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Note: This page contains sample records for the topic "determination catalytic transformation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Catalytic Transformation of Waste Carbon Dioxide into Valuable Products  

NLE Websites -- All DOE Office Websites (Extended Search)

Catalytic Transformation of Waste Catalytic Transformation of Waste Carbon Dioxide into Valuable Products Background Many industrial processes contribute large amounts of carbon dioxide (CO 2 ) to the earth's atmosphere. In an effort to reduce the amount of CO 2 released to the atmosphere, the U.S. Department of Energy (DOE) is funding efforts to develop CO 2 capture and storage technologies. In addition to permanent storage of CO 2 in underground reservoirs, some

2

Speech pitch determination based on Hilbert-Huang transform  

Science Conference Proceedings (OSTI)

Pitch determination is an essential part of speech recognition and speech processing. In this paper, a new pitch determination method based on Hilbert-Huang Transform (HHT) is presented. The assumption of linearity of the speech-production process and ... Keywords: Hilbert-Huang transform, pitch determination, speech analysis

Hai Huang; Jiaqiang Pan

2006-04-01T23:59:59.000Z

3

TRANSFORMATION  

SciTech Connect

Transformation, which alters the genetic makeup of an individual, is a concept that intrigues the human imagination. In Streptococcus pneumoniae such transformation was first demonstrated. Perhaps our fascination with genetics derived from our ancestors observing their own progeny, with its retention and assortment of parental traits, but such interest must have been accelerated after the dawn of agriculture. It was in pea plants that Gregor Mendel in the late 1800s examined inherited traits and found them to be determined by physical elements, or genes, passed from parents to progeny. In our day, the material basis of these genetic determinants was revealed to be DNA by the lowly bacteria, in particular, the pneumococcus. For this species, transformation by free DNA is a sexual process that enables cells to sport new combinations of genes and traits. Genetic transformation of the type found in S. pneumoniae occurs naturally in many species of bacteria (70), but, initially only a few other transformable species were found, namely, Haemophilus influenzae, Neisseria meningitides, Neisseria gonorrheae, and Bacillus subtilis (96). Natural transformation, which requires a set of genes evolved for the purpose, contrasts with artificial transformation, which is accomplished by shocking cells either electrically, as in electroporation, or by ionic and temperature shifts. Although such artificial treatments can introduce very small amounts of DNA into virtually any type of cell, the amounts introduced by natural transformation are a million-fold greater, and S. pneumoniae can take up as much as 10% of its cellular DNA content (40).

LACKS,S.A.

2003-10-09T23:59:59.000Z

4

CX-000735: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

CX-000735: Categorical Exclusion Determination Catalytic Transformation of Waste Carbon Dioxide into Valuable Products CX(s) Applied: A9, B3.6 Date: 01222010...

5

CX-000737: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

CX-000737: Categorical Exclusion Determination Catalytic Transformation of Waste Carbon Dioxide into Valuable Products CX(s) Applied: A9, B3.6 Date: 01222010...

6

CX-000736: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

CX-000736: Categorical Exclusion Determination Catalytic Transformation of Waste Carbon Dioxide into Valuable Products CX(s) Applied: A9, B3.6 Date: 01222010...

7

Determination of Response Threshold of Optical Current Transformer  

Science Conference Proceedings (OSTI)

For an all-electric ship, power system is not only the energy source of power distribution, but also the energy source of ship driving system, so it is the development direction of ship in future. The optical current transformer is very important in ... Keywords: Response, Resolution threshold, Optical Current Transformer, Microminiaturization

Wang Jia-Ying, Fu Hai-Yan, Zhang Guo-Qing, Yu Wen-Bin, Cheng Song, Guo Zhi-Zhong

2012-12-01T23:59:59.000Z

8

TRANSFORMER  

DOE Patents (OSTI)

Transformers of a type adapted for use with extreme high power vacuum tubes where current requirements may be of the order of 2,000 to 200,000 amperes are described. The transformer casing has the form of a re-entrant section being extended through an opening in one end of the cylinder to form a coaxial terminal arrangement. A toroidal multi-turn primary winding is disposed within the casing in coaxial relationship therein. In a second embodiment, means are provided for forming the casing as a multi-turn secondary. The transformer is characterized by minimized resistance heating, minimized external magnetic flux, and an economical construction.

Baker, W.R.

1959-08-25T23:59:59.000Z

9

Catalytic Reforming  

Science Conference Proceedings (OSTI)

Don Little's Catalytic Reforming deals exclusively with reforming. With the increasing need for unleaded gasoline, the importance of this volume has escalated since it combines various related aspects of reforming technology into a single publication. For those with no practical knowledge of catalytic reforming, the chemical reactions, flow schemes and how the cat reformer fits into the overall refinery process will be of interest. Contents include: Catalytic reforming in refinery processing: How catalytic reformers work - chemical reactions; Process design; The catalyst, process variables and unit operation; Commercial processes; BTX operation; Feed preparation; naphtha hydrotreating and catalytic reforming; Index.

Little, D.M.

1985-01-01T23:59:59.000Z

10

Catalytic Distillation  

E-Print Network (OSTI)

Catalytic Distillation' refers to a chemical process which performs both a catalyzed reaction and primary fractionation of the reaction components simultaneously. A structured catalyst which also is an effective distillation component has been patented by Chemical Research & Licensing Co., Houston, Texas, and developed in a joint venture with Neochem Corp., Houston, Texas, and the Department of Energy. The catalytic distillation packing has been commercially demonstrated successfully with nearly three years continuous service for an acid catalyzed reaction in a carbon steel distillation tower.

Smith, L. A., Jr.; Hearn, D.; Wynegar, D. P.

1984-01-01T23:59:59.000Z

11

Catalytic Acceleration of Carbon Capture via Bio-processes  

Science Conference Proceedings (OSTI)

Recently, transformation of the biomass into fuels such as bioethanol, biodiesel or functional chemicals by means of catalytic and enzymatic conversion has ...

12

CSD: Research: Catalytic Science  

NLE Websites -- All DOE Office Websites (Extended Search)

Catalytic Science Catalytic Science The DOE Chemical Energy program supports basic research in the area of chemical transformations or conversions which are fundamental to new or existing concepts of energy production and storage. A further goal of the program is to identify and develop environmentally benign approaches to the synthesis of chemicals via routes requiring a minimal consumption of energy. These objectives lead naturally to an emphasis on catalysis. Novel homogeneous and heterogeneous catalysts are constantly being sought to enable the synthesis of desired products from nontraditional reactants, often with the aim of minimizing the production of toxic intermediates or byproducts, or to enable the more efficient production of products via existing reaction pathways. To this end, efforts are undertaken to

13

Evaluating Transformer Losses  

E-Print Network (OSTI)

This paper outlines how to determine what transformer losses cost and how to evaluate transformer bids to optimize the investment.

Grun, R. L. Jr.

1989-09-01T23:59:59.000Z

14

Catalytic reforming  

Science Conference Proceedings (OSTI)

This patent describes a process for the catalytic reforming of a feedstock which contains at least one reformable organic compound. The process consists of contacting the feedstock under suitable reforming conditions with a catalyst composition selected from the group consisting of a catalyst. The catalyst essentially consists of zinc oxide and a spinel structure alumina. Another catalyst consists essentially of a physical mixture of zinc titanate and a spinel structure alumina in the presence of sufficient added hydrogen to substantially prevent the formation of coke. Insufficient zinc is present in the catalyst composition for the formation of a bulk zinc aluminate.

Aldag, A.W. Jr.

1986-01-28T23:59:59.000Z

15

CATALYTIC BIOMASS LIQUEFACTION  

E-Print Network (OSTI)

LBL-11 019 UC-61 CATALYTIC BIOMASS LIQUEFACTION Sabri Ergun,Catalytic Liquefaction of Biomass,n M, Seth, R. Djafar, G.of California. CATALYTIC BIOMASS LIQUEFACTION QUARTERLY

Ergun, Sabri

2013-01-01T23:59:59.000Z

16

Catalytic reactor  

DOE Patents (OSTI)

A catalytic reactor is provided with one or more reaction zones each formed of set(s) of reaction tubes containing a catalyst to promote chemical reaction within a feed stream. The reaction tubes are of helical configuration and are arranged in a substantially coaxial relationship to form a coil-like structure. Heat exchangers and steam generators can be formed by similar tube arrangements. In such manner, the reaction zone(s) and hence, the reactor is compact and the pressure drop through components is minimized. The resultant compact form has improved heat transfer characteristics and is far easier to thermally insulate than prior art compact reactor designs. Various chemical reactions are contemplated within such coil-like structures such that as steam methane reforming followed by water-gas shift. The coil-like structures can be housed within annular chambers of a cylindrical housing that also provide flow paths for various heat exchange fluids to heat and cool components.

Aaron, Timothy Mark (East Amherst, NY); Shah, Minish Mahendra (East Amherst, NY); Jibb, Richard John (Amherst, NY)

2009-03-10T23:59:59.000Z

17

Raney nickel catalytic device  

DOE Patents (OSTI)

A catalytic device for use in a conventional coal gasification process which includes a tubular substrate having secured to its inside surface by expansion a catalytic material. The catalytic device is made by inserting a tubular catalytic element, such as a tubular element of a nickel-aluminum alloy, into a tubular substrate and heat-treating the resulting composite to cause the tubular catalytic element to irreversibly expand against the inside surface of the substrate.

O' Hare, Stephen A. (Vienna, VA)

1978-01-01T23:59:59.000Z

18

Wavelet Correlation Transform Method and Gradient Method to Determine Aerosol Layering from Lidar Returns: Some Comments  

Science Conference Proceedings (OSTI)

Identification of aerosol layers on lidar measurements is of interest to determine ranges where aerosol properties are likely to be homogeneous and to infer transport phenomena and atmosphere dynamics. For instance, the range-corrected ...

Adolfo Comerón; Michaël Sicard; Francesc Rocadenbosch

2013-06-01T23:59:59.000Z

19

CATALYTIC LIQUEFACTION OF BIOMASS  

E-Print Network (OSTI)

liquid Fuels from Biomass: "Catalyst Screening and KineticUC-61 (l, RCO osn CDL or BIOMASS CATALYTIC LIQUEFACTION ManuCATALYTIC LIQUEFACTION OF BIOMASS Manu Seth, Roger Djafar,

Seth, Manu

2012-01-01T23:59:59.000Z

20

CATALYTIC BIOMASS LIQUEFACTION  

E-Print Network (OSTI)

Solvent Systems Catalystic Biomass Liquefaction Investigatereactor Product collection Biomass liquefaction process12-13, 1980 CATALYTIC BIOMASS LIQUEFACTION Sabri Ergun,

Ergun, Sabri

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "determination catalytic transformation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Process for catalytic reforming  

Science Conference Proceedings (OSTI)

An improved catalytic reforming process is disclosed wherein hydrogen and light hydrocarbons generated in the catalytic reaction zone are passed to a hydrogen production/purification zone and and reacted and processed therein to produce substantially pure hydrogen. A portion of the hydrogen is then admixed with the charge stock to the catalytic reforming zone to provide the hydrogen requirements of the catalytic reforming reaction zone.

James, R. B. Jr.

1984-11-20T23:59:59.000Z

22

Rich catalytic injection  

SciTech Connect

A gas turbine engine includes a compressor, a rich catalytic injector, a combustor, and a turbine. The rich catalytic injector includes a rich catalytic device, a mixing zone, and an injection assembly. The injection assembly provides an interface between the mixing zone and the combustor. The injection assembly can inject diffusion fuel into the combustor, provides flame aerodynamic stabilization in the combustor, and may include an ignition device.

Veninger, Albert (Coventry, CT)

2008-12-30T23:59:59.000Z

23

Multizone catalytic reforming process  

Science Conference Proceedings (OSTI)

This patent describes a process for the catalytic reforming of hydrocarbons comprising contacting the hydrocarbon feed in two sequential catalyst zones. It comprises: a first catalyst zone contains a first catalytic composite consisting essentially of a platinum component, a germanium component, a refractory inorganic oxide, and a halogen component; and a second catalyst zone contains a second catalytic composite comprising a platinum component, a germanium component, a refractory inorganic oxide, a halogen component, and catalytically effective amounts of a metal promoter selected from rhenium, rhodium, ruthenium, cobalt, nickel, and iridium, and mixtures thereof.

Moser, M.C.; Lawson, R.J.; Antos, G.J.; Wang, L.; Parulekar, V.N.

1990-05-29T23:59:59.000Z

24

Catalytic reforming process  

Science Conference Proceedings (OSTI)

A catalytic reforming process is disclosed in which substantially all of the heat requirements of the product stabilizer column is supplied by multiple indirect heat exchange.

Peters, K.D.

1983-10-11T23:59:59.000Z

25

Catalytic conversion of biomass.  

E-Print Network (OSTI)

?? Catalytic processes for conversion of biomass to transportation fuels have gained an increasing attention in sustainable energy production. The biomass can be converted to… (more)

Calleja Aguado, Raquel

2013-01-01T23:59:59.000Z

26

Determination of sympathovagal balance in ventricular tachiarrythmia patients with implanted cardioverter defibrillators using wavelet transform and MLPNN  

Science Conference Proceedings (OSTI)

HRV is a nonstationary signal that includes sympathovagal balance (SB) information related to LF/HF ratio between the sympathetic and parasympathetic nervous systems. In this paper, a solution based on Daubechies wavelet transform (dbN) and multilayer ... Keywords: Heart rate variability, Autonomic nervous system, MLPNN, Sympathovagal balance (SB), Wavelet transform

Suleyman Bilgin; Omer Halil Çolak; Ovunc Polat; Etem Koklukaya

2009-03-01T23:59:59.000Z

27

Catalytic cracking process  

Science Conference Proceedings (OSTI)

Processes and apparatus for providing improved catalytic cracking, specifically improved recovery of olefins, LPG or hydrogen from catalytic crackers. The improvement is achieved by passing part of the wet gas stream across membranes selective in favor of light hydrocarbons over hydrogen.

Lokhandwala, Kaaeid A. (Union City, CA); Baker, Richard W. (Palo Alto, CA)

2001-01-01T23:59:59.000Z

28

Catalytic distillation structure  

DOE Patents (OSTI)

Catalytic distillation structure for use in reaction distillation columns, a providing reaction sites and distillation structure and consisting of a catalyst component and a resilient component intimately associated therewith. The resilient component has at least about 70 volume % open space and being present with the catalyst component in an amount such that the catalytic distillation structure consist of at least 10 volume % open space.

Smith, Jr., Lawrence A. (Bellaire, TX)

1984-01-01T23:59:59.000Z

29

Categorical Exclusion Determinations: American Recovery and Reinvestment  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

22, 2010 22, 2010 CX-000710: Categorical Exclusion Determination Virginia Revision 3 - Economic Development Market Title CX(s) Applied: A9, A11, B5.1 Date: 01/22/2010 Location(s): Virginia Office(s): Energy Efficiency and Renewable Energy, National Energy Technology Laboratory January 22, 2010 CX-000735: Categorical Exclusion Determination Catalytic Transformation of Waste Carbon Dioxide into Valuable Products CX(s) Applied: A9, B3.6 Date: 01/22/2010 Location(s): Newtown Square, Pennsylvania Office(s): Fossil Energy, National Energy Technology Laboratory January 22, 2010 CX-000736: Categorical Exclusion Determination Catalytic Transformation of Waste Carbon Dioxide into Valuable Products CX(s) Applied: A9, B3.6 Date: 01/22/2010 Location(s): Cincinnati, Ohio Office(s): Fossil Energy, National Energy Technology Laboratory

30

Multizone catalytic reforming process  

Science Conference Proceedings (OSTI)

This patent describes a process for the catalytic reforming of hydrocarbons comprising contacting the hydrocarbon feed in two sequential catalyst zones. It comprises: an initial catalyst zone which is a fixed-bed system and contains an initial catalytic composite comprising a platinum component, a germanium component, a refractory inorganic oxide, and a halogen component; and a terminal catalyst zone which is a moving-bed system with associated continuous catalyst regeneration and contains a terminal catalytic composite having the essential absence of germanium and comprising a platinum component, a refractory inorganic oxide, a halogen component, and catalytically effective amounts of a metal promoter selected from one or more of the rhenium, tin, indium, rhodium, ruthenium, cobalt, nickel, and iridium.

Moser, M.; Lawson, R.J.; Wang, L.; Parulekar, V.; Peer, R.L.; Hamlin, C.R.

1991-01-15T23:59:59.000Z

31

Catalytic distillation process  

DOE Patents (OSTI)

A method for conducting chemical reactions and fractionation of the reaction mixture comprising feeding reactants to a distillation column reactor into a feed zone and concurrently contacting the reactants with a fixed bed catalytic packing to concurrently carry out the reaction and fractionate the reaction mixture. For example, a method for preparing methyl tertiary butyl ether in high purity from a mixed feed stream of isobutene and normal butene comprising feeding the mixed feed stream to a distillation column reactor into a feed zone at the lower end of a distillation reaction zone, and methanol into the upper end of said distillation reaction zone, which is packed with a properly supported cationic ion exchange resin, contacting the C.sub.4 feed and methanol with the catalytic distillation packing to react methanol and isobutene, and concurrently fractionating the ether from the column below the catalytic zone and removing normal butene overhead above the catalytic zone.

Smith, Jr., Lawrence A. (Bellaire, TX)

1982-01-01T23:59:59.000Z

32

Catalytic distillation process  

DOE Patents (OSTI)

A method is described for conducting chemical reactions and fractionation of the reaction mixture comprising feeding reactants to a distillation column reactor into a feed zone and concurrently contacting the reactants with a fixed bed catalytic packing to concurrently carry out the reaction and fractionate the reaction mixture. For example, a method for preparing methyl tertiary butyl ether in high purity from a mixed feed stream of isobutene and normal butene comprising feeding the mixed feed stream to a distillation column reactor into a feed zone at the lower end of a distillation reaction zone, and methanol into the upper end of said distillation reaction zone, which is packed with a properly supported cationic ion exchange resin, contacting the C[sub 4] feed and methanol with the catalytic distillation packing to react methanol and isobutene, and concurrently fractionating the ether from the column below the catalytic zone and removing normal butene overhead above the catalytic zone.

Smith, L.A. Jr.

1982-06-22T23:59:59.000Z

33

Catalytic distillation structure  

DOE Patents (OSTI)

Catalytic distillation structure is described for use in reaction distillation columns, and provides reaction sites and distillation structure consisting of a catalyst component and a resilient component intimately associated therewith. The resilient component has at least about 70 volume % open space and is present with the catalyst component in an amount such that the catalytic distillation structure consists of at least 10 volume % open space. 10 figs.

Smith, L.A. Jr.

1984-04-17T23:59:59.000Z

34

Preconversion catalytic deoxygenation of phenolic functional groups  

Science Conference Proceedings (OSTI)

The deoxygenation of phenols is a conceptually simple, but unusually difficult chemical transformation to achieve. Aryl carbon-oxygen bond cleavage is a chemical transformation of importance in coal liquefaction and the upgrading of coal liquids as well as in the synthesis of natural products. This proposed research offers the possibility of effecting the selective catalytic deoxygenation of phenolic functional groups using CO. A program of research for the catalytic deoxygenation of phenols, via a low energy mechanistic pathway that is based on the use of the CO/CO{sub 2} couple to remove phenolic oxygen atoms, is underway. We are focusing on systems which have significant promise as catalysts: Ir(triphos)OPh, (Pt(triphos)OPh){sup +} and Rh(triphos)OPh. Our studies of phenol deoxygenation focus on monitoring the reactions for the elementary processes upon which catalytic activity will depend: CO insertion into M-OPh bonds, CO{sub 2} elimination from aryloxy carbonyls {l brace}M-C(O)-O-Ph{r brace}, followed by formation of a coordinated benzyne intermediate.

Kubiak, C.P.

1991-01-01T23:59:59.000Z

35

Catalytic Coal Gasification Process  

NLE Websites -- All DOE Office Websites (Extended Search)

Catalytic Coal Gasification Process Catalytic Coal Gasification Process for the Production of Methane-Rich Syngas Opportunity Research is active on the patent pending technology, titled "Production of Methane-Rich Syngas from Fuels Using Multi-functional Catalyst/Capture Agent." This technology is available for licensing and/or further collaborative research from the U.S. Department of Energy's National Energy Technology Laboratory. Overview Reducing pollution emitted by coal and waste power plants in an economically viable manner and building power plants that co-generate fuels and chemicals during times of low electricity demand are pressing goals for the energy industry. One way to achieve these goals in an economically viable manner is through the use of a catalytic gasifier that

36

Catalytic hydrotreating process  

DOE Patents (OSTI)

Carbonaceous liquids boiling above about 300.degree. C such as tars, petroleum residuals, shale oils and coal-derived liquids are catalytically hydrotreated by introducing the carbonaceous liquid into a reaction zone at a temperature in the range of 300.degree. to 450.degree. C and a pressure in the range of 300 to 4000 psig for effecting contact between the carbonaceous liquid and a catalytic transition metal sulfide in the reaction zone as a layer on a hydrogen permeable transition metal substrate and then introducing hydrogen into the reaction zone by diffusing the hydrogen through the substrate to effect the hydrogenation of the carbonaceous liquid in the presence of the catalytic sulfide layer.

Karr, Jr., Clarence (Morgantown, WV); McCaskill, Kenneth B. (Morgantown, WV)

1978-01-01T23:59:59.000Z

37

Catalytic Solutions Inc CSI | Open Energy Information  

Open Energy Info (EERE)

Developer of the breakthrough catalytic coating technology and the Mixed Phase Catalyst (MPCTM), and also manufacturer of catalytic converters. References Catalytic...

38

Steam reformer with catalytic combustor  

DOE Patents (OSTI)

A steam reformer is disclosed having an annular steam reforming catalyst bed formed by concentric cylinders and having a catalytic combustor located at the center of the innermost cylinder. Fuel is fed into the interior of the catalytic combustor and air is directed at the top of the combustor, creating a catalytic reaction which provides sufficient heat so as to maintain the catalytic reaction in the steam reforming catalyst bed. Alternatively, air is fed into the interior of the catalytic combustor and a fuel mixture is directed at the top. The catalytic combustor provides enhanced radiant and convective heat transfer to the reformer catalyst bed.

Voecks, Gerald E. (La Crescenta, CA)

1990-03-20T23:59:59.000Z

39

VOC Destruction by Catalytic Combustion Microturbine  

SciTech Connect

This project concerned the application of a catalytic combustion system that has been married to a micro-turbine device. The catalytic combustion system decomposes the VOC's and transmits these gases to the gas turbine. The turbine has been altered to operate on very low-level BTU fuels equivalent to 1.5% methane in air. The performance of the micro-turbine for VOC elimination has some flexibility with respect to operating conditions, and the system is adaptable to multiple industrial applications. The VOC source that was been chosen for examination was the emissions from coal upgrading operations. The overall goal of the project was to examine the effectiveness of a catalytic combustion based system for elimination of VOCs while simultaneously producing electrical power for local consumption. Project specific objectives included assessment of the feasibility for using a Flex-Microturbine that generates power from natural gas while it consumes VOCs generated from site operations; development of an engineering plan for installation of the Flex-Microturbine system; operation of the micro-turbine through various changes in site and operation conditions; measurement of the VOC destruction quantitatively; and determination of the required improvements for further studies. The micro-turbine with the catalytic bed worked effectively to produce power on levels of fuel much lower than the original turbine design. The ability of the device to add or subtract supplemental fuel to augment the amount of VOC's in the inlet air flow made the device an effective replacement for a traditional flare. Concerns about particulates in the inlet flow and the presence of high sulfur concentrations with the VOC mixtures was identified as a drawback with the current catalytic design. A new microturbine design was developed based on this research that incorporates a thermal oxidizer in place of the catalytic bed for applications where particulates or contamination would limit the lifetime of the catalytic bed.

Tom Barton

2009-03-10T23:59:59.000Z

40

VOC Destruction by Catalytic Combustion Microturbine  

SciTech Connect

This project concerned the application of a catalytic combustion system that has been married to a micro-turbine device. The catalytic combustion system decomposes the VOC's and transmits these gases to the gas turbine. The turbine has been altered to operate on very low-level BTU fuels equivalent to 1.5% methane in air. The performance of the micro-turbine for VOC elimination has some flexibility with respect to operating conditions, and the system is adaptable to multiple industrial applications. The VOC source that was been chosen for examination was the emissions from coal upgrading operations. The overall goal of the project was to examine the effectiveness of a catalytic combustion based system for elimination of VOCs while simultaneously producing electrical power for local consumption. Project specific objectives included assessment of the feasibility for using a Flex-Microturbine that generates power from natural gas while it consumes VOCs generated from site operations; development of an engineering plan for installation of the Flex-Microturbine system; operation of the micro-turbine through various changes in site and operation conditions; measurement of the VOC destruction quantitatively; and determination of the required improvements for further studies. The micro-turbine with the catalytic bed worked effectively to produce power on levels of fuel much lower than the original turbine design. The ability of the device to add or subtract supplemental fuel to augment the amount of VOC's in the inlet air flow made the device an effective replacement for a traditional flare. Concerns about particulates in the inlet flow and the presence of high sulfur concentrations with the VOC mixtures was identified as a drawback with the current catalytic design. A new microturbine design was developed based on this research that incorporates a thermal oxidizer in place of the catalytic bed for applications where particulates or contamination would limit the lifetime of the catalytic bed.

Tom Barton

2009-03-10T23:59:59.000Z

Note: This page contains sample records for the topic "determination catalytic transformation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Catalytic coal liquefaction process  

SciTech Connect

An improved process for catalytic solvent refining or hydroliquefaction of non-anthracitic coal at elevated temperatures under hydrogen pressure in a solvent comprises using as catalyst a mixture of a 1,2- or 1,4-quinone and an alkaline compound, selected from ammonium, alkali metal, and alkaline earth metal oxides, hydroxides or salts of weak acids.

Garg, Diwakar (Macungie, PA); Sunder, Swaminathan (Allentown, PA)

1986-01-01T23:59:59.000Z

42

Catalytic conversion of LPG  

Science Conference Proceedings (OSTI)

The low reactivity of light paraffins has long hindered their utilization as petrochemical feedstocks. Except for their use in ethylene crackers, LPG fractions have traditionally been consumed as fuel. New catalytic processes now being commercialized open new avenues for the utilization of LPG as sources of valuable petrochemical intermediates. This paper discusses processes for the dehydrogenation and aromatization of LPG.

Pujado, P.R.; Vora, B.V.; Mowry, J.R.; Anderson, R.F.

1986-01-01T23:59:59.000Z

43

Catalytic coal liquefaction process  

DOE Patents (OSTI)

An improved process for catalytic solvent refining or hydroliquefaction of non-anthracitic coal at elevated temperatures under hydrogen pressure in a solvent comprises using as catalyst a mixture of a 1,2- or 1,4-quinone and an alkaline compound, selected from ammonium, alkali metal, and alkaline earth metal oxides, hydroxides or salts of weak acids. 1 fig.

Garg, D.; Sunder, S.

1986-12-02T23:59:59.000Z

44

Catalytic reforming process  

Science Conference Proceedings (OSTI)

A catalytic reforming process is disclosed wherein the reboiler heat requirements of the stabilizer column are supplied by means of indirect heat exchange with hot combustion gases in the reforming reactants fired heater convection heating section. Heat in excess of the reboiler requirements is passed to the stabilizer column with control being effected by removal of excess heat from the column.

James, R.B. Jr.

1984-02-14T23:59:59.000Z

45

Catalytic skeletal isomerization  

Science Conference Proceedings (OSTI)

The catalytic reforming of a feedstock which contains a derivative of cyclopentane or which contains organic compounds which are convertible to a derivative of cyclopentane is carried out in the presence of a hydrogrel of zinc titanate and a suitable acidic material. Also, the attrition resistance of zinc titanate is improved by incorporating the zinc titanate into a hydrogel structure.

Aldag, A.W.

1984-05-01T23:59:59.000Z

46

Effect of thermal treatment on coke reactivity and catalytic iron mineralogy  

SciTech Connect

Iron minerals in coke can catalyze its gasification and may affect coke behavior in the blast furnace. The catalytic behavior of iron depends largely upon the nature of the iron-bearing minerals. To determine the mineralogical changes that iron could undergo in the blast furnace, cokes made from three coals containing iron present in different mineral forms (clays, carbonates, and pyrite) were examined. All coke samples were heat-treated in a horizontal furnace at 1373, 1573, and 1773 K and then gasified with CO{sub 2} at 1173 K in a fixed bed reactor (FBR). Coke mineralogy was characterized using quantitative X-ray diffraction (XRD) analysis of coke mineral matter prepared by low-temperature ashing (LTA) and field emission scanning electron microscopy combined with energy dispersive X-ray analysis (FESEM/EDS). The mineralogy of the three cokes was most notably distinguished by differing proportions of iron-bearing phases. During heat treatment and subsequent gasification, iron-containing minerals transformed to a range of minerals but predominantly iron-silicides and iron oxides, the relative amounts of which varied with heat treatment temperature and gasification conditions. The relationship between initial apparent reaction rate and the amount of catalytic iron minerals - pyrrhotite, metallic iron, and iron oxides - was linear and independent of heat treatment temperature at total catalyst levels below 1 wt %. The study showed that the coke reactivity decreased with increasing temperature of heat treatment due to decreased levels of catalytic iron minerals (largely due to formation of iron silicides) as well as increased ordering of the carbon structure. The study also showed that the importance of catalytic mineral matter in determining reactivity declines as gasification proceeds. 37 refs., 13 figs., 7 tabs.

Byong-chul Kim; Sushil Gupta; David French; Richard Sakurovs; Veena Sahajwalla [University of New South Wales, Sydney, NSW (Australia). Centre for Sustainable Materials Research and Technology

2009-07-15T23:59:59.000Z

47

Catalytic thermal barrier coatings  

Science Conference Proceedings (OSTI)

A catalyst element (30) for high temperature applications such as a gas turbine engine. The catalyst element includes a metal substrate such as a tube (32) having a layer of ceramic thermal barrier coating material (34) disposed on the substrate for thermally insulating the metal substrate from a high temperature fuel/air mixture. The ceramic thermal barrier coating material is formed of a crystal structure populated with base elements but with selected sites of the crystal structure being populated by substitute ions selected to allow the ceramic thermal barrier coating material to catalytically react the fuel-air mixture at a higher rate than would the base compound without the ionic substitutions. Precious metal crystallites may be disposed within the crystal structure to allow the ceramic thermal barrier coating material to catalytically react the fuel-air mixture at a lower light-off temperature than would the ceramic thermal barrier coating material without the precious metal crystallites.

Kulkarni, Anand A. (Orlando, FL); Campbell, Christian X. (Orlando, FL); Subramanian, Ramesh (Oviedo, FL)

2009-06-02T23:59:59.000Z

48

Concentric catalytic combustor  

DOE Patents (OSTI)

A catalytic combustor (28) includes a tubular pressure boundary element (90) having a longitudinal flow axis (e.g., 56) separating a first portion (94) of a first fluid flow (e.g., 24) from a second portion (95) of the first fluid flow. The pressure boundary element includes a wall (96) having a plurality of separate longitudinally oriented flow paths (98) annularly disposed within the wall and conducting respective portions (100, 101) of a second fluid flow (e.g., 26) therethrough. A catalytic material (32) is disposed on a surface (e.g., 102, 103) of the pressure boundary element exposed to at least one of the first and second portions of the first fluid flow.

Bruck, Gerald J. (Oviedo, FL); Laster, Walter R. (Oviedo, FL)

2009-03-24T23:59:59.000Z

49

Catalytic reforming catalyst  

Science Conference Proceedings (OSTI)

An improved catalyst, having a reduced fouling rate when used in a catalytic reforming process, said catalyst comprising platinum disposed on an alumina support wherein the alumina support is obtained by removing water from aluminum hydroxide produced as a by-product from a ziegler higher alcohol synthesis reaction, and wherein the alumina is calcined at a temperature of 1100-1400/sup 0/F so as to have a surface area of 165 to 215 square meters per gram.

Buss, W.C.; Kluksdahl, H.E.

1980-12-09T23:59:59.000Z

50

Appell Transformation and Canonical Transforms  

E-Print Network (OSTI)

The interpretation of the optical Appell transformation, as previously elaborated in relation to the free-space paraxial propagation under both a rectangular and a circular cylindrical symmetry, is reviewed. Then, the caloric Appell transformation, well known in the theory of heat equation, is shown to be amenable for a similar interpretation involving the Laplace transform rather than the Fourier transform, when dealing with the 1D heat equation. Accordingly, when considering the radial heat equation, suitably defined Hankel-type transforms come to be involved in the inherent Appell transformation. The analysis is aimed at outlining the link between the Appell transformation and the canonical transforms.

Torre, Amalia

2011-01-01T23:59:59.000Z

51

Riesz transforms for Dunkl transform  

E-Print Network (OSTI)

In this paper we obtain the $L^p$-boundedness of Riesz transforms for Dunkl transform for all $1

Amri, Béchir

2011-01-01T23:59:59.000Z

52

Catalytic distillation : design and application of a catalytic distillation column.  

E-Print Network (OSTI)

??Catalytic Distillation (CD) is a hybrid technology that utilizes the dynamics of si- multaneous reaction and separation in a single process unit to achieve a… (more)

Nieuwoudt, Josias Jakobus (Jako)

2005-01-01T23:59:59.000Z

53

Integral transformation and Darboux transformation  

E-Print Network (OSTI)

We review Darboux-Crum transformation of Heun's differential equation. By rewriting an integral transformation of Heun's differential equation into a form of elliptic functions, we see that the integral representation is a generalization of Darboux-Crum transformation. We also consider conservation of monodromy with respect to the transformations.

Takemura, Kouichi

2009-01-01T23:59:59.000Z

54

Catalytic reforming methods  

DOE Patents (OSTI)

A catalytic reforming method is disclosed herein. The method includes sequentially supplying a plurality of feedstocks of variable compositions to a reformer. The method further includes adding a respective predetermined co-reactant to each of the plurality of feedstocks to obtain a substantially constant output from the reformer for the plurality of feedstocks. The respective predetermined co-reactant is based on a C/H/O atomic composition for a respective one of the plurality of feedstocks and a predetermined C/H/O atomic composition for the substantially constant output.

Tadd, Andrew R; Schwank, Johannes

2013-05-14T23:59:59.000Z

55

Catalytic reforming process  

Science Conference Proceedings (OSTI)

This patent describes a catalytic reforming process which comprises contacting a naphtha range feed with a low acidity extrudate comprising an intermediate and/or a large pore acidic zeolite bound with a low acidity refractory oxide under reforming conditions to provide a reaction product of increased aromatic content, the extrudate having been prepared with at least an extrusion-facilitating amount of a low acidity refractory oxide in colloidal form and containing at least one metal species selected from the platinum group metals.

Absil, R.P.; Huss, A. Jr.; McHale, W.D.; Partridge, R.D.

1989-06-13T23:59:59.000Z

56

Lorentz Transformations  

E-Print Network (OSTI)

This paper describes a particularly didactic and transparent derivation of basic properties of the Lorentz group. The generators for rotations and boosts along an arbitrary direction, as well as their commutation relations, are written as functions of the unit vectors that define the axis of rotation or the direction of the boost (an approach that can be compared with the one that in electrodynamics, works with the electric and magnetic fields instead of the Maxwell stress tensor). For finite values of the angle of rotation or the boost's velocity, collectively denoted by V, the existence of an exponential expansion for the coordinate transformation's matrix, M (in terms of GV where G is the generator) requires that the matrix's derivative with respect to V, be equal to GM. This condition can only be satisfied if the transformation is additive as it is indeed the case for rotations, but not for velocities. If it is assumed, however, that for boosts such an expansion exists, with V = V(v), v being the velocity, and if the above condition is imposed on the boost's matrix then its expression in terms of hyperbolic cosh(V) and sinh(V} is recovered, and the expression for V(= arc tanh(v)) is determined. A general Lorentz transformation can be written as an exponential containing the sum of a rotation and a boost, which to first order is equal to the product of a boost with a rotation. The calculations of the second and third order terms show that the equations for the generators used in this paper, allow to reliably infer the expressions for the higher order generators, without having recourse to the commutation relations. The transformationmatrices for Weyl spinors are derived for finite values of the rotation and velocity, and field representations, leading to the expression for the angular momentum operator, are studied.

Bernard R. Durney

2011-03-01T23:59:59.000Z

57

Catalytic dewaxing of middle distillates  

SciTech Connect

The fractionation and stripping equipment of a middle distillate catalytic dewaxing unit may be eliminated by integrating the catalytic dewaxing unit with a catalytic cracking unit. The light cycle oil sidestream from the cat cracker fractionator, bypasses the sidestream stripper and serves as the feed to the catalytic dewaxing unit. The dewaxed product is separated into a gasoline fraction which is recycled for fractionation in the cat cracker fractionator and a fuel oil fraction which is recycled to the cat cracker sidestream stripper for removal of light materials to produce a low pour fuel oil meeting product specifications.

Antal, M.J.

1982-06-01T23:59:59.000Z

58

Novel Catalytic Membrane Reactors  

DOE Green Energy (OSTI)

There are many industrial catalytic organic reversible reactions with amines or alcohols that have water as one of the products. Many of these reactions are homogeneously catalyzed. In all cases removal of water facilitates the reaction and produces more of the desired chemical product. By shifting the reaction to right we produce more chemical product with little or no additional capital investment. Many of these reactions can also relate to bioprocesses. Given the large number of water-organic compound separations achievable and the ability of the Compact Membrane Systems, Inc. (CMS) perfluoro membranes to withstand these harsh operating conditions, this is an ideal demonstration system for the water-of-reaction removal using a membrane reactor. Enhanced reaction synthesis is consistent with the DOE objective to lower the energy intensity of U.S. industry 25% by 2017 in accord with the Energy Policy Act of 2005 and to improve the United States manufacturing competitiveness. The objective of this program is to develop the platform technology for enhancing homogeneous catalytic chemical syntheses.

Stuart Nemser, PhD

2010-10-01T23:59:59.000Z

59

CX-004964: Categorical Exclusion Determination  

Energy.gov (U.S. Department of Energy (DOE))

Catalytic Transformation of Waste Carbon Dioxide into Valuable MaterialsCX(s) Applied: A11, B3.6Date: 12/29/2010Location(s): Orangeburg, South CarolinaOffice(s): Fossil Energy, National Energy Technology Laboratory

60

CX-004967: Categorical Exclusion Determination  

Energy.gov (U.S. Department of Energy (DOE))

Catalytic Transformation of Waste Carbon Dioxide into Valuable MaterialsCX(s) Applied: A11, B3.6Date: 12/30/2010Location(s): Rochester, New YorkOffice(s): Fossil Energy, National Energy Technology Laboratory

Note: This page contains sample records for the topic "determination catalytic transformation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Testability Transformation  

E-Print Network (OSTI)

A testability transformation is a source-to-source transformation that aims to improve the ability of a given test generation method to generate test data for the original program. This paper

Mark Harman; Lin Hu; Robert Hierons; Joachim Wegener; Harmen Sthamer; Andre Baresel; Marc Roper

2004-01-01T23:59:59.000Z

62

Market Transformation  

DOE Green Energy (OSTI)

Summarizes the goals and activities of the DOE Solar Energy Technologies Program efforts within its market transformation subprogram.

Not Available

2008-09-01T23:59:59.000Z

63

Catalytic Conversion of Bioethanol to Hydrocarbons  

ORNL 2011-G00219/jcn UT-B ID 201002414 08.2011 Catalytic Conversion of Bioethanol to Hydrocarbons Technology Summary A method for catalytically converting an alcohol ...

64

Catalytic Conversion of Bioethanol to Hydrocarbons  

ORNL 2011-G00219/jcn UT-B ID 201002414 08.2011 Catalytic Conversion of Bioethanol to Hydrocarbons Technology Summary A method for catalytically ...

65

Thermochemical Equilibrium Modeling of Selective Catalytic Reduction (SRC) Catalyst Poisons  

Science Conference Proceedings (OSTI)

A previous EPRI publication (1022073) provided a detailed literature review on the propensity of the alkali and alkaline earth metals sodium (Na), potassium (K), calcium (Ca) and the Group (V) elements phosphorus (P) and arsenic (As) to deactivate selective catalytic reduction (SCR) catalysts in commercial flue gas cleaning systems. It also listed the conditions under which such deactivation has been reported. This report extends this earlier work to predict the transformation of SCR catalyst ...

2012-11-01T23:59:59.000Z

66

CX-000592: Categorical Exclusion Determination | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

92: Categorical Exclusion Determination 92: Categorical Exclusion Determination CX-000592: Categorical Exclusion Determination 25A3400 - Catalytic Biocrude Production in a Novel, Short-contact Time Reactor CX(s) Applied: B3.6 Date: 12/15/2009 Location(s): North Carolina Office(s): Advanced Research Projects Agency - Energy The goal of this early stage research and development project is to develop a novel single-step catalytic biomass pyrolysis process with high carbon conversion efficiency to produce stable bio-crude with low oxygen content (less than 10 percent). Integrating this transformational technology in the existing domestic petroleum refining infrastructure can be an economically attractive option for second generation biofuels production because hydrogen demand for hydroprocessing would be significantly lower. This

67

Market Transformation  

Fuel Cell Technologies Publication and Product Library (EERE)

This Fuel Cell Technologies Program fact sheet outlines current status and challenges in the market transformation of hydrogen and fuel cell technologies.

68

Catalytic reforming optimization  

Science Conference Proceedings (OSTI)

The authors have previously examined correlations between catalytic reforming parameters for an L-35-6 unit at the Gor'knefteorgsintez Industrial Association. Experimental design was used to derive polynomial equations describing the correlations for each reactor. Further research on optimizing the reforming has been based on these results. They adopted the following strategy to define the best working parameters: they define a temperature that would provide the maximum target-product yield while maintaining a given working life. Most of the aromatic hydrocarbons are formed by the naphthene dehydrogenation, which is endothermic, so the greater the temperature drop over the height, the more rapid the process. The temperature difference thus indicates the current catalyst activity. To increase the target-product yield, one must raise the inlet temperature and ensure the largest drop across the catalyst. They examined an algorithm with fixed inlet conditions as regards flow rate and raw material composition. This algorithm provides the basis of software for the automatic control of the L-35-6 reactor unit at the Gor'knefteorgsintez Industrial Association. The system has been checked out and put into experimental operation.

Mazina, S.G.; Rybtsov, V.V.; Priss-Titarenko, T.A.

1988-11-10T23:59:59.000Z

69

Chemical Transformations | U.S. DOE Office of Science (SC)  

Office of Science (SC) Website

Chemical Transformations Chemical Transformations Chemical Sciences, Geosciences, & Biosciences (CSGB) Division CSGB Home About Research Areas Energy Frontier Research Centers (EFRCs) DOE Energy Innovation Hubs Scientific Highlights Reports & Activities Principal Investigators' Meetings BES Home Research Areas Chemical Transformations Print Text Size: A A A RSS Feeds FeedbackShare Page Research themes include the characterization, control, and optimization of chemistry in many forms. Catalysis science underpins the design of new catalytic methods for the clean and efficient production of fuels and chemicals and emphasizes inorganic and organic complexes; interfacial chemistry, nanostructured and supramolecular catalysts, photocatalysis and electrochemistry, and bio-inspired catalytic processes. Heavy element

70

Puerto Rico Refinery Catalytic Reforming Downstream Charge ...  

U.S. Energy Information Administration (EIA)

Puerto Rico Refinery Catalytic Reforming Downstream Charge Capacity as of January 1 (Barrels per Stream Day)

71

Mississippi Refinery Catalytic Reforming Downstream Charge ...  

