Sample records for denatured aliphatic alcohol

  1. aliphatic secondary alcohols: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for conversion of biomass derived feedstocks to fuels and fuel additives. Synthesis of ethanol and higher aliphatic alcohols from syngas (CO + H2... Baksh, Faisal 2010-04-19 3 The...

  2. Process for the synthesis of aliphatic alcohol-containing mixtures

    DOE Patents [OSTI]

    Greene, M.I.; Gelbein, A.P.

    1984-10-16T23:59:59.000Z

    A process for the synthesis of mixtures which include saturated aliphatic alcohols is disclosed. In the first step of the process, the first catalyst activation stage, a catalyst, which comprises the oxides of copper, zinc, aluminum, potassium and one or two additional metals selected from the group consisting of chromium, magnesium, cerium, cobalt, thorium and lanthanum, is partially activated. In this step, a reducing gas stream, which includes hydrogen and at least one inert gas, flows past the catalyst at a space velocity of up to 5,000 liters (STP) per hour, per kilogram of catalyst. The partially activated catalyst is then subjected to the second step of the process, second-stage catalyst activation. In this step, the catalyst is contacted by an activation gas stream comprising hydrogen and carbon monoxide present in a volume ratio of 0.5:1 and 4:1, respectively, at a temperature of 200 to 450 C and a pressure of between 35 and 200 atmospheres. The activation gas flows at a space velocity of from 1,000 to 20,000 liters (STP) per hour, per kilogram of catalyst. Second-stage activation continues until the catalyst is contacted with at least 500,000 liters (STP) of activation gas per kilogram of catalyst. The fully activated catalyst, in the third step of the process, contacts a synthesis gas stream comprising hydrogen and carbon monoxide.

  3. Process for the synthesis of aliphatic alcohol-containing mixtures

    DOE Patents [OSTI]

    Greene, Marvin I. (Oradell, NJ); Gelbein, Abraham P. (Morristown, NJ)

    1984-01-01T23:59:59.000Z

    A process for the synthesis of mixtures which include saturated aliphatic alcohols is disclosed. In the first step of the process, the first catalyst activation stage, a catalyst, which comprises the oxides of copper, zinc, aluminum, potassium and one or two additional metals selected from the group consisting of chromium, magnesium, cerium, cobalt, thorium and lanthanum, is partially activated. In this step, a reducing gas stream, which includes hydrogen and at least one inert gas, flows past the catalyst at a space velocity of up to 5,000 liters (STP) per hour, per kilogram of catalyst. The partially activated catalyst is then subjected to the second step of the process, second-stage catalyst activation. In this step, the catalyst is contacted by an activation gas stream comprising hydrogen and carbon monoxide present in a volume ratio of 0.5:1 and 4:1, respectively, at a temperature of 200.degree. to 450.degree. C. and a pressure of between 35 and 200 atmospheres. The activation gas flows at a space velocity of from 1,000 to 20,000 liters (STP) per hour, per kilogram of catalyst. Second-stage activation continues until the catalyst is contacted with at least 500,000 liters (STP) of activation gas per kilogram of catalyst. The fully activated catalyst, in the third step of the process, contacts a synthesis gas stream comprising hydrogen and carbon monoxide.

  4. aliphatic alcohols studies: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    second, the efficacy of three psychotherapies for alcoholism in treating extreme West, Mike 393 Characterization of Catalysts for the Synthesis of Higher Alcohols using...

  5. Synthesis Gas Conversion to Aliphatic Alcohols: Study of MoS2 catalytic systems

    E-Print Network [OSTI]

    Baksh, Faisal

    2010-04-19T23:59:59.000Z

    . 1-butanol is considered by many to be the most suitable alcohol replacement for gasoline. Plans for conversion of existing bioethanol facilities to biobutanol are already being drawn up. Early on, methanol-gasoline blends were extensively tested...

  6. aliphatic alkyl quaternaries: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for conversion of biomass derived feedstocks to fuels and fuel additives. Synthesis of ethanol and higher aliphatic alcohols from syngas (CO + H2... Baksh, Faisal 2010-04-19 45...

  7. A novel copper(II)-Schiff base complex containing pyrrole ring: Synthesis, characterization and its modified electrodes applied in oxidation of aliphatic alcohols

    E-Print Network [OSTI]

    Boyer, Edmond

    , ethanol and benzyl alcohol. The electro-reduction of carbon dioxide was also examined. Keywords: Copper] and carbon dioxide [9]. So, in continuation of our recent papers [10], we have undertaken a covalent grafting. Thus, conducting polymeric films of polypyrrole were obtained on the surfaces of glassy carbon and ITO

  8. Denatured Alcohol MATERIAL SAFETY DATA SHEET

    E-Print Network [OSTI]

    Rollins, Andrew M.

    lights, and turn off stoves, heaters, electric motors and all other sources of ignition during use damage, and death. No data available. Signs and Symptoms Of Exposure Diseases of the liver. Medical

  9. Introduction Aliphatic polyesters derived from renewable

    E-Print Network [OSTI]

    Introduction Aliphatic polyesters derived from renewable resources are of increasing interest, there are also opportunities to derive lactones from biomass, which can then be converted to a wide range

  10. Probing the denatured state ensemble with fluorescence

    E-Print Network [OSTI]

    Alston, Roy Willis

    2004-09-30T23:59:59.000Z

    around the original tryptophan substitutions in RNase Sa. Regardless of the denaturant, ?max for the proteins and model compounds differed very little, 349.3 ± 1.2 nm. However, significant differences were observed in the fluorescence intensity at ?max...

  11. Probing the denatured state ensemble with fluorescence 

    E-Print Network [OSTI]

    Alston, Roy Willis

    2004-09-30T23:59:59.000Z

    To understand protein stability and the mechanism of protein folding, it is essential that we gain a better understanding of the ensemble of conformations that make up the denatured state of a protein. The primary goal of the research described...

  12. Competitive Oxidation and Reduction of Aliphatic Alcohols over...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    bond to give alkoxy (RO ) bound to W(VI) centers and a proton (H+) attached to the terminal oxygen atom of a tungstyl group (WO). Two protons adsorbed onto the cluster readily...

  13. Development of aliphatic biodegradable photoluminescent polymers

    E-Print Network [OSTI]

    Yang, Jian

    , 2009 (received for review January 8, 2009) None of the current biodegradable polymers can function monomers including citric acid, aliphatic diols, and various amino acids via a convenient and cost/nano- fabrication. We demonstrate the feasibility of using BPLP-Ser nanoparticles (``biodegradable quantum dots

  14. Process for reducing organic compounds with calcium, amine, and alcohol

    DOE Patents [OSTI]

    Benkeser, R.A.; Laugal, J.A.; Rappa, A.

    1985-08-06T23:59:59.000Z

    Olefins are produced by contacting an organic compound having at least one benzene ring with calcium metal, ethylenediamine, a low molecular weight aliphatic alcohol, and optionally a low molecular weight aliphatic primary amine, and/or an inert, abrasive particulate substance. The reduction is conducted at temperatures ranging from about [minus]10 C to about 30 C or somewhat higher. Substantially all of the organic compounds are converted to corresponding cyclic olefins, primarily diolefins.

  15. Process for reducing organic compounds with calcium, amine, and alcohol

    DOE Patents [OSTI]

    Benkeser, Robert A. (West Lafayette, IN); Laugal, James A. (Lostant, IL); Rappa, Angela (Baltimore, MD)

    1985-01-01T23:59:59.000Z

    Olefins are produced by contacting an organic compound having at least one benzene ring with calcium metal, ethylenediamine, a low molecular weight aliphatic alcohol, and optionally a low molecular weight aliphatic primary amine, and/or an inert, abrasive particulate substance. The reduction is conducted at temperatures ranging from about -10.degree. C. to about 30.degree. C. or somewhat higher. Substantially all of the organic compounds are converted to corresponding cyclic olefins, primarily diolefins.

  16. A denaturation study of human serum transferrin and apotransferrin

    E-Print Network [OSTI]

    Kennah, Harold Edwin

    1974-01-01T23:59:59.000Z

    ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ 19 GuCH1 Denaturation ~ ~ . ~ ~ ~ ~ ~ ~ ~ ~ ~ Urea Denaturation. . . ~ ~ ~ . . . ? . ~ 19 Thermal Denaturation 38 PH Denaturation. . . . ? . . . . ~ ~ ~ ~ DISCUSSION ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ REFERENCES ~ ~ ~ ~ e e o ~ ~ I ~ ~ ~ . ~ I... of apotransferrin ( ~ ) and transferrin (o) by GPC1 at 25 C, pH 7. 45, 6. 24 x 10 M NTA, I = 0 ' 15 N KC1-HC1, e ~ ~ ~ ~ Page 21 The dependence of the apparent changes in free energy on the concentration of GuHC1. ~ ~ , . . . 25 The difference spectra...

  17. DNA Bubble Life Time in Denaturation

    E-Print Network [OSTI]

    Zh. S. Gevorkian; Chin-Kun Hu

    2010-10-11T23:59:59.000Z

    We have investigated the denaturation bubble life time for a homogeneous as well as for a heterogeneous DNA within a Poland-Scheraga model. It is shown that at criticality the bubble life time for a homogeneous DNA is finite provided that the loop entropic exponent c>2 and has a scaling dependence on DNA length for c<2. Heterogeneity in the thermodynamical limit makes the bubble life time infinite for any entropic exponent.

  18. approach aliphatic monoesters: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in treating a variety of electrostatic Jayaram, Bhyravabotla 6 Far infrared spectra of solid state aliphatic amino acids in different protonation states Physics Websites Summary:...

  19. aliphatic copolyester films: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Release: Refer to the SAMPLE INDEX for a list of validated samples. Refer to the DATA 20 Synthesis and Self-Assembly of Amphiphilic Dendrimers Based on Aliphatic Polyether-Type...

  20. Process for producing peracids from aliphatic hydroxy carboxylic acids

    DOE Patents [OSTI]

    Chum, H.L.; Palasz, P.D.; Ratcliff, M.A.

    1984-12-20T23:59:59.000Z

    A process is described for producing peracids from lactic acid-containing solutions derived from biomass processing systems. It consists of adjusting the pH of the solution to about 8 to 9 and removing alkaline residue fractions therefrom to form a solution comprised substantially of lower aliphatic hydroxy acids. The solution is oxidized to produce volatile lower aliphatic aldehydes. The aldehydes are removed as they are generated and converted to peracids.

  1. automated constant denaturant: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Condensed Matter (arXiv) Summary: Experiments show that for many two state folders the free energy of the native state DGND(C) changes linearly as the denaturant...

  2. Synthesis of Aliphatic-Aromatic Copolyesters by a High Temperature

    E-Print Network [OSTI]

    Khan, Saad A.

    -aromatic polyesters. #12;Full Paper: Reverse-selective polymer membranes exhibiting high CO2 affinity can be used for purification of H2 in industrial gasification processes. In this work, the phy- sical properties of CO2Synthesis of Aliphatic-Aromatic Copolyesters by a High Temperature Bulk Reaction Between Poly

  3. How water contributes to pressure and cold denaturation of proteins

    E-Print Network [OSTI]

    Valentino Bianco; Giancarlo Franzese

    2015-05-28T23:59:59.000Z

    The mechanisms of cold- and pressure-denaturation of proteins are matter of debate and are commonly understood as due to water-mediated interactions. Here we study several cases of proteins, with or without a unique native state, with or without hydrophilic residues, by means of a coarse-grain protein model in explicit solvent. We show, using Monte Carlo simulations, that taking into account how water at the protein interface changes its hydrogen bond properties and its density fluctuations is enough to predict protein stability regions with elliptic shapes in the temperature-pressure plane, consistent with previous theories. Our results clearly identify the different mechanisms with which water participates to denaturation and open the perspective to develop advanced computational design tools for protein engineering.

  4. How water contributes to pressure and cold denaturation of proteins

    E-Print Network [OSTI]

    Bianco, Valentino

    2015-01-01T23:59:59.000Z

    The mechanisms of cold- and pressure-denaturation of proteins are matter of debate and are commonly understood as due to water-mediated interactions. Here we study several cases of proteins, with or without a unique native state, with or without hydrophilic residues, by means of a coarse-grain protein model in explicit solvent. We show, using Monte Carlo simulations, that taking into account how water at the protein interface changes its hydrogen bond properties and its density fluctuations is enough to predict protein stability regions with elliptic shapes in the temperature-pressure plane, consistent with previous theories. Our results clearly identify the different mechanisms with which water participates to denaturation and open the perspective to develop advanced computational design tools for protein engineering.

  5. Aerobic microorganism for the degradation of chlorinated aliphatic hydrocarbons

    DOE Patents [OSTI]

    Fliermans, Carl B. (Augusta, GA)

    1989-01-01T23:59:59.000Z

    A chlorinated aliphatic hydrocarbon-degrading microorganism, having American Type Culture Collection accession numbers ATCC 53570 and 53571, in a biologically pure culture aseptically collected from a deep subsurface habitat and enhanced, mineralizes trichloroethylene and tetrachloroethylene to HCl, H.sub.2 O and Co.sub.2 under aerobic conditions stimulated by methane, acetate, methanol, tryptone-yeast extract, propane and propane-methane.

  6. Barnase as a model for the denatured state of proteins

    E-Print Network [OSTI]

    Hoffart, Lee Michael

    2013-02-22T23:59:59.000Z

    Texas A8cM University in partial fulfillment of the requirements of the UNIVERSITY UNDERGRADUATE RESEARCH FELLOWS Approved as to style and content by: C. Nick Pace (Fellows Advisor) Edward A. Funkhouser (Executive Director) April 2002 Group...: Life Sciences II ABSTRACT Barnase As A Model For The Denatured State Of Proteins (April 2002) Lee Michael Hoffart Department of Biochemistry Texas A8cM University Fellows Advisor: Dr. C. Nick Pace Department of Medical Biochemistry and Genetics...

  7. Process for producing peracids from aliphatic hydroxy carboxylic acids

    SciTech Connect (OSTI)

    Chum, H.L.; Ratcliff, M.A.; Palasz, P.D.

    1986-10-14T23:59:59.000Z

    This patent describes a wood pulp processing system of the type producing both pulp and a stream of lactic acid-containing black liquor solution, the processor for production of peracid bleaching agents from hydroxy acid contained in the black liquor solution, comprising: adjusting the pH of the black liquor solution to the range of about 8-9 by exposing the solution to CO/sub 2/ carbon dioxide to form an alkaline precipitate; separating solids from the black liquor solution to produce a residual solution containing lower aliphatic hydroxy acids selected from the group consisting of lactic acid, glycolic acid, 2-hydroxybutanoic acid, xyloisosaccharinic acid, and glucoisosaccharinic acid; decarboxylating the lower aliphatic hydroxy acids to corresponding gaseous aliphatic aldehydes by admixing a powdered semiconductor with the residual solution to form a slurry; removing the gaseous aldehydes from the residual solution by sweeping gas flow as soon as they are generated to prevent further oxidation to carboxylic acids; reacting the gaseous aldehydes with oxygen to form corresponding peracids; and applying the peracids as bleaching agents to the pulp produced in the pulp processing system.

  8. Strategies for denaturing the weapons-grade plutonium stockpile

    SciTech Connect (OSTI)

    Buckner, M.R.; Parks, P.B.

    1992-10-01T23:59:59.000Z

    In the next few years, approximately 50 metric tons of weapons-grade plutonium and 150 metric tons of highly-enriched uranium (HEU) may be removed from nuclear weapons in the US and declared excess. These materials represent a significant energy resource that could substantially contribute to our national energy requirements. HEU can be used as fuel in naval reactors, or diluted with depleted uranium for use as fuel in commercial reactors. This paper proposes to use the weapons-grade plutonium as fuel in light water reactors. The first such reactor would demonstrate the dual objectives of producing electrical power and denaturing the plutonium to prevent use in nuclear weapons.

  9. ORGANIC GEOCHEMICAL STUDIES. II. THE DISTRIBUTION OF ALIPHATIC HYDROCARBONS IN ALGAE, BACTERIA, AND IN A RECENT LAKE SEDIMENT: A PRELIMINARY REPORT

    E-Print Network [OSTI]

    Han, Jerry; McCarthy, E.D.; Van Hoeven Jr., William; Calvin, Melvin; Bradley, W. H.

    2008-01-01T23:59:59.000Z

    significantly to the hydrocarbons of higher molecular weightDISTRIBUTION OF ALIPHATIC HYDROCARBONS IN ALGAE, BACTERIA,T E DISTRIBUTION O ALIPHATIC HYDROCARBONS H F A PRELIMINARY

  10. Kinetics of Loop Formation and Breakage in the Denatured State of Iso-1-cytochrome c

    E-Print Network [OSTI]

    Roder, Heinrich

    Kinetics of Loop Formation and Breakage in the Denatured State of Iso-1-cytochrome c Eydiejo to measure the rates of histidine­heme loop formation and breakage in the denatured state of iso-1-cytochrome single surface histidine variants of iso-1-cytochrome c. A scaling factor (the dependence of kf on log

  11. Interactions mixing alcohol

    E-Print Network [OSTI]

    Bezrukov, Sergey M.

    --including many popular painkillers and cough, cold, and allergy remedies--contain more than one ingredient alcohol. Cough syrup and laxatives may have some of the high- est alcohol concentrations. ALCOHOL AFFECTS

  12. Metal Catalyzed Formation of Aliphatic Polycarbonates Involving Oxetanes and Carbon Dioxide as Monomers

    E-Print Network [OSTI]

    Moncada, Adriana I.

    2011-08-08T23:59:59.000Z

    including phosgene and its derivatives. Therefore, it has been of great interest to investigate greener routes for the production of this important class of polymers. Toward this goal, the synthesis of aliphatic polycarbonates via the metal catalyzed...

  13. Plectoneme tip bubbles: Coupled denaturation and writhing in supercoiled DNA

    E-Print Network [OSTI]

    Christian Matek; Thomas E. Ouldridge; Jonathan P. K. Doye; Ard A. Louis

    2014-04-10T23:59:59.000Z

    Biological information is not only stored in the digital chemical sequence of double helical DNA, but is also encoded in the mechanical properties of the DNA strands, which can influence biochemical processes involving its readout. For example, loop formation in the Lac operon can regulate the expression of key genes, and DNA supercoiling is closely correlated to rhythmic circardian gene expression in cyanobacteria. Supercoiling is also important for large scale organisation of the genome in both eukaryotic and prokaryotic cells. DNA can respond to torsional stress by writhing to form looped structures called plectonemes, thus transferring energy stored as twist into energy stored in bending. Denaturation bubbles can also relax torsional stress, with the enthalpic cost of breaking bonds being compensated by their ability to absorb undertwist. Here we predict a novel regime where bubbles form at the tips of plectonemes, and study its properties using coarse-grained simulations. These tip bubbles can occur for both positive and negative supercoiling and greatly reduce plectoneme diffusion by a pinning mechanism. They can cause plectonemes to preferentially localise to AT rich regions, because bubbles more easily form there. The tip-bubble regime occurs for supercoiling densities and forces that are typically encountered for DNA in vivo, and may be exploited for biological control of genomic processes.

  14. Mechanisms of bioprosthetic heart valve failure: Fatigue causes collagen denaturation and glycosaminoglycan loss

    E-Print Network [OSTI]

    Zand, Robert

    Mechanisms of bioprosthetic heart valve failure: Fatigue causes collagen denaturation heart valve (BPHV) degeneration, characterized by extracellular matrix deterioration, remod- eling) with glutaraldehyde fixed porcine aortic valve bioprostheses, that the mechanical function of cardiac valve cusps

  15. Denaturation and Renaturation of Self-Assembled Yeast Iso-1-cytochrome c on Au

    E-Print Network [OSTI]

    Zare, Richard N.

    Denaturation and Renaturation of Self-Assembled Yeast Iso-1-cytochrome c on Au Soonwoo Chah, Challa 06269-4060 We have made surface plasmon resonance (SPR) mea- surements of yeast iso-1-cytochrome c (Cyt

  16. Process for removing halogenated aliphatic and aromatic compounds from petroleum products

    DOE Patents [OSTI]

    Googin, J.M.; Napier, J.M.; Travaglini, M.A.

    1983-09-20T23:59:59.000Z

    A process is described for removing halogenated aliphatic and aromatic compounds, e.g., polychlorinated biphenyls, from petroleum products by solvent extraction. The halogenated aliphatic and aromatic compounds are extracted from a petroleum product into a polar solvent by contacting the petroleum product with the polar solvent. The polar solvent is characterized by a high solubility for the extracted halogenated aliphatic and aromatic compounds, a low solubility for the petroleum product and considerable solvent power for polyhydroxy compound. The preferred polar solvent is dimethylformamide. A miscible compound, such as, water or a polyhydroxy compound, is added to the polar extraction solvent to increase the polarity of the polar extraction solvent. The halogenated aliphatic and aromatic compounds are extracted from the highly-polarized mixture of water or polyhydroxy compound and polar extraction solvent into a low polar or nonpolar solvent by contacting the water or polyhydroxy compound-polar solvent mixture with the low polar or nonpolar solvent. The halogenated aliphatic and aromatic compounds and the low polar or nonpolar solvent are separated by physical means, e.g., vacuum evaporation. The polar and nonpolar solvents are recovered from recycling. The process can easily be designed for continuous operation. Advantages of the process include that the polar solvent and a major portion of the nonpolar solvent can be recycled, the petroleum products are reclaimable and the cost for disposing of waste containing polychlorinated biphenyls is significantly reduced. 1 fig.

  17. Process for removing halogenated aliphatic and aromatic compounds from petroleum products

    DOE Patents [OSTI]

    Googin, John M. (Oak Ridge, TN); Napier, John M. (Oak Ridge, TN); Travaglini, Michael A. (Oliver Springs, TN)

    1983-01-01T23:59:59.000Z

    A process for removing halogenated aliphatic and aromatic compounds, e.g., polychlorinated biphenyls, from petroleum products by solvent extraction. The halogenated aliphatic and aromatic compounds are extracted from a petroleum product into a polar solvent by contacting the petroleum product with the polar solvent. The polar solvent is characterized by a high solubility for the extracted halogenated aliphatic and aromatic compounds, a low solubility for the petroleum product and considerable solvent power for polyhydroxy compound. The preferred polar solvent is dimethylformamide. A miscible compound, such as, water or a polyhydroxy compound, is added to the polar extraction solvent to increase the polarity of the polar extraction solvent. The halogenated aliphatic and aromatic compounds are extracted from the highly-polarized mixture of water or polyhydroxy compound and polar extraction solvent into a low polar or nonpolar solvent by contacting the water or polyhydroxy compound-polar solvent mixture with the low polar or nonpolar solvent. The halogenated aliphatic and aromatic compounds and the low polar or nonpolar solvent are separated by physical means, e.g., vacuum evaporation. The polar and nonpolar solvents are recovered from recycling. The process can easily be designed for continuous operation. Advantages of the process include that the polar solvent and a major portion of the nonpolar solvent can be recycled, the petroleum products are reclaimable and the cost for disposing of waste containing polychlorinated biphenyls is significantly reduced.

  18. aliphatic hydrocarbons constitute the largest fraction of cuticular wax in bees and cover

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    aliphatic hydrocarbons constitute the largest fraction of cuticular wax in bees and cover a highly hydrocarbons in the cuticular waxes of bees are widely assumed to func- tion as recognition cues (for nestmate hydrocarbons may label individuals in colonies according to the tasks they under- take and that the compounds

  19. Metal Catalyzed Formation of Aliphatic Polycarbonates Involving Oxetanes and Carbon Dioxide as Monomers 

    E-Print Network [OSTI]

    Moncada, Adriana I.

    2011-08-08T23:59:59.000Z

    Catalysts for Ring-Opening Polymerization of Six-Membered Cyclic Carbonates .......................................................................... 8 Aliphatic Polycarbonates from Oxetanes and Carbon Dioxide...... 15 Metal Salen Complexes... in TCE. Slope = -8910.7 with R2 = 0.9997 ......................................................................................... 56 II-15 1H NMR spectrum in CDCl3 of poly(TMC) obtained by way of oxetane/CO2 in the presence of (salen...

  20. Matrixassisted laser desorption/ionization mass spectrometric analysis of aliphatic biodegradable photoluminescent polymers

    E-Print Network [OSTI]

    Yang, Jian

    photoluminescent polymers using new ionic liquid matrices Carlos A. Serrano1 , Yi Zhang2 , Jian Yang2 and Kevin A elucidation of recently developed aliphatic biodegradable polymers by matrixassisted laser desorption/ionization mass spectrometry (MALDIMS). The polymers, formed by a condensation reaction of three components

  1. The extremely slow-exchanging core and acid-denatured state of green fluorescent protein

    E-Print Network [OSTI]

    Jackson, Sophie

    with a complex eleven- stranded -barrel structure. Previous studies have shown that it has a complex energy resonance ,,NMR... techniques to probe the energy landscape for folding of GFP in further detail. H a folding nucleus. Using a pulsed-labeling strategy, the acid-denatured state has been investigated

  2. Furfuryl alcohol cellular product

    DOE Patents [OSTI]

    Sugama, T.; Kukacka, L.E.

    1982-05-26T23:59:59.000Z

    Self-extinguishing rigid foam products are formed by polymerization of furfuryl alcohol in the presence of a lightweight, particulate, filler, zinc chloride and selected catalysts.

  3. alcohol ethyl alcohol: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    second, the efficacy of three psychotherapies for alcoholism in treating extreme West, Mike 243 Characterization of Catalysts for the Synthesis of Higher Alcohols using...

  4. Electrooxidation of Alcohols Catalyzed by Amino Alcohol Ligated Ruthenium Complexes

    E-Print Network [OSTI]

    Zare, Richard N.

    Alcohols are attractive chemical fuels for fuel cells due to their high energy densities, established, even the most highly optimized alcohol electrooxidation catalysts suffer from kinetic limitations

  5. Periodic force induced stabilization or destabilization of the denatured state of a protein

    E-Print Network [OSTI]

    Ghosh, Pulak Kumar; Bag, Bidhan Chandra; 10.1063/1.3635774

    2012-01-01T23:59:59.000Z

    We have studied the effects of an external sinusoidal force in protein folding kinetics. The externally applied force field acts on the each amino acid residues of polypeptide chains. Our simulation results show that mean protein folding time first increases with driving frequency and then decreases passing through a maximum. With further increase of the driving frequency the mean folding time starts increasing as the noise-induced hoping event (from the denatured state to the native state) begins to experience many oscillations over the mean barrier crossing time period. Thus unlike one-dimensional barrier crossing problems, the external oscillating force field induces both \\emph{stabilization or destabilization of the denatured state} of a protein. We have also studied the parametric dependence of the folding dynamics on temperature, viscosity, non-Markovian character of bath in presence of the external field.

  6. Thermal and mechanical denaturation properties of a DNA model with three sites per nucleotide

    E-Print Network [OSTI]

    Florescu, Ana-Maria; 10.1063/1.3626870

    2011-01-01T23:59:59.000Z

    In this paper, we show that the coarse grain model for DNA, which has been proposed recently by Knotts, Rathore, Schwartz and de Pablo (J. Chem. Phys. 126, 084901 (2007)), can be adapted to describe the thermal and mechanical denaturation of long DNA sequences by adjusting slightly the base pairing contribution. The adjusted model leads to (i) critical temperatures for long homogeneous sequences that are in good agreement with both experimental ones and those obtained from statistical models, (ii) a realistic step-like denaturation behaviour for long inhomogeneous sequences, and (iii) critical forces at ambient temperature of the order of 10 pN, close to measured values. The adjusted model furthermore supports the conclusion that the thermal denaturation of long homogeneous sequences corresponds to a first-order phase transition and yields a critical exponent for the critical force equal to sigma=0.70. This model is both geometrically and energetically realistic, in the sense that the helical structure and th...

  7. Supported metal catalysts for alcohol/sugar alcohol steam reforming

    SciTech Connect (OSTI)

    Davidson, Stephen; Zhang, He; Sun, Junming; Wang, Yong

    2014-08-21T23:59:59.000Z

    Despite extensive studies on hydrogen production via steam reforming of alcohols and sugar alcohols, catalysts typically suffer a variety of issues from poor hydrogen selectivity to rapid deactivation. Here, we summarize recent advances in fundamental understanding of functionality and structure of catalysts for alcohol/sugar alcohol steam reforming, and provide perspectives on further development required to design highly efficient steam reforming catalysts.

  8. Attachment F Marketplace Prohibited Items November 2014

    E-Print Network [OSTI]

    . · Alcohol (ethyl alcohol [ethanol] & denatured) · Alcoholic Beverages · Artwork (paintings, pictures, office

  9. Process for removing halogenated aliphatic and aromatic compounds from petroleum products. [Polychlorinated biphenyls; methylene chloride; perchloroethylene; trichlorofluoroethane; trichloroethylene; chlorobenzene

    DOE Patents [OSTI]

    Googin, J.M.; Napier, J.M.; Travaglini, M.A.

    1982-03-31T23:59:59.000Z

    A process for removing halogenated aliphatic and aromatic compounds, e.g., polychlorinated biphenyls, from petroleum products by solvent extraction. The halogenated aliphatic and aromatic compounds are extracted from a petroleum product into a polar solvent by contracting the petroleum product with the polar solvent. The polar solvent is characterized by a high solubility for the extracted halogenated aliphatic and aromatic compounds, a low solubility for the petroleum product and considerable solvent power for polyhydroxy compound. The preferred polar solvent is dimethylformamide. A miscible polyhydroxy compound, such as, water, is added to the polar extraction solvent to increase the polarity of the polar extraction solvent. The halogenated aliphatic and aromatic compounds are extracted from the highly-polarized mixture of polyhydroxy compound and polar extraction solvent into a low polar or nonpolar solvent by contacting the polyhydroxy compound-polar solvent mixture with the low polar or nonpolar solvent. The halogenated aliphatic and aromatic compounds in the low polar or nonpolar solvent by physical means, e.g., vacuum evaporation. The polar and nonpolar solvents are recovered for recycling. The process can easily be designed for continuous operation. Advantages of the process include that the polar solvent and a major portion of the nonpolar solvent can be recycled, the petroleum products are reclaimable and the cost for disposing of waste containing polychlorinated biphenyls is significantly reduced. 2 tables.

  10. A quantitative study of the effect of structure on the saponification rates of aliphatic esters

    E-Print Network [OSTI]

    Gonzalez, Federico P

    1961-01-01T23:59:59.000Z

    of aliphatic ~sters&" (H? ST 'I'basis& The agricul- tural and Hechanicul dolls~", e of Texas, iugust, 1960) ~ J 6 6 11, '. 9. , t 9 ' ~tt ', 10, 41 (199&). APPENDIX 41 TABLE Ssponificstion of Ethyl Acetate st 35 Ca Run 1 Run 2 Time, Resistance Nin... Bennyl Propiona te 14. 55 5. 477 4+041 Oi9992 )o219 Z ~ 420 0. 4604 Oe04956 9i553 TABLE Seoond Order Rate Constants for n-Butyrates Ester h35 2 ~ 1 -1 li aole sino Nethyl n Sutyrate Ethyl a-Butyrate a Propyl n Sutyrate Isopropyl n...

  11. Conceptual design characteristics of a denatured molten-salt reactor with once-through fueling

    SciTech Connect (OSTI)

    Engel, J.R.; Bauman, H.F.; Dearing, J.F.; Grimes, W.R.; McCoy, H.E.; Rhoades, W.A.

    1980-07-01T23:59:59.000Z

    A study was made to examine the conceptual feasibility of a molten-salt power reactor fueled with denatured /sup 235/U and operated with a minimum of chemical processing. Because such a reactor would not have a positive breeding gain, reductions in the fuel conversion ratio were allowed in the design to achieve other potentially favorable characteristics for the reactor. A conceptual core design was developed in which the power density was low enough to allow a 30-year life expectancy of the moderator graphite with a fluence limit of 3 x 10/sup 26/ neutrons/m/sup 2/ (E > 50 keV). This reactor could be made critical with about 3450 kg of 20% enriched /sup 235/U and operated for 30 years with routine additions of denatured /sup 235/U and no chemical processing for removal of fission products. A review of the chemical considerations assoicated with the conceptual fuel cycle indicates that no substantial difficulties would be expected if the soluble fission products and higher actinides were allowed to remain in the fuel salt for the life of the plant.

  12. Production of hydrogen from alcohols

    DOE Patents [OSTI]

    Deluga, Gregg A. (St. Paul, MN); Schmidt, Lanny D. (Minneapolis, MN)

    2007-08-14T23:59:59.000Z

    A process for producing hydrogen from ethanol or other alcohols. The alcohol, optionally in combination with water, is contacted with a catalyst comprising rhodium. The overall process is preferably carried out under autothermal conditions.

  13. Fermentative alcohol production

    DOE Patents [OSTI]

    Wilke, Charles R. (El Cerrito, CA); Maiorella, Brian L. (Berkeley, CA); Blanch, Harvey W. (Berkeley, CA); Cysewski, Gerald R. (Kennewick, WA)

    1982-01-01T23:59:59.000Z

    An improved fermentation process for producing alcohol which includes the combination of vacuum fermentation and vacuum distillation. Preferably, the vacuum distillation is carried out in two phases, one a fermentor proper operated at atmospheric pressure and a flash phase operated at reduced pressure with recycle of fermentation brew having a reduced alcohol content to the fermentor, using vapor recompression heating of the flash-pot recycle stream to heat the flash-pot or the distillation step, and using "water load balancing" (i.e., the molar ratio of water in the fermentor feed is the same as the molar ratio of water in the distillation overhead).

  14. Radionuclide imaging of the spleen with heat denatured technetium-99m RBC when the splenic reticuloendothelial system seems impaired

    SciTech Connect (OSTI)

    Owunwanne, A.; Halkar, R.; Al-Rasheed, A.; Abubacker, K.C.; Abdel-Dayem, H.

    1988-03-01T23:59:59.000Z

    Imaging of the spleen of 10 patients who had been hematologically diagnosed with sickle-cell anemia (SCA) was studied with (/sup 99m/Tc)tin colloid and heat denatured (/sup 99m/Tc)RBCs. In all ten patients, there was faint or nonvisualization of the spleen with (/sup 99m/Tc)tin colloid. However, with heat denatured (/sup 99m/Tc)RBCs, nine spleens were well visualized, and the uptake was homogenous. One spleen had two patchy areas of uptake. The results indicate that when splenic phagocytic function is impaired as reflected by nonvisualization of the spleen with (/sup 99m/Tc)tin colloid, it is still possible to image such a spleen with heat denatured (/sup 99m/Tc)RBCs

  15. Branched aliphatic alkanes with quaternary substituted carbon atoms in modern and ancient geologic samples.

    SciTech Connect (OSTI)

    Kenig, F.; Simons, D.-J. H.; Crich, D.; Cowen, J. P.; Ventura, G. T.; Rehbein-Khalily, T.; Brown, T. C.; Anderson, K. B.; Chemistry; Univ. of Illinois at Chicago; Univ. of Hawaii

    2003-01-01T23:59:59.000Z

    A pseudohomologous series of branched aliphatic alkanes with a quaternary substituted carbon atom (BAQCs, specifically 2,2-di-methylalkanes and 3,3- and 5,5-diethylalkanes) were identified in warm (65{sup o}C) deep-sea hydrothermal waters and Late Cretaceous black shales. 5,5-Diethylalkanes were also observed in modern and Holocene marine shelf sediments and in shales spanning the last 800 million years of the geological record. The carbon number distribution of BAQCs indicates a biological origin. These compounds were observed but not identified in previous studies of 2.0 billion- to 2.2 billion-year-old metasediments and were commonly misidentified in other sediment samples, indicating that BAQCs are widespread in the geological record. The source organisms of BAQCs are unknown, but their paleobiogeographic distribution suggests that they have an affinity for sulfides and might be nonphotosynthetic sulfide oxidizers.

  16. Spatial variations and chronologies of aliphatic hydrocarbons in Lake Michigan sediments.

    SciTech Connect (OSTI)

    Doskey, P. V.; Environmental Research

    2001-01-15T23:59:59.000Z

    Four sediment cores were collected in fine-grained depositional areas of the southern basin of Lake Michigan. Spatial variations of aliphatic hydrocarbons in surficial sediments were consistent with a lakeward movement of riverine sediments in a series of resuspension-settling cycles in which an unresolved complex mixture (UCM) of hydrocarbons associated with dense sediments is deposited in nearshore areas, fine-grained sediments of terrestrial origin accumulate in the deep basin, and planktonic hydrocarbons are depleted by microbial degradation during transport to the deep basin. The rate of accumulation of the UCM (a marker of petroleum residues) in deep basin sediments has increased by more than an order of magnitude since 1880, from 60 {mu}g m{sup -2}{center_dot}a{sup -1} to approximately 960 {mu}g m{sup -2}{center_dot}a{sup -1} in 1980. Crude estimates of the atmospheric loading of the UCM (1100 {mu}g m{sup -2}{center_dot}a{sup -1}) indicate that accumulations in deep-basin sediments might be supported by atmospheric deposition. Agreement was poor between the atmospheric flux of the terrestrial n-alkanes ({Sigma}C{sub 25}, C{sub 27}, C{sub 29}, C{sub 31}) to the deep basin (3200 {mu}g m{sup -2}{center_dot}a{sup -1}) and the sediment accumulation rate (660 {mu}g m{sup -2}{center_dot}a{sup -1}). Understanding of atmospheric fluxes, estimated from the very few available data, would be improved by more frequent measurement of the levels of aliphatic hydrocarbons in air and precipitation and a better knowledge of the particle deposition velocities and precipitation scavenging coefficients.

  17. Fuel alcohol opportunities for Indiana

    SciTech Connect (OSTI)

    Greenglass, Bert

    1980-08-01T23:59:59.000Z

    Prepared at the request of US Senator Birch Bayh, Chairman of the National Alcohol Fuels Commission, this study may be best utilized as a guidebook and resource manual to foster the development of a statewide fuel alcohol plan. It examines sectors in Indiana which will impact or be impacted upon by the fuel alcohol industry. The study describes fuel alcohol technologies that could be pertinent to Indiana and also looks closely at how such a fuel alcohol industry may affect the economic and policy development of the State. Finally, the study presents options for Indiana, taking into account the national context of the developing fuel alcohol industry which, unlike many others, will be highly decentralized and more under the control of the lifeblood of our society - the agricultural community.

  18. ORGANIC GEOCHEMICAL STUDIES. II. THE DISTRIBUTION OF ALIPHATIC HYDROCARBONS IN ALGAE, BACTERIA, AND IN A RECENT LAKE SEDIMENT: A PRELIMINARY REPORT

    E-Print Network [OSTI]

    Han, Jerry; McCarthy, E.D.; Van Hoeven Jr., William; Calvin, Melvin; Bradley, W. H.

    2008-01-01T23:59:59.000Z

    ALIPHATIC HYDROCARBONS IN ALGAE, BACTERIA, AND IN A RECENTH F A PRELIMINARY REPORT IN ALGAE, BACTERIA, AKD IN A RECENTrests on the finding that algae have less cellulose and a

  19. alcoholism: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    second, the efficacy of three psychotherapies for alcoholism in treating extreme West, Mike 237 Characterization of Catalysts for the Synthesis of Higher Alcohols using...

  20. alcoholates: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    second, the efficacy of three psychotherapies for alcoholism in treating extreme West, Mike 237 Characterization of Catalysts for the Synthesis of Higher Alcohols using...

  1. alcohols: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    second, the efficacy of three psychotherapies for alcoholism in treating extreme West, Mike 237 Characterization of Catalysts for the Synthesis of Higher Alcohols using...

