for composition and physical properties. The increasing hydroprocessing severity proportionally decreased nitrogen, sulfur, olefins, aromatics and increased hydrogen content. The nitrogen content was considerable higher even at high severity conditions. Sulfur and olefin contents were lower at all severities. The heat of combustion and the physical properties, except the freezing point, were comparable to petroleum jet fuels. The yields of jet fuels increased proportionally to increased severity. The study showed that high severity hydroprocessing gave better performance in processing shale oils to jet fuels.

Mukherjee, N.L.

1987-01-01T23:59:59.000Z

459

TEC as electric generator in an automobile catalytic converter  

SciTech Connect

Modern cars use more and more electric power due to more on-board electric systems, e.g., ABS brakes, active suspension systems, electric windows, chair adjustment systems and electronic engine control systems. One possible energy source for electricity generation is to use the waste heat from the car`s engine, which generally is as much as 80% of the total energy from the combustion of the gasoline. Maybe the best location to tap the excess heat is the Catalytic Converter (Cat) in the exhaust system or perhaps at the exhaust pipes close to the engine. The Cat must be kept within a certain temperature interval. Large amounts of heat are dissipated through the wall of the Cat. A Thermionic Energy Converter (TEC) in coaxial form could conveniently be located around the ceramic cartridge of the Cat. Since the TEC is a rather good heat insulator before it reaches its working temperature the Cat will reach working temperature faster, and the final temperature of it can be controlled better when encapsulated in a concentric TEC arrangement. It is also possible to regulate the temperature of the Cat and the TEC by controlling the electrical load of the TEC. The possible working temperatures of present and future Cats appear very suitable for the new low work function collector TEC, which has been demonstrated to work down to 470 K.

Svensson, R. [Chalmers Univ. of Technology, Goeteborg (Sweden); Holmlid, L. [Univ. of Goeteborg (Sweden). Dept. of Physical Chemistry

1996-12-31T23:59:59.000Z

460

System Study of Rich Catalytic/Lean burn (RCL) Catalytic Combustion for Natural Gas and Coal-Derived Syngas Combustion Turbines  

SciTech Connect

Rich Catalytic/Lean burn (RCL{reg_sign}) technology has been successfully developed to provide improvement in Dry Low Emission gas turbine technology for coal derived syngas and natural gas delivering near zero NOx emissions, improved efficiency, extending component lifetime and the ability to have fuel flexibility. The present report shows substantial net cost saving using RCL{reg_sign} technology as compared to other technologies both for new and retrofit applications, thus eliminating the need for Selective Catalytic Reduction (SCR) in combined or simple cycle for Integrated Gasification Combined Cycle (IGCC) and natural gas fired combustion turbines.

Shahrokh Etemad; Lance Smith; Kevin Burns

2004-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "determination catalytic transformation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Material transformation designing shape changing interfaces enabled by programmable material anisotropy  

E-Print Network (OSTI)

This thesis takes a material perspective on designing transformable interfaces. The structure of material and mechanical properties such as stiffness, can determine not only its static performances, but also, with the help ...

Ou, Jifei

2014-01-01T23:59:59.000Z

462

Investigation of Coal-biomass Catalytic Gasification using Experiments, Reaction Kinetics, and Computational Fluid Dynamics  

NLE Websites -- All DOE Office Websites (Extended Search)

Coal-biomass Catalytic Coal-biomass Catalytic Gasification using Experiments, Reaction Kinetics, and Computational Fluid Dynamics Background The U.S. Department of Energy (DOE) supports research and development efforts targeted to improve efficiency and reduce the negative environmental effects of the use of fossil fuels. One way to achieve these goals is to combine coal with biomass to create synthesis gas (syngas) for use in turbines and refineries to produce energy, fuels,

463

Effect of support on catalytic behavior of dispersed rhodium for hydrocarbon hydrogenolyses  

E-Print Network (OSTI)

EFFFCT OF SUPPORT ON CATALYTIC BEHAVIOR OF DISPERSED RHODIUM POR HYDROCARBON HYDROGENOLYSES A Thesis AMINA ARMED KHAL'lFA Submi I ted to the Graduate College of Texas AKM University in partial full illment of the requirement for the degree... of MASTER OF SCIENCE December 1986 Major Subject: Chemistry EFFECT OF SUPPORT ON CATALYTIC BEHAVIOR OF DISPERSED RHODIUM FOR HYDROCARBON HYDROGENOLYSES A Thesis by AMINA AHMED KHALIFA Approved as to style and content by: M. P. osynek (Chairman...

