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1

Partitioning of mercury, arsenic, selenium, boron, and chloride in a full-scale coal combustion process equipped with selective catalytic reduction, electrostatic precipitation, and flue gas desulfurization systems  

SciTech Connect (OSTI)

A full-scale field study was carried out at a 795 MWe coal-fired power plant equipped with selective catalytic reduction (SCR), an electrostatic precipitator (ESP), and wet flue gas desulfurization (FGD) systems to investigate the distribution of selected trace elements (i.e., mercury, arsenic, selenium, boron, and chloride) from coal, FGD reagent slurry, makeup water to flue gas, solid byproduct, and wastewater streams. Flue gases were collected from the SCR outlet, ESP inlet, FGD inlet, and stack. Concurrent with flue gas sampling, coal, bottom ash, economizer ash, and samples from the FGD process were also collected for elemental analysis. By combining plant operation parameters, the overall material balances of selected elements were established. The removal efficiencies of As, Se, Hg, and B by the ESP unit were 88, 56, 17, and 8%, respectively. Only about 2.5% of Cl was condensed and removed from flue gas by fly ash. The FGD process removed over 90% of Cl, 77% of B, 76% of Hg, 30% of Se, and 5% of As. About 90% and 99% of the FGD-removed Hg and Se were associated with gypsum. For B and Cl, over 99% were discharged from the coal combustion process with the wastewater. Mineral trona (trisodium hydrogendicarbonate dehydrate, Na{sub 3}H(CO{sub 3}){sub 2}.2H{sub 2}O) was injected before the ESP unit to control the emission of sulfur trioxide (SO{sub 3}). By comparing the trace elements compositions in the fly ash samples collected from the locations before and after the trona injection, the injection of trona did not show an observable effect on the partitioning behaviors of selenium and arsenic, but it significantly increased the adsorption of mercury onto fly ash. The stack emissions of mercury, boron, selenium, and chloride were for the most part in the gas phase. 47 refs., 3 figs., 11 tabs.

Chin-Min Cheng; Pauline Hack; Paul Chu; Yung-Nan Chang; Ting-Yu Lin; Chih-Sheng Ko; Po-Han Chiang; Cheng-Chun He; Yuan-Min Lai; Wei-Ping Pan [Western Kentucky University, Bowling Green, KY (United States). Institute for Combustion Science and Environmental Technology

2009-09-15T23:59:59.000Z

2

Pressurized fluidized-bed hydroretorting of Eastern oil shales -- Sulfur control. Topical report for Subtask 3.1, In-bed sulfur capture tests; Subtask 3.2, Electrostatic desulfurization; Subtask 3.3, Microbial desulfurization and denitrification  

SciTech Connect (OSTI)

This topical report on ``Sulfur Control`` presents the results of work conducted by the Institute of Gas Technology (IGT), the Illinois Institute of Technology (IIT), and the Ohio State University (OSU) to develop three novel approaches for desulfurization that have shown good potential with coal and could be cost-effective for oil shales. These are (1) In-Bed Sulfur Capture using different sorbents (IGT), (2) Electrostatic Desulfurization (IIT), and (3) Microbial Desulfurization and Denitrification (OSU and IGT). The objective of the task on In-Bed Sulfur Capture was to determine the effectiveness of different sorbents (that is, limestone, calcined limestone, dolomite, and siderite) for capturing sulfur (as H{sub 2}S) in the reactor during hydroretorting. The objective of the task on Electrostatic Desulfurization was to determine the operating conditions necessary to achieve a high degree of sulfur removal and kerogen recovery in IIT`s electrostatic separator. The objectives of the task on Microbial Desulfurization and Denitrification were to (1) isolate microbial cultures and evaluate their ability to desulfurize and denitrify shale, (2) conduct laboratory-scale batch and continuous tests to improve and enhance microbial removal of these components, and (3) determine the effects of processing parameters, such as shale slurry concentration, solids settling characteristics, agitation rate, and pH on the process.

Roberts, M.J.; Abbasian, J.; Akin, C.; Lau, F.S.; Maka, A.; Mensinger, M.C.; Punwani, D.V.; Rue, D.M. [Institute of Gas Technology, Chicago, IL (United States); Gidaspow, D.; Gupta, R.; Wasan, D.T. [Illinois Inst. of Tech., Chicago, IL (United States); Pfister, R.M.: Krieger, E.J. [Ohio State Univ., Columbus, OH (United States)

1992-05-01T23:59:59.000Z

3

Monticello Unit 3 recovery project: The rebuild of a first generation wet flue gas desulfurization system  

SciTech Connect (OSTI)

Since November 1993, TU Electric and Sargent & Lundy have been engaged in the repair or replacement of equipment that was damaged by the collapse of the Monticello Unit 3 chimney. In addition to the replacement of the chimney, electrostatic precipitator, and various balance-of-plant systems, the scope of the project includes the demolition, engineering and design, procurement, and construction activities to rebuild major equipment within the wet limestone flue gas desulfurization (FGD) system. This paper reviews and discusses various aspects of the design, procurement and schedule associated with the rebuild of the FGD system. The paper reviews the design selections in the areas of process technology, the absorber island, and technical enhancements to improve the operability of this 1970s-vintage system. Finally, the challenges and solutions in implementing a 17-month schedule for the design, construction, and startup of an FGD system will be discussed.

Guletsky, P.W.; Katzberger, S.M. [Sargent & Lundy, Chicago, IL (United States); Jeanes, R.L. [TU Electric, Dallas, TX (United States)

1995-06-01T23:59:59.000Z

4

Methods, systems, and devices for deep desulfurization of fuel gases  

DOE Patents [OSTI]

A highly effective and regenerable method, system and device that enables the desulfurization of warm fuel gases by passing these warm gasses over metal-based sorbents arranged in a mesoporous substrate. This technology will protect Fischer-Tropsch synthesis catalysts and other sulfur sensitive catalysts, without drastic cooling of the fuel gases. This invention can be utilized in a process either alone or alongside other separation processes, and allows the total sulfur in such a gas to be reduced to less than 500 ppb and in some instances as low as 50 ppb.

Li, Liyu (Richland, WA); King, David L. (Richland, WA); Liu, Jun (Richland, WA); Huo, Qisheng (Richland, WA)

2012-04-17T23:59:59.000Z

5

Integrated operation of a pressurized fixed bed gasifier and hot gas desulfurization system  

SciTech Connect (OSTI)

The primary objective of this contract continues to be the demonstration of high fuel gas desulfurization of high temperature fuel gas desulfurization and particulate removal using a moving bed process with regenerable metal oxide sorbent. The fuel gas source for test operation is a fixed bed, air blown gasifier located at GE Corporate Research and Development in Schenectady, New York. The demonstration project also includes the design, construction, installation and test operation of a gas turbine simulator which includes a modified GE MS6000 type gas turbine combustor and a film cooled, first stage LM 6000 nozzle assembly. The hot gas cleanup (HGCU) system and the gas turbine simulator have been designed to operate with the full 8000 lb/hr fuel gas flow from the gasification of 1800 lb/hr of coal at 280 psig and 1000 to 1150 F. An advanced formulation of zinc ferrite as well as zinc titanate have been used as the regenerable metal oxide sorbents in testing to date. Demonstration of halogen removal as well as characterization of alkali and heavy metal concentrations in the fuel gas remain objectives, as well. Results are discussed.

Cook, C.S.; Gal, E.; Furman, A.H.; Ayala, R.

1992-01-01T23:59:59.000Z

6

Integrated operation of a pressurized fixed bed gasifier and hot gas desulfurization system  

SciTech Connect (OSTI)

The primary objective of this contract continues to be the demonstration of high fuel gas desulfurization of high temperature fuel gas desulfurization and particulate removal using a moving bed process with regenerable metal oxide sorbent. The fuel gas source for test operation is a fixed bed, air blown gasifier located at GE Corporate Research and Development in Schenectady, New York. The demonstration project also includes the design, construction, installation and test operation of a gas turbine simulator which includes a modified GE MS6000 type gas turbine combustor and a film cooled, first stage LM 6000 nozzle assembly. The hot gas cleanup (HGCU) system and the gas turbine simulator have been designed to operate with the full 8000 lb/hr fuel gas flow from the gasification of 1800 lb/hr of coal at 280 psig and 1000 to 1150 F. An advanced formulation of zinc ferrite as well as zinc titanate have been used as the regenerable metal oxide sorbents in testing to date. Demonstration of halogen removal as well as characterization of alkali and heavy metal concentrations in the fuel gas remain objectives, as well. Results are discussed.

Cook, C.S.; Gal, E.; Furman, A.H.; Ayala, R.

1992-12-01T23:59:59.000Z

7

A System-Level Electrostatic-Discharge-Protection Modeling Methodology for Time-  

E-Print Network [OSTI]

A System-Level Electrostatic-Discharge- Protection Modeling Methodology for Time- Domain Analysis. Index Terms--Electromagnetic compatibility (EMC), electrostatic discharge (ESD), modeling, system level precise simulations of electrostatic discharge (ESD) stress propagation on a printed circuit board (PCB

Boyer, Edmond

8

Anion-exchange resin-based desulfurization process  

SciTech Connect (OSTI)

Under DOE Grant No. FG22-90PC90309, the University of Tennessee Space Institute (UTSI) is contracted to further develop its anion-exchange, resin-based desulfurization concept to desulfurize alkali metal sulfates. From environmental as well as economic viewpoints, it is necessary to remove soluble sulfates from the wastes created by flue gas desulfurization systems. In order to do this economically, a low-cost desulfurization process for spent sorbents is necessary. UTSI's anion-exchange resin-based desulfurization concept is believed to satisfy these requirements.

Sheth, A.C.; Strevel, S.D.; Dharmapurikar, R.

1992-01-01T23:59:59.000Z

9

COAL DESULFURIZATION PRIOR TO COMBUSTION  

E-Print Network [OSTI]

90e COAL DESULFURIZATION PRIOR TO COMBUSTION J. Wrathall, T.of coal during combustion. The process involves the additionCOAL DESULFURIZATION PRIOR TO COMBUSTION Lawrence Berkeley

Wrathall, J.

2013-01-01T23:59:59.000Z

10

Permitting and solid waste management issues for the Bailly Station wet limestone Advanced Flue Gas Desulfurization (AFGD) system  

SciTech Connect (OSTI)

Pure Air (a general partnership between Air Products and Chemicals, Inc., and Mitsubishi Heavy Industries America, Inc.). is constructing a wet limestone co-current advanced flue gas desulfurization (AFGD) system that has technological and commercial advantages over conventional FGD systems in the United States. The AFGD system is being installed at the Northern Indiana Public Service Company's Bailly Generating Station near Gary, Indiana. The AFGD system is scheduled to be operational by the Summer, 1992. The AFGD system will remove at least 90 percent of the sulfur dioxide (SO{sub 2}) in the flue gas from Boilers 7 and 8 at the Station while burning 3.2 percent sulfur coal. Also as part of testing the AFGD system, 95 percent removal of SO{sub 2} will be demonstrated on coals containing up to 4.5 percent sulfur. At the same time that SO{sub 2} is removed from the flue gas, a gypsum by-product will be produced which will be used for wallboard manufacturing. Since the AFGD system is a pollution control device, one would expect its installation to be received favorably by the public and regulatory agencies. Although the project was well received by regulatory agencies, on public group (Save the Dunes Council) was initially concerned since the project is located adjacent to the Indiana Dunes National Lakeshore. The purpose of this paper is to describe the project team's experiences in obtaining permits/approvals from regulatory agencies and in dealing with the public. 1 ref., 1 fig., 2 tabs.

Bolinsky, F.T. (Pure Air, Allentown, PA (United States)); Ross, J. (Northern Indiana Public Service Co., Hammond, IN (United States)); Dennis, D.S. (United Engineers and Constructors, Inc., Denver, CO (United States). Stearns-Roger Div.); Huston, J.S. (Environmental Alternatives, Inc., Warren NJ (USA))

1991-01-01T23:59:59.000Z

11

Mechanistic understanding of microbial desulfurization  

E-Print Network [OSTI]

The increasing global levels of sulfur content in crude oil have motivated the development of alternate desulfurization technologies. Microbial desulfurization or biodesulfurization (BDS) has gained interest due to the ...

Abín-Fuentes, Andrés

2013-01-01T23:59:59.000Z

12

COAL DESULFURIZATION PRIOR TO COMBUSTION  

E-Print Network [OSTI]

Corporation, 5-25~79. on Coal Liquefaction at ChevronHamersma, et a L, "Meyers Process for Coal Desulfurization,"in Wheelock, Coal Desulfurization, ACS Symp. Ser 64 (1977(.

Wrathall, J.

2013-01-01T23:59:59.000Z

13

Desulfurization apparatus and method  

DOE Patents [OSTI]

A method and system for desulfurization comprising first and second metal oxides; a walled enclosure having an inlet and an exhaust for the passage of gas to be treated; the first and second metal oxide being combinable with hydrogen sulfide to produce a reaction comprising a sulfide and water; the first metal oxide forming a first layer and the second metal oxide forming a second layer within the walled surroundings; the first and second layers being positioned so the first layer removes the bulk amount of the hydrogen sulfide from the treated gas prior to passage through the second layer, and the second layer removes substantially all of the remaining hydrogen sulfide from the treated gas; the first metal oxide producing a stoichiometrical capacity in excess of 500 mg sulfur/gram; the second metal oxide reacts with the hydrogen sulfide more favorably but has a stoichometrical capacity which is less than the first reactant; whereby the optimal amount by weight of the first and second metal oxides is achieved by utilizing two to three units by weight of the first metal oxide for every unit of the second metal oxide.

Rong, Charles; Jiang, Rongzhong; Chu, Deryn

2013-06-18T23:59:59.000Z

14

Electrostatic coalescence system with independent AC and DC hydrophilic electrodes  

DOE Patents [OSTI]

An improved electrostatic coalescence system is provided in which independent AC and DC hydrophilic electrodes are employed to provide more complete dehydration of an oil emulsion. The AC field is produced between an AC electrode array and the water-oil interface wherein the AC electrode array is positioned parallel to the interface which acts as a grounded electrode. The emulsion is introduced into the AC field in an evenly distributed manner at the interface. The AC field promotes drop-drop and drop-interface coalescence of the water phase in the entering emulsion. The continuous oil phase passes upward through the perforated AC electrode array and enters a strong DC field produced between closely spaced DC electrodes in which small dispersed droplets of water entrained in the continuous phase are removed primarily by collection at hydrophilic DC electrodes. Large droplets of water collected by the electrodes migrate downward through the AC electrode array to the interface. All phase separation mechanisms are utilized to accomplish more complete phase separation.

Hovarongkura, A. David (Arlington, VA); Henry, Jr., Joseph D. (Morgantown, WV)

1981-01-01T23:59:59.000Z

15

On the potential energy in an electrostatically bound two-body system  

E-Print Network [OSTI]

The potential energy problem in an electrostatically bound two-body system is studied in the framework of a recently proposed impact model of the electrostatic force and in analogy to the potential energy in a gravitationally bound system. The physical processes are described that result in the variation of the potential energy as a function of the distance between the charged bodies. The energy is extracted from distributions of hypothetical interaction entities modified by the charged bodies.

K. Wilhelm; B. N. Dwivedi

2014-08-30T23:59:59.000Z

16

On the potential energy in an electrostatically bound two-body system  

E-Print Network [OSTI]

The potential energy problem in an electrostatically bound two-body system is studied in the framework of a recently proposed impact model of the electrostatic force and in analogy to the potential energy in a gravitationally bound system. The physical processes are described that result in the variation of the potential energy as a function of the distance between the charged bodies. The energy is extracted from distributions of hypothetical interaction entities modified by the charged bodies.

Wilhelm, K

2015-01-01T23:59:59.000Z

17

Integrated operation of a pressurized gasifier, hot gas desulfurization system and turbine simulator  

SciTech Connect (OSTI)

The overall objective of the General Electric Hot Gas Cleanup (HGCU) Program is to develop a commercially viable technology to remove sulfur, particulates, and halogens from a high-temperature fuel gas stream using a moving bed, regenerable mixed metal oxide sorbent based process. This technology will ultimately be incorporated into advanced Integrated Gasification Combined Cycle (IGCC) power generation systems. The objectives of the turbine simulator testing are (1) to demonstrate the suitability of fuel gas processed by the HGCU system for use in state-of-the-art gas turbines firing at F conditions (2,350 F rotor inlet temperature) and (2) to quantify the combustion characteristics and emissions of such a combustor. Testing of the GE HGCU system has been underway since December 1990. The two most recent tests, Test 5 and Test 6, represent the latest advancements in regenerator configuration, type of sorbent, and chloride control systems. Test 5 was based on the use of zinc titanate sorbent and included a revised regenerator configuration and a sodium bicarbonate injection system for chloride control. Test 6 incorporated the use of Z-Sorb, a chloride guard in the regenerator recycle loop, and further modifications to the regenerator internal configuration. This report describes the test conditions in detail and discusses the test results.

Bevan, S.; Najewicz, D.; Gal, E.; Furman, A.H.; Ayala, R.; Feitelberg, A.

1994-10-01T23:59:59.000Z

18

Coal Liquefaction desulfurization process  

DOE Patents [OSTI]

In a solvent refined coal liquefaction process, more effective desulfurization of the high boiling point components is effected by first stripping the solvent-coal reacted slurry of lower boiling point components, particularly including hydrogen sulfide and low molecular weight sulfur compounds, and then reacting the slurry with a solid sulfur getter material, such as iron. The sulfur getter compound, with reacted sulfur included, is then removed with other solids in the slurry.

Givens, Edwin N. (Bethlehem, PA)

1983-01-01T23:59:59.000Z

19

Dry flue gas desulfurization process for various coals  

SciTech Connect (OSTI)

Flue gas desulfurization (FGD) processes have been widely used since the early 1970's for control of sulfur dioxide emissions from coal-fired power plants. First generation FGD systems employ ''wet processes'' whereby the flue gas is contacted with a solution or slurry of an alkali reagent. Most of these installations use either lime or limestone. Calcium-based wet systems have, in general, satisfied SO/sub 2/ removal requirements; however, reliability of the early systems was affected by some operational problems. Additionally, sludge dewatering and disposal equipment results in overall system complexity. A dry FGD process which minimizes these problems was developed in late 1970's. It incorporates a spray drying concept for removal of SO/sub 2/ by reaction with lime slurry or soda ash solution. The spray dryer absorber is followed by an electrostatic precipitator or a fabric filter where particulates are collected. The waste product, which is a mixture of FGD reaction products, unreacted reagent and fly ash, is dry thus eliminating the need for dewatering equipment.

Widico, M.J.; Dhargalkar, P.H.

1985-01-01T23:59:59.000Z

20

Anion-exchange resin-based desulfurization process. Quarterly technical progress report, Januray 1, 1992--March 31, 1992  

SciTech Connect (OSTI)

Under DOE Grant No. FG22-90PC90309, the University of Tennessee Space Institute (UTSI) is contracted to further develop its anion-exchange, resin-based desulfurization concept to desulfurize alkali metal sulfates. From environmental as well as economic viewpoints, it is necessary to remove soluble sulfates from the wastes created by flue gas desulfurization systems. In order to do this economically, a low-cost desulfurization process for spent sorbents is necessary. UTSI`s anion-exchange resin-based desulfurization concept is believed to satisfy these requirements.

Sheth, A.C.; Strevel, S.D.; Dharmapurikar, R.

1992-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "desulfurization systems electrostatic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Electrostatic control of acid mist emissions  

SciTech Connect (OSTI)

This paper describes a two-phased study of the control of acid mist emissions using a compact, wet electrostatic precipitator (WESP). The goal of the study was to determine the degree of acid mist control that could be achieved when a compact WESP is used to replace or augment the mist eliminators in a flue gas desulfurization (FGD) system. Phase I of the study examined the electrical operation of a lab-scale WESP collecting an acid mist from a coal combustion pilot plant equipped with a spray chamber. The results of this study were used to develop and validate a computer model of the WESP. In Phase II, measurements were made at two utility scrubber installations to determine the loadings of acid mist, fly ash, and scrubber carryover. These measurements were used as input to the model to project the performance of a retrofitted WESP.

Dahlin, R S [Southern Research Inst., Birmingham, AL (United States)] [Southern Research Inst., Birmingham, AL (United States); Brown, T D [USDOE Pittsburgh Energy Technology Center, PA (United States)] [USDOE Pittsburgh Energy Technology Center, PA (United States)

1991-01-01T23:59:59.000Z

22

Apparatus and method for the desulfurization of petroleum by bacteria  

DOE Patents [OSTI]

A method for treating petroleum with anaerobic microorganisms acting as biocatalysts that can remove sulfur atoms from hydrocarbon molecules, under anaerobic conditions, and then convert the sulfur atoms to hydrogen sulfide. The microorganisms utilized are from the family known as the "Sulfate Reducing Bacteria." These bacteria generate metabolic energy from the oxidation of organic compounds, but use oxidized forms of sulfur as an electron acceptor. Because the biocatalyst is present in the form of bacteria in an aqueous suspension, whereas the reacting substrate consists of hydrocarbon molecules in an organic phase, the actual desulfurization reaction takes place at the aqueous-organic interphase. To ensure adequate interfacial contacting and mass transfer, a biphasic electrostatic bioreactor system is utilized. The bioreactor is utilized to disperse and recoalesce a biocatalyst contained in the aqueous liquid phase into the organic liquid phase containing the sulfur. High-intensity electrical fields rupture the aqueous drops into a plurality of microdroplets and induce continuous coalescence and redispersion as the microdroplets travel through the organic phase, thus increasing surface area. As the aqueous microdroplets progress through the organic phase, the biocatalyst then reacts with the sulfur to produce hydrogen sulfide which is then removed from the bioreactor. The organic liquid, now free of the sulfur, is ready for immediate use or further processing.

Lizama, Hector M. (Knoxville, TN); Scott, Timothy C. (Knoxville, TN); Scott, Charles D. (Oak Ridge, TN)

1995-01-01T23:59:59.000Z

23

Apparatus and method for the desulfurization of petroleum by bacteria  

DOE Patents [OSTI]

A method is described for treating petroleum with anaerobic microorganisms acting as biocatalysts that can remove sulfur atoms from hydrocarbon molecules, under anaerobic conditions, and then convert the sulfur atoms to hydrogen sulfide. The microorganisms utilized are from the family known as the ``Sulfate Reducing Bacteria``. These bacteria generate metabolic energy from the oxidation of organic compounds, but use oxidized forms of sulfur as an electron acceptor. Because the biocatalyst is present in the form of bacteria in an aqueous suspension, whereas the reacting substrate consists of hydrocarbon molecules in an organic phase, the actual desulfurization reaction takes place at the aqueous-organic interphase. To ensure adequate interfacial contacting and mass transfer, a biphasic electrostatic bioreactor system is utilized. The bioreactor is utilized to disperse and recoalesce a biocatalyst contained in the aqueous liquid phase into the organic liquid phase containing the sulfur. High-intensity electrical fields rupture the aqueous drops into a plurality of microdroplets and induce continuous coalescence and redispersion as the microdroplets travel through the organic phase, thus increasing surface area. As the aqueous microdroplets progress through the organic phase, the biocatalyst then reacts with the sulfur to produce hydrogen sulfide which is then removed from the bioreactor. The organic liquid, now free of the sulfur, is ready for immediate use or further processing. 5 figs.

Lizama, H.M.; Scott, T.C.; Scott, C.D.

1995-10-17T23:59:59.000Z

24

Non-invasive optoelectronic system for measurement of electrostatic discharge (ESD) induced phenomena  

SciTech Connect (OSTI)

The design of a high speed optoelectronic system consisting of an electrically floating detector/transmitter module, coupled to a receiver by a fiber optic link, is described. Typical applications of this optical decoupled system, involving electrostatic discharge (ESD), are described. These include: the optical signature characterization of discharges, and the measurement of conducted and radiated electromagnetic interference (EMI) due to ESD. Results of experiments conducted to demonstrate the qualitative performance characteristics of the measurement system are presented.

Greason, W.D.; Kucerovsky, Z.; Bulach, S.; Flatley, M.W. [Univ. of Western Ontario, London, Ontario (Canada). Dept. of Electrical Engineering

1995-12-31T23:59:59.000Z

25

The Biocatalytic Desulfurization Project  

SciTech Connect (OSTI)

The material in this report summarizes the Diversa technical effort in development of a biocatalyst for the biodesulfurization of Petro Star diesel as well as an economic report of standalone and combined desulfurization options, prepared by Pelorus and Anvil, to support and inform the development of a commercially viable process. We will discuss goals of the projected as originally stated and their modification as guided by parallel efforts to evaluate commercialization economics and process parameters. We describe efforts to identify novel genes and hosts for the generation of an optimal biocatalyst, analysis of diesel fuels (untreated, chemically oxidized and hydrotreated) for organosulfur compound composition and directed evolution of enzymes central to the biodesulfurization pathway to optimize properties important for their use in a biocatalyst. Finally we will summarize the challenges and issues that are central to successful development of a viable biodesulfurization process.

David Nunn; James Boltz; Philip M. DiGrazia; Larry Nace

2006-03-03T23:59:59.000Z

26

Generalized Parametric Resonance in Electrostatically-Actuated Microelectromechanical Systems  

E-Print Network [OSTI]

uses a free-space approach consisting of a single microelectromechanical systems MEMS mirror array microelectromechanical systems- MEMS -based White cell TTD device, a lin- ear cell. We used a commercially available MEMS

Rhoads, Jeffrey F.

27

Integrated low emission cleanup system for direct coal-fueled turbines (electrostatic agglomeration)  

SciTech Connect (OSTI)

The objective of this contract was to investigate the removal of SO[sub x] and particulate matter from direct coal fired combustion gas streams at high temperature and high pressure conditions. This investigation was to be accomplished through a bench scale testing and evaluation program for SO[sub x] removal and the innovative particulate collection concept of particulate growth through electrostatic agglomeration followed by high efficiency mechanical collection. The process goal was to achieve control better than that required by 1979 New Source Performance Standards. During Phase I, the designs of the combustor and gas cleanup apparatus were successfully completed. Hot gas cleanup was designed to be accomplished at temperature levels between 1800[degrees] and 2500[degrees]F at pressures up to 15 atmospheres. The combustor gas flow rate could be varied between 0.2--0.5 pounds per second. The electrostatic agglomerator residence time could be varied between 0.25 to 3 seconds. In Phase II, all components were fabricated, and erected successfully. Test data from shakedown testing was obtained. Unpredictable difficulties in pilot plant erection and shakedown consumed more budget resources than was estimated and as a consequence DOE, METC, decided ft was best to complete the contract at the end of Phase II. Parameters studied in shakedown testing revealed that high-temperature high pressure electrostatics offers an alternative to barrier filtration in hot gas cleanup but more research is needed in successful system integration between the combustor and electrostatic agglomerator.

Quimby, J.M.; Kumar, K.S.

1992-01-01T23:59:59.000Z

28

Systems and methods for the magnetic insulation of accelerator electrodes in electrostatic accelerators  

DOE Patents [OSTI]

The present invention provides systems and methods for the magnetic insulation of accelerator electrodes in electrostatic accelerators. Advantageously, the systems and methods of the present invention improve the practically obtainable performance of these electrostatic accelerators by addressing, among other things, voltage holding problems and conditioning issues. The problems and issues are addressed by flowing electric currents along these accelerator electrodes to produce magnetic fields that envelope the accelerator electrodes and their support structures, so as to prevent very low energy electrons from leaving the surfaces of the accelerator electrodes and subsequently picking up energy from the surrounding electric field. In various applications, this magnetic insulation must only produce modest gains in voltage holding capability to represent a significant achievement.

Grisham, Larry R

2013-12-17T23:59:59.000Z

29

Integrated low emission cleanup system for direct coal-fueled turbines (electrostatic agglomeration)  

SciTech Connect (OSTI)

The objective of this contract is to investigate the removal of So{sub x} and particulate matter from direct coal-fired combustion gas streams at high temperature and high pressure conditions. This investigation will be accomplished through a bench-scale testing and evaluation program employing sorbent mixed with a coal-water slurry for So{sub x} removal, and an innovative particulate control concept. The particulate control device utilizes electrostatic agglomeration followed by a high efficiency mechanical collector (cyclone). The process goal is to achieve particulate collection efficiency better than that required by the 1979 new source performance standards. An additional goal is to demonstrate 70% So{sub x} removal efficiency. This research project is now in the second of a 3 phase (Phase II) project. Phase II is to fabricate the combustor and particulate control devices and install the system at a test facility located at Research-Cottrell's, KVB Western Laboratory, Santa Ana, CA. There are three functional categories, or tasks which are to be completed in sequence. These tasks are itemized as follows: Design, procurement, and installation; Shakedown and startup; Reporting. Attempts to validate the concept of electrostatic agglomeration were not possible in the shakedown program before budget constraints halted the program. What was learned was that electrostatic precipitation is feasible in the temperature range of 1600--1800{degrees}F and at pressures above 10 atmospheres.

Quimby, J.M.

1992-02-01T23:59:59.000Z

30

Flue gas desulfurization  

DOE Patents [OSTI]

The invention involves a combustion process in which combustion gas containing sulfur oxide is directed past a series of heat exchangers to a stack and in which a sodium compound is added to the combustion gas in a temparature zone of above about 1400 K to form Na/sub 2/SO/sub 4/. Preferably, the temperature is above about 1800 K and the sodium compound is present as a vapor to provide a gas-gas reaction to form Na/sub 2/SO/sub 4/ as a liquid. Since liquid Na/sub 2/SO/sub 4/ may cause fouling of heat exchanger surfaces downstream from the combustion zone, the process advantageously includes the step of injecting a cooling gas downstream of the injection of the sodium compound yet upstream of one or more heat exchangers to cool the combustion gas to below about 1150 K and form solid Na/sub 2/SO/sub 4/. The cooling gas is preferably a portion of the combustion gas downstream which may be recycled for cooling. It is further advantageous to utilize an electrostatic precipitator downstream of the heat exchangers to recover the Na/sub 2/SO/sub 4/. It is also advantageous in the process to remove a portion of the combustion gas cleaned in the electrostatic precipitator and recycle that portion upstream to use as the cooling gas. 3 figures.

Im, K.H.; Ahluwalia, R.K.

1984-05-01T23:59:59.000Z

31

Flue gas desulfurization method and apparatus  

DOE Patents [OSTI]

A combined furnace limestone injection and dry scrubber flue gas desulfurization (FGD) system collects solids from the flue gas stream in first particulate collection device located downstream of an outlet of a convection pass of the furnace and upstream of the dry scrubber. The collected solids are diverted to the dry scrubber feed slurry preparation system to increase sulfur oxide species removal efficiency and sorbent utilization. The level of lime in the feed slurry provided to the dry scrubber is thus increased, which enhances removal of sulfur oxide species in the dry scrubber. The decreased particulate loading to the dry scrubber helps maintain a desired degree of free moisture in the flue gas stream entering the dry scrubber, which enhances sulfur oxide species removal both in the dry scrubber and downstream particulate collector, normally a baghouse. 5 figs.

Madden, D.A.; Farthing, G.A.

1998-09-29T23:59:59.000Z

32

Flue gas desulfurization method and apparatus  

DOE Patents [OSTI]

A combined furnace limestone injection and dry scrubber flue gas desulfurization (FGD) system collects solids from the flue gas stream in first particulate collection device located downstream of an outlet of a convection pass of the furnace and upstream of the dry scrubber. The collected solids are diverted to the dry scrubber feed slurry preparation system to increase sulfur oxide species removal efficiency and sorbent utilization. The level of lime in the feed slurry provided to the dry scrubber is thus increased, which enhances removal of sulfur oxide species in the dry scrubber. The decreased particulate loading to the dry scrubber helps maintain a desired degree of free moisture in the flue gas stream entering the dry scrubber, which enhances sulfur oxide species removal both in the dry scrubber and downstream particulate collector, normally a baghouse. 5 figs.

Madden, D.A.; Farthing, G.A.

1998-08-18T23:59:59.000Z

33

Low temperature aqueous desulfurization of coal  

DOE Patents [OSTI]

This invention describes a chemical process for desulfurizing coal, especially adaptable to the treatment of coal-water slurries, at temperatures as low as ambient, comprising treating the coal with aqueous titanous chloride whereby hydrogen sulfide is liberated and the desulfurized coal is separated with the conversion of titanous chloride to titanium oxides.

Slegeir, William A. (Hampton Bays, NY); Healy, Francis E. (Massapequa, NY); Sapienza, Richard S. (Shoreham, NY)

1985-01-01T23:59:59.000Z

34

Low temperature aqueous desulfurization of coal  

DOE Patents [OSTI]

This invention describes a chemical process for desulfurizing coal, especially adaptable to the treatment of coal-water slurries, at temperatures as low as ambient, comprising treating the coal with aqueous titanous chloride whereby hydrogen sulfide is liberated and the desulfurized coal is separated with the conversion of titanous chloride to titanium oxides.

Slegeir, W.A.; Healy, F.E.; Sapienza, R.S.

1985-04-18T23:59:59.000Z

35

Electrostatic precipitation of condensed acid mist  

SciTech Connect (OSTI)

Southern Research Institute is developing a compact, wet electrostatic precipitator (WESP) to control acid mist missions from high-sulfur coal combustion. The WESP is being developed as a retrofit technology for existing coal-fired power plants, particularly those equipped with wet flue gas desulfurization (FGD) scrubbers. Acid mist emissions can be a significant problem at these facilities because the sulfuric acid vapor in the flue gas is converted to a very fine mist that is not collected in the scrubber system. Conventional mist eliminators are not adequate in this application due to the very fine size of the mist droplets. The potential for corrosion also makes it difficult to use a fabric filter or a conventional, dry ESP in this application. Therefore, this research project has been structured around the development of a compact WESP that could be retrofit on top of an existing scrubber or within an existing flue gas duct. This paper describes the development and testing of a prototype WESP for the utility acid mist application. Testing was conducted with combustion of sulfur-doped gas to simulate the acid mist alone, and with a combination of coal and sulfur-doped gas to simulate the mixture of acid mist and fly ash downstream from a scrubber. The performance of the WESP test unit was modeled using two different cylindrical-geometry computer models: a current-seeking'' model and a current-specific'' model. 8 refs., 15 figs., 7 tabs.

Dahlin, R.S.

1989-11-01T23:59:59.000Z

36

Electrostatic precipitation of condensed acid mist  

SciTech Connect (OSTI)

This project addresses the acid mist that is formed by condensation of sulfuric acid vapor in flue gas from coal-fired utility boilers. An acid mist can be formed whenever the flue gas temperature approaches the prevailing acid dew point. This commonly occurs when the gas is subjected to rapid adiabatic cooling in a wet scrubber system for flue gas desulfurization. Acid mists can also sometimes result from unexpected temperature excursions caused by air inleakage, load cycling, and start-up operations. A wet electrostatic precipitator (WESP) is the best control option for acid mist. The mist would blind a fabric filter and attach glass fiber fabrics. A wet ESP is required because the acid would quickly corrode the plates in a conventional dry ESP. The wet ESP also offers the advantages of no rapping reentrainment and no sensitivity to fly ash resistivity. Therefore, this program has been structured around the use of a compact, wet ESP to control acid mist emissions. Progress to date is discussed. 7 refs., 1 fig.

Not Available

1990-01-01T23:59:59.000Z

37

Electrostatic precipitation of condensed acid mist  

SciTech Connect (OSTI)

This project addresses the acid mist that is formed by condensation of sulfuric acid vapor in flue gas from coal-fired utility boilers. An acid mist can be formed whenever the flue gas temperature approaches the prevailing acid dew point. This commonly occurs when the gas is subjected to rapid adiabatic cooling in a wet scrubber system for flue gas desulfurization. Acid mists can also sometimes result from unexpected temperature excursions caused by air inleakage, load cycling, and start-up operations. A wet electrostatic precipitator (WESP) is the best control option for acid mist. The mist would blind a fabric filter and attack glass fiber fabrics. A wet ESP is required because the acid would quickly corrode the plates in a conventional dry ESP. The wet ESP also offers the advantages of no rapping reentrainment and no sensitivity to fly ash resistivity. Therefore, this program has been structured around the use of a compact, wet ESP to control acid mist emissions. 7 refs.

Not Available

1990-01-01T23:59:59.000Z

38

Integrated low emission cleanup system for direct coal-fueled turbines (electrostatic agglomeration). Draft final technical report  

SciTech Connect (OSTI)

The objective of this contract was to investigate the removal of SO{sub x} and particulate matter from direct coal fired combustion gas streams at high temperature and high pressure conditions. This investigation was to be accomplished through a bench scale testing and evaluation program for SO{sub x} removal and the innovative particulate collection concept of particulate growth through electrostatic agglomeration followed by high efficiency mechanical collection. The process goal was to achieve control better than that required by 1979 New Source Performance Standards. During Phase I, the designs of the combustor and gas cleanup apparatus were successfully completed. Hot gas cleanup was designed to be accomplished at temperature levels between 1800{degrees} and 2500{degrees}F at pressures up to 15 atmospheres. The combustor gas flow rate could be varied between 0.2--0.5 pounds per second. The electrostatic agglomerator residence time could be varied between 0.25 to 3 seconds. In Phase II, all components were fabricated, and erected successfully. Test data from shakedown testing was obtained. Unpredictable difficulties in pilot plant erection and shakedown consumed more budget resources than was estimated and as a consequence DOE, METC, decided ft was best to complete the contract at the end of Phase II. Parameters studied in shakedown testing revealed that high-temperature high pressure electrostatics offers an alternative to barrier filtration in hot gas cleanup but more research is needed in successful system integration between the combustor and electrostatic agglomerator.

Quimby, J.M.; Kumar, K.S.

1992-12-31T23:59:59.000Z

39

Supercritical Water desulfurization of crude oil  

E-Print Network [OSTI]

Supercritical Water (SCW) desulfurization was investigated for both model sulfur compounds and Arab Heavy crude. In part 1, the reactions of alkyl sulfides in SCW were studied. During hexyl sulfide decomposition in SCW, ...

Kida, Yuko

2014-01-01T23:59:59.000Z

40

Two-stage coal gasification and desulfurization apparatus  

DOE Patents [OSTI]

The present invention is directed to a system which effectively integrates a two-stage, fixed-bed coal gasification arrangement with hot fuel gas desulfurization of a first stream of fuel gas from a lower stage of the two-stage gasifier and the removal of sulfur from the sulfur sorbent regeneration gas utilized in the fuel-gas desulfurization process by burning a second stream of fuel gas from the upper stage of the gasifier in a combustion device in the presence of calcium-containing material. The second stream of fuel gas is taken from above the fixed bed in the coal gasifier and is laden with ammonia, tar and sulfur values. This second stream of fuel gas is burned in the presence of excess air to provide heat energy sufficient to effect a calcium-sulfur compound forming reaction between the calcium-containing material and sulfur values carried by the regeneration gas and the second stream of fuel gas. Any ammonia values present in the fuel gas are decomposed during the combustion of the fuel gas in the combustion chamber. The substantially sulfur-free products of combustion may then be combined with the desulfurized fuel gas for providing a combustible fluid utilized for driving a prime mover.

Bissett, Larry A. (Morgantown, WV); Strickland, Larry D. (Morgantown, WV)

1991-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "desulfurization systems electrostatic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Integrated low emission cleanup system for direct coal-fueled turbines (electrostatic agglomeration)  

SciTech Connect (OSTI)

The objective of this contract is to investigate the removal of SO[sub x] and particulate matter from direct coal-fired combustion gas streams at high temperature and high pressure conditions. This investigation will be accomplished through a bench-scale testing and evaluation program employing sorbent mixed with a coal-water slurry for SO[sub x] removal, and an innovative particulate control concept. The particulate control device utilizes electrostatic agglomeration followed by a high efficiency mechanical collector (cyclone). The process goal is to achieve particulate collection efficiency better than that required by the 1979 new source performance standards. An additional goal is to demonstrate 70% SO[sub x] removal efficiency. This research project is now in the second of a 3 phase (phase II) project. Phase II is to fabricate the combustor and particulate control devices and install the system at a test facility located at Research-Cottrell's, KVB Western Laboratory, Santa Ana, CA. There are three functional categories, or tasks which are to be completed in sequence. These tasks are itemized as follows: design, procurement, and installation, shakedown and startup, and reporting.

Quimby, J.M.

1992-05-01T23:59:59.000Z

42

Exploring the Mechanism of Biocatalyst Inhibition in Microbial Desulfurization  

E-Print Network [OSTI]

Microbial desulfurization, or biodesulfurization (BDS), of fuels is a promising technology because it can desulfurize compounds that are recalcitrant to the current standard technology in the oil industry. One of the ...

Abin-Fuentes, Andres

43

LIFAC sorbent injection desulfurization demonstration project  

SciTech Connect (OSTI)

In December 1990, the US Department of Energy selected 13 projects for funding under the Federal Clean Coal Technology Program (Round 3). One of the projects selected was the project sponsored by LIFAC North America, (LIFAC NA), titled LIFAC Sorbent Injection Desulfurization Demonstration Project.'' The host site for this $17 million, three-phase project is Richmond Power and Light's Whitewater Valley Unit No. 2 in Richmond, Indiana. The LIFAC technology uses upper-furnace limestone injection with patented humidification of the flue gas to remove 75--80% of the sulfur dioxide (SO{sub 2}) in the flue gas. In November 1990, after a ten (10) month negotiation period, LIFAC NA and the US DOE entered into a Cooperative Agreement for the design, construction, and demonstration of the LIFAC system. This report is the first Technical Progress Report covering the period from project execution through the end of December 1990. Due to the power plant's planned outage schedule, and the time needed for engineering, design and procurement of critical equipment, DOE and LIFAC NA agreed to execute the Design Phase of the project in August 1990, with DOE funding contingent upon final signing of the Cooperative Agreement.

Not Available

1991-01-01T23:59:59.000Z

44

Method for desulfurization of coal  

DOE Patents [OSTI]

A process and apparatus for desulfurizing coal which removes sulfur in the inorganic and organic form by preferentially heating the inorganic iron sulfides in coal in a flowing gas to convert some of the inorganic iron sulfides from a pyrite form FeS.sub.2 to a troilite FeS form or a pyrrhotite form Fe.sub.1-x S and release some of the sulfur as a gaseous compound. The troilite and pyrrhotite forms are convenient catalyst for removing the organic sulfur in the next step, which is to react the coal with chemical agents such as alcohol, thus removing the organic sulfur as a liquid or a gas such as H.sub.2 S. The remaining inorganic sulfur is left in the predominantly higher magnetic form of pyrrhotite and is then removed by magnetic separation techniques. Optionally, an organic flocculant may be added after the organic sulfur has been removed and before magnetic separation. The flocculant attaches non-pyrite minerals with the pyrrhotite for removal by magnetic separation to reduce the ash-forming contents.

Kelland, David R. (Lexington, MA)

1987-01-01T23:59:59.000Z

45

Method for desulfurization of coal  

DOE Patents [OSTI]

A process and apparatus are disclosed for desulfurizing coal which removes sulfur in the inorganic and organic form by preferentially heating the inorganic iron sulfides in coal in a flowing gas to convert some of the inorganic iron sulfides from a pyrite form FeS[sub 2] to a troilite FeS form or a pyrrhotite form Fe[sub 1[minus]x]S and release some of the sulfur as a gaseous compound. The troilite and pyrrhotite forms are convenient catalyst for removing the organic sulfur in the next step, which is to react the coal with chemical agents such as alcohol, thus removing the organic sulfur as a liquid or a gas such as H[sub 2]S. The remaining inorganic sulfur is left in the predominantly higher magnetic form of pyrrhotite and is then removed by magnetic separation techniques. Optionally, an organic flocculant may be added after the organic sulfur has been removed and before magnetic separation. The flocculant attaches non-pyrite minerals with the pyrrhotite for removal by magnetic separation to reduce the ash-forming contents. 2 figs.

Kelland, D.R.

1987-07-07T23:59:59.000Z

46

Electrostatic precipitation of condensed acid mist  

SciTech Connect (OSTI)

This report deals with the second part (Phase 2) of a two-phased study of the control of acid mist emissions using a compact, wet electrostatic precipitator (WESP). The goal of the study was to determine the degree of acid mist control that could be achieved when a compact WESP was used to replace or augment the mist eliminators in a flue gas desulfurization (FGD) system. Phase 1 of the study examined the electrical operation of a lab-scale WESP collecting an acid mist from a coal combustion pilot plant equipped with a spray chamber. The results of this study were used to develop and validate a computer model of the WESP. In Phase 2, measurements were made at two utility scrubber installations to determine the loadings of acid mist, fly ash, and scrubber carryover. These measurements were used as input to the computer model to project the performance of retrofitted WESPs at both of the utility test sites. Phase 1 results showed that excellent electrical operating conditions could be achieved, but very high loadings of acid mist or the fine fly ash tended to degrade electrical operation because of space charge suppression of the corona current. Measurements made at the utility sites under Phase 2 showed that acid mist accounted for 40 to 57% of the total particulate mass, while fly ash and scrubber solids accounted for 40 to 55% and 1.0 to 3.4%. Impactor samples from both test sites showed an increase in acid content with decreasing particle size. 9 refs., 14 figs., 13 tabs.

Dahlin, R.S.

1991-04-01T23:59:59.000Z

47

Recombinant DNA encoding a desulfurization biocatalyst  

DOE Patents [OSTI]

This invention relates to a recombinant DNA molecule containing a gene or genes which encode a biocatalyst capable of desulfurizing a fossil fuel which contains organic sulfur molecules. For example, the present invention encompasses a recombinant DNA molecule containing a gene or genes of a strain of Rhodococcus rhodochrous. 13 figs.

Rambosek, J.; Piddington, C.S.; Kovacevich, B.R.; Young, K.D.; Denome, S.A.

1994-10-18T23:59:59.000Z

48

Electrostatic monitoring  

DOE Patents [OSTI]

The apparatus and method provide a technique for more simply measuring alpha and/or beta emissions arising from items or locations. The technique uses indirect monitoring of the emissions by detecting ions generated by the emissions, the ions being attracted electrostatically to electrodes for discharge of collection. The apparatus and method employ a chamber which is sealed around the item or location during monitoring with no air being drawn into or expelled from the chamber during the monitoring process. A simplified structure and operations arises as a result, but without impairing the efficiency and accuracy of the detection technique.

Orr, Christopher Henry (Cumbria, GB); Luff, Craig Janson (Cumbria, GB); Dockray, Thomas (Cumbria, GB); Macarthur, Duncan Whittemore (Los Alamos, NM)

2001-01-01T23:59:59.000Z

49

Evaluation of an Electrostatic Dust Removal System with Potential Application in Next-Step Fusion Devices  

SciTech Connect (OSTI)

The ability to manage inventories of carbon, tritium, and high-Z elements in fusion plasmas depends on means for effective dust removal. A dust conveyor, based on a moving electrostatic potential well, was tested with particles of tungsten, carbon, glass and sand. A digital microscope imaged a representative portion of the conveyor, and dust particle size and volume distributions were derived before and after operation. About 10 mm3 volume of carbon and tungsten particles were moved in under 5 seconds. The highest driving amplitude tested of 3 kV was the most effective. The optimal driving frequency was 210 Hz (maximum tested) for tungsten particles, decreasing to below 60 Hz for the larger sand particles. Measurements of particle size and volume distributions after 10 and 100 cycles show the breaking apart of agglomerated carbon, and the change in particle distribution over short timescales (<1 s).

Friesen, F. QL. [Grinnell College, 1115 8th Avenue, Grinnell, IA 50112-1616

2011-01-20T23:59:59.000Z

50

DESULFURIZATION OF COAL MODEL COMPOUNDS AND COAL LIQUIDS  

E-Print Network [OSTI]

Pollutants Associated With Coal Combustion. • E.P.A.Control Guidelines for Coal-Derived Pollutants .Forms of Sulfur in Coal • . . . . Coal Desulfurization

Wrathall, James Anthony

2011-01-01T23:59:59.000Z

51

Biobriefcase electrostatic aerosol collector  

DOE Patents [OSTI]

A system for sampling air and collecting particles entrained in the air comprising a receiving surface, a liquid input that directs liquid to the receiving surface and produces a liquid surface, an air input that directs the air so that the air with particles entrained in the air impact the liquid surface, and an electrostatic contact connected to the liquid that imparts an electric charge to the liquid. The particles potentially including bioagents become captured in the liquid by the air with particles entrained in the air impacting the liquid surface. Collection efficiency is improved by the electrostatic contact electrically charging the liquid. The effects of impaction and adhesion due to electrically charging the liquid allows a unique combination in a particle capture medium that has a low fluid consumption rate while maintaining high efficiency.

Bell, Perry M. (Tracy, CA); Christian, Allen T. (Madison, WI); Bailey, Christopher G. (Pleasanton, CA); Willis, Ladona (Manteca, CA); Masquelier, Donald A. (Tracy, CA); Nasarabadi, Shanavaz L. (Livermore, CA)

2009-03-17T23:59:59.000Z

52

Particle size effects in particle-particle triboelectric charging studied with an integrated fluidized bed and electrostatic separator system  

SciTech Connect (OSTI)

Fundamental studies of triboelectric charging of granular materials via particle-particle contact are challenging to control and interpret because of foreign material surfaces that are difficult to avoid during contacting and measurement. The measurement of particle charge itself can also induce charging, altering results. Here, we introduce a completely integrated fluidized bed and electrostatic separator system that charges particles solely by interparticle interactions and characterizes their charge on line. Particles are contacted in a free-surface fluidized bed (no reactor walls) with a well-controlled fountain-like flow to regulate particle-particle contact. The charged particles in the fountain are transferred by a pulsed jet of air to the top of a vertically-oriented electrostatic separator consisting of two electrodes at oppositely biased high voltage. The free-falling particles migrate towards the electrodes of opposite charge and are collected by an array of cups where their charge and size can be determined. We carried out experiments on a bidisperse size mixture of soda lime glass particles with systematically varying ratios of concentration. Results show that larger particles fall close to the negative electrode and smaller particles fall close to the positive electrode, consistent with theory and prior experiments that larger particles charge positively and smaller particles charge negatively. The segregation of particles by charge for one of the size components is strongest when its collisions are mostly with particles of the other size component; thus, small particles segregate most strongly to the negative sample when their concentration in the mixture is small (and analogous results occur for the large particles). Furthermore, we find additional size segregation due to granular flow, whereby the fountain becomes enriched in larger particles as the smaller particles are preferentially expelled from the fountain.

Bilici, Mihai A.; Toth, Joseph R.; Sankaran, R. Mohan; Lacks, Daniel J. [Department of Chemical and Biomolecular Engineering, Case Western Reserve University, Cleveland, Ohio 44106-7217 (United States)

2014-10-15T23:59:59.000Z

53

JOURNAL OF MICROELECTROMECHANICAL SYSTEMS, VOL. 14, NO. 2, APRIL 2005 295 Characterization of Electrostatically  

E-Print Network [OSTI]

Laurençot: A free boundary problem modelling a microelectromechanical system Pierluigi Colli: Phase field

Bigelow, Stephen

54

Separation of Mercury from Flue Gas Desulfurization Scrubber Produced Gypsum  

SciTech Connect (OSTI)

Frontier Geosciences (Frontier; FGS) proposed for DOE Grant No. DE-FG02-07ER84669 that mercury control could be achieved in a wet scrubber by the addition of an amendment to the wet-FGD scrubber. To demonstrate this, a bench-scale scrubber and synthetic flue-gas supply was designed to simulate the limestone fed, wet-desulfurization units utilized by coal-fired power plants. Frontier maintains that the mercury released from these utilities can be controlled and reduced by modifying the existing equipment at installations where wet flue-gas desulfurization (FGD) systems are employed. A key element of the proposal was FGS-PWN, a liquid-based mercury chelating agent, which can be employed as the amendment for removal of all mercury species which enter the wet-FGD scrubber. However, the equipment design presented in the proposal was inadequate to demonstrate these functions and no significant progress was made to substantiate these claims. As a result, funding for a Phase II continuation of this work will not be pursued. The key to implementing the technology as described in the proposal and report appears to be a high liquid-to-gas ratio (L/G) between the flue-gas and the scrubber liquor, a requirement not currently implemented in existing wet-FGD designs. It may be that this constraint can be reduced through parametric studies, but that was not apparent in this work. Unfortunately, the bench-scale system constructed for this project did not function as intended and the funds and time requested were exhausted before the separation studies could occur.

Hensman, Carl, E., P.h.D; Baker, Trevor

2008-06-16T23:59:59.000Z

55

Sorbent for use in hot gas desulfurization  

DOE Patents [OSTI]

A multiple metal oxide sorbent supported on a zeolite of substantially silicon oxide is used for the desulfurization of process gas streams, such as from a coal gasifier, at temperatures in the range of about 1200.degree. to about 1600.degree. F. The sorbent is provided by a mixture of copper oxide and manganese oxide and preferably such a mixture with molybdenum oxide. The manganese oxide and the molybdenum are believed to function as promoters for the reaction of hydrogen sulfide with copper oxide. Also, the manganese oxide inhibits the volatilization of the molybdenum oxide at the higher temperatures.

Gasper-Galvin, Lee D. (Washington, PA); Atimtay, Aysel T. (Cankaya, TR)

1993-01-01T23:59:59.000Z

56

Desulfurization of lignite using steam and air  

E-Print Network [OSTI]

with nitrogen to remove oxygen and then the drums were sealed until needed for a run. This procedure was used to prevent weathering and loss of moisture from the coal. Prior to charging, t' he lignite was sized to minus 18 mesh. The larg- er particles...DESULFURIZATION OF LIGNITE USING STEAM AND AIR A Thesis by GLENN ALLEN CARTER, JR. Submitted to the Graduate College of Texas A&M University in partial fulfillment of the degree of MASTER OF SCIENCE August 1982 Major Subject: Chemical...

Carter, Glenn Allen

1982-01-01T23:59:59.000Z

57

Electrostatically screened, voltage-controlled electrostatic chuck  

DOE Patents [OSTI]

Employing an electrostatically screened, voltage-controlled electrostatic chuck particularly suited for holding wafers and masks in sub-atmospheric operations will significantly reduce the likelihood of contaminant deposition on the substrates. The electrostatic chuck includes (1) an insulator block having a outer perimeter and a planar surface adapted to support the substrate and comprising at least one electrode (typically a pair of electrodes that are embedded in the insulator block), (2) a source of voltage that is connected to the at least one electrode, (3) a support base to which the insulator block is attached, and (4) a primary electrostatic shield ring member that is positioned around the outer perimeter of the insulator block. The electrostatic chuck permits control of the voltage of the lithographic substrate; in addition, it provides electrostatic shielding of the stray electric fields issuing from the sides of the electrostatic chuck. The shielding effectively prevents electric fields from wrapping around to the upper or front surface of the substrate, thereby eliminating electrostatic particle deposition.

Klebanoff, Leonard Elliott (San Ramon, CA)

2001-01-01T23:59:59.000Z

58

METC hot gas desulfurization program overview  

SciTech Connect (OSTI)

This overview provides a frame of reference for the Morgantown Energy Technology Center`s (METC`S) on-going hot gas desulfurization research. Although there are several methods to separate contaminant gases from fuel gases, that method receiving primary development is absorption through the use of metal oxides. Research into high-temperature and high-pressure control of sulfur species includes primarily those sorbents made of mixed-metal oxides, which offer the advantages of regenerability. These are predominantly composed of zinc and are made into media that can be utilized in reactors of either fixed-bed, moving-bed, fluidized-bed, or transport configurations. Zinc Ferrite (ZnO-Fe{sub 2}O{sub 3}), Zinc Titanate (ZnO-TiO{sub 2}), Z-SORP{reg_sign}, and METC-2/METC-6 are the current mixed-metal sorbents being investigated. The METC desulfurization program is composed of three major components: bench-scale research, pilot-plant operation, and demonstration that is a portion of the Clean Coal Demonstration projects.

Cicero, D.C.

1994-10-01T23:59:59.000Z

59

Ultrasound-promoted chemical desulfurization of Illinois coals  

SciTech Connect (OSTI)

The overall objectives of the program were to investigate the use of ultrasound to promote coal desulfurization reactions and to evaluate chemical coal desulfurization schemes under mild conditions through a fundamental understanding of their reaction mechanisms and kinetics. The ultimate goal was to develop an economically feasible mild chemical process to reduce the total sulfur content of Illinois Basin Coals, while retaining their original physical characteristics, such as calorific value and volatile matter content. During the program, potential chemical reactions with coal were surveyed under various ultrasonic irradiation conditions for desulfurization, to formulate preliminary reaction pathways, and to select a few of the more promising chemical processes for more extensive study.

Chao, S.S.

1991-01-01T23:59:59.000Z

60

Electrostatics and packing in biomolecules : accounting for conformational change in protein folding and binding  

E-Print Network [OSTI]

The role of electrostatics and packing in protein folding and molecular association was assessed in different biomolecular systems. A continuum electrostatic model was applied to long-range electrostatic effects in the ...

Caravella, Justin Andrew, 1974-

2002-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "desulfurization systems electrostatic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Controlling Nonpolar Colloidal Asphaltene Aggregation by Electrostatic Repulsion  

E-Print Network [OSTI]

truncates asphaltene precipitation and colloidal aggregation by enabling uniform electrostatic chargingControlling Nonpolar Colloidal Asphaltene Aggregation by Electrostatic Repulsion Sara M. Hashmi to petroleum oil systems to thermodynamically prevent asphaltene precipitation, amphiphilic dispersants can

Firoozabadi, Abbas

62

Anion-exchange resin-based desulfurization process  

SciTech Connect (OSTI)

The University of Tennessee Space Institute (UTSI) has been directed to further develop an anion-exchange, resin-based desulfurization concept. It is necessary that the soluble sulfates of alkali metal sorbents be desulfurized (regenerated) and recycled to make regenerative flue gas desulfurization options more attractive. In order to achieve this, a low-temperature, low-cost desulfurization process to reactivate spent alkali metal sorbents is necessary. UTSI's anion-exchange, resin-based concept is believed to satisfy this requirement. Investigators will perform the following investigations: screening of commercially available resins; process variables study and improving resin performance; optimization of resin-regeneration; evaluation of performance enhancers; development of Best-Process Schematic and related economics; and planing for proof-of-concept (POC) scale testing. 2 refs., 3 figs., 3 tabs.