  2. Interactions of chlorosulfonated polyethylene geomembranes with aliphatic esters: Sorption and diffusion phenomena

    SciTech Connect (OSTI)

    Aminabhavi, T.M.; Munnolli, R.S. [Karnatak Univ. (India). Dept. of Chemistry] [Karnatak Univ. (India). Dept. of Chemistry; Ortego, J.D. [Lamar Univ., Beaumont, TX (United States)] [Lamar Univ., Beaumont, TX (United States)

    1995-07-01T23:59:59.000Z

    The resistance of chlorosulfonated polyethylene geomembranes to nine aliphatic esters viz., methyl acetate, ethyl acetate, methyl acetoacetate, n-butyl acetate, diethyl oxalate, iso-amyl acetate, diethyl malonate, and diethyl succinate was investigated in the temperature interval 25--60 C by measuring the liquid sorption using a gravimetric method. A Fickian diffusion equation was used to calculate the diffusion coefficients, and these data were dependent on the type of ester molecules and their interactions with the geomembrane in additions to temperature and solvent concentration. The activation energy values for the diffusion process were in the range 18--41 kJ/mole and the heat of sorption varied from 0.61 to 18.50 kJ/mole. the sorption/swelling results were found to follow the first order kinetics. Solvent front velocities were calculated from the sorption data. The statistical error analysis has been presented in order to judge the reliability of the technique used. The experimental data and calculated parameters were used to discuss transport results in terms of membrane-solvent interactions. None of the esters showed any degradative effects on the geomembrane used.

  3. Alcohol fuels program technical review

    SciTech Connect (OSTI)

    none,

    1981-07-01T23:59:59.000Z

    The last issue of the Alcohol Fuels Process R/D Newsletter contained a work breakdown structure (WBS) of the SERI Alcohol Fuels Program that stressed the subcontracted portion of the program and discussed the SERI biotechnology in-house program. This issue shows the WBS for the in-house programs and contains highlights for the remaining in-house tasks, that is, methanol production research, alcohol utilization research, and membrane research. The methanol production research activity consists of two elements: development of a pressurized oxygen gasifier and synthesis of catalytic materials to more efficiently convert synthesis gas to methanol and higher alcohols. A report is included (Finegold et al. 1981) that details the experimental apparatus and recent results obtained from the gasifier. The catalysis research is principally directed toward producing novel organometallic compounds for use as a homogeneous catalyst. The utilization research is directed toward the development of novel engine systems that use pure alcohol for fuel. Reforming methanol and ethanol catalytically to produce H/sub 2/ and CO gas for use as a fuel offers performance and efficiency advantages over burning alcohol directly as fuel in an engine. An application of this approach is also detailed at the end of this section. Another area of utilization is the use of fuel cells in transportation. In-house researchers investigating alternate electrolyte systems are exploring the direct and indirect use of alcohols in fuel cells. A workshop is being organized to explore potential applications of fuel cells in the transportation sector. The membrane research group is equipping to evaluate alcohol/water separation membranes and is also establishing cost estimation and energy utilization figures for use in alcohol plant design.

  4. Modification of alkaline pulping to facilitate the isolation of aliphatic acids. Part 1. Sodium hydroxide pretreatment of pine wood

    SciTech Connect (OSTI)

    Alen, R.; Niemelae, K.; Sjoestroem, E.

    1984-01-01T23:59:59.000Z

    Pretreating pine chips (Pinus sylvestris) with sodium hydroxide prior to the alkaline delignification kraft, kraft-anthraquinone, and soda-anthraquinone) can facilitate the recovery of the carbohydrate degradation products from alkaline pulping liquors. Under suitable pretreatment conditions large amounts of carbohydrate degradation products (alipahtic acids) were formed relative to lignin. The lignin fraction was composed of comparatively low-molecular-weight fragments. Although the delignification was considerably retarded and the yield (based on wood) was decreased by 1-3%, the properties of the resulting pulp were essentially maintained despite pretreatment. Finally, data are given for the composition of aliphatic acids in liquors resulting from pretreatments.

  5. alcohol testing program: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of alcohol and drugs. 6. Describe the personality traits of the alcoholic and drug addict. 7. Describe the treatment and rehabilitation of the alcoholic and drug addict. 8....

  6. alcohols aromatic tertiary: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of alcohol and drugs. 6. Describe the personality traits of the alcoholic and drug addict. 7. Describe the treatment and rehabilitation of the alcoholic and drug addict. 8....

  7. alcoholic liver injury: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of alcohol and drugs. 6. Describe the personality traits of the alcoholic and drug addict. 7. Describe the treatment and rehabilitation of the alcoholic and drug addict. 8....

  8. alcohol preference identified: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of alcohol and drugs. 6. Describe the personality traits of the alcoholic and drug addict. 7. Describe the treatment and rehabilitation of the alcoholic and drug addict. 8....

  9. alcohol ethanol propanols: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alcohols and ethers in different alcohol-based products, e. g. in whisky, cognac, brandy, wine as well as in waste alcohol and alcohol beverage production, leads to the significant...

  10. alcohol intake alcohol: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    you are the victim of a crime on the U. One 12-ounce bottle of beer or a 5-ounce glass of wine (about a half-cup) has as much alcohol as a 1 Texas at Arlington, University of 11...

  11. Mechanisms of Fetal Alcohol Spectrum Disorders

    E-Print Network [OSTI]

    Wilson, Shannon Elizabeth

    2011-10-21T23:59:59.000Z

    MECHANISMS OF FETAL ALCOHOL SPECTRUM DISORDERS A Dissertation by SHANNON ELIZABETH WILSON Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree... of DOCTOR OF PHILOSOPHY August 2010 Major Subject: Biomedical Sciences Mechanisms of Fetal Alcohol Spectrum Disorders Copyright 2010 Shannon Elizabeth Wilson MECHANISMS OF FETAL ALCOHOL...

  12. Mapping between the order of thermal denaturation and the shape of the critical line of mechanical unzipping in 1-dimensional DNA models

    E-Print Network [OSTI]

    Buyukdagli, Sahin; 10.1016/j.cplett.2009.11.061

    2010-01-01T23:59:59.000Z

    In this Letter, we investigate the link between thermal denaturation and mechanical unzipping for two models of DNA, namely the Dauxois-Peyrard-Bishop model and a variant thereof we proposed recently. We show that the critical line that separates zipped from unzipped DNA sequences in mechanical unzipping experiments is a power-law in the temperature-force plane. We also prove that for the investigated models the corresponding critical exponent is proportional to the critical exponent alpha, which characterizes the behaviour of the specific heat in the neighbourhood of the critical temperature for thermal denaturation.

  13. Catalyst for producing lower alcohols

    DOE Patents [OSTI]

    Rathke, Jerome W. (Bolingbrook, IL); Klingler, Robert J. (Woodridge, IL); Heiberger, John J. (Glen Ellyn, IL)

    1987-01-01T23:59:59.000Z

    A process and system for the production of the lower alcohols such as methanol, ethanol and propanol involves the reaction of carbon monoxide and water in the presence of a lead salt and an alkali metal formate catalyst combination. The lead salt is present as solid particles such as lead titanate, lead molybdate, lead vanadate, lead zirconate, lead tantalate and lead silicates coated or in slurry within molten alkali metal formate. The reactants, carbon monoxide and steam are provided in gas form at relatively low pressures below 100 atmospheres and at temperatures of 200-400.degree. C. The resulted lower alcohols can be separated into boiling point fractions and recovered from the excess reactants by distillation.

  14. Acculturation, Alcohol Expectancies, and Alcohol Use Among Mexican-American Adolescents

    E-Print Network [OSTI]

    Flato, Claudia Graciela

    2011-02-22T23:59:59.000Z

    The current study was designed to examine the influence of cultural orientation on alcohol involvement among Mexican-American adolescents. Also, this study assessed whether cultural orientation predicted positive and negative alcohol expectancies...

  15. District Youth in Brief: Illegal Alcohol Sales to Minors Where Were Underage Youth Sold Alcohol During

    E-Print Network [OSTI]

    Milchberg, Howard

    District Youth in Brief: Illegal Alcohol Sales to Minors Where Were Underage Youth Sold Alcohol the wards, approximately 9 to 16% of all compliance checks resulted in an illegal sale to a minor. The ward

  16. A PROTEOMIC STUDY OF OXIDATIVE STRESS IN ALCOHOLIC LIVER DISEASE

    E-Print Network [OSTI]

    Newton, Billy W.

    2010-01-16T23:59:59.000Z

    Alcoholic steatosis (AS) is the initial pathology associated with early stage alcoholic liver disease and is characterized by the accumulation of fat in the liver. AS is considered clinically benign as it is reversible, as compared with alcoholic...

  17. alcohol assessment measures: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    offspring, collectively termed fetal alcohol children) with a diagnosis of fetal alcohol syn- drome (FAS), partial FAS (pFAS), or alcohol Munoz, Douglas Perry 4 The Trajectory of...

  18. alcohol control policies: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    23 24 25 Next Page Last Page Topic Index 1 Revised.Approved.February 2013. 1 Alcohol Policy Policy Name: Carleton University Alcohol Policy Computer Technologies and Information...

  19. alcohol pricing policies: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    23 24 25 Next Page Last Page Topic Index 1 Revised.Approved.February 2013. 1 Alcohol Policy Policy Name: Carleton University Alcohol Policy Computer Technologies and Information...

  20. alcohol carburante ii: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    second, the efficacy of three psychotherapies for alcoholism in treating extreme West, Mike 255 Characterization of Catalysts for the Synthesis of Higher Alcohols using...

  1. alcohol effects: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    second, the efficacy of three psychotherapies for alcoholism in treating extreme West, Mike 330 Characterization of Catalysts for the Synthesis of Higher Alcohols using...

  2. alcohol oxidoreductases: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    second, the efficacy of three psychotherapies for alcoholism in treating extreme West, Mike 253 Characterization of Catalysts for the Synthesis of Higher Alcohols using...

  3. alcohol exposure produces: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    second, the efficacy of three psychotherapies for alcoholism in treating extreme West, Mike 303 Characterization of Catalysts for the Synthesis of Higher Alcohols using...

  4. alcohol induced hemoglobin: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    second, the efficacy of three psychotherapies for alcoholism in treating extreme West, Mike 339 Characterization of Catalysts for the Synthesis of Higher Alcohols using...

  5. alcoholic intoxication: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    second, the efficacy of three psychotherapies for alcoholism in treating extreme West, Mike 259 Characterization of Catalysts for the Synthesis of Higher Alcohols using...

  6. alcoholic cirrhosis relations: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    second, the efficacy of three psychotherapies for alcoholism in treating extreme West, Mike 314 Characterization of Catalysts for the Synthesis of Higher Alcohols using...

  7. alcohol pendant groups: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    second, the efficacy of three psychotherapies for alcoholism in treating extreme West, Mike 331 Characterization of Catalysts for the Synthesis of Higher Alcohols using...

  8. alcohol blood tests: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    second, the efficacy of three psychotherapies for alcoholism in treating extreme West, Mike 349 Characterization of Catalysts for the Synthesis of Higher Alcohols using...

  9. alcohol dehydrogenase ii: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    second, the efficacy of three psychotherapies for alcoholism in treating extreme West, Mike 345 Characterization of Catalysts for the Synthesis of Higher Alcohols using...

  10. alcoholic liver cirrhosis: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    second, the efficacy of three psychotherapies for alcoholism in treating extreme West, Mike 348 Characterization of Catalysts for the Synthesis of Higher Alcohols using...

  11. allyl alcohols catalyzed: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    second, the efficacy of three psychotherapies for alcoholism in treating extreme West, Mike 474 Characterization of Catalysts for the Synthesis of Higher Alcohols using...

  12. alcohol acyltransferase awat: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    second, the efficacy of three psychotherapies for alcoholism in treating extreme West, Mike 248 Characterization of Catalysts for the Synthesis of Higher Alcohols using...

  13. alcoholic cirrhosis relation: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    second, the efficacy of three psychotherapies for alcoholism in treating extreme West, Mike 314 Characterization of Catalysts for the Synthesis of Higher Alcohols using...

  14. alcohols ketones alkanediols: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    second, the efficacy of three psychotherapies for alcoholism in treating extreme West, Mike 292 Characterization of Catalysts for the Synthesis of Higher Alcohols using...

  15. acetate allyl alcohol: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    second, the efficacy of three psychotherapies for alcoholism in treating extreme West, Mike 350 Characterization of Catalysts for the Synthesis of Higher Alcohols using...

  16. alcohol wipe sampling: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    second, the efficacy of three psychotherapies for alcoholism in treating extreme West, Mike 270 Characterization of Catalysts for the Synthesis of Higher Alcohols using...

  17. amyl alcohols: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    second, the efficacy of three psychotherapies for alcoholism in treating extreme West, Mike 240 Characterization of Catalysts for the Synthesis of Higher Alcohols using...

  18. atribuible al alcohol: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    second, the efficacy of three psychotherapies for alcoholism in treating extreme West, Mike 267 Characterization of Catalysts for the Synthesis of Higher Alcohols using...

  19. alcoholics attending outpatient: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    second, the efficacy of three psychotherapies for alcoholism in treating extreme West, Mike 398 Characterization of Catalysts for the Synthesis of Higher Alcohols using...

  20. alcohol tests: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    second, the efficacy of three psychotherapies for alcoholism in treating extreme West, Mike 269 Characterization of Catalysts for the Synthesis of Higher Alcohols using...

  1. allyl alcohol cyclization: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    second, the efficacy of three psychotherapies for alcoholism in treating extreme West, Mike 333 Characterization of Catalysts for the Synthesis of Higher Alcohols using...

  2. alcohol glucosides implications: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    second, the efficacy of three psychotherapies for alcoholism in treating extreme West, Mike 257 Characterization of Catalysts for the Synthesis of Higher Alcohols using...

  3. alcohol survey hablas: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    second, the efficacy of three psychotherapies for alcoholism in treating extreme West, Mike 299 Characterization of Catalysts for the Synthesis of Higher Alcohols using...

  4. alcohols aldehydes acids: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    second, the efficacy of three psychotherapies for alcoholism in treating extreme West, Mike 323 Characterization of Catalysts for the Synthesis of Higher Alcohols using...

  5. alcohol measurement methodology: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    second, the efficacy of three psychotherapies for alcoholism in treating extreme West, Mike 425 Characterization of Catalysts for the Synthesis of Higher Alcohols using...

  6. acute alcohol intoxication: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    second, the efficacy of three psychotherapies for alcoholism in treating extreme West, Mike 280 Characterization of Catalysts for the Synthesis of Higher Alcohols using...

  7. Design Case Summary: Production of Mixed Alcohols from Municipal...

    Office of Environmental Management (EM)

    Mixed Alcohols from Municipal Solid Waste via Gasification Design Case Summary: Production of Mixed Alcohols from Municipal Solid Waste via Gasification The Bioenergy Technologies...

  8. Renewable Hydrogen Production Using Sugars and Sugar Alcohols...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Using Sugars and Sugar Alcohols (Presentation) Renewable Hydrogen Production Using Sugars and Sugar Alcohols (Presentation) Presented at the 2007 Bio-Derived Liquids to Hydrogen...

  9. aqueous polyvinyl alcohol: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    fuel cell Activated carbon Separator Cathode Poly(vinyl alcohol) High for the oxygen reduction cathode catalyst and the electrode separator. A poly(vinyl alcohol) (PVA 9...

  10. alcoholic beverage hormesis: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Alcohol Defined: Any liquor (distilled spirits), beer (fermented malt beverage) or wine containing ethyl alcohol. Boise State Barrash, Warren 48 THE OHIO STATE UNIVERSITY at...

  11. alcoholic beverage preference: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Alcohol Defined: Any liquor (distilled spirits), beer (fermented malt beverage) or wine containing ethyl alcohol. Boise State Barrash, Warren 50 THE OHIO STATE UNIVERSITY at...

  12. alcoholic beverages: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Alcohol Defined: Any liquor (distilled spirits), beer (fermented malt beverage) or wine containing ethyl alcohol. Boise State Barrash, Warren 47 THE OHIO STATE UNIVERSITY at...

  13. adolescent alcohol abuse: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    consultation with the National Institute on Drug Abuse, the National Institute on Alcohol Abuse and Alcoholism, and the Health Care Financing Administration. Substance Abuse; Child...

  14. alcohol dependence patients: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (Pubmed ID 20192950) Hesselbrock MN, Chartier KG, Chan G Oliver, Douglas L. 4 Treatment of alcohol dependence CiteSeer Summary: It is important to manage alcohol withdrawal...

  15. aqueous alcohol injection: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alcohol with medicines 12;MaycauseDROW SINESS. ALCOHOL mayintensifythiseffect. USE CARE whenoperatingacar ordangerousmachinery. 1 Harmful interactions Some medicines that you...

  16. alcohol dependent patients: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (Pubmed ID 20192950) Hesselbrock MN, Chartier KG, Chan G Oliver, Douglas L. 4 Treatment of alcohol dependence CiteSeer Summary: It is important to manage alcohol withdrawal...

  17. alcohol dehydrogenase: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alcohol with medicines 12;MaycauseDROW SINESS. ALCOHOL mayintensifythiseffect. USE CARE whenoperatingacar ordangerousmachinery. 1 Harmful interactions Some medicines that you...

  18. alcohol dehydrogenase accentuates: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alcohol with medicines 12;MaycauseDROW SINESS. ALCOHOL mayintensifythiseffect. USE CARE whenoperatingacar ordangerousmachinery. 1 Harmful interactions Some medicines that you...

  19. alcohol septal myocardial: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alcohol with medicines 12;MaycauseDROW SINESS. ALCOHOL mayintensifythiseffect. USE CARE whenoperatingacar ordangerousmachinery. 1 Harmful interactions Some medicines that you...

  20. alcohol dehydrogenase accentuated: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alcohol with medicines 12;MaycauseDROW SINESS. ALCOHOL mayintensifythiseffect. USE CARE whenoperatingacar ordangerousmachinery. 1 Harmful interactions Some medicines that you...

  1. alcohol aldehyde esters: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alcohol with medicines 12;MaycauseDROW SINESS. ALCOHOL mayintensifythiseffect. USE CARE whenoperatingacar ordangerousmachinery. 1 Harmful interactions Some medicines that you...

  2. alcohol dehydrogenase fgadh: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alcohol with medicines 12;MaycauseDROW SINESS. ALCOHOL mayintensifythiseffect. USE CARE whenoperatingacar ordangerousmachinery. 1 Harmful interactions Some medicines that you...

  3. alcohol biomarker phosphatidylethanol: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alcohol with medicines 12;MaycauseDROW SINESS. ALCOHOL mayintensifythiseffect. USE CARE whenoperatingacar ordangerousmachinery. 1 Harmful interactions Some medicines that you...

  4. Studies on the mechanism of alcohol oxidase

    E-Print Network [OSTI]

    Menon, Vipin

    1994-01-01T23:59:59.000Z

    substituted ethanois as substrates has been examined using kinetic isotope effects, structure-reactivity correlations, and pH effects. Initial velocity line patterns for ethanol and bromoethanol as substrates for alcohol oxidase showed parallel lines...

  5. Microprocessor control for alcohol fuel fumigation

    SciTech Connect (OSTI)

    Walker, J.T.

    1982-11-01T23:59:59.000Z

    A microprocessor system for controlling alcohol fumigation rate was designed and applied to a diesel tractor. The system uses a single-board microprocessor system to measure throttle position and engine speed. The microprocessor, with appropriate interfaces and software, uses these inputs to control the rate at which a solenoid valve sprays alcohol into the intake tube of a diesel engine. The microprocessor system, interfaces, and software are described in this report.

  6. Third international symposium on alcohol fuels technology

    SciTech Connect (OSTI)

    none,

    1980-04-01T23:59:59.000Z

    At the opening of the Symposium, Dr. Sharrah, Senior Vice President of Continental Oil Company, addressed the attendees, and his remarks are included in this volume. The Symposium was concluded by workshops which addressed specific topics. The topical titles are as follows: alcohol uses; production; environment and safety; and socio-economic. The workshops reflected a growing confidence among the attendees that the alcohols from coal, remote natural gas and biomass do offer alternatives to petroleum fuels. Further, they may, in the long run, prove to be equal or superior to the petroleum fuels when the aspects of performance, environment, health and safety are combined with the renewable aspect of the biomass derived alcohols. Although considerable activity in the production and use of alcohols is now appearing in many parts of the world, the absence of strong, broad scale assessment and support for these fuels by the United States Federal Government was a noted point of concern by the attendees. The environmental consequence of using alcohols continues to be more benign in general than the petroleum based fuels. The exception is the family of aldehydes. Although the aldehydes are easily suppressed by catalysts, it is important to understand their production in the combustion process. Progress is being made in this regard. Of course, the goal is to burn the alcohols so cleanly that catalytic equipment can be eliminated. Separate abstracts are prepared for the Energy Data Base for individual presentations.

  7. Alcohol Services Category #1 # Permit Applica2on Category #2

    E-Print Network [OSTI]

    Powers, Robert

    Alcohol Services Category #1 # Permit Applica2on Category #2 Category #3 If an outdoor event, a;ach UNL Police approved licensed area plan to Permit Request ADMINISTRATOR TO OBTAIN THE REQUIRED ALCOHOL SERVICES PERMIT FOR EACH EVENT

  8. Mechanisms underlying fetal alcohol spectrum disorders: ovine model

    E-Print Network [OSTI]

    Ramadoss, Jayanth

    2009-05-15T23:59:59.000Z

    Maternal alcohol abuse during pregnancy can result in a range of structural and functional abnormalities that include lifelong physical, mental, behavioral and learning disabilities, now collectively termed as Fetal Alcohol Spectrum Disorders (FASD...

  9. Inductive Effect of Alkyl Chains on Alcohol Dehydration at Bridge...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Inductive Effect of Alkyl Chains on Alcohol Dehydration at Bridge-Bonded Oxygen Vacancies of TiO2(110). Inductive Effect of Alkyl Chains on Alcohol Dehydration at Bridge-Bonded...

  10. alcohol fuels provisions: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    were prepared with spray Polyvinyl alcohol a b s t r a c t Separators are used to protect cathodes from biofouling and to avoid 6 Electrooxidation of Alcohols Catalyzed by...

  11. alcohol fuels: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    were prepared with spray Polyvinyl alcohol a b s t r a c t Separators are used to protect cathodes from biofouling and to avoid 5 Electrooxidation of Alcohols Catalyzed by...

  12. Improved fermentative alcohol production. [Patent application

    DOE Patents [OSTI]

    Wilke, C.R.; Maiorella, B.L.; Blanch, H.W.; Cysewski, G.R.

    1980-11-26T23:59:59.000Z

    An improved fermentation process is described for producing alcohol which includes the combination of vacuum fermentation and vacuum distillation. Preferably, the vacuum distillation is carried out in two phases, one a fermentor proper operated at atmospheric pressure and a flash phase operated at reduced pressure with recycle of fermentation brew having a reduced alcohol content to the fermentor, using vapor recompression heating of the flash-pot recycle stream to heat the flash-pot or the distillation step, and using water load balancing (i.e., the molar ratio of water in the fermentor feed is the same as the molar ratio of water in the distillation overhead).

  13. RESIDENCE ALCOHOL POLICY Residence students are expected to use alcohol responsibly and to follow the University Alcohol

    E-Print Network [OSTI]

    of a student's room must be in personalized plastic containers or cans. Students who wish to transport open alcohol within the residence may do so only in a covered personalized plastic container. Cases of beer are not considered personalized containers and therefore are not permitted for consumption in common areas. Unopened

  14. alcoholic pancreatitis lessons: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... 6 Recognizing an alcohol problem ... 8 Guidelines for family and friends Tullos, Desiree 56 Planning Effective Lessons Unit...

  15. Alcohol synthesis from CO or CO.sub.2

    DOE Patents [OSTI]

    Hu, Jianli [Kennewick, WA; Dagle, Robert A [Richland, WA; Holladay, Jamelyn D [Kennewick, WA; Cao, Chunshe [Houston, TX; Wang, Yong [Richland, WA; White, James F [Richland, WA; Elliott, Douglas C [Richland, WA; Stevens, Don J [Richland, WA

    2010-12-28T23:59:59.000Z

    Methods for producing alcohols from CO or CO.sub.2 and H.sub.2 utilizing a palladium-zinc on alumina catalyst are described. Methods of synthesizing alcohols over various catalysts in microchannels are also described. Ethanol, higher alcohols, and other C.sub.2+ oxygenates can produced utilizing Rh--Mn or a Fisher-Tropsch catalyst.

  16. When alcohol-dependent people try to stop drink-

    E-Print Network [OSTI]

    Baker, Chris I.

    some form of treatment. If you or someone you care about may have an alcohol problem, help is available--so they may drink some more, and it becomes a vicious cycle. "Addiction has 3 major problems: You lose your researcher studying new alcoholism treatments. "People develop an alcohol disorder National Institutes

  17. AUTHORIZATION TO PURCHASE ALCOHOL Please provide the following information each time alcohol is ordered.

    E-Print Network [OSTI]

    Weiblen, George D

    : ___________________________________________________________________________ __________________________________________________________________________________________ Order Quantity __________ __________ __________ __________ __________ Stock # CX20442 CX20445 CX20460 CX20457 CX20461 Units Pint Gallon 5 Gallon Gallon 5 Gallon Description 200 Proof Ethyl Alcohol (Case of 24

  18. IDENTIFYING HEALTHY ALCOHOL CUSTOMS: A CULTURAL ANALYSIS COMPARING THE ITALIAN AND AMERICAN ALCOHOL CULTURES

    E-Print Network [OSTI]

    Williams, Cindy 1989-

    2011-08-15T23:59:59.000Z

    indicating Italy‘s ability to limit the probability for unhealthy drinking habits that lead to issues such as drunkenness or alcoholism. Comparison of these data prompted this research. The research aims to highlight the underlying cultural values that lead...

  19. Pervaporation separation of aqueous alcohol solution through asymmetric polycarbonate membrane

    SciTech Connect (OSTI)

    Lee, K.R.; Liu, M.J.; Lai, J.Y. (Chung Yuan Univ., Chung Li (Taiwan, Province of China))

    1994-01-01T23:59:59.000Z

    In the present work the separation of aqueous alcohol mixtures through wet-phase inversion prepared polycarbonate membranes was studied by using the pervaporation process. The formation of asymmetric pervaporation membranes was discussed in terms of the presence of a nonsolvent in the casting solution, the polycarbonate concentration, and the kinds of coagulation media. The effects of feed composition, swelling degree, and the size of the alcohols on the pervaporation performances were investigated. The rate of liquid-liquid demixing increases with a decreasing number of carbon atoms of the alcohol coagulation medium. The permeation rate of the pervaporation process for the nonsolvent-added membrane was much higher than that of the membrane without nonsolvent additive. In binary alcohol mixtures, the permselectivities of small-sized alcohols through the asymmetric membrane are decided by two factors: preferential solubility of larger-sized alcohol and predominant diffusivity of small-sized alcohol. 19 refs., 8 figs., 6 tabs.

  20. Alcohol, Drugs, and Accident Prevention (RC-371/-571) Course Description The role of alcohol and drugs and their relationship to accident causation will be examined. The problem

    E-Print Network [OSTI]

    Wu, Mingshen

    Alcohol, Drugs, and Accident Prevention (RC-371/-571) Course Description The role of alcohol and drugs and their relationship to accident causation will be examined. The problem of alcoholism and drug

  1. Limonene and tetrahydrofurfurly alcohol cleaning agent

    DOE Patents [OSTI]

    Bohnert, George W. (Harrisonville, MO); Carter, Richard D. (Lee's Summit, MO); Hand, Thomas E. (Lee's Summit, MO); Powers, Michael T. (Santa Rosa, CA)

    1997-10-21T23:59:59.000Z

    The present invention is a tetrahydrofurfuryl alcohol and limonene cleaning agent and method for formulating and/or using the cleaning agent. This cleaning agent effectively removes both polar and nonpolar contaminants from various electrical and mechanical parts and is readily used without surfactants, thereby reducing the need for additional cleaning operations. The cleaning agent is warm water rinsable without the use of surfactants. The cleaning agent can be azeotropic, enhancing ease of use in cleaning operations and ease of recycling.

  2. Limonene and tetrahydrofurfuryl alcohol cleaning agent

    DOE Patents [OSTI]

    Bohnert, G.W.; Carter, R.D.; Hand, T.E.; Powers, M.T.

    1996-05-07T23:59:59.000Z

    The present invention is a tetrahydrofurfuryl alcohol and limonene or terpineol cleaning agent and method for formulating and/or using the cleaning agent. This cleaning agent effectively removes both polar and nonpolar contaminants from various electrical and mechanical parts and is readily used without surfactants, thereby reducing the need for additional cleaning operations. The cleaning agent is warm water rinsable without the use of surfactants. The cleaning agent can be azeotropic, enhancing ease of use in cleaning operations and ease of recycling.

  3. Limonene and tetrahydrofurfuryl alcohol cleaning agent

    DOE Patents [OSTI]

    Bohnert, G.W.; Carter, R.D.; Hand, T.E.; Powers, M.T.

    1997-10-21T23:59:59.000Z

    The present invention is a tetrahydrofurfuryl alcohol and limonene cleaning agent and method for formulating and/or using the cleaning agent. This cleaning agent effectively removes both polar and nonpolar contaminants from various electrical and mechanical parts and is readily used without surfactants, thereby reducing the need for additional cleaning operations. The cleaning agent is warm water rinsable without the use of surfactants. The cleaning agent can be azeotropic, enhancing ease of use in cleaning operations and ease of recycling.

  4. Catalyst Activity Comparison of Alcohols over Zeolites

    SciTech Connect (OSTI)

    Ramasamy, Karthikeyan K.; Wang, Yong

    2013-01-01T23:59:59.000Z

    Alcohol transformation to transportation fuel range hydrocarbon on HZSM-5 (SiO2 / Al2O3 = 30) catalyst was studied at 360oC and 300psig. Product distributions and catalyst life were compared using methanol, ethanol, 1-propanol or 1-butanol as a feed. The catalyst life for 1-propanol and 1-butanol was more than double compared to that for methanol and ethanol. For all the alcohols studied, the product distributions (classified to paraffin, olefin, napthene, aromatic and naphthalene compounds) varied with time on stream (TOS). At 24 hours TOS, liquid product from 1-propanol and 1-butanol transformation primarily contains higher olefin compounds. The alcohol transformation process to higher hydrocarbon involves a complex set of reaction pathways such as dehydration, oligomerization, dehydrocyclization, and hydrogenation. Compared to ethylene generated from methanol and ethanol, oligomerization of propylene and butylene has a lower activation energy and can readily take place on weaker acidic sites. On the other hand, dehydrocyclization of propylene and butylene to form the cyclic compounds requires the sits with stronger acid strength. Combination of the above mentioned reasons are the primary reasons for olefin rich product generated in the later stage of the time on stream and for the extended catalyst life time for 1 propanol and 1 butanol compared to methanol and ethanol conversion over HZSM-5.

  5. Separation and concentration of lower alcohols from dilute aqueous solutions

    DOE Patents [OSTI]

    Moore, Raymond H. (Richland, WA); Eakin, David E. (Kennewick, WA); Baker, Eddie G. (Richland, WA); Hallen, Richard T. (Richland, WA)

    1991-01-01T23:59:59.000Z

    A process for producing, from a dilute aqueous solution of a lower (C.sub.1 -C.sub.5) alcohol, a concentrated liquid solution of the alcohol in an aromatic organic solvent is disclosed. Most of the water is removed from the dilute aqueous solution of alcohol by chilling sufficiently to form ice crystals. Simultaneously, the remaining liquid is extracted at substantially the same low temperature with a liquid organic solvent that is substantially immiscible in aqueous liquids and has an affinity for the alcohol at that temperature, causing the alcohol to transfer to the organic phase. After separating the organic liquid from the ice crystals, the organic liquid can be distilled to enrich the concentration of alcohol therein. Ethanol so separated from water and concentrated in an organic solvent such as toluene is useful as an anti-knock additive for gasoline.

  6. Roles of Acetone and Diacetone Alcohol in Coordination and Dissociatio...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    can form stable complexes, but that the effective number of atoms coordinating with uranium in the equatorial plane does not exceed five. Diacetone alcohol ligands are shown...

  7. alcohol randomized controlled: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Anne; Sweeting, Michael; Touquet, Robin; Tyrer, Peter; Ward, Helen; Crawford, Mike J 2012-08-25 2 ALCOHOL CiteSeer Summary: Excess drinking is associated with lost...

  8. adolescent alcohol problems: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ORIENTATION AND SOCIAL PERCEPTION OF AN ALCOHOLIC POPULATION A Thesis by ROBERT MILLARD SHAN Submitted to the Graduate College of Texas ASM University in partial...

  9. alcohol drinking patterns: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Brief Intervention and Referral Treatment ( 2013-01-01 20 Symposium: Drink and the Life Cycle Mathematics Websites Summary: and Alcohol in Ancient Rome." Ruth Cherrington...

  10. alcohol abuse: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    RESEARCH EDUCATION PROJECT GRANTS (R25) Funding Opportunity Number: PAR -11-205. CFDA Number(s) 93.273. Engineering Websites Summary: Grant Title: ALCOHOL RESEARCH EDUCATION...

  11. alcohol industries case: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    documents. The search was conducted by entering alcohol-related terms into search fields of tobacco document archive sites available on the World Wide Web RESULTS: Key...

  12. Cold-Start Performance and Emissions Behavior of Alcohol Fuels...

    Broader source: Energy.gov (indexed) [DOE]

    Emissions Behavior of Alcohol Fuels in an SIDI Engine Using Transient Hardware-In-Loop Test Methods Andrew Ickes & Thomas Wallner Argonne National Laboratory 17 th Directions in...

  13. alcohol aldehyde acetals: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    . Open Access Theses and Dissertations Summary: ??Liver alcohol dehydrogenase oxidizes ethanol to acetaldehyde, which is further oxidized to acetate by aldehyde dehydrogenase-2...

  14. alcohol dehydrogenase effects: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Indianapolis (IUPUI) Alcohol dehydrogenase (ADH) genes encode proteins that metabolize ethanol to acetaldehyde. Humans have seven ADH genes in a cluster. The (more) Pochareddy,...

  15. alcohol ingestion exacerbates: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    25 Next Page Last Page Topic Index 1 Alcoholism and Strongyloides stercoralis: Daily Ethanol Ingestion Has a Positive Correlation with the Frequency of Strongyloides Larvae in...

  16. alcohols aldehydes acetals: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    . Open Access Theses and Dissertations Summary: ??Liver alcohol dehydrogenase oxidizes ethanol to acetaldehyde, which is further oxidized to acetate by aldehyde dehydrogenase-2...

  17. alcohols catalyst names: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    here: Write your TA's name here Mathematics Websites Summary: ), alcohol, tobacco, firearms, explosives, a calculator, other students' tests, anything that has headphones 20 7...

  18. alcohol treatment service: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Background: Alcohol consumption, current injecting drug use, and pre-existing mental illness have been identified as 3 of the main reasons for excluding patients from...

  19. alcohol outcome expectancies: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Background: Alcohol consumption, current injecting drug use, and pre-existing mental illness have been identified as 3 of the main reasons for excluding patients from...

  20. Minimally refined biomass fuel. [carbohydrate-water-alcohol mixture

    SciTech Connect (OSTI)

    Pearson, R.K.; Hirschfeld, T.B.

    1981-03-26T23:59:59.000Z

    A minimally refined fluid composition, suitable as a fuel mixture and derived from biomass material, is comprised of one or more water-soluble carbohydrates such as sucrose, one or more alcohols having less than four carbons, and water. The carbohydrate provides the fuel source; water-solubilizes the carbohydrate; and the alcohol aids in the combustion of the carbohydrate and reduces the viscosity of the carbohydrate/water solution. Because less energy is required to obtain the carbohydrate from the raw biomass than alcohol, an overall energy savings is realized compared to fuels employing alcohol as the primary fuel.

  1. alcoholic beverage consumption: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Email: Date of Event: Event Title: Alcohol Service: Begin Time: End Time: Check here if wine to encourage members of the University community to make responsible decisions about...

  2. alcohol consumption taqib: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Websites Summary: Ancient history of sexual arousal and alcohol For if a man drink wine to drunkenness, he disturbeth from heaven to earth. Clement of Alexandria, 2nd...

  3. alcohol exposed pregnancies: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and health practices in pregnancy.Depression Other diagnosed mental illness Substance Abuse Cigarettes Alcohol Cocaine Heroin Methamphetamine Non-use in pregnancydepression...

  4. alcohol abuse patients: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    treatment outcomes of older adults versus middle-aged and younger adults in a managed care program University of California eScholarship Repository Summary: alcohol use...

  5. alcohol metabolite depends: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Constitutive Nuclear Factor-KB Pathway Biology and Medicine Websites Summary: alcohol treatment are not well studied. Here, we investigated whether the monoterpenes can regu- late...

  6. alcohol dependence severity: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Constitutive Nuclear Factor-KB Pathway Biology and Medicine Websites Summary: alcohol treatment are not well studied. Here, we investigated whether the monoterpenes can regu- late...

  7. alcohol amnestic disorder: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    treatment outcomes of older adults versus middle-aged and younger adults in a managed care program University of California eScholarship Repository Summary: alcohol use...

  8. alcohol dependent hepatocyte: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Constitutive Nuclear Factor-KB Pathway Biology and Medicine Websites Summary: alcohol treatment are not well studied. Here, we investigated whether the monoterpenes can regu- late...

  9. alcohol dependence results: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Constitutive Nuclear Factor-KB Pathway Biology and Medicine Websites Summary: alcohol treatment are not well studied. Here, we investigated whether the monoterpenes can regu- late...

  10. alcohol dependence schizophrenia: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Constitutive Nuclear Factor-KB Pathway Biology and Medicine Websites Summary: alcohol treatment are not well studied. Here, we investigated whether the monoterpenes can regu- late...

  11. alcohol dependence increases: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Constitutive Nuclear Factor-KB Pathway Biology and Medicine Websites Summary: alcohol treatment are not well studied. Here, we investigated whether the monoterpenes can regu- late...

  12. alcohol dependence implicates: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Constitutive Nuclear Factor-KB Pathway Biology and Medicine Websites Summary: alcohol treatment are not well studied. Here, we investigated whether the monoterpenes can regu- late...

  13. Thermochemical Ethanol via Indirect Gasification and Mixed Alcohol...

    Energy Savers [EERE]

    and Mixed Alcohol Synthesis of Lignocellulosic Biomass More Documents & Publications Syngas Upgrading to Hydrocarbon Fuels Technology Pathway Design Case Summary: Production of...

  14. Factor structure analysis of the Comprehensive Effects of Alcohol - Spanish questionnaire among adolescents in Mexico

    E-Print Network [OSTI]

    Flato, Claudia Graciela

    2007-09-17T23:59:59.000Z

    Expectancies about the effects of alcohol predict alcohol consumption among adolescent children. Although alcohol-expectancy measures have been validated to use with English speaking populations, there is currently no available information...

  15. Effects of Maternal L-glutamine Supplementation on Fetus to Mitigate Teratogenic Effects of Alcohol

    E-Print Network [OSTI]

    Sawant, Onkar Balkrishna

    2013-12-05T23:59:59.000Z

    Women who drink alcohol during pregnancy are at high risk of giving birth to children with physical, behavioral or cognitive developmental problems called Fetal Alcohol Spectrum Disorders (FASD). Prenatal alcohol exposure is known to be associated...