U.S. Energy Information Administration (EIA)

Mississippi Refinery Catalytic Reforming Downstream Charge Capacity as of January 1 (Barrels per Stream Day)

72

Louisiana Refinery Catalytic Reforming Downstream Charge Capacity ...  

U.S. Energy Information Administration (EIA)

Louisiana Refinery Catalytic Reforming Downstream Charge Capacity as of January 1 (Barrels per Stream Day)

73

A revolution in micropower : the catalytic nanodiode.  

DOE Green Energy (OSTI)

Our ability to field useful, nano-enabled microsystems that capitalize on recent advances in sensor technology is severely limited by the energy density of available power sources. The catalytic nanodiode (reported by Somorjai's group at Berkeley in 2005) was potentially an alternative revolutionary source of micropower. Their first reports claimed that a sizable fraction of the chemical energy may be harvested via hot electrons (a 'chemicurrent') that are created by the catalytic chemical reaction. We fabricated and tested Pt/GaN nanodiodes, which eventually produced currents up to several microamps. Our best reaction yields (electrons/CO{sub 2}) were on the order of 10{sup -3}; well below the 75% values first reported by Somorjai (we note they have also been unable to reproduce their early results). Over the course of this Project we have determined that the whole concept of 'chemicurrent', in fact, may be an illusion. Our results conclusively demonstrate that the current measured from our nanodiodes is derived from a thermoelectric voltage; we have found no credible evidence for true chemicurrent. Unfortunately this means that the catalytic nanodiode has no future as a micropower source.

Cross, Karen Charlene; Heller, Edwin J.; Figiel, Jeffrey James; Coker, Eric Nicholas; Creighton, James Randall; Koleske, Daniel David; Bogart, Katherine Huderle Andersen; Coltrin, Michael Elliott; Pawlowski, Roger Patrick; Baucom, Kevin C.

2010-11-01T23:59:59.000Z

74

Determination of Planetary Boundary Layer Height on Short Spatial and Temporal Scales: A Demonstration of the Covariance Wavelet Transform in Ground-Based Wind Profiler and Lidar Measurements  

Science Conference Proceedings (OSTI)

This article explores the application of the covariance wavelet transform (CWT) to lidar and, for the first time to the authors' knowledge, wind profiler data to examine the possibility of accurate and continuous planetary boundary layer (PBL) ...

Jaime C. Compton; Ruben Delgado; Timothy A. Berkoff; Raymond M. Hoff

2013-07-01T23:59:59.000Z

75

Lightweight transformer  

DOE Green Energy (OSTI)

The technical effort described in this report relates to the program that was performed to design, fabricate, and test a lightweight transformer for Strategic Defense Initiative Organization (SDIO) mission requirements. The objectives of this program were two-fold: (1) design and fabricate a lightweight transformer using liquid hydrogen as the coolant; and (2) test the completed transformer assembly with a low voltage, dc power source. Although the full power testing with liquid helium was not completed, the program demonstrated the viability of the design approach. The lightweight transformer was designed and fabricated, and low and moderate power testing was completed. The transformer is a liquid hydrogen cooled air core transformer that uses thin copper for its primary and secondary windings. The winding mass was approximately 12 kg, or 0.03 kg/kW. Further refinements of the design to a partial air core transformer could potentially reduce the winding mass to as low as 4 or 5 kg, or 0.0125 kg/kW. No attempt was made on this program to reduce the mass of the related structural components or cryogenic container. 8 refs., 39 figs., 2 tabs.

Swallom, D.W.; Enos, G.

1990-05-01T23:59:59.000Z

76

Transport in a Microfluidic Catalytic Reactor  

DOE Green Energy (OSTI)

A study of the heat and mass transfer, flow, and thermodynamics of the reacting flow in a catalytic microreactor is presented. Methanol reforming is utilized in the fuel processing system driving a micro-scale proton exchange membrane fuel cell. Understanding the flow and thermal transport phenomena as well as the reaction mechanisms is essential for improving the efficiency of the reforming process as well as the quality of the processed fuel. Numerical studies have been carried out to characterize the transport in a silicon microfabricated reactor system. On the basis of these results, optimized conditions for fuel processing are determined.

Park, H G; Chung, J; Grigoropoulos, C P; Greif, R; Havstad, M; Morse, J D

2003-04-30T23:59:59.000Z

77

High severity catalytic reforming process  

Science Conference Proceedings (OSTI)

A high-severity catalytic reforming process is described comprising: (a) passing a mixture comprising a catalytic reforming feed stream and a recycle stream into a catalytic reforming reaction zone which is maintained at high-severity reforming conditions; (b) cooling an effluent stream comprising hydrogen and hydrocarbonaceous catalytic reforming reaction products which is withdrawn from the reaction zone; (c) passing the cooled effluent stream into a vapor-liquid separation zone and recovering therefrom a liquid stream comprising hydrocarbons and a hydrogen-rich gas stream; (d) passing the hydrogen-rich gas stream through an adsorption zone wherein the gas is contacted with a treating material which removes polycyclic aromatic compounds from the gas stream, the compounds remaining in the adsorption zone; (e) mixing a portion of the hydrogen-rich gas stream, which is the recycle stream, with the feed stream to form the charge stock mixture and withdrawing the balance of the hydrogen-rich gas stream, which is denoted as net hydrogen, from the catalytic reforming area, all of the hydrogen-rich gas stream being substantially free of polycyclic aromatic compounds; and (f) fractionating the liquid stream and recovering an overhead product comprising light hydrocarbons and a bottoms product comprising reformate.

Bennett, R.W.; Cottrell, P.R.; Gilsdorf, N.L.; Winfield, M.D.

1988-03-22T23:59:59.000Z

78

CX-010296: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

6: Categorical Exclusion Determination CX-010296: Categorical Exclusion Determination Thermal Barrier Coatings for the LTC Engine - Heat Loss, Combustion, Thermal vs. Catalytic...

79

Transformative copy  

E-Print Network (OSTI)

The ability to create an unlimited number of identical copies is a privilege of digital documents. What if that would not be the case, if each copy of a digital file would go along with some sort of transformation? This ...

Offenhuber, Dietmar

2008-01-01T23:59:59.000Z

80

Determining the effect of thermal loading on the remaining useful life of a power transformer from its impedance versus frequency characteristic  

SciTech Connect

It is well known that cellulose materials used to insulate transformer windings gradually degrade during service due to a combination of thermal, mechanical, and electrical stresses. As a result the mechanical characteristics of the paper change during use and may affect the useful life of the transformer. It has generally been assumed that the electrical characteristics remain relatively constant throughout the aging process. If, however, thermal aging changes the electrical characteristics, it may be possible to gauge the thermal age of a transformer by externally monitoring these electrical characteristics over time. In this work, samples of oil impregnated thermally upgraded Kraft insulating paper are subjected to accelerated thermal aging. The relative dielectric constant and loss tangent are investigated by monitoring changes in capacitance and conductance as a function of frequency and thermal aging. This paper presents data showing that the thermal aging process produces changes in the electrical characteristics of the insulating system paper. An example is presented comparing the admittance versus frequency for a model of a 765 kV 500 MVA auto transformer. This demonstrates that the effect of aging can theoretically be observed from the terminals of the transformer.

Batruni, R.; Degeneff, R.C. [Rensselaer Polytechnic Inst., Troy, NY (United States). Electric Power Engineering Dept.; Lebow, M.A. [Consolidated Edison Co., New York, NY (United States)

1996-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "determination catalytic transformation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

High temperature catalytic membrane reactors  

DOE Green Energy (OSTI)

Current state-of-the-art inorganic oxide membranes offer the potential of being modified to yield catalytic properties. The resulting modules may be configured to simultaneously induce catalytic reactions with product concentration and separation in a single processing step. Processes utilizing such catalytically active membrane reactors have the potential for dramatically increasing yield reactions which are currently limited by either thermodynamic equilibria, product inhibition, or kinetic selectivity. Examples of commercial interest include hydrogenation, dehydrogenation, partial and selective oxidation, hydrations, hydrocarbon cracking, olefin metathesis, hydroformylation, and olefin polymerization. A large portion of the most significant reactions fall into the category of high temperature, gas phase chemical and petrochemical processes. Microporous oxide membranes are well suited for these applications. A program is proposed to investigate selected model reactions of commercial interest (i.e. dehydrogenation of ethylbenzene to styrene and dehydrogenation of butane to butadiene) using a high temperature catalytic membrane reactor. Membranes will be developed, reaction dynamics characterized, and production processes developed, culminating in laboratory-scale demonstration of technical and economic feasibility. As a result, the anticipated increased yield per reactor pass economic incentives are envisioned. First, a large decrease in the temperature required to obtain high yield should be possible because of the reduced driving force requirement. Significantly higher conversion per pass implies a reduced recycle ratio, as well as reduced reactor size. Both factors result in reduced capital costs, as well as savings in cost of reactants and energy.

Not Available

1990-03-01T23:59:59.000Z

82

Substantial Transformation  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

4 4 Recovery Act/Buy American Information Related to Substantial Transformation GUIDANCE ON MANUFACTURED GOODS AND SUBSTANTIAL TRANSFORMATION FOR FINANCIAL ASSISTANCE AWARDS Section 1605 of the Recovery Act states, "None of the funds appropriated or otherwise made available by this Act may be used for a project for the construction, alteration, maintenance, or repair of a public building or public work unless all of the iron, steel, and manufactured goods used in the project are produced in the United States." The Office of Management and Budget's (OMB) guidance on implementing this section defines "manufactured good" as a "good brought to the construction site for incorporation into

83

Superconducting Cuprates on Catalytic Substrates - Energy ...  

Electricity Transmission Superconducting Cuprates on Catalytic Substrates Brookhaven National Laboratory. Contact BNL About This Technology Technology Marketing ...

84

Method for measuring recovery of catalytic elements from fuel cells  

Science Conference Proceedings (OSTI)

A method is provided for measuring the concentration of a catalytic clement in a fuel cell powder. The method includes depositing on a porous substrate at least one layer of a powder mixture comprising the fuel cell powder and an internal standard material, ablating a sample of the powder mixture using a laser, and vaporizing the sample using an inductively coupled plasma. A normalized concentration of catalytic element in the sample is determined by quantifying the intensity of a first signal correlated to the amount of catalytic element in the sample, quantifying the intensity of a second signal correlated to the amount of internal standard material in the sample, and using a ratio of the first signal intensity to the second signal intensity to cancel out the effects of sample size.

Shore, Lawrence (Edison, NJ); Matlin, Ramail (Berkeley, NJ)

2011-03-08T23:59:59.000Z

85

INTEGRAL CATALYTIC COMBUSTION/FUEL REFORMING  

E-Print Network (OSTI)

INTEGRAL CATALYTIC COMBUSTION/FUEL REFORMING FOR GAS TURBINE Prepared For: California Energy REPORT (FAR) INTEGRAL CATALYTIC COMBUSTION/FUEL REFORMING FOR GAS TURBINE CYCLES EISG AWARDEE University://www.energy.ca.gov/research/index.html. #12;Page 1 Integral Catalytic Combustion/Fuel Reforming for Gas Turbine Cycles EISG Grant # 99

86

Functional Mellin Transforms  

E-Print Network (OSTI)

Functional integrals are defined in terms of locally compact topological groups and their associated Banach-valued Haar integrals. This approach generalizes the functional integral scheme of Cartier and DeWitt-Morette. The definition allows a construction of functional Mellin transforms. In turn, the functional Mellin transforms can be used to define functional traces, logarithms, and determinants. The associated functional integrals are useful tools for probing function spaces in general and $C^\\ast$-algebras in particular. Several interesting aspects are explored. As an application, we construct a functional Mellin representation of the quantum evolution operator.

J. LaChapelle

2013-08-05T23:59:59.000Z

87

Acidity and catalytic activity of zeolite catalysts bound with silica and alumina  

E-Print Network (OSTI)

Zeolites ZSM-5 (SiO2/Al2O3=30~280) and Y(SiO2/Al2O3=5.2~80) are bound with silica gel (Ludox HS-40 and Ludox AS-40) and alumina (?- Al2O3 and boehmite) by different binding methods, namely, gel-mixing, powder-mixing and powder-wet-mixing methods. The acidities of the bound catalysts and the zeolite powder are determined by NH3-TPD and FTIR. The textures of these catalysts are analyzed on a BET machine with nitrogen as a probe molecule. The micropore surface area and micropore volume are determined by t-plot method. Micropore volume distribution is determined by Horvath-Kawazoe approach with a cylindrical pore model. Mesopore volume distribution is determined by BJH method from the nitrogen desorption isotherm. Silica from the binder may react with extra-framework alumina in zeolites to form a new protonic acid. SiO2-bound catalysts have less strong acidity, Bronsted acidity and Lewis acidity than the zeolite powder. Also, the strength of strong acid sites of the zeolites is reduced when silica is embedded. Micropore surface area and micropore volume are reduced by about 19% and 18%, respectively, indicating some micropores of ZSM-5 are blocked on binding with silica. SiO2-bound ZSM-5 catalysts have less catalytic activity for butane transformation (cracking and disproportionation) and ethylene oligomerization than ZSM-5 powder. When alumina is used as a binder, both the total acid sites and Lewis acid sites are increased. Micropore surface area and micropore volume of ZSM-5 powder are reduced by 26% and 23%, respectively, indicating some micropores of ZSM-5 are blocked by the alumina binder. Alumina-bound catalysts showed a lower activity for butane transformation and ethylene oligomerization than ZSM-5 powder. Alkaline metals content in the binder is a crucial factor that influences the acidity of a bound catalyst. The metal cations neutralize more selectively Bronsted acid sites than Lewis acid sites. Alkaline metal cations in the binder and micropore blockage cause the bound catalysts to have a lower catalytic activity than the zeolite powder.

Wu, Xianchun

2003-12-01T23:59:59.000Z

88

Categorical Exclusion Determinations: Ohio | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

January 27, 2010 January 27, 2010 CX-000646: Categorical Exclusion Determination An Experimental and Theoretical Investigation of Micropitting in Wind Turbine Gears and Bearings CX(s) Applied: B3.6 Date: 01/27/2010 Location(s): Ohio Office(s): Energy Efficiency and Renewable Energy, Golden Field Office January 27, 2010 CX-000745: Categorical Exclusion Determination Beneficial Carbon Dioxide Capture in an Integrated Algal Biorefinery for Renewable Generation and Transportation Fuels CX(s) Applied: A11, B3.6 Date: 01/27/2010 Location(s): Cleveland, Ohio Office(s): Fossil Energy, National Energy Technology Laboratory January 22, 2010 CX-000736: Categorical Exclusion Determination Catalytic Transformation of Waste Carbon Dioxide into Valuable Products CX(s) Applied: A9, B3.6 Date: 01/22/2010

89

Catalytic Device International LLC | Open Energy Information  

Open Energy Info (EERE)

Catalytic Device International LLC Catalytic Device International LLC Jump to: navigation, search Name Catalytic Device International LLC Place Pleasanton, California Product California-based, firm focused on portable, heat-on-demand products. References Catalytic Device International LLC[1] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. Catalytic Device International LLC is a company located in Pleasanton, California . References ↑ "Catalytic Device International LLC" Retrieved from "http://en.openei.org/w/index.php?title=Catalytic_Device_International_LLC&oldid=343285" Categories: Clean Energy Organizations Companies Organizations Stubs What links here Related changes Special pages

90

Endothermic photo-catalytic reactions  

Science Conference Proceedings (OSTI)

The overall objective of this report is to present the results of an investigation to provide guidelines for future experimental work, on solar energy driven endothermic photo-catalytic reactions, and primarily to select candidate synthesis reactions which lead to high $-value products. An intensive literature search was conducted to find properties, market demand, and prices of pertinent chemicals; meeting four criteria: (1) the reaction must be endothermic and favorable; (2) the reaction must be catalytic; (3) the product must be produced from low cost feedstocks; and (4) the product must have a sales price >$1.00/lb. Initial examination of low cost feedstocks to high value products lead to consideration of n-paraffins to aromatics and substituted aromatics. Fifteen candidate endothermic synthesis reactions, meeting the above criteria, are suggested. The ratio of product price by reactant cost indicates {approximately}5--8 for the best possibilities; all can be visualized as starting with low cost paraffin and methanol feedstocks.

Prengle, H.W. Jr.; Wentworth, W.E.; Polonczyk, K.C.; Saghafi, M.; Wilking, J.A.; Kramer, K.S. (Houston Univ., TX (United States))

1992-04-01T23:59:59.000Z

91

RF transformer  

DOE Patents (OSTI)

There is provided an improved RF transformer having a single-turn secondary of cylindrical shape and a coiled encapsulated primary contained within the secondary. The coil is tapered so that the narrowest separation between the primary and the secondary is at one end of the coil. The encapsulated primary is removable from the secondary so that a variety of different capacity primaries can be utilized with one secondary.

Smith, James L. (Naperville, IL); Helenberg, Harold W. (Calumet City, IL); Kilsdonk, Dennis J. (Joliet, IL)

1979-01-01T23:59:59.000Z

92

Method of improving catalytic activity and catalytics produced thereby  

DOE Patents (OSTI)

A process for dissociating H{sub 2}S in a gaseous feed using an improved catalytic material is disclosed in which the feed is contacted at a temperature of at least about 275C with a catalyst of rutile nanocrystalline titania having grain sizes in the range of from about 1 to about 100 manometers. Other transition metal catalysts are disclosed, each of nanocrystalline material with grain sizes in the 1--100 nm range. This invention may have application to vehicle emissions control (three-way catalysts).

Beck, D.D.; Siegel, R.W.

1993-09-23T23:59:59.000Z

93

TRANSFORMER APPARATUS  

DOE Patents (OSTI)

Transformer apparatus is designed for measuring the amount of a paramagnetic substance dissolved or suspended in a diamagnetic liquid. The apparatus consists of a cluster of tubes, some of which are closed and have sealed within the diamagnetic substance without any of the paramagnetic material. The remaining tubes are open to flow of the mix- ture. Primary and secondary conductors are wrapped around the tubes in such a way as to cancel noise components and also to produce a differential signal on the secondaries based upon variations of the content of the paramagnetic material. (AEC)

Wolfgang, F.; Nicol, J.

1962-11-01T23:59:59.000Z

94

Categorical Exclusion Determinations: National Energy Technology...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Office(s): Energy Efficiency and Renewable Energy, National Energy Technology Laboratory December 30, 2010 CX-004967: Categorical Exclusion Determination Catalytic...

95

Catalytic steam gasification of carbon  

DOE Green Energy (OSTI)

Unsupported carbide powders with high specific surface area, namely {alpha}-WC (35 m{sup 2}/g, hexagonal), {beta}-WC{sub 0.61} (100 m{sup 2}/g, cubic face centered) and {beta}-WC{sub 0.5} (15 m{sup 2}/g, hexagonal) have been prepared. The key element in this preparation is the successful removal of surface polymeric carbon by careful gasification to methane by means of dihydrogen. These tungsten carbide powders have been used in catalytic reactions of oxidation of H{sub 2} and hydrogenolysis of alkanes, such as butane, hexane, and neopentane.

Boudart, M.

1990-12-31T23:59:59.000Z

96

Catalytic membranes for fuel cells  

DOE Patents (OSTI)

A fuel cell of the present invention comprises a cathode and an anode, one or both of the anode and the cathode including a catalyst comprising a bundle of longitudinally aligned graphitic carbon nanotubes including a catalytically active transition metal incorporated longitudinally and atomically distributed throughout the graphitic carbon walls of said nanotubes. The nanotubes also include nitrogen atoms and/or ions chemically bonded to the graphitic carbon and to the transition metal. Preferably, the transition metal comprises at least one metal selected from the group consisting of Fe, Co, Ni, Mn, and Cr.

Liu, Di-Jia (Naperville, IL); Yang, Junbing (Bolingbrook, IL); Wang, Xiaoping (Naperville, IL)

2011-04-19T23:59:59.000Z

97

An update on catalytic reforming  

Science Conference Proceedings (OSTI)

The UOP Platforming process is a catalytic reforming process in widespread use throughout the petroleum and petrochemical industries. Since the first unit went onstream in 1949, the process has become a standard feature in refineries worldwide. Over the years, significant improvements have been made in process catalysts and process design. The most recent improvement is the combination of a catalyst called R-72 with a new patented flow scheme, R-72 staged loading, which gives significantly higher yields and provides increased catalyst stability. In this article, the authors describe two types of Platforming processes and the new R-72 staged loading scheme.

Wei, D.H.; Moser, M.D.; Haizmann, R.S.

1996-10-01T23:59:59.000Z

98

Gold-Copper Nanoparticles: Nanostructural Evolution and Bifunctional Catalytic Sites  

Science Conference Proceedings (OSTI)

Understanding of the atomic-scale structure is essential for exploiting the unique catalytic properties of any nanoalloy catalyst. This report describes novel findings of an investigation of the nanoscale alloying of gold-copper (AuCu) nanoparticles and its impact on the surface catalytic functions. Two pathways have been explored for the formation of AuCu nanoparticles of different compositons, including wet chemical synthesis from mixed Au- and Cu-precursor molecules, and nanoscale alloying via an evolution of mixed Au- and Cu-precursor nanoparticles near the nanoscale melting temperatures. For the evolution of mixed precursor nanoparticles, synchrotron x-ray based in-situ real time XRD was used to monitor the structural changes, revealing nanoscale alloying and reshaping towards an fcc-type nanoalloy (particle or cube) via a partial melting–resolidification mechanism. The nanoalloys supported on carbon or silica were characterized by in-situ high-energy XRD/PDFs, revealing an intriguing lattice "expanding-shrinking" phenomenon depending on whether the catalyst is thermochemically processed under oxidative or reductive atmosphere. This type of controllable structural changes is found to play an important role in determining the catalytic activity of the catalysts for carbon monoxide oxidation reaction. The tunable catalytic activities of the nanoalloys under thermochemically oxidative and reductive atmospheres are also discussed in terms of the bifunctional sites and the surface oxygenated metal species for carbon monoxide and oxygen activation.

Yin, Jun; Shan, Shiyao; Yang, Lefu; Mott, Derrick; Malis, Oana; Petkov, Valeri; Cai, Fan; Ng, Mei; Luo, Jin; Chen, Bing H.; Engelhard, Mark H.; Zhong, Chuan-Jian

2012-12-12T23:59:59.000Z

99

Catalytic Combustor for Fuel-Flexible Turbine  

NLE Websites -- All DOE Office Websites (Extended Search)

Catalytic Lean (RCL TM ) technology, Figure 1, is being developed as an ultra low NOx gas turbine combustor for Integrated Gasification Combined Cycle (IGCC). In this concept,...

100

Gauge transformations in lattice chiral theories  

E-Print Network (OSTI)

We show that gauge-transformation properties of correlation functions in chiral gauge theories on the finite lattice are determined in a general way.

Werner Kerler

2004-12-21T23:59:59.000Z

Note: This page contains sample records for the topic "determination catalytic transformation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Catalytic conversion of light alkanes  

DOE Green Energy (OSTI)

The second Quarterly Report of 1992 on the Catalytic Conversion of Light Alkanes reviews the work done between April 1, 1992 and June 31, 1992 on the Cooperative Agreement. The mission of this work is to devise a new catalyst which can be used in a simple economic process to convert the light alkanes in natural gas to oxygenate products that can either be used as clean-burning, high octane liquid fuels, as fuel components or as precursors to liquid hydrocarbon uwspomdon fuel. During the past quarter we have continued to design, prepare, characterize and test novel catalysts for the mild selective reaction of light hydrocarbons with air or oxygen to produce alcohols directly. These catalysts are designed to form active metal oxo (MO) species and to be uniquely active for the homolytic cleavage of the carbon-hydrogen bonds in light alkanes producing intermediates which can form alcohols. We continue to investigate three molecular environments for the active catalytic species that we are trying to generate: electron-deficient macrocycles (PHASE I), polyoxometallates (PHASE II), and regular oxidic lattices including zeolites and related structures as well as other molecular surface structures having metal oxo groups (PHASE I).

Lyons, J.E.

1992-06-30T23:59:59.000Z

102

Pemex opts for catalytic dehydrogenation  

SciTech Connect

In the gas-rich areas such as the Middle East, Southeast Asia, Canada, and Mexico, low-cost ethane is the feed of choice for ethylene production. Coproduct production is minimal. Continued growth in demand for propylene, isobutylene, normal butone-1, and butadiene requires that alternate sources of these normally coproduct olefins be developed. Catalytic dehydrogenation, with its high selectivity to the desired olefin, is the logical and economic choice. Mexico is a case in point. It's ethylene production is based on ethane. Demand is rising for propylene and butadiene derivatives, and a potential demand exists for isobutylene to produce octane enhancers to implement an announced lead phase down. Only modest amounts of by-product monoolefin will be available from refining operations. Pemex, the Mexican refining and petrochemical giant, recognized this and started up its first Houdry Catadene /SUP TM/ plant in 1975 at Ciudad Madero to produce 55,000 metric ton/year of butadiene from normal butane. Pemex recently committed to a large (350,000 metric ton/year) propylene-from-propane plant at Morelos based on the Houdry Catofin /SUP TM/ catalytic dehydrogenation process. The plant will supply propylene to a long list of derivative plants (Table 1).

Craig, R.G.; Penny, S.J.; Schwartz, W.A.

1983-07-01T23:59:59.000Z

103

Incineration, Waste-to-energy and Catalytic Gasification: the Past, Present and Future of Medical Waste Management  

E-Print Network (OSTI)

- 1 - Incineration, Waste-to-energy and Catalytic Gasification: the Past, Present and Future Determination 19 Discussion of M.W. Disposal/Use Options Incineration 25 Waste-to-Energy 28 Gasification 29 Waste-to-Energy Ash Research 31 Dioxins 35 Discussion of Gasification/Catalytic Alternative 36 GCMS

Columbia University

104

Categorical Exclusion Determinations: A9 | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

4, 2011 4, 2011 CX-004857: Categorical Exclusion Determination Building Operations Certification License CX(s) Applied: A9, A11, B5.1 Date: 01/04/2011 Location(s): Kansas Office(s): Energy Efficiency and Renewable Energy, Golden Field Office January 4, 2011 CX-004854: Categorical Exclusion Determination Missouri-City-St. Peters CX(s) Applied: A1, A9, B2.5, B5.1 Date: 01/04/2011 Location(s): St. Peters, Missouri Office(s): Energy Efficiency and Renewable Energy January 3, 2011 CX-004853: Categorical Exclusion Determination Louisiana-County-St. Landry CX(s) Applied: A9, A11, B2.5, B5.1 Date: 01/03/2011 Location(s): St. Landry Parish, Louisiana Office(s): Energy Efficiency and Renewable Energy December 30, 2010 CX-004966: Categorical Exclusion Determination Catalytic Transformation of Waste Carbon Dioxide into Valuable Materials

105

Method of fabricating a catalytic structure  

SciTech Connect

A precursor to a catalytic structure comprising zinc oxide and copper oxide. The zinc oxide has a sheet-like morphology or a spherical morphology and the copper oxide comprises particles of copper oxide. The copper oxide is reduced to copper, producing the catalytic structure. The catalytic structure is fabricated by a hydrothermal process. A reaction mixture comprising a zinc salt, a copper salt, a hydroxyl ion source, and a structure-directing agent is formed. The reaction mixture is heated under confined volume conditions to produce the precursor. The copper oxide in the precursor is reduced to copper. A method of hydrogenating a carbon oxide using the catalytic structure is also disclosed, as is a system that includes the catalytic structure.

Rollins, Harry W. (Idaho Falls, ID); Petkovic, Lucia M. (Idaho Falls, ID); Ginosar, Daniel M. (Idaho Falls, ID)

2009-09-22T23:59:59.000Z

106

CX-004966: Categorical Exclusion Determination  

Energy.gov (U.S. Department of Energy (DOE))

Catalytic Transformation of Waste Carbon Dioxide into Valuable MaterialsCX(s) Applied: A9, A11, B3.6Date: 12/30/2010Location(s): Ithaca, New YorkOffice(s): Fossil Energy, National Energy Technology Laboratory

107

CX-004968: Categorical Exclusion Determination  

Energy.gov (U.S. Department of Energy (DOE))

Catalytic Transformation of Waste Carbon Dioxide into Valuable MaterialsCX(s) Applied: A9, A11, B3.6Date: 12/29/2010Location(s): Baton Rogue, LouisianaOffice(s): Fossil Energy, National Energy Technology Laboratory

108

Catalytic Hydrothermal Gasification of Biomass  

Science Conference Proceedings (OSTI)

A recent development in biomass gasification is the use of a pressurized water processing environment in order that drying of the biomass can be avoided. This paper reviews the research undertaken developing this new option for biomass gasification. This review does not cover wet oxidation or near-atmospheric-pressure steam-gasification of biomass. Laboratory research on hydrothermal gasification of biomass focusing on the use of catalysts is reviewed here, and a companion review focuses on non-catalytic processing. Research includes liquid-phase, sub-critical processing as well as super-critical water processing. The use of heterogeneous catalysts in such a system allows effective operation at lower temperatures, and the issues around the use of catalysts are presented. This review attempts to show the potential of this new processing concept by comparing the various options under development and the results of the research.

Elliott, Douglas C.

2008-05-06T23:59:59.000Z

109

APPARATUS FOR CATALYTICALLY COMBINING GASES  

DOE Patents (OSTI)

A convection type recombiner is described for catalytically recombining hydrogen and oxygen which have been radiolytically decomposed in an aqueous homogeneous nuclear reactor. The device is so designed that the energy of recombination is used to circulate the gas mixture over the catalyst. The device consists of a vertical cylinder having baffles at its lower enda above these coarse screens having platinum and alumina pellets cemented thereon, and an annular passage for the return of recombined, condensed water to the reactor moderator system. This devicea having no moving parts, provides a simple and efficient means of removing the danger of accumulated hot radioactive, explosive gases, and restoring them to the moderator system for reuse.

Busey, H.M.

1958-08-12T23:59:59.000Z

110

Catalytic reactor with improved burner  

DOE Patents (OSTI)

To more uniformly distribute heat to the plurality of catalyst tubes in a catalytic reaction furnace, the burner disposed in the furnace above the tops of the tubes includes concentric primary and secondary annular fuel and air outlets. The fuel-air mixture from the primary outlet is directed towards the tubes adjacent the furnace wall, and the burning secondary fuel-air mixture is directed horizontally from the secondary outlet and a portion thereof is deflected downwardly by a slotted baffle toward the tubes in the center of the furnace while the remaining portion passes through the slotted baffle to another baffle disposed radially outwardly therefrom which deflects it downwardly in the vicinity of the tubes between those in the center and those near the wall of the furnace.

Faitani, Joseph J. (Hartford, CT); Austin, George W. (Glastonbury, CT); Chase, Terry J. (Somers, CT); Suljak, George T. (Vernon, CT); Misage, Robert J. (Manchester,all of, CT)

1981-01-01T23:59:59.000Z

111

Coal conversion wastewater treatment by catalytic oxidation in supercritical water  

SciTech Connect

Wastewaters from coal-conversion processes contain phenolic compounds in appreciable concentrations. These compounds need to be removed so that the water can be discharged or re-used. Catalytic oxidation in supercritical water is one potential means of treating coal-conversion wastewaters, and this project examined the reactions of phenol over different heterogeneous oxidation catalysts in supercritical water. More specifically, the authors examined the oxidation of phenol over a commercial catalyst and over bulk MnO{sub 2}, bulk TiO{sub 2}, and CuO supported on Al{sub 2}O{sub 3}. They used phenol as the model pollutant because it is ubiquitous in coal-conversion wastewaters and there is a large database for non-catalytic supercritical water oxidation (SCWO) with which they can contrast results from catalytic SCWO. The overall objective of this research project is to obtain the reaction engineering information required to evaluate the utility of catalytic supercritical water oxidation for treating wastes arising from coal conversion processes. All four materials were active for catalytic supercritical water oxidation. Indeed, all four materials produced phenol conversions and CO{sub 2} yields in excess of those obtained from purely homogeneous, uncatalyzed oxidation reactions. The commercial catalyst was so active that the authors could not reliably measure reaction rates that were not limited by pore diffusion. Therefore, they performed experiments with bulk transition metal oxides. The bulk MnO{sub 2} and TiO{sub 2} catalysts enhance both the phenol disappearance and CO{sub 2} formation rates during SCWO. MnO{sub 2} does not affect the selectivity to CO{sub 2}, or to the phenol dimers at a given phenol conversion. However, the selectivities to CO{sub 2} are increased and the selectivities to phenol dimers are decreased in the presence of TiO{sub 2}, which are desirable trends for a catalytic SCWO process. The role of the catalyst appears to be accelerating the rate of formation of phenoxy radicals, which then react in the fluid phase by the same mechanism operative for non-catalytic SCWO of phenol. The rates of phenol disappearance and CO{sub 2} formation are sensitive to the phenol and O{sub 2} concentrations, but independent of the water density. Power-law rate expressions were developed to correlate the catalytic kinetics. The catalytic kinetics were also consistent with a Langmuir-Hinshelwood rate law derived from a dual-site mechanism comprising the following steps: reversible adsorption of phenol on one type of catalytic site, reversible dissociative adsorption of oxygen on a different type of site, and irreversible, rate-determining surface reaction between adsorbed phenol and adsorbed oxygen.

Phillip E. Savage

1999-10-20T23:59:59.000Z

112

COAL CONVERSION WASTEWATER TREATMENT BY CATALYTIC OXIDATION IN SUPERCRITICAL WATER  

SciTech Connect

Wastewaters from coal-conversion processes contain phenolic compounds in appreciable concentrations. These compounds need to be removed so that the water can be discharged or re-used. Catalytic oxidation in supercritical water is one potential means of treating coal-conversion wastewaters, and this project examined the reactions of phenol over different heterogeneous oxidation catalysts in supercritical water. More specifically, we examined the oxidation of phenol over a commercial catalyst and over bulk MnO{sub 2}, bulk TiO{sub 2}, and CuO supported on Al{sub 2} O{sub 3}. We used phenol as the model pollutant because it is ubiquitous in coal-conversion wastewaters and there is a large database for non-catalytic supercritical water oxidation (SCWO) with which we can contrast results from catalytic SCWO. The overall objective of this research project is to obtain the reaction engineering information required to evaluate the utility of catalytic supercritical water oxidation for treating wastes arising from coal conversion processes. All four materials were active for catalytic supercritical water oxidation. Indeed, all four materials produced phenol conversions and CO{sub 2} yields in excess of those obtained from purely homogeneous, uncatalyzed oxidation reactions. The commercial catalyst was so active that we could not reliably measure reaction rates that were not limited by pore diffusion. Therefore, we performed experiments with bulk transition metal oxides. The bulk MnO{sub 2} and TiO{sub 2} catalysts enhance both the phenol disappearance and CO{sub 2} formation rates during SCWO. MnO{sub 2} does not affect the selectivity to CO{sub 2}, or to the phenol dimers at a given phenol conversion. However, the selectivities to CO{sub 2} are increased and the selectivities to phenol dimers are decreased in the presence of TiO{sub 2} , which are desirable trends for a catalytic SCWO process. The role of the catalyst appears to be accelerating the rate of formation of phenoxy radicals, which then react in the fluid phase by the same mechanism operative for non-catalytic SCWO of phenol. The rates of phenol disappearance and CO{sub 2} formation are sensitive to the phenol and O{sub 2} concentrations, but independent of the water density. Power-law rate expressions were developed to correlate the catalytic kinetics. The catalytic kinetics were also consistent with a Langmuir-Hinshelwood rate law derived from a dual-site mechanism comprising the following steps: reversible adsorption of phenol on one type of catalytic site, reversible dissociative adsorption of oxygen on a different type of site, and irreversible, rate-determining surface reaction between adsorbed phenol and adsorbed oxygen.

Phillip E. Savage

1999-10-18T23:59:59.000Z

113

Adsorbate structures and catalytic reactions studied in the torrpressure range by scanning tunneling microscopy  

DOE Green Energy (OSTI)

High-pressure, high-temperature scanning tunneling microscopy (HPHTSTM) was used to study adsorbate structures and reactions on single crystal model catalytic systems. Studies of the automobile catalytic converter reaction [CO + NO {yields} 1/2 N{sub 2} + CO{sub 2}] on Rh(111) and ethylene hydrogenation [C{sub 2}H{sub 4} + H{sub 2} {yields} C{sub 2}H{sub 6}] on Rh(111) and Pt(111) elucidated information on adsorbate structures in equilibrium with high-pressure gas and the relationship of atomic and molecular mobility to chemistry. STM studies of NO on Rh(111) showed that adsorbed NO forms two high-pressure structures, with the phase transformation from the (2 x 2) structure to the (3 x 3) structure occurring at 0.03 Torr. The (3 x 3) structure only exists when the surface is in equilibrium with the gas phase. The heat of adsorption of this new structure was determined by measuring the pressures and temperatures at which both (2 x 2) and (3 x 3) structures coexisted. The energy barrier between the two structures was calculated by observing the time necessary for the phase transformation to take place. High-pressure STM studies of the coadsorption of CO and NO on Rh(111) showed that CO and NO form a mixed (2 x 2) structure at low NO partial pressures. By comparing surface and gas compositions, the adsorption energy difference between topsite CO and NO was calculated. Occasionally there is exchange between top-site CO and NO, for which we have described a mechanism for. At high NO partial pressures, NO segregates into islands, where the phase transformation to the (3 x 3) structure occurs. The reaction of CO and NO on Rh(111) was monitored by mass spectrometry (MS) and HPHTSTM. From MS studies the apparent activation energy of the catalytic converter reaction was calculated and compared to theory. STM showed that under high-temperature reaction conditions, surface metal atoms become mobile. Ethylene hydrogenation and its poisoning by CO was also studied by STM on Rh(111) and Pt(111). Poisoning was found to coincide with decreased adsorbate mobility. Under ethylene hydrogenation conditions, no order is detected by STM at 300 K, as hydrogen and ethylidyne, the surface species formed by gas-phase ethylene, are too mobile. When CO is introduced, the reaction stops, and ordered structures appear on the surface. For Rh(111), the structure is predominantly a mixed c(4 x 2), though there are some areas of (2 x 2). For Pt(111), the structure is hexagonal and resembles the Moire pattern seen when Pt(111) is exposed to pure CO. From these studies it is concluded that CO poisons by stopping adsorbate mobility. This lack of adsorbate mobility prevents the adsorption of ethylene from the gas phase by hindering the creation of adsorption sites.

Hwang, Kevin Shao-Lin

2003-05-23T23:59:59.000Z

114

TCS 2014 Symposium on Thermal and Catalytic Sciences for Biofuels...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

TCS 2014 Symposium on Thermal and Catalytic Sciences for Biofuels and Biobased Products TCS 2014 Symposium on Thermal and Catalytic Sciences for Biofuels and Biobased Products...

115

Catalytic Properties of Ni-Al Intermetallic Nanoparticle Catalysts for ...  

Science Conference Proceedings (OSTI)

In order to pursue high catalytic performance of Ni-Al intermetallic ... very high catalytic activity for methanol decomposition and methane steam reforming.

116

Revolutionary systems for catalytic combustion and diesel catalytic particulate traps.  

DOE Green Energy (OSTI)

This report is a summary of an LDRD project completed for the development of materials and structures conducive to advancing the state of the art for catalyst supports and diesel particulate traps. An ancillary development for bio-medical bone scaffolding was also realized. Traditionally, a low-pressure drop catalyst support, such as a ceramic honeycomb monolith, is used for catalytic reactions that require high flow rates of gases at high-temperatures. A drawback to the traditional honeycomb monoliths under these operating conditions is poor mass transfer to the catalyst surface in the straight-through channels. ''Robocasting'' is a unique process developed at Sandia National Laboratories that can be used to manufacture ceramic monoliths with alternative 3-dimensional geometries, providing tortuous pathways to increase mass transfer while maintaining low-pressure drops. These alternative 3-dimensional geometries may also provide a foundation for the development of self-regenerating supports capable of trapping and combusting soot particles from a diesel engine exhaust stream. This report describes the structures developed and characterizes the improved catalytic performance that can result. The results show that, relative to honeycomb monolith supports, considerable improvement in mass transfer efficiency is observed for robocast samples synthesized using an FCC-like geometry of alternating rods. Also, there is clearly a trade-off between enhanced mass transfer and increased pressure drop, which can be optimized depending on the particular demands of a given application. Practical applications include the combustion of natural gas for power generation, production of syngas, and hydrogen reforming reactions. The robocast lattice structures also show practicality for diesel particulate trapping. Preliminary results for trapping efficiency are reported as well as the development of electrically resistive lattices that can regenerate the structure by combusting the trapped soot. During this project an ancillary bio-medical application was discovered for lattices of hydroxyapatite. These structures show promise as bone scaffolds for the reparation of damaged bone. A case study depicting the manufacture of a customized device that fits into a damaged mandible is described.

Stuecker, John Nicholas; Witze, Peter O.; Ferrizz, Robert Matthew; Cesarano, Joseph, III; Miller, James Edward

2004-12-01T23:59:59.000Z

117

Perfect NOT transformation and conjugate transformation  

E-Print Network (OSTI)

The perfect NOT transformation, probabilistic perfect NOT transformation and conjugate transformation are studied. Perfect NOT transformation criteria on a quantum state set $S$ of a qubit are obtained. Two necessary and sufficient conditions for realizing a perfect NOT transformation on $S$ are derived. When these conditions are not satisfied we discuss a probabilistic perfect NOT transformation (gate). We construct a probabilistic perfect NOT machine (gate) by a general unitary-reduction operation. With a postselection of the measurement outcomes, the probabilistic NOT gate yields perfectly complements of the input states. We prove that one can realize probabilistically the NOT gate of the input states secretly chosen from a certain set $S=\\{|\\Psi_1>, |\\Psi_2>,..., |\\Psi_n>\\}$ if and only if $|\\Psi_1>, |\\Psi_2>,...,$ and $|\\Psi_n>$ are linearly independent. We also generalize the probabilistic NOT transformation to the conjugate transformation in the multi-level quantum system. The lower bound of the best p...

Yan, Fengli; Yan, Zhichao

2012-01-01T23:59:59.000Z

118

Condition Monitoring and Diagnostics of Bushings, Current Transformers, and Voltage Transformers by Oil Analysis  

Science Conference Proceedings (OSTI)

This study was undertaken to determine the merits of oil analysis for condition monitoring and diagnostics of bushings, current, potential and voltage transformers. Oil test results and equipment information from 193 bushings, 830 current transformers, 194 potential transformers and 268 voltage transformers were analyzed. Statistical analyses was used to assigns equipment condition codes from 1 (Normal Operation) to 4 (Extreme) based on threshold limits for dissolved gas in oil results. A more recent set...