Sheth, A.C.; Strevel, S.D.

1991-01-01T23:59:59.000Z

63

ELECTROSTATICALLY-ACTUATED RECONFIGURABLE ELASTOMER MICROFLUIDICS  

E-Print Network [OSTI]

ELECTROSTATICALLY-ACTUATED RECONFIGURABLE ELASTOMER MICROFLUIDICS Meng-Ping Chang1 , and Michel M a user-programmable reconfigurable elastomer microfluidic system which employs electrostatic actuation of water-filled elastomer microfluidic channels. Device actuation was achieved by applying 5 MHz, 15-20 V

Maharbiz, Michel

64

Preliminary evaluation of a process using plasma reactions to desulfurize heavy oils. Final report  

SciTech Connect (OSTI)

Western Research Institute (WRI) has conducted exploratory experiments on the use of microwave-induced plasmas to desulfurize heavy oils. Batch mode experiments were conducted in a quartz reactor system using various reactive and nonreactive plasmas. In these experiments a high-sulfur asphalt was exposed to various plasmas, and the degree of conversion to distillate, gas, and solids was recorded. Products from selected experiments were analyzed to determine if the plasma exposure had resulted in a significant reduction in sulfur content. Exploratory experiments were conducted using reactive plasmas generated from hydrogen and methane and nonreactive plasmas generated from nitrogen. The effects of varying exposure duration, sample temperature, and location of the sample with respect to the plasma discharge were investigated. For comparative purposes two experiments were conducted in which the sample was heated under nitrogen with no plasma exposure. Distillates containing approximately 28% less sulfur than the feedstock represented the maximum desulfurization attained in the plasma experiments. It does not appear that plasma reactions using the simple configurations employed in this study represent a viable method for the desulfurization of heavy oils.

Grimes, P.W.; Miknis, F.P.

1997-09-01T23:59:59.000Z

65

The role of the wet electrostatic precipitator in the coal-fired magnetohydrodynamics system  

SciTech Connect (OSTI)

According to the New Source Performance Standards (NSPS), particulate emissions from advanced energy conversion technologies must be less than 13 ng/J of energy input. Theoretical calculations as well as measurements made at the University of Tennessee Space Institute (UTSI) in the U.S. Department of Energy's Coal-Fired Flow Facility (CFFF) have indicated that a considerable fraction of the entrained particles in the coal-fired MHD system will be in sizes below 1 {mu}m. Thus, capturing very fine particles at an overall efficiency exceeding 99% presents a significant challenge for MHD. At the CFFF, A baghouse (BH) and a dry (ESP) are presently operated in parallel to capture such fine particulates. By the summer of 1992, a wet ESP (WESP) will be installed to replace the existing venturi scrubber/cyclone. In this paper, we have discussed the major differences between the dry and wet ESP; the principle of operation; advantages and disadvantages; and the preliminary bench scale results to identify the WESP's potential in separating soluble potassium salts. (VC)

Sheth, A.C.; Holt, J.K.; Douglas, J.R.; Thompson, B.R.

1992-01-01T23:59:59.000Z

66

The role of the wet electrostatic precipitator in the coal-fired magnetohydrodynamics system  

SciTech Connect (OSTI)

According to the New Source Performance Standards (NSPS), particulate emissions from advanced energy conversion technologies must be less than 13 ng/J of energy input. Theoretical calculations as well as measurements made at the University of Tennessee Space Institute (UTSI) in the U.S. Department of Energy`s Coal-Fired Flow Facility (CFFF) have indicated that a considerable fraction of the entrained particles in the coal-fired MHD system will be in sizes below 1 {mu}m. Thus, capturing very fine particles at an overall efficiency exceeding 99% presents a significant challenge for MHD. At the CFFF, A baghouse (BH) and a dry (ESP) are presently operated in parallel to capture such fine particulates. By the summer of 1992, a wet ESP (WESP) will be installed to replace the existing venturi scrubber/cyclone. In this paper, we have discussed the major differences between the dry and wet ESP; the principle of operation; advantages and disadvantages; and the preliminary bench scale results to identify the WESP`s potential in separating soluble potassium salts. (VC)

Sheth, A.C.; Holt, J.K.; Douglas, J.R.; Thompson, B.R.

1992-07-01T23:59:59.000Z

67

Electrostatic thin film chemical and biological sensor  

DOE Patents [OSTI]

A chemical and biological agent sensor includes an electrostatic thin film supported by a substrate. The film includes an electrostatic charged surface to attract predetermined biological and chemical agents of interest. A charge collector associated with said electrostatic thin film collects charge associated with surface defects in the electrostatic film induced by the predetermined biological and chemical agents of interest. A preferred sensing system includes a charge based deep level transient spectroscopy system to read out charges from the film and match responses to data sets regarding the agents of interest. A method for sensing biological and chemical agents includes providing a thin sensing film having a predetermined electrostatic charge. The film is exposed to an environment suspected of containing the biological and chemical agents. Quantum surface effects on the film are measured. Biological and/or chemical agents can be detected, identified and quantified based on the measured quantum surface effects.

Prelas, Mark A. (Columbia, MO); Ghosh, Tushar K. (Columbia, MO); Tompson, Jr., Robert V. (Columbia, MO); Viswanath, Dabir (Columbia, MO); Loyalka, Sudarshan K. (Columbia, MO)

2010-01-19T23:59:59.000Z

68

Integrated low emission cleanup system for direct coal-fueled turbines (electrostatic agglomeration). Project quarterly report, September 1, 1991--December 31, 1991  

SciTech Connect (OSTI)

The objective of this contract is to investigate the removal of SO{sub x} and particulate matter from direct coal-fired combustion gas streams at high temperature and high pressure conditions. This investigation will be accomplished through a bench-scale testing and evaluation program employing sorbent mixed with a coal-water slurry for SO{sub x} removal, and an innovative particulate control concept. The particulate control device utilizes electrostatic agglomeration followed by a high efficiency mechanical collector (cyclone). The process goal is to achieve particulate collection efficiency better than that required by the 1979 new source performance standards. An additional goal is to demonstrate 70% SO{sub x} removal efficiency. This research project is now in the second of a 3 phase (Phase II) project. Phase II is to fabricate the combustor and particulate control devices and install the system at a test facility located at Research-Cottrell`s, KVB Western Laboratory, Santa Ana, CA. There are three functional categories, or tasks which are to be completed in sequence. These tasks are itemized as follows: Design, procurement, and installation; Shakedown and startup; Reporting. Attempts to validate the concept of electrostatic agglomeration were not possible in the shakedown program before budget constraints halted the program. What was learned was that electrostatic precipitation is feasible in the temperature range of 1600--1800{degrees}F and at pressures above 10 atmospheres.

Quimby, J.M.

1992-02-01T23:59:59.000Z

69

Fast Neutral Generation by Charge Exchange Reaction and Its Effect on Neutron Production Rate in Inertial Electrostatic Confinement Fusion Systems  

SciTech Connect (OSTI)

Fast neutral generation by charge exchange reaction in inertial electrostatic confinement plasmas is studied by solving the Poisson equation and the Boltzmann equation for fast neutrals. Fusion reactions carried by the charge exchange fast neutrals become appreciable compared with ion-background fusion reaction. It is shown that the fusion reaction between fast neutral and background gas is sensitively affected by experimental parameters (grid voltage, background gas pressure) and ion distribution function.

Yoshinaga, S.; Matsuura, H.; Nakao, Y.; Kudo, K. [Kyushu University (Japan)

2005-05-15T23:59:59.000Z

70

DropBot: An open-source digital microfluidic control system with precise control of electrostatic driving force and instantaneous drop velocity measurement  

SciTech Connect (OSTI)

We introduce DropBot: an open-source instrument for digital microfluidics (http://microfluidics.utoronto.ca/dropbot). DropBot features two key functionalities for digital microfluidics: (1) real-time monitoring of instantaneous drop velocity (which we propose is a proxy for resistive forces), and (2) application of constant electrostatic driving forces through compensation for amplifier-loading and device capacitance. We anticipate that this system will enhance insight into failure modes and lead to new strategies for improved device reliability, and will be useful for the growing number of users who are adopting digital microfluidics for automated, miniaturized laboratory operation.

Fobel, Ryan [Institute for Biomaterials and Biomedical Engineering, University of Toronto, 164 College St., Toronto, Ontario M5S 3G9 (Canada) [Institute for Biomaterials and Biomedical Engineering, University of Toronto, 164 College St., Toronto, Ontario M5S 3G9 (Canada); Donnelly Centre for Cellular and Biomolecular Research, 160 College St., Toronto, Ontario M5S 3E1 (Canada); Fobel, Christian [School of Computer Science, University of Guelph, 50 Stone Road East, Guelph, Ontario N1G 2W1 (Canada)] [School of Computer Science, University of Guelph, 50 Stone Road East, Guelph, Ontario N1G 2W1 (Canada); Wheeler, Aaron R. [Institute for Biomaterials and Biomedical Engineering, University of Toronto, 164 College St., Toronto, Ontario M5S 3G9 (Canada) [Institute for Biomaterials and Biomedical Engineering, University of Toronto, 164 College St., Toronto, Ontario M5S 3G9 (Canada); Donnelly Centre for Cellular and Biomolecular Research, 160 College St., Toronto, Ontario M5S 3E1 (Canada); Department of Chemistry, University of Toronto, 80 St. George St., Toronto, Ontario M5S 3H6 (Canada)

2013-05-13T23:59:59.000Z

71

KINETICS OF HOT-GAS DESULFURIZATION SORBENTS FOR TRANSPORT REACTORS  

SciTech Connect (OSTI)

Hot-gas desulfurization for the integrated gasification combined cycle (IGCC) process has been investigated by many researchers to remove effectively hydrogen sulfide with various metal oxide sorbents at elevated temperatures. Various metal oxide sorbents are formulated with metal oxides such as Fe, Co, Zn, and Ti. Initial reaction kinetics of formulated sorbents with hydrogen sulfide is studied in the presence of various amounts of moisture and hydrogen at various reaction temperatures. The objectives of this research are to study initial reaction kinetics for a sorbent-hydrogen sulfide heterogeneous reaction system, to investigate effects of concentrations of hydrogen sulfide, hydrogen, and moisture on dynamic absorption of H{sub 2}S into sorbents, and to evaluate effects of temperature and sorbent amounts on dynamic absorption of H{sub 2}S into sorbents. Experimental data on initial reaction kinetics of hydrogen sulfide with metal oxide sorbents were obtained with a 0.83-cm{sup 3} differential reactor. In this report, the reactivity of AHI-5 was examined. This sorbent was obtained from the Research Triangle Institute (RTI). The sorbent in the form of 70 {micro}m particles are reacted with 9000-18000 ppm hydrogen sulfide at 350-500 C. The range of space time of reaction gas mixtures is 0.071-0.088 s. The range of reaction duration is 4-10800 s.

K.C. Kwon

2001-01-01T23:59:59.000Z

72

KINETICS OF HOT-GAS DESULFURIZATION SORBENTS FOR TRANSPORT REACTORS  

SciTech Connect (OSTI)

Hot-gas desulfurization for the integrated gasification combined cycle (IGCC) process has been investigated by many researchers to remove effectively hydrogen sulfide with various metal oxide sorbents at elevated temperatures. Various metal oxide sorbents are formulated with metal oxides such as Fe, Co, Zn, and Ti. Initial reaction kinetics of formulated sorbents with hydrogen sulfide is studied in the presence of various amounts of moisture and hydrogen at various reaction temperatures. The objectives of this research are to study initial reaction kinetics for a sorbent-hydrogen sulfide heterogeneous reaction system, to investigate effects of concentrations of hydrogen sulfide, hydrogen, and moisture on dynamic absorption of H{sub 2}S into sorbents, and to evaluate effects of temperature and sorbent amounts on dynamic absorption of H{sub 2}S into sorbents. Experimental data on initial reaction kinetics of hydrogen sulfide with metal oxide sorbents were obtained with a 0.83-cm{sup 3} differential reactor. The reactivity of MCRH-67 was examined in this report. This sorbent was obtained from the Research Triangle Institute (RTI). The sorbent in the form of 130 mm particles are reacted with 18000-ppm hydrogen sulfide at 350-525 C. The range of space time of reaction gas mixtures is 0.069-0.088 s. The range of reaction duration is 4-180 s.

K.C. Kwon

2002-01-01T23:59:59.000Z

73

Micromachined electrostatic vertical actuator  

DOE Patents [OSTI]

A micromachined vertical actuator utilizing a levitational force, such as in electrostatic comb drives, provides vertical actuation that is relatively linear in actuation for control, and can be readily combined with parallel plate capacitive position sensing for position control. The micromachined electrostatic vertical actuator provides accurate movement in the sub-micron to micron ranges which is desirable in the phase modulation instrument, such as optical phase shifting. For example, compact, inexpensive, and position controllable micromirrors utilizing an electrostatic vertical actuator can replace the large, expensive, and difficult-to-maintain piezoelectric actuators. A thirty pound piezoelectric actuator with corner cube reflectors, as utilized in a phase shifting diffraction interferometer can be replaced with a micromirror and a lens. For any very precise and small amplitudes of motion` micromachined electrostatic actuation may be used because it is the most compact in size, with low power consumption and has more straightforward sensing and control options.

Lee, Abraham P. (Walnut Creek, CA); Sommargren, Gary E. (Santa Cruz, CA); McConaghy, Charles F. (Livermore, CA); Krulevitch, Peter A. (Pleasanton, CA)

1999-10-19T23:59:59.000Z

74

Bench-scale demonstration of hot-gas desulfurization technology. Quarterly report, October 1 - December 31, 1994  

SciTech Connect (OSTI)

The U.S. Department of Energy (DOE), Morgantown Energy Technology Center (METC), is sponsoring research in advanced methods for controlling contaminants in hot coal gasifier gas (coal gas) streams of integrated gasification combined-cycle (IGCC) power systems. The programs focus on hot-gas particulate removal and desulfurization technologies that match or nearly match the temperatures and pressures of the gasifier, cleanup system, and power generator. The work seeks to eliminate the need for expensive heat recovery equipment, reduce efficiency losses due to quenching, and minimize wastewater treatment costs. Hot-gas desulfurization research has focused on regenerable mixed-metal oxide sorbents which can reduce the sulfur in coal gas to less than 20 ppmv and can be regenerated in a cyclic manner with air for multicycle operation. Zinc titanate (Zn{sub 2}TiO{sub 4} or ZnTiO{sub 3}), formed by a solid-state reaction of zinc (ZnO) and titanium dioxide (TiO{sub 2}), is currently one of the leading sorbents. This report summarizes the highlights and accomplishments of the October slipstream test run of the Zinc Titanate Fluid Bed Desulfurization/Direct Sulfur Recovery Process (ZTFBD/DSRP) Mobile Laboratory at the Department of Energy`s Morgantown Energy Technology Center. Although the run had to be shortened due to mechanical problems with METC`s gasifier, there was sufficient on-stream time to demonstrate highly successful operation of both the zinc titanate fluid bed desulfurization and the DSRP with actual coal gas.

NONE

1994-12-31T23:59:59.000Z

75

Assessment of operating parameter variation on electrostatic precipitator performance  

E-Print Network [OSTI]

lignite coal were collected and resistivity analysis performed for varying conditions of temperature and humidity. As a result of the laboratory analysis, it was determined that moisture and temperature conditioning of Texas lignite coal fly ash... results. I 5. Sample 8 moisturi ed test results. 57 64 66 69 77 LIST OF FIGURES Figure Lignite coal deposit formations in East Texas. Z. The electrostatic precipitator system 3. Electrostatic precipitator in operation. 4. Electrostatic...

Gunn, Roam Anthony

1974-01-01T23:59:59.000Z

76

Thermostabilization of desulfurization enzymes from Rhodococcos sp. IGTS8. Final technical report  

SciTech Connect (OSTI)

The objective of this project was to develop thermophilic cultures capable of expressing the desulfurization (dsz) operon of Rhodococcus sp. IGTS8. The approaches taken in this project included the development of plasmid and integrative expression vectors that function well in Thermus thermophilus, the cloning of Rhodococcus dsz genes in Thermus expression vectors, and the isolation of bacterial cultures that express the dsz operon at thermophilic temperatures. This project has resulted in the development of plasmid and integrative expression vectors for use in T. thermophilus. The dsz genes have been expressed at moderately thermophilic temperatures (52 C) in Mycobacterium phlei and at temperatures as high as 72 C in T. thermophilus. The tools and methods developed in this project will be generally useful for the expression of heterologous genes in Thermus. Key developments in the project have been the isolation of a Mycobacterium phlei culture capable of expressing the desulfurization operon at 52 C, development of plasmid and integrative expression vectors for Thermus thermophilus, and the development of a host-vector system based on the malate dehydrogenase gene that allows plasmids to be stably maintained in T. thermophilus and provides a convenient reporter gene for the accurate quantification of gene expression. Publications have been prepared regarding each of these topics; these preprints are included.

John J. Kilbane II

2000-12-15T23:59:59.000Z

77

Hot coal gas desulfurization with manganese-based sorbents. Final report, September 1992--December 1994  

SciTech Connect (OSTI)

The focus of much current work being performed by the Morgantown Energy Technology Center (METC) of the Department of Energy on hot coal-derived fuel gas desulfurization is in the use of zinc-based sorbents. METC has shown interest in formulating and testing manganese-based pellets as alternative effective sulfur sorbents in the 700 to 1200{degree}C temperature range. To substantiate the potential superiority of Mn-based pellets, a systematic approach toward the evaluation of the desulfurizing power of single-metal sorbents is developed based on thermodynamic considerations. This novel procedure considered several metal-based sorbents and singled out manganese oxide as a prime candidate sorbent capable of being utilized under a wide temperature range, irrespective of the reducing power (determined by CO{sub 2}/CO ratio) of the fuel gas. Then, the thermodynamic feasibility of using Mn-based pellets for the removal of H{sub 2}S from hot-coal derived fuel gases, and the subsequent oxidative regeneration of loaded (sulfided) pellets was established. It was concluded that MnO is the stable form of manganese for virtually all commercially available coal-derived fuel gases. In addition, the objective of reducing the H{sub 2}S concentration below 150 ppMv to satisfy the integrated gasification combined cycle system requirement was shown to be thermodynamically feasible. A novel process is developed for the manufacture of Mn-based spherical pellets which have the desired physical and chemical characteristics required.

Hepworth, M.T.; Slimane, R.B.

1994-11-01T23:59:59.000Z

78

Oxidative desulfurization of dibenzothiophene with tert-butyl hydro peroxide in a photochemical micro-reactor.  

E-Print Network [OSTI]

??Sulfur content in fuels is an increasingly critical environmental issue. Hydrodesulfurization removes sulfur from hydrocarbons; however, further desulfurization is necessary in fuels. New methods are… (more)

Hebert, Eilleen M.

2007-01-01T23:59:59.000Z

79

Electrostatic particle trap for ion beam sputter deposition  

DOE Patents [OSTI]

A method and apparatus for the interception and trapping of or reflection of charged particulate matter generated in ion beam sputter deposition. The apparatus involves an electrostatic particle trap which generates electrostatic fields in the vicinity of the substrate on which target material is being deposited. The electrostatic particle trap consists of an array of electrode surfaces, each maintained at an electrostatic potential, and with their surfaces parallel or perpendicular to the surface of the substrate. The method involves interception and trapping of or reflection of charged particles achieved by generating electrostatic fields in the vicinity of the substrate, and configuring the fields to force the charged particulate material away from the substrate. The electrostatic charged particle trap enables prevention of charged particles from being deposited on the substrate thereby enabling the deposition of extremely low defect density films, such as required for reflective masks of an extreme ultraviolet lithography (EUVL) system.

Vernon, Stephen P. (Pleasanton, CA); Burkhart, Scott C. (Livermore, CA)

2002-01-01T23:59:59.000Z

80

Desulfurization of Texas lignite using steam and air  

E-Print Network [OSTI]

OESULFURIZATION OF TEXAS LIGNITE USI, IG STEA 1 ANO AIR A Thesis by ROSERT REGINALD STONE Submitted to the Graduate College of Texas AIIN University in partial fulfillment of the requirement for the degree of , 'RASTER OF SCIENCE August 1981... Major Subject: Chemical Engineering DESULFURIZATION OF TEXAS LIGNITE USING STEAM AND AIR A Thesis by ROBERT REGINALD STONE Approved as to style and content by: Dr. . A . Bulli n ( Chai rman of Committee) R. G. Anthony (Member) J. W. J ni ngs ( ber...

Stone, Robert Reginald

1981-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "desulfurization systems electrostatic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Hot coal gas desulfurization with manganese-based sorbents  

SciTech Connect (OSTI)

The primary major deposit of manganese in the US which can be readily mined by an in situ process is located in the Emily district of Minnesota. The US Bureau of Mines Research Centers at both the Twin Cities and Salt Lake City have developed a process for extracting and refining manganese in the form of a high-purity carbonate product. This product has been formulated into pellets by a multi-step process of drying, calcination, and induration to produce relatively high-strength formulations which are capable of being used for hot fuel gas desulfurization. These pellets, which have been developed at the University of Minnesota under joint sponsorship of the US Department of Energy and the US Bureau of Mines, appear superior to other, more expensive, formulations of zinc titanate and zinc ferrite which have previously been studied for multi-cycle loading (desulfurization) and regeneration (evolution of high-strength SO{sub 2} and restoration of pellet reactivity). Although these other formulations have been under development for the past twelve years, their prices still exceed $7 per pound. If manganese pellets perform as predicted in fixed bed testing, and if a significant number of utilities which burn high-sulfur coals incorporate combined-cycle gasification with hot coal gas desulfurization as a viable means of increasing conversion efficiencies, then the potential market for manganese pellets may be as high as 200,000 tons per year at a price not less than $3 per pound. This paper discusses the role of manganese pellets in the desulfurization process with respect to the integrated gasification combined-cycle (IGCC) for power generation.

Hepworth, M.T.; Ben-Slimane, R.

1995-11-01T23:59:59.000Z

82

Confined zone dispersion flue gas desulfurization demonstration  

SciTech Connect (OSTI)

Under the Cooperative Agreement with DOE, Bechtel and Pennsylvania Electric Company (Penelec) will jointly demonstrate Bechtel's confined zone dispersion (CZD) process for removing both sulfur and nitrogen pollutants from the flue gases leaving a coal-fired boiler. Demonstration testing of the CZD process will be conducted on the 147 MWe coal-fired generating Seward Station Unit 15 of Penelec. The test will utilize one-half of the existing flue gas capacity, and will be designed to demonstrate the viability of the process and its operability at a total cost of less than $300/ton of SO{sub 2} removed. The CZD process involves injecting a finely atomized slurry of reactive lime into the duct work of a coal-fired utility boiler. The principle of the confined zone is to form a wet zone of slurry droplets in the middle of the duct confined in an envelope of hot gas between the wet zone and the duct walls. The lime slurry reacts with part of the sulfur dioxide (SO{sub 2}) in the gas, and the reaction products dry to form solid particles. An electrostatic precipitator (ESP) downstream from the point of injection captures the reaction products, along with the fly ash entrained in the flue gas. 2 figs.

Not Available

1991-02-22T23:59:59.000Z

83

JOURNAL OF MICROELECTROMECHANICAL SYSTEMS, VOL. 15, NO. 5, OCTOBER 2006 1165 Flatness-Based Control of Electrostatically Actuated  

E-Print Network [OSTI]

to a number of applications at the micrometer or nanometer scale, such as microelectromechanical systems (7

Paris-Sud XI, Université de

84

Electrostatic curtain studies  

SciTech Connect (OSTI)

This report presents the results of experiments using electrostatic curtains (ESCS) as a transuranic (TRU) contamination control technique. The TRU contaminants included small (micrometer to sub micrometer) particles of plutonium and americium compounds associated with defense-related waste. Three series of experiments were conducted. The first was with uncontaminated Idaho National Engineering Laboratory (INEL) soil, the second used contaminated soil containing plutonium-239 (from a mixture of Rocky Flats Plant contaminated soil and INEL uncontaminated soil), and the third was uncontaminated INEL soil spiked with plutonium-239. All experiments with contaminated soil were conducted inside a glove box containing a dust generator, low volume cascade impactor (LVCI), electrostatic separator, and electrostatic materials. The data for these experiments consisted of the mass of dust collected on the various material coupons, plates, and filters; radiochemical analysis of selected samples; and photographs, as well as computer printouts giving particle size distributions and dimensions from the scanning electron microscope (SEM). The following results were found: (a) plutonium content (pCi/g) was found to increase with smaller soil particle sizes and (b) the electrostatic field had a stronger influence on smaller particle sizes compared to larger particle sizes. The SEM analysis indicated that the particle size of the tracer Pu239 used in the spiked soil experiments was below the detectable size limit (0.5 {mu}m) of the SEM and, thus, may not be representative of plutonium particles found in defense-related waste. The use of radiochemical analysis indicated that plutonium could be found on separator plates of both polarities, as well as passing through the electric field and collecting on LVCI filters.

Meyer, L C

1992-05-01T23:59:59.000Z

85

Performance of two fluid bed sludge incinerators with air pollution control systems consisting of a venturi scrubber and wet electrostatic precipitator  

SciTech Connect (OSTI)

Performance tests were recently conducted on two new Hankin Fluid Bed Incineration Systems installed at publicly owned sewage treatment works in New Jersey. The purpose of the tests was to show that the systems met emission limits set by the New Jersey Department of Environmental Protection and Energy (NJDEPE), and that the systems met throughput and fuel consumption requirements. These systems, consisting of a fluid bed incinerator, heat exchanger, venturi scrubber, tray cooler, and wet electrostatic precipitator, were tested for emissions of heavy metals, sulfur oxides, nitrogen oxides, hydrogen chloride, carbon monoxide, volatile organic compounds, and opacity. Both yielded emissions that were well within the stringent limits set by the NJDEPE in the operating permits. The incinerators exhibited a high level of fuel efficiency with fuel oil consumption averaging 5.5 and 6.0 gallons per ton of wet sludge. In addition, combustion efficiency was high, with a maximum average CO of 7.39 ppmvd and VOCs of 1.39 ppmvd (both corrected to 7% O{sub 2}). The air pollution control equipment showed very high removal efficiencies. Except for Mercury, collection efficiencies for all heavy metals fell within 98.7% to 99.999%. Particulate collection efficiency averaged 99.97 and 99.99%. Collection efficiency for HCl averaged 99.2% and 99.92%, and for SO{sub 2} averages were 97.1% and 94.8%. Finally, the level of NO{sub x} in the stack was extremely low with averages of 17.33 ppmvd and 14.19 ppmvd (corrected to 7% O{sub 2}) for the two systems.

Zaman, R.U. [Hankin Environmental Systems Inc., Somerville, NJ (United States)

1995-12-31T23:59:59.000Z

86

Desulfurization of organic sulfur from lignite by an electron transfer process  

SciTech Connect (OSTI)

This study is an attempt to desulfurize organic sulfur from lignite samples with ferrocyanide ion as the electron transferring agent. Effect of temperature, particle size and concentration of ferrocyanide ion on desulfurization from the lignite samples has been investigated. The desulfurization process has been found to be continuous and gradually increases with increase of temperature from 298 to 368 K. The particle size has no significant impact on sulfur removal from the lignite samples. Particle size has no profound impact on the amount of sulfur removal. The desulfurization reaction has been found to be dependent on the concentration of potassium ferrocyanide. Gradual increase in the concentration of potassium ferrocyanide raised the magnitude of desulfurization, but at a higher concentration, the variation is not significant.

Demirbas, A. [Selcuk University, Konya (Turkey). Dept. for Chemical Engineering

2006-10-15T23:59:59.000Z

87

Integrated low emission cleanup system for direct coal-fueled turbines (electrostatic agglomeration). Project quarterly report, January 1, 1992--March 31, 1992  

SciTech Connect (OSTI)

The objective of this contract is to investigate the removal of SO{sub x} and particulate matter from direct coal-fired combustion gas streams at high temperature and high pressure conditions. This investigation will be accomplished through a bench-scale testing and evaluation program employing sorbent mixed with a coal-water slurry for SO{sub x} removal, and an innovative particulate control concept. The particulate control device utilizes electrostatic agglomeration followed by a high efficiency mechanical collector (cyclone). The process goal is to achieve particulate collection efficiency better than that required by the 1979 new source performance standards. An additional goal is to demonstrate 70% SO{sub x} removal efficiency. This research project is now in the second of a 3 phase (phase II) project. Phase II is to fabricate the combustor and particulate control devices and install the system at a test facility located at Research-Cottrell`s, KVB Western Laboratory, Santa Ana, CA. There are three functional categories, or tasks which are to be completed in sequence. These tasks are itemized as follows: design, procurement, and installation, shakedown and startup, and reporting.

Quimby, J.M.

1992-05-01T23:59:59.000Z

88

Field-and concentration-dependence of electrostatics in non-polar colloidal asphaltene suspensions  

E-Print Network [OSTI]

Field- and concentration-dependence of electrostatics in non-polar colloidal asphaltene suspensions.1039/c2sm06865f Electrostatic stabilization has recently been found to be an important factor in non-range nature of electrostatics in non-polar systems, electrophoretic mobility can depend on both electric

Firoozabadi, Abbas

89

The desulfurization of flue gas at the Mae Moh Power Plant Units 12 and 13  

SciTech Connect (OSTI)

As pollution of air, water and ground increasingly raises worldwide concern, the responsible national and international authorities establish and issue stringent regulations in order to maintain an acceptable air quality in the environment. In Thailand, the Electricity Generating Authority of Thailand (EGAT) takes full responsibility in environmental protection matters as well as in generating the electricity needed to supply the country`s very rapid power demand growth. Due to the rapidly increasing electricity demand of the country, EGAT had decided to install two further lignite-fired units of 300 MW each (Units 12 and 13) at the Mae Moh power generation station and they are now under construction. The arrangement and the capacity of all the power plant units are as shown. In 1989, EGAT started the work on the flue gas desulfurization system of Mae Moh power plant units 12 and 13 as planned. A study has been conducted to select the most suitable and most economical process for flue gas desulfurization. The wet scrubbing limestone process was finally selected for the two new units. Local limestone will be utilized in the process, producing a by-product of gypsum. Unfortunately, natural gypsum is found in abundance in Thailand, so the produced gypsum will be treated as landfill by mixing it with ash from the boilers of the power plants and then carrying it to the ash dumping area. The water from the waste ash water lake is utilized in the process as much as possible to minimize the requirement of service water, which is a limited resource. The Mae Moh power generation station is situated in the northern region of Thailand, 600 km north of Bangkok and about 30 km east of the town of Lampang, close to the Mae Moh lignite mine. Three lignite-fired units (Units 1-3) of 75 MW each, four units (Units 4-7) of 150 MW each and four units (Units 8-11) of 300 MW each are in operation.

Haemapun, C.

1993-12-31T23:59:59.000Z

90

Anion-exchange resin-based desulfurization process  

SciTech Connect (OSTI)

Under the current grant (FG22-90PC90309), the University of Tennessee Space Institute (UTSI) will carry out the necessary bench scale experiments to further develop it anion-exchange, resin-based desulfurization concept to desulfurize alkali metal sulfates. In particular, it is planned to screen commercially available resins and then carry out process optimization work with three selected resins. Further optimization of the resin regeneration step as well as evaluation of the effect of various performance enhancers will then be carried out with one selected resin. A process schematic, to be developed based on the bench scale results, will be used to estimate the related economics. Some limited scope testing will also be carried out using the spent-seed and sorbent materials obtained from both the coal-fired magnetohydrodynamics (MHD) and the in-duct sorbent injection pilot scale facilities. During this reporting period, 90% of the planned batch mode screening experiments for the eleven samples of candidate resins were completed. Preliminary evaluation of the resulting data is continuing in order to select a smaller number (3--4) of samples for screening in the fixed-bed setup. The installation of the semi-automated fixed-bed setup is about 70% complete and shakedown experiments will be started in 3--4 weeks. Progress made in relation to these activities is presented below. 2 figs., 3 tabs.

Sheth, A.C.; Strevel, S.D.

1991-01-01T23:59:59.000Z

91

Method for enhancing the desulfurization of hot coal gas in a fluid-bed coal gasifier  

DOE Patents [OSTI]

A process and apparatus for providing additional desulfurization of the hot gas produced in a fluid-bed coal gasifier, within the gasifier. A fluid-bed of iron oxide is located inside the gasifier above the gasification bed in a fluid-bed coal gasifier in which in-bed desulfurization by lime/limestone takes place. The product gases leave the gasification bed typically at 1600.degree. to 1800.degree. F. and are partially quenched with water to 1000.degree. to 1200.degree. F. before entering the iron oxide bed. The iron oxide bed provides additional desulfurization beyond that provided by the lime/limestone.

Grindley, Thomas (Morgantown, WV)

1989-01-01T23:59:59.000Z

92

ADVANCED SULFUR CONTROL CONCEPTS FOR HOT-GAS DESULFURIZATION TECHNOLOGY  

SciTech Connect (OSTI)

This research project examined the feasibility of a second generation high-temperature coal gas desulfurization process in which elemental sulfur is produced directly during the sorbent regeneration phase. Two concepts were evaluated experimentally. In the first, FeS was regenerated in a H2O-O2 mixture. Large fractions of the sulfur were liberated in elemental form when the H2O-O2 ratio was large. However, the mole percent of elemental sulfur in the product was always quite small (<<1%) and a process based on this concept was judged to be impractical because of the low temperature and high energy requirements associated with condensing the sulfur. The second concept involved desulfurization using CeO2 and regeneration of the sulfided sorbent, Ce2O2S, using SO2 to produce elemental sulfur directly. No significant side reactions were observed and the reaction was found to be quite rapid over the temperature range of 500°C to 700°C. Elemental sulfur concentrations (as S2) as large as 20 mol% were produced. Limitations associated with the cerium sorbent process are concentrated in the desulfurization phase. High temperature and highly reducing coal gas such as produced in the Shell gasification process are required if high sulfur removal efficiencies are to be achieved. For example, the equilibrium H2S concentration at 800°C from a Shell gas in contact with CeO2 is about 300 ppmv, well above the allowable IGCC specification. In this case, a two-stage desulfurization process using CeO2 for bulk H2S removal following by a zinc sorbent polishing step would be required. Under appropriate conditions, however, CeO2 can be reduced to non-stoichiometric CeOn (n<2) which has significantly greater affinity for H2S. Pre-breakthrough H2S concentrations in the range of 1 ppmv to 5 ppmv were measured in sulfidation tests using CeOn at 700°C in highly reducing gases, as measured by equilibrium O2 concentration, comparable to the Shell gas. Good sorbent durability was indicated in a twenty-five-cycle test. The sorbent was exposed for 58 consecutive days to temperatures between 600°C and 800°C and gas atmospheres from highly reducing to highly oxidizing without measurable loss of sulfur capacity or reactivity. In the process analysis phase of this study, a two-stage desulfurization process using cerium sorbent with SO2 regeneration followed by zinc sorbent with dilute O2 regeneration was compared to a single-stage process using zinc sorbent and O2 regeneration with SO2 in the regeneration product gas converted to elemental sulfur using the direct sulfur recovery process (DSRP). Material and energy balances were calculated using the process simulation package PRO/II. Major process equipment was sized and a preliminary economic analysis completed. Sorbent replacement rate, which is determined by the multicycle sorbent durability, was found to be the most significant factor in both processes. For large replacement rates corresponding to average sorbent lifetimes of 250 cycles or less, the single-stage zinc sorbent process with DSRP was estimated to be less costly. However, the cost of the two-stage cerium sorbent process was more sensitive to sorbent replacement rate, and, as the required replacement rate decreased, the economics of the two-stage process improved. For small sorbent replacement rates corresponding to average sorbent lifetimes of 1000 cycles or more, the two-stage cerium process was estimated to be less costly. In the relatively wide middle range of sorbent replacement rates, the relative economics of the two processes depends on other factors such as the unit cost of sorbents, oxygen, nitrogen, and the relative capital costs.

A. LOPEZ ORTIZ; D.P. HARRISON; F.R. GROVES; J.D. WHITE; S. ZHANG; W.-N. HUANG; Y. ZENG

1998-10-31T23:59:59.000Z

93

Confined zone dispersion flue gas desulfurization demonstration  

SciTech Connect (OSTI)

This is the fifth quarterly report for this project. This project is divided into three phases. Phase 1, which has been completed, involved design, engineering, and procurement for the CZD system, duct and facility modifications, and supporting equipment. Phase 2, also completed, included equipment acquisition and installation, facility construction, startup, and operator training for parametric testing. Phase 3 broadly covers testing, operation and disposition, but only a portion of Phase 3 was included in Budget Period 1. That portion was concerned with parametric testing of the CZD system to establish the optimum conditions for an extended, one-year, continuous demonstration. As of December 31, 1991, the following goals have been achieved. (1) Nozzle Selection - A modified Spraying Systems Company (SSC) atomizing nozzle has been selected for the one-year continuous CZD demonstration. (2) SO[sub 2] and NO[sub x] Reduction - Preliminary confirmation of 50% SO[sub 2] reduction has been achieved, but the NO[sub x] reduction target cannot be confirmed at this time. (3) Lime Selection - Testing indicated an injection rate of 40 to 50 gallons per minute with a lime slurry concentration of 8 to 10% to achieve 50% SO[sub 2] reduction. There has been no selection of the lime to be used in the one year demonstration. (4) ESP Optimization - Tests conducted to date have shown that lime injection has a very beneficial effect on ESP performance, and little adjustment may be necessary. (5) SO[sub 2] Removal Costs - Testing has not revealed any significant departure from the bases on which Bechtel's original cost estimates (capital and operating) were prepared. Therefore, SO[sub 2] removal costs are still expected to be in the range of $300/ton or less.

Not Available

1992-12-31T23:59:59.000Z

94

ELECTROSTATICALLY ENHANCED BARRIER FILTER COLLECTION  

SciTech Connect (OSTI)

This work was performed through the University of North Dakota (UND) Chemical Engineering Department with assistance from UND's Energy & Environmental Research Center. This research was undertaken in response to the U.S. Department of Energy Federal Technology Center Program Solicitation No. DE-PS26-99FT40479, Support of Advanced Coal Research at U.S. Universities and Colleges. Specifically, this research was in support of the UCR Core Program and addressees Topic 1, Improved Hot-Gas Contaminant and Particulate Removal Techniques, introducing an advanced design for particulate removal. Integrated gasification combined cycle (IGCC) offers the potential for very high efficiency and clean electric generation. In IGCC, the product gas from the gasifier needs to be cleaned of particulate matter to avoid erosion and high-temperature corrosion difficulties arising with the turbine blades. Current methods involve cooling the gases to {approx}100 C to condense alkalis and remove sulfur and particulates using conventional scrubber technology. This ''cool'' gas is then directed to a turbine for electric generation. While IGCC has the potential to reach efficiencies of over 50%, the current need to cool the product gas for cleaning prior to firing it in a turbine is keeping IGCC from reaching its full potential. The objective of the current project was to develop a highly reliable particulate collector system that can meet the most stringent turbine requirements and emission standards, can operate at temperatures above 1500 F, is applicable for use with all U.S. coals, is compatible with various sorbent injection schemes for sulfur and alkali control, can be integrated into a variety of configurations for both pressurized gasification and combustion, increases allowable face velocity to reduce filter system capital cost, and is cost-competitive with existing technologies. The collector being developed is a new concept in particulate control called electrostatically enhanced barrier filter collection (EBFC). This concept combines electrostatic precipitation (ESP) with candle filters in a single unit. Similar technology has been recently proven on a commercial scale for atmospheric applications, but needed to be tested at high temperatures and pressures. The synergy obtained by combining the two control technologies into a single system should actually reduce filter system capital and operating costs and make the system more reliable. More specifically, the ESP is expected to significantly reduce candle filter load and also to limit ash reintrainment, allowing for full recovery of baseline pressure drop during backpulsing of the filters.

John Erjavec; Michael D. Mann; Ryan Z. Knutson; Michael L. Swanson; Michael E. Collings

2003-06-01T23:59:59.000Z

95

Flue gas desulfurization : cost and functional analysis of large-scale and proven plants  

E-Print Network [OSTI]

Flue Gas Desulfurization is a method of controlling the emission of sulfurs, which causes the acid rain. The following study is based on 26 utilities which burn coal, have a generating capacity of at least 50 Megawatts ...

Tilly, Jean

1983-01-01T23:59:59.000Z

96

Coal desulfurization in a rotary kiln combustor  

SciTech Connect (OSTI)

The purpose of this project was to demonstrate the combustion of coal and coal wastes in a rotary kiln reactor with limestone addition for sulfur control. The rationale for the project was the perception that rotary systems could bring several advantages to combustion of these fuels, and may thus offer an alternative to fluid-bed boilers. Towards this end, an existing wood pyrolysis kiln (the Humphrey Charcoal kiln) was to be suitably refurbished and retrofitted with a specially designed version of a patented air distributor provided by Universal Energy, Inc. (UEI). As the project progressed beyond the initial stages, a number of issues were raised regarding the feasibility and the possible advantages of burning coals in a rotary kiln combustor and, in particular, the suitability of the Humphrey Charcoal kiln as a combustor. Instead, an opportunity arose to conduct combustion tests in the PEDCO Rotary Cascading-Bed Boiler (RCBB) commercial demonstration unit at the North American Rayon CO. (NARCO) in Elizabethton, TN. The tests focused on anthracite culm and had two objectives: (a) determine the feasibility of burning anthracite culms in a rotary kiln boiler and (b) obtain input for any further work involving the Humphrey Charcoal kiln combustor. A number of tests were conducted at the PEDCO unit. The last one was conducted on anthracite culm procured directly from the feed bin of a commercial circulating fluid-bed boiler. The results were disappointing; it was difficult to maintain sustained combustion even when large quantities of supplemental fuel were used. Combustion efficiency was poor, around 60 percent. The results suggest that the rotary kiln boiler, as designed, is ill-suited with respect to low-grade, hard to burn solid fuels, such as anthracite culm. Indeed, data from combustion of bituminous coal in the PEDCO unit suggest that with respect to coal in general, the rotary kiln boiler appears inferior to the circulating fluid bed boiler.

Cobb, J.T. Jr.

1992-09-11T23:59:59.000Z

97

Micromachined silicon electrostatic chuck  

DOE Patents [OSTI]

An electrostatic chuck is faced with a patterned silicon plate, created by micromachining a silicon wafer, which is attached to a metallic base plate. Direct electrical contact between the chuck face (patterned silicon plate`s surface) and the silicon wafer it is intended to hold is prevented by a pattern of flat-topped silicon dioxide islands that protrude less than 5 micrometers from the otherwise flat surface of the chuck face. The islands may be formed in any shape. Islands may be about 10 micrometers in diameter or width and spaced about 100 micrometers apart. One or more concentric rings formed around the periphery of the area between the chuck face and wafer contain a low-pressure helium thermal-contact gas used to assist heat removal during plasma etching of a silicon wafer held by the chuck. The islands are tall enough and close enough together to prevent silicon-to-silicon electrical contact in the space between the islands, and the islands occupy only a small fraction of the total area of the chuck face, typically 0.5 to 5 percent. The pattern of the islands, together with at least one hole bored through the silicon veneer into the base plate, will provide sufficient gas-flow space to allow the distribution of the helium thermal-contact gas. 6 figs.

Anderson, R.A.; Seager, C.H.

1996-12-10T23:59:59.000Z

98

A synchrotron X-ray study of competing undulation and electrostatic interlayer interactions in fluid multimembrane lyotropic phases  

E-Print Network [OSTI]

arise from attrac- tive electrodynamic van der Waals and, normally repulsive electrostatic forces [2307 A synchrotron X-ray study of competing undulation and electrostatic interlayer interactions of competing electrostatic and undulation forces in two multimembrane systems in the lamellar L03B1 phase

Boyer, Edmond

99

Electrostatic precipitator for metal and particulate emission control  

SciTech Connect (OSTI)

Improving air pollution control systems is crucial for incinerators to be an option for sewage sludge disposal. Combinations of venturi and tray tower scrubbers are the most popular air pollution control system for sewage sludge incinerators. Recently wet electrostatic precipitators have been installed downstream of the scrubbing system to ensure the compliance of new regulations. Performance and stack tests were conducted on sludge incinerators at Somerset Raritan Valley Sewage Authority and New England Treatment Company. Efficiencies in terms of heavy metal and particulate removals are presented. This paper also describes sewage sludge incinerators, existing air pollution control systems, design considerations of the wet electrostatic precipitator, as well as sampling and analysis methods.

Yang, C.L.; Beltran, M.

2000-03-01T23:59:59.000Z

100

FGD systems -- Physical deterioration of the chemical plant facility  

SciTech Connect (OSTI)

The Clean Air Act of 1970 established the initial requirements for the control of flue gas emissions from fossil-fuel-fired power plants in the US. Until then, only mechanical collectors and electrostatic precipitators regulated smoke and fly ash emissions from these plants. Now, a new technique for controlling the chemical emissions from a fossil-fuel-fired power plant had to be installed. Since there was practically no time for a research and development program, the power industry had to move quickly to select a compliance system. They chose to modify existing technology from the chemical industry for their specific need. Thus, wet limestone flue gas desulfurization (FGD) systems were born into the power industry and a chemical plant was added between the electrostatic precipitator and the chimney. This paper provides insight on how a program can be implemented to reconcile the materials and corrosion protection techniques available today to the specific areas of an FGD system. This paper focuses on a typical wet limestone FGD process. This type of process constitutes the vast majority of the FGD systems by total megawatt generation in the US. The power industry must learn from its chemical plant experience if it intends to extend the service life of FGD systems to match the design life of the remaining plant power block.

Dille, E.R.; Ridge, J.L. [Sargent and Lundy, Chicago, IL (United States)

1996-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "desulfurization systems electrostatic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
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to obtain the most current and comprehensive results.


101

Synthesis of electrostatic multielectrode deflectors  

SciTech Connect (OSTI)

Synthesis of electrostatic deflectors with given source parameters, first-order properties, and minimum aberrations can be realized by using the cubic spline method or the {ital a} {ital priori} given multielectrode approach. Synthesis of electrostatic deflectors was successfully achieved previously by using the cubic spline method. In this paper we present synthesis of electrostatic deflectors based on the {ital a} {ital priori} given multielectrode approach for the purpose of obtaining the minimum beam spot size through a sequential optimization technique. Our calculations show that the third-order geometrical deflection aberrations can be reduced by about two to three orders of magnitude using a multielectrode deflector with three units or five units, each having short cylindrical segments with geometrically octupole symmetry. {copyright} {ital 1995} {ital American} {ital Vacuum} {ital Society}

Cho, H.; Szilagyi, M. [Department of Electrical and Computer Engineering, University of Arizona, Tucson, Arizona 85721 (United States)] [Department of Electrical and Computer Engineering, University of Arizona, Tucson, Arizona 85721 (United States)

1995-09-01T23:59:59.000Z

102

Continuum Electrostatics in Cell Biology  

E-Print Network [OSTI]

Recent experiments revealing possible nanoscale electrostatic interactions in force generation at kinetochores for chromosome motions have prompted speculation regarding possible models for interactions between positively charged molecules in kinetochores and negative charge on C-termini near the plus ends of microtubules. A clear picture of how kinetochores establish and maintain a dynamic coupling to microtubules for force generation during the complex motions of mitosis remains elusive. The current paradigm of molecular cell biology requires that specific molecules, or molecular geometries, for force generation be identified. However, it is possible to account for mitotic motions within a classical electrostatics approach in terms of experimentally known cellular electric charge interacting over nanometer distances. These charges are modeled as bound surface and volume continuum charge distributions. Electrostatic consequences of intracellular pH changes during mitosis may provide a master clock for the events of mitosis.

L. John Gagliardi

2010-02-06T23:59:59.000Z

103

Magnetic and electrostatic confinement of plasma with tuning of electrostatic field  

DOE Patents [OSTI]

A system and method for containing plasma and forming a Field Reversed Configuration (FRC) magnetic topology are described in which plasma ions are contained magnetically in stable, non-adiabatic orbits in the FRC. Further, the electrons are contained electrostatically in a deep energy well, created by tuning an externally applied magnetic field. The simultaneous electrostatic confinement of electrons and magnetic confinement of ions avoids anomalous transport and facilitates classical containment of both electrons and ions. In this configuration, ions and electrons may have adequate density and temperature so that upon collisions they are fused together by nuclear force, thus releasing fusion energy. Moreover, the fusion fuel plasmas that can be used with the present confinement system and method are not limited to neutronic fuels only, but also advantageously include advanced fuels.

Rostoker, Norman (Irvine, CA); Binderbauer, Michl (Irvine, CA); Qerushi, Artan (Irvine, CA); Tahsiri, Hooshang (Irvine, CA)

2008-10-21T23:59:59.000Z

104

Magnetic and electrostatic confinement of plasma with tuning of electrostatic field  

DOE Patents [OSTI]

A system and method for containing plasma and forming a Field Reversed Configuration (FRC) magnetic topology are described in which plasma ions are contained magnetically in stable, non-adiabatic orbits in the FRC. Further, the electrons are contained electrostatically in a deep energy well, created by tuning an externally applied magnetic field. The simultaneous electrostatic confinement of electrons and magnetic confinement of ions avoids anomalous transport and facilitates classical containment of both electrons and ions. In this configuration, ions and electrons may have adequate density and temperature so that upon collisions they are fused together by nuclear force, thus releasing fusion energy. Moreover, the fusion fuel plasmas that can be used with the present confinement system and method are not limited to neutronic fuels only, but also advantageously include advanced fuels.

Rostoker, Norman; Binderbauer, Michl; Qerushi, Artan; Tahsiri, Hooshang

2006-03-21T23:59:59.000Z

105

Magnetic and electrostatic confinement of plasma with tuning of electrostatic field  

DOE Patents [OSTI]

A system and method for containing plasma and forming a Field Reversed Configuration (FRC) magnetic topology are described in which plasma ions are contained magnetically in stable, non-adiabatic orbits in the FRC. Further, the electrons are contained electrostatically in a deep energy well, created by tuning an externally applied magnetic field. The simultaneous electrostatic confinement of electrons and magnetic confinement of ions avoids anomalous transport and facilitates classical containment of both electrons and ions. In this configuration, ions and electrons may have adequate density and temperature so that upon collisions they are fused together by nuclear force, thus releasing fusion energy. Moreover, the fusion fuel plasmas that can be used with the present confinement system and method are not limited to neutronic fuels only, but also advantageously include advanced fuels.

Rostoker, Norman; Binderbauer, Michl; Qerushi, Artan; Tahsiri, Hooshang

2006-10-10T23:59:59.000Z

106

KVB coal desulfurization process development. Quarterly technical progress report, October-December 1980  

SciTech Connect (OSTI)

This is the second technical progress report for the KVB Coal Desulfurization Process Development. The project is a joint venture between Research-Cottrell, Inc. and the College of Engineering of Rutgers University. The process involves oxidation of the sulfur in coal (both organic and pyritic) to soluble forms using nitrogen oxide gas mixtures and subsequent extractive removal. Key features of the process are mild reaction conditions and the use of a regenerable oxidant. Construction of a bench scale oxidation reactor system was completed and a short experimental program was carried out using Illinois No. 6 coal. An investigation of extraction reagents was also conducted. The emphasis to date has been on development and demonstration of procedures rather than on data generation. However preliminary data do indicate reaction of both organic and pyritic sulfur. Preliminary coal characterization work using x-ray fluorescence is also reported. A brief discussion of project plans in the areas of process modelling and commercial evaluation is also given.

Not Available

1980-01-01T23:59:59.000Z

107

Manganese-based sorbents for coal gas desulfurization  

SciTech Connect (OSTI)

The intent of this study is to perform a preliminary screening on a particular Mn-based sorbent, CST-939 (from Chemetals), for hot gas desulfurization. The purpose of the preliminary screening is to determine which temperature and type of coal gas this sorbent demonstrates the greatest capacity and efficiency for sulfur removal. The following conclusions were made from the data collected on the CST-939 sorbent: The sorbent efficiency and capacity are much greater at 343{degrees}C (650{degrees}F) than at 871{degrees}C (1,600{degrees}F). The sorbent efficiency and capacity are much greater in the presence of the more highly-reducing Shell gas than with the less-reducing KRW gas. The sorbent showed tremendous capacity for sulfur pickup, with actual loadings as high as 21 weight percent. Oxidative regeneration at 871{degrees}C (1,600{degrees}F) appeared to decompose sulfate; however, unusually high SO{sub 2} release during the second sulfidations and/or reductive regenerations indicated incomplete regeneration. The average crush strength of the reacted sorbent did not indicate any loss of strength as compared to the fresh sorbent. Superior sorbent performance was obtained in the presence of simulated Shell gas at 538{degrees}C (1,000{degrees}F).

Gasper-Galvin, L.D.; Fisher, E.P. [USDOE Morgantown Energy Technology Center, WV (United States); Goyette, W.J. [Chemetals, Inc., Baltimore, MD (United States)

1996-12-31T23:59:59.000Z

108

Theory, experiment and computer simulation of the electrostatic...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Theory, experiment and computer simulation of the electrostatic potential at crystalelectrolyte interfaces . Theory, experiment and computer simulation of the electrostatic...

109

Molecular surface electrostatic potentials in the analysis of non-hydrogen-bonding noncovalent interactions  

SciTech Connect (OSTI)

Electrostatic potentials computed on molecular surfaces are used to analyze some noncovalent interactions that are not in the category of hydrogen bonding, e.g. halogen bonding. The systems examined include halogenated methanes, substituted benzenes, s-tetrazine and 1,3-bisphenylurea. The data were obtained by ab initio SCF calculations. Electrostatic potentials, Non-hydrogen-bonding noncovalent interactions, Molecular surfaces.

Murray, J.S.; Paulsen, K.; Politzer, P.

1993-12-27T23:59:59.000Z

110

Electrostatic Operation and Curvature Modeling for a MEMS Flexible Film Actuator  

E-Print Network [OSTI]

Electrostatic Operation and Curvature Modeling for a MEMS Flexible Film Actuator B. Edmonds, Jr.1 Introduction and Motivation The electrostatic flexible film actuator, also known as an "Artificial Eyelid," is a unique MEMS (MicroElectronic Mechanical System) actuator fabricated from polyimide and thin metal films

111

Electrostatic dust detector  

DOE Patents [OSTI]

An apparatus for detecting dust in a variety of environments which can include radioactive and other hostile environments both in a vacuum and in a pressurized system. The apparatus consists of a grid coupled to a selected bias voltage. The signal generated when dust impacts and shorts out the grid is electrically filtered, and then analyzed by a signal analyzer which is then sent to a counter. For fine grids a correlation can be developed to relate the number of counts observed to the amount of dust which impacts the grid.

Skinner, Charles H. (Lawrenceville, NJ)

2006-05-02T23:59:59.000Z

112

Method and apparatus for enhancing the desulfurization of hot coal gas in a fluid-bed coal gasifier  

DOE Patents [OSTI]

A process and apparatus for providing additional desulfurization of the hot gas produced in a fluid-bed coal gasifier, within the gasifier is described. A fluid-bed of iron oxide is located inside the gasifier above the gasification bed in a fluid-bed coal gasifier in which in-bed desulfurization by lime/limestone takes place. The product gases leave the gasification bed typically at 1600 to 1800 F and are partially quenched with water to 1000 to 1200 F before entering the iron oxide bed. The iron oxide bed provides additional desulfurization beyond that provided by the lime /limestone. 1 fig.

Grindley, T.

1988-04-05T23:59:59.000Z

113

Ultrasound-promoted chemical desulfurization of Illinois coals. Final technical report, September 1, 1990--August 31, 1991  

SciTech Connect (OSTI)

The overall objectives of the program were to investigate the use of ultrasound to promote coal desulfurization reactions and to evaluate chemical coal desulfurization schemes under mild conditions through a fundamental understanding of their reaction mechanisms and kinetics. The ultimate goal was to develop an economically feasible mild chemical process to reduce the total sulfur content of Illinois Basin Coals, while retaining their original physical characteristics, such as calorific value and volatile matter content. During the program, potential chemical reactions with coal were surveyed under various ultrasonic irradiation conditions for desulfurization, to formulate preliminary reaction pathways, and to select a few of the more promising chemical processes for more extensive study.

Chao, S.S.

1991-12-31T23:59:59.000Z

114

A Reusable Calcium-Based Sorbent for Desulfurizing Hot Coal Gas  

SciTech Connect (OSTI)

The overall objective of this project has been to develop a superior, regenerable, calcium-based sorbent for desulfurizing hot coal gas. The sorbent should be strong, durable, inexpensive to manufacture, and capable of being reused many times. To achieve these objectives the project has focused on the development of the very promising core-in-shell sorbent.

Wheelock, T.D.; Hasler, D.J.L.

2002-09-19T23:59:59.000Z

115

High Temperature Flue Gas Desulfurization In Moving Beds With Regenerable Copper Based Sorbents  

SciTech Connect (OSTI)

The objective of this study was to develop new and improved regenerable copper based sorbent for high temperature flue gas desulfurization in a moving bed application. The targeted areas of sorbent improvement included higher effective capacity, strength and long-term durability for improved process control and economic utilization of the sorbent.

Cengiz, P.A.; Ho, K.K.; Abbasian, J.; Lau, F.S.