  16. Liver proteomics in progressive alcoholic steatosis

    SciTech Connect (OSTI)

    Fernando, Harshica [Department of Pathology, The University of Texas Medical Branch, Galveston, TX 77555 (United States)] [Department of Pathology, The University of Texas Medical Branch, Galveston, TX 77555 (United States); Wiktorowicz, John E.; Soman, Kizhake V. [Department of Biochemistry and Molecular Biology, The University of Texas Medical Branch, Galveston, TX 77555 (United States)] [Department of Biochemistry and Molecular Biology, The University of Texas Medical Branch, Galveston, TX 77555 (United States); Kaphalia, Bhupendra S.; Khan, M. Firoze [Department of Pathology, The University of Texas Medical Branch, Galveston, TX 77555 (United States)] [Department of Pathology, The University of Texas Medical Branch, Galveston, TX 77555 (United States); Shakeel Ansari, G.A., E-mail: sansari@utmb.edu [Department of Pathology, The University of Texas Medical Branch, Galveston, TX 77555 (United States)

    2013-02-01T23:59:59.000Z

    Fatty liver is an early stage of alcoholic and nonalcoholic liver disease (ALD and NALD) that progresses to steatohepatitis and other irreversible conditions. In this study, we identified proteins that were differentially expressed in the livers of rats fed 5% ethanol in a Lieber–DeCarli diet daily for 1 and 3 months by discovery proteomics (two-dimensional gel electrophoresis and mass spectrometry) and non-parametric modeling (Multivariate Adaptive Regression Splines). Hepatic fatty infiltration was significantly higher in ethanol-fed animals as compared to controls, and more pronounced at 3 months of ethanol feeding. Discovery proteomics identified changes in the expression of proteins involved in alcohol, lipid, and amino acid metabolism after ethanol feeding. At 1 and 3 months, 12 and 15 different proteins were differentially expressed. Of the identified proteins, down regulation of alcohol dehydrogenase (? 1.6) at 1 month and up regulation of aldehyde dehydrogenase (2.1) at 3 months could be a protective/adaptive mechanism against ethanol toxicity. In addition, betaine-homocysteine S-methyltransferase 2 a protein responsible for methionine metabolism and previously implicated in fatty liver development was significantly up regulated (1.4) at ethanol-induced fatty liver stage (1 month) while peroxiredoxin-1 was down regulated (? 1.5) at late fatty liver stage (3 months). Nonparametric analysis of the protein spots yielded fewer proteins and narrowed the list of possible markers and identified D-dopachrome tautomerase (? 1.7, at 3 months) as a possible marker for ethanol-induced early steatohepatitis. The observed differential regulation of proteins have potential to serve as biomarker signature for the detection of steatosis and its progression to steatohepatitis once validated in plasma/serum. -- Graphical abstract: The figure shows the Hierarchial cluster analysis of differentially expressed protein spots obtained after ethanol feeding for 1 (1–3) and 3 (4–6) months. C and E represent pair-fed control and ethanol-fed rats, respectively. Highlights: ? Proteins related to ethanol-induced steatosis and mild steatohepatitis are identified. ? ADH1C and ALDH2 involved in alcohol metabolism are differentially expressed at 1 and 3 months. ? Discovery proteomics identified a group of proteins to serve as potential biomarkers. ? Using nonparametric analysis DDT is identified as a possible marker for liver damage.

  17. alcohols structure-activity relationship: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    second, the efficacy of three psychotherapies for alcoholism in treating extreme West, Mike 317 Characterization of Catalysts for the Synthesis of Higher Alcohols using...

  18. alcohol induced region-dependent: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    second, the efficacy of three psychotherapies for alcoholism in treating extreme West, Mike 263 Characterization of Catalysts for the Synthesis of Higher Alcohols using...

  19. alcohol synthesis cu-co: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    second, the efficacy of three psychotherapies for alcoholism in treating extreme West, Mike 278 PROCEDURES FOR LEHIGH UNIVERSITY SPONSORED EVENTS WHERE ALCOHOLIC BEVERAGES ARE...

  20. alcohol synthesis cu-co-cr: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    second, the efficacy of three psychotherapies for alcoholism in treating extreme West, Mike 272 PROCEDURES FOR LEHIGH UNIVERSITY SPONSORED EVENTS WHERE ALCOHOLIC BEVERAGES ARE...

  1. Process for producing fuel grade ethanol by continuous fermentation, solvent extraction and alcohol separation

    DOE Patents [OSTI]

    Tedder, Daniel W. (Marietta, GA)

    1985-05-14T23:59:59.000Z

    Alcohol substantially free of water is prepared by continuously fermenting a fermentable biomass feedstock in a fermentation unit, thereby forming an aqueous fermentation liquor containing alcohol and microorganisms. Continuously extracting a portion of alcohol from said fermentation liquor with an organic solvent system containing an extractant for said alcohol, thereby forming an alcohol-organic solvent extract phase and an aqueous raffinate. Said alcohol is separated from said alcohol-organic solvent phase. A raffinate comprising microorganisms and unextracted alcohol is returned to the fermentation unit.

  2. alcohol dependence-a review: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alcohol with medicines 12;MaycauseDROW SINESS. ALCOHOL mayintensifythiseffect. USE CARE whenoperatingacar ordangerousmachinery. 1 Harmful interactions Some medicines that you...

  3. alcohol abstinence-a randomized: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alcohol with medicines 12;MaycauseDROW SINESS. ALCOHOL mayintensifythiseffect. USE CARE whenoperatingacar ordangerousmachinery. 1 Harmful interactions Some medicines that you...

  4. Alcohol Services Category #1 # Permit Application Category #2

    E-Print Network [OSTI]

    Powers, Robert

    Alcohol Services Category #1 # Permit Application Category #2 Category #3 Facility to be Used If an outdoor event, attach UNL Police approved licensed area plan to Permit Request. This individual may TO OBTAIN THE REQUIRED ALCOHOL SERVICES PERMIT FOR EACH EVENT. THE APPROVED CATERER IS RESPONSIBLE

  5. Office of Alcohol Fuels Program plan, FY 1981

    SciTech Connect (OSTI)

    None

    1980-10-01T23:59:59.000Z

    The goal of the Office of Alcohol Fuels is to promote the production, distribution, and use of alcohol fuels. The program objectives are defined and the strategy for implementation is described. An organizational model of the operation is included. The roles of the 3 program offices and various field offices are described. (DMC)

  6. The effects of adult-onset alcoholism on cortical bone

    E-Print Network [OSTI]

    Moe, Atha Louise

    2001-01-01T23:59:59.000Z

    -fed liquid control diet or rat pellet chow for either 8 or 14 weeks. An additional group of animals (alcohol cessation and pair-fed cessation) was fed the alcohol diet for 8 weeks with pair-fed partners receiving the liquid control diet. These animals were...

  7. Alcohol Fuel Cells at Optimal Temperatures Tetsuya Uda,a

    E-Print Network [OSTI]

    Alcohol Fuel Cells at Optimal Temperatures Tetsuya Uda,a Dane A. Boysen,b Calum R. I. Chisholm of operation, 250°C, is matched both to the optimal value for fuel cell power output and for reforming. Peak, California 91125, USA High-power-density alcohol fuel cells can relieve many of the daunting challenges

  8. Corynebacterium nuruki sp. nov., isolated from an alcohol fermentation starter

    E-Print Network [OSTI]

    Bae, Jin-Woo

    were meso-diaminopimelic acid, alanine, glycine and glutamic acid. The strain contained mycolic acidsCorynebacterium nuruki sp. nov., isolated from an alcohol fermentation starter Na-Ri Shin, Mi , was isolated from a Korean alcohol fermentation starter. Optimal growth occurred at 37 6C, at pH 8 and in 1

  9. Control substances and alcohol use and testing

    SciTech Connect (OSTI)

    Przybylski, J.L.

    1994-07-01T23:59:59.000Z

    The Omnibus Transportation Employee Testing Act was signed into law in October of 1991. The Omnibus Transportation Employee Testing Act of 1991 required the United States Department of Transportation (DOT) to enact regulations requiring the testing of employees that perform ``safety sensitive functions`` for illegal controlled substance use and alcohol misuse. The Transportation Management Division, Office of Environmental Restoration and Waste Management (TMD/EM-261), United States Department of Energy (DOE), Training Program Manager is committed to promoting the availability of the necessary information to those affected members of the Department of Energy (DOE) community in an effort to attain the highest possible level of regulatory compliance and to enhance the safety of each individual in the workplace.

  10. The Fusion Curve of Ammonia and Ethyl Alcohol

    E-Print Network [OSTI]

    Broderson, H.J.

    1911-01-01T23:59:59.000Z

    ’ Center for Digital Scholarship. http://kuscholarworks.ku.edu Submitted to the Graduate School of the University of Kansas for partial completion of Master of Arts. THE FUSION CURVE OF AMMONIA AND ETHYL ALCOHOL H. J. BRODERSON THE 2?03IOH CUHVB OP... AMMOHIA AND ETHXL ALCOHOL. A part of the requirement for the lh A. 2)egree. By K. J. Brodereon, University of Kangaa, May 1911, THE PUSIOB CURVS OP AliKOHlA AHD ETHYL ALCOHOL* Only within tho last fow ycara has any worlc boon done on tho fusion...

  11. Extracting alcohols from aqueous solutions. [USDOE patent application

    DOE Patents [OSTI]

    Compere, A.L.; Googin, J.M.; Griffith, W.L.

    1981-12-02T23:59:59.000Z

    The objective is to provide an efficient process for extracting alcohols in aqueous solutions into hydrocarbon fuel mixtures, such as gasoline, diesel fuel and fuel oil. This is done by contacting an aqueous fermentation liquor with a hydrocarbon or hydrocarbon mixture containing carbon compounds having 5-18 carbon atoms, which may include gasoline, diesel fuel or fuel oil. The hydrocarbon-aqueous alcohol solution is then mixed with one or more of a group of polyoxyalkylene polymers to extract the alcohol into the hydrocarbon fuel-polyoxyalkylene polymer mixture.

  12. Oxidation, Reduction, and Condensation of Alcohols over (MO3...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Alcohols over (MO3)3 (MMo, W) Nanoclusters . Abstract: The reactions of deuterated methanol, ethanol, 1-propanol, 1-butanol, 2-propanol, 2-butanol and t-butanol over cyclic...

  13. alcohol oxidation level: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    second, the efficacy of three psychotherapies for alcoholism in treating extreme West, Mike First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23...

  14. Method for producing hydrocarbon and alcohol mixtures. [Patent application

    DOE Patents [OSTI]

    Compere, A.L.; Googin, J.M.; Griffith, W.L.

    1980-12-01T23:59:59.000Z

    It is an object of this invention to provide an efficient process for extracting alcohols and ketones from an aqueous solution containing the same into hydrocarbon fuel mixtures, such as gasoline, diesel fuel and fuel oil. Another object of the invention is to provide a mixture consisting of hydrocarbon, alcohols or ketones, polyoxyalkylene polymer and water which can be directly added to fuels or further purified. The above stated objects are achieved in accordance with a preferred embodiment of the invention by contacting an aqueous fermentation liquor with a hydrocarbon or hydrocarbon mixture containing carbon compounds having 5 to 18 carbon atoms, which may include gasoline, diesel fuel or fuel oil. The hydrocarbon-aqueous alcohol solution is mixed in the presence or one or more of a group of polyoxyalkylene polymers described in detail hereinafter; the fermentation alcohol being extracted into the hydrocarbon fuel-polyoxyalkylene polymer mixture.

  15. Detection of Physiologically Relevant Alcohol Concentrations Using Raman Spectroscopy

    E-Print Network [OSTI]

    McKay, Joshua L.

    2006-08-16T23:59:59.000Z

    This is the first step in a series of studies to test the feasibility of using Raman Spectroscopy (RS) to non-invasively detect physiologically relevant blood alcohol concentrations. Blood tests, urine tests, and the breathalyzer are currently...

  16. Examining college students' beliefs and behaviors regarding responsible alcohol consumption

    E-Print Network [OSTI]

    Barry, Adam Etheridge

    2009-05-15T23:59:59.000Z

    discussing: (a) the origins and evolution of this message, (b) alcohol product advertisements evincing a responsible drinking prevention message, and (c) practical and ethical concerns associated with brewer-sponsored responsible drinking campaigns...

  17. The effects of alcohol and aspirin on neonatal brain development

    E-Print Network [OSTI]

    Beshear, Myra Dawn

    2013-02-22T23:59:59.000Z

    This study focuses on the effects of alcohol and aspirin on brain development in the neonatal rat. The period of brain development of particular interest is known as the brain growth spurt. Previous studies have shown that the developing brain...

  18. HD Applications of Significantly Downsized SI Engines Using Alcohol...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Using Alcohol DI for Knock Avoidance Direct injection of a second fuel (ethanol or methanol) is explored as a means of avoiding knock in turbocharged, high-compression ratio...

  19. New diversification strategies for the Japanese alcohol industry

    E-Print Network [OSTI]

    Yoshimura, Toru, M.B.A. Massachusetts Institute of Technology

    2007-01-01T23:59:59.000Z

    Japanese major alcoholic beverage companies, whose businesses are mainly the production and sale of beer products, stand at a strategic crossroads. There are several reasons: a slow decrease in the Japanese population, ...

  20. alcohol composite films: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    or reduce the world's dependence on fossil fuels. The continued development of thin-film solid ... Liu, David ShinRen 2014-01-01 92 RESIDENCE ALCOHOL POLICY Residence students...

  1. Alcohol, Tobacco, and Other Drug Use in Illinois: Prevalence

    E-Print Network [OSTI]

    Illinois at Chicago, University of

    Assessment Program. Rod R. Blagojevich, Governor #12;#12;Alcohol, Tobacco, and Other Drug Use in Illinois by the federal Office of Management and Budget. Theodora Binion-Taylor, Associate Director 100 West Randolph

  2. alcohol screening day: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    a drink*. Swinburne and SSAA suppport responsible service of alcohol. Lecture Theatre FBE - EN103 to make the most of the O-Week energy on campus too - and will invite you to...

  3. alcohol problem services: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    a drink*. Swinburne and SSAA suppport responsible service of alcohol. Lecture Theatre FBE - EN103 to make the most of the O-Week energy on campus too - and will invite you to...

  4. alcohol require mglu5: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    a drink*. Swinburne and SSAA suppport responsible service of alcohol. Lecture Theatre FBE - EN103 to make the most of the O-Week energy on campus too - and will invite you to...

  5. alcohol abuse road: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in relation to the use and abuse of alcohol. These groups cite the escalating costs of abuse with time; that the initial Christian response of care and compassion was eventually...

  6. alcohol abuse associations: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in relation to the use and abuse of alcohol. These groups cite the escalating costs of abuse with time; that the initial Christian response of care and compassion was eventually...

  7. alcohol abuse model: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in relation to the use and abuse of alcohol. These groups cite the escalating costs of abuse with time; that the initial Christian response of care and compassion was eventually...

  8. alcohol abuse measurement: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in relation to the use and abuse of alcohol. These groups cite the escalating costs of abuse with time; that the initial Christian response of care and compassion was eventually...

  9. alcohol abusing runaway: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in relation to the use and abuse of alcohol. These groups cite the escalating costs of abuse with time; that the initial Christian response of care and compassion was eventually...

  10. alcohol abuse case: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in relation to the use and abuse of alcohol. These groups cite the escalating costs of abuse with time; that the initial Christian response of care and compassion was eventually...

  11. alcohol abuse related: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in relation to the use and abuse of alcohol. These groups cite the escalating costs of abuse with time; that the initial Christian response of care and compassion was eventually...

  12. alcohol abusers compared: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in relation to the use and abuse of alcohol. These groups cite the escalating costs of abuse with time; that the initial Christian response of care and compassion was eventually...

  13. alcohol concentration induces: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    year. Fifteen percent of this amount is the cost of medical consequences and alcohol treatment; more than 70 percent is due to reduced, lost and forgone earnings; and the...

  14. alcoholic liver diseases: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    year. Fifteen percent of this amount is the cost of medical consequences and alcohol treatment; more than 70 percent is due to reduced, lost and forgone earnings; and the...

  15. alcoholic liver disease: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    year. Fifteen percent of this amount is the cost of medical consequences and alcohol treatment; more than 70 percent is due to reduced, lost and forgone earnings; and the...

  16. Cold-Start Performance and Emissions Behavior of Alcohol Fuels...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    tests using gasoline and 3 alcohol-gasoline blends (50% and 85% ethanol, and 83% iso-butanol) deer11ickes.pdf More Documents & Publications Impact of ethanol and butanol...

  17. The relationship between alcohol consumption and sexual activity

    E-Print Network [OSTI]

    Theis-Cole, Deborah Elaine

    1992-01-01T23:59:59.000Z

    THE RELATIONSHIP BETWEEN ALCOHOL CONSUMPTION AND SEXUAL ACTIVITY A Thesis By DEBORAH ELAINE THEIS-COLE Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER... OF SCIENCE August 1992 Major Subject: Educational Psychology THE RELATIONSHIP BETWEEN ALCOHOL CONSUMPTION AND SEXUAL ACTIVITY A Thesis By Deborah Elaine Theis-Cole Approved as to style and content by: Arthur . Roach (Chair of Committee) Maurice E...

  18. Control orientation and social perception of an alcoholic population

    E-Print Network [OSTI]

    Shaw, Robert Millard

    1975-01-01T23:59:59.000Z

    CONTROL ORIENTATION AND SOCIAL PERCEPTION OF AN ALCOHOLIC POPULATION A Thesis by ROBERT MILLARD SHAN Submitted to the Graduate College of Texas ASM University in partial fulfil'1ment of the requirement for the degree of MASTER OF SCIENCE... 1975 Major Subject: Psychology CONTROL ORIENTATION AND SOCIAL PERCEPTION OF AN ALCOHOLIC POPULATION A Thesis by ROBERT MILLARO SHAW Approved as to style and content by: (Chairman of Committee) (Member) Head of partment I er (Member) May...

  19. Alcohol Use Policy The possession, sale or furnishing of alcohol on the University campus is governed by OSU

    E-Print Network [OSTI]

    Escher, Christine

    to University disciplinary action, criminal prosecution, fine and imprisonment. It is unlawful to sell, furnish for anyone to consume or possess alcohol in any public or private area of campus without prior University

  20. Method of forming a dianhydrosugar alcohol

    DOE Patents [OSTI]

    Holladay, Johnathan E. (Kennewick, WA); Hu, Jianli (Kennewick, WA); Wang, Yong (Richland, WA); Werpy, Todd A. (West Richland, WA); Zhang, Xinjie (Burlington, MA)

    2010-01-19T23:59:59.000Z

    The invention includes methods of producing dianhydrosugars. A polyol is reacted in the presence of a first catalyst to form a monocyclic sugar. The monocyclic sugar is transferred to a second reactor where it is converted to a dianhydrosugar alcohol in the presence of a second catalyst. The invention includes a process of forming isosorbide. An initial reaction is conducted at a first temperature in the presence of a solid acid catalyst. The initial reaction involves reacting sorbitol to produce 1,4-sorbitan, 3,6-sorbitan, 2,5-mannitan and 2,5-iditan. Utilizing a second temperature, the 1,4-sorbitan and 3,6-sorbitan are converted to isosorbide. The invention includes a method of purifying isosorbide from a mixture containing isosorbide and at least one additional component. A first distillation removes a first portion of the isosorbide from the mixture. A second distillation is then conducted at a higher temperature to remove a second portion of isosorbide from the mixture.

  1. Alcohol production from agricultural and forestry residues

    SciTech Connect (OSTI)

    Dale, L; Opilla, R; Surles, T

    1980-09-01T23:59:59.000Z

    Technologies available for the production of ethanol from whole corn are reviewed. Particular emphasis is placed on the environmental aspects of the process, including land utilization and possible air and water pollutants. Suggestions are made for technological changes intended to improve the economics of the process as well as to reduce some of the pollution from by-product disposal. Ethanol may be derived from renewable cellulosic substances by either enzymatic or acid hydrolysis of cellulose to sugar, followed by conventional fermentation and distillation. The use of two agricultural residues - corn stover (field stalks remaining after harvest) and straw from wheat crops - is reviewed as a cellulosic feedstock. Two processes have been evaluated with regard to environmental impact - a two-stage acid process developed by G.T. Tsao of Purdue University and an enzymatic process based on the laboratory findings of C.R. Wilke of the University of California, Berkeley. The environmental residuals expected from the manufacture of methyl and ethyl alcohols from woody biomass are covered. The methanol is produced in a gasification process, whereas ethanol is produced by hydrolysis and fermentation processes similar to those used to derive ethanol from cellulosic materials.

  2. Alcohol production from agricultural and forestry residues

    SciTech Connect (OSTI)

    Opilla, R.; Dale, L.; Surles, T.

    1980-05-01T23:59:59.000Z

    A variety of carbohydrate sources can be used as raw material for the production of ethanol. Section 1 is a review of technologies available for the production of ethanol from whole corn. Particular emphasis is placed on the environmental aspects of the process, including land utilization and possible air and water pollutants. Suggestions are made for technological changes intended to improve the economics of the process as well as to reduce some of the pollution from by-product disposal. Ethanol may be derived from renewable cellulosic substances by either enzymatic or acid hydrolysis of cellulose to sugar, followed by conventional fermentation and distillation. Section 2 is a review of the use of two agricultural residues - corn stover (field stalks remaining after harvest) and straw from wheat crops - as a cellulosic feedstock. Two processes have been evaluated with regard to environmental impact - a two-stage acid process developed by G.T. Tsao of Purdue University and an enzymatic process based on the laboratory findings of C.R. Wilke of the University of California, Berkeley. Section 3 deals with the environmental residuals expected from the manufacture of methyl and ethyl alcohols from woody biomass. The methanol is produced in a gasification process, whereas ethanol is produced by hydrolysis and fermentation processes similar to those used to derive ethanol from cellulosic materials.

  3. Preparation and properties of polyvinyl alcohol microspheres

    SciTech Connect (OSTI)

    Campbell, J.H.; Grens, J.Z.; Poco, J.F.; Ives, B.H.

    1986-06-01T23:59:59.000Z

    Polyvinyl alcohol (PVA) microspheres, having a size range of approx.150- to 250-..mu..m diameter with 1- to 5-..mu..m wall thickness, have been fabricated using a solution droplet technique. The spheres were developed for possible use on the Lawrence Livermore National Laboratory (LLNL) Inertial Confinement Fusion (ICF) Program. PVA, a polymer chosen based on earlier survey work carried out at KMS Fusion, Inc., has good strength, low hydrogen permeability, is optically transparent, and water soluble. The latter property makes it safe and easy to use in our droplet generator system. A unique dual-orifice droplet generator was used to prepare the spheres. The droplet generator operating conditions and the column processing parameters were chosen using results from our 1-D model calculations as a guide. The polymer microsphere model is an extension of the model we developed to support the glass sphere production. After preparation, the spheres were physically characterized for surface quality, sphericity, wall thickness (and uniformity), and size. We also determined the buckling pressure for both uncoated and CH-coated spheres. Radiation stability to beta decay (from tritium) was evaluated by exposing the spheres to a 7-keV electron beam. The results from these and other physical property measurements are presented in this report.

  4. 2013-2014 Annual Notification of Alcohol and Other Drug Information Page 1 2013-2014 Annual Notification of Alcohol and Other Drug Information

    E-Print Network [OSTI]

    Tullos, Desiree

    2013-2014 Annual Notification of Alcohol and Other Drug Information Page 1 2013-2014 Annual Notification of Alcohol and Other Drug Information OSU is required by law to notify annually all students, staff, and faculty of alcohol and other drug policies, sanctions, and risks associated with use

  5. Acknowledgement of Alcohol and Illegal Drug Policy We have read and understand the "Georgia Institute of Technology Student Policy on Alcohol and Illegal

    E-Print Network [OSTI]

    Sherrill, David

    Acknowledgement of Alcohol and Illegal Drug Policy We have read and understand the "Georgia Institute of Technology Student Policy on Alcohol and Illegal Drugs" and shall enforce these provisions with the leaders of the organization, especially: a. Student Policy on Alcohol and Illegal Drugs b. Student

  6. The effects of alcohol consumption after menopause on bone regulating hormones

    E-Print Network [OSTI]

    Blaschke, Dawn Lewis

    1999-01-01T23:59:59.000Z

    The goal of this project was to determine if the alcohol-associated increase in osteopenia as observed in ovariectomized rats, which simulated human females after menopause, was due to the elect of alcohol on hormones that regulate bone metabolism...

  7. The Effects of Alcohol on the Regulation of Imprinted Genes in Mouse Embryonic Stem Cells

    E-Print Network [OSTI]

    Villanueva, Elizabeth Mary

    2013-02-04T23:59:59.000Z

    increasingly common disorder is Fetal Alcohol Spectrum Disorder or FASD. FASD is seen in many infants that have been exposed to alcohol, an environmental toxin, during fetal development. This disorder causes distinct mental and physical abnormalities whose...

  8. The role of non-parental adult social support in adjustment of adolescent children of alcoholics

    E-Print Network [OSTI]

    Roney, James E.

    1997-01-01T23:59:59.000Z

    The present study examined the effect adult social support outside of the family has on subjects' outcome scores in the areas of interpersonal problems, alcohol use and psychological functioning. Results indicate that children of alcoholics who had...

  9. Growing Up With An Alcohol-Dependent Father: Understanding Lived Experience Through Intepretative Phenomenological Analysis 

    E-Print Network [OSTI]

    McNaught, Kirsty, R.

    2011-06-29T23:59:59.000Z

    This study uses IPA (interpretative phenomenological analysis) to explore how paternal alcoholism impacts the child’s experience of life. Due to an abundance of quantitative research on ACOAs (adult children of alcoholics), ...

  10. Alcohol Chemistry on Rutile TiO2(110): The Influence of Alkyl...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Alcohol Chemistry on Rutile TiO2(110): The Influence of Alkyl Substituents on Reactivity and Selectivity. Alcohol Chemistry on Rutile TiO2(110): The Influence of Alkyl Substituents...

  11. The harmful effects of late-onset alcohol consumption on cortical bone in aged rats 

    E-Print Network [OSTI]

    Bowlin, Julie Lee

    2001-01-01T23:59:59.000Z

    to determine bone chemistry and morphological parameters. The effects of alcohol consumption, the aging process and caloric restriction were examined after obtaining results from this experiment. From the results found, it is evident that alcohol does have a...

  12. Characterization of Catalysts for the Synthesis of Higher Alcohols using Transmission Electron Microscopy

    E-Print Network [OSTI]

    Dunin-Borkowski, Rafal E.

    the use of biogas to create alcohol for fuel. Higher alcohols are favorable due to their high energy. In combination with a use of a heating holder, this microscope allows catalysts to be studied using a variety

  13. Effects of La2O3 on the mixed higher alcohols synthesis from...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    La2O3 on the mixed higher alcohols synthesis from syngas over Co catalysts: A combined theoretical and experimental Effects of La2O3 on the mixed higher alcohols synthesis from...

  14. Patterns of role-impairment among alcoholic workers

    E-Print Network [OSTI]

    Goldstein, Carolyn Lesley Klein

    1971-01-01T23:59:59.000Z

    PATTERNS OF ROLE-INPAIRNENT ANi01'1G ALCOHOLIC WORKERS A Thesis by Carolyn Les1ey Klein Goldstein Submitted to the Graduate College of Texas A&N University ini partial fulfillment of the requirements for the dei-ree of NASTER OP SCIENCE Nay... 1971 Najor Su'oject: Sociology 0 R R, 8 PATTERNS OF ROLE-IMPAIRMENT AMONG ALCOHOLIC WORKERS A Thesis Jh '0 a Ql by Carolyn Lesley Klein Goldstein Approved as to style end content by: Chairman of Committee May 19/1 ABSTRACT Patterns...

  15. Imaging of Alcohol-Induced Dopamine Release in Rats: Preliminary Findings With

    E-Print Network [OSTI]

    Morris, Evan D,

    . Normandin: Yale PET Center, P.O. Box 208048, New Haven, CT 06520 *Correspondence to: Evan D. Morris, YaleImaging of Alcohol-Induced Dopamine Release in Rats: Preliminary Findings With [11 C]Raclopride PET positron emission tomography (PET). PET images were acquired in 44 alcohol-nai¨ve male Wistar and alcohol

  16. High octane ethers from synthesis gas-derived alcohols

    SciTech Connect (OSTI)

    Klier, K.; Herman, R.G.; Feeley, O.C.; Johansson, M.A.

    1992-07-01T23:59:59.000Z

    The objective of the proposed research is to synthesize high octane ethers, primarily methyl isobutyl ether (MIBE) and methyl tertiary butyl ether (MTBE), directly from H[sub 2]/CO/CO[sub 2] coal-derived synthesis gas via alcohol mixtures that are rich in methanol and 2-methyl-l-propanol (isobutanol). The overall scheme involves gasification of coal, purification and shifting of the synthesis gas, higher alcohol synthesis, and direct synthesis of ethers. The last stage of the synthesis involves direct coupling of synthesis gas-derived methanol and isobutanol that has been demonstrated by us to occur over superacid catalysts to yield methyl isobutyl ether (MIBE) at moderate pressures and a mixture of methanol and isobutene at low pressures. MIBE is an isomer of MTBE and a process is proposed whereby MTBE from the two alcohols is maximized and MIBE is minimized. This will be achieved by the proper choice of reaction conditions, i.e. intermediate pressures, and of inorganic acid catalysts that are stable at temperatures higher than 200[degree]C, at which the carbonium ion reaction coupling of the two alcohols to MTBE is more effective than the oxonium ion or ester reaction coupling to MIBE. Both organic and inorganic catalysts will be investigated, and the better catalysts of these classes will be subjected to long term performance studies. The long term performance studies of the combined process will extend to 1000 hr and detailed analytical data for all products will be provided.

  17. Methods for sequestering carbon dioxide into alcohols via gasification fermentation

    DOE Patents [OSTI]

    Gaddy, James L; Ko, Ching-Whan; Phillips, J. Randy; Slape, M. Sean

    2013-11-26T23:59:59.000Z

    The present invention is directed to improvements in gasification for use with synthesis gas fermentation. Further, the present invention is directed to improvements in gasification for the production of alcohols from a gaseous substrate containing at least one reducing gas containing at least one microorganism.

  18. University of North Texas ALCOHOL USE REQUEST GUIDELINES

    E-Print Network [OSTI]

    Mohanty, Saraju P.

    in the University Union or Gateway Center, the student organization must purchase beer and/or wine and setups to event. All alcoholic beverages must be removed from premise at conclusion of event. Cash Bar: Beer/Wine only. The student organization must purchase beer and/or wine and setups through Scheduling Services

  19. Stress, Risk Taking, Alcohol/Drugs, and Parents as Partners

    E-Print Network [OSTI]

    Stowell, Michael

    college · Particular Interests Alcohol and other drug abuse Prescription stimulant abuse Marijuana) developmental stage · Need to take risks in order to grow · Frontal part of brain not fully developed · Thinking is inevitable and represents a great learning opportunity Hard to truly grow without setbacks

  20. adult dual alcohol: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    you are the victim of a crime on the U. One 12-ounce bottle of beer or a 5-ounce glass of wine (about a half-cup) has as much alcohol as a 1 Texas at Arlington, University of 18...

  1. alcohol survey implications: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    you are the victim of a crime on the U. One 12-ounce bottle of beer or a 5-ounce glass of wine (about a half-cup) has as much alcohol as a 1 Texas at Arlington, University of 60...

  2. alcohol hospitalizes dozens: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    you are the victim of a crime on the U. One 12-ounce bottle of beer or a 5-ounce glass of wine (about a half-cup) has as much alcohol as a 1 Texas at Arlington, University of 24...

  3. americans baseline alcohol: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    you are the victim of a crime on the U. One 12-ounce bottle of beer or a 5-ounce glass of wine (about a half-cup) has as much alcohol as a 1 Texas at Arlington, University of 37...

  4. alcohol dependence evidence: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    you are the victim of a crime on the U. One 12-ounce bottle of beer or a 5-ounce glass of wine (about a half-cup) has as much alcohol as a 1 Texas at Arlington, University of 99...

  5. alcohol nanocomposite preparation: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    you are the victim of a crime on the U. One 12-ounce bottle of beer or a 5-ounce glass of wine (about a half-cup) has as much alcohol as a 1 Texas at Arlington, University of 80...

  6. alcohol fuel production: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    you are the victim of a crime on the U. One 12-ounce bottle of beer or a 5-ounce glass of wine (about a half-cup) has as much alcohol as a 1 Texas at Arlington, University of 75 A...

  7. alcohols thiophene tetrahydrofuran: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    you are the victim of a crime on the U. One 12-ounce bottle of beer or a 5-ounce glass of wine (about a half-cup) has as much alcohol as a 1 Texas at Arlington, University of 25...

  8. Photoelectron spectroscopy of solvated electrons in alcohol and acetonitrile microjets

    E-Print Network [OSTI]

    Neumark, Daniel M.

    Photoelectron spectroscopy of solvated electrons in alcohol and acetonitrile microjets Alexander T in methanol, ethanol, and acetonitrile microjets are reported. Solvated electrons are generated. Two features are observed in acetonitrile at 2.61 Ã? 0.11 eV and 3.67 Ã? 0.15 eV, attributed

  9. Confirming Diagnosis of Hazardous and Harmful Alcohol Use Diagnostic accuracy of a computer assisted diagnostic system compared to conventional

    E-Print Network [OSTI]

    van Lambalgen, Michiel

    1 TITLE PAGE Confirming Diagnosis of Hazardous and Harmful Alcohol Use Diagnostic accuracy for alcoholism have good screening properties for detecting hazardous and harmful alcohol use (HHAU Test (BAT) for confirming the diagnosis of hazardous and harmful alcohol use. Design and Subjects BAT

  10. Confirming Diagnosis of Hazardous and Harmful Alcohol Use Diagnostic accuracy of a computer assisted diagnostic system compared to conventional

    E-Print Network [OSTI]

    van Lambalgen, Michiel

    1 TITLE PAGE Confirming Diagnosis of Hazardous and Harmful Alcohol Use Diagnostic accuracy for alcoholism have good screening properties for detecting hazardous and harmful alcohol use (HHAU Test (BAT) for confirming the diagnosis of hazardous and harmful alcohol use Design and Subjects BAT

  11. Electrocatalyst for alcohol oxidation at fuel cell anodes

    DOE Patents [OSTI]

    Adzic, Radoslav (East Setauket, NY); Kowal, Andrzej (Cracow, PL)

    2011-11-02T23:59:59.000Z

    In some embodiments a ternary electrocatalyst is provided. The electrocatalyst can be used in an anode for oxidizing alcohol in a fuel cell. In some embodiments, the ternary electrocatalyst may include a noble metal particle having a surface decorated with clusters of SnO.sub.2 and Rh. The noble metal particles may include platinum, palladium, ruthenium, iridium, gold, and combinations thereof. In some embodiments, the ternary electrocatalyst includes SnO.sub.2 particles having a surface decorated with clusters of a noble metal and Rh. Some ternary electrocatalysts include noble metal particles with clusters of SnO.sub.2 and Rh at their surfaces. In some embodiments the electrocatalyst particle cores are nanoparticles. Some embodiments of the invention provide a fuel cell including an anode incorporating the ternary electrocatalyst. In some aspects a method of using ternary electrocatalysts of Pt, Rh, and SnO.sub.2 to oxidize an alcohol in a fuel cell is described.

  12. Alcohol-free alkoxide process for containing nuclear waste

    DOE Patents [OSTI]

    Pope, James M. (Monroeville, PA); Lahoda, Edward J. (Edgewood, PA)

    1984-01-01T23:59:59.000Z

    Disclosed is a method of containing nuclear waste. A composition is first prepared of about 25 to about 80%, calculated as SiO.sub.2, of a partially hydrolyzed silicon compound, up to about 30%, calculated as metal oxide, of a partially hydrolyzed aluminum or calcium compound, about 5 to about 20%, calculated as metal oxide, of a partially hydrolyzed boron or calcium compound, about 3 to about 25%, calculated as metal oxide, of a partially hydrolyzed sodium, potassium or lithium compound, an alcohol in a weight ratio to hydrolyzed alkoxide of about 1.5 to about 3% and sufficient water to remove at least 99% of the alcohol as an azeotrope. The azeotrope is boiled off and up to about 40%, based on solids in the product, of the nuclear waste, is mixed into the composition. The mixture is evaporated to about 25 to about 45% solids and is melted and cooled.

  13. Alcohol-induced suppression of the humoral immune response

    SciTech Connect (OSTI)

    Stolen, J.S.; Draxler, S.; Nagle, J.J.

    1985-01-01T23:59:59.000Z

    The authors report here that summer flounder (Paralichthys dentatus) pretreated by injection of a small amount of the common alcohol, ethanol, or ethanol containing PCB, showed complete suppression of the immune response to a formalin-killed sewage sludge isolate of the human enteric bacteria, E. coli. The unresponsiveness persisted for up to 42 days after injection of bacteria. Demonstrable agglutinating antibody to E. coli was seen in unpretreated fish after seven days. A second injection of bacteria 42 days after the first in pretreated fish, now resulted in immune responsiveness although the magnitude of the response resembled a primary response, indicating that memory to the first injection was also suppressed. Slightly lower responses were seen in the groups of fish injected with ethanol containing the PCB Aroclor 1254 when compared with those given ethanol alone, but the major suppression was alcohol-induced.

  14. Congenital Splenic Cyst Treated with Percutaneous Sclerosis Using Alcohol

    SciTech Connect (OSTI)

    Anon, Ramon [Clinical University Hospital, University of Valencia, Department of Gastroenterology (Spain)], E-mail: ranon@comv.es; Guijarro, Jorge [Clinical University Hospital, University of Valencia, Department of Interventional Radiology (Spain); Amoros, Cirilo [Clinical University Hospital, University of Valencia, Department of Gastroenterology (Spain); Gil, Joaquin [Clinical University Hospital, University of Valencia, Department of Interventional Radiology (Spain); Bosca, Marta M. [Clinical University Hospital, University of Valencia, Department of Gastroenterology (Spain); Palmero, Julio [Clinical University Hospital, University of Valencia, Department of Interventional Radiology (Spain); Benages, Adolfo [Clinical University Hospital, University of Valencia, Department of Gastroenterology (Spain)

    2006-08-15T23:59:59.000Z

    We report a case of successful percutaneous treatment of a congenital splenic cyst using alcohol as the sclerosing agent. A 14-year-old female adolescent presented with a nonsymptomatic cystic mass located in the spleen that was believed to be congenital. After ultrasonography, a drainage catheter was placed in the cavity. About 250 ml of serous liquid was extracted and sent for microbiologic and pathologic studies to rule out an infectious or malignant origin. Immediately afterwards, complete drainage and local sclerotherapy with alcohol was performed. This therapy was repeated 8 days later, after having observed 60 ml of fluid in the drainage bag. One year after treatment the cyst has practically disappeared. We believe that treatment of splenic cyst with percutaneous puncture, ethanolization, and drainage is a valid option and it does not rule out surgery if the conservative treatment fails.

  15. The effects of alcohol use on zinc status

    E-Print Network [OSTI]

    Chapman, Lisa Louise

    1998-01-01T23:59:59.000Z

    and the cessation of estrogen production after menopause (Moniz 1994). As a greater proportion of the American population enters this age group, osteoporosis will become an even greater health concern. Current research indicates that achieving and maintaining peak... bone mass is the most effective method to prevent this disease (Moniz 1994). The relationship between alterations in bone mass and alcohol use was first documented by Saville (1965) Since this initial research, numerous other researchers (Baran et al...

