National Library of Energy BETA

Sample records for depth thickness porosity

  1. Porosity reduction in Monterey Formation, California

    SciTech Connect (OSTI)

    Compton, J.S.

    1987-05-01

    Porosity and grain density were determined for different lithologies from throughout a 1.2-km thick section of the Monterey and Sisquoc formations in the Santa Maria basin area, California. Porosity reduction by physical and chemical compaction in the predominantly siliceous sediment is controlled largely by the bulk sediment composition and silica phase transformations. Physical compaction of sediment grains from increasing overburden pressure is responsible for most of the gradual porosity reduction with increasing burial depth in opal-A siliceous ooze and diatomite. The porous, incompressible diatom frustule maintains a high porosity relative to clayey and calcareous sediment. Therefore, a positive correlation exists between porosity and biogenic silica (diatom) content of the sediment. During the opal-A to opal-CT silica phase transformation, solution of the porous diatom frustule and precipitation of cryptocrystalline opal-CT results in a porosity reduction that roughly correlates with the biogenic silica content of the sediment. Local porosity reduction occurs in pore-filling dolomite and chert nodules. Dry bulk density as well as porosity reduction tend to increase with sediment depth. Dolomite and organic matter have the most significant influence on the bulk density because of their respective high and low density. The maximum burial depth of the uplifted and eroded section is estimated by overlapping the porosity-depth relation of average deep-sea siliceous ooze.

  2. Active probing of cloud thickness and optical depth using wide-angle imaging LIDAR.

    SciTech Connect (OSTI)

    Love, Steven P.; Davis, A. B.; Rohde, C. A.; Tellier, L. L.; Ho, Cheng,

    2002-01-01

    At most optical wavelengths, laser light in a cloud lidar experiment is not absorbed but merely scattered out of the beam, eventually escaping the cloud via multiple scattering. There is much information available in this light scattered far from the input beam, information ignored by traditional 'on-beam' lidar. Monitoring these off-beam returns in a fully space- and time-resolved manner is the essence of our unique instrument, Wide Angle Imaging Lidar (WAIL). In effect, WAIL produces wide-field (60{sup o} full-angle) 'movies' of the scattering process and records the cloud's radiative Green functions. A direct data product of WAIL is the distribution of photon path lengths resulting from multiple scattering in the cloud. Following insights from diffusion theory, we can use the measured Green functions to infer the physical thickness and optical depth of the cloud layer. WAIL is notable in that it is applicable to optically thick clouds, a regime in which traditional lidar is reduced to ceilometry. Section 2 covers the up-to-date evolution of the nighttime WAIL instrument at LANL. Section 3 reports our progress towards daytime capability for WAIL, an important extension to full diurnal cycle monitoring by means of an ultra-narrow magneto-optic atomic line filter. Section 4 describes briefly how the important cloud properties can be inferred from WAIL signals.

  3. Active probing of cloud multiple scattering, optical depth, vertical thickness, and liquid water content using wide-angle imaging LIDAR.

    SciTech Connect (OSTI)

    Love, Steven P.; Davis, A. B.; Rohde, C. A.; Tellier, L. L.; Ho, Cheng,

    2002-01-01

    At most optical wavelengths, laser light in a cloud lidar experiment is not absorbed but merely scattered out of the beam, eventually escaping the cloud via multiple scattering. There is much information available in this light scattered far from the input beam, information ignored by traditional 'on-beam' lidar. Monitoring these off-beam returns in a fully space- and time-resolved manner is the essence of our unique instrument, Wide Angle Imaging Lidar (WAIL). In effect, WAIL produces wide-field (60-degree full-angle) 'movies' of the scattering process and records the cloud's radiative Green functions. A direct data product of WAIL is the distribution of photon path lengths resulting from multiple scattering in the cloud. Following insights from diffusion theory, we can use the measured Green functions to infer the physical thickness and optical depth of the cloud layer, and, from there, estimate the volume-averaged liquid water content. WAIL is notable in that it is applicable to optically thick clouds, a regime in which traditional lidar is reduced to ceilometry. Here we present recent WAIL data oti various clouds and discuss the extension of WAIL to full diurnal monitoring by means of an ultra-narrow magneto-optic atomic line filter for daytime measurements.

  4. Controlled porosity in electrodes

    DOE Patents [OSTI]

    Chiang, Yet-Ming; Bae, Chang-Jun; Halloran, John William; Fu, Qiang; Tomsia, Antoni P.; Erdonmez, Can K.

    2015-06-23

    Porous electrodes in which the porosity has a low tortuosity are generally provided. In some embodiments, the porous electrodes can be designed to be filled with electrolyte and used in batteries, and can include low tortuosity in the primary direction of ion transport during charge and discharge of the battery. In some embodiments, the electrodes can have a high volume fraction of electrode active material (i.e., low porosity). The attributes outlined above can allow the electrodes to be fabricated with a higher energy density, higher capacity per unit area of electrode (mAh/cm.sup.2), and greater thickness than comparable electrodes while still providing high utilization of the active material in the battery during use. Accordingly, the electrodes can be used to produce batteries with high energy densities, high power, or both compared to batteries using electrodes of conventional design with relatively highly tortuous pores.

  5. Dual-porosity ribbed fuel cell cathode

    DOE Patents [OSTI]

    Johnsen, Richard; Yuh, Chao-Yi; Alexander, Michael

    2005-05-10

    A fuel cell cathode comprising a cathode body having rib regions and base regions which connect the rib regions, the rib regions being of greater thickness and of less porosity than the base regions.

  6. Microparticles with hierarchical porosity

    DOE Patents [OSTI]

    Petsev, Dimiter N; Atanassov, Plamen; Pylypenko, Svitlana; Carroll, Nick; Olson, Tim

    2012-12-18

    The present disclosure provides oxide microparticles with engineered hierarchical porosity and methods of manufacturing the same. Also described are structures that are formed by templating, impregnating, and/or precipitating the oxide microparticles and method for forming the same. Suitable applications include catalysts, electrocatalysts, electrocatalysts support materials, capacitors, drug delivery systems, sensors and chromatography.

  7. Deep porosity preservation in the Norphlet Formation, Mobil Bay, Alabama

    SciTech Connect (OSTI)

    Ajdukiewicz, J.M.; Paxton, S.T.; Szabvo, J.O. )

    1991-03-01

    Compaction and pressure solution have commonly been assumed to destroy primary intergranular porosity in deeply buried sandstones. However, primary porosities of up to 20% are preserved at depths greater than 20,000 feet in the Norphlet Formation of Mobile Bay. Previous workers have called upon a number of mechanisms to preserve these high porosities in the Norphlet, specifically chlorite rim cements, gas emplacement, overpressuring, and decementation. In contrast, our study of data from 23 Norphlet wells, including 450 thin sections, indicates that these suggested mechanisms are not the primary cause of porosity preservation in the Norphlet. The authors propose an alternative interpretation: that in the Norphlet, as in other well-sorted, ductile-grain-poor sandstones, porosity loss from compaction did not go to completion under reservoir (premetamorphic) conditions, but stabilized at depths of about 5,000-8,000 feet and porosity values of about 26%. Porosity loss below these values is due to cementation. For cementation to occur, both an adequate source of cement and geochemical conditions favoring cement precipitation must be present. Computer simulations of Norphlet burial history, including post-depositional fluid-flow patterns, suggest that conditions favorable to quartz cementation never occurred in the bulk of the Norphlet because of the formation's stratigraphic position and isolation from a basinward source of silica-saturated fluids.

  8. Thermoelectric materials having porosity

    DOE Patents [OSTI]

    Heremans, Joseph P.; Jaworski, Christopher M.; Jovovic, Vladimir; Harris, Fred

    2014-08-05

    A thermoelectric material and a method of making a thermoelectric material are provided. In certain embodiments, the thermoelectric material comprises at least 10 volume percent porosity. In some embodiments, the thermoelectric material has a zT greater than about 1.2 at a temperature of about 375 K. In some embodiments, the thermoelectric material comprises a topological thermoelectric material. In some embodiments, the thermoelectric material comprises a general composition of (Bi.sub.1-xSb.sub.x).sub.u(Te.sub.1-ySe.sub.y).sub.w, wherein 0.ltoreq.x.ltoreq.1, 0.ltoreq.y.ltoreq.1, 1.8.ltoreq.u.ltoreq.2.2, 2.8.ltoreq.w.ltoreq.3.2. In further embodiments, the thermoelectric material includes a compound having at least one group IV element and at least one group VI element. In certain embodiments, the method includes providing a powder comprising a thermoelectric composition, pressing the powder, and sintering the powder to form the thermoelectric material.

  9. Processing and characterization of high porosity aerogel films

    SciTech Connect (OSTI)

    Hrubesh, L.W.; Poco, J.F.

    1994-11-22

    Aerogels are highly porous solids having unique morphology among materials because both the pores and particles making up the material have sizes less than wavelengths of visible light. Such a unique morphology modifies the normal molecular transport mechanisms within the material, resulting in exceptional thermal, acoustical, mechanical, and electrical properties. For example, aerogels have the lowest measured thermal conductivity and dielectric constant for any solid material. Special methods are required to make aerogel films with high porosity. In this paper, we discuss the special conditions needed to fabricate aerogel films having porosities greater than 75% and we describe methods of processing inorganic aerogel films having controllable thicknesses in the range 0.5 to 200 micrometers. We report methods and results of characterizing the films including thickness, refractive index, density (porosity), and dielectric constant. We also discuss results of metallization and patterning on the aerogel films for applications involving microminiature electronics and thermal detectors.

  10. Dual porosity gas evolving electrode

    DOE Patents [OSTI]

    Townsend, C.W.

    1994-11-15

    A dual porosity electrode is described for use in thermoelectrochemical systems where simultaneous transport of gas and liquid into and/or out of the electrode is required. The electrode includes catalytic electrode particles having diameters ranging from about 25 to 100 angstroms. The catalytic electrode particles are anchored to a support network in clusters which have internal pores ranging in size from 25 to 100 angstroms. The pores between the clusters range in size from between about 1 to 20 microns. A method for making the dual porosity electrodes is also disclosed.

  11. Dual porosity gas evolving electrode

    DOE Patents [OSTI]

    Townsend, Carl W. (Los Angeles, CA)

    1994-01-01

    A dual porosity electrode for use in thermoelectrochemical systems where simultaneous transport of gas and liquid into and/or out of the electrode is required. The electrode includes catalytic electrode particles having diameters ranging from about 25 to 100 angstroms. The catalytic electrode particles are anchored to a support network in clusters which have internal pores ranging in size from 25 to 100 angstroms. The pores between the clusters range in size from between about 1 to 20 microns. A method for making the dual porosity electrodes is also disclosed.

  12. Correlating Spatial Heterogeneities in Porosity and Permeability...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Correlating Spatial Heterogeneities in Porosity and Permeability with Metal Poisoning within an Individual Catalyst Particle using X-ray Microscopy Wednesday, August 21, 2013 -...

  13. Fabrication of dual porosity electrode structure

    DOE Patents [OSTI]

    Smith, James L. (Lemont, IL); Kucera, Eugenia H. (Downers Grove, IL)

    1991-01-01

    A substantially entirely fibrous ceramic which may have dual porosity of both micro and macro pores. Total porosity may be 60-75% by volume. A method of spraying a slurry perpendicularly to an ambient stream of air is disclosed along with a method of removing binders without altering the fiber morphology. Adding fine ceramic particulates to the green ceramic fibers enhances the sintering characteristics of the fibers.

  14. Fabrication of dual porosity electrode structure

    DOE Patents [OSTI]

    Smith, J.L.; Kucera, E.H.

    1991-02-12

    A substantially entirely fibrous ceramic is described which may have dual porosity of both micro and macro pores. Total porosity may be 60-75% by volume. A method of spraying a slurry perpendicularly to an ambient stream of air is disclosed along with a method of removing binders without altering the fiber morphology. Adding fine ceramic particulates to the green ceramic fibers enhances the sintering characteristics of the fibers. 3 figures.

  15. Coatings with controlled porosity and chemical properties

    DOE Patents [OSTI]

    Frye, G.C.; Brinker, C.J.; Doughty, D.H.; Bein, T.; Moller, K.

    1996-12-31

    Coatings and sensors are disclosed having both steric and chemical selectivity. Controlled porosity provides the steric selectivity, whereas chemically tailored film properties, using controlled composition or modification by coupling agents, chemical species replacement, or chemical species within pores, provide the chemical selectivity. Single or multiple layers may be provided. 7 figs.

  16. Coatings with controlled porosity and chemical properties

    DOE Patents [OSTI]

    Frye, G.C.; Brinker, C.J.; Doughty, D.H.; Bein, T.; Moller, K.

    1993-07-06

    Coatings and sensors are described having both steric and chemical selectivity. Controlled porosity provides the steric selectivity, whereas chemically tailored film properties, using controlled composition or modification by coupling agents, chemical species replacement, or chemical species within pores, provide the chemical selectivity. Single or multiple layers may be provided.

  17. ARM - Measurement - Snow depth

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Send Measurement : Snow depth Snow depth measured at the surface Categories Surface Properties Instruments The above measurement is considered scientifically relevant for the...

  18. Understanding Porosity in Amorphous Porous Molecular Solids | Center for

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Gas SeparationsRelevant to Clean Energy Technologies | Blandine Jerome Understanding Porosity in Amorphous Porous Molecular Solids

  19. Turbine airfoil with outer wall thickness indicators

    DOE Patents [OSTI]

    Marra, John J; James, Allister W; Merrill, Gary B

    2013-08-06

    A turbine airfoil usable in a turbine engine and including a depth indicator for determining outer wall blade thickness. The airfoil may include an outer wall having a plurality of grooves in the outer surface of the outer wall. The grooves may have a depth that represents a desired outer surface and wall thickness of the outer wall. The material forming an outer surface of the outer wall may be removed to be flush with an innermost point in each groove, thereby reducing the wall thickness and increasing efficiency. The plurality of grooves may be positioned in a radially outer region of the airfoil proximate to the tip.

  20. CONSTRAINTS ON POROSITY AND MASS LOSS IN O-STAR WINDS FROM THE MODELING OF X-RAY EMISSION LINE PROFILE SHAPES

    SciTech Connect (OSTI)

    Leutenegger, Maurice A.; Sundqvist, Jon O.; Owocki, Stanley P.

    2013-06-10

    We fit X-ray emission line profiles in high resolution XMM-Newton and Chandra grating spectra of the early O supergiant {zeta} Pup with models that include the effects of porosity in the stellar wind. We explore the effects of porosity due to both spherical and flattened clumps. We find that porosity models with flattened clumps oriented parallel to the photosphere provide poor fits to observed line shapes. However, porosity models with isotropic clumps can provide acceptable fits to observed line shapes, but only if the porosity effect is moderate. We quantify the degeneracy between porosity effects from isotropic clumps and the mass-loss rate inferred from the X-ray line shapes, and we show that only modest increases in the mass-loss rate ({approx}< 40%) are allowed if moderate porosity effects (h{sub {infinity}} {approx}< R{sub *}) are assumed to be important. Large porosity lengths, and thus strong porosity effects, are ruled out regardless of assumptions about clump shape. Thus, X-ray mass-loss rate estimates are relatively insensitive to both optically thin and optically thick clumping. This supports the use of X-ray spectroscopy as a mass-loss rate calibration for bright, nearby O stars.

  1. Porosity in plasma sprayed alumina coatings

    SciTech Connect (OSTI)

    Ilavsky, J.; Herman, H.; Berndt, C.C.; Goland, A.N.; Long, G.G.; Krueger, S.; Allen, A.J.

    1994-03-01

    Small-angle neutron scattering (SANS) was used to study the porosity of plasma sprayed deposits of alumina in as-sprayed and heat-treated conditions. SANS results were compared with mercury intrusion porosimetry (MIP) and water immersion techniques. Multiple small-angle neutron scattering yields a volume-weighted effective pore radius (R{sub eff}), for pores with sizes between 0.08 and 10{mu}m, the pore volume in this size region, and from the Porod region, the surface area of pores of all sizes.

  2. Synthesis of high porosity, monolithic alumina aerogels

    SciTech Connect (OSTI)

    Poco, J F; Satcher, J H; Hrubesh, L W

    2000-09-20

    Many non-silica aerogels are notably weak and fragile in monolithic form. Particularly, few monolithic aerogels with densities less than 50kg/m3 have any significant strength. It is especially difficult to prepare uncracked monoliths of pure alumina aerogels that are robust and moisture stable. In this paper, we discuss the synthesis of strong, stable, monolithic, high porosity (>98% porous) alumina aerogels, using a two-step sol-gel process. The alumina aerogels have a polycrystalline morphology that results in enhanced physical properties. Most of the measured physical properties of the alumina aerogels are superior to those for silica aerogels for equivalent densities.

  3. Porosity and mechanical properties of zirconium ceramics

    SciTech Connect (OSTI)

    Kalatur, Ekaterina Narikovich, Anton; Buyakova, Svetlana E-mail: kulkov@ispms.tsc.ru; Kulkov, Sergey E-mail: kulkov@ispms.tsc.ru

    2014-11-14

    The article studies the porous ceramics consisting of ultra-fine ZrO{sub 2} powders. The porosity of ceramic samples varied from 15% to 80%. The structure of the ceramic materials had a cellular configuration. The distinctive feature of all experimentally obtained strain diagrams is their nonlinearity at low deformations characterized by the parabolic law. It was shown that the observed nonlinear elasticity for low deformations shown in strain diagrams is due to the mechanical instability of cellular elements of the ceramic framework.

  4. Porosity, permeability, and their relationship in granite, basalt, and tuff

    SciTech Connect (OSTI)

    Not Available

    1983-04-01

    This report discusses the porosity, storage, and permeability of fractured (mainly crystalline) rock types proposed as host rock for nuclear waste repositories. The emphasis is on the inter-relationships of these properties, but a number of reported measurements are included as well. The porosity of rock is shown to consist of fracture porosity and matrix porosity; techniques are described for determining the total interconnected porosity through both laboratory and field measurement. Permeability coefficient, as obtained by experiments ranging from laboratory to crustal scale, is discussed. Finally, the problem of determining the relationship between porosity and permeability is discussed. There is no simple, all encompassing relationship that describes the dependence of permeability upon porosity. However, two particular cases have been successfully analyzed: flow through a single rough fracture, and flow through isotropic porous rock. These two cases are discussed in this report.

  5. Porosity of additive manufacturing parts for process monitoring

    SciTech Connect (OSTI)

    Slotwinski, J. A.; Garboczi, E. J.

    2014-02-18

    Some metal additive manufacturing processes can produce parts with internal porosity, either intentionally (with careful selection of the process parameters) or unintentionally (if the process is not well-controlled.) Material porosity is undesirable for aerospace parts - since porosity could lead to premature failure - and desirable for some biomedical implants, since surface-breaking pores allow for better integration with biological tissue. Changes in a part's porosity during an additive manufacturing build may also be an indication of an undesired change in the process. We are developing an ultrasonic sensor for detecting changes in porosity in metal parts during fabrication on a metal powder bed fusion system, for use as a process monitor. This paper will describe our work to develop an ultrasonic-based sensor for monitoring part porosity during an additive build, including background theory, the development and detailed characterization of reference additive porosity samples, and a potential design for in-situ implementation.

  6. Protections = Defenses in Depth

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Protections = Defenses in Depth Protections = Defense in Depth We use a defense-in-depth strategy to protect the environment. August 1, 2013 Protections = Defense in Depth: Protection #1: Remove the source of contamination; Protection #2: Stabilize, retain or remove contaminated sediments; Protection #3: Sample for known and unexpected contaminants Clean the Past: Protections Protections: Cleanup Cleanup 101 Corrective Measures Process Protection #1: Remove the Source Example Cleanup: Removal of

  7. Porosity, Permeability, And Fluid Flow In The Yellowstone Geothermal...

    Open Energy Info (EERE)

    Y-8) were evaluated to characterize lithology, texture, alteration, and the degree and nature of fracturing and veining. Porosity and matrix permeability measurements and...

  8. Casting Porosity-Free Grain Refined Magnesium Alloys

    SciTech Connect (OSTI)

    Schwam, David

    2013-08-12

    The objective of this project was to identify the root causes for micro-porosity in magnesium alloy castings and recommend remedies that can be implemented in production. The findings confirm the key role played by utilizing optimal gating and risering practices in minimizing porosity in magnesium castings.?

  9. Data Qualification Report: Calculated Porosity and Porosity-Derived Values for Lithostratigraphic Units for use on the Yucca Mountain Project

    SciTech Connect (OSTI)

    P. Sanchez

    2001-05-30

    The qualification is being completed in accordance with the Data Qualification Plan DQP-NBS-GS-000006, Rev. 00 (CRWMS M&O 2001). The purpose of this data qualification activity is to evaluate for qualification the unqualified developed input and porosity output included in Data Tracking Number (DTN) M09910POROCALC.000. The main output of the analyses documented in DTN M09910POROCALC.000 is the calculated total porosity and effective porosity for 40 Yucca Mountain Project boreholes. The porosity data are used as input to Analysis Model Report (AMR) 10040, ''Rock Properties Model'' (MDL-NBS-GS-000004, Rev. 00), Interim Change Notice [ICN] 02 (CRWMS M&O 2000b). The output from the rock properties model is used as input to numerical physical-process modeling within the context of a relationship developed in the AMR between hydraulic conductivity, bound water and zeolitic zones for use in the unsaturated zone model. In accordance with procedure AP-3.15Q, the porosity output is not used in the direct calculation of Principal Factors for post-closure safety or disruptive events. The original source for DTN M09910POROCALC.000 is a Civilian Radioactive Waste Management System (CRWMS) Management and Operating Contractor (M&O) report, ''Combined Porosity from Geophysical Logs'' (CRWMS M&O 1999a and hereafter referred to as Rael 1999). That report recalculated porosity results for both the historical boreholes covered in Nelson (1996), and the modern boreholes reported in CRWMS M&O (1996a,b). The porosity computations in Rael (1999) are based on density-porosity mathematical relationships requiring various input parameters, including bulk density, matrix density and air and/or fluid density and volumetric water content. The main output is computed total porosity and effective porosity reported on a foot-by-foot basis for each borehole, although volumetric water content is derived from neutron data as an interim output. This qualification report uses technical assessment and corroboration to evaluate the original subject DTN. Rael (1999) provides many technical details of the technical assessment and corroboration methods and partially satisfies the intent of the qualification plan for this analysis. Rael presents a modified method based on Nelson (1996) to recompute porosity and porosity-derived values and uses some of the same inputs. Rael's (1999) intended purpose was to document porosity output relatively free of biases introduced by differing computational methods or parameter selections used for different boreholes. The qualification report necessarily evaluates the soundness of the pre-Process Validation and Re-engineering (PVAR) analyses and methodology, as reported in Rael (1999).

  10. Porosity in collapsible Ball Grid Array solder joints

    SciTech Connect (OSTI)

    Gonzalez, C.A. |

    1998-05-01

    Ball Grid Array (BGA) technology has taken off in recent years due to the increased need for high interconnect density. Opposite to all the advantages BGA packages offer, porosity in collapsible BGA solder joints is often a major concern in the reliability of such packages. The effect of pores on the strength of collapsible BGA solder-joints was studied by manufacturing samples with different degrees of porosity and testing them under a shear load. It was found that the shear strength of the solder joints decreased in a linear fashion with increasing porosity. Failure occurred by internal necking of the interpore matrix. It was confirmed that entrapment of flux residues leads to porosity by manufacturing fluxless samples in a specially made furnace, and comparing them with samples assembled using flux. Also, contamination of Au electrodeposits (in substrate metallization) was determined to cause significant porosity. It was found that hard-Au (Co hardened Au) electrodeposits produce high degrees of porosity even in the absence of flux. Finally, increasing the time the solder spends in the molten state was proven to successfully decrease porosity.

  11. Engineering Strength, Porosity, and Emission Intensity of Nanostructur...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Engineering Strength, Porosity, and Emission Intensity of Nanostructured CdSe Networks by Altering the Building-Block Shape Home Author: H. Yu, R. Bellair, R. M. Kannan, S. L....

  12. Properties of Bulk Sintered Silver As a Function of Porosity

    SciTech Connect (OSTI)

    Wereszczak, Andrew A; Vuono, Daniel J; Wang, Hsin; Ferber, Mattison K; Liang, Zhenxian

    2012-06-01

    This report summarizes a study where various properties of bulk-sintered silver were investigated over a range of porosity. This work was conducted within the National Transportation Research Center's Power Device Packaging project that is part of the DOE Vehicle Technologies Advanced Power Electronics and Electric Motors Program. Sintered silver, as an interconnect material in power electronics, inherently has porosity in its produced structure because of the way it is made. Therefore, interest existed in this study to examine if that porosity affected electrical properties, thermal properties, and mechanical properties because any dependencies could affect the intended function (e.g., thermal transfer, mechanical stress relief, etc.) or reliability of that interconnect layer and alter how its performance is modeled. Disks of bulk-sintered silver were fabricated using different starting silver pastes and different sintering conditions to promote different amounts of porosity. Test coupons were harvested out of the disks to measure electrical resistivity and electrical conductivity, thermal conductivity, coefficient of thermal expansion, elastic modulus, Poisson's ratio, and yield stress. The authors fully recognize that the microstructure of processed bulk silver coupons may indeed not be identical to the microstructure produced in thin (20-50 microns) layers of sintered silver. However, measuring these same properties with such a thin actual structure is very difficult, requires very specialized specimen preparation and unique testing instrumentation, is expensive, and has experimental shortfalls of its own, so the authors concluded that the herein measured responses using processed bulk sintered silver coupons would be sufficient to determine acceptable values of those properties. Almost all the investigated properties of bulk sintered silver changed with porosity content within a range of 3-38% porosity. Electrical resistivity, electrical conductivity, thermal conductivity, elastic modulus, Poisson's ratio, and yield stress all depended on the porosity content in bulk-sintered silver. The only investigated property that was independent of porosity in that range was coefficient of thermal expansion.

  13. Enhanced Tissue Adhesion by Increased Porosity and Surface Roughness of

    Office of Scientific and Technical Information (OSTI)

    Carbon Based Biomaterials (Journal Article) | SciTech Connect Journal Article: Enhanced Tissue Adhesion by Increased Porosity and Surface Roughness of Carbon Based Biomaterials Citation Details In-Document Search Title: Enhanced Tissue Adhesion by Increased Porosity and Surface Roughness of Carbon Based Biomaterials Authors: Zimmerman, R. L. [1] ; Ila, Dr. Daryush [1] ; Muntele, C. I. [1] ; Rodrigues, M. G. [2] ; Poker, David B [3] ; Hensley, Dale K [3] + Show Author Affiliations Alabama

  14. Advanced High Porosity Ceramic Honeycomb Wall Flow Filters | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Porosity Ceramic Honeycomb Wall Flow Filters Advanced High Porosity Ceramic Honeycomb Wall Flow Filters 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT). PDF icon deer07_zuberi.pdf More Documents & Publications New Cordierite Diesel Particulate Filters for Catalyzed and Non-Catalyzed Applications Incorporation

  15. Engineering Strength, Porosity, and Emission Intensity of Nanostructured

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CdSe Networks by Altering the Building-Block Shape | Energy Frontier Research Centers Engineering Strength, Porosity, and Emission Intensity of Nanostructured CdSe Networks by Altering the Building-Block Shape Home Author: H. Yu, R. Bellair, R. M. Kannan, S. L. Brock Year: 2008 Abstract: The effect of primary particle shape on the porosity, mechanical strength, and luminescence intensity of metal chalcogenide aerogels was probed by comparison of CdSe aerogels prepared from spherical and

  16. Thick film hydrogen sensor

    DOE Patents [OSTI]

    Hoffheins, B.S.; Lauf, R.J.

    1995-09-19

    A thick film hydrogen sensor element includes an essentially inert, electrically-insulating substrate having deposited thereon a thick film metallization forming at least two resistors. The metallization is a sintered composition of Pd and a sinterable binder such as glass frit. An essentially inert, electrically insulating, hydrogen impermeable passivation layer covers at least one of the resistors. 8 figs.

  17. Thick film hydrogen sensor

    DOE Patents [OSTI]

    Hoffheins, Barbara S. (Knoxville, TN); Lauf, Robert J. (Oak Ridge, TN)

    1995-01-01

    A thick film hydrogen sensor element includes an essentially inert, electrically-insulating substrate having deposited thereon a thick film metallization forming at least two resistors. The metallization is a sintered composition of Pd and a sinterable binder such as glass frit. An essentially inert, electrically insulating, hydrogen impermeable passivation layer covers at least one of the resistors.

  18. Variable depth core sampler

    DOE Patents [OSTI]

    Bourgeois, Peter M. (Hamburg, NY); Reger, Robert J. (Grand Island, NY)

    1996-01-01

    A variable depth core sampler apparatus comprising a first circular hole saw member, having longitudinal sections that collapses to form a point and capture a sample, and a second circular hole saw member residing inside said first hole saw member to support the longitudinal sections of said first hole saw member and prevent them from collapsing to form a point. The second hole saw member may be raised and lowered inside said first hole saw member.

  19. Variable depth core sampler

    DOE Patents [OSTI]

    Bourgeois, P.M.; Reger, R.J.

    1996-02-20

    A variable depth core sampler apparatus is described comprising a first circular hole saw member, having longitudinal sections that collapses to form a point and capture a sample, and a second circular hole saw member residing inside said first hole saw member to support the longitudinal sections of said first hole saw member and prevent them from collapsing to form a point. The second hole saw member may be raised and lowered inside said first hole saw member. 7 figs.

  20. Determining the Porosity and Saturated Hydraulic Conductivity of Binary Mixtures

    SciTech Connect (OSTI)

    Zhang, Z. F.; Ward, Anderson L.; Keller, Jason M.

    2009-09-27

    Gravels and coarse sands make up significant portions of some environmentally important sediments, while the hydraulic properties of the sediments are typically obtained in the laboratory using only the fine fraction (e.g., <2 mm or 4.75 mm). Researchers have found that the content of gravel has significant impacts on the hydraulic properties of the bulk soils. Laboratory experiments were conducted to measure the porosity and the saturated hydraulic conductivity of binary mixtures with different fractions of coarse and fine components. We proposed a mixing-coefficient model to estimate the porosity and a power-averaging method to determine the effective particle diameter and further to predict the saturated hydraulic conductivity of binary mixtures. The proposed methods could well estimate the porosity and saturated hydraulic conductivity of the binary mixtures for the full range of gravel contents and was successfully applied to two data sets in the literature.

  1. Carbon composition with hierarchical porosity, and methods of preparation

    DOE Patents [OSTI]

    Mayes, Richard T; Dai, Sheng

    2014-10-21

    A method for fabricating a porous carbon material possessing a hierarchical porosity, the method comprising subjecting a precursor composition to a curing step followed by a carbonization step, the precursor composition comprising: (i) a templating component comprised of a block copolymer, (ii) a phenolic component, (iii) a dione component in which carbonyl groups are adjacent, and (iv) an acidic component, wherein said carbonization step comprises heating the precursor composition at a carbonizing temperature for sufficient time to convert the precursor composition to a carbon material possessing a hierarchical porosity comprised of mesopores and macropores. Also described are the resulting hierarchical porous carbon material, a capacitive deionization device in which the porous carbon material is incorporated, as well as methods for desalinating water by use of said capacitive deionization device.

  2. Correlating Spatial Heterogeneities in Porosity and Permeability with Metal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Poisoning within an Individual Catalyst Particle using X-ray Microscopy | Stanford Synchrotron Radiation Lightsource Correlating Spatial Heterogeneities in Porosity and Permeability with Metal Poisoning within an Individual Catalyst Particle using X-ray Microscopy Wednesday, August 21, 2013 - 1:30pm SLAC, Conference Room 137-226 Presented by Darius Morris, Stanford Synchrotron Radiation Lightsource Fluid catalytic cracking (FCC) is a refining process for converting large and/or heavy

  3. Incorporation of Catalytic Compounds in the Porosity of SiC Wall...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Incorporation of Catalytic Compounds in the Porosity of SiC Wall Flow Filters - 4 Way Catalyst and DeNOx Application examples Incorporation of Catalytic Compounds in the Porosity...

  4. Laser-Arc Hybrid Welding of Thick Section Ni-base Alloys Advanced Modeling and Experiments

    SciTech Connect (OSTI)

    Debroy, Tarasankar; Palmer, Todd; Zhang, Wei

    2015-05-21

    Hybrid laser-arc welding of nickel-base alloys can increase productivity and decrease costs during construction and repair of critical components in nuclear power plants. However, laser and hybrid welding of nickel-base alloys is not well understood. This project sought to understand the physical processes during hybrid welding necessary to fabricate quality joints in Alloy 690, a Ni- Cr-Fe alloy. This document presents a summary of the data and results collected over the course of the project. The supporting documents are a collection of the research that has been or will be published in peer-reviewed journals along with a report from the partner at the national lab. Understanding the solidification behavior of Alloy 690 is important for knowing the final properties of the weldment. A study was undertaken to calculate the solidification parameters, such as temperature gradient, solidification rate, and cooling rate in Alloy 690 welds. With this information and measured cell and dendrite arm spacings, an Alloy 690 map was constructed to guide process parameter development and interpret fusion zones in later hybrid welds. This research is contained in Solidification Map of a Nickel Base Alloy. The keyhole formed under high laser intensity gives the hybrid welding technique the greater penetration depths compared to arc welding. However, keyhole behavior can form defects in the material, so knowing transient keyhole characteristics is important. With international collaborators, a study was undertaken to validate a new process monitoring tool known as inline coherent imaging (ICI), which is able to measure the keyhole depth with spatial and temporal resolutions on the order of 10 microns and 10 microseconds. ICI was validated for five alloy systems, including Alloy 690. Additionally, the keyhole growth rates at the start of welding were measured with unprecedented accuracy. This research is contained in Real Time Monitoring of Laser Beam Welding Keyhole Depth by Laser Interferometry. During full penetration welding of thick sections, root defects can form, which result in unacceptable weld quality. A study was undertaken to determine the competing forces in root defect formation by independently changing the weight forces and surface tension forces. The weight force was altered by changing the plate thickness, and the surface tension force was altered by changing the surface condition at the bottom surface. Root defects do depend on these two forces. This research is contained in Mitigation of Root Defect in Laser and Hybrid Laser-Arc Welding. Validation of the hybrid laser-arc model is necessary to properly model heat and mass transfer and fluid flow in Alloy 690 hybrid welds. Therefore, the developed model was validated for low carbon steel. Temperatures calculated by the model were included into a microstructural model in order to calculate the phase fractions. Process maps were developed for the selection of welding parameters to avoid martensite formation. This research is contained in Fusion Zone Microstructure in Full Penetration Laser-Arc Hybrid Welding of Low Alloy Steel. Alloy 690 suffers from ductility dip cracking, a form of hot cracking. This type of cracking inhibits the use of multipass welding to join Alloy 690. Our partners at ORNL performed some hot ductility testing with Alloy 690 samples using digital image correlation. The results of this work is contained in the report Summary of 690 ductility dip cracking testing using Gleeble and digital image correlation. Macro-porosity is a limiting factor in the widespread deployment of laser and hybrid laser-arc welding for construction and repair of nuclear power plant components. Keyhole instability and fluctuation results in the formation of large bubbles, which become trapped at the advancing solid- liquid interface as pores. Laser and hybrid laser-arc welds were fabricated for a range of conditions. Porosity levels in the welds were measured in X-ray computed tomography (CT), which provides very detailed data on the size and lo

  5. Process of making porous ceramic materials with controlled porosity

    DOE Patents [OSTI]

    Anderson, Marc A. (Madison, WI); Ku, Qunyin (Madison, WI)

    1993-01-01

    A method of making metal oxide ceramic material is disclosed by which the porosity of the resulting material can be selectively controlled by manipulating the sol used to make the material. The method can be used to make a variety of metal oxide ceramic bodies, including membranes, but also pellets, plugs or other bodies. It has also been found that viscous sol materials can readily be shaped by extrusion into shapes typical of catalytic or adsorbent bodies used in industry, to facilitate the application of such materials for catalytic and adsorbent applications.

  6. On the relationship between formation resistivity factor and porosity

    SciTech Connect (OSTI)

    Perez-Rosales, C.

    1982-08-01

    A theory on the relationship between formation resistivity factor and porosity is presented. This theory considers that, from the standpoint of the flow of electric current within a porous medium saturated with a conducting fluid, the pore space can be divided into flowing and stagnant regions. This assumption leads to a general expression, and formulas currently used in practice are special cases of this expression. The validity of the new expression is established by the use of data corresponding to sandstones and packings and suspensions of particles. For the case of natural rocks, the theory confirms Darcy's equation and gives an interpretation of the physical significance of the so-called cementation exponent.

  7. Porous Polymer Networks: Synthesis, Porosity, and Applications in Gas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Storage/Separation | Center for Gas SeparationsRelevant to Clean Energy Technologies | Blandine Jerome Porous Polymer Networks: Synthesis, Porosity, and Applications in Gas Storage/Separation Previous Next List Weigang Lu, Daqiang Yuan, Dan Zhao, Christine Inge Schilling, Oliver Plietzsch, Thierry Muller, Stefan Bräse, Johannes Guenther, Janet Blümel, Rajamani Krishna, Zhen Li, and Hong-Cai Zhou, Chem. Mater., 2010, 22 (21), pp 5964-5972 DOI: 10.1021/cm1021068 Abstract Image Abstract:

  8. Rational design of metal-organic frameworks with anticipated porosities

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and functionalities | Center for Gas SeparationsRelevant to Clean Energy Technologies | Blandine Jerome Rational design of metal-organic frameworks with anticipated porosities and functionalities Previous Next List Muwei Zhang, Mathieu Bosch, Thomas Gentle III and Hong-Cai Zhou, CrystEngComm, 16, 4069-4083 (2014) DOI: 10.1039/C4CE00321G GA Abstract: Metal-organic frameworks have emerged as a new category of porous materials that have intriguing structures and diverse applications. Even

  9. Discrimination of porosity and fluid saturation using seismic velocity analysis

    DOE Patents [OSTI]

    Berryman, James G. (Danville, CA)

    2001-01-01

    The method of the invention is employed for determining the state of saturation in a subterranean formation using only seismic velocity measurements (e.g., shear and compressional wave velocity data). Seismic velocity data collected from a region of the formation of like solid material properties can provide relatively accurate partial saturation data derived from a well-defined triangle plotted in a (.rho./.mu., .lambda./.mu.)-plane. When the seismic velocity data are collected over a large region of a formation having both like and unlike materials, the method first distinguishes the like materials by initially plotting the seismic velocity data in a (.rho./.lambda., .mu./.lambda.)-plane to determine regions of the formation having like solid material properties and porosity.

  10. ARM - Measurement - Aerosol optical depth

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    depth ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Aerosol optical depth A measure of how much light aerosols prevent from passing through a column of atmosphere. Categories Aerosols Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all available measurements, including

  11. ARM - Measurement - Cloud optical depth

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    optical depth ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Cloud optical depth Amount of light cloud droplets or ice particles prevent from passing through a column of atmosphere. Categories Cloud Properties Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all

  12. Effects of porosity on leaching of Ca from hardened ordinary Portland

    Office of Scientific and Technical Information (OSTI)

    cement paste (Journal Article) | SciTech Connect Effects of porosity on leaching of Ca from hardened ordinary Portland cement paste Citation Details In-Document Search Title: Effects of porosity on leaching of Ca from hardened ordinary Portland cement paste Aiming at evaluating the effects of porosity in hardened cement paste on dissolution phenomena, we prepared hardened ordinary Portland cement (OPC), with variation in pore volume, and then leached them in deionized water. It was found

  13. Predicting Porosity in Clean and Clay-Ricj Sediments Using Resistivity...

    Office of Scientific and Technical Information (OSTI)

    Conference: Predicting Porosity in Clean and Clay-Ricj Sediments Using Resistivity Logs: The Propagation of Errors and Uncertainty Citation Details In-Document Search Title:...

  14. Practical Analysis of materials with depth varying compositions using FT-IR photoacoustic spectroscopy (PAS)

    SciTech Connect (OSTI)

    J.F. McClelland; R.W. Jones; Siquan Luo

    2004-09-30

    FT-IR photoacoustic spectroscopy (PAS) is discussed as a nondestructive method to probe the molecular composition of materials versus depth on the basis of the analysis of layers of experimentally controllable thickness, which are measured from the sample surface to depths of some tens of micrometers, depending on optical and thermal properties. Computational methods are described to process photoacoustic amplitude and phase spectra for both semi-quantitative and quantitative depth analyses. These methods are demonstrated on layered and gradient samples.

  15. Laser detection of material thickness

    DOE Patents [OSTI]

    Early, James W. (Los Alamos, NM)

    2002-01-01

    There is provided a method for measuring material thickness comprising: (a) contacting a surface of a material to be measured with a high intensity short duration laser pulse at a light wavelength which heats the area of contact with the material, thereby creating an acoustical pulse within the material: (b) timing the intervals between deflections in the contacted surface caused by the reverberation of acoustical pulses between the contacted surface and the opposite surface of the material: and (c) determining the thickness of the material by calculating the proportion of the thickness of the material to the measured time intervals between deflections of the contacted surface.

  16. Oxide Film and Porosity Defects in Magnesium Alloy AZ91

    SciTech Connect (OSTI)

    Wang, Liang [Mississippi State University (MSU); Rhee, Hongjoo [Mississippi State University (MSU); Felicelli, Sergio D. [Mississippi State University (MSU); Sabau, Adrian S [ORNL; Berry, John T. [Mississippi State University (MSU)

    2009-01-01

    Porosity is a major concern in the production of light metal parts. This work aims to identify some of the mechanisms of microporosity formation in magnesium alloy AZ91. Microstructure analysis was performed on several samples obtained from gravity-poured ingots in graphite plate molds. Temperature data during cooling was acquired with type K thermocouples at 60 Hz at three locations of each casting. The microstructure of samples extracted from the regions of measured temperature was then characterized with optical metallography. Tensile tests and conventional four point bend tests were also conducted on specimens cut from the cast plates. Scanning electron microscopy was then used to observe the microstructure on the fracture surface of the specimens. The results of this study revealed the existence of abundant oxide film defects, similar to those observed in aluminum alloys. Remnants of oxide films were detected on some pore surfaces, and folded oxides were observed in fracture surfaces indicating the presence of double oxides entrained during pouring.

  17. Rotating drum variable depth sampler

    DOE Patents [OSTI]

    Nance, Thomas A. (Aiken, SC); Steeper, Timothy J. (Trenton, SC)

    2008-07-01

    A sampling device for collecting depth-specific samples in silt, sludge and granular media has three chambers separated by a pair of iris valves. Rotation of the middle chamber closes the valves and isolates a sample in a middle chamber.

  18. Tube wall thickness measurement apparatus

    DOE Patents [OSTI]

    Lagasse, P.R.

    1985-06-21

    An apparatus for measuring the thickness of a tube's wall for the tube's entire length and radius by determining the deviation of the tube wall thickness from the known thickness of a selected standard item. The apparatus comprises a base and a first support member having first and second ends. The first end is connected to the base and the second end is connected to a spherical element. A second support member is connected to the base and spaced apart from the first support member. A positioning element is connected to and movable relative to the second support member. An indicator is connected to the positioning element and is movable to a location proximate the spherical element. The indicator includes a contact ball for first contacting the selected standard item and holding it against the spherical element. The contact ball then contacts the tube when the tube is disposed about the spherical element. The indicator includes a dial having a rotatable needle for indicating the deviation of the tube wall thickness from the thickness of the selected standard item.

  19. Tube wall thickness measurement apparatus

    DOE Patents [OSTI]

    Lagasse, Paul R. (Santa Fe, NM)

    1987-01-01

    An apparatus for measuring the thickness of a tube's wall for the tube's entire length and circumference by determining the deviation of the tube wall thickness from the known thickness of a selected standard item. The apparatus comprises a base and a first support member having first and second ends. The first end is connected to the base and the second end is connected to a spherical element. A second support member is connected to the base and spaced apart from the first support member. A positioning element is connected to and movable relative to the second support member. An indicator is connected to the positioning element and is movable to a location proximate the spherical element. The indicator includes a contact ball for first contacting the selected standard item and holding it against the spherical element. The contact ball then contacts the tube when the tube is disposed about the spherical element. The indicator includes a dial having a rotatable needle for indicating the deviation of the tube wall thickness from the thickness of the selected standard item.

  20. System for measuring film thickness

    DOE Patents [OSTI]

    Batishko, Charles R. (West Richland, WA); Kirihara, Leslie J. (Richland, WA); Peters, Timothy J. (Richland, WA); Rasmussen, Donald E. (Richland, WA)

    1990-01-01

    A system for determining the thicknesses of thin films of materials exhibiting fluorescence in response to exposure to excitation energy from a suitable source of such energy. A section of film is illuminated with a fixed level of excitation energy from a source such as an argon ion laser emitting blue-green light. The amount of fluorescent light produced by the film over a limited area within the section so illuminated is then measured using a detector such as a photomultiplier tube. Since the amount of fluorescent light produced is a function of the thicknesses of thin films, the thickness of a specific film can be determined by comparing the intensity of fluorescent light produced by this film with the intensity of light produced by similar films of known thicknesses in response to the same amount of excitation energy. The preferred embodiment of the invention uses fiber optic probes in measuring the thicknesses of oil films on the operational components of machinery which are ordinarily obscured from view.

  1. Eddy current thickness measurement apparatus

    DOE Patents [OSTI]

    Rosen, Gary J.; Sinclair, Frank; Soskov, Alexander; Buff, James S.

    2015-06-16

    A sheet of a material is disposed in a melt of the material. The sheet is formed using a cooling plate in one instance. An exciting coil and sensing coil are positioned downstream of the cooling plate. The exciting coil and sensing coil use eddy currents to determine a thickness of the solid sheet on top of the melt.

  2. Percolating porosity in ultrafine grained copper processed by High Pressure Torsion

    SciTech Connect (OSTI)

    Wegner, Matthias Leuthold, Jrn; Peterlechner, Martin; Divinski, Sergiy V. Wilde, Gerhard; Setman, Daria; Zehetbauer, Michael; Pippan, Reinhard

    2013-11-14

    Defect structures in copper of different purity (nominally 99.99 and 99.999?wt.?%) deformed via High Pressure Torsion (HPT) with varying processing parameters are investigated utilizing the radiotracer diffusion technique. While the degree of deformation is kept constant, the effects of applied quasi-hydrostatic pressure, processing temperature, post-deformation annealing treatments, and of the impurity concentration on the deformed samples are analyzed in terms of the formation of interconnected internal porosity. Furthermore, the anisotropy of the developing porosity network is examined. The porosity channels occurred to be interconnected along the direction parallel to the surface normal with a volume fraction of the order of a few ppm while no long-range penetration along the internal porosity could be detected when measured along the azimuthal or radial directions of a HPT processed sample.

  3. Estimation of Fracture Porosity in an Unsaturated Fractured Welded Tuff Using Gas Tracer Testing

    SciTech Connect (OSTI)

    B.M. Freifeild

    2001-10-18

    Kinematic fracture porosity is an important hydrologic transport parameter for predicting the potential of rapid contaminant migration through fractured rock. The transport velocity of a solute moving within a fracture network is inversely related to the fracture porosity. Since fracture porosity is often one or two orders of magnitude smaller than matrix porosity, and fracture permeability is often orders of magnitude greater than matrix permeability, solutes may travel significantly faster in the fracture network than in the surrounding matrix. This dissertation introduces a new methodology for conducting gas tracer tests using a field portable mass spectrometer along with analytical tools for estimating fracture porosity using the measured tracer concentration breakthrough curves. Field experiments were conducted at Yucca Mountain, Nevada, consisting of air-permeability transient testing and gas-tracer-transport tests. The experiments were conducted from boreholes drilled within an underground tunnel as part of an investigation of rock mass hydrological behavior. Air-permeability pressure transients, recorded during constant mass flux injections, have been analyzed using a numerical inversion procedure to identify fracture permeability and porosity. Dipole gas tracer tests have also been conducted from the same boreholes used for air-permeability testing. Mass breakthrough data has been analyzed using a random walk particle-tracking model, with a dispersivity that is a function of the advective velocity. The estimated fracture porosity using the tracer test and air-injection test data ranges from .001 to .015. These values are an order of magnitude greater than the values estimated by others using hydraulically estimated fracture apertures. The estimates of porosity made using air-permeability test data are shown to be highly sensitive to formation heterogeneity. Uncertainty analyses performed on the gas tracer test results show high confidence in the parameter estimates made.

  4. Predicting Porosity in Clean and Clay-Ricj Sediments Using Resistivity

    Office of Scientific and Technical Information (OSTI)

    Logs: The Propagation of Errors and Uncertainty (Conference) | SciTech Connect Conference: Predicting Porosity in Clean and Clay-Ricj Sediments Using Resistivity Logs: The Propagation of Errors and Uncertainty Citation Details In-Document Search Title: Predicting Porosity in Clean and Clay-Ricj Sediments Using Resistivity Logs: The Propagation of Errors and Uncertainty No abstract prepared. Authors: Wempe, Wendy ; Mavko, Gary Publication Date: 1999-10-25 OSTI Identifier: 836300 Resource

  5. Property:Depth(m) | Open Energy Information

    Open Energy Info (EERE)

    Depth(m) Jump to: navigation, search This is a property of type String. Pages using the property "Depth(m)" Showing 25 pages using this property. (previous 25) (next 25) 1 1.5-ft...

  6. Recommended Practice: Defense-in-Depth

    Energy Savers [EERE]

    External Report # INL/EXT-06-11478 Control Systems Cyber Security: Defense in Depth Strategies May 2006 Prepared by Idaho National Laboratory Recommended Best Practice: Defense in Depth 2 Table of Contents Keywords............................................................................................................................. 3 Introduction......................................................................................................................... 3 Background

  7. Uterine caliper and depth gauge

    DOE Patents [OSTI]

    King, Loyd L.; Wheeler, Robert G.; Fish, Thomas M.

    1977-01-01

    A uterine caliper and sound consisting of an elongated body having outwardly biased resilient caliper wings and a spring-loaded slidable cervical stop. A slide on the body is operatively connected to the wings by a monofilament and operates with respect to a first scale on the body as a width indicator. A rod extending longitudinally on the body is connected to the cervical stop and cooperates with a second scale on the body as a depth indicator. The instrument can be positioned to measure the distance from the outer cervical ostium to the fundus, as read on said second scale. The wings may be allowed to open by moving the slide, and when the wings engage the utero-tubal junctions, the width may be read on said first scale. By adjustment of the caliper wings the instrument may be retracted until the resistance of the inner ostium of the cervix is felt, enabling the length of the cervical canal to be read directly by the position of the longitudinal indicator rod with respect to said second scale. The instrument may be employed to measure the width of the uterine cavity at any position between the inner ostium of the cervix and the fundus.

  8. Self-Assembling Sup-porosity: The Effect On Fluid Flow And Seismic Wave Propagation

    SciTech Connect (OSTI)

    Pyrak-Nolte, Laura J.

    2013-04-27

    Fractures and joints in the field often contain debris within the void spaces. Debris originates from many different mechanisms: organic and/or inorganic chemical reactions/mineralization, sediment transport, formation of a fracture, mechanical weathering or combinations of these processes. In many cases, the presence of debris forms a ??sub-porosity? within the fracture void space. This sub-porosity often is composed of material that differs from the fracture walls in mineralogy and morphology. The ??sub-porosity? may partially fill voids that are on the order of hundreds of microns and thereby reduce the local porosity to lengths scales on the order of sub-microns to tens of microns. It is quite clear that a sub-porosity affects fracture porosity, permeability and storativity. What is not known is how the existence/formation of a sub-porosity affects seismic wave propagation and consequently our ability to probe changes in the subsurface caused by the formation or alteration of a sub-porosity. If seismic techniques are to be developed to monitor the injection and containment of phases in sequestration reservoirs or the propping of hydraulically induced fracture to enhance oil & gas production, it is important to understand how a sub-porosity within a fracture affects macroscopic seismic and hydraulic measurements. A sub-porosity will directly affect the interrelationship between the seismic and hydraulic properties of a fracture. This reports contains the results of the three main topics of research that were performed (1) to determine the effect of a sub-porosity composed of spherical grains on seismic wave propagation across fractures, (2) to determine the effect of biofilm growth in pores and between grains on seismic wave propagation in sediment, and (3) to determine the effect of the scale of observation (field-of-view) on monitoring alteration the pore space within a fracture caused by reactive flow. A brief summary of the results for each topic is contained in the report and the full details of the research and approach are contained in the publications found in the Attachment section of this report. A list of presentation and publications of all work associated with this grant is also provided.

  9. Causal Factors of Weld Porosity in Gas Tungsten Arc Welding of Powder Metallurgy Produced Titanium Alloys

    SciTech Connect (OSTI)

    Muth, Thomas R; Yamamoto, Yukinori; Frederick, David Alan; Contescu, Cristian I; Chen, Wei; Lim, Yong Chae; Peter, William H; Feng, Zhili

    2013-01-01

    ORNL undertook an investigation using gas tungsten arc (GTA) welding on consolidated powder metallurgy (PM) titanium (Ti) plate, to identify the causal factors behind observed porosity in fusion welding. Tramp element compounds of sodium and magnesium, residual from the metallothermic reduction of titanium chloride used to produce the titanium, were remnant in the starting powder and were identified as gas forming species. PM-titanium made from revert scrap where sodium and magnesium were absent, showed fusion weld porosity, although to a lesser degree. We show that porosity was attributable to hydrogen from adsorbed water on the surface of the powders prior to consolidation. The removal / minimization of both adsorbed water on the surface of titanium powder and the residues from the reduction process prior to consolidation of titanium powders, are critical to achieve equivalent fusion welding success similar to that seen in wrought titanium produced via the Kroll process.

  10. Incorporation of Catalytic Compounds in the Porosity of SiC Wall Flow

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Filters - 4 Way Catalyst and DeNOx Application examples | Department of Energy Incorporation of Catalytic Compounds in the Porosity of SiC Wall Flow Filters - 4 Way Catalyst and DeNOx Application examples Incorporation of Catalytic Compounds in the Porosity of SiC Wall Flow Filters - 4 Way Catalyst and DeNOx Application examples 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's

  11. A nanotubular metal-organic framework with permanent porosity : structure analysis and gas sorption studies.

    SciTech Connect (OSTI)

    Ma, S.; Simmons, J. M.; Li, J. R.; Yuan, D.; Weng, W.; Liu, D. J.; Zhou, H. C.; Chemical Sciences and Engineering Division; Texas A&M Univ.; NIST

    2009-01-01

    A nanotubular metal-organic framework, PCN-19, was constructed based on a micro3-oxo-trinickel basic carboxylate secondary building unit (SBU) and the 9,10-anthracenedicarboxylate ligand; its permanent porosity was confirmed by N2 adsorption isotherms, and its H2 storage performances were evaluated under both low and high pressures at 77 K.

  12. NUMERICAL MODELING OF THE COAGULATION AND POROSITY EVOLUTION OF DUST AGGREGATES

    SciTech Connect (OSTI)

    Okuzumi, Satoshi; Sakagami, Masa-aki [Graduate School of Human and Environmental Studies, Kyoto University, Yoshida-nihonmatsu-cho, Sakyo-ku, Kyoto 606-8501 (Japan); Tanaka, Hidekazu, E-mail: satoshi.okuzumi@ax2.ecs.kyoto-u.ac.j [Institute of Low Temperature Science, Hokkaido University, Sapporo 060-0819 (Japan)

    2009-12-20

    Porosity evolution of dust aggregates is crucial in understanding dust evolution in protoplanetary disks. In this study, we present useful tools to study the coagulation and porosity evolution of dust aggregates. First, we present a new numerical method for simulating dust coagulation and porosity evolution as an extension of the conventional Smoluchowski equation. This method follows the evolution of the mean porosity for each aggregate mass simultaneously with the evolution of the mass distribution function. This method reproduces the results of previous Monte Carlo simulations with much less computational expense. Second, we propose a new collision model for porous dust aggregates on the basis of our N-body experiments on aggregate collisions. As the first step, we focus on 'hit-and-stick' collisions, which involve neither compression nor fragmentation of aggregates. We first obtain empirical data on porosity changes between the classical limits of ballistic cluster-cluster and particle-cluster aggregation. Using the data, we construct a recipe for the porosity change due to general hit-and-stick collisions as well as formulae for the aerodynamical and collisional cross sections. Our collision model is thus more realistic than a previous model of Ormel et al. based on the classical aggregation limits only. Simple coagulation simulations using the extended Smoluchowski method show that our collision model explains the fractal dimensions of porous aggregates observed in a full N-body simulation and a laboratory experiment. By contrast, similar simulations using the collision model of Ormel et al. result in much less porous aggregates, meaning that this model underestimates the porosity increase upon unequal-sized collisions. Besides, we discover that aggregates at the high-mass end of the distribution can have a considerably small aerodynamical cross section per unit mass compared with aggregates of lower masses. This occurs when aggregates drift under uniform acceleration (e.g., gravity) and their collision is induced by the difference in their terminal velocities. We point out an important implication of this discovery for dust growth in protoplanetary disks.

  13. Hollow cylindrical plasma filament waveguide with discontinuous finite thickness cladding

    SciTech Connect (OSTI)

    Alshershby, Mostafa; Hao Zuoqiang; Lin Jingquan

    2013-01-15

    We have explored here a hollow cylindrical laser plasma multifilament waveguide with discontinuous finite thickness cladding, in which the separation between individual filaments is in the range of several millimeters and the waveguide cladding thickness is in the order of the microwave penetration depth. Such parameters give a closer representation of a realistic laser filament waveguide sustained by a long stable propagation of femtosecond (fs) laser pulses. We report how the waveguide losses depend on structural parameters like normalized plasma filament spacing, filament to filament distance or pitch, normal spatial frequency, and radius of the plasma filament. We found that for typical plasma parameters, the proposed waveguide can support guided modes of microwaves in extremely high frequency even with a cladding consisting of only one ring of plasma filaments. The loss of the microwave radiation is mainly caused by tunneling through the discontinuous finite cladding, i.e., confinement loss, and is weakly dependent on the plasma absorption. In addition, the analysis indicates that the propagation loss is fairly large compared with the loss of a plasma waveguide with a continuous infinite thickness cladding, while they are comparable when using a cladding contains more than one ring. Compared to free space propagation, this waveguide still presents a superior microwave transmission to some distance in the order of the filamentation length; thus, the laser plasma filaments waveguide may be a potential channel for transporting pulsed-modulated microwaves if ensuring a long and stable propagation of fs laser pulses.

  14. Cladding Attachment Over Thick Exterior Rigid Insulation

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cladding Attachment Over Thick Exterior Rigid Insulation Peter Baker, P.Eng. BA Webinar: High Performance Enclosure Strategies: Part II, New Construction Cladding Attachment Over Thick Exterior Rigid Insulation Background  Industry trend to using exterior rigid insulation  Increased thermal value  Condensation resistance  Increased air tightness (possibly)  Increased rainwater management (possibly)  Need to develop a means to attach cladding over thick layers of exterior

  15. Control of electrode depth in electroslag remelting

    DOE Patents [OSTI]

    Melgaard, David K.; Shelmidine, Gregory J.; Damkroger, Brian K.

    2002-01-01

    A method of and apparatus for controlling an electroslag remelting furnace by driving the electrode at a nominal speed based upon melting rate and geometry while making minor proportional adjustments based on a measured metric of the electrode immersion depth. Electrode drive speed is increased if a measured metric of electrode immersion depth differs from a set point by a predetermined amount, indicating that the tip is too close to the surface of a slag pool. Impedance spikes are monitored to adjust the set point for the metric of electrode immersion depth based upon one or more properties of the impedance spikes.

  16. A summary report on the search for current technologies and developers to develop depth profiling/physical parameter end effectors

    SciTech Connect (OSTI)

    Nguyen, Q.H.

    1994-09-12

    This report documents the search strategies and results for available technologies and developers to develop tank waste depth profiling/physical parameter sensors. Sources searched include worldwide research reports, technical papers, journals, private industries, and work at Westinghouse Hanford Company (WHC) at Richland site. Tank waste physical parameters of interest are: abrasiveness, compressive strength, corrosiveness, density, pH, particle size/shape, porosity, radiation, settling velocity, shear strength, shear wave velocity, tensile strength, temperature, viscosity, and viscoelasticity. A list of related articles or sources for each physical parameters is provided.

  17. Method for making surfactant-templated, high-porosity thin films

    DOE Patents [OSTI]

    Brinker, C. Jeffrey (Albuquerque, NM); Lu, Yunfeng (San Jose, CA); Fan, Hongyou (Albuquerque, NM)

    2001-01-01

    An evaporation-induced self-assembly method to prepare a surfactant-templated thin film by mixing a silica sol, a surfactant, and a hydrophobic polymer and then evaporating a portion of the solvent during coating onto a substrate and then heating to form a liquid-phase, thin film material with a porosity greater than approximately 50 percent. The high porosity thin films can have dielectric constants less than 2 to be suitable for applications requiring low-dielectric constants. An interstitial compound can be added to the mixture, with the interstitial compound either covalently bonded to the pores or physically entrapped within the porous structure. The selection of the interstitial compound provides a means for developing thin films for applications including membranes, sensors, low dielectric constant films, photonic materials and optical hosts.

  18. Atomistic study of porosity impact on phonon driven thermal conductivity: Application to uranium dioxide

    SciTech Connect (OSTI)

    Colbert, Mehdi; Ribeiro, Fabienne; Trglia, Guy

    2014-01-21

    We present here an analytical method, based on the kinetic theory, to determine the impact of defects such as cavities on the thermal conductivity of a solid. This approach, which explicitly takes into account the effects of internal pore surfaces, will be referred to as the Phonon Interface THermal cONductivity (PITHON) model. Once exposed in the general case, this method is then illustrated in the case of uranium dioxide. It appears that taking properly into account these interface effects significantly modifies the temperature and porosity dependence of thermal conductivity with respect to that issued from either micromechanical models or more recent approaches, in particular, for small cavity sizes. More precisely, it is found that if the mean free path appears to have a major effect in this system in the temperature and porosity distribution range of interest, the variation of the specific heat at the surface of the cavity is predicted to be essential at very low temperature and small sizes for sufficiently large porosity.