2002-09-20T23:59:59.000Z

116

Novel Nanoscale Catalysts and Desulfurizers for Aviation Fuels Martin Duran* and Abdul-Majeed Azad  

E-Print Network [OSTI]

reforming catalysts for jet fuel", The Ohio Fuel Cell Symposium of the Ohio Fuel Cell Coalition, May 23Novel Nanoscale Catalysts and Desulfurizers for Aviation Fuels Martin Duran* and Abdul-Majeed Azad) to hydrogen through steam reforming poses a challenge since these fuels contain sulfur up to about 1000 ppm

Azad, Abdul-Majeed

117

Synthetic aggregates prepared from flue gas desulfurization by-products using various binder materials  

SciTech Connect (OSTI)

Flue Gas Desulfurization (FGD) by-products can be converted into environmentally safe and structurally stable aggregates. One type of synthetic aggregate was prepared using an optimum mixture of (FGD) by-products, fly ash, and water. Mineral reactions have been examined using X-ray diffraction and scanning electron microscope.

Bellucci, J.; Graham, U.M.; Hower, J.C.; Robl, T.L. [Univ. of Kentucky, Lexington, KY (United States). Center for Applied Energy Research

1994-12-31T23:59:59.000Z

118

Advanced Flue Gas Desulfurization (AFGD) demonstration project: Volume 2, Project performance and economics. Final technical report  

SciTech Connect (OSTI)

The project objective is to demonstrate removal of 90--95% or more of the SO{sub 2} at approximately one-half the cost of conventional scrubbing technology; and to demonstrate significant reduction of space requirements. In this project, Pure Air has built a single SO{sub 2} absorber for a 528-MWe power plant. The absorber performs three functions in a single vessel: prequencher, absorber, and oxidation of sludge to gypsum. Additionally, the absorber is of a co- current design, in which the flue gas and scrubbing slurry move in the same direction and at a relatively high velocity compared to conventional scrubbers. These features all combine to yield a state- of-the-art SO{sub 2} absorber that is more compact and less expensive than conventional scrubbers. The project incorporated a number of technical features including the injection of pulverized limestone directly into the absorber, a device called an air rotary sparger located within the base of the absorber, and a novel wastewater evaporation system. The air rotary sparger combines the functions of agitation and air distribution into one piece of equipment to facilitate the oxidation of calcium sulfite to gypsum. Additionally, wastewater treatment is being demonstrated to minimize water disposal problems inherent in many high-chloride coals. Bituminous coals primarily from the Indiana, Illinois coal basin containing 2--4.5% sulfur were tested during the demonstration. The Advanced Flue Gas Desulfurization (AFGD) process has demonstrated removal of 95% or more of the SO{sub 2} while providing a commercial gypsum by-product in lieu of solid waste. A portion of the commercial gypsum is being agglomerated into a product known as PowerChip{reg_sign} gypsum which exhibits improved physical properties, easier flowability and more user friendly handling characteristics to enhance its transportation and marketability to gypsum end-users.

NONE

1996-04-30T23:59:59.000Z

119

Frequency-dependent electrostatic actuation in microfluidic MEMS.  

SciTech Connect (OSTI)

Electrostatic actuators exhibit fast response times and are easily integrated into microsystems because they can be fabricated with standard IC micromachining processes and materials. Although electrostatic actuators have been used extensively in 'dry' MEMS, they have received less attention in microfluidic systems probably because of challenges such as electrolysis, anodization, and electrode polarization. Here we demonstrate that ac drive signals can be used to prevent electrode polarization, and thus enable electrostatic actuation in many liquids, at potentials low enough to avoid electrochemistry. We measure the frequency response of an interdigitated silicon comb-drive actuator in liquids spanning a decade of dielectric permittivities and four decades of conductivity, and present a simple theory that predicts the characteristic actuation frequency. The analysis demonstrates the importance of the native oxide on silicon actuator response, and suggests that the actuation frequency can be shifted by controlling the thickness of the oxide. For native silicon devices, actuation is predicted at frequencies less than 10 MHz, in electrolytes of ionic strength up to 100 mmol/L, and thus electrostatic actuation may be feasible in many bioMEMS and other microfluidic applications.

Zavadil, Kevin Robert; Michalske, Terry A.; Sounart, Thomas L.

2003-09-01T23:59:59.000Z

120

RESOLVING BEAM TRANSPORT PROBLEMS IN ELECTROSTATIC ACCELERATORS  

E-Print Network [OSTI]

RESOLVING BEAM TRANSPORT PROBLEMS IN ELECTROSTATIC ACCELERATORS J. D. LARSON (*) Oak Ridge National are frequently encounte- red during the design, operation and upgrading of electrostatic accelerators. Examples are provided of analytic procedures that clarify accelerator ion optics and lead to more effective beam

Boyer, Edmond

Note: This page contains sample records for the topic "desulfurization systems electrostatic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
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We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Development and evaluation of two reactor designs for desulfurization of Texas lignites  

E-Print Network [OSTI]

exhibited can be given at this time, but this behavior may be indicative of transformations of inorganic matter, changes in the forms of sulfur present in the lignite, and the overall composition. The results of this test series show a need for further...DEVELOPMENT AND EVALUATION OF TWO REACTOR DESIGNS FOR DESULFURIZATION OF TEXAS LIGNITES A Thesis by STANLEY DUANE MERRITT Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements...

Merritt, Stanley Duane

1991-01-01T23:59:59.000Z

122

Desulfurization of flue gas by the confined zone dispersion process  

SciTech Connect (OSTI)

This Confined Zone Dispersion (CZD) process involves injecting a finely atomized slurry of reactive lime into the ductwork of a coal-fired utility boiler. The principle of the confined zone is to form a wet zone of slurry droplets in the middle of the duct confined in an envelope of hot gas between the wet zone and the duct walls. The lime slurry reacts with part of the sulfur dioxide (SO{sub 2}) in the gas, and the reaction products dry to form solid particles. An electrostatic precipitator (ESP) downstream from the point of injection captures the reaction products, along with the fly ash entrained in the flue gas. The purpose of this project was to prove the CZD process concept by testing it on a limited scale, and then demonstrating the process on a large scale. The scope of work included projecting the cost of commercial implementation. The test facility for the proof-of-concept tests was on a scale equivalent to a 7 MWe generating plant. The large-scale demonstration was made on a scale of 70 MWe. This report describes how data from the two test sites were correlated, and presents conceptual designs for two full-scale retrofit installations. The rationale and data supporting the conclusions are also given in Part 4.

Not Available

1989-10-01T23:59:59.000Z

123

Integrating desulfurization with CO{sub 2}-capture in chemical-looping combustion  

SciTech Connect (OSTI)

Chemical looping combustion (CLC) is an emerging technology for clean combustion. We have previously demonstrated that the embedding of metal nanoparticles into a nanostructured ceramic matrix can result in unusually active and sinter-resistant nanocomposite oxygen carrier materials for CLC which maintain high reactivity and high-temperature stability even when sulfur contaminated fuels are used in CLC. Here, we propose a novel process scheme for in situ desulfurization of syngas with simultaneous CO{sub 2}-capture in chemical looping combustion by using these robust nanocomposite oxygen carriers simultaneously as sulfur-capture materials. We found that a nanocomposite Cu-BHA carrier can indeed strongly reduce the H{sub 2}S concentration in the fuel reactor effluent. However, during the process the support matrix is also sulfidized and takes part in the redox process of CLC. This results in SO{sub 2} production during the reduction of the oxygen carrier and thus limits the degree of desulfurization attainable with this kind of carrier. Nevertheless, the results suggest that simultaneous desulfurization and CO{sub 2} capture in CLC is feasible with Cu as oxygen carrier as long as appropriate carrier support materials are chosen, and could result in a novel, strongly intensified process for low-emission, high efficiency combustion of sulfur contaminated fuel streams.

Solunke, Rahul; Veser, Goetz

2011-02-01T23:59:59.000Z

124

Desulfurization of coal: enhanced selectivity using phase transfer catalysts. Quarterly report, March 1 - May 31, 1996  

SciTech Connect (OSTI)

Due to environmental problems related to the combustion of high sulfur Illinois coal, there continues to be interest in the development in viable pre-combustion desulfurization processes. Recent studies by the authors have obtained very good sulfur removals but the reagents that are used are too expensive. Use of cheaper reagents leads to a loss of desired coal properties. This study investigated the application phase transfer catalysts to the selective oxidation of sulfur in coal using air and oxygen as oxidants. The phase transfer catalyst is expected to function as a selectivity moderator by permitting the use of milder reaction conditions that otherwise necessary. This would enhance the sulfur selectivity and help retain the heating value of the coal. The use of certain coal combustion wastes for desulfurization, and the application of cerium (IV) catalyzed air oxidation for selective sulfur oxidation are also being studied. If successful, this project could lead to the rapid development of a commercially viable desulfurization process. This would significantly improve the marketability of Illinois coal.

Palmer, S.R.; Hippo, E.J. [Southern Illinois Univ., Carbondale, IL (United States)

1996-12-31T23:59:59.000Z

125

Electrostatics and radioactive aerosol behavior  

SciTech Connect (OSTI)

Radioactive aerosols differ from their nonradioactive counterparts by their ability to charge themselves by emitting charged particles during the radioactive decay process. Evidence that electrostatics, including this charging process, can affect the transport of the aerosols was summarized previously. Charge distributions and the mean charge for a monodisperse radioactive aerosol have been considered in detail. The principal results of theory to calculate charge distributions on a aerosol with a size distribution, changes to Brownian coagulation rates for an aerosol in a reactor containment, and possible changes to aerosol deposition resulting from the charging will be presented. The main purpose of the work has been to improve calculations of aerosol behavior in reactor containments, but behavior in less ionizing environments will be affected more strongly, and some problems remain to be solved in performing reliable calculations.

Clement, C.F.

1994-12-31T23:59:59.000Z

126

Carbon nanotubes decorated with Pt nanoparticles via electrostatic...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

nanotubes decorated with Pt nanoparticles via electrostatic self-assembly: a highly active oxygen reduction Carbon nanotubes decorated with Pt nanoparticles via electrostatic...

127

Intrinsic electrostatic effects in nanostructured ceramics  

SciTech Connect (OSTI)

Using empirical potentials, we have found that electrostatic dipoles can be created at grain boundaries formed from non-polar surfaces of fluorite-structured materials. In particular, the {Sigma}5(310)/[001] symmetric tilt grain boundary reconstructs to break the symmetry in the atomic structure at the boundary, forming the dipole. This dipole results in an abrupt change in electrostatic potential across the boundary. In multilayered ceramics composed of stacks of grain boundaries, the change in electrostatic potential at the boundary results in profound electrostatic effects within the crystalline layers, the nature of which depends on the electrostatic boundary conditions. For open-circuit boundary conditions, layers with either high or low electrostatic potential are formed. By contrast, for short-circuit boundary conditions, electric fields can be created within each layer, the strength of which then depends on the thickness of the layers. These electrostatic effects may have important consequences for the behavior of defects and dopants within these materials and offer the possibility of interesting technological applications.

Uberuaga, Blas Pedro [Los Alamos National Laboratory; Stanek, Chris R [Los Alamos National Laboratory; Nerikar, Pankaj V [Los Alamos National Laboratory

2009-01-01T23:59:59.000Z

128

Fluid&ParticulateSystems 424514/2010  

E-Print Network [OSTI]

systems 424514 /2014 GAS/SOLID SEPARATIONS Cyclones, Electrostatic precipitators, (Hot) Gas filtration Ron

Zevenhoven, Ron

129

Electrostatic microvalves utilizing conductive nanoparticles for improved speed, lower power, and higher force actuation.  

SciTech Connect (OSTI)

We have designed and built electrostatically actuated microvalves compatible with integration into a PDMS based microfluidic system. The key innovation for electrostatic actuation was the incorporation of carbon nanotubes into the PDMS valve membrane, allowing for electrostatic charging of the PDMS layer and subsequent discharging, while still allowing for significant distention of the valveseat for low voltage control of the system. Nanoparticles were applied to semi-cured PDMS using a stamp transfer method, and then cured fully to make the valve seats. DC actuation in air of these valves yielded operational voltages as low as 15V, by using a supporting structure above the valve seat that allowed sufficient restoring forces to be applied while not enhancing actuation forces to raise the valve actuation potential. Both actuate to open and actuate to close valves have been demonstrated, and integrated into a microfluidic platform, and demonstrated fluidic control using electrostatic valves.

Ten Eyck, Gregory A.; Branson, Eric D.; Kenis, Paul J. A. (University of Illinois, Champaign Urbana); Desai, Amit (University of Illinois, Champaign Urbana); Schudel, Ben (University of Illinois, Champaign Urbana); Givler, Richard C.; Tice, Josh (University of Illinois, Champaign Urbana); Collord, Andrew; Apblett, Christopher Alan; Cook, Adam W.

2009-09-01T23:59:59.000Z

130

Economic assessment of advanced flue gas desulfurization processes. Final report. Volume 2. Appendices G, H, and I  

SciTech Connect (OSTI)

This report presents the results of a project sponsored by the Morgantown Energy Technology Center (METC). The purpose of the study was to perform an economic and market assessment of advanced flue gas desulfurization (FGD) processes for application to coal-fired electric utility plants. The time period considered in the study is 1981 through 1990, and costs are reported in 1980 dollars. The task was divided into the following four subtasks: (1) determine the factors affecting FGD cost evaluations; (2) select FGD processes to be cost-analyzed; (3) define the future electric utility FGD system market; and (4) perform cost analyses for the selected FGD processes. The study was initiated in September 1979, and separate reports were prepared for the first two subtasks. The results of the latter two subtasks appear only in this final report, since the end-date of those subtasks coincided with the end-date of the overall task. The Subtask 1 report, Criteria and Methods for Performing FGD Cost Evaluation, was completed in October 1980. A slightly modified and condensed version of that report appears as Appendix B to this report. The Subtask 2 report, FGD Candidate Process Selection, was completed in January 1981, and the principal outputs of that subtask appear in Appendices C and D to this report.

Bierman, G. R.; May, E. H.; Mirabelli, R. E.; Pow, C. N.; Scardino, C.; Wan, E. I.

1981-09-01T23:59:59.000Z

131

Summary and assessment of METC zinc ferrite hot coal gas desulfurization test program, final report: Volume 1  

SciTech Connect (OSTI)

The Morgantown Energy Technology Center (METC) has conducted a test program to develop a zinc ferrite-based high temperature desulfurization process which could be applied to fuel gas entering downstream components such as molten carbonate fuel cells or gas turbines. As a result of prior METC work with iron oxide and zinc oxide sorbents, zinc ferrite evolved as a candidate with the potential for high capacity, low equilibrium levels of H/sub 2/S, and structural stability after multiple regenerations. The program consisted of laboratory-scale testing with a two-inch diameter reactor and simulated fixed-bed gasifier gas; bench-scale testing with a six-inch diameter reactor and actual gas from the METC 42-inch fixed bed gasifier; as well as laboratory-scale testing of zinc ferrite with simulated fluidized bed gasifier gas. Optimum operating parameters for zinc ferrite such as temperatures, gas compositions, and space velocities are discussed. From the test results, salient features of zinc ferrite were derived and discussed in regard to system implications, issues raised, and technical requirements. 47 refs., 53 figs., 41 tabs.

Underkoffler, V.S.

1986-12-01T23:59:59.000Z

132

Flow preconditioner for electrostatic precipitator  

SciTech Connect (OSTI)

A flow preconditioner for an electrostatic precipitator removes particulate matter from a stream of polluted gas immediately after it passes through a tangential inlet at the lower end of a vertical cylindrical housing and straightens and divides the stream into laminations parallel to the axis of the housing. It comprises an annular ledge or choke ring extending inwardly from said housing above the inlet and an assembly of vanes above said ledge extending radially from the axis of the housing and angularly spaced apart. Each of said vanes has a flow receiving edge directed toward said inlet, a curved portion extending upwardly and away from said inlet, and a flat portion extending upwardly from said curved portion in a plane parallel to the housing axis. The curved portion of each vane defines a trough having a camber which gradually decreases along its span from the outer end of the vane towards the axis of the housng, together with means to vary the centrifugal flow distribution relative to the housing to render the preconditioner adjustable for various flow capacities.

Honacker, H.; Drlik, R.J.

1980-01-01T23:59:59.000Z

133

Electrostatic-plasma-wave energy flux  

E-Print Network [OSTI]

would reduce cross- field wave-energy convection since theor cross-field leakage of wave energy are ap- that thecomposition of electrostatic-wave-energy field degrees of

Amendt, P.; Rostoker, N.

1984-01-01T23:59:59.000Z

134

Electrostatic Modeling of CMOS sensor array 1 Computing Security  

E-Print Network [OSTI]

to Hades. #12;Electrostatic Modeling of CMOS sensor array 3 7 Kerberos Tickets Used for authentication

Cukic, Bojan

135

Energy conservation in electrostatic fabric filtration of industrial dust  

SciTech Connect (OSTI)

Conservation in energy consumption in industrial fabric filtration systems has become very important due to the substantial increase in energy costs. Recently, an external electric field was utilized in the industrial dust control by fabric filters with very promising initial results. A substantial decrease in the pressure drop and an increase in collection efficiency were observed. The detailed outcome of the experimental research program in electrostatic fabric filtration was presented. The results show that pressure drop decreases substantially with the increased electrostatic field strength for all relevant parameters. Furthermore, the data of the experimental program was utilized to develop a semi-empirical model for the determination of the pressure drop and to establish an Energy-Optimized Design Criteria.

Ariman, T.

1981-12-01T23:59:59.000Z

136

ELECTROSTATIC MODELING OF THE JEFFERSON LABORATORY INVERTED CERAMIC GUN  

SciTech Connect (OSTI)

Jefferson Laboratory (JLab) is currently developing a new 500kV DC electron gun for future use with the FEL. The design consists of two inverted ceramics which support a central cathode electrode. This layout allows for a load-lock system to be located behind the gun chamber. The electrostatic geometry of the gun has been designed to minimize surface electric field gradients and also to provide some transverse focusing to the electron beam during transit between the cathode and anode. This paper discusses the electrode design philosophy and presents the results of electrostatic simulations. The electric field information obtained through modeling was used with particle tracking codes to predict the effects on the electron beam.

P. Evtushenko ,F.E. Hannon, C. Hernandez-Garcia

2010-05-01T23:59:59.000Z

137

Apparatus for magnetic and electrostatic confinement of plasma  

DOE Patents [OSTI]

An apparatus and method for containing plasma and forming a Field Reversed Configuration (FRC) magnetic topology are described in which plasma ions are contained magnetically in stable, non-adiabatic orbits in the FRC. Further, the electrons are contained electrostatically in a deep energy well, created by tuning an externally applied magnetic field. The simultaneous electrostatic confinement of electrons and magnetic confinement of ions avoids anomalous transport and facilitates classical containment of both electrons and ions. In this configuration, ions and electrons may have adequate density and temperature so that upon collisions ions are fused together by nuclear force, thus releasing fusion energy. Moreover, the fusion fuel plasmas that can be used with the present confinement system and method are not limited to neutronic fuels only, but also advantageously include advanced fuels.

Rostoker, Norman; Binderbauer, Michl

2013-06-11T23:59:59.000Z

138

Apparatus for magnetic and electrostatic confinement of plasma  

DOE Patents [OSTI]

An apparatus and method for containing plasma and forming a Field Reversed Configuration (FRC) magnetic topology are described in which plasma ions are contained magnetically in stable, non-adiabatic orbits in the FRC. Further, the electrons are contained electrostatically in a deep energy well, created by tuning an externally applied magnetic field. The simultaneous electrostatic confinement of electrons and magnetic confinement of ions avoids anomalous transport and facilitates classical containment of both electrons and ions. In this configuration, ions and electrons may have adequate density and temperature so that upon collisions they are fused together by nuclear force, thus releasing fusion energy. Moreover, the fusion fuel plasmas that can be used with the present confinement system and method are not limited to neutronic fuels only, but also advantageously include advanced fuels.

Rostoker, Norman; Binderbauer, Michl

2006-04-11T23:59:59.000Z

139

Apparatus for magnetic and electrostatic confinement of plasma  

DOE Patents [OSTI]

An apparatus and method for containing plasma and forming a Field Reversed Configuration (FRC) magnetic topology are described in which plasma ions are contained magnetically in stable, non-adiabatic orbits in the FRC. Further, the electrons are contained electrostatically in a deep energy well, created by tuning an externally applied magnetic field. The simultaneous electrostatic confinement of electrons and magnetic confinement of ions avoids anomalous transport and facilitates classical containment of both electrons and ions. In this configuration, ions and electrons may have adequate density and temperature so that upon collisions they are fused together by nuclear force, thus releasing fusion energy. Moreover, the fusion fuel plasmas that can be used with the present confinement system and method are not limited to neutronic fuels only, but also advantageously include advanced fuels.

Rostoker, Norman; Binderbauer, Michl

2006-10-31T23:59:59.000Z

140

In: Proceedings of the 87th Annual Meeting (held June 19-24 in Cincinnati, OH), Air and Waste Management Association, Pittsburgh, Pennsylvania, June 1994, Paper No. 94-260.05. 1994 H.C. Frey  

E-Print Network [OSTI]

flue gas desulfurization (FGD) system for SO2 control, an electrostatic precipitator (ESP) for PM emission control system for a new pulverized coal (PC) power plant typically consists of a wet limestone

Frey, H. Christopher

Note: This page contains sample records for the topic "desulfurization systems electrostatic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

An improved proximity force approximation for electrostatics  

SciTech Connect (OSTI)

A quite straightforward approximation for the electrostatic interaction between two perfectly conducting surfaces suggests itself when the distance between them is much smaller than the characteristic lengths associated with their shapes. Indeed, in the so called 'proximity force approximation' the electrostatic force is evaluated by first dividing each surface into a set of small flat patches, and then adding up the forces due two opposite pairs, the contributions of which are approximated as due to pairs of parallel planes. This approximation has been widely and successfully applied in different contexts, ranging from nuclear physics to Casimir effect calculations. We present here an improvement on this approximation, based on a derivative expansion for the electrostatic energy contained between the surfaces. The results obtained could be useful for discussing the geometric dependence of the electrostatic force, and also as a convenient benchmark for numerical analyses of the tip-sample electrostatic interaction in atomic force microscopes. - Highlights: Black-Right-Pointing-Pointer The proximity force approximation (PFA) has been widely used in different areas. Black-Right-Pointing-Pointer The PFA can be improved using a derivative expansion in the shape of the surfaces. Black-Right-Pointing-Pointer We use the improved PFA to compute electrostatic forces between conductors. Black-Right-Pointing-Pointer The results can be used as an analytic benchmark for numerical calculations in AFM. Black-Right-Pointing-Pointer Insight is provided for people who use the PFA to compute nuclear and Casimir forces.

Fosco, Cesar D. [Centro Atomico Bariloche, Comision Nacional de Energia Atomica, R8402AGP Bariloche (Argentina) [Centro Atomico Bariloche, Comision Nacional de Energia Atomica, R8402AGP Bariloche (Argentina); Instituto Balseiro, Universidad Nacional de Cuyo, R8402AGP Bariloche (Argentina); Lombardo, Fernando C. [Departamento de Fisica Juan Jose Giambiagi, FCEyN UBA, Facultad de Ciencias Exactas y Naturales, Ciudad Universitaria, Pabellon I, 1428 Buenos Aires (Argentina) [Departamento de Fisica Juan Jose Giambiagi, FCEyN UBA, Facultad de Ciencias Exactas y Naturales, Ciudad Universitaria, Pabellon I, 1428 Buenos Aires (Argentina); IFIBA (Argentina)] [Argentina; Mazzitelli, Francisco D., E-mail: fdmazzi@cab.cnea.gov.ar [Centro Atomico Bariloche, Comision Nacional de Energia Atomica, R8402AGP Bariloche (Argentina); Departamento de Fisica Juan Jose Giambiagi, FCEyN UBA, Facultad de Ciencias Exactas y Naturales, Ciudad Universitaria, Pabellon I, 1428 Buenos Aires (Argentina)

2012-08-15T23:59:59.000Z

142

Optics elements for modeling electrostatic lenses and accelerator components II. Acceleration columns  

SciTech Connect (OSTI)

A set of optical models for a variety of electrostatic lenses and accelerator columns has been developed for the computer code TRACE 3-D. TRACE 3-D is an envelope (matrix) code including space charge that is often used to model bunched beams in magnetic transport systems and radiofrequency (RF) accelerators when the effects of beam current may be important. Several new matrix models have been developed that allow the code to be used for modeling beam lines and accelerators with electrostatic components. The new models include a number of options for: (1) einzel lenses, (2) accelerator columns, (3) electrostatic deflectors (prisms), and (4) an electrostatic quadrupole. A prescription for setting up the initial beam appropriate to modeling 2-D (continuous) beams has also been developed. The new models for (2) are described in this paper, selected comparisons with other calculations are presented, and a beamline application is summarized.

Gillespie, G.H., Brown, T.A.

1998-05-01T23:59:59.000Z

143

Energy issues for construction of electrostatic nano-traps in saline  

E-Print Network [OSTI]

To trap and manipulate nano-sized particles with electrostatic force is an interesting issue for nanoscience and bioscience, yet remains as a technical challenge to date. We present here numerical calculations for the feasibility of trapping a nano-particle with another nano-sized structure in an ionic fluid. The roles of electrostatic energy, entropy and free energy in interplays of these systems have been calculated. We find that in some cases the entropic term contributes more to the total amount of free energy than the electrostatic energy does. We have also discussed the probability for aggregation of two nano-subjects with similar structure but different charge distributions. Although the structures and charge distributions are artificially assumed, the result should be valid for general cases; it provides guiding clues for construction of nanoscale electrostatic tweezers, and may help for a better understand of the interplays among a variety of bio-macromolecules.

Jingkun Guo; Zijin Lei; Shengyong Xu

2015-01-09T23:59:59.000Z

144

Process for the manufacture of an attrition resistant sorbent used for gas desulfurization  

DOE Patents [OSTI]

This process produces a sorbent for use in desulfurization of coal gas. A zinc titanate compound and a metal oxide are mixed by milling the compounds in an aqueous medium, the resulting mixture is dried and then calcined, crushed, sleved and formed into pellets for use in a moving-bed reactor. Metal oxides suitable for use as an additive in this process include: magnesium oxide, magnesium oxide plus molybdenum oxide, calcium oxide, yttrium oxide, hafnium oxide, zirconium oxide, cupric oxide, and tin oxide. The resulting sorbent has a percentage of the original zinc or titanium ions substituted for the oxide metal of the chosen additive.

Venkataramani, Venkat S.; Ayala, Raul E.

2003-09-16T23:59:59.000Z

145

A NEW ELECTROSTATIC RADON PROGENY COLLECTION METHOD  

E-Print Network [OSTI]

A new method for collecting radon progeny was investigated that reduces particle concentration including radon progeny in indoor air without air movement. The LECA (for bge Electrostatically Charged-) system uses a high voltage source to charge the collector surfaces (e.g., furniture pieces were used) once they have been electrically isolated from ground by teflon film. When a piece was touched by the high voltage lead its entire surface immediately become charged to about 60 % of the line voltage regardless of its material makeup. By limiting the current to 250 ua no sparking or shock sensation was experienced when touching the charged wire or collector surfaces. Progeny collection efficiencies were measured for collector areas from 8.6 to 5 1.8 m2 and voltages from 2.5 to 9 KV in an 82 m3 test-room. The optimum LECA configuration tested reduced all particulate in the test-room including both the attached and unattached progeny by about 92%. BACKGROUND Lung cancer, the priiciple radon health effect, is not caused by the radon gas itself but by its progeny, especially by the smaller unattached progeny particles that can penetrate into the deep respiratory tract. Several researchers have investigated methods of reducing progeny in indoor air but most methods tried have been unsuccessful because of their inability to remove enough of those more hazardous unattached progeny.

John C. Dempsey; Rad Elec Inc; Darold M. Wobschall

146

Land application uses for dry flue gas desulfurization by-products: Phase 3  

SciTech Connect (OSTI)

New flue gas desulfurization (FGD) scrubbing technologies create a dry, solid by-product material consisting of excess sorbent, reaction product that contains sulfate and sulfite, and coal fly ash. Generally, dry FGD by-products are treated as solid wastes and disposed in landfills. However, landfill sites are becoming scarce and tipping fees are constantly increasing. Provided the environmental impacts are socially and scientifically acceptable, beneficial uses via recycling can provide economic benefits to both the producer and the end user of the FGD. A study titled ''Land Application Uses for Dry Flue Gas Desulfurization By-Products'' was initiated in December, 1990 to develop and demonstrate large volume, beneficial uses of FGD by-products. Phase 1 and Phase 2 reports have been published by the Electric Power Research Institute (EPRI), Palo Alto, CA. Phase 3 objectives were to demonstrate, using field studies, the beneficial uses of FGD by-products (1) as an amendment material on agricultural lands and on abandoned surface coal mine land, (2) as an engineering material for soil stabilization and raid repair, and (3) to assess the environmental and economic impacts of such beneficial uses. Application of dry FGD by-product to three soils in place of agricultural limestone increased alfalfa (Medicago sativa L.) and corn (Zea may L.) yields. No detrimental effects on soil and plant quality were observed.

Dick, W.; Bigham, J.; Forster, R.; Hitzhusen, F.; Lal, R.; Stehouwer, R.; Traina, S.; Wolfe, W.; Haefner, R.; Rowe, G.

1999-01-31T23:59:59.000Z

147

Electrostatic supersolitons in three-species plasmas  

SciTech Connect (OSTI)

Superficially, electrostatic potential profiles of supersolitons look like those of traditional solitons. However, their electric field profiles are markedly different, having additional extrema on the wings of the standard bipolar structure. This new concept was recently pointed out in the literature for a plasma model with five species. Here, it is shown that electrostatic supersolitons are not an artefact of exotic, complicated plasma models, but can exist even in three-species plasmas and are likely to occur in space plasmas. Further, a methodology is given to delineate their existence domains in a systematic fashion by determining the specific limiting factors.

Verheest, Frank [Sterrenkundig Observatorium, Universiteit Gent, Krijgslaan 281, B-9000 Gent (Belgium); School of Chemistry and Physics, University of KwaZulu-Natal, Durban 4000 (South Africa); Hellberg, Manfred A. [School of Chemistry and Physics, University of KwaZulu-Natal, Durban 4000 (South Africa); Kourakis, Ioannis [Department of Physics and Astronomy, Centre for Plasma Physics, Queen's University Belfast, BT7 1NN Northern Ireland (United Kingdom)

2013-01-15T23:59:59.000Z

148

Advanced Flue Gas Desulfurization (AFGD) Demonstration Project, A DOE Assessment  

SciTech Connect (OSTI)

The AFGD process as demonstrated by Pure Air at the Bailly Station offers a reliable and cost-effective means of achieving a high degree of SO{sub 2} emissions reduction when burning high-sulfur coals. Many innovative features have been successfully incorporated in this process, and it is ready for widespread commercial use. The system uses a single-loop cocurrent scrubbing process with in-situ oxidation to produce wallboard-grade gypsum instead of wet sludge. A novel wastewater evaporation system minimizes effluents. The advanced scrubbing process uses a common absorber to serve multiple boilers, thereby saving on capital through economies of scale. Major results of the project are: (1) SO{sub 2} removal of over 94 percent was achieved over the three-year demonstration period, with a system availability exceeding 99.5 percent; (2) a large, single absorber handled the combined flue gas of boilers generating 528 MWe of power, and no spares were required; (3) direct injection of pulverized limestone into the absorber was successful; (4) Wastewater evaporation eliminated the need for liquid waste disposal; and (5) the gypsum by-product was used directly for wallboard manufacture, eliminating the need to dispose of waste sludge.

National Energy Technology Laboratory

2001-08-31T23:59:59.000Z

149

Advances of flue gas desulfurization technology for coal-fired boilers and strategies for sulfur dioxide pollution prevention in China  

SciTech Connect (OSTI)

Coal is one of the most important kinds of energy resources at the present time and in the immediate future in China. Sulfur dioxide resulting from combustion of coal is one of the principle pollutants in the air. Control of SO{sub 2} discharge is still a major challenge for environmental protection in developing China. In this paper, research, development and application of technology of flue gas desulfurization (FGD) for coal-fired boilers in China will be reviewed with emphasis on cost-effective technology, and the development trends of FGD technology, as well as the strategy for SO{sub 2} discharge control in China, will be analyzed. A practical technology for middle-small-sized boilers developed by the primary author and the field investigation results will also be presented. At present, there are four major kinds of FGD technologies that are practical to be applied in China for their cost-effectiveness and efficiency to middle-small-sized boilers. An important development trend of the FGD technology for middle-small-sized boilers for the next decade is improvement of the existing cost-effective wet-type FGD technology, and in the future it will be the development of dry-type FGD technology. For middle-sized generating boilers, the development direction of the FGD technology is the spraying and drying process. For large-sized generating boilers, the wet-type limestone-plaster process will still be applied in the immediate future, and dry-type FGD technologies, such as ammonia with electron beam irradiation, will be developed in the future. State strategies for the control of SO{sub 2} discharge will involve the development and popularization of efficient coal-fired devices, extension of gas coal and liquefied coal, spreading coal washing, and centralized heating systems.

Yang, C.; Zeng, G.; Li, G.; Qiu, J.

1999-07-01T23:59:59.000Z

150

Enhanced durability of desulfurization sorbents for fluidized-bed applications  

SciTech Connect (OSTI)

To extend the operating temperature range and further improve the durability of fluidizable sorbents, zinc titanate, another leading regenerable sorbent, was selected for development in the later part of this project. A number of zinc titanate formulations were prepared in the 50 to 300 {mu}m range using granulation and spray drying methods. Important sorbent preparation variables investigated included zinc to titanium ratio, binder type, binder amount, and various chemical additives such as cobalt and molybdenum. A number of sorbents selected on the basis of screening tests were subjected to bench-scale testing for 10 cycles at high temperature, high pressure (HTHP) conditions using the reactor system designed and constructed during the base program. This reactor system is capable of operation either as a 2.0 in. or 3.0 in. I.D. bubbling bed and is rated up to 20 atm operation at 871{degrees}C. Bench-scale testing variables included sorbent type, temperature (550 to 750{degrees}C), gas type (KRW or Texaco gasifier gas), steam content of coal gas, and fluidizing gas velocity (6 to 15 cm/s). The sorbents prepared by spray drying showed poor performance in terms of attrition resistance and chemical reactivity. On the other hand, the granulation method proved to be very successful. For example, a highly attrition-resistant zinc titanate formulation, ZT-4, prepared by granulation exhibited virtually no zinc loss and demonstrated a constant high reactivity and sulfur capacity over 10 cycles, i.e., approximately a 60 percent capacity utilization, with Texaco gas at 750{degrees}C, 15 cm/s fluidizing velocity and 15 atm pressure. The commercial potential of the granulation method for zinc titanate manufacture was demonstrated by preparing two 80 lb batches of sorbent with zinc to titanium mol ratios of 0.8 and 1.5.

Gupta, R.P.; Gangwal, S.K.

1992-11-01T23:59:59.000Z

151

Enhanced durability of desulfurization sorbents for fluidized-bed applications  

SciTech Connect (OSTI)

To extend the operating temperature range and further improve the durability of fluidizable sorbents, zinc titanate, another leading regenerable sorbent, was selected for development in the later part of this project. A number of zinc titanate formulations were prepared in the 50 to 300 [mu]m range using granulation and spray drying methods. Important sorbent preparation variables investigated included zinc to titanium ratio, binder type, binder amount, and various chemical additives such as cobalt and molybdenum. A number of sorbents selected on the basis of screening tests were subjected to bench-scale testing for 10 cycles at high temperature, high pressure (HTHP) conditions using the reactor system designed and constructed during the base program. This reactor system is capable of operation either as a 2.0 in. or 3.0 in. I.D. bubbling bed and is rated up to 20 atm operation at 871[degrees]C. Bench-scale testing variables included sorbent type, temperature (550 to 750[degrees]C), gas type (KRW or Texaco gasifier gas), steam content of coal gas, and fluidizing gas velocity (6 to 15 cm/s). The sorbents prepared by spray drying showed poor performance in terms of attrition resistance and chemical reactivity. On the other hand, the granulation method proved to be very successful. For example, a highly attrition-resistant zinc titanate formulation, ZT-4, prepared by granulation exhibited virtually no zinc loss and demonstrated a constant high reactivity and sulfur capacity over 10 cycles, i.e., approximately a 60 percent capacity utilization, with Texaco gas at 750[degrees]C, 15 cm/s fluidizing velocity and 15 atm pressure. The commercial potential of the granulation method for zinc titanate manufacture was demonstrated by preparing two 80 lb batches of sorbent with zinc to titanium mol ratios of 0.8 and 1.5.

Gupta, R.P.; Gangwal, S.K.

1992-11-01T23:59:59.000Z

152

Experimental Characterization of Plasma Heating with Beating Electrostatic Waves  

E-Print Network [OSTI]

Experimental Characterization of Plasma Heating with Beating Electrostatic Waves Benjamin Jorns and Edgar Y. Choueiri Electric Propulsion and Plasma Dynamics Laboratory, Princeton University, Princeton, NJ, 08540 The heating of ions in a magnetized plasma by two electrostatic waves whose frequencies

Choueiri, Edgar

153

Electrostatic plasma lens for focusing negatively charged particle beams  

SciTech Connect (OSTI)

We describe the current status of ongoing research and development of the electrostatic plasma lens for focusing and manipulating intense negatively charged particle beams, electrons, and negative ions. The physical principle of this kind of plasma lens is based on magnetic isolation electrons providing creation of a dynamical positive space charge cloud in shortly restricted volume propagating beam. Here, the new results of experimental investigations and computer simulations of wide-aperture, intense electron beam focusing by plasma lens with positive space charge cloud produced due to the cylindrical anode layer accelerator creating a positive ion stream towards an axis system is presented.

Goncharov, A. A.; Dobrovolskiy, A. M.; Dunets, S. M. [Institute of Physics NAS of Ukraine, Kiev 03028, Ave. Nauki 46 (Ukraine); Litovko, I. V. [Institute for Nuclear Research NAS of Ukraine, Kiev 03650, pr. Nauki 47 (Ukraine); Gushenets, V. I.; Oks, E. M. [High-Current Electronics Institute SB of RAS, Tomsk (Russian Federation)

2012-02-15T23:59:59.000Z

154

Method for the desulfurization of hot product gases from coal gasifier  

DOE Patents [OSTI]

The gasification of sulfur-bearing coal produces a synthesis gas which contains a considerable concentration of sulfur compounds especially hydrogen sulfide that renders the synthesis gas environmentally unacceptable unless the concentration of the sulfur compounds is significantly reduced. To provide for such a reduction in the sulfur compounds a calcium compound is added to the gasifier with the coal to provide some sulfur absorption. The synthesis gas from the gasifier contains sulfur compounds and is passed through an external bed of a regenerable solid absorbent, preferably zinc ferrite, for essentially completed desulfurizing the hot synthesis gas. This absorbent is, in turn, periodically or continuously regenerated by passing a mixture of steam and air or oxygen through the bed for converting absorbed hydrogen sulfide to sulfur dioxide. The resulting tail gas containing sulfur dioxide and steam is injected into the gasifier where the sulfur dioxide is converted by the calcium compound into a stable form of sulfur such as calcium sulfate.

Grindley, Thomas (Morgantown, WV)

1988-01-01T23:59:59.000Z

155

Method for reducing sulfate formation during regeneration of hot-gas desulfurization sorbents  

DOE Patents [OSTI]

The regeneration of sulfur sorbents having sulfate forming tendencies and used for desulfurizing hot product gas streams such as provided by coal gasification is provided by employing a two-stage regeneration method. Air containing a sub-stoichiometric quantity of oxygen is used in the first stage for substantially fully regenerating the sorbent without sulfate formation and then regeneration of the resulting partially regenerated sorbent is completed in the second stage with air containing a quantity of oxygen slightly greater than the stoichiometric amount adequate to essentially fully regenerate the sorbent. Sulfate formation occurs in only the second stage with the extent of sulfate formation being limited only to the portion of the sulfur species contained by the sorbent after substantially all of the sulfur species have been removed therefrom in the first stage.

Bissett, Larry A. (Morgantown, WV); Strickland, Larry D. (Morgantown, WV); Rockey, John M. (Westover, WV)

1994-01-01T23:59:59.000Z

156

Hot gas desulfurization with sorbents containing oxides of zinc, iron, vanadium and copper  

SciTech Connect (OSTI)

The main objective of this research is to evaluate the desulfurization performance of novel sorbents consisting of different combinations of zinc, iron, vanadium and copper oxides; and to develop a sorbent which can reduce H{sub 2}S levels to less than 1 ppmv, which can stabilize zinc, making operations above 650{degrees}C possible, and which can produce economically recoverable amounts of elemental sulfur during regeneration. This objective will be accomplished by evaluating the sorbent performance using fixed-bed and TGA experiments supported by sorbent characterization at various reaction extents. In the seventh quarter, the screening of the promoted sorbents in the packed bed reactor was continued. The results of this work were presented at the 1992 University Coal Research Contractors, Review Conference at Pittsburgh, PA.

Akyurtlu, A.; Akyurtlu, J.F.

1992-01-01T23:59:59.000Z

157

KVB coal desulfurization process development. Quarterly technical progress report for May-September 1980  

SciTech Connect (OSTI)

This is the initial technical progress report for the KVB Coal Desulfurization Process Development. The project is a joint effort between Research-Cottrell, Inc. and the College of Engineering of Rutgers University. The process involves oxidation of the sulfur in coal (both organic and pyritic) to soluble forms using nitrogen oxide gas mixtures and subsequent extractive removal. Key features of the process are mild reaction conditions and the use of regenerable reagents. A description of the process chemistry is given, as well as a brief summary of previous experimental studies. The experimental and analytical procedures being used in the current investigation, which is just getting underway, are described in detail. A brief outline of process modelling and commercial evaluation studies which will be a part of the project is also given.

Not Available

1980-01-01T23:59:59.000Z

158

Activation of Noble Metals on Metal-Carbide Surfaces: Novel Catalysts for CO Oxidation, Desulfurization and Hydrogenation Reactions  

SciTech Connect (OSTI)

This perspective article focuses on the physical and chemical properties of highly active catalysts for CO oxidation, desulfurization and hydrogenation reactions generated by depositing noble metals on metal-carbide surfaces. To rationalize structure-reactivity relationships for these novel catalysts, well-defined systems are required. High-resolution photoemission, scanning tunneling microscopy (STM) and first-principles periodic density-functional (DF) calculations have been used to study the interaction of metals of Groups 9, 10 and 11 with MC(001) (M = Ti, Zr, V, Mo) surfaces. DF calculations give adsorption energies that range from 2 eV (Cu, Ag, Au) to 6 eV (Co, Rh, Ir). STM images show that Au, Cu, Ni and Pt grow on the carbide substrates forming two-dimensional islands at very low coverage, and three-dimensional islands at medium and large coverages. In many systems, the results of DF calculations point to the preferential formation of admetal-C bonds with significant electronic perturbations in the admetal. TiC(001) and ZrC(001) transfer some electron density to the admetals facilitating bonding of the adatom with electron-acceptor molecules (CO, O{sub 2}, C{sub 2}H{sub 4}, SO{sub 2}, thiophene, etc.). For example, the Cu/TiC(001) and Au/TiC(001) systems are able to cleave both S-O bonds of SO{sub 2} at a temperature as low as 150 K, displaying a reactivity much larger than that of TiC(001) or extended surfaces of bulk copper and gold. At temperatures below 200 K, Au/TiC is able to dissociate O{sub 2} and perform the 2CO + O{sub 2} {yields} 2CO{sub 2} reaction. Furthermore, in spite of the very poor hydrodesulfurization performance of TiC(001) or Au(111), a Au/TiC(001) surface displays an activity for the hydrodesulfurization of thiophene higher than that of conventional Ni/MoS{sub x} catalysts. In general, the Au/TiC system is more chemically active than systems generated by depositing Au nanoparticles on oxide surfaces. Thus, metal carbides are excellent supports for enhancing the chemical reactivity of noble metals.

Rodriguez J. A.; Illas, F.

2012-01-01T23:59:59.000Z

159

FIELD TEST PROGRAM TO DEVELOP COMPREHENSIVE DESIGN, OPERATING, AND COST DATA FOR MERCURY CONTROL SYSTEMS  

SciTech Connect (OSTI)

With the Nation's coal-burning utilities facing the possibility of tighter controls on mercury pollutants, the U.S. Department of Energy is funding projects that could offer power plant operators better ways to reduce these emissions at much lower costs. Mercury is known to have toxic effects on the nervous system of humans and wildlife. Although it exists only in trace amounts in coal, mercury is released when coal burns and can accumulate on land and in water. In water, bacteria transform the metal into methylmercury, the most hazardous form of the metal. Methylmercury can collect in fish and marine mammals in concentrations hundreds of thousands times higher than the levels in surrounding waters. One of the goals of DOE is to develop technologies by 2005 that will be capable of cutting mercury emissions 50 to 70 percent at well under one-half of today's costs. ADA Environmental Solutions (ADA-ES) is managing a project to test mercury control technologies at full scale at four different power plants from 2000--2003. The ADA-ES project is focused on those power plants that are not equipped with wet flue gas desulfurization systems. ADA-ES has developed a portable system that will be tested at four different utility power plants. Each of the plants is equipped with either electrostatic precipitators or fabric filters to remove solid particles from the plant's flue gas. ADA-ES's technology will inject a dry sorbent, such as activated carbon, which removes the mercury and makes it more susceptible to capture by the particulate control devices. A fine water mist may be sprayed into the flue gas to cool its temperature to the range where the dry sorbent is most effective. PG&E National Energy Group is providing two test sites that fire bituminous coals and both are equipped with electrostatic precipitators and carbon/ash separation systems. Wisconsin Electric Power Company is providing a third test site that burns Powder River Basin (PRB) coal and has an electrostatic precipitator for particulate control. Alabama Power Company will host a fourth test at its Plant Gaston, which is equipped with a hot-side electrostatic precipitator and a downstream fabric filter.

Michael D. Durham

2003-05-01T23:59:59.000Z

160

Electrostatically Self-assembled Amphiplexes  

SciTech Connect (OSTI)

This research will focus on characterizing the phase behavior of polyelectrolyte-surfactant microemulsions (PSM) that were recently discovered in our lab and indentifing possible uses of their long-range ordered nanostructures towards bioseparation, oil-recovery and drug delivery systems. In addition, we are proposing strategies for synthesizing solid and long-range ordered materials with unit cells on the nanometer scale using polymerization and/or cross-linking to solidify the soft template.

Helmut H. Strey

2011-02-15T23:59:59.000Z

Note: This page contains sample records for the topic "desulfurization systems electrostatic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Molecular electrostatic potentials by systematic molecular fragmentation  

SciTech Connect (OSTI)

A simple method is presented for estimating the molecular electrostatic potential in and around molecules using systematic molecular fragmentation. This approach estimates the potential directly from the electron density. The accuracy of the method is established for a set of organic molecules and ions. The utility of the approach is demonstrated by estimating the binding energy of a water molecule in an internal cavity in the protein ubiquitin.

Reid, David M.; Collins, Michael A. [Research School of Chemistry, Australian National University, Canberra, ACT 0200 (Australia)] [Research School of Chemistry, Australian National University, Canberra, ACT 0200 (Australia)

2013-11-14T23:59:59.000Z

162

Desulfurization of coal: Enhanced selectivity using phase transfer catalysts. Final technical report, September 1, 1995--August 31, 1996  

SciTech Connect (OSTI)

Due to environmental problems related to the combustion of high sulfur Illinois coal, there continues to be interest in the development of viable pre-combustion desulfurization processes. Recent studies by the authors have obtained very good sulfur removals but the reagents that are used are too expensive. Use of cheaper reagents leads to a loss of desired coal properties. This study investigated the application of phase transfer catalysts to the selective oxidation of sulfur in coal using air and oxygen as oxidants. The phase transfer catalyst was expected to function as a selectivity moderator by permitting the use of milder reaction conditions than otherwise necessary. This would enhance the sulfur selectivity and help retain the heating value of the coal. The use of certain coal combustion wastes for desulfurization, and the application of cerium (IV) catalyzed air oxidations for selective sulfur oxidation were also studied. If successful this project would have lead to the rapid development of a commercially viable desulfurization process. This would have significantly improved the marketability of Illinois coal. However, the phase transfer catalysts, the cerium and the scrubber sledge did not catalize the sulfur removal significantly.

Palmer, S.R.; Hippo, E.J.

1997-05-01T23:59:59.000Z

163

Electrostatically-driven elastomer components for user-reconfigurable high density microfluidics  

E-Print Network [OSTI]

Electrostatically-driven elastomer components for user-reconfigurable high density microfluidics microfluidic system intended for very large scale integration (VLSI) microfluidics. By adding thin film metal with standard PDMS microfluidics, has actuation voltages low enough to be driven by commercial CMOS IC's and can

Maharbiz, Michel

164

Electrostatic Energy Harvester and Li-Ion Charger Circuit for Micro-Scale Applications  

E-Print Network [OSTI]

, low duty-cycle task multiplex- ing, and smart power-aware networks, the energy stored in micro- scaleElectrostatic Energy Harvester and Li-Ion Charger Circuit for Micro-Scale Applications Erick O micro-systems like biomedical implants and ad-hoc wireless transceiver micro-sensors continue

Rincon-Mora, Gabriel A.

165

Utility FGD Survey, January--December 1989. Volume 2, Design performance data for operating FGD systems, Part 1  

SciTech Connect (OSTI)

The Utility flue gas desulfurization (FGD) Survey report, which is generated by a computerized data base management system, represents a survey of operational and planned domestic utility flue gas desulfurization (FGD) systems. It summarizes information contributed by the utility industry, system and equipment suppliers, system designers, research organizations, and regulatory agencies. The data cover system design, fuel characteristics, operating history, and actual system performance. Also included is a unit-by-unit discussion of problems and solutions associated with the boilers, scrubbers, and FGD systems. The development status (operational, under construction, or in the planning stages), system supplier, process, waste disposal practice, and regulatory class are tabulated alphabetically by utility company.

Hance, S.L.; McKibben, R.S.; Jones, F.M. [IT Corp., Cincinnati, OH (United States)

1992-03-01T23:59:59.000Z

166

Sulfur dioxide removal by enhanced electrostatics  

SciTech Connect (OSTI)

The economic removal of sulfur dioxide (SO{sub 2}) still represents a significant technical challenge which could determine the use of certain types of fossil fuels for energy production. This paper will present the preliminary results of an innovative research project utilizing a low-cost wet electrostatic precipitator to remove sulfur dioxide. There are many aspects for gas removal in an electrostatic precipitator which are not currently being used. This project utilizes electron attachment of free electrons onto gas molecules and ozone generation to remove sulfur dioxide which is a typical flue gas pollutant. This research was conducted on a bench-scale, wet electrostatic precipitator. A direct-current negative discharge corona is used to generate the ozone in-situ. This ozone will be used to oxidize SO{sub 2} to form sulfuric acid, which is very soluble in water. However, it is believed that the primary removal mechanism is electron attachment of the free electrons from the corona which force the SO{sub 2} to go to equilibrium with the water and be removed from the gas stream. Forcing the equilibrium has been shown to achieve removal efficiencies of up to 70%. The bench scale unit has been designed to operate wet or dry, positive and negative for comparison purposes. The applied dc voltage is variable from 0 to 100 kV, the flow rate is a nominal 7 m{sup 3}/hr and the collecting electrode area is 0.20 m{sup 2}. Tests are conducted on a simulated flue gas stream with SO{sub 2} ranging from 0 to 4,000 ppmv. This paper presents the results of tests conducted to determine the effect of operating conditions on removal efficiency. The removal efficiency was found to vary with gas residence time, water flow rate, inlet concentration, applied power, and the use of corona pulsing.

Larkin, K.; Tseng, C.; Keener, T.C.; Khang, S.J. [Univ. of Cincinnati, OH (United States)

1997-12-31T23:59:59.000Z

167

antimicrobial peptide electrostatic: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Helsing, Johan 294 Experiment for Plasma Energization with Beating Electrostatic Waves Plasma Physics and Fusion Websites Summary: attractive as it is electrodeless (and thus...

168

amplitude electrostatic wave: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Suresh 2012-07-25 20 Experiment for Plasma Energization with Beating Electrostatic Waves Plasma Physics and Fusion Websites Summary: attractive as it is electrodeless (and thus...

169

E-Print Network 3.0 - accelerated electrostatic interactions...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

<< < 1 2 3 4 5 > >> 1 Fly-Casting in Protein-DNA Binding: Frustration between Protein Folding and Electrostatics Facilitates Target Recognition Summary: , the free energy...

170

FIELD TEST PROGRAM TO DEVELOP COMPREHENSIVE DESIGN, OPERATING AND COST DATA FOR MERCURY CONTROL SYSTEMS ON NON-SCRUBBED COAL-FIRED BOILERS  

SciTech Connect (OSTI)

With the nation's coal-burning utilities facing the possibility of tighter controls on mercury pollutants, the U.S. Department of Energy is funding projects that could offer power plant operators better ways to reduce these emissions at much lower costs. Mercury is known to have toxic effects on the nervous systems of humans and wildlife. Although it exists only in trace amounts in coal, mercury is released when coal burns and can accumulate on land and in water. In water, bacteria transform the metal into methylmercury, the most hazardous form of the metal. Methylmercury can collect in fish and marine mammals in concentrations hundreds of thousands times higher than the levels in surrounding waters. One of the goals of DOE is to develop technologies by 2005 that will be capable of cutting mercury emissions 50 to 70 percent at well under one-half of projected DOE/EPA early cost estimates. ADA Environmental Solutions (ADA-ES) is managing a project to test mercury control technologies at full scale at four different power plants from 2000--2003. The ADA-ES project is focused on those power plants that are not equipped with wet flue gas desulfurization systems. ADA-ES has developed a portable system that will be tested at four different utility power plants. Each of the plants is equipped with either electrostatic precipitators or fabric filters to remove solid particles from the plant's flue gas. ADA-ES's technology will inject a dry sorbent, such as activated carbon, which removes the mercury and makes it more susceptible to capture by the particulate control devices. A fine water mist may be sprayed into the flue gas to cool its temperature to the range where the dry sorbent is most effective. PG&E National Energy Group is providing two test sites that fire bituminous coals and both are equipped with electrostatic precipitators and carbon/ash separation systems. Wisconsin Electric Power Company is providing a third test site that burns Powder River Basin (PRB) coal and has an electrostatic precipitator for particulate control. Alabama Power Company will host a fourth test at its Plant Gaston, which is equipped with a hot-side electrostatic precipitator and a downstream fabric filter.

Jean Bustard

2004-04-27T23:59:59.000Z

171

FIELD TEST PROGRAM TO DEVELOP COMPREHENSIVE DESIGN, OPERATING AND COST DATA FOR MERCURY CONTROL SYSTEMS ON NON-SCRUBBED COAL-FIRED BOILERS  

SciTech Connect (OSTI)

With the Nation's coal-burning utilities facing the possibility of tighter controls on mercury pollutants, the U.S. Department of Energy is funding projects that could offer power plant operators better ways to reduce these emissions at much lower costs. Mercury is known to have toxic effects on the nervous system of humans and wildlife. Although it exists only in trace amounts in coal, mercury is released when coal burns and can accumulate on land and in water. In water, bacteria transform the metal into methylmercury, the most hazardous form of the metal. Methylmercury can collect in fish and marine mammals in concentrations hundreds of thousands times higher than the levels in surrounding waters. One of the goals of DOE is to develop technologies by 2005 that will be capable of cutting mercury emissions 50 to 70 percent at well under one-half of today's costs. ADA Environmental Solutions (ADA-ES) is managing a project to test mercury control technologies at full scale at four different power plants from 2000--2003. The ADA-ES project is focused on those power plants that are not equipped with wet flue gas desulfurization systems. ADA-ES will develop a portable system that will be moved to four different utility power plants for field testing. Each of the plants is equipped with either electrostatic precipitators or fabric filters to remove solid particles from the plant's flue gas. ADA-ES's technology will inject a dry sorbent, such as fly ash or activated carbon, that removes the mercury and makes it more susceptible to capture by the particulate control devices. A fine water mist may be sprayed into the flue gas to cool its temperature to the range where the dry sorbent is most effective. PG&E National Energy Group is providing two test sites that fire bituminous coals and are both equipped with electrostatic precipitators and carbon/ash separation systems. Wisconsin Electric Power Company is providing a third test site that burns Powder River Basin (PRB) coal and has an electrostatic precipitator for particulate control. Alabama Power Company will host a fourth test at its Plant Gaston, which is equipped with a hot-side electrostatic precipitator and a downstream fabric filter.

C. Jean Bustard

2001-10-01T23:59:59.000Z

172

FIELD TEST PROGRAM TO DEVELOP COMPREHENSIVE DESIGN, OPERATING AND COST DATA FOR MERCURY CONTROL SYSTEMS ON NON-SCRUBBED COAL-FIRED BOILERS  

SciTech Connect (OSTI)

With the Nation's coal-burning utilities facing the possibility of tighter controls on mercury pollutants, the U.S. Department of Energy is funding projects that could offer power plant operators better ways to reduce these emissions at much lower costs. Mercury is known to have toxic effects on the nervous system of humans and wildlife. Although it exists only in trace amounts in coal, mercury is released when coal burns and can accumulate on land and in water. In water, bacteria transform the metal into methylmercury, the most hazardous form of the metal. Methylmercury can collect in fish and marine mammals in concentrations hundreds of thousands times higher than the levels in surrounding waters. One of the goals of DOE is to develop technologies by 2005 that will be capable of cutting mercury emissions 50 to 70 percent at well under one-half of today's costs. ADA Environmental Solutions (ADA-ES) is managing a project to test mercury control technologies at full scale at four different power plants from 2000--2003. The ADA-ES project is focused on those power plants that are not equipped with wet flue gas desulfurization systems. ADA-ES will develop a portable system that will be moved to four different utility power plants for field testing. Each of the plants is equipped with either electrostatic precipitators or fabric filters to remove solid particles from the plant's flue gas. ADA-ES's technology will inject a dry sorbent, such as fly ash or activated carbon, that removes the mercury and makes it more susceptible to capture by the particulate control devices. A fine water mist may be sprayed into the flue gas to cool its temperature to the range where the dry sorbent is most effective. PG and E National Energy Group is providing two test sites that fire bituminous coals and are both equipped with electrostatic precipitators and carbon/ash separation systems. Wisconsin Electric Power Company is providing a third test site that burns Powder River Basin coal and has an electrostatic precipitator for particulate control. Alabama Power Company will host a fourth test at its Plant Gaston, which is equipped with a hot-side electrostatic precipitator and a downstream fabric filter.

