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Sample records for design optics synthesis

  1. Design, synthesis, and stability of organic glasses for advanced optical applications

    SciTech Connect (OSTI)

    Chen, S.H.; Shi, H.; Mastrangelo, J.C.; Blanton, T.N.

    1995-12-31

    Organic materials have been actively pursued in recent years for various advanced optical applications based on active and passive device concepts. Polymeric materials are unique in their ability to form glassy films or fibers with good morphological stability, whereas low molar mass counterparts are characterized by relative case of processing. To take advantage of the inherent merits of these two distinctive classes of materials, a novel molecular design concept is formulated in which functional moieties are chemically bonded to excluded-volume cores, resulting in amorphous or liquid crystalline glasses. A series of model compounds have been synthesized based on mesogenic and NLO moieties attached to cyclohexane and bicyclooctene rings. Morphological stability has also characterized in terms of crystallization velocity as a function of temperature. It is concluded that stereochemistry plays a critical role in the ability to vitrify and that low molar mass systems can be as morphologically stable as typical slowly crystallizing polymers, e.g. polystyrene.

  2. Optical Design for Extremely Large Telescope Adaptive Optics...

    Office of Scientific and Technical Information (OSTI)

    ThesisDissertation: Optical Design for Extremely Large Telescope Adaptive Optics Systems Citation Details In-Document Search Title: Optical Design for Extremely Large Telescope...

  3. Optical Design for Extremely Large Telescope Adaptive Optics...

    Office of Scientific and Technical Information (OSTI)

    ThesisDissertation: Optical Design for Extremely Large Telescope Adaptive Optics Systems Citation Details In-Document Search Title: Optical Design for Extremely Large Telescope ...

  4. Optical Design for Extremely Large Telescope Adaptive Optics Systems

    Office of Scientific and Technical Information (OSTI)

    (Thesis/Dissertation) | SciTech Connect Thesis/Dissertation: Optical Design for Extremely Large Telescope Adaptive Optics Systems Citation Details In-Document Search Title: Optical Design for Extremely Large Telescope Adaptive Optics Systems Designing an adaptive optics (AO) system for extremely large telescopes (ELT's) will present new optical engineering challenges. Several of these challenges are addressed in this work, including first-order design of multi-conjugate adaptive optics

  5. Design of Nanocrystal Solids for Photoelectrochemical Synthesis...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Design of Nanocrystal Solids for Photoelectrochemical Synthesis of Liquid Fuels The proposed research project seeks to exploit the unique size-, composition-, and surface-tunable...

  6. Core Perylene Diimide Designs via Direct Bay and Ortho (Poly)trifluoromethylation: Synthesis, Isolation, X-ray Structures, Optical and Electronic Properties

    SciTech Connect (OSTI)

    Clikeman, Tyler T.; Bukovsky, Eric V.; Wang, Xue B.; Chen, Yu-Sheng; Rumbles, Garry; Strauss, Steven H.; Boltalina, Olga V.

    2015-10-01

    We developed an efficient solvent- and catalyst-free direct polytrifluoromethylation of solid perylene-3,4,9,10-tetracarboxylic dianhydride that produced a new family of (poly)perfluoroalkyl bay and ortho substituted PDIs with two different imide substituents. Direct hydrogen substitution with CN group led to the synthesis of a cyanated perfluoroalkyl PDI derivative for the first time. Absorption, steady-state and time-resolved emission, X-ray diffraction, electrochemical, and gas-phase electron affinity data allowed for systematic studies of substitution effects at bay, ortho, and imide positions in the new PDIs. Solid-state packing showed remarkable variations in the intermolecular interactions that are important for charge transport and photophysical properties. Analysis of the electrochemical data for 143 electron poor PDIs, including newly reported compounds, revealed some general trends and peculiar effects of electron withdrawing group substitution at all three positions.

  7. Design and Synthesis of Novel Diluted Magnetic Semiconductors...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Design and Synthesis of Novel Diluted Magnetic Semiconductors Diluted magnetic semiconductors (DMSs) are semiconductors doped with small amounts of magnetic active transition...

  8. Gaussian Quadrature for Optical Design with Non-circular Pupils...

    Office of Scientific and Technical Information (OSTI)

    Gaussian Quadrature for Optical Design with Non-circular Pupils and Fields, and Broad Wavelength Ranges Citation Details In-Document Search Title: Gaussian Quadrature for Optical...

  9. LSST Camera Optics Design (Conference) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    LSST Camera Optics Design Citation Details In-Document Search Title: LSST Camera Optics Design You are accessing a document from the Department of Energy's (DOE) SciTech...

  10. Gaussian Quadrature for Optical Design with Non-circular Pupils...

    Office of Scientific and Technical Information (OSTI)

    Optical Design with Non-circular Pupils and Fields, and Broad Wavelength Ranges Citation Details In-Document Search Title: Gaussian Quadrature for Optical Design with Non-circular ...

  11. Optical Design Capabilities at Lawrence Livermore National Laboratory

    SciTech Connect (OSTI)

    Lawson, J K

    2002-12-30

    Optical design capabilities continue to play the same strong role at Lawrence Livermore National Laboratory (LLNL) that they have played in the past. From defense applications to the solid-state laser programs to the Atomic Vapor Laser Isotope Separation (AVLIS), members of the optical design group played critical roles in producing effective system designs and are actively continuing this tradition. This talk will explain the role optical design plays at LLNL, outline current capabilities and summarize a few activities in which the optical design team has been recently participating.

  12. LSST Camera Optics Design (Conference) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    We discuss the rationale for the LSST camera optics design, describe the methodology for ... Netherlands, Jul 01 - Jul 06, 2012 Research Org: Lawrence Livermore National ...

  13. Design, Synthesis and SAR of Novel Glucokinase Activators (Journal Article)

    Office of Scientific and Technical Information (OSTI)

    | SciTech Connect Design, Synthesis and SAR of Novel Glucokinase Activators Citation Details In-Document Search Title: Design, Synthesis and SAR of Novel Glucokinase Activators Authors: Cheruvallath, Z. ; Gwaltney II, S. ; Sabat, M. ; Tang, M. ; Feng, J. ; Wang, H. ; Miura, J. ; Guntupalli, P. ; Jennings, A. ; et al. Publication Date: 2013-04-01 OSTI Identifier: 1162548 Report Number(s): BNL--106493-2014-JA Journal ID: ISSN 0960-894X DOE Contract Number: DE-AC02-98CH10886 Resource Type:

  14. Solar optical materials for innovative window design

    SciTech Connect (OSTI)

    Lampert, C.M.

    1982-08-01

    New and innovative optical materials and coatings can greatly improve the efficiency of window energy systems. These potential materials and coatings increase energy efficiency by reducing radiative losses in the infrared, or reducing visible reflection losses or controlling overheating due to solar gain. Current progress in heat mirror coatings for glass and polymeric substrates is presented. Highly doped semiconducting oxides and metal/dielectric interference coatings are reviewed. Physical and optical properties are outlined for antireflection films and transparent aerogel insulation media. The potential for optical switching films as window elements includes discussions of electrochromic, photochromic and other physical switching processes.

  15. Synthesis, electronic and optical properties of Si nanostructures

    SciTech Connect (OSTI)

    Dinh, L.N.

    1996-09-01

    Silicon and silicon oxide nanostructures have been deposited on solid substrates, in an ultra high vacuum (UHV) chamber, by laser ablation or thermal vaporization. Laser ablation followed by substrate post annealing produced Si clusters with average size of a few nanometers, on highly oriented pyrolytic graphite (HOPG) surfaces. This technique, which is based on surface diffusion, is limited to the production of less than one layer of clusters on a given surface. The low coverage of Si clusters and the possibility of nonradiative decay of excitation in the Si cores to the HOPG substrates in these samples rendered them unsuitable for many optical measurements. Thermal vaporization of Si in an Ar buffer gas, on the contrary, yielded multilayer coverage of Si nanoclusters with a fairly narrow size distribution of about 2 nm, full width at half maximum (FWHM). As a result, further study was performed only on Si nanoclusters synthesized by thermal vaporization in a buffer gas. High resolution transmission electron microscopy (HRTEM) and X-ray diffraction (XRD) revealed that these nanoclusters were crystalline. However, during synthesis, if oxygen was the buffer gas, a network of amorphous Si oxide nanostructures (an-SiO{sub x}) with occasional embedded Si dots was formed. All samples showed strong infrared and/or visible photoluminescence (PL) with varying decay times from nanoseconds to microseconds depending on synthesis conditions. There were differences in PL spectra for hydrogen and oxygen passivated nc-Si, while many common PL properties between oxygen passivated nc-Si and an SiO{sub x} were observed. The observed experimental results can be best explained by a model involving absorption between quantum confined states in the Si cores and emission for which the decay times are very sensitive to surface and/or interface states.

  16. EUV optical design for 100 nm CD imaging system

    SciTech Connect (OSTI)

    Sweeney, D.W.; Hudyma, R.; Chapman, H.B.; Shafer, D.

    1998-04-09

    The imaging specifications for extreme ultraviolet lithography (EUVL) projection optics parallel those of other optical lithographies. Specifications are scaled to reflect the 100 nm critical dimension for the first generation EUVL systems. The design being fabricated for the Engineering Test Stand, an EUVL alpha tool, consists of a condenser with six channels to provide an effective partial coherence factor of 0.7. The camera contains four mirrors; three of the mirrors are aspheres and the fourth is spherical. The design of the optical package has been constrained so that the angles of incidence and the variations in the angle of incidence of all rays allow for uniform multilayer coatings. The multilayers introduce a slight shift in image position and magnification. We have shown that a system aligned with visible light is also aligned at 13.4 nm. Each mirror must be fabricated with an RMS figure error of less than 0.25 nm and better than 0.2 nm RMS roughness. Optical surfaces that exceed each of these specifications individually have been fabricated. The success of EUVL requires that these specifications be met simultaneously.

  17. Lanthanides-clay nanocomposites: Synthesis, characterization and optical properties

    SciTech Connect (OSTI)

    Celedon, Salvador; Quiroz, Carolina; Gonzalez, Guillermo; Sotomayor Torres, Clivia M.; Benavente, Eglantina

    2009-05-06

    Complexes of Europium(III) and Terbium(III) with 2,2-bipyridine and 1,10-phenanthroline were inserted into Na-bentonite by ion exchange reactions at room temperature. The products display interlaminar distances and stoichiometries in agreement with the ion exchange capacity and the interlayer space available in the clay. The optical properties of the intercalates, being qualitatively similar to those of the free complexes, are additionally improved with respect to exchange processes with the medium, especially in a moist environment. The protection again hydrolysis, together with the intensity of the optical transition {sup 5}D{sub 0}-{sup 5}F{sub 2} observed in the nanocomposite, makes these products promising for the development of novel optical materials.

  18. Design, synthesis, characterization and study of novel conjugated polymers

    SciTech Connect (OSTI)

    Chen, W.

    1997-06-24

    After introducing the subject of conjugated polymers, the thesis has three sections each containing a literature survey, results and discussion, conclusions, and experimental methods on the following: synthesis, characterization of electroluminescent polymers containing conjugated aryl, olefinic, thiophene and acetylenic units and their studies for use in light-emitting diodes; synthesis, characterization and study of conjugated polymers containing silole unit in the main chain; and synthesis, characterization and study of silicon-bridged and butadiene-linked polythiophenes.

  19. Designer Catalysts for Next Generation Fuel Synthesis - Energy...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    other pollutants from fuels. This improved synthesis technique produces single layer transition metal sulfide (SLTMS) catalysts, such as molybdenum disulfide, with potentially...

  20. Materials Discovery Design and Synthesis | U.S. DOE Office of Science (SC)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Discovery Design and Synthesis Materials Sciences and Engineering (MSE) Division MSE Home About Research Areas Energy Frontier Research Centers (EFRCs) DOE Energy Innovation Hubs BES Funding Opportunities Reports and Activities Science Highlights Principal Investigators' Meetings BES Home Research Areas Materials Discovery Design and Synthesis Print Text Size: A A A FeedbackShare Page Research is supported in the discovery and design of novel materials and the development of innovative materials

  1. Design and Synthesis of Nucleobase-Incorporated Metal-Organic Materials |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Center for Gas SeparationsRelevant to Clean Energy Technologies | Blandine Jerome Design and Synthesis of Nucleobase-Incorporated Metal-Organic Materials Previous Next List Zhang, Muwei; Lu, Weigang; Li, Jian-Rong; Bosch, Mathieu; Chen,Ying-Pin; Liu, Tian-Fu; Liu, Yangyang; Zhou, Hong-Cai. Design and Synthesis of Nucleobase-Incorporated Metal-Organic Materials. Inorg. Chem. Front., 1, 159-162 (2015). DOI: 10.1039/c3qi00042g design&synthesis Abstract: Two nucleobase-incorporated

  2. Synthesis and optical study of barium magnesium aluminate blue phosphors

    SciTech Connect (OSTI)

    Jeet, Suninder Pandey, O. P.; Sharma, Manoj

    2015-05-15

    Europium doped barium magnesium aluminate (BaMgAl{sub 10}O{sub 17}:Eu{sup 2+}) phosphor was prepared via solution combustion method at 550C using urea as a fuel. Morphological and optical properties of the prepared sample was studied by X-ray diffraction (XRD), Transmission electron microscopy (TEM) and Photoluminescence spectroscopy (PL). XRD result showed the formation of pure phase BaMgAl{sub 10}O{sub 17}(JCPDS 26-0163) along with an additional phase BaAl{sub 2}O{sub 4}(JCPDS 01-082-1350). TEM image indicated the formation of faceted particles with average particle size 40?nm. From PL spectra, a broad emission band obtained at about 450?nm attributes to 4f{sup 6} 5d ? 4f{sup 7} transition of Eu{sup 2+} which lies in the blue region of the visible spectrum.

  3. Automated design synthesis of robotic/human workcells for improved manufacturing system design in hazardous environments

    SciTech Connect (OSTI)

    Williams, Joshua M.

    2012-06-12

    Manufacturing tasks that are deemed too hazardous for workers require the use of automation, robotics, and/or other remote handling tools. The associated hazards may be radiological or nonradiological, and based on the characteristics of the environment and processing, a design may necessitate robotic labor, human labor, or both. There are also other factors such as cost, ergonomics, maintenance, and efficiency that also effect task allocation and other design choices. Handling the tradeoffs of these factors can be complex, and lack of experience can be an issue when trying to determine if and what feasible automation/robotics options exist. To address this problem, we utilize common engineering design approaches adapted more for manufacturing system design in hazardous environments. We limit our scope to the conceptual and embodiment design stages, specifically a computational algorithm for concept generation and early design evaluation. In regard to concept generation, we first develop the functional model or function structure for the process, using the common 'verb-noun' format for describing function. A common language or functional basis for manufacturing was developed and utilized to formalize function descriptions and guide rules for function decomposition. Potential components for embodiment are also grouped in terms of this functional language and are stored in a database. The properties of each component are given as quantitative and qualitative criteria. Operators are also rated for task-relevant criteria which are used to address task compatibility. Through the gathering of process requirements/constraints, construction of the component database, and development of the manufacturing basis and rule set, design knowledge is stored and available for computer use. Thus, once the higher level process functions are defined, the computer can automate the synthesis of new design concepts through alternating steps of embodiment and function structure updates/decomposition. In the process, criteria guide function allocation of components/operators and help ensure compatibility and feasibility. Through multiple function assignment options and varied function structures, multiple design concepts are created. All of the generated designs are then evaluated based on a number of relevant evaluation criteria: cost, dose, ergonomics, hazards, efficiency, etc. These criteria are computed using physical properties/parameters of each system based on the qualities an engineer would use to make evaluations. Nuclear processes such as oxide conversion and electrorefining are utilized to aid algorithm development and provide test cases for the completed program. Through our approach, we capture design knowledge related to manufacturing and other operations in hazardous environments to enable a computational program to automatically generate and evaluate system design concepts.

  4. Summary of the Preliminary Optical ICHMI Design Study: A Preliminary Engineering Design Study for a Standpipe Viewport

    SciTech Connect (OSTI)

    Anheier, Norman C.; Qiao, Hong; Berglin, Eric J.; Hatchell, Brian K.

    2013-12-26

    This summary report examines an in-vessel optical access concept intended to support standoff optical instrumentation, control and human-machine interface (ICHMI) systems for future advanced small modular reactor (AdvSMR) applications. Optical-based measurement and sensing systems for AdvSMR applications have several key benefits over traditional instrumentation and control systems used to monitor reactor process parameters, such as temperature, flow rate, pressure, and coolant chemistry (Anheier et al. 2013). Direct and continuous visualization of the in-vessel components can be maintained using external cameras. Many optical sensing techniques can be performed remotely using open optical beam path configurations. Not only are in-vessel cables eliminated by these configurations, but also sensitive optical monitoring components (e.g., electronics, lasers, detectors, and cameras) can be placed outside the reactor vessel in the instrument vault, containment building, or other locations where temperatures and radiation levels are much lower. However, the extreme AdvSMR environment present challenges for optical access designs and optical materials. Optical access is not provided in any commercial nuclear power plant or featured in any reactor design, although successful implementation of optical access has been demonstrated in test reactors (Arkani and Gharib 2009). This report outlines the key engineering considerations for an AdvSMR optical access concept. Strict American Society of Mechanical Engineers (ASME) construction codes must be followed for any U.S. nuclear facility component (ASME 2013); however, the scope of this study is to evaluate the preliminary engineering issues for this concept, rather than developing a nuclear-qualified design. In addition, this study does not consider accident design requirements. In-vessel optical access using a standpipe viewport concept serves as a test case to explore the engineering challenges and performance requirements for sodium fast reactor (SFR) and high-temperature gas reactor (HTGR) AdvSMR applications. The expected environmental conditions for deployment are reviewed for both AdvSMR designs. Optical and mechanical materials that maximize component lifetime are evaluated for the standpipe viewport design under these conditions. Optical components and opto-mechanical designs that provide robust optical-to-metal seals and stress-free optical component mounting are identified, and then key performance specifications are developed for a sapphire optical viewport concept. Design strategies are examined that protect the internal optical surfaces from liquid-coolant condensation and impurity deposits. Finally, a conceptual standpipe viewport design that is suggestive of how this concept could be assembled using standard nuclear-qualified pipe components, is presented.

  5. Optical apparatus using liquid crystals for shaping the spatial intensity of optical beams having designated wavelengths

    DOE Patents [OSTI]

    Jacobs, Stephen D. (Pittsford, NY); Cerqua, Kathleen A. (Rochester, NY)

    1987-01-01

    The spatial intensity profile of an optical beam of designated wavelengths, such as a laser beam, is shaped (the beam is apodized) by means of cholesteric liquid crystals of opposite chirality disposed successively along the path of the beam. The crystals have curved surfaces, which may be defined by a lens which defines the thickness of the liquid crystal fluid gap in a liquid crystal cell, so as to vary the selective reflection of the designated wavelength across the aperture of the beam. In this way, a soft aperture is provided. By using tandem cell pairs having liquid crystals of opposite chirality, but of different pitch, and with lenses of different curvature, beams of different wavelengths which are projected colinearly along the path may be individually tailored in spatial intensity profile.

  6. Optical apparatus using liquid crystals for shaping the spatial intensity of optical beams having designated wavelengths

    DOE Patents [OSTI]

    Jacobs, S.D.; Cerqua, K.A.

    1987-07-14

    The spatial intensity profile of an optical beam of designated wavelengths, such as a laser beam, is shaped (the beam is apodized) by means of cholesteric liquid crystals of opposite chirality disposed successively along the path of the beam. The crystals have curved surfaces, which may be defined by a lens which defines the thickness of the liquid crystal fluid gap in a liquid crystal cell, so as to vary the selective reflection of the designated wavelength across the aperture of the beam. In this way, a soft aperture is provided. By using tandem cell pairs having liquid crystals of opposite chirality, but of different pitch, and with lenses of different curvature, beams of different wavelengths which are projected colinearly along the path may be individually tailored in spatial intensity profile. 11 figs.

  7. Design and synthesis of mixed oxides nanoparticles for biofuel applications

    SciTech Connect (OSTI)

    Chen, Senniang

    2010-05-15

    The work in this dissertation presents the synthesis of two mixed metal oxides for biofuel applications and NMR characterization of silica materials. In the chapter 2, high catalytic efficiency of calcium silicate is synthesized for transesterfication of soybean oil to biodisels. Chapter 3 describes the synthesis of a new Rh based catalyst on mesoporous manganese oxides. The new catalyst is found to have higher activity and selectivity towards ethanol. Chapter 4 demonstrates the applications of solid-state Si NMR in the silica materials.

  8. PV Optics: A Software Package for Solar Cells and Module Design

    SciTech Connect (OSTI)

    Sopori, B.

    2007-01-01

    PV Optics is a user-friendly software package developed to design and analyze solar cells and modules. It is applicable to a variety of optical structures, including thin and thick cells with light-trapping structures and metal optics. Using a combination of wave and ray optics to include effects of coherence and interference, it can be used to design single-junction and multijunction solar cells and modules. This paper describes some basic applications of PV Optics for crystalline and amorphous Si solar cell design. We present examples to examine the effects on solar cell performance of wafer thickness, antireflection coating thickness, texture height, and metal loss.

  9. Design of pulse stretching cell for a sodium guide star optical system

    SciTech Connect (OSTI)

    Friedman, H.W.; Horton, J.A.; Kuklo, T.J.; Wong, N.J.

    1992-11-10

    A pulse stretcher has been designed for the LLNL sodium guide star experiment to lower the laser flux and avoid saturation effects. The optical design, mechanical layout and wavefront error analysis are presented.

  10. Synthesis, optical properties, and microstructure of semiconductor nanocrystals formed by ion implantation

    SciTech Connect (OSTI)

    Budai, J.D.; White, C.W.; Withrow, S.P.; Zuhr, R.A.; Zhu, J.G.

    1996-12-01

    High-dose ion implantation, followed by annealing, has been shown to provide a versatile technique for creating semiconductor nanocrystals encapsulated in the surface region of a substrate material. The authors have successfully formed nanocrystalline precipitates from groups IV (Si, Ge, SiGe), III-V (GaAs, InAs, GaP, InP, GaN), and II-VI (CdS, CdSe, CdS{sub x}Se{sub 1{minus}x}, CdTe, ZnS, ZnSe) in fused silica, Al{sub 2}O{sub 3} and Si substrates. Representative examples will be presented in order to illustrate the synthesis, microstructure, and optical properties of the nanostructured composite systems. The optical spectra reveal blue-shifts in good agreement with theoretical estimates of size-dependent quantum-confinement energies of electrons and holes. When formed in crystalline substrates, the nanocrystal lattice structure and orientation can be reproducibly controlled by adjusting the implantation conditions.

  11. Gaussian Quadrature for Optical Design with Non-circular Pupils and Fields,

    Office of Scientific and Technical Information (OSTI)

    and Broad Wavelength Ranges (Conference) | SciTech Connect Gaussian Quadrature for Optical Design with Non-circular Pupils and Fields, and Broad Wavelength Ranges Citation Details In-Document Search Title: Gaussian Quadrature for Optical Design with Non-circular Pupils and Fields, and Broad Wavelength Ranges Authors: Bauman, B J ; Xiao, H Publication Date: 2010-06-25 OSTI Identifier: 1117994 Report Number(s): LLNL-CONF-442492 DOE Contract Number: W-7405-ENG-48 Resource Type: Conference

  12. Design and synthesis of thin palladium membranes for hydrogen separation

    SciTech Connect (OSTI)

    Shi, Z.; Szpunar, J. A.; Wu, S.

    2008-07-15

    The progress of electroless deposition of palladium around the pore area at surface of porous stainless steel was recorded in order to understand membrane formation and to control the membrane quality. A bridge structure is formed during the membrane formation around the pore area of the substrate. The porous substrate was modified to be smooth using micro-or nano-size metal or metal oxide particles in order to make sure that palladium membrane is strongly supported by the substrate and as the result the membrane thickness can be further reduced. The experimental results obtained from hydrogen permeation through the palladium membranes having the thickness from 400 nm to 18 {mu}m demonstrate that these thin membranes are solid and they can be used at the temperature of 550 deg.C and hydrogen pressure difference of 350 kPa. The proposed processing will allow optimizing the design and fabrication of thin palladium membranes for hydrogen separation. (authors)

  13. Three-dimensional photonic crystal fluorinated tin oxide (FTO) electrodes : synthesis and optical and electrical properties.

    SciTech Connect (OSTI)

    Yang, Z.; Gao, S.; Li, W.; Vlasko-Vlasov, V.; Welp, U.; Kwok, W.-K.; Xu, T.

    2011-04-01

    Photovoltaic (PV) schemes often encounter a pair of fundamentally opposing requirements on the thickness of semiconductor layer: a thicker PV semiconductor layer provides enhanced optical density, but inevitably increases the charge transport path length. An effective approach to solve this dilemma is to enhance the interface area between the terminal electrode, i.e., transparent conducting oxide (TCO) and the semiconductor layer. As such, we report a facile, template-assisted, and solution chemistry-based synthesis of 3-dimensional inverse opal fluorinated tin oxide (IO-FTO) electrodes. Synergistically, the photonic crystal structure possessed in the IO-FTO exhibits strong light trapping capability. Furthermore, the electrical properties of the IO-FTO electrodes are studied by Hall effect and sheet resistance measurement. Using atomic layer deposition method, an ultrathin TiO{sub 2} layer is coated on all surfaces of the IO-FTO electrodes. Cyclic voltammetry study indicates that the resulting TiO{sub 2}-coated IO-FTO shows excellent potentials as electrodes for electrolyte-based photoelectrochemical solar cells.

  14. Design and synthesis of nucleobase-incorporated metal-organic materials |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Center for Gas SeparationsRelevant to Clean Energy Technologies | Blandine Jerome Design and synthesis of nucleobase-incorporated metal-organic materials Previous Next List Muwei Zhang, Weigang Lu, Jian-Rong Li, Mathieu Bosch, Ying-Pin Chen, Tian-Fu Liu, Yangyang Liu and Hong-Cai Zhou, Inorg. Chem. Front., 1, 159-162 (2014) DOI: 10.1039/C3QI00042G GA Abstract: Two nucleobase-incorporated metal-organic materials were designed, synthesized and structurally characterized. PCN-530 is among the

  15. A novel planar ion funnel design for miniature ion optics

    SciTech Connect (OSTI)

    Chaudhary, A.; Amerom, Friso H. W. van; Short, R. T.

    2014-10-01

    The novel planar ion funnel (PIF) design presented in this article emphasizes simple fabrication, assembly, and operation, making it amenable to extreme miniaturization. Simulations performed in SIMION 8.0 indicate that ion focusing can be achieved by using a gradient of electrostatic potentials on concentric metal rings in a plane. A prototype was fabricated on a 35 35 mm custom-designed printed circuit board (PCB) with a center hole for ions to pass through and a series of concentric circular metal rings of increasing diameter on the front side of the PCB. Metal vias on the PCB electrically connected each metal ring to a resistive potential divider that was soldered on the back of the PCB. The PIF was tested at 5.5 10?? Torr in a vacuum test setup that was equipped with a broad-beam ion source on the front and a micro channel plate (MCP) ion detector on the back of the PIF. The ion current recorded on the MCP anode during testing indicated a 23 increase in the ion transmission through the PIF when electric potentials were applied to the rings. These preliminary results demonstrate the functionality of a 2D ion funnel design with a much smaller footprint and simpler driving electronics than conventional 3D ion funnels. Future directions to improve the design and a possible micromachining approach to fabrication are discussed in the conclusions.

  16. Bragg optics computer codes for neutron scattering instrument design

    SciTech Connect (OSTI)

    Popovici, M.; Yelon, W.B.; Berliner, R.R.; Stoica, A.D.

    1997-09-01

    Computer codes for neutron crystal spectrometer design, optimization and experiment planning are described. Phase space distributions, linewidths and absolute intensities are calculated by matrix methods in an extension of the Cooper-Nathans resolution function formalism. For modeling the Bragg reflection on bent crystals the lamellar approximation is used. Optimization is done by satisfying conditions of focusing in scattering and in real space, and by numerically maximizing figures of merit. Examples for three-axis and two-axis spectrometers are given.

  17. The Nanoscience Beamline at Diamond, Optical Design Considerations

    SciTech Connect (OSTI)

    Reininger, Ruben; Dhesi, Sarnjeet

    2007-01-19

    The main requirement of the Nanoscience Beamline at Diamond is to deliver the highest possible flux at the sample position of a PEEM with a resolving power of about 5000 in the energy range 80-2000 eV. The source of the beamline is a couple of APPLE II helical undulators in tandem that can also be used separately to allow for faster switching of the circular polarization. Based on its versatility, a collimated plane grating monochromator using sagittally focusing elements was chosen to cover the required energy range with three gratings. The operation of this monochromator requires a collimated beam incident on the grating along the dispersion direction. This can be achieved either with a toroid, focusing with its major radius along the non-dispersive direction at the exit slit, or with a sagittal cylinder. The former option uses a sagittal cylinder after the grating to focus the collimated beam at the exit slit. In the latter case, a toroid after the grating is used to focus in both directions at the exit slit. The advantage of the toroid downstream the grating is the higher horizontal demagnification. This configuration fulfills the Nanoscience Beamline's required resolving power but cannot be used to achieve very high resolution due to the astigmatic coma aberration of the toroidal mirror. The focusing at the sample position is performed with a KB pair of plane elliptical mirrors. Assuming achievable values for the errors on all the optical surfaces, the expected spots FWHW in the horizontal and vertical directions are 10 {mu}m and 3 {mu}m, respectively. The calculated photon flux at this spot at 5000 resolving power is >1012 photons/sec between 80 and 1600 eV for linearly polarized light and between 106 and 1200 eV for circularly polarized light. The beamline is expected to be operational in January 2007.

  18. Zeolite-like metal–organic frameworks (ZMOFs): Design, synthesis, and properties

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Eddaoudi, Mohamed; Sava, Dorina F.; Eubank, Jarrod F.; Adil, Karim; Guillerm, Vincent

    2015-10-24

    This study highlights various design and synthesis approaches toward the construction of ZMOFs, which are metal–organic frameworks (MOFs) with topologies and, in some cases, features akin to traditional inorganic zeolites. The interest in this unique subset of MOFs is correlated with their exceptional characteristics arising from the periodic pore systems and distinctive cage-like cavities, in conjunction with modular intra- and/or extra-framework components, which ultimately allow for tailoring of the pore size, pore shape, and properties towards specific applications.

  19. GridOPTICS(TM): A Design for Plug-and-Play Smart Grid Software Architecture

    SciTech Connect (OSTI)

    Gorton, Ian; Liu, Yan; Yin, Jian

    2012-06-03

    As the smart grid becomes reality, software architectures for integrating legacy systems with new innovative approaches for grid management are needed. These architectures must exhibit flexibility, extensibility, interoperability and scalability. In this position paper, we describe our preliminary work to design such an architecture, known as GridOPTICS, that will enable the deployment and integration of new software tools in smart grid operations. Our preliminary design is based upon use cases from PNNLs Future Power Grid Initiative, which is a developing a collection of advanced software technologies for smart grid management and control. We describe the motivations for GridOPTICS, and the preliminary design that we are currently prototyping for several distinct use cases.

  20. Improved Design of Optical MEMS Using the SUMMiT Fabrication Process

    SciTech Connect (OSTI)

    Michalicek, M.A.; Comtois, J.H.; Barron, C.C.

    1997-12-31

    This paper describes the design and fabrication of optical Microelectromechanical Systems (MEMS) devices using the Sandia Ultra planar Multilevel MEMS Technology (SUMMiT) fabrication process. This state of the art process, offered by Sandia National Laboratories, provides unique and very advantageous features which make it ideal for optical devices. This enabling process permits the development of micromirror devices with near ideal characteristics which have previously been unrealizable in standard polysilicon processes. This paper describes such characteristics as elevated address electrodes, individual address wiring beneath the device, planarized mirror surfaces, unique post-process metallization, and the best active surface area to date.

  1. Statistical analysis of sonochemical synthesis of SAPO-34 nanocrystals using Taguchi experimental design

    SciTech Connect (OSTI)

    Askari, Sima [Faculty of Chemical Engineering, Amirkabir University of Technology (Tehran Polytechnic), P.O. Box 15875-4413, Hafez Ave., Tehran (Iran, Islamic Republic of); Halladj, Rouein, E-mail: halladj@aut.ac.ir [Faculty of Chemical Engineering, Amirkabir University of Technology (Tehran Polytechnic), P.O. Box 15875-4413, Hafez Ave., Tehran (Iran, Islamic Republic of); Nazari, Mahdi [Faculty of Chemical Engineering, Amirkabir University of Technology (Tehran Polytechnic), P.O. Box 15875-4413, Hafez Ave., Tehran (Iran, Islamic Republic of)

    2013-05-15

    Highlights: ? Sonochemical synthesis of SAPO-34 nanocrystals. ? Using Taguchi experimental design (L9) for optimizing the experimental procedure. ? The significant effects of all the ultrasonic parameters on the response. - Abstract: SAPO-34 nanocrystals with high crystallinity were synthesized by means of sonochemical method. An L9 orthogonal array of the Taguchi method was implemented to investigate the effects of sonication conditions on the preparation of SAPO-34 with respect to crystallinity of the final product phase. The experimental data establish the favorable phase crystallinity which is improved by increasing the ultrasonic power and the sonication temperature. In the case of ultrasonic irradiation time, however, an initial increases in crystallinity from 5 min to 15 min is followed by a decrease in crystallinity for longer sonication time.

  2. Synthesis, characterization and optical properties of hybrid PVAZnO nanocomposite: A composition dependent study

    SciTech Connect (OSTI)

    Hemalatha, K.S. [Department of Physics, Bangalore University, Bangalore 560 056, Karnataka (India); Department of Physics, Maharani's Science College for Women, Palace Road, Bangalore 560 001, Karnataka (India); Rukmani, K., E-mail: rukmani9909@yahoo.co.in [Department of Physics, Bangalore University, Bangalore 560 056, Karnataka (India); Suriyamurthy, N. [Radiological Safety Division, Indira Gandhi Centre for Atomic Research, Kalpakkam 603 102, Tamil Nadu (India); Nagabhushana, B.M. [Department of Chemistry, M.S. Ramaiah Institute of Technology, Bangalore 560 054, Karnataka (India)

    2014-03-01

    Graphical abstract: - Highlights: ZnO nanoparticles were prepared by solution combustion method. PVAZnO nanocomposites were synthesized by solution casting method. Doped and undoped films were characterized using different techniques. Red shift in optical band gap was observed in Nanocomposite films with respect to nano ZnO. Photoluminescence intensity was found to be optimum for PVA10 mol% ZnO nanocomposite film. - Abstract: Nanocomposites of poly vinyl alcohol (PVA) and ZnO have been synthesized using the solution casting technique for different concentrations of nano ZnO powder prepared by low temperature solution combustion method. The formation of polymer nanocomposite and changes in the structural and micro structural properties of the materials were investigated by X-ray diffraction, Energy dispersive X ray spectroscopy and optical microscopy techniques (FTIR and UVVisible). The surface morphology of PVAZnO nanocomposite films were elucidated using Scanning Electron Microscopy. The optical absorption spectrum of nano ZnO shows blue shift in the optical band gap energy with respect to characteristic bulk ZnO at room temperature, whereas PVAZnO hybrid films show red shift with respect to nano ZnO. The photoluminescence studies show that the intensity of the blue emission (470 nm) varies with change in concentration of ZnO with an optimum intensity observed at 10 mol% of ZnO.

  3. Design, Synthesis, and Characterization of Bent-Core Mesogen-Jacketed Liquid Crystalline Polymers

    SciTech Connect (OSTI)

    Chen,X.; Tenneti, K.; Li, C.; Bai, Y.; Zhou, R.; Wan, X.; Fan, X.; Zhou, Q.

    2006-01-01

    We report the design, synthesis, and characterization of a series of mesogen-jacketed liquid crystalline polymers with bent-core liquid crystals (BCLCs). For the first time, BCLC mesogens were directly side-attached to the polymer backbone and bent-core mesogen-jacketed liquid crystalline polymers (BMJLCPs) were achieved. Both three-ring and five-ring mesogens were employed. The n-alkoxy substituent lengths for the three-ring and five-ring BMJLCPs were controlled as n = 1-5 and n = 6-16, respectively. Various characterization techniques such as differential scanning calorimetry, wide-angle X-ray diffraction, and polarized light microscopy were used to study their mesomorphic phase behavior. The monomers of five-ring BMJLCPs with relatively long tails showed mesophase behavior. Columnar liquid crystalline phase was observed in both three-ring and five-ring BMJLCPs. Columnar rectangular ({phi}{sub R}) phase was observed in the three-ring system. In the five-ring BMJLCPs, relatively short-tail homologues possess {phi}{sub R} phase, while columnar hexagonal phase was observed in the long-tail samples. The differences in the phase structures were attributed to the 'softness' of the macromolecular BMJLCP column surface.

  4. Hydrothermal synthesis of nanostructured zinc oxide and study of their optical properties

    SciTech Connect (OSTI)

    Moulahi, A.; Sediri, F.; Gharbi, N.

    2012-03-15

    Highlights: Black-Right-Pointing-Pointer Nanostructured ZnO were successfully obtained by a hydrothermal route. Black-Right-Pointing-Pointer Inorganic precursor and molar ratio are key factors for morphology and particle size. Black-Right-Pointing-Pointer Optical properties were also studied. -- Abstract: Nanostructured ZnO (nanorods, nanoshuttles) have been synthesized by hydrothermal approach using ZnCl{sub 2} or Zn(NO{sub 3}){sub 2}{center_dot}6H{sub 2}O as zinc sources and cetyltrimethylammonium bromide as structure-directing agent. Techniques X-ray powder diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), UV-visible absorption, Fourier transform infrared spectroscopy (FTIR) and Raman spectroscopy have been used to characterize the structure, morphology and composition of the nanostructured zinc oxide. The optical properties of the as-obtained materials were also studied and showing that it is possible to apply the ZnO nanoshuttles and nanorods on the UV filter, photocatalysis, and special optical devices.

  5. Synthesis and evaluation of optical and electrochemical properties of a new conjugated polymer containing substituted thiophene and non-conjugation linkers

    SciTech Connect (OSTI)

    R, Prashanth Kumar K D, Udayakumar; K, Siji Narendran N; K, Chandrasekharan

    2014-10-15

    Conjugated polymers have been developed in a variety of applied fields owing to their promising optoelectronic properties. These are pursuing considerable interest as opto-electrical material because of their chemical stability and processability. This paper describes the synthesis and study of electro-optical properties of a new donoracceptor polymer composed of substituted thiophene and 4,4?-propane-2,2-diyldiphenol units as electron rich moieties and 1,3,4-oxadiazole unit as electron deficient moiety. The optical properties of the polymer are studied using UV-visible absorption spectroscopy and fluorescent emission spectroscopy. From the electrochemical data, HOMO and LUMO energy levels of the polymer are calculated.

  6. Synthesis and Evaluation of CO2 Thickeners Designed with Molecular Modeling

    SciTech Connect (OSTI)

    Robert Enick; Erick Beckman; J. Karl Johnson

    2009-08-31

    The objective of this research was to use molecular modeling techniques, coupled with our prior experimental results, to design, synthesize and evaluate inexpensive, non-fluorous carbon dioxide thickening agents. The first type of thickener that was considered was associating polymers. Typically, these thickeners are copolymers that contain a highly CO{sub 2}-philic monomer, and a small concentration of a CO{sub 2}-phobic associating monomer. Yale University was solely responsible for the synthesis of a second type of thickener; small, hydrogen bonding compounds. These molecules have a core that contains one or more hydrogen-bonding groups, such as urea or amide groups. Non-fluorous, CO{sub 2}-philic functional groups were attached to the hydrogen bonding core of the compound to impart CO{sub 2} stability and macromolecular stability to the linear 'stack' of these compounds. The third type of compound initially considered for this investigation was CO{sub 2}-soluble surfactants. These surfactants contain conventional ionic head groups and composed of CO{sub 2}-philic oligomers (short polymers) or small compounds (sugar acetates) previously identified by our research team. Mobility reduction could occur as these surfactant solutions contacted reservoir brine and formed mobility control foams in-situ. The vast majority of the work conducted in this study was devoted to the copolymeric thickeners and the small hydrogen-bonding thickeners; these thickeners were intended to dissolve completely in CO{sub 2} and increase the fluid viscosity. A small but important amount of work was done establishing the groundwork for CO{sub 2}-soluble surfactants that reduced mobility by generating foams in-situ as the CO{sub 2}+surfactant solution mixed with in-situ brine.

  7. Confined cooperative self-assembly and synthesis of optically and electrically active nanostructures : final LDRD report

    SciTech Connect (OSTI)

    Coker, Eric Nicholas; Haddad, Raid Edward; Fan, Hongyou; Ta, Anh; Bai, Feng; Rodriguez, Mark Andrew; Huang, Jian Yu

    2011-10-01

    In this project, we developed a confined cooperative self-assembly process to synthesize one-dimensional (1D) j-aggregates including nanowires and nanorods with controlled diameters and aspect ratios. The facile and versatile aqueous solution process assimilates photo-active macrocyclic building blocks inside surfactant micelles, forming stable single-crystalline high surface area nanoporous frameworks with well-defined external morphology defined by the building block packing. Characterizations using TEM, SEM, XRD, N{sub 2} and NO sorption isotherms, TGA, UV-vis spectroscopy, and fluorescence imaging and spectroscopy indicate that the j-aggregate nanostructures are monodisperse and may further assemble into hierarchical arrays with multi-modal functional pores. The nanostructures exhibit enhanced and collective optical properties over the individual chromophores. This project was a small footprint research effort which, nonetheless, produced significant progress towards both the stated goal as well as unanticipated research directions.

  8. Optical reaction cell and light source for 18F! fluoride radiotracer synthesis

    DOE Patents [OSTI]

    Ferrieri, Richard A. (Patchogue, NY); Schlyer, David (Bellport, NY); Becker, Richard J. (Islip, NY)

    1998-09-15

    Apparatus for performing organic synthetic reactions, particularly no-carrier-added nucleophilic radiofluorination reactions for PET radiotracer production. The apparatus includes an optical reaction cell and a source of broadband infrared radiant energy, which permits direct coupling of the emitted radiant energy with the reaction medium to heat the reaction medium. Preferably, the apparatus includes means for focusing the emitted radiant energy into the reaction cell, and the reaction cell itself is preferably configured to reflect transmitted radiant energy back into the reaction medium to further improve the efficiency of the apparatus. The apparatus is well suited to the production of high-yield syntheses of 2-.sup.18 F!fluoro-2-deoxy-D-glucose. Also provided is a method for performing organic synthetic reactions, including the manufacture of .sup.18 F!-labeled compounds useful as PET radiotracers, and particularly for the preparation of 2-.sup.18 F!fluoro-2-deoxy-D-glucose in higher yields than previously possible.

  9. Pencil-like zinc oxide micro/nano-scale structures: Hydrothermal synthesis, optical and photocatalytic properties

    SciTech Connect (OSTI)

    Moulahi, A.; Sediri, F.

    2013-10-15

    Graphical abstract: - Highlights: Zinc oxide micro/nanopencils have been synthesized hydrothermally. Photocatalytic activity has been evaluated by the degradation of methylene blue under UV light irradiation. ZnO nanopencils exhibit much higher photocatalytic activity than the commercial ZnO. - Abstract: Zinc oxide micro/nanopencils have been successfully synthesized by hydrothermal process using zinc acetate and diamines as structure-directing agents. The morphology, the structure, the crystallinity and the composition of the materials were investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), Raman spectroscopy and X-ray photoelectron spectroscopy (XPS). The optical properties of synthesized ZnO were investigated by UVvis spectroscopy. The photocatalytic activity of the material has been evaluated by the degradation of methylene blue under UV irradiation. As a result, after the lapse of 150 min, around 82% bleaching was observed, with ZnO nanopencils yielding more photodegradation compared to that of commercial ZnO (61%)

  10. Optical reaction cell and light source for [18F] fluoride radiotracer synthesis

    DOE Patents [OSTI]

    Ferrieri, R.A.; Schlyer, D.; Becker, R.J.

    1998-09-15

    An apparatus is disclosed for performing organic synthetic reactions, particularly no-carrier-added nucleophilic radiofluorination reactions for PET radiotracer production. The apparatus includes an optical reaction cell and a source of broadband infrared radiant energy, which permits direct coupling of the emitted radiant energy with the reaction medium to heat the reaction medium. Preferably, the apparatus includes means for focusing the emitted radiant energy into the reaction cell, and the reaction cell itself is preferably configured to reflect transmitted radiant energy back into the reaction medium to further improve the efficiency of the apparatus. The apparatus is well suited to the production of high-yield syntheses of 2-[{sup 18}F]fluoro-2-deoxy-Dglucose. Also provided is a method for performing organic synthetic reactions, including the manufacture of [{sup 18}F]-labeled compounds useful as PET radiotracers, and particularly for the preparation of 2-[{sup 18}F]fluoro-2-deoxy-D-glucose in higher yields than previously possible. 4 figs.

  11. Optical reaction cell and light source for ›18F! fluoride radiotracer synthesis

    DOE Patents [OSTI]

    Ferrieri, Richard A.; Schlyer, David; Becker, Richard J.

    1998-09-15

    Apparatus for performing organic synthetic reactions, particularly no-carrier-added nucleophilic radiofluorination reactions for PET radiotracer production. The apparatus includes an optical reaction cell and a source of broadband infrared radiant energy, which permits direct coupling of the emitted radiant energy with the reaction medium to heat the reaction medium. Preferably, the apparatus includes means for focusing the emitted radiant energy into the reaction cell, and the reaction cell itself is preferably configured to reflect transmitted radiant energy back into the reaction medium to further improve the efficiency of the apparatus. The apparatus is well suited to the production of high-yield syntheses of 2-›.sup.18 F!fluoro-2-deoxy-D-glucose. Also provided is a method for performing organic synthetic reactions, including the manufacture of ›.sup.18 F!-labeled compounds useful as PET radiotracers, and particularly for the preparation of 2-›.sup.18 F!fluoro-2-deoxy-D-glucose in higher yields than previously possible.

  12. Extreme temperature robust optical sensor designs and fault-tolerant signal processing

    DOE Patents [OSTI]

    Riza, Nabeel Agha; Perez, Frank

    2012-01-17

    Silicon Carbide (SiC) probe designs for extreme temperature and pressure sensing uses a single crystal SiC optical chip encased in a sintered SiC material probe. The SiC chip may be protected for high temperature only use or exposed for both temperature and pressure sensing. Hybrid signal processing techniques allow fault-tolerant extreme temperature sensing. Wavelength peak-to-peak (or null-to-null) collective spectrum spread measurement to detect wavelength peak/null shift measurement forms a coarse-fine temperature measurement using broadband spectrum monitoring. The SiC probe frontend acts as a stable emissivity Black-body radiator and monitoring the shift in radiation spectrum enables a pyrometer. This application combines all-SiC pyrometry with thick SiC etalon laser interferometry within a free-spectral range to form a coarse-fine temperature measurement sensor. RF notch filtering techniques improve the sensitivity of the temperature measurement where fine spectral shift or spectrum measurements are needed to deduce temperature.

  13. Vehicle Technologies Office Merit Review 2015: Design and Synthesis of Advanced High-Energy Cathode Materials

    Broader source: Energy.gov [DOE]

    Presentation given by Lawrence Berkley National Laboratory at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about design...

  14. Design, synthesis, and characterization of novel fine-particle, unsupported catalysts for coal liquefaction

    SciTech Connect (OSTI)

    Klein, M.T.

    1992-05-22

    An investigation aimed at devising a procedure for preparing alkyl-or aryl-capped iron sulfide particles continues. An initial attempt to prepare fine-particle, aryl-capped iron sulfides (S-31) involved the competitive reaction of thiophenol (PhSH) and sodium sulfide (Na{sub 2}S) with Fe(II). However, SEM examination of the particles formed by this procedure indicated that no size control had been attained. It was thought that the phenyl group of thiophenol was not bulky enough to prevent thiolate bridging and consequent particle size growth of the metal sulfide. So the bulkier thiol 1-adamantanethiol was synthesized and used in synthesis S-33 in the next attempt to prepare fine-particle, capped iron sulfides.

