Sample records for determination catalytic transformation

  1. Determination analysis of energy conservation standards for distribution transformers

    SciTech Connect (OSTI)

    Barnes, P.R.; Van Dyke, J.W.; McConnell, B.W.; Das, S.

    1996-07-01T23:59:59.000Z

    This report contains information for US DOE to use in making a determination on proposing energy conservation standards for distribution transformers as required by the Energy Policy Act of 1992. Potential for saving energy with more efficient liquid-immersed and dry-type distribution transformers could be significant because these transformers account for an estimated 140 billion kWh of the annual energy lost in the delivery of electricity. Objective was to determine whether energy conservation standards for distribution transformers would have the potential for significant energy savings, be technically feasible, and be economically justified from a national perspective. It was found that energy conservation for distribution transformers would be technically and economically feasible. Based on the energy conservation options analyzed, 3.6-13.7 quads of energy could be saved from 2000 to 2030.

  2. Principles of water oxidation and O2-based hydrocarbon transformation by multinuclear catalytic sites

    SciTech Connect (OSTI)

    Musaev, Djamaladdin G [Chemistry, Emory University; Hill, Craig L [Chemistry, Emory University; Morokuma, Keiji [Chemistry, Emory University

    2014-10-28T23:59:59.000Z

    Abstract The central thrust of this integrated experimental and computational research program was to obtain an atomistic-level understanding of the structural and dynamic factors underlying the design of catalysts for water oxidation and selective reductant-free O2-based transformations. The focus was on oxidatively robust polyoxometalate (POM) complexes in which a catalytic active site interacts with proximal metal centers in a synergistic manner. Thirty five publications in high-impact journals arose from this grant. I. Developing an oxidatively and hydrolytically stable and fast water oxidation catalyst (WOC), a central need in the production of green fuels using water as a reductant, has proven particularly challenging. During this grant period we have designed and investigated several carbon-free, molecular (homogenous), oxidatively and hydrolytically stable WOCs, including the Rb8K2[{Ru4O4(OH)2(H2O)4}(?-SiW10O36)2]∑25H2O (1) and [Co4(H2O)2(?-PW9O34)2]10- (2). Although complex 1 is fast, oxidatively and hydrolytically stable WOC, Ru is neither abundant nor inexpensive. Therefore, development of a stable and fast carbon-free homogenous WOC, based on earth-abundant elements became our highest priority. In 2010, we reported the first such catalyst, complex 2. This complex is substantially faster than 1 and stable under homogeneous conditions. Recently, we have extended our efforts and reported a V2-analog of the complex 2, i.e. [Co4(H2O)2(?-VW9O34)2]10- (3), which shows an even greater stability and reactivity. We succeeded in: (a) immobilizing catalysts 1 and 2 on the surface of various electrodes, and (b) elucidating the mechanism of O2 formation and release from complex 1, as well as the Mn4O4L6 ďcubaneĒ cluster. We have shown that the direct O-O bond formation is the most likely pathway for O2 formation during water oxidation catalyzed by 1. II. Oxo transfer catalysts that contain two proximal and synergistically interacting redox active metal centers in the active site form another part of considerable interest of our grant because species with such sites [including methane monooxygenase (MMO) and more] are some of the most effective oxygenase catalysts known. Our team conducted the following research on ?-M2-Keggin complexes: (a) investigated stability of the trimer [{Fe3(OH)3(H2O)2}3(?-SiW10O36)3]15-, 4, in water, and developed the chemistry and catalysis of the di-iron centered POM, [?(1,2)-SiW10{Fe(OH)}2O38]6-, 5, in organic solvents (Figure 2). We also study the thermodynamic and structural stability of ?-M2-Keggin in aqueous media for different Mís (d-electron metals). We have defined two structural classes of POMs with proximally bound d-electron metal centers. We refer to these structural isomers of the {?-M2SiW10} family of POMs as ďin-pocketĒ and ďout-of pocketĒ. We have elucidated the factors controlling the structure and stability of the V, Fe, Ru, Tc, Mo and Rh derivatives of [(SiO4)M2(OH)2W10O32]4- using a range of computational tools. We have: (a) demonstrated that heteroatom X in these polyanions may function as an ďinternal switchĒ for defining the ground electronic states and, consequently, the reactivity of the ?-M2-Keggin POM complexes; (b) elucidated reactivity of divacant lacunary species and polyperoxotungstates (PPTs), {Xn+O4[WO(O2)2]4}n-, which could be degradation products of ?-M2-Keggin complexes in aqueous media; (c) elucidated the role of the POM ligand in stabilization of {Ru2} and {(Ru-oxo)2} fragments in the reactant and product of the reaction of {?-[(Xn+O4)Ru2(OH)2W10O32]}(8-n)- (where X = Si4+, P5+ and S6+) with O2, and (d) the mechanisms of olefin epoxidation catalyzed by these di-d-transition metal substituted and divacant lacunary ?-M2-Keggin complexes. III. Complementing the efforts presented above was the development of less time-consuming but reasonably accurate computational methods allowing one to explore more deeply large catalytic systems. We developed Reactive Force Field (ReaxFF) to study interaction of the targeted POMs with water, pro

  3. Experimental Investigation in Order to Determine Catalytic Package Performances in Case of Tritium Transfer from Water to Gas

    SciTech Connect (OSTI)

    Bornea, Anisia [National Institute of R and D for Cryogenics and Isotopic Separations (Romania); Peculea, M. [Romanian Academy (Romania); Zamfirache, M. [National Institute of R and D for Cryogenics and Isotopic Separations (Romania); Varlam, Carmen [National Institute of R and D for Cryogenics and Isotopic Separations (Romania)

    2005-07-15T23:59:59.000Z

    The processes for hydrogen isotope's separation are very important for nuclear technology. One of the most important processes for tritium separation, is the catalyst isotope exchange water-hydrogen.Our catalytic package consists of Romanian patented catalysts with platinum on charcoal and polytetrafluoretylene (Pt/C/PTFE) and the ordered Romanian patented package B7 type. The catalytic package was tested in an isotope exchange facility for water detritiation at the Experimental Pilot Plant from ICIT Rm.Valcea.In a column of isotope exchange tritium is transferred from liquid phase (tritiated heavy water) in gaseous phase (hydrogen). In the experimental set-up, which was used, the column of catalytic isotope exchange is filled with successive layers of catalyst and ordered package. The catalyst consists of 95.5 wt.% of PTFE, 4.1 wt. % of carbon and 0.40 wt. % of platinum and was of Raschig rings 10 x 10 x 2 mm. The ordered package was B7 type consists of wire mesh phosphor bronze 4 x 1 wire and the mesh dimension is 0.18 x 0.48 mm.We analyzed the transfer phenomena of tritium from liquid to gaseous phase, in this system.The mass transfer coefficient which characterized the isotopic exchange on the package, were determined as function of experimental parameters.

  4. Shear Transformation Zones: State Determined or Protocol Dependent?

    E-Print Network [OSTI]

    Oleg Gendelman; Prabhat K. Jaiswal; Itamar Procaccia; Bhaskar Sen Gupta; Jacques Zylberg

    2014-08-18T23:59:59.000Z

    The concept of a Shear Transformation Zone (STZ) refers to a region in an amorphous solid that undergoes a plastic event when the material is put under an external mechanical load. An important question that had accompanied the development of the theory of plasticity in amorphous solids for many years now is whether an STZ is a {\\em region} existing in the material (which can be predicted by analyzing the unloaded material), or is it an {\\em event} that depends on the loading protocol (i.e., the event cannot be predicted without following the protocol itself). In this Letter we present strong evidence that the latter is the case. Infinitesimal changes of protocol result in macroscopically big jumps in the positions of plastic events, meaning that these can never be predicted from considering the unloaded material.

  5. Determination of the number of catalytic sites for ethylene-octene copolymers made with heterogeneous catalyst via interpretation of ?p13?sC NMR sequence distribution

    E-Print Network [OSTI]

    Moldovan, Daniel Gene

    1990-01-01T23:59:59.000Z

    DETERMINATION OF THE NUMBER OF CATALYTIC SITES FOR ETHYLENE-OCTENE COPOLYMERS MADE WITH HETEROGENEOUS CATALYST VIA INTERPRETATION OF C NMR SEQUENCE DISTRIBUTION A Thesis by DANIEL GENE MOLDOVAN Submitted to the Office of Graduate Studies... VIA INTERPRETATION OF C NMR SEQUENCE DISTRIBUTION A Thesis by DANIEL GENE MOLDOVAN Approved as to style and content by: C. A. J. oeve (Chair of t e committee) E. A. Meyers (Member) E. T. Ad m" (Member) J. S. Ham (Member) M. B. Hall (Head...

  6. Supplement to the ``determination analysis`` (ORNL-6847) and analysis of the NEMA efficiency standard for distribution transformers

    SciTech Connect (OSTI)

    Barnes, P.R.; Das, S.; McConnell, B.W.; Van Dyke, J.W.

    1997-09-01T23:59:59.000Z

    This report contains additional information for use by the US Department of Energy in making a determination on proposing energy conservation standards for distribution transformers as required by the Energy Policy Act of 1992. An earlier determination study by the Oak Ridge National Laboratory determined that cost-effective, technically feasible energy savings could be achieved by distribution transformer standards and that these savings are significant relative to other product conservation standards. This study was documented in a final report, ``Determination Analysis of Energy Conservation Standards for Distribution Transformers`` (ORNL-6847, July 1996). The energy conservation options analyzed in this study were estimated to save 5.2 to 13.7 quads from 2000--2030. The energy savings for the determination study cases have been revised downward for a number of reasons. The transformer market, both present and future, was overestimated in the previous study, particularly for dry-type transformers, which have the greatest energy-saving potential. Moreover, a revision downwards of the effective annual loads for utility owned transformers also results in lower energy savings. The present study assesses four of the five conservation cases from the earlier determination study as well as the National Electrical Manufacturers Association energy efficiency standard NEMA TP 1-1996 using the updated data and a more accurate disaggregated analysis model. According to these new estimates, the savings ranged from 2.5 to 10.7 quads of primary energy for the 30-year period 2004 to 2034. For the TP-1 case, data were available to calculate the payback period required to recover the extra cost from the value of the energy saved. The average payback period based on the average national cost of electricity is 2.76 years. 15 figs., 23 tabs.

  7. CATALYTIC BIOMASS LIQUEFACTION

    E-Print Network [OSTI]

    Ergun, Sabri

    2013-01-01T23:59:59.000Z

    LBL-11 019 UC-61 CATALYTIC BIOMASS LIQUEFACTION Sabri Ergun,Catalytic Liquefaction of Biomass,n M, Seth, R. Djafar, G.of California. CATALYTIC BIOMASS LIQUEFACTION QUARTERLY

  8. Catalytic reactor

    DOE Patents [OSTI]

    Aaron, Timothy Mark (East Amherst, NY); Shah, Minish Mahendra (East Amherst, NY); Jibb, Richard John (Amherst, NY)

    2009-03-10T23:59:59.000Z

    A catalytic reactor is provided with one or more reaction zones each formed of set(s) of reaction tubes containing a catalyst to promote chemical reaction within a feed stream. The reaction tubes are of helical configuration and are arranged in a substantially coaxial relationship to form a coil-like structure. Heat exchangers and steam generators can be formed by similar tube arrangements. In such manner, the reaction zone(s) and hence, the reactor is compact and the pressure drop through components is minimized. The resultant compact form has improved heat transfer characteristics and is far easier to thermally insulate than prior art compact reactor designs. Various chemical reactions are contemplated within such coil-like structures such that as steam methane reforming followed by water-gas shift. The coil-like structures can be housed within annular chambers of a cylindrical housing that also provide flow paths for various heat exchange fluids to heat and cool components.

  9. Catalytic Coherence

    E-Print Network [OSTI]

    Johan Aberg

    2014-10-20T23:59:59.000Z

    Due to conservation of energy we cannot directly turn a quantum system with a definite energy into a superposition of different energies. However, if we have access to an additional resource in terms of a system with a high degree of coherence, as for standard models of laser light, we can overcome this limitation. The question is to what extent coherence gets degraded when utilized. Here it is shown that coherence can be turned into a catalyst, meaning that we can use it repeatedly without ever diminishing its power to enable coherent operations. This finding stands in contrast to the degradation of other quantum resources, and has direct consequences for quantum thermodynamics, as it shows that latent energy that may be locked into superpositions of energy eigenstates can be released catalytically.

  10. Methods for preparation of catalytic materials

    SciTech Connect (OSTI)

    Schwarz, J.A. [Syracuse Univ., NY (United States). Dept. of Chemical Engineering and Materials Science; Contescu, C.; Contescu, A. [Romanian Academy, Bucharest (Romania). Inst. of Physical Chemistry

    1995-05-01T23:59:59.000Z

    To establish guidelines for the development of a scientific basis for catalyst preparation is perhaps a very ambitious goal. One would re required first to answer the following rhetorical questions: what are the properties which determine the performance of a catalytic material; how can these properties be introduced, developed, and/or improved during preparation? The answer to these questions involves a comprehensive discussion of the theories of catalysis, which is beyond the scope of this review. The authors will attempt, instead, to provide a rationale for each reader to answer these questions on the basis of his/her own interests. They start the discussion by describing the fundamental steps in producing bulk catalysts and/or catalyst supports. The fundamental processes involved are those derived from traditional three-dimensional chemistry. The topic areas will include single-component and multicomponent metal oxides. Unsupported metallic catalysts are formed by transformations involving physical or chemical processes, and the preparation methods for this class of materials will be discussed next. Attention will then turn to the preparation of supported catalytic materials. The main topics to be discussed will be those related to the interaction between the support and the active phase when they are put together to generate the catalyst. In this approach, the authors exploit the virtually unexplored field of surface, or two-dimensional, physical chemistry. The materials considered include dispersed metals and alloys and composite oxides. 366 refs.

  11. CATALYTIC LIQUEFACTION OF BIOMASS

    E-Print Network [OSTI]

    Seth, Manu

    2012-01-01T23:59:59.000Z

    liquid Fuels from Biomass: "Catalyst Screening and KineticUC-61 (l, RCO osn CDL or BIOMASS CATALYTIC LIQUEFACTION ManuCATALYTIC LIQUEFACTION OF BIOMASS Manu Seth, Roger Djafar,

  12. CATALYTIC BIOMASS LIQUEFACTION

    E-Print Network [OSTI]

    Ergun, Sabri

    2013-01-01T23:59:59.000Z

    Solvent Systems Catalystic Biomass Liquefaction Investigatereactor Product collection Biomass liquefaction process12-13, 1980 CATALYTIC BIOMASS LIQUEFACTION Sabri Ergun,

  13. CLEAN CAST STEEL TECHNOLOGY: DETERMINATION OF TRANSFORMATION DIAGRAMS FOR DUPLEX STAINLESS STEEL.

    SciTech Connect (OSTI)

    Chumbley. L., S.

    2005-09-18T23:59:59.000Z

    Duplex stainless steels (DSS) constitute both ferrite and austenite as a matrix. Such a microstructure confers a high corrosion resistance with favorable mechanical properties. However, intermetallic phases such as sigma (√?¬?√?¬?√?¬?√?¬?√?¬?√?¬?√?¬?√?¬Į√?¬?√?¬?√?¬?√?¬?√?¬?√?¬?√?¬?√?¬Ā√?¬?√?¬?√?¬?√?¬?√?¬?√?¬?√?¬?√?¬≥) and chi (√?¬?√?¬?√?¬?√?¬?√?¬?√?¬?√?¬?√?¬Į√?¬?√?¬?√?¬?√?¬?√?¬?√?¬?√?¬?√?¬Ā√?¬?√?¬?√?¬?√?¬?√?¬?√?¬?√?¬?√?¬£) can also form during casting or high-temperature processing and can degrade the properties of the DSS. This research was initiated to develop time-temperature-transformation (TTT) and continuous-cooling- transformation (CCT) diagrams of two types of cast duplex stainless steels, CD3MN (Fe 22Cr-5Ni-Mo-N) and CD3MWCuN (Fe-25Cr-7Ni-Mo-W-Cu-N), in order to understand the time and temperature ranges for intermetallic phase formation. The alloys were heat treated isothermally or under controlled cooling conditions and then characterized using conventional metallographic methods that included tint etching, and also using electron microscopy (SEM, TEM) and wavelength dispersive spectroscopy (WDS). The kinetics of intermetallic-phase (√?¬?√?¬?√?¬?√?¬?√?¬?√?¬?√?¬?√?¬Į√?¬?√?¬?√?¬?√?¬?√?¬?√?¬?√?¬?√?¬Ā√?¬?√?¬?√?¬?√?¬?√?¬?√?¬?√?¬?√?¬≥ + √?¬?√?¬?√?¬?√?¬?√?¬?√?¬?√?¬?√?¬Į√?¬?√?¬?√?¬?√?¬?√?¬?√?¬?√?¬?√?¬Ā√?¬?√?¬?√?¬?√?¬?√?¬?√?¬?√?¬?√?¬£) formation were analyzed using the Johnson-Mehl-Avrami (JMA) equation in the case of isothermal transformations and a modified form of this equation in the case of continuous cooling transformations, The rate of intermetallic-phase formation was found to be much faster in CD3MWCuN than CD3MN due mainly to differences in the major alloying contents such as Cr, Ni and Mo. To examine in more detail the effects of these elements of the phase stabilities, a series of eight steel castings was designed with the Cr, Ni and Mo contents systematically varied with respect to the nominal composition of CD3MN. The effects of varying the contents of alloying additions on the formation of intermetallic phases were also studied computationally using the commercial thermodynamic software package, Thermo-Calc. In general, √?¬?√?¬?√?¬?√?¬?√?¬?√?¬?√?¬?√?¬Į√?¬?√?¬?√?¬?√?¬?√?¬?√?¬?√?¬?√?¬Ā√?¬?√?¬?√?¬?√?¬?√?¬?√?¬?√?¬?√?¬≥ was stabilized with increasing Cr addition and by increasing Mo addition. However, a delicate balance among Ni and other minor elements such as N and Si also exists. Phase equilibria in DSS can be affected by local composition fluctuations in the cast alloy. This may cause discrepancy between thermodynamic prediction and experimental observation.

  14. Rich catalytic injection

    DOE Patents [OSTI]

    Veninger, Albert (Coventry, CT)

    2008-12-30T23:59:59.000Z

    A gas turbine engine includes a compressor, a rich catalytic injector, a combustor, and a turbine. The rich catalytic injector includes a rich catalytic device, a mixing zone, and an injection assembly. The injection assembly provides an interface between the mixing zone and the combustor. The injection assembly can inject diffusion fuel into the combustor, provides flame aerodynamic stabilization in the combustor, and may include an ignition device.

  15. Catalytic nanoporous membranes

    DOE Patents [OSTI]

    Pellin, Michael J; Hryn, John N; Elam, Jeffrey W

    2013-08-27T23:59:59.000Z

    A nanoporous catalytic membrane which displays several unique features Including pores which can go through the entire thickness of the membrane. The membrane has a higher catalytic and product selectivity than conventional catalysts. Anodic aluminum oxide (AAO) membranes serve as the catalyst substrate. This substrate is then subjected to Atomic Layer Deposition (ALD), which allows the controlled narrowing of the pores from 40 nm to 10 nm in the substrate by deposition of a preparatory material. Subsequent deposition of a catalytic layer on the inner surfaces of the pores reduces pore sizes to less than 10 nm and allows for a higher degree of reaction selectivity. The small pore sizes allow control over which molecules enter the pores, and the flow-through feature can allow for partial oxidation of reactant species as opposed to complete oxidation. A nanoporous separation membrane, produced by ALD is also provided for use in gaseous and liquid separations. The membrane has a high flow rate of material with 100% selectivity. Also provided is a method for producing a catalytic membrane having flow-through pores and discreet catalytic clusters adhering to the inside surfaces of the pores.

  16. Steam reformer with catalytic combustor

    DOE Patents [OSTI]

    Voecks, Gerald E. (La Crescenta, CA)

    1990-03-20T23:59:59.000Z

    A steam reformer is disclosed having an annular steam reforming catalyst bed formed by concentric cylinders and having a catalytic combustor located at the center of the innermost cylinder. Fuel is fed into the interior of the catalytic combustor and air is directed at the top of the combustor, creating a catalytic reaction which provides sufficient heat so as to maintain the catalytic reaction in the steam reforming catalyst bed. Alternatively, air is fed into the interior of the catalytic combustor and a fuel mixture is directed at the top. The catalytic combustor provides enhanced radiant and convective heat transfer to the reformer catalyst bed.

  17. Study of catalytic diffusion in coal. Final report for 1983/1984 SOMED Project. [Determination of pore (hole) size and pore shape distribution

    SciTech Connect (OSTI)

    Kispert, L.D.

    1984-09-01T23:59:59.000Z

    The purpose of our studies is to determine the pore (hole) size and pore shape distribution in standard bituminous coal samples from various Alabama coal seams such as that of the Mary Lee, Black Creek and Pratt during and after swelling of the coal with different solvents at various temperatures. These samples come from the Penn State Coal Sample Bank at Pennsylvania State University Coal Research Section and from Alabama's Mineral Industries. Methods have been developed in the laboratory whereby free radical probes of varying sizes can be diffused into the coal under various conditions. These probes can be detected and the environment surrounding the probes can be deduced by electron paramagnetic resonance (EPR) methods. To date, we have found that not only can the shape and size of the pores be determined, but that the size distribution varies from one bituminous coal seam to another, even for coal of the same rank, suggesting a different optimal catalyst should be used for each seam. The effect of oxygen on the coal samples during grinding has been studied; however, the free radical technique appears to be insensitive to the presence of oxygen effects. It is our goal to determine the structural differences between various bituminous coals. 9 references, 9 figures, 1 table.

  18. Transform Analysis Using the definition of the Laplace transform, Laplace transform properties, and the integral

    E-Print Network [OSTI]

    Landers, Robert G.

    Transform Analysis QUESTION 1 Using the definition of the Laplace transform, Laplace transform properties, and the integral tables on the course website, determine the Laplace transforms of the functions - = (3) QUESTION 2 Determine the inverse Laplace transform for the functions in equations (1)­(4). ( ) 3

  19. Catalytic coal liquefaction process

    DOE Patents [OSTI]

    Garg, D.; Sunder, S.

    1986-12-02T23:59:59.000Z

    An improved process for catalytic solvent refining or hydroliquefaction of non-anthracitic coal at elevated temperatures under hydrogen pressure in a solvent comprises using as catalyst a mixture of a 1,2- or 1,4-quinone and an alkaline compound, selected from ammonium, alkali metal, and alkaline earth metal oxides, hydroxides or salts of weak acids. 1 fig.

  20. Catalytic coal liquefaction process

    DOE Patents [OSTI]

    Garg, Diwakar (Macungie, PA); Sunder, Swaminathan (Allentown, PA)

    1986-01-01T23:59:59.000Z

    An improved process for catalytic solvent refining or hydroliquefaction of non-anthracitic coal at elevated temperatures under hydrogen pressure in a solvent comprises using as catalyst a mixture of a 1,2- or 1,4-quinone and an alkaline compound, selected from ammonium, alkali metal, and alkaline earth metal oxides, hydroxides or salts of weak acids.

  1. A Photosynthetic Hydrogel for Catalytic Hydrogen Production ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Photosynthetic Hydrogel for Catalytic Hydrogen Production Home > Research > ANSER Research Highlights > A Photosynthetic Hydrogel for Catalytic Hydrogen Production...

  2. Effect of thermal treatment on coke reactivity and catalytic iron mineralogy

    SciTech Connect (OSTI)

    Byong-chul Kim; Sushil Gupta; David French; Richard Sakurovs; Veena Sahajwalla [University of New South Wales, Sydney, NSW (Australia). Centre for Sustainable Materials Research and Technology

    2009-07-15T23:59:59.000Z

    Iron minerals in coke can catalyze its gasification and may affect coke behavior in the blast furnace. The catalytic behavior of iron depends largely upon the nature of the iron-bearing minerals. To determine the mineralogical changes that iron could undergo in the blast furnace, cokes made from three coals containing iron present in different mineral forms (clays, carbonates, and pyrite) were examined. All coke samples were heat-treated in a horizontal furnace at 1373, 1573, and 1773 K and then gasified with CO{sub 2} at 1173 K in a fixed bed reactor (FBR). Coke mineralogy was characterized using quantitative X-ray diffraction (XRD) analysis of coke mineral matter prepared by low-temperature ashing (LTA) and field emission scanning electron microscopy combined with energy dispersive X-ray analysis (FESEM/EDS). The mineralogy of the three cokes was most notably distinguished by differing proportions of iron-bearing phases. During heat treatment and subsequent gasification, iron-containing minerals transformed to a range of minerals but predominantly iron-silicides and iron oxides, the relative amounts of which varied with heat treatment temperature and gasification conditions. The relationship between initial apparent reaction rate and the amount of catalytic iron minerals - pyrrhotite, metallic iron, and iron oxides - was linear and independent of heat treatment temperature at total catalyst levels below 1 wt %. The study showed that the coke reactivity decreased with increasing temperature of heat treatment due to decreased levels of catalytic iron minerals (largely due to formation of iron silicides) as well as increased ordering of the carbon structure. The study also showed that the importance of catalytic mineral matter in determining reactivity declines as gasification proceeds. 37 refs., 13 figs., 7 tabs.

  3. Catalytic hydrodesulfurization of bitumen

    SciTech Connect (OSTI)

    Sharma, R.K.; Olson, E.S. [Univ. of North Dakota, Grand Forks, ND (United States)

    1995-12-31T23:59:59.000Z

    Investigations of the catalytic hydrodesulfurization of Venezuela bitumen and its water emulsion (Orimulsion) were carried out. This material contained a large amount of sulfur and organometallics, such as vanadium and nickel compounds. A variety of nickel and molybdenum catalysts were prepared. These, as well as two commercial catalysts, were tested with Orimulsion and vacuum-dried, pentane-insoluble and soluble bitumen. Catalytic hydrotreatment removed up to 75% of sulfur from the bitumen. Hydrodesulfurization was found to be affected by reaction temperature, reaction time, catalyst, and feed material. Moisture-free bitumen and a pentane-soluble bitumen fraction were desulfurized more effectively than Orimulsion. Zeolite-based catalysts gave higher desulfurization than synthetic clay catalysts.

  4. Concentric catalytic combustor

    DOE Patents [OSTI]

    Bruck, Gerald J. (Oviedo, FL); Laster, Walter R. (Oviedo, FL)

    2009-03-24T23:59:59.000Z

    A catalytic combustor (28) includes a tubular pressure boundary element (90) having a longitudinal flow axis (e.g., 56) separating a first portion (94) of a first fluid flow (e.g., 24) from a second portion (95) of the first fluid flow. The pressure boundary element includes a wall (96) having a plurality of separate longitudinally oriented flow paths (98) annularly disposed within the wall and conducting respective portions (100, 101) of a second fluid flow (e.g., 26) therethrough. A catalytic material (32) is disposed on a surface (e.g., 102, 103) of the pressure boundary element exposed to at least one of the first and second portions of the first fluid flow.

  5. Modeling Transformation

    E-Print Network [OSTI]

    Rose, Michael R.

    Modeling Transformation What does each step do? #12;Transformation Procedure #12;Transformation Procedure #12;Building Your Model Yarn = chromosomal DNA Beads - - - - - - - - - - - - - - Ribosomes #12;Add transformation solution Tube CaCl2 #12;Transformation solution: CaCl2

  6. Challenges in the Selective Transformation of Biomass to Useful Chemical Intermediates and Materials

    E-Print Network [OSTI]

    Abolmaesumi, Purang

    highly hydroxylated biomass feedstocks into new chemical intermediates and thermoplastics. New scientific. We have developed new catalytic methods for transforming biomass feedstocks into new monomers

  7. transformation restrictions

    E-Print Network [OSTI]

    Lyuu, Yuh-Dauh

    Integration of Graph Transformation and Temporal Logic for the Speci#12;cation of Distributed, namely distributed graph transformation and temporal logic. Distributed graph transformation is intended

  8. Catalytic reforming methods

    DOE Patents [OSTI]

    Tadd, Andrew R; Schwank, Johannes

    2013-05-14T23:59:59.000Z

    A catalytic reforming method is disclosed herein. The method includes sequentially supplying a plurality of feedstocks of variable compositions to a reformer. The method further includes adding a respective predetermined co-reactant to each of the plurality of feedstocks to obtain a substantially constant output from the reformer for the plurality of feedstocks. The respective predetermined co-reactant is based on a C/H/O atomic composition for a respective one of the plurality of feedstocks and a predetermined C/H/O atomic composition for the substantially constant output.

  9. Determination of Landau Fermi-liquid parameters of strongly interacting fermions by means of a nonlinear scaling transformation

    E-Print Network [OSTI]

    Ji-sheng Chen

    2009-10-20T23:59:59.000Z

    A nonlinear transformation approach is formulated for the correlated fermions' thermodynamics through a medium-scaling effective action. An auxiliary implicit variable-effective chemical potential is introduced to characterize the non-Gaussian fluctuations physics. By incorporating the nonlocal correlation effects, the achieved grand partition function is made of coupled highly nonlinear parametric equations. Analytically, the low temperature expansions for the strongly interacting unitary Fermi gas are performed for the adiabatic compressibility-sound speed and specific heat with the Sommerfeld lemma. The expressions for the Landau Fermi-Liquid parameters $F_0^s$ and $F_1^s$ of the strongly interacting fermion system are obtained. As a universal constant, the effective fermion mass ratio is $m^*/m={10/9}$ at unitarity.

  10. Transformation Telepresence

    E-Print Network [OSTI]

    Fisher, Kathleen

    Business Transformation through Telepresence Gaining Value with Enterprise Video Collaboration-based research and April, 2011 Business Transformation through Telepresence: Gaining Value with Enterprise Video be used to transform organizations. Why Does Your Business Need to Transform? Traditionally, organizations

  11. Novel Catalytic Membrane Reactors

    SciTech Connect (OSTI)

    Stuart Nemser, PhD

    2010-10-01T23:59:59.000Z

    There are many industrial catalytic organic reversible reactions with amines or alcohols that have water as one of the products. Many of these reactions are homogeneously catalyzed. In all cases removal of water facilitates the reaction and produces more of the desired chemical product. By shifting the reaction to right we produce more chemical product with little or no additional capital investment. Many of these reactions can also relate to bioprocesses. Given the large number of water-organic compound separations achievable and the ability of the Compact Membrane Systems, Inc. (CMS) perfluoro membranes to withstand these harsh operating conditions, this is an ideal demonstration system for the water-of-reaction removal using a membrane reactor. Enhanced reaction synthesis is consistent with the DOE objective to lower the energy intensity of U.S. industry 25% by 2017 in accord with the Energy Policy Act of 2005 and to improve the United States manufacturing competitiveness. The objective of this program is to develop the platform technology for enhancing homogeneous catalytic chemical syntheses.

  12. Catalytic hydrodesulfurization of bitumen

    SciTech Connect (OSTI)

    Sharma, R.K.; Olson, E.S. [Univ. of North Dakota, Grand Forks, ND (United States)

    1995-12-31T23:59:59.000Z

    Investigations of the catalytic hydrodesulfurization of Venezuela bitumen and its water-emulsion (Orimulsion) were carried out. A variety of catalysts were prepared and some impregnated with molybdenum and sulfided. These and two commercial catalysts were tested with Orimulsion, vacuum-dried Orimulsion, and pentane-insoluble and soluble Orimulsion. Hydrotreatment of feed material was done in a 15-mL tube reactor using a variety of catalysts at 390{degrees}C under an initial 1000-psi hydrogen pressure with a reaction time of 1-3 hours. The hydrotreated products were analyzed by total sulfur analysis. Catalytic hydrotreatment removed up to 75% of sulfur from the bitumen. Nickel and/or molybdenum impregnation on various supports promoted sulfur removal from Orimulsion. Hydrodesulfurization was found to be affected by reaction temperature, reaction time, catalyst, and feed material. A moisture-free bitumen and a pentane-soluble bitumen fraction were desulfurized more effectively than Orimulsion. Zeolite-based catalysts gave higher desulfurization than synthetic clay catalysts or commercial AMOCAT and HDN catalysts.

  13. Method and apparatus for monitoring a hydrocarbon-selective catalytic reduction device

    DOE Patents [OSTI]

    Schmieg, Steven J; Viola, Michael B; Cheng, Shi-Wai S; Mulawa, Patricia A; Hilden, David L; Sloane, Thompson M; Lee, Jong H

    2014-05-06T23:59:59.000Z

    A method for monitoring a hydrocarbon-selective catalytic reactor device of an exhaust aftertreatment system of an internal combustion engine operating lean of stoichiometry includes injecting a reductant into an exhaust gas feedstream upstream of the hydrocarbon-selective catalytic reactor device at a predetermined mass flowrate of the reductant, and determining a space velocity associated with a predetermined forward portion of the hydrocarbon-selective catalytic reactor device. When the space velocity exceeds a predetermined threshold space velocity, a temperature differential across the predetermined forward portion of the hydrocarbon-selective catalytic reactor device is determined, and a threshold temperature as a function of the space velocity and the mass flowrate of the reductant is determined. If the temperature differential across the predetermined forward portion of the hydrocarbon-selective catalytic reactor device is below the threshold temperature, operation of the engine is controlled to regenerate the hydrocarbon-selective catalytic reactor device.

  14. Transformations ENGINEERING

    E-Print Network [OSTI]

    Gales, Mark

    On the Complexity of the Discrete Fourier Transform and Related Linear Transforms Preliminary straight line program that computes an encoding of the Hadamard Transform. The transform itself can transforms, like the DFT. 1 Introduction The complexity of special linear transformations (computations

  15. 5, 35333559, 2005 Catalytic conversion

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    measurement technique, employing selective gas- phase catalytic conversion of methanol to formaldehyde it the second most abundant organic trace gas after methane. Methanol can play an important role in upper tropoACPD 5, 3533­3559, 2005 Catalytic conversion of methanol to formaldehyde S. J. Solomon et al. Title

  16. CX-004964: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Catalytic Transformation of Waste Carbon Dioxide into Valuable MaterialsCX(s) Applied: A11, B3.6Date: 12/29/2010Location(s): Orangeburg, South CarolinaOffice(s): Fossil Energy, National Energy Technology Laboratory

  17. CX-004967: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Catalytic Transformation of Waste Carbon Dioxide into Valuable MaterialsCX(s) Applied: A11, B3.6Date: 12/30/2010Location(s): Rochester, New YorkOffice(s): Fossil Energy, National Energy Technology Laboratory

  18. Fourier Transform-Plasmon Waveguide Spectroscopy: A Nondestructive Multifrequency Method for Simultaneously Determining Polymer Thickness and Apparent Index of Refraction

    SciTech Connect (OSTI)

    Bobbitt, Jonathan M [Ames Laboratory; Weibel, Stephen C [GWC Technologies Inc; Elshobaki, Moneim [Iowa State University; Chaudhary, Sumit [Iowa State University; Smith, Emily A.

    2014-12-16T23:59:59.000Z

    Fourier transform (FT)-plasmon waveguide resonance (PWR) spectroscopy measures light reflectivity at a waveguide interface as the incident frequency and angle are scanned. Under conditions of total internal reflection, the reflected light intensity is attenuated when the incident frequency and angle satisfy conditions for exciting surface plasmon modes in the metal as well as guided modes within the waveguide. Expanding upon the concept of two-frequency surface plasmon resonance developed by Peterlinz and Georgiadis [ Opt. Commun. 1996, 130, 260], the apparent index of refraction and the thickness of a waveguide can be measured precisely and simultaneously by FT-PWR with an average percent relative error of 0.4%. Measuring reflectivity for a range of frequencies extends the analysis to a wide variety of sample compositions and thicknesses since frequencies with the maximum attenuation can be selected to optimize the analysis. Additionally, the ability to measure reflectivity curves with both p- and s-polarized light provides anisotropic indices of refraction. FT-PWR is demonstrated using polystyrene waveguides of varying thickness, and the validity of FT-PWR measurements are verified by comparing the results to data from profilometry and atomic force microscopy (AFM).

  19. Synthesis, Characterization, and Catalytic Function of Novel...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Characterization, and Catalytic Function of Novel Highly Dispersed Tungsten Oxide Catalysts on Mesoporous Silica . Synthesis, Characterization, and Catalytic Function of Novel...

  20. Preparation, Characterization, and Catalytic Properties of Tungsten...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Preparation, Characterization, and Catalytic Properties of Tungsten Trioxide Cyclic Trimers on FeO(111)Pt(111). Preparation, Characterization, and Catalytic Properties of Tungsten...

  1. Transforming development

    E-Print Network [OSTI]

    Verbrugge, Clark

    Transforming Java Bytecode Laurie Hendren, Patrick Lam, Jennifer for Analyzing and Transforming Java Bytecode -- p. 1/148 #12; ,Feng,Jennifer) Conclusion, Further Reading & Homework (Laurie) Soot, a Tool for Analyzing and Transforming Java Bytecode

  2. Transformations for densities Linear transformations

    E-Print Network [OSTI]

    Adler, Robert J.

    ' & $ % Lecture 28 Transformations for densities Linear transformations 1-1 differentiable functions General transformations Expectation of a function 1 #12;' & $ % Transformations for discrete transformation of a U[0, 1] · Take X U[0, 1], so that fX(x) = 1 0 0 and set Y

  3. The catalytic oxidation of propane

    E-Print Network [OSTI]

    Sanderson, Charles Frederick

    1949-01-01T23:59:59.000Z

    THE CATALYTIC OXIDATION OP PROPANE A Thesis By Charles Frederick Sandersont * * June 1949 Approval as to style and content recommended: Head of the Department of Chemical Engineering THE CATALYTICi OXIDATTON OF PROPANE A Thesis By Charles... Frederick ;Sandersonit * June 1949 THE CATALYTIC OXIDATION OP PROPANE A Thesis Submitted to the Faculty of the Agricultural and Mechanical College of Texas in Partial Fulfillment of the Requirements for the Degree of Doctor of Philosophy Major...

  4. Appell Transformation and Canonical Transforms

    E-Print Network [OSTI]

    Amalia Torre

    2011-07-19T23:59:59.000Z

    The interpretation of the optical Appell transformation, as previously elaborated in relation to the free-space paraxial propagation under both a rectangular and a circular cylindrical symmetry, is reviewed. Then, the caloric Appell transformation, well known in the theory of heat equation, is shown to be amenable for a similar interpretation involving the Laplace transform rather than the Fourier transform, when dealing with the 1D heat equation. Accordingly, when considering the radial heat equation, suitably defined Hankel-type transforms come to be involved in the inherent Appell transformation. The analysis is aimed at outlining the link between the Appell transformation and the canonical transforms.

  5. Exploring Functional Mellin Transforms

    E-Print Network [OSTI]

    J. LaChapelle

    2015-01-08T23:59:59.000Z

    We define functional Mellin transforms within a scheme for functional integration proposed in [1]. Functional Mellin transforms can be used to define functional traces, logarithms, and determinants. The associated functional integrals are useful tools for probing function spaces in general and $C^\\ast$-algebras in particular. Several interesting aspects are explored.

  6. Lorentz Transformations

    E-Print Network [OSTI]

    Bernard R. Durney

    2011-12-09T23:59:59.000Z

    This paper describes a particularly didactic and transparent derivation of basic properties of the Lorentz group. The generators for rotations and boosts along an arbitrary direction, as well as their commutation relations, are written as functions of the unit vectors that define the axis of rotation or the direction of the boost (an approach that can be compared with the one that in electrodynamics, works with the electric and magnetic fields instead of the Maxwell stress tensor). For finite values of the angle of rotation or the boost's velocity, collectively denoted by V, the existence of an exponential expansion for the coordinate transformation's matrix, M (in terms of GV where G is the generator) requires that the matrix's derivative with respect to V, be equal to GM. This condition can only be satisfied if the transformation is additive as it is indeed the case for rotations, but not for velocities. If it is assumed, however, that for boosts such an expansion exists, with V = V(v), v being the velocity, and if the above condition is imposed on the boost's matrix then its expression in terms of hyperbolic cosh(V) and sinh(V} is recovered, and the expression for V(= arc tanh(v)) is determined. A general Lorentz transformation can be written as an exponential containing the sum of a rotation and a boost, which to first order is equal to the product of a boost with a rotation. The calculations of the second and third order terms show that the equations for the generators used in this paper, allow to reliably infer the expressions for the higher order generators, without having recourse to the commutation relations. The transformationmatrices for Weyl spinors are derived for finite values of the rotation and velocity, and field representations, leading to the expression for the angular momentum operator, are studied.

  7. Integral transformation and Darboux transformation

    E-Print Network [OSTI]

    Kouichi Takemura

    2009-11-11T23:59:59.000Z

    We review Darboux-Crum transformation of Heun's differential equation. By rewriting an integral transformation of Heun's differential equation into a form of elliptic functions, we see that the integral representation is a generalization of Darboux-Crum transformation. We also consider conservation of monodromy with respect to the transformations.

  8. Correlations between surface structure and catalytic activity/selectivity

    SciTech Connect (OSTI)

    Goodman, D.W.