2006-12-12T23:59:59.000Z

119

Transformations | Open Energy Information  

Open Energy Info (EERE)

Transformations Transformations Jump to: navigation, search Name Transformations Place Townsend, MA Website http://transformations-inc.com References Transformations[1] Information About Partnership with NREL Partnership with NREL Yes Partnership Type Test & Evaluation Partner Partnering Center within NREL Electricity Resources & Building Systems Integration LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! Transformations is a company located in Townsend, MA. References ↑ "Transformations" Retrieved from "http://en.openei.org/w/index.php?title=Transformations&oldid=381743" Categories: Clean Energy Organizations Companies Organizations What links here Related changes Special pages Printable version Permanent link Browse properties

120

Categorical Exclusion Determinations: B3.6 | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

3, 2011 3, 2011 CX-005094: Categorical Exclusion Determination Dissolution, Valence Adjustment, and Precipitation of Actinides CX(s) Applied: B3.6 Date: 01/03/2011 Location(s): Aiken, South Carolina Office(s): Savannah River Operations Office January 3, 2011 CX-005093: Categorical Exclusion Determination Development of Cooling Towers as Non-Traditional Collectors of Particles, Biological Agents: Concentration, and Detection CX(s) Applied: B3.6 Date: 01/03/2011 Location(s): Aiken, South Carolina Office(s): Savannah River Operations Office December 30, 2010 CX-004967: Categorical Exclusion Determination Catalytic Transformation of Waste Carbon Dioxide into Valuable Materials CX(s) Applied: A11, B3.6 Date: 12/30/2010 Location(s): Rochester, New York Office(s): Fossil Energy, National Energy Technology Laboratory

Note: This page contains sample records for the topic "determination catalytic transformation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Categorical Exclusion Determinations: A9 | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

2, 2010 2, 2010 CX-000737: Categorical Exclusion Determination Catalytic Transformation of Waste Carbon Dioxide into Valuable Products CX(s) Applied: A9, B3.6 Date: 01/22/2010 Location(s): Ithaca, New York Office(s): Fossil Energy, National Energy Technology Laboratory January 22, 2010 CX-000739: Categorical Exclusion Determination Site Characterization of the Highest-Priority Geologic Formations for Carbon Dioxide storage in Wyoming CX(s) Applied: A1, A9, B3.6 Date: 01/22/2010 Location(s): Laramie, Wyoming Office(s): Fossil Energy, National Energy Technology Laboratory January 22, 2010 CX-000740: Categorical Exclusion Determination Site Characterization for Carbon Dioxide Storage from Coal-fired Power Facilities in the Black Warrior Basin of Alabama CX(s) Applied: A9, B3.1

122

Categorical Exclusion (CX) Determinations By Date | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

2, 2010 2, 2010 CX-000737: Categorical Exclusion Determination Catalytic Transformation of Waste Carbon Dioxide into Valuable Products CX(s) Applied: A9, B3.6 Date: 01/22/2010 Location(s): Ithaca, New York Office(s): Fossil Energy, National Energy Technology Laboratory January 22, 2010 CX-000738: Categorical Exclusion Determination Site Characterization of the Highest-Priority Geologic Formations for Carbon Dioxide storage in Wyoming CX(s) Applied: B3.1, B3.7, B3.8 Date: 01/22/2010 Location(s): Sweetwater County, Wyoming Office(s): Fossil Energy, National Energy Technology Laboratory January 22, 2010 CX-000739: Categorical Exclusion Determination Site Characterization of the Highest-Priority Geologic Formations for Carbon Dioxide storage in Wyoming CX(s) Applied: A1, A9, B3.6

123

Categorical Exclusion Determinations: B3.6 | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

22, 2010 22, 2010 CX-000737: Categorical Exclusion Determination Catalytic Transformation of Waste Carbon Dioxide into Valuable Products CX(s) Applied: A9, B3.6 Date: 01/22/2010 Location(s): Ithaca, New York Office(s): Fossil Energy, National Energy Technology Laboratory January 22, 2010 CX-000739: Categorical Exclusion Determination Site Characterization of the Highest-Priority Geologic Formations for Carbon Dioxide storage in Wyoming CX(s) Applied: A1, A9, B3.6 Date: 01/22/2010 Location(s): Laramie, Wyoming Office(s): Fossil Energy, National Energy Technology Laboratory January 21, 2010 CX-002154: Categorical Exclusion Determination Recovery Act: DeepCwind Consortium National Research Program: Validation of Coupled Models and Optimization of Materials for Offshore Wind Structures

124

Vacuum-insulated catalytic converter  

DOE Patents (OSTI)

A catalytic converter has an inner canister that contains catalyst-coated substrates and an outer canister that encloses an annular, variable vacuum insulation chamber surrounding the inner canister. An annular tank containing phase-change material for heat storage and release is positioned in the variable vacuum insulation chamber a distance spaced part from the inner canister. A reversible hydrogen getter in the variable vacuum insulation chamber, preferably on a surface of the heat storage tank, releases hydrogen into the variable vacuum insulation chamber to conduct heat when the phase-change material is hot and absorbs the hydrogen to limit heat transfer to radiation when the phase-change material is cool. A porous zeolite trap in the inner canister absorbs and retains hydrocarbons from the exhaust gases when the catalyst-coated substrates and zeolite trap are cold and releases the hydrocarbons for reaction on the catalyst-coated substrate when the zeolite trap and catalyst-coated substrate get hot.

Benson, David K. (Golden, CO)

2001-01-01T23:59:59.000Z

125

Institute for Atom-Efficient Chemical Transformations Energy Frontier  

NLE Websites -- All DOE Office Websites (Extended Search)

Institute for Atom-Efficient Chemical Transformations DOE Logo Institute for Atom-Efficient Chemical Transformations DOE Logo Focus Areas Reaction Mechanisms Controlled Active Metals Materials Synthesis Search Argonne ... Search Argonne Home > Institute for Atom-Efficient Chemical Transformations > IACT Home IACT News IACT Partners IACT Staff IACT Awards Publications & Presentations Jobs at IACT Energy Frontier Research Centers at Argonne Strategic Alliances Research Facilities & Tools Institute for Atom-Efficient Chemical Transformations - an Energy Frontier Research Center The Institute for Atom-Efficient Chemical Transformations (IACT) employs a multidisciplinary approach to address key catalytic conversions that could improve the efficiency of producing fuels from biomass. IACT focuses on advancing the science of catalysis for the efficient conversion of energy resources into usable forms. IACT's goal is to find ways to achieve control and efficiency of chemical conversions comparable to those in nature.

126

Spacetime transformation acoustics  

E-Print Network (OSTI)

A recently proposed analogue transformation method has allowed the extension of transformation acoustics to general spacetime transformations. We analyze here in detail the differences between this new analogue transformation acoustics (ATA) method and the standard one (STA). We show explicitly that STA is not suitable for transformations that mix space and time. ATA takes as starting point the acoustic equation for the velocity potential, instead of that for the pressure as in STA. This velocity-potential equation by itself already allows for some transformations mixing space and time, but not all of them. We explicitly obtain the entire set of transformations that do not leave its form invariant. It is in these cases that ATA shows its true potential, allowing for building a transformation acoustics method that enables the full range of spacetime transformations. We provide an example of an important transformation which cannot be achieved with STA. Using this transformation, we design and simulate an acous...

García-Meca, C; Barceló, C; Jannes, G; Sánchez-Dehesa, J; Martínez, A

2013-01-01T23:59:59.000Z

127

CX-008794: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Categorical Exclusion Determination CX-008794: Categorical Exclusion Determination Transformer Replacement and Foundation Work at Flaming Gorge Substation Daggett County, Utah...

128

Glycoside hydrolases: Catalytic base/nucleophile diversity  

NLE Websites -- All DOE Office Websites (Extended Search)

Glycoside Glycoside Hydrolases: Catalytic Base/Nucleophile Diversity Thu V. Vuong, David B. Wilson Department of Molecular Biology and Genetics, Cornell University, 458 Biotechnology Building, Ithaca, New York 14850; telephone: 607-255-5706; fax: 607-255-2428; e-mail: dbw3@cornell.edu Received 1 April 2010; revision received 27 May 2010; accepted 2 June 2010 Published online 15 June 2010 in Wiley Online Library (wileyonlinelibrary.com). DOI 10.1002/bit.22838 ABSTRACT: Recent studies have shown that a number of glycoside hydrolase families do not follow the classical catalytic mechanisms, as they lack a typical catalytic base/ nucleophile. A variety of mechanisms are used to replace this function, including substrate-assisted catalysis, a network of several residues, and the use of non-carboxylate residues or exogenous nucleophiles. Removal of the catalytic base/ nucleophile

129

Optimal control of fluid catalytic cracking processes  

Science Conference Proceedings (OSTI)

An investigation was made of the applicability of optimal control theory to the design of control systems for non-linear, multivariable chemical processes. A hypothetical fluid catalytic cracking process was selected as a typical representative of such ...

L. A. Gould; L. B. Evans; H. Kurihara

1970-09-01T23:59:59.000Z

130

Constraint condition on transformed relation for generalized acoustics  

E-Print Network (OSTI)

Contrary to transformation optics (TO), there exist many possibilities for transformed relations of material property and field variable in case of transformation acoustics (TA). To investigate the underlining mechanism and develop a general method that can obtain the full transformed relations, an alternative interpretation to the form-invariance is explored. We consider a spatial transformation, with which a physical phenomenon described in an initial space is transformed to a deformed space, and interpret the mapping by local affine transformation point-by-point. Further, we postulate that the transformed material property and field must rebuild the same physical process, and that the energy must be conserved at each point during the transformation. These conditions impose the constraint on the transformed relation for material property and field. By establishing two local Cartesian frames defined uniquely by the spatial transformation, any physical quantity is shown to first experience a rigid rotation and then a stretch operation during the transformation. We show that the constraint conditions are not enough to determine completely the transformed relation for TA, leaving a possibility to define them differently as found in the literature. New acoustic transformations with constant density or modulus are also proposed and verified by constructing a two-dimensional acoustic cloak. Finally, we show that the transformed relation is uniquely determined for transformation optics, and discuss how this method can be extended to other transformation physics.

Jin Hu; Xiaoning Liu; Gengkai Hu

2009-12-30T23:59:59.000Z

131

Learning Transformations From Video  

E-Print Network (OSTI)

on Natural Video . . . . . . . . . . . . . . . . .3 Learning Continuous Transformation from VideoProposed Video Coder

Wang, Ching Ming

2010-01-01T23:59:59.000Z

132

Generative model transformer  

Science Conference Proceedings (OSTI)

The Generative Model Transformer (GMT) project is an Open Source initiative to build a Model Driven Architecure™ tool that allows fully customisable Platform Independent Models, Platform Description Models, Texture Mappings, and Refinement Transformations. ... Keywords: QVT, domain-specific languages, generative model transformer (GMT), model driven architecture (MDA), model transformation, open source

Jorn Bettin; Ghica van Emde Boas

2003-10-01T23:59:59.000Z

133

A green transformer  

Science Conference Proceedings (OSTI)

The use of a new transformer and transformer fluid by a rural electric cooperative is described in the article. Edisol TR Transformers, which require about half as much fluid, are being used to replace existing transformers from 10- to 50 kVA. The dielectric fluid used in the transformers biodegrades more rapidly and completely, and is non-bioaccumulating in aquatic species. Standardized tests show that five to six weeks is required for biodegradation. The thermal design increases the efficiency of heat removal and reduces thermal gradients in the winding; the transformer is 20% smaller and 25% lighter than conventional transformers.

Wagner, A.

1997-03-01T23:59:59.000Z

134

Power Transformer Failure Investigation and Root Cause Analysis  

Science Conference Proceedings (OSTI)

This report provides practical, step-by-step guidance to help utility personnel gather evidence and perform investigations on failed or retired high-voltage substation power transformers to assist in determining the cause of the transformer’s failure or the service condition of retired units.BackgroundHigh-voltage transformers are essential to the reliability of the power system, but many are aging and nearing the end of their design lives. Transformer ...

2012-12-12T23:59:59.000Z

135

Broadband Dieletric Properties of Impregnated Transformer Paper Insulation at Various Moisture Contents.  

E-Print Network (OSTI)

?? The actual life of a transformer is determined by ageing of the cellulosic insulation such as transformer paper. The presence of moisture in the… (more)

Cheng, Jialu

2011-01-01T23:59:59.000Z

136

Canonical transformations in three-dimensional phase space  

E-Print Network (OSTI)

Canonical transformation in a three-dimensional phase space endowed with Nambu bracket is discussed in a general framework. Definition of the canonical transformations is constructed as based on canonoid transformations. It is shown that generating functions, transformed Hamilton functions and the transformation itself for given generating functions can be determined by solving Pfaffian differential equations corresponding to that quantities. Types of the generating functions are introduced and all of them is listed. Infinitesimal canonical transformations are also discussed. Finally, we show that decomposition of canonical transformations is also possible in three-dimensional phase space as in the usual two-dimensional one.

Dereli, T; Hakioglu, T

2009-01-01T23:59:59.000Z

137

Canonical transformations in three-dimensional phase space  

E-Print Network (OSTI)

Canonical transformation in a three-dimensional phase space endowed with Nambu bracket is discussed in a general framework. Definition of the canonical transformations is constructed as based on canonoid transformations. It is shown that generating functions, transformed Hamilton functions and the transformation itself for given generating functions can be determined by solving Pfaffian differential equations corresponding to that quantities. Types of the generating functions are introduced and all of them is listed. Infinitesimal canonical transformations are also discussed. Finally, we show that decomposition of canonical transformations is also possible in three-dimensional phase space as in the usual two-dimensional one.

T. Dereli; A. Tegmen; T. Hakioglu

2009-04-25T23:59:59.000Z

138

Catalytic H2O2 decomposition on palladium surfaces  

E-Print Network (OSTI)

The catalytic decomposition of H?O? at smooth single-crystal and polycrystalline palladium surfaces that had been subjected to various surface modifications has been studied. Monolayer and submonolayer coverages of I, Br and Cl adsorbates were used to pretrial the palladium surfaces. The rate of decomposition was found to be dependent upon the coverage and identity of the halogen adsorbate. Experimental measurements were based upon Auger electron spectroscopy (AES), low-energy electron Diffraction (LEED) and X-ray photoelectron spectroscopy (XPS) for the surface adlayers, redox titration for H?O? concentration determinations, and evolved-O? gas volume measurements for the decomposition rates.

Salinas, S. Adriana

1998-01-01T23:59:59.000Z

139

Split manageable efficient algorithm for Fourier and Hadamard transforms  

Science Conference Proceedings (OSTI)

In this paper, a general, efficient, manageable split algorithm to compute one-dimensional (1-D) unitary transforms, by using the special partitioning in the frequency domain, is introduced. The partitions determine fast transformations that split the ...

A.M. Grigoryan; S.S. Agaian

2000-01-01T23:59:59.000Z

140

Catalytic Combustor for Fuel-Flexible Turbine  

SciTech Connect

Under the sponsorship of the U. S. Department of Energy's National Energy Technology Laboratory, Siemens Westinghouse has conducted a three-year program to develop an ultra low NOx, fuel flexible catalytic combustor for gas turbine application in IGCC. The program is defined in three phases: Phase 1 - Implementation Plan, Phase 2 - Validation Testing and Phase 3 - Field Testing. Both Phase 1 and Phase 2 of the program have been completed. In IGCC power plants, the gas turbine must be capable of operating on syngas as a primary fuel and an available back-up fuel such as natural gas. In this program the Rich Catalytic Lean (RCLTM) technology is being developed as an ultra low NOx combustor. In this concept, ultra low NOx is achieved by stabilizing a lean premix combustion process by using a catalytic reactor to oxidize a portion of the fuel, increasing the temperature of fuel/air mixture prior to the main combustion zone. In Phase 1, the feasibility of the catalytic concept for syngas application has been evaluated and the key technology issues identified. In Phase II the technology necessary for the application of the catalytic concept to IGCC fuels was developed through detailed design and subscale testing. Phase III (currently not funded) will consist of full-scale combustor basket testing on natural gas and syngas.

W. R. Laster; E. Anoshkina

2008-01-31T23:59:59.000Z

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141

Catalytic Combustor for Fuel-Flexible Turbine  

SciTech Connect

Under the sponsorship of the U.S. Department of Energy's National Energy Technology Laboratory, Siemens Westinghouse is conducting a three-year program to develop an ultra low NOx, fuel flexible catalytic combustor for gas turbine application in IGCC. The program is defined in three phases: Phase 1-Implementation Plan, Phase 2-Validation Testing and Phase 3-Field Testing. The Phase 1 program has been completed. Phase II was initiated in October 2004. In IGCC power plants, the gas turbine must be capable of operating on syngas as a primary fuel and an available back-up fuel such as natural gas. In this program the Rich Catalytic Lean (RCL{trademark}) technology is being developed as an ultra low NOx combustor. In this concept, ultra low NOx is achieved by stabilizing a lean premix combustion process by using a catalytic reactor to react part of the fuel, increasing the fuel/air mixture temperature. In Phase 1, the feasibility of the catalytic concept for syngas application has been evaluated and the key technology issues identified. In Phase II the catalytic concept will be demonstrated through subscale testing. Phase III will consist of full-scale combustor basket testing on natural gas and syngas.

W. R. Laster; E. Anoshkina; P. Szedlacsek

2006-03-31T23:59:59.000Z

142

Catalytic Combustor for Fuel-Flexible Turbine  

SciTech Connect

Under the sponsorship of the U. S. Department of Energy’s National Energy Technology Laboratory, Siemens Westinghouse has conducted a three-year program to develop an ultra low NOx, fuel flexible catalytic combustor for gas turbine application in IGCC. The program is defined in three phases: Phase 1- Implementation Plan, Phase 2- Validation Testing and Phase 3 – Field Testing. Both Phase 1 and Phase 2 of the program have been completed. In IGCC power plants, the gas turbine must be capable of operating on syngas as a primary fuel and an available back-up fuel such as natural gas. In this program the Rich Catalytic Lean (RCLTM) technology is being developed as an ultra low NOx combustor. In this concept, ultra low NOx is achieved by stabilizing a lean premix combustion process by using a catalytic reactor to oxidize a portion of the fuel, increasing the temperature of fuel/air mixture prior to the main combustion zone. In Phase 1, the feasibility of the catalytic concept for syngas application has been evaluated and the key technology issues identified. In Phase II the technology necessary for the application of the catalytic concept to IGCC fuels was developed through detailed design and subscale testing. Phase III (currently not funded) will consist of full-scale combustor basket testing on natural gas and syngas.

Laster, W. R.; Anoshkina, E.

2008-01-31T23:59:59.000Z

143

On discrete cosine transform  

E-Print Network (OSTI)

The discrete cosine transform (DCT), introduced by Ahmed, Natarajan and Rao, has been used in many applications of digital signal processing, data compression and information hiding. There are four types of the discrete cosine transform. In simulating the discrete cosine transform, we propose a generalized discrete cosine transform with three parameters, and prove its orthogonality for some new cases. A new type of discrete cosine transform is proposed and its orthogonality is proved. Finally, we propose a generalized discrete W transform with three parameters, and prove its orthogonality for some new cases.

Zhou, Jianqin

2011-01-01T23:59:59.000Z

144

Electro Catalytic Oxidation (ECO) Operation  

Science Conference Proceedings (OSTI)

The power industry in the United States is faced with meeting many new regulations to reduce a number of air pollutants including sulfur dioxide, nitrogen oxides, fine particulate matter, and mercury. With over 1,000 power plants in the US, this is a daunting task. In some cases, traditional pollution control technologies such as wet scrubbers and SCRs are not feasible. Powerspan's Electro-Catalytic Oxidation, or ECO{reg_sign} process combines four pollution control devices into a single integrated system that can be installed after a power plant's particulate control device. Besides achieving major reductions in emissions of sulfur dioxide (SO{sub 2}), nitrogen oxides (NOx), fine particulate matter (PM2.5) and mercury (Hg), ECO produces a highly marketable fertilizer, which can help offset the operating costs of the process system. Powerspan has been operating a 50-MW ECO commercial demonstration unit (CDU) at FirstEnergy Corp.'s R.E. Burger Plant near Shadyside, Ohio, since February 2004. In addition to the CDU, a test loop has been constructed beside the CDU to demonstrate higher NOx removal rates and test various scrubber packing types and wet ESP configurations. Furthermore, Powerspan has developed the ECO{reg_sign}{sub 2} technology, a regenerative process that uses a proprietary solvent to capture CO{sub 2} from flue gas. The CO{sub 2} capture takes place after the capture of NOx, SO{sub 2}, mercury, and fine particulate matter. Once the CO{sub 2} is captured, the proprietary solution is regenerated to release CO{sub 2} in a form that is ready for geological storage or beneficial use. Pilot scale testing of ECO{sub 2} began in early 2009 at FirstEnergy's Burger Plant. The ECO{sub 2} pilot unit is designed to process a 1-MW flue gas stream and produce 20 tons of CO{sub 2} per day, achieving a 90% CO{sub 2} capture rate. The ECO{sub 2} pilot program provided the opportunity to confirm process design and cost estimates, and prepare for large scale capture and sequestration projects. The objectives of this project were to prove at a commercial scale that ECO is capable of extended operations over a range of conditions, that it meets the reliability requirements of a typical utility, and that the fertilizer co-product can be consistently generated, providing ECO with an economic advantage over conventional technologies currently available. Further objectives of the project were to show that the ECO system provides flue gas that meets the inlet standards necessary for ECO{sub 2} to operate, and that the outlet CO{sub 2} and other constituents produced by the ECO{sub 2} pilot can meet Kinder-Morgan pipeline standards for purposes of sequestration. All project objectives are consistent with DOE's Pollution Control Innovations for Power Plants program goals.

Morgan Jones

2011-03-31T23:59:59.000Z

145

Post-spinel transformations and equation of state in ZnGa[subscript 2]O[subscript 4]: Determination at high pressure by in situ x-ray diffraction  

Science Conference Proceedings (OSTI)

Room-temperature angle-dispersive x-ray diffraction measurements on spinel ZnGa{sub 2}O{sub 4} up to 56 GPa show evidence of two structural phase transformations. At 31.2 GPa, ZnGa{sub 2}O{sub 4} undergoes a transition from the cubic spinel structure to a tetragonal spinel structure similar to that of ZnMn{sub 2}O{sub 4}. At 55 GPa, a second transition to the orthorhombic marokite structure (CaMn{sub 2}O{sub 4}-type) takes place. The equation of state of cubic spinel ZnGa{sub 2}O{sub 4} is determined: V{sub 0} = 580.1(9) {angstrom}{sup 3}, B{sub 0} = 233(8) GPa, B'{sub 0} = 8.3(4), and B''{sub 0} = -0.1145 GPa{sup -1} (implied value); showing that ZnGa{sub 2}O{sub 4} is one of the less compressible spinels studied to date. For the tetragonal structure an equation of state is also determined: V{sub 0} = 287.8(9) {angstrom}{sup 3}, B{sub 0} = 257(11) GPa, B'{sub 0} = 7.5(6), and B''{sub 0} = -0.0764 GPa{sup -1} (implied value). The reported structural sequence coincides with that found in NiMn{sub 2}O{sub 4} and MgMn{sub 2}O{sub 4}.

Errandonea, D.; Kumar, Ravhi S.; Manjón, F.J.; Ursaki, V.V.; Rusu, E.V.; (UNLV); (Acad.Sci.-Moldova); (Valencia)

2009-01-15T23:59:59.000Z

146

Metrics for enterprise transformation  

E-Print Network (OSTI)

The objective of this thesis is to depict the role of metrics in the evolving journey of enterprise transformation. To this end, three propositions are explored: (i) metrics and measurement systems drive transformation, ...

Blackburn, Craig D. (Craig David), S. M. Massachusetts Institute of Technology

2009-01-01T23:59:59.000Z

147

Electrokinetic effects in power transformers  

Science Conference Proceedings (OSTI)

Electrokinetic effects such as static electrification can cause catastrophic failures in large forced-oil-cooled power transformers. Experimental and analytical studies confirm that surface charges can significantly impact dielectric integrity. The project team used a closed-loop oil circulation system and full-scale models of power transformer cooling duct structures to conduct controlled experiments. They measured charge density in the oil-resulting from flow through these structures-as a function of flow rate, temperature, ac voltage stress, moisture, and duct types. In addition, they constructed models so that the spatial distribution of electrostatically induced currents and stresses could be determined. They developed a finite-element computer program to study the complex voltage distribution in the models and in two transformer winding examples. A special test cell was used to examine the impact of surface charge on creep strength of transformer pressboard. Static electrification in power transformer duct structures is aggravated by flow rate, temperature, presence of collars, and ac energization; and it is mitigated by increasing oil moisture content. Shell-form model structures exhibit more charge generation than disk-type core-form winding ducts under corresponding conditions. Partial discharges were detected in one shell-form model but only under the worst conditions. These discharges were not energetic enough to produce visible damage. Preliminary finite-element analysis indicates that surface charge has more impact on cumulative stress in a shell-form geometry than in a core-form disk winding.

Nelson, J.K.; Lee, M.J.; Salon, S.J. (Rensselaer Polytechnic Inst., Troy, NY (United States). Dept. of Electric Power Engineering)

1992-11-01T23:59:59.000Z

148

Typechecking for XML transformers  

Science Conference Proceedings (OSTI)

We study the typechecking problem for XML transformers: given an XML transformation program and a DTD for the input XML documents, check whether every result of the program conforms to a specified output DTD. We model XML transformers using a novel device ...

Tova Milo; Dan Suciu; Victor Vianu

2000-05-01T23:59:59.000Z

149

A dc transformer  

Science Conference Proceedings (OSTI)

Although conventional transformers are ac, a device that may be termed a dc transformer has been constructed by using superconductors. To provide an understanding of how such a transformer would operate, some of the properties of type I and type II superconductors ...

I. Giaever

1966-09-01T23:59:59.000Z

150

Transforming a Transformative School | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

You are here You are here Home » Transforming a Transformative School Transforming a Transformative School October 11, 2012 - 10:14am Addthis During a yearlong renovation, Harding Charter Preparatory school upgraded lighting fixtures, installed a new heating and cooling system, and replaced the entry doors. The new doors allow daylight into the school and restore the historical building envelope. | Photo courtesy of John Winkel, Energy Department. During a yearlong renovation, Harding Charter Preparatory school upgraded lighting fixtures, installed a new heating and cooling system, and replaced the entry doors. The new doors allow daylight into the school and restore the historical building envelope. | Photo courtesy of John Winkel, Energy Department. Julie McAlpin

151

Fundamental kinetic modeling of the catalytic reforming process  

Science Conference Proceedings (OSTI)

In this work, a fundamental kinetic model for the catalytic reforming process has been developed. The complex network of elementary steps and molecular reactions occurring in catalytic reforming has been generated through a computer algorithm characterizing ...

Rogelio Sotelo-Boyas / Gilbert F. Froment; Rayford G. Anthony

2005-01-01T23:59:59.000Z

152

Annual Operation of Selective Catalytic Reduction Systems  

Science Conference Proceedings (OSTI)

In 2009, many coal-fired generating units equipped with selective catalytic reduction (SCR) systems for nitrogen oxide (NOX) control will convert from seasonal to annual SCR operation. This report provides guidelines on how to prepare for annual operation. It focuses on existing experience with annual operation, catalyst management strategy, equipment reliability, cold weather issues, low load and cycling operation, and risk assessment.

2007-12-18T23:59:59.000Z

153

Fuzzy modeling of fluidized catalytic cracking unit  

Science Conference Proceedings (OSTI)

The paper deals with the fuzzy system identification of reactor-regenerator-stripper-fractionator's (RRSF) section of a fluidized catalytic cracking unit (FCCU). The fuzzy system identification based on the data collected from an operating refinery of ... Keywords: Dynamic fuzzy model, FCCU models, Fuzzy clustering, Fuzzy inference systems, Fuzzy models, Hybrid learning, Mountain clustering, Supervised learning, Unsupervised learning

Mohammad Fazle Azeem; Nesar Ahmad; M. Hanmandlu

2007-01-01T23:59:59.000Z

154

Performance characterization of a hydrogen catalytic heater.  

DOE Green Energy (OSTI)

This report describes the performance of a high efficiency, compact heater that uses the catalytic oxidation of hydrogen to provide heat to the GM Hydrogen Storage Demonstration System. The heater was designed to transfer up to 30 kW of heat from the catalytic reaction to a circulating heat transfer fluid. The fluid then transfers the heat to one or more of the four hydrogen storage modules that make up the Demonstration System to drive off the chemically bound hydrogen. The heater consists of three main parts: (1) the reactor, (2) the gas heat recuperator, and (3) oil and gas flow distribution manifolds. The reactor and recuperator are integrated, compact, finned-plate heat exchangers to maximize heat transfer efficiency and minimize mass and volume. Detailed, three-dimensional, multi-physics computational models were used to design and optimize the system. At full power the heater was able to catalytically combust a 10% hydrogen/air mixture flowing at over 80 cubic feet per minute and transfer 30 kW of heat to a 30 gallon per minute flow of oil over a temperature range from 100 C to 220 C. The total efficiency of the catalytic heater, defined as the heat transferred to the oil divided by the inlet hydrogen chemical energy, was characterized and methods for improvement were investigated.

Johnson, Terry Alan; Kanouff, Michael P.

2010-04-01T23:59:59.000Z

155

Rapid Deployment of Rich Catalytic Combustion  

SciTech Connect

The overall objective of this research under the Turbines Program is the deployment of fuel flexible rich catalytic combustion technology into high-pressure ratio industrial gas turbines. The resulting combustion systems will provide fuel flexibility for gas turbines to burn coal derived synthesis gas or natural gas and achieve NO{sub x} emissions of 2 ppmvd or less (at 15 percent O{sub 2}), cost effectively. This advance will signify a major step towards environmentally friendly electric power generation and coal-based energy independence for the United States. Under Phase 1 of the Program, Pratt & Whitney (P&W) performed a system integration study of rich catalytic combustion in a small high-pressure ratio industrial gas turbine with a silo combustion system that is easily scalable to a larger multi-chamber gas turbine system. An implementation plan for this technology also was studied. The principal achievement of the Phase 1 effort was the sizing of the catalytic module in a manner which allowed a single reactor (rather than multiple reactors) to be used by the combustion system, a conclusion regarding the amount of air that should be allocated to the reaction zone to achieve low emissions, definition of a combustion staging strategy to achieve low emissions, and mechanical integration of a Ceramic Matrix Composite (CMC) combustor liner with the catalytic module.

Richard S. Tuthill

2004-06-10T23:59:59.000Z

156

2001 Workshop on Selective Catalytic Reduction  

Science Conference Proceedings (OSTI)

Approximately 100,000 megawatts of coal-fired capacity in the United States will employ selective catalytic reduction (SCR) for the control of nitrogen oxides (NOx) emissions by 2004. The 2001 Workshop on SCR, held in Baltimore, Maryland, provided a forum for discussion of current SCR issues.

2002-02-04T23:59:59.000Z

157

Purification of reformer streams by catalytic hydrogenation  

Science Conference Proceedings (OSTI)

Catalytic Reforming is one of the most important processes to produce high grade motor gasolines. Feedstocks are mainly gasoline and naphtha streams from the crude oil distillation boiling in the range of 212 F to 350 F. By catalytic reforming the octane number of these gasoline components is increased from 40--60 RON to 95--100 RON. Besides isomerization and dehydrocyclization reactions mainly formation of aromatics by dehydrogenation of naphthenes occur. Thus, catalytic reformers within refineries are an important source of BTX--aromatics (benzene, toluene, xylenes). Frequently, high purity aromatics are recovered from these streams using modern extractive distillation or liquid extraction processes, e.g. the Krupp-Koppers MORPHYLANE{reg_sign} process. Aromatics product specifications, notably bromine index and acid wash color, have obligated producers to utilize clay treatment to remove trace impurities of diolefins and/or olefins. The conventional clay treatment is a multiple vessel batch process which periodically requires disposal of the spent clay in a suitable environmental manner. BASF, in close cooperation with Krupp-Koppers, has developed a continuous Selective Catalytic Hydrogenation Process (SCHP) as an alternative to clay treatment which is very efficient, cost effective and environmentally compatible. In the following the main process aspects including the process scheme catalyst and operating conditions is described.

Polanek, P.J. [BASF Corp., Geismar, LA (United States); Hooper, H.M. [Krupp Wilputte Corp., Bridgeville, PA (United States); Mueller, J.; Walter, M. [BASF AG, Ludwigshafen (Germany); Emmrich, G. [Krupp Koppers GmbH, Essen (Germany)

1996-12-01T23:59:59.000Z

158

Puerto Rico Refinery Catalytic Hydrotreating, Kerosene/Jet Fuel ...  

U.S. Energy Information Administration (EIA)

Puerto Rico Refinery Catalytic Hydrotreating, Kerosene/Jet Fuel Downstream Charge Capacity as of January 1 (Barrels per Stream Day)

159

Puerto Rico Refinery Catalytic Hydrocracking, Gas Oil Downstream ...  

U.S. Energy Information Administration (EIA)

Puerto Rico Refinery Catalytic Hydrocracking, Gas Oil Downstream Charge Capacity as of January 1 (Barrels per Stream Day)

160

Colorado Refinery Catalytic Hydrotreating, Other/Residual Fuel Oil ...  

U.S. Energy Information Administration (EIA)

Colorado Refinery Catalytic Hydrotreating, Other/Residual Fuel Oil Downstream Charge Capacity as of January 1 (Barrels per Stream Day)

Note: This page contains sample records for the topic "determination catalytic transformation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

New Jersey Refinery Catalytic Reforming/High Pressure Downstream ...  

U.S. Energy Information Administration (EIA)

New Jersey Refinery Catalytic Reforming/High Pressure Downstream Charge Capacity as of January 1 (Barrels per Stream Day)

162

Arkansas Refinery Catalytic Reforming/High Pressure Downstream ...  

U.S. Energy Information Administration (EIA)

Arkansas Refinery Catalytic Reforming/High Pressure Downstream Charge Capacity as of January 1 (Barrels per Stream Day)

163

U.S. Refinery Catalytic Hydrotreating, Heavy Gas Oil ...  

U.S. Energy Information Administration (EIA)

U.S. Refinery Catalytic Hydrotreating, Heavy Gas Oil Downstream Charge Capacity as of January 1 (Barrels per Stream Day)

164

When Catalysis is Useful for Probabilistic Entanglement Transformation  

E-Print Network (OSTI)

We determine all $2\\times 2$ quantum states that can serve as useful catalysts for a given probabilistic entanglement transformation, in the sense that they can increase the maximal transformation probability. When higher-dimensional catalysts are considered, a sufficient and necessary condition is derived under which a certain probabilistic transformation has useful catalysts.

Yuan Feng; Runyao Duan; Mingsheng Ying

2004-03-24T23:59:59.000Z

165

The interlaced chirp Z transform  

Science Conference Proceedings (OSTI)

In this paper we introduce the interlaced chirp Z transform (Interlaced CZT), It is based on the computation of several carefully staggered CZT that are progressively interlaced to result in a spectrum that has denser frequency samples where needed. ... Keywords: chirp Z transform, discrete fourier transform, interlaced chirp Z transform, warped discrete fourier transform, zoom chirp Z transform

Indranil Sarkar; Adly T. Fam

2006-09-01T23:59:59.000Z

166

CX-010270: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Exclusion Determination Developing Gas Stripping, Catalytic Fast Pyrolysis Conversion of Corn Stover to Drop-in Quality Hydrocarbons CX(s) Applied: A9, B3.6 Date: 05092013...

167

General Relativistic Contributions in Transformation Optics  

E-Print Network (OSTI)

One potentially realistic specification for devices designed with transformation optics is that they operate with high precision in curved space-time, such as Earth orbit. This raises the question of what, if any, role does space-time curvature play in determining transformation media? Transformation optics has been based on a three-vector representation of Maxwell's equations in flat Minkowski space-time. I discuss a completely covariant, manifestly four-dimensional approach that enables transformations in arbitrary space-times, and demonstrate this approach for stable circular orbits in the spherically symmetric Schwarzschild geometry. Finally, I estimate the magnitude of curvature induced contributions to satellite-borne transformation media in Earth orbit and comment on the level of precision required for metamaterial fabrication before such contributions become important.

Robert T. Thompson

2011-02-08T23:59:59.000Z

168

Transforming Commercial Building Operations  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Transforming Commercial Building Operations Transforming Commercial Building Operations Transforming Commercial Building Operations Ron Underhill Pacific Northwest National Laboratory ronald.underhill@pnnl.gov (509)375-9765 April 4, 2013 2 | Building Technologies Office eere.energy.gov * Most buildings are not commissioned (Cx) before occupancy, including HVAC and lighting systems * Buildings often are poorly operated and maintained leading to significant energy waste of 5 to 20%, even when they have building automation systems (BASs)

169

Transforming Commercial Building Operations  

NLE Websites -- All DOE Office Websites (Extended Search)

Transforming Commercial Building Operations Transforming Commercial Building Operations Transforming Commercial Building Operations Ron Underhill Pacific Northwest National Laboratory ronald.underhill@pnnl.gov (509)375-9765 April 4, 2013 2 | Building Technologies Office eere.energy.gov * Most buildings are not commissioned (Cx) before occupancy, including HVAC and lighting systems * Buildings often are poorly operated and maintained leading to significant energy waste of 5 to 20%, even when they have building automation systems (BASs)

170

Adaptive Discrete Cosine Transform  

Science Conference Proceedings (OSTI)

The theory and performance of the adaptive discrete cosine transform filter is examined. The discrete cosine transform filter is a realization of an FIR filter as the cascade of an all-zero FIR filter with a bank of IIR digital resonators. Each bank ... Keywords: FIR filter, IIR digital resonators, LMS algorithm, adaptive discrete cosine transform filter, adaptive filters, all-zero FIR filter, filter coefficient, frequency, magnitude, phase, transfer function, update method

S. J. Bukowinski; L. Gerhardt; M. Fargues; G. Coutu

1995-10-01T23:59:59.000Z

171

EPRI Transformer Guidebook Development  

Science Conference Proceedings (OSTI)

Utilities are losing many of their subject matter experts through retirement and downsizing. This is particularly true in the case of power transformers, so that there is now a critical need for a comprehensive transformer reference book geared toward utility engineers. In 2007, the Electric Power Research Institute EPRI published the technical update report Transformer Guidebook Design 1013799. That report described the results of the initial project to develop the Copper Book, a comprehensive reference...

2009-12-23T23:59:59.000Z

172

A New Integral Transform  

E-Print Network (OSTI)

Using Bauer's expansion and properties of spherical Bessel and Legender functions, we deduce a new transform and briefly indicate its use.

B. G. Sidharth

2004-12-04T23:59:59.000Z

173

Transforming the Freight Industry  

E-Print Network (OSTI)

Transforming the Freight Industry From Regulation to Icommon-carrier freight industry was Competition to backwardjourneys. When the freight industry was deregulated, it was

Regan, Amelia

2002-01-01T23:59:59.000Z

174

Transformer Ratio Enhancement Experiment  

NLE Websites -- All DOE Office Websites (Extended Search)

TRANSFORMER RATIO ENHANCEMENT EXPERIMENT A. Kanareykin, Euclid Concepts LLC, Solon, OH 44139, USA W. Gai, J. G. Power. ANL, Argonne, IL, 60439, USA E. Nenasheva, Ceramics Ltd., St....

175

Market Transformation Programs  

NLE Websites -- All DOE Office Websites (Extended Search)

Efficiency Improvement Opportunities in TVs Implications for Market Transformation Programs journal Energy Policy volume year month pages keywords appliance energy efficiency...

176

An Energy Analysis of the Catalytic Combustion Burner  

E-Print Network (OSTI)

The gas boilers of conventional flame always produce varying degrees of combustion products NOx and CO, which pollute the environment and waste energy. As a new way of combustion, catalytic combustion breaks the flammable limits of conventional flame combustion, and realizes the combustion of ultra-natural gas/air mixture under the flammable limits. Its combustion efficiency is higher, which improves the ratio of energy utilization. Applying the catalytic combustion to gas boilers could solve the gas boilers' lower combustion efficiency, and achieve energy savings. On the basis of the catalytic combustion burner, the catalytic combustion burner was designed according to the catalytic combustion and water heaters. In this paper, we analyzed the heat loss and thermal efficiency of the catalytic combustion burner, and compared it to that of flame combustion boilers. The results showed that catalytic combustion burner ?'s heat loss is not so high as originally considered, and its pollutant emissions are lower.

Dong, Q.; Zhang, S.; Duan, Z.; Zhou, Q.

2006-01-01T23:59:59.000Z

177

Endothermic photo-catalytic reactions. Final report  

SciTech Connect

The overall objective of this report is to present the results of an investigation to provide guidelines for future experimental work, on solar energy driven endothermic photo-catalytic reactions, and primarily to select candidate synthesis reactions which lead to high $-value products. An intensive literature search was conducted to find properties, market demand, and prices of pertinent chemicals; meeting four criteria: (1) the reaction must be endothermic and favorable; (2) the reaction must be catalytic; (3) the product must be produced from low cost feedstocks; and (4) the product must have a sales price >$1.00/lb. Initial examination of low cost feedstocks to high value products lead to consideration of n-paraffins to aromatics and substituted aromatics. Fifteen candidate endothermic synthesis reactions, meeting the above criteria, are suggested. The ratio of product price by reactant cost indicates {approximately}5--8 for the best possibilities; all can be visualized as starting with low cost paraffin and methanol feedstocks.

Prengle, H.W. Jr.; Wentworth, W.E.; Polonczyk, K.C.; Saghafi, M.; Wilking, J.A.; Kramer, K.S. [Houston Univ., TX (United States)

1992-04-01T23:59:59.000Z

178

Database - Selective Catalytic Reduction Catalyst Deactivation Rates  

Science Conference Proceedings (OSTI)

Selective catalytic reduction (SCR) catalyst deactivation is a critical parameter controlling to a large extent achievable catalyst life, as well as overall SCR system performance. Accurate assessment and prediction of catalyst deactivation is required to adequately manage reactor potential. EPRI has on-going efforts underway aimed at better understanding the factors that affect catalyst deactivation, especially as a function of fuel, boiler design, and boiler operating conditions, in hopes of ...

2013-11-06T23:59:59.000Z

179

2006 Workshop on Selective Catalytic Reduction  

Science Conference Proceedings (OSTI)

EPRI held the 2006 Workshop on Selective Catalytic Reduction (SCR) on October 31 November 2, 2006 at the Dearborn Inn in Dearborn, Michigan and at DTE Energy's Monroe Station. Post-Combustion NOX Control Program members, invited speakers, and EPRI staff participated in this two and a half day event. The workshop agenda was comprised of twenty-seven presentations, two panel discussions, and a plant tour. Operating experience reports on SCR systems at Baldwin, Bowen, Bull Run, Crist, Cumberland, Gaston, Go...

2007-03-07T23:59:59.000Z

180

IFP solutions for revamping catalytic reforming units  

Science Conference Proceedings (OSTI)

The decision-making process for the refiner considering a revamp of a catalytic reforming unit comprises many factors. These may be grouped in two broad areas: technical and economic. This paper presents the results of a study performed by IFP that illustrates catalytic reforming unit revamp options. Three IFP processes are described and operating conditions, expected yields, and economic data are presented. The following options are discussed: base case Conventional, fixed-bed, semi-regenerative catalytic reformer; Case 1--revamp using IFP Dualforming technology; Case 2--revamp using IFP Dualforming Plus technology; and Case 3--revamp to IFP Octanizing technology. The study illustrates various options for the refiner to balance unit performance improvements with equipment, site, and economic constraints. The study was performed assuming design feedrate of 98.2 tons/hour (20,000 BPSD) in all cases. Because of the increased need for octane in many refineries, the study assumed that operating severity was set at a design value of 100 research octane number clear (RON). In all of the cases in this study, it was assumed that the existing recycle compressor was reused. Operating pressure differences between the cases is discussed separately. Also, in all cases, a booster compressor was included in order to return export hydrogen pressure to that of the conventional unit.

