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Sample records for des ox yg

  1. Complex catalytic behaviors of CuTiOx mixed-oxide during CO oxidation

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Complex catalytic behaviors of CuTiOx mixed-oxide during CO oxidation Citation Details In-Document Search This content will become publicly available on September 21, 2016 Title: Complex catalytic behaviors of CuTiOx mixed-oxide during CO oxidation Mixed metal oxides have attracted considerable attention in heterogeneous catalysis due to the unique stability, reactivity, and selectivity. Here, the activity and stability of the CuTiOx monolayer film

  2. Complex catalytic behaviors of CuTiOx mixed-oxide during CO oxidation...

    Office of Scientific and Technical Information (OSTI)

    Complex catalytic behaviors of CuTiOx mixed-oxide during CO oxidation Citation Details ... This content will become publicly available on September 21, 2016 Title: Complex catalytic ...

  3. Interfacial engineering of solution-processed Ni nanochain-SiOx (x < 2)

    Office of Scientific and Technical Information (OSTI)

    cermets towards thermodynamically stable, anti-oxidation solar selective absorbers (Journal Article) | SciTech Connect Interfacial engineering of solution-processed Ni nanochain-SiOx (x < 2) cermets towards thermodynamically stable, anti-oxidation solar selective absorbers Citation Details In-Document Search This content will become publicly available on April 1, 2017 Title: Interfacial engineering of solution-processed Ni nanochain-SiOx (x < 2) cermets towards thermodynamically

  4. Utilisation des défibrillateurs

    ScienceCinema (OSTI)

    None

    2011-10-06

    Information faite par le service medical et le service des pompiers sur l'utilisation des defibrillateurs.

  5. Overall Photocatalytic Water Splitting with NiOx-SrTiO3 – A Revised Mechanism

    SciTech Connect (OSTI)

    Townsend, Troy K.; Browning, Nigel D.; Osterloh, Frank

    2012-11-01

    NiOx (0 < x < 1) modified SrTiO3 (STO) is one of the best studied photocatalyst for overall water splitting under UV light. The established mechanism for this and many other NiOx containing catalysts assumes water oxidation to occur at the early transition metal oxide and water reduction at NiOx. Here we show that NiOx-STO is more likely a three component Ni-STO-NiO catalyst, in which STO absorbs the light, Ni reduces protons, and NiO oxidizes water. This interpretation is based on systematic H2/O2 evolution tests of appropriately varied catalyst compositions using oxidized, chemically and photochemically added nickel and NiO nanoparticle cocatalysts. Surface photovoltage (SPV) measurements reveal that Ni(0) serves as an electron trap (site for water reduction) and that NiO serves as a hole trap (site for water oxidation). Electrochemical measurements show that the overpotential for water oxidation correlates with NiO content, whereas the water reduction overpotential depends on Ni content. Photodeposition experiments with NiCl2 and H2PtCl6 on NiO-STO show that electrons are available on the STO surface, not on the NiO particles. Based on photoelectrochemistry, both NiO and Ni particles suppress the Fermi level in STO, but the effect of this shift on catalytic activity is not clear. Overall, the results suggest a revised role for NiO in NiOx-STO and in many other nickel-containing water splitting systems, including NiOx-La:KTaO3, and many layered perovskites.

  6. Complex catalytic behaviors of CuTiOx mixed-oxide during CO oxidation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kim, Hyun You; Liu, Ping

    2015-09-21

    Mixed metal oxides have attracted considerable attention in heterogeneous catalysis due to the unique stability, reactivity, and selectivity. Here, the activity and stability of the CuTiOx monolayer film supported on Cu(111), CuTiOx/Cu(111), during CO oxidation was explored using density functional theory (DFT). The unique structural frame of CuTiOx is able to stabilize and isolate a single Cu+ site on the terrace, which is previously proposed active for CO oxidation. Furthermore, it is not the case, where the reaction via both the Langmuir–Hinshelwood (LH) and the Mars-van Krevelen (M-vK) mechanisms are hindered on such single Cu+ site. Upon the formation ofmore » step-edges, the synergy among Cuδ+ sites, TiOx matrix, and Cu(111) is able to catalyze the reaction well. Depending on temperatures and partial pressure of CO and O2, the surface structure varies, which determines the dominant mechanism. In accordance with our results, the Cuδ+ ion alone does not work well for CO oxidation in the form of single sites, while the synergy among multiple active sites is necessary to facilitate the reaction.« less

  7. Kinetic simulation of the O-X conversion process in dense magnetized plasmas

    SciTech Connect (OSTI)

    Ali Asgarian, M. [Physics Department, Isfahan University of Technology, Isfahan (Iran, Islamic Republic of) [Physics Department, Isfahan University of Technology, Isfahan (Iran, Islamic Republic of); Department of Electrical and Computer Engineering, Michigan State University, Michigan 48824-1226 (United States); Verboncoeur, J. P. [Department of Electrical and Computer Engineering, Michigan State University, Michigan 48824-1226 (United States)] [Department of Electrical and Computer Engineering, Michigan State University, Michigan 48824-1226 (United States); Parvazian, A. [Physics Department, Isfahan University of Technology, Isfahan (Iran, Islamic Republic of)] [Physics Department, Isfahan University of Technology, Isfahan (Iran, Islamic Republic of); Trines, R. [STFC Rutherford Appleton Laboratory, Didcot (United Kingdom)] [STFC Rutherford Appleton Laboratory, Didcot (United Kingdom)

    2013-10-15

    One scheme for heating a dense magnetized plasma core, such as in a tokamak, involves launching an ordinary (O) electromagnetic wave at the low density edge. It is converted to a reflected extraordinary (X) electromagnetic wave under certain conditions, and then transformed into an electron Bernstein wave able to reach high density regions inaccessible to most other waves. The O-X mode conversion is important in heating and diagnostic processes in different devices such as tokamaks, stellarators, and some types of pinches. The goal of this study has been to demonstrate that the kinetic particle-in-cell (PIC) scheme is suitable for modeling the O-X conversion process as the first step toward a more complete simulation of O-X-B heating. The O-X process is considered and simulated with a kinetic particle model for parameters of the TJ-II stellarator using the PIC code, XOOPIC. This code is able to model the non-monotonic density and the magnetic profile of the TJ-II stellarator. It can also statistically represent the self-consistent distribution function of the plasma, which has not been possible in previous fluid models. By considering the electric and magnetic components of launched and reflected waves, the O-mode and X-mode waves can be detected, and the O-X conversion can be demonstrated. In this work, the optimum angle for conversion efficiency, as predicted by the previous theory and experimentally confirmed, is used. Via considering the power of the launched O-mode wave and the converted X-mode wave, the efficiency of 63% for O-X conversion for the optimum theoretical launch angle of 47{sup ?} is obtained, which is in good agreement with efficiencies computed via full-wave simulations.

  8. MicroRNAs expression in ox-LDL treated HUVECs: MiR-365 modulates apoptosis and Bcl-2 expression

    SciTech Connect (OSTI)

    Qin, Bing; Xiao, Bo; Liang, Desheng; Xia, Jian; Li, Ye; Yang, Huan

    2011-06-24

    Highlights: {yields} We evaluated the role of miRNAs in ox-LDL induced apoptosis in ECs. {yields} We found 4 up-regulated and 11 down-regulated miRNAs in apoptotic ECs. {yields} Target genes of the dysregulated miRNAs regulate ECs apoptosis and atherosclerosis. {yields} MiR-365 promotes ECs apoptosis via suppressing Bcl-2 expression. {yields} MiR-365 inhibitor alleviates ECs apoptosis induced by ox-LDL. -- Abstract: Endothelial cells (ECs) apoptosis induced by oxidized low-density lipoprotein (ox-LDL) is thought to play a critical role in atherosclerosis. MicroRNAs (miRNAs) are a class of noncoding RNAs that posttranscriptionally regulate the expression of genes involved in diverse cell functions, including differentiation, growth, proliferation, and apoptosis. However, whether miRNAs are associated with ox-LDL induced apoptosis and their effect on ECs is still unknown. Therefore, this study evaluated potential miRNAs and their involvement in ECs apoptosis in response to ox-LDL stimulation. Microarray and qRT-PCR analysis performed on human umbilical vein endothelial cells (HUVECs) exposed to ox-LDL identified 15 differentially expressed (4 up- and 11 down-regulated) miRNAs. Web-based query tools were utilized to predict the target genes of the differentially expressed miRNAs, and the potential target genes were classified into different function categories with the gene ontology (GO) term and KEGG pathway annotation. In particular, bioinformatics analysis suggested that anti-apoptotic protein B-cell CLL/lymphoma 2 (Bcl-2) is a target gene of miR-365, an apoptomir up-regulated by ox-LDL stimulation in HUVECs. We further showed that transfection of miR-365 inhibitor partly restored Bcl-2 expression at both mRNA and protein levels, leading to a reduction of ox-LDL-mediated apoptosis in HUVECs. Taken together, our findings indicate that miRNAs participate in ox-LDL-mediated apoptosis in HUVECs. MiR-365 potentiates ox-LDL-induced ECs apoptosis by regulating the expression of Bcl-2, suggesting potential novel therapeutic targets for atherosclerosis.

  9. Nitrogen effects on crystallization kinetics of amorphous TiOxNy thin films

    SciTech Connect (OSTI)

    Hukari, Kyle; Dannenberg, Rand; Stach, E.A.

    2001-03-30

    The crystallization behavior of amorphous TiOxNy (x>>y) thin films was investigated by in-situ transmission electron microscopy. The Johnson-Mehl-Avrami-Kozolog (JMAK) theory is used to determine the Avrami exponent, activation energy, and the phase velocity pre-exponent. Addition of nitrogen inhibits diffusion, increasing the nucleation temperature, while decreasing the growth activation energy. Kinetic variables extracted from individual crystallites are compared to JMAK analysis of the fraction transformed and a change of 6 percent in the activation energy gives agreement between the methods. From diffraction patterns and index of refraction the crystallized phase was found to be predominantly anatase.

  10. Effect of filler metal composition on the strength of yttria stabilized zirconia joints brazed with Pd-Ag-CuOx

    SciTech Connect (OSTI)

    Darsell, Jens T.; Weil, K. Scott

    2008-09-08

    The Ag-CuOx system is of interest to be used to be used as an air braze filler metal for joining high temperature electrochemical devices. Previous work has shown that the melting temperatures can be increased by adding palladium to Ag-CuOx and it is expected that this may aid high temperature stability. This work compares the room temperature bend strength of joints made between yttria-stabilized zirconia (YSZ) air brazed using Ag-CuOx without palladium and with 5 and 15mol% palladium additions. It has been found that in general palladium decreases joint strength, especially in low copper oxide compositions filler metals. At high copper oxide contents, brittle fracture through both copper oxide rich phases and the YSZ limits joint strength.

  11. High critical currents in heavily doped (Gd,Y)Ba2Cu3Ox superconductor tapes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Selvamanickam, V.; Gharahcheshmeh, M. Heydari; Xu, A.; Galstyan, E.; Delgado, L.; Cantoni, C.

    2015-01-20

    REBa2Cu3Ox superconductor tapes with moderate levels of dopants have been optimized for high critical current density in low magnetic fields at 77 K, but they do not exhibit exemplary performance in conditions of interest for practical applications, i.e., temperatures less than 50 K and fields of 2–30 T. Heavy doping of REBCO tapes has been avoided by researchers thus far due to deterioration in properties. Here, we report achievement of critical current densities (Jc) above 20 MA/cm2 at 30 K, 3 T in heavily doped (25 mol. % Zr-added) (Gd,Y)Ba2Cu3Ox superconductor tapes, which is more than three times higher thanmore » the Jc typically obtained in moderately doped tapes. Pinning force levels above 1000 GN/m3 have also been attained at 20 K. A composition map of lift factor in Jc (ratio of Jc at 30 K, 3 T to the Jc at 77 K, 0 T) has been developed which reveals the optimum film composition to obtain lift factors above six, which is thrice the typical value. A highly c-axis aligned BaZrO3 (BZO) nanocolumn defect density of nearly 7 × 1011 cm–2 as well as 2–3nm sized particles rich in Cu and Zr have been found in the high Jc films.« less

  12. Constructing hierarchical interfaces: TiO2-supported PtFe-FeOx nanowires for room temperature CO oxidation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhu, Huiyuan; Wu, Zili; Dong, Su; Veith, Gabriel M.; Lu, Hanfeng; Zhang, Pengfei; Chai, Song -Hai; Dai, Sheng

    2015-08-05

    This is a report of a facile approach to constructing catalytic active hierarchical interfaces in one-dimensional (1D) nanostructure, exemplified by the synthesis of TiO2-supported PtFe–FeOx nanowires (NWs). The hierarchical interface, constituting atomic level interactions between PtFe and FeOx within each NW and the interactions between NWs and support (TiO2), enables CO oxidation with 100% conversion at room temperature. We identify the role of the two interfaces by probing the CO oxidation reaction with isotopic labeling experiments. Both the oxygen atoms (Os) in FeOx and TiO2 participate in the initial CO oxidation, facilitating the reaction through a redox pathway. Moreover, themore » intact 1D structure leads to the high stability of the catalyst. After 30 h in the reaction stream, the PtFe–FeOx/TiO2 catalyst exhibits no activity decay. These results provide a general approach and new insights into the construction of hierarchical interfaces for advanced catalysis.« less

  13. Financiere des Energies | Open Energy Information

    Open Energy Info (EERE)

    Jump to: navigation, search Name: Financiere des Energies Place: Saint Contest, France Zip: 14280 Product: Prospects for new production sites and looks for the best...

  14. Highly dispersed SiOx/Al2O3 catalysts illuminate the reactivity of isolated silanol sites

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mouat, Aidan R.; George, Cassandra; Kobayashi, Takeshi; Pruski, Marek; van Duyne, Richard P.; Marks, Tobin J.; Stair, Peter C.

    2015-09-23

    The reaction of γ-alumina with tetraethylorthosilicate (TEOS) vapor at low temperatures selectively yields monomeric SiOx species on the alumina surface. These isolated (-AlO)3Si(OH) sites are characterized by PXRD, XPS, DRIFTS of adsorbed NH3, CO, and pyridine, and 29Si and 27Al DNP-enhanced solid-state NMR spectroscopy. The formation of isolated sites suggests that TEOS reacts preferentially at strong Lewis acid sites on the γ-Al2O3 surface, functionalizing the surface with “mild” Brønsted acid sites. As a result, for liquid-phase catalytic cyclohexanol dehydration, these SiOx sites exhibit up to 3.5-fold higher specific activity than the parent alumina with identical selectivity.

  15. Structural evolution of epitaxial SrCoOx films near topotactic phase transition

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jeen, Hyoung Jeen; Lee, Ho Nyung

    2015-12-18

    Control of oxygen stoichiometry in complex oxides via topotactic phase transition is an interesting avenue to not only modifying the physical properties, but utilizing in many energy technologies, such as energy storage and catalysts. However, detailed structural evolution in the close proximity of the topotactic phase transition in multivalent oxides has not been much studied. In this work, we used strontium cobaltites (SrCoOx) epitaxially grown by pulsed laser epitaxy (PLE) as a model system to study the oxidation-driven evolution of the structure, electronic, and magnetic properties. We grew coherently strained SrCoO2.5thin films and performed post-annealing at various temperatures for topotacticmore » conversion into the perovskite phase (SrCoO3-δ). We clearly observed significant changes in electronic transport, magnetism, and microstructure near the critical temperature for the topotactic transformation from the brownmillerite to the perovskite phase. Furthermore, the overall crystallinity was well maintained without much structural degradation, indicating that topotactic phase control can be a useful tool to control the physical properties repeatedly via redox reactions.« less

  16. Promotional effect of surface hydroxyls on electrochemical reduction of CO2 over SnOx/Sn electrode

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Cui, Chaonan; Han, Jinyu; Zhu, Xinli; Liu, Xiao; Wang, Hua; Mei, Donghai; Ge, Qingfeng

    2016-01-16

    In this study, tin oxide (SnOx) formation on tin-based electrode surfaces during CO2 electrochemical reduction can have a significant impact on the activity and selectivity of the reaction. In the present study, density functional theory (DFT) calculations have been performed to understand the role of SnOx in CO2 reduction using a SnO monolayer on the Sn(112) surface as a model for SnOx. Water molecules have been treated explicitly and considered actively participating in the reaction. The results showed that H2O dissociates on the perfect SnO monolayer into two hydroxyl groups symmetrically on the surface. CO2 energetically prefers to react withmore » the hydroxyl, forming a bicarbonate (HCO3(t)*) intermediate, which can then be reduced to either formate (HCOO*) by hydrogenating the carbon atom or carboxyl (COOH*) by protonating the oxygen atom. Both steps involve a simultaneous Csingle bondO bond breaking. Further reduction of HCOO* species leads to the formation of formic acid in the acidic solution at pH < 4, while the COOH* will decompose to CO and H2O via protonation. Whereas the oxygen vacancy (VO) in the oxide monolayer maybe formed by the reduction, it can be recovered by H2O dissociation, resulting in two embedded hydroxyl groups. The results show that the hydroxylated surface with two symmetric hydroxyls is energetically more favorable for CO2 reduction than the hydroxylated VO surface with two embedded hydroxyls. The reduction potential for the former has a limiting-potential of –0.20 V (RHE), lower than that for the latter (–0.74 V (RHE)). Compared to the pure Sn electrode, the formation of SnOx monolayer on the electrode under the operating conditions promotes CO2 reduction more effectively by forming surface hydroxyls, thereby providing a new channel via COOH* to the CO formation, although formic acid is still the major reduction product.« less

  17. GoiOF'9yG535--jt; UCRL-JC-114699 PRcTRINT

    Office of Scientific and Technical Information (OSTI)

    ... The model is realized in the prototype computer program 1 PANDORA-l .1. The PANDORA system ... In the last stage of such a release history, the radionuclide is below its solubility ...

  18. Low pressure CO₂ hydrogenation to methanol over gold nanoparticles activated on a CeOx/TiO₂ interface

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yang, Xiaofang; Boscoboinik, J. Anibal; Kattel, Shyam; Senanayake, Sanjaya D.; Nie, Xiaowa; Graciani, Jesus; Rodriguez, Jose A.; Liu, Ping; Stacchiola, Dario J.; Chen, Jingguang G.

    2015-07-28

    Capture and recycling of CO₂ into valuable chemicals such as alcohols could help mitigate its emissions into the atmosphere. Due to its inert nature, the activation of CO₂ is a critical step in improving the overall reaction kinetics during its chemical conversion. Although pure gold is an inert noble metal and cannot catalyze hydrogenation reactions, it can be activated when deposited as nanoparticles on the appropriate oxide support. In this combined experimental and theoretical study, it is shown that an electronic polarization at the metal–oxide interface of Au nanoparticles anchored and stabilized on a CeOx/TiO₂ substrate generates active centers formore » CO₂ adsorption and its low pressure hydrogenation, leading to a higher selectivity toward methanol. In conclusion, this study illustrates the importance of localized electronic properties and structure in catalysis for achieving higher alcohol selectivity from CO₂ hydrogenation.« less

  19. The susceptibility of TaOx-based memristors to high dose rate ionizing radiation and total ionizing dose

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    McLain, Michael Lee; Sheridan, Timothy J.; Hjalmarson, Harold Paul; Mickel, Patrick R.; Hanson, Donald J.; McDonald, Joseph K.; Hughart, David Russell; Marinella, Matthew J.

    2014-11-11

    This paper investigates the effects of high dose rate ionizing radiation and total ionizing dose (TID) on tantalum oxide (TaOx) memristors. Transient data were obtained during the pulsed exposures for dose rates ranging from approximately 5.0 ×107 rad(Si)/s to 4.7 ×108 rad(Si)/s and for pulse widths ranging from 50 ns to 50 μs. The cumulative dose in these tests did not appear to impact the observed dose rate response. Static dose rate upset tests were also performed at a dose rate of ~3.0 ×108 rad(Si)/s. This is the first dose rate study on any type of memristive memory technology. Inmore » addition to assessing the tolerance of TaOx memristors to high dose rate ionizing radiation, we also evaluated their susceptibility to TID. The data indicate that it is possible for the devices to switch from a high resistance off-state to a low resistance on-state in both dose rate and TID environments. The observed radiation-induced switching is dependent on the irradiation conditions and bias configuration. Furthermore, the dose rate or ionizing dose level at which a device switches resistance states varies from device to device; the enhanced susceptibility observed in some devices is still under investigation. As a result, numerical simulations are used to qualitatively capture the observed transient radiation response and provide insight into the physics of the induced current/voltages.« less

  20. Hierarchical heterogeneity at the CeOx-TiO? interface: Electronic and geometric structural influence on the photocatalytic activity of oxide on oxide nanostructures

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    None

    2015-01-13

    Mixed oxide interfaces are critical for delivering active components of demanding catalytic processes such as the photo-catalytic splitting of water. We have studied CeOxTiO? catalysts with low ceria loadings of 1 wt%, 3 wt% and 6 wt% that were prepared with wet impregnation methods to favor a strong interaction between CeOx and TiO?. In these materials the interfaces between CeOx-TiO? have been sequentially loaded (1%, 3% and 6%), with and without Pt (0.5 wt%). The structure and properties of the catalysts were characterized using several X-ray and electron based techniques including XRD, XPS, UPS, NEXAFS, UV-Vis and HR-STEM/STEM-EELS, to unravelmore »the local morphology, bulk structure, surface states and electronic structure. The combination of all these techniques allow us to analyze in a systematic way the complete structural and electronic properties that prevail at the CeOx-TiO? interface. Fluorite structured nano crystallites of ceria on anatase-structured titania were identified by both XRD and NEXAFS. A sequential increasing of the CeOx loading led to the formation of clusters, then plates and finally nano particles in a hierarchical manner on the TiO? support. The electronic structures of these catalysts indicate that the interaction between TiO? and CeO? is closely related to the local morphology of nanostructured CeO?. Ce³? cations were detected at the surface of CeO? and at the interface of the two oxides. In addition, the titania is perturbed by the interaction with ceria and also with Pt. The photocatalytic activity for the splitting of H?O using UV light was measured for these materials and correlated with our understanding of the electronic and structural properties. Optimal catalytic performance and photo response results were found for the 1 wt% CeOx-TiO? catalyst where low dimensional geometry of the ceria provided ideal electronic and geometrical properties. The structural and electronic properties of the interface were critical for the photocatalytic performance of this mixed-oxide nanocatalyst system.« less

  1. Advantages of MgAlOx over gamma-Al2O3 as a support material for potassium-based high temperature lean NOx traps

    SciTech Connect (OSTI)

    Luo, Jinyong; Gao, Feng; Karim, Ayman M.; Xu, Pinghong; Browning, Nigel D.; Peden, Charles HF

    2015-08-07

    MgAlOx mixed oxides were employed as supports for potassium-based lean NOx traps (LNTs) targeted for high temperature applications. Effects of support compositions, K/Pt loadings, thermal aging and catalyst regeneration on NOx storage capacity were systematically investigated. The catalysts were characterized by XRD, NOx-TPD, TEM, STEM-HAADF and in-situ XAFS. The results indicate that MgAlOx mixed oxides have significant advantages over conventional gamma-Al2O3-supports for LNT catalysts, in terms of high temperature NOx trapping capacity and thermal stability. First, as a basic support, MgAlOx stabilizes stored nitrates (in the form of KNO3) to much higher temperatures than mildly acidic gamma-Al2O3. Second, MgAlOx minimizes Pt sintering during thermal aging, which is not possible for gamma-Al2O3 supports. Notably, combined XRD, in-situ XAFS and STEM-HAADF results indicate that Pt species in the thermally aged Pt/MgAlOx samples are finely dispersed in the oxide matrix as isolated atoms. This strong metal-support interaction stabilizes Pt and minimizes the extent of sintering. However, such strong interactions result in Pt oxidation via coordination with the support so that NO oxidation activity can be adversely affected after aging which, in turn, decreases NOx trapping ability for these catalysts. Interestingly, a high-temperature reduction treatment regenerates essentially full NOx trapping performance. In fact, regenerated Pt/K/MgAlOx catalyst exhibits much better NOx trapping performance than fresh Pt/K/Al2O3 LNTs over the entire temperature range investigated here. In addition to thermal aging, Pt/K loading effects were systemically studied over the fresh samples. The results indicate that NOx trapping is kinetically limited at low temperatures, while thermodynamically limited at high temperatures. A simple conceptual model was developed to explain the Pt and K loading effects on NOx storage. An optimized K loading, which allows balancing between the stability of nitrates and exposed Pt surface, gives the best NOx trapping capability.

  2. Community Environmental Response Facilitation Act (CERFA) report. Fort Des Moines, Des Moines, Iowa. Final report

    SciTech Connect (OSTI)

    Young, B.; Rausch, K.; Kang, J.

    1994-04-01

    This report presents the results of the Community Environmental Response Facilitation Act (CERFA) investigation conducted by The Earth Technology Corporation (TETC) at the Fort Des Moines, a U.S. Government property selected for closure by the Base Realignment and Closure (BRAC) Commission. Under CERFA Federal agencies are required to identify real property that can be immediately reused and redeveloped. Satisfying this objective requires the identification of real property where no hazardous substances or petroleum products, regulated by the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA), were stored for one year or more, known to have been released, or disposed. Fort Des Moines is a 53.28-acre site located in Polk County, Iowa, within the city limits of Des Moines. The installation's primary mission is to provide support and shelter for the U.S. Army Reserve. Activities associated with the property that have environmental significance are photographic processing, vehicle maintenance, printing, and fuel storage. TETC reviewed existing investigation documents; U.S. Environmental Protection Agency (USEPA), State, and county regulatory records; environmental data bases; and title documents pertaining to Fort Des Moines during this investigation. In addition, TETC conducted interviews and visual inspections of Fort Des Moines as well as visual inspections and data base searches for the surrounding properties. Information in this CERFA Report was current as of April 1994.

  3. GeOx/Reduced Graphene Oxide Composite as an Anode for Li-ion Batteries: Enhanced Capacity via Reversible Utilization of Li2O along with Improved Rate Performance

    SciTech Connect (OSTI)

    Lv, Dongping; Gordin, Mikhail; Yi, Ran; Xu, Terrence (Tianren); Song, Jiangxuan; Jiang, Yingbing; Choi, Daiwon; Wang, Donghai

    2014-09-01

    A self-assembled GeOx/reduced graphene oxide (GeOx/RGO) composite, where GeOx nanoparticles were grown directly on reduced graphene oxide sheets, was synthesized via a facile one-step reduction approach and studied by X-ray diffraction, transmission electron microscopy, energy dispersive X-ray spectroscopy, electron energy loss spectroscopy elemental mapping, and other techniques. Electrochemical evaluation indicates that incorporation of reduced graphene oxide enhances both the rate capability and reversible capacity of GeOx, with the latter being due to the RGO enabling reversible utilization of Li2O. The composite delivers a high reversible capacity of 1600 mAhg-1 at a current density of 100 mAg-1, and still maintains a capacity of 410 mAhg-1 at a high current density of 20 Ag-1. Owing to the flexible reduced graphene oxide sheets enwrapping the GeOx particles, the cycling stability of the composite was also improved significantly. To further demonstrate its feasibility in practical applications, the synthesized GeOx/RGO composite anode was successfully paired with a high voltage LiNi0.5Mn1.5O4 cathode to form a full cell, which showed good cycling and rate performance.

  4. Sécurité au-delà des mythes et des croyances

    ScienceCinema (OSTI)

    None

    2011-10-06

    Présentation orale en français, support visuel en français et en anglais. La pire des failles de sécurité est l'impression de sécurité. Le décalage entre la compréhension que l?on a des technologies utilisées, et leurs potentiels réels, ainsi que l'impact potentiellement négatif qu'elles peuvent avoir sur nos vies, n'est pas toujours compris, ou pris en compte par la plupart d'entre-nous. On se contente de nos perceptions pour ne pas avoir à se confronter à la réalité... Alors qu'en est-il vraiment ? En matière de sécurité qui de l'humain ou des technologies a le contrôle ?

  5. Laboratoire de Physique des Interfaces et Couches Minces LPICM...

    Open Energy Info (EERE)

    Laboratoire de Physique des Interfaces et Couches Minces (LPICM) Place: Palaiseau, France Zip: 91128 Sector: Carbon Product: Research department of the Ecole Polytechnique in...

  6. Des Plaines, Illinois: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    10th congressional district.12 Registered Energy Companies in Des Plaines, Illinois Gas Technology Institute (Partnership for Advanced Residential Retrofit) NARI National...

  7. Total ionizing dose effect of ?-ray radiation on the switching characteristics and filament stability of HfOx resistive random access memory

    SciTech Connect (OSTI)

    Fang, Runchen; Yu, Shimeng; Gonzalez Velo, Yago; Chen, Wenhao; Holbert, Keith E.; Kozicki, Michael N.; Barnaby, Hugh

    2014-05-05

    The total ionizing dose (TID) effect of gamma-ray (?-ray) irradiation on HfOx based resistive random access memory was investigated by electrical and material characterizations. The memory states can sustain TID level ?5.2 Mrad (HfO{sub 2}) without significant change in the functionality or the switching characteristics under pulse cycling. However, the stability of the filament is weakened after irradiation as memory states are more vulnerable to flipping under the electrical stress. X-ray photoelectron spectroscopy was performed to ascertain the physical mechanism of the stability degradation, which is attributed to the Hf-O bond breaking by the high-energy ?-ray exposure.

  8. Average and local crystal structures of (Ga1–xZnx)(N1–xOx) solid solution nanoparticles

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Feygenson, Mikhail; Neuefeind, Joerg C.; Tyson, Trevor A.; Schieber, Natalie; Han, Wei -Qiang

    2015-11-06

    We report the comprehensive study of the crystal structure of (Ga1–xZnx)(N1–xOx) solid solution nanoparticles by means of neutron and synchrotron x-ray scattering. In our study we used four different types of (Ga1–xZnx)(N1–xOx) nanoparticles, with diameters of 10–27 nm and x = 0.075–0.51, which show the narrow energy-band gaps from 2.21 to 2.61 eV. The Rietveld analysis of the neutron diffraction data revealed that the average crystal structure is the hexagonal wurtzite (space group P63mc), in agreement with previous reports on similar bulk materials. The pair-distribution function (PDF) analysis of the same data found that the local structure is more disorderedmore » than the average one. It is best described by the model with a lower symmetry space group P1, where atoms are quasirandomly distorted from their nominal positions in the hexagonal wurtzite lattice.« less

  9. Des Moines, Washington: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    This article is a stub. You can help OpenEI by expanding it. Des Moines is a city in King County, Washington. It falls under Washington's 9th congressional district.12...

  10. West Des Moines, Iowa: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Hide Map This article is a stub. You can help OpenEI by expanding it. West Des Moines is a city in Dallas County and Polk County and Warren County, Iowa. It falls...

  11. A Touch of Green for Des Moines’ Sherman Hill

    Broader source: Energy.gov [DOE]

    Des Moines' Green & Main intends to intends to renovate an abandoned 1930s grocery store into a mixed-use facility with LEED Platinum certification – a prestigious badge of energy efficiency and sustainable building practices.

  12. 15N2 formation and fast oxygen isotope exchange during pulsed 15N18O exposure of MnOx/CeO2

    SciTech Connect (OSTI)

    Kwak, Ja Hun; Szanyi, Janos

    2014-12-23

    Pulsing 15N18O onto an annealed 1% Mn16Ox/Ce16O2 catalyst resulted in very fast oxygen isotope exchange and 15N2 formation at 295 K. In the 1st 15N18O pulse, due to the presence of large number of surface oxygen defects, extensive 15N218O and 15N2 formations were observed. In subsequent pulses oxygen isotope exchange dominated as a result of highly labile oxygen in the oxide. We gratefully acknowledge the US Department of Energy (DOE), Office of Energy Efficiency and Renewable Energy/Vehicle Technologies Program for the support of this work. The research described in this paper was performed at the Environmental Molecular Sciences Laboratory (EMSL), a national scientific user facility sponsored by the DOE’s Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory (PNNL). PNNL is operated for the US DOE by Battelle.

  13. APUI Incubateur de l Ecole des Mines de Douai | Open Energy Informatio...

    Open Energy Info (EERE)

    APUI Incubateur de l Ecole des Mines de Douai Jump to: navigation, search Name: APUI Incubateur de l'Ecole des Mines de Douai Place: France Sector: Services Product: General...

  14. After 105 Years, Historic City Hall in West Des Moines, Iowa Goes Green |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy After 105 Years, Historic City Hall in West Des Moines, Iowa Goes Green After 105 Years, Historic City Hall in West Des Moines, Iowa Goes Green May 9, 2011 - 5:22pm Addthis The restored Historic City Hall building in West Des Moines' Valley Junction neighborhood. | Photo credit: Vicky Saylor The restored Historic City Hall building in West Des Moines' Valley Junction neighborhood. | Photo credit: Vicky Saylor April Saylor April Saylor Former Digital Outreach Strategist,

  15. Simulations of the OzDES AGN reverberation mapping project

    SciTech Connect (OSTI)

    King, Anthea L.; Martini, Paul; Davis, Tamara M.; Denney, K. D.; Kochanek, C. S.; Peterson, Bradley M.; Skielboe, Andreas; Vestergaard, Marianne; Huff, Eric; Watson, Darach; Banerji, Manda; McMahon, Richard; Sharp, Rob; Lidman, C.

    2015-08-26

    As part of the Australian spectroscopic dark energy survey (OzDES) we are carrying out a large-scale reverberation mapping study of ~500 quasars over five years in the 30 deg2 area of the Dark Energy Survey (DES) supernova fields. These quasars have redshifts ranging up to 4 and have apparent AB magnitudes between 16.8 mag < r < 22.5 mag. The aim of the survey is to measure time lags between fluctuations in the quasar continuum and broad emission-line fluxes of individual objects in order to measure black hole masses for a broad range of active galactic nuclei (AGN) and constrain the radius–luminosity (R–L) relationship. Here we investigate the expected efficiency of the OzDES reverberation mapping campaign and its possible extensions. We expect to recover lags for ~35–45 % of the quasars. AGN with shorter lags and greater variability are more likely to yield a lag measurement, and objects with lags ≲6 months or ~1 yr are expected to be recovered the most accurately. The baseline OzDES reverberation mapping campaign is predicted to produce an unbiased measurement of the R–L relationship parameters for Hβ, MgIIλ2798, and C IVλ1549. As a result, extending the baseline survey by either increasing the spectroscopic cadence, extending the survey season, or improving the emission-line flux measurement accuracy will significantly improve the R–L parameter constraints for all broad emission lines.

  16. Photocatalytic splitting of water under visible-light irradiation over the NiOx-loaded Sm{sub 2}InTaO{sub 7} with 4f-d{sup 10}-d{sup 0} configuration

    SciTech Connect (OSTI)

    Tang Xinde; Ye Hongqi; Liu Hui; Ma Chenxia; Zhao Zhi

    2010-01-15

    A new visible-light-response photocatalyst Sm{sub 2}InTaO{sub 7} with 4f-d{sup 10}-d{sup 0} configuration crystallized in a cubic system with the space group Fd3m was synthesized by a solid-state reaction method. NiOx-loaded Sm{sub 2}InTaO{sub 7} showed high photocatalytic activities for H{sub 2} evolution from pure water under visible light irradiation (lambda>400 nm). Changes in the photocatalytic activity with the calcination temperature of Sm{sub 2}InTaO{sub 7} and the amount of NiOx loaded indicated that the combination of highly crystallized Sm{sub 2}InTaO{sub 7} and a high dispersion of NiOx particles led to high photocatalytic activity. The high photocatalytic performance of NiOx-loaded Sm{sub 2}InTaO{sub 7} supported the existing view that the photocatalytic activity correlated with the lattice distortion. Density functional theory calculation indicated that strong dispersion from the hybridized In 5s 5p orbitals at the bottom of the conduction band was responsible for the high activity of photocatalyst Sm{sub 2}InTaO{sub 7}. - Graphical abstract: A new visible-light-response photocatalyst Sm{sub 2}InTaO{sub 7} with 4f-d{sup 10}-d{sup 0} configuration was developed. DFT calculation indicated that strong dispersion from the hybridized In 5s 5p orbitals was responsible for the high photocatalytic activity.

  17. High Catalytic Activity of Au/CeOx/TiO2(110) Controlled by the Nature of the Mixed Metal Oxide at the Nanometer Level

    SciTech Connect (OSTI)

    Park, J.; Graciani, J; Evans, J; Stacchiola, D; Ma, S; Liu, P; Nambu, A; Sanz, J; Hrbek, J; et. al.

    2009-01-01

    Mixed-metal oxides play a very important role in many areas of chemistry, physics, materials science, and geochemistry. Recently, there has been a strong interest in understanding phenomena associated with the deposition of oxide nanoparticles on the surface of a second (host) oxide. Here, scanning tunneling microscopy, photoemission, and density-functional calculations are used to study the behavior of ceria nanoparticles deposited on a TiO2(110) surface. The titania substrate imposes nontypical coordination modes on the ceria nanoparticles. In the CeOx/TiO2(110) systems, the Ce cations adopt an structural geometry and an oxidation state (+3) that are quite different from those seen in bulk ceria or for ceria nanoparticles deposited on metal substrates. The increase in the stability of the Ce3+ oxidation state leads to an enhancement in the chemical and catalytic activity of the ceria nanoparticles. The codeposition of ceria and gold nanoparticles on a TiO2(110) substrate generates catalysts with an extremely high activity for the production of hydrogen through the water-gas shift reaction (H2O + CO ? H2 + CO2) or for the oxidation of carbon monoxide (2CO + O2 ? 2CO2). The enhanced stability of the Ce3+ state is an example of structural promotion in catalysis described here on the atomic level. The exploration of mixed-metal oxides at the nanometer level may open avenues for optimizing catalysts through stabilization of unconventional surface structures with special chemical activity.

  18. The DES Science Verification Weak Lensing Shear Catalogs

    SciTech Connect (OSTI)

    Jarvis, M.

    2015-07-20

    We present weak lensing shear catalogs for 139 square degrees of data taken during the Science Verification (SV) time for the new Dark Energy Camera (DECam) being used for the Dark Energy Survey (DES). We describe our object selection, point spread function estimation and shear measurement procedures using two independent shear pipelines, IM3SHAPE and NGMIX, which produce catalogs of 2.12 million and 3.44 million galaxies respectively. We also detail a set of null tests for the shear measurements and find that they pass the requirements for systematic errors at the level necessary for weak lensing science applications using the SV data. Furthermore, we discuss some of the planned algorithmic improvements that will be necessary to produce sufficiently accurate shear catalogs for the full 5-year DES, which is expected to cover 5000 square degrees.

  19. Simulations of the OzDES AGN reverberation mapping project

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    King, Anthea L.; Martini, Paul; Davis, Tamara M.; Denney, K. D.; Kochanek, C. S.; Peterson, Bradley M.; Skielboe, Andreas; Vestergaard, Marianne; Huff, Eric; Watson, Darach; et al

    2015-08-26

    As part of the Australian spectroscopic dark energy survey (OzDES) we are carrying out a large-scale reverberation mapping study of ~500 quasars over five years in the 30 deg2 area of the Dark Energy Survey (DES) supernova fields. These quasars have redshifts ranging up to 4 and have apparent AB magnitudes between 16.8 mag < r < 22.5 mag. The aim of the survey is to measure time lags between fluctuations in the quasar continuum and broad emission-line fluxes of individual objects in order to measure black hole masses for a broad range of active galactic nuclei (AGN) and constrainmore » the radius–luminosity (R–L) relationship. Here we investigate the expected efficiency of the OzDES reverberation mapping campaign and its possible extensions. We expect to recover lags for ~35–45 % of the quasars. AGN with shorter lags and greater variability are more likely to yield a lag measurement, and objects with lags ≲6 months or ~1 yr are expected to be recovered the most accurately. The baseline OzDES reverberation mapping campaign is predicted to produce an unbiased measurement of the R–L relationship parameters for Hβ, MgIIλ2798, and C IVλ1549. As a result, extending the baseline survey by either increasing the spectroscopic cadence, extending the survey season, or improving the emission-line flux measurement accuracy will significantly improve the R–L parameter constraints for all broad emission lines.« less

  20. CMB lensing tomography with the DES Science Verification galaxies

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Giannantonio, T.

    2016-01-07

    We measure the cross-correlation between the galaxy density in the Dark Energy Survey (DES) Science Verification data and the lensing of the cosmic microwave background (CMB) as reconstructed with the Planck satellite and the South Pole Telescope (SPT). When using the DES main galaxy sample over the full redshift range 0.2 < zphot < 1.2, a cross-correlation signal is detected at 6σ and 4σ with SPT and Planck respectively. We then divide the DES galaxies into five photometric redshift bins, finding significant (>2σ) detections in all bins. Comparing to the fiducial Planck cosmology, we find the redshift evolution of themore » signal matches expectations, although the amplitude is consistently lower than predicted across redshift bins. We test for possible systematics that could affect our result and find no evidence for significant contamination. Finally, we demonstrate how these measurements can be used to constrain the growth of structure across cosmic time. We find the data are fit by a model in which the amplitude of structure in the z < 1.2 universe is 0.73 ± 0.16 times as large as predicted in the LCDM Planck cosmology, a 1.7σ deviation.« less

  1. Cosmology from Cosmic Shear with DES Science Verification Data

    SciTech Connect (OSTI)

    Abbott, T.

    2015-07-20

    We present the first constraints on cosmology from the Dark Energy Survey (DES), using weak lensing measurements from the preliminary Science Verification (SV) data. We use 139 square degrees of SV data, which is less than 3% of the full DES survey area. Using cosmic shear 2-point measurements over three redshift bins we find ?8(m=0.3)0.5 = 0:81 ± 0:06 (68% confidence), after marginalising over 7 systematics parameters and 3 other cosmological parameters. Furthermore, we examine the robustness of our results to the choice of data vector and systematics assumed, and find them to be stable. About 20% of our error bar comes from marginalising over shear and photometric redshift calibration uncertainties. The current state-of-the-art cosmic shear measurements from CFHTLenS are mildly discrepant with the cosmological constraints from Planck CMB data. Our results are consistent with both datasets. Our uncertainties are ~30% larger than those from CFHTLenS when we carry out a comparable analysis of the two datasets, which we attribute largely to the lower number density of our shear catalogue. We investigate constraints on dark energy and find that, with this small fraction of the full survey, the DES SV constraints make negligible impact on the Planck constraints. The moderate disagreement between the CFHTLenS and Planck values of ?8(?m=0.3)0.5 is present regardless of the value of w.

  2. Partager : des technologies de pointe au service de la société

    ScienceCinema (OSTI)

    None

    2011-10-06

    Médecine, climatologie, métrologie et informatique, les techniques utilisées par le LHC trouvent déjà des répercussions dans d?autres domaines scientifiques. Utilisant des techniques inédites, la physique des particules en fait bénéficier la société toute entière.

  3. Superfund Record of Decision (EPA Region 7): Des Moines TCE Site, Operable Unit 3, Des Moines, IA. (Second remedial action), September 1992. Final report

    SciTech Connect (OSTI)

    Not Available

    1992-09-18

    The Des Moines TCE site is located southwest of downtown Des Moines, Polk County, Iowa. Land use in the area is predominantly industrial and commercial, and part of the site lies within the floodplain of the Raccoon River. Water from the Des Moines Water Works north infiltration gallery was found to be contaminated with trichloroethylene (TCE), dichloroethylene (DCE), and vinyl chloride at levels above accepted drinking water standards. The ROD addresses OU3, which encompasses potential sources of ground water contamination in an area north of the Raccoon River. The selected remedial action for OU3 includes no action with periodic groundwater monitoring.

  4. Hydrogenation of CO2 to methanol on CeOx/Cu(111) and ZnO/Cu(111) catalysts: Role of the metal-oxide interface and importance of Ce3+ sites

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sanjaya D. Senanayake; Ramirez, Pedro J.; Waluyo, Iradwikanari; Kundu, Shankhamala; Mudiyanselage, Kumudu; Liu, Zongyuan; Liu, Zhi; Axnanda, Stephanus; Stacchiola, Dario J.; Evans, Jaime; et al

    2016-01-06

    The role of the interface between a metal and oxide (CeOx–Cu and ZnO–Cu) is critical to the production of methanol through the hydrogenation of CO2 (CO2 + 3H2 → CH3OH + H2O). The deposition of nanoparticles of CeOx or ZnO on Cu(111), θoxi < 0.3 monolayer, produces highly active catalysts for methanol synthesis. The catalytic activity of these systems increases in the sequence: Cu(111) < ZnO/Cu(111) < CeOx/Cu(111). The apparent activation energy for the CO2 → CH3OH conversion decreases from 25 kcal/mol on Cu(111) to 16 kcal/mol on ZnO/Cu(111) and 13 kcal/mol on CeOx/Cu(111). The surface chemistry of the highlymore » active CeOx–Cu(111) interface was investigated using ambient pressure X-ray photoemission spectroscopy (AP-XPS) and infrared reflection absorption spectroscopy (AP-IRRAS). Both techniques point to the formation of formates (HCOO–) and carboxylates (CO2δ–) during the reaction. Our results show an active state of the catalyst rich in Ce3+ sites which stabilize a CO2δ– species that is an essential intermediate for the production of methanol. Furthermore, the inverse oxide/metal configuration favors strong metal–oxide interactions and makes possible reaction channels not seen in conventional metal/oxide catalysts.« less

  5. Cobalt-iron red-ox behavior in nanostructured La{sub 0.4}Sr{sub 0.6}Co{sub 0.8}Fe{sub 0.2}O{sub 3-{delta}} cathodes

    SciTech Connect (OSTI)

    Soldati, Analia L.; Baque, Laura; Napolitano, Federico; Serquis, Adriana

    2013-02-15

    Nano-sized La{sub 0.4}Sr{sub 0.6}Co{sub 0.8}Fe{sub 0.2}O{sub 3-{delta}} (LSCF) perovskite samples (prepared by a conventional acetate route and a novel acetate synthesis with HMTA additives), were tested simulating a red-ox cycle. The crystallography was studied by X-ray Powder Diffraction (XPD) and the changes in the oxidation state of the perovskite B-site were evaluated by synchrotron X-ray Absorption Near Edge Spectroscopy (XANES). After a reducing treatment, LSFC particles show the appearance of a new phase that coexists with the original one. The structural change is accompanied by a Co and Fe formal oxidation states decrease, although Fe remains always closer to 4+ and Co closer to 3+. The treatment produces a B-site valence average reduction from 3.52+ to 3.26+ and the formation of oxygen vacancies. A re-oxidation treatment under O{sub 2} rich atmosphere at 800 Degree-Sign C for 10 h shows that the change is reversible and independent of the two chemical methods used to synthesize the LSCF nano-particles. - Graphical abstract: XANES and XPD measurements in nanostructured LSCF before (black) and after (red/green) a red/ox cycle. Highlights: Black-Right-Pointing-Pointer Red-ox treatments in LSCF nano-particles cause a reversible reaction. Black-Right-Pointing-Pointer XPD analyses show that a new 'reduced' phase coexist with the oxidize one. Black-Right-Pointing-Pointer The B-site formal oxidation state decreases and the {delta} increases upon reduction. Black-Right-Pointing-Pointer Fe remains in a higher valence (closer to 4+) than Co (close to 3+). Black-Right-Pointing-Pointer The behavior seems to be independent of the synthesis method used.

  6. A DES ASIC Suitable for Network Encryption at 10 Gbps and Beyond

    SciTech Connect (OSTI)

    Gass, Karl; Pierson, Lyndon G.; Robertson, Perry J.; Wilcox, D. Craig; Witzke, Edward L.

    1999-04-30

    The Sandia National Laboratories (SNL) Data Encryption Standard (DES) Application Specific Integrated Circuit (ASIC) is the fastest known implementation of the DES algorithm as defined in the Federal Information Processing Standards (FIPS) Publication 46-2. DES is used for protecting data by cryptographic means. The SNL DES ASIC, over 10 times faster than other currently available DES chips, is a high-speed, filly pipelined implementation offering encryption, decryption, unique key input, or algorithm bypassing on each clock cycle. Operating beyond 105 MHz on 64 bit words, this device is capable of data throughputs greater than 6.7 Billion bits per second (tester limited). Simulations predict proper operation up to 9.28 Billion bits per second. In low frequency, low data rate applications, the ASIC consumes less that one milliwatt of power. The device has features for passing control signals synchronized to throughput data. Three SNL DES ASICS may be easily cascaded to provide the much greater security of triple-key, triple-DES.

  7. New Processing and Characterization Approaches for Achieving Full Performance of High Temperature Superconducting Tapes of (Bi,Pb)2Sr2Ca2Cu3Ox

    SciTech Connect (OSTI)

    E.E. Hellstrom; D.C. Larbalestier

    2006-03-22

    The thrust of this research was to identify and understand current limiting mechanisms (CLMs) that limit the current carrying capacity of (Bi,Pb)2Sr2Ca2Cu3Ox (2223) in Ag-sheathed wire. Our program concentrated on developing new methods to identify CLMs at the micrometer scale and new processing techniques to eliminate CLMs. All of the DOE Superconductivity Partnership Initiative (SPI) programs are using 2223 wire, so increasing the critical current density (Jc) in the wire can improve the technical performance of the demonstration projects, and at the same time it can decrease the cost of the wire. The important cost metric for superconducting wire is $/kAm, so increasing Jc, which is in the denominator, decreases the wire cost. The obvious CLMs were micrometer size obstacles in the 2223 ceramic that block current flow, including: misaligned grains, cracks, pores, and nonsuperconducting phases. Pores and cracks - regions where there is no superconductor or the grains are not physically connected to one another ? cannot carry supercurrent, so they were the first CLMs we tried to eliminate with improved processing. Prior to the contract, we had started investigating overpressure (OP) processing with Williams at ORNL to heal cracks and remove pores. OP processing, which is a variant of hot isostatic pressing (HIP), uses an Ar/O2 gas mixture to apply a high pressure (up to 200 atm) to compress the sample and to set the oxygen partial pressure (pO2) to form 2223. Williams had a static pressure system we used to demonstrate that OP processing healed cracks and densified the wire, but the static system limited the processing parameters we could investigate. We proposed building a new gas-flow OP system to expand the experimental capabilities and to investigate new processing routes using the gas-flow OP system. Using the gas-flow OP system, we established new world records in 2003 for Jc and Ic. These records were finally matched by Sumitomo Electric Company in early 2006. The finest scale at which we could probe the local electromagnetic properties of a sample was about 100 m at the beginning of the contract. This was done by attaching voltage taps (10 m diameter wires) about 100 m apart on the 2223 conductor, and measuring the local I-V characteristics between each set of voltage taps. However, the largest CLMs were 2-3 times smaller than this length scale, and most CLMs were even much smaller. The original proposal was to investigate new methods to identify specific regions in samples that contained CLMs from their electromagnetic response, then to examine these regions of the sample using microstructural techniques to identify the CLM. We extended the use of magneto-optic (MO) imaging and magneto-optic current reconstruction (MOCR) and began developing a low-temperature laser scanning microscope (LTLSM) to show local current flow and local current dissipation, respectively, with a resolution of ~5 m. With MOCR we were able to show that local Jc in small regions of OP processed 2223 wire was as high as 300 kA/cm2 at 77K, which was 5-6 times higher than the average Jc measured across the whole sample.

  8. Detection of the kinematic Sunyaev-Zel'dovich effect with DES Year 1 and

    Office of Scientific and Technical Information (OSTI)

    SPT (Journal Article) | SciTech Connect Detection of the kinematic Sunyaev-Zel'dovich effect with DES Year 1 and SPT Citation Details In-Document Search Title: Detection of the kinematic Sunyaev-Zel'dovich effect with DES Year 1 and SPT We detect the kinematic Sunyaev-Zel'dovich (kSZ) effect with a statistical significance of $$4.2 \sigma$$ by combining a cluster catalogue derived from the first year data of the Dark Energy Survey (DES) with CMB temperature maps from the South Pole Telescope

  9. Galaxy-Galaxy Lensing in the DES Science Verification Data (Journal...

    Office of Scientific and Technical Information (OSTI)

    Dividing the lenses into three redshift bins, we find no evidence for evolution in the ... cosmological and galaxy evolution studies with the DES data and redMaGiC galaxy samples. ...

  10. Explorer : des clés pour mieux comprendre la matière

    ScienceCinema (OSTI)

    None

    2011-10-06

    Le LHC va-t-il bouleverser les théories de l'infiniment petit ? Les physiciens aimeraient que l'accélérateur fasse trembler le modèle standard. Cette théorie des particules élémentaires et des forces laisse de nombreuses zones d'ombre. Le LHC et ses expériences ont été conçus pour les éclairer.

  11. Energy Secretary Moniz to Travel to Des Moines and Ames | The Ames

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Laboratory to Travel to Des Moines and Ames News Media Contact: (202) 586-4940 For Immediate Release: Wednesday, May 5, 2016 WASHINGTON - On Friday, Energy Secretary Ernest Moniz will travel to Des Moines, Iowa, where he will participate in a public stakeholder meeting on the second installment of the Quadrennial Energy Review (QER), an integrated study of the U.S. electricity system. Building on the first installment of the QER, which examined the key infrastructure needed for transmission,

  12. Cosmic Shear Measurements with DES Science Verification Data

    SciTech Connect (OSTI)

    Becker, M. R.

    2015-07-20

    We present measurements of weak gravitational lensing cosmic shear two-point statistics using Dark Energy Survey Science Verification data. We demonstrate that our results are robust to the choice of shear measurement pipeline, either ngmix or im3shape, and robust to the choice of two-point statistic, including both real and Fourier-space statistics. Our results pass a suite of null tests including tests for B-mode contamination and direct tests for any dependence of the two-point functions on a set of 16 observing conditions and galaxy properties, such as seeing, airmass, galaxy color, galaxy magnitude, etc. We use a large suite of simulations to compute the covariance matrix of the cosmic shear measurements and assign statistical significance to our null tests. We find that our covariance matrix is consistent with the halo model prediction, indicating that it has the appropriate level of halo sample variance. We also compare the same jackknife procedure applied to the data and the simulations in order to search for additional sources of noise not captured by the simulations. We find no statistically significant extra sources of noise in the data. The overall detection significance with tomography for our highest source density catalog is 9.7σ. Cosmological constraints from the measurements in this work are presented in a companion paper (DES et al. 2015).

  13. EECBG Success Story: After 105 Years, Historic City Hall in West Des Moines, Iowa Goes Green

    Broader source: Energy.gov [DOE]

    The city of West Des Moines, Iowa is used funding to renovate the Historic City Hall building located in Valley Junction, including the installation of four geothermal heating wells, a rooftop covered with vegetation, solar panels and permeable pavers to allow stormwater through to the soil below. Learn more.

  14. DES13S2cmm: The first superluminous supernova from the dark energy survey

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Papadopoulos, A.; D'Andrea, C. B.; Sullivan, M.; Nichol, R. C.; Barbary, K.; Biswas, R.; Brown, P. J.; Covarrubias, R. A.; Finley, D. A.; Fischer, J. A.; et al

    2015-03-23

    We present DES13S2cmm, the first spectroscopically-confirmed superluminous supernova (SLSN) from the Dark Energy Survey (DES). We briefly discuss the data and search algorithm used to find this event in the first year of DES operations, and outline the spectroscopic data obtained from the European Southern Observatory (ESO) Very Large Telescope to confirm its redshift (z = 0.663 ± 0.001 based on the host-galaxy emission lines) and likely spectral type (type I). Using this redshift, we find MUpeak = -21.05???¹?-0.09 for the peak, rest-frame U-band absolute magnitude, and find DES13S2cmm to be located in a faint, low metallicity (sub-solar), low stellar-massmore »host galaxy (log(M/M_sun) = 9.3 ± 0.3); consistent with what is seen for other SLSNe-I. We compare the bolometric light curve of DES13S2cmm to fourteen similarly well-observed SLSNe-I in the literature and find it possesses one of the slowest declining tails (beyond +30 days rest frame past peak), and is the faintest at peak. Moreover, we find the bolometric light curves of all SLSNe-I studied herein possess a dispersion of only 0.2-0.3 magnitudes between +25 and +30 days after peak (rest frame) depending on redshift range studied; this could be important for 'standardising' such supernovae, as is done with the more common type Ia. We fit the bolometric light curve of DES13S2cmm with two competing models for SLSNe-I - the radioactive decay of ??Ni, and a magnetar - and find that while the magnetar is formally a better fit, neither model provides a compelling match to the data. Although we are unable to conclusively differentiate between these two physical models for this particular SLSN-I, further DES observations of more SLSNe-I should break this degeneracy, especially if the light curves of SLSNe-I can be observed beyond 100 days in the rest frame of the supernova.« less

  15. DES13S2cmm: The first superluminous supernova from the Dark Energy Survey

    SciTech Connect (OSTI)

    Papadopoulos, A.; Plazas, A. A.; D"Andrea, C. B.; Sullivan, M.; Nichol, R. C.; Barbary, K.; Biswas, R.; Brown, P. J.; Covarrubias, R. A.; Finley, D. A.; Fischer, J. A.; Foley, R. J.; Goldstein, D.; Gupta, R. R.; Kessler, R.; Kovacs, E.; Kuhlmann, S. E.; Lidman, C.; March, M.; Nugent, P. E.; Sako, M.; Smith, R. C.; Spinka, H.; Wester, W.; Abbott, T. M. C.; Abdalla, F.; Allam, S. S.; Banerji, M.; Bernstein, J. P.; Bernstein, R. A.; Carnero, A.; da Costa, L. N.; DePoy, D. L.; Desai, S.; Diehl, H. T.; Eifler, T.; Evrard, A. E.; Flaugher, B.; Frieman, J. A.; Gerdes, D.; Gruen, D.; Honscheid, K.; James, D.; Kuehn, K.; Kuropatkin, N.; Lahav, O.; Maia, M. A. G.; Makler, M.; Marshall, J. L.; Merritt, K. W.; Miller, C. J.; Miquel, R.; Ogando, R.; Roe, N. A.; Romer, A. K.; Rykoff, E.; Sanchez, E.; Santiago, B. X.; Scarpine, V.; Schubnell, M.; Sevilla, I.; Soares-Santos, M.; Suchyta, E.; Swanson, M.; Tarle, G.; Thaler, J.; Tucker, L. D.; Wechsler, R. H.; Zuntz, J.

    2015-03-23

    We present DES13S2cmm, the first spectroscopically-confirmed superluminous supernova (SLSN) from the Dark Energy Survey (DES). We briefly discuss the data and search algorithm used to find this event in the first year of DES operations, and outline the spectroscopic data obtained from the European Southern Observatory (ESO) Very Large Telescope to confirm its redshift (z = 0.663 ± 0.001 based on the host-galaxy emission lines) and likely spectral type (type I). Using this redshift, we find MpeakU = –21.05+0.10–0.09 for the peak, rest-frame U-band absolute magnitude, and find DES13S2cmm to be located in a faint, low-metallicity (sub-solar), low stellar-mass host galaxy (log(M/M?) = 9.3 ± 0.3), consistent with what is seen for other SLSNe-I. We compare the bolometric light curve of DES13S2cmm to fourteen similarly well-observed SLSNe-I in the literature and find it possesses one of the slowest declining tails (beyond +30 days rest frame past peak), and is the faintest at peak. Moreover, we find the bolometric light curves of all SLSNe-I studied herein possess a dispersion of only 0.2–0.3 magnitudes between +25 and +30 days after peak (rest frame) depending on redshift range studied; this could be important for ‘standardising’ such supernovae, as is done with the more common type Ia. We fit the bolometric light curve of DES13S2cmm with two competing models for SLSNe-I – the radioactive decay of ??Ni, and a magnetar – and find that while the magnetar is formally a better fit, neither model provides a compelling match to the data. Although we are unable to conclusively differentiate between these two physical models for this particular SLSN-I, further DES observations of more SLSNe-I should break this degeneracy, especially if the light curves of SLSNe-I can be observed beyond 100 days in the rest frame of the supernova.

  16. DES13S2cmm: The first superluminous supernova from the Dark Energy Survey

    SciTech Connect (OSTI)

    Papadopoulos, A.; Plazas, A. A.; D"Andrea, C. B.; Sullivan, M.; Nichol, R. C.; Barbary, K.; Biswas, R.; Brown, P. J.; Covarrubias, R. A.; Finley, D. A.; Fischer, J. A.; Foley, R. J.; Goldstein, D.; Gupta, R. R.; Kessler, R.; Kovacs, E.; Kuhlmann, S. E.; Lidman, C.; March, M.; Nugent, P. E.; Sako, M.; Smith, R. C.; Spinka, H.; Wester, W.; Abbott, T. M. C.; Abdalla, F.; Allam, S. S.; Banerji, M.; Bernstein, J. P.; Bernstein, R. A.; Carnero, A.; da Costa, L. N.; DePoy, D. L.; Desai, S.; Diehl, H. T.; Eifler, T.; Evrard, A. E.; Flaugher, B.; Frieman, J. A.; Gerdes, D.; Gruen, D.; Honscheid, K.; James, D.; Kuehn, K.; Kuropatkin, N.; Lahav, O.; Maia, M. A. G.; Makler, M.; Marshall, J. L.; Merritt, K. W.; Miller, C. J.; Miquel, R.; Ogando, R.; Roe, N. A.; Romer, A. K.; Rykoff, E.; Sanchez, E.; Santiago, B. X.; Scarpine, V.; Schubnell, M.; Sevilla, I.; Soares-Santos, M.; Suchyta, E.; Swanson, M.; Tarle, G.; Thaler, J.; Tucker, L. D.; Wechsler, R. H.; Zuntz, J.

    2015-03-23

    We present DES13S2cmm, the first spectroscopically-confirmed superluminous supernova (SLSN) from the Dark Energy Survey (DES). We briefly discuss the data and search algorithm used to find this event in the first year of DES operations, and outline the spectroscopic data obtained from the European Southern Observatory (ESO) Very Large Telescope to confirm its redshift (z = 0.663 ± 0.001 based on the host-galaxy emission lines) and likely spectral type (type I). Using this redshift, we find MpeakU = –21.05+0.10–0.09 for the peak, rest-frame U-band absolute magnitude, and find DES13S2cmm to be located in a faint, low-metallicity (sub-solar), low stellar-mass host galaxy (log(M/M⊙) = 9.3 ± 0.3), consistent with what is seen for other SLSNe-I. We compare the bolometric light curve of DES13S2cmm to fourteen similarly well-observed SLSNe-I in the literature and find it possesses one of the slowest declining tails (beyond +30 days rest frame past peak), and is the faintest at peak. Moreover, we find the bolometric light curves of all SLSNe-I studied herein possess a dispersion of only 0.2–0.3 magnitudes between +25 and +30 days after peak (rest frame) depending on redshift range studied; this could be important for ‘standardising’ such supernovae, as is done with the more common type Ia. We fit the bolometric light curve of DES13S2cmm with two competing models for SLSNe-I – the radioactive decay of ⁵⁶Ni, and a magnetar – and find that while the magnetar is formally a better fit, neither model provides a compelling match to the data. Although we are unable to conclusively differentiate between these two physical models for this particular SLSN-I, further DES observations of more SLSNe-I should break this degeneracy, especially if the light curves of SLSNe-I can be observed beyond 100 days in the rest frame of the supernova.