  16. Alcohol and your health Research-based information from the

    E-Print Network [OSTI]

    Bandettini, Peter A.

    oz of regular beer about 5% alcohol = 8­9 fl oz of malt liquor (shown in a 12 oz glass) about 7-proof spirits or "hard liquor" 12 fl oz = 1 12 fl oz = 1½ 750 ml (a regular a shot (1.5 oz glass/50 ml bottle) = 1 16 fl oz = 1 16 fl oz = 2 wine bottle) = 5 a mixed drink or cocktail = 1 or more 22 fl oz = 2

  17. Electrolytic method to make alkali alcoholates using ion conducting alkali electrolyte/separator

    SciTech Connect (OSTI)

    Joshi, Ashok V. (Salt Lake City, UT); Balagopal, Shekar (Sandy, UT); Pendelton, Justin (Salt Lake City, UT)

    2011-12-13T23:59:59.000Z

    Alkali alcoholates, also called alkali alkoxides, are produced from alkali metal salt solutions and alcohol using a three-compartment electrolytic cell. The electrolytic cell includes an anolyte compartment configured with an anode, a buffer compartment, and a catholyte compartment configured with a cathode. An alkali ion conducting solid electrolyte configured to selectively transport alkali ions is positioned between the anolyte compartment and the buffer compartment. An alkali ion permeable separator is positioned between the buffer compartment and the catholyte compartment. The catholyte solution may include an alkali alcoholate and alcohol. The anolyte solution may include at least one alkali salt. The buffer compartment solution may include a soluble alkali salt and an alkali alcoholate in alcohol.

  18. E-Print Network 3.0 - anhydrous alcohol evaporated Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    peroxide Copper, chromium, iron, most metals or their salts, alcohols, acetone... , carbon tetrachloride or other chlorinated hydrocarbons, carbon dioxide, halogens Ammonia...

  19. Mechanism of the Aerobic Oxidation of Alcohols by Palladium Complexes of N-Heterocyclic Carbenes

    E-Print Network [OSTI]

    Goddard III, William A.

    reductive elimination of acetic acid, which yields a slightly higher calculated activation barrier-catalyzed aerobic oxidations of benzylic and allylic secondary alcohols, routinely fostering selectivity factors (k

  20. E-Print Network 3.0 - alcohol ads targeting Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    into the effects of early chronic ethanol consump- tion, we... compared the drinking behavior of two adult male Wistar rat groups: one that initiated alcohol consumption Source:...

  1. Brief intervention to reduce alcohol use among men who have sex with men

    E-Print Network [OSTI]

    Croff, Julie May Ketchie

    2010-01-01T23:59:59.000Z

    from reducing my carbon footprint. 11. Carpooling preventsfrom reducing my carbon footprint. 10. Carpooling preventsAlcohol-Barriers Carbon Footprint Perceived susceptibility:

  2. acetone-butyl alcohol fermentation: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Dissertations Summary: ??ENGLISH ABSTRACT: Alcoholic fermentation, and especially wine fermentation, is one of the most ancient microbiological processes utilized by man....

  3. alcohol-dependent danes attending: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for alcohol-dependent patients. Stephanie S. O' malley 1995-01-01 74 EARLY CHILDHOOD CARE AND EDUCATION: ECONOMIC IMPACTS IN DANE COUNTY Environmental Sciences and Ecology...

  4. Internal combustion engines for alcohol motor fuels: a compilation of background technical information

    SciTech Connect (OSTI)

    None

    1980-11-01T23:59:59.000Z

    This compilation, a draft training manual containing technical background information on internal combustion engines and alcohol motor fuel technologies, is presented in 3 parts. The first is a compilation of facts from the state of the art on internal combustion engine fuels and their characteristics and requisites and provides an overview of fuel sources, fuels technology and future projections for availability and alternatives. Part two compiles facts about alcohol chemistry, alcohol identification, production, and use, examines ethanol as spirit and as fuel, and provides an overview of modern evaluation of alcohols as motor fuels and of the characteristics of alcohol fuels. The final section compiles cross references on the handling and combustion of fuels for I.C. engines, presents basic evaluations of events leading to the use of alcohols as motor fuels, reviews current applications of alcohols as motor fuels, describes the formulation of alcohol fuels for engines and engine and fuel handling hardware modifications for using alcohol fuels, and introduces the multifuel engines concept. (LCL)

  5. Experimental and Modeling Study of the Flammability of Fuel Tank Headspace Vapors from Ethanol/Gasoline Fuels; Phase 3: Effects of Winter Gasoline Volatility and Ethanol Content on Blend Flammability; Flammability Limits of Denatured Ethanol

    SciTech Connect (OSTI)

    Gardiner, D. P.; Bardon, M. F.; Clark, W.

    2011-07-01T23:59:59.000Z

    This study assessed differences in headspace flammability for summertime gasolines and new high-ethanol content fuel blends. The results apply to vehicle fuel tanks and underground storage tanks. Ambient temperature and fuel formulation effects on headspace vapor flammability of ethanol/gasoline blends were evaluated. Depending on the degree of tank filling, fuel type, and ambient temperature, fuel vapors in a tank can be flammable or non-flammable. Pure gasoline vapors in tanks generally are too rich to be flammable unless ambient temperatures are extremely low. High percentages of ethanol blended with gasoline can be less volatile than pure gasoline and can produce flammable headspace vapors at common ambient temperatures. The study supports refinements of fuel ethanol volatility specifications and shows potential consequences of using noncompliant fuels. E85 is flammable at low temperatures; denatured ethanol is flammable at warmer temperatures. If both are stored at the same location, one or both of the tanks' headspace vapors will be flammable over a wide range of ambient temperatures. This is relevant to allowing consumers to splash -blend ethanol and gasoline at fueling stations. Fuels compliant with ASTM volatility specifications are relatively safe, but the E85 samples tested indicate that some ethanol fuels may produce flammable vapors.

  6. Analyzing the effects of alcohol on IGF-I in bone and plasma and on IGF-I mRNA in the liver and bone

    E-Print Network [OSTI]

    Stine, Christina Nicole

    2001-01-01T23:59:59.000Z

    Alcohol consumption is occurring in the younger generation. It has been found that the sooner people started drinking the shorter they are. Alcohol has also been shown to reduce peak bone mass. Alcohol inhibits osteoblastic proliferation which...

  7. The effects of alcohol and irradiation on the albino rat

    E-Print Network [OSTI]

    Klobukowski, Christopher John

    1963-01-01T23:59:59.000Z

    , Cole and i'. ilia reported that Lifi mice x;her pretxeeted. '. "! th ~ntrapcri toneal injection: of ethanol . nd iz'radiated with doses of X-rays xanging i'rom 600r to g00r (51350 is 620r for this strain) were protected from radiation by a xeduction... administered either orally, (paterson, 1951), or by intrsperitoneal injection, (Cole, 1952; Cole, 1955& praslidka, 1956), anc was given in acute doses. All experiment, showed ;. ome protect' ve effect. 5 ~ -'alcohol administered costirrad3. H, tion...

  8. Quick setting water-compatible furfuryl alcohol polymer concretes

    DOE Patents [OSTI]

    Sugama, Toshifumi (Ridge, NY); Kukacka, Lawrence E. (Port Jefferson, NY); Horn, William H. (Brookhaven, NY)

    1982-11-30T23:59:59.000Z

    A novel quick setting polymer concrete composite comprising a furfuryl alcohol monomer, an aggregate containing a maximum of 8% by weight water, and about 1-10% trichlorotoluene initiator and about 20-80% powdered metal salt promoter, such as zinc chloride, based on the weight of said monomer, to initiate and promote polymerization of said monomer in the presence of said aggregate, within 1 hour after mixing at a temperature of -20.degree. C. to 40.degree. C., to produce a polymer concrete having a 1 hour compressive strength greater than 2000 psi.

  9. T4 DNA condensation in water-alcohol media

    E-Print Network [OSTI]

    M. O. Gallyamov; O. A. Pyshkina; V. G. Sergeyev; I. V. Yaminsky

    2011-07-21T23:59:59.000Z

    The process of compaction of high molecular weight DNA T4 is investigated directly in a AFM liquid cell. The AFM-images of globules formed by DNA molecules in the result of compaction in water-alcohol environments at high izopropanol concentration (80%) are received; it is found that at intermediate concentration of izopropanol (40-50%) the DNA molecules form partially compacted formations in which the separate coils of macromolecules twist in toroidal structures. It is shown using the technique of deconvolution of the AFM-images that the globule include only one closely packed DNA molecule. The model of DNA packing is proposed on the basis of AFM experiment.

  10. Exploring Spatial Associations between On-Sale Alcohol Availability, Neighborhood Population Characteristics, and Violent Crime in a Geographically Isolated City

    E-Print Network [OSTI]

    Han, Daikwon; Gorman, Dennis M.

    2013-01-01T23:59:59.000Z

    Objectives. Despite the increasing evidence of the associations between alcohol availability and violence, there are still inconsistent findings on the effects of on- and off-sale alcohol outlets on violent crime. The aim of this study...

  11. Ethanol's Effect on Stem Cell Subpopulations And The Implications For Cortical Patterning And Development In Fetal Alcohol Syndrome

    E-Print Network [OSTI]

    Tingling, Joseph Duane

    Maternal alcohol consumption during the first and second trimester of pregnancy remains the leading cause of preventable mental retardation in the United States. Fetal Alcohol Syndrome (FAS) is a wide spectrum disease that is characterized...

  12. The effect of alcohol on the bone growth spurt of rats at a time equivalent to adolescent females

    E-Print Network [OSTI]

    Chaffin, Catherine Lee

    1997-01-01T23:59:59.000Z

    . The trabecular bone that remained was widely separated and reduced in thickness. These changes are similar to those observed in osteoporosis. The cause and mechanism of the reduced bone volume after alcohol abuse remains unclear. Alcohol consumption at an early...

  13. Clearwater-Palouse energy cooperative alcohol production feasibility study. Final report

    SciTech Connect (OSTI)

    Hammond, J.S.; Cole, K.M.; Schermerhorn, R.; Smith, S.; Greenwell, G.

    1982-02-01T23:59:59.000Z

    The feasibility of producing anhydrous ethanol from locally grown wheat and barley is explored. The following topics are discussed: feedstock economic analysis, by-product analysis, alcohol market analysis, alcohol market analysis, alternative fuels analysis, existing technology analysis, siting analysis, preliminary facility design, financial implementation plan, ecological assessment, and business management plan. (MHR)

  14. Level of osteopenia and bone recovery in alcohol-fed adolescent rats

    E-Print Network [OSTI]

    Spears, Heather Lynae

    1999-01-01T23:59:59.000Z

    Adolescence is a period in human growth and development that is a time of rapid and drastic change. It is also known to be an age of widespread alcohol abuse. Studies addressing the reversibility of the deleterious effects of chronic alcohol...

  15. The effects of lifelong alcohol consumption on calcium regulating and sex hormones

    E-Print Network [OSTI]

    Booe, Holli Laine

    1999-01-01T23:59:59.000Z

    The purpose of this study was to determine the effect of alcohol on hormones that possibly affect bone health. Sprague-Dawley rats were divided into three diet groups. Alcohol-treated animals were fed a modified Lieber-Decarli diet ad libitum...

  16. The Effects of Alcohol and Age on Astrocytes In Female Rats Following an Inflammatory Stimulus

    E-Print Network [OSTI]

    Simpson, Ashley

    2009-09-30T23:59:59.000Z

    THE EFFECTS OF ALCOHOL AND AGE ON ASTROCYTES IN FEMALE RATS FOLLOWING AN INFLAMMATORY STIMULUS A Senior Scholars Thesis by ASHLEY NICOLE SIMPSON Submitted to the Office of Undergraduate Research Texas A...&M University In partial fulfillment of the requirements for the designation as UNDERGRADUATE RESEARCH SCHOLAR April 2006 Major: Biology THE EFFECTS OF ALCOHOL AND AGE ON ASTROCYTES IN FEMALE RATS FOLLOWING...

  17. Changes in bone morphology and composition following long-term alcohol consumption

    E-Print Network [OSTI]

    Hebert, Valerie Anne

    1998-01-01T23:59:59.000Z

    The objective of this study is to determine the effect ics. of long-term alcohol consumption on bone morphology and composition. Female Sprague-Dawley rats were fed one of three diets (alcohol, pair-fed, or chow) for 18 months. The rats were...

  18. Endorcine Effects of Pyrethroid Pesticide Esfenvalerate Metabolites; 3-Phenoxybenzyl Alcohol and 3-Phenoxybenzoic Acid

    E-Print Network [OSTI]

    Chavez, Marco

    2009-09-30T23:59:59.000Z

    of pyrethroid metabolites, 3-phenoxybenzoic acid and 3-phenoxybenzyl alcohol. Cell proliferation was measured and compared to cells grown in media only and media with 1nM estradiol. By day 10 the metabolite 3-phenoxybenzyl alcohol at a concentration of .001 mM...

  19. Young drivers and the efficacy of the Texas drug and alcohol driving awareness program

    E-Print Network [OSTI]

    Darnell, Richard

    2009-05-15T23:59:59.000Z

    The purpose of this study was to examine the efficacy of the Texas Drug and Alcohol Driving Awareness Program (TDADAP) in relation to alcohol-related offenses among young drivers. Participants in this study were students in pre-license programs...

  20. The harmful effects of late-onset alcohol consumption on cortical bone in aged rats

    E-Print Network [OSTI]

    Bowlin, Julie Lee

    2001-01-01T23:59:59.000Z

    This study looked at the effects of late-onset alcohol consumption for 8 weeks on the aged rat model (15 months old). Thirty 15 month old female Fisher 344 rats were divided into three diet groups: Alcohol (n=9), pair-fed (n=9), and pellet (n=6...

  1. The consequence of late-onset alcohol abuse in aged bone: a histomorhometric analysis

    E-Print Network [OSTI]

    Barker, Lisa Setchfield

    2000-01-01T23:59:59.000Z

    The objective of this experiment was to examine the effect of late-onset alcohol abuse on aged bone using the rat model. Thirty female Fischer 344 rats were separated by weights into one of four groups: baseline, alcohol-fed, pair-fed, and pellet...

  2. Addendum: Tenth International Symposium on Alcohol Fuels, The road to commercialization

    SciTech Connect (OSTI)

    Not Available

    1994-05-01T23:59:59.000Z

    The Tenth International Symposium on ALCOHOL FUELS ``THE ROAD TO COMMERCIALIZATION`` was held at the Broadmoor Hotel, Colorado Springs, Colorado, USA November 7--10, 1993. Twenty-seven papers on the production of alcohol fuels, specifications, their use in automobiles, buses and trucks, emission control, and government policies were presented. Individual papers have been processed separately for entry into the data base.

  3. Cannabinoid receptors as novel therapeutic targets for the management of non alcoholic steatohepatitis

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Cannabinoid receptors as novel therapeutic targets for the management of non alcoholic Marne, Créteil, 94000 France; AP-HP, Groupe hospitalier Henri Mondor-Albert Chenevier, Service d rationale for the use of CB1 antagonists in the management of NASH. KEYWORDS: fatty liver, non alcoholic

  4. Employee Drug and Alcohol Abuse Policy #CofC.HR.DA.03 Revised 12/2001

    E-Print Network [OSTI]

    Kasman, Alex

    Policy Employee Drug and Alcohol Abuse Policy #CofC.HR.DA.03 Revised 12/2001 The Drug-Free Schools and Communities Act The Drug-Free School and Communities Act, Public Law 101-226, requires that as a condition, or distribution of illicit drugs and alcohol by students and employees. The College of Charleston has

  5. Updated 2011-12 HEALTH AND BEHAVIORAL RISKS OF ALCOHOL AND DRUG USE

    E-Print Network [OSTI]

    Marsh, David

    Updated 2011-12 HEALTH AND BEHAVIORAL RISKS OF ALCOHOL AND DRUG USE The negative physical and mental effects of the use of alcohol and other drugs are well documented. Use of these drugs may cause including depression, psychosis, and severe anxiety. Risks associated with specific drugs are described

  6. Tobacco, alcohol, cannabis and other illegal drug use among young adults: the socioeconomic context.

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Tobacco, alcohol, cannabis and other illegal drug use among young adults: the socioeconomic.drugalcdep.2011.09.002 #12;2 Tobacco, alcohol, cannabis and other illegal drug use among young adults (CAST), other illegal drug use. Socioeconomic position was defined by educational attainment

  7. Changes in bone morphology and composition following long-term alcohol consumption 

    E-Print Network [OSTI]

    Hebert, Valerie Anne

    1998-01-01T23:59:59.000Z

    The objective of this study is to determine the effect ics. of long-term alcohol consumption on bone morphology and composition. Female Sprague-Dawley rats were fed one of three diets (alcohol, pair-fed, or chow) for 18 ...

  8. Horizontal well drill-in fluid utilizing alcohol ethoxylate

    SciTech Connect (OSTI)

    Jachnik, R.P.; Green, P.

    1995-11-01T23:59:59.000Z

    The drilling of horizontal wells in the last 6 years has significantly improved the economics of oil and gas production from depleted reservoirs or tight sands. This paper illustrates the application of an alcohol ethoxylate into a drill-in fluid designed to minimize formation damage in low permeability sandstones while drilling horizontal sections as long as 1,617 meters (5,306 ft) at depths approaching 6,580 meters (21,600 ft) and to facilitate formation cleanup. The chemistry of alcohol ethoxylates/alkoxylates are described and the more popular names used within the industry will be discussed. Laboratory results are presented which illustrate colloidal phenomena not previously reported with these systems, the routes taken for successful application into a drill-in fluid and how complex these particular colloidal systems are from a physical chemical viewpoint, along with the inevitable learning curve required to fully optimize these systems. Generalized case histories from the UK Southern North Sea will be described, along with field observations which back up the colloidal phenomena seen in the laboratory.

  9. Novel Vertimass Catalyst for Conversion of Ethanol and Other Alcohols into Fungible Gasoline, Jet, and Diesel Fuel Blend Stocks

    Broader source: Energy.gov [DOE]

    Novel Vertimass Catalyst for Conversion of Ethanol and Other Alcohols into Fungible Gasoline, Jet, and Diesel Fuel Blend Stocks

  10. J. Am. Chem. SOC.1992, 114, 4265-4268 4265 allyl alcohol vs that of acrolein). Alternatively, one could argue

    E-Print Network [OSTI]

    Helgaker, Trygve

    J. Am. Chem. SOC.1992, 114, 4265-4268 4265 allyl alcohol vs that of acrolein). Alternatively, one could argue that acrolein liberates vinyl groups and allyl alcohol liberates acetylene; the former would The principal influences of the C = C group of allyl alcohol and acrolein are on the bonding configuration

  11. Paradoxical increase of positive answers to the CAGE questionnaire during a period of decreasing alcohol consumption: results from two population-

    E-Print Network [OSTI]

    Boyer, Edmond

    first worldwide until 1983, in per capita yearly alcohol intake, and stayed in the top 6 countries since alcohol consumption: results from two population- based surveys in Île-de-France, 1991 and 2005. Short questionnaire during a period of decreasing alcohol consumption: results from two population- based surveys

  12. Catalysts and process for hydrogenolysis of sugar alcohols to polyols

    DOE Patents [OSTI]

    Chopade, Shubham P. (East Lansing, MI) [East Lansing, MI; Miller, Dennis J. (Okemos, MI) [Okemos, MI; Jackson, James E. (Haslett, MI) [Haslett, MI; Werpy, Todd A. (West Richland, WA) [West Richland, WA; Frye, Jr., John G [Richland, WA; Zacher, Alan H. (Richland, WA) [Richland, WA

    2001-09-18T23:59:59.000Z

    The present invention provides a process for preparation of low molecular weight polyols from high molecular weight polyols in a hydrogenolysis reaction under elevated temperature and hydrogen pressure. The process comprises providing in a reaction mixture the polyols, a base, and a metal catalyst prepared by depositing a transition metal salt on an inert support, reducing the metal salt to the metal with hydrogen, and passivating the metal with oxygen, and wherein the catalyst is reduced with hydrogen prior to the reaction. In particular, the process provides for the preparation of glycerol, propylene glycol, and ethylene glycol from sugar alcohols such as sorbitol or xylitol. In a preferred process, the metal catalyst comprises ruthenium which is deposited on an alumina, titania, or carbon support, and the dispersion of the ruthenium on the support increases during the hydrogenolysis reaction.

  13. Computational Studies of [Bmim][PF6]/n-Alcohol Interfaces with Many-Body Potentials

    SciTech Connect (OSTI)

    Chang, Tsun-Mei; Dang, Liem X.

    2014-09-04T23:59:59.000Z

    In this paper, we present the results from molecular-dynamics simulations of the equilibrium properties of liquid/liquid interfaces of room temperature ionic liquid [bmim][PF6] and simple alcohols (i.e., methanol, 1-butanol, and 1-hexanol) at room temperature. Polarizable potential models are employed to describe the interactions among species. Results from our simulations show stable interfaces between the ionic liquid and n-alcohols, and we found that the interfacial widths decrease from methanol to 1-butanol systems, and then increase for 1-hexanol interfaces. Angular distribution analysis reveals that the interface induces a strong orientational order of [bmim] and n-alcohol molecules near the interface, with [bmim] extending its butyl group into the alcohol phase while the alcohol has the OH group pointing into the ion liquid region, which is consistent with the recent sum-frequency-generation experiments. We found the interface to have a significant influence on the dynamics of ionic liquids and n-alcohols. The orientational autocorrelation functions illustrate that [bmim] rotate more freely near the interface than in the bulk, while the rotation of n-alcohol is hindered at the interface. Additionally, the time scale associated with the diffusion along the interfacial direction is found to be faster for [bmim] but slowed down for n-alcohols approaching the interface. We also calculate the dipole moment of n-alcohols as a function of the distance normal to the interface. We found that, even though methanol and 1-butanol have different dipole moments in bulk phase, they reach a similar value at the interface. This work was supported by the U.S. Department of Energy, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences, and Biosciences. Pacific Northwest National Laboratory is a multiprogram national laboratory operated for the Department of Energy by Battelle. The calculations were carried out using computer resources provided by the Office of Basic Energy Sciences.

  14. Denaturing of Molecules | GE Global Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville Power Administration wouldDECOMPOSITIONPortalTo help ensure that sulfatesDo Molecules Get Old?

  15. Alcohol Consumption in University Students: The Relationship Between Personality and Metacognition in Relation to Drinking 

    E-Print Network [OSTI]

    Clark, Ailsa

    2010-03-17T23:59:59.000Z

    There are growing concerns over the heavy drinking found in university students in the UK. Metacognitions; the cognitive processes that oversee, monitor and control, cognition, have been related to alcohol use. The personality ...

  16. Development of miscella refining process for cottonseed oil-isopropyl alcohol system: laboratory-scale evaluations

    E-Print Network [OSTI]

    Chau, Chi-Fai

    1994-01-01T23:59:59.000Z

    A technologically feasible cottonseed oil-isopropyl alcohol (IPA) miscella refining process was developed to produce high quality cottonseed oil. Individual steps necessary to refine cottonseed oil-IPA miscella were determined and improved...

  17. alcohol dehydrogenase-acetyl-coa thio: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    second, the efficacy of three psychotherapies for alcoholism in treating extreme West, Mike First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23...

  18. Synthesis of higher alcohols on copper catalysts supported on alkali-promoted basic oxides

    E-Print Network [OSTI]

    Iglesia, Enrique

    -butyl-ether (MTBE) after isobutanol dehydration to form isobutene. An equimolar ratio of methanol to isobutanol would be preferred for MTBE synthesis. Methanol and higher alcohols can also be used for direct blending

  19. Fluoro-alcohol phase modifiers and process for cesium solvent extraction

    DOE Patents [OSTI]

    Bonnesen, Peter V.; Moyer, Bruce A.; Sachleben, Richard A.

    2003-05-20T23:59:59.000Z

    The invention relates to a class of phenoxy fluoro-alcohols, their preparation, and their use as phase modifiers and solvating agents in a solvent composition for the extraction of cesium from alkaline solutions. These phenoxy fluoro-alcohols comply with the formula: ##STR1## in which n=2 to 4; X represents a hydrogen or a fluorine atom, and R.sup.2 -R.sup.6 are hydrogen or alkyl substituents. These phenoxy fluoro-alcohol phase modifiers are a necessary component to a robust solvent composition and process useful for the removal of radioactive cesium from alkaline nuclear waste streams. The fluoro-alcohols can also be used in solvents designed to extract other cesium from acidic or neutral solutions.

  20. E-Print Network 3.0 - acute alcohol exposure Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    chloride 100-44-7) and benzoyl chloride 98-88-4 (combined exposures) IARC-2A Acrolein Acutely... alcohol AcutelyHazardousWaste alpha,alpha-Dimethylphenethylan-dne...

  1. Influence of Fatty Alcohols and Acids on the Clarity and Biota of Impounded Reservoirs

    E-Print Network [OSTI]

    Davis, W. B.; Reynolds, T. D.

    TR-18 1969 Influence of Fatty Alcohols and Acids on the Clarity and Biota of Impounded Reservoirs W.B. Davis T.D. Reynolds Texas Water Resources Institute Texas A&M University ...

  2. Osteopontin-mediated neutrophilic infiltration and higher liver injury in a female rodent alcoholic steatohepatitis model

    E-Print Network [OSTI]

    Banerjee, Atrayee

    2009-05-15T23:59:59.000Z

    Females are known to be more susceptible to alcoholic liver disease (ALD), but the precise mechanism behind this increased susceptibility is not well understood. The objective of this study was to identify the molecular mechanism behind...

  3. Maternal adrenocorticotropin, cortisol and thyroid hormone responses to chronic binge alcohol exposure throughout gestation: ovine model

    E-Print Network [OSTI]

    Tress, Ursula

    2009-05-15T23:59:59.000Z

    This study investigated the effect of chronic alcohol exposure on the responses of the maternal hypothalamus-pituitary adrenal axis (HPA-axis) and thyroid hormones throughout gestation using an ovine model. Maternal plasma concentrations of ACTH...

  4. Effects of Alcohol on the Regulation of Imprinted Genes in Mouse Stem Cells

    E-Print Network [OSTI]

    Crocker, Alyssa

    2013-02-04T23:59:59.000Z

    ABSTRACT Effects of Alcohol on the Regulation of Imprinted Genes in Mouse Stem Cells. (December 2013) Alyssa Crocker Department of Animal Science Texas A&M University Research Advisor: Dr. Michael Golding Department of Veterinary Physiology...

  5. The effect of moderate alcohol intake on bone mineral density of ovariectomized rats

    E-Print Network [OSTI]

    Shipley, Debra Lynn

    1997-01-01T23:59:59.000Z

    Osteoporosis is a major health problem in the United States, especially for postmenopausal women. It is a condition in which many risk factors and dietary factors have been implicated, such as alcohol and estrogen deficiency. Both have been proven...

  6. Cloning and sequencing of the alcohol dehydrogenase II gene from Zymomonas mobilis

    DOE Patents [OSTI]

    Ingram, Lonnie O. (Gainesville, FL); Conway, Tyrrell (Gainesville, FL)

    1992-01-01T23:59:59.000Z

    The alcohol dehydrogenase II gene from Zymomonas mobilis has been cloned and sequenced. This gene can be expressed at high levels in other organisms to produce acetaldehyde or to convert acetaldehyde to ethanol.

  7. An evaluation of pocket-model, numerical readout breath alcohol testing instruments

    E-Print Network [OSTI]

    Van Tassel, William Edward

    2004-11-15T23:59:59.000Z

    Eight small-scale breath alcohol measurement devices were tested for accuracy, precision and the ability to not yield false positive and false negative readings. These pocket-sized breath testers (PMBTs), which provided numerical readout of Br...

  8. Natural guardians of the race: heredity, hygiene, alcohol, and degeneration in Scottish Psychiatry, c. 1860 – 1920 

    E-Print Network [OSTI]

    Wood, James Anthony

    2012-06-29T23:59:59.000Z

    This thesis investigates the ways in which hereditary degeneration was discussed by Scottish psychiatrists in the late nineteenth and early twentieth centuries with particular reference to the anti-alcohol debate. I ...

  9. alcohol intake-induced myocardial: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    year. Fifteen percent of this amount is the cost of medical consequences and alcohol treatment; more than 70 percent is due to reduced, lost and forgone earnings; and the...

  10. Characterization of Catalysts for Synthesis of Higher Alcohols using Electron Microscopy

    E-Print Network [OSTI]

    Dunin-Borkowski, Rafal E.

    and better production paths. One of these is using biogas to create alcohol as a fuel. Higher. Together with a heating holder, it enables us to study catalysts with TEM methods while

  11. The effect of generalization of extinction on relapse following aversion therapy for alcoholism

    E-Print Network [OSTI]

    Godsey, Robert Lane

    1974-01-01T23:59:59.000Z

    THE EFFECT OF GENERALIZATION OF EXTINCTION ON REI, APSE FOLLOWING AVERSION THERAPY FOR ALCOHOLISM A Thesis by ROBERT LANE GODSEY Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement... for the degree of MASTER OF SCIENCE May 1974 Major Subject: Psychology THE EFFECT OF GENERALIZATION OF EXTINCTION ON RELAPSE FOLLOWING AVERSION THERAPY FOR ALCOHOLISM A Thesis ROBERT LANE GODSEY Approved as to style and content by: (Chairman of Committe...

  12. MMPI scores for criminal and non-criminal adult children of alcoholics

    E-Print Network [OSTI]

    Brill, Phyllis Rose

    1988-01-01T23:59:59.000Z

    MMPI SCORES FOR CRIMINAL AND NON-CRIMINAL ADULT CHILDREN OF ALCOHOLICS A Thesis by PHYLLIS ROSE BRILL Submitted to the Graduate College of Texas AS, M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE... August 1988 Major Subject: Psychology MMPI SCORES FOR CRIMINAL AND NON-CRIMINAL ADULT CHILDREN OF ALCOHOLICS A Thesis by PHYLLIS ROSE BRILL Approved as to style and content by: Can ida . Lutes (Chairman of Committee) Robert R. Reilley (Member...

  13. Optimum catalytic process for alcohol fuels from syngas: Second quarterly technical progress report

    SciTech Connect (OSTI)

    Not Available

    1987-07-30T23:59:59.000Z

    A base case process for economic studies of making fuel alcohols from syngas has been developed. It uses existing technologies which have been demonstrated to be feasible or have already been commercialized. The process consists of the following steps: coal or natural gas (reforming or partial oxidation) to syngas; syngas to methanol by ICI technology; methanol to light olefins by proprietary UCC technology using molecular sieves; olefins to alcohols by hydroformylation (with a homogeneous rhodium catalyst) followed by hydrogenation. Process economics for the two natural gas-based routes have been developed. With insights gained from this, an optimized and integrated multi-step process has been conceptualized which allows estimation of the lowest cost at which fuel alcohols can be produced. A 60% methanol and 40% higher alcohol mix was assumed to be a suitable fuel alcohol blend for gasoline. At a natural gas price of $2/MMBTU, the cost of producing this, by either partial oxidation or reforming, is $1.12/gal. An integrated process with autothermal reforming at 750 psia and methanol synthesis at 700 psia allows incorporation of the best features of reforming and partial oxidation as well as elimination of syngas compression. The production cost of fuel alcohols by this process is estimated to be $0.90/gal. This is, therefore, the lowest cost at which fuel alcohols can be produced by an integrated, multi-step process. An ''ideal'' process has also been conceptualized which establishes a target production cost that new technology should strive for to be competitive. This process incorporates autothermal reforming for producing syngas followed by conversion to fuel alcohols using emerging technologies. The target production cost is estimated to be $0.65/gal. 16 figs., 10 tabs.

  14. Drug and alcohol abuse: The pattern and magnitude of the problem

    SciTech Connect (OSTI)

    Ajayi, P.A.

    1996-12-31T23:59:59.000Z

    In the last 12 months, many more cases of alcohol and drug (substance) abuse in the workplace were seen in the Escravos operations of Chevron Nigeria Limited than in previous years. This called the attention to the rising prevalence of drug and alcohol abuse in contradistinction to reports from similar organizations in other parts of the world. Chevron Nigeria has a written Drug and Alcohol Policy which has been dormant for some time because of the apparent rarity of the problem of substance abuse in the workplace. This Policy is being reviewed to broaden its scope and make it more effective. A total of 30 employees were tested for drugs and alcohol .6 exceeded the legal limits of Blood Alcohol Concentration (BAC) and 5 tested positive for drugs. Tests were mainly post-accident, reasonable cause and random. The common substances abused were alcohol, cannabis, cocaine and morphine in that order. The findings are compared with those of similar organizations in UK and USA. Efforts to control substance abuse in the workplace are being put into place.

  15. Partial oxidation for improved cold starts in alcohol-fueled engines: Phase 2 topical report

    SciTech Connect (OSTI)

    NONE

    1998-04-01T23:59:59.000Z

    Alcohol fuels exhibit poor cold-start performance because of their low volatility. Neat alcohol engines become difficult, if not impossible, to start at temperatures close to or below freezing. Improvements in the cold-start performance (both time to start and emissions) are essential to capture the full benefits of alcohols as an alternative transportation fuel. The objective of this project was to develop a neat alcohol partial oxidation (POX) reforming technology to improve an alcohol engine`s ability to start at low temperatures (as low as {minus}30 C) and to reduce its cold-start emissions. The project emphasis was on fuel-grade ethanol (E95) but the technology can be easily extended to other alcohol fuels. Ultimately a compact, on-vehicle, ethanol POX reactor was developed as a fuel system component to produce a hydrogen-rich, fuel-gas mixture for cold starts. The POX reactor is an easily controllable combustion device that allows flexibility during engine startup even in the most extreme conditions. It is a small device that is mounted directly onto the engine intake manifold. The gaseous fuel products (or reformate) from the POX reactor exit the chamber and enter the intake manifold, either replacing or supplementing the standard ethanol fuel consumed during an engine start. The combustion of the reformate during startup can reduce engine start time and tail-pipe emissions.

  16. Assessment of ether and alcohol fuels from coal. Volume 2. Technical report

    SciTech Connect (OSTI)

    Not Available

    1983-03-01T23:59:59.000Z

    A unique route for the indirect liquefaction of coal to produce transportation fuel has been evaluated. The resultant fuel includes alkyl tertiary alkyl ethers and higher alcohols, all in the gasoline boiling range. When blended into gasoline, the ether fuel provides several advantages over the lower alcohols: (1) lower chemical oxygen content, (2) less-severe water-separation problems, and (3) reduced front-end volatility effects. The ether fuel also has high-octane quality. Further, it can be utilized as a gasoline substitute in all proportions. Production of ether fuel combines several steps, all of which are or have been practiced on an industrial scale: (1) coal gasification, (2) gas cleanup and shift to desired H/sub 2/:CO ratio, (3) conversion of synthesis gas to isobutanol, methanol, and higher alcohols, (4) separation of alcohols, (5) chemical dehydration of isobutanol to isobutylene, and (6) etherification of isobutylene with methanol. A pilot-plant investigation of the isobutanol synthesis step was performed. Estimates of ether-fuel manufacturing costs indicate this process route is significantly more costly than synthesis of methanol. However, the fuel performance features provide incentive for developing the necessary process and catalyst improvements. Co-production of higher-molecular-weight co-solvent alcohols represents a less-drastic form of methanol modification to achieve improvement in the performance of methanol-gasoline blends. Costs were estimated for producing several proportions of methanol plus higher alcohols from coal. Estimated fuel selling price increases regularly but modestly with higher alcohol content.

  17. Debye relaxation and 250 K anomaly in glass forming monohydroxy alcohols

    E-Print Network [OSTI]

    Bauer, S; Gainaru, C; Lunkenheimer, P; Hiller, W; Loidl, A; Böhmer, R

    2013-01-01T23:59:59.000Z

    A previous dielectric, near-infrared (NIR), and nuclear magnetic resonance study on the hydrogen-bonded liquid 2-ethyl-1-hexanol [C. Gainaru et al., Phys. Rev. Lett. 107, 118304 (2011)] revealed anomalous behavior in various static quantities near 250 K. To check whether corresponding observations can be made for other monohydroxy alcohols as well, these experimental methods were applied to such substances with 5, 6, 7, 8, and 10 carbon atoms in their molecular backbone. All studied liquids exhibit a change of behavior near 250 K which is tentatively ascribed to effects of hydrogen bond cooperativity. By analyzing the NIR band intensities, a linear cluster size is derived that agrees with estimates from dielectric spectroscopy. All studied alcohols, except 4-methyl-3-heptanol, display a dominant Debye-like peak. Furthermore, neat 2-ethyl-1-butanol exhibits a well resolved structural relaxation in its dielectric loss spectrum which so far has only been observed for diluted monohydroxy alcohols.

  18. Process to convert biomass and refuse derived fuel to ethers and/or alcohols

    DOE Patents [OSTI]

    Diebold, J.P.; Scahill, J.W.; Chum, H.L.; Evans, R.J.; Rejai, B.; Bain, R.L.; Overend, R.P.

    1996-04-02T23:59:59.000Z

    A process is described for conversion of a feedstock selected from the group consisting of biomass and refuse derived fuel (RDF) to provide reformulated gasoline components comprising a substantial amount of materials selected from the group consisting of ethers, alcohols, or mixtures thereof, comprising: drying said feedstock; subjecting said dried feedstock to fast pyrolysis using a vortex reactor or other means; catalytically cracking vapors resulting from said pyrolysis using a zeolite catalyst; condensing any aromatic byproduct fraction; catalytically alkylating any benzene present in said vapors after condensation; catalytically oligomerizing any remaining ethylene and propylene to higher olefins; isomerizing said olefins to reactive iso-olefins; and catalytically reacting said iso-olefins with an alcohol to form ethers or with water to form alcohols. 35 figs.

  19. Process to convert biomass and refuse derived fuel to ethers and/or alcohols

    DOE Patents [OSTI]

    Diebold, James P. (Lakewood, CO); Scahill, John W. (Evergreen, CO); Chum, Helena L. (Arvada, CO); Evans, Robert J. (Lakewood, CO); Rejai, Bahman (Lakewood, CO); Bain, Richard L. (Golden, CO); Overend, Ralph P. (Lakewood, CO)

    1996-01-01T23:59:59.000Z

    A process for conversion of a feedstock selected from the group consisting of biomass and refuse derived fuel (RDF) to provide reformulated gasoline components comprising a substantial amount of materials selected from the group consisting of ethers, alcohols, or mixtures thereof, comprising: drying said feedstock; subjecting said dried feedstock to fast pyrolysis using a vortex reactor or other means; catalytically cracking vapors resulting from said pyrolysis using a zeolite catalyst; condensing any aromatic byproduct fraction; catalytically alkylating any benzene present in said vapors after condensation; catalytically oligomerizing any remaining ethylene and propylene to higher olefins; isomerizing said olefins to reactive iso-olefins; and catalytically reacting said iso-olefins with an alcohol to form ethers or with water to form alcohols.

  20. Campus Health/forms/2013,06,07 AGREEMENT TO SUBMIT TO AN ALCOHOL AND/OR DRUG TEST

    E-Print Network [OSTI]

    Campus Health/forms/2013,06,07 AGREEMENT TO SUBMIT TO AN ALCOHOL AND/OR DRUG TEST AND AUTHORIZATION FOR THE RELEASE OF TEST RESULTS I have been requested by LSUHSC to submit to an alcohol and/or drug test and/or drug test is completely voluntary on my part and that I have the right to refuse to submit

  1. VI-8.00(B) UMCP POLICY ON STUDENT ALCOHOL AND OTHER DRUG ABUSE APPROVED BY PRESIDENT SEPTEMBER 9, 1992

    E-Print Network [OSTI]

    Li, Teng

    VI-8.00(B) UMCP POLICY ON STUDENT ALCOHOL AND OTHER DRUG ABUSE APPROVED BY PRESIDENT SEPTEMBER 9, 1992 I. Policy The University of Maryland at College Park is dedicated to the pursuit and dissemination of drugs and alcohol. In keeping with this commitment, it is the policy of the University that the illegal

  2. The effect of alcohol on the bone growth spurt of rats at a time equivalent to adolescent females 

    E-Print Network [OSTI]

    Chaffin, Catherine Lee

    1997-01-01T23:59:59.000Z

    The objective of this study is to determine the effect of long-term alcohol consumption on the growth spurt in adolescent rats. Female Sprague-Dawley rats were fed one of three diets (alcohol, pair-fed or chow) for 3 months. ...

