National Library of Energy BETA

Sample records for desiccant enhanced evaporative

  1. Lab Breakthrough: Desiccant Enhanced Evaporative Air Conditioning |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Desiccant Enhanced Evaporative Air Conditioning Lab Breakthrough: Desiccant Enhanced Evaporative Air Conditioning May 29, 2012 - 5:22pm Addthis This breakthrough combines desiccant materials, which remove moisture from the air using heat, and advanced evaporative technologies to develop a cooling unit that uses 90 percent less electricity and up to 80 percent less total energy than traditional air conditioning. This solution, called the desiccant enhanced evaporative air

  2. Breakthrough Video: Desiccant Enhanced Evaporative Air Conditioning

    SciTech Connect (OSTI)

    2012-01-01

    Researchers at the National Renewable Energy Laboratory (NREL) invented a breakthrough technology that improves air conditioning in a novel way—with heat. NREL combined desiccant materials, which remove moisture from the air using heat, and advanced evaporative technologies to develop a cooling unit that uses 90% less electricity and up to 80% less total energy than traditional air conditioning (AC). This solution, called the desiccant enhanced evaporative air conditioner (DEVAP), also controls humidity more effectively to improve the comfort of people in buildings.

  3. Desiccant Enhanced Evaporative Air Conditioning: Parametric Analysis and Design; Preprint

    SciTech Connect (OSTI)

    Woods, J.; Kozubal, E.

    2012-10-01

    This paper presents a parametric analysis using a numerical model of a new concept in desiccant and evaporative air conditioning. The concept consists of two stages: a liquid desiccant dehumidifier and a dew-point evaporative cooler. Each stage consists of stacked air channel pairs separated by a plastic sheet. In the first stage, a liquid desiccant film removes moisture from the process (supply-side) air through a membrane. An evaporatively-cooled exhaust airstream on the other side of the plastic sheet cools the desiccant. The second-stage indirect evaporative cooler sensibly cools the dried process air. We analyze the tradeoff between device size and energy efficiency. This tradeoff depends strongly on process air channel thicknesses, the ratio of first-stage to second-stage area, and the second-stage exhaust air flow rate. A sensitivity analysis reiterates the importance of the process air boundary layers and suggests a need for increasing airside heat and mass transfer enhancements.

  4. Seminar 14 - Desiccant Enhanced Air Conditioning: Desiccant Enhanced Evaporative Air Conditioning (Presentation)

    SciTech Connect (OSTI)

    Kozubal, E.

    2013-02-01

    This presentation explains how liquid desiccant based coupled with an indirect evaporative cooler can efficiently produce cool, dry air, and how a liquid desiccant membrane air conditioner can efficiently provide cooling and dehumidification without the carryover problems of previous generations of liquid desiccant systems. It provides an overview to a liquid desiccant DX air conditioner that can efficiently provide cooling and dehumidification to high latent loads without the need for reheat, explains how liquid desiccant cooling and dehumidification systems can outperform vapor compression based air conditioning systems in hot and humid climates, explains how liquid desiccant cooling and dehumidification systems work, and describes a refrigerant free liquid desiccant based cooling system.

  5. Development and Analysis of Desiccant Enhanced Evaporative Air Conditioner Prototype

    SciTech Connect (OSTI)

    Kozubal, E.; Woods, J.; Judkoff, R.

    2012-04-01

    This report documents the design of a desiccant enhanced evaporative air conditioner (DEVAP AC) prototype and the testing to prove its performance. Previous numerical modeling and building energy simulations indicate a DEVAP AC can save significant energy compared to a conventional vapor compression AC (Kozubal et al. 2011). The purposes of this research were to build DEVAP prototypes, test them to validate the numerical model, and identify potential commercialization barriers.

  6. Development and Analysis of Desiccant Enhanced Evaporative Air Conditioner Prototype

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Development and Analysis of Desiccant Enhanced Evaporative Air Conditioner Prototype Eric Kozubal, Jason Woods, and Ron Judkoff Technical Report NREL/TP-5500-54755 April 2012 NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency & Renewable Energy, operated by the Alliance for Sustainable Energy, LLC. National Renewable Energy Laboratory 15013 Denver West Parkway Golden, Colorado 80401 303-275-3000 * www.nrel.gov Contract No. DE-AC36-08GO28308

  7. Desiccant Enhanced Evaporative Air-Conditioning (DEVap): Evaluation of a New Concept in Ultra Efficient Air Conditioning

    SciTech Connect (OSTI)

    Kozubal, E.; Woods, J.; Burch, J.; Boranian, A.; Merrigan, T.

    2011-01-01

    NREL has developed the novel concept of a desiccant enhanced evaporative air conditioner (DEVap) with the objective of combining the benefits of liquid desiccant and evaporative cooling technologies into an innovative 'cooling core.' Liquid desiccant technologies have extraordinary dehumidification potential, but require an efficient cooling sink. DEVap's thermodynamic potential overcomes many shortcomings of standard refrigeration-based direct expansion cooling. DEVap decouples cooling and dehumidification performance, which results in independent temperature and humidity control. The energy input is largely switched away from electricity to low-grade thermal energy that can be sourced from fuels such as natural gas, waste heat, solar, or biofuels.

  8. Indirect evaporative cooler using membrane-contained, liquid desiccant for dehumidification

    DOE Patents [OSTI]

    Kozubal, Eric Joseph; Slayzak, Steven Joseph

    2014-07-08

    An indirect evaporative cooler for cooling inlet supply air from a first temperature to a second, lower temperature using a stream of liquid coolant and a stream of exhaust or purge air. The cooler includes a first flow channel for inlet supply air and a second flow channel adjacent the first for exhaust air. The first and second flow channels are defined in part by sheets of a membrane permeable to water vapor such that mass is transferred as a vapor through the membrane from the inlet supply air to a contained liquid desiccant for dehumidification and also to the exhaust air as heat is transferred from the inlet supply air to the liquid coolant. A separation wall divides the liquid desiccant and the coolant but allows heat to be transferred from the supply air to the coolant which releases water vapor to the counter or cross flowing exhaust air.

  9. Desiccant Enhanced Evaporative Air-Conditioning (DEVap): Evaluation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... air conditioner market will create some market risk. ... AC. The availability of natural gas or other thermal energy ... 46 5.3 Solar Thermal Integration ......

  10. Desiccant-Enhanced Evaporative Air Conditioning. Parametric Analysis and Design

    SciTech Connect (OSTI)

    Woods, J.; Kozubal, E.

    2012-08-04

    Presented at the Second International Conference on Building Energy and Environment (COBEE2012); Boulder, Colorado; August 1-4-, 2012

  11. Evaporative cooling enhanced cold storage system

    DOE Patents [OSTI]

    Carr, P.

    1991-10-15

    The invention provides an evaporatively enhanced cold storage system wherein a warm air stream is cooled and the cooled air stream is thereafter passed into contact with a cold storage unit. Moisture is added to the cooled air stream prior to or during contact of the cooled air stream with the cold storage unit to effect enhanced cooling of the cold storage unit due to evaporation of all or a portion of the added moisture. Preferably at least a portion of the added moisture comprises water condensed during the cooling of the warm air stream. 3 figures.

  12. Evaporative cooling enhanced cold storage system

    DOE Patents [OSTI]

    Carr, Peter (Cary, NC)

    1991-01-01

    The invention provides an evaporatively enhanced cold storage system wherein a warm air stream is cooled and the cooled air stream is thereafter passed into contact with a cold storage unit. Moisture is added to the cooled air stream prior to or during contact of the cooled air stream with the cold storage unit to effect enhanced cooling of the cold storage unit due to evaporation of all or a portion of the added moisture. Preferably at least a portion of the added moisture comprises water condensed during the cooling of the warm air stream.

  13. Innovative Evaporative and Thermally Activated Technologies Improve Air Conditioning; The Spectrum of Clean Energy Innovation (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2010-06-01

    Fact sheet describes NREL's work on a desiccant enhanced evaporative air conditioner (DEVap) that uses 90% less electricity than traditional air conditioning units.

  14. Indirect evaporative coolers with enhanced heat transfer

    DOE Patents [OSTI]

    Kozubal, Eric; Woods, Jason; Judkoff, Ron

    2015-09-22

    A separator plate assembly for use in an indirect evaporative cooler (IEC) with an air-to-air heat exchanger. The assembly includes a separator plate with a first surface defining a dry channel and a second surface defining a wet channel. The assembly includes heat transfer enhancements provided on the first surface for increasing heat transfer rates. The heat transfer enhancements may include slit fins with bodies extending outward from the first surface of separator plate or may take other forms including vortex generators, offset strip fins, and wavy fins. In slit fin implementations, the separator plate has holes proximate to each of the slit fins, and the separator plate assembly may include a sealing layer applied to the second surface of the separator plate to block air flow through the holes. The sealing layer can be a thickness of adhesive, and a layer of wicking material is applied to the adhesive.

  15. Performance Assessment of a Desiccant Cooling System in a CHP Application with an IC Engine

    SciTech Connect (OSTI)

    Jalalzadeh-Azar, A. A.; Slayzak, S.; Judkoff, R.; Schaffhauser, T.; DeBlasio, R.

    2005-04-01

    Performance of a desiccant cooling system was evaluated in the context of combined heat and power (CHP). The baseline system incorporated a desiccant dehumidifier, a heat exchanger, an indirect evaporative cooler, and a direct evaporative cooler. The desiccant unit was regenerated through heat recovery from a gas-fired reciprocating internal combustion engine. The system offered sufficient sensible and latent cooling capacities for a wide range of climatic conditions, while allowing influx of outside air in excess of what is typically required for commercial buildings. Energy and water efficiencies of the desiccant cooling system were also evaluated and compared with those of a conventional system. The results of parametric assessments revealed the importance of using a heat exchanger for concurrent desiccant post cooling and regeneration air preheating. These functions resulted in enhancement of both the cooling performance and the thermal efficiency, which are essential for fuel utilization improvement. Two approaches for mixing of the return air and outside air were examined, and their impact on the system cooling performance and thermal efficiency was demonstrated. The scope of the parametric analyses also encompassed the impact of improving the indirect evaporative cooling effectiveness on the overall cooling system performance.

  16. Experiments on sorption hysteresis of desiccant materials

    SciTech Connect (OSTI)

    Pesaran, A.; Zangrando, F.

    1984-08-01

    Solid desiccant cooling systems take advantage of solar energy for air conditioning. The process involves passing air through a desiccant bed for drying and subsequent evaporative cooling to provide the air conditioning. The desiccant is then regenerated with hot air provided by a gas burner or solar collectors. This performance is limited by the capacity of the desiccant, its sorption properties, and the long-term stability of the desiccant material under cyclic operation conditions. Therefore, we have developed a versatile test facility to measure the sorption properties of candidate solid desiccant materials under dynamic conditions, under different geometrical configurations, and under a broad range of process air stream conditions, characteristic of desiccant dehumidifer operation. We identified a dependence of the sorption processes on air velocity and the test cell aspect ratio and the dynamic hysteresis between adsorption and desorption processes. These experiments were geared to provide data on the dynamic performance of silica gel in a parallel-passage configuration to prepare for tests with a rotary dehumidifier that will be conducted at SERI in late FY 1984. We also recommend improving the accuracy of the isotopic perturbation technique.

  17. STANDARDS CONTROLLING AIR EMISSIONS FOR THE SOIL DESICCATION PILOT TEST

    SciTech Connect (OSTI)

    BENECKE MW

    2010-09-08

    This air emissions document supports implementation of the Treatability Test Plan for Soil Desiccation as outlined in the Deep Vadose Zone Treatability Test Plan for the Hanford Central Plateau (DOE/RL-2007-56). Treatability testing supports evaluation of remedial technologies for technetium-99 (Tc-99) contamination in the vadose zone at sites such as the BC Cribs and Trenches. Soil desiccation has been selected as the first technology for testing because it has been recommended as a promising technology in previous Hanford Site technology evaluations and because testing of soil desiccation will provide useful information to enhance evaluation of other technologies, in particular gas-phase remediation technologies. A soil desiccation pilot test (SDPT) will evaluate the desiccation process (e.g., how the targeted interval is dried) and the long-term performance for mitigation of contaminant transport. The SDPT will dry out a moist zone contaminated by Tc-99 and nitrate that has been detected at Well 299-E13-62 (Borehole C5923). This air emissions document applies to the activities to be completed to conduct the SDPT in the 200-BC-1 operable unit located in the 200 East Area of the Hanford Site. Well 299-E13-62 is planned to be used as an injection well. This well is located between and approximately equidistant from cribs 216-B-16, 216-B-17, 216-B-18. and 216-B-19. Nitrogen gas will be pumped at approximately 300 ft{sup 3}/min into the 299-EI3-62 injection well, located approximately 12 m (39 ft) away from extraction well 299-EI3-65. The soil gas extraction rate will be approximately 150 ft{sup 3}/min. The SDPT will be conducted continuously over a period of approximately six months. The purpose of the test is to evaluate soil desiccation as a potential remedy for protecting groundwater. A conceptual depiction is provided in Figure 1. The soil desiccation process will physically dry, or evaporate, some of the water from the moist zone of interest. As such, it is

  18. Using liquid desiccant as a regenerable filter for capturing and deactivating contaminants

    DOE Patents [OSTI]

    Slayzak, Steven J.; Anderson, Ren S.; Judkoff, Ronald D.; Blake, Daniel M.; Vinzant, Todd B.; Ryan, Joseph P.

    2007-12-11

    A method, and systems for implementing such method, for purifying and conditioning air of weaponized contaminants. The method includes wetting a filter packing media with a salt-based liquid desiccant, such as water with a high concentration of lithium chloride. Air is passed through the wetted filter packing media and the contaminants in are captured with the liquid desiccant while the liquid desiccant dehumidifies the air. The captured contaminants are then deactivated in the liquid desiccant, which may include heating the liquid desiccant. The liquid desiccant is regenerated by applying heat to the liquid desiccant and then removing moisture. The method includes repeating the wetting with the regenerated liquid desiccant which provides a regenerable filtering process that captures and deactivates contaminants on an ongoing basis while also conditioning the air. The method may include filtration effectiveness enhancement by electrostatic or inertial means.

  19. Composite desiccant structure

    DOE Patents [OSTI]

    Fraioli, Anthony V. (Hawthorn Woods, IL); Schertz, William W. (Batavia, IL)

    1987-01-01

    A composite formed of small desiccant particles retained in a dark matrix composed of a porous binder containing a transition metal oxide with pores to provide moisture transport with respect to the particles, and metallic fibers to remove the heat of condensation during dehumidification and provide heat for the removal of moisture during regeneration. The moisture absorbing properties of the composite may be regenerated by exposure of the dark matrix to solar radiation with dehumidification occurring at night.

  20. Composite desiccant structure

    DOE Patents [OSTI]

    Fraioli, A.V.; Schertz, W.W.

    1984-06-06

    This patent discloses a composite formed of small desiccant particles retained in a dark matrix composed of a porous binder containing a transition metal oxide with pores to provide moisture transport with respect to the particles, and metallic fibers to remove the heat of condensation during dehumidification and provide heat for the removal of moisture during regeneration. The moisture absorbing properties of the composite may be regenerated by exposure of the dark matrix to solar radiation with dehumidification occurring at night.

  1. Control methods and systems for indirect evaporative coolers

    SciTech Connect (OSTI)

    Woods, Jason; Kozubal, Erik

    2015-09-22

    A control method for operating an indirect evaporative cooler to control temperature and humidity. The method includes operating an airflow control device to provide supply air at a flow rate to a liquid desiccant dehumidifier. The supply air flows through the dehumidifier and an indirect evaporative cooler prior to exiting an outlet into a space. The method includes operating a pump to provide liquid desiccant to the liquid desiccant dehumidifier and sensing a temperature of an airstream at the outlet of the indirect evaporative cooler. The method includes comparing the temperature of the airstream at the outlet to a setpoint temperature at the outlet and controlling the pump to set the flow rate of the liquid desiccant. The method includes sensing space temperature, comparing the space temperature with a setpoint temperature, and controlling the airflow control device to set the flow rate of the supply air based on the comparison.

  2. Heat transfer of R-134a in single-tube spray evaporation including lubricant effects and enhanced surface results

    SciTech Connect (OSTI)

    Moeykens, S.A.; Huebsch, W.W.; Pate, M.B.

    1995-08-01

    Single-tube spray evaporation experimental tests were conducted in order to evaluate the average wall heat transfer coefficients for seven different commercially available tubes. Liquid film supply rates were held constant in order to evaluate the effects of the enhancement on shell-side heat transfer under similar conditions. Because the spray evaporation phenomenon is so different from pool boiling, both condensation-type and evaporation-type enhanced surfaces were evaluated. A comparison of the results for all of the tubes showed that the enhanced condensation surfaces performed better than the enhanced boiling surfaces. In addition, the 26-fpi surface tested marginally better than the 40-fpi surface. Small concentrations of a polyol-ester lubricant cause a foaming effect that increases the heat transfer performance. This tendency was seen with both 32-cs and 68-cs polyol-ester oils. The 68-cs lubricant was tested at concentrations of 0.0, 0.5, 1.0, 3.0, and 5.0 with the W-40 fpi and Tu-Cii surfaces. Results with this lubricant show the performance continues to increase through the 3% concentration for most of the heat flux range tested At the upper end of the range tested, the 1.0% mass fraction yielded the best performance. The 32-cs lubricant generated trends similar to those of the 68-cs lubricant. Lubricant concentrations of 1.0%, 2.0%, and 3.0% were evaluated with plain, W-40 fpi, and Tu-Cii surfaces. The 2.0% concentration, not the 1.0 %, generated the best performance at the highest heat flux tested. This difference must be attributed to the difference in the lubricant viscosity.

  3. Desiccant contamination research: Report on the desiccant contamination test facility

    SciTech Connect (OSTI)

    Pesaran, A.A.; Bingham, C.E.

    1991-07-01

    The activity in the cooling systems research involves research on high performance dehumidifiers and chillers that can operate efficiently with the variable thermal outputs and delivery temperatures associated with solar collectors. It also includes work on advanced passive cooling techniques. This report describes the work conducted to improve the durability of solid desiccant dehumidifiers by investigating the causes of degradation of desiccant materials from airborne contaminants and thermal cycling. The performance of a dehumidifier strongly depends on the physical properties and durability of the desiccant material. To make durable and reliable dehumidifiers, an understanding is needed of how and to what degree the performance of a dehumidifier is affected by desiccant degradation. This report, an account of work under Cooling Systems Research, documents the efforts to design and fabricate a test facility to investigate desiccant contamination based on industry and academia recommendations. It also discusses the experimental techniques needed for obtaining high-quality data and presents plans for next year. Researchers of the Mechanical and Industrial Technology Division performed this work at the Solar Energy Research Institute in FY 1988 for DOE's Office of Solar Heat Technologies. 7 refs., 19 figs., 1 tab.

  4. Analysis of a solar space cooling system using liquid desiccants

    SciTech Connect (OSTI)

    Gandhidasan, P. )

    1990-12-01

    For tropical countries, solar space cooling is an attractive proposition. Dehumidification of air in hot, humid climates is almost as important as cooling. Removal of moisture from the air is much easier to achieve than cooling the air. The proposed cooling system operates on the ventilation mode. The ambient air is dehumidified using liquid desiccants followed by adiabatic evaporative cooling. The desiccant soon becomes saturated with the water extracted from the air and can be regenerated by using solar energy. For this system, a simple expression is derived in this paper to predict the amount of heat removed from the space to be conditioned in terms of known initial parameters through a simplified vapor pressure correlation and effectiveness of the dehumidifier and the heat exchanger. The effect of ambient air conditions, solution concentration, the cooling water temperature and the effectiveness of the dehumidifier and the heat exchanger on the performance of the cooling system are also discussed in this paper.

  5. Distributed Energy Technology Characterization (Desiccant Technologies...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and system developers with information on appropriate applications, basic system design and sizing principles, and cost and performance of desiccant systems alone and as part of ...

  6. Polymers as Advanced Materials for Desiccant Applications: 1987

    SciTech Connect (OSTI)

    Czanderna, A. W.

    1988-12-01

    This research is concerned with solid materials used as desiccants for desiccant cooling systems that process water vapor in an atmosphere to produce net cooling.

  7. Optimized Bose-Einstein-condensate production in a dipole trap based on a 1070-nm multifrequency laser: Influence of enhanced two-body loss on the evaporation process

    SciTech Connect (OSTI)

    Lauber, T.; Kueber, J.; Wille, O.; Birkl, G.

    2011-10-15

    We present an optimized strategy for the production of tightly confined Bose-Einstein condensates (BEC) of {sup 87}Rb in a crossed dipole trap with direct loading from a magneto-optical trap. The dipole trap is created with light of a multifrequency fiber laser with a center wavelength of 1070 nm. Evaporative cooling is performed by ramping down the laser power only. A comparison of the resulting atom number in an almost pure BEC to the initial atom number and the value for the gain in phase space density per atom lost confirm that this straightforward strategy is very efficient. We observe that the temporal characteristics of evaporation sequence are strongly influenced by power-dependent two-body losses resulting from enhanced optical pumping to the higher-energy hyperfine state. We characterize these losses and compare them to results obtained with a single-frequency laser at 1030 nm.

  8. Desiccant cooling using unglazed transpired solar collectors

    SciTech Connect (OSTI)

    Pesaran, A A; Wipke, K

    1992-05-01

    The use of unglazed solar collectors for desiccant regeneration in a solid desiccant cooling cycle was investigated because these collectors are lower in cost than conventional glazed flat-plate collectors. Using computer models, the performance of a desiccant cooling ventilation cycle integrated with either unglazed transpired collectors or conventional glazed flat-plate collectors was obtained. We found that the thermal performance of the unglazed system was lower than the thermal performance of the glazed system because the unglazed system could not take advantage of the heat of adsorption released during the dehumidification process. For a 3-ton cooling system, although the area required for the unglazed collector was 69% more than that required for the glazed collector, the cost of the unglazed collector array was 44% less than the cost of the glazed collector array. The simple payback period of the unglazed system was half of the payback period of the glazed collector when compared to an equivalent gas-fired system. Although the use of unglazed transpired collectors makes economic sense, some practical considerations may limit their use in desiccant regeneration. 8 refs.

  9. Conductance enhancement due to interface magnons in electron-beam evaporated MgO magnetic tunnel junctions with CoFeB free layer deposited at different pressure

    SciTech Connect (OSTI)

    Guo, P.; Yu, G. Q.; Wei, H. X.; Han, X. F. E-mail: xfhan@aphy.iphy.ac.cn; Li, D. L.; Feng, J. F. E-mail: xfhan@aphy.iphy.ac.cn; Kurt, H.; Chen, J. Y.; Coey, J. M. D.

    2014-10-21

    Electron-beam evaporated MgO-based magnetic tunnel junctions have been fabricated with the CoFeB free layer deposited at Ar pressure from 1 to 4 mTorr, and their tunneling process has been studied as a function of temperature and bias voltage. By changing the growth pressure, the junction dynamic conductance dI/dV, inelastic electron tunneling spectrum d²I/dV², and tunneling magnetoresistance vary with temperature. Moreover, the low-energy magnon cutoff energy E{sub C} derived from the conductance versus temperature curve agrees with interface magnon energy obtained directly from the inelastic electron tunneling spectrum, which demonstrates that interface magnons are involved in the electron tunneling process, opening an additional conductance channel and thus enhancing the total conductance.

  10. Effects of Porous Medium Heterogeneity on Vadose Zone Desiccation: Intermediate-scale Laboratory Experiments and Simulations

    SciTech Connect (OSTI)

    Oostrom, Martinus; Freedman, Vicky L.; Wietsma, Thomas W.; Dane, Jacob H.; Truex, Michael J.

    2012-11-01

    Soil desiccation (drying), involving water evaporation induced by dry gas injection, is a potentially robust vadose zone remediation process to limit contaminant transport through the vadose zone. A series of four intermediate-scale flow cell experiments was conducted in homogeneous and simple layered heterogeneous porous medium systems to investigate the effects of heterogeneity on desiccation of unsaturated porous media. The permeability ratios of porous medium layers ranged from about five to almost two orders of magnitude. The insulated flow cell was equipped with twenty humidity and temperature sensors and a dual-energy gamma system was used to determine water saturations at various times. The multiphase code STOMP was used to simulate the desiccation process. Results show that injected dry gas flowed predominantly in the higher permeability layer and delayed water removal from the lower permeability material. For the configurations tested, water vapor diffusion from the lower to the higher permeability zone was considerable over the duration of the experiments, resulting in much larger relative humidity values of the outgoing air than based on permeability ratios alone. Acceptable numerical matches with the experimental data were obtained when an extension of the saturation-capillary pressure relation below the residual water saturation was used. The agreements between numerical and experimental results suggest that the correct physics are implemented in the simulator and that the thermal and hydraulic properties of the porous media, flow cell wall and insulation materials were properly represented.

  11. Desiccant cooling: State-of-the-art assessment

    SciTech Connect (OSTI)

    Pesaran, A.A.; Penney, T.R.; Czanderna, A.W.

    1992-10-01

    The objectives of this document are to present an overview of the work accomplished to date on desiccant cooling to provide assessment of the state of the art of desiccant cooling technology in the field of desiccant material dehumidifier components, desiccant systems, and models. The report also discusses the factors that affect the widespread acceptance of desiccant cooling technology. This report is organized as follows. First, a basic description and historical overview of desiccant cooling technology is provided. Then, the recent research and development (R&D) program history (focusing on DOE`s funded efforts) is discussed. The status of the technology elements (materials, components, systems) is discussed in detail and a preliminary study on the energy impact of desiccant technology is presented. R&D needs for advancing the technology in the market are identified. The National Renewable Energy Laboratory`s unique desiccant test facilities and their typical outputs are described briefly. Finally, the results of a comprehensive literature search on desiccant cooling are presented in a bibliography. The bibliography contains approximately 900 citations on desiccant cooling.

  12. Desiccant cooling: State-of-the-art assessment

    SciTech Connect (OSTI)

    Pesaran, A.A.; Penney, T.R.; Czanderna, A.W.

    1992-10-01

    The objectives of this document are to present an overview of the work accomplished to date on desiccant cooling to provide assessment of the state of the art of desiccant cooling technology in the field of desiccant material dehumidifier components, desiccant systems, and models. The report also discusses the factors that affect the widespread acceptance of desiccant cooling technology. This report is organized as follows. First, a basic description and historical overview of desiccant cooling technology is provided. Then, the recent research and development (R D) program history (focusing on DOE's funded efforts) is discussed. The status of the technology elements (materials, components, systems) is discussed in detail and a preliminary study on the energy impact of desiccant technology is presented. R D needs for advancing the technology in the market are identified. The National Renewable Energy Laboratory's unique desiccant test facilities and their typical outputs are described briefly. Finally, the results of a comprehensive literature search on desiccant cooling are presented in a bibliography. The bibliography contains approximately 900 citations on desiccant cooling.

  13. Desiccant-based dehumidification system and method

    DOE Patents [OSTI]

    Fischer, John C.

    2004-06-22

    The present invention provides an apparatus for dehumidifying air supplied to an enclosed space by an air conditioning unit. The apparatus includes a partition separating the interior of the housing into a supply portion and a regeneration portion. The supply portion has an inlet for receiving supply air from the air conditioning unit and an outlet for supplying air to the enclosed space. A regeneration fan creates the regeneration air stream. The apparatus includes an active desiccant wheel positioned such that a portion of the wheel extends into the supply portion and a portion of the wheel extends into the regeneration portion, so that the wheel can rotate through the supply air stream and the regeneration air stream to dehumidify the supply air stream. A heater warms the regeneration air stream as necessary to regenerate the desiccant wheel. The invention also comprises a hybrid system that combines air conditioning and dehumidifying components into a single integrated unit.

  14. Distributed Energy Technology Characterization (Desiccant Technologies), January 2004

    Broader source: Energy.gov [DOE]

    Desiccant technology and applications, and designing them for utilization of available thermal energy in a combined heat and power (CHP) system.

  15. Energy-efficient regenerative liquid desiccant drying process

    DOE Patents [OSTI]

    Ko, Suk M.; Grodzka, Philomena G.; McCormick, Paul O.

    1980-01-01

    This invention relates to the use of desiccants in conjunction with an open oop drying cycle and a closed loop drying cycle to reclaim the energy expended in vaporizing moisture in harvested crops. In the closed loop cycle, the drying air is brought into contact with a desiccant after it exits the crop drying bin. Water vapor in the moist air is absorbed by the desiccant, thus reducing the relative humidity of the air. The air is then heated by the used desiccant and returned to the crop bin. During the open loop drying cycle the used desiccant is heated (either fossil or solar energy heat sources may be used) and regenerated at high temperature, driving water vapor from the desiccant. This water vapor is condensed and used to preheat the dilute (wet) desiccant before heat is added from the external source (fossil or solar). The latent heat of vaporization of the moisture removed from the desiccant is reclaimed in this manner. The sensible heat of the regenerated desiccant is utilized in the open loop drying cycle. Also, closed cycle operation implies that no net energy is expended in heating drying air.

  16. Desiccant Cooling Poised for Entry into Mainstream Markets

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Market projections include retrofits of existing buildings as well as new construction. Desiccant cooling systems use materials such as titanium silica gel to remove moisture from ...

  17. Solar-Powered, Liquid-Desiccant Air Conditioner for Low-Electricity Humidity Control: Report and Summary Report

    SciTech Connect (OSTI)

    Dean, J.; Kozubal, E.; Herrmann, L.; Miller, J.; Lowenstein, A.; Barker, G.; Slayzak, S.

    2012-11-01

    The primary objective of this project was to demonstrate the capabilities of a new high-performance, liquid-desiccant dedicated outdoor air system (DOAS) to enhance cooling efficiency and comfort in humid climates while substantially reducing electric peak demand at Tyndall Air Force Base (AFB), which is 12 miles east of Panama City, Florida.

  18. Desiccant-Based Preconditioning Market Analysis

    SciTech Connect (OSTI)

    Fischer, J.