  17. DES13S2cmm: The first superluminous supernova from the Dark Energy Survey

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Papadopoulos, A.; Plazas, A. A.; D"Andrea, C. B.; Sullivan, M.; Nichol, R. C.; Barbary, K.; Biswas, R.; Brown, P. J.; Covarrubias, R. A.; Finley, D. A.; et al

    2015-03-23

    We present DES13S2cmm, the first spectroscopically-confirmed superluminous supernova (SLSN) from the Dark Energy Survey (DES). We briefly discuss the data and search algorithm used to find this event in the first year of DES operations, and outline the spectroscopic data obtained from the European Southern Observatory (ESO) Very Large Telescope to confirm its redshift (z = 0.663 ± 0.001 based on the host-galaxy emission lines) and likely spectral type (type I). Using this redshift, we find MpeakU = –21.05+0.10–0.09 for the peak, rest-frame U-band absolute magnitude, and find DES13S2cmm to be located in a faint, low-metallicity (sub-solar), low stellar-mass hostmore » galaxy (log(M/M⊙) = 9.3 ± 0.3), consistent with what is seen for other SLSNe-I. We compare the bolometric light curve of DES13S2cmm to fourteen similarly well-observed SLSNe-I in the literature and find it possesses one of the slowest declining tails (beyond +30 days rest frame past peak), and is the faintest at peak. Moreover, we find the bolometric light curves of all SLSNe-I studied herein possess a dispersion of only 0.2–0.3 magnitudes between +25 and +30 days after peak (rest frame) depending on redshift range studied; this could be important for ‘standardising’ such supernovae, as is done with the more common type Ia. We fit the bolometric light curve of DES13S2cmm with two competing models for SLSNe-I – the radioactive decay of ⁵⁶Ni, and a magnetar – and find that while the magnetar is formally a better fit, neither model provides a compelling match to the data. Although we are unable to conclusively differentiate between these two physical models for this particular SLSN-I, further DES observations of more SLSNe-I should break this degeneracy, especially if the light curves of SLSNe-I can be observed beyond 100 days in the rest frame of the supernova.« less

  18. Redshift Distributions of Galaxies in the DES Science Verification Shear Catalogue and Implications for Weak Lensing

    SciTech Connect (OSTI)

    Bonnett, C.

    2015-07-21

    We present photometric redshift estimates for galaxies used in the weak lensing analysis of the Dark Energy Survey Science Verification (DES SV) data. Four model- or machine learning-based photometric redshift methods { annz2, bpz calibrated against BCC-U fig simulations, skynet, and tpz { are analysed. For training, calibration, and testing of these methods, we also construct a catalogue of spectroscopically confirmed galaxies matched against DES SV data. The performance of the methods is evalu-ated against the matched spectroscopic catalogue, focusing on metrics relevant for weak lensing analyses, with additional validation against COSMOS photo-zs. From the galaxies in the DES SV shear catalogue, which have mean redshift 0.72 ±0.01 over the range 0:3 < z < 1:3, we construct three tomographic bins with means of z = {0.45; 0.67,1.00g}. These bins each have systematic uncertainties ?z ? 0.05 in the mean of the fiducial skynet photo-z n(z). We propagate the errors in the redshift distributions through to their impact on cosmological parameters estimated with cosmic shear, and find that they cause shifts in the value of ?8 of approx. 3%. This shift is within the one sigma statistical errors on ?8 for the DES SV shear catalog. We also found that further study of the potential impact of systematic differences on the critical surface density, ?crit, contained levels of bias safely less than the statistical power of DES SV data. We recommend a final Gaussian prior for the photo-z bias in the mean of n(z) of width 0:05 for each of the three tomographic bins, and show that this is a sufficient bias model for the corresponding cosmology analysis.

  19. Cross-correlation of gravitational lensing from DES Science Verification data with SPT and Planck lensing

    SciTech Connect (OSTI)

    Kirk, D.; et al.

    2015-12-14

    We measure the cross-correlation between weak lensing of galaxy images and of the cosmic microwave background (CMB). The effects of gravitational lensing on different sources will be correlated if the lensing is caused by the same mass fluctuations. We use galaxy shape measurements from 139 deg$^{2}$ of the Dark Energy Survey (DES) Science Verification data and overlapping CMB lensing from the South Pole Telescope (SPT) and Planck. The DES source galaxies have a median redshift of $z_{\\rm med} {\\sim} 0.7$, while the CMB lensing kernel is broad and peaks at $z{\\sim}2$. The resulting cross-correlation is maximally sensitive to mass fluctuations at $z{\\sim}0.44$. Assuming the Planck 2015 best-fit cosmology, the amplitude of the DES$\\times$SPT cross-power is found to be $A = 0.88 \\pm 0.30$ and that from DES$\\times$Planck to be $A = 0.86 \\pm 0.39$, where $A=1$ corresponds to the theoretical prediction. These are consistent with the expected signal and correspond to significances of $2.9 \\sigma$ and $2.2 \\sigma$ respectively. We demonstrate that our results are robust to a number of important systematic effects including the shear measurement method, estimator choice, photometric redshift uncertainty and CMB lensing systematics. Significant intrinsic alignment of galaxy shapes would increase the cross-correlation signal inferred from the data; we calculate a value of $A = 1.08 \\pm 0.36$ for DES$\\times$SPT when we correct the observations with a simple IA model. With three measurements of this cross-correlation now existing in the literature, there is not yet reliable evidence for any deviation from the expected LCDM level of cross-correlation, given the size of the statistical uncertainties and the significant impact of systematic errors, particularly IAs. We provide forecasts for the expected signal-to-noise of the combination of the five-year DES survey and SPT-3G.

  20. Mapping and Simulating Systematics Due to Spatially-Varying Observing Conditions in DES Science Verification Data

    SciTech Connect (OSTI)

    Leistedt, B.

    2015-07-20

    Spatially-varying depth and characteristics of observing conditions, such as seeing, airmass, or sky background, are major sources of systematic uncertainties in modern galaxy survey analyses, in particular in deep multi-epoch surveys. We present a framework to extract and project these sources of systematics onto the sky, and apply it to the Dark Energy Survey (DES) to map the observing conditions of the Science Verification (SV) data. The resulting distributions and maps of sources of systematics are used in several analyses of DES SV to perform detailed null tests with the data, and also to incorporate systematics in survey simulations. We illustrate the complementarity of these two approaches by comparing the SV data with the BCC-UFig, a synthetic sky catalogue generated by forward-modelling of the DES SV images. We then analyse the BCC-UFig simulation to construct galaxy samples mimicking those used in SV galaxy clustering studies. We show that the spatially-varying survey depth imprinted in the observed galaxy densities and the redshift distributions of the SV data are successfully reproduced by the simulation and well-captured by the maps of observing conditions. The combined use of the maps, the SV data and the BCC-UFig simulation allows us to quantify the impact of spatial systematics on N(z), the redshift distributions inferred using photometric redshifts. We conclude that spatial systematics in the SV data are mainly due to seeing fluctuations and are under control in current clustering and weak lensing analyses. However, they will need to be carefully characterised in upcoming phases of DES in order to avoid biasing the inferred cosmological results. The framework presented is relevant to all multi-epoch surveys, and will be essential for exploiting future surveys such as the Large Synoptic Survey Telescope, which will require detailed null-tests and realistic end-to-end image simulations to correctly interpret the deep, high-cadence observations of the sky.

  1. Joint Analysis of Galaxy-Galaxy Lensing and Galaxy Clustering: Methodology and Forecasts for DES

    SciTech Connect (OSTI)

    Park, Y.

    2015-07-19

    The joint analysis of galaxy-galaxy lensing and galaxy clustering is a promising method for inferring the growth function of large scale structure. Our analysis will be carried out on data from the Dark Energy Survey (DES), with its measurements of both the distribution of galaxies and the tangential shears of background galaxies induced by these foreground lenses. We develop a practical approach to modeling the assumptions and systematic effects affecting small scale lensing, which provides halo masses, and large scale galaxy clustering. Introducing parameters that characterize the halo occupation distribution (HOD), photometric redshift uncertainties, and shear measurement errors, we study how external priors on different subsets of these parameters affect our growth constraints. Degeneracies within the HOD model, as well as between the HOD and the growth function, are identified as the dominant source of complication, with other systematic effects sub-dominant. The impact of HOD parameters and their degeneracies necessitate the detailed joint modeling of the galaxy sample that we employ. Finally, we conclude that DES data will provide powerful constraints on the evolution of structure growth in the universe, conservatively/optimistically constraining the growth function to 7.9%/4.8% with its first-year data that covered over 1000 square degrees, and to 3.9%/2.3% with its full five-year data that will survey 5000 square degrees, including both statistical and systematic uncertainties.

  2. OzDES multifibre spectroscopy for the Dark Energy Survey: First-year operation and results

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yuan, Fang; Plazas, A. A.; Lidman, C.; Davis, T. M.; Childress, M.; Abdalla, F. B.

    2015-07-29

    OzDES is a five-year, 100-night, spectroscopic survey on the Anglo-Australian Telescope, whose primary aim is to measure redshifts of approximately 2,500 Type Ia supernovae host galaxies over the redshift range 0.1 more »help calibrate photometric redshifts. Here we present an overview of the OzDES program and our first-year results. Between Dec 2012 and Dec 2013, we observed over 10,000 objects and measured more than 6,000 redshifts. Our strategy of retargeting faint objects across many observing runs has allowed us to measure redshifts for galaxies as faint as mr = 25 mag. We outline our target selection and observing strategy, quantify the redshift success rate for different types of targets, and discuss the implications for our main science goals. Finally, we highlight a few interesting objects as examples of the fortuitous yet not totally unexpected discoveries that can come from such a large spectroscopic survey.« less

  3. OzDES multifibre spectroscopy for the Dark Energy Survey: First-year operation and results

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yuan, Fang

    2015-07-29

    The Australian Dark Energy Survey (OzDES) is a five-year, 100-night, spectroscopic survey on the Anglo-Australian Telescope, whose primary aim is to measure redshifts of approximately 2500 Type Ia supernovae host galaxies over the redshift range 0.1 < z < 1.2, and derive reverberation-mapped black hole masses for approximately 500 active galactic nuclei and quasars over 0.3 < z < 4.5. This treasure trove of data forms a major part of the spectroscopic follow-up for the Dark Energy Survey for which we are also targeting cluster galaxies, radio galaxies, strong lenses, and unidentified transients, as well as measuring luminous red galaxiesmore » and emission line galaxies to help calibrate photometric redshifts. Here, we present an overview of the OzDES programme and our first-year results. Between 2012 December and 2013 December, we observed over 10 000 objects and measured more than 6 000 redshifts. Our strategy of retargeting faint objects across many observing runs has allowed us to measure redshifts for galaxies as faint as mr = 25 mag. We outline our target selection and observing strategy, quantify the redshift success rate for different types of targets, and discuss the implications for our main science goals. In conclusion, we highlight a few interesting objects as examples of the fortuitous yet not totally unexpected discoveries that can come from such a large spectroscopic survey.« less

  4. OzDES multifibre spectroscopy for the Dark Energy Survey: First-year operation and results

    SciTech Connect (OSTI)

    Yuan, Fang

    2015-07-29

    The Australian Dark Energy Survey (OzDES) is a five-year, 100-night, spectroscopic survey on the Anglo-Australian Telescope, whose primary aim is to measure redshifts of approximately 2500 Type Ia supernovae host galaxies over the redshift range 0.1 < z < 1.2, and derive reverberation-mapped black hole masses for approximately 500 active galactic nuclei and quasars over 0.3 < z < 4.5. This treasure trove of data forms a major part of the spectroscopic follow-up for the Dark Energy Survey for which we are also targeting cluster galaxies, radio galaxies, strong lenses, and unidentified transients, as well as measuring luminous red galaxies and emission line galaxies to help calibrate photometric redshifts. Here, we present an overview of the OzDES programme and our first-year results. Between 2012 December and 2013 December, we observed over 10 000 objects and measured more than 6 000 redshifts. Our strategy of retargeting faint objects across many observing runs has allowed us to measure redshifts for galaxies as faint as mr = 25 mag. We outline our target selection and observing strategy, quantify the redshift success rate for different types of targets, and discuss the implications for our main science goals. In conclusion, we highlight a few interesting objects as examples of the fortuitous yet not totally unexpected discoveries that can come from such a large spectroscopic survey.

  5. DES14X3taz: A type I superluminous supernova showing a luminous, rapidly cooling initial pre-peak bump

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Smith, M.

    2016-02-03

    Here, we present DES14X3taz, a new hydrogen-poor superluminous supernova (SLSN-I) discovered by the Dark Energy Survey (DES) supernova program, with additional photometric data provided by the Survey Using DECam for Superluminous Supernovae. Spectra obtained using Optical System for Imaging and low-Intermediate-Resolution Integrated Spectroscopy on the Gran Telescopio CANARIAS show DES14X3taz is an SLSN-I at z = 0.608. Multi-color photometry reveals a double-peaked light curve: a blue and relatively bright initial peak that fades rapidly prior to the slower rise of the main light curve. Our multi-color photometry allows us, for the first time, to show that the initial peak cools from 22,000more » to 8000 K over 15 rest-frame days, and is faster and brighter than any published core-collapse supernova, reaching 30% of the bolometric luminosity of the main peak. No physical (56)Ni-powered model can fit this initial peak. We show that a shock-cooling model followed by a magnetar driving the second phase of the light curve can adequately explain the entire light curve of DES14X3taz. Models involving the shock-cooling of extended circumstellar material at a distance of ≃400 R⊙ are preferred over the cooling of shock-heated surface layers of a stellar envelope. We compare DES14X3taz to the few double-peaked SLSN-I events in the literature. Although the rise times and characteristics of these initial peaks differ, there exists the tantalizing possibility that they can be explained by one physical interpretation.« less

  6. Wide-Field Lensing Mass Maps from DES Science Verification Data

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chang, C.; Vikram, V.; Jain, B.

    2015-07-29

    We present a mass map reconstructed from weak gravitational lensing shear measurements over 139 deg2 from the Dark Energy Survey (DES) Science Verification data. The mass map probes both luminous and dark matter, thus providing a tool for studying cosmology. We find good agreement between the mass map and the distribution of massive galaxy clusters identified using a red-sequence cluster finder. Potential candidates for super-clusters and voids are identified using these maps. We measure the cross-correlation between the mass map and a magnitude-limited foreground galaxy sample and find a detection at the 6.8? level with 20 arcminute smoothing. These measurementsmore »are consistent with simulated galaxy catalogs based on ?CDM Nbody simulations, suggesting low systematics uncertainties in the map. We summarize our key findings in this letter; the detailed methodology and tests for systematics are presented in a companion paper.« less

  7. DES J0454–4448: Discovery of the first luminous z ≥ 6 quasar from the Dark Energy Survey

    SciTech Connect (OSTI)

    Reed, S. L.

    2015-10-28

    We present the first results of a survey for high-redshift, z ≥ 6, quasars using izY multicolour photometric observations from the Dark Energy Survey (DES). Here we report the discovery and spectroscopic confirmation of the zAB, YAB = 20.2, 20.2 (M1450 = –26.5) quasar DES J0454–4448 with a redshift of z = 6.09±0.02 based on the onset of the Ly α forest and an H i near zone size of 4.1+1.1–1.2 proper Mpc. The quasar was selected as an i-band drop out with i–z = 2.46 and zAB < 21.5 from an area of ~300 deg2. It is the brightest of our 43 candidates and was identified for spectroscopic follow-up solely based on the DES i–z and z–Y colours. The quasar is detected by WISE and has W1AB = 19.68. The discovery of one spectroscopically confirmed quasar with 5.7 < z < 6.5 and zAB ≤ 20.2 is consistent with recent determinations of the luminosity function at z ~ 6. DES when completed will have imaged ~5000 deg2 to YAB = 23.0 (5σ point source) and we expect to discover 50–100 new quasars with z > 6 including 3–10 with z > 7 dramatically increasing the numbers of quasars currently known that are suitable for detailed studies.

  8. DES J0454–4448: Discovery of the first luminous z ≥ 6 quasar from the Dark Energy Survey

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Reed, S. L.

    2015-10-28

    We present the first results of a survey for high-redshift, z ≥ 6, quasars using izY multicolour photometric observations from the Dark Energy Survey (DES). Here we report the discovery and spectroscopic confirmation of the zAB, YAB = 20.2, 20.2 (M1450 = –26.5) quasar DES J0454–4448 with a redshift of z = 6.09±0.02 based on the onset of the Ly α forest and an H i near zone size of 4.1+1.1–1.2 proper Mpc. The quasar was selected as an i-band drop out with i–z = 2.46 and zAB < 21.5 from an area of ~300 deg2. It is the brightestmore » of our 43 candidates and was identified for spectroscopic follow-up solely based on the DES i–z and z–Y colours. The quasar is detected by WISE and has W1AB = 19.68. The discovery of one spectroscopically confirmed quasar with 5.7 < z < 6.5 and zAB ≤ 20.2 is consistent with recent determinations of the luminosity function at z ~ 6. DES when completed will have imaged ~5000 deg2 to YAB = 23.0 (5σ point source) and we expect to discover 50–100 new quasars with z > 6 including 3–10 with z > 7 dramatically increasing the numbers of quasars currently known that are suitable for detailed studies.« less

  9. redMaGiC. Selecting Luminous Red Galaxies from the DES Science Verification Data

    SciTech Connect (OSTI)

    Rozo, E.

    2015-07-20

    We introduce redMaGiC, an automated algorithm for selecting Luminous Red Galaxies (LRGs). The algorithm was developed to minimize photometric redshift uncertainties in photometric large-scale structure studies. redMaGiC achieves this by self-training the color-cuts necessary to produce a luminosity-thresholded LRG sam- ple of constant comoving density. Additionally, we demonstrate that redMaGiC photo-zs are very nearly as accurate as the best machine-learning based methods, yet they require minimal spectroscopic training, do not suffer from extrapolation biases, and are very nearly Gaussian. We apply our algorithm to Dark Energy Survey (DES) Science Verification (SV) data to produce a redMaGiC catalog sampling the redshift range z ? [0.2,0.8]. Our fiducial sample has a comoving space density of 10-3 (h-1Mpc)-3, and a median photo-z bias (zspec zphoto) and scatter (?z=(1 + z)) of 0.005 and 0.017 respectively.The corresponding 5? outlier fraction is 1.4%. We also test our algorithm with Sloan Digital Sky Survey (SDSS) Data Release 8 (DR8) and Stripe 82 data, and discuss how spectroscopic training can be used to control photo-z biases at the 0.1% level.

  10. Galaxy Clustering, Photometric Redshifts and Diagnosis of Systematics in the DES Science Verification Data

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Crocce, M.

    2015-12-09

    We study the clustering of galaxies detected at i < 22.5 in the Science Verification observations of the Dark Energy Survey (DES). Two-point correlation functions are measured using 2.3 × 106 galaxies over a contiguous 116 deg2 region in five bins of photometric redshift width Δz = 0.2 in the range 0.2 < z < 1.2. The impact of photometric redshift errors is assessed by comparing results using a template-based photo-zalgorithm (BPZ) to a machine-learning algorithm (TPZ). A companion paper presents maps of several observational variables (e.g. seeing, sky brightness) which could modulate the galaxy density. Here we characterize andmore » mitigate systematic errors on the measured clustering which arise from these observational variables, in addition to others such as Galactic dust and stellar contamination. After correcting for systematic effects, we then measure galaxy bias over a broad range of linear scales relative to mass clustering predicted from the Planck Λ cold dark matter model, finding agreement with the Canada-France-Hawaii Telescope Legacy Survey (CFHTLS) measurements with χ2 of 4.0 (8.7) with 5 degrees of freedom for the TPZ (BPZ) redshifts. Furthermore, we test a ‘linear bias’ model, in which the galaxy clustering is a fixed multiple of the predicted non-linear dark matter clustering. The precision of the data allows us to determine that the linear bias model describes the observed galaxy clustering to 2.5 percent accuracy down to scales at least 4–10 times smaller than those on which linear theory is expected to be sufficient.« less

  11. Galaxy Clustering, Photometric Redshifts and Diagnosis of Systematics in the DES Science Verification Data

    SciTech Connect (OSTI)

    Crocce, M.

    2015-12-09

    We study the clustering of galaxies detected at i < 22.5 in the Science Verification observations of the Dark Energy Survey (DES). Two-point correlation functions are measured using 2.3 × 106 galaxies over a contiguous 116 deg2 region in five bins of photometric redshift width ?z = 0.2 in the range 0.2 < z < 1.2. The impact of photometric redshift errors is assessed by comparing results using a template-based photo-zalgorithm (BPZ) to a machine-learning algorithm (TPZ). A companion paper presents maps of several observational variables (e.g. seeing, sky brightness) which could modulate the galaxy density. Here we characterize and mitigate systematic errors on the measured clustering which arise from these observational variables, in addition to others such as Galactic dust and stellar contamination. After correcting for systematic effects, we then measure galaxy bias over a broad range of linear scales relative to mass clustering predicted from the Planck ? cold dark matter model, finding agreement with the Canada-France-Hawaii Telescope Legacy Survey (CFHTLS) measurements with ?2 of 4.0 (8.7) with 5 degrees of freedom for the TPZ (BPZ) redshifts. Furthermore, we test a ‘linear bias’ model, in which the galaxy clustering is a fixed multiple of the predicted non-linear dark matter clustering. The precision of the data allows us to determine that the linear bias model describes the observed galaxy clustering to 2.5 percent accuracy down to scales at least 4–10 times smaller than those on which linear theory is expected to be sufficient.

  12. Low Cost SiOx-Graphite and Olivine Materials

    Broader source: Energy.gov [DOE]

    2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C.

  13. Early Pennsylvanian wrenching along the Red River-Matador Arch: Formation of a pull-apart basin, Depocenter for Atokan to Lower Des Moines (bend) clastics, Cottle County, Texas

    SciTech Connect (OSTI)

    Stephens, W.C. Jr.; Gunn, R.D.

    1995-06-01

    Early Pennsylvanian wrenching along the Red River-Matador Arch (Tectonic Zone) created a braided series of en echelon faults and folds with associated pop-up structures and pull-apart basins. Local extension, or overstepping, in Southeast Cottle County, Texas, has produced the deepest pull-apart basin along the arch with over 10,000` of structural relief. The emerging Wichita-Amarillo Uplift, to the north, provided an abundant sediment source, which prograded rapidly southward as an alluvial fan-braided river complex. Exposure of basement rocks and lower Paleozoic sediments along the Red River-Matador Arch, also contributed to the basin fill. Syntectonic sedimentation led to the accumulation of over 6000` of Bend (Atoka-lower Des Moines) sediments within the basin. Deposition was dominated initially by alluvial fan to fluvial siliciclastics. As basin subsidence was further amplified by sediment loading, accommodation exceeded sedimentation capturing a large segment of the southward prograding Wichita-Amarillo derived clastic wedge. Encroachment of the late Atoka to lower Des Moines epeiric sea promoted further evolution of depositional environments to fan deltas, marine dominated clastics and, later, localized carbonate development. Type III kerogen rich organic shales produced abundant gas prone source rocks. The extreme depth of the basin combined with the local geothermal gradient provided for significant hydrocarbon generation. By early 1988 new well control helped revise previous stratigraphic correlation demonstrating a rapidly expanding lower Des Moines to Atokan section. The drilling of the Gunn Oil Company-Brothers No. 1 to a total depth of 10,301` in the Mississippian Chappel Limestone, encountered 2025` of Bend sediments, with 279` of gross Bend Conglomerate (162` of net pay). The Brothers No. 1 was potentialled on 11/19/89 with a CAOF of 6.0 MMCFD and filed as the field discovery for the Broken Bone (Bend Conglomerate) field.

  14. Comparison of effectiveness of sub-slab ventilation systems for indoor radon mitigation: A numerical study; Comparaison a l`aide d`un outil numerique de l`efficacite des systemes de ventilation active du sol limitant la penetration du radon dans l`habitat

    SciTech Connect (OSTI)

    Bonnefous, Y.C. |; Gadgil, A.J.; Allard, F.

    1992-04-01

    The functioning of an active sub-slab ventilation system (SVS) has been studied successfully with the help of a previously evaluated numerical model. The parameters explored are the permeability of the sub-slab and the gravel placed beneath it, the amplitude of applied pressure at the installation point of the system and the functioning method: depressurization or pressurization. The mechanisms contributing to the success of the two systems are identified. This numerical study shows that the presence of a layer of gravel beneath the sub-slab considerably improves the performance of the SVS. Considered separately from the extremely permeable sub-slabs, the depressurization systems perform better than the pressurization systems. 17 refs. [Francais] Le fonctionnement des Systemes de Ventilation active du Sol (SVS) a ete etudie a l`aide d`un outil numerique precedemment evalue avec succes. Les parametres explores sont les permeabilites du sol et du gravier place sous plancher bas, l`amplitude de la pression appliquee au point d`installation du systeme, et le mode de fonctionnement: Depressurisation ou Pressurisation. Les mecanismes contribuant au succes des deux systemes sont identifies. Cette etude numerique montre que la presence d`une couche de gravier sous plancher bas ameliore de facon considerable les performances des SVS. Mis a part le cas des sols extremement permeables, les systemes de Depressurisation ont de meilleures performances que les systemes de Pressurisation. 17 refs.

  15. Some Lessons Learned from 20 Years in RedOx Flow Battery R&d

    Broader source: Energy.gov [DOE]

    Presentation by Steve Clarke, Applied Intellectual Capital, at the Flow Cells for Energy Storage Workshop held March 7-8, 2012, in Washington, DC.

  16. Interfacial engineering of solution-processed Ni nanochain-SiOx...

    Office of Scientific and Technical Information (OSTI)

    thermodynamically stable, anti-oxidation solar selective absorbers Citation Details ... thermodynamically stable, anti-oxidation solar selective absorbers Authors: Yu, Xiaobai ...

  17. Low Cost SiOx-Graphite and Olivine Materials | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Inc. | Department of Energy A series of brief fact sheet on various topics including:Low Cost High Concentration PV Systems for Utility Power Generation,High Efficiency Concentrating Photovoltaic Power System,Reaching Grid Parity Using BP Solar Crystalline Silicon Technology, Fully Integrated Building Science Solutions for Residential and Commercial Photovoltaic Energy Generation,A Value Chain Partnership to Accelerate U.S. Photovoltaic Industry Growth,AC Module PV System,Flexible Organic

  18. Large voltage-induced modification of spin-orbit torques in Pt/Co/GdOx

    SciTech Connect (OSTI)

    Emori, Satoru Bauer, Uwe; Woo, Seonghoon; Beach, Geoffrey S. D.

    2014-12-01

    We report on large modifications of current-induced spin-orbit torques in a gated Pt/Co/Gd-oxide microstrip due to voltage-driven O{sup 2−} migration. The Slonczewski-like and field-like torques are quantified using a low-frequency harmonic technique based on the polar magneto-optical Kerr effect. Voltage-induced oxidation of Co enhances the Slonczewski-like torque by as much as an order of magnitude and simultaneously reduces the anisotropy energy barrier by a factor of ∼5. Such magneto-ionic tuning of interfacial spin-orbit effects may significantly enhance the efficiency of magnetization switching and provide additional degrees of freedom in spintronic devices.

  19. Low Cost SiOx-Graphite and High Voltage Spinel Cathode

    Broader source: Energy.gov [DOE]

    2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation

  20. EPJ

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Y.G. Ma 1 Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800, China Received: date Revised version: date Abstract. Moment analysis method and ...

  1. Hydrogen Solar Ltd | Open Energy Information

    Open Energy Info (EERE)

    Solar Ltd Jump to: navigation, search Name: Hydrogen Solar Ltd Place: Guildford, United Kingdom Zip: GU2 7YG Sector: Hydro, Hydrogen, Solar Product: Hydrogen Solar Ltd is...

  2. Centrales au gaz et Energies renouvelables: comparer des pommes avec des pommes

    SciTech Connect (OSTI)

    Bolinger, Mark; Wiser, Ryan; Golove, William

    2003-10-20

    The fundamental conclusion that we draw from this analysis is that one should not to base itself blindly on forecasts prices of natural gas when one compare contracts at price fixes with producers of renewable energy with contracts at variable prices with promoters power stations with gas. Indeed, forecasts of the prices of gas do not succeed not to enter the associated costs with the covering of the risk, that they are connected to the negative pressure against the cover, with the CAPM, with costs of transaction or with unspecified combination of three. Thus, insofar as price stability to length term is developed, better way of comparing the two choices would be to have recourse to the data on the prices in the long term natural gas, and not with forecasts of the prices. During three last years at least, the use of these prices in the long term would have besides license to correct a methodological error who, obviously, seem to have supported unduly, and of relatively important way, power stations with natural gas compared to their competitors of renewable energies.

  3. The influence of nano-architectured CeOx supports in RhPd/CeO₂ for the catalytic ethanol steam reforming reaction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Divins, N. J.; Senanayake, S. D.; Casanovas, A.; Xu, W.; Trovarelli, A.; Llorca, J.

    2015-01-19

    The ethanol steam reforming (ESR) reaction has been tested over RhPd supported on polycrystalline ceria in comparison to structured supports composed of nanoshaped CeO₂ cubes and CeO₂ rods tailored towards the production of hydrogen. At 650-700 K the hydrogen yield follows the trend RhPd/CeO₂-cubes > RhPd/CeO₂ -rods > RhPd/CeO₂- polycrystalline, whereas at temperatures higher than 800 K the catalytic performance of all samples is similar and close to the thermodynamic equilibrium. The improved performance of RhPd/CeO₂-cubes and RhPd/CeO₂ -rods for ESR at low temperature is mainly ascribed to higher water-gas shift activity and a strong interaction between the bimetallic -more » oxide support interaction. STEM analysis shows the existence of RhPd alloyed nanoparticles in all samples, with no apparent relationship between ESR performance and RhPd particle size. X-ray diffraction under operating conditions shows metal reorganization on {100} and {110} ceria crystallographic planes during catalyst activation and ESR, but not on {111} ceria crystallographic planes. The RhPd reconstructing and tuned activation over ceria nanocubes and nanorods is considered the main reason for better catalytic activity with respect to conventional catalysts based on polycrystalline ceria« less

  4. Mechanistic insights of ethanol steam reforming over Ni-CeOx(111): The importance of hydroxyl groups for suppressing coke formation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, Zongyuan; Senanayake, Sanjaya D.; Duchon, Tomas; Wang, Huanru; Peterson, Erik W.; Zhou, Yinghui; Luo, Si; Zhou, Jing; Matolin, Vladimir; Stacchiola, Dario J.; et al

    2015-07-10

    We have studied the reaction of ethanol and water over Ni–CeO2-x(111) model surfaces to elucidate the mechanistic steps associated with the ethanol steam reforming (ESR) reaction. Our results provide insights about the importance of hydroxyl groups to the ESR reaction over Ni-based catalysts. Systematically, we have investigated the reaction of ethanol on Ni–CeO2-x(111) at varying Ce³? concentrations (CeO1.8–2.0) with absence/presence of water using a combination of soft X-ray photoelectron spectroscopy (sXPS) and temperature-programmed desorption (TPD). Consistent with previous reports, upon annealing, metallic Ni formed on reduced ceria while NiO was the main component on fully oxidized ceria. Ni? is themore »active phase leading to both the C–C and C–H cleavage of ethanol but is also responsible for carbon accumulation or coking. We have identified a Ni?C phase that formed prior to the formation of coke. At temperatures above 600K, the lattice oxygen from ceria and the hydroxyl groups from water interact cooperatively in the removal of coke, likely through a strong metal–support interaction between nickel and ceria that facilitates oxygen transfer.« less

  5. The influence of nano-architectured CeOx supports in RhPd/CeO₂ for the catalytic ethanol steam reforming reaction

    SciTech Connect (OSTI)

    Divins, N. J.; Senanayake, S. D.; Casanovas, A.; Xu, W.; Trovarelli, A.; Llorca, J.

    2015-01-19

    The ethanol steam reforming (ESR) reaction has been tested over RhPd supported on polycrystalline ceria in comparison to structured supports composed of nanoshaped CeO₂ cubes and CeO₂ rods tailored towards the production of hydrogen. At 650-700 K the hydrogen yield follows the trend RhPd/CeO₂-cubes > RhPd/CeO₂ -rods > RhPd/CeO₂- polycrystalline, whereas at temperatures higher than 800 K the catalytic performance of all samples is similar and close to the thermodynamic equilibrium. The improved performance of RhPd/CeO₂-cubes and RhPd/CeO₂ -rods for ESR at low temperature is mainly ascribed to higher water-gas shift activity and a strong interaction between the bimetallic - oxide support interaction. STEM analysis shows the existence of RhPd alloyed nanoparticles in all samples, with no apparent relationship between ESR performance and RhPd particle size. X-ray diffraction under operating conditions shows metal reorganization on {100} and {110} ceria crystallographic planes during catalyst activation and ESR, but not on {111} ceria crystallographic planes. The RhPd reconstructing and tuned activation over ceria nanocubes and nanorods is considered the main reason for better catalytic activity with respect to conventional catalysts based on polycrystalline ceria

  6. Des Plaines Landfill Biomass Facility | Open Energy Information

    Open Energy Info (EERE)

    mW 0.0038 GW Commercial Online Date 2004 Heat Rate (BTUkWh) 12916.67 References EPA Web Site1 Loading map... "minzoom":false,"mappingservice":"googlemaps3","type":"TERRAIN...

  7. Des Moines Area Community College | OSTI, US Dept of Energy,...

    Office of Scientific and Technical Information (OSTI)

    students at Badger Ridge Log on, Learn...and Grow Boone Campus Medical lab Get In The Loop Ankeny Campus Academic Achievement Center DMACC Video Magazine DMACC Operation Green

  8. Forum des Jeuns du Gabon | Open Energy Information

    Open Energy Info (EERE)

    drought and land degradation, Environmentally sound technologies, Gender, Human rights and Sustainable development plans References "UNEP Major Groups Directory"...

  9. Weak lensing by galaxy troughs in DES Science Verification data

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gruen, D.; Friedrich, O.; Amara, A.; Bacon, D.; Bonnett, C.; Hartley, W.; Jain, B.; M. Jarvis; Kavprzak, T.; Krause, E.; et al

    2015-11-29

    In this study, we measure the weak lensing shear around galaxy troughs, i.e. the radial alignment of background galaxies relative to underdensities in projections of the foreground galaxy field over a wide range of redshift in Science Verification data from the Dark Energy Survey. Our detection of the shear signal is highly significant (10σ–15σ for the smallest angular scales) for troughs with the redshift range z ϵ [0.2, 0.5] of the projected galaxy field and angular diameters of 10 arcmin…1°. These measurements probe the connection between the galaxy, matter density, and convergence fields. By assuming galaxies are biased tracers ofmore » the matter density with Poissonian noise, we find agreement of our measurements with predictions in a fiducial Λ cold dark matter model. The prediction for the lensing signal on large trough scales is virtually independent of the details of the underlying model for the connection of galaxies and matter. Our comparison of the shear around troughs with that around cylinders with large galaxy counts is consistent with a symmetry between galaxy and matter over- and underdensities. In addition, we measure the two-point angular correlation of troughs with galaxies which, in contrast to the lensing signal, is sensitive to galaxy bias on all scales. The lensing signal of troughs and their clustering with galaxies is therefore a promising probe of the statistical properties of matter underdensities and their connection to the galaxy field.« less

  10. Microsoft Word - FY12 Fee Des.doc

    National Nuclear Security Administration (NNSA)

    NR0000031 copies of the amendment; (b) By acknowledging receipt of this amendment on each copy of the offer submitted; or (c) By separate letter or telegram which includes a reference to the solicitation and amendment numbers. FAILURE OF YOUR ACKNOWLEDGEMENT TO BE RECEIVED AT THE PLACE DESIGNATED FOR THE RECEIPT OF OFFERS PRIOR TO THE HOUR AND DATE SPECIFIED MAY RESULT IN REJECTION OF YOUR OFFER. If by virtue of this amendment you desire to change an offer already submitted, such change may be

  11. Weak Lensing by Galaxy Troughs in DES Science Verification Data

    SciTech Connect (OSTI)

    Gruen, D.

    2015-09-29

    We measure the weak lensing shear around galaxy troughs, i.e. the radial alignment of background galaxies relative to underdensities in projections of the foreground galaxy field over a wide range of redshift in Science Verification data from the Dark Energy Survey. Our detection of the shear signal is highly significant (10?–15? for the smallest angular scales) for troughs with the redshift range z ? [0.2, 0.5] of the projected galaxy field and angular diameters of 10 arcmin…1°. These measurements probe the connection between the galaxy, matter density, and convergence fields. By assuming galaxies are biased tracers of the matter density with Poissonian noise, we find agreement of our measurements with predictions in a fiducial ? cold dark matter model. Furthermore, the prediction for the lensing signal on large trough scales is virtually independent of the details of the underlying model for the connection of galaxies and matter. Our comparison of the shear around troughs with that around cylinders with large galaxy counts is consistent with a symmetry between galaxy and matter over- and underdensities. In addition, we measure the two-point angular correlation of troughs with galaxies which, in contrast to the lensing signal, is sensitive to galaxy bias on all scales. Finally, the lensing signal of troughs and their clustering with galaxies is therefore a promising probe of the statistical properties of matter underdensities and their connection to the galaxy field.

  12. Evidence for near-Surface NiOOH Species in Solution-Processed NiOx Selective Interlayer Materials: Impact on Energetics and the Performance of Polymer Bulk Heterojunction Photovoltaics

    SciTech Connect (OSTI)

    Ratcliff, Erin L.; Meyer, Jens; Steirer, K. Xerxes; Garcia, Andres; Berry, Joseph J.; Ginley, David S.; Olson, Dana C.; Kahn, Antoine; Armstrong, Neal R.

    2011-11-22

    The characterization and implementation of solution-processed, wide bandgap nickel oxide (NiO{sub x}) hole-selective interlayer materials used in bulk-heterojunction (BHJ) organic photovoltaics (OPVs) are discussed. The surface electrical properties and charge selectivity of these thin films are strongly dependent upon the surface chemistry, band edge energies, and midgap state concentrations, as dictated by the ambient conditions and film pretreatments. Surface states were correlated with standards for nickel oxide, hydroxide, and oxyhydroxide components, as determined using monochromatic X-ray photoelectron spectroscopy. Ultraviolet and inverse photoemission spectroscopy measurements show changes in the surface chemistries directly impact the valence band energies. O?-plasma treatment of the as-deposited NiO{sub x} films was found to introduce the dipolar surface species nickel oxyhydroxide (NiOOH), rather than the p-dopant Ni?O?, resulting in an increase of the electrical band gap energy for the near-surface region from 3.1 to 3.6 eV via a vacuum level shift. Electron blocking properties of the as-deposited and O?-plasma treated NiO{sub x} films are compared using both electron-only and BHJ devices. O?-plasma-treated NiO{sub x} interlayers produce electron-only devices with lower leakage current and increased turn on voltages. The differences in behavior of the different pretreated interlayers appears to arise from differences in local density of states that comprise the valence band of the NiO{sub x} interlayers and changes to the band gap energy, which influence their hole-selectivity. The presence of NiOOH states in these NiO{sub x} films and the resultant chemical reactions at the oxide/organic interfaces in OPVs is predicted to play a significant role in controlling OPV device efficiency and lifetime.

  13. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    AlOx Fe, oxidation at the Fe4N AlOx interface creates Fe3O4, leading to negativemore ... heterostructures with well-controlled crystallography and interface structures. ...

  14. Targeted Energy Efficiency Expert Evaluation Report: Neal Smith Federal Building, Des Moines, IA

    SciTech Connect (OSTI)

    Fernandez, Nicholas; Goddard, James K.; Underhill, Ronald M.; Gowri, Krishnan

    2013-03-01

    This report summarizes the energy efficiency measures identified and implemented, and an analysis of the energy savings realized using low-cost/no-cost control system measures identified.

  15. SEP Success Story: A Touch of Green for Des Moines’ Sherman Hill

    Broader source: Energy.gov [DOE]

    When the Green & Main Initiative completes the renovation of a 1930s grocery store, the previously abandoned building will be LEED Platinum certified, with a green roof and 54 original windows retrofitted to achieve high energy efficiency standards. Learn more.

  16. The LMC geometry and outer stellar populations from early DES data

    SciTech Connect (OSTI)

    Balbinot, Eduardo; Plazas, A.; Santiago, B. X.; Girardi, L.; Pieres, A.; da Costa, L. N.; Maia, M. A. G.; Gruendl, R. A.; Walker, A. R.; Yanny, B.; Drlica-Wagner, A.; Benoit-Levy, A.; Abbott, T. M. C.; Allam, S. S.; Annis, J.; Bernstein, J. P.; Bernstein, R. A.; Bertin, E.; Brooks, D.; Buckley-Geer, E.; Rosell, A. Carnero; Cunha, C. E.; Depoy, D. L.; Desai, S.; Diehl, H. T.; Doel, P.; Estrada, J.; Evrard, A. E.; Fausti Neto, A.; Finley, D. A.; Flaugher, B.; Frieman, J. A.; Gruen, D.; Honscheid, K.; James, D.; Kuehn, K.; Kuropatkin, N.; Lahav, O.; March, M.; Marshall, J. L.; Miller, C.; Miquel, R.; Ogando, R.; Peoples, J.; Scarpine, V.; Schubnell, M.; Sevilla-Noarbe, I.; Smith, R. C.; Soares-Santos, M.; Suchyta, E.; Swanson, M. E. C.; Tarle, G.; Tucker, D. L.; Wechsler, R.; Zuntz, J.

    2015-03-20

    The Dark Energy Camera has captured a large set of images as part of Science Verification (SV) for the Dark Energy Survey. The SV footprint covers a large portion of the outer Large Magellanic Cloud (LMC), providing photometry 1.5 magnitudes fainter than the main sequence turn-off of the oldest LMC stellar population. We derive geometrical and structural parameters for various stellar populations in the LMC disc. For the distribution of all LMC stars, we find an inclination of i = –38.14°±0.08° (near side in the North) and a position angle for the line of nodes of ?? = 129.51°±0.17°. We find that stars younger than ~4 Gyr are more centrally concentrated than older stars. Fitting a projected exponential disc shows that the scale radius of the old populations is R>4Gyr = 1.41 ± 0.01 kpc, while the younger population has R<4Gyr = 0.72 ± 0.01 kpc. However, the spatial distribution of the younger population deviates significantly from the projected exponential disc model. The distribution of old stars suggests a large truncation radius of Rt = 13.5 ± 0.8 kpc. If this truncation is dominated by the tidal field of the Galaxy, we find that the LMC is ?24+9–6 times less massive than the encircled Galactic mass. By measuring the Red Clump peak magnitude and comparing with the best-fit LMC disc model, we find that the LMC disc is warped and thicker in the outer regions north of the LMC centre. As a result, our findings may either be interpreted as a warped and flared disc in the LMC outskirts, or as evidence of a spheroidal halo component.

  17. QER SECOND INSTALLMENT REGIONAL MEETING--DES MOINES, IOWA | Department of

    Office of Environmental Management (EM)

    BOSTON, MA QER SECOND INSTALLMENT REGIONAL MEETING--BOSTON, MA MEETING DATE AND LOCATION Friday, April 15, 2016 Doors open: 8:30 AM; Program begins: 9:30 AM Marriott Long Wharf (Salons D, E, F, L) 296 State Street Boston, MA 02109 Watch the April 15th Boston regional meeting here. MEETING INFORMATION The U.S. Department of Energy Secretary Ernest Moniz and Dr. John P. Holdren, Director of the White House Office of Science will host a public stakeholder meeting on the second installment of the

  18. A Radiometric All-Sky Infrared Camera (RASICAM) for DES/CTIO

    SciTech Connect (OSTI)

    Lewis, Peter M.; Rogers, Howard; Schindler, Rafe H.; /SLAC

    2010-08-25

    A novel radiometric all-sky infrared camera [RASICAM] has been constructed to allow automated real-time quantitative assessment of night sky conditions for the Dark Energy Camera [DECam] located on the Blanco Telescope at the Cerro Tololo Inter-American Observatory in Chile. The camera is optimized to detect the position, motion and optical depth of thin, high (8-10km) cirrus clouds and contrails by measuring their apparent temperature above the night sky background. The camera system utilizes a novel wide-field equiresolution catadioptic mirror system that provides sky coverage of 2{pi} azimuth and 14-90{sup o} from zenith. Several new technological and design innovations allow the RASICAM system to provide unprecedented cloud detection and IR-based photometricity quantification. The design of the RASICAM system is presented.

  19. The LMC geometry and outer stellar populations from early DES data

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Balbinot, Eduardo; Plazas, A.; Santiago, B. X.; Girardi, L.; Pieres, A.; da Costa, L. N.; Maia, M. A. G.; Gruendl, R. A.; Walker, A. R.; Yanny, B.; et al

    2015-03-20

    The Dark Energy Camera has captured a large set of images as part of Science Verification (SV) for the Dark Energy Survey. The SV footprint covers a large portion of the outer Large Magellanic Cloud (LMC), providing photometry 1.5 magnitudes fainter than the main sequence turn-off of the oldest LMC stellar population. We derive geometrical and structural parameters for various stellar populations in the LMC disc. For the distribution of all LMC stars, we find an inclination of i = –38.14°±0.08° (near side in the North) and a position angle for the line of nodes of θ₀ = 129.51°±0.17°. Wemore » find that stars younger than ~4 Gyr are more centrally concentrated than older stars. Fitting a projected exponential disc shows that the scale radius of the old populations is R>4Gyr = 1.41 ± 0.01 kpc, while the younger population has R<4Gyr = 0.72 ± 0.01 kpc. However, the spatial distribution of the younger population deviates significantly from the projected exponential disc model. The distribution of old stars suggests a large truncation radius of Rt = 13.5 ± 0.8 kpc. If this truncation is dominated by the tidal field of the Galaxy, we find that the LMC is ≃24+9–6 times less massive than the encircled Galactic mass. By measuring the Red Clump peak magnitude and comparing with the best-fit LMC disc model, we find that the LMC disc is warped and thicker in the outer regions north of the LMC centre. As a result, our findings may either be interpreted as a warped and flared disc in the LMC outskirts, or as evidence of a spheroidal halo component.« less

  20. Browse Societies by Language -- E-print Network Societies by...

    Office of Scientific and Technical Information (OSTI)

    des Sciences, des Lettres et des Arts Tunisian Academy of the Sciences, ... de Psilogie Quebec Society of Psychology -- Socit Qubcoise pour l'tude ...

  1. Sorption Energy Ltd | Open Energy Information

    Open Energy Info (EERE)

    Oxford, England, United Kingdom Zip: OX1 2AY Product: Oxford-based firm developing adsorption air-conditioning and heating systems for domestic-scale products. Coordinates:...

  2. Project No 974 | Open Energy Information

    Open Energy Info (EERE)

    Project No 974 Place: Oxford, United Kingdom Zip: OX2 7SG Product: Biological fuel cell technology employing enzymatic catalysts. Project is at present without company name....

  3. Future Energy Solutions | Open Energy Information

    Open Energy Info (EERE)

    Solutions Jump to: navigation, search Name: Future Energy Solutions Place: Didcot, United Kingdom Zip: OX11 0QR Product: Future Energy Solutions is a sustainable energy...

  4. ANL2014-JMA.ppt

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    7 Department of Physics and Astronomy, Rutgers University, New Brunswick, NJ 08903 8 Oxford Physics, University of Oxford, Oxford OX1 3PU, United Kingdom *Research sponsored by...

  5. 1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    coverage was augmented by two additional profilers at Whitewater (wh), Kansas, and Oxford (ox), Kansas, that are part of the Atmospheric Boundary Layer Experiments (ABLE)...

  6. Radiocarbon (Geochronology)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Belfast: Marine Reservoir Database Calib Calibomb CLAMBACON IntCal Database Oxford University Radiocarbon Unit: OxCal PaleoclimateEnvironmental Databases: Neotoma NOAA...

  7. Cornwall Light Power CLP | Open Energy Information

    Open Energy Info (EERE)

    Cornwall Light Power CLP Jump to: navigation, search Name: Cornwall Light & Power (CLP) Place: Didcot, England, United Kingdom Zip: OX11 9DD Sector: Wind energy Product:...

  8. Agrivert | Open Energy Information

    Open Energy Info (EERE)

    Agrivert Jump to: navigation, search Name: Agrivert Place: Chipping Norton, England, United Kingdom Zip: OX7 4EB Product: String representation "Agrivert is a m ... aste...

  9. CoverSheet

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... As the oxidation progressed, several sub- stoichiometric thorium oxides, ThOx (x<1), preferentially formed between the thorium metal and its dioxide layer were observed. The SLD ...

  10. 2degrees | Open Energy Information

    Open Energy Info (EERE)

    Kingdom Zip: OX2 7HT Product: Oxford-based collaborative network provider for sustainability professionals. Coordinates: 43.781517, -89.571699 Show Map Loading map......

  11. Oxford Catalysts Group plc | Open Energy Information

    Open Energy Info (EERE)

    Oxford Catalysts Group plc Place: Oxford, United Kingdom Zip: OX2 6UD Sector: Hydro, Hydrogen Product: Developer of catalysts for room-temperature hydrogen production, hot steam...

  12. Taurine protects HK-2 cells from oxidized LDL-induced cytotoxicity via the ROS-mediated mitochondrial and p53-related apoptotic pathways

    SciTech Connect (OSTI)

    Chang, Chun-Yu; Shen, Chao-Yu; Kang, Chao-Kai; Sher, Yuh-Pyng; Sheu, Wayne H.-H.; Chang, Chia-Che; Lee, Tsung-Han

    2014-09-15

    Oxidized LDL (oxLDL) induces a pro-oxidative environment and promotes apoptosis, causing the progression of renal diseases in humans. Taurine is a semi-essential amino acid in mammals and has been shown to be a potent endogenous antioxidant. The kidney plays a pivotal role in maintaining the balance of taurine. However, the mechanisms underlying the protective effects of taurine against oxLDL-induced injury in renal epithelial cells have not been clarified. In the present study, we investigated the anti-apoptotic effects of taurine on human proximal tubular epithelial (HK-2) cells exposed to oxLDL and explored the related mechanisms. We observed that oxLDL increased the contents of ROS and of malondialdehyde (MDA), which is a lipid peroxidation by-product that acts as an indicator of the cellular oxidation status. In addition, oxLDL induced cell death and apoptosis in HK-2 cells. Pretreatment with taurine at 100 μM significantly attenuated the oxLDL-induced cytotoxicity. We determined that oxLDL triggered the phosphorylation of ERK and, in turn, the activation of p53 and other apoptosis-related events, including calcium accumulation, destabilization of the mitochondrial permeability and disruption of the balance between pro-apoptotic Bax and anti-apoptotic Bcl-2 proteins. The malfunctions induced by oxLDL were effectively blocked by taurine. Thus, our results suggested that taurine exhibits potential therapeutic activity by preventing oxLDL-induced nephrotoxicity. The inhibition of oxLDL-induced epithelial apoptosis by taurine was at least partially due to its anti-oxidant activity and its ability to modulate the ERK and p53 apoptotic pathways. - Highlights: • Oxidized LDL induced cytotoxicity and apoptosis in HK-2 cells. • Pretreatment with taurine attenuated oxLDL-induced nephrotoxicity. • Taurine protected against renal damages through inhibition of ROS generation. • Taurine prevented apoptosis through modulation of the p53 phosphorylation.

  13. How to stabilize highly active Cu+ cations in a mixed-oxide catalyst

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mudiyanselage, Kumudu; Luo, Si; Kim, Hyun You; Yang, Xiaofang; Baber, Ashleigh E.; Hoffmann, Friedrich M.; Senanayake, Sananayake; Rodriguez, Jose A.; Chen, Jingguang G.; Liu, Ping; et al

    2015-09-12

    Mixed-metal oxides exhibit novel properties that are not present in their isolated constituent metal oxides and play a significant role in heterogeneous catalysis. In this study, a titanium-copper mixed-oxide (TiCuOx) film has been synthesized on Cu(111) and characterized by complementary experimental and theoretical methods. At sub-monolayer coverages of titanium, a Cu2O-like phase coexists with TiCuOx and TiOx domains. When the mixed-oxide surface is exposed at elevated temperatures (600–650 K) to oxygen, the formation of a well-ordered TiCuOx film occurs. Stepwise oxidation of TiCuOx shows that the formation of the mixed-oxide is faster than that of pure Cu2O. As the Timore » coverage increases, Ti-rich islands (TiOx) form. The adsorption of CO has been used to probe the exposed surface sites on the TiOx–CuOx system, indicating the existence of a new Cu+ adsorption site that is not present on Cu2O/Cu(111). Adsorption of CO on Cu+ sites of TiCuOx is thermally more stable than on Cu(111), Cu2O/Cu(111) or TiO2(110). The Cu+ sites in TiCuOx domains are stable under both reducing and oxidizing conditions whereas the Cu2O domains present on sub-monolayer loads of Ti can be reduced or oxidized under mild conditions. Furthermore, the results presented here demonstrate novel properties of TiCuOx films, which are not present on Cu(111), Cu2O/Cu(111), or TiO2(110), and highlight the importance of the preparation and characterization of well-defined mixed-metal oxides in order to understand fundamental processes that could guide the design of new materials.« less

  14. Danger radiations

    ScienceCinema (OSTI)

    None

    2011-04-25

    Le conférencier Mons.Hofert parle des dangers et risques des radiations, le contrôle des zones et les précautions à prendre ( p.ex. film badge), comment mesurer les radiations etc.

  15. EIS_Summary

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Des Arc Austin Adona Houston Danville Palestine Perry Corinth Ward Cotton Plant ... Haynes Wheatley Fargo Horseshoe Lake Des Arc Hughes Palestine Ward Cotton Plant Forrest ...

  16. Expression and potential role of the peptide orexin-A in prostate cancer

    SciTech Connect (OSTI)

    Valiante, Salvatore; Liguori, Giovanna; Tafuri, Simona; Pavone, Luigi Michele; Campese, Roberto; Monaco, Roberto; Iachetta, Giuseppina; Assisi, Loredana; Mirabella, Nicola; Forte, Maurizio; Costagliola, Anna; Vittoria, Alfredo

    2015-09-04

    The peptides orexin-A and orexin-B and their G protein-coupled OX1 and OX2 receptors are involved in multiple physiological processes in the central nervous system and peripheral organs. Altered expression or signaling dysregulation of orexins and their receptors have been associated with a wide range of human diseases including narcolepsy, obesity, drug addiction, and cancer. Although orexin-A, its precursor molecule prepro-orexin and OX1 receptor have been detected in the human normal and hyperplastic prostate tissues, their expression and function in the prostate cancer (PCa) remains to be addressed. Here, we demonstrate for the first time the immunohistochemical localization of orexin-A in human PCa specimens, and the expression of prepro-orexin and OX1 receptor at both protein and mRNA levels in these tissues. Orexin-A administration to the human androgen-dependent prostate carcinoma cells LNCaP up-regulates OX1 receptor expression resulting in a decrease of cell survival. Noteworthy, nanomolar concentrations of the peptide counteract the testosterone-induced nuclear translocation of the androgen receptor in the cells: the orexin-A action is prevented by the addition of the OX1 receptor antagonist SB-408124 to the test system. These findings indicate that orexin-A/OX1 receptor interaction interferes with the activity of the androgen receptor which regulates PCa onset and progression, thus suggesting that orexin-A and its receptor might represent novel therapeutic targets to challenge this aggressive cancer. - Highlights: • Orexin-A and OX1 receptor are present in human cancer prostate tissues. • Orexin-A up-regulates OX1 receptor expression in LNCaP cells. • Orexin-A inhibits testosterone-induced nuclear translocation of androgen receptor.

  17. PWR core design, neutronics evaluation and fuel cycle analysis for thorium-uranium breeding recycle

    SciTech Connect (OSTI)

    Bi, G.; Liu, C.; Si, S.

    2012-07-01

    This paper was focused on core design, neutronics evaluation and fuel cycle analysis for Thorium-Uranium Breeding Recycle in current PWRs, without any major change to the fuel lattice and the core internals, but substituting the UOX pellet with Thorium-based pellet. The fuel cycle analysis indicates that Thorium-Uranium Breeding Recycle is technically feasible in current PWRs. A 4-loop, 193-assembly PWR core utilizing 17 x 17 fuel assemblies (FAs) was taken as the model core. Two mixed cores were investigated respectively loaded with mixed reactor grade Plutonium-Thorium (PuThOX) FAs and mixed reactor grade {sup 233}U-Thorium (U{sub 3}ThOX) FAs on the basis of reference full Uranium oxide (UOX) equilibrium-cycle core. The UOX/PuThOX mixed core consists of 121 UOX FAs and 72 PuThOX FAs. The reactor grade {sup 233}U extracted from burnt PuThOX fuel was used to fabrication of U{sub 3}ThOX for starting Thorium-. Uranium breeding recycle. In UOX/U{sub 3}ThOX mixed core, the well designed U{sub 3}ThOX FAs with 1.94 w/o fissile uranium (mainly {sup 233}U) were located on the periphery of core as a blanket region. U{sub 3}ThOX FAs remained in-core for 6 cycles with the discharged burnup achieving 28 GWD/tHM. Compared with initially loading, the fissile material inventory in U{sub 3}ThOX fuel has increased by 7% via 1-year cooling after discharge. 157 UOX fuel assemblies were located in the inner of UOX/U{sub 3}ThOX mixed core refueling with 64 FAs at each cycle. The designed UOX/PuThOX and UOX/U{sub 3}ThOX mixed core satisfied related nuclear design criteria. The full core performance analyses have shown that mixed core with PuThOX loading has similar impacts as MOX on several neutronic characteristic parameters, such as reduced differential boron worth, higher critical boron concentration, more negative moderator temperature coefficient, reduced control rod worth, reduced shutdown margin, etc.; while mixed core with U{sub 3}ThOX loading on the periphery of core has no visible impacts on neutronic characteristics compared with reference full UOX core. The fuel cycle analysis has shown that {sup 233}U mono-recycling with U{sub 3}ThOX fuel could save 13% of natural uranium resource compared with UOX once through fuel cycle, slightly more than that of Plutonium single-recycling with MOX fuel. If {sup 233}U multi-recycling with U{sub 3}ThOX fuel is implemented, more natural uranium resource would be saved. (authors)

  18. Electro Chem Technic | Open Energy Information

    Open Energy Info (EERE)

    Place: Oxford, United Kingdom Zip: OX3 7LA Product: The company makes and sells a novel small fuel cell. They sell as well a wide range of educational material about fuel...

  19. Approaches to Safe Nanotechnology

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... How- ever, since this approach relies primarily on static or area sampling, some ... Environ Health Perspect 114(1):51-58. Fuchs NA 1964. The mechanics of aerosols. Ox- ...

  20. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    colitis in mice, an animal model that mimics IBD. ... STFC Rutherford Appleton Laboratory, Didcot OX11 0FA Two ab ... targets, enhancing the success of AMPLE with small proteins. ...

  1. DOE/ER--0547T DE92

    Office of Scientific and Technical Information (OSTI)

    ... Behavior of Cd on Oxide Surfaces." Environ. Sci. J.A. Leenheer, and P. MacCarthy. 1987. "A ... t'r+lli develtl:mlent ifthe bismuth ptiSlhute, RI?II+)OX, +sd fluride ...

  2. Property:Zip | Open Energy Information

    Open Energy Info (EERE)

    + 21-Century Silicon, Inc. + 75081-1881 + 21st century Green Solutions LLC + 48439 + 25 x 25 America s Energy Future + 21093 + 2OC + BA1 7AB + 2degrees + OX2 7HT + 2e Carbon...

  3. Biojoule Ltd | Open Energy Information

    Open Energy Info (EERE)

    Biojoule Ltd Jump to: navigation, search Name: Biojoule Ltd Place: Oxford, England, United Kingdom Zip: OX4 1RQ Product: Biojoule is a pellets producer who has developed its own...

  4. Climate Care | Open Energy Information

    Open Energy Info (EERE)

    Climate Care Jump to: navigation, search Name: Climate Care Place: Oxford, England, United Kingdom Zip: OX4 1RQ Sector: Carbon Product: Oxford-based carbon offsetting firm- making...

  5. LeekSeek International | Open Energy Information

    Open Energy Info (EERE)

    LeekSeek International Jump to: navigation, search Name: LeekSeek International Place: Oxford, England, United Kingdom Zip: OX4 4GA Product: UK-based group who detect and prevent...

  6. Supported Au-CuO Catalysts for Low Temperature CO Oxidation

    Broader source: Energy.gov [DOE]

    Catalytic properties of Au-CuOx/SiO2 are investigated in removing pollutants from simulated automotive exhaust to meet an increasing demand for high emissions control at low temperatures.

  7. Oxis Energy Ltd | Open Energy Information

    Open Energy Info (EERE)

    Zip: OX14 3DB Product: Oxfordshire-based Oxis Energy is developing a rechargeable lithium-sulphur battery with more capacity than lithium ion, it claims. References: Oxis...

  8. Fuel Cell Technologies Office Funding by State

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Giner Nuvera Fuel Cells Maryland 4.6M National Institute of Standards and Technology (NIST) EnergyWorks RedOx Fuel Cells W. L. Gore & Associates Michigan 4.1M Eaton Ford General ...

  9. Search for: All records | DOE PAGES

    Office of Scientific and Technical Information (OSTI)

    from 0 to 3.3 WmK. Thus, the dominant thermal carrier in TaOx switches between vibrations and charge carriers and is controllable either by oxygen content during deposition,...

  10. Bio Energy Investments BEI | Open Energy Information

    Open Energy Info (EERE)

    Investments BEI Jump to: navigation, search Name: Bio Energy Investments (BEI) Place: Chinnor, United Kingdom Zip: OX39 4TW Sector: Biomass Product: UK-based company involved in...

  11. I

    Office of Legacy Management (LM)

    I & -Ty( p-3, ' W. r( * t P.O. B L a. I 24, Clin CHEMICALS GROUP OX 652 l PASADENA. TEXAS 77601 l (713) 472.3641 LJ April 12, 1979 Mr. William E. Mott Acting Director ...

  12. Novel Electrolytes and Additives | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    es023_abraham_2011_p.pdf More Documents & Publications Novel Electrolytes and Additives Progress in Electrolyte Component R&D within the ABR Program, 2009 thru 2013 Low Cost SiOx-Graphite and Olivine Materials

  13. Tunable Transmittance of Near-infrared and Visible Light in Reconstruc...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in glass composites fig 2 Figure 2: a) Polyniobate clusters (POM)-stabilized ITO aqueous dispersion, POM;N(CH3)46Nb10O28. b) ITO-in-NbOx film (thickness 150 nm) on glass...

  14. Nexeon | Open Energy Information

    Open Energy Info (EERE)

    Zip: OX14 3DB Product: UK-based company developing advanced Li-ion rechargeable battery technology. Coordinates: 51.813938, -1.2937 Show Map Loading map......