  19. Mineral Dissolution and Secondary Precipitation on Quartz Sand in Simulated Hanford Tank Solutions Affecting Subsurface Porosity

    SciTech Connect (OSTI)

    Wang, Guohui; Um, Wooyong

    2012-11-23

    Highly alkaline nuclear waste solutions have been released from underground nuclear waste storage tanks and pipelines into the vadose zone at the U.S. Department of Energys Hanford Site in Washington, causing mineral dissolution and re-precipitation upon contact with subsurface sediments. High pH caustic NaNO3 solutions with and without dissolved Al were reacted with quartz sand through flow-through columns stepwise at 45, 51, and 89C to simulate possible reactions between leaked nuclear waste solution and primary subsurface mineral. Upon reaction, Si was released from the dissolution of quartz sand, and nitrate-cancrinite [Na8Si6Al6O24(NO3)2] precipitated on the quartz surface as a secondary mineral phase. Both steady-state dissolution and precipitation kinetics were quantified, and quartz dissolution apparent activation energy was determined. Mineral alteration through dissolution and precipitation processes results in pore volume and structure changes in the subsurface porous media. In this study, the column porosity increased up to 40.3% in the pure dissolution column when no dissolved Al was present in the leachate, whereas up to a 26.5% porosity decrease was found in columns where both dissolution and precipitation were observed because of the presence of Al in the input solution. The porosity change was also confirmed by calculation using the dissolution and precipitation rates and mineral volume changes.

  20. ARM - PI Product - Niamey Aerosol Optical Depths

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Aerosol Optical Depths ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send PI Product : Niamey Aerosol Optical Depths MFRSR irradiance data collected during the ACRF AMF deployment in Niamey, Niger have been used to derive AOD for five wavelength channels of the MFRSR. These data have been corrected to adjust for filter drift over the course of the campaign and contamination due to forward scattering as a result of

  1. Thick crystalline films on foreign substrates

    DOE Patents [OSTI]

    Smith, H.I.; Atwater, H.A.; Geis, M.W.

    1986-03-18

    To achieve a uniform texture, large crystalline grains or, in some cases, a single crystalline orientation in a thick (>1 [mu]m) film on a foreign substrate, the film is formed so as to be thin (<1 [mu]m) in a certain section. Zone-melting recrystallization is initiated in the thin section and then extended into the thick section. The method may employ planar constriction patterns of orientation filter patterns. 2 figs.

  2. Thick crystalline films on foreign substrates

    DOE Patents [OSTI]

    Smith, Henry I. (Sudbury, MA); Atwater, Harry A. (Somerville, MA); Geis, Michael W. (Acton, MA)

    1986-01-01

    To achieve a uniform texture, large crystalline grains or, in some cases, a single crystalline orientation in a thick (>1 .mu.m) film on a foreign substrate, the film is formed so as to be thin (<1 .mu.m) in a certain section. Zone-melting recrystallization is initiated in the thin section and then extended into the thick section. The method may employ planar constriction patterns of orientation filter patterns.

  3. Lithospheric Thickness Modeled from Long Period Surface Wave Dispersion

    SciTech Connect (OSTI)

    Pasyanos, M E

    2008-05-15

    The behavior of surface waves at long periods is indicative of subcrustal velocity structure. Using recently published dispersion models, we invert surface wave group velocities for lithospheric structure, including lithospheric thickness, over much of the Eastern Hemisphere, encompassing Eurasia, Africa, and the Indian Ocean. Thicker lithosphere under Precambrian shields and platforms are clearly observed, not only under the large cratons (West Africa, Congo, Baltic, Russia, Siberia, India), but also under smaller blocks like the Tarim Basin and Yangtze craton. In contrast, it is found that remobilized Precambrian structures like the Saharan Shield and Sino-Korean Paraplatform do not have well-established lithospheric keels. The thinnest lithospheric thickness is found under oceanic and continental rifts, as well as along convergence zones. We compare our results to thermal models of continental lithosphere, lithospheric cooling models of oceanic lithosphere, lithosphere-asthenosphere boundary (LAB) estimates from S-wave receiver functions, and velocity variations of global tomography models. In addition to comparing results for the broad region, we examine in detail the regions of Central Africa, Siberia, and Tibet. While there are clear differences in the various estimates, overall the results are generally consistent. Inconsistencies between the estimates may be due to a variety of reasons including lateral and depth resolution differences and the comparison of what may be different lithospheric features.

  4. Effect of quartz overgrowth precipitation on the multiscale porosity of sandstone: A (U)SANS and imaging analysis

    SciTech Connect (OSTI)

    Anovitz, Lawrence M.; Cole, David R.; Jackson, Andrew J.; Rother, Gernot; Littrell, Kenneth C.; Allard, Lawrence F.; Pollington, Anthony D.; Wesolowski, David J.

    2015-06-01

    We have performed a series of experiments to understand the effects of quartz overgrowths on nanometer to centimeter scale pore structures of sandstones. Blocks from two samples of St. Peter Sandstone with different initial porosities (5.8 and 18.3%) were reacted from 3 days to 7.5 months at 100 and 200 C in aqueous solutions supersaturated with respect to quartz by reaction with amorphous silica. Porosity in the resultant samples was analyzed using small and ultrasmall angle neutron scattering and scanning electron microscope/backscattered electron (SEM/BSE)-based image-scale processing techniques.Significant changes were observed in the multiscale pore structures. By three days much of the overgrowth in the low-porosity sample dissolved away. The reason for this is uncertain, but the overgrowths can be clearly distinguished from the original core grains in the BSE images. At longer times the larger pores are observed to fill with plate-like precipitates. As with the unreacted sandstones, porosity is a step function of size. Grain boundaries are typically fractal, but no evidence of mass fractal or fuzzy interface behavior was observed suggesting a structural difference between chemical and clastic sediments. After the initial loss of the overgrowths, image scale porosity (>~1 cm) decreases with time. Submicron porosity (typically ~25% of the total) is relatively constant or slightly decreasing in absolute terms, but the percent change is significant. Fractal dimensions decrease at larger scales, and increase at smaller scales with increased precipitation.

  5. Method to produce alumina aerogels having porosities greater than 80 percent

    DOE Patents [OSTI]

    Poco, John F.; Hrubesh, Lawrence W.

    2003-09-16

    A two-step method for producing monolithic alumina aerogels having porosities of greater than 80 percent. Very strong, very low density alumina aerogel monoliths are prepared using the two-step sol-gel process. The method of preparing pure alumina aerogel modifies the prior known sol method by combining the use of substoichiometric water for hydrolysis, the use of acetic acid to control hydrolysis/condensation, and high temperature supercritical drying, all of which contribute to the formation of a polycrystalline aerogel microstructure. This structure provides exceptional mechanical properties of the alumina aerogel, as well as enhanced thermal resistance and high temperature stability.

  6. Porosity in millimeter-scale welds of stainless steel : three-dimensional characterization.

    SciTech Connect (OSTI)

    Aagesen, Larry K.; Madison, Jonathan D.

    2012-05-01

    A variety of edge joints utilizing a continuous wave Nd:YAG laser have been produced and examined in a 304-L stainless steel to advance fundamental understanding of the linkage between processing and resultant microstructure in high-rate solidification events. Acquisition of three-dimensional reconstructions via micro-computed tomography combined with traditional metallography has allowed for qualitative and quantitative characterization of weld joints in a material system of wide use and broad applicability. The presence, variability and distribution of porosity, has been examined for average values, spatial distributions and morphology and then related back to fundamental processing parameters such as weld speed, weld power and laser focal length.

  7. Porosity of coal and shale: Insights from gas adsorption and SANS/USANS techniques

    SciTech Connect (OSTI)

    Mastalerz, Maria; He, Lilin; Melnichenko, Yuri B; Rupp, John A

    2012-01-01

    Two Pennsylvanian coal samples (Spr326 and Spr879-IN1) and two Upper Devonian-Mississippian shale samples (MM1 and MM3) from the Illinois Basin were studied with regard to their porosity and pore accessibility. Shale samples are early mature stage as indicated by vitrinite reflectance (R{sub o}) values of 0.55% for MM1 and 0.62% for MM3. The coal samples studied are of comparable maturity to the shale samples, having vitrinite reflectance of 0.52% (Spr326) and 0.62% (Spr879-IN1). Gas (N{sub 2} and CO{sub 2}) adsorption and small-angle and ultrasmall-angle neutron scattering techniques (SANS/USANS) were used to understand differences in the porosity characteristics of the samples. The results demonstrate that there is a major difference in mesopore (2-50 nm) size distribution between the coal and shale samples, while there was a close similarity in micropore (<2 nm) size distribution. Micropore and mesopore volumes correlate with organic matter content in the samples. Accessibility of pores in coal is pore-size specific and can vary significantly between coal samples; also, higher accessibility corresponds to higher adsorption capacity. Accessibility of pores in shale samples is low.

  8. Defense-in-Depth, How Department of Energy Implements Radiation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Defense-in-Depth, How Department of Energy Implements Radiation Protection in Low Level Waste Disposal Defense-in-Depth, How Department of Energy Implements Radiation Protection in ...

  9. Pd conductor for thick film hydrogen sensor

    SciTech Connect (OSTI)

    Felten, J.J.; Hoffheins, B.S.; Lauf, R.J.

    1996-12-31

    Cooperation between a materials developer and sensor designers has resulted in a palladium conductor used ro design and build a new hydrogen sensor that has superior performance characteristics and is also inexpensive to manufacture. Material characteristics give it faster response time and greater thermal/mechanical stability. The thick film palladium conductor paste, which can be fired at 850{degrees}C-950{degrees}C, has provided device designers a practical conductor paste with which to produce the improved sensor. The conductor uses a high surface area Pd powder combined with a binder glass that is chemically very inert, which combination produces a porous conductor that has good adhesion and chemical resistance. The current sensor design consists of three or four thick film Layers. Because of the flexibility of thick film techniques, the sensor element can be configured to any desired size and shape for specific instrument needs.

  10. Wall thickness measuring method and apparatus

    DOE Patents [OSTI]

    Salzer, Leander J. (Los Alamos, NM); Bergren, Donald A. (Los Alamos, NM)

    1989-01-01

    An apparatus for measuring the wall thickness of a nonmagnetic article having a housing supporting a magnet and a contiguous supporting surface. The tubular article and the housing are releasably secured to the supporting surface and a support member of an optical comparator, respectively. To determine the wall thickness of the article at a selected point, a magnetically responsive ball is positioned within the tubular article over said point and retained therein by means of a magnetic field produced by the magnet. Thereafter, an optical comparator is employed to project a magnified image of the ball on a screen and the wall thickness at the selected point is calculated by using a ball surface measurement taken with the comparator in conjunction with a previously determined base line measurement.

  11. Wall thickness measuring method and apparatus

    DOE Patents [OSTI]

    Salzer, L.J.; Bergren, D.A.

    1987-10-06

    An apparatus for measuring the wall thickness of a nonmagnetic article having a housing supporting a magnet and a contiguous supporting surface. The tubular article and the housing are releasably secured to the supporting surface and a support member of an optical comparator, respectively. To determine the wall thickness of the article at a selected point, a magnetically responsive ball is positioned within the tubular article over said point and retained therein by means of a magnetic field produced by the magnet. Thereafter, an optical comparator is employed to project a magnified image of the ball on a screen and the wall thickness at the selected point is calculated by using a ball surface measurement taken with the comparator in conjunction with a previously determined base line measurement.

  12. Hot rolling of thick uranium molybdenum alloys

    DOE Patents [OSTI]

    DeMint, Amy L.; Gooch, Jack G.

    2015-11-17

    Disclosed herein are processes for hot rolling billets of uranium that have been alloyed with about ten weight percent molybdenum to produce cold-rollable sheets that are about one hundred mils thick. In certain embodiments, the billets have a thickness of about 7/8 inch or greater. Disclosed processes typically involve a rolling schedule that includes a light rolling pass and at least one medium rolling pass. Processes may also include reheating the rolling stock and using one or more heavy rolling passes, and may include an annealing step.

  13. Gas turbine bucket wall thickness control

    DOE Patents [OSTI]

    Stathopoulos, Dimitrios (Glenmont, NY); Xu, Liming (Greenville, SC); Lewis, Doyle C. (Greer, SC)

    2002-01-01

    A core for use in casting a turbine bucket including serpentine cooling passages is divided into two pieces including a leading edge core section and a trailing edge core section. Wall thicknesses at the leading edge and the trailing edge of the turbine bucket can be controlled independent of each other by separately positioning the leading edge core section and the trailing edge core section in the casting die. The controlled leading and trailing edge thicknesses can thus be optimized for efficient cooling, resulting in more efficient turbine operation.

  14. Experimental study of the relationship between formation factor, porosity, and cementation

    SciTech Connect (OSTI)

    Harig, M.D.; Chaney, R.C.

    1999-07-01

    Cemented granular soils are classified based on the size and distribution of the individual grains and qualitatively on the basis of cementation. To uniquely classify these types of soils, information about the fabric (pore geometry and/or level of cementation) of the specimen needs to be quantified. Electrical resistivity, or its reciprocal, conductivity, methods have been extensively used both in situ and in the laboratory to provide a means for determining a variety of soil index, structural, erosional, and cyclic properties. The objective of this study was to determine the relationship between formation factor (F), porosity (n), and cementation factor (m) of remolded sand-cement specimens. This relationship is shown to provide a mechanism for estimating the level of cementation in undisturbed specimens. The formation factor is the ratio of the electrical resistivity of the sand-water-cement mixture to that of the interstitial water.

  15. DEFORMATION AND FRACTURE OF POORLY CONSOLIDATED MEDIA - Borehole Failure Mechanisms in High-Porosity Sandstone

    SciTech Connect (OSTI)

    Bezalel c. Haimson

    2005-06-10

    We investigated failure mechanisms around boreholes and the formation of borehole breakouts in high-porosity sandstone, with particular interest to grain-scale micromechanics of failure leading to the hitherto unrecognized fracture-like borehole breakouts and apparent compaction band formation in poorly consolidated granular materials. We also looked at a variety of drilling-related factors that contribute to the type, size and shape of borehole breakouts. The objective was to assess their effect on the ability to establish correlations between breakout geometry and in situ stress magnitudes, as well as on borehole stability prediction, and hydrocarbon/water extraction in general. We identified two classes of medium to high porosity (12-30%) sandstones, arkosic, consisting of 50-70% quartz and 15 to 50% feldspar, and quartz-rich sandstones, in which quartz grain contents varied from 90 to 100%. In arkose sandstones critical far-field stress magnitudes induced compressive failure around boreholes in the form of V-shaped (dog-eared) breakouts, the result of dilatant intra-and trans-granular microcracking subparallel to both the maximum horizontal far-field stress and to the borehole wall. On the other hand, boreholes in quartz-rich sandstones failed by developing fracture-like breakouts. These are long and very narrow (several grain diameters) tabular failure zones perpendicular to the maximum stress. Evidence provided mainly by SEM observations suggests a failure process initiated by localized grain-bond loosening along the least horizontal far-field stress springline, the packing of these grains into a lower porosity compaction band resembling those discovered in Navajo and Aztec sandstones, and the emptying of the loosened grains by the circulating drilling fluid starting from the borehole wall. Although the immediate several grain layers at the breakout tip often contain some cracked or even crushed grains, the failure mechanism enabled by the formation of the compaction band is largely non-dilatant, a major departure from the dilatant mechanism observed in Tablerock sandstone. The experimental results suggest that unlike our previous assertion, the strength of grain bonding and the mineral composition, rather than the porosity, are major factors in the formation of compaction bands and the ensuing fracture-like breakouts. Some breakout dimensions in all rocks were correlatable to the far-field principal stresses, and could potentially be used (in conjunction with other information) as indicators of their magnitudes. However, we found that several factors can significantly influence breakout geometry. Larger boreholes and increased drilling-fluid flow rates produce longer fracture-like breakouts, suggesting that breakouts in field-scale wellbores could reach considerable lengths. On the other hand, increased drilling-fluid weight and increased drill-bit penetration rate resulted in a decrease in breakout length. These results indicate that breakout growth can be controlled to some degree by manipulating drilling variables. Realizing how drilling variables impact borehole breakout formation is important in understanding the process by which breakouts form and their potential use as indicators of the far-field in situ stress magnitudes and as sources of sand production. As our research indicates, the final breakout size and mechanism of formation can be a function of several variables and conditions, meaning there is still much to be understood about this phenomenon.

  16. The role and importance of porosity in the deflagration rates of HMX-based materials

    SciTech Connect (OSTI)

    Glascoe, E A; Hsu, P C; Springer, H K

    2011-03-15

    The deflagration behavior of thermally damaged HMX-based materials will be discussed. Strands of material were burned at pressures ranging from 10-300 MPa using the LLNL high pressure strand burner. Strands were heated in-situ and burned while still hot; temperatures range from 90-200 C and were chosen in order to allow for thermal damage of the material without significant decomposition of the HMX. The results indicate that multiple variables affect the burn rate but the most important are the polymorph of HMX and the nature and thermal stability of the non-HE portion of the material. Characterization of the strands indicate that the thermal soak produces significant porosity and permeability in the sample allowing for significantly faster burning due to the increased surface area and new pathways for flame spread into the material. Specifically, the deflagration rates of heated PBXN-9, LX-10, and PBX-9501 will be discussed and compared.

  17. Use of a Naphthalene-Based Binder in Injection Molding Net-Shape Titanium Components of Controlled Porosity

    SciTech Connect (OSTI)

    Weil, K. Scott; Nyberg, Eric A.; Simmons, Kevin L.

    2005-07-01

    We have recently developed a naphthalene-based binder system for use in powder injection molding (PIM) of ceramic and metallic materials. The use of a binder that can be removed via sublimation offers several unique advantages relative to the typical thermoplastic and/or thermoset binders employed in PIM. One of these is that essentially no volume change takes place during debindering. This offers a relatively facile method of introducing porosity into a net-shape part of potentially complex geometry. In the study described in this paper, the effects of powder loading and subsequent isostatic compaction on the size and amount of porosity in the components produced by this technique were investigated. In general, it was found that the amount of porosity is inversely proportional to the initial concentration of metal powder in the PIM feedstock. Likewise, average pore size displays a similar relationship with powder loading.

  18. Effect of quartz overgrowth precipitation on the multiscale porosity of sandstone: A (U)SANS and imaging analysis

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Anovitz, Lawrence M.; Cole, David R.; Jackson, Andrew J.; Rother, Gernot; Littrell, Kenneth C.; Allard, Lawrence F.; Pollington, Anthony D.; Wesolowski, David J.

    2015-06-01

    We have performed a series of experiments to understand the effects of quartz overgrowths on nanometer to centimeter scale pore structures of sandstones. Blocks from two samples of St. Peter Sandstone with different initial porosities (5.8 and 18.3%) were reacted from 3 days to 7.5 months at 100 and 200 °C in aqueous solutions supersaturated with respect to quartz by reaction with amorphous silica. Porosity in the resultant samples was analyzed using small and ultrasmall angle neutron scattering and scanning electron microscope/backscattered electron (SEM/BSE)-based image-scale processing techniques.Significant changes were observed in the multiscale pore structures. By three days much ofmore » the overgrowth in the low-porosity sample dissolved away. The reason for this is uncertain, but the overgrowths can be clearly distinguished from the original core grains in the BSE images. At longer times the larger pores are observed to fill with plate-like precipitates. As with the unreacted sandstones, porosity is a step function of size. Grain boundaries are typically fractal, but no evidence of mass fractal or fuzzy interface behavior was observed suggesting a structural difference between chemical and clastic sediments. After the initial loss of the overgrowths, image scale porosity (>~1 cm) decreases with time. Submicron porosity (typically ~25% of the total) is relatively constant or slightly decreasing in absolute terms, but the percent change is significant. Fractal dimensions decrease at larger scales, and increase at smaller scales with increased precipitation.« less

  19. Optical spectroscopy of sputtered nanometer-thick yttrium iron garnet films

    SciTech Connect (OSTI)

    Jakubisova-Liskova, Eva Visnovsky, Stefan; Chang, Houchen; Wu, Mingzhong

    2015-05-07

    Nanometer (nm)-thick yttrium iron garnet (Y{sub 3}Fe{sub 5}O{sub 12}, YIG) films present interest for spintronics. This work employs spectral ellipsometry and magneto-optic Kerr effect (MOKE) spectra to characterize nm-thick YIG films grown on single-crystal Gd{sub 3}Ga{sub 5}O{sub 12} substrates by magnetron sputtering. The thickness (t) of the films ranges between 10 nm and 40 nm. Independent on t, the polar MOKE hysteresis loops saturate in the field of about 1.8 kOe, consistent with the saturation magnetization in bulk YIG (4πM{sub s} ≈ 1.75 kG). The MOKE spectrum measured at photon energies between 1.3 eV and 4.5 eV on the 38-nm-thick film agrees with that measured on single-crystal YIG bulk materials. The MOKE spectrum of the 12-nm-thick film still preserves the structure of the bulk YIG but its amplitude at lower photon energies is modified due to the fact that the radiation penetration depth exceeds 20 nm. The t dependence of the MOKE amplitude is consistent with MOKE calculations. The results indicate that the films are stoichiometric, strain free, without Fe{sup 2+}, and preserve bulk YIG properties down to t ≈ 10 nm.

  20. A de Sitter tachyon thick braneworld

    SciTech Connect (OSTI)

    Germn, Gabriel; Herrera-Aguilar, Alfredo; Malagn-Morejn, Dagoberto; Mora-Luna, Refugio Rigel; Rocha, Roldo da E-mail: aha@fis.unam.mx E-mail: rigel@ifm.umich.mx

    2013-02-01

    Among the multiple 5D thick braneworld models that have been proposed in the last years, in order to address several open problems in modern physics, there is a specific one involving a tachyonic bulk scalar field. Delving into this framework, a thick braneworld with a cosmological background induced on the brane is here investigated. The respective field equations derived from the model with a warped 5D geometry are highly non-linear equations, admitting a non-trivial solution for the warp factor and the tachyon scalar field as well, in a de Sitter 4D cosmological background. Moreover, the non-linear tachyonic scalar field, that generates the brane in complicity with warped gravity, has the form of a kink-like configuration. Notwithstanding, the non-linear field equations restricting character does not allow one to easily find thick brane solutions with a decaying warp factor which leads to the localization of 4D gravity and other matter fields. We derive such a thick brane configuration altogether in this tachyon-gravity setup. When analyzing the spectrum of gravity fluctuations in the transverse traceless sector, the 4D gravity is shown to be localized due to the presence of a single zero mode bound state, separated by a continuum of massive Kaluza-Klein (KK) modes by a mass gap. It contrasts with previous results, where there is a KK massive bound excitation providing no clear physical interpretation. The mass gap is determined by the scale of the metric parameter H. Finally, the corrections to Newton's law in this model are computed and shown to decay exponentially. It is in full compliance to corrections reported in previous results (up to a constant factor) within similar braneworlds with induced 4D de Sitter metric, despite the fact that the warp factor and the massive modes have a different form.

  1. Surface hardening of titanium alloys with melting depth controlled by heat sink

    DOE Patents [OSTI]

    Oden, Laurance L. (Albany, OR); Turner, Paul C. (Albany, OR)

    1995-01-01

    A process for forming a hard surface coating on titanium alloys includes providing a piece of material containing titanium having at least a portion of one surface to be hardened. The piece having a portion of a surface to be hardened is contacted on the backside by a suitable heat sink such that the melting depth of said surface to be hardened may be controlled. A hardening material is then deposited as a slurry. Alternate methods of deposition include flame, arc, or plasma spraying, electrodeposition, vapor deposition, or any other deposition method known by those skilled in the art. The surface to be hardened is then selectively melted to the desired depth, dependent on the desired coating thickness, such that a molten pool is formed of the piece surface and the deposited hardening material. Upon cooling a hardened surface is formed.

  2. Thickness measurement locations of mechanical integrity

    SciTech Connect (OSTI)

    Decker, J.R.; Rivas, N.

    1996-07-01

    This paper will describe the importance of establishing thickness measurement location (TNE) criteria. It will also seek to quantify the frequency of inspections and review the methods for establishing techniques to ensure reliability and repeatability of inspections at TMLs using qualified inspectors. Also discussed will be the most useful way to document the results of an inspection and how to effectively maintain consistency in the mechanical integrity program. It reviews different methods of inspection and uses lessons learned from in-service experience with numerous mechanical projects in the petrochemical industry. The importance of qualified inspectors, quality inspection, electronic data acquisition and electronic data storage will be discussed.

  3. Skin thickness effects on in vivo LXRF

    SciTech Connect (OSTI)

    Preiss, I.L.; Washington, W. II

    1995-12-31

    The analysis of lead concentration in bone utilizing LXRF can be adversely effected by overlying issue. A quantitative measure of the attenuation of the 10.5 keV Pb L a x-ray signal by skin and skin equivalent plastic has been conducted. Concentration ranges in plaster of Paris and goat bone from 7 to 90 ppm with attenuators of Lucite{reg_sign} and pig skin were examined. It is concluded that no quantitative or semi quantitative analysis can be achieved if overlying sue thickness exceeds 3 mm for Ph concentrations of less than 30 porn Ph in bone.

  4. Intermediate depth burial of classified transuranic wastes in arid alluvium

    SciTech Connect (OSTI)

    Cochran, J.R. [Sandia National Labs., Albuquerque, NM (United States). Environmental Risk and Decision Analysis Dept.; Crowe, B.M. [Los Alamos National Lab., NM (United States). Geologic Integration Group; Di Sanza, F. [Dept. of Energy, Las Vegas, NV (United States). Nevada Operations Office

    1999-04-01

    Intermediate depth disposal operations were conducted by the US Department of Energy (DOE) at the DOE`s Nevada Test Site (NTS) from 1984 through 1989. These operations emplaced high-specific activity low-level wastes (LLW) and limited quantities of classified transuranic (TRU) wastes in 37 m (120-ft) deep, Greater Confinement Disposal (GCD) boreholes. The GCD boreholes are 3 m (10 ft) in diameter and founded in a thick sequence of arid alluvium. The bottom 15 m (50 ft) of each borehole was used for waste emplacement and the upper 21 m (70 ft) was backfilled with native alluvium. The bottom of each GCD borehole is almost 200 m (650 ft) above the water table. The GCD boreholes are located in one of the most arid portions of the US, with an average precipitation of 13 cm (5 inches) per year. The limited precipitation, coupled with generally warm temperatures and low humidities results in a hydrologic system dominated by evapotranspiration. The US Environmental Protection Agency`s (EPA`s) 40 CFR 191 defines the requirements for protection of human health from disposed TRU wastes. This EPA standard sets a number of requirements, including probabilistic limits on the cumulative releases of radionuclides to the accessible environment for 10,000 years. The DOE Nevada Operations Office (DOE/NV) has contracted with Sandia National Laboratories (Sandia) to conduct a performance assessment (PA) to determine if the TRU wastes emplaced in the GCD boreholes complies with the EPA`s 40 CFR 191 requirements. This paper describes DOE`s actions undertaken to evaluate whether the TRU wastes in the GCD boreholes will, or will not, endanger human health. Based on preliminary modeling, the TRU wastes in the GCD boreholes meet the EPA`s requirements, and are, therefore, protective of human health.

  5. Gulf of Mexico Proved Reserves By Water Depth, 2009

    Gasoline and Diesel Fuel Update (EIA)

    Gulf of Mexico Proved Reserves and Production by Water Depth, 2009 1 Gulf of Mexico Proved Reserves and Production by Water Depth The Gulf of Mexico Federal Offshore region (GOM ...

  6. Pyrolysis of tire rubber: Porosity and adsorption characteristics of the pyrolytic chars

    SciTech Connect (OSTI)

    Miguel, G.S.; Fowler, G.D.; Sollars, C.J.

    1998-06-01

    Tire rubber has been pyrolyzed at various temperatures under a nitrogen atmosphere. The resulting chars have been analyzed for their porosity using nitrogen gas adsorption and for their aqueous adsorption characteristics using phenol, methylene blue, and the reactive dyes Procion Turquoise H-A and Procion Red H-E3B. Nitrogen adsorption isotherms were modeled to the BET and Dubinin-Astakhov (DA) equations to determine effective surface areas, mesopore volumes, and micropore volumes. Results showed that pyrolysis of tire rubber was essentially complete at 500 C and resulted in a char yield of approximately 42 wt%. Pyrolytic chars exhibited BET surface areas up to 85 m{sup 2}/g and micropore volumes up to 0.04 mL/g. Owing to their poorly developed micropore structure, the pyrolytic chars exhibited limited aqueous adsorption capacity for compounds of small molecular weight, such as phenol. However, the chars possessed significantly greater adsorption capacity for species of large molecular weight which was attributed to the presence of large mesopore volumes (up to 0.19 mL/g).

  7. Method and apparatus for in situ determination of permeability and porosity

    DOE Patents [OSTI]

    Lagus, Peter L. (Olivehain, CA); Peterson, Edward W. (Del Mar, CA)

    1982-10-12

    A method and apparatus for in situ measurement of flow characteristics in boreholes or the like is disclosed for determining various formation characteristics such as permeability, particularly in the range of approximately 100-1,000 microdarcies and lower. One embodiment of the method and apparatus contemplates formation of a test interval in the borehole by a pair of expandable packers, additional guard zones being formed in the borehole at either end of the test interval by two additional guard packers, suitable flow conditions being simultaneously and separately measured within the test interval and each of the guard zones in order to permit determination of multidirectional components of permeability, porosity and other characteristics of the particular formation. Another embodiment contemplates whole hole testing where similar data is developed for a test interval formed between a single packer and the end of the borehole and one guard zone formed by a single additional guard packer. The method and apparatus of this invention are particularly contemplated for obtaining unambiguous measurements of multidirectional flow in low permeability formations.

  8. Hyperspectral Aerosol Optical Depths from TCAP Flights

    SciTech Connect (OSTI)

    Shinozuka, Yohei; Johnson, Roy R.; Flynn, Connor J.; Russell, P. B.; Schmid, Beat; Redemann, Jens; Dunagan, Stephen; Kluzek, Celine D.; Hubbe, John M.; Segal-Rosenheimer, Michal; Livingston, J. M.; Eck, T.; Wagener, Richard; Gregory, L.; Chand, Duli; Berg, Larry K.; Rogers, Ray; Ferrare, R. A.; Hair, John; Hostetler, Chris A.; Burton, S. P.

    2013-11-13

    4STAR (Spectrometer for Sky-Scanning, Sun-Tracking Atmospheric Research), the worlds first hyperspectral airborne tracking sunphotometer, acquired aerosol optical depths (AOD) at 1 Hz during all July 2012 flights of the Two Column Aerosol Project (TCAP). Root-mean square differences from AERONET ground-based observations were 0.01 at wavelengths between 500-1020 nm, 0.02 at 380 and 1640 nm and 0.03 at 440 nm in four clear-sky fly-over events, and similar in ground side-by-side comparisons. Changes in the above-aircraft AOD across 3-km-deep spirals were typically consistent with integrals of coincident in situ (on DOE Gulfstream 1 with 4STAR) and lidar (on NASA B200) extinction measurements within 0.01, 0.03, 0.01, 0.02, 0.02, 0.02 at 355, 450, 532, 550, 700, 1064 nm, respectively, despite atmospheric variations and combined measurement uncertainties. Finer vertical differentials of the 4STAR measurements matched the in situ ambient extinction profile within 14% for one homogeneous column. For the AOD observed between 350-1660 nm, excluding strong water vapor and oxygen absorption bands, estimated uncertainties were ~0.01 and dominated by (then) unpredictable throughput changes, up to +/-0.8%, of the fiber optic rotary joint. The favorable intercomparisons herald 4STARs spatially-resolved high-frequency hyperspectral products as a reliable tool for climate studies and satellite validation.

  9. Seismic Velocities Contain Information About Depth, Lithology, Fluid Content, and Microstructure

    SciTech Connect (OSTI)

    Berge, P A; Bonner, B P

    2002-01-03

    Recent advances in field and laboratory methods for measuring elastic wave velocities provide incentive and opportunity for improving interpretation of geophysical data for engineering and environmental applications. Advancing the state-of-the-art of seismic imaging requires developing petrophysical relationships between measured velocities and the hydrogeology parameters and lithology. Our approach uses laboratory data and rock physics methods. Compressional (Vp) and shear (Vs) wave velocities, Vp/Vs ratios, and relative wave amplitudes show systematic changes related to composition, saturation, applied stress (analogous to depth), and distribution of clay for laboratory ultrasonic measurements on soils. The artificial soils were mixtures of Ottawa sand and a second phase, either Wyoming bentonite or peat moss used to represent clay or organic components found in natural soils. Compressional and shear wave velocities were measured for dry, saturated, and partially-saturated conditions, for applied stresses between about 7 and 100 kPa, representing approximately the top 5 m of the subsurface. Analysis of the results using rock physics methods shows the link between microstructure and wave propagation, and implications for future advances in seismic data interpretation. For example, we found that Vp in dry sand-clay mixtures initially increases as clay cements the sand grains and fills porosity, but then Vp decreases when the clay content is high enough that the clay matrix controls the elastic response of the material. Vs decreases monotonically with increasing clay content. This provides a method for using Vp/Vs ratios to estimate clay content in a dry soil.

  10. Radiation phantom with humanoid shape and adjustable thickness

    DOE Patents [OSTI]

    Lehmann, Joerg (Pleasanton, CA); Levy, Joshua (Salem, NY); Stern, Robin L. (Lodi, CA); Siantar, Christine Hartmann (Livermore, CA); Goldberg, Zelanna (Carmichael, CA)

    2006-12-19

    A radiation phantom comprising a body with a general humanoid shape and at least a portion having an adjustable thickness. In one embodiment, the portion with an adjustable thickness comprises at least one tissue-equivalent slice.

  11. Ferroelectric PLZT thick films grown by poly(1-vinylpyrrolidone...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    PLZT thick films grown by poly(1-vinylpyrrolidone-co-vinyl acetate) (PVPVA)-modified sol-gel process Title Ferroelectric PLZT thick films grown by poly(1-vinylpyrrolidone-co-vi...

  12. Reciprocal space XRD mapping with varied incident angle as a probe of structure variation within surface depth

    SciTech Connect (OSTI)

    Yang, Qiguang; Williams, Frances; Zhao, Xin; Reece, Charles E.; Krishnan, Mahadevan

    2013-09-01

    In this study, we used a differential-depth X-Ray diffraction Reciprocal Spacing Mapping (XRD RSM) technique to investigate the crystal quality of a variety of SRF-relevant Nb film and bulk materials. By choosing different X-ray probing depths, the RSM study successfully revealed evolution the of materials? microstructure after different materials processes, such as energetic condensation or surface polishing. The RSM data clearly measured the materials? crystal quality at different thickness. Through a novel differential-depth RSM technique, this study found: I. for a heteroepitaxy Nb film Nb(100)/MgO(100), the film thickening process, via a cathodic arc-discharge Nb ion deposition, created a near-perfect single crystal Nb on the surface?s top-layer; II. for a mechanically polished single-crystal bulk Nb material, the microstructure on the top surface layer is more disordered than that in-grain.

  13. Optical monitor for real time thickness change measurements via lateral-translation induced phase-stepping interferometry

    DOE Patents [OSTI]

    Rushford, Michael C. (Livermore, CA)

    2002-01-01

    An optical monitoring instrument monitors etch depth and etch rate for controlling a wet-etching process. The instrument provides means for viewing through the back side of a thick optic onto a nearly index-matched interface. Optical baffling and the application of a photoresist mask minimize spurious reflections to allow for monitoring with extremely weak signals. A Wollaston prism enables linear translation for phase stepping.

  14. Anomalous porosity preservation and preferential accumulation of gas hydrate in the Andaman accretionary wedge, NGHP-01 site 17A

    SciTech Connect (OSTI)

    Rose, Kelly K.; Johnson, Joel E.; Torres, Marta E.; Hong, WeiLi; Giosan, Liviu; Solomon, E.; Kastner, Miriam; Cawthern, Thomas; Long, Philip E.; Schaef, Herbert T.

    2014-12-01

    In addition to well established properties that control the presence or absence of the hydrate stability zone, such as pressure, temperature, and salinity, additional parameters appear to influence the concentration of gas hydrate in host sediments. The stratigraphic record at Site 17A in the Andaman Sea, eastern Indian Ocean, illustrates the need to better understand the role pore-scale phenomena play in the distribution and presence of marine gas hydrates in a variety of subsurface settings. In this paper we integrate field-generated datasets with newly acquired sedimentology, physical property, imaging and geochemical data with mineral saturation and ion activity products of key mineral phases such as amorphous silica and calcite, to document the presence and nature of secondary precipitates that contributed to anomalous porosity preservation at Site 17A in the Andaman Sea. This study demonstrates the importance of grain-scale subsurface heterogeneities in controlling the occurrence and distribution of concentrated gas hydrate accumulations in marine sediments, and document the importance that increased permeability and enhanced porosity play in supporting gas concentrations sufficient to support gas hydrate formation. The grain scale relationships between porosity, permeability, and gas hydrate saturation documented at Site 17A likely offer insights into what may control the occurrence and distribution of gas hydrate in other sedimentary settings.

  15. A microwave resonator for limiting depth sensitivity for electron paramagnetic resonance spectroscopy of surfaces

    SciTech Connect (OSTI)

    Sidabras, Jason W.; Varanasi, Shiv K.; Hyde, James S.; Mett, Richard R.; Swarts, Steven G.; Swartz, Harold M.

    2014-10-15

    A microwave Surface Resonator Array (SRA) structure is described for use in Electron Paramagnetic Resonance (EPR) spectroscopy. The SRA has a series of anti-parallel transmission line modes that provides a region of sensitivity equal to the cross-sectional area times its depth sensitivity, which is approximately half the distance between the transmission line centers. It is shown that the quarter-wave twin-lead transmission line can be a useful element for design of microwave resonators at frequencies as high as 10 GHz. The SRA geometry is presented as a novel resonator for use in surface spectroscopy where the region of interest is either surrounded by lossy material, or the spectroscopist wishes to minimize signal from surrounding materials. One such application is in vivo spectroscopy of human finger-nails at X-band (9.5 GHz) to measure ionizing radiation dosages. In order to reduce losses associated with tissues beneath the nail that yield no EPR signal, the SRA structure is designed to limit depth sensitivity to the thickness of the fingernail. Another application, due to the resonator geometry and limited depth penetration, is surface spectroscopy in coating or material science. To test this application, a spectrum of 1.44 ?M of Mg{sup 2+} doped polystyrene 1.1 mm thick on an aluminum surface is obtained. Modeling, design, and simulations were performed using Wolfram Mathematica (Champaign, IL; v. 9.0) and Ansys High Frequency Structure Simulator (HFSS; Canonsburg, PA; v. 15.0). A micro-strip coupling circuit is designed to suppress unwanted modes and provide a balanced impedance transformation to a 50 ? coaxial input. Agreement between simulated and experimental results is shown.

  16. Cladding Attachment Over Thick Exterior Insulating Sheathing

    SciTech Connect (OSTI)

    Baker, P.; Eng, P.; Lepage, R.

    2014-01-01

    The addition of insulation to the exterior of buildings is an effective means of increasing the thermal resistance of both wood framed walls as well as mass masonry wall assemblies. For thick layers of exterior insulation (levels greater than 1.5 inches), the use of wood furring strips attached through the insulation back to the structure has been used by many contractors and designers as a means to provide a convenient cladding attachment location (Straube and Smegal 2009, Pettit 2009, Joyce 2009, Ueno 2010). The research presented in this report is intended to help develop a better understanding of the system mechanics involved and the potential for environmental exposure induced movement between the furring strip and the framing. BSC sought to address the following research questions: 1.What are the relative roles of the mechanisms and the magnitudes of the force that influence the vertical displacement resistance of the system? 2.Can the capacity at a specified deflection be reliably calculated using mechanics based equations? 3.What are the impacts of environmental exposure on the vertical displacement of furring strips attached directly through insulation back to a wood structure?

  17. Cladding Attachment Over Thick Exterior Insulating Sheathing

    SciTech Connect (OSTI)

    Baker, P.; Eng, P.; Lepage, R.

    2014-01-01

    The addition of insulation to the exterior of buildings is an effective means of increasing the thermal resistance of both wood framed walls as well as mass masonry wall assemblies. For thick layers of exterior insulation (levels greater than 1.5 inches), the use of wood furring strips attached through the insulation back to the structure has been used by many contractors and designers as a means to provide a convenient cladding attachment location (Straube and Smegal 2009, Pettit 2009, Joyce 2009, Ueno 2010). The research presented in this report is intended to help develop a better understanding of the system mechanics involved and the potential for environmental exposure induced movement between the furring strip and the framing. BSC sought to address the following research questions: 1. What are the relative roles of the mechanisms and the magnitudes of the force that influence the vertical displacement resistance of the system? 2. Can the capacity at a specified deflection be reliably calculated using mechanics based equations? 3. What are the impacts of environmental exposure on the vertical displacement of furring strips attached directly through insulation back to a wood structure?

  18. Method and apparatus of prefetching streams of varying prefetch depth

    DOE Patents [OSTI]

    Gara, Alan; Ohmacht, Martin; Salapura, Valentina; Sugavanam, Krishnan; Hoenicke, Dirk

    2012-01-24

    Method and apparatus of prefetching streams of varying prefetch depth dynamically changes the depth of prefetching so that the number of multiple streams as well as the hit rate of a single stream are optimized. The method and apparatus in one aspect monitor a plurality of load requests from a processing unit for data in a prefetch buffer, determine an access pattern associated with the plurality of load requests and adjust a prefetch depth according to the access pattern.

  19. Ultrasonic thickness measuring and imaging system and method

    DOE Patents [OSTI]

    Bylenok, Paul J. (Clifton Park, NY); Patmos, William M. (Schenectady, NY); Wagner, Thomas A. (Bronswick, NY); Martin, Francis H. (Melrose, NY)

    1992-01-01

    An ultrasonic thickness measuring and imaging system uses an ultrasonic fsed beam probe for measuring thickness of an object, such as a wall of a tube, a computer for controlling movement of the probe in a scanning pattern within the tube and processing an analog signal produced by the probe which is proportional to the tube wall thickness in the scanning pattern, and a line scan recorder for producing a record of the tube wall thicknesses measured by the probe in the scanning pattern. The probe is moved in the scanning pattern to sequentially scan circumferentially the interior tube wall at spaced apart adjacent axial locations. The computer processes the analog signal by converting it to a digital signal and then quantifies the digital signal into a multiplicity of thickness points with each falling in one of a plurality of thickness ranges corresponding to one of a plurality of shades of grey. From the multiplicity of quantified thickness points, a line scan recorder connected to the computer generates a pictorial map of tube wall thicknesses with each quantified thickness point thus being obtained from a minute area, e.g. 0.010 inch by 0.010 inch, of tube wall and representing one pixel of the pictorial map. In the pictorial map of tube wall thicknesses, the pixels represent different wall thicknesses having different shades of grey.

  20. Ultrasonic thickness measuring and imaging system and method

    DOE Patents [OSTI]

    Bylenok, Paul J.; Patmos, William M.; Wagner, Thomas A.; Martin, Francis H.

    1992-08-04

    An ultrasonic thickness measuring and imaging system uses an ultrasonic fsed beam probe for measuring thickness of an object, such as a wall of a tube, a computer for controlling movement of the probe in a scanning pattern within the tube and processing an analog signal produced by the probe which is proportional to the tube wall thickness in the scanning pattern, and a line scan recorder for producing a record of the tube wall thicknesses measured by the probe in the scanning pattern. The probe is moved in the scanning pattern to sequentially scan circumferentially the interior tube wall at spaced apart adjacent axial locations. The computer processes the analog signal by converting it to a digital signal and then quantifies the digital signal into a multiplicity of thickness points with each falling in one of a plurality of thickness ranges corresponding to one of a plurality of shades of grey. From the multiplicity of quantified thickness points, a line scan recorder connected to the computer generates a pictorial map of tube wall thicknesses with each quantified thickness point thus being obtained from a minute area, e.g. 0.010 inch by 0.010 inch, of tube wall and representing one pixel of the pictorial map. In the pictorial map of tube wall thicknesses, the pixels represent different wall thicknesses having different shades of grey.

  1. Advanced Technology Vehicle Lab Benchmarking - Level 2 (in-depth...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Advanced Technology Vehicle Lab Benchmarking - Level 2 (in-depth) Data Collection for Improved Cold Temperature Thermal Modeling Advanced Technology ...

  2. Bouguer gravity anomalies, depth to bedrock, and shallow temperature...

    Open Energy Info (EERE)

    Bouguer gravity anomalies, depth to bedrock, and shallow temperature in the Humboldt House geothermal area, Pershing County, Nevada Jump to: navigation, search OpenEI Reference...

  3. A Comparison of Cirrus Cloud Visible Optical Depth Derived from...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Comparison of Cirrus Cloud Visible Optical Depth Derived from Lidar Lo, Chaomei Pacific Northwest National Laboratory Comstock, Jennifer Pacific Northwest National Laboratory...

  4. Understanding Fault Characteristics And Sediment Depth For Geothermal...

    Open Energy Info (EERE)

    Understanding Fault Characteristics And Sediment Depth For Geothermal Exploration Using 3D Gravity Inversion In Walker Valley, Nevada Jump to: navigation, search OpenEI Reference...

  5. Control Systems Cyber Security: Defense in Depth Strategies ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cyber Security: Defense in Depth Strategies Control Systems Cyber Security: Defense in ... strategies for organizations that use control system networks while maintaining a ...

  6. Average Depth of Crude Oil and Natural Gas Wells

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Depth of Crude Oil and Natural Gas Wells (Feet per Well) Period: Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes...

  7. Thickness determination of few-layer hexagonal boron nitride films by scanning electron microscopy and Auger electron spectroscopy

    SciTech Connect (OSTI)

    Sutter, P. Sutter, E.

    2014-09-01

    We assess scanning electron microscopy (SEM) and Auger electron spectroscopy (AES) for thickness measurements on few-layer hexagonal boron nitride (h-BN), the layered dielectric of choice for integration with graphene and other two-dimensional materials. Observations on h-BN islands with large, atomically flat terraces show that the secondary electron intensity in SEM reflects monolayer height changes in films up to least 10 atomic layers thickness. From a quantitative analysis of AES data, the energy-dependent electron escape depth in h-BN films is deduced. The results show that AES is suitable for absolute thickness measurements of few-layer h-BN of 1 to 6 layers.

  8. Detecting Fractures Using Technology at High Temperatures and Depths -

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Geothermal Ultrasonic Fracture Imager (GUFI); 2010 Geothermal Technology Program Peer Review Report | Department of Energy Detecting Fractures Using Technology at High Temperatures and Depths - Geothermal Ultrasonic Fracture Imager (GUFI); 2010 Geothermal Technology Program Peer Review Report Detecting Fractures Using Technology at High Temperatures and Depths - Geothermal Ultrasonic Fracture Imager (GUFI); 2010 Geothermal Technology Program Peer Review Report DOE 2010 Geothermal

  9. Electrode immersion depth determination and control in electroslag remelting furnace

    DOE Patents [OSTI]

    Melgaard, David K.; Beaman, Joseph J.; Shelmidine, Gregory J.

    2007-02-20

    An apparatus and method for controlling an electroslag remelting furnace comprising adjusting electrode drive speed by an amount proportional to a difference between a metric of electrode immersion and a set point, monitoring impedance or voltage, and calculating the metric of electrode immersion depth based upon a predetermined characterization of electrode immersion depth as a function of impedance or voltage.

  10. Cladding Attachment Over Thick Exterior Sheathing | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cladding Attachment Over Thick Exterior Sheathing Cladding Attachment Over Thick Exterior Sheathing The addition of insulation to the exterior of buildings is an effective means of increasing the thermal resistance of both wood framed walls as well as mass masonry wall assemblies. For thick layers of exterior insulation (levels greater than 1.5 inches), the use of wood furring strips attached through the insulation back to the structure has been used by many contractors and designers as a means

  11. Effects of Volcanism, Crustal Thickness, and Large Scale Faulting...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Evolution of Geothermal Systems: Collaborative Project in Chile Effects of Volcanism, Crustal Thickness, and Large Scale Faulting on the Development and Evolution of ...

  12. Coating thickness and coverage effects on the forces between...

    Office of Scientific and Technical Information (OSTI)

    forces between silica nanoparticles in water. Citation Details In-Document Search Title: Coating thickness and coverage effects on the forces between silica nanoparticles in water. ...

  13. Variable Crustal Thickness In The Western Great Basin- A Compilation...

    Open Energy Info (EERE)

    et al., 2004). In addition, we have created contoured crustal thickness maps based on literature cited from the comprehensive Braile et al. (1989) study. These maps provide a...

  14. Method and apparatus to measure the depth of skin burns

    DOE Patents [OSTI]

    Dickey, Fred M. (Albuquerque, NM); Holswade, Scott C. (Albuquerque, NM)

    2002-01-01

    A new device for measuring the depth of surface tissue burns based on the rate at which the skin temperature responds to a sudden differential temperature stimulus. This technique can be performed without physical contact with the burned tissue. In one implementation, time-dependent surface temperature data is taken from subsequent frames of a video signal from an infrared-sensitive video camera. When a thermal transient is created, e.g., by turning off a heat lamp directed at the skin surface, the following time-dependent surface temperature data can be used to determine the skin burn depth. Imaging and non-imaging versions of this device can be implemented, thereby enabling laboratory-quality skin burn depth imagers for hospitals as well as hand-held skin burn depth sensors the size of a small pocket flashlight for field use and triage.

  15. Heat Flow At Standard Depth | Open Energy Information

    Open Energy Info (EERE)

    to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Heat Flow At Standard Depth Abstract Secular and long-term periodic changes in surface...

  16. Confocal volume in laser Raman microscopy depth profiling

    SciTech Connect (OSTI)

    Maruyama, Yutaka; Kanematsu, Wataru

    2011-11-15

    To clarify the degradation of confocality in laser Raman microscopy depth profiling (optical sectioning) and the influence of pinhole filtering on it, we investigate the confocal volume in detail based on Gaussian beam optics and scalar wave optics. Theoretical depth profiles of a homogeneous transparent sample for four different pinhole sizes, which are computed using the measured incident beam waist radius w{sub 0} and only a few optical system specific parameters such as a numerical aperture (NA) and a focal length, show a good agreement with the corresponding measured depth profiles. The computed confocal volume demonstrates that the pinhole size affects the actual probe depth as well as the axial resolution and the total intensity loss.

  17. Aerosol Optical Depth Value-Added Product Report

    SciTech Connect (OSTI)

    Koontz, A; Hodges, G; Barnard, J; Flynn, C; Michalsky, J

    2013-03-17

    This document describes the process applied to retrieve aerosol optical depth (AOD) from multifilter rotating shadowband radiometers (MFRSR) and normal incidence multifilter radiometers (NIMFR) operated at the ARM Climate Research Facility’s ground-based facilities.

  18. Depth-resolved confocal micro-Raman spectroscopy for characterizing GaN-based light emitting diode structures

    SciTech Connect (OSTI)

    Chen, Wei-Liang; Lee, Yu-Yang; Chang, Yu-Ming, E-mail: ymchang@ntu.edu.tw [Center for Condensed Matter Sciences, National Taiwan University, 10617 Taipei, Taiwan (China)] [Center for Condensed Matter Sciences, National Taiwan University, 10617 Taipei, Taiwan (China); Chang, Chiao-Yun; Huang, Huei-Min; Lu, Tien-Chang [Department of Photonics, National Chiao Tung University, 30010 Hsinchu, Taiwan (China)] [Department of Photonics, National Chiao Tung University, 30010 Hsinchu, Taiwan (China)

    2013-11-15

    In this work, we demonstrate that depth-resolved confocal micro-Raman spectroscopy can be used to characterize the active layer of GaN-based LEDs. By taking the depth compression effect due to refraction index mismatch into account, the axial profiles of Raman peak intensities from the GaN capping layer toward the sapphire substrate can correctly match the LED structural dimension and allow the identification of unique Raman feature originated from the 0.3 ?m thick active layer of the studied LED. The strain variation in different sample depths can also be quantified by measuring the Raman shift of GaN A{sub 1}(LO) and E{sub 2}(high) phonon peaks. The capability of identifying the phonon structure of buried LED active layer and depth-resolving the strain distribution of LED structure makes this technique a potential optical and remote tool for in operando investigation of the electronic and structural properties of nitride-based LEDs.

  19. Apparatus and method for measuring the thickness of a coating

    DOE Patents [OSTI]

    Carlson, Nancy M.; Johnson, John A.; Tow, David M.; Walter, John B

    2002-01-01

    An apparatus and method for measuring the thickness of a coating adhered to a substrate. An electromagnetic acoustic transducer is used to induce surface waves into the coating. The surface waves have a selected frequency and a fixed wavelength. Interpolation is used to determine the frequency of surface waves that propagate through the coating with the least attenuation. The phase velocity of the surface waves having this frequency is then calculated. The phase velocity is compared to known phase velocity/thickness tables to determine the thickness of the coating.

  20. Control for monitoring thickness of high temperature refractory

    DOE Patents [OSTI]

    Caines, M.J.

    1982-11-23

    This invention teaches an improved monitoring device for detecting the changes in thickness of high-temperature refractory, the device consists of a probe having at least two electrically conductive generally parallel elements separated by a dielectric material. The probe is implanted or embedded directly in the refractory and is elongated to extend in line with the refractory thickness to be measured. Electrical inputs to the conductive elements provide that either or both the electrical conductance or capacitance can be found, so that charges over lapsed time periods can be compared in order to detect changes in the thickness of the refractory.

  1. Simultaneous orientation and thickness mapping in transmission electron microscopy

    SciTech Connect (OSTI)

    Tyutyunnikov, Dmitry; zdl, V. Burak; Koch, Christoph T.

    2014-12-04

    In this paper we introduce an approach for simultaneous thickness and orientation mapping of crystalline samples by means of transmission electron microscopy. We show that local thickness and orientation values can be extracted from experimental dark-field (DF) image data acquired at different specimen tilts. The method has been implemented to automatically acquire the necessary data and then map thickness and crystal orientation for a given region of interest. We have applied this technique to a specimen prepared from a commercial semiconductor device, containing multiple 22 nm technology transistor structures. The performance and limitations of our method are discussed and compared to those of other techniques available.

  2. Measuring depth profiles of residual stress with Raman spectroscopy

    SciTech Connect (OSTI)

    Enloe, W.S.; Sparks, R.G.; Paesler, M.A.

    1988-12-01

    Knowledge of the variation of residual stress is a very important factor in understanding the properties of machined surfaces. The nature of the residual stress can determine a part`s susceptibility to wear deformation, and cracking. Raman spectroscopy is known to be a very useful technique for measuring residual stress in many materials. These measurements are routinely made with a lateral resolution of 1{mu}m and an accuracy of 0.1 kbar. The variation of stress with depth; however, has not received much attention in the past. A novel technique has been developed that allows quantitative measurement of the variation of the residual stress with depth with an accuracy of 10nm in the z direction. Qualitative techniques for determining whether the stress is varying with depth are presented. It is also demonstrated that when the stress is changing over the volume sampled, errors can be introduced if the variation of the stress with depth is ignored. Computer aided data analysis is used to determine the depth dependence of the residual stress.

  3. Thermal spray and cold spray analysis of density, porosity, and tensile Specimens for use with LIGA applications

    SciTech Connect (OSTI)

    DECKER,MERLIN K.; SMITH,MARK F.

    2000-02-01

    This analysis provides a preliminary investigation into using Twin-Wire Arc Thermal Spray and Cold Spray as material deposition processes for LIGA applications. These spray material processes were studied to make an initial determination of their potential as alternatives to producing mechanical parts via the electroplating process. Three materials, UltraMachinable{reg_sign} Stainless Steel, BondArc{reg_sign}, and aluminum, were sprayed using Thermal Spray. Only aluminum was sprayed using the Cold Spray process. Following the spray procedure, the test specimens were released from a copper mold and then tested. Three tests, density, tensile strength, and porosity, were performed on the specimens to determine the spray effect on material properties. Twin-Wire Arc Thermal Spray did not demonstrate adequate deposition properties and does not appear to be a good process candidate for LIGA. However, Cold Spray yielded better density results and warrants further investigation to analyze the minimum feature size produced by the process.

  4. Using presence of calcite cap rock in shales to predict occurrence of reservoirs composed of leached secondary porosity in the geopressured zone. Annual report, June 1, 1980-October 31, 1980

    SciTech Connect (OSTI)

    Kaiser, W.R.; Magara, K.; Milliken, K.L.; Richmann, D.L.

    1981-01-01

    The distribution of high-resistivity shale in the Frio Formation between hydropressured and geopressured strata has been mapped along the Texas Gulf Coast. Two high-resistivity intervals more than 1000 ft thick have been mapped, one in Brazoria and Galveston Counties and the other in Kenedy County. They coincide with Frio delta systems and may be related to extraordinary quantities of CO/sub 2/ produced by deltaic sediments rich in woody and herbaceous matter. Beyond being calcareous, the nature of the high-resistivity interval is enigmatic and its relationship to deep secondary porosity problematic. Most of the contained carbonate is microscopically and isotopically skeletal in origin, revealing no evidence of diagenetic modification. Minor rhombs of iron-bearing carbonate tens of microns in size were identified. Detrital feldspar compositions are being established to test subsequent changes in feldspar composition resulting from progressive burial and albitization. Hydrolysis reactions for authigenic minerals and reactions between key pairs of minerals have been written. Thermodynamic functions for complex phyllosilicates at temperatures up to 200/sup 0/C have been calculated. From thermodynamic calculations it was predicted that ferroan calcite would be the favored authigenic carbonate in shales.

  5. Coating thickness and coverage effects on the forces between silica

    Office of Scientific and Technical Information (OSTI)

    nanoparticles in water. (Journal Article) | SciTech Connect Coating thickness and coverage effects on the forces between silica nanoparticles in water. Citation Details In-Document Search Title: Coating thickness and coverage effects on the forces between silica nanoparticles in water. Abstract not provided. Authors: Salerno, Kenneth Michael ; Lane, J. Matthew ; Grest, Gary S. ; Ismail, Ahmed E. Publication Date: 2014-01-01 OSTI Identifier: 1140719 Report Number(s): SAND2014-0781J Journal

  6. Microfluidic devices with thick-film electrochemical detection

    DOE Patents [OSTI]

    Wang, Joseph; Tian, Baomin; Sahlin, Eskil

    2005-04-12

    An apparatus for conducting a microfluidic process and analysis, including at least one elongated microfluidic channel, fluidic transport means for transport of fluids through the microfluidic channel, and at least one thick-film electrode in fluidic connection with the outlet end of the microfluidic channel. The present invention includes an integrated on-chip combination reaction, separation and thick-film electrochemical detection microsystem, for use in detection of a wide range of analytes, and methods for the use thereof.

  7. Extended, Continuous Pt Nanostructures in Thick, Dispersed Electrodes |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Extended, Continuous Pt Nanostructures in Thick, Dispersed Electrodes Extended, Continuous Pt Nanostructures in Thick, Dispersed Electrodes Presented at the Department of Energy Fuel Cell Projects Kickoff Meeting, September 1 - October 1, 2009 PDF icon pivovar_nrel_kickoff.pdf More Documents & Publications DOE's Fuel Cell Catalyst R&D Activities Fuel Cell Projects Kickoff Meeting PEMFC R&D at the DOE Fuel Cell Technologies Program

  8. OPTICALLY THICK H I DOMINANT IN THE LOCAL INTERSTELLAR MEDIUM: AN ALTERNATIVE INTERPRETATION TO ''DARK GAS''

    SciTech Connect (OSTI)

    Fukui, Y.; Torii, K.; Yamamoto, H.; Okamoto, R.; Hayakawa, T.; Tachihara, K.; Sano, H.; Onishi, T.

    2015-01-01

    Dark gas in the interstellar medium (ISM) is believed to not be detectable either in CO or H I radio emission, but it is detectable by other means including γ rays, dust emission, and extinction traced outside the Galactic plane at |b| > 5°. In these analyses, the 21 cm H I emission is usually assumed to be completely optically thin. We have reanalyzed the H I emission from the whole sky at |b| > 15° by considering temperature stratification in the ISM inferred from the Planck/IRAS analysis of the dust properties. The results indicate that the H I emission is saturated with an optical depth ranging from 0.5 to 3 for 85% of the local H I gas. This optically thick H I is characterized by spin temperature in the range 10 K-60 K, significantly lower than previously postulated in the literature, whereas such low temperature is consistent with emission/absorption measurements of the cool H I toward radio continuum sources. The distribution and the column density of the H I are consistent with those of the dark gas suggested by γ rays, and it is possible that the dark gas in the Galaxy is dominated by optically thick cold H I gas. This result implies that the average density of H I is 2-2.5 times higher than that derived on the optically thin assumption in the local ISM.

  9. Gulf of Mexico Proved Reserves By Water Depth, 2009

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Mexico Proved Reserves and Production by Water Depth, 2009 1 Gulf of Mexico Proved Reserves and Production by Water Depth The Gulf of Mexico Federal Offshore region (GOM Fed) has long been one of the Nation's principal sources of proved reserves. At the end of 2009, the GOM Fed accounted for close to one-fifth of oil proved reserves (second only to Texas) and just over four percent of natural gas proved reserves (the country's seventh largest reporting region). 1 Natural gas proved reserves

  10. Method and system for producing sputtered thin films with sub-angstrom thickness uniformity or custom thickness gradients

    DOE Patents [OSTI]

    Folta, James A. (2262 Hampton Rd., Livermore, CA 94550); Montcalm, Claude (14 Jami St., Livermore, CA 94550); Walton, Christopher (2927 Lorina St., #2, Berkeley, CA 94705-1852)

    2003-01-01

    A method and system for producing a thin film with highly uniform (or highly accurate custom graded) thickness on a flat or graded substrate (such as concave or convex optics), by sweeping the substrate across a vapor deposition source with controlled (and generally, time-varying) velocity. In preferred embodiments, the method includes the steps of measuring the source flux distribution (using a test piece that is held stationary while exposed to the source), calculating a set of predicted film thickness profiles, each film thickness profile assuming the measured flux distribution and a different one of a set of sweep velocity modulation recipes, and determining from the predicted film thickness profiles a sweep velocity modulation recipe which is adequate to achieve a predetermined thickness profile. Aspects of the invention include a practical method of accurately measuring source flux distribution, and a computer-implemented method employing a graphical user interface to facilitate convenient selection of an optimal or nearly optimal sweep velocity modulation recipe to achieve a desired thickness profile on a substrate. Preferably, the computer implements an algorithm in which many sweep velocity function parameters (for example, the speed at which each substrate spins about its center as it sweeps across the source) can be varied or set to zero.

  11. Continuous Snow Depth, Intensive Site 1, Barrow, Alaska

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Bob Busey; Larry Hinzman; Vladimir Romanovsky; William Cable

    Continuous Snow depth data are being collected at several points within four intensive study areas in Barrow, Alaska. These data are being collected to better understand the energy dynamics above the active layer and permafrost. They complement in-situ snow and soil measurements at this location. The data could also be used as supporting measurements for other research and modeling activities.

  12. Continuous Snow Depth, Intensive Site 1, Barrow, Alaska

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Bob Busey; Larry Hinzman; Vladimir Romanovsky; William Cable

    2014-11-06

    Continuous Snow depth data are being collected at several points within four intensive study areas in Barrow, Alaska. These data are being collected to better understand the energy dynamics above the active layer and permafrost. They complement in-situ snow and soil measurements at this location. The data could also be used as supporting measurements for other research and modeling activities.

