National Library of Energy BETA

Sample records for dendrite lacy needle

  1. Three-dimensional Dendritic Needle Network model with application...

    Office of Scientific and Technical Information (OSTI)

    the primary dendrite arm spacing that is significantly over-estimated by 2D simulations. ... Type: Accepted Manuscript Journal Name: IOP Conference Series. Materials Science and ...

  2. Three-dimensional Dendritic Needle Network model with application to Al-Cu directional solidification experiments

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tourret, D.; Karma, A.; Clarke, A. J.; Gibbs, P. J.; Imhoff, S. D.

    2015-06-11

    We present a three-dimensional (3D) extension of a previously proposed multi-scale Dendritic Needle Network (DNN) approach for the growth of complex dendritic microstructures. Using a new formulation of the DNN dynamics equations for dendritic paraboloid-branches of a given thickness, one can directly extend the DNN approach to 3D modeling. We validate this new formulation against known scaling laws and analytical solutions that describe the early transient and steady-state growth regimes, respectively. Finally, we compare the predictions of the model to in situ X-ray imaging of Al-Cu alloy solidification experiments. The comparison shows a very good quantitative agreement between 3D simulationsmore » and thin sample experiments. It also highlights the importance of full 3D modeling to accurately predict the primary dendrite arm spacing that is significantly over-estimated by 2D simulations.« less

  3. lacis-99.PDF

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    GCM Aerosols and Sub-Grid Cloud Heterogeneity A. A. Lacis, B. Cairns, C. Dello, and W. B. Rossow National Aeronautics and Space Administration Goddard Institute for Space Studies New York, New York Introduction In the terrestrial climate system, clouds and aerosols exhibit a great deal of spatial and temporal variability. This makes it difficult both to characterize fully their radiative properties from observations and to model accurately their radiative forcing in climate simulations with

  4. lacis-98.p;df

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Radiation Treatment in the GISS GCM A. A. Lacis, V. Oinas, and B. Cairns NASA-Goddard Institute for Space Studies New York, New York Introduction The primary role of radiative transfer calculations in climate general circulation models (GCMs) is to provide accurate heating and cooling rates for the radiative energy terms in the fundamental equations. A secondary role is to represent GCM physical processes in terms of radiative quantities that can be effectively compared to satellite and

  5. Microsoft PowerPoint - 06_ARM_AWG_Lacis_2007.ppt [Compatibility Mode]

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Geoengineering: Geoengineering: Plan B Remedy for Global Warming y g Andy Lacis Aerosol Working Group 26 March 2007 Some Radiative Aspects of Proposed Geoengineering Countermeasures to Global Warming (submitted to PNAS) g ( ) Andrew A. Lacis, Jennifer L. Alltop, Solomon M. Hsiang, Kirk D. Knobelspiesse, Jing Li, Cindy B. Pearl Accelerated melting of Greenland ice due to global warming . . . How can aerosols be used to counteract global warming? * Injection of sulfur into the lower stratosphere *

  6. Dendrite inhibitor

    DOE Patents [OSTI]

    Miller, William E.

    1989-01-01

    An apparatus for removing dendrites or other crystalline matter from the surface of a liquid in a matter transport process, and an electrolytic cell including such an apparatus. A notch may be provided to allow continuous exposure of the liquid surface, and a bore may be further provided to permit access to the liquid.

  7. Dendrite inhibitor

    DOE Patents [OSTI]

    Miller, W.E.

    1988-06-07

    An apparatus for removing dendrites or other crystalline matter from the surface of a liquid in a matter transport process, and an electrolytic cell including such an apparatus. A notch may be provided to allow continuous exposure of the liquid surface, and a bore may be further provided to permit access to the liquid. 2 figs.

  8. Dendritic metal nanostructures

    DOE Patents [OSTI]

    Shelnutt, John A.; Song, Yujiang; Pereira, Eulalia F.; Medforth, Craig J.

    2010-08-31

    Dendritic metal nanostructures made using a surfactant structure template, a metal salt, and electron donor species.

  9. ElectroNeedle

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... For example, a foot-and-mouth out- break in 2001 cost Great Britain an estimated ... that ElectroNeedles(tm) will find their first implementation in veterinary applications. ...

  10. ElectroNeedle

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ElectroNeedle  (tm) Biomedical Sensor Array 2007 R&D 100 Award Entry Form ElectroNeedle  (tm) Biomedical Sensor Array Sandia National Laboratories PO Box 5800, MS 1425 Albuquerque, NM 87185-1425 USA Stephen Casalnuovo (505) 844-6097 (505) 844-1198 (Fax) sacasal@sandia.gov AFFIRMATION: I affirm that all information submitted as a part of, or supplemental to, this entry is a fair and accurate represen- tation of this product. (Signature)______________________________________ Not

  11. Three-dimensional Dendritic Needle Network model with application...

    Office of Scientific and Technical Information (OSTI)

    We present a three-dimensional (3D) extension of a previously proposed multi-scale ... of a given thickness, one can directly extend the DNN approach to 3D modeling. ...

  12. Needle Federated Search Engine

    Energy Science and Technology Software Center (OSTI)

    2009-12-01

    The Idaho National Laboratory (INL) has combined a number of technologies, tools, and resources to accomplish a new means of federating search results. The resulting product is a search engine called Needle, an open-source-based tool that the INL uses internally for researching across a wide variety of information repositories. Needle has a flexible search interface that allows end users to point at any available data source. A user can select multiple sources such as commercialmore » databases (Web of Science, Engineering Index), external resources (WorldCat, Google Scholar), and internal corporate resources (email, document management system, library collections) in a single interface with one search query. In the future, INL hopes to offer this open-source engine to the public. This session will outline the development processes for making Needle™s search interface and simplifying the federation of internal and external data sources.« less

  13. Needle bar for warp knitting machines

    DOE Patents [OSTI]

    Hagel, Adolf; Thumling, Manfred

    1979-01-01

    Needle bar for warp knitting machines with a number of needles individually set into slits of the bar and having shafts cranked to such an extent that the head section of each needle is in alignment with the shaft section accommodated by the slit. Slackening of the needles will thus not influence the needle spacing.

  14. Stability of dendritic arrays

    SciTech Connect (OSTI)

    Warren, J.A. ); Langer, J.S. )

    1990-09-15

    We propose an approximate method for studying steady-state properties and linear stability of the dendritic arrays that are formed in directional solidification of alloys. Our analysis is valid at high growth rates where the primary spacing between dendrites is larger than the velocity-dependent solutal diffusion length. We compute a neutral stability boundary and find that, in the situations where we expect our results to be valid, the experimental data of Somboonsuk, Mason, and Trivedi (Metall. Trans. A 15A, 967 (1984)) lie in the stable region, well away from the boundary.

  15. Lithium Dendrite Formation

    SciTech Connect (OSTI)

    2015-03-06

    Scientists at the Department of Energy’s Oak Ridge National Laboratory have captured the first real-time nanoscale images of lithium dendrite structures known to degrade lithium-ion batteries. The ORNL team’s electron microscopy could help researchers address long-standing issues related to battery performance and safety. Video shows annular dark-field scanning transmission electron microscopy imaging (ADF STEM) of lithium dendrite nucleation and growth from a glassy carbon working electrode and within a 1.2M LiPF6 EC:DM battery electrolyte.

  16. In vivo expression of the lacY gene in two segments leads to functional lac permease

    SciTech Connect (OSTI)

    Bibi, E.; Kaback, H.R. )

    1990-06-01

    The lacY gene of Escherichia coli was cut into two approximately equal-size fragments with Afl II and subcloned individually or together under separate lac operator/promoters in plasmid pT7-5. Under these conditions, lac permease is expressed in two portions: (i) the N-terminal portion (the N terminus, the first six putative transmembrane helices, and most of putative loop 7) and (ii) the C-terminal portion (the last six putative transmembrane helices and the C terminus). Cells harboring pT7-5 encoding both fragments transport lactose at about 30% the rate of cells expressing intact permease to a comparable steady-state level of accumulation. In contrast, cells expressing either half of the permease independently do not transport lactose. As judged by ({sup 35}S)methionine labeling and immunoblotting, intact permease in completely absent from the membrane of cells expressing lacY fragments either individually or together. Thus, transport activity must result from an association between independently synthesized pieces of lac permease. When the gene fragments are expressed individually, the N-terminal portion of the permease is observed inconsistently, and the C-terminal portion is not observed. When the gene fragments are expressed together, polypeptides identified as the N- and C-terminal moieties of the permease are found in the membrane. It is concluded that the N- or C-terminal halves of lac permease are proteolyzed when synthesized independently and that association between the two complementing polypeptides leads to a more stable, catalytically active complex.

  17. Three-dimensional multiscale modeling of dendritic spacing selection during Al-Si directional solidification

    SciTech Connect (OSTI)

    Tourret, Damien; Clarke, Amy J.; Imhoff, Seth D.; Gibbs, Paul J.; Gibbs, John W.; Karma, Alain

    2015-05-27

    We present a three-dimensional extension of the multiscale dendritic needle network (DNN) model. This approach enables quantitative simulations of the unsteady dynamics of complex hierarchical networks in spatially extended dendritic arrays. We apply the model to directional solidification of Al-9.8 wt.%Si alloy and directly compare the model predictions with measurements from experiments with in situ x-ray imaging. The focus is on the dynamical selection of primary spacings over a range of growth velocities, and the influence of sample geometry on the selection of spacings. Simulation results show good agreement with experiments. The computationally efficient DNN model opens new avenues for investigating the dynamics of large dendritic arrays at scales relevant to solidification experiments and processes.

  18. Three-dimensional multiscale modeling of dendritic spacing selection during Al-Si directional solidification

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tourret, Damien; Clarke, Amy J.; Imhoff, Seth D.; Gibbs, Paul J.; Gibbs, John W.; Karma, Alain

    2015-05-27

    We present a three-dimensional extension of the multiscale dendritic needle network (DNN) model. This approach enables quantitative simulations of the unsteady dynamics of complex hierarchical networks in spatially extended dendritic arrays. We apply the model to directional solidification of Al-9.8 wt.%Si alloy and directly compare the model predictions with measurements from experiments with in situ x-ray imaging. The focus is on the dynamical selection of primary spacings over a range of growth velocities, and the influence of sample geometry on the selection of spacings. Simulation results show good agreement with experiments. The computationally efficient DNN model opens new avenues formore » investigating the dynamics of large dendritic arrays at scales relevant to solidification experiments and processes.« less

  19. Assembly of a Molecular Needle, from the Bottom Up

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Inset: Electron micrograph of the needle complex. The TTSS needle complex is found in gram-negative bacteria (e.g. Yersinia, Shigella, Salmonella, Pseudomonas, and E. coli),...

  20. Reflection Survey At The Needles Area (DOE GTP) | Open Energy...

    Open Energy Info (EERE)

    The Needles Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Reflection Survey At The Needles Area (DOE GTP) Exploration Activity...

  1. Geothermometry At The Needles Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    The Needles Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At The Needles Area (DOE GTP) Exploration Activity...

  2. Cuttings Analysis At The Needles Area (DOE GTP) | Open Energy...

    Open Energy Info (EERE)

    The Needles Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Cuttings Analysis At The Needles Area (DOE GTP) Exploration Activity...

  3. Observation Wells At The Needles Area (DOE GTP) | Open Energy...

    Open Energy Info (EERE)

    The Needles Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Observation Wells At The Needles Area (DOE GTP) Exploration Activity...

  4. Development Wells At The Needles Area (DOE GTP) | Open Energy...

    Open Energy Info (EERE)

    The Needles Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Development Wells At The Needles Area (DOE GTP) Exploration Activity...

  5. Demand for superpremium needle cokes on upswing

    SciTech Connect (OSTI)

    Acciarri, J.A.; Stockman, G.H. )

    1989-12-01

    The authors discuss how recent supply shortages of super-premium quality needle cokes, plus the expectation of increased shortfalls in the future, indicate that refiners should consider upgrading their operations to fill these demands. Calcined, super-premium needle cokes are currently selling for as much as $550/metric ton, fob producer, and increasing demand will continue the upward push of the past year. Needle coke, in its calcined form, is the major raw material in the manufacture of graphite electrodes. Used in steelmaking, graphite electrodes are the electrical conductors that supply the heat source, through arcing electrode column tips, to electric arc steel furnaces. Needle coke is commercially available in three grades - super premium, premium, and intermediate. Super premium is used to produce electrodes for the most severe electric arc furnace steelmaking applications, premium for electrodes destined to less severe operations, and intermediate for even less critical needs.

  6. Method of inhibiting dislocation generation in silicon dendritic webs

    DOE Patents [OSTI]

    Spitznagel, John A.; Seidensticker, Raymond G.; McHugh, James P.

    1990-11-20

    A method of tailoring the heat balance of the outer edge of the dendrites adjacent the meniscus to produce thinner, smoother dendrites, which have substantially less dislocation sources contiguous with the dendrites, by changing the view factor to reduce radiation cooling or by irradiating the dendrites with light from a quartz lamp or a laser to raise the temperature of the dendrites.

  7. Medically relevant ElectroNeedle technology development.

    SciTech Connect (OSTI)

    Schmidt, Carrie Frances; Thomas, Michael Loren; McClain, Jaime L.; Harper, Jason C.; Achyuthan, Komandoor E.; Ten Eyck, Gregory A.

    2008-11-01

    ElectroNeedles technology was developed as part of an earlier Grand Challenge effort on Bio-Micro Fuel Cell project. During this earlier work, the fabrication of the ElectroNeedles was accomplished along with proof-of-concept work on several electrochemically active analytes such as glucose, quinone and ferricyanide. Additionally, earlier work demonstrated technology potential in the field of immunosensors by specifically detecting Troponin, a cardiac biomarker. The current work focused upon fabrication process reproducibility of the ElectroNeedles and then using the devices to sensitively detect p-cresol, a biomarker for kidney failure or nephrotoxicity. Valuable lessons were learned regarding fabrication assurance and quality. The detection of p-cresol was accomplished by electrochemistry as well as using fluorescence to benchmark ElectroNeedles performance. Results from these studies will serve as a guide for the future fabrication processes involving ElectroNeedles as well as provide the groundwork necessary to expand technology applications. One paper has been accepted for publication acknowledging LDRD funding (K. E. Achyuthan et al, Comb. Chem. & HTS, 2008). We are exploring the scope for a second paper describing the applications potential of this technology.

  8. Assembly of a Molecular Needle, from the Bottom Up

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    micrograph of the needle complex. The TTSS needle complex is found in gram-negative bacteria (e.g. Yersinia, Shigella, Salmonella, Pseudomonas, and E. coli), which are all...

  9. Synthesis of nano-crystalline multifibrous zirconia needle

    SciTech Connect (OSTI)

    Biswas, Mridula; Bandyopadhyay, Siddhartha

    2013-06-01

    Graphical abstract: - Highlights: Zirconia needles have been successfully prepared by simple inorganic solgel route. The shape of the needles was retained after firing with aspect ratio > 400. Needles are composed of multiple fibres. Fibres are composed of nano crystals. - Abstract: Zirconia needles have been successfully synthesized using a simple inorganic solgel process without using any template. The method employs mixture of zirconium oxychloride octahydrate and sulphuric acid in aqueous medium. This process requires heat treatment at 40 C for 2 h in an oven for nucleus formation. Complete formation of needle occurs after 17 days. The green needle retained its original shape after calcination at 1200 C. Fired needles were of 12 cm in length and 550 ?m in diameter and possess monoclinic phase. Needles are composed of multiple fibres. Depending on the heat treatment temperature, crystallite size varies in the range of 8 to around 300 nm.

  10. Dual mode fuel injector with one piece needle valve member

    DOE Patents [OSTI]

    Lawrence, Keith E.; Hinrichsen, Michael H.; Buckman, Colby

    2005-01-18

    A fuel injector includes a homogenous charge nozzle outlet set and a conventional nozzle outlet set controlled respectively by inner and outer needle value members. The homogenous charged nozzle outlet set is defined by an outer needle value member that is moveably positioned in an injector body, which defines the conventional nozzle outlet set. The inner needle valve member is positioned in the outer needle valve member. The outer needle valve member is a piece component that includes at least one external guide surface, an external value surface and an internal valve seat.

  11. Mixed mode fuel injector with individually moveable needle valve members

    DOE Patents [OSTI]

    Stewart, Chris; Chockley, Scott A.; Ibrahim, Daniel R.; Lawrence, Keith; Tomaseki, Jay; Azam, Junru H.; Tian, Steven Ye; Shafer, Scott F.

    2004-08-03

    A fuel injector includes a homogenous charge nozzle outlet set and a conventional nozzle outlet set controlled respectively, by first and second needle valve members. One of the needle valve members moves to an open position while the other needle valve member remains stationary for a homogeneous charge injection event. The former needle valve member stays stationary while the other needle valve member moves to an open position for a conventional injection event. One of the needle valve members is at least partially positioned in the other needle valve member. Thus, the injector can perform homogeneous charge injection events, conventional injection events, or even a mixed mode having both types of injection events in a single engine cycle.

  12. Assembly of a Molecular Needle, from the Bottom Up

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Assembly of a Molecular Needle, from the Bottom Up Assembly of a Molecular Needle, from the Bottom Up Print Wednesday, 21 December 2005 00:00 Many pathogenic bacteria use a specialized secretion system to inject virulence proteins directly into the cells they infect. The injected proteins, by mimicking host-cell mechanisms, can then subvert normal cellular function. The type III secretion system (TTSS) is a sophisticated protein complex with an overall shape similar to a hypodermic needle. More

  13. Modeling-Computer Simulations At The Needles Area (Bell & Ramelli...

    Open Energy Info (EERE)

    navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Modeling-Computer Simulations At The Needles Area (Bell & Ramelli, 2009) Exploration Activity Details...

  14. A Shape Memory Polymer Dialysis Needle Adapter for the Reduction...

    Office of Scientific and Technical Information (OSTI)

    A Shape Memory Polymer Dialysis Needle Adapter for the Reduction of Hemodynamic Stress within Arteriovenous Grafts Citation Details In-Document Search Title: A Shape Memory Polymer ...

  15. ALS Technique Gives Novel View of Lithium Battery Dendrite Growth

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS Technique Gives Novel View of Lithium Battery Dendrite Growth ALS Technique Gives Novel View of Lithium Battery Dendrite Growth Print Thursday, 24 April 2014 09:46 Lithium-ion ...

  16. Acoustic Logs At The Needles Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    The Needles Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Acoustic Logs At The Needles Area (DOE GTP) Exploration Activity...

  17. Resistivity Log At The Needles Area (DOE GTP) | Open Energy Informatio...

    Open Energy Info (EERE)

    The Needles Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Resistivity Log At The Needles Area (DOE GTP) Exploration Activity...

  18. Field Mapping At The Needles Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Field Mapping At The Needles Area (DOE GTP) Exploration Activity Details Location The Needles Area...

  19. Flow Test At The Needles Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Flow Test At The Needles Area (DOE GTP) Exploration Activity Details Location The Needles Area...

  20. Apparatus for growing a dendritic web

    DOE Patents [OSTI]

    Duncan, Charles S.; Piotrowski, Paul A.; Skutch, Maria E.; McHugh, James P.

    1983-06-21

    A melt system including a susceptor-crucible assembly having improved gradient control when melt replenishment is used during dendritic web growth. The improvement lies in the formation of a thermal barrier in the base of the receptor which is in the form of a vertical slot in the region of the susceptor underlying the crucible at the location of a compartmental separator dividing the crucible into a growth compartment and a melt replenishment compartment. The result achieved is a step change in temperature gradient in the melt thereby providing a more uniform temperature in the growth compartment from which the dendritic web is drawn.

  1. Hyper-dendritic nanoporous zinc foam anodes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chamoun, Mylad; Hertzberg, Benjamin J.; Gupta, Tanya; Davies, Daniel; Bhadra, Shoham; Van Tassell, Barry.; Erdonmez, Can; Steingart, Daniel A.

    2015-04-24

    The low cost, significant reducing potential, and relative safety of the zinc electrode is a common hope for a reductant in secondary batteries, but it is limited mainly to primary implementation due to shape change. In this work we exploit such shape change for the benefit of static electrodes through the electrodeposition of hyper-dendritic nanoporous zinc foam. Electrodeposition of zinc foam resulted in nanoparticles formed on secondary dendrites in a three-dimensional network with a particle size distribution of 54.1 - 96.0 nm. The nanoporous zinc foam contributed to highly oriented crystals, high surface area and more rapid kinetics in contrastmore » to conventional zinc in alkaline mediums. The anode material presented had a utilization of ~ 88% at full depth-of-discharge at various rates indicating a superb rate-capability. The rechargeability of Zn⁰/Zn²⁺ showed significant capacity retention over 100 cycles at a 40% depth-of-discharge to ensure that the dendritic core structure was imperforated. The dendritic architecture was densified upon charge-discharge cycling and presented superior performance compared to bulk zinc electrodes.« less

  2. Assembly of a Molecular Needle, from the Bottom Up

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in gram-negative bacteria (e.g. Yersinia, Shigella, Salmonella, Pseudomonas, and E. coli), which are all characterized by a double-membrane cell wall. The needle complex spans...

  3. Assembly of a Molecular Needle, from the Bottom Up

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Assembly of a Molecular Needle, from the Bottom Up Print Many pathogenic bacteria use a specialized secretion system to inject virulence proteins directly into the cells they infect. The injected proteins, by mimicking host-cell mechanisms, can then subvert normal cellular function. The type III secretion system (TTSS) is a sophisticated protein complex with an overall shape similar to a hypodermic needle. More than twenty unique types of proteins are required for its assembly, most of which are

  4. Assembly of a Molecular Needle, from the Bottom Up

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Assembly of a Molecular Needle, from the Bottom Up Print Many pathogenic bacteria use a specialized secretion system to inject virulence proteins directly into the cells they infect. The injected proteins, by mimicking host-cell mechanisms, can then subvert normal cellular function. The type III secretion system (TTSS) is a sophisticated protein complex with an overall shape similar to a hypodermic needle. More than twenty unique types of proteins are required for its assembly, most of which are

  5. Assembly of a Molecular Needle, from the Bottom Up

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Assembly of a Molecular Needle, from the Bottom Up Print Many pathogenic bacteria use a specialized secretion system to inject virulence proteins directly into the cells they infect. The injected proteins, by mimicking host-cell mechanisms, can then subvert normal cellular function. The type III secretion system (TTSS) is a sophisticated protein complex with an overall shape similar to a hypodermic needle. More than twenty unique types of proteins are required for its assembly, most of which are

  6. Assembly of a Molecular Needle, from the Bottom Up

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Assembly of a Molecular Needle, from the Bottom Up Print Many pathogenic bacteria use a specialized secretion system to inject virulence proteins directly into the cells they infect. The injected proteins, by mimicking host-cell mechanisms, can then subvert normal cellular function. The type III secretion system (TTSS) is a sophisticated protein complex with an overall shape similar to a hypodermic needle. More than twenty unique types of proteins are required for its assembly, most of which are

  7. Lid for improved dendritic web growth

    DOE Patents [OSTI]

    Duncan, Charles S.; Kochka, Edgar L.; Piotrowski, Paul A.; Seidensticker, Raymond G.

    1992-03-24

    A lid for a susceptor in which a crystalline material is melted by induction heating to form a pool or melt of molten material from which a dendritic web of essentially a single crystal of the material is pulled through an elongated slot in the lid and the lid has a pair of generally round openings adjacent the ends of the slot and a groove extends between each opening and the end of the slot. The grooves extend from the outboard surface of the lid to adjacent the inboard surface providing a strip contiguous with the inboard surface of the lid to produce generally uniform radiational heat loss across the width of the dendritic web adjacent the inboard surface of the lid to reduce thermal stresses in the web and facilitate the growth of wider webs at a greater withdrawal rate.