  15. Mixed N-Heterocyclic Carbene-Bis(oxazolinyl)borato Rhodium and Iridium Complexes in Photochemical and Thermal Oxidative Addition Reactions

    SciTech Connect (OSTI)

    Xu, Songchen; Manna, Kuntal; Ellern, Arkady; Sadow, Aaron D

    2014-12-08

    In order to facilitate oxidative addition chemistry of fac-coordinated rhodium(I) and iridium(I) compounds, carbene–bis(oxazolinyl)phenylborate proligands have been synthesized and reacted with organometallic precursors. Two proligands, PhB(OxMe2)2(ImtBuH) (H[1]; OxMe2 = 4,4-dimethyl-2-oxazoline; ImtBuH = 1-tert-butylimidazole) and PhB(OxMe2)2(ImMesH) (H[2]; ImMesH = 1-mesitylimidazole), are deprotonated with potassium benzyl to generate K[1] and K[2], and these potassium compounds serve as reagents for the synthesis of a series of rhodium and iridium complexes. Cyclooctadiene and dicarbonyl compounds {PhB(OxMe2)2ImtBu}Rh(?4-C8H12) (3), {PhB(OxMe2)2ImMes}Rh(?4-C8H12) (4), {PhB(OxMe2)2ImMes}Rh(CO)2 (5), {PhB(OxMe2)2ImMes}Ir(?4-C8H12) (6), and {PhB(OxMe2)2ImMes}Ir(CO)2 (7) are synthesized along with ToMM(?4-C8H12) (M = Rh (8); M = Ir (9); ToM = tris(4,4-dimethyl-2-oxazolinyl)phenylborate). The spectroscopic and structural properties and reactivity of this series of compounds show electronic and steric effects of substituents on the imidazole (tert-butyl vs mesityl), effects of replacing an oxazoline in ToM with a carbene donor, and the influence of the donor ligand (CO vs C8H12). The reactions of K[2] and [M(?-Cl)(?2-C8H14)2]2 (M = Rh, Ir) provide {?4-PhB(OxMe2)2ImMes?CH2}Rh(?-H)(?-Cl)Rh(?2-C8H14)2 (10) and {PhB(OxMe2)2ImMes}IrH(?3-C8H13) (11). In the former compound, a spontaneous oxidative addition of a mesityl ortho-methyl to give a mixed-valent dirhodium species is observed, while the iridium compound forms a monometallic allyl hydride. Photochemical reactions of dicarbonyl compounds 5 and 7 result in C–H bond oxidative addition providing the compounds {?4-PhB(OxMe2)2ImMes?CH2}RhH(CO) (12) and {PhB(OxMe2)2ImMes}IrH(Ph)CO (13). In 12, oxidative addition results in cyclometalation of the mesityl ortho-methyl similar to 10, whereas the iridium compound reacts with the benzene solvent to give a rare crystallographically characterized cis-[Ir](H)(Ph) complex. Alternatively, the rhodium carbonyl 5 or iridium isocyanide {PhB(OxMe2)2ImMes}Ir(CO)CNtBu (15) reacts with PhSiH3 in the dark to form the silyl compound {PhB(OxMe2)2ImMes}RhH(SiH2Ph)CO (14) or {PhB(OxMe2)2ImMes}IrH(SiH2Ph)CNtBu (17). These examples demonstrate the enhanced thermal reactivity of {PhB(OxMe2)2ImMes}-supported iridium and rhodium carbonyl compounds in comparison to tris(oxazolinyl)borate, tris(pyrazolyl)borate, and cyclopentadienyl-supported compounds.

  16. PV Crystalox Solar AG formerly PV Silicon AG | Open Energy Information

    Open Energy Info (EERE)

    PV Crystalox Solar AG formerly PV Silicon AG Jump to: navigation, search Name: PV Crystalox Solar AG (formerly PV Silicon AG) Place: Abingdon, England, United Kingdom Zip: OX14 4SE...

  17. Structure of the oxygen-annealed chalcogenide superconductor...

    Office of Scientific and Technical Information (OSTI)

    Fe1.08Te0.55Se0.45Ox Authors: Hu, Hefei ; Zuo, Jian-Min ; Zheng, Mao ; Eckstein, James N. ; Park, Wan Kyu ; Greene, Laura H. ; Wen, Jinsheng ; Xu, Zhijun ; Lin, Zhiwei ; Li,...

  18. Multi-stage, isothermal CO preferential oxidation reactor

    DOE Patents [OSTI]

    Skala, Glenn William (Churchville, NY); Brundage, Mark A. (Pittsford, NY); Borup, Rodney Lynn (East Rochester, NY); Pettit, William Henry (Rochester, NY); Stukey, Kevin (W. Henrietta, NY); Hart-Predmore, David James (Rochester, NY); Fairchok, Joel (Alexander, NY)

    2000-01-01

    A multi-stage, isothermal, carbon monoxide preferential oxidation (PrOx) reactor comprising a plurality of serially arranged, catalyzed heat exchangers, each separated from the next by a mixing chamber for homogenizing the gases exiting one heat exchanger and entering the next. In a preferred embodiment, at least some of the air used in the PrOx reaction is injected directly into the mixing chamber between the catalyzed heat exchangers.

  19. Direct Epoxidation of Propylene over Stabilized Cu+ Surface Sites on Ti Modified Cu2O

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yang, X.; Kattel, S.; Xiong, K.; Mudiyanselage, K.; Rykov, S.; Senanayake, S. D.; Rodriguez, J. A.; Liu, P.; Stacchiola, D. J.; Chen, J. G.

    2015-07-17

    Direct propylene epoxidation by O2 is a challenging reaction because of the strong tendency for complete combustion. Results from the current study demonstrate the feasibility to tune the epoxidation selectivity by generating highly dispersed and stabilized Cu+ active sites in a TiCuOx mixed oxide. The TiCuOx surface anchors the key surface intermediate, oxametallacycle, leading to higher selectivity for epoxidation of propylene.

  20. CT NC0

    Office of Legacy Management (LM)

    x-L* d! CT NC0 - i , ,. i, .' i :.:(e.!' ,A\~, L.,t, - (iI :i' , . y- 2 .L i ._ 1 c\ :- i;! Ii $ 4. Ci:lc:i.nnati. 39, t>:::i.f> (J&l3 q-1 -3 sui3 Jrn T3 FRCM .I iirz 1 ?j ~ 1.3 bL1 T:' IP !REFOI?T TC 5YC?CZCiC~ :EWllIFl;j",tsSS L' I"JIsIc:;. .:;xli3;. iCAN !fA(=;-fL,yg-j L' sc,, E. $.iCLX:i?, -iIJ,x:q()Is. ON hL4X 24 - 25 ) 1.9tic ;i. A. Quiglel;, A.3, 3, M. ChenauEt gpxrIvB OF TP.~ The purpose of t3is trip was tc observe a proposed method for the dchy- dratim of green salt

  1. Energy Citations Database (ECD) - Availability

    Office of Scientific and Technical Information (OSTI)

    vente des publications des Communautes Europeenes 37, rue Glesener-Luxembourg. FD U.S. Fish and Wildlife Service, 18th and C Streets, N.W., Mail Stop 1111, Arlington Square Bldg.,...

  2. CX-006500: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Magellan Des Moines Biodiesel Terminal ProjectCX(s) Applied: B5.1Date: 09/06/2011Location(s): Des Moines, IowaOffice(s): Energy Efficiency and Renewable Energy, Golden Field Office

  3. Sciences and society

    SciTech Connect (OSTI)

    2008-01-10

    J.Luns des Pays-Bas, ancien sécétaire général de NATO (OTAN=Organisation du traité de l'Atlantique Nord) parle du passé, présent et future de la défense européenne et des relations est et ouest

  4. Fermilab | Newsroom | Press Releases | March 10, 2015: Scientists...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 March 10, 2015 FOR IMMEDIATE RELEASE Scientists find rare dwarf satellite galaxy candidates in Dark Energy Survey data DES-Dwarf-Galaxies DES-Dwarf-Galaxies Previous Next...

  5. Research- Knowledge

    ScienceCinema (OSTI)

    None

    2011-04-25

    S.Mansholt, connu sur le marché commun de la communité européenne, est agriculteur et agronome de profession et un des pionnier et animateur des affaires d'unification européene

  6. Celebration of PS

    ScienceCinema (OSTI)

    None

    2011-04-25

    Le DG John Adams parle des premières années du PS avec présentation des dias ainsi il honore Pierre Germain qui après 24 ans de travail quitte sa fonction.

  7. Mild partial deoxygenation of esters catalyzed by an oxazolinylborate-coordinated rhodium silylene

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Xu, Songchen; Boschen, Jeffery S.; Biswas, Abhranil; Kobayashi, Takeshi; Pruski, Marek; Windus, Theresa L.; Sadow, Aaron D.

    2015-08-17

    An electrophilic, coordinatively unsaturated rhodium complex supported by borate-linked oxazoline, oxazoline-coordinated silylene, and N-heterocyclic carbene donors [{κ³-N,Si,C-PhB(OxMe²)(OxMe²SiHPh)ImMes}Rh(H)CO][HB(C₆F₅)₃] (2, OxMe² = 4,4-dimethyl-2-oxazoline; ImMes = 1-mesitylimidazole) is synthesized from the neutral rhodium silyl {PhB(OxMe²)₂ImMes}RhH(SiH2Ph)CO (1) and B(C6F5)3. The unusual oxazoline-coordinated silylene structure in 2 is proposed to form by rearrangement of an unobserved isomeric cationic rhodium silylene species [{PhB(OxMe²)₂ImMes}RhH(SiHPh)CO][HB(C₆F₅)₃] generated by H abstraction. Complex 2 catalyzes reductions of organic carbonyl compounds with silanes to give hydrosilylation products or deoxygenation products. The pathway to these reactions is primarily influenced by the degree of substitution of the organosilane. Reactions with primary silanes give deoxygenationmore » of esters to ethers, amides to amines, and ketones and aldehydes to hydrocarbons, whereas tertiary silanes react to give 1,2-hydrosilylation of the carbonyl functionality. In contrast, the strong Lewis acid B(C₆F₅)₃ catalyzes the complete deoxygenation of carbonyl compounds to hydrocarbons with PhSiH₃ as the reducing agent.« less

  8. NASEO Midwest Regional Meeting

    Broader source: Energy.gov [DOE]

    The National Association of State Energy Officials (NASEO) is hosting its Midwest Regional Meeting in Des Moines, Iowa.

  9. Departure Roger Anthoine

    SciTech Connect (OSTI)

    2007-11-28

    Remerciements et discours du D.G. H.Schopper à l'occasion du départ de Roger Anthoine (attaché de presse), qui travaillait dans la communication et quitte le Cern après 27 ans de service. Il gardait des relations avec des médias internationaux et la presse locale; remise des cadeaux: album photo avec images des musés de Genève et un radio aviation; R.A. fait un résumé de ses activités et souvenirs et remercie ses collaborateurs

  10. Midday Meeting- Chemically induced Mind Alteration

    ScienceCinema (OSTI)

    None

    2011-04-25

    Le Docteur Hugo Solms parle de l'abus des drogues, pourquoi les gens en prennent et comment vivre sans

  11. JCS PHEV System Development | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Program | Department of Energy Representatives from the Des Moines Metropolitan WRA and Des Moines Water Works sign the SEP agreement. The Des Moines Metropolitan Wastewater Reclamation Authority (WRA) and Des Moines Water Works have committed to participate in the Superior Energy Performance (SEP) program as the first members of a new program pilot. SEP recognizes facilities that meet the ISO 50001 global energy management standard and demonstrate improved energy performance. A third-party

  12. Gas Technology Institute (Partnership for Advanced Residential...

    Open Energy Info (EERE)

    Technology Institute (Partnership for Advanced Residential Retrofit) Jump to: navigation, search Name: Gas Technology Institute Place: Des Plaines, IL Website:...

  13. Utilization Technology Institute | Open Energy Information

    Open Energy Info (EERE)

    Utilization Technology Institute Jump to: navigation, search Name: Utilization Technology Institute Place: Des Plaines, IL References: Utilization Technology Institute1...

  14. PET

    ScienceCinema (OSTI)

    None

    2011-04-25

    le DG fait l'introduction et laisse la parole à plusieurs intervenants au sujet de la physique des particules

  15. Visit CD

    ScienceCinema (OSTI)

    None

    2011-04-25

    Le DG H.Schopper souhaite la bienvenue aux ambassadeurs des pays membres et aux représentants des pays avec lesquels le Cern entretient des relations proches et fait un exposé sur les activités au Cern

  16. High temperature crystalline superconductors from crystallized glasses

    DOE Patents [OSTI]

    Shi, Donglu

    1992-01-01

    A method of preparing a high temperature superconductor from an amorphous phase. The method involves preparing a starting material of a composition of Bi.sub.2 Sr.sub.2 Ca.sub.3 Cu.sub.4 Ox or Bi.sub.2 Sr.sub.2 Ca.sub.4 Cu.sub.5 Ox, forming an amorphous phase of the composition and heat treating the amorphous phase for particular time and temperature ranges to achieve a single phase high temperature superconductor.

  17. kE.O?-3.1

    Office of Legacy Management (LM)

    in ofdor that the bynyoraoontnotnthortllw ot l ppurod to be aeoommry boomu. pd.0 oould bo Cixod 08 tho ltmu pur&aro pd.7 brlre . . . . . . i. xfy-wkabo ailyarmP qu..t1olm ox'thsd...

  18. Microsoft Word - TRUPACT-III Quick Facts.docx

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    C ommission C ertificate N umber 9 305 General D escription: A r ectangular c ontainer u sed t o t ransport t ransuranic w aste i n a S tandard L arge B ox 2 (SLB2) b y h ighway t...

  19. Development of High Energy Cathode Materials | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon es056_zhang_2011_o.pdf More Documents & Publications Development of High Energy Cathode for Li-ion Batteries Phase Behavior and Solid State Chemistry in Olivines Low Cost SiOx-Graphite and Olivine Materials

  20. Arsenic augments the uptake of oxidized LDL by upregulating the expression of lectin-like oxidized LDL receptor in mouse aortic endothelial cells

    SciTech Connect (OSTI)

    Hossain, Ekhtear; Ota, Akinobu; Karnan, Sivasundaram; Damdindorj, Lkhagvasuren; Takahashi, Miyuki; Konishi, Yuko; Konishi, Hiroyuki; Hosokawa, Yoshitaka

    2013-12-15

    Although chronic arsenic exposure is a well-known risk factor for cardiovascular diseases, including atherosclerosis, the molecular mechanism underlying arsenic-induced atherosclerosis remains obscure. Therefore, this study aimed to elucidate this molecular mechanism. We examined changes in the mRNA level of the lectin-like oxidized LDL (oxLDL) receptor (LOX-1) in a mouse aortic endothelial cell line, END-D, after sodium arsenite (SA) treatment. SA treatment significantly upregulated LOX-1 mRNA expression; this finding was also verified at the protein expression level. Flow cytometry and fluorescence microscopy analyses showed that the cellular uptake of fluorescence (Dil)-labeled oxLDL was significantly augmented with SA treatment. In addition, an anti-LOX-1 antibody completely abrogated the augmented uptake of Dil-oxLDL. We observed that SA increased the levels of the phosphorylated forms of nuclear factor of kappa light polypeptide gene enhancer in B cells (NF-κB)/p65. SA-induced upregulation of LOX-1 protein expression was clearly prevented by treatment with an antioxidant, N-acetylcysteine (NAC), or an NF-κB inhibitor, caffeic acid phenethylester (CAPE). Furthermore, SA-augmented uptake of Dil-oxLDL was also prevented by treatment with NAC or CAPE. Taken together, our results indicate that arsenic upregulates LOX-1 expression through the reactive oxygen species-mediated NF-κB signaling pathway, followed by augmented cellular oxLDL uptake, thus highlighting a critical role of the aberrant LOX-1 signaling pathway in the pathogenesis of arsenic-induced atherosclerosis. - Highlights: • Sodium arsenite (SA) increases LOX-1 expression in mouse aortic endothelial cells. • SA enhances cellular uptake of oxidized LDL in dose-dependent manner. • SA-induced ROS generation enhances phosphorylation of NF-κB. • SA upregulates LOX-1 expression through ROS-activated NF-κB signaling pathway.

  1. Structure and Reactivity of Alkyl Ethers Adsorbed on CeO2(111) Model Catalysts

    SciTech Connect (OSTI)

    F Calaza; T Chen; D Mullins; S Overbury

    2011-12-31

    The effect of surface hydroxyls on the adsorption of ether on ceria was explored. Adsorption of dimethyl ether (DME) and diethyl ether (DEE) on oxidized and reduced CeO{sub 2}(111) films was studied and compared with Ru(0001) using RAIRS and sXPS within a UHV environment. On Ru(0001) the ethers adsorb weakly with the molecular plane close to parallel to the surface plane. On the ceria films, the adsorption of the ethers was stronger than on the metal surface, presumably due to stronger interaction of the ether oxygen lone pair electrons with a cerium cation. This interaction causes the ethers to tilt away from the surface plane compared to the Ru(0001) surface. No pronounced differences were found between oxidized (CeO{sub 2}) and reduced (CeOx) films. The adsorption of the ethers was found to be perturbed by the presence of OH groups on hydroxylated CeOx. In the case of DEE, the geometry of adsorption resembles that found on Ru, and in the case of dimethyl ether DME is in between that one found on clean CeOx and the metal surface. Decomposition of the DEE was observed on the OH/CeOx surface following high DEE exposure at 300 K and higher temperatures. Ethoxides and acetates were identified as adsorbed species on the surface by means of RAIRS and ethoxides and formates by s-XPS. No decomposition of dimethyl ether was observed on the OH/CeOx at these higher temperatures, implying that the dissociation of the C-O bond from ethers requires the presence of {beta}-hydrogen.

  2. Structure and Reactivity of Alkyl Ethers Adsorbed on CeO(2)(111) Model Catalysts

    SciTech Connect (OSTI)

    Calaza, Florencia C; Chen, Tsung-Liang; Mullins, David R; Overbury, Steven {Steve} H

    2011-01-01

    The effect of surface hydroxyls on the adsorption of ether on ceria was explored. Adsorption of dimethyl ether (DME) and diethyl ether (DEE) on oxidized and reduced CeO{sub 2}(111) films was studied and compared with Ru(0001) using RAIRS and sXPS within a UHV environment. On Ru(0001) the ethers adsorb weakly with the molecular plane close to parallel to the surface plane. On the ceria films, the adsorption of the ethers was stronger than on the metal surface, presumably due to stronger interaction of the ether oxygen lone pair electrons with a cerium cation. This interaction causes the ethers to tilt away from the surface plane compared to the Ru(0001) surface. No pronounced differences were found between oxidized (CeO{sub 2}) and reduced (CeOx) films. The adsorption of the ethers was found to be perturbed by the presence of OH groups on hydroxylated CeOx. In the case of DEE, the geometry of adsorption resembles that found on Ru, and in the case of dimethyl ether DME is in between that one found on clean CeOx and the metal surface. Decomposition of the DEE was observed on the OH/CeOx surface following high DEE exposure at 300 K and higher temperatures. Ethoxides and acetates were identified as adsorbed species on the surface by means of RAIRS and ethoxides and formates by s-XPS. No decomposition of dimethyl ether was observed on the OH/CeOx at these higher temperatures, implying that the dissociation of the C-O bond from ethers requires the presence of {beta}-hydrogen.

  3. HI!$PQ

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    §¦ ¨ ©    "!$#&%('£¢)10 2 %435©687 @9BADCE9GF HI!$PQ 7 HR9BHR¢¥¢)S¢T C5UV¡£¢)@9 ADCW9 X©Y CWF F U$!`%4ba ¢c%¥F Hd  e5a#f "F g CihY"¢ prqtsvuxwyq€ƒ‚…„‡†‰ˆv’‘”“–•˜—d™ew’fdgcˆ˜shi„kj’lcwDfkm)—8nBˆv‘o’qpdDq–rbs5’q‡•t— u wys nBg(stsv“yg • —kjw€hxDˆvytwyq m

  4. St. Charles County, Missouri: Energy Resources | Open Energy...

    Open Energy Info (EERE)

    Missouri O'Fallon, Missouri Portage Des Sioux, Missouri St. Charles, Missouri St. Paul, Missouri St. Peters, Missouri Weldon Spring Heights, Missouri Weldon Spring, Missouri...

  5. "Title","Creator/Author","Publication Date","OSTI Identifier...

    Office of Scientific and Technical Information (OSTI)

    Royale Pour L'Avancement Des Sciences","USDOE","36 MATERIALS SCIENCE Clean Coal Technology Coal - Environmental Processes",,"The feasibility of using carbon dioxide as...

  6. The english at Cern

    ScienceCinema (OSTI)

    None

    2011-04-25

    Assemblée du personnel anglais traitant des sujets tels affaires sociales, salaires, caisse de pension etc....avec plusieurs conférenciers (date inconnue)

  7. National Association of the Remodeling Industry (NARI) | Open...

    Open Energy Info (EERE)

    Association of the Remodeling Industry (NARI) Jump to: navigation, search Name: National Association of the Remodeling Industry (NARI) Place: Des Plaines, IL Website: www.nari.org...

  8. 65th Birthday of Dr.Owen Lock

    ScienceCinema (OSTI)

    None

    2011-04-25

    Remerciements au Dr.Owen Lock, un des pionniers du Cern, à l'occasion de son 65me anniversaire et sa retraite (avec plusieurs intervenants)

  9. Roeder Farms | Open Energy Information

    Open Energy Info (EERE)

    Developer 5045 Wind Partners Energy Purchaser Alliant Energy Location Des Moines IA Coordinates 43.29729211, -93.28315258 Show Map Loading map... "minzoom":false,"mapp...

  10. Iowa Office of Energy Independence | Open Energy Information

    Open Energy Info (EERE)

    navigation, search Name: Iowa Office of Energy Independence Place: Des Moines, Iowa Zip: IA 50319 Product: In 2007, Governor Culver and the Iowa State Legislature created the...

  11. Browse by Discipline -- E-print Network Subject Pathways: Plasma...

    Office of Scientific and Technical Information (OSTI)

    Ecole des Mines de Nantes Kasher, Roni (Roni Kasher) - Zuckerberg Institute for Water Research, Zuckerberg Institute for Water Research, Jacob Blaustein Institutes for Desert ...

  12. Apollo Solar Energy Inc | Open Energy Information

    Open Energy Info (EERE)

    Inc Jump to: navigation, search Name: Apollo Solar Energy Inc Place: Bethel, Connecticut Zip: 68010 Sector: Solar Product: String representation "The company des ... e &...

  13. Superior Energy Performance: Certifying Increased Energy Productivity...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Management Working Group (EMWG) Waterwastewater Des Moines, IA (2) Delta Diablo, CA Ithaca, NY Kent County, DE Victor Valley, CA Alexandria (VA) Renew ...

  14. Solaire Durance | Open Energy Information

    Open Energy Info (EERE)

    Jump to: navigation, search Name: Solaire Durance Place: France Sector: Solar Product: Joint venture between French state bank la Caisse des Dpots and French solar power...

  15. International Association of Public Transport | Open Energy Informatio...

    Open Energy Info (EERE)

    search Name: International Association of Public Transport Address: Rue Sainte-Marie 6 (Quai des Charbonnages) Place: Brussels, Belgium Zip: B-1080 Sector: Vehicles Year...

  16. Departure Roger Anthoine

    ScienceCinema (OSTI)

    None

    2011-04-25

    Remerciements et discours du D.G. H.Schopper à l'occasion du départ de Roger Anthoine (attaché de presse), qui travaillait dans la communication et quitte le Cern après 27 ans de service. Il gardait des relations avec des médias internationaux et la presse locale; remise des cadeaux: album photo avec images des musés de Genève et un radio aviation; R.A. fait un résumé de ses activités et souvenirs et remercie ses collaborateurs

  17. Iowa Department of Economic Development | Open Energy Information

    Open Energy Info (EERE)

    Department of Economic Development Jump to: navigation, search Name: Iowa Department of Economic Development Place: Des Moines, Iowa Zip: 50309 Product: Iowa economic development...

  18. EECBG Success Story: After 105 Years, Historic City Hall in West...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    City Hall in West Des Moines, Iowa Goes Green EECBG Success Story: Grant Improves ... of Oro Valley EECBG Success Story: Energy Upgrades to Save Small Arizona Town Big ...

  19. Transcendental Meditation

    ScienceCinema (OSTI)

    None

    2011-04-25

    K.Wallace, qui vient des Etats Unis, parle des effects physiologiques de la méditation transcendantale. Il a fait son bachelor en physique à l'Université de Los Angeles et son doctorat en physiologie aussi à Los Angeles, mais à l'Institut de Recherche sur le cerveau. Il travaille maintenat à Harvard Medical School ou il continue des recherches biochimiques et physiologiques sur l'application médicale de la méditation transcendantale. Il s'occupe principalement des maladies cardiaques et de hypertension artérielle.

  20. June 16 & 17, 2014 Meeting of the Electricity Advisory Committee...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Doug Larson, WIEB Steve Beuning, Xcel Carrie Cullen Hitt, SEIA Tuesday, June 17, 2014 Panel - Distributed Energy Storage (DES) - Wanda Reder, S&C, moderator Willem Fadrhonc, STEM ...

  1. AgraGate Carbon Credits Corporation | Open Energy Information

    Open Energy Info (EERE)

    AgraGate Carbon Credits Corporation Jump to: navigation, search Name: AgraGate Carbon Credits Corporation Place: Des Moines, Iowa Zip: 50266 Product: Offset aggregators that work...

  2. Energy Savings with Acceptable Indoor Air Quality Through Improved Air Flow Control in Residential Retrofit

    Broader source: Energy.gov [DOE]

    Lead Performer: Gas Technology Institute—Des Plaines, IL Partners: -- University of Illinois, Urbana IL -- Midwest Energy Efficiency Alliance, Chicago IL

  3. Secretary Chu Announces Middle and High School Finalists Set...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Lincolnshire Daniel Wright Middle School Indiana Carmel Creekside Middle School West Lafayette Harrison High School Iowa Cedar Rapids Home Schools of Eastern Iowa (MS) West Des ...

  4. FY 2014 Projects for Improving the Design, Construction, and...

    Energy Savers [EERE]

    Institute (Des Plaines, Ill.) - Simultaneous Waste Heat and Water Recovery from Power Plant Flue Gases for Advanced Energy Systems. The project team will further develop an...

  5. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Des Soye, Benjamin J. (1) Fields, Stanley (1) Garruss, Alexander S. (1) Jewett, Michael C. ... new ligands Taylor, Noah D. ; Garruss, Alexander S. ; Moretti, Rocco ; Chan, Sum ; ...

  6. General Staff Meeting

    ScienceCinema (OSTI)

    None

    2011-04-25

    Le DG H.Schopper informe le personnel des derniers événements au Cern, comme: 1.) Décision du LEP 2.) Budget 3.) Pension

  7. Department of Energy Announces $67 Million Investment for Carbon...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Experimental results will be used to refine the integrated process simulation and to design a slipstream facility. (DOE share: 1,266,249) Gas Technology Institute (Des Plaines, ...

  8. Categorical Exclusion Determinations: Western Area PowerAdministratio...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Categorical Exclusion Determinations: Western Area Power Administration-Desert Southwest Region Categorical Exclusion Determinations issued by Western Area Power Administration-Des...

  9. 2016 High School Science Bowl Participating Teams | The Ames...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (Bettendorf) Prince of Peace (Clinton) Regina (Iowa City) Roland-Story Shenandoah St. Albert (Council Bluffs) Union (La Porte City) Valley (West Des Moines) West Central Valley...

  10. Jawaharlal Nehru

    ScienceCinema (OSTI)

    None

    2011-04-25

    L'orateur S.E. Giusti del Giardino a connu Nehru (ennemi des castes) les dernières années de sa vie

  11. The endocrine disruptor diethylstilbestrol induces adipocyte differentiation and promotes obesity in mice

    SciTech Connect (OSTI)

    Hao, Chan-Juan; Cheng, Xue-Jia; Xia, Hong-Fei Ma, Xu

    2012-08-15

    Epidemiology studies indicate that exposure to endocrine disruptors during developmental “window” contributes to adipogenesis and the development of obesity. Implication of endocrine disruptor such as diethylstilbestrol (DES) on adipose tissue development has been poorly investigated. Here we evaluated the effects of DES on adipocyte differentiation in vitro and in vivo, and explored potential mechanism involved in its action. DES induced 3T3-L1 preadipocyte differentiation in a dose-dependent manner, and activated the expression of estrogen receptor (ER) and peroxisome proliferator-acivated receptor (PPAR) γ as well as its target genes required for adipogenesis in vitro. ER mediated the enhancement of DES-induced PPARγ activity. Moreover, DES perturbed key regulators of adipogenesis and lipogenic pathway in vivo. In utero exposure to low dose of DES significantly increased body weight, liver weight and fat mass in female offspring at postnatal day (PND) 60. In addition, serum triglyceride and glucose levels were also significantly elevated. These results suggest that perinatal exposure to DES may be expected to increase the incidence of obesity in a sex-dependent manner and can act as a potential chemical stressor for obesity and obesity-related disorders. -- Highlights: ► DES induced adipocyte differentiation in a dose-dependent manner in 3T3-L1 cells. ► DES activated adipogenic critical regulators and markers in vitro and in vivo. ► Perinatal exposure to DES led to the obese phenotype in female offspring. ► DES might be a potential chemical stressor for obesity and obesity-related disorders.

  12. An improved thermodynamic model for the complexation of trivalent actinides and lanthanide with oxalic acid valid to high ionic strength.

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Xiong, Yongliang; Thakur, Punam; Borkowski, Marian

    2015-07-30

    The dissociation constants of oxalic acid (Ox), and the stability constants of Am3+, Cm3+ and Eu3+ with Ox2– have been determined at 25 °C, over a range of concentration varying from 0.1 to 6.60 m NaClO4 using potentiometric titration and extraction techniques, respectively. The experimental data support the formation of complexes, M(Ox)n3 – 2n, where (M = Am3+, Cm3+ and Eu3+ and n = 1 and 2). The dissociation constant and the stability constant values measured as a function of NaClO4 concentration were used to estimate the Pitzer parameters for the respective interactions of Am3+, Cm3+ and Eu3+ with Ox.more » Furthermore, the stability constants data of Am3+ –Ox measured in NaClO4 and in NaCl solutions from the literature were simultaneously fitted in order to refine the existing actinide–oxalate complexation model that can be used universally in the safety assessment of radioactive waste disposal. The thermodynamic stability constant: log β0101 = 6.30 ± 0.06 and log β0102 = 10.84 ± 0.06 for Am3+ was obtained by simultaneously fitting data in NaCl and NaClO4 media. Additionally, log β0101 = 6.72 ± 0.08 and log β0102 = 11.05 ± 0.09 for the Cm3+ and log β0101 = 6.67 ± 0.08 and log β0102 = 11.15 ± 0.09 for the Eu3+ were calculated by extrapolation of data to zero ionic strength in NaClO4 medium only. For all stability constants, the Pitzer model gives an excellent representation of the data using interaction parameters β(0), β(1), and CΦ determined in this work. The thermodynamic model developed in this work will be useful in accurately modeling the potential solubility of trivalent actinides and early lanthanides to ionic strength of 6.60 m in low temperature environments in the presence of Ox. Furthermore, the work is also applicable to the accurate modeling transport of rare earth elements in various environments under the surface conditions.« less

  13. Hierarchical Heterogeneity at the CeO x –TiO 2 Interface: Electronic and Geometric Structural Influence on the Photocatalytic Activity of Oxide on Oxide Nanostructures

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Luo, Si; Nguyen-Phan, Thuy-Duong; Johnston-Peck, Aaron C.; Barrio, Laura; Sallis, Shawn; Arena, Dario A.; Kundu, Shankhamala; Xu, Wenqian; Piper, Louis F. J.; Stach, Eric A.; et al

    2015-01-13

    Mixed oxide interfaces are critical for delivering active components of demanding catalytic processes such as the photo-catalytic splitting of water. We have studied CeOxTiO₂ catalysts with low ceria loadings of 1 wt%, 3 wt% and 6 wt% that were prepared with wet impregnation methods to favor a strong interaction between CeOx and TiO₂. In these materials the interfaces between CeOx-TiO₂ have been sequentially loaded (1%, 3% and 6%), with and without Pt (0.5 wt%). The structure and properties of the catalysts were characterized using several X-ray and electron based techniques including XRD, XPS, UPS, NEXAFS, UV-Vis and HR-STEM/STEM-EELS, to unravelmore » the local morphology, bulk structure, surface states and electronic structure. The combination of all these techniques allow us to analyze in a systematic way the complete structural and electronic properties that prevail at the CeOx-TiO₂ interface. Fluorite structured nano crystallites of ceria on anatase-structured titania were identified by both XRD and NEXAFS. A sequential increasing of the CeOx loading led to the formation of clusters, then plates and finally nano particles in a hierarchical manner on the TiO₂ support. The electronic structures of these catalysts indicate that the interaction between TiO₂ and CeO₂ is closely related to the local morphology of nanostructured CeO₂. Ce³⁺ cations were detected at the surface of CeO₂ and at the interface of the two oxides. In addition, the titania is perturbed by the interaction with ceria and also with Pt. The photocatalytic activity for the splitting of H₂O using UV light was measured for these materials and correlated with our understanding of the electronic and structural properties. Optimal catalytic performance and photo response results were found for the 1 wt% CeOx-TiO₂ catalyst where low dimensional geometry of the ceria provided ideal electronic and geometrical properties. The structural and electronic properties of the interface were critical for the photocatalytic performance of this mixed-oxide nanocatalyst system.« less

  14. Iowa Water and Wastewater Operators Seek SEP Certification in New Pilot Program

    Broader source: Energy.gov [DOE]

    The Des Moines Metropolitan Wastewater Reclamation Authority (WRA) and Des Moines Water Works have committed to participate in the Superior Energy Performance (SEP) program as the first members of a new program pilot. SEP recognizes facilities that meet the ISO 50001 global energy management standard and demonstrate improved energy performance.

  15. The new role of scientists

    ScienceCinema (OSTI)

    None

    2011-04-25

    Le D.G. Jentschke fait l'introduction et présente le Prof.Kowarsky, spécialiste en microbiologie, physique nucléaire et une des fondateurs du Cern. Il parle entre autre de l'énergie nucléaire (pacifique)et de remise en questions des valeurs scientifiques et techniques

  16. Memorial Lew Kowarski

    ScienceCinema (OSTI)

    None

    2011-04-25

    Le DG J.Adams et d'autres intervenants rendent hommage à L.Kowarski (1907-1979), un des pionniers du Cern en 1952, né à St.Petersbourg et physicien, chimiste et ingénieur. Depuis sa retraite en 1972, il se consacra à l'enseignement et est conseiller des Nations Unies.

  17. Science and Society

    ScienceCinema (OSTI)

    None

    2011-04-25

    Le conférencier (qui? L'introduction manque) est économiste et directeur d'un institut de recherche. Il parlera des conséquences économiques désastreuses des dépenses militaires.

  18. CX-003913: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Iowa-City-Des MoinesCX(s) Applied: A1, A9, A11, B1.32, B5.1Date: 09/17/2010Location(s): Des Moines, IowaOffice(s): Energy Efficiency and Renewable Energy

  19. CX-006016: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Energy Efficiency and Conservation Block Grant Program - Iowa-City-West Des MoinesCX(s) Applied: A1, A9, B2.5, B5.1Date: 05/27/2011Location(s): Des Moines, IowaOffice(s): Energy Efficiency and Renewable Energy

  20. CX-005264: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Illinois-City-Des PlainesCX(s) Applied: A9, B2.5, B3.6, B5.1Date: 02/15/2011Location(s): Des Plaines, IllinoisOffice(s): Energy Efficiency and Renewable Energy

  1. Sciences and society

    ScienceCinema (OSTI)

    None

    2011-04-25

    J.Luns des Pays-Bas, ancien sécétaire général de NATO (OTAN=Organisation du traité de l'Atlantique Nord) parle du passé, présent et future de la défense européenne et des relations est et ouest

  2. CX-001027: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Development of an Autogas Network (Des Plains)CX(s) Applied: A9, B2.5, B3.6, B5.1Date: 03/02/2010Location(s): Des Plaines, IllinoisOffice(s): Energy Efficiency and Renewable Energy, National Energy Technology Laboratory

  3. Meeting Jentschke

    ScienceCinema (OSTI)

    None

    2011-04-25

    Après une introduction des dernières recherches et nouvelles au Cern, le DG W.Jentschke parle du futur management du Cern avec deux nouv directeurs générales, responsables pour les 5 ans prochains: le Dr.J.B.Adams qui s'occupera de l'administration du Cern et aussi de la construction des bâtiments et équipements et Le Dr.L.van Hove qui sera responsable pour les activités de la recherche. Le DG parle des changes et structures prévus, des services communs, des différentes divisions et leurs chefs etc...

  4. Thermal transport in tantalum oxide films for memristive applications

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Landon, Colin Donald; Wilke, Rudeger H. T.; Brumbach, Michael T.; Brennecka, Geoffrey L.; Blea-Kirby, Mia Angelica; Ihlefeld, Jon; Marinella, Matthew; Thomas Edwin Beechem

    2015-07-15

    The thermal conductivity of amorphous TaOx memristive films having variable oxygen content is measured using time domain thermoreflectance. Furthermore, the thermal transport is described by a two-partmodel where the electrical contribution is quantified via the Wiedemann-Franz relation and the vibrational contribution by the minimum thermal conductivity limit for amorphous solids. Additionally, the vibrational contribution remains constant near 0.9 W/mK regardless of oxygen concentration, while the electrical contribution varies from 0 to 3.3 W/mK. Thus, the dominant thermal carrier in TaOx switches between vibrations and charge carriers and is controllable either by oxygen content during deposition, or dynamically by field-induced chargemore » state migration.« less

  5. Final Technical Report

    SciTech Connect (OSTI)

    Logan, Jesse, L; Witmer, Dennis, PhD

    2012-07-29

    The overall goal of this project was to design, evaluate, and engineer a Vanadium Red-Ox Flow Battery's integration into an existing wind site and micro-grid environment to determine if it is possible to achieve a fifteen percent reduction of diesel fuel usage during periods of peak load and otherwise stabilize the grid in potential high wind penetration systems. The bulk of the work was done by modeling the existing hybrid wind-diesel system and the proposed system with added flow battery storage. The flow battery was changed from a Vanadium Red-Ox to a Zinc Bromine flow battery by a different manufacturer during the modeling process. Several complications arose, but modeling proved to be successful and is ongoing. The development of a modeling platform for flow battery energy storage is a key element in evaluating both economic benefits and dispatch strategies for high penetration in micro-grid wind-diesel systems.

  6. Flow Batteries: A Historical Perspective | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Batteries: A Historical Perspective Flow Batteries: A Historical Perspective Presentation by Robert Savinell, Case Western Reserve University, at the Flow Cells for Energy Storage Workshop held March 7-8, 2012, in Washington, DC. PDF icon flowcells2012_savinell.pdf More Documents & Publications Energy Storage Systems 2014 Peer Review Presentations - Poster Session 4 Flow Cells for Energy Storage Workshop Summary Report Some Lessons Learned from 20 Years in RedOx Flow Battery R&d

  7. 06.01.16 BVO - JCAP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Photoanode Development Through Combinatorial Integration of mixed-metal Oxide Catalysts on Bismuth vanadate Guevarra, D. et al. Development of solar fuels photoanodes through combinatorial integration of Ni-La-Co-Ce oxide catalysts on BiVO4. Energy & Environmental Science, DOI: 10.1039/C5EE03488D (2015). Scientific Achievement Multi-metal compositions of (Ni-La-Co-Ce)Ox oxygen evolution reaction (OER) catalyst coatings improve the photoelectrochemical power conversion efficiency 20-fold

  8. 15.02.10 RH Transparent Catalytic - JCAP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transparent Catalytic Nickel Oxide Protecting Films for Photoanodes Sun, K. et al. Stable solar-driven oxidation of water by semiconducting photoanodes protected by transparent catalytic nickel oxide films. PNAS 112 ( 12), 3612-3617, DOI: 10.1073/ pnas . 1423034112 (2015). Scientific Achievement Reactively sputtered NiOx layer provides a transparent, anti-reflective, conductive, chemically stable, inherently catalytic coating that stabilizes many efficient and technologically important

  9. Solid State eBurner for Supplying Power to Laptops, Cellphones - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovation Portal Industrial Technologies Industrial Technologies Electricity Transmission Electricity Transmission Find More Like This Return to Search Solid State eBurner for Supplying Power to Laptops, Cellphones Oak Ridge National Laboratory Contact ORNL About This Technology Electrons from the hot Pt nanoparticles are emitted over the oxide conduction band (CB<sub>ox</sub>) barrier into the cold semiconductor to produce power. Electrons from the hot Pt nanoparticles are

  10. Cyclopentadienyl-bis(oxazoline) magnesium and zirconium complexes in aminoalkene hydroaminations

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Eedugurala, Naresh; Hovey, Megan; Ho, Hung -An; Jana, Barun; Lampland, Nicole L.; Ellern, Arkady; Sadow, Aaron D.

    2015-11-25

    Here, a new class of cyclopentadiene-bis(oxazoline) compounds and their piano-stool-type organometallic complexes have been prepared as catalysts for hydroamination of aminoalkenes. The two compounds MeC(OxMe2)2C5H5 (BoMCpH; OxMe2 = 4,4-dimethyl-2-oxazoline) and MeC(OxMe2)2C5Me4H (BoMCptetH) are synthesized from C5R4HI (R = H, Me) and MeC(OxMe2)2Li. These cyclopentadiene-bis(oxazolines) are converted into ligands that support a variety of metal centers in piano-stool-type geometries, and here we report the preparation of Mg, Tl, Ti, and Zr compounds. BoMCpH and BoMCptetH react with MgMe2(O2C4H8)2 to give the magnesium methyl complexes {BoMCp}MgMe and {BoMCptet}MgMe. BoMCpH and BoMCptetH are converted to BoMCpTl and BoMCptetTl by reaction with TlOEt. Themore » thallium derivatives react with TiCl3(THF)3 to provide [{BoMCp}TiCl(μ-Cl)]2 and [{BoMCptet}TiCl(μ-Cl)]2, the former of which is crystallographically characterized as a dimeric species. BoMCpH and Zr(NMe2)4 react to eliminate dimethylamine and afford {BoMCp}Zr(NMe2)3, which is crystallographically characterized as a monomeric four-legged piano-stool compound. {BoMCp}Zr(NMe2)3, {BoMCp}MgMe, and {BoMCptet}MgMe are efficient catalysts for the hydroamination/cyclization of aminoalkenes under mild conditions.« less

  11. High Temperature Strength of YSZ Joints Brazed with Palladium Silver Copper Oxide Filler Metals

    SciTech Connect (OSTI)

    Darsell, Jens T.; Weil, K. Scott

    2010-06-09

    The Ag-CuOx system is being investigated as potential filler metals for use in air brazing high-temperature electrochemical devices such as solid oxide fuel cells and gas concentrators. The current study examines the effects of palladium addition on the high temperature joint strength of specimens prepared from yttria stabilized zirconia (YSZ) bars brazed with the binary Ag-CuOx, and 15Pd-Ag-CuO. It was found that while the binary Ag-CuOx system exhibits stronger room temperature strength than the 15Pd system the strength is reduced to values equivalent of the 15Pd system at 800°C. The 15Pd system exhibits a lower ambient temperature strength that is retained at 800°C. In both systems the failure mechanism at high temperature appears to be peeling of the noble metal component from the oxide phases and tearing through the noble metal phase whereas sufficient adhesion is retained at lower temperatures to cause fracture of the YSZ substrate.

  12. Introducing improved structural properties and salt dependence into a coarse-grained model of DNA

    SciTech Connect (OSTI)

    Snodin, Benedict E. K. Mosayebi, Majid; Schreck, John S.; Romano, Flavio; Doye, Jonathan P. K.; Randisi, Ferdinando; Šulc, Petr; Ouldridge, Thomas E.; Tsukanov, Roman; Nir, Eyal; Louis, Ard A.

    2015-06-21

    We introduce an extended version of oxDNA, a coarse-grained model of deoxyribonucleic acid (DNA) designed to capture the thermodynamic, structural, and mechanical properties of single- and double-stranded DNA. By including explicit major and minor grooves and by slightly modifying the coaxial stacking and backbone-backbone interactions, we improve the ability of the model to treat large (kilobase-pair) structures, such as DNA origami, which are sensitive to these geometric features. Further, we extend the model, which was previously parameterised to just one salt concentration ([Na{sup +}] = 0.5M), so that it can be used for a range of salt concentrations including those corresponding to physiological conditions. Finally, we use new experimental data to parameterise the oxDNA potential so that consecutive adenine bases stack with a different strength to consecutive thymine bases, a feature which allows a more accurate treatment of systems where the flexibility of single-stranded regions is important. We illustrate the new possibilities opened up by the updated model, oxDNA2, by presenting results from simulations of the structure of large DNA objects and by using the model to investigate some salt-dependent properties of DNA.

  13. Role of precursor chemistry in the direct fluorination to form titanium based conversion anodes for lithium ion batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Adcock, Jamie; Dai, Sheng; Veith, Gabriel M.; Bridges, Craig A.; Powell, Jonathan M.

    2015-10-13

    In this study, a new synthetic route for the formation of titanium oxydifluoride (TiOF2) through the process of direct fluorination via a fluidized bed reactor system and the associated electrochemical properties of the powders formed from this approach are reported. The flexibility of this synthetic route was demonstrated using precursor powders of titanium dioxide (TiO2) nanoparticles, as well as a reduced TiOxNy. An advantage of this synthetic method is the ability to directly control the extent of fluorination as a function of reaction temperature and time. The reversible capacity of TiOF2 anodes was found to depend greatly upon the precursormore » employed. The TiOF2 synthesized from TiO2 and TiOxNy showed reversible capacities of 300 mAh g-1 and 440 mAh g-1, respectively, over 100 cycles. The higher reversible capacity of the TiOF2 powders derived from TiOxNy likely relate to the partial reduction of the Ti in the fluorinated electrode material, highlighting a route to optimize the properties of conversion electrode materials.« less

  14. Hydrogenation of CO2 to methanol: Importance of metal–oxide and metal–carbide interfaces in the activation of CO2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rodriguez, José A.; Liu, Ping; Stacchiola, Dario J.; Senanayake, Sanjaya D.; White, Michael G.; Chen, Jingguang G.

    2015-09-30

    In this study, the high thermochemical stability of CO2 makes it very difficult to achieve the catalytic conversion of the molecule into alcohols or other hydrocarbon compounds, which can be used as fuels or the starting point for the generation of fine chemicals. Pure metals and bimetallic systems used for the CO2 → CH3OH conversion usually bind CO2 too weakly and, thus, show low catalytic activity. Here, we discuss a series of recent studies that illustrate the advantages of metal–oxide and metal–carbide interfaces when aiming at the conversion of CO2 into methanol. CeOx/Cu(111), Cu/CeOx/TiO2(110), and Au/CeOx/TiO2(110) exhibit an activity formore » the CO2 → CH3OH conversion that is 2–3 orders of magnitude higher than that of a benchmark Cu(111) catalyst. In the Cu–ceria and Au–ceria interfaces, the multifunctional combination of metal and oxide centers leads to complementary chemical properties that open active reaction pathways for methanol synthesis. Efficient catalysts are also generated after depositing Cu and Au on TiC(001). In these cases, strong metal–support interactions modify the electronic properties of the admetals and make them active for the binding of CO2 and its subsequent transformation into CH3OH at the metal–carbide interfaces.« less

  15. Development and characterization of a hydrogen peroxide-resistant cholangiocyte cell line: A novel model of oxidative stress-related cholangiocarcinoma genesis

    SciTech Connect (OSTI)

    Thanan, Raynoo; Techasen, Anchalee; Hou, Bo; Jamnongkan, Wassana; Armartmuntree, Napat; Yongvanit, Puangrat; Murata, Mariko

    2015-08-14

    Oxidative stress is a cause of inflammation–related diseases, including cancers. Cholangiocarcinoma is a liver cancer with bile duct epithelial cell phenotypes. Our previous studies in animal and human models indicated that oxidative stress is a major cause of cholangiocarcinoma development. Hydrogen peroxide (H{sub 2}O{sub 2}) can generate hydroxyl radicals, which damage lipids, proteins, and nucleic acids, leading to cell death. However, some cells can survive by adapting to oxidative stress conditions, and selective clonal expansion of these resistant cells would be involved in oxidative stress-related carcinogenesis. The present study aimed to establish H{sub 2}O{sub 2}-resistant cell line from an immortal cholangiocyte cell line (MMNK1) by chronic treatment with low-concentration H{sub 2}O{sub 2} (25 μM). After 72 days of induction, H{sub 2}O{sub 2}-resistant cell lines (ox-MMNK1-L) were obtained. The ox-MMNK1-L cell line showed H{sub 2}O{sub 2}-resistant properties, increasing the expression of the anti-oxidant genes catalase (CAT), superoxide dismutase-1 (SOD1), superoxide dismutase-2 (SOD2), and superoxide dismutase-3 (SOD3) and the enzyme activities of CAT and intracellular SODs. Furthermore, the resistant cells showed increased expression levels of an epigenetics-related gene, DNA methyltransferase-1 (DNMT1), when compared to the parental cells. Interestingly, the ox-MMNK1-L cell line had a significantly higher cell proliferation rate than the MMNK1 normal cell line. Moreover, ox-MMNK1-L cells showed pseudopodia formation and the loss of cell-to-cell adhesion (multi-layers) under additional oxidative stress (100 μM H{sub 2}O{sub 2}). These findings suggest that H{sub 2}O{sub 2}-resistant cells can be used as a model of oxidative stress-related cholangiocarcinoma genesis through molecular changes such as alteration of gene expression and epigenetic changes. - Highlights: • An H{sub 2}O{sub 2}-resistant ox-MMNK1-L cells was established from immortalized cholangiocytes. • The resistance was acquired by daily treatment of low H{sub 2}O{sub 2} (25 μM) for 15 passages. • The cells highly expressed catalase, SODs and DNMT1 with rapid cell proliferation. • Pseudopodia and the loss of cell-to-cell adhesion appeared by 100 μM H{sub 2}O{sub 2} treatment. • The resistant cells can be used as a model of oxidative stress-related carcinogenesis.

  16. Omega-3 fatty acid oxidation products prevent vascular endothelial cell activation by coplanar polychlorinated biphenyls

    SciTech Connect (OSTI)

    Majkova, Zuzana; Layne, Joseph; Sunkara, Manjula; Morris, Andrew J.; Toborek, Michal; Hennig, Bernhard

    2011-02-15

    Coplanar polychlorinated biphenyls (PCBs) may facilitate development of atherosclerosis by stimulating pro-inflammatory pathways in the vascular endothelium. Nutrition, including fish oil-derived long-chain omega-3 fatty acids, such as docosahexaenoic acid (DHA, 22:6{omega}-3), can reduce inflammation and thus the risk of atherosclerosis. We tested the hypothesis that cyclopentenone metabolites produced by oxidation of DHA can protect against PCB-induced endothelial cell dysfunction. Oxidized DHA (oxDHA) was prepared by incubation of the fatty acid with the free radical generator 2,2-azo-bis(2-amidinopropane) dihydrochloride (AAPH). Cellular pretreatment with oxDHA prevented production of superoxide induced by PCB77, and subsequent activation of nuclear factor-{kappa}B (NF-{kappa}B). A{sub 4}/J{sub 4}-neuroprostanes (NPs) were identified and quantitated using HPLC ESI tandem mass spectrometry. Levels of these NPs were markedly increased after DHA oxidation with AAPH. The protective actions of oxDHA were reversed by treatment with sodium borohydride (NaBH{sub 4}), which concurrently abrogated A{sub 4}/J{sub 4}-NP formation. Up-regulation of monocyte chemoattractant protein-1 (MCP-1) by PCB77 was markedly reduced by oxDHA, but not by un-oxidized DHA. These protective effects were proportional to the abundance of A{sub 4}/J{sub 4} NPs in the oxidized DHA sample. Treatment of cells with oxidized eicosapentaenoic acid (EPA, 20:5{omega}-3) also reduced MCP-1 expression, but less than oxDHA. Treatment with DHA-derived cyclopentenones also increased DNA binding of NF-E2-related factor-2 (Nrf2) and downstream expression of NAD(P)H:quinone oxidoreductase (NQO1), similarly to the Nrf-2 activator sulforaphane. Furthermore, sulforaphane prevented PCB77-induced MCP-1 expression, suggesting that activation of Nrf-2 mediates the observed protection against PCB77 toxicity. Our data implicate A{sub 4}/J{sub 4}-NPs as mediators of omega-3 fatty acid-mediated protection against the endothelial toxicity of coplanar PCBs.

  17. Fe/SSZ-13 as an NH3-SCR Catalyst: A Reaction Kinetics and FTIR/Mössbauer Spectroscopic Study

    SciTech Connect (OSTI)

    Gao, Feng; Kollar, Marton; Kukkadapu, Ravi K.; Washton, Nancy M.; Wang, Yilin; Szanyi, Janos; Peden, Charles H.F.

    2015-03-01

    Using a traditional aqueous solution ion-exchange method under a protecting atmosphere of N2, an Fe/SSZ-13 catalyst active in NH3-SCR was synthesized. Mössbauer and FTIR spectroscopies were used to probe the nature of the Fe sites. In the fresh sample, the majority of Fe species are extra-framework cations. The likely monomeric and dimeric ferric ions in hydrated form are [Fe(OH)2]+ and [HO-Fe-O-Fe-OH]2+, based on Mössbauer measurements. During the severe hydrothermal aging (HTA) applied in this study, a majority of cationic Fe species convert to FeAlOx and clustered FeOx species, accompanied by severe dealumination of the SSZ-13 framework. The clustered FeOx species do not give a sextet Mössbauer spectrum, indicating that these are highly disordered. However, some Fe species in cationic positions remain after aging as determined from Mössbauer measurements and CO/NO FTIR titrations. NO/NH3 oxidation reaction tests reveal that dehydrated cationic Fe are substantially more active in catalyzing oxidation reactions than the hydrated ones. For NH3-SCR, enhancement of NO oxidation under ‘dry’ conditions promotes SCR rates below ~300 • C. This is due mainly to contribution from the “fast” SCR channel. Above ~300 • C, enhancement of NH3 oxidation under ‘dry’ conditions, however, becomes detrimental to NOx conversions. The HTA sample loses much of the SCR activity below ~300 • C; however, above ~400 • C much of the activity remains. This may suggest that the FeAlOx and FeOx species become active at such elevated temperatures. Alternatively, the high-temperature activity may be maintained by the remaining extra-framework cationic species. For potential practical applications, Fe/SSZ-13 may be used as a co-catalyst for Cu/CHA as integral aftertreatment SCR catalysts on the basis of the stable high temperature activity after hydrothermal aging. The authors gratefully acknowledge the US Department of Energy (DOE), Energy Efficiency and Renewable Energy, Vehicle Technologies Office for the support of this work. The research described in this paper was performed at the Environmental Molecular Sciences Laboratory (EMSL), a national scientific user facility sponsored by the DOE’s Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory (PNNL). PNNL is operated for the US DOE by Battelle.

  18. The Dark Energy Survey: More than dark energy - An overview

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Abbott, T.

    2016-03-21

    This overview article describes the legacy prospect and discovery potential of the Dark Energy Survey (DES) beyond cosmological studies, illustrating it with examples from the DES early data. DES is using a wide-field camera (DECam) on the 4m Blanco Telescope in Chile to image 5000 sq deg of the sky in five filters (grizY). By its completion the survey is expected to have generated a catalogue of 300 million galaxies with photometric redshifts and 100 million stars. In addition, a time-domain survey search over 27 sq deg is expected to yield a sample of thousands of Type Ia supernovae andmore » other transients. The main goals of DES are to characterise dark energy and dark matter, and to test alternative models of gravity; these goals will be pursued by studying large scale structure, cluster counts, weak gravitational lensing and Type Ia supernovae. However, DES also provides a rich data set which allows us to study many other aspects of astrophysics. In this paper we focus on additional science with DES, emphasizing areas where the survey makes a difference with respect to other current surveys. The paper illustrates, using early data (from `Science Verification', and from the first, second and third seasons of observations), what DES can tell us about the solar system, the Milky Way, galaxy evolution, quasars, and other topics. In addition, we show that if the cosmological model is assumed to be Lambda+ Cold Dark Matter (LCDM) then important astrophysics can be deduced from the primary DES probes. Lastly, highlights from DES early data include the discovery of 34 Trans Neptunian Objects, 17 dwarf satellites of the Milky Way, one published z > 6 quasar (and more confirmed) and two published superluminous supernovae (and more confirmed).« less

  19. Mutual Insurance Company of West

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Step : On the right side of the homepage under "Identity The Protection," click on "Create Member Account." Once you log in, create an additional username and password to For more information call - - or visit ARAGLegalCenter.com. Limitations and exclusions apply. Insurance products are underwritten by ARAG Insurance Company of Des Moines, Iowa, GuideOne ® Mutual Insurance Company of West Des Moines, Iowa or GuideOne Specialty Mutual Insurance Company of West Des Moines,

  20. Two-dimensional electron gas in monolayer InN quantum wells

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Pan, Wei; Dimakis, Emmanouil; Wang, George T.; Moustakas, Theodore D.; Tsui, Daniel C.

    2014-11-24

    We report in this letter experimental results that confirm the two-dimensional nature of the electron systems in monolayer InN quantum wells embedded in GaN barriers. The electron density and mobility of the two-dimensional electron system (2DES) in these InN quantum wells are 5×1015 cm-2 and 420 cm2 /Vs, respectively. Moreover, the diagonal resistance of the 2DES shows virtually no temperature dependence in a wide temperature range, indicating the topological nature of the 2DES.

  1. Mass map shines light on dark matter | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mass map shines light on dark matter By Sarah Schlieder * July 9, 2015 Tweet EmailPrint Dark matter may find it tougher to hide in our universe. An international team of researchers has developed a new map of the distribution of dark matter in the universe using data from the Dark Energy Survey (DES). The DES, underway at the Blanco telescope in Chile, is a cosmological galaxy survey that will map approximately an eighth of the visible sky. The primary aim of the DES is to better characterize

  2. Colloquy Niels Bohr

    ScienceCinema (OSTI)

    None

    2011-04-25

    Célébration du 100me anniversaire de Niels Bohr (1885 - 1962), un des fondateurs de la physique moderne. Plusieurs orateurs parlent de cet homme et le développement de la physique

  3. Science and Society-Consequences of engineering

    ScienceCinema (OSTI)

    None

    2011-04-25

    Le conférencier Mons.Rorsch parle des possibles conséquences économiques et culturelles de la technologie en générale, aussi pour l'environnement

  4. Mutual Insurance Company of West

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    call 800-247-4184 or visit ARAGLegalCenter.com. Limitations and exclusions apply. Insurance products are underwritten by ARAG Insurance Company of Des Moines, Iowa, GuideOne ...

  5. Iowa Community College Campuses Reduce Energy Use

    Broader source: Energy.gov [DOE]

    Des Moines Area Community College (DMACC) serves more than 65,000 Iowans on six campuses, making it the largest two-year college in the state of Iowa.

  6. CX-003877: Categorical Exclusion Determination

    Office of Energy Efficiency and Renewable Energy (EERE)

    Hybrid Membrane/Absorption Process for Post-Combustion Carbon Dioxide CaptureCX(s) Applied: B3.6Date: 09/10/2010Location(s): Des Plaines, IllinoisOffice(s): Fossil Energy, National Energy Technology Laboratory

  7. Improving the Field Performance of Natural Gas Furnaces, Chicago...

    Energy Savers [EERE]

    ... DEsCRIPTION Tune the gas valve to set the firing rate at installation. Adjust the airflow ... best installed performance. * Set the gas valve on the labeled input rate. * Adjust the ...

  8. Renewable Energy Research | Open Energy Information

    Open Energy Info (EERE)

    Research Jump to: navigation, search Name: Renewable Energy Research Address: 2113 C Boulevard St Regis Place: Dollard des Ormeaux Zip: H9B 2M9 Region: Canada Sector: Marine and...

  9. CX-000339: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Chicago Area Alternative Fuel Deployment ProjectCX(s) Applied: A1, A9Date: 12/10/2009Location(s): Des Plaines, IllinoisOffice(s): Energy Efficiency and Renewable Energy, National Energy Technology Laboratory

  10. L2:THM.P4.01 Rob Lowrie LANL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... large-eddy simulation (ILES), detached-eddy simulation (DES), and Spalart-Allmaras (SA). ... Table 7: Averaged time-step based on a fixed-CFL number used for the SA calculations. ...

  11. Category:SmallHotel | Open Energy Information

    Open Energy Info (EERE)

    Cleveland OH Ohio Power Co.png SVSmallHotel Cleveland... 68 KB SVSmallHotel Concord NH Public Service Co of NH.png SVSmallHotel Concord N... 71 KB SVSmallHotel Des Moines IA...

  12. Senior Staff Meeting

    ScienceCinema (OSTI)

    None

    2011-04-25

    Le DG C.Rubbia informe sur les négociations avec le personnel, les discussions avec le conseil d'administration et le budget, suivi des questions

  13. DG's Meeting

    ScienceCinema (OSTI)

    None

    2011-04-25

    Exposés du DG H.Schopper, Blackburne et du président du comité des finances concernant le budget, salaires, pensions etc...avec discussion et questions

  14. Eyes Witness Report on South Vietnam

    ScienceCinema (OSTI)

    None

    2011-04-25

    Mons. Nielson, conseiller des Etats Unis auprès de L'ONU, apporte son témoignage et exprime son opinion quand à la guerre du Vietnam (Sud)

  15. West Burlington, Iowa: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Hide Map This article is a stub. You can help OpenEI by expanding it. West Burlington is a city in Des Moines County, Iowa. It falls under Iowa's 2nd...

  16. Multinational societies and syndicates

    ScienceCinema (OSTI)

    None

    2011-04-25

    Monsieur Charles Levinson, par la longue expérience qu'il a acquise au contact des sociétés multinationales et syndicats, nous en parle ce soir

  17. Pilot-Scale Biorefinery: Sustainable Transport Fuels from Biomass...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    coprocessing of pyrolysis oil (pyoil) in an FCC unit * Summer 2014, RTP unit restarted with plans to run UG1 at Kapolei and complete UG2 in UOP pilot plant in Des Plaines, IL * ...

  18. Churches and Apartheid

    SciTech Connect (OSTI)

    2006-01-16

    Lucas Vischer fait parti du concile mondial des églises et nous parle d'eglises et d'apartheid en Afrique du Sud et se pose la question d'un changement sans violence.....