  13. Advanced Technology Vehicle Lab Benchmarking - Level 2 (in-depth) |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy 1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon vss031_rask_2011_o.pdf More Documents & Publications Advanced Technology Vehicle Lab Benchmarking - Level 2 (in-depth) Data Collection for Improved Cold Temperature Thermal Modeling Advanced Technology Vehicle Benchmark and Assessment

  14. Wide-angle imaging LIDAR (WAIL): a ground-based instrument for monitoring the thickness and density of optically thick clouds.

    SciTech Connect (OSTI)

    Love, Steven P.; Davis, A. B.; Rohde, C. A.; Ho, Cheng,

    2001-01-01

    Traditional lidar provides little information on dense clouds beyond the range to their base (ceilometry), due to their extreme opacity. At most optical wavelengths, however, laser photons are not absorbed but merely scattered out of the beam, and thus eventually escape the cloud via multiple scattering, producing distinctive extended space- and time-dependent patterns which are, in essence, the cloud's radiative Green functions. These Green functions, essentially 'movies' of the time evolution of the spatial distribution of escaping light, are the primary data products of a new type of lidar: Wide Angle Imaging Lidar (WAIL). WAIL data can be used to infer both optical depth and physical thickness of clouds, and hence the cloud liquid water content. The instrumental challenge is to accommodate a radiance field varying over many orders of magnitude and changing over widely varying time-scales. Our implementation uses a high-speed microchannel plate/crossed delay line imaging detector system with a 60-degree full-angle field of view, and a 532 nm doubled Nd:YAG laser. Nighttime field experiments testing various solutions to this problem show excellent agreement with diffusion theory, and retrievals yield plausible values for the optical and geometrical parameters of the observed cloud decks.

  15. Determination of filter-cake thicknesses from on-line flow measurements and gas/particle transport modeling

    SciTech Connect (OSTI)

    Smith, D.H.; Powell, V.; Ibrahim, E.; Ferer, M.; Ahmadi, G.

    1996-12-31

    The use of cylindrical candle filters to remove fine ({approx}0.005 mm) particles from hot ({approx}500- 900{degrees}C) gas streams currently is being developed for applications in advanced pressurized fluidized bed combustion (PFBC) and integrated gasification combined cycle (IGCC) technologies. Successfully deployed with hot-gas filtration, PFBC and IGCC technologies will allow the conversion of coal to electrical energy by direct passage of the filtered gases into non-ruggedized turbines and thus provide substantially greater conversion efficiencies with reduced environmental impacts. In the usual approach, one or more clusters of candle filters are suspended from a tubesheet in a pressurized (P {approx_lt}1 MPa) vessel into which hot gases and suspended particles enter, the gases pass through the walls of the cylindrical filters, and the filtered particles form a cake on the outside of each filter. The cake is then removed periodically by a backpulse of compressed air from inside the filter, which passes through the filter wall and filter cake. In various development or demonstration systems the thickness of the filter cake has proved to be an important, but unknown, process parameter. This paper describes a physical model for cake and pressure buildups between cleaning backpulses, and for longer term buildups of the ``baseline`` pressure drop, as caused by incomplete filter cleaning and/or re-entrainment. When combined with operating data and laboratory measurements of the cake porosity, the model may be used to calculate the (average) filter permeability, the filter-cake thickness and permeability, and the fraction of filter-cake left on the filter by the cleaning backpulse or re-entrained after the backpulse. When used for a variety of operating conditions (e.g., different coals, sorbents, temperatures, etc.), the model eventually may provide useful information on how the filter-cake properties depend on the various operating parameters.

  16. Simultaneous orientation and thickness mapping in transmission electron microscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tyutyunnikov, Dmitry; Özdöl, V. Burak; Koch, Christoph T.

    2014-12-04

    In this paper we introduce an approach for simultaneous thickness and orientation mapping of crystalline samples by means of transmission electron microscopy. We show that local thickness and orientation values can be extracted from experimental dark-field (DF) image data acquired at different specimen tilts. The method has been implemented to automatically acquire the necessary data and then map thickness and crystal orientation for a given region of interest. We have applied this technique to a specimen prepared from a commercial semiconductor device, containing multiple 22 nm technology transistor structures. The performance and limitations of our method are discussed and comparedmore » to those of other techniques available.« less

  17. Process for manufacture of thick film hydrogen sensors

    DOE Patents [OSTI]

    Perdieu, Louisa H. (Overland Park, KS)

    2000-09-09

    A thick film process for producing hydrogen sensors capable of sensing down to a one percent concentration of hydrogen in carrier gasses such as argon, nitrogen, and air. The sensor is also suitable to detect hydrogen gas while immersed in transformer oil. The sensor includes a palladium resistance network thick film printed on a substrate, a portion of which network is coated with a protective hydrogen barrier. The process utilizes a sequence of printing of the requisite materials on a non-conductive substrate with firing temperatures at each step which are less than or equal to the temperature at the previous step.

  18. Pump-Intensity- and Shell-Thickness-Dependent Evolution of

    Office of Scientific and Technical Information (OSTI)

    Photoluminescence Blinking in Individual Core/Shell CdSe/CdS Nanocrystals (Journal Article) | SciTech Connect Journal Article: Pump-Intensity- and Shell-Thickness-Dependent Evolution of Photoluminescence Blinking in Individual Core/Shell CdSe/CdS Nanocrystals Citation Details In-Document Search Title: Pump-Intensity- and Shell-Thickness-Dependent Evolution of Photoluminescence Blinking in Individual Core/Shell CdSe/CdS Nanocrystals Authors: Malko, Anton V. ; Park, Young-Shin ; Sampat,

  19. Quantum rings of non-uniform thickness in magnetic field

    SciTech Connect (OSTI)

    Rodrguez-Prada, F. A.; Garca, L. F.; Mikhailov, I. D.

    2014-05-15

    We consider a model of crater-shaped quantum dot in form of a thin layer whose thickness linearly increases with the distance from the axis. We show that one-particle wave equation for the electron confined in such structure can be completely separated in the adiabatic limit when the quantum dot thickness is much smaller than its lateral dimension. Analytical solutions found for this model has been used as base functions for analysing the effect of non-homogeneity on the electronic spectrum in the framework of the exact diagonalization method.

  20. Method and apparatus for thickness measurement using microwaves

    DOE Patents [OSTI]

    Woskov, Paul (Bedford, MA) [Bedford, MA; Lamar, David A. (West Richland, WA) [West Richland, WA

    2001-01-01

    The method for measuring the thickness of a material which transmits a detectable amount of microwave radiation includes irradiating the material with coherent microwave radiation tuned over a frequency range. Reflected microwave radiation is detected, the reflected radiation having maxima and minima over the frequency range as a result of coherent interference of microwaves reflected from reflecting surfaces of the material. The thickness of the material is determined from the period of the maxima and minima along with knowledge of the index of refraction of the material.

  1. RFID tag modification for full depth backscatter modulation

    DOE Patents [OSTI]

    Scott, Jeffrey Wayne [Pasco, WA; Pratt, Richard M [Richland, WA

    2010-07-20

    A modulated backscatter radio frequency identification device includes a diode detector configured to selectively modulate a reply signal onto an incoming continuous wave; communications circuitry configured to provide a modulation control signal to the diode detector, the diode detector being configured to modulate the reply signal in response to be modulation control signal; and circuitry configured to increase impedance change at the diode detector which would otherwise not occur because the diode detector rectifies the incoming continuous wave while modulating the reply signal, whereby reducing the rectified signal increases modulation depth by removing the reverse bias effects on impedance changes. Methods of improving depth of modulation in a modulated backscatter radio frequency identification device are also provided.

  2. The efficacy of post porosity plasma protection against vacuum-ultraviolet damage in porous low-k materials

    SciTech Connect (OSTI)

    Lionti, K.; Volksen, W.; Darnon, M.; Magbitang, T.; Dubois, G.

    2015-03-21

    As of today, plasma damage remains as one of the main challenges to the reliable integration of porous low-k materials into microelectronic devices at the most aggressive node. One promising strategy to limit damage of porous low-k materials during plasma processing is an approach we refer to as post porosity plasma protection (P4). In this approach, the pores of the low-k material are filled with a sacrificial agent prior to any plasma treatment, greatly minimizing the total damage by limiting the physical interactions between plasma species and the low-k material. Interestingly, the contribution of the individual plasma species to the total plasma damage is not fully understood. In this study, we investigated the specific damaging effect of vacuum-ultraviolet (v-UV) photons on a highly porous, k = 2.0 low-k material and we assessed the P4 protective effect against them. It was found that the impact of the v-UV radiation varied depending upon the v-UV emission lines of the plasma. More importantly, we successfully demonstrated that the P4 process provides excellent protection against v-UV damage.

  3. Method for depositing a uniform layer of particulate material on the surface of an article having interconnected porosity

    DOE Patents [OSTI]

    Wrenn, Jr., George E. (Clinton, TN); Lewis, Jr., John (Oak Ridge, TN)

    1984-01-01

    The invention is a method for depositing liquid-suspended particles on an immersed porous article characterized by interconnected porosity. In one form of the invention, coating is conducted in a vessel containing an organic liquid supporting a colloidal dispersion of graphite sized to lodge in surface pores of the article. The liquid comprises a first volatile component (e.g., acetone) and a second less-volatile component (e.g., toluene) containing a dissolved organic graphite-bonding agent. The liquid also contains an organic agent (e.g., cellulose gum) for maintaining the particles in suspension. A porous carbon article to be coated is immersed in the liquid so that it is permeated therewith. While the liquid is stirred to maintain a uniform blend, the vessel headspace is evacuated to effect flashing-off of the first component from the interior of the article. This causes particle-laden liquid exterior of the article to flow inwardly through its surface pores, lodging particles in these pores and forming a continuous graphite coating. The coated article is retrieved and heated to resin-bond the graphite. The method can be used to form a smooth, adherent, continuous coating of various materials on various porous articles. The method is rapid and reproducible.

  4. Method for depositing a uniform layer of particulate material on the surface of an article having interconnected porosity

    DOE Patents [OSTI]

    Wrenn, G.E. Jr.; Lewis, J. Jr.

    1982-09-29

    The invention is a method for depositing liquid-suspended particles on an immersed porous article characterized by interconnected porosity. In one form of the invention, coating is conducted in a vessel containing an organic liquid supporting a colloidal dispersion of graphite sized to lodge in surface pores of the article. The liquid comprises a first volatile component (e.g., acetone) and a second less-volatile component (e.g., toluene) containing a dissolved organic graphite-bonding agent. The liquid also contains an organic agent (e.g., cellulose gum) for maintaining the particles in suspension. A porous carbon article to be coated is immersed in the liquid so that it is permeated therewith. While the liquid is stirred to maintain a uniform blend, the vessel headspace is evacuated to effect flashing-off of the first component from the interior of the article. This causes particle-laden liquid exterior of the article to flow inwardly through its surface pores, lodging particles in these pores and forming a continuous graphite coating. The coated article is retrieved and heated to resin-bond the graphite. The method can be used to form a smooth, adherent, continuous coating of various materials on various porous articles. The method is rapid and reproducible.

  5. Sensing roller for in-process thickness measurement

    DOE Patents [OSTI]

    Novak, J.L.

    1996-07-16

    An apparatus and method are disclosed for processing materials by sensing roller, in which the sensing roller has a plurality of conductive rings (electrodes) separated by rings of dielectric material. Sensing capacitances or impedances between the electrodes provides information on thicknesses of the materials being processed, location of wires therein, and other like characteristics of the materials. 6 figs.

  6. Method and apparatus for conducting variable thickness vapor deposition

    DOE Patents [OSTI]

    Nesslage, G.V.

    1984-08-03

    A method of vapor depositing metal on a substrate in variable thickness comprises conducting the deposition continuously without interruption to avoid formation of grain boundaries. To achieve reduced deposition in specific regions a thin wire or ribbon blocking body is placed between source and substrate to partially block vapors from depositing in the region immediately below.

  7. Determination of the effective sample thickness via radiative capture

    SciTech Connect (OSTI)

    Hurst, A. M.; Summers, N. C.; Szentmiklosi, L.; Firestone, R. B.; Basunia, M. S.; Escher, J. E.; Sleaford, B. W.

    2015-09-14

    Our procedure for determining the effective thickness of non-uniform irregular-shaped samples via radiative capture is described. In this technique, partial ?-ray production cross sections of a compound nucleus produced in a neutron-capture reaction are measured using Prompt Gamma Activation Analysis and compared to their corresponding standardized absolute values. For the low-energy transitions, the measured cross sections are lower than their standard values due to significant photoelectric absorption of the ? rays within the bulk-sample volume itself. Using standard theoretical techniques, the amount of ?-ray self absorption and neutron self shielding can then be calculated by iteratively varying the sample thickness until the observed cross sections converge with the known standards. The overall attenuation provides a measure of the effective sample thickness illuminated by the neutron beam. This procedure is illustrated through radiative neutron capture using powdered oxide samples comprising enriched 186W and 182W from which their tungsten-equivalent effective thicknesses are deduced to be 0.077(3) mm and 0.042(8) mm, respectively.

  8. Influence of compensator thickness, field size, and off-axis distance on the effective attenuation coefficient of a cerrobend compensator for intensity-modulated radiation therapy

    SciTech Connect (OSTI)

    Haghparast, Abbas; Hashemi, Bijan; Eivazi, Mohammad Taghi

    2013-04-01

    Intensity-modulated radiation therapy (IMRT) can be performed by using compensators. To make a compensator for an IMRT practice, it is required to calculate the effective attenuation coefficient (?{sub eff}) of its material, which is affected by various factors. We studied the effect of the variation of the most important factors on the calculation of the ?{sub eff} of the cerrobend compensator for 6-MV photon beams, including the field size, compensator thickness, and off-axis distance. Experimental measurements were carried out at 100 cm source-to-surface distance and 10 cm depth for the 6-MV photon beams of an Elekta linac using various field size, compensator thickness, and off-axis settings. The field sizes investigated ranged from 4 4 to 25 25 cm{sup 2} and the cerrobend compensator thicknesses from 0.56 cm. For a fixed compensator thickness, variation of the ?{sub eff} with the field size ranged from 3.76.8%, with the highest value attributed to the largest compensator thickness. At the reference field size of 10 10 cm{sup 2}, the ?{sub eff} varied by 16.5% when the compensator thickness was increased from 0.56 cm. However, the variation of the ?{sub eff} with the off-axis distance was only 0.99% at this field size, whereas for the largest field size, it was more significant. Our results indicated that the compensator thickness and field size have the most significant effect on the calculation of the compensator ?{sub eff} for the 6-MV photon beam. Therefore, it is recommended to consider these parameters when calculating the compensator thickness for an IMRT practice designed for these beams. The off-axis distance had a significant effect on the calculation of the ?{sub eff} only for the largest field size. Hence, it is recommended to consider the effect of this parameter only for field sizes larger than 25 25 cm{sup 2}.

  9. Appendix PORSURF: Porosity Surface

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    BRAGFLO constrained to fall on this surface. Various techniques described in Freeze, Larson, and Davies (Freeze, Larson, and Davies 1995) were used to check the validity of this...

  10. Improved Spatial Resolution in Thick, Fully-Depleted CCDs withEnhanced...

    Office of Scientific and Technical Information (OSTI)

    Improved Spatial Resolution in Thick, Fully-Depleted CCDs withEnhanced Red Sensitivity Citation Details In-Document Search Title: Improved Spatial Resolution in Thick,...

  11. Method for making thick and/or thin film

    DOE Patents [OSTI]

    Pham, Ai Quoc; Glass, Robert S.

    2004-11-02

    A method to make thick or thin films a very low cost. The method is generally similar to the conventional tape casting techniques while being more flexible and versatile. The invention involves preparing a slip (solution) of desired material and including solvents such as ethanol and an appropriate dispersant to prevent agglomeration. The slip is then sprayed on a substrate to be coated using an atomizer which spreads the slip in a fine mist. Upon hitting the substrate, the solvent evaporates, leaving a green tape containing the powder and other additives, whereafter the tape may be punctured, cut, and heated for the desired application. The tape thickness can vary from about 1 .mu.m upward.

  12. Thick, low-stress films, and coated substrates formed therefrom

    DOE Patents [OSTI]

    Henager, Jr., Charles H. (Kennewick, WA); Knoll, Robert W. (Menomonee Falls, WI)

    1991-01-01

    Stress-induced deformation, and the damage resulting therefrom, increases with film thickness. The overcoming of excessive stress by the use of the film material of the present invention, permits the formation of thick films that are necessary for certain of the above described applications. The most likely use for the subject film materials, other than their specialized views as an optical film, is for microelectronic packaging of components on silicon substrates. In general, the subject Si-Al-O-N films have excellent adherence to the underlying substrate, a high degree of hardness and durability, and are excellent insulators. Prior art elevated temperature deposition processes cannot meet the microelectronic packaging temperature formation constraints. The process of the present invention is conducted under non-elevated temperature conditions, typically 500# C. or less.

  13. Turbine blade having a constant thickness airfoil skin

    DOE Patents [OSTI]

    Marra, John J

    2012-10-23

    A turbine blade is provided for a gas turbine comprising: a support structure comprising a base defining a root of the blade and a framework extending radially outwardly from the base, and an outer skin coupled to the support structure framework. The skin has a generally constant thickness along substantially the entire radial extent thereof. The framework and the skin define an airfoil of the blade.

  14. Effect of Aerosol Humidification on the Column Aerosol Optical Thickness

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    over the ARM Southern Great Plains Site Effect of Aerosol Humidification on the Column Aerosol Optical Thickness over the ARM Southern Great Plains Site Li, Zhanqing University of Maryland Jeong, Myeong-Jae University of Maryland Category: Aerosols This study investigates the aerosol humidification effect (AHE) using seventy profiles of the aerosol scattering and absorption coefficients at high (~85%) and low (~40%) relative humidity (RH) levels obtained over the Southern Great Plains (SGP)

  15. Identification Of Rippability And Bedrock Depth Using Seismic Refraction

    SciTech Connect (OSTI)

    Ismail, Nur Azwin; Saad, Rosli; Nawawi, M. N. M; Muztaza, Nordiana Mohd; El Hidayah Ismail, Noer; Mohamad, Edy Tonizam

    2010-12-23

    Spatial variability of the bedrock with reference to the ground surface is vital for many applications in geotechnical engineering to decide the type of foundation of a structure. A study was done within the development area of Mutiara Damansara utilising the seismic refraction method using ABEM MK8 24 channel seismograph. The geological features of the subsurface were investigated and velocities, depth to the underlying layers were determined. The seismic velocities were correlated with rippability characteristics and borehole records. Seismic sections generally show a three layer case. The first layer with velocity 400-600 m/s predominantly consists of soil mix with gravel. The second layer with velocity 1600-2000 m/s is suggested to be saturated and weathered area. Both layers forms an overburden and generally rippable. The third layer represents granite bedrock with average depth and velocity 10-30 m and >3000 m/s respectively and it is non-rippable. Steep slope on the bedrock are probably the results of shear zones.

  16. Determination of the effective sample thickness via radiative capture

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hurst, A. M.; Summers, N. C.; Szentmiklosi, L.; Firestone, R. B.; Basunia, M. S.; Escher, J. E.; Sleaford, B. W.

    2015-09-14

    Our procedure for determining the effective thickness of non-uniform irregular-shaped samples via radiative capture is described. In this technique, partial γ-ray production cross sections of a compound nucleus produced in a neutron-capture reaction are measured using Prompt Gamma Activation Analysis and compared to their corresponding standardized absolute values. For the low-energy transitions, the measured cross sections are lower than their standard values due to significant photoelectric absorption of the γ rays within the bulk-sample volume itself. Using standard theoretical techniques, the amount of γ-ray self absorption and neutron self shielding can then be calculated by iteratively varying the sample thicknessmore » until the observed cross sections converge with the known standards. The overall attenuation provides a measure of the effective sample thickness illuminated by the neutron beam. This procedure is illustrated through radiative neutron capture using powdered oxide samples comprising enriched 186W and 182W from which their tungsten-equivalent effective thicknesses are deduced to be 0.077(3) mm and 0.042(8) mm, respectively.« less

  17. Campbell penetration depth in Fe-based superconductors

    SciTech Connect (OSTI)

    Prommapan, Plegchart

    2011-08-15

    A 'true' critical current density, j{sub c}, as opposite to commonly measured relaxed persistent (Bean) current, j{sub B}, was extracted from the Campbell penetration depth, {lambda}{sub c}(T,H) measured in single crystals of LiFeAs, and optimally electron-doped Ba(Fe{sub 0.954}Ni{sub 0.046}){sub 2}As{sub 2} (FeNi122). In LiFeAs, the effective pinning potential is nonparabolic, which follows from the magnetic field - dependent Labusch parameter {alpha}. At the equilibrium (upon field - cooling), {alpha}(H) is non-monotonic, but it is monotonic at a finite gradient of the vortex density. This behavior leads to a faster magnetic relaxation at the lower fields and provides a natural dynamic explanation for the fishtail (second peak) effect. We also find the evidence for strong pinning at the lower fields.The inferred field dependence of the pinning potential is consistent with the evolution from strong pinning, through collective pinning, and eventually to a disordered vortex lattice. The value of j{sub c}(2 K) {approx_equal} 1.22 x 10{sup 6} A/cm{sup 2} provide an upper estimate of the current carrying capability of LiFeAs. Overall, vortex behavior of almost isotropic, fully-gapped LiFeAs is very similar to highly anisotropic d-wave cuprate superconductors, the similarity that requires further studies in order to understand unconventional superconductivity in cuprates and pnictides. In addition to LiFeAs, we also report the magnetic penetration depth in BaFe{sub 2}As{sub 2} based superconductors including irradiation of FeNi122. In unirradiated FeNi122, the maximum critical current value is, j{sub c}(2K) {approx_equal} 3.3 x 10{sup 6} A/cm{sup 2}. The magnetic-dependent feature was observed near the transition temperature in FeTe{sub 0.53}Se{sub 0.47} and irradiated FeNi122. Because of this feature, further studies are required in order to properly calibrate the Campbell penetration depth. Finally, we detected the crossing between the magnetic penetration depth and London penetration depth in optimally hold-doped Ba{sub 0.6}K{sub 0.4}Fe{sub 2}As{sub 2} (BaK122) and isovalent doped BaFe{sub 2}(As{sub 0.7}P{sub 0.3}){sub 2} (BaP122). These phenomena probably coincide with anomalous Meissner effect reported in pnicitde superconductors [Prozorov et al. (2010b)] however more studies are needed in order to clarify this.

  18. Depth-dependent magnetism in epitaxial MnSb thin films: effects of surface passivation and cleaning

    SciTech Connect (OSTI)

    Aldous J. D.; Sanchez-Hanke C.; Burrows, C.W.; Maskery, I.; Brewer, M.S.; Hase, T.P.A.; Duffy, J.A.; Lees, M. Rs; Decoster, T.; Theis, W.; Quesada, A.; Schmid, A.K.; Bell, G.R.

    2012-03-15

    Depth-dependent magnetism in MnSb(0001) epitaxial films has been studied by combining experimental methods with different surface specificities: polarized neutron reflectivity, x-ray magnetic circular dichroism (XMCD), x-ray resonant magnetic scattering and spin-polarized low energy electron microscopy (SPLEEM). A native oxide {approx}4.5 nm thick covers air-exposed samples which increases the film's coercivity. HCl etching efficiently removes this oxide and in situ surface treatment of etched samples enables surface magnetic contrast to be observed in SPLEEM. A thin Sb capping layer prevents oxidation and preserves ferromagnetism throughout the MnSb film. The interpretation of Mn L{sub 3,2} edge XMCD data is discussed.

  19. Effects of the microstructure and porosity on properties of Ti-6Al-4V alloy fabricated by Electron Beam Melting (EBM)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Galarraga, Haize; Lados, Diana; Dehoff, Ryan R; Kirka, Michael M; Nandwana, Peeyush

    2016-01-01

    Electron Beam Melting (EBM) is a metal powder bed-based Additive Manufacturing (AM) technology that makes possible the fabrication of three dimensional near-net-shaped parts directly from computer models. EBM technology has been in continuously updating, obtaining optimized properties of the processed alloys. Ti-6Al-4V titanium alloy is the most widely used and studied alloy for this technology and is the focus of this work. Several research works have been completed to study the mechanisms of microstructure formation as well as its influence on mechanical properties. However, the relationship is not completely understood, and more systematic research work is necessary in order tomoreattain a better understanding of these features. In this work, samples fabricated at different locations, orientations, and distances from the build platform have been characterized, studying the relationship of these variables with the resulting material intrinsic characteristics and properties (surface topography, microstructure, porosity, micro-hardness and static mechanical properties). This study has revealed that porosity is the main factor controlling mechanical properties relative to the other studied variables. Therefore, in future process developments, decreasing of the porosity should be considered as the primary goal in order to improve mechanical properties.less

  20. Effects of the microstructure and porosity on properties of Ti-6Al-4V ELI alloy fabricated by electron beam melting (EBM)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Galarraga, Haize; Lados, Diana A.; Dehoff, Ryan R.; Kirka, Michael M.; Nandwana, Peeyush

    2016-02-11

    Electron Beam Melting (EBM) is a metal powder bed-based Additive Manufacturing (AM) technology that makes possible the fabrication of three dimensional near-net-shaped parts directly from computer models. EBM technology has been in continuously updating, obtaining optimized properties of the processed alloys. Ti-6Al-4V titanium alloy is the most widely used and studied alloy for this technology and is the focus of this work. Several research works have been completed to study the mechanisms of microstructure formation as well as its influence on mechanical properties. However, the relationship is not completely understood, and more systematic research work is necessary in order tomore » attain a better understanding of these features. In this work, samples fabricated at different locations, orientations, and distances from the build platform have been characterized, studying the relationship of these variables with the resulting material intrinsic characteristics and properties (surface topography, microstructure, porosity, micro-hardness and static mechanical properties). This study has revealed that porosity is the main factor controlling mechanical properties relative to the other studied variables. Therefore, in future process developments, decreasing of the porosity should be considered as the primary goal in order to improve mechanical properties.« less

  1. ARM: 10-minute Raman Lidar: aerosol extinction profiles and aerosol optical thickness, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Chitra Sivaraman; Connor Flynn

    1998-03-01

    10-minute Raman Lidar: aerosol extinction profiles and aerosol optical thickness, from first Ferrare algorithm

  2. ARM: 1-minute Raman Lidar: aerosol extinction profiles and aerosol optical thickness, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Chitra Sivaraman; Connor Flynn

    2004-10-01

    1-minute Raman Lidar: aerosol extinction profiles and aerosol optical thickness, from first Ferrare algorithm

  3. ARM: 10-minute Raman Lidar: aerosol extinction profiles and aerosol optical thickness, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Chitra Sivaraman; Connor Flynn

    10-minute Raman Lidar: aerosol extinction profiles and aerosol optical thickness, from first Ferrare algorithm

  4. ARM: 1-minute Raman Lidar: aerosol extinction profiles and aerosol optical thickness, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Chitra Sivaraman; Connor Flynn

    1-minute Raman Lidar: aerosol extinction profiles and aerosol optical thickness, from first Ferrare algorithm

  5. DYNAMIC DELAMINATION IN THROUGH-THICKNESS REINFORCED DCB SPECIMEN

    SciTech Connect (OSTI)

    N. SRIDHAR; ET AL

    2001-02-01

    Bridged crack models using beam theory formulation have proved to be effective in the modeling of quasistatic delamination crack growth in through thickness reinforced structures. In this paper, we model dynamic crack propagation in these structures with the beam theory formulation. Steady state crack propagation characteristics unique to the dynamic case are first identified. Dynamic crack propagation and the energetics of steady state dynamic crack growth for a Double Cantilever beam (DCB) configuration loaded with a flying wedge is examined next. We find that steady state crack growth is attainable for this loading configuration provided certain conditions are satisfied.

  6. Mass gap for gravity localized on Weyl thick branes

    SciTech Connect (OSTI)

    Barbosa-Cendejas, N.; Santos, M. A. Reyes; Herrera-Aguilar, A.; Schubert, C.

    2008-06-15

    We consider thick brane configurations in a pure geometric Weyl integrable 5D space-time, a non-Riemannian generalization of Kaluza-Klein (KK) theory involving a geometric scalar field. Thus, the 5D theory describes gravity coupled to a self-interacting scalar field which gives rise to the structure of the thick branes. We continue the study of the properties of a previously found family of solutions which is smooth at the position of the brane but involves naked singularities in the fifth dimension. Analyzing their graviton spectrum, we find that a particularly interesting situation arises for a special case in which the 4D graviton is separated from the KK gravitons by a mass gap. The corresponding effective Schroedinger equation has a modified Poeschl-Teller potential and can be solved exactly. Apart from the massless 4D graviton, it contains one massive KK bound state, and the continuum spectrum of delocalized KK modes. We also discuss the mass hierarchy problem, and explicitly compute the corrections to Newton's law in the thin brane limit.

  7. Oil shale ash-layer thickness and char combustion kinetics

    SciTech Connect (OSTI)

    Aldis, D.F.; Singleton, M.F.; Watkins, B.E.; Thorsness, C.B.; Cena, R.J.

    1992-04-15

    A Hot-Recycled-Solids (HRS) oil shale retort is being studied at Lawrence Livermore National Laboratory. In the HRS process, raw shale is heated by mixing it with burnt retorted shale. Retorted shale is oil shale which has been heated in an oxygen deficient atmosphere to pyrolyze organic carbon, as kerogen into oil, gas, and a nonvolatile carbon rich residue, char. In the HRS retort process, the char in the spent shale is subsequently exposed to an oxygen environment. Some of the char, starting on the outer surface of the shale particle, is burned, liberating heat. In the HRS retort, the endothermic pyrolysis step is supported by heat from the exothermic char combustion step. The rate of char combustion is controlled by three resistances; the resistance of oxygen mass transfer through the gas film surrounding the solid particle, resistance to mass transfer through a ash layer which forms on the outside of the solid particles as the char is oxidized and the resistance due to the intrinsic chemical reaction rate of char and oxygen. In order to estimate the rate of combustion of the char in a typical oil shale particle, each of these resistances must be accurately estimated. We begin by modeling the influence of ash layer thickness on the over all combustion rate of oil shale char. We then present our experimental measurements of the ash layer thickness of oil shale which has been processed in the HRS retort.

  8. Apparatus and methods for determining gas saturation and porosity of a formation penetrated by a gas filled or liquid filled borehole

    DOE Patents [OSTI]

    Wilson, Robert D. (477 W. Scenic Dr., Grand Junction, CO 81503)

    2001-03-27

    Methods and apparatus are disclosed for determining gas saturation, liquid saturation, porosity and density of earth formations penetrated by a well borehole. Determinations are made from measures of fast neutron and inelastic scatter gamma radiation induced by a pulsed, fast neutron source. The system preferably uses two detectors axially spaced from the neutron source. One detector is preferably a scintillation detector responsive to gamma radiation, and a second detector is preferably an organic scintillator responsive to both neutron and gamma radiation. The system can be operated in cased boreholes which are filled with either gas or liquid. Techniques for correcting all measurements for borehole conditions are disclosed.

  9. Fringe biasing: A variance reduction technique for optically thick meshes

    SciTech Connect (OSTI)

    Smedley-Stevenson, R. P.

    2013-07-01

    Fringe biasing is a stratified sampling scheme applicable to Monte Carlo thermal radiation transport codes. The thermal emission source in optically thick cells is partitioned into separate contributions from the cell interiors (where the likelihood of the particles escaping the cells is virtually zero) and the 'fringe' regions close to the cell boundaries. Thermal emission in the cell interiors can now be modelled with fewer particles, the remaining particles being concentrated in the fringes so that they are more likely to contribute to the energy exchange between cells. Unlike other techniques for improving the efficiency in optically thick regions (such as random walk and discrete diffusion treatments), fringe biasing has the benefit of simplicity, as the associated changes are restricted to the sourcing routines with the particle tracking routines being unaffected. This paper presents an analysis of the potential for variance reduction achieved from employing the fringe biasing technique. The aim of this analysis is to guide the implementation of this technique in Monte Carlo thermal radiation codes, specifically in order to aid the choice of the fringe width and the proportion of particles allocated to the fringe (which are interrelated) in multi-dimensional simulations, and to confirm that the significant levels of variance reduction achieved in simulations can be understood by studying the behaviour for simple test cases. The variance reduction properties are studied for a single cell in a slab geometry purely absorbing medium, investigating the accuracy of the scalar flux and current tallies on one of the interfaces with the surrounding medium. (authors)

  10. Thick-shell nanocrystal quantum dots (Patent) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Patent: Thick-shell nanocrystal quantum dots Citation Details In-Document Search Title: Thick-shell nanocrystal quantum dots You are accessing a document from the Department of...

  11. Compression of 1-mm-thick M9763 cellular silicone foam under...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: Compression of 1-mm-thick M9763 cellular silicone foam under lateral confinement Citation Details In-Document Search Title: Compression of 1-mm-thick M9763...

  12. Thickness-dependent coherent phonon frequency in ultrathin FeSe...

    Office of Scientific and Technical Information (OSTI)

    Thickness-dependent coherent phonon frequency in ultrathin FeSeSrTiO3 films Citation Details In-Document Search Title: Thickness-dependent coherent phonon frequency in ultrathin ...

  13. Method and system using power modulation and velocity modulation producing sputtered thin films with sub-angstrom thickness uniformity or custom thickness gradients

    DOE Patents [OSTI]

    Montcalm, Claude (Livermore, CA); Folta, James Allen (Livermore, CA); Walton, Christopher Charles (Berkeley, CA)

    2003-12-23

    A method and system for determining a source flux modulation recipe for achieving a selected thickness profile of a film to be deposited (e.g., with highly uniform or highly accurate custom graded thickness) over a flat or curved substrate (such as concave or convex optics) by exposing the substrate to a vapor deposition source operated with time-varying flux distribution as a function of time. Preferably, the source is operated with time-varying power applied thereto during each sweep of the substrate to achieve the time-varying flux distribution as a function of time. Preferably, the method includes the steps of measuring the source flux distribution (using a test piece held stationary while exposed to the source with the source operated at each of a number of different applied power levels), calculating a set of predicted film thickness profiles, each film thickness profile assuming the measured flux distribution and a different one of a set of source flux modulation recipes, and determining from the predicted film thickness profiles a source flux modulation recipe which is adequate to achieve a predetermined thickness profile. Aspects of the invention include a computer-implemented method employing a graphical user interface to facilitate convenient selection of an optimal or nearly optimal source flux modulation recipe to achieve a desired thickness profile on a substrate. The method enables precise modulation of the deposition flux to which a substrate is exposed to provide a desired coating thickness distribution.

  14. Assessment of Nuclear Fuels using Radiographic Thickness Measurement Method

    SciTech Connect (OSTI)

    Muhammad Abir; Fahima Islam; Hyoung Koo Lee; Daniel Wachs

    2014-11-01

    The Convert branch of the National Nuclear Security Administration (NNSA) Global Threat Reduction Initiative (GTRI) focuses on the development of high uranium density fuels for research and test reactors for nonproliferation. This fuel is aimed to convert low density high enriched uranium (HEU) based fuel to high density low enriched uranium (LEU) based fuel for high performance research reactors (HPRR). There are five U.S. reactors that fall under the HPRR category, including: the Massachusetts Institute of Technology Reactor (MITR), the National Bureau of Standards Reactor (NBSR), the Missouri University Research Reactor (UMRR), the Advanced Test Reactor (ATR), and the High Flux Isotope Reactor (HFIR). U-Mo alloy fuel phase in the form of either monolithic or dispersion foil type fuels, such as ATR Full-size In center flux trap Position (AFIP) and Reduced Enrichment for Research and Test Reactor (RERTR), are being designed for this purpose. The fabrication process1 of RERTR is susceptible to introducing a variety of fuel defects. A dependable quality control method is required during fabrication of RERTR miniplates to maintain the allowable design tolerances, therefore evaluating and analytically verifying the fabricated miniplates for maintaining quality standards as well as safety. The purpose of this work is to analyze the thickness of the fabricated RERTR-12 miniplates using non-destructive technique to meet the fuel plate specification for RERTR fuel to be used in the ATR.

  15. Thick-Restart Laczos Method for Symmetric Eigenvalue Problems

    Energy Science and Technology Software Center (OSTI)

    1999-01-01

    This software package implements the thick-restart Lanczos method. It can be used on either a single address space machine or distributed parallel machine. The user can choose to implement or use a matrix-vector multiplication routine in any form convenient. Most of the arithmetic computations in the software are done through calls to BLAS and LAPACK. The software is written in Fortran 90. Because Fortran 90 offers many utility functions such functions such as dynamic memorymore » management, timing functions, random number generator and so on, the program is easily portable to different machines without modifying the source code. It can also be easily accessed from other language such as C or C-+. Since the software is highly modularized, it is relatively easy to adopt it for different type of situations. For example if the eigenvalue problem may have some symmetry and only a portion of the physical domain is discretized, then the dot-product routine needs to be modified. In this software, this modification is limited to one subroutine. It also can be instructed to write checkpoint files so that it can be restarted at a later time.« less

  16. Rotary union for use with ultrasonic thickness measuring probe

    DOE Patents [OSTI]

    Nachbar, Henry D. (Schenectady, NY)

    1992-01-01

    A rotary union for rotatably supporting an ultrasonic probe operable to nondestructively measure the thickness of steam generator tubes to determine the amount of corrosion experienced by the tubes includes a stationary body having a bore therethrough and an outlet drain, and a fitting rotatably mounted within the upper end of the body. The fitting has a bore aligned with the bore of the body. An electrical cable positioned within a water supply tube in an annular arrangement passes through the bore of the body and the bore of the fitting. This annular arrangement, in turn, is positioned within a connector element which extends outwardly from the fitting bore and is connected to the ultrasonic probe. An elastomeric lower bushing seals the annular arrangement to the lower end of the rotary union body and an elastomeric upper bushing seals the connector element to the fitting to permit the connector element and the ultrasonic probe connected thereto to rotate with the fitting relative to the body. The lower and upper bushings permit water to be passed through the annular arrangement and into the ultrasonic probe and thereafter discharged between the annular arrangement and the connector element to the outlet drain of the rotary union body.

  17. Rotary union for use with ultrasonic thickness measuring probe

    DOE Patents [OSTI]

    Nachbar, H.D.

    1992-09-15

    A rotary union for rotatably supporting an ultrasonic probe operable to nondestructively measure the thickness of steam generator tubes to determine the amount of corrosion experienced by the tubes includes a stationary body having a bore therethrough and an outlet drain, and a fitting rotatably mounted within the upper end of the body. The fitting has a bore aligned with the bore of the body. An electrical cable positioned within a water supply tube in an annular arrangement passes through the bore of the body and the bore of the fitting. This annular arrangement, in turn, is positioned within a connector element which extends outwardly from the fitting bore and is connected to the ultrasonic probe. An elastomeric lower bushing seals the annular arrangement to the lower end of the rotary union body and an elastomeric upper bushing seals the connector element to the fitting to permit the connector element and the ultrasonic probe connected thereto to rotate with the fitting relative to the body. The lower and upper bushings permit water to be passed through the annular arrangement and into the ultrasonic probe and thereafter discharged between the annular arrangement and the connector element to the outlet drain of the rotary union body. 5 figs.

  18. Cladding Attachment Over Thick Exterior Insulating Sheathing (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2013-11-01

    The addition of insulation to the exterior of buildings is an effective means of increasing the thermal resistance of wood-framed walls and mass masonry wall assemblies. The location of the insulation on the exterior of the structure has many direct benefits, including better effective R-value from reduced thermal bridging, better condensation resistance, reduced thermal stress on the structure, as well as other commonly associated improvements such as increased airtightness and improved water management. For thick layers of exterior insulation (more than 1.5 in.), the use of wood furring strips attached through the insulation back to the structure has been used by many contractors and designers as a means to provide a convenient cladding attachment location. Although the approach has proven effective, there is significant resistance to its widespread implementation due to a lack of research and understanding of the mechanisms involved in the development of the vertical displacement resistance capacity. In addition, the long-term in-service performance of the system has been questioned due to potential creep effects of the assembly under the sustained dead load of the cladding and effects of varying environmental conditions. In addition, the current International Building Code (IBC) and International Residential Code (IRC) do not have a provision that specifically allows this assembly.

  19. Analysis of gamma-ray spectra from foils activated in a range-thick lead target by 800-MeV protons. Final technical report

    SciTech Connect (OSTI)

    Laird, C.E.; Mullins, D.H.

    1995-06-12

    Approximately 400 gamma-ray spectra have been analyzed to obtain the types and quantities of radioisotopes produced when 800-MeV protons interact with a range-thick lead target. These spectra were obtained from the radioactive decay of product isotopes in lead disks placed at various depths and radial positions within the target. These spectra were analyzed with the computer code HYPERMET and the photopeak areas were reduced to nuclei produced per incident proton per cubic centimeter of material. Product nuclei ranged from atomic mass 160 to mass 206 and over a range of half lives from a few minutes to several weeks. The results of this analysis have been outlined in this report and transmitted on computer disk to Los Alamos National Laboratory. The consistency of these analyses have been confirmed by a comparison of photopeak areas obtained at LANL with the computer code GAMANAL with those from HYPERMET for two gamma-ray spectra. Also, the nuclear production per proton per cm{sub 3} obtained from these two spectra analyzed both at LANL and at EKU have been found to agree to within the statistical accuracy of the peak-fitting programs. This analysis of these 400 gamma-ray spectra has determined the nuclear production per incident proton per cm{sub 3} at five regularly-spaced radial positions and depths up to 40 cm into a range-thick lead target.

  20. Los Alamos Drills to Record-breaking Depths | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Drills to Record-breaking Depths Los Alamos Drills to Record-breaking Depths November 26, 2014 - 12:00pm Addthis Workers reached a record-breaking depth of 1,100 feet with a sonic drill rig. Workers reached a record-breaking depth of 1,100 feet with a sonic drill rig. LOS ALAMOS, N.M. - The EM-supported Environmental Programs at Los Alamos National Laboratory is pushing the limits of drilling technology with the use of a sonic drill rig to drill coreholes more than 1,100 feet deep in support of

  1. Thick Concrete Specimen Construction, Testing, and Preliminary Analysis

    SciTech Connect (OSTI)

    Clayton, Dwight A.; Hoegh, Kyle; Khazanovich, Lev

    2015-03-01

    The purpose of the U.S. Department of Energy Office of Nuclear Energys Light Water Reactor Sustainability (LWRS) Program is to develop technologies and other solutions that can improve the reliability, sustain the safety, and extend the operating lifetimes of nuclear power plants (NPPs) beyond 60 years. Since many important safety structures in an NPP are constructed of concrete, inspection techniques must be developed and tested to evaluate the internal condition. In-service containment structures generally do not allow for the destructive measures necessary to validate the accuracy of these inspection techniques. This creates a need for comparative testing of the various nondestructive evaluation (NDE) measurement techniques on concrete specimens with known material properties, voids, internal microstructure flaws, and reinforcement locations. A preliminary report detailed some of the challenges associated with thick reinforced concrete sections and prioritized conceptual designs of specimens that could be fabricated to represent NPP concrete structures for using in NDE evaluation comparisons. This led to the construction of the concrete specimen presented in this report, which has sufficient reinforcement density and cross-sectional size to represent an NPP containment wall. Details on how a suitably thick concrete specimen was constructed are presented, including the construction materials, final nominal design schematic, as well as formwork and rigging required to safely meet the desired dimensions of the concrete structure. The report also details the type and methods of forming the concrete specimen as well as information on how the rebar and simulated defects were embedded. Details on how the resulting specimen was transported, safely anchored, and marked to allow access for systematic comparative NDE testing of defects in a representative NPP containment wall concrete specimen are also given. Data collection using the MIRA Ultrasonic NDE equipment and initial results are also presented along with a discussion of the preliminary findings. Comparative NDE of various defects in reinforced concrete specimens is a key component in identifying the most promising techniques and directing the research and development efforts needed to characterize concrete degradation in commercial NPPs. This requires access to the specimens for data collection using state-of-the-art technology. The construction of the specimen detailed in this report allows for an evaluation of how different NDE techniques may interact with the size and complexities of NPP concrete structures. These factors were taken into account when determining specimen size and features to ensure a realistic design. The lateral dimensions of the specimen were also chosen to mitigate unrealistic boundary effects that would not affect the results of field NPP concrete testing. Preliminary results show that, while the current methods are able to identify some of the deeper defects, improvements in data processing or hardware are necessary to be able to achieve the precision and reliability achieved in evaluating thinner and less heavily reinforced concrete structures.

  2. Thin-thick hydrogen target for nuclear physics

    SciTech Connect (OSTI)

    Gheller, J.-M.; Juster, F.-P.; Authelet, G.; Relland, J.

    2014-01-29

    In spectroscopic studies of unstable nuclei, hydrogen targets are of key importance. The CHyMENE Project aims to provide to the nuclear physics community a thin and pure solid windowless hydrogen or deuterium target. CHyMENE project must respond to this request for the production of solid Hydrogen. The solid hydrogen target is produced in a continuous flow (1 cm/s) by an extrusion technique (developed with the PELIN laboratory) in a vacuum chamber. The shape of the target is determined by the design of the nozzle at the extrusion process. For the purpose, the choice is a rectangular shape with a width of 10 mm and a thickness in the range of 30-50 microns necessary for the physics objectives. The cryostat is equipped with a GM Cryocooler with sufficient power for the solidification of the hydrogen in the lower portion of the extruder. In the higher part of the cryostat, the hydrogen gas is first liquefied and partially solidified. It is then compressed at 100 bars in the cooled extruder before expulsion of the film through the nozzle at the center of the reaction vacuum chamber. After the previous step, the solid hydrogen ribbon falls by gravity into a dedicated chamber where it sublimes and the gas is pumped and evacuated in a exhaust line. This paper deals with the design of the cryostat with its equipment, with the sizing of the thermal bridge (Aluminum and copper), with the results regarding the contact resistance as well as with the vacuum computations of the reaction and recovery hydrogen gas chambers.

  3. Porosity and biocompatibility study of ceramic implants based on ZrO{sub 2} and Al{sub 2}O{sub 3}

    SciTech Connect (OSTI)

    Litvinova, Larisa E-mail: vshupletsova@mail.ru Shupletsova, Valeria E-mail: vshupletsova@mail.ru Leitsin, Vladimir E-mail: vshupletsova@mail.ru; Vasyliev, Roman E-mail: zoubov77@yahoo.com; Zubov, Dmitry E-mail: zoubov77@yahoo.com; Buyakov, Ales E-mail: kulkov@ms.tsc.ru; Kulkov, Sergey E-mail: kulkov@ms.tsc.ru

    2014-11-14

    The work studies ZrO{sub 2}(Me{sub x}O{sub y})-based porous ceramics produced from the powders consisting of hollow spherical particles. It was shown that the structure is represented by a cellular framework with bimodal porosity consisting of sphere-like large pores and pores that were not filled with the powder particles during the compaction. For such ceramics, the increase of pore volume is accompanied by the increased strain in an elastic area. It was also shown that the porous ZrO{sub 2} ceramics had no acute or chronic cytotoxicity. At the same time, ceramics possess the following osteoconductive properties: adhesion support, spreading, proliferation and osteogenic differentiation of MSCs.

  4. Effect of Ru thickness on spin pumping in Ru/Py bilayer

    SciTech Connect (OSTI)

    Behera, Nilamani; Singh, M. Sanjoy; Chaudhary, Sujeet; Pandya, Dinesh K. Muduli, P. K.

    2015-05-07

    We report the effect of Ru thickness (t{sub Ru}) on ferromagnetic resonance (FMR) line-width of Ru(t{sub Ru})/Py(23?nm) bilayer samples grown on Si(100)/SiO{sub 2} substrates at room temperature by magnetron sputtering. The FMR line-width is found to vary linearly with frequency for all thicknesses of Ru, indicating intrinsic origin of damping. For Ru thicknesses below 15?nm, Gilbert-damping parameter, ? is almost constant. We ascribe this behavior to spin back flow that is operative for Ru thicknesses lower than the spin diffusion length in Ru, ?{sub sd}. For thicknesses >15?nm (>?{sub sd}), the damping constant increases with Ru thickness, indicating spin pumping from Py into Ru.

  5. DEPTH-CHARGE static and time-dependent perturbation/sensitivity system for nuclear reactor core analysis. Revision I. [DEPTH-CHARGE code

    SciTech Connect (OSTI)

    White, J.R.

    1985-04-01

    This report provides the background theory, user input, and sample problems required for the efficient application of the DEPTH-CHARGE system - a code black for both static and time-dependent perturbation theory and data sensitivity analyses. The DEPTH-CHARGE system is of modular construction and has been implemented within the VENTURE-BURNER computational system at Oak Ridge National Laboratory. The DEPTH module (coupled with VENTURE) solves for the three adjoint functions of Depletion Perturbation Theory and calculates the desired time-dependent derivatives of the response with respect to the nuclide concentrations and nuclear data utilized in the reference model. The CHARGE code is a collection of utility routines for general data manipulation and input preparation and considerably extends the usefulness of the system through the automatic generation of adjoint sources, estimated perturbed responses, and relative data sensitivity coefficients. Combined, the DEPTH-CHARGE system provides, for the first time, a complete generalized first-order perturbation/sensitivity theory capability for both static and time-dependent analyses of realistic multidimensional reactor models. This current documentation incorporates minor revisions to the original DEPTH-CHARGE documentation (ORNL/CSD-78) to reflect some new capabilities within the individual codes.

  6. Combined UHV/high-pressure catalysis setup for depth-resolved near-surface spectroscopic characterization and catalytic testing of model catalysts

    SciTech Connect (OSTI)

    Mayr, Lukas; Kltzer, Bernhard; Penner, Simon; Rameshan, Raffael; Department of Inorganic Chemistry, Fritz Haber Institute of the Max Planck Society, Faradayweg 4-6, 14195 Berlin ; Rameshan, Christoph; Institute of Materials Chemistry, Vienna University of Technology, Getreidemarkt 9/BC/01, 1060 Vienna

    2014-05-15

    An ultra-high vacuum (UHV) setup for real and inverse model catalyst preparation, depth-resolved near-surface spectroscopic characterization, and quantification of catalytic activity and selectivity under technologically relevant conditions is described. Due to the all-quartz reactor attached directly to the UHV-chamber, transfer of the catalyst for in situ testing without intermediate contact to the ambient is possible. The design of the UHV-compatible re-circulating batch reactor setup allows the study of reaction kinetics under close to technically relevant catalytic conditions up to 1273 K without contact to metallic surfaces except those of the catalyst itself. With the attached differentially pumped exchangeable evaporators and the quartz-microbalance thickness monitoring equipment, a reproducible, versatile, and standardised sample preparation is possible. For three-dimensional near-surface sample characterization, the system is equipped with a hemispherical analyser for X-ray photoelectron spectroscopy (XPS), electron-beam or X-ray-excited Auger-electron spectroscopy, and low-energy ion scattering measurements. Due the dedicated geometry of the X-ray gun (54.7, magic angle) and the rotatable sample holder, depth analysis by angle-resolved XPS measurements can be performed. Thus, by the combination of characterisation methods with different information depths, a detailed three-dimensional picture of the electronic and geometric structure of the model catalyst can be obtained. To demonstrate the capability of the described system, comparative results for depth-resolved sample characterization and catalytic testing in methanol steam reforming on PdGa and PdZn near-surface intermetallic phases are shown.

  7. Two weight system for measuring depth and sediment in slurry-supported excavations

    SciTech Connect (OSTI)

    Deming, P.; Good, D.

    1999-07-01

    This paper describes a two weight system using bar and flat shaped weights for measuring depth and detecting sediment at the bottom of slurry-supported excavations. Currently there are no standard depth measurement weights or methods for reliably identifying bottom sediment. Two weights and a procedural system for using the weights is described. Details suitable for manufacture are provided.

  8. Using the depth-velocity-size diagram to interpret equilibrium bed configurations in river flows

    SciTech Connect (OSTI)

    Southard, J.B. (Massachusetts Institute of Technology, Cambridge, MA (USA))

    1990-05-01

    Data from flume studies that report equilibrium bed configuration as well as water temperature, flow depth, flow velocity, and sediment size were used to develop the best approximation to the relationships among the various bed phases (ripples, dunes, lower regime plane bed, upper regime plane bed, and antidunes) in a three-axis graph (depth-velocity-size diagram) with dimensionless measures of mean flow depth, mean flow velocity, and sediment size along the axis. Relationships are shown in a series of depth-velocity and velocity-size sections through the diagram. Boundaries between bed-phase stability fields are drawn as surfaces that minimize, misplacement of data points. A large subset of the data, for which reliable values of bed shear stress are reported, was also used to represent the stability relationships in a graph of dimensionless boundary shear stress against dimensionless sediment size, but with results less useful for fluvial flow interpretation. The diagram covers about one order of magnitude in flow depth. To be useful for river flows, the diagram must be extrapolated in flow depth by about one more order of magnitude, but this is not a serious problem for approximate work. The depth-velocity-size diagram permits prediction of equilibrium bed configuration in river flows when the approximate flow depth and mean flow velocity are known. Because the diagram is essentially dimensionless, the effect of water temperature (via the fluid viscosity) on the bed configuration is easily accounted for by use of the diagram.

  9. Method for determining depth and shape of a sub-surface conductive object

    DOE Patents [OSTI]

    Lee, D.O.; Montoya, P.C.; Wayland, Jr.

    1984-06-27

    The depth to and size of an underground object may be determined by sweeping a controlled source audio magnetotelluric (CSAMT) signal and locating a peak response when the receiver spans the edge of the object. The depth of the object is one quarter wavelength in the subsurface media of the frequency of the peak. 3 figures.

  10. SU-E-T-319: The Effect of Slice Thickness On IMRT Planning

    SciTech Connect (OSTI)

    Srivastava, S; Das, I; Cheng, C

    2014-06-01

    Purpose: The accuracy of volume estimated of a treatment planning system is investigated in this study. In addition, the effect of slice thickness on IMRT planning is also studied. Methods: The accuracy in volume determination was investigated using a water phantom containing various objects with known volumes ranging from 1100cm{sup 3}. The phantom was scanned with different slice thickness (110 mm). The CT data sets were sent to Eclipse TPS for contour delineation and volume calculation. The effect of slice thickness on IMRT planning was studied using a commercial phantom containing four different shaped objects. The phantom was scanned with different slice thickness (15 mm). IMRT plans were generated for the different CT datasets to calculate TCP, homogeneity (HI) and conformity indices (CI). Results: The variability of volumes with CT slice thickness was significant especially for small volume structures. The minimum and maximum error in the volume estimation is in the range of ?2.3% to 92%. On the other hand, with increasing slice thickness, the PTV mean dose and TCP values decreases. Maximum variation of ?5% was observed in mean dose and ?2% in TCP with slice thickness change from 15 mm. The relative decrease in target volume receiving 95% of prescribed dose is ?5% slice thickness change from 15 mm. HI increases up to 163% and CI decreases by 4% between 15 mm slice thickness change, producing highly inhomogeneous and least conformal plan. Conclusion: Accuracy of volume estimation is dependent on CT slice thickness and the contouring algorithm in a TPS. During TPS commissioning and for all clinical protocols, evaluation of volume should be included to provide the limit of accuracy in DVH calculation. A smaller slice thickness provides superior dosimetry with improved TCP values. Thus, the smallest possible slice thickness should be used for IMRT planning.

  11. Effects of Volcanism, Crustal Thickness, and Large Scale Faulting on the

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Development and Evolution of Geothermal Systems: Collaborative Project in Chile | Department of Energy Effects of Volcanism, Crustal Thickness, and Large Scale Faulting on the Development and Evolution of Geothermal Systems: Collaborative Project in Chile Effects of Volcanism, Crustal Thickness, and Large Scale Faulting on the Development and Evolution of Geothermal Systems: Collaborative Project in Chile Effects of Volcanism, Crustal Thickness, and Large Scale Faulting on the Development

  12. SU-E-I-11: Cascaded Linear System Model for Columnar CsI Flat Panel Imagers with Depth Dependent Gain and Blur

    SciTech Connect (OSTI)

    Peng, B; Lubinsky, A; Zheng, H; Zhao, W; Teymurazyan, A

    2014-06-01

    Purpose: To implement a depth dependent gain and blur cascaded linear system model (CLSM) for optimizing columnar structured CsI indirect conversion flat panel imager (FPI) for advanced imaging applications. Methods: For experimental validation, depth dependent escape efficiency, e(z), was extracted from PHS measurement of different CsI scintillators (thickness, substrate and light output). The inherent MTF and DQE of CsI was measured using high resolution CMOS sensor. For CLSM, e(z) and the depth dependent MTF(f,z), were estimated using Monte Carlo simulation (Geant4) of optical photon transport through columnar CsI. Previous work showed that Monte Carlo simulation for CsI was hindered by the non-ideality of its columnar structure. In the present work we allowed variation in columnar width with depth, and assumed diffusive reflective backing and columns. Monte Carlo simulation was performed using an optical point source placed at different depth of the CsI layer, from which MTF(z,f) and e(z) were computed. The resulting e(z) with excellent matching with experimental measurements were then applied to the CLSM, Monte Carlo simulation was repeated until the modeled MTF, DQE(f) also match experimental measurement. Results: For a 150 micron FOS HL type CsI, e(z) varies between 0.56 to 0.45, and the MTF at 14 cycles/mm varies between 62.1% to 3.9%, from the front to the back of the scintillator. The overall MTF and DQE(f) at all frequencies are in excellent agreement with experimental measurements at all frequencies. Conclusion: We have developed a CLSM for columnar CsI scintillators with depth dependent gain and MTF, which were estimated from Monte Carlo simulation with novel optical simulation settings. Preliminary results showed excellent agreement between simulation results and experimental measurements. Future work is aimed at extending this approach to optimize CsI screen optic design and sensor structure for achieving higher DQE(f) in cone-beam CT, which uses high kVp.

  13. ARM: 10-minute TEMPORARY Raman Lidar: aerosol extinction profiles and aerosol optical thickness, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Sivaraman, Chitra; Flynn, Connor

    2010-12-15

    10-minute TEMPORARY Raman Lidar: aerosol extinction profiles and aerosol optical thickness, from first Ferrare algorithm

  14. ARM: 10-minute TEMPORARY Raman Lidar: aerosol extinction profiles and aerosol optical thickness, from first Ferrare algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Sivaraman, Chitra; Flynn, Connor

    10-minute TEMPORARY Raman Lidar: aerosol extinction profiles and aerosol optical thickness, from first Ferrare algorithm

  15. Depth Profiling of SiC Lattice Damage Using Micro-Raman Spectroscopy

    Office of Scientific and Technical Information (OSTI)

    (Conference) | SciTech Connect Depth Profiling of SiC Lattice Damage Using Micro-Raman Spectroscopy Citation Details In-Document Search Title: Depth Profiling of SiC Lattice Damage Using Micro-Raman Spectroscopy Depth profiling for the amount of lattice damage using a Confocal Micro-Raman (CMR) spectrometer is demonstrated in this paper. Samples of n-type silicon carbide were implanted with 2 MeV He and O ions at both room temperature and 500 C, and fluences between 10{sup 15} and 10{sup 17}

  16. ARM - Evaluation Product - MicroPulse LIDAR Cloud Optical Depth (MPLCOD)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ProductsMicroPulse LIDAR Cloud Optical Depth (MPLCOD) ARM Data Discovery Browse Data Documentation Use the Data File Inventory tool to view data availability at the file level. Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Evaluation Product : MicroPulse LIDAR Cloud Optical Depth (MPLCOD) The MPLCOD VAP retrieves the column cloud visible optical depth using LIDAR derived backscatter from the MPLNOR (Micro Pulse Lidar Normalized Backscatter) and

  17. Riser Difference Evaluation from Ultrasonic Wall Thickness Inspection of Thirteen Double-Shell Tanks

    SciTech Connect (OSTI)

    Weier, Dennis R.; Pardini, Allan F.

    2010-03-15

    PNNL has performed an analysis of ultrasonic thickness measurements taken on Hanford's double-shell tanks (DSTs) approximately eight years apart. The analysis was performed to determine whether significant differences exist between ultrasonic thickness measurements made in two opposite risers in Hanford DSTs that have been examined twice.

  18. Density dependence of the symmetry energy from neutron skin thickness in finite nuclei

    SciTech Connect (OSTI)

    Vinas, X.; Centelles, M.; Roca-Maza, X.; Warda, M.

    2012-10-20

    The density dependence of the symmetry energy, characterized by the parameter L, is studied using information provided by the neutron skin thickness in finite nuclei. An estimate of L is obtained from experimental data of antiprotonic atoms. We also discuss the ability of parity violating electron scatering to obtain information about the neutron skin thickness in {sup 208}Pb.

  19. Vehicle Technologies Office Merit Review 2014: Advanced Technology Vehicle Lab Benchmarking- Level 2 (in-depth)

    Broader source: Energy.gov [DOE]

    Presentation given by Argonne National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about level 2 (in-depth...

  20. Depth-dependent ordering, two-length-scale phenomena, and crossover...

    Office of Scientific and Technical Information (OSTI)

    behavior in a crystal featuring a skin layer with defects Citation Details In-Document Search Title: Depth-dependent ordering, two-length-scale phenomena, and crossover behavior ...

  1. Depth Profile of Uncompensated Spins in an Exchange-Bias System

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A. Mishra, X. Zhang, K. Chesnel, J.B. Kortright, S.K. Sinha, and I.K. Schuller,, "Depth Profile of Uncompensated Spins in an Exchange Bias System," Phys. Rev. Lett. 95, 047201...

  2. Method of varying a physical property of a material through its depth

    DOE Patents [OSTI]

    Daniel, Claus

    2015-04-21

    A method is disclosed for varying a mechanical property of a material at two depths. The method involves the application of at least two laser pulses of different durations. The method involves a determination of the density of the material from the surface to each depth, a determination of the heat capacity of the material from the surface to each depth, and a determination of the thermal conductivity of the material from the surface to each depth. Each laser pulse may affect the density, heat capacity, and thermal conductivity of the material, so it may be necessary to re-evaluate those parameters after each laser pulse and prior to the next pulse. The method may be applied to implantation materials to improve osteoblast and osteoclast activity.

  3. U.S. Average Depth of Crude Oil, Natural Gas, and Dry Developmental...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Developmental Wells Drilled (Feet per Well) U.S. Average Depth of Crude Oil, Natural Gas, and Dry Developmental Wells Drilled (Feet per Well) Decade Year-0 Year-1 Year-2 Year-3...