  3. Process for the conversion of lower alcohols to higher branched oxygenates

    DOE Patents [OSTI]

    Barger, Paul T. (Arlington Heights, IL)

    1996-01-01T23:59:59.000Z

    A process is provided for the production of branched C.sub.4+ oxygenates from lower alcohols such as methanol, ethanol, propanol and mixtures thereof. The process comprises contacting the lower alcohols with a solid catalyst comprising a mixed metal oxide support having components selected from the group consisting of oxides of zinc, magnesium, zirconia, titanium, manganese, chromium, and lanthanides, and an activation metal selected from the group consisting of Group VIII metal, Group IB metals, and mixtures thereof. The advantage of the process is improved yields and selectivity to isobutanol which can subsequently be employed in the production of high octane motor gasoline.

  4. Process for the conversion of lower alcohols to higher branched oxygenates

    DOE Patents [OSTI]

    Barger, P.T.

    1996-09-24T23:59:59.000Z

    A process is provided for the production of branched C{sub x} oxygenates from lower alcohols such as methanol, ethanol, propanol and mixtures thereof. The process comprises contacting the lower alcohols with a solid catalyst comprising a mixed metal oxide support having components selected from the group consisting of oxides of zinc, magnesium, zirconia, titanium, manganese, chromium, and lanthanides, and an activation metal selected from the group consisting of Group VIII metal, Group IB metals, and mixtures thereof. The advantage of the process is improved yields and selectivity to isobutanol which can subsequently be employed in the production of high octane motor gasoline.

  5. Probe molecule studies: Active species in alcohol synthesis. Final report, July 1993--July 1994

    SciTech Connect (OSTI)

    Blackmond, D.G.; Wender, I.; Oukaci, R.; Wang, Jian

    1994-07-01T23:59:59.000Z

    The objectives of this project are to investigate the role(s) of cobalt and copper in constructing the active sites for the formation of higher alcohols from CO/H{sub 2} over the Co-Cu based catalysts by using different reduction treatments and applying selected characterization tools such as TPR, TPD, XRD and XPS as well as to generate mechanistic information on the reaction pathway(s) and key intermediate(s) of higher alcohol synthesis from CO/H{sub 2} over Co-Cu/ZnO catalysts by the approach of in-situ addition of a probe molecule (nitromethane).

  6. MATERNAL COFFEE AND ALCOHOL CONSUMPTION DURING PREGNANCY, PARENTAL SMOKING AND RISK OF CHILDHOOH ACUTE LEUKEMIA

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACUTE LEUKEMIA Short title: Maternal coffee and alcohol consumption, parental smoking and childhood smoking and maternal beverage consumption, were obtained for 280 cases of childhood acute leukemia and 280 acute leukemia in a multicenter case-control study. The study included 280 incident cases and 288

  7. DRD2 Gene Transfer Into the Nucleus Accumbens Core of the Alcohol Preferring and Nonpreferring Rats

    E-Print Network [OSTI]

    Homes, Christopher C.

    their alcohol preference (37% decrease) and intake (48% decrease), and these measures returned to pretreat- ment. Analysis of the [11 C]raclopride micro­positron emission tomography data after chronic (7 weeks) exposure, 1996; Volkow et al., 1996, 2002). These data have led to the hypothesis that DRD2 deficiency or down

  8. Synthesis of higher alcohols from carbon monoxide and hydrogen in a slurry reactor

    SciTech Connect (OSTI)

    McCutchen, M.S.

    1992-08-28T23:59:59.000Z

    Higher, i.e. C{sub 2{sup +}}, alcohols are desired as gasoline additives, feedstocks for producing ethers and as alternative fuels for automobiles. In all cases, the backbone branching of an alcohol improves octane rating, which is essential for good engine performance. These types of branched, higher alcohols are the desired products for a process converting synthesis gas, a CO and H{sub 2} mixture, often generated from coal gasification. Based on this premise, promoted ZnCr oxide catalysts appear to be as one of the best avenues for further investigation. Once this investigation is complete, a natural extension is to replace the Cr in the ZnCr oxide catalyst with Mo and W, both in the same elemental triad with Cr. Mo has already been shown as an active HAS catalyst, both on a SiO{sub 2} support and in the MoS{sub 2} form. The three catalyst combinations, ZnMo, ZnW, and MnCr oxides will be tested in the stirred autoclave system. However, if none of the three indicate any comparable activity and/or selectivity toward higher alcohols as compared with other HAS catalysts, then an investigation of the effects of Cs promotion on the ZnCr oxide methanol catalysts will be executed.

  9. ENVIRONMENTAL BIOTECHNOLOGY 6:2 Fluorotelomer alcohol (6:2 FTOH) biodegradation

    E-Print Network [OSTI]

    Chu, Kung-Hui "Bella"

    ENVIRONMENTAL BIOTECHNOLOGY 6:2 Fluorotelomer alcohol (6:2 FTOH) biodegradation by multiple of 6:2 FTOH has been studied in various environmental matrices such as soils, sediment, and activated pathway I to produce Electronic supplementary material The online version of this article (doi:10.1007/s

  10. WASHINGTON AND LEE UNIVERSITY GUIDELINES FOR ON-CAMPUS SERVING OF ALCOHOL

    E-Print Network [OSTI]

    Marsh, David

    of alcohol is judged an appropriate aspect of a University campus event, consider serving beer and wine and beer is preferred; hard liquor may be served if it is unlikely undergraduates will be present and after, wine, beer and hard liquor may be served. Private events at the President's home need no prior

  11. Exposure to the Taste of Alcohol Elicits Activation of the Mesocorticolimbic Neurocircuitry

    E-Print Network [OSTI]

    Banich, Marie T.

    . Neuropsychopharmacology (2008) 33, 1391­1401; doi:10.1038/sj.npp.1301513; published online 25 July 2007 Keywords: alcohol The construct of craving for substances of abuse by humans has often been defined as the strong desire or urge

  12. *Swinburne and the SSAA support responsible service of alcohol. Student ID card required for entry.

    E-Print Network [OSTI]

    Liley, David

    to have a drink*. Swinburne and SSAA suppport responsible service of alcohol. Lecture Theatre FBE - EN103 FLSS - EN413 Depart from Lecture Theatre The George and surrounds Lecture Theatre FBE - EN103 FLSS - EN413 Lecture Theatre FBE - EN103 FLSS - EN413 Lecture Theatre FBE - EN103 FLSS - EN413 O-Host Marquee

  13. alcohol-related brain damage: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alcohol-related brain damage First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Proteomics of the human...

  14. Vacuum-Ultraviolet Photoionization and Mass Spectrometric Characterization of Lignin Monomers Coniferyl and Sinapyl Alcohols

    SciTech Connect (OSTI)

    Takahashi, Lynelle K.; Zhou, Jia; Kostko, Oleg; Golan, Amir; Leone, Stephen R.; Ahmed, Musahid

    2011-02-09T23:59:59.000Z

    The fragmentation mechanisms of monolignols under various energetic processes are studied with jet-cooled thermal desorption molecular beam (TDMB) mass spectrometry (MS), 25 keV Bi3+ secondary ion MS (SIMS), synchrotron vacuum-ultraviolet secondary neutral MS (VUV-SNMS) and theoretical methods. Experimental and calculated appearance energies of fragments observed in TDMB MS indicate that the coniferyl alcohol photoionization mass spectra contain the molecular parent and several dissociative photoionization products. Similar results obtained for sinapyl alcohol are also discussed briefly. Ionization energies of 7.60 eV ? 0.05 eV for coniferyl alcohol and<7.4 eV for both sinapyl and dihydrosinapyl alcohols are determined. The positive ion SIMS spectrum of coniferyl alcohol shares few characteristic peaks (m/z = 137 and 151) with the TDMB mass spectra, shows extensive fragmentation, and does not exhibit clear molecular parent signals. VUV-SNMS spectra, on the other hand, are dominated by the parent ion and main fragments also present in the TDMB spectra. Molecular fragmentation in VUV-SNMS spectra can be reduced by increasing the extraction delay time. Some features resembling the SIMS spectra are also observed in the desorbed neutral products. The monolignol VUV-SNMS peaks shared with the TDMB mass spectra suggest that dissociative photoionization of ion-sputtered neutral molecules predominate in the VUV-SNMS mass spectra, despite the extra internal energy imparted in the initial ion impact. The potential applications of these results to imaging mass spectrometry of bio-molecules are discussed.

  15. A Single Phosphine Ligand Allows Palladium-Catalyzed Intermolecular C-O Bond Formation with Secondary and Primary Alcohols

    E-Print Network [OSTI]

    Wu, Xiaoxing

    Forging a bond: An efficient, general palladium catalyst for C-O bond-forming reactions of secondary and primary alcohols with a range of aryl halides has been developed using the ligand 1. Heteroaryl halides, and for the ...

  16. Preventive effects of Flos Perariae (Gehua) water extract and its active ingredient puerarin in rodent alcoholism models

    E-Print Network [OSTI]

    Zhang, Zaijun; Li, Sha; Jiang, Jie; Yu, Pei; Liang, Jing; Wang, Yuqiang

    2010-01-01T23:59:59.000Z

    536. 9. Keung WM, Vallee BL: Kudzu root: an ancient Chineseof the Chinese herbal root kudzu reduces alcohol drinking byMcGregor NR: Pueraria lobata (Kudzu root) hangover remedies

  17. Effects of Concentration of Organically Modified Nanoclay on Properties of Sulfonated Poly(vinyl alcohol) Nanocomposite Membranes

    E-Print Network [OSTI]

    Sanglimsuwan, Apiradee

    Electrolyte nanocomposite membranes for proton exchange membrane fuel cells and direct methanol fuel cells were prepared by carrying out a sulfonation of poly(vinyl alcohol) with sulfosuccinic acid and adding a type of ...

  18. Factors affecting alcohol treatment in males: an estimation of gender-role issues, self-concept, and psychiatric symptomatology

    E-Print Network [OSTI]

    Clark, Betty Lynn

    1993-01-01T23:59:59.000Z

    FACTORS AFFECTING ALCOHOL TREATMENT IN MALES: AN EXAMINATION OF GENDER ROLE ISSUES ~ SELF CONCEPT AND PSYCHIATRIC SYMPTOMATOLOGY A Thesis by BETTY LYNN CLARK Submitted to the Office of Graduate Studies of Texas A&M University in partial... fulfillment of the requirements for the degree MASTER OF SCIENCE August 1993 Major Subject: Psychology FACTORS AFFECTING ALCOHOL TREATMENT IN MALES: AN EXAMINATION OF GENDER-ROLE ISSUES, SELF-CONCEPT, AND PSYCHIATRIC SYMPTOMATOLOGY A Thesis by BETTY...

  19. Mechanisms of alcohol-induced neuroteratology: an examination of the roles of fetal cerebral blood flow and hypoxia

    E-Print Network [OSTI]

    Parnell, Scott Edward

    2005-02-17T23:59:59.000Z

    MECHANISMS OF ALCOHOL-INDUCED NEUROTERATOLOGY: AN EXAMINATION OF THE ROLES OF FETAL CEREBRAL BLOOD FLOW AND HYPOXIA A Dissertation by SCOTT EDWARD PARNELL Submitted to the Office of Graduate Studies of Texas A...&M University in partial fulfillment of the requirements for the degree of DOCTOR OF PHILOSOPHY December 2004 Major Subject: Medical Sciences MECHANISMS OF ALCOHOL-INDUCED NEUROTERATOLOGY: AN EXAMINATION OF THE ROLES...

  20. Nuclear magnetic resonance (N.M.R.) studies of alkyl formates and of alcohol-water azeotropes

    E-Print Network [OSTI]

    O'Brien, Patrick William

    1966-01-01T23:59:59.000Z

    NUCLEAR MAGNETIC RESONANCE (N. M. R. ) STUDIES OF ALKYL FORMATES AND OF ALCOHOL-WATER AZEOTROPES A Thesis By PATRICK WILLIAM O' BRIEN Submitted to the Graduate College of the Texas ASM University in partial fulfillment of the requirements... for the degree of MASTER OF SCIENCE January 1966 Major Subject: Chemistry NUCLEAR MAGNETIC RESONANCE (N. M. R. ) STUDIES OF ALKYL FORMATES AND OF ALCOHOL-WATER AZEOTROPES A Thesis By PATRICK WILLIAM O' BRIEN Approved as to style and content by...

  1. Extraction of Cs-137 by alcohol-water solvents from plants containing cardiac glycosides

    E-Print Network [OSTI]

    Dzyubak, S N; Dzyubak, O P; Sorokin, P V; Popov, V F; Orlov, A A; Krasnov, V P; Gubin, Yu.I.

    2001-01-01T23:59:59.000Z

    As a result of nuclear power plant accidents, large areas receive radioactive inputs of Cs-137. This cesium accumulates in herbs growing in such territories. The problem is whether the herbs contaminated by radiocesium may be used as a raw material for medicine. The answer depends on the amount of Cs-137 transfered from the contaminated raw material to the medicine. We have presented new results of the transfer of Cs-137 from contaminated Digitalis grandiflora Mill. and Convallaria majalis L. to medicine. We found that the extraction of Cs-137 depends strongly on the hydrophilicity of the solvent. For example 96.5%(vol.) ethyl alcohol extracts less Cs-137 (11.6%) than 40%(vol.) ethyl alcohol or pure water (66.2%). The solubility of the cardiac glycosides is inverse to the solubility of cesium, which may be of use in the technological processes for manufacturing ecologically pure herbal medicine.

  2. Nickel Phosphine Catalysts with Pendant Amines for Electrocatalytic Oxidation of Alcohols

    SciTech Connect (OSTI)

    Weiss, Charles J.; Wiedner, Eric S.; Roberts, John A.; Appel, Aaron M.

    2015-01-01T23:59:59.000Z

    Nickel phosphine complexes with pendant amines have been found to be electrocatalysts for the oxidation of primary and secondary alcohols, with turnover frequencies as high as 3.3 s-1. These complexes are the first electrocatalysts for alcohol oxidation based on non-precious metals, which will be critical for use in fuel cells. The research by CJW, ESW, and AMA was supported by the US Department of Energy, Office of Science, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences & Biosciences. The research by JASR was supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science. Pacific Northwest National Laboratory is operated by Battelle for the US Department of Energy.

  3. Mild and selective vanadium-catalyzed oxidation of benzylic, allylic, and propargylic alcohols using air

    DOE Patents [OSTI]

    Hanson, Susan Kloek; Silks, Louis A; Wu, Ruilian

    2013-08-27T23:59:59.000Z

    The invention concerns processes for oxidizing an alcohol to produce a carbonyl compound. The processes comprise contacting the alcohol with (i) a gaseous mixture comprising oxygen; and (ii) an amine compound in the presence of a catalyst, having the formula: ##STR00001## where each of R.sup.1-R.sup.12 are independently H, alkyl, aryl, CF.sub.3, halogen, OR.sup.13, SO.sub.3R.sup.14, C(O)R.sup.15, CONR.sup.16R.sup.17 or CO.sub.2R.sup.18; each of R.sup.13-R.sup.18 is independently alkyl or aryl; and Z is alkl or aryl.

  4. Hydrogenolysis of 5-carbon sugars, sugar alcohols, and methods of making propylene glycol

    DOE Patents [OSTI]

    Werpy, Todd A [West Richland, WA; Zacher, Alan H [Kennewick, WA

    2006-05-02T23:59:59.000Z

    Methods and compositions for reactions of hydrogen over a Re-containing catalyst with compositions containing a 5-carbon sugar, sugar alcohol, or lactic acid are described. It has been surprisingly discovered that reaction with hydrogen over a Re-containing multimetallic catalyst resulted in superior conversion and selectivity to desired products such as propylene glycol. A process for the synthesis of PG from lactate or lactic acid is also described.

  5. Hydrogenolysis Of 5-Carbon Sugars, Sugar Alcohols And Compositions For Reactions Involving Hydrogen

    DOE Patents [OSTI]

    Werpy, Todd A. (West Richland, WA); Frye, Jr., John G. (Richland, WA); Zacher, Alan H. (Kennewick, WA); Miller, Dennis J. (Okemos, MI)

    2004-01-13T23:59:59.000Z

    Methods and compositions for reactions of hydrogen over a Re-containing catalyst with compositions containing a 5-carbon sugar, sugar alcohol, or lactic acid are described. It has been surprisingly discovered that reaction with hydrogen over a Re-containing multimetallic catalyst resulted in superior conversion and selectivity to desired products such as propylene glycol. A process for the synthesis of PG from lactate or lactic acid is also described.

  6. Hydrogenolysis of 5-carbon sugars, sugar alcohols, and other methods and compositions for reactions involving hydrogen

    DOE Patents [OSTI]

    Werpy, Todd A [West Richland, WA; Zacher, Alan H [Kennewick, WA

    2002-11-12T23:59:59.000Z

    Methods and compositions for reactions of hydrogen over a Re-containing catalyst with compositions containing a 5-carbon sugar, sugar alcohol, or lactic acid are described. It has been surprisingly discovered that reaction with hydrogen over a Re-containing multimetallic catalyst resulted in superior conversion and selectivity to desired products such as propylene glycol. A process for the synthesis of PG from lactate or lactic acid is also described.

  7. Nuclear magnetic resonance measurements reveal the origin of the Debye process in monohydroxy alcohols

    E-Print Network [OSTI]

    C. Gainaru; R. Meier; S. Schildmann; C. Lederle; W. Hiller; E. A. Rössler; R. Böhmer

    2010-09-03T23:59:59.000Z

    Monohydroxy alcohols show a structural relaxation and at longer time scales a Debye-type dielectric peak. From spin-lattice relaxation experiments using different nuclear probes an intermediate, slower-than-structural dynamics is identified for n-butanol. Based on these findings and on diffusion measurements, a model of self-restructuring, transient chains is proposed. The model is demonstrated to explain consistently the so far puzzling observations made for this class of hydrogen-bonded glass forming liquids.

  8. Reaction of bisarenyl, cyclopentadienyl, and carbonyl transition metal compounds with polyhydric alcohols

    SciTech Connect (OSTI)

    Slushkov, A.M.; Petrov, B.I.; Domrachev, G.A.

    1987-08-20T23:59:59.000Z

    It is shown that the thermally stable (to 300-400/sup 0/C) transition metal glycolates, glycerates, and pinacolates could be obtained from bisarenyl, cyclopentadienyl, and carbonyl metal compounds by reaction with polymeric alcohols. At 150-180/sup 0/C monomeric compounds are formed; these are converted to polymeric products above 200/sup 0/C. When two glycolates react with various metals or when glycolates react with organometallic compounds, new, mixed complexes of a polymeric nature are obtained.

  9. Correlation between speciated hydrocarbon emissions and flame ionization detector response for gasoline/alcohol blends .

    SciTech Connect (OSTI)

    Wallner, T. (Energy Systems)

    2011-08-01T23:59:59.000Z

    The U.S. renewable fuel standard has made it a requirement to increase the production of ethanol and advanced biofuels to 36 billion by 2022. Ethanol will be capped at 15 billion, which leaves 21 billion to come from other sources such as butanol. Butanol has a higher energy density and lower affinity for water than ethanol. Moreover, alcohol fueled engines in general have been shown to positively affect engine-out emissions of oxides of nitrogen and carbon monoxide compared with their gasoline fueled counterparts. In light of these developments, the variety and blend levels of oxygenated constituents is likely to increase in the foreseeable future. The effect on engine-out emissions for total hydrocarbons is less clear due to the relative insensitivity of the flame ionization detector (FID) toward alcohols and aldehydes. It is well documented that hydrocarbon (HC) measurement using a conventional FID in the presence of oxygenates in the engine exhaust stream can lead to a misinterpretation of HC emissions trends for alcohol fuel blends. Characterization of the exhaust stream for all expected hydrocarbon constituents is required to accurately determine the actual concentration of unburned fuel components in the exhaust. In addition to a conventional exhaust emissions bench, this characterization requires supplementary instrumentation capable of hydrocarbon speciation and response factor independent quantification. Although required for certification testing, this sort of instrumentation is not yet widely available in engine development facilities. Therefore, an attempt is made to empirically determine FID correction factors for oxygenate fuels. Exhaust emissions of an engine fueled with several blends of gasoline and ethanol, n-butanol and iso-Butanol were characterized using both a conventional FID and a Fourier transform infrared. Based on these results, a response factor predicting the actual hydrocarbon emissions based solely on FID results as a function of alcohol type and content is presented. Finally, the correlation derived from data presented in this study is compared with equations and results found in the literature.

  10. Intermediate Alcohol-Gasoline Blends, Fuels for Enabling Increased Engine Efficiency and Powertrain Possibilities

    SciTech Connect (OSTI)

    Splitter, Derek A [ORNL] [ORNL; Szybist, James P [ORNL] [ORNL

    2014-01-01T23:59:59.000Z

    The present study experimentally investigates spark-ignited combustion with 87 AKI E0 gasoline in its neat form and in mid-level alcohol-gasoline blends with 24% vol./vol. iso-butanol-gasoline (IB24) and 30% vol./vol. ethanol-gasoline (E30). A single-cylinder research engine is used with a low and high compression ratio of 9.2:1 and 11.85:1 respectively. The engine is equipped with hydraulically actuated valves, laboratory intake air, and is capable of external exhaust gas recirculation (EGR). All fuels are operated to full-load conditions with =1, using both 0% and 15% external cooled EGR. The results demonstrate that higher octane number bio-fuels better utilize higher compression ratios with high stoichiometric torque capability. Specifically, the unique properties of ethanol enabled a doubling of the stoichiometric torque capability with the 11.85:1 compression ratio using E30 as compared to 87 AKI, up to 20 bar IMEPg at =1 (with 15% EGR, 18.5 bar with 0% EGR). EGR was shown to provide thermodynamic advantages with all fuels. The results demonstrate that E30 may further the downsizing and downspeeding of engines by achieving increased low speed torque, even with high compression ratios. The results suggest that at mid-level alcohol-gasoline blends, engine and vehicle optimization can offset the reduced fuel energy content of alcohol-gasoline blends, and likely reduce vehicle fuel consumption and tailpipe CO2 emissions.

  11. Oxidation, Reduction, and Condensation of Alcohols over (MO3)3 (M=Mo, W) Nanoclusters

    SciTech Connect (OSTI)

    Fang, Zongtang; Li, Zhenjun; Kelley, Matthew S.; Kay, Bruce D.; Li, Shenggang; Hennigan, Jamie M.; Rousseau, Roger J.; Dohnalek, Zdenek; Dixon, David A.

    2014-10-02T23:59:59.000Z

    The reactions of deuterated methanol, ethanol, 1-propanol, 1-butanol, 2-propanol, 2-butanol and t-butanol over cyclic (MO3)3 (M = Mo, W) clusters were studied experimentally with temperature programmed desorption (TPD) and theoretically with coupled cluster CCSD(T) theory and density functional theory. The reactions of two alcohols per M3O9 cluster are required to provide agreement with experiment for D2O release, dehydrogenation and dehydration. The reaction begins with the elimination of water by proton transfers and forms an intermediate dialkoxy species which can undergo further reaction. Dehydration proceeds by a ? hydrogen transfer to a terminal M=O. Dehydrogenation takes place via an ? hydrogen transfer to an adjacent MoVI = O atom or a WVI metal center with redox involved for M = Mo and no redox for M = W. The two channels have comparable activation energies. H/D exchange to produce alcohols can take place after olefin is released or via the dialkoxy species depending on the alcohol and the cluster. The Lewis acidity of the metal center with WVI being larger than MoVI results in the increased reactivity of W3O9 over Mo3O9 for dehydrogenation and dehydration.

  12. Potential impact of Thailand's alcohol program on production, consumption, and trade of cassava, sugarcane, and corn

    SciTech Connect (OSTI)

    Boonserm, P.

    1985-01-01T23:59:59.000Z

    On the first of May 1980, Thailand's fuel-alcohol program was announced by the Thai government. According to the program, a target of 147 million liters of ethanol would be produced in 1981, from cassava, sugarcane, and other biomasses. Projecting increases in output each year, the target level of ethanol produciton was set at 482 million liters of ethanol for 1986. The proposed amount of ethanol production could create a major shift up in the demand schedule of energy crops such as cassava, sugarcane, and corn. The extent of the adjustments in price, production, consumption, and exports for these energy crops need to be evaluated. The purpose of this study is to assess the potential impact of Thailand's fuel-alcohol program on price, production, consumption, and exports of three potential energy crops: cassava, sugarcane, and corn. Econometric commodity models of cassava, sugarcane, and corn are constructed and used as a method of assessment. The overall results of the forecasting simulations of the models indicate that the fuel-alcohol program proposed by the Thai government will cause the price, production, and total consumption of cassava, sugarcane, and corn to increase; on the other hand, it will cause exports to decline. In addition, based on the relative prices and the technical coefficients of ethanol production of these three energy crops, this study concludes that only cassava should be used to produce the proposed target of ethanol production.

  13. Activation of farnesoid X receptor attenuates hepatic injury in a murine model of alcoholic liver disease

    SciTech Connect (OSTI)

    Wu, Weibin [Department of Biochemistry and Molecular Biology, Shanghai Medical College, Fudan University, Shanghai 200032 (China) [Department of Biochemistry and Molecular Biology, Shanghai Medical College, Fudan University, Shanghai 200032 (China); Institutes of Biomedical Science, Fudan University, Shanghai 200032 (China); Zhu, Bo; Peng, Xiaomin [Department of Biochemistry and Molecular Biology, Shanghai Medical College, Fudan University, Shanghai 200032 (China)] [Department of Biochemistry and Molecular Biology, Shanghai Medical College, Fudan University, Shanghai 200032 (China); Zhou, Meiling, E-mail: meilingzhou2012@gmail.com [Department of Radiology, Zhongshan Hospital of Fudan University and Shanghai Institute of Medical Imaging, Shanghai 200032 (China)] [Department of Radiology, Zhongshan Hospital of Fudan University and Shanghai Institute of Medical Imaging, Shanghai 200032 (China); Jia, Dongwei, E-mail: jiadongwei@fudan.edu.cn [Department of Biochemistry and Molecular Biology, Shanghai Medical College, Fudan University, Shanghai 200032 (China)] [Department of Biochemistry and Molecular Biology, Shanghai Medical College, Fudan University, Shanghai 200032 (China); Gu, Jianxin [Department of Biochemistry and Molecular Biology, Shanghai Medical College, Fudan University, Shanghai 200032 (China) [Department of Biochemistry and Molecular Biology, Shanghai Medical College, Fudan University, Shanghai 200032 (China); Institutes of Biomedical Science, Fudan University, Shanghai 200032 (China)

    2014-01-03T23:59:59.000Z

    Highlights: •FXR activity was impaired by chronic ethanol ingestion in a murine model of ALD. •Activation of FXR attenuated alcohol-induced liver injury and steatosis. •Activation of FXR attenuated cholestasis and oxidative stress in mouse liver. -- Abstract: Alcoholic liver disease (ALD) is a common cause of advanced liver disease, and considered as a major risk factor of morbidity and mortality worldwide. Hepatic cholestasis is a pathophysiological feature observed in all stages of ALD. The farnesoid X receptor (FXR) is a member of the nuclear hormone receptor superfamily, and plays an essential role in the regulation of bile acid, lipid and glucose homeostasis. However, the role of FXR in the pathogenesis and progression of ALD remains largely unknown. Mice were fed Lieber-DeCarli ethanol diet or an isocaloric control diet. We used a specific agonist of FXR WAY-362450 to study the effect of pharmacological activation of FXR in alcoholic liver disease. In this study, we demonstrated that FXR activity was impaired by chronic ethanol ingestion in a murine model of ALD. Activation of FXR by specific agonist WAY-362450 protected mice from the development of ALD. We also found that WAY-362450 treatment rescued FXR activity, suppressed ethanol-induced Cyp2e1 up-regulation and attenuated oxidative stress in liver. Our results highlight a key role of FXR in the modulation of ALD development, and propose specific FXR agonists for the treatment of ALD patients.

  14. Method and system for producing lower alcohols. [Heteropolyatomic lead salt coated with alkali metal formate

    DOE Patents [OSTI]

    Rathke, J.W.; Klingler, R.J.; Heiberger, J.J.

    1983-09-26T23:59:59.000Z

    It is an object of the present invention to provide an improved catalyst for the reaction of carbon monoxide with water to produce methanol and other lower alcohols. It is a further object to provide a process for the production of methanol from carbon monoxide and water in which a relatively inexpensive catalyst permits the reaction at low pressures. It is also an object to provide a process for the production of methanol from carbon monoxide and water in which a relatively inexpensive catalyst permits the reaction at low pressures. It is also an object to provide a process for the production of methanol in which ethanol is also directly produced. It is another object to provide a process for the production of mixtures of methanol with ethanol and propanol from the reaction of carbon monoxide and water at moderate pressure with inexpensive catalysts. It is likewise an object to provide a system for the catalytic production of lower alcohols from the reaction of carbon monoxide and water at moderate pressure with inexpensive catalysts. In accordance with the present invention, a catalyst is provided for the reaction of carbon monoxide and water to produce lower alcohols. The catalyst includes a lead heteropolyatomic salt in mixture with a metal formate or a precursor to a metal formate.

  15. Catalytic Oxidation of Alcohol via Nickel Phosphine Complexes with Pendant Amines

    SciTech Connect (OSTI)

    Weiss, Charles J.; Das, Partha Pratim; Higgins, Deanna LM; Helm, Monte L.; Appel, Aaron M.

    2014-09-05T23:59:59.000Z

    Nickel complexes were prepared with diphosphine ligands that contain pendant amines, and these complexes catalytically oxidize primary and secondary alcohols to their respective aldehydes and ketones. Kinetic and mechanistic studies of these prospective electrocatalysts were performed to understand what influences the catalytic activity. For the oxidation of diphenylmethanol, the catalytic rates were determined to be dependent on the concentration of both the catalyst and the alcohol. The catalytic rates were found to be independent of the concentration of base and oxidant. The incorporation of pendant amines to the phosphine ligand results in substantial increases in the rate of alcohol oxidation with more electron-donating substituents on the pendant amine exhibiting the fastest rates. We thank Dr. John C. Linehan, Dr. Elliott B. Hulley, Dr. Jonathan M. Darmon, and Dr. Elizabeth L. Tyson for helpful discussions. Research by CJW, PD, DLM, and AMA was supported by the US Department of Energy, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences & Biosciences. Research by MLH was supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Basic Energy Sciences. Pacific Northwest National Laboratory (PNNL) is a multiprogram national laboratory operated for DOE by Battelle.

  16. Role of alkyl alcohol on viscosity of silica-based chemical gels for decontamination of highly radioactive nuclear facilities

    SciTech Connect (OSTI)

    Choi, B. S.; Yoon, S. B.; Jung, C. H.; Lee, K. W.; Moon, J. K. [Div. of Decontamination and Decommissioning Technology Development, Korea Atomic Energy Research Inst., Daedeok-daero 989-111, Yuseong-gu, Daejeon, 305-353 (Korea, Republic of)

    2012-07-01T23:59:59.000Z

    Silica-based chemical gel for the decontamination of nuclear facilities was prepared by using fumed silica as a viscosifier, a 0.5 M Ce (IV) solution dissolved in concentrated nitric acid as a chemical decontamination agent, and tripropylene glycol butyl ether (TPGBE) as a co-viscosifier. A new effective strategy for the preparation of the chemical gel was investigated by introducing the alkyl alcohols as organic solvents to effectively dissolve the co-viscosifier. The mixture solution of the co-viscosifier and alkyl alcohols was more effective in the control of viscosity than that of the co-viscosifier only in gel. Here, the alkyl alcohols played a key role as an effective dissolution solvent for the co-viscosifier in the preparation of the chemical gel, resulting in a reducing of the amount of the co-viscosifier and gel time compared with that of the chemical gel prepared without the alkyl alcohols. It was considered that the alkyl alcohols contributed to the effective dissolution of the co-viscosifier as well as the homogeneous mixing in the formation of the gel, while the co-viscosifier in an aqueous media of the chemical decontamination agent solution showed a lower solubility. The decontamination efficiency of the chemical gels prepared in this work using a multi-channel analyzer (MCA) showed a high decontamination efficiency of over ca. 94% and ca. 92% for Co-60 and Cs-137 contaminated on surface of the stainless steel 304, respectively. (authors)

  17. Hydrogen-bond equilibria and life times in a supercooled monohydroxy alcohol

    E-Print Network [OSTI]

    C. Gainaru; S. Kastner; F. Mayr; P. Lunkenheimer; S. Schildmann; H. J. Weber; W. Hiller; A. Loidl; R. Böhmer

    2011-06-29T23:59:59.000Z

    Dielectric loss spectra covering 13 decades in frequency were collected for 2-ethyl-1-hexanol, a monohydroxy alcohol that exhibits a prominent Debye-like relaxation, typical for several classes of hydrogen-bonded liquids. The thermal variation of the dielectric absorption amplitude agrees well with that of the hydrogen-bond equilibrium population, experimentally mapped out using near infrared (NIR) and nuclear magnetic resonance (NMR) measurements. Despite this agreement, temperature-jump NIR spectroscopy reveals that the hydrogen-bond switching rate does not define the frequency position of the prominent absorption peak. This contrasts with widespread notions and models based thereon, but is consistent with a recent approach.

  18. Transpiration and water use by cotton plants as affected by the soil application of fatty alcohols 

    E-Print Network [OSTI]

    Rhoads, Frederick Milton

    1963-01-01T23:59:59.000Z

    on tz snspl: ' icn cont~ oi is almost non-existent for cotton. The reseat'ch zepo 'ted berin is one. pa. -. of a joint resea h program which is being conducred by t?e Texas Agriculcur=l Experimen Station and the Procter and Gamble Company fo. de... the fatty alcohols were incuba ed in moist soil for the pre- scribed length of time, the soil was dried in an oven, pulverized by grind- ing, placed in marked containers, and shipped to lfr. heal Thompson, of The Procter and Gamble Company (Pecos, Texas...

  19. Investigations on alcohol production and yeast growth as influenced by media conditions

    E-Print Network [OSTI]

    Uddoulah, Md. Seraj

    1961-01-01T23:59:59.000Z

    of 0. 1M acidity per pound of fermented mash. TABLE VIII Yield of Acetone Dried Yeast Cells Grown on Molasses Medium Medica pH Citric Acid psr cent Yeast Yield gas 1 SSrrsIL~a on'~ f~Ye s 1 s Moisture Ash Protein per oant, per cent psr cant... 31 CHAPTER I INTRODUCTION The research investigations presented in this thesis represent a study of the influence of chelating or sequestering agents on the ethyl alcohol fermentation process. Conventional fermentation processes...

  20. Transition-metal pi-complexes of vinyl alcohol: platinum and palladium

    E-Print Network [OSTI]

    Ori, Masaru

    1971-01-01T23:59:59.000Z

    -necked flask, equipped wi th a con- denser with a drying tube on the top, dry mercuric di- acetaldehyde (40 g, 0. 147 mol) was suspended under argon in dry ether (70 ml) containing the freshly distilled N, N-dimethyl aniline (1. Z g, 0. 01 mol ). Under a... )platinum(I I) was prepared by hydrolyzing the x-trimethylsilyl vinyl ether complex, which was obtained by treating the ethyl- ene complex with trimethylsilyl vinyl ether. The vinyl alcohol complex was characterized by nmr, ir, molecular weight...

  1. High octane ethers from synthesis gas-derived alcohols. Quarterly technical progress report, April--June 1993

    SciTech Connect (OSTI)

    Klier, K.; Herman, R.G.; Menszak, J.; Johansson, M.A.; Feeley, O.C.; Kim, D.

    1993-07-01T23:59:59.000Z

    The results shown in Figures 10 and 11 demonstrate that the formation of butenes was very sensitive to the alcohol partial pressure. A small elevation of the alcohol pressure suppressed the formation of butenes rather drastically at both 90 and 117{degree}C. The synthesis rates of DME, MIBE, and MTBE ethers were not significantly affected at 90{degree}C, although there was a trend to increase the space time yield of DME as the alcohol pressure was increased. At the reaction temperature of 117{degree}C, all of the ethers showed increasing productivities as the pressure of the reactants was increased (Figure 11). An isotope labelling experiment was carried out to provide mechanistic insight into the manner in which methanol and isobutanol react together to form DME, MIBE, and MTBE ethers and to determine if MTBE were derived from MIBE.

  2. Ascorbic acid suppresses endotoxemia and NF-?B signaling cascade in alcoholic liver fibrosis in guinea pigs: A mechanistic approach

    SciTech Connect (OSTI)

    Abhilash, P.A.; Harikrishnan, R.; Indira, M., E-mail: indiramadambath@gmail.com

    2014-01-15T23:59:59.000Z

    Alcohol consumption increases the small intestinal bacterial overgrowth (SIBO) and intestinal permeability of endotoxin. The endotoxin mediated inflammatory signaling plays a major role in alcoholic liver fibrosis. We evaluated the effect of ascorbic acid (AA), silymarin and alcohol abstention on the alcohol induced endotoxemia and NF-?B activation cascade pathway in guinea pigs (Cavia porcellus). Guinea pigs were administered ethanol at a daily dose of 4 g/kg b.wt for 90 days. After 90 days, ethanol administration was stopped. The ethanol treated animals were divided into abstention, silymarin (250 mg/kg b.wt) and AA (250 mg/kg b.wt) supplemented groups and maintained for 30 days. The SIBO, intestinal permeability and endotoxin were significantly increased in the ethanol group. The mRNA expressions of intestinal proteins claudin, occludin and zona occludens-1 were significantly decreased in ethanol group. The mRNA levels of inflammatory receptors, activity of IKK? and the protein expressions of phospho-I?B?, NF-?B, TNF-?, TGF-?{sub 1} and IL-6 were also altered in ethanol group. The expressions of fibrosis markers ?-SMA, ?{sub 1} (I) collagen and sirius red staining in the liver revealed the induction of fibrosis. But the supplementation of AA could induce greater reduction of ethanol induced SIBO, intestinal barrier defects, NF-?B activation and liver fibrosis than silymarin. The possible mechanism may be the inhibitory effect of AA on SIBO, intestinal barrier defect and IKK?, which decreased the activation of NF-?B and synthesis of cytokines. This might have led to suppression of HSCs activation and liver fibrosis. - Highlights: • Alcohol increases intestinal bacterial overgrowth and permeability of endotoxin. • Endotoxin mediated inflammation plays a major role in alcoholic liver fibrosis. • Ascorbic acid reduces endotoxemia, NF-?B activation and proinflammatory cytokines. • AA's action is by inhibition of SIBO, IKK? and alteration of intestinal permeability. • This might have led to suppression of HSCs activation and liver fibrosis.

  3. Supersonic Jet Spectroscopic Study of p-Methoxybenzyl Alcohol Min-Chul Yoon, Sun Jong Baek, Hyeongjin Cho, Young S. Choi, and Sang Kyu Kim*

    E-Print Network [OSTI]

    Kim, Sang Kyu

    Supersonic Jet Spectroscopic Study of p-Methoxybenzyl Alcohol Min-Chul Yoon, Sun Jong Baek0 excitation spectra of p-methoxybenzyl alcohol in a supersonic jet are reported. The long in the jet. The torsional barrier height of 316 cm-1 in the S1 ground-vibrational state is obtained from

  4. Estimating changes in the mechanical properties of the femur in the adult and aged rat due to adult-onset alcohol consumption

    E-Print Network [OSTI]

    Nguyen, Lyndon Phuoc

    2001-01-01T23:59:59.000Z

    Numerous studies have shown that alcohol has a disturbing effect on the mechanical properties of the skeleton. To determine whether alcohol has a deleterious effect on the adult skeleton, fifty-four, nine-month old, female Sprague-Dawley rats were...