  8. lacy_qer_santafe.pptx

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    S olar * Belaluz * Valley E lectric A ssoc. * 34 B LM a pplica5ons * Solar E nergy Z one * Solar E nergy Demonstra5on Z one o n Nevada T est S ite * West - Wide E nergy Corridor

  9. ALS Technique Gives Novel View of Lithium Battery Dendrite Growth

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS Technique Gives Novel View of Lithium Battery Dendrite Growth ALS Technique Gives Novel View of Lithium Battery Dendrite Growth Print Thursday, 24 April 2014 09:46 Lithium-ion batteries, popular in today's electronic devices and electric vehicles, could gain significant energy density if their graphite anodes were replaced with lithium metal anodes. But there's a major concern with substituting lithium-when the battery cycles, microscopic fibers of the lithium anodes ("dendrites")

  10. Method for fabricating arrays of micro-needles

    DOE Patents [OSTI]

    Kenney, Christopher J.

    2003-04-22

    An array of micro-needles is created by forming an array pattern on the upper surface of a silicon wafer and etching through openings in the pattern to define micro-needle sized cavities having a desired depth. The mold thus formed may be filled with electrically conductive material, after which a desired fraction of the silicon wafer bulk is removed from the bottom-up by etching, to expose an array of projecting micro-needles. The mold may instead be filled with a flexible material to form a substrate useful in gene cell probing. An array of hollow micro-needles may be formed by coating the lower wafer surface with SiN, and etching through pattern openings in the upper surface down to the SiN layer, and then conformally coating the upper surface with thermal silicon dioxide. The SiN layer is then stripped away and a desired fraction of the bulk of the wafer removed from the bottom-up to expose an array of projecting hollow micro-needles.

  11. Ternary eutectic dendrites: Pattern formation and scaling properties

    SciTech Connect (OSTI)

    Rátkai, László; Szállás, Attila; Pusztai, Tamás; Mohri, Tetsuo; Gránásy, László

    2015-04-21

    Extending previous work [Pusztai et al., Phys. Rev. E 87, 032401 (2013)], we have studied the formation of eutectic dendrites in a model ternary system within the framework of the phase-field theory. We have mapped out the domain in which two-phase dendritic structures grow. With increasing pulling velocity, the following sequence of growth morphologies is observed: flat front lamellae → eutectic colonies → eutectic dendritesdendrites with target pattern → partitionless dendrites → partitionless flat front. We confirm that the two-phase and one-phase dendrites have similar forms and display a similar scaling of the dendrite tip radius with the interface free energy. It is also found that the possible eutectic patterns include the target pattern, and single- and multiarm spirals, of which the thermal fluctuations choose. The most probable number of spiral arms increases with increasing tip radius and with decreasing kinetic anisotropy. Our numerical simulations confirm that in agreement with the assumptions of a recent analysis of two-phase dendrites [Akamatsu et al., Phys. Rev. Lett. 112, 105502 (2014)], the Jackson-Hunt scaling of the eutectic wavelength with pulling velocity is obeyed in the parameter domain explored, and that the natural eutectic wavelength is proportional to the tip radius of the two-phase dendrites. Finally, we find that it is very difficult/virtually impossible to form spiraling two-phase dendrites without anisotropy, an observation that seems to contradict the expectations of Akamatsu et al. Yet, it cannot be excluded that in isotropic systems, two-phase dendrites are rare events difficult to observe in simulations.

  12. Finding a Needle in a Crystalline Haystack | U.S. DOE Office...

    Office of Science (SC) Website

    Finding a Needle in a Crystalline Haystack New X-ray technique reveals the presence of ... Seeing the needle in the haystack. The ring pattern from the new transmission X-ray ...

  13. Platinum dendritic nanoparticles with magnetic behavior

    SciTech Connect (OSTI)

    Li, Wenxian; Sun, Ziqi; Nevirkovets, Ivan P.; Dou, Shi-Xue; Tian, Dongliang

    2014-07-21

    Magnetic nanoparticles have attracted increasing attention for biomedical applications in magnetic resonance imaging, high frequency magnetic field hyperthermia therapies, and magnetic-field-gradient-targeted drug delivery. In this study, three-dimensional (3D) platinum nanostructures with large surface area that features magnetic behavior have been demonstrated. The well-developed 3D nanodendrites consist of plentiful interconnected nano-arms ?4?nm in size. The magnetic behavior of the 3D dendritic Pt nanoparticles is contributed by the localization of surface electrons due to strongly bonded oxygen/Pluronic F127 and the local magnetic moment induced by oxygen vacancies on the neighboring Pt and O atoms. The magnetization of the nanoparticles exhibits a mixed paramagnetic and ferromagnetic state, originating from the core and surface, respectively. The 3D nanodendrite structure is suitable for surface modification and high amounts of drug loading if the transition temperature was enhanced to room temperature properly.

  14. Precision grid and hand motion for accurate needle insertion in brachytherapy

    SciTech Connect (OSTI)

    McGill, Carl S.; Schwartz, Jonathon A.; Moore, Jason Z.; McLaughlin, Patrick W.; Shih, Albert J.

    2011-08-15

    Purpose: In prostate brachytherapy, a grid is used to guide a needle tip toward a preplanned location within the tissue. During insertion, the needle deflects en route resulting in target misplacement. In this paper, 18-gauge needle insertion experiments into phantom were performed to test effects of three parameters, which include the clearance between the grid hole and needle, the thickness of the grid, and the needle insertion speed. Measurement apparatus that consisted of two datum surfaces and digital depth gauge was developed to quantify needle deflections. Methods: The gauge repeatability and reproducibility (GR and R) test was performed on the measurement apparatus, and it proved to be capable of measuring a 2 mm tolerance from the target. Replicated experiments were performed on a 2{sup 3} factorial design (three parameters at two levels) and analysis included averages and standard deviation along with an analysis of variance (ANOVA) to find significant single and two-way interaction factors. Results: Results showed that grid with tight clearance hole and slow needle speed increased precision and accuracy of needle insertion. The tight grid was vital to enhance precision and accuracy of needle insertion for both slow and fast insertion speed; additionally, at slow speed the tight, thick grid improved needle precision and accuracy. Conclusions: In summary, the tight grid is important, regardless of speed. The grid design, which shows the capability to reduce the needle deflection in brachytherapy procedures, can potentially be implemented in the brachytherapy procedure.

  15. The three-dimensional morphology of growing dendrites

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gibbs, J. W.; Mohan, K. A.; Gulsoy, E. B.; Shahani, A. J.; Xiao, X.; Bouman, C. A.; De Graef, M.; Voorhees, P. W.

    2015-07-03

    The processes controlling the morphology of dendrites have been of great interest to a wide range of communities, since they are examples of an out-of-equilibrium pattern forming system, there is a clear connection with battery failure processes, and their morphology sets the properties of many metallic alloys. We determine the three-dimensional morphology of free growing metallic dendrites using a novel X-ray tomographic technique that improves the temporal resolution by more than an order of magnitude compared to conventional techniques. These measurements show that the growth morphology of metallic dendrites is surprisingly different from that seen in model systems, the morphologymore » is not self-similar with distance back from the tip, and that this morphology can have an unexpectedly strong influence on solute segregation in castings. These experiments also provide benchmark data that can be used to validate simulations of free dendritic growth.« less

  16. The three-dimensional morphology of growing dendrites

    SciTech Connect (OSTI)

    Gibbs, J. W.; Mohan, K. A.; Gulsoy, E. B.; Shahani, A. J.; Xiao, X.; Bouman, C. A.; De Graef, M.; Voorhees, P. W.

    2015-07-03

    The processes controlling the morphology of dendrites have been of great interest to a wide range of communities, since they are examples of an out-of-equilibrium pattern forming system, there is a clear connection with battery failure processes, and their morphology sets the properties of many metallic alloys. We determine the three-dimensional morphology of free growing metallic dendrites using a novel X-ray tomographic technique that improves the temporal resolution by more than an order of magnitude compared to conventional techniques. These measurements show that the growth morphology of metallic dendrites is surprisingly different from that seen in model systems, the morphology is not self-similar with distance back from the tip, and that this morphology can have an unexpectedly strong influence on solute segregation in castings. These experiments also provide benchmark data that can be used to validate simulations of free dendritic growth.

  17. ALS Technique Gives Novel View of Lithium Battery Dendrite Growth

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS Technique Gives Novel View of Lithium Battery Dendrite Growth Print Lithium-ion batteries, popular in today's electronic devices and electric vehicles, could gain significant energy density if their graphite anodes were replaced with lithium metal anodes. But there's a major concern with substituting lithium-when the battery cycles, microscopic fibers of the lithium anodes ("dendrites") form on the surface of the lithium electrode and spread across the electrolyte until they reach

  18. 2-M Probe At The Needles Area (Kratt, Et Al., 2010) | Open Energy...

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: 2-M Probe At The Needles Area (Kratt, Et Al., 2010) Exploration Activity Details Location...

  19. Dendrite-free Li deposition using trace-amounts of water as an...

    Office of Scientific and Technical Information (OSTI)

    Dendrite-free Li deposition using trace-amounts of water as an electrolyte additive ... Title: Dendrite-free Li deposition using trace-amounts of water as an electrolyte additive ...

  20. Dendrite-Free Lithium Deposition with Self-Aligned Nanorod Structure...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    December 2, 2014, Research Highlights Dendrite-Free Lithium Deposition with Self-Aligned ... of dendrite-free lithium films with self-aligned and highly-compacted nanorod structure. ...

  1. Prediction of dendritic spacings in a directional-solidification experiment

    SciTech Connect (OSTI)

    Warren, J.A. ); Langer, J.S. )

    1993-04-01

    We present a theoretical analysis of the formation of a dendritic array in a directional-solidification experiment. Our calculation contains three sequential ingredients: acceleration of an initially flat interface and the concomitant buildup of a solutal boundary layer in front of it; onset of a morphological instability, triggered by thermal fluctuations, producing a relatively finely spaced array of dendritic tips; coarsening of this array and final selection of a steady-state primary spacing. For sufficiently large growth speeds, where the resulting dendrites interact with each other weakly, we find--with no adjustable parameters--good agreement with the experiments of Trivedi and Somboonsuk [Acta Metall. 33, 1061 (1985)] and Somboonsuk, Mason, and Trivedi [Metall. Trans A 15A, 967 (1984)].

  2. Dendrite-Free Li Deposition Using Trace-Amounts of Water as an Electrolyte

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Additive - Joint Center for Energy Storage Research April 25, 2015, Research Highlights Dendrite-Free Li Deposition Using Trace-Amounts of Water as an Electrolyte Additive Dendrite growth leads to low CE and safety issues of Li anode. Trace amount of water enables dendrite-free Li deposition. Scientific Achievement Residual water (H2O) present in nonaqueous electrolytes has been widely regarded as a detrimental factor for lithium (Li) batteries. However, dendrite-free Li film can be obtained

  3. Atomic oxygen patterning from a biomedical needle-plasma source

    SciTech Connect (OSTI)

    Kelly, Sen; Turner, Miles M.

    2013-09-28

    A plasma needle is a cold plasma source operating at atmospheric pressure. Such sources interact strongly with living cells, but experimental studies on bacterial samples show that this interaction has a surprising pattern resulting in circular or annular killing structures. This paper presents numerical simulations showing that this pattern occurs because biologically active reactive oxygen and nitrogen species are produced dominantly where effluent from the plasma needle interacts with ambient air. A novel solution strategy is utilised coupling plasma produced neutral (uncharged) reactive species to the gas dynamics solving for steady state profiles at the treated biological surface. Numerical results are compared with experimental reports corroborating evidence for atomic oxygen as a key bactericidal species. Surface losses are considered for interaction of plasma produced reactants with reactive solid and liquid interfaces. Atomic oxygen surface reactions on a reactive solid surface with adsorption probabilities above 0.1 are shown to be limited by the flux of atomic oxygen from the plasma. Interaction of the source with an aqueous surface showed hydrogen peroxide as the dominant species at this interface.

  4. Hot wire needle probe for thermal conductivity detection

    SciTech Connect (OSTI)

    Condie, Keith Glenn; Rempe, Joy Lynn; Knudson, Darrell lee; Daw, Joshua Earl; Wilkins, Steven Curtis; Fox, Brandon S.; Heng, Ban

    2015-11-10

    An apparatus comprising a needle probe comprising a sheath, a heating element, a temperature sensor, and electrical insulation that allows thermal conductivity to be measured in extreme environments, such as in high-temperature irradiation testing. The heating element is contained within the sheath and is electrically conductive. In an embodiment, the heating element is a wire capable of being joule heated when an electrical current is applied. The temperature sensor is contained within the sheath, electrically insulated from the heating element and the sheath. The electrical insulation electrically insulates the sheath, heating element and temperature sensor. The electrical insulation fills the sheath having electrical resistance capable of preventing electrical conduction between the sheath, heating element, and temperature sensor. The control system is connected to the heating element and the temperature sensor.

  5. Needle segmentation using 3D Hough transform in 3D TRUS guided prostate transperineal therapy

    SciTech Connect (OSTI)

    Qiu Wu; Yuchi Ming; Ding Mingyue; Tessier, David; Fenster, Aaron

    2013-04-15

    Purpose: Prostate adenocarcinoma is the most common noncutaneous malignancy in American men with over 200 000 new cases diagnosed each year. Prostate interventional therapy, such as cryotherapy and brachytherapy, is an effective treatment for prostate cancer. Its success relies on the correct needle implant position. This paper proposes a robust and efficient needle segmentation method, which acts as an aid to localize the needle in three-dimensional (3D) transrectal ultrasound (TRUS) guided prostate therapy. Methods: The procedure of locating the needle in a 3D TRUS image is a three-step process. First, the original 3D ultrasound image containing a needle is cropped; the cropped image is then converted to a binary format based on its histogram. Second, a 3D Hough transform based needle segmentation method is applied to the 3D binary image in order to locate the needle axis. The position of the needle endpoint is finally determined by an optimal threshold based analysis of the intensity probability distribution. The overall efficiency is improved through implementing a coarse-fine searching strategy. The proposed method was validated in tissue-mimicking agar phantoms, chicken breast phantoms, and 3D TRUS patient images from prostate brachytherapy and cryotherapy procedures by comparison to the manual segmentation. The robustness of the proposed approach was tested by means of varying parameters such as needle insertion angle, needle insertion length, binarization threshold level, and cropping size. Results: The validation results indicate that the proposed Hough transform based method is accurate and robust, with an achieved endpoint localization accuracy of 0.5 mm for agar phantom images, 0.7 mm for chicken breast phantom images, and 1 mm for in vivo patient cryotherapy and brachytherapy images. The mean execution time of needle segmentation algorithm was 2 s for a 3D TRUS image with size of 264 Multiplication-Sign 376 Multiplication-Sign 630 voxels. Conclusions

  6. Investigating the Effects of Anisotropic Mass Transport on Dendrite Growth in High Energy Density Lithium Batteries

    SciTech Connect (OSTI)

    Tan, Jinwang; Tartakovsky, Alexandre M.; Ferris, Kim F.; Ryan, Emily M.

    2016-01-01

    Dendrite formation on the electrode surface of high energy density lithium (Li) batteries causes safety problems and limits their applications. Suppressing dendrite growth could significantly improve Li battery performance. Dendrite growth and morphology is a function of the mixing in the electrolyte near the anode interface. Most research into dendrites in batteries focuses on dendrite formation in isotropic electrolytes (i.e., electrolytes with isotropic diffusion coefficient). In this work, an anisotropic diffusion reaction model is developed to study the anisotropic mixing effect on dendrite growth in Li batteries. The model uses a Lagrangian particle-based method to model dendrite growth in an anisotropic electrolyte solution. The model is verified by comparing the numerical simulation results with analytical solutions, and its accuracy is shown to be better than previous particle-based anisotropic diffusion models. Several parametric studies of dendrite growth in an anisotropic electrolyte are performed and the results demonstrate the effects of anisotropic transport on dendrite growth and morphology, and show the possible advantages of anisotropic electrolytes for dendrite suppression.

  7. In-plane ultrasonic needle tracking using a fiber-optic hydrophone

    SciTech Connect (OSTI)

    Xia, Wenfeng Desjardins, Adrien E.; Mari, Jean Martial; West, Simeon J.; Ginsberg, Yuval; David, Anna L.; Ourselin, Sebastien

    2015-10-15

    Purpose: Accurate and efficient guidance of needles to procedural targets is critically important during percutaneous interventional procedures. Ultrasound imaging is widely used for real-time image guidance in a variety of clinical contexts, but with this modality, uncertainties about the location of the needle tip within the image plane lead to significant complications. Whilst several methods have been proposed to improve the visibility of the needle, achieving accuracy and compatibility with current clinical practice is an ongoing challenge. In this paper, the authors present a method for directly visualizing the needle tip using an integrated fiber-optic ultrasound receiver in conjunction with the imaging probe used to acquire B-mode ultrasound images. Methods: Needle visualization and ultrasound imaging were performed with a clinical ultrasound imaging system. A miniature fiber-optic ultrasound hydrophone was integrated into a 20 gauge injection needle tip to receive transmissions from individual transducer elements of the ultrasound imaging probe. The received signals were reconstructed to create an image of the needle tip. Ultrasound B-mode imaging was interleaved with needle tip imaging. A first set of measurements was acquired in water and tissue ex vivo with a wide range of insertion angles (15°–68°) to study the accuracy and sensitivity of the tracking method. A second set was acquired in an in vivo swine model, with needle insertions to the brachial plexus. A third set was acquired in an in vivo ovine model for fetal interventions, with insertions to different locations within the uterine cavity. Two linear ultrasound imaging probes were used: a 14–5 MHz probe for the first and second sets, and a 9–4 MHz probe for the third. Results: During insertions in tissue ex vivo and in vivo, the imaged needle tip had submillimeter axial and lateral dimensions. The signal-to-noise (SNR) of the needle tip was found to depend on the insertion angle. With

  8. Direct Observation of SEI and Dendrite Dynamics by Operando Electrochemical

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Scanning Transmission Electron Microscopy - Joint Center for Energy Storage Research February 23, 2015, Research Highlights Direct Observation of SEI and Dendrite Dynamics by Operando Electrochemical Scanning Transmission Electron Microscopy (Top) Li deposited on the Pt anode at the beginning (left), during (middle) and end (right) of the second cycle. Residual "dead Li" can be seen around the anode. (Center) Simultaneous cyclic voltammetry of the second Li deposition/dissolution

  9. Graphlocons: Large dendritic graphene crystals and their electronic properties

    SciTech Connect (OSTI)

    Massicotte, Mathieu; Yu, Victor; Whiteway, Eric; Hilke, Michael

    2013-12-04

    Submillimeter dendritic-shaped crystals were synthesized by low pressure vapor chemical vapor deposition inside a copper enclosure. With their sixfold symmetry and fractal-like shape, the resulting crystals resemble snowflakes. The electronic properties of the devices were investigated down to sub-Kelvin temperatures, showing mobilities over 5000 cm{sup 2}/Vs and the quantum Hall effect at 8T. The magnetoresistance also displayed a sharp peak at zero field which we attribute to weak localization.

  10. Forty-Six-Foot Tall Needle Sculpture Rises Over Arts Quad > EMC2...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Section EMC2 News Archived News Stories Forty-Six-Foot Tall Needle Sculpture Rises Over Arts Quad September 14th, 2014 By ANUSHKA MEHROTRA Students walking around campus this...

  11. Linking instantaneous rate of injection to X-ray needle lift measurements

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for a direct-acting piezoelectric injector | Argonne National Laboratory Linking instantaneous rate of injection to X-ray needle lift measurements for a direct-acting piezoelectric injector Title Linking instantaneous rate of injection to X-ray needle lift measurements for a direct-acting piezoelectric injector Publication Type Journal Article Year of Publication 2016 Authors Viera, JP, Payri, R, Swantek, A, Duke, D, Sovis, N, Kastengren, A, Powell, CF Journal Energy Conversion and

  12. Driven Around the Bend: Novel Use of a Curved Steerable Needle

    SciTech Connect (OSTI)

    Murphy, Darra T. Korzan, Jeffrey R.; Ouellette, Hugue A.; Liu, David M.; Clarkson, Paul W.; Munk, Peter L.

    2013-04-15

    This technical note describes the novel use of a curved, steerable needle to access symptomatic osseous lesions in the pelvis and sacrum for palliative percutaneous treatment that would otherwise be difficult to treat using conventional straight needles. Seven patients with lytic bone lesions were treated. One patient had multiple myeloma; the remaining had metastatic disease: breast carcinoma (n = 2), colorectal carcinoma (n = 1), renal cell carcinoma (n = 1), squamous cell carcinoma (n = 1), and leiomyosarcoma (n = 1). Five of the seven patients had lesions in the posterior acetabulum, and the two other patients had lesions in the sacrum. Four of the seven patients received radiofrequency ablation followed by cementoplasty; three patients received cementation alone. We used a novel needle designed for vertebroplasty, which has an articulating tip allowing it to be guided into lytic bone lesions located in difficult-to-access regions of the pelvis and sacrum. All patients were successfully treated with cementoplasty either with or without thermal ablation. No serious adverse events were reported. The needle was difficult to withdraw in two patients. Steerable curved needles can be successfully used to treat lytic osseous metastases with cementoplasty when lesions are located in sites that may be difficult to reach using conventional straight needles.

  13. In-Situ Liquid (ec)-TEM Cell Shows Dendrite Formation, Providing...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Providing New Insights into Lithium Batteries (Top) In-situ liquid electrochemical ... changing our view of dendrite formation and the safety of lithium-ion batteries. ...

  14. Alloy substantially free of dendrites and method of forming the same

    DOE Patents [OSTI]

    de Figueredo, Anacleto M.; Apelian, Diran; Findon, Matt M.; Saddock, Nicholas

    2009-04-07

    Described herein are alloys substantially free of dendrites. A method includes forming an alloy substantially free of dendrites. A superheated alloy is cooled to form a nucleated alloy. The temperature of the nucleated alloy is controlled to prevent the nuclei from melting. The nucleated alloy is mixed to distribute the nuclei throughout the alloy. The nucleated alloy is cooled with nuclei distributed throughout.

  15. A method for making dendritic metal nanostructures using a surfactant structure template, a metal salt, and electron donor species.

    DOE Patents [OSTI]

    Shelnutt, John A.; Song, Yujiang; Pereira, Eulalia F.; Medforth, Craig J.

    2008-05-20

    A method for making dendritic metal nanostructures using a surfactant structure template, a metal salt, and electron donor species.

  16. Treatment planning for prostate focal laser ablation in the face of needle placement uncertainty

    SciTech Connect (OSTI)

    Cepek, Jeremy Fenster, Aaron; Lindner, Uri; Trachtenberg, John; Davidson, Sean R. H.; Haider, Masoom A.; Ghai, Sangeet

    2014-01-15

    Purpose: To study the effect of needle placement uncertainty on the expected probability of achieving complete focal target destruction in focal laser ablation (FLA) of prostate cancer. Methods: Using a simplified model of prostate cancer focal target, and focal laser ablation region shapes, Monte Carlo simulations of needle placement error were performed to estimate the probability of completely ablating a region of target tissue. Results: Graphs of the probability of complete focal target ablation are presented over clinically relevant ranges of focal target sizes and shapes, ablation region sizes, and levels of needle placement uncertainty. In addition, a table is provided for estimating the maximum target size that is treatable. The results predict that targets whose length is at least 5 mm smaller than the diameter of each ablation region can be confidently ablated using, at most, four laser fibers if the standard deviation in each component of needle placement error is less than 3 mm. However, targets larger than this (i.e., near to or exceeding the diameter of each ablation region) require more careful planning. This process is facilitated by using the table provided. Conclusions: The probability of completely ablating a focal target using FLA is sensitive to the level of needle placement uncertainty, especially as the target length approaches and becomes greater than the diameter of ablated tissue that each individual laser fiber can achieve. The results of this work can be used to help determine individual patient eligibility for prostate FLA, to guide the planning of prostate FLA, and to quantify the clinical benefit of using advanced systems for accurate needle delivery for this treatment modality.