  4. U.S. Average Depth of Crude Oil Exploratory and Developmental...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    and Developmental Wells Drilled (Feet per Well) U.S. Average Depth of Crude Oil Exploratory and Developmental Wells Drilled (Feet per Well) Decade Year-0 Year-1 Year-2 Year-3...

  5. U.S. Average Depth of Natural Gas Exploratory and Developmental...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    and Developmental Wells Drilled (Feet per Well) U.S. Average Depth of Natural Gas Exploratory and Developmental Wells Drilled (Feet per Well) Decade Year-0 Year-1 Year-2 Year-3...

  6. U.S. Average Depth of Dry Holes Developmental Wells Drilled ...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Developmental Wells Drilled (Feet per Well) U.S. Average Depth of Dry Holes Developmental Wells Drilled (Feet per Well) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6...

  7. U.S. Average Depth of Dry Holes Exploratory Wells Drilled (Feet...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Exploratory Wells Drilled (Feet per Well) U.S. Average Depth of Dry Holes Exploratory Wells Drilled (Feet per Well) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7...

  8. U.S. Average Depth of Natural Gas Developmental Wells Drilled...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Developmental Wells Drilled (Feet per Well) U.S. Average Depth of Natural Gas Developmental Wells Drilled (Feet per Well) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6...

  9. U.S. Average Depth of Natural Gas Exploratory Wells Drilled ...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Wells Drilled (Feet per Well) U.S. Average Depth of Natural Gas Exploratory Wells Drilled (Feet per Well) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8...

  10. U.S. Average Depth of Crude Oil, Natural Gas, and Dry Exploratory...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Wells Drilled (Feet per Well) U.S. Average Depth of Crude Oil, Natural Gas, and Dry Exploratory Wells Drilled (Feet per Well) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5...

  11. U.S. Average Depth of Crude Oil Exploratory Wells Drilled (Feet...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Wells Drilled (Feet per Well) U.S. Average Depth of Crude Oil Exploratory Wells Drilled (Feet per Well) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9...

  12. U.S. Average Depth of Crude Oil, Natural Gas, and Dry Exploratory...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    and Developmental Wells Drilled (Feet per Well) U.S. Average Depth of Crude Oil, Natural Gas, and Dry Exploratory and Developmental Wells Drilled (Feet per Well) Decade Year-0...

  13. U.S. Average Depth of Crude Oil Developmental Wells Drilled ...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Developmental Wells Drilled (Feet per Well) U.S. Average Depth of Crude Oil Developmental Wells Drilled (Feet per Well) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6...

  14. U.S. Average Depth of Dry Exploratory and Developmental Wells...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Exploratory and Developmental Wells Drilled (Feet per Well) U.S. Average Depth of Dry Exploratory and Developmental Wells Drilled (Feet per Well) Decade Year-0 Year-1 Year-2 Year-3...

  15. Depth Profile of Uncompensated Spins in an Exchange-Bias System

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Depth Profile of Uncompensated Spins in an Exchange-Bias System Print The phenomenon known as exchange bias at the interface between a ferromagnet and an antiferromagnet is currently a subject of intense research because of its applications in the magnetic recording and read-head industries. An international collaboration headed by researchers from the University of California, San Diego, has used resonant x-ray scattering and polarized-neutron reflectometry to determine the depth-dependent

  16. Depth Profile of Uncompensated Spins in an Exchange-Bias System

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Depth Profile of Uncompensated Spins in an Exchange-Bias System Print The phenomenon known as exchange bias at the interface between a ferromagnet and an antiferromagnet is currently a subject of intense research because of its applications in the magnetic recording and read-head industries. An international collaboration headed by researchers from the University of California, San Diego, has used resonant x-ray scattering and polarized-neutron reflectometry to determine the depth-dependent

  17. Depth Profile of Uncompensated Spins in an Exchange-Bias System

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Depth Profile of Uncompensated Spins in an Exchange-Bias System Print The phenomenon known as exchange bias at the interface between a ferromagnet and an antiferromagnet is currently a subject of intense research because of its applications in the magnetic recording and read-head industries. An international collaboration headed by researchers from the University of California, San Diego, has used resonant x-ray scattering and polarized-neutron reflectometry to determine the depth-dependent

  18. Depth Profile of Uncompensated Spins in an Exchange-Bias System

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Depth Profile of Uncompensated Spins in an Exchange-Bias System Print The phenomenon known as exchange bias at the interface between a ferromagnet and an antiferromagnet is currently a subject of intense research because of its applications in the magnetic recording and read-head industries. An international collaboration headed by researchers from the University of California, San Diego, has used resonant x-ray scattering and polarized-neutron reflectometry to determine the depth-dependent

  19. Depth Profile of Uncompensated Spins in an Exchange-Bias System

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Depth Profile of Uncompensated Spins in an Exchange-Bias System Print The phenomenon known as exchange bias at the interface between a ferromagnet and an antiferromagnet is currently a subject of intense research because of its applications in the magnetic recording and read-head industries. An international collaboration headed by researchers from the University of California, San Diego, has used resonant x-ray scattering and polarized-neutron reflectometry to determine the depth-dependent

  20. Depth Profile of Uncompensated Spins in an Exchange-Bias System

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Depth Profile of Uncompensated Spins in an Exchange-Bias System Depth Profile of Uncompensated Spins in an Exchange-Bias System Print Wednesday, 25 January 2006 00:00 The phenomenon known as exchange bias at the interface between a ferromagnet and an antiferromagnet is currently a subject of intense research because of its applications in the magnetic recording and read-head industries. An international collaboration headed by researchers from the University of California, San Diego, has used

  1. Comparison of Cloud Top Height and Optical Depth Histograms from ISCCP,

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    MISR, and MODIS Comparison of Cloud Top Height and Optical Depth Histograms from ISCCP, MISR, and MODIS Marchand, Roger Pacific Northwest National Laboratory Ackerman, Thomas Pacific Northwest National Laboratory Category: Cloud Properties Joint histograms of Cloud Top Height (CTH) and Optical Depth (OD) derived by the International Satellite Cloud Climatology Project (ISCCP) are being widely used by the climate modeling community in evaluating global climate models. Similar joint histograms

  2. Defense-in-Depth, How Department of Energy Implements Radiation Protection

    Office of Environmental Management (EM)

    in Low Level Waste Disposal | Department of Energy Defense-in-Depth, How Department of Energy Implements Radiation Protection in Low Level Waste Disposal Defense-in-Depth, How Department of Energy Implements Radiation Protection in Low Level Waste Disposal Linda Suttora*, U.S. Department of Energy ; Andrew Wallo, U.S. Department of Energy Abstract: The United States Department of Energy (DOE) has adopted an integrated protection system for the safety of radioactive waste disposal similar to

  3. Insights into the effect of dilute acid, hot water and alkaline pretreatment on cellulose accessible surface area and overall porosity of Populus

    SciTech Connect (OSTI)

    Meng, Xianzhi; Wells, Tyrone; Sun, Qining; Huang, Fang; Ragauskas, Arthur J.

    2015-06-19

    Pretreatment is known to render biomass more reactive to cellulase by altering the chemical compositions as well as physical structures of biomass. Simons stain technique along with mercury porosimetry were applied on the acid, neutral, and alkaline pretreated materials to measure the accessible surface area of cellulose and pore size distribution of Populus. Results indicated that acid pretreatment is much more effective than water and alkaline pretreatment in terms of cellulose accessibility increase. Further investigation suggests that lignin does not dictate cellulose accessibility to the extent that hemicellulose does, but it does restrict xylan accessibility which in turn controls the access of cellulase to cellulose. The most interesting finding is that severe acid pretreatment significantly decreases the average pore size, i.e., 90% average size decrease could be observed after 60 min dilute acid pretreatment at 160 oC; however, the nano-pore space formed between coated microfibrils is increased after pretreatment, especially for the acid pretreatment, suggesting this particular type of biomass porosity is probably the most fundamental barrier to effective enzymatic hydrolysis.

  4. Insights into the effect of dilute acid, hot water and alkaline pretreatment on cellulose accessible surface area and overall porosity of Populus

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Meng, Xianzhi; Wells, Tyrone; Sun, Qining; Huang, Fang; Ragauskas, Arthur J.

    2015-06-19

    Pretreatment is known to render biomass more reactive to cellulase by altering the chemical compositions as well as physical structures of biomass. Simons stain technique along with mercury porosimetry were applied on the acid, neutral, and alkaline pretreated materials to measure the accessible surface area of cellulose and pore size distribution of Populus. Results indicated that acid pretreatment is much more effective than water and alkaline pretreatment in terms of cellulose accessibility increase. Further investigation suggests that lignin does not dictate cellulose accessibility to the extent that hemicellulose does, but it does restrict xylan accessibility which in turn controls themore » access of cellulase to cellulose. The most interesting finding is that severe acid pretreatment significantly decreases the average pore size, i.e., 90% average size decrease could be observed after 60 min dilute acid pretreatment at 160 °C; moreover, the nano-pore space formed between coated microfibrils is increased after pretreatment, especially for the acid pretreatment, suggesting this particular type of biomass porosity is probably the most fundamental barrier to effective enzymatic hydrolysis.« less

  5. Measurement of porosity in a composite high explosive as a function of pressing conditions by ultra-small-angle neutron scattering with contrast variation

    SciTech Connect (OSTI)

    Mang, Joseph Thomas; Hjelm, Rex P; Francois, Elizabeth G

    2009-01-01

    We have used ultra-small-angle neutron scattering (USANS) with contrast variation to measure the porosity (voids and binder-filled regions) in a composite high explosive, PBX 9501, formulated with a deuterated binder. Little is known about the microstructure of pressed PBX 9501 parts and thus how it is affected by processing. Here, we explore the effect of varying the pressing intensity on the PBX 9501 microstructure. Disk-shaped samples of PBX 9501 were die-pressed with applied pressures ranging between 10,000 and 29,000 psi at 90 C. Five samples were prepared at each pressure that differed in the fraction of deuterated binder, facilitating variation of the neutron scattering length density contrast ({Delta}{rho}) and thus, the resolution of microstructural details. The sample composition was determined by calculation of the Porod Invariant as a function of {Delta}{rho} and compared with compositional estimates obtained from the bulk sample density. Structural modeling of the USANS data, at different levels of contrast, assuming both spherical and cylindrical morphologies, allowed the mean size and size distribution of voids and binder-filled regions to be determined. A decrease in the mean diameter of binder-filled regions was found with increasing pressing intensity, while the mean void diameter showed no significant change.

  6. Measurement of sound speed vs. depth in South Pole ice: pressure waves and shear waves

    SciTech Connect (OSTI)

    IceCube Collaboration; Klein, Spencer

    2009-06-04

    We have measured the speed of both pressure waves and shear waves as a function of depth between 80 and 500 m depth in South Pole ice with better than 1% precision. The measurements were made using the South Pole Acoustic Test Setup (SPATS), an array of transmitters and sensors deployed in the ice at the South Pole in order to measure the acoustic properties relevant to acoustic detection of astrophysical neutrinos. The transmitters and sensors use piezoceramics operating at {approx}5-25 kHz. Between 200 m and 500 m depth, the measured profile is consistent with zero variation of the sound speed with depth, resulting in zero refraction, for both pressure and shear waves. We also performed a complementary study featuring an explosive signal propagating vertically from 50 to 2250 m depth, from which we determined a value for the pressure wave speed consistent with that determined for shallower depths, higher frequencies, and horizontal propagation with the SPATS sensors. The sound speed profile presented here can be used to achieve good acoustic source position and emission time reconstruction in general, and neutrino direction and energy reconstruction in particular. The reconstructed quantities could also help separate neutrino signals from background.

  7. Non-destructive in-situ method and apparatus for determining radionuclide depth in media

    DOE Patents [OSTI]

    Xu, X. George (Clifton Park, NY); Naessens, Edward P. (West Point, NY)

    2003-01-01

    A non-destructive method and apparatus which is based on in-situ gamma spectroscopy is used to determine the depth of radiological contamination in media such as concrete. An algorithm, Gamma Penetration Depth Unfolding Algorithm (GPDUA), uses point kernel techniques to predict the depth of contamination based on the results of uncollided peak information from the in-situ gamma spectroscopy. The invention is better, faster, safer, and/cheaper than the current practice in decontamination and decommissioning of facilities that are slow, rough and unsafe. The invention uses a priori knowledge of the contaminant source distribution. The applicable radiological contaminants of interest are any isotopes that emit two or more gamma rays per disintegration or isotopes that emit a single gamma ray but have gamma-emitting progeny in secular equilibrium with its parent (e.g., .sup.60 Co, .sup.235 U, and .sup.137 Cs to name a few). The predicted depths from the GPDUA algorithm using Monte Carlo N-Particle Transport Code (MCNP) simulations and laboratory experiments using .sup.60 Co have consistently produced predicted depths within 20% of the actual or known depth.

  8. Enhancing through thickness thermal conductivity of ultra-thin composite laminates. Final report

    SciTech Connect (OSTI)

    Ramani, K.; Vaidyanathan, A.

    1994-12-31

    The materials used in electronic applications have specific requirements for stiffness, thermal conductivity, and electromagnetic shielding making the choice of materials used very important. Electronic components are very sensitive to heat, hence the heat dissipation or cooling of the various components is necessary to prevent failure. Thus, any material used in the electronic industry must have a high thermal conductivity in addition to a specified thermal expansion, stiffness and strength properties. The purpose of this project was to design and manufacture composite panels which would conduct heat from an electronic chip attached to the top surface to a cooling liquid flowing at its lower surface. To maximize the heat conducted from the chip to the cooling liquid, the composite must have a high through thickness thermal conductivity. Further, design restrictions on the thickness of the composite panel had to be taken into account. It was found that the presence of excess resin adversely affects the conductivity of a woven fabric composite due to which the through thickness conductivity of the 400 {micro}m thick panel was better than the 500 {micro}m thick panel. The through thickness conductivity of the panel with short fibers alone was better than that of the woven cloth panel. The finite element model developed for a priori prediction of the through thickness thermal conductivity of the composite panels is a very powerful tool that can save enormous prototyping times an associates coats.

  9. In situ measurement of low-Z material coating thickness on high Z substrate for tokamaks

    SciTech Connect (OSTI)

    Mueller, D. Roquemore, A. L.; Jaworski, M.; Skinner, C. H.; Miller, J.; Creely, A.; Raman, P.; Ruzic, D.

    2014-11-15

    Rutherford backscattering of energetic particles can be used to determine the thickness of a coating of a low-Z material over a heavier substrate. Simulations indicate that 5 MeV alpha particles from an {sup 241}Am source can be used to measure the thickness of a Li coating on Mo tiles between 0.5 and 15??m thick. Using a 0.1?mCi source, a thickness measurement can be accomplished in 2 h of counting. This technique could be used to measure any thin, low-Z material coating (up to 1?mg/cm{sup 2} thick) on a high-Z substrate, such as Be on W, B on Mo, or Li on Mo. By inserting a source and detector on a moveable probe, this technique could be used to provide an in situ measurement of the thickness of Li coating on NSTX-U Mo tiles. A test stand with an alpha source and an annular solid-state detector was used to investigate the measurable range of low-Z material thicknesses on Mo tiles.

  10. In situ measurement of low-Z material coating thickness on high Z substrate

    Office of Scientific and Technical Information (OSTI)

    for tokamaks (Journal Article) | SciTech Connect In situ measurement of low-Z material coating thickness on high Z substrate for tokamaks Citation Details In-Document Search Title: In situ measurement of low-Z material coating thickness on high Z substrate for tokamaks Rutherford backscattering of energetic particles can be used to determine the thickness of a coating of a low-Z material over a heavier substrate. Simulations indicate that 5 MeV alpha particles from an {sup 241}Am source can

  11. In-situ Measurement of Low-Z Material Coating Thickness on High Z Substrate

    Office of Scientific and Technical Information (OSTI)

    for Tokamaks (Conference) | SciTech Connect Conference: In-situ Measurement of Low-Z Material Coating Thickness on High Z Substrate for Tokamaks Citation Details In-Document Search Title: In-situ Measurement of Low-Z Material Coating Thickness on High Z Substrate for Tokamaks Rutherford backscattering (RBS) of energetic particles can be used to determine the thickness of a coating of a low-Z material over a heavier substrate. Simulations indicate that 5 MeV alpha particles from an Am source

  12. A JOINT MODEL OF X-RAY AND INFRARED BACKGROUNDS. II. COMPTON-THICK ACTIVE

    Office of Scientific and Technical Information (OSTI)

    GALACTIC NUCLEUS ABUNDANCE (Journal Article) | SciTech Connect X-RAY AND INFRARED BACKGROUNDS. II. COMPTON-THICK ACTIVE GALACTIC NUCLEUS ABUNDANCE Citation Details In-Document Search Title: A JOINT MODEL OF X-RAY AND INFRARED BACKGROUNDS. II. COMPTON-THICK ACTIVE GALACTIC NUCLEUS ABUNDANCE We estimate the abundance of Compton-thick (CT) active galactic nuclei (AGNs) based on our joint model of X-ray and infrared backgrounds. At L{sub rest2-10{sub keV}} > 10{sup 42} erg s{sup -1}, the CT

  13. ORIGIN OF CHEMICAL AND DYNAMICAL PROPERTIES OF THE GALACTIC THICK DISK

    SciTech Connect (OSTI)

    Bekki, Kenji [ICRAR, M468, University of Western Australia, Crawley, Western Australia, 6009 (Australia); Tsujimoto, Takuji [National Astronomical Observatory, Mitaka-shi, Tokyo 181-8588 (Japan)

    2011-09-01

    We adopt a scenario in which the Galactic thick disk was formed by minor merging between the first generation of the Galactic thin disk (FGTD) and a dwarf galaxy about {approx}9 Gyr ago and thereby investigate chemical and dynamical properties of the Galactic thick disk. In this scenario, the dynamical properties of the thick disk have long been influenced both by the mass growth of the second generation of the Galactic thin disk (i.e., the present thin disk) and by its non-axisymmetric structures. On the other hand, the early star formation history and chemical evolution of the thin disk was influenced by the remaining gas of the thick disk. Based on N-body simulations and chemical evolution models, we investigate the radial metallicity gradient, structural and kinematical properties, and detailed chemical abundance patterns of the thick disk. Our numerical simulations show that the ancient minor merger event can significantly flatten the original radial metallicity gradient of the FGTD, in particular, in the outer part, and also can be responsible for migration of inner metal-rich stars into the outer part (R > 10 kpc). The simulations show that the central region of the thick disk can develop a bar due to dynamical effects of a separate bar in the thin disk. Whether or not rotational velocities (V{sub {phi}}) can correlate with metallicities ([Fe/H]) for the simulated thick disks depends on the initial metallicity gradients of the FGTDs. The simulated orbital eccentricity distributions in the thick disk for models with higher mass ratios ({approx}0.2) and lower orbital eccentricities ({approx}0.5) of minor mergers are in good agreement with the corresponding observations. The simulated V{sub {phi}}-|z| relation of the thick disk in models with low orbital inclination angles of mergers are also in good agreement with the latest observational results. The vertical metallicity gradient of the simulated thick disk is rather flat or very weakly negative in the solar neighborhood. Our Galactic chemical evolution models show that if we choose two distinctive timescales for star formation in the thin and thick disks, then the models can explain both the observed metallicity distribution functions and correlations between [Mg/Fe] and [Fe/H] for the two disks in a self-consistent manner. We discuss how the early star formation history and chemical evolution of the Galactic thin disk can be influenced by the pre-existing thick disk.

  14. An analysis of the pull strength behaviors of fine-pitch, flip chip solder interconnections using a Au-Pt-Pd thick film conductor on Low-Temperature, Co-fired Ceramic (LTCC) substrates.

    SciTech Connect (OSTI)

    Uribe, Fernando R.; Kilgo, Alice C.; Grazier, John Mark; Vianco, Paul Thomas; Zender, Gary L.; Hlava, Paul Frank; Rejent, Jerome Andrew

    2008-09-01

    The assembly of the BDYE detector requires the attachment of sixteen silicon (Si) processor dice (eight on the top side; eight on the bottom side) onto a low-temperature, co-fired ceramic (LTCC) substrate using 63Sn-37Pb (wt.%, Sn-Pb) in a double-reflow soldering process (nitrogen). There are 132 solder joints per die. The bond pads were gold-platinum-palladium (71Au-26Pt-3Pd, wt.%) thick film layers fired onto the LTCC in a post-process sequence. The pull strength and failure modes provided the quality metrics for the Sn-Pb solder joints. Pull strengths were measured in both the as-fabricated condition and after exposure to thermal cycling (-55/125 C; 15 min hold times; 20 cycles). Extremely low pull strengths--referred to as the low pull strength phenomenon--were observed intermittently throughout the product build, resulting in added program costs, schedule delays, and a long-term reliability concern for the detector. There was no statistically significant correlation between the low pull strength phenomenon and (1) the LTCC 'sub-floor' lot; (2) grit blasting the LTCC surfaces prior to the post-process steps; (3) the post-process parameters; (4) the conductor pad height (thickness); (5) the dice soldering assembly sequence; or (5) the dice pull test sequence. Formation of an intermetallic compound (IMC)/LTCC interface caused by thick film consumption during either the soldering process or by solid-state IMC formation was not directly responsible for the low-strength phenomenon. Metallographic cross sections of solder joints from dice that exhibited the low pull strength behavior, revealed the presence of a reaction layer resulting from an interaction between Sn from the molten Sn-Pb and the glassy phase at the TKN/LTCC interface. The thick film porosity did not contribute, explicitly, to the occurrence of reaction layer. Rather, the process of printing the very thin conductor pads was too sensitive to minor thixotropic changes to ink, which resulted in inconsistent proportions of metal and glassy phase particles present during the subsequent firing process. The consequences were subtle, intermittent changes to the thick film microstructure that gave rise to the reaction layer and, thus, the low pull strength phenomenon. A mitigation strategy would be the use of physical vapor deposition (PVD) techniques to create thin film bond pads; this is multi-chip module, deposited (MCM-D) technology.

  15. Seismic Velocity Structure and Depth-Dependence of Anisotropy in the Red Sea and Arabian Shield from Surface Wave Analysis

    SciTech Connect (OSTI)

    Hansen, S; Gaherty, J; Schwartz, S; Rodgers, A; Al-Amri, A

    2007-07-25

    We investigate the lithospheric and upper mantle structure as well as the depth-dependence of anisotropy along the Red Sea and beneath the Arabian Peninsula using receiver function constraints and phase velocities of surface waves traversing two transects of stations from the Saudi Arabian National Digital Seismic Network. Frequency-dependent phase delays of fundamental-mode Love and Rayleigh waves, measured using a cross-correlation procedure, require very slow shear velocities and the presence of anisotropy throughout the upper mantle. Linearized inversion of these data produce path-averaged 1D radially anisotropic models with about 4% anisotropy in the lithosphere, increasing to about 4.8% anisotropy across the lithosphere-asthenosphere boundary (LAB). Models with reasonable crustal velocities in which the mantle lithosphere is isotropic cannot satisfy the data. The lithospheric lid, which ranges in thickness from about 70 km near the Red Sea coast to about 90 km beneath the Arabian Shield, is underlain by a pronounced low-velocity zone with shear velocities as low as 4.1 km/s. Forward models, which are constructed from previously determined shear-wave splitting estimates, can reconcile surface and body wave observations of anisotropy. The low shear velocity values are similar to many other continental rift and oceanic ridge environments. These low velocities combined with the sharp velocity contrast across the LAB may indicate the presence of partial melt beneath Arabia. The anisotropic signature primarily reflects a combination of plate- and density-driven flow associated with active rifting processes in the Red Sea.

  16. Assessment of underground coal gasification in bituminous coals: catalog of bituminous coals and site selection. Appendix A. National coal resource data system: Ecoal, Wcoal, and Bmalyt. Final report, Phase I. [Bituminous coal; by state; coal seam depth and thickness; identification

    SciTech Connect (OSTI)

    1982-01-31

    Appendix A is a catalog of the bituminous coal in 29 states of the contiguous United States which contain identified bituminous coal resources.

  17. ARM: 10-minute Raman Lidar: aerosol depolarization profiles and single layer cloud optical depths from first Turner algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Chitra Sivaraman; Connor Flynn

    1998-03-01

    10-minute Raman Lidar: aerosol depolarization profiles and single layer cloud optical depths from first Turner algorithm

  18. ARM: 10-minute Raman Lidar: aerosol depolarization profiles and single layer cloud optical depths from first Turner algorithm

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Chitra Sivaraman; Connor Flynn

    10-minute Raman Lidar: aerosol depolarization profiles and single layer cloud optical depths from first Turner algorithm

  19. On-Line Measurement of Lubricant Film Thickness Using Ultrasonic Reflection Coefficients

    SciTech Connect (OSTI)

    Drinkwater, B.W.; Dwyer-Joyce, R.S.; Harper, P.

    2004-02-26

    The ultrasonic reflectivity of a lubricant layer between two solid bodies depends on the ultrasonic frequency, the acoustic properties of the liquid and solid, and the layer thickness. In this paper, ultrasonic reflectivity measurements are used as a method for determining the thickness of lubricating films in bearing systems. An ultrasonic transducer is positioned on the outside of a bearing shell such that the wave is focused on the lubricant film layer. For a particular lubricant film the reflected pulse is processed to give a reflection coefficient spectrum. The lubricant film thickness is then obtained from either the layer stiffness or the resonant frequency. The method has been validated using static fluid wedges and the elastohydrodynamic film formed between a ball sliding on a flat. Film thickness values in the range 50-500 nm were recorded which agreed well with theoretical film formation predictions.

  20. Extraction of depth-dependent perturbation factors for silicon diodes using a plastic scintillation detector

    SciTech Connect (OSTI)

    Lacroix, Frederic; Guillot, Mathieu; McEwen, Malcolm; Gingras, Luc; Beaulieu, Luc

    2011-10-15

    Purpose: This work presents the experimental extraction of the perturbation factor in megavoltage electron beams for three models of silicon diodes (IBA Dosimetry, EFD and SFD, and the PTW 60012 unshielded) using a plastic scintillation detector (PSD). Methods: The authors used a single scanning PSD mounted on a high-precision scanning tank to measure depth-dose curves in 6-, 12-, and 18-MeV clinical electron beams. They also measured depth-dose curves using the IBA Dosimetry, EFD and SFD, and the PTW 60012 unshielded diodes. The authors used the depth-dose curves measured with the PSD as a perturbation-free reference to extract the perturbation factors of the diodes. Results: The authors found that the perturbation factors for the diodes increased substantially with depth, especially for low-energy electron beams. The experimental results show the same trend as published Monte Carlo simulation results for the EFD diode; however, the perturbations measured experimentally were greater. They found that using an effective point of measurement (EPOM) placed slightly away from the source reduced the variation of perturbation factors with depth and that the optimal EPOM appears to be energy dependent. Conclusions: The manufacturer recommended EPOM appears to be incorrect at low electron energy (6 MeV). In addition, the perturbation factors for diodes may be greater than predicted by Monte Carlo simulations.

  1. Daily snow depth measurements from 195 stations in the United States

    SciTech Connect (OSTI)

    Allison, L.J.; Easterling, D.R.; Jamason, P.; Bowman, D.P.; Hughes, P.Y.; Mason, E.H.

    1997-02-01

    This document describes a database containing daily measurements of snow depth at 195 National Weather Service (NWS) first-order climatological stations in the United States. The data have been assembled and made available by the National Climatic Data Center (NCDC) in Asheville, North Carolina. The 195 stations encompass 388 unique sampling locations in 48 of the 50 states; no observations from Delaware or Hawaii are included in the database. Station selection criteria emphasized the quality and length of station records while seeking to provide a network with good geographic coverage. Snow depth at the 388 locations was measured once per day on ground open to the sky. The daily snow depth is the total depth of the snow on the ground at measurement time. The time period covered by the database is 1893--1992; however, not all station records encompass the complete period. While a station record ideally should contain daily data for at least the seven winter months (January through April and October through December), not all stations have complete records. Each logical record in the snow depth database contains one station`s daily data values for a period of one month, including data source, measurement, and quality flags.

  2. Depth profiling analysis of solar wind helium collected in diamond-like carbon film from Genesis

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bajo, Ken-ichi; Olinger, Chad T.; Jurewicz, Amy J.G.; Burnett, Donald S.; Sakaguchi, Isao; Suzuki, Taku; Itose, Satoru; Ishihara, Morio; Uchino, Kiichiro; Wieler, Rainer; et al

    2015-10-01

    The distribution of solar-wind ions in Genesis mission collectors, as determined by depth profiling analysis, constrains the physics of ion solid interactions involving the solar wind. Thus, they provide an experimental basis for revealing ancient solar activities represented by solar-wind implants in natural samples. We measured the first depth profile of ⁴He in a collector; the shallow implantation (peaking at <20 nm) required us to use sputtered neutral mass spectrometry with post-photoionization by a strong field. The solar wind He fluence calculated using depth profiling is ~8.5 x 10¹⁴ cm⁻². The shape of the solar wind ⁴He depth profile ismore » consistent with TRIM simulations using the observed ⁴He velocity distribution during the Genesis mission. It is therefore likely that all solar-wind elements heavier than H are completely intact in this Genesis collector and, consequently, the solar particle energy distributions for each element can be calculated from their depth profiles. Ancient solar activities and space weathering of solar system objects could be quantitatively reproduced by solar particle implantation profiles.« less

  3. A Simple Empirical Equation to Calculate Cloud Optical Thickness from Shortwave Broadband Measurements

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Simple Empirical Equation to Calculate Cloud Optical Thickness from Shortwave Broadband Measurements J. C. Barnard and C. N. Long Pacific Northwest National Laboratory Richland, Washington Introduction Observational studies of shortwave cloud optical thickness, c , play an important role in determining how clouds affect climate. Accordingly, considerable effort has been, and continues to be expended to characterize the spatial and temporal distribution of c over the globe. This effort involves

  4. Compression of 1-mm-thick M9763 cellular silicone foam under lateral

    Office of Scientific and Technical Information (OSTI)

    confinement (Technical Report) | SciTech Connect Compression of 1-mm-thick M9763 cellular silicone foam under lateral confinement Citation Details In-Document Search Title: Compression of 1-mm-thick M9763 cellular silicone foam under lateral confinement Abstract not provided. Authors: Small, W. [1] + Show Author Affiliations Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States) Publication Date: 2014-11-13 OSTI Identifier: 1183540 Report Number(s): LLNL-TR--667442 DOE

  5. Bandgap Engineering of InP QDs Through Shell Thickness and Composition

    Office of Scientific and Technical Information (OSTI)

    (Conference) | SciTech Connect Bandgap Engineering of InP QDs Through Shell Thickness and Composition Citation Details In-Document Search Title: Bandgap Engineering of InP QDs Through Shell Thickness and Composition Fields as diverse as biological imaging and telecommunications utilize the unique photophysical and electronic properties of nanocrystal quantum dots (NQDs). The development of new NQD compositions promises material properties optimized for specific applications, while addressing

  6. LINKING Ly? AND LOW-IONIZATION TRANSITIONS AT LOW OPTICAL DEPTH

    SciTech Connect (OSTI)

    Jaskot, A. E.; Oey, M. S.

    2014-08-20

    We suggest that low optical depth in the Lyman continuum (LyC) may relate the Ly? emission, C II and Si II absorption, and C II* and Si II* emission seen in high-redshift galaxies. We base this analysis on Hubble Space Telescope Cosmic Origins Spectrograph spectra of four Green Pea (GP) galaxies, which may be analogs of z > 2 Ly? emitters (LAEs). In the two GPs with the strongest Ly? emission, the Ly? line profiles show reduced signs of resonant scattering. Instead, the Ly? profiles resemble the H? line profiles of evolved star ejecta, suggesting that the Ly? emission originates from a low column density and similar outflow geometry. The weak C II absorption and presence of non-resonant C II* emission in these GPs support this interpretation and imply a low LyC optical depth along the line of sight. In two additional GPs, weak Ly? emission and strong C II absorption suggest a higher optical depth. These two GPs differ in their Ly? profile shapes and C II* emission strengths, however, indicating different inclinations of the outflows to our line of sight. With these four GPs as examples, we explain the observed trends linking Ly?, C II, and C II* in stacked LAE spectra, in the context of optical depth and geometric effects. Specifically, in some galaxies with strong Ly? emission, a low LyC optical depth may allow Ly? to escape with reduced scattering. Furthermore, C II absorption, C II* emission, and Ly? profile shape can reveal the optical depth, constrain the orientation of neutral outflows in LAEs, and identify candidate LyC emitters.

  7. ToF-SIMS Depth Profiling Of Insulating Samples, Interlaced Mode Or Non-interlaced Mode?

    SciTech Connect (OSTI)

    Wang, Zhaoying; Jin, Ke; Zhang, Yanwen; Wang, Fuyi; Zhu, Zihua

    2014-11-01

    Dual beam depth profiling strategy has been widely adopted in ToF-SIMS depth profiling, in which two basic operation modes, interlaced mode and non-interlaced mode, are commonly used. Generally, interlaced mode is recommended for conductive or semi-conductive samples, whereas non-interlaced mode is recommended for insulating samples, where charge compensation can be an issue. Recent publications, however, show that the interlaced mode can be used effectively for glass depth profiling, despite the fact that glass is an insulator. In this study, we provide a simple guide for choosing between interlaced mode and non-interlaced mode for insulator depth profiling. Two representative cases are presented: (1) depth profiling of a leached glass sample, and (2) depth profiling of a single crystal MgO sample. In brief, the interlaced mode should be attempted first, because (1) it may provide reasonable-quality data, and (2) it is time-saving for most cases, and (3) it introduces low H/C/O background. If data quality is the top priority and measurement time is flexible, non-interlaced mode is recommended because interlaced mode may suffer from low signal intensity and poor mass resolution. A big challenge is tracking trace H/C/O in a highly insulating sample (e.g., MgO), because non-interlaced mode may introduce strong H/C/O background but interlaced mode may suffer from low signal intensity. Meanwhile, a C or Au coating is found to be very effective to improve the signal intensity. Surprisingly, the best analyzing location is not on the C or Au coating, but at the edge (outside) of the coating.

  8. Soil temperature, soil moisture and thaw depth, Barrow, Alaska, Ver. 1

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Sloan, V.L.; J.A. Liebig; M.S. Hahn; J.B. Curtis; J.D. Brooks; A. Rogers; C.M. Iversen; R.J. Norby

    2014-01-10

    This dataset consists of field measurements of soil properties made during 2012 and 2013 in areas A-D of Intensive Site 1 at the Next-Generation Ecosystem Experiments (NGEE) Arctic site near Barrow, Alaska. Included are i) weekly measurements of thaw depth, soil moisture, presence and depth of standing water, and soil temperature made during the 2012 and 2013 growing seasons (June - September) and ii) half-hourly measurements of soil temperature logged continuously during the period June 2012 to September 2013.

  9. In-Depth: Cleantech at the National Labs | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    In-Depth: Cleantech at the National Labs In-Depth: Cleantech at the National Labs January 7, 2014 - 5:30pm Addthis These solar power collection dishes at Sandia National Labs' National Solar Thermal Test Facility are capable of some of the highest solar to electricity conversion. In January 2008, this technology set a new solar-to-grid system conversion efficiency record of 31.25 percent net efficiency rate; the technology is still available to benefit the U.S. by delivering power at all hours

  10. Depth-dependent ordering, two-length-scale phenomena, and crossover

    Office of Scientific and Technical Information (OSTI)

    behavior in a crystal featuring a skin layer with defects (Journal Article) | SciTech Connect Depth-dependent ordering, two-length-scale phenomena, and crossover behavior in a crystal featuring a skin layer with defects Citation Details In-Document Search Title: Depth-dependent ordering, two-length-scale phenomena, and crossover behavior in a crystal featuring a skin layer with defects Structural defects in a crystal are responsible for the ''two-length-scale'' behavior in which a sharp

  11. Soil temperature, soil moisture and thaw depth, Barrow, Alaska, Ver. 1

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Sloan, V.L.; J.A. Liebig; M.S. Hahn; J.B. Curtis; J.D. Brooks; A. Rogers; C.M. Iversen; R.J. Norby

    This dataset consists of field measurements of soil properties made during 2012 and 2013 in areas A-D of Intensive Site 1 at the Next-Generation Ecosystem Experiments (NGEE) Arctic site near Barrow, Alaska. Included are i) weekly measurements of thaw depth, soil moisture, presence and depth of standing water, and soil temperature made during the 2012 and 2013 growing seasons (June - September) and ii) half-hourly measurements of soil temperature logged continuously during the period June 2012 to September 2013.

  12. Method and apparatus for ultrasonic characterization through the thickness direction of a moving web

    DOE Patents [OSTI]

    Jackson, Theodore; Hall, Maclin S.

    2001-01-01

    A method and apparatus for determining the caliper and/or the ultrasonic transit time through the thickness direction of a moving web of material using ultrasonic pulses generated by a rotatable wheel ultrasound apparatus. The apparatus includes a first liquid-filled tire and either a second liquid-filled tire forming a nip or a rotatable cylinder that supports a thin moving web of material such as a moving web of paper and forms a nip with the first liquid-filled tire. The components of ultrasonic transit time through the tires and fluid held within the tires may be resolved and separately employed to determine the separate contributions of the two tire thicknesses and the two fluid paths to the total path length that lies between two ultrasonic transducer surfaces contained within the tires in support of caliper measurements. The present invention provides the benefit of obtaining a transit time and caliper measurement at any point in time as a specimen passes through the nip of rotating tires and eliminates inaccuracies arising from nonuniform tire circumferential thickness by accurately retaining point-to-point specimen transit time and caliper variation information, rather than an average obtained through one or more tire rotations. Morever, ultrasonic transit time through the thickness direction of a moving web may be determined independent of small variations in the wheel axle spacing, tire thickness, and liquid and tire temperatures.

  13. Thick adherent dielectric films on plastic substrates and method for depositing same

    DOE Patents [OSTI]

    Wickboldt, Paul (Walnut Creek, CA); Ellingboe, Albert R. (Fremont, CA); Theiss, Steven D. (Woodbury, MN); Smith, Patrick M. (San Ramon, CA)

    2002-01-01

    Thick adherent dielectric films deposited on plastic substrates for use as a thermal barrier layer to protect the plastic substrates from high temperatures which, for example, occur during laser annealing of layers subsequently deposited on the dielectric films. It is desirable that the barrier layer has properties including: a thickness of 1 .mu.m or greater, adheres to a plastic substrate, does not lift-off when cycled in temperature, has few or no cracks and does not crack when subjected to bending, resistant to lift-off when submersed in fluids, electrically insulating and preferably transparent. The thick barrier layer may be composed, for example, of a variety of dielectrics and certain metal oxides, and may be deposited on a variety of plastic substrates by various known deposition techniques. The key to the method of forming the thick barrier layer on the plastic substrate is maintaining the substrate cool during deposition of the barrier layer. Cooling of the substrate maybe accomplished by the use of a cooling chuck on which the plastic substrate is positioned, and by directing cooling gas, such as He, Ar and N.sub.2, between the plastic substrate and the cooling chucks. Thick adherent dielectric films up to about 5 .mu.m have been deposited on plastic substrates which include the above-referenced properties, and which enable the plastic substrates to withstand laser processing temperatures applied to materials deposited on the dielectric films.

  14. Possibility of using cylindrical ionization chambers for percent depth-dose measurements in clinical electron beams

    SciTech Connect (OSTI)

    Ono, Takeshi; Araki, Fujio; Yoshiyama, Fumiaki

    2011-08-15

    Purpose: This study investigated the possibility of using cylindrical ionization chambers for percent depth-dose (PDD) measurements in high-energy clinical electron beams. Methods: The cavity correction factor, P{sub cav}, for cylindrical chambers with various diameters was calculated as a function of depth from the surface to R{sub 50}, in the energy range of 6-18 MeV electrons with the EGSnrc C ++ -based user-code CAVITY. The results were compared with those for IBA NACP-02 and PTW Roos parallel-plate ionization chambers. The effective point of measurement (EPOM) for the cylindrical chamber and the parallel-plate chamber was positioned according to the IAEA TRS-398 code of practice. The overall correction factor, P{sub Q}, and the percent depth-ionization (PDI) curve for a PTW30013 Farmer-type chamber were also compared with those of NACP-02 and Roos chambers. Results: The P{sub cav} values at depths between the surface and R{sub 50} for cylindrical chambers were all lower than those with parallel-plate chambers. However, the variation in depth for cylindrical chambers equal to or less than 4 mm in diameter was equivalent to or smaller than that for parallel-plate chambers. The P{sub Q} values for the PTW30013 chamber mainly depended on P{sub cav}, and for parallel-plate chambers depended on the wall correction factor, P{sub wall}, rather than P{sub cav}. P{sub Q} at depths from the surface to R{sub 50} for the PTW30013 chamber was consequently a lower value than that with parallel-plate chambers. However, the variation in depth was equivalent to that of parallel-plate chambers at electron energies equal to or greater than 9 MeV. The shift to match calculated PDI curves for the PTW30013 chamber and water (perturbation free) varied from 0.65 to 0 mm between 6 and 18 MeV beams. Similarly, the shifts for NACP-02 and Roos chambers were 0.5-0.6 mm and 0.2-0.3 mm, respectively, and were nearly independent of electron energy. Conclusions: Calculated PDI curves for PTW30013, NACP-02, and Roos chambers agreed well with that of water by using the optimal EPOM. Therefore, the possibility of using cylindrical ionization chambers can be expected for PDD measurements in clinical electron beams.

  15. Thickness-dependent metal-insulator transition in epitaxial SrRuO? ultrathin films

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shen, Xuan; Qiu, Xiangbiao; Su, Dong; Zhou, Shengqiang; Li., Aidong; Wu, Di

    2015-01-06

    Transport characteristics of ultrathin SrRuO? films, deposited epitaxially on TiO?-terminated SrTiO? (001) single-crystal substrates, were studied as a function of film thickness. Evolution from a metallic to an insulating behavior is observed as the film thickness decreases from 20 to 4 unit cells. In films thicker than 4 unit cells, the transport behavior obeys the Drude low temperature conductivity with quantum corrections, which can be attributed to weak localization. Fitting the data with 2-dimensional localization model indicates that electron-phonon collisions are the main inelastic relaxation mechanism. In the film of 4 unit cells in thickness, the transport behavior follows variablemorerange hopping model, indicating a strongly localized state. Magnetoresistance measurements reveal a likely magnetic anisotropy with the magnetic easy axis along the out-of-plane direction.less

  16. Tuning the thickness of electrochemically grafted layers in large area molecular junctions

    SciTech Connect (OSTI)

    Fluteau, T.; Bessis, C.; Barraud, C. Della Rocca, M. L.; Lafarge, P.; Martin, P.; Lacroix, J.-C.

    2014-09-21

    We have investigated the thickness, the surface roughness, and the transport properties of oligo(1-(2-bisthienyl)benzene) (BTB) thin films grafted on evaporated Au electrodes, thanks to a diazonium-based electro-reduction process. The thickness of the organic film is tuned by varying the number of electrochemical cycles during the growth process. Atomic force microscopy measurements reveal the evolution of the thickness in the range of 227 nm. Its variation displays a linear dependence with the number of cycles followed by a saturation attributed to the insulating behavior of the organic films. Both ultrathin (2 nm) and thin (12 and 27 nm) large area BTB-based junctions have then been fabricated using standard CMOS processes and finally electrically characterized. The electronic responses are fully consistent with a tunneling barrier in case of ultrathin BTB film whereas a pronounced rectifying behavior is reported for thicker molecular films.

  17. Investigation of damage behavior of thermally sprayed coatings depending on coating thickness

    SciTech Connect (OSTI)

    Crostack, H.A.; Beller, U.

    1995-12-31

    In order to increase the lifetime of components used for diesel engines or gas turbines surfaces are coated by ceramics. In recent years it succeeded in spraying thermal barrier coatings based on zirconia up to a thickness of a few millimeters. A comparison of the damage behavior between yttria partially stabilized zirconia coatings with different thickness will be presented. The coatings are produced by atmospheric plasma spraying. The thickness is varied from 0.5 mm up to 2 mm. In order to characterize the mechanical as well as the damage processes different methods of destructive testing (tensile, bending, and loading test) are applied. Additionally, non-destructive testing methods were used to investigate the damage processes on micro structural level. The results will be discussed according to the microstructure.

  18. Thickness-dependent metal-insulator transition in epitaxial SrRuO3 ultrathin films

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shen, Xuan; Qiu, Xiangbiao; Su, Dong; Zhou, Shengqiang; Li, Aidong; Wu, Di

    2015-01-06

    Transport characteristics of ultrathin SrRuO₃ films, deposited epitaxially on TiO₂-terminated SrTiO₃ (001) single-crystal substrates, were studied as a function of film thickness. Evolution from a metallic to an insulating behavior is observed as the film thickness decreases from 20 to 4 unit cells. In films thicker than 4 unit cells, the transport behavior obeys the Drude low temperature conductivity with quantum corrections, which can be attributed to weak localization. Fitting the data with 2-dimensional localization model indicates that electron-phonon collisions are the main inelastic relaxation mechanism. In the film of 4 unit cells in thickness, the transport behavior follows variablemore » range hopping model, indicating a strongly localized state. As a result, magnetoresistance measurements reveal a likely magnetic anisotropy with the magnetic easy axis along the out-of-plane direction.« less

  19. Physicochemical controls on absorbed water film thickness in unsaturated geological media

    SciTech Connect (OSTI)

    Tokunaga, T.

    2011-06-14

    Adsorbed water films commonly coat mineral surfaces in unsaturated soils and rocks, reducing flow and transport rates. Therefore, it is important to understand how adsorbed film thickness depends on matric potential, surface chemistry, and solution chemistry. Here, the problem of adsorbed water film thickness is examined through combining capillary scaling with the Derjaguin-Landau-Verwey-Overbeek (DLVO) theory. Novel aspects of this analysis include determining capillary influences on film thicknesses, and incorporating solution chemistry-dependent electrostatic potential at air-water interfaces. Capillary analysis of monodisperse packings of spherical grains provided estimated ranges of matric potentials where adsorbed films are stable, and showed that pendular rings within drained porous media retain most of the 'residual' water except under very low matric potentials. Within drained pores, capillary contributions to thinning of adsorbed films on spherical grains are shown to be small, such that DLVO calculations for flat surfaces are suitable approximations. Hamaker constants of common soil minerals were obtained to determine ranges of the dispersion component to matric potential-dependent film thickness. The pressure component associated with electrical double layer forces was estimated using the compression and linear superposition approximations. The pH-dependent electrical double layer pressure component is the dominant contribution to film thicknesses at intermediate values of matric potential, especially in lower ionic strength solutions (< 10 mol m{sup -3}) on surfaces with higher magnitude electrostatic potentials (more negative than - 50 mV). Adsorbed water films are predicted to usually range in thickness from 1 to 20 nm in drained pores and fractures of unsaturated environments.

  20. Method and apparatus for determining diameter and wall thickness of minute hollow spherical shells

    DOE Patents [OSTI]

    Steinman, D.A.

    1980-05-30

    Method and apparatus for determining diameter and wall thickness of hollow microspheres or shells wherein terminal velocities of shells traveling in fluid-filled conduits of differing diameters are measured. A wall-effect factor is determined as a ratio of the terminal velocities, and shell outside diameter may then be ascertained as a predetermined empirical function of wall-effect factor. For shells of known outside diameter, wall thickness may then be ascertained as a predetermined empirical function of terminal velocity in either conduit.

  1. Nanoscale selective area growth of thick, dense, uniform, In-rich, InGaN

    Office of Scientific and Technical Information (OSTI)

    nanostructure arrays on GaN/sapphire template (Journal Article) | SciTech Connect Nanoscale selective area growth of thick, dense, uniform, In-rich, InGaN nanostructure arrays on GaN/sapphire template Citation Details In-Document Search Title: Nanoscale selective area growth of thick, dense, uniform, In-rich, InGaN nanostructure arrays on GaN/sapphire template Authors: Sundaram, S. [1] ; Puybaret, R. [2] ; El Gmili, Y. [1] ; Li, X. [2] ; Bonanno, P. L. [1] ; Pantzas, K. [3] Search SciTech

  2. The NuSTAR View of Nearby Compton-thick Active Galactic Nuclei: The Cases

    Office of Scientific and Technical Information (OSTI)

    of NGC 424, NGC 1320, and IC 2560 (Journal Article) | SciTech Connect SciTech Connect Search Results Journal Article: The NuSTAR View of Nearby Compton-thick Active Galactic Nuclei: The Cases of NGC 424, NGC 1320, and IC 2560 Citation Details In-Document Search Title: The NuSTAR View of Nearby Compton-thick Active Galactic Nuclei: The Cases of NGC 424, NGC 1320, and IC 2560 Authors: Balokovic, M. ; /Caltech ; Comastri, A. ; /Bologna Observ. ; Harrison, F.A. ; /Caltech ; Alexander, D.M. ;

  3. The NuSTAR View of Nearby Compton-thick Active Galactic Nuclei: The Cases

    Office of Scientific and Technical Information (OSTI)

    of NGC 424, NGC 1320, and IC 2560 (Journal Article) | SciTech Connect The NuSTAR View of Nearby Compton-thick Active Galactic Nuclei: The Cases of NGC 424, NGC 1320, and IC 2560 Citation Details In-Document Search Title: The NuSTAR View of Nearby Compton-thick Active Galactic Nuclei: The Cases of NGC 424, NGC 1320, and IC 2560 × You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This site is a product of DOE's Office of Scientific and Technical Information

  4. Aqueous Synthesis of Zinc Blende CdTe/CdS Magic-Core/Thick-Shell

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tetrahedral Shaped Nanocrystals with Emission Tunable to Near-Infrared Aqueous Synthesis of Zinc Blende CdTe/CdS Magic-Core/Thick-Shell Tetrahedral Shaped Nanocrystals with Emission Tunable to Near-Infrared Authors: Deng, Z., Schulz, O., Lin, S., Ding, B., Liu, X., Wei, X., Ros, R., Liu, Y., Yan, H., and Francis, M. Title: Aqueous Synthesis of Zinc Blende CdTe/CdS Magic-Core/Thick-Shell Tetrahedral Shaped Nanocrystals with Emission Tunable to Near-Infrared Source: Journal of the American

  5. Ferroelectric PLZT thick films grown by poly(1-vinylpyrrolidone-co-vinyl

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    acetate) (PVP/VA)-modified sol-gel process | Argonne National Laboratory Ferroelectric PLZT thick films grown by poly(1-vinylpyrrolidone-co-vinyl acetate) (PVP/VA)-modified sol-gel process Title Ferroelectric PLZT thick films grown by poly(1-vinylpyrrolidone-co-vinyl acetate) (PVP/VA)-modified sol-gel process Publication Type Journal Article Year of Publication 2016 Authors Hu, Z, Ma, B, Li, M, Koritala, RE, Balachandran, U Journal Materials Research Bulletin Volume 75 Start Page 167

  6. Thick-shell nanocrystal quantum dots (Patent) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Patent: Thick-shell nanocrystal quantum dots Citation Details In-Document Search Title: Thick-shell nanocrystal quantum dots Colloidal nanocrystal quantum dots comprising an inner core having an average diameter of at least 1.5 nm and an outer shell, where said outer shell comprises multiple monolayers, wherein at least 30% of the quantum dots have an on-time fraction of 0.80 or greater under continuous excitation conditions for a period of time of at least 10 minutes. Authors: Hollingsworth,

  7. Thickness-dependent coherent phonon frequency in ultrathin FeSe/SrTiO3

    Office of Scientific and Technical Information (OSTI)

    films (Journal Article) | SciTech Connect Thickness-dependent coherent phonon frequency in ultrathin FeSe/SrTiO3 films Citation Details In-Document Search Title: Thickness-dependent coherent phonon frequency in ultrathin FeSe/SrTiO3 films Ultrathin FeSe films grown on SrTiO3 substrates are a recent milestone in atomic material engineering due to their important role in understanding unconventional superconductivity in Fe-based materials. By using femtosecond time- and angle-resolved

  8. Method and apparatus for determining diameter and wall thickness of minute hollow spherical shells

    DOE Patents [OSTI]

    Steinman, David A. (Ann Arbor, MI)

    1982-01-01

    Method and apparatus for determining diameter and wall thickness of hollow microspheres or shells wherein terminal velocities of shells traveling in fluid-filled conduits of differing diameters are measured. A wall-effect factor is determined as a ratio of the terminal velocities, and shell outside diameter may then be ascertained as a predetermined empirical function of wall-effect factor. For shells of known outside diameter, wall thickness may then be ascertained as a predetermined empirical function of terminal velocity in either conduit.

  9. Resistive switching in a few nanometers thick tantalum oxide film formed by a metal oxidation

    SciTech Connect (OSTI)

    Ohno, Takeo; Samukawa, Seiji

    2015-04-27

    Resistive switching in a Cu/Ta{sub 2}O{sub 5}/Pt structure that consisted of a few nanometer-thick Ta{sub 2}O{sub 5} film was demonstrated. The Ta{sub 2}O{sub 5} film with thicknesses of 25?nm was formed with a combination of Ta metal film deposition and neutral oxygen particle irradiation at room temperature. The device exhibited a bipolar resistive switching with a threshold voltage of 0.2?V and multilevel switching operation.

  10. Systems and methods that generate height map models for efficient three dimensional reconstruction from depth information

    DOE Patents [OSTI]

    Frahm, Jan-Michael; Pollefeys, Marc Andre Leon; Gallup, David Robert

    2015-12-08

    Methods of generating a three dimensional representation of an object in a reference plane from a depth map including distances from a reference point to pixels in an image of the object taken from a reference point. Weights are assigned to respective voxels in a three dimensional grid along rays extending from the reference point through the pixels in the image based on the distances in the depth map from the reference point to the respective pixels, and a height map including an array of height values in the reference plane is formed based on the assigned weights. An n-layer height map may be constructed by generating a probabilistic occupancy grid for the voxels and forming an n-dimensional height map comprising an array of layer height values in the reference plane based on the probabilistic occupancy grid.

  11. Effect of Ion Skin Depth on Relaxation of Merging Spheromaks to a Field-Reversed Configuration

    SciTech Connect (OSTI)

    Kawamori, Eiichirou; Ono, Yasushi

    2005-08-19

    The effect of ion skin depth on the relaxation of merging spheromaks to a field-reversed configuration (FRC) is studied experimentally for a wide range of size parameter S* (ratio of minor radius to ion skin depth) from 1 to 7. The two merging spheromaks are observed to relax to an FRC or a new spheromak depending on whether the initial poloidal eigenvalue is smaller or larger than a threshold value. The bifurcation value is found to increase with decreasing size parameter S{sup *}, indicating that the low-S* condition provides a wide bifurcated range of relaxation to an FRC. The FRC-style relaxation under the low-S* conditions was accompanied by the suppression of the low-n modes (n is the toroidal mode number) activity. The fast rotations of the modes were followed by suppression of the low-n modes.

  12. Tsunami and acoustic-gravity waves in water of constant depth

    SciTech Connect (OSTI)

    Hendin, Gali; Stiassnie, Michael

    2013-08-15

    A study of wave radiation by a rather general bottom displacement, in a compressible ocean of otherwise constant depth, is carried out within the framework of a three-dimensional linear theory. Simple analytic expressions for the flow field, at large distance from the disturbance, are derived. Realistic numerical examples indicate that the Acoustic-Gravity waves, which significantly precede the Tsunami, are expected to leave a measurable signature on bottom-pressure records that should be considered for early detection of Tsunami.

  13. Small-angle Compton Scattering to Determine the Depth of a Radioactive Source in Matter

    SciTech Connect (OSTI)

    Oberer, R. B.; Gunn, C. A.; Chiang, L. G.; Valiga, R. E.; Cantrell, J. A.

    2011-04-01

    A gamma-ray peak in a spectrum is often accompanied by a discontinuity in the Compton continuum at the peak. The Compton continuum results from Compton scattering in the detector. The discontinuity at a peak results from small-angle Compton scattering by the gamma rays in matter situated directly between the gamma-ray source and the detector. The magnitude of this discontinuity with respect to the gamma-ray peak is therefore an indicator of the amount of material or shielding between the gamma-ray source and the detector. This small-angle scattering was used to determine the depth of highly-enriched uranium (HEU) solution standards in a concrete floor mockup. The empirical results of the use of this small-angle scattering discontinuity in a concrete floor experiment will be described. A Monte Carlo calculation of the experiment will also be described. In addition, the depth determined from small-angle scattering was used in conjunction with differential attenuation to more accurately measure the uranium content of the mockup. Following these empirical results, the theory of small-angle scattering will be discussed. The magnitude of the discontinuity compared to the peak count rate is directly related to the depth of the gamma-ray source in matter. This relation can be described by relatively simple mathematical expressions. This is the first instance that we are aware of in which the small-angle Compton scattering has been used to determine the depth of a radioactive source. Furthermore this is the first development of the theoretical expressions for the magnitude of the small-angle scattering discontinuity.

  14. DOE/SC-ARM/TR-129 Aerosol Optical Depth Value-Added Product

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    9 Aerosol Optical Depth Value-Added Product A Koontz C Flynn G Hodges J Michalsky J Barnard March 2013 DISCLAIMER This report was prepared as an account of work sponsored by the U.S. Government. Neither the United States nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use

  15. Evaluation of the Effective Moisture Penetration Depth Model for Estimating Moisture Buffering in Buildings

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Evaluation of the Effective Moisture Penetration Depth Model for Estimating Moisture Buffering in Buildings J. Woods, J. Winkler, and D. Christensen National Renewable Energy Laboratory Technical Report NREL/TP-5500-57441 January 2013 NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency & Renewable Energy, operated by the Alliance for Sustainable Energy, LLC. National Renewable Energy Laboratory 15013 Denver West Parkway Golden, Colorado 80401

  16. NREL Takes First In-Depth Look at Solar Project Completion Timelines - News

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Releases | NREL Takes First In-Depth Look at Solar Project Completion Timelines Report examines new data to show how long the PV interconnection process takes in the U.S. February 11, 2015 The Energy Department's National Renewable Energy Laboratory (NREL) has gathered and analyzed data for more than 30,000 solar photovoltaic (PV) installations across the United States to better understand how interconnection regulations align with actual project completion timelines. The findings indicate

  17. High-pressure structure made of rings with peripheral weldments of reduced thickness

    DOE Patents [OSTI]

    Leventry, Samuel C.

    1988-01-01

    A high-pressure structure having a circular cylindrical metal shell made of metal rings joined together by weldments and which have peripheral areas of reduced shell thickness at the weldments which permit a reduction in the amount of weld metal deposited while still maintaining sufficient circumferential or hoop stress strength.

  18. Temperature effects on failure thickness and deflagration-to-detonation transition in PBX 9502 and TATB

    SciTech Connect (OSTI)

    Asay, B.W.; McAfee, J.B.

    1993-01-01

    The deflagration-to-detonation (DDT) behavior of TATB has been investigated at high temperatures and severe confinement. comparison is made to other common explosives under similar confinement. TATB did not DDT under these conditions. The failure thickness of PBX 9502 at 250[degrees]C has also been determined. Two mm appears to be the limiting value at this temperature.

  19. Temperature effects on failure thickness and deflagration-to-detonation transition in PBX 9502 and TATB

    SciTech Connect (OSTI)

    Asay, B.W.; McAfee, J.B.

    1993-04-01

    The deflagration-to-detonation (DDT) behavior of TATB has been investigated at high temperatures and severe confinement. comparison is made to other common explosives under similar confinement. TATB did not DDT under these conditions. The failure thickness of PBX 9502 at 250{degrees}C has also been determined. Two mm appears to be the limiting value at this temperature.

  20. Characterization of thick 4H-SiC hot-wall CVD layers

    SciTech Connect (OSTI)

    Paisley, M.J.; Irvine, K.G.; Kordina, O.; Singh, R.; Palmour, J.W.; Carter, C.H. Jr.

    1999-07-01

    Epitaxial 4H-SiC layers suitable for high power devices have been grown in a hot-wall chemical-vapor deposition (CVD) system. These layers were subsequently characterized for many parameters important in device development and production. The uniformity of both thickness and doping is presented. Doping trends vs. temperature and growth rate is shown for the p-type dopant used. The n-type dopant drops in concentration with increasing temperature or increasing growth rate. In contrast, the p-type dopant increases in concentration with decreasing temperature or increasing growth rate. A simple descriptive model for this behavior is presented. The outcome from capacitance-voltage and SIMS measurements demonstrate that transitions from n to n{sup {minus}}, or p to p{sup {minus}}, and even n to p levels can be made quickly without adjustment to growth conditions. The ability to produce sharp transitions without process changes avoids degrading the resulting surface morphology or repeatability of the process. Avoiding process changes is particularly important in growth of thick layers since surface roughness tends to increase with layer thickness. Device results from diodes producing two different blocking voltages in excess of 5 kV is also shown. The higher voltage diodes exhibited a breakdown behavior which was near the theoretical limit for the epitaxial layer thickness and doping level grown.

  1. Thermal Conductivity Measurement of Xe-Implanted Uranium Dioxide Thick Films using Multilayer Laser Flash Analysis

    SciTech Connect (OSTI)

    Nelson, Andrew T.

    2012-08-30

    The Fuel Cycle Research and Development program's Advanced Fuels campaign is currently pursuing use of ion beam assisted deposition to produce uranium dioxide thick films containing xenon in various morphologies. To date, this technique has provided materials of interest for validation of predictive fuel performance codes and to provide insight into the behavior of xenon and other fission gasses under extreme conditions. In addition to the structural data provided by such thick films, it may be possible to couple these materials with multilayer laser flash analysis in order to measure the impact of xenon on thermal transport in uranium dioxide. A number of substrate materials (single crystal silicon carbide, molybdenum, and quartz) containing uranium dioxide films ranging from one to eight microns in thickness were evaluated using multilayer laser flash analysis in order to provide recommendations on the most promising substrates and geometries for further investigation. In general, the uranium dioxide films grown to date using ion beam assisted deposition were all found too thin for accurate measurement. Of the substrates tested, molybdenum performed the best and looks to be the best candidate for further development. Results obtained within this study suggest that the technique does possess the necessary resolution for measurement of uranium dioxide thick films, provided the films are grown in excess of fifty microns. This requirement is congruent with the material needs when viewed from a fundamental standpoint, as this length scale of material is required to adequately sample grain boundaries and possible second phases present in ceramic nuclear fuel.

