National Library of Energy BETA

Sample records for density lithium-sulfur cells

  1. Development of High Energy Density Lithium-Sulfur Cells

    Broader source: Energy.gov [DOE]

    2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  2. Development of High Energy Density Lithium-Sulfur Cells

    Broader source: Energy.gov [DOE]

    2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  3. Sparingly Solvating Electrolytes for High Energy Density Lithium-Sulfur

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Batteries - Joint Center for Energy Storage Research August 24, 2016, Videos Sparingly Solvating Electrolytes for High Energy Density Lithium-Sulfur Batteries As JCESR scientists work to develop lighter and less expensive chemistries than those used in current lithium-ion batteries, lithium-sulfur shows tremendous promise. However, current lithium-sulfur batteries require an excessive amount of electrolyte to achieve moderate cycle life. This perspective presents an alternate approach of

  4. Lithium / Sulfur Cells with Long Cycle Life and High Specific...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lithium Sulfur Cells with Long Cycle Life and High Specific Energy Lawrence Berkeley ... Song, M-K., Zhang, Y., Cairns, E.J., "A long-life, high-rate lithiumsulfur cell: a ...

  5. Sparingly Solvating Electrolytes for High Energy Density Lithium-Sulfur

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Batteries - Joint Center for Energy Storage Research July 11, 2016, Research Highlights Sparingly Solvating Electrolytes for High Energy Density Lithium-Sulfur Batteries Precipitation-dissolution Li-S chemistry achieved by sparingly solvating electrolyte and various electrolyte design concepts Scientific Achievement This work presents the promising new concepts of using sparingly solvating electrolyte to enable Li-S battery operation at lean electrolyte condition, as well as the design rules

  6. A Long-Life, High-Rate Lithium/Sulfur Cell: A Multifaceted Approach...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Long-Life, High-Rate LithiumSulfur Cell: A Multifaceted Approach to Enhancing Cell Performance Min-Kyu Song, , Yuegang Zhang,* ,, and Elton J. Cairns* ,, The...

  7. Lithium-Sulfur Batteries: Development of High Energy Lithium-Sulfur Cells for Electric Vehicle Applications

    SciTech Connect (OSTI)

    2010-10-01

    BEEST Project: Sion Power is developing a lithium-sulfur (Li-S) battery, a potentially cost-effective alternative to the Li-Ion battery that could store 400% more energy per pound. All batteries have 3 key partsa positive and negative electrode and an electrolytethat exchange ions to store and release electricity. Using different materials for these components changes a batterys chemistry and its ability to power a vehicle. Traditional Li-S batteries experience adverse reactions between the electrolyte and lithium-based negative electrode that ultimately limit the battery to less than 50 charge cycles. Sion Power will sandwich the lithium- and sulfur-based electrode films around a separator that protects the negative electrode and increases the number of charges the battery can complete in its lifetime. The design could eventually allow for a battery with 400% greater storage capacity per pound than Li-Ion batteries and the ability to complete more than 500 recharge cycles.

  8. Lithium-Sulfur Batteries: from Liquid to Solid Cells?

    SciTech Connect (OSTI)

    Lin, Zhan; Liang, Chengdu

    2015-01-01

    Lithium-sulfur (Li-S) batteries supply a theoretical specific energy 5 times higher than that of lithium-ion batteries (2,500 vs. ~500 Wh kg-1). However, the insulating properties and polysulfide shuttle effects of the sulfur cathode and the safety concerns of the lithium anode in liquid electrolytes are still key limitations to practical use of traditional Li-S batteries. In this review, we start with a brief discussion on fundamentals of Li-S batteries and key challenges associated with the conventional liquid cells. Then, we introduce the most recent progresses in the liquid systems, including the sulfur positive electrodes, the lithium negative electrodes, and the electrolytes and binders. We discuss the significance of investigating electrode reaction mechanisms in liquid cells using in-situ techniques to monitor the compositional and morphological changes. By moving from the traditional liquid cells to recent solid cells, we discuss the importance of this game-changing shift with positive advances in both solid electrolytes and electrode materials. Finally, the opportunities and perspectives for future research on Li-S batteries are presented.

  9. Lithium-Sulfur Batteries: from Liquid to Solid Cells?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lin, Zhan; Liang, Chengdu

    2014-11-11

    Lithium-sulfur (Li-S) batteries supply a theoretical specific energy 5 times higher than that of lithium-ion batteries (2,500 vs. ~500 Wh kg-1). However, the insulating properties and polysulfide shuttle effects of the sulfur cathode and the safety concerns of the lithium anode in liquid electrolytes are still key limitations to practical use of traditional Li-S batteries. In this review, we start with a brief discussion on fundamentals of Li-S batteries and key challenges associated with the conventional liquid cells. Then, we introduce the most recent progresses in the liquid systems, including the sulfur positive electrodes, the lithium negative electrodes, and themore » electrolytes and binders. We discuss the significance of investigating electrode reaction mechanisms in liquid cells using in-situ techniques to monitor the compositional and morphological changes. By moving from the traditional liquid cells to recent solid cells, we discuss the importance of this game-changing shift with positive advances in both solid electrolytes and electrode materials. Finally, the opportunities and perspectives for future research on Li-S batteries are presented.« less

  10. Lithium-Sulfur Batteries: from Liquid to Solid Cells?

    SciTech Connect (OSTI)

    Lin, Zhan; Liang, Chengdu

    2014-11-11

    Lithium-sulfur (Li-S) batteries supply a theoretical specific energy 5 times higher than that of lithium-ion batteries (2,500 vs. ~500 Wh kg-1). However, the insulating properties and polysulfide shuttle effects of the sulfur cathode and the safety concerns of the lithium anode in liquid electrolytes are still key limitations to practical use of traditional Li-S batteries. In this review, we start with a brief discussion on fundamentals of Li-S batteries and key challenges associated with the conventional liquid cells. Then, we introduce the most recent progresses in the liquid systems, including the sulfur positive electrodes, the lithium negative electrodes, and the electrolytes and binders. We discuss the significance of investigating electrode reaction mechanisms in liquid cells using in-situ techniques to monitor the compositional and morphological changes. By moving from the traditional liquid cells to recent solid cells, we discuss the importance of this game-changing shift with positive advances in both solid electrolytes and electrode materials. Finally, the opportunities and perspectives for future research on Li-S batteries are presented.

  11. Additives and Cathode Materials for High-Energy Lithium Sulfur...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries 2013 DOE Hydrogen and Fuel Cells...

  12. Fundamental Studies of Lithium-Sulfur Cell Chemistry

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Oct 1 2013 * Project end: Sept 30 2017 * Percent complete: 30% * Barriers addressed - Energy density - Cycle life * Total project funding - DOE share ( 2,000,000) - Contractor...

  13. Fundamental Studies of Lithium-Sulfur Cell Chemistry

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Oct 1 2013 * Project end: Sept 30 2017 * Percent complete: 60% * Barriers addressed - Energy density - Cycle life * Total project funding - DOE share ( 2,000,000) - Contractor...

  14. A class of polysulfide catholytes for lithium-sulfur batteries: energy density, cyclability, and voltage enhancement

    SciTech Connect (OSTI)

    Yu, XW; Manthiram, A

    2015-01-01

    Liquid-phase polysulfide catholytes are attracting much attention in lithium-sulfur (Li-S) batteries as they provide a facile dispersion and homogeneous distribution of the sulfur active material in the conductive matrix. However, the organic solvents used in lithium-polysulfide (Li-PS) batteries play an important role and have an impact on the physico-chemical characteristics of polysulfides. For instance, significantly higher voltages (similar to 2.7 V) of the S/S-n(2-) (4 <= n <= 8) redox couple are observed in Li-PS batteries with dimethyl sulfoxide (DMSO) and N-methyl-2-pyrrolidone (NMP) solvents. Accordingly, high power Li-PS batteries are presented here with the catholyte prepared with NMP solvent and operated with the highly reversible sulfur/long-chain polysulfide redox couple. On the other hand, a remarkable cyclability enhancement of the Li-PS battery is observed with the long-chain, ether-based tetraglyme (TEGDME) solvent. The voltage enhancement and the cyclability enhancement of the Li-PS batteries are attributed to the solvation effect, viscosity, and volatility of the solvents. Finally, highly concentrated polysulfide catholytes are successfully synthesized, with which high energy density Li-PS batteries are demonstrated by employing a multi-walled carbon nanotube (MWCNT) fabric electrode.

  15. Direct measurement of polysulfide shuttle current: A window into understanding the performance of lithium-sulfur cells

    SciTech Connect (OSTI)

    Moy, Derek; Manivannan, A.; Narayanan, S. R.

    2014-11-04

    The shuttling of polysulfide ions between the electrodes in a lithium-sulfur battery is a major technical issue limiting the self-discharge and cycle life of this high-energy rechargeable battery. Although there have been attempts to suppress the shuttling process, there has not been a direct measurement of the rate of shuttling. We report here a simple and direct measurement of the rate of the shuttling (that we term “shuttle current”), applicable to the study of any type of lithium-sulfur cell. We demonstrate the effectiveness of this measurement technique using cells with and without lithium nitrate (a widely-used shuttle suppressor additive). We present a phenomenological analysis of the shuttling process and simulate the shuttle currents as a function of the state-of-charge of a cell. We also demonstrate how the rate of decay of the shuttle current can be used to predict the capacity fade in a lithium-sulfur cell due to the shuttle process. As a result, we expect that this new ability to directly measure shuttle currents will provide greater insight into the performance differences observed with various additives and electrode modifications that are aimed at suppressing the rate of shuttling of polysulfide ions and increasing the cycle life of lithium-sulfur cells.

  16. Direct measurement of polysulfide shuttle current: A window into understanding the performance of lithium-sulfur cells

    SciTech Connect (OSTI)

    Moy, Derek [Univ. of Southern California, Los Angeles, CA (United States). Loker Hydrocarbon Research Institute.; Manivannan, A. [National Energy Technology Lab. (NETL), Morgantown, WV (United States); Narayanan, S. R. [Univ. of Southern California, Los Angeles, CA (United States). Loker Hydrocarbon Research Institute.

    2014-11-01

    The shuttling of polysulfide ions between the electrodes in a lithium-sulfur battery is a major technical issue limiting the self-discharge and cycle life of this high-energy rechargeable battery. Although there have been attempts to suppress the shuttling process, there has not been a direct measurement of the rate of shuttling. We report here a simple and direct measurement of the rate of the shuttling (that we term shuttle current), applicable to the study of any type of lithium-sulfur cell. We demonstrate the effectiveness of this measurement technique using cells with and without lithium nitrate (a widely-used shuttle suppressor additive). We present a phenomenological analysis of the shuttling process and simulate the shuttle currents as a function of the state-of-charge of a cell. We also demonstrate how the rate of decay of the shuttle current can be used to predict the capacity fade in a lithium-sulfur cell due to the shuttle process. We expect that this new ability to directly measure shuttle currents will provide greater insight into the performance differences observed with various additives and electrode modifications that are aimed at suppressing the rate of shuttling of polysulfide ions and increasing the cycle life of lithium-sulfur cells.

  17. Direct measurement of polysulfide shuttle current: A window into understanding the performance of lithium-sulfur cells

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Moy, Derek; Manivannan, A.; Narayanan, S. R.

    2014-11-04

    The shuttling of polysulfide ions between the electrodes in a lithium-sulfur battery is a major technical issue limiting the self-discharge and cycle life of this high-energy rechargeable battery. Although there have been attempts to suppress the shuttling process, there has not been a direct measurement of the rate of shuttling. We report here a simple and direct measurement of the rate of the shuttling (that we term “shuttle current”), applicable to the study of any type of lithium-sulfur cell. We demonstrate the effectiveness of this measurement technique using cells with and without lithium nitrate (a widely-used shuttle suppressor additive). Wemore » present a phenomenological analysis of the shuttling process and simulate the shuttle currents as a function of the state-of-charge of a cell. We also demonstrate how the rate of decay of the shuttle current can be used to predict the capacity fade in a lithium-sulfur cell due to the shuttle process. As a result, we expect that this new ability to directly measure shuttle currents will provide greater insight into the performance differences observed with various additives and electrode modifications that are aimed at suppressing the rate of shuttling of polysulfide ions and increasing the cycle life of lithium-sulfur cells.« less

  18. Sulfur@Carbon Cathodes for Lithium Sulfur Batteries > Research...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for Lithium Sulfur Batteries Better Ham & Cheese: Enhanced Anodes and Cathodes for Fuel Cells Epitaxial Single Crystal Nanostructures for Batteries & PVs High Performance ...

  19. Following the Transient Reactions in Lithium-Sulfur Batteries...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Following the Transient Reactions in Lithium-Sulfur Batteries Using an In Situ Nuclear ... cell electrochemical reactions in Li-S batteries using a microbattery design Interphase ...

  20. Vehicle Technologies Office Merit Review 2015: Fundamental Studies of Lithium-Sulfur Cell Chemistry

    Broader source: Energy.gov [DOE]

    Presentation given by Lawrence Berkley National Laboratory at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about...

  1. Vehicle Technologies Office Merit Review 2014: Fundamental Studies of Lithium-Sulfur Cell Chemistry

    Office of Energy Efficiency and Renewable Energy (EERE)

    Presentation given by Lawrence Berkley National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about...

  2. Better Ham & Cheese: Enhanced Anodes and Cathodes for Fuel Cells...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Density-Functional Theory of Electrochemistry Double-band Electrode Channel Flow DEMS Cell Sulfur@Carbon Cathodes for Lithium Sulfur Batteries Better Ham & Cheese: Enhanced...

  3. Graphene-sulfur nanocomposites for rechargeable lithium-sulfur...

    Office of Scientific and Technical Information (OSTI)

    Title: Graphene-sulfur nanocomposites for rechargeable lithium-sulfur battery electrodes Rechargeable lithium-sulfur batteries having a cathode that includes a graphene-sulfur ...

  4. Scientists Probe Lithium-Sulfur Batteries in Real Time - Joint...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    7, 2012, Videos Scientists Probe Lithium-Sulfur Batteries in Real Time Lithium-sulfur batteries are a promising technology that could some day power electric vehicles. Scientists ...

  5. Understanding Lithium-Sulfur Batteries at the Molecular Level...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    June 17, 2015, Accomplishments Understanding Lithium-Sulfur Batteries at the Molecular Level Conceived some 40 years ago, the lithium-sulfur battery can store, in theory, ...

  6. Manipulating the Surface Reactions in Lithium Sulfur Batteries Using Hybrid Anode Structures

    SciTech Connect (OSTI)

    Huang, Cheng; Xiao, Jie; Shao, Yuyan; Zheng, Jianming; Bennett, Wendy D.; Lu, Dongping; Saraf, Laxmikant V.; Engelhard, Mark H.; Ji, Liwen; Zhang, Jiguang; Li, Xiaolin; Graff, Gordon L.; Liu, Jun

    2014-01-09

    Lithium-sulfur (Li-S) batteries have recently attracted extensive attention due to the high theoretical energy density and potential low cost. Even so, significant challenges prevent widespread adoption, including continuous dissolution and consumption of active sulfur during cycling. Here we present a fundamentally new design using electrically connected graphite and lithium metal as a hybrid anode to control undesirable surface reactions on the anode. The lithiated graphite placed in front of the lithium metal functions as an artificial self-regulated solid electrolyte interface (SEI) layer to actively control the electrochemical reaction while minimizing the deleterious side reactions on the surface and bulk lithium metal. Continuous corrosion and contamination of lithium anode by dissolved polysulfides is largely mitigated. Excellent electrochemical performance has been observed. Li-S cell incorporating the hybrid design retain a capacity of more than 800 mAh g-1 for 400 cycles, corresponding to only 11% fade and a Coulombic efficiency above 99%. This simple hybrid concept may also provide new lessons for protecting metal anodes in other energy storage devices.

  7. Development of High Energy Lithium-Sulfur Batteries

    Broader source: Energy.gov (indexed) [DOE]

    High Energy Lithium-Sulfur Batteries Jun Liu and Dongping Lu Pacific Northwest National Laboratory 2016 DOE Vehicle Technologies Program Review June 6-10, 2016 This presentation does not contain any proprietary, confidential, or otherwise restricted information Project ID #ES282 1 1 2 Overview Timeline * Start date: Oct. 2012 * End date: Sept. 2017 * Percent complete: 80% Budget * Total project funding - DOE share 100% * Funding received in FY15: $400k * Funding for FY16: $400k Barriers *

  8. High Energy Lithium-Sulfur Cathodes

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    * Start: August 1, 2013 * End: July 31, 2016 * Percent complete: 60% Barriers of batteries - High cost (A) - Low energy density (C) - Short battery life (E) Targets:...

  9. Controlled Nucleation and Growth Process of Li2S2/Li2S in Lithium-Sulfur Batteries

    SciTech Connect (OSTI)

    Zheng, Jianming; Gu, Meng; Wang, Chong M.; Zuo, Pengjian; Koech, Phillip K.; Zhang, Jiguang; Liu, Jun; Xiao, Jie

    2013-09-20

    Lithium-sulfur battery is a promising next-generation energy storage system because of its potentially three to five times higher energy density than that of traditional lithium ion batteries. However, the dissolution and precipitation of soluble polysulfides during cycling initiate a series of key-chain reactions that significantly shorten battery life. Herein, we demonstrate that through a simple but effective strategy, significantly improved cycling performance is achieved for high sulfur loading electrodes through controlling the nucleation and precipitation of polysulfieds on the electrode surface. More than 400 or 760 stable cycling are successfully displayed in the cells with locked discharge capacity of 625 mAh g-1 or 500 mAh g-1, respectively. The nucleation and growth process of dissolved polysulfides has been electrochemically altered to confine the thickness of discharge products passivated on the cathode surface, increasing the utilization rate of sulfur while avoiding severe morphology changes on the electrode. More importantly, the exposure of new lithium metal surface to the S-containing electrolyte is also greatly reduced through this strategy, largely minimizing the anode corrosion caused by polysulfides. This work interlocks the electrode morphologies and its evolution with electrochemical interference to modulate cell performances by using Li-S system as a platform, providing different but critical directions for this community.

  10. Direct Observation of Sulfur Radicals as Reaction Media in Lithium Sulfur Batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Qiang; Zheng, Jianming; Walter, Eric; Pan, Huilin; Lv, Dongping; Zuo, Pengjian; Chen, Honghao; Deng, Z. D.; Liaw, Bor Y.; Yu, Xiqian; et al

    2015-01-09

    Lithium sulfur (Li-S) battery has been regaining tremendous interest in recent years because of its attractive attributes such as high gravimetric energy, low cost and environmental benignity. However, it is still not conclusively known how polysulfide ring/chain participates in the whole cycling and whether the discharge and charge processes follow the same pathway. Herein, we demonstrate the direct observation of sulfur radicals by using in situ electron paramagnetic resonance (EPR) technique. Based on the concentration changes of sulfur radicals at different potentials and the electrochemical characteristics of the cell, it is revealed that the chemical and electrochemical reactions in Li-Smore » cell are driving each other to proceed through sulfur radicals, leading to two completely different reaction pathways during discharge and charge. The proposed radical mechanism may provide new perspectives to investigate the interactions between sulfur species and the electrolyte, inspiring novel strategies to develop Li-S battery technology.« less

  11. Direct Observation of Sulfur Radicals as Reaction Media in Lithium Sulfur Batteries

    SciTech Connect (OSTI)

    Wang, Qiang; Zheng, Jianming; Walter, Eric; Pan, Huilin; Lv, Dongping; Zuo, Pengjian; Chen, Honghao; Deng, Z. D.; Liaw, Bor Y.; Yu, Xiqian; Yang, Xiao-Qing; Zhang, Ji-Guang; Liu, Jun; Xiao, Jie

    2015-01-09

    Lithium sulfur (Li-S) battery has been regaining tremendous interest in recent years because of its attractive attributes such as high gravimetric energy, low cost and environmental benignity. However, it is still not conclusively known how polysulfide ring/chain participates in the whole cycling and whether the discharge and charge processes follow the same pathway. Herein, we demonstrate the direct observation of sulfur radicals by using in situ electron paramagnetic resonance (EPR) technique. Based on the concentration changes of sulfur radicals at different potentials and the electrochemical characteristics of the cell, it is revealed that the chemical and electrochemical reactions in Li-S cell are driving each other to proceed through sulfur radicals, leading to two completely different reaction pathways during discharge and charge. The proposed radical mechanism may provide new perspectives to investigate the interactions between sulfur species and the electrolyte, inspiring novel strategies to develop Li-S battery technology.

  12. Direct Observation of Sulfur Radicals as Reaction Media in lithium Sulfur Batteries

    SciTech Connect (OSTI)

    Wang, Qiang; Zheng, Jianming; Walter, Eric D.; Pan, Huilin; Lu, Dongping; Zuo, Pengjian; Chen, Honghao; Deng, Zhiqun; Liaw, Bor Yann; Yu, Xiqian; Yang, Xiaoning; Zhang, Jiguang; Liu, Jun; Xiao, Jie

    2014-12-09

    Lithium sulfur (Li-S) battery has been regaining tremendous interest in recent years because of its attractive attributes such as high gravimetric energy, low cost and environmental benignity. However, it is still not conclusively known how polysulfide ring/chain participates in the whole cycling and whether the discharge and charge process follow the same pathway. Herein, we demonstrate the direct observation of sulfur radicals by using in situ electron paramagnetic resonance (EPR) technique. Based on the concentration changes of sulfur radicals at different potentials, it is revealed that the chemical and electrochemical reactions in Li-S cell are driven each other to proceed through sulfur radicals, leading to two completely different reaction pathways during discharge and charge. The proposed radical mechanism may provide new insights to investigate the interactions between sulfur species and the electrolyte, inspiring novel strategies to develop Li-S battery technology.

  13. Fitting the Lithium-Sulfur Battery with a New Membrane - Joint Center for

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Storage Research October 22, 2015, Accomplishments Fitting the Lithium-Sulfur Battery with a New Membrane The lithium-sulfur battery has higher energy storage capacity and lower cost than lithium ion. But there is a serious stumbling block. Polysulfides form in the cathode during battery cycling and pass through the membrane to contaminate the lithium metal anode. This results in a rapid decline in performance. JCESR researchers appear to have found a solution to the problem - the

  14. Formation of Large Polysulfide Complexes during the Lithium-Sulfur Battery Discharge

    SciTech Connect (OSTI)

    Wang, Bin; Alhassan, Saeed M.; Pantelides, Sokrates T

    2014-01-01

    Sulfur cathodes have much larger capacities than transition-metal-oxide cathodes used in commercial lithium-ion batteries but suffer from unsatisfactory capacity retention and long-term cyclability. Capacity degradation originates from soluble lithium polysulfides gradually diffusing into the electrolyte. Understanding of the formation and dynamics of soluble polysulfides during the discharging process at the atomic level remains elusive, which limits further development of lithium-sulfur (Li-S) batteries. Here we report first-principles molecular dynamics simulations and density functional calculations, through which the discharging products of Li-S batteries are studied. We find that, in addition to simple Li2Sn (1 n 8) clusters generated from single cyclooctasulfur (S8) rings, large Li-S clusters form by collectively coupling several different rings to minimize the total energy. At high lithium concentration, a Li-S network forms at the sulfur surfaces. The results can explain the formation of the soluble Li-S complex, such as Li2S8, Li2S6, and Li2S4, and the insoluble Li2S2 and Li2S structures. In addition, we show that the presence of oxygen impurities in graphene, particularly oxygen atoms bonded to vacancies and edges, may stabilize the lithium polysulfides that may otherwise diffuse into the electrolyte.

  15. Development of bulk-type all-solid-state lithium-sulfur battery using LiBH{sub 4} electrolyte

    SciTech Connect (OSTI)

    Unemoto, Atsushi, E-mail: unemoto@imr.tohoku.ac.jp; Ikeshoji, Tamio [WPI-Advanced Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577 (Japan); Yasaku, Syun; Matsuo, Motoaki [Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577 (Japan); Nogami, Genki; Tazawa, Masaru; Taniguchi, Mitsugu [Mitsubishi Gas Chemicals Co., Ltd., 182 Tayuhama Shinwari, Kita-ku, Niigata 950-3112 (Japan); Orimo, Shin-ichi [WPI-Advanced Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577 (Japan); Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577 (Japan)

    2014-08-25

    Stable battery operation of a bulk-type all-solid-state lithium-sulfur battery was demonstrated by using a LiBH{sub 4} electrolyte. The electrochemical activity of insulating elemental sulfur as the positive electrode was enhanced by the mutual dispersion of elemental sulfur and carbon in the composite powders. Subsequently, a tight interface between the sulfur-carbon composite and the LiBH{sub 4} powders was manifested only by cold-pressing owing to the highly deformable nature of the LiBH{sub 4} electrolyte. The high reducing ability of LiBH{sub 4} allows using the use of a Li negative electrode that enhances the energy density. The results demonstrate the interface modification of insulating sulfur and the architecture of an all-solid-state Li-S battery configuration with high energy density.

  16. Vehicle Technologies Office Merit Review 2014: Development of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of High Energy Density Lithium-Sulfur Cells Vehicle Technologies Office Merit Review 2014: Development of High Energy Density Lithium-Sulfur Cells Presentation given by The ...

  17. Method of preparing graphene-sulfur nanocomposites for rechargeable lithium-sulfur battery electrodes

    SciTech Connect (OSTI)

    Liu, Jun; Lemmon, John P; Yang, Zhenguo; Cao, Yuliang; Li, Xiaolin

    2015-04-07

    A method of preparing a graphene-sulfur nanocomposite for a cathode in a rechargeable lithium-sulfur battery comprising thermally expanding graphite oxide to yield graphene layers, mixing the graphene layers with a first solution comprising sulfur and carbon disulfide, evaporating the carbon disulfide to yield a solid nanocomposite, and grinding the solid nanocomposite to yield the graphene-sulfur nanocomposite. Rechargeable-lithium-sulfur batteries having a cathode that includes a graphene-sulfur nanocomposite can exhibit improved characteristics. The graphene-sulfur nanocomposite can be characterized by graphene sheets with particles of sulfur adsorbed to the graphene sheets. The sulfur particles have an average diameter of less than 50 nm.

  18. Graphene-sulfur nanocomposites for rechargeable lithium-sulfur battery electrodes

    DOE Patents [OSTI]

    Liu, Jun; Lemmon, John P; Yang, Zhenguo; Cao, Yuiliang; Li, Xiaolin

    2014-06-17

    Rechargeable lithium-sulfur batteries having a cathode that includes a graphene-sulfur nanocomposite can exhibit improved characteristics. The graphene-sulfur nanocomposite can be characterized by graphene sheets with particles of sulfur adsorbed to the graphene sheets. The sulfur particles have an average diameter less than 50 nm..

  19. Joint Density-Functional Theory of Electrochemistry > Research Highlights >

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research > The Energy Materials Center at Cornell Research Highlights In This Section The Structural Evolution and Diffusion During the Chemical Transformation from Cobalt to Cobalt Phosphide Nanoparticles Joint Density-Functional Theory of Electrochemistry Double-band Electrode Channel Flow DEMS Cell Sulfur@Carbon Cathodes for Lithium Sulfur Batteries Better Ham & Cheese: Enhanced Anodes and Cathodes for Fuel Cells Epitaxial Single Crystal Nanostructures for Batteries & PVs High

  20. Vehicle Technologies Office Merit Review 2016: Development of...

    Energy Savers [EERE]

    Vehicle Technologies Office Merit Review 2016: Fundamental Studies of Lithium-Sulfur Cell Chemistry Development of High Energy Density Lithium-Sulfur Cells Vehicle Technologies ...

  1. Following the Transient Reactions in Lithium-Sulfur Batteries Using an In

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Situ Nuclear Magnetic Resonance (NMR) Technique - Joint Center for Energy Storage Research 18, 2015, Research Highlights Following the Transient Reactions in Lithium-Sulfur Batteries Using an In Situ Nuclear Magnetic Resonance (NMR) Technique (a) NMR spectra as a function of time during charge-discharge. Peaks 1 to 4 reflect change of concentrations of different polysulfide species. Peaks 5 to 6 reflect the formation of microstructures on Li anodes. (b) Formation of a thick SEI layer on Li

  2. Lithium Polysulfidophosphates: A Family of Lithium-Conducting Sulfur-Rich Compounds for Lithium-Sulfur Batteries

    SciTech Connect (OSTI)

    Lin, Zhan; Liu, Zengcai; Fu, Wujun; Dudney, Nancy J; Liang, Chengdu

    2013-01-01

    Given the great potential for improving the energy density of state-of-the-art lithium-ion batteries by a factor of 5, a breakthrough in lithium-sulfur (Li-S) batteries will have a dramatic impact in a broad scope of energy related fields. Conventional Li-S batteries that use liquid electrolytes are intrinsically short-lived with low energy efficiency. The challenges stem from the poor electronic and ionic conductivities of elemental sulfur and its discharge products. We report herein lithium polysulfidophosphates (LPSP), a family of sulfur-rich compounds, as the enabler of long-lasting and energy-efficient Li-S batteries. LPSP have ionic conductivities of 3.0 10-5 S cm-1 at 25 oC, which is 8 orders of magnitude higher than that of Li2S (~10-13 S cm-1). The high Li-ion conductivity of LPSP is the salient characteristic of these compounds that impart the excellent cycling performance to Li-S batteries. In addition, the batteries are configured in an all-solid state that promises the safe cycling of high-energy batteries with metallic lithium anodes.

  3. Anodes for Rechargeable Lithium-Sulfur Batteries - Joint Center for Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Storage Research 0, 2015, Research Highlights Anodes for Rechargeable Lithium-Sulfur Batteries Recent developments on the protection of the Li metal anode in Li-S batteries are reviewed. Scientific Achievement Recent developments on the protection of the Li metal anode in Li-S batteries are reviewed. The degradation mechanism of Li metal anode in Li-S batteries were analyzed and discussed. Various strategies used to minimize the corrosion of the Li anode and to mitigate the effect of the

  4. Double-band Electrode Channel Flow DEMS Cell > Research Highlights >

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research > The Energy Materials Center at Cornell Research Highlights In This Section The Structural Evolution and Diffusion During the Chemical Transformation from Cobalt to Cobalt Phosphide Nanoparticles Joint Density-Functional Theory of Electrochemistry Double-band Electrode Channel Flow DEMS Cell Sulfur@Carbon Cathodes for Lithium Sulfur Batteries Better Ham & Cheese: Enhanced Anodes and Cathodes for Fuel Cells Epitaxial Single Crystal Nanostructures for Batteries & PVs High

  5. Improving Fuel Cell Electrodes Two-Steps at a Time > Research Highlights >

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research > The Energy Materials Center at Cornell Research Highlights In This Section The Structural Evolution and Diffusion During the Chemical Transformation from Cobalt to Cobalt Phosphide Nanoparticles Joint Density-Functional Theory of Electrochemistry Double-band Electrode Channel Flow DEMS Cell Sulfur@Carbon Cathodes for Lithium Sulfur Batteries Better Ham & Cheese: Enhanced Anodes and Cathodes for Fuel Cells Epitaxial Single Crystal Nanostructures for Batteries & PVs High

  6. Polyamidoamine Dendrimer-Based Binders for High-Loading Lithium-Sulfur Battery Cathodes

    SciTech Connect (OSTI)

    Bhattacharya, Priyanka; Nandasiri, Manjula I.; Lv, Dongping; Schwarz, Ashleigh M.; Darsell, Jens T.; Henderson, Wesley A.; Tomalia, Donald A.; Liu, Jun; Zhang, Jiguang; Xiao, Jie

    2016-01-01

    Lithium-sulfur (Li-S) batteries are regarded as one of the most promising candidates for next generation energy storage systems because of their ultra high theoretical specific energy. To realize the practical application of Li-S batteries, however, a high S active material loading is essential (>70 wt% in the carbon-sulfur (C-S) composite cathode and >2 mg cm-2 in the electrode). A critical challenge to achieving this high capacity in practical electrodes is the dissolution of the longer lithium polysulfide reaction intermediates in the electrolyte (resulting in loss of active material from the cathode and contamination of the anode due to the polysulfide shuttle mechanism). The binder material used for the cathode is therefore crucial as this is a key determinant of the bonding interactions between the active material (S) and electronic conducting support (C), as well as the maintenance of intimate contact between the electrode materials and current collector. The battery performance can thus be directly correlated with the choice of binder, but this has received only minimal attention in the relevant Li-S battery published literature. Here, we investigated the application of polyamidoamine (PAMAM) dendrimers as functional binders in Li-S batteries—a class of materials which has been unexplored for electrode design. By using dendrimers, it is demonstrated that high S loadings (>4 mg cm-2) can be easily achieved using "standard" (not specifically tailored) materials and simple processing methods. An exceptional electrochemical cycling performance was obtained (as compared to cathodes with conventional linear polymeric binders such as carboxymethyl cellulose (CMC) and styrene-butadiene rubber (SBR)) with >100 cycles and 85-98% capacity retention, thus demonstrating the significant utility of this new binder architecture which exhibits critical physicochemical properties and flexible nanoscale design parameters (CNDP's).

  7. Vehicle Technologies Office Merit Review 2014: Development of High Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Density Lithium-Sulfur Cells | Department of Energy of High Energy Density Lithium-Sulfur Cells Vehicle Technologies Office Merit Review 2014: Development of High Energy Density Lithium-Sulfur Cells Presentation given by The Pennsylvania State University at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about development of high energy density lithium-sulfur cells. es125_wang_2014_p.pdf (2.05 MB) More Documents &

  8. Graphene-wrapped sulfur/metal organic framework-derived microporous carbon composite for lithium sulfur batteries

    SciTech Connect (OSTI)

    Chen, Renjie E-mail: chenrj@bit.edu.cn; Zhao, Teng; Tian, Tian; Fairen-Jimenez, David; Cao, Shuai; Coxon, Paul R.; Xi, Kai E-mail: chenrj@bit.edu.cn; Vasant Kumar, R.; Cheetham, Anthony K.

    2014-12-01

    A three-dimensional hierarchical sandwich-type graphene sheet-sulfur/carbon (GS-S/C{sub ZIF8-D}) composite for use in a cathode for a lithium sulfur (Li-S) battery has been prepared by an ultrasonic method. The microporous carbon host was prepared by a one-step pyrolysis of Zeolitic Imidazolate Framework-8 (ZIF-8), a typical zinc-containing metal organic framework (MOF), which offers a tunable porous structure into which electro-active sulfur can be diffused. The thin graphene sheet, wrapped around the sulfur/zeolitic imidazolate framework-8 derived carbon (S/C{sub ZIF8-D}) composite, has excellent electrical conductivity and mechanical flexibility, thus facilitating rapid electron transport and accommodating the changes in volume of the sulfur electrode. Compared with the S/C{sub ZIF8-D} sample, Li-S batteries with the GS-S/C{sub ZIF8-D} composite cathode showed enhanced capacity, improved electrochemical stability, and relatively high columbic efficiency by taking advantage of the synergistic effects of the microporous carbon from ZIF-8 and a highly interconnected graphene network. Our results demonstrate that a porous MOF-derived scaffold with a wrapped graphene conductive network structure is a potentially efficient design for a battery electrode that can meet the challenge arising from low conductivity and volume change.

  9. Carbon/Sulfur Nanocomposites and Additives for High-Energy Lithium Sulfur Batteries

    Broader source: Energy.gov [DOE]

    2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation

  10. Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries

    Broader source: Energy.gov [DOE]

    2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  11. Carbon/Sulfur Nanocomposites and Additives for High-Energy Lithium Sulfur Batteries

    Broader source: Energy.gov [DOE]

    2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  12. Vehicle Technologies Office Merit Review 2015: High Energy Lithium-Sulfur Cathodes

    Office of Energy Efficiency and Renewable Energy (EERE)

    Presentation given by Stanford University at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about high energy lithium...

  13. Vehicle Technologies Office Merit Review 2016: Statically and Dynamically Stable Lithium-Sulfur Batteries

    Office of Energy Efficiency and Renewable Energy (EERE)

    Presentation given by University of Texas at Austin  at the 2016 DOE Vehicle Technologies Office and Hydrogen and Fuel Cells Program Annual Merit Review and Peer Evaluation Meeting about Batteries

  14. Ionic Liquid-Enhanced Solid State Electrolyte Interface (SEI) for Lithium Sulfur Batteries

    SciTech Connect (OSTI)

    Zheng, Jianming; Gu, Meng; Chen, Honghao; Meduri, Praveen; Engelhard, Mark H.; Zhang, Jiguang; Liu, Jun; Xiao, Jie

    2013-05-16

    Li-S battery is a complicated system with many challenges existing before its final market penetration. While most of the reported work for Li-S batteries is focused on the cathode design, we demonstrate in this work that the anode consumption accelerated by corrosive polysulfide solution also critically determines the Li-S cell performance. To validate this hypothesis, ionic liquid (IL) N-methyl-N-butylpyrrolidinium bis(trifluoromethylsulfonyl)imide (Py14TFSI) has been employed to modify the properties of SEI layer formed on Li metal surface in Li-S batteries. It is found that the IL-enhanced passivation film on the lithium anode surface exhibits much different morphology and chemical compositions, effectively protecting lithium metal from continuous attack by soluble polysulfides. Therefore, both cell impedance and the irreversible consumption of polysulfides on lithium metal are reduced. As a result, the Coulombic efficiency and the cycling stability of Li-S batteries have been greatly improved. After 120 cycles, Li-S battery cycled in the electrolyte containing IL demonstrates a high capacity retention of 94.3% at 0.1 C rate. These results unveil another important failure mechanism for Li-S batteries and shin the light on the new approaches to improve Li-S battery performances.

  15. Manufacturing of Protected Lithium Electrodes for Advanced Lithium-Air, Lithium-Water & Lithium-Sulfur Batteries

    SciTech Connect (OSTI)

    Visco, Steven J

    2015-11-30

    The global demand for rechargeable batteries is large and growing rapidly. Assuming the adoption of electric vehicles continues to increase, the need for smaller, lighter, and less expensive batteries will become even more pressing. In this vein, PolyPlus Battery Company has developed ultra-light high performance batteries based on its proprietary protected lithium electrode (PLE) technology. The Company’s Lithium-Air and Lithium-Seawater batteries have already demonstrated world record performance (verified by third party testing), and we are developing advanced lithium-sulfur batteries which have the potential deliver high performance at low cost. In this program PolyPlus Battery Company teamed with Corning Incorporated to transition the PLE technology from bench top fabrication using manual tooling to a pre- commercial semi-automated pilot line. At the inception of this program PolyPlus worked with a Tier 1 battery manufacturing engineering firm to design and build the first-of-its-kind pilot line for PLE production. The pilot line was shipped and installed in Berkeley, California several months after the start of the program. PolyPlus spent the next two years working with and optimizing the pilot line and now produces all of its PLEs on this line. The optimization process successfully increased the yield, throughput, and quality of PLEs produced on the pilot line. The Corning team focused on fabrication and scale-up of the ceramic membranes that are key to the PLE technology. PolyPlus next demonstrated that it could take Corning membranes through the pilot line process to produce state-of-the-art protected lithium electrodes. In the latter part of the program the Corning team developed alternative membranes targeted for the large rechargeable battery market. PolyPlus is now in discussions with several potential customers for its advanced PLE-enabled batteries, and is building relationships and infrastructure for the transition into manufacturing. It is likely

  16. High energy density thermal cell

    SciTech Connect (OSTI)

    Fletcher, A.N.

    1980-04-29

    A thermal battery is described that uses a calcium anode and a catholyte consisting of a mixture of lithium, potassium, nitrate and chloride ions. The device is operable over a temperature range of about 150 to 600/sup 0/C and produces a long lasting, high energy density output.

  17. Identification of cell density signal molecule

    DOE Patents [OSTI]

    Schwarz, Richard I.

    1998-01-01

    Disclosed herein is a novel proteinaceous cell density signal molecule (CDS) between 25 and 35 kD, which is secreted by fibroblastic primary avian tendon cells in culture, and causes the cells to self-regulate their proliferation and the expression of differentiated function. It effects an increase of procollagen production in avian tendon cell cultures of ten fold while proliferation rates are decreased. CDS, and the antibodies which recognize them, are important for the development of diagnostics and treatments for injuries and diseases involving connective tissues, particularly tendon. Also disclosed are methods of production and use.

  18. Identification of cell density signal molecule

    DOE Patents [OSTI]

    Schwarz, R.I.

    1998-04-21

    Disclosed herein is a novel proteinaceous cell density signal molecule (CDS) between 25 and 35 kD, which is secreted by fibroblastic primary avian tendon cells in culture, and causes the cells to self-regulate their proliferation and the expression of differentiated function. It effects an increase of procollagen production in avian tendon cell cultures of ten fold while proliferation rates are decreased. CDS, and the antibodies which recognize them, are important for the development of diagnostics and treatments for injuries and diseases involving connective tissues, particularly tendon. Also disclosed are methods of production and use. 2 figs.

  19. High power density solid oxide fuel cells

    DOE Patents [OSTI]

    Pham, Ai Quoc; Glass, Robert S.

    2004-10-12

    A method for producing ultra-high power density solid oxide fuel cells (SOFCs). The method involves the formation of a multilayer structure cells wherein a buffer layer of doped-ceria is deposited intermediate a zirconia electrolyte and a cobalt iron based electrode using a colloidal spray deposition (CSD) technique. For example, a cobalt iron based cathode composed of (La,Sr)(Co,Fe)O (LSCF) may be deposited on a zirconia electrolyte via a buffer layer of doped-ceria deposited by the CSD technique. The thus formed SOFC have a power density of 1400 mW/cm.sup.2 at 600.degree. C. and 900 mW/cm.sup.2 at 700.degree. C. which constitutes a 2-3 times increased in power density over conventionally produced SOFCs.

  20. Vehicle Technologies Office Merit Review 2016: New Lamination and Doping Concepts for Enhanced Lithium-Sulfur Battery Performance

    Broader source: Energy.gov [DOE]

    Presentation given by University of Pittsburgh at the 2016 DOE Vehicle Technologies Office and Hydrogen and Fuel Cells Program Annual Merit Review and Peer Evaluation Meeting about Batteries

  1. Vehicle Technologies Office Merit Review 2016: Design of Sulfur Cathodes for High Energy Lithium-Sulfur Batteries

    Broader source: Energy.gov [DOE]

    Presentation given by Stanford University at the 2016 DOE Vehicle Technologies Office and Hydrogen and Fuel Cells Program Annual Merit Review and Peer Evaluation Meeting about Batteries

  2. Quantitative Chromatographic Determination of Dissolved Elemental Sulfur in the Non-aqueous Electrolyte for Lithium-Sulfur Batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zheng, Dong; Yang, Xiao-Qing; Zhang, Xuran; Li, Chao; McKinnon, Meaghan E.; Sadok, Rachel G.; Qu, Deyu; Yu, Xiqian; Lee, Hung-Sui; Qu, Deyang

    2014-12-02

    A fast and reliable analytical method is reported for the quantitative determination of dissolved elemental sulfur in non-aqueous electrolytes for Li-S batteries. By using high performance liquid chromatography with a UV detector, the solubility of S in 12 different pure solvents and in 22 different electrolytes was determined. It was found that the solubility of elemental sulfur is dependent on the Lewis basicity, the polarity of solvents and the salt concentration in the electrolytes. In addition, the S content in the electrolyte recovered from a discharged Li-S battery was successfully determined by the proposed HPLC/UV method. Thus, the feasibility ofmore » the method to the online analysis for a Li-S battery is demonstrated. Interestingly, the S was found super-saturated in the electrolyte recovered from a discharged Li-S cell.« less

  3. Quantitative Chromatographic Determination of Dissolved Elemental Sulfur in the Non-aqueous Electrolyte for Lithium-Sulfur Batteries

    SciTech Connect (OSTI)

    Zheng, Dong; Yang, Xiao-Qing; Zhang, Xuran; Li, Chao; McKinnon, Meaghan E.; Sadok, Rachel G.; Qu, Deyu; Yu, Xiqian; Lee, Hung-Sui; Qu, Deyang

    2014-12-02

    A fast and reliable analytical method is reported for the quantitative determination of dissolved elemental sulfur in non-aqueous electrolytes for Li-S batteries. By using high performance liquid chromatography with a UV detector, the solubility of S in 12 different pure solvents and in 22 different electrolytes was determined. It was found that the solubility of elemental sulfur is dependent on the Lewis basicity, the polarity of solvents and the salt concentration in the electrolytes. In addition, the S content in the electrolyte recovered from a discharged Li-S battery was successfully determined by the proposed HPLC/UV method. Thus, the feasibility of the method to the online analysis for a Li-S battery is demonstrated. Interestingly, the S was found super-saturated in the electrolyte recovered from a discharged Li-S cell.