  17. Dendrite-Free Li Deposition Using Trace-Amounts of Water as an...

    Office of Scientific and Technical Information (OSTI)

    Using Trace-Amounts of Water as an Electrolyte Additive Citation Details In-Document Search Title: Dendrite-Free Li Deposition Using Trace-Amounts of Water as an Electrolyte ...

  18. Prostate Brachytherapy With Oblique Needles to Treat Large Glands and Overcome Pubic Arch Interference

    SciTech Connect (OSTI)

    Ryu, Bon; Imaging Research Laboratories, Robarts Research Institute, University of Western Ontario, London, Ontario ; Bax, Jeff; Imaging Research Laboratories, Robarts Research Institute, University of Western Ontario, London, Ontario ; Edirisinge, Chandima; Lewis, Craig; Chen, Jeff; D'Souza, David; Radiation Treatment Program, London Regional Cancer Program, London Health Sciences Centre, London, Ontario ; Fenster, Aaron; Department of Medical Biophysics, University of Western Ontario, London, Ontario; Department of Biomedical Engineering, University of Western Ontario, London, Ontario; Imaging Research Laboratories, Robarts Research Institute, University of Western Ontario, London, Ontario; Department of Oncology, University of Western Ontario, London, Ontario ; Wong, Eugene; Department of Medical Biophysics, University of Western Ontario, London, Ontario; Department of Oncology, University of Western Ontario, London, Ontario

    2012-08-01

    Purpose: First, to show that low-dose-rate prostate brachytherapy plans using oblique needle trajectories are more successful than parallel trajectories for large prostates with pubic arch interference (PAI); second, to test the accuracy of delivering an oblique plan by using a three-dimensional (3D) transrectal ultrasonography (TRUS)-guided mechatronic system. Methods and Materials: Prostates were contoured for 5 subjects' 3D TRUS images showing a maximum PAI of {<=}1 cm and a prostate volume of <50 cc. Two planning studies were done. First, prostate contours were artificially enlarged to 45 to 80 cc in 5- to 10-cc increments for a single subject. Second, all subject prostate contours were enlarged to 60 cc. For each study, three types of plans were manually created for comparison: a parallel needle template (PT) plan, a parallel needle no-template (PNT) plan, and an oblique needle no-template (OBL) plan. Needle positions and angles were not discretized for nontemplate plans. European Society for Therapeutic Radiology and Oncology dose-volume histogram guidelines, iodine-125 (145-Gy prescription, 0.43 U), and needle angles of <15 Degree-Sign were used. An OBL plan was delivered to a pubic arch containing a 60-cc prostate phantom that mimicked the anatomy of the subject with the greatest PAI (23% by volume). Results: In the increasing-prostate volume study, OBL plans were successful for prostates of {<=}80 cc, and PT plans were successful for prostates of <65 cc. In paired, one-sided t tests for the 60-cc volume study, OBL plans showed dosimetric improvements for all organs compared to both of the parallel type plans (p < 0.05); PNT plans showed a benefit only in planning target volumes receiving more than 100 Gy compared to PT plans. A computed tomography scan of the phantom showed submillimeter seed placement accuracy in all directions. Conclusion: OBL plans were significantly better than parallel plans, and an OBL plan was accurately delivered to a 60-cc

  19. Au-Pt heteroaggregate dendritic nanostructures and Au-Pt alloy nanoparticles and their use as catalysts

    DOE Patents [OSTI]

    Eichhorn, Bryan W.; Zhou, Shenghu; Jackson, Gregory Scott

    2011-10-18

    Au--Pt heteroaggregate dendritic nanostructures and AuPt alloy nanoparticles, and their use as anodic catalysts in fuel cells.

  20. PT AND PT/NI "NEEDLE" ELETROCATALYSTS ON CARBON NANOTUBES WITH HIGH ACTIVITY FOR THE ORR

    SciTech Connect (OSTI)

    Colon-Mercado, H.

    2011-11-10

    Platinum and platinum/nickel alloy electrocatalysts supported on graphitized (gCNT) or nitrogen doped carbon nanotubes (nCNT) are prepared and characterized. Pt deposition onto carbon nanotubes results in Pt 'needle' formations that are 3.5 nm in diameter and {approx}100 nm in length. Subsequent Ni deposition and heat treatment results in PtNi 'needles' with an increased diameter. All Pt and Pt/Ni materials were tested as electrocatalysts for the oxygen reduction reaction (ORR). The Pt and Pt/Ni catalysts showed excellent performance for the ORR, with the heat treated PtNi/gCNT (1.06 mA/cm{sup 2}) and PtNi/nCNT (0.664 mA/cm{sup 2}) showing the highest activity.

  1. *** CANCELED *** SCIENCE ON SATURDAY- "Finding a Needle in A (Genomic)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Haystack or How Can Computers Help Cure Cancer" | Princeton Plasma Physics Lab February 9, 2013, 9:30am Science On Saturday MBG Auditorium *** CANCELED *** SCIENCE ON SATURDAY- "Finding a Needle in A (Genomic) Haystack or How Can Computers Help Cure Cancer" Professor Olga G. Troyanskaya Lewis-Sigler Institute for Integrative Genomics & Department of Computer Science, Princeton University Science on Saturday is a series of lectures given by scientists, mathematicians, and

  2. Dendrite-Free Lithium Deposition via Self-Healing Electrostatic Shield Mechanism

    SciTech Connect (OSTI)

    Ding, Fei; Xu, Wu; Graff, Gordon L.; Zhang, Jian; Sushko, Maria L.; Chen, Xilin; Shao, Yuyan; Engelhard, Mark H.; Nie, Zimin; Xiao, Jie; Liu, Xingjiang; Sushko, P. V.; Liu, Jun; Zhang, Jiguang

    2013-02-28

    Lithium metal batteries are called the “holy grail” of energy storage systems. However, lithium dendrite growth in these batteries has prevented their practical applications in the last 40 years. Here we show a novel mechanism which can fundamentally change the dendritic morphology of lithium deposition. A low concentration of the second cations (including ions of cesium, rubidium, potassium, and strontium) exhibits an effective reduction potential lower than the standard reduction potential of lithium ions when the chemical activities of these second cations are much lower than that of lithium ions. During lithium deposition, these second cations will form a self-healing electrostatic shield around the initial tip of lithium whenever it is formed. This shield will repel the incoming lithium ions and force them to deposit in the smoother region of the anode so a dendrite-free film is obtained. This mechanism is effective on dendrite prevention in both lithium metal and lithium ion batteries. They may also prevent dendrite growth in other metal batteries and have transformational impact on the smooth deposition in general electrodeposition processes.

  3. Dynamic Characterization of Dendrite Deposition and Growth in Li-Surface by Electrochemical Impedance Spectroscopy

    SciTech Connect (OSTI)

    Hernandez-Maya, R; Rosas, O; Saunders, J; Castaneda, H

    2015-01-13

    The evolution of dendrite formation is characterized by DC and AC electrochemical techniques. Interfacial mechanisms for lithium deposition are described and quantified by electrochemical impedance spectroscopy (EIS) between a lithium electrode and a graphite electrode. The initiation and growth of dendrites in the lithium surface due to the cathodic polarization conditions following anodic dissolution emulate long term cycling process occurring in the lithium electrodes. The dendrite initiation at the lithium/organic electrolyte interface is proposed to be performed through a combination of layering and interfacial reactions during different cathodic conditions. The growth is proposed to be performed by surface geometrical deposition. In this work, we use EIS in galvanostatic mode to assess the initiation and growth stages of dendrites by the accumulation of precipitates formed under different current conditions. The lithium/organic solvent experimental system using frequency domain techniques is validated by the theoretical approach using a deterministic model that accounts for the faradaic processes at the interface assuming a coverage fraction of the electrodic surface affected by the dendritic growth. (C) 2015 The Electrochemical Society. All rights reserved.

  4. Dendrite-Free Lithium Deposition with Self-Aligned Nanorod Structure

    SciTech Connect (OSTI)

    Zhang, Yaohui; Qian, Jiangfeng; Xu, Wu; Russell, Selena M.; Chen, Xilin; Nasybulin, Eduard; Bhattacharya, Priyanka; Engelhard, Mark H.; Mei, Donghai; Cao, Ruiguo; Ding, Fei; Cresce, Arthur V.; Xu, Kang; Zhang, Jiguang

    2014-12-10

    Suppressing lithium (Li) dendrite growth is one of the most critical challenges for the development of Li metal batteries. We recently proposed a novel self-healing electrostatic shield (SHES) mechanism which can fundamentally change the Li deposition behavior and lead to the growth of dendrite-free Li films. Here, we report for the first time that the as-deposited dendrite-free Li films grown with assistance of SHES additive are actually composed of highly-aligned and compacted Li nanorods with hemispherical tips. Both surface and cross sectional morphology evolution of the Li films during repeated Li deposition/stripping processes were systematically investigated. A new model has been established to explain the formation and evolution of the Li nanorods. A fundamental understanding on the internal structure and evolution of Li metal films may lead to new approaches to stabilize the long term cycling stability of Li metal anode.

  5. Hot wire needle probe for in-reactor thermal conductivity measurement

    SciTech Connect (OSTI)

    JE Daw; JL Rempe; DL Knudson

    2012-08-01

    Thermal conductivity is a key property that must be known for proper design, test, and application of new fuels and structural materials in nuclear reactors. Thermal conductivity is highly dependent on the physical structure, chemical composition, and the state of the material. Typically, thermal conductivity changes that occur during irradiation are measured out-of-pile by Post Irradiated Examination (PIE) using a “cook and look” approach in hot-cells. Repeatedly removing samples from a test reactor to make out-of-pile measurements is expensive, has the potential to disturb phenomena of interest, and only provides understanding of the sample's end state at the time each measurement is made. There are also limited thermophysical property data for advanced fuels. Such data are needed for simulation design codes, the development of next generation reactors, and advanced fuels for existing nuclear plants. Being able to quickly characterize fuel thermal conductivity during irradiation can improve the fidelity of data, reduce costs of post-irradiation examinations, increase understanding of how fuels behave under irradiation, and confirm or improve existing thermal conductivity measurement techniques. This paper discusses recent efforts to develop and evaluate an in-pile thermal conductivity sensor based on a hot wire needle probe. Testing has been performed on samples with thermal conductivities ranging from 0.2 W/m-K to 22 W-m-K in temperatures ranging from 20 °C to 600 °C. Thermal conductivity values measured using the needle probe match data found in the literature to within 5% for samples tested at room temperature, 5.67% for low thermal conductivity samples tested at high temperatures, and 10% for high thermal conductivity samples tested at high temperatures. Experimental results also show that this sensor is capable of operating in various test conditions and of surviving long duration irradiations.

  6. Time dependence of tip morphology during cellular/dendritic arrayed growth

    SciTech Connect (OSTI)

    Song, H.; Tewari, S.N.

    1996-04-01

    Succinonitrile-1.9 wt pct acetone has been directionally solidified in 0.7 x 0.7-cm-square cross section pyrex ampoules in order to observe the cell/dendrite tip morphologies, not influenced by the wall effects, which are present during growth in the generally used thin (about 200 {micro}m) crucibles. The tips do not maintain a steady-state shape, as is generally assumed. Instead, they fluctuate within a shape envelope. The extent of fluctuation increases with decreasing growth speed, as the micro structure changes from the dendritic to cellular. The influence of natural convection has been examined by comparing these morphologies with those grown, without convection, in the thin ampoules.

  7. Method of preparing copper-dendritic composite alloys for mechanical reduction

    DOE Patents [OSTI]

    Verhoeven, J.D.; Gibson, E.D.; Schmidt, F.A.; Spitzig, W.A.

    1988-09-13

    Copper-dendritic composite alloys are prepared for mechanical reduction to increase tensile strength by dispersing molten droplets of the composite alloy into an inert gas; solidifying the droplets in the form of minute spheres or platelets; and compacting a mass of the spheres or platelets into an integrated body. The spheres preferably have diameters of from 50 to 2,000 [mu]m, and the platelets thicknesses of 100 to 2,000 [mu]m. The resulting spheres or platelets will contain ultra-fine dendrites which produce higher strengths on mechanical reduction of the bodies formed therefrom, or comparable strengths at lower reduction values. The method is applicable to alloys of copper with vanadium, niobium, tantalum, chromium, molybdenum, tungsten, iron and cobalt. 3 figs.

  8. Method of preparing copper-dendritic composite alloys for mechanical reduction

    DOE Patents [OSTI]

    Verhoeven, John D.; Gibson, Edwin D.; Schmidt, Frederick A.; Spitzig, William A.

    1988-01-01

    Copper-dendritic composite alloys are prepared for mechanical reduction to increase tensile strength by dispersing molten droplets of the composite alloy into an inert gas; solidifying the droplets in the form of minute spheres or platelets; and compacting a mass of the spheres or platelets into an integrated body. The spheres preferably have diameters of from 50 to 2000 .mu.m, and the platelets thicknesses of 100 to 2000 .mu.m. The resulting spheres or platelets will contain ultra-fine dendrites which produce higher strengths on mechanical reduction of the bodies formed therefrom, or comparable strengths at lower reduction values. The method is applicable to alloys of copper with vanadium, niobium, tantalum, chromium, molybdenum, tungsten, iron and cobalt.

  9. In-Situ Liquid (ec)-TEM Cell Shows Dendrite Formation, Providing New

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Insights into Lithium Batteries - Joint Center for Energy Storage Research March 3, 2014, Research Highlights In-Situ Liquid (ec)-TEM Cell Shows Dendrite Formation, Providing New Insights into Lithium Batteries (Top) In-situ liquid electrochemical (ec)-TEM cell uses two silicon microchips to create a three-electrode electrochemical cell with silicon nitride membranes that seal battery electrolytes. This enables charge/discharge cycling of the battery inside the high vacuum of a transmission

  10. Geoengineering: Plan B Remedy for Global Warming Andrew A. Lacis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mass-specific cross-sections (m2g) at 550 nm and 10 mm for black carbon (BC), sulfuric acid (SA), aluminum (AL) aerosols (A), and mass-specific cooling for SA aerosol for mass ...

  11. SciFri PM: Topics 08: The Role and Benefits of Electromagnetic Needle-Tracking Technologies in Brachytherapy

    SciTech Connect (OSTI)

    Beaulieu, L.; Racine, E.; Boutaleb, S.; Filion, O.; Poulin, E.; Hautvast, G.; Binnekamp, D.

    2014-08-15

    In modern brachytherapy, application of large doses of ionizing radiation in a limited number of fractions is frequent. Furthermore, as with any surgical procedures, brachytherapy is subject to learning curve effects. In this context, there could be advantages of integrating real-time tracking of needles/catheters to existing protocols given the recent prominent advances in tracking technologies. In this work, we review the use of an electromagnetic tracking system (EMTS) based on the second generation Aurora Planar Field Generator (Northern Digital Inc) and custom design needles (Philips Healthcare) for brachytherapy applications. The position and orientation information is obtained from 5 degrees of freedom sensors. Basic system performance characterization is performed in well-controlled conditions to establish accuracy and reproducibility as well as potential interference from standard brachytherapy equipment. The results show that sensor locations can be tracked to within 0.04mm (la) when located within 26cm of the generator. Orientation accuracy of the needle remained within 1 in the same region, but rose quickly at larger distances. The errors on position and orientation strongly dependent the sensor position in the characterization volume (500500500mm{sup 3}). The presence of an ultrasound probe was shown to have negligible effects on tracking accuracy. The use of EMTS for automatic catheter/applicator reconstruction was also explored. Reconstruction time was less than 10 sec/channel and tips identification was within 0.690.29mm of the reference values. Finally, we demonstrate that hollow needle designs with special EM adaptation also allow for real-time seed drop position estimation. In phantom experiments showed that drop positions were on average within 1.60.9mm of the reference position measured from ?CT. Altogether, EMTS offer promising benefits in a wide range of brachytherapy applications.

  12. Cell Wall Ultrastructure of Stem Wood, Roots, and Needles of a Conifer Varies in Response to Moisture Availability

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Pattathil, Sivakumar; Ingwers, Miles W.; Victoriano, Olivia L.; Kandemkavil, Sindhu; McGuire, Mary Anne; Teskey, Robert O.; Aubrey, Doug P.

    2016-06-24

    The composition, integrity, and architecture of the macromolecular matrix of cell walls, collectively referred to as cell wall ultrastructure, exhibits variation across species and organs and among cell types within organs. Indirect approaches have suggested that modifications to cell wall ultrastructure occur in response to abiotic stress; however, modifications have not been directly observed. Glycome profiling was used to study cell wall ultrastructure by examining variation in composition and extractability of non-cellulosic glycans in cell walls of stem wood, roots, and needles of loblolly pine saplings exposed to high and low soil moisture. Soil moisture influenced physiological processes and themore » overall composition and extractability of cell wall components differed as a function of soil moisture treatments. The strongest response of cell wall ultrastructure to soil moisture was increased extractability of pectic backbone epitopes in the low soil moisture treatment. The higher abundance of these pectic backbone epitopes in the oxalate extract indicate that the loosening of cell wall pectic components could be associated with the release of pectic signals as a stress response. The increased extractability of pectic backbone epitopes in response to low soil moisture availability was more pronounced in stem wood than in roots or needles. Additional responses to low soil moisture availability were observed in lignin associated carbohydrates released in chlorite extracts of stem wood, including an increased abundance of pectic arabinogalactan epitopes. Overall, these results indicate that cell walls of loblolly pine organs undergo changes in their ultrastructural composition and extractability as a response to soil moisture availability and that cell walls of the stem wood are more responsive to low soil moisture availability compared to cell walls of roots and needles. In conclusion, to our knowledge, this is the first direct evidence, delineated by

  13. Dendrite-Free Li Deposition Using Trace-Amounts of Water as an Electrolyte Additive

    SciTech Connect (OSTI)

    Qian, Jiangfeng; Xu, Wu; Bhattacharya, Priyanka; Engelhard, Mark H.; Henderson, Wesley A.; Zhang, Yaohui; Zhang, Jiguang

    2015-07-01

    Residual water presents in nonaqueous electrolytes has been widely regarded as a detrimental factor for lithium (Li) batteries. This is because water is highly reactive with the commonly used LiPF6 salt and leads to the formation of HF that corrodes battery materials. In this work, we demonstrate that a controlled trace-amount of water (25-100 ppm) can be an effective electrolyte additive for achieving dendrite-free Li metal deposition in LiPF6-based electrolytes and avoid its detrimental effect at the same time. Detailed analyses reveal that the trace amount of HF formed by the decomposition reaction of LiPF6 with water will be electrochemically reduced during initial Li deposition process to form a uniform and dense LiF-rich SEI layer on the surface of the substrate. This LiF-rich SEI layer leads to a uniform distribution of the electric field on the substrate surface and enables uniform and dendrite-free Li deposition. Meanwhile the detrimental effect of HF is diminished due to the consumption of HF in the LiF formation process. Microscopic analysis reveals that the as-deposited dendrite-free Li films exhibit a self-aligned and highly-compacted Li nanorods structure which is consistent with their charming blue color or known as structure color. These findings clearly demonstrate a novel approach to control the nucleation and grow process of Li metal films using well-controlled trace-amount of water. They also shine the light on the effect of water on other electrodeposition processes.

  14. Microyielding of core-shell crystal dendrites in a bulk-metallic-glass matrix composite

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Huang, E. -Wen; Qiao, Junwei; Winiarski, Bartlomiej; Lee, Wen -Jay; Scheel, Mario; Chuang, Chih -Pin; Liaw, Peter K.; Lo, Yu -Chieh; Zhang, Yong; Di Michiel, Marco

    2014-03-18

    In-situ synchrotron x-ray experiments have been used to follow the evolution of the diffraction peaks for crystalline dendrites embedded in a bulk metallic glass matrix subjected to a compressive loading-unloading cycle. We observe irreversible diffraction-peak splitting even though the load does not go beyond half of the bulk yield strength. The chemical analysis coupled with the transmission electron microscopy mapping suggests that the observed peak splitting originates from the chemical heterogeneity between the core (major peak) and the stiffer shell (minor peak) of the dendrites. A molecular dynamics model has been developed to compare the hkl-dependent microyielding of the bulkmore » metallic-glass matrix composite. As a result, the complementary diffraction measurements and the simulation results suggest that the interfaces between the amorphous matrix and the (211) crystalline planes relax under prolonged load that causes a delay in the reload curve which ultimately catches up with the original path.« less

  15. Needle age and season influence photosynthetic temperature response and total annual carbon uptake in mature Picea mariana trees

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jensen, Anna M.; Warren, Jeffrey; Hanson, Paul J.; Childs, Joanne; Wullschleger, Stan D.

    2015-01-01

    Using seasonal- and cohort-specific photosynthetic temperature response functions, we quantified the physiological significance of maintaining multiple foliar cohorts in mature (~40-45 year old) Picea mariana trees in an ombrotrophic Sphagnum-bog, northern Minnesota, USA. We measured photosynthetic capacity, foliar respiration (Rd), biochemistry and morphology to estimate annual carbon (C) uptake by cohort, season and canopy position. Temperature response of key photosynthetic parameters at 25 C (i.e., light-saturated rate of CO2 assimilation (Asat), light-saturated rate of Rubisco carboxylation (Vcmax), light-saturated electron transport rate (Jmax)) were clearly dependent on season and were generally less responsive in younger needles. Temperature optimums range between 18.7-23.7,more » 31.3-38.3 and 28.7-36.7 C for Asat, Vcmax and Jmax respectively. Current-year (Y0) foliage had lower photosynthetic capacities compared to one-year-old (Y1) and two-year-old (Y2) foliage. As Y0 needles matured, values of Asat, Vcmax, Jmax, foliar LMA and nitrogen increased. Values of Vcmax, Jmax and Rd were related to foliar nitrogen but only in the youngest (Y0) cohort. Foliar ontogeny affected photosynthetic capacity more than growth temperature. Morphological and physiological cohort differences were reflected by their annual contribution to modeled C uptake, with a ~36% lower estimated annual C uptake by Y0 needles (LAI 0.52 m2m-2) compared to Y1&2 cohorts (LAI 0.67 m2m-2). Collectively, these results illustrate the physiological and ecological significance of characterizing multiple foliar cohorts during bud break and throughout the growth season, and for cumulative C uptake model estimates.« less

  16. Needle age and season influence photosynthetic temperature response and total annual carbon uptake in mature Picea mariana trees

    SciTech Connect (OSTI)

    Jensen, Anna M.; Warren, Jeffrey; Hanson, Paul J.; Childs, Joanne; Wullschleger, Stan D.