Khalifa, Amina Ahmed

2012-06-07T23:59:59.000Z

464

Facile Catalytic Combustion of Rice Husk and Burning Temperature Dependence of the Ashes  

Science Journals Connector (OSTI)

Facile Catalytic Combustion of Rice Husk and Burning Temperature Dependence of the Ashes ... However, these traditional applications are of low profits, and in many cases, RH is discarded as agricultural waste, which is mostly burned in open heaps (8). ... The utilization of a vibrofluidized bed of catalysts makes it possible to burn RH at decreased temperatures (10), but the millimetric catalyst particles are ill dispersed over the RH pieces, limiting the catalytic effect. ...

Liangming Xiong; Edson H. Sekiya; Shigetaka Wada; Kazuya Saito

2009-10-27T23:59:59.000Z

465

Lean Catalytic Combustion for Ultra-low Emissions at High Temperature in Gas-Turbine Burners  

Science Journals Connector (OSTI)

This illustrates the weak point of current catalytic combustion technology: the unavailability of catalytic systems stable at the temperature of the gas turbine inlet temperature. ... The possible feeds are methane, gaseous fuels, and gasified biomasses. ... In particular, the paper presents current development status and design challenges being addressed by Siemens Westinghouse Power Corp. for large industrial engines (>200 MW) and by Solar Turbines for smaller engines (Turbine Systems (ATS) program. ...

Fabrizio D’Alessandro; Giovanna Pacchiarotta; Alberto Rubino; Mauro Sperandio; Pierluigi Villa; Arturo Manrique Carrera; Reza Fakhrai; Gianluigi Marra; Annalisa Congiu

2010-12-16T23:59:59.000Z

466

Measurement and Modeling Implications of Transfer and Transformation  

NLE Websites -- All DOE Office Websites (Extended Search)

Measurement and Modeling Implications of Transfer and Transformation Measurement and Modeling Implications of Transfer and Transformation Processes at the Plant/Air Interface Speaker(s): Randy Maddalena Date: October 13, 1998 - 12:00pm Location: 90-3122 Seminar Host/Point of Contact: Richard Sextro To understand the chemodynamic role of vegetation in a multimedia system, the rate and extent of chemical partitioning from adjacent environmental media and the rate of chemical transformation associated with vegetation need to be determined. An exposure system was used to isolate and expose above ground vegetation to semi-volatile air contaminants. Measurements of phenanthrene, anthracene, fluoranthene and pyrene in the chamber air and the plant tissue were collected during both the uptake and clearance phase of exposure events. The measurements were fitted to the mass balance of the

467

Advances in model transformations by graph transformation: specification, execution and analysis  

Science Journals Connector (OSTI)

Model transformations are a core technology of today's model-driven software development processes. Graph transformations provide a state-of-the-art formalism to specify and execute such transformations in practice. This was the case in the SENSORIA ...

Gábor Bergmann; Artur Boronat; Reiko Heckel; Paolo Torrini; István Ráth; Dániel Varró

2011-01-01T23:59:59.000Z

468

Catalytic multi-stage process for hydroconversion and refining hydrocarbon feeds  

DOE Patents (OSTI)

A multi-stage catalytic hydrogenation and hydroconversion process for heavy hydrocarbon feed materials such as coal, heavy petroleum fractions, and plastic waste materials. In the process, the feedstock is reacted in a first-stage, back-mixed catalytic reactor with a highly dispersed iron-based catalyst having a powder, gel or liquid form. The reactor effluent is pressure-reduced, vapors and light distillate fractions are removed overhead, and the heavier liquid fraction is fed to a second stage back-mixed catalytic reactor. The first and second stage catalytic reactors are operated at 700-850.degree. F. temperature, 1000-3500 psig hydrogen partial pressure and 20-80 lb./hr per ft.sup.3 reactor space velocity. The vapor and light distillates liquid fractions removed from both the first and second stage reactor effluent streams are combined and passed to an in-line, fixed-bed catalytic hydrotreater for heteroatom removal and for producing high quality naphtha and mid-distillate or a full-range distillate product. The remaining separator bottoms liquid fractions are distilled at successive atmospheric and vacuum pressures, low and intermediate-boiling hydrocarbon liquid products are withdrawn, and heavier distillate fractions are recycled and further upgraded to provide additional low-boiling hydrocarbon liquid products. This catalytic multistage hydrogenation process provides improved flexibility for hydroprocessing the various carbonaceous feedstocks and adjusting to desired product structures and for improved economy of operations.