  4. Vehicle Technologies Office Merit Review 2014: Fundamental Studies...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fundamental Studies of Lithium-Sulfur Cell Chemistry Vehicle Technologies Office Merit Review 2014: Fundamental Studies of Lithium-Sulfur Cell Chemistry Presentation given by...

  5. High power density fuel cell stack development for automotive applications

    SciTech Connect (OSTI)

    Pow, R.; Reindl, M.; Tilmetz, W.

    1996-12-31

    This paper describes the joint development by Daimler-Benz and Ballard Power Systems of a high power-density fuel cell stack and its demonstration in a 6-passenger Minivan.

  6. Composition for detection of cell density signal molecule

    DOE Patents [OSTI]

    Schwarz, Richard I.

    2001-01-01

    Disclosed herein is a novel proteinaceous cell density signal molecule (CDS), which is secreted by fibroblastic cells in culture, preferably tendon cells, and which provides a means by which the cells self-regulate their proliferation and the expression of differentiated function. CDS, and the antibodies which recognize them, are important for the development of diagnostics and treatments for injuries and diseases involving connective tissues, particularly tendon. Also disclosed are methods of production and use.

  7. Vehicle Technologies Office Merit Review 2015: Fundamental Studies...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Office Merit Review 2014: Fundamental Studies of Lithium-Sulfur Cell Chemistry Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries Vehicle Technologies...

  8. Defect density and dielectric constant in perovskite solar cells

    SciTech Connect (OSTI)

    Samiee, Mehran; Konduri, Siva; Abbas, Hisham A.; Joshi, Pranav; Zhang, Liang; Dalal, Vikram; Ganapathy, Balaji; Kottokkaran, Ranjith; Noack, Max; Kitahara, Andrew

    2014-10-13

    We report on measurement of dielectric constant, mid-gap defect density, Urbach energy of tail states in CH{sub 3}NH{sub 3}PbI{sub x}Cl{sub 1?x} perovskite solar cells. Midgap defect densities were estimated by measuring capacitance vs. frequency at different temperatures and show two peaks, one at 0.66?eV below the conduction band and one at 0.24?eV below the conduction band. The attempt to escape frequency is in the range of 2??10{sup 11}/s. Quantum efficiency data indicate a bandgap of 1.58?eV. Urbach energies of valence and conduction band are estimated to be ?16 and ?18?meV. Measurement of saturation capacitance indicates that the relative dielectric constant is ?18.

  9. Fluid flow plate for decreased density of fuel cell assembly

    SciTech Connect (OSTI)

    Vitale, N.G.

    1999-11-09

    A fluid flow plate includes first and second outward faces. Each of the outward faces has a flow channel thereon for carrying respective fluid. At least one of the fluids serves as reactant fluid for a fuel cell of a fuel cell assembly. One or more pockets are formed between the first and second outward faces for decreasing density of the fluid flow plate. A given flow channel can include one or more end sections and an intermediate section. An interposed member can be positioned between the outward faces at an interface between an intermediate section, of one of the outward faces, and an end section, of that outward face. The interposed member can serve to isolate the reactant fluid from the opposing outward face. The intermediate section(s) of flow channel(s) on an outward face are preferably formed as a folded expanse.

  10. Fluid flow plate for decreased density of fuel cell assembly

    DOE Patents [OSTI]

    Vitale, Nicholas G.

    1999-01-01

    A fluid flow plate includes first and second outward faces. Each of the outward faces has a flow channel thereon for carrying respective fluid. At least one of the fluids serves as reactant fluid for a fuel cell of a fuel cell assembly. One or more pockets are formed between the first and second outward faces for decreasing density of the fluid flow plate. A given flow channel can include one or more end sections and an intermediate section. An interposed member can be positioned between the outward faces at an interface between an intermediate section, of one of the outward faces, and an end section, of that outward face. The interposed member can serve to isolate the reactant fluid from the opposing outward face. The intermediate section(s) of flow channel(s) on an outward face are preferably formed as a folded expanse.

  11. Probing topological relations between high-density and low-density regions of 2MASS with hexagon cells

    SciTech Connect (OSTI)

    Wu, Yongfeng; Xiao, Weike

    2014-02-01

    We introduced a new two-dimensional (2D) hexagon technique for probing the topological structure of the universe in which we mapped regions of the sky with high and low galaxy densities onto a 2D lattice of hexagonal unit cells. We defined filled cells as corresponding to high-density regions and empty cells as corresponding to low-density regions. The numbers of filled cells and empty cells were kept the same by controlling the size of the cells. By analyzing the six sides of each hexagon, we could obtain and compare the statistical topological properties of high-density and low-density regions of the universe in order to have a better understanding of the evolution of the universe. We applied this hexagonal method to Two Micron All Sky Survey data and discovered significant topological differences between the high-density and low-density regions. Both regions had significant (>5?) topological shifts from both the binomial distribution and the random distribution.

  12. Anodes for Rechargeable Lithium-Sulfur Batteries

    SciTech Connect (OSTI)

    Cao, Ruiguo; Xu, Wu; Lu, Dongping; Xiao, Jie; Zhang, Jiguang

    2015-04-10

    In this work, we will review the recent developments on the protection of Li metal anode in Li-S batteries. Various strategies used to minimize the corrosion of Li anode and reducing its impedance increase will be analyzed. Other potential anodes used in sulfur based rechargeable batteries will also be discussed.

  13. Estimation of current density distribution of PAFC by analysis of cell exhaust gas

    SciTech Connect (OSTI)

    Kato, S.; Seya, A.; Asano, A.

    1996-12-31

    To estimate distributions of Current densities, voltages, gas concentrations, etc., in phosphoric acid fuel cell (PAFC) stacks, is very important for getting fuel cells with higher quality. In this work, we leave developed a numerical simulation tool to map out the distribution in a PAFC stack. And especially to Study Current density distribution in the reaction area of the cell, we analyzed gas composition in several positions inside a gas outlet manifold of the PAFC stack. Comparing these measured data with calculated data, the current density distribution in a cell plane calculated by the simulation, was certified.

  14. High power density fuel cell comprising an array of microchannels

    DOE Patents [OSTI]

    Morse, Jeffrey D.; Upadhye, Ravindra S.; Spadaccini, Christopher M.; Park, Hyung Gyu

    2013-10-15

    A fuel cell according to one embodiment includes a porous electrolyte support structure defining an array of microchannels, the microchannels including fuel and oxidant microchannels; fuel electrodes formed along some of the microchannels; and oxidant electrodes formed along other of the microchannels. A method of making a fuel cell according to one embodiment includes forming an array of walls defining microchannels therebetween using at least one of molding, stamping, extrusion, injection and electrodeposition; processing the walls to make the walls porous, thereby creating a porous electrolyte support structure; forming anode electrodes along some of the microchannels; and forming cathode electrodes along other of the microchannels. Additional embodiments are also disclosed.

  15. High power density fuel cell comprising an array of microchannels

    DOE Patents [OSTI]

    Sopchak, David A; Morse, Jeffrey D; Upadhye, Ravindra S; Kotovsky, Jack; Graff, Robert T

    2014-05-06

    A phosphoric acid fuel cell according to one embodiment includes an array of microchannels defined by a porous electrolyte support structure extending between bottom and upper support layers, the microchannels including fuel and oxidant microchannels; fuel electrodes formed along some of the microchannels; and air electrodes formed along other of the microchannels. A method of making a phosphoric acid fuel cell according to one embodiment includes etching an array of microchannels in a substrate, thereby forming walls between the microchannels; processing the walls to make the walls porous, thereby forming a porous electrolyte support structure; forming anode electrodes along some of the walls; forming cathode electrodes along other of the walls; and filling the porous electrolyte support structure with a phosphoric acid electrolyte. Additional embodiments are also disclosed.

  16. Cell density signal protein suitable for treatment of connective tissue injuries and defects

    DOE Patents [OSTI]

    Schwarz, Richard I.

    2002-08-13

    Identification, isolation and partial sequencing of a cell density protein produced by fibroblastic cells. The cell density signal protein comprising a 14 amino acid peptide or a fragment, variant, mutant or analog thereof, the deduced cDNA sequence from the 14 amino acid peptide, a recombinant protein, protein and peptide-specific antibodies, and the use of the peptide and peptide-specific antibodies as therapeutic agents for regulation of cell differentiation and proliferation. A method for treatment and repair of connective tissue and tendon injuries, collagen deficiency, and connective tissue defects.

  17. Measuring the mass, density, and size of particles and cells using a suspended microchannel resonator

    SciTech Connect (OSTI)

    Godin, Michel; Bryan, Andrea K.; Burg, Thomas P.; Babcock, Ken; Manalis, Scott R.

    2007-09-17

    We demonstrate the measurement of mass, density, and size of cells and nanoparticles using suspended microchannel resonators. The masses of individual particles are quantified as transient frequency shifts, while the particles transit a microfluidic channel embedded in the resonating cantilever. Mass histograms resulting from these data reveal the distribution of a population of heterogeneously sized particles. Particle density is inferred from measurements made in different carrier fluids since the frequency shift for a particle is proportional to the mass difference relative to the displaced solution. We have characterized the density of polystyrene particles, Escherichia coli, and human red blood cells with a resolution down to 10{sup -4} g/cm{sup 3}.

  18. MEMS Fuel Cells--Low Temp--High Power Density - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Storage Energy Storage Find More Like This Return to Search MEMS Fuel Cells--Low Temp--High Power Density Lawrence Livermore National Laboratory Contact LLNL About This Technology Technology Marketing Summary Rechargeable batteries presently provide limited energy density and cyclical lifetime for portable power applications, with only incremental improvements forecasted in the foreseeable future. Furthermore, recharging requires access to electrical outlets via a tethered charger. The

  19. Density of states measurements in a p-i-n solar cell

    SciTech Connect (OSTI)

    Crandall, R.S.; Wang, Q.

    1996-09-01

    The authors describe results of density of states (DOS) profiling in p-i-n solar-cell devices using drive-level capacitance (DLC) techniques. Near the p-i interface the defect density is high, decreasing rapidly into the interior, reaching low values in the central region of the cell, and rising rapidly again at the n-i interface. They show that the states in the central region are neutral dangling-bond defects, whereas those near the interfaces with the doped layers are charged dangling bonds.

  20. Density of states measurements in a p-i-n solar cell

    SciTech Connect (OSTI)

    Crandall, R.S.; Wang, Q.

    1996-05-01

    The authors describe results of density of states (DOS) profiling in p-i-n solar-cell devices using drive-level capacitance (DLC) techniques. Near the p-i interface the defect density is high, decreasing rapidly into the interior, reaching low values in the central region of the cell, and rising rapidly again at the n-i interface. They show that the states in the central region are neutral dangling-bond defects, whereas those near the interfaces with the doped layers are charged dangling bonds.

  1. Method of Fabrication of High Power Density Solid Oxide Fuel Cells

    DOE Patents [OSTI]

    Pham, Ai Quoc; Glass, Robert S.

    2008-09-09

    A method for producing ultra-high power density solid oxide fuel cells (SOFCs). The method involves the formation of a multilayer structure cells wherein a buffer layer of doped-ceria is deposited intermediate a zirconia electrolyte and a cobalt iron based electrode using a colloidal spray deposition (CSD) technique. For example, a cobalt iron based cathode composed of (La,Sr)(Co,Fe)O(LSCF) may be deposited on a zirconia electrolyte via a buffer layer of doped-ceria deposited by the CSD technique. The thus formed SOFC have a power density of 1400 mW/cm.sup.2 at 600.degree. C. and 900 mW/cm.sup.2 at 700.degree. C. which constitutes a 2-3 times increased in power density over conventionally produced SOFCs.

  2. Durability of Low Platinum Fuel Cells Operating at High Power Density

    SciTech Connect (OSTI)

    Polevaya, Olga; Blanchet, Scott; Ahluwalia, Rajesh; Borup, Rod; Mukundan, Rangachary

    2014-03-19

    Understanding and improving the durability of cost-competitive fuel cell stacks is imperative to successful deployment of the technology. Stacks will need to operate well beyond today’s state-of-the-art rated power density with very low platinum loading in order to achieve the cost targets set forth by DOE ($15/kW) and ultimately be competitive with incumbent technologies. An accelerated cost-reduction path presented by Nuvera focused on substantially increasing power density to address non-PGM material costs as well as platinum. The study developed a practical understanding of the degradation mechanisms impacting durability of fuel cells with low platinum loading (≤0.2mg/cm2) operating at high power density (≥1.0W/cm2) and worked out approaches for improving the durability of low-loaded, high-power stack designs. Of specific interest is the impact of combining low platinum loading with high power density operation, as this offers the best chance of achieving long-term cost targets. A design-of-experiments approach was utilized to reveal and quantify the sensitivity of durability-critical material properties to high current density at two levels of platinum loading (the more conventional 0.45 mgPt.cm–1 and the much lower 0.2 mgPt.cm–2) across several cell architectures. We studied the relevance of selected component accelerated stress tests (AST) to fuel cell operation in power producing mode. New stress tests (NST) were designed to investigate the sensitivity to the addition of electrical current on the ASTs, along with combined humidity and load cycles and, eventually, relate to the combined city/highway drive cycle. Changes in the cathode electrochemical surface area (ECSA) and average oxygen partial pressure on the catalyst layer with aging under AST and NST protocols were compared based on the number of completed cycles. Studies showed elevated sensitivity of Pt growth to the potential limits and the initial particle size distribution. The ECSA loss

  3. Enhanced photocurrent density in graphene/Si based solar cell (GSSC) by optimizing active layer thickness

    SciTech Connect (OSTI)

    Rosikhin, Ahmad Hidayat, Aulia Fikri; Syuhada, Ibnu; Winata, Toto

    2015-12-29

    Thickness dependent photocurrent density in active layer of graphene/Si based solar cell has been investigated via analytical – simulation study. This report is a preliminary comparison of experimental and analytical investigation of graphene/Si based solar cell. Graphene sheet was interfaced with Si thin film forming heterojunction solar cell that was treated as a device model for photocurrent generator. Such current can be enhanced by optimizing active layer thickness and involving metal oxide as supporting layer to shift photons absorption. In this case there are two type of devices model with and without TiO{sub 2} in which the silicon thickness varied at 20 – 100 nm. All of them have examined and also compared with each other to obtain an optimum value. From this calculation it found that generated currents almost linear with thickness but there are saturated conditions that no more enhancements will be achieved. Furthermore TiO{sub 2} layer is effectively increases photon absorption but reducing device stability, maximum current is fluctuates enough. This may caused by the disturbance of excitons diffusion and resistivity inside each layer. Finally by controlling active layer thickness, it is quite useful to estimate optimization in order to develop the next solar cell devices.

  4. Sulfur-Graphene Oxide Nanocomposite Cathodes for Lithium/Sulfur...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    They are produced using simple chemical deposition techniques and a relatively low-temperature (155 C) thermal treatment process. Graphene oxide transforms insulating graphene ...

  5. Lithium/Sulfur Batteries Based on Doped Mesoporous Carbon - Energy...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of doped mesoporous carbon and elemental sulfur at a temperature inside a stainless steel vessel, which was used in lithiumsulfur batteries that were tested in ...

  6. High-Density and Very-Low-Density Lipoprotein Have Opposing Roles in Regulating Tumor-Initiating Cells and Sensitivity to Radiation in Inflammatory Breast Cancer

    SciTech Connect (OSTI)

    Wolfe, Adam R.; Atkinson, Rachel L.; Reddy, Jay P.; Debeb, Bisrat G.; Larson, Richard; Li, Li; Masuda, Hiroko; Brewer, Takae; Atkinson, Bradley J.; Brewster, Abeena; Ueno, Naoto T.; Woodward, Wendy A.

    2015-04-01

    Purpose: We previously demonstrated that cholesterol-lowering agents regulate radiation sensitivity of inflammatory breast cancer (IBC) cell lines in vitro and are associated with less radiation resistance among IBC patients who undergo postmastectomy radiation. We hypothesized that decreasing IBC cellular cholesterol induced by treatment with lipoproteins would increase radiation sensitivity. Here, we examined the impact of specific transporters of cholesterol (ie lipoproteins) on the responses of IBC cells to self-renewal and to radiation in vitro and on clinical outcomes in IBC patients. Methods and Materials: Two patient-derived IBC cell lines, SUM 149 and KPL4, were incubated with low-density lipoproteins (LDL), very-low-density lipoproteins (VLDL), or high-density lipoproteins (HDL) for 24 hours prior to irradiation (0-6 Gy) and mammosphere formation assay. Cholesterol panels were examined in a cohort of patients with primary IBC diagnosed between 1995 and 2011 at MD Anderson Cancer Center. Lipoprotein levels were then correlated to patient outcome, using the log rank statistical model, and examined in multivariate analysis using Cox regression. Results: VLDL increased and HDL decreased mammosphere formation compared to untreated SUM 149 and KPL4 cells. Survival curves showed enhancement of survival in both of the IBC cell lines when pretreated with VLDL and, conversely, radiation sensitization in all cell lines when pretreated with HDL. In IBC patients, higher VLDL values (>30 mg/dL) predicted a lower 5-year overall survival rate than normal values (hazard ratio [HR] = 1.9 [95% confidence interval [CI]: 1.05-3.45], P=.035). Lower-than-normal patient HDL values (<60 mg/dL) predicted a lower 5-year overall survival rate than values higher than 60 mg/dL (HR = 3.21 [95% CI: 1.25-8.27], P=.015). Conclusions: This study discovered a relationship among the plasma levels of lipoproteins, overall patient response, and radiation resistance in IBC patients

  7. Sion Power Corp formerly Moltech Corp | Open Energy Information

    Open Energy Info (EERE)

    Sector: Vehicles Product: Tucson, Arizona-based privately held developer of thin-film lithium-sulfur rechargeable batteries for propelling vehicles and other high energy-density...

  8. Spatially resolved determination of the short-circuit current density of silicon solar cells via lock-in thermography

    SciTech Connect (OSTI)

    Fertig, Fabian Greulich, Johannes; Rein, Stefan

    2014-05-19

    We present a spatially resolved method to determine the short-circuit current density of crystalline silicon solar cells by means of lock-in thermography. The method utilizes the property of crystalline silicon solar cells that the short-circuit current does not differ significantly from the illuminated current under moderate reverse bias. Since lock-in thermography images locally dissipated power density, this information is exploited to extract values of spatially resolved current density under short-circuit conditions. In order to obtain an accurate result, one or two illuminated lock-in thermography images and one dark lock-in thermography image need to be recorded. The method can be simplified in a way that only one image is required to generate a meaningful short-circuit current density map. The proposed method is theoretically motivated, and experimentally validated for monochromatic illumination in comparison to the reference method of light-beam induced current.

  9. Videos - Joint Center for Energy Storage Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Videos August 24, 2016, Videos Sparingly Solvating Electrolytes for High Energy Density Lithium-Sulfur Batteries As JCESR scientists work to develop lighter and less expensive chemistries than those used in current lithium-ion batteries, lithium-sulfur shows tremendous promise. This perspective presents an alternate approach that could move us closer to long-lived, high energy density lithium-sulfur batteries. Read More Chemical Transformation August 1, 2016, Videos Inside Tesla's Deal to Buy

  10. PORTSMOUTH ON-SITE DISPOSAL CELL HIGH DENSITY POLYETHYLENE GEOMEMBRANE LONGEVITY

    SciTech Connect (OSTI)

    Phifer, M.

    2012-01-31

    It is anticipated that high density polyethylene (HDPE) geomembranes will be utilized within the liner and closure cap of the proposed On-Site Disposal Cell (OSDC) at the Portsmouth Gaseous Diffusion Plant. The likely longevity (i.e. service life) of HDPE geomembranes in OSDC service is evaluated within the following sections of this report: (1) Section 2.0 provides an overview of HDPE geomembranes, (2) Section 3.0 outlines potential HDPE geomembranes degradation mechanisms, (3) Section 4.0 evaluates the applicability of HDPE geomembrane degradation mechanisms to the Portsmouth OSDC, (4) Section 5.0 provides a discussion of the current state of knowledge relative to the longevity (service life) of HDPE geomembranes, including the relation of this knowledge to the Portsmouth OSDC, and (5) Section 6.0 provides summary and conclusions relative to the anticipated service life of HDPE geomembranes in OSDC service. Based upon this evaluation it is anticipated that the service life of HDPE geomembranes in OSDC service would be significantly greater than the 200 year service life assumed for the OSDC closure cap and liner HDPE geomembranes. That is, a 200 year OSDC HDPE geomembrane service life is considered a conservative assumption.

  11. Variation of carrier concentration and interface trap density in 8MeV electron irradiated c-Si solar cells

    SciTech Connect (OSTI)

    Bhat, Sathyanarayana Rao, Asha; Krishnan, Sheeja; Sanjeev, Ganesh; Suresh, E. P.

    2014-04-24

    The capacitance and conductance measurements were carried out for c-Si solar cells, irradiated with 8 MeV electrons with doses ranging from 5kGy 100kGy in order to investigate the anomalous degradation of the cells in the radiation harsh environments. Capacitance Voltage measurements indicate that there is a slight reduction in the carrier concentration upon electron irradiation due to the creation of radiation induced defects. The conductance measurement results reveal that the interface state densities and the trap time constant increases with electron dose due to displacement damages in c-Si solar cells.

  12. News Item

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    PIMs May Be the Cup of Choice for Lithium-Sulfur Batteries Lithium-sulfur batteries, which store electrical energy by transferring electrons to or from a sulfur electrodeare well poised to provide high-density, long-term and low-cost electrochemical energy storage. The potential of lithium-sulfur batteries, has yet to be fully realized, however, due to the uncontrolled migration of soluble sulfur species through the membrane that separates the electrodes. This crossover of polysulfides reduces

  13. Available Technologies - Joint Center for Energy Storage Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Technology Grafting Ionic Moiety to Sulfur for Lithium-Sulfur Battery Massachusetts Institute of Technology MIT Case No. 17699 Gravity Induced Flow Cell Using ...

  14. Epitaxial Single Crystal Nanostructures for Batteries & PVs ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for Lithium Sulfur Batteries Better Ham & Cheese: Enhanced Anodes and Cathodes for Fuel Cells Epitaxial Single Crystal Nanostructures for Batteries & PVs High Performance ...

  15. Research Highlights > Research > The Energy Materials Center at Cornell

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Highlights In This Section The Structural Evolution and Diffusion During the Chemical Transformation from Cobalt to Cobalt Phosphide Nanoparticles Joint Density-Functional Theory of Electrochemistry Double-band Electrode Channel Flow DEMS Cell Sulfur@Carbon Cathodes for Lithium Sulfur Batteries Better Ham & Cheese: Enhanced Anodes and Cathodes for Fuel Cells Epitaxial Single Crystal Nanostructures for Batteries & PVs High Performance Alkaline Fuel Cell Membranes Improving Fuel

  16. Durability of Low Pt Fuel Cells Operating at High Power Density...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Transport Studies Enabling Efficiency Optimization of Cost-Competitive Fuel Cell Stacks Advanced Cathode Catalysts and Supports for PEM Fuel Cells ...

  17. Short-circuit current density imaging of crystalline silicon solar cells via lock-in thermography: Robustness and simplifications

    SciTech Connect (OSTI)

    Fertig, Fabian Greulich, Johannes; Rein, Stefan

    2014-11-14

    Spatially resolved determination of solar cell parameters is beneficial for loss analysis and optimization of conversion efficiency. One key parameter that has been challenging to access by an imaging technique on solar cell level is short-circuit current density. This work discusses the robustness of a recently suggested approach to determine short-circuit current density spatially resolved based on a series of lock-in thermography images and options for a simplified image acquisition procedure. For an accurate result, one or two emissivity-corrected illuminated lock-in thermography images and one dark lock-in thermography image have to be recorded. The dark lock-in thermography image can be omitted if local shunts are negligible. Furthermore, it is shown that omitting the correction of lock-in thermography images for local emissivity variations only leads to minor distortions for standard silicon solar cells. Hence, adequate acquisition of one image only is sufficient to generate a meaningful map of short-circuit current density. Beyond that, this work illustrates the underlying physics of the recently proposed method and demonstrates its robustness concerning varying excitation conditions and locally increased series resistance. Experimentally gained short-circuit current density images are validated for monochromatic illumination in comparison to the reference method of light-beam induced current.

  18. Determination of defect density of state distribution of amorphous silicon solar cells by temperature derivative capacitance-frequency measurement

    SciTech Connect (OSTI)

    Yang, Guangtao Swaaij, R. A. C. M. M. van; Dobrovolskiy, S.; Zeman, M.

    2014-01-21

    In this contribution, we demonstrate the application temperature dependent capacitance-frequency measurements (C-f) to n-i-p hydrogenated amorphous silicon (a-Si:H) solar cells that are forward-biased. By using a forward bias, the C-f measurement can detect the density of defect states in a particular energy range of the interface region. For this contribution, we have carried out this measurement method on n-i-p a-Si:H solar cells of which the intrinsic layer has been exposed to a H{sub 2}-plasma before p-type layer deposition. After this treatment, the open-circuit voltage and fill factor increased significantly, as well as the blue response of the solar cells as is concluded from external quantum efficiency. For single junction, n-i-p a-Si:H solar cells initial efficiency increased from 6.34% to 8.41%. This performance enhancement is believed to be mainly due to a reduction of the defect density in the i-p interface region after the H{sub 2}-plasma treatment. These results are confirmed by the C-f measurements. After H{sub 2}-plasma treatment, the defect density in the intrinsic layer near the i-p interface region is lower and peaks at an energy level deeper in the band gap. These C-f measurements therefore enable us to monitor changes in the defect density in the interface region as a result of a hydrogen plasma. The lower defect density at the i-p interface as detected by the C-f measurements is supported by dark current-voltage measurements, which indicate a lower carrier recombination rate.

  19. Vehicle Technologies Office Merit Review 2015: High Energy Density Li-ion Cells for EV’s Based on Novel, High Voltage Cathode Material Systems

    Broader source: Energy.gov [DOE]

    Presentation given by Farasis at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about high energy density Li-ion cells for...

  20. Development of Large Format Lithium Ion Cells with Higher Energy Density

    Broader source: Energy.gov [DOE]

    2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  1. Design of Safer High-Energy Density Materials for Lithium-Ion Cells

    Broader source: Energy.gov [DOE]

    2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  2. Development of Large Format Lithium Ion Cells with Higher Energy Density Exceeding 500Wh/L

    Office of Energy Efficiency and Renewable Energy (EERE)

    2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  3. Vehicle Technologies Office Merit Review 2016: Development of High Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Lithium-Sulfur Batteries | Department of Energy Development of High Energy Lithium-Sulfur Batteries Vehicle Technologies Office Merit Review 2016: Development of High Energy Lithium-Sulfur Batteries Presentation given by Pacific Northwest National Laboratory (PNNL) at the 2016 DOE Vehicle Technologies Office and Hydrogen and Fuel Cells Program Annual Merit Review and Peer Evaluation Meeting about Batteries es282_liu_2016_p_web.pdf (2.02 MB) More Documents & Publications Vehicle

  4. A low cost, high energy density and long cycle life potassium-sulfur battery for grid-scale energy storage

    SciTech Connect (OSTI)

    Lu, Xiaochuan; Bowden, Mark E.; Sprenkle, Vincent L.; Liu, Jun

    2015-08-15

    Alkali metal-sulfur batteries are attractive for energy storage applications because of their high energy density. Among the batteries, lithium-sulfur batteries typically use liquid in the battery electrolyte, which causes problems in both performance and safety. Sodium-sulfur batteries can use a solid electrolyte such as beta alumina but this requires a high operating temperature. Here we report a novel potassium-sulfur battery with K+-conducting beta-alumina as the electrolyte. Our studies indicate that liquid potassium exhibits much better wettability on the surface of beta-alumina compared to liquid sodium at lower temperatures. Based on this observation, we develop a potassium-sulfur battery that can operate at as low as 150°C with excellent performance. In particular, the battery shows excellent cycle life with negligible capacity fade in 1000 cycles because of the dense ceramic membrane. This study demonstrates a new battery with a high energy density, long cycle life, low cost and high safety, which is ideal for grid-scale energy storage.

  5. Forming high efficiency silicon solar cells using density-graded anti-reflection surfaces

    DOE Patents [OSTI]

    Yuan, Hao-Chih; Branz, Howard M.; Page, Matthew R.

    2014-09-09

    A method (50) is provided for processing a graded-density AR silicon surface (14) to provide effective surface passivation. The method (50) includes positioning a substrate or wafer (12) with a silicon surface (14) in a reaction or processing chamber (42). The silicon surface (14) has been processed (52) to be an AR surface with a density gradient or region of black silicon. The method (50) continues with heating (54) the chamber (42) to a high temperature for both doping and surface passivation. The method (50) includes forming (58), with a dopant-containing precursor in contact with the silicon surface (14) of the substrate (12), an emitter junction (16) proximate to the silicon surface (14) by doping the substrate (12). The method (50) further includes, while the chamber is maintained at the high or raised temperature, forming (62) a passivation layer (19) on the graded-density silicon anti-reflection surface (14).

  6. Forming high-efficiency silicon solar cells using density-graded anti-reflection surfaces

    DOE Patents [OSTI]

    Yuan, Hao-Chih; Branz, Howard M.; Page, Matthew R.

    2015-07-07

    A method (50) is provided for processing a graded-density AR silicon surface (14) to provide effective surface passivation. The method (50) includes positioning a substrate or wafer (12) with a silicon surface (14) in a reaction or processing chamber (42). The silicon surface (14) has been processed (52) to be an AR surface with a density gradient or region of black silicon. The method (50) continues with heating (54) the chamber (42) to a high temperature for both doping and surface passivation. The method (50) includes forming (58), with a dopant-containing precursor in contact with the silicon surface (14) of the substrate (12), an emitter junction (16) proximate to the silicon surface (14) by doping the substrate (12). The method (50) further includes, while the chamber is maintained at the high or raised temperature, forming (62) a passivation layer (19) on the graded-density silicon anti-reflection surface (14).

  7. 2008 Annual Merit Review Results Summary - 4. Exploratory Battery Research

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy 4. Exploratory Battery Research 2008 Annual Merit Review Results Summary - 4. Exploratory Battery Research DOE Vehicle Technologies Annual Merit Review 2008_merit_review_4.pdf (2.34 MB) More Documents & Publications 2011 Annual Merit Review Results Report - Energy Storage Technologies Vehicle Technologies Office Merit Review 2014: Development of High Energy Density Lithium-Sulfur Cells Vehicle Technologies Office Merit Review 2015: Materials Development for High

  8. The Structural Evolution and Diffusion During the Chemical Transformation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    from Cobalt to Cobalt Phosphide Nanoparticles > Research Highlights > Research > The Energy Materials Center at Cornell Research Highlights In This Section The Structural Evolution and Diffusion During the Chemical Transformation from Cobalt to Cobalt Phosphide Nanoparticles Joint Density-Functional Theory of Electrochemistry Double-band Electrode Channel Flow DEMS Cell Sulfur@Carbon Cathodes for Lithium Sulfur Batteries Better Ham & Cheese: Enhanced Anodes and Cathodes for Fuel

  9. Vehicle Technologies Office Merit Review 2014: High Energy Density Li-ion Cells for EV’s Based on Novel, High Voltage Cathode Material Systems

    Broader source: Energy.gov [DOE]

    Presentation given by Farasis Energy, Inc. at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about high energy density Li...

  10. Identification of Catalysts and Materials for a High-Energy Density Biochemical Fuel Cell: Cooperative Research and Development Final Report, CRADA Number CRD-09-345

    SciTech Connect (OSTI)

    Ghirardi, M.; Svedruzic, D.

    2013-07-01

    The proposed research attempted to identify novel biochemical catalysts, catalyst support materials, high-efficiency electron transfer agents between catalyst active sites and electrodes, and solid-phase electrolytes in order to maximize the current density of biochemical fuel cells that utilize various alcohols as substrates.

  11. X-ray Absorption Spectroscopy Characterization of a Li/S Cell

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ye, Yifan; Kawase, Ayako; Song, Min-Kyu; Feng, Bingmei; Liu, Yi-Sheng; Marcus, Matthew A.; Feng, Jun; Cairns, Elton J.; Guo, Jinghua; Zhu, Junfa

    2016-01-11

    The X-ray absorption spectroscopy technique has been applied to study different stages of the lithium/sulfur (Li/S) cell life cycle. We investigated how speciation of S in Li/S cathodes changes upon the introduction of CTAB (cetyltrimethylammonium bromide, CH3(CH2)15N+(CH3)3Br₋) and with charge/discharge cycling. The introduction of CTAB changes the synthesis reaction pathway dramatically due to the interaction of CTAB with the terminal S atoms of the polysulfide ions in the Na2Sx solution. For the cycled Li/S cell, the loss of electrochemically active sulfur and the accumulation of a compact blocking insulating layer of unexpected sulfur reaction products on the cathode surface duringmore » the charge/discharge processes make the capacity decay. Lastly, a modified coin cell and a vacuum-compatible three-electrode electro-chemical cell have been introduced for further in-situ/in-operando studies.« less

  12. Vehicle Technologies Office Merit Review 2014: Development of Large Format Lithium Ion Cells with Higher Energy Density

    Broader source: Energy.gov [DOE]

    Presentation given by XALT Energy LLC at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about development of large format...

  13. Gas-to-liquids synthetic fuels for use in fuel cells : reformability, energy density, and infrastructure compatibility.

    SciTech Connect (OSTI)

    Ahmed, S.; Kopasz, J. P.; Russell, B. J.; Tomlinson, H. L.

    1999-09-08

    The fuel cell has many potential applications, from power sources for electric hybrid vehicles to small power plants for commercial buildings. The choice of fuel will be critical to the pace of its commercialization. This paper reviews the various liquid fuels being considered as an alternative to direct hydrogen gas for the fuel cell application, presents calculations of the hydrogen and carbon dioxide yields from autothermal reforming of candidate liquid fuels, and reports the product gas composition measured from the autothermal reforming of a synthetic fuel in a micro-reactor. The hydrogen yield for a synthetic paraffin fuel produced by a cobalt-based Fischer-Tropsch process was found to be similar to that of retail gasoline. The advantages of the synthetic fuel are that it contains no contaminants that would poison the fuel cell catalyst, is relatively benign to the environment, and could be transported in the existing fuel distribution system.

  14. New Electrode Manufacturing Process Equipment: Novel High Energy Density Lithium-Ion Cell Designs via Innovative Manufacturing Process Modules for Cathode and Integrated Separator

    SciTech Connect (OSTI)

    2010-07-01

    BEEST Project: Applied Materials is developing new tools for manufacturing Li-Ion batteries that could dramatically increase their performance. Traditionally, the positive and negative terminals of Li-Ion batteries are mixed with glue-like materials called binders, pressed onto electrodes, and then physically kept apart by winding a polymer mesh material between them called a separator. With the Applied Materials system, many of these manually intensive processes will be replaced by next generation coating technology to apply each component. This process will improve product reliability and performance of the cells at a fraction of the current cost. These novel manufacturing techniques will also increase the energy density of the battery and reduce the size of several of the batterys components to free up more space within the cell for storage.

  15. CX-003069: Categorical Exclusion Determination

    Office of Energy Efficiency and Renewable Energy (EERE)

    Scion Power - Development of High Energy Lithium Sulfur Cells for Electric VehiclesCX(s) Applied: B3.6Date: 06/02/2010Location(s): WashingtonOffice(s): Advanced Research Projects Agency - Energy

  16. Lewis Acid–Base Interactions between Polysulfides and Metal Organic Framework in Lithium Sulfur Batteries

    SciTech Connect (OSTI)

    Zheng, Jianming; Tian, Jian; Wu, Dangxin; Gu, Meng; Xu, Wu; Wang, Chongmin; Gao, Fei; Engelhard, Mark H.; Zhang, Ji-Guang; Liu, Jun; Xiao, Jie

    2014-05-14

    Lithium–sulfur (Li–S) battery is one of the most promising energy storage systems because of its high specific capacity of 1675 mAh g–1 based on sulfur. However, the rapid capacity degradation, mainly caused by polysulfide dissolution, remains a significant challenge prior to practical applications. This work demonstrates that a novel Ni-based metal organic framework (Ni-MOF), Ni6(BTB)4(BP)3 (BTB = benzene-1,3,5-tribenzoate and BP = 4,4'-bipyridyl), can remarkably immobilize polysulfides within the cathode structure through physical and chemical interactions at molecular level. The capacity retention achieves up to 89% after 100 cycles at 0.1 C. Finally, the excellent performance is attributed to the synergistic effects of the interwoven mesopores (~2.8 nm) and micropores (~1.4 nm) of Ni-MOF, which first provide an ideal matrix to confine polysulfides, and the strong interactions between Lewis acidic Ni(II) center and the polysulfide base, which significantly slow down the migration of soluble polysulfides out of the pores, leading to the excellent cycling performance of Ni-MOF/S composite.

  17. Sulfur-carbon nanocomposites and their application as cathode materials in lithium-sulfur batteries

    SciTech Connect (OSTI)

    Liang, Chengdu; Dudney, Nancy J; Howe, Jane Y

    2015-05-05

    The invention is directed in a first aspect to a sulfur-carbon composite material comprising: (i) a bimodal porous carbon component containing therein a first mode of pores which are mesopores, and a second mode of pores which are micropores; and (ii) elemental sulfur contained in at least a portion of said micropores. The invention is also directed to the aforesaid sulfur-carbon composite as a layer on a current collector material; a lithium ion battery containing the sulfur-carbon composite in a cathode therein; as well as a method for preparing the sulfur-composite material.

  18. Development of bulk-type all-solid-state lithium-sulfur battery...

    Office of Scientific and Technical Information (OSTI)

    Subject: 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; ANODES; BORON COMPOUNDS; CARBON; COLD PRESSING; DISPERSIONS; ELECTROCHEMISTRY; ELECTROLYTES; ENERGY...

  19. Reduction mechanism of sulfur in lithium-sulfur battery: From elemental sulfur to polysulfide

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zheng, Dong; Yang, Xuran; Zhang, Xiaoqing; Wang, Jiankun; Qu, Deyu; Qu, Deyang

    2015-10-30

    In this study, the polysulfide ions formed during the first reduction wave of sulfur in Li–S battery were determined through both in-situ and ex-situ derivatization of polysulfides. By comparing the cyclic voltammetric results with and without the derivatization reagent (methyl triflate) as well as the in-situ and ex-situ derivatization results under potentiostatic condition, in-situ derivatization was found to be more appropriate than its ex-situ counterpart, since subsequent fast chemical reactions between the polysulfides and sulfur may occur during the timeframe of ex-situ procedures. It was found that the major polysulfide ions formed at the first reduction wave of elemental sulfurmore » were the S42– and S52– species, while the widely accepted reduction products of S82– and S62– for the first reduction wave were in low abundance.« less

  20. Li2S encapsulated by nitrogen-doped carbon for lithium sulfur batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chen, Lin; Liu, Yuzi; Ashuri, Maziar; Liu, Caihong; Shaw, Leon L.

    2014-09-26

    Using high-energy ball milling of the Li2S plus carbon black mixture followed by carbonization of pyrrole, we have established a facile approach to synthesize Li2S-plus-C composite particles of average size 400 nm, encapsulated by a nitrogen-doped carbon shell. Such an engineered core–shell structure exhibits an ultrahigh initial discharge specific capacity (1029 mAh/g), reaching 88% of the theoretical capacity (1,166 mAh/g of Li2S) and thus offering the highest utilization of Li2S in the cathode among all of the reported works for the encapsulated Li2S cathodes. This Li2S/C composite core with a nitrogen-doped carbon shell can still retain 652 mAh/g after prolongedmore » 100 cycles. These superior properties are attributed to the nitrogen-doped carbon shell that can improve the conductivity to enhance the utilization of Li2S in the cathode. As a result, fine particle sizes and the presence of carbon black within the Li2S core may also play a role in high utilization of Li2S in the cathode.« less

  1. Reduction mechanism of sulfur in lithium-sulfur battery: From elemental sulfur to polysulfide

    SciTech Connect (OSTI)

    Zheng, Dong; Yang, Xuran; Zhang, Xiaoqing; Wang, Jiankun; Qu, Deyu; Qu, Deyang

    2015-10-30

    In this study, the polysulfide ions formed during the first reduction wave of sulfur in Li–S battery were determined through both in-situ and ex-situ derivatization of polysulfides. By comparing the cyclic voltammetric results with and without the derivatization reagent (methyl triflate) as well as the in-situ and ex-situ derivatization results under potentiostatic condition, in-situ derivatization was found to be more appropriate than its ex-situ counterpart, since subsequent fast chemical reactions between the polysulfides and sulfur may occur during the timeframe of ex-situ procedures. It was found that the major polysulfide ions formed at the first reduction wave of elemental sulfur were the S42– and S52– species, while the widely accepted reduction products of S82– and S62– for the first reduction wave were in low abundance.

  2. News Item

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Controlled Porous Membranes for Better Batteries Scientific Achievement Molecular Foundry staff and users have combined to develop membranes for lithium-sulfur batteries made from polymers of intrinsic microporosity (PIMs) that are 500 times more effective than conventional membranes. Significance and Impact Lithium-sulfur batteries are well poised to provide high-density, long-term and low-cost electrochemical energy storage but current designs have limited efficiency and lifetimes due to the

  3. Redox Mediators that Promote Three-Dimensional Growth of Li2S on Carbon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Current Collectors in Lithium-Sulfur Batteries - Joint Center for Energy Storage Research 21, 2015, Research Highlights Redox Mediators that Promote Three-Dimensional Growth of Li2S on Carbon Current Collectors in Lithium-Sulfur Batteries Controlling the electrodeposition of Li2S onto C using a redox mediator, BPI. With BPI, sulfur utilization improves in Li-S cells due to remote reduction of polysulfides to Li2S. Scientific Achievement Developed, from computation and experiment, redox

  4. Low density carbonized composite foams

    DOE Patents [OSTI]

    Kong, Fung-Ming

    1993-01-01

    A carbonized composite foam having a density less than about 50 mg/cm.sup.3 and individual cell sizes no greater than about 1 .mu.m in diameter is described, and the process of making it.