    2015-07-28

    Using seasonal- and cohort-specific photosynthetic temperature response functions, we quantified the physiological significance of maintaining multiple foliar cohorts in mature (~40-45 year old) Picea mariana trees in an ombrotrophic Sphagnum-bog, northern Minnesota, USA. We measured photosynthetic capacity, foliar respiration (Rd), biochemistry and morphology to estimate annual carbon (C) uptake by cohort, season and canopy position. Temperature response of key photosynthetic parameters at 25 C (i.e., light-saturated rate of CO2 assimilation (Asat), light-saturated rate of Rubisco carboxylation (Vcmax), light-saturated electron transport rate (Jmax)) were clearly dependent on season and were generally less responsive in younger needles. Temperature optimums range between 18.7-23.7, 31.3-38.3 and 28.7-36.7 C for Asat, Vcmax and Jmax respectively. Current-year (Y0) foliage had lower photosynthetic capacities compared to one-year-old (Y1) and two-year-old (Y2) foliage. As Y0 needles matured, values of Asat, Vcmax, Jmax, foliar LMA and nitrogen increased. Values of Vcmax, Jmax and Rd were related to foliar nitrogen but only in the youngest (Y0) cohort. Foliar ontogeny affected photosynthetic capacity more than growth temperature. Morphological and physiological cohort differences were reflected by their annual contribution to modeled C uptake, with a ~36% lower estimated annual C uptake by Y0 needles (LAI 0.52 m2m-2) compared to Y1&2 cohorts (LAI 0.67 m2m-2). Collectively, these results illustrate the physiological and ecological significance of characterizing multiple foliar cohorts during bud break and throughout the growth season, and for cumulative C uptake model estimates.

  17. Comparison of 180-degree and 90-degree needle rotation to reduce wound size in PIT-injected juvenile Chinook salmon

    SciTech Connect (OSTI)

    Bryson, Amanda J.; Woodley, Christa M.; Karls, Rhonda K.; Hall, Kathleen D.; Weiland, Mark A.; Deng, Zhiqun; Carlson, Thomas J.; Eppard, Matthew B.

    2013-04-30

    Animal telemetry, which requires the implantation of passive transponders or active transmitters, is used to monitor and assess fish stock and conservation to gain an understanding of fish movement and behavior. As new telemetry technologies become available, studies of their effects on species of interest are imperative as is development of implantation techniques. In this study, we investigated the effects of bevel rotation (0-, 90-, 180-degree axis rotation) on wound extent, tag loss, and wound healing rates in juvenile Chinook salmon injected with an 8-gauge needle, which is required for implantation of the novel injectable Juvenile Salmon Acoustic Telemetry Systems (JSATS) acoustic transmitter or large passive integrated transponder (PIT) tags. Although the injection sites were not closed after injection (e.g., with sutures or glue), there were no mortalities, dropped tags, or indications of fungus, ulceration, and/or redness around the wound. On Day 0 and post-implantation Day 7, the 90-degree bevel rotation produced smaller wound extent than the 180-degree bevel rotation. No axis rotation (0-degrees) resulted in the PIT tag frequently misleading or falling out upon injection. The results of this study indicated the 90-degree bevel rotation was the more efficient technique, produced less wound extent. Given the wound extent compared to size of fish, we recommend researchers should consider a 90-degree rotation over the 180-degree rotation in telemetry studies. Highlights •Three degrees of needle rotation were examined for effects in Chinook salmon. •Mortality, tag loss, wound extent, healing, and infection indicators were measured. •There were no mortalities, tag loss, or indications of infection. •The 90-degree needle rotation through Day 7 produced the smallest wound extent.

  18. Image-Guided Radiofrequency Ablation (RFA) of Unresectable Hepatic Tumors Using a Triple-Spiral-Shaped Electrode Needle: Initial Experience in 34 Patients

    SciTech Connect (OSTI)

    Thanos, Loukas; Poulou, Loukia S.; Ziakas, Panayiotis D.; Kelekis, Alexis D.; Pomoni, Maria; Kelekis, Dimitrios A.

    2010-02-15

    We evaluated the safety and efficacy of image-guided radiofrequency ablation (RFA) using a triple-spiral-shaped electrode needle for unresectable primary or metastatic hepatic tumors. Thirty-four patients with 46 index tumors were treated. Ablation zone, morbidity, and complications were assessed. The lesions were completely ablated with an ablative margin of about 1 cm. Five patients (14.7%) with a lesion larger than 4.5 cm had local tumor progression after 1 month and were retreated. Hemothorax, as a major complication, occurred in 1 of 34 patients (3.0%) or 1 of 46 lesions ablated (2.2%). RFA using this new electrode needle can be effective in the treatment of large unresectable hepatic tumors.

  19. Observations and models of emissions of volatile terpenoid compounds from needles of ponderosa pine trees growing in situ: Controls by light, temperature and stomatal conductance

    SciTech Connect (OSTI)

    Harley, P.; Eller, Allyson; Guenther, Alex B.; Monson, Russell K.

    2014-07-14

    Terpenoid emissions from ponderosa pine (Pinus ponderosa subsp. scopulorum) were measured in Colorado, USA over two growing seasons to evaluate the role of incident light, needle temperature and stomatal conductance in controlling emissions of 2-methyl-3-buten-2-ol (MBO) and several monoterpenes. MBO was the dominant daylight terpenoid emission, comprising on average 87% of the total flux, and diurnal variations were largely determined by light and temperature. During daytime, oxygenated monoterpenes (especially linalool) comprised up to 75% of the total monoterpenoid flux from needles. A significant fraction of monoterpenoid emissions was light dependent and 13CO2 labeling studies confirmed de novo production. Thus, modeling of monoterpenoid emissions required a hybrid model in which a significant fraction of emissions was dependent on both light and temperature, while the remainder was dependent on temperature alone. Experiments in which stomata were forced to close using abscisic acid demonstrated that MBO and a large fraction of the monoterpene flux, presumably linalool, could be limited at the scale of seconds to minutes by stomatal conductance. Using a previously published model of terpenoid emissions which explicitly accounts for the physico-chemical properties of emitted compounds, we are able to simulate these observed stomatal effects, whether induced through experimentation or arising under naturally fluctuation conditions of temperature and light. This study shows unequivocally that, under naturally occurring field conditions, de novo light dependent monoterpenes can comprise a large fraction of emissions. Differences between the monoterpene composition of ambient air and needle emissions imply a significant non-needle emission source enriched in ?-3-carene.

  20. Lithium-coated polymeric matrix as a minimum volume-change and dendrite-free lithium metal anode

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, Yayuan; Lin, Dingchang; Liang, Zheng; Zhao, Jie; Yan, Kai; Cui, Yi

    2016-03-18

    Lithium metal is the ideal anode for the next generation of high-energy-density batteries. Nevertheless, dendrite growth, side reactions and infinite relative volume change have prevented it from practical applications. Here, we demonstrate a promising metallic lithium anode design by infusing molten lithium into a polymeric matrix. The electrospun polyimide employed is stable against highly reactive molten lithium and, via a conformal layer of zinc oxide coating to render the surface lithiophilic, molten lithium can be drawn into the matrix, affording a nano-porous lithium electrode. Importantly, the polymeric backbone enables uniform lithium stripping/plating, which successfully confines lithium within the matrix, realizingmore » minimum volume change and effective dendrite suppression. The porous electrode reduces the effective current density; thus, flat voltage profiles and stable cycling of more than 100 cycles is achieved even at a high current density of 5 mA cm-2 in both carbonate and ether electrolyte. Furthermore, the advantages of the porous, polymeric matrix provide important insights into the design principles of lithium metal anodes.« less

  1. An Isoreticular Series of Metal-Organic Frameworks with Dendritic Hexacarboxylate Ligands and Exceptionally High Gas-Uptake Capacity

    SciTech Connect (OSTI)

    Yuan, Daqiang; Zhao, Dan; Sun, Daofeng; Zhou, Hong-Cai

    2010-10-01

    Metal-organic frameworks (MOFs) are newly emerging porous materials. Owing to their large surface area and tunable pore size and geometry, they have been studied for applications in gas storage and separation, especially in hydrogen and methane storage and carbon dioxide capture. It has been well established that the high-pressure gravimetric hydrogen-adsorption capacity of an MOF is directly proportional to its surface area. However, MOFs of high surface areas tend to decompose upon activation. In our previous work, we described an approach toward stable MOFs with high surface areas by incorporating mesocavities with microwindows. To extend this work, we now present an isoreticular series of (3,24)-connected MOFs made from dendritic hexacarboxylate ligands, one of which has a Langmuir surface area as high as 6033 m2 g-1. In addition, the gas-adsorption properties of this new isoreticular MOF series have been studied.

  2. A Novel Fenestration Technique for Abdominal Aortic Dissection Membranes Using a Combination of a Needle Re-entry Catheter and the 'Cheese-wire' Technique

    SciTech Connect (OSTI)

    Kos, Sebastian; Guerke, Lorenz; Jacob, Augustinus L.

    2011-12-15

    Purpose: This study was designed to demonstrate the applicability of a combined needle-based re-entry catheter and 'cheese-wire' technique for fenestration of abdominal aortic dissection membranes. Methods: Four male patients (mean age: 65 years) with acute complicated aortic type B dissections were treated at our institution by fenestrating the abdominal aortic dissection membrane using a hybrid technique. This technique combined an initial membrane puncture with a needle-based re-entry catheter using a transfemoral approach. A guidewire was passed through the re-entry catheter and across the membrane. Using a contralateral transfemoral access, this guidewire was then snared, creating a through-and-through wire access. The membrane was then fenestrated using the cheese-wire maneuver. Results: We successfully performed: (a) membrane puncture; (b) guidewire passage; (c) guidewire snaring; and (d) cheese-wire maneuver in all four cases. After this maneuver, decompression of the false lumen and acceptable arterial inflow into the true lumen was observed in all cases. The dependent visceral arteries were reperfused. In one case, portions of the fenestrated membrane occluded the common iliac artery, which was immediately and successfully stented. In another case, long-standing intestinal hypoperfusion before the fenestration resulted in reperfusion-related shock and intraoperative death of the patient. Conclusions: The described hybrid approach for fenestration of dissection membranes is technically feasible and may be established as a therapeutic method in cases with a complicated type B dissection.

  3. Regulation of gene expression and subcellular protein distribution in MLO-Y4 osteocytic cells by lysophosphatidic acid: Relevance to dendrite outgrowth.

    SciTech Connect (OSTI)

    Waters, Katrina M.; Jacobs, Jon M.; Gritsenko, Marina A.; Karin, Norman J.

    2011-02-26

    Osteoblastic and osteocytic cells are highly responsive to the lipid growth factor lysophosphatidic acid (LPA) but the mechanisms by which LPA alters bone cell functions are largely unknown. A major effect of LPA on osteocytic cells is the stimulation of dendrite membrane outgrowth, a process that we predicted to require changes in gene expression and protein distribution. We employed DNA microarrays for global transcriptional profiling of MLO-Y4 osteocytic cells grown for 6 and 24h in the presence or absence of LPA. We identified 932 transcripts that displayed statistically significant changes in abundance of at least 1.25-fold in response to LPA treatment. Gene ontology (GO) analysis revealed that the regulated gene products were linked to diverse cellular processes, including DNA repair, response to unfolded protein, ossification, protein-RNA complex assembly, and amine biosynthesis. Gene products associated with the regulation of actin microfilament dynamics displayed the most robust expression changes, and LPA-induced dendritogenesis in vitro was blocked by the stress fiber inhibitor cytochalasin D. Mass spectrometry-based proteomic analysis of MLO-Y4 cells revealed significant LPA-induced changes in the abundance of 284 proteins at 6h and 844 proteins at 24h. GO analysis of the proteomic data linked the effects of LPA to cell processes that control of protein distribution and membrane outgrowth, including protein localization, protein complex assembly, Golgi vesicle transport, cytoskeleton-dependent transport, and membrane invagination/endocytosis. Dendrites were isolated from LPA-treated MLO-Y4 cells and subjected to proteomic analysis to quantitatively assess the subcellular distribution of proteins. Sets of 129 and 36 proteins were enriched in the dendrite fraction as compared to whole cells after 6h and 24h of LPA exposure, respectively. Protein markers indicated that membranous organelles were largely excluded from the dendrites. Highly represented among

  4. Dendritic cells transduced with Rsf-1/HBXAP gene generate specific cytotoxic T lymphocytes against ovarian cancer in vitro

    SciTech Connect (OSTI)

    Sun, Li; Department of Obstetrics and Gynecology, Qilu Hospital, Shandong University, Jinan, Shandong ; Kong, Beihua; Sheng, Xiugui; Sheu, Jim Jinn-Chyuan; Shih, Ie-Ming

    2010-04-09

    Recently, some studies have indicated that Rsf-1/HBXAP plays a role in chromatin remodeling and transcriptional regulation that may contribute to tumorigenesis in ovarian cancer. The present study demonstrates that using dendritic cells (DCs) from human cord blood CD34{sup +} cells transduced with Rsf-1/HBXAP DNA plasmids by nucleofection generate specific cytotoxic T lymphocytes (CTL) against ovarian cancer in vitro. After transfection, DCs were analyzed for Rsf-1/HBXAP mRNA expression by RT-PCR and protein expression by Western blot. Then the DC phenotypes, T-cell stimulatory capacity, endocytic activity and migration capacity were explored by flow cytometry analysis, allogeneic mixed lymphocyte reaction, endocytosis and transwell chemotaxis assay, respectively. After transfection, Rsf-1/HBXAP expression was detected at mRNA and protein levels. Allogeneic T-cell proliferation induced by transfected DCs was obviously higher than non-transfected DCs, but the endocytosis capacity and migratory ability were not different. Rsf-1/HBXAP gene-transduced DCs could induce antigen-specific CTL and generate a very potent cytotoxicity to OVCAR3 cells. These data suggest that Rsf-1/HBXAP gene-transduced DCs may be a potential adjuvant immunotherapy for ovarian cancer in clinical applications.

  5. 3D dendritic α-Fe{sub 2}O{sub 3} nano-architectures: Synthesis and its application on electrochemical non-enzymatic H{sub 2}O{sub 2} sensing

    SciTech Connect (OSTI)

    Majumder, S.

    2015-06-24

    In this manuscript we have successfully synthesized a large scale 3D dendritic α-Fe{sub 2}O{sub 3} hierarchical structure via a hydrothermal reaction. The crystallinity, composition, purity, morphology of the synthesized α-Fe{sub 2}O{sub 3} are characterized by powder X-ray diffraction (PXRD), field emission scanning electron microscopic (FESEM), energy dispersive X-ray spectroscopic (EDS). FESEM image reveals that the individual α-Fe{sub 2}O{sub 3} dendrite consists of a long central trunk with secondary and tertiary branches. For electrochemical H{sub 2}O{sub 2} sensing we have carried out cyclic voltammetry (CV), amperometric i-t measurement. It has been found that the current density vs. H{sub 2}O{sub 2} concentration calibration curve is linear in nature. The present study reveals that the dendritic α-Fe{sub 2}O{sub 3} hierarchical structure exhibits very sensitive electrochemical sensing capability towards H{sub 2}O{sub 2} reduction.

  6. ElectroNeedle Biological Sensor Array

    ScienceCinema (OSTI)

    None

    2010-01-08

    A device that when pressed against the skin can make rapid, multiplexed diagnostic measurements in a point-of-care setting. 2007 R&D 100 winner (SAND2007-1053P)

  7. ElectroNeedle Biological Sensor Array

    ScienceCinema (OSTI)

    Sandia

    2009-09-01

    : A device that when pressed against the skin can make rapid, multiplexed diagnostic measurements in a point-of-care setting. 2007 R&D 100 winner (SAND2007-1053P)

  8. The Needles Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    and Environmental Issues Click "Edit With Form" above to add content Exploration History First Discovery Well Completion Date: Well Name: Location: Depth: Initial Flow...

  9. The Needles Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    120C393.15 K 248 F 707.67 R 1 USGS Estimated Reservoir Volume: 3 km 1 USGS Mean Capacity: 17 MW 1 Click "Edit With Form" above to add content History and...

  10. Uptake of donor lymphocytes treated with 8-methoxypsoralen and ultraviolet A light by recipient dendritic cells induces CD4{sup +}CD25{sup +}Foxp3{sup +} regulatory T cells and down-regulates cardiac allograft rejection

    SciTech Connect (OSTI)

    Zheng, De-Hua; Dou, Li-Ping; Wei, Yu-Xiang; Du, Guo-Sheng; Zou, Yi-Ping; Song, Ji-Yong; Zhu, Zhi-Dong; Cai, Ming; Qian, Ye-Yong; Shi, Bing-Yi

    2010-05-14

    Extracorporeal photopheresis (ECP) is an effective immunomodulatory therapy and has been demonstrated to be beneficial for graft-vs-host disease and solid-organ allograft rejection. ECP involves reinfusion of a patient's autologous peripheral blood leukocytes treated ex vivo with 8-methoxypsoralen and UVA light radiation (PUVA). Previous studies focused only on ECP treatment of recipient immune cells. Our study is the first to extend the target of ECP treatment to donor immune cells. The results of in vitro co-culture experiments demonstrate uptake of donor PUVA-treated splenic lymphocytes (PUVA-SPs) by recipient immature dendritic cells (DCs). Phagocytosis of donor PUVA-SPs does not stimulate phenotype maturation of recipient DCs. In the same co-culture system, donor PUVA-SPs enhanced production of interleukin-10 and interferon-{gamma} by recipient DCs and impaired the subsequent capability of recipient DCs to stimulate recipient naive T cells. Phagocytosis of donor PUVA-SP (PUVA-SP DCs) by recipient DCs shifted T-cell responses in favor of T helper 2 cells. Infusion of PUVA-SP DCs inhibited cardiac allograft rejection in an antigen-specific manner and induced CD4{sup +}CD25{sup high}Foxp3{sup +} regulatory T cells. In conclusion, PUVA-SP DCs simultaneously deliver the donor antigen and the regulatory signal to the transplant recipient, and thus can be used to develop a novel DC vaccine for negative immune regulation and immune tolerance induction.

  11. Los Angeles Cleantech Incubator: SoCal Edge

    Broader source: Energy.gov [DOE]

    Lead Performer: LA Cleantech Incubator (LACI) -- Los Angeles, CA Partners: LA Better Buildings Challenge (LABBC)

  12. SASproperty8_3_09

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    09 Property List for RO Code '13' 1 BARCODE DESCRIPTION MANUF. MODEL COST 0000016386 COMPUTER PERSONAL E4 GATEWAY E4100 P42.4 1,078.38 0000031152 LaCie 2TB Gigabit Et LACIE...

  13. Multispectral Imaging At The Needles Area (Kratt, Et Al., 2005...

    Open Energy Info (EERE)

    is being used for in situ validation, along with laboratory measurements and x-ray diffraction analyses of samples collected in teh field. We are in the process of producing and...

  14. A Shape Memory Polymer Dialysis Needle Adapter for the Reduction...

    Office of Scientific and Technical Information (OSTI)

    wall shear stress (WSS).2 Nevaril et al.3 show that exposure of red blood cells to ... contributor to vascular access occlusion.4 We present a method for reducing the ...

  15. Force-Based Needle Insertion for Medical Applications (Conference...

    Office of Scientific and Technical Information (OSTI)

    DOE Contract Number: DE-AC05-00OR22725 Resource Type: Conference Resource Relation: Conference: IROS 2009: The 2009 IEEERSJ International Conference on Intelligent Robots and ...

  16. Assembly of a Molecular Needle, from the Bottom Up

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Genetic sequencing studies seem to indicate that type III secretion systems come from a common ancestor foreign to the bacteria. Crystallographic studies such as the one by Yip...

  17. *** CANCELED *** SCIENCE ON SATURDAY- "Finding a Needle in A...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Professor Olga G. Troyanskaya Lewis-Sigler Institute for Integrative Genomics & Department of Computer Science, Princeton University Science on Saturday is a series of lectures ...

  18. City of Needles, California (Utility Company) | Open Energy Informatio...

    Open Energy Info (EERE)

    Data Utility Id 13149 Utility Location Yes Ownership M NERC Location WECC NERC WECC Yes RTO SPP Yes Activity Distribution Yes This article is a stub. You can help OpenEI by...

  19. Finding the needle in the haystack: Algorithms for conformational optimization

    SciTech Connect (OSTI)

    Andricioaei, I.; Straub, J.E.

    1996-09-01

    Algorithms are given for comformational optimization of proteins. The protein folding problems is regarded as a problem of global energy mimimization. Since proteins have hundreds of atoms, finding the lowest-energy conformation in a many-dimensional configuration space becomes a computationally demanding problem.{copyright} {ital American Institute of Physics.}

  20. Dynamics of dendritic polymers in the bulk and under confinement

    SciTech Connect (OSTI)

    Chrissopoulou, K.; Fotiadou, S.; Androulaki, K.; Anastasiadis, S. H.; Tanis, I.; Karatasos, K.; Prevosto, D.; Labardi, M.; Frick, B.

    2014-05-15

    The structure and dynamics of a hyperbranched polyesteramide (Hybrane S 1200) polymer and its nanocomposites with natural montmorillonite (Na{sup +}-MMT) are investigated by XRD, DSC, QENS, DS and Molecular Dynamics (MD) simulation. In bulk, the energy-resolved elastically scattered intensity from the polymer exhibits two relaxation steps, one attributed to sub-T{sub g} motions and one observed at temperatures above the glass transition, T{sub g}. The QENS spectra measured over the complete temperature range are consistent with the elastic measurements and can be correlated to the results emerging from the detailed description afforded by the atomistic simulations, which predict the existence of three relaxation processes. Moreover, dielectric spectroscopy shows the sub- T{sub g} beta process as well as the segmental relaxation. For the nanocomposites, XRD reveals an intercalated structure for all hybrids with distinct interlayer distances due to polymer chains residing within the galleries of the Na{sup +}-MMT. The polymer chains confined within the galleries show similarities in the behavior with that of the polymer in the bulk for temperatures below the bulk polymer T{sub g}, whereas they exhibit frozen dynamics under confinement at temperatures higher than that.

  1. An Isoreticular Series of Metal-Organic Frameworks with Dendritic...

    Office of Scientific and Technical Information (OSTI)

    obtain a copy of this journal article from the publisher. Find in Google Scholar Find in Google Scholar Search WorldCat Search WorldCat to find libraries that may hold this journal

  2. 09-01-2010 CA-B-10-0134

    National Nuclear Security Administration (NNSA)

    Sandia Site Office Thermal Transport Properties of Nanostructured Materials for Energy Conversion Sandia National Laboratories - California LACY,SUSAN DOYLENE 09012010

  3. 11-03-2010 CA-B-10-0149

    National Nuclear Security Administration (NNSA)

    Sandia National LaboratoriesCalifornia (SNLCA), proposes to construct and test an ... Detector, Add-On Task Sandia National Laboratories - California LACY,SUSAN DOYLENE 1103

  4. Evaluation Project 4492

    National Nuclear Security Administration (NNSA)

    preparation of a final report. Sandia Site Office Mesofluidic System for Automated Proteins Enrichment Sandia National Laboratories - California LACY,SUSAN DOYLENE 08032011

  5. Evaluation Project 4492

    National Nuclear Security Administration (NNSA)

    65 Sandia National LaboratoriesCalifornia (SNLCA) proposes to conduct microfluidics ... Joint Sandia - UTMB Microfluidics Sandia National Laboratories - California LACY,SUSAN ...

  6. 10-04-2010 CA-B-10-0139

    National Nuclear Security Administration (NNSA)

    energy conversion phenomena. Sandia Site Office Nanostructured Metal Oxide Photoelectrodes for Solar Hydrogen Production Lawrence Berkeley Laboratory LACY,SUSAN DOYLENE 1004

  7. 08-17-2010 NNSA-B-10-0338

    National Nuclear Security Administration (NNSA)

    utilities could support as many as ten eventually. Sandia Site Office Provide Utilities for Mini-Cielo Computer Sandia National Laboratories - New Mexico LACY,SUSAN DOYLENE ...

