National Library of Energy BETA

Sample records for determination baseload nitrate

  1. Baseload Nitrate Salt Central Receiver Power Plant Design Final Report

    SciTech Connect (OSTI)

    Tilley, Drake; Kelly, Bruce; Burkholder, Frank

    2014-12-12

    The objectives of the work were to demonstrate that a 100 MWe central receiver plant, using nitrate salt as the receiver coolant, thermal storage medium, and heat transport fluid in the steam generator, can 1) operate, at full load, for 6,400 hours each year using only solar energy, and 2) satisfy the DOE levelized energy cost goal of $0.09/kWhe (real 2009 $). To achieve these objectives the work incorporated a large range of tasks relating to many different aspects of a molten salt tower plant. The first Phase of the project focused on developing a baseline design for a Molten Salt Tower and validating areas for improvement. Tasks included a market study, receiver design, heat exchanger design, preliminary heliostat design, solar field optimization, baseline system design including PFDs and P&IDs and detailed cost estimate. The baseline plant met the initial goal of less than $0.14/kWhe, and reinforced the need to reduce costs in several key areas to reach the overall $0.09/kWhe goal. The major improvements identified from Phase I were: 1) higher temperature salt to improve cycle efficiency and reduce storage requirements, 2) an improved receiver coating to increase the efficiency of the receiver, 3) a large receiver design to maximize storage and meet the baseload hours objective, and 4) lower cost heliostat field. The second Phase of the project looked at advancing the baseline tower with the identified improvements and included key prototypes. To validate increasing the standard solar salt temperature to 600 °C a dynamic test was conducted at Sandia. The results ultimately proved the hypothesis incorrect and showed high oxide production and corrosion rates. The results lead to further testing of systems to mitigate the oxide production to be able to increase the salt temperature for a commercial plant. Foster Wheeler worked on the receiver design in both Phase I and Phase II looking at both design and lowering costs utilizing commercial fossil boiler manufacturing. The cost and design goals for the project were met with this task, but the most interesting results had to do with defining the failure modes and looking at a “shakedown analysis” of the combined creep-fatigue failure. A separate task also looked at improving the absorber coatings on the receiver tubes that would improve the efficiency of the receiver. Significant progress was made on developing a novel paint with a high absorptivity that was on par with the current Pyromark, but shows additional potential to be optimized further. Although the coating did not meet the emissivity goals, preliminary testing the new paint shows potential to be much more durable, and potential to improve the receiver efficiency through a higher average absorptivity over the lifetime. Additional coatings were also designed and modeled results meet the project goals, but were not tested. Testing for low cycle fatigue of the full length receiver tubes was designed and constructed, but is still currently undergoing testing. A novel small heliostat was developed through an extensive brainstorming and down select. The concept was then detailed further with inputs from component testing and eventually a full prototype was built and tested. This task met or exceeded the accuracy and structure goals and also beat the cost goal. This provides a significant solar field costs savings for Abengoa that will be developed further to be used in future commercial plants. Ultimately the $0.09/kWhe (real 2009 $) and 6,400 hours goals of the project were met.

  2. Baseload Concentrating Solar Power Generation | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The following projects were selected under this competitive solicitation: Abengoa: Advanced Nitrate Salt Central Receiver Power Plant eSolar: Modular and Scalable Baseload Molten ...

  3. Project Profile: Brayton Cycle Baseload Power Tower

    Broader source: Energy.gov [DOE]

    Wilson Solarpower, under the Baseload CSP FOA, is validating a proposed utility-scale, Brayton cycle baseload power tower system with a capacity factor of at least 75% and LCOE of $0.09/kWh.

  4. Baseload CSP Generation Integrated with Sulfur-Based Thermochemical...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage - FY13 Q1 Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage - FY13 ...

  5. Climate Change Update: Baseload Geothermal is One of the Lowest...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Climate Change Update: Baseload Geothermal is One of the Lowest Emitting Energy Technologies Climate Change Update: Baseload Geothermal is One of the Lowest Emitting Energy...

  6. Climate Change Update: Baseload Geothermal is One of the Lowest...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Climate Change Update: Baseload Geothermal is One of the Lowest Emitting Energy Technologies Climate Change Update: Baseload Geothermal is One of the Lowest Emitting Energy ...

  7. Project Profile: Innovative Thermal Energy Storage for Baseload...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermal Energy Storage for Baseload Solar Power Generation Project Profile: Innovative Thermal Energy Storage for Baseload Solar Power Generation University of South Florida logo ...

  8. Innovative Phase hange Thermal Energy Storage Solution for Baseload...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Phase hange Thermal Energy Storage Solution for Baseload Power Innovative Phase hange Thermal Energy Storage Solution for Baseload Power This presentation was delivered at the ...

  9. CSP Heat Integration for Baseload Renewable Energy Deployment | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Concentrating Solar Power » CSP Heat Integration for Baseload Renewable Energy Deployment CSP Heat Integration for Baseload Renewable Energy Deployment --This project has been closed-- In October 2013, DOE announced an award under the Concentrating Solar Power (CSP) Heat Integration for Baseload Renewable Energy Development (HIBRED) program to advance the state of the art in CSP hybrid plants, which incorporate thermal and or chemical energy from a CSP system into a fossil fueled

  10. LPG-recovery processes for baseload LNG plants examined

    SciTech Connect (OSTI)

    Chiu, C.H.

    1997-11-24

    With demand on the rise, LPG produced from a baseload LNG plant becomes more attractive as a revenue-earning product similar to LNG. Efficient use of gas expanders in baseload LNG plants for LPG production therefore becomes more important. Several process variations for LPG recovery in baseload LNG plants are reviewed here. Exergy analysis (based on the Second Law of Thermodynamics) is applied to three cases to compare energy efficiency resulting from integration with the main liquefaction process. The paper discusses extraction in a baseload plant, extraction requirements, process recovery parameters, extraction process variations, and exergy analysis.

  11. Project Profile: Advanced Nitrate Salt Central Receiver Power Plant

    Broader source: Energy.gov [DOE]

    Abengoa, under the Baseload CSP FOA, will demonstrate a 100-megawatt electrical (MWe) central receiver plant using nitrate salt as the receiver coolant, thermal storage medium, and heat transport fluid in the steam generator.

  12. Innovative Phase Change Thermal Energy Storage Solution for Baseload Power

    Office of Scientific and Technical Information (OSTI)

    Phase 1 Final Report (Technical Report) | SciTech Connect SciTech Connect Search Results Technical Report: Innovative Phase Change Thermal Energy Storage Solution for Baseload Power Phase 1 Final Report Citation Details In-Document Search Title: Innovative Phase Change Thermal Energy Storage Solution for Baseload Power Phase 1 Final Report The primary purpose of this project is to develop and validate an innovative, scalable phase change salt thermal energy storage (TES) system that can

  13. Flexible Coal: Evolution from Baseload to Peaking Plant (Brochure)

    SciTech Connect (OSTI)

    Cochran, J.; Lew, D.; Kumar, N.

    2013-12-01

    Twenty-first century power systems, with higher penetration levels of low-carbon energy, smart grids, and other emerging technologies, will favor resources that have low marginal costs and provide system flexibility (e.g., the ability to cycle on and off to follow changes in variable renewable energy plant output). Questions remain about both the fate of coal plants in this scenario and whether they can cost-effectively continue to operate if they cycle routinely. The experience from the CGS plant demonstrates that coal plants can become flexible resources. This flexibility - namely the ability to cycle on and off and run at lower output (below 40% of capacity) - requires limited hardware modifications but extensive modifications to operational practice. Cycling does damage the plant and impact its life expectancy compared to baseload operations. Nevertheless, strategic modifications, proactive inspections and training programs, among other operational changes to accommodate cycling, can minimize the extent of damage and optimize the cost of maintenance. CGS's cycling, but not necessarily the associated price tag, is replicable. Context - namely, power market opportunities and composition of the generation fleet - will help determine for other coal plants the optimal balance between the level of cycling-related forced outages and the level of capital investment required to minimize those outages. Replicating CGS's experience elsewhere will likely require a higher acceptance of forced outages than regulators and plant operators are accustomed to; however, an increase in strategic maintenance can minimize the impact on outage rates.

  14. Project Profile: Encapsulated Phase Change Material in Thermal Storage for Baseload CSP Plants

    Broader source: Energy.gov [DOE]

    Terrafore, under the Baseload CSP FOA, is developing novel encapsulated phase change materials (PCM) for use in thermal storage applications to significantly reduce the LCOE for baseload CSP plants.

  15. Project Profile: Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage

    Broader source: Energy.gov [DOE]

    General Atomics, under the Baseload CSP FOA, is demonstrating the engineering feasibility of using a sulfur-based thermochemical cycle to store heat from a CSP plant and support baseload power...

  16. Project Profile: Innovative Phase Change Thermal Energy Storage Solution for Baseload Power

    Broader source: Energy.gov [DOE]

    Infinia, under the Baseload CSP FOA, is developing and demonstrating a subscale system for baseload CSP power generation using thermal energy storage (TES) in a unique integration of innovative enhancements that improves performance and reduces cost.

  17. Project Profile: High-Concentration, Low-Cost Parabolic Trough System for Baseload CSP

    Broader source: Energy.gov [DOE]

    SkyFuel, under the Baseload CSP FOA, is developing an advanced, low-cost CSP collector using higher-concentration, higher-temperature, parabolic trough technology to substantially reduce the cost of baseload utility-scale solar power generation.

  18. Sulfur Based Thermochemical Heat Storage for Baseload Concentrated Solar Power Generation

    SciTech Connect (OSTI)

    wong, bunsen

    2014-11-20

    This project investigates the engineering and economic feasibility of supplying baseload power using a concentrating solar power (CSP) plant integrated with sulfur based thermochemical heat storage. The technology stores high temperature solar heat in the chemical bonds of elemental sulfur. Energy is recovered as high temperature heat upon sulfur combustion. Extensive developmental and design work associated with sulfur dioxide (SO2) disproportionation and sulfuric acid (H2SO4) decomposition chemical reactions used in this technology had been carried out in the two completed phases of this project. The feasibility and economics of the proposed concept was demonstrated and determined.

  19. CX-010503: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Baseload Nitrate Salt Central Receiver Power Plant Design CX(s) Applied: A9, B3.6, B5.17 Date: 06/03/2013 Location(s): Colorado, Colorado Offices(s): Golden Field Office

  20. CX-003201: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Baseload Nitrate Salt Central Receiver Power Plant DesignCX(s) Applied: A9Date: 08/04/2010Location(s): ColoradoOffice(s): Energy Efficiency and Renewable Energy, Golden Field Office

  1. Project Profile: Innovative Thermal Energy Storage for Baseload Solar Power Generation

    Broader source: Energy.gov [DOE]

    The University of South Florida, under the Baseload CSP FOA, is researching and developing a thermal energy storage system based on encapsulated phase change materials (PCM) that can meet the utility-scale baseload CSP plant requirements at significantly lower system costs.

  2. A DOE-Funded Design Study for Pioneer Baseload Application Of...

    Open Energy Info (EERE)

    Of an Advanced Geothermal binary Cycle at a Utility Plant in Western Utah Citation W.E. Lewis, M. Ralph. 2002. A DOE-Funded Design Study for Pioneer Baseload Application Of an...

  3. Climate Change Update: Baseload Geothermal is One of the Lowest Emitting

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Technologies | Department of Energy Climate Change Update: Baseload Geothermal is One of the Lowest Emitting Energy Technologies Climate Change Update: Baseload Geothermal is One of the Lowest Emitting Energy Technologies June 26, 2013 - 11:53am Addthis Geothermal energy - energy derived from the heat of the earth - has the ability to produce electricity consistently around the clock, draws a small environmental footprint, and emits little or no greenhouse gases (GHG). Estimates of

  4. Baseload gas turbine to meet utility requirements for reliability and availability

    SciTech Connect (OSTI)

    Grevstad, P.E.; Smith, M.J.; Duncan, R.L.

    1982-04-01

    The coal gasifier-gas turbine, combined cycle is described as a superior baseload electric generating system. It promises lower fuel cost, lower operating and maintenance cost, and superior siting and environmental characteristics over conventional steam systems with flue gas clean up and fluidized bed combined cycle systems. Two major new components are required: 1) the coal gasifier, and 2) the baseload gas turbine. 10 refs.

  5. Flexible Coal: An Example Evolution from Baseload to Peaking Plant (Presentation)

    SciTech Connect (OSTI)

    Cochran, J.

    2014-08-01

    Twenty-first century power systems, with higher penetration levels of low-carbon energy, smart grids, and other emerging technologies, will favor resources that have low marginal costs and provide system flexibility (e.g., the ability to cycle on and off to follow changes in variable renewable energy plant output). Questions remain about both the fate of coal plants in this scenario and whether they can cost-effectively continue to operate if they cycle routinely. The experience from the CGS plant demonstrates that coal plants can become flexible resources. This flexibility - namely the ability to cycle on and off and run at lower output (below 40% of capacity) - requires limited hardware modifications but extensive modifications to operational practice. Cycling does damage the plant and impact its life expectancy compared to baseload operations. Nevertheless, strategic modifications, proactive inspections and training programs, among other operational changes to accommodate cycling, can minimize the extent of damage and optimize the cost of maintenance. CGS's cycling, but not necessarily the associated price tag, is replicable. Context - namely, power market opportunities and composition of the generation fleet - will help determine for other coal plants the optimal balance between the level of cycling-related forced outages and the level of capital investment required to minimize those outages. Replicating CGS's experience elsewhere will likely require a higher acceptance of forced outages than regulators and plant operators are accustomed to; however, an increase in strategic maintenance can minimize the impact on outage rates.

  6. Flexible Coal: An Example Evolution from Baseload to Peaking Plant (Presentation)

    SciTech Connect (OSTI)

    Cochran, J.

    2014-05-01

    Twenty-first century power systems, with higher penetration levels of low-carbon energy, smart grids, and other emerging technologies, will favor resources that have low marginal costs and provide system flexibility (e.g., the ability to cycle on and off to follow changes in variable renewable energy plant output). Questions remain about both the fate of coal plants in this scenario and whether they can cost-effectively continue to operate if they cycle routinely. The experience from the CGS plant demonstrates that coal plants can become flexible resources. This flexibility - namely the ability to cycle on and off and run at lower output (below 40% of capacity) - requires limited hardware modifications but extensive modifications to operational practice. Cycling does damage the plant and impact its life expectancy compared to baseload operations. Nevertheless, strategic modifications, proactive inspections and training programs, among other operational changes to accommodate cycling, can minimize the extent of damage and optimize the cost of maintenance. CGS's cycling, but not necessarily the associated price tag, is replicable. Context - namely, power market opportunities and composition of the generation fleet - will help determine for other coal plants the optimal balance between the level of cycling-related forced outages and the level of capital investment required to minimize those outages. Replicating CGS's experience elsewhere will likely require a higher acceptance of forced outages than regulators and plant operators are accustomed to; however, an increase in strategic maintenance can minimize the impact on outage rates.

  7. Project Profile: Modular and Scalable Baseload Molten Salt Plant Conceptual Design and Feasibility

    Broader source: Energy.gov [DOE]

    eSolar, under the Baseload CSP FOA, is designing a 100-MW, 75% capacity factor, molten salt power tower plant, based around a molten salt receiver and heliostat field module with a nominal thermal rating of 50 MWth. They are taking a modular approach, which can be scaled through replication of the receiver/field module to meet output and capacity factor requirements.

  8. Flexible Coal: Evolution from Baseload to Peaking Plant (Brochure), 21st Century Power Partnership

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Accelerating the transformation of power systems Flexible Coal Evolution from Baseload to Peaking Plant The experience cited in this paper is from a generating station with multiple units located in North America referred to here as the CGS plant. For commercial reasons, the station has not been identified. Jaquelin Cochran, a Debra Lew, a Nikhil Kumar b a National Renewable Energy Laboratory, b Intertek Summary for Policymakers: Key Findings from a North American Coal Generating Station (CGS)

  9. Nitrate reduction

    DOE Patents [OSTI]

    Dziewinski, Jacek J. (Los Alamos, NM); Marczak, Stanislaw (Los Alamos, NM)

    2000-01-01

    Nitrates are reduced to nitrogen gas by contacting the nitrates with a metal to reduce the nitrates to nitrites which are then contacted with an amide to produce nitrogen and carbon dioxide or acid anions which can be released to the atmosphere. Minor amounts of metal catalysts can be useful in the reduction of the nitrates to nitrites. Metal salts which are formed can be treated electrochemically to recover the metals.

  10. Brayton-Cycle Baseload Power Tower CSP System

    SciTech Connect (OSTI)

    Anderson, Bruce

    2013-12-31

    The primary objectives of Phase 2 of this Project were: 1. Engineer, fabricate, and conduct preliminary testing on a low-pressure, air-heating solar receiver capable of powering a microturbine system to produce 300kWe while the sun is shining while simultaneously storing enough energy thermally to power the system for up to 13 hours thereafter. 2. Cycle-test a high-temperature super alloy, Haynes HR214, to determine its efficacy for the system’s high-temperature heat exchanger. 3. Engineer the thermal energy storage system This Phase 2 followed Wilson’s Phase 1, which primarily was an engineering feasibility study to determine a practical and innovative approach to a full Brayton-cycle system configuration that could meet DOE’s targets. Below is a summary table of the DOE targets with Wilson’s Phase 1 Project results. The results showed that a Brayton system with an innovative (low pressure) solar receiver with ~13 hours of dry (i.e., not phase change materials or molten salts but rather firebrick, stone, or ceramics) has the potential to meet or exceed DOE targets. Such systems would consist of pre-engineered, standardized, factory-produced modules to minimize on-site costs while driving down costs through mass production. System sizes most carefully analyzed were in the range of 300 kWe to 2 MWe. Such systems would also use off-the-shelf towers, blowers, piping, microturbine packages, and heliostats. Per DOE’s instructions, LCOEs are based on the elevation and DNI levels of Daggett, CA, for a 100 MWe power plant following 2 GWe of factory production of the various system components. Success criteria DOE targets Wilson system LCOE DOE’s gas price $6.75/MBtu 9 cents/kWh 7.7 cents/kWh LCOE Current gas price $4.71/MBtu NA 6.9 cents/kWh Capacity factor 75% (6500hr) 75-100% Solar fraction 85% (5585hr) >5585hr Receiver cost $170/kWe $50/kWe Thermal storage cost $20/kWhth $13/kWhth Heliostat cost $120/m2 $89.8/m2

  11. Development and Demonstration of an Innovative Thermal Energy Storage System for Baseload Power Generation

    SciTech Connect (OSTI)

    D. Y. Goswami

    2012-09-04

    The objective of this project is to research and develop a thermal energy storage system (operating range 3000C ???¢???????? 450 0C ) based on encapsulated phase change materials (PCM) that can meet the utility-scale base-load concentrated solar power plant requirements at much lower system costs compared to the existing thermal energy storage (TES) concepts. The major focus of this program is to develop suitable encapsulation methods for existing low-cost phase change materials that would provide a cost effective and reliable solution for thermal energy storage to be integrated in solar thermal power plants. This project proposes a TES system concept that will allow for an increase of the capacity factor of the present CSP technologies to 75% or greater and reduce the cost to less than $20/kWht.

  12. Oil-fired cycling station converted to base-loaded, coal-burning operation

    SciTech Connect (OSTI)

    Hunt, J.; Steinbach, P.

    1982-04-01

    The Baltimore Gas and Electric Company has been able to modify its oil-fired Brandon Shores plant while under construction to a base-loaded plant able to burn either oil or coal. Utility planners had the foresight prior to the 1973 embargo to see advantages in a dual-fuel capability. Brandon Shores has experienced the same financing and fluctuating load problems as other projects, but it has evolved into a facility suited for the 1980s and 90s. The original plan included space to handle coal and wastes as well as specifying dual-fuel equipment throughout to minimize future modifications. During one construction delay, the utility initiated a preventative-maintenance program comparable to that of a nuclear plant that has been continued. Extensive environmental planning and interaction with the public have avoided other costly delays. (DCK)

  13. Base-Load and Peak Electricity from a Combined Nuclear Heat and Fossil Combined-Cycle Plant

    SciTech Connect (OSTI)

    Conklin, James C.; Forsberg, Charles W.

    2007-07-01

    A combined-cycle power plant is proposed that uses heat from a high-temperature reactor and fossil fuel to meet base-load and peak electrical demands. The high temperature gas turbine produces shaft power to turn an electric generator. The hot exhaust is then fed to a heat recovery steam generator (HRSG) that provides steam to a steam turbine for added electrical power production. A simplified computational model of the thermal power conversion system was developed in order to parametrically investigate two different steady-state operation conditions: base load nuclear heat only from an Advanced High Temperature Reactor (AHTR), and combined nuclear heat with fossil heat to increase the turbine inlet temperature. These two cases bracket the expected range of power levels, where any intermediate power level can result during electrical load following. The computed results indicate that combined nuclear-fossil systems have the potential to offer both low-cost base-load electricity and lower-cost peak power relative to the existing combination of base-load nuclear plants and separate fossil-fired peak-electricity production units. In addition, electric grid stability, reduced greenhouse gases, and operational flexibility can also result with using the conventional technology presented here for the thermal power conversion system coupled with the AHTR. (authors)

  14. Base-Load and Peak Electricity from a Combined Nuclear Heat and Fossil Combined-Cycle Plant

    SciTech Connect (OSTI)

    Conklin, Jim; Forsberg, Charles W

    2007-01-01

    A combined-cycle power plant is proposed that uses heat from a high-temperature reactor and fossil fuel to meet base-load and peak electrical demands. The high-temperature gas turbine produces shaft power to turn an electric generator. The hot exhaust is then fed to a heat recovery steam generator (HRSG) that provides steam to a steam turbine for added electrical power production. A simplified computational model of the thermal power conversion system was developed in order to parametrically investigate two different steady-state operation conditions: base load nuclear heat only from an Advanced High Temperature Reactor (AHTR), and combined nuclear heat with fossil heat to increase the turbine inlet temperature. These two cases bracket the expected range of power levels, where any intermediate power level can result during electrical load following. The computed results indicate that combined nuclear-fossil systems have the potential to offer both low-cost base-load electricity and lower-cost peak power relative to the existing combination of base-load nuclear plants and separate fossil-fired peak-electricity production units. In addition, electric grid stability, reduced greenhouse gases, and operational flexibility can also result with using the conventional technology presented here for the thermal power conversion system coupled with the AHTR.

  15. Alkali metal nitrate purification

    DOE Patents [OSTI]

    Fiorucci, Louis C. (Hamden, CT); Morgan, Michael J. (Guilford, CT)

    1986-02-04

    A process is disclosed for removing contaminants from impure alkali metal nitrates containing them. The process comprises heating the impure alkali metal nitrates in solution form or molten form at a temperature and for a time sufficient to effect precipitation of solid impurities and separating the solid impurities from the resulting purified alkali metal nitrates. The resulting purified alkali metal nitrates in solution form may be heated to evaporate water therefrom to produce purified molten alkali metal nitrates suitable for use as a heat transfer medium. If desired, the purified molten form may be granulated and cooled to form discrete solid particles of purified alkali metal nitrates.

  16. WIPP Nitrate Updates 2014

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    4 WIPP Nitrate Salt Bearing Waste Container Isolation Plan Implementation Update, December 30, 2014 Waste Isolation Pilot Plant EPA I.D. Number: NM4890139088-TSDF WIPP Nitrate Salt Bearing Waste Container Isolation Plan Implementation Update, December 23, 2014 Waste Isolation Pilot Plant EPA I.D. Number: NM4890139088-TSDF WIPP Nitrate Salt Bearing Waste Container Isolation Plan Implementation Update, December 18, 2014 Waste Isolation Pilot Plant EPA I.D. Number: NM4890139088-TSDF WIPP Nitrate

  17. WIPP Nitrate Updates 2015

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5 WIPP Nitrate Salt Bearing Waste Container Isolation Plan Implementation Update, July 23, 2015 Waste Isolation Pilot Plant EPA I.D. Number: NM4890139088-TSDF WIPP Nitrate Salt Bearing Waste Container Isolation Plan Implementation Update, July 16, 2015 Waste Isolation Pilot Plant EPA I.D. Number: NM4890139088-TSDF WIPP Nitrate Salt Bearing Waste Container Isolation Plan Implementation Update, July 9, 2015 Waste Isolation Pilot Plant EPA I.D. Number: NM4890139088-TSDF WIPP Nitrate Salt Bearing

  18. Thermochemical nitrate destruction

    DOE Patents [OSTI]

    Cox, John L. (Richland, WA); Hallen, Richard T. (Richland, WA); Lilga, Michael A. (Richland, WA)

    1992-01-01

    A method is disclosed for denitrification of nitrates and nitrates present in aqueous waste streams. The method comprises the steps of (1) identifying the concentration nitrates and nitrites present in a waste stream, (2) causing formate to be present in the waste stream, (3) heating the mixture to a predetermined reaction temperature from about 200.degree. C. to about 600.degree. C., and (4) holding the mixture and accumulating products at heated and pressurized conditions for a residence time, thereby resulting in nitrogen and carbon dioxide gas, and hydroxides, and reducing the level of nitrates and nitrites to below drinking water standards.

  19. Thermochemical nitrate destruction

    DOE Patents [OSTI]

    Cox, J.L.; Hallen, R.T.; Lilga, M.A.

    1992-06-02

    A method is disclosed for denitrification of nitrates and nitrites present in aqueous waste streams. The method comprises the steps of (1) identifying the concentration nitrates and nitrites present in a waste stream, (2) causing formate to be present in the waste stream, (3) heating the mixture to a predetermined reaction temperature from about 200 C to about 600 C, and (4) holding the mixture and accumulating products at heated and pressurized conditions for a residence time, thereby resulting in nitrogen and carbon dioxide gas, and hydroxides, and reducing the level of nitrates and nitrites to below drinking water standards.

  20. Nitrate Salt Surrogate Blending Scoping Test Plan

    SciTech Connect (OSTI)

    Anast, Kurt Roy

    2015-11-13

    Test blending equipment identified in the “Engineering Options Assessment Report: Nitrate Salt Waste Stream Processing”. Determine if the equipment will provide adequate mixing of zeolite and surrogate salt/Swheat stream; optimize equipment type and operational sequencing; impact of baffles and inserts on mixing performance; and means of validating mixing performance

  1. Purification of alkali metal nitrates

    DOE Patents [OSTI]

    Fiorucci, Louis C.; Gregory, Kevin M.

    1985-05-14

    A process is disclosed for removing heavy metal contaminants from impure alkali metal nitrates containing them. The process comprises mixing the impure nitrates with sufficient water to form a concentrated aqueous solution of the impure nitrates, adjusting the pH of the resulting solution to within the range of between about 2 and about 7, adding sufficient reducing agent to react with heavy metal contaminants within said solution, adjusting the pH of the solution containing reducing agent to effect precipitation of heavy metal impurities and separating the solid impurities from the resulting purified aqueous solution of alkali metal nitrates. The resulting purified solution of alkali metal nitrates may be heated to evaporate water therefrom to produce purified molten alkali metal nitrate suitable for use as a heat transfer medium. If desired, the purified molten form may be granulated and cooled to form discrete solid particles of alkali metal nitrates.

  2. Using Encapsulated Phase Change Material in Thermal Energy Storage for Baseload Concentrating Solar Power (EPCM-TES)

    SciTech Connect (OSTI)

    Mathur, Anoop

    2013-12-15

    Terrafore successfully demonstrated and optimized the manufacturing of capsules containing phase-changing inorganic salts. The phase change was used to store thermal energy collected from a concentrating solar-power plant as latent heat. This latent heat, in addition to sensible heat increased the energy density (energy stored per unit weight of salt) by over 50%, thus requiring 40% less salt and over 60% less capsule container. Therefore, the cost to store high-temperature thermal energy collected in a concentrating solar power plant will be reduced by almost 40% or more, as compared to conventional two-tank, sensible-only storage systems. The cost for thermal energy storage (TES) system is expected to achieve the Sun Shot goal of $15 per kWh(t). Costs associated with poor heat-transfer in phase change materials (PCM) were also eliminated. Although thermal energy storage that relies on the latent heat of fusion of PCM improves energy density by as much as 50%, upon energy discharge the salt freezes and builds on the heat transfer surfaces. Since these salts have low thermal conductivity, large heat-transfer areas, or larger conventional heat-exchangers are needed, which increases costs. By encapsulating PCM in small capsules we have increased the heat transfer area per unit volume of salt and brought the heat transfer fluid in direct contact with the capsules. These two improvements have increased the heat transfer coefficient and boosted heat transfer. The program was successful in overcoming the phenomenon of melt expansion in the capsules, which requires the creation of open volume in the capsules or shell to allow for expansion of the molten salt on melting and is heated above its melting point to 550°C. Under contract with the Department of Energy, Terrafore Inc. and Southwest Research Institute, developed innovative method(s) to economically create the open volume or void in the capsule. One method consists of using a sacrificial polymer coating as the middle layer between the salt prill and the shell material. The selected polymer decomposes at temperatures below the melting point of the salt and forms gases which escape through the pores in the capsule shell thus leaving a void in the capsule. We have demonstrated the process with a commonly used inorganic nitrate salt in a low-cost shell material that can withstand over 10,000 high-temperature thermal cycles, or a thirty-year or greater life in a solar plant. The shell used to encapsulate the salt was demonstrated to be compatible with molten salt heat transfer fluid typically used in CSP plants to temperatures up to 600 °C. The above findings have led to the concept of a cascaded arrangement. Salts with different melting points can be encapsulated using the same recipe and contained in a packed bed by cascading the salt melting at higher melting point at the top over the salt melting at lower melting point towards the bottom of the tank. This cascaded energy storage is required to effectively transfer the sensible heat collected in heat transfer fluids between the operating temperatures and utilize the latent heat of fusion in the salts inside the capsule. Mathematical models indicate that over 90% of the salts will undergo phase change by using three salts in equal proportion. The salts are selected such that the salt at the top of the tank melts at about 15°C below the high operating-temperature, and the salt at the bottom of the tank melts 15°C above the low operating-temperature. The salt in the middle of tank melts in-between the operating temperature of the heat transfer fluid. A cascaded arrangement leads to the capture of 90% of the latent-heat of fusion of salts and their sensible heats. Thus the energy density is increased by over 50% from a sensible-only, two-tank thermal energy storage. Furthermore, the Terrafore cascaded storage method requires only one tank as opposed to the two-tanks used in sensible heat storage. Since heat is transferred from the heat transfer fluid by direct contact with capsules, external heat-exchangers are not required for charging storage. Thus, the cost of the thermal storage system is reduced due to smaller containers and less salt. The optimum salt proportions, their melting temperature and the number of salts in the cascade are determined by raw materials costs and the mathematical model. We estimate the processing cost of the encapsulation to be low, where the major cost of the capsule will be the cost of the phase-change salt(s). Our economic analyses show that the cost of EPCM-TES is about $17.98 per kWh(t), which is about 40% lower than the $28.36 per kWh(t) for a two-tank sensible heat TES for a large scale CSP-TES design. Finally, additional improvements in the heat-transfer fluids, currently in development elsewhere will further improve the energy density to achieve the SunShot goal of $15 per kWh(t).

  3. Temperature dependent mechanical property testing of nitrate thermal

    Office of Scientific and Technical Information (OSTI)

    storage salts. (Conference) | SciTech Connect Temperature dependent mechanical property testing of nitrate thermal storage salts. Citation Details In-Document Search Title: Temperature dependent mechanical property testing of nitrate thermal storage salts. Three salt compositions for potential use in trough-based solar collectors were tested to determine their mechanical properties as a function of temperature. The mechanical properties determined were unconfined compressive strength,

  4. TREATMENT OF AMMONIUM NITRATE SOLUTIONS

    DOE Patents [OSTI]

    Boyer, T.W.; MacHutchin, J.G.; Yaffe, L.

    1958-06-10

    The treatment of waste solutions obtained in the processing of neutron- irradiated uranium containing fission products and ammonium nitrate is described. The object of this process is to provide a method whereby the ammonium nitrate is destroyed and removed from the solution so as to permit subsequent concentration of the solution.. In accordance with the process the residual nitrate solutions are treated with an excess of alkyl acid anhydride, such as acetic anhydride. Preferably, the residual nitrate solution is added to an excess of the acetic anhydride at such a rate that external heat is not required. The result of this operation is that the ammonium nitrate and acetic anhydride react to form N/sub 2/ O and acetic acid.

  5. Plutonium nitrate bottle counter manual

    SciTech Connect (OSTI)

    Menlove, H.O.; Adams, E.L.; Holbrooks, O.R.

    1984-03-01

    A neutron coincidence counter has been designed for plutonium nitrate assay in large storage bottles. This assay system can be used in the reprocessing plant or in the nitrate-to-oxide conversion facility. The system is based on the family of neutron detectors similar to the high-level neutron coincidence counter. This manual describes the system and gives performance and calibration parameters for typical applications. 4 references, 11 figures, 9 tables.

  6. Effect of composition on the density of multi-component molten nitrate salts.

    SciTech Connect (OSTI)

    Bradshaw, Robert W.

    2009-12-01

    The density of molten nitrate salts was measured to determine the effects of the constituents on the density of multi-component mixtures. The molten salts consisted of various proportions of the nitrates of potassium, sodium, lithium and calcium. Density measurements ere performed using an Archimedean method and the results were compared to data reported in the literature for the individual constituent salts or simple combinations, such as the binary Solar Salt mixture of NaNO3 and KNO3. The addition of calcium nitrate generally ncreased density, relative to potassium nitrate or sodium nitrate, while lithium nitrate decreased density. The temperature dependence of density is described by a linear equation regardless of composition. The molar volume, and thereby, density of multi-component mixtures an be calculated as a function of temperature using a linear additivity rule based on the properties of the individual constituents.

  7. Treatment of Remediated Nitrate Salts

    Broader source: Energy.gov [DOE]

    Los Alamos National Laboratory, provided a presentation at the NNMCABs November 18, 2015 Board Meeting at New Mexico Highlands University. The topic of the presentation was the plan for remediation the nitrate salt waste from the 3706 campaign that is currently stored at Material Disposal Area G, presenter was David Funk, LANS.

  8. Biological denitrification of high concentration nitrate waste

    DOE Patents [OSTI]

    Francis, Chester W.; Brinkley, Frank S.

    1977-01-01

    Biological denitrification of nitrate solutions at concentrations of greater than one kilogram nitrate per cubic meter is accomplished anaerobically in an upflow column having as a packing material a support for denitrifying bacteria.

  9. Process for reducing aqueous nitrate to ammonia

    DOE Patents [OSTI]

    Mattus, Alfred J.

    1993-01-01

    Powdered aluminum is added to a nitrate-containing alkaline, aqueous solution to reduce the nitrate and/or nitrite to ammonia and co-produce a sinterable ceramic product.

  10. Process for reducing aqueous nitrate to ammonia

    DOE Patents [OSTI]

    Mattus, A.J.

    1993-11-30

    Powdered aluminum is added to a nitrate-containing alkaline, aqueous solution to reduce the nitrate and/or nitrite to ammonia and co-produce a sinterable ceramic product. 3 figures.

  11. Method of producing thin cellulose nitrate film

    DOE Patents [OSTI]

    Lupica, S.B.

    1975-12-23

    An improved method for forming a thin nitrocellulose film of reproducible thickness is described. The film is a cellulose nitrate film, 10 to 20 microns in thickness, cast from a solution of cellulose nitrate in tetrahydrofuran, said solution containing from 7 to 15 percent, by weight, of dioctyl phthalate, said cellulose nitrate having a nitrogen content of from 10 to 13 percent.

  12. EP-AREAG-PLAN-1248, R.0 TA-54 Area G Nitrate-Salt Waste Container...

    Office of Environmental Management (EM)

    EP-AREAG-PLAN-1248, R.0 TA-54 Area G Nitrate-Salt Waste Container Response Instructions Effective Date: 5282014 The Responsible Manager has determined that the following...

  13. Viscosity of multi-component molten nitrate salts : liquidus to 200 degrees C.

    SciTech Connect (OSTI)

    Bradshaw, Robert W.

    2010-03-01

    The viscosity of molten salts comprising ternary and quaternary mixtures of the nitrates of sodium, potassium, lithium and calcium was determined experimentally. Viscosity was measured over the temperature range from near the relatively low liquidus temperatures of he individual mixtures to 200C. Molten salt mixtures that do not contain calcium nitrate exhibited relatively low viscosity and an Arrhenius temperature dependence. Molten salt mixtures that contained calcium nitrate were relatively more viscous and viscosity increased as the roportion of calcium nitrate increased. The temperature dependence of viscosity of molten salts containing calcium nitrate displayed curvature, rather than linearity, when plotted in Arrhenius format. Viscosity data for these mixtures were correlated by the Vogel-Fulcher- ammann-Hesse equation.

  14. ARRAYS OF BOTTLES OF PLUTONIUM NITRATE SOLUTION

    SciTech Connect (OSTI)

    Margaret A. Marshall

    2012-09-01

    In October and November of 1981 thirteen approaches-to-critical were performed on a remote split table machine (RSTM) in the Critical Mass Laboratory of Pacific Northwest Laboratory (PNL) in Richland, Washington using planar arrays of polyethylene bottles filled with plutonium (Pu) nitrate solution. Arrays of up to sixteen bottles were used to measure the critical number of bottles and critical array spacing with a tight fitting Plexiglas reflector on all sides of the arrays except the top. Some experiments used Plexiglas shells fitted around each bottles to determine the effect of moderation on criticality. Each bottle contained approximately 2.4 L of Pu(NO3)4 solution with a Pu content of 105 g Pu/L and a free acid molarity H+ of 5.1. The plutonium was of low 240Pu (2.9 wt.%) content. These experiments were sponsored by Rockwell Hanford Operations because of the lack of experimental data on the criticality of arrays of bottles of Pu solution such as might be found in storage and handling at the Purex Facility at Hanford. The results of these experiments were used to provide benchmark data to validate calculational codes used in criticality safety assessments of [the] plant configurations (Ref. 1). Data for this evaluation were collected from the published report (Ref. 1), the approach to critical logbook, the experimenters logbook, and communication with the primary experimenter, B. Michael Durst. Of the 13 experiments preformed 10 were evaluated. One of the experiments was not evaluated because it had been thrown out by the experimenter, one was not evaluated because it was a repeat of another experiment and the third was not evaluated because it reported the critical number of bottles as being greater than 25. Seven of the thirteen evaluated experiments were determined to be acceptable benchmark experiments. A similar experiment using uranyl nitrate was benchmarked as U233-SOL-THERM-014.