  5. Low density carbonized composite foams

    DOE Patents [OSTI]

    Kong, Fung-Ming

    1991-01-01

    A carbonized composite foam having a density less than about 50 mg/cm.sup.3 and individual cell sizes no greater than about 1 .mu.m in diameter is described, and the process of making it.

  6. Vehicle Technologies Office Merit Review 2016: High Energy Density Li-ion Cells for EV’s Based on Novel, High Voltage Cathode Material Systems

    Broader source: Energy.gov [DOE]

    Presentation given by Farasis at the 2016 DOE Vehicle Technologies Office and Hydrogen and Fuel Cells Program Annual Merit Review and Peer Evaluation Meeting about Batteries

  7. Low density microcellular foams

    DOE Patents [OSTI]

    LeMay, J.D.

    1991-11-19

    Disclosed is a process of producing microcellular foam which comprises the steps of: (a) selecting a multifunctional epoxy oligomer resin; (b) mixing said epoxy resin with a non-reactive diluent to form a resin-diluent mixture; (c) forming a diluent containing cross-linked epoxy gel from said resin-diluent mixture; (d) replacing said diluent with a solvent therefore; (e) replacing said solvent with liquid carbon dioxide; and (f) vaporizing off said liquid carbon dioxide under supercritical conditions, whereby a foam having a density in the range of 35-150 mg/cc and cell diameters less than about 1 [mu]m is produced. Also disclosed are the foams produced by the process. 8 figures.

  8. Low density microcellular foams

    DOE Patents [OSTI]

    LeMay, James D.

    1992-01-01

    Disclosed is a process of producing microcellular from which comprises the steps of: (a) selecting a multifunctional epoxy oligomer resin; (b) mixing said epoxy resin with a non-reactive diluent to form a resin-diluent mixture; (c) forming a diluent containing cross-linked epoxy gel from said resin-diluent mixture; (d) replacing said diluent with a solvent therefore; (e) replacing said solvent with liquid carbon dioxide; and (f) vaporizing off said liquid carbon dioxide under supercritical conditions, whereby a foam having a density in the range of 35-150 mg/cc and cell diameters less than about 1 .mu.m is produced. Also disclosed are the foams produced by the process.

  9. Low density microcellular foams

    DOE Patents [OSTI]

    LeMay, James D.

    1991-01-01

    Disclosed is a process of producing microcellular foam which comprises the steps of: (a) selecting a multifunctional epoxy oligomer resin; (b) mixing said epoxy resin with a non-reactive diluent to form a resin-diluent mixture; (c) forming a diluent containing cross-linked epoxy gel from said resin-diluent mixture; (d) replacing said diluent with a solvent therefore; (e) replacing said solvent with liquid carbon dioxide; and (f) vaporizing off said liquid carbon dioxide under supercritical conditions, whereby a foam having a density in the range of 35-150 mg/cc and cell diameters less than about 1 .mu.m is produced. Also disclosed are the foams produced by the process.

  10. Tailoring Pore Size of Nitrogen-Doped Hollow Carbon Nanospheres for Confi ning Sulfur in LithiumSulfur Batteries

    SciTech Connect (OSTI)

    Zhou, Weidong; Wang, Chong M.; Zhang, Quiglin; Abruna, Hector D.; He, Yang; Wang, Jiangwei; Mao, Scott X.; Xiao, Xingcheng

    2015-08-19

    Three types of nitrogen-doped hollow carbon spheres with different pore sized porous shells are prepared to investigate the performance of sulfur confinement. The reason that why no sulfur is observed in previous research is determined and it is successfully demonstrated that the sulfur/polysulfide will overflow the porous carbon during the lithiation process.

  11. Following the Transient Reactions in Lithium-Sulfur Batteries Using In an In Situ Nuclear Magnetic Resonance Technique

    SciTech Connect (OSTI)

    Xiao, Jie; Hu, Jian Z.; Chen, Honghao; Vijayakumar, M.; Zheng, Jianming; Pan, Huilin; Walter, Eric D.; Hu, Mary Y.; Deng, Xuchu; Feng, Ju; Liaw, Bor Yann; Gu, Meng; Deng, Zhiqun; Lu, Dongping; Xu, Suochang; Wang, Chong M.; Liu, Jun

    2015-05-13

    Li-S batteries hold great potential for next-generation, large-format power source applications; yet, the fundamental understanding of the electrochemical reaction pathways remains lacking to enable their functionality as promised. Here, in situ NMR technique employing a specially designed cylindrical micro battery was used to monitor the chemical environments around Li+ ions during repetitive charge-discharge process and track the transient electrochemical and chemical reactions occurring in the whole Li-S system. The in situ NMR provides real time, quantitative information related to the temporal concentration variations of the polysulfides with various chain lengths, providing important clues for the reaction pathways during both discharge and charge processes. The in-situ technique also reveals that redox reactions may involve transient species that are difficult to detect in ex-situ NMR study. Intermediate species such as charged free radicals may play an important role in the formation of the polysulfide products. Additionally, in situ NMR measurement simultaneously reveals vital information on the 7Li chemical environments in the electrochemical and parasitic reactions on the lithium anode that promotes the understanding of the failure mechanism in the Li-S system. These new insights could help design effective strategies to accelerate the development of Li-S battery technology.

  12. Li2S encapsulated by nitrogen-doped carbon for lithium sulfur batteries

    SciTech Connect (OSTI)

    Chen, Lin; Liu, Yuzi; Ashuri, Maziar; Liu, Caihong; Shaw, Leon L.

    2014-09-26

    Using high-energy ball milling of the Li2S plus carbon black mixture followed by carbonization of pyrrole, we have established a facile approach to synthesize Li2S-plus-C composite particles of average size 400 nm, encapsulated by a nitrogen-doped carbon shell. Such an engineered core–shell structure exhibits an ultrahigh initial discharge specific capacity (1029 mAh/g), reaching 88% of the theoretical capacity (1,166 mAh/g of Li2S) and thus offering the highest utilization of Li2S in the cathode among all of the reported works for the encapsulated Li2S cathodes. This Li2S/C composite core with a nitrogen-doped carbon shell can still retain 652 mAh/g after prolonged 100 cycles. These superior properties are attributed to the nitrogen-doped carbon shell that can improve the conductivity to enhance the utilization of Li2S in the cathode. As a result, fine particle sizes and the presence of carbon black within the Li2S core may also play a role in high utilization of Li2S in the cathode.

  13. Low density microcellular foams

    DOE Patents [OSTI]

    Aubert, James H.; Clough, Roger L.; Curro, John G.; Quintana, Carlos A.; Russick, Edward M.; Shaw, Montgomery T.

    1987-01-01

    Low density, microporous polymer foams are provided by a process which comprises forming a solution of polymer and a suitable solvent followed by rapid cooling of the solution to form a phase-separated system and freeze the phase-separated system. The phase-separated system comprises a polymer phase and a solvent phase, each of which is substantially continuous within the other. The morphology of the polymer phase prior to and subsequent to freezing determine the morphology of the resultant foam. Both isotropic and anisotropic foams can be produced. If isotropic foams are produced, the polymer and solvent are tailored such that the solution spontaneously phase-separates prior to the point at which any component freezes. The morphology of the resultant polymer phase determines the morphology of the resultant foam and the morphology of the polymer phase is retained by cooling the system at a rate sufficient to freeze one or both components of the system before a change in morphology can occur. Anisotropic foams are produced by forming a solution of polymer and solvent that will not phase separate prior to freezing of one or both components of the solution. In such a process, the solvent typically freezes before phase separation occurs. The morphology of the resultant frozen two-phase system determines the morphology of the resultant foam. The process involves subjecting the solution to essentially one-dimensional cooling. Means for subjecting such a solvent to one-dimensional cooling are also provided. Foams having a density of less than 0.1 g/cc and a uniform cell size of less than 10 .mu.m and a volume such that the foams have a length greater than 1 cm are provided.

  14. Low density microcellular foams

    DOE Patents [OSTI]

    Aubert, J.H.; Clough, R.L.; Curro, J.G.; Quintana, C.A.; Russick, E.M.; Shaw, M.T.

    1985-10-02

    Low density, microporous polymer foams are provided by a process which comprises forming a solution of polymer and a suitable solvent followed by rapid cooling of the solution to form a phase-separated system and freeze the phase-separated system. The phase-separated system comprises a polymer phase and a solvent phase, each of which is substantially continuous within the other. The morphology of the polymer phase prior to and subsequent to freezing determine the morphology of the resultant foam. Both isotropic and anisotropic foams can be produced. If isotropic foams are produced, the polymer and solvent are tailored such that the solution spontaneously phase-separates prior to the point at which any component freezes. The morphology of the resultant polymer phase determines the morphology of the reusltant foam and the morphology of the polymer phase is retained by cooling the system at a rate sufficient to freeze one or both components of the system before a change in morphology can occur. Anisotropic foams are produced by forming a solution of polymer and solvent that will not phase separate prior to freezing of one or both components of the solution. In such a process, the solvent typically freezes before phase separation occurs. The morphology of the resultant frozen two-phase system determines the morphology of the resultant foam. The process involves subjecting the solution to essentially one-dimensional cooling. Foams having a density of less than 0.1 g/cc and a uniform cell size of less than 10 ..mu..m and a volume such that the foams have a length greater than 1 cm are provided.

  15. Low density, resorcinol-formaldehyde aerogels

    DOE Patents [OSTI]

    Pekala, Richard W.

    1991-01-01

    The polycondensation of resorcinol with formaldehyde under alkaline conditions results in the formation of surface functionalized polymer "Clusters". The covalent crosslinking of these "clusters" produces gels which when processed under supercritical conditions, produce low density, organic aerogels (density.ltoreq.100 mg/cc; cell size .ltoreq.0.1 microns). The aerogels are transparent, dark red in color and consist of interconnected colloidal-like particles with diameters of about 100.circle.. These aerogels may be further carbonized to form low density carbon foams with cell size of about 0.1 micron.

  16. Low density, resorcinol-formaldehyde aerogels

    DOE Patents [OSTI]

    Pekala, Richard W.

    1989-01-01

    The polycondensation of resorcinol with formaldehyde under alkaline conditions results in the formation of surface functionalized polymer "clusters". The covalent crosslinking of these "clusters" produces gels which when processed under supercritical conditions, produce low density, organic aerogels (density .ltoreq.100 mg/cc; cell size .ltoreq.0.1 microns). The aerogels are transparent, dark red in color and consist of interconnected colloidal-like particles with diameters of about 100 .ANG.. These aerogels may be further carbonized to form low density carbon foams with cell size of about 0.1 micron.

  17. Low density, resorcinol-formaldehyde aerogels

    DOE Patents [OSTI]

    Pekala, R.W.

    1989-10-10

    The polycondensation of resorcinol with formaldehyde under alkaline conditions results in the formation of surface functionalized polymer clusters. The covalent crosslinking of these clusters produces gels which when processed under supercritical conditions, produce low density, organic aerogels (density [<=]100 mg/cc; cell size [<=]0.1 microns). The aerogels are transparent, dark red in color and consist of interconnected colloidal-like particles with diameters of about 100 [angstrom]. These aerogels may be further carbonized to form low density carbon foams with cell size of about 0.1 micron.

  18. Low density, resorcinol-formaldehyde aerogels

    DOE Patents [OSTI]

    Pekala, R.W.

    1988-05-26

    The polycondensation of resorcinol with formaldehyde under alkaline conditions results in the formation of surface functionalized polymer ''clusters''. The covalent crosslinking of these ''clusters'' produces gels which when processed under supercritical conditions, produce low density, organic aerogels (density less than or equal to100 mg/cc; cell size less than or equal to0.1 microns). The aerogels are transparent,dark red in color and consist of interconnected colloidal-like particles with diameters of about 100 A/degree/. These aerogels may be further carbonized to form low density carbon foams with cell size of about 0.1 micron. 1 fig., 1 tab.

  19. Visualization of electronic density

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Grosso, Bastien; Cooper, Valentino R.; Pine, Polina; Hashibon, Adham; Yaish, Yuval; Adler, Joan

    2015-04-22

    An atom’s volume depends on its electronic density. Although this density can only be evaluated exactly for hydrogen-like atoms, there are many excellent numerical algorithms and packages to calculate it for other materials. 3D visualization of charge density is challenging, especially when several molecular/atomic levels are intertwined in space. We explore several approaches to 3D charge density visualization, including the extension of an anaglyphic stereo visualization application based on the AViz package to larger structures such as nanotubes. We will describe motivations and potential applications of these tools for answering interesting questions about nanotube properties.

  20. Visualization of electronic density

    SciTech Connect (OSTI)

    Grosso, Bastien; Cooper, Valentino R.; Pine, Polina; Hashibon, Adham; Yaish, Yuval; Adler, Joan

    2015-04-22

    An atoms volume depends on its electronic density. Although this density can only be evaluated exactly for hydrogen-like atoms, there are many excellent numerical algorithms and packages to calculate it for other materials. 3D visualization of charge density is challenging, especially when several molecular/atomic levels are intertwined in space. We explore several approaches to 3D charge density visualization, including the extension of an anaglyphic stereo visualization application based on the AViz package to larger structures such as nanotubes. We will describe motivations and potential applications of these tools for answering interesting questions about nanotube properties.

  1. Particle Gas Target for High Density Laser Produced Plasmas Charles...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Particle Gas Target for High Density Laser Produced Plasmas Charles H. Skinner, Nathaniel Fisch, and Ernest Valeo This invention is a novel "particle gas" cell for achieving plasma ...

  2. Near-surface Density Currents Observed in the Southeast Pacific...

    Office of Scientific and Technical Information (OSTI)

    Density currents preferentially occur in regions of open cells but also occur in regions ... Country of Publication: United States Language: English Subject: marine stratocumulus ...

  3. Density-dependent covariant energy density functionals

    SciTech Connect (OSTI)

    Lalazissis, G. A.

    2012-10-20

    Relativistic nuclear energy density functionals are applied to the description of a variety of nuclear structure phenomena at and away fromstability line. Isoscalar monopole, isovector dipole and isoscalar quadrupole giant resonances are calculated using fully self-consistent relativistic quasiparticle randomphase approximation, based on the relativistic Hartree-Bogoliubovmodel. The impact of pairing correlations on the fission barriers in heavy and superheavy nuclei is examined. The role of pion in constructing desnity functionals is also investigated.

  4. Density Equalizing Map Projections

    Energy Science and Technology Software Center (OSTI)

    1995-07-01

    A geographic map is mathematically transformed so that the subareas of the map are proportional to a given quantity such as population. In other words, population density is equalized over the entire map. The transformed map can be used as a display tool, or it can be statistically analyzed. For example, cases of disease plotted on the transformed map should be uniformly distributed at random, if disease rates are everywhere equal. Geographic clusters of diseasemore » can be readily identified, and their statistical significance determined, on a density equalized map.« less

  5. Multiple density layered insulator

    DOE Patents [OSTI]

    Alger, Terry W.

    1994-01-01

    A multiple density layered insulator for use with a laser is disclosed wh provides at least two different insulation materials for a laser discharge tube, where the two insulation materials have different thermoconductivities. The multiple layer insulation materials provide for improved thermoconductivity capability for improved laser operation.

  6. Energy in density gradient

    SciTech Connect (OSTI)

    Vranjes, J.; Kono, M.

    2015-01-15

    Inhomogeneous plasmas and fluids contain energy stored in inhomogeneity and they naturally tend to relax into lower energy states by developing instabilities or by diffusion. But the actual amount of energy in such inhomogeneities has remained unknown. In the present work, the amount of energy stored in a density gradient is calculated for several specific density profiles in a cylindrical configuration. This is of practical importance for drift wave instability in various plasmas, and, in particular, in its application in models dealing with the heating of solar corona because the instability is accompanied with stochastic heating, so the energy contained in inhomogeneity is effectively transformed into heat. It is shown that even for a rather moderate increase of the density at the axis in magnetic structures in the corona by a factor 1.5 or 3, the amount of excess energy per unit volume stored in such a density gradient becomes several orders of magnitude greater than the amount of total energy losses per unit volume (per second) in quiet regions in the corona. Consequently, within the life-time of a magnetic structure such energy losses can easily be compensated by the stochastic drift wave heating.

  7. Multiple density layered insulator

    DOE Patents [OSTI]

    Alger, T.W.

    1994-09-06

    A multiple density layered insulator for use with a laser is disclosed which provides at least two different insulation materials for a laser discharge tube, where the two insulation materials have different thermoconductivities. The multiple layer insulation materials provide for improved thermoconductivity capability for improved laser operation. 4 figs.

  8. Interferometer for the measurement of plasma density

    DOE Patents [OSTI]

    Jacobson, Abram R.

    1980-01-01

    An interferometer which combines the advantages of a coupled cavity interferometer requiring alignment of only one light beam, and a quadrature interferometer which has the ability to track multi-fringe phase excursions unambiguously. The device utilizes a Bragg cell for generating a signal which is electronically analyzed to unambiguously determine phase modulation which is proportional to the path integral of the plasma density.

  9. Density Log | Open Energy Information

    Open Energy Info (EERE)

    Density Log Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Technique: Density Log Details Activities (7) Areas (6) Regions (0) NEPA(0) Exploration...

  10. Rock Density | Open Energy Information

    Open Energy Info (EERE)

    Density Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Technique: Rock Density Details Activities (2) Areas (2) Regions (0) NEPA(0) Exploration Technique...

  11. Strong Lithium Polysulfide Chemisorption on Electroactive Sites...

    Office of Scientific and Technical Information (OSTI)

    For High-Performance Lithium-Sulfur Battery Cathodes Citation Details In-Document ... For High-Performance Lithium-Sulfur Battery Cathodes Despite the high theoretical ...

  12. Carbon/Sulfur Nanocomposites and Additives for High-Energy Lithium...

    Broader source: Energy.gov (indexed) [DOE]

    Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries CarbonSulfur Nanocomposites and Additives for High-Energy Lithium Sulfur Batteries Vehicle Technologies ...

  13. Carbon/Sulfur Nanocomposites and Additives for High-Energy Lithium...

    Broader source: Energy.gov (indexed) [DOE]

    CarbonSulfur Nanocomposites and Additives for High-Energy Lithium Sulfur Batteries Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries Protection of Li Anodes ...

  14. Gedanken densities and exact constraints in density functional theory

    SciTech Connect (OSTI)

    Perdew, John P.; Department of Chemistry, Temple University, Philadelphia, Pennsylvania 19122 ; Ruzsinszky, Adrienn; Sun, Jianwei; Burke, Kieron

    2014-05-14

    Approximations to the exact density functional for the exchange-correlation energy of a many-electron ground state can be constructed by satisfying constraints that are universal, i.e., valid for all electron densities. Gedanken densities are designed for the purpose of this construction, but need not be realistic. The uniform electron gas is an old gedanken density. Here, we propose a spherical two-electron gedanken density in which the dimensionless density gradient can be an arbitrary positive constant wherever the density is non-zero. The Lieb-Oxford lower bound on the exchange energy can be satisfied within a generalized gradient approximation (GGA) by bounding its enhancement factor or simplest GGA exchange-energy density. This enhancement-factor bound is well known to be sufficient, but our gedanken density shows that it is also necessary. The conventional exact exchange-energy density satisfies no such local bound, but energy densities are not unique, and the simplest GGA exchange-energy density is not an approximation to it. We further derive a strongly and optimally tightened bound on the exchange enhancement factor of a two-electron density, which is satisfied by the local density approximation but is violated by all published GGA's or meta-GGA’s. Finally, some consequences of the non-uniform density-scaling behavior for the asymptotics of the exchange enhancement factor of a GGA or meta-GGA are given.

  15. Low density, microcellular foams, preparation, and articles

    DOE Patents [OSTI]

    Young, Ainslie T.; Marsters, Robert G.; Moreno, Dawn K.

    1984-01-01

    A microcellular low density foam of poly(4-methyl-1-pentene) which is particularly useful for forming targets for inertial confinement fusion has been developed. Articles made from the foam have been machined to tolerances of 0.0001 inch, although the densities of the fragile foam are low (about 10 to about 100 mg/cc) and the cell sizes are small (about 10 to about 30 .mu.m). Methods for forming the foam and articles are given; and the yield strength of the foam of the invention is higher than was obtained in other structures of this same material.

  16. Low density, microcellular foams, preparation, and articles

    DOE Patents [OSTI]

    Young, A.T.

    1982-03-03

    A microcellular low-density foam of poly(4-methyl-1-pentene) particularly useful for forming targets for inertial confinement fusion has been developed. Articles made from the foam have been machined to tolerances of 0.0001 inch, although the densities of the fragile foam are low (about 10 to about 100 mg/cc) and the cell sizes are small (about 10 to about 30 ..mu..m). Methods for forming the foam and articles are given. The yield strength of the foam of the invention is higher than was obtained in other structures of this same material.

  17. High Energy Density Capacitors

    SciTech Connect (OSTI)

    2010-07-01

    BEEST Project: Recapping is developing a capacitor that could rival the energy storage potential and price of todays best EV batteries. When power is needed, the capacitor rapidly releases its stored energy, similar to lightning being discharged from a cloud. Capacitors are an ideal substitute for batteries if their energy storage capacity can be improved. Recapping is addressing storage capacity by experimenting with the material that separates the positive and negative electrodes of its capacitors. These separators could significantly improve the energy density of electrochemical devices.

  18. Development of High Power Density Driveline for Vehicles | Department of

    Broader source: Energy.gov (indexed) [DOE]

    Energy 1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation vss058_fenske_2011_o.pdf (352.55 KB) More Documents & Publications Development of High Power Density Driveline for Vehicles Vehicle Technologies Office Merit Review 2014: Development of High Power Density Driveline for Vehicles Vehicle Technologies Office Merit Review 2015: Development of High Power Density

  19. High Energy Density Microwaves

    SciTech Connect (OSTI)

    Phillips, R.M. [Stanford Linear Accelerator Center, Stanford, CA 94309 (United States)

    1999-04-01

    These proceedings represent papers presented at the RF98 Workshop entitled `High Energy Density Microwaves` held in California in October, 1998. The topics discussed were predominantly accelerator{minus}related. The Workshop dealt, for the most part, with the generation and control of electron beams, the amplification of RF signals, the design of mode converters, and the effect of very high RF field gradients. This Workshop was designed to address the concerns of the microwave tube industry worldwide, the plasma physicists who deal with very high beam currents and gigawatts of RF power, and researchers in accelerator centers around the world. Papers were presented on multibeam klystrons, gyrotron development, plasmas in microwave tubes, RF breakdown, and alternatives to conventional linear coliders at 1 TeV and above. The Workshop was partially sponsored by the US Department of Energy. There were 46 papers presented at the conference,out of which 19 have been abstracted for the Energy,Science and Technology database.(AIP)

  20. Effect of sulfur content in a sulfur-activated carbon composite on the electrochemical properties of a lithium/sulfur battery

    SciTech Connect (OSTI)

    Park, Jin-Woo; Kim, Changhyeon; Ryu, Ho-Suk; Cho, Gyu-Bong; Cho, Kwon-Koo; Kim, Ki-Won; Ahn, Jou-Hyeon; Wang, Guoxiu; Ahn, Jae-Pyeung; Ahn, Hyo-Jun

    2015-09-15

    Highlights: • The content of sulfur in activated carbon was controlled by solution process. • The sulfur electrode with low sulfur content shows the best performance. • The Li/S battery has capacity of 1360 mAh/g at 1 C and 702 mAh/g at 10 C. - Abstract: The content of sulfur in sulfur/activated carbon composite is controlled from 32.37 wt.% to 55.33 wt.% by a one-step solution-based process. When the sulfur content is limited to 41.21 wt.%, it can be loaded into the pores of an activated carbon matrix in a highly dispersed state. On the contrary, when the sulfur content is 55.33 wt.%, crystalline sulfur can be detected on the surface of the activated carbon matrix. The best electrochemical performance can be obtained for a sulfur electrode with the lowest sulfur content. The sulfur/activated carbon composite with 32.37 wt.% sulfur afforded the highest first discharge capacity of 1360 mAh g{sup −1} at 1 C rate and a large reversible capacity of 702 mAh g{sup −1} at 10 C (16.75 A/g)

  1. Strong Lithium Polysulfide Chemisorption on Electroactive Sites of Nitrogen-Doped Carbon Composites For High-Performance Lithium-Sulfur Battery Cathodes

    SciTech Connect (OSTI)

    Song, Jiangxuan; Gordin, Mikhail L.; Xu, Terrence; Chen, Shuru; Yu, Zhaoxin; Sohn, Hiesang; Lu, Jun; Ren, Yang; Duan, Yuhua; Wang, Donghai

    2015-03-27

    Despite the high theoretical capacity of lithium–sulfur batteries, their practical applications are severely hindered by a fast capacity decay, stemming from the dissolution and diffusion of lithium polysulfides in the electrolyte. A novel functional carbon composite (carbon-nanotube-interpenetrated mesoporous nitrogen-doped carbon spheres, MNCS/CNT), which can strongly adsorb lithium polysulfides, is now reported to act as a sulfur host. The nitrogen functional groups of this composite enable the effective trapping of lithium polysulfides on electroactive sites within the cathode, leading to a much improved electrochemical performance (1200 mAhg-1after 200 cycles). The enhancement in adsorption can be attributed to the chemical bonding of lithium ions by nitrogen functional groups in the MNCS/CNT framework. Furthermore, the micrometer-sized spherical structure of the material yields a high areal capacity (ca.6 mAhcm-2) with a high sulfur loading of approximately 5 mgcm-2, which is ideal for practical applications of the lithium–sulfur batteries.

  2. Quantitative and Qualitative Determination of Polysulfide Species in the Electrolyte of a Lithium-Sulfur Battery using HPLC ESI/MS with One-Step Derivatization

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zheng, Dong; Qu, Deyu; Yang, Xiao-Qing; Yu, Xiqian; Lee, Hung-Sui; Qu, Deyang

    2015-01-29

    The polysulfide species dissolved in aprotic solvents can be separated and analyzed by reverse phase (RP) high performance liquid chromatography (HPLC) in tandem with electrospray-mass spectroscopy. The relative distribution of polysulfide species in the electrolyte recovered from Li-S batteries is quantitatively and reliably determined for the first time.

  3. Quantum crystallographic charge density of urea

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wall, Michael E.

    2016-07-01

    Standard X-ray crystallography methods use free-atom models to calculate mean unit-cell charge densities. Real molecules, however, have shared charge that is not captured accurately using free-atom models. To address this limitation, a charge density model of crystalline urea was calculated using high-level quantum theory and was refined against publicly available ultra-high-resolution experimental Bragg data, including the effects of atomic displacement parameters. The resulting quantum crystallographic model was compared with models obtained using spherical atom or multipole methods. Despite using only the same number of free parameters as the spherical atom model, the agreement of the quantum model with the datamore » is comparable to the multipole model. The static, theoretical crystalline charge density of the quantum model is distinct from the multipole model, indicating the quantum model provides substantially new information. Hydrogen thermal ellipsoids in the quantum model were very similar to those obtained using neutron crystallography, indicating that quantum crystallography can increase the accuracy of the X-ray crystallographic atomic displacement parameters. Lastly, the results demonstrate the feasibility and benefits of integrating fully periodic quantum charge density calculations into ultra-high-resolution X-ray crystallographic model building and refinement.« less

  4. Category:Rock Density | Open Energy Information

    Open Energy Info (EERE)

    Rock Density Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Geothermalpower.jpg Looking for the Rock Density page? For detailed information on Rock Density as...

  5. Attractor comparisons based on density

    SciTech Connect (OSTI)

    Carroll, T. L.

    2015-01-15

    Recognizing a chaotic attractor can be seen as a problem in pattern recognition. Some feature vector must be extracted from the attractor and used to compare to other attractors. The field of machine learning has many methods for extracting feature vectors, including clustering methods, decision trees, support vector machines, and many others. In this work, feature vectors are created by representing the attractor as a density in phase space and creating polynomials based on this density. Density is useful in itself because it is a one dimensional function of phase space position, but representing an attractor as a density is also a way to reduce the size of a large data set before analyzing it with graph theory methods, which can be computationally intensive. The density computation in this paper is also fast to execute. In this paper, as a demonstration of the usefulness of density, the density is used directly to construct phase space polynomials for comparing attractors. Comparisons between attractors could be useful for tracking changes in an experiment when the underlying equations are too complicated for vector field modeling.

  6. Phenomenological Relativistic Energy Density Functionals

    SciTech Connect (OSTI)

    Lalazissis, G. A.; Kartzikos, S.; Niksic, T.; Paar, N.; Vretenar, D.; Ring, P.

    2009-08-26

    The framework of relativistic nuclear energy density functionals is applied to the description of a variety of nuclear structure phenomena, not only in spherical and deformed nuclei along the valley of beta-stability, but also in exotic systems with extreme isospin values and close to the particle drip-lines. Dynamical aspects of exotic nuclear structure is explored using the fully consistent quasiparticle random-phase approximation based on the relativistic Hartree-Bogoliubov model. Recent applications of energy density functionals with explicit density dependence of the meson-nucleon couplings are presented.

  7. Low-density microcellular foam and method of making same

    DOE Patents [OSTI]

    Rinde, James A.

    1977-01-01

    Low-density microcellular foam having a cell size of not greater than 2 .mu.m and method of making by dissolving cellulose acetate in an acetone-based solvent, gelling the solution in a water bath maintained at 0.degree.-10.degree. C for a selected period of time to allow impurities to diffuse out, freezing the gel, and then freeze-drying wherein water and solvents sublime and the gel structure solidifies into low-density microcellular foam. The foam has a density of 0.065 to 0.6.times.10.sup.3 kg/m.sup.3 and cell size of about 0.3 to 2 .mu.m. The small cell size foam is particularly applicable for encapsulation of laser targets.

  8. Method of making a cellulose acetate low density microcellular foam

    DOE Patents [OSTI]

    Rinde, James A.

    1978-01-01

    Low-density microcellular foam having a cell size of not greater than 2 .mu.m and method of making by dissolving cellulose acetate in an acetone-based solvent, gelling the solution in a water bath maintained at 0-10.degree. C for a selected period of time to allow impurities to diffuse out, freezing the gel, and then freeze-drying wherein water and solvents sublime and the gel structure solidifies into low-density microcellular foam. The foam has a density of 0.065 to 0.6.times.10.sup.3 kg/m.sup.3 and cell size of about 0.3 to 2 .mu.m. The small cell size foam is particularly adaptable for encapsulation of laser targets.

  9. Low density metal hydride foams

    DOE Patents [OSTI]

    Maienschein, Jon L.; Barry, Patrick E.

    1991-01-01

    Disclosed is a low density foam having a porosity of from 0 to 98% and a density less than about 0.67 gm/cc, prepared by heating a mixture of powered lithium hydride and beryllium hydride in an inert atmosphere at a temperature ranging from about 455 to about 490 K for a period of time sufficient to cause foaming of said mixture, and cooling the foam thus produced. Also disclosed is the process of making the foam.

  10. High Density Sensor Network Development | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    High Density Sensor Network Development

  11. High-density fluid compositions

    SciTech Connect (OSTI)

    Sanders, D.C.

    1981-09-29

    Clear, high-density fluids suitable for use as well completion, packing, and perforation media comprise aqueous solutions of zinc bromide and calcium bromide having densities lying in the range of about 14.5 up to about 18.0 pounds per gallon and measured PH's lying in the range of about 3.5 up to about 6.0. Optionally, such fluids may also comprise calcium chloride and/or a soluble film-forming amine-based corrosion inhibitor. Such fluids under conditions of ordinary use exhibit low corrosion rates and have crystallization points lying well below the range of temperatures under which they are used.

  12. Plasma digital density determining device

    DOE Patents [OSTI]

    Sprott, Julien C.; Lovell, Thomas W.; Holly, Donald J.

    1976-01-01

    The density of a decaying plasma in an electrically conducting enclosure is determined by applying an excitation to the cavity formed by the enclosure and counting digitally the number of resonant frequencies traversed by the combination of the cavity and the decaying plasma.

  13. Current Density Scaling in Electrochemical Flow Capacitors

    SciTech Connect (OSTI)

    Hoyt, NC; Wainright, JS; Savinell, RF

    2015-02-18

    Electrochemical flow capacitors (EFCs) are a recently developed energy storage technology. One of the principal performance metrics of an EFC is the steady-state electrical current density that it can accept or deliver. Numerical models exist to predict this performance for specific cases, but here we present a study of how the current varies with respect to the applied cell voltage, flow rate, cell dimensions, and slurry properties using scaling laws. The scaling relationships are confirmed by numerical simulations and then subsequently by comparison to results from symmetric cell EFC experiments. This modeling approach permits the delimitation of three distinct operational regimes dependent on the values of two nondimensional combinations of the pertinent variables (specifically, a capacitive Graetz number and a conductivity ratio). Lastly, the models and nondimensional numbers are used to provide design guidance in terms of criteria for proper EFC operation. (C) The Author(s) 2015. Published by ECS. This is an open access article distributed under the terms of the Creative Commons Attribution 4.0 License (CC BY, http://creativecommons.org/licenses/by/4.0/), which permits unrestricted reuse of the work in any medium, provided the original work is properly cited. All rights reserved.

  14. Statistical density modification using local pattern matching

    DOE Patents [OSTI]

    Terwilliger, Thomas C.

    2007-01-23

    A computer implemented method modifies an experimental electron density map. A set of selected known experimental and model electron density maps is provided and standard templates of electron density are created from the selected experimental and model electron density maps by clustering and averaging values of electron density in a spherical region about each point in a grid that defines each selected known experimental and model electron density maps. Histograms are also created from the selected experimental and model electron density maps that relate the value of electron density at the center of each of the spherical regions to a correlation coefficient of a density surrounding each corresponding grid point in each one of the standard templates. The standard templates and the histograms are applied to grid points on the experimental electron density map to form new estimates of electron density at each grid point in the experimental electron density map.

  15. ARM - Lesson Plans: Air Density and Temperature

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Teachers' Toolbox Lesson Plans Lesson Plans: Air Density and Temperature Objective The objective of this activity is to investigate the effect of temperature on the density of air. ...

  16. Building a Universal Nuclear Energy Density Functional

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Building a Universal Nuclear Energy Density Functional Building a Universal Nuclear Energy Density Functional VaryMatrix.png Collaboration with mathematicians and computational...

  17. Density variations and anomalies in palladium compacts

    SciTech Connect (OSTI)

    Back, D.; Jones, T.; Ransick, M.; Walburg, T.; Werkmeister, D.

    1992-05-14

    Low-density compacts of palladium powder have relative densities of about 30{plus minus}10% TD. The variations in density are of concern for operations such as chemical/hydrogen pump systems because heat, mass, and momentum transport properties can be affected. Variations in density result from the inherent nature and interacting forces of UASA compaction of powder in cylinders. In addition to these expected variations, discontinuous density anomalies, such as cracks or high density ridges, are also found. An anomaly of particular concern was found to resemble a steer's head.'' it is a symmetrical region of low density located at or near the center of a compact. Typically, this region is surrounded by a band of high density, compacted palladium that sometimes exceeds the density of the surrounding compact matrix by a factor of three. This report examines these density variations and anomalies both theoretically and empirically.

  18. Density variations and anomalies in palladium compacts

    SciTech Connect (OSTI)

    Back, D.; Jones, T.; Ransick, M.; Walburg, T.; Werkmeister, D.

    1992-05-14

    Low-density compacts of palladium powder have relative densities of about 30{plus_minus}10% TD. The variations in density are of concern for operations such as chemical/hydrogen pump systems because heat, mass, and momentum transport properties can be affected. Variations in density result from the inherent nature and interacting forces of UASA compaction of powder in cylinders. In addition to these expected variations, discontinuous density anomalies, such as cracks or high density ridges, are also found. An anomaly of particular concern was found to resemble a ``steer`s head.`` it is a symmetrical region of low density located at or near the center of a compact. Typically, this region is surrounded by a band of high density, compacted palladium that sometimes exceeds the density of the surrounding compact matrix by a factor of three. This report examines these density variations and anomalies both theoretically and empirically.

  19. Low density microcellular carbon foams and method of preparation

    DOE Patents [OSTI]

    Arnold, Jr., Charles; Aubert, James H.; Clough, Roger L.; Rand, Peter B.; Sylwester, Alan P.

    1989-01-01

    A low density, open-celled microcellular carbon foam is disclosed which is prepared by dissolving a carbonizable polymer or copolymer in a solvent, pouring the solution into a mold, cooling the solution, removing the solvent, and then carbonizing the polymer or copolymer in a high temperature oven to produce the foam. If desired, an additive can be introduced in order to produce a doped carbon foam, and the foams can be made isotropic by selection of a suitable solvent. The low density, microcellular foams produced by this process are particularly useful in the fabrication of inertial confinement fusion targets, but can also be used as catalysts, absorbents, and electrodes.

  20. Low density microcellular carbon foams and method of preparation

    DOE Patents [OSTI]

    Arnold, C. Jr.; Aubert, J.H.; Clough, R.L.; Rand, P.B.; Sylwester, A.P.

    1988-06-20

    A low density, open-celled microcellular carbon foam is disclosed which is prepared by dissolving a carbonizable polymer or copolymer in a solvent, pouring the solution into a mold, cooling the solution, removing the solvent, and then carbonizing the polymer or copolymer in a high temperature oven to produce the foam. If desired, an additive can be introduced in order to produce a doped carbon foam, and the foams can be made isotropic by selection of a suitable solvent. The low density, microcellular foams produced by this process are particularly useful in the fabrication of inertial confinement fusion targets, but can also be used as catalysts, absorbents, and electrodes.

  1. Probability distribution of the vacuum energy density

    SciTech Connect (OSTI)

    Duplancic, Goran; Stefancic, Hrvoje; Glavan, Drazen

    2010-12-15

    As the vacuum state of a quantum field is not an eigenstate of the Hamiltonian density, the vacuum energy density can be represented as a random variable. We present an analytical calculation of the probability distribution of the vacuum energy density for real and complex massless scalar fields in Minkowski space. The obtained probability distributions are broad and the vacuum expectation value of the Hamiltonian density is not fully representative of the vacuum energy density.

  2. DENSITY CONTROL IN A REACTOR

    DOE Patents [OSTI]

    Marshall, J. Jr.

    1961-10-24

    A reactor is described in which natural-uranium bodies are located in parallel channels which extend through the graphite mass in a regular lattice. The graphite mass has additional channels that are out of the lattice and contain no uranium. These additional channels decrease in number per unit volume of graphite from the center of the reactor to the exterior and have the effect of reducing the density of the graphite more at the center than at the exterior, thereby spreading neutron activity throughout the reactor. (AEC)

  3. Failure Mechanism of Fast-Charged Lithium Metal Batteries in Liquid Electrolyte

    SciTech Connect (OSTI)

    Lu, Dongping; Shao, Yuyan; Lozano, Terence J.; Bennett, Wendy D.; Graff, Gordon L.; Polzin, Bryant; Zhang, Jiguang; Engelhard, Mark H.; Saenz, Natalio T.; Henderson, Wesley A.; Bhattacharya, Priyanka; Liu, Jun; Xiao, Jie

    2015-02-01

    In recent years, lithium anode has re-attracted broad interest because of the necessity of employing lithium metal in the next-generation battery technologies such as lithium sulfur (Li-S) and lithium oxygen (Li-O2) batteries. Fast capacity degradation and safety issue associated with rechargeable lithium metal batteries have been reported, although the fundamental understanding on the failure mechanism of lithium metal at high charge rate is still under debate due to the complicated interfacial chemistry between lithium metal and electrolyte. Herein, we demonstrate that, at high current density, the quick growth of porous solid electrolyte interphase towards bulk lithium, instead of towards the separator, dramatically builds up the cell impedance that directly leads to the cell failure. Understanding the lithium metal failure mechanism is very critical to gauge the various approaches used to address the stability and safety issues associated with lithium metal anode. Otherwise, all cells will fail quickly at high rates before the observation of any positive effects that might be brought from adopting the new strategies to protect lithium.

  4. Rf Gun with High-Current Density Field Emission Cathode

    SciTech Connect (OSTI)

    Jay L. Hirshfield

    2005-12-19

    High current-density field emission from an array of carbon nanotubes, with field-emission-transistor control, and with secondary electron channel multiplication in a ceramic facing structure, have been combined in a cold cathode for rf guns and diode guns. Electrodynamic and space-charge flow simulations were conducted to specify the cathode configuration and range of emission current density from the field emission cold cathode. Design of this cathode has been made for installation and testing in an existing S-band 2-1/2 cell rf gun. With emission control and modulation, and with current density in the range of 0.1-1 kA/cm2, this cathode could provide performance and long-life not enjoyed by other currently-available cathodes

  5. Vehicle Technologies Office Merit Review 2015: High Energy Density Lithium Battery

    Broader source: Energy.gov [DOE]

    Presentation given by Binghamton U.-SUNY at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about high energy density...

  6. Oxides having high energy densities

    DOE Patents [OSTI]

    Ceder, Gerbrand; Kang, Kisuk

    2013-09-10

    Certain disclosed embodiments generally relate to oxide materials having relatively high energy and/or power densities. Various aspects of the embodiments are directed to oxide materials having a structure B.sub.i(M.sub.jY.sub.k)O.sub.2, for example, a structure Li.sub.j(Ni.sub.jY.sub.k)O.sub.2 such as Li(Ni.sub.0.5Mn.sub.0.5)O.sub.2. In this structure, Y represents one or more atoms, each independently selected from the group consisting of alkaline earth metals, transition metals, Group 14 elements, Group 15, or Group 16 elements. In some embodiments, such an oxide material may have an O3 crystal structure, and/or a layered structure such that the oxide comprises a plurality of first, repeating atomic planes comprising Li, and a plurality of second, repeating atomic planes comprising Ni and/or Y.

  7. Cell Analysis … High-Energy Density Cathodes and Anodes

    Broader source: Energy.gov [DOE]

    2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C.

  8. Development of Large Format Lithium Ion Cells with Higher Energy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Large Format Lithium Ion Cells with Higher Energy Density Exceeding 500WhL Development of Large Format Lithium Ion Cells with Higher Energy Density Exceeding 500WhL 2012 DOE ...

  9. Near-surface Density Currents Observed in the Southeast Pacific Stratocumulus-topped Marine Boundary Layer

    SciTech Connect (OSTI)

    Wilbanks, Matt C.; Yuter, S. E.; de Szoeke, S.; Brewer, W. A.; Miller, Matthew A.; Hall, Andrew M.; Burleyson, Casey D.