  8. 06-14-2010 NNSA-B-10-0269

    National Nuclear Security Administration (NNSA)

    optimal desalination techniques for application to Libyan seawater. Sandia Site Office Libyan Desalination Pilot Demonstration Program Tripoli, Libya LACY,SUSAN DOYLENE 0614

  9. Electric field induced needle-pulsed arc discharge carbon nanotube production apparatus: Circuitry and mechanical design

    SciTech Connect (OSTI)

    Kia, Kaveh Kazemi; Bonabi, Fahimeh

    2012-12-15

    A simple and low cost apparatus is reported to produce multiwall carbon nanotubes and carbon nano-onions by a low power short pulsed arc discharge reactor. The electric circuitry and the mechanical design details and a micro-filtering assembly are described. The pulsed-plasma is generated and applied between two graphite electrodes. The pulse width is 0.3 {mu}s. A strong dc electric field is established along side the electrodes. The repetitive discharges occur in less than 1 mm distance between a sharp tip graphite rod as anode, and a tubular graphite as cathode. A hydrocarbon vapor, as carbon source, is introduced through the graphite nozzle in the cathode assembly. The pressure of the chamber is controlled by a vacuum pump. A magnetic field, perpendicular to the plasma path, is provided. The results show that the synergetic use of a pulsed-current and a dc power supply enables us to synthesize carbon nanoparticles with short pulsed plasma. The simplicity and inexpensiveness of this plan is noticeable. Pulsed nature of plasma provides some extra degrees of freedom that make the production more controllable. Effects of some design parameters such as electric field, pulse frequency, and cathode shape are discussed. The products are examined using scanning probe microscopy techniques.

  10. Point spread function of the optical needle super-oscillatory lens

    SciTech Connect (OSTI)

    Roy, Tapashree; Rogers, Edward T. F.; Yuan, Guanghui; Zheludev, Nikolay I.

    2014-06-09

    Super-oscillatory optical lenses are known to achieve sub-wavelength focusing. In this paper, we analyse the imaging capabilities of a super-oscillatory lens by studying its point spread function. We experimentally demonstrate that a super-oscillatory lens can generate a point spread function 24% smaller than that dictated by the diffraction limit and has an effective numerical aperture of 1.31 in air. The object-image linear displacement property of these lenses is also investigated.

  11. Microstructure Development in Electron Beam-Melted Inconel 718 and Associated Tensile Properties

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kirka, M. M.; Unocic, K. A.; Raghavan, N.; Medina, F.; Dehoff, R. R.; Babu, S. S.

    2016-02-12

    During the electron beam melting (EBM) process, builds occur at temperatures in excess of 800°C for nickel-base superalloys such as Inconel 718. When coupled with the temporal differences between the start and end of a build, a top-to-bottom microstructure gradient forms. Characterized in this study is the microstructure gradient and associated tensile property gradient that are common to all EBM Inconel 718 builds. From the characteristic microstructure elements observed in EBM Inconel 718 material, the microstructure gradient can be classified into three distinct regions. Region 1 (top of a build) and is comprised of a cored dendritic structure that includesmore » carbides and Laves phase within the interdendritic regions. Region 2 is an intermediate transition zone characterized by a diffuse dendritic structure, dissolution of the Laves phase, and precipitation of δ needle networks within the interdendritic regions. The bulk structure (Region 3) is comprised of a columnar grain structure lacking dendritic characteristics with δ networks having precipitated within the grain interiors. Mechanically at both 20°C and 650° C, the yield strength, ultimate tensile strength, and elongation at failure exhibit the general trend of increasing with increasing build height.« less

  12. Atomistic to continuum modeling of solidification microstructures

    SciTech Connect (OSTI)

    Karma, Alain; Tourret, Damien

    2015-09-26

    We summarize recent advances in modeling of solidification microstructures using computational methods that bridge atomistic to continuum scales. We first discuss progress in atomistic modeling of equilibrium and non-equilibrium solid–liquid interface properties influencing microstructure formation, as well as interface coalescence phenomena influencing the late stages of solidification. The latter is relevant in the context of hot tearing reviewed in the article by M. Rappaz in this issue. We then discuss progress to model microstructures on a continuum scale using phase-field methods. We focus on selected examples in which modeling of 3D cellular and dendritic microstructures has been directly linked to experimental observations. Finally, we discuss a recently introduced coarse-grained dendritic needle network approach to simulate the formation of well-developed dendritic microstructures. The approach reliably bridges the well-separated scales traditionally simulated by phase-field and grain structure models, hence opening new avenues for quantitative modeling of complex intra- and inter-grain dynamical interactions on a grain scale.

  13. Atomistic to continuum modeling of solidification microstructures

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Karma, Alain; Tourret, Damien

    2015-09-26

    We summarize recent advances in modeling of solidification microstructures using computational methods that bridge atomistic to continuum scales. We first discuss progress in atomistic modeling of equilibrium and non-equilibrium solid–liquid interface properties influencing microstructure formation, as well as interface coalescence phenomena influencing the late stages of solidification. The latter is relevant in the context of hot tearing reviewed in the article by M. Rappaz in this issue. We then discuss progress to model microstructures on a continuum scale using phase-field methods. We focus on selected examples in which modeling of 3D cellular and dendritic microstructures has been directly linked tomore » experimental observations. Finally, we discuss a recently introduced coarse-grained dendritic needle network approach to simulate the formation of well-developed dendritic microstructures. The approach reliably bridges the well-separated scales traditionally simulated by phase-field and grain structure models, hence opening new avenues for quantitative modeling of complex intra- and inter-grain dynamical interactions on a grain scale.« less

  14. Vehicle Technologies Office Merit Review 2016: Lithium Dendrite Prevention for Lithium-Ion Batteries

    Broader source: Energy.gov [DOE]

    Presentation given by Pacific Northwest National Laboratory (PNNL) at the 2016 DOE Vehicle Technologies Office and Hydrogen and Fuel Cells Program Annual Merit Review and Peer Evaluation Meeting...

  15. Continuous process for forming sheet metal from an alloy containing non-dendritic primary solid

    DOE Patents [OSTI]

    Flemings, Merton C.; Matsuniya, Tooru

    1983-01-01

    A homogeneous mixture of liquid-solid metal is shaped by passing the composition from an agitation zone onto a surface moving relative to the exit of the agitation zone. A portion of the composition contacting the moving surface is solidified and the entire composition then is formed.

  16. ARM - Publications: Science Team Meeting Documents

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    MODIS Data Alexandrov, M.D.(a,b), Marshak, A.(b), Cairns, B.(a,b), Lacis, A.A.(b), and Carlson, B.E.(b), Columbia University (a), NASA (b) Thirteenth Atmospheric Radiation...

  17. ARM - Publications: Science Team Meeting Documents

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Properties from Aircraft Measurements Over the SGP Cairns, B. (a), Lacis, A.A. (b), Carlson, B.E. (b), Alexandrov, A. (a), and Barnard, J.C. (c), Columbia University (a), NASA...

  18. ARM - Publications: Science Team Meeting Documents

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Scattering Albedo of Aerosols During the Aerosol IOP Cairns, B.(a), Gianelli, S.M.(a), Carlson, B.E.(b), and Lacis, A.A.(b), Columbia University (a), NASA GISS (b) Fourteenth...

  19. ARM - 2003 Science Team Meeting Pictures

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Janet Inrieri discuss Dave and Tom's poster. ARM Chief Scientist Tom Ackerman, Dave Turner, and Janet Inrieri discuss Dave and Tom's poster. K.N. Liou and Andy Lacis discuss...

  20. cairns-99

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Photopolarimetry and Aerosols B. Cairns, B. E. Carlson, A. A. Lacis, and L. D. Travis National Aeronautics and Space Administration Goddard Institute for Space Studies New York, New York Introduction Evidence that tropospheric aerosols can cause a direct radiative forcing comparable in magnitude, though opposite in sign, to the expected climate forcing by greenhouse gases (Hansen and Lacis 1990; Penner et al. 1994), makes a compelling case for improved efforts to obtain accurate information

  1. Highlights of SunShot Projects: Interconnection as Part of a Strategic Resources Planning Process

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Highlights of SunShot Projects: Interconnection as Part of a Strategic Resource Planning Process" Virginia Lacy and Mark Dyson with RMI Electricity Practice and Alison Kling with Con Edison September 24, 2014 2 Speakers Alison Kling Distributed Generation Specialist Con Edison Virgina Lacy Principal RMI Electricity Practice Kristen Ardani Solar Analyst National Renewable Energy Laboratory (DGIC moderator) Mark Dyson Senior Associate RMI Electricity Practice A POTENTIAL eLAB INITIATIVE

  2. Electron microscopy study of direct laser deposited IN718

    SciTech Connect (OSTI)

    Ding, R.G.; Huang, Z.W.; Li, H.Y.; Mitchell, I.; Baxter, G.; Bowen, P.

    2015-08-15

    The microstructure of direct laser deposited (DLD) IN718 has been investigated in detail using scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The results confirm that the dendrite core microstructure can be linked to the cooling rate experienced during the deposition. A ~ 100 μm wide δ partially dissolved region in the IN718 substrate was observed close to the substrate/deposit boundary. In the deposited IN718, γ/Laves eutectic constituent is the predominant minor microconstituent. Irregular and regular (small) (Nb,Ti)C carbides and a mixture of the carbides and Laves were observed. Most M{sub 3}B{sub 2} borides were nucleated around a (Nb,Ti)C carbide. Needles of δ phase precipitated from the Laves phase were also observed. A complex constituent (of Laves, δ, α-Cr, γ″, and γ matrix) is reported in IN718 for the first time. The formation of α-Cr particles could be related to Cr rejection during the formation and growth of Cr-depleted δ phase. - Highlights: • Secondary phases in IN718 deposits were identified using electron diffraction and EDS. • MC, M{sub 3}B{sub 2}, γ/Laves eutectic and γ/NbC/Laves eutectic were observed. • Needle-like δ phases were precipitated from the Laves phase. • A complex constituent (Laves, δ, α-Cr, γ″ and γ) was reported for the first time.

  3. SASproperty8_3_09

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    04/09 Property List for RO Code '13' 1 BARCODE DESCRIPTION MANUF. MODEL COST 0000016386 COMPUTER PERSONAL E4 GATEWAY E4100 P4/2.4 $1,078.38 0000031152 LaCie 2TB Gigabit Et LACIE 300961 $999.00 S7237 KODAK PHOTO CD PLAYE KODAK N/A $449.00 0000017846 PRESS BRIDGE VIDEO/A OPAMP LABS VA-8 $1,195.00 0000021344 COMPUTER GATEWAY E-4 GATEWAY E-4500 D $735.00 0000015660 COMPUTER PERSONAL E- GATEWAY E-4000 P4/1.8 $950.00 0000021059 MACKIE AUDIO MIXER ( MACKIE 1402VLZ PRO $399.00 0000030017 CAMCORDER

  4. Microsoft PowerPoint - Gianelli_ARM2007.PPT [Compatibility Mode]

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Bimodal Aerosol Analysis of Bimodal Aerosol Size Distributions at SGP Using RSS 105 and AERONET CIMEL D t AERONET CIMEL Data Scott M Gianelli a,b Andrew A Lacis b Scott M. Gianelli , , Andrew A. Lacis , and Barbara E. Carlson b a Columbia University New York NY a. Columbia University, New York, NY b. NASA Goddard Institute for Space Studies, New York, NY Need for Improved Aerosol Need for Improved Aerosol Size Distribution Monitoring * Liu et al., 2006: Aerosol size distribution climatology in

  5. Towards quantitative off-axis electron holographic mapping of the electric field around the tip of a sharp biased metallic needle

    SciTech Connect (OSTI)

    Beleggia, M.; Kasama, T.; Larson, D. J.; Kelly, T. F.; Dunin-Borkowski, R. E.; Pozzi, G.

    2014-07-14

    We apply off-axis electron holography and Lorentz microscopy in the transmission electron microscope to map the electric field generated by a sharp biased metallic tip. A combination of experimental data and modelling provides quantitative information about the potential and the field around the tip. Close to the tip apex, we measure a maximum field intensity of 82 MV/m, corresponding to a field k factor of 2.5, in excellent agreement with theory. In order to verify the validity of the measurements, we use the inferred charge density distribution in the tip region to generate simulated phase maps and Fresnel (out-of-focus) images for comparison with experimental measurements. While the overall agreement is excellent, the simulations also highlight the presence of an unexpected astigmatic contribution to the intensity in a highly defocused Fresnel image, which is thought to result from the geometry of the applied field.

  6. Strong influence of periodic boundary conditions on lateral diffusion in lipid bilayer membranes

    SciTech Connect (OSTI)

    Camley, Brian A.; Lerner, Michael G.; Pastor, Richard W.; Brown, Frank L. H.

    2015-12-28

    The Saffman-Delbrück hydrodynamic model for lipid-bilayer membranes is modified to account for the periodic boundary conditions commonly imposed in molecular simulations. Predicted lateral diffusion coefficients for membrane-embedded solid bodies are sensitive to box shape and converge slowly to the limit of infinite box size, raising serious doubts for the prospects of using detailed simulations to accurately predict membrane-protein diffusivities and related transport properties. Estimates for the relative error associated with periodic boundary artifacts are 50% and higher for fully atomistic models in currently feasible simulation boxes. MARTINI simulations of LacY membrane protein diffusion and LacY dimer diffusion in DPPC membranes and lipid diffusion in pure DPPC bilayers support the underlying hydrodynamic model.

  7. CX-100295 Categorical Exclusion Determination | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    5 Categorical Exclusion Determination CX-100295 Categorical Exclusion Determination Accelerating Market Adoption of Best-in-Class Building Technologies, the Technology Demonstration Initiative (TDI) Award Number: DE-EE0007065 CX(s) Applied: A9 Building Technologies Office Date: 06/17/2015 Location(s): CA Office(s): Golden Field Office The U.S. Department of Energy (DOE) is proposing to provide federal funding to Los Angeles Cleantech Incubator (LACI) to identify, evaluate and initiate

  8. Technical Sessions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Analysis of Cloud Radiative Forcing and Feedback in a Climate General Circulation Model A. Lacis NASA Goddard Space Flight Center Institute for Space Studies New York, NY 10025 and diffuse transmission as a function of solar zenith angle, optical depth, cloud particle size, and single scatter- ing albedo. These results will replace the current approach which uses the "Single Gauss Point" doubling algorithm to obtain cloud radiative properties. However, the stack of homogeneous layers

  9. ARM - Publications: Science Team Meeting Documents

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Aerosol Absorption, Optical Depth and Vertical Extent Estimates Using UV/blue Satellite Measurements Cairns, B., and Alexandrov, M.D., Columbia University; Carlson, B.E., and Lacis, A.A., NASA Goddard Institute for Space Studies Eighth Atmospheric Radiation Measurement (ARM) Science Team Meeting The radiative balance of the atmosphere and the climatological response of the atmospheric circulation to changes in aerosol loading is principally determined by the vertical extent and single-scatter

  10. ARM - Publications: Science Team Meeting Documents

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Radiative Cooling by Stratospheric Water Vapor: GCM Treatment vs. Observations Lacis, A.A. (a) and Oinas, V. (b), NASA Goddard Institute for Space Studies Eleventh Atmospheric Radiation Measurement (ARM) Science Team Meeting The stratosphere has been cooling over the past two to three decades by about 1-2 K/decade. Recent attempts to reconcile decadal trends in climate data and climate model simulations suggest that stratospheric water vapor is potentially an important contributor to the

  11. Section 14

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    An Analysis of Ground-Based Polarimetric Sky Radiance Measurements B. Cairns Columbia University New York, New York B. E. Carlson and A. A. Lacis NASA/Goddard Institute for Space Studies New York, New York E. Russell Spectir Corporation Goleta, California Abstract An analysis of polarimetric sky radiance measurements made with the engineering model of the Galileo photopolarimeter/radiometer at wavelengths of 410 nm and 678 nm is presented. The polarization measurements are accurate to within

  12. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Characterization of Atmospheric Aerosols Using MFRSR Measurements Download a printable PDF Submitter: Alexandrov, M. D., Columbia University Area of Research: Aerosol Properties Working Group(s): Aerosol Journal Reference: Alexandrov, MD, AA Lacis, BE Carlson, and B Cairns. 2007. "Characterization of atmospheric aerosols using MFRSR measurements." (Journal of Geophysical Research 113, DO8204. Sample spectral optical depths of atmospheric constituents in 300 - 900 nm spectral range:

  13. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Effects of Relative Humidity on Aerosols-Implications for Climate Submitter: Lacis, A. A., NASA - Goddard Institute for Space Studies Area of Research: Aerosol Properties Working Group(s): Aerosol Journal Reference: "Refractive Indices of Three Hygroscopic Aerosols and their Dependence on Relative Humidity," October 2001. Sponsored by the DOE Atmospheric Radiation Measurement (ARM) Program, science collaborators at the National Aeronautics and Space Administration (NASA) Goddard

  14. alexandrov-98.pdf

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Analysis of the MFRSR Data from SGP and NYC Sites M. D. Alexandrov, A. A. Lacis, B. E. Carlson, and B. Cairns NASA-Goddard Institute for Space Studies New York, New York Introduction Aerosols can affect the climate both directly and indirectly and are considered to be the largest source of uncertainty in defining the anthropogenic contribution to global radiative forcing of climate during the past century, and of the projected forcing of climate change in the future. Satellite measurements with

  15. alexandrov-99.PDF

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Validation of MFRSR Data Analysis: Comparison with the Langley Approach M. D. Alexandrov and B. Cairns Columbia University National Aeronautics and Space Administration Goddard Institute for Space Studies New York, New York A. A. Lacis and B. E. Carlson National Aeronautics and Space Administration Goddard Institute for Space Studies New York, New York Introduction In the present study, we validate the retrieval algorithm (Alexandrov et al. 1998a, 1998b, 1998c) for processing of Multifilter

  16. cairns-98.pdf

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5 Estimating Aerosol Absorption, Optical Depth, and Vertical Extent Using Satellite Measurements in the UV/Blue Spectral Domain B. Cairns., A. A. Lacis, and B. E. Carlson NASA-Goddard Institute for Space Studies New York, New York Introduction Until recently, the retrieval of aerosol absorption properties from space seemed so prone to error as to be almost worthless. The principal difficulty being that if the aerosol optical depth is relatively low, then the signal measured at the satellite is

  17. 1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Building Climatologies of Atmospheric Aerosols, Trace Gases, and Water Vapor on the Basis of MFRSR Remote Sensing Retrievals M. D. Alexandrov, A. A. Lacis, B. E. Carlson, and B. Cairns Columbia University National Aeronautics and Space Administration Goddard Institute for Space Studies New York, New York Introduction Atmospheric (and especially tropospheric) aerosols with their direct and indirect radiative forcing remain the source of one of the most significant uncertainties in climate change

  18. 1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Integrated Study of MFRSR-Derived Parameters of Atmospheric Aerosols and Trace Gases Over the ARM Cloud and Radiation Testbed (CART) Site Extended Facilities M. D. Alexandrov and B. Cairns Columbia University National Aeronautics and Space Administration Goddard Institute for Space Studies New York, New York A. A. Lacis and B. E. Carlson National Aeronautics and Space Administration Goddard Institute for Space Studies New York, New York Introduction We present results of a preliminary analysis

  19. Section 71

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Modeling Errors in Diffuse-Sky Radiation A. A. Lacis, J. Chowdhary, B. Cairns and M. I. Mishchenko NASA/Goddard Institute for Space Studies New York, New York Most current methods for calculating radiative transfer treat radiance errors to the point where no one has seriously light as a scalar quantity, even though it is well known that a worried about the adequacy of the scalar approximation in proper description of light requires explicit recognition of its radiative transfer modeling.

  20. CNS employees rise to fitness challenge | Y-12 National Security Complex

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    rise to ... CNS employees rise to fitness challenge Posted: August 29, 2016 - 10:57am Y-12 Site Manager Bill Tindal (second left) and Karen Lacy (right), CNS wellness coordinator and Active for Life program co-director, congratulate members of CNS's winning Active for Life challenge team. This spring, more than 750 Consolidated Nuclear Security, LLC employees participated in the Active for Life℠ challenge, an 8-week program, sponsored by the American Cancer Society®, that encouraged employees

  1. Highlights of SunShot Projects_Interconnection as Part of a Strategic Resource Planning Process

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Highlights of SunShot Projects Interconnection Page 1 of 25 as Part of a Strategic Resource Planning Process Virginia Lacy, Mark Dyson, Kristen Ardani, Alison Kling Page 1 of 25 [Speaker: Kristen Ardani] Cover Slide: Thank you everyone for joining us for today's webinar of the DG Interconnection Collaborative, the topic that we are going to discuss are Highlights of SunShot Projects, Interconnection as Part of a Strategic Resource Plannig Process. Today we are going to hear from RMI, Virginia

  2. Analysis of Langley optical depth data, with aerosol and gas retrievals,

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for the RSS 103 instrument in Barrow, Alaska Analysis of Langley optical depth data, with aerosol and gas retrievals, for the RSS 103 instrument in Barrow, Alaska Gianelli, Scott Columbia University - NASA/GISS Lacis, Andrew NASA/Goddard Institute for Space Studies Carlson, Barbara NASA/Goddard Institute for Space Studies Category: Aerosols Bimodal aerosol retrievals, and high-resolution retrevals of nitrogen dioxide, are performed on the Langley optical depth data from the RSS 103 device

  3. Automated Algorithm for MFRSR Data Analysis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Automated Algorithm for MFRSR Data Analysis M. D. Alexandrov and B. Cairns Columbia University and National Aeronautics and Space Administration Goddard Institute for Space Studies New York, New York A. A. Lacis and B. E. Carlson National Aeronautics and Space Administration Goddard Institute for Space Studies New York, New York A. Marshak National Aeronautics and Space Administration Goddard Space Flight Center Greenbelt, Maryland We present a substantial upgrade of our previously developed

  4. 1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fine and Coarse Mode Aerosols in Southern Great Plains Multi-Filter Rotating Shadowband Radiometer Datasets M. Alexandrov and B. Cairns Columbia University New York, New York M. Alexandrov, B E. Carlson, A.A. Lacis, and B. Cairns National Aeronautics and Space Administration Goddard Institute for Space Studies New York, New York Introduction We present results obtained using the new version of the multi-filter rotating shadowband radiometer (MFRSR) data analysis algorithm (Alexandrov et al.