    1992-10-01T23:59:59.000Z

    Objective is to address the keys to understanding the relation between surface structure and catalytic activity/selectivity. Of concern are questions related to enhanced catalytic properties of mixed-metal catalysts and critical active site requirements for molecular synthesis and rearrangement. The experimental approach utilizes a microcatalytic reactor contiguous to a surface analysis system, an arrangement which allows in vacuo transfer of the catalyst from one chamber to the other. Surface techniques being used include Auger (AES), UV and X-ray photoemission spectroscopy (UPS and XPS), temperature programmed desorption (TPD), low energy electron diffraction (LEED), high resolution electron energy loss spectroscopy (HREELS) and infrared reflection-absorption spectroscopy (IRAS). Our research program builds upon our previous experience relating the results of single crystal kinetic measurements with the results obtained with supported analogs. As well we are exploiting our recent work on the preparation, the characterization, and the determination of the catalytic properties of ultra-thin metal and metal oxide films. The program is proceeding toward the study of the unique catalytic properties of ultrathin metal films; the investigation of the critical ensemble size requirements for principal catalytic reaction types; and the modelling of supported catalysts using ultra-thin planar oxide surfaces.

  9. Method for measuring recovery of catalytic elements from fuel cells

    DOE Patents [OSTI]

    Shore, Lawrence (Edison, NJ); Matlin, Ramail (Berkeley, NJ)

    2011-03-08T23:59:59.000Z

    A method is provided for measuring the concentration of a catalytic clement in a fuel cell powder. The method includes depositing on a porous substrate at least one layer of a powder mixture comprising the fuel cell powder and an internal standard material, ablating a sample of the powder mixture using a laser, and vaporizing the sample using an inductively coupled plasma. A normalized concentration of catalytic element in the sample is determined by quantifying the intensity of a first signal correlated to the amount of catalytic element in the sample, quantifying the intensity of a second signal correlated to the amount of internal standard material in the sample, and using a ratio of the first signal intensity to the second signal intensity to cancel out the effects of sample size.

  10. Market Transformation

    SciTech Connect (OSTI)

    Not Available

    2008-09-01T23:59:59.000Z

    Summarizes the goals and activities of the DOE Solar Energy Technologies Program efforts within its market transformation subprogram.

  11. transformations: representations

    E-Print Network [OSTI]

    Nguyen, Dat H.

    Overview 1. Number transformations: from one base to another 2. Integer representations 3. Real rate, caches... #12; ECS 50, Discussion on 4/25 2 Integer Transformation: From Decimal to Binary Let, Discussion on 4/25 3 Integer Transformation: From Binary to Decimal Compute the weight of each digit position

  12. Transformation Composition

    E-Print Network [OSTI]

    Drewes, Frank

    Proc. AGTIVE'99, to appear in LNCS Graph Transformation Modules and their Composition ? Frank,knirsch,kreo,kuskeg@informatik.uni-bremen.de Abstract. In this paper, we investigate the notion of transformation modules as a structuring principle. Based on the notion of transformation units, a concept that allows to specify binary relations on graphs

  13. Transforming IMAGINATION

    E-Print Network [OSTI]

    Weber, David J.

    Our CAMPAIGN: Transforming MEDICINE Beyond IMAGINATION Endowed Professorships and Chairs #12;As, I know firsthand the many ways that endowed professorships can be transformative. Receiving the John. In the following pages, you can learn more about establishing your legacy by participating in the "Transforming

  14. Transforming IMAGINATION

    E-Print Network [OSTI]

    Weber, David J.

    Our CAMPAIGN: Transforming MEDICINE Beyond IMAGINATION The School of Medicine Research Building in the Transforming Medicine Beyond Imagination Campaign, and to learn more about the specific needs, relative and translational research and help drive medical breakthroughs that will transform the health and well

  15. Understanding ammonia selective catalytic reduction kinetics...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    temperature programmed reduction (TPR), and electron paramagnetic resonance (EPR) spectroscopy. Catalytic properties are examined using NO oxidation, ammonia oxidation,...

  16. Bifunctional Catalysts for the Selective Catalytic Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Reduction (DEER) Conference Presentation: Argonne National Laboratory 2004deermarshall.pdf More Documents & Publications Bifunctional Catalysts for the Selective Catalytic...

  17. INTEGRAL CATALYTIC COMBUSTION/FUEL REFORMING

    E-Print Network [OSTI]

    INTEGRAL CATALYTIC COMBUSTION/FUEL REFORMING FOR GAS TURBINE Prepared For: California Energy REPORT (FAR) INTEGRAL CATALYTIC COMBUSTION/FUEL REFORMING FOR GAS TURBINE CYCLES EISG AWARDEE University://www.energy.ca.gov/research/index.html. #12;Page 1 Integral Catalytic Combustion/Fuel Reforming for Gas Turbine Cycles EISG Grant # 99

  18. Acidity and catalytic activity of zeolite catalysts bound with silica and alumina

    E-Print Network [OSTI]

    Wu, Xianchun

    2004-09-30T23:59:59.000Z

    . Micropore surface area and micropore volume are reduced by about 19% and 18%, respectively, indicating some micropores of ZSM-5 are blocked on binding with silica. SiO2-bound ZSM-5 catalysts have less catalytic activity for butane transformation (cracking...

  19. CX-003202: Categorical Exclusion Determination | Department of...

    Broader source: Energy.gov (indexed) [DOE]

    Exclusion Determination Pilot-Scale Biorefinery: Sustainable Transport Fuels from Biomass and Algae Residues via Integrated Pyrolysis and Catalytic Hydroconversion CX(s)...

  20. Fourier Transform Infrared Spectroscopy

    E-Print Network [OSTI]

    Nizkorodov, Sergey

    FTIR - 1 Fourier Transform Infrared Spectroscopy FTIR DETERMINATION OF MTBE IN GASOLINE AND ETHANOL FTIR DETERMINATION OF MTBE IN GASOLINE AND ETHANOL IN VODKA AND MOUTHWASH INTRODUCTION As a part has contained MTBE (methyl tert­butyl ether) as its primary oxygenate. However, there has been

  1. TRANSFORME Dpartement

    E-Print Network [OSTI]

    Mignotte, Max

    GEODESIE et TRANSFORMATIONS GEODESIQUES Serge BEUCHER CMM ­ Mines ParisTech Novembre 2013 #12;Cours transformation a la propriété suivante: dX,l+m = dX,l [ dX,m] · d est croissante et extensive · d est également croissante lorsqu'on la considère comme une transformation appliquée à l'espace géodésique X (Y fixé) YY

  2. Functional Mellin Transforms

    E-Print Network [OSTI]

    J. LaChapelle

    2015-01-07T23:59:59.000Z

    Functional integrals are defined in terms of locally compact topological groups and their associated Banach-valued Haar integrals. This approach generalizes the functional integral scheme of Cartier and DeWitt-Morette. The definition allows a construction of functional Mellin transforms. In turn, the functional Mellin transforms can be used to define functional traces, logarithms, and determinants. The associated functional integrals are useful tools for probing function spaces in general and $C^\\ast$-algebras in particular. Several interesting aspects are explored.

  3. Market Transformation

    Fuel Cell Technologies Publication and Product Library (EERE)

    This Fuel Cell Technologies Program fact sheet outlines current status and challenges in the market transformation of hydrogen and fuel cell technologies.

  4. TRANSFORME Dpartement

    E-Print Network [OSTI]

    Mignotte, Max

    transformers of kind #3; ! #3;: NatF : #3; ! #3; NatF := #21;X: 1 +X Nat : #3; Nat := #22; NatF #15; Works also

  5. Project TRACS: Empirically Investigating Transformation through Relatedness, Autonomy, and Competence Support Logic Model Rooted in Self-Determination Theory (Deci & Ryan, 2000)

    E-Print Network [OSTI]

    Dyer, Bill

    Project TRACS: Empirically Investigating Transformation through Relatedness, Autonomy appointments toolkit (R, A , C) Project TRACS PI/Director Co-Director & Manager Project Leads & Team MSU&T and hiring procedures -Modern sexism is reduced -Women faculty feel improved job satisfaction -Women intend

  6. Plasma-assisted catalytic reduction system

    DOE Patents [OSTI]

    Vogtlin, G.E.; Merritt, B.T.; Hsiao, M.C.; Wallman, P.H.; Penetrante, B.M.

    1998-01-27T23:59:59.000Z

    Non-thermal plasma gas treatment is combined with selective catalytic reduction to enhance NO{sub x} reduction in oxygen-rich vehicle engine exhausts. 8 figs.

  7. Superconducting Cuprates on Catalytic Substrates - Energy Innovation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transmission Electricity Transmission Find More Like This Return to Search Superconducting Cuprates on Catalytic Substrates Brookhaven National Laboratory Contact BNL About...

  8. Bifunctional Catalysts for the Selective Catalytic Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    3 DEER Conference Presentation: Argonne National Laboratory 2003deermarshall.pdf More Documents & Publications Selectlive Catalytic Reducution of NOx wilth Diesel-Based Fuels as...

  9. Catalytic membranes for fuel cells

    DOE Patents [OSTI]

    Liu, Di-Jia (Naperville, IL); Yang, Junbing (Bolingbrook, IL); Wang, Xiaoping (Naperville, IL)

    2011-04-19T23:59:59.000Z

    A fuel cell of the present invention comprises a cathode and an anode, one or both of the anode and the cathode including a catalyst comprising a bundle of longitudinally aligned graphitic carbon nanotubes including a catalytically active transition metal incorporated longitudinally and atomically distributed throughout the graphitic carbon walls of said nanotubes. The nanotubes also include nitrogen atoms and/or ions chemically bonded to the graphitic carbon and to the transition metal. Preferably, the transition metal comprises at least one metal selected from the group consisting of Fe, Co, Ni, Mn, and Cr.

  10. TRANSFORMATIONS GEODESIQUES

    E-Print Network [OSTI]

    Beucher, Serge

    to A if there is a transformation R which for every input x of B yields an equivalent input R(x) of A. { The answer to x for B

  11. Transformative copy

    E-Print Network [OSTI]

    Offenhuber, Dietmar

    2008-01-01T23:59:59.000Z

    The ability to create an unlimited number of identical copies is a privilege of digital documents. What if that would not be the case, if each copy of a digital file would go along with some sort of transformation? This ...

  12. Utilization of char from biomass gasification in catalytic applications

    E-Print Network [OSTI]

    Utilization of char from biomass gasification in catalytic applications Naomi Klinghoffer Submitted Utilization of char from biomass gasification in catalytic applications Naomi Klinghoffer Utilization takes place during catalytic decomposition. This thesis focuses on the utilization of char as a catalyst

  13. Transforming America's Energy Economy Transforming America's

    E-Print Network [OSTI]

    #12;Transforming America's Energy Economy Transforming America's Energy Economy This document #12;Transforming America's Energy Economy A. Introduction: A Call for Action B. Envisioning the Future.5 Energy Efficiency C. Charting the Path Forward 1 #12;Transforming America's Energy Economy

  14. SPATIAL TRANSFORMATIONS 1 Running head: Spatial transformations

    E-Print Network [OSTI]

    Zacks, Jeffrey M.

    SPATIAL TRANSFORMATIONS 1 Running head: Spatial transformations Multiple Systems for Spatial Imagery: Transformations of Objects and Bodies Jeffrey M. Zacks* and Barbara Tversky * Washington COGNITION & COMPUTATION #12;SPATIAL TRANSFORMATIONS 2 Abstract Problem-solving often requires imagining

  15. Fourier Transform Pairs The Fourier transform transforms a function of

    E-Print Network [OSTI]

    Masci, Frank

    Fourier Transform Pairs The Fourier transform transforms a function of time, f(t), into a function of frequency, F(s): F {f(t)}(s) = F(s) = Z - f(t)e- j2st dt. The inverse Fourier transform transforms a func. The inverse Fourier transform of the Fourier trans- form is the identity transform: f(t) = Z - Z - f()e- j2s

  16. Measurement of diesel solid nanoparticle emissions using a catalytic...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    diesel solid nanoparticle emissions using a catalytic stripper for comparison with Europe's PMP protocol Measurement of diesel solid nanoparticle emissions using a catalytic...

  17. Nanoporous carbon catalytic membranes and method for making the same

    DOE Patents [OSTI]

    Foley, Henry C. (Hockessin, DE); Strano, Michael (Wilmington, DE); Acharya, Madhav (New Castle, DE); Raich, Brenda A. (Houston, TX)

    2002-01-01T23:59:59.000Z

    Catalytic membranes comprising highly-dispersed, catalytically-active metals in nanoporous carbon membranes and a novel single-phase process to produce the membranes.

  18. Passive Catalytic Approach to Low Temperature NOx Emission Abatement...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Catalytic Approach to Low Temperature NOx Emission Abatement Passive Catalytic Approach to Low Temperature NOx Emission Abatement Numerically evaluated and optimized proposed...

  19. High Catalytic Rates for Hydrogen Production Using Nickel Electrocatal...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    High Catalytic Rates for Hydrogen Production Using Nickel Electrocatalysts with Seven-Membered Diphosphine Ligands Containing High Catalytic Rates for Hydrogen Production Using...

  20. Fuel-Flexible, Low-Emissions Catalytic Combustor for Opportunity...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Flexible, Low-Emissions Catalytic Combustor for Opportunity Fuels Fuel-Flexible, Low-Emissions Catalytic Combustor for Opportunity Fuels This fact sheet provides an overview of the...

  1. TCS 2014 Symposium on Thermal and Catalytic Sciences for Biofuels...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    TCS 2014 Symposium on Thermal and Catalytic Sciences for Biofuels and Biobased Products TCS 2014 Symposium on Thermal and Catalytic Sciences for Biofuels and Biobased Products...

  2. transform your thinking transform your environment

    E-Print Network [OSTI]

    Subramanian, Venkat

    MBA #12;transform your thinking 2 transform your environment 18 transform your career 26 start your transformation now 34 transform yourself www.olin.wustl.edu/MBA #12;What distinguishes Washington University. But a great business school transforms the way you think, lead and give back to the world community. #12

  3. Catalytic Hydrothermal Gasification of Biomass

    SciTech Connect (OSTI)

    Elliott, Douglas C.

    2008-05-06T23:59:59.000Z

    A recent development in biomass gasification is the use of a pressurized water processing environment in order that drying of the biomass can be avoided. This paper reviews the research undertaken developing this new option for biomass gasification. This review does not cover wet oxidation or near-atmospheric-pressure steam-gasification of biomass. Laboratory research on hydrothermal gasification of biomass focusing on the use of catalysts is reviewed here, and a companion review focuses on non-catalytic processing. Research includes liquid-phase, sub-critical processing as well as super-critical water processing. The use of heterogeneous catalysts in such a system allows effective operation at lower temperatures, and the issues around the use of catalysts are presented. This review attempts to show the potential of this new processing concept by comparing the various options under development and the results of the research.

  4. Catalytic converter with thermoelectric generator

    SciTech Connect (OSTI)

    Parise, R.J.

    1998-07-01T23:59:59.000Z

    The unique design of an electrically heated catalyst (EHC) and the inclusion of an ECO valve in the exhaust of an internal combustion engine will meet the strict new emission requirements, especially at vehicle cold start, adopted by several states in this country as well as in Europe and Japan. The catalytic converter (CC) has been a most useful tool in pollution abatement for the automobile. But the emission requirements are becoming more stringent and, along with other improvements, the CC must be improved to meet these new standards. Coupled with the ECO valve, the EHC can meet these new emission limits. In an internal combustion engine vehicle (ICEV), approximately 80% of the energy consumed leaves the vehicle as waste heat: out the tail pipe, through the radiator, or convected/radiated off the engine. Included with the waste heat out the tail pipe are the products of combustion which must meet strict emission requirements. The design of a new CC is presented here. This is an automobile CC that has the capability of producing electrical power and reducing the quantity of emissions at vehicle cold start, the Thermoelectric Catalytic Power Generator. The CC utilizes the energy of the exothermic reactions that take place in the catalysis substrate to produce electrical energy with a thermoelectric generator. On vehicle cold start, the thermoelectric generator is used as a heat pump to heat the catalyst substrate to reduce the time to catalyst light-off. Thus an electrically heated catalyst (EHC) will be used to augment the abatement of tail pipe emissions. Included with the EHC in the exhaust stream of the automobile is the ECO valve. This valve restricts the flow of pollutants out the tail pipe of the vehicle for a specified amount of time until the EHC comes up to operating temperature. Then the ECO valve opens and allows the full exhaust, now treated by the EHC, to leave the vehicle.

  5. CX-004968: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Catalytic Transformation of Waste Carbon Dioxide into Valuable MaterialsCX(s) Applied: A9, A11, B3.6Date: 12/29/2010Location(s): Baton Rogue, LouisianaOffice(s): Fossil Energy, National Energy Technology Laboratory

  6. CX-004966: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Catalytic Transformation of Waste Carbon Dioxide into Valuable MaterialsCX(s) Applied: A9, A11, B3.6Date: 12/30/2010Location(s): Ithaca, New YorkOffice(s): Fossil Energy, National Energy Technology Laboratory

  7. The Laplace Transform 1 Laplace transform and inverse transform

    E-Print Network [OSTI]

    Yengulalp, Lynne

    The Laplace Transform Name: 1 Laplace transform and inverse transform Definition. Let f(t) be a function defined for t 0. Then the integral L {f(t)} = 0 e-st f(t)dt is said to be the Laplace transform of f provided the integral converges. Fill in the following Laplace transforms. L {tn } = L {eat } = L

  8. The Laplace Transform 1 Laplace transform and inverse transform

    E-Print Network [OSTI]

    Yengulalp, Lynne

    The Laplace Transform Name: 1 Laplace transform and inverse transform Definition. Let f be a function defined for t 0. Then the integral L {f(t)} = 0 e-st f(t)dt is said to be the Laplace transform of f provided the integral converges. Fill in the following Laplace transforms. L {tn } = n! sn+1 L

  9. Transformers Transformer device used to raise (for

    E-Print Network [OSTI]

    Bertulani, Carlos A. - Department of Physics and Astronomy, Texas A&M University

    Transformers Transformer ­ device used to raise (for transmission) and lower (for use) the ac with different #s of turns #12;Transformers Alternating primary current induces alternating magnetic flux in iron dt d NV B PP -= dt d NV B SS -= S S P P N V N V = #12;Transformers Transformation of voltage

  10. Introduction to Image Transform Fourier Transform

    E-Print Network [OSTI]

    Chen, Chaur-Chin

    Monad Transformers as Monoid Transformers Mauro Jaskelioff CIFASIS/Universidad Nacional de Rosario monadic semantics constructs complex monads by using monad transformers to add computational features transformers to monoid transformers. The generalization brings more simplicity and clarity, and opens the way

  11. Hough Transform Common Names: Hough transform

    E-Print Network [OSTI]

    Masci, Frank

    Hough Transform Common Names: Hough transform Brief Description The Hough transform is a technique that the desired features be specified in some parametric form, the classical Hough transform is most commonly used for the detection of regular curves such as lines, circles, ellipses, etc. A generalized Hough transform can

  12. Vacuum-insulated catalytic converter

    DOE Patents [OSTI]

    Benson, David K. (Golden, CO)

    2001-01-01T23:59:59.000Z

    A catalytic converter has an inner canister that contains catalyst-coated substrates and an outer canister that encloses an annular, variable vacuum insulation chamber surrounding the inner canister. An annular tank containing phase-change material for heat storage and release is positioned in the variable vacuum insulation chamber a distance spaced part from the inner canister. A reversible hydrogen getter in the variable vacuum insulation chamber, preferably on a surface of the heat storage tank, releases hydrogen into the variable vacuum insulation chamber to conduct heat when the phase-change material is hot and absorbs the hydrogen to limit heat transfer to radiation when the phase-change material is cool. A porous zeolite trap in the inner canister absorbs and retains hydrocarbons from the exhaust gases when the catalyst-coated substrates and zeolite trap are cold and releases the hydrocarbons for reaction on the catalyst-coated substrate when the zeolite trap and catalyst-coated substrate get hot.

  13. CX-011250: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Exclusion Determination CX-011250: Categorical Exclusion Determination Transforming Photovoltaic Installations Toward Dispatchable, Schedulable Energy Solutions CX(s) Applied:...

  14. Transformation and Quantization

    E-Print Network [OSTI]

    Yang, Shih-Hsuan

    Transformation and Quantization Shih-Hsuan Yang CSIE Department, NTUT #12;Contents Quantization and Distortion Analysis Lloyd Quantizer Vector Quantization Block Transforms Transform Kernels JPEG Other

  15. Recruitment interactions can override catalytic interactions in determining the functional

    E-Print Network [OSTI]

    Lim, Wendell

    * by Mark Ptashne, Memorial Sloan Kettering Cancer Center, New York, NY, and approved May 4, 2011 (received for review November 3, 2010) The yeast Saccharomyces cerevisae has four distinct mitogen- activated protein- mining the specificity of kinases through recruitment to specific partners and complexes. Here we probe

  16. Catalytic Adsorptive Stripping Determination of Trace Chromium (VI) at

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed New Substation Sites ProposedOccupational Health Services| AdvancedPortalBismuth

  17. Catalytic Combustor for Fuel-Flexible Turbine

    SciTech Connect (OSTI)

    W. R. Laster; E. Anoshkina; P. Szedlacsek

    2006-03-31T23:59:59.000Z

    Under the sponsorship of the U.S. Department of Energy's National Energy Technology Laboratory, Siemens Westinghouse is conducting a three-year program to develop an ultra low NOx, fuel flexible catalytic combustor for gas turbine application in IGCC. The program is defined in three phases: Phase 1-Implementation Plan, Phase 2-Validation Testing and Phase 3-Field Testing. The Phase 1 program has been completed. Phase II was initiated in October 2004. In IGCC power plants, the gas turbine must be capable of operating on syngas as a primary fuel and an available back-up fuel such as natural gas. In this program the Rich Catalytic Lean (RCL{trademark}) technology is being developed as an ultra low NOx combustor. In this concept, ultra low NOx is achieved by stabilizing a lean premix combustion process by using a catalytic reactor to react part of the fuel, increasing the fuel/air mixture temperature. In Phase 1, the feasibility of the catalytic concept for syngas application has been evaluated and the key technology issues identified. In Phase II the catalytic concept will be demonstrated through subscale testing. Phase III will consist of full-scale combustor basket testing on natural gas and syngas.

  18. Testability Transformation --Program Transformation to Improve Testability

    E-Print Network [OSTI]

    Binkley, David W.

    Testability Transformation -- Program Transformation to Improve Testability Mark Harman1 , Andr, 26 Richmond Street, Glasgow G1 1XH, UK. Corresponding Author. Abstract. Testability transformation. The goal is to improve the testing process by transforming a program to one that is more amenable

  19. Testability Transformation: Program Transformation to Improve Testability

    E-Print Network [OSTI]

    Singer, Jeremy

    Testability Transformation: Program Transformation to Improve Testability An Overview of Recent Author. Abstract. Testability transformation is a new form of program transfor- mation in which the goal to some chosen test adequacy criterion. The goal is to improve the testing process by transforming

  20. Transformation Transformation Sommersemester 2012 1 / 121

    E-Print Network [OSTI]

    Snelting, Gregor

    Testability Transformation: Program Transformation to Improve Testability An Overview of Recent Author. Abstract. Testability transformation is a new form of program transfor- mation in which the goal to some chosen test adequacy criterion. The goal is to improve the testing process by transforming

  1. Transformation Market Transformation is based on

    E-Print Network [OSTI]

    Market Transformation Market Transformation is based on the concept that federal support can and reducing high insurance costs. Strategies Market Transformation's primary goal is to accelerate-world implementation Market transformation is built on forming partnerships with stakeholders through- out the country

  2. Transformer modeling in power systems

    SciTech Connect (OSTI)

    Ma, J.; Dawalibi, F.P. [Safe Engineering Services and Technologies Ltd., Montreal, Quebec (Canada)

    1999-11-01T23:59:59.000Z

    A practical and accurate method of modeling various transformers in power systems using a general circuit model approach is described in this paper. The advantage of the new approach is that it can model transformers along with a complex circuit network, while avoiding the use of symmetrical components, unlike other approaches. The transformer modeling technique introduced in this paper is very useful to accurately determine fault current distribution in a power system and electromagnetic interference on pipelines and communication lines installed in a right-of-way consisting of transmission lines operating at different voltages.

  3. Electro Catalytic Oxidation (ECO) Operation

    SciTech Connect (OSTI)

    Morgan Jones

    2011-03-31T23:59:59.000Z

    The power industry in the United States is faced with meeting many new regulations to reduce a number of air pollutants including sulfur dioxide, nitrogen oxides, fine particulate matter, and mercury. With over 1,000 power plants in the US, this is a daunting task. In some cases, traditional pollution control technologies such as wet scrubbers and SCRs are not feasible. Powerspan's Electro-Catalytic Oxidation, or ECO{reg_sign} process combines four pollution control devices into a single integrated system that can be installed after a power plant's particulate control device. Besides achieving major reductions in emissions of sulfur dioxide (SO{sub 2}), nitrogen oxides (NOx), fine particulate matter (PM2.5) and mercury (Hg), ECO produces a highly marketable fertilizer, which can help offset the operating costs of the process system. Powerspan has been operating a 50-MW ECO commercial demonstration unit (CDU) at FirstEnergy Corp.'s R.E. Burger Plant near Shadyside, Ohio, since February 2004. In addition to the CDU, a test loop has been constructed beside the CDU to demonstrate higher NOx removal rates and test various scrubber packing types and wet ESP configurations. Furthermore, Powerspan has developed the ECO{reg_sign}{sub 2} technology, a regenerative process that uses a proprietary solvent to capture CO{sub 2} from flue gas. The CO{sub 2} capture takes place after the capture of NOx, SO{sub 2}, mercury, and fine particulate matter. Once the CO{sub 2} is captured, the proprietary solution is regenerated to release CO{sub 2} in a form that is ready for geological storage or beneficial use. Pilot scale testing of ECO{sub 2} began in early 2009 at FirstEnergy's Burger Plant. The ECO{sub 2} pilot unit is designed to process a 1-MW flue gas stream and produce 20 tons of CO{sub 2} per day, achieving a 90% CO{sub 2} capture rate. The ECO{sub 2} pilot program provided the opportunity to confirm process design and cost estimates, and prepare for large scale capture and sequestration projects. The objectives of this project were to prove at a commercial scale that ECO is capable of extended operations over a range of conditions, that it meets the reliability requirements of a typical utility, and that the fertilizer co-product can be consistently generated, providing ECO with an economic advantage over conventional technologies currently available. Further objectives of the project were to show that the ECO system provides flue gas that meets the inlet standards necessary for ECO{sub 2} to operate, and that the outlet CO{sub 2} and other constituents produced by the ECO{sub 2} pilot can meet Kinder-Morgan pipeline standards for purposes of sequestration. All project objectives are consistent with DOE's Pollution Control Innovations for Power Plants program goals.

  4. Porous Core-Shell Nanostructures for Catalytic Applications

    E-Print Network [OSTI]

    Ewers, Trevor David

    2012-01-01T23:59:59.000Z

    C.Y Mou. Catalytic nano-rattle of Au@ hollow silica: towardshollow nanostructures induced by the Kirkendall effect: The basic concept. NanoHollow mesoporous aluminosilica spheres with perpendicular pore channels as catalytic nanoreactors. ACS Nano,

  5. Catalytic membrane program novation: High temperature catalytic membrane reactors. Final report

    SciTech Connect (OSTI)

    Kleiner, R.N. [Kleiner (Richard N.), Englewood, CO (United States)] [Kleiner (Richard N.), Englewood, CO (United States)

    1998-08-28T23:59:59.000Z

    The original objective was to develop an energy-efficient hydrocarbon dehydrogenation process based on catalytic membrane reactors. Golden Technologies determined that the goals of this contract would be best served by novating the contract to an end user or other interested party which is better informed on the economic justification aspects of petrochemical refining processes to carry out the remaining work. In light of the Chevron results, the program objective was broadened to include development of inorganic membranes for applications in the chemical industry. The proposed membrane technologies shall offer the potential to improve chemical production processes via conversion increase and energy savings. The objective of this subcontract is to seek a party that would serve as a prime contractor to carry out the remaining tasks on the agreement and bring the agreement to a successful conclusion. Four tasks were defined to select the prime contractor. They were (1) prepare a request for proposal, (2) solicit companies as potential prime contractors as well as team members, (3) discuss modifications requested by the potential prime contractors, and (4) obtain, review and rank the proposals. The accomplishments on the tasks is described in detail in the following sections.

  6. Analyzing Signals Fourier transform

    E-Print Network [OSTI]

    Sweldens, Wim

    Page 1 1 Analyzing Signals Fourier transform s frequency content s linear combination of sin frequency analysis s windowed Fourier transform 6 #12;Page 4 7 Gabor Transform function to analyze window Gabor Transform Spatial domain Gabor domain b #12;Page 5 9 Gabor Transform Problems s discrete version

  7. Transparent and Catalytic Carbon Nanotube Films

    E-Print Network [OSTI]

    Hone, James

    , a reaction that is important for the dye-sensitized solar cell, with a charge-transfer resistance as measured for the dye-sensitized solar cell. Other possible applications include batteries, fuel cells to be electrochemically active in several systems.1,8­15 For example, they are catalytic in the dye-sensitized solar cell

  8. Performance characterization of a hydrogen catalytic heater.

    SciTech Connect (OSTI)

    Johnson, Terry Alan; Kanouff, Michael P.

    2010-04-01T23:59:59.000Z

    This report describes the performance of a high efficiency, compact heater that uses the catalytic oxidation of hydrogen to provide heat to the GM Hydrogen Storage Demonstration System. The heater was designed to transfer up to 30 kW of heat from the catalytic reaction to a circulating heat transfer fluid. The fluid then transfers the heat to one or more of the four hydrogen storage modules that make up the Demonstration System to drive off the chemically bound hydrogen. The heater consists of three main parts: (1) the reactor, (2) the gas heat recuperator, and (3) oil and gas flow distribution manifolds. The reactor and recuperator are integrated, compact, finned-plate heat exchangers to maximize heat transfer efficiency and minimize mass and volume. Detailed, three-dimensional, multi-physics computational models were used to design and optimize the system. At full power the heater was able to catalytically combust a 10% hydrogen/air mixture flowing at over 80 cubic feet per minute and transfer 30 kW of heat to a 30 gallon per minute flow of oil over a temperature range from 100 C to 220 C. The total efficiency of the catalytic heater, defined as the heat transferred to the oil divided by the inlet hydrogen chemical energy, was characterized and methods for improvement were investigated.

  9. Pillared clays as superior catalysts for selective catalytic reduction of nitric oxide. Second semiannual report, 1996

    SciTech Connect (OSTI)

    Yang, R.T.; Li, W.B.; Sirilumpen, M.; Tharapiwattananon, N.

    1997-08-01T23:59:59.000Z

    During the first six months of the program, the work has progressed as planned. We have constructed a reactor system and assembled all laboratory essentials for conducting the three-year project. First, the catalytic activities of the Cu(2+) ion exchanged alumina-pillared clay for the selective catalytic reduction of NO by ethylene were measured. The temperature range was 250-500{degrees}C. The activities of this catalyst were substantially higher than the catalyst that has been extensively studied in the literature, Cu-ZSM-5. Fourier Transform Infrared Spectroscopy (FTIR) was used to study the acidity of the catalyst. The second part of the work was an in-depth FTIR study of the NO decomposition mechanism on the catalyst. This was planned as the first and the key step to obtain an understanding of the reaction mechanism. Key surface intermediates were identified from the FTIR spectra, and a redox type Eley-Rideal mechanism was proposed for the NO decomposition on this catalyst. This report will be divided into two parts. In Part One, we report results on the catalytic activities of the Cu-alumina-pillared clay and a direct comparison with other known catalysts. In Part two, we focus on the FTIR study and from the results, we propose a NO decomposition mechanism on this new catalyst. Plans for the next six months include tests of different pillared clays as well as the catalytic mechanism. The micro reactor will continue to be the key equipment for measuring the catalytic activities. FTIR will continue to be the major technique for identifying surface species and hence understanding the reaction mechanism.

  10. GIS TRANSFORMATIONS Conference Presentation

    E-Print Network [OSTI]

    Tobler, Waldo

    GIS TRANSFORMATIONS Conference Presentation Waldo Tobler Geography Department University, line, area, or field phenomena, then the sixteen common classes of transformation are: point -> point (scalar, vector, tensor) data, to obtain eighty distinct possible classes of transformation. The common

  11. Transformations KolahdouzRahimi

    E-Print Network [OSTI]

    Lano, Kevin Charles

    An Incremental XSLT Transformation Processor for XML Document Manipulation Lionel Villard ­ Nabil;Outline Motivation Incremental transformations Principles Static Analysis Incremental execution Conclusion presentation architecture NegotiationNegotiation Result of negotiation (Transformation Sheets) Result

  12. Catalytic ignition of fuel/oxygen/nitrogen mixtures over platinum

    SciTech Connect (OSTI)

    Cho, P.; Law, C.K.

    1986-11-01T23:59:59.000Z

    Ignition of fuel/oxygen/nitrogen mixtures over platinum wire is experimentally studied by using microcalorimetry and by restricting the flow to the low Reynolds number range so that axisymmetry prevails. The fuels studied are propane, butane, propylene, ethylene, carbon monoxide, and hydrogen. Parameters investigated include flow velocity, fuel type and concentration, and oxygen concentration. The catalytic ignition temperatures of the various fuels are accurately determined over extensive ranges of fuel/oxygen/nitrogen concentrations. Results show two distinctly opposite ignition trends depending on the nature of the fuel. That is, the ignition temperature of lean propane/air and butane/air mixtures decreases as their fuel concentration is increased, while the reverse trend is observed for lean mixtures of propylene, ethylene, carbon monoxide, and hydrogen with air. Furthermore, the ignition of propane depends primarily on fuel concentration, while the ignition of carbon monoxide depends on fuel and oxygen concentrations to a comparable extent. These results are explained on the basis of hierarchical surface adsorption strengths of the different reactants in effecting catalytic ignition. Additional phenomena of interest are observed and discussed.

  13. Evaluating Transformer Losses

    E-Print Network [OSTI]

    Grun, R. L. Jr.

    and replacing them with low loss units. Today few industrials evaluate losses on either power or distribution transformers. TRANSFORMER LOSSES Transformer losses are divided 'nto load losses and no-load losses. Load losses are due to the winding resista... therefore are a function of the load squared. No-load losses occur from energizing the transformer steel and fore are continuous regardless of the transformer load. TRANSFORMER DESIGN Both types of losses are a fun ce here ion of design. If losses...

  14. Method and apparatus for a catalytic firebox reactor

    DOE Patents [OSTI]

    Smith, Lance L. (North Haven, CT); Etemad, Shahrokh (Trumbull, CT); Ulkarim, Hasan (Hamden, CT); Castaldi, Marco J. (Bridgeport, CT); Pfefferle, William C. (Madison, CT)

    2001-01-01T23:59:59.000Z

    A catalytic firebox reactor employing an exothermic catalytic reaction channel and multiple cooling conduits for creating a partially reacted fuel/oxidant mixture. An oxidation catalyst is deposited on the walls forming the boundary between the multiple cooling conduits and the exothermic catalytic reaction channel, on the side of the walls facing the exothermic catalytic reaction channel. This configuration allows the oxidation catalyst to be backside cooled by any fluid passing through the cooling conduits. The heat of reaction is added to both the fluid in the exothermic catalytic reaction channel and the fluid passing through the cooling conduits. After discharge of the fluids from the exothermic catalytic reaction channel, the fluids mix to create a single combined flow. A further innovation in the reactor incorporates geometric changes in the exothermic catalytic reaction channel to provide streamwise variation of the velocity of the fluids in the reactor.

  15. On the broken ray transform

    E-Print Network [OSTI]

    Joonas Ilmavirta

    2014-09-26T23:59:59.000Z

    This PhD thesis studies the broken ray transform, a generalization of the geodesic X-ray transform where geodesics are replaced with broken rays that reflect on a part of the boundary. The fundamental question is whether this transform is injective. We employ four different methods to approach this question, and each of them gives interesting results. Direct calculation can be used in a ball, where the geometry is particularly simple. If the reflecting part of the boundary is (piecewise) flat, a reflection argument can be used to reduce the problem to the usual X-ray transform. In some geometries one can use broken rays near the boundary to determine the values of the unknown function at the reflector, and even construct its Taylor series. One can also use energy estimates -- which in this context are known as Pestov identities -- to show injectivity in the presence of one convex reflecting obstacle. Many of these methods work also on Riemannian manifolds. We also discuss the periodic broken ray transform, where the integrals are taken over periodic broken rays. The broken ray transform and its periodic version have applications in other inverse problems, including Calder\\'on's problem and problems related to spectral geometry. A more detailed abstract can be found in the PDF file. This version only contains the introductory parts of the thesis. The full thesis also contains five articles.

  16. Catalytic fast pyrolysis of lignocellulosic biomass

    SciTech Connect (OSTI)

    Liu, Changjun; Wang, Huamin; Karim, Ayman M.; Sun, Junming; Wang, Yong

    2014-11-21T23:59:59.000Z

    Increasing energy demand, especially in the transportation sector, and soaring CO2 emissions necessitate the exploitation of renewable sources of energy. Despite the large variety of new energy Q3 carriers, liquid hydrocarbon still appears to be the most attractive and feasible form of transportation fuel taking into account the energy density, stability and existing infrastructure. Biomass is an abundant, renewable source of energy; however, utilizing it in a cost-effective way is still a substantial challenge. Lignocellulose is composed of three major biopolymers, namely cellulose, hemicellulose and lignin. Fast pyrolysis of biomass is recognized as an efficient and feasible process to selectively convert lignocellulose into a liquid fuelóbio-oil. However bio-oil from fast pyrolysis contains a large amount of oxygen, distributed in hundreds of oxygenates. These oxygenates are the cause of many negative properties, such as low heating values, high corrosiveness, high viscosity, and instability; they also greatly Q4 limit the application of bio-oil particularly as transportation fuel. Hydrocarbons derived from biomass are most attractive because of their high energy density and compatibility with the existing infrastructure. Thus, converting lignocellulose into transportation fuels via catalytic fast pyrolysis has attracted much attention. Many studies related to catalytic fast pyrolysis of biomass have been published. The main challenge of this process is the development of active and stable catalysts that can deal with a large variety of decomposition intermediates from lignocellulose. This review starts with the current understanding of the chemistry in fast pyrolysis of lignocellulose and focuses on the development of catalysts in catalytic fast pyrolysis. Recent progress in the experimental studies on catalytic fast pyrolysis of biomass is also summarized with the emphasis on bio-oil yields and quality.

  17. Catalytic extraction processing of contaminated scrap metal

    SciTech Connect (OSTI)

    Griffin, T.P.; Johnston, J.E.; Payea, B.M.; Zeitoon, B.M.

    1995-12-01T23:59:59.000Z

    Molten Metal Technology was awarded a contract to demonstrate the applicability of the Catalytic Extraction Process, a proprietary process that could be applied to US DOE`s inventory of low level mixed waste. This paper is a description of that technology, and included within this document are discussions of: (1) Program objectives, (2) Overall technology review, (3) Organic feed conversion to synthetic gas, (4) Metal, halogen, and transuranic recovery, (5) Demonstrations, (6) Design of the prototype facility, and (7) Results.

  18. Preface: Challenges for Catalytic Exhaust Aftertreatment

    SciTech Connect (OSTI)

    Nova, Isabella; Epling, Bill; Peden, Charles HF

    2014-03-31T23:59:59.000Z

    This special issue of Catalysis Today continues the tradition established since the 18th NAM in Cancun, 2003, of publishing the highlights coming from these catalytic after-treatment technologies sessions, where this volume contains 18 papers based on oral and poster presentations of the 23rd NAM, 2013. The guest editors would like to thank all of the catalyst scientists and engineers who presented in the "Emission control" sessions, and especially the authors who contributed to this special issue of Catalysis Today.

  19. Learning Transformations From Video

    E-Print Network [OSTI]

    Wang, Ching Ming

    2010-01-01T23:59:59.000Z

    on Natural Video . . . . . . . . . . . . . . . . .3 Learning Continuous Transformation from VideoProposed Video Coder

  20. transformation languages Introduction

    E-Print Network [OSTI]

    Nierstrasz, Oscar

    transformation languages Introduction Transformation languages are widely used for to process can I change / transform the design of a certain task without changing it's logic The common/and hierarchical or/and abstract set of information. It can even be a stream of data. · The transformation engine

  1. TRANSFORMATIONAL GOALS FOR THE

    E-Print Network [OSTI]

    Rhode Island, University of

    TRANSFORMATIONAL GOALS FOR THE 21ST CENTURY PROGRESS REPORT FALL 2014 #12;CONTENTS EXECUTIVE Transformational Goals progress report Fall 2014 #12;Transformational Goals Progress Report | FALL 20142 In 2010 Island Build a community at URI that values and embraces equity and diversity #12;Transformational Goals

  2. Perfect NOT transformation and conjugate transformation

    E-Print Network [OSTI]

    Fengli Yan; Ting Gao; Zhichao Yan

    2012-03-15T23:59:59.000Z

    The perfect NOT transformation, probabilistic perfect NOT transformation and conjugate transformation are studied. Perfect NOT transformation criteria on a quantum state set $S$ of a qubit are obtained. Two necessary and sufficient conditions for realizing a perfect NOT transformation on $S$ are derived. When these conditions are not satisfied we discuss a probabilistic perfect NOT transformation (gate). We construct a probabilistic perfect NOT machine (gate) by a general unitary-reduction operation. With a postselection of the measurement outcomes, the probabilistic NOT gate yields perfectly complements of the input states. We prove that one can realize probabilistically the NOT gate of the input states secretly chosen from a certain set $S=\\{|\\Psi_1>, |\\Psi_2>,..., |\\Psi_n>\\}$ if and only if $|\\Psi_1>, |\\Psi_2>,...,$ and $|\\Psi_n>$ are linearly independent. We also generalize the probabilistic NOT transformation to the conjugate transformation in the multi-level quantum system. The lower bound of the best possible efficiencies attained by a probabilistic perfect conjugate transformation are obtained.