    2015-09-01

    Density currents (i.e. cold pools or outflows) beneath marine stratocumulus clouds are characterized using a 30-d data set of ship-based observations obtained during the 2008 Variability of American Monsoon Systems (VAMOS) Ocean-Cloud-Atmosphere-Land Study Regional Experiment (VOCALS-REx) in the southeast Pacific. An objective method identifies 71 density current fronts using an air density criterion and isolates each density current’s core (peak density) and tail (dissipating) zone. Compared to front and core zones, most density current tails exhibited weaker density gradients and wind anomalies elongated about the axis of the mean wind. The mean cloud-level advection relative to the surface layer wind (1.9 m s-1) nearly matches the mean density current propagation speed (1.8 m s-1). The similarity in speeds allows drizzle cells to deposit tails in their wakes. Based on high-resolution scanning Doppler lidar data, prefrontal updrafts had a mean intensity of 0.91 m s-1, reached an average altitude of 800 m, and were often surmounted by low-lying shelf clouds not connected to the overlying stratocumulus cloud. Nearly 90% of density currents were identified when C-band radar estimated 30-km diameter areal average rain rates exceeded 1 mm d-1. Rather than peaking when rain rates are highest overnight, density current occurrence peaks between 0600 and 0800 local solar time when enhanced local drizzle co-occurs with shallow subcloud dry and stable layers. The dry layers may contribute to density current formation by enhancing subcloud evaporation of drizzle. Density currents preferentially occur in regions of open cells but also occur in regions of closed cells.

  10. Aerodynamic Focusing Of High-Density Aerosols

    SciTech Connect (OSTI)

    Ruiz, D. E.; Fisch, Nathaniel

    2014-02-24

    High-density micron-sized particle aerosols might form the basis for a number of applications in which a material target with a particular shape might be quickly ionized to form a cylindrical or sheet shaped plasma. A simple experimental device was built in order to study the properties of high-density aerosol focusing for 1#22; m silica spheres. Preliminary results recover previous findings on aerodynamic focusing at low densities. At higher densities, it is demonstrated that the focusing properties change in a way which is consistent with a density dependent Stokes number.

  11. Vehicle Technologies Office Merit Review 2015: High Energy Lithium...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    lithium-sulfur cathodes. PDF icon es230cui2015o.pdf More Documents & Publications Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries Vehicle Technologies...

  12. Polyamidoamine Dendrimer-Based Binders for High-Loading Lithium...

    Office of Scientific and Technical Information (OSTI)

    Title: Polyamidoamine Dendrimer-Based Binders for High-Loading Lithium-Sulfur Battery Cathodes Lithium-sulfur (Li-S) batteries are regarded as one of the most promising candidates ...

  13. News Item

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Long Cycle-Life Lithium-Sulfur Battery Researchers at Berkeley Lab, including the Molecular Foundry, have demonstrated in the laboratory a lithium-sulfur (LiS) battery ...

  14. Quartz resonator fluid density and viscosity monitor

    DOE Patents [OSTI]

    Martin, Stephen J.; Wiczer, James J.; Cernosek, Richard W.; Frye, Gregory C.; Gebert, Charles T.; Casaus, Leonard; Mitchell, Mary A.

    1998-01-01

    A pair of thickness-shear mode resonators, one smooth and one with a textured surface, allows fluid density and viscosity to be independently resolved. A textured surface, either randomly rough or regularly patterned, leads to trapping of liquid at the device surface. The synchronous motion of this trapped liquid with the oscillating device surface allows the device to weigh the liquid; this leads to an additional response that depends on liquid density. This additional response enables a pair of devices, one smooth and one textured, to independently resolve liquid density and viscosity; the difference in responses determines the density while the smooth device determines the density-viscosity product, and thus, the pair determines both density and viscosity.

  15. High Density Fuel Development for Research Reactors

    SciTech Connect (OSTI)

    Daniel Wachs; Dennis Keiser; Mitchell Meyer; Douglas Burkes; Curtis Clark; Glenn Moore; Jan-Fong Jue; Totju Totev; Gerard Hofman; Tom Wiencek; Yeon So Kim; Jim Snelgrove

    2007-09-01

    An international effort to develop, qualify, and license high and very high density fuels has been underway for several years within the framework of multi-national RERTR programs. The current development status is the result of significant contributions from many laboratories, specifically CNEA in Argentina, AECL in Canada, CEA in France, TUM in Germany, KAERI in Korea, VNIIM, RDIPE, IPPE, NCCP and RIARR in Russia, INL, ANL and Y-12 in USA. These programs are mainly engaged with UMo dispersion fuels with densities from 6 to 8 gU/cm3 (high density fuel) and UMo monolithic fuel with density as high as 16 gU/cm3 (very high density fuel). This paper, mainly focused on the French & US programs, gives the status of high density UMo fuel development and perspectives on their qualification.

  16. The Quantum Energy Density: Improved E

    SciTech Connect (OSTI)

    Krogel, Jaron; Yu, Min; Kim, Jeongnim; Ceperley, David M.

    2013-01-01

    We establish a physically meaningful representation of a quantum energy density for use in Quantum Monte Carlo calculations. The energy density operator, dened in terms of Hamiltonian components and density operators, returns the correct Hamiltonian when integrated over a volume containing a cluster of particles. This property is demonstrated for a helium-neon \\gas," showing that atomic energies obtained from the energy density correspond to eigenvalues of isolated systems. The formation energies of defects or interfaces are typically calculated as total energy dierences. Using a model of delta-doped silicon (where dopant atoms form a thin plane) we show how interfacial energies can be calculated more eciently with the energy density, since the region of interest is small. We also demonstrate how the energy density correctly transitions to the bulk limit away from the interface where the correct energy is obtainable from a separate total energy calculation.

  17. Normal and abnormal evolution of argon metastable density in high-density plasmas

    SciTech Connect (OSTI)

    Seo, B. H.; Kim, J. H.; You, S. J.

    2015-05-15

    A controversial problem on the evolution of Ar metastable density as a function of electron density (increasing trend versus decreasing trend) was resolved by discovering the anomalous evolution of the argon metastable density with increasing electron density (discharge power), including both trends of the metastable density [Daltrini et al., Appl. Phys. Lett. 92, 061504 (2008)]. Later, by virtue of an adequate physical explanation based on a simple global model, both evolutions of the metastable density were comprehensively understood as part of the abnormal evolution occurring at low- and high-density regimes, respectively, and thus the physics behind the metastable evolution has seemed to be clearly disclosed. In this study, however, a remarkable result for the metastable density behavior with increasing electron density was observed: even in the same electron density regime, there are both normal and abnormal evolutions of metastable-state density with electron density depending on the measurement position: The metastable density increases with increasing electron density at a position far from the inductively coupled plasma antenna but decreases at a position close to the antenna. The effect of electron temperature, which is spatially nonuniform in the plasma, on the electron population and depopulation processes of Argon metastable atoms with increasing electron density is a clue to understanding the results. The calculated results of the global model, including multistep ionization for the argon metastable state and measured electron temperature, are in a good agreement with the experimental results.

  18. Method of synthesizing a low density material

    DOE Patents [OSTI]

    Lorensen, L.E.; Monaco, S.B.

    1987-02-27

    A novel method of synthesizing a polymeric material of low density of the order of 50mg/cc or less. Such a low density material has applications in many areas including laser target fabrication. The method comprises preparing a polymer blend of two incompatible polymers as a major and a minor phase by mixing them and extruding the mixture, and then selectively extracting the major component, to yield a fine, low density structure.

  19. Interaction of CuS and sulfur in Li-S battery system

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sun, Ke; Su, Dong; Zhang, Qing; Bock, David C.; Marschilok, Amy C.; Takeuchi, Kenneth J.; Takeuchi, Esther S.; Gan, Hong

    2015-10-27

    Lithium-Sulfur (Li-S) battery has been a subject of intensive research in recent years due to its potential to provide much higher energy density and lower cost than the current state of the art lithiumion battery technology. In this work, we have investigated Cupric Sulfide (CuS) as a capacitycontributing conductive additive to the sulfur electrode in a Li-S battery. Galvanostatic charge/discharge cycling has been used to compare the performance of both sulfur electrodes and S:CuS hybrid electrodes with various ratios. We found that the conductive CuS additive enhanced the utilization of the sulfur cathode under a 1C rate discharge. However, undermore » a C/10 discharge rate, S:CuS hybrid electrodes exhibited lower sulfur utilization in the first discharge and faster capacity decay in later cycles than a pure sulfur electrode due to the dissolution of CuS. The CuS dissolution is found to be the result of strong interaction between the soluble low order polysulfide Li2S3 and CuS. As a result, we identified the presence of conductive copper-containing sulfides at the cycled lithium anode surface, which may degrade the effectiveness of the passivation function of the solid-electrolyte-interphase (SEI) layer, accounting for the poor cycling performance of the S:CuS hybrid cells at low rate.« less

  20. Interaction of CuS and sulfur in Li-S battery system

    SciTech Connect (OSTI)

    Sun, Ke; Su, Dong; Zhang, Qing; Bock, David C.; Marschilok, Amy C.; Takeuchi, Kenneth J.; Takeuchi, Esther S.; Gan, Hong

    2015-10-27

    Lithium-Sulfur (Li-S) battery has been a subject of intensive research in recent years due to its potential to provide much higher energy density and lower cost than the current state of the art lithiumion battery technology. In this work, we have investigated Cupric Sulfide (CuS) as a capacitycontributing conductive additive to the sulfur electrode in a Li-S battery. Galvanostatic charge/discharge cycling has been used to compare the performance of both sulfur electrodes and S:CuS hybrid electrodes with various ratios. We found that the conductive CuS additive enhanced the utilization of the sulfur cathode under a 1C rate discharge. However, under a C/10 discharge rate, S:CuS hybrid electrodes exhibited lower sulfur utilization in the first discharge and faster capacity decay in later cycles than a pure sulfur electrode due to the dissolution of CuS. The CuS dissolution is found to be the result of strong interaction between the soluble low order polysulfide Li2S3 and CuS. As a result, we identified the presence of conductive copper-containing sulfides at the cycled lithium anode surface, which may degrade the effectiveness of the passivation function of the solid-electrolyte-interphase (SEI) layer, accounting for the poor cycling performance of the S:CuS hybrid cells at low rate.

  1. Building a Universal Nuclear Energy Density Functional

    SciTech Connect (OSTI)

    Bertulani, Carlos A.

    2014-09-10

    This grant had two components: Density functional theory and pairing and Nuclear reactions. This final report summarizes the activities for this SciDAC-2 project.

  2. 3-D capacitance density imaging system

    DOE Patents [OSTI]

    Fasching, G.E.

    1988-03-18

    A three-dimensional capacitance density imaging of a gasified bed or the like in a containment vessel is achieved using a plurality of electrodes provided circumferentially about the bed in levels and along the bed in channels. The electrodes are individually and selectively excited electrically at each level to produce a plurality of current flux field patterns generated in the bed at each level. The current flux field patterns are suitably sensed and a density pattern of the bed at each level determined. By combining the determined density patterns at each level, a three-dimensional density image of the bed is achieved. 7 figs.

  3. Calculating Atomic Number Densities for Uranium

    Energy Science and Technology Software Center (OSTI)

    1993-01-01

    Provides method to calculate atomic number densities of selected uranium compounds and hydrogenous moderators for use in nuclear criticality safety analyses at gaseous diffusion uranium enrichment facilities.

  4. Screening potential in high density plasmas

    SciTech Connect (OSTI)

    Amari, M.; Arranz, J. P.; Butaux, J.; Nguyen, H.

    1997-01-05

    On the basis of a two-ion center model, an accurate closed form of the screening potential is suggested for intermediate and high density plasmas.

  5. Universal Nuclear Energy Density Functional (Technical Report...

    Office of Scientific and Technical Information (OSTI)

    Country of Publication: United States Language: English Subject: 73 NUCLEAR PHYSICS AND RADIATION PHYSICS Nuclear structure; nuclear energy density functional Word Cloud ...

  6. Mini-review of Electron Density Visualization

    SciTech Connect (OSTI)

    Adler, Joan; Adler, Omri; Kreif, Meytal; Cohen, Or; Grosso, Bastien; Hashibon, Adham; Cooper, Valentino R

    2015-01-01

    We describe both educational and research oriented examples of electronic density visualization with AViz. Several detailed cases are presented and the procedures for their preparation are described.

  7. Uncertainty Quantification for Nuclear Density Functional Theory...

    Office of Scientific and Technical Information (OSTI)

    Uncertainty Quantification for Nuclear Density Functional Theory and Information Content of New Measurements Citation Details In-Document Search This content will become publicly...

  8. Chiral dynamics and peripheral transverse densities Granados...

    Office of Scientific and Technical Information (OSTI)

    dynamics and peripheral transverse densities Granados, Carlos G. Uppsala University (Sweden); Weiss, Christian JLAB, Newport News, VA (United States) 72 PHYSICS OF ELEMENTARY...

  9. High Energy Density Ultracapacitors | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    and Vehicle Technologies Program Annual Merit Review and Peer Evaluation es038smith2011p.pdf (1.95 MB) More Documents & Publications High Energy Density Ultracapacitors ...

  10. Direct hydrocarbon fuel cells

    DOE Patents [OSTI]

    Barnett, Scott A.; Lai, Tammy; Liu, Jiang

    2010-05-04

    The direct electrochemical oxidation of hydrocarbons in solid oxide fuel cells, to generate greater power densities at lower temperatures without carbon deposition. The performance obtained is comparable to that of fuel cells used for hydrogen, and is achieved by using novel anode composites at low operating temperatures. Such solid oxide fuel cells, regardless of fuel source or operation, can be configured advantageously using the structural geometries of this invention.

  11. Effects of the density of collision cascades: Separating contributions from dynamic annealing and energy spikes

    SciTech Connect (OSTI)

    Titov, A I; Karaseov, P A; Azarov, A Y; Kucheyev, S O

    2008-08-13

    We present a quantitative model for the efficiency of the molecular effect in damage buildup in semiconductors. Our model takes into account only one mechanism of the cascade density dependence: nonlinear energy spikes. In our three-dimensional analysis, the volume of each individual collision cascade is divided into small cubic cells, and the number of cells that have an average density of displacements above some threshold value is calculated. We assume that such cells experience a catastrophic crystalline-to-amorphous phase transition, while defects in the cells with lower displacement densities have perfect annihilation. For the two limiting cases of heavy (500 keV/atom {sup 209}Bi) and light (40 keV/atom {sup 14}N) ion bombardment of Si, theory predictions are in good agreement with experimental data for a threshold displacement density of 4.5 at.%. For intermediate density cascades produced by small 2.1 keV/amu PF{sub n} clusters, we show that dynamic annealing processes entirely dominate cascade density effects for PF{sub 2} ions, while energy spikes begin contributing in the case of PF{sub 4} cluster bombardment.

  12. Ultra-low density microcellular polymer foam and method

    DOE Patents [OSTI]

    Simandl, Ronald F.; Brown, John D.

    1996-01-01

    An ultra-low density, microcellular open-celled polymer foam and a method for making such foam. A polymer is dissolved in a heated solution consisting essentially of at least one solvent for the dissolution of the polymer in the heated solution and the phase inversion of the dissolved polymer to a liquid gel upon sufficient cooling of the heated solution. The heated solution is contained in a containment means provided with a nucleating promoting means having a relatively rough surface formed of fixed nucleating sites. The heated solution is cooled for a period of time sufficient to form a liquid gel of the polymer by phase inversion. From the gel, a porous foam having a density of less than about 12.0 mg/cm.sup.3 and open porosity provided by well interconnected strut morphology is formed.

  13. Ultra-low density microcellular polymer foam and method

    DOE Patents [OSTI]

    Simandl, R.F.; Brown, J.D.

    1996-03-19

    An ultra-low density, microcellular open-celled polymer foam and a method for making such foam are disclosed. A polymer is dissolved in a heated solution consisting essentially of at least one solvent for the dissolution of the polymer in the heated solution and the phase inversion of the dissolved polymer to a liquid gel upon sufficient cooling of the heated solution. The heated solution is contained in a containment means provided with a nucleating promoting means having a relatively rough surface formed of fixed nucleating sites. The heated solution is cooled for a period of time sufficient to form a liquid gel of the polymer by phase inversion. From the gel, a porous foam having a density of less than about 12.0 mg/cm{sup 3} and open porosity provided by well interconnected strut morphology is formed.

  14. High bandwidth vapor density diagnostic system

    DOE Patents [OSTI]

    Globig, Michael A.; Story, Thomas W.

    1992-01-01

    A high bandwidth vapor density diagnostic system for measuring the density of an atomic vapor during one or more photoionization events. The system translates the measurements from a low frequency region to a high frequency, relatively noise-free region in the spectrum to provide improved signal to noise ratio.

  15. High density laser-driven target

    DOE Patents [OSTI]

    Lindl, John D.

    1981-01-01

    A high density target for implosion by laser energy composed of a central quantity of fuel surrounded by a high-Z pusher shell with a low-Z ablator-pusher shell spaced therefrom forming a region filled with low-density material.

  16. Enhancing critical current density of cuprate superconductors

    DOE Patents [OSTI]

    Chaudhari, Praveen

    2015-06-16

    The present invention concerns the enhancement of critical current densities in cuprate superconductors. Such enhancement of critical current densities include using wave function symmetry and restricting movement of Abrikosov (A) vortices, Josephson (J) vortices, or Abrikosov-Josephson (A-J) vortices by using the half integer vortices associated with d-wave symmetry present in the grain boundary.

  17. Density functional theory for carbon dioxide crystal

    SciTech Connect (OSTI)

    Chang, Yiwen; Mi, Jianguo Zhong, Chongli

    2014-05-28

    We present a density functional approach to describe the solid?liquid phase transition, interfacial and crystal structure, and properties of polyatomic CO{sub 2}. Unlike previous phase field crystal model or density functional theory, which are derived from the second order direct correlation function, the present density functional approach is based on the fundamental measure theory for hard-sphere repulsion in solid. More importantly, the contributions of enthalpic interactions due to the dispersive attractions and of entropic interactions arising from the molecular architecture are integrated in the density functional model. Using the theoretical model, the predicted liquid and solid densities of CO{sub 2} at equilibrium triple point are in good agreement with the experimental values. Based on the structure of crystal-liquid interfaces in different planes, the corresponding interfacial tensions are predicted. Their respective accuracies need to be tested.

  18. Neutral depletion and the helicon density limit

    SciTech Connect (OSTI)

    Magee, R. M.; Galante, M. E.; Carr, J. Jr.; Lusk, G.; McCarren, D. W.; Scime, E. E.

    2013-12-15

    It is straightforward to create fully ionized plasmas with modest rf power in a helicon. It is difficult, however, to create plasmas with density >10{sup 20} m{sup ?3}, because neutral depletion leads to a lack of fuel. In order to address this density limit, we present fast (1 MHz), time-resolved measurements of the neutral density at and downstream from the rf antenna in krypton helicon plasmas. At the start of the discharge, the neutral density underneath the antenna is reduced to 1% of its initial value in 15 ?s. The ionization rate inferred from these data implies that the electron temperature near the antenna is much higher than the electron temperature measured downstream. Neutral density measurements made downstream from the antenna show much slower depletion, requiring 14 ms to decrease by a factor of 1/e. Furthermore, the downstream depletion appears to be due to neutral pumping rather than ionization.

  19. Core density turbulence in the HSX Stellarator

    SciTech Connect (OSTI)

    Deng, C. B.; Brower, D. L.; Anderson, D. T.; Anderson, F. S. B.; Briesemeister, Alexis R.; Likin, K. M.

    2015-10-23

    Broadband turbulent density fluctuations are explored in the helically symmetric stellarator experiment (HSX) by investigating changes related to plasma heating power and location. No fluctuation response is observed to occur with large changes in electron temperature and its gradient, thereby eliminating temperature gradient as a driving mechanism. Instead, measurements reveal that density turbulence varies inversely with electron density scale length. This response is consistent with density gradient drive as one might expect for trapped electron mode (TEM) turbulence. In general, the plasma stored energy and particle confinement are higher for discharges with reduced fluctuations in the plasma core. When the density fluctuation amplitude is reduced, increased plasma rotation is also evident suggesting a role is being played by intrinsic plasma flow.

  20. Ions in solution: Density corrected density functional theory (DC-DFT)

    SciTech Connect (OSTI)

    Kim, Min-Cheol; Sim, Eunji; Burke, Kieron

    2014-05-14

    Standard density functional approximations often give questionable results for odd-electron radical complexes, with the error typically attributed to self-interaction. In density corrected density functional theory (DC-DFT), certain classes of density functional theory calculations are significantly improved by using densities more accurate than the self-consistent densities. We discuss how to identify such cases, and how DC-DFT applies more generally. To illustrate, we calculate potential energy surfaces of HO·Cl{sup −} and HO·H{sub 2}O complexes using various common approximate functionals, with and without this density correction. Commonly used approximations yield wrongly shaped surfaces and/or incorrect minima when calculated self consistently, while yielding almost identical shapes and minima when density corrected. This improvement is retained even in the presence of implicit solvent.

  1. Method for providing a low density high strength polyurethane foam

    DOE Patents [OSTI]

    Whinnery, Jr., Leroy L.; Goods, Steven H.; Skala, Dawn M.; Henderson, Craig C.; Keifer, Patrick N.

    2013-06-18

    Disclosed is a method for making a polyurethane closed-cell foam material exhibiting a bulk density below 4 lbs/ft.sup.3 and high strength. The present embodiment uses the reaction product of a modified MDI and a sucrose/glycerine based polyether polyol resin wherein a small measured quantity of the polyol resin is "pre-reacted" with a larger quantity of the isocyanate in a defined ratio such that when the necessary remaining quantity of the polyol resin is added to the "pre-reacted" resin together with a tertiary amine catalyst and water as a blowing agent, the polymerization proceeds slowly enough to provide a stable foam body.

  2. Mixing device for materials with large density differences

    DOE Patents [OSTI]

    Gregg, D.W.

    1994-08-16

    An auger-tube pump mixing device is disclosed for mixing materials with large density differences while maintaining low stirring RPM and low power consumption. The mixing device minimizes the formation of vortexes and minimizes the incorporation of small bubbles in the liquid during mixing. By avoiding the creation of a vortex the device provides efficient stirring of full containers without spillage over the edge. Also, the device solves the problem of effective mixing in vessels where the liquid height is large compared to the diameter. Because of the gentle stirring or mixing by the device, it has application for biomedical uses where cell damage is to be avoided. 2 figs.

  3. Mixing device for materials with large density differences

    DOE Patents [OSTI]

    Gregg, David W.

    1994-01-01

    An auger-tube pump mixing device for mixing materials with large density differences while maintaining low stirring RPM and low power consumption. The mixing device minimizes the formation of vortexes and minimizes the incorporation of small bubbles in the liquid during mixing. By avoiding the creation of a vortex the device provides efficient stirring of full containers without spillage over the edge. Also, the device solves the problem of effective mixing in vessels where the liquid height is large compared to the diameter. Because of the gentle stirring or mixing by the device, it has application for biomedical uses where cell damage is to be avoided.

  4. Periodic subsystem density-functional theory

    SciTech Connect (OSTI)

    Genova, Alessandro; Pavanello, Michele; Ceresoli, Davide

    2014-11-07

    By partitioning the electron density into subsystem contributions, the Frozen Density Embedding (FDE) formulation of subsystem Density Functional Theory (DFT) has recently emerged as a powerful tool for reducing the computational scaling of Kohn–Sham DFT. To date, however, FDE has been employed to molecular systems only. Periodic systems, such as metals, semiconductors, and other crystalline solids have been outside the applicability of FDE, mostly because of the lack of a periodic FDE implementation. To fill this gap, in this work we aim at extending FDE to treat subsystems of molecular and periodic character. This goal is achieved by a dual approach. On one side, the development of a theoretical framework for periodic subsystem DFT. On the other, the realization of the method into a parallel computer code. We find that periodic FDE is capable of reproducing total electron densities and (to a lesser extent) also interaction energies of molecular systems weakly interacting with metallic surfaces. In the pilot calculations considered, we find that FDE fails in those cases where there is appreciable density overlap between the subsystems. Conversely, we find FDE to be in semiquantitative agreement with Kohn–Sham DFT when the inter-subsystem density overlap is low. We also conclude that to make FDE a suitable method for describing molecular adsorption at surfaces, kinetic energy density functionals that go beyond the GGA level must be employed.

  5. Chiral dynamics and peripheral transverse densities

    SciTech Connect (OSTI)

    Granados, Carlos G.; Weiss, Christian

    2014-01-01

    In the partonic (or light-front) description of relativistic systems the electromagnetic form factors are expressed in terms of frame-independent charge and magnetization densities in transverse space. This formulation allows one to identify the chiral components of nucleon structure as the peripheral densities at transverse distances b = O(M{sub {pi}}{sup -1}) and compute them in a parametrically controlled manner. A dispersion relation connects the large-distance behavior of the transverse charge and magnetization densities to the spectral functions of the Dirac and Pauli form factors near the two--pion threshold at timelike t = 4 M{ sub {pi}}{sup 2}, which can be computed in relativistic chiral effective field theory. Using the leading-order approximation we (a) derive the asymptotic behavior (Yukawa tail) of the isovector transverse densities in the "chiral" region b = O(M{sub {pi}}{sup -1}) and the "molecular" region b = O(M{sub N}{sup 2}/M{sub {pi}}{sup 3}); (b) perform the heavy-baryon expansion of the transverse densities; (c) explain the relative magnitude of the peripheral charge and magnetization densities in a simple mechanical picture; (d) include Delta isobar intermediate states and study the peripheral transverse densities in the large-N{ sub c} limit of QCD; (e) quantify the region of transverse distances where the chiral components of the densities are numerically dominant; (f) calculate the chiral divergences of the b{sup 2}-weighted moments of the isovector transverse densities (charge and anomalous magnetic radii) in the limit M{sub {pi}} -> 0 and determine their spatial support. Our approach provides a concise formulation of the spatial structure of the nucleon's chiral component and offers new insights into basic properties of the chiral expansion. It relates the information extracted from low-t elastic form factors to the generalized parton distributions probed in peripheral high-energy scattering processes.

  6. Silicon Cells | Open Energy Information

    Open Energy Info (EERE)

    a low cost method of processing silicon to produce a new generation of high energy density batteries. References: Silicon Cells1 This article is a stub. You can help OpenEI...

  7. Density controlled carbon nanotube array electrodes

    DOE Patents [OSTI]

    Ren, Zhifeng F.; Tu, Yi

    2008-12-16

    CNT materials comprising aligned carbon nanotubes (CNTs) with pre-determined site densities, catalyst substrate materials for obtaining them and methods for forming aligned CNTs with controllable densities on such catalyst substrate materials are described. The fabrication of films comprising site-density controlled vertically aligned CNT arrays of the invention with variable field emission characteristics, whereby the field emission properties of the films are controlled by independently varying the length of CNTs in the aligned array within the film or by independently varying inter-tubule spacing of the CNTs within the array (site density) are disclosed. The fabrication of microelectrode arrays (MEAs) formed utilizing the carbon nanotube material of the invention is also described.

  8. Separation of carbon nanotubes in density gradients

    DOE Patents [OSTI]

    Hersam, Mark C.; Stupp, Samuel I.; Arnold, Michael S.

    2012-02-07

    The separation of single-walled carbon nanotubes (SWNTs), by chirality and/or diameter, using centrifugation of compositions of SWNTs in and surface active components in density gradient media.

  9. Separation of carbon nanotubes in density gradients

    DOE Patents [OSTI]

    Hersam, Mark C.; Stupp, Samuel I.; Arnold, Michael S.

    2010-02-16

    The separation of single-walled carbon nanotubes (SWNTs), by chirality and/or diameter, using centrifugation of compositions of SWNTs in and surface active components in density gradient media.

  10. High density load bearing insulation peg

    DOE Patents [OSTI]

    Nowobilski, Jeffert J.; Owens, William J.

    1985-01-01

    A high density peg which can support a large load and exhibits excellent thermal resistance produced by a method wherein the peg is made in compliance with specified conditions of time, temperature and pressure.

  11. High density load bearing insulation peg

    DOE Patents [OSTI]

    Nowobilski, J.J.; Owens, W.J.

    1985-01-29

    A high density peg is disclosed which can support a large load and exhibits excellent thermal resistance produced by a method wherein the peg is made in compliance with specified conditions of time, temperature and pressure. 4 figs.

  12. Spacetime Average Density (SAD) cosmological measures

    SciTech Connect (OSTI)

    Page, Don N.

    2014-11-01

    The measure problem of cosmology is how to obtain normalized probabilities of observations from the quantum state of the universe. This is particularly a problem when eternal inflation leads to a universe of unbounded size so that there are apparently infinitely many realizations or occurrences of observations of each of many different kinds or types, making the ratios ambiguous. There is also the danger of domination by Boltzmann Brains. Here two new Spacetime Average Density (SAD) measures are proposed, Maximal Average Density (MAD) and Biased Average Density (BAD), for getting a finite number of observation occurrences by using properties of the Spacetime Average Density (SAD) of observation occurrences to restrict to finite regions of spacetimes that have a preferred beginning or bounce hypersurface. These measures avoid Boltzmann brain domination and appear to give results consistent with other observations that are problematic for other widely used measures, such as the observation of a positive cosmological constant.

  13. Chiral dynamics and peripheral transverse densities (Journal...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Chiral dynamics and peripheral transverse densities Citation Details ... Report Number(s): JLAB-THY--13-1763; DOEOR--23177-2641 Journal ID: ISSN 1029-8479; TRN: ...

  14. Shock compression of low-density foams

    SciTech Connect (OSTI)

    Holmes, N.C.

    1993-07-01

    Shock compression of very low density micro-cellular materials allows entirely new regimes of hot fluid states to be investigated experimentally. Using a two-stage light-gas gun to generate strong shocks, temperatures of several eV are readily achieved at densities of roughly 0.5--1 g/cm{sup 3} in large, uniform volumes. The conditions in these hot, expanded fluids are readily found using the Hugoniot jump conditions. We will briefly describe the basic methodology for sample preparation and experimental measurement of shock velocities. We present data for several materials over a range of initial densities. This paper will explore the applications of these methods for investigations of equations of state and phase diagrams, spectroscopy, and plasma physics. Finally, we discus the need for future work on these and related low-density materials.

  15. Communication: Embedded fragment stochastic density functional theory

    SciTech Connect (OSTI)

    Neuhauser, Daniel; Baer, Roi; Rabani, Eran

    2014-07-28

    We develop a method in which the electronic densities of small fragments determined by Kohn-Sham density functional theory (DFT) are embedded using stochastic DFT to form the exact density of the full system. The new method preserves the scaling and the simplicity of the stochastic DFT but cures the slow convergence that occurs when weakly coupled subsystems are treated. It overcomes the spurious charge fluctuations that impair the applications of the original stochastic DFT approach. We demonstrate the new approach on a fullerene dimer and on clusters of water molecules and show that the density of states and the total energy can be accurately described with a relatively small number of stochastic orbitals.

  16. Breast Density and Cancer | GE Global Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Breast Cancer Awareness Series: Understanding Breast Density Click to email this to a friend (Opens in new window) Share on Facebook (Opens in new window) Click to share (Opens in ...

  17. High Energy Density Ultracapacitors | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. esp22smith.pdf (1.09 MB) More Documents & Publications High Energy Density Ultracapacitors High ...

  18. High-Energy-Density Plasmas, Fluids

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    High-Energy-Density Plasmas, Fluids High-Energy-Density Plasmas, Fluids National security depends on science and technology. The United States relies on Los Alamos National Laboratory for the best of both. No place on Earth pursues a broader array of world-class scientific endeavors. TRIDENT target chamber Sasi Palaniyappan, right, and Rahul Shah left inside a target chamber where the TRIDENT short pulse laser is aimed at a very thin diamond- foil target, a fraction of a micrometer thick. The

  19. Stable laser–plasma accelerators at low densities

    SciTech Connect (OSTI)

    Li, Song; Hafz, Nasr A. M. Mirzaie, Mohammad; Ge, Xulei; Sokollik, Thomas; Chen, Min; Sheng, Zhengming; Zhang, Jie

    2014-07-28

    We report stable laser wakefield acceleration using 17–50 TW laser pulses interacting with 4 mm-long helium gas jet. The initial laser spot size was relatively large (28 μm) and the plasma densities were 0.48–2.0 × 10{sup 19 }cm{sup −3}. High-quality 100–MeV electron beams were generated at the plasma density of 7.5 × 10{sup 18 }cm{sup −3}, at which the beam parameters (pointing angle, energy spectrum, charge, and divergence angle) were measured and stabilized. At higher densities, filamentation instability of the laser-plasma interaction was observed and it has led to multiple wakefield accelerated electron beams. The experimental results are supported by 2D particle-in-cell simulations. The achievement presented here is an important step toward the use of laser-driven accelerators in real applications.

  20. High Power Density Integrated Traction Machine Drive

    Broader source: Energy.gov [DOE]

    2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation

  1. Scattering of electromagnetic waves by vortex density structures associated with interchange instability: Analytical and large scale plasma simulation results

    SciTech Connect (OSTI)

    Sotnikov, V.; Kim, T.; Lundberg, J.; Paraschiv, I.; Mehlhorn, T. A.

    2014-05-15

    The presence of plasma turbulence can strongly influence propagation properties of electromagnetic signals used for surveillance and communication. In particular, we are interested in the generation of low frequency plasma density irregularities in the form of coherent vortex structures. Interchange or flute type density irregularities in magnetized plasma are associated with Rayleigh-Taylor type instability. These types of density irregularities play an important role in refraction and scattering of high frequency electromagnetic signals propagating in the earth ionosphere, in high energy density physics, and in many other applications. We will discuss scattering of high frequency electromagnetic waves on low frequency density irregularities due to the presence of vortex density structures associated with interchange instability. We will also present particle-in-cell simulation results of electromagnetic scattering on vortex type density structures using the large scale plasma code LSP and compare them with analytical results.

  2. Orbital-optimized density cumulant functional theory

    SciTech Connect (OSTI)

    Sokolov, Alexander Yu. Schaefer, Henry F.

    2013-11-28

    In density cumulant functional theory (DCFT) the electronic energy is evaluated from the one-particle density matrix and two-particle density cumulant, circumventing the computation of the wavefunction. To achieve this, the one-particle density matrix is decomposed exactly into the mean-field (idempotent) and correlation components. While the latter can be entirely derived from the density cumulant, the former must be obtained by choosing a specific set of orbitals. In the original DCFT formulation [W. Kutzelnigg, J. Chem. Phys. 125, 171101 (2006)] the orbitals were determined by diagonalizing the effective Fock operator, which introduces partial orbital relaxation. Here we present a new orbital-optimized formulation of DCFT where the energy is variationally minimized with respect to orbital rotations. This introduces important energy contributions and significantly improves the description of the dynamic correlation. In addition, it greatly simplifies the computation of analytic gradients, for which expressions are also presented. We offer a perturbative analysis of the new orbital stationarity conditions and benchmark their performance for a variety of chemical systems.

  3. Statistical approach to nuclear level density

    SciTech Connect (OSTI)

    Sen'kov, R. A.; Horoi, M.; Zelevinsky, V. G.

    2014-10-15

    We discuss the level density in a finite many-body system with strong interaction between the constituents. Our primary object of applications is the atomic nucleus but the same techniques can be applied to other mesoscopic systems. We calculate and compare nuclear level densities for given quantum numbers obtained by different methods, such as nuclear shell model (the most successful microscopic approach), our main instrument - moments method (statistical approach), and Fermi-gas model; the calculation with the moments method can use any shell-model Hamiltonian excluding the spurious states of the center-of-mass motion. Our goal is to investigate statistical properties of nuclear level density, define its phenomenological parameters, and offer an affordable and reliable way of calculation.

  4. Fabrication of low density ceramic material

    DOE Patents [OSTI]

    Meek, T.T.; Blake, R.D.; Sheinberg, H.

    1985-01-01

    A precursor mixture and a method of making a low-density ceramic structural material are disclosed. The precursor mixture includes hollow microballoons, typically made of glass, together with a cementing agent capable of being cured by microwave irradiation. A preferred cementing agent is liquid hydrated potassium silicate, which is mixed with the glass microballoons to form a slurry. Upon irradiation the potassium silicate is dehydrated to form a solid porous matrix in which the microballoons are evenly distributed. Ground glass or other filling agents may be included in the slurry to enhance the properties of the final product. Low-density structural ceramics having densities on the order of 0.1 to 0.3 are obtained.

  5. NEUTRON DENSITY CONTROL IN A NEUTRONIC REACTOR

    DOE Patents [OSTI]

    Young, G.J.

    1959-06-30

    The method and means for controlling the neutron density in a nuclear reactor is described. It describes the method and means for flattening the neutron density distribution curve across the reactor by spacing the absorbing control members to varying depths in the central region closer to the center than to the periphery of the active portion of the reactor to provide a smaller neutron reproduction ratio in the region wherein the members are inserted, than in the remainder of the reactor thereby increasing the over-all potential power output.

  6. Durable high-density data storage

    SciTech Connect (OSTI)

    Stutz, R.A.; Lamartine, B.C.

    1996-09-01

    This paper will discuss the Focus Ion Beam (FIB) milling process, media life considerations, and methods of reading the micromilled data. The FIB process for data storage provides a new non-magnetic storage method for archiving large amounts of data. The process stores data on robust materials such as steel, silicon, and gold coated silicon. The storage process was developed to provide a method to insure the long term storage life of data. We estimate the useful life of data written on silicon or gold coated silicon to be a few thousand years. The process uses an ion beam to carve material from the surface much like stone cutting. The deeper information is carved into the media the longer the expected life of the information. The process can read information in three formats: (1) binary at densities of 3.5 Gbits/cm{sup 2}, (2) alphanumeric at optical or non-optical density, and (3) graphical at optical and non-optical density. The formats can be mixed on the same media; and thus it is possible to record, in a human readable format, instructions that can be read using an optical microscope. These instructions provide guidance on reading the higher density information.

  7. Density waves in the Calogero model - revisited

    SciTech Connect (OSTI)

    Bardek, V. Feinberg, J. Meljanac, S.

    2010-03-15

    The Calogero model bears, in the continuum limit, collective excitations in the form of density waves and solitary modulations of the density of particles. This sector of the spectrum of the model was investigated, mostly within the framework of collective-field theory, by several authors, over the past 15 years or so. In this work we shall concentrate on periodic solutions of the collective BPS-equation (also known as 'finite amplitude density waves'), as well as on periodic solutions of the full static variational equations which vanish periodically (also known as 'large amplitude density waves'). While these solutions are not new, we feel that our analysis and presentation add to the existing literature, as we explain in the text. In addition, we show that these solutions also occur in a certain two-family generalization of the Calogero model, at special points in parameter space. A compendium of useful identities associated with Hilbert transforms, including our own proofs of these identities, appears in Appendix A. In Appendix B we also elucidate in the present paper some fine points having to do with manipulating Hilbert-transforms, which appear ubiquitously in the collective field formalism. Finally, in order to make this paper self-contained, we briefly summarize in Appendix C basic facts about the collective field formulation of the Calogero model.

  8. Vapor-liquid equilibria and densities for the system butane + hexacontane

    SciTech Connect (OSTI)

    Nieuwoudt, I.

    1996-09-01

    Liquid and vapor phase compositions and densities have been measured with a variable volume cell for the binary system butane + hexacontane (n-C{sub 60}H{sub 122}). Data sets at 433.15 K, 438.15 K, and 453.15 K are presented and include measurements in the mixture critical region.

  9. ?Linear Gas Jet with Tailored Density Profile"

    SciTech Connect (OSTI)

    KRISHNAN, Mahadevan

    2012-12-10

    Supersonic, highly collimated gas jets and gas-filled capillary discharge waveguides are two primary targets of choice for Laser Plasma Accelerators (LPA) . Present gas jets have lengths of only 2-4 mm at densities of 1-4E19 cm-3, sufficient for self trapping and electron acceleration to energies up to ~150 MeV. Capillary structures 3 cm long have been used to accelerate beams up to 1 GeV. Capillary discharges used in LPAs serve to guide the pump laser and optimize the energy gain. A wall-stabilized capillary discharge provides a transverse profile across the channel that helps guide the laser and combat diffraction. Gas injection via a fast nozzle at one end provides some longitudinal density control, to improve the coupling. Gas jets with uniform or controlled density profiles may be used to control electron bunch injection and are being integrated into capillary experiments to add tuning of density. The gas jet for electron injection has not yet been optimized. Our Ph-I results have provided the LPA community with an alternative path to realizing a 2-3GeV electron bunch using just a gas jet. For example, our slit/blade combination gives a 15-20mm long acceleration path with tunable density profile, serving as an alternative to a 20-mm long capillary discharge with gas injection at one end. In Ph-II, we will extend these results to longer nozzles, to see whether we can synthesize 30 or 40-mm long plasma channels for LPAs.

  10. Probability density function method for variable-density pressure-gradient-driven turbulence and mixing

    SciTech Connect (OSTI)

    Bakosi, Jozsef; Ristorcelli, Raymond J

    2010-01-01

    Probability density function (PDF) methods are extended to variable-density pressure-gradient-driven turbulence. We apply the new method to compute the joint PDF of density and velocity in a non-premixed binary mixture of different-density molecularly mixing fluids under gravity. The full time-evolution of the joint PDF is captured in the highly non-equilibrium flow: starting from a quiescent state, transitioning to fully developed turbulence and finally dissipated by molecular diffusion. High-Atwood-number effects (as distinguished from the Boussinesq case) are accounted for: both hydrodynamic turbulence and material mixing are treated at arbitrary density ratios, with the specific volume, mass flux and all their correlations in closed form. An extension of the generalized Langevin model, originally developed for the Lagrangian fluid particle velocity in constant-density shear-driven turbulence, is constructed for variable-density pressure-gradient-driven flows. The persistent small-scale anisotropy, a fundamentally 'non-Kolmogorovian' feature of flows under external acceleration forces, is captured by a tensorial diffusion term based on the external body force. The material mixing model for the fluid density, an active scalar, is developed based on the beta distribution. The beta-PDF is shown to be capable of capturing the mixing asymmetry and that it can accurately represent the density through transition, in fully developed turbulence and in the decay process. The joint model for hydrodynamics and active material mixing yields a time-accurate evolution of the turbulent kinetic energy and Reynolds stress anisotropy without resorting to gradient diffusion hypotheses, and represents the mixing state by the density PDF itself, eliminating the need for dubious mixing measures. Direct numerical simulations of the homogeneous Rayleigh-Taylor instability are used for model validation.

  11. High-efficiency acceleration in the laser wakefield by a linearly increasing plasma density

    SciTech Connect (OSTI)

    Dong, Kegong; Wu, Yuchi; Zhu, Bin; Zhang, Zhimeng; Zhao, Zongqing; Zhou, Weimin; Hong, Wei; Cao, Leifeng; Gu, Yuqiu

    2014-12-15

    The acceleration length and the peak energy of the electron beam are limited by the dephasing effect in the laser wakefield acceleration with uniform plasma density. Based on 2D-3V particle in cell simulations, the effects of a linearly increasing plasma density on the electron acceleration are investigated broadly. Comparing with the uniform plasma density, because of the prolongation of the acceleration length and the gradually increasing accelerating field due to the increasing plasma density, the electron beam energy is twice higher in moderate nonlinear wakefield regime. Because of the lower plasma density, the linearly increasing plasma density can also avoid the dark current caused by additional injection. At the optimal acceleration length, the electron energy can be increased from 350 MeV (uniform) to 760 MeV (linearly increasing) with the energy spread of 1.8%, the beam duration is 5 fs and the beam waist is 1.25 μm. This linearly increasing plasma density distribution can be achieved by a capillary with special gas-filled structure, and is much more suitable for experiment.