C. Jean Bustard

2001-07-06T23:59:59.000Z

173

FIELD TEST PROGRAM TO DEVELOP COMPREHENSIVE DESIGN, OPERATING AND COST DATA FOR MERCURY CONTROL SYSTEMS ON NON-SCRUBBED COAL-FIRED BOILERS  

SciTech Connect (OSTI)

With the nation's coal-burning utilities facing the possibility of tighter controls on mercury pollutants, the U.S. Department of Energy is funding projects that could offer power plant operators better ways to reduce these emissions at much lower costs. Mercury is known to have toxic effects on the nervous systems of humans and wildlife. Although it exists only in trace amounts in coal, mercury is released when coal burns and can accumulate on land and in water. In water, bacteria transform the metal into methylmercury, the most hazardous form of the metal. Methylmercury can collect in fish and marine mammals in concentrations hundreds of thousands times higher than the levels in surrounding waters. One of the goals of DOE is to develop technologies by 2005 that will be capable of cutting mercury emissions 50 to 70 percent at well under one-half of projected DOE/EPA early cost estimates. ADA Environmental Solutions (ADA-ES) is managing a project to test mercury control technologies at full scale at four different power plants from 2000-2003. The ADA-ES project is focused on those power plants that are not equipped with wet flue gas desulfurization systems. ADA-ES has developed a portable system that was tested at four different utility power plants. Each of the plants is equipped with either electrostatic precipitators or fabric filters to remove solid particles from the plant's flue gas. ADA-ES's technology injects a dry sorbent, such as activated carbon, which removes the mercury and makes it more susceptible to capture by the particulate control devices. PG&E National Energy Group provided two test sites that fire bituminous coals and both are equipped with electrostatic precipitators and carbon/ash separation systems. Wisconsin Electric Power Company provided a third test site that burns Powder River Basin (PRB) coal and has an electrostatic precipitator for particulate control. Alabama Power Company hosted a fourth test at its Plant Gaston, which is equipped with a hot-side electrostatic precipitator and a downstream fabric filter. During the fifteenth reporting quarter, progress was made on the project in the following areas: (1) Test Sites--Final Reports for the two remaining plants are being written (Salem Harbor and Brayton Point). (2) Technology Transfer--Technical information about the project was presented to a number of organizations during the quarter including members of congress, coal companies, architect/engineering firms, National Mining Association, the North Carolina Department of Air Quality, the National Coal Council and EPA.

Jean Bustard; Richard Schlager

2004-08-03T23:59:59.000Z

174

FIELD TEST PROGRAM TO DEVELOP COMPREHENSIVE DESIGN, OPERATING AND COST DATA FOR MERCURY CONTROL SYSTEMS ON NON-SCRUBBED COAL-FIRED BOILERS  

SciTech Connect (OSTI)

With the Nation's coal-burning utilities facing the possibility of tighter controls on mercury pollutants, the U.S. Department of Energy is funding projects that could offer power plant operators better ways to reduce these emissions at much lower costs. Mercury is known to have toxic effects on the nervous system of humans and wildlife. Although it exists only in trace amounts in coal, mercury is released when coal burns and can accumulate on land and in water. In water, bacteria transform the metal into methylmercury, the most hazardous form of the metal. Methylmercury can collect in fish and marine mammals in concentrations hundreds of thousands times higher than the levels in surrounding waters. One of the goals of DOE is to develop technologies by 2005 that will be capable of cutting mercury emissions 50 to 70 percent at well under one-half of today's costs. ADA Environmental Solutions (ADA-ES) is managing a project to test mercury control technologies at full scale at four different power plants from 2000-2003. The ADA-ES project is focused on those power plants that are not equipped with wet flue gas desulfurization systems. ADA-ES has developed a portable system that will be tested at four different utility power plants. Each of the plants is equipped with either electrostatic precipitators or fabric filters to remove solid particles from the plant's flue gas. ADA-ES's technology will inject a dry sorbent, such as activated carbon, which removes the mercury and makes it more susceptible to capture by the particulate control devices. A fine water mist may be sprayed into the flue gas to cool its temperature to the range where the dry sorbent is most effective. PG&E National Energy Group is providing two test sites that fire bituminous coals and both are equipped with electrostatic precipitators and carbon/ash separation systems. Wisconsin Electric Power Company is providing a third test site that burns Powder River Basin (PRB) coal and has an electrostatic precipitator for particulate control. Alabama Power Company will host a fourth test at its Plant Gaston, which is equipped with a hot-side electrostatic precipitator and a downstream fabric filter. During the eleventh reporting quarter, progress was made on the project in the following areas: (1) All Test Sites--Final reports for Gaston and Pleasant Prairie are complete and have been issued; and Ongoing data and sample analysis is nearly complete as well as work on the final reports. (2) Technology Transfer--A number of technical presentations and briefings were made during the quarter. Several papers were presented at the MEGA Symposium in Washington DC.

Richard Schlager; Tom Millar

2003-07-01T23:59:59.000Z

175

FIELD TEST PROGRAM TO DEVELOP COMPREHENSIVE DESIGN, OPERATING AND COST DATA FOR MERCURY CONTROL SYSTEMS ON NON-SCRUBBED COAL-FIRED BOILERS  

SciTech Connect (OSTI)

With the Nation's coal-burning utilities facing the possibility of tighter controls on mercury pollutants, the U.S. Department of Energy is funding projects that could offer power plant operators better ways to reduce these emissions at much lower costs. Mercury is known to have toxic effects on the nervous system of humans and wildlife. Although it exists only in trace amounts in coal, mercury is released when coal burns and can accumulate on land and in water. In water, bacteria transform the metal into methylmercury, the most hazardous form of the metal. Methylmercury can collect in fish and marine mammals in concentrations hundreds of thousands times higher than the levels in surrounding waters. One of the goals of DOE is to develop technologies by 2005 that will be capable of cutting mercury emissions 50 to 70 percent at well under one-half of today's costs. ADA Environmental Solutions (ADA-ES) is managing a project to test mercury control technologies at full scale at four different power plants from 2000 to 2003. The ADA-ES project is focused on those power plants that are not equipped with wet flue gas desulfurization systems. ADA-ES will develop a portable system that will be moved to four different utility power plants for field testing. Each of the plants is equipped with either electrostatic precipitators or fabric filters to remove solid particles from the plant's flue gas. ADA-ES's technology will inject a dry sorbent, such as fly ash or activated carbon, that removes the mercury and makes it more susceptible to capture by the particulate control devices. A fine water mist may be sprayed into the flue gas to cool its temperature to the range where the dry sorbent is most effective. PG and E National Energy Group is providing two test sites that fire bituminous coals and are both equipped with electrostatic precipitators and carbon/ash separation systems. Wisconsin Electric Power Company is providing a third test site that burns Powder River Basin (PRB) coal and has an electrostatic precipitator for particulate control. Alabama Power Company will host a fourth test at its Plant Gaston, which is equipped with a hot-side electrostatic precipitator and a downstream fabric filter.

C. Jean Bustard

2001-07-31T23:59:59.000Z

176

FIELD TEST PROGRAM TO DEVELOP COMPREHENSIVE DESIGN, OPERATING AND COST DATA FOR MERCURY CONTROL SYSTEMS ON NON-SCRUBBED COAL-FIRED BOILERS  

SciTech Connect (OSTI)

With the nation's coal-burning utilities facing the possibility of tighter controls on mercury pollutants, the U.S. Department of Energy is funding projects that could offer power plant operators better ways to reduce these emissions at much lower costs. Mercury is known to have toxic effects on the nervous systems of humans and wildlife. Although it exists only in trace amounts in coal, mercury is released when coal burns and can accumulate on land and in water. In water, bacteria transform the metal into methylmercury, the most hazardous form of the metal. Methylmercury can collect in fish and marine mammals in concentrations hundreds of thousands times higher than the levels in surrounding waters. One of the goals of DOE is to develop technologies by 2005 that will be capable of cutting mercury emissions 50 to 70 percent at well under one-half of projected DOE/EPA early cost estimates. ADA Environmental Solutions (ADA-ES) is managing a project to test mercury control technologies at full scale at four different power plants from 2000-2003. The ADA-ES project is focused on those power plants that are not equipped with wet flue gas desulfurization systems. ADA-ES has developed a portable system that was tested at four different utility power plants. Each of the plants is equipped with either electrostatic precipitators or fabric filters to remove solid particles from the plant's flue gas. ADA-ES's technology injects a dry sorbent, such as activated carbon, which removes the mercury and makes it more susceptible to capture by the particulate control devices. PG&E National Energy Group provided two test sites that fire bituminous coals and both are equipped with electrostatic precipitators and carbon/ash separation systems. Wisconsin Electric Power Company provided a third test site that burns Powder River Basin (PRB) coal and has an electrostatic precipitator for particulate control. Alabama Power Company hosted a fourth test at its Plant Gaston, which is equipped with a hot-side electrostatic precipitator and a downstream fabric filter. During the seventeenth reporting quarter, progress was made on the project in the following areas: Test Sites--The Topical Report for the Salem Harbor Station was issued during the quarter. The Topical Report for the Brayton Point Station testing is in preparation; and Technology Transfer--Technical information about the project was presented at PowerGen and at an A&WMA Rocky Mountain States Section meeting.

Jean Bustard; Richard Schlager

2005-01-03T23:59:59.000Z

177

FIELD TEST PROGRAM TO DEVELOP COMPREHENSIVE DESIGN, OPERATING AND COST DATA FOR MERCURY CONTROL SYSTEMS ON NON-SCRUBBED COAL-FIRED BOILERS  

SciTech Connect (OSTI)

With the Nation's coal-burning utilities facing the possibility of tighter controls on mercury pollutants, the U.S. Department of Energy is funding projects that could offer power plant operators better ways to reduce these emissions at much lower costs. Mercury is known to have toxic effects on the nervous system of humans and wildlife. Although it exists only in trace amounts in coal, mercury is released when coal burns and can accumulate on land and in water. In water, bacteria transform the metal into methylmercury, the most hazardous form of the metal. Methylmercury can collect in fish and marine mammals in concentrations hundreds of thousands times higher than the levels in surrounding waters. One of the goals of DOE is to develop technologies by 2005 that will be capable of cutting mercury emissions 50 to 70 percent at well under one-half of today's costs. ADA Environmental Solutions (ADA-ES) is managing a project to test mercury control technologies at full scale at four different power plants from 2000-2003. The ADA-ES project is focused on those power plants that are not equipped with wet flue gas desulfurization systems. ADA-ES has developed a portable system that will be tested at four different utility power plants. Each of the plants is equipped with either electrostatic precipitators or fabric filters to remove solid particles from the plant's flue gas. ADA-ES's technology will inject a dry sorbent, such as activated carbon, which removes the mercury and makes it more susceptible to capture by the particulate control devices. A fine water mist may be sprayed into the flue gas to cool its temperature to the range where the dry sorbent is most effective. PG&E National Energy Group is providing two test sites that fire bituminous coals and both are equipped with electrostatic precipitators and carbon/ash separation systems. Wisconsin Electric Power Company is providing a third test site that burns Powder River Basin (PRB) coal and has an electrostatic precipitator for particulate control. Alabama Power Company will host a fourth test at its Plant Gaston, which is equipped with a hot-side electrostatic precipitator and a downstream fabric filter. During the twelfth reporting quarter, progress was made on the project in the following areas: All Test Sites--Ongoing data and sample analysis for the two remaining plants is nearly complete as well as work on the final reports. Technology Transfer--A number of technical presentations and briefings were made during the quarter. Several papers were presented at Air Quality IV in Washington D.C.

Richard Schlager; Tom Millar

2003-11-04T23:59:59.000Z

178

FIELD TEST PROGRAM TO DEVELOP COMPREHENSIVE DESIGN, OPERATING AND COST DATA FOR MERCURY CONTROL SYSTEMS ON NON-SCRUBBED COAL-FIRED BOILERS  

SciTech Connect (OSTI)

With the Nation's coal-burning utilities facing the possibility of tighter controls on mercury pollutants, the U.S. Department of Energy is funding projects that could offer power plant operators better ways to reduce these emissions at much lower costs. Mercury is known to have toxic effects on the nervous system of humans and wildlife. Although it exists only in trace amounts in coal, mercury is released when coal burns and can accumulate on land and in water. In water, bacteria transform the metal into methylmercury, the most hazardous form of the metal. Methylmercury can collect in fish and marine mammals in concentrations hundreds of thousands times higher than the levels in surrounding waters. One of the goals of DOE is to develop technologies by 2005 that will be capable of cutting mercury emissions 50 to 70 percent at well under one-half of today's costs. ADA Environmental Solutions (ADA-ES) is managing a project to test mercury control technologies at full scale at four different power plants from 2000--2003. The ADA-ES project is focused on those power plants that are not equipped with wet flue gas desulfurization systems. ADA-ES will develop a portable system that will be moved to four different utility power plants for field testing. Each of the plants is equipped with either electrostatic precipitators or fabric filters to remove solid particles from the plant's flue gas. ADA-ES's technology will inject a dry sorbent, such as fly ash or activated carbon, that removes the mercury and makes it more susceptible to capture by the particulate control devices. A fine water mist may be sprayed into the flue gas to cool its temperature to the range where the dry sorbent is most effective. PG&E National Energy Group is providing two test sites that fire bituminous coals and are both equipped with electrostatic precipitators and carbon/ash separation systems. Wisconsin Electric Power Company is providing a third test site that burns Powder River Basin (PRB) coal and has an electrostatic precipitator for particulate control. Alabama Power Company will host a fourth test at its Plant Gaston, which is equipped with a hot-side electrostatic precipitator and a downstream fabric filter.

Richard Schlager

2002-04-19T23:59:59.000Z

179

FIELD TEST PROGRAM TO DEVELOP COMPREHENSIVE DESIGN, OPERATING AND COST DATA FOR MERCURY CONTROL SYSTEMS ON NON-SCRUBBED COAL-FIRED BOILERS  

SciTech Connect (OSTI)

With the Nation's coal-burning utilities facing the possibility of tighter controls on mercury pollutants, the U.S. Department of Energy is funding projects that could offer power plant operators better ways to reduce these emissions at much lower costs. Mercury is known to have toxic effects on the nervous system of humans and wildlife. Although it exists only in trace amounts in coal, mercury is released when coal burns and can accumulate on land and in water. In water, bacteria transform the metal into methylmercury, the most hazardous form of the metal. Methylmercury can collect in fish and marine mammals in concentrations hundreds of thousands times higher than the levels in surrounding waters. One of the goals of DOE is to develop technologies by 2005 that will be capable of cutting mercury emissions 50 to 70 percent at well under one-half of today's costs. ADA Environmental Solutions (ADA-ES) is managing a project to test mercury control technologies at full scale at four different power plants from 2000--2003. The ADA-ES project is focused on those power plants that are not equipped with wet flue gas desulfurization systems. ADA-ES will develop a portable system that will be moved to four different utility power plants for field testing. Each of the plants is equipped with either electrostatic precipitators or fabric filters to remove solid particles from the plant's flue gas. ADA-ES's technology will inject a dry sorbent, such as fly ash or activated carbon, that removes the mercury and makes it more susceptible to capture by the particulate control devices. A fine water mist may be sprayed into the flue gas to cool its temperature to the range where the dry sorbent is most effective. PG&E National Energy Group is providing two test sites that fire bituminous coals and are both equipped with electrostatic precipitators and carbon/ash separation systems. Wisconsin Electric Power Company is providing a third test site that burns Powder River Basin (PRB) coal and has an electrostatic precipitator for particulate control. Alabama Power Company will host a fourth test at its Plant Gaston, which is equipped with a hot-side electrostatic precipitator and a downstream fabric filter.

C. Jean Bustard

2002-01-07T23:59:59.000Z

180

FIELD TEST PROGRAM TO DEVELOP COMPREHENSIVE DESIGN, OPERATING AND COST DATA FOR MERCURY CONTROL SYSTEMS ON NON-SCRUBBED COAL-FIRED BOILERS  

SciTech Connect (OSTI)

With the nation's coal-burning utilities facing the possibility of tighter controls on mercury pollutants, the U.S. Department of Energy is funding projects that could offer power plant operators better ways to reduce these emissions at much lower costs. Mercury is known to have toxic effects on the nervous systems of humans and wildlife. Although it exists only in trace amounts in coal, mercury is released when coal burns and can accumulate on land and in water. In water, bacteria transform the metal into methylmercury, the most hazardous form of the metal. Methylmercury can collect in fish and marine mammals in concentrations hundreds of thousands times higher than the levels in surrounding waters. One of the goals of DOE is to develop technologies by 2005 that will be capable of cutting mercury emissions 50 to 70 percent at well under one-half of projected DOE/EPA early cost estimates. ADA Environmental Solutions (ADA-ES) is managing a project to test mercury control technologies at full scale at four different power plants from 2000-2003. The ADA-ES project is focused on those power plants that are not equipped with wet flue gas desulfurization systems. ADA-ES has developed a portable system that was tested at four different utility power plants. Each of the plants is equipped with either electrostatic precipitators or fabric filters to remove solid particles from the plant's flue gas. ADA-ES's technology injects a dry sorbent, such as activated carbon, which removes the mercury and makes it more susceptible to capture by the particulate control devices. PG&E National Energy Group provided two test sites that fire bituminous coals and both are equipped with electrostatic precipitators and carbon/ash separation systems. Wisconsin Electric Power Company provided a third test site that burns Powder River Basin (PRB) coal and has an electrostatic precipitator for particulate control. Alabama Power Company hosted a fourth test at its Plant Gaston, which is equipped with a hot-side electrostatic precipitator and a downstream fabric filter. During the sixteenth reporting quarter, progress was made on the project in the following areas: (1) Test Sites--The Topical Report for the Salem Harbor Station testing was completed during the quarter and will be issued early next quarter. The Topical Report for the Brayton Point Station testing is in preparation. (2) Technology Transfer--Technical information about the project was presented to a chemistry workshop during the quarter.

Jean Bustard; Richard Schlager

2004-10-25T23:59:59.000Z

Note: This page contains sample records for the topic "desulfurization systems electrostatic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

FIELD TEST PROGRAM TO DEVELOP COMPREHENSIVE DESIGN, OPERATING AND COST DATA FOR MERCURY CONTROL SYSTEMS ON NON-SCRUBBED COAL-FIRED BOILERS  

SciTech Connect (OSTI)

With the Nation's coal-burning utilities facing the possibility of tighter controls on mercury pollutants, the U.S. Department of Energy is funding projects that could offer power plant operators better ways to reduce these emissions at much lower costs. Mercury is known to have toxic effects on the nervous system of humans and wildlife. Although it exists only in trace amounts in coal, mercury is released when coal burns and can accumulate on land and in water. In water, bacteria transform the metal into methylmercury, the most hazardous form of the metal. Methylmercury can collect in fish and marine mammals in concentrations hundreds of thousands times higher than the levels in surrounding waters. One of the goals of DOE is to develop technologies by 2005 that will be capable of cutting mercury emissions 50 to 70 percent at well under one-half of today's costs. ADA Environmental Solutions (ADA-ES) is managing a project to test mercury control technologies at full scale at four different power plants from 2000-2003. The ADA-ES project is focused on those power plants that are not equipped with wet flue gas desulfurization systems. ADA-ES has developed a portable system that will be tested at four different utility power plants. Each of the plants is equipped with either electrostatic precipitators or fabric filters to remove solid particles from the plant's flue gas. ADA-ES's technology will inject a dry sorbent, such as activated carbon, which removes the mercury and makes it more susceptible to capture by the particulate control devices. A fine water mist may be sprayed into the flue gas to cool its temperature to the range where the dry sorbent is most effective. PG&E National Energy Group is providing two test sites that fire bituminous coals and both are equipped with electrostatic precipitators and carbon/ash separation systems. Wisconsin Electric Power Company is providing a third test site that burns Powder River Basin (PRB) coal and has an electrostatic precipitator for particulate control. Alabama Power Company will host a fourth test at its Plant Gaston, which is equipped with a hot-side electrostatic precipitator and a downstream fabric filter. During the thirteenth reporting quarter, progress was made on the project in the following areas: All Test Sites--Ongoing data and sample analysis for the two remaining plants is nearly complete as well as work on the final reports. Technology Transfer--A number of technical presentations and briefings were made during the quarter.

Richard Schlager; Tom Millar

2003-03-02T23:59:59.000Z

182

FIELD TEST PROGRAM TO DEVELOP COMPREHENSIVE DESIGN, OPERATING AND COST DATA FOR MERCURY CONTROL SYSTEMS ON NON-SCRUBBED COAL-FIRED BOILERS  

SciTech Connect (OSTI)

With the Nation's coal-burning utilities facing the possibility of tighter controls on mercury pollutants, the U.S. Department of Energy is funding projects that could offer power plant operators better ways to reduce these emissions at much lower costs. Mercury is known to have toxic effects on the nervous system of humans and wildlife. Although it exists only in trace amounts in coal, mercury is released when coal burns and can accumulate on land and in water. In water, bacteria transform the metal into methylmercury, the most hazardous form of the metal. Methylmercury can collect in fish and marine mammals in concentrations hundreds of thousands times higher than the levels in surrounding waters. One of the goals of DOE is to develop technologies by 2005 that will be capable of cutting mercury emissions 50 to 70 percent at well under one-half of today's costs. ADA Environmental Solutions (ADA-ES) is managing a project to test mercury control technologies at full scale at four different power plants from 2000--2003. The ADA-ES project is focused on those power plants that are not equipped with wet flue gas desulfurization systems. ADA-ES has developed a portable system that will be tested at four different utility power plants. Each of the plants is equipped with either electrostatic precipitators or fabric filters to remove solid particles from the plant's flue gas. ADA-ES's technology will inject a dry sorbent, such as activated carbon, which removes the mercury and makes it more susceptible to capture by the particulate control devices. A fine water mist may be sprayed into the flue gas to cool its temperature to the range where the dry sorbent is most effective. PG&E National Energy Group is providing two test sites that fire bituminous coals and both are equipped with electrostatic precipitators and carbon/ash separation systems. Wisconsin Electric Power Company is providing a third test site that burns Powder River Basin (PRB) coal and has an electrostatic precipitator for particulate control. Alabama Power Company will host a fourth test at its Plant Gaston, which is equipped with a hot-side electrostatic precipitator and a downstream fabric filter. During the tenth reporting quarter, progress was made on the project in the following areas: (1) All Test Sites--Ongoing data and sample analysis as well as work on the final reports. (2) Technology Transfer--A number of technical presentations and briefings were made during the quarter. One paper was presented at the American Coal Council Workshop and one at the EUCE Conference.

Richard Schlager; Tom Millar

2003-04-28T23:59:59.000Z

183

System for adding sulfur to a fuel cell stack system for improved fuel cell stability  

DOE Patents [OSTI]

A system for adding sulfur to a fuel cell stack, having a reformer adapted to reform a hydrocarbon fuel stream containing sulfur contaminants, thereby providing a reformate stream having sulfur; a sulfur trap fluidly coupled downstream of the reformer for removing sulfur from the reformate stream, thereby providing a desulfurized reformate stream; and a metering device in fluid communication with the reformate stream upstream of the sulfur trap and with the desulfurized reformate stream downstream of the sulfur trap. The metering device is adapted to bypass a portion of the reformate stream to mix with the desulfurized reformate stream, thereby producing a conditioned reformate stream having a predetermined sulfur concentration that gives an acceptable balance of minimal drop in initial power with the desired maximum stability of operation over prolonged periods for the fuel cell stack.

Mukerjee, Subhasish (Pittsford, NY); Haltiner, Jr., Karl J (Fairport, NY); Weissman, Jeffrey G. (West Henrietta, NY)

2012-03-06T23:59:59.000Z

184

Utility FGD survey, January--December 1989. Volume 2, Design performance data for operating FGD systems: Part 2  

SciTech Connect (OSTI)

This is Volume 2 part 2, of the Utility flue gas desulfurization (FGD) Survey report, which is generated by a computerized data base management system, represents a survey of operational and planned domestic utility flue gas desulfurization (FGD) systems. It summarizes information contributed by the utility industry, system and equipment suppliers, system designers, research organizations, and regulatory agencies. The data cover system design, fuel characteristics, operating history, and actual system performance. Also included is a unit-by-unit discussion of problems and solutions associated with the boilers, scrubbers, and FGD systems. This volume particularly contains basic design and performance data.

Hance, S.L.; McKibben, R.S.; Jones, F.M. [IT Corp., Cincinnati, OH (United States)] [IT Corp., Cincinnati, OH (United States)

1992-03-01T23:59:59.000Z

185

Electrostatic precipitator having high strength discharge electrode  

SciTech Connect (OSTI)

There is disclosed an electrostatic precipitator with a discharge electrode having dimensional and configuration characteristics which provide high field strength and high current density particularly in a wet electrostatic precipitator. The round cylindrical collector tube of length (L) and with an inner diameter (D) has a coaxially positioned discharge electrode having an electrode supporting mast of a diameter from 0.25 to 40 D with an electrically conducting closed screw fli secured to the mast. The screw flight has an overall diameter (D) of from 0.33 to 0.67 D with a pitch of from d-d/2 to d-d and an overall length of from one screw revolution to l-(D-d), preferably one-half L or less and most preferably one to two revolutions. The short screw flight is economical and readily adjusted. The screw flight has a thickness of from about 0.05 to 15 inch and has a symmetrically curved outer edge. Collector tube is flared at its lower end to direct water away from the electrode mast as the water is discharged from the tube. The discharge electrode is supported from above and centered by means of adjustable tie rods at its lower end.

Bakke, E.; Willett, H.P.

1983-06-21T23:59:59.000Z

186

Microbial reduction of SO{sub 2} and NO{sub x} as a means of by-product recovery/disposal from regenerable processes for the desulfurization of flue gas. Final report  

SciTech Connect (OSTI)

The main objective of this research was to investigate microorganisms capable of fossil fuel flue gas desulfurization and denitrification. The study used municipal sewage sludge as a carbon and energy source for SO{sub 2}-reducing cultures. The individual tasks developed a consortium of sulfate-reducing bacteria, investigated the design parameters for a continuous process, preformed a cost analysis, and screened sulfate-reducing bacteria. In the investigation of microbial reduction of NO{sub x} to nitrogen, tasks included screening denitrifying bacteria for NO and NO{sub 2} activity, developing optimum NO-reducing cultures, and investigating design parameters for a continuous system. This final report reviews the work previous to the current project, describes project objectives and the specific work plan, and reports results from the work completed during the previous reporting periods.

Sublette, K.L.

1994-03-01T23:59:59.000Z

187

Electrostatic Free Energy and its Variations in Implicit Solvent Models  

E-Print Network [OSTI]

Electrostatic Free Energy and its Variations in Implicit Solvent Models Jianwei Che , Joachim. The unique set of such concentrations that minimize this free energy are given by the usual Boltzmann. The variation of the electrostatic free energy with respect to the location change of solute-solvent interfaces

Li, Bo

188

A Nystrom algorithm for electrostatics of an anisotropic composite  

E-Print Network [OSTI]

A Nystrom algorithm for electrostatics of an anisotropic composite Johan Helsing Department algorithms for the electrostatics of locally anisotropic composites seems to be a poorly explored area ective properties of lo- cally anisotropic composites is a topic of importance in physics and in physical

Helsing, Johan

189

Construction of an Electrostatic Energy Analyzer for the EQUARS Scientific Satellite  

E-Print Network [OSTI]

Construction of an Electrostatic Energy Analyzer for the EQUARS Scientific Satellite The ELISAScientific Objectives Electron Precipitation in the South Atlantic Magnetic Anomaly Electrons with E with IONEX project (fluctuations) The Electrostatic Energy AnalyzerThe Electrostatic Energy Analyzer rext

190

Reduction of spalling in mixed metal oxide desulfurization sorbents by addition of a large promoter metal oxide  

DOE Patents [OSTI]

Mixed metal oxide pellets for removing hydrogen sulfide from fuel gas mixes derived from coal are stabilized for operation over repeated cycles of desulfurization and regeneration reactions by addition of a large promoter metal oxide such as lanthanum trioxide. The pellets, which may be principally made up of a mixed metal oxide such as zinc titanate, exhibit physical stability and lack of spalling or decrepitation over repeated cycles without loss of reactivity. The lanthanum oxide is mixed with pellet-forming components in an amount of 1 to 10 weight percent.

Poston, James A. (Star City, WV)

1997-01-01T23:59:59.000Z

191

Use of ferric sulfate: acid media for the desulfurization of model compounds of coal. [Dibenzothiophene, diphenyl sulfide, di-n-butyl sulfide  

SciTech Connect (OSTI)

The objective of this work has been to investigate the ability of ferric sulfate-acid leach systems to oxidize the sulfur in model compounds of coal. Ferric iron-acid leach systems have been shown to be quite effective at removal of inorganic sulfur in coal. In this study, the oxidative effect of ferric iron in acid-leach systems was studied using dibenzothiophene, diphenyl sulfide, and di-n-butyl sulfide as models of organic sulfur groups in coal. Nitrogen and oxygen, as well as various transition metal catalysts and oxidants, were utilized in this investigation. Dibenzothiophene was found to be quite refractory to oxidation, except in the case where metavanadate was added, where it appears that 40% oxidation to sulfone could have occurred per hour at 150/sup 0/C and mild oxygen pressure. Diphenyl sulfide was selectively oxidized to sulfoxide and sulfone in an iron and oxygen system. Approximately 15% conversion to sulfone occurred per hour under these conditions. Some of the di-n-butyl sulfide was cracked to 1-butene and 1-butanethiol under similar conditions. Zinc chloride and ferric iron were used at 200/sup 0/C in an attempt to desulfonate dibenzothiophene sulfone, diphenyl sulfone, and di-n-butyl sulfone. Di-n-butyl sulfone was completely desulfurized on one hour and fragmented to oxidized parafins, while dibenzothiophene sulfone and diphenyl sulfone were unaffected. These results suggest that an iron-acid leach process could only selectively oxidize aryl sulfides under mild conditions, representing only 20% of the organic sulfur in coal (8% of the total sulfur). Removal through desulfonation once selective sulfur oxidation had occurred was only demonstrated for alkyl sulfones, with severe oxidation of the fragmented paraffins also occurring in one hour.

Clary, L.R.; Vermeulen, T.; Lynn, S.

1980-12-01T23:59:59.000Z

192

Electrostatic and Magnetic Fields in Bilayer Graphene  

E-Print Network [OSTI]

We compute the transmission probability through rectangular potential barriers and p-n junctions in the presence of a magnetic and electric fields in bilayer graphene taking into account the full four bands of the energy spectrum. For energy E higher than the interlayer coupling $\\gamma_1 (E>\\gamma_1)$ two propagation modes are available for transport giving rise to four possible ways for transmission and reflection probabilities. However, when the energy is less then the height of the barrier the Dirac fermions exhibits transmission resonances and only one mode of propagation is available. We study the effect of the interlayer electrostatic potential $\\delta$ and the different geometry parameters of the barrier on the transmission probability.

Ahmed Jellal; Ilham Redouani; Hocine Bahlouli

2014-11-14T23:59:59.000Z

193

Electrode supporting base for electrostatic precipitators  

SciTech Connect (OSTI)

The disclosure relates to a base for supporting hollow cylindrical and circular in cross section collector electrodes for an electrostatic precipitator. The base comprises a central portion and is generally circular; a plurality of arcuate venturi and collector trough assemblies which are generally circular and which intersect radially disposed drain troughs; said venturi and collector trough assemblies being concentric with said center portion of said base and drain troughs extending radially outward from said center portion; a circular wall structure secured to outer ends of said drain troughs; fixture means for securing said collector electrodes on said drain troughs; uppermost portions of said drain troughs and said venturi and collector troughs being substantially flush with each other and said venturi and collector trough assemblies disposed on a common plane to provide for uniform laminar flow relative to the collector electrodes.

Honacker, H.

1981-01-20T23:59:59.000Z

194

A NOVEL VAPOR-PHASE PROCESS FOR DEEP DESULFURIZATION OF NAPHTHA/DIESEL  

SciTech Connect (OSTI)

Tier 2 regulations issued by the U.S. Environmental Protection Agency (EPA) require a substantial reduction in the sulfur content of gasoline. Similar regulations have been enacted for the sulfur level in on-road diesel and recently off-road diesel. The removal of this sulfur with existing and installed technology faces technical and economic challenges. These challenges created the opportunity for new emerging technologies. Research Triangle Institute (RTI) with subcontract support from Kellogg Brown & Root, Inc., (KBR) used this opportunity to develop RTI's transport reactor naphtha desulfurization (TReND) process. Starting with a simple conceptual process design and some laboratory results that showed promise, RTI initiated an accelerated research program for sorbent development, process development, and marketing and commercialization. Sorbent development has resulted in the identification of an active and attrition resistant sorbent that has been prepared in commercial equipment in 100 lb batches. Process development has demonstrated both the sulfur removal performance and regeneration potential of this sorbent. Process development has scaled up testing from small laboratory to pilot plant transport reactor testing. Testing in the transport reactor pilot plant has demonstrated the attrition resistance, selective sulfur removal activity, and regeneration activity of this sorbent material. Marketing and commercialization activities have shown with the existing information that the process has significant capital and operating cost benefits over existing and other emerging technologies. The market assessment and analysis provided valuable feedback about the testing and performance requirements for the technical development program. This market analysis also provided a list of potential candidates for hosting a demonstration unit. Although the narrow window of opportunity generated by the new sulfur regulations and the conservative nature of the refining industry slowed progress of the demonstration unit, negotiations with potential partners are proceeding for commercialization of this process.

B.S. Turk; R.P. Gupta; S.K. Gangwal

2003-06-30T23:59:59.000Z

195

Charge trapping by anionic quinones electrostatically bound to a highly charged cationic quinone-viologen polymer or a cationic poly(3-viologen-thiophene)  

SciTech Connect (OSTI)

Charge associated with quinone reduction is trapped at low pH in systems composed of sulfonated anthraquinones electrostatically bound to a polymer derived from a monomer consisting of a quinone unit flanked by two viologen units. Each monomer repeat unit carries 6 equiv of positive charge which can be charge compensated by monosulfonated anthraquinone to yield a quinone-viologen ratio of nearly 7:2. At low pH, electrostatic binding is persistent, and the amount of trapped charge is 90% of the theoretical maximum. Some of the electrostatically bound quinine can be replaced with Fe(CN)[sub 6][sup 3[minus

Hable, C.T.; Crooks, R.M.; Valentine, J.R.; Giasson, R.; Wrighton, M.S. (Massachusetts Inst. of Technology, Cambridge (United States))

1993-06-03T23:59:59.000Z

196

Atmos. Chem. Phys., 10, 11831192, 2010 www.atmos-chem-phys.net/10/1183/2010/  

E-Print Network [OSTI]

Reduction (SCR), electrostatic precipitators (ESP), and flue gas desulfu- rization (FGD) using the Ontario), such as electrostatic precipitators (ESP), fabric filter (FF), and flue gas desulfurization (FGD) systems (US EPA, 1997 in the burned coal. The average mercury removal efficiencies of ESP, ESP plus wet FGD, and ESP plus dry FGD

Meskhidze, Nicholas

197

Desulfurization of fuel gases in fluidized bed gasification and hot fuel gas cleanup systems  

DOE Patents [OSTI]

A problem with the commercialization of fluidized bed gasification is that vast amounts of spent sorbent are generated if the sorbent is used on a once-through basis, especially if high sulfur coals are burned. The requirements of a sorbent for regenerative service in the FBG process are: (1) it must be capable of reducing the sulfur containing gas concentration of the FBG flue gas to within acceptable environmental standards; (2) it must not lose its reactivity on cyclic sulfidation and regeneration; (3) it must be capable of regeneration with elimination of substantially all of its sulfur content; (4) it must have good attrition resistance; and, (5) its cost must not be prohibitive. It has now been discovered that calcium silicate pellets, e.g., Portland cement type III pellets meet the criteria aforesaid. Calcium silicate removes COS and H/sub 2/S according to the reactions given to produce calcium sulfide silicate. The sulfur containing product can be regenerated using CO/sub 2/ as the regenerant. The sulfur dioxide can be conveniently reduced to sulfur with hydrogen or carbon for market or storage. The basic reactions in the process of this invention are the reactions with calcium silicate given in the patent. A convenient and inexpensive source of calcium silicate is Portland cement. Portland cement is a readily available, widely used construction meterial.

Steinberg, M.; Farber, G.; Pruzansky, J.; Yoo, H.J.; McGauley, P.

1983-08-26T23:59:59.000Z

198

Formation of a field reversed configuration for magnetic and electrostatic confinement of plasma  

DOE Patents [OSTI]

A system and method for containing plasma and forming a Field Reversed Configuration (FRC) magnetic topology are described in which plasma ions are contained magnetically in stable, non-adiabatic orbits in the FRC. Further, the electrons are contained electrostatically in a deep energy well, created by tuning an externally applied magnetic field. The simultaneous electrostatic confinement of electrons and magnetic confinement of ions avoids anomalous transport and facilitates classical containment of both electrons and ions. In this configuration, ions and electrons may have adequate density and temperature so that upon collisions they are fused together by nuclear force, thus releasing fusion energy. Moreover, the fusion fuel plasmas that can be used with the present confinement system and method are not limited to neutronic fuels only, but also advantageously include advanced fuels.

Rostoker, Norman; Binderbauer, Michl

2003-12-16T23:59:59.000Z

199

Formation of a field reversed configuration for magnetic and electrostatic confinement of plasma  

DOE Patents [OSTI]

A system and method for containing plasma and forming a Field Reversed Configuration (FRC) magnetic topology are described in which plasma ions are contained magnetically in stable, non-adiabatic orbits in the FRC. Further, the electrons are contained electrostatically in a deep energy well, created by tuning an externally applied magnetic field. The simultaneous electrostatic confinement of electrons and magnetic confinement of ions avoids anomalous transport and facilitates classical containment of both electrons and ions. In this configuration, ions and electrons may have adequate density and temperature so that upon collisions they are fused together by nuclear force, thus releasing fusion energy. Moreover, the fusion fuel plasmas that can be used with the present confinement system and method are not limited to neutronic fuels only, but also advantageously include advanced fuels.

Rostoker, Norman; Binderbauer, Michl; Qerushi, Artan; Tahsiri, Hooshang

2006-02-07T23:59:59.000Z

200

Formation of a field reversed configuration for magnetic and electrostatic confinement of plasma  

DOE Patents [OSTI]

A system and method for containing plasma and forming a Field Reversed Configuration (FRC) magnetic topology are described in which plasma ions are contained magnetically in stable, non-adiabatic orbits in the FRC. Further, the electrons are contained electrostatically in a deep energy well, created by tuning an externally applied magnetic field. The simultaneous electrostatic confinement of electrons and magnetic confinement of ions avoids anomalous transport and facilitates classical containment of both electrons and ions. In this configuration, ions and electrons may have adequate density and temperature so that upon collisions they are fused together by nuclear force, thus releasing fusion energy. Moreover, the fusion fuel plasmas that can be used with the present confinement system and method are not limited to neutronic fuels only, but also advantageously include advanced fuels.

Rostoker, Norman; Binderbauer, Michl; Qerushi, Artan; Tahsiri, Hooshang

2007-02-20T23:59:59.000Z

Note: This page contains sample records for the topic "desulfurization systems electrostatic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

ELECTROSTATIC MODE ASSOCIATED WITH PINCH VELOCITY IN RFPS  

SciTech Connect (OSTI)

The existence of a new electrostatic instability is shown for RFP (reversed field pinch) equilibria. This mode arises due to the non-zero equilibrium radial flow (pinch flow). In RFP simulations with no-stress boundary conditions on the tangential velocity at the radial wall, this electrostatic mode is unstable and dominates the nonlinear dynamics, even in the presence of the MHD modes typically responsible for the reversal of the axial magnetic field at edge. Nonlinearly, this mode leads to two beams moving azimuthally towards each other, which eventually collide. The electrostatic mode can be controlled by using Dirichlet (no-slip) boundary conditions on the azimuthal velocity at the radial wall.

DELZANNO, GIAN LUCA [Los Alamos National Laboratory; FINN, JOHN M. [Los Alamos National Laboratory; CHACON, LUIS [Los Alamos National Laboratory

2007-02-08T23:59:59.000Z

202

Electrostatic shape-shifting ion optics  

DOE Patents [OSTI]

Electrostatic shape-shifting ion optics includes an outer electrode that defines an interior region between first and second opposed open ends. A first inner electrode is positioned within the interior region of the outer electrode at about the first open end. A second inner electrode is positioned within the interior region of the outer electrode at about the second open end. A first end cap electrode is positioned at about a first open end of the first inner electrode so that the first end cap electrode substantially encloses the first open end of the first inner electrode. A second end cap electrode is positioned at about a second open end of the second inner electrode so that the second end cap electrode substantially encloses the second open end of the second inner electrode. A voltage source operatively connected to each of the electrodes applies voltage functions to each of the electrodes to produce an electric field within an interior space enclosed by the electrodes.

Dahl, David A.; Scott, Jill R.; Appelhans, Anthony D.

2006-05-02T23:59:59.000Z

203

Confined zone dispersion flue gas desulfurization demonstration. Quarterly report No. 8, August 17, 1992--November 16, 1992  

SciTech Connect (OSTI)

The CZD process involves injecting a finely atomized slurry of reactive lime into the flue gas duct work of a coal-fired utility boiler. The principle of the confined zone is to form a wet zone of slurry droplets in the middle of the duct confined in an envelope of hot gas between the wet zone and the duct walls. The lime slurry reacts with part of the SO{sub 2} in the gas, and the reaction products dry to form solid particles. A solids collector, typically an electrostatic precipitator (ESP) downstream from the point of injection, captures the reaction products along with the fly ash entrained in the flue gas. The goal of this demonstration is to prove the technical and economic feasibility of the CZD technology on a commercial scale. The process is expected to achieve 50% SO{sub 2} removal at lower capital and O&M costs than other systems. To achieve its objectives, the project is divided into the following three phases: Phase 1: Design and Permitting, Phase 2: Construction and Start-up, Phase 3: Operation and Disposition. Phase 1 activities were completed on January 31, 1991. Phase 2 activities were essentially concluded on July 31, 1991, and Phase 3a, Parametric Testing, was initiated on July 1, 1991. This Quarterly Technical Progress Report covers Phase 3b activities from August 17, 1992 through November 16, 1992.

Not Available

1993-09-27T23:59:59.000Z

204

Flue gas desulfurization sludge: establishment of vegetation on ponded and soil-applied waste. Final report January 1977-September 1981  

SciTech Connect (OSTI)

The report gives results of research to identify and evaluate forms of vegetation and methods of their establishment for reclaiming retired flue gas desulfurization sludge ponds. Also studied were the soil liming value of limestone scrubber sludge (LSS) and plant uptake and percolation losses of some chemical nutrients in the sludge. Several vegetation schemes were evaluated between 1977 and 1982 for covering and stabilizing LSS at Colbert Steam Plant, Cherokee, AL, and Shawnee Steam Plant, Paducah, KY. Eleven tree and 10 grass or legume species were tested for adaptability and survival when planted directly in LSS or in LSS amended with soil, municipal sewage sludge, or standard potting mix. Other studies indicated that LSS apparently has sufficient unreacted limestone to be a satisfactory soil liming agent.

Giordano, P.M.; Mays, D.A.; Soileau, J.M.

1984-01-01T23:59:59.000Z

205

Summary and assessment of METC zinc ferrite hot coal gas desulfurization test program, final report: Volume 2, Appendices  

SciTech Connect (OSTI)

The Morgantown Energy Technology Center (METC) has conducted a test program to develop a zinc ferrite-based high temperature desulfurization process which could be applied to fuel gas entering downstream components such as molten carbonate fuel cells or gas turbines. As a result of prior METC work with iron oxide and zinc oxide sorbents, zinc ferrite evolved as a candidate with the potential for high capacity, low equilibrium levels of H/sub 2/S, and structural stability after multiple regenerations. The program consisted of laboratory-scale testing with a two-inch diameter reactor and simulated fixed-bed gasifier gas; bench-scale testing with a six-inch diameter reactor and actual gas from the METC 42-inch fixed bed gasifier; as well as laboratory-scale testing of zinc ferrite with simulated fluidized bed gasifier gas. Data from sidestream testing are presented. 18 refs.

Underkoffler, V.S.

1986-12-01T23:59:59.000Z

206

Hot gas desulfurization with sorbents containing oxides of zinc, iron, vanadium and copper. Quarterly technical progress report, July 1992  

SciTech Connect (OSTI)

The main objective of this research is to evaluate the desulfurization performance of novel sorbents consisting of different combinations of zinc, iron, vanadium and copper oxides; and to develop a sorbent which can reduce H{sub 2}S levels to less than 1 ppmv, which can stabilize zinc, making operations above 650{degrees}C possible, and which can produce economically recoverable amounts of elemental sulfur during regeneration. This objective will be accomplished by evaluating the sorbent performance using fixed-bed and TGA experiments supported by sorbent characterization at various reaction extents. In the seventh quarter, the screening of the promoted sorbents in the packed bed reactor was continued. The results of this work were presented at the 1992 University Coal Research Contractors, Review Conference at Pittsburgh, PA.

Akyurtlu, A.; Akyurtlu, J.F.

1992-09-01T23:59:59.000Z

207

Dynamic pull-in of parallel plate and torsional electrostatic MEMS actuators.  

SciTech Connect (OSTI)

An analysis of the dynamic characteristics of pull-in for parallel-plate and torsional electrostatic actuators is presented. Traditionally, the analysis for pull-in has been done using quasi-static assumptions. However, it was recently shown experimentally that a step input can cause a decrease in the voltage required for pull-in to occur. We propose an energy-based solution for the step voltage required for pull-in that predicts the experimentally observed decrease in the pull-in voltage. We then use similar energy techniques to explore pull-in due to an actuation signal that is modulated depending on the sign of the velocity of the plate (i.e., modulated at the instantaneous mechanical resonant frequency). For this type of actuation signal, significant reductions in the pull-in voltage can theoretically be achieved without changing the stiffness of the structure. This analysis is significant to both parallel-plate and torsional electrostatic microelectromechanical systems (MEMS) switching structures where a reduced operating voltage without sacrificing stiffness is desired, as well as electrostatic MEMS oscillators where pull-in due to dynamic effects needs to be avoided.

Nielson, Gregory N.; Barbastathis, George (Massachusetts Institute of Technology, Cambridge, MA)

2005-02-01T23:59:59.000Z

208

Phenomenology of electrostatically charged droplet combustion in normal gravity  

SciTech Connect (OSTI)

Experimental findings are provided on the effect of electrostatically charging a fuel on single-burning droplet combustion in normal gravity. It was established that significant modification of the flame morphology and the droplet burning time could be achieved, solely by the droplet charge, without the application of external electric fields. Negative charging of the droplets of mixtures of isooctane with either ethanol or a commercially available anti-static additive generated intense motion of the flame and abbreviated the droplet burning time by as much as 40% for certain blend compositions. Positive charging of the droplets generated almost spherical flames, because electrostatic attraction toward the droplets countered the effect of buoyancy. By comparing combustion of droplets of the same conductivity but different compositions, coupling of electrostatics with combustion chemistry was established. (author)

Anderson, Eric K.; Koch, Jeremy A.; Kyritsis, Dimitrios C. [Department of Mechanical Science and Engineering, University of Illinois at Urbana-Champaign, Urbana, IL 61801 (United States)

2008-08-15T23:59:59.000Z

209

Confined zone dispersion flue gas desulfurization demonstration. Quarterly report No. 10, February 17--May 31, 1993  

SciTech Connect (OSTI)

The CZD process involves injecting a finely atomized slurry of reactive lime into the flue gas duct work of a coal-fired utility boiler. The principle of the confined zone is to form a wet zone of slurry droplets in the middle of the duct walls. The lime slurry reacts with part of the SO{sub 2} in the gas, and the reaction products dry to form solid particles. A solids collector, typically an electrostatic precipitator (ESP) downstream from the point of injection, captures the reaction products along with the fly ash entrained in the flue gas. The demonstration is being conducted at Penelec`s Seward Station, Unit No. 15. This boiler is a 147 MWe coal-fired unit, which utilizes Pennsylvania bituminous coal (approximately 1.2 to 2.5% sulfur). One of the two flue gas ducts leading from the boiler has been retrofitted with the CZD technology. The first existing ESP installed in the station is immediately behind the air preheater. The second ESP, installed about 15 years ago, is about 80 feet away from the first ESP. The goal of this demonstration is to prove the technical and economic feasibility of the CZD technology on a commercial scale. The process is expected to achieve 50% SO{sub 2}

Not Available

1993-11-15T23:59:59.000Z

210

Tuning size and electrostatics in non-polar colloidal asphaltene suspensions by polymeric adsorption  

E-Print Network [OSTI]

Tuning size and electrostatics in non-polar colloidal asphaltene suspensions by polymeric as a function of dispersant concentration, suggesting electrostatic repulsion as the primary stabilizing force lead to charge-stabilization of asphaltene colloids. Introduction Asphaltene precipitation causes

Firoozabadi, Abbas

211

Situ Discovery Electrostatic Potential, Trapping Electrons and Mediating Fast Reconnection Earth's Magnetotail  

E-Print Network [OSTI]

Situ Discovery Electrostatic Potential, Trapping Electrons and Mediating Fast Reconnection Earth phase distributions, measured Wind spacecraft a rare crossing diffusion region in Earth's magnetotail, the presence a strong electrostatic potential within ion diffusion region is revealed. potential reaching

Egedal, Jan

212

Charge Trapping in Carbon Nanotube Loops Demonstrated by Electrostatic  

E-Print Network [OSTI]

Charge Trapping in Carbon Nanotube Loops Demonstrated by Electrostatic Force Microscopy Thomas Sand ABSTRACT Electronic devices made from carbon nanotubes (CNTs) can be greatly affected by substrate charges nanotube loops for extended periods of time, showing that nanotubes can act as confining barriers

Nygård, Jesper

213

Experiment for Plasma Energization with Beating Electrostatic Waves  

E-Print Network [OSTI]

Experiment for Plasma Energization with Beating Electrostatic Waves IEPC-2009-199 Presented September 20­24, 2009 Benjamin Jorns and Edgar Y. Choueiri Electric Propulsion and Plasma Dynamics Laboratory, Princeton University, Princeton, NJ, 08540 An experimental study of plasma heating by means

Choueiri, Edgar

214

Electrostatic quadrupole focused particle accelerating assembly with laminar flow beam  

DOE Patents [OSTI]

A charged particle accelerating assembly provided with a predetermined ratio of parametric structural characteristics and with related operating voltages applied to each of its linearly spaced focusing and accelerating quadrupoles, thereby to maintain a particle beam traversing the electrostatic fields of the quadrupoles in the assembly in an essentially laminar flow through the assembly.

Maschke, A.W.

1984-04-16T23:59:59.000Z

215

Electrostatics of pyroelectric accelerators T. Z. Fullem and Y. Danona  

E-Print Network [OSTI]

Electrostatics of pyroelectric accelerators T. Z. Fullem and Y. Danona Department of Mechanical for calculating the potential and field strength in both single-crystal and two-crystal pyroelectric accelerators for better understanding of pyroelectric accelerators. © 2009 American Institute of Physics. doi:10

Danon, Yaron

216

Electrostatic Interchange Instabilities of a Rotating, High-Temperature Plasma  

E-Print Network [OSTI]

Electrostatic Interchange Instabilities of a Rotating, High-Temperature Plasma Confined by a Dipole #2 Mach Probe #1 Mach Probe #2 High-field, 0.2 MA-turn Water-cooled Magnet #12;Interchange Modes-sized/global... Fast hot electron interchange instability: drift-resonant transport; Gryokinetics; phase-space holes

Mauel, Michael E.

217

Electric Charge and Electric Field Electrostatics: Charge at rest  

E-Print Network [OSTI]

Chapter 16 Electric Charge and Electric Field #12;Electrostatics: Charge at rest Electric Charges of conservation of Electric Charge: The net amount of electric charge produced in any process is zero. Model, neutral). #12;· All protons and electrons have same magnitude of electric charge but their masses

Yu, Jaehoon

218

Stray capacitances in the watt balance operation: electrostatic forces  

E-Print Network [OSTI]

In a watt balance, stray capacitances exist between the coil and the magnet. Since the electric current flowing in the coil originates a difference between the coil and magnet electric-potentials, their electrostatic interactions must be taken into account. This paper reports the results of a finite element analysis of the forces acting on the coil.

Quagliotti, Danilo

2014-01-01T23:59:59.000Z

219

Jumping-Droplet Electrostatic Energy Harvesting  

E-Print Network [OSTI]

Micro- and nanoscale wetting phenomena has been an active area of research due to its potential for improving engineered system performance involving phase change. With the recent advancements in micro/nanofabrication ...

Miljkovic, Nenad

2014-06-19T23:59:59.000Z

220

Development of an Electrostatic Energy Analyzer (ESA) for the EQUARS Scientific Satellite  

E-Print Network [OSTI]

Development of an Electrostatic Energy Analyzer (ESA) for the EQUARS Scientific Satellite R. S of an electrostatic energy analyzer to be launched onboard the EQUARS Scientific Satellite. The instrument of scientific instrument: ESA: Electrostatic Energy Analyzer 2. Physical parameters to be measured: Electron

Note: This page contains sample records for the topic "desulfurization systems electrostatic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

oligomeric and polymeric DNA Large electrostatic differences in the binding thermodynamics of a cationic peptide to  

E-Print Network [OSTI]

oligomeric and polymeric DNA Large electrostatic differences in the binding thermodynamics electrostatic differences in the binding thermodynamics of a cationic peptide to oligomeric and polymeric DNA binding to polymeric and oligomeric DNA are not equivalent because of long-range electrostatic effects

Lohman, Timothy M.

222

Study on plasma parameters and dust charging in an electrostatically plugged multicusp plasma device  

SciTech Connect (OSTI)

The effect of the electrostatic confinement potential on the charging of dust grains and its relationship with the plasma parameters has been studied in an electrostatically plugged multicusp dusty plasma device. Electrostatic plugging is implemented by biasing the electrically isolated magnetic multicusp channel walls. The experimental results show that voltage applied to the channel walls can be a controlling parameter for dust charging.

Kakati, B.; Kausik, S. S.; Saikia, B. K. [Centre of Plasma Physics, Institute for Plasma Research, Nazirakhat, Sonapur-782 402, Kamrup, Assam (India); Bandyopadhyay, M. [ITER-India, Institute for Plasma Research, Bhat, Gandhinagar- 382 428 (India)

2011-06-15T23:59:59.000Z

223

Dynamic analysis of an electrostatic energy harvesting system  

E-Print Network [OSTI]

Traditional small-scale vibration energy harvesters have typically low efficiency of energy harvesting from low frequency vibrations. Several recent studies have indicated that introduction of nonlinearity can significantly ...

Niu, Feifei

2013-01-01T23:59:59.000Z

224

Effect of modified phosphate rock saturated by various salts on stack gas desulfurization in a fluidized bed reactor  

SciTech Connect (OSTI)

In this work, the suitability of phosphate ore treated with the varied salts such as FeSO{sub 4}, NaCl, CaCl{sub 2}, Na{sub 2}SiO{sub 3}, and Na{sub 2}SO{sub 4} as an alternative material for limestone and dolomite in flue gas desulfurization has been investigated. Also, the effect of the varied salts on calcination and sulfation of the raw, calcine, and semicalcined phosphate samples has been investigated in a differential fluidized bed reactor at 700-800{sup o}C (4 min) in air and 0.3% SO{sub 2}. It was established that the salts have prominent effects on sulfation and calcination. The changes in the pore structure and products obtained at the end of sulfation were investigated using BET surface area method. In conclusion, it was observed that the sulfation and calcination conversion ratios generally increased when the phosphate rock was treated the varied salts.

Kar, Y.; Kar, H. [Selcuk University, Konya (Turkey). Muhendislik Mimarlik Faculty

2006-04-15T23:59:59.000Z

225

Management of dry flue gas desulfurization by-products in underground mines. Topical report, April 1, 1996--April 30, 1997  

SciTech Connect (OSTI)

This report represents the Final Technical Progress Report for Phase II of the overall program for a cooperative research agreement between the U.S. Department of Energy - MORGANTOWN Energy Technology Center (DOE-METC) and Southern Illinois University at Carbondale (SIUC). Under the agreement, SIUC will develop and demonstrate technologies for the handling, transport, and placement in abandoned underground coal mines of dry flue gas desulfurization by-products, such as fly ash, scrubber sludge, fluidized bed combustion by-products, and will assess the environmental impact of such underground placement. The overall program is divided into three (3) phases. Phase II of the program is primarily concerned with developing and testing the hardware for the actual underground placement demonstrations. Two technologies have been identified and hardware procured for full-scale demonstrations: (1) hydraulic placement, where coal combustion by-products (CCBs) will be placed underground as a past-like mixture containing about 70 to 75 percent solids; and (2) pneumatic placement, where CCBs will be placed underground as a relatively dry material using compressed air. 42 refs., 36 figs., 36 tabs.