    2001-01-11

    A number of important conclusions can be drawn as a result of this broad, first-phase market evaluation. The more important conclusions include the following: (1) A very significant market opportunity will exist for specialized outdoor air-handling units (SOAHUs) as more construction and renovation projects are designed to incorporate the recommendations made by the ASHRAE 62-1989 standard. Based on this investigation, the total potential market is currently $725,000,000 annually (see Table 6, Sect. 3). Based on the market evaluations completed, it is estimated that approximately $398,000,000 (55%) of this total market could be served by DBC systems if they were made cost-effective through mass production. Approximately $306,000,000 (42%) of the total can be served by a non-regenerated, desiccant-based total recovery approach, based on the information provided by this investigation. Approximately $92,000,000 (13%) can be served by a regenerated desiccant-based cooling approach (see Table 7, Sect. 3). (2) A projection of the market selling price of various desiccant-based SOAHU systems was prepared using prices provided by Trane for central-station, air-handling modules currently manufactured. The wheel-component pricing was added to these components by SEMCO. This resulted in projected pricing for these systems that is significantly less than that currently offered by custom suppliers (see Table 4, Sect. 2). Estimated payback periods for all SOAHU approaches were quite short when compared with conventional over-cooling and reheat systems. Actual paybacks may vary significantly depending on site-specific considerations. (3) In comparing cost vs benefit of each SOAHU approach, it is critical that the total system design be evaluated. For example, the cost premium of a DBC system is very significant when compared to a conventional air handling system, yet the reduced chiller, boiler, cooling tower, and other expense often equals or exceeds this premium, resulting in a

  19. Polymers as advanced materials for desiccant applications, 1988

    SciTech Connect (OSTI)

    Czanderna, A.W.; Neidlinger, H.H.

    1990-09-01

    This report documents work to identify a next-generation, low-cost material with which solar energy or heat from another low-cost energy source can be used for regenerating the water vapor sorption activity of the desiccant. The objective of the work is to determine how the desired sorption performance of advanced desiccant materials can be predicted by understanding the role of the material modifications and material surfaces. The work concentrates on solid materials to be used for desiccant cooling systems and which process water vapor in an atmosphere to produce cooling. The work involved preparing modifications of polystyrene sulfonic acid sodium salt, synthesizing a hydrogel, and evaluating the sorption performances of these and similar commercially available polymeric materials; all materials were studied for their potential application in solid commercial desiccant cooling systems. Background information is also provided on desiccant cooling systems and the role of a desiccant material within such a system, and it includes the use of polymers as desiccant materials. 31 refs., 16 figs., 5 tabs.

  20. Apparatus and method for evaporator defrosting

    DOE Patents [OSTI]

    Mei, Viung C.; Chen, Fang C.; Domitrovic, Ronald E.

    2001-01-01

    An apparatus and method for warm-liquid defrosting of the evaporator of a refrigeration system. The apparatus includes a first refrigerant expansion device that selectively expands refrigerant for cooling the evaporator, a second refrigerant expansion device that selectively expands the refrigerant after the refrigerant has passed through the evaporator, and a defrosting control for the first refrigerant expansion device and second refrigerant expansion device to selectively defrost the evaporator by causing warm refrigerant to flow through the evaporator. The apparatus is alternately embodied with a first refrigerant bypass and/or a second refrigerant bypass for selectively directing refrigerant to respectively bypass the first refrigerant expansion device and the second refrigerant expansion device, and with the defrosting control connected to the first refrigerant bypass and/or the second refrigerant bypass to selectively activate and deactivate the bypasses depending upon the current cycle of the refrigeration system. The apparatus alternately includes an accumulator for accumulating liquid and/or gaseous refrigerant that is then pumped either to a refrigerant receiver or the first refrigerant expansion device for enhanced evaporator defrosting capability. The inventive method of defrosting an evaporator in a refrigeration system includes the steps of compressing refrigerant in a compressor and cooling the refrigerant in the condenser such that the refrigerant is substantially in liquid form, passing the refrigerant substantially in liquid form through the evaporator, and expanding the refrigerant with a refrigerant expansion device after the refrigerant substantially passes through the evaporator.

  1. Measure Guideline: Evaporative Condensers

    SciTech Connect (OSTI)

    German, A; Dakin, B.; Hoeschele, M.

    2012-03-01

    This measure guideline on evaporative condensers provides information on properly designing, installing, and maintaining evaporative condenser systems as well as understanding the benefits, costs, and tradeoffs. This is a prescriptive approach that outlines selection criteria, design and installation procedures, and operation and maintenance best practices.

  2. Advanced Development and Market Penetration of Desiccant-Based Air-Conditioning Systems

    SciTech Connect (OSTI)

    Vineyard, E A; Sand, J R; Linkous, R L; Baskin, E; Mason, D

    1998-01-01

    Desiccant Air Conditioning Systems can be used as alternatives for conventional air conditioning equipment in any commercial or residential building.

  3. Advances in open-cycle solid desiccant cooling

    SciTech Connect (OSTI)

    Penney, T R; Maclaine-cross, I

    1985-05-01

    Of the solar cooling options available open cycle solid desiccant cooling looks very promising. A brief review of the experimental and analytical efforts to date shows that within the last 10 years thermal performance has doubled. Research centers have been developed to explore new materials and geometry options and to improve and validate mathematical models that can be used by design engineers to develop new product lines. Typical results from the Solar Energy Research Institute's (SERI) Desiccant Cooling Research Program are shown. Innovative ideas for new cycles and spinoff benefits provide incentives to continue research in this promising field.

  4. Moving Advanced Desiccant Materials into Mainstream Non-CFC Cooling Products

    SciTech Connect (OSTI)

    Sand, J R; Grossman, G; Rice, C K; Fairchild, P D; Gross, I L

    1994-01-01

    Desiccant air-conditioning systems can be used as alternatives for conventional air-conditioning equipment in any commercial or residential building. Recent breakthroughs in desiccant materials technology and the creation of new markets by Indoor Air Quality issues make desiccant-based air-conditioning equipment practical for many space-conditioning applications.

  5. 242-A evaporator safety analysis report

    SciTech Connect (OSTI)

    CAMPBELL, T.A.

    1999-05-17

    This report provides a revised safety analysis for the upgraded 242-A Evaporator (the Evaporator). This safety analysis report (SAR) supports the operation of the Evaporator following life extension upgrades and other facility and operations upgrades (e.g., Project B-534) that were undertaken to enhance the capabilities of the Evaporator. The Evaporator has been classified as a moderate-hazard facility (Johnson 1990). The information contained in this SAR is based on information provided by 242-A Evaporator Operations, Westinghouse Hanford Company, site maintenance and operations contractor from June 1987 to October 1996, and the existing operating contractor, Waste Management Hanford (WMH) policies. Where appropriate, a discussion address the US Department of Energy (DOE) Orders applicable to a topic is provided. Operation of the facility will be compared to the operating contractor procedures using appropriate audits and appraisals. The following subsections provide introductory and background information, including a general description of the Evaporator facility and process, a description of the scope of this SAR revision,a nd a description of the basic changes made to the original SAR.

  6. Mixed feed evaporator

    DOE Patents [OSTI]

    Vakil, Himanshu B. (Schenectady, NY); Kosky, Philip G. (Ballston Lake, NY)

    1982-01-01

    In the preparation of the gaseous reactant feed to undergo a chemical reaction requiring the presence of steam, the efficiency of overall power utilization is improved by premixing the gaseous reactant feed with water and then heating to evaporate the water in the presence of the gaseous reactant feed, the heating fluid utilized being at a temperature below the boiling point of water at the pressure in the volume where the evaporation occurs.

  7. Measure Guideline: Evaporative Condensers

    SciTech Connect (OSTI)

    German, A.; Dakin, B.; Hoeschele, M.

    2012-03-01

    The purpose of this measure guideline on evaporative condensers is to provide information on a cost-effective solution for energy and demand savings in homes with cooling loads. This is a prescriptive approach that outlines selection criteria, design and installation procedures, and operation and maintenance best practices. This document has been prepared to provide a process for properly designing, installing, and maintaining evaporative condenser systems as well as understanding the benefits, costs, and tradeoffs.

  8. Deep Vadose Zone Treatability Test for the Hanford Central Plateau: Interim Post-Desiccation Monitoring Results

    SciTech Connect (OSTI)

    Truex, Michael J.; Oostrom, Martinus; Strickland, Christopher E.; Johnson, Timothy C.; Johnson, Christian D.; Clayton, Ray E.; Chronister, Glen B.

    2013-09-01

    A field test of desiccation is being conducted as an element of the deep vadose zone treatability test program. Desiccation technology relies on removal of water from a portion of the subsurface such that the resultant low moisture conditions inhibit downward movement of water and dissolved contaminants. Previously, a field test report (Truex et al. 2012a) was prepared describing the active desiccation portion of the test and initial post-desiccation monitoring data. Additional monitoring data have been collected at the field test site during the post-desiccation period and is reported herein along with interpretation with respect to desiccation performance. This is an interim report including about 2 years of post-desiccation monitoring data.

  9. Deep Vadose Zone Treatability Test for the Hanford Central Plateau. Interim Post-Desiccation Monitoring Results, Fiscal Year 2015

    SciTech Connect (OSTI)

    Truex, Michael J.; Strickland, Christopher E.; Oostrom, Martinus; Johnson, Christian D.; Tartakovsky, Guzel D.; Johnson, Timothy C.; Clayton, Ray E.; Chronister, Glen B.

    2015-09-01

    A field test of desiccation is being conducted as an element of the Deep Vadose Zone Treatability Test Program. The active desiccation portion of the test has been completed. Monitoring data have been collected at the field test site during the post-desiccation period and are reported herein. This is an interim data summary report that includes about 4 years of post-desiccation monitoring data. The DOE field test plan proscribes a total of 5 years of post-desiccation monitoring.

  10. Enhancement of lanthanide evaporation by complexation: Dysprosium tri-iodide mixed with indium iodide and thulium tri-iodide mixed with thallium iodide

    SciTech Connect (OSTI)

    Curry, J. J.; Henins, A.; Hardis, J. E.; Estupin, E. G.; Lapatovich, W. P.; Shastri, S. D.

    2013-09-28

    The vapors in equilibrium with condensates of DyI{sub 3}, DyI{sub 3}/InI, TmI{sub 3}, and TmI{sub 3}/TlI were observed over the temperature range from 900 K to 1400 K using x-ray induced fluorescence. The total densities of each element (Dy, Tm, In, Tl, and I) in the vapor, summed over all atomic and molecular species, were determined. Dramatic enhancements in the total vapor densities of Dy and Tm were observed in the vapors over DyI{sub 3}/InI and TmI{sub 3}/TlI as compared to the vapors over pure DyI{sub 3} and pure TmI{sub 3}, respectively. An enhancement factor exceeding 10 was observed for Dy at T? 1020 K, decreasing to 0 at T? 1250 K. An enhancement factor exceeding 20 was observed for Tm at T? 1040 K, decreasing to 0 at T? 1300 K. Such enhancements are expected from the formation of the vapor-phase hetero-complexes DyInI{sub 4} and TmTlI{sub 4}. Numerical simulations of the thermo-chemical equilibrium suggest the importance of additional complexes in liquid phases. A description of the measurement technique is given. Improvements in the absolute calibration lead to an approximately 40% correction to previously reported preliminary results [J. J. Curry et al., Chem. Phys. Lett. 507, 52 (2011); Appl. Phys. Lett. 100, 083505 (2012)].

  11. Hot air drum evaporator

    DOE Patents [OSTI]

    Black, Roger L.

    1981-01-01

    An evaporation system for aqueous radioactive waste uses standard 30 and 55 gallon drums. Waste solutions form cascading water sprays as they pass over a number of trays arranged in a vertical stack within a drum. Hot dry air is circulated radially of the drum through the water sprays thereby removing water vapor. The system is encased in concrete to prevent exposure to radioactivity. The use of standard 30 and 55 gallon drums permits an inexpensive compact modular design that is readily disposable, thus eliminating maintenance and radiation build-up problems encountered with conventional evaporation systems.

  12. Method and composition for molding low density desiccant syntactic foam articles

    DOE Patents [OSTI]

    Lula, James W.; Schicker, James R.

    1984-01-01

    A method and a composition are provided for molding low density desiccant syntactic foam articles. A low density molded desiccant article may be made as a syntactic foam by blending a thermosetting resin, microspheres and molecular sieve desiccant powder, molding and curing. Such articles have densities of 0.2-0.9 g/cc, moisture capacities of 1-12% by weight, and can serve as light weight structural supports.

  13. Vertical counterflow evaporative cooler

    DOE Patents [OSTI]

    Bourne, Richard C.; Lee, Brian Eric; Callaway, Duncan

    2005-01-25

    An evaporative heat exchanger having parallel plates that define alternating dry and wet passages. A water reservoir is located below the plates and is connected to a water distribution system. Water from the water distribution system flows through the wet passages and wets the surfaces of the plates that form the wet passages. Air flows through the dry passages, mixes with air below the plates, and flows into the wet passages before exiting through the top of the wet passages.

  14. Design of a test facility for gas-fired desiccant-based air conditioning systems

    SciTech Connect (OSTI)

    Jalalzadeh-Azar, A.A.; Steele, W.G.; Hodge, B.K.

    1996-12-31

    The design of a facility for testing desiccant-based air conditioning systems is presented. The determination of the performance parameters of desiccant systems is discussed including moisture removal capacity, latent and total cooling capacities, and efficiency indexes. The appropriate procedures and key measurements for determining these parameters are identified using uncertainty analysis.

  15. Evaporative Coolers | Department of Energy

    Office of Environmental Management (EM)

    Home Cooling Systems Air Conditioning Evaporative Coolers Fans Radiant Cooling Ventilation for Cooling Whole-House Fans Home Heating Systems Heat Pump Systems Water Heating...

  16. Evaporative Coolers | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Heat & Cool » Home Cooling Systems » Evaporative Coolers Evaporative Coolers Evaporative Coolers, sometimes called swamp coolers, is another way to cool air in warm climates with low humidity. | Photo courtesy of <a href="http://www.flickr.com/people/free-stock/">Public Domain Photos</a>. Evaporative Coolers, sometimes called swamp coolers, is another way to cool air in warm climates with low humidity. | Photo courtesy of Public Domain Photos. In low-humidity areas,

  17. Method and apparatus for extracting water from air using a desiccant

    DOE Patents [OSTI]

    Spletzer, Barry L.; Callow, Diane Schafer

    2003-01-01

    The present invention provides a method and apparatus for extracting liquid water from moist air using minimal energy input. The method can be considered as four phases: (1) adsorbing water from air into a desiccant, (2) isolating the water-laden desiccant from the air source, (3) desorbing water as vapor from the desiccant into a chamber, and (4) isolating the desiccant from the chamber, and compressing the vapor in the chamber to form liquid condensate. The liquid condensate can be removed for use. Careful design of the dead volumes and pressure balances can minimize the energy required. The dried air can be exchanged for fresh moist air and the process repeated. An apparatus comprises a first chamber in fluid communication with a desiccant, and having ports to intake moist air and exhaust dried air. The apparatus also comprises a second chamber in fluid communication with the desiccant. The second chamber allows variable internal pressure, and has a port for removal of liquid condensate. Each chamber can be configured to be isolated or in communication with the desiccant. The first chamber can be configured to be isolated or in communication with a course of moist air. Various arrangements of valves, pistons, and chambers are described.

  18. Evaporative Cooling Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Evaporative Cooling Basics Evaporative Cooling Basics August 16, 2013 - 1:53pm Addthis Evaporative cooling uses evaporated water to naturally and energy-efficiently cool. An illustration of an evaporative cooler. In this example of an evaporative cooler, a small motor (top) drives a large fan (center) which blows air out the bottom and into your home. The fan sucks air in through the louvers around the box, which are covered with water-saturated absorbent material. How Evaporative Coolers Work

  19. Laboratory and Modeling Evaluations in Support of Field Testing for Desiccation at the Hanford Site

    SciTech Connect (OSTI)

    Truex, Michael J.; Oostrom, Martinus; Freedman, Vicky L.; Strickland, Christopher E.; Wietsma, Thomas W.; Tartakovsky, Guzel D.; Ward, Anderson L.

    2011-02-23

    The Deep Vadose Zone Treatability Test Plan for the Hanford Central Plateau includes testing of the desiccation technology as a potential technology to be used in conjunction with surface infiltration control to limit the flux of technetium and other contaminants in the vadose zone to the groundwater. Laboratory and modeling efforts were conducted to investigate technical uncertainties related to the desiccation process and its impact on contaminant transport. This information is intended to support planning, operation, and interpretation of a field test for desiccation in the Hanford Central Plateau.

  20. Vacuum flash evaporated polymer composites

    DOE Patents [OSTI]

    Affinito, John D.; Gross, Mark E.

    1997-01-01

    A method for fabrication of polymer composite layers in a vacuum is disclosed. More specifically, the method of dissolving salts in a monomer solution, vacuum flash evaporating the solution, condensing the flash evaporated solution as a liquid film, and forming the condensed liquid film into a polymer composite layer on a substrate is disclosed.

  1. Vacuum flash evaporated polymer composites

    DOE Patents [OSTI]

    Affinito, J.D.; Gross, M.E.

    1997-10-28

    A method for fabrication of polymer composite layers in a vacuum is disclosed. More specifically, the method of dissolving salts in a monomer solution, vacuum flash evaporating the solution, condensing the flash evaporated solution as a liquid film, and forming the condensed liquid film into a polymer composite layer on a substrate is disclosed.

  2. Experimental and Numerical Investigations of Soil Desiccation for Vadose Zone Remediation: Report for Fiscal Year 2007

    SciTech Connect (OSTI)

    Ward, Andy L.; Oostrom, Mart; Bacon, Diana H.

    2008-02-04

    Apart from source excavation, the options available for the remediation of vadose zone metal and radionuclide contaminants beyond the practical excavation depth (0 to 15 m) are quite limited. Of the available technologies, very few are applicable to the deep vadose zone with the top-ranked candidate being soil desiccation. An expert panel review of the work on infiltration control and supplemental technologies identified a number of knowledge gaps that would need to be overcome before soil desiccation could be deployed. The report documents some of the research conducted in the last year to fill these knowledge gaps. This work included 1) performing intermediate-scale laboratory flow cell experiments to demonstrate the desiccation process, 2) implementing a scalable version of Subsurface Transport Over Multiple PhasesWater-Air-Energy (STOMP-WAE), and 3) performing numerical experiments to identify the factors controlling the performance of a desiccation system.

  3. Deep Vadose Zone Treatability Test for the Hanford Central Plateau: Soil Desiccation Pilot Test Results

    SciTech Connect (OSTI)

    Truex, Michael J.; Oostrom, Martinus; Strickland, Christopher E.; Johnson, Timothy C.; Freedman, Vicky L.; Johnson, Christian D.; Greenwood, William J.; Ward, Anderson L.; Clayton, Ray E.; Lindberg, Michael J.; Peterson, John E.; Hubbard, Susan; Chronister, Glen B.; Benecke, Mark W.

    2012-05-01

    This report describes results of a pilot test of soil desiccation conducted as part of the Deep Vadose Zone Treatability Test program. The report is written in CERCLA treatabilty test report format.

  4. Low-Flow Liquid Desiccant Air Conditioning: General Guidance and Site Considerations

    SciTech Connect (OSTI)

    Kozubal, E.; Herrmann, L.; Deru, M.; Clark, J.

    2014-09-01

    Dehumidification or latent cooling in buildings is an area of growing interest that has been identified as needing more research and improved technologies for higher performance. Heating, ventilating, and air-conditioning (HVAC) systems typically expend excessive energy by using overcool-and-reheat strategies to dehumidify buildings. These systems first overcool ventilation air to remove moisture and then reheat the air to meet comfort requirements. Another common strategy incorporates solid desiccant rotors that remove moisture from the air more efficiently; however, these systems increase fan energy consumption because of the high airside pressure drop of solid desiccant rotors and can add heat of absorption to the ventilation air. Alternatively, liquid desiccant air-conditioning (LDAC) technology provides an innovative dehumidification solution that: (1) eliminates the need for overcooling and reheating from traditional cooling systems; and (2) avoids the increased fan energy and air heating from solid desiccant rotor systems.

  5. Method and composition for molding low-density desiccant syntactic-foam articles

    DOE Patents [OSTI]

    Not Available

    1981-12-07

    These and other objects of the invention are achieved by a process for molding to size a desiccant syntactic foam article having a density of 0.2 to 0.9 g/cc and a moisture capacity of 1 to 12% by weight, comprising the steps of: charging a mold with a powdery mixture of an activated desiccant, microspheres and a thermosetting resin, the amount of the desiccant being sufficient to provide the required moisture capacity, and the amounts of the microspheres and resin being such that the microspheres/desiccant volume fraction exceeds the packing factor by an amount sufficient to substantially avoid shrinkage without causing excessively high molding pressures; covering the mold and heating the covered mold to a temperature and for an amount of time sufficient to melt the resin; and tightly closing the mold and heating the closed mold to a temperature and for an amount of time sufficient to cure the resin, and removing the resultant desiccant syntactic foam article from the mold. In a composition of matter aspect, the present invention provides desiccant syntactic foam articles, and a composition of matter for use in molding the same.

  6. Low-Flow Liquid Desiccant Air-Conditioning: Demonstrated Performance and Cost Implications

    SciTech Connect (OSTI)

    Kozubal, E.; Herrmann, L.; Deru, M.; Clark, J.; Lowenstein, A.

    2014-09-01

    Cooling loads must be dramatically reduced when designing net-zero energy buildings or other highly efficient facilities. Advances in this area have focused primarily on reducing a building's sensible cooling loads by improving the envelope, integrating properly sized daylighting systems, adding exterior solar shading devices, and reducing internal heat gains. As sensible loads decrease, however, latent loads remain relatively constant, and thus become a greater fraction of the overall cooling requirement in highly efficient building designs, particularly in humid climates. This shift toward latent cooling is a challenge for heating, ventilation, and air-conditioning (HVAC) systems. Traditional systems typically dehumidify by first overcooling air below the dew-point temperature and then reheating it to an appropriate supply temperature, which requires an excessive amount of energy. Another dehumidification strategy incorporates solid desiccant rotors that remove water from air more efficiently; however, these systems are large and increase fan energy consumption due to the increased airside pressure drop of solid desiccant rotors. A third dehumidification strategy involves high flow liquid desiccant systems. These systems require a high maintenance separator to protect the air distribution system from corrosive desiccant droplet carryover and so are more commonly used in industrial applications and rarely in commercial buildings. Both solid desiccant systems and most high-flow liquid desiccant systems (if not internally cooled) add sensible energy which must later be removed to the air stream during dehumidification, through the release of sensible heat during the sorption process.

  7. A desiccant/steam-injected gas-turbine industrial cogeneration system

    SciTech Connect (OSTI)

    Jody, B.J.; Daniels, E.J.; Karvelas, D.E.; Teotia, A.P.S.

    1993-12-31

    An integrated desiccant/steam-injected gas-turbine system was evaluated as an industrial cogenerator for the production of electricity and dry, heated air for product drying applications. The desiccant can be regenerated using the heated, compressed air leaving the compressor. The wet stream leaves the regenerator at a lower temperature than when it entered the desiccant regenerator, but with little loss of energy. The wet stream returns to the combustion chamber of the gas-turbine system after preheating by exchanging heat with the turbine exhaust strewn. Therefore, the desiccant is regenerated virtually energy-free. In the proposed system, the moisture-laden air exiting the desiccant is introduced into the combustion chamber of the gas-turbine power system. This paper discusses various possible design configurations, the impact of increased moisture content on the combustion process, the pressure drop across the desiccant regenerator, and the impact of these factors on the overall performance of the integrated system. A preliminary economic analysis including estimated potential energy savings when the system is used in several drying applications, and equipment and operating costs are also presented.

  8. A desiccant/steam-injected gas-turbine industrial cogeneration system

    SciTech Connect (OSTI)

    Jody, B.J.; Daniels, E.J.; Karvelas, D.E.; Teotia, A.P.S.

    1993-01-01

    An integrated desiccant/steam-injected gas-turbine system was evaluated as an industrial cogenerator for the production of electricity and dry, heated air for product drying applications. The desiccant can be regenerated using the heated, compressed air leaving the compressor. The wet stream leaves the regenerator at a lower temperature than when it entered the desiccant regenerator, but with little loss of energy. The wet stream returns to the combustion chamber of the gas-turbine system after preheating by exchanging heat with the turbine exhaust strewn. Therefore, the desiccant is regenerated virtually energy-free. In the proposed system, the moisture-laden air exiting the desiccant is introduced into the combustion chamber of the gas-turbine power system. This paper discusses various possible design configurations, the impact of increased moisture content on the combustion process, the pressure drop across the desiccant regenerator, and the impact of these factors on the overall performance of the integrated system. A preliminary economic analysis including estimated potential energy savings when the system is used in several drying applications, and equipment and operating costs are also presented.

  9. Superhydrophobic Coating for Evaporative Purification and Minerals...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Potable water is becoming an increasingly scarce resource. Evaporative desalination is one ... Because of this, evaporative desalination has all but been abandoned commercially in the ...

  10. Dual manifold heat pipe evaporator

    DOE Patents [OSTI]

    Adkins, Douglas R. (Albuquerque, NM); Rawlinson, K. Scott (Albuquerque, NM)

    1994-01-01

    An improved evaporator section for a dual manifold heat pipe. Both the upper and lower manifolds can have surfaces exposed to the heat source which evaporate the working fluid. The tubes in the tube bank between the manifolds have openings in their lower extensions into the lower manifold to provide for the transport of evaporated working fluid from the lower manifold into the tubes and from there on into the upper manifold and on to the condenser portion of the heat pipe. A wick structure lining the inner walls of the evaporator tubes extends into both the upper and lower manifolds. At least some of the tubes also have overflow tubes contained within them to carry condensed working fluid from the upper manifold to pass to the lower without spilling down the inside walls of the tubes.

  11. Evaporative Cooling | Open Energy Information

    Open Energy Info (EERE)

    By utilizing both water and air one can reduce the amount of water required for a power plant as well as reduce the footprint required for an air cooling system. Evaporative...

  12. 242-A Evaporator - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    began operating in 1977 to reduce the volume of waste stored in Hanford's underground tanks. The 242-A Evaporator is the only operating nuclear processing facility at Hanford. It...

  13. Dual manifold heat pipe evaporator

    DOE Patents [OSTI]

    Adkins, D.R.; Rawlinson, K.S.

    1994-01-04

    An improved evaporator section is described for a dual manifold heat pipe. Both the upper and lower manifolds can have surfaces exposed to the heat source which evaporate the working fluid. The tubes in the tube bank between the manifolds have openings in their lower extensions into the lower manifold to provide for the transport of evaporated working fluid from the lower manifold into the tubes and from there on into the upper manifold and on to the condenser portion of the heat pipe. A wick structure lining the inner walls of the evaporator tubes extends into both the upper and lower manifolds. At least some of the tubes also have overflow tubes contained within them to carry condensed working fluid from the upper manifold to pass to the lower without spilling down the inside walls of the tubes. 1 figure.

  14. A shortcut for designing evaporators

    SciTech Connect (OSTI)

    Durand, M.I.A.A.

    1996-01-01

    Multiple-effect evaporation is commonly used in chemical process plants to minimize energy consumption and cooling water. In this system, several evaporators are connected by piping so that vapor passes from one effect to the next in series. Thus, the heat supplied to the first evaporator is used to vaporize water in the first effect; this vapor, in turn, passes to the next effect, until, finally, the heat in the vapor supplied to the last effect passes on to the condenser. The net result of this arrangement is the multiple reuse of heat, and a marked increase in the economic of the evaporation system. In addition to savings in steam use, there is also a saving in condenser cooling water as the number of effects increases. On the other hand, an increase in the number of effects represents an increase in capital costs since more heat transfer area is required in the evaporator system. Thus, the choice of the proper--that is, optimum--number of effects is dictated by an economic balance between the savings in steam and cooling water versus that of the additional investment costs. The paper describes the basic equations and an economic analysis of evaporator systems, and illustrates the method with an example.

  15. Evaporation of multicomponent drop arrays

    SciTech Connect (OSTI)

    Annamalai, K.; Ryan, W.; Chandra, S. (Texas A M Univ., College Station, TX (United States))

    1993-08-01

    The present paper deals with the evaporation of multicomponent fuel droplets in an array using the recently developed point source method (PSM). First, the quasisteady (QS) evaporation of an isolated, multicomponent droplet is briefly analyzed. The resultant governing equations, along with Raoult's law and the Cox-Antoine relation, constitute the set of equations needed to arrive at the solutions for: (1) the droplet surface temperature, (2) the evaporation rate of each species, and (3) the vapor mass fraction of each species at the droplet surface. The PSM, which treats the droplet as a point mass source and heat sink, is then adopted to obtain an analytic expression for the evaporation rate of a multicomponent droplet in an array of liquid droplets. Defining the correction factor ([eta]) as a ratio of the evaporation of a drop in an array to the evaporation rate of a similar isolated multicomponent drop, an expression for the correction factor is obtained. The results of the point source method (PSM) are then compared with those obtained elsewhere for a three-drop array that uses the method of images (MOI). Excellent agreement is obtained. The treatment is then extended to a binary drop array to study the effect of interdrop spacing on vaporization. 20 refs., 11 figs., 4 tabs.

  16. Method and apparatus for flash evaporation of liquids

    DOE Patents [OSTI]

    Bharathan, Desikan

    1984-01-01

    A vertical tube flash evaporator for introducing a superheated liquid into a flash evaporation chamber includes a vertical inlet tube with a flared diffuser portion at its upper outlet end. A plurality of annular screens are positioned in axially spaced-apart relation to each other around the periphery of the vertical tube and below the diffuser portion thereof. The screens are preferably curved upward in a cup-shaped configuration. These flash evaporators are shown in an ocean thermal energy conversion unit designed for generating electric power from differential temperature gradients in ocean water. The method of use of the flash evaporators of this invention includes flowing liquid upwardly through the vertical tube into the diffuser where initial expansion and boiling occurs quite violently and explosively. Unvaporized liquid sheets and drops collide with each other to enhance surface renewal and evaporation properties, and liquid flowing over the outlet end of the diffuser falls onto the curved screens for further surface renewal and evaporation.