  5. 1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Inversion of Multi-Angle Radiation Measurement B. Cairns and M. Alexandrov Columbia University New York, New York A. Lacis and B. Carlson National Aeronautics and Space Administration - Goddard Institute for Space Studies New York, New York Motivation Observations of the polarization and reflectance in bands at 865 nm (negligible liquid water absorption) and 2250 nm (strong liquid water absorption) cannot be fitted by a simple atmospheric model consisting of a homogeneous cloud with a single

  6. 1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Improving GCM Aerosol Climatology using Satellite and Ground-Based Measurements L. Liu Department of Applied Physics and Applied Mathematics Columbia University New York, New York A.A. Lacis, B.E. Carlson, M.I. Mishchenko, and B. Cairns NASA Goddard Institute for Space Studies New York, New York Abstract A physically based aerosol climatology is essential to address the questions of global climate changes. We use available satellite and ground-based measurements, i.e., moderate-resolution

  7. 1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Developments in Multi-Filter Rotating Shadowband Radiometer Data Analysis M. Alexandrov and B. Cairns Columbia University New York, New York A.A. Lacis and B.E. Carlson National Aeronautics and Space Administration-Goddard Institute for Space Studies New York, New York Introduction We present further development of our analysis algorithm (Alexandrov et al. 2005) for multi-filter rotating shadowband radiometer (MFRSR) data. The new additions include a study of MFRSR retrievals sensitivity to

  8. 1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALIVE Polarization Measurements B. Cairns, K. Knobelspiesse, and M. Alexandrov Columbia University New York, New York A. Lacis and B. Carlson National Aeronautics and Space Administration-Goddard Institute for Space Studies Greenbelt, Maryland Atmospheric Correction The usual way that polarized reflectance measurements are corrected for the contribution of the surface is to assume that the contribution from the surface to the upwelling radiance at the surface or top of the atmosphere can be

  9. Integrated Study of MFRSR-derived Parameters of Atmospheric Aerosols and Trace Gases Over the ARM CART Site Extended Facili...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Integrated Study of MFRSR-Derived Parameters of Atmospheric Aerosols and Trace Gases Over the ARM CART Site Extended Facilities - Comparison with Satellite and Other Ground-Based Measurements M. D. Alexandrov and B. Cairns Columbia University National Aeronautics and Space Administration Goddard Institute for Space Studies New York, New York A. A. Lacis and B. E. Carlson National Aeronautics and Space Administration Goddard Institute for Space Studies New York, New York Comparison of SGP MFRSR

  10. Clear Skies

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A. A. lacis NASA Goddard Space Flight Center Institute for Space Studies New York, NY 10025 "convective adjustment"takes place. Energy is transported upward within the troposphere and, in the process, the "critical lapse rate" of tropospheric temperature isestablished. Similarly, in response to the seasonally driven change in solar forcing, there is a latitudinal redistribution of energy by dynamical transports resulting in the meridional advection of energy. In view of the

  11. Cloudy Skies

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Analysis of Cloud Radiative Forcing andFeedback in a Climate General Circulation Model A. A. lacis NASA Goddard Space Flight Center Institute for Space Studies New York, NY 10225 The principal objectives of the Atmospheric Radiation Measurement (ARM) Program research at the Goddard Institute for Space Studies (GISS) are 1) to improve and validate the radiation parameterizations in the GISS general circulation model (GCM) through model intercomparisons with line-by-line calculations and through

  12. Dual mode fuel injection system and fuel injector for same

    DOE Patents [OSTI]

    Lawrence, Keith E.; Tian, Ye

    2005-09-20

    A fuel injection system has the ability to produce two different spray patterns depending on the positioning of a needle control valve member. Positioning of the needle control valve member determines which of the two needle control chambers are placed in a low pressure condition. First and second needle valve members have closing hydraulic surfaces exposed to fluid pressure in the two needle control chambers. The injector preferably includes a homogenous charge nozzle outlet set and a conventional nozzle outlet set controlled respectively, by the first and second needle valve members.

  13. ARM - Publications: Science Team Meeting Documents

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Retrieving Aerosol Size Distribution Information from Direct Beam Measurements Gianelli, S.M.(a,b), Carlson, B.E.(b), and Lacis, A.A.(b), Columbia University(a), NASA-GISS(b) An algorithm designed specifically to retrieve aerosol size distributions has been designed and implemented using RSS direct-beam data. The wavelengths used in this retrieval are 380, 400, 415, 440, 450, 500, 525, 550, 585, 610, 670, 750, 780, 870, 1020, and 1034 nm. All the MFRSR and CIMEL wavelengths are included, along

  14. Section 33

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in ' c n I o n exp (&T in / µ i ) T i,n ' µ i log (I o n / I i,n ) % µ i log (c n ) Session Papers 145 (1) (2) Multi-Spectral Atmospheric Column Extinction Analysis of Multi-Filter Rotating Shadowband Radiometer Measurements A.A. Lacis and B.E. Carlson National Aeronautics and Space Administration/Goddard Institute for Space Studies New York, New York B. Cairns Columbia University National Aeronautics and Space Administration/Goddard Institute for Space Studies New York, New York Abstract

  15. Crystal structural study of ternary molybdate LiRbBi{sub 2}(MoO{sub 4}){sub 4}

    SciTech Connect (OSTI)

    Klevtsova, R.F.; Glinskaya, L.A.; Alekseev, V.I.

    1994-03-01

    Single crystals of the title compound have been synthesized and its crystal structure has been determined. The compound crystallizes in the monoclinic system, space group C2/c, Z = 2 (a = 5.3056, b = 12.976, c = 19.578 {angstrom}, {beta} = 92.583{degrees}, R = 0.029). A distinctive feature of the structure is lacy layers of eight-vertex Bi polyhedra and Mo tetrahedra connected to them via common vertices. The adjacent layers are linked together by ten-vertex Rb polyhedra and Li octahedra.

  16. X:\ARM_19~1\P139-154.WPD

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    v eff 0.35. µm µm µm Session Papers 151 A General Circulation Model (GCM) Parameterization of Pinatubo Aerosols A. A. Lacis, B.E. Carlson, and M.I. Mishchenko NASA Goddard Institute for Space Studies New York, New York The June 1991 volcanic eruption of Mt. Pinatubo in the model (GCM) predictions of the impact on global climate Philippines is by far the largest and the best documented global climate forcing experiment in recorded history. The time development and geographical dispersion of

  17. X:\ARM_19~1\P193-223.WPD

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    eff µm r eff µm 10 3 ( i ) i w µ 0 µ 180 Session Papers 211 Figure 1. Phase functions of fractal ice particles (solid line) and ISCCP water droplets (dotted line) at 0.63 µm. Effect of Particle Nonsphericity on Bidirectional Reflectance of Cirrus Clouds M. I. Mishchenko, W. B. Rossow, A. Macke, and A. A. Lacis National Aeronautics and Space Administration Goddard Institute for Space Studies New York, New York Previous analyses of the First International Satellite Cloud Climatology Project

  18. Section 85

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    i ' -ln I i I 0 i *µ%c i µ, c i Wm &2 c i NO 2 O 3 NO 2 c i c i NO 2 Session Papers 379 (1) Retrieval of Aerosol Optical Depth, Aerosol Size Distribution Parameters, Ozone and Nitrogen Dioxide Column Amounts from Multifilter Rotating Shadowband Radiometer Data M. Alexandrov, A. A. Lacis, B. E. Carlson and B. Cairns National Aeronautics and Space Administration Goddard Institute for Space Studies New York, New York Introduction The MultiFilter Rotating Shadowband Radiometer (MFRSR)

  19. Heat exchange apparatus

    DOE Patents [OSTI]

    Degtiarenko, Pavel V.

    2003-08-12

    A heat exchange apparatus comprising a coolant conduit or heat sink having attached to its surface a first radial array of spaced-apart parallel plate fins or needles and a second radial array of spaced-apart parallel plate fins or needles thermally coupled to a body to be cooled and meshed with, but not contacting the first radial array of spaced-apart parallel plate fins or needles.

  20. Pyramid Lake Paiute Tribe - Pyramid Lake Energy Project - Geothermal Assessment

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Tribe Pyramid Lake Paiute Tribe Pyramid Lake Energy Project Pyramid Lake Energy Project Geothermal Assessment Geothermal Assessment Pyramid Lake Paiute Reservation 40 miles north of Reno 475,000 acres Pyramid Lake 125,000 surface acres Northern Reservation Needles Area Needles Geyser Needles Geyser Exploration conducted Exploration conducted in 1968 in 1968 Hot water was found Hot water was found at 160 degrees f at 160 degrees f Was not considered Was not considered feasible feasible PLEP

  1. Overview of SoCalGas/SDG&E System Design & Operations

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    North Needles, Topock, Kramer Junction San Juan Basin, Rocky Mountain 1590 Southern Ehrenberg, Blythe, Otay Mesa Permian Basin, LNG 1210 Wheeler Wheeler Ridge, Kern River Sta. ...

  2. Apparatus and method for delivering a fluid to a container

    DOE Patents [OSTI]

    Turner, Terry D.

    2002-01-01

    An apparatus for delivering a fluid into a container has a carriage movably associated with a holding mechanism along an axis. A piston is attached to the carriage and a cylinder is slidably attached to the piston along the axis. The cylinder has a hole formed therein that extends along the axis. A needle extending along the axis is attached to the piston and passes through the cylinder hole. The needle has a first operative position relative to the piston when the needle is retracted within the cylinder and a second operative position relative to the piston when the needle extends from the cylinder.

  3. Mixed Mode Fuel Injector And Injection System

    DOE Patents [OSTI]

    Stewart, Chris Lee; Tian, Ye; Wang, Lifeng; Shafer, Scott F.

    2005-12-27

    A fuel injector includes a homogenous charge nozzle outlet set and a conventional nozzle outlet set that are controlled respectively by first and second three way needle control valves. Each fuel injector includes first and second concentric needle valve members. One of the needle valve members moves to an open position for a homogenous charge injection event, while the other needle valve member moves to an open position for a conventional injection event. The fuel injector has the ability to operate in a homogenous charge mode with a homogenous charge spray pattern, a conventional mode with a conventional spray pattern or a mixed mode.

  4. Hybrid anodes for redox flow batteries (Patent) | DOEPatents

    Office of Scientific and Technical Information (OSTI)

    RFBs having solid hybrid electrodes can address at least the problems of active material consumption, electrode passivation, and metal electrode dendrite growth that can be ...

  5. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... (2) atomic and molecular physics (1) batteries (1) carbonic acid esters lithium batteries (1) coordination (1) dendrite-free (1) ec (1) electrochemical (1) energy storage ...

  6. High Rate and Stable Cycling of Lithium Metal Anode (Journal...

    Office of Scientific and Technical Information (OSTI)

    Title: High Rate and Stable Cycling of Lithium Metal Anode Lithium (Li) metal is an ideal anode material for rechargeable batteries. However, dendritic Li growth and limited ...

  7. High elastic modulus polymer electrolytes (Patent) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    high energy density, high cycle life batteries that do not suffer from failures due to side reactions and dendrite growth on the Li electrodes, and other potential applications. ...

  8. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Filter by Author Davies, Gordon (1) Huang Qiong (1) Mo Xuanxue (1) Rivers, Mark (1) Tan ... ; Zhao Shanrong ; Huang Qiong ; Davies, Gordon ; Mo Xuanxue Diopside dendrites and ...

  9. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    tips as a function of Dmm. Solid lines denote medians, boundaries, and 10th and 90th percentiles. Blue colors represent times graupel dominated, red represents dendrites dominated;...

  10. Ceramic-Metal Composites for Electrodes of Lithium Ion Batteries...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ceramic-Metal Composites for Electrodes of Lithium Ion Batteries Lawrence Berkeley ... it desirable for use in rechargeable batteries, but its tendency to form dendrites has ...

  11. Transmission electron microscopy study of precipitates in an artificially aged Al–12.7Si–0.7Mg alloy

    SciTech Connect (OSTI)

    Liu, Fang; Yu, Fuxiao; Zhao, Dazhi; Zuo, Liang

    2015-09-15

    An investigation of Al–12.7Si–0.7Mg alloy aged at 160 °C, 180 °C and 200 °C for 3 h was carried out in order to identify the precipitating phases. Regular transmission and high resolution electron microscopy (TEM and HREM) were employed for this purpose. The studies were focused on the dark spots and needle-shaped precipitates lying in (001){sub Al} plane. Based on the HREM observations, dark spots and needle-shaped precipitates have different characteristics. The results revealed that the ellipsoidal and needle-shaped precipitates along <100> direction of the matrix coexist in the alloy by tilting experiments at given aging condition. The ellipsoidal dark spot precipitates viewing along [001]{sub Al} is not cross-sectional image of needle-shaped precipitates along <001>{sub Al}. Needle-shaped precipitate is coherent with the matrix. The diffraction pattern associated with the ellipsoidal precipitates is consistent with β″ reported in literature. - Highlights: • Wrought Al–Si–Mg alloy has been investigated to identify the precipitating phases. • The ellipsoidal and needle-shaped precipitates coexist in wrought Al–Si–Mg alloy. • The needle-shaped and ellipsoidal precipitates exhibit different characteristics.

  12. Improvement in Clouds and the Earth's Radiant Energy System/Surface and Atmosphere Radiation Budget Dust Aerosol Properties, Effects on Surface Validation of Clouds and Radiative Swath

    SciTech Connect (OSTI)

    Rutan, D.; Rose, F.; Charlock, T.P.

    2005-03-18

    Within the Clouds and the Earth's Radiant Energy System (CERES) science team (Wielicki et al. 1996), the Surface and Atmospheric Radiation Budget (SARB) group is tasked with calculating vertical profiles of heating rates, globally, and continuously, beneath CERES footprint observations of Top of Atmosphere (TOA) fluxes. This is accomplished using a fast radiative transfer code originally developed by Qiang Fu and Kuo-Nan Liou (Fu and Liou 1993) and subsequently highly modified by the SARB team. Details on the code and its inputs can be found in Kato et al. (2005) and Rose and Charlock (2002). Among the many required inputs is characterization of the vertical column profile of aerosols beneath each footprint. To do this SARB combines aerosol optical depth information from the moderate-resolution imaging spectroradiometer (MODIS) instrument along with aerosol constituents specified by the Model for Atmosphere and Chemical Transport (MATCH) of Collins et al. (2001), and aerosol properties (e.g. single scatter albedo and asymmetry parameter) from Tegen and Lacis (1996) and OPAC (Hess et al. 1998). The publicly available files that include these flux profiles, called the Clouds and Radiative Swath (CRS) data product, available from the Langley Atmospheric Sciences Data Center (http://eosweb.larc.nasa.gov/). As various versions of the code are completed, publishable results are named ''Editions.'' After CRS Edition 2A was finalized it was found that dust aerosols were too absorptive. Dust aerosols have subsequently been modified using a new set of properties developed by Andy Lacis and results have been released in CRS Edition 2B. This paper discusses the effects of changing desert dust aerosol properties, which can be significant for the radiation budget in mid ocean, a few thousand kilometers from the source regions. Resulting changes are validated via comparison of surface observed fluxes from the Saudi Solar Village surface site (Myers et al. 1999), and the E13 site

  13. Microinjector for blasocysts

    DOE Patents [OSTI]

    Remenyik, C.J.; Woychik, R.P.; Patek, D.R.; Hawk, J.A.; Turner, J.C.

    1999-03-02

    An electromechanical device is disclosed for driving the tip of a microinjection cannula, or needle, through the outer barrier of a blastocyst, cell, or cell nucleus for the injection of cells or other bioactive materials. Either a flexible frame or a ram moving within a base member is employed. Cannula motion is achieved by means of a piezoelectric stack and spring return system. The thrust motion over a predetermined microscopic distance is achieved without cannula setback prior to the thrust movement. Instead of specially prepared beveled and tipped needles, standard unimproved cannulas or needles can be used. 6 figs.

  14. Microinjector for blasocysts

    DOE Patents [OSTI]

    Remenyik, Carl J.; Woychik, Richard P.; Patek, David R.; Hawk, James A.; Turner, John C.

    1999-01-01

    An electromechanical device for driving the tip of a microinjection cannula, or needle, through the outer barrier of a blastocyst, cell, or cell nucleus for the injection of cells or other bioactive materials. Either a flexible frame or a ram moving within a base member is employed. Cannula motion is achieved by means of a piezoelectric stack and spring return system. The thrust motion over a predetermined microscopic distance is achieved without cannula setback prior to the thrust movement. Instead of specially prepared beveled and tipped needles, standard unimproved cannulas or needles can be used.

  15. Air-pollution injury on Pinus strobus in Indiana Dunes National Lakeshore - 1985 survey results. Final report

    SciTech Connect (OSTI)

    Sanchini, P.J.

    1986-10-01

    Visible symptoms of ozone injury were observed on 100% of the Eastern white pine trees (Pinus strobus) sampled in 1985 from permanent pine plots at Indiana Dunes National Lakeshore. Average injury was low and affected about 5% of the needle surface. Only 6% of the trees sampled had more than 10% injury. Fleck injury was the most common ozone symptom encountered, followed by tipburn and chlorotic mottle. Significant variation among plots existed in total ozone injury, chlorotic mottle, tipburn, and needle length. Symptoms of other injury types were observed on 9% of the needle surfaces of sampled trees.

  16. Apparatus for silicon web growth of higher output and improved growth stability

    DOE Patents [OSTI]

    Duncan, Charles S.; Piotrowski, Paul A.

    1989-01-01

    This disclosure describes an apparatus to improve the web growth attainable from prior web growth configurations. This apparatus modifies the heat loss at the growth interface in a manner that minimizes thickness variations across the web, especially regions of the web adjacent to the two bounding dendrites. In the unmodified configuration, thinned regions of web, adjacent to the dendrites, were found to be the origin of crystal degradation which ultimately led to termination of the web growth. According to the present invention, thinning adjacent to the dendrites is reduced and the incidence of crystal degradation is similarly reduced.

  17. A Conceptual Model of DI Diesel Combustion Based on Laser-Sheet...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Table 2 summarizes the specifications of the fuel injector. The injector is instru- mented with a Hall-effect needle lift sensor, and injection pressure is determined from strain ...

  18. RADIOLOGICAL ASSESSMENT OF BALLOD AND ASSOCIATES PROPERTY

    Office of Legacy Management (LM)

    ... in the 0.185 MeV photopeak area from the 0.186 MeV Ra-226 gamma ray were subtracted. ... calibrated ('15%) with a sealed Ra-226 needle, certified by Atomic Energy of Canada, Ltd. ...

  19. Tax Credit for Forest Derived Biomass

    Broader source: Energy.gov [DOE]

    Forest-derived biomass includes tree tops, limbs, needles, leaves, and other woody debris leftover from activities such as timber harvesting, forest thinning, fire suppression, or forest health m...

  20. 1999 - 10 | Jefferson Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    October 1999 Sun, 10241999 - 11:00pm A Needle Biopsy Alternative Riverside to Test Small Camera that Points Out Growths in Breast (Daily Press) Fri, 10221999 - 11:00pm Science...

  1. Fermilab Today | Safety Tip of the Week Archive | 2010

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the possibility of clotting. A clot that dislodges and travels to the heart or lungs can cause death. July 12, 2010 Looking for the bad guy's needle in a data haystack...

  2. Microsoft PowerPoint - Sacci_2015_UserProjectHighlight_NanoLett...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lithium dendrite formation is a major safety concern existing in Li-ion and Li-metal batteries. In situ ec-STEM (a liquid cell electron microscopy based characterization method)...

  3. https://www.eere-pmc.energy.gov/GONEPA/ND_Form.aspx?key=21901

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Dr. Prashant Kumta/University of Pittsburgh STATE: PA PROJECT TITLE : Engineering Approaches to Dendrite Free Lithium Anodes Funding Opportunity Announcement Number Procurement Instrument Number NEPA Control Number CID Number DE-FOA-0001384 DE-EE0007797

  4. New Jersey firm creates jobs and vital components for world-leading

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    experiment | Princeton Plasma Physics Lab Jersey firm creates jobs and vital components for world-leading experiment By John Greenwald July 10, 2012 Tweet Widget Google Plus One Share on Facebook This superconducting wire will become thin as a needle when Oxford Superconducting Technology finishes manufacturing it. (Photo by Elle Starkman, PPPL Office Of Communications) This superconducting wire will become thin as a needle when Oxford Superconducting Technology finishes manufacturing it.

  5. Value for controlling flow of cryogenic fluid

    DOE Patents [OSTI]

    Knapp, Philip A.

    1996-01-01

    A valve is provided for accurately controlling the flow of cryogenic fluids such as liquid nitrogen. The valve comprises a combination of disc and needle valves affixed to a valve stem in such a manner that the disc and needle are free to rotate about the stem, but are constrained in lateral and vertical movements. This arrangement provides accurate and precise fluid flow control and positive fluid isolation.

  6. High Rate and Stable Cycling of Lithium Metal Anode - Joint Center for

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Storage Research November 10, 2014, Research Highlights High Rate and Stable Cycling of Lithium Metal Anode Coulombic efficiency (CE) of Li plating/stripping is > 99.1% in concentrated LiFSI-DME electrolyte Scientific Achievement Lithium metal is an ideal battery anode. However, dendrite growth and limited CE during cycling have limited its practical applications. High CE (up to 99.1%) without dendrite growth is achieved by using highly concentrated electrolytes for lithium

  7. Dentritic morphology and microsegregation in directionally solidified superalloy, PWA-1480, single crystal: Effect of gravity; center director's discretionary fund report

    SciTech Connect (OSTI)

    Tewari, S.N.; Kumar, M.V.; Lee, J.E.; Curreri, P.A.

    1990-11-01

    Primary dendrite spacings, secondary dendrite spacings, and microsegregation have been examined in PWA-1480 single crystal specimens which were directionally solidified during parabolic maneuvers on the KC-135 aircraft. Experimentally observed growth rate and thermal gradient dependence of primary dendrite spacings are in good agreement with predictions from dendrite growth models for binary alloys. Secondary dendrite coarsening kinetics show a reasonable fit with the predictions from an analytical model proposed by Kirkwood for a binary alloy. The partition coefficients of tantalum, titanium, and aluminum are observed to be less than unity, while that for tungsten and cobalt are greater than unity. This is qualitatively similar to the nickel base binaries. Microsegregation profiles experimentally observed for PWA-1480 superalloy show a good fit with Bower, Brody, and Flemings model developed for binary alloys. Transitions in gravity levels do not appear to affect primary dendrite spacings. A trend of decreased secondary arm spacings with transition from high gravity to the low gravity period was observed at a growth speed of 0.023 cm s(exp -1). However, definite conclusions can only be drawn by experiments at lower growth speeds which make it possible to examine the side-branch coarsening kinetics over a longer duration. Such experiments, not possible due to the insufficient low-gravity time of the KC-135, may be carried out in the low-gravity environment of space.