Chugh, Y.P.; Brackebusch, F.; Carpenter, J. [and others

1998-12-31T23:59:59.000Z

226

Hydrodynamics and flue gas desulfurization characteristics of a three-phase, gas-continuous, cocurrent semifluidized bed  

SciTech Connect (OSTI)

The hydrodynamic characteristics of a gas-liquid-solid, gas-continuous, cocurrent semifluidized bed were defined. Five different particle types were used to characterize the hydrodynamics. Air and water were used as the gas and liquid streams, respectively. Six flow regimes were observed in the constrained gas-continuous, three-phase bed. These regimes are described in terms of the solids properties and the gas and liquid superficial velocities. The heights of the packed and fluidized beds and the solids holdup in the fluidized section of the semifluidized bed are discussed in terms of the superficial gas and liquid velocities, the solids density and diameter and the initial quantity of particles in the bed. The desulfurization characteristics of the gas-liquid-solid semifluidized bed were determined using a calcium carbonate slurry. Gas side mass transfer coefficients and the ratio of liquid side to gas side mass transfer coefficients were measured and correlated in terms of gas flow rate, liquid flow rate, bed height, calcium carbonate concentration and sulfur dioxide pressure for both the fluidized and packed sections of the semifluidized bed. The hydrodynamic and mass transfer characteristics were used to construct a mathematical model that predicted overall removal of sulfur dioxide from the simulated flue gas.

Beaver, L.E.

1983-01-01T23:59:59.000Z

227

Characterizing toxic emissions from a coal-fired power plant demonstrating the AFGD ICCT Project and a plant utilizing a dry scrubber/baghouse system: Bailly Station Units 7 and 8 and AFGD ICCT Project. Final report. Final report  

SciTech Connect (OSTI)

This report describes results of assessment of the risk of emissions of hazardous air pollutants at one of the electric power stations, Bailly Station, which is also the site of a Clean Coal Technology project demonstrating the Pure Air Advanced Flue Gas Desulfurization process (wet limestone). This station represents the configuration of no NO{sub x} reduction, particulate control with electrostatic precipitators, and SO{sub 2} control with a wet scrubber. The test was conducted September 3--6, 1993. Sixteen trace metals were determined along with 5 major metals. Other inorganic substances and organic compounds were also determined.

Dismukes, E.B.

1994-10-20T23:59:59.000Z

228

Electrostatic apparatus for measurement of microfracture strength  

DOE Patents [OSTI]

A new class of materials testing apparatus has been invented. Particularly suited to the measurement of fracture and fatigue properties in the extremely strong materials encountered in microelectromechanical systems, material strains well in excess of 1% can be applied pseudostatically, dynamically, or repetitively by these testers. There are no other practical methods to determine these material properties routinely in a process environment, and few alternatives in any circumstances.

de Boer, Maarten (Albuquerque, NM); Bitsie, Fernando (Albuquerque, NM); Jensen, Brian D. (Ann Arbor, MI)

2002-01-01T23:59:59.000Z

229

Microturbulence in DIII-D tokamak pedestal. I. Electrostatic instabilities  

SciTech Connect (OSTI)

Gyrokinetic simulations of electrostatic driftwave instabilities in a tokamak edge have been carried out to study the turbulent transport in the pedestal of an H-mode plasma. The simulations use annulus geometry and focus on two radial regions of a DIII-D experiment: the pedestal top with a mild pressure gradient and the middle of the pedestal with a steep pressure gradient. A reactive trapped electron instability with a typical ballooning mode structure is excited by trapped electrons in the pedestal top. In the middle of the pedestal, the electrostatic instability exhibits an unusual mode structure, which peaks at the poloidal angle ?=±?/2. The simulations find that this unusual mode structure is due to the steep pressure gradients in the pedestal but not due to the particular DIII-D magnetic geometry. Realistic DIII-D geometry appears to have a stabilizing effect on the instability when compared to a simple circular tokamak geometry.

Fulton, D. P.; Holod, I. [Department of Physics and Astronomy, University of California, Irvine, California 92697 (United States)] [Department of Physics and Astronomy, University of California, Irvine, California 92697 (United States); Lin, Z., E-mail: zhihongl@uci.edu [Department of Physics and Astronomy, University of California, Irvine, California 92697 (United States); Fusion Simulation Center, Peking University, Beijing 100871 (China); Xiao, Y. [Institute of Fusion Theory and Simulation, Zhejiang University, Hangzhou 310027 (China)] [Institute of Fusion Theory and Simulation, Zhejiang University, Hangzhou 310027 (China)

2014-04-15T23:59:59.000Z

230

Electrostatic dispersion lenses and ion beam dispersion methods  

DOE Patents [OSTI]

An EDL includes a case surface and at least one electrode surface. The EDL is configured to receive through the EDL a plurality of ion beams, to generate an electrostatic field between the one electrode surface and either the case surface or another electrode surface, and to increase the separation between the beams using the field. Other than an optional mid-plane intended to contain trajectories of the beams, the electrode surface or surfaces do not exhibit a plane of symmetry through which any beam received through the EDL must pass. In addition or in the alternative, the one electrode surface and either the case surface or the other electrode surface have geometries configured to shape the field to exhibit a less abrupt entrance and/or exit field transition in comparison to another electrostatic field shaped by two nested, one-quarter section, right cylindrical electrode surfaces with a constant gap width.

Dahl, David A. (Idaho Falls, ID) [Idaho Falls, ID; Appelhans, Anthony D. (Idaho Falls, ID) [Idaho Falls, ID

2010-12-28T23:59:59.000Z

231

Ion-beam-driven electrostatic ion cyclotron instabilities  

SciTech Connect (OSTI)

We present results of numerical simulations on the electrostatic ion cyclotron instabilities driven by the ion beam parallel to the magnetic field. For the beam speed exceeding the thermal speed of background ions and the beam temperature much lower than the background ion temperature, it is found that the instability results in strong perpendicular heating and slowing down of parallel drift of the beam ions, leading to the saturation of the instability. Applications to plasma heating and space plasma physics are discussed.

Miura, A.; Okuda, H.; Ashour-Abdalla, M.

1982-10-01T23:59:59.000Z

232

Ion pump activity generates fluctuating electrostatic forces in biomembranes  

E-Print Network [OSTI]

We study the non-equilibrium dynamics of lipid membranes with proteins that actively pump ions across the membrane. We find that the activity leads to a fluctuating force distribution due to electrostatic interactions arising from variation in dielectric constant across the membrane. By applying a multipole expansion we find effects on both the tension and bending rigidity dominated parts of the membranes fluctuation spectrum. We discuss how our model compares with previous studies of force-multipole models.

B. Loubet; M. A. Lomholt

2011-09-19T23:59:59.000Z

233

Deionization and desalination using electrostatic ion pumping  

DOE Patents [OSTI]

The present invention provides a new method and apparatus/system for purifying ionic solutions, such as, for example, desalinating water, using engineered charged surfaces to sorb ions from such solutions. Surface charge is applied externally, and is synchronized with oscillatory fluid movements between substantially parallel charged plates. Ions are held in place during fluid movement in one direction (because they are held in the electrical double layer), and released for transport during fluid movement in the opposite direction by removing the applied electric field. In this way the ions, such as salt, are "ratcheted" across the charged surface from the feed side to the concentrate side. The process itself is very simple and involves only pumps, charged surfaces, and manifolds for fluid collection.

Bourcier, William L. (Livermore, CA); Aines, Roger D. (Livermore, CA); Haslam, Jeffery J. (Livermore, CA); Schaldach, Charlene M. (Pleasanton, CA); O'Brien, Kevin C. (San Ramon, CA); Cussler, Edward (Edina, MN)

2011-07-19T23:59:59.000Z

234

Deionization and desalination using electrostatic ion pumping  

DOE Patents [OSTI]

The present invention provides a new method and apparatus/system for purifying ionic solutions, such as, for example, desalinating water, using engineered charged surfaces to sorb ions from such solutions. Surface charge is applied externally, and is synchronized with oscillatory fluid movements between substantially parallel charged plates. Ions are held in place during fluid movement in one direction (because they are held in the electrical double layer), and released for transport during fluid movement in the opposite direction by removing the applied electric field. In this way the ions, such as salt, are "ratcheted" across the charged surface from the feed side to the concentrate side. The process itself is very simple and involves only pumps, charged surfaces, and manifolds for fluid collection.

Bourcier, William L.; Aines, Roger D.; Haslam, Jeffery J.; Schaldach, Charlene M.; O'Brien, Kevin C.; Cussler, Edward

2013-06-11T23:59:59.000Z

235

Electrostatic waves in carbon nanotubes with an axial magnetic field  

SciTech Connect (OSTI)

Based on a linearized hydrodynamic model and within the quasi-static approximation, the dispersion relation of electrostatic waves propagating through single-walled carbon nanotubes subject to an axial magnetic field is theoretically explored. In the classical limit, we obtain two main possible waves which in turn are divided into two branches, a low-frequency acoustical and a high-frequency optical plasmon branch. In the quantum case, we have found that the dispersion relation is substantially modified when the electron wavelength becomes large enough compared to the propagation wavelength of the electrostatic waves in the quantum plasma. We also show that the axial magnetic field manifest itself on the perturbed electron density through the quantum term and gives rise to the propagation of the electrostatic waves within the quantum plasma. As a result, the effect of the magnetic field is pronounced in the plasma dispersion relations in such a way that their curves approach to zero when the magnetic field is weak; and for the strong magnetic field, they asymptotically meet the constant lines.

Abdikian, Alireza [Department of Physics, Malayer University, Malayer 65719-95863 (Iran, Islamic Republic of)] [Department of Physics, Malayer University, Malayer 65719-95863 (Iran, Islamic Republic of); Bagheri, Mehran [Laser and Plasma Research Institute, Shahid Beheshti University, G. C., Evin, Tehran 19835-63113 (Iran, Islamic Republic of)] [Laser and Plasma Research Institute, Shahid Beheshti University, G. C., Evin, Tehran 19835-63113 (Iran, Islamic Republic of)

2013-10-15T23:59:59.000Z

236

Utility FGD survey: January--December 1989. Volume 1, Categorical summaries of FGD systems  

SciTech Connect (OSTI)

This is Volume 1 of the Utility flue gas desulfurization (FGD) Survey report, which is generated by a computerized data base management system, represents a survey of operational and planned domestic utility flue gas desulfurization (FGD) systems. It summarizes information contributed by the utility industry, system and equipment suppliers, system designers, research organizations, and regulatory agencies. The data cover system design, fuel characteristics, operating history, and actual system performance. Also included is a unit-by-unit discussion of problems and solutions associated with the boilers, scrubbers, and FGD systems. The development status (operational, under construction, or in the planning stages), system supplier, process, waste disposal practice, and regulatory class are tabulated alphabetically by utility company.

Hance, S.L.; McKibben, R.S.; Jones, F.M.

1992-03-01T23:59:59.000Z

237

E-Print Network 3.0 - anion-exchange resin-based desulfurization...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

with SOFC Power System Recycle Pump 150C HX Recuperator Heat Rejection Purge SOFC POWER MODULE... Water Recovery Exhaust SOFC Stack Anode Adiabatic Reformer...

238

MULTI-POLLUTANT CONTROL USING MEMBRANE--BASED UP-FLOW WET ELECTROSTATIC PRECIPITATION  

SciTech Connect (OSTI)

This is the Final Report of the ''Multi-Pollutant Control Using Membrane-Based Up-flow Wet Electrostatic Precipitation'' project funded by the US Department of Energy's National Energy Technology Laboratory under DOE Award No. DE-FC26-02NT41592 to Croll-Reynolds Clean Air Technologies (CRCAT). In this 18 month project, CRCAT and its team members conducted detailed emission tests of metallic and new membrane collection material within a wet electrostatic precipitator (WESP) at First Energy's Penn Power's Bruce Mansfield (BMP) plant in Shippingport, Pa. The Membrane WESP was designed to be as similar as the metallic WESP in terms of collection area, air-flow, and electrical characteristics. Both units are two-field units. The membrane unit was installed during the 2nd and 3rd quarters of 2003. Testing of the metallic unit was performed to create a baseline since the Mansfield plant had installed selective catalytic reduction equipment for NOx control and a sodium bisulfate injection system for SO3 control during the spring of 2003. Tests results on the metallic WESP were consistent with previous testing for PM2.5, SO3 mist and mercury. Testing on the membrane WESP demonstrated no adverse impact and equivalent removal efficiencies as that of the metallic WESP. Testing on both units was performed at 8,000 acfm and 15,000 acfm. Summary results are shown.

James Reynolds

2004-10-29T23:59:59.000Z

239

Synthesizing aluminum particles towards controlling electrostatic discharge ignition sensitivity  

SciTech Connect (OSTI)

Aluminum particles were synthesized with shell thicknesses ranging from 2.7 to 8.3 nm and a constant diameter of 95 nm. These fuel particles were combined with molybdenum trioxide particles and the electrostatic discharge (ESD) sensitivity of the mixture was measured. Results show ignition delay increased as the alumina shell thickness increased. These results correlated with electrical resistivity measurements of the mixture which increased with alumina concentration. A model was developed using COMSOL for ignition of a single Al particle. The ignition delay in the model was consistent with the experimental results suggesting that the primary ESD ignition mechanism is joule heating.

Eric S. Collins; Jeffery P. Gesner; Michelle L. Pantoya; Michael A. Daniels

2014-02-01T23:59:59.000Z

240

Electrostatic Discharge Sensitivity and Electrical Conductivity of Composite Energetic Materials  

SciTech Connect (OSTI)

Composite energetic material response to electrical stimuli was investigated and a correlation between electrical conductivity and ignition sensitivity was examined. The composites consisted of micrometer particle aluminum combined with another metal, metal oxide, or fluoropolymer. Of the nine tested mixtures, aluminum with copper oxide was the only mixture to ignite by electrostatic discharge with minimum ignition energy (MIE) of 25 mJ and an electrical conductivity of 1246.25 nS; two orders of magnitude higher than the next composite. This study showed a similar trend in MIE for ignition triggered by a discharged spark compared with a thermal hot wire source.

Michael A. Daniels; Daniel J. Prentice; Chelsea Weir; Michelle L. Pantoya; Gautham Ramachandran; Tim Dallas

2013-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "desulfurization systems electrostatic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

E-Print Network 3.0 - analysis electrostatic accelerator Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

; Biology and Medicine 2 Fly-Casting in Protein-DNA Binding: Frustration between Protein Folding and Electrostatics Facilitates Target Recognition Summary: Fly-Casting in...

242

Electrostatic self-energy in static black holes with spherical symmetry  

E-Print Network [OSTI]

We determine the expression of the electrostatic self-energy for a point charge in the static black holes with spherical symmetry having suitable properties

B. Linet

2000-06-28T23:59:59.000Z

243

Attractive electrostatic self-assembly of ordered and disordered heterogeneous colloids  

E-Print Network [OSTI]

Ionic colloidal crystals are here defined as multicomponent ordered colloidal structures stabilized by attractive electrostatic interactions. These crystals are colloidal analogues to ionic materials including zincblende, ...

Maskaly, Garry R. (Garry Russell), 1978-

2005-01-01T23:59:59.000Z

244

Performance history over 10 years of super duplex stainless steel in flue gas desulfurization  

SciTech Connect (OSTI)

25 Cr duplex (austenitic/ferritic) stainless steel containing copper and nitrogen offers a cost effective solution to material selection for pollution control equipment. The properties of duplex stainless steel which make it suitable for this type of application are discussed and long term performance histories presented. It is concluded that high alloy duplex steel has an important role to play in the production of low maintenance reliable equipment for FGD and other pollution control systems.

Bendall, K.C. [Langley Alloys Ltd., Maidenhead (United Kingdom)

1996-08-01T23:59:59.000Z

245

Spherical plasma oscillations in a reversed-polarity inertial-electrostatic confinement device  

SciTech Connect (OSTI)

A pulsed reversed-polarity inertial-electrostatic confinement device has been investigated experimentally using voltage and spectroscopic diagnostics. Large-amplitude oscillations were observed in the floating potential of the plasma immediately following the initiation of the discharge. It is postulated that the observations were the result of coherent ion oscillations within a harmonic potential well formed by a uniform electron density in the center of the device. A simple model of the system predicts the depth of this transient potential well to be approximately 100 V. Observations of the relative occupation of the third and fourth energy levels of hydrogen in the plasma indicated the formation of a Maxwellian electron energy distribution after 20 {mu}s. The results suggest a promising avenue toward a net fusion power gain by utilizing these oscillations to periodically compress and heat the plasma to thermonuclear densities and energies.

Tuft, C.; Khachan, J. [Plasma Physics, School of Physics, University of Sydney, New South Wales 2006 (Australia)

2010-11-15T23:59:59.000Z

246

A unified electrostatic and cavitation model for first-principles molecular dynamics in solution  

E-Print Network [OSTI]

The electrostatic continuum solvent model developed by Fattebert and Gygi is combined with a first-principles formulation of the cavitation energy based on a natural quantum-mechanical definition for the surface of a solute. Despite its simplicity, the cavitation contribution calculated by this approach is found to be in remarkable agreement with that obtained by more complex algorithms relying on a large set of parameters. Our model allows for very efficient Car-Parrinello simulations of finite or extended systems in solution, and demonstrates a level of accuracy as good as that of established quantum-chemistry continuum solvent methods. We apply this approach to the study of tetracyanoethylene dimers in dichloromethane, providing valuable structural and dynamical insights on the dimerization phenomenon.

Damian A. Scherlis; Jean-Luc Fattebert; Francois Gygi; Matteo Cococcioni; Nicola Marzari

2005-10-06T23:59:59.000Z

247

FIELD TEST PROGRAM TO DEVELOP COMPREHENSIVE DESIGN, OPERATING AND COST DATA FOR MERCURY CONTROL SYSTEMS ON NON-SCRUBBED COAL-FIRED BOILERS  

SciTech Connect (OSTI)

With the Nation's coal-burning utilities facing the possibility of tighter controls on mercury pollutants, the U.S. Department of Energy is funding projects that could offer power plant operators better ways to reduce these emissions at much lower costs. Mercury is known to have toxic effects on the nervous system of humans and wildlife. Although it exists only in trace amounts in coal, mercury is released when coal burns and can accumulate on land and in water. In water, bacteria transform the metal into methylmercury, the most hazardous form of the metal. Methylmercury can collect in fish and marine mammals in concentrations hundreds of thousands times higher than the levels in surrounding waters. One of the goals of DOE is to develop technologies by 2005 that will be capable of cutting mercury emissions 50 to 70 percent at well under one-half of today's costs. ADA Environmental Solutions (ADA-ES) is managing a project to test mercury control technologies at full scale at four different power plants from 2000-2003. The ADA-ES project is focused on those power plants that are not equipped with wet flue gas desulfurization systems. ADA-ES will develop a portable system that will be moved to four different utility power plants for field testing. Each of the plants is equipped with either electrostatic precipitators or fabric filters to remove solid particles from the plant's flue gas. ADA-ES's technology will inject a dry sorbent, such as fly ash or activated carbon, that removes the mercury and makes it more susceptible to capture by the particulate control devices. A fine water mist may be sprayed into the flue gas to cool its temperature to the range where the dry sorbent is most effective. PG&E National Energy Group is providing two test sites that fire bituminous coals and both are equipped with electrostatic precipitators and carbon/ash separation systems. Wisconsin Electric Power Company is providing a third test site that burns Powder River Basin (PRB) coal and has an electrostatic precipitator for particulate control. Alabama Power Company will host a fourth test at its Plant Gaston, which is equipped with a hot-side electrostatic precipitator and a downstream fabric filter. During the seventh reporting quarter, progress was made on the project in the following areas: (1) PG&E NEG Brayton Point Station--Sorbent injection equipment was installed at the site during the quarter; Test plans were prepared for the field testing phase of the project; Baseline testing was completed during the quarter and parametric testing was begun; and A paper summarizing the full-scale tests was written and submitted to A&WMA for presentation at the annual meeting in June 2002. (2) Technology Transfer--A number of technical presentations and briefings were made during the quarter. Notable among them are papers published in the A&WMA EM journal and Pollution Engineering. Also, information was provided to the EPA MACT Working Group and a paper was presented at the annual A&WMA meeting.

Richard Schlager

2002-08-01T23:59:59.000Z

248

FIELD TEST PROGRAM TO DEVELOP COMPREHENSIVE DESIGN, OPERATING AND COST DATA FOR MERCURY CONTROL SYSTEMS ON NON-SCRUBBED COAL-FIRED BOILERS  

SciTech Connect (OSTI)

With the Nation's coal-burning utilities facing the possibility of tighter controls on mercury pollutants, the U.S. Department of Energy is funding projects that could offer power plant operators better ways to reduce these emissions at much lower costs. Mercury is known to have toxic effects on the nervous system of humans and wildlife. Although it exists only in trace amounts in coal, mercury is released when coal burns and can accumulate on land and in water. In water, bacteria transform the metal into methylmercury, the most hazardous form of the metal. Methylmercury can collect in fish and marine mammals in concentrations hundreds of thousands times higher than the levels in surrounding waters. One of the goals of DOE is to develop technologies by 2005 that will be capable of cutting mercury emissions 50 to 70 percent at well under one-half of today's costs. ADA Environmental Solutions (ADA-ES) is managing a project to test mercury control technologies at full scale at four different power plants from 2000-2003. The ADA-ES project is focused on those power plants that are not equipped with wet flue gas desulfurization systems. ADA-ES has developed a portable system that will be tested at four different utility power plants. Each of the plants is equipped with either electrostatic precipitators or fabric filters to remove solid particles from the plant's flue gas. ADA-ES's technology will inject a dry sorbent, such as activated carbon, which removes the mercury and makes it more susceptible to capture by the particulate control devices. A fine water mist may be sprayed into the flue gas to cool its temperature to the range where the dry sorbent is most effective. PG&E National Energy Group is providing two test sites that fire bituminous coals and both are equipped with electrostatic precipitators and carbon/ash separation systems. Wisconsin Electric Power Company is providing a third test site that burns Powder River Basin (PRB) coal and has an electrostatic precipitator for particulate control. Alabama Power Company will host a fourth test at its Plant Gaston, which is equipped with a hot-side electrostatic precipitator and a downstream fabric filter. During the eighth reporting quarter, progress was made on the project in the following areas: (1) PG&E NEG Salem Harbor Station--Sorbent injection equipment was installed at the site during the quarter; Test plans were prepared for the field-testing phase of the project; and Baseline testing was completed during the quarter. (2) Technology Transfer--A number of technical presentations and briefings were made during the quarter. Notable among them was a paper published in the JAWMA. Also, two papers were presented at the Air Quality III Conference and one at the Pittsburgh Coal Conference.

Richard Schlager; Tom Millar

2002-10-18T23:59:59.000Z

249

FIELD TEST PROGRAM TO DEVELOP COMPREHENSIVE DESIGN, OPERATING AND COST DATA FOR MERCURY CONTROL SYSTEMS ON NON-SCRUBBED COAL-FIRED BOILERS  

SciTech Connect (OSTI)

With the Nation's coal-burning utilities facing the possibility of tighter controls on mercury pollutants, the U.S. Department of Energy is funding projects that could offer power plant operators better ways to reduce these emissions at much lower costs. Mercury is known to have toxic effects on the nervous system of humans and wildlife. Although it exists only in trace amounts in coal, mercury is released when coal burns and can accumulate on land and in water. In water, bacteria transform the metal into methylmercury, the most hazardous form of the metal. Methylmercury can collect in fish and marine mammals in concentrations hundreds of thousands times higher than the levels in surrounding waters. One of the goals of DOE is to develop technologies by 2005 that will be capable of cutting mercury emissions 50 to 70 percent at well under one-half of today's costs. ADA Environmental Solutions (ADA-ES) is managing a project to test mercury control technologies at full scale at four different power plants from 2000-2003. The ADA-ES project is focused on those power plants that are not equipped with wet flue gas desulfurization systems. ADA-ES has developed a portable system that will be tested at four different utility power plants. Each of the plants is equipped with either electrostatic precipitators or fabric filters to remove solid particles from the plant's flue gas. ADA-ES's technology will inject a dry sorbent, such as activated carbon, which removes the mercury and makes it more susceptible to capture by the particulate control devices. A fine water mist may be sprayed into the flue gas to cool its temperature to the range where the dry sorbent is most effective. PG&E National Energy Group is providing two test sites that fire bituminous coals and both are equipped with electrostatic precipitators and carbon/ash separation systems. Wisconsin Electric Power Company is providing a third test site that burns Powder River Basin (PRB) coal and has an electrostatic precipitator for particulate control. Alabama Power Company will host a fourth test at its Plant Gaston, which is equipped with a hot-side electrostatic precipitator and a downstream fabric filter. During the ninth reporting quarter, progress was made on the project in the following areas: PG&E NEG Salem Harbor Station -- Long term testing and equipment decommissioning has been completed, A web cast/conference call was held to review data, and Preliminary preparation and review of data and test results for the final report. Technology Transfer -- A number of technical presentations and briefings were made during the quarter. Notable among them was a Program Status Report presented to NETL. Also, one paper was presented at Power-Gen and one at the Annual Coal Marketing Strategies Conference.

Richard Schlager; Tom Millar

2003-01-27T23:59:59.000Z

250

Electrostatics-driven shape transitions in soft shells  

E-Print Network [OSTI]

Manipulating the shape of nanoscale objects in a controllable fashion is at the heart of designing materials that act as building blocks for self-assembly or serve as targeted drug delivery carriers. Inducing shape deformations by controlling external parameters is also an important way of designing biomimetic membranes. In this paper, we demonstrate that electrostatics can be used as a tool to manipulate the shape of soft, closed membranes by tuning environmental conditions such as the electrolyte concentration in the medium. Using a molecular dynamics-based simulated annealing procedure, we investigate charged elastic shells that do not exchange material with their environment, such as elastic membranes formed in emulsions or synthetic nanocontainers. We find that by decreasing the salt concentration or increasing the total charge on the shell's surface, the spherical symmetry is broken, leading to the formation of ellipsoids, discs, and bowls. Shape changes are accompanied by a significant lowering of the electrostatic energy and a rise in the surface area of the shell. To substantiate our simulation findings, we show analytically that a uniformly charged disc has a lower Coulomb energy than a sphere of the same volume. Further, we test the robustness of our results by including the effects of charge renormalization in the analysis of the shape transitions and find the latter to be feasible for a wide range of shell volume fractions.

Vikram Jadhao; Creighton K. Thomas; Monica Olvera de la Cruz

2014-09-12T23:59:59.000Z

251

Electrostatic spherically symmetric configurations in gravitating nonlinear electrodynamics  

SciTech Connect (OSTI)

We perform a study of the gravitating electrostatic spherically symmetric (G-ESS) solutions of Einstein field equations minimally coupled to generalized nonlinear Abelian gauge models in three space dimensions. These models are defined by Lagrangian densities which are general functions of the gauge field invariants, restricted by some physical conditions of admissibility. They include the class of nonlinear electrodynamics supporting electrostatic spherically symmetric (ESS) nontopological soliton solutions in absence of gravity. We establish that the qualitative structure of the G-ESS solutions of admissible models is fully characterized by the asymptotic and central-field behaviors of their ESS solutions in flat space (or, equivalently, by the behavior of the Lagrangian densities in vacuum and on the point of the boundary of their domain of definition, where the second gauge invariant vanishes). The structure of these G-ESS configurations for admissible models supporting divergent-energy ESS solutions in flat space is qualitatively the same as in the Reissner-Nordstroem case. In contrast, the G-ESS configurations of the models supporting finite-energy ESS solutions in flat space exhibit new qualitative features, which are discussed in terms of the Arnowitt-Deser-Misner mass, the charge, and the soliton energy. Most of the results concerning well-known models, such as the electrodynamics of Maxwell, Born-Infeld, and the Euler-Heisenberg effective Lagrangian of QED, minimally coupled to gravitation, are shown to be corollaries of general statements of this analysis.

Diaz-Alonso, J.; Rubiera-Garcia, D. [LUTH, Observatoire de Paris, CNRS, , USAUniversite Paris Diderot, 5 Place Jules Janssen, 92190 Meudon (France) and Departamento de Fisica, Universidad de Oviedo, Avda. Calvo Sotelo 18, E-33007 Oviedo, Asturias (Spain)

2010-03-15T23:59:59.000Z

252

Electrostatic rogue-waves in relativistically degenerate plasmas  

SciTech Connect (OSTI)

In this paper, we investigate the modulational instability and the possibility of electrostatic rogue-wave propagations in a completely degenerate plasma with arbitrary degree of degeneracy, i.e., relativistically degenerate plasma, ranging from solid density to the astrophysical compact stars. The hydrodynamic approach along with the perturbation method is used to reduce the governing equations to the nonlinear Schrödinger equation from which the modulational instability, the growth rate of envelope excitations and the occurrence of rogue as well as super-rogue waves in the plasma, is evaluated. It is observed that the modulational instability in a fully degenerate plasma can be quite sensitive to the plasma number-density and the wavenumber of envelop excitations. It is further revealed that the relativistically degeneracy plasmas (R{sub 0}?>?1) are almost always modulationally unstable. It is found, however, that the highly energetic sharply localized electrostatic rogue as well as super-rogue waves can exist in the astrophysical compact objects like white dwarfs and neutron star crusts. The later may provide a link to understand many physical processes in such stars and it may lead us to the origin of the random-localized intense short gamma-ray bursts, which “appear from nowhere and disappear without a trace” quite similar to oceanic rogue structures.

Akbari-Moghanjoughi, M. [Department of Physics, Faculty of Sciences, Azarbaijan Shahid Madani University, 51745-406 Tabriz, Iran and International Centre for Advanced Studies in Physical Sciences and Institute for Theoretical Physics, Ruhr University Bochum, D-44780 Bochum (Germany)

2014-10-15T23:59:59.000Z

253

Novel Au-TiC Catalysts for CO Oxidation and Desulfurization Processes  

SciTech Connect (OSTI)

Recent articles dealing with the physical and chemical properties of novel Au-TiC catalysts are reviewed. High-resolution photoemission, scanning tunneling microscopy and first-principles periodic density-functional calculations were used to study the deposition of gold on a TiC(0 0 1) surface. Gold grows forming two-dimensional (very low coverage) and three-dimensional (medium and large coverage) islands on the carbide substrate. A positive shift in the binding energy of the C 1s core level is observed after the deposition of Au on TiC(0 0 1). The results of the density-functional calculations corroborate the formation of Au-C bonds. In general, the bond between Au and the TiC(0 0 1) surface exhibits very little ionic character, but there is a substantial polarization of electrons around Au that facilitates bonding of the adatoms with electron-acceptor molecules (CO, O{sub 2}, C{sub 2}H{sub 4}, SO{sub 2}, thiophene, etc.). Experimental measurements indicate that Au/TiC(0 0 1) is a very good catalysts for the oxidation of CO, the destruction of SO{sub 2} and the hydrodesulfurization of thiophene. At temperatures below 200 K, Au/TiC(0 0 1) is able to perform the 2CO + O{sub 2} {yields} 2CO{sub 2} reaction and the full decomposition of SO{sub 2}. Furthermore, in spite of the very poor hydrodesulfurization performance of TiC(0 0 1) or Au(1 1 1), a Au/TiC(0 0 1) surface displays a hydrodesulfurization activity higher than that of conventional Ni/MoS{sub x} catalysts. Metal carbides are excellent supports for enhancing the chemical reactivity of gold. The Au/TiC system is more chemically active than systems generated by depositing Au nanoparticles on oxide surfaces.

J Rodriguez; P Liu; Y Takahashi; F Vines; L Feria; E Florez; K Nakamura

2011-12-31T23:59:59.000Z

254

Electrostatically focused addressable field emission array chips (AFEA's) for high-speed massively parallel maskless digital E-beam direct write lithography and scanning electron microscopy  

DOE Patents [OSTI]

Systems and methods are described for addressable field emission array (AFEA) chips. A method of operating an addressable field-emission array, includes: generating a plurality of electron beams from a pluralitly of emitters that compose the addressable field-emission array; and focusing at least one of the plurality of electron beams with an on-chip electrostatic focusing stack. The systems and methods provide advantages including the avoidance of space-charge blow-up.

Thomas, Clarence E. (Knoxville, TN); Baylor, Larry R. (Farragut, TN); Voelkl, Edgar (Oak Ridge, TN); Simpson, Michael L. (Knoxville, TN); Paulus, Michael J. (Knoxville, TN); Lowndes, Douglas H. (Knoxville, TN); Whealton, John H. (Oak Ridge, TN); Whitson, John C. (Clinton, TN); Wilgen, John B. (Oak Ridge, TN)

2002-12-24T23:59:59.000Z

255

Design of an Experiment to Optimize Plasma Energization by Beating Electrostatic Waves  

E-Print Network [OSTI]

Design of an Experiment to Optimize Plasma Energization by Beating Electrostatic Waves B. Jorns and E.Y. Choueiri Electric Propulsion and Plasma Dynamics Laboratory, Princeton University, Princeton and amplitude dependence of the heating of a magnetized plasma with beating electrostatic waves is discussed

Choueiri, Edgar

256

Electrostatics in a Schwarzschild black hole pierced by a cosmic string  

E-Print Network [OSTI]

We explicitly determine the expression of the electrostatic potential generated by a point charge at rest in the Schwarzschild black hole pierced by a cosmic string. We can then calculate the electrostatic self-energy. From this, we find again the upper entropy bound for a charged object by employing thermodynamics of the black hole.

B. Linet

1999-04-19T23:59:59.000Z

257

Coal desulfurization in a rotary kiln combustor. Final report, March 15, 1990--July 31, 1991  

SciTech Connect (OSTI)

The purpose of this project was to demonstrate the combustion of coal and coal wastes in a rotary kiln reactor with limestone addition for sulfur control. The rationale for the project was the perception that rotary systems could bring several advantages to combustion of these fuels, and may thus offer an alternative to fluid-bed boilers. Towards this end, an existing wood pyrolysis kiln (the Humphrey Charcoal kiln) was to be suitably refurbished and retrofitted with a specially designed version of a patented air distributor provided by Universal Energy, Inc. (UEI). As the project progressed beyond the initial stages, a number of issues were raised regarding the feasibility and the possible advantages of burning coals in a rotary kiln combustor and, in particular, the suitability of the Humphrey Charcoal kiln as a combustor. Instead, an opportunity arose to conduct combustion tests in the PEDCO Rotary Cascading-Bed Boiler (RCBB) commercial demonstration unit at the North American Rayon CO. (NARCO) in Elizabethton, TN. The tests focused on anthracite culm and had two objectives: (a) determine the feasibility of burning anthracite culms in a rotary kiln boiler and (b) obtain input for any further work involving the Humphrey Charcoal kiln combustor. A number of tests were conducted at the PEDCO unit. The last one was conducted on anthracite culm procured directly from the feed bin of a commercial circulating fluid-bed boiler. The results were disappointing; it was difficult to maintain sustained combustion even when large quantities of supplemental fuel were used. Combustion efficiency was poor, around 60 percent. The results suggest that the rotary kiln boiler, as designed, is ill-suited with respect to low-grade, hard to burn solid fuels, such as anthracite culm. Indeed, data from combustion of bituminous coal in the PEDCO unit suggest that with respect to coal in general, the rotary kiln boiler appears inferior to the circulating fluid bed boiler.

Cobb, J.T. Jr.

1992-09-11T23:59:59.000Z

258

Confined zone dispersion flue gas desulfurization demonstration. Quarterly report No. 7, May 1, 1992--August 16, 1992  

SciTech Connect (OSTI)

The CZD process involves injecting a finely atomized slurry of reactive lime into the flue gas duct work of a coal-fired utility boiler. The principle of the confined zone is to form a wet zone of slurry droplets in the middle of the duct confined in an envelope of hot gas between the wet zone and the duct walls. The lime slurry reacts with part of the SO{sub 2} in the gas, and the reaction products dry to form solid particles. A solids collector, typically an electrostatic precipitator (ESP) downstream from the point of injection, captures the reaction products along with the fly ash entrained in the flue gas. The features that distinguish the CZD process from other similar injection processes are: (1) Injection of an alkaline slurry directly into the duct, instead of injection of dry solids into the duct ahead of a fabric filter. (2) Use of an ultrafine calcium/magnesium hydroxide, type S pressure-hydrated dolomitic lime. This commercial product is made from plentiful, naturally occurring dolomite. (3) Low residence time, made possible by the high effective surface area of the Type S lime. (4) Localized dispersion of the reagent. (5) Improved electrostatic precipitator performance via gas conditioning from the increased water vapor content, and lower temperatures. The waste product is composed of magnesium and calcium sulfite and sulfate, with some excess lime. This product mixed with fly ash is self-stabilizing because of the excess lime values, and thus tends to retain heavy metals in insoluble forms within the fly ash.

Not Available

1993-02-01T23:59:59.000Z

259

Local and long-range electrostatic interactions in denatured Ribonuclease Sa: comparing the denatured protein with model peptides  

E-Print Network [OSTI]

H dependence of protein stability have highlighted substantial electrostatic structure in the denatured states of many proteins. To increase understanding of such electrostatic structure, unstructured pentapeptides have been used as models of the ionization...

Daily, Michael Douglas

2013-02-22T23:59:59.000Z

260

Wet electrostatic precipitator eliminates over 90% of previous emissions  

SciTech Connect (OSTI)

After ten years of searching for an effective air pollution control device, engineers at Teledyne Wah Chang Albany (TWCA) found that zirconium was the best metal in withstanding the gases generated in the manufacturing process of zirconium and hafnium. The best equipment was a two-stage, modular wet electrostatic precipitator to collect the submicron-size particulates in the form of metal oxides, ammonium sulfate, ammonium sulfite and ammonium bisulfite. All nonmetal components of the precipitator were fabricated entirely from industrial grade reinforced thermoset plastics. All metal components, including process water spray components, pipe fittings, and emitting electrodes - to be charged at 45,000 V - were fabricated from zirconium. Stack emission tests indicate the precipitator has eliminated over 90% of previous particulate emissions. Operation has been virtually maintenance free. The zirconium components show no signs of corrosion to date. (DP)

Not Available

1983-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "desulfurization systems electrostatic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Flue gas desulfurization  

DOE Patents [OSTI]

A process and apparatus for removing sulfur oxide from combustion gas to form Na.sub.2 SO.sub.4 and for reducing the harmful effects of Na.sub.2 SO.sub.4 on auxiliary heat exchangers in which a sodium compound is injected into the hot combustion gas forming liquid Na.sub.2 SO.sub.4 in a gas-gas reaction and the resultant gas containing Na.sub.2 SO.sub.4 is cooled to below about 1150.degree. K. to form particles of Na.sub.2 SO.sub.4 prior to contact with at least one heat exchanger with the cooling being provided by the recycling of combustion gas from a cooled zone downstream from the introduction of the cooling gas.

Im, Kwan H. (Lisle, IL); Ahluwalia, Rajesh K. (Clarendon Hills, IL)

1985-01-01T23:59:59.000Z

262

Hydrocarbon desulfurization process  

SciTech Connect (OSTI)

A process is described for converting a sour hydrocarbon feedstock having a relatively high sulfur content to a hydrocarbon product having a relatively low sulfur content comprising the steps of: (a) hydrodesulfurizing the feedstock having a relatively high sulfur contact with hydrogen to produce the hydrocarbon product having a relatively low sulfur content and hydrogen sulfide gas; (b) contacting the hydrogen sulfide gas with an anthraquinone dissolved in a polar organic solvent having a polarity greater than about 3 Debye units to produce sulfur and an anthrahydroquinone in the solvent; (c) regenerating the anthraquinone from the anthrahydroquinone upon contact with air to produce the anthraquinone and hydrogen peroxide; (d) recycling the anthraquinone to step (b); (e) reducing the hydrogen peroxide to oxygen and water; (f) partially oxidizing a hydrocarbon fuel with the oxygen to produce carbon dioxide and hydrogen; and (g) recycling the hydrogen to step (a).

Plummer, M.A.; Zimmerman, C.C. Jr.

1986-04-08T23:59:59.000Z

263

Desulfurization sorbent regeneration  

DOE Patents [OSTI]

A spent solid sorbent resulting from the removal of hydrogen sulfide from a fuel gas flow is regenerated with a steam-air mixture. The mixture of steam and air may also include additional nitrogen or carbon dioxide. The gas mixture contacts the spent sorbent containing metal sulfide at a temperature above 500/sup 0/C to regenerate the sulfide to metal oxide or carbonate. Various metal species including the period four transition metals and the lanthanides are suitable sorbents that may be regenerated by this method. In addition, the introduction of carbon dioxide gas permits carbonates such as those of strontium, barium and calcium to be regenerated. The steam permits regeneration of spent sorbent without formation of metal sulfate. Moreover, the regeneration will proceed with low oxygen concentrations and will occur without the increase in temperature to minimize the risk of sintering and densification of the sorbent. This method may be used for high-temperature fuel cells.

Jalan, V.M.; Frost, D.G.

1982-07-07T23:59:59.000Z

264

Microbial reduction of SO{sub 2} and NO{sub x} as a means of by-product recovery/disposal from regenerable processes for the desulfurization of flue gas. Technical progress report, March 11, 1993--June 11, 1993  

SciTech Connect (OSTI)

There are two basic approaches to addressing the problem of SO{sub 2} and NO{sub x} emissions: (1) desulfurize (and denitrogenate) the feedstock prior to or during combustion; or (2) scrub the resultant SO{sub 2} and oxides of nitrogen from the boiler flue gases. The flue gas processing alternative has been addressed in this project via microbial reduction of SO{sub 2} and NO{sub x} by sulfate-reducing bacteria

Sublette, K.L.

1993-11-01T23:59:59.000Z

265

Microbial reduction of SO{sub 2} and NO{sub x} as a means of by-product recovery/disposal from regenerable processes for the desulfurization of flue gas. Technical progress report, December 11, 1992--March 11, 1993  

SciTech Connect (OSTI)

This report describes the potential of sulfate reducing bacteria to fix sulfur derived from flue gas desulfurization. The first section reviews the problem, the second section reviews progress of this study to use desulfovibrio desulfuricans for this purpose. The final section related progress during the current reporting period. This latter section describes studies to immobilize the bacteria in co-culture with floc-forming anaerobes, use of sewage sludges in the culture media, and sulfate production from sulfur dioxide.

Sublette, K.L.

1993-12-31T23:59:59.000Z

266

Confined zone dispersion flue gas desulfurization demonstration. Quarterly report No. 9, November 17, 1992--February 16, 1993  

SciTech Connect (OSTI)

The CZD process involves injecting a finely atomized slurry of reactive lime into the flue gas duct work of a coal-fired utility boiler. The principle of the confined zone is to form a wet zone of slurry droplets in the middle of the duct confined in an envelope of hot gas between the wet zone and the duct walls. The lime slurry reacts with part of the SO{sub 2} in the gas, and the reaction products dry to form solid particles. A solids collector, typically on electrostatic precipitator (ESP) downstream from the point of injection, captures the reaction products along with the fly ash entrained in the flue gas. The waste product is composed of magnesium and calcium sulfite and sulfate, with some excess lime. This product mixed with fly ash is self-stabilizing because of the excess lime values, and thus tends to retain heavy metals in insoluble forms within the fly ash. The demonstration is being conducted at Penelec`s Seward Station, Unit No. 15. This boiler is a 147 MWe coal-fired unit, which utilizes Pennsylvania bituminous coal (approximately 1.2 to 2.5% sulfur). Progress is described for the ninth quarter.

Not Available

1993-10-01T23:59:59.000Z

267

Eulerian simulations of collisional effects on electrostatic plasma waves  

SciTech Connect (OSTI)

The problem of collisions in a plasma is a wide subject with a huge historical literature. In fact, the description of realistic plasmas is a tough problem to attack, both from the theoretical and the numerical point of view. In this paper, a Eulerian time-splitting algorithm for the study of the propagation of electrostatic waves in collisional plasmas is presented. Collisions are modeled through one-dimensional operators of the Fokker-Planck type, both in linear and nonlinear forms. The accuracy of the numerical code is discussed by comparing the numerical results to the analytical predictions obtained in some limit cases when trying to evaluate the effects of collisions in the phenomenon of wave plasma echo and collisional dissipation of Bernstein-Greene-Kruskal waves. Particular attention is devoted to the study of the nonlinear Dougherty collisional operator, recently used to describe the collisional dissipation of electron plasma waves in a pure electron plasma column [M. W. Anderson and T. M. O'Neil, Phys. Plasmas 14, 112110 (2007)]. Finally, for the study of collisional plasmas, a recipe to set the simulation parameters in order to prevent the filamentation problem can be provided, by exploiting the property of velocity diffusion operators to smooth out small velocity scales.

Pezzi, Oreste; Valentini, Francesco; Perrone, Denise; Veltri, Pierluigi [Dipartimento di Fisica and CNISM, Università della Calabria, 87036 Rende (CS) (Italy)] [Dipartimento di Fisica and CNISM, Università della Calabria, 87036 Rende (CS) (Italy)

2013-09-15T23:59:59.000Z

268

Electronic responses of long chains to electrostatic fields: Hartree-Fock vs. density-functional theory: A model study  

SciTech Connect (OSTI)

The response to an electrostatic field is determined through simple model calculations, within both the restricted Hartree-Fock and density functional theory methods, for long, finite as well as infinite, periodic chains. The permanent dipole moment, ?{sub 0}, the polarizability, ?, and the hyperpolarizabilities ? and ?, calculated using a finite-field approach, are extensively analyzed. Our simple model allows for treatment of large systems and for separation of the properties into atomic and unit-cell contributions. That part of the response properties attributable to the terminations of the finite system change into delocalized current contributions in the corresponding infinite periodic system. Special emphasis is placed on analyzing the reasons behind the dramatic overestimation of the response properties found with density functional theory methods presently in common use.

Vargas, Jorge, E-mail: j.vargas@mx.uni-saarland.de [Physical and Theoretical Chemistry, University of Saarland, 66123 Saarbrücken (Germany)] [Physical and Theoretical Chemistry, University of Saarland, 66123 Saarbrücken (Germany); Springborg, Michael, E-mail: m.springborg@mx.uni-saarland.de [Physical and Theoretical Chemistry, University of Saarland, 66123 Saarbrücken (Germany) [Physical and Theoretical Chemistry, University of Saarland, 66123 Saarbrücken (Germany); School of Materials Science and Engineering, Tianjin University, Tianjin 300072 (China); Kirtman, Bernard [Department of Chemistry and Biochemistry, University of California, Santa Barbara, California 93106 (United States)] [Department of Chemistry and Biochemistry, University of California, Santa Barbara, California 93106 (United States)

2014-02-07T23:59:59.000Z

269

Effect of functionalization on the electrostatic charging, tunneling, and Raman spectroscopy of epitaxial graphene  

E-Print Network [OSTI]

graphene Appl. Phys. Lett. 101, 111602 (2012); 10.1063/1.4752443 Evidences of electrochemical graphene a marked effect on the homogeneity of the electrostatic charge and leads to an increase of the energy

270

Applications of an electrostatic high-voltage tether to radiation belt remediation  

E-Print Network [OSTI]

A computational algorithm is developed and executed to calculate the rate of depletion of magnetospheric ions by an electrostatic tether at various altitudes. This computation relies upon past studies in the OML regime of ...

Zeineh, Christopher F

2007-01-01T23:59:59.000Z

271

Electrostatic Self-Assembly of Pt-around-Au Nanocomposite with...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Self-Assembly of Pt-around-Au Nanocomposite with High Activity towards Formic Acid Oxidation. Electrostatic Self-Assembly of Pt-around-Au Nanocomposite with High Activity towards...

272

Design of a hermetically sealed MEMS resonator with electrostatic actuation and capacitive third harmonic sensing  

E-Print Network [OSTI]

A microscale beam resonator has been designed and fabricated for use as a modular pressure sensor for vacuum applications. The device dimensions have been optimized to provide measurable signals with low noise. Electrostatic ...

Newton, Eric B

2012-01-01T23:59:59.000Z

273

An innovative accelerator-driven inertial electrostatic confinement device using converging ion beams  

SciTech Connect (OSTI)

Fundamental physics issues facing development of fusion power on a small-scale are assessed with emphasis on the idea of Inertial Electrostatic Confinement (IEC). The authors propose a new concept of accelerator-driven IEC fusion, termed Converging Beam Inertial Electrostatic Confinement (CB-IEC). CB-IEC offers a number of innovative features that make it an attractive pathway toward resolving fundamental physics issues and assessing the ultimate viability of the IEC concept for power generation.

Bauer, T. H.; Wigeland, R. A.

1999-12-08T23:59:59.000Z

274

Study of electrostatic charge generation and antistatic additive effects in used transformer oil  

E-Print Network [OSTI]

STUDY OF ELECTROSTATIC CHARGE GENERATION AND ANTISTATIC ADDITIVE EFFECTS IN USED TRANSFORMER OIL A Thesis by FERNANDO RANGEL CLAVIJO Submitted to the Office of Graduate Studies of Texas A8tM University in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE December 1992 Major Subject: Safety Engineering STUDY OF ELECTROSTATIC CHARGE GENERATION AND ANTISTATIC ADDITIVE EFFECTS IN USED TRANSFORMER OIL A Thesis by FERNANDO RANGEL CLAVIJO Approved as to style...

Rangel Clavijo, Fernando

1992-01-01T23:59:59.000Z

275

COMMENTS ON THE SEARCH FOR ELECTROSTATIC DISCHARGES ON MARS  

SciTech Connect (OSTI)

Ruf et al. used the Deep Space Network (DSN) to search for the emission of non-thermal radiation by martian dust storms, theoretically predicted by Renno et al. They detected the emission of non-thermal radiation that they were searching for, but were surprised that it contained spectral peaks suggesting modulation at various frequencies and their harmonics. Ruf et al. hypothesized that the emission of non-thermal radiation was caused by electric discharges in a deep convective dust storm, modulated by Schumann resonances (SRs). Anderson et al. used the Allen Telescope Array (ATA) to search for similar emissions. They stated that they found only radio frequency interference (RFI) during their search for non-thermal emission by martian dust storms and implicitly suggested that the signal detected by Ruf et al. was also RFI. However, their search was not conducted during the dust storm season when deep convective storms are most likely to occur. Here, we show that the ubiquitous dust devils and small-scale dust storms that were instead likely present during their observations are too shallow to excite SRs and produce the signals detected by Ruf et al. We also show that the spectral and temporal behavior of the signals detected by Anderson et al. corroborates the idea that they originated from man-made pulse-modulated telecommunication signals rather than martian electric discharges. In contrast, an identical presentation of the signals detected by Ruf et al. demonstrates that they do not resemble man-made signals. The presentation indicates that the DSN signals were consistent with modulation by martian SRs, as originally hypothesized by Ruf et al. We propose that a more comprehensive search for electrostatic discharges be conducted with either the ATA or DSN during a future martian dust storm season to test the hypothesis proposed by Ruf et al.

Renno, Nilton O.; Ruf, Christopher S., E-mail: renno@alum.mit.edu [Atmospheric, Oceanic and Space Sciences, University of Michigan, Ann Arbor, MI (United States)

2012-12-20T23:59:59.000Z

276

Dendrite-Free Lithium Deposition via Self-Healing Electrostatic Shield Mechanism  

SciTech Connect (OSTI)

Lithium metal batteries are called the “holy grail” of energy storage systems. However, lithium dendrite growth in these batteries has prevented their practical applications in the last 40 years. Here we show a novel mechanism which can fundamentally change the dendritic morphology of lithium deposition. A low concentration of the second cations (including ions of cesium, rubidium, potassium, and strontium) exhibits an effective reduction potential lower than the standard reduction potential of lithium ions when the chemical activities of these second cations are much lower than that of lithium ions. During lithium deposition, these second cations will form a self-healing electrostatic shield around the initial tip of lithium whenever it is formed. This shield will repel the incoming lithium ions and force them to deposit in the smoother region of the anode so a dendrite-free film is obtained. This mechanism is effective on dendrite prevention in both lithium metal and lithium ion batteries. They may also prevent dendrite growth in other metal batteries and have transformational impact on the smooth deposition in general electrodeposition processes.

Ding, Fei; Xu, Wu; Graff, Gordon L.; Zhang, Jian; Sushko, Maria L.; Chen, Xilin; Shao, Yuyan; Engelhard, Mark H.; Nie, Zimin; Xiao, Jie; Liu, Xingjiang; Sushko, P. V.; Liu, Jun; Zhang, Jiguang

2013-02-28T23:59:59.000Z

277

High-volume, high-value usage of flue gas desulfurization (FGD) by-products in underground mines - Phase I: Laboratory investigations. Quarterly report, October 1993--December 1993  

SciTech Connect (OSTI)

This project proposes to use pneumatically or hydraulically emplaced dry-flue gas desulfurization (FGD) by-products to backfill the adits left by highwall mining. Backfilling highwall mine adits with dry-FGD materials is technically attractive. The use of an active highwall mine would allow the dry-FGD material to be brought in using the same transportation network used to move the coal out, eliminating the need to recreated the transportation infrastructure, thereby saving costs. Activities during the period included the negotiations leading to the final cooperative agreement for the project and the implementation of the necessary instruments at the University of Kentucky to administer the project. Early in the negotiations, a final agreement on a task structure was reached and a milestone plan was filed. A review was initiated of the original laboratory plan as presented in the proposal, and tentative modifications were developed. Selection of a mine site was made early; the Pleasant Valley mine in Greenup County was chosen. Several visits were made to the mine site to begin work on the hydrologic monitoring plan. The investigation of the types of permits needed to conduct the project was initiated. Considerations concerning the acceptance and implementation of technologies led to the choice of circulating fluidized bed ash as the primary material for the study. Finally, the membership of a Technical Advisory Committee for the study was assembled.

Not Available

1994-03-01T23:59:59.000Z

278

pH-dependent charge trapping by quinones electrostatically bound in an electrode confined benzylviologen polymer  

SciTech Connect (OSTI)

Anthraquinone-2,6-disulfonate, 2,6-AQ, and anthraquinone-2-sulfonate, 2-AQ, have been electrostatically bound in an electrode-confined N,N{prime}-bis(p-(trimethoxysilyl)benzyl)-4,4{prime}-bipyridinium-based polymer, (BPQ{sup 2+/+}){sub n}. Under all conditions in aqueous electrolyte it appears that charge transport via the quinone redox system, AQ/AQH{sub 2}, is too slow to allow direct access to all quinone centers in the polymer. Generally, all quinone centers are electrode accessible only via the BPQ{sup 2+/+} redox mediator. At pH 6.5 the electrochemistry of ((BPQ{sup 2+}){sub n}{center dot}(AQ){sub m}){sub surf} is approximately the superposition of the AQ solution electrochemistry and the electrochemistry of surface-confined (BPQ{sup 2+/+}){sub n} examined separately. At pH 1.0 the reduction potential of AQ shifts positive and (BPQ{sup 2+/+}){sub n} can only mediate the reduction of AQ to the 2e{sup {minus}}/2H{sup +} reduced form, AQH{sub 2}, since the oxidation of AQH{sub 2} by BPQ{sup 2+} is thermodynamically uphill. Therefore, the charge associated with the reduced quinone, AQH{sub 2}, remains trapped in analogy to previous reports of charge trapping in bilayer systems. The trapped charge is released from the ((BPQ{sup 2+}){sub n}{center dot}(AQ){sub m}){sub surf} system by a sudden increase in pH which changes the thermodynamics to allow oxidation of the AQH{sub 2} by the BPQ{sup 2+}.

Not Available

1989-02-23T23:59:59.000Z

279

Nitrogen oxides removal by pulsed corona enhanced wet electrostatics precipitation  

SciTech Connect (OSTI)

This paper presents the results of a bench-scale pulsed-corona enhanced wet electrostatic precipitator (wESP) application for removal of nitrogen oxides. This wESP is designed to operate wet/dry, positive/negative, and pulsed/non-pulsed conditions. The applied pulsed voltage is varied from 0 to 60 kV at 70 Hz. Gas flow rate is a nominal 7 m{sup 3}/hr and the collecting electrode area is 0.20 m{sup 2}. A simulated flue gas with NO concentration up to 1,200 ppm{sub v} has been used to determine the feasibility of NO{sub x} removal in the wESP. NO has to be oxidized to N{sub 2} before any removal takes place. NO{sub x} removal efficiency increased with gas residence time, inlet NO concentration and applied corona power. In the air stream with 10 seconds gas residence time, up to 20% of 1,000 ppm NO (or 22% NO{sub x}) was removed from an air stream of 1.9x10{sup {minus}3} m{sup 3}/s with a water flow of 6.3 x 10{sup {minus}5} m{sup 3}/sec and 20 W, 70 Hz pulsed corona. Both ammonia and ozone injections improve the NO{sub x} removal for both the corona and non-corona cases. With the inclusion of NH{sub 3} (NH{sub 3}/NO{sub x} ratio 1.3) and 25 watts corona power, NO removal efficiency was increased from 28% to 57%. The amount of in-situ ozone is not enough to be considered as a major NO{sub x} removal mechanism in this wESP. However, the additional injection of ozone improves the NO removal from 29% to 38% for both the corona and non-corona cases. When the oxygen concentration is dropped to 3% in a simulated flue gas with 12% CO{sub 2} and 800 ppm NO and 70% relative humidity at 11.5 s of gas residence time, the removal efficiency of NO is only 5%. Adding NH{sub 3} (NH{sub 3}/NO{sub x} ratio 1) at 76 watts corona power, NO removal is increased to 13%.

Tseng, C.H.; Keener, T.C.; Khang, S.J.