  17. Method and apparatus for flash evaporation of liquids

    DOE Patents [OSTI]

    Bharathan, D.

    1984-01-01

    A vertical tube flash evaporator for introducing a super-heated liquid into a flash evaporation chamber includes a vertical inlet tube with a flared diffuser portion at its upper outlet end. A plurality of annular screens are positioned in axially spaced-apart relation to each other around the periphery of the vertical tube and below the diffuser portion thereof. The screens are preferably curved upward in a cup-shaped configuration. These flash evaporators are shown in an ocean thermal energy conversion unit designed for generating electric power from differential temperature gradients in ocean water. The method of use of the flash evaporators of this invention includes flowing liquid upwardly through the vertical tube into the diffuser where initial expansion and boiling occurs quite violently and explosively. Unvaporized liquid sheets and drops collide with each other to enhance surface renewal and evaporation properties, and liquid flowing over the outlet end of the diffuser falls onto the curved screens for further surface renewal and evaporation.

  18. Performance predictions of silica-gel desiccant dehumidifiers. Technical report No. 3

    SciTech Connect (OSTI)

    Mathiprakasam, B.; Lavan, Z.

    1980-01-01

    The analysis of a cross-cooled desiccant dehumidifier using silica gel in the form of sheets is described. This unit is the principal component of solar powered desiccant air conditioning system. The mathematical model has first been formulated describing the dynamics of the dehumidifier. The model leads to a system of nonlinear coupled heat and mass transfer equations for the sorption processes and linear heat transfer equations for the purging processes. The model accounts for the gas film resistance and for the moisture diffusion in the desiccant. The governing equations are solved by a finite difference scheme to obtain periodic steady state solutions. The accuracy of the theoretical predictions is ascertained by comparing them with the experimental results. The performance of the dehumidifier, for a chosen set of initial conditions and dehumidifier parameters, has also been given.

  19. Effects of temperature on desiccant catalysis of refrigerant and lubricant decomposition. Final report

    SciTech Connect (OSTI)

    Rohatgi, N.D.T.

    1998-06-01

    Accelerated aging at high temperatures (149 C) for short aging times (28 days) is effective in screening the compatibility of different materials in refrigeration systems. However, in actual applications temperatures are usually lower and operating times much longer. Therefore plots to allow for interpolation or extrapolation of experimental data to actual operating conditions are needed. In the current study, aging of refrigerant/lubricant/desiccant/metal systems was conducted at five different temperatures, and for each temperature at four different aging times. The data collected from this study provided plots relating refrigerant or lubricant decomposition to aging time, aging temperature, and type of desiccant, which can be used for interpolation or extrapolation.

  20. Upward-facing Lithium Flash Evaporator for NSTX-U

    SciTech Connect (OSTI)

    Roquemore, A. L.

    2013-07-09

    NSTX plasma performance has been significantly enhanced by lithium conditioning [1]. To date, the lower divertor and passive plates have been conditioned by downward facing lithium evaporators (LITER) as appropriate for lower null plasmas. The higher power operation expected from NSTX-U requires double null plasma operation in order to distribute the heat flux between the upper and lower divertors making it desirable to coat the upper divertor region with Li as well. An upward aiming LITER (U-LITER) is presently under development and will be inserted into NSTX-U using a horizontal probe drive located in a 6" upper midplane port. In the retracted position the evaporator will be loaded with up to 300 mg of Li granules utilizing one of the calibrated NSTX Li powder droppers[2]. The evaporator will then be inserted into the vessel in a location within the shadow of the RF limiters and will remain in the vessel during the discharge. About 10 seconds before a discharge, it will be rapidly heated and the lithium completely evaporated onto the upper divertor, thus avoiding the complication of a shutter that prevents evaporation during the shot when the diagnostic shutters are open. The minimal time interval between the evaporation and the start of the discharge will avoid the passivation of the lithium by residual gases and enable the study of the conditioning effects of un-passivated Li surfaces [3]. Two methods are being investigated to accomplish the rapid (few second) heating of the lithium. A resistive method relies on passing a large current through a Li filled crucible. A second method requires using a 3 kW e-beam gun to heat the Li. In this paper the evaporator systems will be described and the pros and cons of each heating method will be discussed.

  1. Sensor and numerical simulator evaluation for porous medium desiccation and rewetting at the intermediate laboratory scale

    SciTech Connect (OSTI)

    Oostrom, Martinus; Wietsma, Thomas W.; Strickland, Christopher E.; Freedman, Vicky L.; Truex, Michael J.

    2012-02-01

    Soil desiccation, in conjunction with surface infiltration control, is considered at the Hanford Site as a potential technology to limit the flux of technetium and other contaminants in the vadose zone to the groundwater. An intermediate-scale experiment was conducted to test the response of a series of instruments to desiccation and subsequent rewetting of porous media. The instruments include thermistors, thermocouple psychrometers, dual-probe heat pulse sensors, heat dissipation units, and humidity probes. The experiment was simulated with the multifluid flow simulator STOMP, using independently obtained hydraulic and thermal porous medium properties. All instrument types used for this experiment were able to indicate when the desiccation front passed a certain location. In most cases the changes were sharp, indicating rapid changes in moisture content, water potential, or humidity. However, a response to the changing conditions was recorded only when the drying front was very close to a sensor. Of the tested instruments, only the heat dissipation unit and humidity probes were able to detect rewetting. The numerical simulation results reasonably match the experimental data, indicating that the simulator captures the pertinent gas flow and transport processes related to desiccation and rewetting and may be useful in the design and analysis of field tests.

  2. Iodine retention during evaporative volume reduction

    DOE Patents [OSTI]

    Godbee, H.W.; Cathers, G.I.; Blanco, R.E.

    1975-11-18

    An improved method for retaining radioactive iodine in aqueous waste solutions during volume reduction is disclosed. The method applies to evaporative volume reduction processes whereby the decontaminated (evaporated) water can be returned safely to the environment. The method generally comprises isotopically diluting the waste solution with a nonradioactive iodide and maintaining the solution at a high pH during evaporation.

  3. Evaporative oxidation treatability test report

    SciTech Connect (OSTI)

    1995-04-01

    In 1992, Congress passed the Federal Facilities Compliance Act that requires the U.S. Department of Energy (DOE) to treat and dispose of its mixed waste in accordance with the Resource Conservation and Recovery Act (RCRA) land disposal restrictions (LDRs). In response to the need for mixed-waste treatment capacity where available off-site commercial treatment facilities do not exist or cannot be used, the DOE Albuquerque Operations Office (DOE-AL) organized a Treatment Selection Team to match mixed wastes with treatment options and develop a strategy for treatment of its mixed wastes. DOE-AL manages operations at nine sites with mixed-waste inventories. The Treatment Selection Team determined a need to develop mobile treatment capacity to treat wastes at the sites where the wastes are generated. Treatment processes used for mixed waste not only must address the hazardous component (i.e., meet LDRs) but also must contain the radioactive component in a form that allows final disposal while protecting workers, the public, and the environment. On the basis of recommendations of the Treatment Selection Team, DOE-AL assigned projects to the sites to bring mixed-waste treatment capacity on-line. The three technologies assigned to the DOE Grand Junction Projects Office (GJPO) are evaporative oxidation, thermal desorption, and treated wastewater evaporation. Rust Geotech, the DOE-GJPO prime contractor, was assigned to design and fabricate mobile treatment units (MTUs) for these three technologies and to deliver the MTUs to selected DOE-AL sites. To conduct treatability tests at the GJPO, Rust leased a pilot-scale evaporative oxidation unit from the Clemson Technical Center (CTC), Anderson, South Carolina. The purpose of this report is to document the findings and results of tests performed using this equipment.

  4. Moving Advanced Desiccant Materials into Mainstream Non-CFC Cooling Products

    SciTech Connect (OSTI)

    Sand, J. R.; Grossman, T.; Rice, C. K.; Fairchild, P. D.; Gross, I. L.

    2004-12-30

    Desiccant dehumidification technology is emerging as a technically viable alternative for comfort conditioning in many commercial and institutional buildings. Attempts to improve the indoor air quality of buildings has resulted in increasingly stringent guidelines for occupant outdoor air ventilation rates. Additionally, revised building heating, ventilating, and air-conditioning (HVAC) design criteria based on regional peak dew point data highlight the important of the latent (moisture removal) building load relative to the sensible (temperature) building load.

  5. Low-Flow Liquid Desiccant Air-Conditioning: Demonstrated Performance and Cost Implications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Flow Liquid Desiccant Air-Conditioning: Demonstrated Performance and Cost Implications Eric Kozubal, Lesley Herrmann, and Michael Deru National Renewable Energy Laboratory Jordan Clark University of Texas, Austin Andy Lowenstein AIL Research Technical Report NREL/TP-5500-60695 September 2014 NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency & Renewable Energy, operated by the Alliance for Sustainable Energy, LLC. National Renewable Energy Laboratory

  6. Portable brine evaporator unit, process, and system

    DOE Patents [OSTI]

    Hart, Paul John; Miller, Bruce G.; Wincek, Ronald T.; Decker, Glenn E.; Johnson, David K.

    2009-04-07

    The present invention discloses a comprehensive, efficient, and cost effective portable evaporator unit, method, and system for the treatment of brine. The evaporator unit, method, and system require a pretreatment process that removes heavy metals, crude oil, and other contaminates in preparation for the evaporator unit. The pretreatment and the evaporator unit, method, and system process metals and brine at the site where they are generated (the well site). Thus, saving significant money to producers who can avoid present and future increases in transportation costs.

  7. Dew-Point Evaporative Comfort Cooling (Presentation)

    SciTech Connect (OSTI)

    Dean, J.

    2012-10-01

    Presentation on innovative indirect evaporative cooling technology developed by Coolerado Corporation given at the Rocky Mountain Chapter ASHRAE conference in April 2012.

  8. ARM - Lesson Plans: Sunlight and Evaporation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Objective The objective is to demonstrate that the energy from sunlight can evaporate ... Different wave lengths have different amount of energy. The bulk of the sun's energy ...

  9. High Efficiency Liquid-Desiccant Regenerator for Air Conditioning and Industrial Drying

    SciTech Connect (OSTI)

    Andrew Lowenstein

    2005-12-19

    Over 2 quads of fossil fuels are used each year for moisture removal. This includes industrial and agricultural processes where feedstocks and final products must be dried, as well as comfort conditioning of indoor spaces where the control of humidity is essential to maintaining healthy, productive and comfortable working conditions. Desiccants, materials that have a high affinity for water vapor, can greatly reduce energy use for both drying and dehumidification. An opportunity exists to greatly improve the competitiveness of advanced liquid-desiccant systems by increasing the efficiency of their regenerators. It is common practice within the chemical process industry to use multiple stage boilers to improve the efficiency of thermal separation processes. The energy needed to regenerate a liquid desiccant, which is a thermal separation process, can also be reduced by using a multiple stage boiler. In this project, a two-stage regenerator was developed in which the first stage is a boiler and the second stage is a scavenging-air regenerator. The only energy input to this regenerator is the natural gas that fires the boiler. The steam produced in the boiler provides the thermal energy to run the second-stage scavenging-air regenerator. This two-stage regenerator is referred to as a 1?-effect regenerator. A model of the high-temperature stage of a 1?-effect regenerator for liquid desiccants was designed, built and successfully tested. At nominal operating conditions (i.e., 2.35 gpm of 36% lithium chloride solution, 307,000 Btu/h firing rate), the boiler removed 153 lb/h of water from the desiccant at a gas-based efficiency of 52.9 % (which corresponds to a COP of 0.95 when a scavenging-air regenerator is added). The steam leaving the boiler, when condensed, had a solids concentration of less than 10 ppm. This low level of solids in the condensate places an upper bound of about 6 lb per year for desiccant loss from the regenerator. This low loss will not create

  10. Design, Installation, and Field Verification of Integrated Active Desiccant Hybrid Rooftop Systems Combined with a Natural Gas Driven Cogeneration Package, 2008

    Office of Energy Efficiency and Renewable Energy (EERE)

    Report summary of a research/demonstration project involving a custom 230 kW cogeneration package with four integrated active desiccant rooftop (IADR) systems

  11. Tank 26 Evaporator Feed Pump Transfer Analysis

    SciTech Connect (OSTI)

    Tamburello, David; Dimenna, Richard; Lee, Si

    2009-02-11

    The transfer of liquid salt solution from Tank 26 to an evaporator is to be accomplished by activating the evaporator feed pump, located approximately 72 inches above the sludge layer, while simultaneously turning on the downcomer. Previously, activation of the evaporator feed pump was an isolated event without any other components running at the same time. An analysis of the dissolved solution transfer has been performed using computational fluid dynamics methods to determine the amount of entrained sludge solids pumped out of the tank to the evaporator with the downcomer turned on. The analysis results showed that, for the maximum and minimum supernate levels in Tank 26 (252.5 and 72 inches above the sludge layer, respectively), the evaporator feed pump will entrain between 0.03 and 0.1 wt% sludge undissolved solids weight fraction into the eductor, respectively, and therefore are an order of magnitude less than the 1.0 wt% undissolved solids loading criteria to feed the evaporator. Lower tank liquid levels, with respect to the sludge layer, result in higher amounts of sludge entrainment due to the increased velocity of the plunging jets from the downcomer and evaporator feed pump bypass as well as decreased dissipation depth. Revision 1 clarifies the analysis presented in Revision 0 and corrects a mathematical error in the calculations for Table 4.1 in Revision 0. However, the conclusions and recommendations of the analysis do not change for Revision 1.

  12. 241-A evaporator flowsheet users manual

    SciTech Connect (OSTI)

    Larrick, A.P.

    1994-12-22

    This supporting document presents a description of the 242-A Evaporator flowsheet. Material balances are calculated for feed, slurry, and effluent streams based on input data for the feed stream.

  13. TANK 32 EVAPORATOR FEED PUMP TRANSFER ANALYSIS

    SciTech Connect (OSTI)

    Tamburello, D; Richard Dimenna, R; Si Lee, S

    2009-01-27

    The transfer of liquid salt solution from Tank 32 to an evaporator is to be accomplished by activating the evaporator feed pump, with the supernate surface at a minimum height of approximately 74.4 inches above the sludge layer, while simultaneously turning on the downcomer with a flow rate of 110 gpm. Previously, activation of the evaporator feed pump was an isolated event without any other components running at the same time. An analysis of the dissolved solution transfer has been performed using computational fluid dynamics (CFD) methods to determine the amount of entrained sludge solids pumped out of the tank toward the evaporator with the downcomer turned on. The analysis results shows that, for the minimum tank liquid level of 105 inches above the tank bottom (which corresponds to a liquid depth of 74.4 inches above the sludge layer), the evaporator feed pump will contain less than 0.1 wt% sludge solids in the discharge stream, which is an order of magnitude less than the 1.0 wt% undissolved solids (UDS) loading criteria to feed the evaporator. Lower liquid levels with respect to the sludge layer will result in higher amounts of sludge entrainment due to the increased plunging jet velocity from the downcomer disturbing the sludge layer.

  14. TANK 26 EVAPORATOR FEED PUMP TRANSFER ANALYSIS

    SciTech Connect (OSTI)

    Tamburello, D; Si Lee, S; Richard Dimenna, R

    2008-09-30

    The transfer of liquid salt solution from Tank 26 to an evaporator is to be accomplished by activating the evaporator feed pump, located approximately 72 inches above the sludge layer, while simultaneously turning on the downcomer. Previously, activation of the evaporator feed pump was an isolated event without any other components running at the same time. An analysis of the dissolved solution transfer has been performed using computational fluid dynamics methods to determine the amount of entrained sludge solids pumped out of the tank to the evaporator with the downcomer turned on. The analysis results showed that, for the maximum and minimum supernate levels in Tank 26 (252.5 and 72 inches above the sludge layer, respectively), the evaporator feed pump will entrain between 0.05 and 0.1 wt% sludge solids weight fraction into the eductor, respectively. Lower tank liquid levels, with respect to the sludge layer, result in higher amounts of sludge entrainment due to the increased velocity of the plunging jets from the downcomer and evaporator feed pump bypass as well as decreased dissipation depth.

  15. Need for desiccant in containers exposed to atmospheric conditions for long periods of time

    SciTech Connect (OSTI)

    Mead, K.E.

    1981-11-01

    Current component and system designs are required to perform satisfactorily up to 25 years. A maximum leak rate of 1 x 10/sup -6/ cc(STP) helium/sec-atm is a frequent requirement for component containers. Calculations show that undesiccated component containers continuously exposed to 50% relative humidity at 20/sup 0/C and having an internal free volume of less than 300 cc and the above leak rate will allow the internal dew point to rise enough for potential liquid condensation in less than four years. For the same vapor pressure differential, the moisture permeation rate through one linear inch of silicone o-ring is 750 times as fast as moisture enters a welded container whose leak rate is 1 x 10/sup -6/ cc(STP) helium/sec-atm. For ethylene propylene o-ring material this ratio is about 13. These values correspond to the ratios of the quantities of desiccant required to maintain an acceptable dew point temperature when the moisture capacity of the free volume is not included. Charts are provided for estimating the amount of desiccant required for helium leak tested containers and for containers sealed with elastomeric o-rings.

  16. DWPF RECYCLE EVAPORATOR FLOWSHEET EVALUATION (U)

    SciTech Connect (OSTI)

    Stone, M

    2005-04-30

    The Defense Waste Processing Facility (DWPF) converts the high level waste slurries stored at the Savannah River Site into borosilicate glass for long-term storage. The vitrification process results in the generation of approximately five gallons of dilute recycle streams for each gallon of waste slurry vitrified. This dilute recycle stream is currently transferred to the H-area Tank Farm and amounts to approximately 1,400,000 gallons of effluent per year. Process changes to incorporate salt waste could increase the amount of effluent to approximately 2,900,000 gallons per year. The recycle consists of two major streams and four smaller streams. The first major recycle stream is condensate from the Chemical Process Cell (CPC), and is collected in the Slurry Mix Evaporator Condensate Tank (SMECT). The second major recycle stream is the melter offgas which is collected in the Off Gas Condensate Tank (OGCT). The four smaller streams are the sample flushes, sump flushes, decon solution, and High Efficiency Mist Eliminator (HEME) dissolution solution. These streams are collected in the Decontamination Waste Treatment Tank (DWTT) or the Recycle Collection Tank (RCT). All recycle streams are currently combined in the RCT and treated with sodium nitrite and sodium hydroxide prior to transfer to the tank farm. Tank Farm space limitations and previous outages in the 2H Evaporator system due to deposition of sodium alumino-silicates have led to evaluation of alternative methods of dealing with the DWPF recycle. One option identified for processing the recycle was a dedicated evaporator to concentrate the recycle stream to allow the solids to be recycled to the DWPF Sludge Receipt and Adjustment Tank (SRAT) and the condensate from this evaporation process to be sent and treated in the Effluent Treatment Plant (ETP). In order to meet process objectives, the recycle stream must be concentrated to 1/30th of the feed volume during the evaporation process. The concentrated stream

  17. Ball feeder for replenishing evaporator feed

    DOE Patents [OSTI]

    Felde, D.K.; McKoon, R.H.

    1993-03-23

    Vapor source material such as uranium, which is to be dropped into a melt in an evaporator, is made into many balls of identical diameters and placed inside a container. An elongated sloping pipe is connected to the container and leads to the evaporator such that these balls can travel sequentially therealong by gravity. A metering valve in this pipe for passing these balls one at a time is opened in response to a signal when it is ascertained by a detector that there is a ball ready to be passed. A gate in the pipe near the evaporator momentarily stops the motion of the traveling ball and is then opened to allow the ball drop into the melt at a reduced speed.

  18. Ball feeder for replenishing evaporator feed

    DOE Patents [OSTI]

    Felde, David K.; McKoon, Robert H.

    1993-01-01

    Vapor source material such as uranium, which is to be dropped into a melt in an evaporator, is made into many balls of identical diameters and placed inside a container. An elongated sloping pipe is connected to the container and leads to the evaporator such that these balls can travel sequentially therealong by gravity. A metering valve in this pipe for passing these balls one at a time is opened in response to a signal when it is ascertained by a detector that there is a ball ready to be passed. A gate in the pipe near the evaporator momentarily stops the motion of the traveling ball and is then opened to allow the ball drop into the melt at a reduced speed.

  19. Deep Vadose Zone Treatability Test for the Hanford Central Plateau: Interim Post-Desiccation Monitoring Results, Fiscal Year 2014

    SciTech Connect (OSTI)

    Truex, Michael J.; Strickland, Christopher E.; Johnson, Christian D.; Johnson, Timothy C.; Clayton, Ray E.; Chronister, Glen B.

    2014-09-01

    Over decades of operation, the U.S. Department of Energy (DOE) and its predecessors have released nearly 2 trillion L (450 billion gal.) of liquid into the vadose zone at the Hanford Site. Much of this discharge of liquid waste into the vadose zone occurred in the Central Plateau, a 200 km2 (75 mi2) area that includes approximately 800 waste sites. Some of the inorganic and radionuclide contaminants in the deep vadose zone at the Hanford Site are at depths below the limit of direct exposure pathways, but may need to be remediated to protect groundwater. The Tri-Party Agencies (DOE, U.S. Environmental Protection Agency, and Washington State Department of Ecology) established Milestone M 015 50, which directed DOE to submit a treatability test plan for remediation of technetium-99 (Tc-99) and uranium in the deep vadose zone. These contaminants are mobile in the subsurface environment and have been detected at high concentrations deep in the vadose zone, and at some locations have reached groundwater. Testing technologies for remediating Tc-99 and uranium will also provide information relevant for remediating other contaminants in the vadose zone. A field test of desiccation is being conducted as an element of the DOE test plan published in March 2008 to meet Milestone M 015 50. The active desiccation portion of the test has been completed. Monitoring data have been collected at the field test site during the post-desiccation period and are reported herein. This is an interim data summary report that includes about 3 years of post-desiccation monitoring data. The DOE field test plan proscribes a total of 5 years of post-desiccation monitoring.

  20. Direct Evaporative Precooling Model and Analysis

    SciTech Connect (OSTI)

    Shen, Bo; Ally, Moonis Raza; Rice, C Keith; Craddick, William G

    2011-01-01

    Evaporative condenser pre-cooling expands the availability of energy saving, cost-effective technology options (market engagement) and serves to expedite the range of options in upcoming codes and equipment standards (impacting regulation). Commercially available evaporative pre-coolers provide a low cost retrofit for existing packaged rooftop units, commercial unitary split systems, and air cooled chillers. We map the impact of energy savings and peak energy reduction in the 3 building types (medium office, secondary school, and supermarket) in 16 locations for three building types with four pad effectivenesses and show the effect for HVAC systems using either refrigerants R22 or R410A

  1. Hot air drum evaporator. [Patent application

    DOE Patents [OSTI]

    Black, R.L.

    1980-11-12

    An evaporation system for aqueous radioactive waste uses standard 30 and 55 gallon drums. Waste solutions form cascading water sprays as they pass over a number of trays arranged in a vertical stack within a drum. Hot dry air is circulated radially of the drum through the water sprays thereby removing water vapor. The system is encased in concrete to prevent exposure to radioactivity. The use of standard 30 and 55 gallon drums permits an inexpensive compact modular design that is readily disposable, thus eliminating maintenance and radiation build-up problems encountered with conventional evaporation systems.

  2. Tank 26F-2F Evaporator Study

    SciTech Connect (OSTI)

    Adu-Wusu, K.

    2012-12-19

    Tank 26F supernate sample was sent by Savannah River Remediation to Savannah River National Laboratory for evaporation test to help understand the underlying cause of the recent gravity drain line (GDL) pluggage during operation of the 2F Evaporator system. The supernate sample was characterized prior to the evaporation test. The evaporation test involved boiling the supernate in an open beaker until the density of the concentrate (evaporation product) was between 1.4 to 1.5 g/mL. It was followed by filtering and washing of the precipitated solids with deionized water. The concentrate supernate (or concentrate filtrate), the damp unwashed precipitated solids, and the wash filtrates were characterized. All the precipitated solids dissolved during water washing. A semi-quantitative X-ray diffraction (XRD) analysis on the unwashed precipitated solids revealed their composition. All the compounds with the exception of silica (silicon oxide) are known to be readily soluble in water. Hence, their dissolution during water washing is not unexpected. Even though silica is a sparingly water-soluble compound, its dissolution is also not surprising. This stems from its small fraction in the solids as a whole and also its relative freshness. Assuming similar supernate characteristics, flushing the GDL with water (preferably warm) should facilitate dissolution and removal of future pluggage events as long as build up/aging of the sparingly soluble constituent (silica) is limited. On the other hand, since the amount of silica formed is relatively small, it is quite possible dissolution of the more soluble larger fraction will cause disintegration or fragmentation of the sparingly soluble smaller fraction (that may be embedded in the larger soluble solid mass) and allow its removal via suspension in the flushing water.

  3. Static, mixed-array total evaporation for improved quantitation of plutonium minor isotopes in small samples

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Stanley, F. E.; Byerly, Benjamin L.; Thomas, Mariam R.; Spencer, Khalil J.

    2016-03-31

    Actinide isotope measurements are a critical signature capability in the modern nuclear forensics “toolbox”, especially when interrogating anthropogenic constituents in real-world scenarios. Unfortunately, established methodologies, such as traditional total evaporation via thermal ionization mass spectrometry, struggle to confidently measure low abundance isotope ratios (<10-6) within already limited quantities of sample. Herein, we investigate the application of static, mixed array total evaporation techniques as a straightforward means of improving plutonium minor isotope measurements, which have been resistant to enhancement in recent years because of elevated radiologic concerns. Furthermore, results are presented for small sample (~20 ng) applications involving a well-known plutoniummore » isotope reference material, CRM-126a, and compared with traditional total evaporation methods.« less

  4. Evaporative cooler including one or more rotating cooler louvers

    DOE Patents [OSTI]

    Gerlach, David W

    2015-02-03

    An evaporative cooler may include an evaporative cooler housing with a duct extending therethrough, a plurality of cooler louvers with respective porous evaporative cooler pads, and a working fluid source conduit. The cooler louvers are arranged within the duct and rotatably connected to the cooler housing along respective louver axes. The source conduit provides an evaporative cooler working fluid to the cooler pads during at least one mode of operation.

  5. Flash evaporation of liquid monomer particle mixture

    DOE Patents [OSTI]

    Affinito, John D.; Darab, John G.; Gross, Mark E.

    1999-01-01

    The present invention is a method of making a first solid composite polymer layer. The method has the steps of (a) mixing a liquid monomer with particles substantially insoluble in the liquid monomer forming a monomer particle mixture; (b) flash evaporating the particle mixture and forming a composite vapor; and (c) continuously cryocondensing said composite vapor on a cool substrate and cross-linking the cryocondensed film thereby forming the polymer layer.

  6. Flash evaporation of liquid monomer particle mixture

    DOE Patents [OSTI]

    Affinito, J.D.; Darab, J.G.; Gross, M.E.

    1999-05-11

    The present invention is a method of making a first solid composite polymer layer. The method has the steps of (a) mixing a liquid monomer with particles substantially insoluble in the liquid monomer forming a monomer particle mixture; (b) flash evaporating the particle mixture and forming a composite vapor; and (c) continuously cryocondensing said composite vapor on a cool substrate and cross-linking the cryocondensed film thereby forming the polymer layer. 3 figs.

  7. Tubeless evaporation process development: Final report

    SciTech Connect (OSTI)

    Not Available

    1987-12-01

    A tubeless evaporation process which has the potential to combine the advantage of both evaporation and freezing processes, without their disadvantages is being developed. The TEP is capable of concentrating process solutions of such things as sugar, caustic soda, salt, sodium sulfate, black liquor from the pulp and paper industry, cooling tower blowdown, ''spent'' pickling liquor (sulfuric acid) from the steel industry, and nitric acid with potential energy savings of half to three-quarters of the energy required by conventional evaporators, with about half of the capital and maintenance cost. It has similar potential for the production of fresh water from seawater. The process uses working fluids (WF's) at their freezing point to effect direct contact heat exchange. The purpose of this project was to find additional and lower cost WF's in the laboratory, to obtain sizing information for the major equipment for an economic evaluation and a pilot plant design in a bench scale plant, and to perform the economic evaluation, and the pilot plant design and cost estimate. 6 refs., 37 figs., 7 tabs.

  8. Selection for increased desiccation resistance in Drosophila melanogaster: Additive genetic control and correlated responses for other stresses

    SciTech Connect (OSTI)

    Hoffmann, A.A.; Parsons, P.A. )

    1989-08-01

    Previously we found that Drosophila melanogaster lines selected for increased desiccation resistance have lowered metabolic rate and behavioral activity levels, and show correlated responses for resistance to starvation and a toxic ethanol level. These results were consistent with a prediction that increased resistance to many environmental stresses may be genetically correlated because of a reduction in metabolic energy expenditure. Here we present experiments on the genetic basis of the selection response and extend the study of correlated responses to other stresses. The response to selection was not sex-specific and involved X-linked and autosomal genes acting additively. Activity differences contributed little to differences in desiccation resistance between selected and control lines. Selected lines had lower metabolic rates than controls in darkness when activity was inhibited. Adults from selected lines showed increased resistance to a heat shock, {sup 60}Co-gamma-radiation, and acute ethanol and acetic acid stress. The desiccation, ethanol and starvation resistance of isofemale lines set up from the F2s of a cross between one of the selected and one of the control lines were correlated. Selected and control lines did not differ in ether-extractable lipid content or in resistance to acetone, ether or a cold shock.

  9. Zero Energy Communities with Central Solar Plants using Liquid Desiccants and Local Storage: Preprint

    SciTech Connect (OSTI)

    Burch, J.; Woods, J.; Kozubal, E.; Boranian, A.