  15. Remediated Nitrate Salt Drums Safety Update

    Broader source: Energy.gov [DOE]

    At the March 9, 2016 Combined Committee Meeting Mr. Nickless, Environmental Management Los Alamos, Provided a presentation on the status of the Nitrate Salt waste at Los Alamos.

  16. PREPARATION OF DIBASIC ALUMINUM NITRATE

    DOE Patents [OSTI]

    Gresky, A.T.; Nurmi, E.O.; Foster, D.L.; Wischow, R.P.; Savolainen, J.E.

    1960-04-01

    A method is given for the preparation and recovery of basic aluminum nltrates having an OH: Al ratio of at least two, comprising two steps. First, metallic aluminum is dissolved in aqueous Al(NO/sub 3/)/sub 3/, in the presence of a small quantity of elemental or ionic mercury, to increase its Al: NO/sub 3/ ratio into the range 1 to 1.2. The resulting aqueous solution is then added to an excess of a special organic solvent, typically a mixture of five parts methanol and six parts diethyl ether, whereupon the basic aluminum nitrate, e.g. Al/sub 6/(OH)/sub 13/-(NO/sub 3/)/sub 5/, recoverably precipitates.

  17. CX-003976: Categorical Exclusion Determination | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    976: Categorical Exclusion Determination CX-003976: Categorical Exclusion Determination Development of a High-Concentration Low-Cost Parabolic Trough System for Baseload Concentrated Solar Power Generation CX(s) Applied: A9, B5.1 Date: 09/20/2010 Location(s): Arvada, Colorado Office(s): Energy Efficiency and Renewable Energy, Golden Field Office The Department of Energy is proposing to provide federal funding to SkyFuel to develop and demonstrate an advanced low-cost Concentrated Solar Power

  18. Determination

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Determination of a Minimum Soiling Level to Affect Photovoltaic Devices Patrick D. Burton and Bruce H. King Sandia National Laboratories, Albuquerque, NM 87185 USA...

  19. Remediated Nitrate Salt Drums Storage at Los Alamos National...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Remediated Nitrate Salt Drums Storage at Los Alamos National Laboratory Remediated Nitrate Salt Drums Storage at Los Alamos National Laboratory As a part of its national security ...

  20. Sandia Energy - Molten Nitrate Salt Initial Flow Testing is a...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nitrate Salt Initial Flow Testing is a Tremendous Success Home Renewable Energy News Concentrating Solar Power Solar Molten Nitrate Salt Initial Flow Testing is a Tremendous...

  1. Waste Isolation Pilot Plant Nitrate Salt Bearing Waste Container...

    Office of Environmental Management (EM)

    Nitrate Salt Bearing Waste Container Isolation Plan Waste Isolation Pilot Plant Nitrate Salt Bearing Waste Container Isolation Plan The purpose of this document is to provide the ...

  2. Synthesis of a new energetic nitrate ester

    SciTech Connect (OSTI)

    Chavez, David E

    2008-01-01

    Nitrate esters have been known as useful energetic materials since the discovery of nitroglycerin by Ascanio Sobrero in 1846. The development of methods to increase the safety and utility of nitroglycerin by Alfred Nobel led to the revolutionary improvement in the utility of nitroglycerin in explosive applications in the form of dynamite. Since then, many nitrate esters have been prepared and incorporated into military applications such as double-based propellants, detonators and as energetic plasticizers. Nitrate esters have also been shown to have vasodilatory effects in humans and thus have been studied and used for treatments of ailments such as angina. The mechanism of the biological response towards nitrate esters has been elucidated recently. Interestingly, many of the nitrate esters used for military purposes are liquids (ethylene glycol dinitrate, propylene glycol dinitrate, etc). Pentaerythritol tetranitrate (PETN) is one of the only solid nitrate esters, besides nitrocellulose, that is used in any application. Unfortunately, PETN melting point is above 100 {sup o}C, and thus must be pressed as a solid for detonator applications. A more practical material would be a melt-castable explosive, for potential simplification of manufacturing processes. Herein we describe the synthesis of a new energetic nitrate ester (1) that is a solid at ambient temperatures, has a melting point of 85-86 {sup o}C and has the highest density of any known nitrate ester composed only of carbon, hydrogen, nitrogen and oxygen. We also describe the chemical, thermal and sensitivity properties of 1 as well as some preliminary explosive performance data.

  3. Energetic Material - Electro Nitration - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electro Nitration Idaho National Laboratory Contact INL About This Technology Technology Marketing SummaryINL has developed an improved method of nitrating a nitro compound by oxidizing a chemical mediator in the presence of a voltage in order to produce an oxidizing agent. Then, the agent reacts with a nitro compound and ion source in a solution in order to form a geminaldinitro compound. The electrochemical synthesis of geminaldinitro results in the formation of a nitro compound that may be

  4. Process for the preparation of an energetic nitrate ester

    DOE Patents [OSTI]

    Chavez, David E; Naud, Darren L; Hiskey, Michael A

    2013-12-17

    A process for the preparation of an energetic nitrate ester compound and related intermediates is provided.

  5. Process for decomposing nitrates in aqueous solution

    DOE Patents [OSTI]

    Haas, Paul A.

    1980-01-01

    This invention is a process for decomposing ammonium nitrate and/or selected metal nitrates in an aqueous solution at an elevated temperature and pressure. Where the compound to be decomposed is a metal nitrate (e.g., a nuclear-fuel metal nitrate), a hydroxylated organic reducing agent therefor is provided in the solution. In accordance with the invention, an effective proportion of both nitromethane and nitric acid is incorporated in the solution to accelerate decomposition of the ammonium nitrate and/or selected metal nitrate. As a result, decomposition can be effected at significantly lower temperatures and pressures, permitting the use of system components composed of off-the-shelf materials, such as stainless steel, rather than more costly materials of construction. Preferably, the process is conducted on a continuous basis. Fluid can be automatically vented from the reaction zone as required to maintain the operating temperature at a moderate value--e.g., at a value in the range of from about 130.degree.-200.degree. C.

  6. Laser-induced breakdown spectroscopic study of ammonium nitrate plasma

    SciTech Connect (OSTI)

    Hanif, M.; Salik, M.; Baig, M. A.

    2013-12-15

    We present the optical emission studies of the ammonium nitrate plasma produced by the fundamental (1064 nm) and second (532 nm) harmonics of a Q-switched Nd: YAG laser. The target material was placed in front of the laser beam in an open atmospheric air. The spectrum reveals numerous transitions of neutral nitrogen. We have studied the spatial behavior of the plasma temperature (T{sub e}) and electron number density (N{sub e}) determined using the Boltzmann plot method and Stark broadened line profiles, respectively. Besides, we have studied the variation of the plasma parameters as a function of the laser irradiance.

  7. Denitration of High Nitrate Salts Using Reductants

    SciTech Connect (OSTI)

    HD Smith; EO Jones; AJ Schmidt; AH Zacher; MD Brown; MR Elmore; SR Gano

    1999-05-03

    This report describes work conducted by Pacific Northwest National Laboratory (PNNL), in conjunction with Idaho National Engineering and Environmental Laboratory (INEEL), to remove nitrates in simulated low-activity waste (LAW). The major objective of this work was to provide data for identifying and demonstrating a technically viable and cost-effective approach to condition LAW for immobilization (grout).

  8. NITRATE DESTRUCTION LITERATURE SURVEY AND EVALUATION CRITERIA

    SciTech Connect (OSTI)

    Steimke, J.

    2011-02-01

    This report satisfies the initial phase of Task WP-2.3.4 Alternative Sodium Recovery Technology, Subtask 1; Develop Near-Tank Nitrate/Nitrite Destruction Technology. Some of the more common anions in carbon steel waste tanks at SRS and Hanford Site are nitrate which is corrosive, and nitrite and hydroxide which are corrosion inhibitors. At present it is necessary to periodically add large quantities of 50 wt% caustic to waste tanks. There are three primary reasons for this addition. First, when the contents of salt tanks are dissolved, sodium hydroxide preferentially dissolves and is removed. During the dissolution process the concentration of free hydroxide in the tank liquid can decrease from 9 M to less than 0.2 M. As a result, roughly half way through the dissolution process large quantities of sodium hydroxide must be added to the tank to comply with requirements for corrosion control. Second, hydroxide is continuously consumed by reaction with carbon dioxide which occurs naturally in purge air used to prevent buildup of hydrogen gas inside the tanks. The hydrogen is generated by radiolysis of water. Third, increasing the concentration of hydroxide increases solubility of some aluminum compounds, which is desirable in processing waste. A process that converts nitrate and nitrite to hydroxide would reduce certain costs. (1) Less caustic would be purchased. (2) Some of the aluminum solid compounds in the waste tanks would become more soluble so less mass of solids would be sent to High Level Vitrification and therefore it would be not be necessary to make as much expensive high level vitrified product. (3) Less mass of sodium would be fed to Saltstone at SRS or Low Level Vitrification at Hanford Site so it would not be necessary to make as much low level product. (4) At SRS less nitrite and nitrate would be sent to Defense Waste Processing Facility (DWPF) so less formic acid would be consumed there and less hydrogen gas would be generated. This task involves literature survey of technologies to perform the nitrate to hydroxide conversion, selection of the most promising technologies, preparation of a flowsheet and design of a system. The most promising technologies are electrochemical reduction of nitrates and chemical reduction with hydrogen or ammonia. The primary reviewed technologies are listed and they aredescribed in more detail later in the report: (1) Electrochemical destruction; (2) Chemical reduction with agents such as ammonia, hydrazine or hydrogen; (3) Hydrothermal reduction process; and (4) Calcination. Only three of the technologies on the list have been demonstrated to generate usable amounts of caustic; electrochemical reduction and chemical reduction with ammonia, hydrazine or hydrogen and hydrothermal reduction. Chemical reduction with an organic reactant such as formic acid generates carbon dioxide which reacts with caustic and is thus counterproductive. Treatment of nitrate with aluminum or other active metals generates a solid product. High temperature calcination has the potential to generate sodium oxide which may be hydrated to sodium hydroxide, but this is unproven. The following criteria were developed to evaluate the most suitable option. The numbers in brackets after the criteria are relative weighting factors to account for importance: (1) Personnel exposure to radiation for installation, routine operation and maintenance; (2) Non-radioactive safety issues; (3) Whether the technology generates caustic and how many moles of caustic are generated per mole of nitrate plus nitrite decomposed; (4) Whether the technology can handle nitrate and nitrite at the concentrations encountered in waste; (5) Maturity of technology; (6) Estimated annual cost of operation (labor, depreciation, materials, utilities); (7) Capital cost; (8) Selectivity to nitrogen as decomposition product (other products are flammable and/or toxic); (9) Impact of introduced species; (10) Selectivity for destruction of nitrate vs. nitrite; and (11) Cost of deactivation and demolition. Each technology was given a score from one

  9. CX-011252: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Concentrating Solar Power Heat Integration for Baseload Renewable Energy Deployment CX(s) Applied: A9 Date: 09/23/2013 Location(s): California Offices(s): Golden Field Office

  10. CX-003170: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Innovative Phase Change Thermal Energy Storage Solution for Baseload PowerCX(s) Applied: B3.6Date: 07/26/2010Location(s): WashingtonOffice(s): Energy Efficiency and Renewable Energy, Golden Field Office

  11. CX-008586: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    SkyFuel Baseload Parabolic Trough CX(s) Applied: B3.6, B5.15 Date: 07/11/2012 Location(s): Colorado Offices(s): Golden Field Office

  12. CX-000603: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Baseload Energy Inc. Brasada-Harney 115-kilovolt Transmission Line ProjectCX(s) Applied: B4.6Date: 02/04/2010Location(s): Deschutes County, OregonOffice(s): Bonneville Power Administration

  13. CX-003695: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Baseload Electricity Solar TowerCX(s) Applied: A9, B3.6Date: 09/10/2010Location(s): CaliforniaOffice(s): Energy Efficiency and Renewable Energy, Golden Field Office

  14. Laboratory study of nitrate photolysis in Antarctic snow. II. Isotopic effects and wavelength dependence

    SciTech Connect (OSTI)

    Berhanu, Tesfaye A.; Erbland, Joseph; Savarino, Jol [Laboratoire de Glaciologie et Gophysique de lEnvironnement, CNRS, F-38041 Grenoble (France); Univ. Grenoble Alpes, LGGE, F-38041 Grenoble (France); Meusinger, Carl; Johnson, Matthew S. [Copenhagen Center for Atmospheric Research (CCAR), Department of Chemistry, University of Copenhagen, Copenhagen (Denmark); Jost, Rmy [Laboratoire de Interdisciplinaire de Physique (LIPHY) Univ. de Grenoble, Grenoble (France); Bhattacharya, S. K. [Research Center for Environmental Changes, Academia Sinica, Nangang, Taipei 115, Taiwan (China)

    2014-06-28

    Atmospheric nitrate is preserved in Antarctic snow firn and ice. However, at low snow accumulation sites, post-depositional processes induced by sunlight obscure its interpretation. The goal of these studies (see also Paper I by Meusinger et al. [Laboratory study of nitrate photolysis in Antarctic snow. I. Observed quantum yield, domain of photolysis, and secondary chemistry, J. Chem. Phys. 140, 244305 (2014)]) is to characterize nitrate photochemistry and improve the interpretation of the nitrate ice core record. Naturally occurring stable isotopes in nitrate ({sup 15}N, {sup 17}O, and {sup 18}O) provide additional information concerning post-depositional processes. Here, we present results from studies of the wavelength-dependent isotope effects from photolysis of nitrate in a matrix of natural snow. Snow from Dome C, Antarctica was irradiated in selected wavelength regions using a Xe UV lamp and filters. The irradiated snow was sampled and analyzed for nitrate concentration and isotopic composition (?{sup 15}N, ?{sup 18}O, and ?{sup 17}O). From these measurements an average photolytic isotopic fractionation of {sup 15}? = (?15 1.2) was found for broadband Xe lamp photolysis. These results are due in part to excitation of the intense absorption band of nitrate around 200 nm in addition to the weaker band centered at 305 nm followed by photodissociation. An experiment with a filter blocking wavelengths shorter than 320 nm, approximating the actinic flux spectrum at Dome C, yielded a photolytic isotopic fractionation of {sup 15}? = (?47.9 6.8), in good agreement with fractionations determined by previous studies for the East Antarctic Plateau which range from ?40 to ?74.3. We describe a new semi-empirical zero point energy shift model used to derive the absorption cross sections of {sup 14}NO{sub 3}{sup ?} and {sup 15}NO{sub 3}{sup ?} in snow at a chosen temperature. The nitrogen isotopic fractionations obtained by applying this model under the experimental temperature as well as considering the shift in width and center well reproduced the values obtained in the laboratory study. These cross sections can be used in isotopic models to reproduce the stable isotopic composition of nitrate found in Antarctic snow profiles.

  15. Toluene nitration in irradiated nitric acid and nitrite solution

    SciTech Connect (OSTI)

    Gracy Elias; Bruce J. Mincher; Stephen P. Mezyk; Jim Muller; Leigh R. Martin

    2011-04-01

    The kinetics, mechanisms, and stable products produced for the aryl alkyl mild ortho-para director - toluene, in irradiated nitric acid and neutral nitrite solutions were investigated using ?, and pulse radiolysis. Electron pulse radiolysis was used to determine the bimolecular rate constants for the reaction of toluene with different transient species produced by irradiation. HPLC with UV detection was primarily used to assess the stable reaction products. GC-MS and LC-MS were used to confirm the results from HPLC. Free-radical nitration reaction products were found in irradiated acidic and neutral media. In acidic medium, the ring substitution and side chain substitution and oxidation produced different nitro products. In ring substitution, nitrogen oxide radicals were added mainly to hydroxyl radical-produced cyclohexadienyl radical, and in side chain substitution they were added to the carbon-centered benzyl radical produced by H-atom abstraction. In neutral nitrite toluene solution, radiolytic ring nitration products approached a statistically random distribution, suggesting a free-radical reaction involving addition of the NO2 radical.

  16. Supplemental Cooling for Nitrate Salt Waste

    SciTech Connect (OSTI)

    Goldberg, Mitchell S.

    2015-08-19

    In July 2015, Los Alamos National Laboratory completed installation of a supplemental cooling system in the structure where remediated nitrate salt waste drums are stored. Although the waste currently is in a safe configuration and is monitored daily,controlling the temperature inside the structure adds another layer of protection for workers, the public,and the environment.This effort is among several layers of precautions designed to secure the waste.

  17. Electrochemical cell having an alkali-metal-nitrate electrode

    DOE Patents [OSTI]

    Roche, M.F.; Preto, S.K.

    1982-06-04

    A power-producing secondary electrochemical cell includes a molten alkali metal as the negative-electrode material and a molten-nitrate salt as the positive-electrode material. The molten material in the respective electrodes are separated by a solid barrier of alkali-metal-ion conducting material. A typical cell includes active materials of molten sodium separated from molten sodium nitrate and other nitrates in mixture by a layer of sodium ..beta..'' alumina.

  18. Remediated Nitrate Salt Drums Storage at Los Alamos National Laboratory |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Remediated Nitrate Salt Drums Storage at Los Alamos National Laboratory Remediated Nitrate Salt Drums Storage at Los Alamos National Laboratory As a part of its national security mission, the Laboratory conducts research that generates waste contaminated with radioactive isotopes. During operations, waste is processed, packaged, and shipped to licensed disposal facilities. PDF icon Remediated-Nitrate-Salt-Drums-Storage-at-Los-Alamos-National-Laboratory.pdf More Documents

  19. Operating Experience Level 2, Evaluation of Nitrate Bearing Transurani...

    Broader source: Energy.gov (indexed) [DOE]

    015 OE-2 2015-01: Evaluation of Nitrate Bearing Transuranic Waste Streams This Operating Experience Level 2 (OE-2) document provides actions to perform an evaluation of...

  20. Waste Isolation Pilot Plant Nitrate Salt Bearing Waste Container

    Office of Environmental Management (EM)

    Nitrate Salt Bearing Waste Container Isolation Plan Prepared in Response to New Mexico ... (DOE) and Nuclear Waste Partnership LLC (NWP), collectively referred to as the Permittees. ...

  1. WIPP Nitrate Salt Bearing Waste Container Isolation Plan Implementatio...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nitrate Salt Bearing Waste Container Isolation Plan Implementation Update May 12, 2015 Panel 6 and Panel 7, Room 7 a. Rollback * Contamination Assessment-This prerequisite is ...

  2. Corrosion of aluminides by molten nitrate salt

    SciTech Connect (OSTI)

    Tortorelli, P.F.; Bishop, P.S.

    1990-01-01

    The corrosion of titanium-, iron-, and nickel-based aluminides by a highly aggressive, oxidizing NaNO{sub 3}(-KNO{sub 3})-Na{sub 2}O{sub 2} has been studied at 650{degree}C. It was shown that weight changes could be used to effectively evaluate corrosion behavior in the subject nitrate salt environments provided these data were combined with salt analyses and microstructural examinations. The studies indicated that the corrosion of relatively resistant aluminides by these nitrate salts proceeded by oxidation and a slow release from an aluminum-rich product layer into the salt at rates lower than that associated with many other types of metallic materials. The overall corrosion process and resulting rate depended on the particular aluminide being exposed. In order to minimize corrosion of nickel or iron aluminides, it was necessary to have aluminum concentrations in excess of 30 at. %. However, even at a concentration of 50 at. % Al, the corrosion resistance of TiAl was inferior to that of Ni{sub 3}Al and Fe{sub 3}Al. At higher aluminum concentrations, iron, nickel, and iron-nickel aluminides exhibited quite similar weight changes, indicative of the principal role of aluminum in controlling the corrosion process in NaNO{sub 3}(-KNO{sub 3})-Na{sub 2}O{sub 2} salts. 20 refs., 5 figs., 3 tabs.

  3. Use of tensiometer for in situ measurement of nitrate leaching

    SciTech Connect (OSTI)

    Li, K.; Reddy, M.R.

    1999-07-01

    In order to monitor nitrate leaching from non-point source pollution, this study used tensiometers to measure in situ nitrate concentration and soil-moisture potential. Instead of filling the tensiometers with pure water, the study filled the tensiometers with nitrate ionic strength adjuster (ISA, 1 M (NH{sub 4}){sub 2}SO{sub 4}). After the installation of the tensiometers at various depths along soil profiles, a portable pressure transducer was used to measure the soil moisture potential, and a nitrate electrode attached to an ion analyzer was used to measure the nitrate concentration in situ. The measurement was continuous and non-destructive. To test this method in the laboratory, eight bottles filled with pure sand were treated with known nitrate solutions, and a tensiometer was placed in each bottle. Measurements were taken every day for 30 days. Laboratory test showed a linear relationship between the known nitrate concentration and the tensiometer readings (R{sup 2} = 0.9990). Then a field test was conducted in a watermelon field with green manure mulch. Field data indicated a potential of nitrate leaching below the soil depth of 100 cm when crop uptake of nutrients was low.

  4. Method for improved decomposition of metal nitrate solutions

    DOE Patents [OSTI]

    Haas, P.A.; Stines, W.B.

    1981-01-21

    A method for co-conversion of aqueous solutions of one or more heavy metal nitrates is described, wherein thermal decomposition within a temperature range of about 300 to 800/sup 0/C is carried out in the presence of about 50 to 500% molar concentration of ammonium nitrate to total metal.

  5. Method for improved decomposition of metal nitrate solutions

    DOE Patents [OSTI]

    Haas, Paul A.; Stines, William B.

    1983-10-11

    A method for co-conversion of aqueous solutions of one or more heavy metal nitrates wherein thermal decomposition within a temperature range of about 300.degree. to 800.degree. C. is carried out in the presence of about 50 to 500% molar concentration of ammonium nitrate to total metal.

  6. Basic Energy Sciences Overview | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Baseload Concentrating Solar Power Generation In 2010, DOE issued the Baseload Concentrating Solar Power (CSP) Generation funding opportunity announcement (FOA). The following projects were selected under this competitive solicitation: Abengoa: Advanced Nitrate Salt Central Receiver Power Plant eSolar: Modular and Scalable Baseload Molten Salt Plant Conceptual Design and Feasibility General Atomics: Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage HiTek: Low-Cost

  7. Evaluation of Nitrate-Bearing Transuranic Waste Streams

    Energy Savers [EERE]

    OE-2: 2015-1 June 2015 Evaluation of Nitrate-Bearing Transuranic Waste Streams PURPOSE This Operating Experience Level 2 (OE-2) document provides actions to perform an evaluation...

  8. Decontamination of water using nitrate selective ion exchange resin

    DOE Patents [OSTI]

    Lockridge, J.E.; Fritz, J.S.

    1990-07-31

    A method for nitrate decontamination of water which involves passing the water through a bed of alkyl phosphonium anion exchange resin which has pendant alkyl groups of C[sub 3] or larger.

  9. Decontamination of water using nitrate selective ion exchange resin

    DOE Patents [OSTI]

    Lockridge, James E. (Ames, IA); Fritz, James S. (Ames, IA)

    1990-07-31

    A method for nitrate decontamination of water which involves passing the water through a bed of alkyl phosphonium anion exchange resin which has pendant alkyl groups of C.sub.3 or larger.

  10. Molecular recognition of nitrated fatty acids by PPAR[gamma

    SciTech Connect (OSTI)

    Li, Yong; Zhang, Jifeng; Schopfer, Francisco J.; Martynowski, Dariusz; Garcia-Barrio, Minerva T.; Kovach, Amanda; Suino-Powell, Kelly; Baker, Paul R.S.; Freeman, Bruce A.; Chen, Y. Eugene; Xu, H. Eric

    2010-03-08

    Peroxisome proliferator activated receptor-{gamma} (PPAR{gamma}) regulates metabolic homeostasis and adipocyte differentiation, and it is activated by oxidized and nitrated fatty acids. Here we report the crystal structure of the PPAR{gamma} ligand binding domain bound to nitrated linoleic acid, a potent endogenous ligand of PPAR{gamma}. Structural and functional studies of receptor-ligand interactions reveal the molecular basis of PPAR{gamma} discrimination of various naturally occurring fatty acid derivatives.

  11. Nonaqueous purification of mixed nitrate heat transfer media

    DOE Patents [OSTI]

    Fiorucci, Louis C.; Morgan, Michael J.

    1983-12-20

    A nonaqueous, in-line method for removing carbonate and hydroxide contamination from a molten mixed sodium nitrate/potassium nitrate heat transfer salt. The method comprises dissolving a stoichiometric quantity of anhydrous Ca(NO.sub.3).sub.2 in the melt whereby an insoluble CaCO.sub.3 and Ca(OH).sub.2 precipitate is formed. The precipitate can be removed by settling, filtration or floatation techniques.

  12. Analytical Characterization of the Thorium Nitrate Stockpile

    SciTech Connect (OSTI)

    Mattus, CH

    2003-12-30

    For several years, Oak Ridge National Laboratory (ORNL) has been supporting the Defense Logistics Agency-Defense National Stockpile Center with stewardship of a thorium nitrate (ThN) stockpile. The effort for fiscal year 2002 was to prepare a sampling and analysis plan and to use the activities developed in the plan to characterize the ThN stockpile. The sampling was performed in June and July 2002 by RWE NUKEM with oversight by ORNL personnel. The analysis was performed by Southwest Research Institute of San Antonio, Texas, and data validation was performed by NFT, Inc., of Oak Ridge, Tennessee. Of the {approx} 21,000 drums in the stockpile, 99 were sampled and 53 were analyzed for total metals composition, radiological constituents (using alpha and gamma spectrometry), and oxidizing characteristics. Each lot at the Curtis Bay Depot was sampled. Several of the samples were also analyzed for density. The average density of the domestic ThN was found to be 1.89 {+-} 0.08 g/cm{sup 3}. The oxidizer test was performed following procedures issued by the United Nations in 1999. Test results indicated that none of the samples tested was a Division 5.1 oxidizer per Department of Transportation definition. The samples were analyzed for total metals following the U.S. Environmental Protection Agency methods SW-846-6010B and 6020 (EPA 2003) using a combination of inductively coupled plasma--atomic emission spectroscopy and inductively coupled plasma--mass spectroscopy techniques. The results were used to compare the composition of the eight Resource Conservation and Recovery Act metals present in the sample (arsenic, barium, cadmium, chromium, lead, mercury, selenium, and silver) to regulatory limits. None of the samples was found to be hazardous for toxicity characteristics. The radiological analyses confirmed, when possible, the results obtained by the inductively coupled plasma analyses. These results--combined with the historical process knowledge acquired on the material and the results of previous tests--classified the ThN as low-level radioactive waste for disposal purposes. This characterization was necessary to continue the efforts associated with disposition of the material at the Nevada Test Site, Mercury, Nevada. With the current work presented in this report, the analytical characterization phase is completed for this source material stockpile.

  13. CX-003844: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Modular and Scalable Baseload Molten Salt Plant Conceptual Design and Feasibility ProjectCX(s) Applied: A9, B3.6Date: 09/07/2010Location(s): CaliforniaOffice(s): Energy Efficiency and Renewable Energy, Golden Field Office

  14. CX-003706: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Development and Demonstration of an Innovative Thermal Energy Storage System for Baseload Solar Power GenerationCX(s) Applied: A9, B3.6Date: 09/09/2010Location(s): Tampa, FloridaOffice(s): Energy Efficiency and Renewable Energy, Golden Field Office

  15. CX-003712: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Brayton-Cycle Baseload Power Tower Concentrated Solar Power SystemCX(s) Applied: A9, B3.6Date: 09/09/2010Location(s): Woburn, MassachusettsOffice(s): Energy Efficiency and Renewable Energy, Golden Field Office

  16. Electrochemical reduction of nitrate in the presence of an amide

    DOE Patents [OSTI]

    Dziewinski, Jacek J.; Marczak, Stanislaw

    2002-01-01

    The electrochemical reduction of nitrates in aqueous solutions thereof in the presence of amides to gaseous nitrogen (N.sub.2) is described. Generally, electrochemical reduction of NO.sub.3 proceeds stepwise, from NO.sub.3 to N.sub.2, and subsequently in several consecutive steps to ammonia (NH.sub.3) as a final product. Addition of at least one amide to the solution being electrolyzed suppresses ammonia generation, since suitable amides react with NO.sub.2 to generate N.sub.2. This permits nitrate reduction to gaseous nitrogen to proceed by electrolysis. Suitable amides include urea, sulfamic acid, formamide, and acetamide.

  17. EP-AREAG-PLAN-1248, R.0 TA-54 Area G Nitrate-Salt Waste Container Response Instructions

    Office of Environmental Management (EM)

    EP-AREAG-PLAN-1248, R.0 TA-54 Area G Nitrate-Salt Waste Container Response Instructions Effective Date: 5/28/2014 The Responsible Manager has determined that the following organizations' review/concurrence is required for the initial document and for major revisions a same type and level review is required. Review documentation is contained in the Document History File: EWMO Engineering LANL TRU Programs - Shipping and Safe Storage Disposition LANL TRU Programs - Drum Disposition Project LANL

  18. Engineering Options Assessment Report. Nitrate Salt Waste Stream Processing

    SciTech Connect (OSTI)

    Anast, Kurt Roy

    2015-11-13

    This report examines and assesses the available systems and facilities considered for carrying out remediation activities on remediated nitrate salt (RNS) and unremediated nitrate salt (UNS) waste containers at Los Alamos National Laboratory (LANL). The assessment includes a review of the waste streams consisting of 60 RNS, 29 above-ground UNS, and 79 candidate below-ground UNS containers that may need remediation. The waste stream characteristics were examined along with the proposed treatment options identified in the Options Assessment Report . Two primary approaches were identified in the five candidate treatment options discussed in the Options Assessment Report: zeolite blending and cementation. Systems that could be used at LANL were examined for housing processing operations to remediate the RNS and UNS containers and for their viability to provide repackaging support for remaining LANL legacy waste.

  19. Engineering Options Assessment Report: Nitrate Salt Waste Stream Processing

    SciTech Connect (OSTI)

    Anast, Kurt Roy

    2015-11-18

    This report examines and assesses the available systems and facilities considered for carrying out remediation activities on remediated nitrate salt (RNS) and unremediated nitrate salt (UNS) waste containers at Los Alamos National Laboratory (LANL). The assessment includes a review of the waste streams consisting of 60 RNS, 29 aboveground UNS, and 79 candidate belowground UNS containers that may need remediation. The waste stream characteristics were examined along with the proposed treatment options identified in the Options Assessment Report . Two primary approaches were identified in the five candidate treatment options discussed in the Options Assessment Report: zeolite blending and cementation. Systems that could be used at LANL were examined for housing processing operations to remediate the RNS and UNS containers and for their viability to provide repackaging support for remaining LANL legacy waste.

  20. Waste Isolation Pilot Plant Nitrate Salt Bearing Waste Container

    Office of Environmental Management (EM)

    Nitrate Salt Bearing Waste Container Isolation Plan Prepared in Response to New Mexico Environment Department Administrative Order 05-20001 Issued May 20, 2014 1.0 INTRODUCTION The purpose of this document is to provide the Plan required by the New Mexico Environment Department (NMED) Administrative Order 05-20001 (Order) issued on May 20, 2014 to the U. S. Department of Energy (DOE) and Nuclear Waste Partnership LLC (NWP), collectively referred to as the Permittees. The Order, at paragraph 22,

  1. WIPP Nitrate Salt Bearing Waste Container Isolation Plan Implementation Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nitrate Salt Bearing Waste Container Isolation Plan Implementation Update May 12, 2015 Panel 6 and Panel 7, Room 7 a. Rollback * Contamination Assessment-This prerequisite is complete and therefore status updates are no longer required. * Fixing/Decontamination Activities-Decontaminated equipment has been removed from Room 7 of Panel 7 to prepare for Room 7 closure activities. Remaining items in Panel 7, Room 7 include thirteen empty magnesium oxide racks, about 200 roof bolts, nine messenger

  2. Remediated Nitrate Salt Drums Storage at Los Alamos National Laboratory

    Office of Environmental Management (EM)

    Remediated Nitrate Salt Drums Storage at Los Alamos National Laboratory Background Technical Area (TA) 54 is Los Alamos National Laboratory's transuranic (TRU) and low-level waste storage, characterization, and remediation area. The 63-acre site is located one mile from the community of White Rock and approximately one-eighth mile from the boundary be- tween Pueblo de San Ildefonso and the Laboratory. As a part of its national security mission, the Laboratory conducts research that generates

  3. Watershed scale fungal community characterization along a pH gradient in a subsurface environment co-contaminated with uranium and nitrate

    SciTech Connect (OSTI)

    Jasrotia, Puja; Green, Stefan; Canion, Andy; Overholt, Will; Prakash, Om; Wafula, Dennis; Hubbard, Daniela; Watson, David B; Schadt, Christopher Warren; Brooks, Scott C; Kostka,

    2014-01-01

    The objective of this study was to characterize fungal communities in a subsurface environment co-contaminated with uranium and nitrate at the watershed scale, and to determine the potential contribution of fungi to contaminant transformation (nitrate attenuation). The abundance, distribution and diversity of fungi in subsurface groundwater samples were determined using quantitative and semi-quantitative molecular techniques, including quantitative PCR of eukaryotic SSU rRNA genes and pyrosequencing of fungal internal transcribed spacer (ITS) regions. Potential bacterial and fungal denitrification was assessed in sediment-groundwater slurries amended with antimicrobial compounds and in fungal pure cultures isolated from subsurface. Our results demonstrate that subsurface fungal communities are dominated by members of the phylum Ascomycota, and a pronounced shift in fungal community composition occurs across the groundwater pH gradient at the field site, with lower diversity observed under acidic (pH < 4.5) conditions. Fungal isolates recovered from subsurface sediments were shown to reduce nitrate to nitrous oxide, including cultures of the genus Coniochaeta that were detected in abundance in pyrosequence libraries of site groundwater samples. Denitrifying fungal isolates recovered from the site were classified, and found to be distributed broadly within the phylum Ascomycota, and within a single genus within the Basidiomycota. Potential denitrification rate assays with sediment-groundwater slurries showed the potential for subsurface fungi to reduce nitrate to nitrous oxide under in situ acidic pH conditions.

  4. Real time in situ detection of organic nitrates in atmospheric aerosols

    SciTech Connect (OSTI)

    Rollins, Andrew W.; Smith, Jared D.; Wilson, Kevin R.; Cohen, Ronald C.

    2010-06-11

    A new field instrument is described that quantifies total particle phase organic nitrates. The instrument is based on the thermal dissociation laser induced fluorescence (TD-LIF) method that thermally converts nitrates to NO2 which is then detected by LIF. This instrument is unique in its ability to provide fast sensitive measurements of particle phase organic nitrates, without interference from inorganic nitrate. Here we use it to quantify organic nitrates in SOA generated from high-NOx photooxidation of limonene, a-pinene, D-3-carene, and tridecane. In these experiments the organic nitrate moiety is observed to be 6-15percent of the total SOA mass, depending on the organic precursor.

  5. Low-melting point inorganic nitrate salt heat transfer fluid

    DOE Patents [OSTI]

    Bradshaw, Robert W.; Brosseau, Douglas A.

    2009-09-15

    A low-melting point, heat transfer fluid made of a mixture of four inorganic nitrate salts: 9-18 wt % NaNO.sub.3, 40-52 wt % KNO.sub.3, 13-21 wt % LiNO.sub.3, and 20-27 wt % Ca(NO.sub.3).sub.2. These compositions can have liquidus temperatures less than 100 C; thermal stability limits greater than 500 C; and viscosity in the range of 5-6 cP at 300 C; and 2-3 cP at 400 C.

  6. Memo - Legacy Technical Area (TA)-55 Nitrate Salt Wastes at TA...

    Office of Environmental Management (EM)

    on February 14, 2014, report in Attachment F. Bibliography and References, are available on various public websites. PDF icon Memo - Legacy Technical Area (TA)-55 Nitrate Salt ...

  7. Investigating In Situ Bioremediation Approaches for Sustained Uranium Immobilization Independent of Nitrate Reduction

    SciTech Connect (OSTI)

    Phelps, Tommy; Balkwill, David

    2006-06-01

    The daunting prospect of complete nitrate removal at DOE sites, such as the ERSP Oak Ridge Field Research Center (FRC), provides strong incentive to explore bioremediation strategies that will allow for uranium bioreduction and long-term stabilization in the presence of nitrate. The cost and effort required for complete nitrate removal from the FRC and similar DOE-contaminated sites may prove to be unworkable. For example, field tests of uranium bioreduction at the FRC have shown that nitrate levels rebound quickly and completely after cessation of active biostimulation.

  8. Project Profile: Modular and Scalable Baseload Molten Salt Plant...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    J. E. Pacheco, C. Moursund, D. Rogers; D. Wasyluk. "Conceptual Design of a 100 MWe Modular Molten Salt Power Tower Plant" in Proceedings of SolarPACES 2011, Granada Spain, ...

  9. Project Profile: Baseload CSP Generation Integrated with Sulfur...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Parasitic Loads for Packed Bed Reactors," Proceedings of 16th Annual SolarPACES Conference, Granada, Spain, 2010. SunShot logo Progress Reports May 2013 February 2013 November 2012

  10. Innovative Phase hange Thermal Energy Storage Solution for Baseload Power

    Broader source: Energy.gov [DOE]

    This presentation was delivered at the SunShot Concentrating Solar Power (CSP) Program Review 2013, held April 23–25, 2013 near Phoenix, Arizona.

  11. Innovative Phase Change Thermal Energy Storage Solution for Baseload...

    Office of Scientific and Technical Information (OSTI)

    Close Cite: Bibtex Format Close 0 pages in this document matching the terms "" Search For Terms: Enter terms in the toolbar above to search the full text of this document for ...