  19. CX-004285: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Indigo Dawn Green and Main Street ProjectCX(s) Applied: A9, B5.1Date: 10/20/2010Location(s): Des Moines, IowaOffice(s): Energy Efficiency and Renewable Energy, Golden Field Office

  20. CX-004386: Categorical Exclusion Determination

    Office of Energy Efficiency and Renewable Energy (EERE)

    Chicago Area Alternative Fuels Deployment ProjectCX(s) Applied: B5.1Date: 11/04/2010Location(s): Des Plaines, IllinoisOffice(s): Energy Efficiency and Renewable Energy, National Energy Technology Laboratory

  1. Fermilab Today

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Russia. Read more Frontier Science Result: DES The Dark Energy Survey looks at massive galaxy clusters - and finds filaments With data from the new DECam imager, the Dark Energy...

  2. Meditation and Reality

    ScienceCinema (OSTI)

    None

    2011-04-25

    A.Sujata demande dans son exposé entre autre à ceux/celles des auditeurs/trices qui sont heureux/ses, de lever la main.....qu'est le bonheur?

  3. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... data from X-ray to GeV, within the systematic uncertainties in the EGRB determination ... Transitional change in rat fetal cell proliferation in response to ghrelin and des-acyl ...

  4. Electricity Advisory Committee Meeting Presentations June 2014...

    Office of Environmental Management (EM)

    Tuesday, June 17, 2014 Panel - Distributed Energy Storage (DES) - Wanda Reder, S&C, moderator Willem Fadrhonc, STEM Tom Weaver, AEP Melicia Charles, CPUC Tom Bialek, SDG&E Panel - ...

  5. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... In particular, we examine how optical photometry in the DES grizY bands can be complemented with near infra-red photometry from the planned VISTA Hemisphere Survey (VHS) in the ...

  6. Churches and Apartheid

    ScienceCinema (OSTI)

    None

    2011-04-25

    Lucas Vischer fait parti du concile mondial des églises et nous parle d'eglises et d'apartheid en Afrique du Sud et se pose la question d'un changement sans violence.....

  7. Information Meeting- Education

    ScienceCinema (OSTI)

    None

    2011-04-25

    Suite à un circulaire, Messieurs Goldschmidt et Ullmann donnent plus d'information et attendent des questions/réponses concernant les problèmes d'éducation d'enfants

  8. Expo NL inauguration

    ScienceCinema (OSTI)

    None

    2011-04-25

    Le DG H.Schopper souhaite la bienvenue à toutes les personnes présentes. Plusieurs discours à l'occasion de l'inauguration officielle de l'expo des Pays-Bas.

  9. HyRadix Inc | Open Energy Information

    Open Energy Info (EERE)

    search Name: HyRadix Inc Place: Des Plaines,, Illinois Zip: IL 60018-1 Sector: Hydro, Hydrogen Product: The company aims to develop and supply small-scale hydrogen generation...

  10. Inauguration SC

    ScienceCinema (OSTI)

    None

    2011-04-25

    Le DG W.Jentschke ouvre l'inauguration du Syncro Cyclotron (8') et remercie Mons. Michaelis qui prend la parole (30') avant Mons. Wilkinson (53') qui parle du futur de la machine avec présentation des dias.

  11. Gestational exposure to diethylstilbestrol alters cardiac structure/function, protein expression and DNA methylation in adult male mice progeny

    SciTech Connect (OSTI)

    Haddad, Rami, E-mail: rami.haddad@mail.mcgill.ca [Lady Davis Institute for Medical Research, Jewish General Hospital, 3755 chemin Cote Ste Catherine, Montréal, Québec, Canada H3T 1E2 (Canada) [Lady Davis Institute for Medical Research, Jewish General Hospital, 3755 chemin Cote Ste Catherine, Montréal, Québec, Canada H3T 1E2 (Canada); Division of Experimental Medicine, Department of Medicine, McGill University, 850 Sherbrooke Street, Montréal, Québec, Canada H3A 1A2 (Canada); Kasneci, Amanda, E-mail: amanda.kasneci@mail.mcgill.ca [Lady Davis Institute for Medical Research, Jewish General Hospital, 3755 chemin Cote Ste Catherine, Montréal, Québec, Canada H3T 1E2 (Canada)] [Lady Davis Institute for Medical Research, Jewish General Hospital, 3755 chemin Cote Ste Catherine, Montréal, Québec, Canada H3T 1E2 (Canada); Mepham, Kathryn, E-mail: katherine.mepham@mail.mcgill.ca [Lady Davis Institute for Medical Research, Jewish General Hospital, 3755 chemin Cote Ste Catherine, Montréal, Québec, Canada H3T 1E2 (Canada) [Lady Davis Institute for Medical Research, Jewish General Hospital, 3755 chemin Cote Ste Catherine, Montréal, Québec, Canada H3T 1E2 (Canada); Division of Experimental Medicine, Department of Medicine, McGill University, 850 Sherbrooke Street, Montréal, Québec, Canada H3A 1A2 (Canada); Sebag, Igal A., E-mail: igal.sebag@mcgill.ca [Division of Cardiology, Jewish General Hospital, 3755 chemin Cote Ste Catherine, Montréal, Québec, Canada H3T 1E2 (Canada); and others

    2013-01-01

    Pregnant women, and thus their fetuses, are exposed to many endocrine disruptor compounds (EDCs). Fetal cardiomyocytes express sex hormone receptors making them potentially susceptible to re-programming by estrogenizing EDCs. Diethylstilbestrol (DES) is a proto-typical, non-steroidal estrogen. We hypothesized that changes in adult cardiac structure/function after gestational exposure to the test compound DES would be a proof in principle for the possibility of estrogenizing environmental EDCs to also alter the fetal heart. Vehicle (peanut oil) or DES (0.1, 1.0 and 10.0 ?g/kg/da.) was orally delivered to pregnant C57bl/6n dams on gestation days 11.5–14.5. At 3 months, male progeny were left sedentary or were swim trained for 4 weeks. Echocardiography of isoflurane anesthetized mice revealed similar cardiac structure/function in all sedentary mice, but evidence of systolic dysfunction and increased diastolic relaxation after swim training at higher DES doses. The calcium homeostasis proteins, SERCA2a, phospholamban, phospho-serine 16 phospholamban and calsequestrin 2, are important for cardiac contraction and relaxation. Immunoblot analyses of ventricle homogenates showed increased expression of SERCA2a and calsequestrin 2 in DES mice and greater molecular remodeling of these proteins and phospho-serine 16 phospholamban in swim trained DES mice. DES increased cardiac DNA methyltransferase 3a expression and DNA methylation in the CpG island within the calsequestrin 2 promoter in heart. Thus, gestational DES epigenetically altered ventricular DNA, altered cardiac function and expression, and reduced the ability of adult progeny to cardiac remodel when physically challenged. We conclude that gestational exposure to estrogenizing EDCs may impact cardiac structure/function in adult males. -- Highlights: ? Gestational DES changes cardiac SERCA2a and CASQ2 expression. ? Echocardiography identified systolic dysfunction and increased diastolic relaxation. ? DES increased DNMT3a expression and increased CpG DNA methylation. ? DES impacts fetal heart reducing cardiac reserve on challenge in adulthood. ? Fetal heart can be re-programmed by a non-steroidal estrogen.

  12. Transition metal complexes of oxazolinylboranes and cyclopentadienyl-bis(oxazolinyl)borates: Catalysts for asymmetric olefin hydroamination and acceptorless alcohol decarbonylation

    SciTech Connect (OSTI)

    Manna, Kuntal [Ames Laboratory

    2012-12-17

    The research presented and discussed in this dissertation involves the synthesis of transition metal complexes of oxazolinylboranes and cyclopentadienyl-bis(oxazolinyl)borates, and their application in catalytic enantioselective olefin hydroamination and acceptorless alcohol decarbonylation. Neutral oxazolinylboranes are excellent synthetic intermediates for preparing new borate ligands and also developing organometallic complexes. Achiral and optically active bis(oxazolinyl)phenylboranes are synthesized by reaction of 2-lithio-2-oxazolide and 0.50 equiv of dichlorophenylborane. These bis(oxazolinyl)phenylboranes are oligomeric species in solid state resulting from the coordination of an oxazoline to the boron center of another borane monomer. The treatment of chiral bis(oxazolinyl)phenylboranes with sodium cyclopentadienide provide optically active cyclopentadienyl-bis(oxazolinyl)borates H[PhB(C{sub 5}H{sub 5})(Ox{sup R}){sub 2}] [Ox{sup R} = Ox{sup 4S-iPr,Me2}, Ox{sup 4R-iPr,Me2}, Ox{sup 4S-tBu]}. These optically active proligands react with an equivalent of M(NMe{sub 2}){sub 4} (M = Ti, Zr, Hf) to afford corresponding cyclopentadienyl-bis(oxazolinyl)borato group 4 complexes {PhB(C{sub 5}H{sub 4})(Ox{sup R}){sub 2}}M(NMe{sub 2}){sub 2} in high yields. These group 4 compounds catalyze cyclization of aminoalkenes at room temperature or below, providing pyrrolidine, piperidine, and azepane with enantiomeric excesses up to 99%. Our mechanistic investigations suggest a non-insertive mechanism involving concerted C?N/C?H bond formation in the turnover limiting step of the catalytic cycle. Among cyclopentadienyl-bis(oxazolinyl)borato group 4 catalysts, the zirconium complex {PhB(C{sub 5}H{sub 4})(Ox{sup 4S-iPr,Me2}){sub 2}}Zr(NMe{sub 2}){sub 2} ({S-2}Zr(NMe{sub 2}){sub 2}) displays highest activity and enantioselectivity. Interestingly, {S-2}Zr(NMe{sub 2}){sub 2} also desymmetrizes olefin moieties of achiral non-conjugated aminodienes and aminodiynes during cyclization. The cyclization of aminodienes catalyzed by {S-2}Zr(NMe{sub 2}){sub 2} affords diastereomeric mixture of cis and trans cylic amines with high diasteromeric ratios and excellent enantiomeric excesses. Similarly, the desymmetrization of alkyne moieties in {S-2}Zr(NMe{sub 2}){sub 2}-catalyzed cyclization of aminodiynes provides corresponding cyclic imines bearing quaternary stereocenters with enantiomeric excesses up to 93%. These stereoselective desymmetrization reactions are significantly affected by concentration of the substrate, temperature, and the presence of a noncyclizable primary amine. In addition, both the diastereomeric ratios and enantiomeric excesses of the products are markedly enhanced by N-deuteration of the substrates. Notably, the cationic zirconium-monoamide complex [{S-2}Zr(NMe{sub 2})][B(C{sub 6}F{sub 5}){sub 4}] obtained from neutral {S-2}Zr(NMe{sub 2}){sub 2} cyclizes primary aminopentenes providing pyrrolidines with S-configuration; whereas {S-2}Zr(NMe{sub 2}){sub 2} provides R-configured pyrrolidines. The yttrium complex {S-2}YCH{sub 2}SiMe{sub 3} also affords S-configured pyrrolidines by cyclization of aminopentenes, however the enantiomeric excesses of products are low. An alternative optically active yttrium complex {PhB(C{sub 5}H{sub 4})(Ox{sup 4S-tBu}){sub 2}}YCH{sub 2}SiMe{sub 3} ({S-3}YCH{sub 2}SiMe{sub 3}) is synthesized, which displays highly enantioselective in the cyclization of aminoalkenes at room temperature affording S-configured cyclic amines with enantiomeric excesses up to 96%. A noninsertive mechanism involving a six-membered transition state by a concerted C?N bond formation and N?H bond cleavage is proposed for {S-3}YCH{sub 2}SiMe{sub 3} system based on the kinetic, spectroscopic, and stereochemical features. In the end, a series of bis- and tris(oxazolinyl)borato iridium and rhodium complexes are synthesized with bis(oxazolinyl)phenylborane [PhB(Ox{sup Me2}){sub 2}]{sub n}, tris(oxazolinyl)borane [B(Ox{sup Me2}){sub 3}]n, and tris(4,4-dimethyl-2-oxazolinyl)phenylborate [To{sup M}]{sup ?}. All these new an

  13. Energy secretary: U.S. must be energy independent | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy secretary: U.S. must be energy independent Des Moines Register business - ag, environment, energy reporter Donnelle Eller wrote a story about Energy Secretary Ernest Moniz's appearance Friday morning in Des Moines for a public forum on energy policies, electric markets and the grid. Moniz talked about ethanol, wind and other aspects of energy policy. News Link: Energy secretary: U.S. must be energy independent

  14. Discovery of two gravitationally lensed quasars in the Dark Energy Survey

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Agnello, A.

    2015-10-01

    In this study, we present spectroscopic confirmation of two new lensed quasars via data obtained at the 6.5m Magellan/Baade Telescope. The lens candidates have been selected from the Dark Energy Survey (DES) and WISE based on their multi-band photometry and extended morphology in DES images. Images of DES J0115-5244 show two blue point sources at either side of a red galaxy. Our long-slit data confirm that both point sources are images of the same quasar at zs = 1.64. The Einstein Radius estimated from the DES images is 0.51''. DES J2146-0047 is in the area of overlap between DES andmore » the Sloan Digital Sky Survey (SDSS). Two blue components are visible in the DES and SDSS images. The SDSS fiber spectrum shows a quasar component at zs = 2.38 and absorption compatible with Mg II and Fe II at zl = 0.799, which we tentatively associate with the foreground lens galaxy. The long-slit Magellan spectra show that the blue components are resolved images of the same quasar. Furthermore, the Einstein Radius is 0.68'' corresponding to an enclosed mass of 1.6 × 1011 M⊙. Three other candidates were observed and rejected, two being low-redshift pairs of starburst galaxies, and one being a quasar behind a blue star. These first confirmation results provide an important empirical validation of the data-mining and model-based selection that is being applied to the entire DES dataset.« less

  15. Senior Staff Meeting

    ScienceCinema (OSTI)

    None

    2011-04-25

    Herbert Lengler fait l'introduction et remercie le DG, les directeurs et le vice président de l'association du personnel pour leur présence. Il parlera des activités depuis la dernière réunion et fera des commentaires sur l'"Abragam Commitee Final Report". Une discussion suivra sur plusieurs points importants.

  16. Personnel

    ScienceCinema (OSTI)

    None

    2011-04-25

    Le président du conseil M.Doran explique la décision que le conseil du Cern vient de prendre sur la 4.étape du régime complémentaire des pensions. Le président du comité des finances le Dr.Andersen ainsi que le Prof.Connor(?) prennent aussi la parole

  17. Discovery of two gravitationally lensed quasars in the Dark Energy Survey

    SciTech Connect (OSTI)

    Agnello, A.

    2015-10-01

    In this study, we present spectroscopic confirmation of two new lensed quasars via data obtained at the 6.5m Magellan/Baade Telescope. The lens candidates have been selected from the Dark Energy Survey (DES) and WISE based on their multi-band photometry and extended morphology in DES images. Images of DES J0115-5244 show two blue point sources at either side of a red galaxy. Our long-slit data confirm that both point sources are images of the same quasar at zs = 1.64. The Einstein Radius estimated from the DES images is 0.51''. DES J2146-0047 is in the area of overlap between DES and the Sloan Digital Sky Survey (SDSS). Two blue components are visible in the DES and SDSS images. The SDSS fiber spectrum shows a quasar component at zs = 2.38 and absorption compatible with Mg II and Fe II at zl = 0.799, which we tentatively associate with the foreground lens galaxy. The long-slit Magellan spectra show that the blue components are resolved images of the same quasar. Furthermore, the Einstein Radius is 0.68'' corresponding to an enclosed mass of 1.6 × 1011 M?. Three other candidates were observed and rejected, two being low-redshift pairs of starburst galaxies, and one being a quasar behind a blue star. These first confirmation results provide an important empirical validation of the data-mining and model-based selection that is being applied to the entire DES dataset.

  18. An improved thermodynamic model for the complexation of trivalent actinides and lanthanide with oxalic acid valid to high ionic strength.

    SciTech Connect (OSTI)

    Xiong, Yongliang; Thakur, Punam; Borkowski, Marian

    2015-07-30

    The dissociation constants of oxalic acid (Ox), and the stability constants of Am3+, Cm3+ and Eu3+ with Ox2– have been determined at 25 °C, over a range of concentration varying from 0.1 to 6.60 m NaClO4 using potentiometric titration and extraction techniques, respectively. The experimental data support the formation of complexes, M(Ox)n3 – 2n, where (M = Am3+, Cm3+ and Eu3+ and n = 1 and 2). The dissociation constant and the stability constant values measured as a function of NaClO4 concentration were used to estimate the Pitzer parameters for the respective interactions of Am3+, Cm3+ and Eu3+ with Ox. Furthermore, the stability constants data of Am3+ –Ox measured in NaClO4 and in NaCl solutions from the literature were simultaneously fitted in order to refine the existing actinide–oxalate complexation model that can be used universally in the safety assessment of radioactive waste disposal. The thermodynamic stability constant: log β0101 = 6.30 ± 0.06 and log β0102 = 10.84 ± 0.06 for Am3+ was obtained by simultaneously fitting data in NaCl and NaClO4 media. Additionally, log β0101 = 6.72 ± 0.08 and log β0102 = 11.05 ± 0.09 for the Cm3+ and log β0101 = 6.67 ± 0.08 and log β0102 = 11.15 ± 0.09 for the Eu3+ were calculated by extrapolation of data to zero ionic strength in NaClO4 medium only. For all stability constants, the Pitzer model gives an excellent representation of the data using interaction parameters β(0), β(1), and CΦ determined in this work. The thermodynamic model developed in this work will be useful in accurately modeling the potential solubility of trivalent actinides and early lanthanides to ionic strength of 6.60 m in low temperature environments in the presence of Ox. Furthermore, the work is also applicable to the accurate modeling transport of rare earth elements in various environments under the surface conditions.

  19. Fundamental Bulk/Surface Structure Photoactivity Relationships of Supported (Rh2-yCryO3)/GaN Photocatalysts

    SciTech Connect (OSTI)

    Phivilay, Somphonh; Roberts, Charles; Puretzky, Alexander A; Domen, Kazunari Domen; Wachs, Israel

    2013-01-01

    ABSTRACT. The supported (Rh2-yCryO3)/GaN photocatalyst was examined as a model nitride photocatalyst system to assist in the development of fundamental structure photoactivity relationships for UV activated water splitting. Surface characterization of the outermost surface layers by High Sensitivity-LEIS and High Resolution-XPS revealed for the first time that the GaN support consists of a GaOx outermost surface layer and a thin film of GaOxNy in the surface region. HR-XPS also demonstrates that the supported (Rh2-yCryO3) mixed oxide nanoparticles (NPs) exclusively consist of Cr+3 and Rh+3 cations and are surface enriched for the supported (Rh2-yCryO3)/GaN photocatalyst. Bulk analysis by Raman and UV-vis spectroscopy show that the bulk molecular and electronic structures, respectively, of the GaN support are not perturbed by the deposition of the (Rh2-yCryO3) mixed oxide NPs. The function of the GaN bulk lattice is to generate photoexcited electrons/holes, with the electrons harnessed by the surface Rh+3 sites for evolution of H2 and the holes trapped at the Ga oxide/oxynitride surface sites for splitting of water and evolving O2. These new structure-photoactivity relationships for supported (Rh2-yCryO3)/GaN also extend to the best performing visible light activated supported (Rh2-yCryO3)/(Ga1-xZnx)(N1-xOx) photocatalyst.

  20. Organic waste amendments effect on zinc fraction of two soils

    SciTech Connect (OSTI)

    Shuman, L.M.

    1999-10-01

    Organic soil amendments can ameliorate metal toxicity to plants by redistributing metals to less available fractions. The objective of this study was to determine the effects of organic amendments on Zn distribution among soil fractions. Two soils were amended with five organic waste materials (some of which contained Zn) or commercial humic acid with and without 400 mg kg{sup {minus}1} Zn, incubated, and fractionated using a sequential extraction technique. Where no Zn was added most of the metals were in the residual fraction. Commercial compost, poultry litter, and industrial sewage sludge increased Zn in the exchangeable (EXC), organic (OM), and manganese oxide (MnOx) fractions due to Zn in the materials. Spent mushroom compost (SMC) redistributed Zn from the EXC fraction to the MnOx fraction for the coarse-textured soil. Where Zn was added, most of the metal was in the EXC and OM fractions. The SMC and humic acid lowered Zn in the EXC fraction and increased Zn in the other fractions. Effects of the organic materials on Zn in soil fractions were more evident for the sandy soil dominated by quartz in the clay than for the finer-textured soil dominated by kaolinite in the clay-size fraction. It was concluded that organic materials high in Zn can increase Zn in the EXC, OM, and MnOx fractions where the soil is not contaminated and others such as SMC and HA can lower the potential availability of Zn in contaminated soils by redistributing it from the EXC to less soluble fractions.

  1. When ruthenia met titania: Achieving extraordinary catalytic activity at low temperature by nanostructuring of oxides

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Graciani, J.; Stacchiola, D.; Yang, F.; Evans, J.; Vidal, A. B.; Rodriguez, J. A.; Sanz, J. F.

    2015-09-09

    Nanostructured RuOx/TiO2(110) catalysts have a remarkable catalytic activity for CO oxidation at temperatures in the range of 350–375 K. Furthermore, the RuO2(110) surface has no activity. The state-of-the-art DFT calculations indicate that the main reasons for such an impressive improvement in the catalytic activity are: (i) a decrease of the diffusion barrier of adsorbed O atoms by around 40%, from 1.07 eV in RuO2(110) to 0.66 eV in RuOx/TiO2(110), which explains the shift of the activity to lower temperatures and (ii) a lowering of the barrier by 20% for the association of adsorbed CO and O species to give CO2more » (the main barrier for the CO oxidation reaction) passing from around 0.7 eV in RuO2(110) to 0.55 eV in RuOx/TiO2(110). We show that the catalytic properties of ruthenia are strongly modified when supported as nanostructures on titania, attaining higher activity at temperatures 100 K lower than that needed for pure ruthenia. As in other systems consisting of ceria nanostructures supported on titania, nanostructured ruthenia shows strongly modified properties compared to the pure oxide, consolidating the fact that the nanostructuring of oxides is a main way to attain higher catalytic activity at lower temperatures.« less

  2. This

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    i l, L _l i, ,, , i i i n , ,, To be presented at the Symposium on the Science of Advanced Batteries, Cleveland, Ohio, November 8-9, 1993 and published in Proceedings i i i i ill I H I I I II II THIN-FILM RECHARGEABLE LITHIUM BATTERIES J. B. Bates, G. R. Gruzalski, N. J. Dudney, C. F. Luck, Xiaohua Yu Oak Ridge National Laboratory Oak Ridge, Tennessee 37831-6030 "The submiue.al manuscript hu been au_ox_t by * contractor of the U.S. Government unde_ o_ntract No. DE-AC05-g4OR21400.

  3. TO I

    Office of Legacy Management (LM)

    . PBOM t SUBJBCT: D. Sturges, Chief, Operations Division, Banford Operations Offloe, Bichland, Washington B. J. Smith, Chief, Operations Branoh, Production Divisioh, Eew York operations offlce mmm ~mucmoB LETTER . I. - IACBY TO BEICBABDDAlED OX~ES 15, 1950 SYMBOL1 P01llJS:hb . sTiTEs GOVERNMENT ICT. I ) DATE: Hov~bsr 0,19So ~TEBTIOB:'-.B.E.L. Stanford [Ae appreciate very much having,moeived the subjeqt lettei beoause of its signifioa@ bearing on our am-rent fabrioation de$eloInr+s. The

  4. Cyclopentadienyl-bis(oxazoline) magnesium and zirconium complexes in aminoalkene hydroaminations

    SciTech Connect (OSTI)

    Eedugurala, Naresh; Hovey, Megan; Ho, Hung -An; Jana, Barun; Lampland, Nicole L.; Ellern, Arkady; Sadow, Aaron D.

    2015-11-25

    Here, a new class of cyclopentadiene-bis(oxazoline) compounds and their piano-stool-type organometallic complexes have been prepared as catalysts for hydroamination of aminoalkenes. The two compounds MeC(OxMe2)2C5H5 (BoMCpH; OxMe2 = 4,4-dimethyl-2-oxazoline) and MeC(OxMe2)2C5Me4H (BoMCptetH) are synthesized from C5R4HI (R = H, Me) and MeC(OxMe2)2Li. These cyclopentadiene-bis(oxazolines) are converted into ligands that support a variety of metal centers in piano-stool-type geometries, and here we report the preparation of Mg, Tl, Ti, and Zr compounds. BoMCpH and BoMCptetH react with MgMe2(O2C4H8)2 to give the magnesium methyl complexes {BoMCp}MgMe and {BoMCptet}MgMe. BoMCpH and BoMCptetH are converted to BoMCpTl and BoMCptetTl by reaction with TlOEt. The thallium derivatives react with TiCl3(THF)3 to provide [{BoMCp}TiCl(μ-Cl)]2 and [{BoMCptet}TiCl(μ-Cl)]2, the former of which is crystallographically characterized as a dimeric species. BoMCpH and Zr(NMe2)4 react to eliminate dimethylamine and afford {BoMCp}Zr(NMe2)3, which is crystallographically characterized as a monomeric four-legged piano-stool compound. {BoMCp}Zr(NMe2)3, {BoMCp}MgMe, and {BoMCptet}MgMe are efficient catalysts for the hydroamination/cyclization of aminoalkenes under mild conditions.

  5. Ultra high vacuum broad band high power microwave window

    DOE Patents [OSTI]

    Nguyen-Tuong, Viet; Dylla, III, Henry Frederick

    1997-01-01

    An improved high vacuum microwave window has been developed that utilizes high density polyethylene coated on two sides with SiOx, SiNx, or a combination of the two. The resultant low dielectric and low loss tangent window creates a low outgassing, low permeation seal through which broad band, high power microwave energy may be passed. No matching device is necessary and the sealing technique is simple. The features of the window are broad band transmission, ultra-high vacuum compatibility with a simple sealing technique, low voltage standing wave ratio, high power transmission and low cost.

  6. Ultra high vacuum broad band high power microwave window

    DOE Patents [OSTI]

    Nguyen-Tuong, V.; Dylla, H.F. III

    1997-11-04

    An improved high vacuum microwave window has been developed that utilizes high density polyethylene coated on two sides with SiOx, SiNx, or a combination of the two. The resultant low dielectric and low loss tangent window creates a low outgassing, low permeation seal through which broad band, high power microwave energy may be passed. No matching device is necessary and the sealing technique is simple. The features of the window are broad band transmission, ultra-high vacuum compatibility with a simple sealing technique, low voltage standing wave ratio, high power transmission and low cost. 5 figs.

  7. FRm : John A. Deny, DitiSion Of

    Office of Legacy Management (LM)

    to : lieads of Divisions am3 Man DAW.: December 6, 1954 FRm : John A. Deny, DitiSion Of SPNBOL : csm-R:AcB The attached tabulation of active AEC contracts over $l,ooO,Mx) haa been ,xepared as a result of recurring requests fcr infmmatirm cm ow larger contracts. It consists ox- Pa-t I - E+ime contracts and Pert II - Sub- ccdxacts, and lists the contracts alphabetically bq Operations Office to shar; (1) tne of work being prformed by the contractcr; (2) contract rmter; (3).ac&ated dollar

  8. I|ex~

    Office of Legacy Management (LM)

    I|ex~ ~ ILKE&y~~~ *ORNL/RASA-92/14 OAK RIDGE NATIONAL LABORATORY Results of the Radiological Survey at the former Alba Craft Laboratory Site *z riiiriri-lrirfZ Properties, Oxford, Ohio (OX001) M. E. Murray K. S. Brown R. A. Mathis MANAGED BY MARTIN MARIETTA ENERGY SYSTEMS, INC. FOR THE UNITED STATES DEPARTMENT OF ENERGY | ~~DEPARTMENT OF ENERGY This report has been reproduced directly from the best available copy. Available to DOE and DOE contractors from the Office of Scientific and Techni-

  9. Structural and functional characterization of human and murine C5a anaphylatoxins

    SciTech Connect (OSTI)

    Schatz-Jakobsen, Janus Asbjørn; Yatime, Laure Larsen, Casper; Petersen, Steen Vang; Klos, Andreas; Andersen, Gregers Rom

    2014-06-01

    The structure of the human C5aR antagonist, C5a-A8, reveals a three-helix bundle conformation similar to that observed for human C5a-desArg, whereas murine C5a and C5a-desArg both form the canonical four-helix bundle. These conformational differences are discussed in light of the differential C5aR activation properties observed for the human and murine complement anaphylatoxins across species. Complement is an ancient part of the innate immune system that plays a pivotal role in protection against invading pathogens and helps to clear apoptotic and necrotic cells. Upon complement activation, a cascade of proteolytic events generates the complement effectors, including the anaphylatoxins C3a and C5a. Signalling through their cognate G-protein coupled receptors, C3aR and C5aR, leads to a wide range of biological events promoting inflammation at the site of complement activation. The function of anaphylatoxins is regulated by circulating carboxypeptidases that remove their C-terminal arginine residue, yielding C3a-desArg and C5a-desArg. Whereas human C3a and C3a-desArg adopt a canonical four-helix bundle fold, the conformation of human C5a-desArg has recently been described as a three-helix bundle. Here, the crystal structures of an antagonist version of human C5a, A8{sup ?71–73}, and of murine C5a and C5a-desArg are reported. Whereas A8{sup ?71–73} adopts a three-helix bundle conformation similar to human C5a-desArg, the two murine proteins form a four-helix bundle. A cell-based functional assay reveals that murine C5a-desArg, in contrast to its human counterpart, exerts the same level of activition as murine C5a on its cognate receptor. The role of the different C5a conformations is discussed in relation to the differential activation of C5a receptors across species.

  10. Digging deeper into the Southern skies: A compact Milky Way companion discovered in first-year Dark Energy Survey data

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Luque, E.

    2016-02-09

    Here, the Dark Energy Survey (DES) is a 5000 sq. degree survey in the southern hemisphere, which is rapidly reducing the existing north-south asymmetry in the census of MW satellites and other stellar substructure. We use the first-year DES data down to previously unprobed photometric depths to search for stellar systems in the Galactic halo, therefore complementing the previous analysis of the same data carried out by our group earlier this year. Our search is based on a matched filter algorithm that produces stellar density maps consistent with stellar population models of various ages, metallicities, and distances over the surveymore » area. The most conspicuous density peaks in these maps have been identified automatically and ranked according to their significance and recurrence for different input models. We report the discovery of one additional stellar system besides those previously found by several authors using the same first-year DES data. The object is compact, and consistent with being dominated by an old and metal-poor population. DES J0034-4902 is found at high significance and appears in the DES images as a compact concentration of faint blue point sources at ~ 87 {kpc}.« less

  11. DESAlert: Enabling real-time transient follow-up with Dark Energy Survey data

    SciTech Connect (OSTI)

    Poci, A.

    2015-04-12

    The Dark Energy Survey (DES) is currently undertaking an observational program imaging 1/4 of the southern hemisphere sky with unprecedented photometric accuracy. In the process of observing millions of faint stars and galaxies to constrain the parameters of the dark energy equation of state, the DES will obtain pre-discovery images of the regions surrounding an estimated 100 gamma-ray bursts (GRBs) over five years. Once GRBs are detected by, e.g., the Swift satellite, the DES data will be extremely useful for follow-up observations by the transient astronomy community. We describe a recently-commissioned suite of software that listens continuously for automated notices of GRB activity, collates useful information from archival DES data, and promulgates relevant data products back to the community in near-real-time. Of particular importance are the opportunities that DES data provide for relative photometry of GRBs or their afterglows, as well as for identifying key characteristics (e.g., photometric redshifts) of potential GRB host galaxies. We provide the functional details of the DESAlert software as it presently operates, as well as the data products that it produces, and we show sample results from the application of DESAlert to several previously-detected GRBs.

  12. A biotemplated nickel nanostructure: Synthesis, characterization and antibacterial activity

    SciTech Connect (OSTI)

    Ashtari, Khadijeh; Fasihi, Javad; Mollania, Nasrin; Khajeh, Khosro

    2014-02-01

    Highlights: • Nickel nanostructure-encapsulated bacteria were prepared using electroless deposition. • Bacterium surface was activated by red-ox reaction of its surface amino acids. • Interfacial changes at cell surfaces were investigated using fluorescence spectroscopy. • TEM and AFM depicted morphological changes. • Antibacterial activity of nanostructure was examined against different bacteria strains. - Abstract: Nickel nanostructure-encapsulated bacteria were prepared using the electroless deposition procedure and activation of bacterium cell surface by red-ox reaction of surface amino acids. The electroless deposition step occurred in the presence of Ni(II) and dimethyl amine boran (DMAB). Interfacial changes at bacteria cell surfaces during the coating process were investigated using fluorescence spectroscopy. Fluorescence of tryptophan residues was completely quenched after the deposition of nickel onto bacteria surfaces. Transmission electron microscopy (TEM) and atomic force microscopy (AFM) depicted morphological changes on the surface of the bacterium. It was found that the Ni coated nanostructure was mechanically stable after ultrasonication for 20 min. Significant increase in surface roughness of bacteria was also observed after deposition of Ni clusters. The amount of coated Ni on the bacteria surface was calculated as 36% w/w. The antibacterial activity of fabricated nanostructure in culture media was examined against three different bacteria strains; Escherichia coli, Bacillus subtilis and Xantomonas campestris. The minimum inhibitory concentrations (MIC) were determined as 500 mg/L, 350 mg/L and 200 mg/L against bacteria, respectively.

  13. Bimetallic Ni-Rh catalysts with low amounts of Rh for the steam and autothermal reforming of n-butane for fuel-cell applications.

    SciTech Connect (OSTI)

    Ferrandon, M.; Kropf, A. J.; Krause, T.; Chemical Sciences and Engineering Division

    2010-05-15

    Mono-metallic nickel and rhodium catalysts and bimetallic Ni-Rh catalysts supported on La-Al{sub 2}O{sub 3}, CeZrO{sub 2} and CeMgOx were prepared and evaluated for catalyzing the steam and autothermal reforming of n-butane. The binary Ni-Rh supported on La-Al{sub 2}O{sub 3} catalysts with low weight loading of rhodium exhibited higher H{sub 2} yields than Ni or Rh alone. The Ni-Rh/CeZrO{sub 2} catalyst exhibited higher performance and no coke formation, compared to the same metals on other supports. A NiAl{sub 2}O{sub 4} spinel phase was obtained on all Ni and Ni-Rh catalysts supported on La-Al{sub 2}O{sub 3}. The presence of rhodium stabilized the spinel phase as well as NiOx species upon reforming while Ni alone was mostly reduced into metallic species. Extended X-ray absorption fine-structure analysis showed evidence of Ni-Rh alloy during preparation and even further after an accelerated aging at 900C in a H{sub 2}/H{sub 2}O atmosphere.

  14. An In-Situ XAS Study of the Structural Changes in a CuO-CeO2/Al2O3 Catalyst during Total Oxidation of Propane

    SciTech Connect (OSTI)

    Silversmith, Geert; Poelman, Hilde; Poelman, Dirk; Gryse, Roger de; Olea, Maria; Balcaen, Veerle; Heynderickx, Philippe; Marin, Guy B.

    2007-02-02

    A CuOx-CeOx/Al2O3 catalyst was studied with in-situ transmission Cu K XAS for the total oxidation of propane as model reaction for the catalytic elimination of volatile organic compounds. The local Cu structure was determined for the catalyst as such, after pre-oxidation and after reduction with propane. The catalyst as such has a local CuO structure. No structural effect was observed upon heating in He up to 600 deg. C or after pre-oxidation at 150 deg. C. A full reduction of the Cu2+ towards metallic Cu0 occurred, when propane was fed to the catalyst. The change in local Cu structure during propane reduction was followed with a time resolution of 1 min. The {chi}(k) scans appeared as linear combinations of start and end spectra, CuO and Cu structure, respectively. However, careful examination of the XANES edge spectra indicates the presence of a small amount of additional Cu1+ species.

  15. High-Performance Flexible Perovskite Solar Cells by Using a Combination of Ultrasonic Spray-Coating and Low Thermal Budget Photonic Curing

    SciTech Connect (OSTI)

    Sanjib, Das; Yang, Bin; Gu, Gong; Joshi, Pooran C; Ivanov, Ilia N; Rouleau, Christopher; Aytug, Tolga; Geohegan, David B; Xiao, Kai

    2015-01-01

    Realizing the commercialization of high-performance and robust perovskite solar cells urgently requires the development of economically scalable processing techniques. Here we report a high-throughput ultrasonic spray-coating (USC) process capable of fabricating perovskite film-based solar cells on glass substrates with power conversion efficiency (PCE) as high as 13.04%. Perovskite films with high uniformity, crystallinity, and surface coverage are obtained in a single step. Moreover, we report USC processing on TiOx/ITO-coated polyethylene terephthalate (PET) substrates to realize flexible perovskite solar cells with PCE as high as 8.02% that are robust under mechanical stress. In this case, an optical curing technique was used to achieve a highly-conductive TiOx layer on flexible PET substrates for the first time. The high device performance and reliability obtained by this combination of USC processing with optical curing appears very promising for roll-to-roll manufacturing of high-efficiency, flexible perovskite solar cells.

  16. Enhanced photocatalytic degradation of methylene blue by metal-modified silicon nanowires

    SciTech Connect (OSTI)

    Brahiti, N.; Hadjersi, T.; Menari, H.; Amirouche, S.; El Kechai, O.

    2015-02-15

    Highlights: • SiNWs modified with Pd, Au and Pt were used as photocatalysts to degrade MB. • Yield of photodegardation increases with UV irradiation time. • SiNWs modified with Pd nanoparticles show the best photocatalytic activity. • A degradation of 97% was obtained after 200 min of UV irradiation. - Abstract: Silicon nanowires (SiNWs) modified with Au, Pt and Pd nanoparticles were used as heterogeneous photocatalysts for the photodegradation of methylene blue in water under UV light irradiation. The modification of SiNWs was carried out by deposition of metal nanoparticles using the electroless metal deposition (EMD) technique. The effect of metal nanoparticles deposition time on the photocatalytic activity was studied. It was found that the photocatalytic activity of modified SiNWs was enhanced when the deposition time of metal nanoparticles was increased. In addition of modified SiNWs with Pt, Au and Pd nanoparticles, oxidized silicon substrate (Ox-Si), oxidized silicon nanowires (Ox-SiNWs) and hydrogen-terminated silicon nanowires (H-SiNWs) were also evaluated for the photodegradation of methylene blue.

  17. Electric control of magnetism at the Fe/BaTiO3 interface

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Radaelli, G.; Petti, D.; Plekhanov, E.; Fina, I.; Torelli, P.; Salles, B. R.; Cantoni, M.; Rinaldi, C.; Gutiérrez, D.; Panaccione, G.; et al

    2014-03-03

    Interfacial magnetoelectric coupling (MEC) is a viable path to achieve electrical writing of magnetic information in spintronic devices. For the prototypical Fe/BaTiO3 (BTO) system, only tiny changes of the interfacial Fe magnetic moment upon reversal of the BTO dielectric polarization have been predicted so far. Here, by using X-ray magnetic circular dichroism in combination with high resolution electron microscopy and first principles calculations, we report on an undisclosed physical mechanism for interfacial MEC in the Fe/BTO system. At the Fe/BTO interface, an ultrathin FeOx layer exists, whose magnetization can be electrically and reversibly switched on-off at room-temperature by reversing themore » BTO polarization. The suppression / recovery of interfacial ferromagnetism results from the asymmetric effect that ionic displacements in BTO produces on the exchange coupling constants in the adjacent FeOx layer. The observed giant magnetoelectric response holds potential for optimizing interfacial MEC in view of efficient, low-power spintronic devices.« less

  18. Electrochromic Graphene Molecules

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ji, Zhiqiang; Doorn, Stephen K.; Sykora, Milan

    2015-03-13

    Polyclic aromatic hydrocarbons, also called Graphene Molecules (GMs), with chemical composition C132H36(COOH)2 were synthesized in-situ on the surface of transparent nanocrystaline indium tin oxide (nc-ITO) electrodes. Their electronic structure was studied electrochemically and spectro-electrochemically. Variations in the potential applied onto the nc-ITO/GM electrodes induce only small changes in the observed current but they produce dramatic changes in the absorption of the GMs, which are associated with their oxidation and reduction. Analysis of the absorption changes using modified Nernst equation is used to determine standard potentials associated with the individual charge transfer processes. For the GMs prepared here these were foundmore » to be E1,ox 0 = 0.77± 0.01 V and E2,ox 0 = 1.24 ± 0.02 V vs. NHE for the first and second oxidation and E1,red 0 = -1.50 ± 0.04 V for the first reduction. The charge transfer processes are found to be non-ideal. The non-ideality factors associated with the oxidation and reduction processes suggest presence of strong interactions between the GM redox centers. Under the conditions of potential cycling GMs show rapid (seconds) color change with high contrast and stability. An electrochromic application is demonstrated wherein the GMs are used as the optically active component.« less

  19. Silicon Oxynitride Thin Film Barriers for PV Packaging (Poster)

    SciTech Connect (OSTI)

    del Cueto, J. A.; Glick, S. H.; Terwilliger, K. M.; Jorgensen, G. J.; Pankow, J. W.; Keyes, B. M.; Gedvilas, L. M.; Pern, F. J.

    2006-10-03

    Dielectric, adhesion-promoting, moisture barriers comprised of silicon oxynitride thin film materials (SiOxNy with various material stoichiometric compositions x,y) were applied to: 1) bare and pre-coated soda-lime silicate glass (coated with transparent conductive oxide SnO2:F and/or aluminum), and polymer substrates (polyethylene terephthalate, PET, or polyethylene napthalate, PEN); plus 2) pre- deposited photovoltaic (PV) cells and mini-modules consisting of amorphous silicon (a-Si) and copper indium gallium diselenide (CIGS) thin-film PV technologies. We used plasma enhanced chemical vapor deposition (PECVD) process with dilute silane, nitrogen, and nitrous oxide/oxygen gas mixtures in a low-power (< or = 10 milliW per cm2) RF discharge at ~ 0.2 Torr pressure, and low substrate temperatures < or = 100(degrees)C, over deposition areas ~ 1000 cm2. Barrier properties of the resulting PV cells and coated-glass packaging structures were studied with subsequent stressing in damp-heat exposure at 85(degrees)C/85% RH. Preliminary results on PV cells and coated glass indicate the palpable benefits of the barriers in mitigating moisture intrusion and degradation of the underlying structures using SiOxNy coatings with thicknesses in the range of 100-200 nm.

  20. Piano-stool lutetium amido and imido compounds supported by a constrained bis(oxazoline)cyclopentadienyl ligand

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lampland, Nicole L.; Zhu, Jing; Hovey, Megan; Jana, Barun; Ellern, Arkady; Sadow, Aaron D.

    2015-06-25

    {BoMCptet}Lu(CH2Ph)2 (1; BoMCptet = MeC(OxMe2 2C5Me4; OxMe2 = 4,4-dimethyl-2-oxazoline) was prepared in 95% yield from the reaction of BoMCptetH and Lu(CH2Ph)3THF3. Compound 1 reacts with 1 or 2 equiv of H2NCH2R (R = C6H5, 1-C10H7) to give the corresponding imido complexes [{BoMCptet}LuNCH2R]2 (R = C6H5 (2a), 1-C10H7 (2b)) or amido complexes {BoMCptet}Lu(NHCH2R)2 (R = C6H5 (3a), 1-C10H7 (3b)). When isolated, the imido species are insoluble in nonprotic organic solvents. Crystallographic characterization reveals dimeric [{BoMCptet}LuNCH2(1-C10H7)]2 in the solid state. The reaction of 1 and NH3B(C6F5)3 affords crystallographically characterized {BoMCptet}Lu{NHB(C6F5)2}C6F5. This species is proposed to form via a transient lutetium imido, whichmore » undergoes C6F5 migration to the lutetium center.« less

  1. Electrochromic Graphene Molecules

    SciTech Connect (OSTI)

    Ji, Zhiqiang; Doorn, Stephen K.; Sykora, Milan

    2015-03-13

    Polyclic aromatic hydrocarbons, also called Graphene Molecules (GMs), with chemical composition C132H36(COOH)2 were synthesized in-situ on the surface of transparent nanocrystaline indium tin oxide (nc-ITO) electrodes. Their electronic structure was studied electrochemically and spectro-electrochemically. Variations in the potential applied onto the nc-ITO/GM electrodes induce only small changes in the observed current but they produce dramatic changes in the absorption of the GMs, which are associated with their oxidation and reduction. Analysis of the absorption changes using modified Nernst equation is used to determine standard potentials associated with the individual charge transfer processes. For the GMs prepared here these were found to be E1,ox 0 = 0.77± 0.01 V and E2,ox 0 = 1.24 ± 0.02 V vs. NHE for the first and second oxidation and E1,red 0 = -1.50 ± 0.04 V for the first reduction. The charge transfer processes are found to be non-ideal. The non-ideality factors associated with the oxidation and reduction processes suggest presence of strong interactions between the GM redox centers. Under the conditions of potential cycling GMs show rapid (seconds) color change with high contrast and stability. An electrochromic application is demonstrated wherein the GMs are used as the optically active component.

  2. Air-gap gating of MgZnO/ZnO heterostructures

    SciTech Connect (OSTI)

    Tambo, T.; Falson, J. Kozuka, Y.; Maryenko, D.; Tsukazaki, A.; Kawasaki, M.

    2014-08-28

    The adaptation of “air-gap” dielectric based field-effect transistor technology to controlling the MgZnO/ZnO heterointerface confined two-dimensional electron system (2DES) is reported. We find it possible to tune the charge density of the 2DES via a gate electrode spatially separated from the heterostructure surface by a distance of 5??m. Under static gating, the observation of the quantum Hall effect suggests that the charge carrier density remains homogeneous, with the 2DES in the 3?mm square sample the sole conductor. The availability of this technology enables the exploration of the charge carrier density degree of freedom in the pristine sample limit.

  3. Conference B.Bettelheim

    ScienceCinema (OSTI)

    None

    2011-04-25

    Le Dr.Bruno Bettelheim, psychologue américain, d'origine viennoise, a passé son doctorat en psychologie à l'université de Vienne. Il émigra aux Etats-Unis et enseigna la psychologie au Rockford College en Illinois et la psychologie de l'éducation à L'université de Chicago, où il dirigea également l'institut orthogénique Sonia-Shankman pour le traitement des enfants psychotiques. Cet homme a bouleversé la compréhension des relations parents et enfants en y introduisant la psychanalyse. Basé sur ses expériences aux Etats-Unis,il nous parle des changements dans la structure de la famille et ses conséquences pour la relation entre enfants et parents.

  4. Voyage dans le noir. Trous noirs, matière noire, énergie noire et antimatière

    ScienceCinema (OSTI)

    None

    2011-10-06

    Et si nous faisions avec les physiciens un voyage dans le noir ? De l'astrophysique à la physique des particules les trois noirs, la matière noire, l'énergie noire ou l?antimatière intriguent et fascinent. Que sont ces objets qui bousculent nos idées et qui véhiculent parfois des craintes irraisonnées? Luis Alvarez-Gaume, Michael Doser et Christophe Grojean, physiciens du CERN vous invitent à mettre en lumière (!) les constituants de base de la matière et à explorer les mystères de la physique contemporaine. Une soirée lumineuse pour éclairer des concepts et ne plus avoir peur du noir.

  5. Eight ultra-faint galaxy candidates discovered in year two of the Dark Energy Survey

    SciTech Connect (OSTI)

    Drlica-Wagner, A.

    2015-11-04

    We report the discovery of eight new ultra-faint dwarf galaxy candidates in the second year of optical imaging data from the Dark Energy Survey (DES). Six of these candidates are detected at high confidence, while two lower-confidence candidates are identified in regions of non-uniform survey coverage. The new stellar systems are found by three independent automated search techniques and are identified as overdensities of stars, consistent with the isochrone and luminosity function of an old and metal-poor simple stellar population. The new systems are faint (MV > -4.7 ) and span a range of physical sizes (17 pc < r1/2 < 181pc) and heliocentric distances (25 kpc < D? < 214 kpc). All of the new systems have central surface brightnesses consistent with known ultra-faint dwarf galaxies (? 27.5 mag arcsec -2). Roughly half of the DES candidates are more distant, less luminous, and/or have lower surface brightnesses than previously known Milky Way satellite galaxies. Most of the candidates are found in the southern part of the DES footprint close to the Magellanic Clouds. We find that the DES data alone exclude (p < 10-3) a spatially isotropic distribution of Milky Way satellites and that the observed distribution can be well, though not uniquely, described by an association between several of the DES satellites and the Magellanic system. Furthermore, our model predicts that the full sky may hold ~100 ultra-faint galaxies with physical properties comparable to the DES satellites and that 20%–30% of these would be spatially associated with the Magellanic Clouds.

  6. Eight ultra-faint galaxy candidates discovered in year two of the Dark Energy Survey

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Drlica-Wagner, A.

    2015-11-04

    We report the discovery of eight new ultra-faint dwarf galaxy candidates in the second year of optical imaging data from the Dark Energy Survey (DES). Six of these candidates are detected at high confidence, while two lower-confidence candidates are identified in regions of non-uniform survey coverage. The new stellar systems are found by three independent automated search techniques and are identified as overdensities of stars, consistent with the isochrone and luminosity function of an old and metal-poor simple stellar population. The new systems are faint (MV > -4.7 ) and span a range of physical sizes (17 pc < r1/2more » < 181pc) and heliocentric distances (25 kpc < D⊙ < 214 kpc). All of the new systems have central surface brightnesses consistent with known ultra-faint dwarf galaxies (μ 27.5 mag arcsec -2). Roughly half of the DES candidates are more distant, less luminous, and/or have lower surface brightnesses than previously known Milky Way satellite galaxies. Most of the candidates are found in the southern part of the DES footprint close to the Magellanic Clouds. We find that the DES data alone exclude (p < 10-3) a spatially isotropic distribution of Milky Way satellites and that the observed distribution can be well, though not uniquely, described by an association between several of the DES satellites and the Magellanic system. Furthermore, our model predicts that the full sky may hold ~100 ultra-faint galaxies with physical properties comparable to the DES satellites and that 20%–30% of these would be spatially associated with the Magellanic Clouds.« less

  7. Laboratory evaluation of dynamic traffic assignment systems: Requirements, framework, and system design

    SciTech Connect (OSTI)

    Miaou, S.-P.; Pillai, R.S.; Summers, M.S.; Rathi, A.K.; Lieu, H.C.

    1997-01-01

    The success of Advanced Traveler Information 5ystems (ATIS) and Advanced Traffic Management Systems (ATMS) depends on the availability and dissemination of timely and accurate estimates of current and emerging traffic network conditions. Real-time Dynamic Traffic Assignment (DTA) systems are being developed to provide the required timely information. The DTA systems will provide faithful and coherent real-time, pre-trip, and en-route guidance/information which includes routing, mode, and departure time suggestions for use by travelers, ATIS, and ATMS. To ensure the credibility and deployment potential of such DTA systems, an evaluation system supporting all phases of DTA system development has been designed and presented in this paper. This evaluation system is called the DTA System Laboratory (DSL). A major component of the DSL is a ground- truth simulator, the DTA Evaluation System (DES). The DES is envisioned to be a virtual representation of a transportation system in which ATMS and ATIS technologies are deployed. It simulates the driving and decision-making behavior of travelers in response to ATIS and ATMS guidance, information, and control. This paper presents the major evaluation requirements for a DTA Systems, a modular modeling framework for the DES, and a distributed DES design. The modeling framework for the DES is modular, meets the requirements, can be assembled using both legacy and independently developed modules, and can be implemented as a either a single process or a distributed system. The distributed design is extendible, provides for the optimization of distributed performance, and object-oriented design within each distributed component. A status report on the development of the DES and other research applications is also provided.

  8. EVIDENCE FOR THE DISKY ORIGIN OF LUMINOUS VIRGO DWARF ELLIPTICALS FROM THE KINEMATICS OF THEIR GLOBULAR CLUSTER SYSTEMS

    SciTech Connect (OSTI)

    Beasley, Michael A.; Cenarro, A. Javier; Brodie, Jean P. E-mail: cenarro@iac.es E-mail: brodie@ucolick.org

    2009-06-15

    We report evidence for dynamically significant rotation in the globular cluster systems of two luminous Virgo dwarf ellipticals, VCC1261 and VCC1528. Including previous results for VCC1087, the globular cluster systems of all three Virgo dwarf ellipticals studied in detail to date exhibit v {sub rot}/{sigma}{sub los}>1. Taking the rotation seen in the globular clusters as a maximal disk rotation, and accounting for the possible fading of any hypothetical progenitor galaxy, we find all three dwarf elliptical galaxies (dEs) lie on the r-band Tully-Fisher relation. We argue that these data support the hypothesis that luminous dEs are the remnants of transformed disk galaxies. We also obtained deep, longslit data for the stars in VCC1261 and VCC1528. Both these galaxies show rapid rotation in their inner regions, with spatial scales of {approx}0.5 kpc. These rotation velocities are surprisingly similar to those seen in the globular cluster systems. At larger radii, we see little rotation in the dEs themselves. Since our longslit data for Virgo dEs extend out to 1-2 effective radii (typical of deep observations), whereas the globular clusters extend out to 4-7 effective radii, we conclude that nondetections of rotation in many luminous dEs may simply be due to a lack of radial coverage in the stellar data, and that globular clusters represent singularly sensitive probes of the dynamics of dEs. Based on these data, we suggest that gas disks are significant sites of globular cluster formation in the early universe.

  9. THE DARK ENERGY SURVEY: PROSPECTS FOR RESOLVED STELLAR POPULATIONS

    SciTech Connect (OSTI)

    Rossetto, Bruno M.; Santiago, Basílio X.; Girardi, Léo; Camargo, Julio I. B.; Balbinot, Eduardo; da Costa, Luiz N.; Yanny, Brian; Maia, Marcio A. G.; Makler, Martin; Ogando, Ricardo L. C.; Pellegrini, Paulo S.; Ramos, Beatriz; de Simoni, Fernando; Armstrong, R.; Bertin, E.; Desai, S.; Kuropatkin, N.; Lin, H.; Mohr, J. J.; Tucker, D. L.

    2011-06-01

    Wide angle and deep surveys, regardless of their primary purpose, always sample a large number of stars in the Galaxy and in its satellite system. We here make a forecast of the expected stellar sample resulting from the Dark Energy Survey and the perspectives that it will open for studies of Galactic structure and resolved stellar populations in general. An estimated 1.2 x 108 stars will be sampled in DES grizY filters in the southern equatorial hemisphere. This roughly corresponds to 20% of all DES sources. Most of these stars belong to the stellar thick disk and halo of the Galaxy.

  10. THE DARK ENERGY SURVEY: PROSPECTS FOR RESOLVED STELLAR POPULATIONS

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rossetto, Bruno M.; Santiago, Basílio X.; Girardi, Léo; Camargo, Julio I. B.; Balbinot, Eduardo; da Costa, Luiz N.; Yanny, Brian; Maia, Marcio A. G.; Makler, Martin; Ogando, Ricardo L. C.; et al

    2011-06-01

    Wide angle and deep surveys, regardless of their primary purpose, always sample a large number of stars in the Galaxy and in its satellite system. We here make a forecast of the expected stellar sample resulting from the Dark Energy Survey and the perspectives that it will open for studies of Galactic structure and resolved stellar populations in general. An estimated 1.2 x 108 stars will be sampled in DES grizY filters in the southern equatorial hemisphere. This roughly corresponds to 20% of all DES sources. Most of these stars belong to the stellar thick disk and halo of themore »Galaxy.« less

  11. Eia.gov BETA - Data - U.S. Energy Information Administration (EIA)

    U.S. Energy Information Administration (EIA) Indexed Site

    Tableau croisé des definitions English FranÇais Español A B C D E É F G H I J K L M N O P Q R S T U V W X Y Z Parcourir les termes liés aux catégories suivantes: pétrole brut et équivalents liquides de gaz naturel additifs et composés oxygénés Produits pétroliers gaz naturel biocarburant électricité Consultez l'index des termes

  12. Human Rights

    ScienceCinema (OSTI)

    None

    2011-04-25

    Daniel Meyer, Président de la ligue française de défense de droits de l'homme et du citoyen fait un exposé sur son engagement (politique). Dans la deuxième partie, une avocate brésilienne (en exil)donne un témoignage de la violation des droits de l'homme sous la dictature militaire de son pays; elle a défendu pendant 6 ans des prisonniers politiques.

  13. Air Brazing: A New Method of Ceramic-Ceramic and Ceramic-Metal Joining

    SciTech Connect (OSTI)

    Weil, K. Scott; Darsell, Jens T.; Kim, Jin Yong

    2011-10-01

    A new method of ceramic-ceramic and ceramic-metal joining has emerged over the past several years. Referred to as air brazing, the technique was originally designed and developed for use in fabricating high-temperature solid-state electrochemical devices such as planar SOFCs and oxygen and hydrogen concentrators. The primary advantage of air brazing is that a predominantly metallic joint can be formed directly in air without need of an inert cover gas or the use of surface reactive fluxes. The resulting bond is hermetic, offers excellent room temperature strength, and is inherently resistant to oxidation at high temperature. The key to developing a successful filler metal composition for air brazing is to identify a metal oxide wetting agent that is mutually soluble in a molten noble metal solvent. One particular oxide-metal combination that appears readily suited for this purpose is CuOx-Ag, a system originally of interest in the development of silver clad cuprate-based superconductors. Studies of the equilibrium phases studies in this system indicate that there are two invariant points in the pseudobinary CuOx-Ag phase diagram around which new braze compositions can be developed: 1) a monotectic reaction at 969±1°C, where CuO and a Ag-rich liquid L1 coexist with a second CuOx-rich liquid phase L2 at a composition of xAg/(xAg + xCu) = 0.10±0.03 Ag and 2) a eutectic reaction at 942±1°C, where CuO and Ag coexist with L1 at a composition of xAg/(xAg + xCu) = 0.99±0.005. Specifically, near-eutectic Ag-CuO filler metal compositions have shown good promise in joining electrochemically active ceramics such as yttria-stabilized zirconia, lanthanum strontium manganite, and barium strontium cobalt ferrite, as well as alumina and magnesia. More recently it has been found that various ternary additions can further improve the wetting characteristics of these filler metals, increase their potential operating temperatures, and/or increase the resulting strength of the joint strength. Here we review the basic concept of air brazing and illustrate filler metal selection and design using the Ag-CuO system as an example.

  14. STELLAR KINEMATICS AND STRUCTURAL PROPERTIES OF VIRGO CLUSTER DWARF EARLY-TYPE GALAXIES FROM THE SMAKCED PROJECT. III. ANGULAR MOMENTUM AND CONSTRAINTS ON FORMATION SCENARIOS

    SciTech Connect (OSTI)

    Toloba, E.; Guhathakurta, P.; Peletier, R. F.; Emsellem, E.; Lisker, T.; Van de Ven, G.; Simon, J. D.; Adams, J. J.; Benson, A. J.; Falcón-Barroso, J.; Ryś, A.; Gorgas, J.; Hensler, G.; Janz, J.; Laurikainen, E.; Salo, H.; Paudel, S.

    2015-02-01

    We analyze the stellar kinematics of 39 dwarf early-type galaxies (dEs) in the Virgo Cluster. Based on the specific stellar angular momentum λ{sub Re} and the ellipticity, we find 11 slow rotators and 28 fast rotators. The fast rotators in the outer parts of the Virgo Cluster rotate significantly faster than fast rotators in the inner parts of the cluster. Moreover, 10 out of the 11 slow rotators are located in the inner 3° (D < 1 Mpc) of the cluster. The fast rotators contain subtle disk-like structures that are visible in high-pass filtered optical images, while the slow rotators do not exhibit these structures. In addition, two of the dEs have kinematically decoupled cores and four more have emission partially filling in the Balmer absorption lines. These properties suggest that Virgo Cluster dEs may have originated from late-type star-forming galaxies that were transformed by the environment after their infall into the cluster. The correlation between λ{sub Re} and the clustercentric distance can be explained by a scenario where low luminosity star-forming galaxies fall into the cluster, their gas is rapidly removed by ram-pressure stripping, although some of it can be retained in their core, their star formation is quenched but their stellar kinematics are preserved. After a long time in the cluster and several passes through its center, the galaxies are heated up and transformed into slow rotating dEs.

  15. Press conference

    ScienceCinema (OSTI)

    None

    2011-04-25

    Exposés de plusieurs intervenants de la direction et du conseil, comme le Prof.Ramsey, président du conseil sur l'adhésion récente de la Finlande et le "boom" scientifique des pays de l'est.

  16. Combining Galaxy-Galaxy Lensing and Galaxy Clustering

    SciTech Connect (OSTI)

    Park, Youngsoo; Krause, Elisabeth; Dodelson, Scott; Jain, Bhuvnesh; Amara, Adam; Becker, Matt; Bridle, Sarah; Clampitt, Joseph; Crocce, Martin; Honscheid, Klaus; Gaztanaga, Enrique; Sanchez, Carles; Wechsler, Risa

    2015-01-01

    Combining galaxy-galaxy lensing and galaxy clustering is a promising method for inferring the growth rate of large scale structure, a quantity that will shed light on the mechanism driving the acceleration of the Universe. The Dark Energy Survey (DES) is a prime candidate for such an analysis, with its measurements of both the distribution of galaxies on the sky and the tangential shears of background galaxies induced by these foreground lenses. By constructing an end-to-end analysis that combines large-scale galaxy clustering and small-scale galaxy-galaxy lensing, we also forecast the potential of a combined probes analysis on DES datasets. In particular, we develop a practical approach to a DES combined probes analysis by jointly modeling the assumptions and systematics affecting the different components of the data vector, employing a shared halo model, HOD parametrization, photometric redshift errors, and shear measurement errors. Furthermore, we study the effect of external priors on different subsets of these parameters. We conclude that DES data will provide powerful constraints on the evolution of structure growth in the universe, conservatively/ optimistically constraining the growth function to 8%/4.9% with its first-year data covering 1000 square degrees, and to 4%/2.3% with its full five-year data covering 5000 square degrees.

  17. Browse by Discipline -- E-print Network Subject Pathways: Geosciences...

    Office of Scientific and Technical Information (OSTI)

    A B C D E F G H I J K L M N O P Q R S T U V W X Y Z Institut de Biologie Physico-Chimique CNRS, Physico-Chimie Molculaire des Membranes Biologiques Institute of Catalysis and ...

  18. CX-002724: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Area of Interest 3 Deployment of Flex Combined Heat and Power System (Funding Opportunity Announcement 0000016)CX(s) Applied: B3.6Date: 06/21/2010Location(s): Des Plains, IllinoisOffice(s): Energy Efficiency and Renewable Energy, National Energy Technology Laboratory

  19. Science anc Society

    ScienceCinema (OSTI)

    None

    2011-04-25

    S.P.Worden, membre technique de l'U.S.délégation à Genève pour les négociations sur les armes nucléaires, est physicien, astronome, scientifique et officier de l'armée de l'air. Il parlera des technologies de défense stratégique

  20. 10th Anniversary P.S.

    ScienceCinema (OSTI)

    None

    2011-04-25

    John Adams parle de la préhistoire du P.S. avec présentation des dias. Le DG B.Gregory prend la parole. Les organisateurs présentent sous la direction du "Prof.Ocktette"(?) un sketch très humoristique (p.e.existence de Quark etc.....)