  2. STARSPOTS-TRANSIT DEPTH RELATION OF THE EVAPORATING PLANET CANDIDATE KIC 12557548b

    SciTech Connect (OSTI)

    Kawahara, Hajime; Kurosaki, Kenji; Ito, Yuichi; Ikoma, Masahiro; Hirano, Teruyuki

    2013-10-10

    Violent variation of transit depths and an ingress-egress asymmetry of the transit light curve discovered in KIC 12557548 have been interpreted as evidence of a catastrophic evaporation of atmosphere with dust ( M-dot {sub p}?>1 M{sub ?} Gyr{sup 1}) from a close-in small planet. To explore what drives the anomalous atmospheric escape, we perform time-series analysis of the transit depth variation of Kepler archival data for ?3.5 yr. We find a ?30% periodic variation of the transit depth with P {sub 1} = 22.83 0.21 days, which is within the error of the rotation period of the host star estimated using the light curve modulation, P {sub rot} = 22.91 0.24 days. We interpret the results as evidence that the atmospheric escape of KIC 12557548b correlates with stellar activity. We consider possible scenarios that account for both the mass loss rate and the correlation with stellar activity. X-ray and ultraviolet (XUV)-driven evaporation is possible if one accepts a relatively high XUV flux and a high efficiency for converting the input energy to the kinetic energy of the atmosphere. Star-planet magnetic interaction is another possible scenario, though huge uncertainty remains for the mass loss rate.

  3. Method for the depth corrected detection of ionizing events from a co-planar grids sensor

    DOE Patents [OSTI]

    De Geronimo, Gianluigi (Syosset, NY); Bolotnikov, Aleksey E. (South Setauket, NY); Carini, Gabriella (Port Jefferson, NY)

    2009-05-12

    A method for the detection of ionizing events utilizing a co-planar grids sensor comprising a semiconductor substrate, cathode electrode, collecting grid and non-collecting grid. The semiconductor substrate is sensitive to ionizing radiation. A voltage less than 0 Volts is applied to the cathode electrode. A voltage greater than the voltage applied to the cathode is applied to the non-collecting grid. A voltage greater than the voltage applied to the non-collecting grid is applied to the collecting grid. The collecting grid and the non-collecting grid are summed and subtracted creating a sum and difference respectively. The difference and sum are divided creating a ratio. A gain coefficient factor for each depth (distance between the ionizing event and the collecting grid) is determined, whereby the difference between the collecting electrode and the non-collecting electrode multiplied by the corresponding gain coefficient is the depth corrected energy of an ionizing event. Therefore, the energy of each ionizing event is the difference between the collecting grid and the non-collecting grid multiplied by the corresponding gain coefficient. The depth of the ionizing event can also be determined from the ratio.

  4. Report on the Depth Requirements for a Massive Detector at Homestake

    SciTech Connect (OSTI)

    Bernstein,A.; Blucher, E.; Cline, D. B.; Diwan, M. V.; Fleming, b.; Kadel, R.; Kearns, E.; Klein, J.; Lande, K.; Lanni, F.; Lissauer, D.; McKeown, R.; Morse, W.; Radeika, R.; Scholberg, K.; Smy, M.; Sobel, H.; Sullivan, G.; Svoboda, R.; Vagins, M.; Walter, C.; Zwaska, R.

    2008-12-22

    This report provides the technical justification for locating a large detector underground in a US based Deep Underground Science and Engineering Laboratory. A large detector with a fiducial mass greater than 100 kTon will most likely be a multipurpose facility. The main physics justification for such a device is detection of accelerator generated neutrinos, nucleon decay, and natural sources of neutrinos such as solar, atmospheric and supernova neutrinos. The requirement on the depth of this detector will be guided by the rate of signals from these sources and the rate of backgrounds from cosmic rays over a very wide range of energies (from solar neutrino energies of 5 MeV to high energies in the range of tens of GeV). For the present report, we have examined the depth requirement for a large water Cherenkov detector and a liquid argon time projection chamber. There has been extensive previous experience with underground water Cherenkov detectors such as IMB, Kamioka, and most recently, Super-Kamiokande which has a fiducial mass of 22 kTon and a total mass of 50 kTon at a depth of 2700 meters-water-equivalent. Projections for signal and background capability for a larger and deeper (or shallower) detectors of this type can be scaled from these previous detectors. The liquid argon time projection chamber has the advantage of being a very fine-grained tracking detector, which provides enhanced capability for background rejection. In the current work we have taken the approach that the depth should be sufficient to suppress the cosmogenic background below predicted signal rates for either of the above two technologies. Nevertheless, it is also clear that the underground facility that we are examining must have a long life and will most likely be used either for future novel uses of the currently planned detectors or new technologies. Therefore the depth requirement also needs to be made on the basis of sound judgment regarding possible future use. In particular, the depth should be sufficient for any possible future use of these cavities or the level which will be developed for these large structures. Along with these physics justifications there are practical issues regarding the existing infrastructure at Homestake and also the stress characteristics of the Homestake rock formations. In this report we will examine the various depth choices at Homestake from the point of view of the particle and nuclear physics signatures of interest. We also have sufficient information about the existing infrastructure and the rock characteristics to narrow the choice of levels for the development of large cavities with long lifetimes. We make general remarks on desirable ground conditions for such large cavities and then make recommendations on how to start examining these levels to make a final choice. In the appendix we have outlined the initial requirements for the detectors. These requirements will undergo refinement during the course of the design. Finally, we strongly recommend that the geotechnical studies be commenced at the 4850 ft level, which we find to be the most suitable, in a timely manner.

  5. Report on the Depth Requirements for a Massive Detector at Homestake

    SciTech Connect (OSTI)

    Kadel, Richard W.; Bernstein, Adam; Blucher, Edward; Cline, David B.; Diwan, Milind V.; Fleming, Bonnie; Kearns, Edward; Klein, Joshua; Lande, Kenneth; Lanni, Francesco; Lissauer, David; McKeown, Robert; Morse, William; Rameika, Regina; Scholberg, Kate; Smy, Michael; Sobel, Henry; Sullivan, Gregory; Svoboda, Robert; Vagins, Mark; Walter, Christopher; Zwaska, Robert

    2008-12-23

    This report provides the technical justification for locating a large detector underground in a US based Deep Underground Science and Engineering Laboratory. A large detector with a fiducial mass greater than 100 kTon will most likely be a multipurpose facility. The main physics justification for such a device is detection of accelerator generated neutrinos, nucleon decay, and natural sources of neutrinos such as solar, atmospheric and supernova neutrinos. The requirement on the depth of this detector will be guided by the rate of signals from these sources and the rate of backgrounds from cosmic rays over a very wide range of energies (from solar neutrino energies of 5 MeV to high energies in the range of hundreds of GeV). For the present report, we have examined the depth requirement for a large water Cherenkov detector and a liquid argon time projection chamber. There has been extensive previous experience with underground water Cherenkov detectors such as IMB, Kamioka, and most recently, Super-Kamiokande which has a fiducial mass of 22 kTon and a total mass of 50 kTon at a depth of 2700 meters-water-equivalent in a mountain. Projections for signal and background capability for a larger and deeper(or shallower) detectors of this type can be scaled from these previous detectors. The liquid argon time projection chamber has the advantage of being a very fine-grained tracking detector, which should provide enhanced capability for background rejection. We have based background rejection on reasonable estimates of track and energy resolution, and in some cases scaled background rates from measurements in water. In the current work we have taken the approach that the depth should be sufficient to suppress the cosmogenic background below predicted signal rates for either of the above two technologies. Nevertheless, it is also clear that the underground facility that we are examining must have a long life and will most likely be used either for future novel uses of the currently planned detectors or new technologies. Therefore the depth requirement also needs to be made on the basis of sound judgment regarding possible future use. In particular, the depth should be sufficient for any possible future use of these cavities or the level which will be developed for these large structures.Along with these physics justifications there are practical issues regarding the existing infrastructure at Homestake and also the stress characteristics of the Homestake rock formations. In this report we will examine the various depth choices at Homestake from the point of view of the particle and nuclear physics signatures of interest. We also have sufficient information about the existing infrastructure and the rock characteristics to narrow the choice of levels for the development of large cavities with long lifetimes. We make general remarks on desirable ground conditions for such large cavities and then make recommendations on how to start examining these levels to make a final choice. In the appendix we have outlined the initial requirements for the detectors. These requirements will undergo refinement during the course of the design. Finally, we strongly recommend that the geotechnical studies be commenced at the 4850 ft level, which we find to be the most suitable, in a timely manner.

  6. Thickness independent reduced forming voltage in oxygen engineered HfO{sub 2} based resistive switching memories

    SciTech Connect (OSTI)

    Sharath, S. U. Kurian, J.; Komissinskiy, P.; Hildebrandt, E.; Alff, L.; Bertaud, T.; Walczyk, C.; Calka, P.; Schroeder, T.

    2014-08-18

    The conducting filament forming voltage of stoichiometric hafnium oxide based resistive switching layers increases linearly with layer thickness. Using strongly reduced oxygen deficient hafnium oxide thin films grown on polycrystalline TiN/Si(001) substrates, the thickness dependence of the forming voltage is strongly suppressed. Instead, an almost constant forming voltage of about 3?V is observed up to 200?nm layer thickness. This effect suggests that filament formation and switching occurs for all samples in an oxidized HfO{sub 2} surface layer of a few nanometer thickness while the highly oxygen deficient thin film itself merely serves as a oxygen vacancy reservoir.

  7. SU-E-I-53: Variation in Measurements of Breast Skin Thickness Obtained Using Different Imaging Modalities

    SciTech Connect (OSTI)

    Nguyen, U; Kumaraswamy, N; Markey, M

    2014-06-01

    Purpose: To investigate variation in measurements of breast skin thickness obtained using different imaging modalities, including mammography, computed tomography (CT), ultrasound, and magnetic resonance imaging (MRI). Methods: Breast skin thicknesses as measured by mammography, CT, ultrasound, and MRI were compared. Mammographic measurements of skin thickness were obtained from published studies that utilized standard positioning (upright) and compression. CT measurements of skin thickness were obtained from a published study of a prototype breast CT scanner in which the women were in the prone position and the breast was uncompressed. Dermatological ultrasound exams of the breast skin were conducted at our institution, with the subjects in the upright position and the breast uncompressed. Breast skin thickness was calculated from breast MRI exams at our institution, with the patient in the prone position and the breast uncompressed. Results: T tests for independent samples demonstrated significant differences in the mean breast skin thickness as measured by different imaging modalities. Repeated measures ANOVA revealed significant differences in breast skin thickness across different quadrants of the breast for some modalities. Conclusion: The measurement of breast skin thickness is significantly different across different imaging modalities. Differences in the amount of compression and differences in patient positioning are possible reasons why measurements of breast skin thickness vary by modality.

  8. Observed damage during Argon gas cluster depth profiles of compound semiconductors

    SciTech Connect (OSTI)

    Barlow, Anders J. Portoles, Jose F.; Cumpson, Peter J.

    2014-08-07

    Argon Gas Cluster Ion Beam (GCIB) sources have become very popular in XPS and SIMS in recent years, due to the minimal chemical damage they introduce in the depth-profiling of polymer and other organic materials. These GCIB sources are therefore particularly useful for depth-profiling polymer and organic materials, but also (though more slowly) the surfaces of inorganic materials such as semiconductors, due to the lower roughness expected in cluster ion sputtering compared to that introduced by monatomic ions. We have examined experimentally a set of five compound semiconductors, cadmium telluride (CdTe), gallium arsenide (GaAs), gallium phosphide (GaP), indium arsenide (InAs), and zinc selenide (ZnSe) and a high-? dielectric material, hafnium oxide (HfO), in their response to argon cluster profiling. An experimentally determined HfO etch rate of 0.025?nm/min (3.95??10{sup ?2}?amu/atom in ion) for 6?keV Ar gas clusters is used in the depth scale conversion for the profiles of the semiconductor materials. The assumption has been that, since the damage introduced into polymer materials is low, even though sputter yields are high, then there is little likelihood of damaging inorganic materials at all with cluster ions. This seems true in most cases; however, in this work, we report for the first time that this damage can in fact be very significant in the case of InAs, causing the formation of metallic indium that is readily visible even to the naked eye.

  9. Results of Hg speciation testing on tanks 30, 32, and 37 depth samples

    SciTech Connect (OSTI)

    Bannochie, C. J.

    2015-11-30

    The Savannah River National Laboratory (SRNL) was tasked with preparing and shipping samples for Hg speciation by Eurofins Frontier Global Sciences, Inc. in Seattle, WA on behalf of the Savannah River Remediation (SRR) Mercury Task Team. The twelfth shipment of samples was designated to include 3H evaporator system Tank 30, 32, and 37 depth samples. The Tank 30 depth sample (HTF-30-15-70) was taken at 190 inches from the tank bottom and the Tank 32 depth sample (HTF-32-15-68) was taken at 89 inches from the tank bottom and both were shipped to SRNL on June 29, 2015 in an 80 mL stainless steel dip bottles. The Tank 37 surface sample (HTF-37-15-94) was taken around 253.4 inches from the tank bottom and shipped to SRNL on July 21, 2015 in an 80 mL stainless steel dip bottle. All samples were placed in the SRNL Shielded Cells and left unopened until intermediate dilutions were made on July 24, 2015 using 1.00 mL of sample diluted to 100.00 mL with deionized H2O. A 30 mL Teflon bottle was rinsed twice with the diluted tank sample and then filled leaving as little headspace as possible. It was immediately removed from the Shielded Cells and transferred to refrigerated storage where it remained at 4 C until final dilutions were made on October 20. A second portion of the cells diluted tank sample was poured into a shielded polyethylene bottle and transferred to Analytical Development for radiochemical analysis data needed for Hazardous Material Transportation calculations.

  10. Method for rapid, controllable growth and thickness, of epitaxial silicon films

    DOE Patents [OSTI]

    Wang, Qi; Stradins, Paul; Teplin, Charles; Branz, Howard M.

    2009-10-13

    A method of producing epitaxial silicon films on a c-Si wafer substrate using hot wire chemical vapor deposition by controlling the rate of silicon deposition in a temperature range that spans the transition from a monohydride to a hydrogen free silicon surface in a vacuum, to obtain phase-pure epitaxial silicon film of increased thickness is disclosed. The method includes placing a c-Si substrate in a HWCVD reactor chamber. The method also includes supplying a gas containing silicon at a sufficient rate into the reaction chamber to interact with the substrate to deposit a layer containing silicon thereon at a predefined growth rate to obtain phase-pure epitaxial silicon film of increased thickness.

  11. Post-cast EDM method for reducing the thickness of a turbine nozzle wall

    DOE Patents [OSTI]

    Jones, Raymond Joseph (Duanesburg, NY); Bojappa, Parvangada Ganapathy (Schenectady, NY); Kirkpatrick, Francis Lawrence (Galway, NY); Schotsch, Margaret Jones (Clifton Park, NY); Rajan, Rajiv (Guilderland, NY); Wei, Bin (Mechanicville, NY)

    2002-01-01

    A post-cast EDM process is used to remove material from the interior surface of a nozzle vane cavity of a turbine. A thin electrode is passed through the cavity between opposite ends of the nozzle vane and displaced along the interior nozzle wall to remove the material along a predetermined path, thus reducing the thickness of the wall between the cavity and the external surface of the nozzle. In another form, an EDM process employing a profile as an electrode is disposed in the cavity and advanced against the wall to remove material from the wall until the final wall thickness is achieved, with the interior wall surface being complementary to the profile surface.

  12. Ferroelectric polymer-ceramic composite thick films for energy storage applications

    SciTech Connect (OSTI)

    Singh, Paritosh; Borkar, Hitesh; Singh, B. P.; Singh, V. N.; Kumar, Ashok

    2014-08-15

    We have successfully fabricated large area free standing polyvinylidene fluoride -Pb(Zr{sub 0.52}Ti{sub 0.48})O{sub 3} (PVDF-PZT) ferroelectric polymer-ceramic composite (wt% 8020, respectively) thick films with an average diameter (d) ?0.1 meter and thickness (t) ?50 ?m. Inclusion of PZT in PVDF matrix significantly enhanced dielectric constant (from 10 to 25 at 5 kHz) and energy storage capacity (from 11 to 14 J/cm{sup 3}, using polarization loops), respectively, and almost similar leakage current and mechanical strength. Microstructural analysis revealed the presence of ? and ? crystalline phases and homogeneous distribution of PZT crystals in PVDF matrix. It was also found that apart from the microcrystals, well defined naturally developed PZT nanocrystals were embedded in PVDF matrix. The observed energy density indicates immense potential in PVDF-PZT composites for possible applications as green energy and power density electronic elements.

  13. Neutron-skin thickness from the study of the anti-analog giant dipole resonance

    SciTech Connect (OSTI)

    Krasznahorkay, A.; Stuhl, L.; Csatlos, M.; Algora, A.; and others

    2012-10-20

    The {gamma}-decay of the anti-analog of the giant dipole resonance (AGDR) to the isobaric analog state has been measured following the p({sup 124}Sn,n) reaction at a beam energy of 600 MeV/nucleon. The energy of the transition was also calculated with state-of-the-art self-consistent relativistic random-phase approximation (RPA) and turned out to be very sensitive to the neutronskin thickness ({Delta}R{sub pn}). By comparing the theoretical results with the measured one, the {Delta}R{sub pn} value for {sup 124}Sn was deduced to be 0.21 {+-} 0.07 fm, which agrees well with the previous results. The present method offers new possibilities for measuring the neutron-skin thicknesses of very exotic isotopes.

  14. Effects of catalyst film thickness on plasma-enhanced carbon nanotube growth

    SciTech Connect (OSTI)

    Hofmann, S.; Cantoro, M.; Kleinsorge, B.; Casiraghi, C.; Parvez, A.; Robertson, J.; Ducati, C.

    2005-08-01

    A systematic study is presented of the influence of catalyst film thickness on carbon nanostructures grown by plasma-enhanced chemical-vapor deposition from acetylene and ammonia mixtures. We show that reducing the Fe/Co catalyst film thickness below 3 nm causes a transition from larger diameter (>40 nm), bamboolike carbon nanofibers to small diameter ({approx}5 nm) multiwalled nanotubes with two to five walls. This is accompanied by a more than 50 times faster growth rate and a faster catalyst poisoning. Thin Ni catalyst films only trigger such a growth transition when pretreated with an ammonia plasma. We observe a limited correlation between this growth transition and the coarsening of the catalyst film before deposition. For a growth temperature of {<=}550 deg. C, all catalysts showed mainly a tip growth regime and a similar activity on untreated silicon, oxidized silicon, and silicon nitride support.

  15. Thick, low-stress films, and coated substrates formed therefrom, and methods for making same

    DOE Patents [OSTI]

    Henager, Jr., Charles H. (Kennewick, WA); Knoll, Robert W. (Menomonee Falls, WI)

    1992-01-01

    Stress-induced deformation, and the damage resulting therefrom, increases with film thickness. The overcoming of excessive stress by the use of the Si-Al-N film material of the present invention, permits the formation of thick films that are necessary for certain of the above described applications. The most likely use for the subject film materials, other than their specialized views as an optical film, is for microelectronic packaging of components on silicon substrates. In general, the subject films have excellent adherence to the underlying substrate, a high degree of hardness and durability, and are excellent insulators. Prior art elevated temperature deposition processes cannot meet the microelectronic packaging temperature formation constraints. The process of the present invention is conducted under non-elevated temperature conditions, typically 500.degree. C. or less.

  16. Fermion resonances on a thick brane with a piecewise warp factor

    SciTech Connect (OSTI)

    Li Haitao; Liu Yuxiao; Zhao Zhenhua; Guo Heng

    2011-02-15

    In this paper, we mainly investigate the problems of resonances of massive Kaluza-Klein (KK) fermions on a single scalar constructed thick brane with a piecewise warp factor matching smoothly. The distance between two boundaries and the other parameters are determined by one free parameter through three junction conditions. For the generalized Yukawa coupling {eta}{Psi}{phi}{sup k{Psi}} with odd k=1,3,5,..., the mass eigenvalue m, width {Gamma}, lifetime {tau}, and maximal probability P{sub max} of fermion resonances are obtained. Our numerical calculations show that the brane without internal structure also favors the appearance of resonant states for both left- and right-handed fermions. The scalar-fermion coupling and the thickness of the brane influence the resonant behaviors of the massive KK fermions.

  17. Evaluation of the Effective Moisture Penetration Depth Model for Estimating Moisture Buffering in Buildings

    SciTech Connect (OSTI)

    Woods, J.; Winkler, J.; Christensen, D.

    2013-01-01

    This study examines the effective moisture penetration depth (EMPD) model, and its suitability for building simulations. The EMPD model is a compromise between the simple, inaccurate effective capacitance approach and the complex, yet accurate, finite-difference approach. Two formulations of the EMPD model were examined, including the model used in the EnergyPlus building simulation software. An error in the EMPD model we uncovered was fixed with the release of EnergyPlus version 7.2, and the EMPD model in earlier versions of EnergyPlus should not be used.

  18. Apparatus for in-situ calibration of instruments that measure fluid depth

    DOE Patents [OSTI]

    Campbell, M.D.

    1994-01-11

    The present invention provides a method and apparatus for in-situ calibration of distance measuring equipment. The method comprises obtaining a first distance measurement in a first location, then obtaining at least one other distance measurement in at least one other location of a precisely known distance from the first location, and calculating a calibration constant. The method is applied specifically to calculating a calibration constant for obtaining fluid level and embodied in an apparatus using a pressure transducer and a spacer of precisely known length. The calibration constant is used to calculate the depth of a fluid from subsequent single pressure measurements at any submerged position. 8 figures.

  19. Apparatus for in-situ calibration of instruments that measure fluid depth

    DOE Patents [OSTI]

    Campbell, Melvin D. (Richland, WA)

    1994-01-01

    The present invention provides a method and apparatus for in-situ calibration of distance measuring equipment. The method comprises obtaining a first distance measurement in a first location, then obtaining at least one other distance measurement in at least one other location of a precisely known distance from the first location, and calculating a calibration constant. The method is applied specifically to calculating a calibration constant for obtaining fluid level and embodied in an apparatus using a pressure transducer and a spacer of precisely known length. The calibration constant is used to calculate the depth of a fluid from subsequent single pressure measurements at any submerged position.

  20. Unique Challenges Accompany Thick-Shell CdSe/nCdS (n > 10) Nanocrystal Synthesis

    SciTech Connect (OSTI)

    Guo, Y; Marchuk, K; Abraham, R; Sampat, S; Abraham, R.; Fang, N; Malko, AV; Vela, J

    2011-12-23

    Thick-shell CdSe/nCdS (n {ge} 10) nanocrystals were recently reported that show remarkably suppressed fluorescence intermittency or 'blinking' at the single-particle level as well as slow rates of Auger decay. Unfortunately, whereas CdSe/nCdS nanocrystal synthesis is well-developed up to n {le} 6 CdS monolayers (MLs), reproducible syntheses for n {ge} 10 MLs are less understood. Known procedures sometimes result in homogeneous CdS nucleation instead of heterogeneous, epitaxial CdS nucleation on CdSe, leading to broad and multimodal particle size distributions. Critically, obtained core/shell sizes are often below those desired. This article describes synthetic conditions specific to thick-shell growth (n {ge} 10 and n {ge} 20 MLs) on both small (sub2 nm) and large (>4.5 nm) CdSe cores. We find added secondary amine and low concentration of CdSe cores and molecular precursors give desired core/shell sizes. Amine-induced, partial etching of CdSe cores results in apparent shell-thicknesses slightly beyond those desired, especially for very-thick shells (n {ge} 20 MLs). Thermal ripening and fast precursor injection lead to undesired homogeneous CdS nucleation and incomplete shell growth. Core/shells derived from small CdSe (1.9 nm) have longer PL lifetimes and more pronounced blinking at single-particle level compared with those derived from large CdSe (4.7 nm). We expect our new synthetic approach will lead to a larger throughput of these materials, increasing their availability for fundamental studies and applications.

  1. Thickness effects on the plastic collapse of perforated plates with triangular penetration patterns

    SciTech Connect (OSTI)

    Gordon, J.L.; Jones, D.P.; Holliday, J.E.

    2000-03-01

    This paper investigates the effects of plate thickness on the accuracy of limit load solutions obtained using an elastic-perfectly plastic [EPP] equivalent solid [EQS] procedure for flat perforated plates with a triangular array of penetrations. The EQS approach for limit loads is based on an EQS collapse surface that is valid for generalized plane strain. This assumption is applicable for very thick plates but is known to be less reasonable for very thin plates where plane stress may be a better assumption. The limits of applicability of the generalized plane strain assumption are investigated by obtaining limit load solutions for perforated plates of various thicknesses that are subjected to in-plane and bending loads. Plastic limit load solutions obtained using three-dimensional EPP finite element analysis [FEA] of models which include each penetration explicitly are compared with solutions obtained using the EQS approximation. The penetration pattern chosen for this study has a ligament efficiency (ligament width-to-pitch ratio, h/P) of 0.32. For plates thicker than the pitch, the limit load calculated using the EQS method for both in-plane and bending loads is shown to be very accurate (within 4%) of the limit load calculated for the explicit model. On the other hand, for thin plates (t/P< 2), the EQS limit load is 5% greater than the explicit limit load for bending and 8% greater than the explicit limit load for in-plane loads. For thinner plates, the collapse surface is tied to the local geometry deformation and, hence, an equivalent solid plate representation of plastic collapse is a function of deformation mode and thickness.

  2. Weakly nonlinear Rayleigh-Taylor instability of a finite-thickness fluid layer

    SciTech Connect (OSTI)

    Wang, L. F. Ye, W. H. Liu, Jie; He, X. T.; Guo, H. Y.; Wu, J. F. Zhang, W. Y.

    2014-12-15

    A weakly nonlinear (WN) model has been developed for the Rayleigh-Taylor instability of a finite-thickness incompressible fluid layer (slab). We derive the coupling evolution equations for perturbations on the (upper) “linearly stable” and (lower) “linearly unstable” interfaces of the slab. Expressions of temporal evolutions of the amplitudes of the perturbation first three harmonics on the upper and lower interfaces are obtained. The classical feedthrough (interface coupling) solution obtained by Taylor [Proc. R. Soc. London A 201, 192 (1950)] is readily recovered by the first-order results. Our third-order model can depict the WN perturbation growth and the saturation of linear (exponential) growth of the perturbation fundamental mode on both interfaces. The dependence of the WN perturbation growth and the slab distortion on the normalized layer thickness (kd) is analytically investigated via the third-order solutions. Comparison is made with Jacobs-Catton's formula [J. W. Jacobs and I. Catton, J. Fluid Mech. 187, 329 (1988)] of the position of the “linearly unstable” interface. Using a reduced formula, the saturation amplitude of linear growth of the perturbation fundamental mode is studied. It is found that the finite-thickness effects play a dominant role in the WN evolution of the slab, especially when kd < 1. Thus, it should be included in applications where the interface coupling effects are important, such as inertial confinement fusion implosions and supernova explosions.

  3. Assessment of the single-pass thick-seam longwall mining method. Final report

    SciTech Connect (OSTI)

    Adam, R.F.J.; Douglas, W.J.

    1982-04-01

    The objectives of the project are a review of the foreign experiences in longwall mining of thick seams, an evaluation of the US thick seam reserves, a mine design, equipment specifications, and an economic study for longwall mining in a single pass up to 16 feet in US conditions. The review of foreign experience shows a steady increase in the maximum height of extraction with several examples in the range of 13 to 15 feet. Longwall face equipment is available up to an 18 feet height of extraction, based upon shields support and shearer loader. There are important reserves of thick coal seams which can be mined by a longwall in a single pass (125 billion tons). In US conditions, a retreating face with a 16 foot height of extraction and a double entry system, driven 10 feet high, are proposed. The face stability can be improved by using a two bench face cut in good geological conditions. The economic study compares longwall mining with the room-and-pillar method. Longwall mining 16 feet high coal in a single pass can compete advantageously with room-and-pillar mining. 74 figures, 14 tables.

  4. The effect of mix on capsule yields as a function of shell thickness and gas fill

    SciTech Connect (OSTI)

    Bradley, P. A.

    2014-06-15

    An investigation of direct drive capsules with different shell thicknesses and gas fills was conducted to examine the amount of shock induced (Richtmyer-Meshkov) mix versus Rayleigh-Taylor mix from deceleration of the implosion. The RAGE (Eulerian) code with a turbulent mix model was used to model these capsules for neutron yields along with time-dependent mix amounts. The amount of Richtmyer-Meshkov induced mix from the shock breaking out of the shell is about 0.1??g (0.15??m of shell material), while the Rayleigh-Taylor mix is of order 1??g and determines the mixed simulation yield. The simulations were able to calculate a yield over mix (YOM) ratio (experiment/mix simulation) between 0.5 and 1.0 for capsules with shell thicknesses ranging from 7.5 to 20??m and with gas fills between 3.8 and 20?atm of D{sub 2} or DT. The simulated burn averaged T{sub ion} values typically lie with 0.5?keV of the data, which is within the measurement error. For capsules with shell thicknesses >25??m, the YOM values drop to 0.10??0.05, suggesting that some unmodeled effect needs to be accounted for in the thickest capsules.

  5. Dynamic mask for producing uniform or graded-thickness thin films

    DOE Patents [OSTI]

    Folta, James A. (Livermore, CA)

    2006-06-13

    A method for producing single layer or multilayer films with high thickness uniformity or thickness gradients. The method utilizes a moving mask which blocks some of the flux from a sputter target or evaporation source before it deposits on a substrate. The velocity and position of the mask is computer controlled to precisely tailor the film thickness distribution. The method is applicable to any type of vapor deposition system, but is particularly useful for ion beam sputter deposition and evaporation deposition; and enables a high degree of uniformity for ion beam deposition, even for near-normal incidence of deposition species, which may be critical for producing low-defect multilayer coatings, such as required for masks for extreme ultraviolet lithography (EUVL). The mask can have a variety of shapes, from a simple solid paddle shape to a larger mask with a shaped hole through which the flux passes. The motion of the mask can be linear or rotational, and the mask can be moved to make single or multiple passes in front of the substrate per layer, and can pass completely or partially across the substrate.

  6. Effect of Substrate Thickness on Oxide Scale Spallation for Solid Oxide Fuel Cells

    SciTech Connect (OSTI)

    Liu, Wenning N.; Sun, Xin; Stephens, Elizabeth V.; Khaleel, Mohammad A.

    2011-07-01

    In this paper, the effect of the ferritic substrate's thickness on the delamination/spallation of the oxide scale was investigated experimentally and numerically. At the high-temperature oxidation environment of solid oxide fuel cells (SOFCs), a combination of growth stress with thermal stresses may lead to scale delamination/buckling and eventual spallation during SOFC stack cooling, even leading to serious degradation of cell performance. The growth stress is induced by the growth of the oxide scale on the scale/substrate interface, and thermal stress is induced by a mismatch of the coefficient of thermal expansion between the oxide scale and the substrate. The numerical results show that the interfacial shear stresses, which are the driving force of scale delamination between the oxide scale and the ferritic substrate, increase with the growth of the oxide scale and also with the thickness of the ferritic substrate; i.e., the thick ferritic substrate can easily lead to scale delamination and spallation. Experimental observation confirmed the predicted results of the delamination and spallation of the oxide scale on the ferritic substrate.

  7. MULTIPLICITY OF NOVA ENVELOPE SOLUTIONS AND OCCURRENCE OF OPTICALLY THICK WINDS

    SciTech Connect (OSTI)

    Kato, Mariko; Hachisu, Izumi E-mail: hachisu@ea.c.u-tokyo.ac.jp

    2009-07-10

    We revisit the occurrence condition of optically thick winds reported by Kato in 1985 and Kato and Hachisu in 1989 who mathematically examined nova envelope solutions with an old opacity and found that optically thick winds are accelerated only in massive white dwarfs (WDs) of {approx}>0.9 M{sub sun}. With the OPAL opacity we find that the optically thick wind occurs for {approx}>0.6 M{sub sun} WDs and that the occurrence of winds depends not only on the WD mass but also on the ignition mass. When the ignition mass is larger than a critical value, winds are suppressed by a density-inversion layer. Such a static solution can be realized in WDs of mass {approx}0.6-0.7 M{sub sun}. We propose that sequences consisting only of static solutions correspond to slow evolutions in symbiotic novae like PU Vul because PU Vul shows no indication of strong winds in a long-lasted flat peak followed by a very slow decline in its light curve.

  8. Thickness controlled sol-gel silica films for plasmonic bio-sensing devices

    SciTech Connect (OSTI)

    Figus, Cristiana Quochi, Francesco Artizzu, Flavia Saba, Michele Marongiu, Daniela Mura, Andrea; Bongiovanni, Giovanni; Floris, Francesco; Marabelli, Franco; Patrini, Maddalena; Fornasari, Lucia; Pellacani, Paola; Valsesia, Andrea

    2014-10-21

    Plasmonics has recently received considerable interest due to its potentiality in many fields as well as in nanobio-technology applications. In this regard, various strategies are required for modifying the surfaces of plasmonic nanostructures and to control their optical properties in view of interesting application such as bio-sensing, We report a simple method for depositing silica layers of controlled thickness on planar plasmonic structures. Tetraethoxysilane (TEOS) was used as silica precursor. The control of the silica layer thickness was obtained by optimizing the sol-gel method and dip-coating technique, in particular by properly tuning different parameters such as pH, solvent concentration, and withdrawal speed. The resulting films were characterized via atomic force microscopy (AFM), Fourier-transform (FT) spectroscopy, and spectroscopic ellipsometry (SE). Furthermore, by performing the analysis of surface plasmon resonances before and after the coating of the nanostructures, it was observed that the position of the resonance structures could be properly shifted by finely controlling the silica layer thickness. The effect of silica coating was assessed also in view of sensing applications, due to important advantages, such as surface protection of the plasmonic structure.

  9. Electroplated L1{sub 0} CoPt thick-film permanent magnets

    SciTech Connect (OSTI)

    Oniku, Ololade D. Qi, Bin; Arnold, David P.

    2014-05-07

    The fabrication and magnetic characterization of 15-?m-thick electroplated L1{sub 0} CoPt hard magnets with good magnetic properties is reported in this paper. Experimental study of the dependence of the magnets' properties on annealing temperature reveals that an intrinsic coercivity H{sub ci}?=??800?kA/m (10 kOe), squareness >0.8, and energy product of >150?kJ/m{sup 3} are obtained for photolithographically patterned structures (250??m??2?mm stripes; 15??m thickness) electroplated on silicon substrates and annealed in hydrogen forming gas at 700?C. Scanning electron microscopy is used to inspect the morphology of both the as-deposited and annealed magnetic layers, and X-ray Diffractometer analysis on the magnets annealed at 700?C confirm a phase transformation to an ordered L1{sub 0} CoPt structure, with a minor phase of hcp Co. These thick films are intended for microsystems/MEMS applications.

  10. An in-depth longitudinal analysis of mixing patterns in a small scientific collaboration network

    SciTech Connect (OSTI)

    Rodriguez, Marko A [Los Alamos National Laboratory; Pepe, Alberto [UCLA

    2009-01-01

    Many investigations of scientific collaboration are based on large-scale statistical analyses of networks constructed from bibliographic repositories. These investigations often rely on a wealth of bibliographic data, but very little or no other information about the individuals in the network, and thus, fail to illustate the broader social and academic landscape in which collaboration takes place. In this article, we perform an in-depth longitudinal analysis of a small-scale network of scientific collaboration (N = 291) constructed from the bibliographic record of a research center involved in the development and application of sensor network technologies. We perform a preliminary analysis of selected structural properties of the network, computing its range, configuration and topology. We then support our preliminary statistical analysis with an in-depth temporal investigation of the assortativity mixing of these node characteristics: academic department, affiliation, position, and country of origin of the individuals in the network. Our qualitative analysis of mixing patterns offers clues as to the nature of the scientific community being modeled in relation to its organizational, disciplinary, institutional, and international arrangements of collaboration.

  11. Device and method for the measurement of depth of interaction using co-planar electrodes

    DOE Patents [OSTI]

    DeGeronimo, Gianluigi (Syosset, NY)

    2007-09-18

    A device and method for measuring a depth of interaction of an ionizing event and improving resolution of a co-planar grid sensor (CPG) are provided. A time-of-occurrence is measured using a comparator to time the leading edge of the event pulse from the non-collecting or collecting grid. A difference signal between the grid signals obtained with a differential amplifier includes a pulse with a leading edge occurring at the time-of-detection, measured with another comparator. A timing difference between comparator outputs corresponds to the depth of interaction, calculated using a processor, which in turn weights the difference grid signal to improve spectral resolution of a CPG sensor. The device, which includes channels for grid inputs, may be integrated into an Application Specific Integrated Circuit. The combination of the device and sensor is included. An improved high-resolution CPG is provided, e.g., a gamma-ray Cadmium Zinc Telluride CPG sensor operating at room temperature.

  12. Migration depths of adult steelhead Oncorhynchus mykiss in relation to dissolved gas supersaturation in a regulated river system

    SciTech Connect (OSTI)

    Johnson, Eric L.; Clabough, Tami S.; Caudill, Christopher C.; keefer, matthew L.; Peery, Christopher A.; Richmond, Marshall C.

    2010-04-01

    Adult steelhead tagged with archival transmitters primarily migrated through a large river corridor at depths > 2 m, interspersed with frequent but short (< 5 min) periods closer to the surface. The recorded swimming depths and behaviours probably provided adequate hydrostatic compensation for the encountered supersaturated dissolved gas conditions and probably limited development of gas bubble disease (GBD). Results parallel those from a concurrent adult Chinook salmon study, except steelhead experienced greater seasonal variability and were more likely to have depth-uncompensated supersaturation exposure in some dam tailraces, perhaps explaining the higher incidence of GBD in this species.

  13. Source Parameters for Moderate Earthquakes in the Zagros Mountains with Implications for the Depth Extent of Seismicity

    SciTech Connect (OSTI)

    Adams, A; Brazier, R; Nyblade, A; Rodgers, A; Al-Amri, A

    2009-02-23

    Six earthquakes within the Zagros Mountains with magnitudes between 4.9 and 5.7 have been studied to determine their source parameters. These events were selected for study because they were reported in open catalogs to have lower crustal or upper mantle source depths and because they occurred within an area of the Zagros Mountains where crustal velocity structure has been constrained by previous studies. Moment tensor inversion of regional broadband waveforms have been combined with forward modeling of depth phases on short period teleseismic waveforms to constrain source depths and moment tensors. Our results show that all six events nucleated within the upper crust (<11 km depth) and have thrust mechanisms. This finding supports other studies that call into question the existence of lower crustal or mantle events beneath the Zagros Mountains.

  14. DETERMINATION OF LIQUID FILM THICKNESS FOLLOWING DRAINING OF CONTACTORS, VESSELS, AND PIPES IN THE MCU PROCESS

    SciTech Connect (OSTI)

    Poirier, M; Fernando Fondeur, F; Samuel Fink, S

    2006-06-06

    The Department of Energy (DOE) identified the caustic side solvent extraction (CSSX) process as the preferred technology to remove cesium from radioactive waste solutions at the Savannah River Site (SRS). As a result, Washington Savannah River Company (WSRC) began designing and building a Modular CSSX Unit (MCU) in the SRS tank farm to process liquid waste for an interim period until the Salt Waste Processing Facility (SWPF) begins operations. Both the solvent and the strip effluent streams could contain high concentrations of cesium which must be removed from the contactors, process tanks, and piping prior to performing contactor maintenance. When these vessels are drained, thin films or drops will remain on the equipment walls. Following draining, the vessels will be flushed with water and drained to remove the flush water. The draining reduces the cesium concentration in the vessels by reducing the volume of cesium-containing material. The flushing, and subsequent draining, reduces the cesium in the vessels by diluting the cesium that remains in the film or drops on the vessel walls. MCU personnel requested that Savannah River National Laboratory (SRNL) researchers conduct a literature search to identify models to calculate the thickness of the liquid films remaining in the contactors, process tanks, and piping following draining of salt solution, solvent, and strip solution. The conclusions from this work are: (1) The predicted film thickness of the strip effluent is 0.010 mm on vertical walls, 0.57 mm on horizontal walls and 0.081 mm in horizontal pipes. (2) The predicted film thickness of the salt solution is 0.015 mm on vertical walls, 0.74 mm on horizontal walls, and 0.106 mm in horizontal pipes. (3) The predicted film thickness of the solvent is 0.022 mm on vertical walls, 0.91 mm on horizontal walls, and 0.13 mm in horizontal pipes. (4) The calculated film volume following draining is: (a) Salt solution receipt tank--1.6 gallons; (b) Salt solution feed tank--1.6 gallons; (c) Decontaminated salt solution hold tank--1.6 gallons; (d) Contactor drain tank--0.40 gallons; (e) Strip effluent hold tank--0.33 gallons; (f) Decontaminated salt solution decanter--0.37 gallons; (g) Strip effluent decanter--0.14 gallons; (h) Solvent hold tank--0.30 gallon; and (i) Corrugated piping between contactors--16-21 mL. (5) After the initial vessel draining, flushing the vessels with 100 gallons of water using a spray nozzle that produces complete vessel coverage and draining the flush water reduces the source term by the following amounts: (i) Salt solution receipt tank--63X; (ii) Salt solution feed tank--63X; (iii) Decontaminated salt solution hold tank--63X; (iv) Contactor drain tank--250X; (v) Strip effluent hold tank--300X; (vi) Decontaminated salt solution decanter--270X; (vii) Strip effluent decanter--710X; (viii) Solvent hold tank--330X. Understand that these estimates of film thickness are based on laboratory testing and fluid mechanics theory. The calculations assume drainage occurs by film flow. Much of the data used to develop the models came from tests with very ''clean'' fluids. Impurities in the fluids and contaminants on the vessels walls could increase liquid holdup. The application of film thickness models and source term reduction calculations should be considered along with operational conditions and H-Tank Farm/Liquid Waste operating experience. These calculations exclude the PVV/HVAC duct work and piping, as well as other areas that area outside the scope of this report.

  15. High-speed non-contact measuring apparatus for gauging the thickness of moving sheet material

    DOE Patents [OSTI]

    Grann, Eric B. (San Ramon, CA); Holcomb, David E. (Oak Ridge, TN)

    2000-01-01

    An optical measurement apparatus is provided for measuring the thickness of a moving sheet material (18). The apparatus has a pair of optical measurement systems (21, 31) attached to opposing surfaces (14, 16) of a rigid support structure (10). A pair of high-power laser diodes (20,30) and a pair of photodetector arrays (22,32) are attached to the opposing surfaces. Light emitted from the laser diodes is reflected off of the sheet material surfaces (17, 19) and received by the respective photodetector arrays. An associated method for implementing the apparatus is also provided.

  16. Asymptotic solution of light transport problems in optically thick luminescent media

    SciTech Connect (OSTI)

    ?ahin-Biryol, Derya Ilan, Boaz

    2014-06-15

    We study light transport in optically thick luminescent random media. Using radiative transport theory for luminescent media and applying asymptotic and computational methods, a corrected diffusion approximation is derived with the associated boundary conditions and boundary layer solution. The accuracy of this approach is verified for a plane-parallel slab problem. In particular, the reduced system models accurately the effect of reabsorption. The impacts of varying the Stokes shift and using experimentally measured luminescence data are explored in detail. The results of this study have application to the design of luminescent solar concentrators, fluorescence medical imaging, and optical cooling using anti-Stokes fluorescence.

  17. Layer thickness dependence of current induced effective fields in ferromagnetic multilayers

    SciTech Connect (OSTI)

    Kawaguchi, M. Moriyama, T.; Ono, T.; Koyama, T.; Chiba, D.

    2015-05-07

    We report the relation between current induced effective fields and ferromagnetic layer thickness. Hall measurements with rotating magnetic field show that the transverse and perpendicular effective fields have linear relations to the inverse of the magnetic moment m per area S. The results imply that both of these effective fields may originate from spin angular momentum transferring. However, the non-zero intercept of the transverse field at m/S = 0 implies that magnetization independent effects, such as Rashba effect, may contribute to transverse field.

  18. 1-nm-thick graphene tri-layer as the ultimate copper diffusion barrier

    SciTech Connect (OSTI)

    Nguyen, Ba-Son [Department of Mechanical Engineering, National Cheng Kung University, 1 University Road, Tainan 701, Taiwan (China); Lin, Jen-Fin [Department of Mechanical Engineering, National Cheng Kung University, 1 University Road, Tainan 701, Taiwan (China); Center for Micro/Nano Science and Technology, National Cheng Kung University, 1 University Road, Tainan 701, Taiwan (China); Perng, Dung-Ching, E-mail: dcperng@ee.ncku.edu.tw [Institute of Microelectronics and Electrical Engineering Department, National Cheng Kung University, 1 University Road, Tainan 701, Taiwan (China); Center for Micro/Nano Science and Technology, National Cheng Kung University, 1 University Road, Tainan 701, Taiwan (China)

    2014-02-24

    We demonstrate the thinnest ever reported Cu diffusion barrier, a 1-nm-thick graphene tri-layer. X-ray diffraction patterns and Raman spectra show that the graphene is thermally stable at up to 750?C against Cu diffusion. Transmission electron microscopy images show that there was no inter-diffusion in the Cu/graphene/Si structure. Raman analyses indicate that the graphene may have degraded into a nanocrystalline structure at 750?C. At 800?C, the perfect carbon structure was damaged, and thus the barrier failed. The results of this study suggest that graphene could be the ultimate Cu interconnect diffusion barrier.

  19. Formation of Thick, Large-Area Nanoparticle Superlatices in Lithographically Defined Geometries

    SciTech Connect (OSTI)

    Akey, A.; Yang, L.; Lu, C.; Herman, I.P.

    2010-03-31

    Superlattices of colloidal nanocrystals hold the promise of new nanomaterials with tunable properties. The positioning and size of these structures are often poorly controlled after self-assembly from the solution phase, making studies of their properties difficult. We report the fabrication of {approx}100 layer thick, three-dimensional superlattices on a substrate with controlled lateral placement. This novel fabrication technique generates long-range order over the micrometer scale and controlled placement by employing lithographic patterning and microfluidic flow. Keywords: Nanoparticles; superlattice; self assembly; microfluidics; ordered array.

  20. Sensitivity of the electric dipole polarizability to the neutron skin thickness in {sup 208}Pb

    SciTech Connect (OSTI)

    Roca-Maza, X.; Agrawal, B. K.; Colo, G.; Nazarewicz, W.; Paar, N.; Piekarewicz, J.; Reinhard, P.-G.; Vretenar, D.

    2012-10-20

    The static dipole polarizability, {alpha}{sub D}, in {sup 208}Pb has been recently measured with highresolution via proton inelastic scattering at the Research Center for Nuclear Physics (RCNP) [1]. This observable is thought to be intimately connected with the neutron skin thickness, r{sub skin}, of the same nucleus and, more fundamentally, it is believed to be associated with the density dependence of the nuclear symmetry energy. The impact of r{sub skin} on {alpha}{sub D} in {sup 208}Pb is investigated and discussed on the basis of a large and representative set of relativistic and non-relativistic nuclear energy density functionals (EDF) [2].

  1. Does aspartic acid racemization constrain the depth limit of the subsurface biosphere?

    SciTech Connect (OSTI)

    Onstott, T. C.; Aubrey, A.D.; Kieft, T L; Silver, B J; Phelps, Tommy Joe; Van Heerden, E.; Opperman, D. J.; Bada, J L.

    2014-01-01

    Previous studies of the subsurface biosphere have deduced average cellular doubling times of hundreds to thousands of years based upon geochemical models. We have directly constrained the in situ average cellular protein turnover or doubling times for metabolically active micro-organisms based on cellular amino acid abundances, D/L values of cellular aspartic acid, and the in vivo aspartic acid racemization rate. Application of this method to planktonic microbial communities collected from deep fractures in South Africa yielded maximum cellular amino acid turnover times of ~89 years for 1 km depth and 27 C and 1 2 years for 3 km depth and 54 C. The latter turnover times are much shorter than previously estimated cellular turnover times based upon geochemical arguments. The aspartic acid racemization rate at higher temperatures yields cellular protein doubling times that are consistent with the survival times of hyperthermophilic strains and predicts that at temperatures of 85 C, cells must replace proteins every couple of days to maintain enzymatic activity. Such a high maintenance requirement may be the principal limit on the abundance of living micro-organisms in the deep, hot subsurface biosphere, as well as a potential limit on their activity. The measurement of the D/L of aspartic acid in biological samples is a potentially powerful tool for deep, fractured continental and oceanic crustal settings where geochemical models of carbon turnover times are poorly constrained. Experimental observations on the racemization rates of aspartic acid in living thermophiles and hyperthermophiles could test this hypothesis. The development of corrections for cell wall peptides and spores will be required, however, to improve the accuracy of these estimates for environmental samples.

  2. Liquid film thickness inside the high pressure swirl injectors: Real scale measurement and evaluation of analytical equations

    SciTech Connect (OSTI)

    Moon, Seoksu; Bae, Choongsik; Abo-Serie, Essam

    2010-02-15

    Liquid film thickness inside two swirl injectors for direct injection (DI) gasoline engines was measured at different injection pressure conditions ranging from 2.0 to 7.0 MPa and then previous analytical and empirical equations were examined from the experimental results. Based on the evaluation, a new equation for the liquid film thickness inside the swirl injectors was introduced. A direct photography using two real scale transparent nozzles and a pulsed light source was employed to measure the liquid film thickness inside the swirl injectors. The error in the liquid film thickness measurement, generated from different refractive indices among transparent nozzle, fuel and air, was estimated and corrected based on the geometric optics. Two injectors which have different nozzle diameter and nozzle length were applied to introduce a more general empirical equation for the liquid film thickness inside the pressure swirl injectors. The results showed that the liquid film thickness remains constant at the injection pressures for direct injection gasoline engines while the ratio of nozzle length to nozzle diameter (L/D) shows significant effect on the liquid film thickness. The previously introduced analytical and empirical equations for relatively low injection pressure swirl injectors overestimated the effect of injection pressure at the operating range of high pressure swirl injectors and, in addition, the effect of L/D ratio and swirler geometry was rarely considered. A new empirical equation was suggested based on the experimental results by taking into account the effects of fuel properties, nozzle diameter, nozzle length and swirler geometry. (author)

  3. Porosity, single-phase permeability, and capillary pressure data from preliminary laboratory experiments on selected samples from Marker Bed 139 at the Waste Isolation Pilot Plant. Volume 1 of 3: Main report, appendix A

    SciTech Connect (OSTI)

    Howarth, S.M.; Christian-Frear, T.

    1997-08-01

    Three groups of core samples from Marker Bed 139 of the Salado Formation at the Waste Isolation Pilot Plant (WIPP) were analyzed to provide data to support the development of numerical models used to predict the long-term hydrologic and structural response of the WIPP repository. These laboratory experiments, part of the FY93 Experimental Scoping Activities of the Salado Two-Phase Flow Laboratory Program, were designed to (1) generate WIPP-specific porosity and single-phase permeability data, (2) provide information needed to design and implement planned tests to measure two-phase flow properties, including threshold pressure, capillary pressure, and relative permeability, and (3) evaluate the suitability of using analog correlations for the Salado Formation to assess the long-term performance of the WIPP. This report contains a description of the boreholes core samples, the core preparation techniques used, sample sizes, testing procedures, test conditions, and results of porosity and single-phase permeability tests performed at three laboratories: TerraTek, Inc. (Salt Lake City, UT), RE/SPEC, Inc. (Rapid City, SD), and Core Laboratories-Special Core Analysis Laboratory (Carrollton, TX) for Rock Physics Associates. In addition, this report contains the only WIPP-specific two-phase-flow capillary-pressure data for twelve core samples. The WIPP-specific data generated in this laboratory study and in WIPP field-test programs and information from suitable analogs will form the basis for specification of single- and two-phase flow parameters for anhydrite markers beds for WIPP performance assessment calculations.

  4. Towards III-V solar cells on Si: Improvement in the crystalline quality of Ge-on-Si virtual substrates through low porosity porous silicon buffer layer and annealing

    SciTech Connect (OSTI)

    Calabrese, Gabriele; Baricordi, Stefano; Bernardoni, Paolo; Fin, Samuele; Guidi, Vincenzo; Vincenzi, Donato

    2014-09-26

    A comparison between the crystalline quality of Ge grown on bulk Si and on a low porosity porous Si (pSi) buffer layer using low energy plasma enhanced chemical vapor deposition is reported. Omega/2Theta coupled scans around the Ge and Si (004) diffraction peaks show a reduction of the Ge full-width at half maximum (FWHM) of 22.4% in presence of the pSi buffer layer, indicating it is effective in improving the epilayer crystalline quality. At the same time atomic force microscopy analysis shows an increase in root means square roughness for Ge grown on pSi from 38.5 nm to 48.0 nm, as a consequence of the larger surface roughness of pSi compared to bulk Si. The effect of 20 minutes vacuum annealing at 580C is also investigated. The annealing leads to a FWHM reduction of 23% for Ge grown on Si and of 36.5% for Ge on pSi, resulting in a FWHM of 101 arcsec in the latter case. At the same time, the RMS roughness is reduced of 8.8% and of 46.5% for Ge grown on bulk Si and on pSi, respectively. The biggest improvement in the crystalline quality of Ge grown on pSi with respect to Ge grown on bulk Si observed after annealing is a consequence of the simultaneous reorganization of the Ge epilayer and the buffer layer driven by energy minimization. A low porosity buffer layer can thus be used for the growth of low defect density Ge on Si virtual substrates for the successive integration of III-V multijunction solar cells on Si. The suggested approach is simple and fast thus allowing for high throughput-, moreover is cost effective and fully compatible with subsequent wafer processing. Finally it does not introduce new chemicals in the solar cell fabrication process and can be scaled to large area silicon wafers.

  5. Thickness-dependent electronlattice equilibration in laser-excited thin bismuth films

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sokolowski-Tinten, K.; Li, R. K.; Reid, A. H.; Weathersby, S. P.; Quirin, F.; Chase, T.; Coffee, R.; Corbett, J.; Fry, A.; Hartmann, N.; et al

    2015-11-19

    Electronphonon coupling processes determine electronic transport properties of materials and are responsible for the transfer of electronic excess energy to the lattice. With decreasing device dimensions an understanding of these processes in nanoscale materials is becoming increasingly important. We use time-resolved electron diffraction to directly study energy relaxation in thin bismuth films after optical excitation. Precise measurements of the transient DebyeWaller-effect for various film thicknesses and over an extended range of excitation fluences allow to separate different contributions to the incoherent lattice response. While phonon softening in the electronically excited state is responsible for an immediate increase of the r.m.s.moreatomic displacement within a few hundred fs, 'ordinary' electronphonon coupling leads to subsequent heating of the material on a few ps time-scale. Moreover, the data reveal distinct changes in the energy transfer dynamics which becomes faster for stronger excitation and smaller film thickness, respectively. The latter effect is attributed to a cross-interfacial coupling of excited electrons to phonons in the substrate.less

  6. Fluid Phase Lipid Areas and Bilayer Thicknesses of Commonly Used Phosphatidylcholines as a Function of Temperature

    SciTech Connect (OSTI)

    Kucerka, Norbert; Nieh, Mu-Ping; Katsaras, John

    2011-01-01

    The structural parameters of fluid phase bilayers composed of phosphatidylcholines with fully saturated, mixed, and branched fatty acid chains, at several temperatures, have been determined by simultaneously analyzing small-angle neutron and X-ray scattering data. Bilayer parameters, such as area per lipid and overall bilayer thickness have been obtained in conjunction with intrabilayer structural parameters (e.g. hydrocarbon region thickness). The results have allowed us to assess the effect of temperature and hydrocarbon chain composition on bilayer structure. For example, we found that for all lipids there is, not surprisingly, an increase in fatty acid chain trans-gauche isomerization with increasing temperature. Moreover, this increase in trans-gauche isomerization scales with fatty acid chain length in mixed chain lipids. However, in the case of lipids with saturated fatty acid chains, trans-gauche isomerization is increasingly tempered by attractive chain-chain van der Waals interactions with increasing chain length. Finally, our results confirm a strong dependence of lipid chain dynamics as a function of double bond position along fatty acid chains.

  7. Spectrum and light curve of a supernova shock breakout through a thick Wolf-Rayet wind

    SciTech Connect (OSTI)

    Svirski, Gilad; Nakar, Ehud

    2014-06-20

    Wolf-Rayet stars are known to eject winds. Thus, when a Wolf-Rayet star explodes as a supernova, a fast (? 40, 000 km s{sup 1}) shock is expected to be driven through a wind. We study the signal expected from a fast supernova shock propagating through an optically thick wind and find that the electrons behind the shock driven into the wind are efficiently cooled by inverse Compton over soft photons that were deposited by the radiation-mediated shock that crossed the star. Therefore, the bolometric luminosity is comparable to the kinetic energy flux through the shock, and the spectrum is found to be a power law, whose slope and frequency range depend on the number flux of soft photons available for cooling. Wolf-Rayet supernovae that explode through a thick wind have a high flux of soft photons, producing a flat spectrum, ?F {sub ?} = Const, in the X-ray range of 0.1 ? T ? 50 keV. As the shock expands into an optically thin wind, the soft photons are no longer able to cool the shock that plows through the wind, and the bulk of the emission takes the form of a standard core-collapse supernova (without a wind). However, a small fraction of the soft photons is upscattered by the shocked wind and produces a transient unique X-ray signature.

  8. Snow Depth and Density at End-of-Winter for NGEE Areas A, B, C and D, Barrow, Alaska, 2012-2014

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Anna Liljedahl; Cathy Wilson

    2016-02-02

    End-of-winter snow depth and average snow density from area A, B, C and D, which include 1000's of point depth measurement located between approximately 20 and 50 cm apart.

  9. Vehicle Technologies Office Merit Review 2015: Thick Low-Cost, High-Power Lithium-Ion Electrodes via Aqueous Processing

    Broader source: Energy.gov [DOE]

    Presentation given by Oak Ridge National Laboratory at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about thick low-cost,...

  10. Final Report - Hydraulic Conductivity with Depth for Underground Test Area (UGTA) Wells

    SciTech Connect (OSTI)

    P. Oberlander; D. McGraw; C. Russell

    2007-10-31

    Hydraulic conductivity with depth has been calculated for Underground Test Area (UGTA) wells in volcanic tuff and carbonate rock. The following wells in volcanic tuff are evaluated: ER-EC-1, ER-EC-2a, ER-EC-4, ER-EC-5, ER-5-4#2, ER-EC-6, ER-EC-7, and ER-EC-8. The following wells in carbonate rock are evaluated: ER-7-1, ER-6-1, ER-6-1#2, and ER-12-3. There are a sufficient number of wells in volcanic tuff and carbonate rock to associate the conductivity values with the specific hydrogeologic characteristics such as the stratigraphic unit, hydrostratigraphic unit, hydrogeologic unit, lithologic modifier, and alteration modifier used to describe the hydrogeologic setting. Associating hydraulic conductivity with hydrogeologic characteristics allows an evaluation of the data range and the statistical distribution of values. These results are relevant to how these units are considered in conceptual models and represented in groundwater models. The wells in volcanic tuff illustrate a wide range of data values and data distributions when associated with specific hydrogeologic characteristics. Hydraulic conductivity data within a hydrogeologic characteristic can display normal distributions, lognormal distributions, semi-uniform distribution, or no identifiable distribution. There can be multiple types of distributions within a hydrogeologic characteristic such as a single stratigraphic unit. This finding has implications for assigning summary hydrogeologic characteristics to hydrostratigraphic and hydrogeologic units. The results presented herein are specific to the hydrogeologic characteristic and to the wells used to describe hydraulic conductivity. The wells in carbonate rock are associated with a fewer number of hydrogeologic characteristics. That is, UGTA wells constructed in carbonate rock have tended to be in similar hydrogeologic materials, and show a wide range in hydraulic conductivity values and data distributions. Associations of hydraulic conductivity and hydrogeologic characteristics are graphically presented even when there are only a few data. This approach benchmarks what is currently known about the association of depth-specific hydraulic conductivity and hydrogeologic characteristics.

  11. Depth profiling analysis of solar wind helium collected in diamond-like carbon film from Genesis

    SciTech Connect (OSTI)

    Bajo, Ken-ichi; Olinger, Chad T.; Jurewicz, Amy J.G.; Burnett, Donald S.; Sakaguchi, Isao; Suzuki, Taku; Itose, Satoru; Ishihara, Morio; Uchino, Kiichiro; Wieler, Rainer; Yurimoto, Hisayoshi

    2015-10-01

    The distribution of solar-wind ions in Genesis mission collectors, as determined by depth profiling analysis, constrains the physics of ion solid interactions involving the solar wind. Thus, they provide an experimental basis for revealing ancient solar activities represented by solar-wind implants in natural samples. We measured the first depth profile of ⁴He in a collector; the shallow implantation (peaking at <20 nm) required us to use sputtered neutral mass spectrometry with post-photoionization by a strong field. The solar wind He fluence calculated using depth profiling is ~8.5 x 10¹⁴ cm⁻². The shape of the solar wind ⁴He depth profile is consistent with TRIM simulations using the observed ⁴He velocity distribution during the Genesis mission. It is therefore likely that all solar-wind elements heavier than H are completely intact in this Genesis collector and, consequently, the solar particle energy distributions for each element can be calculated from their depth profiles. Ancient solar activities and space weathering of solar system objects could be quantitatively reproduced by solar particle implantation profiles.

  12. Wave like signatures in aerosol optical depth and associated radiative impacts over the central Himalayan region

    SciTech Connect (OSTI)

    Shukla, K. K.; Phanikumar, D. V.; Kumar, Niranjan; Reddy, Kishore; Kotamarthi, Veerabhadra R.; Newsom, Rob K.; Ouarda, Taha B.

    2015-10-01

    In this study, we present a case study on 16 October 2011 to show the first observational evidence of the influence of short period gravity waves in aerosol transport during daytime over the central Himalayan region. The Doppler lidar data has been utilized to address the daytime boundary layer evolution and related aerosol dynamics over the site. Mixing layer height is estimated by wavelet covariance transform method and found to be ~ 0.7 km, AGL. Aerosol optical depth observations during daytime revealed an asymmetry showing clear enhancement during afternoon hours as compared to forenoon. Interestingly, Fourier and wavelet analysis of vertical velocity and attenuated backscatter showed similar 50-90 min short period gravity wave signatures during afternoon hours. Moreover, our observations showed that gravity waves are dominant within the boundary layer implying that the daytime boundary layer dynamics is playing a vital role in transporting the aerosols from surface to the top of the boundary layer. Similar modulations are also evident in surface parameters like temperature, relative humidity and wind speed indicating these waves are associated with the dynamical aspects over Himalayan region. Finally, time evolution of range-23 height indicator snapshots during daytime showed strong upward velocities especially during afternoon hours implying that convective processes through short period gravity waves plays a significant role in transporting aerosols from the nearby valley region to boundary layer top over the site. These observations also establish the importance of wave induced daytime convective boundary layer dynamics in the lower Himalayan region.