Gendler, J.L. [HRI, Inc., Princeton, NJ (United States); Domergue, B.; Mank, L. [Inst. Francais du Petrole, Rueil Malmaison (France)

1996-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "determination catalytic transformation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Behavior of chars from Bursa Mustafa Kemal Pasa Alpagut and Balkesir Dursunbey Cakiirca Lignite (Turkey) during non-catalytic and catalytic gasification  

Science Conference Proceedings (OSTI)

The reactivities of chars obtained by pyrolysis of Bursa Mustafa Kemal Pasa Alpagut lignite and Balkesir Dursunbey Cakiirca lignite (Turkey) at different temperatures were determined by CO{sub 2} gasification and by combustion with O{sub 2}. Catalytic effect of Na{sub 2}CO{sub 3} on the CO{sub 2} and O{sub 2} gasification reactivity of chars was investigated. Gasification tests were performed in the fixed bed reactors operating at ambient pressure. Reactivity of chars during the CO{sub 2} gasification reactions was determined by calculating the reaction rate constants and reactivity of chars during the O{sub 2} gasification was determined by using ignition temperatures of the samples. Activation energies and Arrhenius constants of the chars on the CO{sub 2} gasification reactions were also calculated by the help of Arrhenius curves. The activation energy for CO{sub 2} gasification was generally decreased with pyrolysis temperature, due to the different surface characteristics and different nature of carbon atoms gasified as the gasification reactions proceed. Generally, the increase in pyrolysis temperature leads to an increase in gasification reactivity with CO{sub 2}. The reactivity of chars in catalytic gasification was higher than the corresponding non-catalytic reactivity of the same chars. Ignition temperature increased with increasing pyrolysis temperature.

Bozkurt, Y.; Misirlioglu, Z.; Sinag, A.; Tekes, A.T.; Canel, M. [Ankara University, Ankara (Turkey). Dept. of Chemistry

2008-07-01T23:59:59.000Z

182

Transformations of Grassman Spaces  

E-Print Network (OSTI)

This is a version of a part of the book ``Transformations of Grassman Spaces'' (in progress). We study transformations of Grassman spaces preserving certain geometrical constructions related to buildings. The next part will be devoted to Grassman spaces associated with polar spaces.

Mark Pankov

2004-04-05T23:59:59.000Z

183

Deployment & Market Transformation (Brochure)  

SciTech Connect

NREL's deployment and market transformation (D and MT) activities encompass the laboratory's full range of technologies, which span the energy efficiency and renewable energy spectrum. NREL staff educates partners on how they can advance sustainable energy applications and also provides clients with best practices for reducing barriers to innovation and market transformation.

Not Available

2012-04-01T23:59:59.000Z

184

Generalized Lorentz Transformations  

E-Print Network (OSTI)

Generalized Lorentz transformations with modified velocity parameter are considered. Lorentz transformations depending on the mass of the observer are suggested.The modified formula for the addition of velocities remarkably preserves the constancy of the velocity of light for all observers. The Doppler red shift is affected and can provide a test of such generalisations.

Virendra Gupta

2013-05-22T23:59:59.000Z

185

Biochemical transformation of coals  

DOE Patents (OSTI)

A method of biochemically transforming macromolecular compounds found in solid carbonaceous materials, such as coal is provided. The preparation of new microorganisms, metabolically weaned through challenge growth processes to biochemically transform solid carbonaceous materials at extreme temperatures, pressures, pH, salt and toxic metal concentrations is also disclosed. 7 figs.

Lin, M.S.; Premuzic, E.T.

1999-03-23T23:59:59.000Z

186

Deployment & Market Transformation (Brochure)  

SciTech Connect

NREL's deployment and market transformation (D and MT) activities encompass the laboratory's full range of technologies, which span the energy efficiency and renewable energy spectrum. NREL staff educates partners on how they can advance sustainable energy applications and also provides clients with best practices for reducing barriers to innovation and market transformation.

2012-04-01T23:59:59.000Z

187

Phenol and phenolics from lignocellulosic biomass by catalytic microwave pyrolysis  

Science Conference Proceedings (OSTI)

Catalytic microwave pyrolysis of biomass using activated carbon was investigated to determine the effects of pyrolytic conditions on the yields of phenol and phenolics. The high concentrations of phenol (38.9%) and phenolics (66.9%) were obtained at the temperature of 589 K, catalyst-to-biomass ratio of 3:1 and retention time of 8 min. The increase of phenol and its derivatives compared to pyrolysis without catalysts has a close relationship with the decomposition of lignin under the performance of activated carbon. The concentration of esters was also increased using activated carbon as a catalyst. The high content of phenols obtained in this study can be used either directly as fuel after upgrading or as feedstock of biobased phenols for chemical industry.

Bu, Quan; Lei, Hanwu; Ren, Shoujie; Wang, Lu; Holladay, Johnathan E.; Zhang, Qin; Tang, Juming; Ruan, Roger

2011-07-01T23:59:59.000Z

188

A discrete fractional random transform  

E-Print Network (OSTI)

We propose a discrete fractional random transform based on a generalization of the discrete fractional Fourier transform with an intrinsic randomness. Such discrete fractional random transform inheres excellent mathematical properties of the fractional Fourier transform along with some fantastic features of its own. As a primary application, the discrete fractional random transform has been used for image encryption and decryption.

Zhengjun Liu; Haifa Zhao; Shutian Liu

2006-05-20T23:59:59.000Z

189

Lorentz transformation by mimicking the Lorentz transformation  

E-Print Network (OSTI)

We show that starting with the fact that special relativity theory is concerned with a distortion of the observed length of a moving rod, without mentioning if it is a "contraction" or "dilation", we can derive the Lorentz transformations for the spacetime coordinates of the same event. This derivation is based on expressing the length of the moving rod as a sum of components with all the lengths involved in this summation being measured by the observers of the same inertial reference frame.

Bernhard Rothenstein; Stefan Popescu

2007-07-16T23:59:59.000Z

190

Market Transformation Fact Sheet  

NLE Websites -- All DOE Office Websites (Extended Search)

Transformation Market Transformation is based on the concept that federal support can catalyze a market to achieve economic and environmental benefits that can reduce costs through economies of scale. Adoption of fuel cells in emerging markets expands the growth of green jobs, with new opportunities in manufacturing, fuel cell maintenance and support systems, and domestic hydrogen fuel production and delivery. By providing reliable field operations data and increasing user confidence, early market deployments help overcome non-technical challenges like developing appropriate safety codes and standards and reducing high insurance costs. Strategies Market Transformation's primary goal is to accelerate the expansion of hydrogen and fuel cell use by lowering the life

191

Fundamental kinetic modeling of the catalytic reforming process  

E-Print Network (OSTI)

In this work, a fundamental kinetic model for the catalytic reforming process has been developed. The complex network of elementary steps and molecular reactions occurring in catalytic reforming has been generated through a computer algorithm characterizing the various species by vectors and Boolean relation matrices. The algorithm is based on the fundamental chemistry occurring on both acid and metal sites of the catalyst. Rates are expressed for each of the elementary steps involved in the transformation of the intermediates. The Hougen-Watson approach is used to express the rates of the molecular reactions occurring on the metal sites of the catalyst. The single event approach is used to account for the effect of structure of reactant and activated complex on the rate coefficients of the elementary steps occurring on the acid sites. This approach recognizes that even if the number of elementary steps is very large they belong to a very limited number of types, and therefore it is possible to express the kinetics of elementary steps by a reduced number of parameters. In addition, the single event approach leads to rate coefficients that are independent of the feedstock, due to their fundamental chemical nature. The total number of parameters at isothermal conditions is 45. To estimate these parameters, an objective function based upon the sum of squares of the residuals was minimized through the Marquardt algorithm. Intraparticle mass transport limitations and deactivation of the catalyst by coke formation are considered in the model. Both the Wilke and the Stefan-Maxwell approaches were used to calculate the concentration gradients inside of the particle. The heterogeneous kinetic model was applied in the simulation of the process for typical industrial conditions for both axial and radial flow fixed bed reactors. The influence of the main process variables on the octane number and reformate volume was investigated and optimal conditions were obtained. Additional aspects studied with the kinetic model are the reduction of aromatics, mainly benzene. The results from the simulations agree with the typical performance found in the industrial process.

Sotelo-Boyas, Rogelio

2005-12-01T23:59:59.000Z

192

CX-005116: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Determination CX-005116: Categorical Exclusion Determination Lusk Substation Transformer Replacement, Lusk, Niobrara County, Wyoming CX(s) Applied: B4.6 Date: 01242011...

193

CX-009198: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Exclusion Determination CX-009198: Categorical Exclusion Determination Ross Transformer Oil Terminal Upgrade CX(s) Applied: B4.6 Date: 09242012 Location(s): Washington...

194

CX-010408: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Determination CX-010408: Categorical Exclusion Determination Emergency Current Transformer Replacement at Gila Substation CX(s) Applied: B4.6 Date: 04262013 Location(s):...

195

CX-007153: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Determination CX-007153: Categorical Exclusion Determination Glen Canyon substation Transformer Addition CX(s) Applied: B4.6 Date: 05052011 Location(s): Coconino County, Arizona...

196

CX-007807: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Determination CX-007807: Categorical Exclusion Determination Griffith Substation Transformer Addition CX(s) Applied: B4.6 Date: 11142011 Location(s): Nevada Offices(s):...

197

CX-005114: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Determination CX-005114: Categorical Exclusion Determination Fleming Substation Transformer Replacement, Fleming, Logan County, Colorado CX(s) Applied: B4.6 Date: 12202010...

198

CX-007883: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Determination CX-007883: Categorical Exclusion Determination SunShot Initiative: Rooftop Solar Challenge to Induce Market Transformation CX(s) Applied: A9, A11 Date: 01272012...

199

CX-007868: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Determination CX-007868: Categorical Exclusion Determination SunShot Initiative: Rooftop Solar Challenge to Induce Market Transformation CX(s) Applied: A9, A11 Date: 01272012...

200

2002 Workshop on Selective Catalytic Reduction  

Science Conference Proceedings (OSTI)

Approximately 100,000 MW of coal-fired generating capacity in the United States will be equipped with selective catalytic reduction (SCR) systems to meet the nitrogen oxides (NOx) limits of the state implementation plan (SIP) call. Approximately 20,000 MW of capacity was expected to go into operation in 2002. Added to early SCR adopters in prior years, about 25 percent of the planned inventory is presently operable. Since 1999, EPRI has organized annual SCR workshops to discuss key issues and development...

2003-01-30T23:59:59.000Z

Note: This page contains sample records for the topic "determination catalytic transformation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

2003 Workshop on Selective Catalytic Reduction  

Science Conference Proceedings (OSTI)

Approximately 105,000 MW of coal-fired generating capacity in the United States will be equipped with selective catalytic reduction (SCR) systems to meet the nitrogen oxide (NOx) limits of the state implementation plan (SIP). Power producers placed approximately 40,000 MW of capacity into operation in 2003. Combined with early SCR adopters from prior years, about 65 percent of the planned inventory is presently operable. Since 1999, EPRI has organized and held annual SCR workshops to discuss key issues a...

2004-02-09T23:59:59.000Z

202

Noble metal alkaline zeolites for catalytic reforming  

Science Conference Proceedings (OSTI)

This patent describes a method for producing a noble-metal containing zeolite suitable for catalytic reforming contacting a zeolite selected from alkaline faujasites and L zeolites and zeolites and zeolites isostructural thereto, with a noble-metal compound selected from Pt(acetylacetonate){sub 2} and Pd(acetylacetonate){sub 2} for a effective amount of time to incorporate Pt and/or Pd into the pore surface regions of the zeolite, but not to disperse the Pt and/or Pd throughout the entire zeolite; and calcining the so treated zeolite at a temperature from about 250 {degrees} C, to about 600 {degrees} C for an effective amount of time.

Schweizer, A.E.

1991-02-12T23:59:59.000Z

203

Catalytic multi-stage liquefaction (CMSL)  

DOE Green Energy (OSTI)

Under contract with the U.S. Department of Energy, Hydrocarbon Technologies, Inc. has conducted a series of eleven catalytic, multi-stage, liquefaction (CMSL) bench scale runs between February, 1991, and September, 1995. The purpose of these runs was to investigate novel approaches to liquefaction relating to feedstocks, hydrogen source, improved catalysts as well as processing variables, all of which are designed to lower the cost of producing coal-derived liquid products. This report summarizes the technical assessment of these runs, and in particular the evaluation of the economic impact of the results.

Comolli, A.G.; Ganguli, P.; Karolkiewicz, W.F.; Lee, T.L.K.; Pradhan, V.R.; Popper, G.A.; Smith, T.; Stalzer, R.

1996-11-01T23:59:59.000Z

204

Development of hollow-fiber catalytic-membrane reactors for high-temperature gas cleanup  

SciTech Connect

The project consist of the following main activities: (1) Design of catalytic hollow fiber membrane reactors. Single and multiple hollow-fiber membranes were studied in reactor/permeation cells made from stainless steel or quartz tubes. Modification of the hollow fiber membrane with catalysts was performed by aqueous impregnation, vapor deposition, and utilization of packed-bed reactors. (2) Investigation of gas separations and catalytic reactions in membrane reactors. Permeation of pure gases and gas mixtures was studied as a function of temperature. Pure component catalytic studies on the decomposition of H{sub 2}S was typically studied using 10% H{sub 2}S diluted in He. The H{sub 2}S and H{sub 2} concentrations were measured in both the tube and shell sides of the membrane reactor to determine the degree of chemical equilibrium shift. (3) Process development of the cleanup system using a simulated gas stream with a composition similar to that from an IGCC system. Catalytic studies using the IGCC gas composition will be performed according to the procedure used in the H{sub 2}S experiments. The conditions for optimum conversion in a gas mixture will be investigated.

Ma, Yi H.; Moser, M.R.; Pien, S.M.

1992-12-01T23:59:59.000Z

205

Development of hollow-fiber catalytic-membrane reactors for high-temperature gas cleanup  

SciTech Connect

The project consist of the following main activities: (1) Design of catalytic hollow fiber membrane reactors. Single and multiple hollow-fiber membranes were studied in reactor/permeation cells made from stainless steel or quartz tubes. Modification of the hollow fiber membrane with catalysts was performed by aqueous impregnation, vapor deposition, and utilization of packed-bed reactors. (2) Investigation of gas separations and catalytic reactions in membrane reactors. Permeation of pure gases and gas mixtures was studied as a function of temperature. Pure component catalytic studies on the decomposition of H[sub 2]S was typically studied using 10% H[sub 2]S diluted in He. The H[sub 2]S and H[sub 2] concentrations were measured in both the tube and shell sides of the membrane reactor to determine the degree of chemical equilibrium shift. (3) Process development of the cleanup system using a simulated gas stream with a composition similar to that from an IGCC system. Catalytic studies using the IGCC gas composition will be performed according to the procedure used in the H[sub 2]S experiments. The conditions for optimum conversion in a gas mixture will be investigated.

Ma, Yi H.; Moser, M.R.; Pien, S.M.

1992-01-01T23:59:59.000Z

206

Transformation inverse design  

E-Print Network (OSTI)

We present a new technique for the design of transformation-optics devices based on large-scale optimization to achieve the optimal effective isotropic dielectric materials within prescribed index bounds, which is ...

Liu, David

207

The Quantum Mellin transform  

E-Print Network (OSTI)

We uncover a new type of unitary operation for quantum mechanics on the half-line which yields a transformation to ``Hyperbolic phase space''. We show that this new unitary change of basis from the position x on the half line to the Hyperbolic momentum $p_\\eta$, transforms the wavefunction via a Mellin transform on to the critial line $s=1/2-ip_\\eta$. We utilise this new transform to find quantum wavefunctions whose Hyperbolic momentum representation approximate a class of higher transcendental functions, and in particular, approximate the Riemann Zeta function. We finally give possible physical realisations to perform an indirect measurement of the Hyperbolic momentum of a quantum system on the half-line.

J. Twamley; G. J. Milburn

2007-02-12T23:59:59.000Z

208

On Bianchi's Backlund transformation  

E-Print Network (OSTI)

We investigate basic features of Bianchi's B\\"acklund transformation of quadrics to see if it can be obtained under weaker assumptions and if it can be generalized to deformations of other surfaces.

Dinca, Ion

2011-01-01T23:59:59.000Z

209

Imaging Fourier transform spectrometer  

DOE Patents (OSTI)

This invention is comprised of an imaging Fourier transform spectrometer having a Fourier transform infrared spectrometer providing a series of images to a focal plane array camera. The focal plane array camera is clocked to a multiple of zero crossing occurrences as caused by a moving mirror of the Fourier transform infrared spectrometer and as detected by a laser detector such that the frame capture rate of the focal plane array camera corresponds to a multiple of the zero crossing rate of the Fourier transform infrared spectrometer. The images are transmitted to a computer for processing such that representations of the images as viewed in the light of an arbitrary spectral ``fingerprint`` pattern can be displayed on a monitor or otherwise stored and manipulated by the computer.

Bennett, C.L.

1993-09-13T23:59:59.000Z

210

Li?0? in Li-0? batteries : catalytic enhancement of electrochemical oxidation and thermophysical transformations  

E-Print Network (OSTI)

Electrification of transportation in the United States is of importance in reducing dependence on foreign oil and curtailing global warming. However, optimal market penetration of electric vehicles is confronted with the ...

Yao, Koffi Pierre (Koffi Pierre Claver)

2013-01-01T23:59:59.000Z

211

CATALYTIC CONVERSION OF SOLVENT REFINED COAL TO LIQUID PRODUCTS  

E-Print Network (OSTI)

and Friedman, S. ,"Conversion of Anthraxylon - Kinetics ofiv- LBL 116807 CATALYTIC CONVERSION OF SOLVENT REFINED COALand Mechanisms of Coal Conversion to Clean Fuel,iI pre-

Tanner, K.I.

2010-01-01T23:59:59.000Z

212

Catalytic conversion of cellulose to liquid hydrocarbon fuels ...  

Catalytic conversion of cellulose to liquid hydrocarbon fuels by progressive removal of oxygen to facilitate separation processes and achieve high selectivities

213

Revealing the rapid isothermal growth of graphene on catalytic...  

NLE Websites -- All DOE Office Websites (Extended Search)

Materials Synthesis from Atoms to Systems Revealing the rapid isothermal growth of graphene on catalytic substrates July 01, 2013 Optical reflectivity tracks the rapid growth of...

214

Hydrogen-assisted catalytic ignition characteristics of different fuels  

SciTech Connect

Hydrogen-assisted catalytic ignition characteristics of methane (CH{sub 4}), n-butane (n-C{sub 4}H{sub 10}) and dimethyl ether (DME) were studied experimentally in a Pt-coated monolith catalytic reactor. It is concluded that DME has the lowest catalytic ignition temperature and the least required H{sub 2} flow, while CH{sub 4} has the highest catalytic ignition temperature and the highest required H{sub 2} flow among the three fuels. (author)

Zhong, Bei-Jing; Yang, Fan [Key Laboratory for Thermal Science and Power Engineering of Ministry of Education, Department of Engineering Mechanics, Tsinghua University, Beijing 100084 (China); Yang, Qing-Tao [Key Laboratory for Thermal Science and Power Engineering of Ministry of Education, Department of Engineering Mechanics, Tsinghua University, Beijing 100084 (China); China Aerodynamics Research and Development Center, Mianyang 621000 (China)

2010-10-15T23:59:59.000Z

215

Piloted rich-catalytic lean-burn hybrid combustor  

DOE Patents (OSTI)

A catalytic combustor assembly which includes, an air source, a fuel delivery means, a catalytic reactor assembly, a mixing chamber, and a means for igniting a fuel/air mixture. The catalytic reactor assembly is in fluid communication with the air source and fuel delivery means and has a fuel/air plenum which is coated with a catalytic material. The fuel/air plenum has cooling air conduits passing therethrough which have an upstream end. The upstream end of the cooling conduits is in fluid communication with the air source but not the fuel delivery means.

Newburry, Donald Maurice (Orlando, FL)

2002-01-01T23:59:59.000Z

216

Multi-step catalytic hydroprocessing to produce hydrocarbon fuels ...  

Multi-step catalytic hydroprocessing to produce hydrocarbon fuels from biomass pyrolysis bio-oil (PNNL IPID 16665) Pacific Northwest National Laboratory

217

Catalytic distillation for the synthesis of tertiary butyl alcohol.  

E-Print Network (OSTI)

??Catalytic Distillation for the synthesis of tertiary butyl alcohol (TBA) is investigated in this thesis. The solvent, ethylene glycol, is proposed as a means of… (more)

Safinski, Tomasz

2005-01-01T23:59:59.000Z

218

Catalytic reforming and hydrocracking of organic compounds employing promoted zinc titanate as the catalytic agent  

Science Conference Proceedings (OSTI)

The catalytic reforming of a feedstock which contains at least one reformable organic compound or the hydrocracking of a feedstock which contains at least one hydrocrackable organic compound is carried out in the presence of a catalyst composition comprising zinc, titanium and rhenium.

Drehman, L.E.; Farha, F.E.

1981-04-21T23:59:59.000Z

219

Catalytic reforming and hydrocracking of organic compounds employing zinc titanate as the catalytic agent  

Science Conference Proceedings (OSTI)

The catalytic reforming of a feedstock which contains at least one reformable organic compound or the hydrocracking of a feedstock which contains at least one hydrocrackable organic compound is carried out in the presence of a catalyst composition comprising zinc and titanium.

Drehman, L.E.; Farha, F.E.; Walker, D.W.

1981-04-21T23:59:59.000Z

220

Series Transmission Line Transformer  

DOE Patents (OSTI)

A series transmission line transformer is set forth which includes two or more of impedance matched sets of at least two transmissions lines such as shielded cables, connected in parallel at one end ans series at the other in a cascading fashion. The cables are wound about a magnetic core. The series transmission line transformer (STLT) which can provide for higher impedance ratios and bandwidths, which is scalable, and which is of simpler design and construction.

Buckles, Robert A. (Livermore, CA); Booth, Rex (Livermore, CA); Yen, Boris T. (El Cerrito, CA)

2004-06-29T23:59:59.000Z

Note: This page contains sample records for the topic "determination catalytic transformation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

About three important transformations groups  

Science Conference Proceedings (OSTI)

In the present paper we introduce the concepts of conformal metrical d-structure and of conformal metrical N-linear connection with respect to the conformal metrical d-structure, corresponding to an 1-form on a generalized Hamilton space. We determine ... Keywords: N-linear connection, conformal metrical N-linear connection, conformal metrical d-structure, invariants, metrical N-linear connection, metrical d-structure, nonlinear connection, second order cotangent bundle, semisymmetric conformal metrical N-linear connection, subgroup, transformations group

Monica A. P. Purcaru; Mirela Târnoveanu; Laura Ciupal?

2010-09-01T23:59:59.000Z

222

Preconversion catalytic deoxygenation of phenolic functional groups. Quarterly technical progress report, April 1, 1991--June 30, 1991  

Science Conference Proceedings (OSTI)

The deoxygenation of phenols is a conceptually simple, but unusually difficult chemical transformation to achieve. Aryl carbon-oxygen bond cleavage is a chemical transformation of importance in coal liquefaction and the upgrading of coal liquids as well as in the synthesis of natural products. This proposed research offers the possibility of effecting the selective catalytic deoxygenation of phenolic functional groups using CO. A program of research for the catalytic deoxygenation of phenols, via a low energy mechanistic pathway that is based on the use of the CO/CO{sub 2} couple to remove phenolic oxygen atoms, is underway. We are focusing on systems which have significant promise as catalysts: Ir(triphos)OPh, [Pt(triphos)OPh]{sup +} and Rh(triphos)OPh. Our studies of phenol deoxygenation focus on monitoring the reactions for the elementary processes upon which catalytic activity will depend: CO insertion into M-OPh bonds, CO{sub 2} elimination from aryloxy carbonyls {l_brace}M-C(O)-O-Ph{r_brace}, followed by formation of a coordinated benzyne intermediate.

Kubiak, C.P.

1991-12-31T23:59:59.000Z

223

Synthesis and catalytic properties of metal and semiconductor nanoclusters  

SciTech Connect

Synthesis of metal or semiconductor nanoclusters in microheterogeneous oil-continuous inverse micelle systems is discussed. We focus on synthesis and catalytic properties of palladium, iron, and iron sulfide nanoclusters. Cluster size-control is achieved by changing the micelle size which is determined by small angle neutron scattering (SANS) and chosen to produce cluster in size range of 1-20 nm. Cluster sizes were determined by either transmission electron microscopy (TEM) or small-angle x-ray scattering (SAXS). Cluster structure was determined by either x-ray or electron diffraction. In the case of Fe nanoclusters the crystal structure depended on the chemical nature of the surfactant micelle used in the synthesis, illustrating the important role of the surfactant during the growth process. Results of in-situ pyrene hydrogenation using size-selected Pd clusters show a significant increase in activity/total surface area as the size decreases. These clusters also proved effective as unsupported catalysts for direct coal hydropyrolysis, even at very low metal concentrations. Synthesis and optical features of a new semiconductor cluster material, FeS{sub 2}, is discussed with regard to its use in photocatalysis. Application of FeS{sub 2} in coal hydrogenolysis reactions has improved yields of short chain hydrocarbons significantly compared to conventional FeS{sub 2} powders.

Wilcoxon, J.P.; Martino, T.; Klavetter, E.; Sylwester, A.P.

1993-08-01T23:59:59.000Z

224

Optical transformation from chirplet to fractional Fourier transformation kernel  

E-Print Network (OSTI)

We find a new integration transformation which can convert a chirplet function to fractional Fourier transformation kernel, this new transformation is invertible and obeys Parseval theorem. Under this transformation a new relationship between a phase space function and its Weyl-Wigner quantum correspondence operator is revealed.

Hong-yi Fan; Li-yun Hu

2009-02-11T23:59:59.000Z

225

Optical transformation from chirplet to fractional Fourier transformation kernel  

E-Print Network (OSTI)

We find a new integration transformation which can convert a chirplet function to fractional Fourier transformation kernel, this new transformation is invertible and obeys Parseval theorem. Under this transformation a new relationship between a phase space function and its Weyl-Wigner quantum correspondence operator is revealed.

Fan, Hong-yi

2009-01-01T23:59:59.000Z

226

Contact transformations for difference schemes  

E-Print Network (OSTI)

We define a class of transformations of the dependent and independent variables in an ordinary difference scheme. The transformations leave the solution set of the system invariant and reduces to a group of contact transformations in the continuous limit. We use a simple example to show that the class is not empty and that such "contact transformations for discrete systems" genuinely exist.

Levi, Decio; Winternitz, Pavel

2011-01-01T23:59:59.000Z

227

Catalytic cartridge SO.sub.3 decomposer  

DOE Patents (OSTI)

A catalytic cartridge surrounding a heat pipe driven by a heat source is utilized as a SO.sub.3 decomposer for thermochemical hydrogen production. The cartridge has two embodiments, a cross-flow cartridge and an axial flow cartridge. In the cross-flow cartridge, SO.sub.3 gas is flowed through a chamber and incident normally to a catalyst coated tube extending through the chamber, the catalyst coated tube surrounding the heat pipe. In the axial-flow cartridge, SO.sub.3 gas is flowed through the annular space between concentric inner and outer cylindrical walls, the inner cylindrical wall being coated by a catalyst and surrounding the heat pipe. The modular cartridge decomposer provides high thermal efficiency, high conversion efficiency, and increased safety.

Galloway, Terry R. (Berkeley, CA)

1982-01-01T23:59:59.000Z

228

Catalytic carbon membranes for hydrogen production  

DOE Green Energy (OSTI)

Commercial carbon composite microfiltration membranes may be modified for gas separation applications by providing a gas separation layer with pores in the 1- to 10-nm range. Several organic polymeric precursors and techniques for depositing a suitable layer were investigated in this project. The in situ polymerization technique was found to be the most promising, and pure component permeation tests with membrane samples prepared with this technique indicated Knudsen diffusion behavior. The gas separation factors obtained by mixed-gas permeation tests were found to depend strongly on gas temperature and pressure indicating significant viscous flow at high-pressure conditions. The modified membranes were used to carry out simultaneous water gas shift reaction and product hydrogen separation. These tests indicated increasing CO conversions with increasing hydrogen separation. A simple process model was developed to simulate a catalytic membrane reactor. A number of simulations were carried out to identify operating conditions leading to product hydrogen concentrations over 90 percent. (VC)

Damle, A.S.; Gangwal, S.K.

1992-01-01T23:59:59.000Z

229

Catalytic cartridge SO/sub 3/ decomposer  

DOE Patents (OSTI)

A catalytic cartridge surrounding a heat pipe driven by a heat source is utilized as a SO/sub 3/ decomposer for thermochemical hydrogen production. The cartridge has two embodiments, a cross-flow cartridge and an axial flow cartridge. In the cross-flow cartridge, SO/sub 3/ gas is flowed through a chamber and incident normally to a catalyst coated tube extending through the chamber, the catalyst coated tube surrounding the heat pipe. In the axial-flow cartridge, SO/sub 3/ gas is flowed through the annular space between concentric inner and outer cylindrical walls, the inner cylindrical wall being coated by a catalyst and surrounding the heat pipe. The modular cartridge decomposer provides high thermal efficiency, high conversion efficiency, and increased safety. A fusion reactor may be used as the heat source.

Galloway, T.R.

1980-11-18T23:59:59.000Z

230

Contact structure for use in catalytic distillation  

DOE Patents (OSTI)

A method and apparatus for conducting catalytic chemical reactions and fractionation of the reaction mixture, comprising and feeding reactants into a distillation column reactor contracting said reactant in a liquid phase with a fixed bed catalyst in the form of a contact catalyst structure, consisting of closed porous containers containing the catalyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column.

Jones, Jr., Edward M. (Friendswood, TX)

1985-01-01T23:59:59.000Z

231

Contact structure for use in catalytic distillation  

DOE Patents (OSTI)

A method is described for conducting catalytic chemical reactions and fractionation of the reaction mixture comprising feeding reactants into a distillation column reactor, contracting said reactant in liquid phase with a fixed bed catalyst in the form of a contact catalyst structure consisting of closed porous containers containing the catalyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column. 7 figs.

Jones, E.M. Jr.

1984-03-27T23:59:59.000Z

232

Contact structure for use in catalytic distillation  

DOE Patents (OSTI)

A method for conducting catalytic chemical reactions and fractionation of the reaction mixture comprising feeding reactants into a distillation column reactor contracting said reactant in liquid phase with a fixed bed catalyst in the form of a contact catalyst structure consisting of closed porous containers containing the catatlyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column.

Jones, Jr., Edward M. (Friendswood, TX)

1984-01-01T23:59:59.000Z

233

Contact structure for use in catalytic distillation  

DOE Patents (OSTI)

A method and apparatus are disclosed for conducting catalytic chemical reactions and fractionation of the reaction mixture, comprising and feeding reactants into a distillation column reactor contracting said reactant in a liquid phase with a fixed bed catalyst in the form of a contact catalyst structure, consisting of closed porous containers containing the catalyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column. 7 figs.

Jones, E.M. Jr.

1985-08-20T23:59:59.000Z

234

Simulation of catalytic oxidation and selective catalytic NOx reduction in lean-exhaust hybrid vehicles  

DOE Green Energy (OSTI)

We utilize physically-based models for diesel exhaust catalytic oxidation and urea-based selective catalytic NOx reduction to study their impact on drive cycle performance of hypothetical light-duty diesel powered hybrid vehicles. The models have been implemented as highly flexible SIMULINK block modules that can be used to study multiple engine-aftertreatment system configurations. The parameters of the NOx reduction model have been adjusted to reflect the characteristics of Cu-zeolite catalysts, which are of widespread current interest. We demonstrate application of these models using the Powertrain System Analysis Toolkit (PSAT) software for vehicle simulations, along with a previously published methodology that accounts for emissions and temperature transients in the engine exhaust. Our results illustrate the potential impact of DOC and SCR interactions for lean hybrid electric and plug-in hybrid electric vehicles.

Gao, Zhiming [ORNL; Daw, C Stuart [ORNL; Chakravarthy, Veerathu K [ORNL

2012-01-01T23:59:59.000Z

235

Partial core pulse transformer  

DOE Patents (OSTI)

A light-weight partial-core pule transformer is provided for generating high voltage output pulses with low distortion. The transformer includes sets of ferrite bars arranged so as to extend longitudinally along the inside and outside surfaces of a high frequency cylindrical coil winding-pair. The ferrite bars are arranged in pairs with the bars of each pair being located on opposite sides of winding-pair. The bars are preferably disposed in a radially symmetric arrangement around the winding-pair, and each has a length at least equal to the width of the winding-pair.

Lawson, R.N.; Rohwein, G.J.

1991-12-31T23:59:59.000Z

236

Model Transformations And Tool Integration  

E-Print Network (OSTI)

Model transformations are increasingly recognised as being of significant importance to many areas of software development and integration. Recent attention on model transformations has particularly focused on the OMG's Queries / Views / Transformations (QVT) Request for Proposals (RFP). In this paper I motivate the need for dedicated approaches to model transformations, particularly for the data involved in tool integration, outline the challenges involved, and then present a number of technologies and techniques which allow the construction of flexible, powerful and practical model transformations.

Laurence Tratt

2004-01-01T23:59:59.000Z

237

Coordinate transformations in quaternion spaces  

E-Print Network (OSTI)

The quaternion spaces can be used to describe the property of electromagnetic field and gravitational field. In the quaternion space, some coordinate transformations can be deduced from the feature of quaternions, including Lorentz transformation and Galilean transformation etc., when the coordinate system is transformed into others. And some coordinate transformations with variable speed of light can be obtained in the electromagnetic field and gravitational field.

Zihua Weng

2008-08-31T23:59:59.000Z

238

Heat storage in alloy transformations. Final report  

DOE Green Energy (OSTI)

A study conducted to determine the feasibility of using metal alloys as thermal energy storage media is described. The study had the following major elements: (1) the identification of congruently transforming alloys and thermochemical property measurements, (2) the development of a precise and convenient method for measuring volume change during phase transformation and thermal expansion coefficients, (3) the development of a numerical modeling routine for calculating heat flow in cylindrical heat exchangers containing phase-change materials, and (4) the identification of materials that could be used to contain the metal alloys. The elements selected as candidate media were limited to aluminum, copper, magnesium, silicon, zinc, calcium, and phosphorus on the basis of low cost and latent heat of transformation. Several new eutectic alloys and ternary intermetallic phases have been determined. A new method employing x-ray absorption techniques was developed to determine the coefficients of thermal expansion of both the solid and liquid phases and the volume change during phase transformation from data that are obtained during one continuous experimental test. The method and apparatus are discussed and the experimental results are presented. The development of the numerical modeling method is presented and results are discussed for both salt and metal alloy phase-change media. Candidate materials were evaluated to determine suitable materials for containment of the metal alloys. Graphite was used to contain the alloys during the volume change measurements. Silicon carbide has been identified as a promising containment material and surface-coated iron alloys were considered.

Birchenall, C E; Gueceri, S I; Farkas, D; Labdon, M B; Nagaswami, N; Pregger, B

1981-03-01T23:59:59.000Z

239

Economics of methanol and SNG production from biomass via catalytic gasification  

Science Conference Proceedings (OSTI)

The steam gasification of wood in the presence of catalysts was studied to determine the technical feasibility of the process to produce specific products and to evaluate the economics of the technical feasible processes. From the results of bench-scale and process development unit (PDU) studies, the production of MeOH and CH4 (SNG) from wood via catalytic gasification is technically feasible. The PDU was operated to obtain data for the design of gasifiers. The cost of MeOH from wood is competitive with the current price of MeOH from natural gas. The cost of SNG from wood is competitive with projected future prices of natural gas. Some advantage of the catalytic steam gasification of biomass over steam-O gasification are discussed.

Mudge, L.K.; Robertus, R.J.; Mitchell, D.H.; Sealock, L.J. Jr.; Weber, S.L.

1981-01-01T23:59:59.000Z

240

Power Transformer Failure Investigation and Root Cause Analysis  

Science Conference Proceedings (OSTI)

This report provides practical, step-by-step guidance to help utility personnel gather evidence and perform investigations on failed or retired high-voltage substation power transformers to assist in determining the cause of the transformer failure or the service condition of retired units.

2011-12-21T23:59:59.000Z

Note: This page contains sample records for the topic "determination catalytic transformation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Power Transformer Failure Investigation and Root Cause Analysis  

Science Conference Proceedings (OSTI)

This report provides practical, step-by-step guidance to help utility personnel gather evidence and perform investigations on failed or retired high-voltage substation power transformers to assist in determining the cause of the transformer failure or the service condition of retired units.

2010-12-23T23:59:59.000Z

242

Effects of low-temperature catalytic pretreatments on coal structure and reactivity in liquefaction  

Science Conference Proceedings (OSTI)

Low-temperature catalytic pretreatment is a promising approach to the development of an improved liquefaction process- This work is a fundamental study on effects of pretreatments on coal structure and reactivity in liquefaction. The main objectives of this project are to study the coal structural changes induced by low-temperature catalytic and thermal pretreatments by using spectroscopic techniques; and to clarify the pretreatment-induced changes in reactivity or convertibility of coals in the subsequent liquefaction. This report describes the recent progress of our work. Substantial progress has been made in the spectroscopic characterization of structure and pretreatment-liquefaction reactions of a Montana subbituminous Coal (DECS-9), and thermochemical analysis of three mw and reacted bituminous coals. Temperature programmed liquefaction has been performed on three low-rank coals both in the presence and absence of dispersed molybdenum sulfide catalyst. We also performed a detailed study of the effects of mild thermal pretreatment -- drying in air and in vacuum -- on thermal and catalytic liquefaction of a Wyodak subbituminous coal. Important information on structure and structure transformation during thermal pretreatment and liquefaction reactions of low-rank coals has been derived by applying solid-state CPMAS [sup 13]C NMR and flash pyrolysis-GC-MS (Py-GC-MS) for characterization of the macromolecular network of a Montana subbituminous coal and its residues from temperature-programmed and nonprogrammed liquefaction (TPL and N-PL) at final temperatures ranging from 300 to 425[degree]C in H-donor and non-donor solvents. The results revealed that this coal contains significant quantities of oxygen-bearing structures, corresponding to about 18 O-bound C per 100 C atoms and one O-bound C per every 5 to 6 aromatic C.

Song, C.; Saini, A.K.; Huang, L.; Wenzel, K.; Hou, L.; Hatcher, P.G.; Schobert, H.H.

1992-08-01T23:59:59.000Z

243

Algorithms for transform selection in multiple-transform video compression  

E-Print Network (OSTI)

Selecting proper transforms for video compression has been based on the rate-distortion criterion. Transforms that appear reasonable are incorporated into a video coding system and their performance is evaluated. This ...

Cai, Xun, S.M. Massachusetts Institute of Technology

2012-01-01T23:59:59.000Z

244

Synergize fuel and petrochemical processing plans with catalytic reforming  

Science Conference Proceedings (OSTI)

Depending on the market, refiner`s plans to produce clean fuels and higher value petrochemicals will weigh heavily on the catalytic reformer`s flexibility. It seems that as soon as a timely article related to catalytic reforming operations is published, a new {open_quotes}boutique{close_quotes} gasoline fuel specification is slapped on to existing fuel standards, affecting reformer operations and processing objectives. Just as importantly, the petrochemical market (such as aromatics) that refiners are targeting, can be very fickle. That`s why process engineers have endeavored to maintain an awareness of the flexibility that technology suppliers are building into modern catalytic reformers.

NONE

1997-03-01T23:59:59.000Z

245

Optimizing Power Using Transformations  

E-Print Network (OSTI)

: The increasing demand for portable computing has elevated power consumption to be one of the most critical design parameters. A high-level synthesis system, HYPER-LP, is presented for minimizing power consumption in application specific datapath intensive CMOS circuits using a variety of architectural and computational transformations. The synthesis environment consists of high-level estimation of power consumption, a library of transformation primitives, and heuristic/probabilistic optimization search mechanisms for fast and efficient scanning of the design space. Examples with varying degree of computational complexity and structures are optimized and synthesized using the HYPER-LP system. The results indicate that more than an order of magnitude reduction in power can be achieved over current-day design methodologies while maintaining the system throughput; in some cases this can be accomplished while preserving or reducing the implementation area. 1.0 Introduction VLSI research a...

Anantha P. Chandrakasan; Miodrag Potkonjak; Renu Mehra; Jan Rabaey; Robert W. Brodersen

1995-01-01T23:59:59.000Z

246

EPRI Intelligent Universal Transformer  

Science Conference Proceedings (OSTI)

The vision of the EPRI ADA Program (Program 124) is to create the technology basis for the distribution system of the future by transforming traditional single-function distribution systems into multifunctional power and information exchange systems with increased reliability, improved performance (lower system losses), better economics, better power quality, and more customer service options. Achieving this vision will require capturing the benefits of new capabilities in power electronics, information ...

2006-12-18T23:59:59.000Z

247

Grid Transformation Workshop Results  

Science Conference Proceedings (OSTI)

In an earlier white paper entitled Needed: A Grid Operating System to Facilitate Grid Transformation; EPRI; Palo Alto, CA: 2011; 1023223, we set the stage for a new grid operating system called Grid 3.0. Since that time we have identified four core research areas that are required to achieve the expected outcome. These research areas are called: seamless geospatial power system model, seamless power system analytics, integrated energy management system and setting-less protection method. While each area ...

2012-05-08T23:59:59.000Z

248

Mercury Oxidation via Catalytic Barrier Filters Phase II  

SciTech Connect

In 2004, the Department of Energy National Energy Technology Laboratory awarded the University of North Dakota a Phase II University Coal Research grant to explore the feasibility of using barrier filters coated with a catalyst to oxidize elemental mercury in coal combustion flue gas streams. Oxidized mercury is substantially easier to remove than elemental mercury. If successful, this technique has the potential to substantially reduce mercury control costs for those installations that already utilize baghouse barrier filters for particulate removal. Completed in 2004, Phase I of this project successfully met its objectives of screening and assessing the possible feasibility of using catalyst coated barrier filters for the oxidation of vapor phase elemental mercury in coal combustion generated flue gas streams. Completed in September 2007, Phase II of this project successfully met its three objectives. First, an effective coating method for a catalytic barrier filter was found. Second, the effects of a simulated flue gas on the catalysts in a bench-scale reactor were determined. Finally, the performance of the best catalyst was assessed using real flue gas generated by a 19 kW research combustor firing each of three separate coal types.

Wayne Seames; Michael Mann; Darrin Muggli; Jason Hrdlicka; Carol Horabik

2007-09-30T23:59:59.000Z

249

Catalytic Hydroprocessing of Chemical Models for Bio-oil  

Science Conference Proceedings (OSTI)

Bio-oil (product liquids from fast pyrolysis of biomass) is a complex mixture of oxygenates derived from the thermal breakdown of the bio-polymers in biomass. In the case of lignocellulosic biomass, the structures of three major components, cellulose, hemicellulose and lignin, are well represented by the bio-oil components. In order to study the chemical mechanisms of catalytic hydroprocessing of bio-oil, three model compounds were chosen to represent those components. Guaiacol represents the large number of mono- and di-methoxy phenols found in bio-oil derived from softwood or hardwood, respectively. Furfural represents a major pyrolysis product group from cellulosics. Acetic acid is a major product from biomass pyrolysis, derived from the hemicellulose, which has important impacts on the further processing of the bio-oil because of the acidic character. These three compounds were processed using palladium or ruthenium catalyst over a temperature range from 150?C to 300?C. The batch reactor was sampled during each test over a period of four hours. The samples were analyzed by gas chromatography with both a mass selective detector and a flame ionization detector. The products were determined and the reaction pathways for their formation are suggested based on these results. Both temperature and catalyst metal have significant effects on the product composition.

Elliott, Douglas C.; Hart, Todd R.