  1. CX-003043: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Development of a Training Program for Commercial Building TechniciansCX(s) Applied: A1, A9, A11Date: 07/19/2010Location(s): Des Plaines, IllinoisOffice(s): Energy Efficiency and Renewable Energy, National Energy Technology Laboratory

  2. Meeting DG's

    ScienceCinema (OSTI)

    None

    2011-04-25

    Le DG J.Adams commente les 3 thèmes de la réunion: 1.) le prochain DG du Cern (qui sera H.Schopper) 2.) le LEP 3.) les conclusions du comité des finances concernant salaires, allocations etc. Discussion entre le DG J.Adams, Mons.Ullmann, chef du personel et l'auditoire

  3. SOLUBILITY OF METHANE I N WATER UNDER NATURAL CONDITIONS A LABORATORY...

    Office of Scientific and Technical Information (OSTI)

    SOLUBILITY OF METHANE I N WATER UNDER NATURAL CONDITIONS A LABORATORY STUDY , DISCLAIMER I DOEET12145--1 DES2 0 1 7 6 8 0 F I N A L REPORT F O R T H E P E R I O D A P R ...

  4. Science and Society

    ScienceCinema (OSTI)

    None

    2011-04-25

    "Can nuclear war be controled?"- la guerre nucléaire peut-elle être contrôlée? Tel est le thème de cette conférence avec présentation des dias.

  5. Science and Society

    ScienceCinema (OSTI)

    None

    2011-04-25

    Dans une période d'un mois, 2me conférence sur le contrôle d'armes. Le conférencier Drell, américain, parle comme son collègue Worden (AUDIO-1985-005) des problèmes de défense stratégique.

  6. Meeting LEP

    ScienceCinema (OSTI)

    None

    2011-04-25

    Le DG J.Adams fait l'introduction et présente les deux autres orateurs. Pierre Darriulat qui fait un doscours sur la physique à l'occasion du LEP, Wolfgang Schnell, qui parle du projet de la machine LEP et le DG lui-même contribue avec quelques réflexions. Présentation des dias

  7. Western Dilemma

    ScienceCinema (OSTI)

    None

    2011-04-25

    L'association du personnel présente Anthony Sampson, écrivain connu dans le monde entier par ses nombreux ouvrages et publications (International Harold Tribune, Observer, News Week). Il nous parle du commerce des armes et du Moyen Orient.

  8. Impressions on Chinas Popular Republic

    ScienceCinema (OSTI)

    None

    2011-04-25

    Le D.G. Jentschke présente le Prof.Yang, née en 1922 en Chine où il a aussi fait ses études; il parle de ses impressions en Chine (p.e. mariage etc....) avec présentation des dias

  9. E-mail et Web : pour une navigation sans risque

    ScienceCinema (OSTI)

    None

    2011-10-06

    Présentation orale en français, support visuel en anglais. À travers des exemples concrets, vous consoliderez vos connaissances et pourrez ainsi réajuster vos habitudes concernant l?utilisation sécurisée de votre boîte e-mail et de votre navigateur Web.

  10. Problem of Questioning

    ScienceCinema (OSTI)

    None

    2011-04-25

    Le Prof.Leprince-Ringuet, chercheur sur le plan scientifique, artistique et humain, parle de la remise en question des hommes et la remise en question scientifique fondamentale ou exemplaire- plusieurs personnes prennent la parole p.ex Jeanmairet, Adam, Gregory. Le Prof.Gregory clot la soirée en remerciant le Prof.Leprince-Ringuet

  11. KINEMATIC PROPERTIES AS PROBES OF THE EVOLUTION OF DWARF GALAXIES IN THE VIRGO CLUSTER

    SciTech Connect (OSTI)

    Toloba, E.; Gorgas, J.; De Paz, A. Gil; Boselli, A.; Peletier, R. F.; Yildiz, U.; Cenarro, A. J.; Gadotti, D. A.; Pedraz, S.

    2009-12-10

    We present new observational results on the kinematical, morphological, and stellar population properties of a sample of 21 dEs located both in the Virgo Cluster and in the field, which show that 52% of the dEs (1) are rotationally supported, (2) exhibit structural signs of typical rotating systems such as disks, bars, or spiral arms, (3) are younger (approx3 Gyr) than non-rotating dEs, and (4) are preferentially located either in the outskirts of Virgo or in the field. This evidence is consistent with the idea that rotationally supported dwarfs are late-type spirals or irregulars that recently entered the cluster and lost their gas through a ram pressure stripping event, quenching their star formation and becoming dEs through passive evolution. We also find that all, but one, galaxies without photometric hints for hosting disks are pressure supported and are all situated in the inner regions of the cluster. This suggests a different evolution from the rotationally supported systems. Three different scenarios for these non-rotating galaxies are discussed (in situ formation, harassment, and ram pressure stripping).

  12. C.F.von Weizsäcker-High Energy Physics

    ScienceCinema (OSTI)

    None

    2011-04-25

    C.F.von Weizsäcker (1912-2007),physicien,philosophe et "chercheur de paix", prit la décision de faire des études de physique sous l'influence de W.Heisenberg qu'il rencontra en 1927.

  13. Andrei Sakharov

    ScienceCinema (OSTI)

    None

    2011-04-25

    Ce discours donné par Mons.Jonauch qui est né en Tchécoslovaquie et a fait ses études à Leningrad, Moscou et Prague, est organisé par le comité Youri Orlov. Le conférencier parle de Andrei Sakharov, ce physicien et homme soviétique qui fit ses études à Moscou, effectua des recherches sur les armes thermonucléaires et entra à l'Académie des Sciences d'URSS en 1953. Il participa à la mise au point de la bombe à hydrogène, mais s'opposa quelques années plus tard à la poursuite des expériences nucléaires. Il créa en 1970 le comité pour la défense des droits de l'homme ce que lui valut le prix Nobel de la paix en 1975.

  14. Bioactive glass coatings for orthopedic metallic implants

    SciTech Connect (OSTI)

    Lopez-Esteban, Sonia; Saiz, Eduardo; Fujino, Sigheru; Oku, Takeo; Suganuma, Katsuaki; Tomsia, Antoni P.

    2003-06-30

    The objective of this work is to develop bioactive glass coatings for metallic orthopedic implants. A new family of glasses in the SiO2-Na2O-K2O-CaO-MgO-P2O5 system has been synthesized and characterized. The glass properties (thermal expansion, softening and transformation temperatures, density and hardness) are in line with the predictions of established empirical models. The optimized firing conditions to fabricate coatings on Ti-based and Co-Cr alloys have been determined and related to the glass properties and the interfacial reactions. Excellent adhesion to alloys has been achieved through the formation of 100-200 nm thick interfacial layers (Ti5Si3 on Ti-based alloys and CrOx on Co-Cr). Finally, glass coatings, approximately 100 mu m thick, have been fabricated onto commercial Ti alloy-based dental implants.

  15. Investigation of forced and isothermal chemical vapor infiltrated SiC/SiC ceramic matrix composites. Final report

    SciTech Connect (OSTI)

    Sankar, J.; Kelkar, A.D.; Vaidyanathan, R.

    1993-09-01

    Mechanical properties of two different layups for each of the forced CVI (41 specimens) and isothermal CVI (36 specimens) materials were investigated in air at room temperature (RT), 1000C, and at room temperature after thermal shock (RT/TS) and exposure to oxidation (RT/OX). The FCVI specimens had a nominal interfacial coating thickness of 0.3 {mu}m of pyrolytic carbon, while CVI specimens had a coating thickness of 0.1 {mu}m. Effect of reinforcement and interfacial bond on mechanical properties of composite were investigated. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) were employed to analyze the fiber-matrix interface and the toughening mechanisms in this ceramic composite system.

  16. Three-dimensional fully-coupled electrical and thermal transport model of dynamic switching in oxide memristors

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gao, Xujiao; Mamaluy, Denis; Mickel, Patrick R.; Marinella, Matthew

    2015-09-08

    In this paper, we present a fully-coupled electrical and thermal transport model for oxide memristors that solves simultaneously the time-dependent continuity equations for all relevant carriers, together with the time-dependent heat equation including Joule heating sources. The model captures all the important processes that drive memristive switching and is applicable to simulate switching behavior in a wide range of oxide memristors. The model is applied to simulate the ON switching in a 3D filamentary TaOx memristor. Simulation results show that, for uniform vacancy density in the OFF state, vacancies fill in the conduction filament till saturation, and then fill outmore » a gap formed in the Ta electrode during ON switching; furthermore, ON-switching time strongly depends on applied voltage and the ON-to-OFF current ratio is sensitive to the filament vacancy density in the OFF state.« less

  17. Thermal-mechanical properties of epoxy-impregnated Bi-2212/Ag composite

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Li, Pei; Wang, Yang; Fermi National Accelerator Lab.; Godeke, Arno; National High Magnetic Field Lab., Tallahassee, FL; Ye, Liyang; Fermi National Accelerator Lab.; Flanagan, Gene; Shen, Tengming

    2014-11-26

    In this study, knowledge of the thermal-mechanical properties of epoxy/superconductor/insulation composite is important for designing, fabricating, and operating epoxy impregnated high field superconducting magnets near their ultimate potentials. We report measurements of the modulus of elasticity, Poisson's ratio, and the coefficient of thermal contraction of epoxy-impregnated composite made from the state-of-the-art powder-in-tube multifilamentary Ag/Bi2Sr2CaCu2Ox round wire at room temperature and cryogenic temperatures. Stress-strain curves of samples made from single-strand and Rutherford cables were tested under both monotonic and cyclic compressive loads, with single strands insulated using a thin TiO2 insulation coating and the Rutherford cable insulated with a braided ceramicmore » sleeve.« less

  18. Supported catalyst systems and method of making biodiesel products using such catalysts

    DOE Patents [OSTI]

    Kim, Manhoe; Yan, Shuli; Salley, Steven O.; Ng, K. Y. Simon

    2015-10-20

    A heterogeneous catalyst system, a method of preparing the catalyst system and a method of forming a biodiesel product via transesterification reactions using the catalyst system is disclosed. The catalyst system according to one aspect of the present disclosure represents a class of supported mixed metal oxides that include at least calcium oxide and another metal oxide deposited on a lanthanum oxide or cerium oxide support. Preferably, the catalysts include CaO--CeO.sub.2ZLa.sub.2O.sub.3 or CaO--La.sub.2O.sub.3/CeO.sub.2. Optionally, the catalyst may further include additional metal oxides, such as CaO--La.sub.2O.sub.3--GdOxZLa.sub.2O.sub.3.

  19. United States Government

    Energy Savers [EERE]

    .---.-.-.--.- -.--..- Department of Enery y memorandum si!%.rE:.c;. Letter Re,porr on "Sandi;;, Natianai .I:,al-ji~;.utory-?L'::'~~i bIe.xieo Stetdent hitern Saf2i-y Training" INS.-L.-OX-46 ('hspeztion 'i'4o. SOS:IS007:) Mzfiager:, Sandla Size 0fr"ice '7'his I.,etter Xtepor? provid.es the results of an CBffice ofInspec1-or Gel~eriii inspection of the student intern safety P P . O ~ T . ~ I X J af the Dcpaxtn~cnt of Energy's (Di:>Ilys] Srnnr1i.a National X,;ll,r>ratr>ry

  20. Thermally integrated staged methanol reformer and method

    DOE Patents [OSTI]

    Skala, Glenn William (Churchville, NY); Hart-Predmore, David James (Rochester, NY); Pettit, William Henry (Rochester, NY); Borup, Rodney Lynn (East Rochester, NY)

    2001-01-01

    A thermally integrated two-stage methanol reformer including a heat exchanger and first and second reactors colocated in a common housing in which a gaseous heat transfer medium circulates to carry heat from the heat exchanger into the reactors. The heat transfer medium comprises principally hydrogen, carbon dioxide, methanol vapor and water vapor formed in a first stage reforming reaction. A small portion of the circulating heat transfer medium is drawn off and reacted in a second stage reforming reaction which substantially completes the reaction of the methanol and water remaining in the drawn-off portion. Preferably, a PrOx reactor will be included in the housing upstream of the heat exchanger to supplement the heat provided by the heat exchanger.

  1. Argon–germane in situ plasma clean for reduced temperature Ge on Si epitaxy by high density plasma chemical vapor deposition

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Douglas, Erica A.; Sheng, Josephine J.; Verley, Jason C.; Carroll, Malcolm S.

    2015-06-04

    We found that the demand for integration of near infrared optoelectronic functionality with silicon complementary metal oxide semiconductor (CMOS) technology has for many years motivated the investigation of low temperature germanium on silicon deposition processes. Our work describes the development of a high density plasma chemical vapor deposition process that uses a low temperature (<460 °C) in situ germane/argon plasma surface preparation step for epitaxial growth of germanium on silicon. It is shown that the germane/argon plasma treatment sufficiently removes SiOx and carbon at the surface to enable germanium epitaxy. Finally, the use of this surface preparation step demonstrates anmore » alternative way to produce germanium epitaxy at reduced temperatures, a key enabler for increased flexibility of integration with CMOS back-end-of-line fabrication.« less

  2. Short time proton dynamics in bulk ice and in porous anode solid oxide fuel cell materials

    SciTech Connect (OSTI)

    Basoli, Francesco; Senesi, Roberto; Kolesnikov, Alexander I; Licoccia, Silvia

    2014-01-01

    Oxygen reduction and incorporation into solid electrolytes and the reverse reaction of oxygen evolution play a cru-cial role in Solid Oxide Fuel Cell (SOFC) applications. However a detailed un derstanding of the kinetics of the cor-responding reactions, i.e. on reaction mechanisms, rate limiting steps, reaction paths, electrocatalytic role of materials, is still missing. These include a thorough characterization of the binding potentials experienced by protons in the lattice. We report results of Inelastic Neutron Scattering (INS) measurements of the vibrational state of the protons in Ni- YSZ highly porous composites (75% to 90% ), a ceramic-metal material showing a high electrical conductivity and ther mal stability, which is known to be most effectively used as anodes for solid ox ide fuel cells. The results are compared with INS and Deep Inelastic Neutron Scattering (DINS) experiments on the proton binding states in bulk ice.

  3. Detection and characterization of multi-filament evolution during resistive switching

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mickel, Patrick R.; Lohn, Andrew J.; Marinella, Matthew J.

    2014-08-05

    We present resistive switching data in TaOx memristors displaying signatures of multi-filament switching modes, and develop a geometrically defined equivalent circuit to separate the individual resistances and powers dissipated in each filament. Using these resolved values, we compare the individual switching curves of each filament and demonstrate that the switching data of each filament collapse onto a single switching curve determined by the analytical steady-state resistive switching solution for filamentary switching. Analyzing our results in terms of this solution, we determine the switching temperature, heat flow, conductivity, and time evolving areas of each filament during resistive switching. Finally, we discussmore » operational modes which may limit the formation of additional conducting filaments, potentially leading to increased device endurance.« less

  4. Integrated atomistic chemical imaging and reactive force field molecular dynamic simulations on silicon oxidation

    SciTech Connect (OSTI)

    Dumpala, Santoshrupa; Broderick, Scott R.; Rajan, Krishna; Khalilov, Umedjon; Neyts, Erik C.; Duin, Adri C. T. van; Provine, J; Howe, Roger T.

    2015-01-05

    In this paper, we quantitatively investigate with atom probe tomography, the effect of temperature on the interfacial transition layer suboxide species due to the thermal oxidation of silicon. The chemistry at the interface was measured with atomic scale resolution, and the changes in chemistry and intermixing at the interface were identified on a nanometer scale. We find an increase of suboxide (SiOx) concentration relative to SiO{sub 2} and increased oxygen ingress with elevated temperatures. Our experimental findings are in agreement with reactive force field molecular dynamics simulations. This work demonstrates the direct comparison between atom probe derived chemical profiles and atomistic-scale simulations for transitional interfacial layer of suboxides as a function of temperature.

  5. Thermal-mechanical Properties of Epoxy-impregnated Bi-2212/Ag Composite

    SciTech Connect (OSTI)

    Li, Pei [Fermi National Accelerator Laboratory (FNAL), Batavia, IL (United States); Wang, Yang [Fermi National Accelerator Laboratory (FNAL), Batavia, IL (United States); Godeke, Arno [Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States); Ye, Liyang [North Carolina State Univ., Raleigh, NC (United States); Flanagan, Gene [Muons Inc., Batavia, IL (United States); Shen, Tengming [Fermi National Accelerator Laboratory (FNAL), Batavia, IL (United States)

    2014-11-26

    Knowledge of the thermal-mechanical properties of epoxy/superconductor/insulation composite is important for designing, fabricating, and operating epoxy impregnated high field superconducting magnets near their ultimate potentials. We report measurements of the modulus of elasticity, Poisson’s ratio, and the coefficient of thermal contraction of epoxy-impregnated composite made from the state-of-the-art powder-in-tube multifilamentary Ag/Bi2Sr2CaCu2Ox round wire at room temperature and cryogenic temperatures. Stress-strain curves of samples made from single-strand and Rutherford cables were tested under both monotonic and cyclic compressive loads, with single strands insulated using a thin TiO2 insulation coating and the Rutherford cable insulated with a braided ceramic sleeve.

  6. Three-dimensional fully-coupled electrical and thermal transport model of dynamic switching in oxide memristors

    SciTech Connect (OSTI)

    Gao, Xujiao; Mamaluy, Denis; Mickel, Patrick R.; Marinella, Matthew

    2015-09-08

    In this paper, we present a fully-coupled electrical and thermal transport model for oxide memristors that solves simultaneously the time-dependent continuity equations for all relevant carriers, together with the time-dependent heat equation including Joule heating sources. The model captures all the important processes that drive memristive switching and is applicable to simulate switching behavior in a wide range of oxide memristors. The model is applied to simulate the ON switching in a 3D filamentary TaOx memristor. Simulation results show that, for uniform vacancy density in the OFF state, vacancies fill in the conduction filament till saturation, and then fill out a gap formed in the Ta electrode during ON switching; furthermore, ON-switching time strongly depends on applied voltage and the ON-to-OFF current ratio is sensitive to the filament vacancy density in the OFF state.

  7. Le LHC, un tunnel cosmique

    ScienceCinema (OSTI)

    None

    2011-10-06

    Et si la lumière au bout du tunnel du LHC était cosmique ? En d?autres termes, qu?est-ce que le LHC peut nous apporter dans la connaissance de l?Univers ? Car la montée en énergie des accélérateurs de particules nous permet de mieux appréhender l?univers primordial, chaud et dense. Mais dans quel sens dit-on que le LHC reproduit des conditions proches du Big bang ? Quelles informations nous apporte-t-il sur le contenu de l?Univers ? La matière noire est-elle détectable au LHC ? L?énergie noire ? Pourquoi l?antimatière accumulée au CERN est-elle si rare dans l?Univers ? Et si le CERN a bâti sa réputation sur l?exploration des forces faibles et fortes qui opèrent au sein des atomes et de leurs noyaux, est-ce que le LHC peut nous apporter des informations sur la force gravitationnelle qui gouverne l?évolution cosmique ? Depuis une trentaine d?années, notre compréhension de l?univers dans ses plus grandes dimensions et l?appréhension de son comportement aux plus petites distances sont intimement liées : en quoi le LHC va-t-il tester expérimentalement cette vision unifiée ? Tout public, entrée libre / Réservations au +41 (0)22 767 76 76

  8. The Dark Energy Survey Data Management System

    SciTech Connect (OSTI)

    Mohr, Joseph J.; Barkhouse, Wayne; Beldica, Cristina; Bertin, Emmanuel; Dora Cai, Y.; Nicolaci da Costa, Luiz A.; Darnell, J.Anthony; Daues, Gregory E.; Jarvis, Michael; Gower, Michelle; Lin, Huan; /Fermilab /Rio de Janeiro Observ.

    2008-07-01

    The Dark Energy Survey (DES) collaboration will study cosmic acceleration with a 5000 deg2 griZY survey in the southern sky over 525 nights from 2011-2016. The DES data management (DESDM) system will be used to process and archive these data and the resulting science ready data products. The DESDM system consists of an integrated archive, a processing framework, an ensemble of astronomy codes and a data access framework. We are developing the DESDM system for operation in the high performance computing (HPC) environments at the National Center for Supercomputing Applications (NCSA) and Fermilab. Operating the DESDM system in an HPC environment offers both speed and flexibility. We will employ it for our regular nightly processing needs, and for more compute-intensive tasks such as large scale image coaddition campaigns, extraction of weak lensing shear from the full survey dataset, and massive seasonal reprocessing of the DES data. Data products will be available to the Collaboration and later to the public through a virtual-observatory compatible web portal. Our approach leverages investments in publicly available HPC systems, greatly reducing hardware and maintenance costs to the project, which must deploy and maintain only the storage, database platforms and orchestration and web portal nodes that are specific to DESDM. In Fall 2007, we tested the current DESDM system on both simulated and real survey data. We used TeraGrid to process 10 simulated DES nights (3TB of raw data), ingesting and calibrating approximately 250 million objects into the DES Archive database. We also used DESDM to process and calibrate over 50 nights of survey data acquired with the Mosaic2 camera. Comparison to truth tables in the case of the simulated data and internal crosschecks in the case of the real data indicate that astrometric and photometric data quality is excellent.

  9. Identification and overexpression of a knotted1-like transcription factor in switchgrass (Panicum virgatum L.) for lignocellulosic feedstock improvement

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wuddineh, Wegi A.; Mazarei, Mitra; Zhang, Ji -Yi; Turner, Geoffrey B.; Sykes, Robert W.; Decker, Stephen R.; Davis, Mark F.; Udvardi, Michael K.; C. Neal Stewart, Jr.

    2016-04-28

    High biomass production and wide adaptation has made switchgrass (Panicum virgatum L.) an important candidate lignocellulosic bioenergy crop. One major limitation of this and other lignocellulosic feedstocks is the recalcitrance of complex carbohydrates to hydrolysis for conversion to biofuels. Lignin is the major contributor to recalcitrance as it limits the accessibility of cell wall carbohydrates to enzymatic breakdown into fermentable sugars. Therefore, genetic manipulation of the lignin biosynthesis pathway is one strategy to reduce recalcitrance. Here, we identified a switchgrass Knotted1 transcription factor, PvKN1, with the aim of genetically engineering switchgrass for reduced biomass recalcitrance for biofuel production. Gene expressionmore » of the endogenous PvKN1 gene was observed to be highest in young inflorescences and stems. Ectopic overexpression of PvKN1 in switchgrass altered growth, especially in early developmental stages. Transgenic lines had reduced expression of most lignin biosynthetic genes accompanied by a reduction in lignin content suggesting the involvement of PvKN1 in the broad regulation of the lignin biosynthesis pathway. Moreover, the reduced expression of the Gibberellin 20-oxidase (GA20ox) gene in tandem with the increased expression of Gibberellin 2-oxidase (GA2ox) genes in transgenic PvKN1 lines suggest that PvKN1 may exert regulatory effects via modulation of GA signaling. Furthermore, overexpression of PvKN1 altered the expression of cellulose and hemicellulose biosynthetic genes and increased sugar release efficiency in transgenic lines. Our findings demonstrated that switchgrass PvKN1 is a putative ortholog of maize KN1 that is linked to plant lignification and cell wall and development traits as a major regulatory gene. Therefore, targeted overexpression of PvKN1 in bioenergy feedstocks may provide one feasible strategy for reducing biomass recalcitrance and simultaneously improving plant growth characteristics.« less

  10. Italian Exposition

    ScienceCinema (OSTI)

    None

    2011-04-25

    Le DG parle dans son allocution à l'occasion de l'exposition (suivi d'une visite)de la contribution du Cern à la création d'une espace de la technologie européenne. Il parle de la manière comment organiser des formes fructueuses de coopération et coordination internationales dans ce domaine. "Afin de renforcer encore notre relation avec l'industrie et intensifier le transfert de la technologie nous proposerons au ministre de recherche de poursuivre dans le cadre du programme EUREKA ensemble avec les industries des programmes concrètes." Le ministre italien prend ensuite la parole.

  11. 25th Birthday Cern- Restaurant

    ScienceCinema (OSTI)

    None

    2011-04-25

    Cérémonie du 25ème anniversaire du Cern avec plusieurs orateurs et la présence de nombreux autorités cantonales et communales genevoises et personnalités, directeurs généraux, ministres, chercheurs.... Le conseiller féderal et chef du département des affaires étrangères de la confédération Monsieur Pierre Aubert prend la parole pour célébrer à la fois les résultats très remarquables de la coopération internationale en matière scientifique, mais aussi la volonté politique des états européens de mettre en commun leurs ressources pour faire oeuvre d'avenir. Un grand hommage est aussi donné aux deux directeurs disparus, les prof.Bakker et Gregory.

  12. 1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ability of MM5 to Simulate Ice Clouds: Systematic Comparison between Simulated and Measured Fluxes and Lidar/Radar Profiles at Site Instrumental de Recherche par Teled'etrection Armospherique Atmospheric Observatory M. Chiriaco, R. Vautard, H. Chepfer, M. Haeffelin, Y. Wanherdrick, Y. Morille Institut Pierre Simon Laplace Laboratiore de Météorologie Dynamique Palaiseu, France A. Protat Institut Pierre Simon Laplace Centre d'études des Environnements Terrestre et Planétaires Paris, France J.

  13. Hig Resolution Seismometer Insensitive to Extremely Strong Magnetic Fields

    SciTech Connect (OSTI)

    Abramovich, Igor A

    2009-07-14

    A highly sensitive broadband seismic sensor has been developed successfully to be used in beam focusing systems of particale accelerators. The sensor is completely insensitive to extremely strong magnetic fields and to hard radiation conditions that exist at the place of their installation. A unique remote sensor calibration method has been invented and implemented. Several such sensors were sold to LAPP (LAPP-IN2P3/CNRS-Université de Savoie; Laboratoire d'Annecy-le-Vieux de Physique des Particules)

  14. Ward Co. Dunn Co. McLean Co. McHenry Co. Mountrail Co. McKenzie Co.

    U.S. Energy Information Administration (EIA) Indexed Site

    WHISKEY JOE WHITE ASH SPRING COULEE DES LACS MAGPIE HARTLAND BEICEGEL CREEK RANCH COULEE WINNER CRAZY MAN CREEK GROS VENTRE BANK W BULLSNAKE UPLAND COULEE REFUGE LARSON GARNET ALKALI CREEK PLUMER RATTLESNAKE POINT ELLSWORTH CHURCH BORDER HANSON GROVER HULSE COULEE SAKAKAWEA AURELIA ROUND TOP BUTTE GORHAM BUTTE W MARMON MANITOU SHEALEY CLAYTON SERGIS N SADDLE BUTTE HAYLAND CEDAR COULEE BOWLINE LITTLE BUTTE LONG CREEK RHOADES HEDBERG FILLMORE EIDSVOLD FAIRFIELD WOLF BAY TOBACCO GARDEN N SPRING

  15. Lumens: The new way to shop for light

    Energy Savers [EERE]

    Gas Heat Pump For Building Space Heating Low-Cost Gas Heat Pump For Building Space Heating Credit: Stone Mountain Technologies Credit: Stone Mountain Technologies Lead Performer: Stone Mountain Technologies - Erwin, TN Partners: -- A.O. Smith - Milwaukee, WI -- Gas Technology Institute - Des Plaines, IL DOE Funding: $903,000 Cost Share: $232,294 Project Term: 3/1/2013 - 2/28/2015 Funding Opportunity: Energy Savings Through Improved Mechanical Systems and Building Envelope Technologies 2012

  16. Roberta Poloni | Center for Gas SeparationsRelevant to Clean Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Technologies | Blandine Jerome Roberta Poloni Previous Next List Poloni Roberta Poloni Formerly: Postdoctoral Researcher, Department of Chemical & Biomolecular Engineering University of California, Berkeley Presently: Postoctoral Researcher, Laboratoire de Science et Ingéniérie des Matériaux et Procédés, Institut Polytechnique de Grenoble, France Ph.D. in Physics, University of Lyon-1, France BS in Physics, Camerino, Italy EFRC research: Detailed studies on the CO2 locations in

  17. Workplace Charging Challenge Partner: Schneider Electric | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Schneider Electric Workplace Charging Challenge Partner: Schneider Electric Workplace Charging Challenge Partner: Schneider Electric Joined the Challenge: March 2013 Headquarters: Palatine, IL Charging Locations: Cedar Rapids, IA; Palatine, IL; O'Fallon, MO; Des Plaines, IL; Knightdale, NC; West Kingston, RI; North Andover, MA; Billerica, MA; Nashville, TN; LaVergne, TN; Smryna, TN; Clovis, CA; Costa Mesa, CA; Carrollton, TX; Seneca, SC; Lexington, KY; Detroit, MI Domestic Employees:

  18. Low-Cost Gas Heat Pump For Building Space Heating | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Gas Heat Pump For Building Space Heating Low-Cost Gas Heat Pump For Building Space Heating Credit: Stone Mountain Technologies Credit: Stone Mountain Technologies Lead Performer: Stone Mountain Technologies - Erwin, TN Partners: -- A.O. Smith - Milwaukee, WI -- Gas Technology Institute - Des Plaines, IL DOE Funding: $903,000 Cost Share: $232,294 Project Term: March 1, 2013 - August 31, 2015 Funding Opportunity: Energy Savings Through Improved Mechanical Systems and Building Envelope Technologies

  19. History of Cern

    ScienceCinema (OSTI)

    None

    2011-04-25

    Cérémonie à l'occasion de l'apparition du premier volume du livre sur l'histoire du Cern, avec plusieurs personnes présentes qui jouaient un rôle important dans cette organisation européenne couronnée de succès grâce à l'esprit des membres fondateurs qui est et restera essentiel

  20. Nuclear Physics Division Theoretical Study Division

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CEBIT 67-18 Nuclear Physics Division Theoretical Study Division 11 July 1967 ORGANISATION EUROPEENNE POUR LA RECHERCHE NUCLEAIRE C E R N EUROPEAN ORGANIZATION FOR NUCLEAR RESEARCH THE K°K° SYSTEM G. Charpak, CERN, Geneva, Switzerland, and M. Gourdin, Faculty des Sciences, Orsay, Prance. Lectures delivered at the Matscience Institute, Madras, India, December 1966 and January 1967 G E N E V A 1967 (C) Copyright CERN, Geneve, 1967 Propriety litteraire et scientifique r&ervee pour tous les

  1. Inauguration LEP

    ScienceCinema (OSTI)

    None

    2011-04-25

    Le DG H.Schopper salue le président de la république française, F.Mitterand, le président de la confédaration suisse P.Aubert, ainsi que les ministres et représentants du gouvernement des 12 états membres pour la célébration et inauguration du LEP.

  2. Photometric Redshifts for the Dark Energy Survey and VISTA and Implications

    Office of Scientific and Technical Information (OSTI)

    for Large Scale Structure (Journal Article) | SciTech Connect SciTech Connect Search Results Journal Article: Photometric Redshifts for the Dark Energy Survey and VISTA and Implications for Large Scale Structure Citation Details In-Document Search Title: Photometric Redshifts for the Dark Energy Survey and VISTA and Implications for Large Scale Structure We conduct a detailed analysis of the photometric redshift requirements for the proposed Dark Energy Survey (DES) using two sets of mock

  3. DOE - Office of Legacy Management -- Rocky Benefits

    Office of Legacy Management (LM)

    Colorado > Rocky Benefits Rocky Flats Site, Colorado Benefits Administration Rocky Flats Benefits Administration Rocky Flats Benefits Center P.O. Box 10361 Des Moines, IA 50306-0361 Phone - (866) 296-5036 Fax - (888) 501-9768 Medical and Life Insurance Administration Pension Administration General Benefits Questions Death Reporting Address Changes Benefits Issue Resolutions Leanna Nighswonger (509) 373-1419 Leanna_c_Nighswonger@rl.gov Last Updated: 4/11

  4. Torleif Ericson 60th Birthday

    ScienceCinema (OSTI)

    None

    2011-04-25

    Plusieurs discours à l'occasion du 60me anniversaire de Torleif Ericson, physicien né à Lund (Suède), et remerciements pour son travail et son effort de relier la physique des particules à la physique nucléaire. A la fin de la cérémonie un document scientifique de 400 pages "die Festschrift" lui est remis comme cadeau d'anniversaire avec un grand nombre de contributions d'amis etc...

  5. Low-Level Waste Disposal Facility Federal Review Group Manual

    Office of Environmental Management (EM)

    Gas Heat Pump For Building Space Heating Low-Cost Gas Heat Pump For Building Space Heating Credit: Stone Mountain Technologies Credit: Stone Mountain Technologies Lead Performer: Stone Mountain Technologies - Erwin, TN Partners: -- A.O. Smith - Milwaukee, WI -- Gas Technology Institute - Des Plaines, IL DOE Funding: $903,000 Cost Share: $232,294 Project Term: March 1, 2013 - August 31, 2015 Funding Opportunity: Energy Savings Through Improved Mechanical Systems and Building Envelope Technologies

  6. DOE - Office of Legacy Management -- Iowa Army Ammunition Plant - IA 02

    Office of Legacy Management (LM)

    Army Ammunition Plant - IA 02 FUSRAP Considered Sites Iowa Army Ammunition Plant, IA Alternate Name(s): Burlington Ordnance Plant Iowa Ordnance Plant Silas Mason Company IA.02-3 Location: Located in Township 70 North, Range 3 West, Section 32, 5th Principal Meridian, Des Moines County, Burlington, Iowa IA.02-1 IA.02-5 Historical Operations: Assembled nuclear weapons, primarily high explosive components and conducted explosives testing using the high explosive components and depleted uranium. AEC

  7. Conference Salam/Musset

    ScienceCinema (OSTI)

    None

    2011-04-25

    Le DG L.Van Hove introduit le Prof. A.Salam né en 1926 dans l'ouest du Pakistan, un des gagnants du prix nobel de physique de cette année. Célébration de ses contributions théoriques mondialement connues. Après chaque discours, un petit historique est présenté par Paul Musset. Mention honorable aussi pour l'expérience Gargamelle et ses collaborateurs.

  8. Everest

    ScienceCinema (OSTI)

    None

    2011-04-25

    Chris Bonington, est né à Hampstead et a fait des études à University Collège School à Londres et au Royal Military Academy à Sundhorst. Il est un alpiniste mondialement connu qui a fait un grand nombre de premiers ascensions, comme celle de la face sud-ouest de l'Everest avec une équipe de 70 hommes en septembre 1975

  9. ContaCt

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ContaCt The nuclear and materials science research ca- pabilities at LANSCE are operated as a DOE-des- ignated user facility in service to the nation. We provide neutron and proton beams as well as instrumentation and sample environments for basic, applied, industry, and defense-related re- search in nuclear physics and materials science. A yearly call invites proposals for beam time for experiments from other national laboratories, academia, and industry users. Proprietary and nonproprietary

  10. LHC, le Big Bang en éprouvette

    ScienceCinema (OSTI)

    None

    2011-10-06

    Notre compréhension de l?Univers est en train de changer? Bar des Sciences - Tout public Débat modéré par Marie-Odile Montchicourt, journaliste de France Info. Evenement en vidéoconférence entre le Globe de la science et de l?innovation, le bar le Baloard de Montpellier et la Maison des Métallos à Paris. Intervenants au CERN : Philippe Charpentier et Daniel Froideveaux, physiciens au CERN. Intervenants à Paris : Vincent Bontemps, philosophe et chercheur au CEA ; Jacques Arnould, philosophe, historien des sciences et théologien, Jean-Jacques Beineix, réalisateur, producteur, scénariste de cinéma. Intervenants à Montpellier (LPTA) : André Neveu, physicien théoricien et directeur de recherche au CNRS ; Gilbert Moultaka, physicien théoricien et chargé de recherche au CNRS. Partenariat : CERN, CEA, IN2P3, Université MPL2 (LPTA) Dans le cadre de la Fête de la science 2008

  11. Modeling the transfer function for the Dark Energy Survey

    SciTech Connect (OSTI)

    Chang, C.; Busha, M. T.; Wechsler, R. H.; Refregier, A.; Amara, A.; Rykoff, E.; Becker, M. R.; Bruderer, C.; Gamper, L.; Leistedt, B.; Peiris, H.; Abbott, T.; Abdalla, F. B.; Balbinot, E.; Banerji, M.; Bernstein, R. A.; Bertin, E.; Brooks, D.; Carnero, A.; Desai, S.; da Costa, L. N.; Cunha, C. E.; Eifler, T.; Evrard, A. E.; Fausti Neto, A.; Gerdes, D.; Gruen, D.; James, D.; Kuehn, K.; Maia, M. A. G.; Makler, M.; Ogando, R.; Plazas, A.; Sanchez, E.; Santiago, B.; Schubnell, M.; Sevilla-Noarbe, I.; Smith, C.; Soares-Santos, M.; Suchyta, E.; Swanson, M. E. C.; Tarle, G.; Zuntz, J.

    2015-03-04

    We present a forward-modelling simulation framework designed to model the data products from the Dark Energy Survey (DES). This forward-model process can be thought of as a transfer function – a mapping from cosmological and astronomical signals to the final data products used by the scientists. Using output from the cosmological simulations (the Blind Cosmology Challenge), we generate simulated images (the Ultra Fast Image Simulator, Berge et al. 2013) and catalogs representative of the DES data. In this work we simulate the 244 deg2 coadd images and catalogs in 5 bands for the DES Science Verification (SV) data. The simulation output is compared with the corresponding data to show that major characteristics of the images and catalogs can be captured. We also point out several directions of future improvements. Two practical examples, star/galaxy classification and proximity effects on object detection, are then used to demonstrate how one can use the simulations to address systematics issues in data analysis. With clear understanding of the simplifications in our model, we show that one can use the simulations side-by-side with data products to interpret the measurements. This forward modelling approach is generally applicable for other upcoming and future surveys. As a result, it provides a powerful tool for systematics studies which is sufficiently realistic and highly controllable.

  12. The geometric factor of electrostatic plasma analyzers: A case study from the Fast Plasma Investigation for the Magnetospheric Multiscale mission

    SciTech Connect (OSTI)

    Collinson, Glyn A.; Dorelli, John C.; Moore, Thomas E.; Pollock, Craig; Mariano, Al; Shappirio, Mark D.; Adrian, Mark L.; Avanov, Levon A.; Lewis, Gethyn R.; Kataria, Dhiren O.; Bedington, Robert; Owen, Christopher J.; Walsh, Andrew P.; Arridge, Chris S.; Gliese, Ulrik; Barrie, Alexander C.; Tucker, Corey

    2012-03-15

    We report our findings comparing the geometric factor (GF) as determined from simulations and laboratory measurements of the new Dual Electron Spectrometer (DES) being developed at NASA Goddard Space Flight Center as part of the Fast Plasma Investigation on NASA's Magnetospheric Multiscale mission. Particle simulations are increasingly playing an essential role in the design and calibration of electrostatic analyzers, facilitating the identification and mitigation of the many sources of systematic error present in laboratory calibration. While equations for laboratory measurement of the GF have been described in the literature, these are not directly applicable to simulation since the two are carried out under substantially different assumptions and conditions, making direct comparison very challenging. Starting from first principles, we derive generalized expressions for the determination of the GF in simulation and laboratory, and discuss how we have estimated errors in both cases. Finally, we apply these equations to the new DES instrument and show that the results agree within errors. Thus we show that the techniques presented here will produce consistent results between laboratory and simulation, and present the first description of the performance of the new DES instrument in the literature.

  13. Ultra-broadband 2D electronic spectroscopy of carotenoid-bacteriochlorophyll interactions in the LH1 complex of a purple bacterium

    SciTech Connect (OSTI)

    Maiuri, Margherita; Réhault, Julien; Polli, Dario; Cerullo, Giulio; Carey, Anne-Marie; Hacking, Kirsty; Cogdell, Richard J.; Garavelli, Marco; Lüer, Larry

    2015-06-07

    We investigate the excitation energy transfer (EET) pathways in the photosynthetic light harvesting 1 (LH1) complex of purple bacterium Rhodospirillum rubrum with ultra-broadband two-dimensional electronic spectroscopy (2DES). We employ a 2DES apparatus in the partially collinear geometry, using a passive birefringent interferometer to generate the phase-locked pump pulse pair. This scheme easily lends itself to two-color operation, by coupling a sub-10 fs visible pulse with a sub-15-fs near-infrared pulse. This unique pulse combination allows us to simultaneously track with extremely high temporal resolution both the dynamics of the photoexcited carotenoid spirilloxanthin (Spx) in the visible range and the EET between the Spx and the B890 bacterio-chlorophyll (BChl), whose Q{sub x} and Q{sub y} transitions peak at 585 and 881 nm, respectively, in the near-infrared. Global analysis of the one-color and two-color 2DES maps unravels different relaxation mechanisms in the LH1 complex: (i) the initial events of the internal conversion process within the Spx, (ii) the parallel EET from the first bright state S{sub 2} of the Spx towards the Q{sub x} state of the B890, and (iii) the internal conversion from Q{sub x} to Q{sub y} within the B890.

  14. Modeling the Transfer Function for the Dark Energy Survey

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chang, C.

    2015-03-04

    We present a forward-modeling simulation framework designed to model the data products from the Dark Energy Survey (DES). This forward-model process can be thought of as a transfer function—a mapping from cosmological/astronomical signals to the final data products used by the scientists. Using output from the cosmological simulations (the Blind Cosmology Challenge), we generate simulated images (the Ultra Fast Image Simulator) and catalogs representative of the DES data. In this work we demonstrate the framework by simulating the 244 deg2 coadd images and catalogs in five bands for the DES Science Verification data. The simulation output is compared with themore » corresponding data to show that major characteristics of the images and catalogs can be captured. We also point out several directions of future improvements. Two practical examples—star-galaxy classification and proximity effects on object detection—are then used to illustrate how one can use the simulations to address systematics issues in data analysis. With clear understanding of the simplifications in our model, we show that one can use the simulations side-by-side with data products to interpret the measurements. This forward modeling approach is generally applicable for other upcoming and future surveys. It provides a powerful tool for systematics studies that is sufficiently realistic and highly controllable.« less

  15. Modeling the transfer function for the Dark Energy Survey

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chang, C.; Busha, M. T.; Wechsler, R. H.; Refregier, A.; Amara, A.; Rykoff, E.; Becker, M. R.; Bruderer, C.; Gamper, L.; Leistedt, B.; et al

    2015-03-04

    We present a forward-modelling simulation framework designed to model the data products from the Dark Energy Survey (DES). This forward-model process can be thought of as a transfer function – a mapping from cosmological and astronomical signals to the final data products used by the scientists. Using output from the cosmological simulations (the Blind Cosmology Challenge), we generate simulated images (the Ultra Fast Image Simulator, Berge et al. 2013) and catalogs representative of the DES data. In this work we simulate the 244 deg2 coadd images and catalogs in 5 bands for the DES Science Verification (SV) data. The simulationmore »output is compared with the corresponding data to show that major characteristics of the images and catalogs can be captured. We also point out several directions of future improvements. Two practical examples, star/galaxy classification and proximity effects on object detection, are then used to demonstrate how one can use the simulations to address systematics issues in data analysis. With clear understanding of the simplifications in our model, we show that one can use the simulations side-by-side with data products to interpret the measurements. This forward modelling approach is generally applicable for other upcoming and future surveys. As a result, it provides a powerful tool for systematics studies which is sufficiently realistic and highly controllable.« less

  16. Plate-Based Fuel Processing System Final Report

    SciTech Connect (OSTI)

    Carlos Faz; Helen Liu; Jacques Nicole; David Yee

    2005-12-22

    On-board reforming of liquid fuels into hydrogen is an enabling technology that could accelerate consumer usage of fuel cell powered vehicles. The technology would leverage the convenience of the existing gasoline fueling infrastructure while taking advantage of the fuel cell efficiency and low emissions. Commercial acceptance of on-board reforming faces several obstacles that include: (1) startup time, (2) transient response, and (3) system complexity (size, weight and cost). These obstacles are being addressed in a variety of projects through development, integration and optimization of existing fuel processing system designs. In this project, CESI investigated steam reforming (SR), water-gas-shift (WGS) and preferential oxidation (PrOx) catalysts while developing plate reactor designs and hardware where the catalytic function is integrated into a primary surface heat exchanger. The plate reactor approach has several advantages. The separation of the reforming and combustion streams permits the reforming reaction to be conducted at a higher pressure than the combustion reaction, thereby avoiding costly gas compression for combustion. The separation of the two streams also prevents the dilution of the reformate stream by the combustion air. The advantages of the plate reactor are not limited to steam reforming applications. In a WGS or PrOx reaction, the non-catalytic side of the plate would act as a heat exchanger to remove the heat generated by the exothermic WGS or PrOx reactions. This would maintain the catalyst under nearly isothermal conditions whereby the catalyst would operate at its optimal temperature. Furthermore, the plate design approach results in a low pressure drop, rapid transient capable and attrition-resistant reactor. These qualities are valued in any application, be it on-board or stationary fuel processing, since they reduce parasitic losses, increase over-all system efficiency and help perpetuate catalyst durability. In this program, CESI took the initial steam reforming plate-reactor concept and advanced it towards an integrated fuel processing system. A substantial amount of modeling was performed to guide the catalyst development and prototype hardware design and fabrication efforts. The plate-reactor mechanical design was studied in detail to establish design guidelines which would help the plate reactor survive the stresses of repeated thermal cycles (from start-ups and shut-downs). Integrated system performance modeling was performed to predict system efficiencies and determine the parameters with the most significant impact on efficiency. In conjunction with the modeling effort, a significant effort was directed towards catalyst development. CESI developed a highly active, sulfur tolerant, coke resistant, precious metal based reforming catalyst. CESI also developed its own non-precious metal based water-gas shift catalyst and demonstrated the catalysts durability over several thousands of hours of testing. CESI also developed a unique preferential oxidation catalyst capable of reducing 1% CO to < 10 ppm CO over a 35 C operating window through a single pass plate-based reactor. Finally, CESI combined the modeling results and steam reforming catalyst development efforts into prototype hardware. The first generation 3kW(e) prototype was fabricated from existing heat-exchanger plates to expedite the fabrication process. This prototype demonstrated steady state operation ranging from 5 to 100% load conditions. The prototype also demonstrated a 20:1 turndown ratio, 10:1 load transient operation and rapid start-up capability.

  17. La supraconductivité a 100 ans !

    ScienceCinema (OSTI)

    None

    2011-10-06

    Il y a 100 ans, le 8 avril 1911, une découverte majeure était réalisée : celle de la supraconductivité. La supraconductivité est la caractéristique qu?ont certains métaux et alliages de perdre toute résistance électrique en dessous d?une température donnée. Cette renversante découverte, réalisée de manière presque fortuite par Kammerlingh Onnes de l?Université de Leyde (Pays-Bas) et son étudiant Gilles Holst, a ouvert un nouveau champ de recherche en physique et de fabuleuses perspectives d?applications technologiques. Du point de vue scientifique, la supraconductivité est en effet l?une des rares manifestations de la physique quantique à l?échelle macroscopique.  Du point de vue des retombées techniques, elle est porteuse d?applications majeures dans le domaine de la santé, des communications et de l?énergie. 100 ans après, les physiciens n?ont toujours pas fini d?explorer ce phénomène et ses applications. Le CERN abrite des applications de la supraconductivité à des échelles inédites. L?accélérateur de particules LHC, avec ses milliers d?aimants supraconducteurs répartis sur 27 kilomètres de circonférence, est en effet la plus grande application mondiale de la supraconductivité. Il ne pourrait exister sans elle.  Le CERN fête donc la découverte de la supraconductivité avec une conférence exceptionnelle donnée par Philippe Lebrun. Au cours de cette conférence, l?expérience historique de Kammerlingh Onnes sera reproduite. Philippe Lebrun racontera l?histoire de cette étonnante découverte, en la replaçant dans le contexte scientifique de l?époque. Il racontera les développements scientifiques et les applications du premier siècle de la supraconductivité. Conférence en français Merci de bien vouloir vous inscrire au : +41 22 767 76 76 ou cern.reception@cern.ch

  18. Hydroxylation of p-substituted phenols by tyrosinase: Further insight into the mechanism of tyrosinase activity

    SciTech Connect (OSTI)

    Munoz-Munoz, Jose Luis; Berna, Jose; Garcia-Molina, Maria del Mar; Garcia-Molina, Francisco; Garcia-Ruiz, Pedro Antonio; Varon, Ramon [Departamento de Quimica-Fisica, Escuela de Ingenieros Industriales de Albacete, Universidad de Castilla la Mancha, Avda. Espana s and others

    2012-07-27

    Highlights: Black-Right-Pointing-Pointer The action the copper complexes and tyrosinase on phenols is equivalent. Black-Right-Pointing-Pointer Isotope effect showed that nucleophilic attack to copper atom may be the slower step. Black-Right-Pointing-Pointer The value of {rho} (Hammett constant) supports an electrophilic aromatic substitution. Black-Right-Pointing-Pointer Data obtained in steady state pH 7 conditions support the mechanism of Scheme 1SM. -- Abstract: A study of the monophenolase activity of tyrosinase by measuring the steady state rate with a group of p-substituted monophenols provides the following kinetic information: k{sub cat}{sup m} and the Michaelis constant, K{sub M}{sup m}. Analysis of these data taking into account chemical shifts of the carbon atom supporting the hydroxyl group ({delta}) and {sigma}{sub p}{sup +}, enables a mechanism to be proposed for the transformation of monophenols into o-diphenols, in which the first step is a nucleophilic attack on the copper atom on the form E{sub ox} (attack of the oxygen of the hydroxyl group of C-1 on the copper atom) followed by an electrophilic attack (attack of the hydroperoxide group on the ortho position with respect to the hydroxyl group of the benzene ring, electrophilic aromatic substitution with a reaction constant {rho} of -1.75). These steps show the same dependency on the electronic effect of the substituent groups in C-4. Furthermore, a study of a solvent deuterium isotope effect on the oxidation of monophenols by tyrosinase points to an appreciable isotopic effect. In a proton inventory study with a series of p-substituted phenols, the representation of k{sub cat}{sup f{sub n}}/k{sub cat}{sup f{sub 0}} against n (atom fractions of deuterium), where k{sub cat}{sup f{sub n}} is the catalytic constant for a molar fraction of deuterium (n) and k{sub cat}{sup f{sub 0}} is the corresponding kinetic parameter in a water solution, was linear for all substrates. These results indicate that only one of the proton transfer processes from the hydroxyl groups involved the catalytic cycle is responsible for the isotope effects. We suggest that this step is the proton transfer from the hydroxyl group of C-1 to the peroxide of the oxytyrosinase form (E{sub ox}). After the nucleophilic attack, the incorporation of the oxygen in the benzene ring occurs by means of an electrophilic aromatic substitution mechanism in which there is no isotopic effect.

  19. The Superconductors That Magnets Really Want: What Stands in the Way? (Superconductors for Accelerator Use: What Next and How Close is the Ideal Conductor?)

    ScienceCinema (OSTI)

    Larbalestier, David [National High Magnetic Field Laboratory] [Florida State University, Tallahassee, Florida, United States

    2010-01-08

    There are over 5000 superconducting materials but only about 5 have ever been useful for applications in magnets, while HEP, which has been so vital for the development of superconducting magnet technology has made virtually every magnet out of just one, the simple bcc alloy Nb-Ti with Tc of 9 K and upper critical field ~ 14T (at 2K). Significant demonstrations of the capability of the brittle intermetallic Nb3Sn have shown that fields of more than 15 T can be generated in dipole form. But Nb-Ti and Nb3Sn are staid, conventional superconductors, far from the cutting edge of superconducting science research where cuprates like YBa2Cu3O7-x and Bi2Sr2CaCu2Ox remain at the scientific forefront and in 2008 were joined by the recently discovered Fe-As pnictide superconductors. What could it mean to have materials for magnets with 10 times the Tc of Nb-Ti (90-120 K) and 3 or more times the critical field (100-240 T)? One enormous barrier is that higher Tc so far always means more complexity and a more localized superconducting interaction which is sensitive to local loss of superconductivity. The issue that has made the cuprate high temperature superconductors so hard to apply is that grain boundaries which form a 3D network in any practical wire form, easily acquire degraded superconducting properties. But conductors can now be made with extreme texture so that grain boundaries are minimized. Moreover almost practical conductors of Bi2Sr2CaCu2Ox and YBa2Cu3O7-x are now are in production and in late 2008 we were, at the Magnet Lab, able to make small solenoids operating at high current density in fields of 32 and almost 34 T respectively. Within the HEP community, there is enthusiasm to embrace HTS conductors for new very high field machines that could, like the Muon Collider, use fields of 30-50 T. In my talk I would like to explore the underlying science controlling such potential applications.

  20. Piano-stool lutetium amido and imido compounds supported by a constrained bis(oxazoline)cyclopentadienyl ligand

    SciTech Connect (OSTI)

    Lampland, Nicole L.; Zhu, Jing; Hovey, Megan; Jana, Barun; Ellern, Arkady; Sadow, Aaron D.

    2015-06-25

    {BoMCptet}Lu(CH2Ph)2 (1; BoMCptet = MeC(OxMe2 2C5Me4; OxMe2 = 4,4-dimethyl-2-oxazoline) was prepared in 95% yield from the reaction of BoMCptetH and Lu(CH2Ph)3THF3. Compound 1 reacts with 1 or 2 equiv of H2NCH2R (R = C6H5, 1-C10H7) to give the corresponding imido complexes [{BoMCptet}LuNCH2R]2 (R = C6H5 (2a), 1-C10H7 (2b)) or amido complexes {BoMCptet}Lu(NHCH2R)2 (R = C6H5 (3a), 1-C10H7 (3b)). When isolated, the imido species are insoluble in nonprotic organic solvents. Crystallographic characterization reveals dimeric [{BoMCptet}LuNCH2(1-C10H7)]2 in the solid state. The reaction of 1 and NH3B(C6F5)3 affords crystallographically characterized {BoMCptet}Lu{NHB(C6F5)2}C6F5. This species is proposed to form via a transient lutetium imido, which undergoes C6F5 migration to the lutetium center.

  1. Broad Temperature Pinning Study of 15 mol.% Zr-Added (Gd, Y)-Ba-Cu-O MOCVD Coated Conductors

    SciTech Connect (OSTI)

    Xu, AX; Khatri, N; Liu, YH; Majkic, G; Galstyan, E; Selvamanickam, V; Chen, YM; Lei, CH; Abraimov, D; Hu, XB; Jaroszynski, J; Larbalestier, D

    2015-06-01

    BaZrO3 (BZO) nanocolumns have long been shown to be very effective for raising the pinning force F-p of REBa2Cu3Ox (REBCO, where RE = rare earth) films at high temperatures and recently at low temperatures too. We have successfully incorporated a high density of BZO nanorods into metal organic chemical vapor deposited (MOCVD) REBCO coated conductors via Zr addition. We found that, compared to the 7.5% Zr-added coated conductor, dense BZO nanorod arrays in the 15% Zr-added conductor are effective over the whole temperature range from 77 K down to 4.2 K. We attribute the substantially enhanced J(c) at 30 K to the weak uncorrelated pinning as well as the strong correlated pinning. Meanwhile, by tripling the REBCO layer thickness to similar to 2.8 mu m, the engineering critical current density J(e) at 30 K exceeds J(e) of optimized Nb-Ti wires at 4.2 K.

  2. Strain control of oxygen vacancies in epitaxial strontium cobaltite films

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jeen, Hyoung Jeen; Choi, Woo Seok; Reboredo, Fernando A.; Freeland, John W.; Eres, Gyula; Lee, Ho Nyung; Petrie, Jonathan R.; Mitra, Chandrima; Meyer, Tricia L.

    2016-01-25

    In this study, the ability to manipulate oxygen anion defects rather than metal cations in complex oxides can facilitate creating new functionalities critical for emerging energy and device technologies. However, the difficulty in activating oxygen at reduced temperatures hinders the deliberate control of important defects, oxygen vacancies. Here, strontium cobaltite (SrCoOx) is used to demonstrate that epitaxial strain is a powerful tool for manipulating the oxygen vacancy concentration even under highly oxidizing environments and at annealing temperatures as low as 300 °C. By applying a small biaxial tensile strain (2%), the oxygen activation energy barrier decreases by ≈30%, resulting inmore » a tunable oxygen deficient steady-state under conditions that would normally fully oxidize unstrained cobaltite. These strain-induced changes in oxygen stoichiometry drive the cobaltite from a ferromagnetic metal towards an antiferromagnetic insulator. The ability to decouple the oxygen vacancy concentration from its typical dependence on the operational environment is useful for effectively designing oxides materials with a specific oxygen stoichiometry.« less

  3. Atomistic Insights Into the Oriented Attachment of Tunnel-Based Oxide Nanostructures

    SciTech Connect (OSTI)

    Yuan, Yifei; Wood, Stephen M; He, Kun; Yao, Wentao; Tompsett, David; Lu, Jun; Nie, Anmin; Islam, M. Saiful; Shahbazian-Yassar, Reza

    2016-01-01

    Controlled synthesis of nanomaterials is one of the grand challenges facing materials scientists. In particular, how tunnel-based nanomaterials aggregate during synthesis while maintaining their well-aligned tunneled structure is not fully understood. Here, we describe the atomistic mechanism of oriented attachment (OA) during solution synthesis of tunneled α-MnO2 nanowires based on a combination of in situ liquid cell transmission electron microscopy (TEM), aberration-corrected scanning TEM with subangstrom spatial resolution, and first-principles calculations. It is found that primary tunnels (1 × 1 and 2 × 2) attach along their common {110} lateral surfaces to form interfaces corresponding to 2 × 3 tunnels that facilitate their short-range ordering. The OA growth of α-MnO2 nanowires is driven by the stability gained from elimination of {110} surfaces and saturation of Mn atoms at {110}-edges. During this process, extra [MnOx] radicals in solution link the two adjacent {110} surfaces and bond with the unsaturated Mn atoms from both surface edges to produce stable nanowire interfaces. Our results provide insights into the controlled synthesis and design of nanomaterials in which tunneled structures can be tailored for use in catalysis, ion exchange, and energy storage applications.

  4. The effect of Fe-Rh alloying on CO hydrogenation to C2+ oxygenates

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Palomino, Robert; Magee, Joseph W.; Llorca, Jordi; Senanayake, Sanjaya D.; White, Michael G.

    2015-05-20

    A combination of reactivity and structural studies using X-ray diffraction (XRD), pair distribution function (PDF), and transmission electron microscopy (TEM) was used to identify the active phases of Fe-modified Rh/TiO2 catalysts for the synthesis of ethanol and other C2+ oxygenates from CO hydrogenation. XRD and TEM confirm the existence of Fe–Rh alloys for catalyst with 1–7 wt% Fe and ~2 wt% Rh. Rietveld refinements show that FeRh alloy content increases with Fe loading up to ~4 wt%, beyond which segregation to metallic Fe becomes favored over alloy formation. Catalysts that contain Fe metal after reduction exhibit some carburization as evidencedmore »by the formation of small amounts of Fe3C during CO hydrogenation. Analysis of the total Fe content of the catalysts also suggests the presence of FeOx also increased under reaction conditions. Reactivity studies show that enhancement of ethanol selectivity with Fe loading is accompanied by a significant drop in CO conversion. Comparison of the XRD phase analyses with selectivity suggests that higher ethanol selectivity is correlated with the presence of Fe–Rh alloy phases. As a result, the interface between Fe and Rh serves to enhance the selectivity of ethanol, but suppresses the activity of the catalyst which is attributed to the blocking or modifying of Rh active sites.« less

  5. Pseudo-capacitor device for aqueous electrolytes

    DOE Patents [OSTI]

    Prakash, J.; Thackeray, M.M.; Dees, D.W.; Vissers, D.R.; Myles, K.M.

    1998-11-24

    A pseudo-capacitor having a high energy storage capacity develops a double layer capacitance as well as a Faradaic or battery-like redox reaction, also referred to as pseudo-capacitance. The Faradaic reaction gives rise to a capacitance much greater than that of the typical ruthenate oxide ultracapacitor which develops only charge separation-based double layer capacitance. The capacitor employs a lead and/or bismuth/ruthenate and/or iridium system having the formula A{sub 2}[B{sub 2{minus}x}Pb{sub x}]O{sub 7{minus}y}, where A=Pb, Bi, and B=Ru, Ir, and O{<=}1 and O

  6. Polyacrylamide medium for the electrophoretic separation of biomolecules

    DOE Patents [OSTI]

    Madabhushi, Ramakrishna S.; Gammon, Stuart A.

    2003-11-11

    A polyacryalmide medium for the electrophoretic separation of biomolecules. The polyacryalmide medium comprises high molecular weight polyacrylamides (PAAm) having a viscosity average molecular weight (M.sub.v) of about 675-725 kDa were synthesized by conventional red-ox polymerization technique. Using this separation medium, capillary electrophoresis of BigDye DNA sequencing standard was performed. A single base resolution of .about.725 bases was achieved in .about.60 minute in a non-covalently coated capillary of 50 .mu.m i.d., 40 cm effective length, and a filed of 160 V/cm at 40.degree. C. The resolution achieved with this formulation to separate DNA under identical conditions is much superior (725 bases vs. 625 bases) and faster (60 min. vs. 75 min.) to the commercially available PAAm, such as supplied by Amersham. The formulation method employed here to synthesize PAAm is straight-forward, simple and does not require cumbersome methods such as emulsion polymerizaiton in order to achieve very high molecular weights. Also, the formulation here does not require separation of PAAm from the reaction mixture prior to reconstituting the polymer to a final concentration. Furthermore, the formulation here is prepared from a single average mol. wt. PAAm as opposed to the mixture of two different average mo. wt. PAAm previously required to achieve high resolution.

  7. Acid Strength and Bifunctional Catalytic Behavior of Alloys Comprised of Noble Metals and Oxophilic Metal Promoters

    SciTech Connect (OSTI)

    Hibbitts, David D.; Tan, Qiaohua; Neurock, Matthew

    2014-06-01

    The promotion of metal catalysts with partially oxidized oxophilic MOx species, such as ReOx-promoted Rh, has been demonstrated to produce Brønsted acid sites that can promote hydrogenolysis of oxygenate intermediates such as those found in biomass-derived species. A wide variety of alloy compositions and structures are examined in this work to investigate strongly acidic promoters by using DFT-calculated deprotonation energies (DPE) as a measure of acid strength. Sites with the highest acid strength had DPE less than 1100 kJ mol-1, similar to DPE values of heteropolyacids or acid-containing zeolites, and were found on alloys composed of an oxophilic metal (such as Re or W) with a noble metal (such as Rh or Pt). NH3 adsorbs more strongly to sites with increasing acid strength and the activation barriers for acid-catalyzed ring opening of a furan ring decrease with increasing acid strength, which was also shown to be stronger for OH acid sites bound to multiple oxophilic metal atoms in a three-fold configuration rather than OH sites adsorbed in an atop configuration on one oxophilic metal, indicating that small MOx clusters may yield sites with the highest acid strength.