  12. Baseload coal investment decisions under uncertain carbon legislation

    SciTech Connect (OSTI)

    Joule A. Bergerson; Lester B. Lave

    2007-05-15

    More than 50% of electricity in the U.S. is generated by coal. The U.S. has large coal resources, the cheapest fuel in most areas. Coal fired power plants are likely to continue to provide much of U.S. electricity. However, the type of power plant that should be built is unclear. Technology can reduce pollutant discharges and capture and sequester the CO{sub 2} from coal-fired generation. The U.S. Energy Policy Act of 2005 provides incentives for large scale commercial deployment of Integrated Coal Gasification Combined Cycle (IGCC) systems (e.g., loan guarantees and project tax credits). This analysis examines whether a new coal plant should be pulverized coal (PC) or IGCC. Do stricter emissions standards (PM, SO{sub 2}, NOx, Hg) justify the higher costs of IGCC over PC? How does potential future carbon legislation affect the decision to add carbon capture and storage (CCS) technology? Finally, can the impact of uncertain carbon legislation be minimized? We find that SO{sub 2}, NOx, PM, and Hg emission standards would have to be far more stringent than twice current standards to justify the increased costs of the IGCC system. A CO{sub 2} tax less than $29/ton would lead companies to continuing to choose PC, paying the tax for emitted CO{sub 2}. The earlier a decision-maker believes the carbon tax will be imposed and the higher the tax, the more likely companies will choose IGCC with CCS. Having government announce the date and level of a carbon tax would promote more sensible decisions, but government would have to use a tax or subsidy to induce companies to choose the technology that is best for society. 14 refs., 6 figs., 4 tabs.

  13. Innovative Phase Change Thermal Energy Storage Solution for Baseload...

    Office of Scientific and Technical Information (OSTI)

    The unique innovation in this project is an integrated TESpool boiler heat transfer system that is the simplest approach identified to date and arguably has the best potential for ...

  14. Brayton Cycle Baseload Power Tower CSP System | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Mark Cecchini-Beaver at the University of Idaho is one of ten new participants in the Hydro Fellowship Program. | Photo courtesy of the Hydro Research Foundation. Mark Cecchini-Beaver at the University of Idaho is one of ten new participants in the Hydro Fellowship Program. | Photo courtesy of the Hydro Research Foundation. Jonathan Bartlett Wind Powering America National Coordinator What are the key facts? Today the Energy Department announced 2012 selections for the Hydro Fellowship Program.

  15. SEPARATION OF BARIUM VALUES FROM URANYL NITRATE SOLUTIONS

    DOE Patents [OSTI]

    Tompkins, E.R.

    1959-02-24

    The separation of radioactive barium values from a uranyl nitrate solution of neutron-irradiated uranium is described. The 10 to 20% uranyl nitrate solution is passed through a flrst column of a cation exchange resin under conditions favoring the adsorption of barium and certain other cations. The loaded resin is first washed with dilute sulfuric acid to remove a portion of the other cations, and then wash with a citric acid solution at pH of 5 to 7 to recover the barium along with a lesser amount of the other cations. The PH of the resulting eluate is adjusted to about 2.3 to 3.5 and diluted prior to passing through a smaller second column of exchange resin. The loaded resin is first washed with a citric acid solution at a pH of 3 to elute undesired cations and then with citric acid solution at a pH of 6 to eluts the barium, which is substantially free of undesired cations.

  16. Solvent Modification in Ion-Pair Extraction: Effect on Sodium Nitrate Transport in Nitrobenzene Using a Crown Ether

    SciTech Connect (OSTI)

    Levitskaia, Tatiana G.; Lumetta, Gregg J.

    2005-10-31

    A comparative quantitative analysis of the effect of solvent modifiers on an ion-pair extraction of an inorganic salt by a crown ether was conducted. Two classes of the solvent modifiers that possess electron-pair donor (EPD) or hydrogen-bond donor (HBD) groups were investigated. The equilibrium constants corresponding to the extraction of sodium nitrate into nitrobenzene (NB) employing model neutral host cis-syn-cis-dicyclohexano-18-crown-6 (1) with and without solvent modifier were determined using the SXLSQI computer model. For a series of EPD modifiers—including tri-n-butyl- and tri-phenylphosphate, tri-n-butyl- and tri-phenylphosphine oxide, N,N-di-n-butyl- and N,N-di-phenyl acetamide—the enhancement of the NaNO3 extraction by 1 was found to be dependent on the hydrogen-bond acceptance ability of the modifier quantified by the b solvatochromic parameter. Application of the solvent EPD modifier improved solvation of the sodium ion, lowering the large energy barrier of Na+ partitioning into the extraction phase. A HBD modifier 3,5-di-t-butylphenol 8 that forms strong hydrogen bonds with nitrate anion in NB, exhibited even greater enhancement of the NaNO3 extraction by 1. The determined extraction constants were correlated with the b or a solvatochromic parameters of the solvent modifiers and linear trends were observed. Hydrogen bond interaction between 3,5-di-t-butylphenol 8 and nitrate anion in the presence of the sodium-loaded crown ether in the extraction phases was studied by vibrational spectroscopy. Formation of the simple 1:1 adduct was demonstrated.

  17. Stainless steel corrosion by molten nitrates : analysis and lessons learned.

    SciTech Connect (OSTI)

    Kruizenga, Alan Michael

    2011-09-01

    A secondary containment vessel, made of stainless 316, failed due to severe nitrate salt corrosion. Corrosion was in the form of pitting was observed during high temperature, chemical stability experiments. Optical microscopy, scanning electron microscopy and energy dispersive spectroscopy were all used to diagnose the cause of the failure. Failure was caused by potassium oxide that crept into the gap between the primary vessel (alumina) and the stainless steel vessel. Molten nitrate solar salt (89% KNO{sub 3}, 11% NaNO{sub 3} by weight) was used during chemical stability experiments, with an oxygen cover gas, at a salt temperature of 350-700 C. Nitrate salt was primarily contained in an alumina vessel; however salt crept into the gap between the alumina and 316 stainless steel. Corrosion occurred over a period of approximately 2000 hours, with the end result of full wall penetration through the stainless steel vessel; see Figures 1 and 2 for images of the corrosion damage to the vessel. Wall thickness was 0.0625 inches, which, based on previous data, should have been adequate to avoid corrosion-induced failure while in direct contact with salt temperature at 677 C (0.081-inch/year). Salt temperatures exceeding 650 C lasted for approximately 14 days. However, previous corrosion data was performed with air as the cover gas. High temperature combined with an oxygen cover gas obviously drove corrosion rates to a much higher value. Corrosion resulted in the form of uniform pitting. Based on SEM and EDS data, pits contained primarily potassium oxide and potassium chromate, reinforcing the link between oxides and severe corrosion. In addition to the pitting corrosion, a large blister formed on the side wall, which was mainly composed of potassium, chromium and oxygen. All data indicated that corrosion initiated internally and moved outward. There was no evidence of intergranular corrosion nor were there any indication of fast pathways along grain boundaries. Much of the pitting occurred near welds; however this was the hottest region in the chamber. Pitting was observed up to two inches above the weld, indicating independence from weld effects.

  18. Analysis of Enriched Uranyl Nitrate in Nested Annular Tank Array

    SciTech Connect (OSTI)

    John D. Bess; James D. Cleaver

    2009-06-01

    Two series of experiments were performed at the Rocky Flats Critical Mass Laboratory during the 1980s using highly enriched (93%) uranyl nitrate solution in annular tanks. [1, 2] Tanks were of typical sizes found in nuclear production plants. Experiments looked at tanks of varying radii in a co-located set of nested tanks, a 1 by 2 array, and a 1 by 3 array. The co-located set of tanks had been analyzed previously [3] as a benchmark for inclusion within the International Handbook of Evaluated Criticality Safety Benchmark Experiments. [4] The current study represents the benchmark analysis of the 1 by 3 array of a series of nested annular tanks. Of the seventeen configurations performed in this set of experiments, twelve were evaluated and nine were judged as acceptable benchmarks.

  19. Hydroxylamine Nitrate Decomposition under Non-radiological Conditions

    SciTech Connect (OSTI)

    McFarlane, Joanna; Delmau, Laetitia Helene; DePaoli, David W.; Mattus, Catherine H.; Phelps, Clarice E.; Roach, Benjamin D.

    2015-07-01

    Hydroxylamine nitrate (HAN) is used to reduce Pu(IV) to Pu(III) in the separation of plutonium from uranium. HAN becomes unstable under certain conditions and has been known to explode, causing injury to humans including death. Hence, it is necessary to deactivate HAN once the reduction of plutonium is finished. This report reviews what is known about the chemistry of HAN and various methods to achieve a safe decomposition. However, there are areas where more information is needed to make a decision about the handling of HAN in reprocessing of nuclear fuel. Experiments have demonstrated a number of non-radiolytic ways to safely decompose HAN, including heating in HNO3, photolytic oxidation in the presence of H2O2, and the addition of a metal such as Fe(III) that will oxidize the HAN.

  20. Combined Extraction of Cesium and Strontium from Akaline Nitrate Solutions

    SciTech Connect (OSTI)

    Delmau, Laetitia Helene; Bonnesen, Peter V; Engle, Nancy L; Haverlock, Tamara; Sloop Jr, Frederick {Fred} V; Moyer, Bruce A

    2006-01-01

    The combined extraction of cesium and strontium from caustic wastes can be achieved by adding a crown ether and a carboxylic acid to the Caustic-Side Solvent Extraction (CSSX) solvent. The ligand 4,4'(5')-di(tert-butyl)cyclohexano-18-crown-6 and one of four different carboxylic acids were combined with the components of the CSSX solvent optimized for the extraction of cesium, allowing for the simultaneous extraction of cesium and strontium from alkaline nitrate media simulating alkaline high level wastes present at the U.S. Department of Energy Savannah River Site. Extraction and stripping experiments were conducted independently and exhibited adequate results for mimicking waste simulant processing through batch contacts. The promising results of these batch tests showed that the system could reasonably be tested on actual waste.

  1. Solidification of Acidic, High Nitrate Nuclear Wastes by Grouting or Absorption on Silica Gel

    SciTech Connect (OSTI)

    A. K. Herbst; S. V. Raman; R. J. Kirkham

    2004-01-01

    The use of grout and silica gel were explored for the solidification of four types of acidic, high nitrate radioactive wastes. Two methods of grouting were tested: direct grouting and pre-neutralization. Two methods of absorption on silica gel were also tested: direct absorption and rotary spray drying. The waste simulant acidity varied between 1 N and 12 N. The waste simulant was neutralized by pre-blending calcium hydroxide with Portland cement and blast furnace slag powders prior to mixing with the simulant for grout solidification. Liquid sodium hydroxide was used to partially neutralize the simulant to a pH above 2 and then it was absorbed for silica gel solidification. Formulations for each of these methods are presented along with waste form characteristics and properties. Compositional variation maps for grout formulations are presented which help determine the optimum "recipe" for a particular waste stream. These maps provide a method to determine the proportions of waste, calcium hydroxide, Portland cement, and blast furnace slag that provide a waste form that meets the disposal acceptance criteria. The maps guide researchers in selecting areas to study and provide an operational envelop that produces acceptable waste forms. The grouts both solidify and stabilize the wastes, while absorption on silica gel produces a solid waste that will not pass standard leaching procedures (TCLP) if required. Silica gel wastes can be made to pass most leach tests if heated to 600C.

  2. Preliminary safe-handling experiments on a mixture of cesium nickel ferrocyanide and equimolar sodium nitrate/nitrite

    SciTech Connect (OSTI)

    Scheele, R.D. ); Cady, H.H. )

    1992-01-01

    As part of the Hanford Site's evaluation of the potential hazards associated with the storage of ferrocyanide wastes generated when ferrocyanide was used to scavenge radiocesium from waste supernates in the 1950s, the Pacific Northwest Laboratory (PNL) subcontracted with Los Alamos National Laboratory (LANL) to perform a series of sensitivity tests. These test supplement PNL's thermal sensitivity testing results on the reactivity of cesium nickel ferrocyanide (Cs{sub 2}NiFe(CN){sub 6}) and nitrates and nitrites (Burger and Schelle 1991). LANL used a selected set of their standard tests to determine the sensitivity of a mixture of Cs{sub 2}NiFe(CN){sub 6} (FECN-1) and equimolar sodium nitrate and nitrite oxidant to nonthermal and thermal stimuli. The stoichiometric ratio of oxidant to Cs{sub 2}NiFe(CN){sub 6} in the tested mixture FECN-1 was 1.1:1. The appendix presents the results of the LANL testing of the sensitivity of FECN-1 to initiation by mechanical impact, spark, friction, and various thermal conditions. In addition to the sensitivity testing, LANL used an Accelerating Rate Calorimeter (ARC) to estimate the behavior of large batches of the mixture.

  3. Preliminary safe-handling experiments on a mixture of cesium nickel ferrocyanide and equimolar sodium nitrate/nitrite

    SciTech Connect (OSTI)

    Scheele, R.D.; Cady, H.H.

    1992-01-01

    As part of the Hanford Site`s evaluation of the potential hazards associated with the storage of ferrocyanide wastes generated when ferrocyanide was used to scavenge radiocesium from waste supernates in the 1950s, the Pacific Northwest Laboratory (PNL) subcontracted with Los Alamos National Laboratory (LANL) to perform a series of sensitivity tests. These test supplement PNL`s thermal sensitivity testing results on the reactivity of cesium nickel ferrocyanide (Cs{sub 2}NiFe(CN){sub 6}) and nitrates and nitrites (Burger and Schelle 1991). LANL used a selected set of their standard tests to determine the sensitivity of a mixture of Cs{sub 2}NiFe(CN){sub 6} (FECN-1) and equimolar sodium nitrate and nitrite oxidant to nonthermal and thermal stimuli. The stoichiometric ratio of oxidant to Cs{sub 2}NiFe(CN){sub 6} in the tested mixture FECN-1 was 1.1:1. The appendix presents the results of the LANL testing of the sensitivity of FECN-1 to initiation by mechanical impact, spark, friction, and various thermal conditions. In addition to the sensitivity testing, LANL used an Accelerating Rate Calorimeter (ARC) to estimate the behavior of large batches of the mixture.

  4. Isotopic identification of soil and permafrost nitrate sources in an Arctic tundra ecosystem

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Heikoop, Jeffrey M.; Throckmorton, Heather M.; Newman, Brent D.; Perkins, George B.; Iversen, Colleen M.; Chowdhury, Taniya Roy; Romanovsky, Vladimir; Graham, David E.; Norby, Richard J.; Wilson, Cathy J.; et al

    2015-05-13

    The nitrate (NO3–) dual isotope approach was applied to snowmelt, tundra active layer pore waters, and underlying permafrost in Barrow, Alaska, USA, to distinguish between NO3– derived from atmospheric deposition versus that derived from microbial nitrification.

  5. EMRTC Report RF 10-13: Application to LANL Evaporator Nitrate...

    Office of Environmental Management (EM)

    and recommendation. Conclusions: 1. Nitrate salts not yet remediated having no free liquid should be mixed with at least 1.2 volumes of Kitty LitterZeolite clay per...

  6. Ab initio calculations of singlet and triplet excited states of chlorine nitrate and nitric acid

    SciTech Connect (OSTI)

    Grana, A.M.; Head-Gordon, M. |; Lee, T.J.

    1995-03-16

    Ab initio calculations of vertical excitations to single and triplet excited states of chlorine nitrate and nitric acid are reported, using the CIS, CIS(D), and CCSD methods. The effects of basis set composition and calculational methods are investigated. The nature of the electronic transitions are examined by decomposing the difference density into the sum of detachment and attachment densities. Counterparts for the three lowest singlet excited states of nitric acid survive relatively unperturbed in chlorine nitrate, while other low lying singlet states of chlorine nitrate appear to be directly dissociative in the CIO chromophore. These results suggest an assignment of the two main peaks in the experimental chlorine nitrate absorption spectrum. In addition, triplet vertical excitations and the lowest optimized triplet geometries of both molecules are studied. 70 refs., 2 figs., 6 tabs.

  7. Waste Isolation Pilot Plant Nitrate Salt Bearing Waste Container Isolation Plan

    Broader source: Energy.gov [DOE]

    The purpose of this document is to provide the Plan required by the New Mexico Environment Department Administrative Order 05-20001 issued on May 20, 2014 to the U. S. Department of Energy and Nuclear Waste Partnership LLC. The Order, at paragraph 22, requires the Permittees to submit a WIPP Nitrate Salt Bearing Waste Container Isolation Plan for identified nitrate salt bearing waste disposed in the Waste Isolation Pilot Plant underground disposal facility.

  8. Analytical Chemistry and Materials Characterization Results for Debris Recovered from Nitrate Salt Waste Drum S855793

    SciTech Connect (OSTI)

    Martinez, Patrick Thomas; Chamberlin, Rebecca M.; Schwartz, Daniel S.; Worley, Christopher Gordon; Garduno, Katherine; Lujan, Elmer J. W.; Borrego, Andres Patricio; Castro, Alonso; Colletti, Lisa Michelle; Fulwyler, James Brent; Holland, Charlotte S.; Keller, Russell C.; Klundt, Dylan James; Martinez, Alexander; Martin, Frances Louise; Montoya, Dennis Patrick; Myers, Steven Charles; Porterfield, Donivan R.; Schake, Ann Rene; Schappert, Michael Francis; Soderberg, Constance B.; Spencer, Khalil J.; Stanley, Floyd E.; Thomas, Mariam R.; Townsend, Lisa Ellen; Xu, Ning

    2015-09-16

    Solid debris was recovered from the previously-emptied nitrate salt waste drum S855793. The bulk sample was nondestructively assayed for radionuclides in its as-received condition. Three monoliths were selected for further characterization. Two of the monoliths, designated Specimen 1 and 3, consisted primarily of sodium nitrate and lead nitrate, with smaller amounts of lead nitrate oxalate and lead oxide by powder x-ray diffraction. The third monolith, Specimen 2, had a complex composition; lead carbonate was identified as the predominant component, and smaller amounts of nitrate, nitrite and carbonate salts of lead, magnesium and sodium were also identified. Microfocused x-ray fluorescence (MXRF) mapping showed that lead was ubiquitous throughout the cross-sections of Specimens 1 and 2, while heteroelements such as potassium, calcium, chromium, iron, and nickel were found in localized deposits. MXRF examination and destructive analysis of fragments of Specimen 3 showed elevated concentrations of iron, which were broadly distributed through the sample. With the exception of its high iron content and low carbon content, the chemical composition of Specimen 3 was within the ranges of values previously observed in four other nitrate salt samples recovered from emptied waste drums.

  9. Laboratory study of nitrate photolysis in Antarctic snow. I. Observed quantum yield, domain of photolysis, and secondary chemistry

    SciTech Connect (OSTI)

    Meusinger, Carl; Johnson, Matthew S. [Department of Chemistry, University of Copenhagen, Copenhagen (Denmark); Berhanu, Tesfaye A.; Erbland, Joseph; Savarino, Joel, E-mail: jsavarino@lgge.obs.ujf-grenoble.fr [Univ. Grenoble Alpes, LGGE, F-38000 Grenoble (France); CNRS, LGGE, F-38000 Grenoble (France)

    2014-06-28

    Post-depositional processes alter nitrate concentration and nitrate isotopic composition in the top layers of snow at sites with low snow accumulation rates, such as Dome C, Antarctica. Available nitrate ice core records can provide input for studying past atmospheres and climate if such processes are understood. It has been shown that photolysis of nitrate in the snowpack plays a major role in nitrate loss and that the photolysis products have a significant influence on the local troposphere as well as on other species in the snow. Reported quantum yields for the main reaction spans orders of magnitude apparently a result of whether nitrate is located at the air-ice interface or in the ice matrix constituting the largest uncertainty in models of snowpack NO{sub x} emissions. Here, a laboratory study is presented that uses snow from Dome C and minimizes effects of desorption and recombination by flushing the snow during irradiation with UV light. A selection of UV filters allowed examination of the effects of the 200 and 305nm absorption bands of nitrate. Nitrate concentration and photon flux were measured in the snow. The quantum yield for loss of nitrate was observed to decrease from 0.44 to 0.003 within what corresponds to days of UV exposure in Antarctica. The superposition of photolysis in two photochemical domains of nitrate in snow is proposed: one of photolabile nitrate, and one of buried nitrate. The difference lies in the ability of reaction products to escape the snow crystal, versus undergoing secondary (recombination) chemistry. Modeled NO{sub x} emissions may increase significantly above measured values due to the observed quantum yield in this study. The apparent quantum yield in the 200nm band was found to be ?1%, much lower than reported for aqueous chemistry. A companion paper presents an analysis of the change in isotopic composition of snowpack nitrate based on the same samples as in this study.

  10. Uranyl nitrate-exposed rat alveolar macrophages cell death: Influence of superoxide anion and TNF ? mediators

    SciTech Connect (OSTI)

    Orona, N.S.; Tasat, D.R.

    2012-06-15

    Uranium compounds are widely used in the nuclear fuel cycle, military and many other diverse industrial processes. Health risks associated with uranium exposure include nephrotoxicity, cancer, respiratory, and immune disorders. Macrophages present in body tissues are the main cell type involved in the internalization of uranium particles. To better understand the pathological effects associated with depleted uranium (DU) inhalation, we examined the metabolic activity, phagocytosis, genotoxicity and inflammation on DU-exposed rat alveolar macrophages (12.5200 ?M). Stability and dissolution of DU could differ depending on the dissolvent and in turn alter its biological action. We dissolved DU in sodium bicarbonate (NaHCO{sub 3} 100 mM) and in what we consider a more physiological vehicle resembling human internal media: sodium chloride (NaCl 0.9%). We demonstrate that uranyl nitrate in NaCl solubilizes, enters the cell, and elicits its cytotoxic effect similarly to when it is diluted in NaHCO{sub 3}. We show that irrespective of the dissolvent employed, uranyl nitrate impairs cell metabolism, and at low doses induces both phagocytosis and generation of superoxide anion (O{sub 2}{sup ?}). At high doses it provokes the secretion of TNF? and through all the range of doses tested, apoptosis. We herein suggest that at DU low doses O{sub 2}{sup ?} may act as the principal mediator of DNA damage while at higher doses the signaling pathway mediated by O{sub 2}{sup ?} may be blocked, prevailing damage to DNA by the TNF? route. The study of macrophage functions after uranyl nitrate treatment could provide insights into the pathophysiology of uranium?related diseases. -- Highlights: ? Uranyl nitrate effect on cultured macrophages is linked to the doses and independent of its solubility. ? At low doses uranyl nitrate induces generation of superoxide anion. ? At high doses uranyl nitrate provokes secretion of TNF?. ? Uranyl nitrate induces apoptosis through all the range of doses tested.

  11. Providing Additional Pressure Relief to the Remediated Nitrate Salt

    Broader source: Energy.gov [DOE]

    After the radiological event on February 14, 2014 at the Waste Isolation Pilot Plant (WIPP), Department of Energy (DOE) scientists from several national laboratories conducted extensive experiments and modeling studies to determine what caused the drum to breach.

  12. Biological Redox Cycling Of Iron In Nontronite And Its Potential Application In Nitrate Removal

    SciTech Connect (OSTI)

    Zhao, Linduo; Dong, Hailiang; Kukkadapu, Ravi K.; Zeng, Qiang; Edelmann, Richard E.; Pentrak, Martin; Agrawal, Abinash

    2015-05-05

    Redox cycling of structural Fe in phyllosilicates provides a potential method to remediate nitrate contamination in natural environment. Past research has only studied chemical redox cycles or a single biologically mediated redox cycle of Fe in phyllosilicates. The objective of this research was to study three microbially driven redox cycles of Fe in one phyllosilicate, nontronite (NAu-2). During the reduction phase structural Fe(III) in NAu-2 served as electron acceptor, lactate as electron donor, AQDS as electron shuttle, and dissimilatory Fe(III)-reducing bacteria Shewanella putrefaciens CN32 as mediator in bicarbonate-buffered and PIPES-buffered media. During the oxidation phase, biogenic Fe(II) served an electron donor, nitrate as electron acceptor, and nitrate-dependent Fe(II)-oxidizing bacteria Pseudogulbenkiania sp. strain 2002 as mediator in the same media. For all three cycles, structural Fe in NAu-2 was able to reversibly undergo 3 redox cycles without significant reductive or oxidative dissolution. X-ray diffraction and scanning and transmission electron microscopy revealed that NAu-2 was the dominant residual mineral throughout the 3 redox cycles with some dissolution textures but no significant secondary mineralization. Mssbauer spectroscopy revealed that Fe(II) in bio-reduced samples likely occurred in two distinct environments, at edges and the interior of the NAu-2 structure. Nitrate was completely reduced to nitrogen gas under both buffer conditions and this extent and rate did not change with Fe redox cycles. Mssbauer spectroscopy further revealed that nitrate reduction was coupled to predominant/preferred oxidation of edge Fe(II). These results suggest that structural Fe in phyllosilicates may represent a renewable source to continuously remove nitrate in natural environments.

  13. Reduction of Nitrate in Shewanella oneidensis depends on atypical NAP and

    Office of Scientific and Technical Information (OSTI)

    NRF systems with NapB as a preferred electron transport protein from CymA to NapA (Journal Article) | SciTech Connect Reduction of Nitrate in Shewanella oneidensis depends on atypical NAP and NRF systems with NapB as a preferred electron transport protein from CymA to NapA Citation Details In-Document Search Title: Reduction of Nitrate in Shewanella oneidensis depends on atypical NAP and NRF systems with NapB as a preferred electron transport protein from CymA to NapA In the genome of

  14. EMRTC Report RF 10-13: Application to LANL Evaporator Nitrate Salts

    Office of Environmental Management (EM)

    Amount of Zeolite Required to Meet the Constraints Established by the EMRTC Report RF 10-13: Application to LANL Evaporator Nitrate Salts 5/8/2012 LANL-Carlsbad Office Difficult Waste Team P2010-3306 Amount of Zeolite Required to Meet the Constraints Established by the EMRTC Report RF 10- 13: Application to LANL Evaporator Nitrate Salts 2 Purpose: The following document was developed in support of the Los Alamos National Laboratory Transuranic Program (LTP) by the LANL-Carlsbad Office, Difficult

  15. [Task 1.] Biodenitrification of low nitrate solar pond waters using sequencing batch reactors. [Task 2.] Solidification/stabilization of high strength and biodenitrified heavy metal sludges with a Portland cement/flyash system

    SciTech Connect (OSTI)

    Figueroa, L.; Cook, N.E.; Siegrist, R.L.; Mosher, J.; Terry, S.; Canonico, S.

    1995-09-22

    Process wastewater and sludges were accumulated on site in solar evaporation ponds during operations at the Department of Energy's Rocky Flats Plant (DOE/RF). Because of the extensive use of nitric acid in the processing of actinide metals, the process wastewater has high concentrations of nitrate. Solar pond waters at DOE/RF contain 300-60,000 mg NO{sub 3}{sup {minus}}/L. Additionally, the pond waters contain varying concentrations of many other aqueous constituents, including heavy metals, alkali salts, carbonates, and low level radioactivity. Solids, both from chemical precipitation and soil material deposition, are also present. Options for ultimate disposal of the pond waters are currently being evaluated and include stabilization and solidification (S/S) by cementation. Removal of nitrates can enhance a wastes amenability to S/S, or can be a unit operation in another treatment scheme. Nitrate removal is also a concern for other sources of pollution at DOE/RF, including contaminated groundwater collected by interceptor trench systems. Finally, nitrate pollution is a problem at many other DOE facilities where actinide metals were processed. The primary objective of this investigation was to optimize biological denitrification of solar pond waters with nitrate concentrations of 300--2,100 mg NO{sub 3}{sup {minus}}/L to below the drinking water standard of 45 mg NO{sub 3}{sup {minus}}/L (10 mg N/L). The effect of pH upon process stability and denitrification rate was determined. In addition, the effect Cr(VI) on denitrification and fate of Cr(VI) in the presence of denitrifying bacteria was evaluated.

  16. In situ BTEX biotransformation under enhanced nitrate- and sulfate-reducing conditions

    SciTech Connect (OSTI)

    Reinhard, M.; Shang, S.; Kitanidis, P.K.; Orwin, E.; Hopkins, G.D.; LeBron, C.A.

    1997-01-01

    In situ anaerobic biotransformation of BTEX (benzene, toluene, ethylbenzene, o-xylene, and m-xylene) was investigated under enhanced nitrate- and sulfate-reducing conditions. Controlled amounts of BTEX compounds added to slugs of treated groundwater were released into a gasoline-contaminated aquifer at Seal Beach, CA. In a series of studies, the slugs, 470-1700 L in volume, were released into the aquifer through a multi-port injection/extraction well and were subsequently withdrawn over a 2-3 month period. To evaluate unamended in situ conditions, the injectate was treated with granular activated carbon (GAC) and augmented with bromide as a tracer. To evaluate nitrate- and sulfate-reducing conditions, the injectate was also deionized and augmented with 200-300 {mu}g/L BTEX, nitrate or sulfate, and background electrolytes. Under unamended conditions, transformation appeared to be limited to the slow removal of toluene and m,p-xylene (i.e. sum of m+p-xylene). Under nitrate-reducing conditions, toluene, ethylbenzene, and m-xylene were transformed without a lag phase in less than 10 days, and o-xylene was transformed in 72 days. Under sulfate-reducing conditions, toluene, m-xylene and o-xylene were completely transformed in less then 50 days, and ethylbenzene was removed in 60 days. Benzene appeared to be removed under sulfate-reducing conditions, but the trend was pronounced only at some levels. 47 refs., 11 figs., 2 tabs.

  17. Sodium nitrate containing mixture for producing ceramic-glass-ceramic seal by microwave heating

    DOE Patents [OSTI]

    Blake, R.D.; Meek, T.T.

    1984-10-10

    A mixture for, and method of using such a mixture, for producing a ceramic-glass-ceramic seal by the use of microwave energy are disclosed, wherein the mixture comprises a glass sealing material, a coupling agent, and an oxidizer. The seal produced exhibits greater strength due to its different microstructure. Sodium nitrate is the most preferred oxidizer.

  18. DWPF coupled feed flowsheet material balance with batch one sludge and copper nitrate catalyst

    SciTech Connect (OSTI)

    Choi, A.S.

    1993-09-28

    The SRTC has formally transmitted a recommendation to DWPF to replace copper formate with copper nitrate as the catalyst form during precipitate hydrolysis [1]. The SRTC was subsequently requested to formally document the technical bases for the recommendation. A memorandum was issued on August 23, 1993 detailing the activities (and responsible individuals) necessary to address the impact of this change in catalyst form on process compatibility, safety, processibility environmental impact and product glass quality [2]. One of the activities identified was the preparation of a material balance in which copper nitrate is substituted for copper formate and the identification of key comparisons between this material balance and the current Batch 1 sludge -- Late Wash material balance [3].

  19. Options assessment report: Treatment of nitrate salt waste at Los Alamos National Laboratory

    SciTech Connect (OSTI)

    Robinson, Bruce Alan; Stevens, Patrice Ann

    2015-09-16

    This report documents the methodology used to select a method of treatment for the remediated nitrate salt (RNS) and unremediated nitrate salt (UNS) waste containers at Los Alamos National Laboratory (LANL). The method selected should treat the containerized waste in a manner that renders the waste safe and suitable for transport and final disposal in the Waste Isolation Pilot Plant (WIPP) repository, under specifications listed in the WIPP Waste Acceptance Criteria (DOE/CBFO, 2013). LANL recognized that the results must be thoroughly vetted with the New Mexico Environment Department (NMED) and the a modification to the LANL Hazardous Waste Facility Permit is a necessary step before implementation of this or any treatment option. Likewise, facility readiness and safety basis approvals must be received from the Department of Energy (DOE). This report presents LANL's preferred option, and the documentation of the process for reaching the recommended treatment option for RNS and UNS waste, and is presented for consideration by NMED and DOE.

  20. Aqueous nitrate waste treatment: Technology comparison, cost/benefit, and market analysis

    SciTech Connect (OSTI)

    Not Available

    1994-01-01

    The purpose of this analysis is to provide information necessary for the Department of Energy (DOE) to evaluate the practical utility of the Nitrate to Ammonia and Ceramic or Glass (NAC/NAG/NAX) process, which is under development in the Oak Ridge National Laboratory. The NAC/NACx/NAX process can convert aqueous radioactive nitrate-laden waste to a glass, ceramic, or grout solid waste form. The tasks include, but are not limited to, the following: Identify current commercial technologies to meet hazardous and radiological waste disposal requirements. The technologies may be thermal or non-thermal but must be all inclusive (i.e., must convert a radionuclide-containing nitrate waste with a pH around 12 to a stable form that can be disposed at permitted facilities); evaluate and compare DOE-sponsored vitrification, grouting, and minimum additive waste stabilization projects for life-cycle costs; compare the technologies above with respect to material costs, capital equipment costs, operating costs, and operating efficiencies. For the NAC/NAG/NAX process, assume aluminum reactant is government furnished and ammonia gas may be marketed; compare the identified technologies with respect to frequency of use within DOE for environmental management applications with appropriate rationale for use; Assess the potential size of the DOE market for the NAC/NAG/NAX process; assess and off-gas issues; and compare with international technologies, including life-cycle estimates.

  1. Effect of Phosphate, Fluoride, and Nitrate on Gibbsite Dissolution Rate and Solubility

    SciTech Connect (OSTI)

    Herting, Daniel L.

    2014-01-29

    Laboratory tests have been completed with simulated tank waste samples to investigate the effects of phosphate, fluoride, and nitrate on the dissolution rate and equilibrium solubility of gibbsite in sodium hydroxide solution at 22 and 40{degrees}C. Results are compared to relevant literature data and to computer model predictions. The presence of sodium nitrate (3 M) caused a reduction in the rate of gibbsite dissolution in NaOH, but a modest increase in the equilibrium solubility of aluminum. The increase in solubility was not as large, though, as the increase predicted by the computer model. The presence of phosphate, either as sodium phosphate or sodium fluoride phosphate, had a negligible effect on the rate of gibbsite dissolution, but caused a slight increase in aluminum solubility. The magnitude of the increased solubility, relative to the increase caused by sodium nitrate, suggests that the increase is due to ionic strength (or water activity) effects, rather than being associated with the specific ion involved. The computer model predicted that phosphate would cause a slight decrease in aluminum solubility, suggesting some Al-PO4 interaction. No evidence was found of such an interaction.

  2. Nitrogen isotopes as indicators of NOx source contributions to atmospheric nitrate deposition across the Midwestern and Northeastern United States

    SciTech Connect (OSTI)

    E.M. Elliott; C. Kendall; S.D. Wanke; D.A. Burns; E.W. Boyer; K. Harlin; D.J. Bain; T.J. Butler

    2007-11-15

    Global inputs of NOx are dominated by fossil fuel combustion from both stationary and vehicular sources and far exceed natural NOx sources. However, elucidating NOx sources to any given location remains a difficult challenge, despite the need for this information to develop sound regulatory and mitigation strategies. We present results from a regional-scale study of nitrogen isotopes (15N) in wet nitrate deposition across 33 sites in the midwestern and northeastern U.S. We demonstrate that spatial variations in 15N are strongly correlated with NOx emissions from surrounding stationary sources and additionally that 15N is more strongly correlated with surrounding stationary source NOx emissions than pH, SO{sub 4}{sup 2-}, or NO{sub 3}{sup -} concentrations. Although emission inventories indicate that vehicle emissions are the dominant NOx source in the eastern U.S., our results suggest that wet NO{sub 3}{sup -} deposition at sites in this study is strongly associated with NOx emissions from power plants. This suggests that large areas of the landscape potentially receive atmospheric NOy deposition inputs in excess of what one would infer from existing monitoring data alone. Moreover, we determined that spatial patterns in 15N values are a robust indicator of stationary NOx contributions to wet NO{sub 3}{sup -} deposition and hence a valuable complement to existing tools for assessing relationships between NO{sub 3}{sup -} deposition, regional emission inventories, and for evaluating progress toward NOx reduction goals. 44 refs., 3 figs.

  3. TREATMENT TESTS FOR EX SITU REMOVAL OF CHROMATE & NITRATE & URANIUM (VI) FROM HANFORD (100-HR-3) GROUNDWATER FINAL REPORT

    SciTech Connect (OSTI)

    BECK MA; DUNCAN JB

    1994-01-03

    This report describes batch and ion exchange column laboratory scale studies investigating ex situ methods to remove chromate (chromium [VI]), nitrate (NO{sub 3}{sup -}) and uranium (present as uranium [VI]) from contaminated Hanford site groundwaters. The technologies investigated include: chemical precipitation or coprecipitation to remove chromate and uranium; and anion exchange to remove chromate, uranium and nitrate. The technologies investigated were specified in the 100-HR-3 Groundwater Treatability Test Plan. The method suggested for future study is anion exchange.

  4. Crystal structure of a new amine nitrate: 4-dimethylaminopyridinium nitrate (C{sub 7}H{sub 11}N{sub 2})NO{sub 3}

    SciTech Connect (OSTI)

    Benhassan, D. Rekik, W.; Naïli, H.; Ślepokura, Katarzyna

    2015-12-15

    The title compound (C{sub 7}H{sub 11}N{sub 2})NO{sub 3} (I) was obtained by the slow evaporation method at room temperature. Its crystal structure consists of organic cations (C{sub 7}H{sub 11}N{sub 2}){sup +} and nitrate anions (NO{sub 3}){sup –} linked by two types of hydrogen bonds. Each monoprotonated nitrogen atom, called bifurcated, is engaged in two N–H···O hydrogen bonds with two symmetric oxygen atoms. In addition, the crystal structure stability is established by C–H···O hydrogen bonds that ensure the formation of infinite layers, parallel to (001) plane. These layers are related together through π···π interactions established between aromatic amines.