  15. The North American Carbon Program Multi-scale synthesis and Terrestrial Model Intercomparison Project Part 1: Overview and experimental design

    SciTech Connect (OSTI)

    Huntzinger, D.N.; Schwalm, C.; Michalak, A.M; Schaefer, K.; King, A.W.; Wei, Y.; Jacobson, A.; Liu, S.; Cook, R.; Post, W.M.; Berthier, G.; Hayes, D.; Huang, M.; Ito, A.; Lei, H.; Lu, C.; Mao, J.; Peng, C.H.; Peng, S.; Poulter, B.; Riccuito, D.; Shi, X.; Tian, H.; Wang, W.; Zeng, N.; Zhao, F.; Zhu, Q.

    2013-01-01

    Terrestrial biosphere models (TBMs) have become an integral tool for extrapolating local observations and understanding of land-atmosphere carbon exchange to larger regions. The North American Carbon Program (NACP) Multi-scale synthesis and Terrestrial Model Intercomparison Project (MsTMIP) is a formal model intercomparison and evaluation effort focused on improving the diagnosis and attribution of carbon exchange at regional and global scales. MsTMIP builds upon current and past synthesis activities, and has a unique framework designed to isolate, interpret, and inform understanding of how model structural differences impact estimates of carbon uptake and release. Here we provide an overview of the MsTMIP effort and describe how the MsTMIP experimental design enables the assessment and quantification of TBM structural uncertainty. Model structure refers to the types of processes considered (e.g. nutrient cycling, disturbance, lateral transport of carbon), and how these processes are represented (e.g. photosynthetic formulation, temperature sensitivity, respiration) in the models. By prescribing a common experimental protocol with standard spin-up procedures and driver data sets, we isolate any biases and variability in TBM estimates of regional and global carbon budgets resulting from differences in the models themselves (i.e. model structure) and model-specific parameter values. An initial intercomparison of model structural differences is represented using hierarchical cluster diagrams (a.k.a. dendrograms), which highlight similarities and differences in how models account for carbon cycle, vegetation, energy, and nitrogen cycle dynamics. We show that, despite the standardized protocol used to derive initial conditions, models show a high degree of variation for GPP, total living biomass, and total soil carbon, underscoring the influence of differences in model structure and parameterization on model estimates.

  16. Near-infrared spectral tomography integrated with digital breast tomosynthesis: Effects of tissue scattering on optical data acquisition design

    SciTech Connect (OSTI)

    Michaelsen, Kelly; Krishnaswamy, Venkat; Pogue, Brian W.; Poplack, Steven P.; Paulsen, Keith D.

    2012-07-15

    Purpose: Design optimization and phantom validation of an integrated digital breast tomosynthesis (DBT) and near-infrared spectral tomography (NIRST) system targeting improvement in sensitivity and specificity of breast cancer detection is presented. Factors affecting instrumentation design include minimization of cost, complexity, and examination time while maintaining high fidelity NIRST measurements with sufficient information to recover accurate optical property maps. Methods: Reconstructed DBT slices from eight patients with abnormal mammograms provided anatomical information for the NIRST simulations. A limited frequency domain (FD) and extensive continuous wave (CW) NIRST system was modeled. The FD components provided tissue scattering estimations used in the reconstruction of the CW data. Scattering estimates were perturbed to study the effects on hemoglobin recovery. Breast mimicking agar phantoms with inclusions were imaged using the combined DBT/NIRST system for comparison with simulation results. Results: Patient simulations derived from DBT images show successful reconstruction of both normal and malignant lesions in the breast. They also demonstrate the importance of accurately quantifying tissue scattering. Specifically, 20% errors in optical scattering resulted in 22.6% or 35.1% error in quantification of total hemoglobin concentrations, depending on whether scattering was over- or underestimated, respectively. Limited frequency-domain optical signal sampling provided two regions scattering estimates (for fat and fibroglandular tissues) that led to hemoglobin concentrations that reduced the error in the tumor region by 31% relative to when a single estimate of optical scattering was used throughout the breast volume of interest. Acquiring frequency-domain data with six wavelengths instead of three did not significantly improve the hemoglobin concentration estimates. Simulation results were confirmed through experiments in two-region breast mimicking gelatin phantoms. Conclusions: Accurate characterization of scattering is necessary for quantification of hemoglobin. Based on this study, a system design is described to optimally combine breast tomosynthesis with NIRST.

  17. Thermochemical Design Report: Thermochemical Ethanol via Indirect Gasification and Mixed Alcohol Synthesis of Lignocellulosic Biomass

    SciTech Connect (OSTI)

    Phillips, S.; Aden, A.; Jechura, J.; Dayton, D.; Eggeman, T.

    2007-04-01

    This process design and technoeconomic evaluation addresses the conversion of biomass to ethanol via thermochemical pathways that are expected to be demonstrated at the pilot-unit level by 2012.

  18. Advanced optical measurements for characterizing photophysical...

    Office of Scientific and Technical Information (OSTI)

    single molecule optical methods for improved control of nanomaterial functionalization. ... paths for future improvements for multiplex nanoparticle synthesis and characterization. ...

  19. Equipment Design and Cost Estimation for Small Modular Biomass Systems, Synthesis Gas Cleanup, and Oxygen Separation Equipment; Task 9: Mixed Alcohols From Syngas -- State of Technology

    SciTech Connect (OSTI)

    Nexant Inc.

    2006-05-01

    This deliverable is for Task 9, Mixed Alcohols from Syngas: State of Technology, as part of National Renewable Energy Laboratory (NREL) Award ACO-5-44027, ''Equipment Design and Cost Estimation for Small Modular Biomass Systems, Synthesis Gas Cleanup and Oxygen Separation Equipment''. Task 9 supplements the work previously done by NREL in the mixed alcohols section of the 2003 technical report Preliminary Screening--Technical and Economic Assessment of Synthesis Gas to Fuels and Chemicals with Emphasis on the Potential for Biomass-Derived Syngas.

  20. Structure tracking aided design and synthesis of Li3V2(PO4)3 nanocrystals as high-power cathodes for lithium ion batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Liping; Bai, Jianming; Gao, Peng; Wang, Xiaoya; Looney, J. Patrick; Wang, Feng

    2015-07-30

    In this study, preparing new electrode materials with synthetic control of phases and electrochemical properties is desirable for battery applications but hardly achievable without knowing how the synthesis reaction proceeds. Herein, we report on structure tracking-aided design and synthesis of single-crystalline Li3V2(PO4)3 (LVP) nanoparticles with extremely high rate capability. A comprehensive investigation was made to the local structural orderings of the involved phases and their evolution toward forming LVP phase using in situ/ex situ synchrotron X-ray and electron-beam diffraction, spectroscopy, and imaging techniques. The results shed light on the thermodynamics and kinetics of synthesis reactions and enabled the design ofmore » a cost-efficient synthesis protocol to make nanocrystalline LVP, wherein solvothermal treatment is a crucial step leading to an amorphous intermediate with local structural ordering resembling that of LVP, which, upon calcination at moderate temperatures, rapidly transforms into the desired LVP phase. The obtained LVP particles are about 50 nm, coated with a thin layer of amorphous carbon and featured with excellent cycling stability and rate capability – 95% capacity retention after 200 cycles and 66% theoretical capacity even at a current rate of 10 C. The structure tracking based method we developed in this work offers a new way of designing battery electrodes with synthetic control of material phases and properties.« less

  1. Dispersed metal cluster catalysts by design. Synthesis, characterization, structure, and performance

    SciTech Connect (OSTI)

    Arslan, Ilke; Dixon, David A.; Gates, Bruce C.; Katz, Alexander

    2015-09-30

    To understand the class of metal cluster catalysts better and to lay a foundation for the prediction of properties leading to improved catalysts, we have synthesized metal catalysts with well-defined structures and varied the cluster structures and compositions systematicallyincluding the ligands bonded to the metals. These ligands include supports and bulky organics that are being tuned to control both the electron transfer to or from the metal and the accessibility of reactants to influence catalytic properties. We have developed novel syntheses to prepare these well-defined catalysts with atomic-scale control the environment by choice and placement of ligands and applied state-of-the art spectroscopic, microscopic, and computational methods to determine their structures, reactivities, and catalytic properties. The ligands range from nearly flat MgO surfaces to enveloping zeolites to bulky calixarenes to provide controlled coverages of the metal clusters, while also enforcing unprecedented degrees of coordinative unsaturation at the metal sitethereby facilitating bonding and catalysis events at exposed metal atoms. With this wide range of ligand properties and our arsenal of characterization tools, we worked to achieve a deep, fundamental understanding of how to synthesize robust supported and ligand-modified metal clusters with controlled catalytic properties, thereby bridging the gap between active site structure and function in unsupported and supported metal catalysts. We used methods of organometallic and inorganic chemistry combined with surface chemistry for the precise synthesis of metal clusters and nanoparticles, characterizing them at various stages of preparation and under various conditions (including catalytic reaction conditions) and determining their structures and reactivities and how their catalytic properties depend on their compositions and structures. Key characterization methods included IR, NMR, and EXAFS spectroscopies to identify ligands on the metals and their reactions; EXAFS spectroscopy and high-resolution STEM to determine cluster framework structures and changes resulting from reactant treatment and locations of metal atoms on support surfaces; X-ray diffraction crystallography to determine full structures of cluster-ligand combinations in the absence of a support, and TEM with tomographic methods to observe individual metal atoms and determine three-dimensional structures of catalysts. Electronic structure calculations were used to verify and interpret spectra and extend the understanding of reactivity beyond what is measurable experimentally.

  2. Modeling and Validation of Performance Limitations for the Optimal Design of Interferometric and Intensity-Modulated Fiber Optic Displacement Sensors

    SciTech Connect (OSTI)

    Moro, Erik A.

    2012-06-07

    Optical fiber sensors offer advantages over traditional electromechanical sensors, making them particularly well-suited for certain measurement applications. Generally speaking, optical fiber sensors respond to a desired measurand through modulation of an optical signal's intensity, phase, or wavelength. Practically, non-contacting fiber optic displacement sensors are limited to intensity-modulated and interferometric (or phase-modulated) methodologies. Intensity-modulated fiber optic displacement sensors relate target displacement to a power measurement. The simplest intensity-modulated sensor architectures are not robust to environmental and hardware fluctuations, since such variability may cause changes in the measured power level that falsely indicate target displacement. Differential intensity-modulated sensors have been implemented, offering robustness to such intensity fluctuations, and the speed of these sensors is limited only by the combined speed of the photodetection hardware and the data acquisition system (kHz-MHz). The primary disadvantages of intensity-modulated sensing are the relatively low accuracy (?m-mm for low-power sensors) and the lack of robustness, which consequently must be designed, often with great difficulty, into the sensor's architecture. White light interferometric displacement sensors, on the other hand, offer increased accuracy and robustness. Unlike their monochromatic-interferometer counterparts, white light interferometric sensors offer absolute, unambiguous displacement measurements over large displacement ranges (cm for low-power, 5 mW, sources), necessitating no initial calibration, and requiring no environmental or feedback control. The primary disadvantage of white light interferometric displacement sensors is that their utility in dynamic testing scenarios is limited, both by hardware bandwidth and by their inherent high-sensitivity to Doppler-effects. The decision of whether to use either an intensity-modulated interferometric sensor depends on an appropriate performance function (e.g., desired displacement range, accuracy, robustness, etc.). In this dissertation, the performance limitations of a bundled differential intensity-modulated displacement sensor are analyzed, where the bundling configuration has been designed to optimize performance. The performance limitations of a white light Fabry-Perot displacement sensor are also analyzed. Both these sensors are non-contacting, but they have access to different regions of the performance-space. Further, both these sensors have different degrees of sensitivity to experimental uncertainty. Made in conjunction with careful analysis, the decision of which sensor to deploy need not be an uninformed one.

  3. Synthesis and investigation of optical properties of TOPO-capped CuInS{sub 2} semiconductor nanocrystal in the presence of different solvent

    SciTech Connect (OSTI)

    Asgary, Saeid; Mirabbaszadeh, Kavoos; Nayebi, Payman; Emadi, Hamid

    2014-03-01

    Graphical abstract: - Highlights: TOPO-capped CuInS{sub 2} nanoparticles were synthesized by injection method. Pure CuInS{sub 2} nanoparticle was obtained by injection in 200 C. The size, shape and optical properties of products were controlled. Nanoparticles with size smaller than 10 nm and wurtzite phase was obtained. The absorption and PL spectra of CuInS{sub 2} nanoparticles were tunable. - Abstract: In this work, synthesis of CuInS{sub 2} semiconductor nanoparticles by thermolysis of a mixed solution of CuAc, In(Ac){sub 3} and DDT in coordinating solvent and trioctylphosphine oxide (TOPO) as ligand was developed. CuInS{sub 2} nanoparticles with size of ?10 nm and nanorods were obtained and optical properties controlled by adjusting the reaction parameters such as temperature and time. Also the shape of nanoparticles was controlled by various solvents elaborately. The as-prepared nanoparticles were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), Scanning electron microscopy (SEM), UVvis absorption, and photoluminescence (PL) spectroscopy. With the use of different solvent different morphology obtained. In the presence of oleylamine/octadecene rectangle-like nanorods obtained while with the use of oleic acid sphere-like nanoparticles achieved.

  4. DEVELOPMENT OF NOVEL CERAMIC NANOFILM-FIBER INTEGRATED OPTICAL SENSORS FOR RAPID DETECTION OF COAL DERIVED SYNTHESIS GAS

    SciTech Connect (OSTI)

    Junhang Dong; Hai Xiao; Xiling Tang; Hongmin Jiang; Kurtis Remmel; Amardeep Kaur

    2012-09-30

    The overall goal of this project is to conduct fundamental studies on advanced ceramic materials and fiber optic devices for developing new types of high temperature (>500{degree}C) fiber optic chemical sensors (FOCS) for monitoring fossil (mainly coal) and biomass derived gases in power plants. The primary technical objective is to investigate and demonstrate the nanocrystalline doped-ceramic thin film enabled FOCS that possess desired stability, sensitivity and selectivity for in-situ, rapid gas detection in the syngas streams from gasification and combustion flue gases. This report summarizes research works of two integrated parts: (1) development of metal oxide solid thin films as sensing materials for detection and measurement of important gas components relevant to the coal- and biomass-derived syngas and combustion gas streams at high temperatures; and (2) development of fiber optic devices that are potentially useful for constructing FOCS in combination with the solid oxide thin films identified in this program.

  5. Design of generic coal conversion facilities: Indirect coal liquefaction, Fischer-Tropsch synthesis

    SciTech Connect (OSTI)

    Not Available

    1991-10-01

    A comprehensive review of Fischer-Tropsch (F-T) technology, including fixed, fluidized, and bubble column reactors, was undertaken in order to develop an information base before initiating the design of the Fischer-Tropsch indirect liquefaction PDU as a part of the Generic Coal Conversion Facilities to be built at the Pittsburgh Energy Technology Center (PETC). The pilot plant will include a fixed bed and slurry bubble column reactor for the F-T mode of operation. The review encompasses current status of both these technologies, their key variables, catalyst development, future directions, and potential improvement areas. However, more emphasis has been placed on the slurry bubble column reactor since this route is likely to be the preferred technology for commercialization, offering process advantages and, therefore, better economics than fixed and fluidized bed approaches.

  6. DESIGN, SYNTHESIS AND STUDY OF MULTI-COMPONENT AND INTEGRATED SYSTEMS FOR LIGHT-DRIVEN HYDROGEN GENERATION

    SciTech Connect (OSTI)

    Professor Richard Eisenberg

    2012-07-18

    The research focussed on fundamental problems in the conversion of light to stored chemical energy. Specifically, work was completed on the design, synthesis and study of multi-component super- and supramolecular systems for photoinduced charge separation, one of the key steps in artificial photosynthesis, and on the use of these and related systems for the photochemical generation of H2 from water. At the center of these systems are chromophores comprised of square planar coordinated Pt(II) ions with arylacetylide and either diimine or terpyridyl ligands. Previous work had shown that the chromophores are photoluminescent in fluid solution with long-lived metal-to-ligand charge transfer (3MLCT) excited states that are necessarily directional. An advance which set the stage for a number of proposed studies was the light-driven production of hydrogen from water using a Pt(terpyridyl)(arylacetylide)+ chromophore and a sacrificial electron donor. The reaction is catalytic and appears to rival previously reported ruthenium bipyridyl systems in terms of H2 production. Variation of system components and mechanistic studies were conducted to understand better the individual steps in the overall process and how to improve its efficiency. Success with light driven H2 generation was employed as a key probe as new systems were constructed consisting of triads for photoinduced charge separation placed in close proximity to the H2 generating catalyst - a Pt colloid - through direct linkage or supramolecular interactions with the polymer used to stabilize the colloid. In order to prepare new donor-chromophore-acceptor (D-C-A) triads and associated D-C and C-A dyads, new ligands were synthesized having functional groups for different coupling reactions such as simple amide formation and Pd-catalyzed coupling. In these systems, the donor was attached to the arylacetylide ligands and the acceptor was linked to the diimine or terpyridyl chelate. Research under the contract proved successful in the development of synthetic methodologies to make multi-component systems designed so as to maintain electronic communication between components held in a defined spatial arrangement. Systems effective for light driven H2 generation were examined by photophysical methods including transient absorption spectroscopy to observe charge-separated states and chart their dynamics. Quantum yields for hydrogen production were also measured. Additional studies examined the effectiveness of these systems for H2 generation and involved the development of new catalysts and systems based thereon. From these studies, a better understanding of initial steps in the light driven generation of hydrogen were obtained.

  7. Optical Design Considerations for Efficient Light Collection from Liquid Scintillation Counters

    SciTech Connect (OSTI)

    Bernacki, Bruce E.; Douglas, Matthew; Erchinger, Jennifer L.; Fuller, Erin S.; Keillor, Martin E.; Morley, Shannon M.; Mullen, Crystal A.; Orrell, John L.; Panisko, Mark E.; Warren, Glen A.; Wright, Michael E.

    2015-01-01

    Liquid scintillation counters measure charged particle-emitting radioactive isotopes and are used for environmental studies, nuclear chemistry, and life science. Alpha and beta emissions arising from the material under study interact with the scintillation cocktail to produce light. The prototypical liquid scintillation counter employs low-level photon-counting detectors to measure the arrival of the scintillation light produced as a result of the dissolved material under study interacting with the scintillation cocktail. For reliable operation the counting instrument must convey the scintillation light to the detectors efficiently and predictably. Current best practices employ the use of two or more detectors for coincidence processing to discriminate true scintillation events from background events due to instrumental effects such as photomultiplier tube dark rates, tube flashing, or other light emission not generated in the scintillation cocktail vial. In low background liquid scintillation counters additional attention is paid to shielding the scintillation cocktail from naturally occurring radioactive material (NORM) present in the laboratory and within the instruments construction materials. Low background design is generally at odds with optimal light collection. This study presents the evolution of a light collection design for liquid scintillation counting in a low background shield. The basic approach to achieve both good light collection and a low background measurement is described. The baseline signals arising from the scintillation vial are modeled and methods to efficiently collect scintillation light are presented as part of the development of a customized low-background, high sensitivity liquid scintillation counting system.

  8. Single-step in-situ synthesis and optical properties of ZnSe nanostructured dielectric nanocomposites

    SciTech Connect (OSTI)

    Dey, Chirantan; Rahaman Molla, Atiar; Tarafder, Anal; Karmakar, Basudeb; Kr Mishra, Manish; De, Goutam; Goswami, Madhumita; Kothiyal, G. P.

    2014-04-07

    This work provides the evidence of visible red photoluminescent light emission from ZnSe nanocrystals (NCs) grown within a dielectric (borosilicate glass) matrix synthesized by a single step in-situ technique for the first time and the NC sizes were controlled by varying only the concentration of ZnSe in glass matrix. The ZnSe NCs were investigated by UV-Vis optical absorption spectroscopy, Raman spectroscopy, and transmission electron microscopy (TEM). The sizes of the ZnSe NCs estimated from the TEM images are found to alter in the range of 2–53 nm. Their smaller sizes of the NCs were also calculated by using the optical absorption spectra and the effective mass approximation model. The band gap enlargements both for carrier and exciton confinements were evaluated and found to be changed in the range of 0–1.0 eV. The Raman spectroscopic studies showed blue shifted Raman peaks of ZnSe at 295 and 315 cm{sup −1} indicating phonon confinement effect as well as compressive stress effect on the surface atoms of the NCs. Red photoluminescence in ZnSe-glass nanocomposite reveals a broad multiple-peak structure due to overlapping of emission from NC size related electron-hole recombination (∼707 nm) and emissions from defects to traps, which were formed due to Se and Zn vacancies signifying potential application in photonics.

  9. Synthesis and optical study of green light emitting polymer coated CdSe/ZnSe core/shell nanocrystals

    SciTech Connect (OSTI)

    Tripathi, S.K.; Sharma, Mamta

    2013-05-15

    Highlights: ► Synthesis of Polymer coated core CdSe and CdSe/ZnSe core/shell NCs. ► From TEM image, the spherical nature of CdSe and CdSe/ZnSe is obtained. ► Exhibiting green band photoemission peak at 541 nm and 549 nm for CdSe core and CdSe/ZnSe core/shell NCs. ► The shell thickness has been calculated by using superposition of quantum confinement energy model. - Abstract: CdSe/ZnSe Core/Shell NCs dispersed in PVA are synthesized by chemical method at room temperature. This is characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), UV/Vis spectra and photoluminescence spectroscopy (PL). TEM image shows the spherical nature of CdSe/ZnSe core/shell NCs. The red shift of absorption and emission peak of CdSe/ZnSe core/shell NCs as compared to CdSe core confirmed the formation of core/shell. The superposition of quantum confinement energy model is used for calculation of thickness of ZnSe shell.

  10. X-shaped Electro-Optic Chromophore with Remarkably Blue-Shifted Optical Absorption. Synthesis, Characterization, Linear/Nonlinear Optical Properties, Self-Assembly, and Thin Film Microstructural Characteristics

    SciTech Connect (OSTI)

    Kang,H.; Evmenenko, G.; Dutta, P.; Clays, K.; Song, K.; Marks, T.

    2006-01-01

    A novel type of 'X-shaped' two-dimensional electro-optic (EO) chromophore with extended conjugation has been synthesized and characterized. This chromophore is found to exhibit a remarkably blue-shifted optical maximum (357 nm in CH{sub 2}Cl{sub 2}) while maintaining a very large first hyperpolarizability ({beta}). Hyper-Rayleigh Scattering (HRS) measurements at 800 nm provide a {beta}{sub zzz} value of 1840 x 10{sup -30} esu. Self-assembled thin films of this chromophore were fabricated via a layer-by-layer chemisorptive siloxane-based approach. The chromophoric multilayers have been characterized by transmission optical spectroscopy, advancing contact angle measurements, synchrotron X-ray reflectivity, atomic force microscopy, and angle-dependent polarized second harmonic generation spectroscopy. The self-assembled chromophoric films exhibit a dramatically blue-shifted optical maximum (325 nm) while maintaining a large EO response ({chi}({sup 2}){sub 333} {approx} 232 pm/V at 1064 nm; r{sub 33} {approx} 45 pm/V at 1310 nm). This work demonstrates an attractive approach to developing EO materials offering improved nonlinearity-transparency trade-offs.

  11. In situ optical emission study on the role of C{sub 2} in the synthesis of single-walled carbon nanotubes

    SciTech Connect (OSTI)

    Motaung, David Edmond; Moodley, Mathew Kisten; Manikandan, E.; Coville, Neil J.

    2010-02-15

    In situ optical emission spectroscopy was used to study the temporal and spatial behavior of laser induced plasmas in the laser-furnace synthesis of single-walled carbon nanotubes (SWCNTs). A graphite composite target located within a sealed quartz tube with a chemical stoichiometric composition of 95:4:1 at. wt % of carbon, yttrium, and nickel, respectively, was ablated by a Q-switched Nd:YAG laser delivering colinear, focused laser pulses of 1064 and 532 nm temporarily separated by 20 ns. The ablation process was done at a furnace temperature of 1273 K in a flow of argon gas at either 150 or 200 SCCM (SCCM denotes cubic centimeter per minute at STP). The pressure was varied (100, 400, and 600 Torr) for each gas flow setting. The temporal and spatial behavior of the emission intensity associated with C{sub 2} Swan bands (d {sup 3{Pi}}{sub g}-a {sup 3{Pi}}{sub u}) was investigated and found to be influenced by the pressure and flow rate of the argon gas. At conditions optimal to SWCNT production, a sharp drop in C{sub 2} intensity followed by a rise in C{sub 2} intensity was observed. The temporal and spatial behavior of the electron density was determined by the Stark broadening profile of the CII emission peak at 283.7 nm and was found to decrease with the adiabatic expansion of the plume. We propose that the sharp drop in C{sub 2} intensity and the rise in electron density and electron temperature observed in this study are due to the accompanying rapid nucleation and growth of SWCNTs.

  12. Synthesis, characterization and optical properties of NH{sub 4}Dy(PO{sub 3}){sub 4}

    SciTech Connect (OSTI)

    Chemingui, S.; Ferhi, M. Horchani-Naifer, K.; Férid, M.

    2014-09-15

    Polycrystalline powders of NH{sub 4}Dy(PO{sub 3}){sub 4} polyphosphate have been grown by the flux method. This compound was found to be isotopic with NH{sub 4}Ce(PO{sub 3}){sub 4} and RbHo(PO{sub 3}){sub 4}. It crystallizes in the monoclinic space group P2{sub 1/n} with unit cell parameters a=10.474(6) Å, b=9.011(4) Å, c=10.947(7) Å and β=106.64(3)°. The title compound has been transformed to triphosphate Dy(PO{sub 3}){sub 3} after calcination at 800 °C. Powder X-ray diffraction, infrared and Raman spectroscopies and the differential thermal analysis have been used to identify these materials. The spectroscopic properties have been investigated through absorption, excitation, emission spectra and decay curves of Dy{sup 3+} ion in both compounds at room temperature. The emission spectra show the characteristic emission bands of Dy{sup 3+} in the two compounds, before and after calcination. The integrated emission intensity ratios of the yellow to blue (I{sub Y}/I{sub B}) transitions and the chromaticity properties have been determined from emission spectra. The decay curves are found to be double-exponential. The non-exponential behavior of the decay rates was related to the resonant energy transfer as well as cross-relaxation between the donor and acceptor Dy{sup 3+} ions. The determined properties have been discussed as function of crystal structure of both compounds. They reveal that NH{sub 4}Dy(PO{sub 3}){sub 4} is promising for white light generation but Dy(PO{sub 3}){sub 3} is potential candidates in field emission display (FED) and plasma display panel (PDP) devices. - Graphical abstract: The CIE color coordinate diagrams showing the chromatic coordinates of Dy{sup 3+} luminescence in NH{sub 4}Dy(PO{sub 3}){sub 4} and Dy(PO{sub 3}){sub 3}. - Highlights: • The polycrystalline powders of NH{sub 4}Dy(PO{sub 3}){sub 4} and Dy(PO{sub 3}){sub 3} are synthesized. • The obtained powders are characterized. • The spectroscopic properties of Dy{sup 3+} ion are investigated. • Results are discussed as function of crystal structure and chemical composition. • The usefulness of NH{sub 4}Dy(PO{sub 3}){sub 4} and Dy(PO{sub 3}){sub 3} in optical devices is revealed.

  13. Equipment Design and Cost Estimation for Small Modular Biomass Systems, Synthesis Gas Cleanup, and Oxygen Separation Equipment; Task 2: Gas Cleanup Design and Cost Estimates -- Wood Feedstock

    SciTech Connect (OSTI)

    Nexant Inc.

    2006-05-01

    As part of Task 2, Gas Cleanup and Cost Estimates, Nexant investigated the appropriate process scheme for treatment of wood-derived syngas for use in the synthesis of liquid fuels. Two different 2,000 metric tonne per day gasification schemes, a low-pressure, indirect system using the gasifier, and a high-pressure, direct system using gasification technology were evaluated. Initial syngas conditions from each of the gasifiers was provided to the team by the National Renewable Energy Laboratory. Nexant was the prime contractor and principal investigator during this task; technical assistance was provided by both GTI and Emery Energy.

  14. High-Efficiency Solar Cells for Large-Scale Electricity Generation & Design Considerations for the Related Optics (Presentation)

    SciTech Connect (OSTI)

    Kurtz, S.; Olson, J.; Geisz, J.; Friedman, D.; McMahon, W.; Ptak, A.; Wanlass, M.k; Kibbler, A.; Kramer, C.; Ward, S.; Duda, A.; Young, M.; Carapella, J.

    2007-09-17

    The photovoltaic industry has been growing exponentially at an average rate of about 35%/year since 1979. Recently, multijunction concentrator cell efficiencies have surpassed 40%. Combined with concentrating optics, these can be used for electricity generation.

  15. Concentrator Optics | Open Energy Information

    Open Energy Info (EERE)

    Concentrator Optics Jump to: navigation, search Name: Concentrator Optics Place: Marburg, Germany Zip: 35037 Product: A Germany-based company engaged in the design and production...

  16. Process Design and Economics for Conversion of Lignocellulosic Biomass to Ethanol: Thermochemical Pathway by Indirect Gasification and Mixed Alcohol Synthesis

    SciTech Connect (OSTI)

    Dutta, A.; Talmadge, M.; Hensley, J.; Worley, M.; Dudgeon, D.; Barton, D.; Groendijk, P.; Ferrari, D.; Stears, B.; Searcy, E. M.; Wright, C. T.; Hess, J. R.

    2011-05-01

    This design report describes an up-to-date benchmark thermochemical conversion process that incorporates the latest research from NREL and other sources. Building on a design report published in 2007, NREL and its subcontractor Harris Group Inc. performed a complete review of the process design and economic model for a biomass-to-ethanol process via indirect gasification. The conceptual design presented herein considers the economics of ethanol production, assuming the achievement of internal research targets for 2012 and nth-plant costs and financing. The design features a processing capacity of 2,205 U.S. tons (2,000 metric tonnes) of dry biomass per day and an ethanol yield of 83.8 gallons per dry U.S. ton of feedstock. The ethanol selling price corresponding to this design is $2.05 per gallon in 2007 dollars, assuming a 30-year plant life and 40% equity financing with a 10% internal rate of return and the remaining 60% debt financed at 8% interest. This ethanol selling price corresponds to a gasoline equivalent price of $3.11 per gallon based on the relative volumetric energy contents of ethanol and gasoline.

  17. Equipment Design and Cost Estimation for Small Modular Biomass Systems, Synthesis Gas Cleanup, and Oxygen Separation Equipment; Task 1: Cost Estimates of Small Modular Systems

    SciTech Connect (OSTI)

    Nexant Inc.

    2006-05-01

    This deliverable is the Final Report for Task 1, Cost Estimates of Small Modular Systems, as part of NREL Award ACO-5-44027, ''Equipment Design and Cost Estimation for Small Modular Biomass Systems, Synthesis Gas Cleanup and Oxygen Separation Equipment''. Subtask 1.1 looked into processes and technologies that have been commercially built at both large and small scales, with three technologies, Fluidized Catalytic Cracking (FCC) of refinery gas oil, Steam Methane Reforming (SMR) of Natural Gas, and Natural Gas Liquids (NGL) Expanders, chosen for further investigation. These technologies were chosen due to their applicability relative to other technologies being considered by NREL for future commercial applications, such as indirect gasification and fluidized bed tar cracking. Research in this subject is driven by an interest in the impact that scaling has on the cost and major process unit designs for commercial technologies. Conclusions from the evaluations performed could be applied to other technologies being considered for modular or skid-mounted applications.

  18. Structure tracking aided design and synthesis of Li3V2(PO4)3 nanocrystals as high-power cathodes for lithium ion batteries

    SciTech Connect (OSTI)

    Wang, Liping; Bai, Jianming; Gao, Peng; Wang, Xiaoya; Looney, J. Patrick; Wang, Feng

    2015-07-30

    In this study, preparing new electrode materials with synthetic control of phases and electrochemical properties is desirable for battery applications but hardly achievable without knowing how the synthesis reaction proceeds. Herein, we report on structure tracking-aided design and synthesis of single-crystalline Li3V2(PO4)3 (LVP) nanoparticles with extremely high rate capability. A comprehensive investigation was made to the local structural orderings of the involved phases and their evolution toward forming LVP phase using in situ/ex situ synchrotron X-ray and electron-beam diffraction, spectroscopy, and imaging techniques. The results shed light on the thermodynamics and kinetics of synthesis reactions and enabled the design of a cost-efficient synthesis protocol to make nanocrystalline LVP, wherein solvothermal treatment is a crucial step leading to an amorphous intermediate with local structural ordering resembling that of LVP, which, upon calcination at moderate temperatures, rapidly transforms into the desired LVP phase. The obtained LVP particles are about 50 nm, coated with a thin layer of amorphous carbon and featured with excellent cycling stability and rate capability 95% capacity retention after 200 cycles and 66% theoretical capacity even at a current rate of 10 C. The structure tracking based method we developed in this work offers a new way of designing battery electrodes with synthetic control of material phases and properties.

  19. Advanced Optical Technologies

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Advanced Optical Technologies The Advanced Optical Components and Technologies program develops, creates and provides critical optical components for laser-based missions at LLNL. Past projects focused on kinoform phase plates for LLNL's Nova laser and on large-area, submicron-pitch holographic diffraction gratings for LLNL's Petawatt (1015 watt) ultrashort-pulse laser. Today, the optical team designs and fabricates a variety of custom diffractive optics for researchers worldwide. Included are

  20. Hybrid Pd/Fe{sub 3}O{sub 4} nanowires: Fabrication, characterization, optical properties and application as magnetically reusable catalyst for the synthesis of N-monosubstituted ureas under ligand-free conditions

    SciTech Connect (OSTI)

    Nasrollahzadeh, Mahmoud; Azarian, Abbas; Ehsani, Ali; Sajadi, S.Mohammad; Babaei, Ferydon

    2014-07-01

    Highlights: Preparation of Pd/Fe{sub 3}O{sub 4} nanowires as magnetically reusable catalysts. The optical properties of the catalyst were studied using Gans theory. N-arylation of benzylurea and in situ hydrogenolysis of 1-benzyl-3-arylureas. - Abstract: This paper reports the synthesis and use of Pd/Fe{sub 3}O{sub 4} nanowires, as magnetically separable catalysts for ligand-free amidation coupling reactions of aryl halides with benzylurea under microwave irradiation. Then, the in situ hydrogenolysis of the products was performed to afford the N-monosubstituted ureas from good to excellent yields. This method has the advantages of high yields, simple methodology and easy work up. The catalyst can be recovered by using a magnet and reused several times without significant loss of its catalytic activity. The catalyst was characterized using the powder XRD, SEM, EDS and UVvis spectroscopy. Experimental absorbance spectra was compared with results from the Gans theory.

  1. DESIGN AND SYNTHESIS OF THE NEXT GENERATION OF CROWN ETHERS FOR WASTE SEPARATIONS: AN INTER-LABORATORY COMPREHENSIVE PROPOSAL

    SciTech Connect (OSTI)

    Moyer, Bruce A.

    2000-12-31

    The objectives of this project were to develop the techniques, materials, and fundamental understanding necessary to solve difficult separations problems of the USDOE in the 21st century. The specific goals included developing new, powerful molecular modeling tools for ligand design, performing computational and structural studies to reveal fundamental properties of ligand-metal ion interactions, studying solvent extraction behavior to provide basic understanding of solution speciation and equilibria, and preparing new ion-exchange resins for the separation of metal ions of environmental significance to the USDOE. Contaminants of special interest included alkali and alkaline-earth metal ions, especially, lithium, cesium, and strontium. For example, Li+ ions contaminate the groundwater at the Oak Ridge Y-12 Plant; Cs+ and Sr2+ represent fission products in groundwater (e.g., INEEL, Hanford), stored waste (e.g., Savannah River Site, Hanford tanks), and process-water streams (e. g., ORNL).

  2. Center for Nanophase Materials Sciences (CNMS) - Inorganic Synthesis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Inorganic Synthesis

  3. Theory, electro-optical design, testing, and calibration of a prototype atmospheric supersaturation, humidity, and temperature sensor. Final report Mar 81-Jul 82

    SciTech Connect (OSTI)

    Nelson, L.D.

    1982-07-15

    A new infrared differential absorption - passive thermal emission based instrument designed to make accurate in-cloud measurements of absolute humidity, air temperature, relative humidity, and ice and water supersaturations has been developed. Absolute humidity is measured by the differential infrared absorption of a broad-band light beam between 2.45 microns wavelength and the strongly absorbing water vapor band at 2.67 microns. Air temperature is sensed by a passive radiometric measurement of the Planck's law radiance emitted by carbon dioxide molecules in their very intense emission band at 4.25 microns. Significant operational advantages over previous 14-16 micron band radiometers are achieved. These non-contact optical measurements of absolute humidity and true air temperature can then be combined to yield relative humidity values with respect to both water and ice which remain valid in condensing supersaturated conditions and in spite of hydrometeors in the sample volume.

  4. An adaptive optics package designed for astronomical use with a laser guide star tuned to an absorption line of atomic sodium

    SciTech Connect (OSTI)

    Salmon, J.T.; Avicola, K.; Brase, J.M.

    1994-04-11

    We present the design and implementation of a very compact adaptive optic system that senses the return light from a sodium guide-star and controls a deformable mirror and a pointing mirror to compensate atmospheric perturbations in the wavefront. The deformable mirror has 19 electrostrictive actuators and triangular subapertures. The wavefront sensor is a Hartmann sensor with lenslets on triangular centers. The high-bandwidth steering mirror assembly incorporates an analog controller that samples the tilt with an avalanche photodiode quad cell. An {line_integral}/25 imaging leg focuses the light into a science camera that can either obtain long-exposure images or speckle data. In laboratory tests overall Strehl ratios were improved by a factor of 3 when a mylar sheet was used as an aberrator. The crossover frequency at unity gain is 30 Hz.

  5. Synthesis, structural and optical characterization of undoped, N-doped ZnO and co-doped ZnO thin films

    SciTech Connect (OSTI)

    Pathak, Trilok Kumar Kumar, R.; Purohit, L. P.

    2015-05-15

    ZnO, N-doped ZnO and Al-N co-doped ZnO thin films were deposited on ITO coated corning glass by spin coater using sol-gel method. The films were annealed in air at 450C for one hour. The crystallographic structure and morphology of the films were studied by X-ray diffraction (XRD) and scanning electron microscopy (SEM) respectively. The X-ray diffraction results confirm that the thin films are of wurtzite hexagonal with a very small distortion. The optical properties were investigated by transmission spectra of different films using spectrophotometer (Shimadzu UV-VIS-NIR 3600). The results indicate that the N doped ZnO thin films have obviously enhanced transmittance in visible region. Moreover, the thickness of the films has strong influences on the optical constants.

  6. Coupled optical/thermal/fluid analysis and design requirements for operation and testing of a supercritical CO2 solar receiver.

    SciTech Connect (OSTI)

    Khivsara, Sagar

    2015-01-01

    Recent studies have evaluated closed-loop supercritical carbon dioxide (s-CO2) Brayton cycles to be a higher energy-density system in comparison to conventional superheated steam Rankine systems. At turbine inlet conditions of 923K and 25 MPa, high thermal efficiency (~50%) can be achieved. Achieving these high efficiencies will make concentrating solar power (CSP) technologies a competitive alternative to current power generation methods. To incorporate a s-CO2 Brayton power cycle in a solar power tower system, the development of a solar receiver capable of providing an outlet temperature of 923 K (at 25 MPa) is necessary. To satisfy the temperature requirements of a s-CO2 Brayton cycle with recuperation and recompression, it is required to heat s-CO2 by a temperature of ~200 K as it passes through the solar receiver. Our objective was to develop an optical-thermal-fluid model to design and evaluate a tubular receiver that will receive a heat input ~1 MWth from a heliostat field. We also undertook the documentation of design requirements for the development, testing and safe operation of a direct s-CO2 solar receiver. The main purpose of this document is to serve as a reference and guideline for design and testing requirements, as well as to address the technical challenges and provide initial parameters for the computational models that will be employed for the development of s-CO2 receivers.

  7. Binary Optics Toolkit

    Energy Science and Technology Software Center (OSTI)

    1996-04-02

    This software is a set of tools for the design and analysis of binary optics. It consists of a series of stand-alone programs written in C and some scripts written in an application-specific language interpreted by a CAD program called DW2000. This software can be used to optimize the design and placement of a complex lens array from input to output and produce contours, mask designs, and data exported for diffractive optic analysis.

  8. Active optical zoom system

    DOE Patents [OSTI]

    Wick, David V.

    2005-12-20

    An active optical zoom system changes the magnification (or effective focal length) of an optical imaging system by utilizing two or more active optics in a conventional optical system. The system can create relatively large changes in system magnification with very small changes in the focal lengths of individual active elements by leveraging the optical power of the conventional optical elements (e.g., passive lenses and mirrors) surrounding the active optics. The active optics serve primarily as variable focal-length lenses or mirrors, although adding other aberrations enables increased utility. The active optics can either be LC SLMs, used in a transmissive optical zoom system, or DMs, used in a reflective optical zoom system. By appropriately designing the optical system, the variable focal-length lenses or mirrors can provide the flexibility necessary to change the overall system focal length (i.e., effective focal length), and therefore magnification, that is normally accomplished with mechanical motion in conventional zoom lenses. The active optics can provide additional flexibility by allowing magnification to occur anywhere within the FOV of the system, not just on-axis as in a conventional system.

  9. Final Optics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Final Optics Schematic layout of NIF's final optics assembly (FOA). The suite of optics for one beamline is on the right. The final optics assemblies (FOAs) are the last element of the main laser system and the first of the target area systems. Each FOA contains four integrated optics modules (IOMs) that incorporate beam conditioning, frequency conversion, focusing, diagnostic sampling, and debris shielding capabilities into a single compact assembly. These optics are shown in the figure at

  10. Design of HIV-1 Protease Inhibitors with Amino-bis-tetrahydrofuran Derivatives as P2-Ligands to Enhance Backbone-Binding Interactions. Synthesis, Biological Evaluation, and Protein-Ligand X-ray Studies

    SciTech Connect (OSTI)

    Ghosh, Arun K.; Martyr, Cuthbert D.; Osswald, Heather L.; Sheri, Venkat Reddy; Kassekert, Luke A.; Chen, Shujing; Agniswamy, Johnson; Wang, Yuan-Fang; Hayashi, Hironori; Aoki, Manabu; Weber, Irene T.; Mitsuya, Hiroaki

    2015-10-30

    Structure-based design, synthesis, and biological evaluation of a series of very potent HIV-1 protease inhibitors are described. In an effort to improve backbone ligandbinding site interactions, we have incorporated basic-amines at the C4 position of the bis-tetrahydrofuran (bis-THF) ring. We speculated that these substituents would make hydrogen bonding interactions in the flap region of HIV-1 protease. Synthesis of these inhibitors was performed diastereoselectively. A number of inhibitors displayed very potent enzyme inhibitory and antiviral activity. Inhibitors 25f, 25i, and 25j were evaluated against a number of highly-PI-resistant HIV-1 strains, and they exhibited improved antiviral activity over darunavir. Two high resolution X-ray structures of 25f- and 25g-bound HIV-1 protease revealed unique hydrogen bonding interactions with the backbone carbonyl group of Gly48 as well as with the backbone NH of Gly48 in the flap region of the enzyme active site. These ligandbinding site interactions are possibly responsible for their potent activity.

  11. Design, synthesis, and characterization of novel fine-particle, unsupported catalysts for coal liquefaction. Technical progress report, January 26, 1992--April 25, 1992

    SciTech Connect (OSTI)

    Klein, M.T.

    1992-05-22

    An investigation aimed at devising a procedure for preparing alkyl-or aryl-capped iron sulfide particles continues. An initial attempt to prepare fine-particle, aryl-capped iron sulfides (S-31) involved the competitive reaction of thiophenol (PhSH) and sodium sulfide (Na{sub 2}S) with Fe(II). However, SEM examination of the particles formed by this procedure indicated that no size control had been attained. It was thought that the phenyl group of thiophenol was not bulky enough to prevent thiolate bridging and consequent particle size growth of the metal sulfide. So the bulkier thiol 1-adamantanethiol was synthesized and used in synthesis S-33 in the next attempt to prepare fine-particle, capped iron sulfides.

  12. Optical microspectrometer

    DOE Patents [OSTI]

    Sweatt, William C.; Christenson, Todd R.

    2004-05-25

    An optical microspectrometer comprises a grism to disperse the spectra in a line object. A single optical microspectrometer can be used to sequentially scan a planar object, such as a dye-tagged microchip. Because the optical microspectrometer is very compact, multiple optical microspectrometers can be arrayed to provide simultaneous readout across the width of the planar object The optical microspectrometer can be fabricated with lithographic process, such as deep X-ray lithography (DXRL), with as few as two perpendicular exposures.

  13. Optical properties database for high performance glazings. Task 12: Building energy analysis and design tools for solar applications, Subtask A.1: High-performance glazing

    SciTech Connect (OSTI)

    Reilly, S.; Selkowitz, S.; Winkelmann, F.

    1992-06-30

    The framework used for the data is described; maintain and updating the database is addressed; and covers extensions of the database are covered. The appendices include the glass library (Appendix A) and the glazing system library (Appendix B) which for the foundation of the optical property database, and a spectral data reporting format (Appendix C).

  14. 1986 European Conference on Optics, Optical Systems and Applications, Florence, Italy, Sept. 30-Oct. 3, 1986, Proceedings

    SciTech Connect (OSTI)

    Sottini, S.; Trigari, S.

    1987-01-01

    Recent advances in optical theory and the design and application of optical systems are examined in reviews and reports. Topics discussed include inverse problems in space optics propagation; optical design and image formation; the processing, storage, and display of holographic images; lasers and laser components; integrated and fiber optics; and optical measurement techniques, metrology, inspection, and remote sensing. Consideration is given to optical and electrooptic materials, medical applications, advanced applications of lasers and laser optics, mechanical applications, nonlinear optics and optical materials, novel spectroscopic techniques and applications, and phase conjugation and bistability.

  15. Relaying an optical wavefront

    DOE Patents [OSTI]

    Sweatt, William C. (Albuquerque, NM); Vawter, G. Allen (Corrales, NM)

    2007-03-06

    A wavefront rely devices samples an incoming optical wavefront at different locations, optically relays the samples while maintaining the relative position of the samples and the relative phase between the samples. The wavefront is reconstructed due to interference of the samples. Devices can be designed for many different wavelengths, including for example the ultraviolet, visible, infrared and even longer wavelengths such as millimeter waves. In one application, the device function as a telescope but with negligible length.

  16. Scalable optical quantum computer

    SciTech Connect (OSTI)

    Manykin, E A; Mel'nichenko, E V [Institute for Superconductivity and Solid-State Physics, Russian Research Centre 'Kurchatov Institute', Moscow (Russian Federation)

    2014-12-31

    A way of designing a scalable optical quantum computer based on the photon echo effect is proposed. Individual rare earth ions Pr{sup 3+}, regularly located in the lattice of the orthosilicate (Y{sub 2}SiO{sub 5}) crystal, are suggested to be used as optical qubits. Operations with qubits are performed using coherent and incoherent laser pulses. The operation protocol includes both the method of measurement-based quantum computations and the technique of optical computations. Modern hybrid photon echo protocols, which provide a sufficient quantum efficiency when reading recorded states, are considered as most promising for quantum computations and communications. (quantum computer)

  17. Proactive Strategies for Designing Thermoelectric Materials for...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    New p-type and n-type multiple-rattler skutterudite thermoelectric materials design, synthesis, fabrication, and characterization for power generation using vehicle exhaust waste ...

  18. Optical probe

    DOE Patents [OSTI]

    Hencken, Kenneth (Pleasanton, CA); Flower, William L. (Livermore, CA)

    1999-01-01

    A compact optical probe is disclosed particularly useful for analysis of emissions in industrial environments. The instant invention provides a geometry for optically-based measurements that allows all optical components (source, detector, rely optics, etc.) to be located in proximity to one another. The geometry of the probe disclosed herein provides a means for making optical measurements in environments where it is difficult and/or expensive to gain access to the vicinity of a flow stream to be measured. Significantly, the lens geometry of the optical probe allows the analysis location within a flow stream being monitored to be moved while maintaining optical alignment of all components even when the optical probe is focused on a plurality of different analysis points within the flow stream.