  13. Low temperature London penetration depth and superfluid density in Fe-based superconductors

    SciTech Connect (OSTI)

    Kim, Hyunsoo

    2013-05-15

    The superconducting gap symmetry of the Fe-based superconductors was studied by measurements and analysis of London penetration depth and super uid density. Tunnel diode resonator technique for these measurements was implemented in a dilution refrigerator allowing for the temperatures down to 50 mK. For the analysis of the super uid density, we used both experimental studies of Al-coated samples and original thermodynamic approach based on Rutgers relation. In three systems studied, we found that the superconducting gap at the optimal doping is best described in multi-gap full gap scenario. By performing experiments on samples with arti#12;cially introduced disorder with heavy ion irradiation, we show that evolution of the superconducting transition temperature and of the super uid density are consistent with full-gap sign changing s#6; superconducting state. The superconducting gap develops strong modulation both in the under-doped and the over-doped regimes. In the terminal hole-doped KFe{sub 2}As{sub 2}, both temperature dependence of the super uid density and its evolution with increase of the scattering rate are consistent with symmetry imposed vertical line nodes in the superconducting gap. By comparative studies of hole-doped (Ba,K)Fe{sub 2}As{sub 2} and electron-doped Ca10-3-8, we show that the superconducting gap modulation in the under-doped regime is intrinsic and is not induced by the coexisting static magnetic order.

  14. Metal affinity enrichment increases the range and depth of proteome identification for extracellular microbial proteins

    SciTech Connect (OSTI)

    Wheeler, Korin; Erickson, Brian K; Mueller, Ryan; Singer, Steven; Verberkmoes, Nathan C; Hwang, Mona; Thelen, Michael P.; Hettich, Robert {Bob} L

    2012-01-01

    Many key proteins, such as those involved in cellular signaling or transcription, are difficult to measure in microbial proteomic experiments due to the interfering presence of more abundant, dominant proteins. In an effort to enhance the identification of previously undetected proteins, as well as provide a methodology for selective enrichment, we evaluated and optimized immobilized metal affinity chromatography (IMAC) coupled with mass spectrometric characterization of extracellular proteins from an extremophilic microbial community. Seven different metals were tested for IMAC enrichment. The combined results added 20% greater proteomic depth to the extracellular proteome. Although this IMAC enrichment could not be conducted at the physiological pH of the environmental system, this approach did yield a reproducible and specific enrichment of groups of proteins with functions potentially vital to the community, thereby providing a more extensive biochemical characterization. Notably, 40 unknown proteins previously annotated as hypothetical were enriched and identified for the first time. Examples of identified proteins includes a predicted TonB signal sensing protein homologous to other known TonB proteins and a protein with a COXG domain previously identified in many chemolithoautotrophic microbes as having a function in the oxidation of CO.

  15. Leakage of CO2 from geologic storage: Role of secondaryaccumulation at shallow depth

    SciTech Connect (OSTI)

    Pruess, K.

    2007-05-31

    Geologic storage of CO2 can be a viable technology forreducing atmospheric emissions of greenhouse gases only if it can bedemonstrated that leakage from proposed storage reservoirs and associatedhazards are small or can be mitigated. Risk assessment must evaluatepotential leakage scenarios and develop a rational, mechanisticunderstanding of CO2 behavior during leakage. Flow of CO2 may be subjectto positive feedbacks that could amplify leakage risks and hazards,placing a premium on identifying and avoiding adverse conditions andmechanisms. A scenario that is unfavorable in terms of leakage behavioris formation of a secondary CO2 accumulation at shallow depth. This paperdevelops a detailed numerical simulation model to investigate CO2discharge from a secondary accumulation, and evaluates the role ofdifferent thermodynamic and hydrogeologic conditions. Our simulationsdemonstrate self-enhancing as well as self-limiting feedbacks.Condensation of gaseous CO2, 3-phase flow of aqueous phase -- liquid CO2-- gaseous CO2, and cooling from Joule-Thomson expansion and boiling ofliquid CO2 are found to play important roles in the behavior of a CO2leakage system. We find no evidence that a subsurface accumulation of CO2at ambient temperatures could give rise to a high-energy discharge, aso-called "pneumatic eruption."

  16. Method of controlling the side wall thickness of a turbine nozzle segment for improved cooling

    DOE Patents [OSTI]

    Burdgick, Steven Sebastian (Schenectady, NY)

    2002-01-01

    A gas turbine nozzle segment has outer and inner bands and a vane extending therebetween. Each band has a side wall, a cover and an impingement plate between the cover and nozzle wall defining two cavities on opposite sides of the impingement plate. Cooling steam is supplied to one cavity for flow through apertures of the impingement plate to cool the nozzle wall. The side wall of the band has an inturned flange defining with the nozzle wall an undercut region. The outer surface of the side wall is provided with a step prior to welding the cover to the side wall. A thermal barrier coating is applied in the step and, after the cover is welded to the side wall, the side wall is finally machined to a controlled thickness removing all, some or none of the coating.

  17. Spray shadowing for stress relief and mechanical locking in thick protective coatings

    DOE Patents [OSTI]

    Hollis, Kendall (Los Alamos, NM); Bartram, Brian (Los Alamos, NM)

    2007-05-22

    A method for applying a protective coating on an article, comprising the following steps: selecting an article with a surface for applying a coating thickness; creating undercut grooves on the article, where the grooves depend beneath the surface to a bottom portion with the grooves having an upper width on the surface and a lower width on the bottom portion connected by side walls, where at least one of the side walls connects the upper width and the lower width to form an undercut angle with the surface less than 90.degree.; and, applying the protective coating onto the article to fill the undercut grooves and cover the surface, thereby forming weak paths within the protective coating.

  18. Direct detection of x-rays for protein crystallography employing a thick, large area CCD

    DOE Patents [OSTI]

    Atac, Muzaffer; McKay, Timothy

    1999-01-01

    An apparatus and method for directly determining the crystalline structure of a protein crystal. The crystal is irradiated by a finely collimated x-ray beam. The interaction of the x-ray beam with the crystal produces scattered x-rays. These scattered x-rays are detected by means of a large area, thick CCD which is capable of measuring a significant number of scattered x-rays which impact its surface. The CCD is capable of detecting the position of impact of the scattered x-ray on the surface of the CCD and the quantity of scattered x-rays which impact the same cell or pixel. This data is then processed in real-time and the processed data is outputted to produce a image of the structure of the crystal. If this crystal is a protein the molecular structure of the protein can be determined from the data received.

  19. Fluorescence measurements for evaluating the application of multivariate analysis techniques to optically thick environments.

    SciTech Connect (OSTI)

    Reichardt, Thomas A.; Timlin, Jerilyn Ann; Jones, Howland D. T.; Sickafoose, Shane M.; Schmitt, Randal L.

    2010-09-01

    Laser-induced fluorescence measurements of cuvette-contained laser dye mixtures are made for evaluation of multivariate analysis techniques to optically thick environments. Nine mixtures of Coumarin 500 and Rhodamine 610 are analyzed, as well as the pure dyes. For each sample, the cuvette is positioned on a two-axis translation stage to allow the interrogation at different spatial locations, allowing the examination of both primary (absorption of the laser light) and secondary (absorption of the fluorescence) inner filter effects. In addition to these expected inner filter effects, we find evidence that a portion of the absorbed fluorescence is re-emitted. A total of 688 spectra are acquired for the evaluation of multivariate analysis approaches to account for nonlinear effects.

  20. Layer thickness and period as design parameters to tailor pyroelectric properties in ferroelectric superlattices

    SciTech Connect (OSTI)

    Misirlioglu, I. B.; Alpay, S. P.

    2014-10-27

    We theoretically examine the pyroelectric properties of ferroelectric-paraelectric superlattices as a function of layer thickness and configuration using non-linear thermodynamics coupled with electrostatic and electromechanical interactions between layers. We specifically study PbZr{sub 0.3}Ti{sub 0.7}O{sub 3}/SrTiO{sub 3} superlattices. The pyroelectric properties of such constructs consisting of relatively thin repeating units are shown to exceed the pyroelectric response of monolithic PbZr{sub 0.3}Ti{sub 0.7}O{sub 3} films. This is related to periodic internal electric fields generated due to the polarization mismatch between layers that allows tailoring of the shift in the transition temperature. Our results indicate that higher and electric field sensitive pyroresponse can be achieved from layer-by-layer engineered ferroelectric heterostructures.

  1. Method and apparatus for monitoring the thickness of a coal rib during rib formation

    DOE Patents [OSTI]

    Mowrey, Gary L. (Jefferson Boro, PA); Ganoe, Carl W. (Pittsburgh, PA); Monaghan, William D. (Dravosburg, PA)

    1996-01-01

    Apparatus for monitoring the position of a mining machine cutting a new entry in a coal seam relative to an adjacent, previously cut entry to determine the distance between a near face of the adjacent previously cut entry and a new face adjacent thereto of a new entry being cut by the mining machine which together define the thickness of a coal rib being formed between the new entry and the adjacent previously cut entry during the new entry-cutting operation. The monitoring apparatus; includes a transmit antenna mounted on the mining machine and spaced inwardly from the new face of the coal rib for transmitting radio energy towards the coal rib so that one portion of the radio energy is reflected by the new face which is defined at an air-coal interface between the new entry and the coal rib and another portion of the radio energy is reflected by the near face of the coal rib which is defined at an air-coal interface between the coal rib and the adjacent previously cut entry. A receive antenna mounted on the mining machine and spaced inwardly of the new face of the coal rib receives the one portion of the radio energy reflected by the new face and also receives the another portion of the radio energy reflected by the near face. A processor determines a first elapsed time period equal to the time required for the one portion of the radio energy reflected by the new face to travel between the transmit antenna and the receive antenna and also determines a second elapsed time period equal to the time required for the another portion of the radio energy reflected by the near face to travel between the transmit antenna and the receive antenna and thereafter calculates the thickness of the coal rib being formed as a function of the difference between the first and second elapsed time periods.

  2. Engineering Task Plan for Development and Fabrication and Deployment of Nested Fixed Depth Fluidic Sampling and At Tank Analysis Systems

    SciTech Connect (OSTI)

    BOGER, R.M.

    2000-10-30

    This engineering task plan identifies the resources, responsibilities, and schedules for the development and deployment of a mobile, variable depth sampling system and an at-tank analysis system. The mobile, variable depth sampling system concept was developed after a cost assessment indicated a high cost for multiple deployments of the nested, fixed-depth sampling system. The sampling will provide double-shell tank (DST) staging tank waste samples for assuring the readiness of the waste for shipment to the LAW/HLW plant for treatment and immobilization. The at-tank analysis system will provide ''real-time'' assessments of the samples' chemical and physical properties. These systems support the Hanford Phase 1B vitrification project.

  3. Quantifying Aerosol Direct Effects from Broadband Irradiance and Spectral Aerosol Optical Depth Observations

    SciTech Connect (OSTI)

    Creekmore, Torreon N.; Joseph, Everette; Long, Charles N.; Li, Siwei

    2014-05-16

    We outline a methodology using broadband and spectral irradiances to quantify aerosol direct effects on the surface diffuse shortwave (SW) irradiance. Best Estimate Flux data span a 13 year timeframe at the Department of Energy Atmospheric Radiation Measurement Program’s Southern Great Plains (SGP) site. Screened clear-sky irradiances and aerosol optical depth (AOD), for solar zenith angles ≤ 65°, are used to estimate clear-sky diffuse irradiances. We validate against detected clear-sky observations from SGP’s Basic Radiation System (BRS). BRS diffuse irradiances were in accordance with estimates, producing a root-mean-square error and mean bias errors of 4.0 W/m2 and -1.4 W/m2, respectively. Absolute differences show 99% of estimates within ±10 W/m2 (10%) of the mean BRS observations. Clear-sky diffuse estimates are used to derive quantitative estimates of aerosol radiative effects, represented as the aerosol diffuse irradiance (ADI). ADI is the contribution of diffuse SW to global SW, attributable to scattering of atmospheric transmission by natural plus anthropogenic aerosols. Estimated slope for the ADI as a function of AOD indicates an increase of ~22 W/m2 in diffuse SW for every 0.1 increase in AOD. Such significant increases in the diffuse fraction could possibly increase photosynthesis. Annual mean ADI is 28.2 W/m2, and heavy aerosol loading at SGP provides up to a maximum increase of 120 W/m2 in diffuse SW over background conditions. With regard to seasonal variation, the mean diffuse forcings are 17.2, 33.3, 39.0, and 23.6 W/m2 for winter, spring, summer, and fall, respectively.

  4. Fabrication of TiO{sub 2} Thick Film for Photocatalyst from Commercial TiO{sub 2} Powder

    SciTech Connect (OSTI)

    Asteti, S. Fuji; Syarif, D. Gustaman

    2008-03-17

    Photocatalytic activity of TiO{sub 2} thick film ceramics made of commercial TiO{sub 2} powder has been studied. The TiO{sub 2} powder was nano sized one that was derived from dried TiO{sub 2} suspension. The TiO{sub 2} suspension was made by pouring some blended commercial TiO{sub 2} powder into some amount of water. The paste of TiO{sub 2} was made by mixing the nano sized TiO{sub 2} powder with organic vehicle and glass frit. The paste was spread on a glass substrate. The paste was dried at 100 deg. C and heated at different temperatures (400 deg. C and 500 deg. C) for 60 minutes to produce thick film ceramics. The photocatalytic activity of these films was evaluated by measuring the concentration of a solution of methylene blue where the thick films were inside after being illuminated by UV light at various periods of times. The initial concentration of the methylene blue solution was 5 ppm. Structural analyses were carried out by X-ray diffraction (XRD). The XRD analyses showed that the produced thick film ceramic had mainly crystal structure of anatase. According to the photocatalytical data, it was known that the produced thick film ceramics were photocatalyst which were capable of decomposing an organic compound such as the methylene blue.

  5. Current longwall ventilation problems and implications for thick seam longwalls. Final technical report. [133 references

    SciTech Connect (OSTI)

    Not Available

    1980-06-01

    The objective of this investigation was to identify, analyze and suggest solutions to ventilation problems of the following mining systems proposed for use in western thick seams; multiple lift longwall; single pass longwall with face height in the range of 12 to 19 feet; longwall sublevel caving. To reach this objective, background information on the regulations and ventilation practices relevant to the three methods was reviewed. This was followed by an identification of ventilation problems including the sources and quantities of methane emissions, respirable coal dust, self ignition and self heating. The problems were then analyzed to determine the probability of occurrence, the cause of the problem, and its consequences. Having analyzed these problems, solutions were described to the problems. The major finding of this effort was that, while certain ventilation difficulties can be isolated peculiar to these three moethods, in general, seam specific conditions have a larger role in determining the success of ventilation than does the method used. The major difficulties to be faced by these novel methods are the same as those to be faced by conventional longwalls. Research efforts should proceed on that basis.

  6. Dynamic Response of a Pulse-Heated, Thick-Walled, Hollow Sphere: Validation of Code Numerics

    SciTech Connect (OSTI)

    Canaan, R.E.

    2000-01-19

    Volumetric pulse heating of a thick-walled hollow sphere is numerically investigated. The primary objective is to validate a variety of LLNL 30 hydrocodes for modeling the dynamic behavior of fissile/fissionable metals subject to rapid ''fission-heating'' transients. The 30 codes tested include both DYNA3D and NIKE3D, as well as the ''ASCI'' code, ALE3D. The codes are compared ''head-to-head'' and are benchmarked against a 1D finite difference solution to the problem that is derived from basic principles. Three pulse-heating transients are examined with full-width-half-maximum pulse durations of 41{micro}s, 85{micro}s, and 140{micro}s, respectively. These three transients produce a significant range of dynamic responses in the thermo-elastic regime. We present results for dynamic radial displacements and stresses for each pulse, and also discuss which code features/options worked best for these types of calculations. In general, the code results are in excellent agreement for the simple system considered. Validation of code numerics in simple systems is a key first step toward future application of the codes in more complicated geometries (U).

  7. More pieces of the puzzle: chemistry and substructures in the galactic thick disk

    SciTech Connect (OSTI)

    Helmi, Amina; Williams, Mary; Freeman, K. C.; Bland-Hawthorn, J.; De Silva, G. E-mail: mary@aip.de

    2014-08-20

    We present a study of the chemical abundances of solar neighborhood stars associated with dynamical structures in the Milky Way's (thick) disk. These stars were identified as an overdensity in the eccentricity range 0.3 < ? < 0.5 in the Copenhagen-Geneva Survey by Helmi et al. We find that stars with these dynamical characteristics do not constitute a homogeneous population. A relatively sharp transition in dynamical and chemical properties appears to occur at a metallicity of [Fe/H] ? 0.4. Stars with [Fe/H] > 0.4 have mostly lower eccentricities, smaller vertical velocity dispersions, are ?-enhanced, and define a rather narrow sequence in [?/Fe] versus [Fe/H], clearly distinct from that of the thin disk. Stars with [Fe/H] < 0.4 have a range of eccentricities, are hotter vertically, and depict a larger spread in [?/Fe]. We also found tentative evidence of a substructure possibly associated with the disruption of a metal-rich star cluster. The differences between these populations of stars is also present in, e.g., [Zn/Fe], [Ni/Fe], and [SmII/Fe], suggesting a real physical distinction.

  8. SN 2008D: A WOLF-RAYET EXPLOSION THROUGH A THICK WIND

    SciTech Connect (OSTI)

    Svirski, Gilad; Nakar, Ehud

    2014-06-10

    Supernova (SN) 2008D/XRT 080109 is considered to be the only direct detection of a shock breakout from a regular SN to date. While a breakout interpretation was favored by several papers, inconsistencies remain between the observations and current SN shock breakout theory. Most notably, the duration of the luminous X-ray pulse is considerably longer than expected for a spherical breakout through the surface of a type Ibc SN progenitor, and the X-ray radiation features, mainly its flat spectrum and its luminosity evolution, are enigmatic. We apply a recently developed theoretical model for the observed radiation from a Wolf-Rayet SN exploding through a thick wind and show that it naturally explains all of the observed features of SN 2008D X-ray emission, including the energetics, the spectrum, and the detailed luminosity evolution. We find that the inferred progenitor and SN parameters are typical for an exploding Wolf-Rayet. A comparison of the wind density found at the breakout radius and the density at much larger radii, as inferred by late radio observations, suggests an enhanced mass-loss rate taking effect about 10days prior to the SN explosion. This finding joins accumulating evidence for a possible late phase in the stellar evolution of massive stars, involving vigorous mass loss a short time before the SN explosion.

  9. Temperature effects on nanostructure and mechanical properties of single-nanoparticle thick membranes.

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Salerno, Kenneth Michael; Grest, Gary S.

    2015-04-30

    In this study, the properties of mechanically stable single-nanoparticle (NP)-thick membranes have largely been studied at room temperature. How these membranes soften as nanoparticle ligands disorder with increasing temperature is unknown. Molecular dynamics simulations are used to probe the temperature dependence of the mechanical and nanostructural properties of nanoparticle membranes made of 6 nm diameter Au nanoparticles coated with dodecanethiol ligands and terminated with either methyl (CH3) or carboxyl (COOH) terminal groups. For methyl-terminated ligands, interactions along the alkane chain provide mechanical stiffness, with a Young's modulus of 1.7 GPa at 300 K. For carboxyl-terminated chains, end-group interactions are significant,more » producing stiffer membranes at all temperatures, with a Young's modulus of 3.8 GPa at 300 K. For both end-group types, membrane stiffness is reduced to zero at about 400 K. Ligand structure and mechanical properties of membranes at 300 K that have been annealed at 400 K are comparable to samples that do not undergo thermal annealing.« less

  10. Thickness-dependent metal-insulator transition in epitaxial SrRuO3 ultrathin films

    SciTech Connect (OSTI)

    Shen, Xuan; Qiu, Xiangbiao; Su, Dong; Zhou, Shengqiang; Li, Aidong; Wu, Di

    2015-01-06

    Transport characteristics of ultrathin SrRuO? films, deposited epitaxially on TiO?-terminated SrTiO? (001) single-crystal substrates, were studied as a function of film thickness. Evolution from a metallic to an insulating behavior is observed as the film thickness decreases from 20 to 4 unit cells. In films thicker than 4 unit cells, the transport behavior obeys the Drude low temperature conductivity with quantum corrections, which can be attributed to weak localization. Fitting the data with 2-dimensional localization model indicates that electron-phonon collisions are the main inelastic relaxation mechanism. In the film of 4 unit cells in thickness, the transport behavior follows variable range hopping model, indicating a strongly localized state. As a result, magnetoresistance measurements reveal a likely magnetic anisotropy with the magnetic easy axis along the out-of-plane direction.

  11. DECOVALEX-THMC Task D: Long-Term Permeability/Porosity Changes inthe EDZ and Near Field due to THM and THC Processes in Volcanic andCrystaline-Bentonite Systems, Status Report October 2005

    SciTech Connect (OSTI)

    Birkholzer, J.; Rutqvist, J.; Sonnenthal, E.; Barr, D.

    2005-11-01

    The DECOVALEX project is an international cooperativeproject initiated by SKI, the Swedish Nuclear Power Inspectorate, withparticipation of about 10 international organizations. The name DECOVALEXstands for DEvelopment of COupled models and their VALidation againstExperiments. The general goal of this project is to encouragemultidisciplinary interactive and cooperative research on modelingcoupled processes in geologic formations in support of the performanceassessment for underground storage of radioactive waste. Three multi-yearproject stages of DECOVALEX have been completed in the past decade,mainly focusing on coupled thermal-hydrological-mechanicalprocesses.Currently, a fourth three-year project stage of DECOVALEX isunder way, referred to as DECOVALEX-THMC. THMC stands for Thermal,Hydrological, Mechanical, and Chemical processes. The new project stageaims at expanding the traditional geomechanical scope of the previousDECOVALEX project stages by incorporating geochemical processes importantfor repository performance. The U.S. Department of Energy (DOE) leadsTask D of the new DECOVALEX phase, entitled "Long-termPermeability/Porosity Changes in the EDZ and Near Field due to THC andTHM Processes for Volcanic and Crystalline-Bentonite Systems." In itsleadership role for Task D, DOE coordinates and sets the direction forthe cooperative research activities of the international research teamsengaged in Task D.

  12. Numerical simulations of optically thick accretion onto a black hole. II. Rotating flow

    SciTech Connect (OSTI)

    Fragile, P. Chris; Olejar, Ally; Anninos, Peter

    2014-11-20

    In this paper, we report on recent upgrades to our general relativistic radiation magnetohydrodynamics code, Cosmos++, including the development of a new primitive inversion scheme and a hybrid implicit-explicit solver with a more general M {sub 1} closure relation for the radiation equations. The new hybrid solver helps stabilize the treatment of the radiation source terms, while the new closure allows for a much broader range of optical depths to be considered. These changes allow us to expand by orders of magnitude the range of temperatures, opacities, and mass accretion rates, and move a step closer toward our goal of performing global simulations of radiation-pressure-dominated black hole accretion disks. In this work, we test and validate the new method against an array of problems. We also demonstrate its ability to handle super-Eddington, quasi-spherical accretion. Even with just a single proof-of-principle simulation, we already see tantalizing hints of the interesting phenomenology associated with the coupling of radiation and gas in super-Eddington accretion flows.

  13. In situ measurement of the bonded film thickness of Z-Tetraol lubricant on magnetic recording media

    SciTech Connect (OSTI)

    Zhu Lei; Li Feng

    2010-10-15

    Currently, the bonded film thickness of perfluoropolyether lubricant on top of magnetic recording media is measured by a two-step process. First, the media disk has to be rinsed thoroughly using a fluorocarbon solvent (for instance, Vetrel) to remove the mobile lubricant. Second, the thickness of the remaining lubricant on the media surface which is regarded as the bonded lubricant thickness is then measured either by Fourier transform infrared spectroscopy (FTIR) or electron spectroscopy for chemical analysis. As the total lubricant thickness approaches single molecular dimension ({approx}10 A), current methods face tremendous challenge on the accuracy and sensitivity of the measurement. We studied the spectral characteristics responding to the lubricant bonding with the carbon overcoat by the time-of-flight secondary ion mass spectra and proposed to use the peak area ratio (C{sub 3}H{sub 2}F/C{sub 3}H{sub 5}O and C{sub 4}H{sub 10}O/C{sub 3}H{sub 6}O{sub 2}) to characterize the bonded Z-Tetraol lubricant that produces a direct bonded lubricant thickness measurement without the need to remove the mobile lubricant with a solvent. After taking the background signal of disks prior to bonding by UV irradiation into account, this method becomes independent of the total lubricant thickness as well as shows good correlation linearity (R{sup 2{approx}}87%) with the current FTIR method for the ratio of C{sub 4}H{sub 10}O/C{sub 3}H{sub 6}O{sub 2}.

  14. Energy-loss- and thickness-dependent contrast in atomic-scale electron energy-loss spectroscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tan, Haiyan; Zhu, Ye; Dwyer, Christian; Xin, Huolin L.

    2014-12-31

    Atomic-scale elemental maps of materials acquired by core-loss inelastic electron scattering often exhibit an undesirable sensitivity to the unavoidable elastic scattering, making the maps counter-intuitive to interpret. Here, we present a systematic study that scrutinizes the energy-loss and sample-thickness dependence of atomic-scale elemental maps acquired using 100 keV incident electrons in a scanning transmission electron microscope. For single-crystal silicon, the balance between elastic and inelastic scattering means that maps generated from the near-threshold Si-L signal (energy loss of 99 eV) show no discernible contrast for a thickness of 0.5λ (λ is the electron mean-free path, here approximately 110 nm). Atmore » greater thicknesses we observe a counter-intuitive “negative” contrast. Only at much higher energy losses is an intuitive “positive” contrast gradually restored. Our quantitative analysis shows that the energy-loss at which a positive contrast is restored depends linearly on the sample thickness. This behavior is in very good agreement with our double-channeling inelastic scattering calculations. We test a recently-proposed experimental method to correct the core-loss inelastic scattering and restore an intuitive “positive” chemical contrast. The method is demonstrated to be reliable over a large range of energy losses and sample thicknesses. The corrected contrast for near-threshold maps is demonstrated to be (desirably) inversely proportional to sample thickness. As a result, implications for the interpretation of atomic-scale elemental maps are discussed.« less

  15. Energy-loss- and thickness-dependent contrast in atomic-scale electron energy-loss spectroscopy

    SciTech Connect (OSTI)

    Tan, Haiyan; Zhu, Ye; Dwyer, Christian; Xin, Huolin L.

    2014-12-31

    Atomic-scale elemental maps of materials acquired by core-loss inelastic electron scattering often exhibit an undesirable sensitivity to the unavoidable elastic scattering, making the maps counter-intuitive to interpret. Here, we present a systematic study that scrutinizes the energy-loss and sample-thickness dependence of atomic-scale elemental maps acquired using 100 keV incident electrons in a scanning transmission electron microscope. For single-crystal silicon, the balance between elastic and inelastic scattering means that maps generated from the near-threshold Si-L signal (energy loss of 99 eV) show no discernible contrast for a thickness of 0.5? (? is the electron mean-free path, here approximately 110 nm). At greater thicknesses we observe a counter-intuitive negative contrast. Only at much higher energy losses is an intuitive positive contrast gradually restored. Our quantitative analysis shows that the energy-loss at which a positive contrast is restored depends linearly on the sample thickness. This behavior is in very good agreement with our double-channeling inelastic scattering calculations. We test a recently-proposed experimental method to correct the core-loss inelastic scattering and restore an intuitive positive chemical contrast. The method is demonstrated to be reliable over a large range of energy losses and sample thicknesses. The corrected contrast for near-threshold maps is demonstrated to be (desirably) inversely proportional to sample thickness. As a result, implications for the interpretation of atomic-scale elemental maps are discussed.

  16. Ligand-Thickness Effect Leads to Enhanced Preference for Large Anions in Alkali Metal Extraction by Crown Ethers

    SciTech Connect (OSTI)

    Haverlock, T.J.; Moyer, B.A.; Sachleben, R.A.

    1999-07-11

    Jean-Marie Lehn (Nobel laureate, 1987) suggested ligand thickness to be an important consideration in the design of host molecules for cation recognition. We have recently expanded the role of this simple ligand property by demonstrating a case in which ligand thickness contributes significantly to anion discrimination. It was found that in the extraction of sodium nitrate and perchlorate by a simple crown ether, bis(t-octylbenzo)-14-crown-4 (BOB 14C4), the normal preference for perchlorate is almost completely lost when the complex cation has the open-face sandwich vs. the sandwich structure.

  17. Influence of the thickness of a crystal on the electrical characteristics of Cd(Zn)Te detectors

    SciTech Connect (OSTI)

    Sklyarchuk, V.; Fochuk, p.; Rarenko, I.; Zakharuk, Z.; Sklyarchuk, O. F.; Bolotnikov, A. E.; James, R. B.

    2015-08-01

    We studied the electrical characteristics of Cd(Zn)Te detectors with rectifying contacts and varying thicknesses, and established that their geometrical dimensions affect the measured electrical properties. We found that the maximum value of the operating-bias voltage and the electric field in the detector for acceptable values of the dark current can be achieved when the crystal has an optimum thickness. This finding is due to the combined effect of generation-recombination in the space-charge region and space-charge limited currents (SCLC).

  18. Monte Carlo study of the depth-dependent fluence perturbation in parallel-plate ionization chambers in electron beams

    SciTech Connect (OSTI)

    Zink, K.; Czarnecki, D.; Voigts-Rhetz, P. von; Looe, H. K.; Harder, D.

    2014-11-01

    Purpose: The electron fluence inside a parallel-plate ionization chamber positioned in a water phantom and exposed to a clinical electron beam deviates from the unperturbed fluence in water in absence of the chamber. One reason for the fluence perturbation is the well-known inscattering effect, whose physical cause is the lack of electron scattering in the gas-filled cavity. Correction factors determined to correct for this effect have long been recommended. However, more recent Monte Carlo calculations have led to some doubt about the range of validity of these corrections. Therefore, the aim of the present study is to reanalyze the development of the fluence perturbation with depth and to review the function of the guard rings. Methods: Spatially resolved Monte Carlo simulations of the dose profiles within gas-filled cavities with various radii in clinical electron beams have been performed in order to determine the radial variation of the fluence perturbation in a coin-shaped cavity, to study the influences of the radius of the collecting electrode and of the width of the guard ring upon the indicated value of the ionization chamber formed by the cavity, and to investigate the development of the perturbation as a function of the depth in an electron-irradiated phantom. The simulations were performed for a primary electron energy of 6 MeV. Results: The Monte Carlo simulations clearly demonstrated a surprisingly large in- and outward electron transport across the lateral cavity boundary. This results in a strong influence of the depth-dependent development of the electron field in the surrounding medium upon the chamber reading. In the buildup region of the depth-dose curve, the inout balance of the electron fluence is positive and shows the well-known dose oscillation near the cavity/water boundary. At the depth of the dose maximum the inout balance is equilibrated, and in the falling part of the depth-dose curve it is negative, as shown here the first time. The influences of both the collecting electrode radius and the width of the guard ring are reflecting the deep radial penetration of the electron transport processes into the gas-filled cavities and the need for appropriate corrections of the chamber reading. New values for these corrections have been established in two forms, one converting the indicated value into the absorbed dose to water in the front plane of the chamber, the other converting it into the absorbed dose to water at the depth of the effective point of measurement of the chamber. In the Appendix, the inout imbalance of electron transport across the lateral cavity boundary is demonstrated in the approximation of classical small-angle multiple scattering theory. Conclusions: The inout electron transport imbalance at the lateral boundaries of parallel-plate chambers in electron beams has been studied with Monte Carlo simulation over a range of depth in water, and new correction factors, covering all depths and implementing the effective point of measurement concept, have been developed.

  19. Study of a prototype high quantum efficiency thick scintillation crystal video-electronic portal imaging device

    SciTech Connect (OSTI)

    Samant, Sanjiv S.; Gopal, Arun

    2006-08-15

    Image quality in portal imaging suffers significantly from the loss in contrast and spatial resolution that results from the excessive Compton scatter associated with megavoltage x rays. In addition, portal image quality is further reduced due to the poor quantum efficiency (QE) of current electronic portal imaging devices (EPIDs). Commercial video-camera-based EPIDs or VEPIDs that utilize a thin phosphor screen in conjunction with a metal buildup plate to convert the incident x rays to light suffer from reduced light production due to low QE (<2% for Eastman Kodak Lanex Fast-B). Flat-panel EPIDs that utilize the same luminescent screen along with an a-Si:H photodiode array provide improved image quality compared to VEPIDs, but they are expensive and can be susceptible to radiation damage to the peripheral electronics. In this article, we present a prototype VEPID system for high quality portal imaging at sub-monitor-unit (subMU) exposures based on a thick scintillation crystal (TSC) that acts as a high QE luminescent screen. The prototype TSC system utilizes a 12 mm thick transparent CsI(Tl) (thallium-activated cesium iodide) scintillator for QE=0.24, resulting in significantly higher light production compared to commercial phosphor screens. The 25x25 cm{sup 2} CsI(Tl) screen is coupled to a high spatial and contrast resolution Video-Optics plumbicon-tube camera system (1240x1024 pixels, 250 {mu}m pixel width at isocenter, 12-bit ADC). As a proof-of-principle prototype, the TSC system with user-controlled camera target integration was adapted for use in an existing clinical gantry (Siemens BEAMVIEW{sup PLUS}) with the capability for online intratreatment fluoroscopy. Measurements of modulation transfer function (MTF) were conducted to characterize the TSC spatial resolution. The measured MTF along with measurements of the TSC noise power spectrum (NPS) were used to determine the system detective quantum efficiency (DQE). A theoretical expression of DQE(0) was developed to be used as a predictive model to propose improvements in the optics associated with the light detection. The prototype TSC provides DQE(0)=0.02 with its current imaging geometry, which is an order of magnitude greater than that for commercial VEPID systems and comparable to flat-panel imaging systems. Following optimization in the imaging geometry and the use of a high-end, cooled charge-coupled-device (CCD) camera system, the performance of the TSC is expected to improve even further. Based on our theoretical model, the expected DQE(0)=0.12 for the TSC system with the proposed improvements, which exceeds the performance of current flat-panel EPIDs. The prototype TSC provides high quality imaging even at subMU exposures (typical imaging dose is 0.2 MU per image), which offers the potential for daily patient localization imaging without increasing the weekly dose to the patient. Currently, the TSC is capable of limited frame-rate fluoroscopy for intratreatment visualization of patient motion at {approx}3 frames/second, since the achievable frame rate is significantly reduced by the limitations of the camera-control processor. With optimized processor control, the TSC is expected to be capable of intratreatment imaging exceeding 10 frames/second to monitor patient motion.

  20. Ligand structure and mechanical properties of single-nanoparticle thick membranes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Salerno, Kenneth Michael; Bolintineanu, Dan; Lane, J. Matthew; Grest, Gary S.

    2015-06-16

    We believe that the high mechanical stiffness of single-nanoparticle-thick membranes is the result of the local structure of ligand coatings that mediate interactions between nanoparticles. These ligand structures are not directly observable experimentally. We use molecular dynamics simulations to observe variations in ligand structure and simultaneously measure variations in membrane mechanical properties. We have shown previously that ligand end group has a large impact on ligand structure and membrane mechanical properties. Here we introduce and apply quantitative molecular structure measures to these membranes and extend analysis to multiple nanoparticle core sizes and ligand lengths. Simulations of nanoparticle membranes with amore » nanoparticle core diameter of 4 or 6 nm, a ligand length of 11 or 17 methylenes, and either carboxyl (COOH) or methyl (CH3) ligand end groups are presented. In carboxyl-terminated ligand systems, structure and interactions are dominated by an end-to-end orientation of ligands. In methyl-terminated ligand systems large ordered ligand structures form, but nanoparticle interactions are dominated by disordered, partially interdigitated ligands. Core size and ligand length also affect both ligand arrangement within the membrane and the membrane's macroscopic mechanical response, but are secondary to the role of the ligand end group. Additionally, the particular end group (COOH or CH3) alters the nature of how ligand length, in turn, affects the membrane properties. The effect of core size does not depend on the ligand end group, with larger cores always leading to stiffer membranes. Asymmetry in the stress and ligand density is observed in membranes during preparation at a water-vapor interface, with the stress asymmetry persisting in all membranes after drying.« less

  1. Robust carbon monolith having hierarchical porosity

    DOE Patents [OSTI]

    Dai, Sheng; Guiohon, Georges A; Liang, Chengdu

    2013-02-05

    A carbon monolith includes a robust carbon monolith characterized by a skeleton size of at least 100 nm, and a hierarchical pore structure having macropores and mesopores.

  2. Robust carbon monolith having hierarchical porosity

    DOE Patents [OSTI]

    Dai, Sheng; Guiochon, Georges A; Liang, Chengdu

    2014-01-14

    A carbon monolith includes a robust carbon monolith characterized by a skeleton size of at least 100 nm, and a hierarchical pore structure having macropores and mesopores.

  3. Impact of polymer film thickness and cavity size on polymer flow during embossing : towards process design rules for nanoimprint lithography.

    SciTech Connect (OSTI)

    Schunk, Peter Randall; King, William P. (Georgia Institute of Technology, Atlanta, GA); Sun, Amy Cha-Tien; Rowland, Harry D.

    2006-08-01

    This paper presents continuum simulations of polymer flow during nanoimprint lithography (NIL). The simulations capture the underlying physics of polymer flow from the nanometer to millimeter length scale and examine geometry and thermophysical process quantities affecting cavity filling. Variations in embossing tool geometry and polymer film thickness during viscous flow distinguish different flow driving mechanisms. Three parameters can predict polymer deformation mode: cavity width to polymer thickness ratio, polymer supply ratio, and Capillary number. The ratio of cavity width to initial polymer film thickness determines vertically or laterally dominant deformation. The ratio of indenter width to residual film thickness measures polymer supply beneath the indenter which determines Stokes or squeeze flow. The local geometry ratios can predict a fill time based on laminar flow between plates, Stokes flow, or squeeze flow. Characteristic NIL capillary number based on geometry-dependent fill time distinguishes between capillary or viscous driven flows. The three parameters predict filling modes observed in published studies of NIL deformation over nanometer to millimeter length scales. The work seeks to establish process design rules for NIL and to provide tools for the rational design of NIL master templates, resist polymers, and process parameters.

  4. The effect of continuous H2S exposure on the performance of thick palladium-copper alloy membranes (book chapter)

    SciTech Connect (OSTI)

    Howard, B.H.; Cugini, A.V.; Killmeyer, R.P.; Morreale, B.D.; Enick, R.M.

    2007-03-01

    Membranes fabricated from Pd-Cu alloys containing 80, 60, and 53wt%Pd, as well as pure Pd, were exposed to flowing 1000 ppm H2S in H2 over the temperature range of 350 to 900C using three approaches to verify NETL's previously reported transient H2S exposure results. 100 um thick braze-mounted foils failed prior to 600C due to apparent sulfur attack at the braze. 1000 um thick welded membranes demonstrated similar trends as found using the transient method in that hydrogen flux through the Pd-Cu alloys with fcc structure was not significantly degraded by H2S exposure. However, both of these experimental methods suffered from possible disadvantages. The transient method had limited H2S availability and limited exposure duration, and in the 1000 um steady-state test, bulk diffusion limitations could mask effects resulting from H2S exposure. Preliminary results obtained using an alternative membrane mounting method and test protocol for steady-state testing of 100 um thick Pd and 80wt%Pd-Cu foils at 350C showed that significant flux losses occurred on exposure to flowing 1000 ppm H2S in H2, contrary to the earlier studies. Characterization showed that relatively thick sulfide layers had developed on the membrane surfaces during the 120 hours of exposure.

  5. Final Report: Depth-specific Hydraulic Testing of Yucca Flat and Frenchman Flat Environmental Restoration Wells, FY 2003

    SciTech Connect (OSTI)

    Oberlander, Phil; Russell, Charles

    2004-03-09

    Borehole flow logging contributes a greater understanding of subsurface conditions than measuring well discharge only at land surface. Combining the results of up to nine borehole flow logs to estimate hydraulic conductivity with depth includes data averaging over vertical intervals and averaging of calculated hydraulic conductivities among the various flow logs. Data filtering is also necessary to aid in differentiating between changes in borehole flow rate due to flow turbulence (and other causes) and those associated with groundwater inflow. Borehole flow logging during well pumping has provided the quantity of groundwater iniflow and hydraulic conductivity at depth for three wells. The results provided are believed to be an appropriate balance between predictive accuracy and preserving spatial resolution.

  6. Single-vortex pinning and penetration depth in superconducting NdFeAsO1-xFx

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhang, Jessie T.; Kim, Jeehoon; Huefner, Magdalena; Ye, Cun; Kim, Stella; Canfield, Paul C.; Prozorov, Ruslan; Auslaender, Ophir M.; Hoffman, Jennifer E.

    2015-10-12

    We use a magnetic force microscope (MFM) to investigate single vortex pinning and penetration depth in NdFeAsO1-xFx, one of the highest-Tc iron-based superconductors. In fields up to 20 Gauss, we observe a disordered vortex arrangement, implying that the pinning forces are stronger than the vortex-vortex interactions. We measure the typical force to depin a single vortex, Fdepin ≃ 4.5 pN, corresponding to a critical current up to Jc ≃ 7×105 A/cm2. As a result, our MFM measurements allow the first local and absolute determination of the superconducting in-plane penetration depth in NdFeAsO1-xFx, λab = 320 ± 60 nm, which ismore » larger than previous bulk measurements.« less

  7. Soil bacterial and fungal community responses to nitrogen addition across soil depth and microhabitat in an arid shrubland

    SciTech Connect (OSTI)

    Mueller, Rebecca C.; Belnap, Jayne; Kuske, Cheryl R.

    2015-09-04

    Arid shrublands are stressful environments, typified by alkaline soils low in organic matter, with biologically-limiting extremes in water availability, temperature, and UV radiation. The widely-spaced plants and interspace biological soil crusts in these regions provide soil nutrients in a localized fashion, creating a mosaic pattern of plant- or crust-associated microhabitats with distinct nutrient composition. With sporadic and limited rainfall, nutrients are primarily retained in the shallow surface soil, patterning biological activity. We examined soil bacterial and fungal community responses to simulated nitrogen (N) deposition in an arid Larrea tridentata-Ambrosia dumosa field experiment in southern Nevada, USA, using high-throughput sequencing of ribosomal RNA genes. To examine potential interactions among the N application, microhabitat and soil depth, we sampled soils associated with shrub canopies and interspace biological crusts at two soil depths (00.5 or 010 cm) across the N-amendment gradient (0, 7, and 15 kg ha1 yr1). We hypothesized that localized compositional differences in soil microbiota would constrain the impacts of N addition to a microhabitat distribution that would reflect highly localized geochemical conditions and microbial community composition. The richness and community composition of both bacterial and fungal communities differed significantly by microhabitat and with soil depth in each microhabitat. Only bacterial communities exhibited significant responses to the N addition. Community composition correlated with microhabitat and depth differences in soil geochemical features. Provided the distinct roles of soil bacteria and fungi in major nutrient cycles, the resilience of fungi and sensitivity of bacteria to N amendments suggests that increased N input predicted for many arid ecosystems could shift nutrient cycling toward pathways driven primarily by fungal communities.

  8. Soil bacterial and fungal community responses to nitrogen addition across soil depth and microhabitat in an arid shrubland

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mueller, Rebecca C.; Belnap, Jayne; Kuske, Cheryl R.

    2015-09-04

    Arid shrublands are stressful environments, typified by alkaline soils low in organic matter, with biologically-limiting extremes in water availability, temperature, and UV radiation. The widely-spaced plants and interspace biological soil crusts in these regions provide soil nutrients in a localized fashion, creating a mosaic pattern of plant- or crust-associated microhabitats with distinct nutrient composition. With sporadic and limited rainfall, nutrients are primarily retained in the shallow surface soil, patterning biological activity. We examined soil bacterial and fungal community responses to simulated nitrogen (N) deposition in an arid Larrea tridentata-Ambrosia dumosa field experiment in southern Nevada, USA, using high-throughput sequencing ofmore » ribosomal RNA genes. To examine potential interactions among the N application, microhabitat and soil depth, we sampled soils associated with shrub canopies and interspace biological crusts at two soil depths (0–0.5 or 0–10 cm) across the N-amendment gradient (0, 7, and 15 kg ha–1 yr–1). We hypothesized that localized compositional differences in soil microbiota would constrain the impacts of N addition to a microhabitat distribution that would reflect highly localized geochemical conditions and microbial community composition. The richness and community composition of both bacterial and fungal communities differed significantly by microhabitat and with soil depth in each microhabitat. Only bacterial communities exhibited significant responses to the N addition. Community composition correlated with microhabitat and depth differences in soil geochemical features. Provided the distinct roles of soil bacteria and fungi in major nutrient cycles, the resilience of fungi and sensitivity of bacteria to N amendments suggests that increased N input predicted for many arid ecosystems could shift nutrient cycling toward pathways driven primarily by fungal communities.« less

  9. EVALUATION OF FROST HEAVE ON WASTE TRANSFER LINES WITH SHALLOW DEPTHS IN DST (DOUBLE SHELL TANK) FARMS

    SciTech Connect (OSTI)

    HAQ MA

    2009-05-12

    The purpose of this document is to evaluate the effect of frost heave on waste transfer lines with shallow depths in DST farms. Because of the insulation, well compacted sandy material around waste transfer lines, the type of sandy and gravel soil, and relatively low precipitation at Hanford site, it is concluded that waste transfer lines with one foot of soil covers (sandy cushion material and insulation) are not expected to undergo frost heave damaging effects.

  10. Thick Thermal Barrier Coatings (TTBCs) for Low Emission, High Efficiency Diesel Engine Components

    SciTech Connect (OSTI)

    M. Brad Beardsley, Caterpillar Inc.; Dr. Darrell Socie, University of Illinois; Dr. Ed Redja, University of Illinois; Dr. Christopher Berndt, State University of New York at Stony Brook

    2006-03-02

    The objective of this program was to advance the fundamental understanding of thick thermal barrier coating (TTBC) systems for application to low heat rejection diesel engine combustion chambers. Previous reviews of thermal barrier coating technology concluded that the current level of understanding of coating system behavior is inadequate and the lack of fundamental understanding may impede the application of thermal barrier coating to diesel engines.(1) Areas of TTBC technology examined in this program include powder characteristics and chemistry; bond coating composition, coating design, microstructure and thickness as they affect properties, durability, and reliability; and TTBC "aging" effects (microstructural and property changes) under diesel engine operating conditions. Fifteen TTBC ceramic powders were evaluated. These powders were selected to investigate the effects of different chemistries, different manufacturing methods, lot-to-lot variations, different suppliers and varying impurity levels. Each of the fifteen materials has been sprayed using 36 parameters selected by a design of experiments (DOE) to determine the effects of primary gas (Ar and N2), primary gas flow rate, voltage, arc current, powder feed rate, carrier gas flow rate, and spraying distance. The deposition efficiency, density, and thermal conductivity of the resulting coatings were measured. A coating with a high deposition efficiency and low thermal conductivity is desired from an economic standpoint. An optimum combination of thermal conductivity and disposition efficiency was found for each lot of powder in follow-on experiments and disposition parameters were chosen for full characterization.(2) Strengths of the optimized coatings were determined using 4-point bending specimens. The tensile strength was determined using free-standing coatings made by spraying onto mild steel substrates which were subsequently removed by chemical etching. The compressive strengths of the coatings were determined using composite specimens of ceramic coated onto stainless steel substrates, tested with the coating in compression and the steel in tension. The strength of the coating was determined from an elastic bi-material analysis of the resulting failure of the coating in compression.(3) Altough initial comparisons of the materials would appear to be straight forward from these results, the results of the aging tests of the materials are necessary to insure that trends in properties remain after long term exposure to a diesel environment. Some comparisons can be made, such as the comparison between for lot-to-lot variation. An axial fatigue test to determine the high cycle fatigue behavior of TTBCs was developed at the University of Illinois under funding from this program.(4) A fatigue test apparatus has been designed and initial work performed which demonstrates the ability to provide a routine method of axial testing of coating. The test fixture replaces the normal load frame and fixtures used to transmit the hydraulic oil loading to the sample with the TTBC specimen itself. The TTBC specimen is a composite metal/coating with stainless steel ends. The coating is sprayed onto a mild steel center tube section onto which the stainless steel ends are press fit. The specimen is then machined. After machining, the specimen is placed in an acid bath which etches the mild steel away leaving the TTBC attached to the the stainless steel ends. Plugs are then installed in the ends and the composite specimen loaded in the test fixture where the hydraulic oil pressurizes each end to apply the load. Since oil transmits the load, bending loads are minimized. This test fixture has been modified to allow piston ends to be attached to the specimen which allows tensile loading as well as compressive loading of the specimen. In addition to the room temperature data, specimens have been tested at 800 Degrees C with the surprising result that at high temperature, the TTBC exhibits much higher fatigue strength. Testing of the TTBC using tension/compression cycling has been conducted using the modified test fixture. The goal of this work was to investigate the failure mechanisms of the coating and to determine if tensile and compressive fatigue damage would interact to influence the resulting life of the coating. Coating samples were run with various mean compressive loads and constant tensile loading approximately equal to 90% of the tensile strength of the coating. The results of this testing shows no interaction of failure resulting from the tensile and compressive load. The material fails in tension at the life predicted by the maximum tensile stress or in compression at the life predicted by the compressive stress. This indicates that there are two differing failure mechanisms for the TTBC in tension and compression.

  11. 3-D Deep Penetration Neutron Imaging of Thick Absorgin and Diffusive Objects Using Transport Theory

    SciTech Connect (OSTI)

    Ragusa, Jean; Bangerth, Wolfgang

    2011-08-01

    A current area of research interest in national security is to effectively and efficiently determine the contents of the many shipping containers that enter ports in the United States. This interest comes as a result of the 9/11 Commission Act passed by Congress in 2007 that requires 100% of inbound cargo to be scanned by 2012. It appears that this requirement will be achieved by 2012, but as of February of 2009 eighty percent of the 11.5 million inbound cargo containers were being scanned. The systems used today in all major U.S. ports to determine the presence of radioactive material within cargo containers are Radiation Portal Monitors (RPM). These devices generally exist in the form of a gate or series of gates that the containers can be driven through and scanned. The monitors are effective for determining the presence of radiation, but offer little more information about the particular source. This simple pass-fail system leads to many false alarms as many everyday items emit radiation including smoke detectors due to the Americium-241 source contained inside, bananas, milk, cocoa powder and lean beef due to the trace amounts of Potassium-40, and fire brick and kitty litter due to their high clay content which often contains traces of uranium and thorium. In addition, if an illuminating source is imposed on the boundary of the container, the contents of the container may become activated. These materials include steel, aluminum and many agricultural products. Current portal monitors also have not proven to be that effective at identifying natural or highly enriched uranium (HEU). In fact, the best available Advanced Spectroscopic Portal Monitors (ASP) are only capable of identifying bare HEU 70-88% of the time and masked HEU and depleted uranium (DU) only 53 percent of the time. Therefore, a better algorithm that uses more information collected from better detectors about the specific material distribution within the container is desired. The work reported here explores the inverse problem of optical tomography applied to heterogeneous domains. The neutral particle transport equation was used as the forward model for how neutral particles stream through and interact within these heterogeneous domains. A constrained optimization technique that uses Newtons method served as the basis of the inverse problem. Optical tomography aims at reconstructing the material properties using (a) illuminating sources and (b) detector readings. However, accurate simulations for radiation transport require that the particle (gamma and/or neutron) energy be appropriate discretize in the multigroup approximation. This, in turns, yields optical tomography problems where the number of unknowns grows (1) about quadratically with respect to the number of energy groups, G, (notably to reconstruct the scattering matrix) and (2) linearly with respect to the number of unknown material regions. As pointed out, a promising approach could rely on algorithms to appropriately select a material type per material zone rather than G2 values. This approach, though promising, still requires further investigation: (a) when switching from cross-section values unknowns to material type indices (discrete integer unknowns), integer programming techniques are needed since derivative information is no longer available; and (b) the issue of selecting the initial material zoning remains. The work reported here proposes an approach to solve the latter item, whereby a material zoning is proposed using one-group or few-groups transport approximations. The capabilities and limitations of the presented method were explored; they are briefly summarized next and later described in fuller details in the Appendices. The major factors that influenced the ability of the optimization method to reconstruct the cross sections of these domains included the locations of the sources used to illuminate the domains, the number of separate experiments used in the reconstruction, the locations where measurements were collected, the optical thickness of the domain, the amount of sign

  12. The Dependence of the Strength and Thickness of Field-Aligned Currents on Solar Wind and Ionospheric Parameters

    SciTech Connect (OSTI)

    Johnson, Jay R.; Wing, Simon

    2014-08-01

    Sheared plasma flows at the low-latitude boundary layer correlate well with early afternoon auroral arcs and #12;eld-aligned currents [Sonnerup, 1980; Lundin and Evans, 1985]. We present a simple analytic model that relates solar wind and ionospheric parameters to the strength and thickness of field-aligned currents in a region of sheared velocity, such as the low latitude boundary layer. We compare the predictions of the model with DMSP observations and #12;nd remarkably good scaling of the currents with solar wind and ionospheric parameters. The sheared boundary layer thickness is inferred to be around 3000km consistent with observational studies. The analytic model provides a simple way to organize data and to infer boundary layer structures from ionospheric data.

  13. Rotational Augmentation on a 2.3 MW Rotor Blade with Thick Flatback Airfoil Cross-Sections: Preprint

    SciTech Connect (OSTI)

    Schreck, S.; Fingersh, L.; Siegel, K.; Singh, M.; Medina, P.

    2013-01-01

    Rotational augmentation was analyzed for a 2.3 MW wind turbine, which was equipped with thick flatback airfoils at inboard radial locations and extensively instrumented for acquisition of time varying surface pressures. Mean aerodynamic force and surface pressure data were extracted from an extensive field test database, subject to stringent criteria for wind inflow and turbine operating conditions. Analyses of these data showed pronounced amplification of aerodynamic forces and significant enhancements to surface pressures in response to rotational influences, relative to two-dimensional, stationary conditions. Rotational augmentation occurrence and intensity in the current effort was found to be consistent with that observed in previous research. Notably, elevated airfoil thickness and flatback design did not impede rotational augmentation.

  14. CONSTRAINTS ON COMPTON-THICK WINDS FROM BLACK HOLE ACCRETION DISKS: CAN WE SEE THE INNER DISK?

    SciTech Connect (OSTI)

    Reynolds, Christopher S.

    2012-11-01

    Strong evidence is emerging that winds can be driven from the central regions of accretion disks in both active galactic nuclei and Galactic black hole binaries. Direct evidence for highly ionized, Compton-thin inner-disk winds comes from observations of blueshifted (v {approx} 0.05-0.1c) iron-K X-ray absorption lines. However, it has been suggested that the inner regions of black hole accretion disks can also drive Compton-thick winds-such winds would enshroud the inner disk, preventing us from seeing direct signatures of the accretion disk (i.e., the photospheric thermal emission, or the Doppler/gravitationally broadened iron K{alpha} line). Here, we show that, provided the source is sub-Eddington, the well-established wind-driving mechanisms fail to launch a Compton-thick wind from the inner disk. For the accelerated region of the wind to be Compton-thick, the momentum carried in the wind must exceed the available photon momentum by a factor of at least 2/{lambda}, where {lambda} is the Eddington ratio of the source, ruling out radiative acceleration unless the source is very close to the Eddington limit. Compton-thick winds also carry large mass fluxes, and a consideration of the connections between the wind and the disk shows this to be incompatible with magneto-centrifugal driving. Finally, thermal driving of the wind is ruled out on the basis of the large Compton radii that typify black hole systems. In the absence of some new acceleration mechanisms, we conclude that the inner regions of sub-Eddington accretion disks around black holes are indeed naked.

  15. Assessment of Barotrauma Resulting from Rapid Decompression of Depth Acclimated Juvenile Chinook Salmon Bearing Radio Telemetry Transmitters

    SciTech Connect (OSTI)

    Brown, Richard S.; Carlson, Thomas J.; Welch, Abigail E.; Stephenson, John R.; Abernethy, Cary S.; McKinstry, Craig A.; Theriault, Marie-Helene

    2007-09-06

    A multifactor study was conducted by Battelle for the US Army Corps of Engineers to assess the significance of the presence of a radio telemetry transmitter on the effects of rapid decompression from simulated hydro turbine passage on depth acclimated juvenile run-of-the-river Chinook salmon. Study factors were: (1) juvenile chinook salmon age;, subyearling or yearling, (2) radio transmitter present or absent, (3) three transmitter implantation factors: gastric, surgical, and no transmitter, and (4) four acclimation depth factors: 1, 10, 20, and 40 foot submergence equivalent absolute pressure, for a total of 48 unique treatments. Exposed fish were examined for changes in behavior, presence or absence of barotrauma injuries, and immediate or delayed mortality. Logistic models were used to test hypotheses that addressed study objectives. The presence of a radio transmitter was found to significantly increase the risk of barotrauma injury and mortality at exposure to rapid decompression. Gastric implantation was found to present a higher risk than surgical implantation. Fish were exposed within 48 hours of transmitter implantation so surgical incisions were not completely healed. The difference in results obtained for gastric and surgical implantation methods may be the result of study design and the results may have been different if tested fish had completely healed surgical wounds. However, the test did simulate the typical surgical-release time frame for in-river telemetry studies of fish survival so the results are probably representative for fish passing through a turbine shortly following release into the river. The finding of a significant difference in response to rapid decompression between fish bearing radio transmitters and those not implies a bias may exist in estimates of turbine passage survival obtained using radio telemetry. However, the rapid decompression (simulated turbine passage) conditions used for the study represented near worst case exposure for fish passing through turbines. At this time, insufficient data exist about the distribution of river-run fish entering turbines, and particularly, the distribution of fish passing through turbine runners, to extrapolate study findings to the population of fish passing through FCRPS turbines. This study is the first study examining rapid decompression study to include acclimation depth as an experimental factor for physostomous fish. We found that fish acclimated to deeper depth were significantly more vulnerable to barotrauma injury and death. Insufficient information about the distribution of fish entering turbines and their depth acclimation currently exists to extrapolate these findings to the population of fish passing through turbines. However, the risk of barotrauma for turbine-passed fish could be particularly high for subyearling Chinook salmon that migrate downstream at deeper depths late in the early summer portion of the outmigration. Barotrauma injuries led to immediate mortality delayed mortality and potential mortality due to increased susceptibility to predation resulting from loss of equilibrium or swim bladder rupture.

  16. The change of microstructure and thermal properties in ion irradiated carbon nanotube mats as a function of ion penetration depth

    SciTech Connect (OSTI)

    Aitkaliyeva, A. [Materials Science and Engineering Program, Texas A and M University, College Station, Texas 77843 (United States)] [Materials Science and Engineering Program, Texas A and M University, College Station, Texas 77843 (United States); Shao, L. [Materials Science and Engineering Program, Texas A and M University, College Station, Texas 77843 (United States) [Materials Science and Engineering Program, Texas A and M University, College Station, Texas 77843 (United States); Department of Nuclear Engineering, Texas A and M University, College Station, Texas 77843 (United States)

    2013-02-11

    A stack of three carbon nanotube (CNT) mats was irradiated with 3 MeV He ions. The change in structural and thermal properties of individual mats as a function of ion penetration depth was characterized using electron microscopy and laser flash techniques. Ion irradiation can enhance thermal conductivity of the mats by introducing inter-tube displacements, which improve phonon transport across adjacent nanotubes. The enhancement, however, is reduced at higher damage levels due to the increasing phonon-defect scattering within the tubes. This study demonstrates the feasibility of using ion irradiation to manipulate thermal transport in carbon nanotubes.

  17. Unit-cell thick BaTiO{sub 3} blocks octahedral tilt propagation across oxide heterointerface

    SciTech Connect (OSTI)

    Kan, Daisuke Aso, Ryotaro; Kurata, Hiroki; Shimakawa, Yuichi

    2014-05-14

    We fabricated SrRuO{sub 3}/BaTiO{sub 3}/GdScO{sub 3} heterostructures in which the BaTiO{sub 3} layer is one unit cell thick by pulsed laser deposition and elucidated how the BaTiO{sub 3} layer influences structural and magneto-transport properties of the SrRuO{sub 3} layer through octahedral connections across the heterointerface. Our X-ray-diffraction-based structural characterizations show that while an epitaxial SrRuO{sub 3} layer grown directly on a GdScO{sub 3} substrate is in the monoclinic phase with RuO{sub 6} octahedral tilts, a one-unit-cell-thick BaTiO{sub 3} layer inserted between SrRuO{sub 3} and GdScO{sub 3} stabilizes the tetragonal SrRuO{sub 3} layer with largely reduced RuO{sub 6} tilts. Our high-angle annular dark-field and annular bright-field scanning transmission electron microscopy observations provide an atomic-level view of the octahedral connections across the heterostructure and reveal that the BaTiO{sub 3} layer only one unit cell thick is thick enough to stabilize the RuO{sub 6}-TiO{sub 6} octahedral connections with negligible in-plane oxygen atomic displacements. This results in no octahedral tilts propagating into the SrRuO{sub 3} layer and leads to the formation of a tetragonal SrRuO{sub 3} layer. The magneto-transport property characterizations also reveal a strong impact of the octahedral connections modified by the inserted BaTiO{sub 3} layer on the spin-orbit interaction of the SrRuO{sub 3} layer. The SrRuO{sub 3} layer on BaTiO{sub 3}/ GdScO{sub 3} has in-plane magnetic anisotropy. This is in contrast to the magnetic anisotropy of the monoclinic SrRuO{sub 3} films on the GdScO{sub 3} substrate, in which the easy axis is ?45 to the film surface normal. Our results demonstrate that the one-unit-cell-thick layer of BaTiO{sub 3} can control and manipulate the interfacial octahedral connection closely linked to the structure-property relationship of heterostructures.

  18. Annealing temperature and barrier thickness effect on the structural and optical properties of silicon nanocrystals/SiO₂ superlattices

    SciTech Connect (OSTI)

    López-Vidrier, J. Hernández, S.; López-Conesa, L.; Peiró, F.; Garrido, B.; Hiller, D.; Gutsch, S.; Zacharias, M.; Estradé, S.