2009-02-20T23:59:59.000Z

250

Catalytic Reactor For Oxidizing Mercury Vapor  

DOE Patents (OSTI)

A catalytic reactor (10) for oxidizing elemental mercury contained in flue gas is provided. The catalyst reactor (10) comprises within a flue gas conduit a perforated corona discharge plate (30a, b) having a plurality of through openings (33) and a plurality of projecting corona discharge electrodes (31); a perforated electrode plate (40a, b, c) having a plurality of through openings (43) axially aligned with the through openings (33) of the perforated corona discharge plate (30a, b) displaced from and opposing the tips of the corona discharge electrodes (31); and a catalyst member (60a, b, c, d) overlaying that face of the perforated electrode plate (40a, b, c) opposing the tips of the corona discharge electrodes (31). A uniformly distributed corona discharge plasma (1000) is intermittently generated between the plurality of corona discharge electrode tips (31) and the catalyst member (60a, b, c, d) when a stream of flue gas is passed through the conduit. During those periods when corona discharge (1000) is not being generated, the catalyst molecules of the catalyst member (60a, b, c, d) adsorb mercury vapor contained in the passing flue gas. During those periods when corona discharge (1000) is being generated, ions and active radicals contained in the generated corona discharge plasma (1000) desorb the mercury from the catalyst molecules of the catalyst member (60a, b, c, d), oxidizing the mercury in virtually simultaneous manner. The desorption process regenerates and activates the catalyst member molecules.

Helfritch, Dennis J. (Baltimore, MD)

1998-07-28T23:59:59.000Z

251

Development of high temperature catalytic membrane reactors  

DOE Green Energy (OSTI)

Significant progress was made in 1991 on the development of ceramic membranes as catalytic reactors. Efforts were focused on the design, construction and startup of a reactor system capable of duplicating relevant commercial operating conditions. With this system, yield enhancement was demonstrated for the dehydrogenation of ethylbenzene to styrene in a membrane reactor compared to the standard packed bed configuration. This enhancement came with no loss in styrene selectivity. During operation, coke deposition on the membrane was observed, but this deposition was mitigated by the presence of steam in the reaction mixture and a steady state permeability was achieved for run times in excess of 200 hours. Work began on optimizing the membrane reactor by exploring several parameters including the effect of N{sub 2} diluent in the reaction feed and the effect of a N{sub 2} purge on the permeate side of the membrane. This report details the experimental progress made in 1991. Interactions with the University of Wisconsin on this project are also summarized. Finally, current status of the project and next steps are outlined.

Not Available

1992-02-01T23:59:59.000Z

252

Catalytic oxidative pyrolysis of liquid fuels  

Science Conference Proceedings (OSTI)

The oxidative pyrolysis of n-heptane was investigated with metal oxides Cr/sub 2/O/sub 3/, MnO/sub 2/, Fe/sub 2/O/sub 3/, NiO, Co/sub 3/O/sub 4/, and CuO supported on alumina. Metallic content of the catalyst weight varied from 0.1 to 2.0% with catalytic activity reaching a maximum when the metal content was 1%. The most active catalysts were Co/sub 3/O/sub 4/, MnO/sub 2/, and NiO. Pyrolysis of cyclohexane and toluene was also studied with Co/sub 3/O/sub 4/-Al/sub 2/O/sub 3/ as catalyst. Hydrocarbon stability and coke formation increase with increase of hydrocarbon condensation in the series paraffin < naphthalene < aromatic hydrocarbons. Pyrolysis of the various hydrocarbons at 800/sup 0/C yielded a gas that has an octane number of 90 to 93, and the process was shown to be adaptable to pyrolysis of various commercial fractions such as benzines A-72 and A-76, petroleum fractions, and liquid paraffins to produce gas of about the same octane. (BLM)

Antonova, V.M.; Gorlov, E.G.; Paushkin, Ya.M.

1981-01-01T23:59:59.000Z

253

Catalytic Preparation of Pyrrolidones from Renewable Resources  

SciTech Connect

Use of renewable resources for production of valuable chemical commodities is becoming a topic of great national interest and importance. This objective fits well with the USDOE’s objective of promoting the industrial bio-refinery concept in which a wide array of valuable chemical, fuel, food, nutraceuticals and animal feed products all result from the integrated processing of grains, oil seeds and other bio-mass materials. The bio-refinery thus serves to enhance the overall utility and profitability of the agriculture industry as well as helping to reduce the dependence on petroleum. Pyrrolidones fit well with the bio-refinery concept since they may be produced in a scheme beginning with the fermentation of a portion of the bio-refinery’s sugar product into succinate. Pyrrolidones are a class of industrially important chemicals with a variety of uses including as polymer intermediates, cleaners, and “green solvents” which can replace hazardous chlorinated compounds. Battelle has developed an efficient process for the thermo – catalytic conversion of succinate into pyrrolidones, especially n-methylpyrrolidone. The process uses both novel Rh based catalysts and novel aqueous process conditions and results in high selectivities and yields of pyrrolidone compounds. The process also includes novel methodology for enhancing yields by recycling and converting non-useful side products of the catalysis into additional pyrrolidone. The process has been demonstrated in both batch and continuous reactors. Additionally, stability of the unique Rh-based catalyst has been demonstrated.

Frye, John G.; Zacher, Alan H.; Werpy, Todd A.; Wang, Yong

2005-12-01T23:59:59.000Z

254

Catalytic Preparation of Pyrrolidones from Renewable Resources  

SciTech Connect

Abstract Use of renewable resources for production of valuable chemical commodities is becoming a topic of great national interest and importance. This objective fits well with the U.S. DOE’s objective of promoting the industrial bio-refinery concept in which a wide array of valuable chemical, fuel, food, nutraceuticals, and animal feed products all result from the integrated processing of grains, oil seeds, and other bio-mass materials. The bio-refinery thus serves to enhance the overall utility and profitability of the agriculture industry as well as helping to reduce the USA’s dependence on petroleum. Pyrrolidones fit well into the bio-refinery concept since they may be produced in a scheme beginning with the fermentation of a portion of the bio-refinery’s sugar product into succinate. Pyrrolidones are a class of industrially important chemicals with a variety of uses including polymer intermediates, cleaners, and “green solvents” which can replace hazardous chlorinated compounds. Battelle has developed an efficient process for the thermo-catalytic conversion of succinate into pyrrolidones, especially n-methyl-2-pyrrolidone. The process uses both novel Rh based catalysts and novel aqueous process conditions and results in high selectivities and yields of pyrrolidone compounds. The process also includes novel methodology for enhancing yields by recycling and converting non-useful side products of the catalysis into additional pyrrolidone. The process has been demonstrated in both batch and continuous reactors. Additionally, stability of the unique Rh-based catalyst has been demonstrated.

Frye, John G.; Zacher, Alan H.; Werpy, Todd A.; Wang, Yong

2005-06-01T23:59:59.000Z

255

Catalytic pyrolysis using UZM-39 aluminosilicate zeolite  

Science Conference Proceedings (OSTI)

A new family of coherently grown composites of TUN and IMF zeotypes has been synthesized and show to be effective catalysts for catalytic pyrolysis of biomass. These zeolites are represented by the empirical formula. Na.sub.nM.sub.m.sup.n+R.sub.rQ.sub.qAl.sub1-xE.sub.xSi.sub.yO.s- ub.z where M represents zinc or a metal or metals from Group 1, Group 2, Group 3 or the lanthanide series of the periodic table, R is an A,.OMEGA.-dihalosubstituted paraffin such as 1,4-dibromobutane, Q is a neutral amine containing 5 or fewer carbon atoms such as 1-methylpyrrolidine and E is a framework element such as gallium. The process involves contacting a carbonaceous biomass feedstock with UZM-39 at pyrolysis conditions to produce pyrolysis gases comprising hydrocarbons. The catalyst catalyzes a deoxygenation reaction converting oxygenated hyrdocarbons into hydrocarbons removing the oxygen as carbon oxides and water. A portion of the pyrolysis gases is condensed to produce low oxygen biomass-derived pyrolysis oil.

Nicholas, Christpher P; Boldingh, Edwin P

2013-12-17T23:59:59.000Z

256

Catalytic partial oxidation reforming of hydrocarbon fuels.  

DOE Green Energy (OSTI)

The polymer electrolyte fuel cell (PEFC) is the primary candidate as the power source for light-duty transportation systems. On-board conversion of fuels (reforming) to supply the required hydrogen has the potential to provide the driving range that is typical of today's automobiles. Petroleum-derived fuels, gasoline or some distillate similar to it, are attractive because of their existing production, distribution, and retailing infrastructure. The fuel may be either petroleum-derived or other alternative fuels such as methanol, ethanol, natural gas, etc. [1]. The ability to use a variety of fuels is also attractive for stationary distributed power generation [2], such as in buildings, or for portable power in remote locations. Argonne National Laboratory has developed a catalytic reactor based on partial oxidation reforming that is suitable for use in light-duty vehicles powered by fuel cells. The reactor has shown the ability to convert a wide variety of fuels to a hydrogen-rich gas at less than 800 C, temperatures that are several hundreds of degrees lower than alternative noncatalytic processes. The fuel may be methanol, ethanol, natural gas, or petroleum-derived fuels that are blends of various hydrocarbons such as paraffins, olefins, aromatics, etc., as in gasoline. This paper will discuss the results obtained from a bench-scale (3-kWe) reactor., where the reforming of gasoline and natural gas generated a product gas that contained 38% and 42% hydrogen on a dry basis at the reformer exit, respectively.

Ahmed, S.

1998-09-21T23:59:59.000Z

257

Microchannel Reactor System for Catalytic Hydrogenation  

Science Conference Proceedings (OSTI)

We successfully demonstrated a novel process intensification concept enabled by the development of microchannel reactors, for energy efficient catalytic hydrogenation reactions at moderate temperature, and pressure, and low solvent levels. We designed, fabricated, evaluated, and optimized a laboratory-scale microchannel reactor system for hydrogenation of onitroanisole and a proprietary BMS molecule. In the second phase of the program, as a prelude to full-scale commercialization, we designed and developed a fully-automated skid-mounted multichannel microreactor pilot plant system for multiphase reactions. The system is capable of processing 1 – 10 kg/h of liquid substrate, and an industrially relevant immiscible liquid-liquid was successfully demonstrated on the system. Our microreactor-based pilot plant is one-of-akind. We anticipate that this process intensification concept, if successfully demonstrated, will provide a paradigm-changing basis for replacing existing energy inefficient, cost ineffective, environmentally detrimental slurry semi-batch reactor-based manufacturing practiced in the pharmaceutical and fine chemicals industries.

Adeniyi Lawal; Woo Lee; Ron Besser; Donald Kientzler; Luke Achenie

2010-12-22T23:59:59.000Z

258

Rainfall Analysis by Power Transformation  

Science Conference Proceedings (OSTI)

Power transformation was used to normalize the peak daily and peak monthly rainfall at various raingage stations in Iraq. Excellent correlations were found between the coefficient of skewness (Cs) and a parameter for power transformation (?), ...

Hameed Rasheed; A. S. Aldabagh; Murur V. Ramamoorthy

1983-08-01T23:59:59.000Z

259

Yeo-Johnson Power Transformations  

E-Print Network (OSTI)

This paper describes an Arc add-in for using the Yeo-Johnson power transformations in place of the Box-Cox power transformations in various places in Arc. 1

Sanford Weisberg

2001-01-01T23:59:59.000Z

260

In situ XAS Characterization of Catalytic Nano-Materials with...  

NLE Websites -- All DOE Office Websites (Extended Search)

XAS Characterization of Catalytic Nano-Materials with Applications to Fuel Cells and Batteries Friday, July 12, 2013 - 11:00am SLAC, Conference Room 137-322 Presented by Qingying...

Note: This page contains sample records for the topic "determination catalytic transformation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Hydrogen permeable protective coating for a catalytic surface  

DOE Patents (OSTI)

A protective coating for a surface comprising a layer permeable to hydrogen, said coating being deposited on a catalyst layer; wherein the catalytic activity of the catalyst layer is preserved.

Liu, Ping (Irvine, CA); Tracy, C. Edwin (Golen, CO); Pitts, J. Roland (Lakewood, CO); Lee, Se-Hee (Lakewood, CO)

2007-06-19T23:59:59.000Z

262

Contact Transformations and Hamiltonian Dynamics in Generalized Semigeostrophic Theories  

Science Conference Proceedings (OSTI)

This paper is concerned with the fundamental role played by contact transformations and their corresponding generating functions in determining the structure and dynamical properties of a very general class of semigeostrophic theories possessing ...

R. J. Purser

1993-06-01T23:59:59.000Z

263

Remarks on restricted Nevanlinna transforms  

E-Print Network (OSTI)

The Nevanlinna transform K(z), of a measure and a real constant, plays an important role in the complex analysis and more recently in the free probability theory (boolean convolution). It is shown that its restriction k(it) (the restricted Nevanlinna transform) to the imaginary axis can be expressed as the Laplace transform of the Fourier transform (characteristic function) of the corresponding measure. Finally, a relation between the Voiculescu and the boolean convolution is indicated.

Jankowski, Lech

2010-01-01T23:59:59.000Z

264

Phase Transformation and Microstructural Evolution  

Science Conference Proceedings (OSTI)

Jul 15, 2013 ... Relationship between Microstructural Evolution, Order-disorder Transformation and Plastic Inhomogeneities during Deformation of Beta Brass.

265

Remarks on the conformal transformations  

E-Print Network (OSTI)

Conformal transformations are obtained by demanding that the form of the metric change by a conformal factor. Nevertheless, this transformation of the metric is not taken into account when a variation of the action is performed. The basic purpose of this paper is to take the transformation of the metric into the variation of the action. When this is done, we obtain now that even massive particles are invariant under the conformal transformations.

L. C. T. Guillen

2004-08-10T23:59:59.000Z

266

Remarks on the conformal transformations  

E-Print Network (OSTI)

Conformal transformations are obtained by demanding that the form of the metric change by a conformal factor. Nevertheless, this transformation of the metric is not taken into account when a variation of the action is performed. The basic purpose of this paper is to take the transformation of the metric into the variation of the action. When this is done, we obtain now that even massive particles are invariant under the conformal transformations.

Guillen, L C T

2004-01-01T23:59:59.000Z

267

Applying a Model Transformation Taxonomy to Graph Transformation Technology  

E-Print Network (OSTI)

A taxonomy of model transformations was introduced in [16]. Among others, such a taxonomy can help developers in deciding which language, forma lism, tool or mechanism is best suited to carry out a particular model transformation activity. In this paper we apply the taxonomy to the technique of graph transformation, and we exemplify it by referring to four representative graph transformation tools. As a byproduct of our analysis, we discuss how well each of the considered tools carry out the activity of model transformation.

Tom Mens; Pieter Van Gorp; Dániel Varró; Gabor Karsai

2005-01-01T23:59:59.000Z

268

Generalized Transforms and Special Functions  

E-Print Network (OSTI)

We study the properties of different type of transforms by means of operational methods and discuss the relevant interplay with many families of special functions. We consider in particular the binomial transform and its generalizations. A general method, based on the use of the Fourier transform technique, is proposed for the study of the properties of functions of operators.

G. Dattoli; E. Sabia

2010-10-08T23:59:59.000Z

269

A taxonomy of model transformation  

E-Print Network (OSTI)

This report summarises the results of the discussions of a working group on model transformation of the Dagstuhl Seminar on Language Engineering for Model-Driven Software Development. The main contribution is a taxonomy of model transformation. This taxonomy can be used to help developers in deciding which model transformation approach is best suited to deal with a particular problem.

Tom Mens; Krzysztof Czarnecki; Pieter Van Gorp

2005-01-01T23:59:59.000Z

270

Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway  

DOE Green Energy (OSTI)

This technology pathway case investigates the catalytic conversion of solubilized carbohydrate streams to hydrocarbon biofuels, utilizing data from recent efforts within the National Advanced Biofuels Consortium (NABC) in collaboration with Virent, Inc. Technical barriers and key research needs that should be pursued for the catalytic conversion of sugars pathway to be competitive with petroleum-derived gasoline-, diesel-, and jet-range hydrocarbon blendstocks have been identified.

Biddy, M.; Jones, S.

2013-03-01T23:59:59.000Z

271

Operation and Maintenance Guidelines for Selective Catalytic Reduction Systems  

Science Conference Proceedings (OSTI)

This document is the 2009 update to Operation and Maintenance Guidelines for Selective Catalytic Reduction Systems, originally published in 2001. The landscape of selective catalytic reduction (SCR) technology has significantly changed since then and promises to continue to change in the coming years. Specifically, the number of SCR applications on coal-fired units has increased considerably beyond the 15 units operating in mid 2001. Approximately 120 GW of capacity are expected to utilize SCR for NOx co...

2009-12-17T23:59:59.000Z

272

Operation and Maintenance Guidelines for Selective Catalytic Reduction Systems  

Science Conference Proceedings (OSTI)

Timely and proper execution of operation and maintenance (O&M) activities may be a key factor in ensuring the successful function of selective catalytic reduction (SCR) systems. This report serves as the 2012 update of EPRI’s Operation and Maintenance Guidelines for Selective Catalytic Reduction Systems, originally published in 2001 and updated annually. New and revised content this year includes: 1) recent developments in in situ NOx analyzers, including a ...

2012-12-05T23:59:59.000Z

273

Operation and Maintenance Guidelines for Selective Catalytic Reduction Systems  

Science Conference Proceedings (OSTI)

This report is the 2011 update of Operation and Maintenance Guidelines for Selective Catalytic Reduction Systems, originally published in 2001 and updated annually. New and revised content this year includes: (1) an analysis of the performance of the U.S. fleet of selective catalytic reduction (SCR)equipped generating units in 2009, 2010, and 2011; (2) a discussion of experience in mitigating the role of arsenic in catalyst deactivation, including the addition of alkali material to the coal; (3) an updat...

2011-12-16T23:59:59.000Z

274

Wavelet transform and Radon transform on the Quaternion Heisenberg group  

E-Print Network (OSTI)

Let $\\mathscr Q$ be the quaternion Heisenberg group, and let $\\mathbf P$ be the affine automorphism group of $\\mathscr Q$. We develop the theory of continuous wavelet transform on the quaternion Heisenberg group via the unitary representations of $\\mathbf P$ on $L^2(\\mathscr Q)$. A class of radial wavelets is constructed. The inverse wavelet transform is simplified by using radial wavelets. Then we investigate the Radon transform on $\\mathscr Q$. A Semyanistri-Lizorkin space is introduced, on which the Radon transform is a bijection. We deal with the Radon transform on $\\mathscr Q$ both by the Euclidean Fourier transform and the group Fourier transform. These two treatments are essentially equivalent. We also give an inversion formula by using wavelets, which does not require the smoothness of functions if the wavelet is smooth.

He, JIanxun

2011-01-01T23:59:59.000Z

275

Catalytic Reforming Downstream Processing of Fresh Feed Input  

U.S. Energy Information Administration (EIA) Indexed Site

Process: Catalytic Reforming Catalytic Cracking Catalytic Hydrocracking Delayed and Fluid Coking Period-Unit: Monthly-Thousand Barrels per Day Annual-Thousand Barrels per Day Process: Catalytic Reforming Catalytic Cracking Catalytic Hydrocracking Delayed and Fluid Coking Period-Unit: Monthly-Thousand Barrels per Day Annual-Thousand Barrels per Day Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Process Area Apr-13 May-13 Jun-13 Jul-13 Aug-13 Sep-13 View History U.S. 2,563 2,667 2,739 2,807 2,705 2,609 2010-2013 PADD 1 176 178 180 173 156 167 2010-2013 East Coast 166 164 163 161 140 153 2010-2013 Appalachian No. 1 9 14 16 12 15 14 2010-2013 PADD 2 642 638 668 695 677 615 2010-2013 Ind., Ill. and Ky. 426 411 426 460 450 399 2010-2013 Minn., Wis., N. Dak., S. Dak. 67 62 70 72 72 57 2010-2013 Okla., Kans., Mo.

276

Nonrelativistic conformal transformations in Lagrangian formalism  

E-Print Network (OSTI)

The conformal transformations corresponding to $N$-Galilean conformal symmetries, previously defined as canonical symmetry transformations on phase space, are constructed as point transformations in coordinate space.

Andrzejewski, K; Kijanka-Dec, A

2013-01-01T23:59:59.000Z

277

Non-catalytic steam hydrolysis of fats  

SciTech Connect

Hydrolysis of fats and oils produces fatty acid and glycerol. The catalyzed, liquid phase Colgate-Emry process, state-of-the-art, produces impure products that require extensive energy investment for their purification to commercial grade. Non-catalytic steam hydrolysis may produce products more easily purified. A bench-scale hydrolyzer was designed and constructed to contact descending liquid fat or oil with rising superheated steam. Each of the five stages in the reactor was designed similar to a distillation column stage to promote intimate liquid-gas contact. Degree of hydrolysis achieved in continuous tests using tallow feed were 15% at 280C and 35% at 300C at a tallow-to-steam mass feed ratio of 4.2. At a feed ratio of 9.2, the degree of hydrolysis was 21% at 300C. Decomposition was strongly evident at 325C but not at lower temperatures. Soybean oil rapidly polymerized under reaction conditions. Batch tests at 320C produced degrees of hydrolyses of between 44% and 63% using tallow and palm oil feeds. Over 95% fatty acids were present in a clean, readily separated organic portion of the overhead product from most tests. The test reactor had serious hydraulic resistance to liquid down-flow which limited operation to very long liquid residence times. These times are in excess of those that tallow and palm oil are stable at the reaction temperature. Little glycerol and extensive light organics were produced indicating that unexplained competing reactions to hydrolysis occurred in the experimental system. Further tests using an improved reactor will be required.

Deibert, M.C.

1992-08-28T23:59:59.000Z

278

Model catalytic studies of single crystal, polycrystalline metal, and supported catalysts  

E-Print Network (OSTI)

This dissertation is focused on understanding the structure-activity relationship in heterogeneous catalysis by studying model catalytic systems. The catalytic oxidation of CO was chosen as a model reaction for studies on a variety of catalysts. A series of Au/TiO2 catalysts were prepared from various metalorganic gold complexes. The catalytic activity and the particle size of the gold catalysts were strongly dependent on the gold complexes. The Au/TiO2 catalyst prepared from a tetranuclear gold complex showed the best performance for CO oxidation, and the average gold particle size of this catalyst was 3.1 nm. CO oxidation was also studied over Au/MgO catalysts, where the MgO supports were annealed to various temperatures between 900 and 1300 K prior to deposition of Au. A correlation was found between the activity of Au clusters for the catalytic oxidation of CO and the F-center concentration in the MgO support. In addition, the catalytic oxidation of CO was studied in a batch reactor over supported Pd/Al2O3 catalysts, a Pd(100) single crystal, as well as polycrystalline metals of rhodium, palladium, and platinum. A hyperactive state, corresponding to an oxygen covered surface, was observed at high O2/CO ratios at elevated pressures. The reaction rate at this state was significantly higher than that on CO-covered surfaces at stoichiometric conditions. The oxygen chemical potential required to achieve the hyperactive state depends on the intrinsic properties of the metal, the particle size, and the reaction temperature. A well-ordered ultra-thin titanium oxide film was synthesized on the Mo(112) surface as a model catalyst support. Two methods were used to prepare this Mo(112)- (8x2)-TiOx film, including direct growth on Mo(112) and indirect growth by deposition of Ti onto monolayer SiO2/Mo(112). The latter method was more reproducible with respect to film quality as determined by low-energy electron diffraction and scanning tunneling microscopy. The thickness of this TiOx film was one monolayer and the oxidation state of Ti was +3 as determined by Auger spectroscopy, high-resolution electron energy loss spectroscopy, and X-ray photoelectron spectroscopy.

Yan, Zhen

2007-12-01T23:59:59.000Z

279

A Bijective String Sorting Transform  

E-Print Network (OSTI)

Given a string of characters, the Burrows-Wheeler Transform rearranges the characters in it so as to produce another string of the same length which is more amenable to compression techniques such as move to front, run-length encoding, and entropy encoders. We present a variant of the transform which gives rise to similar or better compression value, but, unlike the original, the transform we present is bijective, in that the inverse transformation exists for all strings. Our experiments indicate that using our variant of the transform gives rise to better compression ratio than the original Burrows-Wheeler transform. We also show that both the transform and its inverse can be computed in linear time and consuming linear storage.

Gil, Joseph Yossi

2012-01-01T23:59:59.000Z

280

Lorentz transformations: Einstein's derivation simplified  

E-Print Network (OSTI)

We show that the Lorentz transformations for the space-time coordinates of the same event are a direct consequence of the principle of relativity and of Einstein's distant clocks synchronization procedure. In our approach, imposing the linear character of the Lorentz transformations we guess that the transformation equation for the space coordinate has the form x=ax'+cbt'. Imposing the condition that it accounts for the time dilation relativistic effect and taking into account the fact that due to the clock synchronization a la Einstein the space-time coordinates of the same event in the two frames are related by x=ct and x'=ct', we find out expressions for a and b. Dividing the transformation equation for the space coordinate by c we obtain the transformation equation for the time coordinate t=at'+b/cx'. Combining the two transformation equations we obtain directly the inverse Lorentz transformations.

Bernhard Rothenstein; Stefan Popescu

2007-02-19T23:59:59.000Z

Note: This page contains sample records for the topic "determination catalytic transformation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

CX-008826: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Categorical Exclusion Determination Remanufacture, Transport, and Install BHTX-29 Transformer CX(s) Applied: B1.3 Date: 07172012 Location(s): Texas Offices(s): Strategic...

282

CX-003062: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Exclusion Determination Recovery Act-Fault Current Limiting Superconducting Transformer CX(s) Applied: A11, B3.6 Date: 07162010 Location(s): Schenectady, New York...

283

CX-010741: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

CX-010741: Categorical Exclusion Determination Smart Market Advance Retrofit Transformer Program (SMART Scale) CX(s) Applied: A9, B5.1 Date: 08092013 Location(s):...

284

CX-000554: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

CX-000554: Categorical Exclusion Determination Ogallala Substation KY1A Transformer Replacement CX(s) Applied: B4.6 Date: 11162009 Location(s): Ogallala, Nebraska...

285

CX-007686: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

CX-007686: Categorical Exclusion Determination Michigan State University - Transformer-less Unified Power Flow Controller for Wind and Solar Power Transmission CX(s)...

286

CX-009224: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

CX-009224: Categorical Exclusion Determination Project L-718, Electrical Utilities Transformer Management Support Facility CX(s) Applied: B1.15 Date: 09042012 Location(s):...

287

Categorical Exclusion Determinations: Advanced Research Projects...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

5, 2011 CX-007686: Categorical Exclusion Determination Michigan State University - Transformer-less Unified Power Flow Controller for Wind and Solar Power Transmission CX(s)...

288

CX-001667: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Exclusion Determination Market Transformation and Technology Deployment - Renewable Energy Projects (Batesville) CX(s) Applied: B5.1 Date: 04222010 Location(s): Batesville,...

289

CX-001665: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Exclusion Determination Market Transformation and Technology Deployment - Renewable Energy Projects (Pickens) CX(s) Applied: B5.1 Date: 04222010 Location(s): Pickens,...

290

CX-002795: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Exclusion Determination Market Transformation and Technology Deployment - Renewable Energy Projects CX(s) Applied: B5.1 Date: 06252010 Location(s): Perkinston, Mississippi...

291

CX-000778: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Exclusion Determination Market Transformation and Technology Deployment - Renewable Energy Projects CX(s) Applied: A9, A11, B5.1 Date: 02052010 Location(s): Mississippi...

292

CX-001660: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Exclusion Determination Market Transformation and Technology Deployment - Renewable Energy Projects (Perkinston) CX(s) Applied: B5.1 Date: 04222010 Location(s): Perkinston,...

293

CX-003811: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Determination Sara Lee, Market Transformation and Technology Deployment- Renewable Energy Projects CX(s) Applied: B5.1 Date: 09142010 Location(s): Meridian, Mississippi...

294

CX-007877: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Categorical Exclusion Determination Rooftop Solar Challenge: Inducing Photovoltaic Market Transformation in Tennessee CX(s) Applied: A9, A11 Date: 01272012 Location(s):...

295

Transformer requirements for the year 2000. Final report, December 1979  

Science Conference Proceedings (OSTI)

The principal objective of this program was to determine the design parameters required for transformers of the year 2000. The approach to meeting this objective was to determine the changes which may occur in transmission and distribution systems over the next twenty years, and how these changes might affect design parameters of distribution and power transformers. Emphasis was placed on domestic requirements, although the impact of international practices was factored into the overall requirements for transformers. Possible investigations that could help transformer designers meet the long term technical requirements of future transformers were also identified. The principal conclusions of this study were: 1200 kV transmission could be in service by the late 1980's and it is essential to develop 1200 kV transformers for these systems; transformer manufacturers must be prepared to supply higher MVA ratings at all voltage levels; there will be a strong demand for low-loss, minimum cost transformers; and environmental/safety, reliability, and size reduction considerations will increase in importance. (LLL)

Not Available

1980-06-01T23:59:59.000Z

296

Fast Fourier transform telescope  

Science Conference Proceedings (OSTI)

We propose an all-digital telescope for 21 cm tomography, which combines key advantages of both single dishes and interferometers. The electric field is digitized by antennas on a rectangular grid, after which a series of fast Fourier transforms recovers simultaneous multifrequency images of up to half the sky. Thanks to Moore's law, the bandwidth up to which this is feasible has now reached about 1 GHz, and will likely continue doubling every couple of years. The main advantages over a single dish telescope are cost and orders of magnitude larger field-of-view, translating into dramatically better sensitivity for large-area surveys. The key advantages over traditional interferometers are cost (the correlator computational cost for an N-element array scales as Nlog{sub 2}N rather than N{sup 2}) and a compact synthesized beam. We argue that 21 cm tomography could be an ideal first application of a very large fast Fourier transform telescope, which would provide both massive sensitivity improvements per dollar and mitigate the off-beam point source foreground problem with its clean beam. Another potentially interesting application is cosmic microwave background polarization.

Tegmark, Max; Zaldarriaga, Matias [Department of Physics and MIT Kavli Institute, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States); Center for Astrophysics, Harvard University, Cambridge, Massachusetts 02138 (United States)

2009-04-15T23:59:59.000Z

297

LU transformation invariant operators and LU transformation invariant  

E-Print Network (OSTI)

We proposed a concept of LU transformation invariant operators. By using this operator, arbitrary multi-qubit states LU transformation invariant and SLOCC invariant could be easily obtained. And we find that presences two kinds of invariant operators and corresponding invariants. One kind of operators yields LU invariants and the other operators results in SLOCC invariants. For three-qubit states, all independence LU transformation invariant are obtained. Furthermore, by this system method, arbitrary multi-qubit states invariants can be given.

Xin-wei Zha; Chun-min Zhang

2007-02-06T23:59:59.000Z

298

The Investigation of Newly Designed Transformer Windings with Reduced Thickness of Oil-Impregnated Paper Insulation.  

E-Print Network (OSTI)

??For determining the insulation dimensions, Smit Transformers uses a so called “design curve”. As the oil-impregnated paper insulation of the windings has been improved, a… (more)

Singuran, A.I.

2012-01-01T23:59:59.000Z

299

Ultra Low NOx Catalytic Combustion for IGCC Power Plants  

DOE Green Energy (OSTI)

In order to meet DOE's goals of developing low-emissions coal-based power systems, PCI has further developed and adapted it's Rich-Catalytic Lean-burn (RCL{reg_sign}) catalytic reactor to a combustion system operating on syngas as a fuel. The technology offers ultra-low emissions without the cost of exhaust after-treatment, with high efficiency (avoidance of after-treatment losses and reduced diluent requirements), and with catalytically stabilized combustion which extends the lower Btu limit for syngas operation. Tests were performed in PCI's sub-scale high-pressure (10 atm) test rig, using a two-stage (catalytic then gas-phase) combustion process for syngas fuel. In this process, the first stage consists of a fuel-rich mixture reacting on a catalyst with final and excess combustion air used to cool the catalyst. The second stage is a gas-phase combustor, where the air used for cooling the catalyst mixes with the catalytic reactor effluent to provide for final gas-phase burnout and dilution to fuel-lean combustion products. During testing, operating with a simulated Tampa Electric's Polk Power Station syngas, the NOx emissions program goal of less than 0.03 lbs/MMBtu (6 ppm at 15% O{sub 2}) was met. NOx emissions were generally near 0.01 lbs/MMBtu (2 ppm at 15% O{sub 2}) (PCI's target) over a range on engine firing temperatures. In addition, low emissions were shown for alternative fuels including high hydrogen content refinery fuel gas and low BTU content Blast Furnace Gas (BFG). For the refinery fuel gas increased resistance to combustor flashback was achieved through preferential consumption of hydrogen in the catalytic bed. In the case of BFG, stable combustion for fuels as low as 88 BTU/ft{sup 3} was established and maintained without the need for using co-firing. This was achieved based on the upstream catalytic reaction delivering a hotter (and thus more reactive) product to the flame zone. The PCI catalytic reactor was also shown to be active in ammonia reduction in fuel allowing potential reductions in the burner NOx production. These reductions of NOx emissions and expanded alternative fuel capability make the rich catalytic combustor uniquely situated to provide reductions in capital costs through elimination of requirements for SCR, operating costs through reduction in need for NOx abating dilution, SCR operating costs, and need for co-firing fuels allowing use of lower value but more available fuels, and efficiency of an engine through reduction in dilution flows.

Shahrokh Etemad; Benjamin Baird; Sandeep Alavandi; William Pfefferle

2008-03-31T23:59:59.000Z

300

Definition: Transformer | Open Energy Information  

Open Energy Info (EERE)

Transformer Transformer Jump to: navigation, search Dictionary.png Transformer An electromagnetic device that changes the voltage of alternating current electricity.[1] View on Wikipedia Wikipedia Definition View on Reegle Reegle Definition A transformer consists of a primary- and secondary coil, coupled by a magnetic field. The primary coil induces the voltage in the secondary coil. The voltage transformation depends on the number of windings. Related Terms Electricity, Transmission, Electric grid, transmission lines, electricity generation, transmission line, alternating current References ↑ http://www1.eere.energy.gov/site_administration/glossary.html#T Retrieved LikeLike UnlikeLike You like this.Sign Up to see what your friends like. from "http://en.openei.org/w/index.php?title=Definition:Transformer&oldid=502565

Note: This page contains sample records for the topic "determination catalytic transformation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

On-line transformer monitoring  

Science Conference Proceedings (OSTI)

There are presently many different approaches to transformer monitoring, either on the market or under development. There are also, many different opinions about how on-line monitoring should be accomplished. On the one hand, efforts are being made to develop expert systems that monitor all transformer parameters and generate an estimate of overall transformer condition. On the other hand, a large number of transformer monitors, designed to monitor one or two specific parameters are already on the market. Another important factor to consider in choosing a monitor is who receives the information and how it is transmitted. The ultimate transformer monitor should feed into the supervisory control and data acquisition (Scada) system. This paper discusses the various aspects of this issue including asset protection, cost control, dissolved gases, pinpointing bad bushings and current transformers, hot spot measurement partial discharge, and water-in-oil measurements. 10 figs.

NONE

1995-10-01T23:59:59.000Z

302

CATALYTIC GASIFICATION OF COAL USING EUTECTIC SALT MIXTURES  

Science Conference Proceedings (OSTI)

The Gas Research Institute (GRI) estimates that by the year 2010, 40% or more of U.S. gas supply will be provided by supplements including substitute natural gas (SNG) from coal. These supplements must be cost competitive with other energy sources. The first generation technologies for coal gasification e.g. the Lurgi Pressure Gasification Process and the relatively newer technologies e.g. the KBW (Westinghouse) Ash Agglomerating Fluidized-Bed, U-Gas Ash Agglomerating Fluidized-Bed, British Gas Corporation/Lurgi Slagging Gasifier, Texaco Moving-Bed Gasifier, and Dow and Shell Gasification Processes, have several disadvantages. These disadvantages include high severities of gasification conditions, low methane production, high oxygen consumption, inability to handle caking coals, and unattractive economics. Another problem encountered in catalytic coal gasification is deactivation of hydroxide forms of alkali and alkaline earth metal catalysts by oxides of carbon (CO{sub x}). To seek solutions to these problems, a team consisting of Clark Atlanta University (CAU, a Historically Black College and University, HBCU), the University of Tennessee Space Institute (UTSI) and Georgia Institute of Technology (Georgia Tech) proposed to identify suitable low melting eutectic salt mixtures for improved coal gasification. The research objectives of this project were to: Identify appropriate eutectic salt mixture catalysts for coal gasification; Assess agglomeration tendency of catalyzed coal; Evaluate various catalyst impregnation techniques to improve initial catalyst dispersion; Determine catalyst dispersion at high carbon conversion levels; Evaluate effects of major process variables (such as temperature, system pressure, etc.) on coal gasification; Evaluate the recovery, regeneration and recycle of the spent catalysts; and Conduct an analysis and modeling of the gasification process to provide better understanding of the fundamental mechanisms and kinetics of the process.

Dr. Yaw D. Yeboah; Dr. Yong Xu; Dr. Atul Sheth; Dr. Pradeep Agrawal

2001-12-01T23:59:59.000Z

303

Investigation into the effect of transformer oil on polymers  

Science Conference Proceedings (OSTI)

Several thermoplastics and an epoxy were exposed to a variety of conditions to determine the effect of chemical environment on the materials. Weight gain measurements of the samples were made after exposure to low humidity, ambient air, 90 C air, ambient transformer oil, and 90 C transformer oil. Two materials that performed well in these tests were polyetherimide (Ultem) and amine cured bisphenol-A epoxy. It was found that Noryl, a thermoplastic combination of high impact polystyrene and polyphenyleneoxide, was unsuitable for use in transformer oil, as it suffered substantial physical degradation. Polystyrene and high impact polystyrene (rubber modified polystyrene) performed poorly in both ambient and 90{degree} transformer oil tests, with the rubber modified material exhibiting a much greater weight gain. Both high and low density polyethylene also showed large weight gains in hot transformer oil.

Frost, N.E.; McGrath, P.B. [Clarkson Univ., Potsdam, NY (United States); Burns, C.W. [Niagara Mohawk Power Corp., Syracuse, NY (United States)

1996-01-01T23:59:59.000Z

304

Gassing of Transformers: An Update  

Science Conference Proceedings (OSTI)

Transformers rarely, if ever, operate under equilibrium conditions; rather, they exist in a dynamic state where decomposition products migrate among various phases, including headspace (when present), oil, and solid insulation. Detailed knowledge of these parameters is needed for accurately interpreting fault gas analysis and for continuous transformer condition monitoring. This report describes work to date on laboratory experiments using test chambers to simulate transformer conditions under various dy...

2001-11-26T23:59:59.000Z

305

Transformer Population Model With Testing  

Science Conference Proceedings (OSTI)

EPRI's asset management research focuses on developing a rational basis for selecting repair or replacement options for specific classes of equipment by balancing the risks of equipment failure against the costs of continued maintenance or capital replacement. This Model User Guide is a companion to Transformer Asset Management and Testing Methodology, EPRI, Palo Alto, CA: 2006. 1012504, which discusses methods for making decisions about transformers, and It explicitly models transformer degradation, ins...

2006-12-05T23:59:59.000Z

306

Phase Transformation and Microstructural Evolution  

Science Conference Proceedings (OSTI)

Jul 31, 2012 ... Yunzhi Wang, Ohio State University. Scope, Phase transformation is still one of the most effective and efficient means to produce desired ...

307

EPRI Transformer Task Force Proceedings  

Science Conference Proceedings (OSTI)

The EPRI Transformer Task Force held a meeting on December 4, 2007, in San Antonio, Texas. This technical update contains the proceedings of the meeting.

2008-02-12T23:59:59.000Z

308

EPRI Transformer Task Force Proceedings  

Science Conference Proceedings (OSTI)

This report contains the proceedings from the EPRI Transformers Task Force, which was held in Montreal on October 26 and 27, 2006.

2006-12-12T23:59:59.000Z

309

Transformations of hypergeometric elliptic integrals  

E-Print Network (OSTI)

The paper classifies algebraic transformations of Gauss hypergeometric functions with the local exponent differences $(1/2,1/4,1/4)$, $(1/2,1/3,1/6)$ and $(1/3,1/3,1/3)$. These form a special class of algebraic transformations of Gauss hypergeometric functions, of arbitrary high degree. The Gauss hypergeometric functions can be identified as elliptic integrals on the genus 1 curves $y=x^3-x$ or $y=x^3-1$. Especially interesting are algebraic transformations of the hypergeometric functions into themselves; these transformations come from isogenies of the respective elliptic curves.

Vidunas, Raimundas

2008-01-01T23:59:59.000Z

310

An investigation of Lorentz transformation  

E-Print Network (OSTI)

A new method of derivation of Lorentz Transformation (LT) is given based on both axioms of special relativity (SR) and physical intuitions. The essence of the transformation is established and the crucial role played by the presumptions is presented for clarification. I consider the most general form of transformations between two sets of events in two inertial reference frames and use the most basic properties expected from such a transformation together with the principle of the constancy of the velocity of light to derive LT. The method is very simple, succinct and useful for students trying a better understanding of the subject.

Farid Shahandeh

2013-04-13T23:59:59.000Z

311

FOURIER TRANSFORM MULTIPLE QUANTUM NMR  

E-Print Network (OSTI)

TRANSFORM MULTIPLE QUANTUM NMR G. Drobny, A. Pines, S.TRANSFO~~ MULTIPLE QUANTUM NMR G. Drobny, A. Pines, S.

Drobny, G.

2011-01-01T23:59:59.000Z

312

Effect of surface structure on catalytic reactions: A sum frequency generation surface vibrational spectroscopy study  

DOE Green Energy (OSTI)

In the results discussed above, it is clear that Sum Frequency Generation (SFG) is a unique tool that allows the detection of vibrational spectra of adsorbed molecules present on single crystal surfaces under catalytic reaction conditions. Not only is it possible to detect active surface intermediates, it is also possible to detect spectator species which are not responsible for the measured turnover rates. By correlating high-pressure SFG spectra under reaction conditions and gas chromatography (GC) kinetic data, it is possible to determine which species are important under reaction intermediates. Because of the flexibility of this technique for studying surface intermediates, it is possible to determine how the structures of single crystal surfaces affect the observed rates of catalytic reactions. As an example of a structure insensitive reaction, ethylene hydrogenation was explored on both Pt(111) and Pt(100). The rates were determined to be essentially the same. It was observed that both ethylidyne and di-{sigma} bonded ethylene were present on the surface under reaction conditions on both crystals, although in different concentrations. This result shows that these two species are not responsible for the measured turnover rate, as it would be expected that one of the two crystals would be more active than the other, since the concentration of the surface intermediate would be different on the two crystals. The most likely active intermediates are weakly adsorbed molecules such as {pi}-bonded ethylene and ethyl. These species are not easily detected because their concentration lies at the detection limit of SFG. The SFG spectra and GC data essentially show that ethylene hydrogenation is structure insensitive for Pt(111) and Pt(100). SFG has proven to be a unique and excellent technique for studying adsorbed species on single crystal surfaces under high-pressure catalytic reactions. Coupled with kinetic data obtained from gas chromatography measurements, it can give much insight into how the structure of a single crystal surface affects the chemistry of a catalytic reaction by detecting surface species under reaction conditions.

McCrea, Keith R.