  19. Optical keyboard

    DOE Patents [OSTI]

    Veligdan, James T. (Manorville, NY); Feichtner, John D. (Fiddletown, CA); Phillips, Thomas E. (San Diego, CA)

    2001-01-01

    An optical keyboard includes an optical panel having optical waveguides stacked together. First ends of the waveguides define an inlet face, and opposite ends thereof define a screen. A projector transmits a light beam outbound through the waveguides for display on the screen as a keyboard image. A light sensor is optically aligned with the inlet face for sensing an inbound light beam channeled through the waveguides from the screen upon covering one key of the keyboard image.

  20. Metasurface optical antireflection coating

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhang, Boyang; Hendrickson, Joshua; Nader, Nima; Chen, Hou -Tong; Guo, Junpeng

    2014-12-15

    Light reflection at the boundary of two different media is one of the fundamental phenomena in optics, and reduction of reflection is highly desirable in many optical systems. Traditionally, optical antireflection has been accomplished using single- or multiple-layer dielectric films and graded index surface structures in various wavelength ranges. However, these approaches either impose strict requirements on the refractive index matching and film thickness, or involve complicated fabrication processes and non-planar surfaces that are challenging for device integration. Here, we demonstrate an antireflection coating strategy, both experimentally and numerically, by using metasurfaces with designer optical properties in the mid-wave infrared.more » Our results show that the metasurface antireflection is capable of eliminating reflection and enhancing transmission over a broad spectral band and a wide incidence angle range. The demonstrated antireflection technique has no requirement on the choice of materials and is scalable to other wavelengths.« less

  1. Center for Nanophase Materials Sciences (CNMS) - Soft matter synthesis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Soft matter synthesis

  2. Controlled Synthesis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    lUU iIII---11111 q o m Controlled Synthesis of Polyenes by Catalytic Methods Progress Report for the period 12/01/92 - 11/30/93 Richard R. Schrock Five papers have appeared in the last year (see list at end), numbers 225,229, 233, 236, and 240. The living cyclopolymerization of dipropargyl derivatives has been reported for diethyl dipropargylmalonate (X = C(CO2Et)2; Scheme I; #225). We have found that c_ addition and [3 addition take place approximately to an equivalent degree, on the basis of

  3. Optics Tuning Knobs for Facet

    SciTech Connect (OSTI)

    Nosochkov, Yuri; Hogan, Mark J.; Wittmer, Walter; /SLAC

    2011-06-02

    FACET is a new facility under construction at the SLAC National Accelerator Laboratory. The FACET beam line is designed to provide 23 GeV tightly focused and compressed electron and positron bunches for beam driven plasma wakefield acceleration research and other experiments. Achieving optimal beam parameters for various experimental conditions requires the optics capability for tuning in a sufficiently wide range. This will be achieved by using optics tuning systems (knobs). Design of such systems for FACET is discussed.

  4. Low noise optical position sensor

    DOE Patents [OSTI]

    Spear, Jonathan David (Berkeley, CA)

    1999-01-01

    A novel optical position sensor is described that uses two component photodiodes electrically connected in parallel, with opposing polarities. A lens provides optical gain and restricts the acceptance angle of the detector. The response of the device to displacements of an optical spot is similar to that of a conventional bi-cell type position sensitive detector. However, the component photodiode design enables simpler electronic amplification with inherently less electrical noise than the bi-cell. Measurements by the sensor of the pointing noise of a focused helium-neon laser as a function of frequency demonstrate high sensitivity and suitability for optical probe beam deflection experiments.

  5. Low noise optical position sensor

    DOE Patents [OSTI]

    Spear, J.D.

    1999-03-09

    A novel optical position sensor is described that uses two component photodiodes electrically connected in parallel, with opposing polarities. A lens provides optical gain and restricts the acceptance angle of the detector. The response of the device to displacements of an optical spot is similar to that of a conventional bi-cell type position sensitive detector. However, the component photodiode design enables simpler electronic amplification with inherently less electrical noise than the bi-cell. Measurements by the sensor of the pointing noise of a focused helium-neon laser as a function of frequency demonstrate high sensitivity and suitability for optical probe beam deflection experiments. 14 figs.

  6. Polar self-assembled thin films for non-linear optical materials

    DOE Patents [OSTI]

    Yang, XiaoGuang (Los Alamos, NM); Swanson, Basil I. (Los Alamos, NM); Li, DeQuan (Los Alamos, NM)

    2000-01-01

    The design and synthesis of a family of calix[4]arene-based nonlinear optical (NLO) chromophores are discussed. The calixarene chromophores are macrocyclic compounds consisting of four simple D-.pi.-A units bridged by methylene groups. These molecules were synthesized such that four D-.pi.-A units of the calix[4]arene were aligned along the same direction with the calixarene in a cone conformation. These nonlinear optical super-chromophores were subsequently fabricated into covalently bound self-assembled monolayers on the surfaces of fused silica and silicon. Spectroscopic second harmonic generation (SHG) measurements were carried out to determine the absolute value of the dominant element of the second-order nonlinear susceptibility, d.sub.33, and the average molecular alignment, .PSI.. A value of d.sub.33 =60 pm/V at a fundamental wavelength of 890 nm, and .PSI..about.36.degree. was found with respect to the surface normal.

  7. Fiber optic coupled optical sensor

    DOE Patents [OSTI]

    Fleming, Kevin J. (Albuquerque, NM)

    2001-01-01

    A displacement sensor includes a first optical fiber for radiating light to a target, and a second optical fiber for receiving light from the target. The end of the first fiber is adjacent and not axially aligned with the second fiber end. A lens focuses light from the first fiber onto the target and light from the target onto the second fiber.

  8. Green chemical synthesis of silver nanomaterials with maltodextrin.

    Office of Scientific and Technical Information (OSTI)

    (Conference) | SciTech Connect Conference: Green chemical synthesis of silver nanomaterials with maltodextrin. Citation Details In-Document Search Title: Green chemical synthesis of silver nanomaterials with maltodextrin. Silver nanomaterials have significant application resulting from their optical properties related to surface enhanced Raman spectroscopy, high electrical conductivity, and anti-microbial impact. A 'green chemistry' synthetic approach for silver nanomaterials minimizes the

  9. Synthesis and design of silicide intermetallic materials

    SciTech Connect (OSTI)

    Petrovic, J.J.; Castro, R.G.; Butt, D.P.; Park, Y.; Hollis, K.J.; Kung, H.H.

    1998-11-01

    The overall objective of this program is to develop structural silicide-based materials with optimum combinations of elevated temperature strength/creep resistance, low temperature fracture toughness, and high temperature oxidation and corrosion resistance for applications of importance to the U.S. processing industry. A further objective is to develop silicide-based prototype industrial components. The ultimate aim of the program is to work with industry to transfer the structural silicide materials technology to the private sector in order to promote international competitiveness in the area of advanced high temperature materials and important applications in major energy-intensive U.S. processing industries.

  10. Modular optical detector system

    DOE Patents [OSTI]

    Horn, Brent A.; Renzi, Ronald F.

    2006-02-14

    A modular optical detector system. The detector system is designed to detect the presence of molecules or molecular species by inducing fluorescence with exciting radiation and detecting the emitted fluorescence. Because the system is capable of accurately detecting and measuring picomolar concentrations it is ideally suited for use with microchemical analysis systems generally and capillary chromatographic systems in particular. By employing a modular design, the detector system provides both the ability to replace various elements of the detector system without requiring extensive realignment or recalibration of the components as well as minimal user interaction with the system. In addition, the modular concept provides for the use and addition of a wide variety of components, including optical elements (lenses and filters), light sources, and detection means, to fit particular needs.

  11. Optical analyzer

    DOE Patents [OSTI]

    Hansen, A.D.

    1987-09-28

    An optical analyzer wherein a sample of particulate matter, and particularly of organic matter, which has been collected on a quartz fiber filter is placed in a combustion tube, and light from a light source is passed through the sample. The temperature of the sample is raised at a controlled rate and in a controlled atmosphere. The magnitude of the transmission of light through the sample is detected as the temperature is raised. A data processor, differentiator and a two pen recorder provide a chart of the optical transmission versus temperature and the rate of change of optical transmission versus temperature signatures (T and D) of the sample. These signatures provide information as to physical and chemical processes and a variety of quantitative and qualitative information about the sample. Additional information is obtained by repeating the run in different atmospheres and/or different rates or heating with other samples of the same particulate material collected on other filters. 7 figs.

  12. Optical coupler

    DOE Patents [OSTI]

    Majewski, Stanislaw; Weisenberger, Andrew G.

    2004-06-15

    In a camera or similar radiation sensitive device comprising a pixilated scintillation layer, a light guide and an array of position sensitive photomultiplier tubes, wherein there exists so-called dead space between adjacent photomultiplier tubes the improvement comprising a two part light guide comprising a first planar light spreading layer or portion having a first surface that addresses the scintillation layer and optically coupled thereto at a second surface that addresses the photomultiplier tubes, a second layer or portion comprising an array of trapezoidal light collectors defining gaps that span said dead space and are individually optically coupled to individual position sensitive photomultiplier tubes. According to a preferred embodiment, coupling of the trapezoidal light collectors to the position sensitive photomultiplier tubes is accomplished using an optical grease having about the same refractive index as the material of construction of the two part light guide.

  13. Optical memory

    DOE Patents [OSTI]

    Mao, Samuel S; Zhang, Yanfeng

    2013-07-02

    Optical memory comprising: a semiconductor wire, a first electrode, a second electrode, a light source, a means for producing a first voltage at the first electrode, a means for producing a second voltage at the second electrode, and a means for determining the presence of an electrical voltage across the first electrode and the second electrode exceeding a predefined voltage. The first voltage, preferably less than 0 volts, different from said second voltage. The semiconductor wire is optically transparent and has a bandgap less than the energy produced by the light source. The light source is optically connected to the semiconductor wire. The first electrode and the second electrode are electrically insulated from each other and said semiconductor wire.

  14. Facile one-pot synthesis of porphyrin based porous polymer networks...

    Office of Scientific and Technical Information (OSTI)

    porous polymer networks (PPNs) as biomimetic catalysts Citation Details ... Language: English Subject: membrane, carbon capture, materials and chemistry by design, synthesis ...

  15. Optical switch

    DOE Patents [OSTI]

    Reedy, R.P.

    1987-11-10

    An optical switching device is provided whereby light from a first glass fiber or a second glass fiber may be selectively transmitted into a third glass fiber. Each glass fiber is provided with a focusing and collimating lens system. In one mode of operation, light from the first glass fiber is reflected by a planar mirror into the third glass fiber. In another mode of operation, light from the second glass fiber passes directly into the third glass fiber. The planar mirror is attached to a rotatable table which is rotated to provide the optical switching. 3 figs.

  16. Condenser optic with sacrificial reflective surface

    DOE Patents [OSTI]

    Tichenor, Daniel A.; Kubiak, Glenn D.; Lee, Sang Hun

    2006-07-25

    Employing collector optics that have a sacrificial reflective surface can significantly prolong the useful life of the collector optics and the overall performance of the condenser in which the collector optics are incorporated. The collector optics are normally subject to erosion by debris from laser plasma source of radiation. The presence of an upper sacrificial reflective surface over the underlying reflective surface effectively increases the life of the optics while relaxing the constraints on the radiation source. Spatial and temporally varying reflectivity that results from the use of the sacrificial reflective surface can be accommodated by proper condenser design.

  17. Condenser optic with sacrificial reflective surface

    DOE Patents [OSTI]

    Tichenor, Daniel A. (Castro Valley, CA); Kubiak, Glenn D. (Livermore, CA); Lee, Sung Hun (Sunnyvale, CA)

    2007-07-03

    Employing collector optics that has a sacrificial reflective surface can significantly prolong the useful life of the collector optics and the overall performance of the condenser in which the collector optics are incorporated. The collector optics is normally subject to erosion by debris from laser plasma source of radiation. The presence of an upper sacrificial reflective surface over the underlying reflective surface effectively increases the life of the optics while relaxing the constraints on the radiation source. Spatial and temporally varying reflectivity that results from the use of the sacrificial reflective surface can be accommodated by proper condenser design.

  18. Mesoscale Engineering of Nanocomposite Nonlinear Optical Materials

    SciTech Connect (OSTI)

    Afonso, C.N.; Feldman, L.C.; Gonella, F.; Haglund, R.F.; Luepke, G.; Magruder, R.H.; Mazzoldi, P.; Osborne, D.H.; Solis, J.; Zuhr, R.A.

    1999-11-01

    Complex nonlinear optical materials comprising elemental, compound or alloy quantum dots embedded in appropriate dielectric or semiconducting hosts may be suitable for deployment in photonic devices. Ion implantation, ion exchange followed by ion implantation, and pulsed laser deposition have ail been used to synthesize these materials. However, the correlation between the parameters of energetic-beam synthesis and the nonlinear optical properties is still very rudimentary when one starts to ask what is happening at nanoscale dimensions. Systems integration of complex nonlinear optical materials requires that the mesoscale materials science be well understood within the context of device structures. We discuss the effects of beam energy and energy density on quantum-dot size and spatial distribution, thermal conductivity, quantum-dot composition, crystallinity and defects - and, in turn, on the third-order optical susceptibility of the composite material. Examples from recent work in our laboratories are used to illustrate these effects.

  19. Design of Flexure-based Precision Transmission Mechanisms using Screw Theory

    SciTech Connect (OSTI)

    Hopkins, J B; Panas, R M

    2011-02-07

    This paper enables the synthesis of flexure-based transmission mechanisms that possess multiple decoupled inputs and outputs of any type (e.g. rotations, translations, and/or screw motions), which are linked by designer-specified transmission ratios. A comprehensive library of geometric shapes is utilized from which every feasible concept that possesses the desired transmission characteristics may be rapidly conceptualized and compared before an optimal concept is selected. These geometric shapes represent the rigorous mathematics of screw theory and uniquely link a body's desired motions to the flexible constraints that enable those motions. This paper's impact is most significant to the design of nano-positioners, microscopy stages, optical mounts, and sensors. A flexure-based microscopy stage was designed, fabricated, and tested to demonstrate the utility of the theory.

  20. Study of optical Laue diffraction

    SciTech Connect (OSTI)

    Chakravarthy, Giridhar E-mail: aloksharan@email.com; Allam, Srinivasa Rao E-mail: aloksharan@email.com; Satyanarayana, S. V. M. E-mail: aloksharan@email.com; Sharan, Alok E-mail: aloksharan@email.com

    2014-10-15

    We present the study of the optical diffraction pattern of one and two-dimensional gratings with defects, designed using desktop pc and printed on OHP sheet using laser printer. Gratings so prepared, using novel low cost technique provides good visual aid in teaching. Diffraction pattern of the monochromatic light (632.8nm) from the grating so designed is similar to that of x-ray diffraction pattern of crystal lattice with point defects in one and two-dimensions. Here both optical and x-ray diffractions are Fraunhofer. The information about the crystalline lattice structure and the defect size can be known.

  1. Sandia Energy - Quantum Optics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Quantum Optics Home Energy Research EFRCs Solid-State Lighting Science EFRC Quantum Optics Quantum OpticsTara Camacho-Lopez2015-03-30T16:37:03+00:00 Quantum Optics with a Single...

  2. Quantum Optics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Quantum Optics - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced Nuclear

  3. Optical analyzer

    DOE Patents [OSTI]

    Hansen, Anthony D. (Berkeley, CA)

    1989-01-01

    An optical analyzer (10) wherein a sample (19) of particulate matter, and particularly of organic matter, which has been collected on a quartz fiber filter (20) is placed in a combustion tube (11), and light from a light source (14) is passed through the sample (19). The temperature of the sample (19) is raised at a controlled rate and in a controlled atmosphere. The magnitude of the transmission of light through the sample (19) is detected (18) as the temperature is raised. A data processor (23), differentiator (28) and a two pen recorder (24) provide a chart of the optical transmission versus temperature and the rate of change of optical transmission versus temperature signatures (T and D) of the sample (19). These signatures provide information as to physical and chemical processes and a variety of quantitative and qualitative information about the sample (19). Additional information is obtained by repeating the run in different atmospheres and/or different rates of heating with other samples of the same particulate material collected on other filters.

  4. Fiber optic monitoring device

    DOE Patents [OSTI]

    Samborsky, James K. (605 Groves Blvd., N. Augusta, SC 29841)

    1993-01-01

    A device for the purpose of monitoring light transmissions in optical fibers comprises a fiber optic tap that optically diverts a fraction of a transmitted optical signal without disrupting the integrity of the signal. The diverted signal is carried, preferably by the fiber optic tap, to a lens or lens system that disperses the light over a solid angle that facilitates viewing. The dispersed light indicates whether or not the monitored optical fiber or system of optical fibers is currently transmitting optical information.

  5. Parallel optical sampler

    DOE Patents [OSTI]

    Tauke-Pedretti, Anna; Skogen, Erik J; Vawter, Gregory A

    2014-05-20

    An optical sampler includes a first and second 1.times.n optical beam splitters splitting an input optical sampling signal and an optical analog input signal into n parallel channels, respectively, a plurality of optical delay elements providing n parallel delayed input optical sampling signals, n photodiodes converting the n parallel optical analog input signals into n respective electrical output signals, and n optical modulators modulating the input optical sampling signal or the optical analog input signal by the respective electrical output signals, and providing n successive optical samples of the optical analog input signal. A plurality of output photodiodes and eADCs convert the n successive optical samples to n successive digital samples. The optical modulator may be a photodiode interconnected Mach-Zehnder Modulator. A method of sampling the optical analog input signal is disclosed.

  6. Ion optics of RHIC EBIS

    SciTech Connect (OSTI)

    Pikin, A.; Alessi, J.; Beebe, E.; Kponou, A.; Okamura, M.; Raparia, D.; Ritter, J.; Tan, Y.; Kuznetsov, G.

    2011-09-10

    RHIC EBIS has been commissioned to operate as a versatile ion source on RHIC injection facility supplying ion species from He to Au for Booster. Except for light gaseous elements RHIC EBIS employs ion injection from several external primary ion sources. With electrostatic optics fast switching from one ion species to another can be done on a pulse to pulse mode. The design of an ion optical structure and the results of simulations for different ion species are presented. In the choice of optical elements special attention was paid to spherical aberrations for high-current space charge dominated ion beams. The combination of a gridded lens and a magnet lens in LEBT provides flexibility of optical control for a wide range of ion species to satisfy acceptance parameters of RFQ. The results of ion transmission measurements are presented.

  7. Optical microfluidics

    SciTech Connect (OSTI)

    Kotz, K.T.; Noble, K.A.; Faris, G.W. [Molecular Physics Laboratory, SRI International, 333 Ravenswood Avenue, Menlo Park, California 94025 (United States)

    2004-09-27

    We present a method for the control of small droplets based on the thermal Marangoni effect using laser heating. With this approach, droplets covering five orders of magnitude in volume ({approx}1.7 {mu}L to 14 pL), immersed in decanol, were moved on an unmodified polystyrene surface, with speeds of up to 3 mm/s. When two droplets were brought into contact, they spontaneously fused and rapidly mixed in less than 33 ms. This optically addressed microfluidic approach has many advantages for microfluidic transport, including exceptional reconfigurability, low intersample contamination, large volume range, extremely simple substrates, no electrical connections, and ready scaling to large arrays.

  8. Optical devices

    DOE Patents [OSTI]

    Chaves, Julio C.; Falicoff, Waqidi; Minano, Juan C.; Benitez, Pablo; Dross, Oliver; Parkyn, Jr., William A.

    2010-07-13

    An optical manifold for efficiently combining a plurality of blue LED outputs to illuminate a phosphor for a single, substantially homogeneous output, in a small, cost-effective package. Embodiments are disclosed that use a single or multiple LEDs and a remote phosphor, and an intermediate wavelength-selective filter arranged so that backscattered photoluminescence is recycled to boost the luminance and flux of the output aperture. A further aperture mask is used to boost phosphor luminance with only modest loss of luminosity. Alternative non-recycling embodiments provide blue and yellow light in collimated beams, either separately or combined into white.

  9. Optical microphone

    DOE Patents [OSTI]

    Veligdan, James T. (Manorville, NY)

    2000-01-11

    An optical microphone includes a laser and beam splitter cooperating therewith for splitting a laser beam into a reference beam and a signal beam. A reflecting sensor receives the signal beam and reflects it in a plurality of reflections through sound pressure waves. A photodetector receives both the reference beam and reflected signal beam for heterodyning thereof to produce an acoustic signal for the sound waves. The sound waves vary the local refractive index in the path of the signal beam which experiences a Doppler frequency shift directly analogous with the sound waves.

  10. New Optical Evaluation Approach for Parabolic Trough Collectors: First-Principle OPTical Intercept Calculation

    SciTech Connect (OSTI)

    Zhu, G.; Lewandowski, A.

    2012-11-01

    A new analytical method -- First-principle OPTical Intercept Calculation (FirstOPTIC) -- is presented here for optical evaluation of trough collectors. It employs first-principle optical treatment of collector optical error sources and derives analytical mathematical formulae to calculate the intercept factor of a trough collector. A suite of MATLAB code is developed for FirstOPTIC and validated against theoretical/numerical solutions and ray-tracing results. It is shown that FirstOPTIC can provide fast and accurate calculation of intercept factors of trough collectors. The method makes it possible to carry out fast evaluation of trough collectors for design purposes. The FirstOPTIC techniques and analysis may be naturally extended to other types of CSP technologies such as linear-Fresnel collectors and central-receiver towers.

  11. Optical interconnect assembly

    DOE Patents [OSTI]

    Laughlin, Daric; Abel, Philip

    2015-06-09

    An optical assembly includes a substrate with a first row of apertures and a second row of apertures. A first optical die includes a first plurality of optical transducer elements and is mounted on the substrate such that an optical signal interface of each transducer element is aligned with an aperture of the first row of optical apertures. A second optical die includes a second plurality of optical transducer elements and is mounted on the substrate such that an optical signal interface of each of the second plurality of optical transducer elements is aligned with an aperture of the second row of optical apertures. A connector configured to mate with the optical assembly supports a plurality of optical fibers. A terminal end of each optical fiber protrudes from the connector and extends into one of the apertures when the connector is coupled with the optical assembly.

  12. Near-Field Magneto-Optical Microscope (Patent) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Publication: United States Language: English Subject: 47 OTHER INSTRUMENTATION; FIBER OPTICS; MAGNETIC FIELDS; MICROSCOPES; POLARIZATION; RESOLUTION; DESIGN; OPERATION Word Cloud...

  13. Near-Field Magneto-Optical Microscope (Patent) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Country of Publication: United States Language: English Subject: 47 OTHER INSTRUMENTATION; FIBER OPTICS; MAGNETIC FIELDS; MICROSCOPES; POLARIZATION; RESOLUTION; DESIGN; OPERATION...

  14. Optical manifold

    DOE Patents [OSTI]

    Falicoff, Waqidi; Chaves, Julio C.; Minano, Juan Carlos; Benitez, Pablo; Dross, Oliver; Parkyn, Jr., William A.

    2010-02-23

    Optical systems are described that have at least one source of a beam of blue light with divergence under 15.degree.. A phosphor emits yellow light when excited by the blue light. A collimator is disposed with the phosphor and forms a yellow beam with divergence under 15.degree.. A dichroic filter is positioned to transmit the beam of blue light to the phosphor and to reflect the beam of yellow light to an exit aperture. In different embodiments, the beams of blue and yellow light are incident upon said filter with central angles of 15.degree., 22.degree., and 45.degree.. The filter may reflect all of one polarization and part of the other polarization, and a polarization rotating retroreflector may then be provided to return the unreflected light to the filter.

  15. Optical data latch

    DOE Patents [OSTI]

    Vawter, G. Allen

    2010-08-31

    An optical data latch is formed on a substrate from a pair of optical logic gates in a cross-coupled arrangement in which optical waveguides are used to couple an output of each gate to an photodetector input of the other gate. This provides an optical bi-stability which can be used to store a bit of optical information in the latch. Each optical logic gate, which can be an optical NOT gate (i.e. an optical inverter) or an optical NOR gate, includes a waveguide photodetector electrically connected in series with a waveguide electroabsorption modulator. The optical data latch can be formed on a III-V compound semiconductor substrate (e.g. an InP or GaAs substrate) from III-V compound semiconductor layers. A number of optical data latches can be cascaded to form a clocked optical data shift register.

  16. Optical absorption measurement system

    DOE Patents [OSTI]

    Draggoo, Vaughn G. (Livermore, CA); Morton, Richard G. (San Diego, CA); Sawicki, Richard H. (Pleasanton, CA); Bissinger, Horst D. (Livermore, CA)

    1989-01-01

    The system of the present invention contemplates a non-intrusive method for measuring the temperature rise of optical elements under high laser power optical loading to determine the absorption coefficient. The method comprises irradiating the optical element with a high average power laser beam, viewing the optical element with an infrared camera to determine the temperature across the optical element and calculating the absorption of the optical element from the temperature.

  17. Synthesis of amino acids

    DOE Patents [OSTI]

    Davis, J.W. Jr.

    1979-09-21

    A method is described for synthesizing amino acids preceding through novel intermediates of the formulas: R/sub 1/R/sub 2/C(OSOC1)CN, R/sub 1/R/sub 2/C(C1)CN and (R/sub 1/R/sub 2/C(CN)O)/sub 2/SO wherein R/sub 1/ and R/sub 2/ are each selected from hydrogen and monovalent hydrocarbon radicals of 1 to 10 carbon atoms. The use of these intermediates allows the synthesis steps to be exothermic and results in an overall synthesis method which is faster than the synthesis methods of the prior art.

  18. Method of sound synthesis

    DOE Patents [OSTI]

    Miner, Nadine E.; Caudell, Thomas P.

    2004-06-08

    A sound synthesis method for modeling and synthesizing dynamic, parameterized sounds. The sound synthesis method yields perceptually convincing sounds and provides flexibility through model parameterization. By manipulating model parameters, a variety of related, but perceptually different sounds can be generated. The result is subtle changes in sounds, in addition to synthesis of a variety of sounds, all from a small set of models. The sound models can change dynamically according to changes in the simulation environment. The method is applicable to both stochastic (impulse-based) and non-stochastic (pitched) sounds.

  19. Diffractive optical elements for transformation of modes in lasers

    DOE Patents [OSTI]

    Sridharan, Arun K.; Pax, Paul H.; Heebner, John E.; Drachenberg, Derrek R.; Armstrong, James P.; Dawson, Jay W.

    2015-09-01

    Spatial mode conversion modules are described, with the capability of efficiently transforming a given optical beam profile, at one plane in space into another well-defined optical beam profile at a different plane in space, whose detailed spatial features and symmetry properties can, in general, differ significantly. The modules are comprised of passive, high-efficiency, low-loss diffractive optical elements, combined with Fourier transform optics. Design rules are described that employ phase retrieval techniques and associated algorithms to determine the necessary profiles of the diffractive optical components. System augmentations are described that utilize real-time adaptive optical techniques for enhanced performance as well as power scaling.

  20. Optical NAND gate

    DOE Patents [OSTI]

    Skogen, Erik J.; Raring, James; Tauke-Pedretti, Anna

    2011-08-09

    An optical NAND gate is formed from two pair of optical waveguide devices on a substrate, with each pair of the optical waveguide devices consisting of an electroabsorption modulator and a photodetector. One pair of the optical waveguide devices is electrically connected in parallel to operate as an optical AND gate; and the other pair of the optical waveguide devices is connected in series to operate as an optical NOT gate (i.e. an optical inverter). The optical NAND gate utilizes two digital optical inputs and a continuous light input to provide a NAND function output. The optical NAND gate can be formed from III-V compound semiconductor layers which are epitaxially deposited on a III-V compound semiconductor substrate, and operates at a wavelength in the range of 0.8-2.0 .mu.m.

  1. New Selection Metric for Design of Thin-Film Solar Cell Absorber...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    guidance for the experimental synthesis. New Selection Metric for Design of Thin-Film Solar Cell Absorber Materials Research Details * SLME account s for the physics of...

  2. SPIE Optics + Photonics 2011

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SPIE Optics + Photonics 2011 August 21-25, 2011 San Diego Convention Center San Diego

  3. Optical transcutaneous bilirubin detector

    DOE Patents [OSTI]

    Kronberg, J.W.

    1993-11-09

    A transcutaneous bilirubin detector is designed comprising a source of light having spectral components absorbable and not absorbable by bilirubin, a handle assembly, electronic circuitry and a fiber optic bundle connecting the assembly to the light source and circuitry. Inside the assembly is a prism that receives the light from one end of the fiber optic bundle and directs it onto the skin and directs the reflected light back into the bundle. The other end of the bundle is trifucated, with one end going to the light source and the other two ends going to circuitry that determines how much light of each kind has been reflected. A relatively greater amount absorbed by the skin from the portion of the spectrum absorbable by bilirubin may indicate the presence of the illness. Preferably, two measurements are made, one on the kneecap and one on the forehead, and compared to determine the presence of bilirubin. To reduce the impact of light absorption by hemoglobin in the blood carried by the skin, pressure is applied with a plunger and spring in the handle assembly, the pressure limited by points of a button slidably carried in the assembly that are perceived by touch when the pressure applied is sufficient. 6 figures.

  4. Optical NOR gate

    DOE Patents [OSTI]

    Skogen, Erik J.; Tauke-Pedretti, Anna

    2011-09-06

    An optical NOR gate is formed from two pair of optical waveguide devices on a substrate, with each pair of the optical waveguide devices consisting of an electroabsorption modulator electrically connected in series with a waveguide photodetector. The optical NOR gate utilizes two digital optical inputs and a continuous light input to provide a NOR function digital optical output. The optical NOR gate can be formed from III-V compound semiconductor layers which are epitaxially deposited on a III-V compound semiconductor substrate, and operates at a wavelength in the range of 0.8-2.0 .mu.m.

  5. Optical XOR gate

    DOE Patents [OSTI]

    Vawter, G. Allen

    2013-11-12

    An optical XOR gate is formed as a photonic integrated circuit (PIC) from two sets of optical waveguide devices on a substrate, with each set of the optical waveguide devices including an electroabsorption modulator electrically connected in series with a waveguide photodetector. The optical XOR gate utilizes two digital optical inputs to generate an XOR function digital optical output. The optical XOR gate can be formed from III-V compound semiconductor layers which are epitaxially deposited on a III-V compound semiconductor substrate, and operates at a wavelength in the range of 0.8-2.0 .mu.m.

  6. Fiber optic connector

    DOE Patents [OSTI]

    Rajic, S.; Muhs, J.D.

    1996-10-22

    A fiber optic connector and method for connecting composite materials within which optical fibers are imbedded are disclosed. The fiber optic connector includes a capillary tube for receiving optical fibers at opposing ends. The method involves inserting a first optical fiber into the capillary tube and imbedding the unit in the end of a softened composite material. The capillary tube is injected with a coupling medium which subsequently solidifies. The composite material is machined to a desired configuration. An external optical fiber is then inserted into the capillary tube after fluidizing the coupling medium, whereby the optical fibers are coupled. 3 figs.

  7. Graphene-Based Optical Biosensors and Imaging

    SciTech Connect (OSTI)

    Tang, Zhiwen; He, Shijiang; Pei, Hao; Du, Dan; Fan, Chunhai; Lin, Yuehe

    2014-01-13

    This chapter focuses on the design, fabrication and application of graphene based optical nanobiosensors. The emerging graphene based optical nanobiosensors demonstrated the promising bioassay and biomedical applications thanking to the unique optical features of graphene. According to the different applications, the graphene can be tailored to form either fluorescent emitter or efficient fluorescence quencher. The exceptional electronic feature of graphene makes it a powerful platform for fabricating the SPR and SERS biosensors. Today the graphene based optical biosensors have been constructed to detect various targets including ions, small biomolecules, DNA/RNA and proteins. This chapter reviews the recent progress in graphene-based optical biosensors and discusses the opportunities and challenges in this field.

  8. Combinatorial synthesis of novel materials

    DOE Patents [OSTI]

    Schultz, Peter G. (Oakland, CA); Xiang, Xiaodong (Alameda, CA); Goldwasser, Isy (Alameda, CA)

    2002-02-12

    Methods and apparatus for the preparation and use of a substrate having an array of diverse materials in predefined regions thereon. A substrate having an array of diverse materials thereon is generally prepared by delivering components of materials to predefined regions on a substrate, and simultaneously reacting the components to form at least two materials. Materials which can be prepared using the methods and apparatus of the present invention include, for example, covalent network solids, ionic solids and molecular solids. More particularly, materials which can be prepared using the methods and apparatus of the present invention include, for example, inorganic materials, intermetallic materials, metal alloys, ceramic materials, organic materials, organometallic materials, non-biological organic polymers, composite materials (e.g., inorganic composites, organic composites, or combinations thereof), etc. Once prepared, these materials can be screened for useful properties including, for example, electrical, thermal, mechanical, morphological, optical, magnetic, chemical, or other properties. Thus, the present invention provides methods for the parallel synthesis and analysis of novel materials having useful properties.

  9. Combinatorial synthesis of novel materials

    DOE Patents [OSTI]

    Schultz, Peter G. (Oakland, CA); Xiang, Xiaodong (Alameda, CA); Goldwasser, Isy (Menlo Park, CA)

    1999-12-21

    Methods and apparatus for the preparation and use of a substrate having an array of diverse materials in predefined regions thereon. A substrate having an array of diverse materials thereon is generally prepared by delivering components of materials to predefined regions on a substrate, and simultaneously reacting the components to form at least two materials. Materials which can be prepared using the methods and apparatus of the present invention include, for example, covalent network solids, ionic solids and molecular solids. More particularly, materials which can be prepared using the methods and apparatus of the present invention include, for example, inorganic materials, intermetallic materials, metal alloys, ceramic materials, organic materials, organometallic materials, non-biological organic polymers, composite materials (e.g., inorganic composites, organic composites, or combinations thereof), etc. Once prepared, these materials can be screened for useful properties including, for example, electrical, thermal, mechanical, morphological, optical, magnetic, chemical, or other properties. Thus, the present invention provides methods for the parallel synthesis and analysis of novel materials having useful properties.

  10. Combinatorial synthesis of novel materials

    DOE Patents [OSTI]

    Schultz, Peter G. (Oakland, CA); Xiang, Xiaodong (Alameda, CA); Goldwasser, Isy (Alameda, CA)

    1999-01-01

    Methods and apparatus for the preparation and use of a substrate having an array of diverse materials in predefined regions thereon. A substrate having an array of diverse materials thereon is generally prepared by delivering components of materials to predefined regions on a substrate, and simultaneously reacting the components to form at least two materials. Materials which can be prepared using the methods and apparatus of the present invention include, for example, covalent network solids, ionic solids and molecular solids. More particularly, materials which can be prepared using the methods and apparatus of the present invention include, for example, inorganic materials, intermetallic materials, metal alloys, ceramic materials, organic materials, organometallic materials, non-biological organic polymers, composite materials (e.g., inorganic composites, organic composites, or combinations thereof), etc. Once prepared, these materials can be screened for useful properties including, for example, electrical, thermal, mechanical, morphological, optical, magnetic, chemical, or other properties. Thus, the present invention provides methods for the parallel synthesis and analysis of novel materials having useful properties.

  11. Combinatorial synthesis of novel materials

    DOE Patents [OSTI]

    Schultz, Peter G. (Oakland, CA); Xiang, Xiaodong (Alameda, CA); Goldwasser, Isy (Menlo Park, CA)

    2001-01-01

    Methods and apparatus for the preparation and use of a substrate having an array of diverse materials in predefined regions thereon. A substrate having an array of diverse materials thereon is generally prepared by delivering components of materials to predefined regions on a substrate, and simultaneously reacting the components to form at least two materials. Materials which can be prepared using the methods and apparatus of the present invention include, for example, covalent network solids, ionic solids and molecular solids. More particularly, materials which can be prepared using the methods and apparatus of the present invention include, for example, inorganic materials, intermetallic materials, metal alloys, ceramic materials, organic materials, organometallic materials, non-biological organic polymers, composite materials (e.g., inorganic composites, organic composites, or combinations thereof), etc. Once prepared, these materials can be screened for useful properties including, for example, electrical, thermal, mechanical, morphological, optical, magnetic, chemical, or other properties. Thus, the present invention provides methods for the parallel synthesis and analysis of novel materials having useful properties.

  12. Synthesis and Optical Properties of Sulfide Nanoparticles Prepared in Dimethylsulfoxide

    SciTech Connect (OSTI)

    Li, Yuebin; Ma, Lun; Zhang, Xing; Joly, Alan G.; Liu, Zuli; Chen, Wei

    2008-11-01

    Many methods have been reported for the formation of sulfide nanoparticles by the reaction of metallic salts with sulfide chemical sources in aqueous solutions or organic solvents. Here, we report the formation of sulfide nanoparticles in dimethylsulfoxide (DMSO) by boiling metallic salts without sulfide sources. The sulfide sources are generated from the boiling of DMSO and react with metallic salts to form sulfide nanoparticles. In this method DMSO functions as a solvent and a sulfide source as well as a stabilizer for the formation of the nanoparticles. The recipe is simple and economical making sulfide nanoparticles formed in this way readily available for many potential applications.

  13. Integrated self-cleaning window assembly for optical transmission in combustion environments

    DOE Patents [OSTI]

    Kass, Michael D [Oak Ridge, TN

    2007-07-24

    An integrated window design for optical transmission in combustion environments is described. The invention consists of an integrated optical window design that prevents and removes the accumulation of carbon-based particulate matter and gaseous hydrocarbons through a combination of heat and catalysis. These windows will enable established optical technologies to be applied to combustion environments and their exhaust systems.

  14. Latching micro optical switch

    DOE Patents [OSTI]

    Garcia, Ernest J; Polosky, Marc A

    2013-05-21

    An optical switch reliably maintains its on or off state even when subjected to environments where the switch is bumped or otherwise moved. In addition, the optical switch maintains its on or off state indefinitely without requiring external power. External power is used only to transition the switch from one state to the other. The optical switch is configured with a fixed optical fiber and a movable optical fiber. The movable optical fiber is guided by various actuators in conjunction with a latching mechanism that configure the switch in one position that corresponds to the on state and in another position that corresponds to the off state.

  15. Laser Safety Method For Duplex Open Loop Parallel Optical Link

    DOE Patents [OSTI]

    Baumgartner, Steven John (Zumbro Falls, MN); Hedin, Daniel Scott (Rochester, MN); Paschal, Matthew James (Rochester, MN)

    2003-12-02

    A method and apparatus are provided to ensure that laser optical power does not exceed a "safe" level in an open loop parallel optical link in the event that a fiber optic ribbon cable is broken or otherwise severed. A duplex parallel optical link includes a transmitter and receiver pair and a fiber optic ribbon that includes a designated number of channels that cannot be split. The duplex transceiver includes a corresponding transmitter and receiver that are physically attached to each other and cannot be detached therefrom, so as to ensure safe, laser optical power in the event that the fiber optic ribbon cable is broken or severed. Safe optical power is ensured by redundant current and voltage safety checks.

  16. High bandwidth optical mount

    DOE Patents [OSTI]

    Bender, D.A.; Kuklo, T.

    1994-11-08

    An optical mount, which directs a laser beam to a point by controlling the position of a light-transmitting optic, is stiffened so that a lowest resonant frequency of the mount is approximately one kilohertz. The optical mount, which is cylindrically-shaped, positions the optic by individually moving a plurality of carriages which are positioned longitudinally within a sidewall of the mount. The optical mount is stiffened by allowing each carriage, which is attached to the optic, to move only in a direction which is substantially parallel to a center axis of the optic. The carriage is limited to an axial movement by flexures or linear bearings which connect the carriage to the mount. The carriage is moved by a piezoelectric transducer. By limiting the carriage to axial movement, the optic can be kinematically clamped to a carriage. 5 figs.

  17. High bandwidth optical mount

    DOE Patents [OSTI]

    Bender, Donald A. (Dublin, CA); Kuklo, Thomas (Oakdale, CA)

    1994-01-01

    An optical mount, which directs a laser beam to a point by controlling the position of a light-transmitting optic, is stiffened so that a lowest resonant frequency of the mount is approximately one kilohertz. The optical mount, which is cylindrically-shaped, positions the optic by individually moving a plurality of carriages which are positioned longitudinally within a sidewall of the mount. The optical mount is stiffened by allowing each carriage, which is attached to the optic, to move only in a direction which is substantially parallel to a center axis of the optic. The carriage is limited to an axial movement by flexures or linear bearings which connect the carriage to the mount. The carriage is moved by a piezoelectric transducer. By limiting the carriage to axial movement, the optic can be kinematically clamped to a carriage.

  18. Proactive Strategies for Designing Thermoelectric Materials for Power

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Generation | Department of Energy New p-type and n-type multiple-rattler skutterudite thermoelectric materials design, synthesis, fabrication, and characterization for power generation using vehicle exhaust waste heat. PDF icon subramanian

  19. Fiber optic micro accelerometer

    DOE Patents [OSTI]

    Swierkowski, Steve P.

    2005-07-26

    An accelerometer includes a wafer, a proof mass integrated into the wafer, at least one spring member connected to the proof mass, and an optical fiber. A Fabry-Perot cavity is formed by a partially reflective surface on the proof mass and a partially reflective surface on the end of the optical fiber. The two partially reflective surfaces are used to detect movement of the proof mass through the optical fiber, using an optical detection system.

  20. Reflective optical imaging system

    DOE Patents [OSTI]

    Shafer, David R. (Fairfield, CT)

    2000-01-01

    An optical system compatible with short wavelength (extreme ultraviolet) radiation comprising four reflective elements for projecting a mask image onto a substrate. The four optical elements are characterized in order from object to image as convex, concave, convex and concave mirrors. The optical system is particularly suited for step and scan lithography methods. The invention increases the slit dimensions associated with ringfield scanning optics, improves wafer throughput and allows higher semiconductor device density.

  1. Optical voltage reference

    DOE Patents [OSTI]

    Rankin, Richard (Ammon, ID); Kotter, Dale (Bingham County, ID)

    1994-01-01

    An optical voltage reference for providing an alternative to a battery source. The optical reference apparatus provides a temperature stable, high precision, isolated voltage reference through the use of optical isolation techniques to eliminate current and impedance coupling errors. Pulse rate frequency modulation is employed to eliminate errors in the optical transmission link while phase-lock feedback is employed to stabilize the frequency to voltage transfer function.

  2. Optical voltage reference

    DOE Patents [OSTI]

    Rankin, R.; Kotter, D.

    1994-04-26

    An optical voltage reference for providing an alternative to a battery source is described. The optical reference apparatus provides a temperature stable, high precision, isolated voltage reference through the use of optical isolation techniques to eliminate current and impedance coupling errors. Pulse rate frequency modulation is employed to eliminate errors in the optical transmission link while phase-lock feedback is employed to stabilize the frequency to voltage transfer function. 2 figures.

  3. Optical isolation via unidirectional resonant photon tunneling

    SciTech Connect (OSTI)

    Moccia, Massimo; Castaldi, Giuseppe; Galdi, Vincenzo; Al, Andrea; Engheta, Nader

    2014-01-28

    We show that tri-layer structures combining epsilon-negative and magneto-optical material layers can exhibit unidirectional resonant photon tunneling phenomena that can discriminate between circularly polarized (CP) waves of given handedness impinging from opposite directions, or between CP waves with different handedness impinging from the same direction. This physical principle, which can also be interpreted in terms of a Fabry-Perot-type resonance, may be utilized to design compact optical isolators for CP waves. Within this framework, we derive simple analytical conditions and design formulae, and quantitatively assess the isolation performance, also taking into account the unavoidable imperfections and nonidealities.

  4. Nikon PTIPHOT-88 Optical Microscope

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    OPTIPHOT-88 Optical Microscope micro1.jpg (69171 bytes)

  5. Miniature hybrid optical imaging lens

    DOE Patents [OSTI]

    Sitter, Jr., David N. (Knoxville, TN); Simpson, Marc L. (Knoxville, TN)

    1997-01-01

    A miniature lens system that corrects for imaging and chromatic aberrations, the lens system being fabricated from primarily commercially-available components. A first element at the input to a lens housing is an aperture stop. A second optical element is a refractive element with a diffractive element closely coupled to, or formed a part of, the rear surface of the refractive element. Spaced closely to the diffractive element is a baffle to limit the area of the image, and this is closely followed by a second refractive lens element to provide the final correction. The image, corrected for aberrations exits the last lens element to impinge upon a detector plane were is positioned any desired detector array. The diffractive element is fabricated according to an equation that includes, as variables, the design wavelength, the index of refraction and the radius from an optical axis of the lens system components.

  6. Miniature hybrid optical imaging lens

    DOE Patents [OSTI]

    Sitter, D.N. Jr.; Simpson, M.L.

    1997-10-21

    A miniature lens system that corrects for imaging and chromatic aberrations is disclosed, the lens system being fabricated from primarily commercially-available components. A first element at the input to a lens housing is an aperture stop. A second optical element is a refractive element with a diffractive element closely coupled to, or formed a part of, the rear surface of the refractive element. Spaced closely to the diffractive element is a baffle to limit the area of the image, and this is closely followed by a second refractive lens element to provide the final correction. The image, corrected for aberrations exits the last lens element to impinge upon a detector plane were is positioned any desired detector array. The diffractive element is fabricated according to an equation that includes, as variables, the design wavelength, the index of refraction and the radius from an optical axis of the lens system components. 2 figs.

  7. Omnidirectional fiber optic tiltmeter

    DOE Patents [OSTI]

    Benjamin, B.C.; Miller, H.M.

    1983-06-30

    A tiltmeter is provided which is useful in detecting very small movements such as earth tides. The device comprises a single optical fiber, and an associated weight affixed thereto, suspended from a support to form a pendulum. A light source, e.g., a light emitting diode, mounted on the support transmits light through the optical fiber to a group of further optical fibers located adjacent to but spaced from the free end of the single optical fiber so that displacement of the single optical fiber with respect to the group will result in a change in the amount of light received by the individual optical fibers of the group. Photodetectors individually connectd to the fibers produce corresponding electrical outputs which are differentially compared and processed to produce a resultant continuous analog output representative of the amount and direction of displacement of the single optical fiber.

  8. Fiber optic vibration sensor

    DOE Patents [OSTI]

    Dooley, Joseph B. (Harriman, TN); Muhs, Jeffrey D. (Lenoir City, TN); Tobin, Kenneth W. (Harriman, TN)

    1995-01-01

    A fiber optic vibration sensor utilizes two single mode optical fibers supported by a housing with one optical fiber fixedly secured to the housing and providing a reference signal and the other optical fiber having a free span length subject to vibrational displacement thereof with respect to the housing and the first optical fiber for providing a signal indicative of a measurement of any perturbation of the sensor. Damping or tailoring of the sensor to be responsive to selected levels of perturbation is provided by altering the diameter of optical fibers or by immersing at least a portion of the free span length of the vibration sensing optical fiber into a liquid of a selected viscosity.

  9. Fiber optic vibration sensor

    DOE Patents [OSTI]

    Dooley, J.B.; Muhs, J.D.; Tobin, K.W.

    1995-01-10

    A fiber optic vibration sensor utilizes two single mode optical fibers supported by a housing with one optical fiber fixedly secured to the housing and providing a reference signal and the other optical fiber having a free span length subject to vibrational displacement thereof with respect to the housing and the first optical fiber for providing a signal indicative of a measurement of any perturbation of the sensor. Damping or tailoring of the sensor to be responsive to selected levels of perturbation is provided by altering the diameter of optical fibers or by immersing at least a portion of the free span length of the vibration sensing optical fiber into a liquid of a selected viscosity. 2 figures.