    2014-10-07

    The effect of the annealing temperature and the SiO₂ barrier thickness of silicon nanocrystal (NC)/SiO₂ superlattices (SLs) on their structural and optical properties is investigated. Energy-filtered transmission electron microscopy (TEM) revealed that the SL structure is maintained for annealing temperatures up to 1150 °C, with no variation on the nanostructure morphology for different SiO₂ barrier thicknesses. Nevertheless, annealing temperatures as high as 1250 °C promote diffusion of Si atoms into the SiO₂ barrier layers, which produces larger Si NCs and the loss of the NC size control expected from the SL approach. Complementary Raman scattering measurements corroborated these results for all the SiO₂ and Si-rich oxynitride layer thicknesses. In addition, we observed an increasing crystalline fraction up to 1250 °C, which is related to a decreasing contribution of the suboxide transition layer between Si NCs and the SiO₂ matrix due to the formation of larger NCs. Finally, photoluminescence measurements revealed that the emission of the superlattices exhibits a Gaussian-like lineshape with a maximum intensity after annealing at 1150 °C, indicating a high crystalline degree in good agreement with Raman results. Samples submitted to higher annealing temperatures display a progressive emission broadening, together with an increase in the central emission wavelength. Both effects are related to a progressive broadening of the size distribution with a larger mean size, in agreement with TEM observations. On the other hand, whereas the morphology of the Si NCs is unaffected by the SiO₂ barrier thickness, the emission properties are slightly modified. These observed modifications in the emission lineshape allow monitoring the precipitation process of Si NCs in a direct non-destructive way. All these experimental results evidence that an annealing temperature of 1150 °C and 1-nm SiO₂ barrier can be reached whilst preserving the SL structure, being thus the optimal structural SL parameters for their use in optoelectronics.

  19. Photochemistry in terrestrial exoplanet atmospheres. III. Photochemistry and thermochemistry in thick atmospheres on super Earths and mini Neptunes

    SciTech Connect (OSTI)

    Hu, Renyu; Seager, Sara

    2014-03-20

    Some super Earths and mini Neptunes will likely have thick atmospheres that are not H{sub 2}-dominated. We have developed a photochemistry-thermochemistry kinetic-transport model for exploring the compositions of thick atmospheres on super Earths and mini Neptunes, applicable for both H{sub 2}-dominated atmospheres and non-H{sub 2}-dominated atmospheres. Using this model to study thick atmospheres for wide ranges of temperatures and elemental abundances, we classify them into hydrogen-rich atmospheres, water-rich atmospheres, oxygen-rich atmospheres, and hydrocarbon-rich atmospheres. We find that carbon has to be in the form of CO{sub 2} rather than CH{sub 4} or CO in a H{sub 2}-depleted water-dominated thick atmosphere and that the preferred loss of light elements from an oxygen-poor carbon-rich atmosphere leads to the formation of unsaturated hydrocarbons (C{sub 2}H{sub 2} and C{sub 2}H{sub 4}). We apply our self-consistent atmosphere models to compute spectra and diagnostic features for known transiting low-mass exoplanets GJ 1214 b, HD 97658 b, and 55 Cnc e. For GJ 1214 b, we find that (1) C{sub 2}H{sub 2} features at 1.0 and 1.5 ?m in transmission and C{sub 2}H{sub 2} and C{sub 2}H{sub 4} features at 9-14 ?m in thermal emission are diagnostic for hydrocarbon-rich atmospheres; (2) a detection of water-vapor features and a confirmation of the nonexistence of methane features would provide sufficient evidence for a water-dominated atmosphere. In general, our simulations show that chemical stability has to be taken into account when interpreting the spectrum of a super Earth/mini Neptune. Water-dominated atmospheres only exist for carbon to oxygen ratios much lower than the solar ratio, suggesting that this kind of atmospheres could be rare.

  20. Focusing of dipole radiation by a negative index chiral layer. 1. A thick layer as compared with the wavelength

    SciTech Connect (OSTI)

    Guzatov, D V; Klimov, V V

    2014-09-30

    We have derived and investigated the analytical expressions for the fields of scattered radiation of an electric dipole source by a chiral (bi-isotropic) layer with arbitrary permittivity and permeability and arbitrary thickness. It is shown that in the negativeindex chiral layer the focus spot of dipole radiation is split due to excitation of right- and left-hand circularly polarised waves. The conditions are found under which the waves with one of the polarisations can be suppressed, which leads to a substantial improvement of the focusing properties of the chiral layer. (metamaterials)

  1. Laser-ultrasound spectroscopy apparatus and method with detection of shear resonances for measuring anisotropy, thickness, and other properties

    DOE Patents [OSTI]

    Levesque, Daniel (Terrebonne, CA); Moreau, Andre (St-Bruno-de-Montarville, CA); Dubois, Marc (Montreal, CA); Monchalin, Jean-Pierre (Montreal, CA); Bussiere, Jean (St-Bruno, CA); Lord, Martin (Beloeil, CA); Padioleau, Christian (Montreal, CA)

    2000-01-01

    Apparatus and method for detecting shear resonances includes structure and steps for applying a radiation pulse from a pulsed source of radiation to an object to generate elastic waves therein, optically detecting the elastic waves generated in the object, and analyzing the elastic waves optically detected in the object. These shear resonances, alone or in combination with other information, may be used in the present invention to improve thickness measurement accuracy and to determine geometrical, microstructural, and physical properties of the object. At least one shear resonance in the object is detected with the elastic waves optically detected in the object. Preferably, laser-ultrasound spectroscopy is utilized to detect the shear resonances.

  2. A Bayesian inversion framework for yield and height-of-burst/depth-of-burial for near-surface explosions

    SciTech Connect (OSTI)

    Johannesson, Gardar; Bulaevskaya, Vera; Ramirez, Abe; Ford, Sean; Rodgers, Artie

    2015-09-07

    A Bayesian inversion framework is presented to estimate the yield of an explosion and height-of-burst/depth-of-burial (HOB/DOB) using seismic and air pressure data. This is accomplished by first calibrating the parameters in the forward models that relate the observations to the yield and HOB/DOB and then using the calibrated model to estimate yield and HOB/DOB associated with a new set of seismic and air pressure observations. The MCMC algorithms required to perform these steps are outlined, and the results with real data are shown. Finally, an extension is proposed for a case when clustering in the seismic displacement occurs as a function of different types of rock and other factors.

  3. Spatially resolved penetration depth measurements and vortex manipulation in the ferromagnetic superconductor ErNi2B2C

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wulferding, Dirk; Yang, Ilkyu; Yang, Jinho; Lee, Minkyung; Choi, Hee Cheul; Bud'ko, Sergey L.; Canfield, Paul C.; Yeom, Han Woong; Kim, Jeehoon

    2015-07-31

    We present a local probe study of the magnetic superconductor ErNi2B2C, using magnetic force microscopy at sub-Kelvin temperatures. ErNi2B2C is an ideal system to explore the effects of concomitant superconductivity and ferromagnetism. At 500 mK, far below the transition to a weakly ferromagnetic state, we directly observe a structured magnetic background on the micrometer scale. We determine spatially resolved absolute values of the magnetic penetration depth λ and study its temperature dependence as the system undergoes magnetic phase transitions from paramagnetic to antiferromagnetic, and to weak ferromagnetic, all within the superconducting regime. We estimate the absolute pinning force of Abrikosovmore » vortices, which shows a position dependence and temperature dependence as well, and discuss the possibility of the purported spontaneous vortex formation.« less

  4. Measurement of the Depth of Maximum of Extensive Air Showers above 10^18 eV

    SciTech Connect (OSTI)

    Abraham, J.; Abreu, P.; Aglietta, M.; Ahn, E.J.; Allard, D.; Allekotte, I.; Allen, J.; Alvarez-Muniz, J.; Ambrosio, M.; Anchordoqui, L.; Andringa, S.; /Lisbon, IST /Boskovic Inst., Zagreb

    2010-02-01

    We describe the measurement of the depth of maximum, X{sub max}, of the longitudinal development of air showers induced by cosmic rays. Almost 4000 events above 10{sup 18} eV observed by the fluorescence detector of the Pierre Auger Observatory in coincidence with at least one surface detector station are selected for the analysis. The average shower maximum was found to evolve with energy at a rate of (106{sub -21}{sup +35}) g/cm{sup 2}/decade below 10{sup 18.24 {+-} 0.05}eV, and (24 {+-} 3) g/cm{sup 2}/decade above this energy. The measured shower-to-shower fluctuations decrease from about 55 to 26 g/cm{sup 2}. The interpretation of these results in terms of the cosmic ray mass composition is briefly discussed.

  5. Depth-dependent Vertical-to-Horizontal (V/H) Ratios of Free-Field Ground Motion Response Spectra for Deeply Embedded Nuclear Structures

    SciTech Connect (OSTI)

    Wei X.; Braverman J.; Miranda, M.; Rosario, M.E.; Costantino, C.J.

    2015-02-25

    This report documents the results of a study to determine the depth-dependent V/H ratios of ground motion response spectra in the free field. The V/H ratios reported herein were developed from a worldwide database of surface and downhole acceleration recordings obtained from 45 vertical array stations. This database was specifically compiled for this project, and includes information from a diversity of active tectonic regions (California, Alaska, Taiwan, Japan), site conditions (rock to soft soil), ground motion intensity levels (PGAs between 0.01 g and 0.50 g), magnitudes (between ML 2.78 and JMA 8.1), epicentral distances (between 3.2 km and 812 km), and source depths (between 1.2 km and 112 km), as well as sensors at surface and at a wide range of depths relevant to the project. To study the significance of the depth effect, V/H ratios from all the records were sorted into a number of depth bins relevant to the project, and statistics (average, standard deviation, coefficient of variation, 16th, 50th, and 84th percentiles) of the V/H ratios within each bin were computed. Similar analyses were repeated, controlling for different site conditions, ground motion intensity levels, array locations, and source depths, to study their relative effect on the V/H ratios. Our findings confirm the importance of the depth effect on the V/H ratios. The research findings in this report can be used to provide guidance on the significance of the depth effect, and the extent to which this effect should be considered in the seismic design of deeply embedded SMR structures and NPP structures in general.

  6. Niamey Aerosol Optical Depths

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Flynn, Connor

    2008-10-01

    MFRSR irradiance data collected during the ACRF AMF deployment in Niamey, Niger have been used to derive AOD for five wavelength channels of the MFRSR. These data have been corrected to adjust for filter drift over the course of the campaign and contamination due to forward scattering as a result of large dust particles in the atmosphere around Niamey.

  7. Strain-relaxation and critical thickness of epitaxial La1.85Sr0.15CuO4 films

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Meyer, Tricia L; Jiang, Lu; Park, Sungkyun; Egami, Takeshi; Lee, Ho Nyung

    2015-12-08

    We report the thickness-dependent strain-relaxation behavior and the associated impacts upon the superconductivity in epitaxial La1.85Sr0.15CuO4 films grown on different substrates, which provide a range of strain. We have found that the critical thickness for the onset of superconductivity in La1.85Sr0.15CuO4 films is associated with the finite thickness effect and epitaxial strain. In particular, thin films with tensile strain greater than ~0.25% revealed no superconductivity. We attribute this phenomenon to the inherent formation of oxygen vacancies that can be minimized via strain relaxation.

  8. Bell-Plesset effects in Rayleigh-Taylor instability of finite-thickness spherical and cylindrical shells

    SciTech Connect (OSTI)

    Velikovich, A. L.; Schmit, P. F.

    2015-12-28

    Bell-Plesset (BP) effects account for the influence of global convergence or divergence of the fluid flow on the evolution of the interfacial perturbations embedded in the flow. The development of the Rayleigh-Taylor instability in radiation-driven spherical capsules and magnetically-driven cylindrical liners necessarily includes a significant contribution from BP effects due to the time dependence of the radius, velocity, and acceleration of the unstable surfaces or interfaces. An analytical model is presented that, for an ideal incompressible fluid and small perturbation amplitudes, exactly evaluates the BP effects in finite-thickness shells through acceleration and deceleration phases. The time-dependent dispersion equations determining the “instantaneous growth rate” are derived. It is demonstrated that by integrating this approximate growth rate over time, one can accurately evaluate the number of perturbation e-foldings during the inward acceleration phase of the implosion. As a result, in the limit of small shell thickness, exact thin-shell perturbationequations and approximate thin-shell dispersion equations are obtained, generalizing the earlier results [E. G. Harris, Phys. Fluids 5, 1057 (1962); E. Ott, Phys. Rev. Lett. 29, 1429 (1972); A. B. Bud'ko et al., Phys. Fluids B 2, 1159 (1990)].

  9. Bell-Plesset effects in Rayleigh-Taylor instability of finite-thickness spherical and cylindrical shells

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Velikovich, A. L.; Schmit, P. F.

    2015-12-28

    Bell-Plesset (BP) effects account for the influence of global convergence or divergence of the fluid flow on the evolution of the interfacial perturbations embedded in the flow. The development of the Rayleigh-Taylor instability in radiation-driven spherical capsules and magnetically-driven cylindrical liners necessarily includes a significant contribution from BP effects due to the time dependence of the radius, velocity, and acceleration of the unstable surfaces or interfaces. An analytical model is presented that, for an ideal incompressible fluid and small perturbation amplitudes, exactly evaluates the BP effects in finite-thickness shells through acceleration and deceleration phases. The time-dependent dispersion equations determining themore » “instantaneous growth rate” are derived. It is demonstrated that by integrating this approximate growth rate over time, one can accurately evaluate the number of perturbation e-foldings during the inward acceleration phase of the implosion. As a result, in the limit of small shell thickness, exact thin-shell perturbationequations and approximate thin-shell dispersion equations are obtained, generalizing the earlier results [E. G. Harris, Phys. Fluids 5, 1057 (1962); E. Ott, Phys. Rev. Lett. 29, 1429 (1972); A. B. Bud'ko et al., Phys. Fluids B 2, 1159 (1990)].« less

  10. THE RADIAL METALLICITY GRADIENTS IN THE MILKY WAY THICK DISK AS FOSSIL SIGNATURES OF A PRIMORDIAL CHEMICAL DISTRIBUTION

    SciTech Connect (OSTI)

    Curir, A.; Serra, A. L.; Spagna, A.; Lattanzi, M. G.; Re Fiorentin, P.; Diaferio, A.

    2014-04-01

    In this Letter we examine the evolution of the radial metallicity gradient induced by secular processes, in the disk of an N-body Milky Way-like galaxy. We assign a [Fe/H] value to each particle of the simulation according to an initial, cosmologically motivated, radial chemical distribution and let the disk dynamically evolve for ∼6 Gyr. This direct approach allows us to take into account only the effects of dynamical evolution and to gauge how and to what extent they affect the initial chemical conditions. The initial [Fe/H] distribution increases with R in the inner disk up to R ≈ 10 kpc and decreases for larger R. We find that the initial chemical profile does not undergo major transformations after ∼6 Gyr of dynamical evolution. The final radial chemical gradients predicted by the model in the solar neighborhood are positive and of the same order as those recently observed in the Milky Way thick disk. We conclude that (1) the spatial chemical imprint at the time of disk formation is not washed out by secular dynamical processes and (2) the observed radial gradient may be the dynamical relic of a thick disk originated from a stellar population showing a positive chemical radial gradient in the inner regions.

  11. Outdoor Testing of GaInP2/GaAs Tandem Cells with Top Cell Thickness Varied

    SciTech Connect (OSTI)

    McMahon, W. E.; Emergy, K. E.; Friedman, D. J.; Ottoson, L.; Young, M. S.; Ward, J. S.; Kramer, C. M.; Duda, A.; Kurtz, S.

    2005-08-01

    In this study, we measure the performance of GaInP2/GaAs tandem cells under direct beam sunlight outdoors in order to quantify their sensitivity to both spectral variation and GaInP2 top-cell thickness. A set of cells with five different top-cell thicknesses was mounted on a two-axis tracker with the incident sunlight collimated to exclude all except the direct beam. Current-voltage (I-V) curves were taken throughout the course of several days, along with measurements of the direct solar spectrum. Our two major conclusions are: (1) GaInP2/GaAs tandem cells designed for either the ASTM G-173 direct (G-173D) spectrum or the "air mass 1.5 global" (AM1.5G) spectrum perform the best, and (2) cells can be characterized indoors and modeled using outdoor spectra with the same result. These results are equally valid for GaInP2/GaAs/Ge triple-junction cells.

  12. Reduced Cu(InGa)Se2 Thickness in Solar Cells Using a Superstrate Configuration

    SciTech Connect (OSTI)

    Shafarman, William N.

    2015-03-30

    This project by the Institute of Energy Conversion (IEC) and the Department of Electrical and Computer Engineering at the University of Delaware sought to develop the technology and underlying science to enable reduced cost of Cu(InGa)Se2 manufacturing by reducing the thickness of the Cu(InGa)Se2 absorber layer by half compared to typical production. The approach to achieve this was to use the superstrate cell configuration in which light is incident on the cell through the glass. This structure facilitates optical enhancement approaches needed to achieve high efficiency with Cu(InGa)Se2 thicknesses less than 1 m. The primary objective was to demonstrate a Cu(InGa)Se2 cell with absorber thickness 0.5 - 0.7 m and 17% efficiency, along with a quantitative loss analysis to define a pathway to 20% efficiency. Additional objectives were the development of stable TCO and buffer layers or contact layers to withstand the Cu(InGa)Se2 deposition temperature and of advanced optical enhancement methods. The underlying fundamental science needed to effectively transition these outcomes to large scale was addressed by extensive materials and device characterization and by development of comprehensive optical models. Two different superstrate configurations have been investigated. A frontwall cell is illuminated through the glass to the primary front junction of the device. This configuration has been used for previous efforts on superstrate Cu(InGa)Se2 but performance has been limited by interdiffusion or reaction with CdS or other buffer layers. In this project, several approaches to overcome these limitations were explored using CdS, ZnO and ZnSe buffer layers. In each case, mechanisms that limit device performance were identified using detailed characterization of the materials and junctions. Due to the junction formation difficulties, efforts were concentrated on a new backwall configuration in which light is incident through the substrate into the back of the absorber layer. The primary junction is then formed after Cu(InGa)Se2 deposition. This allows the potential benefits of superstrate cells for optical enhancement while maintaining processing advantages of the substrate configuration and avoiding the harmful effects of high temperature deposition on p-n junction formation. Backwall devices have outperformed substrate cells at absorber thicknesses of 0.1-0.5 m through enhanced JSC due to easy incorporation of a Ag reflector and, with light incident on the absorber, the elimination of parasitic absorption in the CdS buffer. An efficiency of 9.7% has been achieved for a backwall Cu(InGa)Se2 device with absorber thickness ~0.4 ?m. A critical achievement that enabled implementation of the backwall cell was the development of a transparent back contact using MoO3 or WO3. Processes for controlled deposition of each material by reactive rf sputtering from metal targets were developed. These contacts have wide bandgaps making them well-suited for application as contacts for backwall devices as well as potential use in bifacial cells and as the top cell of tandem CuInSe2-based devices. Optical enhancement will be critical for further improvements. Wet chemical texturing of ZnO films has been developed for a simple, low cost light-trapping scheme for backwall superstrate devices to enhance long wavelength quantum efficiency. An aqueous oxalic acid etch was developed and found to strongly texture sputtered ZnO with high haze ? 0.9 observed across the whole spectrum. And finally, advanced optical models have been developed to assist the characterization and optimization of Cu(InGa)Se2 cells with thin absorbers

  13. Cladding Attachment Over Thick Exterior Insulating Sheathing (Fact Sheet), Building America Case Study: Technology Solutions for New and Existing Homes, Building Technologies Office (BTO)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cladding Attachment Over Thick Exterior Insulating Sheathing Project InformatIon: Project name: Cladding Attachment Over Thick Exterior Insulating Sheathing Partners: Building Science Corporation www.buildingscience.com The Dow Chemical Company www.dow.com James Hardie Building Products www.jameshardie.com Building component: Building envelope component application: New and/or retrofit; Single and/or multifamily Year research conducted: 2011 through 2012 applicable climate Zone(s): All The

  14. Surface and Interface Properties of 10–12 Unit Cells Thick Sputter Deposited Epitaxial CeO 2 Films

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Saraf, L. V.; Wang, C. M.; Engelhard, M. H.; Nachimuthu, P.

    2008-01-01

    Ulmore » trathin and continuous epitaxial films with relaxed lattice strain can potentially maintain more of its bulk physical and chemical properties and are useful as buffer layers. We study surface, interface, and microstructural properties of ultrathin ( ∼ 10–12 unit cells thick) epitaxial ceria films grown on single crystal YSZ substrates. The out-of -plane and in-plane lattice parameters indicate relaxation in the continuous film due to misfit dislocations seen by high-resolution transmission electron microscopy (HRTEM) and substrate roughness of ∼ 1-2 unit cells, confirmed by atomic force microscopy and HRTEM. A combination of secondary sputtering, lattice mismatch, substrate roughness, and surface reduction creating secondary phase was likely the cause of surface roughness which should be reduced to a minimum level for effective use of it as buffer layers.« less

  15. Surface and Interface Properties of 1012 Unit Cells Thick Sputter Deposited Epitaxial CeO2Films

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Saraf, L. V.; Wang, C. M.; Engelhard, M. H.; Nachimuthu, P.

    2008-01-01

    Ultrathin and continuous epitaxial films with relaxed lattice strain can potentially maintain more of its bulk physical and chemical properties and are useful as buffer layers. We study surface, interface, and microstructural properties of ultrathin (?1012 unit cells thick) epitaxial ceria films grown on single crystal YSZ substrates. The out-of -plane and in-plane lattice parameters indicate relaxation in the continuous film due to misfit dislocations seen by high-resolution transmission electron microscopy (HRTEM) and substrate roughness of?1-2 unit cells, confirmed by atomic force microscopy and HRTEM. A combination of secondary sputtering, lattice mismatch, substrate roughness, and surface reduction creating secondary phasemorewas likely the cause of surface roughness which should be reduced to a minimum level for effective use of it as buffer layers.less

  16. Temperature dependent DC electrical conductivity studies of ZnO nanoparticle thick films prepared by simple solution combustion method

    SciTech Connect (OSTI)

    Naveen, C. S. Jayanna, H. S. Lamani, Ashok R. Rajeeva, M. P.

    2014-04-24

    ZnO nanoparticles of different size were prepared by varying the molar ratio of glycine and zinc nitrate hexahydrate as fuel and oxidizer (F/O = 0.8, 1.11, 1.7) by simple solution combustion method. Powder samples were characterized by UV-Visible spectrophotometer, X-ray diffractometer, Scanning electron microscope (SEM). DC electrical conductivity measurements at room temperature and in the temperature range of 313-673K were carried out for the prepared thick films and it was found to increase with increase of temperature which confirms the semiconducting nature of the samples. Activation energies were calculated and it was found that, F/O molar ratio 1.7 has low E{sub AL} (Low temperature activation energy) and high E{sub AH} (High temperature activation energy) compared to other samples.

  17. In-Depth Analysis of Simulation Engine Codes for Comparison with DOE s Roof Savings Calculator and Measured Data

    SciTech Connect (OSTI)

    New, Joshua Ryan; Levinson, Ronnen; Huang, Yu; Sanyal, Jibonananda; Miller, William A.; Mellot, Joe; Childs, Kenneth W.; Kriner, Scott

    2014-06-01

    The Roof Savings Calculator (RSC) was developed through collaborations among Oak Ridge National Laboratory (ORNL), White Box Technologies, Lawrence Berkeley National Laboratory (LBNL), and the Environmental Protection Agency in the context of a California Energy Commission Public Interest Energy Research project to make cool-color roofing materials a market reality. The RSC website and a simulation engine validated against demonstration homes were developed to replace the liberal DOE Cool Roof Calculator and the conservative EPA Energy Star Roofing Calculator, which reported different roof savings estimates. A preliminary analysis arrived at a tentative explanation for why RSC results differed from previous LBNL studies and provided guidance for future analysis in the comparison of four simulation programs (doe2attic, DOE-2.1E, EnergyPlus, and MicroPas), including heat exchange between the attic surfaces (principally the roof and ceiling) and the resulting heat flows through the ceiling to the building below. The results were consolidated in an ORNL technical report, ORNL/TM-2013/501. This report is an in-depth inter-comparison of four programs with detailed measured data from an experimental facility operated by ORNL in South Carolina in which different segments of the attic had different roof and attic systems.

  18. Determination of hydrogen diffusion coefficients in F82H by hydrogen depth profiling with a tritium imaging plate technique

    SciTech Connect (OSTI)

    Higaki, M.; Otsuka, T.; Hashizume, K.; Tokunaga, K.; Ezato, K.; Suzuki, S.; Enoeda, M.; Akiba, M.

    2015-03-15

    Hydrogen diffusion coefficients in a reduced activation ferritic/martensitic steel (F82H) and an oxide dispersion strengthened F82H (ODS-F82H) have been determined from depth profiles of plasma-loaded hydrogen with a tritium imaging plate technique (TIPT) in the temperature range from 298 K to 523 K. Data on hydrogen diffusion coefficients, D, in F82H, are summarized as D [m{sup 2}*s{sup -1}] =1.1*10{sup -7}exp(-16[kJ mol{sup -1}]/RT). The present data indicate almost no trapping effect on hydrogen diffusion due to an excess entry of energetic hydrogen by the plasma loading, which results in saturation of the trapping sites at the surface and even in the bulk. In the case of ODS-F82H, data of hydrogen diffusion coefficients are summarized as D [m{sup 2}*s{sup -1}] =2.2*10{sup -7}exp(-30[kJ mol{sup -1}]/RT) indicating a remarkable trapping effect on hydrogen diffusion caused by tiny oxide particles (Y{sub 2}O{sub 3}) in the bulk of F82H. Such oxide particles introduced in the bulk may play an effective role not only on enhancement of mechanical strength but also on suppression of hydrogen penetration by plasma loading.

  19. Clinal morphological variation along a depth gradient in the living scleractinian reef coral Favia pallida: Effects on perceived evolutionary tempos in the fossil record

    SciTech Connect (OSTI)

    Cuffey, R.J. ); Pachut, J.F. )

    1990-12-01

    The Holocene reef-building coral Favia pallida was sampled at 4.5 m depth increments (to 40 m) from two reefs on Enewetak Atoll to examine intraspecific environmental effects. An exposed outer reef was massive and wall-like, whereas a sheltered lagoonal reef grew as a slender pinnacle. Corallite diameter and growth rate, two attributes retrievable in fossil corals, were measured with data partitioned into shallow (<20 m), intermediate (20 to 29 m), and deep-water (>29 m) subsets. Highly significant differences between depth zone populations were found for both corallite diameters and growth rates in analyses of individual and combined reef data sets. Canonical variates analyses (CVA) separated populations from depth zones along single, highly significant, functions. Centroids and 95% confidence intervals, calculated from CVA scores of colonies in each population, are widely separated for the lagoon reef and combined data sets. Conversely, populations from shallow and intermediate depths on the outer reef display overlapping confidence bars indicative of more gradational morphologic changes. When CV's were used to classify specimens to groups, misassignments of intermediate depth specimens to shallow or deep-water populations underscored the gradational nature of the environment. Completely intergrading populations of Favia pallida collected from different depths can be morphologically separated into statistically distinct groupings. A stratigraphic succession of such morphotypes might be interpreted as abruptly appearing separate species if sampling were not as uniform, systematic, and detailed as was possible on modern reefs. Analyses of evolutionary patterns must carefully assess potential effects of clinal variation if past evolutionary patterns are to be interpreted correctly.

  20. Detecting Fractures Using Technology at High Temperatures and Depths - Geothermal Ultrasonic Fracture Imager (GUFI); 2010 Geothermal Technology Program Peer Review Report

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    7 4.4.1 Detecting Fractures Using Technology at High Temperatures and Depths - Geothermal Ultrasonic Fracture Imager (GUFI) Presentation Number: 015 Investigator: Patterson, Doug (Baker Hughes Oilfield Operations Incorporated) Objectives: To develop an ultrasonic borehole televiewer that can operate at temperatures as high as 300 °C and in depths as great as 10,000 m. Average Overall Score: 3.3/4.0 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 Relevance/ Impact Scientific/ Technical Approach

  1. Electrochemical characteristics of samaria-doped ceria infiltrated strontium-doped LaMnO3 cathodes with varied thickness for yttria-stabilized zirconia electrolytes

    SciTech Connect (OSTI)

    Dong Ding; Mingyang Gonga; Chunchuan Xu; Nicholas Baxter; Yihong Li; John Zondlo; Kirk Gerdes; Xingbo Liu

    2010-11-09

    Samaria-doped ceria (SDC) infiltrated into strontium-doped LaMnO3 (LSM) cathodes with varied cathode thickness on yttria-stabilized zirconia (YSZ) were investigated via symmetrical cell, half cell, and full cell configurations. The results of the symmetrical cells showed that the interfacial polarization resistance (RP) decreased with increasing electrode thickness up to?30#2;m, and further increases in the thickness of the cathode did not cause significant variation of electrode performance. At 800 ?C, the minimum RP was around 0.05#2;cm2. The impedance spectra indicated that three main electrochemical processes existed, possibly corresponding to the oxygen ion incorporation, surface diffusion of oxygen species and oxygen adsorption and dissociation. The DC polarization on the half cells and characterization of the full cells also demonstrated a similar correlation between the electrode performance and the electrode thickness. The peak power densities of the single cells with the 10, 30, and 50-#2;m thick electrodes were 0.63, 1.16 and 1.11Wcm?2, respectively. The exchange current densities under moderate polarization are calculated and possible rate-determining steps are discussed.

  2. Response of flame thickness and propagation speed under intense turbulence in spatially developing lean premixed methaneair jet flames

    SciTech Connect (OSTI)

    Sankaran, Ramanan; Hawkes, Evatt R.; Yoo, Chun Sang; Chen, Jacqueline H.

    2015-06-22

    Direct numerical simulations of three-dimensional spatially-developing turbulent Bunsen flames were performed at three different turbulence intensities. We performed these simulations using a reduced methaneair chemical mechanism which was specifically tailored for the lean premixed conditions simulated here. A planar-jet turbulent Bunsen flame configuration was used in which turbulent preheated methaneair mixture at 0.7 equivalence ratio issued through a central jet and was surrounded by a hot laminar coflow of burned products. The turbulence characteristics at the jet inflow were selected such that combustion occured in the thin reaction zones (TRZ) regime. At the lowest turbulence intensity, the conditions fall on the boundary between the TRZ regime and the corrugated flamelet regime, and progressively moved further into the TRZ regime by increasing the turbulent intensity. The data from the three simulations was analyzed to understand the effect of turbulent stirring on the flame structure and thickness. Furthermore, statistical analysis of the data showed that the thermal preheat layer of the flame was thickened due to the action of turbulence, but the reaction zone was not significantly affected. A global and local analysis of the burning velocity of the flame was performed to compare the different flames. Detailed statistical averages of the flame speed were also obtained to study the spatial dependence of displacement speed and its correlation to strain rate and curvature.

  3. In situ determination of lithium ion cathode/electrolyte thickness and composition as a function of charge

    SciTech Connect (OSTI)

    Baggetto, Loic; Browning, Jim; Tenhaeff, Wyatt E; Keum, Jong Kahk; Wood III, David L; Veith, Gabriel M

    2014-01-01

    In this work we report the first experimental in situ determination of the thickness and estimated composition of a condensed electrode/electrolyte interface at various states of charge for the high voltage Li-ion cathode LiMn1.5Ni0.5O4 by exploiting the power of neutron reflectometry.1 Understanding the electrode/electrolyte interface is critical to developing an understanding of interfacial reactions needed to model transport phenomena and predict more stable electrolytes for electrochemical cells.2,3 However, developing the ability to control interfacial reactions in electrochemical cells is arguably one of the most critical challenges confronting researchers focused on energy storage and conversion reactions as well as liquid phase reactions such as photocatalysts and biomass conversion.2 For example, in electrochemical energy storage systems, such as batteries, the reactions between a solid electrode and a liquid electrolyte can lead to the formation of the solid electrolyte interphase (SEI), which directly mediates the stability, durability and safety of the cell. Controlling these interfacial reactions is essential to developing new, durable, and higher energy storage systems needed in the future.

  4. Welding for testability: An approach aimed at improving the ultrasonic testing of thick-walled austenitic and dissimilar metal welds

    SciTech Connect (OSTI)

    Wagner, Sabine; Dugan, Sandra [Materials Testing Institute University of Stuttgart (MPA), Pfaffenwaldring 32, 70569 Stuttgart (Germany); Barth, Martin; Schubert, Frank; Khler, Bernd [Fraunhofer Institute for Nondestructive Testing, Dresden Branch (IZFP-D), Maria-Reiche-Str. 2, 01109 Dresden (Germany)

    2014-02-18

    Austenitic and dissimilar welds in thick walled components show a coarse grained, dendritic microstructure. Therefore, ultrasonic testing has to deal with beam refraction, scattering and mode conversion effects. As a result, the testing techniques typically applied for isotropic materials yield dissatisfying results. Most approaches for improvement of ultrasonic testing have been based on modeling and improved knowledge of the complex wave propagation phenomena. In this paper, we discuss an alternative approach: is it possible to use a modified welding technology which eliminates the cause of the UT complications, i.e. the large-grained structure of the weld seams? Various modification parameters were tested, including: TIG current pulsing, additional DC and AC magnetic fields, and also additional external vibrations during welding. For all welds produced under different conditions, the grain structure of the weld seam was characterized by optical and GIUM microstructure visualizations on cross sections, wave field propagation measurements, and ultrasonic tests of correct detectability of flaws. The mechanical properties of the welds were also tested.

  5. Response of flame thickness and propagation speed under intense turbulence in spatially developing lean premixed methane air jet flames

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sankaran, Ramanan; Hawkes, Evatt R.; Yoo, Chun Sang; Chen, Jacqueline H.

    2015-06-22

    Direct numerical simulations of three-dimensional spatially-developing turbulent Bunsen flames were performed at three different turbulence intensities. We performed these simulations using a reduced methaneair chemical mechanism which was specifically tailored for the lean premixed conditions simulated here. A planar-jet turbulent Bunsen flame configuration was used in which turbulent preheated methaneair mixture at 0.7 equivalence ratio issued through a central jet and was surrounded by a hot laminar coflow of burned products. The turbulence characteristics at the jet inflow were selected such that combustion occured in the thin reaction zones (TRZ) regime. At the lowest turbulence intensity, the conditions fall onmorethe boundary between the TRZ regime and the corrugated flamelet regime, and progressively moved further into the TRZ regime by increasing the turbulent intensity. The data from the three simulations was analyzed to understand the effect of turbulent stirring on the flame structure and thickness. Furthermore, statistical analysis of the data showed that the thermal preheat layer of the flame was thickened due to the action of turbulence, but the reaction zone was not significantly affected. A global and local analysis of the burning velocity of the flame was performed to compare the different flames. Detailed statistical averages of the flame speed were also obtained to study the spatial dependence of displacement speed and its correlation to strain rate and curvature.less

  6. Response of flame thickness and propagation speed under intense turbulence in spatially developing lean premixed methane–air jet flames

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sankaran, Ramanan; Hawkes, Evatt R.; Yoo, Chun Sang; Chen, Jacqueline H.

    2015-06-22

    Direct numerical simulations of three-dimensional spatially-developing turbulent Bunsen flames were performed at three different turbulence intensities. We performed these simulations using a reduced methane–air chemical mechanism which was specifically tailored for the lean premixed conditions simulated here. A planar-jet turbulent Bunsen flame configuration was used in which turbulent preheated methane–air mixture at 0.7 equivalence ratio issued through a central jet and was surrounded by a hot laminar coflow of burned products. The turbulence characteristics at the jet inflow were selected such that combustion occured in the thin reaction zones (TRZ) regime. At the lowest turbulence intensity, the conditions fall onmore » the boundary between the TRZ regime and the corrugated flamelet regime, and progressively moved further into the TRZ regime by increasing the turbulent intensity. The data from the three simulations was analyzed to understand the effect of turbulent stirring on the flame structure and thickness. Furthermore, statistical analysis of the data showed that the thermal preheat layer of the flame was thickened due to the action of turbulence, but the reaction zone was not significantly affected. A global and local analysis of the burning velocity of the flame was performed to compare the different flames. Detailed statistical averages of the flame speed were also obtained to study the spatial dependence of displacement speed and its correlation to strain rate and curvature.« less

  7. Direct determination of solid-electrolyte interphase thickness and composition as a function of state of charge on a silicon anode

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Veith, Gabriel M.; Doucet, Mathieu; Baldwin, J. K.; Sacci, Robert L.; Fears, Tyler M.; Wang, Yongqiang; Browning, Jim

    2015-08-17

    Using neutron reflectometry we have determined the thickness and chemistry of the solid-electrolyte interphase (SEI) layer grown on a silicon anode as a function of state of charge and during cycling. We show the chemistry of this SEI layer becomes more LiF like with increasing lithiation and more Li-C-O-F like with delithiation. More importantly the SEI layer thickness appears to increase (about 250 ) as the electrode becomes less lithiated and thins to 180 with increasing Li content (Li3.7Si). We attribute this breathing to the continual consumption of electrolyte with cycling.

  8. Direct determination of solid-electrolyte interphase thickness and composition as a function of state of charge on a silicon anode

    SciTech Connect (OSTI)

    Veith, Gabriel M.; Doucet, Mathieu; Baldwin, J. K.; Sacci, Robert L.; Fears, Tyler M.; Wang, Yongqiang; Browning, Jim

    2015-08-17

    Using neutron reflectometry we have determined the thickness and chemistry of the solid-electrolyte interphase (SEI) layer grown on a silicon anode as a function of state of charge and during cycling. We show the chemistry of this SEI layer becomes more LiF like with increasing lithiation and more Li-C-O-F like with delithiation. More importantly the SEI layer thickness appears to increase (about 250 ) as the electrode becomes less lithiated and thins to 180 with increasing Li content (Li3.7Si). We attribute this breathing to the continual consumption of electrolyte with cycling.

  9. Temperature and epi thickness dependence of the heavy ion induced latchup threshold for a CMOS/epi 16K static RAM

    SciTech Connect (OSTI)

    Smith, L.S.; Nichols, D.K.; Coss, J.R.; Price, W.E.; Binder, D.

    1987-12-01

    Data have been obtained with krypton and xenon ions for the latchup threshold vs. temperature of four different versions of a Harris CMOS/epi 16K static RAM. These special versions of the HM6516 RAM have 12-micron, 9-micron, 7-micron and 5-micron epi thicknesses, as grown. The test data showed a marked improvement in latchup resistance with decreasing epi thickness and with decreasing temperature over the range of 25/sup 0/C (operating chip ambient) to 100/sup 0/C.s.

  10. EVOLUTION OF SNOW LINE IN OPTICALLY THICK PROTOPLANETARY DISKS: EFFECTS OF WATER ICE OPACITY AND DUST GRAIN SIZE

    SciTech Connect (OSTI)

    Oka, Akinori; Nakamoto, Taishi; Ida, Shigeru, E-mail: akinorioka1@gmail.com, E-mail: nakamoto@geo.titech.ac.jp [Department of Earth and Planetary Sciences, Tokyo Institute of Technology, Tokyo (Japan)

    2011-09-10

    Evolution of a snow line in an optically thick protoplanetary disk is investigated with numerical simulations. The ice-condensing region in the disk is obtained by calculating the temperature and the density with the 1+1D approach. The snow line migrates as the mass accretion rate ( M-dot ) in the disk decreases with time. Calculations are carried out from an early phase with high disk accretion rates ( M-dot {approx}10{sup -7} M{sub sun} yr{sup -1}) to a later phase with low disk accretion rates ( M-dot {approx}10{sup -12} M{sub sun} yr{sup -1}) using the same numerical method. It is found that the snow line moves inward for M-dot {approx}>10{sup -10} M{sub sun} yr{sup -1}, while it gradually moves outward in the later evolution phase with M-dot {approx}<10{sup -10} M{sub sun} yr{sup -1}. In addition to the silicate opacity, the ice opacity is taken into consideration. In the inward migration phase, the additional ice opacity increases the distance of the snow line from the central star by a factor of 1.3 for dust grains {approx}< 10 {mu}m in size and of 1.6 for {approx}> 100 {mu}m. It is inevitable that the snow line comes inside Earth's orbit in the course of the disk evolution if the viscosity parameter {alpha} is in the range 0.001-0.1, the dust-to-gas mass ratio is higher than a tenth of the solar abundance value, and the dust grains are smaller than 1 mm. The formation of water-devoid planetesimals in the terrestrial planet region seems to be difficult throughout the disk evolution, which imposes a new challenge to planet formation theory.

  11. Tunability of conduction at the LaAlO{sub 3}/SrTiO{sub 3} heterointerface: Thickness and compositional studies

    SciTech Connect (OSTI)

    Breckenfeld, E.; Bronn, N.; Mason, N.; Martin, L. W.

    2014-09-22

    The role of chemistry, film thickness, and oxygen pressure in influencing the electrical and thermal transport properties of LaAlO{sub 3}/SrTiO{sub 3} heterointerfaces is explored. Unit-cell precise growth was accomplished for films between 3 and 160 unit cells thick using reflection high-energy electron diffraction-assisted pulsed-laser deposition. Subsequent temperature-dependent studies of electrical resistivity reveal three important observations: (1) by tuning the laser fluence, we can systematically tune the interfacial conductance in a step-wise manner in this system, (2) all films exhibit a critical thickness of 34 unit cells for the onset of conduction, and (3) the nature of the conductance is highly influenced by the stoichiometry of the LaAlO{sub 3} film with La-deficient samples showing dramatic changes with thickness, while stoichiometric and La-excess films show little dependence. Time-domain thermoreflectance studies show a diminished interfacial thermal conductance for the La-deficient films when compared to La-excess and stoichiometric films, suggesting that the interfacial conductance is more influenced by extrinsic factors such as oxygen deficiency.

  12. Thicknesses, densities, and calculated thermal resistances for loose-fill rock wool installed in two attic sections of a manufactured house

    SciTech Connect (OSTI)

    Graves, R.S.; Yarbrough, D.W.

    1986-02-01

    The effect of vibrations due to manufacturing and transport on the thickness, density, and calculated thermal resistance (R-value) of loose-fill rock wool insulation installed in two manufactured home units has been determined. Thickness and density measurements on blown attic insulation were made after installation, at the end of the manufacturing process, and after the units were towed 265 miles. These measurements were used to calculate R-values for the attic insulation. The end sections of the two units showed an overall insulation thickness decrease of about 16% and an average R-value change from 31.2 to 28.8 ft/sup 2/ x h x /sup 0/F/Btu. An estimated R-value greater than 30 ft/sup 2/ x h x /sup 0/F/Btu resulted from averaging the end and middle sections of the two units. The effect of reduced thickness along the edges of the attic space was not included in the estimate.

  13. Single-vortex pinning and penetration depth in superconducting NdFeAsO1-xFx

    SciTech Connect (OSTI)

    Zhang, Jessie T.; Kim, Jeehoon; Huefner, Magdalena; Ye, Cun; Kim, Stella; Canfield, Paul C.; Prozorov, Ruslan; Auslaender, Ophir M.; Hoffman, Jennifer E.

    2015-10-12

    We use a magnetic force microscope (MFM) to investigate single vortex pinning and penetration depth in NdFeAsO1-xFx, one of the highest-Tc iron-based superconductors. In fields up to 20 Gauss, we observe a disordered vortex arrangement, implying that the pinning forces are stronger than the vortex-vortex interactions. We measure the typical force to depin a single vortex, Fdepin ? 4.5 pN, corresponding to a critical current up to Jc ? 7105 A/cm2. As a result, our MFM measurements allow the first local and absolute determination of the superconducting in-plane penetration depth in NdFeAsO1-xFx, ?ab = 320 60 nm, which is larger than previous bulk measurements.

  14. Method and apparatus for the evaluation of a depth profile of thermo-mechanical properties of layered and graded materials and coatings

    DOE Patents [OSTI]

    Finot, Marc (Somerville, MA); Kesler, Olivera (Cambridge, MA); Suresh, Subra (Wellesley, MA)

    1998-01-01

    A technique for determining properties such as Young's modulus, coefficient of thermal expansion, and residual stress of individual layers within a multi-layered sample is presented. The technique involves preparation of a series of samples, each including one additional layer relative to the preceding sample. By comparison of each sample to a preceding sample, properties of the topmost layer can be determined, and residual stress at any depth in each sample, resulting from deposition of the top layer, can be determined.

  15. Interaction between arsenic exposure from drinking water and genetic susceptibility in carotid intima–media thickness in Bangladesh

    SciTech Connect (OSTI)

    Wu, Fen; Jasmine, Farzana; Kibriya, Muhammad G.; Liu, Mengling; Cheng, Xin; Parvez, Faruque; Paul-Brutus, Rachelle; Islam, Tariqul; Paul, Rina Rani; Sarwar, Golam; Ahmed, Alauddin; Jiang, Jieying; Islam, Tariqul; Slavkovich, Vesna; Rundek, Tatjana; Demmer, Ryan T.; Desvarieux, Moise; and others

    2014-05-01

    Epidemiologic studies that evaluated genetic susceptibility for the effects of arsenic exposure from drinking water on subclinical atherosclerosis are limited. We conducted a cross-sectional study of 1078 participants randomly selected from the Health Effects of Arsenic Longitudinal Study in Bangladesh to evaluate whether the association between arsenic exposure and carotid artery intima–media thickness (cIMT) differs by 207 single-nucleotide polymorphisms (SNPs) in 18 genes related to arsenic metabolism, oxidative stress, inflammation, and endothelial dysfunction. Although not statistically significant after correcting for multiple testing, nine SNPs in APOE, AS3MT, PNP, and TNF genes had a nominally statistically significant interaction with well-water arsenic in cIMT. For instance, the joint presence of a higher level of well-water arsenic (≥ 40.4 μg/L) and the GG genotype of AS3MT rs3740392 was associated with a difference of 40.9 μm (95% CI = 14.4, 67.5) in cIMT, much greater than the difference of cIMT associated with the genotype alone (β = − 5.1 μm, 95% CI = − 31.6, 21.3) or arsenic exposure alone (β = 7.2 μm, 95% CI = − 3.1, 17.5). The pattern and magnitude of the interactions were similar when urinary arsenic was used as the exposure variable. Additionally, the at-risk genotypes of the AS3MT SNPs were positively related to the proportion of monomethylarsonic acid (MMA) in urine, which is indicative of arsenic methylation capacity. The findings provide novel evidence that genetic variants related to arsenic metabolism may play an important role in arsenic-induced subclinical atherosclerosis. Future replication studies in diverse populations are needed to confirm the findings. - Highlights: • Nine SNPs had a nominally significant interaction with well-water arsenic in cIMT. • Three SNPs in AS3MT showed nominally significant interactions with urinary arsenic. • cIMT was much higher among subjects with higher arsenic exposure and AS3MT SNPs. • The at-risk genotypes of AS3MT SNPs were positively related to urinary MMA%.

  16. Effects of substrate temperature and Cu underlayer thickness on the formation of SmCo{sub 5}(0001) epitaxial thin films

    SciTech Connect (OSTI)

    Ohtake, Mitsuru; Nukaga, Yuri; Futamoto, Masaaki; Kirino, Fumiyoshi

    2010-05-15

    SmCo{sub 5}(0001) epitaxial thin films were prepared on Cu(111) underlayers heteroepitaxially grown on Al{sub 2}O{sub 3}(0001) single-crystal substrates by molecular beam epitaxy. The effects of substrate temperature and Cu underlayer thickness on the crystallographic properties of SmCo{sub 5}(0001) epitaxial films were investigated. The Cu atoms of underlayer diffuse into the SmCo{sub 5} film and substitute the Co sites in SmCo{sub 5} structure forming an alloy compound of Sm(Co,Cu){sub 5}. The ordered phase formation is enhanced with increasing the substrate temperature and with increasing the Cu underlayer thickness. The Cu atom diffusion into the SmCo{sub 5} film is assisting the formation of Sm(Co,Cu){sub 5} ordered phase.

  17. Co-electrospinning fabrication and photocatalytic performance of TiO{sub 2}/SiO{sub 2} core/sheath nanofibers with tunable sheath thickness

    SciTech Connect (OSTI)

    Cao, Houbao Du, Pingfan; Song, Lixin; Xiong, Jie Yang, Junjie; Xing, Tonghai; Liu, Xin; Wu, Rongrong; Wang, Minchao; Shao, Xiaoli

    2013-11-15

    Graphical abstract: - Highlights: The coresheath TiO{sub 2}/SiO{sub 2} nanofibers were fabricated by co-electrospinning technique. The catalytic property of nanofibers with different sheath thickness was studied. The potential methods of improving catalytic efficiency are suggested. - Abstract: In this paper, core/sheath TiO{sub 2}/SiO{sub 2} nanofibers with tunable sheath thickness were directly fabricated via a facile co-electrospinning technique with subsequent calcination at 500 C. The morphologies and structures of core/sheath TiO{sub 2}/SiO{sub 2} nanofibers were characterized by TGA, FESEM, TEM, FTIR, XPS and BET. It was found that the 1D core/sheath nanofibers are made up of anataserutile TiO{sub 2} core and amorphous SiO{sub 2} sheath. The influences of SiO{sub 2} sheath and its thickness on the photoreactivity were evaluated by observing photo-degradation of methylene blue aqueous solution under the irradiation of UV light. Compared with pure TiO{sub 2} nanofibers, the core/sheath TiO{sub 2}/SiO{sub 2} nanofibers performed a better catalytic performance. That was attributed to not only efficient separation of holeelectron pairs resulting from the formation of heterojunction but also larger surface area and surface silanol group which will be useful to provide higher capacity for oxygen adsorption to generate more hydroxyl radicals. And the optimized core/sheath TiO{sub 2}/SiO{sub 2} nanofibers with a sheath thickness of 37 nm exhibited the best photocatalytic performance.

  18. Electric-Field Modulation of Curie Temperature in (Ga, Mn)As Field-Effect Transistor Structures with Varying Channel Thickness and Mn Compositions

    SciTech Connect (OSTI)

    Nishitani, Y.; Endo, M.; Chiba, D.; Matsukura, F.; Ohno, H.

    2010-01-04

    We have investigated the change of T{sub C} of ferromagnetic semiconductor (Ga, Mn)As by changing hole concentration p. The field effect transistor structure was utilized to change p. The relation T{sub C}propor top{sup 0.2} is obtained for three samples, despite the difference of their Mn composition and thickness, indicating that the relation holds over 2 decades of p.

  19. Synthesis and characterization of 10?nm thick piezoelectric AlN films with high c-axis orientation for miniaturized nanoelectromechanical devices

    SciTech Connect (OSTI)

    Zaghloul, Usama; Piazza, Gianluca

    2014-06-23

    The scaling of piezoelectric nanoelectromechanical systems (NEMS) is challenged by the synthesis of ultrathin and high quality piezoelectric films on very thin electrodes. We report the synthesis and characterization of the thinnest piezoelectric aluminum nitride (AlN) films (10?nm) ever deposited on ultrathin platinum layers (25?nm) using reactive sputtering. X-ray diffraction, high-resolution transmission electron microscopy, and fast Fourier transform analyses confirmed the proper crystal orientation, fine columnar texture, and the continuous lattice structure within individual grains in the deposited AlN nanometer thick films. The average extracted d{sub 31} piezoelectric coefficient for the synthesized films is ?1.73 pC/N, which is comparable to the reported values for micron thick and highly c-axis oriented AlN films. The 10?nm AlN films were employed to demonstrate two different types of optimized piezoelectric nanoactuators. The unimorph actuators exhibit vertical displacements as large as 1.1??m at 0.7?V for 25??m long and 30?nm thick beams. These results have a great potential to realize miniaturized NEMS relays with extremely low voltage, high frequency resonators, and ultrasensitive sensors.

  20. Thickness Effect of Al-Doped ZnO Window Layer on Damp Heat Stability of CuInGaSe2 Solar Cells: Preprint

    SciTech Connect (OSTI)

    Pern, F. J.; Mansfield, L.; DeHart, C.; Glick, S. H.; Yan, F.; Noufi, R.

    2011-07-01

    We investigated the damp heat (DH) stability of CuInGaSe2 (CIGS) solar cells as a function of thickness of the Al-doped ZnO (AZO) window layer from the 'standard' 0.12 ?m to a modest 0.50 ?m over an underlying 0.10-?m intrinsic ZnO buffer layer. The CIGS cells were prepared with external electrical contact using fine Au wire to the tiny 'standard' Ni/Al (0.05 ?m/3 ?m) metal grid contact pads. Bare cell coupons and sample sets encapsulated in a specially designed, Al-frame test structure with an opening for moisture ingress control using a TPT backsheet were exposed to DH at 85oC and 85% relative humidity, and characterized by current-voltage (I-V), quantum efficiency (QE), and (electrochemical) impedance spectroscopy (ECIS). The results show that bare cells exhibited rapid degradation within 50-100 h, accompanied by film wrinkling and delamination and corrosion of Mo and AlNi grid, regardless of AZO thickness. In contrast, the encapsulated cells did not show film wrinkling, delamination, and Mo corrosion after 168 h DH exposure; but the trend of efficiency degradation rate showed a weak correlation to the AZO thickness.

  1. Method and system for determining depth distribution of radiation-emitting material located in a source medium and radiation detector system for use therein

    DOE Patents [OSTI]

    Benke, Roland R. (Helotes, TX); Kearfott, Kimberlee J. (Ann Arbor, MI); McGregor, Douglas S. (Ann Arbor, MI)

    2003-03-04

    A method, system and a radiation detector system for use therein are provided for determining the depth distribution of radiation-emitting material distributed in a source medium, such as a contaminated field, without the need to take samples, such as extensive soil samples, to determine the depth distribution. The system includes a portable detector assembly with an x-ray or gamma-ray detector having a detector axis for detecting the emitted radiation. The radiation may be naturally-emitted by the material, such as gamma-ray-emitting radionuclides, or emitted when the material is struck by other radiation. The assembly also includes a hollow collimator in which the detector is positioned. The collimator causes the emitted radiation to bend toward the detector as rays parallel to the detector axis of the detector. The collimator may be a hollow cylinder positioned so that its central axis is perpendicular to the upper surface of the large area source when positioned thereon. The collimator allows the detector to angularly sample the emitted radiation over many ranges of polar angles. This is done by forming the collimator as a single adjustable collimator or a set of collimator pieces having various possible configurations when connected together. In any one configuration, the collimator allows the detector to detect only the radiation emitted from a selected range of polar angles measured from the detector axis. Adjustment of the collimator or the detector therein enables the detector to detect radiation emitted from a different range of polar angles. The system further includes a signal processor for processing the signals from the detector wherein signals obtained from different ranges of polar angles are processed together to obtain a reconstruction of the radiation-emitting material as a function of depth, assuming, but not limited to, a spatially-uniform depth distribution of the material within each layer. The detector system includes detectors having different properties (sensitivity, energy resolution) which are combined so that excellent spectral information may be obtained along with good determinations of the radiation field as a function of position.

  2. Method and apparatus for the evaluation of a depth profile of thermo-mechanical properties of layered and graded materials and coatings

    DOE Patents [OSTI]

    Finot, M.; Kesler, O.; Suresh, S.

    1998-12-08

    A technique for determining properties such as Young`s modulus, coefficient of thermal expansion, and residual stress of individual layers within a multi-layered sample is presented. The technique involves preparation of a series of samples, each including one additional layer relative to the preceding sample. By comparison of each sample to a preceding sample, properties of the topmost layer can be determined, and residual stress at any depth in each sample, resulting from deposition of the top layer, can be determined. 11 figs.

  3. Absorption enhancement through Fabry-Prot resonant modes in a 430?nm thick InGaAs/GaAsP multiple quantum wells solar cell

    SciTech Connect (OSTI)

    Behaghel, B.; Tamaki, R.; Watanabe, K.; Sodabanlu, H.; Vandamme, N.; Dupuis, C.; Bardou, N.; Cattoni, A.; Okada, Y.; Sugiyama, M.; Collin, S.; Guillemoles, J.-F.

    2015-02-23

    We study light management in a 430?nm-thick GaAs p-i-n single junction solar cell with 10 pairs of InGaAs/GaAsP multiple quantum wells (MQWs). The epitaxial layer transfer on a gold mirror improves light absorption and increases the external quantum efficiency below GaAs bandgap by a factor of four through the excitation of Fabry-Perot resonances. We show a good agreement with optical simulation and achieve around 10% conversion efficiency. We demonstrate numerically that this promising result can be further improved by anti-reflection layers. This study paves the way to very thin MQWs solar cells.

  4. Enhanced Tissue Adhesion by Increased Porosity and Surface Roughness...

    Office of Scientific and Technical Information (OSTI)

    Research Org: Oak Ridge National Laboratory (ORNL) Sponsoring Org: SC USDOE - Office of Science (SC) Country of Publication: United States Language: English Word Cloud More Like ...

  5. Poisson's ratio and porosity at Coso geothermal area, California...

    Open Energy Info (EERE)

    of the model, are estimated by a jackknife method. We use perturbations of r V p V s ratio and Psi V p .V s product to derive distributions of Poisson's ratio, sigma , and...

  6. Effects of porosity on leaching of Ca from hardened ordinary...

    Office of Scientific and Technical Information (OSTI)

    DOI: 10.1016j.cemconres.2004.06.034; PII: S0008-8846(04)00287-X; Copyright (c) 2004 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved; Country of input: ...

  7. Closeout of Advanced Boron and Metal Loaded High Porosity Carbons.

    SciTech Connect (OSTI)

    Peter C. Eklund (deceased); T. C. Mike Chung; Henry C. Foley; Vincent H. Crespi

    2011-05-01

    The Penn State effort explored the development of new high-surface-area materials for hydrogen storage, materials that could offer enhancement in the hydrogen binding energy through a direct chemical modification of the framework in high specific-surface-area platforms. The team chemically substituted boron into the hexagonal sp2 carbon framework, dispersed metal atoms bound to the boro-carbon structure, and generated the theory of novel nanoscale geometries that can enhance storage through chemical frustration, sheet curvature, electron deficiency, large local fields and mixed hybridization states. New boro-carbon materials were synthesized by high temperature plasma, pyrolysis of boron-carbon precursor molecules, and post-synthesis modification of carbons. Hydrogen uptake has been assessed, and several promising leads have been identified, with the requirement to simultaneously optimize total surface area while maintaining the enhanced hydrogen binding energies already demonstrated.

  8. ORNUGWPO-019 Determination of Effective Porosity of Mudrocks...

    Office of Scientific and Technical Information (OSTI)

    37831-6285 LOCKHEED MARTIN ENERGY RESEARCH, COW. for the US DEPARTMENT OF ENERGY ......... 12 methodology . .. .. .. .. . . .. .. . . . . . .. .. ...

  9. Preparation of high porosity xerogels by chemical surface modification.

    DOE Patents [OSTI]

    Deshpande, Ravindra (51 Michelle Dr. Apt. A 11, Lancaster, PA 17603); Smith, Douglas M. (1412 Marquette Pl. NE., Albuquerque, NM 87122); Brinker, C. Jeffrey (14 Eagle Nest Dr. NE., Albuquerque, NM 87122)

    1996-01-01

    This invention provides an extremely porous xerogel dried at vacuum-to-below supercritical pressures but having the properties of aerogels which are typically dried at supercritical pressures. This is done by reacting the internal pore surface of the wet gel with organic substances in order to change the contact angle of the fluid meniscus in the pores during drying. Shrinkage of the gel (which is normally prevented by use of high autoclave pressures, such that the pore fluid is at temperature and pressure above its critical values) is avoided even at vacuum or ambient pressures.

  10. Image Logs | Open Energy Information

    Open Energy Info (EERE)

    StratigraphicStructural: -Fault and fracture identification -Rock texture, porosity, and stress analysis -determine dip, thickness, and geometry of rock strata in vicinity of...

  11. Measuring the depth profiles of strain/composition in AlGaN-graded layer by high-resolution x-ray diffraction

    SciTech Connect (OSTI)

    Kuchuk, A. V.; Stanchu, H. V.; Kladko, V. P.; Belyaev, A. E.; Li, Chen; Ware, M. E.; Mazur, Yu. I.; Salamo, G. J.

    2014-12-14

    Here, we demonstrate X-ray fitting through kinematical simulations of the intensity profiles of symmetric reflections for epitaxial compositionally graded layers of AlGaN grown by molecular beam epitaxy pseudomorphically on [0001]-oriented GaN substrates. These detailed simulations depict obvious differences between changes in thickness, maximum concentration, and concentration profile of the graded layers. Through comparison of these simulations with as-grown samples, we can reliably determine these parameters, most important of which are the profiles of the concentration and strain which determine much of the electrical properties of the film. In addition to learning about these parameters for the characterization of thin film properties, these fitting techniques create opportunities to calibrate growth rates and control composition profiles of AlGaN layers with a single growth rather than multiple growths as has been done traditionally.

  12. International Energy Agency Building Energy Simulation Test and Diagnostic Method (IEA BESTEST): In-Depth Diagnostic Cases for Ground Coupled Heat Transfer Related to Slab-on-Grade Construction

    SciTech Connect (OSTI)

    Neymark, J.; Judkoff, R.; Beausoleil-Morrison, I.; Ben-Nakhi, A.; Crowley, M.; Deru, M.; Henninger, R.; Ribberink, H.; Thornton, J.; Wijsman, A.; Witte, M.

    2008-09-01

    This report documents a set of idealized in-depth diagnostic test cases for use in validating ground-coupled floor slab heat transfer models. These test cases represent an extension to IEA BESTEST.

  13. Depth of maximum of air-shower profiles at the Pierre Auger Observatory. I. Measurements at energies above $$10^{17.8}$$ eV

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Aab, Alexander

    2014-12-31

    We report a study of the distributions of the depth of maximum, Xmax, of extensive air-shower profiles with energies above 1017.8 eV as observed with the fluorescence telescopes of the Pierre Auger Observatory. The analysis method for selecting a data sample with minimal sampling bias is described in detail as well as the experimental cross-checks and systematic uncertainties. Furthermore, we discuss the detector acceptance and the resolution of the Xmax measurement and provide parametrizations thereof as a function of energy. Finally, the energy dependence of the mean and standard deviation of the Xmax distributions are compared to air-shower simulations formore » different nuclear primaries and interpreted in terms of the mean and variance of the logarithmic mass distribution at the top of the atmosphere.« less

  14. Compositional analysis and depth profiling of thin film CrO{sub 2} by heavy ion ERDA and standard RBS: a comparison

    SciTech Connect (OSTI)

    Khamlich, S.; Msimanga, M.; Pineda-Vargas, C.A.; Nuru, Z.Y.; McCrindle, R.; Maaza, M.