  8. Electronic properties of quasi one-dimensional quantum wire models under equal coupling strength superpositions of Rashba and Dresselhaus spin-orbit interactions in the presence of an in-plane magnetic field

    SciTech Connect (OSTI)

    Papp, E.; Micu, C.; Racolta, D.

    2013-11-13

    In this paper one deals with the theoretical derivation of energy bands and of related wavefunctions characterizing quasi 1D semiconductor heterostructures, such as InAs quantum wire models. Such models get characterized this time by equal coupling strength superpositions of Rashba and Dresselhaus spin-orbit interactions of dimensionless magnitude a under the influence of in-plane magnetic fields of magnitude B. We found that the orientations of the field can be selected by virtue of symmetry requirements. For this purpose one resorts to spin conservations, but alternative conditions providing sensible simplifications of the energy-band formula can be reasonably accounted for. Besides the wavenumber k relying on the 1D electron, one deals with the spin-like s=±1 factors in the front of the square root term of the energy. Having obtained the spinorial wavefunction, opens the way to the derivation of spin precession effects. For this purpose one resorts to the projections of the wavenumber operator on complementary spin states. Such projections are responsible for related displacements proceeding along the Ox-axis. This results in a 2D rotation matrix providing both the precession angle as well as the precession axis.

  9. Ultrafast nanolaser device for detecting cancer in a single live cell.

    SciTech Connect (OSTI)

    Gourley, Paul Lee; McDonald, Anthony Eugene

    2007-11-01

    Emerging BioMicroNanotechnologies have the potential to provide accurate, realtime, high throughput screening of live tumor cells without invasive chemical reagents when coupled with ultrafast laser methods. These optically based methods are critical to advancing early detection, diagnosis, and treatment of disease. The first year goals of this project are to develop a laser-based imaging system integrated with an in- vitro, live-cell, micro-culture to study mammalian cells under controlled conditions. In the second year, the system will be used to elucidate the morphology and distribution of mitochondria in the normal cell respiration state and in the disease state for normal and disease states of the cell. In this work we designed and built an in-vitro, live-cell culture microsystem to study mammalian cells under controlled conditions of pH, temp, CO2, Ox, humidity, on engineered material surfaces. We demonstrated viability of cell culture in the microsystem by showing that cells retain healthy growth rates, exhibit normal morphology, and grow to confluence without blebbing or other adverse influences of the material surfaces. We also demonstrated the feasibility of integrating the culture microsystem with laser-imaging and performed nanolaser flow spectrocytometry to carry out analysis of the cells isolated mitochondria.

  10. The effect of Fe-Rh alloying on CO hydrogenation to C2+ oxygenates

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Palomino, Robert; Magee, Joseph W.; Llorca, Jordi; Senanayake, Sanjaya D.; White, Michael G.

    2015-05-20

    A combination of reactivity and structural studies using X-ray diffraction (XRD), pair distribution function (PDF), and transmission electron microscopy (TEM) was used to identify the active phases of Fe-modified Rh/TiO2 catalysts for the synthesis of ethanol and other C2+ oxygenates from CO hydrogenation. XRD and TEM confirm the existence of Fe–Rh alloys for catalyst with 1–7 wt% Fe and ~2 wt% Rh. Rietveld refinements show that FeRh alloy content increases with Fe loading up to ~4 wt%, beyond which segregation to metallic Fe becomes favored over alloy formation. Catalysts that contain Fe metal after reduction exhibit some carburization as evidencedmore » by the formation of small amounts of Fe3C during CO hydrogenation. Analysis of the total Fe content of the catalysts also suggests the presence of FeOx also increased under reaction conditions. Reactivity studies show that enhancement of ethanol selectivity with Fe loading is accompanied by a significant drop in CO conversion. Comparison of the XRD phase analyses with selectivity suggests that higher ethanol selectivity is correlated with the presence of Fe–Rh alloy phases. As a result, the interface between Fe and Rh serves to enhance the selectivity of ethanol, but suppresses the activity of the catalyst which is attributed to the blocking or modifying of Rh active sites.« less

  11. Comparison of growth texture in round Bi2212 and flat Bi2223 wires and its relation to high critical current density development

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kametani, F.; Jiang, J.; Matras, M.; Abraimov, D.; Hellstrom, E. E.; Larbalestier, D. C.

    2015-02-10

    Why Bi₂Sr₂CaCu₂Ox (Bi2212) allows high critical current density Jc in round wires rather than only in the anisotropic tape form demanded by all other high temperature superconductors is important for future magnet applications. Here we compare the local texture of state-of-the-art Bi2212 and Bi2223 ((Bi,Pb)₂Sr₂Ca₂Cu₃O₁₀), finding that round wire Bi2212 generates a dominant a-axis growth texture that also enforces a local biaxial texture (FWHM <15°) while simultaneously allowing the c-axes of its polycrystals to rotate azimuthally along and about the filament axis so as to generate macroscopically isotropic behavior. By contrast Bi2223 shows only a uniaxial (FWHM <15°) c-axis texturemore » perpendicular to the tape plane without any in-plane texture. Consistent with these observations, a marked, field-increasing, field-decreasing Jc(H) hysteresis characteristic of weak-linked systems appears in Bi2223 but is absent in Bi2212 round wire. Growth-induced texture on cooling from the melt step of the Bi2212 Jc optimization process appears to be the key step in generating this highly desirable microstructure.« less

  12. Atmospheric Dispersion Effects in Weak Lensing Measurements

    SciTech Connect (OSTI)

    Plazas, Andrés Alejandro; Bernstein, Gary

    2012-10-01

    The wavelength dependence of atmospheric refraction causes elongation of finite-bandwidth images along the elevation vector, which produces spurious signals in weak gravitational lensing shear measurements unless this atmospheric dispersion is calibrated and removed to high precision. Because astrometric solutions and PSF characteristics are typically calibrated from stellar images, differences between the reference stars' spectra and the galaxies' spectra will leave residual errors in both the astrometric positions (dr) and in the second moment (width) of the wavelength-averaged PSF (dv) for galaxies.We estimate the level of dv that will induce spurious weak lensing signals in PSF-corrected galaxy shapes that exceed the statistical errors of the DES and the LSST cosmic-shear experiments. We also estimate the dr signals that will produce unacceptable spurious distortions after stacking of exposures taken at different airmasses and hour angles. We also calculate the errors in the griz bands, and find that dispersion systematics, uncorrected, are up to 6 and 2 times larger in g and r bands,respectively, than the requirements for the DES error budget, but can be safely ignored in i and z bands. For the LSST requirements, the factors are about 30, 10, and 3 in g, r, and i bands,respectively. We find that a simple correction linear in galaxy color is accurate enough to reduce dispersion shear systematics to insignificant levels in the r band for DES and i band for LSST,but still as much as 5 times than the requirements for LSST r-band observations. More complex corrections will likely be able to reduce the systematic cosmic-shear errors below statistical errors for LSST r band. But g-band effects remain large enough that it seems likely that induced systematics will dominate the statistical errors of both surveys, and cosmic-shear measurements should rely on the redder bands.

  13. Assessment of Systematic Chromatic Errors that Impact Sub-1% Photometric Precision in Large-Area Sky Surveys

    SciTech Connect (OSTI)

    Li, T.S.; et al.

    2016-01-01

    Meeting the science goals for many current and future ground-based optical large-area sky surveys requires that the calibrated broadband photometry is stable in time and uniform over the sky to 1% precision or better. Past surveys have achieved photometric precision of 1-2% by calibrating the survey's stellar photometry with repeated measurements of a large number of stars observed in multiple epochs. The calibration techniques employed by these surveys only consider the relative frame-by-frame photometric zeropoint offset and the focal plane position-dependent illumination corrections, which are independent of the source color. However, variations in the wavelength dependence of the atmospheric transmission and the instrumental throughput induce source color-dependent systematic errors. These systematic errors must also be considered to achieve the most precise photometric measurements. In this paper, we examine such systematic chromatic errors using photometry from the Dark Energy Survey (DES) as an example. We define a natural magnitude system for DES and calculate the systematic errors on stellar magnitudes, when the atmospheric transmission and instrumental throughput deviate from the natural system. We conclude that the systematic chromatic errors caused by the change of airmass in each exposure, the change of the precipitable water vapor and aerosol in the atmosphere over time, and the non-uniformity of instrumental throughput over the focal plane, can be up to 2% in some bandpasses. We compare the calculated systematic chromatic errors with the observed DES data. For the test sample data, we correct these errors using measurements of the atmospheric transmission and instrumental throughput. The residual after correction is less than 0.3%. We also find that the errors for non-stellar objects are redshift-dependent and can be larger than those for stars at certain redshifts.

  14. Atmospheric Dispersion Effects in Weak Lensing Measurements

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Plazas, Andrés Alejandro; Bernstein, Gary

    2012-10-01

    The wavelength dependence of atmospheric refraction causes elongation of finite-bandwidth images along the elevation vector, which produces spurious signals in weak gravitational lensing shear measurements unless this atmospheric dispersion is calibrated and removed to high precision. Because astrometric solutions and PSF characteristics are typically calibrated from stellar images, differences between the reference stars' spectra and the galaxies' spectra will leave residual errors in both the astrometric positions (dr) and in the second moment (width) of the wavelength-averaged PSF (dv) for galaxies.We estimate the level of dv that will induce spurious weak lensing signals in PSF-corrected galaxy shapes that exceed themore » statistical errors of the DES and the LSST cosmic-shear experiments. We also estimate the dr signals that will produce unacceptable spurious distortions after stacking of exposures taken at different airmasses and hour angles. We also calculate the errors in the griz bands, and find that dispersion systematics, uncorrected, are up to 6 and 2 times larger in g and r bands,respectively, than the requirements for the DES error budget, but can be safely ignored in i and z bands. For the LSST requirements, the factors are about 30, 10, and 3 in g, r, and i bands,respectively. We find that a simple correction linear in galaxy color is accurate enough to reduce dispersion shear systematics to insignificant levels in the r band for DES and i band for LSST,but still as much as 5 times than the requirements for LSST r-band observations. More complex corrections will likely be able to reduce the systematic cosmic-shear errors below statistical errors for LSST r band. But g-band effects remain large enough that it seems likely that induced systematics will dominate the statistical errors of both surveys, and cosmic-shear measurements should rely on the redder bands.« less

  15. No Galaxy Left Behind: Accurate Measurements with the Faintest Objects in the Dark Energy Survey

    SciTech Connect (OSTI)

    Suchyta, E.

    2015-07-29

    Accurate statistical measurement with large imaging surveys has traditionally required throwing away a sizable fraction of the data. This is because most measurements have have relied on selecting nearly complete samples, where variations in the composition of the galaxy population with seeing, depth, or other survey characteristics are small. We introduce a new measurement method that aims to minimize this wastage, allowing precision measurement for any class of stars or galaxies detectable in an imaging survey. We have implemented our proposal in Balrog, a software package which embeds fake objects in real imaging in order to accurately characterize measurement biases. We also demonstrate this technique with an angular clustering measurement using Dark Energy Survey (DES) data. We first show that recovery of our injected galaxies depends on a wide variety of survey characteristics in the same way as the real data. We then construct a flux-limited sample of the faintest galaxies in DES, chosen specifically for their sensitivity to depth and seeing variations. Using the synthetic galaxies as randoms in the standard LandySzalay correlation function estimator suppresses the effects of variable survey selection by at least two orders of magnitude. Now our measured angular clustering is found to be in excellent agreement with that of a matched sample drawn from much deeper, higherresolution space-based COSMOS imaging; over angular scales of 0.004° < ? < 0.2 ° , we find a best-fit scaling amplitude between the DES and COSMOS measurements of 1.00 ± 0.09. We expect this methodology to be broadly useful for extending the statistical reach of measurements in a wide variety of coming imaging surveys.

  16. Comparative study of microwave radiation-induced magnetoresistive oscillations induced by circularly- and linearly- polarized photo-excitation

    SciTech Connect (OSTI)

    Ye, Tianyu; Liu, Han -Chun; Wang, Zhuo; Wegscheider, W.; Mani, Ramesh G.

    2015-10-09

    A comparative study of the radiation-induced magnetoresistance oscillations in the high mobility GaAs/AlGaAs heterostructure two dimensional electron system (2DES) under linearly- and circularly- polarized microwave excitation indicates a profound difference in the response observed upon rotating the microwave launcher for the two cases, although circularly polarized microwave radiation induced magnetoresistance oscillations observed at low magnetic fields are similar to the oscillations observed with linearly polarized radiation. For the linearly polarized radiation, the magnetoresistive response is a strong sinusoidal function of the launcher rotation (or linear polarization) angle, θ. As a result, for circularly polarized radiation, the oscillatory magnetoresistive response is hardly sensitive to θ.

  17. Tuning the Formations of Metal-Organic Frameworks by Modification of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ratio of Reactant, Acidity of Reaction System, and Use of a Secondary Ligand | Center for Gas SeparationsRelevant to Clean Energy Technologies | Blandine Jerome Tuning the Formations of Metal-Organic Frameworks by Modification of Ratio of Reactant, Acidity of Reaction System, and Use of a Secondary Ligand Previous Next List Qian Gao, Ya-Bo Xie, Jian-Rong Li, Da-Qiang Yuan, Audrey A. Yakovenko, Ji-Hong Sun, and Hong-Cai Zhou, Cryst. Growth Des., 2012, 12 (1), pp 281-288 DOI: 10.1021/cg201059d

  18. ORISE: Dose Coefficients for Intakes of Radionuclides via Contaminated Wounds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Dose CoeffiCients for intakes of raDionuCliDes via ContaminateD WounDs R. E. Toohey*, L. Bertelli + , S. L. Sugarman*, A. L. Wiley* and D. M. Christensen* *Radiation Emergency Assistance Center/Training Site, Oak Ridge Institute for Science and Education, Oak Ridge, TN 37031-0117; + Radiation Protection Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545. Ver. 2, Aug 2014 The NCRP Wound Model describing the retention of selected radionuclides at the site of a contaminated

  19. Modeling of dielectric elastomer as electromechanical resonator

    SciTech Connect (OSTI)

    Li, Bo Liu, Lei; Chen, Hualing; Jia, Shuhai; Zhang, Junshi; Li, Dichen

    2014-09-28

    Dielectric elastomers (DEs) feature nonlinear dynamics resulting from an electromechanical coupling. Under alternating voltage, the DE resonates with tunable performances. We present an analysis of the nonlinear dynamics of a DE as electromechanical resonator (DEER) configured as a pure shear actuator. A theoretical model is developed to characterize the complex performance under different boundary conditions. Physical mechanisms are presented and discussed. Chaotic behavior is also predicted, illustrating instabilities in the dynamics. The results provide a guide to the design and application of DEER in haptic devices.

  20. American Socient of Safety Engineers offers Ergonomic Tips for Businesses, Home

    Broader source: Energy.gov [DOE]

    DES PLAINES, IL (March 28, 2002) - With workplace musculoskeletal disorders (MSDs) being the single largest occupational safety and health problem in the U.S. according to the National Institute of Occupational Safety and Health, the American Society of Safety Engineers (ASSE) urges employers to develop and implement now an effective ergonomic system to reduce those injuries. An initial investment in ergonomic programs removes barriers to quality, productivity and human performance by fitting products, tasks, and environments to people and in the long run will save millions later.

  1. Final Report for the Scaled Asynchronous Transfer Mode (ATM) Encryption Laboratory Directed Research and Development Project

    SciTech Connect (OSTI)

    Pierson, L.G.; Witzke, E.L.

    1999-01-01

    This effort studied the integration of innovative methods of key management crypto synchronization, and key agility while scaling encryption speed. Viability of these methods for encryption of ATM cell payloads at the SONET OC- 192 data rate (10 Gb/s), and for operation at OC-48 rates (2.5 Gb/s) was shown. An SNL-Developed pipelined DES design was adapted for the encryption of ATM cells. A proof-of-principle prototype circuit board containing 11 Electronically Programmable Logic Devices (each holding the equivalent of 100,000 gates) was designed, built, and used to prototype a high speed encryptor.

  2. ESMC

    ScienceCinema (OSTI)

    None

    2011-04-25

    Workshops de 2 jours au Cern: 1.partie: communication scientifique: plusieurs discours suivis de questions et intenses discussions: 1.François de Closet "le progrès scientifique" 2.Gerhard Moosleiter(?) exposé avec dias et questions 3.H.Meyers "comment créer de meilleures conditions en communication scientifique 2.partie: science et communication :présentation des dias et questions. Une Russe de Moscou parle entre autre de la situation actuelle de la presse scientifique en Russie 3.partie: conclusions et rapports de la veille de differents groupes de travail 4.partie:questions avec C.Rubbia et N.Calder et remerciements

  3. NETL F 451.1/1-1, Categorical Exclusion Designation Form

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    FE0023577 Gas Technology Institu Multiple states, CAN (1)Gas Technology Institute, Canoga Park, CA & Des Plaines, IL;(2)RTI International, Research Triangle Park, NC; (3)Nexant,Inc, San Francisco, CA;(4)Coanda R&D, Burnaby, BC, Canada; and (5)Aerojet Rocketdyne, Canoga Park, CA FE/TDIC/Coal/AES Team K. David Lyons Adv. Gasifier and Water Gas Shift Techs for Low Cost Coal Conv to High-H2 Syngas Address remaining risks associated w/ compact gasifier design for first-of-a-kind commercially-

  4. Ceremony 25th birthday Cern

    ScienceCinema (OSTI)

    None

    2011-04-25

    Célébration du 25ème anniversaire du Cern (jour par jour) avec discours de L.Van Hove et J.B.Adams, des interludes musicals offerts par Mme Mey et ses collègues (au debut 1.mouvement du quatuor avec piano no 3 de L.van Beethoven) Les directeurs généraux procéderont à la remise du souvenir aux membres de personnel ayant 25 années de service dans l'organisation. Un témoignage de reconnaissance est auss fait à l'interprète Mme Zwerner

  5. Memorial V.J.Glaser

    ScienceCinema (OSTI)

    None

    2011-04-25

    Plusieurs orateurs rendent hommage au grand physicien et scientifique Vladimir Jurko Glaser (1924 - 1984) qui travaillait au Ruder Boscovic Institut à Zagreb avant de venir au Cern en 1957 où il trouvait un poste permanent au département de physique théorique. Walter Tearing, Harry Lehmann,Henry Epstein, Jacques Bros et André Martin font des résumés biographiques de leurs collègue et ami en honorant ses grands qualités d'homme et ses remarquables conquêtes de la science et leurs accomplissement.

  6. ENERGY OF THE DEFECTS INDUCED BY NEUTRON IRRADIATION IN MgO. (Journal

    Office of Scientific and Technical Information (OSTI)

    Article) | SciTech Connect ENERGY OF THE DEFECTS INDUCED BY NEUTRON IRRADIATION IN MgO. Citation Details In-Document Search Title: ENERGY OF THE DEFECTS INDUCED BY NEUTRON IRRADIATION IN MgO. (in French) Authors: Roux, A. ; Elston, J. Publication Date: 1970-01-01 OSTI Identifier: 4170057 Resource Type: Journal Article Resource Relation: Journal Name: Compt. Rend., Ser. C 270: 505-8(9 Feb 1970).; Other Information: Orig. Receipt Date: 31-DEC-70 Research Org: Institut National des Sciences

  7. DOE - Office of Legacy Management -- Mound_Benefits

    Office of Legacy Management (LM)

    Ohio > Mound_Benefits Mound, Ohio, Site Former Workers' Employment Verification and Benefits Administration Contractor Employment Verification Mercer, Mound Benefits Center (866) 296-5036 Medical and Life Insurance for Former EG&G, BWXTO, and CH2M HILL Employees For questions about health insurance coverage and/or dependent information, life insurance and/or beneficiaries, etc.: Mound Benefits Center P.O. Box 10361 Des Moines, IA 50306-0361 Benefit Center Website (866) 296-5036 9:00 a.m.

  8. How to Find Ames Laboratory | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    How to Find Ames Laboratory Finding the Ames Laboratory The Ames Laboratory has it's main administrative offices in the Technical and Administrative Services Facility (TASF) building on the Iowa State University Campus. For directions, please use the GPS coordinates 42.0305° N, 93.6482° W. For directions from the Des Moines Airport please use the link with the following directions: https://goo.gl/maps/c6SOK Finding the Ames Laboratory on the ISU Campus Image Click on the map to download a

  9. Los Alamos National Laboratory * Est. 1943 The Pulse-Newsletter of the Los Alamos Neutron Science Center and Accelerator Operations and Technology Division

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 Los Alamos National Laboratory * Est. 1943 The Pulse-Newsletter of the Los Alamos Neutron Science Center and Accelerator Operations and Technology Division I N S I D E 2 From Alex's Desk 3 lujAn Center reseArCh FeAtureD on Cover oF Langmuir 4 FunCtionAl oxiDes unDer extreme ConDi- tions-quest For new mAteriAls 6 heADs uP! By Diana Del Mauro ADEPS Communications Inside the Lujan Neutron Scattering Center, Victor Fanelli is busy preparing a superconducting magnet. In a series of delicate steps,

  10. Open University

    ScienceCinema (OSTI)

    None

    2011-04-25

    Michel Pentz est née en Afrique du Sud et venu au Cern en 1957 comme physicien et président de l'associaion du personnel. Il est également fondateur du mouvement Antiapartheid de Genève et a participé à la fondation de l'Open University en Grande-Bretagne. Il nous parle des contextes pédagogiques, culturels et nationaux dans lesquels la méthode peut s'appliquer.

  11. Summary - SRS Salt Waste Processing Facility

    Office of Environmental Management (EM)

    SRS Co DOE S Proces concen actinid in a se remov adjustm sorben sorben solutio passed separa stream extract sufficie separa (with S vitrifica (DWP Sr/acti federa assure and ha Critica The te (CTE) descrip Readin The Ele Site: S roject: S F Report Date: J ited States Why DOE omposite High Lev Savannah Rive ssing Facility (S ntrate targeted des) from High eries of unit ope ved by contactin ment) with a m nt in a batch m nt (containing S on by cross flow d to a solvent e ated to an aque m. The bulk

  12. Isolated spinach ribulose-1,5-bisphosphate carboxylase/oxgenase large subunit .epsilon. n-methyltransferase and method of inactivating ribulose-1,5-bishosphatase .epsilon. n-methyltransferase activity

    DOE Patents [OSTI]

    Houtz, Robert L.

    2001-01-01

    The gene sequence for ribulose-1,5-bisphosphate carboxylase/oxygenase (Rubisco) large subunit (LS) .sup..epsilon. N-methyltansferase (protein methylase III or Rubisco LSMT) from a plant which has a des(methyl) lysyl residue in the LS is disclosed. In addition, the full-length cDNA clones for Rubisco LSMT are disclosed. Transgenic plants and methods of producing same which have the Rubisco LSMT gene inserted into the DNA are also provided. Further, methods of inactivating the enzymatic activity of Rubisco LSMT are also disclosed.

  13. Isolated spinach ribulose-1,5-bisphosphate carboxylase/oxygenase large subunit .sup..epsilon. N-methyltransferase and method of inactivating ribulose-1,5-bisphosphatase carboxylase/oxygenase large subunit .sup..epsilon. N-methyltransferase activity

    DOE Patents [OSTI]

    Houtz, Robert L.

    1999-01-01

    The gene sequence for ribulose-1,5-bisphosphate carboxylase/oxygenase (Rubisco) large subunit (LS) .sup..epsilon. N-methyltransferase (protein methylase III or Rubisco LSMT) from a plant which has a des(methyl) lysyl residue in the LS is disclosed. In addition, the full-length cDNA clones for Rubisco LSMT are disclosed. Transgenic plants and methods of producing same which have the Rubisco LSMT gene inserted into the DNA are also provided. Further, methods of inactivating the enzymatic activity of Rubisco LSMT are also disclosed.

  14. L'Aventure du LHC

    ScienceCinema (OSTI)

    None

    2011-10-06

    Cette présentation s?adressera principalement aux personnes qui ont construit le LHC. La construction du LHC fut longue et difficile. De nombreux problèmes sont apparus en cours de route. Tous ont été résolus grâce au dévouement et à l?engagement du personnel et des collaborateurs. Je reviendrai sur les coups durs et les réussites qui ont marqués ces 15 dernières années et je vous montrerai combien cette machine, le fruit de vos efforts, est extraordinaire.

  15. F.S.V.B. Volleyball

    ScienceCinema (OSTI)

    None

    2011-04-25

    22me assemblée des délégués de la Fédération Suisse de Volley Ball (F.S.V.B.), en présence entre autres de Claude Delay, représentant de la société fédérale de gymnastique et Hans Gauer, représentant de l'association suisse de gymnastique féminine. Annonce d'une démonstration d'un mini match de volley ball à Meyrin dans l'après-midi.

  16. 2015HSSB Resultsbracket

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    13 21 3 4 14 5 6 15 22 7 8 16 27 9 10 11 12 L 15 23 L 16 18 L 13 19 L 14 20 24 17 L 21 25 L 22 26 28 L 27 29 30 CHAMPIONSHIP Champion ______________________ Runner-up _______________________ Third Place ____________________________ Fourth Place ___________________________ Challenger Bracket Undefeated Bracket Science Bowl 2016 Double Elimination Competition Central Lee #2 Prince of Peace (withdrew) Valley 94 Ames 50 Grinnell 52 Shenandoah 26 Des Moines Central 78 Lynnville-Sully 8 Boyer Valley

  17. The Dark Energy Survey Camera (DECam)

    SciTech Connect (OSTI)

    Diehl, H.Thomas; /Fermilab

    2011-09-09

    The Dark Energy Survey (DES) is a next generation optical survey aimed at understanding the expansion rate of the Universe using four complementary methods: weak gravitational lensing, galaxy cluster counts, baryon acoustic oscillations, and Type Ia supernovae. To perform the survey, the DES Collaboration is building the Dark Energy Camera (DECam), a 3 square degree, 570 Megapixel CCD camera that will be mounted at the prime focus of the Blanco 4-meter telescope at the Cerro Tololo Inter-American Observatory. CCD production has finished, yielding roughly twice the required 62 2k x 4k detectors. The construction of DECam is nearly finished. Integration and commissioning on a 'telescope simulator' of the major hardware and software components, except for the optics, recently concluded at Fermilab. Final assembly of the optical corrector has started at University College, London. Some components have already been received at CTIO. 'First-light' will be sometime in 2012. This oral presentation concentrates on the technical challenges involved in building DECam (and how we overcame them), and the present status of the instrument.

  18. Influence of the support of CoMo sulfide catalysts and of the addition of potassium and platinum on the catalytic performances for the hydrodeoxygenation of carbonyl, carboxyl, and guaiacol-type molecules

    SciTech Connect (OSTI)

    Centeno, A.; Laurent, E.; Delmon, B. [Universite Catholique de Louvain, Louvain-la-Neuve (Belgium)] [Universite Catholique de Louvain, Louvain-la-Neuve (Belgium)

    1995-07-01

    The present work corresponds to part of a program aimed at upgrading oil obtained by pyrolysis of biomass by hydrotreatment (hydrodeoxygenation HDO). CoMo sulfide catalysts, nonsupported, supported on different supports (alumina, carbon, silica), or modified by K or Pt, were used. The authors used a model reacting mixture containing compounds representative of the molecules that must react to permit a primary stabilisation of the pyrolytic oil: 4-methy lacetophenone (4-MA), diethylsebacate (DES), and guaiacol (GUA). In the reaction of the carbonyl group of the 4-MA it is shown that no important role is played by any acid-base mechanism; dispersion determines the activity. Acidity of the support influences the formation of active sites for decarboxylation and hydrogenation of the carboxyl group of DES. It was confirmed that guaiacol-type molecules lead to coking reactions. The role of acidity in the mechanism of these reactions is confirmed, but the modifications made in the catalysts in this work are still not sufficient to control coke deposition. The catalysts supported on carbon lead to the direct elimination of the methoxyl group of the guaiacol. Carbon, on the whole, seems to be a promising support. This work suggests that appropriate modifications of the hydrotreating catalysts can lead to a more effective process for stabilisation of the bio-oils by reaction with hydrogen. 55 refs., 3 figs., 5 tabs.

  19. Cooling the dark energy camera instrument

    SciTech Connect (OSTI)

    Schmitt, R.L.; Cease, H.; DePoy, D.; Diehl, H.T.; Estrada, J.; Flaugher, B.; Kuhlmann, S.; Onal, Birce; Stefanik, A.; /Fermilab

    2008-06-01

    DECam, camera for the Dark Energy Survey (DES), is undergoing general design and component testing. For an overview see DePoy, et al in these proceedings. For a description of the imager, see Cease, et al in these proceedings. The CCD instrument will be mounted at the prime focus of the CTIO Blanco 4m telescope. The instrument temperature will be 173K with a heat load of 113W. In similar applications, cooling CCD instruments at the prime focus has been accomplished by three general methods. Liquid nitrogen reservoirs have been constructed to operate in any orientation, pulse tube cryocoolers have been used when tilt angles are limited and Joule-Thompson or Stirling cryocoolers have been used with smaller heat loads. Gifford-MacMahon cooling has been used at the Cassegrain but not at the prime focus. For DES, the combined requirements of high heat load, temperature stability, low vibration, operation in any orientation, liquid nitrogen cost and limited space available led to the design of a pumped, closed loop, circulating nitrogen system. At zenith the instrument will be twelve meters above the pump/cryocooler station. This cooling system expected to have a 10,000 hour maintenance interval. This paper will describe the engineering basis including the thermal model, unbalanced forces, cooldown time, the single and two-phase flow model.

  20. Wide-field lensing mass maps from Dark Energy Survey science verification data: Methodology and detailed analysis

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Vikram, V.

    2015-07-29

    Weak gravitational lensing allows one to reconstruct the spatial distribution of the projected mass density across the sky. These “mass maps” provide a powerful tool for studying cosmology as they probe both luminous and dark matter. In this paper, we present a weak lensing mass map reconstructed from shear measurements in a 139 deg2 area from the Dark Energy Survey (DES) science verification data. We compare the distribution of mass with that of the foreground distribution of galaxies and clusters. The overdensities in the reconstructed map correlate well with the distribution of optically detected clusters. We demonstrate that candidate superclustersmore » and voids along the line of sight can be identified, exploiting the tight scatter of the cluster photometric redshifts. We cross-correlate the mass map with a foreground magnitude-limited galaxy sample from the same data. Our measurement gives results consistent with mock catalogs from N-body simulations that include the primary sources of statistical uncertainties in the galaxy, lensing, and photo-z catalogs. The statistical significance of the cross-correlation is at the 6.8σ level with 20 arcminute smoothing. We find that the contribution of systematics to the lensing mass maps is generally within measurement uncertainties. In this study, we analyze less than 3% of the final area that will be mapped by the DES; the tools and analysis techniques developed in this paper can be applied to forthcoming larger data sets from the survey.« less

  1. Automated transient identification in the Dark Energy Survey

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Goldstein, D. A.; D'Andrea, C. B.; Fischer, J. A.; Foley, R. J.; Gupta, R. R.; Kessler, R.; Kim, A. G.; Nichol, R. C.; Nungent, P.; Papadopoulos, A.; et al

    2015-09-01

    We describe an algorithm for identifying point-source transients and moving objects on reference-subtracted optical images containing artifacts of processing and instrumentation. The algorithm makes use of the supervised machine learning technique known as Random Forest. We present results from its use in the Dark Energy Survey Supernova program (DES-SN), where it was trained using a sample of 898,963 signal and background events generated by the transient detection pipeline. After reprocessing the data collected during the first DES-SN observing season (2013 September through 2014 February) using the algorithm, the number of transient candidates eligible for human scanning decreased by a factormore » of 13.4, while only 1.0% of the artificial Type Ia supernovae (SNe) injected into search images to monitor survey efficiency were lost, most of which were very faint events. Furthermore, we characterize the algorithm's performance in detail, and we discuss how it can inform pipeline design decisions for future time-domain imaging surveys, such as the Large Synoptic Survey Telescope and the Zwicky Transient Facility.« less

  2. Eight new Milky Way companions discovered in first-year Dark Energy Survey data

    SciTech Connect (OSTI)

    Bechtol, K.; et al.

    2015-06-30

    We report the discovery of eight new Milky Way companions in $\\sim 1800\\;{\\mathrm{deg}}^{2}$ of optical imaging data collected during the first year of the Dark Energy Survey (DES). Each system is identified as a statistically significant over-density of individual stars consistent with the expected isochrone and luminosity function of an old and metal-poor stellar population. The objects span a wide range of absolute magnitudes (MV from $-2.2$ to $-7.4\\;\\mathrm{mag}$), physical sizes ($10-170\\;\\mathrm{pc}$), and heliocentric distances ($30-330\\;\\mathrm{kpc}$). Based on the low surface brightnesses, large physical sizes, and/or large Galactocentric distances of these objects, several are likely to be new ultra-faint satellite galaxies of the Milky Way and/or Magellanic Clouds. We introduce a likelihood-based algorithm to search for and characterize stellar over-densities, as well as identify stars with high satellite membership probabilities. As a result, we also present completeness estimates for detecting ultra-faint galaxies of varying luminosities, sizes, and heliocentric distances in the first-year DES data.

  3. Eight new Milky Way companions discovered in first-year Dark Energy Survey data

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bechtol, K.

    2015-06-30

    We report the discovery of eight new Milky Way companions inmore » $$\\sim 1800\\;{\\mathrm{deg}}^{2}$$ of optical imaging data collected during the first year of the Dark Energy Survey (DES). Each system is identified as a statistically significant over-density of individual stars consistent with the expected isochrone and luminosity function of an old and metal-poor stellar population. The objects span a wide range of absolute magnitudes (MV from $-2.2$ to $$-7.4\\;\\mathrm{mag}$$), physical sizes ($$10-170\\;\\mathrm{pc}$$), and heliocentric distances ($$30-330\\;\\mathrm{kpc}$$). Based on the low surface brightnesses, large physical sizes, and/or large Galactocentric distances of these objects, several are likely to be new ultra-faint satellite galaxies of the Milky Way and/or Magellanic Clouds. We introduce a likelihood-based algorithm to search for and characterize stellar over-densities, as well as identify stars with high satellite membership probabilities. As a result, we also present completeness estimates for detecting ultra-faint galaxies of varying luminosities, sizes, and heliocentric distances in the first-year DES data.« less

  4. Automated transient identification in the Dark Energy Survey

    SciTech Connect (OSTI)

    Goldstein, D. A.

    2015-08-20

    We describe an algorithm for identifying point-source transients and moving objects on reference-subtracted optical images containing artifacts of processing and instrumentation. The algorithm makes use of the supervised machine learning technique known as Random Forest. We present results from its use in the Dark Energy Survey Supernova program (DES-SN), where it was trained using a sample of 898,963 signal and background events generated by the transient detection pipeline. After reprocessing the data collected during the first DES-SN observing season (2013 September through 2014 February) using the algorithm, the number of transient candidates eligible for human scanning decreased by a factor of 13.4, while only 1.0 percent of the artificial Type Ia supernovae (SNe) injected into search images to monitor survey efficiency were lost, most of which were very faint events. Here we characterize the algorithm's performance in detail, and we discuss how it can inform pipeline design decisions for future time-domain imaging surveys, such as the Large Synoptic Survey Telescope and the Zwicky Transient Facility.

  5. Automated transient identification in the Dark Energy Survey

    SciTech Connect (OSTI)

    Goldstein, D. A.; D'Andrea, C. B.; Fischer, J. A.; Foley, R. J.; Gupta, R. R.; Kessler, R.; Kim, A. G.; Nichol, R. C.; Nungent, P.; Papadopoulos, A.; Sako, M.; Smith, M.; Sullivan, M.; Thomas, R. C.; Wester, W.; Wolf, R. C.; Abdalla, F. B.; Banjeri, M.; Benoit-Levy, A.; Bertin, E.; Brooks, D.; Rosell, A. Carnero; Castander, F. J.; da Costa, L. N.; Covarrubias, R.; DePoy, D. L.; Desai, S.; Diehl, H. T.; Doel, P.; Eifler, T. F.; Neto, A. Fausti; Finley, D. A.; Flaugher, B.; Fosalba, P.; Frieman, J.; Gerdes, D.; Gruen, D.; Gruendl, R. A.; James, D.; Kuehn, K.; Kuropatkin, N.; Lahav, O.; Li, T. S.; Maia, M. A. G.; Makler, M.; March, M.; Marshall, J. L.; Martini, P.; Merritt, K. W.; Miquel, R.; Nord, B.; Ogando, R.; Plazas, A. A.; Romer, A. K.; Roodman, A.; Sanchez, E.; Scarpine, V.; Schubnell, M.; Sevilla-Noarbe, I.; Smith, R. C.; Soares-Santos, M.; Sobreira, F.; Suchyta, E.; Swanson, M. E. C.; Tarle, G.; Thaler, J.; Walker, A. R.

    2015-09-01

    We describe an algorithm for identifying point-source transients and moving objects on reference-subtracted optical images containing artifacts of processing and instrumentation. The algorithm makes use of the supervised machine learning technique known as Random Forest. We present results from its use in the Dark Energy Survey Supernova program (DES-SN), where it was trained using a sample of 898,963 signal and background events generated by the transient detection pipeline. After reprocessing the data collected during the first DES-SN observing season (2013 September through 2014 February) using the algorithm, the number of transient candidates eligible for human scanning decreased by a factor of 13.4, while only 1.0% of the artificial Type Ia supernovae (SNe) injected into search images to monitor survey efficiency were lost, most of which were very faint events. Furthermore, we characterize the algorithm's performance in detail, and we discuss how it can inform pipeline design decisions for future time-domain imaging surveys, such as the Large Synoptic Survey Telescope and the Zwicky Transient Facility.

  6. Enhancing Complex System Performance Using Discrete-Event Simulation

    SciTech Connect (OSTI)

    Allgood, Glenn O; Olama, Mohammed M; Lake, Joe E

    2010-01-01

    In this paper, we utilize discrete-event simulation (DES) merged with human factors analysis to provide the venue within which the separation and deconfliction of the system/human operating principles can occur. A concrete example is presented to illustrate the performance enhancement gains for an aviation cargo flow and security inspection system achieved through the development and use of a process DES. The overall performance of the system is computed, analyzed, and optimized for the different system dynamics. Various performance measures are considered such as system capacity, residual capacity, and total number of pallets waiting for inspection in the queue. These metrics are performance indicators of the system's ability to service current needs and respond to additional requests. We studied and analyzed different scenarios by changing various model parameters such as the number of pieces per pallet ratio, number of inspectors and cargo handling personnel, number of forklifts, number and types of detection systems, inspection modality distribution, alarm rate, and cargo closeout time. The increased physical understanding resulting from execution of the queuing model utilizing these vetted performance measures identified effective ways to meet inspection requirements while maintaining or reducing overall operational cost and eliminating any shipping delays associated with any proposed changes in inspection requirements. With this understanding effective operational strategies can be developed to optimally use personnel while still maintaining plant efficiency, reducing process interruptions, and holding or reducing costs.

  7. Discovery of a stellar overdensity in Eridanus-Phoenix in the dark energy survey

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Li, T. S.; Balbinot, E.; Mondrik, N.; Marshall, J. L.; Yanny, B.; Bechtol, K.; Drlica-Wagner, A.; Oscar, D.; Santiago, B.; Simon, J. D.; et al

    2016-01-27

    We report the discovery of an excess of main sequence turn-off stars in the direction of the constellations of Eridanus and Phoenix from the first year data of the Dark Energy Survey (DES). The Eridanus-Phoenix (EriPhe) overdensity is centered around l~285 deg and b~-60 deg and spans at least 30 deg in longitude and 10 deg in latitude. The Poisson significance of the detection is at least 9 sigma. The stellar population in the overdense region is similar in brightness and color to that of the nearby globular cluster NGC 1261, indicating that the heliocentric distance of EriPhe is aboutmore » d~16 kpc. The extent of EriPhe in projection is therefore at least ~4 kpc by ~3 kpc. On the sky, this overdensity is located between NGC 1261 and a new stellar stream discovered by DES at a similar heliocentric distance, the so-called Phoenix Stream. Given their similar distance and proximity to each other, it is possible that these three structures may be kinematically associated. Alternatively, the EriPhe overdensity is morphologically similar to the Virgo overdensity and the Hercules-Aquila cloud, which also lie at a similar Galactocentric distance. These three overdensities lie along a polar plane separated by ~120 deg and may share a common origin. Spectroscopic follow-up observations of the stars in EriPhe are required to fully understand the nature of this overdensity.« less

  8. TIDAL INTERACTION AS THE ORIGIN OF EARLY-TYPE DWARF GALAXIES IN GROUP ENVIRONMENTS

    SciTech Connect (OSTI)

    Paudel, Sanjaya; Ree, Chang H.

    2014-11-20

    We present a sample of dwarf galaxies that suffer ongoing disruption by the tidal forces of nearby massive galaxies. By analyzing structural and stellar population properties using the archival imaging and spectroscopic data from the Sloan Digital Sky Survey (SDSS), we find that they are likely a ''smoking gun'' example of the formation through tidal stirring of early-type dwarf galaxies (dEs) in the galaxy group environment. The inner cores of these galaxies are fairly intact and the observed light profiles are well fit by the Sérsic functions while the tidally stretched stellar halos are prominent in the outer parts. They are all located within a sky-projected distance of 50 kpc from the centers of the host galaxies and no dwarf galaxies have relative line-of-sight velocities larger than 205 km s{sup –1} to their hosts. We derive the Composite Stellar Population properties of these galaxies by fitting the SDSS optical spectra to a multiple-burst composite stellar population model. We find that these galaxies accumulate a significant fraction of stellar mass within the last 1 Gyr and contain a majority stellar population with an intermediate age of 2 to 4 Gyr. Based on this evidence, we argue that tidal stirring, particularly through the galaxy-galaxy interaction, might have an important role in the formation and evolution of dEs in the group environment where the influence of other gas stripping mechanism might be limited.

  9. Discovery of a Stellar Overdensity in Eridanus-Phoenix in the Dark Energy Survey

    SciTech Connect (OSTI)

    Li, T.S.; et al.

    2015-09-14

    We report the discovery of an excess of main sequence turn-off stars in the direction of the constellations of Eridanus and Phoenix from the first year data of the Dark Energy Survey (DES). The Eridanus-Phoenix (EriPhe) overdensity is centered around l~285 deg and b~-60 deg and spans at least 30 deg in longitude and 10 deg in latitude. The Poisson significance of the detection is at least 9 sigma. The stellar population in the overdense region is similar in brightness and color to that of the nearby globular cluster NGC 1261, indicating that the heliocentric distance of EriPhe is about d~16 kpc. The extent of EriPhe in projection is therefore at least ~4 kpc by ~3 kpc. On the sky, this overdensity is located between NGC 1261 and a new stellar stream discovered by DES at a similar heliocentric distance, the so-called Phoenix Stream. Given their similar distance and proximity to each other, it is possible that these three structures may be kinematically associated. Alternatively, the EriPhe overdensity is morphologically similar to the Virgo overdensity and the Hercules-Aquila cloud, which also lie at a similar Galactocentric distance. These three overdensities lie along a polar plane separated by ~120 deg and may share a common origin. Spectroscopic follow-up observations of the stars in EriPhe are required to fully understand the nature of this overdensity.

  10. Looking Wider and Further: The Evolution of Galaxies Inside Galaxy Clusters

    SciTech Connect (OSTI)

    Zhang, Yuanyuan

    2016-01-01

    Galaxy clusters are rare objects in the universe, but on-going wide field optical surveys are identifying many thousands of them to redshift 1.0 and beyond. Using early data from the Dark Energy Survey (DES) and publicly released data from the Sloan Digital Sky Survey (SDSS), this dissertation explores the evolution of cluster galaxies in the redshift range from 0 to 1.0. As it is common for deep wide field sky surveys like DES to struggle with galaxy detection efficiency at cluster core, the first component of this dissertation describes an efficient package that helps resolving the issue. The second part focuses on the formation of cluster galaxies. The study quantifies the growth of cluster bright central galaxies (BCGs), and argues for the importance of merging and intra-cluster light production during BCG evolution. An analysis of cluster red sequence galaxy luminosity function is also performed, demonstrating that the abundance of these galaxies is mildly dependent on cluster mass and redshift. The last component of the dissertation characterizes the properties of galaxy filaments to help understanding cluster environments

  11. Wide-field lensing mass maps from Dark Energy Survey science verification data: Methodology and detailed analysis

    SciTech Connect (OSTI)

    Vikram, V.

    2015-07-29

    Weak gravitational lensing allows one to reconstruct the spatial distribution of the projected mass density across the sky. These “mass maps” provide a powerful tool for studying cosmology as they probe both luminous and dark matter. In this paper, we present a weak lensing mass map reconstructed from shear measurements in a 139 deg2 area from the Dark Energy Survey (DES) science verification data. We compare the distribution of mass with that of the foreground distribution of galaxies and clusters. The overdensities in the reconstructed map correlate well with the distribution of optically detected clusters. We demonstrate that candidate superclusters and voids along the line of sight can be identified, exploiting the tight scatter of the cluster photometric redshifts. We cross-correlate the mass map with a foreground magnitude-limited galaxy sample from the same data. Our measurement gives results consistent with mock catalogs from N-body simulations that include the primary sources of statistical uncertainties in the galaxy, lensing, and photo-z catalogs. The statistical significance of the cross-correlation is at the 6.8? level with 20 arcminute smoothing. We find that the contribution of systematics to the lensing mass maps is generally within measurement uncertainties. In this study, we analyze less than 3% of the final area that will be mapped by the DES; the tools and analysis techniques developed in this paper can be applied to forthcoming larger data sets from the survey.

  12. A series of Cd(II) complexes with {pi}-{pi} stacking and hydrogen bonding interactions: Structural diversities by varying the ligands

    SciTech Connect (OSTI)

    Wang Xiuli; Zhang Jinxia; Liu Guocheng; Lin Hongyan

    2011-02-15

    Seven new Cd(II) complexes consisting of different phenanthroline derivatives and organic acid ligands, formulated as [Cd(PIP){sub 2}(dnba){sub 2}] (1), [Cd(PIP)(ox)].H{sub 2}O (2), [Cd(PIP)(1,4-bdc)(H{sub 2}O)].4H{sub 2}O (3), [Cd(3-PIP){sub 2}(H{sub 2}O){sub 2}].4H{sub 2}O (4), [Cd{sub 2}(3-PIP){sub 4}(4,4'-bpdc)(H{sub 2}O){sub 2}].5H{sub 2}O (5), [Cd(3-PIP)(nip)(H{sub 2}O)].H{sub 2}O (6), [Cd{sub 2}(TIP){sub 4}(4,4'-bpdc)(H{sub 2}O){sub 2}].3H{sub 2}O (7) (PIP=2-phenylimidazo[4,5-f]1,10-phenanthroline, 3-PIP=2-(3-pyridyl)imidazo[4,5-f]1,10-phenanthroline, TIP=2-(2-thienyl)imidazo[4,5-f]1,10-phenanthroline, Hdnba=3,5-dinitrobenzoic acid, H{sub 2}ox=oxalic acid, 1,4-H{sub 2}bdc=benzene-1,4-dicarboxylic acid, 4,4'-H{sub 2}bpdc=biphenyl-4,4'-dicarboxylic acid, H{sub 2}nip=5-nitroisophthalic acid) have been synthesized under hydrothermal conditions. Complexes 1 and 4 possess mononuclear structures; complexes 5 and 7 are isostructural and have dinuclear structures; complexes 2 and 3 feature 1D chain structures; complex 6 contains 1D double chain, which are further extended to a 3D supramolecular structure by {pi}-{pi} stacking and hydrogen bonding interactions. The N-donor ligands with extended {pi}-system and organic acid ligands play a crucial role in the formation of the final supramolecular frameworks. Moreover, thermal properties and fluorescence of 1-7 are also investigated. -- Graphical abstract: Seven new supramolecular architectures have been successfully isolated under hydrothermal conditions by reactions of different phen derivatives and Cd(II) salts together with organic carboxylate anions auxiliary ligands. Display Omitted Research highlights: {yields} Complexes 1-7 are 0D or 1D polymeric structure, the {pi}-{pi} stacking and H-bonding interactions extend the complexes into 3D supramolecular network. To our knowledge, systematic study on {pi}-{pi} stacking and H-bonding interactions in cadmium(II) complexes are still limited. {yields} The structural differences among the title complexes indicate the importance of N-donor chelating ligands for the creation of molecular architectures. {yields} The thermal and fluorescence properties of title complexes have also been reported.

  13. Effects of support on bifunctional methanol oxidation pathways catalyzed by polyoxometallate keggin clusters

    SciTech Connect (OSTI)

    Liu, Haichao; Iglesia, Enrique

    2003-12-26

    H5PV2Mo10O40 polyoxometallate Keggin clusters supported on ZrO2, TiO2, SiO2, and Al2O3 are effective catalysts for CH3OH oxidation reactions to form HCHO, methyl formate (MF), and dimethoxymethane (DMM). Rates and selectivities and the structure of supported clusters depend on the surface properties of the oxide supports. Raman spectroscopy showed that Keggin structures remained essentially intact on ZrO2, TiO2, and SiO2 after treatment in air at 553 K, but decomposed to MoOx and VOx oligomers on Al2O3. Accessible protons per Keggin unit (KU) were measured during CH3OH oxidation by titration with 2,6-di-tert-butyl pyridine. For similar KU surface densities (0.28 0.37 KU/nm2), the number of accessible protons was larger on SiO2 than on ZrO2 and TiO2 and much smaller on Al2O3 supports, even though residual dimethyl ether (DME) synthesis rates after titrant saturation indicated that the fractional dispersion of KU was similar on the first three supports. These effects of support on structure and on H+ accessibility reflect varying extents of interaction between polyoxometallate clusters and supports. Rates of CH3OH oxidative dehydrogenation per KU were higher on ZrO2 and TiO2 than on SiO2 at similar KU surface densities (0.28 0.37 KU/nm2) and dispersion, indicating that redox properties of Keggin clusters depend on the identity of the support used to disperse them. ZrO2 and TiO2 supports appear to enhance the reducibility of anchored polyoxometallate clusters. Rates were much lower on Al2O3, because structural degradation led to less reactive MoOx and VOx domains. CH3OH reactions involve primary oxidation to form HCHO and subsequent secondary reactions to form DMM and MF. These reactions involve HCHO CH3OH acetalization steps leading to methoxymethanol (CH3OCH2OH) or hemiacetal intermediates, which condense with CH3OH on acid sites to form DMM or dehydrogenate to form MF. COx formation rates are much lower than those of other reactions, and DME forms in parallel pathways catalyzed by acid sites. Secondary reactions leading to DMM and MF are strongly influenced by the chemical properties of support surfaces. Acidic SiO2 surfaces favored DMM formation, while amphoteric or dehydrogenating surfaces on ZrO2 and TiO2 led to MF formation, as a result of the varying role of each support in directing the reactions of HCHO and CH3OH and of the CH3OCH2OH intermediates toward DMM or MF, which was confirmed using physical catalyst pure support mixtures. These support effects reflect the bifunctional pathways of CH3OH reactions. These pathways are consistent with the effects of residence time and of the partial removal of H+ sites by titration using 2,6-di-tert-butyl pyridine.

  14. SECA Coal-Based Systems - LGFCS

    SciTech Connect (OSTI)

    Goettler, Richard

    2013-08-01

    LGFCS is developing an integrated planar (IP) SOFC technology for mega-watt scale power generation including the potential for use in highly efficient, economically competitive central generation power plant facilities fuel by coal synthesis gas. This Department of Energy Solid-State Energy Conversion Alliance (SECA) program is aimed at achieving further cell and stack technical advancements and assessing the readiness of the LGFCS SOFC stack technology to be scaled to larger-scale demonstrations in subsequent phases. LGFCS is currently in Phase 2 of the program with the Phase 1 test carrying over for completion during Phase 2. Major technical results covering the initial Phase 2 budget period include: Metric Stack Testing: 1. The Phase I metric test is a ~7.6 kW block test (2 strips) in Canton that started in March 2012 and logged 2135 hours of testing prior to an event that required the test to be shutdown. The degradation rate through 2135 hours was 0.4%/1000 hours, well below the Phase I target of 2%/1000 hours and the Phase 2 target of 1.5%/1000 hours. 2. The initial Phase II metric test consisting of 5 strips (~19 kW) was started in May 2012. At the start of the test OCV was low and stack temperatures were out of range. Shutdown and inspection revealed localized structural damage to the strips. The strips were repaired and the test restarted October 11, 2012. 3. Root cause analysis of the Phase 1 and initial Phase 2 start-up failures concluded a localized short circuit across adjacent tubes/bundles caused localized heating and thermal stress fracture of substrates. Pre-reduction of strips rather than in-situ reduction within block test rigs now provides a critical quality check prior to block testing. The strip interconnect design has been modified to avoid short circuits. Stack Design: 1. Dense ceramic strip components were redesigned to achieve common components and a uniform design for all 12 bundles of a strip while meeting a flow uniformity of greater than 95% of the mean flow for all bundles. The prior design required unique bundle components and pressure drops specifications to achieve overall strip fuel flow uniformity. 2. Slow crack growth measurements in simulated fuel environments of the MgO-MgAl2O4 substrate by ORNL reveal favorable tolerance against slow crack growth. Evidence as well of a high stress intensity threshold below which crack growth would be avoided. These findings can have very positive implications on long-term structural reliability. More testing is required, including under actual reformate fuels, to gain a deeper understanding of such time dependent reliability mechanisms. 3. A next generation (Gen2) substrate from the LGFCS supplier has been qualified. The substrate incorporates cost reductions and quality improvements. Cell Developments: 1. Subscale testing of the epsilon technology under system relevant conditions surpassed 16,000 hours with a power degradation rate of <1%/1000 hours. Key degradation mechanisms have been identified: (1) MnOx accumulation near the cathode-electrolyte interface and cathode densification (2) metals migration across the anode-ACC bilayer and general microstructure coarsening at high temperatures and peak fuel utilizations and (3) metal migration into primary interconnect (lesser mechanism) 5 2. Alternate LSM cathodes show slightly lower ASR and lesser free MnOx and chromium contamination. Long-term durability screening of three alternate cathodes is being performed. 3. Single layer anodes show very significant improvement in microstructure stability after 5000 hours testing at aggressive conditions of 925C and bundle outlet, high utilization fuel. 4. New primary interconnect designs are being tested that achieve lower ASR. Modeling performed to further balance ASR and cost through optimized designs.

  15. Chemical stability of highly (0001) textured Sm(CoCu){sub 5} thin films with a thin Ta capping layer

    SciTech Connect (OSTI)

    Zhao Haibao; Wang Hao; Liu Xiaoqi; Wang Jianping; Zhang Tao

    2011-04-01

    With the highest magnetocrystalline anisotropy constant (Ku) among practical magnetic materials, SmCo{sub 5} could be a very attractive candidate for future high areal density magnetic recording. However, its corrosion resistance is always a concern in recording media applications. In this paper, the chemical stability and microstructures of highly (0001) textured Sm(CoCu){sub 5} thin films with and without a 3 nm Ta capping layer were reported. For Sm(CoCu){sub 5} thin films without a capping layer, the coercivity decreases significantly (from 8kOe to 1kOe) within one month. Sm(CoCu){sub 5} thin films capped with a thin Ta layer (3 nm) behave differently. Even exposed to a laboratory environment (25 deg. C) over 3 years, the Ta-capped Sm(CoCu){sub 5} thin films are stable in terms of structural and magnetic properties, i.e., there were no changes in X-ray diffraction peaks and vibrating sample magnetometer hysteresis loops. Microstructure of Ta-capped Sm(CoCu){sub 5} thin films showed that Sm(CoCu){sub 5} formed a domelike particle assembly structure on a smooth Ru underlayer and were well covered by partially oxidized Ta capping layer, as shown by TEM cross-section micrographs. Accelerated corrosion treatment (130 deg. C, 95% relative humidity, 6 h) was performed on Ta-capped Sm(CoCu){sub 5} thin films. X-ray photoelectron spectroscopy (XPS) results showed that no Co was detected on the sample surface before the corrosion treatment, but strong XPS signals of CoOx and Co(OH)x were observed after treatment. Therefore, none of our Sm(CoCu){sub 5} thin films can pass the accelerated corrosion test. Hcp-phased CoPt-alloys are proposed as better capping materials for Sm(CoCu){sub 5} thin films in future high-density magnetic recording applications.

  16. Structure Stabilization by Mixed Anions in Oxyfluoride Cathodes for High-Energy Lithium Batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kim, Sung-Wook; Pereira, Nathalie; Chernova, Natasha A.; Omenya, Fredrick; Gao, Peng; Whittingham, M. Stanley; Amatucci, Glenn G.; Su, Dong; Wang, Feng

    2015-08-24

    Mixed-anion oxyfluorides (i.e., FeOxF2-x) are an appealing alternative to pure fluorides as high-capacity cathodes in lithium batteries, with enhanced cyclability via oxygen substitution. Yet, it is still unclear how the mixed anions impact the local phase transformation and structural stability of oxyfluorides during cycling due to the complexity of electrochemical reactions, involving both lithium intercalation and conversion. Herein, we investigated the local chemical and structural ordering in FeO0.7F1.3 at length scales spanning from single particles to the bulk electrode, via a combination of electron spectrum-imaging, magnetization, electrochemistry, and synchrotron X-ray measurements. The FeO0.7F1.3 nanoparticles retain a FeF2-like rutile structuremore » but chemically heterogeneous, with an F-rich core covered by thin O-rich shell. Upon lithiation the O-rich rutile phase is transformed into Li—Fe—O(—F) rocksalt that has high lattice coherency with converted metallic Fe, a feature that may facilitate the local electron and ion transport. The O-rich rocksalt is highly stable over lithiation/delithiation and thus advantageous to maintain the integrity of the particle, and due to its predominant distribution on the surface, it is expected to prevent the catalytic interaction of Fe with electrolyte. Our findings of the structural origin of cycling stability in oxyfluorides may provide insights into developing viable high-energy electrodes for lithium batteries.« less

  17. Active phase distribution changes within a catalyst particle during Fischer–Tropsch synthesis as revealed by multi-scale microscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Cats, K. H.; Andrews, J. C.; Stephan, O.; March, K.; Karunakaran, C.; Meirer, F.; de Groot, F. M. F.; Weckhuysen, B. M.

    2016-02-16

    In this study, the Fischer-Tropsch synthesis (FTS) reaction is one of the most promising processes to convert alternative energy sources, such as natural gas, coal or biomass, into liquid fuels and other high-value products. Despite its commercial implementation, we still lack fundamental insights into the various deactivation processes taking place during FTS. In this work, a combination of three methods for studying single catalyst particles at different length scales has been developed and applied to study the deactivation of Co/TiO2 Fischer-Tropsch synthesis (FTS) catalysts. By combining transmission X-ray microscopy (TXM), scanning transmission X-ray microscopy (STXM) and scanning transmission electron microscopy-electronmore » energy loss spectroscopy (STEM-EELS) we visualized changes in the structure, aggregate size and distribution of supported Co nanoparticles that occur during FTS. At the microscale, Co nanoparticle aggregates are transported over several μm leading to a more homogeneous Co distribution, while at the nanoscale Co forms a thin layer of ~1-2 nm around the TiO2 support. The formation of the Co layer is the opposite case to the “classical” strong metal-support interaction (SMSI) in which TiO2 surrounds the Co, and is possibly related to the surface oxidation of Co metal nanoparticles in combination with coke formation. In other words, the observed migration and formation of a thin CoOx layer are similar to a previously discussed reaction-induced spreading of metal oxides across a TiO2 surface.« less

  18. Uniform 2 nm gold nanoparticles supported on iron oxides as active catalysts for CO oxidation reaction: Structure-activity relationship

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Guo, Yu; Senanayake, Sanjaya; Gu, Dong; Jin, Zhao; Du, Pei -Pei; Si, Rui; Xu, Wen -Qian; Huang, Yu -Ying; Tao, Jing; Song, Qi -Sheng; et al

    2015-01-12

    Uniform Au nanoparticles (~2 nm) with narrow size-distribution (standard deviation: 0.5–0.6 nm) supported on both hydroxylated (Fe_OH) and dehydrated iron oxide (Fe_O) have been prepared by either deposition-precipitation (DP) or colloidal-deposition (CD) methods. Different structural and textural characterizations were applied to the dried, calcined and used gold-iron oxide samples. The transmission electron microscopy (TEM) and high-resolution TEM (HRTEM) described the high homogeneity in the supported Au nanoparticles. The ex-situ and in-situ X-ray absorption fine structure (XAFS) characterization monitored the electronic and short-range local structure of active gold species. The synchrotron-based in-situ X-ray diffraction (XRD), together with the corresponding temperature-programmed reductionmore » by hydrogen (H₂-TPR), indicated a structural evolution of the iron-oxide supports, correlating to their reducibility. An inverse order of catalytic activity between DP (Au/Fe_OH < Au/Fe_O) and CD (Au/Fe_OH > Au/Fe_O) was observed. Effective gold-support interaction results in a high activity for gold nanoparticles, locally generated by the sintering of dispersed Au atoms on the oxide support in the DP synthesis, while a hydroxylated surface favors the reactivity of externally introduced Au nanoparticles on Fe_OH support for the CD approach. This work reveals why differences in the synthetic protocol translate to differences in the catalytic performance of Au/FeOx catalysts with very similar structural characteristics in CO oxidation.« less

  19. Geothermal Target Areas in Colorado as Identified by Remote Sensing Techniques

    SciTech Connect (OSTI)

    Hussein, Khalid

    2012-02-01

    Citation Information: Originator: Earth Science &Observation Center (ESOC), CIRES, University of Colorado at Boulder Publication Date: 2012 Title: Target Areas Edition: First Publication Information: Publication Place: Earth Science & Observation Center, Cooperative Institute for Research in Environmental Science, University of Colorado, Boulder, Colorado Publisher: Earth Science &Observation Center (ESOC), CIRES, University of Colorado at Boulder Description: This layer contains the areas identified as targets of potential geothermal activity. The Criteria used to identify the target areas include: hot/warm surface exposures modeled from ASTER/Landsat satellite imagery and geological characteristics, alteration mineral commonly associated with hot springs (clays, Si, and FeOx) modeled from ASTER and Landsat data, Coloradodo Geological Survey (CGS) known thermal hot springs/wells and heat-flow data points, Colorado deep-seated fault zones, weakened basement identified from isostatic gravity data, and Colorado sedimentary and topographic characteristics Spatial Domain: Extent: Top: 4546251.530446 m Left: 151398.567298 m Right: 502919.587395 m Bottom: 4095100.068903 m Contact Information: Contact Organization: Earth Science &Observation Center (ESOC), CIRES, University of Colorado at Boulder Contact Person: Khalid Hussein Address: CIRES, Ekeley Building Earth Science & Observation Center (ESOC) 216 UCB City: Boulder State: CO Postal Code: 80309-0216 Country: USA Contact Telephone: 303-492-6782 Spatial Reference Information: Coordinate System: Universal Transverse Mercator (UTM) WGS’1984 Zone 13N False Easting: 500000.00000000 False Northing: 0.00000000 Central Meridian: -105.00000000 Scale Factor: 0.99960000 Latitude of Origin: 0.00000000 Linear Unit: Meter Datum: World Geodetic System ’1984 (WGS ’1984) Prime Meridian: Greenwich Angular Unit: Degree Digital Form: Format Name: Shape file

  20. Synthesis and Evaluation of Cu-SAPO-34 Catalysts for Ammonia Selective Catalytic Reduction. 1. Aqueous Solution Ion Exchange

    SciTech Connect (OSTI)

    Gao, Feng; Walter, Eric D.; Washton, Nancy M.; Szanyi, Janos; Peden, Charles HF

    2013-09-06

    SAPO-34 molecular sieves are synthesized using various structure directing agents (SDAs). Cu-SAPO-34 catalysts are prepared via aqueous solution ion exchange. Catalysts are characterized with surface area/pore volume measurements, temperature programmed reduction (TPR), electron paramagnetic resonance (EPR) and nuclear magnetic resonance (NMR) spectroscopies. Catalytic properties are examined using standard ammonia selective catalytic reduction (NH3-SCR) and ammonia oxidation reactions. During solution ion exchange, different SAPO-34 samples undergo different extent of structural damage via irreversible hydrolysis. Si content within the samples (i.e., Al-O-Si bond density) and framework stress are key factors that affect irreversible hydrolysis. Even using very dilute Cu acetate solutions, it is not possible to generate Cu-SAPO-34 samples with only isolated Cu2+ ions. Small amounts of CuOx species always coexist with isolated Cu2+ ions. Highly active and selective Cu-SAPO-34 catalysts for NH3-SCR are readily generated using this synthesis protocol, even for SAPO-34 samples that degrade substantially during solution ion exchange. High-temperature aging is found to improve the catalytic performance. This is likely due to reduction of intracrystalline mass-transfer limitations via formation of additional porosity in the highly defective SAPO-34 particles formed after ion exchange. The authors gratefully acknowledge the US Department of Energy (DOE), Office of Energy Efficiency and Renewable Energy, Office of Vehicle Technologies for the support of this work. The research described in this paper was performed at the Environmental Molecular Sciences Laboratory (EMSL), a national scientific user facility sponsored by the DOE’s Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory (PNNL). PNNL is operated for the US DOE by Battelle Memorial Institute under contract number DE-AC05-76RL01830.