  10. Optics Tuning Knobs for Facet (Conference) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Optics Tuning Knobs for Facet Citation Details In-Document Search Title: Optics Tuning Knobs for Facet FACET is a new facility under construction at the SLAC National Accelerator Laboratory. The FACET beam line is designed to provide 23 GeV tightly focused and compressed electron and positron bunches for beam driven plasma wakefield acceleration research and other experiments. Achieving optimal beam parameters for various experimental conditions requires the optics capability for tuning in a

  11. A reflective optical transport system for ultraviolet Thomson scattering

    Office of Scientific and Technical Information (OSTI)

    from electron plasma waves on OMEGA (Journal Article) | SciTech Connect A reflective optical transport system for ultraviolet Thomson scattering from electron plasma waves on OMEGA Citation Details In-Document Search Title: A reflective optical transport system for ultraviolet Thomson scattering from electron plasma waves on OMEGA A reflective optical transport system has been designed for the OMEGA Thomson-scattering diagnostic. A Schwarzschild objective that uses two concentric spherical

  12. 'Slow light' advance could speed optical computing, telecommunications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    "Slow light" and specialized metamaterials 'Slow light' advance could speed optical computing, telecommunications Researchers have made the first demonstration of rapidly switching on and off "slow light" in specially designed materials at room temperature. February 12, 2013 Schematic of active optical control of terahertz waves in electromagnetically induced transparency metamaterials. Schematic of active optical control of terahertz waves in electromagnetically induced

  13. Cone penetrometer fiber optic raman spectroscopy probe assembly

    DOE Patents [OSTI]

    Kyle, Kevin R. (Brentwood, CA); Brown, Steven B. (Livermore, CA)

    2000-01-01

    A chemically and mechanically robust optical Raman spectroscopy probe assembly that can be incorporated in a cone penetrometer (CPT) for subsurface deployment. This assembly consists of an optical Raman probe and a penetrometer compatible optical probe housing. The probe is intended for in-situ chemical analysis of chemical constituents in the surrounding environment. The probe is optically linked via fiber optics to the light source and the detection system at the surface. A built-in broadband light source provides a strobe method for direct measurement of sample optical density. A mechanically stable sapphire window is sealed directly into the side-wall of the housing using a metallic, chemically resistant, hermetic seal design. This window permits transmission of the interrogation light beam and the resultant signal. The spectroscopy probe assembly is capable of accepting Raman, Laser induced Fluorescence, reflectance, and other optical probes with collimated output for CPT deployment.

  14. Optical sedimentation recorder

    DOE Patents [OSTI]

    Bishop, James K.B.

    2014-05-06

    A robotic optical sedimentation recorder is described for the recordation of carbon flux in the oceans wherein both POC and PIC particles are captured at the open end of a submersible sampling platform, the captured particles allowed to drift down onto a collection plate where they can be imaged over time. The particles are imaged using three separate light sources, activated in sequence, one source being a back light, a second source being a side light to provide dark field illumination, and a third source comprising a cross polarized light source to illuminate birefringent particles. The recorder in one embodiment is attached to a buoyancy unit which is capable upon command for bringing the sedimentation recorder to a programmed depth below the ocean surface during recordation mode, and on command returning the unit to the ocean surface for transmission of recorded data and receipt of new instructions. The combined unit is provided with its own power source and is designed to operate autonomously in the ocean for extended periods of time.

  15. Oxygenates from synthesis gas

    SciTech Connect (OSTI)

    Falter, W.; Keim, W.

    1994-12-31

    The direct synthesis of oxygenates starting from synthesis gas is feasible by homogeneous and heterogeneous catalysis. Homogeneous Rh and Ru based catalysts yielding methyl formate and alcohols will be presented. Interestingly, modified heterogeneous catalysts based on {open_quotes}Isobutyl Oel{close_quotes} catalysis, practized in Germany (BRD) up to 1952 and in the former DDR until recently, yield isobutanol in addition to methanol. These {open_quotes}Isobutyl Oel{close_quotes} catalysts are obtained by adding a base such as Li < Na < K < Cs to a Zn-Cr{sub 2}O{sub 3} methanol catalyst. Isobutanol is obtained in up to 15% yield. Our best catalyst a Zr-Zn-Mn-Li-Pd catalyst produced isobotanol up to 60% at a rate of 740g isobutanol per liter catalyst and hour.

  16. The solution combustion synthesis of nanophosphors

    SciTech Connect (OSTI)

    Tornga, Stephanie C

    2009-01-01

    Nanophosphors are defined as nano-sized (1-100mn), insulating, inorganic materials that emit light under particle or electromagnetic excitation. Their unique luminescence properties provide an excellent potential for applications in radiation detection and imaging. Herein, solution combustion synthesis (SCS) is presented as a method to prepare nanophosphor powders, while X-ray diffraction (XRD), transmission electron microscopy (TEM), photoluminescence (PL), photoluminescence excitation (PLE), and other techniques were used to characterize their structural and optical properties. The goal of this work is to synthesize bright, high-quality powders of nanophosphors, consolidate them into bulk materials and study their structural and optical properties using XRD, TEM, PL, and PLE. SCS is of interest because it is a robust, inexpensive, and facile technique, which yields a significant amount of a wide variety of oxide materials, in a short amount of time. Several practical nanophosphors were synthesized and investigated in this work, including simple oxides such as Y{sub 2}O{sub 3}:Bi, Y{sub 2}O{sub 3}:Tb, Y{sub 2}O{sub 3}:Eu and Gd{sub 2}O{sub 3}:Eu, complex oxides such as Gd{sub 2}SiO{sub 5}:Ce, Y{sub 2}SiO{sub 5}:Ce, Lu{sub 2}SiO{sub 5}:Ce, Zn{sub 2}SiO{sub 4}:Mn, and Y{sub 3}Al{sub 5}O{sub 12}:Ce. Results demonstrate that altering the processing parameters such as water content of the precursor solution, ignition temperature, fuel type and amount, and post-synthesis annealing can significantly improve light output, and that it is possible to optimize the luminescence output of oxyorthosilicates by reducing the amount of silica in the precursor mixture.

  17. Optical waveguides having flattened high order modes

    DOE Patents [OSTI]

    Messerly, Michael Joseph; Beach, Raymond John; Heebner, John Edward; Dawson, Jay Walter; Pax, Paul Henry

    2014-08-05

    A deterministic methodology is provided for designing optical fibers that support field-flattened, ring-like higher order modes. The effective and group indices of its modes can be tuned by adjusting the widths of the guide's field-flattened layers or the average index of certain groups of layers. The approach outlined here provides a path to designing fibers that simultaneously have large mode areas and large separations between the propagation constants of its modes.

  18. Multichannel optical sensing device

    DOE Patents [OSTI]

    Selkowitz, S.E.

    1985-08-16

    A multichannel optical sensing device is disclosed, for measuring the outdoor sky luminance or illuminance or the luminance or illuminance distribution in a room, comprising a plurality of light receptors, an optical shutter matrix including a plurality of liquid crystal optical shutter elements operable by electrical control signals between light transmitting and light stopping conditions, fiber optical elements connected between the receptors and the shutter elements, a microprocessor based programmable control unit for selectively supplying control signals to the optical shutter elements in a programmable sequence, a photodetector including an optical integrating spherical chamber having an input port for receiving the light from the shutter matrix and at least one detector element in the spherical chamber for producing output signals corresponding to the light, and output units for utilizing the output signals including a storage unit having a control connection to the microprocessor based programmable control unit for storing the output signals under the sequence control of the programmable control unit.

  19. Multichannel optical sensing device

    DOE Patents [OSTI]

    Selkowitz, Stephen E. (Piedmont, CA)

    1990-01-01

    A multichannel optical sensing device is disclosed, for measuring the outr sky luminance or illuminance or the luminance or illuminance distribution in a room, comprising a plurality of light receptors, an optical shutter matrix including a plurality of liquid crystal optical shutter elements operable by electrical control signals between light transmitting and light stopping conditions, fiber optic elements connected between the receptors and the shutter elements, a microprocessor based programmable control unit for selectively supplying control signals to the optical shutter elements in a programmable sequence, a photodetector including an optical integrating spherical chamber having an input port for receiving the light from the shutter matrix and at least one detector element in the spherical chamber for producing output signals corresponding to the light, and output units for utilizing the output signals including a storage unit having a control connection to the microprocessor based programmable control unit for storing the output signals under the sequence control of the programmable control unit.

  20. Atmospheric optical calibration system

    DOE Patents [OSTI]

    Hulstrom, Roland L. (Bloomfield, CO); Cannon, Theodore W. (Golden, CO)

    1988-01-01

    An atmospheric optical calibration system is provided to compare actual atmospheric optical conditions to standard atmospheric optical conditions on the basis of aerosol optical depth, relative air mass, and diffuse horizontal skylight to global horizontal photon flux ratio. An indicator can show the extent to which the actual conditions vary from standard conditions. Aerosol scattering and absorption properties, diffuse horizontal skylight to global horizontal photon flux ratio, and precipitable water vapor determined on a real-time basis for optical and pressure measurements are also used to generate a computer spectral model and for correcting actual performance response of a photovoltaic device to standard atmospheric optical condition response on a real-time basis as the device is being tested in actual outdoor conditions.

  1. Transpiration purged optical probe

    DOE Patents [OSTI]

    2004-01-06

    An optical apparatus for clearly viewing the interior of a containment vessel by applying a transpiration fluid to a volume directly in front of the external surface of the optical element of the optical apparatus. The fluid is provided by an external source and transported by means of an annular tube to a capped end region where the inner tube is perforated. The perforation allows the fluid to stream axially towards the center of the inner tube and then axially away from an optical element which is positioned in the inner tube just prior to the porous sleeve. This arrangement draws any contaminants away from the optical element keeping it free of contaminants. In one of several embodiments, the optical element can be a lens, a viewing port or a laser, and the external source can provide a transpiration fluid having either steady properties or time varying properties.

  2. Atmospheric optical calibration system

    DOE Patents [OSTI]

    Hulstrom, R.L.; Cannon, T.W.

    1988-10-25

    An atmospheric optical calibration system is provided to compare actual atmospheric optical conditions to standard atmospheric optical conditions on the basis of aerosol optical depth, relative air mass, and diffuse horizontal skylight to global horizontal photon flux ratio. An indicator can show the extent to which the actual conditions vary from standard conditions. Aerosol scattering and absorption properties, diffuse horizontal skylight to global horizontal photon flux ratio, and precipitable water vapor determined on a real-time basis for optical and pressure measurements are also used to generate a computer spectral model and for correcting actual performance response of a photovoltaic device to standard atmospheric optical condition response on a real-time basis as the device is being tested in actual outdoor conditions. 7 figs.

  3. Optical atomic magnetometer

    DOE Patents [OSTI]

    Budker, Dmitry; Higbie, James; Corsini, Eric P.

    2013-11-19

    An optical atomic magnetometers is provided operating on the principles of nonlinear magneto-optical rotation. An atomic vapor is optically pumped using linearly polarized modulated light. The vapor is then probed using a non-modulated linearly polarized light beam. The resulting modulation in polarization angle of the probe light is detected and used in a feedback loop to induce self-oscillation at the resonant frequency.

  4. Compound semiconductor optical waveguide switch

    DOE Patents [OSTI]

    Spahn, Olga B.; Sullivan, Charles T.; Garcia, Ernest J.

    2003-06-10

    An optical waveguide switch is disclosed which is formed from III-V compound semiconductors and which has a moveable optical waveguide with a cantilevered portion that can be bent laterally by an integral electrostatic actuator to route an optical signal (i.e. light) between the moveable optical waveguide and one of a plurality of fixed optical waveguides. A plurality of optical waveguide switches can be formed on a common substrate and interconnected to form an optical switching network.

  5. Prismatic optical display

    DOE Patents [OSTI]

    Veligdan, James T.; DeSanto, Leonard; Brewster, Calvin

    2004-06-29

    A spatially modulated light beam is projected, reflected, and redirected through a prismatic optical panel to form a video image for direct viewing thereon.

  6. Optical contact micrometer

    DOE Patents [OSTI]

    Jacobson, Steven D.

    2014-08-19

    Certain examples provide optical contact micrometers and methods of use. An example optical contact micrometer includes a pair of opposable lenses to receive an object and immobilize the object in a position. The example optical contact micrometer includes a pair of opposable mirrors positioned with respect to the pair of lenses to facilitate viewing of the object through the lenses. The example optical contact micrometer includes a microscope to facilitate viewing of the object through the lenses via the mirrors; and an interferometer to obtain one or more measurements of the object.

  7. Optical amplifiers and lasers

    DOE Patents [OSTI]

    Klimov, Victor I.; Mikhailovski, Alexandre; Hollingsworth, Jennifer A.; Leatherdale, Catherine A.; Bawendi, Moungi G.

    2004-11-16

    An optical amplifier and laser having both broad band and wide range specific band capability can be based on semiconductor nanocrystal solids.

  8. Optical limiting materials

    DOE Patents [OSTI]

    McBranch, Duncan W. (Santa Fe, NM); Mattes, Benjamin R. (Santa Fe, NM); Koskelo, Aaron C. (Los Alamos, NM); Heeger, Alan J. (Santa Barbara, CA); Robinson, Jeanne M. (Los Alamos, NM); Smilowitz, Laura B. (Los Alamos, NM); Klimov, Victor I. (Los Alamos, NM); Cha, Myoungsik (Goleta, CA); Sariciftci, N. Serdar (Santa Barbara, CA); Hummelen, Jan C. (Groningen, NL)

    1998-01-01

    Optical limiting materials. Methanofullerenes, fulleroids and/or other fullerenes chemically altered for enhanced solubility, in liquid solution, and in solid blends with transparent glass (SiO.sub.2) gels or polymers, or semiconducting (conjugated) polymers, are shown to be useful as optical limiters (optical surge protectors). The nonlinear absorption is tunable such that the energy transmitted through such blends saturates at high input energy per pulse over a wide range of wavelengths from 400-1100 nm by selecting the host material for its absorption wavelength and ability to transfer the absorbed energy into the optical limiting composition dissolved therein. This phenomenon should be generalizable to other compositions than substituted fullerenes.

  9. Facile synthesis and photoluminescence mechanism of graphene quantum dots

    SciTech Connect (OSTI)

    Yang, Ping; Zhou, Ligang; Zhang, Shenli; Pan, Wei Shen, Wenzhong; Wan, Neng

    2014-12-28

    We report a facile hydrothermal synthesis of intrinsic fluorescent graphene quantum dots (GQDs) with two-dimensional morphology. This synthesis uses glucose, concentrate sulfuric acid, and deionized water as reagents. Concentrated sulfuric acid is found to play a key role in controlling the transformation of as-prepared hydrothermal products from amorphous carbon nanodots to well-crystallized GQDs. These GQDs show typical absorption characteristic for graphene, and have nearly excitation-independent ultraviolet and blue intrinsic emissions. Temperature-dependent PL measurements have demonstrated strong electron-electron scattering and electron-phonon interactions, suggesting a similar temperature behavior of GQDs to inorganic semiconductor quantum dots. According to optical studies, the ultraviolet emission is found to originate from the recombination of electron-hole pairs localized in the C=C bonds, while the blue emission is from the electron transition of sp{sup 2} domains.

  10. Solvothermal routes for synthesis of zinc oxide nanorods.

    SciTech Connect (OSTI)

    Bell, Nelson Simmons

    2005-03-01

    Control of the synthesis of nanomaterials to produce morphologies exhibiting quantized properties will enable device integration of several novel applications including biosensors, catalysis, and optical devices. In this work, solvothermal routes to produce zinc oxide nanorods are explored. Much previous work has relied on the addition of growth directing/inhibiting agents to control morphology. It was found in coarsening studies that zinc oxide nanodots will ripen to nanorod morphologies at temperatures of 90 to 120 C. The resulting nanorods have widths of 9-12 nm average dimension, which is smaller than current methods for nanorod synthesis. Use of nanodots as nuclei may be an approach that will allow for controlled growth of higher aspect ratio nanorods.

  11. Topsoe integrated gasoline synthesis (TIGAS)

    SciTech Connect (OSTI)

    Hansen, H.K.; Joensen, F.

    1987-01-01

    Integration of Haldor Topsoe's oxygenate (MeOH, DME) synthesis and the MTG process into one single synthesis loop provides a new low investment route to gasoline from natural gas. The integrated process has been demonstrated in an industrial pilot with a capacity of 1 MTPD gasoline since 1984. The pilot has operated successfully for more than 10,000 hours.

  12. Telescope Adaptive Optics Code

    Energy Science and Technology Software Center (OSTI)

    2005-07-28

    The Telescope AO Code has general adaptive optics capabilities plus specialized models for three telescopes with either adaptive optics or active optics systems. It has the capability to generate either single-layer or distributed Kolmogorov turbulence phase screens using the FFT. Missing low order spatial frequencies are added using the Karhunen-Loeve expansion. The phase structure curve is extremely dose to the theoreUcal. Secondly, it has the capability to simulate an adaptive optics control systems. The defaultmore » parameters are those of the Keck II adaptive optics system. Thirdly, it has a general wave optics capability to model the science camera halo due to scintillation from atmospheric turbulence and the telescope optics. Although this capability was implemented for the Gemini telescopes, the only default parameter specific to the Gemini telescopes is the primary mirror diameter. Finally, it has a model for the LSST active optics alignment strategy. This last model is highly specific to the LSST« less

  13. XrayOpticsConstants

    Energy Science and Technology Software Center (OSTI)

    2005-06-20

    This application (XrayOpticsConstants) is a tool for displaying X-ray and Optical properties for a given material, x-ray photon energy, and in the case of a gas, pressure. The display includes fields such as the photo-electric absorption attenuation length, density, material composition, index of refraction, and emission properties (for scintillator materials).

  14. Dual frequency optical cavity

    DOE Patents [OSTI]

    George, E. Victor (Livermore, CA); Schipper, John F. (Palo Alto, CA)

    1985-01-01

    Method and apparatus for generating two distinct laser frequencies in an optical cavity, using a "T" configuration laser cavity and means for intermittently increasing or decreasing the index of refraction n of an associated transmission medium in one arm of the optical cavity to enhance laser action in one arm or the second arm of the cavity.

  15. Stepped inlet optical panel

    DOE Patents [OSTI]

    Veligdan, James T. (6 Stephanie La., Manorville, NY 11949)

    2001-01-01

    An optical panel includes stacked optical waveguides having stepped inlet facets collectively defining an inlet face for receiving image light, and having beveled outlet faces collectively defining a display screen for displaying the image light channeled through the waveguides by internal reflection.

  16. Flexible optical panel

    DOE Patents [OSTI]

    Veligdan, James T. (Manorville, NY)

    2001-01-01

    A flexible optical panel includes laminated optical waveguides, each including a ribbon core laminated between cladding, with the core being resilient in the plane of the core for elastically accommodating differential movement thereof to permit winding of the panel in a coil.

  17. Multimode optical fiber

    DOE Patents [OSTI]

    Bigot-Astruc, Marianne; Molin, Denis; Sillard, Pierre

    2014-11-04

    A depressed graded-index multimode optical fiber includes a central core, an inner depressed cladding, a depressed trench, an outer depressed cladding, and an outer cladding. The central core has an alpha-index profile. The depressed claddings limit the impact of leaky modes on optical-fiber performance characteristics (e.g., bandwidth, core size, and/or numerical aperture).

  18. Optical scanning apparatus

    DOE Patents [OSTI]

    Villarreal, R.A.

    1985-11-06

    An optical scanner employed in a radioactive environment for reading indicia imprinted about a cylindrical surface of an article by means of an optical system including metallic reflective and mirror surfaces resistant to degradation and discoloration otherwise imparted to glass surfaces exposed to radiation is described.

  19. Fiber optic hydrophone

    DOE Patents [OSTI]

    Kuzmenko, P.J.; Davis, D.T.

    1994-05-10

    A miniature fiber optic hydrophone based on the principles of a Fabry-Perot interferometer is disclosed. The hydrophone, in one embodiment, includes a body having a shaped flexible bladder at one end which defines a volume containing air or suitable gas, and including a membrane disposed adjacent a vent. An optical fiber extends into the body with one end terminating in spaced relation to the membrane. Acoustic waves in the water that impinge on the bladder cause the pressure of the volume therein to vary causing the membrane to deflect and modulate the reflectivity of the Fabry-Perot cavity formed by the membrane surface and the cleaved end of the optical fiber disposed adjacent to the membrane. When the light is transmitted down the optical fiber, the reflected signal is amplitude modulated by the incident acoustic wave. Another embodiment utilizes a fluid filled volume within which the fiber optic extends. 2 figures.

  20. Fiber optic hydrophone

    DOE Patents [OSTI]

    Kuzmenko, Paul J. (Livermore, CA); Davis, Donald T. (Livermore, CA)

    1994-01-01

    A miniature fiber optic hydrophone based on the principles of a Fabry-Perot interferometer. The hydrophone, in one embodiment, includes a body having a shaped flexible bladder at one end which defines a volume containing air or suitable gas, and including a membrane disposed adjacent a vent. An optic fiber extends into the body with one end terminating in spaced relation to the membrane. Acoustic waves in the water that impinge on the bladder cause the pressure of the volume therein to vary causing the membrane to deflect and modulate the reflectivity of the Fabry-Perot cavity formed by the membrane surface and the cleaved end of the optical fiber disposed adjacent to the membrane. When the light is transmitted down the optical fiber, the reflected signal is amplitude modulated by the incident acoustic wave. Another embodiment utilizes a fluid filled volume within which the fiber optic extends.

  1. Digital optical conversion module

    DOE Patents [OSTI]

    Kotter, D.K.; Rankin, R.A.

    1988-07-19

    A digital optical conversion module used to convert an analog signal to a computer compatible digital signal including a voltage-to-frequency converter, frequency offset response circuitry, and an electrical-to-optical converter. Also used in conjunction with the digital optical conversion module is an optical link and an interface at the computer for converting the optical signal back to an electrical signal. Suitable for use in hostile environments having high levels of electromagnetic interference, the conversion module retains high resolution of the analog signal while eliminating the potential for errors due to noise and interference. The module can be used to link analog output scientific equipment such as an electrometer used with a mass spectrometer to a computer. 2 figs.

  2. Digital optical conversion module

    DOE Patents [OSTI]

    Kotter, Dale K. (North Shelley, ID); Rankin, Richard A. (Ammon, ID)

    1991-02-26

    A digital optical conversion module used to convert an analog signal to a computer compatible digital signal including a voltage-to-frequency converter, frequency offset response circuitry, and an electrical-to-optical converter. Also used in conjunction with the digital optical conversion module is an optical link and an interface at the computer for converting the optical signal back to an electrical signal. Suitable for use in hostile environments having high levels of electromagnetic interference, the conversion module retains high resolution of the analog signal while eliminating the potential for errors due to noise and interference. The module can be used to link analog output scientific equipment such as an electrometer used with a mass spectrometer to a computer.

  3. Proceedings of the PILAC optics workshop

    SciTech Connect (OSTI)

    Not Available

    1991-11-01

    This report contains viewgraphs on the following topics: PILAC Overview; PILAC Injection Line; PILAC General-Purpose Line Design; Program RAYTRACE; Design Performance of MRS; Program MOTER; Recent Upgrades of MOTER; Use of MOTER at Michigan State; Spectrometer Design at Michigan State; Use of MOTER at CEBAF Related Topics; TOSCA Calculations at CEBAF; TOSCA Calculations for PILAC; Measurements of EPICS Quadrupoles; Quadrupole Measurements and Analysis at Bates Laboratory; Analysis of 3D Quadrupole Data; Quadrupole 3D Fringe Fields (Theoretical Lecture); Analysis of 3D Field Data; Analysis of Dipole Fringe Fields; Quadrupoles with Perfect N=2 Symmetry; CEBAF Superconducting Cos (20) Quadrupole; Upgrades to TRANSPORT and TURTLE; Optics using Differential Algebra; and A Possible Test of Quad Optics Using EPICS.

  4. Proceedings of the PILAC optics workshop

    SciTech Connect (OSTI)

    Not Available

    1991-11-01

    This report contains viewgraphs on the following topics: PILAC Overview; PILAC Injection Line; PILAC General-Purpose Line Design; Program RAYTRACE; Design & Performance of MRS; Program MOTER; Recent Upgrades of MOTER; Use of MOTER at Michigan State; Spectrometer Design at Michigan State; Use of MOTER at CEBAF & Related Topics; TOSCA Calculations at CEBAF; TOSCA Calculations for PILAC; Measurements of EPICS Quadrupoles; Quadrupole Measurements and Analysis at Bates Laboratory; Analysis of 3D Quadrupole Data; Quadrupole 3D Fringe Fields (Theoretical Lecture); Analysis of 3D Field Data; Analysis of Dipole Fringe Fields; Quadrupoles with Perfect N=2 Symmetry; CEBAF Superconducting Cos (20) Quadrupole; Upgrades to TRANSPORT and TURTLE; Optics using Differential Algebra; and A Possible Test of Quad Optics Using EPICS.

  5. Estimating of pulsed electric fields using optical measurements.

    SciTech Connect (OSTI)

    Flanagan, Timothy McGuire; Chantler, Gary R.

    2013-09-01

    We performed optical electric field measurements ion nanosecond time scales using the electrooptic crystal beta barium borate (BBO). Tests were based on a preliminary bench top design intended to be a proofofprinciple stepping stone towards a modulardesign optical Efield diagnostic that has no metal in the interrogated environment. The long term goal is to field a modular version of the diagnostic in experiments on large scale xray source facilities, or similarly harsh environments.

  6. Fiber optics in the BNL booster radiation environment

    SciTech Connect (OSTI)

    Beadle, E.R.

    1991-01-01

    The Booster instrumentation uses analog and digital fiber optic links, designed to withstand at least 50 krads without performance degradation. The links use inexpensive and commercially available components that operate at a center wavelength of 820 nm. The analog link operates to 30 MHz over a 200 m fiber and can provide insertion gain. The digital link provides 60 ns timing pulses without the dispersive effects of coaxial cables. The optical fiber is a step-index hard clad silica type with a 200 micron core. This paper presents the component selection criteria, link design, installation, testing and performance for the optical links in the Booster instrumentation systems. 7 refs., 4 figs.

  7. Modular initiator with integrated optical diagnostic

    DOE Patents [OSTI]

    Alam, M. Kathleen (Cedar Crest, NM); Schmitt, Randal L. (Tijeras, NM); Welle, Eric J. (Niceville, FL); Madden, Sean P. (Arlington, MA)

    2011-05-17

    A slapper detonator which integrally incorporates an optical wavequide structure for determining whether there has been degradation of the explosive in the explosive device that is to be initiated by the detonator. Embodiments of this invention take advantage of the barrel-like character of a typical slapper detonator design. The barrel assembly, being in direct contact with the energetic material, incorporates an optical diagnostic device into the barrel assembly whereby one can monitor the state of the explosive material. Such monitoring can be beneficial because the chemical degradation of the explosive plays an important in achieving proper functioning of a detonator/initiator device.

  8. Characterization of Photo-Induced Charge Transfer and Hot Carrier...

    Office of Scientific and Technical Information (OSTI)

    phonons, thermal conductivity, electrodes - solar, materials and chemistry by design, optics, synthesis (novel materials), synthesis (self-assembly) Word Cloud More Like This Full...

  9. Synthesis and study of conjugated polymers containing Di- or Triphenylamine

    SciTech Connect (OSTI)

    Sukwattanasinitt, M.

    1996-06-21

    This thesis consists of two separate parts. The first part addresses the synthesis and study of conjugated polymers containing di- or triphenylamine. Two types of polymers: linear polymers and dendrimers, were synthesized. The polymers were characterized by NMR, IR, UV, GPC, TGA and DSC. Electronic and optical properties of the polymers were studied through the conductivity measurements and excitation- emission spectra. the second part of this thesis deals with a reaction of electron-rich acetylenes with TCNE. The discovery of the reaction from charge transfer complex studies and the investigation of this reaction on various electron-rich acetylenes are presented.

  10. Projection optics box

    DOE Patents [OSTI]

    Hale, Layton C. (Livermore, CA); Malsbury, Terry (Tracy, CA); Hudyma, Russell M. (San Ramon, CA); Parker, John M. (Tracy, CA)

    2000-01-01

    A projection optics box or assembly for use in an optical assembly, such as in an extreme ultraviolet lithography (EUVL) system using 10-14 nm soft x-ray photons. The projection optics box utilizes a plurality of highly reflective optics or mirrors, each mounted on a precision actuator, and which reflects an optical image, such as from a mask, in the EUVL system onto a point of use, such as a target or silicon wafer, the mask, for example, receiving an optical signal from a source assembly, such as a developed from laser system, via a series of highly reflective mirrors of the EUVL system. The plurality of highly reflective optics or mirrors are mounted in a housing assembly comprised of a series of bulkheads having wall members secured together to form a unit construction of maximum rigidity. Due to the precision actuators, the mirrors must be positioned precisely and remotely in tip, tilt, and piston (three degrees of freedom), while also providing exact constraint.

  11. Achromatic Interaction Point Design

    SciTech Connect (OSTI)

    Guimei Wang,, Yaroslav Derbenev, S.Alex Bogacz, P. Chevtsov, Andre Afanaciev, Charles Ankenbrandt, Valentin Ivanov, Rolland P. Johnson

    2009-05-01

    Designers of high-luminosity energy-frontier muon colliders must provide strong beam focusing in the interaction regions. However, the construction of a strong, aberration-free beam focus is difficult and space consuming, and long straight sections generate an off-site radiation problem due to muon decay neutrinos that interact as they leave the surface of the earth. Without some way to mitigate the neutrino radiation problem, the maximum c.m. energy of a muon collider will be limited to about 3.5 TeV. A new concept for achromatic low beta design is being developed, in which the interaction region telescope and optical correction elements, are installed in the bending arcs. The concept, formulated analytically, combines space economy, a preventative approach to compensation for aberrations, and a reduction of neutrino flux concentration. An analytical theory for the aberration-free, low beta, spatially compact insertion is being developed.

  12. Semiconductor sensor for optically measuring polarization rotation of optical wavefronts using rare earth iron garnets

    DOE Patents [OSTI]

    Duncan, Paul G. (8544 Electric Ave., Vienna, VA 22182)

    2002-01-01

    Described are the design of a rare earth iron garnet sensor element, optical methods of interrogating the sensor element, methods of coupling the optical sensor element to a waveguide, and an optical and electrical processing system for monitoring the polarization rotation of a linearly polarized wavefront undergoing external modulation due to magnetic field or electrical current fluctuation. The sensor element uses the Faraday effect, an intrinsic property of certain rare-earth iron garnet materials, to rotate the polarization state of light in the presence of a magnetic field. The sensor element may be coated with a thin-film mirror to effectively double the optical path length, providing twice the sensitivity for a given field strength or temperature change. A semiconductor sensor system using a rare earth iron garnet sensor element is described.

  13. ARM - Measurement - Aerosol optical properties

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    : Aerosol optical properties The optical properties of aerosols, including asymmetry factor, phase-function, single-scattering albedo, refractive index, and backscatter...

  14. LSU EFRC - Center for Atomic Level Catalyst Design - Article Archives

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Articles >> space control Catalysts by Design for Syngas Cleanup space control Quantitative Relationship between Support Porosity and the Stability of Pore-Confined Metal Nanoparticles Studied on CuZnO/SiO2 Methanol Synthesis Catalysts space control Millifluidics for Time-resolved Mapping of the Growth of Gold Nanostructures space control Geometric optimization of liquid-liquid slug flow in a flow-focusing millifluidic device for synthesis of nanomaterials space control An article about

  15. LSU EFRC - Center for Atomic Level Catalyst Design

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    space control Our Mission Statement space control "Building Effective Catalysts from First Principles: Computational Catalysis and Atomic-Level Synthesis" The mission of LSU's Center for Atomic Level Catalyst Design is to advance: the ability of computational methods to accurately model catalytic reactions on solid surfaces over time and length scales far more representative of realistic conditions than is possible at present, and the tools of materials synthesis/characterization, so

  16. Tuned optical cavity magnetometer

    DOE Patents [OSTI]

    Okandan, Murat (Edgewood, NM); Schwindt, Peter (Albuquerque, NM)

    2010-11-02

    An atomic magnetometer is disclosed which utilizes an optical cavity formed from a grating and a mirror, with a vapor cell containing an alkali metal vapor located inside the optical cavity. Lasers are used to magnetically polarize the alkali metal vapor and to probe the vapor and generate a diffracted laser beam which can be used to sense a magnetic field. Electrostatic actuators can be used in the magnetometer for positioning of the mirror, or for modulation thereof. Another optical cavity can also be formed from the mirror and a second grating for sensing, adjusting, or stabilizing the position of the mirror.

  17. Fiber optic laser rod

    DOE Patents [OSTI]

    Erickson, G.F.

    1988-04-13

    A laser rod is formed from a plurality of optical fibers, each forming an individual laser. Synchronization of the individual fiber lasers is obtained by evanescent wave coupling between adjacent optical fiber cores. The fiber cores are dye-doped and spaced at a distance appropriate for evanescent wave coupling at the wavelength of the selected dye. An interstitial material having an index of refraction lower than that of the fiber core provides the optical isolation for effective lasing action while maintaining the cores at the appropriate coupling distance. 2 figs.

  18. Optical limiting materials

    DOE Patents [OSTI]

    McBranch, D.W.; Mattes, B.R.; Koskelo, A.C.; Heeger, A.J.; Robinson, J.M.; Smilowitz, L.B.; Klimov, V.I.; Cha, M.; Sariciftci, N.S.; Hummelen, J.C.

    1998-04-21

    Methanofullerenes, fulleroids and/or other fullerenes chemically altered for enhanced solubility, in liquid solution, and in solid blends with transparent glass (SiO{sub 2}) gels or polymers, or semiconducting (conjugated) polymers, are shown to be useful as optical limiters (optical surge protectors). The nonlinear absorption is tunable such that the energy transmitted through such blends saturates at high input energy per pulse over a wide range of wavelengths from 400--1,100 nm by selecting the host material for its absorption wavelength and ability to transfer the absorbed energy into the optical limiting composition dissolved therein. This phenomenon should be generalizable to other compositions than substituted fullerenes. 5 figs.

  19. Silicon fiber optic sensors

    DOE Patents [OSTI]

    Pocha, Michael D. (Livermore, CA); Swierkowski, Steve P. (Livermore, CA); Wood, Billy E. (Livermore, CA)

    2007-10-02

    A Fabry-Perot cavity is formed by a partially or wholly reflective surface on the free end of an integrated elongate channel or an integrated bounding wall of a chip of a wafer and a partially reflective surface on the end of the optical fiber. Such a constructed device can be utilized to detect one or more physical parameters, such as, for example, strain, through the optical fiber using an optical detection system to provide measuring accuracies of less than aboutb0.1%.

  20. Computational method and system for modeling, analyzing, and optimizing DNA amplification and synthesis

    DOE Patents [OSTI]

    Vandersall, Jennifer A.; Gardner, Shea N.; Clague, David S.

    2010-05-04

    A computational method and computer-based system of modeling DNA synthesis for the design and interpretation of PCR amplification, parallel DNA synthesis, and microarray chip analysis. The method and system include modules that address the bioinformatics, kinetics, and thermodynamics of DNA amplification and synthesis. Specifically, the steps of DNA selection, as well as the kinetics and thermodynamics of DNA hybridization and extensions, are addressed, which enable the optimization of the processing and the prediction of the products as a function of DNA sequence, mixing protocol, time, temperature and concentration of species.

  1. Structure-Based Design of Novel HIV-1 Protease Inhibitors to Combat Drug Resistance

    SciTech Connect (OSTI)

    Ghosh,A.; Sridhar, P.; Leshchenko, S.; Hussain, A.; Li, J.; Kovalevsky, A.; Walters, D.; Wedelind, J.; Grum-Tokars, V.; et al.

    2006-01-01

    Structure-based design and synthesis of novel HIV protease inhibitors are described. The inhibitors are designed specifically to interact with the backbone of HIV protease active site to combat drug resistance. Inhibitor 3 has exhibited exceedingly potent enzyme inhibitory and antiviral potency. Furthermore, this inhibitor maintains impressive potency against a wide spectrum of HIV including a variety of multi-PI-resistant clinical strains. The inhibitors incorporated a stereochemically defined 5-hexahydrocyclopenta[b]furanyl urethane as the P2-ligand into the (R)-(hydroxyethylamino)sulfonamide isostere. Optically active (3aS,5R,6aR)-5-hydroxy-hexahydrocyclopenta[b]furan was prepared by an enzymatic asymmetrization of meso-diacetate with acetyl cholinesterase, radical cyclization, and Lewis acid-catalyzed anomeric reduction as the key steps. A protein-ligand X-ray crystal structure of inhibitor 3-bound HIV-1 protease (1.35 Angstroms resolution) revealed extensive interactions in the HIV protease active site including strong hydrogen bonding interactions with the backbone. This design strategy may lead to novel inhibitors that can combat drug resistance.

  2. Gregorian optical system with non-linear optical technology for protection against intense optical transients

    DOE Patents [OSTI]

    Ackermann, Mark R. (Albuquerque, NM); Diels, Jean-Claude M. (Albuquerque, NM)

    2007-06-26

    An optical system comprising a concave primary mirror reflects light through an intermediate focus to a secondary mirror. The secondary mirror re-focuses the image to a final image plane. Optical limiter material is placed near the intermediate focus to optically limit the intensity of light so that downstream components of the optical system are protected from intense optical transients. Additional lenses before and/or after the intermediate focus correct optical aberrations.

  3. Cathode Synthesis and Voltage Fade: Designed Solutions Based on Theory

    Broader source: Energy.gov [DOE]

    2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  4. Multi-tipped optical component

    DOE Patents [OSTI]

    D'Urso, Brian R.; Simpson, John T.

    2010-04-13

    An optical component has a plurality of parallel noncontiguous optical conduits of at least one protrusive phase material embedded in a recessive phase material that acts as a support structure. The optical conduits extend from a proximal surface to a distal surface of the optical component. The distal surface has a plurality of spaced apart surface features of the protrusive phase material. Each independent optical conduits act as waveguides for a wavelength or range of wavelengths. The optical component can be formed such that the protruding surface features at the distal end of the component form an ordered array. An optical instrument can include the optical component in conjunction with a light source for illuminating a sample and a detector in optical communication optical component via the optical conduits.

  5. Advanced Imaging Optics Utilizing Wavefront Coding.

    SciTech Connect (OSTI)

    Scrymgeour, David; Boye, Robert; Adelsberger, Kathleen

    2015-06-01

    Image processing offers a potential to simplify an optical system by shifting some of the imaging burden from lenses to the more cost effective electronics. Wavefront coding using a cubic phase plate combined with image processing can extend the system's depth of focus, reducing many of the focus-related aberrations as well as material related chromatic aberrations. However, the optimal design process and physical limitations of wavefront coding systems with respect to first-order optical parameters and noise are not well documented. We examined image quality of simulated and experimental wavefront coded images before and after reconstruction in the presence of noise. Challenges in the implementation of cubic phase in an optical system are discussed. In particular, we found that limitations must be placed on system noise, aperture, field of view and bandwidth to develop a robust wavefront coded system.

  6. Optical gamma thermometer

    DOE Patents [OSTI]

    Koster, Glen Peter; Xia, Hua; Lee, Boon Kwee

    2013-08-06

    An optical gamma thermometer includes a metal mass having a temperature proportional to a gamma flux within a core of a nuclear reactor, and an optical fiber cable for measuring the temperature of the heated metal mass. The temperature of the heated mass may be measured by using one or more fiber grating structures and/or by using scattering techniques, such as Raman, Brillouin, and the like. The optical gamma thermometer may be used in conjunction with a conventional reactor heat balance to calibrate the local power range monitors over their useful in-service life. The optical gamma thermometer occupies much less space within the in-core instrument tube and costs much less than the conventional gamma thermometer.

  7. Stereoscopic optical viewing system

    DOE Patents [OSTI]

    Tallman, Clifford S. (Walnut Creek, CA)

    1987-01-01

    An improved optical system which provides the operator a stereoscopic viewing field and depth of vision, particularly suitable for use in various machines such as electron or laser beam welding and drilling machines. The system features two separate but independently controlled optical viewing assemblies from the eyepiece to a spot directly above the working surface. Each optical assembly comprises a combination of eye pieces, turning prisms, telephoto lenses for providing magnification, achromatic imaging relay lenses and final stage pentagonal turning prisms. Adjustment for variations in distance from the turning prisms to the workpiece, necessitated by varying part sizes and configurations and by the operator's visual accuity, is provided separately for each optical assembly by means of separate manual controls at the operator console or within easy reach of the operator.

  8. Optical displacement sensor

    DOE Patents [OSTI]

    Carr, Dustin W. (Albuquerque, NM)

    2008-04-08

    An optical displacement sensor is disclosed which uses a vertical-cavity surface-emitting laser (VCSEL) coupled to an optical cavity formed by a moveable membrane and an output mirror of the VCSEL. This arrangement renders the lasing characteristics of the VCSEL sensitive to any movement of the membrane produced by sound, vibrations, pressure changes, acceleration, etc. Some embodiments of the optical displacement sensor can further include a light-reflective diffractive lens located on the membrane or adjacent to the VCSEL to control the amount of lasing light coupled back into the VCSEL. A photodetector detects a portion of the lasing light from the VCSEL to provide an electrical output signal for the optical displacement sensor which varies with the movement of the membrane.

  9. Stereoscopic optical viewing system

    DOE Patents [OSTI]

    Tallman, C.S.

    1986-05-02

    An improved optical system which provides the operator with a stereoscopic viewing field and depth of vision, particularly suitable for use in various machines such as electron or laser beam welding and drilling machines. The system features two separate but independently controlled optical viewing assemblies from the eyepiece to a spot directly above the working surface. Each optical assembly comprises a combination of eye pieces, turning prisms, telephoto lenses for providing magnification, achromatic imaging relay lenses and final stage pentagonal turning prisms. Adjustment for variations in distance from the turning prisms to the workpiece, necessitated by varying part sizes and configurations and by the operator's visual accuity, is provided separately for each optical assembly by means of separate manual controls at the operator console or within easy reach of the operator.

  10. Optical fiber switch

    DOE Patents [OSTI]

    Early, James W. (Los Alamos, NM); Lester, Charles S. (San Juan Pueblo, NM)

    2002-01-01

    Optical fiber switches operated by electrical activation of at least one laser light modulator through which laser light is directed into at least one polarizer are used for the sequential transport of laser light from a single laser into a plurality of optical fibers. In one embodiment of the invention, laser light from a single excitation laser is sequentially transported to a plurality of optical fibers which in turn transport the laser light to separate individual remotely located laser fuel ignitors. The invention can be operated electro-optically with no need for any mechanical or moving parts, or, alternatively, can be operated electro-mechanically. The invention can be used to switch either pulsed or continuous wave laser light.

  11. Fiber optic fluid detector

    DOE Patents [OSTI]

    Angel, S. Michael (Livermore, CA)

    1989-01-01

    Particular gases or liquids are detected with a fiber optic element (11, 11a to 11j) having a cladding or coating of a material (23, 23a to 23j) which absorbs the fluid or fluids and which exhibits a change of an optical property, such as index of refraction, light transmissiveness or fluoresence emission, for example, in response to absorption of the fluid. The fluid is sensed by directing light into the fiber optic element and detecting changes in the light, such as exit angle changes for example, that result from the changed optical property of the coating material. The fluid detector (24, 24a to 24j) may be used for such purposes as sensing toxic or explosive gases in the atmosphere, measuring ground water contamination or monitoring fluid flows in industrial processes, among other uses.

  12. Erected mirror optical switch

    DOE Patents [OSTI]

    Allen, James J.

    2005-06-07

    A microelectromechanical (MEM) optical switching apparatus is disclosed that is based on an erectable mirror which is formed on a rotatable stage using surface micromachining. An electrostatic actuator is also formed on the substrate to rotate the stage and mirror with a high angular precision. The mirror can be erected manually after fabrication of the device and used to redirect an incident light beam at an arbitrary angel and to maintain this state in the absence of any applied electrical power. A 1.times.N optical switch can be formed using a single rotatable mirror. In some embodiments of the present invention, a plurality of rotatable mirrors can be configured so that the stages and mirrors rotate in unison when driven by a single micromotor thereby forming a 2.times.2 optical switch which can be used to switch a pair of incident light beams, or as a building block to form a higher-order optical switch.

  13. Fiber optic fluid detector

    DOE Patents [OSTI]

    Angel, S.M.

    1987-02-27

    Particular gases or liquids are detected with a fiber optic element having a cladding or coating of a material which absorbs the fluid or fluids and which exhibits a change of an optical property, such as index of refraction, light transmissiveness or fluoresence emission, for example, in response to absorption of the fluid. The fluid is sensed by directing light into the fiber optic element and detecting changes in the light, such as exit angle changes for example, that result from the changed optical property of the coating material. The fluid detector may be used for such purposes as sensing toxic or explosive gases in the atmosphere, measuring ground water contamination or monitoring fluid flows in industrial processes, among other uses. 10 figs.

  14. Methods for globally treating silica optics to reduce optical damage

    DOE Patents [OSTI]

    Miller, Philip Edward; Suratwala, Tayyab Ishaq; Bude, Jeffrey Devin; Shen, Nan; Steele, William Augustus; Laurence, Ted Alfred; Feit, Michael Dennis; Wong, Lana Louie

    2012-11-20

    A method for preventing damage caused by high intensity light sources to optical components includes annealing the optical component for a predetermined period. Another method includes etching the optical component in an etchant including fluoride and bi-fluoride ions. The method also includes ultrasonically agitating the etching solution during the process followed by rinsing of the optical component in a rinse bath.

  15. Optical layout and mechanical structure of polarimeter-interferometer system for Experimental Advanced Superconducting Tokamak

    SciTech Connect (OSTI)

    Zou, Z. Y.; Liu, H. Q. Jie, Y. X.; Wang, Z. X.; Shen, J. S.; An, Z. H.; Yang, Y.; Zeng, L.; Wei, X. C.; Li, G. S.; Zhu, X.; Ding, W. X.; Brower, D. L.; Lan, T.

    2014-11-15

    A Far-InfaRed (FIR) three-wave POlarimeter-INTerferometer (POINT) system for measurement current density profile and electron density profile is under development for the EAST tokamak. The FIR beams are transmitted from the laser room to the optical tower adjacent to EAST via ?20 m overmoded dielectric waveguide and then divided into 5 horizontal chords. The optical arrangement was designed using ZEMAX, which provides information on the beam spot size and energy distribution throughout the optical system. ZEMAX calculations used to optimize the optical layout design are combined with the mechanical design from CATIA, providing a 3D visualization of the entire POINT system.

  16. Synthesis of acylphosphonites

    SciTech Connect (OSTI)

    Prishchenko, A.A.; Livantsov, M.V.; Lutsenko I.F.

    1987-12-10

    The authors showed earlier that (alkoxycarbonyl)phosphonites are obtained in high yields by the reactions of (dialkoxymethyl)phosphonites with alkyl chloroformates. In the present work the analogous reactions of the phosphonites with acyl chlorides were applied in the synthesis of the previously difficultly accessible acylphosphonites. The phosphonites are formed rapidly when mixtures of the reactants are boiled in ether. The IR spectra were determined on a IKS-22 spectrometer, the PMR spectra of a Tesla BS-467 spectrometer, and /sup 13/C and /sup 31/P NMR spectra on Varian FT-80A and Jeol FX-100 spectrometers; standards: TMS (/sup 1/H, /sup 13/C) and an 85% solution of H/sub 3/PO/sub 4/ in D/sub 2/O.

  17. Patent: Optically transduced MEMS magnetometer | DOEpatents

    Office of Scientific and Technical Information (OSTI)

    Optically transduced MEMS magnetometer Citation Details Title: Optically transduced MEMS magnetometer

  18. Optical pumping in a whispering mode optical waveguide

    DOE Patents [OSTI]

    Kurnit, Norman A. (Santa Fe, NM)

    1984-01-01

    A device and method for optical pumping in a whispering mode optical waveguide. Both a helical ribbon and cylinder are disclosed which incorporate an additional curvature for confining the beam to increase intensity. An optical pumping medium is disposed in the optical path of the beam as it propagates along the waveguide. Optical pumping is enhanced by the high intensities of the beam and long interaction pathlengths which are achieved in a small volume.

  19. Optical pumping in a whispering-mode optical waveguide

    DOE Patents [OSTI]

    Kurnit, N.A.

    1981-08-11

    A device and method for optical pumping in a whispering mode optical waveguide are described. Both a helical ribbon and cylinder are disclosed which incorporate an additional curvature for confining the beam to increase intensity. An optical pumping medium is disposed in the optical path of the beam as it propagates along the waveguide. Optical pumping is enhanced by the high intensities of the beam and long interaction path lengths which are achieved in a small volume.

  20. Fault location in optical networks

    DOE Patents [OSTI]

    Stevens, Rick C. (Apple Valley, MN); Kryzak, Charles J. (Mendota Heights, MN); Keeler, Gordon A. (Albuquerque, NM); Serkland, Darwin K. (Albuquerque, NM); Geib, Kent M. (Tijeras, NM); Kornrumpf, William P. (Schenectady, NY)

    2008-07-01

    One apparatus embodiment includes an optical emitter and a photodetector. At least a portion of the optical emitter extends a radial distance from a center point. The photodetector provided around at least a portion of the optical emitter and positioned outside the radial distance of the portion of the optical emitter.