    2012-08-01

    The zero energy community considered here consists of tens to tens-of-thousands of residences coupled to a central solar plant that produces all the community's electrical and thermal needs. A distribution network carries fluids to meet the heating and cooling loads. Large central solar systems can significantly reduce cost of energy vs. single family systems, and they enable economical seasonal heat storage. However, the thermal distribution system is costly. Conventional district heating/cooling systems use a water/glycol solution to deliver sensible energy. Piping is sized to meet the peak instantaneous load. A new district system introduced here differs in two key ways: (i) it continuously distributes a hot liquid desiccant (LD) solution to LD-based heating and cooling equipment in each home; and (ii) it uses central and local storage of both LD and heat to reduce flow rates to meet average loads. Results for piping sizes in conventional and LD thermal communities show that the LD zero energy community reduces distribution piping diameters meeting heating loads by {approx}5X and meeting cooling loads by {approx}8X for cooling, depending on climate.

  10. CHEMISTRY IN EVAPORATING ICES-UNEXPLORED TERRITORY

    SciTech Connect (OSTI)

    Cecchi-Pestellini, Cesare; Rawlings, Jonathan M. C.; Viti, Serena; Williams, David A. E-mail: jcr@star.ucl.ac.u E-mail: daw@star.ucl.ac.u

    2010-12-20

    We suggest that three-body chemistry may occur in warm high-density gas evaporating in transient co-desorption events on interstellar ices. Using a highly idealized computational model we explore the chemical conversion from simple species of the ice to more complex species containing several heavy atoms, as a function of density and of adopted three-body rate coefficients. We predict that there is a wide range of densities and rate coefficients in which a significant chemical conversion may occur. We discuss the implications of this idea for the astrochemistry of hot cores.

  11. Treatment of evaporator condensates by pervaporation

    DOE Patents [OSTI]

    Blume, Ingo; Baker, Richard W.

    1990-01-01

    A pervaporation process for separating organic contaminants from evaporator condensate streams is disclosed. The process employs a permselective membrane that is selectively permeable to an organic component of the condensate. The process involves contacting the feed side of the membrane with a liquid condensate stream, and withdrawing from the permeate side a vapor enriched in the organic component. The driving force for the process is the in vapor pressure across the membrane. This difference may be provided for instance by maintaining a vacuum on the permeate side, or by condensing the permeate. The process offers a simple, economic alternative to other separation techniques.

  12. Two stage indirect evaporative cooling system

    DOE Patents [OSTI]

    Bourne, Richard C.; Lee, Brian E.; Callaway, Duncan

    2005-08-23

    A two stage indirect evaporative cooler that moves air from a blower mounted above the unit, vertically downward into dry air passages in an indirect stage and turns the air flow horizontally before leaving the indirect stage. After leaving the dry passages, a major air portion travels into the direct stage and the remainder of the air is induced by a pressure drop in the direct stage to turn 180.degree. and returns horizontally through wet passages in the indirect stage and out of the unit as exhaust air.

  13. Models of crystallization in evaporating droplets

    SciTech Connect (OSTI)

    Ford, I.J.

    1996-12-31

    The spray drying of a droplet containing a substance in solution can produce solid particles with a variety of final shapes: hollow, punctured, squashed, as well as solid spheres. The geometry affects the properties of the product. Models are presented here which describe the processes of solvent evaporation and solute crystallization as drying takes place. The formation of a crust on the surface of the droplet is addressed. It is proposed that such a crust with a thickness of two crystallite diameters can develop into dry hollow shell. Some example calculations of the spray drying of droplets of sodium chloride solution are described.

  14. Simple flash evaporator for making thin films of compounds

    SciTech Connect (OSTI)

    Hemanadhan, M.; Bapanayya, Ch.; Agarwal, S. C. [Department of Physics, Indian Institute of Technology, Kanpur 208016 (India)

    2010-07-15

    A simple and compact arrangement for flash evaporation is described. It uses a cell phone vibrator for powder dispensing that can be incorporated into a vacuum deposition chamber without any major alterations. The performance of the flash evaporation system is checked by making thin films of the optical memory chalcogenide glass Ge{sub 2}Sb{sub 2}Te{sub 5} (GST). Energy dispersive x-ray analysis shows that the flash evaporation preserves the stoichiometry in thin films.

  15. Metered Evaporator for Tokamak Wall Conditioning --- Inventor(s): Charles

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    H. Skinner, Dennis Mansfield, Henry Kugel, Hans Schneider and Lane Roquemore | Princeton Plasma Physics Lab Metered Evaporator for Tokamak Wall Conditioning --- Inventor(s): Charles H. Skinner, Dennis Mansfield, Henry Kugel, Hans Schneider and Lane Roquemore A novel lithium evaporator for the controlled introduction of lithium into tokamaks for wall conditioning is described. The concept uses a Li granule injector with a heated in-vessel yttrium crucible to evaporate a controlled amount of

  16. NANO- AND MICROSTRUCTURES FOR THIN-FILM EVAPORATION-A REVIEW

    SciTech Connect (OSTI)

    Plawsky, JL; Fedorov, AG; Garimella, SV; Ma, HB; Maroo, SC; Chen, L; Nam, Y

    2014-07-23

    Evaporation from thin films is a key feature of many processes, including energy conversion, microelectronics cooling, boiling, perspiration, and self-assembly operations. The phase change occurring in these systems is governed by transport processes at the contact line where liquid, vapor, and solid meet. Evidence suggests that altering the surface chemistry and surface topography on the micro-and the nanoscales can be used to dramatically enhance vaporization. The 2013 International Workshop on Micro- and Nanostructures for Phase-Change Heat Transfer brought together a group of experts to review the current state-of-the-art and discuss future research needs. This article is focused on the thin-film evaporation panel discussion and outlines some of the key principles and conclusions reached by that panel and the workshop attendees.

  17. Simulation of Heterogeneous Atom Probe Tip Shapes Evolution during Field Evaporation Using a Level Set Method and Different Evaporation Models

    SciTech Connect (OSTI)

    Xu, Zhijie; Li, Dongsheng; Xu, Wei; Devaraj, Arun; Colby, Robert J.; Thevuthasan, Suntharampillai; Geiser, B. P.; Larson, David J.

    2015-04-01

    In atom probe tomography (APT), accurate reconstruction of the spatial positions of field evaporated ions from measured detector patterns depends upon a correct understanding of the dynamic tip shape evolution and evaporation laws of component atoms. Artifacts in APT reconstructions of heterogeneous materials can be attributed to the assumption of homogeneous evaporation of all the elements in the material in addition to the assumption of a steady state hemispherical dynamic tip shape evolution. A level set method based specimen shape evolution model is developed in this study to simulate the evaporation of synthetic layered-structured APT tips. The simulation results of the shape evolution by the level set model qualitatively agree with the finite element method and the literature data using the finite difference method. The asymmetric evolving shape predicted by the level set model demonstrates the complex evaporation behavior of heterogeneous tip and the interface curvature can potentially lead to the artifacts in the APT reconstruction of such materials. Compared with other APT simulation methods, the new method provides smoother interface representation with the aid of the intrinsic sub-grid accuracy. Two evaporation models (linear and exponential evaporation laws) are implemented in the level set simulations and the effect of evaporation laws on the tip shape evolution is also presented.

  18. Report on Analyses of WAC Samples of Evaporator Overheads - 2004

    SciTech Connect (OSTI)

    Oji, L

    2005-03-18

    In November and December of 2004, the Tank Farm submitted annual samples from 2F, 2H and 3H Evaporator Overhead streams for characterization to verify compliance with the new Effluent Treatment Facility (ETF) Waste Acceptance Criteria (WAC) and to look for organic species. With the exception of slightly high ammonia in the 2F evaporator overheads and high radiation control guide number for the 3H and 2F evaporator overhead samples, all the overheads samples were found to be in compliance with the Effluent Treatment Facility WAC. The ammonium concentration in the 2F-evaporator overhead, at 33 mg/L, was above the ETF waste water collection tank (WWCT) limits of 28 mg/L. The RCG Number for the 3H and 2F evaporator samples at, respectively, 1.38E-02 and 8.24E-03 were higher than the WWCT limit of 7.69E-03. The analytical detection limits for americium-241 and radium-226 in the evaporator samples were not consistently met because of low WWCT detection limits and insufficient evaporator samples.

  19. 242-A Evaporator quality assurance plan. Revision 2

    SciTech Connect (OSTI)

    Basra, T.S.

    1995-05-04

    The purpose of this quality assurance project plan (Plan) is to provide requirements for activities pertaining to sampling, shipping, and analyses associated with candidate feed tank samples for the 242-A Evaporator project. The purpose of the 242-A Evaporator project is to reduce the volume of aqueous waste in the Double Shell Tank (DST) System and will result in considerable savings to the disposal of mixed waste. The 242-A Evaporator feed stream originates from DSTs identified as candidate feed tanks. The 242-A Evaporator reduces the volume of aqueous waste contained in DSTs by boiling off water and sending the condensate (called process condensate) to the Liquid Effluent Retention Facility (LEPF) storage basin where it is stored prior to treatment in the Effluent Treatment Facility (ETF). The objective of this quality assurance project plan is to provide the planning, implementation, and assessment of sample collection and analysis, data issuance, and validation activities for the candidate feed tanks.

  20. EVAPORATION OF ICY PLANETESIMALS DUE TO BOW SHOCKS

    SciTech Connect (OSTI)

    Tanaka, Kyoko K.; Yamamoto, Tetsuo; Tanaka, Hidekazu [Institute of Low Temperature Science, Hokkaido University, Sapporo 060-0819 (Japan)] [Institute of Low Temperature Science, Hokkaido University, Sapporo 060-0819 (Japan); Miura, Hitoshi [Department of Earth Sciences, Tohoku University, Sendai 980-8578 (Japan)] [Department of Earth Sciences, Tohoku University, Sendai 980-8578 (Japan); Nagasawa, Makiko; Nakamoto, Taishi [Earth and Planetary Sciences, Tokyo Institute of Technology, Tokyo 152-8551 (Japan)] [Earth and Planetary Sciences, Tokyo Institute of Technology, Tokyo 152-8551 (Japan)

    2013-02-20

    We present the novel concept of evaporation of planetesimals as a result of bow shocks associated with planetesimals orbiting with supersonic velocities relative to the gas in a protoplanetary disk. We evaluate the evaporation rates of the planetesimals based on a simple model describing planetesimal heating and evaporation by the bow shock. We find that icy planetesimals with radius {approx}>100 km evaporate efficiently even outside the snow line in the stage of planetary oligarchic growth, where strong bow shocks are produced by gravitational perturbations from protoplanets. The obtained results suggest that the formation of gas giant planets is suppressed owing to insufficient accretion of icy planetesimals onto the protoplanet within the {approx}<5 AU disk region.

  1. Water Managment: The Dynamic Challenges of Evaporative Cooling...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    As water flows over the tower, heat picked up by the process is released by evaporation. The cooling water then returns to the heat exchangers to pick up more heat. Cooling Tower ...

  2. Angular momentum effects in fusion-fission and fusion-evaporation reactions

    SciTech Connect (OSTI)

    Plasil, F.

    1980-01-01

    The study of heavy-ion fusion reactions is complicated by the possible contributions of several mechanisms. The various types of heavy-ion-induced fission are discussed. Then compound-nucleus fission is considered with reference to fission barriers deduced from heavy-ion-induced fission. Next, the problems associated with measured values of evaporation-residue cross sections and the angular momentum dependence of incomplete fusion are examined. Finally, the de-excitation of compound nuclei is again taken up, this time with reference to the greatly enhanced ..cap alpha.. emission predicted on the basis of the rotating liquid drop model. 24 figures. (RWR)

  3. Superhydrophobic coated apparatus for liquid purification by evaporative condensation

    DOE Patents [OSTI]

    Simpson, John T; McNeany, Steve R; Dinsmore, Thomas V; Hunter, Scott R; Ivanov, Ilia N

    2014-03-11

    Disclosed are examples of apparatuses for evaporative purification of a contaminated liquid. In each example, there is a first vessel for storing the contaminated fluid. The first vessel includes a surface coated with a layer of superhydrophobic material and the surface is at least partially in contact with the contaminated liquid. The contaminants do not adhere to the surface as the purified liquid evaporates, thus simplifying maintenance of the apparatus.

  4. "Increasing Solar Panel Efficiency And Reliability By Evaporative

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cooling" Inventors..--.. Lewis Meixler, Charles Gentile, Patricia Hillyer, Dylan Carpe, Jason Wang, Caroline Brooks | Princeton Plasma Physics Lab Increasing Solar Panel Efficiency And Reliability By Evaporative Cooling" Inventors..--.. Lewis Meixler, Charles Gentile, Patricia Hillyer, Dylan Carpe, Jason Wang, Caroline Brooks The efficiency and reliability of photovoltaic solar panels decreases with increasing operating temperatures. In hot, dry climates, evaporative cooling with a

  5. DOE - Office of Legacy Management -- Swenson Evaporator Co - IL 23

    Office of Legacy Management (LM)

    Swenson Evaporator Co - IL 23 FUSRAP Considered Sites Site: SWENSON EVAPORATOR CO. (IL.23 ) Eliminated from further consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: Harvey , Illinois IL.23-1 Evaluation Year: 1987 IL.23-1 Site Operations: Scheduled a raffinate spray drying test that was later cancelled. IL.23-1 Site Disposition: Eliminated - No indication that radioactive materials were handled at this site IL.23-1 Radioactive Materials Handled: None

  6. NWCF Evaporator Tank System 2001 Offgas Emissions Inventory

    SciTech Connect (OSTI)

    Boardman, R.D.; Lamb, K.M.; Matejka, L.A.; Nenni, J.A.

    2002-02-27

    An offgas emissions inventory and liquid stream characterization of the Idaho New Waste Calcining Facility (NWCF) Evaporator Tank System (ETS), formerly known as the High Level Liquid Waste Evaporator (HLLWE), has been completed. The emissions rates of volatile and semi-volatile organic compounds, multiple metals, particulate, and hydrochloric acid were measured in accordance with an approved Quality Assurance Project Plan (QAPjP) and Test Plan that invoked U.S. Environmental Protection Agency (EPA) standard sample collection and analysis procedures. Offgas samples were collected during the start up and at the end of evaporator batches when it was hypothesized the emissions would be at peak rates. Corresponding collection of samples from the evaporator feed overhead condensate, and bottoms was made at approximately the same time as the emissions inventory to support material balance determinations for the evaporator process. The data indicate that organic compound emissions are slightly higher at the beginning of the batch while metals emissions, including mercury, are slightly higher at the end of the evaporator batch. The maximum emissions concentrations are low for all constituents of primary concern. Mercury emissions were less than 5 ppbv, while the sum of HCl and Cl2 emissions was less than 1 ppmv. The sum of all organic emissions also was less than 1 ppmv. The estimated hazardous quotient (HQ) for the evaporator was 6.2e-6 as compared to 0.25 for the EPA target criteria. The cancer risk was 1.3e-10 compared to an EPA target of le-5.

  7. NWCF Evaporator Tank System 2001 Offgas Emissions Inventory

    SciTech Connect (OSTI)

    Boardman, Richard Doin; Lamb, Kenneth Mitchel; Matejka, Leon Anthony; Nenni, Joseph A

    2002-02-01

    An offgas emissions inventory and liquid stream characterization of the Idaho New Waste Calcining Facility (NWCF) Evaporator Tank System (ETS), formerly known as the High Level Liquid Waste Evaporator (HLLWE), has been completed. The emissions rates of volatile and semi-volatile organic compounds, multiple metals, particulate, and hydrochloric acid were measured in accordance with an approved Quality Assurance Project Plan (QAPjP) and Test Plan that invoked U.S. Environmental Protection Agency (EPA) standard sample collection and analysis procedures. Offgas samples were collected during the start up and at the end of evaporator batches when it was hypothesized the emissions would be at peak rates. Corresponding collection of samples from the evaporator feed overhead condensate, and bottoms was made at approximately the same time as the emissions inventory to support material balance determinations for the evaporator process. The data indicate that organic compound emissions are slightly higher at the beginning of the batch while metals emissions, including mercury, are slightly higher at the end of the evaporator batch. The maximum emissions concentrations are low for all constituents of primary concern. Mercury emissions were less than 5 ppbv, while the sum of HCl and Cl2 emissions was less than 1 ppmv. The sum of all organic emissions also was less than 1 ppmv. The estimated hazardous quotient (HQ) for the evaporator was 6.2e-6 as compared to 0.25 for the EPA target criteria. The cancer risk was 1.3e-10 compared to an EPA target of le-5.

  8. Open cycle liquid desiccant dehumidifier and hybrid solar/electric absorption refrigeration system. Annual report, January 1993--December 1993. Calendar year 1993

    SciTech Connect (OSTI)

    Nimmo, B.G.; Thornbloom, M.D.

    1995-04-01

    This annual report presents work performed during calendar year 1993 by the Florida Solar Energy Center under contract to the US Department of Energy. Two distinctively different solar powered indoor climate control systems were analyzed: the open cycle liquid desiccant dehumidifier, and an improved efficiency absorption system which may be fired by flat plate solar collectors. Both tasks represent new directions relative to prior FSEC research in Solar Cooling and Dehumidification.

  9. Analysis of the adsorption process and of desiccant cooling systems: a pseudo- steady-state model for coupled heat and mass transfer. [DESSIM, DESSIM2, DESSIM4

    SciTech Connect (OSTI)

    Barlow, R.S.

    1982-12-01

    A computer model to simulate the adiabatic adsorption/desorption process is documented. Developed to predict the performance of desiccant cooling systems, the model has been validated through comparison with experimental data for single-blow adsorption and desorption. A literature review on adsorption analysis, detailed discussions of the adsorption process, and an initial assessment of the potential for performance improvement through advanced component development are included.

  10. Black hole evaporation in a noncommutative charged Vaidya model

    SciTech Connect (OSTI)

    Sharif, M. Javed, W.

    2012-06-15

    We study the black hole evaporation and Hawking radiation for a noncommutative charged Vaidya black hole. For this purpose, we determine a spherically symmetric charged Vaidya model and then formulate a noncommutative Reissner-Nordstroem-like solution of this model, which leads to an exact (t - r)-dependent metric. The behavior of the temporal component of this metric and the corresponding Hawking temperature are investigated. The results are shown in the form of graphs. Further, we examine the tunneling process of charged massive particles through the quantum horizon. We find that the tunneling amplitude is modified due to noncommutativity. Also, it turns out that the black hole evaporates completely in the limits of large time and horizon radius. The effect of charge is to reduce the temperature from a maximum value to zero. We note that the final stage of black hole evaporation is a naked singularity.

  11. Development of a Direct Evaporator for the Organic Rankine Cycle

    SciTech Connect (OSTI)

    Donna Post Guillen; Helge Klockow; Matthew Lehar; Sebastian Freund; Jennifer Jackson

    2011-02-01

    This paper describes research and development currently underway to place the evaporator of an Organic Rankine Cycle (ORC) system directly in the path of a hot exhaust stream produced by a gas turbine engine. The main goal of this research effort is to improve cycle efficiency and cost by eliminating the usual secondary heat transfer loop. The project’s technical objective is to eliminate the pumps, heat exchangers and all other added cost and complexity of the secondary loop by developing an evaporator that resides in the waste heat stream, yet virtually eliminates the risk of a working fluid leakage into the gaseous exhaust stream. The research team comprised of Idaho National Laboratory and General Electric Company engineers leverages previous research in advanced ORC technology to develop a new direct evaporator design that will reduce the ORC system cost by up to 15%, enabling the rapid adoption of ORCs for waste heat recovery.

  12. Simulation of Diffusive Lithium Evaporation Onto the NSTX Vessel Walls

    SciTech Connect (OSTI)

    Stotler, D. P.; Skinner, C. H.; Blanchard, W. R.; Krstic, P. S.; Kugel, H. W.; Schneider, H.; Zakharov, L. E.

    2010-12-09

    A model for simulating the diffusive evaporation of lithium into a helium filled NSTX vacuum vessel is described and validated against an initial set of deposition experiments. The DEGAS 2 based model consists of a three-dimensional representation of the vacuum vessel, the elastic scattering process, and a kinetic description of the evaporated atoms. Additional assumptions are required to account for deuterium out-gassing during the validation experiments. The model agrees with the data over a range of pressures to within the estimated uncertainties. Suggestions are made for more discriminating experiments that will lead to an improved model.

  13. Evaporation of water with single and multiple impinging air jets

    SciTech Connect (OSTI)

    Trabold, T.A.; Obot, N.T. )

    1991-08-01

    An experimental investigation of impingement water evaporation under a single jet and arrays of circular jets was made. The parametric study included the effects of jet Reynolds number and standoff spacing for both single and multiple jets, as well as surface-to-nozzle diameter ratio and fractional nozzle open area for single and multiple jets, respectively. The nozzle exit temperature of the air jet, about the same as that of the laboratory, was 3-6C higher than that of the evaporating water. Predictive equations are provided for mass transfer coefficient in terms of the flow and geometric conditions.

  14. Vacuum thermal evaporation of polyaniline doped with camphor sulfonic acid

    SciTech Connect (OSTI)

    Boyne, Devon; Menegazzo, Nicola; Pupillo, Rachel C.; Rosenthal, Joel; Booksh, Karl S.

    2015-05-15

    Intrinsically conducting polymers belong to a class of organic polymers with intriguing electronic and physical properties specifically for electro-optical applications. Significant interest into doped polyaniline (PAni) can be attributed to its high conductivity and environmental stability. Poor dissolution in most solvents has thus far hindered the successful integration of PAni into commercial applications, which in turn, has led to the investigations of various deposition and acidic doping methods. Physical vapor deposition methods, including D.C. magnetron sputtering and vacuum thermal evaporation, have shown exceptional control over physical film properties (thickness and morphology). However, resulting films are less conductive than films deposited by conventional methods (i.e., spin and drop casting) due to interruption of the hyperconjugation of polymer chains. Specifically, vacuum thermal evaporation requires a postdoping process, which results in incorporation of impurities and oxidation of surface moieties. In this contribution, thermally evaporated films, sequentially doped by vacuum evaporation of an organic acid (camphorsulfonic acid, CSA) is explored. Spectroscopic evidence confirms the successful doping of PAni with CSA while physical characterization (atomic force microscopy) suggests films retain good morphology and are not damaged by the doping process. The procedure presented herein also combines other postpreparation methods in an attempt to improve conductivity and/or substrate adhesion.

  15. Evaporation of iodine-containing off-gas scrubber solution

    DOE Patents [OSTI]

    Partridge, J.A.; Bosuego, G.P.

    1980-07-14

    Mercuric nitrate-nitric acid scrub solutions containing radioiodine may be reduced in volume without excessive loss of volatile iodine. The use of concentrated nitric acid during an evaporation process oxidizes the mercury-iodide complex to a less volatile mercuric iodate precipitate.

  16. Calculation of Reactive-evaporation Rates of Chromia

    SciTech Connect (OSTI)

    Holcomb, G.R.

    2008-04-01

    A methodology is developed to calculate Cr-evaporation rates from Cr2O3 with a flat planar geometry. Variables include temperature, total pressure, gas velocity, and gas composition. The methodology was applied to solid-oxide, fuel cell conditions for metallic interconnects and to advanced-steam turbines conditions. The high velocities and pressures of the advanced steam turbine led to evaporation predictions as high as 5.18 9 10-8 kg/m2/s of CrO2(OH)2(g) at 760 °C and 34.5 MPa. This is equivalent to 0.080 mm per year of solid Cr loss. Chromium evaporation is expected to be an important oxidation mechanism with the types of nickel-base alloys proposed for use above 650 °C in advanced-steam boilers and turbines. It is shown that laboratory experiments, with much lower steam velocities and usually much lower total pressure than found in advanced steam turbines, would best reproduce chromium-evaporation behavior with atmospheres that approach either O2 + H2O or air + H2O with 57% H2O.

  17. Analysis of design tradeoffs for diplay case evaporators

    SciTech Connect (OSTI)

    Bullard, CLARK

    2004-08-11

    A model for simulating a display case evaporator under frosting conditions has been developed, using a quasi-steady and finite-volume approach and a Newton-Raphson based solution algorithm. It is capable of simulating evaporators with multiple modules having different geometries, e.g. tube and fin thicknesses and pitch. The model was validated against data taken at two-minute intervals from a well-instrumented medium-temperature vertical display case, for two evaporators having very different configurations. The data from these experiments provided both the input data for the model and also the data to compare the modeling results. The validated model has been used to generate some general guidelines for coil design. Effects of various geometrical parameters were quantified, and compressor performance data were used to express the results in terms of total power consumption. Using these general guidelines, a new prototype evaporator was designed for the subject display case, keeping in mind the current packaging restrictions, tube and fin availabilities. It is an optimum coil for the given external load conditions. Subsequently, the validated model was used in a more extensive analysis to design prototype coils with some of the current tube and fin spacing restrictions removed. A new microchannel based suction line heat exchanger was installed in the display case system. The performance of this suction line heat exchanger is reported.

  18. Calculation notes that support accident scenario and consequence of the evaporator dump

    SciTech Connect (OSTI)

    Crowe, R.D., Westinghouse Hanford

    1996-09-09

    The purpose of this calculation note is to provide the basis for evaporator dump consequence for the Tank Farm Safety Analysis Report (FSAR). Evaporator Dump scenario is developed and details and description of the analysis methods are provided.

  19. Calculation notes that support accident scenario and consequence of the evaporator dump

    SciTech Connect (OSTI)

    Crowe, R.D.

    1996-09-27

    The purpose of this calculation note is to provide the basis for evaporator dump consequence for the Tank Farm Safety Analysis Report (FSAR). Evaporator Dump scenario is developed and details and description of the analysis methods are provided.

  20. Bench-Scale Evaporation of a Large Hanford Envelope C Sample (Tank 241-AN-102)

    SciTech Connect (OSTI)

    Crowder, M.L.

    2001-07-13

    This report contains the results of the Bench Scale evaporation of a large sample of pretreated Envelope C (AN102).

  1. Evaporation-based Ge/.sup.68 Ga Separation

    DOE Patents [OSTI]

    Mirzadeh, Saed; Whipple, Richard E.; Grant, Patrick M.; O'Brien, Jr., Harold A.

    1981-01-01

    Micro concentrations of .sup.68 Ga in secular equilibrium with .sup.68 Ge in strong aqueous HCl solution may readily be separated in ionic form from the .sup.68 Ge for biomedical use by evaporating the solution to dryness and then leaching the .sup.68 Ga from the container walls with dilute aqueous solutions of HCl or NaCl. The chloro-germanide produced during the evaporation may be quantitatively recovered to be used again as a source of .sup.68 Ga. If the solution is distilled to remove any oxidizing agents which may be present as impurities, the separation factor may easily exceed 10.sup.5. The separation is easily completed and the .sup.68 Ga made available in ionic form in 30 minutes or less.

  2. Solar evaporation of fertilizers/ag-chemical aqueous mixtures

    SciTech Connect (OSTI)

    Ash, D.H.; Salladay, D.G.; Norwood, V.M. ); Guinn, G.R. )

    1991-01-01

    Even when best management practices are employed, dealers can have 2000 to 7000 gallons of fertilizer/pesticide rinsewaters each year that cannot be used on nonlabel crops or indiscriminately applied or disposed of without violating Environmental Protection Agency (EPA) pesticide label application regulations. A novel, easily implemented solution for reduction of these rinsewaters has been developed at the University of Alabama at Huntsville (UAH) working with researchers from the Tennessee Valley Authority's (TVA) National Fertilizer and Environmental Research Center (NFERC), Muscle Shoals, Alabama. Researchers have developed a passive flat-plate solar evaporator. It is a stainless steel/glass unit approximately 8inches [times] 7inches [times] 5inches, and can be produced on an assembly line basis for less than $4000 each. NFERC technologists will use these units for environmental research and demonstration projects at other universities and dealers this year. Each unit can evaporate 900--1200 gallons of water per year.

  3. Axially Tapered And Bilayer Microchannels For Evaporative Cooling Devices

    DOE Patents [OSTI]

    Nilson, Robert; Griffiths, Stewart

    2005-10-04

    The invention consists of an evaporative cooling device comprising one or more microchannels whose cross section is axially reduced to control the maximum capillary pressure differential between liquid and vapor phases. In one embodiment, the evaporation channels have a rectangular cross section that is reduced in width along a flow path. In another embodiment, channels of fixed width are patterned with an array of microfabricated post-like features such that the feature size and spacing are gradually reduced along the flow path. Other embodiments incorporate bilayer channels consisting of an upper cover plate having a pattern of slots or holes of axially decreasing size and a lower fluid flow layer having channel widths substantially greater than the characteristic microscale dimensions of the patterned cover plate. The small dimensions of the cover plate holes afford large capillary pressure differentials while the larger dimensions of the lower region reduce viscous flow resistance.