  5. Emission Spectroscopy of Dissociative Allyl Iodide and Allyl Alcohol Excited at 199.7 nm B. F. Parsons, D. E. Szpunar, and L. J. Butler*

    E-Print Network [OSTI]

    Butler, Laurie J.

    Emission Spectroscopy of Dissociative Allyl Iodide and Allyl Alcohol Excited at 199.7 nm B. F investigated the emission spectroscopy of allyl iodide, CH2dCHCH2I, and allyl alcohol, CH2dCHCH2- OH, excited). The emission spectrum is dominated by activity in the CH2 wag and the CdC stretch, reflecting the dynamics

  6. Alcohol and Drug Abuse Education Programs The University has developed a program to prevent the illicit use of drugs and the abuse of

    E-Print Network [OSTI]

    Escher, Christine

    Alcohol and Drug Abuse Education Programs The University has developed a program to prevent the illicit use of drugs and the abuse of alcohol by students and employees. The program provides services related to drug use and abuse including dissemination of informational materials, educational programs

  7. Syngas production by plasma treatments of alcohols, bio-oils and wood This article has been downloaded from IOPscience. Please scroll down to see the full text article.

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Syngas production by plasma treatments of alcohols, bio-oils and wood This article has been Contact us My IOPscience #12;Syngas production by plasma treatments of alcohols, bio-oils and wood K to recover energy from biomass. The Syngas produced from biomass can be used to power internal combustion

  8. Polymer Growth Rate in a Wire Chamber with Oxygen,Water, or Alcohol Gas Additives

    SciTech Connect (OSTI)

    Boyarski, Adam; /SLAC

    2008-07-02T23:59:59.000Z

    The rate of polymer growth on wires was measured in a wire chamber while the chamber was aged initially with helium-isobutane (80:20) gas, and then with either oxygen, water, or alcohol added to the gas. At the completion of the aging process for each gas mixture, the carbon content on the wires was measured in a SEM/EDX instrument. The same physical wires were used in all the gas mixtures, allowing measurement of polymer build up or polymer depletion by each gas additive. It is found that the rate of polymer growth is not changed by the presence of oxygen, water or alcohol. Conjecture that oxygen reduces breakdown by removing polymer deposits on field wires is negated by these measurements. Instead, it appears that the reduced breakdown is due to lower resistance in the polymer from oxygen ions being transported into the polymer. It is also observed that field wires bombarded by the electrons in the SEM and then placed back into the chamber show an abundance of single electrons being emitted, indicating that electron charge is stored in the polymer layer and that a high electric field is necessary to remove the charge.

  9. ALCOHOL FLUSHING FOR REMOVING DNAPL'S FROM CLAY AND SAND LAYERED AQUIFER SYSTEMS

    SciTech Connect (OSTI)

    N.J. Hayden; P. Padgett; C. Farrell; J. Diebold; X. Zhou; M. Hood

    1999-08-01T23:59:59.000Z

    Alcohol flushing, also called cosolvent flushing, is a relatively new in-situ remediation technology that shows promise for removing organic solvents from the soil and groundwater. Soil and groundwater contamination from organic solvents and petroleum products is one of the most serious and widespread environmental problems of our time. Most of the DOE facilities and inactive sites are experiencing soil and groundwater contamination from organic solvents. These water immiscible solvents have entered the subsurface from leaking underground storage tanks and piping, and from past waste handling and disposal practices such as leaking lagoons, holding ponds and landfills. In many cases, they have traveled hundreds of feet down into the saturated zone. If left in the soil, these chemicals may pose a significant environmental and human health risk. Alcohol flushing has potential for application to spilled solvents located deep within the saturated zone which are difficult if not impossible to remove by current remediation strategies, thus, greatly expediting restoration time, reducing total remediation cost and reducing risk.

  10. The potential for alcohols and related ethers to displace conventional gasoline components

    SciTech Connect (OSTI)

    Hadder, G.R. [Oak Ridge National Lab., TN (United States); McNutt, B.D. [USDOE, Washington, DC (United States)

    1996-02-01T23:59:59.000Z

    The United States Department of Energy is required by law to determine the feasibility of producing sufficient replacement fuels to replace 30 percent of the projected United States consumption of motor fuels by light duty vehicles in the year 2010. A replacement fuel is a non-petroleum portion of gasoline, including alcohols, natural gas and certain other components. A linear program has been used to study refinery impacts for production of ``low petroleum`` gasolines, which contain replacement fuels. The analysis suggests that high oxygenation is the key to meeting the replacement fuel target, and major contributors to cost increase can include investment in processes to produce olefins for etherification with alcohols. High oxygenation can increase the costs of control of vapor pressure, distillation properties, and pollutant emissions of gasolines. Year-round low petroleum gasoline with near-30 percent non-petroleum might be produced with cost increases of 23 to 37 cents per gallon, with substantial decreases in greenhouse gas emissions in some cases. Cost estimates are sensitive to assumptions about extrapolation of a national model for pollutant emissions, availability of raw materials and other issues. Reduction in crude oil use, a major objective of the low petroleum gasoline program, is 10 to 17 percent in the analysis.

  11. Alcohol homologation

    DOE Patents [OSTI]

    Wegman, Richard W. (South Charleston, WV); Moloy, Kenneth G. (Charleston, WV)

    1988-01-01T23:59:59.000Z

    A process for the homologation of an alkanol by reaction with synthesis gas in contact with a system containing rhodium atom, ruthenium atom, iodine atom and a bis(diorganophosphino) alkane to selectivity produce the next higher homologue.

  12. Alcohol homologation

    DOE Patents [OSTI]

    Wegman, R.W.; Moloy, K.G.

    1988-02-23T23:59:59.000Z

    A process is described for the homologation of an alkanol by reaction with synthesis gas in contact with a system containing rhodium atom, ruthenium atom, iodine atom and a bis(diorganophosphino) alkane to selectivity produce the next higher homologue.

  13. C:\\Documents and Settings\\cfan\\Local Settings\\Temporary Internet Files\\Content.Outlook\\WAA5WMY7\\AODflyerSpring 2013.doc1/16/2013 CONCERNED ABOUT YOUR ALCOHOL OR DRUG USE?

    E-Print Network [OSTI]

    Kammen, Daniel M.

    \\AODflyerSpring 2013.doc1/16/2013 CONCERNED ABOUT YOUR ALCOHOL OR DRUG USE? Choose a Healthier Lifestyle effects from their alcohol or other drug use. Harm Reduction: Tuesdays, 4:10 ­ 6:00 pm. This group is for students who would like to make healthier decisions around their alcohol/drug use to minimize the negative

  14. High octane ethers from synthesis gas-derived alcohols. Quarterly technical progress report, April--June 1992

    SciTech Connect (OSTI)

    Klier, K.; Herman, R.G.; Feeley, O.C.; Johansson, M.A.

    1992-07-01T23:59:59.000Z

    The objective of the proposed research is to synthesize high octane ethers, primarily methyl isobutyl ether (MIBE) and methyl tertiary butyl ether (MTBE), directly from H{sub 2}/CO/CO{sub 2} coal-derived synthesis gas via alcohol mixtures that are rich in methanol and 2-methyl-l-propanol (isobutanol). The overall scheme involves gasification of coal, purification and shifting of the synthesis gas, higher alcohol synthesis, and direct synthesis of ethers. The last stage of the synthesis involves direct coupling of synthesis gas-derived methanol and isobutanol that has been demonstrated by us to occur over superacid catalysts to yield methyl isobutyl ether (MIBE) at moderate pressures and a mixture of methanol and isobutene at low pressures. MIBE is an isomer of MTBE and a process is proposed whereby MTBE from the two alcohols is maximized and MIBE is minimized. This will be achieved by the proper choice of reaction conditions, i.e. intermediate pressures, and of inorganic acid catalysts that are stable at temperatures higher than 200{degree}C, at which the carbonium ion reaction coupling of the two alcohols to MTBE is more effective than the oxonium ion or ester reaction coupling to MIBE. Both organic and inorganic catalysts will be investigated, and the better catalysts of these classes will be subjected to long term performance studies. The long term performance studies of the combined process will extend to 1000 hr and detailed analytical data for all products will be provided.

  15. Hydrogen Bond Breaking and Reformation in Alcohol Oligomers Following Vibrational Relaxation of a Non-Hydrogen-Bond Donating Hydroxyl Stretch

    E-Print Network [OSTI]

    Fayer, Michael D.

    Hydrogen Bond Breaking and Reformation in Alcohol Oligomers Following Vibrational Relaxation of a Non-Hydrogen-Bond Donating Hydroxyl Stretch K. J. Gaffney, I. R. Piletic, and M. D. Fayer* Department measured with ultrafast infrared pump-probe experiments. Non-hydrogen-bond donating OD stretches (2690 cm-1

  16. "Smoking Cessation Interventions and Program Availability for Drug and Alcohol Addicted Low Income Populations in Substance Abuse Treatment"

    E-Print Network [OSTI]

    Arnold, Jonathan

    "Smoking Cessation Interventions and Program Availability for Drug and Alcohol Addicted Low Income. The first aim examines longitudinally the availability of EBTs for smoking among those seeking treatment for co-occurring substance abuse and explores the predictors of changes in service availability over time

  17. CER4 Encodes an Alcohol-Forming Fatty Acyl-Coenzyme A Reductase Involved in Cuticular Wax Production

    E-Print Network [OSTI]

    Kunst, Ljerka

    CER4 Encodes an Alcohol-Forming Fatty Acyl-Coenzyme A Reductase Involved in Cuticular Wax surfaces of land plants. It is composed of a cutin polymer matrix and waxes. Cuticular waxes are complex and characterization of CER4, a wax bio- synthetic gene from Arabidopsis (Arabidopsis thaliana). Arabidopsis cer4

  18. Amino Alcohols as Ligands for Nickel-Catalyzed Suzuki Reactions of Unactivated Alkyl Halides, Including Secondary Alkyl Chlorides, with

    E-Print Network [OSTI]

    Fu, Gregory C.

    Amino Alcohols as Ligands for Nickel-Catalyzed Suzuki Reactions of Unactivated Alkyl Halides February 27, 2006; E-mail: gcf@mit.edu Early work in the area of palladium- and nickel-catalyzed cross of unactivated secondary alkyl halides is based on nickel/bathophenanthroline.4 This method can be applied

  19. Techno-Economics for Conversion of Lignocellulosic Biomass to Ethanol by Indirect Gasification and Mixed Alcohol Synthesis

    SciTech Connect (OSTI)

    Abhijit Dutta; Michael Talmadge; Jesse Hensley; Matt Worley; Doug Dudgeon; David Barton; Peter Groenendijk; Daniela Ferrari; Brien Stears; Erin Searcy; Christopher Wright; J. Richard Hess

    2012-07-01T23:59:59.000Z

    This techno-economic study investigates the production of ethanol and a higher alcohols coproduct by conversion of lignocelluosic biomass to syngas via indirect gasification followed by gas-to-liquids synthesis over a precommercial heterogeneous catalyst. The design specifies a processing capacity of 2,205 dry U.S. tons (2,000 dry metric tonnes) of woody biomass per day and incorporates 2012 research targets from NREL and other sources for technologies that will facilitate the future commercial production of cost-competitive ethanol. Major processes include indirect steam gasification, syngas cleanup, and catalytic synthesis of mixed alcohols, and ancillary processes include feed handling and drying, alcohol separation, steam and power generation, cooling water, and other operations support utilities. The design and analysis is based on research at NREL, other national laboratories, and The Dow Chemical Company, and it incorporates commercial technologies, process modeling using Aspen Plus software, equipment cost estimation, and discounted cash flow analysis. The design considers the economics of ethanol production assuming successful achievement of internal research targets and nth-plant costs and financing. The design yields 83.8 gallons of ethanol and 10.1 gallons of higher-molecular-weight alcohols per U.S. ton of biomass feedstock. A rigorous sensitivity analysis captures uncertainties in costs and plant performance.

  20. Diagram of the Biofuel Production Process (SPORL -Alcohol Production):Introduction: The Northwest Advanced Renewables Alliance (NARA) is an organization

    E-Print Network [OSTI]

    Collins, Gary S.

    Diagram of the Biofuel Production Process (SPORL - Alcohol Production):Introduction: The Northwest Advanced Renewables Alliance (NARA) is an organization that aims to create a sustainable aviation biofuels to determine the atmospheric emissions and emission sources that may be released from proposed NARA biofuels

  1. Comparing the effects of various fuel alcohols on the natural attenuation of Benzene Plumes using a general substrate interaction model

    E-Print Network [OSTI]

    Alvarez, Pedro J.

    and Environmental Engineering, Rice University, MS-317, 6100 Main St., Houston, TX 77005, USA a r t i c l e i n f o a b s t r a c t Article history: Received 30 October 2009 Received in revised form 26 January 2010 generalizations about the level of impact of specific fuel alcohols on benzene plume dynamics. © 2010 Elsevier B

  2. Did you know? Many health problems are either the result of or made worse by abuse of alcohol and/

    E-Print Network [OSTI]

    O'Toole, Alice J.

    abuse and dependency are medical conditions that can respond to medical treatment. There are physicians, called addictionologists, who specialize in the treatment of problematic use of alcohol and/or drugs to turn for help. Addictive substances produce changes in brain reward pathways, and these changes cause

  3. COMMUNITY RESOURCES ALCOHOL & OTHER DRUGS Akeela, Inc. 2804 Bering St., Anchorage 99503; 562-4556; www.akeela.org

    E-Print Network [OSTI]

    Pantaleone, Jim

    -4556; www.akeela.org Provides immediate care, aftercare, residential long-term treatment, and a large-5130. Provides immediate care, residential short-term treatment, day treatment. Booth Memorial Youth and Family and support groups for people with drug addictions. Elmendorf AFB Alcohol Drug Abuse Prevention Treatment

  4. Reconceptualising public acceptability: A study of the ways people respond to policies aimed to reduce alcohol consumption

    E-Print Network [OSTI]

    Cohn, Simon

    2015-03-13T23:59:59.000Z

    petrol with a bit of lemon juice in it’. Similarly, another describes how young people unable to purchase alcohol simply take up an alternative: There’s another side effect, is that some of the youth market will be tempted towards drugs which...

  5. The economical production of alcohol fuels from coal-derived synthesis gas: Case studies, design, and economics

    SciTech Connect (OSTI)

    NONE

    1995-10-01T23:59:59.000Z

    This project is a combination of process simulation and catalyst development aimed at identifying the most economical method for converting coal to syngas to linear higher alcohols to be used as oxygenated fuel additives. There are two tasks. The goal of Task 1 is to discover, study, and evaluate novel heterogeneous catalytic systems for the production of oxygenated fuel enhancers from synthesis gas, and to explore, analytically and on the bench scale, novel reactor and process concepts for use in converting syngas to liquid fuel products. The goal of Task 2 is to simulate, by computer, energy efficient and economically efficient processes for converting coal to energy (fuel alcohols and/or power). The primary focus is to convert syngas to fuel alcohols. This report contains results from Task 2. The first step for Task 2 was to develop computer simulations of alternative coal to syngas to linear higher alcohol processes, to evaluate and compare the economics and energy efficiency of these alternative processes, and to make a preliminary determination as to the most attractive process configuration. A benefit of this approach is that simulations will be debugged and available for use when Task 1 results are available. Seven cases were developed using different gasifier technologies, different methods for altering the H{sub 2}/CO ratio of the syngas to the desired 1.1/1, and with the higher alcohol fuel additives as primary products and as by-products of a power generation facility. Texaco, Shell, and Lurgi gasifier designs were used to test gasifying coal. Steam reforming of natural gas, sour gas shift conversion, or pressure swing adsorption were used to alter the H{sub 2}/CO ratio of the syngas. In addition, a case using only natural gas was prepared to compare coal and natural gas as a source of syngas.

  6. Liquid Fuel From Renewable Electricity and Bacteria: Electro-Autotrophic Synthesis of Higher Alcohols

    SciTech Connect (OSTI)

    None

    2010-07-01T23:59:59.000Z

    Electrofuels Project: UCLA is utilizing renewable electricity to power direct liquid fuel production in genetically engineered Ralstonia eutropha bacteria. UCLA is using renewable electricity to convert carbon dioxide into formic acid, a liquid soluble compound that delivers both carbon and energy to the bacteria. The bacteria are genetically engineered to convert the formic acid into liquid fuel—in this case alcohols such as butanol. The electricity required for the process can be generated from sunlight, wind, or other renewable energy sources. In fact, UCLA’s electricity-to-fuel system could be a more efficient way to utilize these renewable energy sources considering the energy density of liquid fuel is much higher than the energy density of other renewable energy storage options, such as batteries.

  7. Aerobic mineralization of MTBE and tert-butyl alcohol by stream-bed sediment microorganisms

    SciTech Connect (OSTI)

    Bradley, P.M.; Landmeyer, J.E.; Chapelle, F.H. [Geological Survey, Columbia, SC (United States)] [Geological Survey, Columbia, SC (United States)

    1999-06-01T23:59:59.000Z

    Microorganisms indigenous to the stream-bed sediments at two gasoline-contaminated groundwater sites demonstrated significant mineralization of the fuel oxygenates, methyl tert-butyl ether (MTBE) and tert-butyl alcohol (TBA). Up to 73% of [U-{sup 14}C]-MTBE and 84% of [U-{sup 14}C]-TBA were degraded to {sup 14}CO{sub 2} under mixed aerobic/anaerobic conditions. No significant mineralization was observed under strictly anaerobic conditions. The results indicate that, under the mixed aerobic/anaerobic conditions characteristic of stream-bed sediments, microbial processes may provide a significant environmental sink for MTBE and TBA delivered to surface water bodies by contaminated groundwater or by other sources.

  8. Optimization of Rhodium-Based Catalysts for Mixed Alcohol Synthesis – 2012 Progress Report

    SciTech Connect (OSTI)

    Gerber, Mark A.; Gray, Michel J.; Albrecht, Karl O.; Thompson, Becky L.

    2012-11-01T23:59:59.000Z

    Pacific Northwest National Laboratory has been conducting research to investigate the feasibility of producing mixed alcohols from biomass-derived synthesis gas (syngas). In recent years, this research has primarily involved the further development of catalysts containing rhodium and manganese based on the results of earlier catalyst screening tests. Testing continued in FY 2012 to further improve the Ir-promoted RhMn catalysts on both silica and carbon supports for producing mixed oxygenates from synthesis gas. This testing re-examined selected alternative silica and carbon supports to follow up on some uncertainties in the results with previous test results. Additional tests were conducted to further optimize the total and relative concentrations of Rh, Mn, and Ir, and to examine selected promoters and promoter combinations based on earlier results. To establish optimum operating conditions, the effects of the process pressure and the feed gas composition also were evaluated.

  9. Earlier effective monitoring of alcohol-fuels projects may have minimized problems

    SciTech Connect (OSTI)

    Not Available

    1982-04-23T23:59:59.000Z

    Although the Department of Energy's system for monitoring projects for the development and production of alcohol fuels now seems effective, it was not established until 7 months after some of the projects started and after major portions of them were conducted. This contributed to problems which may result in some projects not being completed after substantial portions of project funds were spent. GAO also found that 24 grantees scheduled to be paid on a reimbursable basis were erroneously advanced about $3 million. Of those grantees, only five returned a total of $378,110; and by the time the errors were detected, grantees had spent the balance of the funds advanced. Earlier effective monitoring may have detected the errors sooner, enabled more advances to be returned, and prevented a weakening of the Department's oversight and control over the projects. GAO makes recommendations which could help future projects from starting without effective monitoring.

  10. Endovascular Embolization of Visceral Artery Aneurysms with Ethylene-vinyl Alcohol (Onyx): A Case Series

    SciTech Connect (OSTI)

    Bratby, M.J.; Lehmann, E.D. [St. George's Hospital, Department of Radiology (United Kingdom); Bottomley, J.; Kessel, D.O.; Nicholson, A.A.; McPherson, S.J. [Leeds Teaching Hospitals NHS Trust, Department of Radiology (United Kingdom); Morgan, R.A.; Belli, A.-M. [St. George's Hospital, Department of Radiology (United Kingdom)], E-mail: Anna.Belli@stgeorges.nhs.uk

    2006-12-15T23:59:59.000Z

    We report the application of the liquid embolic agent ethylene-vinyl alcohol (Onyx; MicroTherapeutics, Irvine, CA, USA) in the management of visceral artery aneurysms. The technique and indications for using Onyx are discussed with emphasis on the management of wide-necked aneurysms and maintenance of patency of the parent vessel. None of the cases was considered suitable for stent-grafting or embolization with conventional agents. Two aneurysms of the renal artery bifurcation and one aneurysm of the inferior pancreaticoduodenal artery were treated. Following treatment there was complete exclusion of all aneurysms. There was no evidence of end-organ infarction. Follow-up with intervals up to 6 months has shown sustained aneurysm exclusion. Onyx is known to be effective in the management of intracranial aneurysms. Our experience demonstrates the efficacy and applicability of the use of Onyx in the treatment of complex visceral artery aneurysms.

  11. Feasibility study of fuel grade ethanol plant for Alcohol Fuels of Mississippi, Inc. , Vicksburg, Mississippi

    SciTech Connect (OSTI)

    None

    1981-01-01T23:59:59.000Z

    The results are presented of a feasibility study performed to determine the technical and economic viability of constructing an alcohol plant utilizing the N.Y.U. continuous acid hydrolysis process to convert wood wastes to fuel grade alcohol. The following is a summary of the results: (1) The proposed site in the Vicksburg Industrial Foundation Corporation Industrial Park is adequate from all standpoints, for all plant capacities envisioned. (2) Local hardwood sawmills can provide adequate feedstock for the facility. The price per dry ton varies between $5 and $15. (3) Sale of fuel ethanol would be made primarily through local distributors and an adequate market exists for the plant output. (4) With minor modifications to the preparation facilities, other waste cellulose materials can also be utilized. (5) There are no anticipated major environmental, health, safety or socioeconomic risks related to the construction and operation of the proposed facility. (6) The discounted cash flow and rate of return analysis indicated that the smallest capacity unit which should be built is the 16 million gallon per year plant, utilizing cogeneration. This facility has a 3.24 year payback. (7) The 25 million gallon per year plant utilizing cogeneration is an extremely attractive venture, with a zero interest break-even point of 1.87 years, and with a discounted rate of return of 73.6%. (8) While the smaller plant capacities are unattractive from a budgetary viewpoint, a prudent policy would dictate that a one million gallon per year plant be built first, as a demonstration facility. This volume contains process flowsheets and maps of the proposed site.

  12. Metabolism of C26 bile alcohols in the bullfrog, Rana catesbeiana

    SciTech Connect (OSTI)

    Noma, Y.; Kihira, K.; Kuramoto, T.; Hoshita, T.

    1988-03-01T23:59:59.000Z

    Metabolism of C26 bile alcohols in the bullfrog, Rana catesbeiana, was studied. (24-14C)-24-Dehydro-26-deoxy-5 beta-ranol (3 alpha,7 alpha,12 alpha-trihydroxy-27-nor-5 beta-cholestan-24-one) was chemically synthesized from (24-14C)cholic acid and incubated with bullfrog liver homogenate fortified with NADPH. 24-Dehydro-26-deoxy-5 beta-ranol was shown to be converted into both 26-deoxy-5 beta-ranol and 24-epi-26-deoxy-5 beta-ranol ((24S)- and (24R)-27-nor-5 beta-cholestane-3 alpha,7 alpha,12 alpha,24-tetrols) in addition to 5 beta-ranol ((24R)-27-nor-5 beta-cholestane-3 alpha,7 alpha,12 alpha,24,26-pentol), which is the major bile alcohol of the bullfrog. (24-3H)-26-Deoxy-5 beta-ranol and (24-3H)-24-epi-26-deoxy-5 beta-ranol were prepared from 24-dehydro-26-deoxy-5 beta-ranol by reduction with sodium (3H) borohydride and administered respectively to two each of four bullfrogs by intraperitoneal injection. After 24 h, labeled 5 beta-ranol was isolated from the bile of the bullfrogs that received (24-3H)-26-deoxy-5 beta-ranol. In contrast little if any radioactivity could be detected in 5 beta-ranol or its 24-epimer after administration of (24-3H)-24-epi-26-deoxy-5 beta-ranol.

  13. Investigation and demonstration of a rich combustor cold-start device for alcohol-fueled engines

    SciTech Connect (OSTI)

    Hodgson, J.W.; Irick, D.K. [Univ. of Tennessee, Knoxville, TN (United States)] [Univ. of Tennessee, Knoxville, TN (United States)

    1998-04-01T23:59:59.000Z

    The authors have completed a study in which they investigated the use of a rich combustor to aid in cold starting spark-ignition engines fueled with either neat ethanol or neat methanol. The rich combustor burns the alcohol fuel outside the engine under fuel-rich conditions to produce a combustible product stream that is fed to the engine for cold starting. The rich combustor approach significantly extends the cold starting capability of alcohol-fueled engines. A design tool was developed that simulates the operation of the combustor and couples it to an engine/vehicle model. This tool allows the user to determine the fuel requirements of the rich combustor as the vehicle executes a given driving mission. The design tool was used to design and fabricate a rich combustor for use on a 2.8 L automotive engine. The system was tested using a unique cold room that allows the engine to be coupled to an electric dynamometer. The engine was fitted with an aftermarket engine control system that permitted the fuel flow to the rich combustor to be programmed as a function of engine speed and intake manifold pressure. Testing indicated that reliable cold starts were achieved on both neat methanol and neat ethanol at temperatures as low as {minus}20 C. Although starts were experienced at temperatures as low as {minus}30 C, these were erratic. They believe that an important factor at the very low temperatures is the balance between the high mechanical friction of the engine and the low energy density of the combustible mixture fed to the engine from the rich combustor.

  14. Substrate denaturation and translocation by a proteolytic machine

    E-Print Network [OSTI]

    Kenniston, Jon Anders

    2005-01-01T23:59:59.000Z

    Many AAA+ molecular machines generate power and drive cellular processes by harnessing energy from cycles of ATP hydrolysis. ClpX is a relatively simple AAA+ ATPase that powers regulated protein degradation by binding ...

  15. Denaturing Urea PAGE -Large Gel Preparation of Glass Plates

    E-Print Network [OSTI]

    Aris, John P.

    tube. Mix. Pour ~2.5 mls on inside surface of long glass plate. Spread and polish with Kimwipes. Repeat gel solution down middle of glass plates with 25 ml pipette. Do not trap bubbles in gel. Adjust flow rate with tilt of gel. Place gel close to horizontal (top end slightly elevated). Insert comb. Do

  16. affect surfactant denaturation: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    For vanishing hydrophobic forces this complex has the architecture of a molecular bottle-brush cylindrically centered around the stretched PE molecule. Upon increasing the...

  17. A microfluidic device for DNA sequencing by denaturation

    E-Print Network [OSTI]

    Walsh, Matthew Thomas

    2011-01-01T23:59:59.000Z

    T: Thymine TE: Thermoelectric TEG: Triethylene glycol Tm:via a triethylene glycol (TEG) linker on the 5’ end.template is: 5'-(Biotin-TEG)-(Biotin-TEG)-TAC AGA CTT AGT

  18. Self-protection analysis of denatured thorium-plutonium fuel

    E-Print Network [OSTI]

    Torres, Luis Alberto (Torres Mendoza)

    2010-01-01T23:59:59.000Z

    With growing demands for commercial nuclear power, there is also a growing need for better energy efficiency from nuclear power reactors. In order to reach a high burnup up to 100 MWd/kg, previous research has examined the ...

  19. Local and long-range electrostatic interactions in denatured Ribonuclease Sa: comparing the denatured protein with model peptides

    E-Print Network [OSTI]

    Daily, Michael Douglas

    2013-02-22T23:59:59.000Z

    behavior of a total of fourteen aspartates, glutamates, and histidines in a hypothetical random-coil conformation of the simple protein RNase Sa. The pK[a]s of the residues of interest in the model peptides have already been compared the intrinsic p...

  20. Direct Conversion of Syngas-to-Hydrocarbons over Higher Alcohols Synthesis Catalysts Mixed with HZSM-5

    SciTech Connect (OSTI)

    Lebarbier Dagel, Vanessa M.; Dagle, Robert A.; Li, Jinjing; Deshmane, Chinmay A.; Taylor, Charles E.; Bao, Xinhe; Wang, Yong

    2014-09-10T23:59:59.000Z

    The synthesis of hydrocarbon fuels directly from synthesis gas (i.e. one step process) was investigated with a catalytic system comprised of HZSM-5 physically mixed with either a methanol synthesis catalyst or a higher alcohols synthesis (HAS) catalyst. The metal sites of the methanol or HAS synthesis catalyst enable the conversion of syngas to alcohols, whereas HZSM-5 provides acid sites required for methanol dehydration, and dimethyl ether-to-hydrocarbons reactions. Catalytic performance for HZSM-5 when mixed with either a 5 wt.% Pd/ZnO/Al2O3 methanol synthesis catalyst or a HAS catalyst was evaluated at 300°C, 70 bars, GHSV=700 h-1 and H2/CO=1 using a HZSM-5: alcohols synthesis catalyst weight ratio of 3:1. The major difference observed between the methanol synthesis and HAS catalyst mixtures was found in the production of durene which is an undesirable byproduct. While durene formation is negligible with any of the HAS catalysts mixed with the HZSM-5 evaluated in this study, it represents almost 50% of the C5+ fraction for the methanol synthesis catalyst (5 wt.% Pd/ZnO/Al2O3 ) mixed with HZSM-5. This presents an advantage for using HAS catalysts over the methanol synthesis catalyst to minimize the durene by-product. The yield toward the desired C5+ hydrocarbons is thus twice higher with selected HAS catalysts as compared to when HZSM-5 is mixed with 5 wt.% Pd/ZnO/Al2O3. Among all the HAS catalysts evaluated in this study, a catalyst with 0.5 wt.% Pd/FeCoCu catalyst was found the most promising due to higher production of C5+ hydrocarbons and low durene formation. The efficiency of the one-step process was thus further evaluated using the HZSM-5: 0.5 wt.% Pd/FeCoCu catalyst mixture under a number of process conditions to maximize liquid hydrocarbons product yield. At 300oC, 70 bars, GHSV = 700 h-1 and HZSM-5: 0.5 wt.% Pd/FeCoCu = 3:1 (wt.), the C5+ fraction represents 48.5% of the hydrocarbons. Unfortunately, it is more difficult to achieve higher selectivity to desired C5+ hydrocarbons as the formation of CO2, CH4, and other light hydrocarbons is challenging to suppress in the presence of mixed metal and acid sites. When the 0.5 wt.% Pd/FeCoCu and HZSM-5 are operated sequentially by way of a two-step process the C5+ hydrocarbons fraction is lower and represents 30.4% of the hydrocarbons under comparable conditions. The yield toward the C5+ hydrocarbons is twice higher for the one-step process due to an improved CO conversion and higher C5+ hydrocarbons fraction. The main advantage of the one-step process is that higher syngas conversion can be achieved as the equilibrium-driven conversion limitations for methanol and dimethyl ether are removed since they are intermediates to the final hydrocarbons product.

  1. Quantitative temperature effects on the saponification rates of aliphatic esters

    E-Print Network [OSTI]

    Schreck, James Otto

    1962-01-01T23:59:59.000Z

    . Heat of Activation Entro of Activati an Free Ener o t vat on Using Eyring's basic equation40 40. S. Glasstone K. J. Laidler, H. Eyring, "The Theory of, Rate Processes, " NcGraw-Hill Book Company, Inc. , New York, N. Y. , 1941: p. 195. k = K -2 (18...

  2. aliphatic unsaturated unconjugated: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3.3, 6.2, 7.7, 8.6, and 11.3 micrometer, commonly attributed to polycyclic aromatic hydrocarbon (PAH) molecules, have been recently ascribed to coal- or kerogen-like organic...

  3. aliphatic saturated primary: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3.3, 6.2, 7.7, 8.6, and 11.3 micrometer, commonly attributed to polycyclic aromatic hydrocarbon (PAH) molecules, have been recently ascribed to coal- or kerogen-like organic...

  4. Quantitative relationships between structure and reactivity of aliphatic esters

    E-Print Network [OSTI]

    Yager, Billy Joe

    1960-01-01T23:59:59.000Z

    ~rity of' cstor and bsso s~lution (100 nl. ), 0. 02/76 ii &ol~rfty of nixture of' base and ester solution, 0. 01186 '! t, R& "inutco Qhm 1176 1/d x 10 (1/R 1/R ) x 10 1/t (1/2 - 1 ~Rt} x 1(P o 0 0, (~90' 7 9, 0 11. 0 1': 6 Q, ypCQ 1 940 Jg.... 210 1. 1$ 0, y~? -l. r4 0, 215 -O. g Wtc on i'. ethyl a b 0 1' 0. 00 -0. 'V -0, 67 1, 06 -0, 70 -1. 24 -1. 74 -2. 46 -0 69 (n-y) loC ~k 1 ~ 2iFgG 1, 169' d. 87l7 &47100 O. -fPjO 0. 1752 -0. 1700 a b a, :al'erenoe 5', roI'orenoo 9...

  5. aliphatic tertiary amines: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of the system. If so, all close binaries should be members of triple (or higher-order) systems. As a test of this prediction, we present a search for the signature of third...

  6. aliphatic ch bonds: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2015-01-01 39 H-atom high-n Rydberg time-of-flight spectroscopy of CH bond fission in acrolein dissociated at 193 nm Chemistry Websites Summary: H-atom high-n Rydberg...

  7. aromatic aliphatic copolyester: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Based on studies of PAH destruction, we argue that a size distribution shifted towards sm... Sandstrom, Karin M; Bot, Caroline; Draine, B T; Ingalls, James G; Israel, Frank P;...

  8. Low-Temperature Photoelectron Spectroscopy of Aliphatic Dicarboxylate...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    anions are cyclic due to strong intramolecular hydrogen bonding between the terminal –CO2H and –CO2 - groups. The measured electron binding energies are...

  9. aliphatic hydrocarbons separacion: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Technologies and Information Sciences Websites Summary: by the Spanish Ministry: TITLE: Gestion de la movilidad basada en la separacion de identificadores. (NAME: Naming:...

  10. aliphatic carboxylic acids: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and spot selling price of various carboxylic acids. 1-3 Names used for biomass feedstocks. . 1-4 2-1 Sample processing. Rinsing scheme for precipitated solids. 12 3-1...

  11. aliphatic carboxylic acid: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and spot selling price of various carboxylic acids. 1-3 Names used for biomass feedstocks. . 1-4 2-1 Sample processing. Rinsing scheme for precipitated solids. 12 3-1...

  12. aliphatic primary diamines: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    STUDY OF DNA DOUBLE-STRAND BREAKS IN BYSTANDER PRIMARY HUMAN FIBROBLASTS L. B. Smilenov-or-nothing manner(7) . Bystander cells exhibit a variety of characteristics of...

  13. aliphatic chains affects: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Harvard Medical School, 200 Longwood Avenue, Boston, MA 02115; b Department, maximum entropy reconstruction, non-uniform sampling, reduced-dimensionality, side-chain...

  14. aliphatic biodegradable photoluminescent: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    oxide phosphors. Furthermore, strong photoluminescence (PL) in Zn SiO doped with rare earths such as Eu Steckl, Andrew J. 295 Circularly Polarized Photoluminescence as a...

  15. Characterization of a Saturated and Flexible Aliphatic Polyol Anion Receptor

    SciTech Connect (OSTI)

    Shokri, Alireza; Schmidt, Jacob C.; Wang, Xue B.; Kass, Steven R.

    2012-10-17T23:59:59.000Z

    Nature employs flexible molecules to bind anions in a variety of physiologically important processes whereas supramolecular chemists have been designing rigid substrates that minimize or eliminate intramolecular hydrogen bond interactions to carry out anion recogni-tion. Herein, the association of a flexible polyhydroxy alkane with chloride ion is described and the bound re-ceptor is characterized by infrared and photoelectron spectroscopy in the gas phase, computations, and its bind-ing constant as a function of temperature in acetonitrile.

  16. Alcohol decreases baseline brain glucose metabolism more in heavy drinkers than controls but has no effect on stimulation-induced metabolic increases

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Volkow, Nora D. [National Inst. on Alcohol Abuse and Alcoholism, Bethesda, MD (United States); Fowler, Joanna S. [Brookhaven National Lab. (BNL), Upton, NY (United States); Wang, Gene-Jack [National Inst. on Alcohol Abuse and Alcoholism, Bethesda, MD (United States); Kojori, Eshan Shokri [National Inst. on Alcohol Abuse and Alcoholism, Bethesda, MD (United States); Benveniste, Helene [Stony Brook Medicine, Stony Brook, NY (United States); Tomasi, Dardo [National Inst. on Alcohol Abuse and Alcoholism, Bethesda, MD (United States)

    2015-02-18T23:59:59.000Z

    During alcohol intoxication the human brain increases metabolism of acetate and decreases metabolism of glucose as energy substrate. Here we hypothesized that chronic heavy drinking facilitates this energy substrate shift both for baseline and stimulation conditions. To test this hypothesis we compared the effects of alcohol intoxication (0.75g/kg alcohol versus placebo) on brain glucose metabolism during video-stimulation (VS) versus when given with no-stimulation (NS), in 25 heavy drinkers (HD) and 23 healthy controls each of whom underwent four PET-¹?FDG scans. We showed that resting whole-brain glucose metabolism (placebo-NS) was lower in HD than controls (13%, p=0.04); that alcohol (compared to placebo) decreased metabolism more in HD (20±13%) than controls (9±11%, p=0.005) and in proportion to daily alcohol consumption (r=0.36, p=0.01) but found that alcohol did not reduce the metabolic increases in visual cortex from VS in either group. Instead, VS reduced alcohol-induced decreases in whole-brain glucose metabolism (10±12%) compared to NS in both groups (15±13%, p=0.04), consistent with stimulation-related glucose metabolism enhancement. These findings corroborate our hypothesis that heavy alcohol consumption facilitates use of alternative energy substrates (i.e. acetate) for resting activity during intoxication, which might persist through early sobriety, but indicate that glucose is still favored as energy substrate during brain stimulation. Our findings are consistent with reduced reliance on glucose as the main energy substrate for resting brain metabolism during intoxication (presumably shifting to acetate or other ketones) and a priming of this shift in heavy drinkers, which might make them vulnerable to energy deficits during withdrawal.

  17. Anhydrous aluminum chloride as an alkylation catalyst: identification of mono- and dialkyl-benzenes from the condensation of tertiary butyl alcohol with benzene.

    E-Print Network [OSTI]

    Scoggins, Lacey E

    1959-01-01T23:59:59.000Z

    LIBRARY a a w c"I. I. SI - O~ TI:YAf ANHYDROUS ALUMINUM CHLORIDE AS AN ALKYLATION CATALYST: IDENTIFICATION OF MONO- AND DIALKYIZENZENES FROM THE CONDENSATION QF TERTIARY BUTYL ALCOHOL WITH BENKENE IACEY EUGENE SCOGGINS 4 A Thesis Submitted...: IDENTIFICATION OF MONO- AND DI~NZZNES FROM THE CONDENSATION OF TERTIARY BUTYL ALCOHOL WITH BENZENE A Thesis By LACEY EUGENE SCOGGINS Approved as to style and content hy: Chairman of Committee Head of Chemistry Department 1959 ACKNOWLEDGME1VTS The author...