  5. Cold adaptation of the mononuclear molybdoenzyme periplasmic nitrate reductase from the Antarctic bacterium Shewanella gelidimarina

    SciTech Connect (OSTI)

    Simpson, Philippa J.L.; Codd, Rachel; School of Medical Sciences and Bosch Institute, University of New South Wales, New South Wales 2006

    2011-11-04

    Highlights: Black-Right-Pointing-Pointer Cold-adapted phenotype of NapA from the Antarctic bacterium Shewanella gelidimarina. Black-Right-Pointing-Pointer Protein homology model of NapA from S. gelidimarina and mesophilic homologue. Black-Right-Pointing-Pointer Six amino acid residues identified as lead candidates governing NapA cold adaptation. Black-Right-Pointing-Pointer Molecular-level understanding of designing cool-temperature in situ oxyanion sensors. -- Abstract: The reduction of nitrate to nitrite is catalysed in bacteria by periplasmic nitrate reductase (Nap) which describes a system of variable protein subunits encoded by the nap operon. Nitrate reduction occurs in the NapA subunit, which contains a bis-molybdopterin guanine dinucleotide (Mo-MGD) cofactor and one [4Fe-4S] iron-sulfur cluster. The activity of periplasmic nitrate reductase (Nap) isolated as native protein from the cold-adapted (psychrophilic) Antarctic bacterium Shewanella gelidimarina (Nap{sub Sgel}) and middle-temperature adapted (mesophilic) Shewanella putrefaciens (Nap{sub Sput}) was examined at varied temperature. Irreversible deactivation of Nap{sub Sgel} and Nap{sub Sput} occurred at 54.5 and 65 Degree-Sign C, respectively. When Nap{sub Sgel} was preincubated at 21-70 Degree-Sign C for 30 min, the room-temperature nitrate reductase activity was maximal and invariant between 21 and 54 Degree-Sign C, which suggested that Nap{sub Sgel} was poised for optimal catalysis at modest temperatures and, unlike Nap{sub Sput}, did not benefit from thermally-induced refolding. At 20 Degree-Sign C, Nap{sub Sgel} reduced selenate at 16% of the rate of nitrate reduction. Nap{sub Sput} did not reduce selenate. Sequence alignment showed 46 amino acid residue substitutions in Nap{sub Sgel} that were conserved in NapA from mesophilic Shewanella, Rhodobacter and Escherichia species and could be associated with the Nap{sub Sgel} cold-adapted phenotype. Protein homology modeling of Nap{sub Sgel} using a mesophilic template with 66% amino acid identity showed the majority of substitutions occurred at the protein surface distal to the Mo-MGD cofactor. Two mesophilic {r_reversible} psychrophilic substitutions (Asn {r_reversible} His, Val {r_reversible} Trp) occurred in a region close to the surface of the NapA substrate funnel resulting in potential interdomain {pi}-{pi} and/or cation-{pi} interactions. Three mesophilic {r_reversible} psychrophilic substitutions occurred within 4.5 A of the Mo-MGD cofactor (Phe {r_reversible} Met, Ala {r_reversible} Ser, Ser {r_reversible} Thr) resulting in local regions that varied in hydrophobicity and hydrogen bonding networks. These results contribute to the understanding of thermal protein adaptation in a redox-active mononuclear molybdenum enzyme and have implications in optimizing the design of low-temperature environmental biosensors.

  6. Comparison of FTIR and Particle Mass Spectrometry for the Measurement of Paticulate Organic Nitrates

    SciTech Connect (OSTI)

    Bruns, Emily; Perraud, Veronique; Zelenyuk, Alla; Ezell, Michael J.; Johnson, Stanley N.; Yu, Yong; Imre, D.; Finlayson-Pitts, Barbara J.; Alexander, M. L.

    2010-02-01

    While multifunctional organic nitrates are formed during the atmospheric oxidation of volatile organic compounds, relatively little is known about their signatures in particle mass spectrometers. High resolution time-of-flight aerosol mass spectrometry (HR-ToF-AMS) was applied to NH4NO3, NaNO3 and isosorbide 5-mononitrate (IMN) particles, and to secondary organic aerosol (SOA) from NO3 radical reactions at 22 C and 1 atm in air with and pinene, 3-carene, limonene and isoprene. For comparison, single particle laser ablation mass spectra (SPLAT II) were also obtained for IMN and SOA from the pinene reaction. The mass spectra of all particles exhibit significant intensity at m/z 30, and for the SOA, weak peaks corresponding to various organic fragments containing nitrogen [CxHyNzOa]+ were identified using HR-ToF-AMS. The NO+/NO2+ ratios from HR-ToF-AMS were 10-15 for IMN and the SOA from the and pinene, 3-carene and limonene reactions, ~5 for the isoprene reaction, 2.4 for NH4NO3 and 80 for NaNO3. The N/H ratios from HR-ToF-AMS for the SOA were smaller by a factor of 2 to 4 than the -ONO2/C-H ratios measured using FTIR on particles impacted on ZnSe windows. While the NO+/NO2+ ratio may provide a generic indication of organic nitrates under some conditions, specific identification of particulate organic nitrates awaits further development of particle mass spectrometry techniques.

  7. Molten Nitrate Salt Development for Thermal Energy Storage in Parabolic Trough Solar Power Systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ES2008-54174 This manuscript has been authored by Sandia Corporation under Contact No. DE-AC04-94AL85000 with the U.S. Dept. of Energy. The United States Government retains and the publisher, by accepting this article for publication, acknowledges that the United States Government retains a non-exclusive, paid-up, irrevocable, world-wide license to publish or reproduce the published form of this manuscript, or allow others to do so, for United States Government purposes. MOLTEN NITRATE SALT

  8. Process for converting sodium nitrate-containing, caustic liquid radioactive wastes to solid insoluble products

    DOE Patents [OSTI]

    Barney, Gary S.; Brownell, Lloyd E.

    1977-01-01

    A method for converting sodium nitrate-containing, caustic, radioactive wastes to a solid, relatively insoluble, thermally stable form is provided and comprises the steps of reacting powdered aluminum silicate clay, e.g., kaolin, bentonite, dickite, halloysite, pyrophyllite, etc., with the sodium nitrate-containing radioactive wastes which have a caustic concentration of about 3 to 7 M at a temperature of 30.degree. C to 100.degree. C to thereby entrap the dissolved radioactive salts in the aluminosilicate matrix. In one embodiment the sodium nitrate-containing, caustic, radioactive liquid waste, such as neutralized Purex-type waste, or salts or oxide produced by evaporation or calcination of these liquid wastes (e.g., anhydrous salt cake) is converted at a temperature within the range of 30.degree. C to 100.degree. C to the solid mineral form-cancrinite having an approximate chemical formula 2(NaAlSiO.sub.4) .sup.. xSalt.sup.. y H.sub.2 O with x = 0.52 and y = 0.68 when the entrapped salt is NaNO.sub.3. In another embodiment the sodium nitrate-containing, caustic, radioactive liquid is reacted with the powdered aluminum silicate clay at a temperature within the range of 30.degree. C to 100.degree. C, the resulting reaction product is air dried eitheras loose powder or molded shapes (e.g., bricks) and then fired at a temperature of at least 600.degree. C to form the solid mineral form-nepheline which has the approximate chemical formula of NaAlSiO.sub.4. The leach rate of the entrapped radioactive salts with distilled water is reduced essentially to that of the aluminosilicate lattice which is very low, e.g., in the range of 10.sup.-.sup.2 to 10.sup.-.sup.4 g/cm.sup.2 -- day for cancrinite and 10.sup.-.sup.3 to 10.sup.-.sup.5 g/cm.sup.2 -- day for nepheline.

  9. Conversion of actinide and RE oxides into nitrates and their recovery into fluids

    SciTech Connect (OSTI)

    Bondin, V.V.; Bychkov, S.I.; Efremov, I.G.; Revenko, Y.A.; Babain, V.A.; Murzin, A.A.; Romanovsky, V.N; Fedorov, Y.S.; Shadrin, A.Y.; Ryabkova, N.V.; Li, E.N.

    2007-07-01

    The conditions for uranium oxides completely convert into uranyl nitrate hexahydrate in nitrogen tetra-oxide media (75 deg. C, 0,5-3,0 MPa, [UO{sub x}]:[H{sub 2}O]:[NO{sub 2}]=1:8:6) were found out. The conversion of Pu contained simulator of oxide spent nuclear fuel of thermal reactors was successfully demonstrated. The possibility of uranium recovery up to 95% from TR SNF without plutonium separation from FP is practically showed, what corresponds with Non-proliferation Treaty. (authors)

  10. Investigations on spectral and dielectric properties of semi-organic single crystal – morpholinium nitrate

    SciTech Connect (OSTI)

    Arul, H.; Babu, D. Rajan Vizhi, R. Ezhil

    2015-06-24

    Semi organic nonlinear optical crystal Morpholinium nitrate (MN) was synthesized and subsequently grown from the solution by slow evaporation method. The sample has been subjected to powder X-ray diffraction to identify the crystalline nature and the prominent peaks were indexed. The crystal belongs to the monoclinic system with a space group P2{sub 1}/C. Carbon NMR analysis confirms the presence of carbon in the structure of the title compound. Dielectric studies have been carried out on the grown crystal as a function of frequencies at different temperatures. Dielectric constant, dielectric loss and AC conductivity were also calculated.

  11. Speciation model selection by Monte Carlo analysis of optical absorption spectra: Plutonium(IV) nitrate complexes

    SciTech Connect (OSTI)

    Berg, John M.; Veirs, D. Kirk; Vaughn, Randolph B.; Cisneros, Michael R.; Smith, Coleman A.

    2000-06-01

    Standard modeling approaches can produce the most likely values of the formation constants of metal-ligand complexes if a particular set of species containing the metal ion is known or assumed to exist in solution equilibrium with complexing ligands. Identifying the most likely set of species when more than one set is plausible is a more difficult problem to address quantitatively. A Monte Carlo method of data analysis is described that measures the relative abilities of different speciation models to fit optical spectra of open-shell actinide ions. The best model(s) can be identified from among a larger group of models initially judged to be plausible. The method is demonstrated by analyzing the absorption spectra of aqueous Pu(IV) titrated with nitrate ion at constant 2 molal ionic strength in aqueous perchloric acid. The best speciation model supported by the data is shown to include three Pu(IV) species with nitrate coordination numbers 0, 1, and 2. Formation constants are {beta}{sub 1}=3.2{+-}0.5 and {beta}{sub 2}=11.2{+-}1.2, where the uncertainties are 95% confidence limits estimated by propagating raw data uncertainties using Monte Carlo methods. Principal component analysis independently indicates three Pu(IV) complexes in equilibrium. (c) 2000 Society for Applied Spectroscopy.

  12. Options Assessment Report: Treatment of Nitrate Salt Waste at Los Alamos National Laboratory

    SciTech Connect (OSTI)

    Robinson, Bruce Alan; Stevens, Patrice Ann

    2015-12-17

    This report documents the methodology used to select a method of treatment for the remediated nitrate salt (RNS) and unremediated nitrate salt (UNS) waste containers at Los Alamos National Laboratory (LANL). The method selected should treat the containerized waste in a manner that renders the waste safe and suitable for transport and final disposal in the Waste Isolation Pilot Plant (WIPP) repository, under specifications listed in the WIPP Waste Acceptance Criteria (DOE/CBFO, 2013). LANL recognizes that the results must be thoroughly vetted with the New Mexico Environment Department (NMED) and that a modification to the LANL Hazardous Waste Facility Permit is a necessary step before implementation of this or any treatment option. Likewise, facility readiness and safety basis approvals must be received from the Department of Energy (DOE). This report presents LANL’s preferred option, and the documentation of the process for reaching the recommended treatment option for RNS and UNS waste, and is presented for consideration by NMED and DOE.

  13. Method and apparatus for nitrogen oxide determination

    DOE Patents [OSTI]

    Hohorst, Frederick A.

    1990-01-01

    Method and apparatus for determining nitrogen oxide content in a high temperature process gas, which involves withdrawing a sample portion of a high temperature gas containing nitrogen oxide from a source to be analyzed. The sample portion is passed through a restrictive flow conduit, which may be a capillary or a restriction orifice. The restrictive flow conduit is heated to a temperature sufficient to maintain the flowing sample portion at an elevated temperature at least as great as the temperature of the high temperature gas source, to thereby provide that deposition of ammonium nitrate within the restrictive flow conduit cannot occur. The sample portion is then drawn into an aspirator device. A heated motive gas is passed to the aspirator device at a temperature at least as great as the temperature of the high temperature gas source. The motive gas is passed through the nozzle of the aspirator device under conditions sufficient to aspirate the heated sample portion through the restrictive flow conduit and produce a mixture of the sample portion in the motive gas at a dilution of the sample portion sufficient to provide that deposition of ammonium nitrate from the mixture cannot occur at reduced temperature. A portion of the cooled dilute mixture is then passed to analytical means capable of detecting nitric oxide.

  14. A study of the organic emission from a turbocharged diesel engine running on 12 percent hexyl nitrate dissolved in ethanol

    SciTech Connect (OSTI)

    Walde, N.; Westerholm, R.; Persson, K.-A.

    1984-01-01

    A highly rated turbocharged diesel engine adapted for an alternative fuel based on ethanol and hexyl nitrate has been investigated with respect to the emission of organic compounds in the exhausts. The adaption involves: ignition nozzles with larger holes, a change of injection timing and more fuel injected per stroke. Emissions were measured at four different driving modes ie, 1, 8, 10 and 12 respectively, in the California Cycle. The exhaust composition are different compared to conventional diesel emissions. The main part of the organic pollutants consists of unburned ethanol and hexyl nitrate, acetaldehyde being the most abundant aldehyde.

  15. Structural Aspects of Hydrogen Bonding with Nitrate and Sulfate: Design Criteria for Polyalcohol Hosts

    SciTech Connect (OSTI)

    Hay, Benjamin P.; Dixon, David A.; Lumetta, Gregg J.; Vargas, Rubicelia; Garza, Jorge

    2004-01-01

    Organic hosts for oxyanion complexation can be constructed by combining two or more hydrogen bonding sites. The deliberate design of architectures for such hosts requires knowledge of the optimal geometry for the hydrogen bonds formed between the host and the guest. Important structural parameters include the O--H distance, the O--H-D angle, the X-O--H angle, and the X-O--H-D dihedral angle (H-D=hydrogen bond donor, X=any atom). This information can be obtained through the analysis of hydrogen bonding observed in crystal structures and electronic structure calculations on simple gas-phase complexes. In this chapter, we present an analysis of hydrogen bonding structural parameters for alcohol hydrogen donors and the oxygen atom acceptors in nitrate and sulfate.

  16. Thermal behavior of glassy phase stabilized ammonium nitrate (PSAN) thin films

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yeager, J. D.; Chellappa, R.; Singh, S.; Majewski, J.

    2015-06-01

    Ammonium nitrate (AN) is a high interest material because of its wide usage in propellants and explosives but can be difficult to handle from a formulation standpoint. It is soluble in many common solvents and has complex phase behavior. Here, we formulate phase stabilized AN (PSAN) films in a polymer matrix and characterize thermal and phase behavior using neutron reflectometry and ellipsometry. Our PSAN films are generally stable up to 160 °C, though we observe small material loss between 60 and 100 °C, which we attribute to solvent interactions with the PSAN. Crystallization of AN from supersaturated polymer is mostmore » common at thicker regions of the film, suggesting a critical nucleation thickness for the AN which can be avoided by making very thin films.« less

  17. Thermal behavior of glassy phase stabilized ammonium nitrate (PSAN) thin films

    SciTech Connect (OSTI)

    Yeager, J. D.; Chellappa, R.; Singh, S.; Majewski, J.

    2015-06-01

    Ammonium nitrate (AN) is a high interest material because of its wide usage in propellants and explosives but can be difficult to handle from a formulation standpoint. It is soluble in many common solvents and has complex phase behavior. Here, we formulate phase stabilized AN (PSAN) films in a polymer matrix and characterize thermal and phase behavior using neutron reflectometry and ellipsometry. Our PSAN films are generally stable up to 160 °C, though we observe small material loss between 60 and 100 °C, which we attribute to solvent interactions with the PSAN. Crystallization of AN from supersaturated polymer is most common at thicker regions of the film, suggesting a critical nucleation thickness for the AN which can be avoided by making very thin films.

  18. THE SENSITIVITY OF CARBON STEELS' SUSCEPTIBILITY TO LOCALIZED CORROSION TO THE PH OF NITRATE BASED NUCLEAR WASTES

    SciTech Connect (OSTI)

    BOOMER KD

    2010-01-14

    The Hanford tank reservation contains approximately 50 million gallons of liquid legacy radioactive waste from cold war weapons production, which is stored in 177 underground storage tanks. The tanks will be in use until waste processing operations are completed. The wastes tend to be high pH (over 10) and nitrate based. Under these alkaline conditions carbon steels tend to be passive and undergo relatively slow uniform corrosion. However, the presence of nitrate and other aggressive species, can lead to pitting and stress corrosion cracking. This work is a continuation of previous work that investigated the propensity of steels to suffer pitting and stress corrosion cracking in various waste simulants. The focus of this work is an investigation of the sensitivity of the steels' pitting and stress corrosion cracking susceptibility tosimulant pH. Previous work demonstrated that wastes that are high in aggressive nitrate and low in inhibitory nitrite are susceptible to localized corrosion. However, the previous work involved wastes with pH 12 or higher. The current work involves wastes with lower pH of 10 or 11. It is expected that at these lower pHs that a higher nitrite-to-nitrate ratio will be necessary to ensure tank integrity. This experimental work involved both electrochemical testing, and slow strain rate testing at either the free corrosion potential or under anodic polarization. The results of the current work will be discussed, and compared to work previously presented.

  19. Enhanced liquid-liquid anion exchange using macrocyclic anion receptors: effect of receptor structure on sulphate-nitrate exchange selectivity

    SciTech Connect (OSTI)

    Moyer, Bruce A; Sloop Jr, Frederick {Fred} V; Fowler, Christopher J; Haverlock, Tamara; Kang, Hyun Ah; Delmau, Laetitia Helene; Bau, Diadra; Hossain, Alamgir; Bowman-James, Kristin; Shriver, James A.; Gross, Mr. Dustin E.; Bill, Nathan; Marquez, Manuel; Lynch, Vincent M.; Sessler, Jonathan L.

    2010-01-01

    When certain macrocyclic anion receptors are added to a chloroform solution of the nitrate form of a lipophilic quaternary ammonium salt (methyltri-C8,10-ammonium nitrate, Aliquat 336N), the extraction of sulphate from an aqueous sodium nitrate solution via exchange with the organic-phase nitrate is significantly enhanced. Eight macrocycles were surveyed, including two derivatives of a tetraamide macrocycle, five derivatives of calix[4]pyrrole and -decafluorocalix[5]pyrrole. Under the hypothesis that the enhancement originates from sulphate binding by the anion receptors in the chloroform phase, it was possible to obtain reasonable fits to the sulphate distribution survey data based on the formation of 1:1 and 2:1 receptor:sulphate complexes in the chloroform phase. Apparent 1:1 sulphate-binding constants obtained from the model in this system fell in the range . Comparison of the results for the various anion receptors included in this study reveals that sulphate binding is sensitive to the nature of the substituents on the parent macrocycle scaffolds in a way that does not follow straightforwardly from simple chemical expectations, such as electron-withdrawing effects on hydrogen-bond donor strength.

  20. Draft Genome Sequence for Microbacterium laevaniformans Strain OR221, a Bacterium Tolerant to Metals, Nitrate, and Low pH

    SciTech Connect (OSTI)

    Brown, Steven D; Palumbo, Anthony Vito; Panikov, Nikolai; Ariyawansa, Thilini; Klingeman, Dawn Marie; Johnson, Courtney M; Land, Miriam L; Utturkar, Sagar M; Epstein, Slava

    2012-01-01

    Microbacterium laevaniformans strain OR221 was isolated from subsurface sediments obtained from the Field Research Center (FRC) in Oak Ridge, TN. It was characterized as a bacterium tolerant to heavy metals such as uranium, nickel, cobalt, cadmium, as well as nitrate and low pH. We present its draft genome sequence.

  1. Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage- FY12 Q4

    Broader source: Energy.gov [DOE]

    This document summarizes the progress of this General Atomics project, funded by SunShot, for the fourth quarter of fiscal year 2012.

  2. Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage- FY13 Q1

    Broader source: Energy.gov [DOE]

    This document summarizes the progress of this General Atomics project, funded by SunShot, for the first quarter of fiscal year 2013.

  3. Baseload CSP Generation Integrated with Sulfur-Based Thermochemical Heat Storage- FY13 Q2

    Broader source: Energy.gov [DOE]

    This document summarizes the progress of this General Atomics project, funded by SunShot, for the second quarter of fiscal year 2013.

  4. Development of an Advanced, Low-Cost parabolic Trough Collector for Baseload Operation

    Broader source: Energy.gov [DOE]

    This presentation was delivered at the SunShot Concentrating Solar Power (CSP) Program Review 2013, held April 23–25, 2013 near Phoenix, Arizona.

  5. Life cycle assessment of base-load heat sources for district heating system options

    SciTech Connect (OSTI)

    Ghafghazi, Saeed; Sowlati, T.; Sokhansanj, Shahabaddine; Melin, Staffan

    2011-03-01

    Purpose There has been an increased interest in utilizing renewable energy sources in district heating systems. District heating systems are centralized systems that provide heat for residential and commercial buildings in a community. While various renewable and conventional energy sources can be used in such systems, many stakeholders are interested in choosing the feasible option with the least environmental impacts. This paper evaluates and compares environmental burdens of alternative energy source options for the base load of a district heating center in Vancouver, British Columbia (BC) using the life cycle assessment method. The considered energy sources include natural gas, wood pellet, sewer heat, and ground heat. Methods The life cycle stages considered in the LCA model cover all stages from fuel production, fuel transmission/transportation, construction, operation, and finally demolition of the district heating system. The impact categories were analyzed based on the IMPACT 2002+ method. Results and discussion On a life-cycle basis, the global warming effect of renewable energy options were at least 200 kgeqCO2 less than that of the natural gas option per MWh of heat produced by the base load system. It was concluded that less than 25% of the upstream global warming impact associated with the wood pellet energy source option was due to transportation activities and about 50% of that was resulted from wood pellet production processes. In comparison with other energy options, the wood pellets option has higher impacts on respiratory of inorganics, terrestrial ecotoxicity, acidification, and nutrification categories. Among renewable options, the global warming impact of heat pump options in the studied case in Vancouver, BC, were lower than the wood pellet option due to BC's low carbon electricity generation profile. Ozone layer depletion and mineral extraction were the highest for the heat pump options due to extensive construction required for these options. Conclusions Natural gas utilization as the primary heat source for district heat production implies environmental complications beyond just the global warming impacts. Diffusing renewable energy sources for generating the base load district heat would reduce human toxicity, ecosystem quality degradation, global warming, and resource depletion compared to the case of natural gas. Reducing fossil fuel dependency in various stages of wood pellet production can remarkably reduce the upstream global warming impact of using wood pellets for district heat generation.

  6. Cost-Effective Integration of Efficient Low-Lift Baseload Cooling Equipment: FY08 Final Report

    SciTech Connect (OSTI)

    Katipamula, Srinivas; Armstrong, P. R.; Wang, Weimin; Fernandez, Nicholas; Cho, Heejin; Goetzler, W.; Burgos, J.; Radhakrishnan, R.; Ahlfeldt, C.

    2010-01-31

    Documentation of a study to investigate one heating, ventilation and air conditioning (HVAC) system option, low-lift cooling, which offers potentially exemplary HVAC energy performance relative to American Society of Heating, Refrigeration and Air Conditioning Engineers (ASHRAE) Standard 90.1-2004.

  7. The combination of once-through Fischer-Tropsch with baseload IGCC Technology

    SciTech Connect (OSTI)

    Tam, S.S.; Pollock, D.C.; Fox, J.M. III

    1993-12-31

    Integrated Gasification Combined Cycle (IGCC) is an emerging technology for electric power generation from coal with minimum impact on the environment. Power is generated efficiently by a combination of syngas-driven gas turbines and steam turbines. Studies have shown that the capital cost of an IGCC plant is relatively high when compared to a natural-gas-fired combined cycle plant while its variable operating costs are comparatively low because coal is a lower priced fuel. Favorable IGCC economics thus require high capacity utilization as well as the high availability and reliability normally required for utility industry power plans. A base load plant will meet these criteria if adequate attention is paid to gasifier reliability. In a study sponsored by Florida Power and Light Company (FPL) and the Electric Power Research Institute (EPRI), Bechtel investigated the addition of an operating spare gasification train with methanol co-production from the syngas in order to improve the reliability of a base load electric power plant. As shown, the net result was an improved plant availability along with the co-production of a valuable by-product which paid for the addition of the spare gasifier. Co-production of hydrocarbons via Fischer-Tropsch (F-T) technology is a logical alternative to methanol co-production because it can offer the similar synergistic effects on the power plant similar to the methanol co-production scheme. Bechtel is currently carrying out a Baseline Design/Economics Study for Department of Energy, Pittsburgh Energy Technology Center (DOE/PETC) on indirect coal liquefaction using advanced F-T technology.

  8. Using Encapsulated Phase Change Material for Thermal Energy Storage for Baseload CSP

    Broader source: Energy.gov [DOE]

    This presentation was delivered at the SunShot Concentrating Solar Power (CSP) Program Review 2013, held April 23–25, 2013 near Phoenix, Arizona.

  9. Rapid formation of the Bi{sub 2{minus}x}Pb{sub x}Sr{sub 2}Ca{sub 2}Cu{sub 3}O{sub y} high {Tc}-phase, using spray-dried nitrate precursor powders

    SciTech Connect (OSTI)

    Van Driessche, I.; Mouton, R.; Hoste, S.

    1996-08-01

    This study describes the use of spray-dried nitrate precursor powders in the synthesis of Bi-2223 high {Tc}-superconductors. The decomposition of the precursor powder is studied using TGA/DTA, XRD, IR, and nitrogen analyses. The particle size is determined using SEM. The low decomposition temperature of the nitrates ({approximately}600 C) and the small particle size of the spray dried powder ({approximately}3{center_dot}10{sup {minus}6} m), resulting in a lowering of the calcination temperature and a shortening of the sinter time, enabled the authors to synthesize a > 96% pure Bi-2223 phase (from XRD peak intensities) after a thermal process of 5h at 650 C and 60 h at 855 C.

  10. Polyethylene encapsulatin of nitrate salt wastes: Waste form stability, process scale-up, and economics

    SciTech Connect (OSTI)

    Kalb, P.D.; Heiser, J.H. III; Colombo, P.

    1991-07-01

    A polyethylene encapsulation system for treatment of low-level radioactive, hazardous, and mixed wastes has been developed at Brookhaven National Laboratory. Polyethylene has several advantages compared with conventional solidification/stabilization materials such as hydraulic cements. Waste can be encapsulated with greater efficiency and with better waste form performance than is possible with hydraulic cement. The properties of polyethylene relevant to its long-term durability in storage and disposal environments are reviewed. Response to specific potential failure mechanisms including biodegradation, radiation, chemical attack, flammability, environmental stress cracking, and photodegradation are examined. These data are supported by results from extensive waste form performance testing including compressive yield strength, water immersion, thermal cycling, leachability of radioactive and hazardous species, irradiation, biodegradation, and flammability. The bench-scale process has been successfully tested for application with a number of specific problem'' waste streams. Quality assurance and performance testing of the resulting waste form confirmed scale-up feasibility. Use of this system at Rocky Flats Plant can result in over 70% fewer drums processed and shipped for disposal, compared with optimal cement formulations. Based on the current Rocky Flats production of nitrate salt per year, polyethylene encapsulation can yield an estimated annual savings between $1.5 million and $2.7 million, compared with conventional hydraulic cement systems. 72 refs., 23 figs., 16 tabs.

  11. Combined uranous nitrate production consisting of undivided electrolytic cell and divided electrolytic cell (Electrolysis ? Electrolytic cell)

    SciTech Connect (OSTI)

    Yuan, Zhongwei; Yan, Taihong; Zheng, Weifang; Li, Xiaodong; Yang, Hui; Xian, Liang

    2013-07-01

    The electrochemical reduction of uranyl nitrate is a green, mild way to make uranous ions. Undivided electrolyzers whose maintenance is less but their conversion ratio and current efficiency are low, have been chosen. However, at the beginning of undivided electrolysis, high current efficiency can also be maintained. Divided electrolyzers' conversion ratio and current efficiency is much higher because the re-oxidation of uranous on anode is avoided, but their maintenance costs are more, because in radioactive environment the membrane has to be changed after several operations. In this paper, a combined method of uranous production is proposed which consists of 2 stages: undivided electrolysis (early stage) and divided electrolysis (late stage) to benefit from the advantages of both electrolysis modes. The performance of the combined method was tested. The results show that in combined mode, after 200 min long electrolysis (80 min undivided electrolysis and 120 min divided electrolysis), U(IV) yield can achieve 92.3% (500 ml feed, U 199 g/l, 72 cm{sup 2} cathode, 120 mA/cm{sup 2}). Compared with divided mode, about 1/3 working time in divided electrolyzer is reduced to achieve the same U(IV) yield. If 120 min long undivided electrolysis was taken, more than 1/2 working time can be reduced in divided electrolyzer, which means that about half of the maintenance cost can also be reduced. (authors)

  12. Materials corrosion of high temperature alloys immersed in 600C binary nitrate salt.

    SciTech Connect (OSTI)

    Kruizenga, Alan Michael; Gill, David Dennis; LaFord, Marianne Elizabeth

    2013-03-01

    Thirteen high temperature alloys were immersion tested in a 60/40 binary nitrate salt. Samples were interval tested up to 3000 hours at 600%C2%B0C with air as the ullage gas. Chemical analysis of the molten salt indicated lower nitrite concentrations present in the salt, as predicted by the equilibrium equation. Corrosion rates were generally low for all alloys. Corrosion products were identified using x-ray diffraction and electron microprobe analysis. Fe-Cr based alloys tended to form mixtures of sodium and iron oxides, while Fe-Ni/Cr alloys had similar corrosion products plus oxides of nickel and chromium. Nickel based alloys primarily formed NiO, with chromium oxides near the oxide/base alloy interface. In625 exhibited similar corrosion performance in relation to previous tests, lending confidence in comparisons between past and present experiments. HA230 exhibited internal oxidation that consisted of a nickel/chromium oxide. Alloys with significant aluminum alloying tended to exhibit superior performance, due formation of a thin alumina layer. Soluble corrosion products of chromium, molybdenum, and tungsten were also formed and are thought to be a significant factor in alloy performance.

  13. Description of Rhodanobacter denitrificans sp. nov., isolated from nitrate-rich zones of a contaminated aquifer

    SciTech Connect (OSTI)

    Prakash, Om; Green, Stefan; Jasrotia, Puja; Overholt, Will; Canion, Andy; Watson, David B; Brooks, Scott C; Kostka,

    2012-01-01

    Bacterial strains 2APBS1T and 116-2 were isolated from the subsurface of a nuclear legacy waste site where sediments are co-contaminated with large amounts of acidity, nitrate, metal radionuclides and other heavy metals. A combination of physiological and genetic assays indicated that these strains represent the first members of the Rhodanobacter genus shown to be capable of complete denitrification. Cells of strain 2APBS1T and 116-2 were Gram negative, non-spore-forming, rods, 3-5 micro;m long and 0.25-0.5 m in diameter. The isolates were facultative anaerobes, and had temperature and pH optima for growth at 30 C and pH 6.5, respectively, and could tolerate up to 2.0 % NaCl, though growth improved in its absence. Strains 2APBS1T and 116-2 contained fatty acid profiles and 100 % Q-8 ubiquinone, that are characteristic features of the genus Rhodanobacter. Although strains 2APBS1T and 116-2 share high SSU rRNA gene sequence similarity to R. thiooxydans (>99%), DNA-DNA hybridization values were substantially below the 70% threshold used to designate novel species. Thus, based on genotypic, phylogenetic, chemotaxonomic and physiological differences, strains 2APBS1T and 116-2 are considered to represent a novel species of the genus Rhodanobacter, for which the name Rhodanobacter denitrificans sp. nov is proposed. The type strain is 2APBS1T (=DSM 23569T =JCM 17641T). Strain 116-2 (=DSM 24678 = JCM 17642) is a reference strain.

  14. Isotopic identification of soil and permafrost nitrate sources in an Arctic tundra ecosystem

    SciTech Connect (OSTI)

    Heikoop, Jeffrey M.; Throckmorton, Heather M.; Newman, Brent D.; Perkins, George B.; Iversen, Colleen M.; Chowdhury, Taniya Roy; Romanovsky, Vladimir E.; Graham, David E.; Norby, Richard J.; Wilson, Cathy J.; Wullschleger, Stan D.

    2015-06-08

    The nitrate (NO₃⁻) dual isotope approach was applied to snowmelt, tundra active layer pore waters, and underlying permafrost in Barrow, Alaska, USA, to distinguish between NO₃⁻ derived from at NO₃⁻ signal with δ¹⁵N averaging –4.8 ± 1.0‰ (standard error of the mean) and δ¹⁸O averaging 70.2 ±1.7‰. In active layer pore waters, NO₃⁻ primarily occurred at concentrations suitable for isotopic analysis in the relatively dry and oxic centers of high-centered polygons. The average δ¹⁵N and δ¹⁸O of NO₃⁻ from high-centered polygons were 0.5 ± 1.1‰ and –4.1 ± 0.6‰, respectively. When compared to the δ¹⁵N of reduced nitrogen (N) sources, and the δ¹⁸O of soil pore waters, it was evident that NO₃⁻ in high-centered polygons was primarily from microbial nitrification. Permafrost NO₃⁻ had δ¹⁵N ranging from approximately –6‰ to 10‰, similar to atmospheric and microbial NO₃⁻, and highly variable δ¹⁸O ranging from approximately –2‰ to 38‰. Permafrost ice wedges contained a significant atmospheric component of NO₃⁻, while permafrost textural ice contained a greater proportion of microbially derived NO₃⁻. Large-scale permafrost thaw in this environment would release NO₃⁻ with a δ¹⁸O signature intermediate to that of atmospheric and microbial NO₃. Consequently, while atmospheric and microbial sources can be readily distinguished by the NO₃⁻ dual isotope technique in tundra environments, attribution of NO₃⁻ from thawing permafrost will not be straightforward. The NO₃⁻ isotopic signature, however, appears useful in identifying NO₃⁻ sources in extant permafrost ice.

  15. Isotopic identification of soil and permafrost nitrate sources in an Arctic tundra ecosystem

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Heikoop, Jeffrey M.; Throckmorton, Heather M.; Newman, Brent D.; Perkins, George B.; Iversen, Colleen M.; Chowdhury, Taniya Roy; Romanovsky, Vladimir E.; Graham, David E.; Norby, Richard J.; Wilson, Cathy J.; et al

    2015-06-08

    The nitrate (NO₃⁻) dual isotope approach was applied to snowmelt, tundra active layer pore waters, and underlying permafrost in Barrow, Alaska, USA, to distinguish between NO₃⁻ derived from at NO₃⁻ signal with δ¹⁵N averaging –4.8 ± 1.0‰ (standard error of the mean) and δ¹⁸O averaging 70.2 ±1.7‰. In active layer pore waters, NO₃⁻ primarily occurred at concentrations suitable for isotopic analysis in the relatively dry and oxic centers of high-centered polygons. The average δ¹⁵N and δ¹⁸O of NO₃⁻ from high-centered polygons were 0.5 ± 1.1‰ and –4.1 ± 0.6‰, respectively. When compared to the δ¹⁵N of reduced nitrogen (N) sources,more » and the δ¹⁸O of soil pore waters, it was evident that NO₃⁻ in high-centered polygons was primarily from microbial nitrification. Permafrost NO₃⁻ had δ¹⁵N ranging from approximately –6‰ to 10‰, similar to atmospheric and microbial NO₃⁻, and highly variable δ¹⁸O ranging from approximately –2‰ to 38‰. Permafrost ice wedges contained a significant atmospheric component of NO₃⁻, while permafrost textural ice contained a greater proportion of microbially derived NO₃⁻. Large-scale permafrost thaw in this environment would release NO₃⁻ with a δ¹⁸O signature intermediate to that of atmospheric and microbial NO₃. Consequently, while atmospheric and microbial sources can be readily distinguished by the NO₃⁻ dual isotope technique in tundra environments, attribution of NO₃⁻ from thawing permafrost will not be straightforward. The NO₃⁻ isotopic signature, however, appears useful in identifying NO₃⁻ sources in extant permafrost ice.« less

  16. Criticality experiments with planar arrays of three-liter bottles containing plutonium nitrate solution

    SciTech Connect (OSTI)

    Durst, B.M.; Clayton, E.D.; Smith, J.H.

    1985-01-01

    The objective of these experiments was to provide benchmark data to validate calculational codes used in critically safety assessments of plant configurations. Arrays containing up to as many as sixteen three-liter bottles filled with plutonium nitrate were used in the experiments. A split-table device was used in the final assembly of the arrays. Ths planar arrays were reflected with close fitting plexiglas on each side and on the bottom but not the top surface. The experiments addressed a number of factors effecting criticality: the critical air gap between bottles in an array of fixed number of bottles, the number of bottles required for criticality if the bottles were touching, and the effect on critical array spacing and critical bottle number due to the insertion of an hydrogeneous substance into the air gap between bottles. Each bottle contained about 2.4l of Pu(NO{sub 3}){sub 4} solution at a Pu concentration of 105g Pu/l, with the {sup 240}Pu content being 2.9 wt% at a free acid molarity H{sup +} of 5.1. After the initial series of experiments were performed with bottles separated by air gaps, plexiglas shells of varying thicknesses were placed around each bottle to investigate how moderation between bottles affects both the number of bottles required for criticality and the critical spacing between each bottle. The minimum of bottles required for criticality was found to be 10.9 bottles, occurring for a square array with bottles in contact. As the bottles were spaced apart, the critical number increased. For sixteen bottles in a square array, the critical separation between surfaces in both x and y direction was 0.96 cm. The addition of plexiglas around each bottle decreased the critical bottle number, compared to those separated in air, but the critical bottle number, even with interstitial plastic in place was always greater than 10.9 bottles. The most reactive configuration was a tightly packed array of bottles with no intervening material.