  12. Distribution of Radiation Density in a Homogeneous Cloudy Laye

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Radiation Density in a Homogeneous Cloudy Layer S. V. Dvoryashin, K. A. Shukorov, A. H. ... method) allowing calculating radiation density in homogeneous and non-uniform ...

  13. Real-Time Simultaneous Measurements of Size, Density, and Composition...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Simultaneous Measurements of Size, Density, and Composition of Single Ultrafine Diesel Tailpipe Particles Real-Time Simultaneous Measurements of Size, Density, and Composition of ...

  14. Density Functional Theory Approach to Nuclear Fission (Conference...

    Office of Scientific and Technical Information (OSTI)

    Density Functional Theory Approach to Nuclear Fission Citation Details In-Document Search Title: Density Functional Theory Approach to Nuclear Fission You are accessing a document ...

  15. Density Functional Theory Study of Surface Carbonate Formation...

    Office of Scientific and Technical Information (OSTI)

    Density Functional Theory Study of Surface Carbonate Formation on BaO(001) Citation Details In-Document Search Title: Density Functional Theory Study of Surface Carbonate Formation ...

  16. Ultra Low Density Amorphous Shape Memory polymer Foams. (Conference...

    Office of Scientific and Technical Information (OSTI)

    Ultra Low Density Amorphous Shape Memory polymer Foams. Citation Details In-Document Search Title: Ultra Low Density Amorphous Shape Memory polymer Foams. You are accessing a ...

  17. Time Adaptive Conditional Kernel Density Estimation for Wind...

    Office of Scientific and Technical Information (OSTI)

    Time Adaptive Conditional Kernel Density Estimation for Wind Power Forecasting Citation Details In-Document Search Title: Time Adaptive Conditional Kernel Density Estimation for ...

  18. Combinatorial nuclear level-density model (Journal Article) ...

    Office of Scientific and Technical Information (OSTI)

    Combinatorial nuclear level-density model Citation Details In-Document Search Title: Combinatorial nuclear level-density model You are accessing a document from the Department ...

  19. Engineering Density of States of Earth Abundant Semiconductors...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Density of States of Earth Abundant Semiconductors for Enhanced Thermoelectric Power Factor Engineering Density of States of Earth Abundant Semiconductors for Enhanced ...

  20. Error Analysis in Nuclear Density Functional Theory (Journal...

    Office of Scientific and Technical Information (OSTI)

    Error Analysis in Nuclear Density Functional Theory Citation Details In-Document Search Title: Error Analysis in Nuclear Density Functional Theory Authors: Schunck, N ; McDonnell,...

  1. Error Analysis in Nuclear Density Functional Theory (Journal...

    Office of Scientific and Technical Information (OSTI)

    Error Analysis in Nuclear Density Functional Theory Citation Details In-Document Search Title: Error Analysis in Nuclear Density Functional Theory You are accessing a document...

  2. XUV Absorption by Solid Density Aluminum (Journal Article) |...

    Office of Scientific and Technical Information (OSTI)

    XUV Absorption by Solid Density Aluminum Citation Details In-Document Search Title: XUV Absorption by Solid Density Aluminum An inverse bremsstrahlung model for plasmas and simple ...

  3. Mitigating Breakdown in High Energy Density Perovskite Polymer...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Mitigating Breakdown in High Energy Density Perovskite Polymer Nanocomposite Capacitors Mitigating Breakdown in High Energy Density Perovskite Polymer Nanocomposite Capacitors 2012 ...

  4. Controlling the Actuation Rate of Low Density Shape Memory Polymer...

    Office of Scientific and Technical Information (OSTI)

    Density Shape Memory Polymer Foams in Water Citation Details In-Document Search Title: Controlling the Actuation Rate of Low Density Shape Memory Polymer Foams in Water Authors: ...

  5. Using Radio Waves to Control Fusion Plasma Density

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Using Radio Waves to Control Fusion Plasma Density Using Radio Waves to Control Fusion Plasma Density Simulations Run at NERSC Support Fusion Experiments at MIT, General Atomics ...

  6. Pairing Nambu-Goldstone Modes within Nuclear Density Functional...

    Office of Scientific and Technical Information (OSTI)

    Pairing Nambu-Goldstone Modes within Nuclear Density Functional Theory Citation Details ... Title: Pairing Nambu-Goldstone Modes within Nuclear Density Functional Theory Authors: ...

  7. Accuracy of density functionals for molecular electronics: The...

    Office of Scientific and Technical Information (OSTI)

    Accuracy of density functionals for molecular electronics: The Anderson junction Title: Accuracy of density functionals for molecular electronics: The Anderson junction Authors: ...

  8. Molecular adsorption on metal surfaces with van der Waals density...

    Office of Scientific and Technical Information (OSTI)

    Molecular adsorption on metal surfaces with van der Waals density functionals Title: Molecular adsorption on metal surfaces with van der Waals density functionals Authors: Li, Guo ...

  9. Low density biodegradable shape memory polyurethane foams for...

    Office of Scientific and Technical Information (OSTI)

    Low density biodegradable shape memory polyurethane foams for embolic biomedical applications Citation Details In-Document Search Title: Low density biodegradable shape memory...

  10. Basic Research Needs for High Energy Density Laboratory Physics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    National Laboratory. Basic Research Needs for High Energy Density Laboratory Physics Report of the Workshop on High Energy Density Laboratory Physics Research Needs November ...

  11. High Energy Density Laboratory Plasmas Program | National Nuclear...

    National Nuclear Security Administration (NNSA)

    Jobs Apply for Our Jobs Our Jobs Working at NNSA Blog Home High Energy Density Laboratory Plasmas Program High Energy Density Laboratory Plasmas Program NNSA invests in next ...

  12. Probability Density Function Method for Langevin Equations with...

    Office of Scientific and Technical Information (OSTI)

    Probability Density Function Method for Langevin Equations with Colored Noise Citation Details In-Document Search Title: Probability Density Function Method for Langevin Equations ...

  13. Stabilizing laser energy density on a target during pulsed laser...

    Office of Scientific and Technical Information (OSTI)

    Patent: Stabilizing laser energy density on a target during pulsed laser deposition of thin films Citation Details In-Document Search Title: Stabilizing laser energy density on a ...

  14. Research on Factors Relating to Density and Climate Change |...

    Open Energy Info (EERE)

    on Factors Relating to Density and Climate Change Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Research on Factors Relating to Density and Climate Change Agency...

  15. A New Mechanism of Charge Density Wave Discovered in Transition...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    8 A New Mechanism of Charge Density Wave Discovered in Transition Metal Dichalcogenides Charge density waves (CDW) are a type of coupled electronic-lattice instability found in...

  16. The problem of the universal density functional and the density matrix functional theory

    SciTech Connect (OSTI)

    Bobrov, V. B. Trigger, S. A.

    2013-04-15

    The analysis in this paper shows that the Hohenberg-Kohn theorem is the constellation of two statements: (i) the mathematically rigorous Hohenberg-Kohn lemma, which demonstrates that the same ground-state density cannot correspond to two different potentials of an external field, and (ii) the hypothesis of the existence of the universal density functional. Based on the obtained explicit expression for the nonrel-ativistic particle energy in a local external field, we prove that the energy of the system of more than two non-interacting electrons cannot be a functional of the inhomogeneous density. This result is generalized to the system of interacting electrons. It means that the Hohenberg-Kohn lemma cannot provide justification of the universal density functional for fermions. At the same time, statements of the density functional theory remain valid when considering any number of noninteracting ground-state bosons due to the Bose condensation effect. In the framework of the density matrix functional theory, the hypothesis of the existence of the universal density matrix functional corresponds to the cases of noninteracting particles and to interaction in the Hartree-Fock approximation.

  17. DOE Technical Targets for Fuel Cell Systems for Portable Power...

    Energy Savers [EERE]

    Portable Power and Auxiliary Power Applications DOE Technical Targets for Fuel Cell Systems ... specific energy and energy density. d Cost includes material and labor costs ...

  18. Ultra-high density diffraction grating

    DOE Patents [OSTI]

    Padmore, Howard A.; Voronov, Dmytro L.; Cambie, Rossana; Yashchuk, Valeriy V.; Gullikson, Eric M.

    2012-12-11

    A diffraction grating structure having ultra-high density of grooves comprises an echellette substrate having periodically repeating recessed features, and a multi-layer stack of materials disposed on the echellette substrate. The surface of the diffraction grating is planarized, such that layers of the multi-layer stack form a plurality of lines disposed on the planarized surface of the structure in a periodical fashion, wherein lines having a first property alternate with lines having a dissimilar property on the surface of the substrate. For example, in one embodiment, lines comprising high-Z and low-Z materials alternate on the planarized surface providing a structure that is suitable as a diffraction grating for EUV and soft X-rays. In some embodiments, line density of between about 10,000 lines/mm to about 100,000 lines/mm is provided.

  19. Inductor Geometry With Improved Energy Density

    SciTech Connect (OSTI)

    Cui, H; Ngo, KDT; Moss, J; Lim, MHF; Rey, E

    2014-10-01

    The "constant-flux" concept is leveraged to achieve high magnetic-energy density, leading to inductor geometries with height significantly lower than that of conventional products. Techniques to shape the core and to distribute the winding turns to shape a desirable field profile are described for the two basic classes of magnetic geometries: those with the winding enclosed by the core and those with the core enclosed by the winding. A relatively constant flux distribution is advantageous not only from the density standpoint, but also from the thermal standpoint via the reduction of hot spots, and from the reliability standpoint via the suppression of flux crowding. In this journal paper on a constant-flux inductor (CFI) with enclosed winding, the foci are operating principle, dc analysis, and basic design procedure. Prototype cores and windings were routed from powder-iron disks and copper sheets, respectively. The design of CFI was validated by the assembled inductor prototype.

  20. Global coherence of dust density waves

    SciTech Connect (OSTI)

    Killer, Carsten; Melzer, Andr

    2014-06-15

    The coherence of self-excited three-dimensional dust density waves has been experimentally investigated by comparing global and local wave properties. For that purpose, three-dimensional dust clouds have been confined in a radio frequency plasma with thermophoretic levitation. Global wave properties have been measured from the line-of-sight integrated dust density obtained from homogenous light extinction measurements. Local wave properties have been obtained from thin, two-dimensional illuminated laser slices of the cloud. By correlating the simultaneous global and local wave properties, the spatial coherence of the waves has been determined. We find that linear waves with small amplitudes tend to be fragmented, featuring an incoherent wave field. Strongly non-linear waves with large amplitudes, however, feature a strong spatial coherence throughout the dust cloud, indicating a high level of synchronization.

  1. Current density fluctuations and ambipolarity of transport

    SciTech Connect (OSTI)

    Shen, W.; Dexter, R.N.; Prager, S.C.

    1991-10-01

    The fluctuation in the plasma current density is measured in the MIST reversed field pinch experiment. Such fluctuations, and the measured radial profile of the k spectrum of magnetic fluctuations, supports the view and that low frequency fluctuations (f < 30 kHz) are tearing modes and high frequency fluctuations (30 kHz < f < 250 kHz) are localized turbulence in resonance with the local equilibrium magnetic field (i.e., k {center_dot} B = 0). Correlation of current density and magnetic fluctuations (< {tilde j}{parallel}{tilde B}{sub r} >) demonstrates that radial particle transport from particle motion parallel to a fluctuating magnetic field is ambipolar over the full frequency range.

  2. Current density fluctuations and ambipolarity of transport

    SciTech Connect (OSTI)

    Shen, W.; Dexter, R.N.; Prager, S.C.

    1991-10-01

    The fluctuation in the plasma current density is measured in the MIST reversed field pinch experiment. Such fluctuations, and the measured radial profile of the k spectrum of magnetic fluctuations, supports the view and that low frequency fluctuations (f < 30 kHz) are tearing modes and high frequency fluctuations (30 kHz < f < 250 kHz) are localized turbulence in resonance with the local equilibrium magnetic field (i.e., k {center dot} B = 0). Correlation of current density and magnetic fluctuations (< {tilde j}{parallel}{tilde B}{sub r} >) demonstrates that radial particle transport from particle motion parallel to a fluctuating magnetic field is ambipolar over the full frequency range.

  3. Energy flux density in a thermoacoustic couple

    SciTech Connect (OSTI)

    Cao, N.; Chen, S. |; Olson, R.; Swift, G.W.

    1996-06-01

    The hydro- and thermodynamical processes near and within a thermoacoustic couple are simulated and analyzed by numerical solution of the compressible Navier-Stokes, continuity, and energy equations for an ideal gas, concentrating on the time-averaged energy flux density in the gas. The numerical results show details of the heat sink at one end of the plates in the thermoacoustic couple. 15 refs., 10 figs., 1 tab.

  4. Density fluctuations of polymers in disordered media

    SciTech Connect (OSTI)

    Deutsch, Joshua M.; Olvera de la Cruz, Monica

    2011-03-02

    We study self-avoiding random walks in an environment where sites are excluded randomly, in two and three dimensions. For a single polymer chain, we study the statistics of the time averaged monomer density and show that these are well described by multifractal statistics. This is true even far from the percolation transition of the disordered medium. We investigate solutions of chains in a disordered environment and show that the statistics cease to be multifractal beyond the screening length of the solution.

  5. High-density carbon ablator ignition path with low-density gas-filled rugby hohlraum

    SciTech Connect (OSTI)

    Amendt, Peter; Ho, Darwin D.; Jones, Ogden S.

    2015-04-15

    A recent low gas-fill density (0.6 mg/cc {sup 4}He) cylindrical hohlraum experiment on the National Ignition Facility has shown high laser-coupling efficiency (>96%), reduced phenomenological laser drive corrections, and improved high-density carbon capsule implosion symmetry [Jones et al., Bull. Am. Phys. Soc. 59(15), 66 (2014)]. In this Letter, an ignition design using a large rugby-shaped hohlraum [Amendt et al., Phys. Plasmas 21, 112703 (2014)] for high energetics efficiency and symmetry control with the same low gas-fill density (0.6 mg/cc {sup 4}He) is developed as a potentially robust platform for demonstrating thermonuclear burn. The companion high-density carbon capsule for this hohlraum design is driven by an adiabat-shaped [Betti et al., Phys. Plasmas 9, 2277 (2002)] 4-shock drive profile for robust high gain (>10) 1-D ignition performance and large margin to 2-D perturbation growth.

  6. Effects of argon gas pressure on its metastable-state density in high-density plasmas

    SciTech Connect (OSTI)

    Seo, B. H.; Kim, J. H.; You, S. J.

    2015-05-15

    The effect of argon gas pressure on its metastable density in inductively coupled plasmas (ICPs) is investigated by using the laser-induced fluorescence method. Our results show that the metastable-state density of argon varies with the gas pressure depending on the measurement position; the density decreases with the pressure at a position far from the ICP antenna, whereas it increases with the pressure at a position near the antenna. This contrast in the metastable-state density trend with the pressure is explained by considering the electron temperature variations at the two measurement positions. The theoretical interpretation and calculation using a global model are also addressed in detail in this paper.

  7. Self-humidified proton exchange membrane fuel cells: Operation of larger cells and fuel cell stacks

    SciTech Connect (OSTI)

    Dhar, H.P.; Lee, J.H.; Lewinski, K.A.

    1996-12-31

    The PEM fuel cell is promising as the power source for use in mobile and stationary applications primarily because of its high power density, all solid components, and simplicity of operation. For wide acceptability of this power source, its cost has to be competitive with the presently available energy sources. The fuel cell requires continuous humidification during operation as a power source. The humidification unit however, increases fuel cell volume, weight, and therefore decreases its overall power density. Great advantages in terms of further fuel cell simplification can be achieved if the humidification process can be eliminated or minimized. In addition, cost reductions are associated with the case of manufacturing and operation. At BCS Technology we have developed a technology of self-humidified operation of PEM fuel cells based on the mass balance of the reactants and products and the ability of membrane electrode assembly (MEA) to retain water necessary for humidification under the cell operating conditions. The reactants enter the fuel cell chambers without carrying any form of water, whether in liquid or vapor form. Basic principles of self-humidified operation of fuel cells as practiced by BCS Technology, Inc. have been presented previously in literature. Here, we report the operation of larger self-humidified single cells and fuel cell stacks. Fuel cells of areas Up to 100 cm{sup 2} have been operated. We also show the self-humidified operation of fuel cell stacks of 50 and 100 cm{sup 2} electrode areas.

  8. Vehicle Technologies Office Merit Review 2015: High-Efficiency High-Density

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    GaN-Based 6.6kW Bidirectional On-Board Charger for PEVs | Department of Energy High-Efficiency High-Density GaN-Based 6.6kW Bidirectional On-Board Charger for PEVs Vehicle Technologies Office Merit Review 2015: High-Efficiency High-Density GaN-Based 6.6kW Bidirectional On-Board Charger for PEVs Presentation given by Delta Products Corporation at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about high-efficiency

  9. Theory of melting at high pressures: Amending density functional theory with quantum Monte Carlo

    SciTech Connect (OSTI)

    Shulenburger, L.; Desjarlais, M. P.; Mattsson, T. R.

    2014-10-01

    We present an improved first-principles description of melting under pressure based on thermodynamic integration comparing Density Functional Theory (DFT) and quantum Monte Carlo (QMC) treatments of the system. The method is applied to address the longstanding discrepancy between density functional theory (DFT) calculations and diamond anvil cell (DAC) experiments on the melting curve of xenon, a noble gas solid where van der Waals binding is challenging for traditional DFT methods. The calculations show excellent agreement with data below 20 GPa and that the high-pressure melt curve is well described by a Lindemann behavior up to at least 80 GPa, a finding in stark contrast to DAC data.

  10. Radiography to measure the longitudinal density gradients of Pd compacts

    SciTech Connect (OSTI)

    Back, D.D.

    1992-05-14

    This study used radiography to detect and quantify density gradients in green compacts of Palladium powder. Ultrasonic velocity measurements had been tried previously, but they were affected by material properties, in addition to the density, so that an alternative was sought. The alternative technique used radiographic exposures of a series of standard compacts whose density is known and correlated with the radiographic film density. These correlations are used to predict the density in subsequent compacts.

  11. Wave-function functionals for the density

    SciTech Connect (OSTI)

    Slamet, Marlina; Pan Xiaoyin; Sahni, Viraht

    2011-11-15

    We extend the idea of the constrained-search variational method for the construction of wave-function functionals {psi}[{chi}] of functions {chi}. The search is constrained to those functions {chi} such that {psi}[{chi}] reproduces the density {rho}(r) while simultaneously leading to an upper bound to the energy. The functionals are thereby normalized and automatically satisfy the electron-nucleus coalescence condition. The functionals {psi}[{chi}] are also constructed to satisfy the electron-electron coalescence condition. The method is applied to the ground state of the helium atom to construct functionals {psi}[{chi}] that reproduce the density as given by the Kinoshita correlated wave function. The expectation of single-particle operators W={Sigma}{sub i}r{sub i}{sup n}, n=-2,-1,1,2, W={Sigma}{sub i}{delta}(r{sub i}) are exact, as must be the case. The expectations of the kinetic energy operator W=-(1/2){Sigma}{sub i}{nabla}{sub i}{sup 2}, the two-particle operators W={Sigma}{sub n}u{sup n}, n=-2,-1,1,2, where u=|r{sub i}-r{sub j}|, and the energy are accurate. We note that the construction of such functionals {psi}[{chi}] is an application of the Levy-Lieb constrained-search definition of density functional theory. It is thereby possible to rigorously determine which functional {psi}[{chi}] is closer to the true wave function.

  12. Fast magnetic reconnection in low-density electron-positron plasmas

    SciTech Connect (OSTI)

    Bessho, Naoki; Bhattacharjee, A.

    2010-10-15

    Two-dimensional particle-in-cell simulations have been performed to study magnetic reconnection in low-density electron-positron plasmas without a guide magnetic field. Impulsive reconnection rates become of the order of unity when the background density is much smaller than 10% of the density in the initial current layer. It is demonstrated that the outflow speed is less than the upstream Alfven speed, and that the time derivative of the density must be taken into account in the definition of the reconnection rate. The reconnection electric fields in the low-density regime become much larger than the ones in the high-density regime, and it is possible to accelerate the particles to high energies more efficiently. The inertial term in the generalized Ohm's law is the most dominant term that supports a large reconnection electric field. An effective collisionless resistivity is produced and tracks the extension of the diffusion region in the late stage of the reconnection dynamics, and significant broadening of the diffusion region is observed. Because of the broadening of the diffusion region, no secondary islands, which have been considered to play a role to limit the diffusion region, are generated during the extension of the diffusion region in the outflow direction.

  13. Method of high-density foil fabrication

    DOE Patents [OSTI]

    Blue, Craig A.; Sikka, Vinod K.; Ohriner, Evan K.

    2003-12-16

    A method for preparing flat foils having a high density includes the steps of mixing a powdered material with a binder to form a green sheet. The green sheet is exposed to a high intensity radiative source adapted to emit radiation of wavelengths corresponding to an absorption spectrum of the powdered material. The surface of the green sheet is heated while a lower sub-surface temperature is maintained. An apparatus for preparing a foil from a green sheet using a radiation source is also disclosed.

  14. MULTIPLE THICKNESS TIMES DENSITY GAMMA GAGE

    DOE Patents [OSTI]

    Cherry, N.H.

    1962-07-24

    A device was developed for measuring simultaneously the thicknesses of two dissimilar materials superimposed on each other, such as coating of one material on another. The apparatus utilizes a double gamma radiation source producing radiation in two narrow band energy levels. The different materials attenuate the two bands of energy unequally with the result that a composite signal is received which can be analyzed to separate out the components due to the differing materials and indicate the thickness or densities of the two layers. (AEC)

  15. High Energy Density Utracapacitors: Low-Cost, High Energy and Power Density, Nanotube-Enhanced Ultracapacitors

    SciTech Connect (OSTI)

    2010-04-01

    Broad Funding Opportunity Announcement Project: FastCAP is improving the performance of an ultracapacitor—a battery-like electronic device that can complement, and possibly even replace, an HEV or EV battery pack. Ultracapacitors have many advantages over conventional batteries, including long lifespans (over 1 million cycles, as compared to 10,000 for conventional batteries) and better durability. Ultracapacitors also charge more quickly than conventional batteries, and they release energy more quickly. However, ultracapacitors have fallen short of batteries in one key metric: energy density—high energy density means more energy storage. FastCAP is redesigning the ultracapacitor’s internal structure to increase its energy density. Ultracapacitors traditionally use electrodes made of irregularly shaped, porous carbon. FastCAP’s ultracapacitors are made of tiny, aligned carbon nanotubes. The nanotubes provide a regular path for ions moving in and out of the ultracapacitor’s electrode, increasing the overall efficiency and energy density of the device.

  16. Gamma Reaction History ablator areal density constraints upon correlated diagnostic modeling of National Ignition Facility implosion experiments

    SciTech Connect (OSTI)

    Cerjan, C. Sayre, D. B.; Landen, O. L.; Church, J. A.; Stoeffl, W.; Grafil, E. M.; Herrmann, H. W.; Hoffman, N. M.; Kim, Y.

    2015-03-15

    The inelastic neutron scattering induced γ-ray signal from {sup 12}C in an Inertial Confinement Fusion capsule is demonstrated to be an effective and general diagnostic for shell ablator areal density. Experimental acquisition of the time-integrated signal at 4.4 MeV using threshold detection from four gas Čerenkov cells provides a direct measurement of the {sup 12}C areal density near stagnation. Application of a three-dimensional isobaric static model of data acquired in a recent high neutron yield National Ignition Facility experimental campaign reveals two general trends: smaller remaining ablator mass at stagnation and higher shell density with increasing laser drive.

  17. Nonlinear evolution of stimulated Raman scattering near the quarter-critical density

    SciTech Connect (OSTI)

    Xiao, C. Z.; Wu, D.; Liu, Z. J.; Zheng, C. Y. He, X. T.

    2015-05-15

    Nonlinear evolution of stimulated Raman scattering (SRS) near the quarter-critical density is studied using one-dimensional (1D) and two-dimensional (2D) particle-in-cell simulations in homogeneous plasmas. In 1D configuration, with two-plasmon decay (TPD) instability excluded, the system evolves into two regimes distinguished by whether density cavities have been formed or not. At low temperatures, a cavity regime characterised by high absorption and low reflection, and at high temperatures nonlinear frequency shift regime due to particle trapping, are observed. Furthermore, a competition between SRS and TPD in 2D simulations reveals that the nonlinear SRS does play a significant role near the quarter-critical density, whose influences were mostly neglected before.

  18. High energy density redox flow device

    DOE Patents [OSTI]

    Chiang, Yet-Ming; Carter, W. Craig; Ho, Bryan Y; Duduta, Mihai; Limthongkul, Pimpa

    2014-05-13

    Redox flow devices are described in which at least one of the positive electrode or negative electrode-active materials is a semi-solid or is a condensed ion-storing electroactive material, and in which at least one of the electrode-active materials is transported to and from an assembly at which the electrochemical reaction occurs, producing electrical energy. The electronic conductivity of the semi-solid is increased by the addition of conductive particles to suspensions and/or via the surface modification of the solid in semi-solids (e.g., by coating the solid with a more electron conductive coating material to increase the power of the device). High energy density and high power redox flow devices are disclosed. The redox flow devices described herein can also include one or more inventive design features. In addition, inventive chemistries for use in redox flow devices are also described.

  19. Reformulation of Density Functional Theory for N-Representable Densities and the Resolution of the v-Representability Problem

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gonis, A.; Zhang, X. G.; Stocks, G. M.; Nicholson, D. M.

    2015-10-23

    Density functional theory for the case of general, N-representable densities is reformulated in terms of density functional derivatives of expectation values of operators evaluated with wave functions leading to a density, making no reference to the concept of potential. The developments provide a complete solution of the v-representability problem by establishing a mathematical procedure that determines whether a density is v-representable and in the case of an affirmative answer determines the potential (within an additive constant) as a derivative with respect to the density of a constrained search functional. It also establishes the existence of an energy functional of themore » density that, for v-representable densities, assumes its minimum value at the density describing the ground state of an interacting many-particle system. The theorems of Hohenberg and Kohn emerge as special cases of the formalism.« less

  20. Reformulation of Density Functional Theory for N-Representable Densities and the Resolution of the v-Representability Problem

    SciTech Connect (OSTI)

    Gonis, A.; Zhang, X. G.; Stocks, G. M.; Nicholson, D. M.

    2015-10-23

    Density functional theory for the case of general, N-representable densities is reformulated in terms of density functional derivatives of expectation values of operators evaluated with wave functions leading to a density, making no reference to the concept of potential. The developments provide a complete solution of the v-representability problem by establishing a mathematical procedure that determines whether a density is v-representable and in the case of an affirmative answer determines the potential (within an additive constant) as a derivative with respect to the density of a constrained search functional. It also establishes the existence of an energy functional of the density that, for v-representable densities, assumes its minimum value at the density describing the ground state of an interacting many-particle system. The theorems of Hohenberg and Kohn emerge as special cases of the formalism.

  1. Corrugated Membrane Fuel Cell Structures

    SciTech Connect (OSTI)

    Grot, Stephen

    2013-09-30

    One of the most challenging aspects of traditional PEM fuel cell stacks is the difficulty achieving the platinum catalyst utilization target of 0.2 gPt/kWe set forth by the DOE. Good catalyst utilization can be achieved with state-of-the-art catalyst coated membranes (CCM) when low catalyst loadings (<0.3 mg/cm2) are used at a low current. However, when low platinum loadings are used, the peak power density is lower than conventional loadings, requiring a larger total active area and a larger bipolar plate. This results in a lower overall stack power density not meeting the DOE target. By corrugating the fuel cell membrane electrode structure, Ion Power?s goal is to realize both the Pt utilization targets as well as the power density targets of the DOE. This will be achieved by demonstrating a fuel cell single cell (50 cm2) with a twofold increase in the membrane active area over the geometric area of the cell by corrugating the MEA structure. The corrugating structure must be able to demonstrate the target properties of < 10 mOhm-cm2 electrical resistance at > 20 psi compressive strength over the active area, in combination with offering at least 80% of power density that can be achieved by using the same MEA in a flat plate structure. Corrugated membrane fuel cell structures also have the potential to meet DOE power density targets by essentially packaging more membrane area into the same fuel cell volume as compared to conventional stack constructions.

  2. Comparative mutagenesis of human cells in vivo and in vitro

    SciTech Connect (OSTI)

    Thilly, W.G.

    1992-05-01

    This report discusses measuring methods of point mutations; high density cell cultures for low dose studies; measurement and sequence determination of mutations in DNA; the mutational spectra of styrene oxide and ethlyene oxide in TK-6 cells; mutational spectrum of Cr in human lymphoblast cells; mutational spectra of radon in TK-6 cells; and the mutational spectra of smokeless tobacco. (CBS)

  3. Reticulation of low density shape memory polymer foam with an in vivo demonstration of vascular occlusion

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rodriguez, Jennifer N.; Miller, Matthew W.; Boyle, Anthony; Horn, John; Yang, Cheng-Kang; Wilson, Thomas S.; Ortega, Jason M.; Small, Ward; Nash, Landon; Skoog, Hunter; et al

    2014-08-11

    Recently, predominantly closed-cell low density shape memory polymer (SMP) foam was reported to be an effective aneurysm filling device in a porcine model (Rodriguez et al., Journal of Biomedical Materials Research Part A 2013: (http://dx.doi.org/10.1002/jbm.a.34782)). Because healing involves blood clotting and cell migration throughout the foam volume, a more open-cell structure may further enhance the healing response. This research sought to develop a non-destructive reticulation process for this SMP foam to disrupt the membranes between pore cells. Non-destructive mechanical reticulation was achieved using a gravity-driven floating nitinol pin array coupled with vibratory agitation of the foam and supplemental chemical etching.more » Lastly, reticulation resulted in a reduced elastic modulus and increased permeability, but did not impede the shape memory behavior. Reticulated foams were capable of achieving rapid vascular occlusion in an in vivo porcine model.« less

  4. Reticulation of low density shape memory polymer foam with an in vivo demonstration of vascular occlusion

    SciTech Connect (OSTI)

    Rodriguez, Jennifer N.; Miller, Matthew W.; Boyle, Anthony; Horn, John; Yang, Cheng-Kang; Wilson, Thomas S.; Ortega, Jason M.; Small, Ward; Nash, Landon; Skoog, Hunter; Maitland, Duncan J.

    2014-08-11

    Recently, predominantly closed-cell low density shape memory polymer (SMP) foam was reported to be an effective aneurysm filling device in a porcine model (Rodriguez et al., Journal of Biomedical Materials Research Part A 2013: (http://dx.doi.org/10.1002/jbm.a.34782)). Because healing involves blood clotting and cell migration throughout the foam volume, a more open-cell structure may further enhance the healing response. This research sought to develop a non-destructive reticulation process for this SMP foam to disrupt the membranes between pore cells. Non-destructive mechanical reticulation was achieved using a gravity-driven floating nitinol pin array coupled with vibratory agitation of the foam and supplemental chemical etching. Lastly, reticulation resulted in a reduced elastic modulus and increased permeability, but did not impede the shape memory behavior. Reticulated foams were capable of achieving rapid vascular occlusion in an in vivo porcine model.

  5. Initial energy density and gluon distribution from the glasma...

    Office of Scientific and Technical Information (OSTI)

    Initial energy density and gluon distribution from the glasma in heavy-ion collisions Citation Details In-Document Search Title: Initial energy density and gluon distribution from the ...

  6. Effect of Lithium PFC Coatings on NSTX Density Control (Journal...

    Office of Scientific and Technical Information (OSTI)

    Effect of Lithium PFC Coatings on NSTX Density Control Citation Details In-Document Search Title: Effect of Lithium PFC Coatings on NSTX Density Control Lithium coatings on the ...

  7. Effect of Lithium PFC Coatings on NSTX Density Control (Journal...

    Office of Scientific and Technical Information (OSTI)

    Effect of Lithium PFC Coatings on NSTX Density Control Citation Details In-Document Search Title: Effect of Lithium PFC Coatings on NSTX Density Control You are accessing a ...

  8. File:Air Density Lab.pdf | Open Energy Information

    Open Energy Info (EERE)

    Air Density Lab.pdf Jump to: navigation, search File File history File usage Metadata File:Air Density Lab.pdf Size of this preview: 463 599 pixels. Other resolution: 464 600...

  9. Silicon-Nanowire Based Lithium Ion Batteries for Vehicles With Double the Energy Density

    SciTech Connect (OSTI)

    Stefan, Ionel; Cohen, Yehonathan

    2015-03-31

    Amprius researched and developed silicon nanowire anodes. Amprius then built and delivered high-energy lithium-ion cells that met the project’s specific energy goal and exceeded the project’s energy density goal. But Amprius’ cells did not meet the project’s cycle life goal, suggesting additional manufacturing process development is required. With DOE support, Amprius developed a new anode material, silicon, and a new anode structure, nanowire. During the project, Amprius also began to develop a new multi-step manufacturing process that does not involve traditional anode production processes (e.g. mixing, drying and calendaring).

  10. Density and potential measurements in an intense ion-beam-generated plasma

    SciTech Connect (OSTI)

    Abt, N.E.

    1982-05-01

    Neutral beams are created by intense large area ion beams which are neutralized in a gas cell. The interaction of the beam with the gas cell creates a plasma. Such a plasma is studied here. The basic plasma parameters, electron temperature, density, and plasma potential, are measured as a function of beam current and neutral gas pressure. These measurements are compared to a model based on the solution of Poisson's equation. Because of the cylindrical geometry the equation cannot be solved analytically. Details of the numerical method are presented.

  11. Fabrication of thin-wall hollow nickel spheres and low density syntactic foams

    SciTech Connect (OSTI)

    Clancy, R.B.; Sanders, T.H. Jr.; Cochran, J.K.

    1991-12-31

    A process has been developed to fabricate thin-wall hollow spheres from conventional oxide powders at room temperature. The polymer- bonded powder shells are fired in air to sinter the walls, leaving the shells either impervious or porous. Alternatively, the oxide shells can be preferentially reduced to produce thin-wall hollow metal spheres which can be bonded together to produce an ultra light weight closed-cell foam. Processing and properties of this class of low density structures will be discussed.

  12. Density of sodium chloride solutions at high temperatures and...

    Office of Scientific and Technical Information (OSTI)

    Subject: 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; SEAWATER; DENSITY; SODIUM CHLORIDES; AQUEOUS SOLUTIONS; CHEMICAL COMPOSITION; CORRELATIONS; EQUATIONS; HIGH ...

  13. Chiral dynamics and peripheral transverse densities (Journal Article) |

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Journal Article: Chiral dynamics and peripheral transverse densities Citation Details In-Document Search Title: Chiral dynamics and peripheral transverse densities In the partonic (or light-front) description of relativistic systems the electromagnetic form factors are expressed in terms of frame-independent charge and magnetization densities in transverse space. This formulation allows one to identify the chiral components of nucleon structure as the peripheral densities at

  14. High current density cathode for electrorefining in molten electrolyte

    DOE Patents [OSTI]

    Li, Shelly X.

    2010-06-29

    A high current density cathode for electrorefining in a molten electrolyte for the continuous production and collection of loose dendritic or powdery deposits. The high current density cathode eliminates the requirement for mechanical scraping and electrochemical stripping of the deposits from the cathode in an anode/cathode module. The high current density cathode comprises a perforated electrical insulated material coating such that the current density is up to 3 A/cm.sup.2.

  15. Quantum coherent switch utilizing commensurate nanoelectrode and charge density periodicities

    DOE Patents [OSTI]

    Harrison, Neil; Singleton, John; Migliori, Albert

    2008-08-05

    A quantum coherent switch having a substrate formed from a density wave (DW) material capable of having a periodic electron density modulation or spin density modulation, a dielectric layer formed onto a surface of the substrate that is orthogonal to an intrinsic wave vector of the DW material; and structure for applying an external spatially periodic electrostatic potential over the dielectric layer.

  16. Spatially separated charge densities of electrons and holes in organic-inorganic halide perovskites

    SciTech Connect (OSTI)

    Li, Dan; Liang, Chunjun E-mail: zhqhe@bjtu.edu.cn; Zhang, Huimin; You, Fangtian; He, Zhiqun E-mail: zhqhe@bjtu.edu.cn; Zhang, Chunxiu

    2015-02-21

    Solution-processable methylammonium lead trihalide perovskites exhibit remarkable high-absorption and low-loss properties for solar energy conversion. Calculation from density functional theory indicates the presence of non-equivalent halogen atoms in the unit cell because of the specific orientation of the organic cation. Considering the ?100? orientation as an example, I{sub 1}, one of the halogen atoms, differs from the other iodine atoms (I{sub 2} and I{sub 3}) in terms of its interaction with the organic cation. The valance-band-maximum (VBM) and conduction-band-minimum (CBM) states are derived mainly from 5p orbital of I{sub 1} atom and 6p orbital of Pb atom, respectively. The spatially separated charge densities of the electrons and holes justify the low recombination rate of the pure iodide perovskite. Chlorine substitution further strengthens the unique position of the I{sub 1} atom, leading to more localized charge density around the I{sub 1} atom and less charge density around the other atoms at the VBM state. The less overlap of charge densities between the VBM and CBM states explains the relatively lower carrier recombination rate of the iodine-chlorine mixed perovskite. Chlorine substitution significantly reduces the effective mass at a direction perpendicular to the Pb-Cl bond and organic axis, enhancing the carrier transport property of the mixed perovskite in this direction.

  17. Experimental and numerical investigations of electron density in low-pressure dual-frequency capacitively coupled oxygen discharges

    SciTech Connect (OSTI)

    Liu, Jia; Wen, De-Qi; Liu, Yong-Xin; Gao, Fei; Lu, Wen-Qi; Wang, You-Nian [School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 (China)] [School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 (China)

    2013-11-15

    The electron density is measured in low-pressure dual-frequency (2/60 MHz) capacitively coupled oxygen discharges by utilizing a floating hairpin probe. The dependence of electron density at the discharge center on the high frequency (HF) power, low frequency (LF) power, and gas pressure are investigated in detail. A (1D) particle-in-cell/Monte Carlo method is developed to calculate the time-averaged electron density at the discharge center and the simulation results are compared with the experimental ones, and general agreements are achieved. With increasing HF power, the electron density linearly increases. The electron density exhibits different changes with the LF power at different HF powers. At low HF powers (e.g., 30 W in our experiment), the electron density increases with increasing LF power while the electron density decreases with increasing LF power at relatively high HF powers (e.g., 120 W in our experiment). With increasing gas pressure the electron density first increases rapidly to reach a maximum value and then decreases slowly due to the combined effect of the production process by the ionization and the loss processes including the surface and volume losses.

  18. High energy density battery with cathode composition

    SciTech Connect (OSTI)

    Nalewajek, D.; Eibeck, R. E.; Sukornick, B.

    1985-10-22

    A cell which employs an active metal anode such as lithium and a liquid organic electrolyte that is improved by the use of a cathode comprised of carbon fluoride chloride is described. The cathode comprises a carbon fluoride chloride of the general formula (C /SUB y/ F /SUB x/ Cl /SUB z/ ) /SUB n/ wherein y is 1 to 2, x is greater than 0 to 1.2, z is less than or equal to0.1 and n defines the number of repeating units occurring in the carbon fluoride chloride molecule of high molecular weight. The resulting battery has improved discharge and shelf-life characteristics.

  19. Sodium-tetravalent sulfur molten chloroaluminate cell

    DOE Patents [OSTI]

    Mamantov, Gleb (Knoxville, TN)

    1985-04-02

    A sodium-tetravalent sulfur molten chloroaluminate cell with a .beta."-alumina sodium ion conductor having a S-Al mole ratio of above about 0.15 in an acidic molten chloroaluminate cathode composition is disclosed. The cathode composition has an AlCl.sub.3 -NaCl mole percent ratio of above about 70-30 at theoretical full charge. The cell provides high energy densities at low temperatures and provides high energy densities and high power densities at moderate temperatures.

  20. Building a Universal Nuclear Energy Density Functional

    SciTech Connect (OSTI)

    Carlson, Joe A.; Furnstahl, Dick; Horoi, Mihai; Lust, Rusty; Nazaewicc, Witek; Ng, Esmond; Thompson, Ian; Vary, James

    2012-12-30

    During the period of Dec. 1 2006 – Jun. 30, 2012, the UNEDF collaboration carried out a comprehensive study of all nuclei, based on the most accurate knowledge of the strong nuclear interaction, the most reliable theoretical approaches, the most advanced algorithms, and extensive computational resources, with a view towards scaling to the petaflop platforms and beyond. The long-term vision initiated with UNEDF is to arrive at a comprehensive, quantitative, and unified description of nuclei and their reactions, grounded in the fundamental interactions between the constituent nucleons. We seek to replace current phenomenological models of nuclear structure and reactions with a well-founded microscopic theory that delivers maximum predictive power with well-quantified uncertainties. Specifically, the mission of this project has been three-fold:  First, to find an optimal energy density functional (EDF) using all our knowledge of the nucleonic Hamiltonian and basic nuclear properties;  Second, to apply the EDF theory and its extensions to validate the functional using all the available relevant nuclear structure and reaction data;  Third, to apply the validated theory to properties of interest that cannot be measured, in particular the properties needed for reaction theory.

  1. Practicality of magnetic compression for plasma density control

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gueroult, Renaud; Fisch, Nathaniel J.

    2016-03-16

    Here, plasma densification through magnetic compression has been suggested for time-resolved control of the wave properties in plasma-based accelerators [P. F. Schmit and N. J. Fisch, Phys. Rev. Lett. 109, 255003 (2012)]. Using particle in cell simulations with real mass ratio, the practicality of large magnetic compression on timescales shorter than the ion gyro-period is investigated. For compression times shorter than the transit time of a compressional Alfven wave across the plasma slab, results show the formation of two counter-propagating shock waves, leading to a highly non-uniform plasma density profile. Furthermore, the plasma slab displays large hydromagnetic like oscillations aftermore » the driving field has reached steady state. Peak compression is obtained when the two shocks collide in the mid-plane. At this instant, very large plasma heating is observed, and the plasmaβ is estimated to be about 1. Although these results point out a densification mechanism quite different and more complex than initially envisioned, these features still might be advantageous in particle accelerators.« less

  2. Anomalous density for Bose gases at finite temperature

    SciTech Connect (OSTI)

    Boudjemaa, A.; Benarous, M.

    2011-10-15

    We analyze the behavior of the anomalous density as function of the radial distance at different temperatures in a variational framework. We show that the temperature dependence of the anomalous density agrees with the Hartree-Fock-Bogoliubov (HFB) calculations. Comparisons between the normal and anomalous fractions at low temperature show that the latter remains higher and, consequently, the neglect of the anomalous density may destabilize the condensate. These results are compatible with those of Yukalov. Surprisingly, the study of the anomalous density in terms of the interaction parameter shows that the dip in the central density is destroyed for sufficiently weak interactions. We explain this effect.

  3. State densities and spectrum fluctuations: Information propagation in complex nuclei

    SciTech Connect (OSTI)

    French, J.B.; Kota, V.K.B.

    1988-01-01

    At excitation energies in nuclei where the state density is unambiguously defined there is a sharp separation between the smoothed spectrum (which defines the density) and fluctuations about it which have recently been studied with a view to understanding some aspects of quantum chaos. We briefly review these two complementary subjects, paying special attention to: the role of the effective interaction in determining the density; the calculation of interacting-particle state and level densities, and of expectation values of interesting operators; the information about the effective nucleon-nucleon interaction which is carried both by the density and the fluctuations. 28 refs., 1 fig.