  3. On the positivity of Fourier transforms

    E-Print Network [OSTI]

    Bertrand G. Giraud; Robi Peschanski

    2014-05-13T23:59:59.000Z

    Characterizing in a constructive way the set of real functions whose Fourier transforms are positive appears to be yet an open problem. Some sufficient conditions are known but they are far from being exhaustive. We propose two constructive sets of necessary conditions for positivity of the Fourier transforms and test their ability of constraining the positivity domain. One uses analytic continuation and Jensen inequalities and the other deals with Toeplitz determinants and the Bochner theorem. Applications are discussed, including the extension to the two-dimensional Fourier-Bessel transform and the problem of positive reciprocity, i.e. positive functions with positive transforms.

  4. Catalytic Oxidation of Alcohol via Nickel Phosphine Complexes with Pendant Amines

    SciTech Connect (OSTI)

    Weiss, Charles J.; Das, Partha Pratim; Higgins, Deanna LM; Helm, Monte L.; Appel, Aaron M.

    2014-09-05T23:59:59.000Z

    Nickel complexes were prepared with diphosphine ligands that contain pendant amines, and these complexes catalytically oxidize primary and secondary alcohols to their respective aldehydes and ketones. Kinetic and mechanistic studies of these prospective electrocatalysts were performed to understand what influences the catalytic activity. For the oxidation of diphenylmethanol, the catalytic rates were determined to be dependent on the concentration of both the catalyst and the alcohol. The catalytic rates were found to be independent of the concentration of base and oxidant. The incorporation of pendant amines to the phosphine ligand results in substantial increases in the rate of alcohol oxidation with more electron-donating substituents on the pendant amine exhibiting the fastest rates. We thank Dr. John C. Linehan, Dr. Elliott B. Hulley, Dr. Jonathan M. Darmon, and Dr. Elizabeth L. Tyson for helpful discussions. Research by CJW, PD, DLM, and AMA was supported by the US Department of Energy, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences & Biosciences. Research by MLH was supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Basic Energy Sciences. Pacific Northwest National Laboratory (PNNL) is a multiprogram national laboratory operated for DOE by Battelle.

  5. Gauge transformations are canonical transformations, redux

    E-Print Network [OSTI]

    Z. K. Silagadze

    2014-09-02T23:59:59.000Z

    In this short note we return to the old paper by Tai L. Chow (Eur. J. Phys. 18 (1997), 467-468) and correct its erroneous final part. We also note that the main result of that paper, that gauge transformations of mechanics are canonical transformations, was known much earlier.

  6. Catalytic reduction system for oxygen-rich exhaust

    DOE Patents [OSTI]

    Vogtlin, G.E.; Merritt, B.T.; Hsiao, M.C.; Wallman, P.H.; Penetrante, B.M.

    1999-04-13T23:59:59.000Z

    Non-thermal plasma gas treatment is combined with selective catalytic reduction to enhance NO{sub x} reduction in oxygen-rich vehicle engine exhausts. 8 figs.

  7. Single Supported Atoms Participate in Catalytic Processes | ornl...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Functional Materials for Energy Single Supported Atoms Participate in Catalytic Processes December 04, 2014 Pathways for NO oxidation on single Pt atoms supported on the (010)...

  8. The Effects of Trace Contaminants on Catalytic Processing of...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Processing of Biomass-Derived Feedstocks . Abstract: Trace components in biomass feedstocks are potential catalyst poisons when catalytically processing these materials to...

  9. Selective Catalytic Reduction and Exhaust Gas Recirculation Systems...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Reduction and Exhaust Gas Recirculation Systems Optimization Selective Catalytic Reduction and Exhaust Gas Recirculation Systems Optimization A patented EGR-SCR approach was shown...

  10. Printing 3D Catalytic Devices | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Printing 3D Catalytic Devices Ames Laboratory scientist Igor Slowing discusses using 3D printers to create new materials, including catalysts...

  11. Piloted rich-catalytic lean-burn hybrid combustor

    DOE Patents [OSTI]

    Newburry, Donald Maurice (Orlando, FL)

    2002-01-01T23:59:59.000Z

    A catalytic combustor assembly which includes, an air source, a fuel delivery means, a catalytic reactor assembly, a mixing chamber, and a means for igniting a fuel/air mixture. The catalytic reactor assembly is in fluid communication with the air source and fuel delivery means and has a fuel/air plenum which is coated with a catalytic material. The fuel/air plenum has cooling air conduits passing therethrough which have an upstream end. The upstream end of the cooling conduits is in fluid communication with the air source but not the fuel delivery means.

  12. Selectlive Catalytic Reducution of NOx wilth Diesel-Based Fuels...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Engine Emissions Reduction (DEER) Conference Presentations and Posters 2005deermarshall.pdf More Documents & Publications Bifunctional Catalysts for the Selective Catalytic...

  13. Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway...

    Energy Savers [EERE]

    the catalytic conversion of solubilized carbohydrate streams to hydrocarbon biofuels, utilizing data from recent efforts within the National Advanced Biofuels Consortium...

  14. Catalytic multi-stage liquefaction (CMSL)

    SciTech Connect (OSTI)

    Comolli, A.G.; Ganguli, P.; Karolkiewicz, W.F.; Lee, T.L.K.; Pradhan, V.R.; Popper, G.A.; Smith, T.; Stalzer, R.

    1996-11-01T23:59:59.000Z

    Under contract with the U.S. Department of Energy, Hydrocarbon Technologies, Inc. has conducted a series of eleven catalytic, multi-stage, liquefaction (CMSL) bench scale runs between February, 1991, and September, 1995. The purpose of these runs was to investigate novel approaches to liquefaction relating to feedstocks, hydrogen source, improved catalysts as well as processing variables, all of which are designed to lower the cost of producing coal-derived liquid products. This report summarizes the technical assessment of these runs, and in particular the evaluation of the economic impact of the results.

  15. Kinetic study on the catalytic performance of Rh/TiO/sub 2/ reduced at different temperatures in the CO-H/sub 2/ reaction

    SciTech Connect (OSTI)

    Fujitsu, H.; Ikeyama, N.; Mochida, I.

    1986-08-01T23:59:59.000Z

    Catalytic CO-H/sub 2/ reaction on Rh/TiO/sub 2/ reduced at 200, 400, and 500/sup 0/C (Cat-200, -400, -500) for 2 h was kinetically studied at 250/sup 0/C using a circulating reactor and Fourier transform-infrared (FT-IR) spectroscopy to determine how Cat-400 exhibited the highest activity. The rate equation distinguished the best catalyst with zero and first orders in CO and H/sub 2/, respectively, from other catalysts with negative order in CO. The adsorption ability of the catalyst at 200/sup 0/C was comparable to that of Cat-200, and two to three times larger than that of Cat-500, although the ability of Cat-200 was much larger at room temperature. Carbon monoxide adsorbed on the catalysts reversibly as well as irreversibly. IR spectroscopy revealed that the major form of irreversibly adsorbed CO was linear on Cat-200, whereas similar amounts of linear and bridge forms were observed on Cat-400 and Cat-500. These latter forms were highly reactive against hydrogen molecules when no carbon monoxide was present in the gas phase. Based on these results, the highest activity of Cat-400 is ascribed to rhodium metal modified by properly reduced TiO/sub 2/ to show the appropriate adsorption ability of carbon monoxide which least retards the activation of hydrogen according to first-order kinetics. Typical strong metal-support interaction decreases the catalytic activity by decreasing the active sites and strengthening the CO adsorption too much.

  16. Landscapes of transformation

    E-Print Network [OSTI]

    Ambs, Emily (Emily Kiersten)

    2007-01-01T23:59:59.000Z

    This thesis aims to examine the cultural effect of transformation through the lens of procedural techniques applied to the human body and architecture. The body and architecture both operate as landscapes of transformation. ...

  17. Metrics for enterprise transformation

    E-Print Network [OSTI]

    Blackburn, Craig D. (Craig David), S. M. Massachusetts Institute of Technology

    2009-01-01T23:59:59.000Z

    The objective of this thesis is to depict the role of metrics in the evolving journey of enterprise transformation. To this end, three propositions are explored: (i) metrics and measurement systems drive transformation, ...

  18. Transformations Ordered set of

    E-Print Network [OSTI]

    Jacobs, David

    Modeling Transformations Michael Kazhdan (600.357 / 600.457) HB Ch. 5 FvDFH Ch. 5 #12;Anouncements · Assignment 2 has been posted! #12;Overview · Ray-Tracing so far · Modeling transformations #12;Ray Casting

  19. The Patch Transform

    E-Print Network [OSTI]

    Avidan, Shai

    The patch transform represents an image as a bag of overlapping patches sampled on a regular grid. This representation allows users to manipulate images in the patch domain, which then seeds the inverse patch transform to ...

  20. CX-007858: Categorical Exclusion Determination | Department of...

    Broader source: Energy.gov (indexed) [DOE]

    Exclusion Determination CX-007858: Categorical Exclusion Determination Southwest Solar Transformation Initiative CX(s) Applied: A9, A11 Date: 01272012 Location(s):...

  1. CX-011102: Categorical Exclusion Determination | Department of...

    Broader source: Energy.gov (indexed) [DOE]

    Exclusion Determination CX-011102: Categorical Exclusion Determination American Solar Transformation Initiative CX(s) Applied: A11 Date: 08092013 Location(s):...

  2. CX-007153: Categorical Exclusion Determination | Department of...

    Broader source: Energy.gov (indexed) [DOE]

    Determination CX-007153: Categorical Exclusion Determination Glen Canyon substation Transformer Addition CX(s) Applied: B4.6 Date: 05052011 Location(s): Coconino County, Arizona...

  3. CX-005116: Categorical Exclusion Determination | Department of...

    Broader source: Energy.gov (indexed) [DOE]

    Determination CX-005116: Categorical Exclusion Determination Lusk Substation Transformer Replacement, Lusk, Niobrara County, Wyoming CX(s) Applied: B4.6 Date: 01242011...

  4. CX-010546: Categorical Exclusion Determination | Department of...

    Broader source: Energy.gov (indexed) [DOE]

    Determination CX-010546: Categorical Exclusion Determination Liberty Substation Transformer Replacement Project, Maricopa County, Arizona CX(s) Applied: B4.11 Date: 06062013...

  5. CX-004129: Categorical Exclusion Determination | Department of...

    Broader source: Energy.gov (indexed) [DOE]

    Determination CX-004129: Categorical Exclusion Determination Distributed Generation Transformer for Megawatt-Scale Wind Turbines using Alternating Current-Link CX(s) Applied:...

  6. CX-005114: Categorical Exclusion Determination | Department of...

    Broader source: Energy.gov (indexed) [DOE]

    Determination CX-005114: Categorical Exclusion Determination Fleming Substation Transformer Replacement, Fleming, Logan County, Colorado CX(s) Applied: B4.6 Date: 12202010...

  7. CX-005115: Categorical Exclusion Determination | Department of...

    Broader source: Energy.gov (indexed) [DOE]

    Determination CX-005115: Categorical Exclusion Determination Weld Substation Transformer Placement, Greeley, Weld County, Colorado CX(s) Applied: B4.6 Date: 01072011...

  8. CX-003621: Categorical Exclusion Determination | Department of...

    Broader source: Energy.gov (indexed) [DOE]

    Determination CX-003621: Categorical Exclusion Determination Hayden Substation Transformer Replacement CX(s) Applied: B4.6 Date: 08232010 Location(s): Routt County,...

  9. LAPPED TRANSFORMS COMPRESSION

    E-Print Network [OSTI]

    de Queiroz, Ricardo L.

    Chapter 6 LAPPED TRANSFORMS FOR IMAGE COMPRESSION Ricardo L. de Queiroz Digital Imaging Technology aspects of lapped transforms and their applications to image compression. It is a subject that has been extensively studied mainly because lapped transforms are closely related to filter banks, wavelets, and time

  10. TRANSFORMATIONAL GOALS FOR THE

    E-Print Network [OSTI]

    Rhode Island, University of

    TRANSFORMATIONAL GOALS FOR THE 21ST CENTURY The presidenT's 21sT cenTury fund for excellence #12;TRANSFORMATIONAL GOALS FOR THE 21ST CENTURY 1 THE UNIVERSITY OF RHODE ISLAND The University of Rhode Island and transform our approaches to teaching, research, and service so that we can prepare students for a rapidly

  11. Transforming Health Research

    E-Print Network [OSTI]

    Diggle, Peter J.

    Transforming Health Research the first two years National Institute for Health Research Progress For Information R OCR R ef: 0 Gateway R ef: 9298 Title Transforming Health Research the first two years. Health Institute for Health Research Progress Report i Transforming Health Research the first two years National

  12. transform e Construction

    E-Print Network [OSTI]

    Cs√ľr√∂s, Mikl√≥s

    Abstraction by Symbolic Indexing Transformations Thomas F. Melham1 and Robert B. Jones2 1 describes some logical machinery aimed at bridging these gaps. We present an algorithm to transform ordinary-conditions that must hold for this transformation to be sound. We also describe how the algorithm can be applied

  13. Transformation and Quantization

    E-Print Network [OSTI]

    Yang, Shih-Hsuan

    ' & $ % Linear Transformations (Yet Again!!) Mark Gales CAMBRIDGE UNIVERSITY ENGINEERING DEPARTMENT mjfg@eng.cam.ac.uk 1 #12; ' & $ % Introduction Linear transformations within HMM systems have been shown to be very useful. ffl Adaptation: MLLR, SAT, CAT, Cluster Transform etc etc. ffl Feature space

  14. Transforming Anxiety into ENERGYTM

    E-Print Network [OSTI]

    Maryland, Baltimore County, University of

    Transforming Anxiety into ENERGYTM How to Prevent Panic and Promote Productivity in Turbulent Times By Wendy Mack with contributions from Meredith Kimbell and Myron Radio #12;Transforming Anxiety into Energy, consultants, and researchers who shared their stories and expertise. 1 #12;Transforming Anxiety into Energy

  15. Spacetime transformation acoustics

    E-Print Network [OSTI]

    C. GarcŪa-Meca; S. Carloni; C. Barcelů; G. Jannes; J. SŠnchez-Dehesa; A. MartŪnez

    2014-07-08T23:59:59.000Z

    A recently proposed analogue transformation method has allowed the extension of transformation acoustics to general spacetime transformations. We analyze here in detail the differences between this new analogue transformation acoustics (ATA) method and the standard one (STA). We show explicitly that STA is not suitable for transformations that mix space and time. ATA takes as starting point the acoustic equation for the velocity potential, instead of that for the pressure as in STA. This velocity-potential equation by itself already allows for some transformations mixing space and time, but not all of them. We explicitly obtain the entire set of transformations that do not leave its form invariant. It is in these cases that ATA shows its true potential, allowing for building a transformation acoustics method that enables the full range of spacetime transformations. We provide an example of an important transformation which cannot be achieved with STA. Using this transformation, we design and simulate an acoustic frequency converter via the ATA approach. Furthermore, in those cases in which one can apply both the STA and ATA approaches, we study the different transformational properties of the corresponding physical quantities.

  16. TRANSFORM a electronics

    E-Print Network [OSTI]

    Candan, Cagatay

    THE DISCRETE FRACTIONAL FOURIER TRANSFORM a thesis submitted to the department of electrical TRANSFORM C ¬ła~ gatay Candan M.S. in Electrical and Electronics Engineering Supervisor: Haldun M. ¬® Ozakta Transform (FrFT) is proposed, discussed and consolidated. The discrete trans¬≠ form generalizes the Discrete

  17. Transformation haskell-Programs

    E-Print Network [OSTI]

    √Ābrah√°m, Erika

    On the Transformation of Control Flow between Block-Oriented and Graph-Oriented Process Modeling E-mail: zdun@acm.org Abstract: Much recent research work discusses the transformation between differ. In this article, we aim to abstract from concrete transformations by distinguishing two major paradigms

  18. The Tunneling Transform

    E-Print Network [OSTI]

    Robert Hipple

    2014-11-10T23:59:59.000Z

    We supplement the Lorentz transform $L(v)$ with a new "Tunneling" transform $T(v)$. Application of this new transform to elementary quantum mechanics offers a novel, intuitive insight into the nature of quantum tunneling; in particular, the so called "Klein Paradox" is discussed.

  19. Transforming Data into Knowledge

    E-Print Network [OSTI]

    Giles, C. Lee

    The Application Of Correctness Preserving Transformations To Software Maintenance J. Paul Gibson transformation (CPT), to a real software engineering prob- lem: the need for optimization during the maintenance of code. We present four program transformations and a model that forms a framework for proof

  20. transforming human health

    E-Print Network [OSTI]

    Kenny, Paraic

    transforming human health AnnUAl REpoRt 2011­2012 #12;#12;how we're changing medical research 1 are transforming health. He proposed an entirely new theory for developing drugs to treat diseases that have malaria and solid tumors such as lung and breast cancers are in development. #12;A TrAnsformATive educ

  1. Transforming our information systems

    E-Print Network [OSTI]

    Strathclyde, University of

    Transforming our information systems and technology Information Systems Development Framework #12 university. In support of this position we are transforming our information systems, servicesDonald Principal and Vice-Chancellor #12;Strategy for transformation Tactical Delivering the services and tools our

  2. Transformer Addition Project near Page, Coconino County, Arizona

    Broader source: Energy.gov (indexed) [DOE]

    r * I. Categorical Exclusion for Glen Canyon 230138-kV Transformer Addition Project near Page, Coconino County, Arizona RECORD OF CATEGORICAL EXCLUSION DETERMINATION A. Proposed...

  3. Catalytic reactor for low-Btu fuels

    DOE Patents [OSTI]

    Smith, Lance (North Haven, CT); Etemad, Shahrokh (Trumbull, CT); Karim, Hasan (Simpsonville, SC); Pfefferle, William C. (Madison, CT)

    2009-04-21T23:59:59.000Z

    An improved catalytic reactor includes a housing having a plate positioned therein defining a first zone and a second zone, and a plurality of conduits fabricated from a heat conducting material and adapted for conducting a fluid therethrough. The conduits are positioned within the housing such that the conduit exterior surfaces and the housing interior surface within the second zone define a first flow path while the conduit interior surfaces define a second flow path through the second zone and not in fluid communication with the first flow path. The conduit exits define a second flow path exit, the conduit exits and the first flow path exit being proximately located and interspersed. The conduits define at least one expanded section that contacts adjacent conduits thereby spacing the conduits within the second zone and forming first flow path exit flow orifices having an aggregate exit area greater than a defined percent of the housing exit plane area. Lastly, at least a portion of the first flow path defines a catalytically active surface.

  4. Catalytic bromine recovery from HBr waste

    SciTech Connect (OSTI)

    Schubert, P.F.; Beatty, R.D.; Mahajan, S. [Catalytica Inc., Mountain View, CA (United States)

    1993-12-31T23:59:59.000Z

    Waste HBr is formed during the bromination of many organic molecules, such as flame retardants, pharmaceuticals, and agricultural chemicals. For over 50 years attempts to recover the bromine from waste HBr by catalytic oxidation have been unsuccessful due to low catalyst activity and stability. The discovery of a new high-activity catalysts with excellent long-term stability and life capable of high HBr conversion below 300{degrees}C has made catalytic oxidation of waste HBr commercially feasible. The oxidation of anhydrous HBr using oxygen is highly exothermic, giving an adiabatic temperature rise of 2000{degrees}C. Use of 48 wt% HBr in the oxidation reduces the adiabatic temperature rise to only 300{degrees}C. A multitubular heat exchanger type of reactor can then be used to manage the heat. A 5,000 kg/yr pilot plant was built to verify the performance of the catalyst, the suitability of the reactor materials of construction, and the multibular reactor concept. The pilot unit has a single full-scale reactor tube 4 m long and 2.54 cm in diameter with a hot oil jacket for heat management. Excellent catalyst stability was observed during a 600 h catalyst-life test. HBr conversion of 99% was maintained throughout the run, and over 360 kg of bromine was produced. The temperature at a localized hot spot near the reactor inlet was only 15-20{degrees}C above the reactor inlet temperature, indicating efficient heat management.

  5. Invertible Darboux Transformations

    E-Print Network [OSTI]

    Ekaterina Shemyakova

    2013-01-04T23:59:59.000Z

    For operators of many different kinds it has been proved that (generalized) Darboux transformations can be built using so called Wronskian formulae. Such Darboux transformations are not invertible in the sense that the corresponding mappings of the operator kernels are not invertible. The only known invertible ones were Laplace transformations (and their compositions), which are special cases of Darboux transformations for hyperbolic bivariate operators of order 2. In the present paper we find a criteria for a bivariate linear partial differential operator of an arbitrary order d to have an invertible Darboux transformation. We show that Wronkian formulae may fail in some cases, and find sufficient conditions for such formulae to work.

  6. Ability of Catalytic Converters to Reduce Air Pollution

    E-Print Network [OSTI]

    Nizkorodov, Sergey

    NOx - 1 Ability of Catalytic Converters to Reduce Air Pollution MEASUREMENT OF SELECTED AIR POLLUTANTS IN CAR EXHAUST Last updated: June 17, 2014 #12;NOx - 2 Ability of Catalytic Converters to Reduce Air Pollution MEASUREMENT OF SELECTED AIR POLLUTANTS IN CAR EXHAUST INTRODUCTION Automobile engines

  7. Catalytic Membrane Reactor for Extraction of Hydrogen from Bioethanol Reforming

    E-Print Network [OSTI]

    Kuncharam, Bhanu Vardhan

    2013-11-26T23:59:59.000Z

    -gas-shift catalytic membrane reactor, and (2) a multi-layer design for bioethanol reforming. A two-dimensional model is developed to describe reaction and diffusion in the catalytic membrane coupled with plug-flow equations in the retentate and permeate volumes using...

  8. Transformation Nets -A Runtime Model for Transformation Languages

    E-Print Network [OSTI]

    Hochreiter, Sepp

    Transformation Nets - A Runtime Model for Transformation Languages Johannes Schoenboeck Institute transformation languages. Although numerous approaches are available, they lack convenient facilities for supporting debugging and understand- ing of the transformation logic. This is not least because

  9. Correlations between surface structure and catalytic activity/selectivity. Progress report, January 1, 1994--December 31, 1994

    SciTech Connect (OSTI)

    Goodman, D.W.

    1994-09-01T23:59:59.000Z

    The primary focus of this research is to address those issues which are keys to understanding the relationship between surface properties and catalytic activity/selectivity. These issues also impact the understanding of the origins of the enhanced catalytic properties of mixed-metal catalysts. The experimental approach utilizes a microcatalytic reactor contiguous to a surface analysis system, an arrangement which allows in vacuo transfer of the catalyst from one chamber to the other. Surface techniques being used include Auger (AES), ultraviolet and X-ray photoemission spectroscopy (UPS and XPS), temperature programmed desorption (TPD), low energy electron diffraction (LEED), high resolution electron energy loss spectroscopy (HREELS), infrared reflection absorption spectroscopy (IRAS), and scanning tunneling and atomic force microscopy (STM and AFM). This research program builds upon previous experience relating the results of single crystal kinetic measurements with the results obtained with supported analogs. As well, the authors are exploiting recent work on the preparation, the characterization, and the determination of the catalytic properties of ultra-thin metal and metal oxide films. Specifically, the program is proceeding toward three goals: (1) the study of the unique catalytic properties of ultrathin metal films; (2) the investigation of the critical ensemble size requirements for principal catalytic reaction types; and (3) the modelling of supported catalysts using ultra-thin planar oxide surfaces.

  10. Correlations between surface structure and catalytic activity/selectivity. Progress report, January 1, 1992--December 31, 1992

    SciTech Connect (OSTI)

    Goodman, D.W.

    1992-10-01T23:59:59.000Z

    Objective is to address the keys to understanding the relation between surface structure and catalytic activity/selectivity. Of concern are questions related to enhanced catalytic properties of mixed-metal catalysts and critical active site requirements for molecular synthesis and rearrangement. The experimental approach utilizes a microcatalytic reactor contiguous to a surface analysis system, an arrangement which allows in vacuo transfer of the catalyst from one chamber to the other. Surface techniques being used include Auger (AES), UV and X-ray photoemission spectroscopy (UPS and XPS), temperature programmed desorption (TPD), low energy electron diffraction (LEED), high resolution electron energy loss spectroscopy (HREELS) and infrared reflection-absorption spectroscopy (IRAS). Our research program builds upon our previous experience relating the results of single crystal kinetic measurements with the results obtained with supported analogs. As well we are exploiting our recent work on the preparation, the characterization, and the determination of the catalytic properties of ultra-thin metal and metal oxide films. The program is proceeding toward the study of the unique catalytic properties of ultrathin metal films; the investigation of the critical ensemble size requirements for principal catalytic reaction types; and the modelling of supported catalysts using ultra-thin planar oxide surfaces.

  11. Preparation and characterization of VOx/TiO2 catalytic coatings on stainless steel plates for structured catalytic reactors.

    E-Print Network [OSTI]

    Boyer, Edmond

    for structured catalytic reactors. Thierry Giornelli, Axel Löfberg* and Elisabeth Bordes-Richard Unité de.Lofberg@univ-lille1.fr Abstract The parameters to be controlled to coat metallic walls by VOx/TiO2 catalysts which) was chosen because of its large application in industrial catalytic reactors. TiO2 films on stainless steel

  12. Catalytic cracking of residual petroleum fractions

    SciTech Connect (OSTI)

    Moore, H.F.; Mayo, S.L.; Goolsby, T.L. (Research and Development Dept., Ashland Petroleum Co., Ashland, KY (US))

    1991-01-01T23:59:59.000Z

    This paper reports on Arabian Light crude oil vacuum bottoms fractionated into five high-boiling fractions by wiped film evaporation, and the fractions subjected to catalytic cracking in a fixed-fluidized bed using a commercial equilibrium cracking catalyst. Density, aromaticity, and heteroatom content generally increased with boiling point, as did metals content except for vanadium and iron which demonstrated possible bimodal distributions. The cracking response of these fractions showed increasing yields of dry gas and coke, with decreasing gasoline yields, as a function of increasing apparent boiling point as would normally be expected. Surprisingly, however, local maxima were observed for wet gas yield and total conversion, with local minima for cycle oil and slurry yields, in the region of the 1200-1263{degrees}F (650-680{degrees}C) middle fraction. All fractions showed significant response to cracking, with coke yields generally being the only negative factor observed.

  13. Contact structure for use in catalytic distillation

    DOE Patents [OSTI]

    Jones, E.M. Jr.

    1984-03-27T23:59:59.000Z

    A method is described for conducting catalytic chemical reactions and fractionation of the reaction mixture comprising feeding reactants into a distillation column reactor, contracting said reactant in liquid phase with a fixed bed catalyst in the form of a contact catalyst structure consisting of closed porous containers containing the catalyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column. 7 figs.

  14. Contact structure for use in catalytic distillation

    DOE Patents [OSTI]

    Jones, E.M. Jr.

    1985-08-20T23:59:59.000Z

    A method and apparatus are disclosed for conducting catalytic chemical reactions and fractionation of the reaction mixture, comprising and feeding reactants into a distillation column reactor contracting said reactant in a liquid phase with a fixed bed catalyst in the form of a contact catalyst structure, consisting of closed porous containers containing the catalyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column. 7 figs.

  15. Contact structure for use in catalytic distillation

    DOE Patents [OSTI]

    Jones, Jr., Edward M. (Friendswood, TX)

    1984-01-01T23:59:59.000Z

    A method for conducting catalytic chemical reactions and fractionation of the reaction mixture comprising feeding reactants into a distillation column reactor contracting said reactant in liquid phase with a fixed bed catalyst in the form of a contact catalyst structure consisting of closed porous containers containing the catatlyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column.

  16. Contact structure for use in catalytic distillation

    DOE Patents [OSTI]

    Jones, Jr., Edward M. (Friendswood, TX)

    1985-01-01T23:59:59.000Z

    A method and apparatus for conducting catalytic chemical reactions and fractionation of the reaction mixture, comprising and feeding reactants into a distillation column reactor contracting said reactant in a liquid phase with a fixed bed catalyst in the form of a contact catalyst structure, consisting of closed porous containers containing the catalyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column.

  17. Fluid catalytic cracking of heavy petroleum fractions

    SciTech Connect (OSTI)

    McHenry, K.W.

    1981-06-30T23:59:59.000Z

    A process is claimed for fluid catalytic cracking of residuum and other heavy oils comprising of gas oil, petroleum residue, reduced and whole crudes and shale oil to produce gasoline and other liquid products which are separated in various streams in a fractionator and associated vapor recovery equipment. The heat from combustion of coke on the coked catalyst is removed by reacting sulfur-containing coke deposits with steam and oxygen in a separate stripper-gasifier to produce a low btu gas stream comprising of sulfur compounds, methane, carbon monoxide, hydrogen, and carbon dioxide at a temperature of from about 1100/sup 0/F. To about 2200/sup 0/F. The partially regenerated catalyst then undergoes complete carbon removal in a regeneration vessel. The regenerated catalyst is recycled for re-use in the cracking of heavy petroleum fractions. The liquid products are gasoline, distillates, heavy fuel oil, and light hydrocarbons.

  18. Catalytic cartridge SO/sub 3/ decomposer

    DOE Patents [OSTI]

    Galloway, T.R.

    1980-11-18T23:59:59.000Z

    A catalytic cartridge surrounding a heat pipe driven by a heat source is utilized as a SO/sub 3/ decomposer for thermochemical hydrogen production. The cartridge has two embodiments, a cross-flow cartridge and an axial flow cartridge. In the cross-flow cartridge, SO/sub 3/ gas is flowed through a chamber and incident normally to a catalyst coated tube extending through the chamber, the catalyst coated tube surrounding the heat pipe. In the axial-flow cartridge, SO/sub 3/ gas is flowed through the annular space between concentric inner and outer cylindrical walls, the inner cylindrical wall being coated by a catalyst and surrounding the heat pipe. The modular cartridge decomposer provides high thermal efficiency, high conversion efficiency, and increased safety. A fusion reactor may be used as the heat source.

  19. Catalytic carbon membranes for hydrogen production

    SciTech Connect (OSTI)

    Damle, A.S.; Gangwal, S.K.

    1992-01-01T23:59:59.000Z

    Commercial carbon composite microfiltration membranes may be modified for gas separation applications by providing a gas separation layer with pores in the 1- to 10-nm range. Several organic polymeric precursors and techniques for depositing a suitable layer were investigated in this project. The in situ polymerization technique was found to be the most promising, and pure component permeation tests with membrane samples prepared with this technique indicated Knudsen diffusion behavior. The gas separation factors obtained by mixed-gas permeation tests were found to depend strongly on gas temperature and pressure indicating significant viscous flow at high-pressure conditions. The modified membranes were used to carry out simultaneous water gas shift reaction and product hydrogen separation. These tests indicated increasing CO conversions with increasing hydrogen separation. A simple process model was developed to simulate a catalytic membrane reactor. A number of simulations were carried out to identify operating conditions leading to product hydrogen concentrations over 90 percent. (VC)

  20. Li?0? in Li-0? batteries : catalytic enhancement of electrochemical oxidation and thermophysical transformations

    E-Print Network [OSTI]

    Yao, Koffi Pierre (Koffi Pierre Claver)

    2013-01-01T23:59:59.000Z

    Electrification of transportation in the United States is of importance in reducing dependence on foreign oil and curtailing global warming. However, optimal market penetration of electric vehicles is confronted with the ...

  1. Catalytic Transformation of C7-C9 Methyl Benzenes over USY-based FCC Zeolite Catalyst

    E-Print Network [OSTI]

    Al-Khattaf, Sulaiman

    in the petrochemical market. Most of the currently working isomerization plants are using zeolite based catalysts. One

  2. Catalytic Transformation of Waste CO{sub 2} into Valuable Products

    SciTech Connect (OSTI)

    Anderson, Jason; Shepard, Peter; Valente, Ron

    2013-09-30T23:59:59.000Z

    Novomerís novel materials contain up to 50% by mass CO{sub 2} and provide a unique platform for re-using CO{sub 2} from waste industrial sources and converting it into useful products. This Report covers the progress made by Novomer during the DOE funded project (DOE Award #: DE-FE0002474) under the ďCarbon Capture and Sequestration from Industrial Sources and Innovative Concepts for Beneficial CO{sub 2} UseĒ program. This includes Phase 1 and Phase 2, including all three subphases of the latter. Novomer completed all technical and commercial objectives in both Phase 1 and Phase 2, including the six Phase 2 Objectives outlined in the SOPO within budget by the project end date of September 30, 2013. These are: validating the economics are competitive, validate the carbon footprint, validate acceptable product performance, verify robust manufacturing process, validate large markets exist, and qualify at least 3 products with customers.

  3. Superluminal transformations in complex Minkowski spaces

    SciTech Connect (OSTI)

    Ramon, C.; Rauscher, E.A.

    1980-08-01T23:59:59.000Z

    We calculate the mixing of real and imaginary components of space and time under the influence of superluminal boots in the x direction. A unique mixing is determined for this superluminal Lorentz transformation when we consider the symmetry properties afforded by the inclusion of three temporal directions. Superluminal transformations in complex six-dimensional space exhibit unique tachyonic connections which have both remote and local space--time event connections.

  4. Grid Transformation Workshop

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3-03-Grid-Transformation-Workshop Sign In About | Careers | Contact | Investors | bpa.gov Search News & Us Expand News & Us Projects & Initiatives Expand Projects &...

  5. Transforming a Transformative School | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-Up from theDepartment of EnergyThe Sun andDepartmentTransformationalTransforming a

  6. Sequential tasks performed by catalytic pumps for colloidal crystallization

    E-Print Network [OSTI]

    Ali Afshar Farniya; Maria J. Esplandiu; Adrian Bachtold

    2014-10-20T23:59:59.000Z

    Gold-platinum catalytic pumps immersed in a chemical fuel are used to manipulate silica colloids. The manipulation relies on the electric field and the fluid flow generated by the pump. Catalytic pumps perform various tasks, such as the repulsion of colloids, the attraction of colloids, and the guided crystallization of colloids. We demonstrate that catalytic pumps can execute these tasks sequentially over time. Switching from one task to the next is related to the local change of the proton concentration, which modifies the colloid zeta potential and consequently the electric force acting on the colloids.

  7. Final Technical Report [Development of Catalytic Alkylation and Fluoroalkylation Methods

    SciTech Connect (OSTI)

    Vicic, David A.

    2014-05-01T23:59:59.000Z

    In the early stages of this DOE-funded research project, we sought to prepare and study a well-defined nickel-alkyl complex containing tridentate nitrogen donor ligands. We found that reaction of (TMEDA)NiMe2 (1) with terpyridine ligand cleanly led to the formation of (terpyridyl)NiMe (2), which we also determined to be an active alkylation catalyst. The thermal stability of 2 was unlike that seen for any of the active pybox ligands, and enabled a number of key studies on alkyl transfer reactions to be performed, providing new insights into the mechanism of nickel-mediated alkyl-alkyl cross-coupling reactions. In addition to the mechanistic studies, we showed that the terpyridyl nickel compounds can catalytically cross-couple alkyl iodides in yields up to 98% and bromides in yields up to 46 %. The yields for the bromides can be increased up to 67 % when the new palladium catalyst [(tpyí)Pd-Ph]I is used. The best route to the targeted [(tpy)NiBr] (1) was found to involve the comproportionation reaction of [(dme)NiBr{sub 2}] and [Ni(COD){sub 2}] in the presence of two equivalents of terpyridine. This reaction was driven to high yields of product formation (72 % isolated) by the precipitation of 1 from THF solvent.

  8. Mercury Oxidation via Catalytic Barrier Filters Phase II

    SciTech Connect (OSTI)

    Wayne Seames; Michael Mann; Darrin Muggli; Jason Hrdlicka; Carol Horabik

    2007-09-30T23:59:59.000Z

    In 2004, the Department of Energy National Energy Technology Laboratory awarded the University of North Dakota a Phase II University Coal Research grant to explore the feasibility of using barrier filters coated with a catalyst to oxidize elemental mercury in coal combustion flue gas streams. Oxidized mercury is substantially easier to remove than elemental mercury. If successful, this technique has the potential to substantially reduce mercury control costs for those installations that already utilize baghouse barrier filters for particulate removal. Completed in 2004, Phase I of this project successfully met its objectives of screening and assessing the possible feasibility of using catalyst coated barrier filters for the oxidation of vapor phase elemental mercury in coal combustion generated flue gas streams. Completed in September 2007, Phase II of this project successfully met its three objectives. First, an effective coating method for a catalytic barrier filter was found. Second, the effects of a simulated flue gas on the catalysts in a bench-scale reactor were determined. Finally, the performance of the best catalyst was assessed using real flue gas generated by a 19 kW research combustor firing each of three separate coal types.

  9. Deployment & Market Transformation (Brochure)

    SciTech Connect (OSTI)

    Not Available

    2012-04-01T23:59:59.000Z

    NREL's deployment and market transformation (D and MT) activities encompass the laboratory's full range of technologies, which span the energy efficiency and renewable energy spectrum. NREL staff educates partners on how they can advance sustainable energy applications and also provides clients with best practices for reducing barriers to innovation and market transformation.

  10. Biochemical transformation of coals

    DOE Patents [OSTI]

    Lin, M.S.; Premuzic, E.T.

    1999-03-23T23:59:59.000Z

    A method of biochemically transforming macromolecular compounds found in solid carbonaceous materials, such as coal is provided. The preparation of new microorganisms, metabolically weaned through challenge growth processes to biochemically transform solid carbonaceous materials at extreme temperatures, pressures, pH, salt and toxic metal concentrations is also disclosed. 7 figs.

  11. TRANSFORMATION FOURIER--BOREL

    E-Print Network [OSTI]

    Waldschmidt, Michel

    LA TRANSFORMATION DE FOURIER--BOREL : ‚?? ‚?? de Hilbert est duale de celle de Gel'fond, tandis que la z e , t h d dz t dont la transforme ‚??e de Fourier--Borel est #(u) = q th u t e h#u . 0 1 #(## 0 # 1

  12. Transforming Education at Einstein

    E-Print Network [OSTI]

    Yates, Andrew

    Transforming Education at Einstein EinstEin Winter/spring 2012 The Magazine for Alumni and Friends trANsfOrMiNg eDuCAtiON At eiNsteiN Education at Albert Einstein College of Medicine is undergoing

  13. Amplified Quantum Transforms

    E-Print Network [OSTI]

    David Cornwell

    2014-06-01T23:59:59.000Z

    In this thesis we investigate two new Amplified Quantum Transforms. In particular we create and analyze the Amplified Quantum Fourier Transform (Amplified-QFT) and the Amplified-Haar Wavelet Transform. First, we provide a brief history of quantum mechanics and quantum computing. Second, we examine the Amplified-QFT in detail and compare it against the Quantum Fourier Transform (QFT) and Quantum Hidden Subgroup (QHS) algorithms for solving the Local Period Problem. We calculate the probabilities of success of each algorithm and show the Amplified-QFT is quadratically faster than the QFT and QHS algorithms. Third, we examine the Amplified-QFT algorithm for solving The Local Period Problem with an Error Stream. Fourth, we produce an uncertainty relation for the Amplified-QFT algorithm. Fifth, we show how the Amplified-Haar Wavelet Transform can solve the Local Constant or Balanced Signal Decision Problem which is a generalization of the Deutsch-Jozsa algorithm.

  14. Program Transformation Mechanics A Classification of Mechanisms for Program Transformation

    E-Print Network [OSTI]

    Utrecht, Universiteit

    Program Transformation Mechanics A Classification of Mechanisms for Program Transformation with a Survey of Existing Transformation Systems Jonne van Wijngaarden Eelco Visser UU-CS-2003-048 Institute Transformation Mechanics A Classification of Mechanisms for Program Transformation with a Survey of Existing

  15. Logarithmic transformation of response Logarithmic transformation of response

    E-Print Network [OSTI]

    Komarek, Arnost

    Logarithmic transformation of response Logarithmic transformation of response Often, support S of Y is S = (0, ). Logarithm is then one of transformations to consider when trying to obtain a correct (wrong. Model Building 1. Transformation of response #12;Logarithmic transformation of response When does

  16. IMAGINED TRANSFORMATIONS 1 Running head: IMAGINED TRANSFORMATION OF BODIES

    E-Print Network [OSTI]

    Zacks, Jeffrey M.

    IMAGINED TRANSFORMATIONS 1 Running head: IMAGINED TRANSFORMATION OF BODIES Imagined Transformations TRANSFORMATIONS 2 Abstract A number of spatial reasoning problems can be solved by performing an imagined transformation of one's egocentric perspective. A series of experiments were carried out to characterize

  17. Laplace Transforms (Ch. 7) LAPLACE TRANSFORMS (Ch. 7)

    E-Print Network [OSTI]

    Meade, Douglas B.