  17. Fluidized Bed Steam Reforming (FBSR) Mineralization for High Organic and Nitrate Waste Streams for the Global Nuclear Energy Partnership (GNEP)

    SciTech Connect (OSTI)

    Jantzen, C.M.; Williams, M.R. [Savannah River National Laboratory, Aiken, SC (United States)

    2008-07-01

    Waste streams that may be generated by the Global Nuclear Energy Partnership (GNEP) Advanced Energy Initiative may contain significant quantities of organics (0-53 wt%) and/or nitrates (0-56 wt%). Decomposition of high nitrate streams requires reducing conditions, e.g. organic additives such as sugar or coal, to reduce the NOx in the off-gas to N{sub 2} to meet the Clean Air Act (CAA) standards during processing. Thus, organics will be present during waste form stabilization regardless of which GNEP processes are chosen, e.g. organics in the feed or organics for nitrate destruction. High organic containing wastes cannot be stabilized with the existing HLW Best Developed Available Technology (BDAT) which is HLW vitrification (HLVIT) unless the organics are removed by preprocessing. Alternative waste stabilization processes such as Fluidized Bed Steam Reforming (FBSR) operate at moderate temperatures (650-750 deg. C) compared to vitrification (1150-1300 deg. C). FBSR converts organics to CAA compliant gases, creates no secondary liquid waste streams, and creates a stable mineral waste form that is as durable as glass. For application to the high Cs-137 and Sr-90 containing GNEP waste streams a single phase mineralized Cs-mica phase was made by co-reacting illite clay and GNEP simulated waste. The Cs-mica accommodates up to 30% wt% Cs{sub 2}O and all the GNEP waste species, Ba, Sr, Rb including the Cs-137 transmutation to Ba-137. For reference, the cesium mineral pollucite (CsAlSi{sub 2}O{sub 6}), currently being studied for GNEP applications, can only be fabricated at {>=}1000 deg. C. Pollucite mineralization creates secondary aqueous waste streams and NOx. Pollucite is not tolerant of high concentrations of Ba, Sr or Rb and forces the divalent species into different mineral host phases. The pollucite can accommodate up to 33% wt% Cs{sub 2}O. (authors)

  18. FLUIDIZED BED STEAM REFORMING MINERALIZATION FOR HIGH ORGANIC AND NITRATE WASTE STREAMS FOR THE GLOBAL NUCLEAR ENERGY PARTNERSHIP

    SciTech Connect (OSTI)

    Jantzen, C; Michael Williams, M

    2008-01-11

    Waste streams that may be generated by the Global Nuclear Energy Partnership (GNEP) Advanced Energy Initiative may contain significant quantities of organics (0-53 wt%) and/or nitrates (0-56 wt%). Decomposition of high nitrate streams requires reducing conditions, e.g. organic additives such as sugar or coal, to reduce the NO{sub x} in the off-gas to N{sub 2} to meet the Clean Air Act (CAA) standards during processing. Thus, organics will be present during waste form stabilization regardless of which GNEP processes are chosen, e.g. organics in the feed or organics for nitrate destruction. High organic containing wastes cannot be stabilized with the existing HLW Best Developed Available Technology (BDAT) which is HLW vitrification (HLVIT) unless the organics are removed by preprocessing. Alternative waste stabilization processes such as Fluidized Bed Steam Reforming (FBSR) operate at moderate temperatures (650-750 C) compared to vitrification (1150-1300 C). FBSR converts organics to CAA compliant gases, creates no secondary liquid waste streams, and creates a stable mineral waste form that is as durable as glass. For application to the high Cs-137 and Sr-90 containing GNEP waste streams a single phase mineralized Cs-mica phase was made by co-reacting illite clay and GNEP simulated waste. The Cs-mica accommodates up to 30% wt% Cs{sub 2}O and all the GNEP waste species, Ba, Sr, Rb including the Cs-137 transmutation to Ba-137. For reference, the cesium mineral pollucite (CsAlSi{sub 2}O{sub 6}), currently being studied for GNEP applications, can only be fabricated at {ge} 1000 C. Pollucite mineralization creates secondary aqueous waste streams and NO{sub x}. Pollucite is not tolerant of high concentrations of Ba, Sr or Rb and forces the divalent species into different mineral host phases. The pollucite can accommodate up to 33% wt% Cs{sub 2}O.

  19. Highly Enriched Uranyl Nitrate in Annular Tanks with Concrete Reflection: 1 x 3 Line Array of Nested Pairs of Tanks

    SciTech Connect (OSTI)

    James Cleaver; John D. Bess; Nathan Devine; Fitz Trumble

    2009-09-01

    A series of seven experiments were performed at the Rocky Flats Critical Mass Laboratory beginning in August, 1980 (References 1 and 2). Highly enriched uranyl nitrate solution was introduced into a 1-3 linear array of nested stainless steel annular tanks. The tanks were inside a concrete enclosure, with various moderator and absorber materials placed inside and/or between the tanks. These moderators and absorbers included boron-free concrete, borated concrete, borated plaster, and cadmium. Two configurations included placing bottles of highly enriched uranyl nitrate between tanks externally. Another experiment involved nested hemispheres of highly enriched uranium placed between tanks externally. These three configurations are not evaluated in this report. The experiments evaluated here are part of a series of experiments, one set of which is evaluated in HEU-SOL-THERM-033. The experiments in this and HEU-SOL-THERM-033 were performed similarly. They took place in the same room and used the same tanks, some of the same moderators and absorbers, some of the same reflector panels, and uranyl nitrate solution from the same location. There are probably additional similarities that existed that are not identified here. Thus, many of the descriptions in this report are either the same or similar to those in the HEU-SOL-THERM-033 report. Seventeen configurations (sixteen of which were critical) were performed during seven experiments; six of those experiments are evaluated here with thirteen configurations. Two configurations were identical, except for solution height, and were conducted to test repeatability. The solution heights were averaged and the two were evaluated as one configuration, which gives a total of twelve evaluated configurations. One of the seventeen configurations was subcritical. Of the twelve critical configurations evaluated, nine were judged as acceptable as benchmarks.

  20. Ferrocyanide Safety Project Dynamic X-Ray Diffraction studies of sodium nickel ferrocyanide reactions with equimolar nitrate/nitrite salts

    SciTech Connect (OSTI)

    Dodds, J.N. |

    1994-07-01

    Dynamic X-ray Diffraction (DXRD) has been to used to identify and quantify the solid state reactions that take place between sodium nickel ferrocyanide, Na{sub 2}NiFe(CN){sub 6}, and equimolar concentrations of sodium nitrate/nitrite, reactions of interest to the continued environmental safety of several large underground waste storage tanks at the Hanford site in eastern Washington. The results are supportive of previous work, which indicated that endothermic dehydration and melting of the nitrates take place before the occurrence of exothermic reactions that being about 300{degrees}C. The DXRD results show that a major reaction set at these temperatures is the occurrence of a series reaction that produces sodium cyanate, NaCNO, as an intermediate in a mildly exothermic first step. In the presence of gaseous oxygen, NaCNO subsequently reacts exothermally and at a faster rate to form metal oxides. Measurements of the rate of this reaction are used to estimate the heat release. Comparisons of this estimated heat release rate with heat transfer rates from a hypothetical ``hot spot`` show that, even in a worst-case scenario, the heat transfer rates are approximately eight times higher than the rate of energy release from the exothermic reactions.

  1. MOLECULAR APPROACHES FOR IN SITU IDENTIFCIATION OF NITRATE UTILIZATION BY MARINE BACTERIA AND PHYTOPLANKTON

    SciTech Connect (OSTI)

    Frischer, Marc E.; Verity, Peter G.; Gilligan, Mathew R.; Bronk, Deborah A.; Zehr, Jonathan P.; Booth, Melissa G.

    2013-09-12

    Traditionally, the importance of inorganic nitrogen (N) for the nutrition and growth of marine phytoplankton has been recognized, while inorganic N utilization by bacteria has received less attention. Likewise, organic N has been thought to be important for heterotrophic organisms but not for phytoplankton. However, accumulating evidence suggests that bacteria compete with phytoplankton for nitrate (NO3-) and other N species. The consequences of this competition may have a profound effect on the flux of N, and therefore carbon (C), in ocean margins. Because it has been difficult to differentiate between N uptake by heterotrophic bacterioplankton versus autotrophic phytoplankton, the processes that control N utilization, and the consequences of these competitive interactions, have traditionally been difficult to study. Significant bacterial utilization of DIN may have a profound effect on the flux of N and C in the water column because sinks for dissolved N that do not incorporate inorganic C represent mechanisms that reduce the atmospheric CO2 drawdown via the ?biological pump? and limit the flux of POC from the euphotic zone. This project was active over the period of 1998-2007 with support from the DOE Biotechnology Investigations ? Ocean Margins Program (BI-OMP). Over this period we developed a tool kit of molecular methods (PCR, RT-PCR, Q-PCR, QRT-PCR, and TRFLP) and combined isotope mass spectrometry and flow-cytometric approaches that allow selective isolation, characterization, and study of the diversity and genetic expression (mRNA) of the structural gene responsible for the assimilation of NO3- by heterotrophic bacteria (nasA). As a result of these studies we discovered that bacteria capable of assimilating NO3- are ubiquitous in marine waters, that the nasA gene is expressed in these environments, that heterotrophic bacteria can account for a significant fraction of total DIN uptake in different ocean margin systems, that the expression of nasA is differentially regulated in genetically distinct NO3- assimilating bacteria, and that the best predictors of nasA gene expression are either NO3- concentration or NO3- uptake rates. These studies provide convincing evidence of the importance of bacterial utilization of NO3-, insight into controlling processes, and provide a rich dataset that are being used to develop linked C and N modeling components necessary to evaluate the significance of bacterial DIN utilization to global C cycling. Furthermore, as a result of BI-OMP funding we made exciting strides towards institutionalizing a research and education based collaboration between the Skidaway Institute of Oceanography (SkIO) and Savannah State University (SSU), an historically black university within the University System of Georgia with undergraduate and now graduate programs in marine science. The BI-OMP program, in addition to supporting undergraduate (24) graduate (10) and postdoctoral (2) students, contributed to the development of a new graduate program in Marine Sciences at SSU that remains an important legacy of this project. The long-term goals of these collaborations are to increase the capacity for marine biotechnology research and to increase representation of minorities in marine, environmental and biotechnological sciences.

  2. Utilization of Common Automotive Three-Way NO{sub x} Reduction Catalyst for Managing Off- Gas from Thermal Treatment of High-Nitrate Waste - 13094

    SciTech Connect (OSTI)

    Foster, Adam L.; Ki Song, P.E.

    2013-07-01

    Studsvik's Thermal Organic Reduction (THOR) steam reforming process has been tested and proven to effectively treat radioactive and hazardous wastes streams with high nitrate contents to produce dry, stable mineral products, while providing high conversion (>98%) of nitrates and nitrites directly to nitrogen gas. However, increased NO{sub x} reduction may be desired for some waste streams under certain regulatory frameworks. In order to enhance the NO{sub x} reduction performance of the THOR process, a common Three-Way catalytic NO{sub x} reduction unit was installed in the process gas piping of a recently completed Engineering Scale Technology Demonstration (ESTD). The catalytic DeNO{sub x} unit was located downstream of the main THOR process vessel, and it was designed to catalyze the reduction of residual NO{sub x} to nitrogen gas via the oxidation of the hydrogen, carbon monoxide, and volatile organic compounds that are inherent to the THOR process gas. There was no need for auxiliary injection of a reducing gas, such as ammonia. The unit consisted of four monolith type catalyst sections positioned in series with a gas mixing section located between each catalyst section. The process gas was monitored for NO{sub x} concentration upstream and downstream of the catalytic DeNO{sub x} unit. Conversion efficiencies ranged from 91% to 97% across the catalytic unit, depending on the composition of the inlet gas. Higher concentrations of hydrogen and carbon monoxide in the THOR process gas increased the NO{sub x} reduction capability of the catalytic DeNO{sub x} unit. The NO{sub x} destruction performance of THOR process in combination with the Three-Way catalytic unit resulted in overall system NO{sub x} reduction efficiencies of greater than 99.9% with an average NO{sub x} reduction efficiency of 99.94% for the entire demonstration program. This allowed the NO{sub x} concentration in the ESTD exhaust gas to be maintained at less than 40 parts per million (ppm), dry basis with an average concentration of approximately 17 ppm, dry basis. There were no signs of catalyst deactivation throughout the 6 day demonstration program, even under the high steam (>50%) content and chemically reducing conditions inherent to the THOR process. Utilization of the common Three-Way automotive catalyst may prove to be a cost effective method for improving NO{sub x} emissions from thermal treatment processes that utilize similar processing conditions. This paper will discuss the details of the implementation and performance of the Three-Way catalytic DeNO{sub x} unit at the THOR ESTD, as well as a discussion of future work to determine the long-term durability of the catalyst in the THOR process. (authors)

  3. Modeling of early age loss of lithium ions from pore solution of cementitious systems treated with lithium nitrate

    SciTech Connect (OSTI)

    Kim, Taehwan Olek, Jan

    2015-01-15

    Addition of lithium nitrate admixture to the fresh concrete mixture helps to minimize potential problems related to alkali-silica reaction. For this admixture to function as an effective ASR control measure, it is imperative that the lithium ions remain in the pore solution. However, it was found that about 50% of the originally added lithium ions are removed from the pore solution during early stages of hydration. This paper revealed that the magnitude of the Li{sup +} ion loss is highly dependent on the concentration of Li{sup +} ions in the pore solution and the hydration rate of the cementitious systems. Using these findings, an empirical model has been developed which can predict the loss of Li{sup +} ions from the pore solution during the hydration period. The proposed model can be used to investigate the effects of mixture parameters on the loss of Li{sup +} ions from the pore solution of cementitious system.

  4. Corrosion resistance of stainless steels during thermal cycling in alkali nitrate molten salts.

    SciTech Connect (OSTI)

    Bradshaw, Robert W.; Goods, Steven Howard

    2001-09-01

    The corrosion behavior of three austenitic stainless steels was evaluated during thermal cycling in molten salt mixtures consisting of NaNO{sub 3} and KNO{sub 3}. Corrosion tests were conducted with Types 316, 316L and 304 stainless steels for more than 4000 hours and 500 thermal cycles at a maximum temperature of 565 C. Corrosion rates were determined by chemically descaling coupons. Metal losses ranged from 5 to 16 microns and thermal cycling resulted in moderately higher corrosion rates compared to isothermal conditions. Type 316 SS was somewhat more corrosion resistant than Type 304 SS in these tests. The effect of carbon content on corrosion resistance was small, as 316L SS corroded only slightly slower than 316 SS. The corrosion rates increased as the dissolved chloride content of the molten salt mixtures increased. Chloride concentrations approximating 1 wt.%, coupled with thermal cycling, resulted in linear weight loss kinetics, rather than parabolic kinetics, which described corrosion rates for all other conditions. Optical microscopy and electron microprobe analysis revealed that the corrosion products consisted of iron-chromium spinel, magnetite, and sodium ferrite, organized as separate layers. Microanalysis of the elemental composition of the corrosion products further demonstrated that the chromium content of the iron-chromium spinel layer was relatively high for conditions in which parabolic kinetics were observed. However, linear kinetics were observed when the spinel layer contained relatively little chromium.

  5. Ion Recognition Approach to Volume Reduction of Alkaline Tank Waste by Separation and Recycle of Sodium Hydroxide and Sodium Nitrate

    SciTech Connect (OSTI)

    Moyer, Bruce A.; Marchand, Alan P.

    2001-06-01

    Disposal of high-level nuclear waste is horrendously expensive, in large part because the actual radioactive matter in the tanks has been diluted over 1000-fold by ordinary inorganic chemicals. Treatment processes themselves can exacerbate the problem by adding further volume to the waste. Waste retrieval and sludge washing, for example, will require copious amounts of sodium hydroxide. If the needed sodium hydroxide could be separated from the waste and recycled, however, the addition of fresh sodium hydroxide could be avoided, ultimately reducing the final waste volume and associated disposal costs. The major objective of this research is to explore new liquid-liquid extraction approaches to the selective separation of sodium hydroxide from alkaline high-level wastes stored in underground tanks at the Hanford and Savannah River sites. Consideration is also given to separating potassium and abundant anions, including nitrate, nitrite, aluminate, and carbonate. Salts of these ions represent possible additional value for recycle, alternative disposal, or even use as commodity chemicals. A comprehensive approach toward understanding the extractive chemistry of these salts is envisioned, involving systems of varying complexity, from use of simple solvents to new bifunctional host molecules for ion-pair recognition. These extractants will ideally require no adjustment of the waste composition and will release the extracted salt into water, thereby consuming no additional chemicals and producing no additional waste volume. The overall goal of this research is to provide a scientific foundation upon which the feasibility of new liquid-liquid extraction chemistry applicable to the bulk reduction of the volume of tank waste can be evaluated.

  6. Ion Recognition Approach to Volume Reduction of Alkaline Tank Waste by Separation and Recycle of Sodium Hydroxide and Sodium Nitrate

    SciTech Connect (OSTI)

    Moyer, Bruce A.; Marchand, Alan P.

    2000-06-01

    Disposal of high- level waste is horrendously expensive, in large part because the actual radioactive matter in the tanks has been diluted over 1000-fold by ordinary inorganic chemicals. Treatment processes themselves can exacerbate the problem by adding further volume to the waste. Waste retrieval and sludge washing, for example, will require copious amounts of sodium hydroxide. If the needed sodium hydroxide could be separated from the waste and recycled, however, the addition of fresh sodium hydroxide could be avoided, ultimately reducing the final waste volume and associated disposal costs. The major objective of this research is to explore new liquid- liquid extraction approaches to the selective separation of sodium hydroxide from alkaline high-level wastes stored in underground tanks at the Hanford and Savannah River sites. Consideration is also given to separating potassium and abundant anions, including nitrate, nitrite, aluminate, and carbonate. Salts of these ions represent possible additional value for recycle, alternative disposal, or even use as commodity chemicals. A comprehensive approach toward understanding the extractive chemistry of these salts is envisioned, involving systems of varying complexity, from use of simple solvents to new bifunctional host molecules for ion-pair recognition. These extractants will ideally require no adjustment of the waste composition and will release the extracted salt into water, thereby consuming no additional chemicals and producing no additional waste volume. The overall goal of this research is to provide a scientific foundation upon which the feasibility of new liquid-liquid extraction chemistry applicable to the bulk reduction of the volume of tank waste can be evaluated.

  7. Ion Recognition Approach to Volume Reduction of Alkaline Tank Waste by Separation and Recycle of Sodium Hydroxide and Sodium Nitrate

    SciTech Connect (OSTI)

    Moyer, Bruce A.; Marchand, Alan P.; Bryan, Jeffrey C.; Bonnesen, Peter V.

    1999-06-01

    The objective of this research is to explore new liquid-liquid extraction approaches to the selective separation of major sodium salts from alkaline high-level wastes stored in underground tanks at Hanford, Savannah River, and Oak Ridge sites. Disposal of high level waste is horrendously expensive, in large part because the actual radioactive matter in the tanks has been diluted over 1000-fold by ordinary inorganic chemicals. Since the residual bulk chemicals must still undergo expensive treatment and disposal after most of the hazardous radionuclides have been removed, large cost savings will result from processes that reduce the overall waste volume. It is proposed that major cost savings can be expected if sodium hydroxide needed for sludge washing can be obtained from the waste itself, thus avoiding the addition of yet another bulk chemical to the waste and still further increase of the waste volume and disposal cost. Secondary priority is given to separating potassium an d abundant anions, including nitrate, nitrite, aluminate, and carbonate. Salts of these ions represent possible additional value for recycle, alternative disposal, or even use as commodity chemicals. A comprehensive approach toward understanding the extractive chemistry of these salts is envisioned, involving systems of varying complexity, from use of simple solvents to new bifunctional host molecules for ion-pair recognition. These extractants will ideally require no adjustment of the waste composition and will release the extracted salt into water, thereby consuming no additional chemicals and producing no additional waste volume. The overall goal of this research is to provide a scientific foundation upon which the feasibility of new liquid-liquid extraction chemistry applicable to the bulk reduction of the volume of tank waste can be evaluated.

  8. Temperature determination using pyrometry

    DOE Patents [OSTI]

    Breiland, William G.; Gurary, Alexander I.; Boguslavskiy, Vadim

    2002-01-01

    A method for determining the temperature of a surface upon which a coating is grown using optical pyrometry by correcting Kirchhoff's law for errors in the emissivity or reflectance measurements associated with the growth of the coating and subsequent changes in the surface thermal emission and heat transfer characteristics. By a calibration process that can be carried out in situ in the chamber where the coating process occurs, an error calibration parameter can be determined that allows more precise determination of the temperature of the surface using optical pyrometry systems. The calibration process needs only to be carried out when the physical characteristics of the coating chamber change.

  9. NEPA Determination Complete

    Broader source: Energy.gov [DOE]

    DOE has determined that this proposed project is a major Federal action that may significantly affect the quality of the human environment. To comply with the National Environmental Policy Act ...

  10. Solids mass flow determination

    DOE Patents [OSTI]

    Macko, Joseph E.

    1981-01-01

    Method and apparatus for determining the mass flow rate of solids mixed with a transport fluid to form a flowing mixture. A temperature differential is established between the solids and fluid. The temperature of the transport fluid prior to mixing, the temperature of the solids prior to mixing, and the equilibrium temperature of the mixture are monitored and correlated in a heat balance with the heat capacities of the solids and fluid to determine the solids mass flow rate.

  11. Uranyl Nitrate Flow Loop

    SciTech Connect (OSTI)

    Ladd-Lively, Jennifer L

    2008-10-01

    The objectives of the work discussed in this report were to: (1) develop a flow loop that would simulate the purified uranium-bearing aqueous stream exiting the solvent extraction process in a natural uranium conversion plant (NUCP); (2) develop a test plan that would simulate normal operation and disturbances that could be anticipated in an NUCP; (3) use the flow loop to test commercially available flowmeters for use as safeguards monitors; and (4) recommend a flowmeter for production-scale testing at an NUCP. There has been interest in safeguarding conversion plants because the intermediate products [uranium dioxide (UO{sub 2}), uranium tetrafluoride (UF{sub 4}), and uranium hexafluoride (UF{sub 6})] are all suitable uranium feedstocks for producing special nuclear materials. Furthermore, if safeguards are not applied virtually any nuclear weapons program can obtain these feedstocks without detection by the International Atomic Energy Agency (IAEA). Historically, IAEA had not implemented safeguards until the purified UF{sub 6} product was declared as feedstock for enrichment plants. H. A. Elayat et al. provide a basic definition of a safeguards system: 'The function of a safeguards system on a chemical conversion plant is in general terms to verify that no useful nuclear material is being diverted to use in a nuclear weapons program'. The IAEA now considers all highly purified uranium compounds as candidates for safeguarding. DOE is currently interested in 'developing instruments, tools, strategies, and methods that could be of use to the IAEA in the application of safeguards' for materials found in the front end of the nuclear fuel cycle-prior to the production of the uranium hexafluoride or oxides that have been the traditional starting point for IAEA safeguards. Several national laboratories, including Oak Ridge, Los Alamos, Lawrence Livermore, and Brookhaven, have been involved in developing tools or techniques for safeguarding conversion plants. This study was sponsored by the U.S. Department of Energy (DOE) NA-241, Office of Dismantlement and Transparency.

  12. Time-resolved infrared reflectance studies of the dehydration-induced transformation of uranyl nitrate hexahydrate to the trihydrate form

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Johnson, Timothy J.; Sweet, Lucas E.; Meier, David E.; Edward J. Mausolf; Kim, Eunja; Weck, Philippe F.; Buck, Edgar C.; Bruce K. McNamara

    2015-09-08

    Uranyl nitrate is a key species in the nuclear fuel cycle. However, this species is known to exist in different states of hydration, including the hexahydrate ([UO2(NO3)2(H2O)6] often called UNH), the trihydrate [UO2(NO3)2(H2O)3 or UNT], and in very dry environments the dihydrate form [UO2(NO3)2(H2O)2]. Their relative stabilities depend on both water vapor pressure and temperature. In the 1950s and 1960s, the different phases were studied by infrared transmission spectroscopy but were limited both by instrumental resolution and by the ability to prepare the samples for transmission. We have revisited this problem using time-resolved reflectance spectroscopy, which requires no sample preparationmore » and allows dynamic analysis while the sample is exposed to a flow of N2 gas. Samples of known hydration state were prepared and confirmed via X-ray diffraction patterns of known species. In reflectance mode the hexahydrate UO2(NO3)2(H2O)6 has a distinct uranyl asymmetric stretch band at 949.0 cm–1 that shifts to shorter wavelengths and broadens as the sample desiccates and recrystallizes to the trihydrate, first as a shoulder growing in on the blue edge but ultimately results in a doublet band with reflectance peaks at 966 and 957 cm–1. The data are consistent with transformation from UNH to UNT as UNT has two inequivalent UO22+ sites. The dehydration of UO2(NO3)2(H2O)6 to UO2(NO3)2(H2O)3 is both a structural and morphological change that has the lustrous lime green UO2(NO3)2(H2O)6 crystals changing to the matte greenish yellow of the trihydrate solid. As a result, the phase transformation and crystal structures were confirmed by density functional theory calculations and optical microscopy methods, both of which showed a transformation with two distinct sites for the uranyl cation in the trihydrate, with only one in the hexahydrate.« less

  13. Nitrative DNA damage induced by multi-walled carbon nanotube via endocytosis in human lung epithelial cells

    SciTech Connect (OSTI)

    Guo, Feiye; Ma, Ning; Horibe, Yoshiteru; Kawanishi, Shosuke; Murata, Mariko; Hiraku, Yusuke

    2012-04-15

    Carbon nanotube (CNT) has a promising usage in the field of material science for industrial purposes because of its unique physicochemical property. However, intraperitoneal administration of CNT was reported to cause mesothelioma in experimental animals. Chronic inflammation may contribute to carcinogenesis induced by fibrous materials. 8-Nitroguanine is a mutagenic DNA lesion formed during inflammation and may play a role in CNT-induced carcinogenesis. In this study, we examined 8-nitroguanine formation in A549 human lung alveolar epithelial cells treated with multi-walled CNT (MWCNT) by fluorescent immunocytochemistry. Both MWCNTs with diameter of 2030 nm (CNT20) and 4070 nm (CNT40) significantly induced 8-nitroguanine formation at 5 and 10 ?g/ml (p < 0.05), which persisted for 24 h, although there was no significant difference in DNA-damaging abilities of these MWCNTs. MWCNTs significantly induced the expression of inducible nitric oxide synthase (iNOS) for 24 h (p < 0.05). MWCNTs also significantly increased the level of nitrite, a hydrolysis product of oxidized NO, in the culture supernatant at 4 and 8 h (p < 0.05). MWCNT-induced 8-nitroguanine formation and iNOS expression were largely suppressed by inhibitors of iNOS (1400 W), nuclear factor-?B (Bay11-7082), actin polymerization (cytochalasin D), caveolae-mediated endocytosis (methyl-?-cyclodextrin, MBCD) and clathrin-mediated endocytosis (monodansylcadaverine, MDC). Electron microscopy revealed that MWCNT was mainly located in vesicular structures in the cytoplasm, and its cellular internalization was reduced by MBCD and MDC. These results suggest that MWCNT is internalized into cells via clathrin- and caveolae-mediated endocytosis, leading to inflammatory reactions including iNOS expression and resulting nitrative DNA damage, which may contribute to carcinogenesis. Highlights: ?Multi-walled carbon nanotube (MWCNT) caused DNA damage in A549 cells. ?MWCNT formed 8-nitroguanine, a DNA lesion associated with inflammatory response. ?MWCNT was internalized into cells via caveolin- and clathrin-mediated endocytosis. ?8-Nitroguanine formation and iNOS expression involved these types of endocytosis. ?Internalized MWCNT plays a key role in inflammatory response and DNA damage.

  14. Time-Resolved Infrared Reflectance Studies of the Dehydration-Induced Transformation of Uranyl Nitrate Hexahydrate to the Trihydrate Form

    SciTech Connect (OSTI)

    Johnson, Timothy J.; Sweet, Lucas E.; Meier, David E.; Mausolf, Edward J.; Kim, Eunja; Weck, Philippe F.; Buck, Edgar C.; McNamara, Bruce K.

    2015-10-01

    Uranyl nitrate is a key species in the nuclear fuel cycle. However, this species is known to exist in different states of hydration, including the hexahydrate ([UO2(NO3)2(H2O)6] often called UNH), the trihydrate [UO2(NO3)2(H2O)3 or UNT], and in very dry environments the dihydrate form [UO2(NO3)2(H2O)2]. Their relative stabilities depend on both water vapor pressure and temperature. In the 1950s and 1960s the different phases were studied by infrared transmission spectroscopy, but were limited both by instrumental resolution and by the ability to prepare the samples for transmission. We have revisited this problem using time-resolved reflectance spectroscopy, which requires no sample preparation and allows dynamic analysis while the sample is exposed to a flow of N2 gas. Samples of known hydration state were prepared and confirmed via X-ray diffraction patterns of known species. In reflectance mode the hexahydrate UO2(NO3)2(H2O)6 has a distinct uranyl asymmetric stretch band at 949.0 cm-1 that shifts to shorter wavelengths and broadens as the sample desiccates and recrystallizes to the trihydrate, first as a shoulder growing in on the blue edge but ultimately results in a doublet band with reflectance peaks at 966 and 957 cm-1. The data are consistent with transformation from UNH to UNT as UNT has two inequivalent UO22+ sites. The dehydration of UO2(NO3)2(H2O)6 to UO2(NO3)2(H2O)3 is both a structural and morphological change that has the lustrous lime green UO2(NO3)2(H2O)6 crystals changing to the matte greenish yellow of the trihydrate solid. The phase transformation and crystal structures were confirmed by density functional theory calculations and optical microscopy methods, both of which showed a transformation with two distinct sites for the uranyl cation in the trihydrate, with but one in the hexahydrate.

  15. Dual nitrate isotopes clarify the role of biological processing and hydrologic flow paths on nitrogen cycling in subtropical low-gradient watersheds

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Griffiths, Natalie A.; Jackson, C. Rhett; McDonnell, Jeffrey J.; Klaus, Julian; Du, Enhao; Bitew, Menberu M.

    2016-02-08

    Nitrogen (N) is an important nutrient as it often limits productivity but in excess can impair water quality. Most studies on watershed N cycling have occurred in upland forested catchments where snowmelt dominates N export; fewer studies have focused on low-relief watersheds that lack snow. We examined watershed N cycling in three adjacent, low-relief watersheds in the Upper Coastal Plain of the southeastern United States to better understand the role of hydrological flow paths and biological transformations of N at the watershed scale. Groundwater was the dominant source of nitrified N to stream water in two of the three watersheds,more » while atmospheric deposition comprised 28% of stream water nitrate in one watershed. The greater atmospheric contribution may have been due to the larger stream channel area relative to total watershed area or the dominance of shallow subsurface flow paths contributing to stream flow in this watershed. There was a positive relationship between temperature and stream water ammonium concentrations and a negative relationship between temperature and stream water nitrate concentrations in each watershed suggesting that N cycling processes (i.e., nitrification and denitrification) varied seasonally. However, there were no clear patterns in the importance of denitrification in different water pools possibly because a variety of factors (i.e., assimilatory uptake, dissimilatory uptake, and mixing) affected nitrate concentrations. In conclusion, together, these results highlight the hydrological and biological controls on N cycling in low-gradient watersheds and variability in N delivery flow paths among adjacent watersheds with similar physical characteristics.« less

  16. Categorical Exclusion Determinations: Environmental Management...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Consolidated Business Service Center Categorical Exclusion Determinations: Environmental Management Consolidated Business Service Center Categorical Exclusion Determinations issued ...

  17. Categorical Exclusion Determinations: Minnesota | Department...

    Office of Environmental Management (EM)

    Minnesota Categorical Exclusion Determinations: Minnesota Location Categorical Exclusion Determinations issued for actions in Minnesota. DOCUMENTS AVAILABLE FOR DOWNLOAD December ...

  18. Waste Determination Equivalency - 12172

    SciTech Connect (OSTI)

    Freeman, Rebecca D.

    2012-07-01

    The Savannah River Site (SRS) is a Department of Energy (DOE) facility encompassing approximately 800 square kilometers near Aiken, South Carolina which began operations in the 1950's with the mission to produce nuclear materials. The SRS contains fifty-one tanks (2 stabilized, 49 yet to be closed) distributed between two liquid radioactive waste storage facilities at SRS containing carbon steel underground tanks with storage capacities ranging from 2,800,000 to 4,900,000 liters. Treatment of the liquid waste from these tanks is essential both to closing older tanks and to maintaining space needed to treat the waste that is eventually vitrified or disposed of onsite. Section 3116 of the Ronald W. Reagan National Defense Authorization Act of Fiscal Year 2005 (NDAA) provides the Secretary of Energy, in consultation with the Nuclear Regulatory Commission (NRC), a methodology to determine that certain waste resulting from prior reprocessing of spent nuclear fuel are not high-level radioactive waste if it can be demonstrated that the waste meets the criteria set forth in Section 3116(a) of the NDAA. The Secretary of Energy, in consultation with the NRC, signed a determination in January 2006, pursuant to Section 3116(a) of the NDAA, for salt waste disposal at the SRS Saltstone Disposal Facility. This determination is based, in part, on the Basis for Section 3116 Determination for Salt Waste Disposal at the Savannah River Site and supporting references, a document that describes the planned methods of liquid waste treatment and the resulting waste streams. The document provides descriptions of the proposed methods for processing salt waste, dividing them into 'Interim Salt Processing' and later processing through the Salt Waste Processing Facility (SWPF). Interim Salt Processing is separated into Deliquification, Dissolution, and Adjustment (DDA) and Actinide Removal Process/Caustic Side Solvent Extraction Unit (ARP/MCU). The Waste Determination was signed by the Secretary of Energy in January of 2006 based on proposed processing techniques with the expectation that it could be revised as new processing capabilities became viable. Once signed, however, it became evident that any changes would require lengthy review and another determination signed by the Secretary of Energy. With the maturation of additional salt removal technologies and the extension of the SWPF start-up date, it becomes necessary to define 'equivalency' to the processes laid out in the original determination. For the purposes of SRS, any waste not processed through Interim Salt Processing must be processed through SWPF or an equivalent process, and therefore a clear statement of the requirements for a process to be equivalent to SWPF becomes necessary. (authors)

  19. Interim Action Determination

    Energy Savers [EERE]

    Interim Action Determination Processing of Plutonium Materials from the DOE Standard 3013 Surveillance Program in H-Canyon at the Savannah River Site The Department of Energy (DOE) is preparing the Surplus Plutonium Disposition Supplemental Environmental Impact Statement (SPD SEIS, DOE/EIS-0283-S2). DOE is evaluating alternatives for disposition of non-pit plutonium that is surplus to the national security needs of the United States. Although the Deputy Secretary of Energy approved Critical

  20. NEPA Determination Form

    National Nuclear Security Administration (NNSA)

    LA NEPA COMPLIANCE DETERMINATION FORM PRID - 09P-0059 V2 Page 1 of 8 Project/Activity Title: TA-3 Substation Replacement Project PRID: 09P-0059 V2 Date: February 16, 2016 Purpose: The proposed demolition and replacement of the Los Alamos National Laboratory's (LANL) Technical Area (TA)-3 electrical power substation is needed to provide reliable and efficient electrical distribution systems with sufficient electrical capacity to support the national security missions. The electrical distribution

  1. Award Fee Determination Summary

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 CH2M Hill Plateau Remediation Company Contract Number: DE-AC06-08RL14788 Final Fee Determination for Base funded Performance Measures Basis of Evaluation: Completion of Performance Measures contained in Section J, Attachment J.4, Performance Evaluation and Measurement Plan, according to the identified completion criteria. Evaluation Results: FY 2012 Base Period Fee Available Fee allocated to FY 2012* Performance Measures $10,399,033.60 Incremental Fee $4,490,000.00 Provisional Fee

  2. Award Fee Determination Summary

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 CH2M Hill Plateau Remediation Company Contract Number: DE-AC06-08RL14788 Final Fee Determination for Base funded and American Recovery and Reinvestment Act (Recovery) funded Performance Measures Basis of Evaluation: Completion of Performance Measures contained in Section J, AttachmentJ.4, Performance Evaluation and Measurement Plan, according to the identified completion criteria. Evaluation Results: Fiscal Year 2011 (Oct 1, 2010 - Sept 30, 2011) Base Funded Fee Recovery Funded Fee Available

  3. Time-resolved infrared reflectance studies of the dehydration-induced transformation of uranyl nitrate hexahydrate to the trihydrate form

    SciTech Connect (OSTI)

    Johnson, Timothy J.; Sweet, Lucas E.; Meier, David E.; Edward J. Mausolf; Kim, Eunja; Weck, Philippe F.; Buck, Edgar C.; Bruce K. McNamara

    2015-09-08

    Uranyl nitrate is a key species in the nuclear fuel cycle. However, this species is known to exist in different states of hydration, including the hexahydrate ([UO2(NO3)2(H2O)6] often called UNH), the trihydrate [UO2(NO3)2(H2O)3 or UNT], and in very dry environments the dihydrate form [UO2(NO3)2(H2O)2]. Their relative stabilities depend on both water vapor pressure and temperature. In the 1950s and 1960s, the different phases were studied by infrared transmission spectroscopy but were limited both by instrumental resolution and by the ability to prepare the samples for transmission. We have revisited this problem using time-resolved reflectance spectroscopy, which requires no sample preparation and allows dynamic analysis while the sample is exposed to a flow of N2 gas. Samples of known hydration state were prepared and confirmed via X-ray diffraction patterns of known species. In reflectance mode the hexahydrate UO2(NO3)2(H2O)6 has a distinct uranyl asymmetric stretch band at 949.0 cm–1 that shifts to shorter wavelengths and broadens as the sample desiccates and recrystallizes to the trihydrate, first as a shoulder growing in on the blue edge but ultimately results in a doublet band with reflectance peaks at 966 and 957 cm–1. The data are consistent with transformation from UNH to UNT as UNT has two inequivalent UO22+ sites. The dehydration of UO2(NO3)2(H2O)6 to UO2(NO3)2(H2O)3 is both a structural and morphological change that has the lustrous lime green UO2(NO3)2(H2O)6 crystals changing to the matte greenish yellow of the trihydrate solid. As a result, the phase transformation and crystal structures were confirmed by density functional theory calculations and optical microscopy methods, both of which showed a transformation with two distinct sites for the uranyl cation in the trihydrate, with only one in the hexahydrate.