  4. Current density partitioning in time-dependent current density functional theory

    SciTech Connect (OSTI)

    Mosquera, Martín A.; Wasserman, Adam; Department of Physics, Purdue University, West Lafayette, Indiana 47907

    2014-05-14

    We adapt time-dependent current density functional theory to allow for a fragment-based solution of the many-electron problem of molecules in the presence of time-dependent electric and magnetic fields. Regarding a molecule as a set of non-interacting subsystems that individually evolve under the influence of an auxiliary external electromagnetic vector-scalar potential pair, the partition 4-potential, we show that there are one-to-one mappings between this auxiliary potential, a sharply-defined set of fragment current densities, and the total current density of the system. The partition electromagnetic (EM) 4-potential is expressed in terms of the real EM 4-potential of the system and a gluing EM 4-potential that accounts for exchange-correlation effects and mutual interaction forces between fragments that are required to yield the correct electron dynamics. We prove the zero-force theorem for the fragmented system, establish a variational formulation in terms of action functionals, and provide a simple illustration for a charged particle in a ring.

  5. Comparison of real-time and linear-response time-dependent density functional theories for molecular chromophores ranging from sparse to high densities of states

    SciTech Connect (OSTI)

    Tussupbayev, Samat; Govind, Niranjan; Lopata, Kenneth A.; Cramer, Christopher J.

    2015-03-10

    We assess the performance of real-time time-dependent density functional theory (RT-TDDFT) for the calculation of absorption spectra of 12 organic dye molecules relevant to photovoltaics and dye sensitized solar cells with 8 exchange-correlation functionals (3 traditional, 3 global hybrids, and 2 range-separated hybrids). We compare the calculations with traditional linear-response (LR) TDDFT. In addition, we demonstrate the efficacy of the RT-TDDFT approach to calculate wide absorption spectra of two large chromophores relevant to photovoltaics and molecular switches.

  6. Compensated amorphous silicon solar cell

    DOE Patents [OSTI]

    Carlson, David E.

    1980-01-01

    An amorphous silicon solar cell incorporates a region of intrinsic hydrogenated amorphous silicon fabricated by a glow discharge wherein said intrinsic region is compensated by P-type dopants in an amount sufficient to reduce the space charge density of said region under illumination to about zero.

  7. High energy density redox flow device

    DOE Patents [OSTI]

    Chiang, Yet-Ming; Carter, William Craig; Duduta, Mihai; Limthongkul, Pimpa

    2014-05-13

    Redox flow devices are described including a positive electrode current collector, a negative electrode current collector, and an ion-permeable membrane separating said positive and negative current collectors, positioned and arranged to define a positive electroactive zone and a negative electroactive zone; wherein at least one of said positive and negative electroactive zone comprises a flowable semi-solid composition comprising ion storage compound particles capable of taking up or releasing said ions during operation of the cell, and wherein the ion storage compound particles have a polydisperse size distribution in which the finest particles present in at least 5 vol % of the total volume, is at least a factor of 5 smaller than the largest particles present in at least 5 vol % of the total volume.

  8. High energy density redox flow device

    DOE Patents [OSTI]

    Chiang, Yet -Ming; Carter, W. Craig; Duduta, Mihai; Limthongkul, Pimpa

    2015-10-06

    Redox flow devices are described including a positive electrode current collector, a negative electrode current collector, and an ion-permeable membrane separating said positive and negative current collectors, positioned and arranged to define a positive electroactive zone and a negative electroactive zone; wherein at least one of said positive and negative electroactive zone comprises a flowable semi-solid composition comprising ion storage compound particles capable of taking up or releasing said ions during operation of the cell, and wherein the ion storage compound particles have a polydisperse size distribution in which the finest particles present in at least 5 vol % of the total volume, is at least a factor of 5 smaller than the largest particles present in at least 5 vol % of the total volume.

  9. Comparison of alternative energy storage systems for automobiles

    SciTech Connect (OSTI)

    Not Available

    1982-01-01

    This report outlines a number of areas of research that are recommended for attention (in addition to areas of basic research in support of the more promising rechargeable batteries) as part of a well-rounded investigation of internal combustion engine alternatives. Specifically, the following recommendations are made: electrolytes and novel electrode structures should be investigated for lithium/sulfur batteries, and secondary lithium/sulfur dioxide cells should receive research attention; cost and life problems of air electrodes for aluminum-air batteries should be studied, together with the potential impacts of large numbers of aluminum-air powered cars on the aluminum industry infrastructure. Existing research on aluminum-air batteries might be expanded following such studies; improved materials for phosphoric acid fuel cell structures should be identified through research, as should electrolytes to improve the system start-up times and responses; and systems studies and fuel acceptability analyses for alkaline fuel cells should be conducted, and research should be directed to the solution of air electrode cost and life problems, ongoing flywheel R and D programs should be continued, but with added emphasis on continuously variable transmissions and on overall flywheel-transmission system designs.

  10. A DENSITY-INDEPENDENT FORMULATION OF SMOOTHED PARTICLE HYDRODYNAMICS

    SciTech Connect (OSTI)

    Saitoh, Takayuki R.; Makino, Junichiro

    2013-05-01

    The standard formulation of the smoothed particle hydrodynamics (SPH) assumes that the local density distribution is differentiable. This assumption is used to derive the spatial derivatives of other quantities. However, this assumption breaks down at the contact discontinuity. At the contact discontinuity, the density of the low-density side is overestimated while that of the high-density side is underestimated. As a result, the pressure of the low-density (high-density) side is overestimated (underestimated). Thus, unphysical repulsive force appears at the contact discontinuity, resulting in the effective surface tension. This tension suppresses fluid instabilities. In this paper, we present a new formulation of SPH, which does not require the differentiability of density. Instead of the mass density, we adopt the internal energy density (pressure) and its arbitrary function, which are smoothed quantities at the contact discontinuity, as the volume element used for the kernel integration. We call this new formulation density-independent SPH (DISPH). It handles the contact discontinuity without numerical problems. The results of standard tests such as the shock tube, Kelvin-Helmholtz and Rayleigh-Taylor instabilities, point-like explosion, and blob tests are all very favorable to DISPH. We conclude that DISPH solved most of the known difficulties of the standard SPH, without introducing additional numerical diffusion or breaking the exact force symmetry or energy conservation. Our new SPH includes the formulation proposed by Ritchie and Thomas as a special case. Our formulation can be extended to handle a non-ideal gas easily.

  11. Surface Treatment of Polymers by Ion Beam Irradiation to Control the Human Osteoblast Adhesion: Fluence and Current Density Study

    SciTech Connect (OSTI)

    Guibert, G.; Mikhailov, S.; Rossel, T.; Weder, G.; Betschart, B.; Meunier, C.

    2009-03-10

    In the biomaterial field, the modification of surfaces are used to create polymers with high performances, preserving their bulk properties and creating specific interactions between the designed surfaces and the cells or tissues. The polymers were irradiated with a 900 keV Helium beam to modify their surface properties. Cell cultivation on the samples was done using human osteoblasts cells (hFOB 1.19). For PTFE, PS and PEEK polymers, the cell adhesion occurs after reached some threshold values of fluences. For PET or PMMA polymers, the cells adhere on the non irradiated samples, however the fluence value modifies the cell density. For PMMA and PTFE both, the fluence and the current density influence the cell adhesion. By modifying the appropriate parameters on each material, the control of the cell adhesion is possible. Indeed the surface treatment must be selected and adapted according to the further application: for biosensors, tissue engineering, tissue regeneration, neural probes, drug delivery, bio-actuators etc.

  12. Cancer therapy using non-thermal atmospheric pressure plasma with ultra-high electron density

    SciTech Connect (OSTI)

    Tanaka, Hiromasa; Mizuno, Masaaki; Toyokuni, Shinya; Maruyama, Shoichi; Kodera, Yasuhiro; Terasaki, Hiroko; Adachi, Tetsuo; Kato, Masashi; Kikkawa, Fumitaka; Hori, Masaru

    2015-12-15

    Cancer therapy using non-thermal atmospheric pressure plasma is a big challenge in plasma medicine. Reactive species generated from plasma are key factors for treating cancer cells, and thus, non-thermal atmospheric pressure plasma with high electron density has been developed and applied for cancer treatment. Various cancer cell lines have been treated with plasma, and non-thermal atmospheric plasma clearly has anti-tumor effects. Recent innovative studies suggest that plasma can both directly and indirectly affect cells and tissues, and this observation has widened the range of applications. Thus, cancer therapy using non-thermal atmospheric pressure plasma is promising. Animal experiments and understanding the mode of action are essential for clinical application in the future. A new academic field that combines plasma science, the biology of free radicals, and systems biology will be established.

  13. Investigation of density limit processes in DIII-D

    SciTech Connect (OSTI)

    Maingi, R.; Mahdavi, M.A.; Petrie, T.W.

    1999-02-01

    A series of experiments has been conducted in DIII-D to investigate density-limiting processes. The authors have studied divertor detachment and MARFEs on closed field lines and find semi-quantitative agreement with theoretical calculations of onset conditions. They have shown that the critical density for MARFE onset at low edge temperature scales as I{sub p}/a{sup 2}, i.e. similar to Greenwald scaling. They have also shown that the scaling of the critical separatrix density with heating power at partial detachment onset agrees with Borass` model. Both of these processes yield high edge density limits for reactors such as ITER. By using divertor pumping and pellet fueling they have avoided these and other processes and accessed densities > 1.5{times} Greenwald limit scaling with H-mode confinement, demonstrating that the Greenwald limit is not a fundamental limit on the core density.

  14. Textured-surface quartz resonator fluid density and viscosity monitor

    DOE Patents [OSTI]

    Martin, Stephen J.; Wiczer, James J.; Cernosek, Richard W.; Frye, Gregory C.; Gebert, Charles T.; Casaus, Leonard; Mitchell, Mary A.

    1998-08-25

    A pair of thickness-shear mode resonators, one smooth and one with a textured surface, allows fluid density and viscosity to be independently resolved. A textured surface, either randomly rough or regularly patterned, leads to trapping of liquid at the device surface. The synchronous motion of this trapped liquid with the oscillating device surface allows the device to weigh the liquid; this leads to an additional response that depends on liquid density. This additional response enables a pair of devices, one smooth and one textured, to independently resolve liquid density and viscosity; the difference in responses determines the density while the smooth device determines the density-viscosity product, and thus, the pair determines both density and viscosity.

  15. Method for solvent extraction with near-equal density solutions

    DOE Patents [OSTI]

    Birdwell, Joseph F.; Randolph, John D.; Singh, S. Paul

    2001-01-01

    Disclosed is a modified centrifugal contactor for separating solutions of near equal density. The modified contactor has a pressure differential establishing means that allows the application of a pressure differential across fluid in the rotor of the contactor. The pressure differential is such that it causes the boundary between solutions of near-equal density to shift, thereby facilitating separation of the phases. Also disclosed is a method of separating solutions of near-equal density.

  16. Testing the density matrix expansion against ab initio calculations of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    trapped neutron drops | Argonne Leadership Computing Facility Testing the density matrix expansion against ab initio calculations of trapped neutron drops Authors: Bogner, S., Furnstahl, R.J., Hergert, H., Kortelainen, M., Maris, P., Stoitsov, M., Vary, J.P. Microscopic input to a universal nuclear energy density functional can be provided through the density matrix expansion (DME), which has recently been revived and improved. Several DME implementation strategies are tested for neutron

  17. Method for measuring the density of lightweight materials

    DOE Patents [OSTI]

    Snow, Samuel G.; Giacomelli, Edward J.

    1980-01-01

    This invention relates to a nondestructive method for measuring the density of articles composed of elements having a low atomic number such as plastic and carbon composites. The measurement is accomplished by striking the article with a collimated beam of X radiation, simultaneously monitoring the radiation scattered and the radiation transmitted by the article, then relating the ratio of the radiation scattered to the radiation transmitted with the density of the article. The above method is insensitive to all variables except density.

  18. Videos - Joint Center for Energy Storage Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    July 17, 2012, Videos Scientists Probe Lithium-Sulfur Batteries in Real Time Lithium-sulfur batteries are a promising technology that could some day power electric vehicles. Scientists at SLAC and Stanford University took microscope snapshots of individual sulfur particles - the first real-time imaging of a lithium-sulfur battery in operation. Read More July 18, 2011, Videos Researchers Create Transparent Lithium-Ion Battery Stanford and SLAC National Accelerator Laboratory researchers have

  19. Development of alkaline fuel cells.

    SciTech Connect (OSTI)

    Hibbs, Michael R.; Jenkins, Janelle E.; Alam, Todd Michael; Janarthanan, Rajeswari; Horan, James L.; Caire, Benjamin R.; Ziegler, Zachary C.; Herring, Andrew M.; Yang, Yuan; Zuo, Xiaobing; Robson, Michael H.; Artyushkova, Kateryna; Patterson, Wendy; Atanassov, Plamen Borissov

    2013-09-01

    This project focuses on the development and demonstration of anion exchange membrane (AEM) fuel cells for portable power applications. Novel polymeric anion exchange membranes and ionomers with high chemical stabilities were prepared characterized by researchers at Sandia National Laboratories. Durable, non-precious metal catalysts were prepared by Dr. Plamen Atanassov's research group at the University of New Mexico by utilizing an aerosol-based process to prepare templated nano-structures. Dr. Andy Herring's group at the Colorado School of Mines combined all of these materials to fabricate and test membrane electrode assemblies for single cell testing in a methanol-fueled alkaline system. The highest power density achieved in this study was 54 mW/cm2 which was 90% of the project target and the highest reported power density for a direct methanol alkaline fuel cell.

  20. Radiation-Matter Coupling for Low Density Plasmas (Conference...

    Office of Scientific and Technical Information (OSTI)

    Citation Details In-Document Search Title: Radiation-Matter Coupling for Low Density ... considered when constructing transport algorithms that are intended to provide ...

  1. Ultra Low Density and Highly Crosslinked Biocompatible Shape...

    Office of Scientific and Technical Information (OSTI)

    Biocompatible Shape Memory Polyurethane Foams Citation Details In-Document Search Title: Ultra Low Density and Highly Crosslinked Biocompatible Shape Memory Polyurethane Foams ...

  2. A density-matching approach for optimization under uncertainty...

    Office of Scientific and Technical Information (OSTI)

    A density-matching approach for optimization under uncertainty Citation Details ... Journal Name: Computer Methods in Applied Mechanics and Engineering Additional Journal ...

  3. 3-D capacitance density imaging of fluidized bed

    DOE Patents [OSTI]

    Fasching, George E.

    1990-01-01

    A three-dimensional capacitance density imaging of a gasified bed or the like in a containment vessel is achieved using a plurality of electrodes provided circumferentially about the bed in levels and along the bed in channels. The electrodes are individually and selectively excited electrically at each level to produce a plurality of current flux field patterns generated in the bed at each level. The current flux field patterns are suitably sensed and a density pattern of the bed at each level determined. By combining the determined density patterns at each level, a three-dimensional density image of the bed is achieved.

  4. Laser Propagation in Nanostructured Ultra-Low-Density Materials...

    Office of Scientific and Technical Information (OSTI)

    By design, the gas and aerogel targets will have identical densities and identical effective ionization states. Authors: Fournier, K. B. 1 ; Colvin, J. 1 ; Yogo, A 2 ; Kemp, ...

  5. Combined local-density and dynamical mean field theory calculations...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Combined local-density and dynamical mean ... Citation Details In-Document Search Title: Combined ... This paper reports calculations for compressed Ce (4fsup ...

  6. Ultra Low Density Shape Memory Polymer Foams With Tunable Physicochemi...

    Office of Scientific and Technical Information (OSTI)

    ThesisDissertation: Ultra Low Density Shape Memory Polymer Foams With Tunable Physicochemical Properties for Treatment of intracranial Aneurysms Citation Details In-Document ...

  7. The Effects of Highly Structured Low Density Carbon Nanotube...

    Office of Scientific and Technical Information (OSTI)

    Carbon Nanotube Networks on the Thermal Degradation Behaviour of Polysiloxanes Citation Details In-Document Search Title: The Effects of Highly Structured Low Density Carbon ...

  8. Density functional theory and conductivity studies of boron-based...

    Office of Scientific and Technical Information (OSTI)

    The receptors are also potentially beneficial to rechargeable lithium ion and lithium air batteries. We apply Density Functional Theory (DFT) to show that an oxalate-based ...

  9. Inhomogeneity smoothing using density valley formed by ion beam...

    Office of Scientific and Technical Information (OSTI)

    in an ion-beam inertial confinement fusion pellets by numerical simulation. The simulation results show that the radiation energy is confined in the density valley, and the ...

  10. Key Parameters Governing the Energy Density of Rechargeable Li...

    Office of Scientific and Technical Information (OSTI)

    of Rechargeable LiS Batteries Citation Details In-Document Search Title: Key Parameters Governing the Energy Density of Rechargeable LiS Batteries Authors: Gao, Jie ; ...

  11. Internal field, density & temperature measurements in MTF plasmas...

    Office of Scientific and Technical Information (OSTI)

    Title: Internal field, density & temperature measurements in MTF plasmas using Pulsed Polarimetry final report Authors: Smith, Roger J. Publication Date: 2014-08-11 OSTI ...

  12. Viscosity and density tables of sodium chloride solutions (Technical...

    Office of Scientific and Technical Information (OSTI)

    A file is presented containing tabulated data extracted from the scientific literature on the density and viscosity of aqueous sodium chloride solutions. Also included is a ...

  13. Centrality evolution of the charged-particle pseudorapidity density...

    Office of Scientific and Technical Information (OSTI)

    Centrality evolution of the charged-particle pseudorapidity density over a broad ... Citation Details In-Document Search Title: Centrality evolution of the charged-particle ...

  14. Practicality of magnetic compression for plasma density control...

    Office of Scientific and Technical Information (OSTI)

    control Citation Details In-Document Search This content will become publicly available on March 16, 2017 Title: Practicality of magnetic compression for plasma density control ...

  15. Controlling the Actuation Rate of Low Density Shape Memory Polymer...

    Office of Scientific and Technical Information (OSTI)

    Memory Polymer Foams in Water Citation Details In-Document Search Title: Controlling the Actuation Rate of Low Density Shape Memory Polymer Foams in Water Authors: Singhal, P ; ...

  16. High Island Densities and Long Range Repulsive Interactions:...

    Office of Scientific and Technical Information (OSTI)

    long range repulsive interactions. Kinetic Monte Carlo simulations and density functional theory calculations support this conclusion. In addition to answering an outstanding...

  17. CORRELATION BETWEEN GROUP LOCAL DENSITY AND GROUP LUMINOSITY

    SciTech Connect (OSTI)

    Deng Xinfa; Yu Guisheng

    2012-11-10

    In this study, we investigate the correlation between group local number density and total luminosity of groups. In four volume-limited group catalogs, we can conclude that groups with high luminosity exist preferentially in high-density regions, while groups with low luminosity are located preferentially in low-density regions, and that in a volume-limited group sample with absolute magnitude limit M{sub r} = -18, the correlation between group local number density and total luminosity of groups is the weakest. These results basically are consistent with the environmental dependence of galaxy luminosity.

  18. Density Log At Valles Caldera - Redondo Geothermal Area (Rowley...

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Density Log At Valles Caldera - Redondo Geothermal Area (Rowley, Et Al., 1987) Exploration...

  19. Rock Density At Alum Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Rock Density At Alum Area (DOE GTP) Exploration Activity Details Location Alum Geothermal Area...

  20. Density Log At Valles Caldera - Redondo Geothermal Area (Wilt...

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Density Log At Valles Caldera - Redondo Geothermal Area (Wilt & Haar, 1986) Exploration...

  1. Advanced intermediate temperature sodium-nickel chloride batteries with ultra-high energy density

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Li, Guosheng; Lu, Xiaochuan; Kim, Jin Yong; Meinhardt, Kerry D.; Chang, Hee -Jung; Canfield, Nathan L.; Sprenkle, Vincent L.

    2016-02-11

    Here we demonstrate for the first time that planar Na-NiCl2 batteries can be operated at an intermediate temperature of 190°C with ultra-high energy density. A specific energy density of 350 Wh/kg, which is 3 times higher than that of conventional tubular Na-NiCl2 batteries operated at 280°C, was obtained for planar Na-NiCl2 batteries operated at 190°C over a long-term cell test (1000 cycles). The high energy density and superior cycle stability are attributed to the slower particle growth of the cathode materials (NaCl and Ni) at 190°C. The results reported in this work demonstrate that planar Na-NiCl2 batteries operated at anmore » intermediate temperature could greatly benefit this traditional energy storage technology by improving battery energy density, cycle life and reducing material costs.« less

  2. Bonding Low-density Nanoporous Metal Foams Using Sputtered Solder

    SciTech Connect (OSTI)

    Bono, M; Cervantes, O; Akaba, C; Hamza, A; Foreman, R; Teslich, N

    2007-08-21

    A method has been developed for bonding low-density nanoporous metal foam components to a substrate using solder that is sputtered onto the surfaces. Metal foams have unusual properties that make them excellent choices for many applications, and as technologies for processing these materials are evolving, their use in industry is increasing dramatically. Metal foams are lightweight and have advantageous dynamic properties, which make them excellent choices for many structural applications. They also provide good acoustic damping, low thermal conductivity, and excellent energy absorption characteristics. Therefore, these materials are commonly used in the automotive, aerospace, construction, and biomedical industries. The synthesis of nanoporous metal foams with a cell size of less then 1 {micro}m is an emerging technology that is expected to lead to widespread application of metal foams in microdevices, such as sensors and actuators. One of the challenges to manufacturing components from metal foams is that they can be difficult to attach to other structures without degrading their properties. For example, traditional liquid adhesives cannot be used because they are absorbed into foams. The problem of bonding or joining can be particularly difficult for small-scale devices made from nanoporous foam, due to the requirement for a thin bond layer. The current study addresses this problem and develops a method of soldering a nanoporous metal foam to a substrate with a bond thickness of less than 2 {micro}m. There are many applications that require micro-scale metal foams precisely bonded to substrates. This study was motivated by a physics experiment that used a laser to drive a shock wave through an aluminum foil and into a copper foam, in order to determine the speed of the shock in the copper foam. To avoid disturbing the shock, the interface between the copper foam and the aluminum substrate had to be as thin as possible. There are many other applications that

  3. Plasma ionization frequency, edge-to-axis density ratio, and density on axis of a cylindrical gas discharge

    SciTech Connect (OSTI)

    Palacio Mizrahi, J. H.

    2014-06-15

    A rigorous derivation of expressions, starting from the governing equations, for the ionization frequency, edge-to-axis ratio of plasma density, plasma density at the axis, and radially averaged plasma density in a cylindrical gas discharge has been obtained. The derived expressions are simple and involve the relevant parameters of the discharge: Cylinder radius, axial current, and neutral gas pressure. The found expressions account for ion inertia, ion temperature, and changes in plasma ion collisionality.

  4. Density Functional Studies of Stoichiometric Surfaces of Orthorhombic...

    Office of Scientific and Technical Information (OSTI)

    are highly attractive for dye-sensitized solar cells as demonstrated by their rapid ... structural design of perovskite based solar cells, in order to achieve further ...

  5. Expancel Foams: Fabrication and Characterization of a New Reduced Density Cellular Material for Structural Applications

    SciTech Connect (OSTI)

    L. Whinnery; S. Goods; B. Even

    2000-08-01

    This study was initiated to produce a low-density centering medium for use in experiments investigating the response of materials to shock-loading. While the main drivers for material selection were homogeneity, dimensional stability, performance and cost, other secondary requirements included fine cell size, the ability to manufacture 5--10 cm-sized parts and an extremely compressed development time. The authors chose a non-traditional methodology using a hollow, expandable, polymeric microballoon material system called Expancel{reg_sign}. These microballoons are made from a copolymer of polyacrylonitrile (PAN) and polymethacrylonitrile (PMAN) and use iso-pentane as the blowing agent. The average diameter (by volume) of the unexpanded powder is approximately 13 {micro}m, while the average of the expanded powder is 35--55 {micro}m, with a few large microballoons approaching 150--200 p.m. A processing method was developed that established a pre-mixed combination of unexpanded and expanded Expancel at a ratio such that the tap (or vibration) density of the mixed powders was the same as that desired of the final part. Upon heating above the tack temperature of the polymer, this zero-rise approach allowed only expansion of the unexpanded powder to fill the interstices between the pre-expanded balloons. The mechanical action of the expanding powder combined with the elevated processing temperature yielded flee-standing and mechanically robust parts. Although mechanical properties of these foams were not a key performance requirement, the data allowed for the determination of the best temperature to heat the samples. Processing the foam at higher temperatures enhanced both modulus and strength. The maximum allowable temperature was limited by dimensional stability and shrinkback considerations. Tomographic analysis of foam billets revealed very flat density profiles. Parts of any density between the low density expanded powder (approximately 0.013 g/cm{sup 3}) and the

  6. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Na+, Mg2+ or Al3+ as conductive media, providing a useful alternative strategy ... Highly dispersed Sulfur in porous aromatic framework as cathode for Lithium-Sulfur ...

  7. Presentations | JCESR

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    a Viable Lithium-Sulfur Transportation Battery Kevin Zavadil, JCESR Thrust PI, Chemical Transformation Pathways to Non-aqueous Redox Flow (NRF) Batteries for Grid Storage Fikile ...

  8. Understanding and Manipulating Solution Chemistry of Polysulfides...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Understanding and Manipulating Solution Chemistry of Polysulfides for Lithium Sulfur Batteries (Top)Fundamental details regarding the solution chemistry of polysulfides in organic ...

  9. Mechanism of Enhanced Carbon Cathode Performance by Nitrogen...

    Office of Scientific and Technical Information (OSTI)

    Mechanism of Enhanced Carbon Cathode Performance by Nitrogen Doping in LithiumSulfur ... Citation Details In-Document Search Title: Mechanism of Enhanced Carbon Cathode ...

  10. Nitrogen-Doped Mesoporous Carbon Promoted Chemical Adsorption...

    Office of Scientific and Technical Information (OSTI)

    of High-Areal-Capacity Sulfur Cathode with Exceptional Cycling Stability for Lithium-Sulfur Batteries Citation Details In-Document Search Title: Nitrogen-Doped Mesoporous Carbon ...

  11. Seminar Series | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... we can use defect simulation to guide the ... lithium-oxygen, lithium-sulfur, and redox ... fundamental redox processes and design strategies in these battery systems. ...

  12. Microsoft PowerPoint - Liang_ACSNano-2013.pptx

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    interfacial resistance. Reference: "A Lithium Superionic Sulfide Cathode for All-Solid Lithium-Sulfur Batteries" Z. Lin (Materials Science and Technology Division, ORNL), Z. Liu...

  13. Monte Carlo modeling of electron density in hypersonic rarefied gas flows

    SciTech Connect (OSTI)

    Fan, Jin; Zhang, Yuhuai; Jiang, Jianzheng

    2014-12-09

    The electron density distribution around a vehicle employed in the RAM-C II flight test is calculated with the DSMC method. To resolve the mole fraction of electrons which is several orders lower than those of the primary species in the free stream, an algorithm named as trace species separation (TSS) is utilized. The TSS algorithm solves the primary and trace species separately, which is similar to the DSMC overlay techniques; however it generates new simulated molecules of trace species, such as ions and electrons in each cell, basing on the ionization and recombination rates directly, which differs from the DSMC overlay techniques based on probabilistic models. The electron density distributions computed by TSS agree well with the flight data measured in the RAM-C II test along a decent trajectory at three altitudes 81km, 76km, and 71km.

  14. Highly collimated monoenergetic target-surface electron acceleration in near-critical-density plasmas

    SciTech Connect (OSTI)

    Mao, J. Y.; Chen, L. M.; Huang, K.; Ma, Y.; Zhao, J. R.; Yan, W. C.; Ma, J. L.; Wei, Z. Y.; Li, D. Z.; Aeschlimann, M.; Zhang, J.

    2015-03-30

    Optimized-quality monoenergetic target surface electron beams at MeV level with low normalized emittance (0.03π mm mrad) and high charge (30 pC) per shot have been obtained from 3 TW laser-solid interactions at a grazing incidence. The 2-Dimension particle-in-cell simulations suggest that electrons are wake-field accelerated in a large-scale, near-critical-density preplasma. It reveals that a bubble-like structure as an accelerating cavity appears in the near-critical-density plasma region and travels along the target surface. A bunch of electrons are pinched transversely and accelerated longitudinally by the wake field in the bubble. The outstanding normalized emittance and monochromaticity of such highly collimated surface electron beams could make it an ideal beam for fast ignition or may serve as an injector in traditional accelerators.

  15. Theory of melting at high pressures: Amending density functional theory with quantum Monte Carlo

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shulenburger, L.; Desjarlais, M. P.; Mattsson, T. R.

    2014-10-01

    We present an improved first-principles description of melting under pressure based on thermodynamic integration comparing Density Functional Theory (DFT) and quantum Monte Carlo (QMC) treatments of the system. The method is applied to address the longstanding discrepancy between density functional theory (DFT) calculations and diamond anvil cell (DAC) experiments on the melting curve of xenon, a noble gas solid where van der Waals binding is challenging for traditional DFT methods. The calculations show excellent agreement with data below 20 GPa and that the high-pressure melt curve is well described by a Lindemann behavior up to at least 80 GPa, amore » finding in stark contrast to DAC data.« less

  16. Electrode for a lithium cell

    DOE Patents [OSTI]

    Thackeray, Michael M.; Vaughey, John T.; Dees, Dennis W.

    2008-10-14

    This invention relates to a positive electrode for an electrochemical cell or battery, and to an electrochemical cell or battery; the invention relates more specifically to a positive electrode for a non-aqueous lithium cell or battery when the electrode is used therein. The positive electrode includes a composite metal oxide containing AgV.sub.3O.sub.8 as one component and one or more other components consisting of LiV.sub.3O.sub.8, Ag.sub.2V.sub.4O.sub.11, MnO.sub.2, CF.sub.x, AgF or Ag.sub.2O to increase the energy density of the cell, optionally in the presence of silver powder and/or silver foil to assist in current collection at the electrode and to improve the power capability of the cell or battery.

  17. Symmetry Energy as a Function of Density and Mass

    SciTech Connect (OSTI)

    Danielewicz, Pawel; Lee, Jenny

    2007-10-26

    Energy in nuclear matter is, in practice, completely characterized at different densities and asymmetries, when the density dependencies of symmetry energy and of energy of symmetric matter are specified. The density dependence of the symmetry energy at subnormal densities produces mass dependence of nuclear symmetry coefficient and, thus, can be constrained by that latter dependence. We deduce values of the mass dependent symmetry coefficients, by using excitation energies to isobaric analog states. The coefficient systematic, for intermediate and high masses, is well described in terms of the symmetry coefficient values of a{sub a}{sup V} = (31.5-33.5) MeV for the volume coefficient and a{sub a}{sup S} = (9-12) MeV for the surface coefficient. These two further correspond to the parameter values describing density dependence of symmetry energy, of L{approx}95 MeV and K{sub sym}{approx}25 MeV.

  18. Method to improve reliability of a fuel cell system using low performance cell detection at low power operation

    SciTech Connect (OSTI)

    Choi, Tayoung; Ganapathy, Sriram; Jung, Jaehak; Savage, David R.; Lakshmanan, Balasubramanian; Vecasey, Pamela M.

    2013-04-16

    A system and method for detecting a low performing cell in a fuel cell stack using measured cell voltages. The method includes determining that the fuel cell stack is running, the stack coolant temperature is above a certain temperature and the stack current density is within a relatively low power range. The method further includes calculating the average cell voltage, and determining whether the difference between the average cell voltage and the minimum cell voltage is greater than a predetermined threshold. If the difference between the average cell voltage and the minimum cell voltage is greater than the predetermined threshold and the minimum cell voltage is less than another predetermined threshold, then the method increments a low performing cell timer. A ratio of the low performing cell timer and a system run timer is calculated to identify a low performing cell.

  19. Density impact on performance of composite Si/graphite electrodes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dufek, Eric J.; Picker, Michael; Petkovic, Lucia M.

    2016-01-27

    The ability of alkali-substituted binders for composite Si and graphite negative electrodes to minimize capacity fade for lithium ion batteries is investigated. Polymer films and electrodes are described and characterized by FTIR following immersion in electrolyte (1:2 EC:DMC) for 24 h. FTIR analysis following electrode formation displayed similar alkali-ion dependent shifts in peak location suggesting that changes in the vibrational structure of the binder are maintained after electrode formation. The Si and graphite composite electrodes prepared using the alkali-substituted polyacrylates were also exposed to electrochemical cycling and it has been found that the performance of the Na-substituted binder is superiormore » to a comparable density K-substituted system. However, in comparing performance across many different electrode densities attention needs to be placed on making comparisons at similar densities, as low density electrodes tend to exhibit lower capacity fade over cycling. This is highlighted by a 6% difference between a low density K-substituted electrode and a high density Na-substituted sample. As a result, this low variance between the two systems makes it difficult to quickly make a direct evaluation of binder performance unless electrode density is tightly controlled.« less

  20. Postmortem validation of breast density using dual-energy mammography

    SciTech Connect (OSTI)

    Molloi, Sabee Ducote, Justin L.; Ding, Huanjun; Feig, Stephen A.

    2014-08-15

    Purpose: Mammographic density has been shown to be an indicator of breast cancer risk and also reduces the sensitivity of screening mammography. Currently, there is no accepted standard for measuring breast density. Dual energy mammography has been proposed as a technique for accurate measurement of breast density. The purpose of this study is to validate its accuracy in postmortem breasts and compare it with other existing techniques. Methods: Forty postmortem breasts were imaged using a dual energy mammography system. Glandular and adipose equivalent phantoms of uniform thickness were used to calibrate a dual energy basis decomposition algorithm. Dual energy decomposition was applied after scatter correction to calculate breast density. Breast density was also estimated using radiologist reader assessment, standard histogram thresholding and a fuzzy C-mean algorithm. Chemical analysis was used as the reference standard to assess the accuracy of different techniques to measure breast composition. Results: Breast density measurements using radiologist reader assessment, standard histogram thresholding, fuzzy C-mean algorithm, and dual energy were in good agreement with the measured fibroglandular volume fraction using chemical analysis. The standard error estimates using radiologist reader assessment, standard histogram thresholding, fuzzy C-mean, and dual energy were 9.9%, 8.6%, 7.2%, and 4.7%, respectively. Conclusions: The results indicate that dual energy mammography can be used to accurately measure breast density. The variability in breast density estimation using dual energy mammography was lower than reader assessment rankings, standard histogram thresholding, and fuzzy C-mean algorithm. Improved quantification of breast density is expected to further enhance its utility as a risk factor for breast cancer.

  1. Relativistic equation of state at subnuclear densities in the Thomas-Fermi approximation

    SciTech Connect (OSTI)

    Zhang, Z. W.; Shen, H., E-mail: shennankai@gmail.com [School of Physics, Nankai University, Tianjin 300071 (China)

    2014-06-20

    We study the non-uniform nuclear matter using the self-consistent Thomas-Fermi approximation with a relativistic mean-field model. The non-uniform matter is assumed to be composed of a lattice of heavy nuclei surrounded by dripped nucleons. At each temperature T, proton fraction Y{sub p} , and baryon mass density ? {sub B}, we determine the thermodynamically favored state by minimizing the free energy with respect to the radius of the Wigner-Seitz cell, while the nucleon distribution in the cell can be determined self-consistently in the Thomas-Fermi approximation. A detailed comparison is made between the present results and previous calculations in the Thomas-Fermi approximation with a parameterized nucleon distribution that has been adopted in the widely used Shen equation of state.

  2. Controlling the Actuation Rate of Low Density Shape Memory Polymer...

    Office of Scientific and Technical Information (OSTI)

    Title: Controlling the Actuation Rate of Low Density Shape Memory Polymer Foams in Water Authors: Singhal, P ; Boyle, T ; Infanger, S ; Letts, S ; Small, W ; Maitland, D J ; Wilson...

  3. Paper area density measurement from forward transmitted scattered light

    DOE Patents [OSTI]

    Koo, Jackson C.

    2001-01-01

    A method whereby the average paper fiber area density (weight per unit area) can be directly calculated from the intensity of transmitted, scattered light at two different wavelengths, one being a non-absorpted wavelength. Also, the method makes it possible to derive the water percentage per fiber area density from a two-wavelength measurement. In the optical measuring technique optical transmitted intensity, for example, at 2.1 microns cellulose absorption line is measured and compared with another scattered, optical transmitted intensity reference in the nearby spectrum region, such as 1.68 microns, where there is no absorption. From the ratio of these two intensities, one can calculate the scattering absorption coefficient at 2.1 microns. This absorption coefficient at this wavelength is, then, experimentally correlated to the paper fiber area density. The water percentage per fiber area density can be derived from this two-wavelength measurement approach.

  4. Optical Properties of the Charge-Density-Wave Polychalcogenide...

    Office of Scientific and Technical Information (OSTI)

    the rare-earth polychalcogenide Rsub 2Tesub 5 (R Nd, Sm and Gd) charge-density-wave (CDW) compounds by optical methods. From the absorption spectrum we extract the...

  5. Effect of Chemical Pressure on the Charge Density Wave Transition...

    Office of Scientific and Technical Information (OSTI)

    The charge density wave transition is investigated in the bilayer family of rare-earth tritelluride RTesub 3 compounds (RSm, Gd, Tb, Dy, Ho, Er, and Tm) via high-resolution ...

  6. Low density lipoprotein fraction assay for cardiac disease risk

    DOE Patents [OSTI]

    Krauss, Ronald M.; Blanche, Patricia J.; Orr, Joseph

    1999-01-01

    A variable rate density gradient electrophoric gel is described which separate LDL subfractions with the precision of ultracentrifugation techniques. Also, an innovative bottom inlet mixing chamber particularly useful for producing these gels is described.

  7. Direct experimental determination of spectral densities of molecular complexes

    SciTech Connect (OSTI)

    Pachn, Leonardo A.; Brumer, Paul

    2014-11-07

    Determining the spectral density of a molecular system immersed in a proteomic scaffold and in contact to a solvent is a fundamental challenge in the coarse-grained description of, e.g., electron and energy transfer dynamics. Once the spectral density is characterized, all the time scales are captured and no artificial separation between fast and slow processes need to be invoked. Based on the fluorescence Stokes shift function, we utilize a simple and robust strategy to extract the spectral density of a number of molecular complexes from available experimental data. Specifically, we show that experimental data for dye molecules in several solvents, amino acid proteins in water, and some photochemical systems (e.g., rhodopsin and green fluorescence proteins), are well described by a three-parameter family of sub-Ohmic spectral densities that are characterized by a fast initial Gaussian-like decay followed by a slow algebraic-like decay rate at long times.

  8. COLLOQUIUM: Frontiers in Plasma Science: A High Energy Density...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    January 13, 2016, 4:15pm to 5:30pm Colloquia MBG AUDITORIUM COLLOQUIUM: Frontiers in Plasma Science: A High Energy Density Perspective Dr. Bruce A. Remington Lawrence Livermore ...

  9. Creating, Diagnosing and Controlling High-energy-density Matter...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    October 22, 2013, 3:00pm to 4:15pm Colloquia MBG Auditorium Creating, Diagnosing and Controlling High-energy-density Matter with Lasers Dr. Yuan Ping Lawrence Livermore National ...

  10. The tokamak density limit: A thermo-resistive disruption mechanism...

    Office of Scientific and Technical Information (OSTI)

    Title: The tokamak density limit: A thermo-resistive disruption mechanism Authors: Gates, D. A. 1 ; Brennan, D. P. 1 ; Delgado-Aparicio, L. 1 ; White, R. B. 1 + Show Author ...

  11. Controlling the Actuation Rate of Low Density Shape Memory Polymer...

    Office of Scientific and Technical Information (OSTI)

    Memory Polymer Foams in Water Citation Details In-Document Search Title: Controlling the Actuation Rate of Low Density Shape Memory Polymer Foams in Water You are accessing a ...

  12. Low density lipoprotein fraction assay for cardiac disease risk

    DOE Patents [OSTI]

    Krauss, R.M.; Blanche, P.J.; Orr, J.

    1999-07-20

    A variable rate density gradient electrophoric gel is described which separates LDL subfractions with the precision of ultracentrifugation techniques. Also, an innovative bottom inlet mixing chamber particularly useful for producing these gels is described. 8 figs.

  13. Plasma density diagnostic for capillary-discharge based plasma...

    Office of Scientific and Technical Information (OSTI)

    Plasma density diagnostic for capillary-discharge based plasma channels Authors: Daniels, J. 1 Search SciTech Connect for author "Daniels, J." Search SciTech Connect for...

  14. Optical Properties of the Charge-Density-Wave Polychalcogenide...

    Office of Scientific and Technical Information (OSTI)

    Optical Properties of the Charge-Density-Wave Polychalcogenide Compounds R2Te5 (RNd, Sm and Gd) Citation Details In-Document Search Title: Optical Properties of the...

  15. Probing Electron Dynamics with the Laplacian of the Momentum Density

    SciTech Connect (OSTI)

    Sukumar, N.; MacDougall, Preston J.; Levit, M. Creon

    2012-09-24

    This chapter in the above-titled monograph presents topological analysis of the Laplacian of the electron momentum density in organic molecules. It relates topological features in this distribution to chemical and physical properties, particularly aromaticity and electron transport.

  16. Effect of Chemical Pressure on the Charge Density Wave Transition...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Effect of Chemical Pressure on the Charge Density Wave Transition in Rare-Earth ... These compounds have the chemical formula RTe3, where R represents a rare earth element ...

  17. Exact and approximate Kohn-Sham potentials in ensemble density...

    Office of Scientific and Technical Information (OSTI)

    Title: Exact and approximate Kohn-Sham potentials in ensemble density-functional theory Authors: Yang, Zeng-hui ; Trail, John R. ; Pribram-Jones, Aurora ; Burke, Kieron ; Needs, ...

  18. Surface modification of low density silica and bridged polysilsesquioxane aerogels

    SciTech Connect (OSTI)

    DeFriend, K. A. (Kimberly A.); Loy, D. A. (Douglas A.); Salazar, K. V. (Kenneth V.); Wilson, K. V. (Kennard V.)

    2004-01-01

    Silica and bridged polysilsesquioxane aerogels are low density materials that are attractive for applications such as, thermal insulation, porous separation media or catalyst supports, adsorbents. However, aerogels are notoriously weak and brittle making it difficult to handle and machine monoliths into desired forms. This prevents the development of many applications that would otherwise benefit from the use of the low density materials. We will describe our efforts to chemically modify and mechanically enhance silica-based aerogels using chemical vapor techniques without sacrificing their characteristic low densities. Monolithic silica and organically bridged polysilsesquioxane aerogels were prepared by sol-gel polymerization of the respective methoxysilane monomers followed by supercritical carbon dioxide drying of the gels. Reactive modification of the gels with volatile silylating compounds during and after the drying process and these effects on the mechanical properties and density of the aerogels will be described.

  19. Low density biodegradable shape memory polyurethane foams for...

    Office of Scientific and Technical Information (OSTI)

    Citation Details In-Document Search Title: Low density ... OSTI Identifier: 1122211 Report Number(s): LLNL-JRNL-623392 DOE Contract Number: W-7405-ENG-48 Resource Type: Journal ...