Comolli, Alfred G. (Yardley, PA); Lee, Lap-Keung (Cranbury, NJ)

2001-01-01T23:59:59.000Z

469

Coke gasification: the influence and behavior of inherent catalytic mineral matter  

SciTech Connect

Gasification of coke contributes to its degradation in the blast furnace. In this study, the effect of gasification on the inherent catalytic minerals in cokes and their reciprocal influence on gasification are investigated. The catalytic mineral phases identified in the cokes used in this study were metallic iron, iron sulfides, and iron oxides. Metallic iron and pyrrhotite were rapidly oxidized during gasification to iron oxide. The catalysts had a strong influence on the apparent rates at the initial stages of reaction. As gasification proceeds, their effect on the reaction rate diminishes as a result of reducing the surface contact between catalyst and carbon matrix because of carbon consumption around the catalyst particles; with extended burnout the reactivity of the coke becomes increasingly dependent on surface area. The reaction rate in the initial stages was also influenced by the particle size of the catalytic minerals; for a given catalytic iron level, the cokes whose catalytic minerals were more finely dispersed had a higher apparent reaction rate than cokes containing larger catalytic particles. Iron, sodium, and potassium in the amorphous phase did not appear to affect the reaction rate. 40 refs., 16 figs., 6 tabs.

Mihaela Grigore; Richard Sakurovs; David French; Veena Sahajwalla [Commonwealth Scientific and Industrial Research Organisation (CSIRO), Bangor, NSW (Australia)

2009-04-15T23:59:59.000Z

470

Test results of low NO[sub x] catalytic combustors for gas turbines  

SciTech Connect

Catalytic combustion is an ultralow NO[sub x] combustion method, so it is expected that this method will be applied to a gas turbine combustor, However, it is difficult to develop a catalytic combustor because catalytic reliability at high temperature is still insufficient. To overcome this difficulty, the authors designed a catalytic combustor in which premixed combustion was combined. By this device, it is possible to obtain combustion gas at a combustion temperature of 1,300 C while keeping the catalytic temperature below 1,000 C. After performing preliminary tests using LPG, the authors designed two types of combustor for natural gas with a capacity equivalent to one combustor used in a 20 MW class multican-type gas turbine. Combustion tests were conducted at atmospheric pressure using natural gas. As a result, it was confirmed that a combustor in which catalytic combustor segments were arranged alternately with premixing nozzles could achieve low NO[sub x] and high combustion efficiency in the range from 1,000 C to 1,300 C of the combustor exit gas temperature.

Ozawa, Y.; Hirano, J.; Sato, M. (Central Research Inst. of Electric Power Industry, Kanagawa (Japan)); Saiga, M.; Watanabe, S. (Kansai Electric Power Co., Inc., Hyogo (Japan))

1994-07-01T23:59:59.000Z

471

Influence of complexation processes on the catalytic properties of some polymer-based cobalt compounds for oxygen electroreduction  

SciTech Connect

Electrochemical and X-ray absorption techniques have been used to determine the influence of complexation processes on the catalytic properties of heat-treated systems composed by the mixture of one polymer and Co acetate. Three non-nitrogenous polymers were studied: poly(methyl vinyl ketone) (PVK), poly(acrylic acid) (PAA); and polystyrene (PE). The catalysts composed by PE and PAA presented very low activity for the O{sub 2} reduction; a maximum of activity was found for the PVK catalyst at 100{degree}C. XAFS experiments at the Co, N, C, and O K edges showed that complexation between Co ions and the polymer yields a good dispersion of the Co ions and formation of small Co clusters during the thermal treatment. The absence of complexation leads to very poor activity, as in the case of PE and PAA. 14 refs., 13 figs., 5 tabs.