1999-07-01T23:59:59.000Z

280

Electrostatic beneficiation of coal. Quarterly technical progress report, January 1, 1994--March 31, 1994  

SciTech Connect (OSTI)

Electrostatic beneficiation of dry coal has received significant attention in the last decade. In this process the coal is ground and then charged, either by corona charging or by triboelectrification (friction charging). Coal and minerals receive different levels of charge -- often opposite polarities in the case of triboelectrification -- and can then be separated based on differences in electrical mobility. Problems associated with the techniques include rapid deposition of particles on the electrodes, thus, effecting further separation. The goal of this project is to optimize the electrostatic coal cleaning process to remove pyrites and inorganic materials through studies of the electrostatic properties of powdered coal, in-situ measurements of the electrodynamics of coal and mineral particles inside the separator, and development of self-cleaning collector plates for continuous separation.

Mazumder, M.K.

1994-04-28T23:59:59.000Z

Note: This page contains sample records for the topic "desulfurization systems electrostatic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
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We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Pressurized fluidized-bed hydroretorting of eastern oil shales. Volume 2, Task 3, Testing of process improvement concepts: Final report, September 1987--May 1991  

SciTech Connect (OSTI)

This final report, Volume 2, on ``Process Improvement Concepts`` presents the results of work conducted by the Institute of Gas Technology (IGT), the Illinois Institute of Technology (IIT), and the Ohio State University (OSU) to develop three novel approaches for desulfurization that have shown good potential with coal and could be cost-effective for oil shales. These are (1) In-Bed Sulfur Capture using different sorbents (IGT), (2) Electrostatic Desulfurization (IIT), and (3) Microbial Desulfurization and Denitrification (OSU and IGT). Results of work on electroseparation of shale oil and fines conducted by IIT is included in this report, as well as work conducted by IGT to evaluate the restricted pipe discharge system. The work was conducted as part of the overall program on ``Pressurized Fluidized-Bed Hydroretorting of Eastern Oil Shales.``

Not Available

1992-03-01T23:59:59.000Z

282

Progresses in Ab Initio QM/MM Free Energy Simulations of Electrostatic Energies in Proteins: Accelerated QM/MM Studies of pKa, Redox Reactions and Solvation Free Energies  

SciTech Connect (OSTI)

Hybrid quantum mechanical / molecular mechanical (QM/MM) approaches have been used to provide a general scheme for chemical reactions in proteins. However, such approaches still present a major challenge to computational chemists, not only because of the need for very large computer time in order to evaluate the QM energy but also because of the need for propercomputational sampling. This review focuses on the sampling issue in QM/MM evaluations of electrostatic energies in proteins. We chose this example since electrostatic energies play a major role in controlling the function of proteins and are key to the structure-function correlation of biological molecules. Thus, the correct treatment of electrostatics is essential for the accurate simulation of biological systems. Although we will be presenting here different types of QM/MM calculations of electrostatic energies (and related properties), our focus will be on pKa calculations. This reflects the fact that pKa of ionizable groups in proteins provide one of the most direct benchmarks for the accuracy of electrostatic models of macromolecules. While pKa calculations by semimacroscopic models have given reasonable results in many cases, existing attempts to perform pKa calculations using QM/MM-FEP have led to large discrepancies between calculated and experimental values. In this work, we accelerate our QM/MM calculations using an updated mean charge distribution and a classical reference potential. We examine both a surface residue (Asp3) of the bovine pancreatic trypsin inhibitor, as well as a residue buried in a hydrophobic pocket (Lys102) of the T4-lysozyme mutant. We demonstrate that by using this approach, we are able to reproduce the relevant sidechain pKas with an accuracy of 3 kcal/mol. This is well within the 7 kcal/mol energy difference observed in studies of enzymatic catalysis, and is thus sufficient accuracy to determine the main contributions to the catalytic energies of enzymes. We also provide an overall perspective of the potential of QM/MM calculations in general evaluations of electrostatic free energies, pointing out that our approach should provide a very powerful and accurate tool to predict the electrostatics of not only solution but also enzymatic reactions, as well as the solvation free energies of even larger systems, such as nucleic acid bases incorporated into DNA.

Kamerlin, Shina C. L.; Haranczyk, Maciej; Warshel, Arieh

2009-03-01T23:59:59.000Z

283

EUROTeV-Memo-2007-003 Power loss estimation in the Electrostatic Separators of the ILC  

E-Print Network [OSTI]

EUROTeV-Memo-2007-003 - 1 - Power loss estimation in the Electrostatic Separators of the ILC presents the power loss estimation in the Electrostatic Separators of the ILC alternative head-on scheme-003 - 2 - Computation The computation of the power losses has been realized using DIMAD software

Boyer, Edmond

284

Laboratory Measurements of Electrostatic Solitary Structures Generated by Beam Injection Bertrand Lefebvre,1,* Li-Jen Chen,1  

E-Print Network [OSTI]

Laboratory Measurements of Electrostatic Solitary Structures Generated by Beam Injection Bertrand February 2010; published 7 September 2010) Electrostatic solitary structures are generated by injection-widths 4 to 25De and velocities 1 to 3 times the background electron thermal speed. Nonlinear wave packets

California at Los Angles, University of

285

LARGE-SCALE MECURY CONTROL TECHNOLOGY TESTING FOR LIGNITE-FIRED UTILITIES-OXIDATION SYSTEMS FOR WET FGD  

SciTech Connect (OSTI)

The Energy & Environmental Research Center (EERC) is conducting a consortium-based effort directed toward resolving the mercury (Hg) control issues facing the lignite industry. Specifically, the EERC team--the EERC, EPRI, URS, ADA-ES, Babcock & Wilcox, the North Dakota Industrial Commission, SaskPower, and the Mercury Task Force, which includes Basin Electric Power Cooperative, Otter Tail Power Company, Great River Energy, Texas Utilities (TXU), Montana-Dakota Utilities Co., Minnkota Power Cooperative, BNI Coal Ltd., Dakota Westmoreland Corporation, and the North American Coal Company--has undertaken a project to significantly and cost-effectively oxidize elemental mercury in lignite combustion gases, followed by capture in a wet scrubber. This approach will be applicable to virtually every lignite utility in the United States and Canada and potentially impact subbituminous utilities. The oxidation process is proven at the pilot-scale and in short-term full-scale tests. Additional optimization is continuing on oxidation technologies, and this project focuses on longer-term full-scale testing. The lignite industry has been proactive in advancing the understanding of and identifying control options for Hg in lignite combustion flue gases. Approximately 1 year ago, the EERC and EPRI began a series of Hg-related discussions with the Mercury Task Force as well as utilities firing Texas and Saskatchewan lignites. This project is one of three being undertaken by the consortium to perform large-scale Hg control technology testing to address the specific needs and challenges to be met in controlling Hg from lignite-fired power plants. This project involves Hg oxidation upstream of a system equipped with an electrostatic precipitator (ESP) followed by wet flue gas desulfurization (FGD). The team involved in conducting the technical aspects of the project includes the EERC, Babcock & Wilcox, URS, and ADA-ES. The host sites include Minnkota Power Cooperative Milton R. Young Unit 2 and TXU Monticello Unit 3. The work involves establishing Hg oxidation levels upstream of air pollution control devices (APCDs) and removal rates across existing ESP and FGD units, determining costs associated with those removal rates, investigating the possibility of the APCD acting as a multipollutant control device, quantifying the balance of plant impacts of the control technologies, and facilitating technology commercialization.

Michael J. Holmes; Steven A. Benson; Jeffrey S. Thompson

2004-03-01T23:59:59.000Z

286

An improved fast multipole method for electrostatic potential calculations in a class of coarse-grained molecular simulations  

SciTech Connect (OSTI)

This paper presents a novel algorithm to approximate the long-range electrostatic potential field in the Cartesian coordinates applicable to 3D coarse-grained simulations of biopolymers. In such models, coarse-grained clusters are formed via treating groups of atoms as rigid and/or flexible bodies connected together via kinematic joints. Therefore, multibody dynamic techniques are used to form and solve the equations of motion of such coarse-grained systems. In this article, the approximations for the potential fields due to the interaction between a highly negatively/positively charged pseudo-atom and charged particles, as well as the interaction between clusters of charged particles, are presented. These approximations are expressed in terms of physical and geometrical properties of the bodies such as the entire charge, the location of the center of charge, and the pseudo-inertia tensor about the center of charge of the clusters. Further, a novel substructuring scheme is introduced to implement the presented far-field potential evaluations in a binary tree framework as opposed to the existing quadtree and octree strategies of implementing fast multipole method. Using the presented Lagrangian grids, the electrostatic potential is recursively calculated via sweeping two passes: assembly and disassembly. In the assembly pass, adjacent charged bodies are combined together to form new clusters. Then, the potential field of each cluster due to its interaction with faraway resulting clusters is recursively calculated in the disassembly pass. The method is highly compatible with multibody dynamic schemes to model coarse-grained biopolymers. Since the proposed method takes advantage of constant physical and geometrical properties of rigid clusters, improvement in the overall computational cost is observed comparing to the tradition application of fast multipole method.

Poursina, Mohammad [Department of Aerospace and Mechanical Engineering, University of Arizona, Tucson, AZ 85721 (United States); Anderson, Kurt S. [Department of Mechanical, Aerospace and Nuclear Engineering, Rensselaer Polytechnic Institute (RPI), Troy, NY 12180 (United States)

2014-08-01T23:59:59.000Z

287

Electrostatic dynamo in reversed field pinch plasmas: simple common fundamental nature of laminar and turbulent regimes  

SciTech Connect (OSTI)

Within the framework of magnetohydrodynamic (MHD) numerical modelling, the Reversed Field Pinch (RFP) has been found to develop turbulent or laminar regimes switching from the former to the latter in a continuous way depending on the strength of dissipative forces. The laminar solution corresponds to a simple global helical deformation of the current channel. A helically-modulated electrostatic field arises in order to account for the helical modulation of the current density along magnetic field lines. The associated electrostatic drift yields the main component of the dynamo velocity field. The continuity of the transition between the two regimes suggests that the simple laminar helical solution can provide a fruitful intuitive description of the RFP dynamo in general. In fact, the electrostatic drift remains the main component of the dynamo velocity field in the non-stationary turbulent regime for a sustained RFP. We show that the same dynamo action, due to the electrostatic drift, is provided either by one single mode and its harmonics, as in the laminar regime, or by a rich spectrum of modes with the action of full nonlinear coupling, as in the turbulent one. Here, we review our previous work and present new elements to clarify the physics of the RFP dynamo. Many of the MHD predictions are in good agreement with experimental findings.

Bonfiglio, D.; Cappello, S. [Consorzio RFX, Associazione EURATOM-ENEA sulla fusione, Padova (Italy); Escande, D. F. [Consorzio RFX, Associazione EURATOM-ENEA sulla fusione, Padova (Italy); CNRS-Universite de Provence, Marseille (France)

2006-11-30T23:59:59.000Z

288

Efficient Evaluation of Binding Free Energy Using Continuum Electrostatics Danzhi Huang and Amedeo Caflisch*  

E-Print Network [OSTI]

Efficient Evaluation of Binding Free Energy Using Continuum Electrostatics Solvation Danzhi Huang of the absolute free energy of binding. A predictive accuracy of about 1.0 kcal/mol is obtained for 13 and 29 into proteins of known structure require fast and accurate methods for the evaluation of binding free energies.1

Caflisch, Amedeo

289

ChemicalPhysicsLetters270 (1997) 476-483 Electrostatics by Brownian dynamics  

E-Print Network [OSTI]

ELSEVIER 30May 1997 ChemicalPhysicsLetters270 (1997) 476-483 CHEMICAL PHYSICS LETTERS, Jerusalem 91904, Israel Received26 December1996;in finalform31 March1997 Abstract The isomorphism between is demonstrated in simple illustrative calculations. © 1997 Elsevier Science B.V. 1. Introduction Electrostatic

Agmon, Noam

290

Design considerations for electrostatic microvalves with applications in poly(dimethylsiloxane)-based microfluidics  

E-Print Network [OSTI]

(dimethylsiloxane)-based microfluidics Amit V. Desai,a Joshua D. Tice,a Christopher A. Apblettbc and Paul J. A. Kenis*a Received 19th of integrated microfluidic chips for a wide range of applications. In this paper, we present an analytical model to guide the design of electrostatic microvalves that can be integrated into microfluidic chips using

Kenis, Paul J. A.

291

Branches of electrostatic turbulence inside solitary plasma structures in the auroral ionosphere  

SciTech Connect (OSTI)

The excitation of electrostatic turbulence inside space-observed solitary structures is a central topic of this exposition. Three representative solitary structures observed in the topside auroral ionosphere as large-amplitude nonlinear signatures in the electric field and magnetic-field-aligned current on the transverse scales of ?10{sup 2}–10{sup 3}?m are evaluated by the theories of electrostatic wave generation in inhomogeneous background configurations. A quantitative analysis shows that the structures are, in general, effective in destabilizing the inhomogeneous energy-density-driven (IEDD) waves, as well as of the ion acoustic waves modified by a shear in the parallel drift of ions. It is demonstrated that the dominating branch of the electrostatic turbulence is determined by the interplay of various driving sources inside a particular solitary structure. The sources do not generally act in unison, so that their common effect may be inhibiting for excitation of electrostatic waves of a certain type. In the presence of large magnetic-field-aligned current, which is not correlated to the inhomogeneous electric field inside the structure, the ion-acoustic branch becomes dominating. In other cases, the IEDD instability is more central.

Golovchanskaya, Irina V.; Kozelov, Boris V. [Polar Geophysical Institute, Apatity 184209 (Russian Federation); Chernyshov, Alexander A.; Mogilevsky, Mikhail M. [Space research Institute, Moscow 117997 (Russian Federation); Ilyasov, Askar A. [Moscow Institute of Physics and Technology, Moscow 141700 (Russian Federation); Space research Institute, Moscow 117997 (Russian Federation)

2014-08-15T23:59:59.000Z

292

Entropy bound of a charged object and electrostatic self-energy in black holes  

E-Print Network [OSTI]

Without pretending to any rigour, we find a general expression of the electrostatic self-energy in static black holes with spherical symmetry. We determine the entropy bound of a charged object by assuming the existence of thermodynamics for these black holes. By combining these two results, we show that the entropy bound does not depend on the considered black hole.

B. Linet

1999-11-30T23:59:59.000Z

293

Electrostatic self-force in a static weak gravitational field with cylindrical symmetry  

E-Print Network [OSTI]

We determine the electrostatic self-force at rest in an arbitrary static metric with cylindrical symmetry in the linear approximation in the Newtonian constant. In linearised Einstein theory, we express it in terms of the components of the energy-momentum tensor.

B. Boisseau; C. Charmousis; B. Linet

1996-03-04T23:59:59.000Z

294

A METHOD FOR IMAGING CORROSION DAMAGE IN THIN PLATES FROM ELECTROSTATIC DATA  

E-Print Network [OSTI]

A METHOD FOR IMAGING CORROSION DAMAGE IN THIN PLATES FROM ELECTROSTATIC DATA Peter G. Kaup 1 nondestructive evaluation of corrosion in plates is considered. The inpection method uses boundary measurements of currents and voltages to determine the material loss caused by corrosion. The development of the method

Santosa, Fadil

295

An impact model of the electrostatic force: Coulomb's law re-visited  

E-Print Network [OSTI]

The electrostatic force is described in this model by the action of electric dipole distributions on charged particles. The individual hypothetical dipoles are propagating at the speed of light in vacuum transferring momentum and energy between charges through interactions on a local basis. The model is constructed in analogy to an impact model describing the gravitational forces.

K. Wilhelm; B. N. Dwivedi; H. Wilhelm

2014-05-27T23:59:59.000Z

296

Photothermal electrostatics of the d-poiyvlnylidene fluoride photopyroelectric hydrogen gas sensor  

E-Print Network [OSTI]

atoms adsorbed and subsequently absorbed in the Pd ground electrode of the PVDF. In this paper in Fig. 1. This amounts to a capacitor consisting of Pd-elec- trode (ground; anode)/PVDF dielectric/Al-Ni-electrode) A detailed photothermal electrostatic consideration of the Pd-pyroelectric junction H, sensor is presented

Mandelis, Andreas

297

Electrostatic electron cyclotron waves generated by low-energy electron beams  

E-Print Network [OSTI]

Electrostatic electron cyclotron waves generated by low-energy electron beams J. D. Menietti, O the role of electron beams with E ] 1 keV in the generation of these waves. Observed plasma parameters these waves are an indicator of the presence of low-energy electron beams and a cold electron component (E ] 0

Santolik, Ondrej

298

Soft-X-Ray-Charged Vertical Electrets and Its Application to Electrostatic Transducers  

E-Print Network [OSTI]

Soft-X-Ray-Charged Vertical Electrets and Its Application to Electrostatic Transducers Makoto A novel charging method for vertical electrets in narrow gaps using soft X-rays has been developed is necessary after charging the electrets. Recently, we have developed a new charging method using soft X-ray

Kasagi, Nobuhide

299

Yukawa-field approximation of electrostatic free energy and dielectric boundary force This article has been downloaded from IOPscience. Please scroll down to see the full text article.  

E-Print Network [OSTI]

Yukawa-field approximation of electrostatic free energy and dielectric boundary force This article.1088/0951-7715/24/11/011 Yukawa-field approximation of electrostatic free energy and dielectric boundary force Hsiao-Bing Cheng1. The electrostatic free energy determines the dielectric boundary force that in turn influences crucially

Li, Bo

300

Exploratory test of utility of magnetic insulation for electrostatic accelerators L. R. Grisham, A. von Halle, A. F. Carpe, Guy Rossi, K. R. Gilton et al.  

E-Print Network [OSTI]

Exploratory test of utility of magnetic insulation for electrostatic accelerators L. R. Grisham, A;Exploratory test of utility of magnetic insulation for electrostatic accelerators L. R. Grisham,a) A. von of the electrodes in an electrostatic accelerator, along with their support structures, might suppress field

Gilson, Erik

Note: This page contains sample records for the topic "desulfurization systems electrostatic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Simulations of Direct Ion Acceleration with Beating Electrostatic Waves  

E-Print Network [OSTI]

. Gardineer, IV , Benjamin Jorns , and Edgar Y. Choueiri Electric Propulsion and Plasma Dynamics Laboratory Wave Thruster (BWT) ­ an electrodeless electric propulsion concept based on direct ion acceleration. The ultimate goal is for this acceleration mechanism to form the basis of a new plasma propulsion system called

Choueiri, Edgar

302

Confined zone dispersion flue gas desulfurization demonstration. Volume 1, Quarterly report No. 5, November 1, 1991--January 31, 1992  

SciTech Connect (OSTI)

This is the fifth quarterly report for this project. This project is divided into three phases. Phase 1, which has been completed, involved design, engineering, and procurement for the CZD system, duct and facility modifications, and supporting equipment. Phase 2, also completed, included equipment acquisition and installation, facility construction, startup, and operator training for parametric testing. Phase 3 broadly covers testing, operation and disposition, but only a portion of Phase 3 was included in Budget Period 1. That portion was concerned with parametric testing of the CZD system to establish the optimum conditions for an extended, one-year, continuous demonstration. As of December 31, 1991, the following goals have been achieved. (1) Nozzle Selection - A modified Spraying Systems Company (SSC) atomizing nozzle has been selected for the one-year continuous CZD demonstration. (2) SO{sub 2} and NO{sub x} Reduction - Preliminary confirmation of 50% SO{sub 2} reduction has been achieved, but the NO{sub x} reduction target cannot be confirmed at this time. (3) Lime Selection - Testing indicated an injection rate of 40 to 50 gallons per minute with a lime slurry concentration of 8 to 10% to achieve 50% SO{sub 2} reduction. There has been no selection of the lime to be used in the one year demonstration. (4) ESP Optimization - Tests conducted to date have shown that lime injection has a very beneficial effect on ESP performance, and little adjustment may be necessary. (5) SO{sub 2} Removal Costs - Testing has not revealed any significant departure from the bases on which Bechtel`s original cost estimates (capital and operating) were prepared. Therefore, SO{sub 2} removal costs are still expected to be in the range of $300/ton or less.

Not Available

1992-12-31T23:59:59.000Z

303

Geometric nonlinear analysis of microbeam under electrostatic loading  

E-Print Network [OSTI]

mature, and a variety of new engineering products are being introduced into the market, there arises a need for sophisticated computer-aided engineering (CAE) tools or computer-aided design systems (CAD). Computational prototyping or simulations, when...- static field analysis [12]. Omar et al. [13] present a finite element method (FEM) for modeling electric and fluid fields in micrometers. Mullen et al. [14] used the finite element method to predict the load and buckling behavior of micro...

Murgude, Nikhil C.

2001-01-01T23:59:59.000Z

304

Magnetohydrodynamic dynamo in reversed field pinch plasmas: Electrostatic drift nature of the dynamo velocity field  

SciTech Connect (OSTI)

Within the framework of magnetohydrodynamic (MHD) numerical modeling, the reversed field pinch (RFP) has been found to develop turbulent or laminar regimes switching from the former to the latter in a continuous way when the strength of dissipative forces increases. The laminar solution corresponds to a simple global helical deformation of the current channel and is associated with an electrostatic dynamo field. The related electrostatic drift yields the main component of the dynamo velocity field. While quite natural in the stationary helical state, this analysis is shown to extend also to the dynamic turbulent regime for an Ohmic RFP. The continuity of the transition between the two regimes suggests that the simple helical symmetric solution can provide a fruitful intuitive description of the RFP dynamo in general. Many of the MHD predictions are in good agreement with experimental findings.

Cappello, S.; Bonfiglio, D.; Escande, D.F. [Consorzio RFX, Associazione Euratom-ENEA sulla Fusione, Corso Stati Uniti 4, 35127 Padova (Italy); Consorzio RFX, Associazione Euratom-ENEA sulla Fusione, Corso Stati Uniti 4, 35127 Padova (Italy); UMR 6633, CNRS-Universite de Provence, Marseille (France)

2006-05-15T23:59:59.000Z

305

MULTI-POLLUTANT CONTROL USING MEMBRANE--BASED UP-FLOW WET ELECTROSTATIC PRECIPITATION  

SciTech Connect (OSTI)

This is the second quarterly report of the ''Multi-Pollutant Control Using Membrane-Based Upflow Wet Electrostatic Precipitation'' project funded by the US Department of Energy's National Energy Technology Laboratory under DOE Award No. DE-FC26-02NT41592 to Croll-Reynolds Clean Air Technologies (CRCAT). In this 18 month project, CRCAT and its team members will conduct detailed emission tests of metallic and new membrane collection material within a wet electrostatic precipitator (WESP) at First Energy's Penn Power's Bruce Mansfield (BMP) plant in Shippingport, Pa. Test results performed on the existing metallic WESP during November of 2002 showed consistent results with previous test results. Average collection efficiency of 89% on SO{sub 3} mist was achieved. Additionally, removal efficiencies of 62% were achieved at very high velocity, greater than 15 ft./sec. During the first quarter of 2003 final design and start of fabrication of the membrane wet ESP was undertaken.

James Reynolds

2003-04-30T23:59:59.000Z

306

MULTI-POLLUTANT CONTROL USING MEMBRANE-BASED UP-FLOW WET ELECTROSTATIC PRECIPITATION  

SciTech Connect (OSTI)

This is the first quarterly report of the ''Multi-Pollutant Control Using Membrane--Based Upflow Wet Electrostatic Precipitation'' project funded by the US Department of Energy's National Energy Technology Laboratory under DOE Award No. DE-FC26-02NT41592 to Croll-Reynolds Clean Air Technologies (CRCAT). In this 18 month project, CRCAT and its team members will conduct detailed emission tests of metallic and new membrane collection material within a wet electrostatic precipitator (WESP) at First Energy's Penn Power's Bruce Mansfield (BMP) plant in Shippingport, Pa. Test results performed on the existing metallic WESP during November of 2002 showed consistent results with previous test results. Average collection efficiency of 89% on SO{sub 3} mist was achieved. Additionally, removal efficiencies of 62% were achieved at very high velocity, greater than 15 ft./sec.

James Reynolds

2003-01-01T23:59:59.000Z

307

Electromagnetic field generation in the downstream of electrostatic shocks due to electron trapping  

E-Print Network [OSTI]

A new magnetic field generation mechanism in electrostatic shocks is found, which can produce fields with magnetic energy density as high as 0.01 of the kinetic energy density of the flows on time scales $ \\tilde \\, 10^4 \\, {\\omega}_{pe}^{-1}$. Electron trapping during the shock formation process creates a strong temperature anisotropy in the distribution function, giving rise to the pure Weibel instability. The generated magnetic field is well-confined to the downstream region of the electrostatic shock. The shock formation process is not modified and the features of the shock front responsible for ion acceleration, which are currently probed in laser-plasma laboratory experiments, are maintained. However, such a strong magnetic field determines the particle trajectories downstream and has the potential to modify the signatures of the collisionless shock.

Stockem, A; Fonseca, R A; Silva, L O

2014-01-01T23:59:59.000Z

308

Selective electrostatic binding of ions by monolayers of mercaptan derivatives adsorbed to gold substrates  

SciTech Connect (OSTI)

A single, self-assembled monolayer of organic material is used to impart pH-dependent electrostatic-based recognition capability to an Au electrode. The results show that 4-aminothiophenol and related mercaptans change the surface characteristics of naked Au toward the adsorption of positively and negatively charged ions as a function of pH. For example, anthraquinone-2,6-disulfonate irreversibly adsorbs to naked Au surfaces over a broad range of pH. However, a preadsorbed monolayer of 4-aminothiophenol prevents adsorption of anthraquinone-2,6-disulfonate at high pH but electrostatically binds it at low pH. The principle of pH-dependent binding is general for a number of amine-, carboxylic acid-, and pyridine-terminated mercaptan derivatives adsorbed to Au surfaces.

Sun, Li; Johnson, B.; Wade, T.; Crooks, R.M. (Univ. of New Mexico, Albuquerque (USA))

1990-12-27T23:59:59.000Z

309

Tailored Ink For Piston-Driven Electrostatic Liquid Drop Modulator  

DOE Patents [OSTI]

The present invention relates to an ink composition including water, a solvent, a solvent-soluble dye, and a surfactant, where the ink exhibits a stable liquid microemulsion phase at a first temperature and a second temperature higher than the first temperature and has a conductivity of at most about 200 .mu.S/cm and a dielectric constant of at least about 60, and methods of making such ink compositions. The present invention also relates to a method of making an ink composition for use in a microelectromechanical system-based fluid ejector. The method involves providing a solution or dispersion including a dye or a pigment and adding to the solution or dispersion an additive which includes a material that enhances dielectric permittivity and/or reduces conductivity under conditions effective to produce an ink composition having a conductivity of at most about 200 .mu.S/cm and a dielectric constant of at least about 60.

Wong, Raymond W. (Mississauga, CA); Breton, Marcel P. (Mississauga, CA); Bedford, Christine E. (Toronto, CA); Carreira, Leonard M. (Penfield, NY); Gooray, Arthur M. (Penfield, NY); Roller, George J. (Penfield, NY); Zavadil, Kevin (Benalillo, NM); Galambos, Paul (Albuquerque, NM); Crowley, Joseph (Morgan Hill, CA)

2005-04-19T23:59:59.000Z

310

Electrostatic ion-acoustic-like instabilities in the solar wind with a backstreaming alpha particle beam  

SciTech Connect (OSTI)

Nonlinear electrostatic instabilities have been shown to occur frequently and under very different conditions in plasma with two ion beams such as the fast solar wind. These instabilities can be triggered when the phase velocity of electrostatic ion-acoustic waves propagating forward and backward relative to the interplanetary magnetic field overlaps due to the presence of a finite amplitude of circularly polarized wave. The instabilities can be triggered by waves supported by the same ion component, or by waves supported by different ion components. By assuming a beam of alpha particles moving backward relative to the external magnetic field, as observed in some events in the fast solar wind, it is shown that a very small negative drift velocity of the alpha particle beam relative to the core plasma--a few percent of the local Alfven velocity--can trigger a very rich variety of nonlinear electrostatic acousticlike instabilities. Their growth rates can be rather large and they persist for larger negative alpha particles drift velocities and temperatures.

Gomberoff, L. [Departamento de Fisica, Facultad de Ciencias, Universidad de Chile, Santiago (Chile); Gomberoff, K. [Department of Physics, Technion, Haifa 32000 (Israel); Deutsch, A. [Rafael, P.O. Box 2250, Haifa 31021 (Israel)

2010-06-15T23:59:59.000Z

311

Revamping AK-Ashland gas cleaning system  

SciTech Connect (OSTI)

AK Steel`s (formerly Armco) BOF shop was using a static precipitator for the primary collection. The system was designed for full combustion in the gas collecting hoods. No secondary dust collection was in place. A detailed study on alternative solutions led to a completely different system in 1990, and an order was awarded to Mannesmann Demag Corp. (MDC) in Dec. 1990. The new gas collection system is using suppressed combustion with the capability to collect Co at a later stage. The gas cleaning uses the Mannesmann Demag Baumco scrubber with a venturi throat for gas flow control. All auxiliary components, water treatment plant, electric substations and sludge handling were designed and supplied by MDC. The secondary dust collection covers the hot metal and scrap charging into the BOF`s, reladling, desulfurization and deslagging by a pulse jet baghouse. All emission limits set by the EPA and guaranteed by MDC have been met by the systems installed.

Brandes, H.; Koerbel, R. [Mannesmann Demag Corp., Coraopolis, PA (United States); Haberkamp, K. [Mannesmann Demag Huttentechnik, Duisburg (Germany); Keeton, S. [AK Steel Corp., Ashland, KY (United States)

1995-07-01T23:59:59.000Z

312

Effect of squeeze on electrostatic Trivelpiece-Gould wave damping  

SciTech Connect (OSTI)

We present a theory for increased damping of Trivelpiece-Gouid plasma modes on a nonneutral plasma column, due to application of a Debye shielded cylindrically symmetric squeeze potential ?{sub 1}. We present two models of the effect this has on the plasma modes: a 1D model with only axial dependence, and a 2D model that also keeps radial dependence in the squeezed equilibrium and the mode. We study the models using both analytical and numerical methods. For our analytical studies, we assume that ?{sub 1}/T?1, and we treat the Debye shielded squeeze potential as a perturbation in the equilibrium Hamiltonian. Our numerical simulations solve the 1D Vlasov-Poisson system and obtain the frequency and damping rate for a self-consistent plasma mode, making no assumptions as to the size of the squeeze. In both the 1D and 2D models, damping of the mode is caused by Landau resonances at energies E{sub n} for which the particle bounce frequency ?{sub b}(E{sub n}) and the wave frequency ? satisfy ?=n?{sub b}(E{sub n}). Particles experience a non-sinusoidal wave potential along their bounce orbits due to the squeeze potential. As a result, the squeeze induces bounce harmonics with n?>?1 in the perturbed distribution. The harmonics allow resonances at energies E{sub n}?T that cause substantial damping, even when wave phase velocities are much larger than the thermal velocity. In the regime ?/k??(T/m) (k is the wave number) and T??{sub 1}, the resonance damping rate has a |?{sub 1}|{sup 2} dependence. This dependence agrees with the simulations and experimental results.

Ashourvan, Arash; Dubin, Daniel H. E. [Department of Physics, University of California at San Diego, La Jolla, California 92093 (United States)

2014-05-15T23:59:59.000Z

313

The chemical enhancement of the triboelectric separation of coal from pyrite and ash: A novel approach for electrostatic separation of mineral matter from coal. Final report  

SciTech Connect (OSTI)

Arthur D. Little, Inc., under contract to the US DOE Pittsburgh Energy Technology Center, has developed a triboelectric separation device for coal beneficiation, that employs an entrained-flow, rotating-cylinder concept. The described apparatus has been used to test the efficacy of chemical pretreatment and in-situ treatment of coal on separation efficiency. Coal particle entrainment is achieved with gaseous carbon dioxide and particle collection is accomplished by an electrostatic plate separator. The triboelectric separation device incorporates instrumentation for the direct measurement of charge in the dilute-phase particle stream. Some of the pretreatment materials investigated under this project to modify the surface charging characteristics of the coal included oleic acid, sodium oleate, quinoline and dicyclohexylamine. Ammonia and sulfur dioxide at a concentration up to 1000 ppM was used for in-situ treatment of the coal, with carbon dioxide as the carrier/inerting gas. Nitrogen was used earlier in the test program as the carrier/inerting gas for the coal, but a severe arcing problem was encountered in the electrostatic collector with nitrogen as the carrier gas. This problem did not occur when carbon dioxide was used. The report covers the chemical treatment employed, and summarizes and interprets the results achieved. In addition, an economic analysis of a full scale system based on this concept is presented.

Gustafson, R.M.; DiMare, S.; Sabatini, J.

1992-02-01T23:59:59.000Z

314

The chemical enhancement of the triboelectric separation of coal from pyrite and ash: A novel approach for electrostatic separation of mineral matter from coal  

SciTech Connect (OSTI)

Arthur D. Little, Inc., under contract to the US DOE Pittsburgh Energy Technology Center, has developed a triboelectric separation device for coal beneficiation, that employs an entrained-flow, rotating-cylinder concept. The described apparatus has been used to test the efficacy of chemical pretreatment and in-situ treatment of coal on separation efficiency. Coal particle entrainment is achieved with gaseous carbon dioxide and particle collection is accomplished by an electrostatic plate separator. The triboelectric separation device incorporates instrumentation for the direct measurement of charge in the dilute-phase particle stream. Some of the pretreatment materials investigated under this project to modify the surface charging characteristics of the coal included oleic acid, sodium oleate, quinoline and dicyclohexylamine. Ammonia and sulfur dioxide at a concentration up to 1000 ppM was used for in-situ treatment of the coal, with carbon dioxide as the carrier/inerting gas. Nitrogen was used earlier in the test program as the carrier/inerting gas for the coal, but a severe arcing problem was encountered in the electrostatic collector with nitrogen as the carrier gas. This problem did not occur when carbon dioxide was used. The report covers the chemical treatment employed, and summarizes and interprets the results achieved. In addition, an economic analysis of a full scale system based on this concept is presented.

Gustafson, R.M.; DiMare, S.; Sabatini, J.

1992-02-01T23:59:59.000Z

315

Pilot-scale ESP (electrostatic precipitator) and hydro-sonic scrubber parametric tests for particulate, metals, and HC1 emissions. Draft report  

SciTech Connect (OSTI)

The EPA's Office of Solid Waste is currently developing additional regulations to control emissions of particulate matter, toxic metals, and hydrochloric acid (HC1) from hazardous-waste incinerators. Emissions data were collected to support these regulations; testing was conducted on two pilot-scale air-pollution-control systems installed and operated in Tulsa, OK. The test program took place between March 28 and April 4, 1989. This report represents the results of the testing program and describes the processes involved as well as the testing and analytical methods used. The primary objective of the test program was to collect particulate and toxic metals removal-efficiency and emissions data for two pilot-scale air-pollution-control systems: hydro-sonic wet scrubber; and beltran two-stage electrostatic precipitator.

Garg, S.

1989-06-01T23:59:59.000Z

316

Association of the sites of heavy metals with nanoscale carbon in a Kentucky electrostatic precipitator fly ash  

SciTech Connect (OSTI)

A combination of high-resolution transmission electron microscopy, scanning transmission electron microscopy, and electron energy-loss spectroscopy (HRTEM-STEM-EELS) was used to study fly ashes produced from the combustion of an eastern Kentucky coal at a southeastern-Kentucky wall-fired pulverized coal utility boiler retrofitted for low-NOx combustion. Fly ash was collected from individual hoppers in each row of the electrostatic precipitators (ESP) pollution-control system, with multiple hoppers sampled within each of the three rows. Temperatures within the ESP array range from about 200 {degree}C at the entry to the first row to <150{degree}C at the exit of the third row. HRTEM-STEM-EELS study demonstrated the presence of nanoscale (10 s nm) C agglomerates with typical soot-like appearance and others with graphitic fullerene-like nanocarbon structures. The minute carbon agglomerates are typically juxtaposed and intergrown with slightly larger aluminosilicate spheres and often form an ultrathin halo or deposit on the fly ash particles. The STEM-EELS analyses revealed that the nanocarbon agglomerates host even finer (<3 nm) metal and metal oxide particles. Elemental analysis indicated an association of Hg with the nanocarbon. Arsenic, Se, Pb, Co, and traces of Ti and Ba are often associated with Fe-rich particles within the nanocarbon deposits. 57 refs., 5 figs.

James C. Hower; Uschi M. Graham; Alan Dozier; Michael T. Tseng; Rajesh A. Khatri [University of Kentucky, Lexington, KY (United States). Center for Applied Energy Research

2008-11-15T23:59:59.000Z

317

Process for desulfurizing petroleum feedstocks  

SciTech Connect (OSTI)

A process for upgrading an oil feedstock includes reacting the oil feedstock with a quantity of an alkali metal, wherein the reaction produces solid materials and liquid materials. The solid materials are separated from the liquid materials. The solid materials may be washed and heat treated by heating the materials to a temperature above 400.degree. C. The heat treating occurs in an atmosphere that has low oxygen and water content. Once heat treated, the solid materials are added to a solution comprising a polar solvent, where sulfide, hydrogen sulfide or polysulfide anions dissolve. The solution comprising polar solvent is then added to an electrolytic cell, which during operation, produces alkali metal and sulfur.

Gordon, John Howard; Alvare, Javier

2014-06-10T23:59:59.000Z

318

Deep desulfurization of hydrocarbon fuels  

DOE Patents [OSTI]

The invention relates to processes for reducing the sulfur content in hydrocarbon fuels such as gasoline, diesel fuel and jet fuel. The invention provides a method and materials for producing ultra low sulfur content transportation fuels for motor vehicles as well as for applications such as fuel cells. The materials and method of the invention may be used at ambient or elevated temperatures and at ambient or elevated pressures without the need for hydrogen.

Song, Chunshan (State College, PA); Ma, Xiaoliang (State College, PA); Sprague, Michael J. (Calgary, CA); Subramani, Velu (State College, PA)

2012-04-17T23:59:59.000Z

319

Electrostatic charge generation during impeller mixing in two-phase systems  

E-Print Network [OSTI]

of water to toluene was varied during the tests by adding 18 megaohm-cm, deionized, ultrapure water and using a vacuum apparatus to remove precisely measured quantities of toluene. The variance in concentra- tion of water was 0, 1, 3, 5, 7, 104...) 500 RPM 700 PN 1000 RPN 7. 48 E-13 2. 75 E-13 9. 00 E-12 2. 00 E-11 4. 74 E-11 7. 46 E-11 1. 18 E-10 1. 5 E-9 3. 0 E-9 4. 15 E-9 1. 65 E-9 3. 5 E-9 7. 5 E-9 2. 5 E-10 3. 85 E-9 5. 0 E-9 8. 3 E-9 8. 0 E-9 9. 0 E-9 3. 5 E-10 8. 0 E-9 8...

Hernandez, Andrew

1988-01-01T23:59:59.000Z

320

Electrostatic and affinity enhancements of protein partitioning in two-phase aqueous micellar systems  

E-Print Network [OSTI]

This thesis was motivated by the practical need to develop a scalable and cost-effective separation method for low-cost, high-volume protein products. This unmet challenge can potentially be addressed by extraction in ...

Lam, Hei Ning Henry

2005-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "desulfurization systems electrostatic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

An experimental system for controlled exposure of biological samples to electrostatic discharges  

E-Print Network [OSTI]

in 1809 [1] ­ have many fields of application, ranging from light sources (arc lamps, including (arc furnaces) and plasma cutting. Recently, it was reported that nanosecond electric arcs (sparks an electric arc with adjust- able air gap width or through direct contact, and reliable electrical insulation

Ljubljana, University of

322

EVALUATION OF MERCURY EMISSIONS FROM COAL-FIRED FACILITIES WITH SCR AND FGD SYSTEMS  

SciTech Connect (OSTI)

CONSOL Energy Inc., Research & Development (CONSOL), with support from the U.S. Department of Energy, National Energy Technology Laboratory (DOE) is evaluating the effects of selective catalytic reduction (SCR) on mercury (Hg) capture in coal-fired plants equipped with an electrostatic precipitator (ESP) - wet flue gas desulfurization (FGD) combination or a spray dyer absorber--fabric filter (SDA-FF) combination. In this program CONSOL is determining mercury speciation and removal at 10 coal-fired facilities. The objectives are (1) to evaluate the effect of SCR on mercury capture in the ESP-FGD and SDA-FF combinations at coal-fired power plants, (2) evaluate the effect of catalyst degradation on mercury capture; (3) evaluate the effect of low load operation on mercury capture in an SCR-FGD system, and (4) collect data that could provide the basis for fundamental scientific insights into the nature of mercury chemistry in flue gas, the catalytic effect of SCR systems on Hg speciation and the efficacy of different FGD technologies for Hg capture. This document, the second in a series of topical reports, describes the results and analysis of mercury sampling performed on a 330 MW unit burning a bituminous coal containing 1.0% sulfur. The unit is equipped with a SCR system for NOx control and a spray dryer absorber for SO{sub 2} control followed by a baghouse unit for particulate emissions control. Four sampling tests were performed in March 2003. Flue gas mercury speciation and concentrations were determined at the SCR inlet, air heater outlet (ESP inlet), and at the stack (FGD outlet) using the Ontario Hydro method. Process stream samples for a mercury balance were collected to coincide with the flue gas measurements. Due to mechanical problems with the boiler feed water pumps, the actual gross output was between 195 and 221 MW during the tests. The results showed that the SCR/air heater combination oxidized nearly 95% of the elemental mercury. Mercury removal, on a coal-to-stack basis, was 87%. The mercury material balance closures for the four tests conducted at the plant ranged from 89% to 114%, with an average of 100%. These results appear to show that the SCR had a positive effect on mercury removal. In earlier programs, CONSOL sampled mercury at six plants with wet FGDs for SO{sub 2} control without SCR catalysts. At those plants, an average of 61 {+-} 15% of the mercury was in the oxidized form at the air heater outlet. The principal purpose of this work is to develop a better understanding of the potential Hg removal ''co-benefits'' achieved by NOx, and SO{sub 2} control technologies. It is expected that this data will provide the basis for fundamental scientific insights into the nature of Hg chemistry in flue gas, the catalytic effect of SCR systems on Hg speciation and the efficacy of different FGD technologies for Hg capture. Ultimately, this insight could help to design and operate SCR and FGD systems to maximize Hg removal.

J. A. Withum; S.C. Tseng; J. E. Locke

2004-10-31T23:59:59.000Z

323

Controlling the Electrostatic Discharge Ignition Sensitivity of Composite Energetic Materials Using Carbon Nanotube Additives  

SciTech Connect (OSTI)

Powder energetic materials are highly sensitive to electrostatic discharge (ESD) ignition. This study shows that small concentrations of carbon nanotubes (CNT) added to the highly reactive mixture of aluminum and copper oxide (Al + CuO) significantly reduces ESD ignition sensitivity. CNT act as a conduit for electric energy, bypassing energy buildup and desensitizing the mixture to ESD ignition. The lowest CNT concentration needed to desensitize ignition is 3.8 vol.% corresponding to percolation corresponding to an electrical conductivity of 0.04 S/cm. Conversely, added CNT increased Al + CuO thermal ignition sensitivity to a hot wire igniter.

Kade H. Poper; Eric S. Collins; Michelle L. Pantoya; Michael Daniels

2014-10-01T23:59:59.000Z

324

Wet electrostatic precipitator having removable nested hexagonal collector plates and magnetic aligning and rapping means  

SciTech Connect (OSTI)

A wet electrostatic precipitator including a plurality of removable nested collecting electrodes or plates forming a repeating pattern of hexagonal collecting zones throughout the precipitator. Each collecting plate is formed with a sixty degree bend along two opposing longitudinal edges so as to allow three plates to form a self-nesting Y-shaped intersection point. Six points form a hexagonal collecting zone. The plates are removable thereby expediting replacement. A plurality of strategically placed spray nozzles provide wash fluid to the plates. Magnet sets provide for discharge electrode alignment and rapping.

Young, C.E.; Drzewiecki, G.

1984-04-10T23:59:59.000Z

325

Phase-mixing of electrostatic modes in a cold magnetized electron-positron plasma  

SciTech Connect (OSTI)

In a fluid description, we study space-time evolution of electrostatic oscillations in a cold magnetized electron-positron plasma. Nonlinear results up to third order, obtained by employing a simple perturbation technique, indicate phase-mixing and thus breaking of excited oscillations, and provide an expression for the phase-mixing time. It is shown that an increase in the strength of ambient magnetic field results in an increase in the phase-mixing time. The results of our investigation will be of relevance to astrophysical environments as well as laboratory experiments.

Maity, Chandan; Chakrabarti, Nikhil [Saha Institute of Nuclear Physics, 1/AF Bidhannagar, Kolkata 700 064 (India)] [Saha Institute of Nuclear Physics, 1/AF Bidhannagar, Kolkata 700 064 (India); Sengupta, Sudip [Institute for Plasma Research, Bhat, Gandhinagar 382 428 (India)] [Institute for Plasma Research, Bhat, Gandhinagar 382 428 (India)

2013-08-15T23:59:59.000Z

326

Atomic resolution electrostatic potential mapping of graphene sheets by off-axis electron holography  

SciTech Connect (OSTI)

Off-axis electron holography has been performed at atomic resolution with the microscope operated at 80?kV to provide electrostatic potential maps from single, double, and triple layer graphene. These electron holograms have been reconstructed in order to obtain information about atomically resolved and mean inner potentials. We propose that off-axis electron holography can now be used to measure the electrical properties in a range of two-dimensional semiconductor materials and three dimensional devices comprising stacked layers of films to provide important information about their electrical properties.

Cooper, David, E-mail: david.cooper@cea.fr [University Grenoble Alpes, F-38000 Grenoble (France); CEA, LETI, MINATEC Campus, F-38054, Grenoble (France); Pan, Cheng-Ta; Haigh, Sarah [School of Materials, The University of Manchester, Manchester M13 9PL (United Kingdom)

2014-06-21T23:59:59.000Z

327

Amperometric Glucose Biosensor by Means of Electrostatic Layer-by-layer Adsorption onto Electrospun Polyaniline Fibers  

E-Print Network [OSTI]

with glutaraldehyde, reactions to produce covalent bonding, entrapment by an electrostatic interaction and a sol-gel reaction. All of these methods have their own merits and demerits. Hence, many studies have been carried out to increase their individual merits.11-21.... J. Faraday Discuss Chem Soc 1989, 88, 317. 4. Cao, Y.; smith, P.; Heeger, A. J. Synth Met 1992, 48, 91. 5. Lange, U.; Roznyatovskaya, N. V.; Mirsky, V. M. Anal Chim Acta 2008, 614, 1. 6. Mi, H.; Zhang, X.; Yang, S.; Ye, X.; Luo, J. Mater. Chem...

Shin, Young J.

2010-07-14T23:59:59.000Z

328

EVALUATION OF MERCURY EMISSIONS FROM COAL-FIRED FACILITIES WITH SCR AND FGD SYSTEMS  

SciTech Connect (OSTI)

CONSOL Energy Inc., Research & Development (CONSOL), with support from the U.S. Department of Energy, National Energy Technology Laboratory (DOE) and the Electric Power Research Institute (EPRI), is evaluating the effects of selective catalytic reduction (SCR) on mercury (Hg) capture in coal-fired plants equipped with an electrostatic precipitator (ESP)--wet flue gas desulfurization (FGD) combination or a spray dryer absorber--fabric filter (SDA-FF) combination. In this program CONSOL is determining mercury speciation and removal at 10 coal-fired facilities. The objectives are (1) to evaluate the effect of SCR on mercury capture in the ESP-FGD and SDA-FF combinations at coal-fired power plants, (2) evaluate the effect of catalyst degradation on mercury capture; (3) evaluate the effect of low load operation on mercury capture in an SCR-FGD system, and (4) collect data that could provide the basis for fundamental scientific insights into the nature of mercury chemistry in flue gas, the catalytic effect of SCR systems on mercury speciation and the efficacy of different FGD technologies for mercury capture. This document, the seventh in a series of topical reports, describes the results and analysis of mercury sampling performed on a 1,300 MW unit burning a bituminous coal containing three percent sulfur. The unit was equipped with an ESP and a limestone-based wet FGD to control particulate and SO2 emissions, respectively. At the time of sampling an SCR was not installed on this unit. Four sampling tests were performed in September 2003. Flue gas mercury speciation and concentrations were determined at the ESP outlet (FGD inlet), and at the stack (FGD outlet) using the Ontario Hydro method. Process stream samples for a mercury balance were collected to coincide with the flue gas measurements. The results show that the FGD inlet flue gas oxidized:elemental mercury ratio was roughly 2:1, with 66% oxidized mercury and 34% elemental mercury. Mercury removal, on a coal-to-stack basis, was 53%. The average Hg concentration in the stack flue gas was 4.09 {micro}g/m{sup 3}. The average stack mercury emission was 3.47 Ib/TBtu. The mercury material balance closures ranged from 87% to 108%, with an average of 97%. A sampling program similar to this one was performed on a similar unit (at the same plant) that was equipped with an SCR for NOx control. Comparison of the results from the two units show that the SCR increases the percentage of mercury that is in the oxidized form, which, in turn, lends to more of the total mercury being removed in the wet scrubber. The principal purpose of this work is to develop a better understanding of the potential mercury removal ''co-benefits'' achieved by NOx, and SO{sub 2} control technologies. It is expected that this data will provide the basis for fundamental scientific insights into the nature of mercury chemistry in flue gas, the catalytic effect of SCR systems on mercury speciation and the efficacy of different FGD technologies for mercury capture. Ultimately, this insight could help to design and operate SCR and FGD systems to maximize mercury removal.

J.A. Withum; S.C. Tseng; J.E. Locke

2005-11-01T23:59:59.000Z

329

Evaluation of Mercury Emissions from Coal-Fired Facilities with SCR and FGD Systems  

SciTech Connect (OSTI)

CONSOL Energy Inc., Research & Development (CONSOL), with support from the U.S. Department of Energy, National Energy Technology Laboratory (DOE) and the Electric Power Research Institute (EPRI), is evaluating the effects of selective catalytic reduction (SCR) on mercury (Hg) capture in coal-fired plants equipped with an electrostatic precipitator (ESP)--wet flue gas desulfurization (FGD) combination or a spray dyer absorber--fabric filter (SDA-FF) combination. In this program CONSOL is determining mercury speciation and removal at 10 coal-fired facilities. The principal purpose of this work is to develop a better understanding of the potential mercury removal ''co-benefits'' achieved by NO{sub x}, and SO{sub 2} control technologies. It is expected that these data will provide the basis for fundamental scientific insights into the nature of mercury chemistry in flue gas, the catalytic effect of SCR systems on mercury speciation and the efficacy of different FGD technologies for mercury capture. Ultimately, this insight could help to design and operate SCR and FGD systems to maximize mercury removal. The objectives are (1) to evaluate the effect of SCR on mercury capture in the ESP-FGD and SDA-FF combinations at coal-fired power plants, (2) evaluate the effect of SCR catalyst degradation on mercury capture; (3) evaluate the effect of low load operation on mercury capture in an SCR-FGD system, and (4) collect data that could provide the basis for fundamental scientific insights into the nature of mercury chemistry in flue gas, the catalytic effect of SCR systems on mercury speciation and the efficacy of different FGD technologies for mercury capture. This document, the ninth in a series of topical reports, describes the results and analysis of mercury sampling performed on Unit 1 at Plant 7, a 566 MW unit burning a bituminous coal containing 3.6% sulfur. The unit is equipped with a SCR, ESP, and wet FGD to control NO{sub x}, particulate, and SO{sub 2} emissions, respectively. Four sampling tests were performed in August 2004 during ozone season with the SCR operating; flue gas mercury speciation and concentrations were determined at the SCR inlet, SCR outlet, air heater outlet (ESP inlet), ESP outlet (FGD inlet), and at the stack (FGD outlet) using the Ontario Hydro method. Three sampling tests were also performed in November 2004 during non-ozone season with the SCR bypassed; flue gas mercury speciation and concentrations were determined at the ESP outlet (FGD inlet), and at the stack (FGD outlet). Process samples for material balances were collected during the flue gas measurements. The results show that, at the point where the flue gas enters the FGD, a greater percentage of the mercury was in the oxidized form when the SCR was operating compared to when the SCR was bypassed (97% vs 91%). This higher level of oxidation resulted in higher mercury removals in the FGD because the FGD removed 90-94% of the oxidized mercury in both cases. Total coal-to-stack mercury removal was 86% with the SCR operating, and 73% with the SCR bypassed. The average mercury mass balance closure was 81% during the ozone season tests and 87% during the non-ozone season tests.

J. A. Withum; S. C. Tseng; J. E. Locke

2006-01-31T23:59:59.000Z

330

Evaluation of Mercury Emissions from Coal-Fired Facilities with SCR and FGD Systems  

SciTech Connect (OSTI)

CONSOL Energy Inc., Research & Development (CONSOL), with support from the U.S. Department of Energy, National Energy Technology Laboratory (DOE) and the Electric Power Research Institute (EPRI), is evaluating the effects of selective catalytic reduction (SCR) on mercury (Hg) capture in coal-fired plants equipped with an electrostatic precipitator (ESP)--wet flue gas desulfurization (FGD) combination or a spray dyer absorber--fabric filter (SDA-FF) combination. In this program CONSOL is determining mercury speciation and removal at 10 coal-fired facilities. The principal purpose of this work is to develop a better understanding of the potential mercury removal ''co-benefits'' achieved by NO{sub x}, and SO{sub 2} control technologies. It is expected that this data will provide the basis for fundamental scientific insights into the nature of mercury chemistry in flue gas, the catalytic effect of SCR systems on mercury speciation and the efficacy of different FGD technologies for mercury capture. Ultimately, this insight could help to design and operate SCR and FGD systems to maximize mercury removal. The objectives are (1) to evaluate the effect of SCR on mercury capture in the ESP-FGD and SDA-FF combinations at coal-fired power plants, (2) evaluate the effect of SCR catalyst degradation on mercury capture; (3) evaluate the effect of low load operation on mercury capture in an SCR-FGD system, and (4) collect data that could provide the basis for fundamental scientific insights into the nature of mercury chemistry in flue gas, the catalytic effect of SCR systems on mercury speciation and the efficacy of different FGD technologies for mercury capture. This document, the tenth in a series of topical reports, describes the results and analysis of mercury sampling performed on two 468 MW units burning bituminous coal containing 1.3-1.7% sulfur. Unit 2 is equipped with an SCR, ESP, and wet FGD to control NO{sub x}, particulate, and SO{sub 2} emissions, respectively. Unit 1 is similar to Unit 2, except that Unit 1 has no SCR for NOx control. Four sampling tests were performed on both units in January 2005; flue gas mercury speciation and concentrations were determined at the economizer outlet, air heater outlet (ESP inlet), ESP outlet (FGD inlet), and at the stack (FGD outlet) using the Ontario Hydro method. Process samples for material balances were collected with the flue gas measurements. The results show that the SCR increased the oxidation of the mercury at the air heater outlet. At the exit of the air heater, a greater percentage of the mercury was in the oxidized and particulate forms on the unit equipped with an SCR compared to the unit without an SCR (97.4% vs 91%). This higher level of oxidation resulted in higher mercury removals in the scrubber. Total mercury removal averaged 97% on the unit with the SCR, and 87% on the unit without the SCR. The average mercury mass balance closure was 84% on Unit 1 and 103% on Unit 2.

J. A. Withum; J. E. Locke

2006-02-01T23:59:59.000Z

331

Electrostatic mode associated with the pinch velocity in reversed field pinch simulations  

SciTech Connect (OSTI)

The existence of a new phenomenon in reversed field pinch (RFP) simulations related to the equilibrium pinch flow is discussed. This behavior is due to the inward equilibrium flow, but is strongly affected by boundary conditions on the perturbed azimuthal flow. It is important to understand and control this mechanism in single helicity simulations of RFPs. This mechanism can be explained in terms of an electrostatic instability related to a mode which can occur in fluid dynamics. In a simple linear model, it is shown that the mode, which is related to the inward advection of angular momentum from the edge, can be stabilized by using homogeneous Dirichlet (no-slip) boundary conditions at the wall. Behavior due to this mode is present in nonlinear simulations with zero-viscous-stress boundary conditions on the tangential velocity at the wall and, even in the presence of the usual magnetohydrodynamic modes, this mode can dominate the nonlinear dynamics of the velocity. In nonlinear simulations with Dirichlet boundary conditions on the tangential velocity, behavior associated with this electrostatic mode is not observed.

Delzanno, Gian Luca [Los Alamos National Laboratory (LANL); Chacon, Luis [Oak Ridge National Laboratory (ORNL); Finn, John M. [Los Alamos National Laboratory (LANL)

2008-01-01T23:59:59.000Z

332

Electrostatic mode associated with the pinch velocity in reversed field pinch simulations  

SciTech Connect (OSTI)

The existence of a new phenomenon in reversed field pinch (RFP) simulations related to the equilibrium pinch flow is discussed. This behavior is due to the inward equilibrium flow, but is strongly affected by boundary conditions on the perturbed azimuthal flow. It is important to understand and control this mechanism in single helicity simulations of RFPs. This mechanism can be explained in terms of an electrostatic instability related to a mode which can occur in fluid dynamics. In a simple linear model, it is shown that the mode, which is related to the inward advection of angular momentum from the edge, can be stabilized by using homogeneous Dirichlet (no-slip) boundary conditions at the wall. Behavior due to this mode is present in nonlinear simulations with zero-viscous-stress boundary conditions on the tangential velocity at the wall and, even in the presence of the usual magnetohydrodynamic modes, this mode can dominate the nonlinear dynamics of the velocity. In nonlinear simulations with Dirichlet boundary conditions on the tangential velocity, behavior associated with this electrostatic mode is not observed.