  1. Dissecting the steps of CO2 reduction: 2. The interaction of CO and CO2 with Pd/?-Al2O3: an in situ FTIR study

    SciTech Connect (OSTI)

    Szanyi, Janos; Kwak, Ja Hun

    2014-08-07

    Alumina supported Pd catalysts with metal loadings of 0.5, 2.5 and 10 wt% were investigated by in situ FTIR spectroscopy in order to understand the nature of adsorbed species formed during their exposure to CO2 and CO. Exposing the annealed samples to CO2 at 295 K resulted in the formation of alumina support-bound surface species only: linear adsorbed CO2, bidentate carbonates and bicarbonates. Room temperature exposure of all three samples to CO produced IR features characteristic of both ionic and metallic Pd, as well as bands we observed upon CO2 adsorption (alumina support-bound species). Low temperature (100 K) adsorption of CO on the three samples provided information about the state of Pd after oxidation and reduction. Oxidized samples contained exclusively ionic Pd, while mostly metallic Pd was present in the reduced samples. Subsequent annealing of the CO-saturated samples revealed the facile (low temperature) reduction of PdOx species by adsorbed CO. This process was evidenced by the variations in IR bands characteristic of ionic and metallic Pd-bound CO, as well as by the appearance of IR bands associated with CO2 adsorption as a function of annealing temperature. Samples containing oxidized Pd species (oxidized, annealed or reduced) always produced CO2 upon their exposure to CO, while CO2-related surface entities were observed on samples having only fully reduced (metallic) Pd. Acknowledgements: The catalyst preparation was supported by a Laboratory Directed Research and Development (LDRD) project. This work was supported by the US Department of Energy Basic Energy Sciences, Division of Chemical Sciences, Geosciences & Biosciences. Pacific Northwest National Laboratory is operated by Battelle for the US Department of Energy. JHK also acknowledges the support of this work by the 2013 Research Fund of UNIST (Ulsan National Institute of Science and Technology, Ulsan, Korea).

  2. Understanding the origin of high-rate intercalation pseudocapacitance in Nb2O5 crystals

    SciTech Connect (OSTI)

    Ganesh, Panchapakesan; Kent, P. R. C.; Sumpter, Bobby G; Lubimtsev, Andrew A

    2013-01-01

    Pseudocapacitors aim to maintain the high power density of supercapacitors while increasing the energy density towards those of energy dense storage systems such as lithium ion batteries. Recently discovered intercalation pseudocapacitors (e.g. Nb2O5) are particularly interesting because their performance is seemingly not limited by surface reactions or structures, but instead determined by the bulk crystalline structure of the material. We study ordered polymorphs of Nb2O5 and detail the mechanism for the intrinsic high rates and energy density observed for this class of materials. We find that the intercalating atom (lithium) forms a solid solution adsorbing at specific sites in a network of quasi-2D NbOx faces with x {1.3, 1.67, or 2}, donating electrons locally to its neighboring atoms, reducing niobium. Open channels in the structure have low diffusion barriers for ions to migrate between these sites (Eb 0.28 0.44 eV) comparable to high-performance solid electrolytes. Using a combination of complementary theoretical methods we rationalize this effect in LixNb2O5 for a wide range of compositions (x) and at finite temperatures. Multiple adsorption sites per unit-cell with similar adsorption energies and local charge transfer result in high capacity and energy density, while the interconnected open channels lead to low cost diffusion pathways between these sites, resulting in high power density. The nano-porous structure exhibiting local chemistry in a crystalline framework is the origin of high-rate pseudocapacitance in this new class of intercalation pseudocapacitor materials. This new insight provides guidance for improving the performance of this family of materials.

  3. A HEURISTIC PREDICTION OF THE COSMIC EVOLUTION OF THE CO-LUMINOSITY FUNCTIONS

    SciTech Connect (OSTI)

    Obreschkow, D.; Heywood, I.; Kloeckner, H.-R.; Rawlings, S.

    2009-09-10

    We predict the emission line luminosity functions (LFs) of the first 10 rotational transitions of {sup 12}C{sup 16}O in galaxies at redshift z = 0 to z = 10. This prediction relies on a recently presented simulation of the molecular cold gas content in {approx}3 x 10{sup 7} evolving galaxies based on the Millennium Simulation. We combine this simulation with a model for the conversion between molecular mass and CO-line intensities, which incorporates the following mechanisms: (1) molecular gas is heated by the cosmic microwave background (CMB), starbursts (SBs), and active galactic nuclei (AGNs); (2) molecular clouds in dense or inclined galaxies can overlap; (3) compact gas can attain a smooth distribution in the densest part of disks; (4) CO luminosities scale with metallicity changes between galaxies; and (5) CO luminosities are always detected against the CMB. We analyze the relative importance of these effects and predict the cosmic evolution of the CO-LFs. The most notable conclusion is that the detection of regular galaxies (i.e., no AGN, no massive SB) at high z {approx}> 7 in CO emission will be dramatically hindered by the weak contrast against the CMB, in contradiction to earlier claims that CMB heating will ease the detection of high-redshift CO. The full simulation of extragalactic CO lines and the predicted CO-LFs at any redshift can be accessed online (http://s-cubed.physics.ox.ac.uk/, go to {sup S3}-SAX) and they should be useful for the modeling of CO-line surveys with future telescopes, such as the Atacama Large Millimeter/submillimeter Array or the Square Kilometre Array.

  4. In-situ DRIFTS measurements for the mechanistic study of NO oxidation over a commercial Cu-CHA catalyst

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ruggeri, Maria Pia; Nova, Isabella; Tronconi, Enrico; Pihl, Josh A.; Toops, Todd J.; Partridge, Jr., William P.

    2014-11-03

    We report a mechanistic DRIFTS in-situ study of NO2, NO + O2 and NO adsorption on a commercial Cu-CHA catalyst for NH3-SCR of NOx. Both pre-reduced and pre-oxidized catalyst samples were investigated with the aim of clarifying mechanistic aspects of the NO oxidation to NO2 as a preliminary step towards the study of the Standard SCR reaction mechanism at low temperatures. Nitrosonium cations (NO+, N formal oxidation state = +3) were identified as key surface intermediates in the process of NO (+2) oxidation to NO2 (+4) and nitrates (+5). While NO+ and nitrates were formed simultaneously upon catalyst exposure tomore » NO2, nitrates evolved consecutively to NO+ when the catalyst was exposed to NO + O2, suggesting that nitrite-like species, and not NO2, are formed as the primary products of the NO oxidative activation over Cu-CHA. Upon catalyst exposure to NO only, i.e. in the absence of gaseous O2, NO+ and then nitrates were formed on a pre-oxidized sample but not on a pre-reduced one, which demonstrates the red-ox nature of the NO oxidation mechanism. The negative effect of H2O on NO+ and nitrates formation was also clearly established. Assuming Cu dimers as the active sites for NO oxidation to NO2, we propose a mechanism which reconciles all the experimental observations. Specifically, we show that such a mechanism also explains the observed kinetic effects of H2O, O2 and NO2 on the NO oxidation activity of the investigated Cu zeolite catalyst.« less

  5. Correlation Between Optical Properties And Chemical Composition Of Sputter-deposited Germanium Cxide (GeOx) Films

    SciTech Connect (OSTI)

    Murphy, Neil R.; Grant, J. T.; Sun, L.; Jones, J. G.; Jakubiak, R.; Shutthanandan, V.; Ramana, Chintalapalle V.

    2014-03-18

    Germanium oxide (GeOx) films were grown on (1 0 0) Si substrates by reactive Direct-Current (DC) magnetron sputter-deposition using an elemental Ge target. The effects of oxygen gas fraction, Г = O2/(Ar + O2), on the deposition rate, structure, chemical composition and optical properties of GeOx films have been investigated. The chemistry of the films exhibits an evolution from pure Ge to mixed Ge + GeO + GeO2 and then finally to GeO2 upon increasing Г from 0.00 to 1.00. Grazing incidence X-ray analysis indicates that the GeOx films grown were amorphous. The optical properties probed by spectroscopic ellipsometry indicate that the effect of Г is significant on the optical constants of the GeOx films. The measured index of refraction (n) at a wavelength (λ) of 550 nm is 4.67 for films grown without any oxygen, indicating behavior characteristic of semiconducting Ge. The transition from germanium to mixed Ge + GeO + GeO2 composition is associated with a characteristic decrease in n (λ = 550 nm) to 2.62 and occurs at Г = 0.25. Finally n drops to 1.60 for Г = 0.50–1.00, where the films become GeO2. A detailed correlation between Г, n, k and stoichiometry in DC sputtered GeOx films is presented and discussed.

  6. High temperature solar selective coatings

    DOE Patents [OSTI]

    Kennedy, Cheryl E

    2014-11-25

    Improved solar collectors (40) comprising glass tubing (42) attached to bellows (44) by airtight seals (56) enclose solar absorber tubes (50) inside an annular evacuated space (54. The exterior surfaces of the solar absorber tubes (50) are coated with improved solar selective coatings {48} which provide higher absorbance, lower emittance and resistance to atmospheric oxidation at elevated temperatures. The coatings are multilayered structures comprising solar absorbent layers (26) applied to the meta surface of the absorber tubes (50), typically stainless steel, topped with antireflective Savers (28) comprising at least two layers 30, 32) of refractory metal or metalloid oxides (such as titania and silica) with substantially differing indices of refraction in adjacent layers. Optionally, at least one layer of a noble metal such as platinum can be included between some of the layers. The absorbent layers cars include cermet materials comprising particles of metal compounds is a matrix, which can contain oxides of refractory metals or metalloids such as silicon. Reflective layers within the coating layers can comprise refractory metal silicides and related compounds characterized by the formulas TiSi. Ti.sub.3SiC.sub.2, TiAlSi, TiAN and similar compounds for Zr and Hf. The titania can be characterized by the formulas TiO.sub.2, Ti.sub.3O.sub.5. TiOx or TiO.sub.xN.sub.1-x with x 0 to 1. The silica can be at least one of SiO.sub.2, SiO.sub.2x or SiO.sub.2xN.sub.1-x with x=0 to 1.

  7. Réunion publique HR

    ScienceCinema (OSTI)

    None

    2011-10-06

    Chers Collègues,Je me permets de vous rappeler qu'une réunion publique organisée par le Département HR se tiendra aujourd'hui:Vendredi 30 avril 2010 à 9h30 dans l'Amphithéâtre principal (café offert dès 9h00).Durant cette réunion, des informations générales seront données sur:le CERN Admin e-guide, qui est un nouveau guide des procédures administratives du CERN ayant pour but de faciliter la recherche d'informations pratiques et d'offrir un format de lecture convivial;le régime d'Assurance Maladie de l'Organisation (présentation effectuée par Philippe Charpentier, Président du CHIS Board) et;la Caisse de Pensions (présentation effectuée par Théodore Economou, Administrateur de la Caisse de Pensions du CERN).Une transmission simultanée de cette réunion sera assurée dans l'Amphithéâtre BE de Prévessin et également disponible à l'adresse suivante: http://webcast.cern.chJe me réjouis de votre participation!Meilleures salutations,Anne-Sylvie CatherinChef du Département des Ressources humaines__________________________________________________________________________________Dear Colleagues,I should like to remind you that a plublic meeting organised by HR Department will be held today:Friday 30 April 2010 at 9:30 am in the Main Auditorium (coffee from 9:00 am).During this meeting, general information will be given about:the CERN Admin e-guide which is a new guide to the Organization's administrative procedures, drawn up to facilitate the retrieval of practical information and to offer a user-friendly format;the CERN Health Insurance System (presentation by Philippe Charpentier, President of the CHIS Board) and;the Pension Fund (presentation by Theodore Economou, Administrator of the CERN Pension Fund).A simultaneous transmission of this meeting will be broadcast in the BE Auditorium at Prévessin and will also be available at the following address. http://webcast.cern.chI look forward to your participation!Best regards,Anne-Sylvie CatherinHead, Human Resources Department

  8. The Difference Imaging Pipeline for the Transient Search in the Dark Energy Survey

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kessler, R.

    2015-09-09

    We describe the operation and performance of the difference imaging pipeline (DiffImg) used to detect transients in deep images from the Dark Energy Survey Supernova program (DES-SN) in its first observing season from 2013 August through 2014 February. DES-SN is a search for transients in which ten 3 deg2 fields are repeatedly observed in the g, r, i, zpassbands with a cadence of about 1 week. Our observing strategy has been optimized to measure high-quality light curves and redshifts for thousands of Type Ia supernovae (SNe Ia) with the goal of measuring dark energy parameters. The essential DiffImg functions aremore » to align each search image to a deep reference image, do a pixel-by-pixel subtraction, and then examine the subtracted image for significant positive detections of point-source objects. The vast majority of detections are subtraction artifacts, but after selection requirements and image filtering with an automated scanning program, there are ~130 detections per deg2 per observation in each band, of which only ~25% are artifacts. Of the ~7500 transients discovered by DES-SN in its first observing season, each requiring a detection on at least two separate nights, Monte Carlo (MC) simulations predict that 27% are expected to be SNe Ia or core-collapse SNe. Another ~30% of the transients are artifacts in which a small number of observations satisfy the selection criteria for a single-epoch detection. Spectroscopic analysis shows that most of the remaining transients are AGNs and variable stars. Fake SNe Ia are overlaid onto the images to rigorously evaluate detection efficiencies and to understand the DiffImg performance. Furthermore, the DiffImg efficiency measured with fake SNe agrees well with expectations from a MC simulation that uses analytical calculations of the fluxes and their uncertainties. In our 8 "shallow" fields with single-epoch 50% completeness depth ~23.5, the SN Ia efficiency falls to 1/2 at redshift z ≈ 0.7; in our 2 "deep" fields with mag-depth ~24.5, the efficiency falls to 1/2 at z ≈ 1.1. A remaining performance issue is that the measured fluxes have additional scatter (beyond Poisson fluctuations) that increases with the host galaxy surface brightness at the transient location. This bright-galaxy issue has minimal impact on the SNe Ia program, but it may lower the efficiency for finding fainter transients on bright galaxies.« less

  9. The Difference Imaging Pipeline for the Transient Search in the Dark Energy Survey

    SciTech Connect (OSTI)

    Kessler, R.

    2015-09-09

    We describe the operation and performance of the difference imaging pipeline (DiffImg) used to detect transients in deep images from the Dark Energy Survey Supernova program (DES-SN) in its first observing season from 2013 August through 2014 February. DES-SN is a search for transients in which ten 3 deg2 fields are repeatedly observed in the g, r, i, zpassbands with a cadence of about 1 week. Our observing strategy has been optimized to measure high-quality light curves and redshifts for thousands of Type Ia supernovae (SNe Ia) with the goal of measuring dark energy parameters. The essential DiffImg functions are to align each search image to a deep reference image, do a pixel-by-pixel subtraction, and then examine the subtracted image for significant positive detections of point-source objects. The vast majority of detections are subtraction artifacts, but after selection requirements and image filtering with an automated scanning program, there are ~130 detections per deg2 per observation in each band, of which only ~25% are artifacts. Of the ~7500 transients discovered by DES-SN in its first observing season, each requiring a detection on at least two separate nights, Monte Carlo (MC) simulations predict that 27% are expected to be SNe Ia or core-collapse SNe. Another ~30% of the transients are artifacts in which a small number of observations satisfy the selection criteria for a single-epoch detection. Spectroscopic analysis shows that most of the remaining transients are AGNs and variable stars. Fake SNe Ia are overlaid onto the images to rigorously evaluate detection efficiencies and to understand the DiffImg performance. Furthermore, the DiffImg efficiency measured with fake SNe agrees well with expectations from a MC simulation that uses analytical calculations of the fluxes and their uncertainties. In our 8 "shallow" fields with single-epoch 50% completeness depth ~23.5, the SN Ia efficiency falls to 1/2 at redshift z ≈ 0.7; in our 2 "deep" fields with mag-depth ~24.5, the efficiency falls to 1/2 at z ≈ 1.1. A remaining performance issue is that the measured fluxes have additional scatter (beyond Poisson fluctuations) that increases with the host galaxy surface brightness at the transient location. This bright-galaxy issue has minimal impact on the SNe Ia program, but it may lower the efficiency for finding fainter transients on bright galaxies.

  10. Memorial W.Gentner

    ScienceCinema (OSTI)

    None

    2011-04-25

    Le DG H.Schopper fait une introduction pour la commémoration et cérémonie de la vie et du travail du Prof.Wolfgang Gentner. W. Gentner, physicien allemand, né en 1906 à Francfort et mort en septembre 1980 à Heidelberg, était directeur au Cern de 1955 à 1960, président du "scientific policy commitee" de 1968 à 1971 et président du Conseil du Cern de 1972 à 1974. Il était un des fondateurs du Cern et 4 personnes qui l'ont bien connu lui rendent hommage, entre autres un de ses élèves, ainsi que Mme ?, J.B.Adams et O.Sheffard(?)

  11. Local Voltage Support from Distributed Energy Resources to Prevent Air Conditioner Motor Stalling

    SciTech Connect (OSTI)

    Baone, Chaitanya A; Xu, Yan; Kueck, John D

    2010-01-01

    Microgrid voltage collapse often happens when there is a high percentage of low inertia air-conditioning (AC) motors in the power systems. The stalling of the AC motors results in Fault Induced Delayed Voltage Recovery (FIDVR). A hybrid load model including typical building loads, AC motor loads, and other induction motor loads is built to simulate the motoring stalling phenomena. Furthermore, distributed energy resources (DE) with local voltage support capability are utilized to boost the local bus voltage during a fault, and prevent the motor stalling. The simulation results are presented. The analysis of the simulation results show that local voltage support from multiple DEs can effectively and economically solve the microgrid voltage collapse problem.

  12. The Fifth Omega Laser Facility Users Group Workshop

    SciTech Connect (OSTI)

    Petrasso, R. D.

    2015-10-01

    A capacity gathering of over 100 researchers from 25 universities and laboratories met at the Laboratory for Laser Energetics (LLE) for the Fifth Omega Laser Facility Users Group (OLUG) workshop. The purpose of the 2.5-day workshop was to facilitate communications and exchanges among individual Omega users and between users and the LLE management; to present ongoing and proposed research; to encourage research opportunities and collaborations that could be undertaken at the Omega Laser Facility and in a complementary fashion at other facilities [such as the National Ignition Facility (NIF) or the Laboratoire pour l’Utilisation des Lasers Intenses (LULI)]; to provide an opportunity for students, postdoctoral fellows, and young researchers to present their research in an informal setting; and to provide feedback to LLE management from the users about ways to improve the facility and future experimental campaigns.

  13. Heteropolymer freezing and design: Towards physical models of protein folding

    SciTech Connect (OSTI)

    Pande, Vijay S. [Chemistry Department, Stanford University, Stanford, California 94305-5080 (United States)] [Chemistry Department, Stanford University, Stanford, California 94305-5080 (United States); Grosberg, Alexander Yu. [Department of Physics, University of Minnesota, Minneapolis, Minnesota 55455 (United States)] [Department of Physics, University of Minnesota, Minneapolis, Minnesota 55455 (United States); Tanaka, Toyoichi [Department of Physics and Center for Materials Science and Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States)] [Department of Physics and Center for Materials Science and Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States)

    2000-01-01

    Protein folding has become one of the most actively studied problems in modern molecular biophysics. Approaches to the problem combine ideas from the physics of disordered systems, polymer physics, and molecular biology. Much can be learned from the statistical properties of model heteropolymers, the chain molecules having different monomers in irregular sequences. Even in highly evolved proteins, there is a strong random element in the sequences, which gives rise to a statistical ensemble of sequences for a given folded shape. Simple analytic models give rise to phase transitions between random, glassy, and folded states, depending on the temperature T and the design temperature T{sup des} of the ensemble of sequences. Besides considering the analytic results obtainable in a random-energy model and in the Flory mean-field model of polymers, the article reports on confirming numerical simulations. (c) 2000 The American Physical Society.

  14. LANL: AOT & LANSCE The Pulse March 2010

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Los Alamos National Laboratory * Est. 1943 The Pulse-Newsletter of the Los Alamos Neutron Science Center and Accelerator Operations and Technology Division I N S I D E 2 Tajima receives DOe early career awarD 2 NeuTrON reflec- TOmeTry prOviDes firsT sub-NaNOmeTer visualizaTiON Of live cell aDhesiON 3 creaTiNg a high- efficieNcy cOmpacT iON acceleraTOr, aN alTerNaTive TO larger, mOre cOsTly sTruc- Tures 4 heaDs up! LANSCE beam reliability achieves "world class" ranking AOT has issued

  15. LANL: AOT & LANSCE The Pulse October 2011

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 Los Alamos National Laboratory * Est. 1943 The Pulse-Newsletter of the Los Alamos Neutron Science Center and Accelerator Operations and Technology Division I N S I D E 3 From Alex's Desk 3 NeutroN scAtteriNg proviDes iNsight iNto eNzymAtic DegrADAtioN oF cellulose 4 NeutroN totAl scAtteriNg moNitors shiFts iN vAleNce stAtes 5 NeutroN reFlec- tometry exAmiNes the perFormANce oF rADiAtioN-resistANt mAteriAls 6 meAsuriNg the FissioN NeutroN spectrum At lANsce 7 heADs up! Daniel Shoemaker receives

  16. High Energy Physics at the University of Illinois

    SciTech Connect (OSTI)

    Liss, Tony M.; Thaler, Jon J.

    2013-07-26

    This is the final report for DOE award DE-FG02-91ER40677 (“High Energy Physics at the University of Illinois”), covering the award period November 1, 2009 through April 30, 2013. During this period, our research involved particle physics at Fermilab and CERN, particle physics related cosmology at Fermilab and SLAC, and theoretical particle physics. Here is a list of the activities described in the final report: * The CDF Collaboration at the Fermilab Tevatron * Search For Lepton Flavor Violation in the Mu2e Experiment At Fermilab * The ATLAS Collaboration at the CERN Large Hadron Collider * the Study of Dark Matter and Dark Energy: DES and LSST * Lattice QCD * String Theory and Field Theory * Collider Phenomenology

  17. Club of Rome

    ScienceCinema (OSTI)

    None

    2011-04-25

    Le Club de Rome s'est fait connaître du grand public par la publication du premier ouvrage "Halte à la croissance" qui a fait l'object d'un débat, il y a 2 ans. Le Prof. Tinbergen a commencé par s'adonner à la physique, il est docteur en physique et très tôt il s'est tourné vers les problèmes sociaux économiques. Il est expert auprès des nombreux gouvernements et organisations internationales et il a vu ses travaux couronnés par le prix Nobel en 1969.

  18. Offshore Wind Guidance Document: Oceanography and Sediment Stability (Version 1) Development of a Conceptual Site Model.

    SciTech Connect (OSTI)

    Roberts, Jesse D.; Jason Magalen; Craig Jones

    2014-06-01

    This guidance document provide s the reader with an overview of the key environmental considerations for a typical offshore wind coastal location and the tools to help guide the reader through a thoro ugh planning process. It will enable readers to identify the key coastal processes relevant to their offshore wind site and perform pertinent analysis to guide siting and layout design, with the goal of minimizing costs associated with planning, permitting , and long - ter m maintenance. The document highlight s site characterization and assessment techniques for evaluating spatial patterns of sediment dynamics in the vicinity of a wind farm under typical, extreme, and storm conditions. Finally, the document des cribe s the assimilation of all of this information into the conceptual site model (CSM) to aid the decision - making processes.

  19. Tomography and weak lensing statistics

    SciTech Connect (OSTI)

    Munshi, Dipak; Coles, Peter; Kilbinger, Martin E-mail: peter.coles@astro.cf.ac.uk

    2014-04-01

    We provide generic predictions for the lower order cumulants of weak lensing maps, and their correlators for tomographic bins as well as in three dimensions (3D). Using small-angle approximation, we derive the corresponding one- and two-point probability distribution function for the tomographic maps from different bins and for 3D convergence maps. The modelling of weak lensing statistics is obtained by adopting a detailed prescription for the underlying density contrast that involves hierarchal ansatz and lognormal distribution. We study the dependence of our results on cosmological parameters and source distributions corresponding to the realistic surveys such as LSST and DES. We briefly outline how photometric redshift information can be incorporated in our results. We also show how topological properties of convergence maps can be quantified using our results.

  20. Large linear magnetoresistance in a GaAs/AlGaAs heterostructure

    SciTech Connect (OSTI)

    Aamir, Mohammed Ali, E-mail: aamir@physics.iisc.ernet.in; Goswami, Srijit, E-mail: aamir@physics.iisc.ernet.in; Ghosh, Arindam [Department of Physics, Indian Institute of Science, Bangalore 560 012 (India); Baenninger, Matthias; Farrer, Ian; Ritchie, David A. [Cavendish Laboratory, University of Cambridge, J.J. Thomson Avenue, Cambridge CB3 0HE (United Kingdom); Tripathi, Vikram [Department of Theoretical Physics, Tata Institute of Fundamental Research, Homi Bhabha Road, Mumbai 400005 (India); Pepper, Michael [Department of Electrical and Electronic Engineering, University College, London WC1E 7JE (United Kingdom)

    2013-12-04

    We report non-saturating linear magnetoresistance (MR) in a two-dimensional electron system (2DES) at a GaAs/AlGaAs heterointerface in the strongly insulating regime. We achieve this by driving the gate voltage below the pinch-off point of the device and operating it in the non-equilibrium regime with high source-drain bias. Remarkably, the magnitude of MR is as large as 500% per Tesla with respect to resistance at zero magnetic field, thus dwarfing most non-magnetic materials which exhibit this linearity. Its primary advantage over most other materials is that both linearity and the enormous magnitude are retained over a broad temperature range (0.3 K to 10 K), thus making it an attractive candidate for cryogenic sensor applications.

  1. Final report for the virtual channel encryptor laboratory directed research and development project

    SciTech Connect (OSTI)

    Gibson, D.J.; Sarfaty, R.A.

    1997-08-01

    A workstation with a single physical connection to a data communications network may have a requirement for simultaneous `virtual` communication channels to more than one destination. This report describes the development of techniques based on the Data Encryption Standard (DES) which encrypt these virtual channels to secure the data being transmitted against unauthorized access. A software module has been developed for the UNIX operating system using these techniques for encryption, and some development has also been done on a hardware device to be included between the workstation and network which can also provide these functions. The material presented in this report will be useful to those with a need to protect information in data communications systems from unauthorized access.

  2. Cultural Alimentation in Latin America

    ScienceCinema (OSTI)

    None

    2011-04-25

    Le Prof. Paolo Freire(nom?) a dirigé en Brésil un plan national d'alphabétisatation d'adultes. La base de sa méthode est d'essayer de ne pas rester sur la mécanique du mot, mais de le relier avec la réalité sociale et donner un réveillement critique de la conscience populaire en face de la réalité historique du pays. Il était professeur d'histoire et de philosophie de Récife, puis exilé et depuis il était prof. à Harvard, a travaillé à l'Unesco et est maintenant conseiller spécial à l'Office d'Education du centre oecuménique des églises

  3. Electron heating due to microwave photoexcitation in the high mobility GaAs/AlGaAs two dimensional electron system

    SciTech Connect (OSTI)

    Ramanayaka, A. N.; Mani, R. G.; Wegscheider, W.

    2013-12-04

    We extract the electron temperature in the microwave photo-excited high mobility GaAs/AlGaAs two dimensional electron system (2DES) by studying the influence of microwave radiation on the amplitude of Shubnikov-de Haas oscillations (SdHOs) in a regime where the cyclotron frequency, ?{sub c}, and the microwave angular frequency, ?, satisfy 2? ? ?{sub c} ? 3.5? The results indicate that increasing the incident microwave power has a weak effect on the amplitude of the SdHOs and therefore the electron temperature, in comparison to the influence of modest temperature changes on the dark-specimen SdH effect. The results indicate negligible electron heating under modest microwave photo-excitation, in good agreement with theoretical predictions.

  4. Les vies de Galilée

    ScienceCinema (OSTI)

    None

    2011-10-06

    Qu'est-ce que l'astronomie? A quoi sert-elle ? Qui était Galilée ? Une soirée avec Fiami, auteur et dessinateur autour des vies de Galilée, titre de son nouvel ouvrage. Galilée y joue le protagoniste ou le complice de grandes découvertes à différentes époques et sous divers profils : Galilée à Babylone (-568) | Galilée à Alexandrie (-197) | Galilée en Inde (499) | Galilée à Venise (1609) | Galilée et Halley (1705) | Galilée revient (2009) Dans le cadre de l'année mondiale de l'astronomie. » Tout public » Entrée libre » Réservation groupes au +41 (0)22 767 76 76

  5. The Sixth Omega Laser Facility Users Group Workshop

    SciTech Connect (OSTI)

    Petrasso, R. D.

    2014-10-01

    A capacity gathering of over 100 researchers from 25 universities and laboratories met at the Laboratory for Laser Energetics (LLE) for the Sixth Omega Laser Facility Users Group (OLUG) workshop. The purpose of the 2.5-day workshop was to facilitate communications and exchanges among individual OMEGA users, and between users and the LLE management; to present ongoing and proposed research; to encourage research opportunities and collaborations that could be undertaken at the Omega Laser Facility and in a complementary fashion at other facilities [such as the National Ignition Facility (NIF) or the Laboratoire pour l’Utilisation des Lasers Intenses (LULI)]; to provide an opportunity for students, postdoctoral fellows, and young researchers to present their research in an informal setting; and to provide feedback from the users to LLE management about ways to improve and keep the facility and future experimental campaigns at the cutting edge.

  6. Supporting Advanced Scientific Computing Research * Basic Energy Sciences * Biological

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy S ciences N etwork Enabling Virtual Science June 9, 2009 Steve C o/er steve@es.net Dept. H ead, E nergy S ciences N etwork Lawrence B erkeley N aDonal L ab The E nergy S ciences N etwork The D epartment o f E nergy's O ffice o f S cience i s o ne o f t he l argest s upporters o f basic r esearch i n t he p hysical s ciences i n t he U .S. * Directly s upports t he r esearch o f s ome 1 5,000 s cienDsts, p ostdocs a nd g raduate s tudents at D OE l aboratories, u niversiDes, o ther F

  7. Comparative study of microwave radiation-induced magnetoresistive oscillations induced by circularly- and linearly- polarized photo-excitation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ye, Tianyu; Liu, Han -Chun; Wang, Zhuo; Wegscheider, W.; Mani, Ramesh G.

    2015-10-09

    A comparative study of the radiation-induced magnetoresistance oscillations in the high mobility GaAs/AlGaAs heterostructure two dimensional electron system (2DES) under linearly- and circularly- polarized microwave excitation indicates a profound difference in the response observed upon rotating the microwave launcher for the two cases, although circularly polarized microwave radiation induced magnetoresistance oscillations observed at low magnetic fields are similar to the oscillations observed with linearly polarized radiation. For the linearly polarized radiation, the magnetoresistive response is a strong sinusoidal function of the launcher rotation (or linear polarization) angle, θ. As a result, for circularly polarized radiation, the oscillatory magnetoresistive response ismore » hardly sensitive to θ.« less

  8. Material report in support to RCC-MRX code 2010 stainless steel parts and products

    SciTech Connect (OSTI)

    Ancelet, Olivier; Lebarbe, Thierry; Dubiez-Le Goff, Sophie; Bonne, Dominique; Gelineau, Odile

    2012-07-01

    This paper presents the Material Report dedicated to stainless steels parts and products issued by AFCEN (Association Francaise pour les regles de Conception et de Construction des Materiels des Chaudieres Electro-Nucleaires) in support to RCC-MRx 2010 Code. The RCC-MRx Code is the result of the merger of the RCC-MX 2008, developed in the context of the research reactor Jules Horowitz Reactor project, in the RCC-MR 2007, which set up rules applicable to the design of components operating at high temperature and to the Vacuum Vessel of ITER (a presentation of RCC-MRx 2010 Code is the subject of another paper proposed in this Congress; it explains in particular the status of this Code). This Material Report is part of a set of Criteria of RCC-MRx (this set of Criteria is under construction). The Criteria aim at explaining the design and construction rules of the Code. They cover analyses rules as well as part procurement, welding, methods of tests and examination and fabrication rules. The Material Report particularly provides justifications and explanations on requirements and features dealing with parts and products proposed in the Code. The Material Report contains the following information: Introduction of the grade(s): codes and standards and Reference Procurement Specifications covering parts and products, applications and experience gained, - Physical properties, - Mechanical properties used for design calculations (base metal and welds): basic mechanical properties, creep mechanical properties, irradiated mechanical properties, - Fabrication: experience gained, metallurgy, - Welding: weldability, experience gained during welding and repair procedure qualifications, - Non-destructive examination, - In-service behaviour. In the article, examples of data supplied in the Material Report dedicated to stainless steels will be exposed. (authors)

  9. Assessment of contaminant levels and trophic relations at a World Heritage Site by measurements in a characteristic shorebird species

    SciTech Connect (OSTI)

    Schwemmer, Philipp; Covaci, Adrian; Das, Krishna; Lepoint, Gilles; Adler, Sven; Garthe, Stefan

    2015-01-15

    The River Elbe is responsible for influxes of contaminants into the Wadden Sea World Heritage Site. We investigated levels of polychlorinated biphenyls (PCBs), oxychlordane (OxC), hexachlorobenzene (HCB), hexachlorocyclohexanes (α-, β-, γ-HCHs), dichlorodiphenyltrichloroethane (DDT) and its metabolites, and polybrominated diphenyl ethers (PBDEs) in blood and feathers from Eurasian oystercatchers (Haematopus ostralegus; n=28) at the Elbe and compared it with a non-riverine site about 90 km further north. (1) Mean levels of all contaminants in feathers and serum were significantly higher at the river (∑PCBs: 27.6 ng/g feather, 37.0 ng/ml serum; ∑DDTs: 5.3 ng/g feather, 4.4 ng/ml serum) compared with the non-riverine site (∑PCBs: 6.5 ng/g feather, 1.2 ng/ml serum; ∑DDTs: 1.4 ng/g feather, 0.5 ng/ml serum). Mean ∑HCH and HCB levels were <1.8 ng/g in feather and <1.8 ng/ml in serum at both sites. (2) Levels of most detectable compounds in serum and feathers were significantly related, but levels were not consistently higher in either tissue. (3) There was no significant relationship between trophic level in individual oystercatchers (expressed as δ15N) or the degree of terrestrial feeding (expressed as δ13C) and contaminant loads. (4) PBDEs were not detected in significant amounts at either site. The results of this study indicate that the outflow from one of Europe′s largest river systems is associated with significant historical contamination, reflected by the accumulation of contaminants in body tissues in a coastal benthivore predator. - Highlights: • Contaminants in Oystercatchers from the Elbe river and a non-riverine site were measured. • Mean levels of contaminants were higher at the river than at the non-riverine site. • Levels of most contaminants in serum and feathers were significantly related. • No relationship between trophic level (δ15N) and contaminant level was found. • One of Europe′s largest river systems is associated with major historical contamination.

  10. Mixed metallic Ba(Co,Mn)X{sub 0.2-x}O{sub 3-{delta}} (X=F, Cl) hexagonal perovskites

    SciTech Connect (OSTI)

    Iorgulescu, Mihaela; Roussel, Pascal; Tancret, Nathalie; Renaut, Nicolas; Tiercelin, Nicolas; Mentre, Olivier

    2013-02-15

    We show here that the incorporation of Mn in Ba-Co-oxohalide, BaCoX{sub 0.2-x}O{sub 3-{delta}}, hexagonal perovskite stabilizes the 6H-form (stacking sequence (chhhch Prime ); c, h=[BaO{sub 3}] and h Prime =[BaOX] layers), with tetramers of face-sharing octahedra) rather than the trimeric 10H-form. On the contrary to previous results on the Fe incorporation in similar system leading to more reduced 10H-compounds, the Mn effect is to increase the mean (Co/Mn) valence better suited to the 6H form. We experienced a poor Mn/Co miscibility during our syntheses leading to great difficulties to isolate mixed Co/Mn single phase materials and/or weak reproducibility. Powder neutron diffraction data shows a mixed Mn/Co octahedral occupancy, while the tetrahedra are filled by Co{sup 3+} cations. Anionic vacancies were refined in the h Prime -[BaO{sub 1-z}X{sub 1-x}] layer and the next c-[BaO{sub 3-z}] layers, while the h-[BaO{sub 3}] layers are not oxygen deficient. Magnetic properties suggest that a part of Mn cations remain paramagnetic until low temperature, while isolated spin clusters (probably driven by AFM Co tetrahedral dimers) behave as low-dimensional AFM systems. Transport measurements reveal a transition from high-temperature metallic to low-temperature semi-conducting states that could occur from defect shallow donor upon the Mn for Co substitution. - Graphical abstract: The incorporation of Mn in Ba-Co-oxohalide, BaCoX{sub 0.2-x}O{sub 3-{delta}}, hexagonal perovskite stabilizes the 6H-form with tetrameric (Co,Mn){sub 4}O{sub 15} face sharing linear chains. This results from a oxidizing Mn effect and particular Mn/Co distribution. Highlights: Black-Right-Pointing-Pointer The incorporation of Mn in BaCoX{sub 0.2-x}O{sub 3-{delta}} (X=F,Cl) hexagonal perovskites stabilizes the 6H-form. Black-Right-Pointing-Pointer It contains tetrameric (Co,Mn){sub 4}O{sub 15} face sharing linear chains. Black-Right-Pointing-Pointer The preference for such chains better than trimeric ones is due to the Manganese oxidizing effect. Black-Right-Pointing-Pointer A particular Mn/Co distribution was evidenced. Black-Right-Pointing-Pointer Transport and magnetic properties drastically change during the Mn incorporation.

  11. Ethane oxidative dehydrogenation pathways on vanadium oxide catalysts

    SciTech Connect (OSTI)

    Argyle, Morris; Chen, Kaidong; Bell, Alexis T.; Iglesia, Enrique

    2001-12-10

    Kinetic and isotopic tracer and exchange measurements were used to determine the identity and reversibility of elementary steps involved in ethane oxidative dehydrogenation (ODH) on VOx/Al2O3 and VOx/ZrO2. C2H6-C2D6-O2 and C2H6-D2O-O2 react to form alkenes and COx without concurrent formation of C2H6-xDx orC2H4-xDx isotopomers, suggesting that C-H bond cleavage in ethane and ethene is an irreversible and kinetically relevant step in ODH and combustion reactions. Primary ethane ODH reactions show normal kinetic isotopic effects (kC-H/kC-D) 2.4; similar values were measured for ethane and ethene combustion(1.9 and 2.8, respectively). 16O2-18O2-C2H6 reactions on supported V16Ox domains led to the initial appearance of 16O from the lattice in H2O, CO, and CO2, consistent with the involvement of lattice oxygen in C-H bond activation steps. Isotopic contents are similar in H2O, CO, and CO2, suggesting that ODH and combustion reactions use similar lattice oxygen sites. No 16O-18O isotopomer s were detected during reactions of 16O2-18O2-C2H6 mixtures, as expected if dissociative O2 chemisorption steps were irreversible. The alkyl species formed in these steps desorb irreversibly as ethene and the resulting O-H groups recombine to form H2O and reduced V centers in reversible desorption steps. These reduced V centers reoxidize by irreversible dissociative chemisorption of O2. A pseudo-steady state analysis of these elementary steps together with these reversibility assumptions led to a rate expression that accurately describes the observed inhibition of ODH rates by water and the measured kinetic dependence of ODH rates on C2H6 and O2 pressures. This kinetic analysis suggests that surface oxygen, OH groups, and oxygen vacancies are the most abundant reactive intermediates during ethane ODH on active VOx domains.

  12. Ethane oxidative dehydrogenation pathways on vanadium oxide catalysts

    SciTech Connect (OSTI)

    Argyle, Morris; Chen, Kaidong; Bell, Alexis T.; Iglesia, Enrique

    2001-12-10

    Kinetic and isotopic tracer and exchange measurements were used to determine the identity and reversibility of elementary steps involved in ethane oxidative dehydrogenation (ODH) on VOx/Al2O3 and VOx/ZrO2. C2H6-C2D6-O2 and C2H6-D2O-O2 react to form alkenes and COx without concurrent formation of C2H6-xDx orC2H4-xDx isotopomers, suggesting that C-H bond cleavage in ethane and ethene is an irreversible and kinetically relevant step in ODH and combustion reactions. Primary ethane ODH reactions show normal kinetic isotopic effects (kC-H/kC-D 2.4); similar values were measured for ethane and ethene combustion(1.9 and 2.8, respectively). 16O2-18O2-C2H6 reactions on supported V16Ox domains led to the initial appearance of 16O from the lattice in H2O, CO, and CO2, consistent with the involvement of lattice oxygen in C-H bond activation steps. Isotopic contents are similar in H2O, CO, and CO2, suggesting that ODH and combustion reactions use similar lattice oxygen sites. No 16O-18O isotopomer s were detected during reactions of 16O2-18O2-C2H6 mixtures, as expected if dissociative O2 chemisorption steps were irreversible. The alkyl species formed in these steps desorb irreversibly as ethene and the resulting O-H groups recombine to form H2O and reduced V centers in reversible desorption steps. These reduced V centers reoxidize by irreversible dissociative chemisorption of O2. A pseudo-steady state analysis of these elementary steps together with these reversibility assumptions led to a rate expression that accurately describes the observed inhibition of ODH rates by water and the measured kinetic dependence of ODH rates on C2H6 and O2 pressures. This kinetic analysis suggests that surface oxygen, OH groups, and oxygen vacancies are the most abundant reactive intermediates during ethane ODH on active VOx domains.

  13. Northeast Clean Energy Application Center

    SciTech Connect (OSTI)

    Bourgeois, Tom

    2013-09-30

    From October 1, 2009 through September 30, 2013 (“contract period”), the Northeast Clean Energy Application Center (“NE-CEAC”) worked in New York and New England (Connecticut, Rhode Island, Vermont, Massachusetts, New Hampshire, and Maine) to create a more robust market for the deployment of clean energy technologies (CETs) including combined heat and power (CHP), district energy systems (DES), and waste heat recovery (WHR) systems through the provision of technical assistance, education and outreach, and strategic market analysis and support for decision-makers. CHP, DES, and WHR can help reduce greenhouse gas emissions, reduce electrical and thermal energy costs, and provide more reliable energy for users throughout the United States. The NE-CEAC’s efforts in the provision of technical assistance, education and outreach, and strategic market analysis and support for decision-makers helped advance the market for CETs in the Northeast thereby helping the region move towards the following outcomes: • Reduction of greenhouse gas emissions and criteria pollutants • Improvements in energy efficiency resulting in lower costs of doing business • Productivity gains in industry and efficiency gains in buildings • Lower regional energy costs • Strengthened energy security • Enhanced consumer choice • Reduced price risks for end-users • Economic development effects keeping more jobs and more income in our regional economy Over the contract period, NE-CEAC provided technical assistance to approximately 56 different potential end-users that were interested in CHP and other CETs for their facility or facilities. Of these 56 potential end-users, five new CHP projects totaling over 60 MW of install capacity became operational during the contract period. The NE-CEAC helped host numerous target market workshops, trainings, and webinars; and NE-CEAC staff delivered presentations at many other workshops and conferences. In total, over 60 different workshops, conferences, webinars, and presentation were hosted or delivered during the contract period. The NE-CEAC also produced publically available educational materials such as CHP project profiles. Finally, the NE-CEAC worked closely with the relevant state agencies involved with CHP development. In New York, the NE-CEAC played an important role in securing and maintaining funding for CHP incentive programs administered by the New York State Energy Research Development Authority. NE-CEAC was also involved in the NYC Mayor's Office DG Collaborative. The NECEAC was also named a strategic resource for the Connecticut Department of Energy and Environmental Protection’s innovative Microgrid Pilot Program.

  14. Clean Energy Application Center

    SciTech Connect (OSTI)

    Freihaut, Jim

    2013-09-30

    The Mid Atlantic Clean Energy Application Center (MACEAC), managed by The Penn State College of Engineering, serves the six states in the Mid-Atlantic region (Pennsylvania, New Jersey, Delaware, Maryland, Virginia and West Virginia) plus the District of Columbia. The goals of the Mid-Atlantic CEAC are to promote the adoption of Combined Heat and Power (CHP), Waste Heat Recovery (WHR) and District Energy Systems (DES) in the Mid Atlantic area through education and technical support to more than 1,200 regional industry and government representatives in the region. The successful promotion of these technologies by the MACEAC was accomplished through the following efforts; (1)The MACEAC developed a series of technology transfer networks with State energy and environmental offices, Association of Energy Engineers local chapters, local community development organizations, utilities and, Penn State Department of Architectural Engineering alumni and their firms to effectively educate local practitioners about the energy utilization, environmental and economic advantages of CHP, WHR and DES; (2) Completed assessments of the regional technical and market potential for CHP, WHR and DE technologies application in the context of state specific energy prices, state energy and efficiency portfolio development. The studies were completed for Pennsylvania, New Jersey and Maryland and included a set of incentive adoption probability models used as a to guide during implementation discussions with State energy policy makers; (3) Using the technical and market assessments and adoption incentive models, the Mid Atlantic CEAC developed regional strategic action plans for the promotion of CHP Application technology for Pennsylvania, New Jersey and Maryland; (4) The CHP market assessment and incentive adoption model information was discussed, on a continuing basis, with relevant state agencies, policy makers and Public Utility Commission organizations resulting in CHP favorable incentive programs in New Jersey, Pennsylvania, Maryland and Delaware; (5) Developed and maintained a MACEAC website to provide technical information and regional CHP, WHR and DE case studies and site profiles for use by interested stakeholders in information transfer and policy discussions; (6) Provided Technical Assistance through feasibility studies and on site evaluations. The MACEAC completed 28 technical evaluations and 9 Level 1 CHP analyses ; and (7) the MACEAC provided Technical Education to the region through a series of 29 workshops and webinars, 37 technical presentations, 14 seminars and participation in 13 CHP conferences.

  15. Nicotine impairs cyclooxygenase-2-dependent kinin-receptor-mediated murine airway relaxations

    SciTech Connect (OSTI)

    Xu, Yuan Cardell, Lars-Olaf

    2014-02-15

    Introduction: Cigarette smoke induces local inflammation and airway hyperreactivity. In asthmatics, it worsens the symptoms and increases the risk for exacerbation. The present study investigates the effects of nicotine on airway relaxations in isolated murine tracheal segments. Methods: Segments were cultured for 24 h in the presence of vehicle, nicotine (10 ?M) and/or dexamethasone (1 ?M). Airway relaxations were assessed in myographs after pre-contraction with carbachol (1 ?M). Kinin receptors, cyclooxygenase (COX) and inflammatory mediator expressions were assessed by real-time PCR and confocal-microscopy-based immunohistochemistry. Results: The organ culture procedure markedly increased bradykinin- (selective B{sub 2} receptor agonist) and des-Arg{sup 9}-bradykinin- (selective B{sub 1} receptor agonist) induced relaxations, and slightly increased relaxation induced by isoprenaline, but not that induced by PGE{sub 2}. The kinin receptor mediated relaxations were epithelium-, COX-2- and EP2-receptor-dependent and accompanied by drastically enhanced mRNA levels of kinin receptors, as well as inflammatory mediators MCP-1 and iNOS. Increase in COX-2 and mPGES-1 was verified both at mRNA and protein levels. Nicotine selectively suppressed the organ-culture-enhanced relaxations induced by des-Arg{sup 9}-bradykinin and bradykinin, at the same time reducing mPGES-1 mRNA and protein expressions. ?7-nicotinic acetylcholine receptor inhibitors ?-bungarotoxin and MG624 both blocked the nicotine effects on kinin B{sub 2} receptors, but not those on B{sub 1}. Dexamethasone completely abolished kinin-induced relaxations. Conclusion: It is tempting to conclude that a local inflammatory process per se could have a bronchoprotective component by increasing COX-2 mediated airway relaxations and that nicotine could impede this safety mechanism. Dexamethasone further reduced airway inflammation together with relaxations. This might contribute to the steroid resistance seen in some patients with asthma. - Highlights: • Nicotine from smoking impaired epithelial COX-2-mediated airway relaxation. • Nicotine's effects were at least partially mediated by ?7-nicotinic receptors. • Kinin-receptor-mediated airway relaxations are mediated by EP2 receptors in mice. • Nicotine reduced mPGES-1 mRNA and protein expressions in airway smooth muscle. • Dexamethasone could not restore nicotine-impaired airway relaxations.

  16. The Open Science Grid status and architecture

    SciTech Connect (OSTI)

    Pordes, Ruth; Petravick, Don; Kramer, Bill; Olsen, James D.; Livny, Miron; Roy, Gordon A.; Avery, Paul Ralph; Blackburn, Kent; Wenaus, Torre J.; Wuerthwein, Frank K.; Foster, Ian; /Chicago U. /Indiana U.

    2007-09-01

    The Open Science Grid (OSG) provides a distributed facility where the Consortium members provide guaranteed and opportunistic access to shared computing and storage resources. The OSG project[1] is funded by the National Science Foundation and the Department of Energy Scientific Discovery through Advanced Computing program. The OSG project provides specific activities for the operation and evolution of the common infrastructure. The US ATLAS and US CMS collaborations contribute to and depend on OSG as the US infrastructure contributing to the World Wide LHC Computing Grid on which the LHC experiments distribute and analyze their data. Other stakeholders include the STAR RHIC experiment, the Laser Interferometer Gravitational-Wave Observatory (LIGO), the Dark Energy Survey (DES) and several Fermilab Tevatron experiments- CDF, D0, MiniBoone etc. The OSG implementation architecture brings a pragmatic approach to enabling vertically integrated community specific distributed systems over a common horizontal set of shared resources and services. More information can be found at the OSG web site: www.opensciencegrid.org.

  17. Wide-field lensing mass maps from Dark Energy Survey science verification data: Methodology and detailed analysis

    SciTech Connect (OSTI)

    Vikram, V.; Sheldon, E.; Chang, C.; Jain, B.; Bacon, D.; Amara, A.; Becker, M. R.; Bernstein, G.; Bonnett, C.; Bridle, S.; Brout, D.; Busha, M.; Frieman, J.; Gaztanaga, E.; Hartley, W.; Jarvis, M.; Kacprzak, T.; Kovacs, A.; Lahav, O.; Leistedt, B.; Lin, H.; Melchior, P.; Peiris, H.; Rozo, E.; Rykoff, E.; Sanchez, C.; Sheldon, E.; Troxel, M. A.; Wechsler, R.; Zuntz, J.; Abbott, T.; Abdalla, F. B.; Armstrong, R.; Banerji, M.; Bauer, A. H.; Benoit-Levy, A.; Bertin, E.; Brooks, D.; Buckley-Geer, E.; Burke, D. L.; Capozzi, D.; Carnero Rosell, A.; Kind, M. Carrasco; Castander, F. J.; Crocce, M.; Cunha, C. E.

    2015-07-29

    Weak gravitational lensing allows one to reconstruct the spatial distribution of the projected mass density across the sky. These “mass maps” provide a powerful tool for studying cosmology as they probe both luminous and dark matter. In this paper, we present a weak lensing mass map reconstructed from shear measurements in a 139 deg2 area from the Dark Energy Survey science verification data. We compare the distribution of mass with that of the foreground distribution of galaxies and clusters. The overdensities in the reconstructed map correlate well with the distribution of optically detected clusters. We demonstrate that candidate superclusters and voids along the line of sight can be identified, exploiting the tight scatter of the cluster photometric redshifts. We cross-correlate the mass map with a foreground magnitude-limited galaxy sample from the same data. Our measurement gives results consistent with mock catalogs from N-body simulations that include the primary sources of statistical uncertainties in the galaxy, lensing, and photo-z catalogs. The statistical significance of the cross-correlation is at the 6.8? level with 20 arcminute smoothing. We find that the contribution of systematics to the lensing mass maps is generally within measurement uncertainties. We analyze less than 3% of the final area that will be mapped by the DES; the tools and analysis techniques developed in this paper can be applied to forthcoming larger data sets from the survey.

  18. Direct production of hydrogen and aromatics from methane or natural gas: Review of recent U.S. patents

    SciTech Connect (OSTI)

    Lucia M. Petkovic; Daniel M. Ginosar

    2012-03-01

    Since the year 2000, the United States Patent and Trademark Office (USPTO) has granted a dozen patents for inventions related to methane dehydroaromatization processes. One of them was granted to UOP LLC (Des Plaines). It relates to a catalyst composition and preparation method. Two patents were granted to Conoco Phillips Company (Houston, TX). One was aimed at securing a process and operating conditions for methane aromatization. The other was aimed at securing a process that may be integrated with separation of wellhead fluids and blending of the aromatics produced from the gas with the crude. Nine patents were granted to ExxonMobil Chemical Patents Inc. (Houston, TX). Most of these were aimed at securing a dehydroaromatization process where methane-containing feedstock moves counter currently to a particulate catalyst. The coked catalyst is heated or regenerated either in the reactor, by cyclic operation, or in annex equipment, and returned to the reactor. The reactor effluent stream may be separated in its main components and used or recycled as needed. A brief summary of those inventions is presented in this review.

  19. Improving the Field Performance of Natural Gas Furnaces, Chicago, Illinois (Fact Sheet)

    SciTech Connect (OSTI)

    Rothgeb, S.; Brand, L.

    2013-11-01

    The objective of this project is to examine the impact that common installation practices and age-induced equipment degradation may have on the installed performance of natural gas furnaces, as measured by steady-state efficiency and AFUE. PARR identified twelve furnaces of various ages and efficiencies that were operating in residential homes in the Des Moines Iowa metropolitan area and worked with a local HVAC contractor to retrieve them and test them for steady-state efficiency and AFUE in the lab. Prior to removal, system airflow, static pressure, equipment temperature rise, and flue loss measurements were recorded for each furnace. After removal from the field the furnaces were transported to the Gas Technology Institute (GTI) laboratory, where PARR conducted steady-state efficiency and AFUE testing. The test results show that steady-state efficiency in the field was 6.4% lower than that measured for the same furnaces under standard conditions in the lab, which included tuning the furnace input and air flow rate. Comparing AFUE measured under ASHRAE standard conditions with the label value shows no reduction in efficiency for the furnaces in this study over their 15 to 24 years of operation when tuned to standard conditions. Further analysis of the data showed no significant correlation between efficiency change and the age or the rated efficiency of the furnace.

  20. Performance of internal covariance estimators for cosmic shear correlation functions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Friedrich, O.; Seitz, S.; Eifler, T. F.; Gruen, D.

    2015-12-31

    Data re-sampling methods such as the delete-one jackknife are a common tool for estimating the covariance of large scale structure probes. In this paper we investigate the concepts of internal covariance estimation in the context of cosmic shear two-point statistics. We demonstrate how to use log-normal simulations of the convergence field and the corresponding shear field to carry out realistic tests of internal covariance estimators and find that most estimators such as jackknife or sub-sample covariance can reach a satisfactory compromise between bias and variance of the estimated covariance. In a forecast for the complete, 5-year DES survey we show that internally estimated covariance matrices can provide a large fraction of the true uncertainties on cosmological parameters in a 2D cosmic shear analysis. The volume inside contours of constant likelihood in themore » $$\\Omega_m$$-$$\\sigma_8$$ plane as measured with internally estimated covariance matrices is on average $$\\gtrsim 85\\%$$ of the volume derived from the true covariance matrix. The uncertainty on the parameter combination $$\\Sigma_8 \\sim \\sigma_8 \\Omega_m^{0.5}$$ derived from internally estimated covariances is $$\\sim 90\\%$$ of the true uncertainty.« less

  1. Improving Gas Furnace Performance: A Field and Laboratory Study at End of Life

    SciTech Connect (OSTI)

    Brand, L.; Yee, S.; Baker, J.

    2015-02-01

    In 2010, natural gas provided 54% of total residential space heating energy the U.S. on a source basis, or 3.5 Quadrillion Btu. Natural gas burned in furnaces accounted for 92% of that total, and boilers and other equipment made up the remainder. A better understanding of installed furnace performance is a key to energy savings for this significant energy usage. In this project, the U.S. Department of Energy Building America team Partnership for Advanced Residential Retrofit examined the impact that common installation practices and age-induced equipment degradation may have on the installed performance of natural gas furnaces over the life of the product, as measured by steady-state efficiency and annual efficiency. The team identified 12 furnaces of various ages and efficiencies that were operating in residential homes in the Des Moines, Iowa, metropolitan area and worked with a local heating, ventilation, and air conditioning contractor to retrieve furnaces and test them at the Gas Technology Institute laboratory for steady-state efficiency and annual efficiency. Prior to removal, system airflow, static pressure, equipment temperature rise, and flue loss measurements were recorded for each furnace as installed in the house.

  2. PDES. FIPS Standard Data Encryption Algorithm

    SciTech Connect (OSTI)

    Nessett, D.N.

    1992-03-03

    PDES performs the National Bureau of Standards FIPS Pub. 46 data encryption/description algorithm used for the cryptographic protection of computer data. The DES algorithm is designed to encipher and decipher blocks of data consisting of 64 bits under control of a 64-bit key. The key is generated in such a way that each of the 56 bits used directly by the algorithm are random and the remaining 8 error-detecting bits are set to make the parity of each 8-bit byte of the key odd, i.e. there is an odd number of 1 bits in each 8-bit byte. Each member of a group of authorized users of encrypted computer data must have the key that was used to encipher the data in order to use it. Data can be recovered from cipher only by using exactly the same key used to encipher it, but with the schedule of addressing the key bits altered so that the deciphering process is the reverse of the enciphering process. A block of data to be enciphered is subjected to an initial permutation, then to a complex key-dependent computation, and finally to a permutation which is the inverse of the initial permutation. Two PDES routines are included; both perform the same calculation. One, identified as FDES.MAR, is designed to achieve speed in execution, while the other identified as PDES.MAR, presents a clearer view of how the algorithm is executed.

  3. DEMONSTRATION OF POTENTIAL FOR SELECTIVE CATALYTIC REDUCTION AND DIESEL PARTICULATE FILTERS

    SciTech Connect (OSTI)

    McGILL,R; KHAIR, M; SHARP, C

    2003-08-24

    This project addresses the potential for Selective Catalytic Reduction (SCR) devices (using urea as reductant) together with Diesel Particulate Filters (DPF) and low-pressure loop exhaust gas recirculation (EGR) to achieve future stringent emissions standards for heavy-duty engines powering Class 8 vehicles. Two emission control systems consisting of the three technologies (EGR, SCR, and DPF) were calibrated on a Caterpillar C-12 heavy-duty diesel engine. Results of these calibrations showed good promise in meeting the 2010 heavy-duty emission standards as set forth by the Environmental Protection Agency (EPA). These two emission control systems were developed to evaluate a series of fuels that have similar formulations except for their sulfur content. Additionally, one fuel, code-named BP15, was also evaluated. This fuel was prepared by processing straight-run distillate stocks through a commercial, single stage hydrotreater employing high activity catalyst at maximum severity. An additional goal of this program is to provide data for an on-going EPA technology review that evaluates progress toward meeting 2007/2010 emission standards. These emissions levels were to be achieved not only on the transient test cycles but in other modes of operation such as the steady-state Euro-III style emission test known as the OICA (Organisation Internationale des Compagnies d'Automobiles) or the ESC (European Stationary Cycle). Additionally, hydrocarbon and carbon monoxide emissions standards are to be met.

  4. Technology Solutions Case Study: Improving the Field Performance of Natural Gas Furnaces

    SciTech Connect (OSTI)

    2013-11-01

    The objective of this project is to examine the impact that common installation practices and age-induced equipment degradation may have on the installed performance of natural gas furnaces, as measured by steady-state efficiency and AFUE. PARR identified twelve furnaces of various ages and efficiencies that were operating in residential homes in the Des Moines Iowa metropolitan area and worked with a local HVAC contractor to retrieve them and test them for steady-state efficiency and AFUE in the lab. Prior to removal, system airflow, static pressure, equipment temperature rise, and flue loss measurements were recorded for each furnace. After removal from the field the furnaces were transported to the Gas Technology Institute (GTI) laboratory, where PARR conducted steady-state efficiency and AFUE testing. The test results show that steady-state efficiency in the field was 6.4% lower than that measured for the same furnaces under standard conditions in the lab, which included tuning the furnace input and air flow rate. Comparing AFUE measured under ASHRAE standard conditions with the label value shows no reduction in efficiency for the furnaces in this study over their 15 to 24 years of operation when tuned to standard conditions. Further analysis of the data showed no significant correlation between efficiency change and the age or the rated efficiency of the furnace.