    Laplace Transforms (Ch. 7) LAPLACE TRANSFORMS (Ch. 7) ? restart; ? with( plots ): ? with( DEtools ): The Laplace transform is a very common, and useful, technique for solving and analyz­ ing the solution of the Laplace transform is that derivatives are transformed into powers; thus, the differential equation

  18. CATALYTIC MICROWAVE PYROLYSIS OF BIOMASS FOR RENEWABLE PHENOLS AND FUELS .

    E-Print Network [OSTI]

    [No author

    2013-01-01T23:59:59.000Z

    ??Bio-oil is an unstable intermediate and needs to be upgraded before its use. This study focused on improving the selectivity of bio-oilby catalytic pyrolysis ofÖ (more)

  19. atp catalytic domain: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    produc Kik, Pieter 328 Development of a catalytic combustion system for the MIT Micro Gas Turbine Engine MIT - DSpace Summary: As part of the MIT micro-gas turbine engine...

  20. acidic multimetallic catalytic: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    produc Kik, Pieter 106 Development of a catalytic combustion system for the MIT Micro Gas Turbine Engine MIT - DSpace Summary: As part of the MIT micro-gas turbine engine...

  1. automobile catalytic converters: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Odei 2006-01-01 408 Development of a catalytic combustion system for the MIT Micro Gas Turbine Engine MIT - DSpace Summary: As part of the MIT micro-gas turbine engine...

  2. atp catalytic cycle: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    produc Kik, Pieter 275 Development of a catalytic combustion system for the MIT Micro Gas Turbine Engine MIT - DSpace Summary: As part of the MIT micro-gas turbine engine...

  3. advanced catalytic hydrogenation: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    produc Kik, Pieter 188 Development of a catalytic combustion system for the MIT Micro Gas Turbine Engine MIT - DSpace Summary: As part of the MIT micro-gas turbine engine...

  4. apparent catalytic site: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    produc Kik, Pieter 257 Development of a catalytic combustion system for the MIT Micro Gas Turbine Engine MIT - DSpace Summary: As part of the MIT micro-gas turbine engine...

  5. advanced catalytic materials: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    produc Kik, Pieter 225 Development of a catalytic combustion system for the MIT Micro Gas Turbine Engine MIT - DSpace Summary: As part of the MIT micro-gas turbine engine...

  6. acrylamide catalytically inhibits: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    produc Kik, Pieter 78 Development of a catalytic combustion system for the MIT Micro Gas Turbine Engine MIT - DSpace Summary: As part of the MIT micro-gas turbine engine...

  7. assisted catalytic oxidation: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    produc Kik, Pieter 251 Development of a catalytic combustion system for the MIT Micro Gas Turbine Engine MIT - DSpace Summary: As part of the MIT micro-gas turbine engine...

  8. active catalytic sites: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    produc Kik, Pieter 337 Development of a catalytic combustion system for the MIT Micro Gas Turbine Engine MIT - DSpace Summary: As part of the MIT micro-gas turbine engine...

  9. atpase catalytic domain: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    produc Kik, Pieter 266 Development of a catalytic combustion system for the MIT Micro Gas Turbine Engine MIT - DSpace Summary: As part of the MIT micro-gas turbine engine...

  10. advanced catalytic materials 1996: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    produc Kik, Pieter 467 Development of a catalytic combustion system for the MIT Micro Gas Turbine Engine MIT - DSpace Summary: As part of the MIT micro-gas turbine engine...

  11. archaeal primase catalytic: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    produc Kik, Pieter 92 Development of a catalytic combustion system for the MIT Micro Gas Turbine Engine MIT - DSpace Summary: As part of the MIT micro-gas turbine engine...

  12. advanced catalytic science: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    produc Kik, Pieter 488 Development of a catalytic combustion system for the MIT Micro Gas Turbine Engine MIT - DSpace Summary: As part of the MIT micro-gas turbine engine...

  13. Catalyst Cartography: 3D Super-Resolution Mapping of Catalytic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Catalyst Cartography: 3D Super-Resolution Mapping of Catalytic Activity Thanks to a groundbreaking new method, scientists have created the first 3D super-resolution maps of...

  14. Hydrogen permeable protective coating for a catalytic surface

    DOE Patents [OSTI]

    Liu, Ping (Irvine, CA); Tracy, C. Edwin (Golen, CO); Pitts, J. Roland (Lakewood, CO); Lee, Se-Hee (Lakewood, CO)

    2007-06-19T23:59:59.000Z

    A protective coating for a surface comprising a layer permeable to hydrogen, said coating being deposited on a catalyst layer; wherein the catalytic activity of the catalyst layer is preserved.

  15. In situ XAS Characterization of Catalytic Nano-Materials with...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    XAS Characterization of Catalytic Nano-Materials with Applications to Fuel Cells and Batteries Friday, July 12, 2013 - 11:00am SLAC, Conference Room 137-322 Presented by Qingying...

  16. Catalytic H2O2 decomposition on palladium surfaces

    E-Print Network [OSTI]

    Salinas, S. Adriana

    1998-01-01T23:59:59.000Z

    The catalytic decomposition of H?O? at smooth single-crystal and polycrystalline palladium surfaces that had been subjected to various surface modifications has been studied. Monolayer and submonolayer coverages of I, Br and Cl adsorbates were used...

  17. Catalytic pyrolysis using UZM-39 aluminosilicate zeolite

    SciTech Connect (OSTI)

    Nicholas, Christopher P; Boldingh, Edwin P

    2014-10-07T23:59:59.000Z

    A new family of coherently grown composites of TUN and IMF zeotypes has been synthesized and shown to be effective catalysts for catalytic pyrolysis of biomass. These zeolites are represented by the empirical formula. Na.sub.nM.sub.m.sup.n+R.sub.rQ.sub.qAl.sub.1-xE.sub.xSi.sub.yO.s- ub.z where M represents zinc or a metal or metals from Group 1, Group 2, Group 3 or the lanthanide series of the periodic table, R is an A,.OMEGA.-dihalosubstituted paraffin such as 1,4-dibromobutane, Q is a neutral amine containing 5 or fewer carbon atoms such as 1-methylpyrrolidine and E is a framework element such as gallium. The process involves contacting a carbonaceous biomass feedstock with UZM-39 at pyrolysis conditions to produce pyrolysis gases comprising hydrocarbons. The catalyst catalyzes a deoxygenation reaction converting oxygenated hydrocarbons into hydrocarbons and removing the oxygen as carbon oxides and water. A portion of the pyrolysis gases is condensed to produce low oxygen biomass-derived pyrolysis oil.

  18. Catalytic pyrolysis using UZM-39 aluminosilicate zeolite

    DOE Patents [OSTI]

    Nicholas, Christpher P; Boldingh, Edwin P

    2013-12-17T23:59:59.000Z

    A new family of coherently grown composites of TUN and IMF zeotypes has been synthesized and show to be effective catalysts for catalytic pyrolysis of biomass. These zeolites are represented by the empirical formula. Na.sub.nM.sub.m.sup.n+R.sub.rQ.sub.qAl.sub1-xE.sub.xSi.sub.yO.s- ub.z where M represents zinc or a metal or metals from Group 1, Group 2, Group 3 or the lanthanide series of the periodic table, R is an A,.OMEGA.-dihalosubstituted paraffin such as 1,4-dibromobutane, Q is a neutral amine containing 5 or fewer carbon atoms such as 1-methylpyrrolidine and E is a framework element such as gallium. The process involves contacting a carbonaceous biomass feedstock with UZM-39 at pyrolysis conditions to produce pyrolysis gases comprising hydrocarbons. The catalyst catalyzes a deoxygenation reaction converting oxygenated hyrdocarbons into hydrocarbons removing the oxygen as carbon oxides and water. A portion of the pyrolysis gases is condensed to produce low oxygen biomass-derived pyrolysis oil.

  19. Catalytic Reactor For Oxidizing Mercury Vapor

    DOE Patents [OSTI]

    Helfritch, Dennis J. (Baltimore, MD)

    1998-07-28T23:59:59.000Z

    A catalytic reactor (10) for oxidizing elemental mercury contained in flue gas is provided. The catalyst reactor (10) comprises within a flue gas conduit a perforated corona discharge plate (30a, b) having a plurality of through openings (33) and a plurality of projecting corona discharge electrodes (31); a perforated electrode plate (40a, b, c) having a plurality of through openings (43) axially aligned with the through openings (33) of the perforated corona discharge plate (30a, b) displaced from and opposing the tips of the corona discharge electrodes (31); and a catalyst member (60a, b, c, d) overlaying that face of the perforated electrode plate (40a, b, c) opposing the tips of the corona discharge electrodes (31). A uniformly distributed corona discharge plasma (1000) is intermittently generated between the plurality of corona discharge electrode tips (31) and the catalyst member (60a, b, c, d) when a stream of flue gas is passed through the conduit. During those periods when corona discharge (1000) is not being generated, the catalyst molecules of the catalyst member (60a, b, c, d) adsorb mercury vapor contained in the passing flue gas. During those periods when corona discharge (1000) is being generated, ions and active radicals contained in the generated corona discharge plasma (1000) desorb the mercury from the catalyst molecules of the catalyst member (60a, b, c, d), oxidizing the mercury in virtually simultaneous manner. The desorption process regenerates and activates the catalyst member molecules.

  20. Microchannel Reactor System for Catalytic Hydrogenation

    SciTech Connect (OSTI)

    Adeniyi Lawal; Woo Lee; Ron Besser; Donald Kientzler; Luke Achenie

    2010-12-22T23:59:59.000Z

    We successfully demonstrated a novel process intensification concept enabled by the development of microchannel reactors, for energy efficient catalytic hydrogenation reactions at moderate temperature, and pressure, and low solvent levels. We designed, fabricated, evaluated, and optimized a laboratory-scale microchannel reactor system for hydrogenation of onitroanisole and a proprietary BMS molecule. In the second phase of the program, as a prelude to full-scale commercialization, we designed and developed a fully-automated skid-mounted multichannel microreactor pilot plant system for multiphase reactions. The system is capable of processing 1 Ė 10 kg/h of liquid substrate, and an industrially relevant immiscible liquid-liquid was successfully demonstrated on the system. Our microreactor-based pilot plant is one-of-akind. We anticipate that this process intensification concept, if successfully demonstrated, will provide a paradigm-changing basis for replacing existing energy inefficient, cost ineffective, environmentally detrimental slurry semi-batch reactor-based manufacturing practiced in the pharmaceutical and fine chemicals industries.

  1. Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway

    SciTech Connect (OSTI)

    Biddy, M.; Jones, S.

    2013-03-01T23:59:59.000Z

    This technology pathway case investigates the catalytic conversion of solubilized carbohydrate streams to hydrocarbon biofuels, utilizing data from recent efforts within the National Advanced Biofuels Consortium (NABC) in collaboration with Virent, Inc. Technical barriers and key research needs that should be pursued for the catalytic conversion of sugars pathway to be competitive with petroleum-derived gasoline-, diesel-, and jet-range hydrocarbon blendstocks have been identified.

  2. Catalytic and physicochemical properties of aluminoplatinum catalysts modified with indium and gallium

    SciTech Connect (OSTI)

    Zaitsev, A.V.; Tyupaev, A.P.; Borovkov, V.Yu.; Timofeeva, E.A.; Isatulyants, G.V.; Kazanskii, B.B.

    1986-10-10T23:59:59.000Z

    Aluminoplatinum catalysts (APC) are widely used in transformations of hydrocarbons, particularly in reforming of gasoline fractions and dehydrogenation of higher normal paraffins. Promotion of APC with indium and gallium increases their activity and stability in the dehydrogenation of paraffins. Introduction of group III elements in APC inhibits coke formation during dehydrogenation and prevents blocking of the surface of the Pt. The change in the catalytic properties of APC modified with In is due to the partial transfer of the electron density from Pt to In. Both APC with In and Ga additives and monometallic catalysts were studied in the present article by the methods of IR spectroscopy and adsorption. In addition to traditional transmission IR spectroscopy, IR spectroscopy in diffusely scattered light was used, which permits conducting both spectral and adsorption measurements on the same samples.

  3. Effects of dispersion and support on adsorption, catalytic and electronic properties of cobalt/alumina CO hydrogenation catalysts: (Technical progress report)

    SciTech Connect (OSTI)

    Bartholomew, C.H. Jr.

    1986-12-22T23:59:59.000Z

    The continued investigation of dispersion and metal-support interactions and their effects upon the adsorption, activity/selectivity, and electronic properties of the metal in cobalt/alumina (and to a lesser extent on iron/alumina) catalysts is proposed. The objectives of this research are to determine the effects of surface structure and metal dispersion on the adsorption and catalytic properties of cobalt, and determine the effects of metal-support interactions, i.e., effects of decorating support species on metal crystallites and of direct electronic interactions between metal clusters and the support, on the adsoprtion, catalytic and electronic properties of cobalt supported on alumina.

  4. A discrete fractional random transform

    E-Print Network [OSTI]

    Zhengjun Liu; Haifa Zhao; Shutian Liu

    2006-05-20T23:59:59.000Z

    We propose a discrete fractional random transform based on a generalization of the discrete fractional Fourier transform with an intrinsic randomness. Such discrete fractional random transform inheres excellent mathematical properties of the fractional Fourier transform along with some fantastic features of its own. As a primary application, the discrete fractional random transform has been used for image encryption and decryption.

  5. Transformer Abdullah Al-Otaibi

    E-Print Network [OSTI]

    Masoudi, Husain M.

    Transformer Abdullah Al-Otaibi ID#242374 Section#2 Abstract- this is a brief description for transformer and how it works. I. DEFINITION A transformer is a device that transfers electrical energy from of the transformer in 1831. The transformer is used by Faraday only to demonstrate the principle of electromagnetic

  6. Lorentz transformation by mimicking the Lorentz transformation

    E-Print Network [OSTI]

    Bernhard Rothenstein; Stefan Popescu

    2007-09-24T23:59:59.000Z

    We show that starting with the fact that special relativity theory is concerned with a distortion of the observed length of a moving rod, without mentioning if it is a "contraction" or "dilation", we can derive the Lorentz transformations for the spacetime coordinates of the same event. This derivation is based on expressing the length of the moving rod as a sum of components with all the lengths involved in this summation being measured by the observers of the same inertial reference frame.

  7. Synthesis and characterization of supported heteropolymolybdate nanoparticles between silicate layers of Bentonite with enhanced catalytic activity for epoxidation of alkenes

    SciTech Connect (OSTI)

    Salavati, Hossein, E-mail: hosseinsalavati@yahoo.com [Department of Chemistry, Payame Noor University (PNU), 19395-4697, Tehran, Islamic Republic of Iran (Iran, Islamic Republic of)] [Department of Chemistry, Payame Noor University (PNU), 19395-4697, Tehran, Islamic Republic of Iran (Iran, Islamic Republic of); Rasouli, Nahid [Department of Chemistry, Payame Noor University (PNU), 19395-4697, Tehran, Islamic Republic of Iran (Iran, Islamic Republic of)] [Department of Chemistry, Payame Noor University (PNU), 19395-4697, Tehran, Islamic Republic of Iran (Iran, Islamic Republic of)

    2011-11-15T23:59:59.000Z

    Highlights: {yields} The PVMo and nanocomposite catalyst (PVMo/Bentonite) as catalyst for epoxidation of alkenes. {yields} The composite catalyst showed higher catalytic activity than parent heteropolymolybdate (PVMo). {yields}The use of ultrasonic irradiation increased the conversions and reduced the reaction times. {yields} The H{sub 2}O{sub 2} is a green and eco-friendly oxidant in this catalytic system. -- Abstract: A new heterogeneous catalyst (PVMo/Bentonite) consisting of vanadium substituted heteropolymolybdate with Keggin-type structure Na{sub 5}[PV{sub 2}Mo{sub 10}O{sub 40}].14H{sub 2}O (PVMo) supported between silicate layers of bentonite has been synthesized by impregnation method and characterized using X-ray diffraction, Fourier-transformed infrared spectroscopy, scanning electron microscopy, UV-vis diffuse reflectance spectroscopy, transmission electron microscopy and elemental analysis. X-ray diffraction and scanning electron microscopy analysis indicated that PVMo was finely dispersed into layers of bentonite as support. The PVMo/Bentonite used as an efficient heterogeneous catalyst for epoxidation of alkenes. Various cyclic and linear alkenes were oxidized into the corresponding epoxides in high yields and selectivity with 30% aqueous H{sub 2}O{sub 2}. The catalyst was reused several times, without observable loss of activity and selectivity. The obtained results showed that the catalytic activity of the PVMo/Bentonite was higher than that of pure heteropolyanion (PVMo).

  8. TRANSFORMATIONS 4.1 TRANSFORMATIONS, ISOMETRIES. The term transformation has several

    E-Print Network [OSTI]

    1 Chapter 4 TRANSFORMATIONS 4.1 TRANSFORMATIONS, ISOMETRIES. The term transformation has several. On the other hand, in linear algebra courses a linear transformation maps vectors to vectors and subspaces to subspaces. When we use the term transformation in geometry, however, we have all of these interpretations

  9. Linear Transformer Ideal Transformer Consider linear and ideal transformers attached to Circuit 1 and Circuit 2.

    E-Print Network [OSTI]

    Kozick, Richard J.

    Linear Transformer Ideal Transformer I1 + V2 _ + V1 _ Consider linear and ideal transformers in linear transformer equations for :MLL ,, 21 ( ) ( ) ( ) ( ) ( ) ( ) 12212212 2 1 112 2 12 2 1 2212 2 PP Now solve the linear transformer equations for the currents: 1 212 2 22 2 1 2 1 212 2 22 12 2 2 2

  10. Transforming California's Freight Transport System

    E-Print Network [OSTI]

    California at Davis, University of

    Transforming California's Freight Transport System Policy Forum on the Role of Freight Transport Standard #12;2050 Vision- Key Conceptual Outcomes Technology Transformation Early Action Cleaner Combustion Multiple Strategies Federal Action Efficiency Gains Energy Transformation 9 #12;Further reduce localized

  11. Plasma-assisted catalytic storage reduction system

    DOE Patents [OSTI]

    Penetrante, Bernardino M. (San Ramon, CA); Vogtlin, George E. (Fremont, CA); Merritt, Bernard T. (Livermore, CA); Brusasco, Raymond M. (Livermore, CA)

    2002-01-01T23:59:59.000Z

    A two-stage method for NO.sub.x reduction in an oxygen-rich engine exhaust comprises a plasma oxidative stage and a storage reduction stage. The first stage employs a non-thermal plasma treatment of NO.sub.x gases in an oxygen-rich exhaust and is intended to convert NO to NO.sub.2 in the presence of O.sub.2 and hydrocarbons. The second stage employs a lean NO.sub.x trap to convert such NO.sub.2 to environmentally benign gases that include N.sub.2, CO.sub.2, and H.sub.2 O. By preconverting NO to NO.sub.2 in the first stage with a plasma, the efficiency of the second stage for NO.sub.x reduction is enhanced. For example, an internal combustion engine exhaust is connected by a pipe to a first chamber in which a non-thermal plasma converts NO to NO.sub.2 in the presence of O.sub.2 and hydrocarbons, such as propene. A flow of such hydrocarbons (C.sub.x H.sub.y) is input from usually a second pipe into at least a portion of the first chamber. The NO.sub.2 from the plasma treatment proceeds to a storage reduction catalyst (lean NO.sub.x trap) that converts NO.sub.2 to N.sub.2, CO.sub.2, and H.sub.2 O, and includes a nitrate-forming catalytic site. The hydrocarbons and NO.sub.x are simultaneously reduced while passing through the lean-NO.sub.x trap catalyst. The method allows for enhanced NO.sub.x reduction in vehicular engine exhausts, particularly those having relatively high sulfur contents.

  12. Plasma-assisted catalytic storage reduction system

    DOE Patents [OSTI]

    Penetrante, Bernardino M. (San Ramon, CA); Vogtlin, George E. (Fremont, CA); Merritt, Bernard T. (Livermore, CA); Brusasco, Raymond M. (Livermore, CA)

    2000-01-01T23:59:59.000Z

    A two-stage method for NO.sub.x reduction in an oxygen-rich engine exhaust comprises a plasma oxidative stage and a storage reduction stage. The first stage employs a non-thermal plasma treatment of NO.sub.x gases in an oxygen-rich exhaust and is intended to convert NO to NO.sub.2 in the presence of O.sub.2 and hydrocarbons. The second stage employs a lean NO.sub.x trap to convert such NO.sub.2 to environmentally benign gases that include N.sub.2, CO.sub.2, and H.sub.2 O. By preconverting NO to NO.sub.2 in the first stage with a plasma, the efficiency of the second stage for NO.sub.x reduction is enhanced. For example, an internal combustion engine exhaust is connected by a pipe to a first chamber in which a non-thermal plasma converts NO to NO.sub.2 in the presence of O.sub.2 and hydrocarbons, such as propene. A flow of such hydrocarbons (C.sub.x H.sub.y) is input from usually a second pipe into at least a portion of the first chamber. The NO.sub.2 from the plasma treatment proceeds to a storage reduction catalyst (lean NO.sub.x trap) that converts NO.sub.2 to N.sub.2, CO.sub.2, and H.sub.2 O, and includes a nitrate-forming catalytic site. The hydrocarbons and NO.sub.x are simultaneously reduced while passing through the lean-NO.sub.x trap catalyst. The method allows for enhanced NO.sub.x reduction in vehicular engine exhausts, particularly those having relatively high sulfur contents.

  13. The Quantum Mellin transform

    E-Print Network [OSTI]

    J. Twamley; G. J. Milburn

    2007-02-12T23:59:59.000Z

    We uncover a new type of unitary operation for quantum mechanics on the half-line which yields a transformation to ``Hyperbolic phase space''. We show that this new unitary change of basis from the position x on the half line to the Hyperbolic momentum $p_\\eta$, transforms the wavefunction via a Mellin transform on to the critial line $s=1/2-ip_\\eta$. We utilise this new transform to find quantum wavefunctions whose Hyperbolic momentum representation approximate a class of higher transcendental functions, and in particular, approximate the Riemann Zeta function. We finally give possible physical realisations to perform an indirect measurement of the Hyperbolic momentum of a quantum system on the half-line.

  14. Transformation inverse design

    E-Print Network [OSTI]

    Liu, David

    We present a new technique for the design of transformation-optics devices based on large-scale optimization to achieve the optimal effective isotropic dielectric materials within prescribed index bounds, which is ...

  15. Hydrothermal synthesis and catalytic properties of {alpha}- and {beta}-MnO{sub 2} nanorods

    SciTech Connect (OSTI)

    Cao, Guangsheng, E-mail: daqingcgs@163.com [Key Laboratory of Enhanced Oil and Gas Recovery of Ministry of Education, Daqing Petroleum Institute, Daqing 163318 (China)] [Key Laboratory of Enhanced Oil and Gas Recovery of Ministry of Education, Daqing Petroleum Institute, Daqing 163318 (China); Su, Ling; Zhang, Xiaojuan; Li, Hui [Key Laboratory of Enhanced Oil and Gas Recovery of Ministry of Education, Daqing Petroleum Institute, Daqing 163318 (China)] [Key Laboratory of Enhanced Oil and Gas Recovery of Ministry of Education, Daqing Petroleum Institute, Daqing 163318 (China)

    2010-04-15T23:59:59.000Z

    One-dimensional {alpha}-MnO{sub 2} and {beta}-MnO{sub 2} single-crystalline nanostructures were prepared by hydrothermal process. The products were characterized in detail by multiform techniques: X-ray diffraction, scanning electron microscopy, and transmission electron microscopy. Experimental results indicate that the temperature plays important roles in determining produce {alpha}-MnO{sub 2} and {beta}-MnO{sub 2} nanorods. In addition, the as-prepared {alpha}-MnO{sub 2} and {beta}-MnO{sub 2} nanorods showed excellent catalytic performance in the Fenton-like reaction.

  16. Series Transmission Line Transformer

    DOE Patents [OSTI]

    Buckles, Robert A. (Livermore, CA); Booth, Rex (Livermore, CA); Yen, Boris T. (El Cerrito, CA)

    2004-06-29T23:59:59.000Z

    A series transmission line transformer is set forth which includes two or more of impedance matched sets of at least two transmissions lines such as shielded cables, connected in parallel at one end ans series at the other in a cascading fashion. The cables are wound about a magnetic core. The series transmission line transformer (STLT) which can provide for higher impedance ratios and bandwidths, which is scalable, and which is of simpler design and construction.

  17. CX-010981: Categorical Exclusion Determination | Department of...

    Broader source: Energy.gov (indexed) [DOE]

    Determination High-Throughput Study of Diffusion and Phase Transformation Kinetics of Magnesium-Based Systems... CX(s) Applied: A9 Date: 09132013 Location(s): Wisconsin...

  18. CX-011647: Categorical Exclusion Determination | Department of...

    Broader source: Energy.gov (indexed) [DOE]

    CX-011647: Categorical Exclusion Determination Replacement of Big Hill TX-14 Transformer, Government Furnished Equipment CX(s) Applied: B1.3 Date: 10312013 Location(s):...

  19. CX-000554: Categorical Exclusion Determination | Department of...

    Broader source: Energy.gov (indexed) [DOE]

    CX-000554: Categorical Exclusion Determination Ogallala Substation KY1A Transformer Replacement CX(s) Applied: B4.6 Date: 11162009 Location(s): Ogallala, Nebraska...

  20. CX-009224: Categorical Exclusion Determination | Department of...

    Broader source: Energy.gov (indexed) [DOE]

    CX-009224: Categorical Exclusion Determination Project L-718, Electrical Utilities Transformer Management Support Facility CX(s) Applied: B1.15 Date: 09042012 Location(s):...

  1. CX-008826: Categorical Exclusion Determination | Department of...

    Broader source: Energy.gov (indexed) [DOE]

    Categorical Exclusion Determination Remanufacture, Transport, and Install BHTX-29 Transformer CX(s) Applied: B1.3 Date: 07172012 Location(s): Texas Offices(s): Strategic...

  2. Central Moloney: Noncompliance Determination (2013-SE-4702) ...

    Broader source: Energy.gov (indexed) [DOE]

    Determination to Central Moloney, Inc. finding that liquid-immersed distribution transformer basic models 30300150 and 32500095 do not comport with the energy conservation...

  3. CX-007160: Categorical Exclusion Determination | Department of...

    Broader source: Energy.gov (indexed) [DOE]

    Exclusion Determination Pinnacle Peak Substation Coupling Capacitor Voltage Transformer Installation CX(s) Applied: B4.6 Date: 05102010 Location(s): Maricopa County,...

  4. Ultra Low NOx Catalytic Combustion for IGCC Power Plants

    SciTech Connect (OSTI)

    Shahrokh Etemad; Benjamin Baird; Sandeep Alavandi; William Pfefferle

    2008-03-31T23:59:59.000Z

    In order to meet DOE's goals of developing low-emissions coal-based power systems, PCI has further developed and adapted it's Rich-Catalytic Lean-burn (RCL{reg_sign}) catalytic reactor to a combustion system operating on syngas as a fuel. The technology offers ultra-low emissions without the cost of exhaust after-treatment, with high efficiency (avoidance of after-treatment losses and reduced diluent requirements), and with catalytically stabilized combustion which extends the lower Btu limit for syngas operation. Tests were performed in PCI's sub-scale high-pressure (10 atm) test rig, using a two-stage (catalytic then gas-phase) combustion process for syngas fuel. In this process, the first stage consists of a fuel-rich mixture reacting on a catalyst with final and excess combustion air used to cool the catalyst. The second stage is a gas-phase combustor, where the air used for cooling the catalyst mixes with the catalytic reactor effluent to provide for final gas-phase burnout and dilution to fuel-lean combustion products. During testing, operating with a simulated Tampa Electric's Polk Power Station syngas, the NOx emissions program goal of less than 0.03 lbs/MMBtu (6 ppm at 15% O{sub 2}) was met. NOx emissions were generally near 0.01 lbs/MMBtu (2 ppm at 15% O{sub 2}) (PCI's target) over a range on engine firing temperatures. In addition, low emissions were shown for alternative fuels including high hydrogen content refinery fuel gas and low BTU content Blast Furnace Gas (BFG). For the refinery fuel gas increased resistance to combustor flashback was achieved through preferential consumption of hydrogen in the catalytic bed. In the case of BFG, stable combustion for fuels as low as 88 BTU/ft{sup 3} was established and maintained without the need for using co-firing. This was achieved based on the upstream catalytic reaction delivering a hotter (and thus more reactive) product to the flame zone. The PCI catalytic reactor was also shown to be active in ammonia reduction in fuel allowing potential reductions in the burner NOx production. These reductions of NOx emissions and expanded alternative fuel capability make the rich catalytic combustor uniquely situated to provide reductions in capital costs through elimination of requirements for SCR, operating costs through reduction in need for NOx abating dilution, SCR operating costs, and need for co-firing fuels allowing use of lower value but more available fuels, and efficiency of an engine through reduction in dilution flows.

  5. APPENDIX F. TRANSFORMS, COMPLEX ANALYSIS 1 Transforms, Complex

    E-Print Network [OSTI]

    Callen, James D.

    APPENDIX F. TRANSFORMS, COMPLEX ANALYSIS 1 Appendix F Transforms, Complex Analysis This appendix discusses Fourier and Laplace transforms as they are used in plasma physics and this book. Also, key properties of complex variable theory that are needed for understanding and inverting these transforms

  6. From transformation traces to transformation rules: Assisting Model Driven Engineering

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    From transformation traces to transformation rules: Assisting Model Driven Engineering approach. In this paper we are interested in semi-automatically gen- erating labelled graph (model) transformations conform to a particu- lar syntax (meta-model). Those transformations are basic operations in model driven

  7. Optical transformation from chirplet to fractional Fourier transformation kernel

    E-Print Network [OSTI]

    Hong-yi Fan; Li-yun Hu

    2009-02-11T23:59:59.000Z

    We find a new integration transformation which can convert a chirplet function to fractional Fourier transformation kernel, this new transformation is invertible and obeys Parseval theorem. Under this transformation a new relationship between a phase space function and its Weyl-Wigner quantum correspondence operator is revealed.

  8. Laplace Transforms An integral transform is an operator

    E-Print Network [OSTI]

    Ikenaga, Bruce

    9­28­1998 Laplace Transforms An integral transform is an operator F (s) = Z b a K(s; t)f(t) dt: The input to the transform is the function f(t); the output is the function F (s). (By convention, small letters denote the inputs to a transform, and the corresponding capital letters denote the corresponding

  9. Transform Coding: Past, Present, and Future Transforms are perva-

    E-Print Network [OSTI]

    Vetterli, Martin

    Transform Coding: Past, Present, and Future Transforms are perva- sive in signal process- ing) and wavelets are part of the widely used JPEG standards, transforms are at the heart of the compression engine of transforms in compression, and the flurry of activ- ity in both research and applications around signal

  10. Early diagenetic transformations of peat Original research

    E-Print Network [OSTI]

    Paris-Sud XI, Universitť de

    Early diagenetic transformations of peat Original research Organic matter sources and decay;KEY WORDS: bioindicators - carbohydrates - labile organic matter - peat botanical composition to the fate of organic matter (OM) in the underlying peat. Our aims were to determine how moisture conditions

  11. CATALYTIC GASIFICATION OF COAL USING EUTECTIC SALT MIXTURES

    SciTech Connect (OSTI)

    Dr. Yaw D. Yeboah; Dr. Yong Xu; Dr. Atul Sheth; Dr. Pradeep Agrawal

    2001-12-01T23:59:59.000Z

    The Gas Research Institute (GRI) estimates that by the year 2010, 40% or more of U.S. gas supply will be provided by supplements including substitute natural gas (SNG) from coal. These supplements must be cost competitive with other energy sources. The first generation technologies for coal gasification e.g. the Lurgi Pressure Gasification Process and the relatively newer technologies e.g. the KBW (Westinghouse) Ash Agglomerating Fluidized-Bed, U-Gas Ash Agglomerating Fluidized-Bed, British Gas Corporation/Lurgi Slagging Gasifier, Texaco Moving-Bed Gasifier, and Dow and Shell Gasification Processes, have several disadvantages. These disadvantages include high severities of gasification conditions, low methane production, high oxygen consumption, inability to handle caking coals, and unattractive economics. Another problem encountered in catalytic coal gasification is deactivation of hydroxide forms of alkali and alkaline earth metal catalysts by oxides of carbon (CO{sub x}). To seek solutions to these problems, a team consisting of Clark Atlanta University (CAU, a Historically Black College and University, HBCU), the University of Tennessee Space Institute (UTSI) and Georgia Institute of Technology (Georgia Tech) proposed to identify suitable low melting eutectic salt mixtures for improved coal gasification. The research objectives of this project were to: Identify appropriate eutectic salt mixture catalysts for coal gasification; Assess agglomeration tendency of catalyzed coal; Evaluate various catalyst impregnation techniques to improve initial catalyst dispersion; Determine catalyst dispersion at high carbon conversion levels; Evaluate effects of major process variables (such as temperature, system pressure, etc.) on coal gasification; Evaluate the recovery, regeneration and recycle of the spent catalysts; and Conduct an analysis and modeling of the gasification process to provide better understanding of the fundamental mechanisms and kinetics of the process.

  12. Effect of surface structure on catalytic reactions: A sum frequency generation surface vibrational spectroscopy study

    SciTech Connect (OSTI)

    McCrea, Keith R.

    2001-09-07T23:59:59.000Z

    In the results discussed above, it is clear that Sum Frequency Generation (SFG) is a unique tool that allows the detection of vibrational spectra of adsorbed molecules present on single crystal surfaces under catalytic reaction conditions. Not only is it possible to detect active surface intermediates, it is also possible to detect spectator species which are not responsible for the measured turnover rates. By correlating high-pressure SFG spectra under reaction conditions and gas chromatography (GC) kinetic data, it is possible to determine which species are important under reaction intermediates. Because of the flexibility of this technique for studying surface intermediates, it is possible to determine how the structures of single crystal surfaces affect the observed rates of catalytic reactions. As an example of a structure insensitive reaction, ethylene hydrogenation was explored on both Pt(111) and Pt(100). The rates were determined to be essentially the same. It was observed that both ethylidyne and di-{sigma} bonded ethylene were present on the surface under reaction conditions on both crystals, although in different concentrations. This result shows that these two species are not responsible for the measured turnover rate, as it would be expected that one of the two crystals would be more active than the other, since the concentration of the surface intermediate would be different on the two crystals. The most likely active intermediates are weakly adsorbed molecules such as {pi}-bonded ethylene and ethyl. These species are not easily detected because their concentration lies at the detection limit of SFG. The SFG spectra and GC data essentially show that ethylene hydrogenation is structure insensitive for Pt(111) and Pt(100). SFG has proven to be a unique and excellent technique for studying adsorbed species on single crystal surfaces under high-pressure catalytic reactions. Coupled with kinetic data obtained from gas chromatography measurements, it can give much insight into how the structure of a single crystal surface affects the chemistry of a catalytic reaction by detecting surface species under reaction conditions.

  13. Generalization of Conformal Transformations

    E-Print Network [OSTI]

    G. I. Garas'ko

    2005-09-19T23:59:59.000Z

    Conformal transformations of a Euclidean (complex) plane have some kind of completeness (sufficiency) for the solution of many mathematical and physical-mathematical problems formulated on this plane. There is no such completeness in the case of Euclidean, pseudo-Euclidean and polynumber spaces of dimension greater than two. In the present paper we show that using the concepts of analogical geometries allows us to generalize conformal transformations not only to the case of Euclidean or pseudo-Euclidean spaces, but also to the case of Finsler spaces, analogous to the spaces of affine connectedness. Examples of such transformations in the case of complex and hypercomplex numbers H_4 are presented. In the general case such transformations form a group of transitions, the elements of which can be viewed as transitions between projective Euclidean geometries of a distinguished class fixed by the choice of metric geometry admitting affine coordinates. The correlation between functions realizing generalized conformal transformations and generalized analytical functions can appear to be productive for the solution of fundamental problems in theoretical and mathematical physics.

  14. Imaging Catalytic Surfaces by Multiplexed Capillary Electrophoresis With Absorption Detection

    SciTech Connect (OSTI)

    Michael Christodoulou

    2002-08-27T23:59:59.000Z

    A new technique for in situ imaging and screening heterogeneous catalysts by using multiplexed capillary electrophoresis with absorption detection was developed. By bundling the inlets of a large number of capillaries, an imaging probe can be created that can be used to sample products formed directly from a catalytic surface with high spatial resolution. In this work, they used surfaces made of platinum, iron or gold wires as model catalytic surfaces for imaging. Various shapes were recorded including squares and triangles. Model catalytic surfaces consisting of both iron and platinum wires in the shape of a cross were also imaged successfully. Each of the two wires produced a different electrochemical product that was separated by capillary electrophoresis. Based on the collected data they were able to distinguish the products from each wire in the reconstructed image.

  15. Transformer design and application considerations for nonsinusoidal load currents

    SciTech Connect (OSTI)

    Pierce, L.W. [General Electric Co., Rome, GA (United States)] [General Electric Co., Rome, GA (United States)

    1996-05-01T23:59:59.000Z

    The use of adjustable-speed drives requires transformers capable of withstanding high levels of harmonic currents under normal operating conditions. Experience has been that overheating problems are much more common with dry-type transformers than with liquid-filled transformers. Transformer insulation life is determined by the hot spot temperature but confirmation of hot spot temperature rise is one performance characteristic which is ignored in industry standards. This is especially important for transformers rated for nonsinusoidal load currents. Hot spot allowances used in IEEE standards for ventilated dry-type transformers were developed in 1944 and recent data indicates that revisions are required. The design of transformers for nonsinusoidal load currents should include an analysis of the eddy loss distribution in the windings and calculation of the hot spot temperature rise. Calculations and thermal tests giving only average winding temperature rises are not sufficient. Thermal tests with nonsinusoidal currents and measurements of hot spot temperature rises are extremely difficult on large transformers. The combination of testing and analysis may be the only economically practical approach. Analysis indicates that the dry type transformer hot spot temperature is very sensitive to the eddy loss magnitude and distribution. The Underwriters Laboratories Inc. (UL) K-factor rated dry type transformer and the recommended practices given in ANSI/IEEE C57.110 are reviewed. When purchasing transformers subject to nonsinusoidal load currents, considerations should be given to the manufacturer`s development program and capability to calculate the eddy loss distribution and hot spot temperatures.

  16. Fuel Flexible, Low Emission Catalytic Combustor for Opportunity Fuel Applications

    SciTech Connect (OSTI)

    Eteman, Shahrokh

    2013-06-30T23:59:59.000Z

    Limited fuel resources, increasing energy demand and stringent emission regulations are drivers to evaluate process off-gases or process waste streams as fuels for power generation. Often these process waste streams have low energy content and/or highly reactive components. Operability of low energy content fuels in gas turbines leads to issues such as unstable and incomplete combustion. On the other hand, fuels containing higher-order hydrocarbons lead to flashback and auto-ignition issues. Due to above reasons, these fuels cannot be used directly without modifications or efficiency penalties in gas turbine engines. To enable the use of these wide variety of fuels in gas turbine engines a rich catalytic lean burn (RCLģ) combustion system was developed and tested in a subscale high pressure (10 atm.) rig. The RCLģ injector provided stability and extended turndown to low Btu fuels due to catalytic pre-reaction. Previous work has shown promise with fuels such as blast furnace gas (BFG) with LHV of 85 Btu/ft3 successfully combusted. This program extends on this work by further modifying the combustor to achieve greater catalytic stability enhancement. Fuels containing low energy content such as weak natural gas with a Lower Heating Value (LHV) of 6.5 MJ/m3 (180 Btu/ft3 to natural gas fuels containing higher hydrocarbon (e.g ethane) with LHV of 37.6 MJ/m3 (1010 Btu/ft3) were demonstrated with improved combustion stability; an extended turndown (defined as the difference between catalytic and non-catalytic lean blow out) of greater than 250oF was achieved with CO and NOx emissions lower than 5 ppm corrected to 15% O2. In addition, for highly reactive fuels the catalytic region preferentially pre-reacted the higher order hydrocarbons with no events of flashback or auto-ignition allowing a stable and safe operation with low NOx and CO emissions.

  17. Novel Fast Pyrolysis/Catalytic Technology for the Production of Stable Upgraded Liquids

    SciTech Connect (OSTI)

    Ted Oyama, Foster Agblevor, Francine Battaglia, Michael Klein

    2013-01-18T23:59:59.000Z

    The objective of the proposed research is the demonstration and development of a novel biomass pyrolysis technology for the production of a stable bio-oil. The approach is to carry out catalytic hydrodeoxygenation (HDO) and upgrading together with pyrolysis in a single fluidized bed reactor with a unique two-level design that permits the physical separation of the two processes. The hydrogen required for the HDO will be generated in the catalytic section by the water-gas shift reaction employing recycled CO produced from the pyrolysis reaction itself. Thus, the use of a reactive recycle stream is another innovation in this technology. The catalysts will be designed in collaboration with BASF Catalysts LLC (formerly Engelhard Corporation), a leader in the manufacture of attrition-resistant cracking catalysts. The proposed work will include reactor modeling with state-of-the-art computational fluid dynamics in a supercomputer, and advanced kinetic analysis for optimization of bio-oil production. The stability of the bio-oil will be determined by viscosity, oxygen content, and acidity determinations in real and accelerated measurements. A multi-faceted team has been assembled to handle laboratory demonstration studies and computational analysis for optimization and scaleup.