  18. Alcohol decreases baseline brain glucose metabolism more in heavy drinkers than controls but has no effect on stimulation-induced metabolic increases

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Volkow, Nora D.; Fowler, Joanna S.; Wang, Gene-Jack; Kojori, Eshan Shokri; Benveniste, Helene; Tomasi, Dardo

    2015-02-18T23:59:59.000Z

    During alcohol intoxication the human brain increases metabolism of acetate and decreases metabolism of glucose as energy substrate. Here we hypothesized that chronic heavy drinking facilitates this energy substrate shift both for baseline and stimulation conditions. To test this hypothesis we compared the effects of alcohol intoxication (0.75g/kg alcohol versus placebo) on brain glucose metabolism during video-stimulation (VS) versus when given with no-stimulation (NS), in 25 heavy drinkers (HD) and 23 healthy controls each of whom underwent four PET-¹?FDG scans. We showed that resting whole-brain glucose metabolism (placebo-NS) was lower in HD than controls (13%, p=0.04); that alcohol (compared tomore »placebo) decreased metabolism more in HD (20±13%) than controls (9±11%, p=0.005) and in proportion to daily alcohol consumption (r=0.36, p=0.01) but found that alcohol did not reduce the metabolic increases in visual cortex from VS in either group. Instead, VS reduced alcohol-induced decreases in whole-brain glucose metabolism (10±12%) compared to NS in both groups (15±13%, p=0.04), consistent with stimulation-related glucose metabolism enhancement. These findings corroborate our hypothesis that heavy alcohol consumption facilitates use of alternative energy substrates (i.e. acetate) for resting activity during intoxication, which might persist through early sobriety, but indicate that glucose is still favored as energy substrate during brain stimulation. Our findings are consistent with reduced reliance on glucose as the main energy substrate for resting brain metabolism during intoxication (presumably shifting to acetate or other ketones) and a priming of this shift in heavy drinkers, which might make them vulnerable to energy deficits during withdrawal.« less

  19. Solvation studies on anion radicals of alkyl nitrobenzene derivatives in acetonitrile-alkyl alcohol solvent mixtures at 25 p0 sC

    E-Print Network [OSTI]

    Chu, William Wen-Chen

    1970-01-01T23:59:59.000Z

    SOLVATION STUDIES OM ANION RADICALS QF ALKYL NITROBENZENE DERIVATIVES IN ACETONITRILE- ALKYL ALCOHOL SOLVENT MIXTURES AT PS C A Thesis by WILLIAM WEN CHEN CHU Submitted to the Graduate College of Texas ASM University in partial fulfillment... of the requirement for the degree of MASTER OF SCIENCE August 1970 Ma)or Sub)oct: Chemistry SOLVATION STUDIES ON ANION RADICALS OF ALKYL NITROBENZENE DERIVATIVES IN ACETONITRILE- ALKYL ALCOHOL SOLVENT MIXTURES AT 25'C A Thesis NILLIAM HEN-CHEN CHU Approved...

  20. Effects of partial charge-transfer solute -- solvent interactions in absorption spectra of aromatic hydrocarbons in aqueous and alcoholic solutions

    E-Print Network [OSTI]

    I. A. Ar'ev; N. I. Lebovka; E. A. Solovieva

    2013-03-03T23:59:59.000Z

    A method for study of charge-transfer interactions between solute molecules and solvent based on the comparison of the ratios of spectral shifts of different electronic transitions in solute molecules in chemically inert solvent is proposed. The method is applicable to molecules that do not change their dipole moment on excitation. As an example, a presence of charge transfer interactions in higher electronic states of aromatic hydrocarbons (benzene, phenanthrene, and naphthalene) dissolved in water and alcohols was demonstrated.

  1. Nitric oxide control of steroidogenesis: Endocrine effects of N sup G -nitro-L-arginine and comparisons to alcohol

    SciTech Connect (OSTI)

    Adams, M.L.; Nock, B.; Truong, R.; Cicero, T.J. (Washington Univ., St. Louis, MO (United States))

    1992-01-01T23:59:59.000Z

    Recent studies suggest that nitric oxide (NO) may regulate hormone biosynthesis and secretion. This was tested by treating male rats with N{sup G}-nitro-L-arginine methyl ester (NAME), a NO synthase inhibitor, and measuring serum and testicular interstitial fluid testosterone and serum corticosterone, luteinizing hormone (LH), and prolactin (PRL). The effect of N{sup G}-nitro-L-arginine (NA), a less-soluble form of the same NO synthase inhibitor, on the reproductive suppressant actions of alcohol was also examined. NAME increased testosterone and corticosterone secretion dose-dependently without affecting LH and PRL secretion. The alcohol-induced suppression of testosterone or LH secretion was not altered by treatment with NA. Although effects of NAME and NA on other systems may be involved, these results indicate that testicular and adrenal steroidogenesis are negatively regulated by endogenous NO and that NO does not regulate LH and PRL secretion or inhibit the testicular steroidogenic pathway in the same way as alcohol.

  2. Long-Term Testing of Rhodium-Based Catalysts for Mixed Alcohol Synthesis – 2013 Progress Report

    SciTech Connect (OSTI)

    Gerber, Mark A.; Gray, Michel J.; Thompson, Becky L.

    2013-09-23T23:59:59.000Z

    The U.S. Department of Energy’s Pacific Northwest National Laboratory has been conducting research since 2005 to develop a catalyst for the conversion of synthesis gas (carbon monoxide and hydrogen) into mixed alcohols for use in liquid transportation fuels. Initially, research involved screening possible catalysts based on a review of the literature, because at that time, there were no commercial catalysts available. The screening effort resulted in a decision to focus on catalysts containing rhodium and manganese. Subsequent research identified iridium as a key promoter for this catalyst system. Since then, research has continued to improve rhodium/manganese/iridium-based catalysts, optimizing the relative and total concentrations of the three metals, examining baseline catalysts on alternative supports, and examining effects of additional promoters. Testing was continued in FY 2013 to evaluate the performance and long-term stability of the best catalysts tested to date. Three tests were conducted. A long-term test of over 2300 hr duration at a single set of operating conditions was conducted with the best carbon-supported catalyst. A second test of about 650 hr duration at a single set of operating conditions was performed for comparison using the same catalyst formulation on an alternative carbon support. A third test of about 680 hr duration at a single set of operating conditions was performed using the best silica-supported catalyst tested to date.

  3. Room temperature alcohol sensing by oxygen vacancy controlled TiO{sub 2} nanotube array

    SciTech Connect (OSTI)

    Hazra, A.; Dutta, K.; Bhowmik, B.; Bhattacharyya, P., E-mail: pb-etc-besu@yahoo.com [Nano-Thin Films and Solid State Gas Sensor Devices Laboratory, Department of Electronics and Telecommunication Engineering, Indian Institute of Engineering Science and Technology (IIEST), Shibpur, Howrah (India); Chattopadhyay, P. P. [Department of Metallurgy and Materials Engineering, Indian Institute of Engineering Science and Technology (IIEST), Shibpur, Howrah (India)

    2014-08-25T23:59:59.000Z

    Oxygen vacancy (OV) controlled TiO{sub 2} nanotubes, having diameters of 50–70?nm and lengths of 200–250?nm, were synthesized by electrochemical anodization in the mixed electrolyte comprising NH{sub 4}F and ethylene glycol with selective H{sub 2}O content. The structural evolution of TiO{sub 2} nanoforms has been studied by field emission scanning electron microscopy. Variation in the formation of OVs with the variation of the structure of TiO{sub 2} nanoforms has been evaluated by photoluminescence and X-ray photoelectron spectroscopy. The sensor characteristics were correlated to the variation of the amount of induced OVs in the nanotubes. The efficient room temperature sensing achieved by the control of OVs of TiO{sub 2} nanotube array has paved the way for developing fast responding alcohol sensor with corresponding response magnitude of 60.2%, 45.3%, and 36.5% towards methanol, ethanol, and 2-propanol, respectively.

  4. Batch Microreactor Studies of Lignin Depolymerization by Bases. 1. Alcohol Solvents

    SciTech Connect (OSTI)

    MILLER, JAMES E.; EVANS, LINDSEY; LITTLEWOLF, ALICIA; TRUDELL, DANIEL E.

    2002-05-01T23:59:59.000Z

    Biomass feedstocks contain roughly 10-30% lignin, a substance that can not be converted to fermentable sugars. Hence, most schemes for producing biofuels (ethanol) assume that the lignin coproduct will be utilized as boiler fuel to provide heat and power to the process. However, the chemical structure of lignin suggests that it will make an excellent high value fuel additive, if it can be broken down into smaller molecular units. From fiscal year 1997 through fiscal year 2001, Sandia National Laboratories was a participant in a cooperative effort with the National Renewable Energy Laboratory and the University of Utah to develop and scale a base catalyzed depolymerization (BCD) process for lignin conversion. SNL's primary role in the effort was to utilize rapidly heated batch microreactors to perform kinetic studies, examine the reaction chemistry, and to develop alternate catalyst systems for the BCD process. This report summarizes the work performed at Sandia during FY97 and FY98 with alcohol based systems. More recent work with aqueous based systems will be summarized in a second report.

  5. Synthesis, characterization, and catalytic activity of Rh-based lanthanum zirconate pyrochlores for higher alcohol synthesis

    SciTech Connect (OSTI)

    Abdelsayed, Victor; Shekhawat, Dushyant; Poston, James A., Jr.; Spivey, James J.

    2013-05-01T23:59:59.000Z

    Two lanthanum zirconate pyrochlores (La{sub 2}Zr{sub 2}O{sub 7}; LZ) were prepared by Pechini method and tested for higher alcohols selectivity. In one, Rh was substituted into the pyrochlore lattice (LRZ, 1.7 wt%) while for the second, Rh was supported on an unsubstituted La{sub 2}Zr{sub 2}O{sub 7} (R/LZ, 1.8 wt%). X-ray photoelectron spectroscopy (XPS) and temperature programmed reduction (TPR) results show that the surface reducibility depends on whether the Rh is in (or supported on) the LZ pyrochlore. Rhodium in the LRZ is more reducible than rhodium supported on the R/LZ pyrochlore, likely due to the presence of a perovskite phase (LaRhO{sub 3}; identified by XRD), in which rhodium is more reducible. The formation of the perovskite accompanies that of the pyrochlore. CO hydrogenation results show higher ethanol selectivity for R/LZ than LRZ, possibly due to the strong interaction between Rh and LZ on the R/LZ, forming atomically close Rh{sup +}/Rh{sup 0} sites, which have been suggested to favor ethanol production.

  6. The economical production of alcohol fuels from coal-derived synthesis gas. Quarterly technical progress report Number 8, 1 July, 1993--30 September, 1993

    SciTech Connect (OSTI)

    Not Available

    1993-10-01T23:59:59.000Z

    Task 1, the preparation of catalyst materials, is proceeding actively. At WVU, catalysts based on Mo are being prepared using a variety of approaches to alter the oxidation state and environment of the Mo. At UCC and P, copper-based zinc chromite spinel catalysts will be prepared and tested. The modeling of the alcohol-synthesis reaction in a membrane reactor is proceeding actively. Under standard conditions, pressure drop in the membrane reactor has been shown to be negligible. In Task 2, base case designs had previously been completed with a Texaco gasifier. Now, similar designs have been completed using the Shell gasifier. A comparison of the payback periods or production cost of these plants shows significant differences among the base cases. However, a natural gas only design, prepared for comparison purposes, gives a lower payback period or production cost. Since the alcohol synthesis portion of the above processes is the same, the best way to make coal-derived higher alcohols more attractive economically than natural gas-derived higher alcohols is by making coal-derived syngas less expensive than natural gas-derived syngas. The maximum economically feasible capacity for a higher alcohol plant from coal-derived syngas appears to be 32 MM bbl/yr. This is based on consideration of regional coal supply in the eastern US, coal transportation, and regional product demand. The benefits of economics of scale are illustrated for the base case designs. A value for higher alcohol blends has been determined by appropriate combination of RVP, octane number, and oxygen content, using MTBE as a reference. This analysis suggests that the high RVP of methanol in combination with its higher water solubility make higher alcohols more valuable than methanol.

  7. Novel Characterization of GDI Engine Exhaust for Gasoline and Mid-Level Gasoline-Alcohol Blends

    SciTech Connect (OSTI)

    Storey, John Morse [ORNL] [ORNL; Lewis Sr, Samuel Arthur [ORNL] [ORNL; Szybist, James P [ORNL] [ORNL; Thomas, John F [ORNL] [ORNL; Barone, Teresa L [ORNL] [ORNL; Eibl, Mary A [ORNL] [ORNL; Nafziger, Eric J [ORNL] [ORNL; Kaul, Brian C [ORNL] [ORNL

    2014-01-01T23:59:59.000Z

    Gasoline direct injection (GDI) engines can offer improved fuel economy and higher performance over their port fuel-injected (PFI) counterparts, and are now appearing in increasingly more U.S. and European vehicles. Small displacement, turbocharged GDI engines are replacing large displacement engines, particularly in light-duty trucks and sport utility vehicles, in order for manufacturers to meet more stringent fuel economy standards. GDI engines typically emit the most particulate matter (PM) during periods of rich operation such as start-up and acceleration, and emissions of air toxics are also more likely during this condition. A 2.0 L GDI engine was operated at lambda of 0.91 at typical loads for acceleration (2600 rpm, 8 bar BMEP) on three different fuels; an 87 anti-knock index (AKI) gasoline (E0), 30% ethanol blended with the 87 AKI fuel (E30), and 48% isobutanol blended with the 87 AKI fuel. E30 was chosen to maximize octane enhancement while minimizing ethanol-blend level and iBu48 was chosen to match the same fuel oxygen level as E30. Particle size and number, organic carbon and elemental carbon (OC/EC), soot HC speciation, and aldehydes and ketones were all analyzed during the experiment. A new method for soot HC speciation is introduced using a direct, thermal desorption/pyrolysis inlet for the gas chromatograph (GC). Results showed high levels of aromatic compounds were present in the PM, including downstream of the catalyst, and the aldehydes were dominated by the alcohol blending.

  8. Multiple Pathways for Benzyl Alcohol Oxidation by RuV=O3+ and RuIV=O2+

    SciTech Connect (OSTI)

    Paul, Amit; Hull, Jonathan F; Norris, Michael R; Chen, Zuofeng; Ess, Daniel H; Concepcion, Javier J; Meyer, Thomas J

    2011-01-01T23:59:59.000Z

    Significant rate enhancements are found for benzyl alcohol oxidation by the Ru{sup V}?O{sup 3+} form of the water oxidation catalyst [Ru(Mebimpy)(bpy)(OH{sub 2})]{sup 2+} [Mebimpy = 2,6-bis(1-methylbenzimidazol-2-yl)pyridine; bpy = 2,2?-bipyridine] compared to Ru{sup IV}?O{sup 2+} and for the Ru{sup IV}?O{sup 2+} form with added bases due to a new pathway, concerted hydride proton transfer (HPT).

  9. Multiple Pathways for Benzyl Alcohol Oxidation by Ru(V)?O3+ and Ru(IV)?O2+

    SciTech Connect (OSTI)

    Paul, Amit; Hull, Jonathan F; Norris, Michael R; Chen, Zuofeng; Ess, Daniel H.; Concepcion, Javier J; Meyer, Thomas J.

    2011-01-01T23:59:59.000Z

    Significant rate enhancements are found for benzyl alcohol oxidation by the Ru{sup V}?O{sup 3+} form of the water oxidation catalyst [Ru(Mebimpy)(bpy)(OH{sub 2})]{sup 2+} [Mebimpy = 2,6-bis(1-methylbenzimidazol-2-yl)pyridine; bpy = 2,2?-bipyridine] compared to Ru{sup IV}?O{sup 2+} and for the Ru{sup IV}?O{sup 2+} form with added bases due to a new pathway involving concerted hydride proton transfer (HPT).

  10. Estimating changes in the mechanical properties of the femur in the adult and aged rat due to adult-onset alcohol consumption 

    E-Print Network [OSTI]

    Nguyen, Lyndon Phuoc

    2001-01-01T23:59:59.000Z

    in animals 15 and 19 months of age, which is comparable to the young adult and aged human. 2. 6 Relevant Research on the Mechanical Properties of Rat Bone Emphasis on safety in automotive, aircraft and aerospace engineering has lead to a growing interest... the second set (eight- week alcohol plus six-week cessation) only consisted of an alcohol and a pair-fed group. At eight weeks and again at fourteen weeks, the rats were sacrificed and the femurs were removed for mechanical testing. This is summarized...

  11. Analyzing the effects of alcohol on IGF-I in bone and plasma and on IGF-I mRNA in the liver and bone 

    E-Print Network [OSTI]

    Stine, Christina Nicole

    2001-01-01T23:59:59.000Z

    (Member) John E. Bauer (Chair of Nutrition) Bryan H. Johnson (Department Head) August 2001 Major: Nutrition ABSTRACT Analyzing the Effects of Alcohol on IGF-I in Bone and Plasma and on IGF-I mRNA in the Liver and Bone. (August 2001) Christina... different effector pathways to increase proliferation at the growth plate (Klaus et al. , 1998). Therefore Vitamin D may not have an effect on IGF-I. Alcoholics have decreased plasma 25-hydroxyvitamin D which is an indicator of Vitamin D status (Peris et...

  12. A study of the condensation of primary, secondary, and tertiary butyl alcohols with benzene in the presence of anhydrous ferric chloride

    E-Print Network [OSTI]

    Dodson, Ralph Jordan

    1939-01-01T23:59:59.000Z

    A PKDT Qt THE COND%SATION QE PRECUT, SSQGNDART~ AND T~ NOTCL ALCOHOLS NITH SEEZEEE IN THE ~E GF ANBIINKU8 mRIQ CHLORIDE Asm 1959 4 et Chea1stxy and 0 A STOSX Gf THE OQtGRWSATIOR Of PRXRARX, SWOORBARX ARRI TCBTXARX WTXL ALQOBOLB WITH 8%%ESSE IR... THS F58XWOR Of AWHXQREUS FERRIC CBLORISR A STUART OF TBR CNRRGATTGR OF PIIRSGKo SROOP~e ARD TRRTZART RDTTL ALCOHOLS RITE ~R ZN TKR FRRSRBCR OP ARBTDROUS PRIBKC OHLORTDR A Theete Parttal Palfileaat cf the ReRNLreewate Ter the aeggso cf Rse4e et...

  13. Investigation of the possibility of intermediate formation of allyl alcohol in the process of oxidative acetoxylation of propylene on a palladium-copper zeolite catalyst

    SciTech Connect (OSTI)

    Minachev, K.M.; Chizhov, O.S.; Kadentsev, V.I.; Kharlamov, V.V.; Nefedov, O.M.; Rodin, A.N.

    1985-12-10T23:59:59.000Z

    The formation of allyl acetate in reactions of oxidative acetoxylation of propylene by labeled acetic acid and esterification of labeled acetic acid by allyl alcohol on a Pd, Cu-zeolite catalyst occur with complete conservation of the labeled oxygen of the original labeled acetic acid in the reaction product. The authors propose a reaction scheme for the oxidative acetoxylation of propylene, providing for the formation of allyl alcohol as an intermediate compound, present in a chemisorbed state in the form of a complex with a Pd atom. The gas-phase oxidative acetoxylation of propylene is an industrial method of producing allyl acetate.

  14. Thermal Decomposition of Bulk K-CoMoSx Mixed Alcohol Catalyst Precursors and Effects on Catalyst Morphology and Performance

    SciTech Connect (OSTI)

    Menart, M. J.; Hensley, J. E.; Costelow, K. E.

    2012-09-26T23:59:59.000Z

    Cobalt molybdenum sulfide-type mixed alcohol catalysts were synthesized via calcination of precipitated bulk sulfides and studied with temperature programmed decomposition analysis. Precursors containing aqueous potassium were also considered. Precipitates thermally decomposed in unique events which released ammonia, carbon dioxide, and sulfur. Higher temperature treatments led to more crystalline and less active catalysts in general with ethanol productivity falling from 203 to 97 g (kg cat){sup -1} h{sup -1} when the calcination temperature was increased from 375 to 500 C. The addition of potassium to the precursor led to materials with crystalline potassium sulfides and good catalytic performance. In general, less potassium was required to promote alcohol selectivity when added before calcination. At calcination temperatures above 350 C, segregated cobalt sulfides were observed, suggesting that thermally decomposed sulfide precursors may contain a mixture of molybdenum and cobalt sulfides instead of a dispersed CoMoS type of material. When dimethyl disulfide was fed to the precursor during calcination, crystalline cobalt sulfides were not detected, suggesting an important role of free sulfur during decomposition.

  15. THE ECONOMICAL PRODUCTION OF ALCOHOL FUELS FROM COAL-DERIVED SYNTHESIS GAS. Includes quarterly technical progress report No.25 from 10/01/1997-12/31/1997, and quarterly technical progress report No.26 from 01/01/1998-03/31/1998

    SciTech Connect (OSTI)

    None

    1999-03-01T23:59:59.000Z

    This project was divided into two parts. One part evaluated possible catalysts for producing higher-alcohols (C{sub 2} to C{sub 5+}) as fuel additives. The other part provided guidance by looking both at the economics of mixed-alcohol production from coal-derived syngas and the effect of higher alcohol addition on gasoline octane and engine performance. The catalysts studied for higher-alcohol synthesis were molybdenum sulfides promoted with potassium. The best catalysts produced alcohols at a rate of 200 g/kg of catalyst/h. Higher-alcohol selectivity was over 40%. The hydrocarbon by-product was less than 20%. These catalysts met established success criteria. The economics for mixed alcohols produced from coal were poor compared to mixed alcohols produced from natural gas. Syngas from natural gas was always less expensive than syngas from coal. Engine tests showed that mixed alcohols added to gasoline significantly improved fuel quality. Mixed-alcohols as produced by our catalysts enhanced gasoline octane and decreased engine emissions. Mixed-alcohol addition gave better results than adding individual alcohols as had been done in the 1980's when some refiners added methanol or ethanol to gasoline.

  16. Rh-Based Mixed Alcohol Synthesis Catalysts: Characterization and Computational Report

    SciTech Connect (OSTI)

    Albrecht, Karl O.; Glezakou, Vassiliki Alexandra; Rousseau, Roger J.; Engelhard, Mark H.; Varga, Tamas; Colby, Robert J.; Jaffe, John E.; Li, Xiaohong S.; Mei, Donghai; Windisch, Charles F.; Kathmann, Shawn M.; Lemmon, Teresa L.; Gray, Michel J.; Hart, Todd R.; Thompson, Becky L.; Gerber, Mark A.

    2013-08-01T23:59:59.000Z

    The U.S. Department of Energy is conducting a program focused on developing a process for the conversion of biomass to bio-based fuels and co-products. Biomass-derived syngas is converted thermochemically within a temperature range of 240 to 330°C and at elevated pressure (e.g., 1200 psig) over a catalyst. Ethanol is the desired reaction product, although other side compounds are produced, including C3 to C5 alcohols; higher (i.e., greater than C1) oxygenates such as methyl acetate, ethyl acetate, acetic acid and acetaldehyde; and higher hydrocarbon gases such as methane, ethane/ethene, propane/propene, etc. Saturated hydrocarbon gases (especially methane) are undesirable because they represent a diminished yield of carbon to the desired ethanol product and represent compounds that must be steam reformed at high energy cost to reproduce CO and H2. Ethanol produced by the thermochemical reaction of syngas could be separated and blended directly with gasoline to produce a liquid transportation fuel. Additionally, higher oxygenates and unsaturated hydrocarbon side products such as olefins also could be further processed to liquid fuels. The goal of the current project is the development of a Rh-based catalyst with high activity and selectivity to C2+ oxygenates. This report chronicles an effort to characterize numerous supports and catalysts to identify particular traits that could be correlated with the most active and/or selective catalysts. Carbon and silica supports and catalysts were analyzed. Generally, analyses provided guidance in the selection of acceptable catalyst supports. For example, supports with high surface areas due to a high number of micropores were generally found to be poor at producing oxygenates, possibly because of mass transfer limitations of the products formed out of the micropores. To probe fundamental aspects of the complicated reaction network of CO with H2, a computational/ theoretical investigation using quantum mechanical and ab initio molecular dynamics calculations was initiated in 2009. Computational investigations were performed first to elucidate understanding of the nature of the catalytically active site. Thermodynamic calculations revealed that Mn likely exists as a metallic alloy with Rh in Rh-rich environments under reducing conditions at the temperatures of interest. After determining that reduced Rh-Mn alloy metal clusters were in a reduced state, the activation energy barriers of numerous transition state species on the catalytically active metal particles were calculated to compute the activation barriers of several reaction pathways that are possible on the catalyst surface. Comparison of calculations with a Rh nanoparticle versus a Rh-Mn nanoparticle revealed that the presence of Mn enabled the reaction pathway of CH with CO to form an adsorbed CHCO species, which was a precursor to C2+ oxygenates. The presence of Mn did not have a significant effect on the rate of CH4 production. Ir was observed during empirical catalyst screening experiments to improve the activity and selectivity of Rh-Mn catalysts. Thus, the addition of Ir to the Rh-Mn nanoparticles also was probed computationally. Simulations of Rh-Mn-Ir nanoparticles revealed that, with sufficient Ir concentrations, the Rh, Mn and Ir presumably would be well mixed within a nanoparticle. Activation barriers were calculated for Rh-Mn-Ir nanoparticles for several C-, H-, and O-containing transitional species on the nanoparticle surface. It was found that the presence of Ir opened yet another reactive pathway whereby HCO is formed and may undergo insertion with CHx surface moieties. The reaction pathway opened by the presence of Ir is in addition to the CO + CH pathway opened by the presence of Mn. Similar to Mn, the presence of Ir was not found to not affect the rate of CH4 production.

  17. http://www.sjsu.edu/senate/s91-8.htm S91-8 SJSU ALCOHOL AND OTHER DRUG POLICY

    E-Print Network [OSTI]

    Gleixner, Stacy

    http://www.sjsu.edu/senate/s91-8.htm S91-8 SJSU ALCOHOL AND OTHER DRUG POLICY Legislative History Policy Recommendation presented by Gabe Reyes for the Instruction and Student Affairs Committee. This policy was approved and accepted as University Policy effective immediately. Copies were sent

  18. Characterization of oculomotor response to pseudorandom stimuli using time-domain analysis-effects of alcohol intoxication on smooth pursuit movements

    E-Print Network [OSTI]

    Goldsberry, Dennis Hamilton

    1997-01-01T23:59:59.000Z

    Oculomotor impairment is often a sign of brain dysfiinction. This study extends the effects of alcohol intoxication on the response of the smooth pursuit system to a pseudorandom non-linear sum-of-sinusoids input and attempts to develop mathematical...

  19. Catalytic decomposition of alcohols over size-selected Pt nanoparticles supported on ZrO2: A study of activity, selectivity, and stability

    E-Print Network [OSTI]

    Kik, Pieter

    ,17]. Catalytic reforming of gasoline additives, e.g. methanol, ethanol, and potentially butanol, may serve. Recent studies have focused on the feasibility of obtaining hydrogen (via steam reforming) from 2 hydrogen generation from alcohols (i.e. methanol, ethanol, propanol, butanol) can promote the use of fuel

  20. The economical production of alcohol fuels from coal-derived synthesis gas. Quarterly technical progress report No. 5, October 1, 1992--December 31, 1992

    SciTech Connect (OSTI)

    Not Available

    1993-01-01T23:59:59.000Z

    Two base case flow sheets have now been prepared. In the first, which was originally presented in TPR4, a Texaco gasifier is used. Natural gas is also burned in sufficient quantity to increase the hydrogen to carbon monoxide ratio of the synthesis gas to the required value of 1. 1 for alcohol synthesis. Acid gas clean up and sulfur removal are accomplished using the Rectisol process followed by the Claus and Beavon processes. About 10% of the synthesis gas is sent to a power generation unit in order to produce electric power, with the remaining 90% used for alcohol synthesis. For this process, the estimated installed cost is $474.2 mm. The estimated annual operating costs are $64.5 MM. At a price of alcohol fuels in the vicinity of $1. 00/gal, the pay back period for construction of this plant is about four years. The details of this case, called Base Case 1, are presented in Appendix 1. The second base case, called Base Case 2, also has a detailed description and explanation in Appendix 1. In Base Case 2, a Lurgi Gasifier is used. The motivation for using a Lurgi Gasifier is that it runs at a lower temperature and pressure and, therefore, produces by-products such as coal liquids which can be sold. Based upon the economics of joint production, discussed in Technical Progress Report 4, this is a necessity. Since synthesis gas from natural gas is always less expensive to produce than from coal, then alcohol fuels will always be less expensive to produce from natural gas than from coal. Therefore, the only way to make coal- derived alcohol fuels economically competitive is to decrease the cost of production of coal-derived synthesis gas. one method for accomplishing this is to sell the by-products from the gasification step. The details of this strategy are discussed in Appendix 3.

  1. Supramolecular structures in monohydroxy alcohols: Insights from shear-mechanical studies of a systematic series of octanol structural isomers

    E-Print Network [OSTI]

    Tina Hecksher; Bo Jakobsen

    2014-09-11T23:59:59.000Z

    A recent study [Gainaru et al. PRL., 112, 098301 (2014)] of two supercooled monohydroxy alcohols close to the glass-transition temperature showed that the Debye peak, thus far mainly observed in the electrical response, also has a mechanical signature. In this work, we apply broadband shear-mechanical spectroscopy to a systematic series of octanol structural isomers, x-methyl-3-heptanol (with x ranging from 2 to 6). We find that the characteristics of the mechanical signature overall follow the systematic behavior observed in dielectric spectroscopy. However, the influence from the molecular structure is strikingly small in mechanics (compared to roughly a factor 100 increase in dielectric strength) and one isomer clearly does not conform to the general ordering. Finally, the mechanical data surprisingly indicate that the size of the supramolecular structures responsible for the Debye process is nearly unchanged in the series.

  2. The economical production of alcohol fuels from coal-derived synthesis gas. Quarterly technical progress report Number 9, October 1, 1993--December 31, 1993

    SciTech Connect (OSTI)

    Not Available

    1994-01-01T23:59:59.000Z

    Catalysts based on molybdenum are being prepared using four different approaches. These materials have been characterized by IR, XRD and single-crystal studies. Modeling studies are continuing satisfactorily. The overall efficiency of each base case has been calculated and tested as a screening method to select feasible technologies. A methodology to determine the effects and influences of process variable uncertainties on the performance of a design has been developed. Input variables in the model to be considered include the reaction product distribution, the operating temperatures of equipment (e.g., gasifiers, separators, etc.), and the estimates of the thermodynamic model used in the computer aided design simulation of the process. The efficiency of the process can be modeled by calculation of output variables such as the payback period or the energy efficiency of the plant. The result will be a range of expected operating conditions for the process and an indication of which variables` uncertainties are most likely to affect process operating conditions. The stream exiting the reactor consists of alcohols, esters and water. The separation block consists of a network of distillation columns which separate the various alcohols and water. The choice and order of separation, operating conditions, degree of separation and amount to be bypassed are the random variables to be optimized by simulated annealing. The value of the above variables controls the mix of the alcohol streams to be used as gasoline additives exiting the network of distillation column. The total profitability is the price obtained by selling the various blended products after accounting for the cost of production of various alcohols.

  3. The economical production of alcohol fuels from coal-derived synthesis gas. Seventh quarterly technical progress report, April 1, 1993--June 30, 1993

    SciTech Connect (OSTI)

    Not Available

    1993-07-01T23:59:59.000Z

    An analysis of the current base cases has been undertaken to determine if the economic status of the proposed alcohol fuels may benefit from economies of scale. This analysis was based on a literature review which suggested that plants of capacities substantially below 5000 metric tons/day are unlikely to be competitive for the bulk production of alcohols for fuel consumption or chemicals manufacture. The preliminary results of this scale up procedure would indicate that the capacity of the current base cases be increased by a factor of eight. This would yield annual production of 4.1 million metric tons and essentially reduce the plant gate cost by approximately 41 percent in both cases. A facility of this size would be the equivalent of a medium sized oil refinery and would be capable of sustaining local market demands for fuel oxygenates. The actual competitiveness of this product with current oxygenates such as MTBE remains to be determined. The alcohol synthesis loop is being used to evaluate optimization procedures which will eventually be used to optimize the entire process. A more detailed design of the synthesis reactor is required, and a preliminary design of this reactor has been completed.

  4. Catalysis for Mixed Alcohol Synthesis from Biomass Derived Syngas: Cooperative Research and Development Final Report, CRADA Number CRD-08-292

    SciTech Connect (OSTI)

    Hensley, J.

    2013-04-01T23:59:59.000Z

    The Dow Chemical Company (Dow) developed and tested catalysts for production of mixed alcohols from synthesis gas (syngas), under research and development (R&D) projects that were discontinued a number of years ago. Dow possesses detailed laboratory notebooks, catalyst samples, and technical expertise related to this past work. The National Renewable Energy Laboratory (NREL) is conducting R&D in support of the United States Department of Energy (DOE) to develop methods for economically producing ethanol from gasified biomass. NREL is currently conducting biomass gasification research at an existing 1/2 ton/day thermochemical test platform. Both Dow and NREL believe that the ability to economically produce ethanol from biomass-derived syngas can be enhanced through collaborative testing, refinement, and development of Dow's mixed-alcohol catalysts at NREL's and/or Dow's bench- and pilot-scale facilities. Dow and NREL further agree that collaboration on improvements in catalysts as well as gasifier operating conditions (e.g., time, temperature, upstream gas treatment) will be necessary to achieve technical and economic goals for production of ethanol and other alcohols.

  5. Prenatal ethanol exposure programs an increased susceptibility of non-alcoholic fatty liver disease in female adult offspring rats

    SciTech Connect (OSTI)

    Shen, Lang; Liu, Zhongfen; Gong, Jun; Zhang, Li [Department of Pharmacology, Basic Medical School of Wuhan University, Wuhan 430071 (China); Wang, Linlong [Department of Orthopedic Surgery, Zhongnan Hospital of Wuhan University, Wuhan 430071 (China); Magdalou, Jacques [UMR 7561 CNRS-Nancy Université, Faculté de Médicine, Vandoeuvre-lès-Nancy (France); Chen, Liaobin [Department of Orthopedic Surgery, Zhongnan Hospital of Wuhan University, Wuhan 430071 (China); Wang, Hui, E-mail: wanghui19@whu.edu.cn [Department of Pharmacology, Basic Medical School of Wuhan University, Wuhan 430071 (China); Research Center of Food and Drug Evaluation, Wuhan University, Wuhan 430071 (China)

    2014-01-15T23:59:59.000Z

    Prenatal ethanol exposure (PEE) induces dyslipidemia and hyperglycemia in fetus and adult offspring. However, whether PEE increases the susceptibility to non-alcoholic fatty liver disease (NAFLD) in offspring and its underlying mechanism remain unknown. This study aimed to demonstrate an increased susceptibility to high-fat diet (HFD)-induced NAFLD and its intrauterine programming mechanisms in female rat offspring with PEE. Rat model of intrauterine growth retardation (IUGR) was established by PEE, the female fetus and adult offspring that fed normal diet (ND) or HFD were sacrificed. The results showed that, in PEE + ND group, serum corticosterone (CORT) slightly decreased and insulin-like growth factor-1 (IGF-1) and glucose increased with partial catch-up growth; In PEE + HFD group, serum CORT decreased, while serum IGF-1, glucose and triglyceride (TG) increased, with notable catch-up growth, higher metabolic status and NAFLD formation. Enhanced liver expression of the IGF-1 pathway, gluconeogenesis, and lipid synthesis as well as reduced expression of lipid output were accompanied in PEE + HFD group. In PEE fetus, serum CORT increased while IGF-1 decreased, with low body weight, hyperglycemia, and hepatocyte ultrastructural changes. Hepatic IGF-1 expression as well as lipid output was down-regulated, while lipid synthesis significantly increased. Based on these findings, we propose a “two-programming” hypothesis for an increased susceptibility to HFD-induced NAFLD in female offspring of PEE. That is, the intrauterine programming of liver glucose and lipid metabolic function is “the first programming”, and postnatal adaptive catch-up growth triggered by intrauterine programming of GC-IGF1 axis acts as “the second programming”. - Highlights: • Prenatal ethanol exposure increase the susceptibility of NAFLD in female offspring. • Prenatal ethanol exposure reprograms fetal liver’s glucose and lipid metabolism . • Prenatal ethanol exposure cause the adaptive change of glucocorticoid-IGF1 axis.

  6. MRI Assessment of Uterine Artery Patency and Fibroid Infarction Rates 6 Months after Uterine Artery Embolization with Nonspherical Polyvinyl Alcohol

    SciTech Connect (OSTI)

    Das, Raj, E-mail: rajdas@nhs.net; Gonsalves, Michael; Vlahos, Ioannis [St George's Healthcare NHS Trust, Blackshaw, Department of Radiology (United Kingdom)] [St George's Healthcare NHS Trust, Blackshaw, Department of Radiology (United Kingdom); Manyonda, Issac [St George's Healthcare NHS Trust, Department of Gynaecology (United Kingdom)] [St George's Healthcare NHS Trust, Department of Gynaecology (United Kingdom); Belli, Anna-Maria [St George's Healthcare NHS Trust, Blackshaw, Department of Radiology (United Kingdom)] [St George's Healthcare NHS Trust, Blackshaw, Department of Radiology (United Kingdom)

    2013-10-15T23:59:59.000Z

    Purpose: We have observed significant rates of uterine artery patency after uterine artery embolization (UAE) with nonspherical polyvinyl alcohol (nsPVA) on 6 month follow-up MR scanning. The study aim was to quantitatively assess uterine artery patency after UAE with nsPVA and to assess the effect of continued uterine artery patency on outcomes. Methods: A single centre, retrospective study of 50 patients undergoing bilateral UAE for uterine leiomyomata was undertaken. Pelvic MRI was performed before and 6 months after UAE. All embolizations were performed with nsPVA. Outcome measures included uterine artery patency, uterine and dominant fibroid volume, dominant fibroid percentage infarction, presence of ovarian arterial collaterals, and symptom scores assessed by the Uterine Fibroid Symptom and Quality of Life questionnaire (UFS-QOL). Results: Magnetic resonance angiographic evidence of uterine artery recanalization was demonstrated in 90 % of the patients (64 % bilateral, 26 % unilateral) at 6 months. Eighty percent of all dominant fibroids demonstrated >90 % infarction. The mean percentage reduction in dominant fibroid volume was 35 %. No significant difference was identified between nonpatent, unilateral, and bilateral recanalization of the uterine arteries with regard to percentage dominant fibroid infarction or dominant fibroid volume reduction. The presence of bilaterally or unilaterally patent uterine arteries was not associated with inferior clinical outcomes (symptom score or UFS-QOL scores) at 6 months. Conclusion: The high rates of uterine artery patency challenge the current paradigm that nsPVA is a permanent embolic agent and that permanent uterine artery occlusion is necessary to optimally treat uterine fibroids. Despite high rates of uterine artery recanalization in this cohort, satisfactory fibroid infarction rates and UFS-QOL scores were achieved.

  7. Transarterial Ethylene Vinyl Alcohol Copolymer Visualization and Penetration After Embolization of Life-Threatening Hemoptysis: Technical and Clinical Outcomes

    SciTech Connect (OSTI)

    Bommart, Sebastien, E-mail: s-bommart@chu-montpellier.fr [CHU of Montpellier, Arnaud de Villeneuve Hospital, Department of Radiology (France); Bourdin, Arnaud [CHU of Montpellier, Arnaud de Villeneuve Hospital, Department of Respiratory Diseases (France); Giroux, Marie France [Centre Hospitalier de l'Universite de Montreal, Notre-Dame Hospital, Department of Radiology (Canada); Klein, Francois; Micheau, Antoine; Bares, Valerie Monnin; Kovacsik, Helene [CHU of Montpellier, Arnaud de Villeneuve Hospital, Department of Radiology (France)

    2012-06-15T23:59:59.000Z

    Objectives: This study was designed to evaluate the feasibility of using ethylene vinyl alcohol copolymer (EVAC) for bronchial artery embolization (BAE) in patients with life-threatening hemoptysis and to compare the visualization and transarterial penetration of EVAC under fluoroscopy and computed tomography (CT). Methods: Fifteen patients (mean age, 62.9 (range, 24-82) years) who were referred for life-threatening hemoptysis (27 month period) underwent BAE using EVAC. All patients had thoracic CT examination before and after BAE. Technical and clinical results were evaluated. Visibility and extent of cast penetration (graded 1-4) on fluoroscopy and postprocedure CT were assessed and compared. Results: BAE was feasible in all but one artery (due to spasm; n = 27; 96.4%). No procedure-related complications or deaths were detected. Two patients had recurrent bleeding in the following day (13.3%). Immediate clinical success was achieved in 14 cases (93.3%) after reembolization of pulmonary artery pseudoaneurysm in one patient (mean follow-up, 43.5 (range, 14-148) days). Visibility of the cast was possible in 73.3% of patients (n = 11) under fluoroscopy (mean cast penetration 1.66) and in all patients under CT (mean cast penetration 2.06). The postinjection fluoroscopic visibility in 6 of 15 (40%) patients was inferior to CT (P < 0.02). Conclusions: BAE with EVAC seems to be feasible and safe with immediate control of hemoptysis in most patients. The postinjection fluoroscopic visibility of EVAC under fluoroscopy was inferior to CT.