Alves, M.C.M.; Tourillon, G. [LURE, Orsay (France)

1996-05-02T23:59:59.000Z

472

PILOT-SCALE EVALUATION OF THE IMPACT OF SELECTIVE CATALYTIC REDUCTION FOR NOx ON MERCURY SPECIATION  

SciTech Connect

Full-scale tests in Europe and bench-scale tests in the United States have indicated that the catalyst, normally vanadium/titanium metal oxide, used in the selective catalytic reduction (SCR) of NO{sub x}, may promote the formation of Hg{sup 2+} and/or particulate-bound mercury (Hg{sub p}). To investigate the impact of SCR on mercury speciation, pilot-scale screening tests were conducted at the Energy & Environmental Research Center. The primary research goal was to determine whether the catalyst or the injection of ammonia in a representative SCR system promotes the conversion of Hg{sup 0} to Hg{sup 2+} and/or Hg{sub p} and, if so, which coal types and parameters (e.g., rank and chemical composition) affect the degree of conversion. Four different coals, three eastern bituminous coals and a Powder River Basin (PRB) subbituminous coal, were tested. Three tests were conducted for each coal: (1) baseline, (2) NH{sub 3} injection, and (3) SCR of NO{sub x}. Speciated mercury, ammonia slip, SO{sub 3}, and chloride measurements were made to determine the effect the SCR reactor had on mercury speciation. It appears that the impact of SCR of NO{sub x} on mercury speciation is coal-dependent. Although there were several confounding factors such as temperature and ammonia concentrations in the flue gas, two of the eastern bituminous coals showed substantial increases in Hg{sub p} at the inlet to the ESP after passing through an SCR reactor. The PRB coal showed little if any change due to the presence of the SCR. Apparently, the effects of the SCR reactor are related to the chloride, sulfur and, possibly, the calcium content of the coal. It is clear that additional work needs to be done at the full-scale level.

Dennis L. Laudal; John H. Pavlish; Kevin C. Galbreath; Jeffrey S. Thompson; Gregory F. Weber; Everett Sondreal

2000-12-01T23:59:59.000Z

473

Nanopattering in CeOx/Cu(111): A New Type of Surface Reconstruction and Enhancement of Catalytic Activity  

SciTech Connect

Our results indicate that small amounts of an oxide deposited on a stable metal surface can trigger a massive surface reconstruction under reaction conditions. In low-energy electron microscopy (LEEM) experiments, no reconstruction of Cu(111) is observed after chemisorbing oxygen or after reducing O/Cu(111) in a CO atmosphere. On the other hand, LEEM images taken in situ during the reduction of CeO{sub 2}/CuO{sub 1-x}/Cu(111) show a complex nonuniform transformation of the surface morphology. Ceria particles act as nucleation sites for the growth of copper microterraces once CuO{sub 1-x} is reduced. Can this reconstructed surface be used to enhance the catalytic activity of inverse oxide/metal catalysts? Indeed, CeO{sub x} on reconstructed Cu(111) is an extremely active catalyst for the water-gas shift process (CO + H{sub 2}O {yields} H{sub 2} + CO{sub 2}), with the Cu microterraces providing very efficient sites for the dissociation of water and subsequent reaction with CO.

Rodriguez J. A.; Senanayake, S.D.; Sadowski, J.; Evans, J.; Kundu, S.; Agnoli, S.; Yang, F.; Stacchiola, D.; Flege, J.I.; Hrbek, J.

2012-04-05T23:59:59.000Z

474

Bubbling bed catalytic hydropyrolysis process utilizing larger catalyst particles and smaller biomass particles featuring an anti-slugging reactor  

SciTech Connect

This invention relates to a process for thermochemically transforming biomass or other oxygenated feedstocks into high quality liquid hydrocarbon fuels. In particular, a catalytic hydropyrolysis reactor, containing a deep bed of fluidized catalyst particles is utilized to accept particles of biomass or other oxygenated feedstocks that are significantly smaller than the particles of catalyst in the fluidized bed. The reactor features an insert or other structure disposed within the reactor vessel that inhibits slugging of the bed and thereby minimizes attrition of the catalyst. Within the bed, the biomass feedstock is converted into a vapor-phase product, containing hydrocarbon molecules and other process vapors, and an entrained solid char product, which is separated from the vapor stream after the vapor stream has been exhausted from the top of the reactor. When the product vapor stream is cooled to ambient temperatures, a significant proportion of the hydrocarbons in the product vapor stream can be recovered as a liquid stream of hydrophobic hydrocarbons, with properties consistent with those of gasoline, kerosene, and diesel fuel. Separate streams of gasoline, kerosene, and diesel fuel may also be obtained, either via selective condensation of each type of fuel, or via later distillation of the combined hydrocarbon liquid.