    2012-08-15

    Chromium dioxide (CrO{sub 2}) thin film has generated considerable interest in applied research due to the wide variety of its technological applications. It has been extensively investigated in recent years, attracting the attention of researchers working on spintronic heterostructures and in the magnetic recording industry. However, its synthesis is usually a difficult task due to its metastable nature and various synthesis techniques are being investigated. In this work a polycrystalline thin film of CrO{sub 2} was prepared by electron beam vaporization of Cr{sub 2}O{sub 3} onto a Si substrate. The polycrystalline structure was confirmed through XRD analysis. The stoichiometry and elemental depth distribution of the deposited film were measured by ion beam nuclear analytical techniques heavy ion elastic recoil detection analysis (ERDA) and Rutherford backscattering spectrometry (RBS), which both have relative advantage over non-nuclear spectrometries in that they can readily provide quantitative information about the concentration and distribution of different atomic species in a layer. Moreover, the analysis carried out highlights the importance of complementary usage of the two techniques to obtain a more complete description of elemental content and depth distribution in thin films. - Graphical abstract: Heavy ion elastic recoil detection analysis (ERDA) and Rutherford backscattering spectrometry (RBS) both have relative advantage over non-nuclear spectrometries in that they can readily provide quantitative information about the concentration and distribution of different atomic species in a layer. Highlights: Black-Right-Pointing-Pointer Thin films of CrO{sub 2} have been grown by e-beam evaporation of Cr{sub 2}O{sub 3} target in vacuum. Black-Right-Pointing-Pointer The composition was determined by heavy ion-ERDA and RBS. Black-Right-Pointing-Pointer HI-ERDA and RBS provided information on the light and heavy elements, respectively.

  15. Depth-discrete sampling port

    DOE Patents [OSTI]

    Pemberton, Bradley E. (Aiken, SC); May, Christopher P. (Columbia, MD); Rossabi, Joseph (Aiken, SC); Riha, Brian D. (Augusta, GA); Nichols, Ralph L. (North Augusta, SC)

    1998-07-07

    A sampling port is provided which has threaded ends for incorporating the port into a length of subsurface pipe. The port defines an internal receptacle which is in communication with subsurface fluids through a series of fine filtering slits. The receptacle is in further communication through a bore with a fitting carrying a length of tubing there which samples are transported to the surface. Each port further defines an additional bore through which tubing, cables, or similar components of adjacent ports may pass.

  16. Depth-discrete sampling port

    DOE Patents [OSTI]

    Pemberton, Bradley E. (Aiken, SC); May, Christopher P. (Columbia, MD); Rossabi, Joseph (Aiken, SC); Riha, Brian D. (Augusta, GA); Nichols, Ralph L. (North Augusta, SC)

    1999-01-01

    A sampling port is provided which has threaded ends for incorporating the port into a length of subsurface pipe. The port defines an internal receptacle which is in communication with subsurface fluids through a series of fine filtering slits. The receptacle is in further communication through a bore with a fitting carrying a length of tubing there which samples are transported to the surface. Each port further defines an additional bore through which tubing, cables, or similar components of adjacent ports may pass.

  17. Thickness dependent hierarchical meso/nano scale morphologies of a metal-containing block copolymer thin film induced by hybrid annealing and their pattern transfer abilities.

    SciTech Connect (OSTI)

    Ramanathan, M.; Darling, S. B.; Center for Nanoscale Materials

    2009-01-01

    In this paper we describe dewetting phenomena in organic (polystyrene, PS)/inorganic (polyferrocenyldimethylsilane, PFS) block copolymer thin films. Mesoscale dendritic structures are induced when the spin-cast thin film of this polymer is subjected to so-called hybrid annealing, which involves both thermal and solvent annealing. We show that the development and arrangement of these mesoscale dendritic structures depends on the initial film thickness in addition to the annealing time. Importantly, there are two criteria that must be fulfilled to achieve these mesoscale morphologies: (i) the film has to be subjected to hybrid annealing, i.e. either only thermal or only solvent annealing does not produce any notable mesostructures and (ii) both PS and PFS blocks must be present during the thermal and solvent annealing procedures; if one of the blocks, for instance PS, is removed before annealing then there is no mesostructure. Various possible mechanisms for the formation of these structures are discussed and results indicate that the PFS block dominates the structure formation. We also observe a ring- or worm-like nanostructure which develops only when the film is subjected to hybrid annealing at a particular film thickness. Apart from these results, here we demonstrate that mesoscale structures can be successfully transferred onto underlying substrates.

  18. Cone beam breast CT with a high pitch (75 ?m), thick (500 ?m) scintillator CMOS flat panel detector: Visibility of simulated microcalcifications

    SciTech Connect (OSTI)

    Shen, Youtao; Zhong, Yuncheng; Lai, Chao-Jen; Wang, Tianpeng; Shaw, Chris C.

    2013-10-15

    Purpose: To measure and investigate the improvement of microcalcification (MC) visibility in cone beam breast CT with a high pitch (75 ?m), thick (500 ?m) scintillator CMOS/CsI flat panel detector (Dexela 2923, Perkin Elmer).Methods: Aluminum wires and calcium carbonate grains of various sizes were embedded in a paraffin cylinder to simulate imaging of calcifications in a breast. Phantoms were imaged with a benchtop experimental cone beam CT system at various exposure levels. In addition to the Dexela detector, a high pitch (50 ?m), thin (150 ?m) scintillator CMOS/CsI flat panel detector (C7921CA-09, Hamamatsu Corporation, Hamamatsu City, Japan) and a widely used low pitch (194 ?m), thick (600 ?m) scintillator aSi/CsI flat panel detector (PaxScan 4030CB, Varian Medical Systems) were also used in scanning for comparison. The images were independently reviewed by six readers (imaging physicists). The MC visibility was quantified as the fraction of visible MCs and measured as a function of the estimated mean glandular dose (MGD) level for various MC sizes and detectors. The modulation transfer functions (MTFs) and detective quantum efficiencies (DQEs) were also measured and compared for the three detectors used.Results: The authors have demonstrated that the use of a high pitch (75 ?m) CMOS detector coupled with a thick (500 ?m) CsI scintillator helped make the smaller 150160, 160180, and 180200 ?m MC groups more visible at MGDs up to 10.8, 9, and 10.8 mGy, respectively. It also made the larger 200212 and 212224 ?m MC groups more visible at MGDs up to 7.2 mGy. No performance improvement was observed for 224250 ?m or larger size groups. With the higher spatial resolution of the Dexela detector based system, the apparent dimensions and shapes of MCs were more accurately rendered. The results show that with the aforementioned detector, a 73% visibility could be achieved in imaging 160180 ?m MCs as compared to 28% visibility achieved by the low pitch (194 ?m) aSi/CsI flat panel detector. The measurements confirm that the Hamamatsu detector has the highest MTF, followed by the Dexel detector, and then the Varian detector. However, the Dexela detector, with its thick (500 ?m) CsI scintillator and low noise level, has the highest DQE at all frequencies, followed by the Varian detector, and then the Hamamatsu detector. The findings on the MC visibility correlated well with the differences in MTFs, noise power spectra, and DQEs measured for these three detectors.Conclusions: The authors have demonstrated that the use of the CMOS type Dexela detector with its high pitch (75 ?m) and thick (500 ?m) CsI scintillator could help improve the MC visibility. However, the improvement depended on the exposure level and the MC size. For imaging larger MCs or scanning at high exposure levels, there was little advantage in using the Dexela detector as compared to the aSi type Varian detector. These findings correlate well with the higher measured DQEs of the Dexela detector, especially at higher frequencies.

  19. Plasma assisted molecular beam epitaxy growth and effect of varying buffer thickness on the formation of ultra-thin In{sub 0.17}Al{sub 0.83}N/GaN heterostructure on Si(111)

    SciTech Connect (OSTI)

    Chowdhury, Subhra; Biswas, Dhrubes

    2015-02-23

    This work reports on the detailed plasma-assisted molecular beam epitaxy (PAMBE) growth of ultra-thin In{sub 0.17}Al{sub 0.83}N/GaN heterostructures on Si(111) substrate with three different buffer thickness (600?nm, 400?nm, and 200?nm). Growth through critical optimization of growth conditions is followed by the investigation of impact of varying buffer thickness on the formation of ultra-thin 1.5?nm, In{sub 0.17}Al{sub 0.83}N1.25?nm, GaN1.5?nm, In{sub 0.17}Al{sub 0.83}N heterostructure, in terms of threading dislocation (TD) density. Analysis reveals a drastic reduction of TD density from the order 10{sup 10?}cm{sup ?2} to 10{sup 8?}cm{sup ?2} with increasing buffer thickness resulting smooth ultra-thin active region for thick buffer structure. Increasing strain with decreasing buffer thickness is studied through reciprocal space mapping analysis. Surface morphology through atomic force microscopy analysis also supports our study by observing an increase of pits and root mean square value (0.89?nm, 1.2?nm, and 1.45?nm) with decreasing buffer thickness which are resulted due to the internal strain and TDs.

  20. Exploring the concept of compressed air energy storage (CAES) in lined rock caverns at shallow depth: A modeling study of air tightness and energy balance

    SciTech Connect (OSTI)

    Kim, H.-M.; Rutqvist, J.; Ryu, D.-W.; Choi, B.-H.; Sunwoo, C.; Song, W.-K.

    2011-07-15

    This paper presents a numerical modeling study of coupled thermodynamic, multiphase fluid flow and heat transport associated with underground compressed air energy storage (CAES) in lined rock caverns. Specifically, we explored the concept of using concrete lined caverns at a relatively shallow depth for which constructing and operational costs may be reduced if air tightness and stability can be assured. Our analysis showed that the key parameter to assure long-term air tightness in such a system was the permeability of both the concrete lining and the surrounding rock. The analysis also indicated that a concrete lining with a permeability of less than 110{sup -18} m{sup 2} would result in an acceptable air leakage rate of less than 1%, with the operational pressure range between 5 and 8 MPa at a depth of 100 m. It was further noted that capillary retention properties and the initial liquid saturation of the lining were very important. Indeed, air leakage could be effectively prevented when the air-entry pressure of the concrete lining is higher than the operational air pressure and when the lining is kept moist at a relatively high liquid saturation. Our subsequent energy-balance analysis demonstrated that the energy loss for a daily compression and decompression cycle is governed by the air-pressure loss, as well as heat loss by conduction to the concrete liner and surrounding rock. For a sufficiently tight system, i.e., for a concrete permeability off less than 110{sup -18} m{sup 2}, heat loss by heat conduction tends to become proportionally more important. However, the energy loss by heat conduction can be minimized by keeping the air-injection temperature of compressed air closer to the ambient temperature of the underground storage cavern. In such a case, almost all the heat loss during compression is gained back during subsequent decompression. Finally, our numerical simulation study showed that CAES in shallow rock caverns is feasible from a leakage and energy efficiency viewpoint. Our numerical approach and energy analysis will next be applied in designing and evaluating the performance of a planned full-scale pilot test of the proposed underground CAES concept.

  1. Method and apparatus to produce and maintain a thick, flowing, liquid lithium first wall for toroidal magnetic confinement DT fusion reactors

    DOE Patents [OSTI]

    Woolley, Robert D. (Hillsborough, NJ)

    2002-01-01

    A system for forming a thick flowing liquid metal, in this case lithium, layer on the inside wall of a toroid containing the plasma of a deuterium-tritium fusion reactor. The presence of the liquid metal layer or first wall serves to prevent neutron damage to the walls of the toroid. A poloidal current in the liquid metal layer is oriented so that it flows in the same direction as the current in a series of external magnets used to confine the plasma. This current alignment results in the liquid metal being forced against the wall of the toroid. After the liquid metal exits the toroid it is pumped to a heat extraction and power conversion device prior to being reentering the toroid.

  2. Recovery Act: Novel Kerf-Free PV Wafering that provides a low-cost approach to generate wafers from 150um to 50um in thickness

    SciTech Connect (OSTI)

    Fong, Theodore E.

    2013-05-06

    The technical paper summarizes the project work conducted in the development of Kerf-Free silicon wafering equipment for silicon solar wafering. This new PolyMax technology uses a two step process of implantation and cleaving to exfoliate 50um to 120um wafers with thicknesses ranging from 50um to 120um from a 125mm or 156mm pseudo-squared silicon ingot. No kerf is generated using this method of wafering. This method of wafering contrasts with the current method of making silicon solar wafers using the industry standard wire saw equipment. The report summarizes the activity conducted by Silicon Genesis Corporation in working to develop this technology further and to define the roadmap specifications for the first commercial proto-type equipment for high volume solar wafer manufacturing using the PolyMax technology.

  3. Macro-to-microchannel transition in two-phase flow: Part 1 - Two-phase flow patterns and film thickness measurements

    SciTech Connect (OSTI)

    Ong, C.L.; Thome, J.R. [Ecole Polytechnique Federale de Lausanne, EPFL-STI-IGM-LTCM, Station 9, CH-1015 Lausanne (Switzerland)

    2011-01-15

    The classification of macroscale, mesoscale and microscale channels with respect to two-phase processes is still an open question. The main objective of this study focuses on investigating the macro-to-microscale transition during flow boiling in small scale channels of three different sizes with three different refrigerants over a range of saturation conditions to investigate the effects of channel confinement on two-phase flow patterns and liquid film stratification in a single circular horizontal channel (Part 2 covers the flow boiling heat transfer and critical heat flux). This paper presents the experimental two-phase flow pattern transition data together with a top/bottom liquid film thickness comparison for refrigerants R134a, R236fa and R245fa during flow boiling in small channels of 1.03, 2.20 and 3.04 mm diameter. Based on this work, an improved flow pattern map has been proposed by determining the flow patterns transitions existing under different conditions including the transition to macroscale slug/plug flow at a confinement number of Co {approx} 0.3-0.4. From the top/bottom liquid film thickness comparison results, it was observed that the gravity forces are fully suppressed and overcome by the surface tension and shear forces when the confinement number approaches 1, Co {approx} 1. Thus, as a new approximate rule, the lower threshold of macroscale flow is Co = 0.3-0.4 while the upper threshold of symmetric microscale flow is Co {approx} 1 with a transition (or mesoscale) region in-between. (author)

  4. Elucidating hydrogen oxidation/evolution kinetics in base and acid by enhanced activities at the optimized Pt shell thickness on the Ru core

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Elbert, Katherine; Hu, Jue; Ma, Zhong; Zhang, Yu; Chen, Guangyu; An, Wei; Liu, Ping; Isaacs, Hugh S.; Adzic, Radoslav R.; Wang, Jia X.

    2015-10-05

    Hydrogen oxidation and evolution on Pt in acid are facile processes, while in alkaline electrolytes, they are 2 orders of magnitude slower. Thus, developing catalysts that are more active than Pt for these two reactions is important for advancing the performance of anion exchange membrane fuel cells and water electrolyzers. Herein, we detail a 4-fold enhancement of Pt mass activity that we achieved using single-crystalline Ru@Pt core–shell nanoparticles with two-monolayer-thick Pt shells, which doubles the activity on Pt–Ru alloy nanocatalysts. For Pt specific activity, the two- and one-monolayer-thick Pt shells exhibited enhancement factors of 3.1 and 2.3, respectively, compared tomore » the Pt nanocatalysts in base, differing considerably from the values of 1 and 0.4, respectively, in acid. To explain such behavior and the orders of magnitude difference in activity on going from acid to base, we performed kinetic analyses of polarization curves over a wide range of potential from –250 to 250 mV using the dual-pathway kinetic equation. From acid to base, the activation free energies increase the most for the Volmer reaction, resulting in a switch of the rate-determining step from the Tafel to the Volmer reaction, and a shift to a weaker optimal hydrogen binding energy. Furthermore, the much higher activation barrier for the Volmer reaction in base than in acid is ascribed to one or both of the two catalyst-insensitive factors: slower transport of OH– than H+ in water and a stronger O–H bond in water molecules (HO–H) than in hydrated protons (H2O–H+).« less

  5. Elucidating hydrogen oxidation/evolution kinetics in base and acid by enhanced activities at the optimized Pt shell thickness on the Ru core

    SciTech Connect (OSTI)

    Elbert, Katherine; Hu, Jue; Ma, Zhong; Zhang, Yu; Chen, Guangyu; An, Wei; Liu, Ping; Isaacs, Hugh S.; Adzic, Radoslav R.; Wang, Jia X.

    2015-10-05

    Hydrogen oxidation and evolution on Pt in acid are facile processes, while in alkaline electrolytes, they are 2 orders of magnitude slower. Thus, developing catalysts that are more active than Pt for these two reactions is important for advancing the performance of anion exchange membrane fuel cells and water electrolyzers. Herein, we detail a 4-fold enhancement of Pt mass activity that we achieved using single-crystalline Ru@Pt core–shell nanoparticles with two-monolayer-thick Pt shells, which doubles the activity on Pt–Ru alloy nanocatalysts. For Pt specific activity, the two- and one-monolayer-thick Pt shells exhibited enhancement factors of 3.1 and 2.3, respectively, compared to the Pt nanocatalysts in base, differing considerably from the values of 1 and 0.4, respectively, in acid. To explain such behavior and the orders of magnitude difference in activity on going from acid to base, we performed kinetic analyses of polarization curves over a wide range of potential from –250 to 250 mV using the dual-pathway kinetic equation. From acid to base, the activation free energies increase the most for the Volmer reaction, resulting in a switch of the rate-determining step from the Tafel to the Volmer reaction, and a shift to a weaker optimal hydrogen binding energy. Furthermore, the much higher activation barrier for the Volmer reaction in base than in acid is ascribed to one or both of the two catalyst-insensitive factors: slower transport of OH than H+ in water and a stronger O–H bond in water molecules (HO–H) than in hydrated protons (H2O–H+).

  6. Depth-resolved ultra-violet spectroscopic photo current-voltage measurements for the analysis of AlGaN/GaN high electron mobility transistor epilayer deposited on Si

    SciTech Connect (OSTI)

    Ozden, Burcu; Yang, Chungman; Tong, Fei; Khanal, Min P.; Mirkhani, Vahid; Sk, Mobbassar Hassan; Ahyi, Ayayi Claude; Park, Minseo

    2014-10-27

    We have demonstrated that the depth-dependent defect distribution of the deep level traps in the AlGaN/GaN high electron mobility transistor (HEMT) epi-structures can be analyzed by using the depth-resolved ultra-violet (UV) spectroscopic photo current-voltage (IV) (DR-UV-SPIV). It is of great importance to analyze deep level defects in the AlGaN/GaN HEMT structure, since it is recognized that deep level defects are the main source for causing current collapse phenomena leading to reduced device reliability. The AlGaN/GaN HEMT epi-layers were grown on a 6 in. Si wafer by metal-organic chemical vapor deposition. The DR-UV-SPIV measurement was performed using a monochromatized UV light illumination from a Xe lamp. The key strength of the DR-UV-SPIV is its ability to provide information on the depth-dependent electrically active defect distribution along the epi-layer growth direction. The DR-UV-SPIV data showed variations in the depth-dependent defect distribution across the wafer. As a result, rapid feedback on the depth-dependent electrical homogeneity of the electrically active defect distribution in the AlGaN/GaN HEMT epi-structure grown on a Si wafer with minimal sample preparation can be elucidated from the DR-UV-SPIV in combination with our previously demonstrated spectroscopic photo-IV measurement with the sub-bandgap excitation.

  7. Development of RAMS-CMAQ to Simulate Aerosol Optical Depth and Aerosol Direct Radiative Forcing and Its Application to East Asia

    SciTech Connect (OSTI)

    Han, Xiao; Zhang, Meigen; Liu, Xiaohong; Ghan, Steven J.; Xin, Jin-Yuan; Wang, Li-Li

    2009-11-16

    The air quality modeling system RAMS (Regional Atmospheric Modeling System)-CMAQ (Models-3 Community Multi-scale Air Quality) is developed to simulate the aerosol optical depth (AOD) and aerosol direct forcing (DF). The aerosol-specific extinction, single scattering albedo, and asymmetry factor are parameterized based on Mie theory taking into account the aerosol size distribution, composition, refractive index, and water uptake of solution particles. A two-stream solar radiative model considers all gaseous molecular absorption, Rayleigh scattering, and aerosols and clouds. RAMSCMAQ is applied to simulate all major aerosol concentrations (e.g., sulfate, nitrate, ammonium, organic carbon, black carbon, fine soil, and sea salt) and AOD and DF over East Asia in 2005. To evaluate its performance, the simulated AOD values were compared with ground-based in situ measurements. The comparison shows that RAMSCMAQ performed well in most of the model domain and generally captured the observed variations. High AOD values (0.2?1.0) mainly appear in the Sichuan Basin as well as in central and southeastern China. The geographic distribution of DF generally follows the AOD distribution patterns, and the DF at the top-of-the-atmosphere is less than ?25 and ?20 W m?2 in clear-sky and all-sky over the Sichuan Basin. Both AOD and DF exhibit seasonal variations with lower values in July and higher ones in January. The DF could obviously be impacted by high cloud fractions.

  8. High Temperature Superconducting Thick Films

    DOE Patents [OSTI]

    Arendt, Paul N. (Los Alamos, NM); Foltyn, Stephen R. (Los Alamos, NM); Groves, James R. (Los Alamos, NM); Holesinger, Terry G. (Los Alamos, NM); Jia, Quanxi (Los Alamos, NM)

    2005-08-23

    An article including a substrate, a layer of an inert oxide material upon the surface of the substrate, (generally the inert oxide material layer has a smooth surface, i.e., a RMS roughness of less than about 2 nm), a layer of an amorphous oxide or oxynitride material upon the inert oxide material layer, a layer of an oriented cubic oxide material having a rock-salt-like structure upon the amorphous oxide material layer is provided together with additional layers such as at least one layer of a buffer material upon the oriented cubic oxide material layer or a HTS top-layer of YBCO directly upon the oriented cubic oxide material layer. With a HTS top-layer of YBCO upon at least one layer of a buffer material in such an article, Jc's of 1.4106 A/cm2 have been demonstrated with projected Ic's of 210 Amperes across a sample 1 cm wide.

  9. Measurement of neutron spectra generated from bombardment of 4 to 24 MeV protons on a thick {sup 9}Be target and estimation of neutron yields

    SciTech Connect (OSTI)

    Paul, Sabyasachi; Sahoo, G. S.; Tripathy, S. P. E-mail: tripathy@barc.gov.in; Sunil, C.; Bandyopadhyay, T.; Sharma, S. C.; Ramjilal,; Ninawe, N. G.; Gupta, A. K.

    2014-06-15

    A systematic study on the measurement of neutron spectra emitted from the interaction of protons of various energies with a thick beryllium target has been carried out. The measurements were carried out in the forward direction (at 0 with respect to the direction of protons) using CR-39 detectors. The doses were estimated using the in-house image analyzing program autoTRAK-n, which works on the principle of luminosity variation in and around the track boundaries. A total of six different proton energies starting from 4 MeV to 24 MeV with an energy gap of 4 MeV were chosen for the study of the neutron yields and the estimation of doses. Nearly, 92% of the recoil tracks developed after chemical etching were circular in nature, but the size distributions of the recoil tracks were not found to be linearly dependent on the projectile energy. The neutron yield and dose values were found to be increasing linearly with increasing projectile energies. The response of CR-39 detector was also investigated at different beam currents at two different proton energies. A linear increase of neutron yield with beam current was observed.

  10. Reconstruction 3-dimensional image from 2-dimensional image of status optical coherence tomography (OCT) for analysis of changes in retinal thickness

    SciTech Connect (OSTI)

    Arinilhaq,; Widita, Rena [Department of Physics, Nuclear Physics and Biophysics Research Group, Institut Teknologi Bandung (Indonesia)

    2014-09-30

    Optical Coherence Tomography is often used in medical image acquisition to diagnose that change due easy to use and low price. Unfortunately, this type of examination produces a two-dimensional retinal image of the point of acquisition. Therefore, this study developed a method that combines and reconstruct 2-dimensional retinal images into three-dimensional images to display volumetric macular accurately. The system is built with three main stages: data acquisition, data extraction and 3-dimensional reconstruction. At data acquisition step, Optical Coherence Tomography produced six *.jpg images of each patient were further extracted with MATLAB 2010a software into six one-dimensional arrays. The six arrays are combined into a 3-dimensional matrix using a kriging interpolation method with SURFER9 resulting 3-dimensional graphics of macula. Finally, system provides three-dimensional color graphs based on the data distribution normal macula. The reconstruction system which has been designed produces three-dimensional images with size of 481 481 h (retinal thickness) pixels.

  11. Influence of dosing sequence and film thickness on structure and resistivity of Al-ZnO films grown by atomic layer deposition

    SciTech Connect (OSTI)

    Pollock, Evan B. Lad, Robert J.

    2014-07-01

    Aluminum-doped zinc oxide (AZO) films were deposited onto amorphous silica substrates using an atomic layer deposition process with diethyl zinc (DEZ), trimethyl aluminum (TMA), and deionized water at 200?C. Three different Al doping sequences were used at a ZnO:Al ratio of 11:1 within the films. A minimum film resistivity of 1.6??10{sup ?3}?? cm was produced using sequential dosing of DEZ, TMA, DEZ, followed by H{sub 2}O for the Al doping step. This ZAZW sequence yielded an AZO film resistivity that is independent of film thickness, crystallographic texture, and grain size, as determined by high resolution x-ray diffraction (XRD). A pseudo-Voigt analysis method yields values for grain sizes that are smaller than those calculated using other XRD methods. Anisotropic grain sizes or variations in crystallographic texture have minimal influence on film resistivity, which suggests that factors other than film texture, such as intragrain scattering, may be important in influencing film resistivity.

  12. Dependence of inverse-spin Hall effect and spin-rectified voltage on tantalum thickness in Ta/CoFeB bilayer structure

    SciTech Connect (OSTI)

    Kim, Sang-Il; Seo, Min-Su; Park, Seung-Young; Kim, Dong-Jun; Park, Byong-Guk

    2015-01-19

    Ta-layer thickness (t{sub Ta}) dependence of the measured DC voltage V from the inverse-spin Hall effect (ISHE) in Ta/CoFeB bilayer structure is experimentally investigated using the ferromagnetic resonance in the TE{sub 011} resonant cavity. The ISHE signals excluding the spin-rectified effect (SRE) were separated from the fitted curve of V against t{sub Ta}. For t{sub Ta} ≈ λ{sub Ta} (Ta-spin diffusion length = 2.7 nm), the deviation in ISHE voltage V{sub ISH} between the experimental and theoretical values is significantly increased because of the large SRE contribution, which also results in a large deviation in the spin Hall angle θ{sub SH} (from 10% to 40%). However, when t{sub Ta} ≫ λ{sub Ta}, the V{sub ISH} values are consistent with theoretical values because the SRE terms become negligible, which subsequently improves the accuracy of the obtained θ{sub SH} within 4% deviation. The results will provide an outline for an accurate estimation of the θ{sub SH} for materials with small λ value, which would be useful for utilizing the spin Hall effect in a 3-terminal spintronic devices in which magnetization can be controlled by in-plane current.

  13. High quality HfO{sub 2}/p-GaSb(001) metal-oxide-semiconductor capacitors with 0.8?nm equivalent oxide thickness

    SciTech Connect (OSTI)

    Barth, Michael; Datta, Suman; Bruce Rayner, G.; McDonnell, Stephen; Wallace, Robert M.; Bennett, Brian R.; Engel-Herbert, Roman

    2014-12-01

    We investigate in-situ cleaning of GaSb surfaces and its effect on the electrical performance of p-type GaSb metal-oxide-semiconductor capacitor (MOSCAP) using a remote hydrogen plasma. Ultrathin HfO{sub 2} films grown by atomic layer deposition were used as a high permittivity gate dielectric. Compared to conventional ex-situ chemical cleaning methods, the in-situ GaSb surface treatment resulted in a drastic improvement in the impedance characteristics of the MOSCAPs, directly evidencing a much lower interface trap density and enhanced Fermi level movement efficiency. We demonstrate that by using a combination of ex-situ and in-situ surface cleaning steps, aggressively scaled HfO{sub 2}/p-GaSb MOSCAP structures with a low equivalent oxide thickness of 0.8?nm and efficient gate modulation of the surface potential are achieved, allowing to push the Fermi level far away from the valence band edge high up into the band gap of GaSb.

  14. Methods and costs of thin-seam mining. Final report, 25 September 1977-24 January 1979. [Thin seam in association with a thick seam

    SciTech Connect (OSTI)

    Finch, T.E.; Fidler, E.L.

    1981-02-01

    This report defines the state of the art (circa 1978) in removing thin coal seams associated with vastly thicker seams found in the surface coal mines of the western United States. New techniques are evaluated and an innovative method and machine is proposed. Western states resource recovery regulations are addressed and representative mining operations are examined. Thin seam recovery is investigated through its effect on (1) overburden removal, (2) conventional seam extraction methods, and (3) innovative techniques. Equations and graphs are used to accommodate the variable stratigraphic positions in the mining sequence on which thin seams occur. Industrial concern and agency regulations provided the impetus for this study of total resource recovery. The results are a compendium of thin seam removal methods and costs. The work explains how the mining industry recovers thin coal seams in western surface mines where extremely thick seams naturally hold the most attention. It explains what new developments imply and where to look for new improvements and their probable adaptability.

  15. Influence of humidity on the scattering of {gamma}-rays in soil

    SciTech Connect (OSTI)

    Cortes, M. L.; Melo, L. M.; Cristancho, F.

    2010-08-04

    Transmission and backscattering of {gamma}-rays have been used to study soil properties such as its porosity, hydraulic conductivity and also for the detection of organic material buried in soil. These applications require a deeper understanding of the interaction of {gamma}-rays with soil. In the present work a study of the interaction of 511 keV {gamma}-rays with layers of sand varying both its humidity and thickness is presented. The experimental set-up uses the positron decay of a {sup 22}Na source, and two gamma detectors connected in fast time-coincidence. Both transmitted and backscattered spectra are obtained. For transmission, the photopeak and the low angle scattered photons are studied, and for backscattering we analyze the number of single and multiple backscattered photons as a function of thickness. Finally, a theoretical model for the derivative of the number of backscattered photons as a function of depth is presented.

  16. Population studies. XIII. A new analysis of the Bidelman-Macconnell 'weak-metal' stars - confirmation of metal-poor stars in the thick disk of the galaxy

    SciTech Connect (OSTI)

    Beers, Timothy C.; Norris, John E.; Placco, Vinicius M.; Lee, Young Sun; Rossi, Silvia; Carollo, Daniela; Masseron, Thomas E-mail: jen@mso.anu.edu.au E-mail: youngsun@cnu.ac.kr E-mail: daniela.carollo@mq.edu.au

    2014-10-10

    A new set of very high signal-to-noise (S/N > 100/1), medium-resolution (R ? 3000) optical spectra have been obtained for 302 of the candidate 'weak-metal' stars selected by Bidelman and MacConnell. We use these data to calibrate the recently developed generalization of the Sloan Extension for Galactic Exploration and Understanding and Exploration (SEGUE) Stellar Parameter Pipeline, and obtain estimates of the atmospheric parameters (T {sub eff}, log g, and [Fe/H]) for these non-Sloan Digital Sky Survey/SEGUE data; we also obtain estimates of [C/Fe]. The new abundance measurements are shown to be consistent with available high-resolution spectroscopic determinations, and represent a substantial improvement over the accuracies obtained from the previous photometric estimates reported in Paper I of this series. The apparent offset in the photometric abundances of the giants in this sample noted by several authors is confirmed by our new spectroscopy; no such effect is found for the dwarfs. The presence of a metal-weak thick-disk (MWTD) population is clearly supported by these new abundance data. Some 25% of the stars with metallicities 1.8 < [Fe/H] ?0.8 exhibit orbital eccentricities e < 0.4, yet are clearly separated from members of the inner-halo population with similar metallicities by their location in a Lindblad energy versus angular momentum diagram. A comparison is made with recent results for a similar-size sample of Radial Velocity Experiment stars from Ruchti et al. We conclude, based on both of these samples, that the MWTD is real, and must be accounted for in discussions of the formation and evolution of the disk system of the Milky Way.

  17. Oxygen Reduction Reaction Measurements on Platinum Electrocatalysts Utilizing Rotating Disk Electrode Technique: II. Influence of Ink Formulation, Catalyst Layer Uniformity and Thickness

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shinozaki, Kazuma; Zack, Jason W.; Pylypenko, Svitlana; Pivovar, Bryan S.; Kocha, Shyam S.

    2015-09-17

    Platinum electrocatalysts supported on high surface area and Vulcan carbon blacks (Pt/HSC, Pt/V) were characterized in rotating disk electrode (RDE) setups for electrochemical area (ECA) and oxygen reduction reaction (ORR) area specific activity (SA) and mass specific activity (MA) at 0.9 V. Films fabricated using several ink formulations and film-drying techniques were characterized for a statistically significant number of independent samples. The highest quality Pt/HSC films exhibited MA 870 ± 91 mA/mgPt and SA 864 ± 56 μA/cm2 Pt while Pt/V had MA 706 ± 42 mA/mgPt and SA 1120 ± 70 μA/cm2 Pt when measured in 0.1 M HClO4,more » 20 mV/s, 100 kPa O2 and 23±2°C. An enhancement factor of 2.8 in themeasured SA was observable on eliminating Nafion ionomer and employing extremely thin, uniform films (~4.5 μg/cm2 Pt) of Pt/HSC. The ECA for Pt/HSC (99 ± 7 m2/gPt) and Pt/V (65 ± 5 m2/gPt) were statistically invariant and insensitive to film uniformity/thickness/fabrication technique; accordingly, enhancements in MA are wholly attributable to increases in SA. Impedance measurements coupled with scanning electron microscopy were used to de-convolute the losses within the catalyst layer and ascribed to the catalyst layer resistance, oxygen diffusion, and sulfonate anion adsorption/blocking. The ramifications of these results for proton exchange membrane fuel cells have also been examined.« less

  18. This invention relates to methods of generating NP gallium nitride (GaN) across large areas (>1 cm.sup.2) with controlled pore diameters, pore density, and porosity. Also disclosed are methods of generating novel optoelectronic devices based on porous GaN. Additionally a layer transfer scheme to separate and create free-standing crystalline GaN thin layers is disclosed that enables a new device manufacturing paradigm involving substrate recycling. Other disclosed embodiments of this invention relate to fabrication of GaN based nanocrystals and the use of NP GaN electrodes for electrolysis, water splitting, or photosynthetic process applications.

    DOE Patents [OSTI]

    Zhang, Yu; Sun, Qian; Han, Jung

    2015-12-08

    This invention relates to methods of generating NP gallium nitride (GaN) across large areas (>1 cm.sup.2) with controlled pore diameters, pore density, and porosity. Also disclosed are methods of generating novel optoelectronic devices based on porous GaN. Additionally a layer transfer scheme to separate and create free-standing crystalline GaN thin layers is disclosed that enables a new device manufacturing paradigm involving substrate recycling. Other disclosed embodiments of this invention relate to fabrication of GaN based nanocrystals and the use of NP GaN electrodes for electrolysis, water splitting, or photosynthetic process applications.

  19. Controlling the crystallite size and influence of the film thickness on the optical and electrical characteristics of nanocrystalline Cu{sub 2}S films

    SciTech Connect (OSTI)

    Rafea, M. Abdel; Farag, A.A.M.; Roushdy, N.

    2012-02-15

    Highlights: Black-Right-Pointing-Pointer Modification of the preparation technique in order to deposit nanostructure Cu{sub 2}S thin films. Black-Right-Pointing-Pointer Controlling the crystallite size of the prepared films. Black-Right-Pointing-Pointer Study the surface morphology, optical and electrical characteristics of Cu{sub 2}S films. -- Abstract: In this work, Cu{sub 2}S nanocrystalline films have been successfully prepared using dip-coating technique. The stoichiometry and the structural characteristics of the prepared films were characterized by energy dispersive X-ray spectroscopy (EDX) and X-ray diffraction (XRD), respectively. The surface morphology of the deposited Cu{sub 2}S film was studied using both the scanning electron microscopy (SEM) and the atomic force microscopy (AFM). The SEM and AFM images indicate that the prepared Cu{sub 2}S films are characterized by a well-dispersed and highly dense with spherical like-shaped aggregates of size in the nano scale. The optical absorption measurements indicate that the Cu{sub 2}S nanoparticles have a direct band gap of 2.92 eV. The dispersion and absorption parameters such as the dispersion energy, oscillating energy, real and imaginary dielectric constants and dissipation factor were calculated within a wide wavelength range of the spectrum that indicates the suitability of the deposited films as solar absorber using this technique. The dark electrical resistivity ({rho}) measurements were carried out at different temperatures in the range 312-440 K. These results confirm the semiconducting characteristic of the prepared Cu{sub 2}S films. Moreover, two activation energies were obtained that indicate the presence of two dominating conduction mechanisms in these temperature ranges. The bulk electrical resistivity ({rho}{sub B}) and the mean free path (l{sub 0}) of charge carriers were estimated from the resistivity-thickness dependence. The heterojunction device of n-ZnCdS/p-Cu{sub 2}S behaves good rectifying property. The photovoltaic characteristic of the heterojunction device using the current-voltage characteristic under illumination of 100 mW/cm{sup 2} was also observed. Discussion of the obtained results and their comparison with the previous published data were also considered.

  20. Penetration depth and absorption mechanisms of spin currents in Ir{sub 20}Mn{sub 80} and Fe{sub 50}Mn{sub 50} polycrystalline films by ferromagnetic resonance and spin pumping

    SciTech Connect (OSTI)

    Merodio, P.; Ghosh, A.; Lemonias, C.; Gautier, E.; Ebels, U.; Chshiev, M.; Béa, H. E-mail: helene.bea@cea.fr; Baltz, V. E-mail: helene.bea@cea.fr

    2014-01-20

    Spintronics relies on the spin dependent transport properties of ferromagnets (Fs). Although antiferromagnets (AFs) are used for their magnetic properties only, some fundamental F-spintronics phenomena like spin transfer torque, domain wall motion, and tunnel anisotropic magnetoresistance also occur with AFs, thus making AF-spintronics attractive. Here, room temperature critical depths and absorption mechanisms of spin currents in Ir{sub 20}Mn{sub 80} and Fe{sub 50}Mn{sub 50} are determined by F-resonance and spin pumping. In particular, we find room temperature critical depths originating from different absorption mechanisms: dephasing for Ir{sub 20}Mn{sub 80} and spin flipping for Fe{sub 50}Mn{sub 50}.

  1. Seismic signatures of the Lodgepole fractured reservoir in Utah-Wyoming overthrust belt

    SciTech Connect (OSTI)

    Parra, J.; Collier, H.; Angstman, B.

    1997-08-01

    In low porosity, low permeability zones, natural fractures are the primary source of permeability which affect both production and injection of fluids. The open fractures do not contribute much to porosity, but they provide an increased drainage network to any porosity. An important approach to characterizing the fracture orientation and fracture permeability of reservoir formations is one based upon the effects of such conditions on the propagation of acoustic and seismic waves in the rock. We present the feasibility of using seismic measurement techniques to map the fracture zones between wells spaced 2400 ft at depths of about 1000 ft. For this purpose we constructed computer models (which include azimuthal anisotropy) using Lodgepole reservoir parameters to predict seismic signatures recorded at the borehole scale, crosswell scale, and 3 D seismic scale. We have integrated well logs with existing 2D surfaces seismic to produce petrophysical and geological cross sections to determine the reservoir parameters and geometry for the computer models. In particular, the model responses are used to evaluate if surface seismic and crosswell seismic measurements can capture the anisotropy due to vertical fractures. Preliminary results suggested that seismic waves transmitted between two wells will propagate in carbonate fracture reservoirs, and the signal can be received above the noise level at the distance of 2400 ft. In addition, the large velocities contrast between the main fracture zone and the underlying unfractured Boundary Ridge Member, suggested that borehole reflection imaging may be appropriate to map and fracture zone thickness variation and fracture distributions in the reservoir.

  2. Thickness dependence of magnetoelectric response for composites of Pb(Zr{sub 0.52}Ti{sub 0.48})O{sub 3} films on CoFe{sub 2}O{sub 4} ceramic substrates

    SciTech Connect (OSTI)

    Wang, Jing Zhu, Kongjun; Wu, Xia; Deng, Chaoyong; Peng, Renci; Wang, Jianjun

    2014-08-15

    Using chemical solution spin-coating we grew Pb(Zr{sub 0.52}Ti{sub 0.48})O{sub 3} films of different thicknesses on highly dense CoFe{sub 2}O{sub 4} ceramics. X-ray diffraction revealed no other phases except Pb(Zr{sub 0.52}Ti{sub 0.48})O{sub 3} and CoFe{sub 2}O{sub 4}. In many of these samples we observed typical ferroelectric hysteresis loops, butterfly-shaped piezoelectric strains, and the magnetic-field-dependent magnetostriction. These behaviors caused appreciable magnetoelectric responses based on magnetic-mechanical-electric coupling. Our results indicated that the thickness of the Pb(Zr{sub 0.52}Ti{sub 0.48})O{sub 3} film was important in obtaining strong magnetoelectric coupling.

  3. Effect of spacer layer thickness on multi-stacked InGaAs quantum dots grown on GaAs (311)B substrate for application to intermediate band solar cells

    SciTech Connect (OSTI)

    Shoji, Yasushi; Narahara, Kohei; Okada, Yoshitaka; Tanaka, Hideharu; Kita, Takashi; Akimoto, Katsuhiro

    2012-04-01

    We have investigated the properties of multi-stacked layers of self-organized In{sub 0.4}Ga{sub 0.6}As quantum dots (QDs) on GaAs (311)B grown by molecular beam epitaxy. We found that a high degree of in-plane ordering of QDs structure with a six-fold symmetry was maintained though the growth has been performed at a higher growth rate than the conventional conditions. The dependence of photoluminescence characteristics on spacer layer thickness showed an increasing degree of electronic coupling between the stacked QDs for thinner spacer layers. The external quantum efficiency for an InGaAs/GaAs quantum dot solar cell (QDSC) with a thin spacer layer thickness increased in the longer wavelength range due to additive contribution from QD layers inserted in the intrinsic region. Furthermore, a photocurrent production by 2-step photon absorption has been observed at room temperature for the InGaAs/GaAs QDSC with a spacer layer thickness of 15 nm.

  4. Multi-frequency optical-depth maps and the case for free-free absorption in two compact symmetric radio sources: The CSO candidate J1324 + 4048 and the CSO J0029 + 3457

    SciTech Connect (OSTI)

    Marr, J. M.; Read, J.; Morris, A. O.; Perry, T. M.; Taylor, G. B.

    2014-01-10

    We obtained dual-polarization very long baseline interferometry observations at six frequencies of the compact symmetric object J0029 + 3457 and the compact symmetric object candidate J1324 + 4048. By comparing the three lower-frequency maps with extrapolations of the high-frequency maps, we produced maps of the optical depth as a function of frequency. The morphology of the optical-depth maps of J1324 + 4048 is strikingly smooth, suggestive of a foreground screen of absorbing gas. The spectra at the intensity peaks fit a simple free-free absorption (FFA) model, with ?{sub ?}{sup 2}?2, better than a simple synchrotron self-absorption model, in which ?{sub ?}{sup 2}?3.5--5.5. We conclude that the case for FFA in J1324 + 4048 is strong. The optical-depth maps of J0029 + 3457 exhibit structure, but the morphology does not correlate with that in the intensity maps. The fit of the spectra at the peaks to a simple FFA model yields ?{sub ?}{sup 2}?1, but because the turnover is gradual, the fit is relatively insensitive to the input parameters. We find that FFA by a thin amount of gas in J0029 + 3457 is likely but not definitive. One compact feature in J0029 + 3457 has an inverted spectrum even at the highest frequencies. We infer this to be the location of the core and estimate an upper limit to the magnetic field of order 3 Gauss at a radius of order 1 pc. In comparison with maps from observations at earlier epochs, no apparent growth in either J1324 + 4048 or J0029 + 3457 is apparent, with upper limits of 0.03 and 0.02 mas yr{sup 1}, corresponding to maximum linear separation speeds of 0.6c and 0.4c.

  5. The impact of monolayer coverage, barrier thickness and growth rate on the thermal stability of photoluminescence of coupled InAs/GaAs quantum dot hetero-structure with quaternary capping of InAlGaAs

    SciTech Connect (OSTI)

    Mandal, A.; Verma, U.; Halder, N.; Chakrabarti, S.

    2012-03-15

    Highlight: Black-Right-Pointing-Pointer Coupled InAs/GaAs MQDs with (In{sub 0.21}Al{sub 0.21}Ga{sub 0.58}As + GaAs) caps are considered. Black-Right-Pointing-Pointer Monolayer coverage, barrier thickness and growth rate of the dots are the factors. Black-Right-Pointing-Pointer PL peaks for the samples are within 1.1-1.3 {mu}m; significant for IBSCs and lasers. Black-Right-Pointing-Pointer NPTP (non-resonant multi-phonon assisted tunneling process) effect on FWHM of PL. -- Abstract: The self-assembled InAs/GaAs MQDs are widely investigated for their potential application in optoelectronic devices like lasers and photovoltaics. We have explored the effect of QD growth rate and structural parameters like capping layer thickness on the morphology and optical properties of the MQD heterostructures overgrown with a combination capping of InAlGaAs and GaAs. The growth rate of the seed layers in the MQD samples is also varied to investigate its effect in the vertical stacking of the islands. The change in the morphology and the optical properties of the samples due to variation in growth and structural parameters are explained by the presence of strain in the QD structures, which arises due to lattice mismatch.

  6. Total reflection inelastic x-ray scattering from a 10 nm thick La{sub 0.6}Sr{sub 0.2}CoO{sub 3} thin film.

    SciTech Connect (OSTI)

    Fister, T. T.; Fong, D. D.; Eastman, J. A.; Iddir, H.; Zapol, P.; Fuoss, P. H.; Balasubramanian, M.; Gordon, R. A.; Balasubramaniam, K. R.; Salvador, P. A.; Simon Fraser Univ.; Carnegie Mellon Univ.

    2011-01-18

    To study equilibrium changes in composition, valence, and electronic structure near the surface and into the bulk, we demonstrate the use of a new approach, total-reflection inelastic x-ray scattering, as a sub-keV spectroscopy capable of depth profiling chemical changes in thin films with nanometer resolution. By comparing data acquired under total x-ray reflection and penetrating conditions, we are able to separate the O K-edge spectra from a 10 nm La{sub 0.6}Sr{sub 0.4}CoO{sub 3} thin film from that of the underlying SrTiO{sub 3} substrate. With a smaller wavelength probe than comparable soft x-ray absorption measurements, we also describe the ability to easily access dipole-forbidden final states, using the dramatic evolution of the La N{sub 4,5} edge with momentum transfer as an example.

  7. Analytical Modeling At Coso Geothermal Area (1980) | Open Energy...

    Open Energy Info (EERE)

    5000 ft., depth 5000 ft., and steam-filled porosity of 5%. References Hardee, H.C. ; Larson, D.W. (1 January 1980) Thermal techniques for characterizing magma body geometries...

  8. Thick-shell nanocrystal quantum dots

    DOE Patents [OSTI]

    Hollingsworth, Jennifer A. (Los Alamos, NM); Chen, Yongfen (Eugene, OR); Klimov, Victor I. (Los Alamos, NM); Htoon, Han (Los Alamos, NM); Vela, Javier (Los Alamos, NM)

    2011-05-03

    Colloidal nanocrystal quantum dots comprising an inner core having an average diameter of at least 1.5 nm and an outer shell, where said outer shell comprises multiple monolayers, wherein at least 30% of the quantum dots have an on-time fraction of 0.80 or greater under continuous excitation conditions for a period of time of at least 10 minutes.

  9. Thick diffusion limit boundary layer test problems

    SciTech Connect (OSTI)

    Bailey, T. S.; Warsa, J. S.; Chang, J. H.; Adams, M. L.

    2013-07-01

    We develop two simple test problems that quantify the behavior of computational transport solutions in the presence of boundary layers that are not resolved by the spatial grid. In particular we study the quantitative effects of 'contamination' terms that, according to previous asymptotic analyses, may have a detrimental effect on the solutions obtained by both discontinuous finite element (DFEM) and characteristic-method (CM) spatial discretizations, at least for boundary layers caused by azimuthally asymmetric incident intensities. Few numerical results have illustrated the effects of this contamination, and none have quantified it to our knowledge. Our test problems use leading-order analytic solutions that should be equal to zero in the problem interior, which means the observed interior solution is the error introduced by the contamination terms. Results from DFEM solutions demonstrate that the contamination terms can cause error propagation into the problem interior for both orthogonal and non-orthogonal grids, and that this error is much worse for non-orthogonal grids. This behavior is consistent with the predictions of previous analyses. We conclude that these boundary layer test problems and their variants are useful tools for the study of errors that are introduced by unresolved boundary layers in diffusive transport problems. (authors)

  10. A modeling study of the effect of depth of burial of depleted uranium and thorium on radon gas flux at a dry desert alluvial soil radioactive waste management site (RWMS)

    SciTech Connect (OSTI)

    Lindstrom, F.T.; Cawlfield, D.E.; Emer, D.F.; Shott, G.J.

    1993-08-01

    An integral part of designing low-level waste (LLW) disposal pits and their associated closure covers in very dry desert alluvium is the use of a radon gas transport and fate model. Radon-222 has the potential to be a real heath hazard. The production of radon-222 results from the radioactive decay (a particle emission) of radium-226 in the uranium-235 and 238 Bateman chains. It is also produced in the thorium-230 series. Both long lived radionuclides have been proposed for disposal in the shallow land burial pits in Area 5 RWMS compound of Nevada Test Site (NTS). The constructed physics based model includes diffusion and barometric pressure-induced advection of an M-chain of radionuclides. The usual Bateman decay mechanics are included for each radionuclide. Both linear reversible and linear irreversible first order sorption kinetics are assumed for each radionuclide. This report presents the details of using the noble gas transport model, CASCADR9, in an engineering design study mode. Given data on the low-level waste stream, which constitutes the ultimate source of radon-222 in the RWMS, CASCADR9 is used to generate the surface flux (pCi/cm{sup 2}-sec) of radon-222 under the realistic atmospheric and alluvial soil conditions found in the RWMS at Area 5, of the NTS. Specifically, this study examines the surface flux of radon-222 as a function of the depth of burial below the land surface.

  11. H I, CO, and Planck/IRAS dust properties in the high latitude cloud complex, MBM 53, 54, 55 and HLCG 92 – 35. Possible evidence for an optically thick H I envelope around the CO clouds

    SciTech Connect (OSTI)

    Fukui, Yasuo; Okamoto, Ryuji; Kaji, Ryohei; Yamamoto, Hiroaki; Torii, Kazufumi; Hayakawa, Takahiro; Tachihara, Kengo; Okuda, Takeshi; Ohama, Akio; Kuroda, Yutaka; Kuwahara, Toshihisa; Dickey, John M.

    2014-11-20

    We present an analysis of the H I and CO gas in conjunction with the Planck/IRAS submillimeter/far-infrared dust properties toward the most outstanding high latitude clouds MBM 53, 54, 55 and HLCG 92 – 35 at b = –30° to – 45°. The CO emission, dust opacity at 353 GHz (τ{sub 353}), and dust temperature (T {sub d}) show generally good spatial correspondence. On the other hand, the correspondence between the H I emission and the dust properties is less clear than in CO. The integrated H I intensity W{sub H} {sub I} and τ{sub 353} show a large scatter with a correlation coefficient of ∼0.6 for a T {sub d} range from 16 K to 22 K. We find, however, that W{sub H} {sub I} and τ{sub 353} show better correlation for smaller ranges of T {sub d} every 0.5 K, generally with a correlation coefficient of 0.7-0.9. We set up a hypothesis that the H I gas associated with the highest T {sub d} ≥ 21.5 K is optically thin, whereas the H I emission is generally optically thick for T {sub d} lower than 21.5 K. We have determined a relationship for the optically thin H I gas between atomic hydrogen column density and τ{sub 353}, N{sub H} {sub I} (cm{sup −2})=(1.5×10{sup 26})⋅τ{sub 353}, under the assumption that the dust properties are uniform and we have applied this to estimate N{sub H} {sub I} from τ{sub 353} for the whole cloud. N{sub H} {sub I} was then used to solve for T {sub s} and τ{sub H} {sub I} over the region. The result shows that the H I is dominated by optically thick gas having a low spin temperature of 20-40 K and a density of 40-160 cm{sup –3}. The H I envelope has a total mass of ∼1.2 × 10{sup 4} M {sub ☉}, an order of magnitude larger than that of the CO clouds. The H I envelope properties derived by this method do not rule out a mixture of H I and H{sub 2} in the dark gas, but we present indirect evidence that most of the gas mass is in the atomic state.

  12. Dependency of tunneling magneto-resistance on Fe insertion-layer thickness in Co{sub 2}Fe{sub 6}B{sub 2}/MgO-based magnetic tunneling junctions

    SciTech Connect (OSTI)

    Chae, Kyo-Suk; Park, Jea-Gun

    2015-04-21

    For Co{sub 2}Fe{sub 6}B{sub 2}/MgO-based perpendicular magnetic tunneling junctions spin valves with [Co/Pd]{sub n}-synthetic-antiferromagnetic (SyAF) layers, the tunneling-magneto-resistance (TMR) ratio strongly depends on the nanoscale Fe insertion-layer thickness (t{sub Fe}) between the Co{sub 2}Fe{sub 6}B{sub 2} pinned layer and MgO tunneling barrier. The TMR ratio rapidly increased as t{sub Fe} increased up to 0.4?nm by improving the crystalline linearity of a MgO tunneling barrier and by suppressing the diffusion of Pd atoms from a [Co/Pd]{sub n}-SyAF. However, it abruptly decreased by further increasing t{sub Fe} in transferring interfacial-perpendicular magnetic anisotropy into the IMA characteristic of the Co{sub 2}Fe{sub 6}B{sub 2} pinned layer. Thus, the TMR ratio peaked at t{sub Fe}?=?0.4?nm: i.e., 120% at 29???m{sup 2}.

  13. Ground-state energy trends in single and multilayered coupled InAs/GaAs quantum dots capped with InGaAs layers: Effects of InGaAs layer thickness and annealing temperature

    SciTech Connect (OSTI)

    Shah, S.; Ghosh, K.; Jejurikar, S.; Mishra, A.; Chakrabarti, S.

    2013-08-01

    Graphical abstract: - Highlights: Investigation of ground state energy in single and multi-layered InAs/GaAs QD. Strain reducing layer (InGaAs) prevents the formation of non-radiative. Strain reducing layer (InGaAs) is responsible for high activation energy. Significant deviation from the Varshni model, E(T) = E ? ?T{sup 2}/T + ?. - Abstract: Vertically coupled, multilayered InAs/GaAs quantum dots (QDs) covered with thin InGaAs strain-reducing layers (SRLs) are in demand for various technological applications. We investigated low temperature photoluminescence of single and multilayered structures in which the SRL thickness was varied. The SRL layer was responsible for high activation energies. Deviation of experimental data from the Varshni (1967) model, E(T) = E ? ? T{sup 2}/T + ?, suggests that the InAs-layered QDs have properties different from those in bulk material. Anomalous ground-state peak linewidths (FWHM), especially for annealed multilayer structures, were observed. A ground-state peak blue-shift with a broadened linewidth was also observed. Loss of intensity was detected in samples annealed at 800 C. Presence of SRLs prevents formation of non-radiative centers under high temperature annealing. The results indicate the potential importance of such structures in optoelectronic applications.

  14. Permeability and porosity of hydrate-bearing sediments in the northern Gulf of Mexico

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Daigle, Hugh; Cook, Ann; Malinverno, Alberto

    2015-10-14

    Hydrate-bearing sands are being actively explored because they contain the highest concentrations of hydrate and are the most economically recoverable hydrate resource. However, relatively little is known about the mechanisms or timescales of hydrate formation, which are related to methane supply, fluid flux, and host sediment properties such as permeability. We used logging-while-drilling data from locations in the northern Gulf of Mexico to develop an effective medium theory-based model for predicting permeability based on clay-sized sediment fraction. The model considers permeability varying between sand and clay endpoint permeabilities that are defined from laboratory data. We verified the model using permeabilitymore » measurements on core samples from three boreholes, and then used the model to predict permeability in two wells drilled in Walker Ridge Block 313 during the Gulf of Mexico Gas Hydrate Joint Industry Project Leg II expedition in 2009. We found that the cleanest sands (clay-sized fraction <0.05) had intrinsic (hydrate-free) permeability contrasts of 5-6 orders of magnitude with the surrounding clays, which is sufficient to provide focused hydrate formation due to advection of methane from a deep source or diffusion of microbial methane from nearby clay layers. In sands where the clay-sized fraction exceeds 0.05, the permeability reduces significantly and focused flow is less pronounced. In these cases, diffusion of dissolved microbial methane is most likely the preferred mode of methane supply for hydrate formation. In conclusion, our results provide important constraints on methane supply mechanisms in the Walker Ridge area and have global implications for evaluating rates of methane migration and hydrate formation in hydrate-bearing sands.« less

  15. Carbide-Derived Carbons with Tunable Porosity Optimized for Hydrogen Storage

    SciTech Connect (OSTI)

    Fisher, John E.; Gogotsi, Yury; Yildirim, Taner

    2010-01-07

    On-board hydrogen storage is a key requirement for fuel cell-powered cars and trucks. Porous carbon-based materials can in principle adsorb more hydrogen per unit weight at room temperature than liquid hydrogen at -176 oC. Achieving this goal requires interconnected pores with very high internal surface area, and binding energies between hydrogen and carbon significantly enhanced relative to H2 on graphite. In this project a systematic study of carbide-derived carbons, a novel form of porous carbon, was carried out to discover a high-performance hydrogen sorption material to meet the goal. In the event we were unable to improve on the state of the art in terms of stored hydrogen per unit weight, having encountered the same fundamental limit of all porous carbons: the very weak interaction between H2 and the carbon surface. On the other hand we did discover several strategies to improve storage capacity on a volume basis, which should be applicable to other forms of porous carbon. Further discoveries with potentially broader impacts include Proof that storage performance is not directly related to pore surface area, as had been previously claimed. Small pores (< 1.5 nm) are much more effective in storing hydrogen than larger ones, such that many materials with large total surface areas are sub-par performers. Established that the distribution of pore sizes can be controlled during CDC synthesis, which opens the possibility of developing high performance materials within a common family while targeting widely disparate applications. Examples being actively pursued with other funding sources include methane storage, electrode materials for batteries and supercapacitors with record high specific capacitance, and perm-selective membranes which bind cytokines for control of infections and possibly hemodialysis filters.

  16. Controlling porosity in lignin-derived nanoporous carbon for supercapacitor applications

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jeon, Ju-Won; Zhang, Libing; Lutkenhaus, Jodie L.; Laskar, Dhrubojyoti D.; Lemmon, John P.; Choi, Daiwon; Nandasiri, Manjula I.; Hashmi, Ali; Xu, Jie; Motkuri, Radha K.; et al

    2015-02-01

    Low-cost renewable lignin has been used as a precursor to produce porous carbons. However, to date, it has not been easy to obtain high surface area porous carbon without activation processes or templating agents. Here, we demonstrate that low molecular weight lignin yields highly porous carbon (1092 m² g⁻¹) with more graphitization through direct carbonization without additional activation processes or templating agents. We found that molecular weight and oxygen consumption during carbonization are critical factors to obtain high surface area, graphitized porous carbons. This highly porous carbon from low-cost renewable lignin sources is a good candidate for supercapacitor electrode materials.

  17. Properties of CO2-Rich Pore Fluids and Their Effect on Porosity Evolution in EGS Rocks

    Broader source: Energy.gov [DOE]

    Project objective: Quantify key parameters critically needed for developing and validating numerical modeling of chemical interactions between EGS reservoir rocks and supercritical CO2and CO2-rich aqueous fluids.

  18. Rapidly assessing the activation conditions and porosity of metal-organic frameworks using thermogravimetric analysis

    SciTech Connect (OSTI)

    McDonald, TM; Bloch, ED; Long, JR

    2015-01-01

    A methodology utilizing a thermogravimetric analyzer to monitor propane uptake following incremental increases of the temperature is demonstrated as a means of rapidly identifying porous materials and determining the optimum activation conditions of metal-organic frameworks.

  19. Permeability and porosity of hydrate-bearing sediments in the northern Gulf of Mexico

    SciTech Connect (OSTI)

    Daigle, Hugh; Cook, Ann; Malinverno, Alberto

    2015-10-14

    Hydrate-bearing sands are being actively explored because they contain the highest concentrations of hydrate and are the most economically recoverable hydrate resource. However, relatively little is known about the mechanisms or timescales of hydrate formation, which are related to methane supply, fluid flux, and host sediment properties such as permeability. We used logging-while-drilling data from locations in the northern Gulf of Mexico to develop an effective medium theory-based model for predicting permeability based on clay-sized sediment fraction. The model considers permeability varying between sand and clay endpoint permeabilities that are defined from laboratory data. We verified the model using permeability measurements on core samples from three boreholes, and then used the model to predict permeability in two wells drilled in Walker Ridge Block 313 during the Gulf of Mexico Gas Hydrate Joint Industry Project Leg II expedition in 2009. We found that the cleanest sands (clay-sized fraction <0.05) had intrinsic (hydrate-free) permeability contrasts of 5-6 orders of magnitude with the surrounding clays, which is sufficient to provide focused hydrate formation due to advection of methane from a deep source or diffusion of microbial methane from nearby clay layers. In sands where the clay-sized fraction exceeds 0.05, the permeability reduces significantly and focused flow is less pronounced. In these cases, diffusion of dissolved microbial methane is most likely the preferred mode of methane supply for hydrate formation. In conclusion, our results provide important constraints on methane supply mechanisms in the Walker Ridge area and have global implications for evaluating rates of methane migration and hydrate formation in hydrate-bearing sands.

  20. Toward the standard population synthesis model of the X-ray background: Evolution of X-ray luminosity and absorption functions of active galactic nuclei including Compton-thick populations

    SciTech Connect (OSTI)

    Ueda, Yoshihiro; Akiyama, Masayuki; Hasinger, Gnther; Miyaji, Takamitsu; Watson, Michael G.

    2014-05-10

    We present the most up to date X-ray luminosity function (XLF) and absorption function of active galactic nuclei (AGNs) over the redshift range from 0 to 5, utilizing the largest, highly complete sample ever available obtained from surveys performed with Swift/BAT, MAXI, ASCA, XMM-Newton, Chandra, and ROSAT. The combined sample, including that of the Subaru/XMM-Newton Deep Survey, consists of 4039 detections in the soft (0.5-2 keV) and/or hard (>2 keV) band. We utilize a maximum likelihood method to reproduce the count rate versus redshift distribution for each survey, by taking into account the evolution of the absorbed fraction, the contribution from Compton-thick (CTK) AGNs, and broadband spectra of AGNs, including reflection components from tori based on the luminosity- and redshift-dependent unified scheme. We find that the shape of the XLF at z ? 1-3 is significantly different from that in the local universe, for which the luminosity-dependent density evolution model gives much better description than the luminosity and density evolution model. These results establish the standard population synthesis model of the X-ray background (XRB), which well reproduces the source counts, the observed fractions of CTK AGNs, and the spectrum of the hard XRB. The number ratio of CTK AGNs to the absorbed Compton-thin (CTN) AGNs is constrained to be ?0.5-1.6 to produce the 20-50 keV XRB intensity within present uncertainties, by assuming that they follow the same evolution as CTN AGNs. The growth history of supermassive black holes is discussed based on the new AGN bolometric luminosity function.