  4. Studies on lanthanoid complexes of open chain multidentate ligands. VIII. Preparation and structural characterization of the undecacoordinate complex of neodymium nitrate with N,N{prime}-bis(4-methoxyphenyl)tetraglycollic diamide

    SciTech Connect (OSTI)

    Zhijian Liang; Xinmin Gan; Ning Tang; Minyu Tan; Kaibei Yu; Ganzu Tan

    1993-12-31

    The title compound [Nd(L)(NO{sub 3}){sub 3}]2CH{sub 3}CN was formed by reaction of neodymium nitrate with N,N{prime}-bis(4-methoxyphenyl)tetraglycollic diamide (L). The complex crystallizes in the monoclinic system, space group Cc with Z = 4, a = 21.305(6), b = 11.470(4), c = 14.436(3) {angstrom}, {beta} = 97.41(2), V = 3498(2) {angstrom}{sup 3}. The pentadentate organic ligand wraps around the neodymium ion which is also bonded to three bidentate nitrate groups, achieving uncommon undecacoordination with the following mean bond lengths: Nd-O(etheric), 2.703; Nd-O(carbonyl), 2.518; Nd-O(nitrate), 2.546 {angstrom}. 18 refs., 2 figs., 3 tabs.

  5. Categorical Exclusion Determinations: California | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... February 25, 2016 CX-100493 Categorical Exclusion Determination Integrated Glass Coating ... February 25, 2016 CX-100514 Categorical Exclusion Determination Crop Protection Utilizing ...

  6. Categorical Exclusion Determinations: Connecticut | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    August 11, 2014 CX-100033: Categorical Exclusion Determination "Smart" Matrix Development ... May 22, 2014 CX-012145: Categorical Exclusion Determination Connecticut Clean Cities ...

  7. Categorical Exclusion Determinations: Louisiana | Department...

    Office of Environmental Management (EM)

    March 4, 2016 CX-100533 Categorical Exclusion Determination Pump Station Improvements ... February 18, 2015 CX-100185 Categorical Exclusion Determination Pump Station Improvements ...

  8. Categorical Exclusion Determinations: Mississippi | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    March 30, 2015 CX-013741: Categorical Exclusion Determination Statistical Analysis of ... March 30, 2015 CX-013758: Categorical Exclusion Determination Statistical Analysis of ...

  9. Total carbon dioxide, hydrographic, and nitrate measurements in the Southwest Pacific during Austral autumn, 1990: Results from NOAA/PMEL CGC-90 cruise

    SciTech Connect (OSTI)

    Lamb, M.F.; Feely, R.A.; Moore, L.

    1995-10-01

    In support of the National Oceanic and Atmospheric Administration (NOAA) Climate and Global Change (C&GC) Program, Pacific Marine Environmental Laboratory (PMEL) scientists have been measuring the growing burden of greenhouse gases in the thermocline waters of the Pacific Ocean since 1980. Collection of data at a series of hydrographic stations along longitude 170{degrees} W during austral autumn of 1990 was designed to enhance understanding of the increase in the column burden of chlorofluorocarbons and carbon dioxide in the thermocline waters since the last expedition in 1984. This document presents the procedures and methods used to obtain total carbon dioxide (TCO{sub 2}), hydrographic, and nitrate data during the NOAA/PMEL research vessel (R/V) Malcolm Baldrige CGC-90 Cruise. Data were collected along two legs; sampling for Leg 1 began along 170{degrees} W from 15{degrees} S to 60{degrees} S, then angled northwest toward New Zealand across the Western Boundary Current. Leg 2 included a reoccupation of some stations between 30{degrees} S and 15{degrees} S on 170{degrees} W and measurements from 15{degrees} S to 5{degrees} N along 170{degrees} W. The following data report summarizes the TCO{sub 2}, salinity, temperature, and nitrate measurements from 63 stations. The TCO, concentration in seawater samples was measured using a coulometric/extraction system (Models 5011 and 5030, respectively) originated by Ken Johnson. The NOAA/PMEL R/V Malcolm Baldrige CGC-90 Cruise data set is available without charge as a numeric data package (NDP) from the Carbon Dioxide Information Analysis Center. The NDP consists of two oceanographic data files, two FORTRAN 77 data retrieval routine files, a {open_quotes}readme{close_quotes} file, and this printed documentation, which describes the contents and format of all files as well as the procedures and methods used to obtain the data.

  10. Intracellular L-arginine concentration does not determine NO production in endothelial cells: Implications on the 'L-arginine paradox'

    SciTech Connect (OSTI)

    Shin, Soyoung; Mohan, Srinidi; Fung, Ho-Leung

    2011-11-04

    Highlights: Black-Right-Pointing-Pointer Our findings provide a possible solution to the 'L-arginine paradox'. Black-Right-Pointing-Pointer Extracellular L-arginine concentration is the major determinant of NO production. Black-Right-Pointing-Pointer Cellular L-arginine action is limited by cellular ARG transport, not the K{sub m} of NOS. Black-Right-Pointing-Pointer We explain how L-arginine supplementation can work to increase endothelial function. -- Abstract: We examined the relative contributory roles of extracellular vs. intracellular L-arginine (ARG) toward cellular activation of endothelial nitric oxide synthase (eNOS) in human endothelial cells. EA.hy926 human endothelial cells were incubated with different concentrations of {sup 15}N{sub 4}-ARG, ARG, or L-arginine ethyl ester (ARG-EE) for 2 h. To modulate ARG transport, siRNA for ARG transporter (CAT-1) vs. sham siRNA were transfected into cells. ARG transport activity was assessed by cellular fluxes of ARG, {sup 15}N{sub 4}-ARG, dimethylarginines, and L-citrulline by an LC-MS/MS assay. eNOS activity was determined by nitrite/nitrate accumulation, either via a fluorometric assay or by{sup 15}N-nitrite or estimated {sup 15}N{sub 3}-citrulline concentrations when {sup 15}N{sub 4}-ARG was used to challenge the cells. We found that ARG-EE incubation increased cellular ARG concentration but no increase in nitrite/nitrate was observed, while ARG incubation increased both cellular ARG concentration and nitrite accumulation. Cellular nitrite/nitrate production did not correlate with cellular total ARG concentration. Reduced {sup 15}N{sub 4}-ARG cellular uptake in CAT-1 siRNA transfected cells vs. control was accompanied by reduced eNOS activity, as determined by {sup 15}N-nitrite, total nitrite and {sup 15}N{sub 3}-citrulline formation. Our data suggest that extracellular ARG, not intracellular ARG, is the major determinant of NO production in endothelial cells. It is likely that once transported inside the cell, ARG can no longer gain access to the membrane-bound eNOS. These observations indicate that the 'L-arginine paradox' should not consider intracellular ARG concentration as a reference point.

  11. Radiolytic Degradation in Lanthanide/Actinide Separation LigandsNOPOPO: Radical Kinetics and Efficiencies Determinations

    SciTech Connect (OSTI)

    Katy L. Swancutt; Stephen P. Mezyk; Richard D. Tillotson; Sylvie Pailloux; Manab Chakravarty; Robert T. Paine; Leigh R. Martin

    2011-07-01

    Trivalent lanthanide/actinide separations from used nuclear fuel occurs in the presence radiation fields that degrades the extraction ligands and solvents. Here we have investigated the stability of a new ligand for lanthanide/actinide separation; 2,6-bis[(di(2-ethylhexyl)phosphino)methyl] pyridine N,P,P-trioxide, TEH(NOPOPO). The impact of {gamma}-radiolysis on the distribution ratios for actinide (Am) and Lanthanide (Eu) extraction both in the presence and absence of an acidic aqueous phase by TEH(NOPOPO) was determined. Corresponding reaction rate constants for the two major radicals, hydroxyl and nitrate, were determined for TEH(NOPOPO) in the aqueous phase, with room temperature values of (3.49 {+-} 0.10) x 10{sup 9} and (1.95 {+-} 0.15) x 10{sup 8} M{sup -1} s{sup -1}, respectively. The activation energy for this reaction was found to be 30.2 {+-} 4.1 kJ mol{sup -1}. Rate constants for two analogues (2-methylphosphonic acid pyridine N,P-dioxide and 2,6-bis(methylphosphonic acid) pyridine N,P,P-trioxide) were also determined to assist in determining the major reaction pathways.

  12. Categorical Exclusion Determinations: Tennessee | Department...

    Energy Savers [EERE]

    February 26, 2016 CX-100506 Categorical Exclusion Determination Biofuel Micro-Refineries ... Low-Viscosity Oils for Automotive Engine and Rear Axle Lubrication for 4% Improved ...

  13. CX-012200: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Determination of Excess Real Property CX(s) Applied: B1.36 Date: 05/01/2014 Location(s): Colorado Offices(s): Legacy Management

  14. CX-010689: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Generic CX Determination for Financial Assistance Awards CX(s) Applied: Unknown Date: 07/17/2013 Location(s): Illinois Offices(s): Chicago Office

  15. Categorical Exclusion Determinations: Environmental Management...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... September 13, 2011 CX-006990: Categorical Exclusion Determination Synthesis and Characterization of Coatings by Chemical Solution Deposition Methods CX(s) Applied: B3.6 Date: 09...

  16. Structural Criteria for the Rational Design of Selective Ligands: Convergent Hydrogen Bonding Sites for the Nitrate Anion

    SciTech Connect (OSTI)

    Hay, Benjamin P.; Gutowski, Maciej S.; Dixon, David A.; Garza , Jorge; Vargas, Rubicelia; Moyer, Bruce A.

    2004-06-30

    Molecular hosts for anion complexation are often constructed by combining two or more hydrogen bonding functional groups, DH. The deliberate design of complementary host architectures requires knowledge of the optimal geometry for the hydrogen bonds formed between the host and the guest. Herein, we present a detailed study of the structural aspects of hydrogen bonding interactions with the NO3 anion. A large number of crystal structures are analyzed to determine the number of hydrogen bond contacts per anion and to further characterize the structural aspects of these interactions. Electronic structure calculations are used to determine stable geometries and interaction energies for NO3 complexes with several simple molecules possessing DH groups, including water, methanol, N-methylformamide, and methane. Theoretical results are reported at several levels of density functional theory, including BP86/DN**, B3LYP/TZVP, and B3LYP/TZVP+, and at MP2/aug-cc-pVDZ. In addition, MP2 binding energies for these complexes were obtained at the complete basis set limit by extrapolating from single point energies obtained with larger correlation-consistent basis sets. The results establish that NO3 has an intrinsic hydrogen bonding topography in which there are six optimal sites for proton location. The structural features observed in crystal structures and in the optimized geometries of complexes are explained by a preference to locate the DH protons in these positions. For the strongest hydrogen bonding interactions, the NOH angle is bent at an angle of 115 10, and the hydrogen atom lies in the NO3 plane giving ONOH dihedral angles of 0 and 180. In addition, the D-H vector points towards the oxygen atom, giving DHO angles that are near linear, 170 10. Due to steric hindrance, simple alcohol OH and amide NH donors form 3:1 complexes with NO3, with HO distances of 1.85 0.5 . Thus, the optimal cavity radius for a tridentate host, defined as the distance from the center to the DH hydrogen atoms, is 2.65 0.15 .

  17. Ion Recognition Approach to Volume Reduction of Alkaline Tank Waste by Separation and Recycle of Sodium Hydroxide and Sodium Nitrate

    SciTech Connect (OSTI)

    Moyer, Bruce A.; Marchand, Alan P.; Bonnesen, Peter V.; Bryan, Jeffrey C.; Haverlock, Tamara J.

    2002-03-30

    This research has focused on new liquid-liquid extraction chemistry applicable to separation of major sodium salts from alkaline tank waste. It was the overall goal to provide the scientific foundation upon which the feasibility of liquid-liquid extraction chemistry for bulk reduction of the volume of tank waste can be evaluated. Sodium hydroxide represented the initial test case and primary focus. It is a primary component of the waste1 and has the most value for recycle. A full explanation of the relevance of this research to USDOE Environmental Management needs will be given in the Relevance, Impact, and Technology Transfer section below. It should be noted that this effort was predicated on the need for sodium removal primarily from low-activity waste, whereas evolving needs have shifted attention to volume reduction of the high-activity waste. The results of the research to date apply to both applications, though treatment of high-activity wastes raises new questions that will be addressed in the renewal period. Toward understanding the extractive chemistry of sodium hydroxide and other sodium salts, it was the intent to identify candidate extractants and determine their applicable basic properties regarding selectivity, efficiency, speciation, and structure. A hierarchical strategy was to be employed in which the type of liquid-liquid-extraction system varied in sophistication from simple, single-component solvents to solvents containing designer host molecules. As an aid in directing this investigation toward addressing the fundamental questions having the most value, a conceptualization of an ideal process was advanced. Accordingly, achieving adequate selectivity for sodium hydroxide represented a primary goal, but this result is worthwhile for waste applications only if certain conditions are met.

  18. Method of determining glass durability

    DOE Patents [OSTI]

    Jantzen, C.M.; Pickett, J.B.; Brown, K.G.; Edwards, T.B.

    1998-12-08

    A process is described for determining one or more leachate concentrations of one or more components of a glass composition in an aqueous solution of the glass composition by identifying the components of the glass composition, including associated oxides, determining a preliminary glass dissolution estimator, {Delta}G{sub p}, based upon the free energies of hydration for the component reactant species, determining an accelerated glass dissolution function, {Delta}G{sub a}, based upon the free energy associated with weak acid dissociation, {Delta}G{sub a}{sup WA}, and accelerated matrix dissolution at high pH, {Delta}G{sub a}{sup SB} associated with solution strong base formation, and determining a final hydration free energy, {Delta}G{sub f}. This final hydration free energy is then used to determine leachate concentrations for elements of interest using a regression analysis and the formula log{sub 10}(N C{sub i}(g/L))=a{sub i} + b{sub i}{Delta}G{sub f}. The present invention also includes a method to determine whether a particular glass to be produced will be homogeneous or phase separated. The present invention is also directed to methods of monitoring and controlling processes for making glass using these determinations to modify the feedstock materials until a desired glass durability and homogeneity is obtained. 4 figs.

  19. Method of determining glass durability

    DOE Patents [OSTI]

    Jantzen, Carol Maryanne; Pickett, John Butler; Brown, Kevin George; Edwards, Thomas Barry

    1998-01-01

    A process for determining one or more leachate concentrations of one or more components of a glass composition in an aqueous solution of the glass composition by identifying the components of the glass composition, including associated oxides, determining a preliminary glass dissolution estimator, .DELTA.G.sub.p, based upon the free energies of hydration for the component reactant species, determining an accelerated glass dissolution function, .DELTA.G.sub.a, based upon the free energy associated with weak acid dissociation, .DELTA.G.sub.a.sup.WA, and accelerated matrix dissolution at high pH, .DELTA.G.sub.a.sup.SB associated with solution strong base formation, and determining a final hydration free energy, .DELTA.G.sub.f. This final hydration free energy is then used to determine leachate concentrations for elements of interest using a regression analysis and the formula log.sub.10 (N C.sub.i (g/L))=a.sub.i +b.sub.i .DELTA.G.sub.f. The present invention also includes a method to determine whether a particular glass to be produced will be homogeneous or phase separated. The present invention is also directed to methods of monitoring and controlling processes for making glass using these determinations to modify the feedstock materials until a desired glass durability and homogeneity is obtained.

  20. Categorical Exclusion Determinations: Pennsylvania | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    August 3, 2015 CX-100321 Categorical Exclusion Determination VOLTTRON Compatible Whole Building root-Fault Detection and Diagnosis Award Number: DE-EE0007135 CX(s) Applied: A9, ...

  1. CX-100604 Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Final Determination of Coverage for Miscellaneous Refrigeration Products RIN 1904-AC66 CX(s) Applied: A6 EERE-Buildings Technology Program Date: 05/04/2016 Location(s): Nationwide Office(s): Golden Field Office

  2. CX-000768: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Determining the Variability of Continuous Mercury Monitors at Low Mercury LevelsCX(s) Applied: B3.6Date: 02/07/2010Location(s): Grand Forks, North DakotaOffice(s): Fossil Energy, National Energy Technology Laboratory

  3. CX-008905: Categorical Exclusion Determination

    Office of Energy Efficiency and Renewable Energy (EERE)

    Optimizing Accuracy of Determinations of Carbon Dioxide Storage Capacity and Permanence CX(s) Applied: A1, A9, B3.6 Date: 08/29/2012 Location(s): Wyoming Offices(s): National Energy Technology Laboratory

  4. CX-010776: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Advanced Test Reactor (ATR) Primary Coolant Leak Rate Determination System Equipment Replacement CX(s) Applied: B2.2 Date: 07/24/2013 Location(s): Idaho Offices(s): Nuclear Energy

  5. CX-010493: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Determining Distribution Coefficients by Surface-Enhanced Raman Spectroscopy (SERS) CX(s) Applied: B3.6 Date: 05/14/2013 Location(s): South Carolina Offices(s): Savannah River Operations Office

  6. Categorical Exclusion Determinations: Wisconsin | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... March 4, 2015 CX-100191 Categorical Exclusion Determination Cost-Optimized Modular Helical Rotors Turbine-Generator System for Small Hydro Power Plants Award Number: DE-EE0006927 ...

  7. Categorical Exclusion Determinations: Nationwide | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    March 25, 2016 CX-100584 Categorical Exclusion Determination Data Collection and Comparison with Forecasted Sales of Five Lamp Types RIN NA CX(s) Applied: A6 EERE-Buildings ...

  8. Categorical Exclusion Determinations: Massachusetts | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    December 3, 2015 CX-100413 Categorical Exclusion Determination The French Modular Impoundment Award Number: DE-FOA-0007244 CX(s) Applied: A9, B3.6 Wind and Water Power Technologies ...

  9. CX-012121: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Notice of Preliminary Determination of Energy Savings for ANSI/ASHRAE/IES Standard 90.1-2013 CX(s) Applied: A6 Date: 04/25/2014 Location(s): CX: none Offices(s): Golden Field Office

  10. CX-004264: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Phase II, Determination of Uranium in GroundwaterCX(s) Applied: B3.8Date: 09/27/2010Location(s): Richland, WashingtonOffice(s): Environmental Management, Office of River Protection-Richland Office

  11. Gender determination of avian embryo

    DOE Patents [OSTI]

    Daum, Keith A.; Atkinson, David A.

    2002-01-01

    Disclosed is a method for gender determination of avian embryos. During the embryo incubation process, the outer hard shells of eggs are drilled and samples of allantoic fluid are removed. The allantoic fluids are directly introduced into an ion mobility spectrometer (IMS) for analysis. The resulting spectra contain the relevant marker peaks in the positive or negative mode which correlate with unique mobilities which are sex-specific. This way, the gender of the embryo can be determined.

  12. Nitrogen Oxides in the Nocturnal Boundary Layer: Chemistry of Nitrous Acid (HONO) and the Nitrate Radical (N03)

    SciTech Connect (OSTI)

    Jochen Stutz

    2005-05-24

    Summary Chemical processes occurring at night in the lowest part of the urban atmosphere, the so called nocturnal boundary layer (NBL), can influence the composition of the atmosphere during the night as well as the following day. They may impact the budgets of some of the most important pollutants, such as ozone and nitrogen oxides, as well as influence size and composition of particular matter. Few studies have thus far concentrated on the nocturnal chemistry of the urban NBL, most likely due to the strong influence of vertical transport and mixing, which requires the measurement of trace gas profiles instead of simple point observations. Motivated by our lack of observations and understanding of nocturnal chemistry, the focus of this project was the study of the vertical distribution of trace gases and the altitude dependence of nocturnal chemistry under polluted conditions through field observations and modeling studies. The analysis of three field experiments (TEXAQS, Houston, 2000; Phoenix Sunrise Ozone Experiment, 2001; NAPOX, Boston, 2002), two of which were performed in this project, showed that ozone concentrations typically increase with height in the lowest 150m, while NO2 typically decreases. NO3, the dominant nocturnal radical species, showed much higher concentrations in the upper part of the NBL, and was often not present at the ground. With the help of a one-dimensional chemical transport model, developed in this project, we found that the interaction of ground emissions of NOx and hydrocarbons, together with their vertical transport, is responsible for the vertical profiles. The dominant chemical reactions influencing ozone, NO2 and NO3 are the reaction of ozone and NO3 with freshly emitted NO. Sensitivity studies with our model showed that the magnitude of the trace gas gradients depend both on the emission rates and the vertical stability of the NBL. Observations and model analysis clearly show that nocturnal chemistry in urban areas is altitude dependent. Measurements at one altitude, for example at the ground, where most air quality monitoring stations are located, are not representative for the rest of the NBL. Our model also revealed that radical chemistry is, in general, altitude dependent at night. We distinguish three regions: an unreactive, NO rich, ground layer; an upper, O3 and NO3 dominated layer, and a reactive mixing layer, where RO2 radicals are mixed from aloft with NO from the ground. In this reactive layer an active radical chemistry and elevated OH radical levels can be found. The downward transport of N2O5 and HO2NO2, followed by their thermal decay, was also identified as a radical source in this layer. Our observations also gave insight into the formation of HONO in the NBL. Based on our field experiments we were able to show that the NO2 to HONO conversion was relative humidity dependent. While this fact was well known, we found that it is most likely the uptake of HONO onto surfaces which is R.H. dependent, rather than the NO2 to HONO conversion. This finding led to the proposal of a new NO2 to HONO conversion mechanism, which is based on solid physical chemical principles. Noteworthy is also the observation of enhanced NO2 to HONO conversion during a dust storm event in Phoenix. The final activity in our project investigated the influence of the urban canopy, i.e. building walls and surfaces, on nocturnal chemistry. For the first time the surface area of a city was determined based on a Geographical Information System database of the city of Santa Monica. The surface to volume areas found in this study showed that, in the 2 lower part of the NBL, buildings provide a much larger surface area than the aerosol. In addition, buildings take up a considerable amount of the volume near the ground. The expansion of our model and sensitivity studies based on the Santa Monica data revealed that the surface area of buildings considerably influences HONO levels in urban areas. The volume reduction leads to a decrease of O3 and an increase of NO2 near the ground due to the stronger impact of NO emissions. Our project shows that the urban canopy should be included in future air quality models to better represent nocturnal chemistry. This project has considerably advanced our understanding of the chemistry of the urban nocturnal boundary layer. The results of this project have implications for air quality studies in the urban nocturnal boundary layer. The study has also identified new questions on nocturnal processes, which we will continue to address through other projects.

  13. A Study Plan for Determining Recharge Rates at the Hanford Site Using Environmental Tracers

    SciTech Connect (OSTI)

    Murphy,, E. M.; Szecsody,, J. E.; Phillips,, S. J.

    1991-02-01

    This report presents a study plan tor estimating recharge at the Hanford Site using environmental tracers. Past operations at the Hanford Site have led to both soil and groundwater contamination, and recharge is one of the primary mechanisms for transporting contaminants through the vadose zone and into the groundwater. The prediction of contaminant movement or transport is one aspect of performance assessment and an important step in the remedial investigation/feasibility study (RI/FS) process. In the past, recharge has been characterized by collecting lysimeter data. Although lysimeters can generate important and reliable data, their limitations include 1) fixed location, 2) fixed sediment contents, 3) edge effects, 4) low rates, and 5) relatively short duration of measurement. These limitations impact the ability to characterize the spatial distribution of recharge at the Hanford Site, and thus the ability to predict contaminant movement in the vadose zone. An alternative to using fixed lysimeters for determining recharge rates in the vadose zone is to use environmental tracers. Tracers that have been used to study water movement in the vadose zone include total chloride, {sup 36}CI, {sup 3}H, and {sup 2}H/{sup 18}O. Atmospheric levels of {sup 36}CI and {sup 3}H increased during nuclear bomb testing in the Pacific, and the resulting "bomb pulse" or peak concentration can be measured in the soil profile. Locally, past operations at the Hanford Site have resu~ed in the atmospheric release of numerous chemical and isotopic tracers, including nitrate, {sup 129}I, and {sup 99}Tc. The radionuclides, in particular, reached a well-defined atmospheric peak in 1945. Atmospheric releases of {sup 129}I and {sup 99}Tc were greatly reduced by mid-1946, but nitrogen oxides continued to be released from the uranium separations facilities. As a result, the nitrate concentrations probably peaked in the mid-1950s, when the greatest number of separations facilities were operating. Seven study sites on the Hanford Site have been selected, in two primary soil types that are believed to represent the extremes in recharge, the Quincy sand and the Warden silt loam. An additional background study site upwind of the Hanford facilities has been chosen at the Yakima Firing Center. Study sites at Hanford were chosen close to micrometeorology stations on downwind transects from the operational facilities. Initial testing will be done on sites that lack perennial vegetation. Six tracer techniques (total chlortde, {sup 36}Cl, {sup 3}H, nitrate, {sup 129}I, and {sup 99}Tc) will be tested on at least one site in the Quincy sand, one site in the Warden si~ loam, and the background site, to determine which combination of tracers wortks best for a given soil type. In subsequent years, additional sites will be investigated to determine the effect of vegetation on recharge estimates and on the performance of individual tracers. The use of environmental tracers is perhaps the only cost-effective method for estimating the spatial vartability of recharge at a site as large as Hanford. The tracer techniques used at Hanford have wide applicability at other and sites operated by the U.S. Department of Energy as well as at low-level radioactive waste disposal sites.

  14. 100 MWe Baseload Molten Salt Plant Phase 1 & 2 Summary Report: Summary of Conceptual Design, Preliminary Design, Commercialization and Risk Reduction Activities

    SciTech Connect (OSTI)

    Tyner, Craig; Kraft, Dave; Moursund, Carter; Santelmann, Ken; Greaney, Andy; Zillmer, Andrew; Heap, Andy; Sakadjian, Bartev; Hannemann, Chris; Rogers, Dale; Gross, David; Wasyluk, David; Fondriest, Ed; Soni, Gaurav; Bindra, Hitesh; Marshall, Jason; Risner, Jeremy; Pacheco, Jim; Martin, Joe; Montesano, Kevin; Foder, Matt; Zavodny, Maximillian; Slack, Mike; Donnellan, Nathan; Sage, William

    2012-11-27

    This document describes steps taken to develop our conceptual and preliminary designs of a modular concept for deploying a 75% capacity factor, 100-MWe solar power plant. The modular approach consists of 14 solar power towers interconnected by hot and cold salt piping leading back to a central power block where the salt storage tanks and power generation systems are located. The plant is described in several sections. First, the overall plant is described, including the general arrangement, process and heat flow diagrams, system interface definitions, and electrical description. Next, each system is described in detail following the flow of energy from incident sunlight, through the plant, to the grid. These systems include the solar collector system (SCS), solar receiver system (SRS), thermal storage system (TSS), steam generator system (SGS), and power generation system (PGS). Then, the plant control system (PCS) and balance of plant (BOP) are discussed as supporting entities. Each system of the plant is described in sufficient detail to allow for the following to be developed: material cost, erection cost, project schedule, EPC bids, detailed performance modeling, and operations and maintenance cost. Cost, schedule, and performance estimates are not described in this document. Two approaches to demonstration of the technology are presented: a single tower integrated into an existing power block and a four tower stand alone 50 MWe power plant. Various demonstration partners have expressed interested in both approaches. The process by which a detailed plant performance model was developed is described to support the development of accurate LCOE data. Information on material and instrument testing is also provided for critical materials and instruments required for molten salt service.

  15. MEANS FOR DETERMINING CENTRIFUGE ALIGNMENT

    DOE Patents [OSTI]

    Smith, W.Q.

    1958-08-26

    An apparatus is presented for remotely determining the alignment of a centrifuge. The centrifage shaft is provided with a shoulder, upon which two followers ride, one for detecting radial movements, and one upon the shoulder face for determining the axial motion. The followers are attached to separate liquid filled bellows, and a tube connects each bellows to its respective indicating gage at a remote location. Vibrations produced by misalignment of the centrifuge shaft are transmitted to the bellows, and tbence through the tubing to the indicator gage. This apparatus is particularly useful for operation in a hot cell where the materials handled are dangerous to the operating personnel.

  16. Categorical Exclusion Determinations: Health, Safety, and Security...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Health, Safety, and Security Categorical Exclusion Determinations: Health, Safety, and Security Categorical Exclusion Determinations issued by Health, Safety, and Security. ...

  17. Categorical Exclusion Determinations: Civilian Radioactive Waste...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Civilian Radioactive Waste Management Categorical Exclusion Determinations: Civilian Radioactive Waste Management Categorical Exclusion Determinations issued by Civilian ...

  18. CX-100267 Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Exclusion Determination CX-100267 Categorical Exclusion Determination Next Generation Logistics Systems for Delivering Optimal Biomass Feedstocks to Biorefining Industries in...

  19. Categorical Exclusion Determinations: Strategic Petroleum Reserve...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Strategic Petroleum Reserve Field Office Categorical Exclusion Determinations: Strategic Petroleum Reserve Field Office Categorical Exclusion Determinations issued by Strategic ...

  20. CX-100144 Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Exclusion Determination CX-100144 Categorical Exclusion Determination Solar and Distributed Generation as Key Elements in Meeting Vermont's Comprehensive Energy Plan...

  1. Categorical Exclusion Determinations: Office of Electricity Delivery...

    Office of Environmental Management (EM)

    Electricity Delivery and Energy Reliability Categorical Exclusion Determinations: Office of Electricity Delivery and Energy Reliability Categorical Exclusion Determinations issued ...

  2. CX-100363 Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Exclusion Determination CX-100363 Categorical Exclusion Determination Marine Algae Industrialization Consortium (MAGIC): Combining biofuel and high-value bioproducts to...

  3. Categorical Exclusion Determinations: Natural Gas Regulation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Natural Gas Regulation Categorical Exclusion Determinations: Natural Gas Regulation Categorical Exclusion Determinations issued by Natural Gas Regulation. DOCUMENTS AVAILABLE FOR ...

  4. Adjudicative Guidelines for Determining Eligibility for Access...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Adjudicative Guidelines for Determining Eligibility for Access to Classified Information Adjudicative Guidelines for Determining Eligibility for Access to Classified Information ...

  5. Categorical Exclusion Determinations: Carlsbad Field Office ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Carlsbad Field Office Categorical Exclusion Determinations: Carlsbad Field Office Categorical Exclusion Determinations issued by Carlsbad Field Office. DOCUMENTS AVAILABLE FOR ...

  6. Categorical Exclusion Determinations: Energy Technology Engineering...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Technology Engineering Center Categorical Exclusion Determinations: Energy Technology Engineering Center Categorical Exclusion Determinations issued by Energy Technology ...

  7. Plasma digital density determining device

    DOE Patents [OSTI]

    Sprott, Julien C.; Lovell, Thomas W.; Holly, Donald J.

    1976-01-01

    The density of a decaying plasma in an electrically conducting enclosure is determined by applying an excitation to the cavity formed by the enclosure and counting digitally the number of resonant frequencies traversed by the combination of the cavity and the decaying plasma.

  8. CX-002602: Categorical Exclusion Determination

    Office of Energy Efficiency and Renewable Energy (EERE)

    Determining Optimal Fuel Performance in Adapting Onsite Electrical Generation Platforms to Operate on Producer Gas from Fuels of OpportunityCX(s) Applied: A9, A11Date: 12/11/2009Location(s): Minneapolis, MinnesotaOffice(s): Energy Efficiency and Renewable Energy, National Energy Technology Laboratory

  9. CX-002600: Categorical Exclusion Determination

    Office of Energy Efficiency and Renewable Energy (EERE)

    Determining Optimal Fuel Performance in Adapting Onsite Electrical Generation Platforms to Operate on Producer Gas from Fuels of OpportunityCX(s) Applied: B3.6Date: 12/11/2009Location(s): Minneapolis, MinnesotaOffice(s): Energy Efficiency and Renewable Energy, National Energy Technology Laboratory

  10. CX-002599: Categorical Exclusion Determination

    Office of Energy Efficiency and Renewable Energy (EERE)

    Determining Optimal Fuel Performance in Adapting Onsite Electrical Generation Platforms to Operate on Producer Gas from Fuels of OpportunityCX(s) Applied: B3.6Date: 12/11/2009Location(s): Berkeley, CaliforniaOffice(s): Energy Efficiency and Renewable Energy, National Energy Technology Laboratory

  11. CX-002598: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Determining Optimal Fuel Performance in Adapting Onsite Electrical Generation Platforms to Operate on Producer Gas from Fuels of OpportunityCX(s) Applied: B3.6Date: 12/11/2009Location(s): Morris, MinnesotaOffice(s): Energy Efficiency and Renewable Energy, National Energy Technology Laboratory

  12. CX-002601: Categorical Exclusion Determination

    Office of Energy Efficiency and Renewable Energy (EERE)

    Determining Optimal Fuel Performance in Adapting Onsite Electrical Generation Platforms to Operate on Producer Gas from Fuels of OpportunityCX(s) Applied: B3.6Date: 12/11/2009Location(s): Fridley, MinnesotaOffice(s): Energy Efficiency and Renewable Energy, National Energy Technology Laboratory

  13. CX-011193: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Categorical Exclusion Determination for Indoor, Small- and Pilot-Scale Research and Development CX(s) Applied: A9, B1.7, B3.6, B3.10, B3.12, B3.15, B5.1, B5.15 Date: 08/05/2013 Location(s): California Offices(s): Berkeley Site Office

  14. CX-008738: Categorical Exclusion Determination

    Office of Energy Efficiency and Renewable Energy (EERE)

    Determination of Microstructure and Chemical State Changes in Ion-Irradiated Fuels and Structural Components with a High Kinetic Energy Electron Detector – Illinois Institute of Technology CX(s) Applied: B3.6 Date: 05/22/2012 Location(s): Idaho Offices(s): Idaho Operations Office

  15. CX-013440: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Record of Categorical Exclusion Determination to Replace Piping Header at Bryan Mound RWIS and RWIP (BM-MM-1027) CX(s) Applied: B1.3Date: 02/18/2015 Location(s): TexasOffices(s): Strategic Petroleum Reserve Field Office

  16. CX-000373: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Measurements of 222 Radon, 220 Radon, and Carbon Dioxide Emissions in Natural Carbon Dioxide Fields in Wyoming: Monitoring, Verification, and Analysis Techniques for Determining Gas Transport and Caprock IntegrityCX(s) Applied: A1, A9, B3.6, B3.8Date: 11/20/2009Location(s): Laramie, WyomingOffice(s): Fossil Energy, National Energy Technology Laboratory

  17. CX-100312 Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Withdrawal of Proposed Determination Regarding Energy Conservation Program: Natural Draft Commercial Boilers RIN: 1904-AD01 CX(s) Applied: A5 EERE- Buildings Technology Program Date: 07/20/2015 Location(s): Nationwide Office(s): Golden Field Office

  18. CX-012693: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Experimental Determination and Mechanistic Modeling of Used Fuel Drying by Vacuum and Gas Circulation for Dry Cask Storage University of South Carolina CX(s) Applied: B3.6Date: 41869 Location(s): South CarolinaOffices(s): Nuclear Energy

  19. CX-100019: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Determination of Rare Earths in Geothermal Brines and Evaluation of Potential Extraction Techniques CX(s) Applied: A9, B3.1, B3.6 Date: 08/18/2014 Location(s): California Offices(s): Golden Field Office Technology Office: Geothermal Technologies Award Number: DE-EE0006750

  20. CX-100558 Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Final Determination of Coverage for Portable Air Conditioners (1904-AD02) RIN 1904-AD02 CX(s) Applied: A6 EERE-Buildings Technology Program Date: 03/03/2016 Location(s): Nationwide Office(s): Golden Field Office

  1. Remediated Nitrate Salt Drums Background

    Office of Environmental Management (EM)

    Reliability Considerations from the Integration of Smart Grid 116-390 Village Blvd., Princeton, NJ 08540 609.452.8060 | 609.452.9550 fax www.nerc.com the reliability of the to ensure bulk power system December 2010 (This page intentionally left blank) to ensure the reliability of the bulk power system Reliability Considerations of Integration of Smart Grid i December 2010 N N E E R R C C ' ' s s M M i i s s s s i i o o n n The North American Electric Reliability Corporation (NERC) is an

  2. Range determination for scannerless imaging

    DOE Patents [OSTI]

    Muguira, Maritza Rosa; Sackos, John Theodore; Bradley, Bart Davis; Nellums, Robert

    2000-01-01

    A new method of operating a scannerless range imaging system (e.g., a scannerless laser radar) has been developed. This method is designed to compensate for nonlinear effects which appear in many real-world components. The system operates by determining the phase shift of the laser modulation, which is a physical quantity related physically to the path length between the laser source and the detector, for each pixel of an image.

  3. Method for determining gene knockouts

    DOE Patents [OSTI]

    Maranas, Costa D; Burgard, Anthony R; Pharkya, Priti

    2013-06-04

    A method for determining candidates for gene deletions and additions using a model of a metabolic network associated with an organism, the model includes a plurality of metabolic reactions defining metabolite relationships, the method includes selecting a bioengineering objective for the organism, selecting at least one cellular objective, forming an optimization problem that couples the at least one cellular objective with the bioengineering objective, and solving the optimization problem to yield at least one candidate.

  4. Method for determining gene knockouts

    DOE Patents [OSTI]

    Maranas, Costas D.; Burgard, Anthony R.; Pharkya, Priti

    2011-09-27

    A method for determining candidates for gene deletions and additions using a model of a metabolic network associated with an organism, the model includes a plurality of metabolic reactions defining metabolite relationships, the method includes selecting a bioengineering objective for the organism, selecting at least one cellular objective, forming an optimization problem that couples the at least one cellular objective with the bioengineering objective, and solving the optimization problem to yield at least one candidate.