  8. SU-D-BRF-06: A Brachytherapy Simulator with Realistic Haptic Force Feedback and Real-Time Ultrasounds Image Simulation for Training and Teaching

    SciTech Connect (OSTI)

    Beaulieu, L; Carette, A; Comtois, S; Lavigueur, M; Cardou, P; Laurendeau, D

    2014-06-01

    Purpose: Surgical procedures require dexterity, expertise and repetition to reach optimal patient outcomes. However, efficient training opportunities are usually limited. This work presents a simulator system with realistic haptic force-feedback and full, real-time ultrasounds image simulation. Methods: The simulator is composed of a custom-made Linear-DELTA force-feedback robotic platform. The needle tip is mounted on a force gauge at the end effector of the robot, which responds to needle insertion by providing reaction forces. 3D geometry of the tissue is using a tetrahedral finite element mesh (FEM) mimicking tissue properties. As the needle is inserted/retracted, tissue deformation is computed using a mass-tensor nonlinear visco-elastic FEM. The real-time deformation is fed to the L-DELTA to take into account the force imparted to the needle, providing feedback to the end-user when crossing tissue boundaries or needle bending. Real-time 2D US image is also generated synchronously showing anatomy, needle insertion and tissue deformation. The simulator is running on an Intel I7 6- core CPU at 3.26 MHz. 3D tissue rendering and ultrasound display are performed on a Windows 7 computer; the FEM computation and L-DELTA control are executed on a similar PC using the Neutrino real-time OS. Both machines communicate through an Ethernet link. Results: The system runs at 500 Hz for a 8333-tetrahedron tissue mesh and a 100-node angular spring needle model. This frame rate ensures a relatively smooth displacement of the needle when pushed or retracted (±20 N in all directions at speeds of up to 2 m/s). Unlike commercially-available haptic platforms, the oblong workspace of the L-DELTA robot complies with that required for brachytherapy needle displacements of 0.1m by 0.1m by 0.25m. Conclusion: We have demonstrated a real-life, realistic brachytherapy simulator developed for prostate implants (LDR/HDR). The platform could be adapted to other sites or training for other

  9. WE-A-17A-09: Exploiting Electromagnetic Technologies for Real-Time Seed Drop Position Validation in Permanent Implant Brachytherapy

    SciTech Connect (OSTI)

    Racine, E; Hautvast, G; Binnekamp, D; Beaulieu, L

    2014-06-15

    Purpose: To report on preliminary results validating the performance of a specially designed LDR brachytherapy needle prototype possessing both electromagnetic (EM) tracking and seed drop detection abilities. Methods: An EM hollow needle prototype has been designed and constructed in collaboration with research partner Philips Healthcare. The needle possesses conventional 3D tracking capabilities, along with a novel seed drop detection mechanism exploiting local changes of electromagnetic properties generated by the passage of seeds in the needle's embedded sensor coils. These two capabilities are exploited by proprietary engineering and signal processing techniques to generate seed drop position estimates in real-time treatment delivery. The electromagnetic tracking system (EMTS) used for the experiment is the NDI Aurora Planar Field Generator. The experiment consisted of dropping a total of 35 seeds in a prismatic agarose phantom, and comparing the 3D seed drop positions of the EMTS to those obtained by an image analysis of subsequent micro-CT scans. Drop position error computations and statistical analysis were performed after a 3D registration of the two seed distributions. Results: Of the 35 seeds dropped in the phantom, 32 were properly detected by the needle prototype. Absolute drop position errors among the detected seeds ranged from 0.5 to 4.8 mm with mean and standard deviation values of 1.6 and 0.9 mm, respectively. Error measurements also include undesirable and uncontrollable effects such as seed motion upon deposition. The true accuracy performance of the needle prototype is therefore underestimated. Conclusion: This preliminary study demonstrates the potential benefits of EM technologies in detecting the passage of seeds in a hollow needle as a means of generating drop position estimates in real-time treatment delivery. Such tools could therefore represent a potentially interesting addition to existing brachytherapy protocols for rapid dosimetry

  10. Embolization by Direct Puncture with a Transpedicular Approach Using an Isocenter Puncture (ISOP) Method in a Patient with a Type II Endoleak After Endovascular Aortic Repair (EVAR)

    SciTech Connect (OSTI)

    Ogawa, Yukihisa Hamaguchi, Shingo; Nishimaki, Hiroshi; Kon, Yuri; Chiba, Kiyoshi; Sakurai, Yuka; Murakami, Kenji; Arai, Yasunori; Miyairi, Takeshi; Nakajima, Yasuo

    2015-06-15

    BackgroundEndovascular aortic repair (EVAR) requires further intervention in 20-30 % of cases, often due to type II endoleak (T2EL). Management options for T2EL include transarterial embolization, direct puncture (DP), or transcaval embolization. We report the case of an 80-year-old man with T2EL who successfully underwent DP embolization.MethodsEmbolization by DP was performed with a transpedicular approach using an isocenter puncture (ISOP) method. An isocenter marker (ICM) was placed at a site corresponding to the aneurysm sac on fluoroscopy in two directions (frontal and lateral views). A vertebroplasty needle was inserted tangentially to the ICM under fluoroscopy and advanced to the anterior wall of the vertebral body. A 20 cm-length, 20-G-PTCD needle was inserted through the outer needle of the 13-G needle and advanced to the ICM. Sac embolization using 25 % N-buty-2-cyanoacrylate diluted with Lipiodol was performed. After complete embolization, rotational DA confirmed good filling of the sac with Lipiodol. The outer cannula and 13-G needle were removed and the procedure was completed.ResultsThe patient was discharged the next day. Contrast-enhanced computed tomography 1 and 8 months later showed no Lipiodol washout in the aneurysm sac, no endoleak recurrence, and no expansion of the excluded aneurysm.ConclusionDP with a transpedicular approach using ISOP may be useful when translumbar and transabdominal approaches prove difficult.

  11. CT-Guided Interventions Using a Free-Hand, Optical Tracking System: Initial Clinical Experience

    SciTech Connect (OSTI)

    Schubert, Tilman Jacob, Augustinus L.; Pansini, Michele; Liu, David; Gutzeit, Andreas; Kos, Sebastian

    2013-08-01

    PurposeThe present study was designed to evaluate the geometrical accuracy and clinical applicability of a new, free-hand, CT-guided, optical navigation system.MethodsFifteen procedures in 14 consecutive patients were retrospectively analyzed. The navigation system was applied for interventional procedures on small target lesions, in cases with long needle paths, narrow access windows, or when an out-of-plane access was expected. Mean lesion volume was 27.9 ml, and mean distance to target measured was 107.5 mm. Eleven of 15 needle trajectories were planned as out-of-plane approaches regarding the axial CT plane.ResultsNinety-one percent of the biopsies were diagnostic. All therapeutic interventions were technically successful. Targeting precision was high with a mean distance of the needle tip from planned target of 1.98 mm. Mean intervention time was 1:12 h. A statistically significant correlation between angular needle deviation and intervention time (p = 0.007), respiratory movement of the target (p = 0.008), and body mass index (p = 0.02) was detected. None of the evaluated parameters correlated significantly with the distance from the needle tip to the planned target.ConclusionsThe application of a navigation system for complex CT-guided procedures provided safe and effective targeting within a reasonable intervention time in our series.

  12. FLUID SELECTING APPARATUS

    DOE Patents [OSTI]

    Stinson, W.J.

    1958-09-16

    A valve designed to selectively sample fluids from a number of sources is described. The valve comprises a rotatable operating lever connected through a bellows seal to a rotatable assembly containing a needle valve, bearings, and a rotational lock. The needle valve is connected through a flexible tube to the sample fluid outlet. By rotating the lever the needle valve is placed over . one of several fluid sources and locked in position so that the fluid is traasferred through the flexible tubing and outlet to a remote sampling system. The fluids from the nonselected sources are exhausted to a waste line. This valve constitutes a simple, dependable means of selecting a sample from one of several scurces.

  13. HIGH PRESSURE GAS REGULATOR

    DOE Patents [OSTI]

    Ramage, R.W.

    1962-05-01

    A gas regulator operating on the piston and feedback principle is described. The device is particularly suitable for the delicate regulation of high pressure, i.e., 10,000 psi and above, gas sources, as well as being perfectly adaptable for use on gas supplies as low as 50 psi. The piston is adjustably connected to a needle valve and the movement of the piston regulates the flow of gas from the needle valve. The gas output is obtained from the needle valve. Output pressure is sampled by a piston feedback means which, in turn, regulates the movement of the main piston. When the output is other than the desired value, the feedback system initiates movement of the main piston to allow the output pressure to be corrected or to remain constant. (AEC)

  14. Solidification behavior and structure of Al-Cu alloy welds

    SciTech Connect (OSTI)

    Brooks, J.A.; Li, M.; Yang, N.C.Y.

    1997-09-01

    The microsegregation behavior of electron beam (EB) and gas tungsten arc (GTA) welds of Al-Cu alloys covering a range from 0.19 to 7.74 wt% Cu were characterized for dendrite core concentrations and fraction eutectic solidification. Although a single weld speed of 12.7 mm/sec was used, some differences were observed in the segregation behavior of the two weld types. The microsegregation behavior was also modeled using a finite differences technique considering dendrite tip and eutectic undercooling and solid state diffusion. Fairly good agreement was observed between measured and calculated segregation behavior although differences between the two weld types could not be completely accounted for. The concept of dendrite tip undercooling was used to explain the formation of a single through thickness centerline grain in the higher alloy content GTA welds.

  15. Mechanism of surface modification of the Ti-6Al-4V alloy using a gas tungsten arc heat source

    SciTech Connect (OSTI)

    Labudovic, M.; Kovacevic, R.; Kmecko, I.; Khan, T.I.; Blecic, D.; Blecic, Z.

    1999-06-01

    The surface modification of a Ti-6Al-4V alloy using a gas tungsten arc, as a heat source, was studied. The experimental results show that the titanium alloy surface can be melted and nitrided using pure nitrogen or a nitrogen/argon mixture shielding atmosphere. The resolidified surfaces are 0.9 to 1.2-mm thick and contain titanium nitride dendrites, {alpha}-titanium, and {alpha}{double_prime}-titanium (martensite). The average dendrite arm spacing is influenced by the electrode speed. Small titanium nitride dendrites are homogeneously distributed in the resolidified surfaces. The microstructure and phase constitution in the resolidified surfaces were determined and analyzed, and the mechanism of the formation of titanium nitrides is discussed. The results show that the nitriding kinetics obey parabolic laws and are, therefore, controlled by nitrogen diffusion. The nitrogen-concentration depth profiles, calculated using Fick`s second law of diffusion, are compared to experimental nitrogen depth profiles, showing satisfactory agreement.

  16. Process for producing amorphous and crystalline silicon nitride

    DOE Patents [OSTI]

    Morgan, P.E.D.; Pugar, E.A.

    1985-11-12

    A process for producing amorphous or crystalline silicon nitride is disclosed which comprises reacting silicon disulfide ammonia gas at elevated temperature. In a preferred embodiment silicon disulfide in the form of whiskers'' or needles is heated at temperature ranging from about 900 C to about 1,200 C to produce silicon nitride which retains the whisker or needle morphological characteristics of the silicon disulfide. Silicon carbide, e.g. in the form of whiskers, also can be prepared by reacting substituted ammonia, e.g. methylamine, or a hydrocarbon containing active hydrogen-containing groups, such as ethylene, with silicon disulfide, at elevated temperature, e.g. 900 C. 6 figs.

  17. Process for producing amorphous and crystalline silicon nitride

    DOE Patents [OSTI]

    Morgan, Peter E. D.; Pugar, Eloise A.

    1985-01-01

    A process for producing amorphous or crystalline silicon nitride is disclosed which comprises reacting silicon disulfide ammonia gas at elevated temperature. In a preferred embodiment silicon disulfide in the form of "whiskers" or needles is heated at temperature ranging from about 900.degree. C. to about 1200.degree. C. to produce silicon nitride which retains the whisker or needle morphological characteristics of the silicon disulfide. Silicon carbide, e.g. in the form of whiskers, also can be prepared by reacting substituted ammonia, e.g. methylamine, or a hydrocarbon containing active hydrogen-containing groups, such as ethylene, with silicon disulfide, at elevated temperature, e.g. 900.degree. C.

  18. Area C borrow Site Habitat Assessment

    SciTech Connect (OSTI)

    Sackschewsky, Michael R.; Downs, Janelle L.

    2009-12-04

    A habitat quality assessment was performed within selected portions of the proposed Area C Borrow Source. The previously identified Bitterbrush / Indian ricegrass stabilized dune element occurrence was determined to be better described as a sagebrush /needle-and-thread grass element occurrence of fair to good quality. A new habitat polygon is suggested adjacent to this element occurrence, which would also be sagebrush/needle-and-thread grass, but of poor quality. The proposed site of initial borrow site development was found to be a very low quality community dominated by cheatgrass.

  19. Nozzle insert for mixed mode fuel injector

    DOE Patents [OSTI]

    Lawrence, Keith E.

    2006-11-21

    A fuel injector includes a homogenous charge nozzle outlet set and a conventional nozzle outlet set controlled respectively, by first and second needle valve members. The homogeneous charged nozzle outlet set is defined by a nozzle insert that is attached to an injector body, which defines the conventional nozzle outlet set. The nozzle insert is a one piece metallic component with a large diameter segment separated from a small diameter segment by an annular engagement surface. One of the needle valve members is guided on an outer surface of the nozzle insert, and the nozzle insert has an interference fit attachment to the injector body.

  20. Development and validation of a new guidance device for lateral approach stereotactic breast biopsy

    SciTech Connect (OSTI)

    Ma, K.; Kornecki, A.; Bax, J.; Mundt, Y.; Fenster, A.

    2009-06-15

    Stereotactic breast biopsy (SBB) is the gold standard for minimally invasive breast cancer diagnosis. Current systems rely on one of two methods for needle insertion: A vertical approach (perpendicular to the breast compression plate) or a lateral approach (parallel to the compression plate). While the vertical approach is more frequently used, it is not feasible in patients with thin breasts (<3 cm thick after compression) or with superficial lesions. Further, existing SBB guidance hardware provides at most one degree of rotational freedom in the needle trajectory, and as such requires a separate skin incision for each biopsy target. The authors present a new design of lateral guidance device for SBB, which addresses the limitations of the vertical approach and provides improvements over the existing lateral guidance hardware. Specifically, the new device provides (1) an adjustable rigid needle support to minimize needle deflection within the breast and (2) an additional degree of rotational freedom in the needle trajectory, allowing the radiologist to sample multiple targets through a single skin incision. This device was compared to a commercial lateral guidance device in a series of phantom experiments. Needle placement error using each device was measured in agar phantoms for needle insertions at lateral depths of 2 and 5 cm. The biopsy success rate for each device was then estimated by performing biopsy procedures in commercial SBB phantoms. SBB performed with the new lateral guidance device provided reduced needle placement error relative to the commercial lateral guidance device (0.89{+-}0.22 vs 1.75{+-}0.35 mm for targets at 2 cm depth; 1.94{+-}0.20 vs 3.21{+-}0.31 mm for targets at 5 cm depth). The new lateral guidance device also provided improved biopsy accuracy in SBB procedures compared to the commercial lateral guidance device (100% vs 58% success rate). Finally, experiments were performed to demonstrate that the new device can accurately sample

  1. Support to DHS Chemical Detection Field Testing and Countermeasures Studies: Report to Sponsors

    SciTech Connect (OSTI)

    Sohn, Michael; Black, Douglas; Delp, William

    2011-09-01

    This document reports on work that Lawrence Berkeley National Laboratory performed to support the Department of Homeland Security's testing of ARFCAM and LACIS systems. In the sections that follow, LBNL lists the scope of work, field analyses conducted, and preliminary results. LBNL developed a model of the Port Gaston building at the Nevada Test Site and calibrated it using data from field experiments, both blower door and tracer gas tests. Model development and comparison to data show very good agreement. The model was developed to (1) support the interpretation of data from field trials performed by Signature Science LLC, (2) support the placement of sampler equipment, and (3) predict if meteorological differences between the Wet-Run/Dry-Run and the Hot-Run might adversely affect the development of the Hot Run Test Plan. LBNL reported its findings on each task to the experiment team at scheduled planning meetings. In the end, we note that the model was used limitedly because the data from the Wet-Run/Dry Run were if such high quality. Lastly, LBNL conducted a research experiment at the end of the Wet-Run/Dry-Run to study if, and to what degree, specific TICs sorb and desorb on indoor surfaces. We found that several of the TICs either sorb onto surfaces or are lost through chemical reactions. These findings may have important implications on determining sheltering-in-place concepts of operation.

  2. Methods of nanoassembly of a fractal polymer and materials formed thereby

    DOE Patents [OSTI]

    Newkome, George R.; Moorefield, Charles N.

    2012-07-24

    The invention relates to the formation of synthesized fractal constructs and the methods of chemical self-assembly for the preparation of a non-dendritic, nano-scale, fractal constructs or molecules. More particularly, the invention relates to fractal constructs formed by molecular self-assembly, to create synthetic, nanometer-scale fractal shapes. In an embodiment, a nanoscale Sierpinski hexagonal gasket is formed. This non-dendritic, perfectly self-similar fractal macromolecule is comprised of bisterpyridine building blocks that are bound together by coordination to 36 Ru and 6 Fe ions to form a nearly planar array of increasingly larger hexagons around a hollow center.

  3. Methods of nanoassembly of a fractal polymer and materials formed thereby

    DOE Patents [OSTI]

    Newkome, George R; Moorefield, Charles N

    2014-09-23

    The invention relates to the formation of synthesized fractal constructs and the methods of chemical self-assembly for the preparation of a non-dendritic, nano-scale, fractal constructs or molecules. More particularly, the invention relates to fractal constructs formed by molecular self-assembly, to create synthetic, nanometer-scale fractal shapes. In an embodiment, a nanoscale Sierpinski hexagonal gasket is formed. This non-dendritic, perfectly self-similar fractal macromolecule is comprised of bisterpyridine building blocks that are bound together by coordination to (36) Ru and (6) Fe ions to form a nearly planar array of increasingly larger hexagons around a hollow center.

  4. Effect of Morphology of CdS thin film on the Photocatalytic Decomposition of Hydrogen Sulfide

    SciTech Connect (OSTI)

    Takahashi, A.; Ishiyama, T.; Takahashi, H.; Sato, Y.; Jeyadevan, B.; Tohji, K.

    2007-03-20

    Photocatalytic activity of the CdS thin film depended very much on the film density, adhesion between the CdS and substrate, and whether effective electron path existed or not. We have proposed the formation of a bridging layer of Cd metal to improve the film density, adhesivity and the electron conduction path. Here, we report the results of the study undertaken to develop CdS/Cd (dendrite)/Ti film with enhanced photocatalytic property to decompose hydrogen sulphide. CdS/Cd (dendrite)/Ti photocatalyst showed the highest photocatalytic activity and photocurrent, which was 1.4 times higher than the traditional CdS/Ti photocatalyst.

  5. The effect of elevated carbon dioxide on a Sierra-Nevadan dominant species: Pinus ponderosa

    SciTech Connect (OSTI)

    Pushnik, J.C.; Demaree, R.S.; Flory, W.B.; Bauer, S.M.; Houpis, J.L.J.; Anderson, P.D.

    1995-01-01

    The impact of increasing atmospheric C0{sub 2} has not been fully evaluated on western coniferous forest species. Two year old seedlings of Pinusponderosa were grown in environmentally controlled chambers under increased C0{sub 2} conditions for 6 months. These trees exhibit morphological, physiological, and biochemical alterations when compared to our controls. Analysis of whole plant biomass distribution has shown no significant effect to the root to shoot ratios, however needles subjected to elevated C0{sub 2} exhibited an increased overall specific needle mass and a decreased total needle area. Morphological changes at the needle level included decreased mesophyll to vascular tissue 91 ratio and variations in starch storage in chloroplasts. The elevated CO{sub 2} increased internal CO{sub 2} concentrations and assimilation of carbon. Biochemical assays revealed that ribulose-bisphosphate carboxylase specific activities increased on per unit area basis with C0{sub 2} treatment levels. Sucrose phosphate synthase (SPS) activities exhibited an increase of 55% in the 700 uL L{sup {minus}1} treatment. These results indicate that the sink-source relationships of these trees have shifted carbon allocation toward above ground growth, possibly due to transport limitations.

  6. Percutaneous Extraction of Cement Leakage After Vertebroplasty Under CT and Fluoroscopy Guidance: A New Technique

    SciTech Connect (OSTI)

    Amoretti, Nicolas Huwart, Laurent

    2012-12-15

    Purpose: We report a new minimally invasive technique of extraction of cement leakage following percutaneous vertebroplasty in adults. Methods: Seven adult patients (five women, two men; mean age: 81 years) treated for vertebral compression fractures by percutaneous vertebroplasty had cement leakage into perivertebral soft tissues along the needle route. Immediately after vertebroplasty, the procedure of extraction was performed under computed tomography (CT) and fluoroscopy guidance: a Chiba needle was first inserted using the same route as the vertebroplasty until contact was obtained with the cement fragment. This needle was then used as a guide for an 11-gauge Trocar t'am (Thiebaud, France). After needle withdrawal, a 13-gauge endoscopy clamp was inserted through the cannula to extract the cement fragments. The whole procedure was performed under local anesthesia. Results: In each patient, all cement fragments were withdrawn within 10 min, without complication. Conclusions: This report suggests that this CT- and fluoroscopy-guided percutaneous technique of extraction could reduce the rate of cement leakage-related complications.

  7. June

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 » June June Read about Los Alamos Lab's science highlights, honors, achievements, and awards. The mineral "Terrywallaceite" "Terrywallaceite" now in official roster of known minerals The slender, needle-like metallic-black crystals of Terrywallaceite were found in the Julcani Mining District of Peru. - 6/8/11 Science Briefs - 2011 June

  8. Method for fabricating a substrate having spaced apart microcapillaries thereon

    DOE Patents [OSTI]

    Jarvis, E.E.

    1995-01-24

    Methods are disclosed for manufacturing a self-supporting substrate having a plurality of spaced-apart needles (spikes or microcapillaries) projecting upwardly from a major surface of the substrate. In a preferred method, metal is deposited onto a porous membrane such that the metal extends into the pores, after which the membrane is dissolved. 9 figures.

  9. LDRD final report on synthesis of shape-and size-controlled platinum and platinum alloy nanostructures on carbon with improved durability.

    SciTech Connect (OSTI)

    Shelnutt, John Allen; Garcia, Robert M.; Song, Yujiang; Moreno, Andres M.; Stanis, Ronald J.

    2008-10-01

    This project is aimed to gain added durability by supporting ripening-resistant dendritic platinum and/or platinum-based alloy nanostructures on carbon. We have developed a new synthetic approach suitable for directly supporting dendritic nanostructures on VXC-72 carbon black (CB), single-walled carbon nanotubes (SWCNTs), and multi-walled carbon nanotubes (MWCNTs). The key of the synthesis is to creating a unique supporting/confining reaction environment by incorporating carbon within lipid bilayer relying on a hydrophobic-hydrophobic interaction. In order to realize size uniformity control over the supported dendritic nanostructures, a fast photocatalytic seeding method based on tin(IV) porphyrins (SnP) developed at Sandia was applied to the synthesis by using SnP-containing liposomes under tungsten light irradiation. For concept approval, one created dendritic platinum nanostructure supported on CB was fabricated into membrane electrode assemblies (MEAs) for durability examination via potential cycling. It appears that carbon supporting is essentially beneficial to an enhanced durability according to our preliminary results.

  10. Hierarchical electrode architectures for electrical energy storage & conversion.

    SciTech Connect (OSTI)

    Zavadil, Kevin Robert; Missert, Nancy A.; Shelnutt, John Allen; van Swol, Frank B.

    2012-01-01

    The integration and stability of electrocatalytic nanostructures, which represent one level of porosity in a hierarchical structural scheme when combined with a three-dimensional support scaffold, has been studied using a combination of synthetic processes, characterization techniques, and computational methods. Dendritic platinum nanostructures have been covalently linked to common electrode surfaces using a newly developed chemical route; a chemical route equally applicable to a range of metals, oxides, and semiconductive materials. Characterization of the resulting bound nanostructure system confirms successful binding, while electrochemistry and microscopy demonstrate the viability of these electroactive particles. Scanning tunneling microscopy has been used to image and validate the short-term stability of several electrode-bound platinum dendritic sheet structures toward Oswald ripening. Kinetic Monte Carlo methods have been applied to develop an understanding of the stability of the basic nano-scale porous platinum sheets as they transform from an initial dendrite to hole containing sheets. Alternate synthetic strategies were pursued to grow dendritic platinum structures directly onto subunits (graphitic particles) of the electrode scaffold. A two-step photocatalytic seeding process proved successful at generating desirable nano-scale porous structures. Growth in-place is an alternate strategy to the covalent linking of the electrocatalytic nanostructures.