  1. Fibre optics: Forty years later

    SciTech Connect (OSTI)

    Dianov, Evgenii M

    2010-01-31

    This paper presents a brief overview of the state of the art in fibre optics and its main applications: optical fibre communications, fibre lasers and fibre sensors for various physical property measurements. The future of fibre optics and the status of this important area of the modern technology in Russia are discussed. (fiber optics)

  2. Electro-optic voltage sensor head

    DOE Patents [OSTI]

    Crawford, Thomas M.; Davidson, James R.; Woods, Gregory K.

    1999-01-01

    The invention is an electro-optic voltage sensor head designed for integration with existing types of high voltage transmission and distribution apparatus. The sensor head contains a transducer, which comprises a transducing material in which the Pockels electro-optic effect is observed. In the practice of the invention at least one beam of electromagnetic radiation is routed into the transducing material of the transducer in the sensor head. The beam undergoes an electro-optic effect in the sensor head when the transducing material is subjected to an E-field. The electro-optic effect is observed as a differential phase a shift, also called differential phase modulation, of the beam components in orthogonal planes of the electromagnetic radiation. In the preferred embodiment the beam is routed through the transducer along an initial axis and then reflected by a retro-reflector back substantially parallel to the initial axis, making a double pass through the transducer for increased measurement sensitivity. The preferred embodiment of the sensor head also includes a polarization state rotator and at least one beam splitter for orienting the beam along major and minor axes and for splitting the beam components into two signals which are independent converse amplitude-modulated signals carrying E-field magnitude and hence voltage information from the sensor head by way of optic fibers.

  3. Electro-optic voltage sensor head

    DOE Patents [OSTI]

    Crawford, T.M.; Davidson, J.R.; Woods, G.K.

    1999-08-17

    The invention is an electro-optic voltage sensor head designed for integration with existing types of high voltage transmission and distribution apparatus. The sensor head contains a transducer, which comprises a transducing material in which the Pockels electro-optic effect is observed. In the practice of the invention at least one beam of electromagnetic radiation is routed into the transducing material of the transducer in the sensor head. The beam undergoes an electro-optic effect in the sensor head when the transducing material is subjected to an E-field. The electro-optic effect is observed as a differential phase a shift, also called differential phase modulation, of the beam components in orthogonal planes of the electromagnetic radiation. In the preferred embodiment the beam is routed through the transducer along an initial axis and then reflected by a retro-reflector back substantially parallel to the initial axis, making a double pass through the transducer for increased measurement sensitivity. The preferred embodiment of the sensor head also includes a polarization state rotator and at least one beam splitter for orienting the beam along major and minor axes and for splitting the beam components into two signals which are independent converse amplitude-modulated signals carrying E-field magnitude and hence voltage information from the sensor head by way of optic fibers. 6 figs.

  4. Integrated digital metamaterials enables ultra-compact optical diodes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shen, Bing; Polson, Randy; Menon, Rajesh

    2015-01-01

    We applied nonlinear optimization to design integrated digital metamaterials in silicon for unidirectional energy flow. Two devices, one for each polarization state, were designed, fabricated, and characterized. Both devices offer comparable or higher transmission efficiencies and extinction ratios, are easier to fabricate, exhibit larger bandwidths and are more tolerant to fabrication errors, when compared to alternatives. Furthermore, each device footprint is only 3?m 3?m, which is the smallest optical diode ever reported. To illustrate the versatility of digital metamaterials, we also designed a polarization-independent optical diode.

  5. Embedded fiducials in optical surfaces

    DOE Patents [OSTI]

    Sommargren, Gary E. (Santa Cruz, CA)

    2000-01-01

    Embedded fiducials are provided in optical surfaces and a method for embedding the fiducials. Fiducials, or marks on a surface, are important for optical fabrication and alignment, particularly when individual optical elements are aspheres. Fiducials are used during the course of the polishing process to connect interferometric data, and the equation describing the asphere, to physical points on the optic. By embedding fiducials below the surface of the optic and slightly outside the clear aperture of the optic, the fiducials are not removed by polishing, do not interfere with the polishing process, and do not affect the performance of the finished optic.

  6. Quasi-Optical 34-GHz Rf Pulse Compressor

    SciTech Connect (OSTI)

    Hirshfield, Jay L

    2007-06-19

    Designs have been carried out on non-high-vacuum, low-power versions of three- and four-mirror quasi-optical passive and active Ka-band pulse compressors, and prototypes built and tested based on these designs. The active element is a quasi-optical grating employing gas discharge tubes in the gratings. Power gains of about 3:1 were observed experimentally for the passive designs, and about 7:1 with the active designs. High-power, high-vacuum versions of the three-and four-mirror quasi-optical pulse compressors were built and tested at low power. These now await installation and testing using multi-MW power from the 34-GHz magnicon.

  7. Differential Optical Synthetic Aperture Radar

    DOE Patents [OSTI]

    Stappaerts, Eddy A. (San Ramon, CA)

    2005-04-12

    A new differential technique for forming optical images using a synthetic aperture is introduced. This differential technique utilizes a single aperture to obtain unique (N) phases that can be processed to produce a synthetic aperture image at points along a trajectory. This is accomplished by dividing the aperture into two equal "subapertures", each having a width that is less than the actual aperture, along the direction of flight. As the platform flies along a given trajectory, a source illuminates objects and the two subapertures are configured to collect return signals. The techniques of the invention is designed to cancel common-mode errors, trajectory deviations from a straight line, and laser phase noise to provide the set of resultant (N) phases that can produce an image having a spatial resolution corresponding to a synthetic aperture.

  8. Application of modern-control-design methodologies to a multi-segmented deformable-mirror system. Master's thesis

    SciTech Connect (OSTI)

    Vaughan, E.M.

    1991-05-23

    The multi-segmented deformable mirror system is proposed as an element for a portion of a ballistic missile defense system. The size of the mirror required for this defense function requires that the mirror be developed in segments, and then these segments should be phased together to produce one continuous, large optic. The application of multivariable control system synthesis techniques to provide closed-loop wavefront control of the deformable mirror system is the problem discussed in this thesis. The method of H at infinity control system synthesis using loop-shaping techniques was used to develop a controller that meets a robust performance specification. The number and location of sensors was treated as a design variable, and the structured singular value (mu) was used to determine the performance robustness of the deformable mirror system. Decentralized control issues are also addressed through the use of necessary conditions in an effort to determine a suitable decentralized control structure with performance similar to that of the centralized controller.

  9. Crooker named Optical Society Fellow

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Crooker named Optical Society Fellow January 23, 2014 Scott Crooker of LANL's Condensed Matter and Magnet Science group is a 2014 Fellow of the Optical Society (OSA). The Society selected 71 new Fellows based on their overall impact on optics, as gauged through specific scientific, engineering and technological contributions, significant publications or patents related to optics, technical leadership in the field and service to OSA and the global optics community. Crooker's achievements The

  10. Transparent electrode for optical switch

    DOE Patents [OSTI]

    Goldhar, J.; Henesian, M.A.

    1984-10-19

    The invention relates generally to optical switches and techniques for applying a voltage to an electro-optical crystal, and more particularly, to transparent electodes for an optical switch. System architectures for very large inertial confinement fusion (ICF) lasers require active optical elements with apertures on the order of one meter. Large aperture optical switches are needed for isolation of stages, switch-out from regenerative amplifier cavities and protection from target retroreflections.

  11. Synthesis of optimal adsorptive carbon capture processes.

    SciTech Connect (OSTI)

    chang, Y.; Cozad, A.; Kim, H.; Lee, A.; Vouzis, P.; Konda, M.; Simon, A.; Sahinidis, N.; Miller, D.

    2011-01-01

    Solid sorbent carbon capture systems have the potential to require significantly lower regeneration energy compared to aqueous monoethanol amine (MEA) systems. To date, the majority of work on solid sorbents has focused on developing the sorbent materials themselves. In order to advance these technologies, it is necessary to design systems that can exploit the full potential and unique characteristics of these materials. The Department of Energy (DOE) recently initiated the Carbon Capture Simulation Initiative (CCSI) to develop computational tools to accelerate the commercialization of carbon capture technology. Solid sorbents is the first Industry Challenge Problem considered under this initiative. An early goal of the initiative is to demonstrate a superstructure-based framework to synthesize an optimal solid sorbent carbon capture process. For a given solid sorbent, there are a number of potential reactors and reactor configurations consisting of various fluidized bed reactors, moving bed reactors, and fixed bed reactors. Detailed process models for these reactors have been modeled using Aspen Custom Modeler; however, such models are computationally intractable for large optimization-based process synthesis. Thus, in order to facilitate the use of these models for process synthesis, we have developed an approach for generating simple algebraic surrogate models that can be used in an optimization formulation. This presentation will describe the superstructure formulation which uses these surrogate models to choose among various process alternatives and will describe the resulting optimal process configuration.

  12. Plasma Synthesis of Nanoparticles for Nanocomposite Energy Applications

    SciTech Connect (OSTI)

    Peter C. Kong; Alex W. Kawczak

    2008-09-01

    The nanocomposite energy applications for plasma reactor produced nanoparticles are reviewed. Nanoparticles are commonly defined as particles less than 100 nm in diameter. Due to this small size, nanoparticles have a high surface-to-volume ratio. This increases the surface energy compared to the bulk material. The high surface-to-volume ratio and size effects (quantum effects) give nanoparticles distinctive chemical, electronic, optical, magnetic and mechanical properties from those of the bulk material. Nanoparticles synthesis can be grouped into 3 broad approaches. The first one is wet phase synthesis (sol-gel processing), the second is mechanical attrition, and the third is gas-phase synthesis (aerosol). The properties of the final product may differ significantly depending on the fabrication route. Currently, there are no economical large-scale production processes for nanoparticles. This hinders the widespread applications of nanomaterials in products. The Idaho National Laboratory (INL) is engaging in research and development of advanced modular hybrid plasma reactors for low cost production of nanoparticles that is predicted to accelerate application research and enable the formation of technology innovation alliances that will result in the commercial production of nanocomposites for alternative energy production devices such as fuel cells, photovoltaics and electrochemical double layer capacitors.

  13. Low-Cost Fiber Optic Pressure Sensor

    DOE Patents [OSTI]

    Sheem, Sang K. (Pleasanton, CA)

    2004-05-18

    The size and cost of fabricating fiber optic pressure sensors is reduced by fabricating the membrane of the sensor in a non-planar shape. The design of the sensors may be made in such a way that the non-planar membrane becomes a part of an air-tight cavity, so as to make the membrane resilient due to the air-cushion effect of the air-tight cavity. Such non-planar membranes are easier to make and attach.

  14. Low-Cost Fiber Optic Pressure Sensor

    DOE Patents [OSTI]

    Sheem, Sang K. (Pleasanton, CA)

    2003-07-22

    The size and cost of fabricating fiber optic pressure sensors is reduced by fabricating the membrane of the sensor in a non-planar shape. The design of the sensors may be made in such a way that the non-planar membrane becomes a part of an air-tight cavity, so as to make the membrane resilient due to the air-cushion effect of the air-tight cavity. Such non-planar membranes are easier to make and attach.

  15. Optical high acidity sensor

    DOE Patents [OSTI]

    Jorgensen, Betty S. (Jemez Springs, NM); Nekimken, Howard L. (Los Alamos, NM); Carey, W. Patrick (Lynnwood, WA); O'Rourke, Patrick E. (Martinez, GA)

    1997-01-01

    An apparatus and method for determining acid concentrations in solutions having acid concentrations of from about 0.1 Molar to about 16 Molar is disclosed. The apparatus includes a chamber for interrogation of the sample solution, a fiber optic light source for passing light transversely through the chamber, a fiber optic collector for receiving the collimated light after transmission through the chamber, a coating of an acid resistant polymeric composition upon at least one fiber end or lens, the polymeric composition in contact with the sample solution within the chamber and having a detectable response to acid concentrations within the range of from about 0.1 Molar to about 16 Molar, a measurer for the response of the polymeric composition in contact with the sample solution, and, a comparer of the measured response to predetermined standards whereby the acid molarity of the sample solution within the chamber can be determined. Preferably, a first lens is attached to the end of the fiber optic light source, the first lens adapted to collimate light from the fiber optic light source, and a second lens is attached to the end of the fiber optic collector for focusing the collimated light after transmission through the chamber.

  16. Optical high acidity sensor

    DOE Patents [OSTI]

    Jorgensen, B.S.; Nekimken, H.L.; Carey, W.P.; O`Rourke, P.E.

    1997-07-22

    An apparatus and method for determining acid concentrations in solutions having acid concentrations of from about 0.1 Molar to about 16 Molar is disclosed. The apparatus includes a chamber for interrogation of the sample solution, a fiber optic light source for passing light transversely through the chamber, a fiber optic collector for receiving the collimated light after transmission through the chamber, a coating of an acid resistant polymeric composition upon at least one fiber end or lens, the polymeric composition in contact with the sample solution within the chamber and having a detectable response to acid concentrations within the range of from about 0.1 Molar to about 16 Molar, a measurer for the response of the polymeric composition in contact with the sample solution, and a comparer of the measured response to predetermined standards whereby the acid molarity of the sample solution within the chamber can be determined. Preferably, a first lens is attached to the end of the fiber optic light source, the first lens adapted to collimate light from the fiber optic light source, and a second lens is attached to the end of the fiber optic collector for focusing the collimated light after transmission through the chamber. 10 figs.

  17. Fiber optic hydrogen sensor

    DOE Patents [OSTI]

    Buchanan, Bruce R.; Prather, William S.

    1992-01-01

    An apparatus and method for detecting a chemical substance by exposing an optic fiber having a core and a cladding to the chemical substance so that the chemical substance can be adsorbed onto the surface of the cladding. The optic fiber is coiled inside a container having a pair of valves for controlling the entrance and exit of the substance. Light from a light source is received by one end of the optic fiber, preferably external to the container, and carried by the core of the fiber. Adsorbed substance changes the transmissivity of the fiber as measured by a spectrophotometer at the other end, also preferably external to the container. Hydrogen is detected by the absorption of infrared light carried by an optic fiber with a silica cladding. Since the adsorption is reversible, a sensor according to the present invention can be used repeatedly. Multiple positions in a process system can be monitored using a single container that can be connected to each location to be monitored so that a sample can be obtained for measurement, or, alternatively, containers can be placed near each position and the optic fibers carrying the partially-absorbed light can be multiplexed for rapid sequential reading by a single spectrophotometer.

  18. Fiber optic hydrogen sensor

    DOE Patents [OSTI]

    Buchanan, B.R.; Prather, W.S.

    1991-01-01

    Apparatus and method for detecting a chemical substance by exposing an optic fiber having a core and a cladding to the chemical substance so that the chemical substance can be adsorbed onto the surface of the cladding. The optic fiber is coiled inside a container having a pair of valves for controlling the entrance and exit of the substance. Light from a light source is received by one end of the optic fiber, preferably external to the container, and carried by the core of the fiber. Adsorbed substance changes the transmissivity of the fiber as measured by a spectrophotometer at the other end, also preferably external to the container. Hydrogen is detected by the absorption of infrared light carried by an optic fiber with a silica cladding. Since the adsorption is reversible, a sensor according to the present invention can be used repeatedly. Multiple positions in a process system can be monitored using a single container that can be connected to each location to be monitored so that a sample can be obtained for measurement, or, alternatively, containers can be placed near each position and the optic fibers carrying the partially-absorbed light can be multiplexed for rapid sequential reading, by a single spectrophotometer.

  19. Fiber optic hydrogen sensor

    DOE Patents [OSTI]

    Buchanan, B.R.; Prather, W.S.

    1992-10-06

    An apparatus and method are described for detecting a chemical substance by exposing an optic fiber having a core and a cladding to the chemical substance so that the chemical substance can be adsorbed onto the surface of the cladding. The optic fiber is coiled inside a container having a pair of valves for controlling the entrance and exit of the substance. Light from a light source is received by one end of the optic fiber, preferably external to the container, and carried by the core of the fiber. Adsorbed substance changes the transmissivity of the fiber as measured by a spectrophotometer at the other end, also preferably external to the container. Hydrogen is detected by the absorption of infrared light carried by an optic fiber with a silica cladding. Since the adsorption is reversible, a sensor according to the present invention can be used repeatedly. Multiple positions in a process system can be monitored using a single container that can be connected to each location to be monitored so that a sample can be obtained for measurement, or, alternatively, containers can be placed near each position and the optic fibers carrying the partially-absorbed light can be multiplexed for rapid sequential reading by a single spectrophotometer. 4 figs.

  20. Optical key system

    DOE Patents [OSTI]

    Hagans, Karla G. (Livermore, CA); Clough, Robert E. (Danville, CA)

    2000-01-01

    An optical key system comprises a battery-operated optical key and an isolated lock that derives both its operating power and unlock signals from the correct optical key. A light emitting diode or laser diode is included within the optical key and is connected to transmit a bit-serial password. The key user physically enters either the code-to-transmit directly, or an index to a pseudorandom number code, in the key. Such person identification numbers can be retained permanently, or ephemeral. When a send button is pressed, the key transmits a beam of light modulated with the password information. The modulated beam of light is received by a corresponding optical lock with a photovoltaic cell that produces enough power from the beam of light to operate a password-screen digital logic. In one application, an acceptable password allows a two watt power laser diode to pump ignition and timing information over a fiberoptic cable into a sealed engine compartment. The receipt of a good password allows the fuel pump, spark, and starter systems to each operate. Therefore, bypassing the lock mechanism as is now routine with automobile thieves is pointless because the engine is so thoroughly disabled.

  1. Micro-optics for high-efficiency optical performance and simplified tracking for concentrated photovoltaics (CPV).

    SciTech Connect (OSTI)

    Sinclair, Michael B.; Filatov, Anton; Lentine, Anthony L.; Sweatt, William C.; Nielson, Gregory N.; Okandan, Murat; Jared, Bradley Howell

    2010-02-01

    Micro-optical 5mm lenses in 50mm sub-arrays illuminate arrays of photovoltaic cells with 49X concentration. Fine tracking over {+-}10{sup o} FOV in sub-array allows coarse tracking by meter-sized solar panels. Plastic prototype demonstrated for 400nm < {lambda} < 1600 nm. We have designed a solar collector that will be composed of 50-mm-diameter sub-arrays, each containing {approx}100 5-mm plastic micro-lenses. Each micro-lens illuminates a stack of about four 0.7mm PV cells that collect sunlight from 400nm to 1600 nm with a theoretical efficiency approaching 50%. Each sub-array has internal solar tracking and alignment over a {+-}10{sup o} field, so a large array of sub-arrays only needs to coarsely track the sun. The refractive lenses in the design are thin so the optical transmission can be >90% and the optics will weigh very little. There are other optical properties incorporated in this design that help the photovoltaic cells to operate very efficiently. We are building a pre-prototype system now, and will describe our progress at the conference.

  2. Optical and magneto-optical studies of martensitic transformation in

    Office of Scientific and Technical Information (OSTI)

    Ni-Mn-Ga magnetic shape memory alloys (Journal Article) | SciTech Connect Optical and magneto-optical studies of martensitic transformation in Ni-Mn-Ga magnetic shape memory alloys Citation Details In-Document Search Title: Optical and magneto-optical studies of martensitic transformation in Ni-Mn-Ga magnetic shape memory alloys Optical and magneto-optical properties of single crystal of Ni{sub 50.1}Mn{sub 28.4}Ga{sub 21.5} magnetic shape memory alloy during its transformation from

  3. Interactive optical panel

    DOE Patents [OSTI]

    Veligdan, James T. (Manorville, NY)

    1995-10-03

    An interactive optical panel assembly 34 includes an optical panel 10 having a plurality of ribbon optical waveguides 12 stacked together with opposite ends thereof defining panel first and second faces 16, 18. A light source 20 provides an image beam 22 to the panel first face 16 for being channeled through the waveguides 12 and emitted from the panel second face 18 in the form of a viewable light image 24a. A remote device 38 produces a response beam 40 over a discrete selection area 36 of the panel second face 18 for being channeled through at least one of the waveguides 12 toward the panel first face 16. A light sensor 42,50 is disposed across a plurality of the waveguides 12 for detecting the response beam 40 therein for providing interactive capability.

  4. Interactive optical panel

    DOE Patents [OSTI]

    Veligdan, J.T.

    1995-10-03

    An interactive optical panel assembly includes an optical panel having a plurality of ribbon optical waveguides stacked together with opposite ends thereof defining panel first and second faces. A light source provides an image beam to the panel first face for being channeled through the waveguides and emitted from the panel second face in the form of a viewable light image. A remote device produces a response beam over a discrete selection area of the panel second face for being channeled through at least one of the waveguides toward the panel first face. A light sensor is disposed across a plurality of the waveguides for detecting the response beam therein for providing interactive capability. 10 figs.

  5. Optical voltage and current sensors used in a revenue metering system

    SciTech Connect (OSTI)

    Cease, T.W.; Driggans, J.G. ); Weikel, S.J. )

    1991-10-01

    This paper discusses the development of an optical voltage sensor as part of an all optic or Faraday effect was used to implement a Magneto-Optic Voltage Transducer (MOVT) to measure voltage by sensing the current flow through a capacitor connected from a 161 kV transmission line to ground. The current sensor was a Magneto-Optic Current Transducer (MOCT), developed previously. The unique design of the voltage sensors using the magneto-optic effects allows the implementation of that revenue metering system using all optical sensors. This method of measuring voltage was previously unproven. The components of the all optical sensor revenue metering system, the site installation, and the data acquisition system used to monitor the system are described. Decisions leading to the design of the MOVT are discussed.

  6. Benchmarking and Disclosure: State and Local Policy Design Guide and Sample Policy Language

    SciTech Connect (OSTI)

    Existing Commercial Buildings Working Group

    2012-05-16

    Provides sample policy language based on a synthesis of existing state and local policies, and discussion on key provisions, for the design of a commercial benchmarking and disclosure policy.

  7. Chemistry of the Colloidal Group II-VI Nanocrystal Synthesis

    SciTech Connect (OSTI)

    Liu, Haitao

    2007-05-17

    In the last two decades, the field of nanoscience andnanotechnology has witnessed tremendous advancement in the synthesis andapplication of group II-VI colloidal nanocrystals. The synthesis based onhigh temperature decomposition of organometallic precursors has becomeone of the most successful methods of making group II-VI colloidalnanocrystals. This method is first demonstrated by Bawendi and coworkersin 1993 to prepare cadmium chalcogenide colloidal quantum dots and laterextended by others to prepare other group II-VI quantum dots as well asanisotropic shaped colloidal nanocrystals, such as nanorod and tetrapod.This dissertation focuses on the chemistry of this type of nanocrystalsynthesis. The synthesis of group II-VI nanocrystals was studied bycharacterizing the molecular structures of the precursors and productsand following their time evolution in the synthesis. Based on theseresults, a mechanism was proposed to account for the 2 reaction betweenthe precursors that presumably produces monomer for the growth ofnanocrystals. Theoretical study based on density functional theorycalculations revealed the detailed free energy landscape of the precursordecomposition and monomerformation pathway. Based on the proposedreaction mechanism, a new synthetic method was designed that uses wateras a novel reagent to control the diameter and the aspect ratio of CdSeand CdS nanorods.

  8. Chemistry of the Colloidal Group II-VI Nanocrystal Synthesis

    SciTech Connect (OSTI)

    Liu, Haitao

    2007-05-17

    In the last two decades, the field of nanoscience andnanotechnology has witnessed tremendous advancement in the synthesis andapplication of group II-VI colloidal nanocrystals. The synthesis based onhigh temperature decomposition of organometallic precursors has becomeone of the most successful methods of making group II-VI colloidalnanocrystals. This methodis first demonstrated by Bawendi and coworkersin 1993 to prepare cadmium chalcogenide colloidal quantum dots and laterextended by others to prepare other group II-VI quantum dots as well asanisotropic shaped colloidal nanocrystals, such as nanorod and tetrapod.This dissertation focuses on the chemistry of this type of nanocrystalsynthesis. The synthesis of group II-VI nanocrystals was studied bycharacterizing the molecular structures of the precursors and productsand following their time evolution in the synthesis. Based on theseresults, a mechanism was proposed to account for the 2 reaction betweenthe precursors that presumably produces monomer for the growth ofnanocrystals. Theoretical study based on density functional theorycalculations revealed the detailed free energy landscape of the precursordecomposition and monomerformation pathway. Based on the proposedreaction mechanism, a new synthetic method was designed that uses wateras a novel reagent to control the diameter and the aspect ratio of CdSeand CdS nanorods.

  9. Absolute calibration of optical flats

    DOE Patents [OSTI]

    Sommargren, Gary E.

    2005-04-05

    The invention uses the phase shifting diffraction interferometer (PSDI) to provide a true point-by-point measurement of absolute flatness over the surface of optical flats. Beams exiting the fiber optics in a PSDI have perfect spherical wavefronts. The measurement beam is reflected from the optical flat and passed through an auxiliary optic to then be combined with the reference beam on a CCD. The combined beams include phase errors due to both the optic under test and the auxiliary optic. Standard phase extraction algorithms are used to calculate this combined phase error. The optical flat is then removed from the system and the measurement fiber is moved to recombine the two beams. The newly combined beams include only the phase errors due to the auxiliary optic. When the second phase measurement is subtracted from the first phase measurement, the absolute phase error of the optical flat is obtained.

  10. Gigashot Optical Laser Demonstrator

    SciTech Connect (OSTI)

    Deri, R. J.

    2015-10-13

    The Gigashot Optical Laser Demonstrator (GOLD) project has demonstrated a novel optical amplifier for high energy pulsed lasers operating at high repetition rates. The amplifier stores enough pump energy to support >10 J of laser output, and employs conduction cooling for thermal management to avoid the need for expensive and bulky high-pressure helium subsystems. A prototype amplifier was fabricated, pumped with diode light at 885 nm, and characterized. Experimental results show that the amplifier provides sufficient small-signal gain and sufficiently low wavefront and birefringence impairments to prove useful in laser systems, at repetition rates up to 60 Hz.

  11. Nonimaging optical illumination system

    DOE Patents [OSTI]

    Winston, R.; Ries, H.

    1998-10-06

    A nonimaging illumination optical device for producing a selected far field illuminance over an angular range. The optical device includes a light source a light reflecting surface, and a family of light edge rays defined along a reference line with the reflecting surface defined in terms of the reference lines a parametric function R(t) where t is a scalar parameter position and R(t)=k(t)+Du(t) where k(t) is a parameterization of the reference line, and D is a distance from a point on the reference line to the reflection surface along the desired edge ray through the point. 35 figs.

  12. Nonimaging optical illumination system

    DOE Patents [OSTI]

    Winston, R.; Ries, H.

    1996-12-17

    A nonimaging illumination optical device for producing a selected far field illuminance over an angular range. The optical device includes a light source, a light reflecting surface, and a family of light edge rays defined along a reference line with the reflecting surface defined in terms of the reference line as a parametric function R(t) where t is a scalar parameter position and R(t)=k(t)+Du(t) where k(t) is a parameterization of the reference line, and D is a distance from a point on the reference line to the reflection surface along the desired edge ray through the point. 35 figs.

  13. Solid state optical microscope

    DOE Patents [OSTI]

    Young, I.T.

    1983-08-09

    A solid state optical microscope wherein wide-field and high-resolution images of an object are produced at a rapid rate by utilizing conventional optics with a charge-coupled photodiode array. A galvanometer scanning mirror, for scanning in one of two orthogonal directions is provided, while the charge-coupled photodiode array scans in the other orthogonal direction. Illumination light from the object is incident upon the photodiodes, creating packets of electrons (signals) which are representative of the illuminated object. The signals are then processed, stored in a memory, and finally displayed as a video signal. 2 figs.

  14. Solid state optical microscope

    DOE Patents [OSTI]

    Young, Ian T. (Pleasanton, CA)

    1983-01-01

    A solid state optical microscope wherein wide-field and high-resolution images of an object are produced at a rapid rate by utilizing conventional optics with a charge-coupled photodiode array. A galvanometer scanning mirror, for scanning in one of two orthogonal directions is provided, while the charge-coupled photodiode array scans in the other orthogonal direction. Illumination light from the object is incident upon the photodiodes, creating packets of electrons (signals) which are representative of the illuminated object. The signals are then processed, stored in a memory, and finally displayed as a video signal.

  15. Full spectrum optical safeguard

    DOE Patents [OSTI]

    Ackerman, Mark R.

    2008-12-02

    An optical safeguard device with two linear variable Fabry-Perot filters aligned relative to a light source with at least one of the filters having a nonlinear dielectric constant material such that, when a light source produces a sufficiently high intensity light, the light alters the characteristics of the nonlinear dielectric constant material to reduce the intensity of light impacting a connected optical sensor. The device can be incorporated into an imaging system on a moving platform, such as an aircraft or satellite.

  16. Optical Characterization Laboratory (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2011-10-01

    This fact sheet describes the purpose, lab specifications, applications scenarios, and information on how to partner with NREL's Optical Characterization Laboratory at the Energy Systems Integration Facility. The Optical Characterization Laboratory at NREL's Energy Systems Integration Facility (ESIF) conducts optical characterization of large solar concentration devices. Concentration solar power (CSP) mirror panels and concentrating solar systems are tested with an emphasis is on measurement of parabolic trough mirror panels. The Optical Characterization Laboratory provides state-of-the-art characterization and testing capabilities for assessing the optical surface quality and optical performance for various CSP technologies including parabolic troughs, linear Fresnel, dishes, and heliostats.

  17. Optical loss due to diffraction by concentrator Fresnel lenses

    SciTech Connect (OSTI)

    Hornung, Thorsten Nitz, Peter

    2014-09-26

    Fresnel lenses are widely used in concentrating photovoltaic (CPV) systems as a primary optical element. They focus sunlight on small solar cells or on the entrance apertures of secondary optical elements. A Fresnel lens consists of several prism rings and diffraction by these prism rings is unavoidable. Some of the light that would reach a designated target area according to geometric optics will miss it due to diffraction. This diffraction loss may be of relevant magnitude for CPV applications. The results of published analytical calculations are evaluated, discussed, and compared to computer simulations and measurements.

  18. Implementation of Double-Waist Chicane Optics in SPEAR3

    SciTech Connect (OSTI)

    Corbett, J.; Cornacchia, M.; Dao, T.; Dell'Orco, D.; Rafael, F.; Harrington, D.; Hettel, R.; Huang, X.; Nosochkov, Y.; Rabedeau, T.; Rarback, H.; Ringwall, A.; Safranek, J.; Scott, B.; Sebek, J.; Tanabe, J.; Terebilo, A.; Wermelskirchen, C.; Widmeyer, M.; Yoon, Moohyun; /POSTECH

    2006-08-16

    The SPEAR3 accelerator upgrade opened up two 7.6m racetrack straights in the magnet lattice. In one of these straights, we recently added a magnetic chicane to separate two insertion device (ID) beam lines by 10mrad. A quadrupole triplet in the center creates a ''double focus'' optics with {beta}y = 1.6m at the middle of each ID, hence the term ''double-waist chicane''. The new optics also reduced {beta}y in the four matching straights adjacent to the racetrack straights to 2.5m. In this paper, we outline design features of the optics and physical implementation of the lattice.

  19. Combinatorial synthesis of inorganic or composite materials

    DOE Patents [OSTI]

    Goldwasser, Isy (Palo Alto, CA); Ross, Debra A. (Mountain Ranch, CA); Schultz, Peter G. (La Jolla, CA); Xiang, Xiao-Dong (Danville, CA); Briceno, Gabriel (Baldwin Park, CA); Sun, Xian-Dong (Fremont, CA); Wang, Kai-An (Cupertino, CA)

    2010-08-03

    Methods and apparatus for the preparation and use of a substrate having an array of diverse materials in predefined regions thereon. A substrate having an array of diverse materials thereon is generally prepared by delivering components of materials to predefined regions on a substrate, and simultaneously reacting the components to form at least two materials or, alternatively, allowing the components to interact to form at least two different materials. Materials which can be prepared using the methods and apparatus of the present invention include, for example, covalent network solids, ionic solids and molecular solids. More particularly, materials which can be prepared using the methods and apparatus of the present invention include, for example, inorganic materials, intermetallic materials, metal alloys, ceramic materials, organic materials, organometallic materials, nonbiological organic polymers, composite materials (e.g., inorganic composites, organic composites, or combinations thereof), etc. Once prepared, these materials can be screened for useful properties including, for example, electrical, thermal, mechanical, morphological, optical, magnetic, chemical, or other properties. Thus, the present invention provides methods for the parallel synthesis and analysis of novel materials having useful properties.

  20. Synthesis and screening combinatorial arrays of zeolites

    DOE Patents [OSTI]

    Schultz, Peter G.; Xiang, Xiaodong; Goldwasser, Isy

    2003-11-18

    Methods and apparatus for the preparation and use of a substrate having an array of diverse materials in predefined regions thereon. A substrate having an array of diverse materials thereon is generally prepared by delivering components of materials to predefined regions on a substrate, and simultaneously reacting the components to form at least two materials. Materials which can be prepared using the methods and apparatus of the present invention include, for example, covalent network solids, ionic solids and molecular solids. More particularly, materials which can be prepared using the methods and apparatus of the present invention include, for example, inorganic materials, intermetallic materials, metal alloys, ceramic materials, organic materials, organometallic materials, non-biological organic polymers, composite materials (e.g., inorganic composites, organic composites, or combinations thereof), etc. Once prepared, these materials can be screened for useful properties including, for example, electrical, thermal, mechanical, morphological, optical, magnetic, chemical, or other properties. Thus, the present invention provides methods for the parallel synthesis and analysis of novel materials having useful properties.

  1. NETL F 451.1/1-1, Categorical Exclusion Designation Form

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fincham Hydrate Modeling & Flow Loop Experiments for Water Continuous and Dispersed Sys. Design and machine fiber optic seismic sensors. Wind sensors in the Paulsson clean room....

  2. Status of the MEIC ion collider ring design (Conference) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    current-dominated super-conducting magnets. We describe complete ion collider optics including an independently-designed modular detector region. Authors: Morozov, Vasiliy...

  3. Split image optical display

    DOE Patents [OSTI]

    Veligdan, James T. (Manorville, NY)

    2007-05-29

    A video image is displayed from an optical panel by splitting the image into a plurality of image components, and then projecting the image components through corresponding portions of the panel to collectively form the image. Depth of the display is correspondingly reduced.

  4. Split image optical display

    DOE Patents [OSTI]

    Veligdan, James T.

    2005-05-31

    A video image is displayed from an optical panel by splitting the image into a plurality of image components, and then projecting the image components through corresponding portions of the panel to collectively form the image. Depth of the display is correspondingly reduced.

  5. High throughput optical scanner

    DOE Patents [OSTI]

    Basiji, David A. (Seattle, WA); van den Engh, Gerrit J. (Seattle, WA)

    2001-01-01

    A scanning apparatus is provided to obtain automated, rapid and sensitive scanning of substrate fluorescence, optical density or phosphorescence. The scanner uses a constant path length optical train, which enables the combination of a moving beam for high speed scanning with phase-sensitive detection for noise reduction, comprising a light source, a scanning mirror to receive light from the light source and sweep it across a steering mirror, a steering mirror to receive light from the scanning mirror and reflect it to the substrate, whereby it is swept across the substrate along a scan arc, and a photodetector to receive emitted or scattered light from the substrate, wherein the optical path length from the light source to the photodetector is substantially constant throughout the sweep across the substrate. The optical train can further include a waveguide or mirror to collect emitted or scattered light from the substrate and direct it to the photodetector. For phase-sensitive detection the light source is intensity modulated and the detector is connected to phase-sensitive detection electronics. A scanner using a substrate translator is also provided. For two dimensional imaging the substrate is translated in one dimension while the scanning mirror scans the beam in a second dimension. For a high throughput scanner, stacks of substrates are loaded onto a conveyor belt from a tray feeder.

  6. GridOPTICS Software System

    Energy Science and Technology Software Center (OSTI)

    2014-02-24

    GridOPTICS Software System (GOSS) is a middleware that facilitates creation of new, modular and flexible operational and planning platforms that can meet the challenges of the next generation power grid. GOSS enables Department of Energy, power system utilities, and vendors to build better tools faster. GOSS makes it possible to integrate Future Power Grid Initiative software products/prototypes into existing power grid software systems, including the PNNL PowerNet and EIOC environments. GOSS is designed to allowmore » power grid applications developed for different underlying software platforms installed in different utilities to communicate with ease. This can be done in compliance with existing security and data sharing policies between the utilities. GOSS not only supports one-to-one data transfer between applications, but also publisher/subscriber scheme. To support interoperability requirements of future EMS, GOSS is designed for CIM compliance. In addition to this, it supports authentication and authorization capabilities to protect the system from cyber threats. In summary, the contributions of the GOSS middleware are as follows: • A platform to support future EMS development. • A middleware that promotes interoperability between power grid applications. • A distributed architecture that separates data sources from power grid applications. • Support for data exchange with either one-to-one or publisher/subscriber interfaces. • An authentication and authorization scheme for limiting the access to data between utilities.« less

  7. Optical apparatus for forming correlation spectrometers and optical processors

    DOE Patents [OSTI]

    Butler, Michael A. (Albuquerque, NM); Ricco, Antonio J. (Albuquerque, NM); Sinclair, Michael B. (Albuquerque, NM); Senturia, Stephen D. (Brookline, MA)

    1999-01-01

    Optical apparatus for forming correlation spectrometers and optical processors. The optical apparatus comprises one or more diffractive optical elements formed on a substrate for receiving light from a source and processing the incident light. The optical apparatus includes an addressing element for alternately addressing each diffractive optical element thereof to produce for one unit of time a first correlation with the incident light, and to produce for a different unit of time a second correlation with the incident light that is different from the first correlation. In preferred embodiments of the invention, the optical apparatus is in the form of a correlation spectrometer; and in other embodiments, the apparatus is in the form of an optical processor. In some embodiments, the optical apparatus comprises a plurality of diffractive optical elements on a common substrate for forming first and second gratings that alternately intercept the incident light for different units of time. In other embodiments, the optical apparatus includes an electrically-programmable diffraction grating that may be alternately switched between a plurality of grating states thereof for processing the incident light. The optical apparatus may be formed, at least in part, by a micromachining process.

  8. Optical apparatus for forming correlation spectrometers and optical processors

    DOE Patents [OSTI]

    Butler, M.A.; Ricco, A.J.; Sinclair, M.B.; Senturia, S.D.

    1999-05-18

    Optical apparatus is disclosed for forming correlation spectrometers and optical processors. The optical apparatus comprises one or more diffractive optical elements formed on a substrate for receiving light from a source and processing the incident light. The optical apparatus includes an addressing element for alternately addressing each diffractive optical element thereof to produce for one unit of time a first correlation with the incident light, and to produce for a different unit of time a second correlation with the incident light that is different from the first correlation. In preferred embodiments of the invention, the optical apparatus is in the form of a correlation spectrometer; and in other embodiments, the apparatus is in the form of an optical processor. In some embodiments, the optical apparatus comprises a plurality of diffractive optical elements on a common substrate for forming first and second gratings that alternately intercept the incident light for different units of time. In other embodiments, the optical apparatus includes an electrically-programmable diffraction grating that may be alternately switched between a plurality of grating states thereof for processing the incident light. The optical apparatus may be formed, at least in part, by a micromachining process. 24 figs.

  9. Deactivation of methanol synthesis catalysts

    SciTech Connect (OSTI)

    Roberts, G.W.; Brown, D.M.; Hsiung, T.H.; Lewnard, J.J. (Air Products and Chemicals, Inc., Allentown, PA (United States))

    1993-08-01

    A novel methanol synthesis process, the liquid-phase methanol (LPMEOH) process, has been developed and scaled up to a nominal 380 kg/h (10 ton/day) pilot plant. The process is based on a gas-sparged slurry reactor instead of a conventional, fixed-bed reactor. The use of slurry reactors, which are essentially gradientless, greatly facilitated the interpretation and quantification of catalyst deactivation phenomena. With a poison-free, CO-rich feedstream, the rate of deactivation of the Cu/ZnO catalyst increased rapidly with temperature. At constant temperature, in the absence of poisons, the decline with time in the rate constant for methanol synthesis correlated with the loss of BET surface area. Iron carbonyl, nickel carbonyl, and carbonyl sulfide are severe and highly specific poisons for methanol-synthesis catalyst. There was a linear relationship between the catalyst activity loss and the concentration of metal or sulfur on the catalyst.

  10. Navy explosive ordnance disposal project: Optical ordnance system development. Final report

    SciTech Connect (OSTI)

    Merson, J.A.; Salas, F.J.; Helsel, F.M.

    1996-03-01

    An optical ordnance firing system consisting of a portable hand held solid state rod laser and an optically ignited detonator has been developed for use in explosive ordnance disposal (EOD) activities. Solid state rod laser systems designed to have an output of 150 mJ in a 500 microsecond pulse have been produced and evaluated. A laser ignited detonator containing no primary explosives has been designed and fabricated. The detonator has the same functional output as an electrically fired blasting cap. The optical ordnance firing system has demonstrated the ability to reliably detonate Comp C-4 through 1000 meters of optical fiber.

  11. Specification of optical components for a high average-power laser environment

    SciTech Connect (OSTI)

    Taylor, J.R.; Chow, R.; Rinmdahl, K.A.; Willis, J.B.; Wong, J.N.

    1997-06-25

    Optical component specifications for the high-average-power lasers and transport system used in the Atomic Vapor Laser Isotope Separation (AVLIS) plant must address demanding system performance requirements. The need for high performance optics has to be balanced against the practical desire to reduce the supply risks of cost and schedule. This is addressed in optical system design, careful planning with the optical industry, demonstration of plant quality parts, qualification of optical suppliers and processes, comprehensive procedures for evaluation and test, and a plan for corrective action.

  12. Synthesis metal nanoparticle

    DOE Patents [OSTI]

    Bunge, Scott D.; Boyle, Timothy J.

    2005-08-16

    A method for providing an anhydrous route for the synthesis of amine capped coinage-metal (copper, silver, and gold) nanoparticles (NPs) using the coinage-metal mesityl (mesityl=C.sub.6 H.sub.2 (CH.sub.3).sub.3 -2,4,6) derivatives. In this method, a solution of (Cu(C.sub.6 H.sub.2 (CH.sub.3).sub.3).sub.5, (Ag(C.sub.6 H.sub.2 (CH.sub.3).sub.3).sub.4, or (Au(C.sub.6 H.sub.2 (CH.sub.3).sub.3).sub.5 is dissolved in a coordinating solvent, such as a primary, secondary, or tertiary amine; primary, secondary, or tertiary phosphine, or alkyl thiol, to produce a mesityl precursor solution. This solution is subsequently injected into an organic solvent that is heated to a temperature greater than approximately 100.degree. C. After washing with an organic solvent, such as an alcohol (including methanol, ethanol, propanol, and higher molecular-weight alcohols), oxide free coinage NP are prepared that could be extracted with a solvent, such as an aromatic solvent (including, for example, toluene, benzene, and pyridine) or an alkane (including, for example, pentane, hexane, and heptane). Characterization by UV-Vis spectroscopy and transmission electron microscopy showed that the NPs were approximately 9.2.+-.2.3 nm in size for Cu.degree., (no surface oxide present), approximately 8.5.+-.1.1 nm Ag.degree. spheres, and approximately 8-80 nm for Au.degree..

  13. 4-ID-D optics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    4-ID-D Beamline Optics A schetch of the major optical components for beam line 4-ID-D are shown above. All these components located in the B-station upstream from the D...

  14. Optical fiber stripper positioning apparatus

    DOE Patents [OSTI]

    Fyfe, Richard W. (Las Vegas, NV); Sanchez, Jr., Amadeo (Las Vegas, NV)

    1990-01-01

    An optical fiber positioning apparatus for an optical fiber stripping device is disclosed which is capable of providing precise axial alignment between an optical fiber to be stripped of its outer jacket and the cutting blades of a stripping device. The apparatus includes a first bore having a width approximately equal to the diameter of an unstripped optical fiber and a counter bore axially aligned with the first bore and dimensioned to precisely receive a portion of the stripping device in axial alignment with notched cutting blades within the stripping device to thereby axially align the notched cutting blades of the stripping device with the axis of the optical fiber to permit the notched cutting blades to sever the jacket on the optical fiber without damaging the cladding on the optical fiber. In a preferred embodiment, the apparatus further includes a fiber stop which permits determination of the length of jacket to be removed from the optical fiber.

  15. Diagnostics Implemented on NIF - Optical

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Streaked Optical Pyrometer Shared LOS 90-315 DIM LLNL SOP measures the breakout time of an optically emitting shock. Robert M. Malone et al., "Combining a thermal-imaging...

  16. Magneto-optic current sensor

    DOE Patents [OSTI]

    Lanagan, Michael T.; Valsko-Vlasov, Vitalii K.; Fisher, Brandon L.; Welp, Ulrich

    2003-10-07

    An optical current transducer configured to sense current in the conductor is disclosed. The optical current transducer includes a light source and a polarizer that generates linearly polarized light received from a the light source. The light is communicated to a magneto-optic garnet that includes, among other elements, bismuth, iron and oxygen and is coupled to the conductor. The magneto-optic garnet is configured to rotate the polarization of the linearly polarized light received from the polarizer. The optical current transducer also includes an analyzer in optical communication with the magneto-optic garnet. The analyzer detects the rotation of the linearly polarized light caused by the magneto-optic garnet.

  17. Combustion synthesis method and products

    DOE Patents [OSTI]

    Holt, J.B.; Kelly, M.

    1993-03-30

    Disclosed is a method of producing dense refractory products, comprising: (a) obtaining a quantity of exoergic material in powder form capable of sustaining a combustion synthesis reaction; (b) removing absorbed water vapor therefrom; (c) cold-pressing said material into a formed body; (d) plasma spraying said formed body with a molten exoergic material to form a coat thereon; and (e) igniting said exoergic coated formed body under an inert gas atmosphere and pressure to produce self-sustained combustion synthesis. Also disclosed are products produced by the method.

  18. Combustion synthesis method and products

    DOE Patents [OSTI]

    Holt, J. Birch (San Jose, CA); Kelly, Michael (West Alexandria, OH)

    1993-01-01

    Disclosed is a method of producing dense refractory products, comprising: (a) obtaining a quantity of exoergic material in powder form capable of sustaining a combustion synthesis reaction; (b) removing absorbed water vapor therefrom; (c) cold-pressing said material into a formed body; (d) plasma spraying said formed body with a molten exoergic material to form a coat thereon; and (e) igniting said exoergic coated formed body under an inert gas atmosphere and pressure to produce self-sustained combustion synthesis. Also disclosed are products produced by the method.

  19. Design Considerations

    Office of Environmental Management (EM)

    TS NOT MEASUREMENT SENSITIVE DOE-HDBK-1132-99 April 1999 Reaffirmed 2014 DOE HANDBOOK DESIGN CONSIDERATIONS U.S. Department of Energy AREA EDCN Washington, D.C. 20585 DISTRIBUTION STATEMENT A. Approved for public release; distribution is unlimited. DOE-HDBK-1132-99 February 2014 Table of Changes Page Paragraph Changed To Throughout Reference citations. Revised all reference citations throughout the Order to reflect current versions of the documents. Throughout Formatting Made editorial and

  20. Crooker named Optical Society Fellow

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Crooker named Optical Society Fellow Crooker named Optical Society Fellow The society recognized Crooker for "the development and application of magneto-optical spectroscopies to colloidal quantum dots and to electron spin transport and noise in semiconductors." January 23, 2014 Scott Crooker Scott Crooker Crooker's research focuses on the development of ultra-sensitive optical techniques to measure the static and dynamic properties of electron spins and magnetization in semiconductor

  1. Optics learning through affordable kit

    SciTech Connect (OSTI)

    P, Anusha N E-mail: chitrashaji@gmail.com Shaji, Chitra E-mail: chitrashaji@gmail.com Sharan, Alok E-mail: chitrashaji@gmail.com

    2014-10-15

    An affordable kit which helps to understand some of the optical phenomena qualitatively and quantitatively is presented in this paper. It supplements optics taught in classes. The kit consists of equipments which are available in the market at nominal cost such as laser pointer, lenses, glass plates, razor blades, coins, ball bearing etc. Experiments which come under wave optics (interference and diffraction) and ray optics (reflection and refraction) are explained using this kit.