  5. Liquid chromatographic determination of water

    DOE Patents [OSTI]

    Fortier, Nancy E.; Fritz, James S.

    1990-11-13

    A sensitive method for the determination of water in the presence of common interferences is presented. The detection system is based on the effect of water on the equilibrium which results from the reaction aryl aldehydes, such as cinnamaldehyde and methanol in the eluent to form cinnamaldehyde dimethylacetal, plus water. This equilibrium is shifted in a catalytic atmosphere of a hydrogen ion form past column reactor. The extent of the shift and the resulting change in absorbance are proportional to the amount of water present.

  6. Liquid chromatographic determination of water

    DOE Patents [OSTI]

    Fortier, N.E.; Fritz, J.S.

    1990-11-13

    A sensitive method for the determination of water in the presence of common interferences is presented. The detection system is based on the effect of water on the equilibrium which results from the reaction aryl aldehydes, such as cinnamaldehyde and methanol in the eluent to form cinnamaldehyde dimethylacetal, plus water. This equilibrium is shifted in a catalytic atmosphere of a hydrogen ion form past column reactor. The extent of the shift and the resulting change in absorbance are proportional to the amount of water present. 1 fig.

  7. RECORD OF CATEGORICAL EXCLUSION DETERMINATION

    Energy Savers [EERE]

    geological boring near 9 structure locations along the existing ED2-ED5 230-kV transmission line located in Pinal County, Arizona RECORD OF CATEGORICAL EXCLUSION DETERMINATION A, Proposed Action: Western proposes to do geologic borings within our right-of-way near structures 21/5,22/5,23/6,25/4,26/5,27/6,28/5,29/5 & 30/4 along the existing ED2-ED5 230-kV transmission line. This project involves accessing each bore hole location with a auger/drill rig and light crew trucks, setting up the

  8. Crystal face temperature determination means

    DOE Patents [OSTI]

    Nason, D.O.; Burger, A.

    1994-11-22

    An optically transparent furnace having a detection apparatus with a pedestal enclosed in an evacuated ampule for growing a crystal thereon is disclosed. Temperature differential is provided by a source heater, a base heater and a cold finger such that material migrates from a polycrystalline source material to grow the crystal. A quartz halogen lamp projects a collimated beam onto the crystal and a reflected beam is analyzed by a double monochromator and photomultiplier detection spectrometer and the detected peak position in the reflected energy spectrum of the reflected beam is interpreted to determine surface temperature of the crystal. 3 figs.

  9. Project Profile: Encapsulated Phase Change Material in Thermal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    in Thermal Storage for Baseload CSP Plants Project Profile: Encapsulated Phase Change Material in Thermal Storage for Baseload CSP Plants Terrafore logo Terrafore, under the ...

  10. Project Profile: Innovative Phase Change Thermal Energy Storage...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Phase Change Thermal Energy Storage Solution for Baseload Power Project Profile: Innovative Phase Change Thermal Energy Storage Solution for Baseload Power Infinia logo Infinia, ...

  11. Using Encapsulated Phase Change Material for Thermal Energy Storage...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Encapsulated Phase Change Material for Thermal Energy Storage for Baseload CSP Using Encapsulated Phase Change Material for Thermal Energy Storage for Baseload CSP This ...

  12. Determination of a mutational spectrum

    DOE Patents [OSTI]

    Thilly, William G.; Keohavong, Phouthone

    1991-01-01

    A method of resolving (physically separating) mutant DNA from nonmutant DNA and a method of defining or establishing a mutational spectrum or profile of alterations present in nucleic acid sequences from a sample to be analyzed, such as a tissue or body fluid. The present method is based on the fact that it is possible, through the use of DGGE, to separate nucleic acid sequences which differ by only a single base change and on the ability to detect the separate mutant molecules. The present invention, in another aspect, relates to a method for determining a mutational spectrum in a DNA sequence of interest present in a population of cells. The method of the present invention is useful as a diagnostic or analytical tool in forensic science in assessing environmental and/or occupational exposures to potentially genetically toxic materials (also referred to as potential mutagens); in biotechnology, particularly in the study of the relationship between the amino acid sequence of enzymes and other biologically-active proteins or protein-containing substances and their respective functions; and in determining the effects of drugs, cosmetics and other chemicals for which toxicity data must be obtained.

  13. NREL: Climate Neutral Research Campuses - Determine Baseline...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Determine Baseline Energy Consumption To create a climate action plan for your research campus, begin by determining current energy consumption and the resulting greenhouse gas ...

  14. Categorical Exclusion Determinations: Pantex Site Office | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    March 18, 2015 CX-013480: Categorical Exclusion Determination Lightning Mapping Array ... December 27, 2013 CX-011714: Categorical Exclusion Determination Lightning Mapping Array ...

  15. Categorical Exclusion Determinations: West Valley Demonstration...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    September 8, 2011 CX-009529: Categorical Exclusion Determination WVDP-2011-01 Erdman Brook ... September 8, 2011 CX-006811: Categorical Exclusion Determination Erdman Brook Erosion ...

  16. Categorical Exclusion Determinations: Office of Energy Efficiency...

    Office of Environmental Management (EM)

    Energy Efficiency and Renewable Energy Categorical Exclusion Determinations: Office of Energy Efficiency and Renewable Energy Categorical Exclusion Determinations issued by Energy ...

  17. Determinations and Coverage Rulemakings | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Determinations and Coverage Rulemakings Determinations and Coverage Rulemakings The Energy Policy and Conservation Act (EPCA) (42 U.S.C. 6292(a)) contains a list of 19 consumer ...

  18. CX-011104: Categorical Exclusion Determination | Department of...

    Energy Savers [EERE]

    Coupled Thermo-Mechanical and Photo-Chemical Degradation Mechanisms that Determine ... coupled thermo-mechanical and photo-chemical degradation mechanisms that determine ...

  19. CX-007095: Categorical Exclusion Determination | Department of...

    Office of Environmental Management (EM)

    Determination CX-007095: Categorical Exclusion Determination Paving the Way with Propane: The AutoGas Corridor Development Program CX(s) Applied: B5.1 Date: 10132011...

  20. CX-007096: Categorical Exclusion Determination | Department of...

    Office of Environmental Management (EM)

    Determination CX-007096: Categorical Exclusion Determination Paving the Way with Propane: The AutoGas Corridor Development Program CX(s) Applied: B5.1 Date: 10132011...

  1. CX-011970: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Exclusion Determination CX-011970: Categorical Exclusion Determination Tuscarora Phase II Geothermal Observation Wells CX(s) Applied: B3.7 Date: 02222013 Location(s):...

  2. CX-001087: Categorical Exclusion Determination | Department of...

    Office of Environmental Management (EM)

    87: Categorical Exclusion Determination CX-001087: Categorical Exclusion Determination State of Nevada Energy Efficiency and Conservation Block Grant - American Recovery and...

  3. CX-006491: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Categorical Exclusion Determination CX-006491: Categorical Exclusion Determination Photovoltaic Manufacturing Consortium CX(s) Applied: B3.6 Date: 09012011 Location(s): Florida...

  4. CX-007867: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Exclusion Determination CX-007867: Categorical Exclusion Determination Northeast Photovoltaic Regional Training Provider CX(s) Applied: A9, A11, B5.16 Date: 01272012...

  5. Categorical Exclusion Determinations: Florida | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    September 16, 2015 CX-100377 Categorical Exclusion Determination US-INDIA CONSORTIUM FOR ... September 8, 2015 CX-100367 Categorical Exclusion Determination US-India Consortium for ...

  6. CX-003164: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Categorical Exclusion Determination CX-003164: Categorical Exclusion Determination Optimization of Biomass Production Across a Landscape CX(s) Applied: A9 Date: 07262010...

  7. CX-004247: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Exclusion Determination CX-004247: Categorical Exclusion Determination Carolina Blue Skies Initiative CX(s) Applied: A1, B5.1 Date: 10142010 Location(s): Indian Trail,...

  8. CX-008810: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Exclusion Determination CX-008810: Categorical Exclusion Determination One Nevada Optimization of Microwave Telecommunication System CX(s) Applied: B1.19, B4.6 Date: 05292012...

  9. Categorical Exclusion Determinations: Kentucky | Department of...

    Office of Environmental Management (EM)

    ... May 14, 2013 CX-010281: Categorical Exclusion Determination Low Temperature Nitrous Oxide ... Determination Cost-Effective Treatment of Flowback and Produced Water via an ...

  10. Crystal face temperature determination means

    DOE Patents [OSTI]

    Nason, Donald O.; Burger, Arnold

    1994-01-01

    An optically transparent furnace (10) having a detection apparatus (29) with a pedestal (12) enclosed in an evacuated ampule (16) for growing a crystal (14) thereon. Temperature differential is provided by a source heater (20), a base heater (24) and a cold finger (26) such that material migrates from a polycrystalline source material (18) to grow the crystal (14). A quartz halogen lamp (32) projects a collimated beam (30) onto the crystal (14) and a reflected beam (34) is analyzed by a double monochromator and photomultiplier detection spectrometer (40) and the detected peak position (48) in the reflected energy spectrum (44) of the reflected beam (34) is interpreted to determine surface temperature of the crystal (14).

  11. Novel imaging techniques, integrated with mineralogical, geochemical and microbiological characterizations to determine the biogeochemical controls on technetium mobility in FRC sediments

    SciTech Connect (OSTI)

    Jonathan R. Lloyd

    2009-02-03

    The objective of this research program was to take a highly multidisciplinary approach to define the biogeochemical factors that control technetium (Tc) mobility in FRC sediments. The aim was to use batch and column studies to probe the biogeochemical conditions that control the mobility of Tc at the FRC. Background sediment samples from Area 2 (pH 6.5, low nitrate, low {sup 99}Tc) and Area 3 (pH 3.5, high nitrate, relatively high {sup 99}Tc) of the FRC were selected (http://www.esd.ornl.gov/nabirfrc). For the batch experiments, sediments were mixed with simulated groundwater, modeled on chemical constituents of FRC waters and supplemented with {sup 99}Tc(VII), both with and without added electron donor (acetate). The solubility of the Tc was monitored, alongside other biogeochemical markers (nitrate, nitrite, Fe(II), sulfate, acetate, pH, Eh) as the 'microcosms' aged. At key points, the microbial communities were also profiled using both cultivation-dependent and molecular techniques, and results correlated with the geochemical conditions in the sediments. The mineral phases present in the sediments were also characterized, and the solid phase associations of the Tc determined using sequential extraction and synchrotron techniques. In addition to the batch sediment experiments, where discrete microbial communities with the potential to reduce and precipitate {sup 99}Tc will be separated in time, we also developed column experiments where biogeochemical processes were spatially separated. Experiments were conducted both with and without amendments proposed to stimulate radionuclide immobilization (e.g. the addition of acetate as an electron donor for metal reduction), and were also planned with and without competing anions at high concentration (e.g. nitrate, with columns containing Area 3 sediments). When the columns had stabilized, as determined by chemical analysis of the effluents, we used a spike of the short-lived gamma emitter {sup 99m}Tc (50-200 MBq; half life 6 hours) and its mobility was monitored using a {gamma}-camera. Incorporation of low concentrations of the long-lived 99Tc gave a tracer that can be followed by scintillation counting, should the metastable form of the radionuclide decay to below detection limits before the end of the experiment (complete immobilization or loss of the Tc from the column). After the Tc was reduced and immobilized, or passed through the system, the columns were dismantled carefully in an anaerobic cabinet and the pore water geochemistry and mineralogy of the columns profiled. Microbial community analysis was determined, again using molecular and culture-dependent techniques. Experimental results were also modeled using an established coupled speciation and transport code, to develop a predictive tool for the mobility of Tc in FRC sediments. From this multidisciplinary approach, we hoped to obtain detailed information on the microorganisms that control the biogeochemical cycling of key elements at the FRC, and we would also be able to determine the key factors that control the mobility of Tc at environmentally relevant concentrations at this site.

  12. Ballistic projectile trajectory determining system

    DOE Patents [OSTI]

    Karr, T.J.

    1997-05-20

    A computer controlled system determines the three-dimensional trajectory of a ballistic projectile. To initialize the system, predictions of state parameters for a ballistic projectile are received at an estimator. The estimator uses the predictions of the state parameters to estimate first trajectory characteristics of the ballistic projectile. A single stationary monocular sensor then observes the actual first trajectory characteristics of the ballistic projectile. A comparator generates an error value related to the predicted state parameters by comparing the estimated first trajectory characteristics of the ballistic projectile with the observed first trajectory characteristics of the ballistic projectile. If the error value is equal to or greater than a selected limit, the predictions of the state parameters are adjusted. New estimates for the trajectory characteristics of the ballistic projectile are made and are then compared with actual observed trajectory characteristics. This process is repeated until the error value is less than the selected limit. Once the error value is less than the selected limit, a calculator calculates trajectory characteristics such a the origin and destination of the ballistic projectile. 8 figs.

  13. Ballistic projectile trajectory determining system

    DOE Patents [OSTI]

    Karr, Thomas J.

    1997-01-01

    A computer controlled system determines the three-dimensional trajectory of a ballistic projectile. To initialize the system, predictions of state parameters for a ballistic projectile are received at an estimator. The estimator uses the predictions of the state parameters to estimate first trajectory characteristics of the ballistic projectile. A single stationary monocular sensor then observes the actual first trajectory characteristics of the ballistic projectile. A comparator generates an error value related to the predicted state parameters by comparing the estimated first trajectory characteristics of the ballistic projectile with the observed first trajectory characteristics of the ballistic projectile. If the error value is equal to or greater than a selected limit, the predictions of the state parameters are adjusted. New estimates for the trajectory characteristics of the ballistic projectile are made and are then compared with actual observed trajectory characteristics. This process is repeated until the error value is less than the selected limit. Once the error value is less than the selected limit, a calculator calculates trajectory characteristics such a the origin and destination of the ballistic projectile.

  14. DOE ER63951-3 Final Report: An Integrated Assessment of Geochemical and Community Structure Determinants of Metal Reduction Rates in Subsurface Sediments

    SciTech Connect (OSTI)

    Susan Pfiffner

    2010-06-28

    The objective of this research was to examine the importance of microbial community structure in influencing uranium reduction rates in subsurface sediments. If the redox state alone is the key to metal reduction, then any organisms that can utilize the oxygen and nitrate in the subsurface can change the geochemical conditions so metal reduction becomes an energetically favored reaction. Thus, community structure would not be critical in determining rates or extent of metal reduction unless community structure influenced the rate of change in redox. Alternatively, some microbes may directly catalyze metal reduction (e.g., specifically reduce U). In this case the composition of the community may be more important and specific types of electron donors may promote the production of communities that are more adept at U reduction. Our results helped determine if the type of electron donor or the preexisting community is important in the bioremediation of metal-contaminated environments subjected to biostimulation. In a series of experiments at the DOE FRC site in Oak Ridge we have consistently shown that all substrates promoted nitrate reduction, while glucose, ethanol, and acetate always promoted U reduction. Methanol only occasionally promoted extensive U reduction which is possibly due to community heterogeneity. There appeared to be limitations imposed on the community related to some substrates (e.g. methanol and pyruvate). Membrane lipid analyses (phospholipids and respiratory quinones) indicated different communities depending on electron donor used. Terminal restriction fragment length polymorphism and clone libraries indicated distinct differences among communities even in treatments that promoted U reduction. Thus, there was enough metabolic diversity to accommodate many different electron donors resulting in the U bioimmobilization.

  15. 2015 Secretarial Determination | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Secretarial Determination 2015 Secretarial Determination On May 1, 2015, the Secretary of Energy determined that continued uranium transfers for cleanup services at the Portsmouth Gaseous Diffusion Plant and for down-blending of highly-enriched uranium to low-enriched uranium will not have an adverse material impact on the domestic uranium mining, conversion, or enrichment industry ("2015 Secretarial Determination"). This Determination covers continued transfers at the rates specified

  16. Categorical Exclusion Determinations: B1.36

    Broader source: Energy.gov [DOE]

    B1.36: Determinations of excess real propertyDeterminations that real property is excess to the needs of DOE and, in the case of acquired real property, the subsequent reporting of such...

  17. CX-004531: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Determination CX-004531: Categorical Exclusion Determination Surprise Valley Multiple Use Geothermal Development CX(s) Applied: A9, B3.1, B5.12 Date: 11242010 Location(s):...

  18. CX-100322 Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Exclusion Determination CX-100322 Categorical Exclusion Determination Plug and Play Photovoltaics for American Homes Award Number: DE-EE0006035 CX(s) Applied: A9, B3.6, B5.15...

  19. CX-100193 Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Exclusion Determination CX-100193 Categorical Exclusion Determination Installation of Solar Panels at Municipal Owned Facilities Award Number: DE-EE0003195 CX(s) Applied: B5.1...

  20. Categorical Exclusion Determinations: Intelligence and Counterintelligence

    Energy Savers [EERE]

    | Department of Energy Intelligence and Counterintelligence Categorical Exclusion Determinations: Intelligence and Counterintelligence Categorical Exclusion Determinations issued by Intelligence and Counterintelligence. DOCUMENTS AVAILABLE FOR DOWNLOAD No downloads found for this office.

  1. Categorical Exclusion Determinations: Western Area Power Administration |

    Energy Savers [EERE]

    Department of Energy Administration Categorical Exclusion Determinations: Western Area Power Administration Categorical Exclusion Determinations issued by Western Area Power Administration. DOCUMENTS AVAILABLE FOR DOWNLOAD No downloads found for this office.

  2. CX-100317 Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    7 Categorical Exclusion Determination CX-100317 Categorical Exclusion Determination Solar Hot Water Project in Greenburgh, NY Award Number: DE-EE0003193 CX(s) Applied: B5.16...

  3. Categorical Exclusion Determinations: Program and Field Offices |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Determinations: Program and Field Offices Categorical Exclusion Determinations: Program and Field Offices This page contains links (below) to pages on DOE Program, Field, or Site Office websites containing the CX determinations required to be posted under this policy, and also some for which documentation and posting are optional, i.e., determinations involving classes of actions listed in Appendix A or made before the policy's effective date of November 2, 2009. You may

  4. NREL Programmatic NEPA Determinations | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Programmatic NEPA Determinations NREL Programmatic NEPA Determinations The U.S. Department of Energy's (DOE) Office of Energy Efficiency and Renewable Energy has developed five Programmatic NEPA Determinations (PND) to address routine activities and ongoing research conducted at National Renewable Energy Laboratory (NREL) facilities. These determinations were conducted as part of a joint DOE and NREL NEPA Enhancement Project that was developed to help streamline the NEPA process for activities

  5. POLICY GUIDANCE MEMORANDUM #26 Official Worksite Determinations |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy 6 Official Worksite Determinations POLICY GUIDANCE MEMORANDUM #26 Official Worksite Determinations The following information is provided to assist in determinations of official worksites for remote workers. This guidance applies to Federal employees and employees hired under the Intergovernmental Personnel Act (IPA). PDF icon POLICY GUIDANCE MEMORANDUM #26 Official Worksite Determinations Responsible Contacts Ahtora Brooks Human Resource Specialists E-mail

  6. Categorical Exclusion Determinations: Oregon | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Recovery Act: Crump Geyser - High Precision Geophysics & ... Novel Hybrid Microbial Electrochemical System for Efficient ... Determination Microchannel Solar Receiver Development Award ...

  7. Categorical Exclusion Determinations: Advanced Technology Vehicles

    Energy Savers [EERE]

    Manufacturing Loan Program | Department of Energy Technology Vehicles Manufacturing Loan Program Categorical Exclusion Determinations: Advanced Technology Vehicles Manufacturing Loan Program Categorical Exclusion Determinations issued by Advanced Technology Vehicles Manufacturing Loan Program. DOCUMENTS AVAILABLE FOR DOWNLOAD September 6, 2011 CX-006488: Categorical Exclusion Determination Chrysler Group LLC, Revised Specific Project Application 2, Retooling, Reequipping and Engineering

  8. Categorical Exclusion Determinations: NNSA-Proliferation Detection |

    Energy Savers [EERE]

    Department of Energy Proliferation Detection Categorical Exclusion Determinations: NNSA-Proliferation Detection Categorical Exclusion Determinations issued by NNSA-Proliferation Detection. DOCUMENTS AVAILABLE FOR DOWNLOAD September 17, 2010 CX-004080: Categorical Exclusion Determination Fisk University Nonproliferation Grant CX(s) Applied: B3.6 Date: 09/17/2010 Location(s): Tennessee Office(s): NNSA-Proliferation Detection

  9. Categorical Exclusion Determinations: Southeastern Power Administration |

    Energy Savers [EERE]

    Department of Energy Southeastern Power Administration Categorical Exclusion Determinations: Southeastern Power Administration Categorical Exclusion Determinations issued by Southeastern Power Administration. DOCUMENTS AVAILABLE FOR DOWNLOAD August 3, 2009 CX-000478: Categorical Exclusion Determination Proposed rate adjustment for the Jim Woodruff System CX(s) Applied: B4.3 Date: 08/03/2009 Location(s): Panhandle, Florida Office(s): Southeastern Power Administration

  10. CX-100327 Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-100327 Categorical Exclusion Determination Proposed Rulemaking for Energy Conservation Standards for Commercial Water Heating Equipment RIN: 1904-AD34 CX(s)...

  11. CX-009019: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DEVELOPMENT AND FULL-SCALE TESTING CX-009001: Categorical Exclusion Determination Ammonia Sensors Based on Doped-Sol-Gel-Tipped Optical Fibers for Catalyst System Diagnostics

  12. Perlick: Noncompliance Determination (2013-SE-14001)

    Broader source: Energy.gov [DOE]

    DOE issued a Notice of Noncompliance Determination to Perlick Corporation finding that freezer basic model HP24F does not comport with the energy conservation standards.

  13. Perlick: Noncompliance Determination (2013-SE-14002)

    Broader source: Energy.gov [DOE]

    DOE issued a Notice of Noncompliance Determination to Perlick Corporation finding that refrigerator basic model HP48RR does not comport with the energy conservation standards.

  14. Hydac: Noncompliance Determination (2012-SE-4107)

    Broader source: Energy.gov [DOE]

    DOE issued a Notice of Noncompliance Determination to Hydac Technology Corporation finding that a variety of electric motor basic models do not comport with the energy conservation standards.

  15. Mueller Streamline: Noncompliance Determination (2011-SW-2802)

    Broader source: Energy.gov [DOE]

    DOE issued a Notice of Noncompliance Determination to Mueller Streamline Co. finding that faucet model 120-003NL does not comport with the water conservation standards.

  16. Whirlpool: Noncompliance Determination (2013-SE-1420)

    Broader source: Energy.gov [DOE]

    DOE issued a Notice of Noncompliance Determination to Whirlpool Corporation finding that refrigerator-freezer basic model 8TAR81 does not comport with the energy conservation standards.

  17. CX-010763: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-010763: Categorical Exclusion Determination Nevada Desert Research Institute- Photovoltaic Installation CX(s) Applied: B5.16 Date: 07172013 Location(s): Nevada Offices(s):...

  18. CX-003980: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-003980: Categorical Exclusion Determination Integration of Advanced Logistical Systems ... a comprehensive biomass supply chain system through collecting and deliver of ...

  19. Categorical Exclusion Determinations: Golden Field Office | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Categorical Exclusion Determination U.S. Department of Energy Collegiate Entrepreneurship Prize Award Number: TBD FOA CX(s) Applied: A9 Date: 12222014 Location(s): CO...

  20. CX-006520: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-006520: Categorical Exclusion Determination High Energy Density Distributed Hydrostatic Direct Drive for Large Wind Turbine and Marine Hydro-Kinetic Device Applications CX(s) ...

  1. CX-003608: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-003608: Categorical Exclusion Determination Sustainable Algal Energy Production and Environmental Remediation CX(s) Applied: A9, B3.6 Date: 08252010 Location(s): Virginia ...

  2. CX-006863: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-006863: Categorical Exclusion Determination Production ... Minnesota Office(s): Energy Efficiency and Renewable ... aims to establish a sustainable supply of ...

  3. CX-001627: Categorical Exclusion Determination | Department of...

    Office of Environmental Management (EM)

    CX-001627: Categorical Exclusion Determination Test Reactor Cask Implementation CX(s) ... This proposed action is a process and facility modification. The Advanced Test Reactor ...

  4. Methods for threshold determination in multiplexed assays

    DOE Patents [OSTI]

    Tammero, Lance F. Bentley; Dzenitis, John M; Hindson, Benjamin J

    2014-06-24

    Methods for determination of threshold values of signatures comprised in an assay are described. Each signature enables detection of a target. The methods determine a probability density function of negative samples and a corresponding false positive rate curve. A false positive criterion is established and a threshold for that signature is determined as a point at which the false positive rate curve intersects the false positive criterion. A method for quantitative analysis and interpretation of assay results together with a method for determination of a desired limit of detection of a signature in an assay are also described.

  5. Categorical Exclusion Determinations: Idaho | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... June 18, 2015 CX-013839: Categorical Exclusion Determination Materials and Fuels Complex (MFC)-752 Analytical Laboratory Casting Laboratory Glovebox Heat Detection CX(s) Applied: ...

  6. CX-008761: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-008761: Categorical Exclusion Determination Surface Water and Groundwater Sampling Near the Naturita, Colorado Title I Uranium Mill Tailings Radiation Control Act (UMTRCA) ...

  7. CX-100596 Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    by DOE under the Assisting Federal Facilities with Energy Conservation ... This conditional NEPA determination applies solely to preliminary design and project planning ...

  8. CX-100343 Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-100343 Categorical Exclusion Determination RPM Solar Asset Management Software Award ... Management to develop a cloud based software platform that manages the financial and ...

  9. CX-000321: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-000321: Categorical Exclusion Determination Kentucky Revision 2 - Green and Healthy ...232009 Location(s): Kentucky Office(s): Energy Efficiency and Renewable Energy, National ...

  10. CX-000322: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-000322: Categorical Exclusion Determination Kentucky Revision 2 - Green Bank of Kentucky Date: 11232009 Location(s): Kentucky Office(s): Energy Efficiency and Renewable ...

  11. Categorical Exclusion Determinations: National Energy Technology...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Laboratory September 9, 2014 CX-012155: Categorical Exclusion Determination Subsea High Voltage Direct Current Connectors for Environmentally Safe and Reliable Powering of UDW... ...

  12. CX-004649: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The Painesville Municipal Power Vanadium Redox Battery Demonstration Program CX(s) ... CX-006145: Categorical Exclusion Determination Fact Sheet: Vanadium Redox Battery ...

  13. Categorical Exclusion Determinations: Oklahoma | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... June 17, 2013 CX-010520: Categorical Exclusion Determination Silica Polymer Initiator ... PetrophysicsTight Rock Characterization for Improved Stimulation and Production ...

  14. Felix Storch: Noncompliance Determination (2010-SCE-0111)

    Broader source: Energy.gov [DOE]

    DOE issued a Notice of Noncompliance Determination to Felix Storch finding that basic model FS62, a compact upright freezer, does not comport with the energy conservation standards.

  15. Morris: Noncompliance Determination (2013-SE-5403)

    Broader source: Energy.gov [DOE]

    DOE issued a Notice of Noncompliance Determination to Morris Products, Inc. finding that various models of metal halide lamp fixtures do not comport with the energy conservation standards.

  16. CX-006211: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Exclusion Determination Missouri Independent Energy Efficiency Program: Henniges Automotive - Process Air Compressor Upgrades CX(s) Applied: B5.1 Date: 07182011 Location(s):...

  17. CX-013404: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-013404: Categorical Exclusion Determination NARUCDOE Natural Gas Infrastructure and Liquefied Natural Gas Partnership CX(s) Applied: A9, A11 Date: 02092015 Location(s): ...

  18. CX-000294: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-000294: Categorical Exclusion Determination A Novel Biogas Desulphurization Sorbent ... gas, providing an essentially sulfur-free biogas for Direct Fuel Cell? power plants. ...

  19. CX-000293: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-000293: Categorical Exclusion Determination A Novel Biogas Desulphurization Sorbent ... gas, providing an essentially sulfur-free biogas for Direct Fuel Cell? power plants. ...

  20. CX-001856: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Exclusion Determination Rural Cooperative Geothermal Development Electric and Agriculture CX(s) Applied: B3.1 Date: 04282010 Location(s): Paisley, Oregon Office(s): Energy...

  1. Categorical Exclusion Determinations: Bonneville Power Administration...

    Energy Savers [EERE]

    Power Administration July 9, 2015 CX-013781: Categorical Exclusion Determination Acquisition of Multiple Access Road Easements for the Holcomb-Naselle No. 1 Transmission Line ...

  2. DNA Sequence Determinants Controlling Affinity, Stability and...

    Office of Scientific and Technical Information (OSTI)

    the Nucleoid Protein Fis Citation Details In-Document Search Title: DNA Sequence Determinants Controlling Affinity, Stability and Shape of DNA Complexes Bound by the Nucleoid ...

  3. CX-003703: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Determination Florida Hydrogen Initiative - Florida Institute of Technology (Interdisciplinary Hydrogen and Fuel Cell Technology Academic Program) CX(s) Applied: A9 Date: 09...

  4. CX-011250: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Determination Transforming Photovoltaic Installations Toward Dispatchable, Schedulable Energy Solutions CX(s) Applied: B3.6, B5.15 Date: 10172013 Location(s): Oregon...

  5. CX-100138 Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-100138 Categorical Exclusion Determination Sacrificial Protective Coating Materials ... a chemically resistant and anti-fouling coating for low-cost Weak Black Liquor (WBL) ...

  6. Categorical Exclusion Determinations: North Carolina | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Texas, Massachusetts Offices(s): Golden Field Office November 27, 2013 CX-011733: Categorical Exclusion Determination Research Triangle Institute - High Operating Temperature ...

  7. Zoe Industries: Noncompliance Determination (2011-SW-2912)

    Broader source: Energy.gov [DOE]

    DOE issued a Notice of Noncompliance Determination to Zoe Industries, Inc. finding that Giessdorf 150043 model, a showerhead, does not comport with the water conservation standards.

  8. Arelik A.?: Compliance Determination (2010-SE-0105)

    Broader source: Energy.gov [DOE]

    DOE issued a Notice of Compliance Determination after test results revealed that Arelik's Blomberg BRFB1450 refrigerator-freezer complies with the applicable energy conservation standards.

  9. Categorical Exclusion Determinations: Nuclear Energy | Department...

    Energy Savers [EERE]

    ... June 17, 2015 CX-013826: Categorical Exclusion Determination Assessment of Aging Degradation Mechanisms of Alloy 709 for Sodium Fast Reactors - Colorado School of Mines CX(s) ...

  10. CX-005301: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    wind turbine(s); conducting business and organizational planning to determine whether a wind-diesel plant is feasible; developing and conducting educational and informational...

  11. CX-006215: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-006215: Categorical Exclusion Determination Oklahoma State Energy Program American Recovery and Reinvestment Act - Oklahoma Department of Commerce Large System Application ...

  12. CX-006216: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-006216: Categorical Exclusion Determination Oklahoma State Energy Program American Recovery and Reinvestment Act - Oklahoma Municipal Power Authority Large System Request R ...

  13. CX-005432: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-005432: Categorical Exclusion Determination Oklahoma State Energy Program American Recovery and Reinvestment Act - Oklahoma Municipal Power Authority Large System Rebate Request ...

  14. CX-003838: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-003838: Categorical Exclusion Determination Demolition of the X-605 H Booster Pump ... The proposed action involves the demolition of the X-605 H Booster Pump House Building, ...

  15. ET Industries: Noncompliance Determination (2012-SE-2902)

    Broader source: Energy.gov [DOE]

    DOE issued a Notice of Noncompliance Determination to ET Industries, Inc. finding that showerhead basic model TH-1 does not comport with the water conservation standards.

  16. CX-009166: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-009166: Categorical Exclusion Determination Bioelectrochemical Integration of Waste Heat Recovery, Waste-to-Energy Conversion, and Waste-to-Chemical Conversion with Industrial ...

  17. Categorical Exclusion Determinations: New Jersey | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    August 1, 2014 CX-012497: Categorical Exclusion Determination Geophysical and Mineralogical Controls on the Rheology of Fracture Slip... CX(s) Applied: B3.6 Date: 41852 ...

  18. CX-002452: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Assessment of the Environmental Effects of Hydrokinetic Turbines on Fish CX(s) Applied: ... to determine injury and survival rates for fish passing through hydrokinetic turbines. ...

  19. CX-002506: Categorical Exclusion Determination | Department of...

    Energy Savers [EERE]

    CX-002506: Categorical Exclusion Determination Rhode Island Commercial and Industrial Energy Efficiency Initiative CX(s) Applied: A9, A11, B5.1 Date: 06012010...

  20. CX-010272: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-010272: Categorical Exclusion Determination Chesapeake Light Tower Survey, ... The U.S. Department of Energy's (DOE) National Renewable Energy Laboratory is proposing to ...

  1. CX-001068: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-001068: Categorical Exclusion Determination Analysis of Energy, Environmental, and Life Cycle Cost Reduction Potential of Ground Source Heat Pumps in Hot and Humid Climate CX(s) ...

  2. CX-010269: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-010269: Categorical Exclusion Determination Renewable Energy Initiatives for Clark ... The U.S. Department of Energy (DOE) is proposing to provide federal funding to the Clark ...

  3. CX-005846: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-005846: Categorical Exclusion Determination Wood Pole Replacement and Minor Access Road Maintenance Along Various Transmission Line Rights-Of-Way in the Wenatchee District CX(s) ...

  4. CX-100229 Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-100229 Categorical Exclusion Determination Center for Ocean Renewable Energy (CORE) ... of New Hampshire (UNH) Center for Ocean Renewable Energy (CORE) to develop a tidal ...

  5. Categorical Exclusion Determinations: Missouri | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    March 7, 2016 CX-100535 Categorical Exclusion Determination Large Scale GSHP as Alternative Energy for American Farmers: Technical Demonstration & Business Approach Award Number: ...

  6. CX-004656: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-004656: Categorical Exclusion Determination Small Wind Turbine Regional Test Center - Otisco, New York; National Renewable Energy Laboratory Tracking Number 10-028 CX(s) ...

  7. Electrolux: Compliance Determination (2010-SE-0108)

    Broader source: Energy.gov [DOE]

    After conducting testing of Electrolux's Frigidaire chest freezer model FFN09M5HWC, DOE determined that the model met the applicable energy conservation standard.

  8. Vitrification Melter Waste Incidental to Reprocessing Determination...

    Office of Environmental Management (EM)

    Reprocessing Determination For The West Valley Demonstration Project Concentrator Feed Makeup Tank and Melter Feed Hold Tank Responses to Public Comments on Draft Vitrification...

  9. CX-007901: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-007901: Categorical Exclusion Determination Improving Atmospheric Models for Offshore Wind Resource Mapping and Prediction Using LIDAR, Aircraft, and In-Ocean...

  10. Categorical Exclusion Determinations: Alabama | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... September 17, 2013 CX-010944: Categorical Exclusion Determination Daikin Advanced Lithium Ion Battery Technology - High Voltage Electrolyte CX(s) Applied: B3.6 Date: 09172013 ...

  11. Categorical Exclusion Determinations: Illinois | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... March 9, 2015 CX-013445: Categorical Exclusion Determination Scale Up of Lithium Ion Battery Material Recycling, Building 369 CX(s) Applied: B3.6 Date: 03092015 ...

  12. Watermark: Noncompliance Determination (2011-SW-2908)

    Broader source: Energy.gov [DOE]

    DOE issued a Notice of Noncompliance Determination to Watermark Designs, Ltd. finding that model SH-FAL-90, a showerhead, does not comport with the water conservation standards.

  13. Categorical Exclusion Determinations: Savannah River Operations...

    Office of Environmental Management (EM)

    Savannah River Operations Office Categorical Exclusion Determinations: Savannah River ... Install Concrete Block Bins for Additional Rock Storage at MOX Batch Plant CX(s) Applied: ...

  14. Caldicellulosiruptor Core and Pangenomes Reveal Determinants...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Caldicellulosiruptor Core and Pangenomes Reveal Determinants for Citation Details In-Document Search Title: Caldicellulosiruptor Core and Pangenomes Reveal ...

  15. Determining Memory Use | Argonne Leadership Computing Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Allinea DDT Core File Settings Determining Memory Use Using VNC with a Debugger bgqstack gdb Coreprocessor Runjob termination TotalView Performance Tools & APIs Software &...

  16. Categorical Exclusion Determinations: Maryland | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... May 27, 2014 CX-012134: Categorical Exclusion Determination Development of Advanced CFD Tools for Enhanced Prediction of Explosion Pressure Development and ... CX(s) Applied: A9, ...

  17. Categorical Exclusion Determinations: Ohio | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... August 12, 2014 CX-012681: Categorical Exclusion Determination Experimental Investigation and CFD Analysis of Steam Ingress Accidents in HTGRs - Ohio State University CX(s) ...

  18. CX-001207: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-001207: Categorical Exclusion Determination Grid-Scale Energy Storage Demonstration for ... of UltraBattery modules, integrated in a turnkey battery energy storage system (BESS). ...

  19. CX-009199: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-009199: Categorical Exclusion Determination Access Road Improvement For the ... Bonneville Power Administration proposes to perform access road maintenance on several ...

  20. Categorical Exclusion Determinations: Idaho Operations Office...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    May 5, 2015 CX-013679: Categorical Exclusion Determination In situ Raman Spectroscopy to Enhance Nuclear Materials Research and Education- University of Nevada Reno CX(s) Applied: ...

  1. Categorical Exclusion Determinations: Advanced Research Projects...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... November 19, 2013 CX-011740: Categorical Exclusion Determination Stanford University - Robust Multifunctional Battery Chassis Systems for Automotive Applications CX(s) Applied: ...

  2. Categorical Exclusion Determinations: Arkansas | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... February 7, 2011 CX-007795: Categorical Exclusion Determination Easement Acquisition, Carroll County, Arkansas CX(s) Applied: B1.24 Date: 02072011 Location(s): Arkansas ...