  20. Ultra Low Density and Highly Crosslinked Biocompatible Shape...

    Office of Scientific and Technical Information (OSTI)

    Citation Details In-Document Search Title: Ultra Low Density ... OSTI Identifier: 1111124 Report Number(s): LLNL-JRNL-501951 DOE Contract Number: W-7405-ENG-48 Resource Type: Journal ...

  1. A Comprehensive Study Of Fracture Patterns And Densities In The...

    Open Energy Info (EERE)

    specific knowledge of these in the Geysers area. (2)By locating zones of high fracture density it will be possible to reduce the cost of geothermal power development with the...

  2. Efficient Real-Time Time-Dependent Density Functional Theory...

    Office of Scientific and Technical Information (OSTI)

    Efficient Real-Time Time-Dependent Density Functional Theory Method and its Application to a Collision of an Ion with a 2D Material Title: Efficient Real-Time Time-Dependent ...

  3. Separation of solids by varying the bulk density of a fluid separating medium

    DOE Patents [OSTI]

    Peterson, Palmer L.; Duffy, James B.; Tokarz, Richard D.

    1978-01-01

    A method and apparatus for separating objects having a density greater than a selected density value from objects having a density less than said selected density value. The method typically comprises: (a) providing a separation vessel having an upper and lower portion, said vessel containing a liquid having a density exceeding said selected density value; (b) reducing the apparent density of the liquid to said selected density value by introducing solid, bubble-like bodies having a density less than that of the liquid into the lower portion of the vessel and permitting them to rise therethrough; (c) introducing the objects to be separated into the separation vessel and permitting the objects having a density greater than the apparent density of the liquid to sink to the lower portion of the vessel, while the objects having a density less than said selected density value float in the upper portion of the vessel; and (d) separately removing the higher density objects in the lower portion and the lower density objects in the upper portion from the separation vessel. The apparatus typically comprises: (a) a vessel containing a liquid having a density such that at least part of said objects having a density exceeding said selected density value will float therein; (b) means to place said objects into said vessel; (c) means to reduce the effective density of at least a portion of said liquid to said selected density value, whereby said objects having a density exceeding said selected density value sink into said liquid and said objects having a density less than said selected density value remain afloat, said means to adjust the effective density comprising solid, bubble-like bodies having a density less than said selected density value and means for introducing said bodies into said liquid; and (d) means for separately removing said objects having a density exceeding said selected density value and said objects having a density less than said selected density value

  4. Low density biodegradable shape memory polyurethane foams for embolic

    Office of Scientific and Technical Information (OSTI)

    biomedical applications (Journal Article) | SciTech Connect Low density biodegradable shape memory polyurethane foams for embolic biomedical applications Citation Details In-Document Search Title: Low density biodegradable shape memory polyurethane foams for embolic biomedical applications Authors: Singhal, P ; Small, W ; Cosgriff-Hernandez, E ; Maitland, D ; Wilson, T Publication Date: 2013-02-27 OSTI Identifier: 1122211 Report Number(s): LLNL-JRNL-623392 DOE Contract Number: W-7405-ENG-48

  5. Density Functional Theory with Dissipation: Transport through Single Molecules

    SciTech Connect (OSTI)

    Kieron Burke

    2012-04-30

    A huge amount of fundamental research was performed on this grant. Most of it focussed on fundamental issues of electronic structure calculations of transport through single molecules, using density functional theory. Achievements were: (1) First density functional theory with dissipation; (2) Pseudopotential plane wave calculations with master equation; (3) Weak bias limit; (4) Long-chain conductance; and (5) Self-interaction effects in tunneling.

  6. High Energy Density Laboratory Plasmas Program | National Nuclear Security

    National Nuclear Security Administration (NNSA)

    Administration | (NNSA) High Energy Density Laboratory Plasmas Program Steady advances in increasing the energy, power, and brightness of lasers and particle beams and advances in pulsed power systems have made possible the exploration of matter at extremely high energy density in the laboratory. Exciting new experimental regimes are being realized by exploiting the scientific capabilities of existing ICF Office facilities, as well as the relevant Department of Defense (DoD) and university

  7. High Energy Density Laboratory Plasmas | National Nuclear Security

    National Nuclear Security Administration (NNSA)

    Administration | (NNSA) High Energy Density Laboratory Plasmas NNSA's Office of Inertial Confinement Fusion and DOE's Office of Science established a joint program in HEDLP in 2008. Initially, this program was a combination of work that was funded as part of the NNSA's Stewardship Science Academic Alliances Program in the research area of high energy density physics and the DOE Office of Science's HEDLP Program and Innovative Confinement Concepts Program. Steady advances in increasing the

  8. Non-invasive fluid density and viscosity measurement

    DOE Patents [OSTI]

    Sinha, Dipen N.

    2012-05-01

    The noninvasively measurement of the density and viscosity of static or flowing fluids in a section of pipe such that the pipe performs as the sensing apparatus, is described. Measurement of a suitable structural vibration resonance frequency of the pipe and the width of this resonance permits the density and viscosity to be determined, respectively. The viscosity may also be measured by monitoring the decay in time of a vibration resonance in the pipe.

  9. Simulations of liquid ribidium expanded to the critical density

    SciTech Connect (OSTI)

    Ross, M; Yang, L H; Pilgrim, W

    2006-05-16

    Quantum molecular dynamic simulations were used to examine the change in atomic and electronic structure in liquid rubidium along its liquid-vapor coexistence curve. Starting from the liquid at the triple point, with increasing expansion we observe a continuous increase in the electron localization leading to ion clustering near the metal-nonmetal transition at about twice the critical density, in agreement with electrical measurements, and to the presence of dimers near and below the critical density.

  10. Preface: Special Topic on Advances in Density Functional Theory

    SciTech Connect (OSTI)

    Yang, Weitao

    2014-05-14

    This Special Topic Issue on the Advances in Density Functional Theory, published as a celebration of the fifty years of density functional theory, contains a retrospective article, a perspective article, and a collection of original research articles that showcase recent theoretical advances in the field. It provides a timely discussion reflecting a cross section of our understanding, and the theoretical and computational developments, which have significant implications in broad areas of sciences and engineering.

  11. Comparing the Powertrain Energy Densities of Electric and Gasoline Vehicles

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    | Argonne National Laboratory Comparing the Powertrain Energy Densities of Electric and Gasoline Vehicles Title Comparing the Powertrain Energy Densities of Electric and Gasoline Vehicles Publication Type Conference Paper Year of Publication 2016 Authors Vijayagopal, R, Gallagher, K, Lee, D, Rousseau, A Conference Name SAE 2016 World Congress and Exhibition Date Published 04052016 Other Numbers SAE Paper No. 2016-01-0903 Keywords batteries, electric vehicles, EVs, fuel economy, gasoline,

  12. Improving experimental phases for strong reflections prior to density modification

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Uervirojnangkoorn, Monarin; Hilgenfeld, Rolf; Terwilliger, Thomas C.; Read, Randy J.

    2013-09-20

    Experimental phasing of diffraction data from macromolecular crystals involves deriving phase probability distributions. These distributions are often bimodal, making their weighted average, the centroid phase, improbable, so that electron-density maps computed using centroid phases are often non-interpretable. Density modification brings in information about the characteristics of electron density in protein crystals. In successful cases, this allows a choice between the modes in the phase probability distributions, and the maps can cross the borderline between non-interpretable and interpretable. Based on the suggestions by Vekhter [Vekhter (2005), Acta Cryst. D61, 899–902], the impact of identifying optimized phases for a small number ofmore » strong reflections prior to the density-modification process was investigated while using the centroid phase as a starting point for the remaining reflections. A genetic algorithm was developed that optimizes the quality of such phases using the skewness of the density map as a target function. Phases optimized in this way are then used in density modification. In most of the tests, the resulting maps were of higher quality than maps generated from the original centroid phases. In one of the test cases, the new method sufficiently improved a marginal set of experimental SAD phases to enable successful map interpretation. Lastly, a computer program,SISA, has been developed to apply this method for phase improvement in macromolecular crystallography.« less

  13. Density-shear instability in electron magneto-hydrodynamics

    SciTech Connect (OSTI)

    Wood, T. S. Hollerbach, R.; Lyutikov, M.

    2014-05-15

    We discuss a novel instability in inertia-less electron magneto-hydrodynamics (EMHD), which arises from a combination of electron velocity shear and electron density gradients. The unstable modes have a lengthscale longer than the transverse density scale, and a growth-rate of the order of the inverse Hall timescale. We suggest that this density-shear instability may be of importance in magnetic reconnection regions on scales smaller than the ion skin depth, and in neutron star crusts. We demonstrate that the so-called Hall drift instability, previously argued to be relevant in neutron star crusts, is a resistive tearing instability rather than an instability of the Hall term itself. We argue that the density-shear instability is of greater significance in neutron stars than the tearing instability, because it generally has a faster growth-rate and is less sensitive to geometry and boundary conditions. We prove that, for uniform electron density, EMHD is at least as stable as regular, incompressible MHD, in the sense that any field configuration that is stable in MHD is also stable in EMHD. We present a connection between the density-shear instability in EMHD and the magneto-buoyancy instability in anelastic MHD.

  14. Durability of Low Pt Fuel Cells Operating at High Power Density

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Comparative data for SCLC & SCNOF on AST protocols published 3 Model correlations to full- area test results published 4 Validated model & data set published and available to ...

  15. Measurement of defect densities and Urbach energies of tail states in PTB7 solar cells

    SciTech Connect (OSTI)

    Samiee, Mehran; Joshi, Pranav; Dalal, Vikram; Aidarkhanov, Damir

    2014-09-29

    Poly[[4,8-bis[(2-ethylhexyl)oxy]benzo[1,2-b:4,5-b?]dithiophene-2,6-diyl] [3-fluoro-2-[(2-ethylhexyl) carbonyl]thieno[3,4-b]thiophenediyl

  16. Novel and Optimized Materials Phases for High Energy Density Batteries

    Broader source: Energy.gov [DOE]

    2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  17. Mitigating Breakdown in High Energy Density Perovskite Polymer Nanocomposite Capacitors

    Broader source: Energy.gov [DOE]

    2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  18. The Effects of Dry Density and Pore-water Salinity on the Physical and Microbiological Characteristics of Compacted 100% Bentonite

    SciTech Connect (OSTI)

    Stroes-Gascoyne, S.; Hamon, C.J.; Dixon, D.A.; Kohle, C.L.; Maak, P.

    2007-07-01

    This study examined the conditions required to suppress microbial activity in compacted bentonite, such that microbially influenced corrosion (MIC) of copper waste containers, surrounded by compacted bentonite in a future deep geologic repository, would become insignificant. Experiments were carried out to determine the effects of dry density and pore-water salinity on swelling pressure, water activity (a{sub w}) and the culturable microbial community in compacted bentonite. A dry density {>=} 1.6 g/cm{sup 3} ensures that a{sub w} is < 0.96 and the swelling pressure > 2 MPa. Both conditions suppress microbial culturability below background levels (2.1 x 10{sup 2} Colony-Forming Units/g) in as-purchased bentonite. Under such conditions, cells likely survive as dormant cells or inactive spores, which greatly reduces the possibility of significant MIC. Observations in natural clay-rich environments support these findings. (authors)

  19. Talbot-Lau X-ray Deflectometer electron density diagnostic for laser and pulsed power high energy density plasma experiments

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Valdivia, M. P.; Stutman, D.; Stoeckl, C.; Mileham, C.; Begishev, I.; Theobald, W.; Bromage, J.; Regan, S. P.; Klein, S. R.; Munoz-Cordoves, G.; et al

    2016-04-21

    Talbot-Lau X-ray Deflectometry has been developed as an electron density diagnostic for High Energy Density plasmas. The technique can deliver x-ray refraction, attenuation, elemental composition, and scatter information from a single Moiré image. An 8 keV Talbot-Lau interferometer was deployed using laser and x-pinch backlighters. Grating survival and electron density mapping was demonstrated for 25-29 J, 8-30 ps laser pulses using copper foil targets. Moire pattern formation and grating survival was also observed using a copper x-pinch driven at 400 kA, ~1 kA/ns. Lastly, these results demonstrate the potential of TXD as an electron density diagnostic for HED plasmas.

  20. Direct Measurements of Pore Fluid Density by Vibrating Tube Densimetry

    SciTech Connect (OSTI)

    Gruszkiewicz, Miroslaw {Mirek} S; Rother, Gernot; Wesolowski, David J; Cole, David R; Wallacher, Dirk

    2012-01-01

    The densities of pore-confined fluids were measured for the first time by means of a vibrating tube method. Isotherms of total adsorption capacity were measured directly making the method complementary to the conventional gravimetric or volumetric/piezometric adsorption techniques, which yield the excess adsorption (the Gibbsian surface excess). A custom-made high-pressure, high-temperature vibrating tube densimeter (VTD) was used to measure the densities of subcritical and supercritical propane (between 35 C and 97 C) and supercritical carbon dioxide (between 32 C and 50 C) saturating hydrophobic silica aerogel (0.2 g/cm3, 90% porosity) synthesized inside Hastelloy U-tubes. Additionally, excess adsorption isotherms for supercritical CO2 and the same porous solid were measured gravimetrically using a precise magnetically-coupled microbalance. Pore fluid densities and total adsorption isotherms increased monotonically with increasing density of the bulk fluid, in contrast to excess adsorption isotherms, which reached a maximum at a subcritical density of the bulk fluid, and then decreased towards zero or negative values at supercritical densities. Compression of the confined fluid significantly beyond the density of the bulk liquid at the same temperature was observed at subcritical temperatures. The features of the isotherms of confined fluid density are interpreted to elucidate the observed behavior of excess adsorption. The maxima of excess adsorption were found to occur below the critical density of the bulk fluid at the conditions corresponding to the beginning of the plateau of total adsorption, marking the end of the transition of pore fluid to a denser, liquid-like pore phase. The results for propane and carbon dioxide showed similarity in the sense of the principle of corresponding states. No measurable effect of pore confinement on the liquid-vapor critical point was found. Quantitative agreement was obtained between excess adsorption isotherms determined

  1. High Energy Density Na-S/NiCl2 Hybrid Battery

    SciTech Connect (OSTI)

    Lu, Xiaochuan; Lemmon, John P.; Kim, Jin Yong; Sprenkle, Vincent L.; Yang, Zhenguo

    2013-02-15

    High temperature (250-350C) sodium-beta alumina batteries (NBBs) are attractive energy storage devices for renewable energy integration and other grid related applications. Currently, two technologies are commercially available in NBBs, e.g., sodium-sulfur (Na-S) battery and sodium-metal halide (ZEBRA) batteries. In this study, we investigated the combination of these two chemistries with a mixed cathode. In particular, the cathode of the cell consisted of molten NaAlCl4 as a catholyte and a mixture of Ni, NaCl and Na2S as active materials. During cycling, two reversible plateaus were observed in cell voltage profiles, which matched electrochemical reactions for Na-S and Na-NiCl2 redox couples. An irreversible reaction between sulfur species and Ni was identified during initial charge at 280C, which caused a decrease in cell capacity. The final products on discharge included Na2Sn with 1< n < 3, which differed from Na2S3 found in traditional Na-S battery. Reduction of sulfur in the mixed cathode led to an increase in overall energy density over ZEBRA batteries. Despite of the initial drop in cell capacity, the mixed cathode demonstrated relatively stable cycling with more than 95% of capacity retained over 60 cycles under 10mA/cm2. Optimization of the cathode may lead to further improvements in battery performance.

  2. Criticality Calculations Using the Isopiestic Density Law of Actinide Nitrates

    SciTech Connect (OSTI)

    Leclaire, Nicolas P.; Anno, Jacques A.; Courtois, Gerard; Dannus, Pascal; Poullot, Gilles; Rouyer, Veronique

    2003-12-15

    Up to now, criticality safety experts used density laws fitted on experimental data and applied them outside the measurement range. Depending on the case, such an approach could be wrong for nitrate solutions. Seven components are concerned: UO{sub 2}(NO{sub 3}){sub 2}, U(NO{sub 3}){sub 4}, Pu(NO{sub 3}){sub 4}, Pu(NO{sub 3}){sub 3}, Th(NO{sub 3}){sub 4}, Am(NO{sub 3}){sub 3}, and HNO{sub 3}. To obviate this problem, a new methodology based on the thermodynamic concept of mixtures of binary electrolytes solutions (one electrolyte + water) at constant water activity, a so-called 'isopiestic' solution, has been developed by the Institute de Radioprotection et de Surete Nucleaire (IRSN) to calculate the nitrate solutions density. This paper presents its qualification by using criticality experiments. The theory and the implementation are also given.Qualification results of the uranyl and plutonium nitrate solutions show that the new density law (also called the isopiestic law) is in good agreement with the benchmarks. Thus, no bias is put into evidence for the uranium solutions, and a small negative bias equal to 0.2% is found for the plutonium solutions.Moreover, the isopiestic law corrects the observed 1% overestimation of k{sub eff} due to the empirical IRSN Leroy and Jouan density law for uranium solutions and the observed 3.4% underestimation of k{sub eff} due to the ARH-600 density law for plutonium solutions.The isopiestic density law has been implemented in CIGALES V2.0, the graphical user interface of the French criticality safety package CRISTAL that calculates the atom densities of nuclides (and writes the input file for CRISTAL computations)

  3. DIFFUSE MOLECULAR CLOUD DENSITIES FROM UV MEASUREMENTS OF CO ABSORPTION

    SciTech Connect (OSTI)

    Goldsmith, Paul F.

    2013-09-10

    We use UV measurements of interstellar CO toward nearby stars to calculate the density in the diffuse molecular clouds containing the molecules responsible for the observed absorption. Chemical models and recent calculations of the excitation rate coefficients indicate that the regions in which CO is found have hydrogen predominantly in molecular form and that collisional excitation is by collisions with H{sub 2} molecules. We carry out statistical equilibrium calculations using CO-H{sub 2} collision rates to solve for the H{sub 2} density in the observed sources without including effects of radiative trapping. We have assumed kinetic temperatures of 50 K and 100 K, finding this choice to make relatively little difference to the lowest transition. For the sources having T{sup ex}{sub 10} only for which we could determine upper and lower density limits, we find (n(H{sub 2})) = 49 cm{sup -3}. While we can find a consistent density range for a good fraction of the sources having either two or three values of the excitation temperature, there is a suggestion that the higher-J transitions are sampling clouds or regions within diffuse molecular cloud material that have higher densities than the material sampled by the J = 1-0 transition. The assumed kinetic temperature and derived H{sub 2} density are anticorrelated when the J = 2-1 transition data, the J = 3-2 transition data, or both are included. For sources with either two or three values of the excitation temperature, we find average values of the midpoint of the density range that is consistent with all of the observations equal to 68 cm{sup -3} for T{sup k} = 100 K and 92 cm{sup -3} for T{sup k} = 50 K. The data for this set of sources imply that diffuse molecular clouds are characterized by an average thermal pressure between 4600 and 6800 K cm{sup -3}.

  4. Pion transverse charge density and the edge of hadrons

    SciTech Connect (OSTI)

    Carmignotto, Marco; Horn, Tanja; Miller, Gerald A.

    2014-08-01

    We use the world data on the pion form factor for space-like kinematics and a technique used to extract the proton transverse densities, to extract the transverse pion charge density and its uncertainty due to experimental uncertainties and incomplete knowledge of the pion form factor at large values of Q2. The pion charge density at small values of b<0.1 fm is dominated by this incompleteness error while the range between 0.1-0.3 fm is relatively well constrained. A comparison of pion and proton charge densities shows that the pion is denser than the proton for values of b<0.2 fm. The pion and proton distributions seem to be the same for values of b=0.2-0.6 fm. Future data from Jlab 12 GeV and the EIC will increase the dynamic extent of the data to higher values of Q2 and thus reduce the uncertainties in the extracted pion charge density.

  5. Dynamics and diffusion mechanism of low-density liquid silicon

    SciTech Connect (OSTI)

    Shen, B.; Wang, Z. Y.; Dong, F.; Guo, Y. R.; Zhang, R. J.; Zheng, Y. X.; Wang, S. Y.; Wang, C. Z.; Ho, K. M.; Chen, L. Y.

    2015-11-05

    A first-order phase transition from a high-density liquid to a low-density liquid has been proposed to explain the various thermodynamic anomies of water. It also has been proposed that such liquid–liquid phase transition would exist in supercooled silicon. Computer simulation studies show that, across the transition, the diffusivity drops roughly 2 orders of magnitude, and the structures exhibit considerable tetrahedral ordering. The resulting phase is a highly viscous, low-density liquid silicon. Investigations on the atomic diffusion of such a novel form of liquid silicon are of high interest. Here we report such diffusion results from molecular dynamics simulations using the classical Stillinger–Weber (SW) potential of silicon. We show that the atomic diffusion of the low-density liquid is highly correlated with local tetrahedral geometries. We also show that atoms diffuse through hopping processes within short ranges, which gradually accumulate to an overall random motion for long ranges as in normal liquids. There is a close relationship between dynamical heterogeneity and hopping process. We point out that the above diffusion mechanism is closely related to the strong directional bonding nature of the distorted tetrahedral network. Here, our work offers new insights into the complex behavior of the highly viscous low density liquid silicon, suggesting similar diffusion behaviors in other tetrahedral coordinated liquids that exhibit liquid–liquid phase transition such as carbon and germanium.

  6. Dynamics and diffusion mechanism of low-density liquid silicon

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shen, B.; Wang, Z. Y.; Dong, F.; Guo, Y. R.; Zhang, R. J.; Zheng, Y. X.; Wang, S. Y.; Wang, C. Z.; Ho, K. M.; Chen, L. Y.

    2015-11-05

    A first-order phase transition from a high-density liquid to a low-density liquid has been proposed to explain the various thermodynamic anomies of water. It also has been proposed that such liquid–liquid phase transition would exist in supercooled silicon. Computer simulation studies show that, across the transition, the diffusivity drops roughly 2 orders of magnitude, and the structures exhibit considerable tetrahedral ordering. The resulting phase is a highly viscous, low-density liquid silicon. Investigations on the atomic diffusion of such a novel form of liquid silicon are of high interest. Here we report such diffusion results from molecular dynamics simulations using themore » classical Stillinger–Weber (SW) potential of silicon. We show that the atomic diffusion of the low-density liquid is highly correlated with local tetrahedral geometries. We also show that atoms diffuse through hopping processes within short ranges, which gradually accumulate to an overall random motion for long ranges as in normal liquids. There is a close relationship between dynamical heterogeneity and hopping process. We point out that the above diffusion mechanism is closely related to the strong directional bonding nature of the distorted tetrahedral network. Here, our work offers new insights into the complex behavior of the highly viscous low density liquid silicon, suggesting similar diffusion behaviors in other tetrahedral coordinated liquids that exhibit liquid–liquid phase transition such as carbon and germanium.« less

  7. PREPARATION OF HIGH-DENSITY THORIUM OXIDE SPHERES

    DOE Patents [OSTI]

    McNees, R.A. Jr.; Taylor, A.J.

    1963-12-31

    A method of preparing high-density thorium oxide spheres for use in pellet beds in nuclear reactors is presented. Sinterable thorium oxide is first converted to free-flowing granules by means such as compression into a compact and comminution of the compact. The granules are then compressed into cubes having a density of 5.0 to 5.3 grams per cubic centimeter. The cubes are tumbled to form spheres by attrition, and the spheres are then fired at 1250 to 1350 deg C. The fired spheres are then polished and fired at a temperature above 1650 deg C to obtain high density. Spherical pellets produced by this method are highly resistant to mechanical attrition hy water. (AEC)

  8. On the density limit in the helicon plasma sources

    SciTech Connect (OSTI)

    Kotelnikov, Igor A.

    2014-12-15

    Existence of the density limit in the helicon plasma sources is revisited. The low- and high-frequency regimes of a helicon plasma source operation are distinguished. In the low-frequency regime with ω<√(ω{sub ci}ω{sub ce}), the density limit is deduced from the Golant-Stix criterion of the accessibility of the lower hybrid resonance. In the high-frequency case, ω>√(ω{sub ci}ω{sub ce}), an appropriate limit is given by the Shamrai-Taranov criterion. Both these criteria are closely related to the phenomenon of the coalescence of the helicon wave with the Trivelpiece-Gould mode. We draw a conclusion that the derived density limits are not currently achieved in existing devices, perhaps, because of high energy cost of gas ionization.

  9. Transverse charge and magnetization densities in the nucleon's chiral periphery

    SciTech Connect (OSTI)

    Granados, Carlos G.; Weiss, Christian

    2014-01-01

    In the light-front description of nucleon structure the electromagnetic form factors are expressed in terms of frame-independent transverse densities of charge and magnetization. Recent work has studied the transverse densities at peripheral distances b = O(M{pi}{sup -1}), where they are governed by universal chiral dynamics and can be computed in a model-independent manner. Of particular interest is the comparison of the peripheral charge and magnetization densities. We summarize (a) their interpretation as spin-independent and -dependent current matrix elements; (b) the leading-order chiral effective field theory results; (c) their mechanical interpretation in the light-front formulation; (d) the large-N_c limit of QCD and the role of {Delta} intermediate states; (e) the connection with generalized parton distributions and peripheral high-energy scattering processes.

  10. The density gradient effect on quantum Weibel instability

    SciTech Connect (OSTI)

    Mahdavi, M. Khodadadi Azadboni, F.

    2015-03-15

    The Weibel instability plays an important role in stopping the hot electrons and energy deposition mechanism in the fast ignition of inertial fusion process. In this paper, the effects of the density gradient and degeneracy on Weibel instability growth rate are investigated. Calculations show that decreasing the density degenerate in the plasma corona, near the relativistic electron beam emitting region by 8.5% leads to a 92% reduction in the degeneracy parameter and about 90% reduction in Weibel instability growth rate. Also, decreasing the degenerate density near the fuel core by 8.5% leads to 1% reduction in the degeneracy parameter and about 8.5% reduction in Weibel instability growth rate. The Weibel instability growth rate shrinks to zero and the deposition condition of relativistic electron beam energy can be shifted to the fuel core for a suitable ignition by increasing the degeneracy parameter in the first layer of plasma corona.

  11. Nonlinear upper hybrid waves and the induced density irregularities

    SciTech Connect (OSTI)

    Kuo, Spencer P.

    2015-08-15

    Upper hybrid waves are excited parametrically by the O-mode high-frequency heater waves in the ionospheric heating experiments. These waves grow to large amplitudes and self-induced density perturbations provide nonlinear feedback. The lower hybrid resonance modifies the nonlinear feedback driven by the ponderomotive force; the nonlinear equation governing the envelope of the upper hybrid waves is derived. Solutions in symmetric alternating functions, in non-alternating periodic functions, as well as in solitary functions are shown. The impact of lower hybrid resonance on the envelope of the upper hybrid waves is explored; the results show that both the spatial period and amplitude are enlarged. The average fluctuation level of induced density irregularities is also enhanced. In the soliton form, the induced density cavity is widened considerably.

  12. Modelling charge transfer reactions with the frozen density embedding formalism

    SciTech Connect (OSTI)

    Pavanello, Michele; Neugebauer, Johannes

    2011-12-21

    The frozen density embedding (FDE) subsystem formulation of density-functional theory is a useful tool for studying charge transfer reactions. In this work charge-localized, diabatic states are generated directly with FDE and used to calculate electronic couplings of hole transfer reactions in two {pi}-stacked nucleobase dimers of B-DNA: 5{sup '}-GG-3{sup '} and 5{sup '}-GT-3{sup '}. The calculations rely on two assumptions: the two-state model, and a small differential overlap between donor and acceptor subsystem densities. The resulting electronic couplings agree well with benchmark values for those exchange-correlation functionals that contain a high percentage of exact exchange. Instead, when semilocal GGA functionals are used the electronic couplings are grossly overestimated.

  13. High density electronic circuit and process for making

    DOE Patents [OSTI]

    Morgan, William P.

    1999-01-01

    High density circuits with posts that protrude beyond one surface of a substrate to provide easy mounting of devices such as integrated circuits. The posts also provide stress relief to accommodate differential thermal expansion. The process allows high interconnect density with fewer alignment restrictions and less wasted circuit area than previous processes. The resulting substrates can be test platforms for die testing and for multi-chip module substrate testing. The test platform can contain active components and emulate realistic operational conditions, replacing shorts/opens net testing.

  14. Nonlinear eigenvalue problems in Density Functional Theory calculations

    SciTech Connect (OSTI)

    Fattebert, J

    2009-08-28

    Developed in the 1960's by W. Kohn and coauthors, Density Functional Theory (DFT) is a very popular quantum model for First-Principles simulations in chemistry and material sciences. It allows calculations of systems made of hundreds of atoms. Indeed DFT reduces the 3N-dimensional Schroedinger electronic structure problem to the search for a ground state electronic density in 3D. In practice it leads to the search for N electronic wave functions solutions of an energy minimization problem in 3D, or equivalently the solution of an eigenvalue problem with a non-linear operator.

  15. High density electronic circuit and process for making

    DOE Patents [OSTI]

    Morgan, W.P.

    1999-06-29

    High density circuits with posts that protrude beyond one surface of a substrate to provide easy mounting of devices such as integrated circuits are disclosed. The posts also provide stress relief to accommodate differential thermal expansion. The process allows high interconnect density with fewer alignment restrictions and less wasted circuit area than previous processes. The resulting substrates can be test platforms for die testing and for multi-chip module substrate testing. The test platform can contain active components and emulate realistic operational conditions, replacing shorts/opens net testing. 8 figs.

  16. Fourth International Conference on High Energy Density Physics

    SciTech Connect (OSTI)

    Beg, Farhat

    2015-01-06

    The Fourth International Conference on High Energy Density Physics (ICHED 2013) was held in Saint Malo, France, at the Palais du Grand Large on 25-28 June 2013 (http://web.luli.polytechnique.fr/ICHED2013/). This meeting was the fourth in a series which was first held in 2008. This conference covered all the important aspects of High Energy Density Physics including fundamental topics from strong-field physics to creating new states of matter (including radiation-dominated, high-pressure quantum and relativistic plasmas) and ultra-fast lattice dynamics on the timescale of atomic transitions.

  17. Extended length microchannels for high density high throughput electrophoresis systems

    DOE Patents [OSTI]

    Davidson, James C.; Balch, Joseph W.

    2000-01-01

    High throughput electrophoresis systems which provide extended well-to-read distances on smaller substrates, thus compacting the overall systems. The electrophoresis systems utilize a high density array of microchannels for electrophoresis analysis with extended read lengths. The microchannel geometry can be used individually or in conjunction to increase the effective length of a separation channel while minimally impacting the packing density of channels. One embodiment uses sinusoidal microchannels, while another embodiment uses plural microchannels interconnected by a via. The extended channel systems can be applied to virtually any type of channel confined chromatography.

  18. Semi-exact concentric atomic density fitting: Reduced cost and increased accuracy compared to standard density fitting

    SciTech Connect (OSTI)

    Hollman, David S.; Department of Chemistry, Virginia Tech, Blacksburg, Virginia 24061 ; Schaefer, Henry F.; Valeev, Edward F.

    2014-02-14

    A local density fitting scheme is considered in which atomic orbital (AO) products are approximated using only auxiliary AOs located on one of the nuclei in that product. The possibility of variational collapse to an unphysical “attractive electron” state that can affect such density fitting [P. Merlot, T. Kjærgaard, T. Helgaker, R. Lindh, F. Aquilante, S. Reine, and T. B. Pedersen, J. Comput. Chem. 34, 1486 (2013)] is alleviated by including atom-wise semidiagonal integrals exactly. Our approach leads to a significant decrease in the computational cost of density fitting for Hartree–Fock theory while still producing results with errors 2–5 times smaller than standard, nonlocal density fitting. Our method allows for large Hartree–Fock and density functional theory computations with exact exchange to be carried out efficiently on large molecules, which we demonstrate by benchmarking our method on 200 of the most widely used prescription drug molecules. Our new fitting scheme leads to smooth and artifact-free potential energy surfaces and the possibility of relatively simple analytic gradients.

  19. Density Functional Studies of Stoichiometric Surfaces of Orthorhombic...

    Office of Scientific and Technical Information (OSTI)

    Organicinorganic hybrid perovskite materials are highly attractive for dye-sensitized solar cells as demonstrated by their rapid advances in energy conversion efficiency. In this ...

  20. Fuel cell tubes and method of making same

    DOE Patents [OSTI]

    Borglum, Brian P.

    1999-11-30

    A method of manufacturing porous ceramic tubes for fuel cells with improved properties and higher manufacturing yield is disclosed. The method involves extruding a closed end fuel cell tube, such as an air electrode of a solid oxide fuel cell, in which the closed end also functions as the sintering support. The resultant fuel cell tube has a superior porosity distribution which allows improved diffusion of oxygen at the closed end of the tube during operation of the fuel cell. Because this region has the highest current density, performance enhancement and improved reliability of the fuel cell tube result. Furthermore, the higher manufacturing yield associated with the present method decreases the overall fuel cell cost. A method of manufacturing porous ceramic tubes for fuel cells with improved properties and higher manufacturing yield is disclosed. The method involves extruding a closed end fuel cell tube, such as an air electrode of a solid oxide fuel cell, in which the closed end also functions as the sintering support. The resultant fuel cell tube has a superior porosity distribution which allows improved diffusion of oxygen at the closed end of the tube during operation of the fuel cell. Because this region has the highest current density, performance enhancement and improved reliability of the fuel cell tube result. Furthermore, the higher manufacturing yield associated with the present method decreases the overall fuel cell cost.

  1. A Density Functional Approach to Polarizable Models: A Kim-Gordon-Response Density Interaction Potential for Molecular Simulations

    SciTech Connect (OSTI)

    Tabacchi, G; Hutter, J; Mundy, C

    2005-04-07

    A combined linear response--frozen electron density model has been implemented in a molecular dynamics scheme derived from an extended Lagrangian formalism. This approach is based on a partition of the electronic charge distribution into a frozen region described by Kim-Gordon theory, and a response contribution determined by the instaneous ionic configuration of the system. The method is free from empirical pair-potentials and the parameterization protocol involves only calculations on properly chosen subsystems. They apply this method to a series of alkali halides in different physical phases and are able to reproduce experimental structural and thermodynamic properties with an accuracy comparable to Kohn-Sham density functional calculations.

  2. Quantum Chromodynamics and Nuclear Physics at Extreme Energy Density

    SciTech Connect (OSTI)

    Mueller, B.; Bass, S.A.; Chandrasekharan, S.; Mehen, T.; Springer, R.P.

    2005-11-07

    The report describes research in theoretical quantum chromodynamics, including effective field theories of hadronic interactions, properties of strongly interacting matter at extreme energy density, phenomenology of relativistic heavy ion collisions, and algorithms and numerical simulations of lattice gauge theory and other many-body systems.

  3. Method to reduce dislocation density in silicon using stress

    DOE Patents [OSTI]

    Buonassisi, Anthony; Bertoni, Mariana; Argon, Ali; Castellanos, Sergio; Fecych, Alexandria; Powell, Douglas; Vogl, Michelle

    2013-03-05

    A crystalline material structure with reduced dislocation density and method of producing same is provided. The crystalline material structure is annealed at temperatures above the brittle-to-ductile transition temperature of the crystalline material structure. One or more stress elements are formed on the crystalline material structure so as to annihilate dislocations or to move them into less harmful locations.

  4. Single particle density of trapped interacting quantum gases

    SciTech Connect (OSTI)

    Bala, Renu; Bosse, J.; Pathak, K. N.

    2015-05-15

    An expression for single particle density for trapped interacting gases has been obtained in first order of interaction using Greens function method. Results are easily simplified for homogeneous quantum gases and are found to agree with famous results obtained by Huang-Yang-Luttinger and Lee-Yang.

  5. High Density Polymer-Based Integrated Electgrode Array

    DOE Patents [OSTI]

    Maghribi, Mariam N.; Krulevitch, Peter A.; Davidson, James Courtney; Hamilton, Julie K.

    2006-04-25

    A high density polymer-based integrated electrode apparatus that comprises a central electrode body and a multiplicity of arms extending from the electrode body. The central electrode body and the multiplicity of arms are comprised of a silicone material with metal features in said silicone material that comprise electronic circuits.

  6. On direct and indirect methanol fuel cells for transportation applications

    SciTech Connect (OSTI)

    Ren, Xiaoming; Wilson, M.S.; Gottesfeld, S.

    1995-09-01

    Power densities in electrolyte Direct Methanol Fuel Cells have been achieved which are only three times lower than those achieved with similar reformate/air fuel cells. Remaining issues are: improved anode catalyst activity, demonstrated long-term stable performance, and high fuel efficiencies.

  7. The effects of low environmental cadmium exposure on bone density

    SciTech Connect (OSTI)

    Trzcinka-Ochocka, M.; Jakubowski, M.; Szymczak, W.; Janasik, B.; Brodzka, R.

    2010-04-15

    Recent epidemiological data indicate that low environmental exposure to cadmium, as shown by cadmium body burden (Cd-U), is associated with renal dysfunction as well as an increased risk of cadmium-induced bone disorders. The present study was designed to assess the effects of low environmental cadmium exposure, at the level sufficient to induce kidney damage, on bone metabolism and mineral density (BMD). The project was conducted in the area contaminated with cadmium, nearby a zinc smelter located in the region of Poland where heavy industry prevails. The study population comprised 170 women (mean age=39.7; 18-70 years) and 100 men (mean age=31.9; 18-76 years). Urinary and blood cadmium and the markers of renal tubular dysfunction ({beta}{sub 2}M-U RBP, NAG), glomerular dysfunction (Alb-U and {beta}{sub 2}M-S) and bone metabolism markers (BAP-S, CTX-S) as well as forearm BMD, were measured. The results of this study based on simple dose-effect analysis showed the relationship between increasing cadmium concentrations and an increased excretion of renal dysfunction markers and decreasing bone density. However, the results of the multivariate analysis did not indicate the association between exposure to cadmium and decrease in bone density. They showed that the most important factors that have impact on bone density are body weight and age in the female subjects and body weight and calcium excretion in males. Our investigation revealed that the excretion of low molecular weight proteins occurred at a lower level of cadmium exposure than the possible loss of bone mass. It seems that renal tubular markers are the most sensitive and significant indicators of early health effects of cadmium intoxication in the general population. The correlation of urinary cadmium concentration with markers of kidney dysfunction was observed in the absence of significant correlations with bone effects. Our findings did not indicate any effects of environmental cadmium exposure on bone

  8. Method for detecting a mass density image of an object (Patent...

    Office of Scientific and Technical Information (OSTI)

    Method for detecting a mass density image of an object Title: Method for detecting a mass density image of an object A method for detecting a mass density image of an object. An ...

  9. Microstructural characterization of in situ MXCT images of high density foams under large strains

    SciTech Connect (OSTI)

    Patterson, Brian M; Gleiman, Seth; Marks, Trevor G; Milstein, Fredrick

    2009-01-01

    Foams are used in numerous applications, such as vibration damping and energy mitigation (e.g., packaging and helmets), wherein their mechanical properties are of critical importance. A typical compressive response of a high density elastomeric foam, shown in Fig 1, generally contains three regions of interest: (I) a linear-elastic region, governed by strut bending; (II) a relatively flat, or slowly increasing stress-strain response, accompanied by strut buckling and the localized collapse of pores; and (III) an exponentially increasing stress-strain curve wherein the collapse of the pore matrix leads to densification. Two material properties of interest, upon which considerable research has focused are the foam's Young's modulus, E{sub f}, defined as the slope of the stress-strain response in region I, and the collapse stress, {sigma}{sub f}, defined as the stress at which the response begins to deviate from linearity. It has been observed [1, 2, 3] that Young's modulus and the collapse stress are dependent on the material properties of the strut material and the non-dimensional relative-density of the foam, {rho}* = {rho}{sub f}/{rho}{sub m}, where {rho}{sub r} is the gross density of the foam and {rho}{sub m} is the density of the strut, or matrix, material. For foam of low relative-density, i.e, {rho}* < 0.1, the collapse stress and Young's modulus obey the relations {sigma}{sub c}/E{sub m} {proportional_to} ({rho}*){sup m} and E{sub f}/E{sub m} {proportional_to} ({rho}*){sup n} where E{sub m} is Young's modulus of the strut material and the bounds on the parameters m and n are 0.05 {le} m {le} 0.2 and 1 {le} n {le} 4 [4]. For open-celled foams, n = 2, whereas for closed-celled foams, n = 3. Theoretically, n = 1 for foams with an ''ideal strut'' configuration [6]. Foams of high relative-density ({rho}* > 0.1) require correcting terms to account for the axial contributions of the ''thick'' struts [5]. The above equations relate important foam properties to the

  10. An x-ray backlit Talbot-Lau deflectometer for high-energy-density electron density diagnostics

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Valdivia, M. P.; Stutman, D.; Stoeckl, C.; Theobald, W.; Mileham, C.; Begishev, I. A.; Bromage, J.; Regan, S. P.

    2016-02-10

    X-ray phase-contrast techniques can measure electron density gradients in high-energy-density plasmas through refraction induced phase shifts. An 8 keV Talbot-Lau interferometer consisting of free standing ultrathin gratings was deployed at an ultra-short, high-intensity laser system using K-shell emission from a 1-30 J, 8 ps laser pulse focused on thin Cu foil targets. Grating survival was demonstrated for 30 J, 8 ps laser pulses. The first x-ray deflectometry images obtained under laser backlighting showed up to 25% image contrast and thus enabled detection of electron areal density gradients with a maximum value of 8.1 ± 0.5 × 1023 cm₋3 in amore » low-Z millimeter sized sample. An electron density profile was obtained from refraction measurements with an error of <8%. We found the 50 ± 15 μm spatial resolution achieved across the full field of view was limited by the x-ray source-size, similar to conventional radiography.« less

  11. Bethe Ansatz Approach to the Kondo Effect within Density-Functional...

    Office of Scientific and Technical Information (OSTI)

    Bethe Ansatz Approach to the Kondo Effect within Density-Functional Theory Prev Next Title: Bethe Ansatz Approach to the Kondo Effect within Density-Functional Theory ...

  12. A novel zirconium K{alpha} imager for high energy density physics...

    Office of Scientific and Technical Information (OSTI)

    for high energy density physics research Citation Details In-Document Search Title: A novel zirconium Kalpha imager for high energy density physics research We report on the ...

  13. High energy density Z-pinch plasmas using flow stabilization

    SciTech Connect (OSTI)

    Shumlak, U. Golingo, R. P. Nelson, B. A. Bowers, C. A. Doty, S. A. Forbes, E. G. Hughes, M. C. Kim, B. Knecht, S. D. Lambert, K. K. Lowrie, W. Ross, M. P. Weed, J. R.