  2. Large core fiber optic cleaver

    DOE Patents [OSTI]

    Halpin, J.M.

    1996-03-26

    The present invention relates to a device and method for cleaving optical fibers which yields cleaved optical fiber ends possessing high damage threshold surfaces. The device can be used to cleave optical fibers with core diameters greater than 400 {micro}m. 30 figs.

  3. Large core fiber optic cleaver

    DOE Patents [OSTI]

    Halpin, John M. (Livermore, CA)

    1996-01-01

    The present invention relates to a device and method for cleaving optical fibers which yields cleaved optical fiber ends possessing high damage threshold surfaces. The device can be used to cleave optical fibers with core diameters greater than 400 .mu.m.

  4. Aerogel-clad optical fiber

    DOE Patents [OSTI]

    Sprehn, G.A.; Hrubesh, L.W.; Poco, J.F.; Sandler, P.H.

    1997-11-04

    An optical fiber is surrounded by an aerogel cladding. For a low density aerogel, the index of refraction of the aerogel is close to that of air, which provides a high numerical aperture to the optical fiber. Due to the high numerical aperture, the aerogel clad optical fiber has improved light collection efficiency. 4 figs.

  5. Aerogel-clad optical fiber

    DOE Patents [OSTI]

    Sprehn, Gregory A. (Livermore, CA); Hrubesh, Lawrence W. (Pleasanton, CA); Poco, John F. (Livermore, CA); Sandler, Pamela H. (San Marino, CA)

    1997-01-01

    An optical fiber is surrounded by an aerogel cladding. For a low density aerogel, the index of refraction of the aerogel is close to that of air, which provides a high numerical aperture to the optical fiber. Due to the high numerical aperture, the aerogel clad optical fiber has improved light collection efficiency.

  6. Nonimaging optical illumination system

    DOE Patents [OSTI]

    Winston, Roland (Chicago, IL); Ries, Harald (Villigen PSI, CH)

    1998-01-01

    A nonimaging illumination optical device for producing a selected far field illuminance over an angular range. The optical device includes a light source 102, a light reflecting surface 108, and a family of light edge rays defined along a reference line 104 with the reflecting surface 108 defined in terms of the reference line 104 as a parametric function R(t) where t is a scalar parameter position and R(t)=k(t)+Du(t) where k(t) is a parameterization of the reference line 104, and D is a distance from a point on the reference line 104 to the reflection surface 108 along the desired edge ray through the point.

  7. Nonimaging optical illumination system

    DOE Patents [OSTI]

    Winston, Roland (Chicago, IL); Ries, Harald (Villigen, CH)

    1996-01-01

    A nonimaging illumination optical device for producing a selected far field illuminance over an angular range. The optical device includes a light source 102, a light reflecting surface 108, and a family of light edge rays defined along a reference line 104 with the reflecting surface 108 defined in terms of the reference line 104 as a parametric function R(t) where t is a scalar parameter position and R(t)=k(t)+Du(t) where k(t) is a parameterization of the reference line 104, and D is a distance from a point on the reference line 104 to the reflection surface 108 along the desired edge ray through the point.

  8. Nonimaging optical illumination system

    DOE Patents [OSTI]

    Winston, Roland (Chicago, IL); Ries, Harald (Villigen PSI, CH)

    2000-01-01

    A nonimaging illumination optical device for producing a selected far field illuminance over an angular range. The optical device includes a light source 102, a light reflecting surface 108, and a family of light edge rays defined along a reference line 104 with the reflecting surface 108 defined in terms of the reference line 104 as a parametric function R(t) where t is a scalar parameter position and R(t)=k(t)+Du(t) where k(t) is a parameterization of the reference line 104, and D is a distance from a point on the reference line 104 to the reflection surface 108 along the desired edge ray through the point.

  9. Thin optical display panel

    DOE Patents [OSTI]

    Veligdan, James Thomas (Manorville, NY)

    1997-01-01

    An optical display includes a plurality of optical waveguides each including a cladding bound core for guiding internal display light between first and second opposite ends by total internal reflection. The waveguides are stacked together to define a collective display thickness. Each of the cores includes a heterogeneous portion defining a light scattering site disposed longitudinally between the first and second ends. Adjacent ones of the sites are longitudinally offset from each other for forming a longitudinal internal image display over the display thickness upon scattering of internal display light thereagainst for generating a display image. In a preferred embodiment, the waveguides and scattering sites are transparent for transmitting therethrough an external image in superposition with the display image formed by scattering the internal light off the scattering sites for defining a heads up display.

  10. Nonimaging Optical Illumination System

    DOE Patents [OSTI]

    Winston, Roland (Chicago, IL)

    1994-02-22

    A nonimaging illumination or concentration optical device. An optical device is provided having a light source, a light reflecting surface with an opening and positioned partially around the light source which is opposite the opening of the light reflecting surface. The light reflecting surface is disposed to produce a substantially uniform intensity output with the reflecting surface defined in terms of a radius vector R.sub.i in conjunction with an angle .phi..sub.i between R.sub.i, a direction from the source and an angle .theta..sub.i between direct forward illumination and the light ray reflected once from the reflecting surface. R.sub.i varies as the exponential of tan (.phi..sub.i -.theta..sub.i)/2 integrated over .phi..sub.i.

  11. Fiber optic moisture sensor

    DOE Patents [OSTI]

    Kirkham, R.R.

    1984-08-03

    A method and apparatus for sensing moisture changes by utilizing optical fiber technology. One embodiment uses a reflective target at the end of an optical fiber. The reflectance of the target varies with its moisture content and can be detected by a remote unit at the opposite end of the fiber. A second embodiment utilizes changes in light loss along the fiber length. This can be attributed to changes in reflectance of cladding material as a function of its moisture content. It can also be affected by holes or inserts interposed in the cladding material and/or fiber. Changing light levels can also be coupled from one fiber to another in an assembly of fibers as a function of varying moisture content in their overlapping lengths of cladding material.

  12. Black optic display

    DOE Patents [OSTI]

    Veligdan, James T. (Manorville, NY)

    1997-01-01

    An optical display includes a plurality of stacked optical waveguides having first and second opposite ends collectively defining an image input face and an image screen, respectively, with the screen being oblique to the input face. Each of the waveguides includes a transparent core bound by a cladding layer having a lower index of refraction for effecting internal reflection of image light transmitted into the input face to project an image on the screen, with each of the cladding layers including a cladding cap integrally joined thereto at the waveguide second ends. Each of the cores is beveled at the waveguide second end so that the cladding cap is viewable through the transparent core. Each of the cladding caps is black for absorbing external ambient light incident upon the screen for improving contrast of the image projected internally on the screen.

  13. Center for Inverse Design: Inverse Design Approach

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Inverse Design Approach This page describes the inverse materials design methodology used by the Center for Inverse Design, which integrates and combines the following: (1) theory,...

  14. Optically pulsed electron accelerator

    DOE Patents [OSTI]

    Fraser, J.S.; Sheffield, R.L.

    1985-05-20

    An optically pulsed electron accelerator can be used as an injector for a free electron laser and comprises a pulsed light source, such as a laser, for providing discrete incident light pulses. A photoemissive electron source emits electron bursts having the same duration as the incident light pulses when impinged upon by same. The photoemissive electron source is located on an inside wall of a radiofrequency-powered accelerator cell which accelerates the electron burst emitted by the photoemissive electron source.

  15. Optically pulsed electron accelerator

    DOE Patents [OSTI]

    Fraser, John S. (Los Alamos, NM); Sheffield, Richard L. (Los Alamos, NM)

    1987-01-01

    An optically pulsed electron accelerator can be used as an injector for a free electron laser and comprises a pulsed light source, such as a laser, for providing discrete incident light pulses. A photoemissive electron source emits electron bursts having the same duration as the incident light pulses when impinged upon by same. The photoemissive electron source is located on an inside wall of a radio frequency powered accelerator cell which accelerates the electron burst emitted by the photoemissive electron source.

  16. MicroSight Optics

    ScienceCinema (OSTI)

    None

    2013-05-28

    MicroSight is an innovative gunsight technology that allows a marksman's eye to focus on both the front gunsight and the intended target. The MicroSight improves both firearm safety and performance by imaging two objects at different focal distances. The MicroSight was developed at Idaho National Laboratory, and has been licensed by Apollo Optical Systems. You can learn more about INL's research programs at http://www.facebook.com/idahonationallaboratory.

  17. Triggered optical biosensor

    DOE Patents [OSTI]

    Song, Xuedong (Los Alamos, NM); Swanson, Basil I. (Los Alamos, NM)

    2001-10-02

    An optical biosensor is provided for the detection of a multivalent target biomolecule, the biosensor including a substrate having a bilayer membrane thereon, a recognition molecule situated at the surface, the recognition molecule capable of binding with the multivalent target biomolecule, the recognition molecule further characterized as including a fluorescence label thereon and as being movable at the surface and a device for measuring a fluorescence change in response to binding between the recognition molecule and the multivalent target biomolecule.

  18. Enhanced radiation resistant fiber optics

    DOE Patents [OSTI]

    Lyons, P.B.; Looney, L.D.

    1993-11-30

    A process for producing an optical fiber having enhanced radiation resistance is provided, the process including maintaining an optical fiber within a hydrogen-containing atmosphere for sufficient time to yield a hydrogen-permeated optical fiber having an elevated internal hydrogen concentration, and irradiating the hydrogen-permeated optical fiber at a time while the optical fiber has an elevated internal hydrogen concentration with a source of ionizing radiation. The radiation source is typically a cobalt-60 source and the fiber is pre-irradiated with a dose level up to about 1000 kilorads of radiation. 4 figures.

  19. Enhanced radiation resistant fiber optics

    DOE Patents [OSTI]

    Lyons, Peter B. (Los Alamos, NM); Looney, Larry D. (Los Alamos, NM)

    1993-01-01

    A process for producing an optical fiber having enhanced radiation resitance is provided, the process including maintaining an optical fiber within a hydrogen-containing atmosphere for sufficient time to yield a hydrogen-permeated optical fiber having an elevated internal hydrogen concentration, and irradiating the hydrogen-permeated optical fiber at a time while the optical fiber has an elevated internal hydrogen concentration with a source of ionizing radiation. The radiation source is typically a cobalt-60 source and the fiber is pre-irradiated with a dose level up to about 1000 kilorads of radiation.

  20. Synthesis of nanosized sodium titanates

    DOE Patents [OSTI]

    Hobbs, David T.; Taylor-Pashow, Kathryn M. L.; Elvington, Mark C.

    2015-09-29

    Methods directed to the synthesis and peroxide-modification of nanosized monosodium titanate are described. Methods include combination of reactants at a low concentration to a solution including a nonionic surfactant. The nanosized monosodium titanate can exhibit high selectivity for sorbing various metallic ions.

  1. Optical ionization detector

    DOE Patents [OSTI]

    Wuest, C.R.; Lowry, M.E.

    1994-03-29

    An optical ionization detector wherein a beam of light is split so that one arm passes through a fiber optics and the other arm passes through a gas-filled region, and uses interferometry to detect density changes in a gas when charged particles pass through it. The gas-filled region of the detector is subjected to a high electric field and as a charged particle traverses this gas region electrons are freed from the cathode and accelerated so as to generate an electron avalanche which is collected on the anode. The gas density is effected by the electron avalanche formation and if the index or refraction is proportional to the gas density the index will change accordingly. The detector uses this index change by modulating the one arm of the split light beam passing through the gas, with respect to the other arm that is passed through the fiber optic. Upon recombining of the beams, interference fringe changes as a function of the index change indicates the passage of charged particles through the gaseous medium. 3 figures.

  2. Optical fiber inspection system

    DOE Patents [OSTI]

    Moore, Francis W. (Richland, WA)

    1987-01-01

    A remote optical inspection system including an inspection head. The inspection head has a passageway through which pellets or other objects are passed. A window is provided along the passageway through which light is beamed against the objects being inspected. A plurality of lens assemblies are arranged about the window so that reflected light can be gathered and transferred to a plurality of coherent optical fiber light guides. The light guides transfer the light images to a television or other image transducer which converts the optical images into a representative electronic signal. The electronic signal can then be displayed on a signal viewer such as a television monitor for inspection by a person. A staging means can be used to support the objects for viewing through the window. Routing means can be used to direct inspected objects into appropriate exit passages for accepted or rejected objects. The inspected objects are advantageously fed in a singular manner to the staging means and routing means. The inspection system is advantageously used in an enclosure when toxic or hazardous materials are being inspected.

  3. Optical fiber inspection system

    DOE Patents [OSTI]

    Moore, F.W.

    1985-04-05

    A remote optical inspection system including an inspection head. The inspection head has a passageway through which pellets or other objects are passed. A window is provided along the passageway through which light is beamed against the objects being inspected. A plurality of lens assemblies are arranged about the window so that reflected light can be gathered and transferred to a plurality of coherent optical fiber light guides. The light guides transfer the light images to a television or other image transducer which converts the optical images into a representative electronic signal. The electronic signal can then be displayed on a signal viewer such as a television monitor for inspection by a person. A staging means can be used to support the objects for viewing through the window. Routing means can be used to direct inspected objects into appropriate exit passages for accepted or rejected objects. The inspected objects are advantageously fed in a singular manner to the staging means and routing means. The inspection system is advantageously used in an enclosure when toxic or hazardous materials are being inspected. 10 figs.

  4. Optical polarizer material

    DOE Patents [OSTI]

    Ebbers, C.A.

    1999-08-31

    Several crystals have been identified which can be grown using standard single crystals growth techniques and which have a high birefringence. The identified crystals include Li.sub.2 CO.sub.3, LiNaCO.sub.3, LiKCO.sub.3, LiRbCO.sub.3 and LiCsCO.sub.3. The condition of high birefringence leads to their application as optical polarizer materials. In one embodiment of the invention, the crystal has the chemical formula LiK.sub.(1-w-x-y) Na.sub.(1-w-x-z) Rb.sub.(1-w-y-z) Cs.sub.(1-x-y-z) CO.sub.3, where w+x+y+z=1. In another embodiment, the crystalline material may be selected from a an alkali metal carbonate and a double salt of alkali metal carbonates, where the polarizer has a Wollaston configuration, a Glan-Thompson configuration or a Glan-Taylor configuration. A method of making an LiNaCO.sub.3 optical polarizer is described. A similar method is shown for making an LiKCO.sub.3 optical polarizer.

  5. Optical polarizer material

    DOE Patents [OSTI]

    Ebbers, Christopher A. (Livermore, CA)

    1999-01-01

    Several crystals have been identified which can be grown using standard single crystals growth techniques and which have a high birefringence. The identified crystals include Li.sub.2 CO.sub.3, LiNaCO.sub.3, LiKCO.sub.3, LiRbCO.sub.3 and LiCsCO.sub.3. The condition of high birefringence leads to their application as optical polarizer materials. In one embodiment of the invention, the crystal has the chemical formula LiK.sub.(1-w-x-y) Na.sub.(1-w-x-z) Rb.sub.(1-w-y-z) Cs.sub.(1-x-y-z) CO.sub.3, where w+x+y+z=1. In another embodiment, the crystalline material may be selected from a an alkali metal carbonate and a double salt of alkali metal carbonates, where the polarizer has a Wollaston configuration, a Glan-Thompson configuration or a Glan-Taylor configuration. A method of making an LiNaCO.sub.3 optical polarizer is described. A similar method is shown for making an LiKCO.sub.3 optical polarizer.

  6. Optical ionization detector

    DOE Patents [OSTI]

    Wuest, Craig R. (Danville, CA); Lowry, Mark E. (Castro Valley, CA)

    1994-01-01

    An optical ionization detector wherein a beam of light is split so that one arm passes through a fiber optics and the other arm passes through a gas-filled region, and uses interferometry to detect density changes in a gas when charged particles pass through it. The gas-filled region of the detector is subjected to a high electric field and as a charged particle traverses this gas region electrons are freed from the cathode and accelerated so as to generate an electron avalanche which is collected on the anode. The gas density is effected by the electron avalanche formation and if the index or refraction is proportional to the gas density the index will change accordingly. The detector uses this index change by modulating the one arm of the split light beam passing through the gas, with respect to the other arm that is passed through the fiber optic. Upon recombining of the beams, interference fringe changes as a function of the index change indicates the passage of charged particles through the gaseous medium.

  7. CONCEPTUAL DESIGN REPORT

    SciTech Connect (OSTI)

    ROBINSON,K.

    2006-12-31

    Brookhaven National Laboratory has prepared a conceptual design for a world class user facility for scientific research using synchrotron radiation. This facility, called the ''National Synchrotron Light Source II'' (NSLS-II), will provide ultra high brightness and flux and exceptional beam stability. It will also provide advanced insertion devices, optics, detectors, and robotics, and a suite of scientific instruments designed to maximize the scientific output of the facility. Together these will enable the study of material properties and functions with a spatial resolution of {approx}1 nm, an energy resolution of {approx}0.1 meV, and the ultra high sensitivity required to perform spectroscopy on a single atom. The overall objective of the NSLS-II project is to deliver a research facility to advance fundamental science and have the capability to characterize and understand physical properties at the nanoscale, the processes by which nanomaterials can be manipulated and assembled into more complex hierarchical structures, and the new phenomena resulting from such assemblages. It will also be a user facility made available to researchers engaged in a broad spectrum of disciplines from universities, industries, and other laboratories.

  8. Electrochemical synthesis and characterization of zinc oxalate nanoparticles

    SciTech Connect (OSTI)

    Shamsipur, Mojtaba; Roushani, Mahmoud; Pourmortazavi, Seied Mahdi

    2013-03-15

    Highlights: ? Synthesis of zinc oxalate nanoparticles via electrolysis of a zinc plate anode in sodium oxalate solutions. ? Design of a Taguchi orthogonal array to identify the optimal experimental conditions. ? Controlling the size and shape of particles via applied voltage and oxalate concentration. ? Characterization of zinc oxalate nanoparticles by SEM, UVvis, FT-IR and TGDTA. - Abstract: A rapid, clean and simple electrodeposition method was designed for the synthesis of zinc oxalate nanoparticles. Zinc oxalate nanoparticles in different size and shapes were electrodeposited by electrolysis of a zinc plate anode in sodium oxalate aqueous solutions. It was found that the size and shape of the product could be tuned by electrolysis voltage, oxalate ion concentration, and stirring rate of electrolyte solution. A Taguchi orthogonal array design was designed to identify the optimal experimental conditions. The morphological characterization of the product was carried out by scanning electron microscopy. UVvis and FT-IR spectroscopies were also used to characterize the electrodeposited nanoparticles. The TGDTA studies of the nanoparticles indicated that the main thermal degradation occurs in two steps over a temperature range of 350430 C. In contrast to the existing methods, the present study describes a process which can be easily scaled up for the production of nano-sized zinc oxalate powder.

  9. Reducing the losses of optical metamaterials

    SciTech Connect (OSTI)

    Fang, Anan

    2010-12-15

    The field of metamaterials is driven by fascinating and far-reaching theoretical visions, such as perfect lenses, invisibility cloaking, and enhanced optical nonlinearities. However, losses have become the major obstacle towards real world applications in the optical regime. Reducing the losses of optical metamaterials becomes necessary and extremely important. In this thesis, two approaches are taken to reduce the losses. One is to construct an indefinite medium. Indefinite media are materials where not all the principal components of the permittivity and permeability tensors have the same sign. They do not need the resonances to achieve negative permittivity, {var_epsilon}. So, the losses can be comparatively small. To obtain indefinite media, three-dimensional (3D) optical metallic nanowire media with different structures are designed. They are numerically demonstrated that they are homogeneous effective indefinite anisotropic media by showing that their dispersion relations are hyperbolic. Negative group refraction and pseudo focusing are observed. Another approach is to incorporate gain into metamaterial nanostructures. The nonlinearity of gain is included by a generic four-level atomic model. A computational scheme is presented, which allows for a self-consistent treatment of a dispersive metallic photonic metamaterial coupled to a gain material incorporated into the nanostructure using the finite-difference time-domain (FDTD) method. The loss compensations with gain are done for various structures, from 2D simplified models to 3D realistic structures. Results show the losses of optical metamaterials can be effectively compensated by gain. The effective gain coefficient of the combined system can be much larger than the bulk gain counterpart, due to the strong local-field enhancement.

  10. Large optics inspection, tilting, and washing stand

    DOE Patents [OSTI]

    Ayers, Marion Jay; Ayers, Shannon Lee

    2012-10-09

    A large optics stand provides a risk free means of safely tilting large optics with ease and a method of safely tilting large optics with ease. The optics are supported in the horizontal position by pads. In the vertical plane the optics are supported by saddles that evenly distribute the optics weight over a large area.

  11. Large optics inspection, tilting, and washing stand

    DOE Patents [OSTI]

    Ayers, Marion Jay (Brentwood, CA); Ayers, Shannon Lee (Brentwood, CA)

    2010-08-24

    A large optics stand provides a risk free means of safely tilting large optics with ease and a method of safely tilting large optics with ease. The optics are supported in the horizontal position by pads. In the vertical plane the optics are supported by saddles that evenly distribute the optics weight over a large area.

  12. Advanced turbine systems program conceptual design and product development. Quarterly report, February 1995--April 1995

    SciTech Connect (OSTI)

    1995-06-01

    Research continued on the design of advanced turbine systems. This report describes the design and test of critical components such as blades, materials, cooling, combustion, and optical diagnostics probes.

  13. High density, optically corrected, micro-channel cooled, v-groove monolithic laser diode array

    DOE Patents [OSTI]

    Freitas, B.L.

    1998-10-27

    An optically corrected, micro-channel cooled, high density laser diode array achieves stacking pitches to 33 bars/cm by mounting laser diodes into V-shaped grooves. This design will deliver > 4kW/cm{sup 2} of directional pulsed laser power. This optically corrected, micro-channel cooled, high density laser is usable in all solid state laser systems which require efficient, directional, narrow bandwidth, high optical power density pump sources. 13 figs.

  14. High density, optically corrected, micro-channel cooled, v-groove monolithic laser diode array

    DOE Patents [OSTI]

    Freitas, Barry L.

    1998-01-01

    An optically corrected, micro-channel cooled, high density laser diode array achieves stacking pitches to 33 bars/cm by mounting laser diodes into V-shaped grooves. This design will deliver>4kW/cm2 of directional pulsed laser power. This optically corrected, micro-channel cooled, high density laser is usable in all solid state laser systems which require efficient, directional, narrow bandwidth, high optical power density pump sources.

  15. Thermal-stress modeling of an optical microphone at high temperature.

    Office of Scientific and Technical Information (OSTI)

    (Technical Report) | SciTech Connect Thermal-stress modeling of an optical microphone at high temperature. Citation Details In-Document Search Title: Thermal-stress modeling of an optical microphone at high temperature. To help determine the capability range of a MEMS optical microphone design in harsh conditions computer simulations were carried out. Thermal stress modeling was performed up to temperatures of 1000 C. Particular concern was over stress and strain profiles due to the

  16. Ion optics of RHIC electron beam ion source

    SciTech Connect (OSTI)

    Pikin, A.; Alessi, J.; Beebe, E.; Kponou, A.; Okamura, M.; Raparia, D.; Ritter, J.; Tan, Y.; Kuznetsov, G.

    2012-02-15

    RHIC electron beam ion source has been commissioned to operate as a versatile ion source on RHIC injection facility supplying ion species from He to Au for Booster. Except for light gaseous elements RHIC EBIS employs ion injection from several external primary ion sources. With electrostatic optics fast switching from one ion species to another can be done on a pulse to pulse mode. The design of an ion optical structure and the results of simulations for different ion species are presented. In the choice of optical elements special attention was paid to spherical aberrations for high-current space charge dominated ion beams. The combination of a gridded lens and a magnet lens in LEBT provides flexibility of optical control for a wide range of ion species to satisfy acceptance parameters of RFQ. The results of ion transmission measurements are presented.

  17. Experimental stress–strain analysis of tapered silica optical fibers with nanofiber waist

    SciTech Connect (OSTI)

    Holleis, S.; Hoinkes, T.; Wuttke, C.; Schneeweiss, P.; Rauschenbeutel, A.

    2014-04-21

    We experimentally determine tensile force–elongation diagrams of tapered optical fibers with a nanofiber waist. The tapered optical fibers are produced from standard silica optical fibers using a heat and pull process. Both, the force–elongation data and scanning electron microscope images of the rupture points indicate a brittle material. Despite the small waist radii of only a few hundred nanometers, our experimental data can be fully explained by a nonlinear stress–strain model that relies on material properties of macroscopic silica optical fibers. This is an important asset when it comes to designing miniaturized optical elements as one can rely on the well-founded material characteristics of standard optical fibers. Based on this understanding, we demonstrate a simple and non-destructive technique that allows us to determine the waist radius of the tapered optical fiber. We find excellent agreement with independent scanning electron microscope measurements of the waist radius.

  18. Pedestal substrate for coated optics

    DOE Patents [OSTI]

    Hale, Layton C.; Malsbury, Terry N.; Patterson, Steven R.

    2001-01-01

    A pedestal optical substrate that simultaneously provides high substrate dynamic stiffness, provides low surface figure sensitivity to mechanical mounting hardware inputs, and constrains surface figure changes caused by optical coatings to be primarily spherical in nature. The pedestal optical substrate includes a disk-like optic or substrate section having a top surface that is coated, a disk-like base section that provides location at which the substrate can be mounted, and a connecting cylindrical section between the base and optics or substrate sections. The connecting cylindrical section may be attached via three spaced legs or members. However, the pedestal optical substrate can be manufactured from a solid piece of material to form a monolith, thus avoiding joints between the sections, or the disk-like base can be formed separately and connected to the connecting section. By way of example, the pedestal optical substrate may be utilized in the fabrication of optics for an extreme ultraviolet (EUV) lithography imaging system, or in any optical system requiring coated optics and substrates with reduced sensitivity to mechanical mounts.

  19. All-optical switching in optically induced nonlinear waveguide couplers

    SciTech Connect (OSTI)

    Diebel, Falko Boguslawski, Martin; Rose, Patrick; Denz, Cornelia; Leykam, Daniel; Desyatnikov, Anton S.

    2014-06-30

    We experimentally demonstrate all-optical vortex switching in nonlinear coupled waveguide arrays optically induced in photorefractive media. Our technique is based on multiplexing of nondiffracting Bessel beams to induce various types of waveguide configurations. Using double- and quadruple-well potentials, we demonstrate precise control over the coupling strength between waveguides, the linear and nonlinear dynamics and symmetry-breaking bifurcations of guided light, and a power-controlled optical vortex switch.

  20. Fiber optic geophysical sensors

    DOE Patents [OSTI]

    Homuth, E.F.

    1991-03-19

    A fiber optic geophysical sensor is described in which laser light is passed through a sensor interferometer in contact with a geophysical event, and a reference interferometer not in contact with the geophysical event but in the same general environment as the sensor interferometer. In one embodiment, a single tunable laser provides the laser light. In another embodiment, separate tunable lasers are used for the sensor and reference interferometers. The invention can find such uses as monitoring for earthquakes, and the weighing of objects. 2 figures.

  1. Integrated optical XY coupler

    DOE Patents [OSTI]

    Vawter, G. Allen (Albuquerque, NM); Hadley, G. Ronald (Albuquerque, NM)

    1997-01-01

    An integrated optical XY coupler having two converging input waveguide arms meeting in a central section and a central output waveguide arm and two diverging flanking output waveguide arms emanating from the central section. In-phase light from the input arms constructively interfers in the central section to produce a single mode output in the central output arm with the rest of the light being collected in the flanking output arms. Crosstalk between devices on a substrate is minimized by this collection of the out-of-phase light by the flanking output arms of the XY coupler.

  2. Integrated optical XY coupler

    DOE Patents [OSTI]

    Vawter, G.A.; Hadley, G.R.

    1997-05-06

    An integrated optical XY coupler having two converging input waveguide arms meeting in a central section and a central output waveguide arm and two diverging flanking output waveguide arms emanating from the central section. In-phase light from the input arms constructively interferes in the central section to produce a single mode output in the central output arm with the rest of the light being collected in the flanking output arms. Crosstalk between devices on a substrate is minimized by this collection of the out-of-phase light by the flanking output arms of the XY coupler. 9 figs.

  3. Ferroelectric optical image comparator

    DOE Patents [OSTI]

    Butler, Michael A. (Albuquerque, NM); Land, Cecil E. (Albuquerque, NM); Martin, Stephen J. (Albuquerque, NM); Pfeifer, Kent B. (Los Lunas, NM)

    1993-01-01

    A ferroelectric optical image comparator has a lead lanthanum zirconate titanate thin-film device which is constructed with a semi-transparent or transparent conductive first electrode on one side of the thin film, a conductive metal second electrode on the other side of the thin film, and the second electrode is in contact with a nonconducting substrate. A photoinduced current in the device represents the dot product between a stored image and an image projected onto the first electrode. One-dimensional autocorrelations are performed by measuring this current while displacing the projected image.

  4. Nonimaging Optical Illumination System

    DOE Patents [OSTI]

    Winston, Roland (Chicago, IL)

    1994-08-02

    A nonimaging illumination optical device for producing selected intensity output over an angular range. The device includes a light reflecting surface (24, 26) around a light source (22) which is disposed opposite the aperture opening of the light reflecting surface (24, 26). The light source (22) has a characteristic dimension which is small relative to one or more of the distance from the light source (22) to the light reflecting surface (24, 26) or the angle subtended by the light source (22) at the light reflecting surface (24, 26).

  5. Optical humidity sensor

    DOE Patents [OSTI]

    Tarvin, J.A.

    1987-02-10

    An optical dielectric humidity sensor is disclosed which includes a dielectric mirror having multiple alternating layers of two porous water-adsorbent dielectric materials with differing indices of refraction carried by a translucent substrate. A narrow-band polarized light source is positioned to direct light energy onto the mirror, and detectors are positioned to receive light energy transmitted through and reflected by the mirror. A ratiometer indicates humidity in the atmosphere which surrounds the dielectric mirror as a function of a ratio of light energies incident on the detectors. 2 figs.

  6. Ferroelectric optical image comparator

    DOE Patents [OSTI]

    Butler, M.A.; Land, C.E.; Martin, S.J.; Pfeifer, K.B.

    1993-11-30

    A ferroelectric optical image comparator has a lead lanthanum zirconate titanate thin-film device which is constructed with a semi-transparent or transparent conductive first electrode on one side of the thin film, a conductive metal second electrode on the other side of the thin film, and the second electrode is in contact with a nonconducting substrate. A photoinduced current in the device represents the dot product between a stored image and an image projected onto the first electrode. One-dimensional autocorrelations are performed by measuring this current while displacing the projected image. 7 figures.

  7. Nonlinear optical coupler using a doped optical waveguide

    DOE Patents [OSTI]

    Pantell, Richard H. (Menlo Park, CA); Sadowski, Robert W. (Stanford, CA); Digonnet, Michel J. F. (Palo Alto, CA); Shaw, Herbert J. (Stanford, CA)

    1994-01-01

    An optical mode coupling apparatus includes an Erbium-doped optical waveguide in which an optical signal at a signal wavelength propagates in a first spatial propagation mode and a second spatial propagation mode of the waveguide. The optical signal propagating in the waveguide has a beat length. The coupling apparatus includes a pump source of perturbational light signal at a perturbational wavelength that propagates in the waveguide in the first spatial propagation mode. The perturbational signal has a sufficient intensity distribution in the waveguide that it causes a perturbation of the effective refractive index of the first spatial propagation mode of the waveguide in accordance with the optical Kerr effect. The perturbation of the effective refractive index of the first spatial propagation mode of the optical waveguide causes a change in the differential phase delay in the optical signal propagating in the first and second spatial propagation modes. The change in the differential phase delay is detected as a change in the intensity distribution between two lobes of the optical intensity distribution pattern of an output signal. The perturbational light signal can be selectively enabled and disabled to selectively change the intensity distribution in the two lobes of the optical intensity distribution pattern.

  8. Method for optical and mechanically coupling optical fibers

    DOE Patents [OSTI]

    Toeppen, J.S.

    1996-10-01

    A method and apparatus are disclosed for splicing optical fibers. A fluorescing solder glass frit having a melting point lower than the melting point of first and second optical fibers is prepared. The solder glass frit is then attached to the end of the first optical fiber and/or the end of the second optical fiber. The ends of the optical fibers are aligned and placed in close proximity to each other. The solder glass frit is then heated to a temperature which is lower than the melting temperature of the first and second optical fibers, but which is high enough to melt the solder glass frit. A force is applied to the first and second optical fibers pushing the ends of the fibers towards each other. As the solder glass flit becomes molten, the layer of molten solder glass is compressed into a thin layer between the first and second optical fibers. The thin compressed layer of molten solder glass is allowed to cool such that the first and second optical fibers are bonded to each other by the hardened layer of solder glass. 6 figs.

  9. Method for optical and mechanically coupling optical fibers

    DOE Patents [OSTI]

    Toeppen, John S. (Livermore, CA)

    1996-01-01

    A method and apparatus for splicing optical fibers. A fluorescing solder glass frit having a melting point lower than the melting point of first and second optical fibers is prepared. The solder glass frit is then attached to the end of the first optical fiber and/or the end of the second optical fiber. The ends of the optical fibers are aligned and placed in close proximity to each other. The solder glass frit is then heated to a temperature which is lower than the melting temperature of the first and second optical fibers, but which is high enough to melt the solder glass frit. A force is applied to the first and second optical fibers pushing the ends of the fibers towards each other. As the solder glass flit becomes molten, the layer of molten solder glass is compressed into a thin layer between the first and second optical fibers. The thin compressed layer of molten solder glass is allowed to cool such that the first and second optical fibers are bonded to each other by the hardened layer of solder glass.

  10. LSU EFRC - Center for Atomic Level Catalyst Design - Technical Conference

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2011 1 space control 2011 Technical Conference: Center for Atomic-level Catalyst Design Oct. 25-27, 2011 Note: Links available only on request to CALCD members. Contact Webmaster Presentations from the EFRC Technical Conference 2011 Mike Janik Mike Janik (Penn State): "Modeling and synthesis of rare earth oxides" Ulrike Diebold Ulrike Diebold (TU Vienna): "Designing Nanocatalysts via Atomically Controlled Metal Clusters and their Supports" Petra de Jongh Petra de Jongh

  11. High speed two-dimensional optical beam position detector

    SciTech Connect (OSTI)

    Rutten, Paul Edmond

    2011-07-15

    Disclosed is the design of a high speed two-dimensional optical beam position detector which outputs the X and Y displacement and total intensity linearly. The experimental detector measures the displacement from DC to 123 MHz and the intensity of an optical spot in a similar way as a conventional quadrant photodiode detector. The design uses four discrete photodiodes and simple dedicated optics for the position decomposition which enables higher spatial accuracy and faster electronic processing than conventional detectors. Measurements of the frequency response and the spatial sensitivity demonstrate high suitability for atomic force microscopy, scanning probe data storage applications, and wideband wavefront sensing. The operation principle allows for position measurements up to 20 GHz and more in bandwidth.

  12. Application of chiral critical clusters to assymetric synthesis

    DOE Patents [OSTI]

    Ferrieri, Richard A.

    2002-01-01

    Disclosed is a composition, a method of making and a method of using critical clusters for asymmetric synthesis using substantially optically-pure chiral solvent molecules in a supercritical fluid. The solvent molecules are capable of forming a multipoint hydrogen bonded solvate as they encage at least one solute molecule. The encaged solute molecule is capable of reacting to form an optically active chiral center. In another aspect, there is disclosed a method of directing the position of bonding between a solute molecule and a ligand involving encaging the solute molecule and the ligand with polar solvent molecules in a supercritical fluid under conditions of temperature and pressure sufficient to change electric charge distribution in the solute molecule. In yet another aspect, disclosed is a method of making pharmaceutical compounds involving encaging a solute molecule, which is capable of forming a chiral center, and a ligand with polar solvent molecules in a supercritical fluid under conditions of temperature and pressure sufficient to change electric charge distribution of the solute molecule. The solute molecule and ligand are then reacted whereby the ligand bonds to the solute molecule forming a chiral center. Also disclosed is a method for racemic resolution using critical clusters involving encaging racemic mixtures of solute molecules with substantially optically-pure chiral solvent molecules in a supercritical fluid under conditions of temperature and pressure sufficient to form critical clusters. The solvent molecules are capable of multipoint hydrogen bonding with the solute molecules. The encaged solute molecules are then nonenzymatically reacted to enhance the optical purity of the solute molecules.

  13. Optical fuel pin scanner. [Patent application; for reading identifications

    DOE Patents [OSTI]

    Kirchner, T.L.; Powers, H.G.

    1980-12-09

    This patent relates to an optical identification system developed for post-irradiation disassembly and analysis of fuel bundle assemblies. The apparatus is designed to be lowered onto a stationary fuel pin to read identification numbers or letters imprinted on the circumference of the top fuel pin and cap. (DLC)

  14. Environmentally responsive optical microstructured hybrid actuator assemblies and applications thereof

    DOE Patents [OSTI]

    Aizenberg, Joanna; Aizenberg, Michael; Kim, Philseok

    2016-01-05

    Microstructured hybrid actuator assemblies in which microactuators carrying designed surface properties to be revealed upon actuation are embedded in a layer of responsive materials. The microactuators in a microactuator array reversibly change their configuration in response to a change in the environment without requiring an external power source to switch their optical properties.

  15. Synthesis of Polycyclic Natural Products

    SciTech Connect (OSTI)

    Tuan Hoang Nguyen

    2003-05-31

    With the continuous advancements in molecular biology and modern medicine, organic synthesis has become vital to the support and extension of those discoveries. The isolations of new natural products allow for the understanding of their biological activities and therapeutic value. Organic synthesis is employed to aid in the determination of the relationship between structure and function of these natural products. The development of synthetic methodologies in the course of total syntheses is imperative for the expansion of this highly interdisciplinary field of science. In addition to the practical applications of total syntheses, the structural complexity of natural products represents a worthwhile challenge in itself. The pursuit of concise and efficient syntheses of complex molecules is both gratifying and enjoyable.

  16. Optical oxygen concentration monitor

    DOE Patents [OSTI]

    Kebabian, Paul (Acton, MA)

    1997-01-01

    A system for measuring and monitoring the concentration of oxygen uses as a light source an argon discharge lamp, which inherently emits light with a spectral line that is close to one of oxygen's A-band absorption lines. In a preferred embodiment, the argon line is split into sets of components of shorter and longer wavelengths by a magnetic field of approximately 2000 Gauss that is parallel to the light propagation from the lamp. The longer wavelength components are centered on an absorption line of oxygen and thus readily absorbed, and the shorter wavelength components are moved away from that line and minimally absorbed. A polarization modulator alternately selects the set of the longer wavelength, or upshifted, components or the set of the shorter wavelength, or downshifted, components and passes the selected set to an environment of interest. After transmission over a path through that environment, the transmitted optical flux of the argon line varies as a result of the differential absorption. The system then determines the concentration of oxygen in the environment based on the changes in the transmitted optical flux between the two sets of components. In alternative embodiments modulation is achieved by selectively reversing the polarity of the magnetic field or by selectively supplying the magnetic field to either the emitting plasma of the lamp or the environment of interest.

  17. Optical oxygen concentration monitor

    DOE Patents [OSTI]

    Kebabian, P.

    1997-07-22

    A system for measuring and monitoring the concentration of oxygen uses as a light source an argon discharge lamp, which inherently emits light with a spectral line that is close to one of oxygen`s A-band absorption lines. In a preferred embodiment, the argon line is split into sets of components of shorter and longer wavelengths by a magnetic field of approximately 2,000 Gauss that is parallel to the light propagation from the lamp. The longer wavelength components are centered on an absorption line of oxygen and thus readily absorbed, and the shorter wavelength components are moved away from that line and minimally absorbed. A polarization modulator alternately selects the set of the longer wavelength, or upshifted, components or the set of the shorter wavelength, or downshifted, components and passes the selected set to an environment of interest. After transmission over a path through that environment, the transmitted optical flux of the argon line varies as a result of the differential absorption. The system then determines the concentration of oxygen in the environment based on the changes in the transmitted optical flux between the two sets of components. In alternative embodiments modulation is achieved by selectively reversing the polarity of the magnetic field or by selectively supplying the magnetic field to either the emitting plasma of the lamp or the environment of interest. 4 figs.

  18. Optical transcutaneous bilirubin detector

    DOE Patents [OSTI]

    Kronberg, James W. (108 Independent Blvd., Aiken, SC 29801)

    1993-01-01

    A transcutaneous bilirubin detector comprising a source of light having spectral components absorbable and not absorbable by bilirubin, a handle assembly, electronic circuitry and a fiber optic bundle connecting the assembly to the light source and circuitry. Inside the assembly is a prism that receives the light from one end of the fiber optic bundle and directs it onto the skin and directs the reflected light back into the bundle. The other end of the bundle is trifucated, with one end going to the light source and the other two ends going to circuitry that determines how much light of each kind has been reflected. A relatively greater amount absorbed by the skin from the portion of the spectrum absorbable by bilirubin may indicate the presence of the illness. Preferably, two measurements are made, one on the kneecap and one on the forehead, and compared to determine the presence of bilirubin. To reduce the impact of light absorption by hemoglobin in the blood carried by the skin, pressure is applied with a plunger and spring in the handle assembly, the pressure limited by points of a button slidably carried in the assembly that are perceived by touch when the pressure applied is sufficient.

  19. Tapered capillary optics

    DOE Patents [OSTI]

    Hirsch, Gregory (365 Talbot Ave., Pacifica, CA 94044)

    1998-01-01

    A metal or glass wire is etched with great precision into a very narrowly tapering cone which has the shape of the desired final capillary-optics bore. By controlling the rate of removal of the wire from an etchant bath, a carefully controlled taper is produced. A sensor measures the diameter of the wire as it leaves the surface of the etchant. This signal is used for feedback control of the withdrawal speed. The etched wire undergoes a treatment to produce an extremely low surface-roughness. The etched and smoothed wire is coated with the material of choice for optimizing the reflectivity of the radiation being focused. This could be a vacuum evaporation, sputtering, CVD or aqueous chemical process. The coated wire is either electroplated, built up with electroless plating, or encapsulated in a polymer cylinder such as epoxy to increase the diameter of the wire for easier handling and greater robustness. During this process, the wire is vertically oriented and tensioned to assure that the wire is absolutely straight. The coated and electroformed wire is bonded to a flat, rigid substrate and is then periodically segmented by cutting or etching a series of narrow slits or grooves into the wire. The wire is vertically oriented and tensioned during the bonding process to assure that it is straight. The original wire material is then chemically etched away through the slits or otherwise withdrawn to leave the hollow internal bore of the final tapered-capillary optical element.

  20. Bundled monocapillary optics

    DOE Patents [OSTI]

    Hirsch, Gregory (1277 Linds Mar Center, Suite 128, Pacifica, CA 94044)

    2002-01-01

    A plurality of glass or metal wires are precisely etched to form the desired shape of the individual channels of the final polycapillary optic. This shape is created by carefully controlling the withdrawal speed of a group of wires from an etchant bath. The etched wires undergo a subsequent operation to create an extremely smooth surface. This surface is coated with a layer of material which is selected to maximize the reflectivity of the radiation being used. This reflective surface may be a single layer of material, or a multilayer coating for optimizing the reflectivity in a narrower wavelength interval. The collection of individual wires is assembled into a close-packed multi-wire bundle, and the wires are bonded together in a manner which preserves the close-pack configuration, irrespective of the local wire diameter. The initial wires are then removed by either a chemical etching procedure or mechanical force. In the case of chemical etching, the bundle is generally segmented by cutting a series of etching slots. Prior to removing the wire, the capillary array is typically bonded to a support substrate. The result of the process is a bundle of precisely oriented radiation-reflecting hollow channels. The capillary optic is used for efficiently collecting and redirecting the radiation from a source of radiation which could be the anode of an x-ray tube, a plasma source, the fluorescent radiation from an electron microprobe, a synchrotron radiation source, a reactor or spallation source of neutrons, or some other source.

  1. Optical transcutaneous bilirubin detector

    DOE Patents [OSTI]

    Kronberg, J.W.

    1991-03-04

    This invention consists of a transcutaneous bilirubin detector comprising a source of light having spectral components absorbable and not absorbable by bilirubin, a handle assembly, electronic circuitry and a fiber optic bundle connecting the assembly to the light source and circuitry. Inside the assembly is a prism that receives the light from one end of the fiber optic bundle and directs it onto the skin and directs the reflected light back into the bundle. The other end of the bundle is trifucated, with one end going to the light source and the other two ends going to circuitry that determines how much light of each kind has been reflected. A relatively greater amount absorbed by the skin from the portion of the spectrum absorbable by bilirubin may indicate the presence of the illness. Preferably, two measurements are made, one on the kneecap and one on the forehead, and compared to determine the presence of bilirubin. To reduce the impact of light absorption by hemoglobin in the blood carried by the skin, pressure is applied with a plunger and spring in the handle assembly, the pressure limited by points of a button slidably carried in the assembly that are perceived by touch when the pressure applied is sufficient.

  2. System for testing optical fibers

    DOE Patents [OSTI]

    Golob, John E. [Olathe, KS; Looney, Larry D. [Los Alamos, NM; Lyons, Peter B. [Los Alamos, NM; Nelson, Melvin A. [Santa Barbara, CA; Davies, Terence J. [Santa Barbara, CA

    1980-07-15

    A system for measuring a combination of optical transmission properties of fiber optic waveguides. A polarized light pulse probe is injected into one end of the optical fiber. Reflections from discontinuities within the fiber are unpolarized whereas reflections of the probe pulse incident to its injection remain polarized. The polarized reflections are prevented from reaching a light detector whereas reflections from the discontinuities reaches the detector.

  3. Spatial optic multiplexer/diplexer

    DOE Patents [OSTI]

    Tremblay, Paul L. (Idaho Falls, ID)

    1991-01-01

    An apparatus for simultaneous transmission of optic signals having different wavelengths over a single optic fiber. Multiple light signals are transmitted through optic fibers that are formed into a circumference surrounding a central core fiber. The multiple light signals are directed by a lens into a single receiving fiber where the light combines and is then focused into the central core fiber which transmits the light to a wavelength discriminating receiver assembly.

  4. Materials Synthesis and Integrated Devices

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    11 Materials Synthesis and Integrated Devices We conduct basic and applied research in areas related to applied energy programs and a variety of problems relevant to the weapons program. Contact Us Group Leader Andrew Dattelbaum Email Deputy Group Leader George Goff Email Deputy Group Leader Jeff Willis Email Group Office (505) 665-9330 Dipen Sinha and team win Richard P. Feynman Innovation Prize Los Alamos researcher Dipen Sinha and team were recognized with the Richard P. Feynman Innovation

  5. Optically stimulated differential impedance spectroscopy

    DOE Patents [OSTI]

    Maxey, Lonnie C; Parks, II, James E; Lewis, Sr., Samuel A; Partridge, Jr., William P

    2014-02-18

    Methods and apparatuses for evaluating a material are described. Embodiments typically involve use of an impedance measurement sensor to measure the impedance of a sample of the material under at least two different states of illumination. The states of illumination may include (a) substantially no optical stimulation, (b) substantial optical stimulation, (c) optical stimulation at a first wavelength of light, (d) optical stimulation at a second wavelength of light, (e) a first level of light intensity, and (f) a second level of light intensity. Typically a difference in impedance between the impedance of the sample at the two states of illumination is measured to determine a characteristic of the material.

  6. Fiber optic diffraction grating maker

    DOE Patents [OSTI]

    Deason, V.A.; Ward, M.B.

    1991-05-21

    A compact and portable diffraction grating maker is comprised of a laser beam, optical and fiber optics devices coupling the beam to one or more evanescent beam splitters, and collimating lenses or mirrors directing the split beam at an appropriate photosensitive material. The collimating optics, the output ends of the fiber optic coupler and the photosensitive plate holder are all mounted on an articulated framework so that the angle of intersection of the beams can be altered at will without disturbing the spatial filter, collimation or beam quality, and assuring that the beams will always intersect at the position of the plate. 4 figures.