Delzanno, Gian Luca; Finn, John M. [T-15 Plasma Theory Group, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Chacon, Luis [T-15 Plasma Theory Group, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Fusion Energy Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37830 (United States)

2008-12-15T23:59:59.000Z

333

Differences in Electrostatic Potential Around DNA Fragments Containing Guanine and 8-oxo-Guanine  

SciTech Connect (OSTI)

hanges of electrostatic potential (EP) around the DNA molecule resulting from chemical modifications of nucleotides may play a role in enzymatic recognition of damaged sites. Effects of chemical modifications of nucleotides on the structure of DNA have been characterized through large scale density functional theory computations. Quantum mechanical structural optimizations of DNA fragments with three pairs of nucleotoides and accompanying counteractions were performed with a B3LYP exchange-correlation functional and 6-31G** basis sets. The “intact” DNA fragment contained guanine in the middle layer, while the “damaged” fragment had the guanine replaced with 8-oxo-guanine. The electrostatic potential around these DNA fragments was projected on a surface around the double helix. The 2D maps of EP of intact and damaged DNA fragments were analyzed to identify these modifications of EP that result from the occurrence of 8-oxo-guanine. It was found that distortions of the phosphate groups and displacements of the accompanying countercations are clearly reflected in the EP maps.

Haranczyk, Maciej; Gutowski, Maciej S.

2007-02-01T23:59:59.000Z

334

Load sensing system  

DOE Patents [OSTI]

A load sensing system inexpensively monitors the weight and temperature of stored nuclear material for long periods of time in widely variable environments. The system can include an electrostatic load cell that encodes weight and temperature into a digital signal which is sent to a remote monitor via a coaxial cable. The same cable is used to supply the load cell with power. When multiple load cells are used, vast

Sohns, Carl W. (Oak Ridge, TN); Nodine, Robert N. (Knoxville, TN); Wallace, Steven Allen (Knoxville, TN)

1999-01-01T23:59:59.000Z

335

Gas-solid transport in a 0. 0508 m pipe at various inclinations with and without electrostatics  

SciTech Connect (OSTI)

The transport of solid particles by air through a 0.0508 m pipe was studied in vertical, horizontal, and 45/sup 0/ orientations. Through control of the air humidity, the effects of electrostatic charging was observed. Pressure drop and particle velocities were measured. Particles used included 79 ..mu..m, 125 ..mu..m, and 450 ..mu..m glass beads and 128 ..mu..m Plexiglas beads. Analysis of particle velocity, pressure drop fluctuation, electrostatic pressure drop, choking and saltation was performed. Visual observations of the flow patterns and behavior were made. A linear stability analysis for the three orientations was performed.

Myler, C.A.; Zaltash, A.; Klinzing, G.E.

1985-01-01T23:59:59.000Z

336

Emergent behavior in particle-laden microfluidic systems informs strategies for improving cell and particle separations  

E-Print Network [OSTI]

Emergent behavior in particle-laden microfluidic systems informs strategies for improving cell quantitatively, especially in the confined environments typical of microfluidic devices. To better understand a simple microfluidic device in which hydrodynamic and electrostatic forces are leveraged to concentrate

Voldman, Joel

337

anaerobic digestion systems: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

for Korean food waste with high water contents (>80%). The hydrogen sulfide in the biogas was removed by a biological desulfurization equipment integrated in the horizontal...

338

anaerobic digestion system: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

for Korean food waste with high water contents (>80%). The hydrogen sulfide in the biogas was removed by a biological desulfurization equipment integrated in the horizontal...

339

How and why electrostatic charge of combustible nanoparticles can radically change the mechanism and rate of their oxidation in humid atmosphere  

E-Print Network [OSTI]

Electrostatically charged aerosol nanoparticles strongly attract surrounding polar gas molecules due to a charge-dipole interaction. In humid air, the substantial electrostatic attraction and acceleration of surrounding water vapour molecules towards charged combustible nanoparticles cause intense electrostatic hydration and preferential oxidation of these nanoparticles by accelerated water vapor molecules rather than non-polar oxygen molecules. In particular, electrostatic acceleration, acquired by surrounding water vapour molecules at a distance of their mean free path from the minimally charged iron metal nanoparticle can increase an oxidative activity of these polar molecules with respect to the nanoparticle by a factor of one million. Intense electrostatic hydration of charged metal nanoparticles converts the nanoparticle's oxide based shells into the hydroxide based electrolyte shells, transforming these nanoparticles into metal/air core-shell nanobatteries, periodically short-circuited by intra-particl...

Meshcheryakov, Oleg

2010-01-01T23:59:59.000Z

340

Performance results from the operation of an MgO-base FGD system  

SciTech Connect (OSTI)

An MgO-base wet FGD system was constructed and demonstrated with localized technology. The total capital cost is 40% lower than overseas price. This FGD system was developed for a 130 tons per hour steam, coal-fired cogeneration plant and has reached more than 95% of desulfurization without using any additive in the slurry absorbent. In order to meet the current SO{sub 2} emission control and the stringent regulation in, the future, a duct bypassing the FGD system was directly connected to stack to regulate the emission of mixed flue gas with and without desulfurization. The plume opacity is also improved. The nickel-base alloy sheet, INCO alloy C-276, was utilized in part as lining material at the intersections of mixing of cold and hot flows to enhance the local corrosion resistance. A process for preparing magnesium hydroxide slurry from magnesium oxide powder is also demonstrated. Performance results were obtained including SO{sub 2} removal efficiency, bypass flue gas mixing, liquid-to-gas ratio effect, scrubber pressure drop, and slurry pH effect.

Wu, S.R.; Hsu, H.W.; Uen, T.W. [Energy and Resources Labs., Hsinchu (Taiwan, Province of China)] [and others

1995-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "desulfurization systems electrostatic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

A particle-in-cell approach to obliquely propagating electrostatic waves  

SciTech Connect (OSTI)

The electron-acoustic and beam-driven modes associated with electron beams have previously been identified and studied numerically. These modes are associated with Broadband Electrostatic Noise found in the Earth's auroral and polar cusp regions. Using a 1-D spatial Particle-in-Cell simulation, the electron-acoustic instability is studied for a magnetized plasma, which includes cool ions, cool electrons and a hot, drifting electron beam. Both the weakly and strongly magnetized regimes with varying wave propagation angle, ?, with respect to the magnetic field are studied. The amplitude and frequency of the electron-acoustic mode are found to decrease with increasing ?. The amplitude of the electron-acoustic mode is found to significantly grow at intermediate wavenumber ranges. It reaches a saturation level at the point, where a plateau forms in the hot electron velocity distribution after which the amplitude of the electron-acoustic mode decays.

Koen, Etienne J. [Space Commercial Services Holdings (SCSH) Group, Somerset West (South Africa); School of Electrical Engineering, Royal Institute of Technology (KTH), Stockholm (Sweden); South African National Space Agency (SANSA), Space Science, Hermanus (South Africa); Collier, Andrew B. [University of KwaZulu-Natal, Durban (South Africa); Exegetic Analytics, Durban (South Africa); Maharaj, Shimul K. [South African National Space Agency (SANSA), Space Science, Hermanus (South Africa)

2014-09-15T23:59:59.000Z

342

Electrostatic-precipitator efficiency on a multiple-hearth incinerator burning sewage sludge  

SciTech Connect (OSTI)

A pilot-scale electrostatic precipitator (ESP) was evaluated for its removal performance of 23 metals and for sulfur-containing particles when fitted to a multiple hearth incinerator burning sewage sludge. The small-scale ESP was installed to take a slipstream of about 3% of the total incinerator emissions. Particle size fractions were collected from the gas streams entering and leaving the ESP. Each particle was evaluated for overall removal efficiency, size-fraction removal efficiency, and selective removal of specific metals. Total concentrations of each element in the controlled emission stream was determined as well as the proportionate concentration of species in the solid and volatile states. Concentrations of each metal in the emission stream were compared with the concentration in the sludge residue. To obtain comparisons of ESP performance with a more typical emission-control device, the performance of the incinerator's full-scale wet scrubber was also evaluated.

Adams, R.C.; Bockol, G.; Maddox, J.A.; Robb, E.V.

1987-09-01T23:59:59.000Z

343

Electrostatic precipitation of condensed acid mist: Third quarterly technical progress report, March 1--May 31, 1989  

SciTech Connect (OSTI)

Acid mists can sometimes constitute a significant portion of the total particulate emissions from power plants burning high-sulfur coals. A wet electrostatic precipitator (WESP) is the best control option for acid mist. The mist would blind a fabric filter and attack glass fiber fabrics. A wet ESP is required because the acid would quickly corrode the plates in a conventional dry ESP. The wet ESP also offers the advantages of no rapping reentrainment and no sensitivity to fly ash resistivity. The project is organized in two phases. Phase I, which is scheduled for September 1988 to September 1989, involves the WESP fabrication, laboratory and pilot combustor testing, and computer modeling. Phase II, which is scheduled for September 1989 to September 1990, involves the solicitation of a utility demonstration site, preliminary site measurements, and planning for the demonstration test program. Progress on Phase I work is addressed in this discussion. 5 refs., 4 figs.

Not Available

1989-01-01T23:59:59.000Z

344

Study on space charge effect in an electrostatic ion analyzer applied to measure laser produced ions  

SciTech Connect (OSTI)

The abundance of different ions produced by laser ion sources is usually analyzed by an electrostatic ion analyzer (EIA). Ion current intensities in the range of several mA/cm{sup 2} at the position of the EIA have been achieved from the laser ion source developed by the Institute of Modern Physics; this indicates that a noticeable influence of space charge effect during the ion transmission will occur. Hence, while the parameters of the EIA or the beams are changed, such as ion species, current intensity, the ions’ transmission efficiency through the EIA is different, which will result in an uncertainty in the estimation of the ions’ yields. Special attention is focused on this issue in this paper. Ion's transmissions through the EIA under different circumstances are studied with simulations and experiments, the results of which are consistent with each other.

Jin, Q. Y.; Li, Zh. M.; Liu, W. [Institute of Modern Physics, Chinese Academy of Sciences, Lanzhou 730000 (China) [Institute of Modern Physics, Chinese Academy of Sciences, Lanzhou 730000 (China); University of Chinese Academy of Sciences, Beijing 100049 (China); Zhao, H. Y., E-mail: zhaohy@impcas.ac.cn; Sha, S.; Zhang, J. J.; Zhang, X. Zh.; Sun, L. T.; Zhao, H. W. [Institute of Modern Physics, Chinese Academy of Sciences, Lanzhou 730000 (China)] [Institute of Modern Physics, Chinese Academy of Sciences, Lanzhou 730000 (China)

2014-03-15T23:59:59.000Z

345

Spherical ion oscillations in a positive polarity gridded inertial-electrostatic confinement device  

SciTech Connect (OSTI)

A pulsed, positive polarity gridded inertial electrostatic confinement device has been investigated experimentally, using a differential emissive probe and potential traces as primary diagnostics. Large amplitude oscillations in the plasma current and plasma potential were observed within a microsecond of the discharge onset, which are indicative of coherent ion oscillations about a temporarily confined excess of recirculating electron space charge. The magnitude of the depth of the potential well in the established virtual cathode was determined using a differential emissive Langmuir probe, which correlated well to the potential well inferred from the ion oscillation frequency for both hydrogen and argon experiments. It was found that the timescale for ion oscillation dispersion is strongly dependent on the neutral gas density, and weakly dependent on the peak anode voltage. The cessation of the oscillations was found to be due to charge exchange processes converting ions to high velocity neutrals, causing the abrupt de-coherence of the oscillations through an avalanche dispersion in phase space.

Bandara, R.; Khachan, J. [Plasma Physics, School of Physics, University of Sydney, Camperdown, New South Wales 2006 (Australia)] [Plasma Physics, School of Physics, University of Sydney, Camperdown, New South Wales 2006 (Australia)

2013-07-15T23:59:59.000Z

346

Electrostatic potential variation on the flux surface and its impact on impurity transport  

E-Print Network [OSTI]

The particle transport of impurities in magnetically confined plasmas under some conditions does not find, neither quantitatively nor qualitatively, a satisfactory theory-based explanation. This compromise the successful realization of thermo-nuclear fusion for energy production since its accumulation is known to be one of the causes that leads to the plasma breakdown. In standard reactor-relevant conditions this accumulation is in most stellarators intrinsic to the lack of toroidal symmetry, that leads to the neoclassical electric field to point radially inwards. This statement, that the standard theory allows to formulate, has been contradicted by some experiments that showed weaker or no accumulation under such conditions \\cite{Ida_pop_16_056111_2009, Yoshinuma_nf_49_062002_2009}. The charge state of the impurities makes its transport more sensitive to the electric fields. Thus, the short length scale turbulent electrostatic potential or its long wave-length variation on the flux surface $\\Phi_{1}$ -- that...

García-Regaña, J M; Turkin, Y; Kleiber, R; Helander, P; Maaßberg, H; Alonso, J A; Velasco, J L

2015-01-01T23:59:59.000Z

347

Head-on collisions of electrostatic solitons in multi-ion plasmas  

SciTech Connect (OSTI)

Head-on collisions between two electrostatic solitons are dealt with by the Poincare-Lighthill-Kuo method of strained coordinates, for a plasma composed of a number of cold (positive and negative) ion species and Boltzmann electrons. The nonlinear evolution equations for both solitons and their phase shift due to the collision, resulting in time delays, are established. A Korteweg-de Vries description is the generic conclusion, except when the plasma composition is special enough to replace the quadratic by a cubic nonlinearity in the evolution equations, with concomitant repercussions on the phase shifts. Applications include different two-ion plasmas, showing positive or negative polarity solitons in the generic case. At critical composition, a combination of a positive and a negative polarity soliton is possible.

Verheest, Frank [Sterrenkundig Observatorium, Universiteit Gent, Krijgslaan 281, B-9000 Gent (Belgium); School of Chemistry and Physics, University of KwaZulu-Natal, Durban 4000 (South Africa); Hellberg, Manfred A. [School of Chemistry and Physics, University of KwaZulu-Natal, Durban 4000 (South Africa); Hereman, Willy A. [Department of Applied Mathematics and Statistics, Colorado School of Mines, Golden, Colorado 80401-1887 (United States)

2012-09-15T23:59:59.000Z

348

Modulational instability of electrostatic acoustic waves in an electron-hole semiconductor quantum plasma  

SciTech Connect (OSTI)

The modulational instability of quantum electrostatic acoustic waves in electron-hole quantum semiconductor plasmas is investigated using the quantum hydrodynamic model, from which a modified nonlinear Schrödinger equation with damping effects is derived using the reductive perturbation method. Here, we consider the combined effects of quantum recoil, quantum degenerate pressures, as well as the exchange-correlation effect standing for the electrons (holes) spin. The modulational instability for different semiconductors (GaAs, GaSb, and InP) is discussed. The collision between electron (hole) and phonon is also investigated. The permitted maximum time for modulational instability and the damping features of quantum envelope solitary wave are all determined by the collision. The approximate solitary solution with damping effects is presented in weak collision limit. The damping properties were discussed by numerical method.

Wang, Yunliang, E-mail: ylwang@ustb.edu.cn; Lü, Xiaoxia [Department of Physics, School of Mathematics and Physics, University of Science and Technology Beijing, Beijing 100083 (China)] [Department of Physics, School of Mathematics and Physics, University of Science and Technology Beijing, Beijing 100083 (China)

2014-02-15T23:59:59.000Z

349

Design and validation of a high-voltage levitation circuit for electrostatic accelerometers  

SciTech Connect (OSTI)

A simple high-voltage circuit with a voltage range of 0 to 900 V and an open-loop bandwidth of 11 kHz is realized by using an operational amplifier and a MOSFET combination. The circuit is used for the levitation of a test mass of 71 g, suspended below the top-electrodes with a gap distance of 57 ?m, so that the performance of an electrostatic accelerometer can be tested on the ground. The translation noise of the accelerometer, limited by seismic noise, is about 4 × 10{sup ?8} m/s{sup 2}/Hz{sup 1/2} at 0.1 Hz, while the high-voltage coupling noise is one-order of magnitude lower.

Li, G.; Wu, S. C.; Zhou, Z. B.; Bai, Y. Z.; Hu, M.; Luo, J. [MOE Key Laboratory of Fundamental Physical Quantities Measurements, School of Physics, Huazhong University of Science and Technology, Wuhan, Hubei 430074 (China)] [MOE Key Laboratory of Fundamental Physical Quantities Measurements, School of Physics, Huazhong University of Science and Technology, Wuhan, Hubei 430074 (China)

2013-12-15T23:59:59.000Z

350

High efficiency photodetectors fabricated by electrostatic layer-by-layer self-assembly of CdTe quantum dots  

E-Print Network [OSTI]

High efficiency photodetectors fabricated by electrostatic layer-by-layer self-assembly of CdTe 20 October 2008 We demonstrate high-performance photodetectors from multilayers of CdTe quantum dots. The synthesis of CdTe QDs in aqueous solution using cadmium perchlorate hydrate and Al2Te3 was previously re

Lin, Lih Y.

351

Upgrade of the MIT Linear Electrostatic Ion Accelerator (LEIA) for nuclear diagnostics development for Omega, Z and the NIF  

E-Print Network [OSTI]

Accelerator (LEIA) generates DD and D3 He fusion products for the development of nuclear diagnostics for OmegaUpgrade of the MIT Linear Electrostatic Ion Accelerator (LEIA) for nuclear diagnostics development Graaff accelerator terminal Rev. Sci. Instrum. 83, 02A340 (2012) Status of ion sources at National

352

Excitation and propagation of Electrostatic Ion Cyclotron waves in rf-sustained plasmas of interest to propulsion research  

E-Print Network [OSTI]

it is thus necessary to heat these ions considerably. Various types of electrodeless plasma heating provideExcitation and propagation of Electrostatic Ion Cyclotron waves in rf-sustained plasmas of interest to propulsion research Rostislav Spektor and Edgar Y. Choueiri Electric Propulsion and Plasma Dynamics

Choueiri, Edgar

353

Type of presentation: Oral IT-11-O-1669 Electrostatic potential of single-layer graphene measured using  

E-Print Network [OSTI]

Type of presentation: Oral IT-11-O-1669 Electrostatic potential of single-layer graphene measured, University of Limerick, Ireland 3 Email of the presenting author: shery.chang@fz-juelich.de Graphene devices, energy storage, and electrocatalysis [2]. Characterisation of graphene imposes a requirement

Dunin-Borkowski, Rafal E.

354

Droplet Dynamics Changes in Electrostatic Sprays of Methanol-Water Mixtures Zohra Olumee, John H. Callahan, and Akos Vertes*,  

E-Print Network [OSTI]

conductivity, dielectric constant, surface tension, viscosity, and density) and on the spraying conditionsDroplet Dynamics Changes in Electrostatic Sprays of Methanol-Water Mixtures Zohra Olumee, John H generated from methanol-water mixtures. We investigated spraying conditions close to those of electrospray

Vertes, Akos

355

Multi-dimensional modelling of electrostatic force distance curve over dielectric surface: Influence of tip geometry and correlation with experiment  

SciTech Connect (OSTI)

Electric Force-Distance Curves (EFDC) is one of the ways whereby electrical charges trapped at the surface of dielectric materials can be probed. To reach a quantitative analysis of stored charge quantities, measurements using an Atomic Force Microscope (AFM) must go with an appropriate simulation of electrostatic forces at play in the method. This is the objective of this work, where simulation results for the electrostatic force between an AFM sensor and the dielectric surface are presented for different bias voltages on the tip. The aim is to analyse force-distance curves modification induced by electrostatic charges. The sensor is composed by a cantilever supporting a pyramidal tip terminated by a spherical apex. The contribution to force from cantilever is neglected here. A model of force curve has been developed using the Finite Volume Method. The scheme is based on the Polynomial Reconstruction Operator—PRO-scheme. First results of the computation of electrostatic force for different tip–sample distances (from 0 to 600?nm) and for different DC voltages applied to the tip (6 to 20?V) are shown and compared with experimental data in order to validate our approach.

Boularas, A., E-mail: boularas@laplace.univ-tlse.fr; Baudoin, F.; Villeneuve-Faure, C. [LAPLACE (Laboratoire Plasma et Conversion d'Energie), Université de Toulouse, UPS, INPT, 118 route de Narbonne, 31062 Toulouse cedex 9 (France); Clain, S. [Universidade do Minho, Centro de Matemática, Campus de Gualtar, 4710 - 057 Braga (Portugal); Université Paul Sabatier, Institut de Mathématiques de Toulouse, 31062 Toulouse (France); Teyssedre, G. [LAPLACE (Laboratoire Plasma et Conversion d'Energie), Université de Toulouse, UPS, INPT, 118 route de Narbonne, 31062 Toulouse cedex 9 (France); CNRS, LAPLACE, F-31071 Toulouse (France)

2014-08-28T23:59:59.000Z

356

EVALUATION OF MERCURY EMISSIONS FROM COAL-FIRED FACILITIES WITH SCR AND FGD SYSTEMS  

SciTech Connect (OSTI)

CONSOL Energy Inc., Research & Development (CONSOL), with support from the U.S. Department of Energy, National Energy Technology Laboratory (DOE) and the Electric Power Research Institute (EPRI), evaluated the effects of selective catalytic reduction (SCR) on mercury (Hg) capture in coal-fired plants equipped with an electrostatic precipitator (ESP)-wet flue gas desulfurization (FGD) combination or a spray dyer absorber-fabric filter (SDA-FF) combination. In this program CONSOL determined mercury speciation and removal at 10 bituminous coal-fired facilities; at four of these facilities, additional tests were performed on units without SCR, or with the existing SCR bypassed. This project final report summarizes the results and discusses the findings of the body of work as a whole. Eleven Topical Reports were issued (prior to this report) that describe in great detail the sampling results at each of the ten power plants individually. The results showed that the SCR-FGD combination removed a substantial fraction of mercury from flue gas. The coal-to-stack mercury removals ranged from 65% to 97% for the units with SCR and from 53% to 87% for the units without SCR. There was no indication that any type of FGD system was more effective at mercury removal than others. The coal-to-stack mercury removal and the removal in the wet scrubber were both negatively correlated with the elemental mercury content of the flue gas and positively correlated with the scrubber liquid chloride concentration. The coal chlorine content was not a statistically significant factor in either case. Mercury removal in the ESP was positively correlated with the fly ash carbon content and negatively correlated with the flue gas temperature. At most of the units, a substantial fraction (>35%) of the flue gas mercury was in the elemental form at the boiler economizer outlet. After passing through the SCR-air heater combination very little of the total mercury (<10%) remained in the elemental form in the flue gas; this was true for all SCR catalyst types and sources. Although chlorine has been suggested as a factor affecting the mercury speciation in flue gas, coal chlorine was not a statistically significant factor affecting mercury speciation at the economizer exit or at the air heater exit. The only statistically significant factors were the coal ash CaO content and the fly ash carbon content; the fraction of mercury in the elemental form at the economizer exit was positively correlated with both factors. In a direct comparison at four SCR-equipped units vs. similar units at the same sites without SCR (or with the SCR bypassed), the elemental mercury fractions (measured at the ESP outlet) were lower, and the coal-to-stack mercury removals were higher, when the SCR was present and operating. The average coal-to-stack mercury removal at the four units without an operating SCR was 72%, whereas the average removal at the same sites with operating SCRs was 88%. The unit mercury mass balance (a gauge of the overall quality of the tests) at all of the units ranged from 81% to 113%, which were within our QA/QC criterion of 80-120%.

J.A. Withum

2006-03-07T23:59:59.000Z

357

Exact evaluation of the rates of electrostatic decay and scattering off thermal ions for an unmagnetized Maxwellian plasma  

SciTech Connect (OSTI)

Electrostatic decay of Langmuir waves into Langmuir and ion sound waves (L?L?+S) and scattering of Langmuir waves off thermal ions (L+i?L?+i?, also called “nonlinear Landau damping”) are important nonlinear weak-turbulence processes. The rates for these processes depend on the quadratic longitudinal response function ?{sup (2)} (or, equivalently, the quadratic longitudinal susceptibility ?{sup (2)}), which describes the second-order response of a plasma to electrostatic wave fields. Previous calculations of these rates for an unmagnetized Maxwellian plasma have relied upon an approximate form for ?{sup (2)} that is valid where two of the wave fields are fast (i.e., v{sub ?}=?/k?V{sub e} where ? is the angular frequency, k is the wavenumber, and V{sub e} is the electron thermal speed) and one is slow (v{sub ?}?V{sub e}). Recently, an exact expression was derived for ?{sup (2)} that is valid for any phase speeds of the three waves in an unmagnetized Maxwellian plasma. Here, this exact ?{sup (2)} is applied to the calculation of the three-dimensional rates for electrostatic decay and scattering off thermal ions, and the resulting exact rates are compared with the approximate rates. The calculations are performed using previously derived three-dimensional rates for electrostatic decay given in terms of a general ?{sup (2)}, and newly derived three-dimensional rates for scattering off thermal ions; the scattering rate is derived assuming a Maxwellian ion distribution, and both rates are derived assuming arc distributions for the wave spectra. For most space plasma conditions, the approximate rate is found to be accurate to better than 20%; however, for sufficiently low Langmuir phase speeds (v{sub ?}/V{sub e}?3) appropriate to some spatial domains of the foreshock regions of planetary bow shocks and type II solar radio bursts, the use of the exact rate may be necessary for accurate calculations. The relative rates of electrostatic decay and scattering off thermal ions are calculated for a range of parameters using the exact expressions for the rates; electrostatic decay is found to have the larger growth rate over the whole range of parameters, consistent with previous approximate calculations.

Layden, B.; Cairns, Iver H.; Robinson, P. A. [School of Physics, University of Sydney, Sydney, NSW 2006 (Australia)] [School of Physics, University of Sydney, Sydney, NSW 2006 (Australia)

2013-08-15T23:59:59.000Z

358

An electrostatic nanogenerator based on ZnO/ZnS core/shell electrets with stabilized quasi-permanent charge  

SciTech Connect (OSTI)

ZnO-based nanogenerators with excellent performance and convenient functionalization are particularly desirable for self-powered technology, which is however difficult to achieve simultaneously in traditional piezoelectric ZnO nanogenerators. Here, we report a design of electrostatic ZnO nanogenerator by virtue of a type-II ZnO/ZnS core/shell nanostructure electrets, which can turn acoustic waves into electric power with an energy conversion efficiency of 2.2%. The ZnO/ZnS core/shell electrets are charged by ultraviolet irradiation with a long-term stability of the electrostatic charges under ambient condition. The electronic and atomic structure evolution in the charged ZnO/ZnS core/shell electrets are also discussed by detailed experimental and theoretical investigations. This design opens up an alternative path for fabricating robust ZnO-based nanogenerator for future nanotechnology application.

Wang, Chao; Cai, Liang; Feng, Yajuan; Chen, Lin; Yan, Wensheng, E-mail: ywsh2000@ustc.edu.cn, E-mail: zhsun@ustc.edu.cn; Liu, Qinghua; Yao, Tao; Hu, Fengchun; Pan, Zhiyun; Sun, Zhihu, E-mail: ywsh2000@ustc.edu.cn, E-mail: zhsun@ustc.edu.cn; Wei, Shiqiang [National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei, Anhui 230029 (China)

2014-06-16T23:59:59.000Z

359

Measurements of the Casimir-Lifshitz force in fluids: the effect of electrostatic forces and Debye screening  

E-Print Network [OSTI]

In this work, we present detailed measurements of the Casimir-Lifshitz force between two gold surfaces (a sphere and a plate) immersed in ethanol and study the effect of residual electrostatic forces, which are dominated by static fields within the apparatus and can be reduced with proper shielding. Electrostatic forces are further reduced by Debye screening through the addition of salt ions to the liquid. Additionally, the salt leads to a reduction of the Casimir-Lifshitz force by screening the zero-frequency contribution to the force; however, the effect is small between gold surfaces at the measured separations and within experimental error. An improved calibration procedure is described and compared to previous methods. Finally, the experimental results are compared to Lifshitz's theory and found to be consistent for the materials used in the experiment.

J. N. Munday; Federico Capasso; V. Adrian Parsegian; Sergey M. Bezrukov

2008-08-13T23:59:59.000Z

360

Nonlinear Modulated Envelope Electrostatic Wavepacket Propagation in Space and Laboratory Plasmas  

SciTech Connect (OSTI)

A brief review of the occurrence of amplitude modulated structures in space and laboratory plasmas is provided, followed by a theoretical analysis of the mechanism of carrier wave (self-) interaction, with respect to electrostatic plasma modes. A generic collisionless unmagnetized fluid model is employed. Both cold-(zero-temperature) and warm-(finite temperature) fluid descriptions are considered and compared. The weakly nonlinear oscillation regime is investigated by applying a multiple scale (reductive perturbation) technique and a Nonlinear Schroedinger Equation (NLSE) is obtained, describing the evolution of the slowly varying wave amplitude in time and space. The amplitude's stability profile reveals the possibility of modulational instability to occur under the influence of external perturbations. The NLSE admits exact localized envelope (solitary wave) solutions of bright (pulses) or dark (holes, voids) type, whose characteristics depend on intrinsic plasma parameters. The role of perturbation obliqueness (with respect to the propagation direction), finite temperature and -- possibly -- defect (dust) concentration is explicitly considered. The relevance of this description with respect to known electron-ion (e-i) as well as dusty (complex) plasma modes is briefly discussed.

Kourakis, Ioannis; Shukla, Padma Kant [Institut fuer Theoretische Physik IV, Fakultaet fuer Physik und Astronomie, Ruhr-Universitaet Bochum, D-44780 Bochum (Germany)

2004-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "desulfurization systems electrostatic" from the National Library of EnergyBeta (NLEBeta).
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361

Survey and evaluation of modern electrostatic concepts applied to high-resistivity fly ash  

SciTech Connect (OSTI)

The ineffectiveness of conventional electrostatic precipitators on high resistivity fly ash has different, though interrelated, causes. Voltages high enough to generate corona at the discharge electrode also generate back corona on the deposited dust layer. Removal of the layer results in reentrainment losses. Reduction of voltage to suppress back corona reduces precipitation effectiveness. All of the surveyed concepts attempt to deal with one or more of these problems; most but none will address all of the deficiencies. A versatile multiple-concept pilot precipitator would allow GFETC to develop the optimum combination of novel concepts. Acurex is recommending a precipitator with component interchangeability in three sections: (1) the main precipitator section (one or more cells) should be designed to accept either conventional electrodes or a few tri-electrode configurations. Versatile pulse-charged power supplies will be needed to accommodate the various electrode configurations. The best method of suppressing back-corona in the precipitator itself can thus be developed; (2) a precharger section should be installed ahead of the main precipitator to optimize precharger design; and (3) a downstream collector section would test the effectiveness of concepts which lend themselves to effective collection of low-load, high-resistivity, small particles. These include wet precipitators, fabric filters, and bed filters. The separation of functions will allow more effective particle charging in the first section, collection of most of the particulate without reverse ionization in the main section, and polishing of the remaining fine and reentrained particulate in a suitable downstream collector.

Not Available

1980-12-01T23:59:59.000Z

362

A comb-sampling method for enhanced mass analysis in linear electrostatic ion traps  

SciTech Connect (OSTI)

In this paper an algorithm for extracting spectral information from signals containing a series of narrow periodic impulses is presented. Such signals can typically be acquired by pickup detectors from the image-charge of ion bunches oscillating in a linear electrostatic ion trap, where frequency analysis provides a scheme for high-resolution mass spectrometry. To provide an improved technique for such frequency analysis, we introduce the CHIMERA algorithm (Comb-sampling for High-resolution IMpulse-train frequency ExtRAaction). This algorithm utilizes a comb function to generate frequency coefficients, rather than using sinusoids via a Fourier transform, since the comb provides a superior match to the data. This new technique is developed theoretically, applied to synthetic data, and then used to perform high resolution mass spectrometry on real data from an ion trap. If the ions are generated at a localized point in time and space, and the data is simultaneously acquired with multiple pickup rings, the method is shown to be a significant improvement on Fourier analysis. The mass spectra generated typically have an order of magnitude higher resolution compared with that obtained from fundamental Fourier frequencies, and are absent of large contributions from harmonic frequency components.

Greenwood, J. B.; Kelly, O.; Calvert, C. R.; Duffy, M. J.; King, R. B.; Belshaw, L.; Graham, L.; Alexander, J. D.; Williams, I. D. [Centre for Plasma Physics, School of Mathematics and Physics, Queen's University Belfast, Belfast BT7 1NN (United Kingdom); Bryan, W. A. [Department of Physics, Swansea University, Swansea SA2 8PP (United Kingdom); Turcu, I. C. E.; Cacho, C. M.; Springate, E. [Central Laser Facility, STFC Rutherford Appleton Laboratory, Didcot, Oxfordshire OX11 0QX (United Kingdom)

2011-04-15T23:59:59.000Z

363

Influence of pH condition on colloidal suspension of exfoliated graphene oxide by electrostatic repulsion  

SciTech Connect (OSTI)

A facile chemical process is described to produce graphene oxide utilizing a zwitterions amino acid intermediate from graphite oxide sheets. 11-aminoundecanoic acid molecules were protonated to intercalate molecules into the graphite oxide sheets to achieve ion exchange, and the carboxyl groups were then ionized in a NaOH solution to exfoliate the graphite oxide sheets. In this way, the produced graphene oxide nanosheets were stably dispersed in water. The delaminated graphene nanosheets were confirmed by XRD, AFM, and TEM. XRD patterns indicated the d{sub 002}-spacing of the graphite greatly increased from 0.380 nm and 0.870 nm. AFM and TEM images showed that the ordered graphite crystal structure of graphene nanosheets was effectively exfoliated by this method. The prepared graphene nanosheets films showed 87.1% transmittance and a sheet resistance of 2.1 Multiplication-Sign 10{sup 3} {Omega}/square. - Graphical abstract: A stable graphene oxide suspension could be quickly prepared by exfoliating a graphite oxide suspension by a host-guest electrostatic repulsion in aqueous solution. Highlights: Black-Right-Pointing-Pointer Graphene nanosheets were prepared by a zwitterions amino acid intermediate from graphite oxide. Black-Right-Pointing-Pointer 11-aminoundecanoic acid was protonated to intercalate molecules into the graphene oxide to achieve ion exchange. Black-Right-Pointing-Pointer The d{sub 002}-spacing of the graphite oxide greatly increased from 0.330 nm to 0.415 nm after 11-aminoundecanoic acid treatment.

Meng, Long-Yue [Department of Chemistry, Inha University, 253 Nam-gu, Incheon 402-751 (Korea, Republic of); Park, Soo-Jin, E-mail: sjpark@inha.ac.kr [Department of Chemistry, Inha University, 253 Nam-gu, Incheon 402-751 (Korea, Republic of)

2012-02-15T23:59:59.000Z

364

Electrostatic wave structures in a magnetized superthermal plasma with two-temperature electrons  

SciTech Connect (OSTI)

The linear and nonlinear excitation of arbitrary amplitude ion-acoustic (IA) solitary waves in a magnetized plasma comprising two-temperature electrons and cold ions are studied. The oblique propagation properties of two possible modes (in the linear regime) are investigated. It is found that the electron superthermality reduces the phase velocities of both modes, whereas obliqueness leads to an increase in the separation between two modes. In the nonlinear regime, an energy-like equation describes the evolution of IA solitary waves in the present model. The combined effects of the electron superthermality, magnitude of magnetic field, obliqueness and electron population are incorporated in the study of the existence domain of solitary waves and the soliton characteristics. It is shown that the small values of the hot electron population shift the permitted interval of Mach number to the lower values. Both compressive and rarefactive solitary structures are found to exist in the presence of two temperature electrons. The present investigation contributes to the physics of electrostatic wave structures in Saturn's magnetosphere in which two temperature electrons with kappa distribution exist.

Shahmansouri, M. [Department of Physics, Faculty of Science, Arak University, Arak 38156- 8 8349 (Iran, Islamic Republic of)] [Department of Physics, Faculty of Science, Arak University, Arak 38156- 8 8349 (Iran, Islamic Republic of); Alinejad, H. [Department of Physics, Faculty of Basic Science, Babol University of Technology, Babol 47148-71167 (Iran, Islamic Republic of)] [Department of Physics, Faculty of Basic Science, Babol University of Technology, Babol 47148-71167 (Iran, Islamic Republic of)

2013-08-15T23:59:59.000Z

365

Electrostatics on the sphere with applications to Monte Carlo simulations of two dimensional polar fluids  

E-Print Network [OSTI]

We present two methods for solving the electrostatics of point charges and multipoles on the surface of a sphere, \\textit{i.e.} in the space $\\mathcal{S}_{2}$, with applications to numerical simulations of two-dimensional polar fluids. In the first approach, point charges are associated with uniform neutralizing backgrounds to form neutral pseudo-charges, while, in the second, one instead considers bi-charges, \\textit{i.e.} dumbells of antipodal point charges of opposite signs. We establish the expressions of the electric potentials of pseudo- and bi-charges as isotropic solutions of the Laplace-Beltrami equation in $\\mathcal{S}_{2}$. A multipolar expansion of pseudo- and bi-charge potentials leads to the electric potentials of mono- and bi-multipoles respectively. These potentials constitute non-isotropic solutions of the Laplace-Beltrami equation the general solution of which in spherical coordinates is recast under a new appealing form. We then focus on the case of mono- and bi-dipoles and build the theory...

Caillol, Jean-Michel

2015-01-01T23:59:59.000Z

366

Gyrokinetic theory of electrostatic lower-hybrid drift instabilities in a current sheet with guide field  

SciTech Connect (OSTI)

A kinetic electrostatic eigenvalue equation for the lower-hybrid drift instability (LHDI) in a thin Harris current sheet with a guide field is derived based on the gyrokinetic electron and fully kinetic ion(GeFi) description. Three-dimensional nonlocal analyses are carried out to investigate the influence of a guide field on the stabilization of the LHDI by finite parallel wavenumber, k{sub ?}. Detailed stability properties are first analyzed locally, and then as a nonlocal eigenvalue problem. Our results indicate that at large equilibrium drift velocities, the LHDI is further destabilized by finite k{sub ?} in the short-wavelength domain. This is demonstrated in a local stability analysis and confirmed by the peak in the eigenfunction amplitude. We find the most unstable modes localized at the current sheet edges, and our results agree well with simulations employing the GeFi code developed by Lin et al. [Plasma Phys. Controlled Fusion 47, 657 (2005); Plasma Phys. Controlled Fusion 53, 054013 (2011)].

Tummel, K., E-mail: tummel08@gmail.com [Department of Physics and Astronomy, University of California at Irvine, Irvine, California 92697 (United States); Chen, L. [Institute for Fusion Theory and Simulation and Department of Physics, ZheJiang University, Hang Zhou, ZheJiang 310058 (China) [Institute for Fusion Theory and Simulation and Department of Physics, ZheJiang University, Hang Zhou, ZheJiang 310058 (China); Department of Physics and Astronomy, University of California at Irvine, Irvine, California 92697 (United States); Wang, Z.; Wang, X. Y.; Lin, Y. [Department of Physics, Auburn University, Auburn, Alabama 36849 (United States)] [Department of Physics, Auburn University, Auburn, Alabama 36849 (United States)

2014-05-15T23:59:59.000Z

367

Filter systems for IGCC applications  

SciTech Connect (OSTI)

The objectives of this program were to identify metallic filter medium to be utilized in the Integrated Gasification Combined Cycle process (IGCC). In IGCC processes utilizing high efficiency desulfurizing technology, the traditional corrosion attack, sulfidation, is minimized so that metallic filters are viable alternatives over ceramic filters. Tampa Electric Company`s Polk Power Station is being developed to demonstrate Integrated Gasification Combined Cycle technology. The Pall Gas Solid Separation (GSS) System is a self cleaning filtration system designed to remove virtually all particulate matter from gas streams. The heart of the system is the filter medium used to collect the particles on the filter surface. The medium`s filtration efficiency, uniformity, permeability, voids volume, and surface characteristics are all important to establishing a permeable permanent cake. In-house laboratory blowback tests, using representative full scale system particulate, were used to confirm the medium selection for this project. Test elements constructed from six alloys were supplied for exposure tests: PSS 310SC (modified 310S alloy); PSS 310SC heat treated; PSS 310SC-high Cr; PSS 310SC-high Cr heat treated; PSS Hastelloy X; and PSS Hastelloy X heat treated.

Bevan, S.; Gieger, R.; Sobel, N.; Johnson, D.

1995-11-01T23:59:59.000Z

368

Excitation of electrostatic waves in the electron cyclotron frequency range during magnetic reconnection in laboratory overdense plasmas  

SciTech Connect (OSTI)

We report the observation of electromagnetic radiation at high harmonics of the electron cyclotron frequency that was considered to be converted from electrostatic waves called electron Bernstein waves (EBWs) during magnetic reconnection in laboratory overdense plasmas. The excitation of EBWs was attributed to the thermalization of electrons accelerated by the reconnection electric field around the X-point. The radiative process discussed here is an acceptable explanation for observed radio waves pulsation associated with major flares.

Kuwahata, A., E-mail: kuwahata@ts.t.u-tokyo.ac.jp [Graduate School of Engineering, The University of Tokyo, Tokyo 113-8656 (Japan); Igami, H. [National Institute for Fusion Science, Toki 509-5292 (Japan); Kawamori, E. [Institute of Space and Plasma Sciences, National Cheng Kung University, Tainan 70101, Taiwan (China); Kogi, Y. [Fukuoka Institute of Technology, Fukuoka 811-0295 (Japan); Inomoto, M.; Ono, Y. [Graduate School of Frontier Sciences, The University of Tokyo, Kashiwa 277-8561 (Japan)

2014-10-15T23:59:59.000Z

369

Comment on {open_quote}{open_quote}Optimization of electrostatic deflectors{close_quote}{close_quote} [J. Vac. Sci. Technol. B {bold 13}, 142 (1995)  

SciTech Connect (OSTI)

It is contended that contrarily to the claim of Szilagyi and Cho (Ref. 1), thecoma of deflection as well as field curvature can not be eliminated in the optimized electrostatic deflectors. (AIP)

Lencova, B. [Institute of Scientific Instruments, Academy of Sciences of the Czech Republic, Kralovopolska 147, 612 64 Brno (Czech Republic)] [Institute of Scientific Instruments, Academy of Sciences of the Czech Republic, Kralovopolska 147, 612 64 Brno (Czech Republic)

1996-05-01T23:59:59.000Z

370

Measuring time of flight of fusion products in an inertial electrostatic confinement fusion device for spatial profiling of fusion reactions  

SciTech Connect (OSTI)

A new diagnostic has been developed that uses the time of flight (TOF) of the products from a nuclear fusion reaction to determine the location where the fusion reaction occurred. The TOF diagnostic uses charged particle detectors on opposing sides of the inertial electrostatic confinement (IEC) device that are coupled to high resolution timing electronics to measure the spatial profile of fusion reactions occurring between the two charged particle detectors. This diagnostic was constructed and tested by the University of Wisconsin-Madison Inertial Electrostatic Confinement Fusion Group in the IEC device, HOMER, which accelerates deuterium ions to fusion relevant energies in a high voltage ({approx}100 kV), spherically symmetric, electrostatic potential well [J. F. Santarius, G. L. Kulcinski, R. P. Ashley, D. R. Boris, B. B. Cipiti, S. K. Murali, G. R. Piefer, R. F. Radel, T. E. Radel, and A. L. Wehmeyer, Fusion Sci. Technol. 47, 1238 (2005)]. The TOF diagnostic detects the products of D(d,p)T reactions and determines where along a chord through the device the fusion event occurred. The diagnostic is also capable of using charged particle spectroscopy to determine the Doppler shift imparted to the fusion products by the center of mass energy of the fusion reactants. The TOF diagnostic is thus able to collect spatial profiles of the fusion reaction density along a chord through the device, coupled with the center of mass energy of the reactions occurring at each location. This provides levels of diagnostic detail never before achieved on an IEC device.

Donovan, D. C. [Sandia National Laboratories, 7011 East Avenue, Livermore, California 94550 (United States); Boris, D. R. [Naval Research Laboratory, 4555 Overlook Avenue, South West, Washington, DC 20375 (United States); Kulcinski, G. L.; Santarius, J. F. [Fusion Technology Institute, University of Wisconsin-Madison, 1500 Engineering Drive, Madison, Wisconsin 53706 (United States); Piefer, G. R. [Phoenix Nuclear Labs, 2555 Industrial Drive, Madison, Wisconsin 53713 (United States)

2013-03-15T23:59:59.000Z

371

Electrostatic solitary structures in presence of non-thermal electrons and a warm electron beam on the auroral field lines  

SciTech Connect (OSTI)

Electrostatic solitary waves (ESWs) have been observed by satellites in the auroral region of the Earth's magnetosphere. These ESWs are found to be having both positive and negative electrostatic potentials. Using the Sagdeeev psuedo-potential technique, arbitrary amplitude electron-acoustic solitary waves/double layers are studied in an unmagnetized plasma consisting of non-thermally distributed hot electrons, fluid cold electrons, a warm electron beam, and ions. The inertia of the warm electrons, and not the beam speed, is essential for the existence of positive potential solitary structures. Existence domains for positive as well as negative potential electrostatic solitons/double layers are obtained. For the typical auroral region parameters, the electric field amplitude of the negative potential solitons is found to be in the range {approx}(3-30) mV/m and {approx}(5-80) mV/m for the positive potential solitons. For the negative potential solitons/double layers, the amplitudes are higher when their widths are smaller. On the other hand, the amplitude of the positive potential structures increase with their widths.

Singh, S. V. [Indian Institute of Geomagnetism, Navi Mumbai (India); School of Physics, University of Kwazulu-Natal, Durban (South Africa); Lakhina, G. S. [Indian Institute of Geomagnetism, Navi Mumbai (India); Bharuthram, R. [University of the Western Cape, Bellville (South Africa); Pillay, S. R. [School of Physics, University of Kwazulu-Natal, Durban (South Africa)

2011-12-15T23:59:59.000Z

372

Design, Fabrication and Testing of Angled Fiber Suspension for Electrostatic Actuators  

E-Print Network [OSTI]

Journal of Microelectromechanical Systems, 2:3, 1993. [59]Journal of Microelectromechanical Systems, 12:656–671,ca- pacitive microelectromechanical systems (MEMS). Sensors

Schubert, Bryan Edward

2011-01-01T23:59:59.000Z

373

FULL-SCALE TESTING OF ENHANCED MERCURY CONTROL TECHNOLOGIES FOR WET FGD SYSTEMS  

SciTech Connect (OSTI)

Wet flue gas desulfurization (wet FGD) systems are currently installed on about 25% of the coal-fired utility generating capacity in the U.S., representing about 15% of the number of coal-fired units. Depending on the effect of operating parameters such as mercury content of the coal, form of mercury (elemental or oxidized) in the flue gas, scrubber spray tower configuration, liquid-to-gas ratio, and slurry chemistry, FGD systems can provide cost-effective, near-term mercury emissions control options with a proven history of commercial operation. For boilers already equipped with FGD systems, the incremental cost of any vapor phase mercury removal achieved is minimal. To be widely accepted and implemented, technical approaches that improve mercury removal performance for wet FGD systems should also have low incremental costs and have little or no impact on operation and SO{sub 2} removal performance. The ultimate goal of the Full-scale Testing of Enhanced Mercury Control for Wet FGD Systems Program was to commercialize methods for the control of mercury in coal-fired electric utility systems equipped with wet flue gas desulfurization (wet FGD). The program was funded by the U.S. Department of Energy's National Energy Technology Laboratory, the Ohio Coal Development Office within the Ohio Department of Development, and Babcock & Wilcox. Host sites and associated support were provided by Michigan South Central Power Agency (MSCPA) and Cinergy. Field-testing was completed at two commercial coal-fired utilities with wet FGD systems: (1) MSCPA's 55 MW{sub e} Endicott Station and (2) Cinergy's 1300 MW{sub e} Zimmer Station. Testing was conducted at these two locations because of the large differences in size and wet scrubber chemistry. Endicott employs a limestone, forced oxidation (LSFO) wet FGD system, whereas Zimmer uses Thiosorbic{reg_sign} Lime (magnesium enhanced lime) and ex situ oxidation. Both locations burn Ohio bituminous coal.

D.K. McDonald; G.T. Amrhein; G.A. Kudlac; D. Madden Yurchison

2003-05-07T23:59:59.000Z

374

DOE-backed independent scrubber system is criticized by AEP  

SciTech Connect (OSTI)

Among the five early contract signers from the second round of 16 clean-coal technologies selected by the Dept of Energy (DOE) for partial funding was Pure Air's flue-gas desulfurization (FGD) technology-and-service project for Northern Indiana Public Service Co (Nipsco). Pure Air is not only financing, designing, and building the $141-million Nipsco advanced wet-scrubber system at Units 7 (183 MW) and 8 (345 MW) of the utility's Bailly powerplant, it is also operating and maintaining the scrubber. It is the own-and-operate approach that caught DOE's eye, because it allows utilities who are inexperienced in running a complex chemical plant to remain focused on electricity production while avoiding a major capital expense. American Electric Power Service Co questions the service contract, but not the technology. AEP's assistant general counsel foresees a full array of possibilities associated with contract complexity when dealing with removal. The paper briefly describes these complexities.

Not Available

1990-02-01T23:59:59.000Z

375

Nonlinear, stationary electrostatic ion cyclotron waves: Exact solutions for solitons, periodic waves, and wedge shaped waveforms  

SciTech Connect (OSTI)

The theory of fully nonlinear stationary electrostatic ion cyclotron waves is further developed. The existence of two fundamental constants of motion; namely, momentum flux density parallel to the background magnetic field and energy density, facilitates the reduction of the wave structure equation to a first order differential equation. For subsonic waves propagating sufficiently obliquely to the magnetic field, soliton solutions can be constructed. Importantly, analytic expressions for the amplitude of the soliton show that it increases with decreasing wave Mach number and with increasing obliquity to the magnetic field. In the subsonic, quasi-parallel case, periodic waves exist whose compressive and rarefactive amplitudes are asymmetric about the 'initial' point. A critical 'driver' field exists that gives rise to a soliton-like structure which corresponds to infinite wavelength. If the wave speed is supersonic, periodic waves may also be constructed. The aforementioned asymmetry in the waveform arises from the flow being driven towards the local sonic point in the compressive phase and away from it in the rarefactive phase. As the initial driver field approaches the critical value, the end point of the compressive phase becomes sonic and the waveform develops a wedge shape. This feature and the amplitudes of the compressive and rarefactive portions of the periodic waves are illustrated through new analytic expressions that follow from the equilibrium points of a wave structure equation which includes a driver field. These expressions are illustrated with figures that illuminate the nature of the solitons. The presently described wedge-shaped waveforms also occur in water waves, for similar 'transonic' reasons, when a Coriolis force is included.

McKenzie, J. F. [Department of Mathematics, Statistics and Physics, Durban University of Technology, Steve Biko Campus, Durban 4001 (South Africa); School of Mathematical Sciences, University of KwaZulu-Natal, Private Bag: X54001, Durban 4001 (South Africa); Doyle, T. B. [Materials Research Division, iThemba LABS, P.O.Box 722, Somerset West, 7129, South Africa and School of Chemistry and Physics, University of KwaZulu-Natal, Private Bag: X54001, Durban 4001 (South Africa); Rajah, S. S. [Department of Mathematics, Statistics and Physics, Durban University of Technology, Steve Biko Campus, Durban 4001 (South Africa)

2012-11-15T23:59:59.000Z

376

A conceptual design of a Reactive Ion Etch back end system for the direct reuse of process gases  

E-Print Network [OSTI]

Pyrolitic Flame Separator. Absorption and Adsorption Processes. ' . Beltran Electrostatic Precipitator. ' Dyna-Therm Corporation Centrifugal Separator. CzFs Capture Efficiencies as a Percentage of CzF& in the System. CF& Capture Efficiencies as a.... Rotary Flow Dust Separator. " Page 25 27 28 Fig. 7. Fig. 8. Fig. 9 Fig. 10. Fig. I 1. Fig. 12. Fig. 13. Fig. 14. Fig. 15. Fig. 16. Fig. 17. Fig. 18. Fig. 19. Electrostatic Separator. Bag Filter Separation. n Venturi Separation. ' sz...

Tiner, Paul Alan

1994-01-01T23:59:59.000Z

377

Apparatus and method for improving electrostatic precipitator performance by plasma reactor conversion of SO.sub.2 to SO.sub.3  

DOE Patents [OSTI]

An apparatus and process that utilize a low temperature nonequilibrium plasma reactor, for improving the particulate removal efficiency of an electrostatic precipitator (ESP) are disclosed. A portion of the flue gas, that contains a low level of SO.sub.2 O.sub.2 H.sub.2 O, and particulate matter, is passed through a low temperature plasma reactor, which defines a plasma volume, thereby oxidizing a portion of the SO.sub.2 present in the flue gas into SO.sub.3. An SO.sub.2 rich flue gas is thereby generated. The SO.sub.3 rich flue gas is then returned to the primary flow of the flue gas in the exhaust treatment system prior to the ESP. This allows the SO.sub.3 to react with water to form H.sub.2 SO.sub.4 that is in turn is absorbed by fly ash in the gas stream in order to improve the removal efficiency of the EPS.

Huang, Hann-Sheng (Darien, IL); Gorski, Anthony J. (Woodridge, IL)

1999-01-01T23:59:59.000Z

378

Electromagnetic effects on transportation systems  

SciTech Connect (OSTI)

Electronic and electrical system protection design can be used to eliminate deleterious effects from lightning, electromagnetic interference, and electrostatic discharges. Evaluation of conventional lightning protection systems using advanced computational modeling in conjunction with rocket-triggered lightning tests suggests that currently used lightning protection system design rules are inadequate and that significant improvements in best practices used for electronic and electrical system protection designs are possible. A case study of lightning induced upset and failure of a railway signal and control system is sketched.

Morris, M.E.; Dinallo, M.A.

1996-05-01T23:59:59.000Z

379

Characterization of fundamental catalytic properties of MoS2/WS2 nanotubes and nanoclusters for desulfurization catalysis - a surface temperature study  

SciTech Connect (OSTI)

The prior project consisted of two main project lines. First, characterization of novel nanomaterials for hydrodesulfurization (HDS) applications. Second, studying more traditional model systems for HDS such as vapor-deposited silica-supported Mo and MoSx clusters. In the first subproject, we studied WS2 and MoS2 fullerene-like nanoparticles as well as WS2 nanotubes. Thiophene (C4H4S) was used as the probe molecule. Interestingly, metallic and sulfur-like adsorption sites could be identified on the silica-supported fullerene-particles system. Similar structures are seen for the traditional system (vapor-deposited clusters). Thus, this may be a kinetics fingerprint feature of modern HDS model systems. In addition, kinetics data allowed characterization of the different adsorption sites for thiophene on and inside WS2 nanotube bundles. The latter is a unique feature of nanotubes that has not been reported before for any inorganic nanotube system; however, examples are known for carbon nanotubes, including prior work of the PI. Although HDS has been studied for decades, utilizing nanotubes as nanosized HDS reactors has never been tried before, as far as we know. This is of interest from a fundamental perspective. Unfortunately, the HDS activity of the nanocatalysts at ultra-high vacuum (UHV) conditions was close to the detection limit of our techniques. Therefore, we propose to run experiments at ambient pressure on related nanopowder samples as part of the renewal application utilizing a now-available GC (gas chromatograph) setup. In addition, Ni and Co doped nanocatalyts are proposed for study. These dopants will boost the catalytic activity. In the second subproject of the prior grant, we studied HDS-related chemistry on more traditional supported cluster catalysts. Mo clusters supported by physical vapor deposition (PVD) on silica have been characterized. Two reaction pathways are evident when adsorbing thiophene on Mo and MoSx clusters: molecular adsorption and dissociation. PVD Mo clusters turned out to be very reactive toward thiophene bond activation. Sulfur and carbon residuals form, which poison the catalyst and sulfide the Mo clusters. Sulfided silica-supported MoSx samples are not reactive toward thiophene bond activation. In addition to S and C deposits, H2, H2S, and small organic molecules were detected in the gas phase. Catalyst reactivation procedures, including O2 and atomic hydrogen treatments, have been tested. Cluster size effects have been seen: thiophene adsorbs molecularly with larger binding energies on smaller clusters. However, larger clusters have smaller activation energy for C4H4S bond activation than smaller clusters. The latter is consistent with early catalysis studies. Kinetics and dynamics parameters have been determined quantitatively. We spent a significant amount of time on upgrades of our equipment. A 2nd-hand refurbished X-ray photoelectron spectrometer (XPS) has been integrated into the existing molecular beam scattering system and is already operational (supported by the DoE supplemental grant available in October 2009). We also added a time of flight (TOF) system to the beam scattering apparatus and improved on the accessible impact energy range (new nozzle heater and gas mixing manifold) for the beam scattering experiments. In addition, a GC-based powder atmospheric flow reactor for studies on powder samples is now operational. Furthermore, a 2nd UHV kinetics system has been upgraded as well. In summary, mostly single crystal systems have so far been considered in basic science studies about HDS. Industrial catalysts, however, can be better approximated with the supported cluster systems that we studied in this project. Furthermore, an entirely new class of HDS systems, namely fullerene-like particles and inorganic nanotubes, has been included. Studying new materials and systems has the potential to impact science and technology. The systems investigated are closely related to energy and environmental-related surface science/catalysis. This prior project, conducted at NDSU by a sma

U. Burghaus

2012-07-05T23:59:59.000Z

380

Load sensing system  

DOE Patents [OSTI]

A load sensing system inexpensively monitors the weight and temperature of stored nuclear material for long periods of time in widely variable environments. The system can include an electrostatic load cell that encodes weight and temperature into a digital signal which is sent to a remote monitor via a coaxial cable. The same cable is used to supply the load cell with power. When multiple load cells are used, vast inventories of stored nuclear material can be continuously monitored and inventoried of minimal cost. 4 figs.