  5. DESI and other Dark Energy experiments in the era of neutrino mass measurements

    SciTech Connect (OSTI)

    Font-Ribera, Andreu; McDonald, Patrick; Mostek, Nick; Reid, Beth A.; Seo, Hee-Jong; Slosar, Anže E-mail: PVMcDonald@lbl.gov E-mail: BAReid@lbl.gov E-mail: anze@bnl.gov

    2014-05-01

    We present Fisher matrix projections for future cosmological parameter measurements, including neutrino masses, Dark Energy, curvature, modified gravity, the inflationary perturbation spectrum, non-Gaussianity, and dark radiation. We focus on DESI and generally redshift surveys (BOSS, HETDEX, eBOSS, Euclid, and WFIRST), but also include CMB (Planck) and weak gravitational lensing (DES and LSST) constraints. The goal is to present a consistent set of projections, for concrete experiments, which are otherwise scattered throughout many papers and proposals. We include neutrino mass as a free parameter in most projections, as it will inevitably be relevant — DESI and other experiments can measure the sum of neutrino masses to ? 0.02 eV or better, while the minimum possible sum is ? 0.06 eV. We note that constraints on Dark Energy are significantly degraded by the presence of neutrino mass uncertainty, especially when using galaxy clustering only as a probe of the BAO distance scale (because this introduces additional uncertainty in the background evolution after the CMB epoch). Using broadband galaxy power becomes relatively more powerful, and bigger gains are achieved by combining lensing survey constraints with redshift survey constraints. We do not try to be especially innovative, e.g., with complex treatments of potential systematic errors — these projections are intended as a straightforward baseline for comparison to more detailed analyses.

  6. Wide-field lensing mass maps from Dark Energy Survey science verification data: Methodology and detailed analysis

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Vikram, V.; Sheldon, E.; Chang, C.; Jain, B.; Bacon, D.; Amara, A.; Becker, M. R.; Bernstein, G.; Bonnett, C.; Bridle, S.; et al

    2015-07-29

    Weak gravitational lensing allows one to reconstruct the spatial distribution of the projected mass density across the sky. These “mass maps” provide a powerful tool for studying cosmology as they probe both luminous and dark matter. In this paper, we present a weak lensing mass map reconstructed from shear measurements in a 139 deg2 area from the Dark Energy Survey science verification data. We compare the distribution of mass with that of the foreground distribution of galaxies and clusters. The overdensities in the reconstructed map correlate well with the distribution of optically detected clusters. We demonstrate that candidate superclusters andmore »voids along the line of sight can be identified, exploiting the tight scatter of the cluster photometric redshifts. We cross-correlate the mass map with a foreground magnitude-limited galaxy sample from the same data. Our measurement gives results consistent with mock catalogs from N-body simulations that include the primary sources of statistical uncertainties in the galaxy, lensing, and photo-z catalogs. The statistical significance of the cross-correlation is at the 6.8? level with 20 arcminute smoothing. We find that the contribution of systematics to the lensing mass maps is generally within measurement uncertainties. We analyze less than 3% of the final area that will be mapped by the DES; the tools and analysis techniques developed in this paper can be applied to forthcoming larger data sets from the survey.« less

  7. ReSS: Resource Selection Service for National and Campus Grid Infrastructure

    SciTech Connect (OSTI)

    Mhashilkar, Parag; Garzoglio, Gabriele; Levshina, Tanya; Timm, Steve; /Fermilab

    2009-05-01

    The Open Science Grid (OSG) offers access to around hundred Compute elements (CE) and storage elements (SE) via standard Grid interfaces. The Resource Selection Service (ReSS) is a push-based workload management system that is integrated with the OSG information systems and resources. ReSS integrates standard Grid tools such as Condor, as a brokering service and the gLite CEMon, for gathering and publishing resource information in GLUE Schema format. ReSS is used in OSG by Virtual Organizations (VO) such as Dark Energy Survey (DES), DZero and Engagement VO. ReSS is also used as a Resource Selection Service for Campus Grids, such as FermiGrid. VOs use ReSS to automate the resource selection in their workload management system to run jobs over the grid. In the past year, the system has been enhanced to enable publication and selection of storage resources and of any special software or software libraries (like MPI libraries) installed at computing resources. In this paper, we discuss the Resource Selection Service, its typical usage on the two scales of a National Cyber Infrastructure Grid, such as OSG, and of a campus Grid, such as FermiGrid.

  8. Fluidized-bed copper oxide process. Phase IV. Conceptual design and economic evaluation, Volume I. Final report

    SciTech Connect (OSTI)

    1994-11-30

    Universal Oil Products, Inc. (UOP) of Des Plaines, Illinois has contracted A.E. Roberts & Associates, Inc. (AERA) of Atlanta, Georgia to prepare a sensitivity analysis for the development of the Fluidized-bed Copper Oxide (FBCO) process. As proposed by AERA in September 1991, development of the FBCO process design for a 500 mega-watt (MW) unit was divided into three tasks: (1) Establishment of a Conceptual Design, (2) Conceptual Design, (3) Cost Analysis Task 1 determined the basis for a conceptual design for the 500 megawatt (MW) FBCO process. It was completed by AERA in September of 1992, and a report was submitted at that time {open_quotes}Establishment of the Design Basis for Application to a 500 MW Coal-fired Facility.{close_quotes} Task 2 gathered all pertinent data available to date and reviewed its applicability to the 500 MW FBCO process. Work on this task was carried out on a joint basis by the AERA team members: Roberts & Schaefers worked on the dense phase transport aspect of the design; Cornell and Carnegie Mellon Universities worked on the design kinetics and modeling; and AERA contributed commercial power and combustion experience. Task 3 provides budgetary cost estimates for the FBCO process and competing alternative technologies for sulfur dioxide and nitrogen oxide removal.

  9. Conceptual design of a gas turbine for PFBC applications

    SciTech Connect (OSTI)

    Bannister, R.L.; McGuigan, A.W.; Risley, T.P.; Smith, O.J.

    1992-01-01

    First generation pressurized fluidized bed (PFBC) technology has potential advantages which include: lower capital cost, Unproved environmental performance, shorter lead times, higher efficiency and enhanced fuel flexibility. Coal firing with combustion turbines experiments have been conducted for over forty years. These efforts have evolved to the point where commercial demonstrations are now feasible. The PFBC is one of these technologies. It will be demonstrated as part of the Clean Coal III initiative. PFBC technology is applicable for new installations, replacement of existing equipment as well as repower and retrofit. Included with these options is the opportunity to reduce dependency on fuel oil and well as enhancing environmental performance and increasing efficiency. The turbo-machinery will require design changes to meet the requirements for PFBC application. The major change to the combustion turbine take place in the center section. This section will include provisions to supply compressed air to the PFBC as well as receive vitiated air from the PFBC. These efforts also have the objective of reducing the degree of change from a standard unit. Under a clean coal program a first generation PFBC demonstration win take place at the Des Moines Energy Center. For this demonstration it will be necessary to remove two stages from the 251B12 compressor. This will make the air supplied by the compressor suitable for the PFBC system. The results from this program will be applicable to the DMEC-1 program.

  10. Conceptual design of a gas turbine for PFBC applications

    SciTech Connect (OSTI)

    Bannister, R.L.; McGuigan, A.W.; Risley, T.P.; Smith, O.J.

    1992-12-31

    First generation pressurized fluidized bed (PFBC) technology has potential advantages which include: lower capital cost, Unproved environmental performance, shorter lead times, higher efficiency and enhanced fuel flexibility. Coal firing with combustion turbines experiments have been conducted for over forty years. These efforts have evolved to the point where commercial demonstrations are now feasible. The PFBC is one of these technologies. It will be demonstrated as part of the Clean Coal III initiative. PFBC technology is applicable for new installations, replacement of existing equipment as well as repower and retrofit. Included with these options is the opportunity to reduce dependency on fuel oil and well as enhancing environmental performance and increasing efficiency. The turbo-machinery will require design changes to meet the requirements for PFBC application. The major change to the combustion turbine take place in the center section. This section will include provisions to supply compressed air to the PFBC as well as receive vitiated air from the PFBC. These efforts also have the objective of reducing the degree of change from a standard unit. Under a clean coal program a first generation PFBC demonstration win take place at the Des Moines Energy Center. For this demonstration it will be necessary to remove two stages from the 251B12 compressor. This will make the air supplied by the compressor suitable for the PFBC system. The results from this program will be applicable to the DMEC-1 program.

  11. Railroad accident report: Head-on collision between Iowa Interstate Railroad Extra 470 West and Extra 406 East with release of hazardous materials near Altoona, Iowa, on July 30, 1988. Irregular report

    SciTech Connect (OSTI)

    Not Available

    1989-07-06

    About 11:40 a.m. central daylight saving time on July 30, 1988, Iowa Interstate Railroad Ltd. (IAIS) freight trains Extra 470 West and Extra 406 East collided head on within the yard limits of Altoona, Iowa, about 10 miles east of Des Moines, Iowa. All 5 locomotive units from both trains; 11 cars of Extra 406 East; and 3 cars, including two tank cars containing denatured alcohol, of Extra 470 West derailed. The denatured alcohol, which was released through the pressure relief valves and the manway domes of the two derailed tank cars, was ignited by the fire resulting from the collision of the locomotives. Both crew members of Extra 470 West were fatally injured; the two crew members of Extra 406 East were only slightly injured. The estimated damage (including lading) as a result of this accident exceeded $1 million. The major safety issues in the accident include operational methods employed by the IAIS, training and selection of train and engine personnel, supervisory oversight by the IAIS, design of closure fittings on hazardous materials rail tanks, and oversight of regional railroads by the Federal Railroad Administration.

  12. Third international workshop on ice storage for cooling applications

    SciTech Connect (OSTI)

    Gorski, A.J.

    1986-04-01

    The third international workshop on ice storage for cooling applications which was informal and interactive in nature, was open to persons interested in all ice-growing technologies and in ice storage, both seasonal and diurnal. Presentations were made on some 20 topics, ranging from freezers in Alaska to ice cooling of commercial jet aircraft. Workshop tours included visits to ice-storage systems at Commonwealth Edison's facilities in Bolingbrook and Des Plaines Valley, the A.C. Neilsen builing in Northbrook, and the new State of Illinois Center in Chicago. The first workshop in the present series considered the future of ice storage and predicted applications in the agricultural sector, desalinization, and commercial ice production. Progress has been rapid in the intervening two years, and an important topic at the third workshop was the possible use of ''warm ices'' (clathrate hydrates) for energy storage. This report consists primarily of abstracts of presentations made at the workshop. Persons wishing to obtain further information about particular papers should contact the speakers directly; speakers' addresses and telephone numbers are listed in this report.

  13. Lessons from Iowa : development of a 270 megawatt compressed air energy storage project in midwest Independent System Operator : a study for the DOE Energy Storage Systems Program.

    SciTech Connect (OSTI)

    Holst, Kent; Huff, Georgianne; Schulte, Robert H.; Critelli, Nicholas

    2012-01-01

    The Iowa Stored Energy Park was an innovative, 270 Megawatt, $400 million compressed air energy storage (CAES) project proposed for in-service near Des Moines, Iowa, in 2015. After eight years in development the project was terminated because of site geological limitations. However, much was learned in the development process regarding what it takes to do a utility-scale, bulk energy storage facility and coordinate it with regional renewable wind energy resources in an Independent System Operator (ISO) marketplace. Lessons include the costs and long-term economics of a CAES facility compared to conventional natural gas-fired generation alternatives; market, legislative, and contract issues related to enabling energy storage in an ISO market; the importance of due diligence in project management; and community relations and marketing for siting of large energy projects. Although many of the lessons relate to CAES applications in particular, most of the lessons learned are independent of site location or geology, or even the particular energy storage technology involved.

  14. Fibre optique à la maison en Pays de Gex et de Bellegarde

    ScienceCinema (OSTI)

    None

    2011-10-06

    Le Syndicat Intercommunal d’Electricité de l’Ain(SIEA) déploie un réseau FTTH (Fiber To The Home) de fibres optiques dans le département de l’Ain vers l’ensemble des habitations. Le déploiement sur la zone pilote du Pays de Gex et du Bassin Bellegardien arrive dans la phase terminale vers les habitations. Le SIEA présentera ses activités, l’état du développement du réseau, les implications d’une connexion fibre optique et les procédures d’abonnement. La présentation sera donnée en Français. -------------------------------------------------------------------------------------------------------------------------------Public conference "Optical fiber To The Home in Pays de Gex et de Bellegarde" Michel Chanel et Jean Paul Goy (SIEA) Wednesday, 19th May at 11.30 hrs., Council Chamber, CERN The ‘’ Syndicat Intercommunal d’Electricité de l’Ain’’(SIEA) is deploying an optical fiber network FTTH (Fiber To The Home) in the Ain department towards the ensemble of houses. The installation on the pilot areas of Pays de Gex and Bassin Bellegardien is arriving in the phase of connecting houses. The SIEA will show its activities, the state of the network development, the implications of an optical fiber connection and the contract procedures. The presentation will be given in French

  15. Star/galaxy separation at faint magnitudes: Application to a simulated Dark Energy Survey

    SciTech Connect (OSTI)

    Soumagnac, M.T.; et al.

    2013-06-21

    We address the problem of separating stars from galaxies in future large photometric surveys. We focus our analysis on simulations of the Dark Energy Survey (DES). In the first part of the paper, we derive the science requirements on star/galaxy separation, for measurement of the cosmological parameters with the Gravitational Weak Lensing and Large Scale Structure probes. These requirements are dictated by the need to control both the statistical and systematic errors on the cosmological parameters, and by Point Spread Function calibration. We formulate the requirements in terms of the completeness and purity provided by a given star/galaxy classifier. In order to achieve these requirements at faint magnitudes, we propose a new method for star/galaxy separation in the second part of the paper. We first use Principal Component Analysis to outline the correlations between the objects parameters and extract from it the most relevant information. We then use the reduced set of parameters as input to an Artificial Neural Network. This multi-parameter approach improves upon purely morphometric classifiers (such as the classifier implemented in SExtractor), especially at faint magnitudes: it increases the purity by up to 20% for stars and by up to 12% for galaxies, at i-magnitude fainter than 23.

  16. LOW-RESOLUTION SPECTROSCOPY OF GAMMA-RAY BURST OPTICAL AFTERGLOWS: BIASES IN THE SWIFT SAMPLE AND CHARACTERIZATION OF THE ABSORBERS

    SciTech Connect (OSTI)

    Fynbo, J. P. U.; Malesani, D.; Vreeswijk, P. M.; Hjorth, J.; Sollerman, J.; Thoene, C. C.; Jakobsson, P.; Bjoernsson, G.; De Cia, A.; Prochaska, J. X.; Nardini, M.; Chen, H.-W.; Bloom, J. S.; Castro-Tirado, A. J.; Gorosabel, J.; Christensen, L.; Fruchter, A. S.

    2009-12-01

    We present a sample of 77 optical afterglows (OAs) of Swift detected gamma-ray bursts (GRBs) for which spectroscopic follow-up observations have been secured. Our first objective is to measure the redshifts of the bursts. For the majority (90%) of the afterglows, the redshifts have been determined from the spectra. We provide line lists and equivalent widths (EWs) for all detected lines redward of Ly{alpha} covered by the spectra. In addition to the GRB absorption systems, these lists include line strengths for a total of 33 intervening absorption systems. We discuss to what extent the current sample of Swift bursts with OA spectroscopy is a biased subsample of all Swift detected GRBs. For that purpose we define an X-ray-selected statistical sample of Swift bursts with optimal conditions for ground-based follow-up from the period 2005 March to 2008 September; 146 bursts fulfill our sample criteria. We derive the redshift distribution for the statistical (X-ray selected) sample and conclude that less than 18% of Swift bursts can be at z > 7. We compare the high-energy properties (e.g., {gamma}-ray (15-350 keV) fluence and duration, X-ray flux, and excess absorption) for three subsamples of bursts in the statistical sample: (1) bursts with redshifts measured from OA spectroscopy; (2) bursts with detected optical and/or near-IR afterglow, but no afterglow-based redshift; and (3) bursts with no detection of the OA. The bursts in group (1) have slightly higher {gamma}-ray fluences and higher X-ray fluxes and significantly less excess X-ray absorption than bursts in the other two groups. In addition, the fractions of dark bursts, defined as bursts with an optical to X-ray slope {beta}{sub OX} < 0.5, is 14% in group (1), 38% in group (2), and >39% in group (3). For the full sample, the dark burst fraction is constrained to be in the range 25%-42%. From this we conclude that the sample of GRBs with OA spectroscopy is not representative for all Swift bursts, most likely due to a bias against the most dusty sight lines. This should be taken into account when determining, e.g., the redshift or metallicity distribution of GRBs and when using GRBs as a probe of star formation. Finally, we characterize GRB absorption systems as a class and compare them to QSO absorption systems, in particular the damped Ly{alpha} absorbers (DLAs). On average GRB absorbers are characterized by significantly stronger EWs for H I as well as for both low and high ionization metal lines than what is seen in intervening QSO absorbers. However, the distribution of line strengths is very broad and several GRB absorbers have lines with EWs well within the range spanned by QSO-DLAs. Based on the 33 z > 2 bursts in the sample, we place a 95% confidence upper limit of 7.5% on the mean escape fraction of ionizing photons from star-forming galaxies.

  17. HOx radical chemistry in oxidation flow reactors with low-pressure mercury lamps systematically examined by modeling

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Peng, Z.; Day, D. A.; Stark, H.; Li, R.; Palm, B. B.; Brune, W. H.; Jimenez, J. L.

    2015-04-20

    Oxidation flow reactors (OFRs) using OH produced from low-pressure Hg lamps at 254 nm (OFR254) or both 185 and 254 nm (OFR185) are commonly used in atmospheric chemistry and other fields. OFR254 requires the addition of externally formed O3 since OH is formed from O3 photolysis, while OFR185 does not since O2 can be photolyzed to produce O3 and OH can also be formed from H2O photolysis. In this study, we use a plug-flow kinetic model to investigate OFR properties under a very wide range of conditions applicable to both field and laboratory studies. We show that the radical chemistrymore » in OFRs can be characterized as a function of UV light intensity, H2O concentration, and total external OH reactivity (OHRext, e.g., from VOCs, NOx, and SO2). OH exposure is decreased by added external OH reactivity. OFR185 is especially sensitive to this effect at low UV intensity due to low primary OH production. OFR254 can be more resilient against OH suppression at high injected O3 (e.g., 70 ppm), as a larger primary OH source from O3, as well as enhanced recycling of HO2 to OH, make external perturbations to the radical chemistry less significant. However if the external OH reactivity in OFR254 is much larger than OH reactivity from injected O3, OH suppression can reach two orders of magnitude. For a typical input of 7 ppm O3 (OHRO3 = 10 s−1) ten-fold OH suppression is observed at OHRext ∼ 100 s−1, which is similar or lower than used in many laboratory studies. This finding may have important implications for the interpretation of past laboratory studies, as applying OHexp measurements acquired under different conditions could lead to over an order-of-magnitude error in the estimated OHexp. The uncertainties of key model outputs due to uncertainty in all rate constants and absorption cross-sections in the model are within ± 25% for OH exposure and within ± 60% for other parameters. These uncertainties are small relative to the dynamic range of outputs. Uncertainty analysis shows that most of the uncertainty is contributed by photolysis rates of O3, O2, and H2O and reactions of OH and HO2 with themselves or with some abundant species, i.e., O3 and H2O2. Using HOx-recycling vs. destructive external OH reactivity only leads to small changes in OHexp under most conditions. Changing the identity (rate constant) of external OH reactants can result in substantial changes in OHexp due to different reductions in OH suppression as the reactant is consumed. We also report two equations for estimating OH exposure in OFR254. We find that the equation estimating OHexp from measured O3 consumption performs better than an alternative equation that does not use it, and thus recommend measuring both input and output O3 concentrations in OFR254 experiments. This study contributes to establishing a firm and systematic understanding of the gas-phase HOx and Ox chemistry in these reactors, and enables better experiment planning and interpretation as well as improved design of future reactors.« less

  18. EMAPS: An Efficient Multiscale Approach to Plasma Systems with Non-MHD Scale Effects

    SciTech Connect (OSTI)

    Omelchenko, Yuri A; Karimabadi, Homa

    2014-10-14

    Using Discrete-Event Simulation (DES) as a novel paradigm for time integration of large-scale physics-driven systems, we have achieved significant breakthroughs in simulations of multi-dimensional magnetized plasmas where ion kinetic and finite Larmor radius (FLR) and Hall effects play a crucial role. For these purposes we apply a unique asynchronous simulation tool: a parallel, electromagnetic Particle-in-Cell (PIC) code, HYPERS (Hybrid Particle Event-Resolved Simulator), which treats plasma electrons as a charge neutralizing fluid and solves a self-consistent set of non-radiative Maxwell, electron fluid equations and ion particle equations on a structured computational grid. HYPERS enables adaptive local time steps for particles, fluid elements and electromagnetic fields. This ensures robustness (stability) and efficiency (speed) of highly dynamic and nonlinear simulations of compact plasma systems such spheromaks, FRCs, ion beams and edge plasmas. HYPERS is a unique asynchronous code that has been designed to serve as a test bed for developing multi-physics applications not only for laboratory plasma devices but generally across a number of plasma physics fields, including astrophysics, space physics and electronic devices. We have made significant improvements to the HYPERS core: (1) implemented a new asynchronous magnetic field integration scheme that preserves local divB=0 to within round-off errors; (2) Improved staggered-grid discretizations of electric and magnetic fields. These modifications have significantly enhanced the accuracy and robustness of 3D simulations. We have conducted first-ever end-to-end 3D simulations of merging spheromak plasmas. The preliminary results show: (1) tilt-driven relaxation of a freely expanding spheromak to an m=1 Taylor helix configuration and (2) possibility of formation of a tilt-stable field-reversed configuration via merging and magnetic reconnection of two double-sided spheromaks with opposite helicities.

  19. Mass and galaxy distributions of four massive galaxy clusters from Dark Energy Survey Science Verification data

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Melchior, P.; Suchyta, E.; Huff, E.; Hirsch, M.; Kacprzak, T.; Rykoff, E.; Gruen, D.; Armstrong, R.; Bacon, D.; Bechtol, K.; et al

    2015-03-31

    We measure the weak-lensing masses and galaxy distributions of four massive galaxy clusters observed during the Science Verification phase of the Dark Energy Survey. This pathfinder study is meant to 1) validate the DECam imager for the task of measuring weak-lensing shapes, and 2) utilize DECam's large field of view to map out the clusters and their environments over 90 arcmin. We conduct a series of rigorous tests on astrometry, photometry, image quality, PSF modelling, and shear measurement accuracy to single out flaws in the data and also to identify the optimal data processing steps and parameters. We find Sciencemore » Verification data from DECam to be suitable for the lensing analysis described in this paper. The PSF is generally well-behaved, but the modelling is rendered difficult by a flux-dependent PSF width and ellipticity. We employ photometric redshifts to distinguish between foreground and background galaxies, and a red-sequence cluster finder to provide cluster richness estimates and cluster-galaxy distributions. By fitting NFW profiles to the clusters in this study, we determine weak-lensing masses that are in agreement with previous work. For Abell 3261, we provide the first estimates of redshift, weak-lensing mass, and richness. Additionally, the cluster-galaxy distributions indicate the presence of filamentary structures attached to 1E 0657-56 and RXC J2248.7-4431, stretching out as far as 1degree (approximately 20 Mpc), showcasing the potential of DECam and DES for detailed studies of degree-scale features on the sky.« less

  20. Energy Transfer in Collisions of Peptide Ions with Surfaces

    SciTech Connect (OSTI)

    Laskin, Julia; Futrell, Jean H.

    2003-08-08

    Time- and energy-resolved surface induced (SID) dissociation of a singly protonated octapeptide des-Arg1-bradykinin (PPGFSPFR) was used to study the effect of physical properties of the SID target on the efficiency of translational to vibrational energy transfer (T > V) in collisions of peptide ions with surfaces. Four SID targets of varying chemical composition and stiffness were examined in this work: self-assembled monolayers of 1-dodecane thiol (HSAM) and its fluorinated analog (CF3(CF2)9C2H4SH - FSAM) on gold, a 300 nm thick layer of lithium fluoride (LiF) on a polished titanium surface, and a 2 m carbon vapor deposited diamond layer on a titanium surface. An RRKM-based modeling approach was utilized to extract internal energy distributions deposited into the precursor ion upon collisions with different surfaces. We found that the percent of T -> V transfer increases in the order: HSAM (10.1%), LiF (12.0%), diamond (19.2%), FSAM (20.5%). Furthermore, the width of the energy deposition function (EDF) is affected by the properties of the SID target. Collisions of peptide ions with the HSAM surface results in deposition of relatively narrow internal energy distributions with the width of the EDF increasing in the order: HSAM < FSAM < LiF < Diamond. The results demonstrate that surface stiffness has a major effect on the width of the EDF, while the average energy deposited into the ion is mainly affected by the mass of the chemical moiety representing an immediate collision partner for the ion impacting the surface.

  1. The Phoenix stream: A cold stream in the southern hemisphere

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Balbinot, E.

    2016-03-17

    In this study, we report the discovery of a stellar stream in the Dark Energy Survey (DES) Year 1 (Y1A1) data. The discovery was made through simple color-magnitude filters and visual inspection of the Y1A1 data. We refer to this new object as the Phoenix stream, after its resident constellation. After subtraction of the background stellar population we detect a clear signal of a simple stellar population. By fitting the ridge line of the stream in color-magnitude space, we find that a stellar population with agemore » $$\\tau=11.5\\pm0.5$$ Gyr and $[Fe/H]<-1.6$ located 17.5$$\\pm$$0.9 kpc from the Sun gives an adequate description of the stream stellar population. The stream is detected over an extension of 8$$^{\\circ}.$$1 (2.5 kpc) and has a width of $$\\sim$$54 pc assuming a Gaussian profile, indicating that a globular cluster is a probable progenitor. There is no known globular cluster within 5 kpc compatible with being the progenitor of the stream, assuming that the stream traces its orbit. We examined overdensities along the stream, however no obvious counterpart bound stellar system is visible in the coadded images. We also find overdensities along the stream that appear to be symmetrically distributed - consistent with the epicyclic overdensity scenario for the formation of cold streams - as well as a misalignment between the Northern and Southern part of stream. Despite the close proximity we find no evidence that this stream and the halo cluster NGC 1261 have a common accretion origin linked to the recently found EriPhe overdensity (Li et al. 2016).« less

  2. Unusual Application Of Ion Beam Analysis For The Study Of Surface Layers On Materials Relevant To Cultural Heritage

    SciTech Connect (OSTI)

    Mathis, F.; Salomon, J.; Aucouturier, M.; Trocellier, P.

    2006-12-01

    Recently a new thematic of research -- intentional patinas on antic copper-base objects -- lead the AGLAE (Accelerateur Grand Louvre pour l'Analyse Elementaire) team of the C2RMF (Centre de Recherche et de Restauration des Musees de France) to improve its methods of analyzing thin surface layers both in their elemental composition and in-depth elemental distribution. A new beam extraction set-up containing a particle detector has been developed in order to use a 6 MeV alpha beam both in PIXE and RBS mode and to monitor precisely the ion dose received by the sample. Both RBS and ionization cross sections were assessed in order to make sure that the analysis can be quantitative. This set up allows great progresses in the understanding of both nature and structure of this very particular oxide layer obtained in the antiquity by chemical treatment on copper alloys, containing gold and/or silver and presenting very interesting properties of color and stability.Besides the non destructive properties of the IBA in external beam mode, this method of analyzing allows the study of samples in interaction with its environment. This was used to study the high temperature oxidation of Cu-Sn alloys using a furnace developed in order to heat a sample and analyze it in RBS mode at the same time. This new way of studying the growth of oxide layers permits to understand the oxidation mechanism of this system and to propose an experimental model for the identification of oxide layers due to an exposition to a high temperature, model needed for a long time by curators in charge of the study and the conservation of archaeological bronzes.

  3. LNG demand, shipping will expand through 2010

    SciTech Connect (OSTI)

    True, W.R.

    1998-02-09

    The 1990s, especially the middle years, have witnessed a dramatic turnaround in the growth of liquefied-natural-gas demand which has tracked equally strong natural-gas demand growth. This trend was underscored late last year by several annual studies of world LNG demand and shipping. As 1998 began, however, economic turmoil in Asian financial markets has clouded near-term prospects for LNG in particular and all energy in general. But the extent of damage to energy markets is so far unclear. A study by US-based Institute of Gas Technology, Des Plaines, IL, reveals that LNG imports worldwide have climbed nearly 8%/year since 1980 and account for 25% of all natural gas traded internationally. In the mid-1970s, the share was only 5%. In 1996, the most recent year for which complete data are available, world LNG trade rose 7.7% to a record 92 billion cu m, outpacing the overall consumption for natural gas which increased 4.7% in 1996. By 2015, says the IGT study, natural-gas use would surpass coal as the world`s second most widely used fuel, after petroleum. Much of this growth will occur in the developing countries of Asia where gas use, before the current economic crisis began, was projected to grow 8%/year through 2015. Similar trends are reflected in another study of LNG trade released at year end 1997, this from Ocean Shipping Consultants Ltd., Surrey, U.K. The study was done too early, however, to consider the effects of the financial problems roiling Asia.

  4. Cupola Furnace Computer Process Model

    SciTech Connect (OSTI)

    Seymour Katz

    2004-12-31

    The cupola furnace generates more than 50% of the liquid iron used to produce the 9+ million tons of castings annually. The cupola converts iron and steel into cast iron. The main advantages of the cupola furnace are lower energy costs than those of competing furnaces (electric) and the ability to melt less expensive metallic scrap than the competing furnaces. However the chemical and physical processes that take place in the cupola furnace are highly complex making it difficult to operate the furnace in optimal fashion. The results are low energy efficiency and poor recovery of important and expensive alloy elements due to oxidation. Between 1990 and 2004 under the auspices of the Department of Energy, the American Foundry Society and General Motors Corp. a computer simulation of the cupola furnace was developed that accurately describes the complex behavior of the furnace. When provided with the furnace input conditions the model provides accurate values of the output conditions in a matter of seconds. It also provides key diagnostics. Using clues from the diagnostics a trained specialist can infer changes in the operation that will move the system toward higher efficiency. Repeating the process in an iterative fashion leads to near optimum operating conditions with just a few iterations. More advanced uses of the program have been examined. The program is currently being combined with an ''Expert System'' to permit optimization in real time. The program has been combined with ''neural network'' programs to affect very easy scanning of a wide range of furnace operation. Rudimentary efforts were successfully made to operate the furnace using a computer. References to these more advanced systems will be found in the ''Cupola Handbook''. Chapter 27, American Foundry Society, Des Plaines, IL (1999).

  5. Opacity of iron, nickel, and copper plasmas in the x-ray wavelength range: Theoretical interpretation of 2p-3d absorption spectra

    SciTech Connect (OSTI)

    Blenski, T.; Loisel, G.; Poirier, M.; Thais, F.; Arnault, P.; Caillaud, T.; Fariaut, J.; Gilleron, F.; Pain, J.-C.; Porcherot, Q.; Reverdin, C.; Silvert, V.; Villette, B.; Bastiani-Ceccotti, S.; Turck-Chieze, S.; Foelsner, W.; Gaufridy de Dortan, F. de

    2011-09-15

    This paper deals with theoretical studies on the 2p-3d absorption in iron, nickel, and copper plasmas related to LULI2000 (Laboratoire pour l'Utilisation des Lasers Intenses, 2000J facility) measurements in which target temperatures were of the order of 20 eV and plasma densities were in the range 0.004-0.01 g/cm{sup 3}. The radiatively heated targets were close to local thermodynamic equilibrium (LTE). The structure of 2p-3d transitions has been studied with the help of the statistical superconfiguration opacity code sco and with the fine-structure atomic physics codes hullac and fac. A new mixed version of the sco code allowing one to treat part of the configurations by detailed calculation based on the Cowan's code rcg has been also used in these comparisons. Special attention was paid to comparisons between theory and experiment concerning the term features which cannot be reproduced by sco. The differences in the spin-orbit splitting and the statistical (thermal) broadening of the 2p-3d transitions have been investigated as a function of the atomic number Z. It appears that at the conditions of the experiment the role of the term and configuration broadening was different in the three analyzed elements, this broadening being sensitive to the atomic number. Some effects of the temperature gradients and possible non-LTE effects have been studied with the help of the radiative-collisional code scric. The sensitivity of the 2p-3d structures with respect to temperature and density in medium-Z plasmas may be helpful for diagnostics of LTE plasmas especially in future experiments on the {Delta}n=0 absorption in medium-Z plasmas for astrophysical applications.

  6. HR Public meeting

    ScienceCinema (OSTI)

    None

    2011-10-06

    Cher(e)s collègues, En collaboration avec le Département HR, le Directeur général a le plaisir de vous convier à une réunion publique qui se tiendra le vendredi 25 juin 2010 à 9h30 dans l?Amphithéâtre principal (Bâtiment 500)*. Un café d?accueil y sera servi à partir de 9h. Cette réunion abordera les thèmes suivants : ? Valeurs de l?Organisation (Directeur général) ? Code de Conduite (Directeur général / Anne-Sylvie Catherin) ? Création du nouveau rôle d?Ombudsperson (Vincent Vuillemin) Ces présentations seront suivies d?une séance de questions-réponses. Nous espérons vous retrouver nombreux le 25 juin ! Meilleures salutations, Anne-Sylvie Catherin Chef du Département des Ressources humaines *Cette réunion sera retransmise simultanément dans l?Amphithéâtre BE de Prévessin (Bâtiment 864) et également disponible à l?adresse suivante : http://webcast.cern.ch -------------------------------------------------------- Dear colleagues, In collaboration with HR Department, the Director-General would like to invite you to an information meeting which will be held on Friday 25 June 2010 at 9:30 am in the Main Auditorium (Building 500)*. A welcome coffee will be available from 9:00 am. During this meeting, information will be given about: ? Organization?s values (Director-General) ? Code of Conduct (Director-General / Anne-Sylvie Catherin) ? New Ombudsperson role (Vincent Vuillemin) These presentations will be followed by a questions & answers session. We look forward to seeing you all on 25 June! Best regards, Anne-Sylvie Catherin Head, Human Resources Department *This meeting will be simultaneously retransmitted in BE Auditorium (Building 864) and available at the following address: http://webcast.cern.ch.

  7. Turbulent Flow Effects on the Biological Performance of Hydro-Turbines

    SciTech Connect (OSTI)

    Richmond, Marshall C.; Romero Gomez, Pedro DJ

    2014-08-25

    The hydro-turbine industry uses Computational Fluid Dynamics (CFD) tools to predict the flow conditions as part of the design process for new and rehabilitated turbine units. Typically the hydraulic design process uses steady-state simulations based on Reynolds-Averaged Navier-Stokes (RANS) formulations for turbulence modeling because these methods are computationally efficient and work well to predict averaged hydraulic performance, e.g. power output, efficiency, etc. However, in view of the increasing emphasis on environmental concerns, such as fish passage, the consideration of the biological performance of hydro-turbines is also required in addition to hydraulic performance. This leads to the need to assess whether more realistic simulations of the turbine hydraulic environment −those that resolve unsteady turbulent eddies not captured in steady-state RANS computations− are needed to better predict the occurrence and extent of extreme flow conditions that could be important in the evaluation of fish injury and mortality risks. In the present work, we conduct unsteady, eddy-resolving CFD simulations on a Kaplan hydro-turbine at a normal operational discharge. The goal is to quantify the impact of turbulence conditions on both the hydraulic and biological performance of the unit. In order to achieve a high resolution of the incoming turbulent flow, Detached Eddy Simulation (DES) turbulence model is used. These transient simulations are compared to RANS simulations to evaluate whether extreme hydraulic conditions are better captured with advanced eddy-resolving turbulence modeling techniques. The transient simulations of key quantities such as pressure and hydraulic shear flow that arise near the various components (e.g. wicket gates, stay vanes, runner blades) are then further analyzed to evaluate their impact on the statistics for the lowest absolute pressure (nadir pressures) and for the frequency of collisions that are known to cause mortal injury in fish passing through hydro-turbines.

  8. SNF AGING SYSTEM DESCRIPTION DOCUMENT

    SciTech Connect (OSTI)

    L.L. Swanson

    2005-04-06

    The purpose of this system description document (SDD) is to establish requirements that drive the design of the spent nuclear fuel (SNF) aging system and associated bases, which will allow the design effort to proceed. This SDD will be revised at strategic points as the design matures. This SDD identifies the requirements and describes the system design, as it currently exists, with emphasis on attributes of the design provided to meet the requirements. This SDD is an engineering tool for design control; accordingly, the primary audience and users are design engineers. This SDD is part of an iterative design process. It leads the design process with regard to the flow down of upper tier requirements onto the system. Knowledge of these requirements is essential in performing the design process. The SDD follows the design with regard to the description of the system. The description provided in the SDD reflects the current results of the design process. Throughout this SDD, the term aging cask applies to vertical site-specific casks and to horizontal aging modules. The term overpack is a vertical site-specific cask that contains a dual-purpose canister (DPC) or a disposable canister. Functional and operational requirements applicable to this system were obtained from ''Project Functional and Operational Requirements'' (F&OR) (Curry 2004 [DIRS 170557]). Other requirements that support the design process were taken from documents such as ''Project Design Criteria Document'' (PDC) (BSC 2004 [DES 171599]), ''Site Fire Hazards Analyses'' (BSC 2005 [DIRS 172174]), and ''Nuclear Safety Design Bases for License Application'' (BSC 2005 [DIRS 171512]). The documents address requirements in the ''Project Requirements Document'' (PRD) (Canori and Leitner 2003 [DIRS 166275]). This SDD includes several appendices. Appendix A is a Glossary; Appendix B is a list of key system charts, diagrams, drawings, lists and additional supporting information; and Appendix C is a list of procedures that will be used to operate the system.

  9. Deployment of FlexCHP System

    SciTech Connect (OSTI)

    Cygan, David

    2015-11-01

    The Gas Technology Institute (GTI), along with its partner Integrated CHP Systems Corporation, has developed and demonstrated an Ultra-Low-Nitrogen Oxide (ULN) Flexible Combined Heat and Power (FlexCHP) system that packages a state-of-the-art Capstone C65 gas microturbine and Johnston PFXX100 boiler with an innovative natural gas-fired supplemental burner. Supplemental burners add heat as needed in response to facility demand, which increases energy efficiency, but typically raises exhaust NOx levels, degrading local air quality unless a costly and complicated catalytic treatment system is added. The FlexCHP system increases energy efficiency and achieves the 2007 California Air Resource Board (CARB) distributed generation emissions standards for Nitrogen oxides (NOx), Carbon Monoxide (CO), and Total Hydrocarbons (THC) without catalytic exhaust gas treatment. The key to this breakthrough performance is a simple and reliable burner design which utilizes staged combustion with engineered internal recirculation. This ULN burner system successfully uses turbine exhaust as an oxidizer, while achieving high efficiencies and low emissions. In tests at its laboratory facilities in Des Plaines, Illinois, GTI validated the ability of the system to achieve emissions of NOx, CO, and THC below the CARB criteria of 0.07, 0.10, and 0.02 lb/MW-h respectively. The FlexCHP system was installed at the field demonstration site, Inland Empire Foods, in Riverside, California to verify performance of the technology in an applied environment. The resulting Combined Heat and Power (CHP) package promises to make CHP implementation more attractive, mitigate greenhouse gas emissions, and improve the reliability of electricity supply.

  10. Impact of operating parameters changing on energy, environment and economic efficiencies of a lean burn gas engine used in a cogeneration plant

    SciTech Connect (OSTI)

    Lemoult, B.; Tazerout, M.; Rousseau, S.

    1998-07-01

    The facts that national electrical company Electricite de France (EDF) has a monopoly on electrical power production in France and an extensive installed base of nuclear power plants, explain the difficulty encountered in developing cogeneration technology in France. Cogeneration only really first appeared in this country in the early 1990's, with the liberalization of energy markets and the government's encouragement. Since then, the number of cogeneration plants has continuously increased and electrical generating capacity is now approximately 1,200 MWe. Turbine and reciprocating engines (most of which are natural gas fired) account respectively for about 55% and 45% of the installed power. Unlike other countries, such as Germany--which has about two thousand 500 kWe and smaller units--the future of low-power cogeneration in France is far from assured, and there are currently less than 10 such plants. To help develop this efficient technology for producing electrical power and hot water, the Ecole des Mines de Nantes purchased a 210 kWe cogeneration generator set in 1996. This facility provides all or part of the school's electrical and heat requirements during five months between November and March. This cogeneration facility is also used during the rest of the year to perform research experiments in the field of lean-burn natural gas combustion. Lastly, it is also used to provide training for industry in cogeneration technology. Within this context, work was undertaken to study the set's energy and emissions performance, in relation to such parameters as spark advance and air factor, and at various loads.

  11. Excess Foundry Sand Characterization and Experimental Investigation in Controlled Low-Strength Material and Hot-Mixing Asphalt

    SciTech Connect (OSTI)

    Pauul J. Tikalsky

    2004-10-31

    This report provides technical data regarding the reuse of excess foundry sand. The report addresses three topics: (1) a statistically sound evaluation of the characterization of foundry sand, (2) a laboratory investigation to qualify excess foundry sand as a major component in controlled low-strength material (CLSM), and (3) the identification of the best methods for using foundry sand as a replacement for natural aggregates for construction purposes, specifically in asphalt paving materials. The survival analysis statistical technique was used to characterize foundry sand over a full spectrum of general chemical parameters, metallic elements, and organic compounds regarding bulk analysis and leachate characterization. Not limited to characterization and environmental impact, foundry sand was evaluated by factor analyses, which contributes to proper selection of factor and maximization of the reuse marketplace for foundry sand. Regarding the integration of foundry sand into CLSM, excavatable CLSM and structural CLSM containing different types of excess foundry sands were investigated through laboratory experiments. Foundry sand was approved to constitute a major component in CLSM. Regarding the integration of foundry sand into asphalt paving materials, the optimum asphalt content was determined for each mixture, as well as the bulk density, maximum density, asphalt absorption, and air voids at N{sub ini}, N{sub des}, and N{sub max}. It was found that foundry sands can be used as an aggregate in hot-mix asphalt production, but each sand should be evaluated individually. Foundry sands tend to lower the strength of mixtures and also may make them more susceptible to moisture damage. Finally, traditional anti-stripping additives may decrease the moisture sensitivity of a mixture containing foundry sand, but not to the level allowed by most highway agencies.

  12. High Fidelity Simulations of Large-Scale Wireless Networks

    SciTech Connect (OSTI)

    Onunkwo, Uzoma; Benz, Zachary

    2015-11-01

    The worldwide proliferation of wireless connected devices continues to accelerate. There are 10s of billions of wireless links across the planet with an additional explosion of new wireless usage anticipated as the Internet of Things develops. Wireless technologies do not only provide convenience for mobile applications, but are also extremely cost-effective to deploy. Thus, this trend towards wireless connectivity will only continue and Sandia must develop the necessary simulation technology to proactively analyze the associated emerging vulnerabilities. Wireless networks are marked by mobility and proximity-based connectivity. The de facto standard for exploratory studies of wireless networks is discrete event simulations (DES). However, the simulation of large-scale wireless networks is extremely difficult due to prohibitively large turnaround time. A path forward is to expedite simulations with parallel discrete event simulation (PDES) techniques. The mobility and distance-based connectivity associated with wireless simulations, however, typically doom PDES and fail to scale (e.g., OPNET and ns-3 simulators). We propose a PDES-based tool aimed at reducing the communication overhead between processors. The proposed solution will use light-weight processes to dynamically distribute computation workload while mitigating communication overhead associated with synchronizations. This work is vital to the analytics and validation capabilities of simulation and emulation at Sandia. We have years of experience in Sandia’s simulation and emulation projects (e.g., MINIMEGA and FIREWHEEL). Sandia’s current highly-regarded capabilities in large-scale emulations have focused on wired networks, where two assumptions prevent scalable wireless studies: (a) the connections between objects are mostly static and (b) the nodes have fixed locations.

  13. Mass and galaxy distributions of four massive galaxy clusters from Dark Energy Survey Science Verification data

    SciTech Connect (OSTI)

    Melchior, P.; Suchyta, E.; Huff, E.; Hirsch, M.; Kacprzak, T.; Rykoff, E.; Gruen, D.; Armstrong, R.; Bacon, D.; Bechtol, K.; Bernstein, G. M.; Bridle, S.; Clampitt, J.; Honscheid, K.; Jain, B.; Jouvel, S.; Krause, E.; Lin, H.; MacCrann, N.; Patton, K.; Plazas, A.; Rowe, B.; Vikram, V.; Wilcox, H.; Young, J.; Zuntz, J.; Abbott, T.; Abdalla, F. B.; Allam, S. S.; Banerji, M.; Bernstein, J. P.; Bernstein, R. A.; Bertin, E.; Buckley-Geer, E.; Burke, D. L.; Castander, F. J.; da Costa, L. N.; Cunha, C. E.; Depoy, D. L.; Desai, S.; Diehl, H. T.; Doel, P.; Estrada, J.; Evrard, A. E.; Neto, A. F.; Fernandez, E.; Finley, D. A.; Flaugher, B.; Frieman, J. A.; Gaztanaga, E.; Gerdes, D.; Gruendl, R. A.; Gutierrez, G. R.; Jarvis, M.; Karliner, I.; Kent, S.; Kuehn, K.; Kuropatkin, N.; Lahav, O.; Maia, M. A. G.; Makler, M.; Marriner, J.; Marshall, J. L.; Merritt, K. W.; Miller, C. J.; Miquel, R.; Mohr, J.; Neilsen, E.; Nichol, R. C.; Nord, B. D.; Reil, K.; Roe, N. A.; Roodman, A.; Sako, M.; Sanchez, E.; Santiago, B. X.; Schindler, R.; Schubnell, M.; Sevilla-Noarbe, I.; Sheldon, E.; Smith, C.; Soares-Santos, M.; Swanson, M. E. C.; Sypniewski, A. J.; Tarle, G.; Thaler, J.; Thomas, D.; Tucker, D. L.; Walker, A.; Wechsler, R.; Weller, J.; Wester, W.

    2015-03-31

    We measure the weak-lensing masses and galaxy distributions of four massive galaxy clusters observed during the Science Verification phase of the Dark Energy Survey. This pathfinder study is meant to 1) validate the DECam imager for the task of measuring weak-lensing shapes, and 2) utilize DECam's large field of view to map out the clusters and their environments over 90 arcmin. We conduct a series of rigorous tests on astrometry, photometry, image quality, PSF modelling, and shear measurement accuracy to single out flaws in the data and also to identify the optimal data processing steps and parameters. We find Science Verification data from DECam to be suitable for the lensing analysis described in this paper. The PSF is generally well-behaved, but the modelling is rendered difficult by a flux-dependent PSF width and ellipticity. We employ photometric redshifts to distinguish between foreground and background galaxies, and a red-sequence cluster finder to provide cluster richness estimates and cluster-galaxy distributions. By fitting NFW profiles to the clusters in this study, we determine weak-lensing masses that are in agreement with previous work. For Abell 3261, we provide the first estimates of redshift, weak-lensing mass, and richness. Additionally, the cluster-galaxy distributions indicate the presence of filamentary structures attached to 1E 0657-56 and RXC J2248.7-4431, stretching out as far as 1degree (approximately 20 Mpc), showcasing the potential of DECam and DES for detailed studies of degree-scale features on the sky.

  14. HOx radical chemistry in oxidation flow reactors with low-pressure mercury lamps systematically examined by modeling

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Peng, Z.; Day, D. A.; Stark, H.; Li, R.; Lee-Taylor, J.; Palm, B. B.; Brune, W. H.; Jimenez, J. L.

    2015-11-20

    Oxidation flow reactors (OFRs) using OH produced from low-pressure Hg lamps at 254 nm (OFR254) or both 185 and 254 nm (OFR185) are commonly used in atmospheric chemistry and other fields. OFR254 requires the addition of externally formed O3 since OH is formed from O3 photolysis, while OFR185 does not since O2 can be photolyzed to produce O3, and OH can also be formed from H2O photolysis. In this study, we use a plug-flow kinetic model to investigate OFR properties under a very wide range of conditions applicable to both field and laboratory studies. We show that the radical chemistrymore » in OFRs can be characterized as a function of UV light intensity, H2O concentration, and total external OH reactivity (OHRext, e.g., from volatile organic compounds (VOCs), NOx, and SO2). OH exposure is decreased by added external OH reactivity. OFR185 is especially sensitive to this effect at low UV intensity due to low primary OH production. OFR254 can be more resilient against OH suppression at high injected O3 (e.g., 70 ppm), as a larger primary OH source from O3, as well as enhanced recycling of HO2 to OH, make external perturbations to the radical chemistry less significant. However if the external OH reactivity in OFR254 is much larger than OH reactivity from injected O3, OH suppression can reach 2 orders of magnitude. For a typical input of 7 ppm O3 (OHRO3 = 10 s−1), 10-fold OH suppression is observed at OHRext ~ 100 s−1, which is similar or lower than used in many laboratory studies. The range of modeled OH suppression for literature experiments is consistent with the measured values except for those with isoprene. The finding on OH suppression may have important implications for the interpretation of past laboratory studies, as applying OHexp measurements acquired under different conditions could lead to over a 1-order-of-magnitude error in the estimated OHexp. The uncertainties of key model outputs due to uncertainty in all rate constants and absorption cross-sections in the model are within ±25 % for OH exposure and within ±60 % for other parameters. These uncertainties are small relative to the dynamic range of outputs. Uncertainty analysis shows that most of the uncertainty is contributed by photolysis rates of O3, O2, and H2O and reactions of OH and HO2 with themselves or with some abundant species, i.e., O3 and H2O2. OHexp calculated from direct integration and estimated from SO2 decay in the model with laminar and measured residence time distributions (RTDs) are generally within a factor of 2 from the plug-flow OHexp. However, in the models with RTDs, OHexp estimated from SO2 is systematically lower than directly integrated OHexp in the case of significant SO2 consumption. We thus recommended using OHexp estimated from the decay of the species under study when possible, to obtain the most appropriate information on photochemical aging in the OFR. Using HOx-recycling vs. destructive external OH reactivity only leads to small changes in OHexp under most conditions. Changing the identity (rate constant) of external OH reactants can result in substantial changes in OHexp due to different reductions in OH suppression as the reactant is consumed. We also report two equations for estimating OH exposure in OFR254. We find that the equation estimating OHexp from measured O3 consumption performs better than an alternative equation that does not use it, and thus recommend measuring both input and output O3 concentrations in OFR254 experiments. This study contributes to establishing a firm and systematic understanding of the gas-phase HOx and Ox chemistry in these reactors, and enables better experiment planning and interpretation as well as improved design of future reactors.« less

  15. The International Framework for Maintaining Equivalence and Traceability in Radionuclide Metrology

    SciTech Connect (OSTI)

    Woods, Mike; Sahagia, Maria

    2008-08-14

    Confidence that a testing or calibration laboratory consistently obtains reliable results is of major importance to users of laboratory services and participation in proficiency testing schemes provides laboratories with an objective means of assessing and demonstrating the level of confidence that can be ascribed to the reliability of the data they are producing. That level of confidence, in turn, depends on the quality of the proficiency tests and, in particular, on the accuracy of the property values associated with the test samples. In the ideal situation, the relevant property value, such as the activity of a particular radionuclide in a test matrix, will be directly traceable to the SI via comparisons with a national or international metrology institute (NMI). This, in turn, begs the question of, how reliable are the results from that NMI.Demonstration of that reliability at the highest metrological levels is achieved through inter-laboratory comparisons that are conducted between national and international metrological institutes. These are coordinated primarily by the Bureau International des Poids et Mesures (BIPM) via Key Comparisons or by comparisons within Regional Metrological Organisations (RMOs), with the results from those RMO exercises being linked to the BIPM Key Comparison results. Such programmes have been in place for many years but they have grown in importance and frequency over the past decade. Tabulation of these comparison data has been regularized recently and made available to the user communities via the BIPM Key Comparison Database (KCDB).In the field of ionizing radiation, the radionuclide metrology discipline exhibits a number of special features. For example, these include the number of potential radionuclides in a user sample; the variety of physical and chemical formats that may be presented; the statistical and temporal effects of radioactive decay; the variations in primary standardization techniques; and the restricted applicability of those primary standardization techniques to the full range of potential radionuclides and activities. Each of these, singly or in combination, ensure that there can never be a fully comprehensive set of Key Comparisons which will cover the requirements of the user community and, in turn, compromise the ability to provide a full range of proficiency tests for testing and calibration laboratories.These problems are discussed, in the context of radioactivity measurements, together with the structure and range of Key Comparisons and associated databases at the highest international level that are currently in place to underpin the proficiency tests that are necessary for the user communities in this field of application.

  16. Final Report for Research in High Energy Physics at the University of Pennsylvania for the period ending April 30, 2012

    SciTech Connect (OSTI)

    Williams, Hugh H.; Balasubramanian, V.; Bernstein, G.; Beier, E. W.; Cvetiˇc, M.; Gladney, L.; Jain, B.; Klein, J.; Kroll, J.; Lipeles, E.; Ovrut, B.; Thomson, E.

    2015-07-23

    The University of Pennsylvania elementary particle physics/particle cosmology group, funded by the Department of Energy Office of Science, participates in research in high energy physics and particle cosmology that addresses some of the most important unanswered questions in science. The research is divided into five areas. Energy Frontier - We participate in the study of proton-proton collisions at the Large Hadron Collider in Geneva, Switzerland using the ATLAS detector. The University of Pennsylvania group was responsible for the design, installation, and commissioning of the front-end electronics for the Transition Radiation Tracker (TRT) and plays the primary role in its maintenance and operation. We play an important role in the triggering of ATLAS, and we have made large contributions to the TRT performance and to the study and identification of electrons, photons, and taus. We have been actively involved in searches for the Higgs boson and for SUSY and other exotic particles. We have made significant contributions to measurement of Standard Model processes such as inclusive photon production and WW pair production. We also have participated significantly in R&D for upgrades to the ATLAS detector. Cosmic Frontier - The Dark Energy Survey (DES) telescope will be used to elucidate the nature of dark energy and the distribution of dark matter. Penn has played a leading role both in the use of weak gravitational lensing of distant galaxies and the discovery of large numbers of distant supernovae. The techniques and forecasts developed at Penn are also guiding the development of the proposed Large Synoptic Survey Telescope (LSST).We are also developing a new detector, MiniClean, to search for direct detection of dark matter particles. Intensity Frontier - We are participating in the design and R&D of detectors for the Long Baseline Neutrino Experiment (now DUNE), a new experiment to study the properties of neutrinos. Advanced Techology R&D - We have an extensive involvement in electronics required for sophisticated new detectors at the LHC and are developing electronics for the LSST camera. Theoretical Physics - We are carrying out a broad program studying the fundamental forces of nature and early universe cosmology and mathematical physics. Our activities span the range from model building, formal field theory, and string theory to new paradigms for cosmology and the interface of string theory with mathematics. Our effort combines extensive development of the formal aspects of string theory with a focus on real phenomena in particle physics, cosmology and gravity.

  17. TEXAS LPG FUEL CELL DEVELOPMENT AND DEMONSTRATION PROJECT Full-Text - Submission contains both citation data and full-text of the journal article. Full-text can be either a pre-print or post-print, but not the copyrighted article.

    SciTech Connect (OSTI)

    SOUTHWEST RESEARCH LABORATORY SUBMITTED BY SUBCONTRACTOR, RAILROAD COMMISSION OF TEXAS

    2004-07-26

    The State Energy Conservation Office has executed its first Fuel Cell Project which was awarded under a Department of Energy competitive grant process. The Texas LPG Fuel Processor Development and Fuel Cell Demonstration Program is a broad-based public/private partnership led by the Texas State Energy Conservation Office (SECO). Partners include the Alternative Fuels Research and Education Division (AFRED) of the Railroad Commission of Texas; Plug Power, Inc., Latham, NY, UOP/HyRadix, Des Plaines, IL; Southwest Research Institute (SwRI), San Antonio, TX; the Texas Natural Resource Conservation Commission (TNRCC), and the Texas Department of Transportation (TxDOT). The team proposes to mount a development and demonstration program to field-test and evaluate markets for HyRadix?s LPG fuel processor system integrated into Plug Power?s residential-scale GenSys 5C (5 kW) PEM fuel cell system in a variety of building types and conditions of service. The program?s primary goal is to develop, test, and install a prototype propane-fueled residential fuel cell power system supplied by Plug Power and HyRadix in Texas. The propane industry is currently funding development of an optimized propane fuel processor by project partner UOP/HyRadix through its national checkoff program, the Propane Education and Research Council (PERC). Following integration and independent verification of performance by Southwest Research Institute, Plug Power and HyRadix will produce a production-ready prototype unit for use in a field demonstration. The demonstration unit produced during this task will be delivered and installed at the Texas Department of Transportation?s TransGuide headquarters in San Antonio, Texas. Simultaneously, the team will undertake a market study aimed at identifying and quantifying early-entry customers, technical and regulatory requirements, and other challenges and opportunities that need to be addressed in planning commercialization of the units. For further information please contact Mary-Jo Rowan at mary-jo.rowan@cpa.state.tx.us

  18. DISCRETE ELEMENT MODELING OF BLADE–STRIKE FREQUENCY AND SURVIVAL OF FISH PASSING THROUGH HYDROKINETIC TURBINES

    SciTech Connect (OSTI)

    Romero Gomez, Pedro DJ; Richmond, Marshall C.

    2014-04-17

    Evaluating the consequences from blade-strike of fish on marine hydrokinetic (MHK) turbine blades is essential for incorporating environmental objectives into the integral optimization of machine performance. For instance, experience with conventional hydroelectric turbines has shown that innovative shaping of the blade and other machine components can lead to improved designs that generate more power without increased impacts to fish and other aquatic life. In this work, we used unsteady computational fluid dynamics (CFD) simulations of turbine flow and discrete element modeling (DEM) of particle motion to estimate the frequency and severity of collisions between a horizontal axis MHK tidal energy device and drifting aquatic organisms or debris. Two metrics are determined with the method: the strike frequency and survival rate estimate. To illustrate the procedure step-by-step, an exemplary case of a simple runner model was run and compared against a probabilistic model widely used for strike frequency evaluation. The results for the exemplary case showed a strong correlation between the two approaches. In the application case of the MHK turbine flow, turbulent flow was modeled using detached eddy simulation (DES) in conjunction with a full moving rotor at full scale. The CFD simulated power and thrust were satisfactorily comparable to experimental results conducted in a water tunnel on a reduced scaled (1:8.7) version of the turbine design. A cloud of DEM particles was injected into the domain to simulate fish or debris that were entrained into the turbine flow. The strike frequency was the ratio of the count of colliding particles to the crossing sample size. The fish length and approaching velocity were test conditions in the simulations of the MHK turbine. Comparisons showed that DEM-based frequencies tend to be greater than previous results from Lagrangian particles and probabilistic models, mostly because the DEM scheme accounts for both the geometric aspects of the passage event ---which the probabilistic method does--- as well as the fluid-particle interactions ---which the Lagrangian particle method does. The DEM-based survival rates were comparable to laboratory results for small fish but not for mid-size fish because of the considerably different turbine diameters. The modeling framework can be used for applications that aim at evaluating the biological performance of MHK turbine units during the design phase and to provide information to regulatory agencies needed for the environmental permitting process.

  19. HR Public meeting

    ScienceCinema (OSTI)

    None

    2011-10-06

    Cher(e)s collègues, En collaboration avec le Département HR, le Directeur général a le plaisir de vous convier à une réunion publique qui se tiendra le vendredi 25 juin 2010 à 9h30 dans l?Amphithéâtre principal (Bâtiment 500)*. Un café d?accueil y sera servi à partir de 9h. Cette réunion abordera les thèmes suivants : ? Valeurs de l?Organisation (Directeur général) ? Code de Conduite (Directeur général / Anne-Sylvie Catherin) ? Création du nouveau rôle d?Ombudsperson (Vincent Vuillemin) Ces présentations seront suivies d?une séance de questions-réponses. Nous espérons vous retrouver nombreux le 25 juin ! Meilleures salutations, Anne-Sylvie Catherin Chef du Département des Ressources humaines *Cette réunion sera retransmise simultanément dans l?Amphithéâtre BE de Prévessin (Bâtiment 864) et également disponible à l?adresse suivante : http://webcast.cern.ch -------------------------------------------------------- Dear colleagues, In collaboration with HR Department, the Director-General would like to invite you to an information meeting which will be held on Friday 25 June 2010 at 9:30 am in the Main Auditorium (Building 500)*. A welcome coffee will be available from 9:00 am. During this meeting, information will be given about: ? Organization?s values (Director-General) ? Code of Conduct (Director-General / Anne-Sylvie Catherin) ? New Ombudsperson role (Vincent Vuillemin) These presentations will be followed by a questions & answers session. We look forward to seeing you all on 25 June! Best regards, Anne-Sylvie Catherin Head, Human Resources Department *This meeting will be simultaneously retransmitted in BE Auditorium (Building 864) and available at the following address: http://webcast.cern.ch.

  20. RECONSTRUCTING REDSHIFT DISTRIBUTIONS WITH CROSS-CORRELATIONS: TESTS AND AN OPTIMIZED RECIPE

    SciTech Connect (OSTI)

    Matthews, Daniel J.; Newman, Jeffrey A., E-mail: djm70@pitt.ed, E-mail: janewman@pitt.ed [Department of Physics and Astronomy, University of Pittsburgh, 3941 O'Hara Street, Pittsburgh, PA 15260 (United States)

    2010-09-20

    Many of the cosmological tests to be performed by planned dark energy experiments will require extremely well-characterized photometric redshift measurements. Current estimates for cosmic shear are that the true mean redshift of the objects in each photo-z bin must be known to better than 0.002(1 + z), and the width of the bin must be known to {approx}0.003(1 + z) if errors in cosmological measurements are not to be degraded significantly. A conventional approach is to calibrate these photometric redshifts with large sets of spectroscopic redshifts. However, at the depths probed by Stage III surveys (such as DES), let alone Stage IV (LSST, JDEM, and Euclid), existing large redshift samples have all been highly (25%-60%) incomplete, with a strong dependence of success rate on both redshift and galaxy properties. A powerful alternative approach is to exploit the clustering of galaxies to perform photometric redshift calibrations. Measuring the two-point angular cross-correlation between objects in some photometric redshift bin and objects with known spectroscopic redshift, as a function of the spectroscopic z, allows the true redshift distribution of a photometric sample to be reconstructed in detail, even if it includes objects too faint for spectroscopy or if spectroscopic samples are highly incomplete. We test this technique using mock DEEP2 Galaxy Redshift survey light cones constructed from the Millennium Simulation semi-analytic galaxy catalogs. From this realistic test, which incorporates the effects of galaxy bias evolution and cosmic variance, we find that the true redshift distribution of a photometric sample can, in fact, be determined accurately with cross-correlation techniques. We also compare the empirical error in the reconstruction of redshift distributions to previous analytic predictions, finding that additional components must be included in error budgets to match the simulation results. This extra error contribution is small for surveys that sample large areas of sky (>{approx}10{sup 0}-100{sup 0}), but dominant for {approx}1 deg{sup 2} fields. We conclude by presenting a step-by-step, optimized recipe for reconstructing redshift distributions from cross-correlation information using standard correlation measurements.