  18. Research Councils UK Transforming

    E-Print Network [OSTI]

    Berzins, M.

    research is helping to accelerate the use of green energy technologies. RCUK has played a key role to help combat climate change, accelerate the deployment of green energy technologies and create newResearch Councils UK Transforming our energy future #12;Research funded by the Research Councils

  19. TO TRANSFORM BIOMEDICAL ENGINEERING

    E-Print Network [OSTI]

    IT'S TIME TO TRANSFORM BIOMEDICAL ENGINEERING EDUCATION #12;Charles H. & Bettye Barclay Professor Head, Department of Biomedical Engineering Texas A&M University We're dedicated to solving the world in biomedical engineering research and education ­ and we're well on our way. Our faculty continues to engineer

  20. Student Preferences for Academic Advisors as Transformational Leaders

    E-Print Network [OSTI]

    Drozd, Deborah Suzanne

    2011-02-22T23:59:59.000Z

    A quantitative study was conducted to determine the preferences of undergraduate students for academic advisors as transformational leaders. A questionnaire was developed and distributed to undergraduate students enrolled in leadership classes at a...

  1. 5 Hz Catalytic Emissions FT-IR Monitoring during Lean-Rich Engine...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hz Catalytic Emissions FT-IR Monitoring during Lean-Rich Engine Cycles: Comparison to Reference Methods 5 Hz Catalytic Emissions FT-IR Monitoring during Lean-Rich Engine Cycles:...

  2. Bioenergy Technologies Office R&D Pathways: In-Situ Catalytic...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Office R&D Pathways: In-Situ Catalytic Fast Pyrolysis The in-situ catalytic fast pyrolysis pathway involves rapidly heating biomass with a catalyst to create bio-oils,...

  3. Bioenergy Technologies Office R&D Pathways: Ex-Situ Catalytic...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Office R&D Pathways: Ex-Situ Catalytic Fast Pyrolysis In ex-situ catalytic fast pyrolysis, biomass is heated with catalysts to create bio-oils, which are then used to...

  4. Development of a catalytic combustion system for the MIT Micro Gas Turbine Engine

    E-Print Network [OSTI]

    Peck, Jhongwoo, 1976-

    2003-01-01T23:59:59.000Z

    As part of the MIT micro-gas turbine engine project, the development of a hydrocarbon-fueled catalytic micro-combustion system is presented. A conventionally-machined catalytic flow reactor was built to simulate the ...

  5. Model catalytic studies of single crystal, polycrystalline metal, and supported catalysts

    E-Print Network [OSTI]

    Yan, Zhen

    2009-05-15T23:59:59.000Z

    This dissertation is focused on understanding the structure-activity relationship in heterogeneous catalysis by studying model catalytic systems. The catalytic oxidation of CO was chosen as a model reaction for studies on a variety of catalysts. A...

  6. Continued investigations of the catalytic reduction of N? to NH? by molybdenum triamidoamine complexes

    E-Print Network [OSTI]

    Hanna, Brian S. (Brian Stewart)

    2011-01-01T23:59:59.000Z

    A study of the effects of employing different solvents and the introduction of dihydrogen during the catalytic reduction of dinitrogen to ammonia with [HIPTN 3N]Mo complexes was completed. During a catalytic reaction, the ...

  7. Methods of using structures including catalytic materials disposed within porous zeolite materials to synthesize hydrocarbons

    DOE Patents [OSTI]

    Rollins, Harry W. (Idaho Falls, ID); Petkovic, Lucia M. (Idaho Falls, ID); Ginosar, Daniel M. (Idaho Falls, ID)

    2011-02-01T23:59:59.000Z

    Catalytic structures include a catalytic material disposed within a zeolite material. The catalytic material may be capable of catalyzing a formation of methanol from carbon monoxide and/or carbon dioxide, and the zeolite material may be capable of catalyzing a formation of hydrocarbon molecules from methanol. The catalytic material may include copper and zinc oxide. The zeolite material may include a first plurality of pores substantially defined by a crystal structure of the zeolite material and a second plurality of pores dispersed throughout the zeolite material. Systems for synthesizing hydrocarbon molecules also include catalytic structures. Methods for synthesizing hydrocarbon molecules include contacting hydrogen and at least one of carbon monoxide and carbon dioxide with such catalytic structures. Catalytic structures are fabricated by forming a zeolite material at least partially around a template structure, removing the template structure, and introducing a catalytic material into the zeolite material.

  8. Impact of Biodiesel-Based Na on the Selective Catalytic Reduction...

    Broader source: Energy.gov (indexed) [DOE]

    Impact of Biodiesel-Based Na on the Selective Catalytic Reduction (SCR) of NOx Using Cu-zeolite Impact of Biodiesel-Based Na on the Selective Catalytic Reduction (SCR) of NOx Using...

  9. Aluminosilicates as controlled molecular environments for selective photochemical and catalytic reactions

    SciTech Connect (OSTI)

    Carrado, K.A.

    1986-01-01T23:59:59.000Z

    This dissertation concerns research that involves photochemical, catalytic and spectroscopic studies of clays, pillared clays and zeolites. Incorporation of uranyl ions into hectorite, montmorillonite, bentonite and vermiculite clays was monitored by XRD and luminescence methods. Excitation and emission characteristics were studied in order to understand the behavior of uranyl ions in clays after various thermal treatments. Luminescence lifetime measurements elucidated the number of uranyl sites. Uranyl-exchanged clays were found to absorb light at lower energies (445-455nm) than analogous uranyl-exchanged zeolites (425nm). Each uranyl-exchanged clay was tested as a catalyst for the photoassisted oxidation of isopropyl alcohol. Energy transfer (ET) between uranyl and Eu(III) ions in different zeolite framework systems was examined. The efficiency of ET (eta/sub t/) was found to be affected by the type of framework present. Pillared bentonites were examined in the hydrocracking of decane. A catalytically and spectroscopically active dopant ion, Cr(III), was introduced into the clays in both pillared and unpillared forms depending upon synthetic conditions. EPR and DRS were employed to monitor the environment of Cr(III) for determination of its location - whether in the micropore structure or associated with alumina pillars. Catalytic behavior based upon this variability of location was examined. Incorporation of Cr(III) ions into an alumina pillar was found to increase the stability and activity with respect to an alumina PILC catalyst. The results of these studies suggest that selective, efficient catalysts can be designed around inorganic ions in aluminosilicate supports.

  10. Formic Acid Free Flowsheet Development To Eliminate Catalytic Hydrogen Generation In The Defense Waste Processing

    SciTech Connect (OSTI)

    Lambert, Dan P.; Stone, Michael E.; Newell, J. David; Fellinger, Terri L.; Bricker, Jonathan M.

    2012-09-14T23:59:59.000Z

    The Defense Waste Processing Facility (DWPF) processes legacy nuclear waste generated at the Savannah River Site (SRS) during production of plutonium and tritium demanded by the Cold War. The nuclear waste is first treated via a complex sequence of controlled chemical reactions and then vitrified into a borosilicate glass form and poured into stainless steel canisters. Converting the nuclear waste into borosilicate glass canisters is a safe, effective way to reduce the volume of the waste and stabilize the radionuclides. Testing was initiated to determine whether the elimination of formic acid from the DWPF's chemical processing flowsheet would eliminate catalytic hydrogen generation. Historically, hydrogen is generated in chemical processing of alkaline High Level Waste sludge in DWPF. In current processing, sludge is combined with nitric and formic acid to neutralize the waste, reduce mercury and manganese, destroy nitrite, and modify (thin) the slurry rheology. The noble metal catalyzed formic acid decomposition produces hydrogen and carbon dioxide. Elimination of formic acid by replacement with glycolic acid has the potential to eliminate the production of catalytic hydrogen. Flowsheet testing was performed to develop the nitric-glycolic acid flowsheet as an alternative to the nitric-formic flowsheet currently being processed at the DWPF. This new flowsheet has shown that mercury can be reduced and removed by steam stripping in DWPF with no catalytic hydrogen generation. All processing objectives were also met, including greatly reducing the Slurry Mix Evaporator (SME) product yield stress as compared to the baseline nitric/formic flowsheet. Ten DWPF tests were performed with nonradioactive simulants designed to cover a broad compositional range. No hydrogen was generated in testing without formic acid.

  11. Final Report: Catalytic Hydrocarbon Reactions over Supported Metal Oxides, August 1, 1995 - July 31, 1999

    SciTech Connect (OSTI)

    Ekerdt, John G.

    1999-07-31T23:59:59.000Z

    The research program focused on the catalysis of hydrodesulfurization (HDS) over molybdenum-based catalysts and how catalyst composition, redox ability, structure and neighboring sites control the catalytic properties of metal oxides. We sought to understand the catalytic features/sites that control hydrogenation, hydrogenolysis, and isomerization during HDS. Unprompted silica-supported molybdenum oxides and molybdenum sulfides were studied. Model catalyst systems were prepared from organometallic precursors or cluster compounds to generate supported structures that feature Mo(II) and Mo(IV) cations that are isolated or in ensembles and that have either Mo-O or Mo-S bonds. Conventional MOS{sub 2} catalysts, which contain both edge and rim sites, were be studied. Finally, single-layer MOS{sub 2} structures were also prepared from 2H-MoS{sub 2} powder so that the model systems could be compared against a disulfide catalyst that only involves rim sites. Catalytic reactions for thiophene and tetrahydrothione were studied over the various catalysts. Oxidation states were determined using X-ray photoelectron spectroscopy. X-ray crystallography was used to characterize and follow changes in the MOS{sub 2} structures. The program on metal oxides prepared supported oxides that have a specific structure and oxidation state to serve as model templates for the more complex commercial catalysts and then employed these structures in reaction studies. This focus area examined the relationships between structure and cation redox characteristics in oxidation catalysis. Infrared and Raman spectroscopy were used to characterize the cations and reaction intermediates.

  12. Phase Transformation in Cast Superaustenitic Stainless Steels

    SciTech Connect (OSTI)

    Nathaniel Steven Lee Phillips

    2006-12-12T23:59:59.000Z

    Superaustenitic stainless steels constitute a group of Fe-based alloys that are compositionally balanced to have a purely austenitic matrix and exhibit favorable pitting and crevice corrosion resistant properties and mechanical strength. However, intermetallic precipitates such as sigma and Laves can form during casting or exposure to high-temperature processing, which degrade the corrosion and mechanical properties of the material. The goal of this study was to accurately characterize the solid-solid phase transformations seen in cast superaustenitic stainless steels. Heat treatments were performed to understand the time and temperature ranges for intermetallic phase formations in alloys CN3MN and CK3MCuN. Microstructures were characterized using scanning electron microscopy (SEM), transmission electron microscopy (TEM), and energy and wavelength dispersive spectroscopy (EDS, WDS). The equilibrium microstructures, composed primarily of sigma and Laves within purely austenitic matrices, showed slow transformation kinetics. Factors that determine the extent of transformation, including diffusion, nucleation, and growth, are discussed.

  13. Catalytic two-stage coal hydrogenation and hydroconversion process

    DOE Patents [OSTI]

    MacArthur, James B. (Denville, NJ); McLean, Joseph B. (So. Somerville, NJ); Comolli, Alfred G. (Yardley, PA)

    1989-01-01T23:59:59.000Z

    A process for two-stage catalytic hydrogenation and liquefaction of coal to produce increased yields of low-boiling hydrocarbon liquid and gas products. In the process, the particulate coal is slurried with a process-derived liquid solvent and fed at temperature below about 650.degree. F. into a first stage catalytic reaction zone operated at conditions which promote controlled rate liquefaction of the coal, while simultaneously hydrogenating the hydrocarbon recycle oils at conditions favoring hydrogenation reactions. The first stage reactor is maintained at 650.degree.-800.degree. F. temperature, 1000-4000 psig hydrogen partial pressure, and 10-60 lb coal/hr/ft.sup.3 reactor space velocity. The partially hydrogenated material from the first stage reaction zone is passed directly to the close-coupled second stage catalytic reaction zone maintained at a temperature at least about 25.degree. F. higher than for the first stage reactor and within a range of 750.degree.-875.degree. F. temperature for further hydrogenation and thermal hydroconversion reactions. By this process, the coal feed is successively catalytically hydrogenated and hydroconverted at selected conditions, which results in significantly increased yields of desirable low-boiling hydrocarbon liquid products and minimal production of undesirable residuum and unconverted coal and hydrocarbon gases, with use of less energy to obtain the low molecular weight products, while catalyst life is substantially increased.

  14. In-Situ Catalytic Fast Pyrolysis Technology Pathway

    SciTech Connect (OSTI)

    Biddy, M.; Dutta, A.; Jones, S.; Meyer, A.

    2013-03-01T23:59:59.000Z

    This technology pathway case investigates converting woody biomass using in-situ catalytic fast pyrolysis followed by upgrading to gasoline-, diesel-, and jet-range hydrocarbon blendstocks. Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified.

  15. Ex-Situ Catalytic Fast Pyrolysis Technology Pathway

    SciTech Connect (OSTI)

    Biddy, M.; Dutta, A.; Jones, S.; Meyer, A.

    2013-03-01T23:59:59.000Z

    This technology pathway case investigates converting woody biomass using ex-situ catalytic fast pyrolysis followed by upgrading to gasoline-, diesel-, and jet-range hydrocarbon blendstocks. Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified.

  16. Short Communication Catalytic coal gasification: use of calcium versus potassium*

    E-Print Network [OSTI]

    Short Communication Catalytic coal gasification: use of calcium versus potassium* Ljubisa R on the gasification in air and 3.1 kPa steam of North Dakota lignitic chars prepared under slow and rapid pyrolysis of calcium is related to its sintering via crystallite growth. (Keywords: coal; gasification; catalysis

  17. Catalytic, Enantioselective Alkylations of N,O-Acetals

    E-Print Network [OSTI]

    Lectka, Thomas

    , 10998-10999. (2) Hoveyda et al. have developed a Ni-catalyzed alkylation reaction of allylic acetalsCatalytic, Enantioselective Alkylations of N,O-Acetals Dana Ferraris, Travis Dudding, Brandon Young alkylation reactions of acetals have attained a prominent position in organic synthesis.1 Methods employing

  18. Catalytic Asymmetric Synthesis of Hydroxy Enol Ethers: Approach to a

    E-Print Network [OSTI]

    Walsh, Patrick J.

    for the generation of polypro- pionate backbone.1-7 In contrast, the asymmetric acetate aldol reaction that leads associated with acetate aldol reactions have prompted investigations into alternative methods to generate the catalytic asymmetric allylation of aldehydes followed by oxidative cleavage of the allyl group (Scheme 1, A

  19. Scaling behavior of optimally structured catalytic microfluidic reactors

    E-Print Network [OSTI]

    Okkels, F; Bruus, Henrik; Okkels, Fridolin

    2006-01-01T23:59:59.000Z

    In this study of catalytic microfluidic reactors we show that, when optimally structured, these reactors share underlying scaling properties. The scaling is predicted theoretically and verified numerically. Furthermore, we show how to increase the reaction rate significantly by distributing the active porous material within the reactor using a high-level implementation of topology optimization.

  20. Structural Dynamics of a Catalytic Monolayer Probed by Ultrafast

    E-Print Network [OSTI]

    Fayer, Michael D.

    REPORTS Structural Dynamics of a Catalytic Monolayer Probed by Ultrafast 2D IR Vibrational Echoes in solutions. Here, we extend the technique to probing the interfacial dynamics and structure of a silica. The structural dynamics, as reported on by a carbonyl stretch vibration of the surface-bound complex, have

  1. Nanostructured Molybdenum Carbide: Sonochemical Synthesis and Catalytic Properties

    E-Print Network [OSTI]

    Suslick, Kenneth S.

    to be a useful technique to generate nanophase transition metals.7,8 Recently, molybdenum and tungsten carbides of metal salts.5,6 Sonochemical decomposition of transition metal carbonyl compounds has also been provenNanostructured Molybdenum Carbide: Sonochemical Synthesis and Catalytic Properties Taeghwan Hyeon

  2. The Biodiversity of Catalytic Super-Brownian Motion Klaus Fleischmann

    E-Print Network [OSTI]

    Klenke, Achim

    The Biodiversity of Catalytic Super-Brownian Motion Klaus Fleischmann Weierstra√?-Institut f that the reactant has an infinite local biodiversity or genetic abundance. This contrasts the finite local biodiversity of the equilibrium of classical super-Brownian motion. Another question we address

  3. Catalytic Methane Reduction in the Exhaust Gas of Combustion Engines

    E-Print Network [OSTI]

    Dunin-Borkowski, Rafal E.

    Catalytic Methane Reduction in the Exhaust Gas of Combustion Engines Peter Mauermann1,* , Michael Dornseiffer6 , Frank Amkreutz6 1 Institute for Combustion Engines , RWTH Aachen University, Schinkelstr. 8, D of the hydrocarbon exhaust of internal combustion engines. In contrast to other gaseous hydrocarbons, significant

  4. Catalytic Domain of Phosphoinositide-specific Phospholipase C (PLC)

    E-Print Network [OSTI]

    Williams, Roger L.

    Catalytic Domain of Phosphoinositide-specific Phospholipase C (PLC) MUTATIONAL ANALYSIS OF RESIDUES WITHIN THE ACTIVE SITE AND HYDROPHOBIC RIDGE OF PLC 1* (Received for publication, November 20, 1997 Institute, University of Dundee, Dundee DD1 4HN, United Kingdom Structural studies of phospholipase C 1 (PLC

  5. Linear Transformations, Canonoid Transformations and BiHamiltonian Structures

    E-Print Network [OSTI]

    Giovanni Rastelli; Manuele Santoprete

    2014-07-19T23:59:59.000Z

    We give a characterization of linear canonoid transformations on symplectic manifolds and we use it to generate biHamiltonian structures for some mechanical systems. Utilizing this characterization we also study the behavior of quadratic superintegrable systems under canonoid transformations. We present a description of canonoid transformations due to E.T. Whittaker, and we show that it leads, in a natural way, to the modern, coordinate-independent definition of canonoid transformations. We also generalize canonoid transformations to Poisson manifolds by introducing Poissonoid transformations. We give examples of such transformations for Euler's equations of the rigid body (on $ \\mathfrak{ so}^\\ast (3) $ and $ \\mathfrak{ so}^\\ast (4)$) and for an integrable case of Kirchhoff's equations for the motion of a rigid body immersed in an ideal fluid. We study the relationship between biHamiltonian structures and Poissonoid transformations for these examples.

  6. Interacting FisherWright Diffusions in a Catalytic Medium Andreas Greven

    E-Print Network [OSTI]

    Klenke, Achim

    environment (catalytic medium). Here we introduce a model of interacting Fisher­Wright diffusions where environment, catalytic medium, longtime behaviour, rescaling. AMS Subject Classification: 60K35, 60J70Interacting Fisher­Wright Diffusions in a Catalytic Medium Andreas Greven Mathematisches Institut

  7. Catalytic autothermal reforming increases fuel cell flexibility

    SciTech Connect (OSTI)

    Flytzani-Stephanopoulos, M.; Voecks, G.E.

    1981-12-01T23:59:59.000Z

    Experimental results are presented for the autothermal reforming (ATR) of n-hexane, n-tetradecane, benzene and benzene solutions of naphthalene. The tests were run at atmospheric pressure and at moderately high reactant preheat temperatures in the 800-900 K range. Carbon formation lines were determined for paraffinic and aromatic liquids. Profiles were determined for axial bed temperature and composition. Space velocity efforts were assessed, and the locations and types of carbon were recorded. Significant reactive differences between hydrocarbons were identified. Carbon formation characteristics were hydrocarbon specific. The differing behavior of paraffinic and aromatic fuels with respect to their carbon formation may be important in explaining the narrow range of carbon-free operating conditions found in the ATR of number two fuel oil.

  8. CX-000798: Categorical Exclusion Determination | Department of...

    Broader source: Energy.gov (indexed) [DOE]

    Determination CX-000798: Categorical Exclusion Determination Relocate Padmounted Transformer in R-Area CX(s) Applied: B4.11 Date: 01202010 Location(s): Aiken, South Carolina...

  9. CX-009716: Categorical Exclusion Determination | Department of...

    Broader source: Energy.gov (indexed) [DOE]

    Determination CX-009716: Categorical Exclusion Determination Loss of a Major Transformer at Bryan Mound or West Hackberry CX(s) Applied: B1.3 Date: 12112012 Location(s):...

  10. CX-012081: Categorical Exclusion Determination | Department of...

    Broader source: Energy.gov (indexed) [DOE]

    Determination CX-012081: Categorical Exclusion Determination Kimball Substation KY1A Transformer Replacement and Road Maintenance CX(s) Applied: B1.3 Date: 02102014 Location(s):...

  11. Industrial Gas Turbine Engine Catalytic Pilot Combustor-Prototype Testing

    SciTech Connect (OSTI)

    Shahrokh Etemad; Benjamin Baird; Sandeep Alavandi; William Pfefferle

    2009-09-30T23:59:59.000Z

    PCI has developed and demonstrated its Rich Catalytic Lean-burn (RCL¬ģ) technology for industrial and utility gas turbines to meet DOE‚??s goals of low single digit emissions. The technology offers stable combustion with extended turndown allowing ultra-low emissions without the cost of exhaust after-treatment and further increasing overall efficiency (avoidance of after-treatment losses). The objective of the work was to develop and demonstrate emission benefits of the catalytic technology to meet strict emissions regulations. Two different applications of the RCL¬ģ concept were demonstrated: RCL¬ģ catalytic pilot and Full RCL¬ģ. The RCL¬ģ catalytic pilot was designed to replace the existing pilot (a typical source of high NOx production) in the existing Dry Low NOx (DLN) injector, providing benefit of catalytic combustion while minimizing engine modification. This report discusses the development and single injector and engine testing of a set of T70 injectors equipped with RCL¬ģ pilots for natural gas applications. The overall (catalytic pilot plus main injector) program NOx target of less than 5 ppm (corrected to 15% oxygen) was achieved in the T70 engine for the complete set of conditions with engine CO emissions less than 10 ppm. Combustor acoustics were low (at or below 0.1 psi RMS) during testing. The RCL¬ģ catalytic pilot supported engine startup and shutdown process without major modification of existing engine controls. During high pressure testing, the catalytic pilot showed no incidence of flashback or autoignition while operating over a wide range of flame temperatures. In applications where lower NOx production is required (i.e. less than 3 ppm), in parallel, a Full RCL¬ģ combustor was developed that replaces the existing DLN injector providing potential for maximum emissions reduction. This concept was tested at industrial gas turbine conditions in a Solar Turbines, Incorporated high-pressure (17 atm.) combustion rig and in a modified Solar Turbines, Incorporated Saturn engine rig. High pressure single-injector rig and modified engine rig tests demonstrated NOx less than 2 ppm and CO less than 10 ppm over a wide flame temperature operating regime with low combustion noise (<0.15% peak-to-peak). Minimum NOx for the optimized engine retrofit Full RCL¬ģ designs was less than 1 ppm with CO emissions less than 10 ppm. Durability testing of the substrate and catalyst material was successfully demonstrated at pressure and temperature showing long term stable performance of the catalytic reactor element. Stable performance of the reactor element was achieved when subjected to durability tests (>5000 hours) at simulated engine conditions (P=15 atm, Tin=400C/750F.). Cyclic tests simulating engine trips was also demonstrated for catalyst reliability. In addition to catalyst tests, substrate oxidation testing was also performed for downselected substrate candidates for over 25,000 hours. At the end of the program, an RCL¬ģ catalytic pilot system has been developed and demonstrated to produce NOx emissions of less than 3 ppm (corrected to 15% O2) for 100% and 50% load operation in a production engine operating on natural gas. In addition, a Full RCL¬ģ combustor has been designed and demonstrated less than 2 ppm NOx (with potential to achieve 1 ppm) in single injector and modified engine testing. The catalyst/substrate combination has been shown to be stable up to 5500 hrs in simulated engine conditions.

  12. Two-stage Catalytic Reduction of NOx with Hydrocarbons

    SciTech Connect (OSTI)

    Umit S. Ozkan; Erik M. Holmgreen; Matthew M. Yung; Jonathan Halter; Joel Hiltner

    2005-12-21T23:59:59.000Z

    A two-stage system for the catalytic reduction of NO from lean-burn natural gas reciprocating engine exhaust is investigated. Each of the two stages uses a distinct catalyst. The first stage is oxidation of NO to NO{sub 2} and the second stage is reduction of NO{sub 2} to N{sub 2} with a hydrocarbon. The central idea is that since NO{sub 2} is a more easily reduced species than NO, it should be better able to compete with oxygen for the combustion reaction of hydrocarbon, which is a challenge in lean conditions. Early work focused on demonstrating that the N{sub 2} yield obtained when NO{sub 2} was reduced was greater than when NO was reduced. NO{sub 2} reduction catalysts were designed and silver supported on alumina (Ag/Al{sub 2}O{sub 3}) was found to be quite active, able to achieve 95% N{sub 2} yield in 10% O{sub 2} using propane as the reducing agent. The design of a catalyst for NO oxidation was also investigated, and a Co/TiO{sub 2} catalyst prepared by sol-gel was shown to have high activity for the reaction, able to reach equilibrium conversion of 80% at 300 C at GHSV of 50,000h{sup -1}. After it was shown that NO{sub 2} could be more easily reduced to N{sub 2} than NO, the focus shifted on developing a catalyst that could use methane as the reducing agent. The Ag/Al{sub 2}O{sub 3} catalyst was tested and found to be inactive for NOx reduction with methane. Through iterative catalyst design, a palladium-based catalyst on a sulfated-zirconia support (Pd/SZ) was synthesized and shown to be able to selectively reduce NO{sub 2} in lean conditions using methane. Development of catalysts for the oxidation reaction also continued and higher activity, as well as stability in 10% water, was observed on a Co/ZrO{sub 2} catalyst, which reached equilibrium conversion of 94% at 250 C at the same GHSV. The Co/ZrO{sub 2} catalyst was also found to be extremely active for oxidation of CO, ethane, and propane, which could potential eliminate the need for any separate oxidation catalyst. At every stage, catalyst synthesis was guided by the insights gained through detailed characterization of the catalysts using many surface and bulk analysis techniques such as X-ray diffraction, X-ray photoelectron spectroscopy, Temperature-programmed Reduction, Temperature programmed Desorption, and Diffuse Reflectance InfraRed Fourier Transform Spectroscopy as well as steady state reaction experiments. Once active catalysts for each stage had been developed, a physical mixture of the two catalysts was tested for the reduction of NO with methane in lean conditions. These experiments using a mixture of the catalysts produced N2 yields as high as 90%. In the presence of 10% water, the catalyst mixture produced 75% N{sub 2} yield, without any optimization. The dual catalyst system developed has the potential to be implemented in lean-burn natural gas engines for reducing NOx in lean exhaust as well as eliminating CO and unburned hydrocarbons without any fuel penalty or any system modifications. If funding continues, future work will focus on improving the hydrothermal stability of the system to bring the technology closer to application.

  13. Liquid Metal Transformers

    E-Print Network [OSTI]

    Sheng, Lei; Liu, Jing

    2014-01-01T23:59:59.000Z

    The room temperature liquid metal is quickly emerging as an important functional material in a variety of areas like chip cooling, 3D printing or printed electronics etc. With diverse capabilities in electrical, thermal and flowing behaviors, such fluid owns many intriguing properties that had never been anticipated before. Here, we show a group of unconventional phenomena occurring on the liquid metal objects. Through applying electrical field on the liquid metals immersed in water, a series of complex transformation behaviors such as self-assembling of a sheet of liquid metal film into a single sphere, quick mergences of separate metal droplets, controlled self-rotation and planar locomotion of liquid metal objects can be realized. Meanwhile, it was also found that two accompanying water vortexes were induced and reliably swirled near the rotating liquid metal sphere. Further, effects of the shape, size, voltage, orientation and geometries of the electrodes to control the liquid metal transformers were clar...

  14. Transformations of polynomial ensembles

    E-Print Network [OSTI]

    Arno B. J. Kuijlaars

    2015-01-30T23:59:59.000Z

    A polynomial ensemble is a probability density function for the position of $n$ real particles of the form $\\frac{1}{Z_n} \\, \\prod_{jtransformations that preserve the structure of a polynomial ensemble. These transformations include the restriction of a Hermitian matrix by removing one row and one column, a rank-one modification of a Hermitian matrix, and the extension of a Hermitian matrix by adding an extra row and column with complex Gaussians.

  15. Transformative Wave Technologies Kent, Washington

    E-Print Network [OSTI]

    California at Davis, University of

    Transformative Wave Technologies Kent, Washington www.transformativewave.com #12;#12;North America are shifted to off peak times #12;#12;Transformative Wave Technologies www.transformativewave.com #12

  16. Transforming Parks and Protected Areas

    E-Print Network [OSTI]

    Bolch, Tobias

    Transforming Parks and Protected Areas Policy and governance in a changing world Edited by Kevin S from the British Library Library of Congress Cataloging In Publication Data Transforming parks

  17. Entropy production of a steady-growth cell with catalytic reactions

    E-Print Network [OSTI]

    Yusuke Himeoka; Kunihiko Kaneko

    2014-03-15T23:59:59.000Z

    Cells generally convert external nutrient resources to support metabolismand growth. Understanding the thermodynamic efficiency of this conversion is essential to determine the general characteristics of cellular growth. Using a simple protocell model with catalytic reaction dynamics to synthesize the necessary enzyme and membrane components from nutrients, the entropy production per unit cell-volume growth is calculated analytically and numerically based on the rate equation for chemical kinetics and linear non-equilibrium thermodynamics. The minimal entropy production per unit cell growth is found to be achieved at a non-zero nutrient uptake rate, rather than at a quasi-static limit as in the standard Carnot engine. This difference appears because the equilibration mediated by the enzyme exists only within cells that grow through enzyme and membrane synthesis. Optimal nutrient uptake is also confirmed by protocell models with many chemical components synthesized through a catalytic reaction network. The possible relevance of the identified optimal uptake to optimal yield for cellular growth is also discussed.

  18. Nonlocal conservation laws and related Bšcklund transformations via reciprocal transformations

    E-Print Network [OSTI]

    Sen-Yue Lou

    2014-06-08T23:59:59.000Z

    A set of infinitely many nonlocal conservation laws are revealed for (1+1)-dimensional evolution equations. For some special known integrable systems, say, the KdV and Dym equations, it is found that different nonlocal conservation laws can lead to same new integrable systems via reciprocal transformation. On the other hand, it can be considered as one solution of the new model obtained via reciprocal transformation(s) can be changed to different solutions of the original model. The fact indicates also that two or more different (local and nonlocal) conservation laws can be used to find implicit auto-B\\"acklund transformations via reciprocal transformation to other systems.

  19. Method for recovering catalytic elements from fuel cell membrane electrode assemblies

    DOE Patents [OSTI]

    Shore, Lawrence (Edison, NJ); Matlin, Ramail (Berkeley Heights, NJ); Heinz, Robert (Ludwigshafen, DE)

    2012-06-26T23:59:59.000Z

    A method for recovering catalytic elements from a fuel cell membrane electrode assembly is provided. The method includes converting the membrane electrode assembly into a particulate material, wetting the particulate material, forming a slurry comprising the wetted particulate material and an acid leachate adapted to dissolve at least one of the catalytic elements into a soluble catalytic element salt, separating the slurry into a depleted particulate material and a supernatant containing the catalytic element salt, and washing the depleted particulate material to remove any catalytic element salt retained within pores in the depleted particulate material.

  20. Generalized Transforms and Special Functions

    E-Print Network [OSTI]

    G. Dattoli; E. Sabia

    2010-10-08T23:59:59.000Z

    We study the properties of different type of transforms by means of operational methods and discuss the relevant interplay with many families of special functions. We consider in particular the binomial transform and its generalizations. A general method, based on the use of the Fourier transform technique, is proposed for the study of the properties of functions of operators.

  1. VLA Antenna Pad Transformer Breaker

    E-Print Network [OSTI]

    Groppi, Christopher

    NRAO VLA Antenna Pad Transformer Breaker Survey B-Array, November 22nd , 2013 Summary: None connections in the cabinet and may be indicating a problem inside the transformer. If the heating on these bushings continues the transformer may need service. NOTE: The low ambient temperature and good conductance

  2. VLA Antenna Pad Transformer Breaker

    E-Print Network [OSTI]

    Groppi, Christopher

    NRAO VLA Antenna Pad Transformer Breaker Survey D-Array, April 5th 2013 #12;VLA Antenna Pad Transformer Breaker Survey D-Array, April 2013, Bob Broilo 2 Summary: No action needed. Inspected by: Bob2 Visible Light Image Notes: #12;VLA Antenna Pad Transformer Breaker Survey D-Array, April 2013, Bob

  3. VLA Antenna Pad Transformer Breaker

    E-Print Network [OSTI]

    Groppi, Christopher

    NRAO VLA Antenna Pad Transformer Breaker Survey A-Array, July 2011, Bob Broilo #12;A-Array Antenna Pad Transformer Survey July 2011, Bob Broilo 2 Inspected by: Bob Broilo Inspection Date: 6/16/2011 2 Transformer Survey July 2011, Bob Broilo 3 Inspected by: Bob Broilo Inspection Date: 6/16/2011 1:58:06 PM

  4. VLA Antenna Pad Transformer Breaker

    E-Print Network [OSTI]

    Groppi, Christopher

    NRAO VLA Antenna Pad Transformer Breaker Survey C-Array, August 20th 2013 #12;VLA Antenna Pad Transformer Breaker Survey C-Array, August 2013, Bob Broilo 2 Summary: Breaker at CE7 needs to be replaced transformer can be shut down with the switch at DE9. Inspected by: Bob Broilo Inspection Date: 8/16/2013 2

  5. VLA Antenna Pad Transformer Breaker

    E-Print Network [OSTI]

    Groppi, Christopher

    NRAO VLA Antenna Pad Transformer Breaker Survey D-Array, October 2011, Bob Broilo #12;D-Array Antenna Pad Transformer Survey October 2011, Bob Broilo 2 Inspected by: Bob Broilo Inspection Date: 10-hand) feeds DE2. #12;D-Array Antenna Pad Transformer Survey October 2011, Bob Broilo 3 Inspected by: Bob

  6. The Transformer By Aaron Lo

    E-Print Network [OSTI]

    Treuille, Adrien

    (3) Transforming lambda-expressions with several patterns n pat 1 : : : pat n -> exp n pat 1 -> (n pat 2 -> : : : (n pat n -> exp) : : :) where n #21; 2 (4) Transforming lambda-patterns into case n pat -> exp n var -> case var of pat -> exp where pat is no variable, var is new (5) Transforming case

  7. VLA Antenna Pad Transformer Breaker

    E-Print Network [OSTI]

    Groppi, Christopher

    NRAO VLA Antenna Pad Transformer Breaker Survey C-Array, April 2012, Bob Broilo #12;C-Array Antenna Pad Transformer Survey April 2012, Bob Broilo 2 Inspected by: Bob Broilo Inspection Date: 4/4/2012 2 Pad Transformer Survey April 2012, Bob Broilo 3 Inspected by: Bob Broilo Inspection Date: 4/4/2012 2

  8. VLA Antenna Pad Transformer Breaker

    E-Print Network [OSTI]

    Groppi, Christopher

    NRAO VLA Antenna Pad Transformer Breaker Survey A-Array, May 20, 2014 Summary: The breakers at AN5 Transformer Breaker Survey A-Array, May 2014, Bob Broilo 2 Inspected by: Bob Broilo Inspection Date: 5 Notes: #12;VLA Antenna Pad Transformer Breaker Survey A-Array, May 2014, Bob Broilo 3 Inspected by: Bob

  9. TRANSFORMING MEDICINE October 1, 2009

    E-Print Network [OSTI]

    Valero-Cuevas, Francisco

    TRANSFORMING MEDICINE October 1, 2009 Strategic Plan #12;ABOUT THE KECK SCHOOL OF MEDICINE OF USC Century for the benefit of humankind. This is an exciting time of great transformation as we endeavor of Medicine is undergoing a major transformation. It was sparked by the expansion of biomedical research

  10. VLA Antenna Pad Transformer Breaker

    E-Print Network [OSTI]

    Groppi, Christopher

    NRAO VLA Antenna Pad Transformer Breaker Survey B-Array, May 2011, Bob Broilo #12;B-array Antenna Pad Transformer Breaker Survey May 2011, Bob Broilo 2 Inspected by: Bob Broilo Inspection Date: 5 Transformer Breaker Survey May 2011, Bob Broilo 3 Inspected by: Bob Broilo Inspection Date: 5/5/2011 3

  11. Catalytic autothermal reforming increases fuel cell flexibility

    SciTech Connect (OSTI)

    Flytzani-Stephanopoulos, M.; Voecks, G.E.

    1981-12-01T23:59:59.000Z

    To give a better understanding of autothermal reforming (ATR), a process which offers an advantageous alternative to steam reforming for H/sub 2/ production for fuel cells because of the wider range of fuels which can be converted, the conversion of individual fuel components was studied. Attempts have been made to characterize the chemical reactions of light and heavy paraffins and aromatics in ATR. Results of studies to determine the effects of operating parameters on the carbon-forming tendency of each hydrocarbon type are reported. The catalyst used for the ATR process was three-layers of supported nickel catalysts, Norton NC-100 spheres in the top zone, cylindrical G-56B tablets in the bottom one, and either ICI 46-I or ICI 46-4 Raschig rings in the middle zone. A summary of the experimental studies of the ATR of n-hexane, n-tetradecane, benzene, and benzene solutions of naphthalene is presented. (BLM)

  12. Transformer requirements for the year 2000. Final report, December 1979

    SciTech Connect (OSTI)

    Not Available

    1980-06-01T23:59:59.000Z

    The principal objective of this program was to determine the design parameters required for transformers of the year 2000. The approach to meeting this objective was to determine the changes which may occur in transmission and distribution systems over the next twenty years, and how these changes might affect design parameters of distribution and power transformers. Emphasis was placed on domestic requirements, although the impact of international practices was factored into the overall requirements for transformers. Possible investigations that could help transformer designers meet the long term technical requirements of future transformers were also identified. The principal conclusions of this study were: 1200 kV transmission could be in service by the late 1980's and it is essential to develop 1200 kV transformers for these systems; transformer manufacturers must be prepared to supply higher MVA ratings at all voltage levels; there will be a strong demand for low-loss, minimum cost transformers; and environmental/safety, reliability, and size reduction considerations will increase in importance. (LLL)

  13. Formation and control of fuel-nitrogen pollutants in catalytic combustion of coal-derived gases. Final report

    SciTech Connect (OSTI)

    Walsh, P. M.; Bruno, C.; Santavicca, D. A.; Bracco, F. V.

    1980-02-01T23:59:59.000Z

    The objective of this program has been the elucidation of the mechanism of high temperature catalytic oxidation of coal-derived gases, including their individual constituents,and the effects of sulfur and nitrogen impurities. Detailed experimental data were obtained and a two-dimensional model is being developed and tested by comparison with the experimental data. When complete, the model can be used to optimize designs of catalytic combustors. The model at present includes axial and radial diffusion and gas and surface chemical reactions. Measured substrate temperatures are input in lieu of complete coupling of gas and solid energy conservation equations and radiative heat transfer. Axial and radial gas temperature and composition profiles inside a catalyst channel were computed and compared with experimental measurements at the catalyst outlet. Experimental investigations were made of carbon monoxide and medium-Btu gas combustion in the presence of platinum supported on a monolithic Cordierite substrate. Axial profiles of substrate temperature, gas temperature, and gas composition were determined at different gas velocities and equivalence ratios. The effects of H/sub 2/S and NH/sub 3/ in the medium-Btu gas were also investigated. Systems were proposed for making resonance absorption and Raman scattering measurements of gas temperature and/or species concentrations in a catalytic reactor. A new pulsed multipass Raman scattering technique for increasing photon yield from a scattering volume was developed.

  14. Tripartite entanglement transformations and tensor rank

    E-Print Network [OSTI]

    Eric Chitambar; Runyao Duan; Yaoyun Shi

    2008-05-19T23:59:59.000Z

    Understanding the nature of multipartite entanglement is a central mission of quantum information theory. To this end, we investigate the question of tripartite entanglement convertibility. We find that there exists no easy criterion to determine whether a general tripartite transformation can be performed with a nonzero success probability and in fact, the problem is NP-hard. Our results are based on the connections between multipartite entanglement and tensor rank (also called Schmidt rank), a key concept in algebraic complexity theory. Not only does this relationship allow us to characterize the general difficulty in determining possible entanglement transformations, but it also enables us to observe the previously overlooked fact that {\\em the Schmidt rank is not an additive entanglement measure}. As a result, we improve some best known transformation rates between specific tripartite entangled states. In addition, we find obtaining the most efficient algorithm for matrix multiplication to be precisely equivalent to determining the optimal rate of conversion between the Greenberger-Horne-Zeilinger state and a triangular distribution of three Einstein-Podolsky-Rosen states.

  15. Transforming Commercial Building Operations

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion |Energy Usage ¬Ľof EnergyThe EnergyDepartment7 th ,TopDepartmentPlanarWorkshopTransforming

  16. Transformations | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revisionEnvReviewNonInvasiveExplorationUT-gTaguspark JumpDetective:Toyo Aluminium KK JumpMyTransformations Jump

  17. Selective dehydrogenation of propane over novel catalytic materials

    SciTech Connect (OSTI)

    Sault, A.G.; Boespflug, E.P.; Martino, A.; Kawola, J.S.