2001-09-07T23:59:59.000Z

313

DOE - Office of Legacy Management -- Catalytic Co - PA 40  

NLE Websites -- All DOE Office Websites (Extended Search)

Catalytic Co - PA 40 Catalytic Co - PA 40 FUSRAP Considered Sites Site: Catalytic Co. (PA.40 ) Eliminated from further consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: Philadelphia , Pennsylvania PA.40-1 Evaluation Year: 1991 PA.40-1 Site Operations: Prime contractor for construction of the Fernald facility. Records indicate one time shipment of a very small quantity (4 lbs) of uranium metal to this site. PA.40-1 Site Disposition: Eliminated - Construction contractor - Potential for residual contamination from the very small quantity of uranium shipped to this site is considered remote PA.40-2 Radioactive Materials Handled: None - as a construction contractor Primary Radioactive Materials Handled: Uranium Metal - Believed to be a Souvenier. PA.40-1

314

Business Transformation Workbench: A Practitioner's Tool for Business Transformation  

Science Conference Proceedings (OSTI)

Business transformation is a key management initiative that attempts to align people, process and technology of an enterprise more closely with its business strategy and vision. It is an essential part of the competitive business cycle. Existing consulting ... Keywords: business transformation, business process models, software tools

Juhnyoung Lee; Rama Akkiraju; Chun Hua Tian; Shun Jiang; Sivaprashanth Danturthy; Ponn Sundhararajan; Carl Nordman; Rakesh Mohan; Hitansh Singala; Wei Ding

2008-07-01T23:59:59.000Z

315

Effects of Chlorine and Other Flue Gas Parameters on Selective Catalytic Reduction Technology for Mercury Oxidation and Capture  

Science Conference Proceedings (OSTI)

Selective Catalytic Reduction (SCR) technologythe technology of choice for meeting stringent nitrogen oxides (NOx) emission limits for coal-fired electric generating plantshas potential for oxidizing mercury, which would provide enhanced removal in downstream systems. Catalyst behavior is relatively well understood for deNOx and SO2 oxidation, but less is known about mercury oxidation behavior. This test program was designed to determine general behavior of typical SCR catalysts on mercury oxidation and ...

2009-12-21T23:59:59.000Z

316

Catalytic Cracking of Gaseous Heavy Hydrocarbons by Ceramic Filters  

DOE Green Energy (OSTI)

The use of syngas from waste or biomass gasification to generate electricity is a way which is attracting increasing attention especially with regard to the demands of regenerable energy consumption and to the reduction of waste disposal. In order to feed the syngas to a gas motor or a gas turbine the gas has to be cleaned. In future also the coupling of biomass gasification with a fuel cell will be applied, which needs a very efficient gas cleaning. The decomposition of tars and the removal of particles from the gas are the key issues of gas cleaning. Up to now these two steps are performed in two separate units. Normally, the tars are decomposed in catalytic beds or honeycomb structures. The catalytic decomposition is achieved at temperatures between 750 C and 900 C depending on the catalyst used. Particles are removed by filtration of the hot gas. Filtration at high temperatures and with high efficiencies is possible when using ceramic filter elements. Ceramic hot gas filters are well established in advanced coal gasification, such as the integrated gasification combined cycle process, as well as in waste and biomass gasification and pyrolysis processes. Since the catalytic reaction requires high temperatures the gas has to be reheated after the particles are removed in the filter or the hot unfiltered gas has to flow through the catalytic unit. If the gas is filtered first, reheating of the gas stream is an additional cost factor. Furthermore, pipes downstream of the filter can be plugged, if the temperature of the gas falls below the condensation temperature of the heavy hydrocarbons. Using the second way of hot unfiltered gas flows through the catalytic unit, there is the problem of deactivation of the catalyst by deposition of dust at higher dust concentrations. At worst the catalytic unit can be plugged by dust deposition.

Heidenreich, S.; Nacken, M.; Walch, A.; Chudzinski, S.

2002-09-19T23:59:59.000Z

317

Optimum catalytic process for alcohol fuels from syngas  

DOE Green Energy (OSTI)

The objectives of this contract are to discover and evaluate the catalytic properties of novel homogeneous, heterogeneous, or combination catalytic systems for the production of alcohol fuel extenders from syngas, to evaluate analytically and on the bench scale novel reactor concepts for use in converting syngas to liquid fuel products, and to develop on the bench scale the best combination of chemistry, reactor, and total process configuration to achieve the minimum product cost for conversion of syngas to liquid fuel products. Methanol production and heterogeneous catalysis utilizing transition elements supported on metal oxides with spinel structure are discussed. 12 figs., 16 tabs.

Not Available

1990-04-28T23:59:59.000Z

318

New process model proves accurate in tests on catalytic reformer  

Science Conference Proceedings (OSTI)

A mathematical model has been devised to represent the process that takes place in a fixed-bed, tubular, adiabatic catalytic reforming reactor. Since its development, the model has been applied to the simulation of a commercial semiregenerative reformer. The development of mass and energy balances for this reformer led to a model that predicts both concentration and temperature profiles along the reactor. A comparison of the model's results with experimental data illustrates its accuracy at predicting product profiles. Simple steps show how the model can be applied to simulate any fixed-bed catalytic reformer.

Aguilar-Rodriguez, E.; Ancheyta-Juarez, J. (Inst. Mexicano del Petroleo, Mexico City (Mexico))

1994-07-25T23:59:59.000Z

319

Definition: Line Transformer Monitors | Open Energy Information  

Open Energy Info (EERE)

Transformer Monitors Transformer Monitors Jump to: navigation, search Dictionary.png Line Transformer Monitors Transformer Monitoring System can monitor different aspects of transformers, including oil levels and multiple temperatures within the transformer. This allows for analysis of the health of either individual key power transformers or multiple power transformers networked in the system. For example, the transformer monitors provide transformer oil dissolved gas analysis (DGA), oil temperature, ambient temperature, and moisture in oil measurements. These measurements are made in relation to transformer load.[1] Related Terms transformer, system, transformer References ↑ https://www.smartgrid.gov/category/technology/line_transformer_monitors [[Cat LikeLike UnlikeLike You like this.Sign Up to see what your friends like.

320

Trace metal transformation in gasification  

SciTech Connect

The Energy & Environmental Research Center (EERC) is carrying out an investigation that will provide methods to predict the fate of selected trace elements in integrated gasification combined cycle (IGCC) and integrated gasification fuel cell (IGFC) systems to aid in the development of methods to control the emission of trace elements determined to be air toxics. The goal of this project is to identify the effects of critical chemical and physical transformations associated with trace element behavior in IGCC and IGFC systems. The trace elements included in this project are arsenic, chromium, cadmium, mercury, nickel, selenium, and lead. The research seeks to identify and fill, experimentally and/or theoretically, data gaps that currently exist on the fate and composition of trace elements. The specific objectives are to 1) review the existing literature to identify the type and quantity of trace elements from coal gasification systems, 2) perform laboratory-scale experimentation and computer modeling to enable prediction of trace element emissions, and 3) identify methods to control trace element emissions.

Benson, S.A.; Erickson, T.A.; Zygarlicke, C.J.; O`Keefe, C.A.; Katrinak, K.A.; Allen, S.E.; Hassett, D.J.; Hauserman, W.B. [North Dakota Univ., Grand Forks, ND (United States). Energy and Environmental Research Center; Holcombe, N.T. [USDOE Morgantown Energy Technology Center, WV (United States)

1996-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "determination catalytic transformation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Trace metal transformations in gasification  

SciTech Connect

The Energy & Environmental Research Center (EERC) is carrying out an investigation that will provide methods to predict the fate of selected trace elements in integrated gasification combined cycle (IGCC) and integrated gasification fuel cell (IGFC) systems to aid in the development of methods to control the emission of trace elements determined to be air toxics. The goal of this project is to identify the effects of critical chemical and physical transformations associated with trace element behavior in IGCC and IGFC systems. The trace elements included in this project are arsenic, chromium, cadmium, mercury, nickel, selenium, and lead. The research seeks to identify and fill, experimentally and/or theoretically, data gaps that currently exist on the fate and composition of trace elements. The specific objectives are to (1) review the existing literature to identify the type and quantity of trace elements from coal gasification systems, (2) perform laboratory-scale experimentation and computer modeling to enable prediction of trace element emissions, and (3) identify methods to control trace element emissions.

Benson, S.; Erickson, T.A.; Zygarlicke, C.J. [and others

1995-12-01T23:59:59.000Z

322

Diagnostics Techniques of Power Transformer  

Science Conference Proceedings (OSTI)

This paper provides the information on the diagnostics techniques for condition monitoring of power transformer (PT). This paper deals with the practical importance of the transformer diagnostic in the Electrical Engineering field. A review has been ... Keywords: temperature, condition monitoring, diagnostics methods, paper analysis techniques, oil analysis techniques

Piush Verma; Y. R. Sood; Jashandeep Singh

2009-12-01T23:59:59.000Z

323

Graph Transformations in Relational Databases  

E-Print Network (OSTI)

The theory of graph transformation [2] was originally developed as a generalization of Chomsky grammars from strings to graphs. Methods, techniques, and tools from the area of graph transformations have already been studied and applied in many fields of computer science such as formal language theory, pattern recognition and generation, compiler construction, software engineering, etc. Despite the large variety of existing graph transformation tools, the implementation of their graph transformation engine typically follows the same principle. In this respect, first a matching occurrence of the left-hand side (LHS) of the graph transformation rule is being found by some sophisticated graph pattern matching algorithm. Then the engine performs some local modifications to add or remove graph elements to the matching pattern, and the entire process starts all over again. Since graph pattern matching leads to the subgraph isomorphism problem that is known to be NPcomplete in general, this step is considered to be the most crucial in the overall performance of a graph transformation engine. Current tools (e.g., PROGRES [4]) use different efficient strategies for the graph pattern matching phase. However, I argue that the overall complexity of a graph transformation engine is not necessarily equal to the complexity of the graph pattern matching phase, especially for long transformation sequences.

Gergely Varró

2004-01-01T23:59:59.000Z

324

Novel Fast Pyrolysis/Catalytic Technology for the Production of Stable Upgraded Liquids  

SciTech Connect

The objective of the proposed research is the demonstration and development of a novel biomass pyrolysis technology for the production of a stable bio-oil. The approach is to carry out catalytic hydrodeoxygenation (HDO) and upgrading together with pyrolysis in a single fluidized bed reactor with a unique two-level design that permits the physical separation of the two processes. The hydrogen required for the HDO will be generated in the catalytic section by the water-gas shift reaction employing recycled CO produced from the pyrolysis reaction itself. Thus, the use of a reactive recycle stream is another innovation in this technology. The catalysts will be designed in collaboration with BASF Catalysts LLC (formerly Engelhard Corporation), a leader in the manufacture of attrition-resistant cracking catalysts. The proposed work will include reactor modeling with state-of-the-art computational fluid dynamics in a supercomputer, and advanced kinetic analysis for optimization of bio-oil production. The stability of the bio-oil will be determined by viscosity, oxygen content, and acidity determinations in real and accelerated measurements. A multi-faceted team has been assembled to handle laboratory demonstration studies and computational analysis for optimization and scaleup.

Ted Oyama, Foster Agblevor, Francine Battaglia, Michael Klein

2013-01-18T23:59:59.000Z

325

Contamination of the transformer oil of power transformers and shunting reactors by metal-containing colloidal particles  

SciTech Connect

The results of a measurement of the contamination of the oil in 66 transformers by metal-containing colloidal particles, formed as a result of the interaction of the oil with the structural materials (the copper of the windings, the iron of the tank and core etc.), and also the results of measurements of the optical turbidity of the oil in 136 transformers when they were examined at the Power Engineering Research and Development Center Company are presented. Methods of determining the concentration of copper and iron in transformer oil are considered. The limiting values of the optical turbidity factors, the copper and iron content are determined. These can serve as a basis for taking decisions on whether to replace the silica gel of the filters for continuously purifying the oil of power transformers and the shunting reactors in addition to the standardized oil contamination factors, namely, the dielectric loss tangent and the acidity number of the oil.

L'vov, S. Yu. [LLC 'Presselektro' (Russian Federation); Komarov, V. B.; Bondareva, V. N.; Seliverstov, A. F. [A. N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences (IFCE of RAS) (Russian Federation); Lyut'ko, E. O.; L'vov, Yu. N. [JSC 'R and D Centre for Power Engineering' (Russian Federation); Ershov, B. G. [A. N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences (IFCE of RAS) (Russian Federation)

2011-05-15T23:59:59.000Z

326

Categorical Exclusion Determinations: Kentucky | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Kentucky Kentucky Categorical Exclusion Determinations: Kentucky Location Categorical Exclusion Determinations issued for actions in Kentucky. DOCUMENTS AVAILABLE FOR DOWNLOAD September 23, 2013 CX-010919: Categorical Exclusion Determination Advanced Catalytic Solvent for Carbon Dioxide (CO2) Capture CX(s) Applied: B3.6 Date: 09/23/2013 Location(s): Kentucky Offices(s): National Energy Technology Laboratory September 23, 2013 CX-010921: Categorical Exclusion Determination Advanced Catalytic Solvent for Carbon Dioxide (CO2) Capture CX(s) Applied: A9 Date: 09/23/2013 Location(s): Kentucky Offices(s): National Energy Technology Laboratory July 25, 2013 CX-010606: Categorical Exclusion Determination Development of Subsurface Brine Disposal Framework in the Northern Appalachian Basin

327

CX-001058: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Categorical Exclusion Determination CX-001058: Categorical Exclusion Determination Data Center Transformation from Always-On to Always-Available CX(s) Applied: A9, B3.6, B5.1...

328

Development of a catalytic combustion system for the MIT Micro Gas Turbine Engine  

E-Print Network (OSTI)

As part of the MIT micro-gas turbine engine project, the development of a hydrocarbon-fueled catalytic micro-combustion system is presented. A conventionally-machined catalytic flow reactor was built to simulate the ...

Peck, Jhongwoo, 1976-

2003-01-01T23:59:59.000Z

329

Catalytic activation and reforming of methane on supported palladium clusters Aritomo Yamaguchi, Enrique Iglesia *  

E-Print Network (OSTI)

of pollutants, oxygen generation, and intermediate-temperature solid oxide fuel cells, as well as catalytic reforming. Sekine et al.56 investigated four catalytic reactions assisted with an electric field to promote

Iglesia, Enrique

330

Continued investigations of the catalytic reduction of N? to NH? by molybdenum triamidoamine complexes  

E-Print Network (OSTI)

A study of the effects of employing different solvents and the introduction of dihydrogen during the catalytic reduction of dinitrogen to ammonia with [HIPTN 3N]Mo complexes was completed. During a catalytic reaction, the ...

Hanna, Brian S. (Brian Stewart)

2011-01-01T23:59:59.000Z

331

Pyrolysis Oil Upgrading to Transportation Fuels by Catalytic  

E-Print Network (OSTI)

such as fast- pyrolysis and catalytic fast-pyrolysis for producing liquid fuels from biomass feedstocks biomass to a fast-pyrolysis reactor (Table 3.4), the greatest mass yield of bio-oil can be attributed............................................................................................- 70 - TABLE 2.18. BIOMASS PYROLYSIS TECHNOLOGIES, REACTION CONDITIONS AND PRODUCTS................- 70

Groningen, Rijksuniversiteit

332

Catalytic Esterification of Model Compounds of Biomass Pyrolysis Oil  

Science Conference Proceedings (OSTI)

Biomass pyrolysis oil is a complex mixture containing a wide variety of oxygenated compounds, which results in difficulties in bio-oil upgrading. To gain a clearer understanding of the reaction pathways, seven compounds were chosen to represent biomass ... Keywords: pyrolysis oil, model compounds, catalytic esterification

Zuo-gang Guo; Shu-rong Wang; Ying-ying Zhu

2009-10-01T23:59:59.000Z

333

Homogeneous catalytic hydrogenations of complex carbonaceous substrates. [16 references  

SciTech Connect

Results of homogeneous catalytic hydrogenation of complex unsaturated substrates including coal and coal-derived materials are reported, with organic soluble molecular complexes as catalysts. Among the substrates used were Hvab coal, solvent-refined coal, and COED pyrolysate. The hydrogenations were carried out in an autoclave. The results are summarized in tables.

Cox, J L; Wilcox, W A; Roberts, G L

1976-11-05T23:59:59.000Z

334

Ex-Situ Catalytic Fast Pyrolysis Technology Pathway  

DOE Green Energy (OSTI)

This technology pathway case investigates converting woody biomass using ex-situ catalytic fast pyrolysis followed by upgrading to gasoline-, diesel-, and jet-range hydrocarbon blendstocks. Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified.

Biddy, M.; Dutta, A.; Jones, S.; Meyer, A.

2013-03-01T23:59:59.000Z

335

In-Situ Catalytic Fast Pyrolysis Technology Pathway  

DOE Green Energy (OSTI)

This technology pathway case investigates converting woody biomass using in-situ catalytic fast pyrolysis followed by upgrading to gasoline-, diesel-, and jet-range hydrocarbon blendstocks. Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified.

Biddy, M.; Dutta, A.; Jones, S.; Meyer, A.

2013-03-01T23:59:59.000Z

336

ULTRA LOW NOx CATALYTIC COMBUSTION FOR IGCC POWER PLANTS  

Science Conference Proceedings (OSTI)

Tests were performed in PCI's sub-scale high-pressure (10 atm) test rig, using PCI's two-stage (catalytic / gas-phase) combustion process for syngas fuel. In this process, the first stage is a Rich-Catalytic Lean-burn (RCL{trademark}) catalytic reactor, wherein a fuel-rich mixture contacts the catalyst and reacts while final and excess combustion air cool the catalyst. The second stage is a gas-phase combustor, wherein the catalyst cooling air mixes with the catalytic reactor effluent to provide for final gas-phase burnout and dilution to fuel-lean combustion products. During the reporting period, PCI successfully achieved NOx = 0.011 lbs/MMBtu at 10 atm pressure (corresponding to 2.0 ppm NOx corrected to 15% O{sub 2} dry) with near-zero CO emissions, surpassing the project goal of baseload conditions corresponding to Tampa Electric's Polk Power Station operation on 100% syngas (no co-firing of natural gas).

Lance L. Smith

2004-03-01T23:59:59.000Z

337

Catalytic pyrolysis of xylan-based hemicellulose over zeolites  

Science Conference Proceedings (OSTI)

Xylan was selected as model compound of hemicellulose to investigate its thermal behavior over zeolites by using TG-FTIR. The chemical structure of xylan and characterization of catalysts were first studied. All the three catalysts, HZSM-5, H-? ... Keywords: TG-FTIR, acids, catalytic pyrolysis, furans, hemicellulose, xylan, zeolites

Xiujuan Guo; Shurong Wang; Yan Zhou; Zhongynag Luo

2011-02-01T23:59:59.000Z

338

Recycling and Disposal of Spent Selective Catalytic Reduction Catalyst  

Science Conference Proceedings (OSTI)

Selective catalytic reduction (SCR) technology has become widespread within the utility industry as a means of controlling emissions of nitrogen oxides (NOx). The technology uses a solid catalyst that deactivates over time; and thus significant volumes of catalyst will need regeneration, recycle, or disposal. This study examined issues related to spent catalyst recycle and disposal.

2003-11-12T23:59:59.000Z

339

Chemical Imaging of Catalytic Solids with Synchrotron Radiation  

Science Conference Proceedings (OSTI)

Heterogeneous catalysis is a term normally used to describe a group of catalytic processes, yet it could equally be employed to describe the catalytic solid itself. A better understanding of the chemical and structural variation within such materials is thus a pre-requisite for the rationalising of structure-function relationships and ultimately to the design of new, more sustainable catalytic processes. The past 20 years has witnessed marked improvements in technologies required for analytical measurements at synchrotron sources, including higher photon brightness, nano-focusing, rapid, high resolution data acquisition and in the handling of large volumes of data. It is now possible to image materials using the entire synchrotron radiative profile, thus heralding a new era of in situ/operando measurements of catalytic solids. In this tutorial review we discuss the recent work in this exciting new research area and finally conclude with a future outlook on what will be possible/challenging to measure in the not-too-distant future.

A Beale; S Jacques; B Weckhuysen

2011-12-31T23:59:59.000Z

340

Catalytic cracking. (Latest citations from the Compendex database). Published Search  

Science Conference Proceedings (OSTI)

The bibliography contains citations concerning applications of catalytic cracking processes in fluidized bed systems, moving beds, refineries, vacuum distillations, and reformers. Design aspects, modeling, control systems, and operating procedures are also discussed. (Contains a minimum of 149 citations and includes a subject term index and title list.)

Not Available

1993-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "determination catalytic transformation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Simulation of Hydrogen Production from Biomass Catalytic Gasification  

Science Conference Proceedings (OSTI)

In this study, biomass catalytic gasification process for producing H2-rich gas was presented. The process consists of mainly two fluidized beds—a gasifier and a CaO regenerator. The objective of this research is to develop a computer model of ... Keywords: biomass gasification, hydrogen production, Aspen Plus

Shan Cheng; Qian Wang; Hengsong Ji

2010-12-01T23:59:59.000Z

342

High Performance Catalytic Heat Exchanger for SOFC Systems - FuelCell Energy  

NLE Websites -- All DOE Office Websites (Extended Search)

Catalytic Heat Catalytic Heat Exchanger for SOFC Systems-FuelCell Energy Background In a typical solid oxide fuel cell (SOFC) power generation system, hot (~900 °C) effluent gas from a catalytic combustor serves as the heat source within a high-temperature heat exchanger, preheating incoming fresh air for the SOFC's cathode. The catalytic combustor and the cathode air heat exchanger together represent the largest opportunity for cost

343

Component Development to Accelerate Commercial Implementation of Ultra-Low Emissions Catalytic Combustion  

SciTech Connect

This final report describes a 2000-2003 program for the development of components and processes to enhance the commercialization of ultra-low emissions catalytic combustion in industrial gas turbines. The range of project tasks includes: development of more durable, lower-cost catalysts and catalytic combustor components; development and design of a catalytic pre-burner and a catalytic pilot burner for gas turbines, and on-site fuel conversion processing for utilization of liquid fuel.

Jon McCarty, Brian Berry, Kare Lundberg, Orris Anson

2003-03-31T23:59:59.000Z

344

Selective Catalytic Reduction (SCR) Procurement Guideline for Simple- and Combined-Cycle Combustion Turbines  

Science Conference Proceedings (OSTI)

This report is a selective catalytic reduction (SCR) procurement guideline for simple- and combined-cycle combustion turbines.

2008-03-17T23:59:59.000Z

345

Plasma Catalytic Conversion of Methane in Ultra Rich Flame using Transient Gliding Arc Combustion Support  

E-Print Network (OSTI)

be carried out in a number of ways: steam reforming, thermo-catalytic reforming, partial oxidation, etc. [1

346

Industrial Gas Turbine Engine Catalytic Pilot Combustor-Prototype Testing  

SciTech Connect

PCI has developed and demonstrated its Rich Catalytic Lean-burn (RCL®) technology for industrial and utility gas turbines to meet DOEâ??s goals of low single digit emissions. The technology offers stable combustion with extended turndown allowing ultra-low emissions without the cost of exhaust after-treatment and further increasing overall efficiency (avoidance of after-treatment losses). The objective of the work was to develop and demonstrate emission benefits of the catalytic technology to meet strict emissions regulations. Two different applications of the RCL® concept were demonstrated: RCL® catalytic pilot and Full RCL®. The RCL® catalytic pilot was designed to replace the existing pilot (a typical source of high NOx production) in the existing Dry Low NOx (DLN) injector, providing benefit of catalytic combustion while minimizing engine modification. This report discusses the development and single injector and engine testing of a set of T70 injectors equipped with RCL® pilots for natural gas applications. The overall (catalytic pilot plus main injector) program NOx target of less than 5 ppm (corrected to 15% oxygen) was achieved in the T70 engine for the complete set of conditions with engine CO emissions less than 10 ppm. Combustor acoustics were low (at or below 0.1 psi RMS) during testing. The RCL® catalytic pilot supported engine startup and shutdown process without major modification of existing engine controls. During high pressure testing, the catalytic pilot showed no incidence of flashback or autoignition while operating over a wide range of flame temperatures. In applications where lower NOx production is required (i.e. less than 3 ppm), in parallel, a Full RCL® combustor was developed that replaces the existing DLN injector providing potential for maximum emissions reduction. This concept was tested at industrial gas turbine conditions in a Solar Turbines, Incorporated high-pressure (17 atm.) combustion rig and in a modified Solar Turbines, Incorporated Saturn engine rig. High pressure single-injector rig and modified engine rig tests demonstrated NOx less than 2 ppm and CO less than 10 ppm over a wide flame temperature operating regime with low combustion noise (<0.15% peak-to-peak). Minimum NOx for the optimized engine retrofit Full RCL® designs was less than 1 ppm with CO emissions less than 10 ppm. Durability testing of the substrate and catalyst material was successfully demonstrated at pressure and temperature showing long term stable performance of the catalytic reactor element. Stable performance of the reactor element was achieved when subjected to durability tests (>5000 hours) at simulated engine conditions (P=15 atm, Tin=400C/750F.). Cyclic tests simulating engine trips was also demonstrated for catalyst reliability. In addition to catalyst tests, substrate oxidation testing was also performed for downselected substrate candidates for over 25,000 hours. At the end of the program, an RCL® catalytic pilot system has been developed and demonstrated to produce NOx emissions of less than 3 ppm (corrected to 15% O2) for 100% and 50% load operation in a production engine operating on natural gas. In addition, a Full RCL® combustor has been designed and demonstrated less than 2 ppm NOx (with potential to achieve 1 ppm) in single injector and modified engine testing. The catalyst/substrate combination has been shown to be stable up to 5500 hrs in simulated engine conditions.

Shahrokh Etemad; Benjamin Baird; Sandeep Alavandi; William Pfefferle

2009-09-30T23:59:59.000Z

347

On the fundamental limitations of transformational design  

Science Conference Proceedings (OSTI)

The completeness of a collection of design transformations is an important aspect in transformational design. Completeness guarantees that any correct design can in principle be explored using the transformation system. In the field of transformational ... Keywords: Completeness, formal methods, high-level synthesis, syntactic variance problem, transformational design

Jeroen Voeten

2001-10-01T23:59:59.000Z

348

FORMIC ACID FREE FLOWSHEET DEVELOPMENT TO ELIMINATE CATALYTIC HYDROGEN GENERATION IN THE DEFENSE WASTE PROCESSING  

SciTech Connect

The Defense Waste Processing Facility (DWPF) processes legacy nuclear waste generated at the Savannah River Site (SRS) during production of plutonium and tritium demanded by the Cold War. The nuclear waste is first treated via a complex sequence of controlled chemical reactions and then vitrified into a borosilicate glass form and poured into stainless steel canisters. Converting the nuclear waste into borosilicate glass canisters is a safe, effective way to reduce the volume of the waste and stabilize the radionuclides. Testing was initiated to determine whether the elimination of formic acid from the DWPF’s chemical processing flowsheet would eliminate catalytic hydrogen generation. Historically, hydrogen is generated in chemical processing of alkaline High Level Waste sludge in DWPF. In current processing, sludge is combined with nitric and formic acid to neutralize the waste, reduce mercury and manganese, destroy nitrite, and modify (thin) the slurry rheology. The noble metal catalyzed formic acid decomposition produces hydrogen and carbon dioxide. Elimination of formic acid by replacement with glycolic acid has the potential to eliminate the production of catalytic hydrogen. Flowsheet testing was performed to develop the nitric-glycolic acid flowsheet as an alternative to the nitric-formic flowsheet currently being processed at the DWPF. This new flowsheet has shown that mercury can be reduced and removed by steam stripping in DWPF with no catalytic hydrogen generation. All processing objectives were also met, including greatly reducing the Slurry Mix Evaporator (SME) product yield stress as compared to the baseline nitric/formic flowsheet. Ten DWPF tests were performed with nonradioactive simulants designed to cover a broad compositional range. No hydrogen was generated in testing without formic acid.

Lambert, D.; Stone, M.; Newell, J.; Fellinger, T.; Bricker, J.

2012-09-14T23:59:59.000Z

349

Formic Acid Free Flowsheet Development To Eliminate Catalytic Hydrogen Generation In The Defense Waste Processing  

Science Conference Proceedings (OSTI)

The Defense Waste Processing Facility (DWPF) processes legacy nuclear waste generated at the Savannah River Site (SRS) during production of plutonium and tritium demanded by the Cold War. The nuclear waste is first treated via a complex sequence of controlled chemical reactions and then vitrified into a borosilicate glass form and poured into stainless steel canisters. Converting the nuclear waste into borosilicate glass canisters is a safe, effective way to reduce the volume of the waste and stabilize the radionuclides. Testing was initiated to determine whether the elimination of formic acid from the DWPF's chemical processing flowsheet would eliminate catalytic hydrogen generation. Historically, hydrogen is generated in chemical processing of alkaline High Level Waste sludge in DWPF. In current processing, sludge is combined with nitric and formic acid to neutralize the waste, reduce mercury and manganese, destroy nitrite, and modify (thin) the slurry rheology. The noble metal catalyzed formic acid decomposition produces hydrogen and carbon dioxide. Elimination of formic acid by replacement with glycolic acid has the potential to eliminate the production of catalytic hydrogen. Flowsheet testing was performed to develop the nitric-glycolic acid flowsheet as an alternative to the nitric-formic flowsheet currently being processed at the DWPF. This new flowsheet has shown that mercury can be reduced and removed by steam stripping in DWPF with no catalytic hydrogen generation. All processing objectives were also met, including greatly reducing the Slurry Mix Evaporator (SME) product yield stress as compared to the baseline nitric/formic flowsheet. Ten DWPF tests were performed with nonradioactive simulants designed to cover a broad compositional range. No hydrogen was generated in testing without formic acid.

2012-09-14T23:59:59.000Z

350

Transformer Efficiency Assessment - Okinawa, Japan  

Science Conference Proceedings (OSTI)

The US Army Engineering & Support Center, Huntsville (USAESCH), and the US Marine Corps Base (MCB), Okinawa, Japan retained Idaho National Laboratory (INL) to conduct a Transformer Efficiency Assessment of “key” transformers located at multiple military bases in Okinawa, Japan. The purpose of this assessment is to support the Marine Corps Base, Okinawa in evaluating medium voltage distribution transformers for potential efficiency upgrades. The original scope of work included the MCB providing actual transformer nameplate data, manufacturer’s factory test sheets, electrical system data (kWh), demand data (kWd), power factor data, and electricity cost data. Unfortunately, the MCB’s actual data is not available and therefore making it necessary to de-scope the original assessment. Note: Any similar nameplate data, photos of similar transformer nameplates, and basic electrical details from one-line drawings (provided by MCB) are not a replacement for actual load loss test data. It is recommended that load measurements are performed on the high and low sides of transformers to better quantify actual load losses, demand data, and power factor data. We also recommend that actual data, when available, be inserted by MCB Okinawa where assumptions have been made and then the LCC analysis updated. This report covers a generalized assessment of modern U.S. transformers in a three level efficiency category, Low-Level efficiency, Medium-Level efficiency, and High-Level efficiency.

Thomas L. Baldwin; Robert J. Turk; Kurt S. Myers; Jake P. Gentle; Jason W. Bush

2012-08-01T23:59:59.000Z

351

Transformer Efficiency Assessment - Okinawa, Japan  

SciTech Connect

The US Army Engineering & Support Center, Huntsville (USAESCH), and the US Marine Corps Base (MCB), Okinawa, Japan retained Idaho National Laboratory (INL) to conduct a Transformer Efficiency Assessment of “key” transformers located at multiple military bases in Okinawa, Japan. The purpose of this assessment is to support the Marine Corps Base, Okinawa in evaluating medium voltage distribution transformers for potential efficiency upgrades. The original scope of work included the MCB providing actual transformer nameplate data, manufacturer’s factory test sheets, electrical system data (kWh), demand data (kWd), power factor data, and electricity cost data. Unfortunately, the MCB’s actual data is not available and therefore making it necessary to de-scope the original assessment. Note: Any similar nameplate data, photos of similar transformer nameplates, and basic electrical details from one-line drawings (provided by MCB) are not a replacement for actual load loss test data. It is recommended that load measurements are performed on the high and low sides of transformers to better quantify actual load losses, demand data, and power factor data. We also recommend that actual data, when available, be inserted by MCB Okinawa where assumptions have been made and then the LCC analysis updated. This report covers a generalized assessment of modern U.S. transformers in a three level efficiency category, Low-Level efficiency, Medium-Level efficiency, and High-Level efficiency.

Thomas L. Baldwin; Robert J. Turk; Kurt S. Myers; Jake P. Gentle; Jason W. Bush

2012-05-01T23:59:59.000Z

352

Research on Differential Protection of Power Transformer Based Wavelet Transform  

Science Conference Proceedings (OSTI)

This article introduces wavelet analysis theory to identify inrush and internal fault correctly. The wavelet transform has the characteristic of multi-scale analysis and good time and frequency domain localization, fits to extract sudden-change signals ...

Yang Long; Li Donghui

2009-10-01T23:59:59.000Z

353

Transformational Manufacturing | Argonne National Laboratory  

NLE Websites -- All DOE Office Websites (Extended Search)

Transformational Manufacturing Transformational Manufacturing Argonne's new Advanced Battery Materials Synthesis and Manufacturing R&D Program focuses on scalable process R&D to produce advanced battery materials in sufficient quantity for industrial testing. The U.S. manufacturing industry consumes more than 30 quadrillion Btu of energy per year, directly employs about 12 million people and generates another 7 million jobs in related businesses. Argonne is working with industry to develop innovative and transformational technology to improve the efficiency and competitiveness of domestic manufacturing while reducing its carbon footprint. The lab's efforts concentrate on sustainable manufacturing, applied nanotechnology and distributed energy, with an emphasis on transitioning science discoveries to the market.

354

Transforms for the Motion Compensation Residual  

E-Print Network (OSTI)

The Discrete-Cosine-Transform (DCT) is the most widely used transform in image and video compression. Its use in image compression is often justified by the notion that it is the statistically optimal transform for first-order ...

Kamisli, Fatih

355

Reusable and correct endogenous model transformations  

Science Conference Proceedings (OSTI)

Correctness of model transformations is a prerequisite for generating correct implementations from models. Given refining model transformations that preserve desirable properties, models can be transformed into correct-by-construction implementations. ...

Suzana Andova; Mark G. J. van den Brand; Luc Engelen

2012-05-01T23:59:59.000Z

356

Mineral Transformation and Biomass Accumulation Associated With  

E-Print Network (OSTI)

Mineral Transformation and Biomass Accumulation Associated With Uranium Bioremediation at Rifle transformation and biomass accumulation, both of which can alter the flow field and potentially bioremediation to understand the biogeochemical processes and to quantify the biomass and mineral transformation/ accumulation

Hubbard, Susan

357

Electrokinetic Effects in Power Transformers  

Science Conference Proceedings (OSTI)

Electrokinetic effects such as static electrification can cause catastrophic failures in large forced-oil-cooled power transformers. The development of a network-based theoretical model provides a critical perspective not apparent from previous small-scale laboratory experiments.

1999-08-10T23:59:59.000Z

358

Substation distribution transformers failures and spares  

Science Conference Proceedings (OSTI)

Electric utilities should have a sufficient number of spare transformers to backup substation distribution transformers to replace transformers that fail and require factory rebuild or replacement. To identify such a number, the statistical methodology was developed to analyze available failure data for different groups of transformer. That methodology enables the estimation of future numbers of failures with associated probabilities, recommends the proper number of spares, identifies the necessity and shows the means to shorten the transformer`s replacement time.

Kogan, V.I. Roeger, C.J.; Tipton, D.E. [American Electric Power Service Corp., Columbus, OH (United States)

1996-11-01T23:59:59.000Z

359

Inducing Transformational Energy Technological Change  

Science Conference Proceedings (OSTI)

Reducing risks of severe climate change in the latter part of the 20th Century is likely to require not only incremental improvements in known energy technologies, but the discovery of transformational new energy technologies. This paper reviews current knowledge about both demand and supply aspects of the challenge of accelerating transformational change, considering both economic and policy incentives, including targeted government funding of research and development, and several other schools of thought about drivers of scientific discovery and innovation.

Wilbanks, Thomas J [ORNL

2011-01-01T23:59:59.000Z

360

Performance and emissions of a catalytic reactor with propane, diesel, and Jet A fuels  

DOE Green Energy (OSTI)

As part of the ERDA-funded Gas Turbine Highway Vehicle Systems project, tests were made to determine the performance and emissions of a catalytic reactor operated with propane, No. 2 diesel, and Jet A fuels. A 12-cm diameter and 16-cm long catalytic reactor using a proprietary noble metal catalyst was operated at an inlet temperature of 800 K, a pressure of 3 x 10/sup 5/ Pa and reference velocities of 10 to 15 m/s. No significant differences between the performance of the three fuels were observed when 98.5% purity propane was used. The combustion efficiency for 99.8% purity propane tested later was significantly lower, however. The diesel fuel contained 135 ppM of bound nitrogen and consequently produced the highest NO/sub x/ emissions of the three fuels. As much as 85% of the bound nitrogen was converted to NO/sub x/. Steady-state emissions goals based on half the most stringent proposed automotive standards were met when the reactor was operated at an adiabatic combustion temperature higher than 1350 K with all fuels except the 99.8% purity propane. With that fuel, a minimum temperature of 1480 K was required.

Anderson, D.N.

1977-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "determination catalytic transformation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Relations among various versions of the Segal-Bargmann transform  

E-Print Network (OSTI)

We present various relations among Versions A, B and C of the Segal-Bargmann transform. We get results for the Segal-Bargmann transform associated to a Coxeter group acting on a finite dimensional Euclidean space. Then analogous results are shown for the Segal-Bargmann transform of a connected, compact Lie group for all except one of the identities established in the Coxeter case. A counterexample is given to show that the remaining identity from the Coxeter case does not have an analogous identity for the Lie group case. A major result is that in both contexts the Segal-Bargmann transform for Version C is determined by that for Version A.

Stephen Bruce Sontz

2009-12-13T23:59:59.000Z

362

Conditional quantum-state transformation at a beam splitter  

E-Print Network (OSTI)

Using conditional measurement on a beam splitter, we study the transformation of the quantum state of the signal mode within the concept of two-port non-unitary transformation. Allowing for arbitrary quantum states of both the input reference mode and the output reference mode on which the measurement is performed, we show that the non-unitary transformation operator can be given as an $s$-ordered operator product, where the value of $s$ is entirely determined by the absolute value of the beam splitter reflectance (or transmittance). The formalism generalizes previously obtained results that can be recovered by simple specification of the non-unitary transformation operator. As an application, we consider the generation of Schr\\"odinger-cat-like states. An extension to mixed states and imperfect detection is outlined.

J. Clausen; M. Dakna; L. Knoll; D. -G. Welsch

1998-11-24T23:59:59.000Z

363

Method for recovering catalytic elements from fuel cell membrane electrode assemblies  

DOE Patents (OSTI)

A method for recovering catalytic elements from a fuel cell membrane electrode assembly is provided. The method includes converting the membrane electrode assembly into a particulate material, wetting the particulate material, forming a slurry comprising the wetted particulate material and an acid leachate adapted to dissolve at least one of the catalytic elements into a soluble catalytic element salt, separating the slurry into a depleted particulate material and a supernatant containing the catalytic element salt, and washing the depleted particulate material to remove any catalytic element salt retained within pores in the depleted particulate material.

Shore, Lawrence (Edison, NJ); Matlin, Ramail (Berkeley Heights, NJ); Heinz, Robert (Ludwigshafen, DE)

2012-06-26T23:59:59.000Z

364

High-Tech Buildings - Market Transformation Project  

NLE Websites -- All DOE Office Websites (Extended Search)

Tech Buildings - Market Transformation Project Title High-Tech Buildings - Market Transformation Project Publication Type Report LBNL Report Number LBNL-49112 Year of Publication...

365

NREL: Technology Deployment - Deployment and Market Transformation...  

NLE Websites -- All DOE Office Websites (Extended Search)

Deployment Search More Search Options Site Map Printable Version Deployment and Market Transformation Email Updates NREL's deployment and market transformation email updates...

366

TRANSFORMING ELECTRICITY DELIVERY | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

TRANSFORMING ELECTRICITY DELIVERY TRANSFORMING ELECTRICITY DELIVERY Designing research, development, and demonstration programs based on a future look at electric power delivery...

367

National Electric Delivery Technologies Roadmap: Transforming...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Delivery Technologies Roadmap: Transforming the Grid to Revolutionize Electric Power in North America National Electric Delivery Technologies Roadmap: Transforming the Grid to...

368

Optimization of distribution transformer efficiency characteristics. Final report  

SciTech Connect

A method for distribution transformer loss evaluation was derived. The total levelized annual cost method was used and was extended to account properly for conditions of energy cost inflation, peak load growth, and transformer changeout during the evaluation period. The loss costs included were the no-load and load power losses, no-load and load reactive losses, and the energy cost of regulation. The demand and energy components of loss costs were treated separately to account correctly for the diversity of load losses and energy cost inflation. An analysis was performed to find what level of transformer loss yields the minimum total levelized annual cost for a given kVA rating and a given set of load and cost parameters. Initial transformer costs as a function of no-load loss, load loss, and kVA were generated and used in the evaluation. Both single and multiple efficiency designs were considered. The total levelized annual costs of the two designs were compared. In each case the multiple efficiency design was less costly. A sensitivity analysis was performed to find the change in total levelized annual cost due to changes in the input parameters. Also, an analysis was conducted to determine the amount of energy required to produce the materials for distribution transformers. It was determined that the energy content of the extra materials used to produce a higher efficiency transformer was less than the amount of energy saved in operating costs. Therefore, from a total energy standpoint, it is worth using the extra energy to manufacture a more efficient transformer. Recommendations for distribution transformer efficiency characteristics and recommendations for further investigation are included. (LCL)

Braunstein, H.

1979-12-04T23:59:59.000Z

369

IN-SITU MAGIC ANGLE SPINNING NMR INVESTIGATIONS ON CATALYTIC CONVERSION OF BIOGENIC MOLECULES IN THE PRESENCE OF AQUEOUS WATER  

SciTech Connect

The catalyzed conversion of biomass to hydrocarbon energy carriers requires a cascade of reactions that deconstruct and reduce the polymeric, highly oxofunctionalized biomass material. While lignin is the most intractable component of lignocellulose, its conversion to useful products is key in this catalytic chemistry, because the carbon in lignin is the most reduced one in lignocellulose. This chemistry faces steep challenges, as most of the reactions have to be performed in an aqueous environment under conditions that are highly corrosive towards catalysts. The anticipated scale of the transformations demands that the complex catalysts involved be highly efficient, stable, regenerable, and economically viable catalysts. Currently, none of the known heterogeneous solid catalysts meets these requirements. In order to develop new catalysts satisfying these requirements, a fundamental understanding of the active centers, reaction intermediates and reaction dynamics/kinetics associated with the multi-step conversion of biomass/biomass components, or biomass related polar molecules, i.e., the precursor molecules to fuels, on multifunctional catalytic surfaces is critically needed.

Hu, Mary Y.; Feng, Ju; Camaioni, Donald M.; Turcu, Romulus VF; Peden, Charles HF; Lercher, Johannes A.; Hu, Jian Z.

2012-09-01T23:59:59.000Z

370

CATALYTICALLY ENCHANCED SYSTEMS FOR HYDROGEN STORAGE  

DOE Green Energy (OSTI)

Previous U.S. DOE sponsored research at the University of Hawaii resulted in the development of methods of doping of sodium aluminum hydride, NaAlH4 with titanium, zirconium and other catalysts such that: dehydriding occurs at temperatures as low as 100°C; rehydriding requires less than 1 h; and >4 weight percent hydrogen can be repeatedly cycled through dehydriding/rehydriding. These materials appeared to be on the threshold of practical viability as hydrogen carriers for onboard fuel cells. However, it was apparent that further kinetic enhancement was required to achieve commercial viability. Thus, one of the primary goals of this project was to develop the requisite improved catalysts. Over the course of this project, a variety of titanium and zirconium dopant precursors were investigated. Moreover, the approach was to conduct guided search for improved catalysts by obtaining a fundamental understanding of the chemical nature of the titanium dopants and their mechanism of action. Therefore, the projected also aimed to determined the chemical nature of the titanium species that are formed upon mechanical milling of NaAlH4 with the dopant precursors through synchrotron X-ray and neutron diffraction as well as transmission electron microscopy, scanning electron microscopy, and electron paramagnetic resonance (EPR) spectroscopy. In addition to kinetic studies, insight into the mechanism of action of the dopants was gained through studies of the destabilization of hydrogen in NaAlH4 by the dopants through infrared, NMR, and anelastic spectroscopy.