  11. Flow-Assisted Alkaline Battery: Low-Cost Grid-Scale Electrical Storage using a Flow-Assisted Rechargeable Zinc-Manganese Dioxide Battery

    SciTech Connect (OSTI)

    2010-09-15

    GRIDS Project: Traditional consumer-grade disposable batteries are made of Zinc and Manganese, 2 inexpensive, abundant, and non-toxic metals. But these disposable batteries can only be used once. If they are recharged, the Zinc in the battery develops filaments called dendrites that grow haphazardly and disrupt battery performance, while the Manganese quickly loses its ability to store energy. CUNY Energy Institute is working to tame dendrite formation and to enhance the lifetime of Manganese in order to create a long-lasting, fully rechargeable battery for grid-scale energy storage. CUNY Energy Institute is also working to reduce dendrite formation by pumping fluid through the battery, enabling researchers to fix the dendrites as theyre forming. The team has already tested its Zinc battery through 3,000 recharge cycles (and counting). CUNY Energy Institute aims to demonstrate a better cycle life than lithium-ion batteries, which can be up to 20 times more expensive than Zinc-based batteries.

  12. An HRTEM investigation of the metastable low-temperature silica phase opal-CT in cherts and porcelanites from the Monterey Formation, CA

    SciTech Connect (OSTI)

    Cady, S.L.; Wenk, H.R. )

    1992-01-01

    High resolution transmission electron microscopy (HRTEM) is used to investigate the metastable low-temperature silica phase opal-CT in cherts and porcelanites from the Miocene Monterey Formation of California. Low-dose imaging techniques developed to image highly beam sensitive proteins were used in this study and have resulted in good phase contrast images of this hydrous silica phase. Detailed X-ray powder diffraction studies of stratigraphically equivalent rocks along the Santa Barbara coast indicate that the primary d-spacing of newly formed opal-CT differs in rocks with different ratios of silica and detrital minerals. Opal-CT forms progressively later and with a smaller primary d-spacing in rocks with increasing amounts of detrital minerals. In siliceous cherts opal-CT occurs as long needles that most often form dense spherulitic fiber bundles which are randomly dispersed within the rock matrix. The random orientation of fiber bundle nucleation centers does not appear to be associated with any obvious nucleation site, unlike the length-slow opal-CT fibers known as lussatite. Opal-CT needles produce optical diffractogram patterns that are compatible with tridymite and crystobalite. Streaking in the diffraction pattern of individual needles is attributed to a high density of planar defects parallel to their length. Planar defects are not as abundant in opal-CT needles formed in detrital-rich rocks suggesting the rapid growth of opal-CT in highly siliceous environments results in a greater proportion of stacking disorder in the needles. HRTEM provides a method for investigating the development of the microstructure of opal-CT during diagenesis.

  13. Solidification process in melt spun Nd-Fe-B type magnets

    SciTech Connect (OSTI)

    Li, C.

    1998-02-23

    A generalized solidification model has been developed based on a systematic investigation on the microstructure of melt spun Nd-Fe-B alloys. Melt spinning was conducted on initial stoichiometric and TiC added Nd{sub 2}Fe{sub 14}B (2-14-1) compositions to produce under, optimally and over quenched microstructures. Microstructural characterization was carried out by TEM, SEM, Optical microscopy, XRD, DTA, VSM and DC SQUID techniques. By taking the dendritic breakup during recalescence into consideration, this generalized model has successfully explained the solidification process of the melt spun Nd-Fe-B alloys. Challenging the conventional homogeneous nucleation models, the new model explains the fine and uniform equiaxed 2-14-1 microstructure in optimally quenched ribbons as a result of the breakup of the 2-14-1 dendrites which nucleate heterogeneously from the wheel surface and grow dendritically across the ribbon thickness due to the recalescence. Besides this dendritic breakup feature, the under quenched microstructure is further featured with another growth front starting with the primary solidification of Fe phase near the free side, which results in a coarsely grained microstructure with Fe dendritic inclusions and overall variation in microstructure across the ribbon thickness. In addition, because a epitaxy exists between the Fe phase and the 2-14-1, the so-formed coarse 2-14-1 grains may be textured. C-axis texturing was observed in under quenched ribbons. As a constraint to solidification models in this system, the cause and characteristics of this phenomenon has been studied in detail to test the authors proposed model, and agreement has been found. An extension has also been made to understand the solidification process when TiC is added, which suggests that Ti and C slow down the growth front of both Fe and 2-14-1 phase.

  14. Developing A Laser Shockwave Model For Characterizing Diffusion Bonded Interfaces

    SciTech Connect (OSTI)

    James A. Smith; Jeffrey M. Lacy; Barry H. Rabin

    2014-07-01

    12. Other advances in QNDE and related topics: Preferred Session Laser-ultrasonics Developing A Laser Shockwave Model For Characterizing Diffusion Bonded Interfaces 41st Annual Review of Progress in Quantitative Nondestructive Evaluation Conference QNDE Conference July 20-25, 2014 Boise Centre 850 West Front Street Boise, Idaho 83702 James A. Smith, Jeffrey M. Lacy, Barry H. Rabin, Idaho National Laboratory, Idaho Falls, ID ABSTRACT: The US National Nuclear Security Agency has a Global Threat Reduction Initiative (GTRI) which is assigned with reducing the worldwide use of high-enriched uranium (HEU). A salient component of that initiative is the conversion of research reactors from HEU to low enriched uranium (LEU) fuels. An innovative fuel is being developed to replace HEU. The new LEU fuel is based on a monolithic fuel made from a U-Mo alloy foil encapsulated in Al-6061 cladding. In order to complete the fuel qualification process, the laser shock technique is being developed to characterize the clad-clad and fuel-clad interface strengths in fresh and irradiated fuel plates. The Laser Shockwave Technique (LST) is being investigated to characterize interface strength in fuel plates. LST is a non-contact method that uses lasers for the generation and detection of large amplitude acoustic waves to characterize interfaces in nuclear fuel plates. However the deposition of laser energy into the containment layer on specimen’s surface is intractably complex. The shock wave energy is inferred from the velocity on the backside and the depth of the impression left on the surface from the high pressure plasma pulse created by the shock laser. To help quantify the stresses and strengths at the interface, a finite element model is being developed and validated by comparing numerical and experimental results for back face velocities and front face depressions with experimental results. This paper will report on initial efforts to develop a finite element model for laser

  15. Stress corrosion cracking of alloys 600 and 690 in all-volatile-treated water at elevated temperatures: Final report

    SciTech Connect (OSTI)

    Miglin, B.P.; Theus, G.J.

    1988-05-01

    This report describes stress corrosion (SCC) tests of Inconnel alloys 600 and 690 in all-volatile treated (AVT) water. Specimens of alloys 600 and 690 were exposed to AVT water at 288/degree/, 332/degree/, 343/degree/, and 360/degree/C. Alloy 660 generally resists SCC in high-purity water at normal sevice temperatures, but is susceptible to SCC at higher temperatures. In general, mill-annealed alloy 600 is more susceptible than high-treated material with fine lacy grain boundary carbides. Very high stresses (near or above yield) are required to induce cracking of alloy 600 in AVT or other high-purity waters. For alloy 600, 78 of 520 alloy 600 specimens eventually cracked. Although exposed for less total time than alloy 600 specimens, no alloy 690 specimens cracked. Three alloy 600 specimens cracked in the same autoclave tests in less time than those accumulated by the alloy 690 specimens. Longitudinally-oriented ID cracks became evident on alloy 690 split-tube U-bend specimens after autoclave exposures. These cracks on the 690 specimens were from three to ten times longer after exposure than similar defects found on unexposed alloy 690 specimens. The longitudinal crack lengthening on the alloy 690 split-tube U-bend specimens may have been a stress relaxation process or possibly a crack opening process of pre-existing, partially closed, longitudinal defects. Similar cracks were present in alloy 600 specimens, but in at least one case SCC did initiate from these shallow, blunt cracks.

  16. Length Scale Correlations of Cellular Microstructures in Directionally Solidified Binary System

    SciTech Connect (OSTI)

    Yunxue Shen

    2002-08-01

    In a cellular array, a range of primary spacing is found to be stable under given growth conditions. Since a strong coupling of solute field exists between the neighboring cells, primary spacing variation should also influence other microstructure features such as cell shape and cell length. The existence of multiple solutions is examined in this study both theoretically as well as experimentally. A theoretical model is developed that identifies and relates four important microstructural lengths, which are found to be primary spacing, tip radius, cell width and cell length. This general microstructural relationship is shown to be valid for different cells in an array as well as for other cellular patterns obtained under different growth conditions. The unique feature of the model is that the microstructure correlation does not depend on composition or growth conditions since these variables scale microstructural lengths to satisfy the relationship obtained in this study. Detailed directional solidification experimental studies have been carried out in the succinonitrile-salol system to characterize and measure these four length scales. Besides the validation of the model, experimental results showed additional scaling laws to be present. In the regime where only a cellular structure is formed, the shape of the cell, the cell tip radius and the length of the cell are all found to scale individually with the local primary spacing. The presence of multiple solutions of primary spacing is also shown to influence the cell-dendrite transition that is controlled not only by the processing variables (growth velocity, thermal gradient and composition) but also by the local cell spacing. The cell-dendrite transition was found not to be sharp, but occurred over a range of processing conditions. Two critical conditions have been identified such that only cells are present below lower critics condition, and only dendrites are formed above the upper critics condition. Between

  17. Length Scale Correlations of Cellular Microstructures in Directionally Solidified Binary System

    SciTech Connect (OSTI)

    Yunxue Shen

    2002-06-27

    In a cellular array, a range of primary spacing is found to be stable under given growth conditions. Since a strong coupling of solute field exists between the neighboring cells, primary spacing variation should also influence other microstructure features such as cell shape and cell length. The existence of multiple solutions is examined in this study both theoretically as well as experimentally. A theoretical model is developed that identifies and relates four important microstructural lengths, which are found to be primary spacing, tip radius, cell width and cell length. This general microstructural relationship is shown to be valid for different cells in an array as well as for other cellular patterns obtained under different growth conditions. The unique feature of the model is that the microstructure correlation does not depend on composition or growth conditions since these variables scale microstructural lengths to satisfy the relationship obtained in this study. Detailed directional solidification experimental studies have been carried out in the succinonitrile-salol system to characterize and measure these four length scales. Besides the validation of the model, experimental results showed additional scaling laws to be present. In the regime where only a cellular structure is formed, the shape of the cell, the cell tip radius and the length of the cell are all found to scale individually with the local primary spacing. The presence of multiple solutions of primary spacing is also shown to influence the cell-dendrite transition that is controlled not only by the processing variables (growth velocity, thermal gradient and composition) but also by the local cell spacing. The cell-dendrite transition was found not to be sharp, but occurred over a range of processing conditions. Two critical conditions have been identified such that only cells are present below lower critics condition, and only dendrites are formed above the upper critics condition. Between

  18. Robot-Assisted Antegrade In-Situ Fenestrated Stent Grafting

    SciTech Connect (OSTI)

    Riga, Celia V. Bicknell, Colin D.; Wallace, Daniel; Hamady, Mohamad; Cheshire, Nicholas

    2009-05-15

    To determine the technical feasibility of a novel approach of in-situ fenestration of aortic stent grafts by using a remotely controlled robotic steerable catheter system in the porcine model. A 65-kg pig underwent robot-assisted bilateral antegrade in-situ renal fenestration of an abdominal aortic stent graft with subsequent successful deployment of a bare metal stent into the right renal artery. A 16-mm iliac extension covered stent served as the porcine aortic endograft. Under fluoroscopic guidance, the graft was punctured with a 20-G customized diathermy needle that was introduced and kept in place by the robotic arm. The needle was exchanged for a 4 x 20 mm cutting balloon before successful deployment of the renal stent. Robot-assisted antegrade in-situ fenestration is technically feasible in a large mammalian model. The robotic system enables precise manipulation, stable positioning, and minimum instrumentation of the aorta and its branches while minimizing radiation exposure.

  19. Porous protective solid phase micro-extractor sheath

    DOE Patents [OSTI]

    Andresen, Brian D.; Randich, Erik

    2005-03-29

    A porous protective sheath for active extraction media used in solid phase microextraction (SPME). The sheath permits exposure of the media to the environment without the necessity of extending a fragile coated fiber from a protective tube or needle. Subsequently, the sheath can pierce and seal with GC-MS septums, allowing direct injection of samples into inlet ports of analytical equipment. Use of the porous protective sheath, within which the active extraction media is contained, mitigates the problems of: 1) fiber breakage while the fiber is extended during sampling, 2) active media coating loss caused by physical contact of the bare fiber with the sampling environment; and 3) coating slough-off during fiber extension and retraction operations caused by rubbing action between the fiber and protective needle or tube.

  20. Fuel injector system

    DOE Patents [OSTI]

    Hsu, Bertrand D.; Leonard, Gary L.

    1988-01-01

    A fuel injection system particularly adapted for injecting coal slurry fuels at high pressures includes an accumulator-type fuel injector which utilizes high-pressure pilot fuel as a purging fluid to prevent hard particles in the fuel from impeding the opening and closing movement of a needle valve, and as a hydraulic medium to hold the needle valve in its closed position. A fluid passage in the injector delivers an appropriately small amount of the ignition-aiding pilot fuel to an appropriate region of a chamber in the injector's nozzle so that at the beginning of each injection interval the first stratum of fuel to be discharged consists essentially of pilot fuel and thereafter mostly slurry fuel is injected.

  1. Effects of polymethylmethacrylate-transfer residues on the growth of organic semiconductor molecules on chemical vapor deposited graphene

    SciTech Connect (OSTI)

    Kratzer, Markus Teichert, Christian; Bayer, Bernhard C.; Kidambi, Piran R.; Matkovi?, Aleksandar; Gaji?, Rado; Cabrero-Vilatela, Andrea; Weatherup, Robert S.; Hofmann, Stephan

    2015-03-09

    Scalably grown and transferred graphene is a highly promising material for organic electronic applications, but controlled interfacing of graphene thereby remains a key challenge. Here, we study the growth characteristics of the important organic semiconductor molecule para-hexaphenyl (6P) on chemical vapor deposited graphene that has been transferred with polymethylmethacrylate (PMMA) onto oxidized Si wafer supports. A particular focus is on the influence of PMMA residual contamination, which we systematically reduce by H{sub 2} annealing prior to 6P deposition. We find that 6P grows in a flat-lying needle-type morphology, surprisingly independent of the level of PMMA residue and of graphene defects. Wrinkles in the graphene typically act as preferential nucleation centers. Residual PMMA does however limit the length of the resulting 6P needles by restricting molecular diffusion/attachment. We discuss the implications for organic device fabrication, with particular regard to contamination and defect tolerance.

  2. Atmospheric pressure plasma analysis by modulated molecular beam mass spectrometry

    SciTech Connect (OSTI)

    Aranda Gonzalvo, Y.; Whitmore, T.D.; Rees, J.A.; Seymour, D.L.; Stoffels, E.

    2006-05-15

    Fractional number density measurements for a rf plasma 'needle' operating at atmospheric pressure have been obtained using a molecular beam mass spectrometer (MBMS) system designed for diagnostics of atmospheric plasmas. The MBMS system comprises three differentially pumped stages and a mass/energy analyzer and includes an automated beam-to-background measurement facility in the form of a software-controlled chopper mechanism. The automation of the beam modulation allows the neutral components in the plasma to be rapidly and accurately measured using the mass spectrometer by threshold ionization techniques. Data are reported for plasma generated by a needle plasma source operated using a helium/air mixture. In particular, data for the conversion of atmospheric oxygen and nitrogen into nitric oxide are discussed with reference to its significance for medical applications such as disinfecting wounds and dental cavities and for microsurgery.

  3. Preparation and characterization of Chitosan/Konjac glucomannan/CdS nanocomposite film with low infrared emissivity

    SciTech Connect (OSTI)

    Zhang, Feng-Ying; Zhou, Yu-Ming; Sun, Yan-qing; Chen, Jing; Ye, Xiao-yun; Huang, Jing-yi

    2010-07-15

    Novel organic-inorganic nanocomposite films were prepared with Chitosan (CS), Konjac glucomannan (KGM) and CdS by one-step synthesis. As-prepared films were characterized by IR spectra, transmission electron microscopy (TEM), scanning electron microscopy (SEM) and infrared emissometer (IR). The results indicated that grown CdS dendrites were formed with reaction time of 12 h for Cd{sup 2+} and CS/KGM, and were well dispersed in CS/KGM with an average diameter of 40 nm. The CS/KGM/CdS nanocomposite films had significantly low infrared emissivity. When the mole ratio of CdS to summation of CS and KGM construction units was 1.0 with CdS size of 10-20 nm, the film got the lowest infrared emissivity value of 0.011, which could be attributed to the strong synergism effect existing between CS/KGM and CdS dendrites.

  4. Solid solution lithium alloy cermet anodes

    DOE Patents [OSTI]

    Richardson, Thomas J.

    2013-07-09

    A metal-ceramic composite ("cermet") has been produced by a chemical reaction between a lithium compound and another metal. The cermet has advantageous physical properties, high surface area relative to lithium metal or its alloys, and is easily formed into a desired shape. An example is the formation of a lithium-magnesium nitride cermet by reaction of lithium nitride with magnesium. The reaction results in magnesium nitride grains coated with a layer of lithium. The nitride is inert when used in a battery. It supports the metal in a high surface area form, while stabilizing the electrode with respect to dendrite formation. By using an excess of magnesium metal in the reaction process, a cermet of magnesium nitride is produced, coated with a lithium-magnesium alloy of any desired composition. This alloy inhibits dendrite formation by causing lithium deposited on its surface to diffuse under a chemical potential into the bulk of the alloy.

  5. Interdendritic spacing: Pt. II. A comparison of theory and experiment

    SciTech Connect (OSTI)

    Trivedi, R.

    1984-06-01

    The primary spacing data of Part I are compared to the existing theoretical models of Hunt and of Kurz and Fisher, and a significant disagreement is found. A theoretical model based on the Hunt model is developed, and it is found that the theory adequately explains the variation in primary spacing, lambda/sub 1/ corresponds to the growth rate, V. A maximum in lambda/sub 1/ vs V is predicted and the velocity at which the maximum occurs matches with the result obtained experimentally. It is shown that the maximum in lambda/sub 1/ corresponds to the dendrite-to-cell transition and cellular structures are found to grow with much smaller spacings than dendritic structures under identical growth conditions.

  6. Evolution of the microstructure and hardness of a rapidly solidified/melt-spun AZ91 alloy upon aging at different temperatures

    SciTech Connect (OSTI)

    Wang Baishu; Liu Yongbing; An Jian; Li Rongguang; Su Zhenguo; Su Guihua; Lu You; Cao Zhanyi

    2009-04-15

    The effect of aging at different temperatures on a rapidly solidified/melt-spun AZ91 alloy has been investigated in depth. The microstructures of as-spun and aged ribbons with a thickness of approximately 60 {mu}m were characterized using X-ray diffraction, transmission electron microscopy and laser optical microscopy; microhardness measurements were also conducted. It was found that the commercial AZ91 alloy undergoes a cellular/dendritic transition during melt-spinning at a speed of 34 m/s. A strengthening effect due to aging was observed: a maximum hardness of 110 HV/0.05 and an age-hardenability of 50% were obtained when the ribbon was aged at 200 deg. C for 20 min. The {beta}-Mg{sub 17}Al{sub 12} phase exhibits net and dispersion types of distribution during precipitation. The dispersion of precipitates in dendritic grains or cells is the main source of strengthening.

  7. Ductile alloy and process for preparing composite superconducting wire

    DOE Patents [OSTI]

    Verhoeven, J.D.; Finnemore, D.K.; Gibson, E.D.; Ostenson, J.E.

    An alloy for the commercial production of ductile superconducting wire is prepared by melting together copper and at least 15 weight percent niobium under non-oxygen-contaminating conditions, and rapidly cooling the melt to form a ductile composite consisting of discrete, randomly distributed and oriented dendritic-shaped particles of niobium in a copper matrix. As the wire is worked, the dendritic particles are realigned parallel to the longitudinal axis and when drawn form a plurality of very fine ductile superconductors in a ductile copper matrix. The drawn wire may be tin coated and wound into magnets or the like before diffusing the tin into the wire to react with the niobium. Impurities such as aluminum or gallium may be added to improve upper critical field characteristics.

  8. Metal Alloy Compositions And Process Background Of The Invention

    DOE Patents [OSTI]

    Flemings, Merton C.; Martinez-Ayers, Raul A.; de Figueredo, Anacleto M.; Yurko, James A.

    2003-11-11

    A skinless metal alloy composition free of entrapped gas and comprising primary solid discrete degenerate dendrites homogeneously dispersed within a secondary phase is formed by a process wherein the metal alloy is heated in a vessel to render it a liquid. The liquid is then rapidly cooled while vigorously agitating it under conditions to avoid entrapment of gas while forming solid nuclei homogeneously distributed in the liquid. Agitation then is ceased when the liquid contains a small fraction solid or the liquid-solid alloy is removed from the source of agitation while cooling is continued to form the primary solid discrete degenerate dendrites in liquid secondary phase. The solid-liquid mixture then can be formed such as by casting.

  9. Quality Assurance of Multifractionated Pelvic Interstitial Brachytherapy for Postoperative Recurrences of Cervical Cancers: A Prospective Study

    SciTech Connect (OSTI)

    Shukla, Pragya; Chopra, Supriya; Engineer, Reena; Mahantshetty, Umesh; Paul, Siji Nojin; Phurailatpam, Reena; SV, Jamema; Shrivastava, Shyam K.

    2012-03-15

    Purpose: To evaluate three-dimensional needle displacements during multifractionated interstitial brachytherapy (BT) for cervical cancers. Methods and Materials: Patients scheduled to undergo pelvic interstitial BT for postoperative and or postradiation vault recurrences were included from November 2009 to December 2010. All procedures were performed under spinal anesthesia. Postprocedure BT planning CT scans were obtained with patients in supine position with arms on the chest (interslice thickness of 3 mm). Thereafter, verification CT was repeated at every alternate fraction. Needle displacements were measured in reference to a relocatable bony point. The mean cranial, caudal, anteroposterior, and mediolateral displacements were recorded. Statistical significance of mean interfraction displacements was evaluated with Wilcoxon Test. Results: Twenty patients were included. Seventeen received boost BT (20 Gy/5 fractions/3 days) after external radiation, three received radical BT alone (36 Gy/9 fractions/5-8 days). An average of three scans (range, 2-3) were available per patient, and 357 needle displacements were analyzed. For the entire study cohort, the average of mean needle displacement was 2.5 mm (range, 0-7.4), 17.4 mm (range, 0-27.9), 1.7 mm (range, 0-6.7), 2.1 mm (range, 0-9.5), 1.7 mm (range, 0-9.3), and 0.6 mm (range, 0-7.8) in cranial, caudal, anterior, posterior, right, and left directions, respectively. The mean displacement in the caudal direction was higher between Days 1 and 2 than that between Days 2 and 3 (13.4 mm vs. 3.8 mm; p = 0.01). The average caudal displacements were no different between reirradiation and boost cohort (15.2 vs. 17.8 mm). Conclusions: Clinically significant caudal displacements occur during multifractionated pelvic brachytherapy. Optimal margins need to be incorporated while preplanning brachytherapy to account for interfraction displacements.

  10. Saul Perlmutter,

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Data, Computation, and the Fate of the Universe Saul Perlmutter, which are needles in haystack of 1 M candidates/night. SN observations compared to supercomputer-based simulations. Statistical analyses of cosmological parameters need Markov Chain Monte Carlo (MCMC). Baryon Acoustic Oscillations (BAO): Large quantities of data need to be analyzed. Imaging survey in 2005: 20 TB in 2025 60 PB Statistical analyses need MCMC for cross- correlation of the millions of galaxies -- collapsing the problem