  4. Energy and economic assessment of desiccant cooling systems coupled with single glazed air and hybrid PV/thermal solar collectors for applications in hot and humid climate

    SciTech Connect (OSTI)

    Beccali, Marco; Finocchiaro, Pietro; Nocke, Bettina

    2009-10-15

    This paper presents a detailed analysis of the energy and economic performance of desiccant cooling systems (DEC) equipped with both single glazed standard air and hybrid photovoltaic/thermal (PV/t) collectors for applications in hot and humid climates. The use of 'solar cogeneration' by means of PV/t hybrid collectors enables the simultaneous production of electricity and heat, which can be directly used by desiccant air handling units, thereby making it possible to achieve very energy savings. The present work shows the results of detailed simulations conducted for a set of desiccant cooling systems operating without any heat storage. System performance was investigated through hourly simulations for different systems and load combinations. Three configurations of DEC systems were considered: standard DEC, DEC with an integrated heat pump and DEC with an enthalpy wheel. Two kinds of building occupations were considered: office and lecture room. Moreover, three configurations of solar-assisted air handling units (AHU) equipped with desiccant wheels were considered and compared with standard AHUs, focusing on achievable primary energy savings. The relationship between the solar collector's area and the specific primary energy consumption for different system configurations and building occupation patterns is described. For both occupation patterns, sensitivity analysis on system performance was performed for different solar collector areas. Also, this work presents an economic assessment of the systems. The cost of conserved energy and the payback time were calculated, with and without public incentives for solar cooling systems. It is worth noting that the use of photovoltaics, and thus the exploitation of related available incentives in many European countries, could positively influence the spread of solar air cooling technologies (SAC). An outcome of this work is that SAC systems equipped with PV/t collectors are shown to have better performance in terms of

  5. Mesoporous-silica films, fibers, and powders by evaporation

    DOE Patents [OSTI]

    Bruinsma, Paul J.; Baskaran, Suresh; Bontha, Jagannadha R.; Liu, Jun

    1999-01-01

    This invention pertains to surfactant-templated nanometer-scale porosity of a silica precursor solution and forming a mesoporous material by first forming the silica precursor solution into a preform having a high surface area to volume ratio, then rapid drying or evaporating a solvent from the silica precursor solution. The mesoporous material may be in any geometric form, but is preferably in the form of a film, fiber, powder or combinations thereof. The rapid drying or evaporation of solvent from the solution is accomplished by layer thinning, for example spin casting, liquid drawing, and liquid spraying respectively. Production of a film is by layer thinning, wherein a layer of the silica precursor solution is formed on a surface followed by removal of an amount of the silica precursor solution and leaving a geometrically thinner layer of the silica precursor solution from which the solvent quickly escapes via evaporation. Layer thinning may be by any method including but not limited to squeegeeing and/or spin casting. In powder formation by spray drying, the same conditions of fast drying exists as in spin-casting (as well as in fiber spinning) because of the high surface-area to volume ratio of the product. When a powder is produced by liquid spraying, the particles or micro-bubbles within the powder are hollow spheres with walls composed of mesoporous silica. Mesoporous fiber formation starts with a similar silica precursor solution but with an added pre-polymer making a pituitous mixture that is drawn into a thin strand from which solvent is evaporated leaving the mesoporous fiber(s).

  6. Mesoporous-silica films, fibers, and powders by evaporation

    DOE Patents [OSTI]

    Bruinsma, Paul J.; Baskaran, Suresh; Bontha, Jagannadha R.; Liu, Jun

    2008-05-06

    This invention pertains to surfactant-templated nanometer-scale porosity of a silica precursor solution and forming a mesoporous material by first forming the silica precursor solution into a preform having a high surface area to volume ratio, then rapid drying or evaporating a solvent from the silica precursor solution. The mesoporous material may be in any geometric form, but is preferably in the form of a film, fiber, powder or combinations thereof. The rapid drying or evaporation of solvent from the solution is accomplished by layer thinning, for example spin casting, liquid drawing, and liquid spraying respectively. Production of a film is by layer thinning, wherein a layer of the silica precursor solution is formed on a surface followed by removal of an amount of the silica precursor solution and leaving a geometrically thinner layer of the silica precursor solution from which the solvent quickly escapes via evaporation. Layer thinning may be by any method including but not limited to squeegeeing and/or spin casting. In powder formation by spray drying, the same conditions of fast drying exists as in spin-casting (as well as in fiber spinning) because of the high surface-area to volume ratio of the product. When a powder is produced by liquid spraying, the particles or micro-bubbles within the powder are hollow spheres with walls composed of mesoporous silica. Mesoporous fiber formation starts with a similar silica precursor solution but with an added pre-polymer making a pituitous mixture that is drawn into a thin strand from which solvent is evaporated leaving the mesoporous fiber(s).

  7. Mesoporous-silica films, fibers, and powders by evaporation

    DOE Patents [OSTI]

    Bruinsma, P.J.; Baskaran, S.; Bontha, J.R.; Liu, J.

    1999-07-13

    This invention pertains to surfactant-templated nanometer-scale porosity of a silica precursor solution and forming a mesoporous material by first forming the silica precursor solution into a preform having a high surface area to volume ratio, then rapid drying or evaporating a solvent from the silica precursor solution. The mesoporous material may be in any geometric form, but is preferably in the form of a film, fiber, powder or combinations thereof. The rapid drying or evaporation of solvent from the solution is accomplished by layer thinning, for example spin casting, liquid drawing, and liquid spraying respectively. Production of a film is by layer thinning, wherein a layer of the silica precursor solution is formed on a surface followed by removal of an amount of the silica precursor solution and leaving a geometrically thinner layer of the silica precursor solution from which the solvent quickly escapes via evaporation. Layer thinning may be by any method including but not limited to squeegeeing and/or spin casting. In powder formation by spray drying, the same conditions of fast drying exists as in spin-casting (as well as in fiber spinning) because of the high surface-area to volume ratio of the product. When a powder is produced by liquid spraying, the particles or micro-bubbles within the powder are hollow spheres with walls composed of mesoporous silica. Mesoporous fiber formation starts with a similar silica precursor solution but with an added pre-polymer making a pituitous mixture that is drawn into a thin strand from which solvent is evaporated leaving the mesoporous fiber(s). 24 figs.

  8. Tank 241-A-105 evaporation estimate, 1970 through 1978

    SciTech Connect (OSTI)

    Allen, G.K.

    1991-09-01

    Tank 241-A-105 was subjected to a severe steam explosion in January 1965 that caused the metal liner on the bottom to bulge upward approximately 8 feet above its concrete foundation. Shortly after this event, radiation was detected in drywells around the tank and it was declared a leaker. Sluicing operations to remove material from the tank began in August 1968 and continued through August 1970. After sluicing was completed, a significant amount of heat generating material still remained in the tank. To keep tank temperatures below operating limits, the water level in the tank was maintained at an approximate depth of 1.5 feet. This practice was continued until January 1979 when it was believed that the contents had decayed sufficiently to discontinue the water addition and put the tank on a portable exhauster system. Recent concern has focused on what portion of this cooling water added to Tank 241-A-105 actually evaporated and how much leaked into the soil during the nine year time period. This report presents the results of a study that estimates the amount of water evaporated from Tank 241-A-105 between 1970 and 1979. The problem was completed in two parts. The first part involved development of a three dimensional heat transfer model which was used to establish the tank heat load. The results of this model were validated against thermocouple data from Tank 241-A-105. The heat removed from the tank by the ventilation air was then used as input to a second computer code, which calculated the water evaporation. Based upon these two models, the amount of water evaporated from Tank 241-A-105, between 1970 and 1979, was between 378,000 and 410,000 gallons. 9 refs., 17 figs., 7 tabs.

  9. Determination of the Evaporation Coefficient of D2O

    SciTech Connect (OSTI)

    Drisdell, Walter S.; Cappa, Christopher D.; Smith, Jared D.; Saykally, Richard J.; Cohen, Ronald C.

    2008-03-26

    The evaporation rate of D{sub 2}O has been determined by Raman thermometry of a droplet train (12-15 {micro}m diameter) injected into vacuum ({approx}10{sup -5} torr). The cooling rate measured as a function of time in vacuum was fit to a model that accounts for temperature gradients between the surface and the core of the droplets, yielding an evaporation coefficient ({gamma}{sub e}) of 0.57 {+-} 0.06. This is nearly identical to that found for H{sub 2}O (0.62 {+-} 0.09) using the same experimental method and model, and indicates the existence of a kinetic barrier to evaporation. The application of a recently developed transition state theory (TST) model suggests that the kinetic barrier is due to librational and hindered translational motions at the liquid surface, and that the lack of an isotope effect is due to competing energetic and entropic factors. The implications of these results for cloud and aerosol particles in the atmosphere are discussed.

  10. Documenting the Effectiveness of Cosorption of Airborne Contaminants by a Field-Installed Active Desiccant System: Final Report - Phase 2D

    SciTech Connect (OSTI)

    Fischer, J

    2003-01-23

    The final report for Phase 1 of this research effort (ORNL/SUB/94-SV004/1) concluded that a significant market opportunity would exist for active desiccant systems if it could be demonstrated that they can remove a significant proportion of common airborne contaminants while simultaneously performing the primary function of dehumidifying a stream of outdoor air or recirculated building air. If the engineering community begins to follow the intent of ASHRAE Standard 62, now part of all major building codes, the outdoor air in many major cities may need to be pre-cleaned before it is introduced into occupied spaces. Common air contaminant cosorption capability would provide a solution to three important aspects of the ASHRAE 62-89 standard that have yet to be effectively addressed by heating, ventilation, and air-conditioning (HVAC) equipment manufacturers: (1) The ASHRAE standard defines acceptable outdoor air quality. If the outdoor air contains unacceptable levels of certain common outdoor air contaminants (e.g., sulfur dioxide, ozone), then the standard requires that these contaminants be removed from the outdoor air stream to reach compliance with the acceptable outdoor air quality guidelines. (2) Some engineers prefer to apply a filtration or prescriptive approach rather than a ventilation approach to solving indoor air quality problems. The ASHRAE standard recognizes this approach provided that the filtration technology exists to remove the gaseous contaminants encountered. The performance of current gaseous filtration technologies is not well documented, and they can be costly to maintain because the life of the filter is limited and the cost is high. Moreover, it is not easy to determine when the filters need changing. In such applications, an additional advantage provided by the active desiccant system would be that the same piece of equipment could control space humidity and provide filtration, even during unoccupied periods, if the active desiccant system

  11. Technical support for authorization of 242-A evaporator campaign 97-2, Hanford Site, Richland, Washington

    SciTech Connect (OSTI)

    Daling, P.M.; Lavender, J.C.

    1997-07-01

    An analysis was performed to determine the acceptability of processing 242-A Evaporator/Crystallizer Campaign 97-2 feed. Inhalation unit liter doses (ULDs) were calculated using the methods and data described in the Tank Waste Remediation System Basis for Interim Operation (TWRS BIO) and 242-A Evaporator/Crystallizer Safety Analysis Report. The ULD calculated for the Campaign 97-2 slurry was found to be less than the TWRS BIO evaporator slurry ULD and so would be within the analyzed safety envelope defined in the TWRS BIO. The Evaporator slurry ULD established in the TWRS BIO and supporting documents was calculated using the bounding source strength defined in the 242-A Evaporator SAR. Consequently, the risks and consequences associated with the Campaign 97-2 slurry would be lower than those already accepted by DOE and documented in the TWRS BIO and 242-A Evaporator SAR. The direct radiation exposures from formation of a liquid pool of Campaign 97-2 slurry were demonstrated to be less than the exposures from a pool formed by bounding source strength evaporator slurry as defined in the 242-A Evaporator SAR. This was demonstrated via a comparison of the Campaign 97-2 slurry composition and the 242-A Evaporator SAR bounding source strength. It was concluded that the direct radiation exposures from Campaign 97-2 slurry would be within the analyzed safety envelope in the 242-A Evaporator SAR.

  12. Enhanced two phase flow in heat transfer systems

    DOE Patents [OSTI]

    Tegrotenhuis, Ward E; Humble, Paul H; Lavender, Curt A; Caldwell, Dustin D

    2013-12-03

    A family of structures and designs for use in devices such as heat exchangers so as to allow for enhanced performance in heat exchangers smaller and lighter weight than other existing devices. These structures provide flow paths for liquid and vapor and are generally open. In some embodiments of the invention, these structures can also provide secondary heat transfer as well. In an evaporate heat exchanger, the inclusion of these structures and devices enhance the heat transfer coefficient of the evaporation phase change process with comparable or lower pressure drop.

  13. Evaporative heat transfer in beds of sensible heat pellets

    SciTech Connect (OSTI)

    Arimilli, R.V.; Moy, C.A.

    1989-03-01

    An experimental study of boiling/evaporative heat transfer from heated spheres in vertical packed beds with downward liquid-vapor flow of Refrigerant-113 was conducted. Surface superheats of 1 to 50{degrees}C, mass flow rates of 1.7 to 5.6 Kg/min, sphere diameters of 1.59 and 2.54 cm, quality (i.e., mass fraction of vapor) of the inlet flow of 0.02 to 1.0, and two surface conditions were considered. Instrumented smooth and rough aluminum spheres were used to measure the heat transfer coefficients under steady state conditions. Heat transfer coefficients were independently determined for each sphere at three values three values of surface superheat. The quantitative results of this extensive experimental study are successfully correlated. The correlation equation for the boiling heat transfer coefficients is presented in terms of a homogeneous model. The correlation may be used in the development of numerical models to simulate the transient thermal performance of packed bed thermal energy storage unit while operating as an evaporator. The boiling of the liquid-vapor flow around the spheres in the packed bed was visually observed with a fiber-optic baroscope and recorded on a videotape. The visualization results showed qualitatively the presence of four distinct flow regimes. One of these occurs under saturated inlet conditions and are referred to as the Low-quality, Medium-quality, and High-quality Regimes. The regimes are discussed in detail in this paper.

  14. On the interface instability during rapid evaporation in microgravity

    SciTech Connect (OSTI)

    Juric, D.

    1997-05-01

    The rapid evaporation of a superheated liquid (vapor explosion) under microgravity conditions is studied by direct numerical simulation. The time-dependent Navier-Stokes and energy equations coupled to the interface dynamics are solved using a two-dimensional finite-difference/front-tracking method. Large interface deformations, topology change, latent heat, surface tension and unequal material properties between the liquid and vapor phases are included in the simulations. A comparison of numerical results to the exact solution of a one-dimensional test problem shows excellent agreement. For the two-dimensional rapid evaporation problem, the vapor volume growth rate and unstable interface dynamics are studied for increasing levels of initial liquid superheat. As the superheat is increased the liquid-vapor interface experiences increasingly unstable energetic growth. These results indicate that heat transfer plays a very important role in the instability mechanism leading to vapor explosions. It is suggested that the Mullins-Sekerka instability could play a role in the instability initiation mechanism.

  15. Primordial Black Holes: Observational characteristics of the final evaporation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ukwatta, T. N.; Stump, D. R.; Linnemann, J. T.; MacGibbon, J. H.; Marinelli, S. S.; Yapici, T.; Tollefson, K.

    2016-07-01

    For many early universe theories predict the creation of Primordial Black Holes (PBHs). PBHs could have masses ranging from the Planck mass to 105 solar masses or higher depending on the size of the universe at formation. A Black Hole (BH) has a Hawking temperature which is inversely proportional to its mass. Hence a sufficiently small BH will quasi-thermally radiate particles at an ever-increasing rate as emission lowers its mass and raises its temperature. Moreover, the final moments of this evaporation phase should be explosive and its description is dependent on the particle physics model. In this work we investigatemore » the final few seconds of BH evaporation, using the Standard Model and incorporating the most recent Large Hadron Collider (LHC) results, and provide a new parameterization for the instantaneous emission spectrum. We calculate for the first time energy-dependent PBH burst light curves in the GeV/TeV energy range. Moreover, we explore PBH burst search methods and potential observational PBH burst signatures. We have found a unique signature in the PBH burst light curves that may be detectable by GeV/TeV gamma-ray observatories such as the High Altitude Water Cerenkov (HAWC) observatory. Finally, the implications of beyond the Standard Model theories on the PBH burst observational characteristics are also discussed, including potential sensitivity of the instantaneous photon detection rate to a squark threshold in the 5–10 TeV range.« less

  16. Glass Development for Treatment of LANL Evaporator Bottoms Waste

    SciTech Connect (OSTI)

    DE Smith; GF Piepel; GW Veazey; JD Vienna; ML Elliott; RK Nakaoka; RP Thimpke

    1998-11-20

    Vitrification is an attractive treatment option for meeting the stabilization and final disposal requirements of many plutonium (Pu) bearing materials and wastes at the Los Alamos National Laboratory (LANL) TA-55 facility, Rocky Flats Environmental Technology Site (RFETS), Hanford, and other Department of Energy (DOE) sites. The Environmental Protection Agency (EPA) has declared that vitrification is the "best demonstrated available technology" for high- level radioactive wastes (HLW) (Federal Register 1990) and has produced a handbook of vitriilcation technologies for treatment of hazardous and radioactive waste (US EPA, 1992). This technology has been demonstrated to convert Pu-containing materials (Kormanos, 1997) into durable (Lutze, 1988) and accountable (Forsberg, 1995) waste. forms with reduced need for safeguarding (McCulhun, 1996). The composition of the Evaporator Bottoms Waste (EVB) at LANL, like that of many other I%-bearing materials, varies widely and is generally unpredictable. The goal of this study is to optimize the composition of glass for EVB waste at LANL, and present the basic techniques and tools for developing optimized glass compositions for other Pu-bearing materials in the complex. This report outlines an approach for glass formulation with fixed property restrictions, using glass property-composition databases. This approach is applicable to waste glass formulation for many variable waste streams and vitrification technologies.. Also reported are the preliminary property data for simulated evaporator bottom glasses, including glass viscosity and glass leach resistance using the Toxicity Characteristic Leaching Procedure (TCLP).

  17. Energy savings from indirect evaporative pre-cooling: Control strategies and commissioning

    SciTech Connect (OSTI)

    Felts, D.; Jump, D.A.

    1998-07-01

    Package rooftop air conditioning units (RTU) with evaporative pre-cooling systems were installed at an Agricultural History Museum and conference center in the northern Sacramento Valley in California, a hot and dry summer climate region. The evaporative pre-coolers serve to extend the economizer range of the RTU's. A commissioning team monitored the performance of the RTU evaporative pre-coolers. The purpose of the monitoring was to determine if changes were warranted to optimize the system's energy efficiency. The commissioning process revealed that the RTU evaporative pre-coolers were being controlled by the economizer control cycle. With this control cycle, the evaporative pre-cooler operates when the outdoor air temperature is falling below the space return air temperature. This means that the pre-cooler will never operate at peak load conditions. The conference center is an assembly occupancy. Building codes require significant levels of outdoor air for ventilation. The evaporative pre-cooler system provides the means to significantly offset the energy requirements for cooling down and heating up this ventilation air. A DOE2 energy simulation analysis indicated that the evaporative pre-cooler could cut energy use by over 50% if it were working correctly. Investigation concludes that in buildings with high outdoor air requirements, evaporative pre-cooling, using building exhaust air as the indirect evaporative cooling source, significantly reduce building energy consumption. This evaporative pre-cooling technology works in any climate, regardless of outdoor conditions, since the return air stream exhausted from the building provides a relatively constant temperature and humidity source for evaporative cooling. An added benefit is that the evaporative pre-cooler heat exchanger recovers heat from the exhausted air stream in cold weather.

  18. Evaporation-powered Motor and Light | U.S. DOE Office of Science...

    Office of Science (SC) Website

    Evaporation-powered Motor and Light Basic Energy Sciences (BES) BES Home About Research Facilities Science Highlights Benefits of BES Funding Opportunities Basic Energy Sciences ...

  19. SERI Desiccant Cooling Test Facility. Status report. Preliminary data on the performance of a rotary parallel-passage silica-gel dehumidifier

    SciTech Connect (OSTI)

    Schultz, K.J.

    1986-04-01

    This report describes the SERI Desiccant Cooling Test Facility. The facility can test bench-scale rotary dehumidifiers over a wide range of controlled conditions. We constructed and installed in the test loop a prototype parallel-passage rotary dehumidifier that has spirally wound polyester tape coated with silica gel. The initial tests gave satisfactory results indicating that approximately 90% of the silica gel was active and the overall Lewis number of the wheel was near unity. The facility has several minor difficulties including an inability to control humidity satisfactorily and nonuniform and highly turbulent inlet velocities. To completely validate the facility requires a range of dehumidifier designs. Several choices are available including constructing a second parallel-passage dehumidifier with the passage spacing more uniform.

  20. Fixture for forming evaporative pattern (EPC) process patterns

    DOE Patents [OSTI]

    Turner, Paul C.; Jordan, Ronald R.; Hansen, Jeffrey S.

    1993-01-01

    A method of casting metal using evaporative pattern casting process patterns in combination with a fixture for creating and maintaining a desired configuration in flexible patterns. A pattern is constructed and gently bent to the curvature of a suitable fixture. String or thin wire, which burns off during casting, is used to tie the pattern to the fixture. The fixture with pattern is dipped in a commercially available refractory wash to prevent metal adherence and sticking to the fixture. When the refractory wash is dry, the fixture and pattern are placed in a flask, and sand is added and compacted by vibration. The pattern remains in position, restrained by the fixture. Metal that is poured directly into the pattern replaces the pattern exactly but does not contact or weld to the fixture due to the protective refractory layer. When solid, the casting is easily separated from the fixture. The fixture can be cleaned for reuse in conventional casting cleaning equipment.

  1. Transparent electrical conducting films by activated reactive evaporation

    DOE Patents [OSTI]

    Bunshah, Rointan; Nath, Prem

    1982-01-01

    Process and apparatus for producing transparent electrical conducting thin films by activated reactive evaporation. Thin films of low melting point metals and alloys, such as indium oxide and indium oxide doped with tin, are produced by physical vapor deposition. The metal or alloy is vaporized by electrical resistance heating in a vacuum chamber, oxygen and an inert gas such as argon are introduced into the chamber, and vapor and gas are ionized by a beam of low energy electrons in a reaction zone between the resistance heater and the substrate. There is a reaction between the ionized oxygen and the metal vapor resulting in the metal oxide which deposits on the substrate as a thin film which is ready for use without requiring post deposition heat treatment.

  2. Multi-scale evaporator architectures for geothermal binary power plants

    SciTech Connect (OSTI)

    Sabau, Adrian S; Nejad, Ali; Klett, James William; Bejan, Adrian

    2016-01-01

    In this paper, novel geometries of heat exchanger architectures are proposed for evaporators that are used in Organic Rankine Cycles. A multi-scale heat exchanger concept was developed by employing successive plenums at several length-scale levels. Flow passages contain features at both macro-scale and micro-scale, which are designed from Constructal Theory principles. Aside from pumping power and overall thermal resistance, several factors were considered in order to fully assess the performance of the new heat exchangers, such as weight of metal structures, surface area per unit volume, and total footprint. Component simulations based on laminar flow correlations for supercritical R134a were used to obtain performance indicators.

  3. Addressing Water Consumption of Evaporative Coolers with Greywater

    SciTech Connect (OSTI)

    Sahai, Rashmi; Shah, Nihar; Phadke, Amol

    2012-07-01

    Evaporative coolers (ECs) provide significant gains in energy efficiency compared to vapor compression air conditioners, but simultaneously have significant onsite water demand. This can be a major barrier to deployment in areas of the world with hot and arid climates. To address this concern, this study determined where in the world evaporative cooling is suitable, the water consumption of ECs in these cities, and the potential that greywater can be used reduce the consumption of potable water in ECs. ECs covered 69percent of the cities where room air conditioners are may be deployed, based on comfort conditions alone. The average water consumption due to ECs was found to be 400 L/household/day in the United States and Australia, with the potential for greywater to provide 50percent this amount. In the rest of the world, the average water consumption was 250 L/household/day, with the potential for greywater to supply 80percent of this amount. Home size was the main factor that contributed to this difference. In the Mediterranean, the Middle East, Northern India, and the Midwestern and Southwestern United States alkalinity levels are high and water used for bleeding will likely contribute significantly to EC water consumption. Although technically feasible, upfront costs for household GW systems are currently high. In both developed and developing parts of the world, however, a direct EC and GW system is cost competitive with conventional vapor compression air conditioners. Moreover, in regions of the world that face problems of water scarcity the benefits can substantially outweigh the costs.

  4. Improvement to Air2Air Technology to Reduce Fresh-Water Evaporative Cooling Loss at Coal-Based Thermoelectric Power Plants

    SciTech Connect (OSTI)

    Ken Mortensen

    2011-12-31

    This program was undertaken to enhance the manufacturability, constructability, and cost of the Air2Air{TM} Water Conservation and Plume Abatement Cooling Tower, giving a validated cost basis and capability. Air2Air{TM} water conservation technology recovers a portion of the traditional cooling tower evaporate. The Condensing Module provides an air-to-air heat exchanger above the wet fill media, extracting the heat from the hot saturated moist air leaving in the cooling tower and condensing water. The rate of evaporate water recovery is typically 10% - 25% annually, depending on the cooling tower location (climate). This program improved the efficiency and cost of the Air2Air{TM} Water Conservation Cooling Tower capability, and led to the first commercial sale of the product, as described.

  5. Steam Oxidation and Chromia Evaporation in Ultra-Supercritical Steam Boilers and Turbines

    SciTech Connect (OSTI)

    Gordon H. Holcomb

    2009-01-01

    U.S. Department of Energy’s goals include power generation from coal at 60% efficiency, which requires steam conditions of up to 760 °C and 340 atm, so-called ultra-supercritical (USC) conditions. Evaporation of protective chromia scales is expected to be a primary corrosion mechanism. A methodology to calculate Cr evaporation rates from chromia scales was developed and combined with Cr diffusion calculations within the alloy (with a constant flux of Cr leaving the alloy from evaporation) to predict Cr concentration profiles and to predict the time until breakaway oxidation. At the highest temperatures and pressures, the time until breakaway oxidation was predicted to be quite short for the turbine blade, and of concern within the steam pipe and the higher temperature portions of the superheater tube. Alloy additions such as Ti may allow for a reduction in evaporation rate with time, mitigating the deleterious effects of chromia evaporation.

  6. Steam oxidation and chromia evaporation in ultrasupercritical steam boilers and turbines

    SciTech Connect (OSTI)

    Holcomb, G.R.

    2009-07-01

    The U.S. Department of Energy's goals include power generation from coal at 60% efficiency, which requires steam conditions of up to 760 {sup o}C and 340 atm, so-called ultrasupercritical conditions. Evaporation of protective chromia scales is a primary corrosion mechanism. A methodology to calculate Cr evaporation rates from chromia scales was developed and combined with Cr diffusion calculations within the alloy (with a constant flux of Cr leaving the alloy from evaporation) to predict Cr concentration profiles and to predict the time until breakaway oxidation. At the highest temperatures and pressures, the time until breakaway oxidation was quite short for the turbine blade, and of concern within the steam pipe and the higher temperature portions of the superheater tube. Alloy additions such as Ti may allow for a reduction in evaporation rate with time, mitigating the deleterious effects of chromia evaporation.

  7. Tetrafluoroethane (R134a) hydrate formation within variable volume reactor accompanied by evaporation and condensation

    SciTech Connect (OSTI)

    Jeong, K.; Choo, Y. S.; Hong, H. J.; Yoon, Y. S.; Song, M. H.

    2015-03-15

    Vast size hydrate formation reactors with fast conversion rate are required for the economic implementation of seawater desalination utilizing gas hydrate technology. The commercial target production rate is order of thousand tons of potable water per day per train. Various heat and mass transfer enhancement schemes including agitation, spraying, and bubbling have been examined to maximize the production capacities in scaled up design of hydrate formation reactors. The present experimental study focused on acquiring basic knowledge needed to design variable volume reactors to produce tetrafluoroethane hydrate slurry. Test vessel was composed of main cavity with fixed volume of 140 ml and auxiliary cavity with variable volume of 0 ∼ 64 ml. Temperatures at multiple locations within vessel and pressure were monitored while visual access was made through front window. Alternating evaporation and condensation induced by cyclic volume change provided agitation due to density differences among water and vapor, liquid and hydrate R134a as well as extended interface area, which improved hydrate formation kinetics coupled with latent heat release and absorption. Influences of coolant temperature, piston stroke/speed, and volume change period on hydrate formation kinetics were investigated. Suggestions of reactor design improvement for future experimental study are also made.

  8. Entropy localization and extensivity in the semiclassical black hole evaporation

    SciTech Connect (OSTI)

    Casini, H.

    2009-01-15

    I aim to quantify the distribution of information in the Hawking radiation and inside the black hole in the semiclassical evaporation process. The structure of relativistic quantum field theory does not allow one to define a localized entropy unambiguously, but rather forces one to consider the shared information (mutual information) between two different regions of space-time. Using this tool, I first show that the entropy of a thermal gas at the Unruh temperature underestimates the actual amount of (shared) information present in a region of the Rindler space. Then, I analyze the mutual information between the black hole and the late time radiation region. A well-known property of the entropy implies that this is monotonically increasing with time. This means that in the semiclassical picture it is not possible to recover the eventual purity of the initial state in the final Hawking radiation through subtle correlations established during the whole evaporation period, no matter the interactions present in the theory. I find extensivity of the entropy as a consequence of a reduction to a two dimensional conformal problem in a simple approximation. However, the extensivity of information in the radiation region in a full four dimensional calculation seems not to be guaranteed on general grounds. I also analyze the localization of shared information inside the black hole finding that a large amount of it is contained in a small, approximately flat region of space-time near the point where the horizon begins. This gives place to large violations of the entropy bounds. I show that this problem is not eased by backscattering effects and argue that a breaking of conformal invariance is necessary to delocalize the entropy. Finally, I indicate that the mutual information could lead to a way to understand the Bekenstein-Hawking black hole entropy which does not require a drastic reduction in degrees of freedom in order to regulate the entanglement entropy. On the contrary

  9. A Novel Absorption Cycle for Combined Water Heating, Dehumidification, and Evaporative Cooling

    SciTech Connect (OSTI)

    CHUGH, Devesh; Gluesenkamp, Kyle R; Abdelaziz, Omar; Moghaddam, Saeed

    2014-01-01

    In this study, development of a novel system for combined water heating, dehumidification, and space evaporative cooling is discussed. Ambient water vapor is used as a working fluid in an open system. First, water vapor is absorbed from an air stream into an absorbent solution. The latent heat of absorption is transferred into the process water that cools the absorber. The solution is then regenerated in the desorber, where it is heated by a heating fluid. The water vapor generated in the desorber is condensed and its heat of phase change is transferred to the process water in the condenser. The condensed water can then be used in an evaporative cooling process to cool the dehumidified air exiting the absorber, or it can be drained if primarily dehumidification is desired. Essentially, this open absorption cycle collects space heat and transfers it to process water. This technology is enabled by a membrane-based absorption/desorption process in which the absorbent is constrained by hydrophobic vapor-permeable membranes. Constraining the absorbent film has enabled fabrication of the absorber and desorber in a plate-and-frame configuration. An air stream can flow against the membrane at high speed without entraining the absorbent, which is a challenge in conventional dehumidifiers. Furthermore, the absorption and desorption rates of an absorbent constrained by a membrane are greatly enhanced. Isfahani and Moghaddam (Int. J. Heat Mass Transfer, 2013) demonstrated absorption rates of up to 0.008 kg/m2s in a membrane-based absorber and Isfahani et al. (Int. J. Multiphase Flow, 2013) have reported a desorption rate of 0.01 kg/m2s in a membrane-based desorber. The membrane-based architecture also enables economical small-scale systems, novel cycle configurations, and high efficiencies. The absorber, solution heat exchanger, and desorber are fabricated on a single metal sheet. In addition to the open arrangement and membrane-based architecture, another novel feature of the

  10. Heat exchanger efficiently operable alternatively as evaporator or condenser

    DOE Patents [OSTI]

    Ecker, Amir L.