    1998-02-01T23:59:59.000Z

    The conversion of small alkanes into alkenes represents an important chemical processing area; ethylene and propylene are the two most important organic chemicals manufactured in the U.S. These chemicals are currently manufactured by steam cracking of ethane and propane, an extremely energy intensive, nonselective process. The development of catalytic technologies (e.g., selective dehydrogenation) that can be used to produce ethylene and propylene from ethane and propane with greater selectivity and lower energy consumption than steam cracking will have a major impact on the chemical processing industry. This report details a study of two novel catalytic materials for the selective dehydrogenation of propane: Cr supported on hydrous titanium oxide ion-exchangers, and Pt nanoparticles encapsulated in silica and alumina aerogel and xerogel matrices.

  18. Protocol development for evaluation of commercial catalytic cracking catalysts

    SciTech Connect (OSTI)

    Mitchell, M.M. Jr.; Moore, H.F. (Ashland Petroleum Co., KY (USA))

    1988-09-01T23:59:59.000Z

    A complete, new set of testing protocols has been developed for qualification of catalysts for Ashland's commercial catalytic cracking units. The objective of this test development is to identify new generations of improved cracking catalysts. Prior test protocols have classically utilized microactivity (MAT) testing of steamed virgin catalysts, while more advanced methods have utilized fixed fluid bed and/or circulating pilot units. Each of these techniques, however, have been limited by their correlation to commercial operations, weaknesses in metallation and preparation of pseudo-equilibrium catalysts, and mechanical constraints on the use of heavy, vacuum bottoms-containing feedstocks. These new protocols have been baselined, compared to commercial Ashland results on known catalytic cracking catalysts, and utilized to evaluate a range of potentially new catalyst samples.

  19. Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway

    SciTech Connect (OSTI)

    Biddy, Mary J.; Jones, Susanne B.

    2013-03-31T23:59:59.000Z

    In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to hydrocarbon fuels to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This technology pathway case investigates the catalytic conversion of solubilized carbohydrate streams to hydrocarbon biofuels, utilizing data from recent efforts within the National Advanced Biofuels Consortium (NABC) in collaboration with Virent, Inc.. Technical barriers and key research needs that should be pursued for the catalytic conversion of sugars pathway to be competitive with petroleum-derived gasoline, diesel and jet range hydrocarbon blendstocks have been identified.

  20. The Role of Carbon in Catalytically Stabilized Transition Metal Sulfides

    SciTech Connect (OSTI)

    Kelty,S.; Berhault, G.; Chianelli, R.

    2007-01-01T23:59:59.000Z

    Since WWII considerable progress has been made in understanding the basis for the activity and the selectivity of molybdenum and tungsten based hydrotreating catalysts. Recently, the focus of investigation has turned to the structure of the catalytically stabilized active catalyst. The surface of the catalytically stabilized MoS2 has been shown to be carbided with the formula MoSxCy under hydrotreating conditions. In this paper we review the basis for this finding and present new data extending the concept to the promoted TMS (transition metal sulfides) systems CoMoC and NiMoC. Freshly sulfided CoMoS and NiMoS catalyst have a strong tendency to form the carbided surface phases from any available carbon source.

  1. Catalytic destruction of groundwater contaminants in reactive extraction wells

    DOE Patents [OSTI]

    McNab, Jr., Walt W. (Concord, CA); Reinhard, Martin (Stanford, CA)

    2002-01-01T23:59:59.000Z

    A system for remediating groundwater contaminated with halogenated solvents, certain metals and other inorganic species based on catalytic reduction reactions within reactive well bores. The groundwater treatment uses dissolved hydrogen as a reducing agent in the presence of a metal catalyst, such a palladium, to reduce halogenated solvents (as well as other substituted organic compounds) to harmless species (e.g., ethane or methane) and immobilize certain metals to low valence states. The reactive wells function by removing water from a contaminated water-bearing zone, treating contaminants with a well bore using catalytic reduction, and then reinjecting the treated effluent into an adjacent water-bearing zone. This system offers the advantages of a compact design with a minimal surface footprint (surface facilities) and the destruction of a broad suite of contaminants without generating secondary waste streams.

  2. Catalytic Combustion for Ultra-Low NOx Hydrogen Turbines

    SciTech Connect (OSTI)

    Etemad, Shahrokh; Baird, Benjamin; Alavandi, Sandeep

    2011-06-30T23:59:59.000Z

    Precision Combustion, Inc., (PCI) in close collaboration with Solar Turbines, Incorporated, has developed and demonstrated a combustion system for hydrogen fueled turbines that reduces NOx to low single digit level while maintaining or improving current levels of efficiency and eliminating emissions of carbon dioxide. Full scale Rich Catalytic Hydrogen (RCH1) injector was developed and successfully tested at Solar Turbines, Incorporated high pressure test facility demonstrating low single digit NOx emissions for hydrogen fuel in the range of 2200F-2750F. This development work was based on initial subscale development for faster turnaround and reduced cost. Subscale testing provided promising results for 42% and 52% H2 with NOx emissions of less than 2 ppm with improved flame stability. In addition, catalytic reactor element testing for substrate oxidation, thermal cyclic injector testing to simulate start-stop operation in a gas turbine environment, and steady state 15 atm. operation testing were performed successfully. The testing demonstrated stable and robust catalytic element component life for gas turbine conditions. The benefit of the catalytic hydrogen combustor technology includes capability of delivering near-zero NOx without costly post-combustion controls and without requirement for added sulfur control. In addition, reduced acoustics increase gas turbine component life. These advantages advances Department of Energy (DOEís) objectives for achievement of low single digit NOx emissions, improvement in efficiency vs. postcombustion controls, fuel flexibility, a significant net reduction in Integrated Gasification Combined Cycle (IGCC) system net capital and operating costs, and a route to commercialization across the power generation field from micro turbines to industrial and utility turbines.

  3. Hybrid lean premixing catalytic combustion system for gas turbines

    DOE Patents [OSTI]

    Critchley, Ian L.

    2003-12-09T23:59:59.000Z

    A system and method of combusting a hydrocarbon fuel is disclosed. The system combines the accuracy and controllability of an air staging system with the ultra-low emissions achieved by catalytic combustion systems without the need for a pre-heater. The result is a system and method that is mechanically simple and offers ultra-low emissions over a wide range of power levels, fuel properties and ambient operating conditions.

  4. Liquid Metal Transformers

    E-Print Network [OSTI]

    Lei Sheng; Jie Zhang; Jing Liu

    2014-01-30T23:59:59.000Z

    The room temperature liquid metal is quickly emerging as an important functional material in a variety of areas like chip cooling, 3D printing or printed electronics etc. With diverse capabilities in electrical, thermal and flowing behaviors, such fluid owns many intriguing properties that had never been anticipated before. Here, we show a group of unconventional phenomena occurring on the liquid metal objects. Through applying electrical field on the liquid metals immersed in water, a series of complex transformation behaviors such as self-assembling of a sheet of liquid metal film into a single sphere, quick mergences of separate metal droplets, controlled self-rotation and planar locomotion of liquid metal objects can be realized. Meanwhile, it was also found that two accompanying water vortexes were induced and reliably swirled near the rotating liquid metal sphere. Further, effects of the shape, size, voltage, orientation and geometries of the electrodes to control the liquid metal transformers were clarified. Such events are hard to achieve otherwise on rigid metal or conventional liquid spheres. This finding has both fundamental and practical significances which suggest a generalized way of making smart soft machine, collecting discrete metal fluids, as well as flexibly manipulating liquid metal objects including accompanying devices.

  5. Crystallographic Snapshots of the Complete Catalytic Cycle of the Unregulated Aspartate Transcarbamoylase from Bacillus subtilis

    SciTech Connect (OSTI)

    K Harris; G Cockrell; D Puleo; E Kantrowitz

    2011-12-31T23:59:59.000Z

    Here, we report high-resolution X-ray structures of Bacillus subtilis aspartate transcarbamoylase (ATCase), an enzyme that catalyzes one of the first reactions in pyrimidine nucleotide biosynthesis. Structures of the enzyme have been determined in the absence of ligands, in the presence of the substrate carbamoyl phosphate, and in the presence of the bisubstrate/transition state analog N-phosphonacetyl-L-aspartate. Combining the structural data with in silico docking and electrostatic calculations, we have been able to visualize each step in the catalytic cycle of ATCase, from the ordered binding of the substrates, to the formation and decomposition of the tetrahedral intermediate, to the ordered release of the products from the active site. Analysis of the conformational changes associated with these steps provides a rationale for the lack of cooperativity in trimeric ATCases that do not possess regulatory subunits.

  6. Development of a catalytic partial oxidation ethanol reformer for fuel cell applications

    SciTech Connect (OSTI)

    Mitchell, W.L.; Thijssen, J.H.J.; Bentley, J.M.; Marek, N.J.

    1995-12-31T23:59:59.000Z

    Arthur D. Little in conjunction with the Department of Energy and the Illinois Department of Commerce and Community Affairs are developing an ethanol fuel processor for fuel cell vehicles. Initial studies were carried out on a 25 kWe catalytic partial oxidation (POX) reformer to determine the effect of equivalence ratio, steam to carbon ratio, and residence time on ethanol conversion. Results of the POX experiments show near equilibrium yields of hydrogen and carbon monoxide for an equivalence ratio of 3.0 with a fuel processor efficiency of 80%. The size and weight of the prototype reformer yield power densities of 1.44 l/kW and 1.74 kg/kW at an estimated cost of $20/kW.

  7. Study of catalytic effects of mineral matter level on coal reactivity

    SciTech Connect (OSTI)

    Mazzocco, Nestor J.; Klunder, Edgar B.; Krastman, Donald

    1981-03-01T23:59:59.000Z

    Coal liquefaction experiments using a 400-lb/day bubble-column reactor tested the catalytic effects of added mineral matter level on coal conversion, desulfurization, and distillate yields in continuous operation under recycle conditions, with specific emphasis on the use of a disposable pyrite catalyst indigenous to the feed coal. Western Kentucky No. 11 run-of-mine (ROM) and washed coals were used as feedstocks to determine the effects of levels of mineral matter, specifically iron compounds. Liquefaction reactivity as characterized by total distillate yield was lower for washed coal, which contained less mineral matter. Liquefaction reactivity was regained when pyrite concentrate was added as a disposable catalyst to the washed coal feed in sufficient quantity to match the feed iron concentration of the run-of-mine coal liquefaction test run.

  8. Kinetics of liquid phase catalytic dehydration of methanol to dimethyl ether

    SciTech Connect (OSTI)

    Gogate, M.R.; Lee, B.G.; Lee, S. (Akron Univ., OH (USA). Dept. of Chemical Engineering); Kulik, C.J. (Electric Power Research Inst., Palo Alto, CA (USA))

    1990-01-01T23:59:59.000Z

    This paper reports the kinetics of the liquid phase catalytic dehydration of methanol to dimethyl ether investigated. The experiments were carried out under low concentrations of feed in a 1-L stirred autoclave, according to a statistical experimental design. The inert liquid phase used for this investigation was a 78:22 blend of paraffinic and naphthenic mineral oils. A complete thermodynamic analysis was carried out in order to determine the liquid phase concentrations of the dissolved species. A global kinetic model was developed for the rate of dimethyl ether synthesis in terms of the liquid phase concentration of methanol. The activation energy of the reaction was found to be 18,830 cal/gmol. Based on a step-wise linear regression analysis of the kinetic data, the order of the reaction which gave the best fit was 0.28 with respect to methanol.

  9. LU transformation invariant operators and LU transformation invariant

    E-Print Network [OSTI]

    Xin-wei Zha; Chun-min Zhang

    2007-02-06T23:59:59.000Z

    We proposed a concept of LU transformation invariant operators. By using this operator, arbitrary multi-qubit states LU transformation invariant and SLOCC invariant could be easily obtained. And we find that presences two kinds of invariant operators and corresponding invariants. One kind of operators yields LU invariants and the other operators results in SLOCC invariants. For three-qubit states, all independence LU transformation invariant are obtained. Furthermore, by this system method, arbitrary multi-qubit states invariants can be given.

  10. Pressure Induced Structural Transformation in Gd2Ti2O7 and Gd2Zr2O7...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in determining the pressure induced phase transformation. Citation: Xiao HY, and WJ Weber.2011."Pressure Induced Structural Transformation in Gd2Ti2O7 and Gd2Zr2O7."Journal of...

  11. PCB (polychlorinated biphenyl) residues in transformer carcasses: Final report

    SciTech Connect (OSTI)

    Rouse, T.O.; Raymond, C.T.; Fessler, W.A.

    1989-08-01T23:59:59.000Z

    This project had three objectives. The first was to assess the population of PCB-containing transformers remaining in service in the US in 1988. While this could not be done with great precision, it appears that the population of oil-filled transformers containing > 50 /mu/g PCB/g oil has decreased by some 15% since 1982 and that the population of askarel-filled transformers has decreased by some 40% in the same time period. This progress could be continued and accelerated if additional reliable and accepted routes for disposal of PCBs contained in transformers would be developed. The second and third objectives of this project have been to examine two simplified approaches to this end. The second objective was to determine if, by draining PCB-containing oil from transformers and refilling with PCB-free oil, a level of PCBs below 50 ppM (/mu/g/g oil) could be reached with assurance. It appears that reclassification of ''PCB-contaminated'' oil-filled transformers (50--500 /mu/g PCB/g oil) of all ratings by draining and refilling could be done routinely. The third objective was to determine the level of residual PCBs left on the metallic surfaces of askarel-filled transformers which, if these units were refilled with PCB-free mineral transformer oil, would have resulted in concentrations of <50 /mu/g PCB/g oil. It appears that cleaning the surfaces of the metallic components, after careful separation and disposal of the liquid and impregnated solid insulations, to a level of 400 /mu/gPCB/100 cm/sup 2/ would result in transformer carcasses of all sizes which would contain less PCBs than would be found were these transformers to have contained oil at the level of 50 /mu/gPCB/g oil. 7 refs., 6 figs., 9 tabs.

  12. z Transform Chapter Intended Learning Outcomes

    E-Print Network [OSTI]

    So, Hing-Cheung

    z Transform Chapter Intended Learning Outcomes: (i) Understanding the relationship between transform and the Fourier transform for discrete-time signals (ii) Understanding the characteristics and properties of transform (iii) Ability to compute transform and inverse transform (iv) Ability to apply

  13. Particle Detector / Beam Current Transformer

    E-Print Network [OSTI]

    McDonald, Kirk

    Particle Detector / Beam Current Transformer Analysis December 8, 2009 Harold G. Kirk #12;ShotSignal,A.U. Proton Bunch Number Beam Current Transformer - 17011 0 2 4 6 8 0 2 4 6 8 10 12 14 16 18 20 Integrated Transformer Pump 187829 (au) Probe 196504 (au) Ratios: Beam Current 1.046 SF 1.019 2.9% difference #12;Shot

  14. Final Report, "Molecular Design of Hydrocarbon Oxidation Catalytic Processes"

    SciTech Connect (OSTI)

    Professor Francisco Zaera

    2007-08-09T23:59:59.000Z

    The main goal of this project had been to use model systems to correlate selectivities in partial oxidation catalysis with the presence of specific sites on the surface of the catalyst. Extensive work was performed this year on characterizing oxygen-treated nickel surfaces by chemical means. Specifically, the surface chemistry of ammonia coadsorbed with atomic oxygen on Ni(110) single-crystal surfaces was studied by temperature-programmed desorption (TPD) and X-ray photoelectron spectroscopy (XPS). It was determined that at intermediate oxygen coverages direct ammonia adsorption on nickel sites is suppressed, but a new high-temperature reaction regime is generated at 400 K where NHx surface fragments are rehydrogenated concurrently with the production of water and molecular hydrogen. The extensive isotope scrambling and hydrogen transfer seen from nitrogen- to oxygen-containing surface intermediates, and the optimum yields seen for this 400 K state at intermediate oxygen coverages, strongly suggest the direct interaction of the adsorbed ammonia with oxygen atoms at the end of the ĖNiĖO- rows that form upon reconstruction of the surface. Hydrogen transfer between ammonia and oxygen appears to take place directly via hydrogen bonding, and to be reversible but biased towards water formation. An equilibrium is reached between the produced water and the reacting surface oxygen and hydrogen. The strong influence of the OH surface groups on the thermal chemistry of the adsorbed ammonia was interpreted in terms of the adsorbing geometry of the OH groups on the surface, and of hydrogen bonding between adsorbed OH and NH3 species. In terms of alcohol reactivity, the adsorption of 2-iodoethanol, a precursor for the preparation of 2-hydroxyethyl and oxametallacycle surface species, was found to lead to two configurations involving either just the iodine atom or both iodine and hydroxyl ends of the molecule. A complex chemical behavior starts around 140 K with the production of small amounts of ethylene and water, most likely via the concerted decomposition or disproportionation of the adsorbed molecular species. The bulk of the 2-iodoethanol decomposes at about 150 K via an initial carbon-iodine scission to form ĖO(H)CH2CH2Ė (~80%) and 2-hydroxyethyl (~20%) intermediates. Two competing reactions are involved with the subsequent conversion of the 2-hydroxyethyl species around 160 K, a reductive elimination with surface hydrogen to yield ethanol, and a ?-H elimination to surface vinyl alcohol. The ĖO(H)CH2CH2Ė, on the other hand, dehydrogenates to a ĖOCH2CH2Ė oxametallacycle species about the same temperature. Both 2-hydroxyethyl and oxametallacycle species tautomerize to acetaldehyde, around 210 K and above 250 K, respectively, and some of that acetaldehyde desorbs while the rest decomposes to hydrogen and carbon monoxide. We contend that a better understanding of the surface chemistry of oxygen-containing surfaces can lead to better selectivities in catalysis. This is arguably the most important issue in the field of catalysis in the near future, and one that impacts several technologies of interest to DOE such as the manufacturing of speciality chemicals and the control and removal of pollutants. Additional work was performed on the characterization of the chemistry of methyl and methylene adsorbed species on oxygen-treated nickel surfaces. Complex chemistry was observed involving not only hydrogenation and dehydrogenation steps, but also C-C couplings and methylene insertions to produce heavier hydrocarbons, and oxygen insertion reactions that yield oxygenates. Finally, a dual titration technique employing xenon and a chemically sensitive probe was developed to identify minority catalytic sites on oxide surfaces. In the case of oxygen-treated Ni(110) single crystals, it was found that both hydrogen transfer with adsorbed water or ammonia and certain hydrocarbon hydrogenation reactions take place at the end of the ĖNiĖO rows that form in this system. Carbon and nitrogen oxides, on the other hand, display no pre

  15. Monitoring Uranium Transformations Determined by the Evolution of Biogeochemical Processes

    SciTech Connect (OSTI)

    Marsh, Terence L.

    2013-07-30T23:59:59.000Z

    Our contribution to the larger project (ANL) was the phylogenetic analysis of evolved communities capable of reducing metals including uranium.

  16. A VSP transformation technique for the determination of subsurface structure

    E-Print Network [OSTI]

    Malloy, Jeffrey Edward

    1985-01-01T23:59:59.000Z

    offset is 305 m, and reflector depth is 3000 m. . . . . . . . . . . . . . . . . , . . . . . . . 13 5 Plot showing normalized coverage as a function of dip of the reflector. Source offset is 305 m. Reflector depth is 2000 m, 6 Plot showing normalized... Geometry showing significance of as. 10 Physical significance of angle uo. 20 22 11 Stacking fold vs. bin offset for a reflector at 2000 m with a dip of 15'. Source offset is 305 m. 23 12 Stack'ing fold vs. bin offset for a reflector at 2000 m with a...

  17. Power transformers - Part 11: Dry-type transformers

    E-Print Network [OSTI]

    International Electrotechnical Commission. Geneva

    2004-01-01T23:59:59.000Z

    Applies to dry-type power transformers (including auto-transformers) having values of highest voltage for equipment up to and including 36 kV and at least one winding operating at greater than 1,1 kV. Applies to all construction technologies.

  18. Catalytic microwave torrefaction and pyrolysis of Douglas fir pellet to improve biofuel quality .

    E-Print Network [OSTI]

    [No author

    2012-01-01T23:59:59.000Z

    ??The aims of this dissertation were to understand the effects of torrefaction as pretreatment on biomass pyrolysis and catalytic pyrolysis for improving biofuel quality, andÖ (more)

  19. New sub-family of lysozyme-like proteins shows no catalytic activity...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    modest sequence similarity to phage-like lysozyme (N-acetylmuramidase) but appears to lack essential catalytic residues that are strictly conserved in all lysozymes. Close...

  20. E-Print Network 3.0 - auto-catalytic electroless plating Sample...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    electroless plating Page: << < 1 2 3 4 5 > >> 1 Preparation of highly dispersed PEM fuel cell catalysts using electroless deposition methods Summary: (ED). ED is a catalytic...

  1. Solid state oxygen anion and electron mediating membrane and catalytic membrane reactors containing them

    DOE Patents [OSTI]

    Schwartz, Michael (Boulder, CO); White, James H. (Boulder, CO); Sammells, Anthony F. (Boulder, CO)

    2001-01-01T23:59:59.000Z

    A process for production of synthesis gas employing a catalytic membrane reactor wherein the membrane comprises a mixed metal oxide material.

  2. Recent Advances in Catalytic Conversion of Ethanol to Chemicals

    SciTech Connect (OSTI)

    Sun, Junming; Wang, Yong

    2014-04-30T23:59:59.000Z

    With increased availability and decreased cost, ethanol is potentially a promising platform molecule for the production of a variety of value-added chemicals. In this review, we provide a detailed summary of recent advances in catalytic conversion of ethanol to a wide range of chemicals and fuels. We particularly focus on catalyst advances and fundamental understanding of reaction mechanisms involved in ethanol steam reforming (ESR) to produce hydrogen, ethanol conversion to hydrocarbons ranging from light olefins to longer chain alkenes/alkanes and aromatics, and ethanol conversion to other oxygenates including 1-butanol, acetaldehyde, acetone, diethyl ether, and ethyl acetate.

  3. Inversion of the star transform

    E-Print Network [OSTI]

    Fan Zhao; John C. Schotland; Vadim A. Markel

    2014-05-06T23:59:59.000Z

    We define the star transform as a generalization of the broken ray transform introduced by us in previous work. The advantages of using the star transform include the possibility to reconstruct the absorption and the scattering coefficients of the medium separately and simultaneously (from the same data) and the possibility to utilize scattered radiation which, in the case of the conventional X-ray tomography, is discarded. In this paper, we derive the star transform from physical principles, discuss its mathematical properties and analyze numerical stability of inversion. In particular, it is shown that stable inversion of the star transform can be obtained only for configurations involving odd number of rays. Several computationally-efficient inversion algorithms are derived and tested numerically.

  4. ForReview.Confidential-ACS Catalytic Transformation of 1,3,5 -Trimethyl Benzene over USY Zeolite

    E-Print Network [OSTI]

    Al-Khattaf, Sulaiman

    and trimethylbenzenes (TMB) coming from the reforming and pyrolysis of gasoline, into benzene and xylenes via

  5. Catalytic combustor for integrated gasification combined cycle power plant

    DOE Patents [OSTI]

    Bachovchin, Dennis M. (Mauldin, SC); Lippert, Thomas E. (Murrysville, PA)

    2008-12-16T23:59:59.000Z

    A gasification power plant 10 includes a compressor 32 producing a compressed air flow 36, an air separation unit 22 producing a nitrogen flow 44, a gasifier 14 producing a primary fuel flow 28 and a secondary fuel source 60 providing a secondary fuel flow 62 The plant also includes a catalytic combustor 12 combining the nitrogen flow and a combustor portion 38 of the compressed air flow to form a diluted air flow 39 and combining at least one of the primary fuel flow and secondary fuel flow and a mixer portion 78 of the diluted air flow to produce a combustible mixture 80. A catalytic element 64 of the combustor 12 separately receives the combustible mixture and a backside cooling portion 84 of the diluted air flow and allows the mixture and the heated flow to produce a hot combustion gas 46 provided to a turbine 48. When fueled with the secondary fuel flow, nitrogen is not combined with the combustor portion.

  6. Studies Relevent to Catalytic Activation Co & other small Molecules

    SciTech Connect (OSTI)

    Ford, Peter C

    2005-02-22T23:59:59.000Z

    Detailed annual and triannual reports describing the progress accomplished during the tenure of this grant were filed with the Program Manager for Catalysis at the Office of Basic Energy Sciences. To avoid unnecessary duplication, the present report will provide a brief overview of the research areas that were sponsored by this grant and list the resulting publications and theses based on this DOE supported research. The scientific personnel participating in (and trained by) this grant's research are also listed. Research carried out under this DOE grant was largely concerned with the mechanisms of the homogeneous catalytic and photocatalytic activation of small molecules such as carbon monoxide, dihydrogen and various hydrocarbons. Much of the more recent effort has focused on the dynamics and mechanisms of reactions relevant to substrate carbonylations by homogeneous organometallic catalysts. A wide range of modern investigative techniques were employed, including quantitative fast reaction methodologies such as time-resolved optical (TRO) and time-resolved infrared (TRIR) spectroscopy and stopped flow kinetics. Although somewhat diverse, this research falls within the scope of the long-term objective of applying quantitative techniques to elucidate the dynamics and understand the principles of mechanisms relevant to the selective and efficient catalytic conversions of fundamental feedstocks to higher value materials.

  7. HYBRID SELECTIVE NON-CATALYTIC REDUCTION (SNCR)/SELECTIVE CATALYTIC REDUCTION (SCR) DEMONSTRATION FOR THE REMOVAL OF NOx FROM BOILER FLUE GASES

    SciTech Connect (OSTI)

    Jerry B. Urbas

    1999-05-01T23:59:59.000Z

    The U. S. Department of Energy (DOE), Electric Power Research Institute (EPRI), Pennsylvania Electric Energy Research Council, (PEERC), New York State Electric and Gas and GPU Generation, Inc. jointly funded a demonstration to determine the capabilities for Hybrid SNCR/SCR (Selective Non-Catalytic Reduction/Selective Catalytic Reduction) technology. The demonstration site was GPU Generation's Seward Unit No.5 (147MW) located in Seward Pennsylvania. The demonstration began in October of 1997 and ended in December 1998. DOE funding was provided through Grant No. DE-FG22-96PC96256 with T. J. Feeley as the Project Manager. EPRI funding was provided through agreements TC4599-001-26999 and TC4599-002-26999 with E. Hughes as the Project Manager. This project demonstrated the operation of the Hybrid SNCR/SCR NO{sub x} control process on a full-scale coal fired utility boiler. The hybrid technology was expected to provide a cost-effective method of reducing NO{sub x} while balancing capital and operation costs. An existing urea based SNCR system was modified with an expanded-duct catalyst to provide increased NO{sub x} reduction efficiency from the SNCR while producing increased ammonia slip levels to the catalyst. The catalyst was sized to reduce the ammonia slip to the air heaters to less than 2 ppm while providing equivalent NO{sub x} reductions. The project goals were to demonstrate hybrid technology is capable of achieving at least a 55% reduction in NO{sub x} emissions while maintaining less than 2ppm ammonia slip to the air heaters, maintain flyash marketability, verify the cost benefit and applicability of Hybrid post combustion technology, and reduce forced outages due to ammonium bisulfate (ABS) fouling of the air heaters. Early system limitations, due to gas temperature stratification, restricted the Hybrid NO{sub x} reduction capabilities to 48% with an ammonia slip of 6.1 mg/Nm{sup 3} (8 ppm) at the catalyst inlet. After resolving the stratification problem, the catalyst did not have sufficient activity in order to continue the planned test program. Arsenic poisoning was found to be the cause of premature catalyst deactivation.

  8. Formal Transformations and WSL Martin Ward

    E-Print Network [OSTI]

    Singer, Jeremy

    Formal Transformations and WSL Part Two Martin Ward STRL Senior Research Fellow Royal Society of Transformations #12;Types of Transformations A Syntactic Transformation changes the syntax of the program but preserves the exact sequence of operations carried out by the program. Many restructuring transformations

  9. CX-010683: Categorical Exclusion Determination | Department of...

    Broader source: Energy.gov (indexed) [DOE]

    Categorical Exclusion Determination "Glen Canyon Substation Stage 09- 50MVA 23069KV Transformer addition CX(s) Applied: B4.11 Date: 07022013 Location(s): Arizona, Arizona...

  10. CX-008351: Categorical Exclusion Determination | Department of...

    Broader source: Energy.gov (indexed) [DOE]

    Categorical Exclusion Determination Transport and Perform TD&I on Big Hill TX-29 Transformer CX(s) Applied: B1.3 Date: 03282012 Location(s): Texas Offices(s): Strategic...

  11. CX-006257: Categorical Exclusion Determination | Department of...

    Broader source: Energy.gov (indexed) [DOE]

    CX-006257: Categorical Exclusion Determination Ponderosa 500-230 Kilovolt (kV) Transformer Addition CX(s) Applied: B4.6 Date: 06292011 Location(s): Prineville, Oregon...

  12. CX-010715: Categorical Exclusion Determination | Department of...

    Broader source: Energy.gov (indexed) [DOE]

    CX-010715: Categorical Exclusion Determination Replace Bayou Choctaw 500 KVA Power Transformer CX(s) Applied: B1.3 Date: 07092013 Location(s): Louisiana Offices(s): Strategic...

  13. CX-010543: Categorical Exclusion Determination | Department of...

    Broader source: Energy.gov (indexed) [DOE]

    CX-010543: Categorical Exclusion Determination Repair of Big Hill Texas-14 Transformer CX(s) Applied: B1.3 Date: 06242013 Location(s): Texas Offices(s): Strategic...

  14. CX-009705: Categorical Exclusion Determination | Department of...

    Broader source: Energy.gov (indexed) [DOE]

    CX-009705: Categorical Exclusion Determination Lane Substation 500230-kV Transformer Phase Separation Project CX(s) Applied: B4.6 Date: 12062012 Location(s): Oregon...

  15. CX-002435: Categorical Exclusion Determination | Department of...

    Broader source: Energy.gov (indexed) [DOE]

    CX-002435: Categorical Exclusion Determination Redmond Substation 230-115-Kilovolt Transformer Addition CX(s) Applied: B4.6 Date: 05072010 Location(s): Deschutes County, Oregon...

  16. Transformer Efficiency Assessment - Okinawa, Japan

    SciTech Connect (OSTI)

    Thomas L. Baldwin; Robert J. Turk; Kurt S. Myers; Jake P. Gentle; Jason W. Bush

    2012-05-01T23:59:59.000Z

    The US Army Engineering & Support Center, Huntsville (USAESCH), and the US Marine Corps Base (MCB), Okinawa, Japan retained Idaho National Laboratory (INL) to conduct a Transformer Efficiency Assessment of ďkeyĒ transformers located at multiple military bases in Okinawa, Japan. The purpose of this assessment is to support the Marine Corps Base, Okinawa in evaluating medium voltage distribution transformers for potential efficiency upgrades. The original scope of work included the MCB providing actual transformer nameplate data, manufacturerís factory test sheets, electrical system data (kWh), demand data (kWd), power factor data, and electricity cost data. Unfortunately, the MCBís actual data is not available and therefore making it necessary to de-scope the original assessment. Note: Any similar nameplate data, photos of similar transformer nameplates, and basic electrical details from one-line drawings (provided by MCB) are not a replacement for actual load loss test data. It is recommended that load measurements are performed on the high and low sides of transformers to better quantify actual load losses, demand data, and power factor data. We also recommend that actual data, when available, be inserted by MCB Okinawa where assumptions have been made and then the LCC analysis updated. This report covers a generalized assessment of modern U.S. transformers in a three level efficiency category, Low-Level efficiency, Medium-Level efficiency, and High-Level efficiency.

  17. Transformer Efficiency Assessment - Okinawa, Japan

    SciTech Connect (OSTI)

    Thomas L. Baldwin; Robert J. Turk; Kurt S. Myers; Jake P. Gentle; Jason W. Bush

    2012-08-01T23:59:59.000Z

    The US Army Engineering & Support Center, Huntsville (USAESCH), and the US Marine Corps Base (MCB), Okinawa, Japan retained Idaho National Laboratory (INL) to conduct a Transformer Efficiency Assessment of ďkeyĒ transformers located at multiple military bases in Okinawa, Japan. The purpose of this assessment is to support the Marine Corps Base, Okinawa in evaluating medium voltage distribution transformers for potential efficiency upgrades. The original scope of work included the MCB providing actual transformer nameplate data, manufacturerís factory test sheets, electrical system data (kWh), demand data (kWd), power factor data, and electricity cost data. Unfortunately, the MCBís actual data is not available and therefore making it necessary to de-scope the original assessment. Note: Any similar nameplate data, photos of similar transformer nameplates, and basic electrical details from one-line drawings (provided by MCB) are not a replacement for actual load loss test data. It is recommended that load measurements are performed on the high and low sides of transformers to better quantify actual load losses, demand data, and power factor data. We also recommend that actual data, when available, be inserted by MCB Okinawa where assumptions have been made and then the LCC analysis updated. This report covers a generalized assessment of modern U.S. transformers in a three level efficiency category, Low-Level efficiency, Medium-Level efficiency, and High-Level efficiency.

  18. A new perspective on renormalization: the scattering transformation

    E-Print Network [OSTI]

    Michael E. Glinsky

    2014-06-28T23:59:59.000Z

    The scattering transformation developed by Mallat is put into the perspective of field theory. It is shown to be a simultaneous transformation of the field and the "time" parameter explicitly used in the definition of path integrals central to the Lagrangian approach and in the definition of the "time" ordered products used in the Hamiltonian (or canonical) approach. This transformation preserves the form of the S-matrix as "time" ordered products. The transformed "time" coordinate is the inverse "time" scale. This is traditionally the UV cutoff or renormalization parameter in standard approaches to renormalization. The critical calculation will be the determination of the form of the effective action in this transformed coordinate system. This action will now be expressed as an integral of a Lagrangian density that is a function of the renormalization parameter or transformed "time". Other symmetries of the action can be explicitly built into the transformation. It will be demonstrated on a simple 1D $\\phi^4$ field theory. This non-perturbative approach has great potential in possibly being used to renormalize quantum gravity and obtaining expressions for the strongly coupled limit of QCD.

  19. DNA UPTAKE BY TRANSFORMABLE BACTERIA

    SciTech Connect (OSTI)

    LACKS,S.A.

    1999-09-07T23:59:59.000Z

    The various processes of DNA uptake by cells can be categorized as: viral DNA entry, conjugation, or transformation. Within each category, a variety of mechanisms have been found. However, considerable similarities occur among the different mechanisms of conjugation and, especially, transformation. All of these natural mechanisms of DNA transfer are quite elaborate and involve multiple protein components, as the case may be, of the virus, the donor cell, and the recipient cell. The mechanisms of viral infection and conjugation will be discussed mainly with respect to their relevance to transformation.

  20. An atomic-scale analysis of catalytically-assisted chemical vapor deposition of carbon nanotubes

    E-Print Network [OSTI]

    Grujicic, Mica

    An atomic-scale analysis of catalytically-assisted chemical vapor deposition of carbon nanotubes M Growth of carbon nanotubes during transition-metal particles catalytically-assisted thermal decomposition of various nanotube surface and edge reactions (e.g. adsorption of hydrocarbons and hydrogen onto the surface

  1. Control of Natural Gas Catalytic Partial Oxidation for Hydrogen Generation in Fuel Cell Applications1

    E-Print Network [OSTI]

    Peng, Huei

    Control of Natural Gas Catalytic Partial Oxidation for Hydrogen Generation in Fuel Cell Ghosh3 , Huei Peng2 Abstract A fuel processor that reforms natural gas to hydrogen-rich mixture to feed of the hydrogen in the fuel processor is based on catalytic partial oxidation of the methane in the natural gas

  2. Burning Velocities in Catalytically Assisted Self-Propagating High-Temperature Combustion Synthesis Systems

    E-Print Network [OSTI]

    Wooldridge, Margaret S.

    Burning Velocities in Catalytically Assisted Self-Propagating High-Temperature Combustion Synthesis of catalytically assisted self-propagating high-temperature synthesis (SHS) of the tantalum/carbon material system. © 2001 by The Combustion Institute INTRODUCTION Self-propagating high-temperature combustion synthesis

  3. Scaling behavior of optimally structured catalytic microfluidic reactors Fridolin Okkels and Henrik Bruus

    E-Print Network [OSTI]

    Scaling behavior of optimally structured catalytic microfluidic reactors Fridolin Okkels and Henrik of catalytic microfluidic reactors we show that, when optimally structured, these reactors share underlying the reactor using a high-level implementation of topology optimization. DOI: 10.1103/PhysRevE.75.016301 PACS

  4. Micro Catalytic Combustor with Pd/Nano-porous Alumina for High-Temperature Application

    E-Print Network [OSTI]

    Kasagi, Nobuhide

    Micro Catalytic Combustor with Pd/Nano-porous Alumina for High-Temperature Application Takashi: A micro-scale catalytic combustor using high-precision ceramic tape-casting technology has been developed surface reaction of butane. In combustion experiments with a prototype combustor, the wall temperature

  5. Non-uniform Heat Generation in Micro Catalytic Combustor Takashi Okamasa*, Yuji Suzuki, and Nobuhide Kasagi

    E-Print Network [OSTI]

    Kasagi, Nobuhide

    Non-uniform Heat Generation in Micro Catalytic Combustor Takashi Okamasa*, Yuji Suzuki@thtlab.t.u-tokyo.ac.jp Abstract We developed a micro catalytic combustor using high-precision ceramic tape-casting technology and nano-porous alumina catalyst layer. It is found that failure of the ceramic combustor occurs due

  6. The Catalytic Chemistry of HCN+NO over Na- and Ba-Y, FAU: An...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Catalytic Chemistry of HCN+NO over Na- and Ba-Y, FAU: An In Situ FTIR and TPDTPR Study. The Catalytic Chemistry of HCN+NO over Na- and Ba-Y, FAU: An In Situ FTIR and TPDTPR...

  7. MEMS-based fuel cells with integrated catalytic fuel processor and method thereof

    DOE Patents [OSTI]

    Jankowski, Alan F. (Livermore, CA); Morse, Jeffrey D. (Martinez, CA); Upadhye, Ravindra S. (Pleasanton, CA); Havstad, Mark A. (Davis, CA)

    2011-08-09T23:59:59.000Z

    Described herein is a means to incorporate catalytic materials into the fuel flow field structures of MEMS-based fuel cells, which enable catalytic reforming of a hydrocarbon based fuel, such as methane, methanol, or butane. Methods of fabrication are also disclosed.

  8. 2298 IEEE TRANSACTIONS ON APPLIED SUPERCONDUCTIVITY, VOL. 13, NO. 2, JUNE 2003 Cryogenic Cooling Temperature of HTS Transformers

    E-Print Network [OSTI]

    Chang, Ho-Myung

    , thermal optimization, transformer. I. INTRODUCTION MAIN advantages of HTS power transformers are the small and efficiency. As small size and low power consumption are conflicting in determining the oper- ating at around 77 K [1]. Toward the practical applications, an operation of HTS transformers at temperatures well

  9. Mineral Transformation and Biomass Accumulation Associated With

    E-Print Network [OSTI]

    Hubbard, Susan

    Mineral Transformation and Biomass Accumulation Associated With Uranium Bioremediation at Rifle transformation and biomass accumulation, both of which can alter the flow field and potentially bioremediation to understand the biogeochemical processes and to quantify the biomass and mineral transformation/ accumulation

  10. Transforms for the Motion Compensation Residual

    E-Print Network [OSTI]

    Kamisli, Fatih

    The Discrete-Cosine-Transform (DCT) is the most widely used transform in image and video compression. Its use in image compression is often justified by the notion that it is the statistically optimal transform for first-order ...

  11. TRANSFORMING ACADEMIA Historical Developments, Contemporary Perspectives and

    E-Print Network [OSTI]

    Li, Mo

    ISyE 8803A TRANSFORMING ACADEMIA Historical Developments, Contemporary Perspectives independence and this organizational structure represent the first major transformation of academia. These characteristics of academia have persisted for over 900 years and seem immutable. Yet, notable transformations

  12. Ancilla Approximable Quantum State Transformations

    E-Print Network [OSTI]

    Andreas Blass; Yuri Gurevich

    2014-03-30T23:59:59.000Z

    We consider the transformations of quantum states obtainable by a process of the following sort. Combine the given input state with a specially prepared initial state of an auxiliary system. Apply a unitary transformation to the combined system. Measure the state of the auxiliary subsystem. If (and only if) it is in a specified final state, consider the process successful, and take the resulting state of the original (principal) system as the result of the process. We review known information about exact realization of transformations by such a process. Then we present results about approximate realization of finite partial transformations. We consider primarily the issue of approximation to within a specified positive epsilon, but we also address the question of arbitrarily close approximation.

  13. Amendment 1 - Dry-type power transformers

    E-Print Network [OSTI]

    International Electrotechnical Commission. Geneva

    1986-01-01T23:59:59.000Z

    Specifies requirements for dry-type power transformers (including auto-transformers) having values of highest voltage for equipment up to and including 36 kV. The following small and special dry-type transformers are not covered by this standard: -instrument transformers (covered by IEC 60185 and 60186); -transformers for static convertors (covered by IEC 60084, 60119 and 60146). Where IEC standards do not exist for other special transformers, this standard may be applicable as a whole or in part.