    2014-12-15

    The ZaP Flow Z-Pinch research project[1] at the University of Washington investigates the effect of sheared flows on MHD instabilities. Axially flowing Z-pinch plasmas are produced that are 100 cm long with a 1 cm radius. The plasma remains quiescent for many radial Alfvén times and axial flow times. The quiescent periods are characterized by low magnetic mode activity measured at several locations along the plasma column and by stationary visible plasma emission. Plasma evolution is modeled with high-resolution simulation codes – Mach2, WARPX, NIMROD, and HiFi. Plasma flow profiles are experimentally measured with a multi-chord ion Doppler spectrometer. A sheared flow profile is observed to be coincident with the quiescent period, and is consistent with classical plasma viscosity. Equilibrium is determined by diagnostic measurements: interferometry for density; spectroscopy for ion temperature, plasma flow, and density[2]; Thomson scattering for electron temperature; Zeeman splitting for internal magnetic field measurements[3]; and fast framing photography for global structure. Wall stabilization has been investigated computationally and experimentally by removing 70% of the surrounding conducting wall to demonstrate no change in stability behavior.[4] Experimental evidence suggests that the plasma lifetime is only limited by plasma supply and current waveform. The flow Z-pinch concept provides an approach to achieve high energy density plasmas,[5] which are large, easy to diagnose, and persist for extended durations. A new experiment, ZaP-HD, has been built to investigate this approach by separating the flow Z-pinch formation from the radial compression using a triaxial-electrode configuration. This innovation allows more detailed investigations of the sheared flow stabilizing effect, and it allows compression to much higher densities than previously achieved on ZaP by reducing the linear density and increasing the pinch current. Experimental results and

  14. Process and system for producing high-density pellets from a gaseous medium

    DOE Patents [OSTI]

    Foster, Christopher A.

    1999-01-01

    A process and system for producing pellets of high density carbon dioxide or other gases utilize a chamber containing a plurality of cell-like freezing compartments within which ice is to be formed. A gas desired to be frozen into ice is introduced into the chamber while the internal pressure of the chamber is maintained at a level which is below the equilibrium triple pressure of the gas. The temperature of the freezing compartments is lowered to a temperature which is below the equilibrium vapor pressure temperature of the gas at the chamber pressure so that the gas condenses into ice within the compartments. The temperature of the freezing compartments is thereafter raised so that the ice is thereby released from and falls out of the compartments as pellets for collection.

  15. Combinatorial density functional theory-based screening of surface alloys for the oxygen reduction reaction.

    SciTech Connect (OSTI)

    Greeley, J.; Norskov, J.; Center for Nanoscale Materials; Technical Univ. of Denmark

    2009-03-26

    A density functional theory (DFT) -based, combinatorial search for improved oxygen reduction reaction (ORR) catalysts is presented. A descriptor-based approach to estimate the ORR activity of binary surface alloys, wherein alloying occurs only in the surface layer, is described, and rigorous, potential-dependent computational tests of the stability of these alloys in aqueous, acidic environments are presented. These activity and stability criteria are applied to a database of DFT calculations on nearly 750 binary transition metal surface alloys; of these, many are predicted to be active for the ORR but, with few exceptions, they are found to be thermodynamically unstable in the acidic environments typical of low-temperature fuel cells. The results suggest that, absent other thermodynamic or kinetic mechanisms to stabilize the alloys, surface alloys are unlikely to serve as useful ORR catalysts over extended periods of operation.

  16. Fuel Cells

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and robust solid oxide fuel cell (SOFC) system. Specific objectives include achieving an efficiency of greater than 60 percent, meeting a stack cost target of 175 per kW, and ...

  17. Electrochemical cell

    DOE Patents [OSTI]

    Redey, L.I.; Vissers, D.R.; Prakash, J.

    1996-07-16

    An electrochemical cell is described having a bimodal positive electrode, a negative electrode of an alkali metal, and a compatible electrolyte including an alkali metal salt molten at the cell operating temperature. The positive electrode has an electrochemically active layer of at least one transition metal chloride at least partially present as a charging product, and additives of bromide and/or iodide and sulfur in the positive electrode or the electrolyte. Electrode volumetric capacity is in excess of 400 Ah/cm{sup 3}; the cell can be 90% recharged in three hours and can operate at temperatures below 160 C. There is also disclosed a method of reducing the operating temperature and improving the overall volumetric capacity of an electrochemical cell and for producing a positive electrode having a BET area greater than 6{times}10{sup 4}cm{sup 2}/g of Ni. 6 figs.

  18. Electrochemical cell

    DOE Patents [OSTI]

    Redey, Laszlo I.; Vissers, Donald R.; Prakash, Jai

    1994-01-01

    An electrochemical cell having a bimodal positive electrode, a negative electrode of an alkali metal, and a compatible electrolyte including an alkali metal salt molten at the cell operating temperature. The positive electrode has an electrochemically active layer of at least one transition metal chloride at least partially present as a charging product, and additives of bromide and/or iodide and sulfur in the positive electrode or the electrolyte. Electrode volumetric capacity is in excess of 400 Ah/cm.sup.3 ; the cell can be 90% recharged in three hours and can operate at temperatures below 160.degree. C. There is also disclosed a method of reducing the operating temperature and improving the overall volumetric capacity of an electrochemical cell and for producing a positive electrode having a BET area greater than 6.times.10.sup.4 cm.sup.2 /g of Ni.

  19. Electrochemical cell

    DOE Patents [OSTI]

    Redey, L.I.; Vissers, D.R.; Prakash, J.

    1994-02-01

    An electrochemical cell is described having a bimodal positive electrode, a negative electrode of an alkali metal, and a compatible electrolyte including an alkali metal salt molten at the cell operating temperature. The positive electrode has an electrochemically active layer of at least one transition metal chloride at least partially present as a charging product, and additives of bromide and/or iodide and sulfur in the positive electrode or the electrolyte. Electrode volumetric capacity is in excess of 400 Ah/cm[sup 3]; the cell can be 90% recharged in three hours and can operate at temperatures below 160 C. There is also disclosed a method of reducing the operating temperature and improving the overall volumetric capacity of an electrochemical cell and for producing a positive electrode having a BET area greater than 6[times]10[sup 4] cm[sup 2]/g of Ni. 8 figures.

  20. Electrochemical cell

    DOE Patents [OSTI]

    Redey, Laszlo I.; Vissers, Donald R.; Prakash, Jai

    1996-01-01

    An electrochemical cell having a bimodal positive electrode, a negative electrode of an alkali metal, and a compatible electrolyte including an alkali metal salt molten at the cell operating temperature. The positive electrode has an electrochemically active layer of at least one transition metal chloride at least partially present as a charging product, and additives of bromide and/or iodide and sulfur in the positive electrode or the electrolyte. Electrode volumetric capacity is in excess of 400 Ah/cm.sup.3 ; the cell can be 90% recharged in three hours and can operate at temperatures below 160.degree. C. There is also disclosed a method of reducing the operating temperature and improving the overall volumetric capacity of an electrochemical cell and for producing a positive electrode having a BET area greater than 6.times.10.sup.4 cm.sup.2 /g of Ni.

  1. Dynamics of ionization-induced electron injection in the high density regime of laser wakefield acceleration

    SciTech Connect (OSTI)

    Desforges, F. G.; Paradkar, B. S. Ju, J.; Audet, T. L.; Maynard, G.; Cros, B.; Hansson, M.; Senje, L.; Persson, A.; Lundh, O.; Wahlström, C.-G.; Dobosz-Dufrénoy, S.; Monot, P.; Vay, J.-L.

    2014-12-15

    The dynamics of ionization-induced electron injection in high density (∼1.2 × 10{sup 19} cm{sup −3}) regime of laser wakefield acceleration is investigated by analyzing the betatron X-ray emission. In such high density operation, the laser normalized vector potential exceeds the injection-thresholds of both ionization-injection and self-injection due to self-focusing. In this regime, direct experimental evidence of early on-set of ionization-induced injection into the plasma wave is given by mapping the X-ray emission zone inside the plasma. Particle-In-Cell simulations show that this early on-set of ionization-induced injection, due to its lower trapping threshold, suppresses the trapping of self-injected electrons. A comparative study of the electron and X-ray properties is performed for both self-injection and ionization-induced injection. An increase of X-ray fluence by at least a factor of two is observed in the case of ionization-induced injection due to increased trapped charge compared to self-injection mechanism.

  2. Tunable one-dimensional electron gas carrier densities at nanostructured oxide interfaces

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhang, Lipeng; Xu, Haixuan; Kent, Paul R. C.; Ganesh, Panchapakesan; Cooper, Valentino R.; Zhuang, Houlong L.

    2016-05-06

    The emergence of two-dimensional metallic states at the LaAlO3/SrTiO3 (LAO/STO) heterostructure interface is known to occur at a critical thickness of four LAO over layers. This insulator-to-metal transition can be explained through the polar catastrophe mechanism arising from the divergence of the electrostatic potential at the LAO surface. Here, we demonstrate that nanostructuring can be effective in reducing or eliminating this critical thickness. Employing a modified polar catastrophe" model, we demonstrate that the nanowire heterostructure electrostatic potential diverges more rapidly as a function of layer thickness than in a regular heterostructure. Our first principles calculations indicate that for nanowire heterostructuremore » geometries a one-dimensional electron gas (1DEG) can be induced, consistent with recent experimental observations of 1D conductivity in LAO/STO steps. Similar to LAO/STO 2DEGs, we predict that the 1D charge density will decay laterally within a few unit cells away from the nanowire; thus providing a mechanism for tuning the carrier behavior between 1D and 2D conductivity. Furthermore, our work provides insight into the creation and manipulation of charge density at an oxide heterostructure interface and therefore may be beneficial for future nanoelectronic devices and for the engineering of novel quantum phases.« less

  3. Radical Coupling Reactions in Lignin Synthesis: A Density Functional Theory Study

    SciTech Connect (OSTI)

    Sangha, A. K.; Parks, J. M.; Standaert, R. F.; Ziebell, A.; Davis, M.; Smith, J. C.

    2012-04-26

    Lignin is a complex, heterogeneous polymer in plant cell walls that provides mechanical strength to the plant stem and confers resistance to degrading microbes, enzymes, and chemicals. Lignin synthesis initiates through oxidative radical-radical coupling of monolignols, the most common of which are p-coumaryl, coniferyl, and sinapyl alcohols. Here, we use density functional theory to characterize radical-radical coupling reactions involved in monolignol dimerization. We compute reaction enthalpies for the initial self- and cross-coupling reactions of these monolignol radicals to form dimeric intermediates via six major linkages observed in natural lignin. The 8-O-4, 8-8, and 8-5 coupling are computed to be the most favorable, whereas the 5-O-4, 5-5, and 8-1 linkages are less favorable. Overall, p-coumaryl self- and cross-coupling reactions are calculated to be the most favorable. For cross-coupling reactions, in which each radical can couple via either of the two sites involved in dimer formation, the more reactive of the two radicals is found to undergo coupling at its site with the highest spin density.

  4. Load cell

    DOE Patents [OSTI]

    Spletzer, Barry L.

    2001-01-01

    A load cell combines the outputs of a plurality of strain gauges to measure components of an applied load. Combination of strain gauge outputs allows measurement of any of six load components without requiring complex machining or mechanical linkages to isolate load components. An example six axis load cell produces six independent analog outputs which can be combined to determine any one of the six general load components.

  5. Load cell

    DOE Patents [OSTI]

    Spletzer, Barry L.

    1998-01-01

    A load cell combines the outputs of a plurality of strain gauges to measure components of an applied load. Combination of strain gauge outputs allows measurement of any of six load components without requiring complex machining or mechanical linkages to isolate load components. An example six axis load cell produces six independent analog outputs, each directly proportional to one of the six general load components.

  6. Load cell

    DOE Patents [OSTI]

    Spletzer, B.L.

    1998-12-15

    A load cell combines the outputs of a plurality of strain gauges to measure components of an applied load. Combination of strain gauge outputs allows measurement of any of six load components without requiring complex machining or mechanical linkages to isolate load components. An example six axis load cell produces six independent analog outputs, each directly proportional to one of the six general load components. 16 figs.

  7. Electrochemical cell

    DOE Patents [OSTI]

    Redey, Laszlo I.; Vissers, Donald R.; Prakash, Jai

    1994-01-01

    An electrochemical cell having an alkali metal negative electrode such as sodium and a positive electrode including Ni or transition metals, separated by a .beta." alumina electrolyte and NaAlCl.sub.4 or other compatible material. Various concentrations of a bromine, iodine and/or sulfur containing additive and pore formers are disclosed, which enhance cell capacity and power. The pore formers may be the ammonium salts of carbonic acid or a weak organic acid or oxamide or methylcellulose.

  8. Electrostatic lens to focus an ion beam to uniform density

    DOE Patents [OSTI]

    Johnson, Cleland H.

    1977-01-11

    A focusing lens for an ion beam having a gaussian or similar density profile is provided. The lens is constructed to provide an inner zero electrostatic field, and an outer electrostatic field such that ions entering this outer field are deflected by an amount that is a function of their distance from the edge of the inner field. The result is a beam that focuses to a uniform density in a manner analogous to that of an optical ring lens. In one embodiment, a conically-shaped network of fine wires is enclosed within a cylindrical anode. The wire net together with the anode produces a voltage field that re-directs the outer particles of the beam while the axial particles pass undeflected through a zero field inside the wire net. The result is a focused beam having a uniform intensity over a given target area and at a given distance from the lens.

  9. Method of measuring reactive acoustic power density in a fluid

    DOE Patents [OSTI]

    Wheatley, J.C.; Swift, G.W.; Migliori, A.

    1985-09-03

    A method for determining reactive acoustic power density level and its direction in a fluid using a single sensor is disclosed. In the preferred embodiment, an apparatus for conducting the method, which is termed a thermoacoustic couple, consists of a stack of thin, spaced apart polymeric plates, selected ones of which include multiple bimetallic thermocouple junctions positioned along opposite end edges thereof. The thermocouple junctions are connected in series in the nature of a thermopile, and are arranged so as to be responsive to small temperature differences between the opposite edges of the plates. The magnitude of the temperature difference, as represented by the magnitude of the electrical potential difference generated by the thermopile, is found to be directly related to the level of acoustic power density in the gas. 5 figs.

  10. Spin projection with double hybrid density functional theory

    SciTech Connect (OSTI)

    Thompson, Lee M.; Hratchian, Hrant P.

    2014-07-21

    A spin projected double-hybrid density functional theory is presented that accounts for different scaling of opposite and same spin terms in the second order correction. This method is applied to three dissociation reactions which in the unprojected formalism exhibit significant spin contamination with higher spin states. This gives rise to a distorted potential surface and can lead to poor geometries and energies. The projected method presented is shown to improve the description of the potential over unprojected double hybrid density functional theory. Comparison is made with the reference states of the two double hybrid functionals considered here (B2PLYP and mPW2PLYP) in which the projected potential surface is degraded by an imbalance in the description of dynamic and static correlation.

  11. Carrier Density Modulation in Ge Heterostructure by Ferroelectric Switching

    SciTech Connect (OSTI)

    Ponath, Patrick; Fredrickson, Kurt; Posadas, Agham B.; Ren, Yuan; Vasudevan, Rama K; Okatan, Mahmut Baris; Jesse, Stephen; Aoki, Toshihiro; McCartney, Martha; Smith, David J; Kalinin, Sergei V; Lai, Keji; Demkov, Alexander A.

    2015-01-01

    The development of nonvolatile logic through direct coupling of spontaneous ferroelectric polarization with semiconductor charge carriers is nontrivial, with many issues, including epitaxial ferroelectric growth, demonstration of ferroelectric switching, and measurable semiconductor modulation. Here we report a true ferroelectric field effect carrier density modulation in an underlying Ge(001) substrate by switching of the ferroelectric polarization in the epitaxial c-axis-oriented BaTiO3 (BTO) grown by molecular beam epitaxy (MBE) on Ge. Using density functional theory, we demonstrate that switching of BTO polarization results in a large electric potential change in Ge. Aberration-corrected electron microscopy confirms the interface sharpness, and BTO tetragonality. Electron-energy-loss spectroscopy (EELS) indicates the absence of any low permittivity interlayer at the interface with Ge. Using piezoelectric force microscopy (PFM), we confirm the presence of fully switchable, stable ferroelectric polarization in BTO that appears to be single domain. Using microwave impedance microscopy (MIM), we clearly demonstrate a ferroelectric field effect.

  12. Extreme hydrogen plasma densities achieved in a linear plasma generator

    SciTech Connect (OSTI)

    Rooij, G. J. van; Veremiyenko, V. P.; Goedheer, W. J.; de Groot, B.; Kleyn, A. W.; Smeets, P. H. M.; Versloot, T. W.; Whyte, D. G.; Engeln, R.; Schram, D. C.; Cardozo, N. J. Lopes

    2007-03-19

    A magnetized hydrogen plasma beam was generated with a cascaded arc, expanding in a vacuum vessel at an axial magnetic field of up to 1.6 T. Its characteristics were measured at a distance of 4 cm from the nozzle: up to a 2 cm beam diameter, 7.5x10{sup 20} m{sup -3} electron density, {approx}2 eV electron and ion temperatures, and 3.5 km/s axial plasma velocity. This gives a 2.6x10{sup 24} H{sup +} m{sup -2} s{sup -1} peak ion flux density, which is unprecedented in linear plasma generators. The high efficiency of the source is obtained by the combined action of the magnetic field and an optimized nozzle geometry. This is interpreted as a cross-field return current that leads to power dissipation in the beam just outside the source.

  13. Improved association in a classical density functional theory for water

    SciTech Connect (OSTI)

    Krebs, Eric J.; Schulte, Jeff B.; Roundy, David

    2014-03-28

    We present a modification to our recently published statistical associating fluid theory-based classical density functional theory for water. We have recently developed and tested a functional for the averaged radial distribution function at contact of the hard-sphere fluid that is dramatically more accurate at interfaces than earlier approximations. We now incorporate this improved functional into the association term of our free energy functional for water, improving its description of hydrogen bonding. We examine the effect of this improvement by studying two hard solutes (a hard hydrophobic rod and a hard sphere) and a Lennard-Jones approximation of a krypton atom solute. The improved functional leads to a moderate change in the density profile and a large decrease in the number of hydrogen bonds broken in the vicinity of the hard solutes. We find an improvement of the partial radial distribution for a krypton atom in water when compared with experiment.

  14. Density gradient effects on transverse shear driven lower hybrid waves

    SciTech Connect (OSTI)

    DuBois, Ami M.; Thomas, Edward; Amatucci, William E.; Ganguli, Gurudas

    2014-06-15

    Shear driven instabilities are commonly observed in the near-Earth space, particularly in boundary layer plasmas. When the shear scale length (L{sub E}) is much less than the ion gyro-radius (?{sub i}) but greater than the electron gyro-radius (?{sub e}), the electrons are magnetized in the shear layer, but the ions are effectively un-magnetized. The resulting shear driven instability, the electron-ion hybrid (EIH) instability, is investigated in a new interpenetrating plasma configuration in the Auburn Linear EXperiment for Instability Studies. In order to understand the dynamics of magnetospheric boundary layers, the EIH instability is studied in the presence of a density gradient located at the boundary layer between two plasmas. This paper reports on a recent experiment in which electrostatic lower hybrid waves are identified as the EIH instability, and the effect of a density gradient on the instability properties are investigated.

  15. Sublinear scaling for time-dependent stochastic density functional theory

    SciTech Connect (OSTI)

    Gao, Yi; Neuhauser, Daniel; Baer, Roi; Rabani, Eran

    2015-01-21

    A stochastic approach to time-dependent density functional theory is developed for computing the absorption cross section and the random phase approximation (RPA) correlation energy. The core idea of the approach involves time-propagation of a small set of stochastic orbitals which are first projected on the occupied space and then propagated in time according to the time-dependent Kohn-Sham equations. The evolving electron density is exactly represented when the number of random orbitals is infinite, but even a small number (≈16) of such orbitals is enough to obtain meaningful results for absorption spectrum and the RPA correlation energy per electron. We implement the approach for silicon nanocrystals using real-space grids and find that the overall scaling of the algorithm is sublinear with computational time and memory.

  16. High-density FRC formation studies on FRX-L.

    SciTech Connect (OSTI)

    Taccetti, J. M.; Intrator, Thomas; Zhang, S.; Wurden, G. A.; Begay, D. W.; Mignardot, E. R.; Waganaar, W. J.; Siemon, R. E.; Tuszewski, M. G.; Sanchez, P. G.; Degnan, J. H.; Sommars, W.

    2002-01-01

    FRX-L (Field Reversed configuration experiment - Liner) is a magnetized-target injector for magnetized target fusion (MTF) experiments. It was designed with the goal of producing high-density n-1017 cm3 field reversed configurations (FRCs) and translating them into an aluminum liner (1-mm thick, 10-cm diameter cylindrical shell) for further compression to fusion conditions. Although operation at these high densities leads to shorter FRC lifetimes, our application requires thlat the plasma live only long enough to be translated and compressed, or on the order of 10-20 ps. Careful study of FRC formation in situ will be done in the present experiment to differentiate between effects introduced in future experiments by translation, trapping, and compression of the FRC. We present current results on the optimization of the FRC formation process on RX-L and compare the results with those from past experiments.

  17. Method for detecting a mass density image of an object

    DOE Patents [OSTI]

    Wernick, Miles N.; Yang, Yongyi

    2008-12-23

    A method for detecting a mass density image of an object. An x-ray beam is transmitted through the object and a transmitted beam is emitted from the object. The transmitted beam is directed at an angle of incidence upon a crystal analyzer. A diffracted beam is emitted from the crystal analyzer onto a detector and digitized. A first image of the object is detected from the diffracted beam emitted from the crystal analyzer when positioned at a first angular position. A second image of the object is detected from the diffracted beam emitted from the crystal analyzer when positioned at a second angular position. A refraction image is obtained and a regularized mathematical inversion algorithm is applied to the refraction image to obtain a mass density image.

  18. Method of measuring reactive acoustic power density in a fluid

    DOE Patents [OSTI]

    Wheatley, John C.; Swift, Gregory W.; Migliori, Albert

    1985-01-01

    A method for determining reactive acoustic power density level and its direction in a fluid using a single sensor is disclosed. In the preferred embodiment, an apparatus for conducting the method, which is termed a thermoacoustic couple, consists of a stack of thin, spaced apart polymeric plates, selected ones of which include multiple bimetallic thermocouple junctions positioned along opposite end edges thereof. The thermocouple junctions are connected in series in the nature of a thermopile, and are arranged so as to be responsive to small temperature differences between the opposite edges of the plates. The magnitude of the temperature difference, as represented by the magnitude of the electrical potential difference generated by the thermopile, is found to be directly related to the level of acoustic power density in the gas.

  19. Neutrinoless double-beta decay in covariant density functional theory

    SciTech Connect (OSTI)

    Ring, P.; Yao, J. M.; Song, L. S.; Hagino, K.; Meng, J.

    2015-10-15

    We use covariant density functional theory beyond mean field in order to describe neutrinoless double-beta decay in a fully relativistic way. The dynamic effects of particle-number and angular-momentum conservations as well as shape fluctuations of quadrupole character are taken into account within the generator coordinate method for both initial and final nuclei. The calculations are based on the full relativistic transition operator. The nuclear matrix elements (NME’s) for a large number of possible transitions are investigated. The results are compared with various non-relativistic calculations, in particular also with the density functional theory based on the Gogny force. We find that the non-relativistic approximation is justified and that the total NME’s can be well approximated by the pure axial-vector coupling term. This corresponds to a considerable reduction of the computational effort.

  20. A novel electron density reconstruction method for asymmetrical toroidal plasmas

    SciTech Connect (OSTI)

    Shi, N.; Ohshima, S.; Minami, T.; Nagasaki, K.; Yamamoto, S.; Mizuuchi, T.; Okada, H.; Kado, S.; Kobayashi, S.; Konoshima, S.; Sano, F.; Tanaka, K.; Ohtani, Y.; Zang, L.; Kenmochi, N.

    2014-05-15

    A novel reconstruction method is developed for acquiring the electron density profile from multi-channel interferometric measurements of strongly asymmetrical toroidal plasmas. It is based on a regularization technique, and a generalized cross-validation function is used to optimize the regularization parameter with the aid of singular value decomposition. The feasibility of method could be testified by simulated measurements based on a magnetic configuration of the flexible helical-axis heliotron device, Heliotron J, which has an asymmetrical poloidal cross section. And the successful reconstruction makes possible to construct a multi-channel Far-infrared laser interferometry on this device. The advantages of this method are demonstrated by comparison with a conventional method. The factors which may affect the accuracy of the results are investigated, and an error analysis is carried out. Based on the obtained results, the proposed method is highly promising for accurately reconstructing the electron density in the asymmetrical toroidal plasma.

  1. A NEW RECIPE FOR OBTAINING CENTRAL VOLUME DENSITIES OF PRESTELLAR CORES FROM SIZE MEASUREMENTS

    SciTech Connect (OSTI)

    Tassis, Konstantinos; Yorke, Harold W. [Jet Propulsion Laboratory, California Institute of Technology, Pasadena, CA 91109 (United States)

    2011-07-10

    We propose a simple analytical method for estimating the central volume density of prestellar molecular cloud cores from their column density profiles. Prestellar cores feature a flat central part of the column density and volume density profiles of the same size indicating the existence of a uniform-density inner region. The size of this region is set by the thermal pressure force which depends only on the central volume density and temperature of the core, and can provide a direct measurement of the central volume density. Thus, a simple length measurement can immediately yield a central density estimate independent of any dynamical model for the core and without the need for fitting. Using the radius at which the column density is 90% of the central value as an estimate of the size of the flat inner part of the column density profile yields an estimate of the central volume density within a factor of two for well-resolved cores.

  2. Differential white cell count by centrifugal microfluidics.

    SciTech Connect (OSTI)

    Sommer, Gregory Jon; Tentori, Augusto M.; Schaff, Ulrich Y.

    2010-07-01

    We present a method for counting white blood cells that is uniquely compatible with centrifugation based microfluidics. Blood is deposited on top of one or more layers of density media within a microfluidic disk. Spinning the disk causes the cell populations within whole blood to settle through the media, reaching an equilibrium based on the density of each cell type. Separation and fluorescence measurement of cell types stained with a DNA dye is demonstrated using this technique. The integrated signal from bands of fluorescent microspheres is shown to be proportional to their initial concentration in suspension. Among the current generation of medical diagnostics are devices based on the principle of centrifuging a CD sized disk functionalized with microfluidics. These portable 'lab on a disk' devices are capable of conducting multiple assays directly from a blood sample, embodied by platforms developed by Gyros, Samsung, and Abaxis. [1,2] However, no centrifugal platform to date includes a differential white blood cell count, which is an important metric complimentary to diagnostic assays. Measuring the differential white blood cell count (the relative fraction of granulocytes, lymphocytes, and monocytes) is a standard medical diagnostic technique useful for identifying sepsis, leukemia, AIDS, radiation exposure, and a host of other conditions that affect the immune system. Several methods exist for measuring the relative white blood cell count including flow cytometry, electrical impedance, and visual identification from a stained drop of blood under a microscope. However, none of these methods is easily incorporated into a centrifugal microfluidic diagnostic platform.

  3. Finite-size instabilities in nuclear energy density functionals

    SciTech Connect (OSTI)

    Hellemans, V.; Heenen, P.-H.; Bender, M.

    2012-10-20

    The systematic lack of convergence of self-consistent mean-field calculations with certain parameterizations of the Skyrme energy density functional has been attributed to the appearance of finite-size instabilities. In this contribution, we investigate what happens at the instability associated with the C{sub 0}{sup {Delta}s}s{sub 0} Dot-Operator {Delta}s{sub 0} term in a high-spin state of the superdeformed band in {sup 194}Hg.

  4. Noncanonical Hamiltonian density formulation of hydrodynamics and ideal MHD

    SciTech Connect (OSTI)

    Morrison, P.J.; Greene, J.M.

    1980-04-01

    A new Hamiltonian density formulation of a perfect fluid with or without a magnetic field is presented. Contrary to previous work the dynamical variables are the physical variables, rho, v, B, and s, which form a noncanonical set. A Poisson bracket which satisfies the Jacobi identity is defined. This formulation is transformed to a Hamiltonian system where the dynamical variables are the spatial Fourier coefficients of the fluid variables.

  5. Charge-density patching method for unconventional semiconductor binary systems

    SciTech Connect (OSTI)

    Wang, Lin-Wang

    2002-09-17

    Unconventional semiconductor alloys exhibit many unusual features and are under intensive studies recently. However, as initio methods cannot be applied directly to these systems due to their large sizes. In this work, a motif based charge patching method is introduced to generate the ab initio quality charge densities for these large systems. The resulting eigen energies are almost the same as the original ab initio eigen energies (with 20-50 meV errors).

  6. Frontiers for Discovery in High Energy Density Physics

    SciTech Connect (OSTI)

    Davidson, R. C.; Katsouleas, T.; Arons, J.; Baring, M.; Deeney, C.; Di Mauro, L.; Ditmire, T.; Falcone, R.; Hammer, D.; Hill, W.; Jacak, B.; Joshi, C.; Lamb, F.; Lee, R.; Logan, B. G.; Melissinos, A.; Meyerhofer, D.; Mori, W.; Murnane, M.; Remington, B.; Rosner, R.; Schneider, D.; Silvera, I.; Stone, J.; Wilde, B.; Zajc. W.

    2004-07-20

    The report is intended to identify the compelling research opportunities of high intellectual value in high energy density physics. The opportunities for discovery include the broad scope of this highly interdisciplinary field that spans a wide range of physics areas including plasma physics, laser and particle beam physics, nuclear physics, astrophysics, atomic and molecular physics, materials science and condensed matter physics, intense radiation-matter interaction physics, fluid dynamics, and magnetohydrodynamics

  7. Mineral density volume gradients in normal and diseased human tissues

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Djomehri, Sabra I.; Candell, Susan; Case, Thomas; Browning, Alyssa; Marshall, Grayson W.; Yun, Wenbing; Lau, S. H.; Webb, Samuel; Ho, Sunita P.; Aikawa, Elena

    2015-04-09

    Clinical computed tomography provides a single mineral density (MD) value for heterogeneous calcified tissues containing early and late stage pathologic formations. The novel aspect of this study is that, it extends current quantitative methods of mapping mineral density gradients to three dimensions, discretizes early and late mineralized stages, identifies elemental distribution in discretized volumes, and correlates measured MD with respective calcium (Ca) to phosphorus (P) and Ca to zinc (Zn) elemental ratios. To accomplish this, MD variations identified using polychromatic radiation from a high resolution micro-computed tomography (micro-CT) benchtop unit were correlated with elemental mapping obtained from a microprobe X-raymore » fluorescence (XRF) using synchrotron monochromatic radiation. Digital segmentation of tomograms from normal and diseased tissues (N=5 per group; 40-60 year old males) contained significant mineral density variations (enamel: 2820-3095mg/cc, bone: 570-1415mg/cc, cementum: 1240-1340mg/cc, dentin: 1480-1590mg/cc, cementum affected by periodontitis: 1100-1220mg/cc, hypomineralized carious dentin: 345-1450mg/cc, hypermineralized carious dentin: 1815-2740mg/cc, and dental calculus: 1290-1770mg/cc). A plausible linear correlation between segmented MD volumes and elemental ratios within these volumes was established, and Ca/P ratios for dentin (1.49), hypomineralized dentin (0.32-0.46), cementum (1.51), and bone (1.68) were observed. Furthermore, varying Ca/Zn ratios were distinguished in adapted compared to normal tissues, such as in bone (855-2765) and in cementum (595-990), highlighting Zn as an influential element in prompting observed adaptive properties. Hence, results provide insights on mineral density gradients with elemental concentrations and elemental footprints that in turn could aid in elucidating mechanistic processes for pathologic formations.« less

  8. High density, high-aspect-ratio precision polyimide nanofilters | Argonne

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    National Laboratory High density, high-aspect-ratio precision polyimide nanofilters December 1, 2009 Tweet EmailPrint Collaborative users from Creatv MicroTech, Inc. and Los Alamos National Laboratory, working with CNM's Nanofabrication & Devices Group, have demonstrated a novel fabrication process that produces high-porosity polymer nanofilters with smooth, uniform. and straight pores and high aspect ratios. Nanofilters have a wide range of applications for various size-exclusion-based

  9. Mineral density volume gradients in normal and diseased human tissues

    SciTech Connect (OSTI)

    Djomehri, Sabra I.; Candell, Susan; Case, Thomas; Browning, Alyssa; Marshall, Grayson W.; Yun, Wenbing; Lau, S. H.; Webb, Samuel; Ho, Sunita P.; Aikawa, Elena

    2015-04-09

    Clinical computed tomography provides a single mineral density (MD) value for heterogeneous calcified tissues containing early and late stage pathologic formations. The novel aspect of this study is that, it extends current quantitative methods of mapping mineral density gradients to three dimensions, discretizes early and late mineralized stages, identifies elemental distribution in discretized volumes, and correlates measured MD with respective calcium (Ca) to phosphorus (P) and Ca to zinc (Zn) elemental ratios. To accomplish this, MD variations identified using polychromatic radiation from a high resolution micro-computed tomography (micro-CT) benchtop unit were correlated with elemental mapping obtained from a microprobe X-ray fluorescence (XRF) using synchrotron monochromatic radiation. Digital segmentation of tomograms from normal and diseased tissues (N=5 per group; 40-60 year old males) contained significant mineral density variations (enamel: 2820-3095mg/cc, bone: 570-1415mg/cc, cementum: 1240-1340mg/cc, dentin: 1480-1590mg/cc, cementum affected by periodontitis: 1100-1220mg/cc, hypomineralized carious dentin: 345-1450mg/cc, hypermineralized carious dentin: 1815-2740mg/cc, and dental calculus: 1290-1770mg/cc). A plausible linear correlation between segmented MD volumes and elemental ratios within these volumes was established, and Ca/P ratios for dentin (1.49), hypomineralized dentin (0.32-0.46), cementum (1.51), and bone (1.68) were observed. Furthermore, varying Ca/Zn ratios were distinguished in adapted compared to normal tissues, such as in bone (855-2765) and in cementum (595-990), highlighting Zn as an influential element in prompting observed adaptive properties. Hence, results provide insights on mineral density gradients with elemental concentrations and elemental footprints that in turn could aid in elucidating mechanistic processes for pathologic formations.

  10. Method and apparatus for measuring lung density by Compton backscattering

    DOE Patents [OSTI]

    Loo, Billy W.; Goulding, Frederick S.

    1991-01-01

    The density of the lung of a patient suffering from pulmonary edema is monitored by irradiating the lung by a single collimated beam of monochromatic photons and measuring the energies of photons Compton backscattered from the lung by a single high-resolution, high-purity germanium detector. A compact system geometry and a unique data extraction scheme are utilized to monimize systematic errors due to the presence of the chestwall and multiple scattering.

  11. Method and apparatus for measuring lung density by Compton backscattering

    DOE Patents [OSTI]

    Loo, B.W.; Goulding, F.S.

    1988-03-11

    The density of the lung of a patient suffering from pulmonary edema is monitored by irradiating the lung by a single collimated beam of monochromatic photons and measuring the energies of photons compton back-scattered from the lung by a single high-resolution, high-purity germanium detector. A compact system geometry and a unique data extraction scheme are utilized to minimize systematic errors due to the presence of the chestwall and multiple scattering. 11 figs., 1 tab.

  12. 2D Monolayers Could Yield Thinnest Solar Cells Ever

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Thinnest solar cells ever 2D Monolayers Could Yield Thinnest Solar Cells Ever October 21, 2013 Contact: Kathy Kincade, +1 510 495 2124, kkincade@lbl.gov Efforts to improve solar cells have historically focused on improving energy conversion efficiencies and lowering manufacturing costs. But new computer simulations have shown how using a different type of material could yield thinner, more lightweight solar panels that provide power densities - watts per kilogram of material - orders of

  13. The transition to the metallic state in low density hydrogen

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    McMinis, Jeremy; Morales, Miguel A.; Ceperley, David M.; Kim, Jeongnim

    2015-11-18

    Solid atomic hydrogen is one of the simplest systems to undergo a metal-insulator transition. Near the transition, the electronic degrees of freedom become strongly correlated and their description provides a difficult challenge for theoretical methods. As a result, the order and density of the phase transition are still subject to debate. In this work we use diffusion quantum Monte Carlo to benchmark the transition between the paramagnetic and anti-ferromagnetic phases of ground state body centered cubic atomic hydrogen. We locate the density of the transition by computing the equation of state for these two phases and identify the phase transitionmore » order by computing the band gap near the phase transition. These benchmark results show that the phase transition is continuous and occurs at a Wigner-Seitz radius of rs = 2.27(3)a0. As a result, we compare our results to previously reported density functional theory, Hedin s GW approximation, and dynamical mean field theory results.« less

  14. Calibration models for density borehole logging - construction report

    SciTech Connect (OSTI)

    Engelmann, R.E.; Lewis, R.E.; Stromswold, D.C.

    1995-10-01

    Two machined blocks of magnesium and aluminum alloys form the basis for Hanford`s density models. The blocks provide known densities of 1.780 {plus_minus} 0.002 g/cm{sup 3} and 2.804 {plus_minus} 0.002 g/cm{sup 3} for calibrating borehole logging tools that measure density based on gamma-ray scattering from a source in the tool. Each block is approximately 33 x 58 x 91 cm (13 x 23 x 36 in.) with cylindrical grooves cut into the sides of the blocks to hold steel casings of inner diameter 15 cm (6 in.) and 20 cm (8 in.). Spacers that can be inserted between the blocks and casings can create air gaps of thickness 0.64, 1.3, 1.9, and 2.5 cm (0.25, 0.5, 0.75 and 1.0 in.), simulating air gaps that can occur in actual wells from hole enlargements behind the casing.

  15. The transition to the metallic state in low density hydrogen

    SciTech Connect (OSTI)

    McMinis, Jeremy; Morales, Miguel A.; Ceperley, David M.; Kim, Jeongnim

    2015-11-18

    Solid atomic hydrogen is one of the simplest systems to undergo a metal-insulator transition. Near the transition, the electronic degrees of freedom become strongly correlated and their description provides a difficult challenge for theoretical methods. As a result, the order and density of the phase transition are still subject to debate. In this work we use diffusion quantum Monte Carlo to benchmark the transition between the paramagnetic and anti-ferromagnetic phases of ground state body centered cubic atomic hydrogen. We locate the density of the transition by computing the equation of state for these two phases and identify the phase transition order by computing the band gap near the phase transition. These benchmark results show that the phase transition is continuous and occurs at a Wigner-Seitz radius of rs = 2.27(3)a0. As a result, we compare our results to previously reported density functional theory, Hedin s GW approximation, and dynamical mean field theory results.

  16. Silylation of low-density silica and bridged polysilsesquioxane aerogels

    SciTech Connect (OSTI)

    DeFriend, K. A. (Kimberly A.); Loy, D. A. (Douglas A.); Salazar, K. V. (Kenneth V.); Wilson, K. V. (Kennard V.)

    2004-01-01

    Silica and bridged polysilsesquioxane aerogels are low-density materials that are attractive for applications such as thermal insulation, porous separation media or catalyst supports, adsorbents, and cometary dust capture agents. However, aerogels are notoriously weak and brittle making it difficult to handle and machine monoliths into desired forms. This complication prevents the development of many applications that would otherwise benefit from the use of the low-density materials. Here, we will describe our efforts to chemically modify and mechanically enhance silica-based aerogels using chemical vapor techniques without sacrificing their characteristic low densities. Monolithic silica and organic-bridged polysilsesquioxane aerogels were prepared by sol-gel polymerization of the respective methoxysilane monomers followed by supercritical carbon dioxide drying of the gels. Then the gels were reactively modified with silylating agents to demonstrate the viability of CVD modification of aerogels, and to determine the effects of silylation of surface silanols on the morphology, surface area, and mechanical properties of the resulting aerogels.

  17. NEUTRONIC REACTOR HAVING LOCALIZED AREAS OF HIGH THERMAL NEUTRON DENSITIES

    DOE Patents [OSTI]

    Newson, H.W.

    1958-06-01

    A nuclear reactor for the irradiation of materials designed to provide a localized area of high thermal neutron flux density in which the materials to be irradiated are inserted is described. The active portion of the reactor is comprised of a cubicle graphite moderator of about 25 feet in length along each axis which has a plurality of cylindrical channels for accommodatirg elongated tubular-shaped fuel elements. The fuel elements have radial fins for spacing the fuel elements from the channel walls, thereby providing spaces through which a coolant may be passed, and also to serve as a heatconductirg means. Ducts for accommnodating the sample material to be irradiated extend through the moderator material perpendicular to and between parallel rows of fuel channels. The improvement is in the provision of additional fuel element channels spaced midway between 2 rows of the regular fuel channels in the localized area surrounding the duct where the high thermal neutron flux density is desired. The fuel elements normally disposed in the channels directly adjacent the duct are placed in the additional channels, and the channels directly adjacent the duct are plugged with moderator material. This design provides localized areas of high thermal neutron flux density without the necessity of providing additional fuel material.

  18. Compacted carbon for electrochemical cells

    DOE Patents [OSTI]

    Greinke, R.A.; Lewis, I.C.

    1997-10-14

    This invention provides compacted carbon that is useful in the electrode of an alkali metal/carbon electrochemical cell of improved capacity selected from the group consisting of: (a) coke having the following properties: (1) an x-ray density of at least 2.00 grams per cubic centimeters, (2) a closed porosity of no greater than 5%, and (3) an open porosity of no greater than 47%; and (b) graphite having the following properties: (1) an x-ray density of at least 2.20 grams per cubic centimeters, (2) a closed porosity of no greater than 5%, and (3) an open porosity of no greater than 25%. This invention also relates to an electrode for an alkali metal/carbon electrochemical cell comprising compacted carbon as described above and a binder. This invention further provides an alkali metal/carbon electrochemical cell comprising: (a) an electrode as described above, (b) a non-aqueous electrolytic solution comprising an organic aprotic solvent and an electrolytically conductive salt and an alkali metal, and (c) a counter electrode. 10 figs.

  19. Compacted carbon for electrochemical cells

    DOE Patents [OSTI]

    Greinke, Ronald Alfred; Lewis, Irwin Charles

    1997-01-01

    This invention provides compacted carbon that is useful in the electrode of an alkali metal/carbon electrochemical cell of improved capacity selected from the group consisting of: (a) coke having the following properties: (i) an x-ray density of at least 2.00 grams per cubic centimeters, (ii) a closed porosity of no greater than 5%, and (iii) an open porosity of no greater than 47%; and (b) graphite having the following properties: (i) an x-ray density of at least 2.20 grams per cubic centimeters, (ii) a closed porosity of no greater than 5%, and (iii) an open porosity of no greater than 25%. This invention also relates to an electrode for an alkali metal/carbon electrochemical cell comprising compacted carbon as described above and a binder. This invention further provides an alkali metal/carbon electrochemical cell comprising: (a) an electrode as described above, (b) a non-aqueous electrolytic solution comprising an organic aprotic solvent and an electrolytically conductive salt and an alkali metal, and (c) a counterelectrode.

  20. 'Nano'tubes, Surface Area & NanoSolar Cells

    K-12 Energy Lesson Plans and Activities Web site (EERE)

    This unit takes students through several introductory lessons designed to gain a better understanding of the 'nano' scale as it relates to the creation of a (dye-sensitized) solar cell (DSSC). The introductory lessons guide students through activities covering volume, surface area and density and exploration of the relationship between these factors. The unit culminates with students building a Gratzel cell, a solar cell employing a layer of nanospheres of TiO2 as the semiconductor and blackberry juice as the light absorber in a non-Si-based solar cell. Students are able to build a small solar cell and test its efficiency.