  7. Fiber optic diffraction grating maker

    DOE Patents [OSTI]

    Deason, Vance A. (Idaho Falls, ID); Ward, Michael B. (Idaho Falls, ID)

    1991-01-01

    A compact and portable diffraction grating maker comprised of a laser beam, optical and fiber optics devices coupling the beam to one or more evanescent beam splitters, and collimating lenses or mirrors directing the split beam at an appropriate photosensitive material. The collimating optics, the output ends of the fiber optic coupler and the photosensitive plate holder are all mounted on an articulated framework so that the angle of intersection of the beams can be altered at will without disturbing the spatial filter, collimation or beam quality, and assuring that the beams will always intersect at the position of the plate.

  8. Sandia Energy - Sensors & Optical Diagnostics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    & Optical Diagnostics Home CRF Permalink Gallery CRF Article Chosen by The Journal of Chemical Physics to Commemorate 80th Anniversary CRF, Energy, Facilities, News, News & Events,...

  9. The Synthesis and Characterization of Substituted Phosphates...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Phosphates and Layered Manganese Oxides The Synthesis and Characterization of Substituted Phosphates and Layered Manganese Oxides 2011 DOE Hydrogen and Fuel Cells Program, and...

  10. Nuclear Engineering Science Laboratory Synthesis program accepting...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nuclear Engineering Science Laboratory Synthesis program accepting applications for spring, summer 2016 Opportunity provides students with research experience at Oak Ridge National...

  11. Synthesis and structural characterization of ferrous trioctahedral...

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Search Results Journal Article: Synthesis and structural characterization of ferrous trioctahedral smectites: Implications for clay mineral genesis and ...

  12. Synthesis and tribological behavior of silicon oxycarbonitride...

    Office of Scientific and Technical Information (OSTI)

    Country of Publication: United States Language: English Subject: 36 MATERIALS SCIENCE; SILICON COMPOUNDS; SYNTHESIS; THIN FILMS; OXYCARBIDES; NITRIDES; TRIBOLOGY Word Cloud More ...

  13. Novel Solar Energy Conversion Materials by Design of Mn(II) Oxides

    SciTech Connect (OSTI)

    Lany, S.; Peng, H.; Ndione, P.; Zakutayev, A.; Ginley, D. S.

    2013-01-01

    Solar energy conversion materials need to fulfill simultaneously a number of requirements in regard of their band-structure, optical properties, carrier transport, and doping. Despite their desirable chemical properties, e.g., for photo-electrocatalysis, transition-metal oxides usually do not have desirable semiconducting properties. Instead, oxides with open cation d-shells are typically Mott or charge-transfer insulators with notoriously poor transport properties, resulting from large effective electron/hole masses or from carrier self-trapping. Based on the notion that the electronic structure features (p-d interaction) supporting the p-type conductivity in d10 oxides like Cu2O and CuAlO2 occurs in a similar fashion also in the d5 (high-spin) oxides, we recently studied theoretically the band-structure and transport properties of the prototypical binary d5 oxides MnO and Fe2O3 [PRB 85, 201202(R)]. We found that MnO tends to self-trap holes by forming Mn+III, whereas Fe2O3 self-traps electrons by forming Fe+II. However, the self-trapping of holes is suppressed by when Mn is tetrahedrally coordinated, which suggests specific routes to design novel solar conversion materials by considering ternary Mn(II) oxides or oxide alloys. We are presenting theory, synthesis, and initial characterization for these novel energy materials.

  14. CMI Unique Facility: Bulk Combinatoric Materials Synthesis Facility...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Bulk Combinatoric Materials Synthesis Facility The Bulk Combinatoric Materials Synthesis Facility is one of half a dozen unique facilities developed by the Critical Materials...

  15. Synthesis of Phenylene Vinylene Macrocycles through Acyclic Diene...

    Office of Scientific and Technical Information (OSTI)

    Synthesis of Phenylene Vinylene Macrocycles through Acyclic Diene Metathesis Macrocyclization and Their Aggregation Behavior Citation Details In-Document Search Title: Synthesis of ...

  16. Synthesis of very small diameter silica nanofibers using sound...

    Office of Scientific and Technical Information (OSTI)

    Synthesis of very small diameter silica nanofibers using sound waves Citation Details In-Document Search Title: Synthesis of very small diameter silica nanofibers using sound waves...

  17. Synthesis, Structure, and Properties of Alternating and Random...

    Office of Scientific and Technical Information (OSTI)

    Synthesis, Structure, and Properties of Alternating and Random Poly(styrene-b-butadiene) Multiblock Copolymers Citation Details In-Document Search Title: Synthesis, Structure, and...

  18. Templated photocatalytic synthesis of well-defined Pt hollow...

    Office of Scientific and Technical Information (OSTI)

    Templated photocatalytic synthesis of well-defined Pt hollow nanostructures with enhanced ... Title: Templated photocatalytic synthesis of well-defined Pt hollow nanostructures with ...

  19. Theoretical Synthesis of Mixed Materials for CO2 Capture Applications...

    Office of Scientific and Technical Information (OSTI)

    Theoretical Synthesis of Mixed Materials for CO2 Capture Applications Citation Details In-Document Search Title: Theoretical Synthesis of Mixed Materials for CO2 Capture...

  20. Synthesis and Rheological Characterization of Poly (vinyl acetate...

    Office of Scientific and Technical Information (OSTI)

    Synthesis and Rheological Characterization of Poly (vinyl acetate-b-vinyl alcohol-b-vinyl acetate) Triblock Copolymer Hydrogels Citation Details In-Document Search Title: Synthesis ...

  1. Synthesis and Engineering Materials Properties of Fluid Phase...

    Office of Scientific and Technical Information (OSTI)

    Synthesis and Engineering Materials Properties of Fluid Phase Chemical Hydrogen Storage Materials for Automotive Applications Citation Details In-Document Search Title: Synthesis ...

  2. On the Synthesis and Structure of Resorcinol-Formaldehyde Polymeric...

    Office of Scientific and Technical Information (OSTI)

    Synthesis and Structure of Resorcinol-Formaldehyde Polymeric Networks - Precursors to 3D Carbon Macroassemblies Citation Details In-Document Search Title: On the Synthesis and...

  3. Optical cavity furnace for semiconductor wafer processing

    DOE Patents [OSTI]

    Sopori, Bhushan L.

    2014-08-05

    An optical cavity furnace 10 having multiple optical energy sources 12 associated with an optical cavity 18 of the furnace. The multiple optical energy sources 12 may be lamps or other devices suitable for producing an appropriate level of optical energy. The optical cavity furnace 10 may also include one or more reflectors 14 and one or more walls 16 associated with the optical energy sources 12 such that the reflectors 14 and walls 16 define the optical cavity 18. The walls 16 may have any desired configuration or shape to enhance operation of the furnace as an optical cavity 18. The optical energy sources 12 may be positioned at any location with respect to the reflectors 14 and walls defining the optical cavity. The optical cavity furnace 10 may further include a semiconductor wafer transport system 22 for transporting one or more semiconductor wafers 20 through the optical cavity.

  4. Multilayer optical dielectric coating

    DOE Patents [OSTI]

    Emmett, John L. (Pleasanton, CA)

    1990-01-01

    A highly damage resistant, multilayer, optical reflective coating includes alternating layers of doped and undoped dielectric material. The doping levels are low enough that there are no distinct interfaces between the doped and undoped layers so that the coating has properties nearly identical to the undoped material. The coating is fabricated at high temperature with plasma-assisted chemical vapor deposition techniques to eliminate defects, reduce energy-absorption sites, and maintain proper chemical stoichiometry. A number of differently-doped layer pairs, each layer having a thickness equal to one-quarter of a predetermined wavelength in the material are combined to form a narrowband reflective coating for a predetermined wavelength. Broadband reflectors are made by using a number of narrowband reflectors, each covering a portion of the broadband.

  5. Integrated optical sensor

    DOE Patents [OSTI]

    Watkins, A.D.; Smartt, H.B.; Taylor, P.L.

    1994-01-04

    An integrated optical sensor for arc welding having multifunction feedback control is described. The sensor, comprising generally a CCD camera and diode laser, is positioned behind the arc torch for measuring weld pool position and width, standoff distance, and post-weld centerline cooling rate. Computer process information from this sensor is passed to a controlling computer for use in feedback control loops to aid in the control of the welding process. Weld pool position and width are used in a feedback loop, by the weld controller, to track the weld pool relative to the weld joint. Sensor standoff distance is used in a feedback loop to control the contact tip to base metal distance during the welding process. Cooling rate information is used to determine the final metallurgical state of the weld bead and heat affected zone, thereby controlling post-weld mechanical properties. 6 figures.

  6. Integrated optical sensor

    DOE Patents [OSTI]

    Watkins, Arthur D. (Idaho Falls, ID); Smartt, Herschel B. (Idaho Falls, ID); Taylor, Paul L. (Idaho Falls, ID)

    1994-01-01

    An integrated optical sensor for arc welding having multifunction feedback control. The sensor, comprising generally a CCD camera and diode laser, is positioned behind the arc torch for measuring weld pool position and width, standoff distance, and post-weld centerline cooling rate. Computer process information from this sensor is passed to a controlling computer for use in feedback control loops to aid in the control of the welding process. Weld pool position and width are used in a feedback loop, by the weld controller, to track the weld pool relative to the weld joint. Sensor standoff distance is used in a feedback loop to control the contact tip to base metal distance during the welding process. Cooling rate information is used to determine the final metallurgical state of the weld bead and heat affected zone, thereby controlling post-weld mechanical properties.

  7. Fluorescent optical position sensor

    DOE Patents [OSTI]

    Weiss, Jonathan D.

    2005-11-15

    A fluorescent optical position sensor and method of operation. A small excitation source side-pumps a localized region of fluorescence at an unknown position along a fluorescent waveguide. As the fluorescent light travels down the waveguide, the intensity of fluorescent light decreases due to absorption. By measuring with one (or two) photodetectors the attenuated intensity of fluorescent light emitted from one (or both) ends of the waveguide, the position of the excitation source relative to the waveguide can be determined by comparing the measured light intensity to a calibrated response curve or mathematical model. Alternatively, excitation light can be pumped into an end of the waveguide, which generates an exponentially-decaying continuous source of fluorescent light along the length of the waveguide. The position of a photodetector oriented to view the side of the waveguide can be uniquely determined by measuring the intensity of the fluorescent light emitted radially at that location.

  8. Monolithic fiber optic sensor assembly

    DOE Patents [OSTI]

    Sanders, Scott

    2015-02-10

    A remote sensor element for spectrographic measurements employs a monolithic assembly of one or two fiber optics to two optical elements separated by a supporting structure to allow the flow of gases or particulates therebetween. In a preferred embodiment, the sensor element components are fused ceramic to resist high temperatures and failure from large temperature changes.

  9. Semiconductor-based optical refrigerator

    DOE Patents [OSTI]

    Epstein, Richard I. (Santa Fe, NM); Edwards, Bradley C. (Nekoosa, WI); Sheik-Bahae, Mansoor (Albuquerque, NM)

    2002-01-01

    Optical refrigerators using semiconductor material as a cooling medium, with layers of material in close proximity to the cooling medium that carries away heat from the cooling material and preventing radiation trapping. In addition to the use of semiconducting material, the invention can be used with ytterbium-doped glass optical refrigerators.

  10. Bi-stable optical actuator

    DOE Patents [OSTI]

    Holdener, Fred R. (Tracy, CA); Boyd, Robert D. (Livermore, CA)

    2000-01-01

    The present invention is a bi-stable optical actuator device that is depowered in both stable positions. A bearing is used to transfer motion and smoothly transition from one state to another. The optical actuator device may be maintained in a stable position either by gravity or a restraining device.

  11. Resonator design for a visible wavelength free-electron laser (*)

    SciTech Connect (OSTI)

    Bhowmik, A.; Lordi, N. . Rocketdyne Div.); Ben-Zvi, I.; Gallardo, J. )

    1990-01-01

    Design requirements for a visible wavelength free-electron laser being developed at the Accelerator Test Facility at Brookhaven National Laboratory are presented along with predictions of laser performance from 3-D numerical simulations. The design and construction of the optical resonator, its alignment and control systems are also described. 15 refs., 8 figs., 4 tabs.

  12. Miniature mechanical transfer optical coupler

    DOE Patents [OSTI]

    Abel, Philip (Overland Park, KS); Watterson, Carl (Kansas City, MO)

    2011-02-15

    A miniature mechanical transfer (MT) optical coupler ("MMTOC") for optically connecting a first plurality of optical fibers with at least one other plurality of optical fibers. The MMTOC may comprise a beam splitting element, a plurality of collimating lenses, and a plurality of alignment elements. The MMTOC may optically couple a first plurality of fibers disposed in a plurality of ferrules of a first MT connector with a second plurality of fibers disposed in a plurality of ferrules of a second MT connector and a third plurality of fibers disposed in a plurality of ferrules of a third MT connector. The beam splitting element may allow a portion of each beam of light from the first plurality of fibers to pass through to the second plurality of fibers and simultaneously reflect another portion of each beam of light from the first plurality of fibers to the third plurality of fibers.

  13. Optical set-reset latch

    DOE Patents [OSTI]

    Skogen, Erik J.

    2013-01-29

    An optical set-reset (SR) latch is formed from a first electroabsorption modulator (EAM), a second EAM and a waveguide photodetector (PD) which are arranged in an optical and electrical feedback loop which controls the transmission of light through the first EAM to latch the first EAM in a light-transmissive state in response to a Set light input. A second waveguide PD controls the transmission of light through the second EAM and is used to switch the first EAM to a light-absorptive state in response to a Reset light input provided to the second waveguide PD. The optical SR latch, which may be formed on a III-V compound semiconductor substrate (e.g. an InP or a GaAs substrate) as a photonic integrated circuit (PIC), stores a bit of optical information and has an optical output for the logic state of that bit of information.

  14. Investigation of fluorine-doped tin oxide based optically transparent E-shaped patch antenna for terahertz communications

    SciTech Connect (OSTI)

    Anand, S. E-mail: darak.mayur@gmail.com Darak, Mayur Sudesh E-mail: darak.mayur@gmail.com Kumar, D. Sriram E-mail: darak.mayur@gmail.com

    2014-10-15

    In this paper, a fluorine-doped tin oxide based optically transparent E-shaped patch antenna is designed and its radiation performance is analyzed in the 705 804 GHz band. As optically transparent antennas can be mounted on optical display, they facilitate the reduction of overall system size. The proposed antenna design is simulated using electromagnetic solver - Ansys HFSS and its characteristics such as impedance bandwidth, directivity, radiation efficiency and gain are observed. Results show that the fluorine-doped tin oxide based optically transparent patch antenna overcomes the conventional patch antenna limitations and thus the same can be used for solar cell antenna used in satellite systems.

  15. Method and apparatus for synthesis of arrays of DNA probes

    DOE Patents [OSTI]

    Cerrina, Francesco (Madison, WI); Sussman, Michael R. (Madison, WI); Blattner, Frederick R. (Madison, WI); Singh-Gasson, Sangeet (Madison, WI); Green, Roland (Madison, WI)

    2002-04-23

    The synthesis of arrays of DNA probes sequences, polypeptides, and the like is carried out using a patterning process on an active surface of a substrate. An image is projected onto the active surface of the substrate utilizing an image former that includes a light source that provides light to a micromirror device comprising an array of electronically addressable micromirrors, each of which can be selectively tilted between one of at least two positions. Projection optics receives the light reflected from the micromirrors along an optical axis and precisely images the micromirrors onto the active surface of the substrate, which may be used to activate the surface of the substrate. The first level of bases may then be applied to the substrate, followed by development steps, and subsequent exposure of the substrate utilizing a different pattern of micromirrors, with further repeats until the elements of a two dimensional array on the substrate surface have an appropriate base bound thereto. The micromirror array can be controlled in conjunction with a DNA synthesizer supplying appropriate reagents to a flow cell containing the active substrate to control the sequencing of images presented by the micromirror array in coordination of the reagents provided to the substrate.

  16. Catalytic Synthesis of Oxygenates: Mechanisms, Catalysts and Controlling Characteristics

    SciTech Connect (OSTI)

    Kamil Klier; Richard G. Herman

    2005-11-30

    This research focused on catalytic synthesis of unsymmetrical ethers as a part of a larger program involving oxygenated products in general, including alcohols, ethers, esters, carboxylic acids and their derivatives that link together environmentally compliant fuels, monomers, and high-value chemicals. The catalysts studied here were solid acids possessing strong Br???????¸nsted acid functionalities. The design of these catalysts involved anchoring the acid groups onto inorganic oxides, e.g. surface-grafted acid groups on zirconia, and a new class of mesoporous solid acids, i.e. propylsulfonic acid-derivatized SBA-15. The former catalysts consisted of a high surface concentration of sulfate groups on stable zirconia catalysts. The latter catalyst consists of high surface area, large pore propylsulfonic acid-derivatized silicas, specifically SBA-15. In both cases, the catalyst design and synthesis yielded high concentrations of acid sites in close proximity to one another. These materials have been well-characterization in terms of physical and chemical properties, as well as in regard to surface and bulk characteristics. Both types of catalysts were shown to exhibit high catalytic performance with respect to both activity and selectivity for the bifunctional coupling of alcohols to form ethers, which proceeds via an efficient SN2 reaction mechanism on the proximal acid sites. This commonality of the dual-site SN2 reaction mechanism over acid catalysts provides for maximum reaction rates and control of selectivity by reaction conditions, i.e. pressure, temperature, and reactant concentrations. This research provides the scientific groundwork for synthesis of ethers for energy applications. The synthesized environmentally acceptable ethers, in part derived from natural gas via alcohol intermediates, exhibit high cetane properties, e.g. methylisobutylether with cetane No. of 53 and dimethylether with cetane No. of 55-60, or high octane properties, e.g. diisopropylether with blending octane No. of 105, and can replace aromatics in liquid fuels.

  17. Ship Effect Measurements With Fiber Optic Neutron Detector

    SciTech Connect (OSTI)

    King, Kenneth L.; Dean, Rashe A.; Akbar, Shahzad; Kouzes, Richard T.; Woodring, Mitchell L.

    2010-08-10

    The main objectives of this research project was to assemble, operate, test and characterize an innovatively designed scintillating fiber optic neutron radiation detector manufactured by Innovative American Technology with possible application to the Department of Homeland Security screening for potential radiological and nuclear threats at US borders (Kouzes 2004). One goal of this project was to make measurements of the neutron ship effect for several materials. The Virginia State University DOE FaST/NSF summer student-faculty team made measurements with the fiber optic radiation detector at PNNL above ground to characterize the ship effect from cosmic neutrons, and underground to characterize the muon contribution.

  18. The role of lanthanides in optical materials

    SciTech Connect (OSTI)

    Weber, M.J.

    1995-05-01

    A survey is presented of the use of the lanthanides as chemical components in transmitting optical materials and as activators in materials for luminescent, electro-optic, magneto-optic, and various photosensitive applications.

  19. Conceptual Safety Design RM

    Office of Environmental Management (EM)

    Area Identifier Safety Design Strategy SD Hazards Identification & Control Selection HI Conceptual Safety Design Report CR Risks to Project Safety Decisions SR Safety Design...

  20. Reduction of damage initiation density in fused silica optics via UV laser conditioning

    DOE Patents [OSTI]

    Peterson, John E.; Maricle, Stephen M.; Brusasco, Raymond M.; Penetrante, Bernardino M.

    2004-03-16

    The present invention provides a method for reducing the density of sites on the surface of fused silica optics that are prone to the initiation of laser-induced damage, resulting in optics which have far fewer catastrophic defects and are better capable of resisting optical deterioration upon exposure for a long period of time to a high-power laser beam having a wavelength of about 360 nm or less. The initiation of laser-induced damage is reduced by conditioning the optic at low fluences below levels that normally lead to catastrophic growth of damage. When the optic is then irradiated at its high fluence design limit, the concentration of catastrophic damage sites that form on the surface of the optic is greatly reduced.

  1. Accelerating Science Driven System Design With RAMP

    SciTech Connect (OSTI)

    Wawrzynek, John

    2015-05-01

    Researchers from UC Berkeley, in collaboration with the Lawrence Berkeley National Lab, are engaged in developing an Infrastructure for Synthesis with Integrated Simulation (ISIS). The ISIS Project was a cooperative effort for “application-driven hardware design” that engages application scientists in the early parts of the hardware design process for future generation supercomputing systems. This project served to foster development of computing systems that are better tuned to the application requirements of demanding scientific applications and result in more cost-effective and efficient HPC system designs. In order to overcome long conventional design-cycle times, we leveraged reconfigurable devices to aid in the design of high-efficiency systems, including conventional multi- and many-core systems. The resulting system emulation/prototyping environment, in conjunction with the appropriate intermediate abstractions, provided both a convenient user programming experience and retained flexibility, and thus efficiency, of a reconfigurable platform. We initially targeted the Berkeley RAMP system (Research Accelerator for Multiple Processors) as that hardware emulation environment to facilitate and ultimately accelerate the iterative process of science-driven system design. Our goal was to develop and demonstrate a design methodology for domain-optimized computer system architectures. The tangible outcome is a methodology and tools for rapid prototyping and design-space exploration, leading to highly optimized and efficient HPC systems.

  2. Polyhedral integrated and free space optical interconnection

    DOE Patents [OSTI]

    Erteza, Ireena A. (913 McDuffie Cir., NE., Albuquerque, NM 87110)

    1998-01-01

    An optical communication system uses holographic optical elements to provide guided wave and non-guided communication, resulting in high bandwidth, high connectivity optical communications. Holograms within holographic optical elements route optical signals between elements and between nodes connected to elements. Angular and wavelength multiplexing allow the elements to provide high connectivity. The combination of guided and non-guided communication allows compact polyhedral system geometries. Guided wave communications provided by multiplexed substrate-mode holographic optical elements eases system alignment.

  3. Polyhedral integrated and free space optical interconnection

    DOE Patents [OSTI]

    Erteza, I.A.

    1998-01-06

    An optical communication system uses holographic optical elements to provide guided wave and non-guided communication, resulting in high bandwidth, high connectivity optical communications. Holograms within holographic optical elements route optical signals between elements and between nodes connected to elements. Angular and wavelength multiplexing allow the elements to provide high connectivity. The combination of guided and non-guided communication allows compact polyhedral system geometries. Guided wave communications provided by multiplexed substrate-mode holographic optical elements eases system alignment. 7 figs.

  4. Synthesis of Methyl Methacrylate from Coal-Derived Syngas

    SciTech Connect (OSTI)

    Gerald N. Choi; James J. Spivey; Jospeh R. Zoeller; Makarand R. Gogate; Richard D. Colberg; Samuel S. Tam

    1998-04-17

    Research Triangle Institute (RTI), Eastman Chemical Company, and Bechtel collectively are developing a novel three-step process for the synthesis of methyl methacrylate (MMA) from coal-derived syngas that consists of the steps of synthesis of a propionate, its condensation with formaldehyde to form methacrylic acid (MAA), and esterification of MAA with methanol to produce MMA. RTI has completed the research on the three-step methanol-based route to MMA. Under an extension to the original contract, RTI is currently evaluating a new DME-based process for MMA. The key research need for DME route is to develop catalysts for DME partial oxidation reactions and DME condensation reactions. Over the last month, RTI has finalized the design of a fixed-bed microreactor system for DME partial oxidation reactions. RTI incorporated some design changes to the feed blending system, so as to be able to blend varying proportions of DME and oxygen. RTI has also examined the flammability limits of DME-air mixtures. Since the lower flammability limit of DME in air is 3.6 volume percent, RTI will use a nominal feed composition of 1.6 percent in air, which is less than half the lower explosion limit for DME-air mixtures. This nominal feed composition is thus considered operationally safe, for DME partial oxidation reactions. RTI is also currently developing an analytical system for DME partial oxidation reaction system.

  5. Power inverter with optical isolation

    DOE Patents [OSTI]

    Duncan, Paul G.; Schroeder, John Alan

    2005-12-06

    An optically isolated power electronic power conversion circuit that includes an input electrical power source, a heat pipe, a power electronic switch or plurality of interconnected power electronic switches, a mechanism for connecting the switch to the input power source, a mechanism for connecting comprising an interconnecting cable and/or bus bar or plurality of interconnecting cables and/or input bus bars, an optically isolated drive circuit connected to the switch, a heat sink assembly upon which the power electronic switch or switches is mounted, an output load, a mechanism for connecting the switch to the output load, the mechanism for connecting including an interconnecting cable and/or bus bar or plurality of interconnecting cables and/or output bus bars, at least one a fiber optic temperature sensor mounted on the heat sink assembly, at least one fiber optic current sensor mounted on the load interconnection cable and/or output bus bar, at least one fiber optic voltage sensor mounted on the load interconnection cable and/or output bus bar, at least one fiber optic current sensor mounted on the input power interconnection cable and/or input bus bar, and at least one fiber optic voltage sensor mounted on the input power interconnection cable and/or input bus bar.

  6. Optically Directed Assembly of Continuous Mesoscale Filaments...

    Office of Scientific and Technical Information (OSTI)

    Optically Directed Assembly of Continuous Mesoscale Filaments Title: Optically Directed Assembly of Continuous Mesoscale Filaments Authors: Bahns, J. T. ; Sankaranarayanan, S. K. ...

  7. Metasurface optical antireflection coating (Journal Article)...

    Office of Scientific and Technical Information (OSTI)

    at the boundary of two different media is one of the fundamental phenomena in optics, and reduction of reflection is highly desirable in many optical systems....

  8. Chameleon Optics Inc | Open Energy Information

    Open Energy Info (EERE)

    Chameleon Optics Inc Jump to: navigation, search Name: Chameleon Optics Inc Place: Philadelphia, Pennsylvania Zip: PA 19104 Sector: Wind energy Product: Has invented low-cost,...

  9. Metamaterial flexible sheets could transform optics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Metamaterial flexible sheets could transform optics Metamaterial flexible sheets could transform optics Advances would boost security screening systems, infrared thermal cameras,...

  10. Funding Opportunity Announcement: CSP: Concentrating Optics for...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CSP: Concentrating Optics for Lower Levelized Energy Costs (COLLECTS) Funding Opportunity Announcement: CSP: Concentrating Optics for Lower Levelized Energy Costs (COLLECTS)...

  11. Metasurface optical antireflection coating (Journal Article)...

    Office of Scientific and Technical Information (OSTI)

    Search Title: Metasurface optical antireflection coating Light reflection at the boundary of two different media is one of the fundamental phenomena in optics, and...

  12. Design of the First Infrared Beamline at the Siam Photon Laboratory

    SciTech Connect (OSTI)

    Pattanasiriwisawa, W.; Songsiriritthigul, P.; Dumas, P.

    2010-06-23

    This report presents the optical design and optical simulations for the first infrared beamline at the Siam Photon Laboratory. The beamline collects the edge radiation and bending magnet radiation, producing from the BM4 bending magnet of the 1.2 GeV storage ring of the Siam Photon Source. The optical design is optimized for the far- to mid-infrared spectral range (4000-100 cm{sup -1}) for microspectroscopic applications. The optical performance has been examined by computer simulations.

  13. Fiber optic temperature sensor

    SciTech Connect (OSTI)

    Rabold, D.

    1995-12-01

    Our fiber optic temperature measurement sensor and system is a major improvement over methods currently in use in most industrial processes, and it delivers all of the attributes required simplicity, accuracy, and cost efficiency-to help improve all of these processes. Because temperature is a basic physical attribute of nearly every industrial and commercial process, our system can eventually result in significant improvements in nearly every industrial and commercial process. Many finished goods, and the materials that go into them, are critically dependent on the temperature. The better the temperature measurement, the better quality the goods will be and the more economically they can be produced. The production and transmission of energy requires the monitoring of temperature in motors, circuit breakers, power generating plants, and transmission line equipment. The more reliable and robust the methods for measuring these temperature, the more available, stable, and affordable the supply of energy will become. The world is increasingly realizing the threats to health and safety of toxic or otherwise undesirable by products of the industrial economy in the environment. Cleanup of such contamination often depends on techniques that require the constant monitoring of temperature in extremely hazardous environments, which can damage most conventional temperature sensors and which are dangerous for operating personnel. Our system makes such monitoring safer and more economical.

  14. Polyplanar optical display electronics

    SciTech Connect (OSTI)

    DeSanto, L.; Biscardi, C.

    1997-07-01

    The Polyplanar Optical Display (POD) is a unique display screen which can be used with any projection source. The prototype ten inch display is two inches thick and has a matte black face which allows for high contrast images. The prototype being developed is a form, fit and functional replacement display for the B-52 aircraft which uses a monochrome ten-inch display. In order to achieve a long lifetime, the new display uses a 100 milliwatt green solid-state laser (10,000 hr. life) at 532 nm as its light source. To produce real-time video, the laser light is being modulated by a Digital Light Processing (DLP{trademark}) chip manufactured by Texas Instruments. In order to use the solid-state laser as the light source and also fit within the constraints of the B-52 display, the Digital Micromirror Device (DMD{trademark}) circuit board is removed from the Texas Instruments DLP light engine assembly. Due to the compact architecture of the projection system within the display chassis, the DMD{trademark} chip is operated remotely from the Texas Instruments circuit board. The authors discuss the operation of the DMD{trademark} divorced from the light engine and the interfacing of the DMD{trademark} board with various video formats (CVBS, Y/C or S-video and RGB) including the format specific to the B-52 aircraft. A brief discussion of the electronics required to drive the laser is also presented.

  15. Optical and magneto-optical studies of martensitic transformation...

    Office of Scientific and Technical Information (OSTI)

    Magneto-optical spectroscopy and spectroscopic ellipsometry were measured in the sample temperature range from 297 to 373 K and photon energy range from 1.2 to 6.5 eV. ...

  16. Optic probe for semiconductor characterization

    DOE Patents [OSTI]

    Sopori, Bhushan L. (Denver, CO); Hambarian, Artak (Yerevan, AM)

    2008-09-02

    Described herein is an optical probe (120) for use in characterizing surface defects in wafers, such as semiconductor wafers. The optical probe (120) detects laser light reflected from the surface (124) of the wafer (106) within various ranges of angles. Characteristics of defects in the surface (124) of the wafer (106) are determined based on the amount of reflected laser light detected in each of the ranges of angles. Additionally, a wafer characterization system (100) is described that includes the described optical probe (120).

  17. Thin-film optical initiator

    DOE Patents [OSTI]

    Erickson, Kenneth L.

    2001-01-01

    A thin-film optical initiator having an inert, transparent substrate, a reactive thin film, which can be either an explosive or a pyrotechnic, and a reflective thin film. The resultant thin-film optical initiator system also comprises a fiber-optic cable connected to a low-energy laser source, an output charge, and an initiator housing. The reactive thin film, which may contain very thin embedded layers or be a co-deposit of a light-absorbing material such as carbon, absorbs the incident laser light, is volumetrically heated, and explodes against the output charge, imparting about 5 to 20 times more energy than in the incident laser pulse.

  18. Optical switches and switching methods

    DOE Patents [OSTI]

    Doty, Michael

    2008-03-04

    A device and method for collecting subject responses, particularly during magnetic imaging experiments and testing using a method such as functional MRI. The device comprises a non-metallic input device which is coupled via fiber optic cables to a computer or other data collection device. One or more optical switches transmit the subject's responses. The input device keeps the subject's fingers comfortably aligned with the switches by partially immobilizing the forearm, wrist, and/or hand of the subject. Also a robust nonmetallic switch, particularly for use with the input device and methods for optical switching.

  19. AIRBORNE, OPTICAL REMOTE SENSING OF METHANE AND ETHANE FOR NATURAL GAS PIPELINE LEAK DETECTION

    SciTech Connect (OSTI)

    Jerry Myers

    2003-11-12

    Ophir Corporation was awarded a contract by the U. S. Department of Energy, National Energy Technology Laboratory under the Project Title ''Airborne, Optical Remote Sensing of Methane and Ethane for Natural Gas Pipeline Leak Detection'' on October 14, 2002. This second six-month technical report summarizes the progress made towards defining, designing, and developing the hardware and software segments of the airborne, optical remote methane and ethane sensor. The most challenging task to date has been to identify a vendor capable of designing and developing a light source with the appropriate output wavelength and power. This report will document the work that has been done to identify design requirements, and potential vendors for the light source. Significant progress has also been made in characterizing the amount of light return available from a remote target at various distances from the light source. A great deal of time has been spent conducting laboratory and long-optical path target reflectance measurements. This is important since it helps to establish the overall optical output requirements for the sensor. It also reduces the relative uncertainty and risk associated with developing a custom light source. The data gathered from the optical path testing has been translated to the airborne transceiver design in such areas as: fiber coupling, optical detector selection, gas filters, and software analysis. Ophir will next, summarize the design progress of the transceiver hardware and software development. Finally, Ophir will discuss remaining project issues that may impact the success of the project.

  20. Fluxnet Synthesis Dataset Collaboration Infrastructure

    SciTech Connect (OSTI)

    Agarwal, Deborah A.; Humphrey, Marty; van Ingen, Catharine; Beekwilder, Norm; Goode, Monte; Jackson, Keith; Rodriguez, Matt; Weber, Robin

    2008-02-06

    The Fluxnet synthesis dataset originally compiled for the La Thuile workshop contained approximately 600 site years. Since the workshop, several additional site years have been added and the dataset now contains over 920 site years from over 240 sites. A data refresh update is expected to increase those numbers in the next few months. The ancillary data describing the sites continues to evolve as well. There are on the order of 120 site contacts and 60proposals have been approved to use thedata. These proposals involve around 120 researchers. The size and complexity of the dataset and collaboration has led to a new approach to providing access to the data and collaboration support and the support team attended the workshop and worked closely with the attendees and the Fluxnet project office to define the requirements for the support infrastructure. As a result of this effort, a new website (http://www.fluxdata.org) has been created to provide access to the Fluxnet synthesis dataset. This new web site is based on a scientific data server which enables browsing of the data on-line, data download, and version tracking. We leverage database and data analysis tools such as OLAP data cubes and web reports to enable browser and Excel pivot table access to the data.

  1. Mixed Alcohol Synthesis Catalyst Screening

    SciTech Connect (OSTI)

    Gerber, Mark A.; White, James F.; Stevens, Don J.

    2007-09-03

    National Renewable Energy Laboratory (NREL) and Pacific Northwest National Laboratory (PNNL) are conducting research to investigate the feasibility of producing mixed alcohols from biomass-derived synthesis gas (syngas). PNNL is tasked with obtaining commercially available or preparing promising mixed-alcohol catalysts and screening them in a laboratory-scale reactor system. Commercially available catalysts and the most promising experimental catalysts are provided to NREL for testing using a slipstream from a pilot-scale biomass gasifier. From the standpoint of producing C2+ alcohols as the major product, it appears that the rhodium catalyst is the best choice in terms of both selectivity and space-time yield (STY). However, unless the rhodium catalyst can be improved to provide minimally acceptable STYs for commercial operation, mixed alcohol synthesis will involve significant production of other liquid coproducts. The modified Fischer-Tropsch catalyst shows the most promise for providing both an acceptable selectivity to C2+ alcohols and total liquid STY. However, further optimization of the Fischer-Tropsch catalysts to improve selectivity to higher alcohols is highly desired. Selection of a preferred catalyst will likely entail a decision on the preferred coproduct slate. No other catalysts tested appear amenable to the significant improvements needed for acceptable STYs.

  2. Bioinspired synthesis of magnetic nanoparticles

    SciTech Connect (OSTI)

    David, Anand

    2009-05-26

    The synthesis of magnetic nanoparticles has long been an area of active research. Magnetic nanoparticles can be used in a wide variety of applications such as magnetic inks, magnetic memory devices, drug delivery, magnetic resonance imaging (MRI) contrast agents, and pathogen detection in foods. In applications such as MRI, particle uniformity is particularly crucial, as is the magnetic response of the particles. Uniform magnetic particles with good magnetic properties are therefore required. One particularly effective technique for synthesizing nanoparticles involves biomineralization, which is a naturally occurring process that can produce highly complex nanostructures. Also, the technique involves mild conditions (ambient temperature and close to neutral pH) that make this approach suitable for a wide variety of materials. The term 'bioinspired' is important because biomineralization research is inspired by the naturally occurring process, which occurs in certain microorganisms called 'magnetotactic bacteria'. Magnetotactic bacteria use biomineralization proteins to produce magnetite crystals having very good uniformity in size and morphology. The bacteria use these magnetic particles to navigate according to external magnetic fields. Because these bacteria synthesize high quality crystals, research has focused on imitating aspects of this biomineralization in vitro. In particular, a biomineralization iron-binding protein found in a certain species of magnetotactic bacteria, magnetospirillum magneticum, AMB-1, has been extracted and used for in vitro magnetite synthesis; Pluronic F127 gel was used to increase the viscosity of the reaction medium to better mimic the conditions in the bacteria. It was shown that the biomineralization protein mms6 was able to facilitate uniform magnetite synthesis. In addition, a similar biomineralization process using mms6 and a shorter version of this protein, C25, has been used to synthesize cobalt ferrite particles. The overall goal of this project is to understand the mechanism of magnetite particle synthesis in the presence of the biomineralization proteins, mms6 and C25. Previous work has hypothesized that the mms6 protein helps to template magnetite and cobalt ferrite particle synthesis and that the C25 protein templates cobalt ferrite formation. However, the effect of parameters such as the protein concentration on the particle formation is still unknown. It is expected that the protein concentration significantly affects the nucleation and growth of magnetite. Since the protein provides iron-binding sites, it is expected that magnetite crystals would nucleate at those sites. In addition, in the previous work, the reaction medium after completion of the reaction was in the solution phase, and magnetic particles had a tendency to fall to the bottom of the medium and aggregate. The research presented in this thesis involves solid Pluronic gel phase reactions, which can be studied readily using small-angle x-ray scattering, which is not possible for the solution phase experiments. In addition, the concentration effect of both of the proteins on magnetite crystal formation was studied.

  3. Optical analog-to-digital converter

    DOE Patents [OSTI]

    Vawter, G. Allen (Corrales, NM); Raring, James (Goleta, CA); Skogen, Erik J. (Albuquerque, NM)

    2009-07-21

    An optical analog-to-digital converter (ADC) is disclosed which converts an input optical analog signal to an output optical digital signal at a sampling rate defined by a sampling optical signal. Each bit of the digital representation is separately determined using an optical waveguide interferometer and an optical thresholding element. The interferometer uses the optical analog signal and the sampling optical signal to generate a sinusoidally-varying output signal using cross-phase-modulation (XPM) or a photocurrent generated from the optical analog signal. The sinusoidally-varying output signal is then digitized by the thresholding element, which includes a saturable absorber or at least one semiconductor optical amplifier, to form the optical digital signal which can be output either in parallel or serially.

  4. Optical ordance system for use in explosive ordnance disposal activities

    SciTech Connect (OSTI)

    Merson, J.A.; Salas, F.J.; Helsel, F.M.

    1994-01-01

    A portable hand-held solid state rod laser system and an optically-ignited detonator have been developed for use in explosive ordnance disposal (EOD) activities. Laser prototypes from Whittaker Ordnance and Universal Propulsion have been tested and evaluated. The optical detonator contains 2-(5 cyanotetrazolato) pentaamine cobalt III perchlorate (CP) as the DDT column and the explosive Octahydro 1, 3, 5, 7 -- tetranitro -- 1, 3, 5, 7 -- tetrazocine (HMX) as the output charge. The laser is designed to have an output of 150 mJ in a 500 microsecond pulse. This output allows firing through 2000 meters of optical fiber. The detonator can also be ignited with a portable laser diode source through a shorter length of fiber.

  5. Scintillator fiber optic long counter

    DOE Patents [OSTI]

    McCollum, Tom (Sterling, VA); Spector, Garry B. (Fairfax, VA)

    1994-01-01

    A flat response position sensitive neutron detector capable of providing neutron spectroscopic data utilizing scintillator fiber optic filaments embedded in a neutron moderating housing having an open end through which neutrons enter to be detected.

  6. Sandia Energy - Sensors & Optical Diagnostics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sensors & Optical Diagnostics Home Analysis Schematic representation of the experimental set-up. Shown in the figure is the jet-stirred reactor that is located within an oven, all...

  7. Scintillator fiber optic long counter

    DOE Patents [OSTI]

    McCollum, T.; Spector, G.B.

    1994-03-29

    A flat response position sensitive neutron detector capable of providing neutron spectroscopic data utilizing scintillator fiber optic filaments embedded in a neutron moderating housing having an open end through which neutrons enter to be detected is described. 11 figures.

  8. ARM - Measurement - Cloud optical depth

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    optical depth ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Cloud optical depth Amount of light cloud droplets or ice particles prevent from passing through a column of atmosphere. Categories Cloud Properties Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all

  9. Light diffusing fiber optic chamber

    DOE Patents [OSTI]

    Maitland, Duncan J. (Lafayette, CA)

    2002-01-01

    A light diffusion system for transmitting light to a target area. The light is transmitted in a direction from a proximal end to a distal end by an optical fiber. A diffusing chamber is operatively connected to the optical fiber for transmitting the light from the proximal end to the distal end and transmitting said light to said target area. A plug is operatively connected to the diffusing chamber for increasing the light that is transmitted to the target area.

  10. Synthesis of alpha-amino acids

    DOE Patents [OSTI]

    Davis, Jr., Jefferson W. (San Francisco, CA)

    1983-01-01

    A method for synthesizing alpha amino acids proceding through novel intermediates of the formulas: R.sub.1 R.sub.2 C(OSOCl)CN, R.sub.1 R.sub.2 C(Cl)CN and [R.sub.1 R.sub.2 C(CN)O].sub.2 SO wherein R.sub.1 and R.sub.2 are each selected from hydrogen monovalent substituted and unsubstituted hydrocarbon radicals of 1 to 12 carbon atoms. The use of these intermediates allows the synthesis steps to be exothermic and results in an overall synthesis method which is faster than the synthesis methods of the prior art.

  11. Synthesis of alpha-amino acids

    DOE Patents [OSTI]

    Davis, Jr., Jefferson W. (San Francisco, CA)

    1983-01-01

    A method for synthesizing alpha amino acids proceeding through novel intermediates of the formulas: R.sub.1 R.sub.2 C(OSOCl)CN, R.sub.1 R.sub.2 C(Cl)CN and [R.sub.1 R.sub.2 C(CN)O].sub.2 SO wherein R.sub.1 and R.sub.2 are each selected from hydrogen monovalent substituted and unsubstituted hydrocarbon radicals of 1 to 12 carbon atoms. The use of these intermediates allows the synthesis steps to be exothermic and results in an overall synthesis method which is faster than the synthesis methods of the prior art.

  12. Multiparameter fiber optic sensing system for monitoring enhanced geothermal systems

    SciTech Connect (OSTI)

    William A. Challener

    2014-12-04

    The goal of this project was to design, fabricate and test an optical fiber cable which supports multiple sensing modalities for measurements in the harsh environment of enhanced geothermal systems. To accomplish this task, optical fiber was tested at both high temperatures and strains for mechanical integrity, and in the presence of hydrogen for resistance to darkening. Both single mode (SM) and multimode (MM) commercially available optical fiber were identified and selected for the cable based on the results of these tests. The cable was designed and fabricated using a tube-within-tube construction containing two MM fibers and one SM fiber, and without supporting gel that is not suitable for high temperature environments. Commercial fiber optic sensing instruments using Raman DTS (distributed temperature sensing), Brillouin DTSS (distributed temperature and strain sensing), and Raleigh COTDR (coherent optical time domain reflectometry) were selected for field testing. A microelectromechanical systems (MEMS) pressure sensor was designed, fabricated, packaged, and calibrated for high pressure measurements at high temperatures and spliced to the cable. A fiber Bragg grating (FBG) temperature sensor was also spliced to the cable. A geothermal well was selected and its temperature and pressure were logged. The cable was then deployed in the well in two separate field tests and measurements were made on these different sensing modalities. Raman DTS measurements were found to be accurate to ±5°C, even with some residual hydrogen darkening. Brillouin DTSS measurements were in good agreement with the Raman results. The Rayleigh COTDR instrument was able to detect some acoustic signatures, but was generally disappointing. The FBG sensor was used to determine the effects of hydrogen darkening, but drift over time made it unreliable as a temperature or pressure sensor. The MEMS sensor was found to be highly stable and accurate to better than its 0.1% calibration.

  13. Optomechanical design of a prompt gamma reaction history diagnostic

    SciTech Connect (OSTI)

    Hermann, Hans W; Kaufman, Morris I; Malone, Robert M; Frogget, Brent C; Tunnell, Thomas W; Cox, Brian; Frayer, Daniel K; Ali, Zaheer; Stoeffl, Wolfgang

    2009-01-01

    The National Ignition Facility and the Omega Laser Facility both have a need for measuring prompt gamma radiation as part of a nuclear diagnostic program. A new gamma-detection diagnostic using off-axis-parabolic mirrors has been built. Some new techniques were used in the design, construction, and tolerancing of this gamma ray diagnostic. Because of the wavelength requirement (250-700 nm), the optical element surface finishes were a key design consideration. The optical enclosure had to satisfy pressure safety concerns and shielding against electromagnetic interference induced by gammas and neutrons. Structural finite element analysis was needed to meet rigorous optical and safety requirements. The optomechanical design is presented. Alignment issues are also discussed.

  14. Fiber optic sensor and method for making

    DOE Patents [OSTI]

    Vartuli, James Scott; Bousman, Kenneth Sherwood; Deng, Kung-Li; McEvoy, Kevin Paul; Xia, Hua

    2010-05-18

    A fiber optic sensor including a fiber having a modified surface integral with the fiber wherein the modified surface includes an open pore network with optical agents dispersed within the open pores of the open pore network. Methods for preparing the fiber optic sensor are also provided. The fiber optic sensors can withstand high temperatures and harsh environments.

  15. Optical feedback structures and methods of making

    DOE Patents [OSTI]

    Snee, Preston T; Chan, Yin Thai; Nocera, Daniel G; Bawendi, Moungi G

    2014-11-18

    An optical resonator can include an optical feedback structure disposed on a substrate, and a composite including a matrix including a chromophore. The composite disposed on the substrate and in optical communication with the optical feedback structure. The chromophore can be a semiconductor nanocrystal. The resonator can provide laser emission when excited.

  16. Optical monitor for observing turbulent flow

    DOE Patents [OSTI]

    Albrecht, Georg F. (Livermore, CA); Moore, Thomas R. (Rochester, NY)

    1992-01-01

    The present invention provides an apparatus and method for non-invasively monitoring turbulent fluid flows including anisotropic flows. The present invention uses an optical technique to filter out the rays travelling in a straight line, while transmitting rays with turbulence induced fluctuations in time. The output is two dimensional, and can provide data regarding the spectral intensity distribution, or a view of the turbulence in real time. The optical monitor of the present invention comprises a laser that produces a coherent output beam that is directed through a fluid flow, which phase-modulates the beam. The beam is applied to a temporal filter that filters out the rays in the beam that are straight, while substantially transmitting the fluctuating, turbulence-induced rays. The temporal filter includes a lens and a photorefractive crystal such as BaTiO.sub.3 that is positioned in the converging section of the beam near the focal plane. An imaging system is used to observe the filtered beam. The imaging system may take a photograph, or it may include a real time camera that is connected to a computer. The present invention may be used for many purposes including research and design in aeronautics, hydrodynamics, and combustion.

  17. Patch-clamp array with on-chip electronics, optics, flow control and mechanical actuation.

    SciTech Connect (OSTI)

    James, Conrad D.; Okandan, Murat; Draper, Bruce Leroy; Mani, Seethambal S.

    2003-07-01

    Fast and quantitative analysis of cellular activity, signaling and responses to external stimuli is a crucial capability and it has been the goal of several projects focusing on patch clamp measurements. To provide the maximum functionality and measurement options, we have developed a patch clamp array device that incorporates on-chip electronics, mechanical, optical and microfluidic coupling as well as cell localization through fluid flow. The preliminary design, which integrated microfluidics, electrodes and optical access, was fabricated and tested. In addition, new designs which further combine mechanical actuation, on-chip electronics and various electrode materials with the previous designs are currently being fabricated.

  18. Optical manufacturing requirements for an AVLIS plant

    SciTech Connect (OSTI)

    Primdahl, K.; Chow, R.; Taylor, J.R.