  14. Coupled diffusional/displacive transformations

    E-Print Network [OSTI]

    Mujahid, Shafiq Ahmad

    ), TRIP steels (transformation in- duced plasticity), ausforming steels (plastically deformed austenite prior to quenching) and dual phase steels (a mixture of ferrite + martensite obtained by quenching from the 1+ Q' field). a c b d Figure 1... Supersaturated Ferrite Plates 137 v Abstract The displacive transformation of austenite to ferrite in steels containing both substitutional and interstitial elements has been studied. The aim was to establish the conditions under which plates of the product phase...

  15. Metamaterial flexible sheets could transform optics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Metamaterial flexible sheets could transform optics Metamaterial flexible sheets could transform optics Advances would boost security screening systems, infrared thermal cameras,...

  16. The Industrial Transformation of Subarctic Canada

    E-Print Network [OSTI]

    Mathoor, Vineeth

    2011-01-01T23:59:59.000Z

    in the subarctic region of Canada. The role of scientificTransformation of Subarctic Canada By Liza Piper Reviewed byTransformation of Subarctic Canada. Vancouver, BC: UBC

  17. Energy Department Finalizes Loan Guarantee for Transformational...

    Office of Environmental Management (EM)

    Transformational Rooftop Solar Project Energy Department Finalizes Loan Guarantee for Transformational Rooftop Solar Project September 30, 2011 - 3:37pm Addthis Washington D.C. -...

  18. Investigation of Mineral Transformations in Wet Supercritical...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mineral Transformations in Wet Supercritical CO2 by Electron Microscopy. Investigation of Mineral Transformations in Wet Supercritical CO2 by Electron Microscopy. Abstract: The...

  19. Mineralogical transformations controlling acid mine drainage...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mineralogical transformations controlling acid mine drainage chemistry. Mineralogical transformations controlling acid mine drainage chemistry. Abstract: The role of Fe(III)...

  20. Marketing and Market Transformation | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Market Transformation Marketing and Market Transformation Presents how going green will grow your business, as well as how programs can overcome appraisal challenges....

  1. Sandia National Laboratories: Solar Market Transformation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transformation * photovoltaic * Photovoltaics * PV * Renewable Energy * SAND 2011-4654W * Solar Energy * Solar Market Transformation * Solar Research Comments are closed. Renewable...

  2. Building America Expert Meeting: Transforming Existing Buildings...

    Energy Savers [EERE]

    Transforming Existing Buildings through New Media--An Idea Exchange Building America Expert Meeting: Transforming Existing Buildings through New Media--An Idea Exchange This report...

  3. Tantalum pillard montmorillonite: II. Acidic and catalytic properties

    SciTech Connect (OSTI)

    Guiu, G.; Grange, P. [Universite Catholique de Louvain, Louvain-la-Neuve (Belgium)] [Universite Catholique de Louvain, Louvain-la-Neuve (Belgium)

    1997-06-01T23:59:59.000Z

    The acidic and catalytic properties of a series of Ta-PILCs synthesized with a different initial tantalum content were characterized by adsorption of gaseous probe molecules (TPD of ammonia and FTIR spectra of absorbed pyridine) and by the test reaction of 1-butanol dehydration. A large increase of acidity was noted in Ta-PILCs compared to Na-montmorillonite or tantalum oxide. Cross-linking pillars and silica layers of the clay induce stronger Lewis and new Bronsted sites. The lack of basic sites formation is evidenced by the dehydration of 1-butanol to butene selectivity (100%). The incorporation of the tantalum oxide between the montmorillonite sheets produce, within Ta-PILC, acid centers of the same nature as observed for the silicon-tantalum mixed oxides. 32 refs., 4 figs., 5 tabs.

  4. Producing Clean Syngas via Catalytic Reforming for Fuels Production

    SciTech Connect (OSTI)

    Magrini, K. A.; Parent, Y.; Jablonski, W.; Yung, M.

    2012-01-01T23:59:59.000Z

    Thermochemical biomass conversion to fuels and chemicals can be achieved through gasification to syngas. The biomass derived raw syngas contains the building blocks of carbon monoxide and hydrogen as well as impurities such as tars, light hydrocarbons, and hydrogen sulfide. These impurities must be removed prior to fuel synthesis. We used catalytic reforming to convert tars and hydrocarbons to additional syngas, which increases biomass carbon utilization. In this work, nickel based, fluidizable tar reforming catalysts were synthesized and evaluated for tar and methane reforming performance with oak and model syngas in two types of pilot scale fluidized reactors (recirculating and recirculating regenerating). Because hydrogen sulfide (present in raw syngas and added to model syngas) reacts with the active nickel surface, regeneration with steam and hydrogen was required. Pre and post catalyst characterization showed changes specific to the syngas type used. Results of this work will be discussed in the context of selecting the best process for pilot scale demonstration.

  5. Method for selective catalytic reduction of nitrogen oxides

    DOE Patents [OSTI]

    Mowery-Evans, Deborah L. (Broomfield, CO); Gardner, Timothy J. (Albuquerque, NM); McLaughlin, Linda I. (Albuquerque, NM)

    2005-02-15T23:59:59.000Z

    A method for catalytically reducing nitrogen oxide compounds (NO.sub.x, defined as nitric oxide, NO, +nitrogen dioxide, NO.sub.2) in a gas by a material comprising a base metal consisting essentially of CuO and Mn, and oxides of Mn, on an activated metal hydrous metal oxide support, such as HMO:Si. A promoter, such as tungsten oxide or molybdenum oxide, can be added and has been shown to increase conversion efficiency. This method provides good conversion of NO.sub.x to N.sub.2, good selectivity, good durability, resistance to SO.sub.2 aging and low toxicity compared with methods utilizing vanadia-based catalysts.

  6. Method For Selective Catalytic Reduction Of Nitrogen Oxides

    DOE Patents [OSTI]

    Mowery-Evans, Deborah L. (Broomfield, CO); Gardner, Timothy J. (Albuquerque, NM); McLaughlin, Linda I. (Albuquerque, NM)

    2005-02-15T23:59:59.000Z

    A method for catalytically reducing nitrogen oxide compounds (NO.sub.x, defined as nitric oxide, NO, +nitrogen dioxide, NO.sub.2) in a gas by a material comprising a base metal consisting essentially of CuO and Mn, and oxides of Mn, on an activated metal hydrous metal oxide support, such as HMO:Si. A promoter, such as tungsten oxide or molybdenum oxide, can be added and has been shown to increase conversion efficiency. This method provides good conversion of NO.sub.x to N.sub.2, good selectivity, good durability, resistance to SO.sub.2 aging and low toxicity compared with methods utilizing vanadia-based catalysts.

  7. Ex-Situ Catalytic Fast Pyrolysis Technology Pathway

    SciTech Connect (OSTI)

    Biddy, Mary J.; Dutta, Abhijit; Jones, Susanne B.; Meyer, Pimphan A.

    2013-03-31T23:59:59.000Z

    In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to hydrocarbon fuels to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This pathway case investigates converting woody biomass using ex-situ catalytic fast pyrolysis followed by upgrading to gasoline , diesel and jet range blendstocks . Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified.

  8. In-Situ Catalytic Fast Pyrolysis Technology Pathway

    SciTech Connect (OSTI)

    Biddy, Mary J.; Dutta, Abhijit; Jones, Susanne B.; Meyer, Pimphan A.

    2013-03-31T23:59:59.000Z

    In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to hydrocarbon fuels to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This pathway case investigates converting woody biomass using in-situ catalytic fast pyrolysis followed by upgrading to gasoline, diesel, and jet range blendstocks. Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified.

  9. Catalytic Hydrogenation of Bio-Oil for Chemicals and Fuels

    SciTech Connect (OSTI)

    Elliott, Douglas C.

    2006-02-14T23:59:59.000Z

    The scope of work includes optimizing processing conditions and demonstrating catalyst lifetime for catalyst formulations that are readily scaleable to commercial operations. We use a bench-scale, continuous-flow, packed-bed, catalytic, tubular reactor, which can be operated in the range of 100-400 mL/hr., from 50-400 C and up to 20MPa (see Figure 1). With this unit we produce upgraded bio-oil from whole bio-oil or useful bio-oil fractions, specifically pyrolytic lignin. The product oils are fractionated, for example by distillation, for recovery of chemical product streams. Other products from our tests have been used in further testing in petroleum refining technology at UOP and fractionation for product recovery in our own lab. Further scale-up of the technology is envisioned and we will carry out or support process design efforts with industrial partners, such as UOP.

  10. Methods and apparatus for catalytic hydrothermal gasification of biomass

    DOE Patents [OSTI]

    Elliott, Douglas C.; Butner, Robert Scott; Neuenschwander, Gary G.; Zacher, Alan H.; Hart, Todd R.

    2012-08-14T23:59:59.000Z

    Continuous processing of wet biomass feedstock by catalytic hydrothermal gasification must address catalyst fouling and poisoning. One solution can involve heating the wet biomass with a heating unit to a temperature sufficient for organic constituents in the feedstock to decompose, for precipitates of inorganic wastes to form, for preheating the wet feedstock in preparation for subsequent separation of sulfur contaminants, or combinations thereof. Treatment further includes separating the precipitates out of the wet feedstock, removing sulfur contaminants, or both using a solids separation unit and a sulfur separation unit, respectively. Having removed much of the inorganic wastes and the sulfur that can cause poisoning and fouling, the wet biomass feedstock can be exposed to the heterogeneous catalyst for gasification.

  11. Fabrication of fuel cell electrodes and other catalytic structures

    DOE Patents [OSTI]

    Smith, J.L.

    1987-02-11T23:59:59.000Z

    A porous layer of catalyst material suitable for use as an electrode in a molten carbonate fuel cell includes elongated pores substantially extending across the layer thickness. The catalyst layer is prepared by depositing particulate catalyst material into polymeric flocking on a substrate surface by a procedure such as tape casting. The loaded substrate is heated in a series of steps with rising temperatures to set the tape, thermally decompose the substrate with flocking and sinter bond the catalyst particles into a porous catalytic layer with elongated pores across its thickness. Employed as an electrode, the elongated pores provide distribution of reactant gas into contact with catalyst particles wetted by molten electrolyte. 1 fig.

  12. An Energy Analysis of the Catalytic Combustion Burner

    E-Print Network [OSTI]

    Dong, Q.; Zhang, S.; Duan, Z.; Zhou, Q.

    2006-01-01T23:59:59.000Z

    ICEBO2006, Shenzhen, China Heating technologies for energy efficiency Vol.III-1-3 An Energy Analysis of the Catalytic Combustion Burner Qingshan Dong Postgraduate Shihong. Zhang Ph. D. Professor Zhiyin Duan Postgraduate Qi Zhou... for energy efficiency Vol.III-1-3 Tab. 1 Compositions of natural gas Compositions CH4 C2H6 C3H8 i-C4H10 n-C4H10 CO2 N2 O2 Volume fraction (%) 93.908 0.951 0.198 0.012 0.011 2.657 1.894 0.369 Lower heating value (kJ Nm-3) 35906 64397 93244 122857...

  13. Studies of coupled chemical and catalytic coal conversion methods

    SciTech Connect (OSTI)

    Stock, L.M.; Chatterjee, K.; Cheng, C.; Ettinger, M.; Flores, F.; Jiralerspong, S.; Miyake, M.; Muntean, J.

    1991-12-01T23:59:59.000Z

    The objective of this research was to convert coal into a soluble substance under mild conditions. The strategy involved two steps, first to breakdown the macromolecular network of coal, and second to add hydrogen catalytically. We investigated different basic reagents that could, in priciple, break down coal's structure and alkylation strategies that might enhance its solubility. We examined O- and C-alkylation, the importance of the strength of the base, the character of the added alkyl groups and other reaction parameters. This work provided new information concerning the way in which hydrogen bonding, polarization interactions between aromatic structures and covalent bonding could be disrupted and solubility enhanced. The objective of our research was to explore new organochromium chemistry that might be feasible for the hydrogenation of coal under mild conditions.

  14. Studies of coupled chemical and catalytic coal conversion methods

    SciTech Connect (OSTI)

    Stock, L.M.; Chatterjee, K.; Cheng, C.; Ettinger, M.; Flores, F.; Jiralerspong, S.; Miyake, M.; Muntean, J.

    1991-12-01T23:59:59.000Z

    The objective of this research was to convert coal into a soluble substance under mild conditions. The strategy involved two steps, first to breakdown the macromolecular network of coal, and second to add hydrogen catalytically. We investigated different basic reagents that could, in priciple, break down coal`s structure and alkylation strategies that might enhance its solubility. We examined O- and C-alkylation, the importance of the strength of the base, the character of the added alkyl groups and other reaction parameters. This work provided new information concerning the way in which hydrogen bonding, polarization interactions between aromatic structures and covalent bonding could be disrupted and solubility enhanced. The objective of our research was to explore new organochromium chemistry that might be feasible for the hydrogenation of coal under mild conditions.

  15. Catalytic carbon membranes for hydrogen production. Final report

    SciTech Connect (OSTI)

    Damle, A.S.; Gangwal, S.K.

    1992-01-01T23:59:59.000Z

    Commercial carbon composite microfiltration membranes may be modified for gas separation applications by providing a gas separation layer with pores in the 1- to 10-nm range. Several organic polymeric precursors and techniques for depositing a suitable layer were investigated in this project. The in situ polymerization technique was found to be the most promising, and pure component permeation tests with membrane samples prepared with this technique indicated Knudsen diffusion behavior. The gas separation factors obtained by mixed-gas permeation tests were found to depend strongly on gas temperature and pressure indicating significant viscous flow at high-pressure conditions. The modified membranes were used to carry out simultaneous water gas shift reaction and product hydrogen separation. These tests indicated increasing CO conversions with increasing hydrogen separation. A simple process model was developed to simulate a catalytic membrane reactor. A number of simulations were carried out to identify operating conditions leading to product hydrogen concentrations over 90 percent. (VC)

  16. Catalytic gasification studies in a pressurized fluid-bed unit

    SciTech Connect (OSTI)

    Mudge, L.K.; Baker, E.G.; Mitchell, D.H.; Robertus, R.J.; Brown, M.D.

    1983-07-01T23:59:59.000Z

    The purpose of the project is to evaluate the technical and economic feasibility of producing specific gas products via the catalytic gasification of biomass. This report presents the results of research conducted from October 1980 to November 1982. In the laboratory scale studis, active catalysts were developed for generation of synthesis gases from wood by steam gasification. A trimetallic catalyst, Ni-Co-Mo on silica-alumina doped with 2 wt % Na, was found to retain activity indefinitely for generation of a methanol synthesis gas from wood at 1380/sup 0/F (750/sup 0/C) and 1 atm (100 kPa) absolute pressure. Catalysts for generation of a methane-rich gas were deactivated rapidly and could not be regenerated as required for economic application. Sodium carbonate and potassium carbonate were effective as catalysts for conversion of wood to synthesis gases and methane-rich gas and should be economically viable. Catalytic gasification conditions were found to be suitable for processing of alternative feedstocks: bagasse, alfalfa, rice hulls, and almond hulls. The PDU was operated successfully at absolute pressures of up to 10 atm (1000 kPa) and temperatures of up to 1380/sup 0/F (750/sup 0/C). Yields of synthesis gases at elevated pressure were greater than those used for previous economic evaluations. A trimetallic catalyst, Ni-Cu-Mo on silica-alumina, did not display a long life as did the doped trimetallic catalyst used in laboratory studies. A computer program for a Radio Shack TRS-80 Model I microcomputer was developed to evaluate rapidly the economics of producing either methane or methanol from wood. The program is based on economic evaluations reported in previous studies. Improved yields from the PDU studies were found to result in a reduction of about 9 cents/gal in methanol cost.

  17. Catalytic Synthesis of Oxygenates: Mechanisms, Catalysts and Controlling Characteristics

    SciTech Connect (OSTI)

    Kamil Klier; Richard G. Herman

    2005-11-30T23:59:59.000Z

    This research focused on catalytic synthesis of unsymmetrical ethers as a part of a larger program involving oxygenated products in general, including alcohols, ethers, esters, carboxylic acids and their derivatives that link together environmentally compliant fuels, monomers, and high-value chemicals. The catalysts studied here were solid acids possessing strong Br√?¬?√?¬?√?¬?√?¬łnsted acid functionalities. The design of these catalysts involved anchoring the acid groups onto inorganic oxides, e.g. surface-grafted acid groups on zirconia, and a new class of mesoporous solid acids, i.e. propylsulfonic acid-derivatized SBA-15. The former catalysts consisted of a high surface concentration of sulfate groups on stable zirconia catalysts. The latter catalyst consists of high surface area, large pore propylsulfonic acid-derivatized silicas, specifically SBA-15. In both cases, the catalyst design and synthesis yielded high concentrations of acid sites in close proximity to one another. These materials have been well-characterization in terms of physical and chemical properties, as well as in regard to surface and bulk characteristics. Both types of catalysts were shown to exhibit high catalytic performance with respect to both activity and selectivity for the bifunctional coupling of alcohols to form ethers, which proceeds via an efficient SN2 reaction mechanism on the proximal acid sites. This commonality of the dual-site SN2 reaction mechanism over acid catalysts provides for maximum reaction rates and control of selectivity by reaction conditions, i.e. pressure, temperature, and reactant concentrations. This research provides the scientific groundwork for synthesis of ethers for energy applications. The synthesized environmentally acceptable ethers, in part derived from natural gas via alcohol intermediates, exhibit high cetane properties, e.g. methylisobutylether with cetane No. of 53 and dimethylether with cetane No. of 55-60, or high octane properties, e.g. diisopropylether with blending octane No. of 105, and can replace aromatics in liquid fuels.

  18. The Ideal Transformer Description and Circuit Symbol

    E-Print Network [OSTI]

    King, Roger

    The Ideal Transformer Description and Circuit Symbol As with all the other circuit elements, there is a physical transformer commonly used in circuits whose behavior can be discussed in great detail. However, in many cases the practical transformer can be adequately approximated by the "ideal transformer," which

  19. Phase Transformations in Confined Nanosystems

    SciTech Connect (OSTI)

    Shield, Jeffrey E. [Department of Mechanical & Materials Engineering] [Department of Mechanical & Materials Engineering; Belashchenko, Kirill [Department of Physics & Astronomy] [Department of Physics & Astronomy

    2014-04-29T23:59:59.000Z

    This project discovered that non-equilibrium structures, including chemically ordered structures not observed in bulk systems, form in isolated nanoscale systems. Further, a generalized model was developed that effectively explained the suppression of equilibrium phase transformations. This thermodynamic model considered the free energy decrease associated with the phase transformation was less than the increase in energy associated with the formation of an interphase interface, therefore inhibiting the phase transformation. A critical diameter exists where the system transitions to bulk behavior, and a generalized equation was formulated that successfully predicted this transition in the Fe-Au system. This provided and explains a new route to novel structures not possible in bulk systems. The structural characterization was accomplished using transmission electron microscopy in collaboration with Matthew Kramer of Ames Laboratory. The PI and graduate student visited Ames Laboratory several times a year to conduct the experiments.

  20. Catalytic Hydroprocessing of Biomass Fast Pyrolysis Bio-oil to Produce Hydrocarbon Products

    SciTech Connect (OSTI)

    Elliott, Douglas C.; Hart, Todd R.; Neuenschwander, Gary G.; Rotness, Leslie J.; Zacher, Alan H.

    2009-10-01T23:59:59.000Z

    Catalytic hydroprocessing has been applied to biomass fast pyrolysis liquid product (bio-oil) in a bench-scale continuous-flow fixed-bed reactor system. The intent of the research was to develop process technology to convert the bio-oil into a petroleum refinery feedstock to supplement fossil energy resources and to displace imported feedstock. The project was a cooperative research and development agreement among UOP LLC, the National Renewable Energy Laboratory and the Pacific Northwest National Laboratory (PNNL). This paper is focused on the process experimentation and product analysis undertaken at PNNL. The paper describes the experimental methods used and relates the results of the product analyses. A range of catalyst formulations were tested over a range of operating parameters including temperature, pressure, and flow-rate with bio-oil derived from several different biomass feedstocks. Effects of liquid hourly space velocity and catalyst bed temperature were assessed. Details of the process results were presented including mass and elemental balances. Detailed analysis of the products were provided including elemental composition, chemical functional type determined by mass spectrometry, and product descriptors such as density, viscosity and Total Acid Number (TAN). In summation, the paper provides an understanding of the efficacy of hydroprocessing as applied to bio-oil.

  1. Effect of Pt promotion on Ni/Al{sub 2}O{sub 3} for the selective catalytic reduction of NO with hydrogen

    SciTech Connect (OSTI)

    Mihet, Maria, E-mail: maria.mihet@itim-cj.ro; Lazar, Mihaela D., E-mail: maria.mihet@itim-cj.ro; Borodi, G., E-mail: maria.mihet@itim-cj.ro; Almasan, V., E-mail: maria.mihet@itim-cj.ro [National Institute for Research and Development of Isotopic and Molecular Technologies-INCDTIM, 65-103 Donath Str., 400293 Cluj-Napoca (Romania)

    2013-11-13T23:59:59.000Z

    Ni/Al{sub 2}O{sub 3} (10 wt.% Ni) and Ni-Pt/Al{sub 2}O{sub 3} (10 wt.% Ni, 0.5 wt.% Pt) were comparatively tested in the hydrogen selective catalytic reduction process (H{sub 2}-SCR), at reaction temperatures below 350įC. Catalytic activity tests consisted in temperature programmed reactions (TPRea) under plug flow conditions from 50 to 350įC, with a temperature rate of 5įC/min, using a feed stream with a reactant ratio NO:H{sub 2}?=?1:1.3 and a GHSV of 4500 h{sup ?1}. Promotion with Pt increases the catalytic performances of the Ni based catalyst, in respect to NO conversion, N{sub 2} selectivity and N{sub 2} yield. The reaction temperatures for NO conversion above 95% decrease significantly due to Pt addition, from 250įC for Ni/Al{sub 2}O{sub 3} to 125įC for Ni-Pt/Al{sub 2}O{sub 3}. Characterization of catalysts was performed by: X ray powder diffraction (XRD) for the estimation of Ni crystallite size, temperature programmed reduction (TPR) for the catalyst reducibility, temperature programmed desorption of hydrogen (H{sub 2}-TPD) for the investigation of active sites and metal dispersion on the support, N{sub 2} adsorption-desorption isotherms at ?196įC for the determination of total specific surface area and pore size distribution, and H/D isotopic exchange on the catalyst surface.

  2. On the equivalence of state transformer semantics and predicate transformer semantics

    E-Print Network [OSTI]

    Keimel, Klaus

    On the equivalence of state transformer semantics and predicate transformer semantics Dedicated and the author [13] have worked out the equivalence between state transformer semantics and predicate transformer the last section, where the equivalence of predicate and state transformer semantics is finally put

  3. Model Transformations? Transformation Models! Jean Bezivin (A) , Fabian Buttner (B) , Martin Gogolla (B) ,

    E-Print Network [OSTI]

    Gogolla, Martin - Fachbereich 3

    Model Transformations? Transformation Models! Jean Bezivin (A) , Fabian Bň?uttner (B) , Martin of the current work on model transformations seems essentially operational and executable in nature. Executable, transformations can also be viewed as descriptive models by stating only the properties a transformation has

  4. ENGI 2422 Laplace Transforms Page 5-01 5.01 Transforms

    E-Print Network [OSTI]

    George, Glyn

    ENGI 2422 Laplace Transforms Page 5-01 5.01 Transforms In some situations, a difficult problem can be transformed into an easier problem, whose solution can be transformed back into the solution of the original problem. For example, an integrating factor can sometimes be found to transform a non-exact first order

  5. Higher Order BLG Supersymmetry Transformations from 10-Dimensional Super Yang Mills

    E-Print Network [OSTI]

    John Hall; Andrew Low

    2014-03-28T23:59:59.000Z

    We study a Simple Route for constructing the higher order Bagger-Lambert-Gustavsson theory - both supersymmetry transformations and Lagrangian - starting from knowledge of only the $10$-dimensional Super Yang Mills Fermion Supersymmetry transformation. We are able to uniquely determine the four-derivative order corrected supersymmetry transformations, to lowest non-trivial order in Fermions, for the most general three-algebra theory. For the special case of Euclidean three-algbera, we reproduce the result presented in arXiv:$1207.1208$, with significantly less labour. In addition, we apply our method to calculate the quadratic fermion terms in the higher order BLG fermion supersymmetry transformation.

  6. Induced geometry from disformal transformation

    E-Print Network [OSTI]

    Yuan, Fang-Fang

    2015-01-01T23:59:59.000Z

    In this note, we use the disformal transformation to induce a geometry from the manifold which is originally Riemannian. The new geometry obtained here can be considered as a generalization of Weyl integrable geometry. Based on these results, we further propose a geometry which is naturally a generalization of Weyl geometry.

  7. Induced geometry from disformal transformation

    E-Print Network [OSTI]

    Fang-Fang Yuan; Peng Huang

    2015-02-08T23:59:59.000Z

    In this note, we use the disformal transformation to induce a geometry from the manifold which is originally Riemannian. The new geometry obtained here can be considered as a generalization of Weyl integrable geometry. Based on these results, we further propose a geometry which is naturally a generalization of Weyl geometry.

  8. Oxygen transport membrane system and method for transferring heat to catalytic/process reactors

    DOE Patents [OSTI]

    Kelly, Sean M; Kromer, Brian R; Litwin, Michael M; Rosen, Lee J; Christie, Gervase Maxwell; Wilson, Jamie R; Kosowski, Lawrence W; Robinson, Charles

    2014-01-07T23:59:59.000Z

    A method and apparatus for producing heat used in a synthesis gas production is provided. The disclosed method and apparatus include a plurality of tubular oxygen transport membrane elements adapted to separate oxygen from an oxygen containing stream contacting the retentate side of the membrane elements. The permeated oxygen is combusted with a hydrogen containing synthesis gas stream contacting the permeate side of the tubular oxygen transport membrane elements thereby generating a reaction product stream and radiant heat. The present method and apparatus also includes at least one catalytic reactor containing a catalyst to promote the stream reforming reaction wherein the catalytic reactor is surrounded by the plurality of tubular oxygen transport membrane elements. The view factor between the catalytic reactor and the plurality of tubular oxygen transport membrane elements radiating heat to the catalytic reactor is greater than or equal to 0.5.

  9. Effects of copper catalytic reactions on the development of supersonic hydrogen flames

    SciTech Connect (OSTI)

    Chang, S.L.; Lottes, S.A.; Berry, G.F.

    1992-10-01T23:59:59.000Z

    Copper species are present in hydrogen flames in arc heated supersonic ramjet testing facilities. Homogeneous and heterogeneous copper catalytic reactions may affect the flame development by enhancing the recombination of hydrogen atoms. Computer simulation is used to investigate the effects of the catalytic reactions on the reaction and ignition times of the flames. The simulation uses a modified general chemical kinetics computer program to simulate the development of copper-contaminated hydrogen flames under scramjet testing conditions. Reaction times of hydrogen flames are found to be reduced due to the copper catalytic effects, but ignition times are much less sensitive to such effects. The reduction of reaction time depends on copper concentration, particle size (if copper is in the condensed phase), and Mach number (or initial temperature and pressure). As copper concentration increases or the particle size decreases, reaction time decreases. As Mach number increases (or pressure and temperature decrease), the copper catalytic effects are greater.

  10. argonaute-like catalytic triad: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    produc Kik, Pieter 93 Development of a catalytic combustion system for the MIT Micro Gas Turbine Engine MIT - DSpace Summary: As part of the MIT micro-gas turbine engine...

  11. Reaction kinetics of olefin saturation in the hydrodesulfurization of fluid catalytic cracked naphtha

    E-Print Network [OSTI]

    Schumann, Brian Herbert

    2012-06-07T23:59:59.000Z

    U.S. governmental agencies are calling for strict environmental regulations on the quality of gasoline. Fluid catalytic cracked naphtha is an important blending component of the gasoline pool. The majority of the sulfur in the gasoline pool comes...

  12. Comparison of Gas Catalytic and Electric Infrared Performance for Industrial Applications

    E-Print Network [OSTI]

    Eshraghi, R. R.; Welch, D. E.

    A study was conducted to evaluate the performance of gas catalytic and electric infrared for industrial applications. The project focused on fabric drying, paper drying, metal heating, and plastic forming as target industrial applications. Tests...

  13. Reaction mechanisms for catalytic partial oxidation systems : application to ethylene epoxidation

    E-Print Network [OSTI]

    Anantharaman, Bharthwaj

    2005-01-01T23:59:59.000Z

    With the rapid advances in kinetic modeling, building elementary surface mechanisms have become vital to understand the complex chemistry for catalytic partial oxidation systems. Given that there is selected experimental ...

  14. CO-CATALYTIC ABSORPTION LAYERS FOR CONTROLLED LASER-INDUCED CHEMICAL VAPOR DEPOSITION OF CARBON NANOTUBES

    E-Print Network [OSTI]

    Michaelis, F.B.; Weatherup, R.S.; Bayer, B.C.; Bock, M.C.D; Sugime, H.; Caneva, S.; Robertson, J.; Baumberg, J.J.; Hofmann, S.

    2014-02-24T23:59:59.000Z

    The concept of co-catalytic layer structures for controlled laser-induced chemical vapor deposition of carbon nanotubes is established, in which a thin Ta support layer chemically aids the initial Fe catalyst reduction. This enables a significant...

  15. Catalytic roles of Co0 and Co2+ during steam reforming of ethanol...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    roles of Co0 and Co2+ during steam reforming of ethanol on CoMgO catalysts . Catalytic roles of Co0 and Co2+ during steam reforming of ethanol on CoMgO catalysts . Abstract:...

  16. Nanostructured Materials Generated by High-Intensity Ultrasound: Sonochemical Synthesis and Catalytic

    E-Print Network [OSTI]

    Suslick, Kenneth S.

    and Catalytic Studies Kenneth S. Suslick,* Taeghwan Hyeon, and Mingming Fang School of Chemical Sciences. Mater. 1991, 3, 30. (10) Klabunde, K. J.; Zhang, D.; Glavee, G. N.; Sorensen, C. M. Chem. Mater. 1994, 6

  17. Calibration and performance of a selective catalytic reduction (SCR) bench rig for NOx? emissions control

    E-Print Network [OSTI]

    Castro Galnares, SebastiŠn (Castro Galnares Wright Paz)

    2008-01-01T23:59:59.000Z

    A laboratory test rig was designed and built to easily test SCR (Selective Catalytic Reduction) technology. Equipped with three 6 kW heaters, connections for liquid N2 and an assortment of test gases, and a connection with ...

  18. Center for Catalytic Science and Technology Recent Highlights from the Center for

    E-Print Network [OSTI]

    Firestone, Jeremy

    for Catalytic Science and Technology CCST Research Areas Electrocatalysts and hydrogen processing for PEM fuel cells Selective oxidation and selective hydrogenation Biomass to fuels and chemicals phosphates prepared in ionic liquids A straightforward, cost-effective and scalable synthesis

  19. Regional catalytic economic impacts and noise-damage costs of aviation growth

    E-Print Network [OSTI]

    Tam, Ryan Aung Min, 1973-

    2008-01-01T23:59:59.000Z

    There is growing recognition that transportation or infrastructure improvements can have longer-term catalytic impacts economic productivity, which are in addition to the direct, indirect, or induced household spending ...

  20. Enhanced thermal and gas flow performance in a three-way catalytic...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    thermal and gas flow performance in a three-way catalytic converter through use of insulation within the ceramic monolith Enhanced thermal and gas flow performance in a three-way...

  1. Impact of Biodiesel-Based Na on the Selective Catalytic Reduction...

    Broader source: Energy.gov (indexed) [DOE]

    Biodiesel-Based Na on the Selective Catalytic Reduction (SCR) of NO x Using Cu-zeolite D. William Brookshear 1 , Todd J. Toops 2 , William Rohr 1 , Ke Nguyen 1 , and Bruce G....

  2. Catalytic Hydrodeoxygenation of Methyl-Substituted Phenols: Correlations of Kinetic Parameters with Molecular Properties

    E-Print Network [OSTI]

    Simons, Jack

    . Introduction As a result of increasing environmental concerns, catalytic hydrotreating has become an important, oil shale, and tar sands would render the hydrotreating of oxygen-containing com- pounds, mostly

  3. Catalytic Addition of Simple Alkenes to Carbonyl Compounds by Use of Group 10 Metals

    E-Print Network [OSTI]

    Ho, Chun-Yu

    Recent advances using nickel complexes in the activation of unactivated monosubstituted olefins for catalytic intermolecular carbon-carbon bond-forming reactions with carbonyl compounds, such as simple aldehydes, isocyanates, ...

  4. Material transformation designing shape changing interfaces enabled by programmable material anisotropy

    E-Print Network [OSTI]

    Ou, Jifei

    2014-01-01T23:59:59.000Z

    This thesis takes a material perspective on designing transformable interfaces. The structure of material and mechanical properties such as stiffness, can determine not only its static performances, but also, with the help ...

  5. Effect of severity on catalytic hydroprocessed shale oil jet fuels

    SciTech Connect (OSTI)

    Mukherjee, N.L.

    1987-01-01T23:59:59.000Z

    Catalytic hydroprocessed shale oil jet fuels in the USA were characterized and compared with petroleum jet fuel to demonstrate their possibility as a conventional jet fuel substitute. The shale oils (Geokinetics, Occidental, Paraho and Tosco II) were hydrotreated in a 0.0508m ID by K1.524m long reactor containing Ni/Mo/Al/sub 2/O/sub 3/ catalyst. The fractionated hydrogenated shale oils at jet fuel ranges (120-300/degree/C) were analyzed for composition and physical properties. The increasing hydroprocessing severity proportionally decreased nitrogen, sulfur, olefins, aromatics and increased hydrogen content. The nitrogen content was considerable higher even at high severity conditions. Sulfur and olefin contents were lower at all severities. The heat of combustion and the physical properties, except the freezing point, were comparable to petroleum jet fuels. The yields of jet fuels increased proportionally to increased severity. The study showed that high severity hydroprocessing gave better performance in processing shale oils to jet fuels.

  6. TEC as electric generator in an automobile catalytic converter

    SciTech Connect (OSTI)

    Svensson, R. [Chalmers Univ. of Technology, Goeteborg (Sweden); Holmlid, L. [Univ. of Goeteborg (Sweden). Dept. of Physical Chemistry

    1996-12-31T23:59:59.000Z

    Modern cars use more and more electric power due to more on-board electric systems, e.g., ABS brakes, active suspension systems, electric windows, chair adjustment systems and electronic engine control systems. One possible energy source for electricity generation is to use the waste heat from the car`s engine, which generally is as much as 80% of the total energy from the combustion of the gasoline. Maybe the best location to tap the excess heat is the Catalytic Converter (Cat) in the exhaust system or perhaps at the exhaust pipes close to the engine. The Cat must be kept within a certain temperature interval. Large amounts of heat are dissipated through the wall of the Cat. A Thermionic Energy Converter (TEC) in coaxial form could conveniently be located around the ceramic cartridge of the Cat. Since the TEC is a rather good heat insulator before it reaches its working temperature the Cat will reach working temperature faster, and the final temperature of it can be controlled better when encapsulated in a concentric TEC arrangement. It is also possible to regulate the temperature of the Cat and the TEC by controlling the electrical load of the TEC. The possible working temperatures of present and future Cats appear very suitable for the new low work function collector TEC, which has been demonstrated to work down to 470 K.

  7. Low-temperature catalytic gasification of wet industrial wastes

    SciTech Connect (OSTI)

    Elliott, D C; Neuenschwander, G G; Baker, E G; Sealock, Jr, L J; Butner, R S

    1991-04-01T23:59:59.000Z

    Bench-scale reactor tests are in progress at Pacific Northwest Laboratory to develop a low-temperature, catalytic gasification system. The system, licensed under the trade name Thermochemical Environmental Energy System (TEES{reg sign}), is designed for treating a wide variety of feedstocks ranging from dilute organics in water to waste sludges from food processing. This report describes a test program which used a continuous-feed tubular reactor. This test program is an intermediate stage in the process development. The reactor is a laboratory-scale version of the commercial concept as currently envisioned by the process developers. An energy benefit and economic analysis was also completed on the process. Four conceptual commercial installations of the TEES process were evaluated for three food processing applications and one organic chemical manufacturing application. Net energy production (medium-Btu gas) was achieved in all four cases. The organic chemical application was found to be economically attractive in the present situation. Based on sensitivity studies included in the analysis, the three food processing cases will likely become attractive in the near future as waste disposal regulations tighten and disposal costs increase. 21 refs., 2 figs., 9 tabs.

  8. Structural Basis for Catalytic Activation of a Serine Recombinase

    SciTech Connect (OSTI)

    Keenholtz, Ross A.; Rowland, Sally-J.; Boocock, Martin R.; Stark, W. Marshall; Rice, Phoebe A. (Glasgow); (UC)

    2014-10-02T23:59:59.000Z

    Sin resolvase is a site-specific serine recombinase that is normally controlled by a complex regulatory mechanism. A single mutation, Q115R, allows the enzyme to bypass the entire regulatory apparatus, such that no accessory proteins or DNA sites are required. Here, we present a 1.86 {angstrom} crystal structure of the Sin Q115R catalytic domain, in a tetrameric arrangement stabilized by an interaction between Arg115 residues on neighboring subunits. The subunits have undergone significant conformational changes from the inactive dimeric state previously reported. The structure provides a new high-resolution view of a serine recombinase active site that is apparently fully assembled, suggesting roles for the conserved active site residues. The structure also suggests how the dimer-tetramer transition is coupled to assembly of the active site. The tetramer is captured in a different rotational substate than that seen in previous hyperactive serine recombinase structures, and unbroken crossover site DNA can be readily modeled into its active sites.

  9. System Study of Rich Catalytic/Lean burn (RCL) Catalytic Combustion for Natural Gas and Coal-Derived Syngas Combustion Turbines

    SciTech Connect (OSTI)

    Shahrokh Etemad; Lance Smith; Kevin Burns

    2004-12-01T23:59:59.000Z

    Rich Catalytic/Lean burn (RCL{reg_sign}) technology has been successfully developed to provide improvement in Dry Low Emission gas turbine technology for coal derived syngas and natural gas delivering near zero NOx emissions, improved efficiency, extending component lifetime and the ability to have fuel flexibility. The present report shows substantial net cost saving using RCL{reg_sign} technology as compared to other technologies both for new and retrofit applications, thus eliminating the need for Selective Catalytic Reduction (SCR) in combined or simple cycle for Integrated Gasification Combined Cycle (IGCC) and natural gas fired combustion turbines.

  10. Effect of support on catalytic behavior of dispersed rhodium for hydrocarbon hydrogenolyses

    E-Print Network [OSTI]

    Khalifa, Amina Ahmed

    2012-06-07T23:59:59.000Z

    EFFFCT OF SUPPORT ON CATALYTIC BEHAVIOR OF DISPERSED RHODIUM POR HYDROCARBON HYDROGENOLYSES A Thesis AMINA ARMED KHAL'lFA Submi I ted to the Graduate College of Texas AKM University in partial full illment of the requirement for the degree... of MASTER OF SCIENCE December 1986 Major Subject: Chemistry EFFECT OF SUPPORT ON CATALYTIC BEHAVIOR OF DISPERSED RHODIUM FOR HYDROCARBON HYDROGENOLYSES A Thesis by AMINA AHMED KHALIFA Approved as to style and content by: M. P. osynek (Chairman...

  11. Coke gasification: the influence and behavior of inherent catalytic mineral matter

    SciTech Connect (OSTI)

    Mihaela Grigore; Richard Sakurovs; David French; Veena Sahajwalla [Commonwealth Scientific and Industrial Research Organisation (CSIRO), Bangor, NSW (Australia)

    2009-04-15T23:59:59.000Z

    Gasification of coke contributes to its degradation in the blast furnace. In this study, the effect of gasification on the inherent catalytic minerals in cokes and their reciprocal influence on gasification are investigated. The catalytic mineral phases identified in the cokes used in this study were metallic iron, iron sulfides, and iron oxides. Metallic iron and pyrrhotite were rapidly oxidized during gasification to iron oxide. The catalysts had a strong influence on the apparent rates at the initial stages of reaction. As gasification proceeds, their effect on the reaction rate diminishes as a result of reducing the surface contact between catalyst and carbon matrix because of carbon consumption around the catalyst particles; with extended burnout the reactivity of the coke becomes increasingly dependent on surface area. The reaction rate in the initial stages was also influenced by the particle size of the catalytic minerals; for a given catalytic iron level, the cokes whose catalytic minerals were more finely dispersed had a higher apparent reaction rate than cokes containing larger catalytic particles. Iron, sodium, and potassium in the amorphous phase did not appear to affect the reaction rate. 40 refs., 16 figs., 6 tabs.