Craig M. Jensen

2007-04-23T23:59:59.000Z

371

Directional lapped transforms for image coding  

E-Print Network (OSTI)

Abstract—In this paper, we present the design of directional lapped transforms for image coding. A lapped transform, which can be implemented by a prefilter followed by a discrete cosine transform (DCT), can be factorized into elementary operators. The corresponding directional lapped transform is generated by applying each elementary operator along a given direction. The proposed directional lapped transforms are not only nonredundant and perfectly reconstructed, but they can also provide a basis along an arbitrary direction. These properties, along with the advantages of lapped transforms, make the proposed transforms appealing for image coding. A block-based directional transform scheme is also presented and integrated into HD Phtoto, one of the state-of-the-art image coding systems, to verify the effectiveness of the proposed transforms. Index Terms—Directional transform, image coding, lapped transform.

Jizheng Xu; Feng Wu; Senior Member; Jie Liang; Wenjun Zhang

2008-01-01T23:59:59.000Z

372

Catalytic destruction of groundwater contaminants in reactive extraction wells  

DOE Green Energy (OSTI)

A system for remediating groundwater contaminated with halogenated solvents, certain metals and other inorganic species based on catalytic reduction reactions within reactive well bores. The groundwater treatment uses dissolved hydrogen as a reducing agent in the presence of a metal catalyst, such a palladium, to reduce halogenated solvents (as well as other substituted organic compounds) to harmless species (e.g., ethane or methane) and immobilize certain metals to low valence states. The reactive wells function by removing water from a contaminated water-bearing zone, treating contaminants with a well bore using catalytic reduction, and then reinjecting the treated effluent into an adjacent water-bearing zone. This system offers the advantages of a compact design with a minimal surface footprint (surface facilities) and the destruction of a broad suite of contaminants without generating secondary waste streams.

McNab, Jr., Walt W. (Concord, CA); Reinhard, Martin (Stanford, CA)

2002-01-01T23:59:59.000Z

373

Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway  

Science Conference Proceedings (OSTI)

In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to hydrocarbon fuels to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This technology pathway case investigates the catalytic conversion of solubilized carbohydrate streams to hydrocarbon biofuels, utilizing data from recent efforts within the National Advanced Biofuels Consortium (NABC) in collaboration with Virent, Inc.. Technical barriers and key research needs that should be pursued for the catalytic conversion of sugars pathway to be competitive with petroleum-derived gasoline, diesel and jet range hydrocarbon blendstocks have been identified.

Biddy, Mary J.; Jones, Susanne B.

2013-03-31T23:59:59.000Z

374

Selective dehydrogenation of propane over novel catalytic materials  

Science Conference Proceedings (OSTI)

The conversion of small alkanes into alkenes represents an important chemical processing area; ethylene and propylene are the two most important organic chemicals manufactured in the U.S. These chemicals are currently manufactured by steam cracking of ethane and propane, an extremely energy intensive, nonselective process. The development of catalytic technologies (e.g., selective dehydrogenation) that can be used to produce ethylene and propylene from ethane and propane with greater selectivity and lower energy consumption than steam cracking will have a major impact on the chemical processing industry. This report details a study of two novel catalytic materials for the selective dehydrogenation of propane: Cr supported on hydrous titanium oxide ion-exchangers, and Pt nanoparticles encapsulated in silica and alumina aerogel and xerogel matrices.

Sault, A.G.; Boespflug, E.P.; Martino, A.; Kawola, J.S.

1998-02-01T23:59:59.000Z

375

Selective Dehydrogenation of Propane over Novel Catalytic Materials  

E-Print Network (OSTI)

The conversion of small alkanes into alkenes represents an important chemical processing area; ethylene and propylene are the two most important organic chemicals manufactured in the U.S. These chemicals are currently manufactured by steam cracking of ethane and propane, an extremely energy intensive, nonselective process. The development of catalytic technologies (e.g., selective dehydrogenation) that can be used to produce ethylene and propylene from ethane and propane with greater selectivity and lower energy consumption than steam cracking will have a major impact on the chemical processing industry. This report details a study of two novel catalytic materials for the selective dehydrogenation of propane: Cr supported on hydrous titanium oxide ion-exchangers, and Pt nanoparticles encapsulated in silica and alumina aerogel and xerogel matrices. 4 Acknowledgment The authors thank United Catalysts, Inc. for stimulating technical discussions and for providing samples of commercial ...

Allen Sault Elaine; Elaine P. Boespflug Anthony Martino; Jeffrey S. Kawola

1998-01-01T23:59:59.000Z

376

Size Effect of Ruthenium Nanoparticles in Catalytic Carbon Monoxide Oxidation  

Science Conference Proceedings (OSTI)

Carbon monoxide oxidation over ruthenium catalysts has shown an unusual catalytic behavior. Here we report a particle size effect on CO oxidation over Ru nanoparticle (NP) catalysts. Uniform Ru NPs with a tunable particle size from 2 to 6 nm were synthesized by a polyol reduction of Ru(acac){sub 3} precursor in the presence of poly(vinylpyrrolidone) stabilizer. The measurement of catalytic activity of CO oxidation over two-dimensional Ru NPs arrays under oxidizing reaction conditions (40 Torr CO and 100 Torr O{sub 2}) showed an activity dependence on the Ru NP size. The CO oxidation activity increases with NP size, and the 6 nm Ru NP catalyst shows 8-fold higher activity than the 2 nm catalysts. The results gained from this study will provide the scientific basis for future design of Ru-based oxidation catalysts.

Joo, Sang Hoon; Park, Jeong Y.; Renzas, J. Russell; Butcher, Derek R.; Huang, Wenyu; Somorjai, Gabor A.

2010-04-04T23:59:59.000Z

377

Selective Catalytic Reduction Mercury Oxidation Data to Support Catalyst Management  

Science Conference Proceedings (OSTI)

Selective catalytic reduction (SCR) mercury oxidation can be pivotal for Mercury and Air Toxics Standards compliance, especially for those units that rely on co-benefits as their primary method of mercury control. Much work has been done historically to understand the mercury behavior across SCRs, especially as a function of operating conditions, and in particular, flue gas composition. The present work seeks to integrate the accumulated knowledge into a practical document that will aid utilities in ...

2013-11-13T23:59:59.000Z

378

Selective Non-Catalytic Reduction (SNCR) Technology Overview  

Science Conference Proceedings (OSTI)

This document provides a technology overview regarding the application and operation of selective non-catalytic reduction (SNCR) to coal-fired electric utility boilers for the incremental reduction of NOx emissions. The document provides a historical perspective of the SNCR technology development, background regarding the reaction chemistry, and process parameters that impact SNCR NOx reduction performance. In addition, a review of reagent choices along with storage and handling requirements is ...

2013-09-12T23:59:59.000Z

379

Operation and Maintenance Guidelines for Selective Catalytic Reduction Systems  

Science Conference Proceedings (OSTI)

This document is the 2010 version of Operation and Maintenance Guidelines for Selective Catalytic Reduction Systems, originally published in 2001 and updated annually. New content this year includes: (1) A section on static mixers added in Chapter 3; (2) Substantial expansion of the discussion on inspection of ammonia storage and delivery equipment in Chapter 8; (3) Expanded coverage of unit startup, shutdown, and low-load operation in Chapter 15; (4) a new chapter, Chapter 18, on the means to ensure tha...

2010-11-29T23:59:59.000Z

380

CATALYTIC CONVERSION OF ORGANIC COMPOUNDS USING PENETRATING RADIATION  

DOE Patents (OSTI)

A method of hydrogenating an olefinic hydrocarbon by irradiating a substrate catalyst and increasing its catalytic activity is described. Ferric oxide with about 0.005% by weight of at least one oxide of a metal selected from the group consisting of aluminum, magnesium, nickel, zirconium, and manganese incorporated therein is irradiated. Then an alkane is placed upon the surface of the catalyst and irradiated in an atmosphere of hydrogen. Any olefin produced from this radiolysis becomes hydrogenated. (AEC)

Caffrey, J.M. Jr.

1961-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "determination catalytic transformation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Equilibrium Characteristics of Selective Catalytic Reduction (SCR) Catalyst Poisons  

Science Conference Proceedings (OSTI)

In Power River Basin (PRB) coal applications, phosphorus (P) is known as the primary catalyst poison. Recent utility experience shows that some units burning PRB coal are deactivating the selective catalytic reduction (SCR) catalyst more rapidly than others. The exact mechanism is not well understood but could be related to boiler type or combustion modifications leading to increased levels of phosphorus vaporization. With increased levels of phosphorus in flue gas, greater quantities of phosphorus would...

2011-12-20T23:59:59.000Z

382

Selective Catalytic Reduction Catalyst Recycle and Re-Use Options  

Science Conference Proceedings (OSTI)

Given the widespread implementation of selective catalytic reduction (SCR) technology, there is a great deal of interest in finding viable recycle/re-use routes for spent catalyst as an alternative to landfilling. The current effort has focused on detailed evaluation of several recycle/re-use processes that were identified in previous EPRI studies. These recycle/re-use technologies include mineral filler applications, incorporation into wet-bottom boiler slag, cement kiln co-processing, and use in iron/s...

2010-12-21T23:59:59.000Z

383

Simulation of ethylbenzene dehydrogenation in microporous catalytic membrane reactors  

DOE Green Energy (OSTI)

Current state-of-the-art inorganic oxide membranes offer the potential of being modified to yield catalytic properties. The resulting modules may be configured to simultaneously induce catalytic reactions with product concentration and separation in a single processing step. Processes utilizing such catalytically active membrane reactors have the potential for dramatically increasing yield of reactions which are currently limited by either thermodynamic equilibria, product inhibition, or kinetic selectivity. Examples of systems of commercial interest include hydrogenation, dehydrogenation, partial and selective oxidation, hydrations, hydrocarbon cracking, olefin metathesis, hydroformylation, and olefin polymerization. A large portion of the most significant reactions fall into the category of high temperature, gas phase chemical and petrochemical processes. Microporous oxide membranes are well suited for these applications. A program is proposed to investigate selected model reactions of commercial interest (i.e., dehydrogenation of ethylbenzene to styrene and dehydrogenation of butane to butadiene) using a high temperature catalytic membrane reactor. Membranes will be developed, reaction dynamics characterized, and production processes developed, culminating in laboratory-scale demonstration of technical and economic feasibility. As a result of the anticipated increased yield per reactor pass, large economic incentives are envisioned. First, a large decrease in the temperature required to obtain high yield should be possible because of the reduced driving force requirement. Significantly higher conversion per pass implies a reduced recycle ratio, as well as reduced reactor size. Both factors result in reduced capital costs, as well as savings in cost reactants and energy. The controlled, defined reaction zone (the membrane interface), will facilitate the reactor design process and permit greater control of reactor dynamics.

Not Available

1989-04-01T23:59:59.000Z

384

Exxon Catalytic Coal Gasification Process Predevelopment Program. Final project report  

SciTech Connect

This report summarizes the results of work conducted on Predevelopment Research for the Exxon Catalytic Coal Gasification Process. The eighteen-month effort (July 1976-December 1977) was a coordinated program which included operation of a continuous fluidized-bed gasifier, parallel bench-scale research, and engineering studies leading to the preparation of a commercial-scale plant study design and economics for producing SNG from Illinois coal.

Kalina, T.; Nahas, N.C.

1978-12-01T23:59:59.000Z

385

An approach for exploring code improving transformations  

Science Conference Proceedings (OSTI)

Although code transformations are routinely applied to improve the performance of programs for both scalar and parallel machines, the properties of code-improving transformations are not well understood. In this article we present a framework that enables ... Keywords: automatic generation of optimizers, code-improving transformations, enabling and disabling of optimizations, parallelizing transformations, specification of program optimizations

Deborah L. Whitfield; Mary Lou Soffa

1997-11-01T23:59:59.000Z

386

Transform Solar | Open Energy Information  

Open Energy Info (EERE)

Transform Solar Transform Solar Jump to: navigation, search Name Transform Solar Place Boise, Idaho Product Idaho-based PV module maker and joint venture between Micron and Origin Energy. Coordinates 43.60698°, -116.193409° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":43.60698,"lon":-116.193409,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

387

Towards a Number Theoretic Discrete Hilbert Transform  

E-Print Network (OSTI)

This paper presents an approach for the development of a number theoretic discrete Hilbert transform. The forward transformation has been applied by taking the odd reciprocals that occur in the DHT matrix with respect to a power of 2. Specifically, the expression for a 16-point transform is provided and results of a few representative signals are provided. The inverse transform is the inverse of the forward 16-point matrix. But at this time the inverse transform is not identical to the forward transform and, therefore, our proposed number theoretic transform must be taken as a provisional result.

Kandregula, Renuka

2009-01-01T23:59:59.000Z

388

Catalytic fabric filtration for simultaneous NO{sub x} and particulate control. Final report  

SciTech Connect

The overall objective of the project proposed was to evaluate the catalyst-coated fabric filter concept for effective control of NO{sub 2} and particulate emissions simultaneously. General goals included demonstrating high removal efficiency of NO{sub x} and particulate matter, acceptable bag and catalyst life, and that process economics show a significant cost savings in comparison to a commercial SCR process and conventional particulate control. Specific goals included the following: reduce NO{sub x} emissions to 60 ppM or less; demonstrate particulate removal efficiency of >99.5%; demonstrate a bag/catalyst life of >1 year; Control ammonia slip to <25 ppM; show that catalytic fabric filtration can achieve a 50% cost savings over conventional fabric filtration and SCR control technology; determine compatibility with S0{sub 2} removal systems; and show that the concept results in a nonhazardous waste product.

Weber, G.F.; Dunham, G.E.; Laudal, D.L.; Ness, S.R.; Schelkoph, G.L.

1994-08-01T23:59:59.000Z

389

Transforming quantum operations: quantum supermaps  

E-Print Network (OSTI)

We introduce the concept of quantum supermap, describing the most general transformation that maps an input quantum operation into an output quantum operation. Since quantum operations include as special cases quantum states, effects, and measurements, quantum supermaps describe all possible transformations between elementary quantum objects (quantum systems as well as quantum devices). After giving the axiomatic definition of supermap, we prove a realization theorem, which shows that any supermap can be physically implemented as a simple quantum circuit. Applications to quantum programming, cloning, discrimination, estimation, information-disturbance trade-off, and tomography of channels are outlined.

G. Chiribella; G. M. D'Ariano; P. Perinotti

2008-04-01T23:59:59.000Z

390

Amorphous Metal Transformer: Next Steps  

Science Conference Proceedings (OSTI)

Amorphous-metal transformers were developed through EPRI in the early 1980's. Over the next 15 years, US electric utilities bought and installed over 500,000 units and had satisfactory field experience. The demand for this product disappeared in North America late in the 1990's as deregulation set-in. Globally, this product has been in use, and its acceptance has been increasing. This paper describes the current state of amorphous transformer activities globally. An analysis using US Department of Energy...

2009-07-31T23:59:59.000Z

391

Conditioned Unitary Transformation on biphotons  

E-Print Network (OSTI)

A conditioned unitary transformation ($90^o$ polarization rotation) is performed at single-photon level. The transformation is realized by rotating polarization for one of the photons of a polarization-entangled biphoton state (signal photon) by means of a Pockel's cell triggered by the detection of the other (idler) photon after polarization selection. As a result, polarization degree for the signal beam changes from zero to the value given by the idler detector quantum efficiency. This result is relevant to practical realization of various quantum information schemes and can be used for developing a new method of absolute quantum efficiency calibration.

G. Brida; M. Chekhova; M. Genovese; M. Gramegna; L. Krivitsky; S. Kulik

2003-12-29T23:59:59.000Z

392

Computation of Lie Transformations from a Power Series: Bounds and Optimum Truncation  

E-Print Network (OSTI)

The problem considered is the computation of an infinite product (composition) of Lie transformations generated by homogeneous polynomials of increasing order from a given convergent power series. Bounds are computed for the infinitesimal form of Lie transformations. The results obtained do not guarantee convergence of the product. Instead, the optimum truncation is determined by minimizing the terms of order n+1 that remain after the first n Lie transformations have been applied.

Ivan Gjaja

1994-11-03T23:59:59.000Z

393

Gauge transformations in non-perturbative chiral gauge theories  

E-Print Network (OSTI)

We reconsider gauge-transformation properties in chiral gauge theories on the lattice observing all pertinent information and show that these properties are actually determined in a general way for any gauge group and for any value of the index. In our investigations we also clarify several related issues.

Werner Kerler

2005-07-20T23:59:59.000Z

394

Determination of the Intrinsic Interface Mobility in Binary Ferrous ...  

Science Conference Proceedings (OSTI)

Register as a New User ... However, the determination of the interfacial mobility is not straightforward due to the fact that the usual transformation kinetics are ...

395

Categorical Exclusion Determinations: Western Area PowerAdministratio...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

January 7, 2011 CX-005115: Categorical Exclusion Determination Weld Substation Transformer Placement, Greeley, Weld County, Colorado CX(s) Applied: B4.6 Date: 01072011...

396

Determination Analysis of Energy Conservation Standards for Distributi...  

NLE Websites -- All DOE Office Websites (Extended Search)

NATIONAL LABORATORY n LOCKHEED MARTI MANAGED AND OPERATED BY Determination Analysis of Energy Conservation Standards for Distribution Transformers P. R. Barnes J. VI. Van Dyke 5....

397

Categorical Exclusion Determinations: A9 | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Technology Laboratory February 5, 2010 CX-000778: Categorical Exclusion Determination Market Transformation and Technology Deployment - Renewable Energy Projects CX(s) Applied:...

398

Liquid chromatographic determination of water  

DOE Green Energy (OSTI)

A sensitive method for the determination of water in the presence of common interferences is presented. The detection system is based on the effect of water on the equilibrium which results from the reaction aryl aldehydes, such as cinnamaldehyde and methanol in the eluent to form cinnamaldehyde dimethylacetal, plus water. This equilibrium is shifted in a catalytic atmosphere of a hydrogen ion form past column reactor. The extent of the shift and the resulting change in absorbance are proportional to the amount of water present.

Fortier, Nancy E. (Fairfield, OH); Fritz, James S. (Ames, IA)

1990-11-13T23:59:59.000Z

399

Final Report, "Molecular Design of Hydrocarbon Oxidation Catalytic Processes"  

SciTech Connect

The main goal of this project had been to use model systems to correlate selectivities in partial oxidation catalysis with the presence of specific sites on the surface of the catalyst. Extensive work was performed this year on characterizing oxygen-treated nickel surfaces by chemical means. Specifically, the surface chemistry of ammonia coadsorbed with atomic oxygen on Ni(110) single-crystal surfaces was studied by temperature-programmed desorption (TPD) and X-ray photoelectron spectroscopy (XPS). It was determined that at intermediate oxygen coverages direct ammonia adsorption on nickel sites is suppressed, but a new high-temperature reaction regime is generated at 400 K where NHx surface fragments are rehydrogenated concurrently with the production of water and molecular hydrogen. The extensive isotope scrambling and hydrogen transfer seen from nitrogen- to oxygen-containing surface intermediates, and the optimum yields seen for this 400 K state at intermediate oxygen coverages, strongly suggest the direct interaction of the adsorbed ammonia with oxygen atoms at the end of the –Ni–O- rows that form upon reconstruction of the surface. Hydrogen transfer between ammonia and oxygen appears to take place directly via hydrogen bonding, and to be reversible but biased towards water formation. An equilibrium is reached between the produced water and the reacting surface oxygen and hydrogen. The strong influence of the OH surface groups on the thermal chemistry of the adsorbed ammonia was interpreted in terms of the adsorbing geometry of the OH groups on the surface, and of hydrogen bonding between adsorbed OH and NH3 species. In terms of alcohol reactivity, the adsorption of 2-iodoethanol, a precursor for the preparation of 2-hydroxyethyl and oxametallacycle surface species, was found to lead to two configurations involving either just the iodine atom or both iodine and hydroxyl ends of the molecule. A complex chemical behavior starts around 140 K with the production of small amounts of ethylene and water, most likely via the concerted decomposition or disproportionation of the adsorbed molecular species. The bulk of the 2-iodoethanol decomposes at about 150 K via an initial carbon-iodine scission to form –O(H)CH2CH2– (~80%) and 2-hydroxyethyl (~20%) intermediates. Two competing reactions are involved with the subsequent conversion of the 2-hydroxyethyl species around 160 K, a reductive elimination with surface hydrogen to yield ethanol, and a ?-H elimination to surface vinyl alcohol. The –O(H)CH2CH2–, on the other hand, dehydrogenates to a –OCH2CH2– oxametallacycle species about the same temperature. Both 2-hydroxyethyl and oxametallacycle species tautomerize to acetaldehyde, around 210 K and above 250 K, respectively, and some of that acetaldehyde desorbs while the rest decomposes to hydrogen and carbon monoxide. We contend that a better understanding of the surface chemistry of oxygen-containing surfaces can lead to better selectivities in catalysis. This is arguably the most important issue in the field of catalysis in the near future, and one that impacts several technologies of interest to DOE such as the manufacturing of speciality chemicals and the control and removal of pollutants. Additional work was performed on the characterization of the chemistry of methyl and methylene adsorbed species on oxygen-treated nickel surfaces. Complex chemistry was observed involving not only hydrogenation and dehydrogenation steps, but also C-C couplings and methylene insertions to produce heavier hydrocarbons, and oxygen insertion reactions that yield oxygenates. Finally, a dual titration technique employing xenon and a chemically sensitive probe was developed to identify minority catalytic sites on oxide surfaces. In the case of oxygen-treated Ni(110) single crystals, it was found that both hydrogen transfer with adsorbed water or ammonia and certain hydrocarbon hydrogenation reactions take place at the end of the –Ni–O rows that form in this system. Carbon and nitrogen oxides, on the other hand, display no pre

Professor Francisco Zaera

2007-08-09T23:59:59.000Z

400

Image capture system colors transforms  

Science Conference Proceedings (OSTI)

The goal of this paper is to simulate the colors transforms of the reflected light from an illuminated object that passes trough an image capture system. We are interested to see the colors differences at the output of each component from which the light ... Keywords: CIE standards, human eye response, lenses and filters transmittance, spectral images

Toadere Florin

2010-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "determination catalytic transformation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Coupled diffusional/displacive transformations  

E-Print Network (OSTI)

.~...., 0 OJII <- OM -1G1d /J mole Figure 2.2: Illustration of the dependence of interfacial composition x I on the interfacial dissipation Gid for a Fe-0.2C wt.% transformed at 486 QC . Bl and B2 are the coefficients...

Mujahid, Shafiq Ahmad

402

Scalable spectral transforms at petascale  

Science Conference Proceedings (OSTI)

In this paper, I describe a framework for spectral transforms called P3DFFT, and its extended features and applications. I discuss the scaling seen on petascale platforms, and directions and some results of the ongoing work on improving performance, ... Keywords: community applications, high performance computing (HPC), numerical libraries, open source software, parallel performance, petascale, scalability, two-dimensional decomposition

Dmitry Pekurovsky

2013-07-01T23:59:59.000Z

403

Filter Properties of Spectral transformations  

Science Conference Proceedings (OSTI)

Recently, a special group of global spherical coordinate transformations has been introduced in order to focus attention on the interactions of an enlarged spectral band of only one selected area, while de-focusing the rest of the globe and thus ...

Frank Schmidt

1981-02-01T23:59:59.000Z

404

Security-oriented program transformations  

Science Conference Proceedings (OSTI)

Security experts generally believe that, "security cannot be added on, it must be designed from the beginning" [1]. This is because the typical way of improving system security by patches is ad hoc and has not produced good results. My work shows that ... Keywords: program transformation, security

Munawar Hafiz; Ralph E. Johnson

2009-04-01T23:59:59.000Z

405

CX-003621: Categorical Exclusion Determination | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

21: Categorical Exclusion Determination 21: Categorical Exclusion Determination CX-003621: Categorical Exclusion Determination Hayden Substation Transformer Replacement CX(s) Applied: B4.6 Date: 08/23/2010 Location(s): Routt County, Colorado Office(s): Western Area Power Administration-Rocky Mountain Region Western Area Power Administration proposes to replace the existing 100 megavolt-amphere (MVA) three phase transformer, KZ1A, at the Hayden Substation with a new three phase transformer. This project is required to remedy a temporary transformer configuration due to the failure of one of the windings of the original transformer. It is proposed that the temporary 230/138 kilovolt, 1000 MVA KZ1A transformer at Western's Hayden Substation be replaced with a new transformer having greater capacity so that existing

406

Catalytic hydroprocessing of shale oil to produce distillate fuels  

DOE Green Energy (OSTI)

Results are presented of a Chevron Research Company study sponsored by the Energy Research and Development Administration (ERDA) to demonstrate the feasibility of converting whole shale oil to a synthetic crude resembling a typical petroleum distillate. The synthetic crude thus produced can then be processed, in conventional petroleum-refining facilities, to transportation fuels such as high octane gasoline, diesel, and jet fuel. The raw shale oil feed used is a typical Colorado shale oil produced in a surface retort in the so-called indirectly heated mode. It is shown that whole shale oil can be catalytically hydrodenitrified to reduce the nitrogen to levels as low as one part per million in a single catalytic stage. However, for economic reasons, it appears preferable to denitrify to about 0.05 wt % nitrogen. The resulting synthetic crude resembles a petroleum distillate that can be fractionated and further processed as necessary in conventional petroleum refining facilities. Shale oil contains about 0.6% sulfur. Sulfur is more easily removed by hydrofining than is nitrogen; therefore, only a few parts per million of sulfur remain at a product nitrogen of 0.05 wt %. Oxygen contained in the shale oil is also reduced to low levels during hydrodenitrification. The shale oil contains appreciable quantities of iron and arsenic which are also potential catalyst poisons. These metals are removed by a guard bed placed upstream from the hydrofining catalyst. Based on correlations, the naphthas from the shale oil hydrofiner can readily be upgraded to high octane gasolines by catalytic reforming. The middle distillate fractions may require some additional hydrofining to produce salable diesel or jet fuel. The technology is available, and pilot plant studies are scheduled to verify diesel hydrofiner performance.

Sullivan, R.F.; Stangeland, B.E.

1977-01-01T23:59:59.000Z

407

Effect of reformer conditions on catalytic reforming of biomass-gasification tars  

Science Conference Proceedings (OSTI)

Parametric tests on catalytic reforming of tars produced in biomass gasification are performed using a bench-scale, fluid-bed catalytic reformer containing a commercial nickel-based catalyst. The product gas composition and yield vary with reformer temperature, space time, and steam: biomass ratio. Under certain catalytic tar reforming conditions, the gas yield increases by 70%; 97% of the tars are cracked into gases; and benzene and naphthalene, the predominant tar species, are virtually eliminated from the product gas.

Kinoshita, C.M.; Wang, Y.; Zhou, J. [Univ. of Hawaii, Honolulu, HI (United States)

1995-09-01T23:59:59.000Z

408

Fabrication of catalytic electrodes for molten carbonate fuel cells  

DOE Patents (OSTI)

A porous layer of catalyst material suitable for use as an electrode in a molten carbonate fuel cell includes elongated pores substantially extending across the layer thickness. The catalyst layer is prepared by depositing particulate catalyst material into polymeric flocking on a substrate surface by a procedure such as tape casting. The loaded substrate is heated in a series of steps with rising temperatures to set the tape, thermally decompose the substrate with flocking and sinter bond the catalyst particles into a porous catalytic layer with elongated pores across its thickness. Employed as an electrode, the elongated pores provide distribution of reactant gas into contact with catalyst particles wetted by molten electrolyte.

Smith, James L. (Lemont, IL)

1988-01-01T23:59:59.000Z

409

Catalytic steam gasification of bagasse for the production of methanol  

DOE Green Energy (OSTI)

Pacific Northwest Laboratory (PNL) tested the catalytic gasification of bagasse for the production of methanol synthesis gas. The process uses steam, indirect heat, and a catalyst to produce synthesis gas in one step in fluidized bed gasifier. Both laboratory and process development scale (nominal 1 ton/day) gasifiers were used to test two different catalyst systems: (1) supported nickel catalysts and (2) alkali carbonates doped on the bagasse. This paper presents the results of laboratory and process development unit gasification tests and includes an economic evaluation of the process. 20 references, 6 figures, 9 tables.

Baker, E.G.; Brown, M.D.

1983-12-01T23:59:59.000Z

410

Inter-Layer Mixing in Selective Catalytic Reduction Systems  

Science Conference Proceedings (OSTI)

The primary parameter for achieving high NOx reduction and low ammonia (NH3) slip in Selective Catalytic Reduction (SCR) systems on large coal-fired boilers is a uniform NH3/NOx ratio distribution at the catalyst surface. Large non-uniformities yield local NH3/NOx ratios greater than one, leading directly to NH3 slip. Areas of low NH3/NOx ratios have low NOx reduction. Both of these conditions are undesirable. SCR system designers specify a maximum acceptable NH3/NOx non-uniformity at the catalyst inlet....

2005-12-20T23:59:59.000Z

411

Catalytic reforming of liquid fuels: Deactivation of catalysts  

Science Conference Proceedings (OSTI)

The catalytic reforming of logistic fuels (e.g., diesel) to provide hydrogen-rich gas for various fuel cells is inevitably accompanied by deactivation. This deactivation can be caused by various mechanisms, such as carbon deposition, sintering, and sulfur poisoning. In general, these mechanisms are, not independent—e.g., carbon deposition may affect sulfur poisoning. However, they are typically studied in separate experiments, with relatively little work reported on their interaction at conditions typical of liquid fuel reforming. Recent work at the U.S. Dept. of Energy/NETL and Louisiana State University has shown progress in understanding the interaction of these deactivation processes, and catalysts designed to minimize them.

Spivey, J.J.; Haynes, D.J.; Berry, D.A.; Shekhawat, Dushyant; Gardner, T.H.

2007-10-01T23:59:59.000Z

412

Catalytic effects of period iv transition metal in the oxidation of biodiesel.  

E-Print Network (OSTI)

??CATALYTIC EFFECTS OF PERIOD IV TRANSITION METALS IN THE OXIDATION OF BIODIESEL BRADLEY R CLARK December 2011 Advisors: Dr. Steve Salley, Dr. Simon Ng, Dr.… (more)

Clark, Bradley

2012-01-01T23:59:59.000Z

413

Catalytic conversion of C3+ alcohols to hydrocarbon blend-stock  

Catalytic conversion of C3+ alcohols to hydrocarbon blend-stock Note: The technology described above is an early stage opportunity. Licensing rights to this ...

414

Microsoft Word - 41890_PW_Catalytic Combustion_Factsheet_Rev01...  

NLE Websites -- All DOE Office Websites (Extended Search)

Plan and Integration Study for rich catalytic combustion as applied to industrial gas turbines fired on both natural gas and coal derived synthesis gas. The overall goal is...

415

Experimental investigation and systems modeling of fractional catalytic pyrolysis of pine .  

E-Print Network (OSTI)

??The fractional catalytic pyrolysis of pine was studied both experimentally and through models. A preliminary stage economic analysis was conducted for a wood chip pyrolysis… (more)

Goteti, Anil Chaitanya

2010-01-01T23:59:59.000Z

416

CX-003028: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Exclusion Determination Recovery Act - Fault Current Limiting Superconducting Transformer CX(s) Applied: A9, B3.6, B4.11 Date: 07132010 Location(s): Oak Ridge, Tennessee...

417

CX-010543: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

CX-010543: Categorical Exclusion Determination Repair of Big Hill Texas-14 Transformer CX(s) Applied: B1.3 Date: 06242013 Location(s): Texas Offices(s): Strategic...

418

CX-002435: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

CX-002435: Categorical Exclusion Determination Redmond Substation 230-115-Kilovolt Transformer Addition CX(s) Applied: B4.6 Date: 05072010 Location(s): Deschutes County, Oregon...

419

CX-010715: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

CX-010715: Categorical Exclusion Determination Replace Bayou Choctaw 500 KVA Power Transformer CX(s) Applied: B1.3 Date: 07092013 Location(s): Louisiana Offices(s): Strategic...

420

CX-003029: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Exclusion Determination Recovery Act - Fault Current Limiting Superconducting Transformer CX(s) Applied: A11, B3.6 Date: 07132010 Location(s): Houston, Texas Office(s):...

Note: This page contains sample records for the topic "determination catalytic transformation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

CX-003030: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Exclusion Determination Recovery Act - Fault Current Limiting Superconducting Transformer CX(s) Applied: B3.6, B4.11, B5.1 Date: 07132010 Location(s): Waukesha, Wisconsin...

422

CX-010683: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Categorical Exclusion Determination "Glen Canyon Substation Stage 09- 50MVA 23069KV Transformer addition CX(s) Applied: B4.11 Date: 07022013 Location(s): Arizona, Arizona...

423

Categorical Exclusion Determinations: Nebraska | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

16, 2009 CX-000554: Categorical Exclusion Determination Ogallala Substation KY1A Transformer Replacement CX(s) Applied: B4.6 Date: 11162009 Location(s): Ogallala, Nebraska...

424

CX-008351: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Categorical Exclusion Determination Transport and Perform TD&I on Big Hill TX-29 Transformer CX(s) Applied: B1.3 Date: 03282012 Location(s): Texas Offices(s): Strategic...

425

CX-000523: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Categorical Exclusion Determination Electrical Isolation of 652-68G and 652-70G Transformers CX(s) Applied: B4.10 Date: 09092009 Location(s): Aiken, South Carolina Office(s):...

426

CX-003806: Categorical Exclusion Determination | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Exclusion Determination Market Transformation and Technology Deployment-Renewable Energy Projects CX(s) Applied: A9, A11, B5.1 Date: 09152010 Location(s): Mississippi...

427

Categorical Exclusion (CX) Determination  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Movement of the Shirley Pump substation to a new site away from Movement of the Shirley Pump substation to a new site away from Yellowstone River and replacement of the Shirley Pump substation transformer. Description of Proposed Action: Move the existing Shirley Pump substation approximately 200 meters to the southeast away from its current location and the Yellowstone River as well as replace the aging transformer with a new one. Number and Title of Categorical Exclusions Being Applied: 10 CPR 1021.410 Subpart D, Appendix B, B4.11: Construction of electric power substations ... or modification of existing substations and support facilities. Regulatory Requirements for CX Determination: The DOE Guidelines for Compliance with the Regulatory Requirements for the National Environmental Policy Act at 10 CPR 1021.41 O(b),

428

Measurement and Modeling Implications of Transfer and Transformation  

NLE Websites -- All DOE Office Websites (Extended Search)

Measurement and Modeling Implications of Transfer and Transformation Measurement and Modeling Implications of Transfer and Transformation Processes at the Plant/Air Interface Speaker(s): Randy Maddalena Date: October 13, 1998 - 12:00pm Location: 90-3122 Seminar Host/Point of Contact: Richard Sextro To understand the chemodynamic role of vegetation in a multimedia system, the rate and extent of chemical partitioning from adjacent environmental media and the rate of chemical transformation associated with vegetation need to be determined. An exposure system was used to isolate and expose above ground vegetation to semi-volatile air contaminants. Measurements of phenanthrene, anthracene, fluoranthene and pyrene in the chamber air and the plant tissue were collected during both the uptake and clearance phase of exposure events. The measurements were fitted to the mass balance of the

429

IN SITU STUDIES ON THE CATALYTIC AND ELECTRONIC PROPERTIES OF MULTI-DIMENSIONAL CATHODE  

DOE Green Energy (OSTI)

The overall objective of this program was to provide the fundamental background to enable SECA Industrial Team Members to select and develop oxide cathodes for the operation of solid oxide fuel cells in the intermediate temperature (500-700 C). A number of experimental techniques were used to address the specific obstacles within the program. The work expanded our existing experimental techniques to the use of in situ diffraction and spectroscopic techniques that are sensitive to the oxygen and iron structural and chemical environment. Such measurements were coupled with the evaluation and determination of the catalytic properties of potential cathode oxides. The scope of the work was to prepare carefully controlled cathode samples of various compositions and microstructure and perform fundamental measurements of their physical properties. The measurement of physical properties of the cathode materials systems were used to correlate those properties to the overall effectiveness of the material as a constituent of an SOFC cell. The measurements techniques of neutron scattering and Moessbauer are relatively unique capabilities which have significance to the LSCF cathode system. The unique ability to make thin film samples can provide special samples for surface science efforts to understand cathodic catalytic activity. The data obtained from neutron diffraction, Moessbauer Spectroscopy, electrical measurements and modeling show that the oxygen vacancy content at 500 C in air for La{sub 0.8}Sr{sub 0.2}MnO{sub 3}, La{sub 0.6}Sr{sub 0.4}FeO{sub 3} and La{sub 0.6}Sr{sub 0.4}Fe{sub 0.8}Co{sub 0.2}O{sub 3-{delta}} are 0, 1% and 5% respectively. This is a significant finding that should relate to performance as a cathode, and gives criteria for the selection of new cathode materials.

Harlan U. Anderson

2003-12-01T23:59:59.000Z

430

Catalytic hydrocarbon reactions over supported metal oxides. Progress report, April 1, 1994--January 31, 1995  

DOE Green Energy (OSTI)

Oxide catalysis plays a central role in hydrocarbon processing and improvements in catalytic activity or selectivity are of great technological importance because these improvements will translate directly into more efficient utilization of hydrocarbon supplies and lower energy consumption in separation processes. An understanding of the relationships between surface structure and catalytic properties is needed to describe and improve oxide catalysts. Our approach has been to prepare supported oxides that have a specific structure and oxidation state and then employ these structures in reaction studies. Our current research program is focused on studying the fundamental relationships between structure and reactivity for two important reactions that are present in many oxide-catalyzed processes, partial oxidation and carbon-carbon bond formation. Oxide catalysis can be a complex process with both metal cation and oxygen anions participating in the chemical reactions. From an energy perspective carbon-carbon bond formation is particularly relevant to CO hydrogenation in isosynthesis. Hydrogenolysis and hydrogenation form the basis for heteroatom removal in fuels processing. Understanding the catalysis of these processes (and others) requires isolating reaction steps in the overall cycle and determining how structure and composition influence the individual reaction steps. Specially designed oxides, such as we use, permit one to study some of the steps in oxidation, carbon-carbon coupling and heteroatom removal catalysis. During the course of our studies we have: (1) developed methods to form and stabilize various Mo and W oxide structures on silica; (2) studied C-H abstraction reactions over the fully oxidized cations; (3) studied C-C bond coupling by methathesis and reductive coupling of aldehydes and ketones over reduced cation structures; and (4) initiated a study of hydrogenation and hydrogenolysis over reduced cation structures.

Ekerdt, J.G.

1995-01-31T23:59:59.000Z

431

Catalytic combustor for integrated gasification combined cycle power plant  

DOE Patents (OSTI)

A gasification power plant 10 includes a compressor 32 producing a compressed air flow 36, an air separation unit 22 producing a nitrogen flow 44, a gasifier 14 producing a primary fuel flow 28 and a secondary fuel source 60 providing a secondary fuel flow 62 The plant also includes a catalytic combustor 12 combining the nitrogen flow and a combustor portion 38 of the compressed air flow to form a diluted air flow 39 and combining at least one of the primary fuel flow and secondary fuel flow and a mixer portion 78 of the diluted air flow to produce a combustible mixture 80. A catalytic element 64 of the combustor 12 separately receives the combustible mixture and a backside cooling portion 84 of the diluted air flow and allows the mixture and the heated flow to produce a hot combustion gas 46 provided to a turbine 48. When fueled with the secondary fuel flow, nitrogen is not combined with the combustor portion.

Bachovchin, Dennis M. (Mauldin, SC); Lippert, Thomas E. (Murrysville, PA)

2008-12-16T23:59:59.000Z

432

Intensified Fischer-Tropsch Synthesis Process with Microchannel Catalytic Reactors  

SciTech Connect

A microchannel catalytic reactor with improved heat and mass transport has been used for Fischer-Tropsch synthesis to produce fuels and chemicals. This type of novel reactor takes advantages of highly active and selective catalysts with increased site density so that the FT synthesis process can be intensified. It was demonstrated that this microchannel reactor based process can be carried out at gas hourly space velocity (GHSV) as high as 60,000 hr-1 to achieve greater than 60% of one-pass CO conversion while maintaining low methane selectivity (<10%) and high chain growth probability(>0.9). Such superior FT synthesis performance has not ever been reported in the prior open literatures. The overall productivity to heavy hydrocarbons has been significantly improved over the conventional reactor technology. In this study, performance data were obtained in a wide range of pressure (10atm-35atm) and hydrogen to carbon monoxide ratio (1-2.5). The catalytic system was characterized by BET, scanning electron microcopy (SEM), transmission electron microcopy(TEM), and H2 chemisorption. A three dimensional pseudo-homogeneous model were used to simulate temperature profiles in the exothermic reaction system in order to optimize the reactor design and intensify the synthesis process. Intraparticle non-isothermal characteristics are also analyzed for the FT synthesis catalyst.

Cao, Chunshe; Hu, Jianli; Li, Shari; Wilcox, Wayne A.; Wang, Yong

2009-02-28T23:59:59.000Z

433

An Exploration of Catalytic Chemistry on Au/Ni(111)  

Science Conference Proceedings (OSTI)

This project explored the catalytic oxidation chemistry that can be effected on a Au/Ni(111) surface alloy. A Au/Ni(111) surface alloy is a Ni(111) surface on which less than 60% of the Ni atoms are replaced at random positions by Au atoms. The alloy is produced by vapor deposition of a small amount of Au onto Ni single crystals. The Au atoms do not result in an epitaxial Au overlayer or in the condensation of the Au into droplets. Instead, Au atoms displace and then replace Ni atoms on a Ni(111) surface, even though Au is immiscible in bulk Ni. The two dimensional structure of the clean Ni surface is preserved. This alloy is found to stabilize an adsorbed peroxo-like O2 species that is shown to be the critical reactant in the low temperature catalytic oxidation of CO and that is suspected to be the critical reactant in other oxidation reactions. This investigation revealed a new, practically important catalyst for CO oxidation that has since been patented.

Sylvia T. Ceyer

2011-12-09T23:59:59.000Z

434

Design of Catalytic Materials for Plasma Assisted Catalysis System  

DOE Green Energy (OSTI)

In recent years, the Plasma Assisted Catalysis (PAC) approach for controlling NOx and/or particulate emissions from mobile diesel engines has received a significant amount of attention from researchers. Substantial work has been performed by various researchers to develop an understanding of the reaction mechanisms in a plasma reactor in conjunction with conventional lean-NOx catalyst materials. However, less effort has been devoted to systematically investigating new catalyst materials specifically designed for application in the PAC system. Since it is believed that plasma produces a unique environment for a catalyst bed (i.e. oxidation of NO to NO2 and partial oxidation/reforming of hydrocarbon reductants in the exhaust), new catalytic materials that take advantage of the plasma reactor conditions need to be studied. Optimum catalyst materials will be required in order to develop a PAC system that achieves maximum deNOx performance over the wide range of operating conditions in which the system will be required to operate for application on heavy duty diesel engines. This presentation discusses the issues involved in designing catalytic materials for achieving high NOx conversion in a laboratory test PAC system, and what is required to improve the catalyst materials further for application in an on-engine environment.

Park, Paul W.

2000-08-20T23:59:59.000Z

435

Novel Sensor for Transformer Diagnosis  

Science Conference Proceedings (OSTI)

This report details the progress made in the detection of acetylene and hydrogen gas dissolved in oil using novel methods of optical fiber sensing. Of note in this report are the sensitivity and resolution enhancements of the two sensing methods as well as the construction of a field-testable prototype. The sensor’s non-sensitivity to several other gases commonly found in insulating transformer oil is also described. With some further development, the resolution of gas detection can still be ...