Marker, Terry L; Felix, Larry G; Linck, Martin B; Roberts, Michael J

2014-09-23T23:59:59.000Z

475

Continuous space-time transformations  

E-Print Network (OSTI)

We prove that every continuous map acting on the four-dimensional Minkowski space and preserving light cones in one direction only is either a Poincar\\'e similarity, that is, a product of a Lorentz transformation and a dilation, or it is of a very special degenerate form. In the presence of the continuity assumption the main tool in the proof is a basic result from the homotopy theory of spheres.

Clément de Seguins Pazzis; Peter Šemrl

2015-02-04T23:59:59.000Z

476

ADVANCED BYPRODUCT RECOVERY: DIRECT CATALYTIC REDUCTION OF SO2 TO ELEMENTAL SULFUR  

SciTech Connect

Arthur D. Little, Inc., together with its commercialization partner, Engelhard Corporation, and its university partner Tufts, investigated a single-step process for direct, catalytic reduction of sulfur dioxide from regenerable flue gas desulfurization processes to the more valuable elemental sulfur by-product. This development built on recently demonstrated SO{sub 2}-reduction catalyst performance at Tufts University on a DOE-sponsored program and is, in principle, applicable to processing of regenerator off-gases from all regenerable SO{sub 2}-control processes. In this program, laboratory-scale catalyst optimization work at Tufts was combined with supported catalyst formulation work at Engelhard, bench-scale supported catalyst testing at Arthur D. Little and market assessments, also by Arthur D. Little. Objectives included identification and performance evaluation of a catalyst which is robust and flexible with regard to choice of reducing gas. The catalyst formulation was improved significantly over the course of this work owing to the identification of a number of underlying phenomena that tended to reduce catalyst selectivity. The most promising catalysts discovered in the bench-scale tests at Tufts were transformed into monolith-supported catalysts at Engelhard. These catalyst samples were tested at larger scale at Arthur D. Little, where the laboratory-scale results were confirmed, namely that the catalysts do effectively reduce sulfur dioxide to elemental sulfur when operated under appropriate levels of conversion and in conditions that do not contain too much water or hydrogen. Ways to overcome those limitations were suggested by the laboratory results. Nonetheless, at the end of Phase I, the catalysts did not exhibit the very stringent levels of activity or selectivity that would have permitted ready scale-up to pilot or commercial operation. Therefore, we chose not to pursue Phase II of this work which would have included further bench-scale testing, scale-up, pilot-scale (0.5 MW{sub e}) testing at conditions representative of various regenerable SO{sub 2}-control systems, preparation of a commercial process design, and development of a utility-scale demonstration plan.