    1981-01-01

    A heat exchanger adapted for efficient operation alternatively as evaporator or condenser and characterized by flexible outer tube having a plurality of inner conduits and check valves sealingly disposed within the outer tube and connected with respective inlet and outlet master flow conduits and configured so as to define a parallel flow path for a first fluid such as a refrigerant when flowed in one direction and to define a serpentine and series flow path for the first fluid when flowed in the opposite direction. The flexible outer tube has a heat exchange fluid, such as water, flowed therethrough by way of suitable inlet and outlet connections. The inner conduits and check valves form a package that is twistable so as to define a spiral annular flow path within the flexible outer tube for the heat exchange fluid. The inner conduits have thin walls of highly efficient heat transfer material for transferring heat between the first and second fluids. Also disclosed are specific materials and configurations.

  11. Waste characterization for radioactive liquid waste evaporators at Argonne National Laboratory - West.

    SciTech Connect (OSTI)

    Christensen, B. D.

    1999-02-15

    Several facilities at Argonne National Laboratory - West (ANL-W) generate many thousand gallons of radioactive liquid waste per year. These waste streams are sent to the AFL-W Radioactive Liquid Waste Treatment Facility (RLWTF) where they are processed through hot air evaporators. These evaporators remove the liquid portion of the waste and leave a relatively small volume of solids in a shielded container. The ANL-W sampling, characterization and tracking programs ensure that these solids ultimately meet the disposal requirements of a low-level radioactive waste landfill. One set of evaporators will process an average 25,000 gallons of radioactive liquid waste, provide shielding, and reduce it to a volume of six cubic meters (container volume) for disposal. Waste characterization of the shielded evaporators poses some challenges. The process of evaporating the liquid and reducing the volume of waste increases the concentrations of RCIU regulated metals and radionuclides in the final waste form. Also, once the liquid waste has been processed through the evaporators it is not possible to obtain sample material for characterization. The process for tracking and assessing the final radioactive waste concentrations is described in this paper, The structural components of the evaporator are an approved and integral part of the final waste stream and they are included in the final waste characterization.

  12. Simulated Waste Testing Of Glycolate Impacts On The 2H-Evaporator System

    SciTech Connect (OSTI)

    Martino, C. J.

    2013-08-13

    Glycolic acid is being studied as a total or partial replacement for formic acid in the Defense Waste Processing Facility (DWPF) feed preparation process. After implementation, the recycle stream from DWPF back to the high-level waste tank farm will contain soluble sodium glycolate. Most of the potential impacts of glycolate in the tank farm were addressed via a literature review, but several outstanding issues remained. This report documents the non-radioactive simulant tests impacts of glycolate on storage and evaporation of Savannah River Site high-level waste. The testing for which non-radioactive simulants could be used involved the following: the partitioning of glycolate into the evaporator condensate, the impacts of glycolate on metal solubility, and the impacts of glycolate on the formation and dissolution of sodium aluminosilicate scale within the evaporator. The following are among the conclusions from this work: Evaporator condensate did not contain appreciable amounts of glycolate anion. Of all tests, the highest glycolate concentration in the evaporator condensate was 0.38 mg/L. A significant portion of the tests had glycolate concentration in the condensate at less than the limit of quantification (0.1 mg/L). At ambient conditions, evaporator testing did not show significant effects of glycolate on the soluble components in the evaporator concentrates. Testing with sodalite solids and silicon containing solutions did not show significant effects of glycolate on sodium aluminosilicate formation or dissolution.

  13. Evaporation and NARS Nitric Acid Mass Balance Summary: 2000--2005

    SciTech Connect (OSTI)

    B.D. Kreutzberg; R.L. Ames; K.M. Hansel

    2005-11-01

    A compilation of the historical nitric acid processing data for the evaporation and nitric acid recycle system (NARS) in TA-55 has provided general acid mass balance trends, as well as the location of missing information in both the evaporation system and NARS data logs. The data were accumulated during the calendar years 2000 to 2005. After making a number of processing assumptions, the empirical system information was used to create an interactive spreadsheet that predicts, with moderate accuracy, some of the various stream variables for the combined evaporation and acid recycle processes. Empirical data and interactive calculations were compared to an Aspen Plus{trademark} simulation of the process.

  14. Field Performance of a Slimline Turbomist Evaporator under Southeastern U. S. Climate Conditions

    SciTech Connect (OSTI)

    Sappington, F.C.

    2003-12-15

    A recent study of evaporation technologies for treating F- and H-area groundwater contaminated with radionuclides and metals (Flach 2002) suggested that spray evaporation might be a viable alternative or supplemental technique for managing tritiated groundwater at the Mixed Waste Management Facility. The particular technology of interest in this study is the Slimline Manufacturing Ltd. Turbo-Mist Evaporator, which uses a powerful blower and high-pressure spray nozzles to propel a fine mist into the air at high air and water flowrates.

  15. Evaporative cooling of microscopic water droplets in vacuo: Molecular dynamics simulations and kinetic gas theory

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Schlesinger, Daniel; Sellberg, Jonas A.; Nilsson, Anders; Pettersson, Lars G. M.

    2016-03-22

    In the present study, we investigate the process of evaporative cooling of nanometer-sized droplets in vacuum using molecular dynamics simulations with the TIP4P/2005 water model. The results are compared to the temperature evolution calculated from the Knudsen theory of evaporation which is derived from kinetic gas theory. The calculated and simulation results are found to be in very good agreement for an evaporation coefficient equal to unity. Lastly, our results are of interest to experiments utilizing droplet dispensers as well as to cloud micro-physics.

  16. Evaporator Campaigns Create 300,000 Gallons of Double-Shell Tank...

    Office of Environmental Management (EM)

    ... The maintenance team also replaced two half-ton crane hoists in the evaporator canyon and worked more than 50 preventive-maintenance tasks to prepare for the operating campaign. ...

  17. The thermophysics of electron beam evaporative sources: Annual report, 21 April 1986-20 April 1987

    SciTech Connect (OSTI)

    Self, S.A.

    1987-06-01

    This report presents work accomplished in preparing equipment for study of evaporative electron beam sources. Faraday cups and x-ray imaging equipment were developed. Due to other commitments, the future of this work is uncertain. (JDH)

  18. Dew Point Evaporative Comfort Cooling: Report and Summary Report

    SciTech Connect (OSTI)

    Dean, J.; Herrmann, L.; Kozubal, E.; Geiger, J.; Eastment, M.; Slayzak, S.

    2012-11-01

    The project objective was to demonstrate the capabilities of the high-performance multi-staged IEC technology and its ability to enhance energy efficiency and interior comfort in dry climates, while substantially reducing electric-peak demand. The project was designed to test 24 cooling units in five commercial building types at Fort Carson Army Base in Colorado Springs, Colorado.

  19. Effect of argon gas flow rate on properties of film electrodes prepared by thermal vacuum evaporation from synthesized Cu{sub 2}SnSe{sub 3} source

    SciTech Connect (OSTI)

    Sabli, Nordin; Talib, Zainal Abidin; Yunus, Wan Mahmood Mat; Zainal, Zulkarnain; Hilal, Hikmat S.; Fujii, Masatoshi

    2014-03-05

    This work describes a new technique to enhance photoresponse of metal chalcogenide-based semiconductor film electrodes deposited by thermal vacuum evaporation under argon gas flow from synthesized Cu{sub 2}SnSe{sub 3} sources. SnSe formation with Cu-doped was obtained under higher argon gas flow rate (V{sub A} = 25 cm{sup 3}/min). Higher value of photoresponse was observed for films deposited under V{sub A} = 25 cm{sup 3}/min which was 9.1%. This finding indicates that Cu atoms inside the SnSe film were important to increase carrier concentrations that promote higher photoresponse.

  20. LITERATURE REVIEW ON IMPACT OF GLYCOLATE ON THE 2H EVAPORATOR AND THE EFFLUENT TREATMENT FACILITY

    SciTech Connect (OSTI)

    Adu-Wusu, K.

    2012-05-10

    Glycolic acid (GA) is being studied as an alternate reductant in the Defense Waste Processing Facility (DWPF) feed preparation process. It will either be a total or partial replacement for the formic acid that is currently used. A literature review has been conducted on the impact of glycolate on two post-DWPF downstream systems - the 2H Evaporator system and the Effluent Treatment Facility (ETF). The DWPF recycle stream serves as a portion of the feed to the 2H Evaporator. Glycolate enters the evaporator system from the glycolate in the recycle stream. The overhead (i.e., condensed phase) from the 2H Evaporator serves as a portion of the feed to the ETF. The literature search revealed that virtually no impact is anticipated for the 2H Evaporator. Glycolate may help reduce scale formation in the evaporator due to its high complexing ability. The drawback of the solubilizing ability is the potential impact on the criticality analysis of the 2H Evaporator system. It is recommended that at least a theoretical evaluation to confirm the finding that no self-propagating violent reactions with nitrate/nitrites will occur should be performed. Similarly, identification of sources of ignition relevant to glycolate and/or update of the composite flammability analysis to reflect the effects from the glycolate additions for the 2H Evaporator system are in order. An evaluation of the 2H Evaporator criticality analysis is also needed. A determination of the amount or fraction of the glycolate in the evaporator overhead is critical to more accurately assess its impact on the ETF. Hence, use of predictive models like OLI Environmental Simulation Package Software (OLI/ESP) and/or testing are recommended for the determination of the glycolate concentration in the overhead. The impact on the ETF depends on the concentration of glycolate in the ETF feed. The impact is classified as minor for feed glycolate concentrations {le} 33 mg/L or 0.44 mM. The ETF unit operations that will have

  1. Applicability of post-ionization theory to laser-assisted field evaporation of magnetite

    SciTech Connect (OSTI)

    Schreiber, Daniel K.; Chiaramonti, Ann N.; Gordon, Lyle M.; Kruska, Karen

    2014-12-15

    Analysis of the mean Fe ion charge state from laser-assisted field evaporation of magnetite (Fe3O4) reveals unexpected trends as a function of laser pulse energy that break from conventional post-ionization theory for metals. For Fe ions evaporated from magnetite, the effects of post-ionization are partially offset by the increased prevalence of direct evaporation into higher charge states with increasing laser pulse energy. Therefore the final charge state is related to both the field strength and the laser pulse energy, despite those variables themselves being intertwined when analyzing at a constant detection rate. Comparison of data collected at different base temperatures also show that the increased prevalence of Fe2+ at higher laser energies is possibly not a direct thermal effect. Conversely, the ratio of 16O+:16O2+ is well-correlated with field strength and unaffected by laser pulse energy on its own, making it a better overall indicator of the field evaporation conditions than the mean Fe charge state. Plotting the normalized field strength versus laser pulse energy also elucidates a non-linear dependence, in agreement with previous observations on semiconductors, that suggests a field-dependent laser absorption efficiency. Together these observations demonstrate that the field evaporation process for laser-pulsed oxides exhibits fundamental differences from metallic specimens that cannot be completely explained by post-ionization theory. Further theoretical studies, combined with detailed analytical observations, are required to understand fully the field evaporation process of non-metallic samples.

  2. Projected Benefits of New Residential Evaporative Cooling Systems: Progress Report #2

    SciTech Connect (OSTI)

    Kutscher, C.; Eastment, M.; Hancock, E.; Reeves, P.

    2006-10-01

    The use of conventional evaporative cooling has rapidly declined in the United States despite the fact that it has high potential for energy savings in dry climates. Evaporative systems are very competitive in terms of first cost and provide significant reductions in operating energy use, as well as peak-load reduction benefits. Significant market barriers still remain and can be addressed through improved systems integration. This report investigates the first of these approaches, exploring innovative components. The U.S. Department of Energy (DOE) Building America research teams are investigating the use of two promising new pieces of residential cooling equipment that employ evaporative cooling as a part of their system design. The OASys unit, which is a combination of direct and indirect evaporative cooling stages developed by Davis Energy Group (DEG) and manufactured by Speakman CRS, is used to ultimately provide outside air to the living space. The outdoor air provided is indirectly and directly evaporatively cooled in two stages to a condition that can be below the wet-bulb (wb) temperature of the outside air, thus outperforming a conventional single-stage direct evaporative cooler.

  3. Enhanced Micellar Catalysis LDRD.

    SciTech Connect (OSTI)

    Betty, Rita G.; Tucker, Mark David; Taggart, Gretchen; Kinnan, Mark K.; Glen, Crystal Chanea; Rivera, Danielle; Sanchez, Andres; Alam, Todd Michael

    2012-12-01

    The primary goals of the Enhanced Micellar Catalysis project were to gain an understanding of the micellar environment of DF-200, or similar liquid CBW surfactant-based decontaminants, as well as characterize the aerosolized DF-200 droplet distribution and droplet chemistry under baseline ITW rotary atomization conditions. Micellar characterization of limited surfactant solutions was performed externally through the collection and measurement of Small Angle X-Ray Scattering (SAXS) images and Cryo-Transmission Electron Microscopy (cryo-TEM) images. Micellar characterization was performed externally at the University of Minnesota's Characterization Facility Center, and at the Argonne National Laboratory Advanced Photon Source facility. A micellar diffusion study was conducted internally at Sandia to measure diffusion constants of surfactants over a concentration range, to estimate the effective micelle diameter, to determine the impact of individual components to the micellar environment in solution, and the impact of combined components to surfactant phase behavior. Aerosolized DF-200 sprays were characterized for particle size and distribution and limited chemical composition. Evaporation rates of aerosolized DF-200 sprays were estimated under a set of baseline ITW nozzle test system parameters.

  4. Arabidopsis AtSerpin1, Crystal Structure and in Vivo Interaction with Its Target Protease RESPONSIVE TO DESICCATION-21 (RD21)

    SciTech Connect (OSTI)

    Lampl, Nardy; Budai-Hadrian, Ofra; Davydov, Olga; Joss, Tom V.; Harrop, Stephen J.; Curmi, Paul M.G.; Roberts, Thomas H.; Fluhr, Robert

    2010-05-25

    In animals, protease inhibitors of the serpin family are associated with many physiological processes, including blood coagulation and innate immunity. Serpins feature a reactive center loop (RCL), which displays a protease target sequence as a bait. RCL cleavage results in an irreversible, covalent serpin-protease complex. AtSerpin1 is an Arabidopsis protease inhibitor that is expressed ubiquitously throughout the plant. The x-ray crystal structure of recombinant AtSerpin1 in its native stressed conformation was determined at 2.2 {angstrom}. The electrostatic surface potential below the RCL was found to be highly positive, whereas the breach region critical for RCL insertion is an unusually open structure. AtSerpin1 accumulates in plants as a full-length and a cleaved form. Fractionation of seedling extracts by nonreducing SDS-PAGE revealed the presence of an additional slower migrating complex that was absent when leaves were treated with the specific cysteine protease inhibitor l-trans-epoxysuccinyl-l-leucylamido (4-guanidino)butane. Significantly, RESPONSIVE TO DESICCATION-21 (RD21) was the major protease labeled with the l-trans-epoxysuccinyl-l-leucylamido (4-guanidino)butane derivative DCG-04 in wild type extracts but not in extracts of mutant plants constitutively overexpressing AtSerpin1, indicating competition. Fractionation by nonreducing SDS-PAGE followed by immunoblotting with RD21-specific antibody revealed that the protease accumulated both as a free enzyme and in a complex with AtSerpin1. Importantly, both RD21 and AtSerpin1 knock-out mutants lacked the serpin-protease complex. The results establish that the major Arabidopsis plant serpin interacts with RD21. This is the first report of the structure and in vivo interaction of a plant serpin with its target protease.

  5. Effect of lubricant on spray evaporation heat transfer performance of R-134a and R-22 in tube bundles

    SciTech Connect (OSTI)

    Moeykens, S.A.; Pate, M.B.

    1996-11-01

    This study evaluates the effects of lubricant on spray evaporation heat transfer performance. Tests were conducted with refrigerant R-134a and triangular-pitch tube bundles made from enhanced-condensation, enhanced-boiling, low-finned, and plain-surface tubes. A 340-SUS polyol-ester (POE) oil was used for the R-134a testing because this lubricant is being integrated into industry for use with this refrigerant. Refrigerant was sprayed onto the tube bundles with low-pressure-drop, wide-angle nozzles located directly above the bundle. Collector testing was conducted with both R-134a and R-22 to determine the percentage of refrigerant contacting the tue bundle. It was found that small concentrations of the polyol-ester lubricant yielded significant improvement in the heat transfer performance of R-134a. The shell-side heat transfer coefficient was more dependent on lubricant concentration than on film-feed supply rate within the range of the respective parameters evaluated in this study. As expected, pure R-22 results show higher heat transfer coefficients than those obtained with pure R-134a at the same saturation temperature of 2.0 C (35.6 F).

  6. Laboratory studies of 2H evaporator scale dissolution in dilute nitric acid

    SciTech Connect (OSTI)

    Oji, L.

    2014-09-23

    The rate of 2H evaporator scale solids dissolution in dilute nitric acid has been experimentally evaluated under laboratory conditions in the SRNL shielded cells. The 2H scale sample used for the dissolution study came from the bottom of the evaporator cone section and the wall section of the evaporator cone. The accumulation rate of aluminum and silicon, assumed to be the two principal elemental constituents of the 2H evaporator scale aluminosilicate mineral, were monitored in solution. Aluminum and silicon concentration changes, with heating time at a constant oven temperature of 90 deg C, were used to ascertain the extent of dissolution of the 2H evaporator scale mineral. The 2H evaporator scale solids, assumed to be composed of mostly aluminosilicate mineral, readily dissolves in 1.5 and 1.25 M dilute nitric acid solutions yielding principal elemental components of aluminum and silicon in solution. The 2H scale dissolution rate constant, based on aluminum accumulation in 1.5 and 1.25 M dilute nitric acid solution are, respectively, 9.21E-04 ± 6.39E-04 min{sup -1} and 1.07E-03 ± 7.51E-05 min{sup -1}. Silicon accumulation rate in solution does track the aluminum accumulation profile during the first few minutes of scale dissolution. It however diverges towards the end of the scale dissolution. This divergence therefore means the aluminum-to-silicon ratio in the first phase of the scale dissolution (non-steady state conditions) is different from the ratio towards the end of the scale dissolution. Possible causes of this change in silicon accumulation in solution as the scale dissolution progresses may include silicon precipitation from solution or the 2H evaporator scale is a heterogeneous mixture of aluminosilicate minerals with several impurities. The average half-life for the decomposition of the 2H evaporator scale mineral in 1.5 M nitric acid is 12.5 hours, while the half-life for the decomposition of the 2H evaporator scale in 1.25 M nitric acid is 10

  7. Analysis Of 2H-Evaporator Scale Pot Bottom Sample [HTF-13-11-28H

    SciTech Connect (OSTI)

    Oji, L. N.

    2013-07-15

    Savannah River Remediation (SRR) is planning to remove a buildup of sodium aluminosilicate scale from the 2H-evaporator pot by loading and soaking the pot with heated 1.5 M nitric acid solution. Sampling and analysis of the scale material from the 2H evaporator has been performed so that the evaporator can be chemically cleaned beginning July of 2013. Historically, since the operation of the Defense Waste Processing Facility (DWPF), silicon in the DWPF recycle stream combines with aluminum in the typical tank farm supernate to form sodium aluminosilicate scale mineral deposits in the 2H-evaporator pot and gravity drain line. The 2H-evaporator scale samples analyzed by Savannah River National Laboratory (SRNL) came from the bottom cone sections of the 2H-evaporator pot. The sample holder from the 2H-evaporator wall was virtually empty and was not included in the analysis. It is worth noting that after the delivery of these 2H-evaporator scale samples to SRNL for the analyses, the plant customer determined that the 2H evaporator could be operated for additional period prior to requiring cleaning. Therefore, there was no need for expedited sample analysis as was presented in the Technical Task Request. However, a second set of 2H evaporator scale samples were expected in May of 2013, which would need expedited sample analysis. X-ray diffraction analysis (XRD) confirmed the bottom cone section sample from the 2H-evaporator pot consisted of nitrated cancrinite, (a crystalline sodium aluminosilicate solid), clarkeite and uranium oxide. There were also mercury compound XRD peaks which could not be matched and further X-ray fluorescence (XRF) analysis of the sample confirmed the existence of elemental mercury or mercuric oxide. On ''as received'' basis, the scale contained an average of 7.09E+00 wt % total uranium (n = 3; st.dev. = 8.31E-01 wt %) with a U-235 enrichment of 5.80E-01 % (n = 3; st.dev. = 3.96E-02 %). The measured U-238 concentration was 7.05E+00 wt % (n=3, st

  8. Preliminary experimental studies with seawater on OTEC spout evaporator thermal effectiveness and phase transition in upcomer

    SciTech Connect (OSTI)

    Sonwalkar, N.; Larsen-Basse, J.

    1987-01-01

    An experimental open-cycle ocean thermal energy conversion (OC-OTEC) test facility has been erected to perform spout evaporator experiments with seawater. The facility, located at Ke-ahole Point, Kona, Hawaii, consists of a spout evaporator, a spray condenser and an on-line deaerator. Warm seawater at 25-27/sup 0/C from 8 m depth and cold deep seawater at 7-10/sup 0/C from 580 m depth is available throughout the year to the facility. The results of thermal effectiveness tests are reported. The error due to instrumental uncertainties in thermal effectiveness measurements has been estimated to be of the order +-5.5 percent. The effect of design parameters; spout height, spout diameter and liquid loading on thermal effectiveness have been observed and compared with the existing theoretical predictions. A modified thermodynamic approach is proposed to evaluate average heat transfer characteristics of spout evaporators using a three component heat transfer coefficient approach. It adequately describes heat transfer characteristics of the spout evaporator under study. Results essentially agree with data obtained by others for fresh water, but clearly indicate the need for improvement of the existing model to take into account a number of identified factors associated with the real life OC-OTEC conditions, such as the transience in evaporator performance associated with the ocean-generated flow and pressure fluctuations and effects of noncondensable gases.

  9. Evaporation system and method for gas jet deposition of thin film materials

    DOE Patents [OSTI]

    Schmitt, Jerome J.; Halpern, Bret L.

    1994-01-01

    A method and apparatus for depositing thin films of materials such as metals, oxides and nitrides at low temperature relies on a supersonic free jet of inert carrier gas to transport vapor species generated from an evaporation source to the surface of a substrate. Film deposition vapors are generated from solid film precursor materials, including those in the form of wires or powders. The vapor from these sources is carried downstream in a low pressure supersonic jet of inert gas to the surface of a substrate where the vapors deposit to form a thin film. A reactant gas can be introduced into the gas jet to form a reaction product with the evaporated material. The substrate can be moved from the gas jet past a gas jet containing a reactant gas in which a discharge has been generated, the speed of movement being sufficient to form a thin film which is chemically composed of the evaporated material and reactant gases.

  10. Spallation process with simultaneous multi-particle emission in nuclear evaporation

    SciTech Connect (OSTI)

    Santos, B. M.

    2013-05-06

    High energy probes have been used currently to explore nuclear reaction mechanism and nuclear structure. The spallation process governs the reaction process around 1 GeV energy regime. A new aspect introduced here to describe the nuclear reaction is the in-medium nucleonnucleon collision framework. The nucleon-nucleon scattering is kinematically treated by using an effective mass to represent the nuclear binding. In respect to the evaporation phase of the reaction, we introduce the simultaneous particles emission decay. This process becomes important due to the rise of new channels at high excitation energy regime of the compound nucleus. As results, the particles yields in the rapid and evaporation phases are obtained and compared to experimental data. The effect and relevance of these simultaneous emission processes in the evaporation chain is also discussed.

  11. EMRTC Report RF 10-13: Application to LANL Evaporator Nitrate Salts

    Office of Environmental Management (EM)

    Amount of Zeolite Required to Meet the Constraints Established by the EMRTC Report RF 10-13: Application to LANL Evaporator Nitrate Salts 5/8/2012 LANL-Carlsbad Office Difficult Waste Team P2010-3306 Amount of Zeolite Required to Meet the Constraints Established by the EMRTC Report RF 10- 13: Application to LANL Evaporator Nitrate Salts 2 Purpose: The following document was developed in support of the Los Alamos National Laboratory Transuranic Program (LTP) by the LANL-Carlsbad Office, Difficult

  12. Simulation and economic evaluation of a solar evaporation system for concentrating sodium chloride brines

    SciTech Connect (OSTI)

    Smith, M.K.; Newell, T.A. )

    1991-01-01

    An hourly simulation program has been developed for detailed modelin of an evaporation surface (ES) and an evaporation pond (EP) for reconcentration of a solar pond's (SP's) surface brine. The results are relavant to other systems in which it is desirable to concentrate a brine. The simulation results are used in three ways: first, for general comparison of brine reconcentration performance for a variety of locations; second, development of an ES design method based on long term monthly averaged weather data; and third, an economic comparison between ESs and EPs. The results show that regions with moderate to high precipitation favor ESs over EPs. Dry climates will generally favor EPs for brine reconcentration.

  13. Comparison of Cf-252 Thin-Film Sources Prepared by Evaporation or Self-Transfer

    SciTech Connect (OSTI)

    Algutifan, Noor J; Sherman, Steven R; Alexander, Charles W

    2015-01-01

    Californium-252 (Z = 98) is valued as a potent neutron source due to its spontaneous fission decay path. Thin film sources containing Cf-252 were prepared by two techniques: evaporation and self-transfer. The sources were analyzed by alpha and gamma spectroscopy. Results indicate that self-transfer sources exhibit less alpha energy straggling and energy loss than evaporative sources. Fission fragments may also self-transfer, and sources made by self-transfer may need some decay time to reach radioactive equilibrium.

  14. Comparison of Cf-252 thin-film sources prepared by evaporation or self-transfer

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Algutifan, Noor J.; Sherman, Steven R.; Alexander, Charles W.

    2014-11-29

    Californium-252 (Z = 98) is valued as a potent neutron source due to its spontaneous fission decay path. Thin film sources containing Cf-252 were prepared by two techniques: evaporation and self-transfer. The sources were analyzed by alpha and gamma spectroscopy. Results indicate that self-transfer sources exhibit less alpha energy straggling and energy loss than evaporative sources. Fission fragments may also self-transfer, and sources made by self-transfer may need some decay time to reach radioactive equilibrium.

  15. Heat transfer and flow resistance of a shell and plate-type evaporator

    SciTech Connect (OSTI)

    Uehara, H.; Stuhltraeger, E.; Miyara, A.; Murakami, H.; Miyazaki, K.

    1997-05-01

    The performance test of a shell-and-plate-type evaporator designed for OTEC plants, geothermal power plants, and heat pump systems is reported. This evaporator contains 30 plates with a unit area of 0.813 m{sup 2}, coated with aluminum powder on the working fluid side. Freon 22 is used as working fluid. Results show an overall heat transfer coefficient of about 5,000 W/(m{sup 2}K) when the heating water velocity is 1M/s. The mean boiling heat transfer coefficient is compared with a precious correlation proposed by Nakaoka and Uehara (1988). The water-side pressure loss is also reported.

  16. Demolition of the waste evaporator facility at Oak Ridge National Laboratory

    SciTech Connect (OSTI)

    Mandry, G.J. [Lockheed Martin Energy Systems, Inc., Oak Ridge, TN (United States); Becker, C.L. [Allied Technology Group, Inc., Oak Ridge, TN (United States)

    1997-08-01

    Lockheed Martin Energy Systems, in conjunction with Allied Technology Group, Inc., successfully executed the decommissioning of a former waste evaporator facility at ONRL. This project was conducted as a non-time critical removal action under CERCLA. The decommissioning alternative selected for the Waste Evaporator Facility was partial dismantlement. This alternative provided for the demolition of all above-grade structures; concrete which did not exceed pre-established radiological levels were eligible for placement in the below-grade portion of the facility. This project demonstrated a coordinated team approach that allowed the successful completion of one of the first full-scale decommissioning projects at ORNL.

  17. Laboratory Evaporation Testing Of Hanford Waste Treatment Plant Low Activity Waste Off-Gas Condensate Simulant

    SciTech Connect (OSTI)

    Adamson, Duane J.; Nash, Charles A.; McCabe, Daniel J.; Crawford, Charles L.; Wilmarth, William R.

    2014-01-27

    The Hanford Waste Treatment and Immobilization Plant (WTP) Low Activity Waste (LAW) vitrification facility will generate an aqueous condensate recycle stream, LAW Off-Gas Condensate, from the off-gas system. The baseline plan for disposition of this stream is to send it to the WTP Pretreatment Facility, where it will be blended with LAW, concentrated by evaporation and recycled to the LAW vitrification facility again. Alternate disposition of this stream would eliminate recycling of problematic components, and would enable de-coupled operation of the LAW melter and the Pretreatment Facilities. Eliminating this stream from recycling within WTP would also decrease the LAW vitrification mission duration and quantity of canistered glass waste forms. This LAW Off-Gas Condensate stream contains components that are volatile at melter temperatures and are problematic for the glass waste form. Because this stream recycles within WTP, these components accumulate in the Condensate stream, exacerbating their impact on the number of LAW glass containers that must be produced. Approximately 32% of the sodium in Supplemental LAW comes from glass formers used to make the extra glass to dilute the halides to be within acceptable concentration ranges in the LAW glass. Diverting the stream reduces the halides in the recycled Condensate and is a key outcome of this work. Additionally, under possible scenarios where the LAW vitrification facility commences operation prior to the WTP Pretreatment facility, identifying a disposition path becomes vitally important. This task examines the impact of potential future disposition of this stream in the Hanford tank farms, and investigates auxiliary evaporation to enable another disposition path. Unless an auxiliary evaporator is used, returning the stream to the tank farms would require evaporation in the 242-A evaporator. This stream is expected to be unusual because it will be very high in corrosive species that are volatile in the melter

  18. Results from evaporation tests to support the MWTF heat removal system design

    SciTech Connect (OSTI)

    Crea, B.A.