    1997-07-14

    A uranium enrichment plant utilizing Atomic Vapor Laser Isotope Separation (AVLIS) technology is currently being planned. Deployment of the Plant will require tens of thousands of commercial and custom optical components and subsystems. The Plant optical system will be expected to perform at a high level of optical efficiency and reliability in a high-average-power-laser production environment. During construction, demand for this large number of optics must be coordinated with the manufacturing capacity of the optical industry. The general requirements and approach to ensure supply of optical components is described. Dynamic planning and a closely coupled relationship with the optics industry will be required to control cost, schedule, and quality.

  19. Synthesis gas method and apparatus

    DOE Patents [OSTI]

    Kelly, Sean M.; Kromer, Brian R.; Litwin, Michael M.; Rosen, Lee J.; Christie, Gervase Maxwell; Wilson, Jamie; Kosowski, Lawrence W; Robinson, Charles

    2015-11-06

    A method and apparatus for producing a synthesis gas product having one or more oxygen transport membrane elements thermally coupled to one or more catalytic reactors such that heat generated from the oxygen transport membrane element supplies endothermic heating requirements for steam methane reforming reactions occurring within the catalytic reactor through radiation and convention heat transfer. A hydrogen containing stream containing no more than 20 percent methane is combusted within the oxygen transport membrane element to produce the heat and a heated combustion product stream. The heated combustion product stream is combined with a reactant stream to form a combined stream that is subjected to the reforming within the catalytic reactor. The apparatus may include modules in which tubular membrane elements surround a central reactor tube.

  20. Synthesis gas method and apparatus

    DOE Patents [OSTI]

    Kelly, Sean M.; Kromer, Brian R.; Litwin, Michael M.; Rosen, Lee J.; Christie, Gervase Maxwell; Wilson, Jamie R.; Kosowski, Lawrence W.; Robinson, Charles

    2013-01-08

    A method and apparatus for producing a synthesis gas product having one or more oxygen transport membrane elements thermally coupled to one or more catalytic reactors such that heat generated from the oxygen transport membrane element supplies endothermic heating requirements for steam methane reforming reactions occurring within the catalytic reactor through radiation and convention heat transfer. A hydrogen containing stream containing no more than 20 percent methane is combusted within the oxygen transport membrane element to produce the heat and a heated combustion product stream. The heated combustion product stream is combined with a reactant stream to form a combined stream that is subjected to the reforming within the catalytic reactor. The apparatus may include modules in which tubular membrane elements surround a central reactor tube.

  1. Solution synthesis of germanium nanocrystals

    DOE Patents [OSTI]

    Gerung, Henry (Albuquerque, NM); Boyle, Timothy J. (Kensington, MD); Bunge, Scott D. (Cuyahoga Falls, OH)

    2009-09-22

    A method for providing a route for the synthesis of a Ge(0) nanometer-sized material from. A Ge(II) precursor is dissolved in a ligand heated to a temperature, generally between approximately 100.degree. C. and 400.degree. C., sufficient to thermally reduce the Ge(II) to Ge(0), where the ligand is a compound that can bond to the surface of the germanium nanomaterials to subsequently prevent agglomeration of the nanomaterials. The ligand encapsulates the surface of the Ge(0) material to prevent agglomeration. The resulting solution is cooled for handling, with the cooling characteristics useful in controlling the size and size distribution of the Ge(0) materials. The characteristics of the Ge(II) precursor determine whether the Ge(0) materials that result will be nanocrystals or nanowires.

  2. Combustion synthesis continuous flow reactor

    DOE Patents [OSTI]

    Maupin, Gary D. (Richland, WA); Chick, Lawrence A. (West Richland, WA); Kurosky, Randal P. (Maple Valley, WA)

    1998-01-01

    The present invention is a reactor for combustion synthesis of inorganic powders. The reactor includes a reaction vessel having a length and a first end and a second end. The reaction vessel further has a solution inlet and a carrier gas inlet. The reactor further has a heater for heating both the solution and the carrier gas. In a preferred embodiment, the reaction vessel is heated and the solution is in contact with the heated reaction vessel. It is further preferred that the reaction vessel be cylindrical and that the carrier gas is introduced tangentially into the reaction vessel so that the solution flows helically along the interior wall of the reaction vessel. As the solution evaporates and combustion produces inorganic material powder, the carrier gas entrains the powder and carries it out of the reactor.

  3. Electrochemical synthesis of multisegmented nanowires

    SciTech Connect (OSTI)

    Kok, Kuan-Ying; Ng, Inn-Khuan; Saidin, Nur Ubaidah

    2012-11-27

    Electrochemical deposition has emerged as a promising route for nanostructure fabrication in recent years due to the many inherent advantages it possesses. This study focuses on the synthesis of high-aspect-ratio multisegmented Au/Ni nanowires using template-directed sequential electrochemical deposition techniques. By selectively removing the Ni segments in the nanowires, high-yield of pure gold nanorods of predetermined lengths was obtained. Alternatively, the sacrificial Ni segments in the nanowires can be galvanically displaced with Bi and Te to form barbells structures with Bi{sub x}Te{sub y} nanotubes attached to neighbouring gold segments. Detailed studies on the nanostructures obtained were carried out using various microscopy, diffraction and probebased techniques for structural, morphological and chemical characterizations.

  4. Combustion synthesis continuous flow reactor

    DOE Patents [OSTI]

    Maupin, G.D.; Chick, L.A.; Kurosky, R.P.

    1998-01-06

    The present invention is a reactor for combustion synthesis of inorganic powders. The reactor includes a reaction vessel having a length and a first end and a second end. The reaction vessel further has a solution inlet and a carrier gas inlet. The reactor further has a heater for heating both the solution and the carrier gas. In a preferred embodiment, the reaction vessel is heated and the solution is in contact with the heated reaction vessel. It is further preferred that the reaction vessel be cylindrical and that the carrier gas is introduced tangentially into the reaction vessel so that the solution flows helically along the interior wall of the reaction vessel. As the solution evaporates and combustion produces inorganic material powder, the carrier gas entrains the powder and carries it out of the reactor. 10 figs.

  5. Nanoparticles synthesis of tungsten disulfide via AOT-based microemulsions

    SciTech Connect (OSTI)

    Ghoreishi, S.M.; Meshkat, S.S.; Department of Chemical Engineering, Urmia University of Technology, Urmia 57155-419 ; Ghiaci, M.; Dadkhah, A.A.

    2012-06-15

    Graphical abstract: A controlled synthesis of WS2 nanoparticles (most probably inorganic fullerene (IF)) via microemulsion was applied for the first time to prepare WS2 (712 nm) by acidification of the water cores of the AOT reverse microemulsion. Highlights: ? An innovative reverse microemulsion technique was developed for WS{sub 2} synthesis. ? WS{sub 2} nanoparticles were obtained with narrow size distribution in range of 712 nm. ? Operating cost of microemulsion was lower in contrast to quartz reactor method. ? WS{sub 2} morphology could be controlled to obtain highly active and selective catalysts. ? Lower size of WS{sub 2} in this study overcomes the shortcoming of quartz reactor method. -- Abstract: The tungsten disulfide (WS{sub 2}) nanoparticles (most probably inorganic fullerene (IF)) with a narrow size distribution were synthesized by a reverse micelle technique for the first time. The particle size was controlled by varying water-to-surfactant molar ratio (W{sub 0}), aging time and reagent concentration. The synthesized WS{sub 2} nanoparticles were characterized by zetasizer, UVvisible spectrophotometers and transmission electron microscopy (TEM). The WS{sub 2} nanoparticles with particle diameter size of 712 nm were obtained via 24 h aging time. The particle size was controlled by changing the aging time and molar ratio of water/surfactant. Doubling W{sub 0} increased the amount and particle size of WS{sub 2} by 22 and 26%, respectively. The effect of aging time in the range of 624 h was investigated and the complete disappearance of yellowish color at 24 h resulted in an optically clear solution, which was the indication of WS{sub 2} formation with 100% conversion of reactant ((NH{sub 4}){sub 2}WS{sub 4}) in the batch reactor.

  6. Anthrax carbohydrates, synthesis and uses thereof

    DOE Patents [OSTI]

    Carlson, Russell W.; Boons, Geert-Jan; Quinn, Conrad; Vasan, Mahalakshmi; Wolfert, Margreet A.; Choudhury, Biswa; Kannenberg, Elmar; Leoff, Christine; Mehta, Alok; Saile, Elke; Rauvolfova, Jana; Wilkins, Patricia; Harvey, Alex J.

    2013-04-16

    The present invention presents the isolation, characterization and synthesis of oligosaccharides of Bacillus anthracis. Also presented are antibodies that bind to such saccharide moieties and various methods of use for such saccharide moieties and antibodies.

  7. Synthesis and characterization of silicon phthalocyanines bearing...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Authors: Bergkamp, J. J., Sherman, B. D., Mario-Ochoa, E., Palacios, R. E., Cosa, G., Moore, T. A., Gust, D., and Moore, A. L. Title: Synthesis and characterization of silicon...

  8. Synthesis and Characterization of Telluride Aerogels: Effect...

    Office of Scientific and Technical Information (OSTI)

    Synthesis and Characterization of Telluride Aerogels: Effect of Gelation on Thermoelectric Performance of Bi2Te3 and Bi2-xSbxTe3 Nanostructures Citation Details In-Document Search ...

  9. A simple growth method for Nb?O? films and their optical properties

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dash, J. K.; Kisslinger, K.; Chen, L.; Topka, Michael R.; Dinolfo, Peter H.; Zhang, L. H.; Lu, T. -M.; Wang, G. -C.

    2015-04-13

    A simple method for the synthesis of Nb?O? films of thicknesses ranging from tens to several hundreds of nanometers on amorphous silicon dioxide or quartz substrates is presented. Nb?O? films were formed by annealing the sputter deposited Nb films under an Ar flow and without oxygen plasma in a quartz tube within a furnace at 850 C. The structural, compositional, optical, and vibrational properties were characterized by grazing incidence X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy, ultraviolet visible spectroscopy, and Raman scattering. Each of the Nb?O? films is polycrystalline with an orthorhombic crystal structure. We observed vibrational modes includingmorelongitudinal optical, transverse optical, and triply degenerate modes, and measured the indirect optical band gap to be ~3.65 eV. The transmittance spectrum of the ~20 nm thick Nb?O? film shows over 90% transmittance below the band gap energy in the visible wavelength range and decreases to less than 20% in the ultraviolet regime. The optical properties of the films in the UV-vis range show potential applications as UV detectors.less

  10. A simple growth method for Nb2O5 films and their optical properties

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dash, J. K.; Chen, L.; Topka, Michael R.; Dinolfo, Peter H.; Zhang, L. H.; Kisslinger, K.; Lu, T. -M.; Wang, G. -C.

    2015-04-13

    A simple method for the synthesis of Nb₂O₅ films of thicknesses ranging from tens to several hundreds of nanometers on amorphous silicon dioxide or quartz substrates is presented. Nb₂O₅ films were formed by annealing the sputter deposited Nb films under an Ar flow and without oxygen plasma in a quartz tube within a furnace at 850 °C. The structural, compositional, optical, and vibrational properties were characterized by grazing incidence X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy, ultraviolet visible spectroscopy, and Raman scattering. Each of the Nb₂O₅ films is polycrystalline with an orthorhombic crystal structure. We observed vibrational modes includingmore » longitudinal optical, transverse optical, and triply degenerate modes, and measured the indirect optical band gap to be ~3.65 eV. The transmittance spectrum of the ~20 nm thick Nb₂O₅ film shows over 90% transmittance below the band gap energy in the visible wavelength range and decreases to less than 20% in the ultraviolet regime. As a result, the optical properties of the films in the UV-vis range show potential applications as UV detectors.« less

  11. Sandia National Labs: PCNSC: Research: Optical Sciences

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Optical Sciences The focus of the Optical Sciences thrust is to understand and exploit the elegant interaction between light and matter. Our research portfolio encompasses the generation, transmission, manipulation, and detection of light and the development of optical materials with user defined characteristics. We emphasize innovative work in laser and optical materials development, nonlinear optics, spectroscopy, remote sensing, and photon-material interactions. In partnership with our DOE,

  12. LSU EFRC - Center for Atomic Level Catalyst Design - About Us

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    About Us >> space control Our Mission Statement space control Message From The Director space control space control Our Mission Statement space control "Building Effective Catalysts from First Principles: Computational Catalysis and Atomic-Level Synthesis" The mission of LSU's Center for Atomic Level Catalyst Design is to advance: the ability of computational methods to accurately model catalytic reactions on solid surfaces over time and length scales far more representative of

  13. Extraordinary optical transmission in nanopatterned ultrathin metal films without holes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Peer, Akshit; Biswas, Rana

    2016-02-01

    In this study, we experimentally and theoretically demonstrate that a continuous gold film on a periodically textured substrate exhibits extraordinary optical transmission, even though no holes were etched in the film. Our film synthesis started by nanoimprinting a periodic array of nanocups with a period of ~750 nm on a polystyrene film over a glass substrate. A thin non-conformal gold film was sputter-deposited on the polystyrene by angle-directed deposition. The gold film was continuous with spatial thickness variation, the film being thinnest at the bottom of the nanocup. Measurements revealed an extraordinary transmission peak at a wavelength just smaller thanmore » the period, with an enhancement of ~2.5 compared to the classically expected value. Scattering matrix simulations model well the transmission and reflectance measurements when an ultrathin gold layer (~5 nm), smaller than the skin depth is retained at the bottom of the nanocups. Electric field intensities are enhanced by >100 within the nanocup, and ~40 in the ultrathin gold layer causing transmission through it. We show a wavelength red-shift of ~30 nm in the extraordinary transmission peak when the nanocups are coated with a thin film of a few nanometers, which can be utilized for biosensing. The continuous corrugated metal films are far simpler structures to observe extraordinary transmission, circumventing the difficult process of etching the metal film. Such continuous metal films with ultrathin regions are simple platforms for non-linear optics, plasmonics, and biological and chemical sensing.« less

  14. Plasma-Thermal Synthesis - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Thermal Synthesis Idaho National Laboratory Contact INL About This Technology Technology Marketing Summary INL's Plasma-Thermal Synthesis process improves the conversion process for natural gas into liquid hydrocarbon fuels. Description This process provides a method and apparatus for increasing acetylene yield from the thermal conversion of natural gas. The reactants inserted into the reactor chamber are applied at a high temperature of ionized gas. At this time, the reactants are changed to

  15. Lanthanide coordination polymers: Synthesis, diverse structure and

    Office of Scientific and Technical Information (OSTI)

    luminescence properties (Journal Article) | SciTech Connect Lanthanide coordination polymers: Synthesis, diverse structure and luminescence properties Citation Details In-Document Search Title: Lanthanide coordination polymers: Synthesis, diverse structure and luminescence properties The new semirigid exo-bidentate ligand incorporating furfurysalicylamide terminal groups, namely, 1,4-bis([(2'-furfurylaminoformyl)phenoxyl]methyl)-2,5-bismethylbenzene (L) was synthesized and used as building

  16. Synthesis and structural characterization of ferrous trioctahedral

    Office of Scientific and Technical Information (OSTI)

    smectites: Implications for clay mineral genesis and detectability on Mars (Journal Article) | SciTech Connect SciTech Connect Search Results Journal Article: Synthesis and structural characterization of ferrous trioctahedral smectites: Implications for clay mineral genesis and detectability on Mars Citation Details In-Document Search Title: Synthesis and structural characterization of ferrous trioctahedral smectites: Implications for clay mineral genesis and detectability on Mars Authors:

  17. Catalysis and Synthesis | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Catalysis and Synthesis Catalysis and Synthesis Many different types of chemical reactions depend on catalysts in order to work, and the hunt for better catalysts has deep connections to our nation's economy. From biofuels to plastics, the majority of the products we depend on in our everyday lives rely on catalysts. An estimate from the American Chemical Society found that catalysts and catalytic processes are responsible for more than 20 percent of America's gross domestic product. The

  18. Nuclear Engineering Science Laboratory Synthesis program accepting

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    applications for spring, summer 2016 Nuclear Engineering Science Laboratory Synthesis program accepting applications for spring, summer 2016 Opportunity provides students with research experience at Oak Ridge National Laboratory FOR IMMEDIATE RELEASE Nov. 11, 2015 FY16-06 OAK RIDGE, Tenn.-The Nuclear Engineering Science Laboratory Synthesis (NESLS) program is accepting applications for spring and summer 2016. NESLS is a cooperative research initiative at Oak Ridge National Laboratory (ORNL)

  19. ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS

    SciTech Connect (OSTI)

    1999-10-01

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  20. ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS

    SciTech Connect (OSTI)

    Peter J. Tijrn

    2000-03-31

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  1. ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS

    SciTech Connect (OSTI)

    Unknown

    1999-04-01

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  2. ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS

    SciTech Connect (OSTI)

    Unknown

    2000-10-01

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  3. ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS

    SciTech Connect (OSTI)

    Peter J. Tijrn

    2000-09-30

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  4. ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS

    SciTech Connect (OSTI)

    Unknown

    1999-01-01

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  5. Alternative Fuels and Chemicals from Synthesis Gas

    SciTech Connect (OSTI)

    Peter Tijrn

    2003-01-02

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  6. Fiber optic based optical coherence tomography (OCT) for dental applications

    SciTech Connect (OSTI)

    Everett, M. J., LLNL

    1998-06-02

    We have developed a hand-held fiber optic based optical coherence tomography (OCT) system for scanning of the oral cavity We have produced, using this scanning device, in viva cross-sectional images of hard and soft dental tissues in human volunteers Clinically relevant anatomical structures, including the gingival margin, periodontal sulcus, and dento-enamel junction, were visible in all the images The dento-enamel junction and the alveolar bone were identifiable in approximately two thirds of the images These images represent, to our knowledge, the first in viva OCT images of human dental tissue.

  7. Fiber optics spectrochemical emission sensors

    DOE Patents [OSTI]

    Griffin, J.W.; Olsen, K.B.

    1992-02-04

    A method is described of in situ monitoring of a body of a fluid stored in a tank or groundwater or vadose zone gases in a well for the presence of selected chemical species. The method uses a probe insertable into the well or tank via a cable and having an electrical apparatus for exciting selected chemical species in the body of fluid. The probe can have a pair of electrodes for initiating a spark or a plasma cell for maintaining a plasma to excite the selected chemical species. The probe also has an optical apparatus for receiving optical emissions emitted by the excited species and optically transmitting the emissions via the cable to an analysis location outside the well. The analysis includes detecting a selected wavelength in the emissions indicative of the presence of the selected chemical species. A plurality of probes can be suspended at an end of a respective cable, with the transmitting and analyzing steps for each probe being synchronized sequentially for one set of support equipment and instrumentation to monitor at multiple test points. The optical apparatus is arranged about the light guide axis so that the selected chemical species are excited in the fluid in alignment with the light guide axis. Optical emissions are received from the excited chemical species along such axis. 18 figs.

  8. Optical sensor of magnetic fields

    DOE Patents [OSTI]

    Butler, M.A.; Martin, S.J.

    1986-03-25

    An optical magnetic field strength sensor for measuring the field strength of a magnetic field comprising a dilute magnetic semi-conductor probe having first and second ends, longitudinally positioned in the magnetic field for providing Faraday polarization rotation of light passing therethrough relative to the strength of the magnetic field. Light provided by a remote light source is propagated through an optical fiber coupler and a single optical fiber strand between the probe and the light source for providing a light path therebetween. A polarizer and an apparatus for rotating the polarization of the light is provided in the light path and a reflector is carried by the second end of the probe for reflecting the light back through the probe and thence through the polarizer to the optical coupler. A photo detector apparatus is operably connected to the optical coupler for detecting and measuring the intensity of the reflected light and comparing same to the light source intensity whereby the magnetic field strength may be calculated.

  9. Optical coherence domain reflectometry guidewire

    DOE Patents [OSTI]

    Colston, Billy W. (Livermore, CA); Everett, Matthew (Pleasanton, CA); Da Silva, Luiz B. (Danville, CA); Matthews, Dennis (Moss Beach, CA)

    2001-01-01

    A guidewire with optical sensing capabilities is based on a multiplexed optical coherence domain reflectometer (OCDR), which allows it to sense location, thickness, and structure of the arterial walls or other intra-cavity regions as it travels through the body during minimally invasive medical procedures. This information will be used both to direct the guidewire through the body by detecting vascular junctions and to evaluate the nearby tissue. The guidewire contains multiple optical fibers which couple light from the proximal to distal end. Light from the fibers at the distal end of the guidewire is directed onto interior cavity walls via small diameter optics such as gradient index lenses and mirrored corner cubes. Both forward viewing and side viewing fibers can be included. The light reflected or scattered from the cavity walls is then collected by the fibers, which are multiplexed at the proximal end to the sample arm of an optical low coherence reflectometer. The guidewire can also be used in nonmedical applications.

  10. Fiber optics spectrochemical emission sensors

    DOE Patents [OSTI]

    Griffin, Jeffrey W. (Kennewick, WA); Olsen, Khris B. (West Richland, WA)

    1992-01-01

    A method of in situ monitoring of a body of a fluid stored in a tank or groundwater or vadose zone gases in a well for the presence of selected chemical species uses a probe insertable into the well or tank via a cable and having electrical apparatus for exciting selected chemical species in the body of fluid. The probe can have a pair of electrodes for initiating a spark or a plasma cell for maintaining a plasma to excite the selected chemical species. The probe also has optical apparatus for receiving optical emissions emitted by the excited species and optically transmitting the emissions via the cable to an analysis location outside the well. The analysis includes detecting a selected wavelength in the emissions indicative of the presence of the selected chemical species. A plurality of probes can be suspended at an end of a respective cable, with the transmitting and analyzing steps for each probe being synchronized sequentially for one set of support equipment and instrumentation to monitor at multiple test points. The optical apparatus is arranged about the light guide axis so that the selected chemical species are excited the fluid in alignment with the light guide axis and optical emissions are received from the excited chemical species along such axis.

  11. Design | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Design Design Earth-sheltered homes, like the one pictured, are a unique option for efficiently designed homes. No matter the type of home you choose, energy efficient design strategies will save you money and energy. | Photo courtesy of Pamm McFadden/NREL. Earth-sheltered homes, like the one pictured, are a unique option for efficiently designed homes. No matter the type of home you choose, energy efficient design strategies will save you money and energy. | Photo courtesy of Pamm

  12. Arc Plasma Synthesis of Nanostructured Materials: Techniques and Innovations

    SciTech Connect (OSTI)

    Das, A. K.; Bhoraskar, S. V.; Kakati, M.; Karmakar, Soumen

    2008-10-23

    Arc plasma aided synthesis of nanostructured materials has the potential of producing complex nano phase structures in bulk quantities. Successful implementation of this potential capability to industrial scale nano generation needs establishment of a plasma parameter control regime in terms of plasma gas, flow pattern, pressure, local temperature and the plasma fields to obtain the desired nano phase structures. However, there is a need to design innovative in situ experiments for generation of an extensive database and subsequently to correlate plasma parameters to the size, shape and phase of the generated nanostructures. The present paper reviews the various approaches utilized in the field of arc plasma nanosynthesis in general and in the authors' laboratories in particular. Simple plasma diagnostics and monitoring schemes have been used in conjunction with nano materials characterization tools to explore the possibility of controlling the size, shape, yield and phase composition of the arc generated nanostructures through plasma control. Case studies related to synthesis of AlN, Al2O3, TiO2, ZrO2, ZnO), magnetic (e.g. {gamma}-Fe2O3, Fe3O4) and single elemental materials (e.g. carbon nanotubes) are presented.

  13. Integrated optical biosensor system (IOBS)

    DOE Patents [OSTI]

    Grace, Karen M. (Los Alamos, NM); Sweet, Martin R. (Los Alamos, NM); Goeller, Roy M. (Los Alamos, NM); Morrison, Leland Jean (White Rock, NM); Grace, Wynne Kevin (Los Alamos, NM); Kolar, Jerome D. (Los Alamos, NM)

    2007-10-30

    An optical biosensor has a first enclosure with a pathogen recognition surface, including a planar optical waveguide and grating located in the first enclosure. An aperture is in the first enclosure for insertion of sample to be investigated to a position in close proximity to the pathogen recognition surface. A laser in the first enclosure includes means for aligning and means for modulating the laser, the laser having its light output directed toward said grating. Detection means are located in the first enclosure and in optical communication with the pathogen recognition surface for detecting pathogens after interrogation by the laser light and outputting the detection. Electronic means is located in the first enclosure and receives the detection for processing the detection and outputting information on the detection, and an electrical power supply is located in the first enclosure for supplying power to the laser, the detection means and the electronic means.

  14. Fabrication of optical multilayer for two-color phase plate in super-resolution microscope

    SciTech Connect (OSTI)

    Iketaki, Yoshinori; Kitagawa, Katsuichi; Hidaka, Kohjiro; Kato, Naoki; Hirabayashi, Akira; Bokor, Nandor

    2014-07-15

    In super-resolution microscopy based on fluorescence depletion, the two-color phase plate (TPP) is an indispensable optical element, which can independently control the phase shifts for two beams of different color, i.e., the pump and erase beams. By controlling a phase shift of the erase beam through the TPP, the erase beam can be modulated into a doughnut shape, while the pump beam maintains the initial Gaussian shape. To obtain a reliable optical multiplayer (ML) for the TPP, we designed a ML with only two optical layers by performing numerical optimization. The measured phase shifts generated by the fabricated ML using interferometry correspond to the design values. The beam profiles in the focal plane are also consistent with theoretical results. Although the fabricated ML consists of only two optical layers, the ML can provide a suitable phase modulation function for the TPP in a practical super-resolution microscope.

  15. Precision optical slit for high heat load or ultra high vacuum

    DOE Patents [OSTI]

    Andresen, Nord C. (Hayward, CA); DiGennaro, Richard S. (Albany, CA); Swain, Thomas L. (Richmond, CA)

    1995-01-01

    This invention relates generally to slits used in optics that must be precisely aligned and adjusted. The optical slits of the present invention are useful in x-ray optics, x-ray beam lines, optical systems in which the entrance slit is critical for high wavelength resolution. The invention is particularly useful in ultra high vacuum systems where lubricants are difficult to use and designs which avoid the movement of metal parts against one another are important, such as monochrometers for high wavelength resolution with ultra high vacuum systems. The invention further relates to optical systems in which temperature characteristics of the slit materials is important. The present invention yet additionally relates to precision slits wherein the opposing edges of the slit must be precisely moved relative to a center line between the edges with each edge retaining its parallel orientation with respect to the other edge and/or the center line.

  16. Precision optical slit for high heat load or ultra high vacuum

    DOE Patents [OSTI]

    Andresen, N.C.; DiGennaro, R.S.; Swain, T.L.

    1995-01-24

    This invention relates generally to slits used in optics that must be precisely aligned and adjusted. The optical slits of the present invention are useful in x-ray optics, x-ray beam lines, optical systems in which the entrance slit is critical for high wavelength resolution. The invention is particularly useful in ultra high vacuum systems where lubricants are difficult to use and designs which avoid the movement of metal parts against one another are important, such as monochromators for high wavelength resolution with ultra high vacuum systems. The invention further relates to optical systems in which temperature characteristics of the slit materials is important. The present invention yet additionally relates to precision slits wherein the opposing edges of the slit must be precisely moved relative to a center line between the edges with each edge retaining its parallel orientation with respect to the other edge and/or the center line. 21 figures.

  17. Preliminary Safety Design RM

    Office of Environmental Management (EM)

    Identifier Safety Guidance & Requirements SG Hazards Identification & Control Selection HI Preliminary Safety Design Report PR Risks to Project Safety Decisions SR Safety Design...

  18. Optical pumping and xenon NMR

    SciTech Connect (OSTI)

    Raftery, M.D.

    1991-11-01

    Nuclear Magnetic Resonance (NMR) spectroscopy of xenon has become an important tool for investigating a wide variety of materials, especially those with high surface area. The sensitivity of its chemical shift to environment, and its chemical inertness and adsorption properties make xenon a particularly useful NMR probe. This work discusses the application of optical pumping to enhance the sensitivity of xenon NMR experiments, thereby allowing them to be used in the study of systems with lower surface area. A novel method of optically-pumping [sup 129]Xe in low magnetic field below an NMR spectrometer and subsequent transfer of the gas to high magnetic field is described. NMR studies of the highly polarized gas adsorbed onto powdered samples with low to moderate surface areas are now possible. For instance, NMR studies of optically-pumped xenon adsorbed onto polyacrylic acid show that xenon has a large interaction with the surface. By modeling the low temperature data in terms of a sticking probability and the gas phase xenon-xenon interaction, the diffusion coefficient for xenon at the surface of the polymer is determined. The sensitivity enhancement afforded by optical pumping also allows the NMR observation of xenon thin films frozen onto the inner surfaces of different sample cells. The geometry of the thin films results in interesting line shapes that are due to the bulk magnetic susceptibility of xenon. Experiments are also described that combine optical pumping with optical detection for high sensitivity in low magnetic field to observe the quadrupoler evolution of 131 Xe spins at the surface of the pumping cells. In cells with macroscopic asymmetry, a residual quadrupolar interaction causes a splitting in the [sup 131]Xe NMR frequencies in bare Pyrex glass cells and cells with added hydrogen.

  19. Optical pumping and xenon NMR

    SciTech Connect (OSTI)

    Raftery, M.D.

    1991-11-01

    Nuclear Magnetic Resonance (NMR) spectroscopy of xenon has become an important tool for investigating a wide variety of materials, especially those with high surface area. The sensitivity of its chemical shift to environment, and its chemical inertness and adsorption properties make xenon a particularly useful NMR probe. This work discusses the application of optical pumping to enhance the sensitivity of xenon NMR experiments, thereby allowing them to be used in the study of systems with lower surface area. A novel method of optically-pumping {sup 129}Xe in low magnetic field below an NMR spectrometer and subsequent transfer of the gas to high magnetic field is described. NMR studies of the highly polarized gas adsorbed onto powdered samples with low to moderate surface areas are now possible. For instance, NMR studies of optically-pumped xenon adsorbed onto polyacrylic acid show that xenon has a large interaction with the surface. By modeling the low temperature data in terms of a sticking probability and the gas phase xenon-xenon interaction, the diffusion coefficient for xenon at the surface of the polymer is determined. The sensitivity enhancement afforded by optical pumping also allows the NMR observation of xenon thin films frozen onto the inner surfaces of different sample cells. The geometry of the thin films results in interesting line shapes that are due to the bulk magnetic susceptibility of xenon. Experiments are also described that combine optical pumping with optical detection for high sensitivity in low magnetic field to observe the quadrupoler evolution of 131 Xe spins at the surface of the pumping cells. In cells with macroscopic asymmetry, a residual quadrupolar interaction causes a splitting in the {sup 131}Xe NMR frequencies in bare Pyrex glass cells and cells with added hydrogen.

  20. Optical Switch Using Risley Prisms

    DOE Patents [OSTI]

    Sweatt, William C. (Albuquerque, NM); Christenson, Todd R. (Albuquerque, NM)

    2005-02-22

    An optical switch using Risley prisms and rotary microactuators to independently rotate the wedge prisms of each Risley prism pair is disclosed. The optical switch comprises an array of input Risley prism pairs that selectively redirect light beams from a plurality of input ports to an array of output Risley prism pairs that similarly direct the light beams to a plurality of output ports. Each wedge prism of each Risley prism pair can be independently rotated by a variable-reluctance stepping rotary microactuator that is fabricated by a multi-layer LIGA process. Each wedge prism can be formed integral to the annular rotor of the rotary microactuator by a DXRL process.

  1. Optical switch using Risley prisms

    DOE Patents [OSTI]

    Sweatt, William C. (Albuquerque, NM); Christenson, Todd R. (Albuquerque, NM)

    2003-04-15

    An optical switch using Risley prisms and rotary microactuators to independently rotate the wedge prisms of each Risley prism pair is disclosed. The optical switch comprises an array of input Risley prism pairs that selectively redirect light beams from a plurality of input ports to an array of output Risley prism pairs that similarly direct the light beams to a plurality of output ports. Each wedge prism of each Risley prism pair can be independently rotated by a variable-reluctance stepping rotary microactuator that is fabricated by a multi-layer LIGA process. Each wedge prism can be formed integral to the annular rotor of the rotary microactuator by a DXRL process.

  2. Solid-state optical microscope

    DOE Patents [OSTI]

    Young, I.T.

    1981-01-07

    A solid state optical microscope is described wherein wide-field and high-resolution images of an object are produced at a rapid rate by utilizing conventional optics with a charge-coupled photodiode array. Means for scanning in one of two orthogonal directions are provided, while the charge-coupled photodiode array scans in the other orthogonal direction. Illumination light from the object is incident upon the photodiodes, creating packets of electrons (signals) which are representative of the illuminated object. The signals are then processed, stored in a memory, and finally displayed as a video signal.

  3. Solar Design Workbook

    SciTech Connect (OSTI)

    Franta, G.; Baylin, F.; Crowther, R.; Dubin, F.; Grace, A., Griffith, J.W.; Holtz, M.; Kutscher, C.; Nordham, D.; Selkowitz, S.; Villecco, M.

    1981-06-01

    This Solar Design Workbook presents solar building design applications for commercial buildir^s. The book is divided into four sections. The first section describes the variety of solar applications in buildings including conservation aspects, solar fundamentals, passive systems, active systems, daylighting, and other solar options. Solar system design evaluation techniques including considerations for building energy requirements, passive systems, active systems, and economics are presented in Section II. The third section attempts to assist the designer in the building design process for energy conservation and solar applications including options and considerations for pre-design, design, and post-design phases. The information required for the solar design proee^ has not been fully developed at this time. Therefore, Section III is incomplete, but an overview of the considerations with some of the design proces elements is presented. Section IV illustrates ease studies that utilize solar applications in the building design.

  4. WhiteOptics' Low-Cost Reflector Composite Boosts LED Fixture Efficiency

    Broader source: Energy.gov [DOE]

    With the help of DOE funding, WhiteOptics has developed a composite coating that can be used to improve efficiency in backlit, indirect, and cavity-mixing LED luminaire designs by maximizing light reflection and output. The highly diffuse coating, which is based on a novel high-reflectance particle technology, allows for uniform distribution of light without exaggerating the point-source nature of the LEDs, and is intended to offer an overall system cost-improving solution for LED optics.

  5. Post delivery test report for light duty utility arm optical alignment system (OAS)

    SciTech Connect (OSTI)

    Pardini, A.F.

    1996-04-18

    This report documents the post delivery testing of the Optical Alignment System (OAS) LDUA system, designed for use by the Light Duty Utility Arm (LDUA) project. The post delivery test shows by demonstration that the optical alignment system is fully operational to perform the task of aligning the LDUA arm and mast with the entry riser during deployment operations within a Hanford Site waste tank.

  6. Reflective optical imaging system with balanced distortion

    SciTech Connect (OSTI)

    Chapman, Henry N.; Hudyma, Russell M.; Shafer, David R.; Sweeney, Donald W.

    1999-01-01

    An optical system compatible with short wavelength (extreme ultraviolet) An optical system compatible with short wavelength (extreme ultraviolet) radiation comprising four reflective elements for projecting a mask image onto a substrate. The four optical elements comprise, in order from object to image, convex, concave, convex and concave mirrors. The optical system is particularly suited for step and scan lithography methods. The invention enables the use of larger slit dimensions associated with ring field scanning optics, improves wafer throughput and allows higher semiconductor device density. The inventive optical system is characterized by reduced dynamic distortion because the static distortion is balanced across the slit width.

  7. Integrated optical tamper sensor with planar waveguide

    DOE Patents [OSTI]

    Carson, R.F.; Casalnuovo, S.A.

    1993-01-05

    A monolithic optical tamper sensor, comprising an optical emitter and detector, connected by an optical waveguide and placed into the critical entry plane of an enclosed sensitive region, the tamper sensor having a myriad of scraps of a material optically absorbent at the wavelength of interest, such that when the absorbent material is in place on the waveguide, an unique optical signature can be recorded, but when entry is attempted into the enclosed sensitive region, the scraps of absorbent material will be displaced and the optical/electrical signature of the tamper sensor will change and that change can be recorded.

  8. Integrated optical tamper sensor with planar waveguide

    DOE Patents [OSTI]

    Carson, Richard F. (Albuquerque, NM); Casalnuovo, Stephen A. (Albuquerque, NM)

    1993-01-01

    A monolithic optical tamper sensor, comprising an optical emitter and detector, connected by an optical waveguide and placed into the critical entry plane of an enclosed sensitive region, the tamper sensor having a myriad of scraps of a material optically absorbent at the wavelength of interest, such that when the absorbent material is in place on the waveguide, an unique optical signature can be recorded, but when entry is attempted into the enclosed sensitive region, the scraps of absorbent material will be displaced and the optical/electrical signature of the tamper sensor will change and that change can be recorded.

  9. On the Radio and Optical Luminosity Evolution of Quasars

    SciTech Connect (OSTI)

    Singal, J.; Petrosian, V.; Lawrence, A.; Stawarz, L.; /JAXA, Sagamihara /Jagiellonian U., Astron. Observ.

    2011-05-20

    We calculate simultaneously the radio and optical luminosity evolutions of quasars, and the distribution in radio loudness R defined as the ratio of radio and optical luminosities, using a flux limited data set containing 636 quasars with radio and optical fluxes from White et al. We first note that when dealing with multivariate data it is imperative to first determine the true correlations among the variables, not those introduced by the observational selection effects, before obtaining the individual distributions of the variables. We use the methods developed by Efron and Petrosian which are designed to obtain unbiased correlations, distributions, and evolution with redshift from a data set truncated due to observational biases. It is found that as expected the population of quasars exhibits strong positive correlation between the radio and optical luminosities and that this correlation deviates from a simple linear relation in a way indicating that more luminous quasars are more radio loud. We also find that there is a strong luminosity evolution with redshift in both wavebands, with significantly higher radio than optical evolution. We conclude that the luminosity evolution obtained by arbitrarily separating the sources into radio loud (R > 10) and radio quiet (R < 10) populations introduces significant biases that skew the result considerably. We also construct the local radio and optical luminosity functions and the density evolution. Finally, we consider the distribution of the radio loudness parameter R obtained from careful treatment of the selection effects and luminosity evolutions with that obtained from the raw data without such considerations. We find a significant difference between the two distributions and no clear sign of bi-modality in the true distribution. Our results indicate therefore, somewhat surprisingly, that there is no critical switch in the efficiency of the production of disk outflows/jets between very radio quiet and very radio loud quasars, but rather a smooth transition. Also, this efficiency seems higher for the high-redshift and more luminous sources in the considered sample.

  10. Nanoscale Synthesis and Characterization Laboratory Annual Report 2005

    SciTech Connect (OSTI)

    Hamza, A V; Lesuer, D R

    2006-01-03

    The Nanoscale Synthesis and Characterization Laboratory's (NSCL) primary mission is to create and advance interdisciplinary research and development opportunities in nanoscience and technology. The initial emphasis of the NSCL has been on development of scientific solutions in support of target fabrication for the NIF laser and other stockpile stewardship experimental platforms. Particular emphasis has been placed on the design and development of innovative new materials and structures for use in these targets. Projects range from the development of new high strength nanocrystalline alloys to graded density materials to high Z nanoporous structures. The NSCL also has a mission to recruit and train personnel for Lab programs such as the National Ignition Facility (NIF), Defense and Nuclear Technologies (DNT), and Nonproliferation, Arms control and International security (NAI). The NSCL continues to attract talented scientists to the Laboratory.

  11. DOE handbook: Design considerations

    SciTech Connect (OSTI)

    1999-04-01

    The Design Considerations Handbook includes information and suggestions for the design of systems typical to nuclear facilities, information specific to various types of special facilities, and information useful to various design disciplines. The handbook is presented in two parts. Part 1, which addresses design considerations, includes two sections. The first addresses the design of systems typically used in nuclear facilities to control radiation or radioactive materials. Specifically, this part addresses the design of confinement systems and radiation protection and effluent monitoring systems. The second section of Part 1 addresses the design of special facilities (i.e., specific types of nonreactor nuclear facilities). The specific design considerations provided in this section were developed from review of DOE 6430.1A and are supplemented with specific suggestions and considerations from designers with experience designing and operating such facilities. Part 2 of the Design Considerations Handbook describes good practices and design principles that should be considered in specific design disciplines, such as mechanical systems and electrical systems. These good practices are based on specific experiences in the design of nuclear facilities by design engineers with related experience. This part of the Design Considerations Handbook contains five sections, each of which applies to a particular engineering discipline.

  12. Hadamard multimode optical imaging transceiver

    DOE Patents [OSTI]

    Cooke, Bradly J; Guenther, David C; Tiee, Joe J; Kellum, Mervyn J; Olivas, Nicholas L; Weisse-Bernstein, Nina R; Judd, Stephen L; Braun, Thomas R

    2012-10-30

    Disclosed is a method and system for simultaneously acquiring and producing results for multiple image modes using a common sensor without optical filtering, scanning, or other moving parts. The system and method utilize the Walsh-Hadamard correlation detection process (e.g., functions/matrix) to provide an all-binary structure that permits seamless bridging between analog and digital domains. An embodiment may capture an incoming optical signal at an optical aperture, convert the optical signal to an electrical signal, pass the electrical signal through a Low-Noise Amplifier (LNA) to create an LNA signal, pass the LNA signal through one or more correlators where each correlator has a corresponding Walsh-Hadamard (WH) binary basis function, calculate a correlation output coefficient for each correlator as a function of the corresponding WH binary basis function in accordance with Walsh-Hadamard mathematical principles, digitize each of the correlation output coefficient by passing each correlation output coefficient through an Analog-to-Digital Converter (ADC), and performing image mode processing on the digitized correlation output coefficients as desired to produce one or more image modes. Some, but not all, potential image modes include: multi-channel access, temporal, range, three-dimensional, and synthetic aperture.

  13. Fiber optic refractive index monitor

    DOE Patents [OSTI]

    Weiss, Jonathan David (Albuquerque, NM)

    2002-01-01

    A sensor for measuring the change in refractive index of a liquid uses the lowest critical angle of a normal fiber optic to achieve sensitivity when the index of the liquid is significantly less than the index of the fiber core. Another embodiment uses a liquid filled core to ensure that its index is approximately the same as the liquid being measured.

  14. System for testing optical fibers

    DOE Patents [OSTI]

    Davies, Terence J. (Santa Barbara, CA); Franks, Larry A. (Santa Barbara, CA); Nelson, Melvin A. (Santa Barbara, CA)

    1981-01-01

    A system for nondestructively determining the attenuation coefficient, .alpha.(.lambda.), of low-loss optical fiber wave guides. Cerenkov light pulses are generated at a plurality of locations in the fiber by a beam of charged particles. The transit times of selected spectral components and their intensities are utilized to unfold the .alpha.(.lambda.) values over the measured spectrum.

  15. Remotely readable fiber optic compass

    DOE Patents [OSTI]

    Migliori, A.; Swift, G.W.; Garrett, S.L.

    1985-04-30

    A remotely readable fiber optic compass. A sheet polarizer is affixed to a magnet rotatably mounted in a compass body, such that the polarizer rotates with the magnet. The optical axis of the sheet polarizer is preferably aligned with the north-south axis of the magnet. A single excitation light beam is divided into four identical beams, two of which are passed through the sheet polarizer and through two fixed polarizing sheets which have their optical axes at right angles to one another. The angle of the compass magnet with respect to a fixed axis of the compass body can be determined by measuring the ratio of the intensities of the two light beams. The remaining ambiguity as to which of the four possible quadrants the magnet is pointing to is resolved by the second pair of light beams, which are passed through the sheet polarizer at positions which are transected by two semicircular opaque strips formed on the sheet polarizer. The incoming excitation beam and the four return beams are communicated by means of optical fibers, giving a remotely readable compass which has no electrical parts.

  16. Fabrication of an optical component

    DOE Patents [OSTI]

    Nichols, Michael A.; Aikens, David M.; Camp, David W.; Thomas, Ian M.; Kiikka, Craig; Sheehan, Lynn M.; Kozlowski, Mark R.

    2000-01-01

    A method for forming optical parts used in laser optical systems such as high energy lasers, high average power lasers, semiconductor capital equipment and medical devices. The optical parts will not damage during the operation of high power lasers in the ultra-violet light range. A blank is first ground using a fixed abrasive grinding method to remove the subsurface damage formed during the fabrication of the blank. The next step grinds and polishes the edges and forms bevels to reduce the amount of fused-glass contaminants in the subsequent steps. A loose abrasive grind removes the subsurface damage formed during the fixed abrasive or "blanchard" removal process. After repolishing the bevels and performing an optional fluoride etch, the surface of the blank is polished using a zirconia slurry. Any subsurface damage formed during the loose abrasive grind will be removed during this zirconia polish. A post polish etch may be performed to remove any redeposited contaminants. Another method uses a ceria polishing step to remove the subsurface damage formed during the loose abrasive grind. However, any residual ceria may interfere with the optical properties of the finished part. Therefore, the ceria and other contaminants are removed by performing either a zirconia polish after the ceria polish or a post ceria polish etch.

  17. Solid colloidal optical wavelength filter

    DOE Patents [OSTI]

    Alvarez, Joseph L. (Boulder, CO)

    1992-01-01

    A solid colloidal optical wavelength filter includes a suspension of spheal particles dispersed in a coagulable medium such as a setting plastic. The filter is formed by suspending spherical particles in a coagulable medium; agitating the particles and coagulable medium to produce an emulsion of particles suspended in the coagulable medium; and allowing the coagulable medium and suspended emulsion of particles to cool.

  18. Interferometric fiber optic displacement sensor

    DOE Patents [OSTI]

    Farah, John

    1999-01-01

    A method is presented to produce a change in the optical path length in the gap between two single mode optical fibers proportional to the lateral displacement of either fiber end normal to its axis. This is done with the use of refraction or diffraction at the interface between a guiding and non-guiding media to change the direction of propagation of the light in the gap. A method is also presented for laying a waveguide on a cantilever so that the displacement of the tip of the cantilever produces a proportional path length change in the gap by distancing the waveguide from the neutral axis of the cantilever. The fiber is supported as a cantilever or a waveguide is deposited on a micromachined cantilever and incorporated in an interferometer which is made totally on a silicon substrate with the use of integrated-optic technology. A resonant element in the form of a micro-bridge is incorporated in the ridge waveguide and produces a frequency output which is readily digitizeable and immune to laser frequency noise. Finally, monolithic mechanical means for phase modulation are provided on the same sensor substrate. This is done by vibrating the cantilever or micro-bridge either electrically or optically.

  19. Interferometric fiber optic displacement sensor

    DOE Patents [OSTI]

    Farah, J.

    1995-05-30

    A method is presented to produce a change in the optical path length in the gap between two single mode optical fibers proportional to the lateral displacement of either fiber end normal to its axis. This is done with the use of refraction or diffraction at the interface between a guiding and non-guiding media to change the direction of propagation of the light in the gap. A method is also presented for laying a waveguide on a cantilever so that the displacement of the tip of the cantilever produces a proportional path length change in the gap by distancing the waveguide from the neutral axis of the cantilever. The fiber is supported as a cantilever or a waveguide is deposited on a micromachined cantilever and incorporated in an interferometer which is made totally on a silicon substrate with the use of integrated-optic technology. A resonant element in the form of a micro-bridge is incorporated in the ridge waveguide and produces a frequency output which is readily digitizeable and immune to laser frequency noise. Finally, monolithic mechanical means for phase modulation are provided on the same sensor substrate. This is done by vibrating the cantilever or micro-bridge either electrically or optically. 29 figs.

  20. Interferometric fiber optic displacement sensor

    DOE Patents [OSTI]

    Farah, J.

    1999-04-06

    A method is presented to produce a change in the optical path length in the gap between two single mode optical fibers proportional to the lateral displacement of either fiber end normal to its axis. This is done with the use of refraction or diffraction at the interface between a guiding and non-guiding media to change the direction of propagation of the light in the gap. A method is also presented for laying a waveguide on a cantilever so that the displacement of the tip of the cantilever produces a proportional path length change in the gap by distancing the waveguide from the neutral axis of the cantilever. The fiber is supported as a cantilever or a waveguide is deposited on a micromachined cantilever and incorporated in an interferometer which is made totally on a silicon substrate with the use of integrated-optic technology. A resonant element in the form of a micro-bridge is incorporated in the ridge waveguide and produces a frequency output which is readily digitizeable and immune to laser frequency noise. Finally, monolithic mechanical means for phase modulation are provided on the same sensor substrate. This is done by vibrating the cantilever or micro-bridge either electrically or optically. 23 figs.