Robert S. Weber

1999-05-01T23:59:59.000Z

477

Integrating catalytic coal gasifiers with solid oxide fuel cells  

SciTech Connect

A review was conducted for coal gasification technologies that integrate with solid oxide fuel cells (SOFC) to achieve system efficiencies near 60% while capturing and sequestering >90% of the carbon dioxide [1-2]. The overall system efficiency can reach 60% when a) the coal gasifier produces a syngas with a methane composition of roughly 25% on a dry volume basis, b) the carbon dioxide is separated from the methane-rich synthesis gas, c) the methane-rich syngas is sent to a SOFC, and d) the off-gases from the SOFC are recycled back to coal gasifier. The thermodynamics of this process will be reviewed and compared to conventional processes in order to highlight where available work (i.e. exergy) is lost in entrained-flow, high-temperature gasification, and where exergy is lost in hydrogen oxidation within the SOFC. The main advantage of steam gasification of coal to methane and carbon dioxide is that the amount of exergy consumed in the gasifier is small compared to conventional, high temperature, oxygen-blown gasifiers. However, the goal of limiting the amount of exergy destruction in the gasifier has the effect of limiting the rates of chemical reactions. Thus, one of the main advantages of steam gasification leads to one of its main problems: slow reaction kinetics. While conventional entrained-flow, high-temperature gasifiers consume a sizable portion of the available work in the coal oxidation, the consumed exergy speeds up the rates of reactions. And while the rates of steam gasification reactions can be increased through the use of catalysts, only a few catalysts can meet cost requirements because there is often significant deactivation due to chemical reactions between the inorganic species in the coal and the catalyst. Previous research into increasing the kinetics of steam gasification will be reviewed. The goal of this paper is to highlight both the challenges and advantages of integrating catalytic coal gasifiers with SOFCs.

Siefert, N.; Shamsi, A.; Shekhawat, D.; Berry, D.

2010-01-01T23:59:59.000Z

478

Transforms for prediction residuals in video coding  

E-Print Network (OSTI)

Typically the same transform, the 2-D Discrete Cosine Transform (DCT), is used to compress both image intensities in image coding and prediction residuals in video coding. Major prediction residuals include the motion ...

Kam??l?, Fatih

2010-01-01T23:59:59.000Z

479

Measure Transformer Semantics for Bayesian Machine Learning  

E-Print Network (OSTI)

Measure Transformer Semantics for Bayesian Machine Learning Johannes Borgstr¨om1, Andrew D. Gordon1 define combinators for measure transformers, based on theorems in measure theory, and use these to give

Plotkin, Joshua B.

480

Biolistic transformation of a procaryote, Bacillus megaterium.  

Science Journals Connector (OSTI)

...gunpowder-driven sys- tem. Particle accelerator conditions were optimized for...lid removed), and a partial vacuum was drawn (29 in. [ca...technology (28). Also, nuclear transformation ; f eucaryotic...Johnston. 1990. Biolistic nuclear transformation of Saccharomyces...

K B Shark; F D Smith; P R Harpending; J L Rasmussen; J C Sanford

1991-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "determination catalytic transformation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Repair-dependent cell radiation survival and transformation: an integrated theory  

Science Journals Connector (OSTI)

The repair-dependent model of cell radiation survival is extended to include radiation-induced transformations. The probability of transformation is presumed to scale with the number of potentially lethal damages that are repaired in a surviving cell or the interactions of such damages. The theory predicts that at doses corresponding to high survival, the transformation frequency is the sum of simple polynomial functions of dose; linear, quadratic, etc, essentially as described in widely used linear-quadratic expressions. At high doses, corresponding to low survival, the ratio of transformed to surviving cells asymptotically approaches an upper limit. The low dose fundamental- and high dose plateau domains are separated by a downwardly concave transition region. Published transformation data for mammalian cells show the high-dose plateaus predicted by the repair-dependent model for both ultraviolet and ionizing radiation. For the neoplastic transformation experiments that were analyzed, the data can be fit with only the repair-dependent quadratic function. At low doses, the transformation frequency is strictly quadratic, but becomes sigmodial over a wider range of doses. Inclusion of data from the transition region in a traditional linear-quadratic analysis of neoplastic transformation frequency data can exaggerate the magnitude of, or create the appearance of, a linear component. Quantitative analysis of survival and transformation data shows good agreement for ultraviolet radiation; the shapes of the transformation components can be predicted from survival data. For ionizing radiations, both neutrons and x-rays, survival data overestimate the transforming ability for low to moderate doses. The presumed cause of this difference is that, unlike UV photons, a single x-ray or neutron may generate more than one lethal damage in a cell, so the distribution of such damages in the population is not accurately described by Poisson statistics. However, the complete sigmodial dose-response data for neoplastic transformations can be fit using the repair-dependent functions with all parameters determined only from transformation frequency data.