  3. Categorical Exclusion Determinations: Southwestern Power Administratio...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... February 7, 2011 CX-007795: Categorical Exclusion Determination Easement Acquisition, Carroll County, Arkansas CX(s) Applied: B1.24 Date: 02072011 Location(s): Arkansas ...

  4. Zinc Speciation in Contaminated Sediments: Quantitative Determination...

    Office of Scientific and Technical Information (OSTI)

    Zinc Speciation in Contaminated Sediments: Quantitative Determination of Zinc Coordination by X-ray Absorption Spectroscopy Citation Details In-Document Search Title: Zinc ...

  5. Categorical Exclusion Determinations: Golden Field Office | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Program Date: 03252015 Location(s): Nationwide Office(s): Golden Field Office March 24, 2015 CX-100203 Categorical Exclusion Determination Solar Hot Water Project in Greenburgh,...

  6. Categorical Exclusion Determinations: Vermont | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    January 27, 2016 CX-100465 Categorical Exclusion Determination Training for State Officials to Make Solar More Inclusive, Affordable, and Consumer Friendly Award Number: ...

  7. CX-002955: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-002955: Categorical Exclusion Determination Hawaii Hydrogen Power Park - Technology ... for use in the Hawaii Volcano National Park system (HAVO) on the Big Island of Hawaii. ...

  8. Determination Of Ph Including Hemoglobin Correction

    DOE Patents [OSTI]

    Maynard, John D.; Hendee, Shonn P.; Rohrscheib, Mark R.; Nunez, David; Alam, M. Kathleen; Franke, James E.; Kemeny, Gabor J.

    2005-09-13

    Methods and apparatuses of determining the pH of a sample. A method can comprise determining an infrared spectrum of the sample, and determining the hemoglobin concentration of the sample. The hemoglobin concentration and the infrared spectrum can then be used to determine the pH of the sample. In some embodiments, the hemoglobin concentration can be used to select an model relating infrared spectra to pH that is applicable at the determined hemoglobin concentration. In other embodiments, a model relating hemoglobin concentration and infrared spectra to pH can be used. An apparatus according to the present invention can comprise an illumination system, adapted to supply radiation to a sample; a collection system, adapted to collect radiation expressed from the sample responsive to the incident radiation; and an analysis system, adapted to relate information about the incident radiation, the expressed radiation, and the hemoglobin concentration of the sample to pH.

  9. Determining Price Reasonableness in Federal ESPCs

    SciTech Connect (OSTI)

    Shonder, J.A.

    2005-03-08

    This document reports the findings and implementation recommendations of the Price Reasonableness Working Group to the Federal ESPC Steering Committee. The working group was formed to address concerns of agencies and oversight organizations related to pricing and fair and reasonable price determination in federal energy savings performance contracts (ESPCs). This report comprises the working group's recommendations and is the proposed draft of a training curriculum on fair and reasonable price determination for users of federal ESPCs. The report includes: (1) A review of federal regulations applicable to determining price reasonableness of federal ESPCs (section 2), (2) Brief descriptions of the techniques described in Federal Acquisition Regulations (FAR) 15.404-1 and their applicability to ESPCs (section 3), and (3) Recommended strategies and procedures for cost-effectively completing price reasonableness determinations (sections 4). Agencies have struggled with fair and reasonable price determinations in their ESPCs primarily because this alternative financing vehicle is relatively new and relatively rare in the federal sector. The methods of determining price reasonableness most familiar to federal contracting officers (price competition based on the government's design and specifications, in particular) are generally not applicable to ESPCs. The regulatory requirements for determining price reasonableness in federal ESPCs have also been misunderstood, as federal procurement professionals who are inexperienced with ESPCs are further confused by multiple directives, including Executive Order 13123, which stresses life-cycle cost-effectiveness. Uncertainty about applicable regulations and inconsistent practice and documentation among agencies have fueled claims that price reasonableness determinations have not been sufficiently rigorous in federal ESPCs or that the prices paid in ESPCs are generally higher than the prices paid for similar goods and services obtained through conventional procurements. While claims of excessive prices are largely unsubstantiated and based on anecdotal evidence, the perception that there is a problem is shared by many in the ESPC community and has been noted by auditors and oversight organizations. The Price Reasonableness Working Group determined that a more formal emphasis on FAR 15.404-1 in the ESPC process could remove much of the doubt about price reasonableness determinations. The working group's recommended consensus policy on price reasonableness stresses the price analysis techniques described in the FAR that are applicable to ESPCs and includes guidance for agencies use of these techniques in determining price reasonableness for their ESPC delivery orders. The recommended policy and guidance, if communicated to federal ESPC stakeholders, can ensure that agencies will comply with the FAR in awarding ESPCs, obtain fair and reasonable prices and best value for the government, and follow procedures that provide auditable documentation of due diligence in price reasonableness determinations.

  10. Season and diurnal variations of peroxyacetyl nitrate (PAN) in a suburban area of central Italy and their relation with the meteorological conditions and the concentration of other photochemical oxidants and their precursors

    SciTech Connect (OSTI)

    Ciccioli, P.; Cecinato, A.; Brancaleoni, E.; Brachetti, A. )

    1988-09-01

    Peroxyacetyl nitrate (PAN), is a photochemical oxidant formed in the atmosphere when large amounts of hydrocarbons (HC) and NO{sub x} are emitted in air and exposed to the UV radiation coming from the sun. Its formation proceeds through the conversion of HC, mainly olefins, into aldehydes that, after oxidation into peroxyradicals, react with NO{sub 2} to give this gaseous pollutant. Although the amount of PAN in air represents a suitable index for measuring photochemical smog and photochemical episodes can easily be observed in many Italian cities, almost no data have been collected in their country. In this paper the authors present the results obtained during a two years monitoring campaign carried in a suburban area of Central Italy placed downwind to Rome. Seasonal and daily trends of PAN will be reported together with the meteorological parameters and the change in concentration of other photochemical oxidants (ozone), its precursors (HC and aldehydes) and some acidic species. The results indicate that PAN, formed within the city, is transported into site together with other oxidants.

  11. Haier: Noncompliance Determination (2011-SE-1408)

    Broader source: Energy.gov [DOE]

    DOE issued a Notice of Noncompliance Determination to Haier America Trading, L.L.C. finding that model number HNCM070, a chest freezer, does not comport with the energy conservation standards.

  12. Categorical Exclusion Determinations | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    under the Department's NEPA regulations (10 CFR Part 1021) and NEPA Order (DOE Order 451.1B) to document and post online its categorical exclusion (CX) determinations involving ...

  13. CX-001862: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-001862: Categorical Exclusion Determination Clearwater Campus District Cooling - Activity 3 CX(s) Applied: B3.6, A1, B5.1 Date: 04192010 Location(s): Pinellas County, Florida ...

  14. Central Moloney: Noncompliance Determination (2013-SE-4702)

    Broader source: Energy.gov [DOE]

    DOE issued a Notice of Noncompliance Determination to Central Moloney, Inc. finding that liquid-immersed distribution transformer basic models 30300150 and 32500095 do not comport with the energy conservation standards.

  15. Everest Refrigeration: Noncompliance Determination (2015-SE-42001)

    Broader source: Energy.gov [DOE]

    DOE issued a Notice of Noncompliance Determination to Bu Sung America Corporation (dba Everest Refrigeration) finding that commercial refrigeration equipment model number ESGR3 does not comport with the energy conservation standards.

  16. Universal: Noncompliance Determination (2013-SE-26004)

    Broader source: Energy.gov [DOE]

    DOE issued a Notice of Noncompliance Determination to Universal Lighting Technologies, Inc. finding that fluorescent lamp ballast model B140R277HP does not comport with the energy conservation standards.

  17. Cooper: Noncompliance Determination (2012-SE-4701)

    Broader source: Energy.gov [DOE]

    DOE issued a Notice of Noncompliance Determination to Cooper Power Systems, LLC finding that basic models 277-99.28, 277-99.26, and 277-99.22 of distribution transformers do not comport with the energy conservation standards.

  18. Harrington: Noncompliance Determination (2014-SW-28011)

    Broader source: Energy.gov [DOE]

    DOE issued a Notice of Noncompliance Determination to Harrington Brass Works finding that kitchen faucet individual model 20-210-026 does not comport with the water conservation standards.

  19. Whirlpool: Compliance Determination (2010-SE-0103)

    Broader source: Energy.gov [DOE]

    DOE issued a Notice of Compliance Determination to Whirlpool Corporation after DOE testing confirmed that the Maytag refrigerator-freezer model MSD2578VE comports with the applicable energy conservation standard.

  20. Islandaire: Noncompliance Determination (2015-SE-43009)

    Broader source: Energy.gov [DOE]

    DOE issued a Notice of Noncompliance Determination to Islandaire, Inc. finding that the Islandaire package terminal air conditioner basic model CPZ-07ANR1-B, which includes model EZDR07B, does not comport with the applicable energy conservation standards.

  1. Utility: Noncompliance Determination (2016-SE-42003)

    Broader source: Energy.gov [DOE]

    DOE issued a Notice of Noncompliance Determination to Utility Refrigerator finding that commercial refrigeration equipment basic model number PT-R-75-SS-3S-3S-N does not comport with the energy conservation standards.

  2. Bigwall: Noncompliance Determination (2014-SE-15006)

    Broader source: Energy.gov [DOE]

    DOE issued a Notice of Noncompliance Determination to Bigwall Enterprises, Inc. finding that PerfectAire brand model PACH8000 ("Bigwall model PACH8000") of room air conditioners do not comport with the energy conservation standards.

  3. Mile High: Noncompliance Determination (2012-SE-4501)

    Broader source: Energy.gov [DOE]

    DOE issued a Notice of Noncompliance Determination to Mile High Equipment, LLC finding that Ice-O-Matic brand automatic commercial ice maker basic model ICE2106 FW, HW does not comport with the energy conservation standards.

  4. Sunshine Lighting: Noncompliance Determination (2014-SE-54008)

    Broader source: Energy.gov [DOE]

    DOE issued a Notice of Noncompliance Determination to Sunshine Lighting Company finding that Sunlite brand metal halide lamp fixture basic models 04937-SU, 04938-SU, 04952 SU, and 04956 SU do not comport with the energy conservation standards.

  5. Engineered Products: Noncompliance Determination (2012-SE-5401)

    Broader source: Energy.gov [DOE]

    DOE issued a Notice of Noncompliance Determination to Engineered Products Company finding that basic model 15701 of metal halide lamp fixture does not comport with the energy conservation standards.

  6. CX-007373: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-007373: Categorical Exclusion Determination Minnesota-City-Lakeville CX(s) Applied: B1.32, B2.5, B5.1 Date: 11222011 Location(s): Minnesota Offices(s): Energy Efficiency and ...

  7. CX-006218: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-006218: Categorical Exclusion Determination Aptera All-Electric and Hybrid Electric Vehicles CX(s) Applied: B1.31, B5.1 Date: 06202011 Location(s): Grand Rapids, Michigan ...

  8. CX-007065: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Categorical Exclusion Determination Slipstream Pilot-Scale Demonstration of a Novel Amine-Based Post-Combustion Technology for Carbon Dioxide Capture CX(s) Applied: B3.6...

  9. Categorical Exclusion Determinations: Other Location | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Propulsion Program March 27, 2015 CX-013774: Categorical Exclusion Determination Contra Costa Soil Testing and Equipment Upgrades CX(s) Applied: B4.6, B4.11 Date: 03272015 ...

  10. CX-002794: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-002794: Categorical Exclusion Determination Advanced Implementation of A123's Community Energy Storage (CES) System for Grid Support CX(s) Applied: B4.6, B5.1 Date: 06252010 ...

  11. CX-010745: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-010745: Categorical Exclusion Determination America Saves Energizing Main Street Small Businesses CX(s) Applied: A9, A11 Date: 08162013 Location(s): CX: none Offices(s): ...

  12. Fuzhou Sunlight: Noncompliance Determination (2010-SE-1402)

    Broader source: Energy.gov [DOE]

    DOE issued a Notice of Noncompliance Determination to Fuzhou Sunlight Lighting Electrical Appliance Co., Ltd. finding that a variety of models of incandescent reflector lamps do not comport with the energy conservation standards.

  13. Haier: Noncompliance Determination (2011-SE-1428)

    Broader source: Energy.gov [DOE]

    DOE issued a Notice of Noncompliance Determination to Haier America Trading, LLC finding that Haier model HMCM106EA, a freezer, does not comport with the energy conservation standards.

  14. Aspen: Noncompliance Determination (2010-SE-0305)

    Broader source: Energy.gov [DOE]

    DOE issued a Notice of Noncompliance Determination to Aspen Manufacturing finding that a variety of basic models of split-system air conditioning heat pumps do not comport with the energy conservation standards.

  15. CX-007529: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-007529: Categorical Exclusion Determination Missouri-City-St. Charles CX(s) Applied: ... efficient lighting at City Hall, 2) develop and write "green" building codes for the city. ...

  16. Categorical Exclusion Determinations: Golden Field Office | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    31, 2015 CX-100349 Categorical Exclusion Determination Advanced Trough with Lower-cost System-architecture (ATLAS) Award Number: DE-EE0007121 CX(s) Applied: A9, B3.6, B5.17...

  17. Categorical Exclusion (CX) Determinations By Date | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    31, 2015 CX-100349 Categorical Exclusion Determination Advanced Trough with Lower-cost System-architecture (ATLAS) Award Number: DE-EE0007121 CX(s) Applied: A9, B3.6, B5.17...

  18. Categorical Exclusion Determinations: Kansas City Site Office...

    Energy Savers [EERE]

    April 1, 2014 CX-012094: Categorical Exclusion Determination Project 1612B Removal and Disposal of Polychlorinated Biphenyls Contaminated Equipment CX(s) Applied: B1.17 Date: 04...

  19. Categorical Exclusion Determinations: West Virginia | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    September 2, 2014 CX-012402: Categorical Exclusion Determination B-33 Roof Replacement and Fall Protection System Installation CX(s) Applied: B1.3, B2.2, B2.3 Date: 41884 ...

  20. YMGI: Noncompliance Determination (2011-SCE-1605)

    Broader source: Energy.gov [DOE]

    DOE issued a Notice of Noncompliance Determination to YMGI Group, LLC, finding that YMGI's through-the-wall split system central air conditioner basic model TTWC-18K-31B fails to meet applicable DOE energy conservation standards.

  1. Categorical Exclusion Determinations: Golden Field Office | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Determination Current Energy Harnessing using Synergistic Kinematics of Schools of Fish-Shaped Bodies Award Number: DE-EE0006780 CX(s) Applied: A9, B3.6 Date: 12112014...

  2. Categorical Exclusion Determinations: NNSA-Headquarters | Department...

    Energy Savers [EERE]

    February 8, 2013 CX-010705: Categorical Exclusion Determination National Laser Facility Program Funding Opportunity CX(s) Applied: A1, A9, A11, B3.6 Date: 02082013 Location(s): ...

  3. Categorical Exclusion Determinations: Lawrence Livermore Site...

    Energy Savers [EERE]

    April 16, 2015 CX-013666: Categorical Exclusion Determination Ground-Based Laser Field Experiments CX(s) Applied: B3.11 Date: 04162015 Location(s): California Offices(s): ...

  4. CX-010658: Categorical Exclusion Determination | Department of...

    Office of Environmental Management (EM)

    CX-010658: Categorical Exclusion Determination Analytical Development Laser Maintenance CX(s) Applied: B3.6 Date: 06172013 Location(s): South Carolina Offices(s): Savannah River ...

  5. Cone Penetrometer N Factor Determination Testing Results

    SciTech Connect (OSTI)

    Follett, Jordan R.

    2014-03-05

    This document contains the results of testing activities to determine the empirical 'N Factor' for the cone penetrometer in kaolin clay simulant. The N Factor is used to releate resistance measurements taken with the cone penetrometer to shear strength.

  6. Felix Storch: Noncompliance Determination (2011-SE-1420)

    Broader source: Energy.gov [DOE]

    DOE issued a Notice of Noncompliance Determination to Felix Storch, Inc., finding that model number CF11ES, a chest freezer does not comport with the energy conservation standards.

  7. SRS FTF Section 3116 Basis for Determination

    Broader source: Energy.gov [DOE]

    Basis for Section 3116 Determination for Closure of F-Tank Farm at the Savannah River Site. In accordance with NDAA Section 3116, certain waste from reprocessing of spent nuclear fuel is not high...

  8. Categorical Exclusion Determinations: Nebraska | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    June 23, 2014 CX-012279: Categorical Exclusion Determination Vertically Aligned Carbon-Nanotubes Embedded in Ceramic Matrices for Hot Electrode Applications CX(s) Applied: B3.6 ...

  9. CX-100101: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-100101: Categorical Exclusion Determination Laufer Wind Group NWTC Structure Lighting Tests; NREL Tracking No. 13-014 Award Number: DE-AC36-08GO28308 CX(s) Applied: A9, B1.31, ...

  10. CX-100252 Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-100252 Categorical Exclusion Determination NREL - NWTC Site 3.3 Cable Repair; NREL Tracking No. 15-019 Award Number: DE-AC36-08GO28308 DOEEA 1914 (NREL NWTC) National Renewable ...

  11. CX-001062: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Exclusion Determination High-Temperature, High-Pressure Devices for Zonal Isolation in Geothermal Wells CX(s) Applied: A9, B3.6 Date: 03102010 Location(s): Lafayette, Colorado...

  12. CX-009921: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-009921: Categorical Exclusion Determination Technology Research, Development and Tools for Clean Biomass Cookstoves CX(s) Applied: A9, B3.6, B5.15 Date: 01072013...

  13. CX-100270 Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Determination Proposed Rulemaking for Energy Conservation Standards for Ceiling Fan Light Kits RIN: 1904-AC87 CX(s) Applied: B5.1 EERE- Buildings Technology Program Date:...

  14. CX-100231 Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-100231 Categorical Exclusion Determination STM FTLB Groundwater Monitoring Wells, NREL Tracking No. 15-016 Award Number: DE-AC36-08GO28308 CX(s) Applied: B3.1 National...

  15. Lutron Electronics: Noncompliance Determination (2012-SE-3796)

    Broader source: Energy.gov [DOE]

    DOE issued a Notice of Noncompliance Determination to Lutron Electronics Co., Inc. finding that a variety of Class A external power supply basic models do not comport with the energy conservation standards.

  16. Categorical Exclusion Determinations: Nevada Site Office | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    October 28, 2009 CX-001377: Categorical Exclusion Determination Nevada Test Site, Area 12 Camp Cafeteria Renovation CX(s) Applied: B1.3 Date: 10282009 Location(s): Nevada ...

  17. Hicon: Noncompliance Determination (2013-SE-1426)

    Broader source: Energy.gov [DOE]

    DOE issued a Notice of Noncompliance Determination to Ningbo Hicon International Industry Company, Ltd. finding that model number BD-200, a compact chest freezer, does not comport with the energy conservation standards.

  18. Categorical Exclusion Determinations: Alaska | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... July 19, 2012 CX-008577: Categorical Exclusion Determination Acoustic Monitoring of Beluga Whale Interactions with Cook Inlet Tidal Energy Project CX(s) Applied: B3.3 Date: 0719...

  19. Precision: Noncompliance Determination (2013-SE-1410)

    Broader source: Energy.gov [DOE]

    DOE issued a Notice of Noncompliance Determination to Precision Trading Corp. finding that Precision brand model Premium PFR515M, a freezer, does not comport with the energy conservation standards.

  20. Patterson: Noncompliance Determination (2011-SW-2911)

    Broader source: Energy.gov [DOE]

    DOE issued a Notice of Noncompliance Determination to Dan Patterson finding that the "ThunderHead" showerhead basic model manufactured by ET Industries, Inc. and imported by Dan Patterson does not comport with the water conservation standards.

  1. Categorical Exclusion Determinations: Loan Guarantee Program...

    Energy Savers [EERE]

    January 24, 2012 CX-007677: Categorical Exclusion Determination Project Eagle Phase 1 Direct WaferCell Solar Facility CX(s) Applied: B1.31 Date: 01242012 Location(s): ...

  2. Categorical Exclusion Determinations: Delaware | Department of...

    Office of Environmental Management (EM)

    ... August 26, 2011 CX-006578: Categorical Exclusion Determination Delaware State Energy Office Sub GranteeBridgeville Well Pump Replacement CX(s) Applied: B5.1 Date: 08262011 ...

  3. Categorical Exclusion Determinations: Iowa | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    October 25, 2013 CX-011288: Categorical Exclusion Determination 2009 National Biodiesel Foundation Biodiesel Infrastructure Project CX(s) Applied: B5.2, B5.22 Date: 10252013 ...

  4. Bigwall: Noncompliance Determination (2013-SE-1412)

    Broader source: Energy.gov [DOE]

    DOE issued a Notice of Noncompliance Determination to Bigwall Enterprises, Inc. finding that freezer model W1CF106 under the Wellington brand (''the Wellington W1CF106") does not comport with the energy conservation standards.

  5. Categorical Exclusion (CX) Determinations By Date | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Categorical Exclusion Determination Reducing Soft Costs through Hardware Innovation - Phase II Award Number: DE- EE-0007199 CX(s) Applied: A9, B3.6 Solar Energy Technologies...

  6. CX-003841: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-003841: Categorical Exclusion Determination Demolition and Removal of the X-230J9 North ... Office The demolition and removal of the X-230J9 North Environmental Sampling Building ...

  7. CX-008246: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Determination Recovery Act: Tennessee Energy Efficient Schools Initiative Ground Source Heat Pump Program CX(s) Applied: A9, B2.1, B5.19 Date: 05152012 Location(s): Tennessee...

  8. CX-008246: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-008246: Categorical Exclusion Determination Recovery Act: Tennessee Energy Efficient Schools Initiative Ground Source Heat Pump Program CX(s) Applied: A9, B2.1, B5.19 Date: 05...

  9. Categorical Exclusion Determinations: Michigan | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    March 3, 2016 CX-100561 Categorical Exclusion Determination Current Energy Harnessing using Synergistic Kinematics of Schools of Fish-Shaped Bodies Award Number: DE-EE0006780 CX(s) ...

  10. Categorical Exclusion Determinations: Texas | Department of Energy

    Office of Environmental Management (EM)

    ... June 17, 2015 CX-100294 Categorical Exclusion Determination Texturizing Wind Turbine Towers ... Convert BMT-4 to External Floating Roof Tank (BM-MM-740) (BMT-4) CX(s) Applied: B1.3 ...

  11. Categorical Exclusion Determinations: New Hampshire | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... November 15, 2011 CX-007727: Categorical Exclusion Determination Dartmouth College - Nanocrystalline T-MnAl Permanent Magnets CX(s) Applied: A9, B3.6 Date: 11152011 Location(s): ...

  12. CX-009154: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-009154: Categorical Exclusion Determination Scale-up of Novel Low-Cost Carbon Fibers Leading to High-Volume Commercial Launch CX(s) Applied: A9, B3.6 Date: 09052012 ...

  13. Midea: Noncompliance Determination (2010-SE-0110)

    Broader source: Energy.gov [DOE]

    DOE issued a Notice of Noncompliance Determination to Midea America Corporation finding that basic model number HS-390C, a chest freezer, does not comport with the energy conservation standards.

  14. FY 14 Award Fee Determination Scorecard

    Office of Environmental Management (EM)

    14 Award Fee Determination Scorecard Contractor: Swift and Staley Inc. (SST) Contract: DE-AC30-10CC40021 Award Period: October 1,2013 - September 30,2014 Basis of Evaluation: FY 14 ...

  15. Categorical Exclusion (CX) Determinations By Date | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Categorical Exclusion Determination Highly Active, Durable, and Ultra-low PGM NSTF Thin Film ORR Catalysts and Supports Award Number: DE-FOA-0007270 CX(s) Applied: A9, B3.6...

  16. Categorical Exclusion Determinations: Golden Field Office | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Categorical Exclusion Determination Highly Active, Durable, and Ultra-low PGM NSTF Thin Film ORR Catalysts and Supports Award Number: DE-FOA-0007270 CX(s) Applied: A9, B3.6...

  17. Golden Opportunity: Noncompliance Determination (2013-SE-1418)

    Broader source: Energy.gov [DOE]

    DOE issued a Notice of Noncompliance Determination to Golden Opportunity, Inc. finding that freezer models Golden GFC51 and Golden GFC69 do not comport with the energy conservation standards.

  18. Simkar: Noncompliance Determination (2012-SE-5408)

    Broader source: Energy.gov [DOE]

    DOE issued a Notice of Noncompliance Determination to Simkar Corporation finding that magnetic probe-start and pulse-start basic models of metal halide lamp fixtures do not comport with the energy conservation standards.

  19. Categorical Exclusion Determinations: Colorado | Department of...

    Office of Environmental Management (EM)

    March 7, 2016 CX-100538 Categorical Exclusion Determination ESIF Window Retrofit; NREL Tracking No. 14-018 Award Number: DE-AC36-08GO28308 CX(s) Applied: B1.20 National Renewable ...

  20. Categorical Exclusion Determinations: Hawaii | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    April 6, 2016 CX-100590 Categorical Exclusion Determination Ocean Energy Demonstration of the Ocean Energy (OE) Buoy at US Navy's Wave Energy Test Site Award Number: DE-EE0006924 ...

  1. CX-002682: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-002682: Categorical Exclusion Determination Landfill Gas Utilization Project CX(s) Applied: B5.1 Date: 06082010 Location(s): Madison County, New York Office(s): Energy ...

  2. CX-006627: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-006627: Categorical Exclusion Determination Elverta Maintenance Facility Remodel CX(s) Applied: B1.4, B1.15, B2.1, B2.3, B2.5 Date: 08242011 Location(s): Sacramento County, ...

  3. Categorical Exclusion Determinations: RMOTC | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Applied: B5.4, B5.6 Date: 12302013 Location(s): Wyoming Offices(s): RMOTC July 26, 2013 CX-010688: Categorical Exclusion Determination Optimization Project 3 CX(s) Applied: ...

  4. CX-006232: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-006232: Categorical Exclusion Determination Town of Glocester CX(s) Applied: B5.1 Date: 07012011 Location(s): Chapachet, Rhode Island Office(s): Energy Efficiency and ...

  5. CX-002776: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-002776: Categorical Exclusion Determination California-City-Elk Grove CX(s) Applied: B2.5, A9, A11, B5.1 Date: 06152010 Location(s): Elk Grove, California Office(s): Energy ...

  6. CX-006217: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-006217: Categorical Exclusion Determination OPOC Engine Manufacturing Project CX(s) Applied: B1.31, B5.1 Date: 06162011 Location(s): Troy, Michigan Office(s): Advanced ...

  7. CX-003520: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-003520: Categorical Exclusion Determination Pontiac High School Geothermal CX(s) Applied: B5.1 Date: 08262010 Location(s): Pontiac, Illinois Office(s): Energy Efficiency and ...

  8. CX-008030: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-008030: Categorical Exclusion Determination Energy Retrofits CX(s) Applied: B5.1 Date: 12012011 Location(s): Nationwide Offices(s): Energy Efficiency and Renewable Energy ...

  9. Midea: Noncompliance Determination (2012-SE-1404)

    Office of Energy Efficiency and Renewable Energy (EERE)

    DOE issued a Notice of Noncompliance Determination to Midea America Corp. finding that basic models UL-WD195-D and UL-WD145-D of freezers do not comport with the energy conservation standards.

  10. CX-012666: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-012666: Categorical Exclusion Determination Carib Energy (USA) LLC CX(s) Applied: B5.7 Date: 41789 Location(s): Florida Offices(s): Fossil Energy Carib Energy (USA), LLC, a ...

  11. CX-009911: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-009911: Categorical Exclusion Determination Geothermal Retrofit of Illinois National Guard's State Headquarters Building CX(s) Applied: A9, B2.1, B5.19 Date: 01142013 ...

  12. CX-004355: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-004355: Categorical Exclusion Determination Performance Contracting Energy AuditsRetrofitting City Buildings CX(s) Applied: A1, A9, B1.2, B1.4, B2.5, B5.1 Date: 11022010 ...

  13. Philips: Noncompliance Determination (2012-SE-2605)

    Broader source: Energy.gov [DOE]

    DOE issued a Notice of Noncompliance Determination to Philips Lighting Electronics N. A. finding that basic model VEL-I S40-SC, a fluorescent lamp ballast, does not comport with the energy conservation standards.

  14. LG: Noncompliance Determination (2014-SE-15011)

    Broader source: Energy.gov [DOE]

    DOE issued a Notice of Noncompliance Determination to LG Electronics USA, Inc. finding that room air conditioner basic model LT143CNR does not comport with the energy conservation standards.

  15. Categorical Exclusion Determinations: New Mexico | Department...

    Office of Environmental Management (EM)

    ... July 1, 2014 CX-012357: Categorical Exclusion Determination Shiprock Substation Stormwater Erosion Control Maintenance, San Juan County, New Mexico CX(s) Applied: B1.33 Date: 07...

  16. Categorical Exclusion Determinations: Montana | Department of...

    Energy Savers [EERE]

    March 11, 2015 CX-013448: Categorical Exclusion Determination Taft Substation Retaining Wall and Stormwater Maintenance Project CX(s) Applied: B1.3 Date: 03112015 Location(s): ...

  17. AHT: Noncompliance Determination (2015-SE-42031)

    Broader source: Energy.gov [DOE]

    DOE issued a Notice of Noncompliance Determination to AHT Cooling Systems, Inc. finding that commercial refrigeration equipment model number RIO S 68 F L R404A does not comport with the energy conservation standards.

  18. Goodman Manufacturing: Noncompliance Determination (2011-SE-4301)

    Broader source: Energy.gov [DOE]

    DOE issued a Notice of Noncompliance Determination to Goodman Manufacturing finding that model CPC180XXX3BXXXAA (CPC180*) of commercial package air conditioner does not comport with the energy conservation standards.

  19. CX-011991: Categorical Exclusion Determination | Department of...

    Office of Environmental Management (EM)

    CX-011991: Categorical Exclusion Determination SoloPower, Inc. Electrodeposition-based Solar Panel Manufacturing Facilities CX(s) Applied: B1.31 Date: 08152011 Location(s): ...

  20. CX-010792: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-010792: Categorical Exclusion Determination Gulf of Mexico Miocene Carbon Dioxide (CO2) Site Characterization Mega Transect - Task 8 CX(s) Applied: A1, A9, A11 Date: 08142013 ...

  1. Demagnetization using a determined estimated magnetic state

    DOE Patents [OSTI]

    Denis, Ronald J; Makowski, Nathanael J

    2015-01-13

    A method for demagnetizing comprising positioning a core within the electromagnetic field generated by a first winding until the generated first electrical current is not substantially increasing, thereby determining a saturation current. A second voltage, having the opposite polarity, is then applied across the first winding until the generated second electrical current is approximately equal to the magnitude of the determined saturation current. The maximum magnetic flux within the core is then determined using the voltage across said first winding and the second current. A third voltage, having the opposite polarity, is then applied across the first winding until the core has a magnetic flux equal to approximately half of the determined maximum magnetic flux within the core.

  2. CX-003720: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Categorical Exclusion Determination Recovery Act - Los Angeles Department of Water and Power Smart Grid Regional Demonstration Project CX(s) Applied: A9, A11, B3.6, B4.4, B5.1...

  3. Categorical Exclusion Determinations: Maine | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... November 30, 2011 CX-007739: Categorical Exclusion Determination University of Colorado - Boulder - Wafer-Level Sub-Module Integrated DCDC Converter CX(s) Applied: A9, B3.6 Date: ...

  4. CX-008824: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-008824: Categorical Exclusion Determination X-608 Well Field Transfer CX(s) Applied: ... The wells, well pumps and related underground piping are located within the X-608 well ...

  5. CX-006213: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-006213: Categorical Exclusion Determination Recovery Act: Conducting a 3D Converted Shear Wave Project to Reduce Exploration Risk at Wister, California CX(s) Applied: A9, B3.1, ...

  6. Friedrich: Noncompliance Determination (2014-SE-15010)

    Broader source: Energy.gov [DOE]

    DOE issued a Notice of Noncompliance Determination to Friedrich Air Conditioning Co. finding that room air conditioner basic model SQ10N10 does not comport with the energy conservation standards.

  7. Sanyo: Noncompliance Determination (2013-SE-1428)

    Broader source: Energy.gov [DOE]

    DOE issued a Notice of Noncompliance Determination to Sanyo E & E Corporation finding that model number SBC-500, a compact refrigerator with manual defrost, does not comport with the energy conservation standards.

  8. Substrates and method for determining enzymes

    DOE Patents [OSTI]

    Smith, R.E.; Bissell, E.R.

    1981-10-13

    A method is disclosed for determining the presence of an enzyme in a biological fluid, which includes the steps of contacting the fluid with a synthetic chromogenic substrate, which is an amino acid derivative of 7-amino-4-trifluoromethylcoumarin; incubating the substrate-containing fluid to effect enzymatic hydrolysis; and fluorometrically determining the presence of the free 7-amino-4-trifluoromethylcoumarin chromophore in the hydrolyzate. No Drawings

  9. Substrates and method for determining enzymes

    DOE Patents [OSTI]

    Smith, Robert E. (574 Escondido Cir., Livermore, CA 94550); Bissell, Eugene R. (101 Via Lucia, Alamo, CA 94507)

    1981-01-01

    A method is disclosed for determining the presence of an enzyme in a biological fluid, which includes the steps of contacting the fluid with a synthetic chromogenic substrate, which is an amino acid derivative of 7-amino-4-trifluoromethylcoumarin; incubating the substrate-containing fluid to effect enzymatic hydrolysis; and fluorometrically determining the presence of the free 7-amino-4-trifluoromethylcoumarin chromophore in the hydrolyzate.

  10. Determining Allocation Requirements | Argonne Leadership Computing Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Allocation Management Determining Allocation Requirements Querying Allocations Using cbank Mira/Cetus/Vesta Cooley Policies Documentation Feedback Please provide feedback to help guide us as we continue to build documentation for our new computing resource. [Feedback Form] Determining Allocation Requirements Estimating CPU-Hours for ALCF Blue Gene/Q Systems When estimating CPU-hours for the ALCF Blue Gene/Q systems, it is important to take into consideration the unique aspects of the Blue Gene

  11. Quantitative determination of atmospheric hydroperoxyl radical

    DOE Patents [OSTI]

    Springston, Stephen R.; Lloyd, Judith; Zheng, Jun

    2007-10-23

    A method for the quantitative determination of atmospheric hydroperoxyl radical comprising: (a) contacting a liquid phase atmospheric sample with a chemiluminescent compound which luminesces on contact with hydroperoxyl radical; (b) determining luminescence intensity from the liquid phase atmospheric sample; and (c) comparing said luminescence intensity from the liquid phase atmospheric sample to a standard luminescence intensity for hydroperoxyl radical. An apparatus for automating the method is also included.

  12. CHPRC Fee Determination Summaries - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CHPRC Fee Determination Summaries DOE-RL Contracts/Procurements RL Contracts & Procurements Home Prime Contracts Current Solicitations Other Sources DOE RL Contracting Officers DOE RL Contracting Officer Representatives CHPRC Fee Determination Summaries Email Email Page | Print Print Page |Text Increase Font Size Decrease Font Size CHPRC Fiscal Year 2015 Fee Evaluation Summary CHPRC Fiscal Year 2014 Fee Evaluation Summary CHPRC Fiscal Year 2013 Fee Evaluation Summary CHPRC Fiscal Year 2012

  13. Project Profile: Low-Cost Heliostat Development | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cost Heliostat Development Project Profile: Low-Cost Heliostat Development HiTek logo HiTek Services, under the Baseload CSP FOA, is conducting fundamental parametric analyses of the optimum heliostat size and developing a novel low-cost heliostat design. Approach There are four tasks under this award: Photo of a machine with two round discs connected by intertwined chains. Develop a means to determine the optimum size range of the heliostat, in terms of the applied forces and moments,

  14. Secretarial Determination for the Sale or Transfer of Uranium...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Secretarial Determination for the Sale or Transfer of Uranium Secretarial Determination for the Sale or Transfer of Uranium Secretarial Determination for the Sale or Transfer of...

  15. Office of Federal Procurement (OFPP) Determination of Executive...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Federal Procurement (OFPP) Determination of Executive Compensation Benchmark Amount for ... Office of Federal Procurement (OFPP) Determination of Executive Compensation Benchmark ...

  16. Islandaire: Noncompliance Determination (2015-SE-43008)

    Broader source: Energy.gov [DOE]

    DOE issued a Notice of Noncompliance Determination to Islandaire, Inc. finding that the Islandaire package terminal air conditioner basic model CPZ-129ANR1-B, which includes models EZDR12B and EZD4212B, does not comport with the applicable energy conservation standards.

  17. Midea America: Noncompliance Determination (2014-SEW-20006)

    Broader source: Energy.gov [DOE]

    DOE issued a Notice of Noncompliance Determination to Midea America Corp. finding that residential clothes washer basic model MAE80-S1702GPS, manufactured by Hefei Rongshida Washing Equipment Manufacturing Co., Ltd., a subsidiary of Midea Group, and distributed by Midea America does not comport with the energy and water conservation standards.

  18. Teddico: Noncompliance Determination (2012-SE-5409)

    Broader source: Energy.gov [DOE]

    DOE issued a Notice of Noncompliance Determination to The Electrical Design, Development and Implementation Company d/b/a Teddico finding that a variety of basic models of magnetic probe-start metal halide lamp fixtures do not comport with the energy conservation standards.

  19. Heat Controller: Noncompliance Determination (2014-SE-15004)

    Broader source: Energy.gov [DOE]

    DOE issued a Notice of Noncompliance Determination to Heat Controller, Inc. finding that the room air conditioner distributed in commerce by Heat Controller as Comfort Aire brand models CGREG-81H and REG-81J does not comport with the energy conservation standards.

  20. Midea: Noncompliance Determination (2013-SE-1505)

    Broader source: Energy.gov [DOE]

    DOE issued a Notice of Noncompliance Determination to GD Midea Air-Conditioning Equipment Co. Ltd. finding that Arctic King brand room air conditioner basic model MWJ1-08ERN1-BI8, manufactured by Midea, does not comport with the energy conservation standards.