    1994-12-22

    An experimental tests program was conducted to measure the evaporative heat removal from the surface of a tank of simulated waste. The results contained in this report constitute definition design data for the latest heat removal function of the MWTF primary ventilation system.

  19. AN-107 (C) Simulant Bench-Scale LAW Evaporation with Organic Regulatory Analysis

    SciTech Connect (OSTI)

    Saito, H.H.

    2001-05-15

    The overall objective of this work is to develop preliminary operating data including expected concentration endpoints using a C waste envelope simulant. The data is to be used for the preliminary Hanford RPP flow sheet development and LAW Melter Feed Evaporator design.

  20. Influence of instrument conditions on the evaporation behavior of uranium dioxide with UV laser-assisted atom probe tomography

    SciTech Connect (OSTI)

    Valderrama, B.; Henderson, H.B.; Gan, J.; Manuel, M.V.

    2015-04-01

    Atom probe tomography (APT) provides the ability to detect subnanometer chemical variations spatially, with high accuracy. However, it is known that compositional accuracy can be affected by experimental conditions. A study of the effect of laser energy, specimen base temperature, and detection rate is performed on the evaporation behavior of uranium dioxide (UO2). In laser-assisted mode, tip geometry and standing voltage also contribute to the evaporation behavior. In this investigation, it was determined that modifying the detection rate and temperature did not affect the evaporation behavior as significantly as laser energy. It was also determined that three laser evaporation regimes are present in UO2. Very low laser energy produces a behavior similar to DC-field evaporation, moderate laser energy produces the desired laser-assisted field evaporation characteristic and high laser energy induces thermal effects, negatively altering the evaporation behavior. The need for UO2 to be analyzed under moderate laser energies to produce accurate stoichiometry distinguishes it from other oxides. The following experimental conditions providing the best combination of mass resolving power, accurate stoichiometry, and uniform evaporation behavior: 50 K, 10 pJ laser energy, a detection rate of 0.003 atoms per pulse, and a 100 kHz repetition rate.

  1. Vapor pressure and evaporation rate of certain heat-resistant compounds in a vacuum at high temperatures

    SciTech Connect (OSTI)

    Bolgar, A.S.; Verkhoglyadova, T.S.; Samsonov, G.V.

    1985-02-01

    The vapor pressure and evaporation rate of borides of titanium, zirconium, and chrome and of strontium and carbides of titanium, zirconium, and chrome, molybdenum silicide and nitrides of titanium, niobium, and tantalum in a vacuum were studied. It is concluded that all subject compounds evaporate by molecular structures except AlB sub 12' which dissociates, losing the aluminum.

  2. Literature survey of heat transfer enhancement techniques in refrigeration applications

    SciTech Connect (OSTI)

    Jensen, M.K.; Shome, B.

    1994-05-01

    A survey has been performed of the technical and patent literature on enhanced heat transfer of refrigerants in pool boiling, forced convection evaporation, and condensation. Extensive bibliographies of the technical literature and patents are given. Many passive and active techniques were examined for pure refrigerants, refrigerant-oil mixtures, and refrigerant mixtures. The citations were categorized according to enhancement technique, heat transfer mode, and tube or shell side focus. The effects of the enhancement techniques relative to smooth and/or pure refrigerants were illustrated through the discussion of selected papers. Patented enhancement techniques also are discussed. Enhanced heat transfer has demonstrated significant improvements in performance in many refrigerant applications. However, refrigerant mixtures and refrigerant-oil mixtures have not been studied extensively; no research has been performed with enhanced refrigerant mixtures with oil. Most studies have been of the parametric type; there has been inadequate examination of the fundamental processes governing enhanced refrigerant heat transfer, but some modeling is being done and correlations developed. It is clear that an enhancement technique must be optimized for the refrigerant and operating condition. Fundamental processes governing the heat transfer must be examined if models for enhancement techniques are to be developed; these models could provide the method to optimize a surface. Refrigerant mixtures, with and without oil present, must be studied with enhancement devices; there is too little known to be able to estimate the effects of mixtures (particularly NARMs) with enhanced heat transfer. Other conclusions and recommendations are offered.

  3. Co-Evaporated Cu2ZnSnSe4 Films and Devices

    SciTech Connect (OSTI)

    Repins, I.; Beall, C.; Vora, N.; DeHart, C.; Kuciauskas, D.; Dippo, P.; To, B.; Mann, J.; Hsu, W. C.; Goodrich, A.; Noufi, R.

    2012-06-01

    The use of vacuum co-evaporation to produce Cu2ZnSnSe4 photovoltaic devices with 9.15% total-area efficiency is described. These new results suggest that the early success of the atmospheric techniques for kesterite photovoltaics may be related to the ease with which one can control film composition and volatile phases, rather than a fundamental benefit of atmospheric conditions for film properties. The co-evaporation growth recipe is documented, as is the motivation for various features of the recipe. Characteristics of the resulting kesterite films and devices are shown in scanning electron micrographs, including photoluminescence, current-voltage, and quantum efficiency. Current-voltage curves demonstrate low series resistance without the light-dark cross-over seen in many devices in the literature. Band gap indicated by quantum efficiency and photoluminescence is roughly consistent with that expected from first principles calculation.

  4. Fabrication and characterization of silver- and copper-coated Nylon 6 forcespun nanofibers by thermal evaporation

    SciTech Connect (OSTI)

    Mihut, Dorina M. Lozano, Karen; Foltz, Heinrich

    2014-11-01

    Silver and copper nanoparticles were deposited as thin films onto substrates consisting of Nylon 6 nanofibers manufactured using forcespinning{sup ®} equipment. Different rotational speeds were used to obtain continuous nanofibers of various diameters arranged as nonwoven mats. The Nylon 6 nanofibers were collected as successive layers on frames, and a high-vacuum thermal evaporation method was used to deposit the silver and copper thin films on the nanofibers. The structures were investigated using scanning electron microscopy–scanning transmission electron microscopy, atomic force microscopy, x-ray diffraction, and electrical resistance measurements. The results indicate that evaporated silver and copper nanoparticles were successfully deposited on Nylon 6 nanofibers as thin films that adhered well to the polymer substrate while the native morphology of the nanofibers were preserved, and electrically conductive nanostructures were achieved.

  5. Spin-pump-induced spin transport in a thermally evaporated pentacene film

    SciTech Connect (OSTI)

    Tani, Yasuo; Shikoh, Eiji; Teki, Yoshio

    2015-12-14

    We report the spin-pump-induced spin transport properties of a pentacene film prepared by thermal evaporation. In a palladium(Pd)/pentacene/Ni{sub 80}Fe{sub 20} tri-layer sample, a pure spin-current is generated in the pentacene layer by the spin-pumping of Ni{sub 80}Fe{sub 20}, which is independent of the conductance mismatch problem in spin injection. The spin current is absorbed into the Pd layer, converted into a charge current with the inverse spin-Hall effect in Pd, and detected as an electromotive force. This is clear evidence for the pure spin current at room temperature in pentacene films prepared by thermal evaporation.

  6. Green Data Center Cooling: Achieving 90% Reduction: Airside Economization and Unique Indirect Evaporative Cooling

    SciTech Connect (OSTI)

    Weerts, B. A.; Gallaher, D.; Weaver, R.; Van Geet, O.

    2012-01-01

    The Green Data Center Project was a successful effort to significantly reduce the energy use of the National Snow and Ice Data Center (NSIDC). Through a full retrofit of a traditional air conditioning system, the cooling energy required to meet the data center's constant load has been reduced by over 70% for summer months and over 90% for cooler winter months. This significant change is achievable through the use of airside economization and a new indirect evaporative cooling system. One of the goals of this project was to create awareness of simple and effective energy reduction strategies for data centers. This project's geographic location allowed maximizing the positive effects of airside economization and indirect evaporative cooling, but these strategies may also be relevant for many other sites and data centers in the U.S.

  7. Characterization Results For The 2013 HTF 3H Evaporator Overhead Samples

    SciTech Connect (OSTI)

    Washington, A. L. II

    2013-12-04

    This report tabulates the radiochemical analysis of the 3H evaporator overhead sample for {sup 137}Cs, {sup 90}Sr, and {sup 129}I to meet the requirements in the Effluent Treatment Project (ETP) Waste Acceptance Criteria (WAC) (rev. 6). This report identifies the sample receipt date, preparation method, and analysis performed in the accumulation of the listed values. All data was found to be within the ETP WAC (rev. 6) specification for the Waste Water Collection Tanks (WWCT).

  8. A simple model of chromospheric evaporation and condensation driven conductively in a solar flare

    SciTech Connect (OSTI)

    Longcope, D. W.

    2014-11-01

    Magnetic energy released in the corona by solar flares reaches the chromosphere where it drives characteristic upflows and downflows known as evaporation and condensation. These flows are studied here for the case where energy is transported to the chromosphere by thermal conduction. An analytic model is used to develop relations by which the density and velocity of each flow can be predicted from coronal parameters including the flare's energy flux F. These relations are explored and refined using a series of numerical investigations in which the transition region (TR) is represented by a simplified density jump. The maximum evaporation velocity, for example, is well approximated by v{sub e} ? 0.38(F/?{sub co,} {sub 0}){sup 1/3}, where ?{sub co,} {sub 0} is the mass density of the pre-flare corona. This and the other relations are found to fit simulations using more realistic models of the TR both performed in this work, and taken from a variety of previously published investigations. These relations offer a novel and efficient means of simulating coronal reconnection without neglecting entirely the effects of evaporation.

  9. Tests of the fission-evaporation competition in the deexcitation of heavy nuclei

    SciTech Connect (OSTI)

    Siwek-Wilczynska, K.; Skwira, I.; Wilczynski, J.

    2005-09-01

    In order to verify methods of calculating the fission-evaporation competition in reactions used to synthesize new super-heavy nuclei in 'cold' (1n) and 'hot' (3n,4n) fusion reactions, we present an analysis of existing experimental data on the evaporation-residue cross sections in two selected reactions, {sup 208}Pb({sup 16}O, xn) and {sup 236}U({sup 12}C, xn), for which complementary experimental information necessary to unambiguously calculate the survival probabilities is available: precisely measured fusion excitation functions and saddle-point energies of the fissioning nuclei, deduced from experiments. Standard statistical model calculations, with shell effects accounted for by the Ignatyuk formula, were carried out assuming the ground state shell corrections of Moeller et al., and zero shell correction at the saddle configuration (resulting from the presented systematics). Good agreement of the calculated evaporation-residue cross sections with experimental data for different xn reaction channels at low excitation energies leaves no room for modifications of the conventional way of calculating the {gamma}{sub n}/{gamma}{sub f} ratio, particularly for including into this ratio an additional preexponential factor (such as the Kramers fission hindrance factor or an effective collective factor) significantly different from 1.

  10. Evaporation system and method for gas jet deposition of thin film materials

    DOE Patents [OSTI]

    Schmitt, J.J.; Halpern, B.L.

    1994-10-18

    A method and apparatus are disclosed for depositing thin films of materials such as metals, oxides and nitrides at low temperature relies on a supersonic free jet of inert carrier gas to transport vapor species generated from an evaporation source to the surface of a substrate. Film deposition vapors are generated from solid film precursor materials, including those in the form of wires or powders. The vapor from these sources is carried downstream in a low pressure supersonic jet of inert gas to the surface of a substrate where the vapors deposit to form a thin film. A reactant gas can be introduced into the gas jet to form a reaction product with the evaporated material. The substrate can be moved from the gas jet past a gas jet containing a reactant gas in which a discharge has been generated, the speed of movement being sufficient to form a thin film which is chemically composed of the evaporated material and reactant gases. 8 figs.

  11. Lignite Fuel Enhancement

    SciTech Connect (OSTI)

    Charles Bullinger; Nenad Sarunac

    2010-03-31

    Pulverized coal power plants which fire lignites and other low-rank high-moisture coals generally operate with reduced efficiencies and increased stack emissions due to the impacts of high fuel moisture on stack heat loss and pulverizer and fan power. A process that uses plant waste heat sources to evaporate a portion of the fuel moisture from the lignite feedstock in a moving bed fluidized bed dryer (FBD) was developed in the U.S. by a team led by Great River Energy (GRE). The demonstration was conducted with Department of Energy (DOE) funding under DOE Award Number DE-FC26-04NT41763. The objectives of GRE's Lignite Fuel Enhancement project were to demonstrate reduction in lignite moisture content by using heat rejected from the power plant, apply technology at full scale at Coal Creek Station (CCS), and commercialize it. The Coal Creek Project has involved several stages, beginning with lignite drying tests in a laboratory-scale FBD at the Energy Research Center (ERC) and development of theoretical models for predicting dryer performance. Using results from these early stage research efforts, GRE built a 2 ton/hour pilot-scale dryer, and a 75 ton/hour prototype drying system at Coal Creek Station. Operated over a range of drying conditions, the results from the pilot-scale and prototype-scale dryers confirmed the performance of the basic dryer design concept and provided the knowledge base needed to scale the process up to commercial size. Phase 2 of the GRE's Lignite Fuel Enhancement project included design, construction and integration of a full-scale commercial coal drying system (four FBDs per unit) with Coal Creek Units 1 and 2 heat sources and coal handling system. Two series of controlled tests were conducted at Coal Creek Unit 1 with wet and dried lignite to determine effect of dried lignite on unit performance and emissions. Wet lignite was fired during the first, wet baseline, test series conducted in September 2009. The second test series was performed

  12. NREL Demonstrates Game-Changing Air Conditioner Technology (Fact Sheet), Highlights in Research & Development, NREL (National Renewable Energy Laboratory)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Testing of DEVAP prototype validates modeled predictions of 40% to 85% energy savings. Researchers in the NREL Buildings group are moving the award-winning desiccant enhanced evaporative (DEVAP) air conditioning technol- ogy further toward commercialization by demonstrating that its energy-saving perfor- mance matches closely with thermodynamic model predictions. Industry partners Synapse Product Development and AIL Research built two prototypes of DEVAP based on NREL's design and modeling,

  13. Past Projects | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Commercial Buildings » Past Projects Past Projects Photo of NREL senior engineer Eric Kozubal examining a prototype airflow channel of the desiccant enhanced evaporative (DEVap) air conditioner with a graph superimposed on the photo that shows how hot humid air, in red, changes to cool dry air, in blue, as the air passes through the DEVap core. The Building Technologies Office (BTO) research portfolio of advanced technologies, systems, tools, and strategies aimed at improving the energy

  14. APPLICATION OF A THIN FILM EVAPORATOR SYSTEM FOR MANAGEMENT OF LIQUID HIGH-LEVEL WASTES AT HANFORD

    SciTech Connect (OSTI)

    TEDESCHI AR; WILSON RA

    2010-01-14

    A modular, transportable evaporator system, using thin film evaporative technology, is planned for deployment at the Hanford radioactive waste storage tank complex. This technology, herein referred to as a wiped film evaporator (WFE), will be located at grade level above an underground storage tank to receive pumped liquids, concentrate the liquid stream from 1.1 specific gravity to approximately 1.4 and then return the concentrated solution back into the tank. Water is removed by evaporation at an internal heated drum surface exposed to high vacuum. The condensed water stream will be shipped to the site effluent treatment facility for final disposal. This operation provides significant risk mitigation to failure of the aging 242-A Evaporator facility; the only operating evaporative system at Hanford maximizing waste storage. This technology is being implemented through a development and deployment project by the tank farm operating contractor, Washington River Protection Solutions (WRPS), for the Office of River Protection/Department of Energy (ORP/DOE), through Columbia Energy & Environmental Services, Inc. (Columbia Energy). The project will finalize technology maturity and install a system at one of the double-shell tank farms. This paper discusses results of pre-project pilot-scale testing by Columbia Energy and ongoing technology maturation development scope through fiscal year 2012, including planned additional pilot-scale and full-scale simulant testing and operation with actual radioactive tank waste.

  15. Nuclear Reactions X-Sections By Evaporation Model, Gamma-Cascades

    Energy Science and Technology Software Center (OSTI)

    2000-06-27

    Calculation of energy-averaged cross sections for nuclear reactions with emission of particles and gamma rays and fission. The models employed are the evaporation model with inclusion of pre-equilibrium decay and gamma ray cascade model. Angular momentum and parity conservation are accounted for. Major improvement to the 1976 STAPRE program (NEA 0461) relates to level density approach, implemwnted in subroutine ZSTDE. Generalized superfluid model is incorporated, Boltzman-gas modelling of intrinsic state density and semi-empirical modelling ofmore » a few quasiparticle effects in total level density in equilibrium and saddle deformations of actinide nuclei.« less

  16. Tank 30 and 37 Supernatant Sample Cross-Check and Evaporator Feed Qualification Analysis-2012

    SciTech Connect (OSTI)

    Oji, L. N.

    2013-03-07

    This report summarizes the analytical data reported by the F/H and Savannah River National Laboratories for the 2012 cross-check analysis for high level waste supernatant liquid samples from SRS Tanks 30 and 37. The intent of this Tank 30 and 37 sample analyses was to perform cross-checks against routine F/H Laboratory analyses (corrosion and evaporator feed qualification programs) using samples collected at the same time from both tanks as well as split samples from the tanks.

  17. Non Evaporable Getter (NEG) Pumps: a Route to UHV-XHV

    SciTech Connect (OSTI)

    Manini, Paolo

    2009-08-04

    Non Evaporable Getter (NEG) technology has been developed in the 1970's and since then adopted by industry, R and D labs, research centres and in large physics projects like accelerators, synchrotrons and fusion reactors. NEG pumps are very compact and vibration-free devices able to deliver very high pumping with minimal power requirement and electromagnetic interference. In the present paper, main features and performances of getter pumps are reviewed and discussed with a special focus to photocathode gun application, where UHV or XHV conditions are mandatory to ensure adequate gun life. NEG coating and future challenges for NEG technology are also discussed.

  18. Evaluation of multi-phase heat transfer and droplet evaporation in petroleum cracking flows

    SciTech Connect (OSTI)

    Chang, S.L.; Lottes, S.A.; Petrick, M.; Zhou, C.Q.

    1996-04-01

    A computer code ICRKFLO was used to simulate the multiphase reacting flow of fluidized catalytic cracking (FCC) riser reactors. The simulation provided a fundamental understanding of the hydrodynamics and heat transfer processes in an FCC riser reactor, critical to the development of a new high performance unit. The code was able to make predictions that are in good agreement with available pilot-scale test data. Computational results indicate that the heat transfer and droplet evaporation processes have a significant impact on the performance of a pilot-scale FCC unit. The impact could become even greater on scale-up units.

  19. Evaluation of multi-phase heat transfer and droplet evaporation in petroleum cracking flows

    SciTech Connect (OSTI)

    Chang, S.L.; Lottes, S.A.; Petrick, M.; Zhou, C.Q.

    1996-12-31

    A computer code ICRKFLO was used to simulate the multi-phase reacting flow of fluidized catalytic cracking (FCC) riser reactors. The simulation provided a fundamental understanding of the hydrodynamics and heat transfer processes in an FCC riser reactor, critical to the development of a new high performance unit. The code was able to make predictions that in good agreement with available pilot-scale test data. Computational results indicate that the heat transfer and droplet evaporation processes have a significant impact on the performance of a pilot-scale FCC unit. The impact could become even greater on scale-up units.

  20. Imaging the condensation and evaporation of molecularly thin ethanol films with surface forces apparatus

    SciTech Connect (OSTI)

    Zhao, Gutian; Tan, Qiyan; Xiang, Li; Zhang, Di; Ni, Zhonghua E-mail: yunfeichen@seu.edu.cn; Yi, Hong; Chen, Yunfei E-mail: yunfeichen@seu.edu.cn

    2014-01-15

    A new method for imaging condensation and evaporation of molecularly thin ethanol films is reported. It is found that the first adsorbed layer of ethanol film on mica surface behaves as solid like structure that cannot flow freely. With the increase of exposure time, more ethanol molecules condense over the mica surface in the saturated ethanol vapor condition. The first layer of adsorbed ethanol film is about 3.8 Å thick measured from the surface forces apparatus, which is believed to be the average diameter of ethanol molecules while they are confined in between two atomically smooth mica surfaces.

  1. Characterization Results for the 2014 HTF 3H & 2H Evaporator Overhead Samples

    SciTech Connect (OSTI)

    Washington, A.

    2015-05-11

    This report tabulates the radiochemical analysis of the 3H and 2H evaporator overhead samples for 137Cs, 90Sr, and 129I to meet the requirements in the Effluent Treatment Project (ETP) Waste Acceptance Criteria (WAC) (rev. 6). This report identifies the sample receipt date, preparation method, and analysis performed in the accumulation of the listed values. All data was found to be within the ETP WAC (rev. 6) specification for the Waste Water Collection Tanks (WWCT).

  2. A Remote Absorption Process for Disposal of Evaporate and Reverse Osmosis Concentrates

    SciTech Connect (OSTI)

    Brunsell, D.A.

    2008-07-01

    Many commercial nuclear plants and DOE facilities generate secondary waste streams consisting of evaporator bottoms and reverse osmosis (RO) concentrate. Since liquids are not permitted in disposal facilities, these waste streams must be converted to dry solids, either by evaporation to dried solids or by solidification to liquid-free solids. Evaporation of the liquid wastes reduces their volume, but requires costly energy and capital equipment. In some cases, concentration of the contaminants during drying can cause the waste to exceed Class A waste for nuclear utilities or exceed DOE transuranic limits. This means that disposal costs will be increased, or that, when the Barnwell, SC disposal site closes to waste outside of the Atlantic Compact in July 2008, the waste will be precluded from disposal for the foreseeable future). Solidification with cement agents requires less energy and equipment than drying, but results in a volume increase of 50-100%. The doubling or tripling of waste weight, along with the increased volume, sharply increases shipping and disposal costs. Confronted with these unattractive alternatives, Diversified Technologies Services (DTS), in conjunction with selected nuclear utilities and D and D operations at Rocky Flats, undertook an exploratory effort to convert this liquid wastewater to a solid without using cement. This would avoid the bulking effect of cement, and permit the waste to be disposed of the Energy Solutions facility in Utah as well as some DOE facilities. To address the need for an attractive alternative to drying and cement solidification, a test program was developed using a polymer absorbent media to convert the concentrate streams to a liquid-free waste form that meets the waste acceptance criteria of the pertinent burial sites. Two approaches for mixing the polymer with the liquid were tested: mechanical mixing and in-situ incorporation. As part of this test program, a process control program (PCP) was developed that is

  3. Milagro limits and HAWC sensitivity for the rate-density of evaporating primordial black holes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Abdo, A. A.; Abeysekara, A. U.; Alfaro, R.; Allen, B. T.; Alvarez, C.; Alvarez, J. D.; Arceo, R.; Arteaga-Velazquez, J. C.; Aune, T.; H. A. Ayala Solares; et al

    2015-04-01

    Primordial Black Holes (PBHs) are gravitationally collapsed objects that may have been created by density fluctuations in the early universe and could have arbitrarily small masses down to the Planck scale. Hawking showed that due to quantum effects, a black hole has a temperature inversely proportional to its mass and will emit all species of fundamental particles thermally. PBHs with initial masses of ~ 5.0 × 10¹⁴ g should be expiring in the present epoch with bursts of high-energy particles, including gamma radiation in the GeV – TeV energy range. The Milagro high energy observatory, which operated from 2000 tomore » 2008, is sensitive to the high end of the PBH evaporation gamma-ray spectrum. Due to its large field-of-view, more than 90% duty cycle and sensitivity up to 100 TeV gamma rays, the Milagro observatory is well suited to perform a search for PBH bursts. Based on a search on the Milagro data, we report new PBH burst rate density upper limits over a range of PBH observation times. In addition, we report the sensitivity of the Milagro successor, the High Altitude Water Cherenkov (HAWC) observatory, to PBH evaporation events.« less

  4. Milagro limits and HAWC sensitivity for the rate-density of evaporating primordial black holes

    SciTech Connect (OSTI)

    Abdo, A. A.; Abeysekara, A. U.; Alfaro, R.; Allen, B. T.; Alvarez, C.; Alvarez, J. D.; Arceo, R.; Arteaga-Velazquez, J. C.; Aune, T.; H. A. Ayala Solares; Barber, A. S.; Baughman, B. M.; Bautista-Elivar, N.; Gonzalez, J. Becerra; Belmont, E.; BenZvi, S. Y.; Berley, D.; Bonilla Rosales, M.; Braun, J.; Caballero-Lopez, R. A.; Caballero-Mora, K. S.; Carraminana, A.; Castillo, M.; Christopher, G. E.; Cotti, U.; Cotzomi, J.; de la Fuente, E.; De León, C.; DeYoung, T.; Diaz Hernandez, R.; Diaz-Cruz, L.; Díaz-Vélez, J. C.; Dingus, B. L.; DuVernois, M. A.; Ellsworth, R. W.; Fiorino, D. W.; Fraija, N.; Galindo, A.; Garfias, F.; González, M. M.; Goodman, J. A.; Grabski, V.; Gussert, M.; Hampel-Arias, Z.; Harding, J. P.; Hays, E.; Hoffman, C. M.; Hui, C. M.; Hüntemeyer, P.; Imran, A.; Iriarte, A.; Karn, P.; Kieda, D.; Kolterman, B. E.; Kunde, G. J.; Lara, A.; Lauer, R. J.; Lee, W. H.; Lennarz, D.; Vargas, H. Leon; Linares, E. C.; Linnemann, J. T.; Longo, M.; Luna-GarcIa, R.; MacGibbon, J. H.; Marinelli, A.; Marinelli, S. S.; Martinez, H.; Martinez, O.; Martínez-Castro, J.; J. A.J. Matthews; McEnery, J.; Mendoza Torres, E.; Mincer, A. I.; Miranda-Romagnoli, P.; Moreno, E.; Morgan, T.; Mostafa, M.; Nellen, L.; Nemethy, P.; Newbold, M.; Noriega-Papaqui, R.; Oceguera-Becerra, T.; Patricelli, B.; Pelayo, R.; Perez-Perez, E. G.; Pretz, J.; Riviere, C.; Rosa-Gonzalez, D.; Ruiz-Velasco, E.; Ryan, J.; Salazar, H.; Salesa, F.; Sandoval, A.; Saz Parkinson, P. M.; Schneider, M.; Silich, S.; Sinnis, G.; Smith, A. J.; Stump, D.; Sparks Woodle, K.; Springer, R. W.; Taboada, I.; Toale, P. A.; Tollefson, K.; Torres, I.; Ukwatta, T. N.; Vasileiou, V.; Villasenor, L.; Weisgarber, T.; Westerhoff, S.; Williams, D. A.; Wisher, I. G.; Wood, J.; Yodh, G. B.; Younk, P. W.; Zaborov, D.; Zepeda, A.; Zhou, H.

    2015-04-01

    Primordial Black Holes (PBHs) are gravitationally collapsed objects that may have been created by density fluctuations in the early universe and could have arbitrarily small masses down to the Planck scale. Hawking showed that due to quantum effects, a black hole has a temperature inversely proportional to its mass and will emit all species of fundamental particles thermally. PBHs with initial masses of ~ 5.0 × 10¹⁴ g should be expiring in the present epoch with bursts of high-energy particles, including gamma radiation in the GeV – TeV energy range. The Milagro high energy observatory, which operated from 2000 to 2008, is sensitive to the high end of the PBH evaporation gamma-ray spectrum. Due to its large field-of-view, more than 90% duty cycle and sensitivity up to 100 TeV gamma rays, the Milagro observatory is well suited to perform a search for PBH bursts. Based on a search on the Milagro data, we report new PBH burst rate density upper limits over a range of PBH observation times. In addition, we report the sensitivity of the Milagro successor, the High Altitude Water Cherenkov (HAWC) observatory, to PBH evaporation events.

  5. Electron-beam-evaporated thin films of hafnium dioxide for fabricating electronic devices

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Xiao, Zhigang; Kisslinger, Kim

    2015-06-17

    Thin films of hafnium dioxide (HfO2) are widely used as the gate oxide in fabricating integrated circuits because of their high dielectric constants. In this paper, the authors report the growth of thin films of HfO2 using e-beam evaporation, and the fabrication of complementary metal-oxide semiconductor (CMOS) integrated circuits using this HfO2 thin film as the gate oxide. The authors analyzed the thin films using high-resolution transmission electron microscopy and electron diffraction, thereby demonstrating that the e-beam-evaporation-grown HfO2 film has a polycrystalline structure and forms an excellent interface with silicon. Accordingly, we fabricated 31-stage CMOS ring oscillator to test themore » quality of the HfO2 thin film as the gate oxide, and obtained excellent rail-to-rail oscillation waveforms from it, denoting that the HfO2 thin film functioned very well as the gate oxide.« less

  6. STARSPOTS-TRANSIT DEPTH RELATION OF THE EVAPORATING PLANET CANDIDATE KIC 12557548b

    SciTech Connect (OSTI)

    Kawahara, Hajime; Kurosaki, Kenji; Ito, Yuichi; Ikoma, Masahiro; Hirano, Teruyuki

    2013-10-10

    Violent variation of transit depths and an ingress-egress asymmetry of the transit light curve discovered in KIC 12557548 have been interpreted as evidence of a catastrophic evaporation of atmosphere with dust ( M-dot {sub p}?>1 M{sub ?} Gyr{sup 1}) from a close-in small planet. To explore what drives the anomalous atmospheric escape, we perform time-series analysis of the transit depth variation of Kepler archival data for ?3.5 yr. We find a ?30% periodic variation of the transit depth with P {sub 1} = 22.83 0.21 days, which is within the error of the rotation period of the host star estimated using the light curve modulation, P {sub rot} = 22.91 0.24 days. We interpret the results as evidence that the atmospheric escape of KIC 12557548b correlates with stellar activity. We consider possible scenarios that account for both the mass loss rate and the correlation with stellar activity. X-ray and ultraviolet (XUV)-driven evaporation is possible if one accepts a relatively high XUV flux and a high efficiency for converting the input energy to the kinetic energy of the atmosphere. Star-planet magnetic interaction is another possible scenario, though huge uncertainty remains for the mass loss rate.