John C Sutherland

2014-01-01T23:59:59.000Z

482

Model-to-model transformations by demonstration  

Science Journals Connector (OSTI)

During the last decade several approaches have been proposed for easing the burden of writing model transformation rules manually. Among them are Model Transformation By-Demonstration (MTBD) approaches which record actions performed on example models ... Keywords: by-demonstration, by-example, model transformations

Philip Langer; Manuel Wimmer; Gerti Kappel

2010-06-01T23:59:59.000Z

483

Study on life management of power transformer  

Science Journals Connector (OSTI)

This paper presents the general knowledge, theory and methodology of life management that used in electric power transformer. The paper also discusses the basic failure theory and method to establish failure model of power transformer. Insulation ageing ... Keywords: fuzzy logic, life management, neural networks, power transformer, reliability, rough set theory

Zhang Weizheng; Li Yanming; Yang Lanjun; Wang Zhenggang; Zhang Jinguang; Hu Bo; Kuang Shi

2006-04-01T23:59:59.000Z

484

Accelerating the transformation of power systems  

E-Print Network (OSTI)

Accelerating the transformation of power systems Ancillary Services Peer Exchange with India- to-peer consultation. The 21st Century Power Partnership aims to accelerate the global transformation consultative support Accelerating the transformation of power systems NREL/FS-6A20-61811 · May 2014 15013

485

The TRANSFORMATION OF CONFLICTS AMONG ETHIOPIAN PASTORALISTS  

E-Print Network (OSTI)

The TRANSFORMATION OF CONFLICTS AMONG ETHIOPIAN PASTORALISTS: Ethnography of the Notion of Conflict This PhD thesis is concerned with studying the conceptualization, performance and transformation in their nature and have not yet achieved full transformation to peace. The research supports the notion

Richner, Heinz

486

Transforming and Refining Abstract Constraint Specifications  

E-Print Network (OSTI)

Transforming and Refining Abstract Constraint Specifications Alan M. Frisch1 , Brahim Hnich2 , Ian choose model transformations to reduce greatly the amount of effort that is required to solve a problem by systematic search. It is a consid- erable challenge to automate such transformations. A problem may be viewed

Walsh, Toby

487

LAPPED TRANSFORMS Ricardo L. de Queiroz  

E-Print Network (OSTI)

LAPPED TRANSFORMS Ricardo L. de Queiroz Advanced Color Imaging Xerox Corporation queiroz@wrc.xerox.com 0.1 Introduction The idea of a lapped transform (LT, for short) maintaining orthogonality and non with the blocking artifacts so common in traditional block transform coding of images. The idea was to extend

de Queiroz, Ricardo L.

488

Quantum arithmetic with the Quantum Fourier Transform  

E-Print Network (OSTI)

The Quantum Fourier Transform offers an interesting way to perform arithmetic operations on a quantum computer. We review existing Quantum Fourier Transform adders and multipliers and propose some modifications that extend their capabilities. Among the new circuits, we propose a quantum method to compute the weighted average of a series of inputs in the transform domain.

Lidia Ruiz-Perez; Juan Carlos Garcia-Escartin

2014-11-21T23:59:59.000Z

489

Non-Hermitian Hamiltonians and similarity transformations  

E-Print Network (OSTI)

We show that a straightforward similarity transformation between an Hermitian operator and a non-Hermitian one enables one to prove the results obtained by other authors by means of a gauge-like transformation. The similarity transformation also reveals the connection with pseudo-Hermiticity

Francisco M. Fernández

2015-02-04T23:59:59.000Z

490

YANGMILLS THEORY AND THE SEGALBARGMANN TRANSFORM  

E-Print Network (OSTI)

YANG­MILLS THEORY AND THE SEGAL­BARGMANN TRANSFORM BRIAN C. HALL Abstract. Motivated by the results cylinder, with the goal of obtaining an appropriate Segal­Bargmann transform. Using a Gaussian mea­ sure a variant of the classical Segal­Bargmann transform. A simple but non­rigorous argument shows

491

Metal nanoparticles in catalytic polymer membranes and ion-exchange systems for advanced purification of water from molecular oxygen  

Science Journals Connector (OSTI)

Methods of synthesis of metal nanoparticles and metal/polymer nanocomposites including ion-exchange materials are considered. The effect of the composition and size of nanoparticles on their catalytic activity is analyzed. Attention is focused on the composites used in catalytic processes, namely, catalytic membranes and ion-exchange systems. The problems associated with the removal of dissolved oxygen from water by means of such composites are discussed. The bibliography includes 225 references.