Sohns, C.W.; Nodine, R.N.; Wallace, S.A.

1999-05-04T23:59:59.000Z

Note: This page contains sample records for the topic "desulfurization systems electrostatic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Collaborative research: Dynamics of electrostatic solitary waves and their effects on current layers  

SciTech Connect (OSTI)

The project has accomplished the following achievements including the goals outlined in the original proposal. Generation and measurements of Debye-scale electron holes in laboratory: We have generated by beam injections electron solitary waves in the LAPD experiments. The measurements were made possible by the fabrication of the state-of-the-art microprobes at UCLA to measure Debye-scale electric fields [Chiang et al., 2011]. We obtained a result that challenged the state of knowledge about electron hole generation. We found that the electron holes were not due to two-stream instability, but generated by a current-driven instability that also generated whistler-mode waves [Lefebvre et al., 2011, 2010b]. Most of the grant supported a young research scientist Bertrand Lefebvre who led the dissemination of the laboratory experimental results. In addition to two publications, our work relevant to the laboratory experiments on electron holes has resulted in 7 invited talks [Chen, 2007, 2009; Pickett et al., 2009a; Lefebvre et al., 2010a; Pickett et al., 2010; Chen et al., 2011c, b] (including those given by the co-I Jolene Pickett) and 2 contributed talks [Lefebvre et al., 2009b, a]. Discovery of elecctron phase-space-hole structure in the reconnection electron layer: Our theoretical analyses and simulations under this project led to the discovery of an inversion electric field layer whose phase-space signature is an electron hole within the electron diffusion layer in 2D anti-parallel reconnection [Chen et al., 2011a]. We carried out particle tracing studies to understand the electron orbits that result in the phase-space hole structure. Most importantly, we showed that the current density in the electron layer is limited in collisionless reconnection with negligible guide field by the cyclotron turning of meandering electrons. Comparison of electrostatic solitary waves in current layers observed by Cluster and in LAPD: We compared the ESWs observed in a supersubstorm by the Cluster spacecraft and those measured in LAPD. One of the similarities in the characteristics of ESWs observed in space and in LAPD is that the time duration tends to be approximately the inverse of the electron plasma frequency [Pickett et al., 2009b]. Discovery of suprathermal electron bursts inside a series of magnetic islands: Our effort in examining the roles of ESWs in reconnection current layers resulted in the serendipitous discovery that was published in Nature Physics. In earth’s magnetosphere, we observed through the measurements from the four Cluster spacecraft, a series of magnetic islands and suprathermal electron bursts within the islands. The islands were identified to be effectively acceleration sites for electrons [Chen et al., 2008, 2009].

Chen, Li-Jen

2014-04-18T23:59:59.000Z

382

Fluid simulation of an electrostatic plasma sheath with two species of positive ions and charged nanoparticles  

SciTech Connect (OSTI)

One-dimensional fluid simulations are used to study the dynamics of an electrostatic plasma sheath containing nanosized dust grains and two species of positive ions, i.e., He{sup +} and Ar{sup +}. The impacts of the concentration of each species, the velocity at the sheath edge of the ions, and the bias voltage of the substrate, on the spatial distribution of the velocity and number density of the plasma particles, and the incident fluxes of the ions on the substrate, are investigated. The numerical results show that the sheath thickness increases with increasing {sigma}, the density ratio of He{sup +} ions to Ar{sup +} ions at the sheath edge. For nanosized dust particles considered in this work, the dominant forces are the ion drag and the electric force and the effects of the neutral drag and gravity are negligible. Due to enhancement of the ion drag force and the electric force, the dust velocity increases and, consequently, the dust number density decreases as the concentration at the sheath edge of Ar{sup +} ions is increased. For the same velocity and number density at the sheath edge, the number density of Ar{sup +} ions near the wall is larger than that of He{sup +} ions, but their incident fluxes are the same. The maximum in the dust number density increases with the velocity of Ar{sup +} ions at the sheath edge, but it weakly changes with the Mach number of He{sup +} ions, except for large values of {sigma}. The position of the maximum dust number density initially decreases very quickly with increasing the velocity at the sheath edge of the ions from small values, but then at larger values it changes quite slowly. The differences in the sheath parameters for different values of {sigma} disappear at some values of the velocity at the sheath edge of the ions and dust particles. The incident flux of the ions are independent of the bias voltage of the substrate, but their kinetic energy is equal to the bias potential.

Foroutan, G. [Department of Physics, Faculty of Science, Sahand University of Technology, 51335-1996 Tabriz (Iran, Islamic Republic of); Nanostructure Material Research Center, Sahand University of Technology, 51335-1996 Tabriz (Iran, Islamic Republic of) and School of Physics, University of Sydney, New South Wales 2006, Sydney (Australia)

2010-12-15T23:59:59.000Z

383

A study of toxic emissions from a coal-fired power plant utilizing an ESP/Wet FGD system. Volume 1, Sampling, results, and special topics: Final report  

SciTech Connect (OSTI)

This was one of a group of assessments of toxic emissions from coal-fired power plants, conducted for DOE-PETC in 1993 as mandated by the 1990 Clean Air Act. It is organized into 2 volumes; Volume 1 describes the sampling effort, presents the concentration data on toxic chemicals in several power plant streams, and reports the results of evaluations and calculations. The study involved solid, liquid, and gaseous samples from input, output, and process streams at Coal Creek Station Unit No. 1, Underwood, North Dakota (1100 MW mine-mouth plant burning lignite from the Falkirk mine located adjacent to the plant). This plant had an electrostatic precipitator and a wet scrubber flue gas desulfurization unit. Measurements were conducted on June 21--24, 26, and 27, 1993; chemicals measured were 6 major and 16 trace elements (including Hg, Cr, Cd, Pb, Se, As, Be, Ni), acids and corresponding anions (HCl, HF, chloride, fluoride, phosphate, sulfate), ammonia and cyanide, elemental C, radionuclides, VOCs, semivolatiles (incl. PAH, polychlorinated dioxins, furans), and aldehydes. Volume 2: Appendices includes process data log sheets, field sampling data sheets, uncertainty calculations, and quality assurance results.

Not Available

1994-07-01T23:59:59.000Z

384

Applications and experiences with super duplex stainless steel in wet FGD scrubber systems  

SciTech Connect (OSTI)

The paper presents the properties of the author`s company`s proprietary super duplex stainless steel. Work is presented showing the development of a more realistic laboratory solution representing typical limestone slurries found in real flue gas desulfurization (FGD) systems. The importance of additions of metal ions such as Fe{sup 3+} and Mn{sup 2+} as well as partially oxidized sulfur species is demonstrated. Results are presented comparing the crevice corrosion resistance of super duplex stainless steel in these slurries with other commonly used wrought and cast stainless steels, for both simulated anthracite and lignite type slurries. Data from loop tests on the erosion resistance of a range of alloys in simulated FGD slurries is presented. The results clearly show the superior resistance of super duplex stainless steel to both crevice corrosion and erosion in FGD slurries. Finally the experiences in UK FGD systems with both cast and wrought super duplex stainless steel are presented.

Francis, R.; Byrne, G.; Warburton, G.; Hebdon, S. [Weir Materials Ltd., Manchester (United Kingdom)

1998-12-31T23:59:59.000Z

385

Electrostatic precipitation of condensed acid mist: Second quarterly technical progress report, December 1, 1988--February 28, 1989  

SciTech Connect (OSTI)

This report covers the project scope and structure for developing and demonstrating a compact, wet electrostatic collector for condensed acid mist in power plant flue gas. In order to accomplish this goal, the objectives to be met are: (1) a laboratory-version of the WESP (Wet Electrostatic Precipitator) must be fabricated, (2) the WESP performance must be optimized through laboratory tests with a nonvolatile simulant aerosol having a size distribution similar to the acid mist, (3) the WESP concept must be proven by demonstrating adequate collection of actual acid mist in a pilot coal combustion facility under conditions simulating a full-scale power plant burning high-sulfur coal, (4) a computer model of the WESP process must be developed to assist in the process optimization, interpretation of test results, and extrapolation to full scale, and (5) utility participation must be solicited in a follow-on demonstration of the WESP concept at a full-scale power plant. Progress in laboratory testing and collection efficiency is described. 5 refs., 2 figs.

Dahlin, R.S.

1989-01-01T23:59:59.000Z

386

Electrostatic precipitation of condensed acid mist: First quarterly technical progress report, September 1 to November 30, 1988  

SciTech Connect (OSTI)

This report covers the project scope and structure for developing and demonstrating a compact, wet electrostatic collector for condensed acid mist in power plant flue gas. In order to accomplish this goal, the objectives to be met are: (1) a laboratory-version of the WESP (Wet Electrostatic Precipitator) must be fabricated. (2) the WESP performance must be optimized through laboratory tests with a nonvolatile simulant aerosol having a size distribution similar to the acid mist. (3) the WESP concept must be proven by demonstrating adequate collection of actual acid mist in a pilot coal combustion facility under conditions simulating a full-scale power plant burning high-sulfur coal. (4) a computer model of the WESP process must be developed to assist in the process optimization, interpretation of test results, and extrapolation to full scale. (5) Utility participation must be solicited in a follow-on demonstration of the WESP concept at a full-scale power plant. 5 refs., 2 figs. (JL)

Dahlin, R.S.

1988-01-01T23:59:59.000Z

387

Improved lifetimes and synchronization behavior in multi-grid inertial electrostatic confinement fusion devices  

E-Print Network [OSTI]

A high output power source is required for fast, manned exploration of the solar system, especially the outer planets. Travel times measured in months, not years, will require high power, lightweight nuclear systems. The ...

McGuire, Thomas John, 1977-

2007-01-01T23:59:59.000Z

388

Kinetic Electrostatic Electron Nonlinear (KEEN) Waves and their Interactions Driven by the Ponderomotive Force of Crossing Laser Beams  

E-Print Network [OSTI]

We have found, using 1D periodic Vlasov-Poisson simulations, new nonlinear, nonstationary, stable, long lived, coherent structures in phase space, called kinetic electrostatic electron nonlinear (KEEN) waves. Ponderomotively driven for a short period of time, at a particular frequency and wavenumber, well inside the band gap that was thought to exist between electron plasma and electron acoustic wave frequencies, KEEN waves are seen to self-consistently form, and persist for thousands of plasma periods. KEEN waves are comprised of 4 or more significant phase-locked harmonic modes which persist only when driven sufficiently strongly. They also merge when two or more at different frequencies are driven sequentially. However, the final stable KEEN state that emerges is highly sensitive to their relative order of excitation. KEEN waves also interact quite strongly with electron plasma waves (EPW) especially when their harmonics are close to being resonant with the EPW frequency at the same k. The common assumptio...

Afeyan, Bedros; Savchenko, V; Johnston, T; Ghizzo, A; Bertrand, P

2012-01-01T23:59:59.000Z

389

Effects of obliqueness and strong electrostatic interaction on linear and nonlinear propagation of dust-acoustic waves in a magnetized strongly coupled dusty plasma  

SciTech Connect (OSTI)

Linear and nonlinear propagation of dust-acoustic waves in a magnetized strongly coupled dusty plasma is theoretically investigated. The normal mode analysis (reductive perturbation method) is employed to investigate the role of ambient/external magnetic field, obliqueness, and effective electrostatic dust-temperature in modifying the properties of linear (nonlinear) dust-acoustic waves propagating in such a strongly coupled dusty plasma. The effective electrostatic dust-temperature, which arises from strong electrostatic interactions among highly charged dust, is considered as a dynamical variable. The linear dispersion relation (describing the linear propagation characteristics) for the obliquely propagating dust-acoustic waves is derived and analyzed. On the other hand, the Korteweg-de Vries equation describing the nonlinear propagation of the dust-acoustic waves (particularly, propagation of dust-acoustic solitary waves) is derived and solved. It is shown that the combined effects of obliqueness, magnitude of the ambient/external magnetic field, and effective electrostatic dust-temperature significantly modify the basic properties of linear and nonlinear dust-acoustic waves. The results of this work are compared with those observed by some laboratory experiments.

Shahmansouri, M. [Department of Physics, Faculty of Science, Arak University, Arak 38156- 8 8349 (Iran, Islamic Republic of)] [Department of Physics, Faculty of Science, Arak University, Arak 38156- 8 8349 (Iran, Islamic Republic of); Mamun, A. A. [Department of Physics, Jahangirnagar University, Savar, Dhaka-1342 (Bangladesh)] [Department of Physics, Jahangirnagar University, Savar, Dhaka-1342 (Bangladesh)

2014-03-15T23:59:59.000Z

390

Behavioral ESD Protection Modeling to perform System Level ESD Efficient Design  

E-Print Network [OSTI]

) and semi- conductor suppliers, the prediction of ElectroStatic Discharge (ESD) events into design phase goal of the proposed model is that it could be shared by IC suppliers and EMs to ensure that ICs can aggressions of a system. The level of ESD stress required during the system qualification is increasing over

Paris-Sud XI, Université de

391

Flue gas desulfurization gypsum and fly ash  

SciTech Connect (OSTI)

The Cumberland Fossil Plant (CUF) is located in Stewart County, Tennessee, and began commercial operation in 1972. This is the Tennessee Valley Authority`s newest fossil (coal-burning) steam electric generating plant. Under current operating conditions, the plant burns approximately seven million tons of coal annually. By-products from the combustion of coal are fly ash, approximately 428,000 tons annually, and bottom ash, approximately 115,000 tons annually. Based on historical load and projected ash production rates, a study was initially undertaken to identify feasible alternatives for marketing, utilization and disposal of ash by-products. The preferred alternative to ensure that facilities are planned for all by-products which will potentially be generated at CUF is to plan facilities to handle wet FGD gypsum and dry fly ash. A number of different sites were evaluated for their suitability for development as FGD gypsum and ash storage facilities. LAW Engineering was contracted to conduct onsite explorations of sites to develop information on the general mature of subsurface soil, rock and groundwater conditions in the site areas. Surveys were also conducted on each site to assess the presence of endangered and threatened species, wetlands and floodplains, archaeological and cultural resources, prime farmland and other site characteristics which must be considered from an environmental perspective.

Not Available

1992-05-01T23:59:59.000Z

392

High temperature desulfurization of synthesis gas  

DOE Patents [OSTI]

The hot process gas stream from the partial oxidation of sulfur-containing heavy liquid hydrocarbonaceous fuel and/or sulfur-containing solid carbonaceous fuel comprising gaseous mixtures of H.sub.2 +CO, sulfur-containing gases, entrained particulate carbon, and molten slag is passed through the unobstructed central passage of a radiant cooler where the temperature is reduced to a temperature in the range of about 1800.degree. F. to 1200.degree. F. From about 0 to 95 wt. % of the molten slag and/or entrained material may be removed from the hot process gas stream prior to the radiant cooler with substantially no reduction in temperature of the process gas stream. In the radiant cooler, after substantially all of the molten slag has solidified, the sulfur-containing gases are contacted with a calcium-containing material to produce calcium sulfide. A partially cooled stream of synthesis gas, reducing gas, or fuel gas containing entrained calcium sulfide particulate matter, particulate carbon, and solidified slag leaves the radiant cooler containing a greatly reduced amount of sulfur-containing gases.

Najjar, Mitri S. (Hopewell Junction, NY); Robin, Allen M. (Anaheim, CA)

1989-01-01T23:59:59.000Z

393

Process for production desulfurized of synthesis gas  

DOE Patents [OSTI]

A process for the partial oxidation of a sulfur- and silicate-containing carbonaceous fuel to produce a synthesis gas with reduced sulfur content which comprises partially oxidizing said fuel at a temperature in the range of 1900.degree.-2600.degree. F. in the presence of a temperature moderator, an oxygen-containing gas and a sulfur capture additive which comprises a calcium-containing compound portion, a sodium-containing compound portion, and a fluoride-containing compound portion to produce a synthesis gas comprising H.sub.2 and CO with a reduced sulfur content and a molten slag which comprises (1) a sulfur-containing sodium-calcium-fluoride silicate phase; and (2) a sodium-calcium sulfide phase.

Wolfenbarger, James K. (Torrance, CA); Najjar, Mitri S. (Wappingers Falls, NY)

1993-01-01T23:59:59.000Z

394

Diesel Desulfurization Filter | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeat Pump Models |Conduct, Parent CompanyaUSAMPRelated PathStrategy | Department

395

Desulfurization Fuel Filter | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeat Pump Models |Conduct, Parent Company AgreesDesiree Pipkins About Us

396

System to control contamination during retrieval of buried TRU waste  

DOE Patents [OSTI]

A system to control contamination during the retrieval of hazardous waste comprising an outer containment building, an inner containment building, within the outer containment building, an electrostatic radioactive particle recovery unit connected to and in communication with the inner and outer containment buildings, and a contaminate suppression system including a moisture control subsystem, and a rapid monitoring system having the ability to monitor conditions in the inner and outer containment buildings.

Menkhaus, Daniel E. (Idaho Falls, ID); Loomis, Guy G. (Idaho Falls, ID); Mullen, Carlan K. (Idaho Falls, ID); Scott, Donald W. (Idaho Falls, ID); Feldman, Edgar M. (Idaho Falls, ID); Meyer, Leroy C. (Idaho Falls, ID)

1993-01-01T23:59:59.000Z

397

System to control contamination during retrieval of buried TRU waste  

DOE Patents [OSTI]

A system is described to control contamination during the retrieval of hazardous waste comprising an outer containment building, an inner containment building, within the outer containment building, an electrostatic radioactive particle recovery unit connected to and in communication with the inner and outer containment buildings, and a contaminate suppression system including a moisture control subsystem, and a rapid monitoring system having the ability to monitor conditions in the inner and outer containment buildings.

Menkhaus, D.E.; Loomis, G.G.; Mullen, C.K.; Scott, D.W.; Feldman, E.M.; Meyer, L.C.

1993-04-20T23:59:59.000Z

398

KPFM and PFM of Biological Systems  

SciTech Connect (OSTI)

Surface potentials and electrostatic interactions in biological systems are a key element of cellular regulation and interaction. Examples include cardiac and muscular activity, voltage-gated ion channels, protein folding and assembly, and electroactive cells and electrotransduction. The coupling between electrical, mechanical, and chemical signals and responses in cellular systems necessitates the development of tools capable of measuring the distribution of charged species, surface potentials, and mechanical responses to applied electrical stimuli and vice versa, ultimately under physiological conditions. In this chapter, applications of voltage-modulated atomic force microscopy (AFM) methods including Kelvin probe force microscopy (KPFM) and piezoresponse force microscopy (PFM) to biological systems are discussed. KPFM is a force-sensitive non-contact or intermittent-contact mode AFM technique that allows electrostatic interactions and surface potentials to be addressed. Beyond long-range electrostatic interactions, the application of bias can lead to a mechanical response, e.g., due to linear piezoelectric coupling in polar biopolymers or via more complex electrotransduction and redox pathways in other biosystems. The use and development of PFM, based on direct electromechanical detection, to biological systems will also be addressed. The similarities and limitations of measuring surface potentials and electromechanical coupling in solution will be outlined.

Rodriguez, Brian [University College, Dublin; Kalinin, Sergei V [ORNL

2011-01-01T23:59:59.000Z

399

Calculating the binding free energies of charged species based on explicit-solvent simulations employing lattice-sum methods: An accurate correction scheme for electrostatic finite-size effects  

SciTech Connect (OSTI)

The calculation of a protein-ligand binding free energy based on molecular dynamics (MD) simulations generally relies on a thermodynamic cycle in which the ligand is alchemically inserted into the system, both in the solvated protein and free in solution. The corresponding ligand-insertion free energies are typically calculated in nanoscale computational boxes simulated under periodic boundary conditions and considering electrostatic interactions defined by a periodic lattice-sum. This is distinct from the ideal bulk situation of a system of macroscopic size simulated under non-periodic boundary conditions with Coulombic electrostatic interactions. This discrepancy results in finite-size effects, which affect primarily the charging component of the insertion free energy, are dependent on the box size, and can be large when the ligand bears a net charge, especially if the protein is charged as well. This article investigates finite-size effects on calculated charging free energies using as a test case the binding of the ligand 2-amino-5-methylthiazole (net charge +1 e) to a mutant form of yeast cytochrome c peroxidase in water. Considering different charge isoforms of the protein (net charges ?5, 0, +3, or +9 e), either in the absence or the presence of neutralizing counter-ions, and sizes of the cubic computational box (edges ranging from 7.42 to 11.02 nm), the potentially large magnitude of finite-size effects on the raw charging free energies (up to 17.1 kJ?mol{sup ?1}) is demonstrated. Two correction schemes are then proposed to eliminate these effects, a numerical and an analytical one. Both schemes are based on a continuum-electrostatics analysis and require performing Poisson-Boltzmann (PB) calculations on the protein-ligand system. While the numerical scheme requires PB calculations under both non-periodic and periodic boundary conditions, the latter at the box size considered in the MD simulations, the analytical scheme only requires three non-periodic PB calculations for a given system, its dependence on the box size being analytical. The latter scheme also provides insight into the physical origin of the finite-size effects. These two schemes also encompass a correction for discrete solvent effects that persists even in the limit of infinite box sizes. Application of either scheme essentially eliminates the size dependence of the corrected charging free energies (maximal deviation of 1.5 kJ?mol{sup ?1}). Because it is simple to apply, the analytical correction scheme offers a general solution to the problem of finite-size effects in free-energy calculations involving charged solutes, as encountered in calculations concerning, e.g., protein-ligand binding, biomolecular association, residue mutation, pK{sub a} and redox potential estimation, substrate transformation, solvation, and solvent-solvent partitioning.

Rocklin, Gabriel J. [Department of Pharmaceutical Chemistry, University of California San Francisco, 1700 4th St., San Francisco, California 94143-2550, USA and Biophysics Graduate Program, University of California San Francisco, 1700 4th St., San Francisco, California 94143-2550 (United States)] [Department of Pharmaceutical Chemistry, University of California San Francisco, 1700 4th St., San Francisco, California 94143-2550, USA and Biophysics Graduate Program, University of California San Francisco, 1700 4th St., San Francisco, California 94143-2550 (United States); Mobley, David L. [Departments of Pharmaceutical Sciences and Chemistry, University of California Irvine, 147 Bison Modular, Building 515, Irvine, California 92697-0001, USA and Department of Chemistry, University of New Orleans, 2000 Lakeshore Drive, New Orleans, Louisiana 70148 (United States)] [Departments of Pharmaceutical Sciences and Chemistry, University of California Irvine, 147 Bison Modular, Building 515, Irvine, California 92697-0001, USA and Department of Chemistry, University of New Orleans, 2000 Lakeshore Drive, New Orleans, Louisiana 70148 (United States); Dill, Ken A. [Laufer Center for Physical and Quantitative Biology, 5252 Stony Brook University, Stony Brook, New York 11794-0001 (United States)] [Laufer Center for Physical and Quantitative Biology, 5252 Stony Brook University, Stony Brook, New York 11794-0001 (United States); Hünenberger, Philippe H., E-mail: phil@igc.phys.chem.ethz.ch [Laboratory of Physical Chemistry, Swiss Federal Institute of Technology, ETH, 8093 Zürich (Switzerland)

2013-11-14T23:59:59.000Z

400

Emissions estimation for lignite-fired power plants in Turkey  

SciTech Connect (OSTI)

The major gaseous emissions (e.g. sulfur dioxide, nitrogen oxides, carbon dioxide, and carbon monoxide), some various organic emissions (e.g. benzene, toluene and xylenes) and some trace metals (e.g. arsenic, cobalt, chromium, manganese and nickel) generated from lignite-fired power plants in Turkey are estimated. The estimations are made separately for each one of the thirteen plants that produced electricity in 2007, because the lignite-fired thermal plants in Turkey are installed near the regions where the lignite is mined, and characteristics and composition of lignite used in each power plant are quite different from a region to another. Emission factors methodology is used for the estimations. The emission factors obtained from well-known literature are then modified depending on local moisture content of lignite. Emission rates and specific emissions (per MWh) of the pollutants from the plants without electrostatic precipitators and flue-gas desulfurization systems are found to be higher than emissions from the plants having electrostatic precipitators and flue -gas desulfurization systems. Finally a projection for the future emissions due to lignite-based power plants is given. Predicted demand for the increasing generation capacity based on the lignite-fired thermal power plant, from 2008 to 2017 is around 30%. 39 refs., 13 figs., 10 tabs.

Nurten Vardar; Zehra Yumurtaci [Yildiz Technical University Mechanical Engineering Faculty, Istanbul (Turkey)

2010-01-15T23:59:59.000Z

Note: This page contains sample records for the topic "desulfurization systems electrostatic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Technical report on the General Electric model #1 electrostatic electron microscope  

E-Print Network [OSTI]

screen Vacuum Chamber' Figi 5. Sectionalized View of the Lens System of the General Electric Electron microscope. which is held in place with the micalex insulatoz s is a source of many difficulties. Ii' the combination of the insulators and central..., or if desired to give the beam a diverging angle with the optical axis. The filament of the General Electric Electron Gun is heated with 60 cycle alternating current. This gives rise to an alternat1ng field about the f1lament which will deflect...

Druce, Albert J

1950-01-01T23:59:59.000Z

402

Avoid stainless steel failures in FGD systems  

SciTech Connect (OSTI)

Preventing pitting and localized corrosion is the key to success where low maintenance and high reliability are rime considerations in flue-gas desulfurization (FGD) designs. Knowing when to use a stainless steel, and when not to, is crucial. Operating parameters and environmental factors greatly affect alloy performance, especially pH, temperature, and chloride and oxygen levels. Failures of stainless steels can be avoided by understanding their limits in light of these variables. This article will focus on the capabilities of Types 316L, 317L, 317LM, 317LMN, 904L, and 6% Mo stainless steels and their applications, as well as provide details on unique combination of mechanical properties and corrosion resistance of the 22% Cr duplex and 25% Cr super-duplex stainless steels in acid chloride systems. Guidelines will be presented on methods to prevent intergranular corrosion, stress corrosion cracking, and pitting and crevice corrosion, and what process steps can be taken to assure reasonable performance of marginal alloy selections. Emphasis will be on the lime/limestone wet scrubbing process and the quencher/absorber.

Mills, J.P.; Schillmoller, C.M.

1995-11-01T23:59:59.000Z

403

Electrostatic binding of bicarbonate and formate in viologen-based redox polymers: importance in catalytic reduction of bicarbonate to formate  

SciTech Connect (OSTI)

The relative importance of electrostatic binding of CO3H and HCO2 in a redox polymer derived from an N,N'-dialkyl-4,4'-bipyridinium monomer has been investigated by Fourier transform infrared (FTIR) spectroscopy. At 298 K and a total concentration of C-containing species of 0.1 M the two species are equally firmly bound in a polymer immobilized on a single-crystal Si electrode surface. When the concentration of C-containing species is 1.0 M, the CO3H ion is more firmly bound by about a factor of 2.5, and at a total concentration of 3.0 M the CO3H ion is about 7 times more firmly bound than the HCO2 ion. The HCO2 and Cl anions are equally firmly bound at 1.0 M total anion concentration. On the basis of the lack of change in the cyclic voltammetry response of a derivatized electrode in 1.0 M Na(CO3H) or Na(HCO2) compared to 1.0 M NaCl, the exchange rate of the C-containing anions does not appear to be a factor that would limit the rate of reduction of the CO3H ion at an electrode modified with the polymer and impregnated with Pd(0).

Andre, J.F.; Wrighton, M.S.

1985-12-04T23:59:59.000Z

404

Kinetic Electrostatic Electron Nonlinear (KEEN) Waves and their Interactions Driven by the Ponderomotive Force of Crossing Laser Beams  

E-Print Network [OSTI]

We have found, using 1D periodic Vlasov-Poisson simulations, new nonlinear, nonstationary, stable, long lived, coherent structures in phase space, called kinetic electrostatic electron nonlinear (KEEN) waves. Ponderomotively driven for a short period of time, at a particular frequency and wavenumber, well inside the band gap that was thought to exist between electron plasma and electron acoustic wave frequencies, KEEN waves are seen to self-consistently form, and persist for thousands of plasma periods. KEEN waves are comprised of 4 or more significant phase-locked harmonic modes which persist only when driven sufficiently strongly. They also merge when two or more at different frequencies are driven sequentially. However, the final stable KEEN state that emerges is highly sensitive to their relative order of excitation. KEEN waves also interact quite strongly with electron plasma waves (EPW) especially when their harmonics are close to being resonant with the EPW frequency at the same k. The common assumption that whenever sufficiently large amplitude coherent laser energy is present in an unmagnetized plasma, EPWs and IAWs are the only waves with which the electromagnetic energy can interact coherently may require reconsideration.

Bedros Afeyan; K. Won; V. Savchenko; T. Johnston; A. Ghizzo; P. Bertrand

2012-10-30T23:59:59.000Z

405

Simulation and optimization of a 10 A electron gun with electrostatic compression for the electron beam ion source  

SciTech Connect (OSTI)

Increasing the current density of the electron beam in the ion trap of the Electron Beam Ion Source (EBIS) in BNL's Relativistic Heavy Ion Collider facility would confer several essential benefits. They include increasing the ions' charge states, and therefore, the ions' energy out of the Booster for NASA applications, reducing the influx of residual ions in the ion trap, lowering the average power load on the electron collector, and possibly also reducing the emittance of the extracted ion beam. Here, we discuss our findings from a computer simulation of an electron gun with electrostatic compression for electron current up to 10 A that can deliver a high-current-density electron beam for EBIS. The magnetic field in the cathode-anode gap is formed with a magnetic shield surrounding the gun electrodes and the residual magnetic field on the cathode is (5 Division-Sign 6) Gs. It was demonstrated that for optimized gun geometry within the electron beam current range of (0.5 Division-Sign 10) A the amplitude of radial beam oscillations can be maintained close to 4% of the beam radius by adjusting the injection magnetic field generated by a separate magnetic coil. Simulating the performance of the gun by varying geometrical parameters indicated that the original gun model is close to optimum and the requirements to the precision of positioning the gun elements can be easily met with conventional technology.

Pikin, A.; Beebe, E. N.; Raparia, D. [Brookhaven National Laboratory, Upton, New York 11973 (United States)

2013-03-15T23:59:59.000Z

406

Large-Scale Mercury Control Technology Testing for Lignite-Fired Utilities - Oxidation Systems for Wet FGD  

SciTech Connect (OSTI)

Mercury (Hg) control technologies were evaluated at Minnkota Power Cooperative's Milton R. Young (MRY) Station Unit 2, a 450-MW lignite-fired cyclone unit near Center, North Dakota, and TXU Energy's Monticello Steam Electric Station (MoSES) Unit 3, a 793-MW lignite--Powder River Basin (PRB) subbituminous coal-fired unit near Mt. Pleasant, Texas. A cold-side electrostatic precipitator (ESP) and wet flue gas desulfurization (FGD) scrubber are used at MRY and MoSES for controlling particulate and sulfur dioxide (SO{sub 2}) emissions, respectively. Several approaches for significantly and cost-effectively oxidizing elemental mercury (Hg{sup 0}) in lignite combustion flue gases, followed by capture in an ESP and/or FGD scrubber were evaluated. The project team involved in performing the technical aspects of the project included Babcock & Wilcox, the Energy & Environmental Research Center (EERC), the Electric Power Research Institute, and URS Corporation. Calcium bromide (CaBr{sub 2}), calcium chloride (CaCl{sub 2}), magnesium chloride (MgCl{sub 2}), and a proprietary sorbent enhancement additive (SEA), hereafter referred to as SEA2, were added to the lignite feeds to enhance Hg capture in the ESP and/or wet FGD. In addition, powdered activated carbon (PAC) was injected upstream of the ESP at MRY Unit 2. The work involved establishing Hg concentrations and removal rates across existing ESP and FGD units, determining costs associated with a given Hg removal efficiency, quantifying the balance-of-plant impacts of the control technologies, and facilitating technology commercialization. The primary project goal was to achieve ESP-FGD Hg removal efficiencies of {ge}55% at MRY and MoSES for about a month.

Steven A. Benson; Michael J. Holmes; Donald P. McCollor; Jill M. Mackenzie; Charlene R. Crocker; Lingbu Kong; Kevin C. Galbreath

2007-03-31T23:59:59.000Z

407

Evaluation of Insulation Systems for the Optimal Design of High Voltage Pulse Transformers  

E-Print Network [OSTI]

This paper presents a study for the design of the insulation systems of high voltage pulse transformer based on experimental tests and numerical simulations. Data of high voltage tests on solid and liquid insulation materials are presented and discussed. The understanding of each part of the insulation is supported by electrostatic fields simulations.

Sylvain, Candolfi; Davide, Aguglia; Philippe, Viarouge; Jürgen, Biela; Jerome, Cros

2015-01-01T23:59:59.000Z

408

Pressurized fluidized-bed hydroretorting of Eastern oil shales -- Sulfur control  

SciTech Connect (OSTI)

This topical report on Sulfur Control'' presents the results of work conducted by the Institute of Gas Technology (IGT), the Illinois Institute of Technology (IIT), and the Ohio State University (OSU) to develop three novel approaches for desulfurization that have shown good potential with coal and could be cost-effective for oil shales. These are (1) In-Bed Sulfur Capture using different sorbents (IGT), (2) Electrostatic Desulfurization (IIT), and (3) Microbial Desulfurization and Denitrification (OSU and IGT). The objective of the task on In-Bed Sulfur Capture was to determine the effectiveness of different sorbents (that is, limestone, calcined limestone, dolomite, and siderite) for capturing sulfur (as H{sub 2}S) in the reactor during hydroretorting. The objective of the task on Electrostatic Desulfurization was to determine the operating conditions necessary to achieve a high degree of sulfur removal and kerogen recovery in IIT's electrostatic separator. The objectives of the task on Microbial Desulfurization and Denitrification were to (1) isolate microbial cultures and evaluate their ability to desulfurize and denitrify shale, (2) conduct laboratory-scale batch and continuous tests to improve and enhance microbial removal of these components, and (3) determine the effects of processing parameters, such as shale slurry concentration, solids settling characteristics, agitation rate, and pH on the process.

Roberts, M.J.; Abbasian, J.; Akin, C.; Lau, F.S.; Maka, A.; Mensinger, M.C.; Punwani, D.V.; Rue, D.M. (Institute of Gas Technology, Chicago, IL (United States)); Gidaspow, D.; Gupta, R.; Wasan, D.T. (Illinois Inst. of Tech., Chicago, IL (United States)); Pfister, R.M.: Krieger, E.J. (Ohio State Univ., Columbus, OH (United States))

1992-05-01T23:59:59.000Z

409

Staged fluidized-bed combustion and filter system  

DOE Patents [OSTI]

A staged fluidized-bed combustion and filter system for substantially reducing the quantity of waste through the complete combustion into ash-type solids and gaseous products. The device has two fluidized-bed portions, the first primarily as a combustor/pyrolyzer bed, and the second as a combustor/filter bed. The two portions each have internal baffles to define stages so that material moving therein as fluidized beds travel in an extended route through those stages. Fluidization and movement is achieved by the introduction of gases into each stage through a directional nozzle. Gases produced in the combustor/pyrolyzer bed are permitted to travel into corresponding stages of the combustor/filter bed through screen filters that permit gas flow but inhibit solids flow. Any catalyst used in the combustor/filter bed is recycled. The two beds share a common wall to minimize total volume of the system. A slightly modified embodiment can be used for hot gas desulfurization and sorbent regeneration. Either side-by-side rectangular beds or concentric beds can be used. The system is particularly suited to the processing of radioactive and chemically hazardous waste.

Mei, Joseph S. (Morgantown, WV); Halow, John S. (Waynesburg, PA)

1994-01-01T23:59:59.000Z

410

Proceedings of the coal-fired power systems 94: Advances in IGCC and PFBC review meeting. Volume 1  

SciTech Connect (OSTI)

The Coal-Fired Power Systems 94 -- Advances in IGCC and PFBC Review Meeting was held June 21--23, 1994, at the Morgantown Energy Center (METC) in Morgantown, West Virginia. This Meeting was sponsored and hosted by METC, the Office of Fossil Energy, and the US Department of Energy (DOE). METC annually sponsors this conference for energy executives, engineers, scientists, and other interested parties to review the results of research and development projects; to discuss the status of advanced coal-fired power systems and future plans with the industrial contractors; and to discuss cooperative industrial-government research opportunities with METC`s in-house engineers and scientists. Presentations included industrial contractor and METC in-house technology developments related to the production of power via coal-fired Integrated Gasification Combined Cycle (IGCC) and Pressurized Fluidized Bed Combustion (PFBC) systems, the summary status of clean coal technologies, and developments and advancements in advanced technology subsystems, such as hot gas cleanup. A keynote speaker and other representatives from the electric power industry also gave their assessment of advanced power systems. This meeting contained 11 formal sessions and one poster session, and included 52 presentations and 24 poster presentations. Volume I contains papers presented at the following sessions: opening commentaries; changes in the market and technology drivers; advanced IGCC systems; advanced PFBC systems; advanced filter systems; desulfurization system; turbine systems; and poster session. Selected papers have been processed separately for inclusion in the Energy Science and Technology Database.

McDaniel, H.M.; Staubly, R.K.; Venkataraman, V.K. [eds.

1994-06-01T23:59:59.000Z

411

TVA`s Cumberland Units 1&2 SO{sub 2} removal system - an update  

SciTech Connect (OSTI)

Tennessee Valley Authority`s Cumberland Fossil Plant (CUF) is a Phase I facility listed under the 1990 CAA Amendments. Units 1 & 2 are two 1300 MWe coal fired units which presently bum an eastern bituminous coal containing approximately 2.8% sulfur. The Flue Gas Desulfurization (FGD) system reduces sulfur dioxide (SO{sub 2}) emissions from Units 1 and 2 by means of wet limestone - forced oxidation scrubbing. The absorber modules were provided by ABB Environmental Systems (ABBES) with balance of plant engineering, construction management, and startup provided by Raytheon Engineers and Constructors (RE&C) under a partnership arrangement with TVA. The FGD systems for Unit 1 & 2 were brought on-line October 12, 1994 and December 14, 1994, respectively. This paper will present a brief description of the overall project, the design basis, challenging problems and solutions during construction and initial startup. Specific topics will include: (1) Optimization studies underway; (2) Unique design aspects of the facility; (3) A description of the absorber and supporting systems including the limestone barge unloader, ball mill system for reagent preparation, and draft system upgrades; and (4) Experience gained in management of a large project under the unique partnership agreement.

Buckner, J.H. [Tennessee Valley Authority, Chattanooga, TN (United States); Brodsky, I.S. [Raytheon Engineers & Constructors, Philadelphia, PA (United States); Muraskin, D.J. [ABB Environmental Systems, Birmingham, AL (United States)

1995-06-01T23:59:59.000Z

412

Excitons in Electrostatic Lattices /  

E-Print Network [OSTI]

modern day photovoltaics, optoelectronics, plasmonics, andand every advance in optoelectronics requires a new level ofdevelopment of both optoelectronics and photovoltaics. The

Remeika, Mikas

2013-01-01T23:59:59.000Z

413

Excitons in Electrostatic Lattices /  

E-Print Network [OSTI]

which are similar to Josephson junction arrays (see sectionsimilar to that of Josephson junction arrays. Here the phase

Remeika, Mikas

2013-01-01T23:59:59.000Z

414

Electrostatics of moving plasma  

SciTech Connect (OSTI)

The stability of charge distribution over the surface of a conducting body in moving plasma is analyzed. Using a finite-width plate streamlined by a cold neutralized electron flow as an example, it is shown that an electrically neutral body can be unstable against the development of spontaneous polarization. The plasma parameters at which such instability takes place, as well as the frequency and growth rate of the fundamental mode of instability, are determined.

Ignatov, A. M. [Russian Academy of Sciences, Prokhorov General Physics Institute (Russian Federation)] [Russian Academy of Sciences, Prokhorov General Physics Institute (Russian Federation)

2013-07-15T23:59:59.000Z

415

Excitons in Electrostatic Lattices /  

E-Print Network [OSTI]

6.4 Exciton Energy and Intensity Modulation Measurement .6.4: Observable energy and intensity modulation at differentmodulations in energy and intensity (red, right magnified

Remeika, Mikas

2013-01-01T23:59:59.000Z

416

The self-consistent parallel electric field due to electrostatic ion-cyclotron turbulence in downward auroral-current regions of the Earth's magnetosphere. IV  

SciTech Connect (OSTI)

The physical processes that determine the self-consistent electric field (E{sub ||}) parallel to the magnetic field have been an unresolved problem in magnetospheric physics for over 40 years. Recently, a new multimoment fluid theory was developed for inhomogeneous, nonuniformly magnetized plasma in the guiding-center and gyrotropic approximation that includes the effect of electrostatic, turbulent, wave-particle interactions (see Jasperse et al. [Phys. Plasmas 13, 072903 (2006); ibid.13, 112902 (2006)]). In the present paper and its companion paper [Jasperse et al., Phys. Plasmas 17, 062903 (2010)], which are intended as sequels to the earlier work, a fundamental model for downward, magnetic field-aligned (Birkeland) currents for quasisteady conditions is presented. The model includes the production of electrostatic ion-cyclotron turbulence in the long-range potential region by an electron, bump-on-tail-driven ion-cyclotron instability. Anomalous momentum transfer (anomalous resistivity) by itself is found to produce a very small contribution to E{sub ||}; however, the presence of electrostatic, ion-cyclotron turbulence has a very large effect on the altitude dependence of the entire quasisteady solution. Anomalous energy transfer (anomalous heating and cooling) modifies the density, drift, and temperature altitude profiles and hence the generalized parallel-pressure gradients and mirror forces in the electron and ion momentum-balance equations. As a result, |E{sub ||}| is enhanced by nearly a factor of 40 compared to its value when turbulence is absent. The space-averaged potential increase associated with the strong double layer at the bottom of the downward-current sheet is estimated using the FAST satellite data and the multimoment fluid theory.

Jasperse, John R.; Basu, Bamandas [Air Force Research Laboratory, Space Vehicles Directorate, Hanscom AFB, Massachusetts 01731 (United States); Lund, Eric J. [Space Science Center, University of New Hampshire, Durham, New Hampshire 03824 (United States); Grossbard, Neil [Institute for Scientific Research, Boston College, Chestnut Hill, Massachusetts 02467 (United States)

2010-06-15T23:59:59.000Z

417

Electrostatic self-energy of a partially formed spherical shell in salt solution: application to stability of tethered and fluid shells -- viruses and vesicles  

E-Print Network [OSTI]

We investigate the electrostatics of a partially formed, charged spherical shell in a salt solution. We solve the problem numerically at the Poisson-Boltzmann level and analytically in the Debye-Huckel regime. From the results on energetics of partially formed shells we examine the stability of tethered (crystalline) and fluid shells towards rupture. We clearly delineate different regimes of stability towards rupture, where, for fluid shells, we also include the effects of bending elasticity of the shells. Our analysis shows how charging of the shell induces its instability towards rupture but also provides insight regarding growth of charged shells.

Anze Losdorfer Bozic; Antonio Siber; Rudolf Podgornik

2011-04-24T23:59:59.000Z

418

APBF-DEC Heavy Duty NOx Adsorber/DPF Project: Heavy Duty Linehaul...  

Broader source: Energy.gov (indexed) [DOE]

Quality Management District G0075 3 Objectives Design and build engine and emissions control system to permit regeneration and desulfurization under transient and steady state...

419

acid fgd additives: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of sulfur dioxide into the atmosphere. Efforts to curb damage to the environment by acid rain has necessitated the construction of flue gas desulfurization (FGD) systems...

420

CX-004983: Categorical Exclusion Determination | Department of...  

Broader source: Energy.gov (indexed) [DOE]

FMC Corporation technology to reduce nitrous oxide emissions and potentially reduce mercury using a spray dryer absorber flue gas desulfurization system. DOCUMENT(S) AVAILABLE...

Note: This page contains sample records for the topic "desulfurization systems electrostatic" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

NETL F 451.1-1/1 Categorical Exclusion (CX) Designation Form  

Broader source: Energy.gov (indexed) [DOE]

proprietary FMC Corporation technology to reduce NOx emissions and potentially reduce mercury using a spray dryer absorber flue gas desulfurization system. 03 18 2010 Andrew P....

422

U.S. DEPARTMENT OF ENERGY - NETL CATEGORICAL EXCLUSION (CX) DESIGNATIO...  

Broader source: Energy.gov (indexed) [DOE]

Golden, CO A Novel Biogas Desulfurization Sorbent Technology for Molten Carbonate Fuel Cell- Based Combined Heat and Power Systems Develop an expendable, high capacity sorbent to...

423

Anomalous momentum and energy transfer rates for electrostatic ion-cyclotron turbulence in downward auroral-current regions of the Earth's magnetosphere. III  

SciTech Connect (OSTI)

Recently, a new multimoment fluid theory was developed for inhomogeneous, nonuniformly magnetized plasma in the guiding-center and gyrotropic approximation that includes the effect of electrostatic, turbulent, wave-particle interactions (see Jasperse et al. [Phys. Plasmas 13, 072903 (2006); ibid.13, 112902 (2006)]). In the present paper, which is intended as a sequel, it is concluded from FAST satellite data that the electrostatic ion-cyclotron turbulence that appears is due to the operation of an electron, bump-on-tail-driven ion-cyclotron instability for downward currents in the long-range potential region of the Earth's magnetosphere. Approximate closed-form expressions for the anomalous momentum and energy transfer rates for the ion-cyclotron turbulence are obtained. The turbulent, inhomogeneous, nonuniformly magnetized, multimoment fluid theory given above, in the limit of a turbulent, homogeneous, uniformly magnetized, quasisteady plasma, yields the well-known formula for the anomalous resistivity given by Gary and Paul [Phys. Rev. Lett. 26, 1097 (1971)] and Tange and Ichimaru [J. Phys. Soc. Jpn. 36, 1437 (1974)].

Jasperse, John R.; Basu, Bamandas [Air Force Research Laboratory, Space Vehicles Directorate, Hanscom AFB, Massachusetts 01731 (United States); Lund, Eric J. [Space Science Center, University of New Hampshire, Durham, New Hampshire 03824 (United States); Grossbard, Neil [Institute for Scientific Research, Boston College, Chestnut Hill, Massachusetts 02467 (United States)

2010-06-15T23:59:59.000Z

424

Evaluation of gasification and gas cleanup processes for use in molten carbonate fuel cell power plants. Final report. [Contains lists and evaluations of coal gasification and fuel gas desulfurization processes  

SciTech Connect (OSTI)

This report satisfies the requirements for DOE Contract AC21-81MC16220 to: List coal gasifiers and gas cleanup systems suitable for supplying fuel to molten carbonate fuel cells (MCFC) in industrial and utility power plants; extensively characterize those coal gas cleanup systems rejected by DOE's MCFC contractors for their power plant systems by virtue of the resources required for those systems to be commercially developed; develop an analytical model to predict MCFC tolerance for particulates on the anode (fuel gas) side of the MCFC; develop an analytical model to predict MCFC anode side tolerance for chemical species, including sulfides, halogens, and trace heavy metals; choose from the candidate gasifier/cleanup systems those most suitable for MCFC-based power plants; choose a reference wet cleanup system; provide parametric analyses of the coal gasifiers and gas cleanup systems when integrated into a power plant incorporating MCFC units with suitable gas expansion turbines, steam turbines, heat exchangers, and heat recovery steam generators, using the Westinghouse proprietary AHEAD computer model; provide efficiency, investment, cost of electricity, operability, and environmental effect rankings of the system; and provide a final report incorporating the results of all of the above tasks. Section 7 of this final report provides general conclusions.

Jablonski, G.; Hamm, J.R.; Alvin, M.A.; Wenglarz, R.A.; Patel, P.

1982-01-01T23:59:59.000Z

425

Molten-Caustic-Leaching (MCL or Gravimelt) System Integration Project  

SciTech Connect (OSTI)

This is a report of the results obtained from the operation of an integrated test circuit for the Molten-Caustic-Leaching (MCL or Gravimelt) process for the desulfurization and demineralization of coal. The objectives of operational testing of the 20 pounds of coal per hour integrated MCL test circuit are: (1) to demonstrate the technical capability of the process for producing a demineralized and desulfurized coal that meets New Source Performance Standards (NSPS); (2) to determine the range of effective process operation; (3) to test process conditions aimed at significantly lower costs; and (4) to deliver product coal.

Not Available

1990-11-01T23:59:59.000Z

426

TI-59 programmable calculator programs for in-stack opacity, venturi scrubbers, and electrostatic precipitators. User manual Jul 78-Jul 79  

SciTech Connect (OSTI)

The report explains the basic concepts of in-stack opacity as measured by in-stack opacity monitors. Also included are calculator programs that model the performance of venturi scrubbers and electrostatic precipitators. The effect of particulate control devices on in-stack opacity can be predicted by using these programs. The size distribution data input can be either in lognormal or histogram format. The opacity is calculated using Deirmendjian's approximation to Mie series to obtain extinction efficiencies. An alternative opacity program employing the exact Mie series solution is also described. The running time for this program is about 8 hours; that for the approximation program is 30 minutes. The accuracy of these programs is as good as the measured data input.

Cowen, S.J.; Ensor, D.S.; Sparks, L.E.

1980-05-01T23:59:59.000Z

427

Comparison of organic combustion products in fly ash collected by a venturi wet scrubber and an electrostatic precipitator at a coal-fired power station  

SciTech Connect (OSTI)

Organic compounds recovered from fly ash collected by an electrostatic precipitator (ESP) and a venturi wet scrubber (WS) at a coal-fired power station were analysed. Organic constituents in extracts of solid waste included large numbers of aliphatic and aromatic compounds. A series of normal C/sub 15/-C/sub 30/ paraffins was found in the aliphatic fractions. The aromatic compounds were of 1,2,3 and 4 rings. Polynuclear aromatic hydrocarbons containing more than 4 rings were shown to be poorly recovered. Comparison of organic constituents in extracts of fly ash from the WS and the ESP showed that ESP extracts contained more compounds in greater quantities. The types and quantities of organic compounds recovered are not expected to present any environmental hazard.

Harrison, F.L.

1985-02-01T23:59:59.000Z

428

In Situ Electrostatic Separation of Ambient PM2.5 into Source-Specific Fractions During Collection in a FRM Sampler  

SciTech Connect (OSTI)

Coal combustion is generally viewed as a major source of PM2.5 emissions into the atmosphere. For some time, toxicologists have been asking for an exposure environment enriched with the coal combustion source specific PM{sub 2.5} to conduct meaningful exposure studies to better understand the mechanisms of the adverse health effects of coal combustion specific PM2.5 in the ambient environment. There are several unique characteristics of primary PM generated from coal combustion. In this research project, an attempt has been made to exploit some of the unique properties of PM generated from coal fired power plants to preferentially separate them out from the rest of the primary and secondary PM in the ambient environment. An existing FRM sampler used for monitoring amount of PM{sub 2.5} in the ambient air is modified to incorporate an electrostatic field. A DC corona charging device is also installed at the ambient air inlet to impart positive or negative charge to the PM. Visual Basic software has been written to simulate the lateral movement of PM as it passes through the electrostatic separator under varying operating conditions. The PM samples collected on polycarbonate filters under varying operating conditions were extensively observed for clustering and/or separation of PM in the direction parallel to the electric field. No systematic PM separation was observed under any of the operating conditions. A solution to overcome this kind of turbulence caused remixing has been offered. However, due to major programmatic changes in the DOE UCR program, there are no venues available to further pursue this research.

Naresh Shah; Frank E. Huggins; Gerald P. Huffman

2006-07-31T23:59:59.000Z

429

Altering the Electrostatic Potential in the Major Groove: Thermodynamic and Structural Characterization of 7-Deaza-2;#8242;-deoxyadenosine:dT Base Pairing in DNA  

SciTech Connect (OSTI)

As part of an ongoing effort to explore the effect of major groove electrostatics on the thermodynamic stability and structure of DNA, a 7-deaza-2'-deoxyadenosine:dT (7-deaza-dA:dT) base pair in the Dickerson-Drew dodecamer (DDD) was studied. The removal of the electronegative N7 atom on dA and the replacement with an electropositive C-H in the major groove was expected to have a significant effect on major groove electrostatics. The structure of the 7-deaza-dA:dT base pair was determined at 1.1 {angstrom} resolution in the presence of Mg{sup 2+}. The 7-deaza-dA, which is isosteric for dA, had minimal effect on the base pairing geometry and the conformation of the DDD in the crystalline state. There was no major groove cation association with the 7-deaza-dA heterocycle. In solution, circular dichroism showed a positive Cotton effect centered at 280 nm and a negative Cotton effect centered at 250 nm that were characteristic of a right-handed helix in the B-conformation. However, temperature-dependent NMR studies showed increased exchange between the thymine N3 imino proton of the 7-deaza-dA:dT base pair and water, suggesting reduced stacking interactions and an increased rate of base pair opening. This correlated with the observed thermodynamic destabilization of the 7-deaza-dA modified duplex relative to the DDD. A combination of UV melting and differential scanning calorimetry experiments were conducted to evaluate the relative contributions of enthalpy and entropy in the thermodynamic destabilization of the DDD. The most significant contribution arose from an unfavorable enthalpy term, which probably results from less favorable stacking interactions in the modified duplex, which was accompanied by a significant reduction in the release of water and cations from the 7-deaza-dA modified DNA.

Kowal, Ewa A.; Ganguly, Manjori; Pallan, Pradeep S.; Marky, Luis A.; Gold, Barry; Egli, Martin; Stone, Michael P. (Pitt); (Vanderbilt); (Nebraska-Med)

2012-02-15T23:59:59.000Z

430

How does this stack up for removing SO/sub 2/ and particles  

SciTech Connect (OSTI)

Coal-fired boiler emissions are usually controlled by one of the following methods: (1) a high velocity spray tower for flue gas desulfurization (FGD) installed downstream of a dry electrostatic precipitator, or a baghouse which removes the fly ash. Lime or limestone is used for neutralization; (2) a high energy venturi scrubber for fly ash removal followed by a high velocity spray tower for FGD. The alkaline ash, with lime or limestone added is used for neutralization and saves alkali costs. Peabody Process Systems has been investigating an additional system comprising a low pressure drop gas quencher and an FRG spray tower with a Wet Tubular Precipitator (WTP) installed on top of the spray tower. The alkalinity in the ash, augmented with lime or limestone, can be used for neutralization if the full fly ash load goes into the tower.

Bakke, E.

1981-03-01T23:59:59.000Z

431

Remote measurement of sulfur dioxide emissions using an ultraviolet light sensitive video system  

SciTech Connect (OSTI)

Remote measurements of SO/sub 2/ emissions and plume velocities were made with a portable ultraviolet light-sensitive video system and compared with EPA in-stack compliance measurement methods. The instrument system measures the ultraviolet light absorption of SO/sub 2/ and movement of SO/sub 2/ fluctuations in the effluent plume and relates these measurements to the SO/sub 2/ concentration and velocity of the plume. Laboratory and field tests were conducted to establish the potential for using this technique for rapid surveillance of SO/sub 2/ emissions. The effects caused by submicron aerosols also were investigated. The field tests were performed on two occasions. On the first occasion, SO/sub 2/ and plume velocity measurements were made at a typical coal-fired power plant with flue gas desulfurization (FGD) controls (concentrations ranged from 80 to 365 ppm). The second occasion involved participation in an urban particulate modeling study, which resulted in routine SO/sub 2/ emission measurements performed at 12 industrial sites. The results of smoke generator and field tests indicate that the sulfur dioxide concentration of smoke stack emissions can be made with an accuracy less than +/-120 ppm (relative to the EPA stack test compliance method), provided the particulate opacity of the emissions is less than 22 percent. The velocity measurement feature of the instrument correlated poorly with the EPA compliance method for stack gas velocity.

McElhoe, H.B.; Conner, W.D.

1986-01-01T23:59:59.000Z

432

ECE Department, Boston University 4/17/2011 Title Electrostatic Dry Powder Inhaler for Constant-Dose  

E-Print Network [OSTI]

for improved drug formulation, (2) Design of an electrodynamic dispersion system for respiratory drug delivery-Dose Respiratory Drug Delivery (BME-ECE-ME) Technical areas (1) Pharmaceutical particle surface engineering design process, and (3) Precision mechanical design of an inhalation chamber with computer control Customer

433

Emissions control: Despite market uncertainty, a few new approaches come forward  

SciTech Connect (OSTI)

Innovative business practices that substantially reduce costs prevail over technological risk. Despite this, several new processes are now ready for commercial deployment as part of the nation`s emissions-control effort. This article describes these processes and their relative economic and technical merits. The DOE Clean Coal Technology Demonstration Program is almost a decade old. Several important control technologies have emerged from that program that could challenge conventional wisdom on process selection and site management. Combined with several other technologies funded by EPRI and others, now ready for commercial deployment, process selection has become more than choosing between a fabric filter (FF) and an electrostatic precipitator (ESP), a wet or dry flue-gas desulfurization (FGD) system, or a selective catalytic reduction (SCR) or selective non-catalytic reduction (SNCR) process.

Makansi, J.

1996-03-01T23:59:59.000Z

434

A new class of high force, low-voltage, compliant actuation system  

SciTech Connect (OSTI)

Although many actuators employing electrostatic comb drives have been demonstrated in a laboratory environment, widespread acceptance in mass produced microelectromechanical systems (MEMS) may be limited due to issues associated with low drive force, large real estate demands, high operating voltages, and reliability concerns due to stiction. On the other hand, comb drives require very low drive currents, offer predictable response, and are highly compatible with the fabrication technology. The expand the application space and facilitate the widespread deployment of self-actuated MEMS, a new class of advanced actuation systems has been developed that maintains the highly desirable aspects of existing components, while significantly diminishing the issues that could impede large scale acceptance. In this paper, the authors will present low-voltage electrostatic actuators that offer a dramatic increase in force over conventional comb drive designs. In addition, th