2012-12-12T23:59:59.000Z

436

Entanglement transformations using separable operations  

E-Print Network (OSTI)

We study conditions for the deterministic transformation $\\ket{\\psi}\\longrightarrow\\ket{\\phi}$ of a bipartite entangled state by a separable operation. If the separable operation is a local operation with classical communication (LOCC), Nielsen's majorization theorem provides necessary and sufficient conditions. For the general case we derive a necessary condition in terms of products of Schmidt coefficients, which is equivalent to the Nielsen condition when either of the two factor spaces is of dimension 2, but is otherwise weaker. One implication is that no separable operation can reverse a deterministic map produced by another separable operation, if one excludes the case where the Schmidt coefficients of $\\ket{\\psi}$ and are the same as those of $\\ket{\\phi}$. The question of sufficient conditions in the general separable case remains open. When the Schmidt coefficients of $\\ket{\\psi}$ are the same as those of $\\ket{\\phi}$, we show that the Kraus operators of the separable transformation restricted to the supports of $\\ket{\\psi}$ on the factor spaces are proportional to unitaries. When that proportionality holds and the factor spaces have equal dimension, we find conditions for the deterministic transformation of a collection of several full Schmidt rank pure states $\\ket{\\psi_j}$ to pure states $\\ket{\\phi_j}$.

Vlad Gheorghiu; Robert B. Griffiths

2007-05-02T23:59:59.000Z

437

97e Intermediate Temperature Catalytic Reforming of Bio-Oil for Distributed Hydrogen Production  

Science Conference Proceedings (OSTI)

With the world's energy demands rapidly increasing, it is necessary to look to sources other than fossil fuels, preferably those that minimize greenhouse emissions. One such renewable source of energy is biomass, which has the added advantage of being a near-term source of hydrogen. While there are several potential routes to produce hydrogen from biomass thermally, given the near-term technical barriers to hydrogen storage and delivery, distributed technologies such that hydrogen is produced at or near the point of use are attractive. One such route is to first produce bio-oil via fast pyrolysis of biomass close to its source to create a higher energy-density product, then ship this bio-oil to its point of use where it can be reformed to hydrogen and carbon dioxide. This route is especially well suited for smaller-scale reforming plants located at hydrogen distribution sites such as filling stations. There is also the potential for automated operation of the conversion system. A system has been developed for volatilizing bio-oil with manageable carbon deposits using ultrasonic atomization and by modifying bio-oil properties, such as viscosity, by blending or reacting bio-oil with methanol. Non-catalytic partial oxidation of bio-oil is then used to achieve significant conversion to CO with minimal aromatic hydrocarbon formation by keeping the temperature at 650 C or less and oxygen levels low. The non-catalytic reactions occur primarily in the gas phase. However, some nonvolatile components of bio-oil present as aerosols may react heterogeneously. The product gas is passed over a packed bed of precious metal catalyst where further reforming as well as water gas shift reactions are accomplished completing the conversion to hydrogen. The approach described above requires significantly lower catalyst loadings than conventional catalytic steam reforming due to the significant conversion in the non-catalytic step. The goal is to reform and selectively oxidize the bio-oil and catalyze the water gas shift reaction without catalyzing methanation or oxidation of CO and H{sub 2}, thus attaining equilibrium levels of H{sub 2}, CO, H{sub 2}O, and CO{sub 2} at the exit of the catalyst bed. Experimental Bio-oil (mixed with varied amounts of methanol to reduce the viscosity and homogenize the bio-oil) or selected bio-oil components are introduced at a measured flow rate through the top of a vertical quartz reactor which is heated using a five zone furnace. The ultrasonic nozzle used to feed the reactants allows the bio-oil to flow down the center of the reactor at a low, steady flow rate. Additionally, the fine mist created by the nozzle allows for intimate mixing with oxygen and efficient heat transfer, providing optimal conditions to achieve high conversion at relatively low temperatures in the non-catalytic step thus reducing the required catalyst loading. Generation of the fine mist is especially important for providing good contact between non-volatile bio-oil components and oxygen. Oxygen and helium are also delivered at the top of the reactor via mass flow meters with the amount of oxygen being varied to maximize the yields of H{sub 2} and CO and the amount of helium being adjusted such that the gas phase residence time in the hot zone is {approx}0.3 and {approx}0.45 s for bio-oil and methanol experiments, respectively. A catalyst bed can be located at the bottom of the reactor tube. To date, catalyst screening experiments have used Engelhard noble metal catalysts. The catalysts used for these experiments were 0.5 % rhodium, ruthenium, platinum, and palladium (all supported on alumina). Experiments were performed using pure alumina as well. Both the catalyst type and the effect of oxygen and steam on the residual hydrocarbons and accumulated carbon containing particulates were investigated. The residence time before the catalyst is varied to determine the importance of the non-catalytic step and its potential effect on the required catalyst loading. Non-catalytic experiments (primarily homogeneous cracking) use a bed of quartz p

Marda, J. R.; Dean, A. M.; Czernik, S.; Evans, R. J.; French, R.; Ratcliff, M.

2008-01-01T23:59:59.000Z

438

Nonlinear transform coding with lossless polar coordinates  

E-Print Network (OSTI)

In conventional transform coding, the importance of preserving desirable quantization partition cell shapes prevents one from considering the use of a nonlinear change of variables. If no linear transformation of a given ...

Ba, Demba Elimane

2006-01-01T23:59:59.000Z

439

Transforms for prediction residuals in video coding  

E-Print Network (OSTI)

Typically the same transform, the 2-D Discrete Cosine Transform (DCT), is used to compress both image intensities in image coding and prediction residuals in video coding. Major prediction residuals include the motion ...

Kam??l?, Fatih

2010-01-01T23:59:59.000Z

440

Numerical Transform Inversion Using Gaussian Quadrature  

Science Conference Proceedings (OSTI)

Numerical inversion of Laplace transforms is a powerful tool in computational probability. It greatly enhances the applicability of stochastic models in many fields. In this article we present a simple Laplace transform inversion algorithm that can compute ...

Peter Den Iseger

2006-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "determination catalytic transformation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Vertical Normal Mode Transforms: Theory and Application  

Science Conference Proceedings (OSTI)

The separation of the vertical structure of the, solutions of the primitive (hydrostatic) meteorological equations is formalized as a vertical normal-mode transform. The transform is implemented for arbitrary static stability profiles by the ...

Scott R. Fulton; Wayne H. Schubert

1985-04-01T23:59:59.000Z

442

Emissions Tradeoffs Between Boiler Operations and a Selective Catalytic Reduction System: Field Test Results on an 850-MW Opposed-Wall Design Unit  

Science Conference Proceedings (OSTI)

Burning low-cost, high-sulfur coals under staged combustion conditions can lead to increased waterwall wastage. Utilities are thus in need of a method for determining the least-cost approach for minimizing nitrogen oxide (NOx) through both boiler and selective catalytic reduction (SCR) operations, while taking into account potential cost impacts of various operating scenarios. This report is one in an EPRI series to quantify the costs and benefits associated with different boiler and SCR ...

2013-06-25T23:59:59.000Z

443

A Fuzzy-Neural Technique for Flashover Diagnosis of Winding Insulation in Transformers  

Science Conference Proceedings (OSTI)

A Fuzzy-Neural pattern recognition technique for insulation flashover diagnosis in oil filled power transformers has been described in the paper. Determination of exact nature and location of internal insulation flashover during impulse testing of power ...

Abhinandan De; Nirmalendu Chatterjee

2002-02-01T23:59:59.000Z

444

On the Minkowski-Funk Transform  

E-Print Network (OSTI)

The subject of this paper is the history of the Minkowski-Funk Transform. After introducing the Minkowski-Funk Transform as well as its dual transform and a generalization of both, we will present an inversion formula of the Minkowski-Funk Transform. Then we will discuss the history of this problem: related work by Minkowski and Funk and the connection between their work.

Dann, Susanna

2010-01-01T23:59:59.000Z

445

Computational Thermodynamics and Phase Transformations - TMS  

Science Conference Proceedings (OSTI)

May 1, 2007 ... Computational Thermodynamics and Phase Transformations ... Computation also provides a powerful tool for increasing basic understanding ...

446

Catalyst-assisted Probabilistic Entanglement Transformation  

E-Print Network (OSTI)

We are concerned with catalyst-assisted probabilistic entanglement transformations. A necessary and sufficient condition is presented under which there exist partial catalysts that can increase the maximal transforming probability of a given entanglement transformation. We also design an algorithm which leads to an efficient method for finding the most economical partial catalysts with minimal dimension. The mathematical structure of catalyst-assisted probabilistic transformation is carefully investigated.

Yuan Feng; Runyao Duan; Mingsheng Ying

2004-04-27T23:59:59.000Z

447

Mild Catalytic methods for Alkyl-Alkyl Bond Formation  

DOE Green Energy (OSTI)

Overview of Research Goals and Accomplishments for the Period 07/01/06 – 06/30/07: Our overall research goal is to transform the rapidly emerging synthetic chemistry involving alkyl-alkyl cross-couplings into more of a mechanism-based field so that that new, rationally-designed catalysts can be performed under energy efficient conditions. Our specific objectives for the previous year were 1) to obtain a proper electronic description of an active catalyst for alkyl-alkyl cross-coupling reactions and 2) to determine the effect of ligand structure on the rate, scope, selectivity, and functional group compatibility of C(sp3)-C(sp3) cross-coupling catalysis. We have completed both of these initial objectives and established a firm base for further studies. The specific significant achievements of the current grant period include: 1) we have performed magnetic and computational studies on (terpyridine)NiMe, an active catalyst for alkyl-alkyl cross couplings, and have discovered that the unpaired electron resides heavily on the terpyridine ligand and that the proper electronic description of this nickel complex is a Ni(II)-methyl cation bound to a reduced terpyridine ligand; 2) we have for the first time shown that alkyl halide reduction by terpyridyl nickel catalysts is substantially ligand based; 3) we have shown by isotopic labeling studies that the active catalyst (terpyridine)NiMe is not produced via a mechanism that involves the formation of methyl radicals when (TMEDA)NiMe2 is used as the catalyst precursor; 4) we have performed an extensive ligand survey for the alkyl-alkyl cross-coupling reactions and have found that electronic factors only moderately influence reactivity in the terpyridine-based catalysis and that the most dramatic effects arise from steric and solubility factors; 5) we have found that the use of bis(dialkylphosphino)methanes as ligands for nickel does not produce active catalysts for cross-coupling but rather leads to bridging hydride complexes of varying geometries; 6) we have determined that the geometry of aforementioned bridging hydride complexes is largely determined by external forces such as hydrogen bonding interactions and crystal packing forces; 7) we have found that the rate of reductive elimination of alkane from a (pyridyl-2-pyrrolide)AuMe2 complex is severely inhibited due to the rigid geometry of the pyridyl-2-pyrrolide ligand; 8) we have prepared, structurally characterized, and explored the reactivity of 1-adamantylzinc reagents as model nucleophiles for sterically challenging alkyl-alkyl cross-coupling reactions. The continued success of this work will lead to alkyl-alkyl cross-coupling catalysts with broad scope and selectivities. The work has potential to significantly impact science and technologies of interest to the DOE as the chemistry is focused on developing useful reactions using reagents that can be directly prepared from petroleum and natural gas feedstocks. Moreover, the developing synthetic chemistry can profoundly affect the way materials, fine chemicals, and drugs are made. Since the methodology we are developing can shorten existing synthetic protocols, proceed at room temperature, and operate under environmentally benign conditions, it can greatly reduce energy expenditures, especially considering the contribution of the chemical manufacturing field to the gross domestic product.

David A Vicic

2009-08-10T23:59:59.000Z

448

Simulation of Top Oil Temperature for Transformers  

E-Print Network (OSTI)

Simulation of Top Oil Temperature for Transformers Masters Thesis and Final Project Report Power-Oil Temperature for Transformers Thesis and Final Report Yong Liang PSERC Publication 01-21 February 2001 #12 for the PSERC project "On-Line Peak Loading of Substation Distribution Transformers Through Accurate Temperature

449

Canonical transformations for fermions in superanalysis  

E-Print Network (OSTI)

Canonical transformations (Bogoliubov transformations) for fermions with an infinite number of degrees of freedom are studied within a calculus of superanalysis. A continuous representation of the orthogonal group is constructed on a Grassmann module extension of the Fock space. The pull-back of these operators to the Fock space yields a unitary ray representation of the group that implements the Bogoliubov transformations.

Joachim Kupsch

2013-04-08T23:59:59.000Z

450

Transformation Optics in Nonvacuum Initial Dielectric Media  

E-Print Network (OSTI)

Previous formulations of transformation optics have generally been restricted to transformations from relatively simple initial media, such as the vacuum, because of limitations due to their non-covariance. I show that a completely covariant approach enables arbitrary transformations from arbitrarily complex initial linear dielectrics.

Thompson, Robert T

2010-01-01T23:59:59.000Z

451

AALBORGUNIVERSITY DEPARTMENTOFENERGY TECHNOLOGY Transformer in series  

E-Print Network (OSTI)

AALBORGUNIVERSITY­ DEPARTMENTOFENERGY TECHNOLOGY Transformer in series Filipe Miguel Faria Da that corresponds to a neighbour transformer. Both loads are 3-phase loads, which can be unbalanced to generated. The harmonics are generated inside the farm, thus, the current source is grounded at the transformer's neutral

Silva, Filipe Faria Da

452

Gravity Transform for Input Conditioning in  

E-Print Network (OSTI)

Gravity Transform for Input Conditioning in Brain Machine Interfaces António R. C. Paiva, José C. Motivation 2. Methods i. Gravity Transform ii. Modeling and output sensitivity analysis 3. Data Analysis #12;3 Outline 1. Motivation 2. Methods i. Gravity Transform ii. Modeling and output sensitivity analysis 3. Data

Paiva, António R. C.

453

Moment invariants to affine transformation of colours  

Science Conference Proceedings (OSTI)

Most colour descriptors are not robust because they are constructed for simple colour transformations, such as a diagonal-offset transformation. In this paper, a type of colour descriptor is proposed which is composed of rational expression of moments ... Keywords: Affine transformation, Colour, Image retrieval, Moment invariants, Pattern recognition

Ming Gong, Hua Li, Weiguo Cao

2013-08-01T23:59:59.000Z

454

A nonlinear lumped parameter model for transient studies of single-phase core form transformers  

Science Conference Proceedings (OSTI)

Power transformers, in service, are subjected to voltage transients. The transformer insulation should be designed to withstand the internal stresses initiated by these transients. To determine these stresses during the design stage, lumped parameter models of the transformer are employed. Computer models are the best tools for predetermination of these stresses. To date, in spite of the great efforts employed, lack of accurate and consistent transformer models are felt to contribute to the relatively high failure rate of the EHV transformers. This thesis is based on a detailed transformer model developed by G.E. for transformer insulation design. Although this model has provided the designer a suitable tool for transient study during design stage, it assumed a linear characteristic for iron core and employed an empirical method to model damping effect of transformer losses. It is felt that the core`s non-linear magnetic characteristic has an appreciable effect on the transformers transient response. This thesis develops a detailed transformer model which accurately models the nonlinear, saturable, characteristic of transformer magnetic core. The model is based on linearization of the core`s saturable characteristic during each time interval of solution. Then the linear model is solved within that interval and based on the magnetizing flux in the core, the inductance model is adjusted for the next time interval of solution, and the updated linear model is solved for the interval. A stable solution routine is developed to solve the nonlinear model`s system of O.D.E.`s. Supplementary features needed for transformer design such as external circuits, switches and nonlinear resistors are developed for this solution routine. The necessary methods are developed for verification of the linear transformer model in the frequency domain.

Vakilian, M.

1993-12-31T23:59:59.000Z

455

Deactivation and regeneration of ZSM-5 zeolite in catalytic pyrolysis of plastic wastes  

Science Conference Proceedings (OSTI)

Highlights: > Pyrolysis transforms plastic wastes in valuable liquids and gases useful as fuels or source of chemicals. > The use of ZSM-5 zeolite in pyrolysis favours the production of gases and of lighter and more aromatic liquids. > ZSM-5 zeolite is almost completely deactivated after one plastics pyrolysis experiment. > ZSM-5 zeolite used in plastic wastes pyrolysis can be regenerated by burning the deposited coke in an air stream. > Regenerated ZSM-5 recovers its activity and produces liquids and gases equivalent to those obtained with fresh catalyst. - Abstract: In this work, a study of the regeneration and reuse of ZSM-5 zeolite in the pyrolysis of a plastic mixture has been carried out in a semi-batch reactor at 440 deg. C. The results have been compared with those obtained with fresh-catalyst and in non-catalytic experiments with the same conditions. The use of fresh catalyst produces a significant change in both the pyrolysis yields and the properties of the liquids and gases obtained. Gases more rich in C3-C4 and H{sub 2} are produced, as well as lower quantities of aromatic liquids if compared with those obtained in thermal decomposition. The authors have proved that after one pyrolysis experiment the zeolite loses quite a lot of its activity, which is reflected in both the yields and the products quality; however, this deactivation was found to be reversible since after regeneration heating at 550 deg. C in oxygen atmosphere, this catalyst recovered its initial activity, generating similar products and in equivalent proportions as those obtained with fresh catalyst.

Lopez, A., E-mail: alex.lopez@ehu.es [Chemical and Environmental Engineering Department, School of Engineering of Bilbao, Alameda Urquijo s/n, 48013 Bilbao (Spain); Marco, I. de; Caballero, B.M.; Adrados, A.; Laresgoiti, M.F. [Chemical and Environmental Engineering Department, School of Engineering of Bilbao, Alameda Urquijo s/n, 48013 Bilbao (Spain)

2011-08-15T23:59:59.000Z

456

Research on Algae Removal by Electro-flotation/Photo-catalytic Oxidization Combined Process  

Science Conference Proceedings (OSTI)

The lake-type raw water was treated in Photo-catalytic Oxidization reactor. Under the condition of the inflow discharge control in 15L/h, the padding packing compares 2/5, UV lamp 30W, added no chemicals, pH 7.35, use the electro-flotation to treat it ... Keywords: algae, Electro-flotation, photo-catalytic oxidization

Wang Liping; Jiang Weijuan; Gao Naiyun

2011-01-01T23:59:59.000Z

457

==================== !"#$%&'()*+,-+./,0)12 Development of Micro Ejector for Butane Catalytic Combustor  

E-Print Network (OSTI)

==================== !"#$%&'()*+,-+./,0)12 Development of Micro Ejector for Butane Catalytic Combustor ===== ==== !" = !" = = !" A micro ejector for butane catalytic combustor is investigated. Quasi-1 ejector that the volume flow rate of entrained air can reach 43 times the value of butane when the back

Kasagi, Nobuhide

458

Simulation and Optimization of the Stabilizer Tower Operation at Catalytic Reforming of Esfahan Oil Refining Company  

Science Conference Proceedings (OSTI)

Production of gasoline with low RVP specifications have made the operators of the catalytic reforming unit of Esfahan Oil refining company in Iran to apply new operating conditions. RVP is an abbreviation for Reid Vapor Pressure which is the vapor pressure ... Keywords: RVP, platformate, initial boiling point, catalytic reforming, distillation curve

Ali Izadyar; Bahram Hashemi Shahraki; Ahmad Shariati

2010-01-01T23:59:59.000Z

459

MEMS-based fuel cells with integrated catalytic fuel processor and method thereof  

Science Conference Proceedings (OSTI)

Described herein is a means to incorporate catalytic materials into the fuel flow field structures of MEMS-based fuel cells, which enable catalytic reforming of a hydrocarbon based fuel, such as methane, methanol, or butane. Methods of fabrication are also disclosed.

Jankowski, Alan F. (Livermore, CA); Morse, Jeffrey D. (Martinez, CA); Upadhye, Ravindra S. (Pleasanton, CA); Havstad, Mark A. (Davis, CA)

2011-08-09T23:59:59.000Z

460

Control of Natural Gas Catalytic Partial Oxidation for Hydrogen Generation in Fuel Cell Applications1  

E-Print Network (OSTI)

Control of Natural Gas Catalytic Partial Oxidation for Hydrogen Generation in Fuel Cell Ghosh3 , Huei Peng2 Abstract A fuel processor that reforms natural gas to hydrogen-rich mixture to feed of the hydrogen in the fuel processor is based on catalytic partial oxidation of the methane in the natural gas

Peng, Huei

Note: This page contains sample records for the topic "determination catalytic transformation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
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461

Catalytic studies of supported Pd-Au catalysts  

E-Print Network (OSTI)

Although Pd-Au high-surface area catalysts are used in industry to improve activity and selectivity, a thorough understanding of the nature of these enhancements is lacking. A molecular-level understanding of catalytic reactions under actual reaction conditions is the ultimate goal. This thesis is mainly focused on the application of Pd-Au supported catalysts for vinyl acetate synthesis and CO oxidation reactions using highsurface area catalysts. We have attempted to improve the conventional Pd-Au based catalyst by synthesizing novel acetate-based and polymer-based catalysts. The corresponding catalytic reactivity and selectivity were measured and compared to conventional Pd-Au based catalyst systems. Subsequent characterization was performed using characterization techniques, such as, X-ray diffraction (XRD) and transmission electron microscopy (TEM). From our bimetallic catalytic studies, it was evident that the addition of Au to Pd leads to increased reactivity and selectivity. This surface modification is an important factor in the altered reaction kinetics for vinyl acetate (VA) synthesis and CO oxidation reactions. Promoted and unpromoted Pd-Au/SiO2/K+ catalyst were used for VA synthesis and the effect of pre-adsorbed O2, acetic acid and the role of oxygen were explored. The VA reaction rate of novel acetate-based Pd-Au/SiO2 catalyst was 3.5 times higher than conventional Pd-Au catalysts. Also, 100% selectivity was obtained for acetate-based Pd-Au/SiO2 at 130 oC and the VA formation rate was comparable to that of conventional Pd-Au catalysts. Therefore, the acetate-based Pd-Au/SiO2 catalyst seems very promising and can be explored further. Also, Pd(1):Au(4)/SiO2 catalysts demonstrate 100% CO conversion at much lower temperatures (90 oC) compared with other Pd-Au based catalysts. Furthermore, we were successful in obtaining sufficient CO oxidation activity with increased metal loading (5 wt%) and these catalysts did not deactivate under above-ambient reaction temperature conditions, which make 1:4 Pd- Au/SiO2 catalyst a good candidate for further exploration in CO oxidation reactions.

Boopalachandran, Praveenkumar

462

A Superconducting transformer system for high current cable testing  

E-Print Network (OSTI)

A Superconducting Transformer System for High Current CableDC) superconducting transformer system for the high currentsuperconducting cables. The transformer consists of a core-

Godeke, A.

2010-01-01T23:59:59.000Z

463

Feasibility of SF6 Gas-Insulated Transformers  

NLE Websites -- All DOE Office Websites (Extended Search)

Gas-insulated transformers (GIT) Gas-insulated transformer benefits Gas-insulated transformer concerns Risks and Unknowns Questions? BUILDING STRONG PORTLAND...

464

A Novel Discriminative Approach Based on Hidden Markov Models and Wavelet Transform to Transformer Protection  

Science Conference Proceedings (OSTI)

In this paper we present a combinatorial scheme based on hidden Markov models (HMM) and wavelet transform (WT) to discriminate between magnetizing inrush currents and internal faults in power transformers. HMMs are powerful tools for transient classification ... Keywords: differential protection, discrete hidden Markov models, discrete wavelet transform, inrush current, internal fault, power transformer, signal classification.

Saeed Jazebi; Behrooz Vahidi; Seyed Hossein Hosseinian

2010-02-01T23:59:59.000Z

465

Grid Transformation Workshop Results Grid Transformation Workshop Results 2 April 2012  

E-Print Network (OSTI)

Grid Transformation Workshop Results April 2012 #12;Grid Transformation Workshop Results 2 April 2012 Grid Transformation Workshop Results plications. We will explore the basics of data modeling Transformation Workshop: Advanced Reading Material Product ID 1024659. The material in this report builds upon

466

CX-006289: Categorical Exclusion Determination | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

289: Categorical Exclusion Determination 289: Categorical Exclusion Determination CX-006289: Categorical Exclusion Determination Willow Creek Substation -Transformer Replacement and Substation Modifications CX(s) Applied: B4.6 Date: 07/26/2011 Location(s): Grand County, Colorado Office(s): Western Area Power Administration-Rocky Mountain Region Western Area Power Administration (Western) proposes to make modifications to the Willow Creek Substation, near Grand Lake, Grand County, Colorado. The project includes removing two existing transformers and replacing them with one larger transformer. DOCUMENT(S) AVAILABLE FOR DOWNLOAD CX-006289.pdf More Documents & Publications CX-009235: Categorical Exclusion Determination CX-006280: Categorical Exclusion Determination EIS-0400: Draft Environmental Impact Statement

467

Backlund Transformations for Darboux Integrable Differential Systems  

E-Print Network (OSTI)

We give a new mechanism for constructing Backlund transformations by using symmetry reduction of differential systems. We then characterize a family of Backlund transformations between Darboux integrable systems where the Backlund transformation can be constructed by the proposed symmetry reduction method. It is then shown that the well-known Backlund transformations between Darboux integrable Monge-Ampere systems can all be constructed using group quotients. A simple group theoretical argument leads to a non-existence result for Backlund transformations which disagrees with Theorem 1 in arXiv:0707.4408v2. A variety of examples are given.

Anderson, Ian M

2011-01-01T23:59:59.000Z

468

Gale transform of a starshaped sphere  

E-Print Network (OSTI)

Gale transform is a simple but powerful tool in convex geometry. In particular, the use of Gale transform is the main argument in the classification of polytopes with few vertices. Many books and documents cover the definition of Gale transform and its main properties related to convex polytopes. But it seems that there does not exist document studying the Gale transform of more general objects, such that triangulation of spheres. In this paper, we study the properties of the Gale transform of a large class of such spheres called starshaped spheres.

Tambour, Jerome

2012-01-01T23:59:59.000Z

469

Microsoft Word - 41891_SWPC_Catalytic Combustor_Factsheet_Rev01_04-24.doc  

NLE Websites -- All DOE Office Websites (Extended Search)

891_SWPC_CATALYTIC COMBUSTOR_FACTSHEET_REV01_04-24.DOC 891_SWPC_CATALYTIC COMBUSTOR_FACTSHEET_REV01_04-24.DOC Facts Sheet: Catalytic Combustor for Fuel Flexible Gas Turbine (DE-FC26-03NT41891) I. PROJECT PARTICIPANTS A. Siemens Westinghouse Power Corporation B. Caterpillar/Solar Turbine C. Penn State University D. Southern Company Services II. PROJECT DESCRIPTION A. Objective: To develop and demonstrate a cost effective, fuel flexible (syngas/natural gas) catalytic combustor that will achieve ultra low NOx emissions (2ppm) at the exit of the gas turbine and without the use of backend cleanup in Integrated Gasification Combined Cycle (IGCC) application. B. Background/Relevancy 1. Background: Catalytic combustion has been shown to achieve lowest emissions in conventional gas turbine application (natural gas only). Available technical data indicate that it can be effective

470

Catalytic carbon membranes for hydrogen production. Final report  

DOE Green Energy (OSTI)

Commercial carbon composite microfiltration membranes may be modified for gas separation applications by providing a gas separation layer with pores in the 1- to 10-nm range. Several organic polymeric precursors and techniques for depositing a suitable layer were investigated in this project. The in situ polymerization technique was found to be the most promising, and pure component permeation tests with membrane samples prepared with this technique indicated Knudsen diffusion behavior. The gas separation factors obtained by mixed-gas permeation tests were found to depend strongly on gas temperature and pressure indicating significant viscous flow at high-pressure conditions. The modified membranes were used to carry out simultaneous water gas shift reaction and product hydrogen separation. These tests indicated increasing CO conversions with increasing hydrogen separation. A simple process model was developed to simulate a catalytic membrane reactor. A number of simulations were carried out to identify operating conditions leading to product hydrogen concentrations over 90 percent. (VC)

Damle, A.S.; Gangwal, S.K.

1992-01-01T23:59:59.000Z

471

Catalytic Hydrogenation of Bio-Oil for Chemicals and Fuels  

DOE Green Energy (OSTI)

The scope of work includes optimizing processing conditions and demonstrating catalyst lifetime for catalyst formulations that are readily scaleable to commercial operations. We use a bench-scale, continuous-flow, packed-bed, catalytic, tubular reactor, which can be operated in the range of 100-400 mL/hr., from 50-400 C and up to 20MPa (see Figure 1). With this unit we produce upgraded bio-oil from whole bio-oil or useful bio-oil fractions, specifically pyrolytic lignin. The product oils are fractionated, for example by distillation, for recovery of chemical product streams. Other products from our tests have been used in further testing in petroleum refining technology at UOP and fractionation for product recovery in our own lab. Further scale-up of the technology is envisioned and we will carry out or support process design efforts with industrial partners, such as UOP.

Elliott, Douglas C.

2006-02-14T23:59:59.000Z

472

Catalytic Fast Pyrolysis for the Production of the Hydrocarbon Biofuels  

SciTech Connect

Catalytic fast pyrolysis is a promising technique for conversion of biomass into hydrocarbons for use as transportation fuels. For over 30 years this process has been studied and it has been demonstrated that oils can be produced with high concentrations of hydrocarbons and low levels of oxygen. However, the yields from this type of conversion are typically low and the catalysts, which are often zeolites, are quickly deactivated through coking. In addition, the hydrocarbons produced are primarily aromatic molecules (benzene, toluene, xylene) that not desirable for petroleum refineries and are not well suited for diesel or jet engines. The goals of our research are to develop new multifunction catalysts for the production of gasoline, diesel and jet fuel range molecules and to improve process conditions for higher yields and low coking rates. We are investigating filtration and the use of hydrogen donor molecules to improve catalyst performance.

Nimlos, M. R.; Robichaud, D. J.; Mukaratate, C.; Donohoe, B. S.; Iisa, K.

2013-01-01T23:59:59.000Z

473

Coal hydrogenation and deashing in ebullated bed catalytic reactor  

SciTech Connect

An improved process for hydrogenation of coal containing ash with agglomeration and removal of ash from an ebullated bed catalytic reactor to produce deashed hydrocarbon liquid and gas products. In the process, a flowable coal-oil slurry is reacted with hydrogen in an ebullated catalyst bed reaction zone at elevated temperature and pressure conditions. The upward velocity and viscosity of the reactor liquid are controlled so that a substantial portion of the ash released from the coal is agglomerated to form larger particles in the upper portion of the reactor above the catalyst bed, from which the agglomerated ash is separately withdrawn along with adhering reaction zone liquid. The resulting hydrogenated hydrocarbon effluent material product is phase separated to remove vapor fractions, after which any ash remaining in the liquid fraction can be removed to produce substantially ash-free coal-derived liquid products.

Huibers, Derk T. A. (Pennington, NJ); Johanson, Edwin S. (Princeton, NJ)

1983-01-01T23:59:59.000Z

474

Ex-Situ Catalytic Fast Pyrolysis Technology Pathway  

SciTech Connect

In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to hydrocarbon fuels to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This pathway case investigates converting woody biomass using ex-situ catalytic fast pyrolysis followed by upgrading to gasoline , diesel and jet range blendstocks . Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified.

Biddy, Mary J.; Dutta, Abhijit; Jones, Susanne B.; Meyer, Pimphan A.

2013-03-31T23:59:59.000Z

475

In-Situ Catalytic Fast Pyrolysis Technology Pathway  

SciTech Connect

In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to hydrocarbon fuels to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This pathway case investigates converting woody biomass using in-situ catalytic fast pyrolysis followed by upgrading to gasoline, diesel, and jet range blendstocks. Technical barriers and key research needs that should be pursued for this pathway to be competitive with petroleum-derived blendstocks have been identified.

Biddy, Mary J.; Dutta, Abhijit; Jones, Susanne B.; Meyer, Pimphan A.

2013-03-31T23:59:59.000Z

476

For stricter emissions needs, try custom catalytic reduction  

Science Conference Proceedings (OSTI)

When O`Brien California Cogen Ltd. was contracted to develop a system to generate steam for an Artesia, Calif., mild producer`s evaporation process, local regulations required NO{sub x} emissions reduced 9 ppm and CO to 10 ppm. Johnson Matthey supplied the solution with a custom system combining an oxidation catalyst to control CSO emissions and a selective catalytic reduction (SCR) system to control NO{sub x}. O`Brien`s cogen operation runs off an aircraft-derivative GE Gas Turbine, model LM2500, with a 22.4-MW output. The catalyst system is installed in the exhaust stream of a heat recovery steam generator (HRSG) form the Henry Vogt Machine Co.

Chambers, A.

1995-08-01T23:59:59.000Z

477

Method For Selective Catalytic Reduction Of Nitrogen Oxides  

DOE Patents (OSTI)

A method for catalytically reducing nitrogen oxide compounds (NO.sub.x, defined as nitric oxide, NO, +nitrogen dioxide, NO.sub.2) in a gas by a material comprising a base metal consisting essentially of CuO and Mn, and oxides of Mn, on an activated metal hydrous metal oxide support, such as HMO:Si. A promoter, such as tungsten oxide or molybdenum oxide, can be added and has been shown to increase conversion efficiency. This method provides good conversion of NO.sub.x to N.sub.2, good selectivity, good durability, resistance to SO.sub.2 aging and low toxicity compared with methods utilizing vanadia-based catalysts.

Mowery-Evans, Deborah L. (Broomfield, CO); Gardner, Timothy J. (Albuquerque, NM); McLaughlin, Linda I. (Albuquerque, NM)

2005-02-15T23:59:59.000Z

478

Method for selective catalytic reduction of nitrogen oxides  

DOE Patents (OSTI)

A method for catalytically reducing nitrogen oxide compounds (NO.sub.x, defined as nitric oxide, NO, +nitrogen dioxide, NO.sub.2) in a gas by a material comprising a base metal consisting essentially of CuO and Mn, and oxides of Mn, on an activated metal hydrous metal oxide support, such as HMO:Si. A promoter, such as tungsten oxide or molybdenum oxide, can be added and has been shown to increase conversion efficiency. This method provides good conversion of NO.sub.x to N.sub.2, good selectivity, good durability, resistance to SO.sub.2 aging and low toxicity compared with methods utilizing vanadia-based catalysts.

Mowery-Evans, Deborah L. (Broomfield, CO); Gardner, Timothy J. (Albuquerque, NM); McLaughlin, Linda I. (Albuquerque, NM)

2005-02-15T23:59:59.000Z

479

Removal of sulfur from recycle gas streams in catalytic reforming  

Science Conference Proceedings (OSTI)

This patent describes improvement in a process for catalytically reforming a hydrocarbonaceous feedstock boiling in the gasoline range, wherein the reforming is conducted in the presence of hydrogen in a reforming process unit under reforming conditions, the process unit comprised of serially connected reactors, each of the reactors containing a reforming catalyst, and which process unit also includes a regeneration circuit for regenerating the catalyst after it becomes coked, the regeneration comprising treatment with a sulfur containing gas, and which process unit also includes a gas/liquid separator wherein a portion of the gas is recycled and the remaining portion is collected as make-gas. The improvement comprises using a sulfur trap, containing a catalyst comprised of about 10 to about 70 wt. % nickel dispersed on a support, between the gas/liquid separator and the first reactor.

Boyle, J.P.

1991-08-27T23:59:59.000Z

480

Producing Clean Syngas via Catalytic Reforming for Fuels Production  

Science Conference Proceedings (OSTI)

Thermochemical biomass conversion to fuels and chemicals can be achieved through gasification to syngas. The biomass derived raw syngas contains the building blocks of carbon monoxide and hydrogen as well as impurities such as tars, light hydrocarbons, and hydrogen sulfide. These impurities must be removed prior to fuel synthesis. We used catalytic reforming to convert tars and hydrocarbons to additional syngas, which increases biomass carbon utilization. In this work, nickel based, fluidizable tar reforming catalysts were synthesized and evaluated for tar and methane reforming performance with oak and model syngas in two types of pilot scale fluidized reactors (recirculating and recirculating regenerating). Because hydrogen sulfide (present in raw syngas and added to model syngas) reacts with the active nickel surface, regeneration with steam and hydrogen was required. Pre and post catalyst characterization showed changes specific to the syngas type used. Results of this work will be discussed in the context of selecting the best process for pilot scale demonstration.

Magrini, K. A.; Parent, Y.; Jablonski, W.; Yung, M.

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "determination catalytic transformation" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Advances in the chemistry of catalytic reforming of naphtha  

Science Conference Proceedings (OSTI)

Catalytic reforming of naphtha remains the key process for production of high octane gasoline and aromatics (BTX) which are used as petrochemicals feedstocks. The increased demand for these products has led refiners to investigate ways for improving the performance of the reforming process and its catalysts. Moreover, in order to comply with environmental restrictions, the reduction in lead content would require further increase in the reformate octane number. In response to these requirements, refiners and catalyst manufacturers are examining the role of the catalysts in improving the selectivity to aromatics and in octane enhancement. By understanding the chemistry and the mechanism of the reforming process, higher performance catalysts with longer life on stream and lower cost can be developed. This review covers recent developments in reforming catalysts, process reaction chemistry and mechanism. It also highlights prospective areas of research.

Anabtawi, J.A.; Redwan, D.S.; Al-Jarallah, A.M.; Aitani, A.M. (Petroleum and Gas Technology Div., Research Inst., King Fahd Univ. of Petroleum and Minerals, Dhahran (SA))

1991-01-01T23:59:59.000Z

482

Separation of hydrogen from a catalytic reforming zone effluent stream  

Science Conference Proceedings (OSTI)

A process for the catalytic reforming of a hydrocarbonaceous feedstock at reforming conditions including a pressure of from about 50 to about 250 psig. Is disclosed. A portion of the hydrogen-rich vapor phase recovered from the reforming zone effluent at a relatively low pressure is compressed and recycled to the reforming zone without further purification. The balance of said hydrogen-rich vapor phase, or the net hydrogen, is compressed to a relatively high pressure and recontacted with at least a portion of the liquid hydrocarbon phase recovered from said low pressure separation to effect a further purification of said net hydrogen and to maximize the recovery of C/sub 3/-C/sub 6/+ the liquid phase.

Schmelzer, E.; Tagamolila, C.P.

1983-02-22T23:59:59.000Z

483

Applications and benefits of catalytic converter thermal management  

DOE Green Energy (OSTI)

A catalytic converter thermal management system (TMS) using variable-conductance vacuum insulation and phase-change thermal storage can maintain the converter temperature above its operating temperature for many hours, allowing most trips to begin with minimal ``cold-start`` emissions. The latest converter TMS prototype was tested on a Ford Taurus (3.0 liter flex-fuel engine) at Southwest Research Institute. Following a 24-hour soak, the FTP-75 emissions were 0.031, 0.13, and 0.066 g/mile for NMHC, CO, and NOx, respectively. Tests were also run using 85% ethanol (E85), resulting in values of 0.005, 0.124, and 0.044 g/mile, and 0.005 g/mile NMOG. Compared to the baseline FTP levels, these values represent reductions of 84% to 96% for NMHC, NMOG, and CO.

Burch, S.D.; Keyser, M.A.; Colucci, C.P.; Potter, T.F.; Benson, D.K.; Biel, J.P.

1996-07-01T23:59:59.000Z

484

Nonferromagnetic linear variable differential transformer  

DOE Patents (OSTI)

A nonferromagnetic linear variable differential transformer for accurately measuring mechanical displacements in the presence of high magnetic fields is provided. The device utilizes a movable primary coil inside a fixed secondary coil that consists of two series-opposed windings. Operation is such that the secondary output voltage is maintained in phase (depending on polarity) with the primary voltage. The transducer is well-suited to long cable runs and is useful for measuring small displacements in the presence of high or alternating magnetic fields.

Ellis, James F. (Powell, TN); Walstrom, Peter L. (Oak Ridge, TN)

1977-06-14T23:59:59.000Z

485

High flux solar energy transformation  

DOE Patents (OSTI)

Disclosed are multi-stage systems for high flux transformation of solar energy allowing for uniform solar intensification by a factor of 60,000 suns or more. Preferred systems employ a focusing mirror as a primary concentrative device and a non-imaging concentrator as a secondary concentrative device with concentrative capacities of primary and secondary stages selected to provide for net solar flux intensification of greater than 2000 over 95 percent of the concentration area. Systems of the invention are readily applied as energy sources for laser pumping and in other photothermal energy utilization processes. 7 figures.

Winston, R.; Gleckman, P.L.; O' Gallagher, J.J.

1991-04-09T23:59:59.000Z

486

High flux solar energy transformation  

DOE Patents (OSTI)

Disclosed are multi-stage systems for high flux transformation of solar energy allowing for uniform solar intensification by a factor of 60,000 suns or more. Preferred systems employ a focusing mirror as a primary concentrative device and a non-imaging concentrator as a secondary concentrative device with concentrative capacities of primary and secondary stages selected to provide for net solar flux intensification of greater than 2000 over 95 percent of the concentration area. Systems of the invention are readily applied as energy sources for laser pumping and in other photothermal energy utilization processes.

Winston, Roland (Chicago, IL); Gleckman, Philip L. (Chicago, IL); O' Gallagher, Joseph J. (Flossmoor, IL)

1991-04-09T23:59:59.000Z

487

The IHS Transformations Based Image Fusion  

E-Print Network (OSTI)

The IHS sharpening technique is one of the most commonly used techniques for sharpening. Different transformations have been developed to transfer a color image from the RGB space to the IHS space. Through literature, it appears that, various scientists proposed alternative IHS transformations and many papers have reported good results whereas others show bad ones as will as not those obtained which the formula of IHS transformation were used. In addition to that, many papers show different formulas of transformation matrix such as IHS transformation. This leads to confusion what is the exact formula of the IHS transformation?. Therefore, the main purpose of this work is to explore different IHS transformation techniques and experiment it as IHS based image fusion. The image fusion performance was evaluated, in this study, using various methods to estimate the quality and degree of information improvement of a fused image quantitatively.

Al-Wassai, Firouz Abdullah; Al-Zuky, Ali A

2011-01-01T23:59:59.000Z

488

Catalytic gasification studies in a pressurized fluid-bed unit  

DOE Green Energy (OSTI)

The purpose of the project is to evaluate the technical and economic feasibility of producing specific gas products via the catalytic gasification of biomass. This report presents the results of research conducted from October 1980 to November 1982. In the laboratory scale studis, active catalysts were developed for generation of synthesis gases from wood by steam gasification. A trimetallic catalyst, Ni-Co-Mo on silica-alumina doped with 2 wt % Na, was found to retain activity indefinitely for generation of a methanol synthesis gas from wood at 1380/sup 0/F (750/sup 0/C) and 1 atm (100 kPa) absolute pressure. Catalysts for generation of a methane-rich gas were deactivated rapidly and could not be regenerated as required for economic application. Sodium carbonate and potassium carbonate were effective as catalysts for conversion of wood to synthesis gases and methane-rich gas and should be economically viable. Catalytic gasification conditions were found to be suitable for processing of alternative feedstocks: bagasse, alfalfa, rice hulls, and almond hulls. The PDU was operated successfully at absolute pressures of up to 10 atm (1000 kPa) and temperatures of up to 1380/sup 0/F (750/sup 0/C). Yields of synthesis gases at elevated pressure were greater than those used for previous economic evaluations. A trimetallic catalyst, Ni-Cu-Mo on silica-alumina, did not display a long life as did the doped trimetallic catalyst used in laboratory studies. A computer program for a Radio Shack TRS-80 Model I microcomputer was developed to evaluate rapidly the economics of producing either methane or methanol from wood. The program is based on economic evaluations reported in previous studies. Improved yields from the PDU studies were found to result in a reduction of about 9 cents/gal in methanol cost.