V V Volkov; T A Kravchenko; Vyacheslav I Roldughin

2013-01-01T23:59:59.000Z

492

Feasibility of SF6 Gas-Insulated Transformers  

NLE Websites -- All DOE Office Websites (Extended Search)

Design Center 14 June 2012 BUILDING STRONG PORTLAND DISTRICT 2 Outline Transformer Background & Basics Oil-filled transformers Oil-filled transformer concerns...

493

Cauchy transforms of measures viewed as some functionals of Fourier transforms  

E-Print Network (OSTI)

Cauchy transforms of measures viewed as some functionals of Fourier transforms Zbigniew J. Jurek Urbanik ABSTRACT. The Cauchy transform of a positive measure plays an impor- tant role in complex analysis and more recently in so-called free probability. We show here that the Cauchy transform restricted

Jurek, Zbigniew J.

494

Cauchy transforms of measures viewed as some functionals of Fourier transforms #  

E-Print Network (OSTI)

Cauchy transforms of measures viewed as some functionals of Fourier transforms # Zbigniew J. Jurek Urbanik ABSTRACT. The Cauchy transform of a positive measure plays an impor­ tant role in complex analysis and more recently in so­called free probability. We show here that the Cauchy transform restricted

Jurek, Zbigniew J.

495

Learning transformation rules from transformation examples: An approach based on Relational Concept Analysis  

E-Print Network (OSTI)

Learning transformation rules from transformation examples: An approach based on Relational Concept), model transformations are basic and primordial entities, thus easing their design and implementation is an important issue. A quite recently proposed way to create model transformations consists in deducing

Paris-Sud XI, Université de

496

Chemical Fixation of Carbon Dioxide Using a Green and Efficient Catalytic System Based on Sugarcane Bagasse—An Agricultural Waste  

Science Journals Connector (OSTI)

Chemical Fixation of Carbon Dioxide Using a Green and Efficient Catalytic System Based on Sugarcane Bagasse—An Agricultural Waste ... § Wisconsin

Wei Chen; Lin-xin Zhong; Xin-wen Peng; Run-cang Sun; Fa-chuang Lu

2014-11-17T23:59:59.000Z

497

Catalytic ozonation of azo dye active brilliant red X-3B in water with natural mineral brucite  

Science Journals Connector (OSTI)

Natural mineral brucite was used directly in catalytic ozonation of dye wastewater of active brilliant red X-3B. Compared with single ozonation, degradation of X-3B increased from 47% to 89%, and removal rate of COD increased from 9% to 32.5% in catalytic ozonation for 15 min. The catalytic ozonation of X-3B followed a direct oxidization mechanism by ozone molecule, and this was actually a homogeneous catalysis of OH? due to dissolution of Mg(OH)2 from natural brucite. As a natural mineral catalyst, brucite has supplied an economical and feasible choice for catalytic ozonation of X-3B in industrial wastewater.

Yuming Dong; Kun He; Bo Zhao; Ying Yin; Lin Yin; Aimin Zhang

2007-01-01T23:59:59.000Z

498

Superior catalysts for selective catalytic reduction of nitric oxide. Quarterly technical progress report, April 1, 1995--June 30, 1995  

SciTech Connect

Efforts continued towards the synthesis of new pillared clay catalysts for the selective catalytic reduction of nitric oxide by ammonia. The possibility of utilizing hydrocarbons was also investigated.

Li, W.B.; Yang, R.T.

1995-12-01T23:59:59.000Z

499

Effect of K and Ca on catalytic activity of Mn-CeO x /Ti-PILC  

Science Journals Connector (OSTI)

Mn-CeO x /Ti-pillared clay (PILC) is an attractive catalyst for selective catalytic... x at low temperature because of its low cost. The poison...

Boxiong Shen; Lidan Deng; Jianhong Chen

2013-08-01T23:59:59.000Z

500

Hydrodesulfurization of Fluid Catalytic Cracking Decant Oils for the Production of Low-sulfur Needle Coke Feedstocks.  

E-Print Network (OSTI)

??Needle coke, produced by the delayed coking of fluid catalytic cracking decant oils, is the primary filler used in the production of graphite electrodes. The… (more)

Wincek, Ronald

2013-01-01T23:59:59.000Z