  12. Catalytic multi-stage process for hydroconversion and refining hydrocarbon feeds

    DOE Patents [OSTI]

    Comolli, Alfred G. (Yardley, PA); Lee, Lap-Keung (Cranbury, NJ)

    2001-01-01T23:59:59.000Z

    A multi-stage catalytic hydrogenation and hydroconversion process for heavy hydrocarbon feed materials such as coal, heavy petroleum fractions, and plastic waste materials. In the process, the feedstock is reacted in a first-stage, back-mixed catalytic reactor with a highly dispersed iron-based catalyst having a powder, gel or liquid form. The reactor effluent is pressure-reduced, vapors and light distillate fractions are removed overhead, and the heavier liquid fraction is fed to a second stage back-mixed catalytic reactor. The first and second stage catalytic reactors are operated at 700-850.degree. F. temperature, 1000-3500 psig hydrogen partial pressure and 20-80 lb./hr per ft.sup.3 reactor space velocity. The vapor and light distillates liquid fractions removed from both the first and second stage reactor effluent streams are combined and passed to an in-line, fixed-bed catalytic hydrotreater for heteroatom removal and for producing high quality naphtha and mid-distillate or a full-range distillate product. The remaining separator bottoms liquid fractions are distilled at successive atmospheric and vacuum pressures, low and intermediate-boiling hydrocarbon liquid products are withdrawn, and heavier distillate fractions are recycled and further upgraded to provide additional low-boiling hydrocarbon liquid products. This catalytic multistage hydrogenation process provides improved flexibility for hydroprocessing the various carbonaceous feedstocks and adjusting to desired product structures and for improved economy of operations.

  13. Nanopattering in CeOx/Cu(111): A New Type of Surface Reconstruction and Enhancement of Catalytic Activity

    SciTech Connect (OSTI)

    Rodriguez J. A.; Senanayake, S.D.; Sadowski, J.; Evans, J.; Kundu, S.; Agnoli, S.; Yang, F.; Stacchiola, D.; Flege, J.I.; Hrbek, J.

    2012-04-05T23:59:59.000Z

    Our results indicate that small amounts of an oxide deposited on a stable metal surface can trigger a massive surface reconstruction under reaction conditions. In low-energy electron microscopy (LEEM) experiments, no reconstruction of Cu(111) is observed after chemisorbing oxygen or after reducing O/Cu(111) in a CO atmosphere. On the other hand, LEEM images taken in situ during the reduction of CeO{sub 2}/CuO{sub 1-x}/Cu(111) show a complex nonuniform transformation of the surface morphology. Ceria particles act as nucleation sites for the growth of copper microterraces once CuO{sub 1-x} is reduced. Can this reconstructed surface be used to enhance the catalytic activity of inverse oxide/metal catalysts? Indeed, CeO{sub x} on reconstructed Cu(111) is an extremely active catalyst for the water-gas shift process (CO + H{sub 2}O {yields} H{sub 2} + CO{sub 2}), with the Cu microterraces providing very efficient sites for the dissociation of water and subsequent reaction with CO.

  14. Bubbling bed catalytic hydropyrolysis process utilizing larger catalyst particles and smaller biomass particles featuring an anti-slugging reactor

    SciTech Connect (OSTI)

    Marker, Terry L; Felix, Larry G; Linck, Martin B; Roberts, Michael J

    2014-09-23T23:59:59.000Z

    This invention relates to a process for thermochemically transforming biomass or other oxygenated feedstocks into high quality liquid hydrocarbon fuels. In particular, a catalytic hydropyrolysis reactor, containing a deep bed of fluidized catalyst particles is utilized to accept particles of biomass or other oxygenated feedstocks that are significantly smaller than the particles of catalyst in the fluidized bed. The reactor features an insert or other structure disposed within the reactor vessel that inhibits slugging of the bed and thereby minimizes attrition of the catalyst. Within the bed, the biomass feedstock is converted into a vapor-phase product, containing hydrocarbon molecules and other process vapors, and an entrained solid char product, which is separated from the vapor stream after the vapor stream has been exhausted from the top of the reactor. When the product vapor stream is cooled to ambient temperatures, a significant proportion of the hydrocarbons in the product vapor stream can be recovered as a liquid stream of hydrophobic hydrocarbons, with properties consistent with those of gasoline, kerosene, and diesel fuel. Separate streams of gasoline, kerosene, and diesel fuel may also be obtained, either via selective condensation of each type of fuel, or via later distillation of the combined hydrocarbon liquid.

  15. ADVANCED BYPRODUCT RECOVERY: DIRECT CATALYTIC REDUCTION OF SO2 TO ELEMENTAL SULFUR

    SciTech Connect (OSTI)

    Robert S. Weber

    1999-05-01T23:59:59.000Z

    Arthur D. Little, Inc., together with its commercialization partner, Engelhard Corporation, and its university partner Tufts, investigated a single-step process for direct, catalytic reduction of sulfur dioxide from regenerable flue gas desulfurization processes to the more valuable elemental sulfur by-product. This development built on recently demonstrated SO{sub 2}-reduction catalyst performance at Tufts University on a DOE-sponsored program and is, in principle, applicable to processing of regenerator off-gases from all regenerable SO{sub 2}-control processes. In this program, laboratory-scale catalyst optimization work at Tufts was combined with supported catalyst formulation work at Engelhard, bench-scale supported catalyst testing at Arthur D. Little and market assessments, also by Arthur D. Little. Objectives included identification and performance evaluation of a catalyst which is robust and flexible with regard to choice of reducing gas. The catalyst formulation was improved significantly over the course of this work owing to the identification of a number of underlying phenomena that tended to reduce catalyst selectivity. The most promising catalysts discovered in the bench-scale tests at Tufts were transformed into monolith-supported catalysts at Engelhard. These catalyst samples were tested at larger scale at Arthur D. Little, where the laboratory-scale results were confirmed, namely that the catalysts do effectively reduce sulfur dioxide to elemental sulfur when operated under appropriate levels of conversion and in conditions that do not contain too much water or hydrogen. Ways to overcome those limitations were suggested by the laboratory results. Nonetheless, at the end of Phase I, the catalysts did not exhibit the very stringent levels of activity or selectivity that would have permitted ready scale-up to pilot or commercial operation. Therefore, we chose not to pursue Phase II of this work which would have included further bench-scale testing, scale-up, pilot-scale (0.5 MW{sub e}) testing at conditions representative of various regenerable SO{sub 2}-control systems, preparation of a commercial process design, and development of a utility-scale demonstration plan.

  16. Ultrafast Transformations in Superionic Nanocrystals

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched Ferromagnetism in Layeredof2014 EIAUltrafast Transformations in Superionic

  17. Continuous space-time transformations

    E-Print Network [OSTI]

    Clťment de Seguins Pazzis; Peter äemrl

    2015-02-04T23:59:59.000Z

    We prove that every continuous map acting on the four-dimensional Minkowski space and preserving light cones in one direction only is either a Poincar\\'e similarity, that is, a product of a Lorentz transformation and a dilation, or it is of a very special degenerate form. In the presence of the continuity assumption the main tool in the proof is a basic result from the homotopy theory of spheres.

  18. Counter urban transformation in Istanbul Beyoglu

    E-Print Network [OSTI]

    Uzunyayla, Sakine Dicle

    2014-01-01T23:59:59.000Z

    Urban transformation has become central to the Turkish government's neo-liberal program of commercial development for Istanbul. These transformations have provoked public discontent and passionate responses, the largest ...

  19. Harmonic Wavelet Transform and Image Approximation

    E-Print Network [OSTI]

    Zhang, Zhihua; Saito, Naoki

    2010-01-01T23:59:59.000Z

    DOI 10.1007/s10851-010-0202-x Harmonic Wavelet Transform andwe approximate f by a harmonic function u such that thebanks. We call this the Harmonic Wavelet Transform (HWT).

  20. Transforms for prediction residuals in video coding

    E-Print Network [OSTI]

    Kam??l?, Fatih

    2010-01-01T23:59:59.000Z

    Typically the same transform, the 2-D Discrete Cosine Transform (DCT), is used to compress both image intensities in image coding and prediction residuals in video coding. Major prediction residuals include the motion ...

  1. Measure Transformer Semantics for Bayesian Machine Learning

    E-Print Network [OSTI]

    Plotkin, Joshua B.

    Measure Transformer Semantics for Bayesian Machine Learning Johannes Borgstr¨om1, Andrew D. Gordon1 define combinators for measure transformers, based on theorems in measure theory, and use these to give

  2. Accelerating the transformation of power systems

    E-Print Network [OSTI]

    Accelerating the transformation of power systems Ancillary Services Peer Exchange with India- to-peer consultation. The 21st Century Power Partnership aims to accelerate the global transformation consultative support Accelerating the transformation of power systems NREL/FS-6A20-61811 · May 2014 15013

  3. Gravity Transform for Input Conditioning in

    E-Print Network [OSTI]

    Paiva, António R. C.

    Gravity Transform for Input Conditioning in Brain Machine Interfaces António R. C. Paiva, José C. Motivation 2. Methods i. Gravity Transform ii. Modeling and output sensitivity analysis 3. Data Analysis #12;3 Outline 1. Motivation 2. Methods i. Gravity Transform ii. Modeling and output sensitivity analysis 3. Data

  4. RECENTER -ADVERSITY INTO TRANSFORMATION Course Description

    E-Print Network [OSTI]

    Coles, William A.

    Center" delivers power tools and real time strategies for creating performance transformation ≠ no matter what and practical system for transforming your communication skills from the inside and outside. ∑ Use real timeRECENTER - ADVERSITY INTO TRANSFORMATION Course Description: Knowing how to use adversity

  5. The TRANSFORMATION OF CONFLICTS AMONG ETHIOPIAN PASTORALISTS

    E-Print Network [OSTI]

    Richner, Heinz

    The TRANSFORMATION OF CONFLICTS AMONG ETHIOPIAN PASTORALISTS: Ethnography of the Notion of Conflict This PhD thesis is concerned with studying the conceptualization, performance and transformation in their nature and have not yet achieved full transformation to peace. The research supports the notion

  6. Transforming and Refining Abstract Constraint Specifications

    E-Print Network [OSTI]

    Walsh, Toby

    Transforming and Refining Abstract Constraint Specifications Alan M. Frisch1 , Brahim Hnich2 , Ian choose model transformations to reduce greatly the amount of effort that is required to solve a problem by systematic search. It is a consid- erable challenge to automate such transformations. A problem may be viewed

  7. LAPPED TRANSFORMS Ricardo L. de Queiroz

    E-Print Network [OSTI]

    de Queiroz, Ricardo L.

    LAPPED TRANSFORMS Ricardo L. de Queiroz Advanced Color Imaging Xerox Corporation queiroz@wrc.xerox.com 0.1 Introduction The idea of a lapped transform (LT, for short) maintaining orthogonality and non with the blocking artifacts so common in traditional block transform coding of images. The idea was to extend

  8. Quantum arithmetic with the Quantum Fourier Transform

    E-Print Network [OSTI]

    Lidia Ruiz-Perez; Juan Carlos Garcia-Escartin

    2014-11-21T23:59:59.000Z

    The Quantum Fourier Transform offers an interesting way to perform arithmetic operations on a quantum computer. We review existing Quantum Fourier Transform adders and multipliers and propose some modifications that extend their capabilities. Among the new circuits, we propose a quantum method to compute the weighted average of a series of inputs in the transform domain.

  9. Non-Hermitian Hamiltonians and similarity transformations

    E-Print Network [OSTI]

    Francisco M. FernŠndez

    2015-02-04T23:59:59.000Z

    We show that a straightforward similarity transformation between an Hermitian operator and a non-Hermitian one enables one to prove the results obtained by other authors by means of a gauge-like transformation. The similarity transformation also reveals the connection with pseudo-Hermiticity

  10. YANGMILLS THEORY AND THE SEGALBARGMANN TRANSFORM

    E-Print Network [OSTI]

    YANG­MILLS THEORY AND THE SEGAL­BARGMANN TRANSFORM BRIAN C. HALL Abstract. Motivated by the results cylinder, with the goal of obtaining an appropriate Segal­Bargmann transform. Using a Gaussian mea­ sure a variant of the classical Segal­Bargmann transform. A simple but non­rigorous argument shows

  11. A Superconducting transformer system for high current cable testing

    E-Print Network [OSTI]

    Godeke, A.

    2010-01-01T23:59:59.000Z

    A Superconducting Transformer System for High Current Cablea Direct-Current (DC) superconducting transformer system forhigh current test of superconducting cables. The transformer

  12. Towards Sustainable Communities: Transitions and Transformations in Environmental Policy

    E-Print Network [OSTI]

    Ghosh, Kaustuv

    2010-01-01T23:59:59.000Z

    Transformations in Environmental Policy Daniel A. MazmanianTransformations in Environmental Policy (2 ed). Cambridge,Transformation in Environmental Policy is the second edition

  13. Cauchy transforms of measures viewed as some functionals of Fourier transforms

    E-Print Network [OSTI]

    Jurek, Zbigniew J.

    Cauchy transforms of measures viewed as some functionals of Fourier transforms Zbigniew J. Jurek Urbanik ABSTRACT. The Cauchy transform of a positive measure plays an impor- tant role in complex analysis and more recently in so-called free probability. We show here that the Cauchy transform restricted

  14. Cauchy transforms of measures viewed as some functionals of Fourier transforms #

    E-Print Network [OSTI]

    Jurek, Zbigniew J.

    Cauchy transforms of measures viewed as some functionals of Fourier transforms # Zbigniew J. Jurek Urbanik ABSTRACT. The Cauchy transform of a positive measure plays an impor­ tant role in complex analysis and more recently in so­called free probability. We show here that the Cauchy transform restricted

  15. Learning transformation rules from transformation examples: An approach based on Relational Concept Analysis

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Learning transformation rules from transformation examples: An approach based on Relational Concept), model transformations are basic and primordial entities, thus easing their design and implementation is an important issue. A quite recently proposed way to create model transformations consists in deducing

  16. Grid Transformation Workshop Results Grid Transformation Workshop Results 2 April 2012

    E-Print Network [OSTI]

    Grid Transformation Workshop Results April 2012 #12;Grid Transformation Workshop Results 2 April 2012 Grid Transformation Workshop Results plications. We will explore the basics of data modeling Transformation Workshop: Advanced Reading Material Product ID 1024659. The material in this report builds upon

  17. Superior catalysts for selective catalytic reduction of nitric oxide. Quarterly technical progress report, April 1, 1995--June 30, 1995

    SciTech Connect (OSTI)

    Li, W.B.; Yang, R.T.

    1995-12-01T23:59:59.000Z

    Efforts continued towards the synthesis of new pillared clay catalysts for the selective catalytic reduction of nitric oxide by ammonia. The possibility of utilizing hydrocarbons was also investigated.

  18. Educating Consumers: New Content on Diesel Vehicles, Diesel Exhaust Fluid, and Selective Catalytic Reduction Technologies on the AFDC (Presentation)

    SciTech Connect (OSTI)

    Brodt-Giles, D.

    2008-08-05T23:59:59.000Z

    Presentation covers new content available on the Alternative Fuels and Advanced Vehicle Data Center regarding diesel vehicles, diesel exhaust fluid, and selective catalytic reduction technologies.

  19. Computing Instantaneous Frequency by normalizing Hilbert Transform

    DOE Patents [OSTI]

    Huang, Norden E.

    2005-05-31T23:59:59.000Z

    This invention presents Normalized Amplitude Hilbert Transform (NAHT) and Normalized Hilbert Transform(NHT), both of which are new methods for computing Instantaneous Frequency. This method is designed specifically to circumvent the limitation set by the Bedorsian and Nuttal Theorems, and to provide a sharp local measure of error when the quadrature and the Hilbert Transform do not agree. Motivation for this method is that straightforward application of the Hilbert Transform followed by taking the derivative of the phase-angle as the Instantaneous Frequency (IF) leads to a common mistake made up to this date. In order to make the Hilbert Transform method work, the data has to obey certain restrictions.

  20. Catalytic two-stage coal hydrogenation process using extinction recycle of heavy liquid fraction

    DOE Patents [OSTI]

    MacArthur, James B. (Denville, NJ); Comolli, Alfred G. (Yardley, PA); McLean, Joseph B. (Somerville, NJ)

    1989-01-01T23:59:59.000Z

    A process for catalytic two-stage hydrogenation and liquefaction of coal with selective extinction recycle of all heavy liquid fractions boiling above a distillation cut point of about 600.degree.-750.degree. F. to produce increased yields of low-boiling hydrocarbon liquid and gas products. In the process, the particulate coal feed is slurried with a process-derived liquid solvent normally boiling above about 650.degree. F. and fed into a first stage catalytic reaction zone operated at conditions which promote controlled rate liquefaction of the coal, while simultaneously hydrogenating the hydrocarbon recycle oils. The first stage reactor is maintained at 710.degree.-800.degree. F. temperature, 1000-4000 psig hydrogen partial pressure, and 10-90 lb/hr per ft.sup.3 catalyst space velocity. Partially hydrogenated material withdrawn from the first stage reaction zone is passed directly to the second stage catalytic reaction zone maintained at 760.degree.-860.degree. F. temperature for further hydrogenation and hydroconversion reactions. A 600.degree.-750.degree. F..sup.+ fraction containing 0-20 W % unreacted coal and ash solids is recycled to the coal slurrying step. If desired, the cut point lower boiling fraction can be further catalytically hydrotreated. By this process, the coal feed is successively catalytically hydrogenated and hydroconverted at selected conditions, to provide significantly increased yields of desirable low-boiling hydrocarbon liquid products and minimal production of hydrocarbon gases, and no net production of undesirable heavy oils and residuum materials.

  1. Catalytic two-stage coal hydrogenation process using extinction recycle of heavy liquid fraction

    DOE Patents [OSTI]

    MacArthur, J.B.; Comolli, A.G.; McLean, J.B.

    1989-10-17T23:59:59.000Z

    A process is described for catalytic two-stage hydrogenation and liquefaction of coal with selective extinction recycle of all heavy liquid fractions boiling above a distillation cut point of about 600--750 F to produce increased yields of low-boiling hydrocarbon liquid and gas products. In the process, the particulate coal feed is slurried with a process-derived liquid solvent normally boiling above about 650 F and fed into a first stage catalytic reaction zone operated at conditions which promote controlled rate liquefaction of the coal, while simultaneously hydrogenating the hydrocarbon recycle oils. The first stage reactor is maintained at 710--800 F temperature, 1,000--4,000 psig hydrogen partial pressure, and 10-90 lb/hr per ft[sup 3] catalyst space velocity. Partially hydrogenated material withdrawn from the first stage reaction zone is passed directly to the second stage catalytic reaction zone maintained at 760--860 F temperature for further hydrogenation and hydroconversion reactions. A 600--750 F[sup +] fraction containing 0--20 W % unreacted coal and ash solids is recycled to the coal slurrying step. If desired, the cut point lower boiling fraction can be further catalytically hydrotreated. By this process, the coal feed is successively catalytically hydrogenated and hydroconverted at selected conditions, to provide significantly increased yields of desirable low-boiling hydrocarbon liquid products and minimal production of hydrocarbon gases, and no net production of undesirable heavy oils and residuum materials. 2 figs.

  2. Effects of dispersion and support on adsorption, catalytic and electronic properties of cobalt/alumina CO hydrogenation catalysts: Annual progress report, August 1, 1987-July 31, 1988

    SciTech Connect (OSTI)

    Bartholomew, C.H.

    1988-08-22T23:59:59.000Z

    An investigation of the effects of surface structure, dispersion, and support on the adsorption, catalytic, and electronic properties of cobalt/alumina is described, the objectives of which are to determine (1) the effects of surface structure and metal dispersion on the adsorption and catalytic properties of cobalt and (2) the effects of decorating support species on metal crystallites and of direct electronic interactions between metal clusters and support, on the adsorption, catalytic and electronic properties of cobalt supported on alumina. During the first year effects of surface structure and dispersion on the adsorption, activity/selectivity, and electronic properties of Co/W single crystal surfaces and alumina-supported cobalt were investigated in a surface science investigation, lab reactor studies, TPD/TPSR studies, and a Moessbauer spectroscopy study. The structure, stability, surface electronic properties, and chemisorptive properties of vapor-deposited cobalt overlayers (0-4 ML) on W(110) and W(100) were studied by Auger electron spectroscopy, low energy electron diffraction, work function changes, and temperature programmed desorption (TPD) of cobalt, hydrogen, and carbon monoxide. The CO chemisorptive properties of the two cobalt overlayers are quite different, CO adsorption being dissociative on the W(100) surface and nondissociative on the W(110) surface; comparison of the results with those for Ni/W(100) indicate that Co/W(100) as a result of electronic interaction with the tungsten substrate. Activities and selectivities of cobalt/alumina catalysts for CO hydrogenation prepared by decomposition of Co/sub 4/(CO)/sub 12/ were determined as functions of metal loading, dispersion, and extent of reduction. Steady-state activity and product molecular weight were found to increase with increasing metal loading (decreasing dispersion and increasing extent of reduction). 10 refs.

  3. High flux solar energy transformation

    DOE Patents [OSTI]

    Winston, R.; Gleckman, P.L.; O'Gallagher, J.J.

    1991-04-09T23:59:59.000Z

    Disclosed are multi-stage systems for high flux transformation of solar energy allowing for uniform solar intensification by a factor of 60,000 suns or more. Preferred systems employ a focusing mirror as a primary concentrative device and a non-imaging concentrator as a secondary concentrative device with concentrative capacities of primary and secondary stages selected to provide for net solar flux intensification of greater than 2000 over 95 percent of the concentration area. Systems of the invention are readily applied as energy sources for laser pumping and in other photothermal energy utilization processes. 7 figures.

  4. High flux solar energy transformation

    DOE Patents [OSTI]

    Winston, Roland (Chicago, IL); Gleckman, Philip L. (Chicago, IL); O'Gallagher, Joseph J. (Flossmoor, IL)

    1991-04-09T23:59:59.000Z

    Disclosed are multi-stage systems for high flux transformation of solar energy allowing for uniform solar intensification by a factor of 60,000 suns or more. Preferred systems employ a focusing mirror as a primary concentrative device and a non-imaging concentrator as a secondary concentrative device with concentrative capacities of primary and secondary stages selected to provide for net solar flux intensification of greater than 2000 over 95 percent of the concentration area. Systems of the invention are readily applied as energy sources for laser pumping and in other photothermal energy utilization processes.

  5. Ultrafast Transformations in Superionic Nanocrystals

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched Ferromagnetism in Layeredof2014 EIAUltrafast Transformations in SuperionicUltrafast

  6. Market Transformation | Department of Energy

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of Inspector General Office0-72.pdfGeorgeDoesn't HappenLow-CostManufacturingMarginalMarket Transformation Market

  7. Transform Solar | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia:FAQ < RAPID Jump to:Seadov Pty LtdSteen,LtdInformation Dixie Valley Geothermal AreaTraillGreenTransform

  8. Modeling Solid Propellant Strand Burner Experiments with Catalytic Additives

    E-Print Network [OSTI]

    Frazier, Corey

    2012-02-14T23:59:59.000Z

    This dissertation studies how nanoadditives influence burning rates through the development and use of a model to conduct parametric studies on nanoadditive interaction and to formulate theories. Decades of research have yet to determine...

  9. Disformal transformation of cosmological perturbations

    E-Print Network [OSTI]

    Masato Minamitsuji

    2014-09-04T23:59:59.000Z

    We investigate the gauge-invariant cosmological perturbations in the gravity and matter frames in the general scalar-tensor theory where two frames are related by the disformal transformation. The gravity and matter frames are the extensions of the Einstein and Jordan frames in the scalar-tensor theory where two frames are related by the conformal transformation, respectively. First, it is shown that the curvature perturbation in the comoving gauge to the scalar field is disformally invariant as well as conformally invariant, which gives the predictions from the cosmological model where the scalar field is responsible both for inflation and cosmological perturbations. Second, in case that the disformally coupled matter sector also contributes to curvature perturbations, we derive the evolution equations of the curvature perturbation in the uniform matter energy density gauge from the energy (non)conservation in the matter sector, which are independent of the choice of the gravity sector. While in the matter frame the curvature perturbation in the uniform matter energy density gauge is conserved on superhorizon scales for the vanishing nonadiabatic pressure, in the gravity frame it is not conserved even if the nonadiabatic pressure vanishes. The formula relating two frames gives the amplitude of the curvature perturbation in the matter frame, once it is evaluated in the gravity frame.

  10. A Transformational View of Cartography W. R. Tobler

    E-Print Network [OSTI]

    Clarke, Keith

    A Transformational View of Cartography W. R. Tobler ABSTRACT. Cartographic transformations aliases are between points, lines, and areas. Substantive transformations occur in map interpolation transformational grammars, as originally devised for linguistics.2, 4 A similar, though less ambitious, attempt

  11. Transformation induced plasticity assisted steels: stress or strain affected martensitic

    E-Print Network [OSTI]

    Cambridge, University of

    Transformation induced plasticity assisted steels: stress or strain affected martensitic transformation? S. Chatterjee and H. K. D. H. Bhadeshia* Transformation induced plasticity (TRIP) assisted steels contain a small quantity of carbon enriched retained austenite, which transforms into martensite during

  12. System and method for determining an ammonia generation rate in a three-way catalyst

    DOE Patents [OSTI]

    Sun, Min; Perry, Kevin L; Kim, Chang H

    2014-12-30T23:59:59.000Z

    A system according to the principles of the present disclosure includes a rate determination module, a storage level determination module, and an air/fuel ratio control module. The rate determination module determines an ammonia generation rate in a three-way catalyst based on a reaction efficiency and a reactant level. The storage level determination module determines an ammonia storage level in a selective catalytic reduction (SCR) catalyst positioned downstream from the three-way catalyst based on the ammonia generation rate. The air/fuel ratio control module controls an air/fuel ratio of an engine based on the ammonia storage level.

  13. NEMA Distribution Transformers, CCE Overview and Update presentation...

    Broader source: Energy.gov (indexed) [DOE]

    Distribution Transformers, CCE Overview and Update presentation, dated 05242011 NEMA Distribution Transformers, CCE Overview and Update presentation, dated 05242011 This...

  14. The Mineralogic Transformation of Ferrihydrite Induced by Heterogeneou...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transformation of Ferrihydrite Induced by Heterogeneous Reaction with Bioreduced Anthraquinone Disulfonate (AQDS The Mineralogic Transformation of Ferrihydrite Induced by...

  15. Energy Technology Solutions: Public-Private Partnerships Transforming...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Solutions: Public-Private Partnerships Transforming Industry, November 2010 Energy Technology Solutions: Public-Private Partnerships Transforming Industry, November 2010...

  16. Structural, textural and catalytic properties of Al-, Ti-pillared clays

    SciTech Connect (OSTI)

    Ramos-Galvan, C.E.; Dominguez, J.M.; Sandoval-Robles, G.; Castillo-Mares, A.; Nava E, N.

    1996-12-31T23:59:59.000Z

    Al-, Ti- and Zr-pillared clays were characterized and NiMo/Pilc`s were tested in HDS reactions. The combination of activity measurements with Moessbauer Spectroscopy and x-ray microanalysis at microscopical scale give insight in the metal phases migration during pillaring, reaction and regeneration steps. {Alpha}-Fe phase in free Fe{sub 2}O{sub 3} islands predominate together with structural Fe{sup 3+} phase, but during the catalytic reaction Fe{sup 2+} forms. Delamination of the Ti- and Zr-Clay supports, together with high Lewis acidity might enhance their catalytic properties.

  17. The Effects of Trace Contaminants on Catalytic Processing of Biomass-Derived Feedstocks

    SciTech Connect (OSTI)

    Elliott, Douglas C.; Peterson, Keith L.; Muzatko, Danielle S.; Alderson, Eric V.; Hart, Todd R.; Neuenschwander, Gary G.

    2004-03-25T23:59:59.000Z

    Trace components in biomass feedstocks are potential catalyst poisons when catalytically processing these materials to value-added chemical products. Trace components include inorganic elements such as alkali metals and alkaline earths, phosphorus or sulfur, aluminum or silicon, chloride, or transition metals. Protein components in biomass feedstocks can lead to formation of peptide fractions (from hydrolysis) or ammonium ions (from more severe breakdown) both of which might interfere with catalysis. The effects of these components on catalytic hydrogenation processing has been studied in batch reactor processing tests

  18. Hydrogen ions produced by plasma-assisted catalytic ionization using nickel grid

    SciTech Connect (OSTI)

    Oohara, W.; Kawata, K.; Hibino, T. [Department of Electronic Device Engineering, Yamaguchi University, Ube 755-8611 (Japan)] [Department of Electronic Device Engineering, Yamaguchi University, Ube 755-8611 (Japan)

    2013-06-15T23:59:59.000Z

    Positive and negative hydrogen ions are produced by plasma-assisted catalytic ionization using a nickel grid, where the irradiation current density of positive ions onto the grid can be controlled by the discharge power. The irradiation energy can be controlled by both the grid potential and the discharge plasma potential. Extraction properties and energy distributions of positive and negative ions produced in the cases of using the grid and a porous nickel plate are compared. Two production mechanisms of negative ions are found in the process of plasma-assisted catalytic ionization.

  19. Development of Micro Catalytic Combustor Using Ceramic Tape Casting Takashi OKAMASA, Gwang-Goo LEE, Yuji SUZUKI, and Nobuhide KASAGI

    E-Print Network [OSTI]

    Kasagi, Nobuhide

    Development of Micro Catalytic Combustor Using Ceramic Tape Casting Takashi OKAMASA, Gwang-Goo LEE@thtlab.t.u-tokyo.ac.jp Abstract Micro-scale catalytic combustor fueled by butane is investigated. A cost-effective ceramic combustor is developed using high- precision tape-casting technology. Nano-porous alumina fabricated through

  20. Diffusion and Catalytic Cracking of 1,3,5 Tri-iso-propyl-benzene in FCC Catalysts

    E-Print Network [OSTI]

    Al-Khattaf, Sulaiman

    1 Diffusion and Catalytic Cracking of 1,3,5 Tri-iso- propyl-benzene in FCC Catalysts S.Al-Khattaf1 describes catalytic cracking experiments developed in a novel CREC Riser Simulator using 1,3,5-Tri-iso

  1. Shape transformations of toroidal vesicles

    E-Print Network [OSTI]

    Hiroshi Noguchi; Ai Sakashita; Masayuki Imai

    2014-10-17T23:59:59.000Z

    Morphologies of genus-1 and 2 toroidal vesicles are studied numerically by dynamically triangulated membrane models and experimentally by confocal laser microscopy. Our simulation results reproduce shape transformations observed in our experiments well. At large reduced volumes of the genus-1 vesicles, obtained vesicle shapes agree with the previous theoretical prediction, in which axisymmetric shapes are assumed: double-necked stomatocyte, discoidal toroid, and circular toroid. However, for small reduced volumes, it is revealed that a non-axisymmetric discoidal toroid and handled discocyte exist in thermal equilibrium in the parameter range, in which the previous theory predicts axisymmetric discoidal shapes. Polygonal toroidal vesicles and subsequent budding transitions are also found. The entropy caused by shape fluctuations slightly modifies the stability of the vesicle shapes.

  2. Quantum Energy Regression using Scattering Transforms

    E-Print Network [OSTI]

    Hirn, Matthew; Mallat, Stephane

    2015-01-01T23:59:59.000Z

    We present a novel approach to the regression of quantum mechanical energies based on a scattering transform of an intermediate electron density representation. A scattering transform is a deep convolution network computed with a cascade of multiscale wavelet transforms. It possesses appropriate invariant and stability properties for quantum energy regression. This new framework removes fundamental limitations of Coulomb matrix based energy regressions, and numerical experiments give state-of-the-art accuracy over planar molecules.

  3. Nonlinear Transformation Group of CAR Fermion Algebra

    E-Print Network [OSTI]

    Mitsuo Abe; Katsunori Kawamura

    2001-10-01T23:59:59.000Z

    Based on our previous work on the recursive fermion system in the Cuntz algebra, it is shown that a nonlinear transformation group of the CAR fermion algebra is induced from a $U(2^p)$ action on the Cuntz algebra ${\\cal O}_{2^p}$ with an arbitrary positive integer $p$. In general, these nonlinear transformations are expressed in terms of finite polynomials in generators. Some Bogoliubov transformations are involved as special cases.

  4. Displacements and Transformations in Caribbean Cultures

    E-Print Network [OSTI]

    Maurer, Bill

    2010-01-01T23:59:59.000Z

    and Transformations in Caribbean Cultures. LIZABETHdefine a "global Caribbean" (p. 3) characterized bythe authors consider the Caribbean as a problematic more

  5. agrobacterium tumefaciens-mediated transformation: Topics by...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    that allows to specify binary relations on graphs Drewes, Frank 51 Constructors transformers Computer Technologies and Information Sciences Websites Summary: Proc. AGTIVE'99,...

  6. Transformers: The Levers and Gears of Electricity

    Broader source: Energy.gov [DOE]

    This video is a great resource for teachers, demonstrating how transformers work. It includes experiments and demos that can be shared with students.

  7. An index 2F2 hypergeometric transform

    E-Print Network [OSTI]

    Zouhair Mouayn

    2011-05-12T23:59:59.000Z

    We construct a new one-parameter family of index hypergeometric transforms associated with the relativistic pseudoharmonic oscillator by using coherent states analysis.

  8. Molecular Mechanisms of Bacterial Mercury Transformation

    SciTech Connect (OSTI)

    smith, jeremy

    2014-04-15T23:59:59.000Z

    Mercury (Hg) is a major global pollutant arising from both natural and anthropogenic sources. Defining the factors that determine the relative affinities of different ligands for the mercuric ion, Hg2+, is critical to understanding its speciation, transformation, and bioaccumulation in the environment. Here, we used quantum chemistry to dissect the relative binding free energies for a series of inorganic anion complexes of Hg2+. The results show that, whereas in the gas phase the binding affinity of two identical anionic ligands (forming HgL2) increases with ligand (LĖ) hardness, in contrast, in the aqueous phase the affinity increases with ligand softness. This switch in affinity upon hydration is shown to result mostly from interactions with only a small number (e.g. one or two) of water molecules. The results yield a clear, robust periodic trend within the chalcogenide and halide groups and are in agreement with the well-known experimentally observed preference of Hg2+ for soft ligands. By comparing the Hg2+ binding of one with two anions, the gas phase preferences are found to arise from the enhancement of reactivity of the cationic complex (HgL+) with the hardness of LĖ. The approach establishes a theoretical basis for understanding Hg speciation in the biosphere.

  9. Multiple Glycogen-binding Sites in Eukaryotic Glycogen Synthase Are Required for High Catalytic Efficiency toward Glycogen

    SciTech Connect (OSTI)

    Baskaran, Sulochanadevi; Chikwana, Vimbai M.; Contreras, Christopher J.; Davis, Keri D.; Wilson, Wayne A.; DePaoli-Roach, Anna A.; Roach, Peter J.; Hurley, Thomas D. (Indiana-Med); (Des Moines U)

    2012-12-10T23:59:59.000Z

    Glycogen synthase is a rate-limiting enzyme in the biosynthesis of glycogen and has an essential role in glucose homeostasis. The three-dimensional structures of yeast glycogen synthase (Gsy2p) complexed with maltooctaose identified four conserved maltodextrin-binding sites distributed across the surface of the enzyme. Site-1 is positioned on the N-terminal domain, site-2 and site-3 are present on the C-terminal domain, and site-4 is located in an interdomain cleft adjacent to the active site. Mutation of these surface sites decreased glycogen binding and catalytic efficiency toward glycogen. Mutations within site-1 and site-2 reduced the V{sub max}/S{sub 0.5} for glycogen by 40- and 70-fold, respectively. Combined mutation of site-1 and site-2 decreased the V{sub max}/S{sub 0.5} for glycogen by >3000-fold. Consistent with the in vitro data, glycogen accumulation in glycogen synthase-deficient yeast cells ({Delta}gsy1-gsy2) transformed with the site-1, site-2, combined site-1/site-2, or site-4 mutant form of Gsy2p was decreased by up to 40-fold. In contrast to the glycogen results, the ability to utilize maltooctaose as an in vitro substrate was unaffected in the site-2 mutant, moderately affected in the site-1 mutant, and almost completely abolished in the site-4 mutant. These data show that the ability to utilize maltooctaose as a substrate can be independent of the ability to utilize glycogen. Our data support the hypothesis that site-1 and site-2 provide a 'toehold mechanism,' keeping glycogen synthase tightly associated with the glycogen particle, whereas site-4 is more closely associated with positioning of the nonreducing end during catalysis.

  10. DOI: 10.1002/chem.200700579 Selective Catalytic Oxidation of Ethanol to Acetic Acid on Dispersed

    E-Print Network [OSTI]

    Iglesia, Enrique

    % ethanol conversion) were much higher than in previous re- ports. The presence of TiO2 during syn- thesisDOI: 10.1002/chem.200700579 Selective Catalytic Oxidation of Ethanol to Acetic Acid on Dispersed Mo, easily separated from organic reactants and products, and gas-phase process- es that avoid solid

  11. Production of renewable jet fuel range alkanes and commodity chemicals from integrated catalytic

    E-Print Network [OSTI]

    California at Riverside, University of

    and techno-economic analysis of a catalytic process for the conversion of whole biomass into drop-in aviation processing of biomass Jesse Q. Bond,a Aniruddha A. Upadhye,b Hakan Olcay,c Geoffrey A. Tompsett,d Jungho Jae fuels with maximal carbon yields. The combined research areas highlighted include biomass pretreatment

  12. ENGINEERING SCALE UP OF RENEWABLE HYDROGEN PRODUCTION BY CATALYTIC STEAM REFORMING OF PEANUT

    E-Print Network [OSTI]

    ENGINEERING SCALE UP OF RENEWABLE HYDROGEN PRODUCTION BY CATALYTIC STEAM REFORMING OF PEANUT SHELLS, and academic organizations is developing a steam reforming process to be demonstrated on the gaseous byproducts of this engineering demonstration project. After an initial problem with the heaters that required modification

  13. Catalytic study of SOFC electrode materials in engine exhaust gas Pauline Briaulta

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Catalytic study of SOFC electrode materials in engine exhaust gas atmosphere Pauline Briaulta. An innovative application of this system would be to recover energy from exhaust gas of a thermal engine in a mixture of hydrocarbons (propane, propene), oxygen, carbon monoxide, carbon dioxide, hydrogen and water

  14. Aligned carbon nanotube with electro-catalytic activity for oxygen reduction reaction

    DOE Patents [OSTI]

    Liu, Di-Jia (Naperville, IL); Yang, Junbing (Westmont, IL); Wang, Xiaoping (Naperville, IL)

    2010-08-03T23:59:59.000Z

    A catalyst for an electro-chemical oxygen reduction reaction (ORR) of a bundle of longitudinally aligned carbon nanotubes having a catalytically active transition metal incorporated longitudinally in said nanotubes. A method of making an electro-chemical catalyst for an oxygen reduction reaction (ORR) having a bundle of longitudinally aligned carbon nanotubes with a catalytically active transition metal incorporated throughout the nanotubes, where a substrate is in a first reaction zone, and a combination selected from one or more of a hydrocarbon and an organometallic compound containing an catalytically active transition metal and a nitrogen containing compound and an inert gas and a reducing gas is introduced into the first reaction zone which is maintained at a first reaction temperature for a time sufficient to vaporize material therein. The vaporized material is then introduced to a second reaction zone maintained at a second reaction temperature for a time sufficient to grow longitudinally aligned carbon nanotubes over the substrate with a catalytically active transition metal incorporated throughout the nanotubes.

  15. Use of Simulation To Optimize NOx Abatement by Absorption and Selective Catalytic Reduction

    E-Print Network [OSTI]

    Liu, Y. A.

    Use of Simulation To Optimize NOx Abatement by Absorption and Selective Catalytic Reduction Andrew This paper describes the development of an ASPEN PLUS simulation model for a commercial NOx abatement system nitric acid production and the abatement of NOx- laden effluent streams for environmental protection.1

  16. Coating of a stainless steel tube-wall catalytic reactor with thermally treated polysiloxane thick films

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Coating of a stainless steel tube-wall catalytic reactor with thermally treated polysiloxane thick stainless steel by plasma assisted chemical vapour deposition process. Thicknesses up to 10¬Ķm were developed glass-like silicon oxide but cannot be related to an amorphous silica structure. At 1273K the steel

  17. Comparison of the Catalytic Oxidation Reaction on Graphene Oxide and Reduced Graphene Oxide

    E-Print Network [OSTI]

    Kim, Sehun

    Comparison of the Catalytic Oxidation Reaction on Graphene Oxide and Reduced Graphene Oxide Laboratory (PAL), Pohang 790-784, Republic of Korea ABSTRACT: The capacities of graphene oxide (GO) and reduced graphene oxide (rGO) films grown on silicon substrate to cause the aniline to azobenzene oxidation

  18. Catalytically Assisted Self-Propagating High-Temperature Synthesis of Tantalum Carbide Powders

    E-Print Network [OSTI]

    Wooldridge, Margaret S.

    Catalytically Assisted Self-Propagating High-Temperature Synthesis of Tantalum Carbide Powders Troy high-temperature combustion synthesis (SHS) of materials has gained recognition for its energy in the context of gas-phase and solid-phase transport models. I. Introduction IN RECENT years, self-propagating

  19. ==================== !"#$%&'()*+,-+./,0)12 Development of Micro Ejector for Butane Catalytic Combustor

    E-Print Network [OSTI]

    Kasagi, Nobuhide

    pumps ambient air to the combustion chamber by utilizing the vapor pressure of liquified fuel. Catalytic with the excessive heat of the exhaust gas. The advantage of using ejector is that air-entrainment is achieved without an additional air container or a micro pump, and thus the system should be simple, safe

  20. Prediction of catalytic residues in proteins using machine-learning techniques

    E-Print Network [OSTI]

    Prediction of catalytic residues in proteins using machine-learning techniques Natalia V. Petrova) and prediction of protein function using various properties of proteins and amino acids (2). Prediction of the functional residues is a challenging and interesting task. The results of such prediction could