  7. Electron-beam-evaporated thin films of hafnium dioxide for fabricating electronic devices

    SciTech Connect (OSTI)

    Xiao, Zhigang; Kisslinger, Kim

    2015-06-17

    Thin films of hafnium dioxide (HfO2) are widely used as the gate oxide in fabricating integrated circuits because of their high dielectric constants. In this paper, the authors report the growth of thin films of HfO2 using e-beam evaporation, and the fabrication of complementary metal-oxide semiconductor (CMOS) integrated circuits using this HfO2 thin film as the gate oxide. The authors analyzed the thin films using high-resolution transmission electron microscopy and electron diffraction, thereby demonstrating that the e-beam-evaporation-grown HfO2 film has a polycrystalline structure and forms an excellent interface with silicon. Accordingly, we fabricated 31-stage CMOS ring oscillator to test the quality of the HfO2 thin film as the gate oxide, and obtained excellent rail-to-rail oscillation waveforms from it, denoting that the HfO2 thin film functioned very well as the gate oxide.

  8. Thermal evaporation and condensation synthesis of metallic Zn layered polyhedral microparticles

    SciTech Connect (OSTI)

    Khan, Waheed S.; Cao, Chuanbao; Usman, Zahid; Hussain, Sajad; Nabi, Ghulam; Butt, Faheem K.; Ali, Zulfiqar; Mahmood, Tariq; Niaz, Niaz Ahmad

    2011-12-15

    Highlights: Black-Right-Pointing-Pointer Zn polyhedral microparticles prepared by thermal evaporation and condensation route. Black-Right-Pointing-Pointer Vapour-solid process based growth model governs the formation of Zn microparticles. Black-Right-Pointing-Pointer A strong PL emission band is observed at 369 nm in UV region. Black-Right-Pointing-Pointer Radiative recombination of electrons in the s, p conduction band and the holes in the d bands causes this emission. -- Abstract: Metallic zinc layered polyhedral microparticles have been fabricated by thermal evaporation and condensation technique using zinc as precursor at 750 Degree-Sign C for 120 min and NH{sub 3} as a carrier gas. The zinc polyhedral microparticles with oblate spherical shape are observed to be 2-9 {mu}m in diameter along major axes and 1-7 {mu}m in thickness along minor axes. The structural, compositional and morphological characterizations were performed by X-ray diffraction (XRD), energy dispersive X-ray spectroscopy (EDS), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and selected area electron diffraction (SAED). A vapour-solid (VS) mechanism based growth model has been proposed for the formation of Zn microparticles. Room temperature photoluminescence (PL) emission spectrum of the product exhibited a strong emission band at 369 nm attributed to the radiative recombination of electrons in the s, p conduction band near Fermi surface and the holes in the d bands generated by the optical excitation.

  9. Crystallization Temperature of Aqueous Lithium Bromide Solutions at Low Evaporation Temperature

    SciTech Connect (OSTI)

    Kisari, Padmaja; Wang, Kai; Abdelaziz, Omar; Vineyard, Edward Allan

    2010-01-01

    Water- aqueous Lithium Bromide (LiBr) solutions have shown superior performance as working fluid pairs for absorption refrigeration cycles. Most of the available literature (e.g. ASHRAE Handbook of Fundamentals, etc.) provide crystallization behavior down to only 10 C. The typical evaporating temperature for an absorption chiller system is usually lower than 10 C. Hence, it is essential to have an accurate prediction of the crystallization temperature in this range in order to avoid crystallization during the design phase. We have therefore conducted a systematic study to explore the crystallization temperatures of LiBr/Water solutions that fall below an evaporating temperature of 10 C. Our preliminary studies revealed that the rate of cooling of the sample solution influences the crystallization temperature; therefore we have performed a quasi steady test where the sample was cooled gradually by reducing the sample temperature in small steps. Results from this study are reported in this paper and can be used to extend the data available in open literature.

  10. Engineering work plan for implementing the Process Condensate Recycle Project at the 242-A evaporator

    SciTech Connect (OSTI)

    Haring, D.S.

    1995-02-02

    The 242-A Evaporator facility is used to reduce the volume of waste stored in the Hanford double shell tanks. This facility uses filtered raw water for cooling, de-entrainment pad sprays, pump seal water, and chemical tank make-up. Some of these uses result in the introduction of filtered raw water into the process, thus increasing the volume of waste requiring evaporation and subsequent treatment by the 200 East Effluent Treatment Facility. The pump seal water and the de-entrainment pad spray systems were identified as candidates for a waste minimization upgrade. This work plan describes the activities associated with the design, installation, testing and initial operation of the process condensate recycle system. Implementation of the process condensate recycle system will permit the use of process condensate in place of raw water for the de-entrainment pad sprays and pump seals. This will reduce the amount of low-level liquid waste and generated during facility operation through source reduction and recycling.

  11. TANK 26F SUPERNATANT AND 2F EVAPORATOR EDUCTOR PUMP SAMPLE CHARACTERIZATION RESULTS

    SciTech Connect (OSTI)

    King, W.; Hay, M.; Coleman, C.

    2011-08-23

    In an effort to understand the reasons for system plugging problems in the SRS 2F evaporator, supernatant samples were retrieved from the evaporator feed tank (Tank 26F) and solids were collected from the evaporator eductor feed pump for characterization. The variable depth supernatant samples were retrieved from Tank 26F in early December of 2010 and samples were provided to SRNL and the F/H Area laboratories for analysis. Inspection and analysis of the samples at SRNL was initiated in early March of 2011. During the interim period, samples were frequently exposed to temperatures as low as 12 C with daily temperature fluctuations as high as 10 C. The temperature at the time of sample collection from the waste tank was 51 C. Upon opening the supernatant bottles at SRNL, many brown solids were observed in both of the Tank 26F supernatant samples. In contrast, no solids were observed in the supernatant samples sent to the F/H Area laboratories, where the analysis was completed within a few days after receipt. Based on these results, it is believed that the original Tank 26F supernatant samples did not contain solids, but solids formed during the interim period while samples were stored at ambient temperature in the SRNL shielded cells without direct climate control. Many insoluble solids (>11 wt. % for one sample) were observed in the Tank 26F supernatant samples after three months of storage at SRNL which would not dissolve in the supernatant solution in two days at 51 C. Characterization of these solids along with the eductor pump solids revealed the presence of sodium oxalate and clarkeite (uranyl oxyhydroxide) as major crystalline phases. Sodium nitrate was the dominant crystalline phase present in the unwashed Eductor Pump solids. Crystalline sodium nitrate may have formed during the drying of the solids after filtration or may have been formed in the Tank 26F supernatant during storage since the solution was found to be very concentrated (9-12 M Na

  12. Analysis Of 2H-Evaporator Scale Wall [HTF-13-82] And Pot Bottom [HTF-13-77] Samples

    SciTech Connect (OSTI)

    Oji, L. N.

    2013-09-11

    Savannah River Remediation (SRR) is planning to remove a buildup of sodium aluminosilicate scale from the 2H-evaporator pot by loading and soaking the pot with heated 1.5 M nitric acid solution. Sampling and analysis of the scale material has been performed so that uranium and plutonium isotopic analysis can be input into a Nuclear Criticality Safety Assessment (NCSA) for scale removal by chemical cleaning. Historically, since the operation of the Defense Waste Processing Facility (DWPF), silicon in the DWPF recycle stream combines with aluminum in the typical tank farm supernate to form sodium aluminosilicate scale mineral deposits in the 2H-evaporator pot and gravity drain line. The 2H-evaporator scale samples analyzed by Savannah River National Laboratory (SRNL) came from two different locations within the evaporator pot; the bottom cone sections of the 2H-evaporator pot [Sample HTF-13-77] and the wall 2H-evaporator [sample HTF-13-82]. X-ray diffraction analysis (XRD) confirmed that both the 2H-evaporator pot scale and the wall samples consist of nitrated cancrinite (a crystalline sodium aluminosilicate solid) and clarkeite (a uranium oxyhydroxide mineral). On ''as received'' basis, the bottom pot section scale sample contained an average of 2.59E+00 {+-} 1.40E-01 wt % total uranium with a U-235 enrichment of 6.12E-01 {+-} 1.48E-02 %, while the wall sample contained an average of 4.03E+00 {+-} 9.79E-01 wt % total uranium with a U-235 enrichment of 6.03E-01% {+-} 1.66E-02 wt %. The bottom pot section scale sample analyses results for Pu-238, Pu-239, and Pu-241 are 3.16E-05 {+-} 5.40E-06 wt %, 3.28E-04 {+-} 1.45E-05 wt %, and <8.80E-07 wt %, respectively. The evaporator wall scale samples analysis values for Pu-238, Pu-239, and Pu-241 averages 3.74E-05 {+-} 6.01E-06 wt %, 4.38E-04 {+-} 5.08E-05 wt %, and <1.38E-06 wt %, respectively. The Pu-241 analyses results, as presented, are upper limit values. For these two evaporator scale samples obtained at two different

  13. Silicon dioxide and hafnium dioxide evaporation characteristics from a high-frequency sweep e-beam system

    SciTech Connect (OSTI)

    Chow, R. [Lawrence Livermore National Laboratory, Livermore, California 94551-0808 (United States); Tsujimoto, N. [MDC Vacuum Products Corporation, Hayward, California 94545 (United States)

    1996-09-01

    Reactive oxygen evaporation characteristics were determined as a function of the front-panel control parameters provided by a programmable, high-frequency sweep e-beam system. An experimental design strategy used deposition rate, beam speed, pattern, azimuthal rotation speed, and dwell time as the variables. The optimal settings for obtaining a broad thickness distribution, efficient silicon dioxide boule consumption, and minimal hafnium dioxide defect density were generated. The experimental design analysis showed the compromises involved with evaporating these oxides. {copyright} {ital 1996 Optical Society of America.}

  14. Waste Heat Recovery and Recycling in Thermal Separation Processes: Distillation, Multi-Effect Evaporation (MEE) and Crystallization Processes

    SciTech Connect (OSTI)

    Emmanuel A. Dada; Chandrakant B. Panchal; Luke K. Achenie; Aaron Reichl; Chris C. Thomas

    2012-12-03

    Evaporation and crystallization are key thermal separation processes for concentrating and purifying inorganic and organic products with energy consumption over 1,000 trillion Btu/yr. This project focused on a challenging task of recovering low-temperature latent heat that can have a paradigm shift in the way thermal process units will be designed and operated to achieve high-energy efficiency and significantly reduce the carbon footprint as well as water footprint. Moreover, this project has evaluated the technical merits of waste-heat powered thermal heat pumps for recovery of latent heat from distillation, multi-effect evaporation (MEE), and crystallization processes and recycling into the process. The Project Team has estimated the potential energy, economics and environmental benefits with the focus on reduction in CO2 emissions that can be realized by 2020, assuming successful development and commercialization of the technology being developed. Specifically, with aggressive industry-wide applications of heat recovery and recycling with absorption heat pumps, energy savings of about 26.7 trillion Btu/yr have been estimated for distillation process. The direct environmental benefits of this project are the reduced emissions of combustible products. The estimated major reduction in environmental pollutants in the distillation processes is in CO2 emission equivalent to 3.5 billion lbs/year. Energy consumption associated with water supply and treatments can vary between 1,900 kWh and 23,700 kWh per million-gallon water depending on sources of natural waters [US DOE, 2006]. Successful implementation of this technology would significantly reduce the demand for cooling-tower waters, and thereby the use and discharge of water treatment chemicals. The Project Team has also identified and characterized working fluid pairs for the moderate-temperature heat pump. For an MEE process, the two promising fluids are LiNO3+KNO3+NANO3 (53:28:19 ) and LiNO3+KNO3+NANO2

  15. Simulation of a photovoltaic/thermal heat pump system having a modified collector/evaporator

    SciTech Connect (OSTI)

    Xu, Guoying; Deng, Shiming; Zhang, Xiaosong; Yang, Lei; Zhang, Yuehong

    2009-11-15

    A new photovoltaic/thermal heat pump (PV/T-HP) system having a modified collector/evaporator (C/E) has been developed and numerically studied. Multi-port flat extruded aluminum tubes were used in the modified C/E, as compared to round copper tubes used in a conventional C/E. Simulation results suggested that a better operating performance can be achieved for a PV/T-HP system having such a modified C/E. In addition, using the meteorological data in both Nanjing and Hong Kong, China, the simulation results showed that this new PV/T-HP system could efficiently generate electricity and thermal energy simultaneously in both cities all-year-round. Furthermore, improved operation by using variable speed compressor has been designed and discussed. (author)

  16. Preparation and characterization of indium zinc oxide thin films by electron beam evaporation technique

    SciTech Connect (OSTI)

    Keshavarzi, Reza [Chemistry Department, Catalysis Division, University of Isfahan, Isfahan 81746-73441 (Iran, Islamic Republic of)] [Chemistry Department, Catalysis Division, University of Isfahan, Isfahan 81746-73441 (Iran, Islamic Republic of); Mirkhani, Valiollah, E-mail: mirkhani@sci.ui.ac.ir [Chemistry Department, Catalysis Division, University of Isfahan, Isfahan 81746-73441 (Iran, Islamic Republic of)] [Chemistry Department, Catalysis Division, University of Isfahan, Isfahan 81746-73441 (Iran, Islamic Republic of); Moghadam, Majid, E-mail: moghadamm@sci.ui.ac.ir [Chemistry Department, Catalysis Division, University of Isfahan, Isfahan 81746-73441 (Iran, Islamic Republic of) [Chemistry Department, Catalysis Division, University of Isfahan, Isfahan 81746-73441 (Iran, Islamic Republic of); Department of Nanotechnology Engineering, University of Isfahan, Isfahan 81746-73441 (Iran, Islamic Republic of); Tangestaninejad, Shahram; Mohammadpoor-Baltork, Iraj [Chemistry Department, Catalysis Division, University of Isfahan, Isfahan 81746-73441 (Iran, Islamic Republic of)] [Chemistry Department, Catalysis Division, University of Isfahan, Isfahan 81746-73441 (Iran, Islamic Republic of); Fallah, Hamid Reza; Dastjerdi, Mohammad Javad Vahid; Modayemzadeh, Hamed Reza [Department of Physics, University of Isfahan, Isfahan 81746-73441 (Iran, Islamic Republic of)] [Department of Physics, University of Isfahan, Isfahan 81746-73441 (Iran, Islamic Republic of)

    2011-04-15

    In this work, the preparation of In{sub 2}O{sub 3}-ZnO thin films by electron beam evaporation technique on glass substrates is reported. Optical and electrical properties of these films were investigated. The effect of dopant amount and annealing temperature on the optical and electrical properties of In{sub 2}O{sub 3}-ZnO thin films was also studied. Different amount of ZnO was used as dopant and the films were annealed at different temperature. The results showed that the most crystalline, transparent and uniform films with lowest resistivity were obtained using 25 wt% of ZnO annealed at 500 {sup o}C.

  17. Nuclear level densities of 64,66 Zn from neutron evaporation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ramirez, A. P. D.; Voinov, A. V.; Grimes, S. M.; Schiller, A.; Brune, C. R.; Massey, T. N.; Salas-Bacci, A.

    2013-12-26

    Double differential cross sections of neutrons from d+63,65Cu reactions have been measured at deuteron energies of 6 and 7.5 MeV. The cross sections measured at backward angles have been compared to theoretical calculations in the framework of the statistical Hauser-Feshbach model. Three different level density models were tested: the Fermi-gas model, the Gilbert-Cameron model, and the microscopic approach through the Hartree-Fock-Bogoliubov method (HFBM). The calculations using the Gilbert-Cameron model are in best agreement with our experimental data. Level densities of the residual nuclei 64Zn and 66Zn have been obtained from statistical neutron evaporation spectra. In conclusion, the angle-integrated cross sectionsmore » have been analyzed with the exciton model of nuclear reaction.« less

  18. Code System to Calculate Nuclear Reaction Cross Sections by Evaporation Model.

    Energy Science and Technology Software Center (OSTI)

    2000-11-27

    Version: 00 Both STAPRE and STAPREF are included in this package. STAPRE calculates energy-averaged cross sections for nuclear reactions with emission of particles and gamma rays and fission. The models employed are the evaporation model with inclusion of pre-equilibrium decay and a gamma-ray cascade model. Angular momentum and parity conservation are accounted for. Major improvement in the 1976 STAPRE program relates to level density approach, implemented in subroutine ZSTDE. Generalized superfluid model is incorporated, boltzman-gasmore » modeling of intrinsic state density and semi-empirical modeling of a few-quasiparticle effects in total level density at equilibrium and saddle deformations of actinide nuclei. In addition to the activation cross sections, particle and gamma-ray production spectra are calculated. Isomeric state populations and production cross sections for gamma rays from low excited levels are obtained, too. For fission a single or a double humped barrier may be chosen.« less

  19. RESULTS OF THE 2H EVAPORATOR ACID CLEANING AND IN-POT NEUTRALIZATION

    SciTech Connect (OSTI)

    Wilmarth, B; Phillip Norris, P; Terry Allen, T

    2007-05-29

    The estimated 200 gallons of sodium aluminosilicate scale (NAS) present in the 242-16H Evaporator pot prior to chemical cleaning was subjected to four batches of 1.5 M (9 wt%) nitric acid. Each batch was neutralized with 19 M (50 wt %) sodium hydroxide (caustic) before transfer to Tank 38. The chemical cleaning process began on November 20, 2006, and was terminated on December 10, 2006. An inspection of the pot's interior was performed and based on data gathered during that inspection; the current volume of scale in the pot is conservatively estimated to be 36.3 gallons, which is well below the 200 gallon limit specified in the Technical Safety Requirements. In addition, the performance during all aspects of cleaning agreed well with the flowsheet developed at the bench and pilot scale. There were some lessons learned during the cleaning outage and are detailed in appendices of this report.

  20. Heat capacity of quantum adsorbates: Hydrogen and helium on evaporated gold films

    SciTech Connect (OSTI)

    Birmingham, J.T. |

    1996-06-01

    The author has constructed an apparatus to make specific heat measurements of quantum gases adsorbed on metallic films at temperatures between 0.3 and 4 K. He has used this apparatus to study quench-condensed hydrogen films between 4 and 923 layers thick with J = 1 concentrations between 0.28 and 0.75 deposited on an evaporated gold surface. He has observed that the orientational ordering of the J = 1 molecules depends on the substrate temperature during deposition of the hydrogen film. He has inferred that the density of the films condensed at the lowest temperatures is 25% higher than in bulk H{sub 2} crystals and have observed that the structure of those films is affected by annealing at 3.4 K. The author has measured the J = 1 to J = 0 conversion rate to be comparable to that of the bulk for thick films; however, he found evidence that the gold surface catalyzes conversion in the first two to four layers. He has also used this apparatus to study films of {sup 4}He less than one layer thick adsorbed on an evaporated gold surface. He shows that the phase diagram of the system is similar to that for {sup 4}He/graphite although not as rich in structure, and the phase boundaries occur at different coverages and temperatures. At coverages below about half a layer and at sufficiently high temperatures, the {sup 4}He behaves like a two-dimensional noninteracting Bose gas. At lower temperatures and higher coverages, liquidlike and solidlike behavior is observed. The Appendix shows measurements of the far-infrared absorptivity of the high-{Tc} superconductor La{sub 1.87}Sr{sub 0.13}CuO{sub 4}.

  1. Impact of California Phase 2 reformulated gasoline on atmospheric reactivity of exhaust and evaporative emissions

    SciTech Connect (OSTI)

    Kirchstetter, T.W.; Singer, B.C.; Harley, R.A.; Kendall, G.R.; Traverse, M.

    1997-12-31

    Phase 2 of California`s reformulated gasoline (RFG) program took effect statewide in the first half of 1996. Changes to gasoline composition required by Phase 2 specifications included: lower vapor pressure; lower olefin, aromatic, benzene, and sulfur content; lower T50 and T90; and a minimum oxygen content. In this paper, impacts of Phase 2 RFG on the atmospheric reactivity of motor vehicle exhaust and evaporative emissions are described. Volatile organic compounds in motor vehicle exhaust were measured at the Caldecott tunnel in summer 1995 and 1996. Aggregate emissions of greater than 8000 vehicles were measured each day. Regular and premium grade gasoline samples were collected from service stations in Berkeley concurrently with tunnel measurements both summers. Liquid gasoline samples and their headspace vapors were analyzed to determine detailed chemical composition. Normalized reactivity was calculated for exhaust and evaporative emissions by applying maximum incremental reactivity values to the detailed speciation profiles. Results indicate that the composition of gasoline in 1996 differed markedly from that of 1995. Changes in liquid gasoline composition led to corresponding changes in the speciation of vehicle exhaust and of gasoline headspace vapors. Benzene concentration in liquid gasoline decreased from 2.0 to 0.6 wt%, which contributed to a 70 and 37% reduction in benzene weight fraction in headspace vapors and vehicle exhaust, respectively. Addition of MTBE and reduction of olefins and aromatics in gasoline led to significant reductions in the atmospheric reactivity of unburned gasoline and gasoline headspace vapors. The normalized reactivity of liquid gasoline and headspace vapors decreased by 23 and 19%, respectively, between 1995 and 1996. The normalized reactivity of non-methane organic compounds in vehicle exhaust decreased by about 8%, but the uncertainty in this change was large.

  2. Multilayer formation and evaporation of deuterated ices in prestellar and protostellar cores

    SciTech Connect (OSTI)

    Taquet, Vianney; Charnley, Steven B.; Sipil, Olli

    2014-08-10

    Extremely large deuteration of several molecules has been observed toward prestellar cores and low-mass protostars for a decade. New observations performed toward low-mass protostars suggest that water presents a lower deuteration in the warm inner gas than in the cold external envelope. We coupled a gas-grain astrochemical model with a one-dimensional model of a collapsing core to properly follow the formation and the deuteration of interstellar ices as well as their subsequent evaporation in the low-mass protostellar envelopes with the aim of interpreting the spatial and temporal evolutions of their deuteration. The astrochemical model follows the formation and the evaporation of ices with a multilayer approach and also includes a state-of-the-art deuterated chemical network by taking the spin states of H{sub 2} and light ions into account. Because of their slow formation, interstellar ices are chemically heterogeneous and show an increase of their deuterium fractionation toward the surface. The differentiation of the deuteration in ices induces an evolution of the deuteration within protostellar envelopes. The warm inner region is poorly deuterated because it includes the whole molecular content of ices, while the deuteration predicted in the cold external envelope scales with the highly deuterated surface of ices. We are able to reproduce the observed evolution of water deuteration within protostellar envelopes, but we are still unable to predict the super-high deuteration observed for formaldehyde and methanol. Finally, the extension of this study to the deuteration of complex organics, important for the prebiotic chemistry, shows good agreement with the observations, suggesting that we can use the deuteration to retrace their mechanisms and their moments of formation.

  3. High-level waste storage tank farms/242-A evaporator Standards/Requirements Identification Document (S/RID), Volume 5

    SciTech Connect (OSTI)

    Not Available

    1994-04-01

    The High-Level Waste Storage Tank Farms/242-A Evaporator Standards/Requirements Identification Document (S/RID) is contained in multiple volumes. This document (Volume 5) outlines the standards and requirements for the Fire Protection and Packaging and Transportation sections.

  4. Determination of the crystalline structure of scale solids from the 16H evaporator gravity drain line to tank 38H

    SciTech Connect (OSTI)

    Oji, L. N.

    2015-10-01

    August 2015, scale solids from the 16H Evaporator Gravity Drain Line (GDL) to the Tank 38H were delivered to SRNL for analysis. The desired analytical goal was to identify and confirm the crystalline structure of the scale material and determine if the form of the aluminosilicate mineral was consistent with previous analysis of the scale material from the GDL.

  5. High-level waste storage tank farms/242-A evaporator Standards/Requirements Identification Document (S/RID), Volume 4

    SciTech Connect (OSTI)

    Not Available

    1994-04-01

    The High-Level Waste Storage Tank Farms/242-A Evaporator Standards/Requirements Identification Document (S/RID) is contained in multiple volumes. This document (Volume 4) presents the standards and requirements for the following sections: Radiation Protection and Operations.

  6. FULL SCALE TESTING TECHNOLOGY MATURATION OF A THIN FILM EVAPORATOR FOR HIGH-LEVEL LIQUID WASTE MANAGEMENT AT HANFORD - 12125

    SciTech Connect (OSTI)

    TEDESCHI AR; CORBETT JE; WILSON RA; LARKIN J

    2012-01-26

    Simulant testing of a full-scale thin-film evaporator system was conducted in 2011 for technology development at the Hanford tank farms. Test results met objectives of water removal rate, effluent quality, and operational evaluation. Dilute tank waste simulant, representing a typical double-shell tank supernatant liquid layer, was concentrated from a 1.1 specific gravity to approximately 1.5 using a 4.6 m{sup 2} (50 ft{sup 2}) heated transfer area Rototherm{reg_sign} evaporator from Artisan Industries. The condensed evaporator vapor stream was collected and sampled validating efficient separation of the water. An overall decontamination factor of 1.2E+06 was achieved demonstrating excellent retention of key radioactive species within the concentrated liquid stream. The evaporator system was supported by a modular steam supply, chiller, and control computer systems which would be typically implemented at the tank farms. Operation of these support systems demonstrated successful integration while identifying areas for efficiency improvement. Overall testing effort increased the maturation of this technology to support final deployment design and continued project implementation.

  7. High level waste storage tank farms/242-A evaporator Standards/Requirements Identification Document (S/RID), Volume 6

    SciTech Connect (OSTI)

    Not Available

    1994-04-01

    The High-Level Waste Storage Tank Farms/242-A Evaporator Standards/Requirements Identification Document (S/RID) is contained in multiple volumes. This document (Volume 6) outlines the standards and requirements for the sections on: Environmental Restoration and Waste Management, Research and Development and Experimental Activities, and Nuclear Safety.

  8. A simple technique to reduce evaporation of crystallization droplets by using plate lids with apertures for adding liquids

    SciTech Connect (OSTI)

    Zipper, Lauren E.; Aristide, Xavier; Bishop, Dylan P.; Joshi, Ishita; Kharzeev, Julia; Patel, Krishna B.; Santiago, Brianna M.; Joshi, Karan; Dorsinvil, Kahille; Sweet, Robert M.; Soares, Alexei S.

    2014-11-28

    This article describes the use of evaporation control lids that are fitted to crystallization plates to improve the reproducibility of trials using as little as 5 nl. The plate lids contain apertures which are large enough for the transfer of protein containing droplets, but small enough to greatly reduce the rate of evaporation during the time needed to prepare the plate. A method is described for using plate lids to reduce evaporation in low-volume vapor-diffusion crystallization experiments. The plate lids contain apertures through which the protein and precipitants were added to different crystallization microplates (the reservoir was filled before fitting the lids). Plate lids were designed for each of these commonly used crystallization microplates. This system minimizes the dehydration of crystallization droplets containing just a few nanolitres of protein and precipitant, and results in more reproducible diffraction from the crystals. For each lid design, changes in the weight of the plates were used to deduce the rate of evaporation under different conditions of temperature, air movement, droplet size and precipitant. For comparison, the state of dehydration was also visually assessed throughout the experiment. Finally, X-ray diffraction methods were used to compare the diffraction of protein crystals that were conventionally prepared against those that were prepared on plates with plate lids. The measurements revealed that the plate lids reduced the rate of evaporation by 63–82%. Crystals grown in 5 nl drops that were set up with plate lids diffracted to higher resolution than similar crystals from drops that were set up without plate lids. The results demonstrate that plate lids can be instrumental for improving few-nanolitre crystallizations.

  9. Broadband enhancement of infrared absorption in microbolometers using Ag nanocrystals

    SciTech Connect (OSTI)

    Hyun, Jerome K.; Ahn, Chi Won; Kim, Woo Choong; Kim, Tae Hyun; Hyun, Moon Seop; Kim, Hee Yeoun E-mail: jhpark@nnfc.re.kr; Park, Jae Hong E-mail: jhpark@nnfc.re.kr; Lee, Won-Oh

    2015-12-21

    High performance microbolometers are widely sought for thermal imaging applications. In order to increase the performance limits of microbolometers, the responsivity of the device to broadband infrared (IR) radiation needs to be improved. In this work, we report a simple, quick, and cost-effective approach to modestly enhance the broadband IR response of the device by evaporating Ag nanocrystals onto the light entrance surface of the device. When irradiated with IR light, strong fields are built up within the gaps between adjacent Ag nanocrystals. These fields resistively generate heat in the nanocrystals and underlying substrate, which is transduced into an electrical signal via a resistive sensing element in the device. Through this method, we are able to enhance the IR absorption over a broadband spectrum and improve the responsivity of the device by ∼11%.

  10. Fabrication of ultrathin solid electrolyte membranes of β-Li3PS4 nanoflakes by evaporation-induced self-assembly for all-solid-state batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Hui; Hood, Zachary D.; Xia, Younan; Liang, Chengdu

    2016-04-25

    All-solid-state lithium batteries are attractive candidates for next-generation energy storage devices because of their anticipated high energy density and intrinsic safety. Owing to their excellent ionic conductivity and stability with metallic lithium anodes, nanostructured lithium thiophosphate solid electrolytes such as β-Li3PS4 have found use in the fabrication of all-solid lithium batteries for large-scale energy storage systems. However, current methods for preparing air-sensitive solid electrolyte membranes of lithium thiophosphates can only generate thick membranes that compromise the battery's gravimetric/volumetric energy density and thus its rate performance. To overcome this limitation, the solid electrolyte's thickness needs to be effectively decreased to achievemore » ideal energy density and enhanced rate performance. In this paper, we show that the evaporation-induced self-assembly (EISA) technique produces ultrathin membranes of a lithium thiophosphate solid electrolyte with controllable thicknesses between 8 and 50 μm while maintaining the high ionic conductivity of β-Li3PS4 and stability with metallic lithium anodes up to 5 V. Finally, it is clearly demonstrated that this facile EISA approach allows for the preparation of ultrathin lithium thiophosphate solid electrolyte membranes for all-solid-state batteries.« less