  8. Hydrogen bonding and solvation dynamics of n-methylacetamide in denatured water (D?O) or denatured chloroform (CDCl?) from nonlinear spectroscopy

    E-Print Network [OSTI]

    McCracken, Justine M. (Justine Meghan), 1979-

    2004-01-01T23:59:59.000Z

    Hydrogen bonding between N-methylacetamide (NMA) and different solvents (D?O or CDCl?) was studied by using two-dimensional infrared spectroscopy to probe the frequency fluctuations of the amide I mode of the solvated NMA. ...

  9. Coal liquefaction process using pretreatment with a binary solvent mixture

    DOE Patents [OSTI]

    Miller, Robert N. (Allentown, PA)

    1986-01-01T23:59:59.000Z

    An improved process for thermal solvent refining or hydroliquefaction of non-anthracitic coal at elevated temperatures under hydrogen pressure in a hydrogen donor solvent comprises pretreating the coal with a binary mixture of an aromatic hydrocarbon and an aliphatic alcohol at a temperature below 300.degree. C. before the hydroliquefaction step. This treatment generally increases both conversion of coal and yields of oil.

  10. Identification of the Wax Ester Synthase/Acyl-Coenzyme A:Diacylglycerol Acyltransferase WSD1 Required for

    E-Print Network [OSTI]

    Kunst, Ljerka

    Identification of the Wax Ester Synthase/Acyl-Coenzyme A:Diacylglycerol Acyltransferase WSD1 Required for Stem Wax Ester Biosynthesis in Arabidopsis1,2[W][OA] Fengling Li, Xuemin Wu, Patricia Lam Columbia, Canada V6T 1Z1 (R.J.) Wax esters are neutral lipids composed of aliphatic alcohols and acids

  11. Municipal Solid Waste (MSW) to Liquid Fuels Synthesis, Volume 2: A Techno-economic Evaluation of the Production of Mixed Alcohols

    SciTech Connect (OSTI)

    Jones, Susanne B.; Zhu, Yunhua; Valkenburt, Corinne

    2009-05-01T23:59:59.000Z

    Biomass is a renewable energy resource that can be converted into liquid fuel suitable for transportation applications and thus help meet the Energy Independence and Security Act renewable energy goals (U.S. Congress 2007). However, biomass is not always available in sufficient quantity at a price compatible with fuels production. Municipal solid waste (MSW) on the other hand is readily available in large quantities in some communities and is considered a partially renewable feedstock. Furthermore, MSW may be available for little or no cost. This report provides a techno-economic analysis of the production of mixed alcohols from MSW and compares it to the costs for a wood based plant. In this analysis, MSW is processed into refuse derived fuel (RDF) and then gasified in a plant co-located with a landfill. The resulting syngas is then catalytically converted to mixed alcohols. At a scale of 2000 metric tons per day of RDF, and using current technology, the minimum ethanol selling price at a 10% rate of return is approximately $1.85/gallon ethanol (early 2008 $). However, favorable economics are dependent upon the toxicity characteristics of the waste streams and that a market exists for the by-product scrap metal recovered from the RDF process.

  12. Ethyl Alcohol Production.

    E-Print Network [OSTI]

    O'Neal, Henry

    1981-01-01T23:59:59.000Z

    +------.-----.------.------.-----.------.-- o 2 3 4 5 6 Time (hrs.) Batch 29 Cooking and Fermenting Log Corn . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 682 pounds (12.2 bushels) Natural gas used Meter measures in increments of 100 cubic feet. Cooking.... The following general production steps are the ones presently used and may change with future production experience. 1. The grain is ground in a hammermill with a 1/8- inch screen. Each of the 350 gallon cooker fermenter tanks normally handles a 12...

  13. E-Print Network 3.0 - acid-denatured acbp controlled Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ; Biology and Medicine 5 Rapid mixing methods for exploring the kinetics of protein folding Heinrich Roder,a,b,* Kosuke Maki,a,1 Summary: events, such as cis-trans...

  14. proteinsSTRUCTURE O FUNCTION O BIOINFORMATICS Compact dimension of denatured states

    E-Print Network [OSTI]

    Technology Division, National Nano Device Laboratories, Hsinchu 30078, Taiwan 6 Institute of Physics, Academy folding/unfolding proc- esses would not be solved completely even the protein native state might have been the methods of fluorescence stopped-flow kinetics and efficiency of energy transfer (EET)12­14 to monitor

  15. Analysis of yeast and archaeal population dynamics in kimchi using denaturing gradient gel electrophoresis

    E-Print Network [OSTI]

    Bae, Jin-Woo

    -806, South Korea b Environmental Biotechnology National Core Research Center, Gyeongsang National University Korea A B S T R A C TA R T I C L E I N F O Article history: Received 10 April 2008 Received in revised kimchi fermentation presents a range of environmental conditions that could support many different

  16. A comparison of the urea and guanidinium chloride denaturation of four proteins

    E-Print Network [OSTI]

    Greene, Raymond Franklin

    1973-01-01T23:59:59.000Z

    . 3. ~sos(ace Lysosyme (Lot No. LYSF OCC) was obtained from Worthington Biochemical Corporation as a two time recrystallised powder. The protein was used without further purification. 0. c-+C~a~ot ~sip. e-Chymotrypsln (Lot No. CDI 2LX), a three... time recrystallised produot of chymo- trypsinogen was obtained from Worthington Biochemical Corporation as a lyophilised powder and used without further purifioation. 5. Urea. Ultra pure urea (Lot No. U1039) was purchased from Mann Research...

  17. Temperature and Chemical Denaturant Dependence of Forced Unfolding of Titin I27 Eric Botello,

    E-Print Network [OSTI]

    Kiang, Ching-Hwa

    environment to alter the protein folding energy landscape and compared the change in the unfolding free-14 and the reaction rates of receptor-ligand binding15,16 and protein folding17 are increased to allow one to observe effects on protein folding offers great opportunity to explore the complex protein folding landscape21

  18. Toward a Taxonomy of the Denatured State: Small Angle Scattering Studies of Unfolded Proteins

    SciTech Connect (OSTI)

    Millett, I.S.; Doniach, S.; Plaxco, K.W. (Stanford); (UCSB)

    2005-02-15T23:59:59.000Z

    Despite the critical role the unfolded state plays in defining protein folding kinetics and thermodynamics (Berg et al., 2002; Dunker, 2002; Shortle, 2002; Wright and Dyson, 2002), our understanding of its detailed structure remains rather rudimentary; the heterogeneity of the unfolded ensemble renders difficult or impossible its study by traditional, atomic-level structural methods. Consequently, recent years have seen a significant expansion of small-angle X-ray and neutron scattering (SAXS and SANS, respectively) techniques that provide direct, albeit rotationally and time-averaged, measures of the geometric properties of the unfolded ensemble. These studies have reached a critical mass, allowing us for the first time to define general observations regarding the nature of the geometry - and possibly the chemistry and physics - of unfolded proteins.

  19. Transition metal complexes of oxazolinylboranes and cyclopentadienyl-bis(oxazolinyl)borates: Catalysts for asymmetric olefin hydroamination and acceptorless alcohol decarbonylation

    SciTech Connect (OSTI)

    Manna, Kuntal [Ames Laboratory

    2012-12-17T23:59:59.000Z

    The research presented and discussed in this dissertation involves the synthesis of transition metal complexes of oxazolinylboranes and cyclopentadienyl-bis(oxazolinyl)borates, and their application in catalytic enantioselective olefin hydroamination and acceptorless alcohol decarbonylation. Neutral oxazolinylboranes are excellent synthetic intermediates for preparing new borate ligands and also developing organometallic complexes. Achiral and optically active bis(oxazolinyl)phenylboranes are synthesized by reaction of 2-lithio-2-oxazolide and 0.50 equiv of dichlorophenylborane. These bis(oxazolinyl)phenylboranes are oligomeric species in solid state resulting from the coordination of an oxazoline to the boron center of another borane monomer. The treatment of chiral bis(oxazolinyl)phenylboranes with sodium cyclopentadienide provide optically active cyclopentadienyl-bis(oxazolinyl)borates H[PhB(C{sub 5}H{sub 5})(Ox{sup R}){sub 2}] [Ox{sup R} = Ox{sup 4S-iPr,Me2}, Ox{sup 4R-iPr,Me2}, Ox{sup 4S-tBu]}. These optically active proligands react with an equivalent of M(NMe{sub 2}){sub 4} (M = Ti, Zr, Hf) to afford corresponding cyclopentadienyl-bis(oxazolinyl)borato group 4 complexes {PhB(C{sub 5}H{sub 4})(Ox{sup R}){sub 2}}M(NMe{sub 2}){sub 2} in high yields. These group 4 compounds catalyze cyclization of aminoalkenes at room temperature or below, providing pyrrolidine, piperidine, and azepane with enantiomeric excesses up to 99%. Our mechanistic investigations suggest a non-insertive mechanism involving concerted C?N/C?H bond formation in the turnover limiting step of the catalytic cycle. Among cyclopentadienyl-bis(oxazolinyl)borato group 4 catalysts, the zirconium complex {PhB(C{sub 5}H{sub 4})(Ox{sup 4S-iPr,Me2}){sub 2}}Zr(NMe{sub 2}){sub 2} ({S-2}Zr(NMe{sub 2}){sub 2}) displays highest activity and enantioselectivity. Interestingly, {S-2}Zr(NMe{sub 2}){sub 2} also desymmetrizes olefin moieties of achiral non-conjugated aminodienes and aminodiynes during cyclization. The cyclization of aminodienes catalyzed by {S-2}Zr(NMe{sub 2}){sub 2} affords diastereomeric mixture of cis and trans cylic amines with high diasteromeric ratios and excellent enantiomeric excesses. Similarly, the desymmetrization of alkyne moieties in {S-2}Zr(NMe{sub 2}){sub 2}-catalyzed cyclization of aminodiynes provides corresponding cyclic imines bearing quaternary stereocenters with enantiomeric excesses up to 93%. These stereoselective desymmetrization reactions are significantly affected by concentration of the substrate, temperature, and the presence of a noncyclizable primary amine. In addition, both the diastereomeric ratios and enantiomeric excesses of the products are markedly enhanced by N-deuteration of the substrates. Notably, the cationic zirconium-monoamide complex [{S-2}Zr(NMe{sub 2})][B(C{sub 6}F{sub 5}){sub 4}] obtained from neutral {S-2}Zr(NMe{sub 2}){sub 2} cyclizes primary aminopentenes providing pyrrolidines with S-configuration; whereas {S-2}Zr(NMe{sub 2}){sub 2} provides R-configured pyrrolidines. The yttrium complex {S-2}YCH{sub 2}SiMe{sub 3} also affords S-configured pyrrolidines by cyclization of aminopentenes, however the enantiomeric excesses of products are low. An alternative optically active yttrium complex {PhB(C{sub 5}H{sub 4})(Ox{sup 4S-tBu}){sub 2}}YCH{sub 2}SiMe{sub 3} ({S-3}YCH{sub 2}SiMe{sub 3}) is synthesized, which displays highly enantioselective in the cyclization of aminoalkenes at room temperature affording S-configured cyclic amines with enantiomeric excesses up to 96%. A noninsertive mechanism involving a six-membered transition state by a concerted C?N bond formation and N?H bond cleavage is proposed for {S-3}YCH{sub 2}SiMe{sub 3} system based on the kinetic, spectroscopic, and stereochemical features. In the end, a series of bis- and tris(oxazolinyl)borato iridium and rhodium complexes are synthesized with bis(oxazolinyl)phenylborane [PhB(Ox{sup Me2}){sub 2}]{sub n}, tris(oxazolinyl)borane [B(Ox{sup Me2}){sub 3}]n, and tris(4,4-dimethyl-2-oxazolinyl)phenylborate [To{sup M}]{sup ?}. All these new an

  20. Photochemistry and Photobiology, 2014, 90: 338343 Aliphatic b-Nitroalcohols for Therapeutic Corneoscleral Cross-Linking

    E-Print Network [OSTI]

    Turro, Nicholas J.

    are relevant to the translation of this technol- ogy into clinical use. INTRODUCTION Riboflavin layer followed by the application of a 0.1% riboflavin-containing solution to the exposed underlying corneal stromal bed. After confirming ade- quate infiltration of the riboflavin photosensitizer, a 360 nm

  1. aliphatic solvent n-hexane: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    n-hexane crystallized in silicon nanochannels: A combined x-ray diffraction and sorption isotherm study CERN Preprints Summary: We present an x-ray diffraction study on n-hexane...

  2. Alteration and release of aliphatic compounds by the polychaete Nereis virens (Sars) experimentally fed with

    E-Print Network [OSTI]

    Boyer, Edmond

    with time and no microbial hydrocarbon biodegradation were evidenced. Our results suggest that marine worm an important role with regard to the fate of hydrocarbon pollutants (Lee and Swartz, 1980). Previous works their bioavailability (Mihelcic and Luthy, 1991; Madsen et al., 1997) and resulting bacterial biodegradation (Gordon et

  3. Alteration and release of aliphatic compounds by the polychaete Nereis virens (Sars) experimentally fed with

    E-Print Network [OSTI]

    Mailhes, Corinne

    with time and no microbial hydrocarbon biodegradation were evidenced. Our results suggest that marine worm `bioturbation' play an important role with regard to the fate of hydrocarbon pollutants (Lee and Swartz, 1980 biodegradation (Gordon et al., 1978; Bauer et al., 1988; McElroy et al., 1990). In areas of intensive reworking

  4. Binary Phases of Aliphatic N-Oxides and Water: Force Field Development and Molecular Dynamics Simulation

    E-Print Network [OSTI]

    Berry, R. Stephen

    the reactivity of the swollen cellulose material for further derivatization in pollution-free industrial fiber future parametrization of other species. By construction, the force field is compatible with widely used play an increasingly important role for industrial applications, e.g., for tuning solubility

  5. Divergent Mechanistic Avenues to an Aliphatic Polyesteracetal or Polyester from a Single Cyclic Esteracetal

    E-Print Network [OSTI]

    Kokkoli, Efie

    , a statistical copolymer of 1,3-dioxolan-4-one (DOX) and lactide was reported. While the patent provided little the synthesis of a variety of copolymers of DOX and lactide and reports up to 36% DOX incorporation. A computational study of the ring strain in DOX suggests that DOX is slightly less strained than -butyrolactone

  6. aliphatic carbon-centered radicals: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    organizational transformation, new organizational forms and the new public management (NPM) in a novel way. Data reveal important limits to intended organizational transformation...

  7. Reductive dechlorination of chlorinated aliphatic hydrocarbons by Fe(ii) in degradative solidification/stabilization

    E-Print Network [OSTI]

    Jung, Bahng Mi

    2007-04-25T23:59:59.000Z

    ............................................................................................7 2.1 Degradative Solidification/Stabilization...................................................7 2.2 Cement Chemistry.....................................................................................8 2.2.1 Portland Cement... of typical cements . .........................9 Table 2.2 Portland cement compound transformation................................................15 Table 2.3 The oxides, hydroxides, and oxyhydroxides of Fe.....................................16 Table 2...

  8. A kinetic study of the reactions of diphenyldiazomethane with some aliphatic carboxylic acids

    E-Print Network [OSTI]

    Hoefelmeyer, Albert Bernard

    1954-01-01T23:59:59.000Z

    (a) C. K. Ingold, J. Chem. Soc., 1032 (1930). (b) S. W. Timm and C. N. Iiinshelwood, J. Chem. Soc., 862 (1933). (c) C. K. Ingold et al., J. Chem. Soc., 3^27?(l 9^3). 13 ?. A. Waters, "Physical Aspects of Organic Chemistry," D. Van Nostrand Co., Inc...., New York, N. Y., 1950# Chapter XI. nil (a) I. Dostrovsky, E. D. Hughes, and K. Ingold, J.Chem. Soc., 173 (19U6). (b) K. A. Cooper, S. D. Hughes, C. K. Ingold, and B. J. Mac Nulty, J. Chem. Soc., 2038 (l 9 l|8). (c) P. M. Dunbar and L. P. Hammett, J...

  9. aliphatic c-h bond: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    activation of functionalized hydrocarbons. II. CH and CCN bond activation of acetonitrile and benzonitrile. Open Access Theses and Dissertations Summary: ??Several...

  10. Adsorption from flooding solutions in porous media: Second annual report, October 1986-October 1987. [C)sub 8)benzenesulfonate and C)sub 12)EO)sub 8) alcohol

    SciTech Connect (OSTI)

    Somasundaran, P.; Bell, R.; Boyd, J.; Chandar, P.; Fu, E.; Huang, Y.; Ramachandran, R.; Pereira, V.; Sivakumar, A.; Snell, E.; Velosa, A.; Viswanathan, K.V.

    1988-03-01T23:59:59.000Z

    Surfactant formulations that are used in enhanced oil recovery consist of mixtures of various components. We have continued studies on mixtures of an anionic surfactant, C/sub 8/benzenesulfonate, and a nonionic surfactantt. C/sub 12/EO/sub 8/alcohol. Adsorption data on alumina and silica show that strong interactions between the two surfactants occur. On alumina on which the nonionic does not absorb by itself the presence of small amounts of adsorbed sulfonate was sufficient to cause significant adsorption of ethoxylated alcohol. On silica sulfonate did not absorb by itself but only did so in the presence of alcohol. Interactions between surfactants were quantified using the regular mixing model. Interaction parameters between -3 and -5 were determined at the liquidair interface in mixed micelles from surface tension data for different surfactant compositions. Work is focused on directly measuring thermodynamic quantities using microcalorimetry. Surfactant structural effects were also studied. A series of branched C/sub 14/benezenesulfonates emphasizes characterization along with adsorption measurements. Results showed major influences in addition to that of chain lenth and chain branching due to the position in the benzene ring of the longer alkyl chain in relation to that of the sulfonate group. 43 refs., 54 figs., 3 tabs

  11. Fourier transform electron paramagnetic resonance study of the photoreduction of anthraquinone with 4-methyl-2,6-di-tert-butylphenol in alcoholic solutions

    SciTech Connect (OSTI)

    Plueschau, M.; Kroll, G. [Universitaet Dortmund (Germany); Dinse, K.P. [TH Darmstadt (Germany)] [and others

    1992-10-29T23:59:59.000Z

    Using FT-EPR following laser excitation, the primary photochemical process in the photoreduction of anthraquinone with 4-methyl-2,6-di-tert-butylphenol was investigated. High-resolved spin-polarized EPR spectra taken with nanosecond time resolution gave unambiguous evidence for a two-step hydrogen abstraction reaction, consisting of a primary electron transfer followed by proton abstraction with a time delay, which allows for a noticeable escape probability of the initially generated anthrasemiquinone radical anion (AQ{sup {sm_bullet}minus}). The time dependence of the EPR intensities of the neutral 10-hydroxy-anthroxyl radical (AQH{sup {sm_bullet}}) as well as of AQ{sup {sm_bullet}} could be simulated for the full experimentally accessible time interval of 10 ns to 100 {mu}s. The kinetic model used invokes optical spin polarization, spin-lattice relaxation, radical generation, and AQH{sup {sm_bullet}}AQ interconversion. In addition, from an analysis of the highly-resolved FT-EPR spectra a complete set of AQH{sup {sm_bullet}} hyperfine splitting (hfs) constants could be measured in two different alcohols for the first time. 30 refs., 4 figs., 2 tabs.

  12. Fluctuating micro-heterogeneity in water–tert-butyl alcohol mixtures and lambda-type divergence of the mean cluster size with phase transition-like multiple anomalies

    SciTech Connect (OSTI)

    Banerjee, Saikat; Furtado, Jonathan; Bagchi, Biman, E-mail: bbagchi@sscu.iisc.ernet.in [SSCU, Indian Institute of Science, Bangalore 560012 (India)] [SSCU, Indian Institute of Science, Bangalore 560012 (India)

    2014-05-21T23:59:59.000Z

    Water–tert-butyl alcohol (TBA) binary mixture exhibits a large number of thermodynamic and dynamic anomalies. These anomalies are observed at surprisingly low TBA mole fraction, with x{sub TBA} ? 0.03–0.07. We demonstrate here that the origin of the anomalies lies in the local structural changes that occur due to self-aggregation of TBA molecules. We observe a percolation transition of the TBA molecules at x{sub TBA} ? 0.05. We note that “islands” of TBA clusters form even below this mole fraction, while a large spanning cluster emerges above that mole fraction. At this percolation threshold, we observe a lambda-type divergence in the fluctuation of the size of the largest TBA cluster, reminiscent of a critical point. Alongside, the structure of water is also perturbed, albeit weakly, by the aggregation of TBA molecules. There is a monotonic decrease in the tetrahedral order parameter of water, while the dipole moment correlation shows a weak nonlinearity. Interestingly, water molecules themselves exhibit a reverse percolation transition at higher TBA concentration, x{sub TBA} ? 0.45, where large spanning water clusters now break-up into small clusters. This is accompanied by significant divergence of the fluctuations in the size of largest water cluster. This second transition gives rise to another set of anomalies around. Both the percolation transitions can be regarded as manifestations of Janus effect at small molecular level.

  13. Conducting polymer blends: Polypyrrole and polythiophene blends with polystyrene, polycarbonate resin, poly(vinyl alcohol) and poly(vinyl methyl ketone)

    SciTech Connect (OSTI)

    Wang, H.L.

    1992-01-01T23:59:59.000Z

    Various aromatic compounds can be polymerized by electrochemical oxidation in solution containing a supporting electrolyte. Most studies have been devoted to polypyrrole and polythiophene. In situ doping during electrochemical polymerization yields free standing conductive polymer film. One major approach to making conducting polymer blends is electrochemical synthesis after coating the host polymer on a platinum electrode. In the electrolysis of pyrrole or thiophene monomer, using (t-Bu[sub 4]N)BF[sub 4] as supporting electrolyte, and acetonitrile as solvent, monomer can diffuse through the polymer film, to produce a polypyrrole or polythiophene blend in the film. Doping occurs along with polymerization to form a conducting polymer alloy. The strongest molecular interaction in polymers, and one that is central to phase behavior, is hydrogen bonding. This mixing at the molecular level enhances the degree of miscibility between two polymers and results in macroscopic properties indicative of single phase behavior. In this dissertation, the authors describes the syntheses of conducting polymer blends: polypyrrole and polythiophene blends with polystyrene, poly(bisphenol-A-carbonate), polyvinyl alcohol and poly(vinyl methyl ketone). The syntheses are performed both electrochemically and chemically. Characterization of these blends was carried out by Fourier Transform Infrared spectroscopy, Differential Scanning Calorimetry, Thermogravimetric Analysis, Scanning Electron Microscopy, and X-ray diffraction. Percolating threshold conductivities occur from 7% to 20% for different polymer blends. The low threshold conductivity is attributed to blend homogeneity enhanced by hydrogen bonding between the carbonyl group in the insulating polymer and the N-H group in polypyrrole. Thermal stability, environmental stability, mechanical properties, crystallinity and morphological structure are also discussed. The authors have also engaged in the polymerization of imidazoles.

  14. Portal Vein Embolization with Radiolabeled Polyvinyl Alcohol Particles in a Swine Model: Hepatic Distribution and Implications for Pancreatic Islet Cell Transplantation

    SciTech Connect (OSTI)

    Owen, Richard J., E-mail: drrichardowen@tbwifi.c [University of Alberta, Department of Radiology and Diagnostic Imaging, Faculty of Medicine, Walter Mackenzie Health Sciences Center (Canada); Mercer, John R. [University of Alberta, Department of Oncologic Imaging, Faculty of Medicine (Canada); Al-Saif, Faisal; Molinari, Michele [University of Alberta Hospital, Department of Surgery (Canada); Ashforth, Robert A. [University of Alberta, Department of Radiology and Diagnostic Imaging, Faculty of Medicine, Walter Mackenzie Health Sciences Center (Canada); Rajotte, Ray V. [University of Alberta, Surgical-Medical Research Institute (Canada); Conner-Spady, Barbara [University of Alberta, Department of Radiology and Diagnostic Imaging, Faculty of Medicine, Walter Mackenzie Health Sciences Center (Canada); Shapiro, A. M. James [University of Alberta, Clinical Islet Transplant Program (Canada)

    2009-05-15T23:59:59.000Z

    The distribution of radiolabeled polyvinyl alcohol microspheres (PVAMs) when infused into the portal vein of domestic swine was investigated, with the purpose of assessing implications for pancreatic islet cell transplantation. PVAMs measuring 100-300 {mu}m (Contour SE) and labeled with {sup 99m}Tc were infused into the main portal vein of 12 swine, with intermittent portal venous pressure measurements. The infusion catheter was introduced antegradely via direct or indirect cannulation of the portal vein. The liver was subsequently divided into anatomical segments. Radioactivity (decay corrected) was measured for {sup 99m}Tc microsphere synthesis, dose preparation, gross organ activities, tissue samples, and blood. Particulate labeling, catheter positioning, and infusion were successful in all cases. The number of particles used was (185,000 {+-} 24,000) with a volume of 1 ml. Mean portal pressure at 5 min was significantly higher than baseline, but without a significant difference at 15 min. Extrahepatic tissue and serum radioactivity was negligible. A significant difference in number of radioactive particles per gram was detected between segments 6/7 and segments 5/8. Intrasegmental activity was analyzed, and for segments 2/3 a significant difference in the percentage dose per gram across samples was demonstrated (P = 0.001). Effective and stable radiolabeling of PVAMs with {sup 99m}Tc-sulfur colloid was demonstrated. Portal venous infusion of 100- to 300-{mu}m particles showed entrapment in the sinusoidal hepatic system with transient portal pressure elevation. Preferential embolization into the right lateral and posterior segments occurs, suggesting that flow dynamics/catheter tip position plays a role in particle distribution.

  15. A SEARCH FOR INTERSTELLAR CARBON-CHAIN ALCOHOL HC{sub 4}OH IN STAR-FORMING REGION L1527 AND DARK CLOUD TMC-1

    SciTech Connect (OSTI)

    Araki, Mitsunori; Yamabe, Hiromichi; Koshikawa, Naohiro; Tsukiyama, Koichi [Department of Chemistry, Faculty of Science Division I, Tokyo University of Science, 1-3 Kagurazaka, Shinjuku-ku 162-8601, Tokyo (Japan); Takano, Shuro [Nobeyama Radio Observatory, 462-2 Nobeyama, Minamimaki, Minamisaku, Nagano 384-1305 (Japan); Nakane, Aya; Okabayashi, Toshiaki [Department of Chemistry, Faculty of Science, Shizuoka University, 836 Oya, Suruga-ku, Shizuoka 422-8529 (Japan); Kunimatsu, Arisa; Kuze, Nobuhiko, E-mail: araki@rs.kagu.tus.ac.jp [Department of Materials and Life Sciences, Faculty of Science and Technology, Sophia University, 7-1 Kioi-cho, Chiyoda-ku 102-8554, Tokyo (Japan)

    2012-01-10T23:59:59.000Z

    We report a sensitive search for the rotational transitions of the carbon-chain alcohol HC{sub 4}OH in the frequency range 21.2-46.7 GHz in the star-forming region L1527 and the dark cloud TMC-1. The motivation was laboratory detection of HC{sub 4}OH by microwave spectroscopy. Despite achieving rms noise levels of several millikelvin in the antenna temperature using the 45 m telescope at Nobeyama Radio Observatory, the detection was not successful, leading to 3{sigma} upper limits corresponding to the column densities of 2.0 Multiplication-Sign 10{sup 12} and 5.6 Multiplication-Sign 10{sup 12} cm{sup -2} in L1527 and TMC-1, respectively. These upper limits indicate that [HC{sub 4}OH]/[HC{sub 5}N] ratios are less than 0.3 and 0.1 in L1527 and TMC-1, respectively, where HC{sub 5}N is an HC{sub 4}-chain cyanide and HC{sub 4}OH is a hydroxide. These ratios suggest that the cyano carbon-chain molecule dominates the hydroxyl carbon-chain molecule in L1527 and TMC-1. This is contrary to the case of saturated compounds in hot cores, e.g., CH{sub 3}OH and CH{sub 3}CN, and can be a chemical feature of carbon-chain molecules in L1527 and TMC-1. In addition, the column densities of the 'unsubstituted' carbon-chain molecule C{sub 4}H and the sulfur-bearing molecules SO and HCS{sup +} were determined from detected lines in L1527.

  16. Coal liquefaction process using pretreatment with a binary solvent mixture

    DOE Patents [OSTI]

    Miller, R.N.

    1986-10-14T23:59:59.000Z

    An improved process for thermal solvent refining or hydroliquefaction of non-anthracitic coal at elevated temperatures under hydrogen pressure in a hydrogen donor solvent comprises pretreating the coal with a binary mixture of an aromatic hydrocarbon and an aliphatic alcohol at a temperature below 300 C before the hydroliquefaction step. This treatment generally increases both conversion of coal and yields of oil. 1 fig.

  17. Homologation process making higher alcohols

    DOE Patents [OSTI]

    Leung, Tak W. (Charleston, WV); Dombek, Bernard D. (Charleston, WV)

    1990-01-01T23:59:59.000Z

    A liquid phase process for the manufacture of C.sub.2+ alkanols by the reaction of hydrogen with carbon monoxide in the presence of a catalyst containing ruthenium, cobalt, a halide-containing compound, and an aromatic compound substituted in adjacent ring positions by nitrogen atoms. The process embraces the use of rhodium as an additive to the catalyst system.

  18. Alcohol Use, Comorbidity, and Mortality

    E-Print Network [OSTI]

    2006-01-01T23:59:59.000Z

    2–3 drinks per day and having gout or anxiety or taking aby a doctor that they had gout, hepatitis, or ulcer disease,psychiatric conditions Gout, anxiety disorder (history of

  19. ESE Alcohol | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualPropertyd8c-a9ae-f8521cbb8489 No revision| Open Jump to: navigation,ProtectionEQuilibriumSpaESE

  20. The Care and Cleaning of Furniture and Furnishings.

    E-Print Network [OSTI]

    O'Donnell, Dorothy C.

    1981-01-01T23:59:59.000Z

    . SILVER Plated or Sterling Commercially-prepared polishes in liquid, powder or paste form are readily available. Through recent research, a tarnish preventative silver polish has been developed. Many silversmith companies recommend and some produce... removes tarnish, it also kills the depth of pattern and luster of silver. The method is omitted from this booklet. Cleaner for Sterling or Plated Silver How to make: 3 parts fine whiting 1 part either household ammonia (clear) or denatured alcohol...

  1. Potential of mean force between hydrophobic solutes in the Jagla model of water and implications for cold denaturation of proteins

    E-Print Network [OSTI]

    Stanley, H. Eugene

    of nanoparticles J. Appl. Phys. 111, 024702 (2012) Hybrid modeling and simulation of stochastic effects on progression through the eukaryotic cell cycle J. Chem. Phys. 136, 034105 (2012) Amino acid analogues bind on the hard spheres as a function of their separation, and (c) determining the position dependent chemical po

  2. Electrochemical and Solid-State Letters, 9 ?6 ? A261-A264 ?2006? 1099-0062/2006/9?6?/A261/4/$20.00 © The Electrochemical Society Alcohol Fuel Cells at Optimal Temperatures

    E-Print Network [OSTI]

    Tetsuya Uda; A Dane A. Boysen; B Calum R. I. Chisholm; Sossina M. Haile Z

    High-power-density alcohol fuel cells can relieve many of the daunting challenges facing a hydrogen energy economy. Here, such fuel cells are achieved using CsH 2PO 4 as the electrolyte and integrating into the anode chamber a Cu-ZnO/Al 2O 3 methanol steam-reforming catalyst. The temperature of operation, ?250°C, is matched both to the optimal value for fuel cell power output and for reforming. Peak power densities using methanol and ethanol were 226 and 100 mW/cm 2, respectively. The high power output ?305 mW/cm 2 ? obtained from reformate fuel containing 1 % CO demonstrates the potential of this approach with optimized reforming catalysts and also the tolerance to CO poisoning at these elevated temperatures.

  3. Application of organolithium compounds for the preparation of some aliphatic and alicyclic phosphines, phosphine oxides and phosphine sulfides

    E-Print Network [OSTI]

    Screttas, Constantinos G

    1961-01-01T23:59:59.000Z

    @? ~?? Qg) 23h2? 19? Oelkie? N?? pygmy? Qgg? ~i? @ 636)71h(1486)? 2o. te?L~. 4. w. , Net, a. m Isg?14. a. I. , g. ~. ~. , gg. g9. RL ~ heal& 0? Lh?? @g? Q~Q Qgg? ~ g? 326(1932) TL?Q? $? g? 966(1933) ~ 22? 9?fs??a? ??, y? ~. ~? @g, ?, g, 1684(1921) ~ 23...? Oaf fs?ay D? D? ??4 Watt?1 ~ C? 4 ~ ~ QQ?? Q? 3696(1999) ~ 2$? LLL?h?elis, ??, ~?? ~? 63(1901) ~ l5eh?elis, k? a?4 Oleishs?sa? L? ~ ~?? g? 801?1961(lw)2) ~ 26? ICeh?olio/ I? ??4 Ileeee? ?? ~ Q@?? gy 1610(1842)? 27 ~ Herr?LL ~ D? I?? g? AS...

  4. THE CHEMISTRY OF COAL MODEL COMPOUNDS -CLEAVAGE OF ALIPHATIC BRIDGES BETWEEN AROMATIC NUCLEI CATALYSED BY LEWIS ACIDS

    E-Print Network [OSTI]

    Taylor, Newell D.

    2011-01-01T23:59:59.000Z

    and Background I. II. III. IV. II. Coal Liquefaction . •Coal Structure • • . Lewis Acid Catalysts. Scope andOrganic Structure of Bituminous Coal", Proceedings, Stanford

  5. INTRODUCTION Asphalt is a mixture of a wide variety of chemical compounds that include aliphatic hydrocarbons and highly fused

    E-Print Network [OSTI]

    Harms, Kyle E.

    hydrocarbons and highly fused aromatic ring systems.They are classified as asphaltenes (medium molecular weight

  6. THE CHEMISTRY OF COAL MODEL COMPOUNDS -CLEAVAGE OF ALIPHATIC BRIDGES BETWEEN AROMATIC NUCLEI CATALYSED BY LEWIS ACIDS

    E-Print Network [OSTI]

    Taylor, Newell D.

    2011-01-01T23:59:59.000Z

    and at the Nature of Asphaltenes" , Preprints L Div. of Fuelcoal that the formation of asphaltenes might be ascribed to

  7. Determination of Methyl tert-Butyl Ether and tert-Butyl Alcohol in Water by Solid-Phase Microextraction/Head Space Analysis in Comparison to EPA Method 5030/8260B

    SciTech Connect (OSTI)

    Oh, Keun-Chan; Stringfellow, William T.

    2003-10-02T23:59:59.000Z

    Methyl tert-butyl ether (MTBE) is now one of the most common groundwater contaminants in the United States. Groundwater contaminated with MTBE is also likely to be contaminated with tert-butyl alcohol (TBA), because TBA is a component of commercial grade MTBE, TBA can also be used as a fuel oxygenate, and TBA is a biodegradation product of MTBE. In California, MTBE is subject to reporting at concentrations greater than 3 {micro}g/L. TBA is classified as a ''contaminant of current interest'' and has a drinking water action level of 12 {micro}g/L. In this paper, we describe the development and optimization of a simple, automated solid phase microextraction (SPME) method for the analysis of MTBE and TBA in water and demonstrate the applicability of this method for monitoring MTBE and TBA contamination in groundwater, drinking water, and surface water. In this method, the headspace (HS) of a water sample is extracted with a carboxen/polydimethylsiloxane SPME fiber, the MTBE and TBA are desorbed into a gas chromatograph (GC), and detected using mass spectrometry (MS). The method is optimized for the routine analysis of MTBE and TBA with a level of quantitation of 0.3 {micro}g/L and 4 {micro}g/L, respectively, in water. MTBE quantitation was linear for over two orders of concentration (0.3 {micro}g/L -80 {micro}g/L). TBA was found to be linear within the range of 4 {micro}g/L-7,900 {micro}g/L. The lower level of detection for MTBE is 0.03 {micro}g/L using this method. This SPME method using headspace extraction was found to be advantageous over SPME methods requiring immersion of the fiber into the water samples, because it prolonged the life of the fiber by up to 400 sample analyses. This is the first time headspace extraction SPME has been shown to be applicable to the measurement of both MTBE and TBA at concentrations below regulatory action levels. This method was compared with the certified EPA Method 5030/8260B (purge-and-trap/GC/MS) using split samples from laboratory bioreactors treating MTBE contaminated water and applied to environmental samples collected throughout the East Bay area of California. Results from the SPME-HS/GC/MS method were directly comparable to the EPA Method 5030/8260B. This method provides an simple, inexpensive, accurate, and sensitive alternative to EPA Method 5030/8260B for the analysis of MTBE and TBA in water samples.

  8. Demonstration of alcohol as an aviation fuel

    SciTech Connect (OSTI)

    NONE

    1996-07-01T23:59:59.000Z

    A recently funded Southeastern Regional Biomass Energy Program (SERBEP) project with Baylor University will demonstrate the effectiveness of ethanols as an aviation fuel while providing several environmental and economic benefits. Part of this concern is caused by the petroleum industry. The basis for the petroleum industry to find an alternative aviation fuel will be dictated mainly by economic considerations. Three other facts compound the problem. First is the disposal of oil used in engines burning leaded fuel. This oil will contain too much lead to be burned in incinerators and will have to be treated as a toxic waste with relatively high disposal fees. Second, as a result of a greater demand for alkalites to be used in the automotive reformulated fuel, the costs of these components are likely to increase. Third, the Montreal Protocol will ban in 1998 the use of Ethyl-Di-Bromide, a lead scavenger used in leaded aviation fuel. Without a lead scavenger, leaded fuels cannot be used. The search for alternatives to leaded aviation fuels has been underway by different organizations for some time. As part of the search for alternatives, the Renewable Aviation Fuels Development Center (RAFDC) at Baylor University in Waco, Texas, has received a grant from the Federal Aviation Administration (FAA) to improve the efficiencies of ethanol powered aircraft engines and to test other non-petroleum alternatives to aviation fuel.

  9. Alcohol and Historiography in Early China

    E-Print Network [OSTI]

    Sterckx, Roel

    2015-01-01T23:59:59.000Z

    ’s visionary prediction that wine would one day lead to the inevitable demise of some states is also incorporated in the following anecdote: 14 The king of Liang ?, Wei Ying ??, was hosting his feudal lords with a toast at Fantai ??. Feeling...

  10. The social situation of alcoholism in Japan

    E-Print Network [OSTI]

    Maguire, Tara Ann

    2011-01-01T23:59:59.000Z

    in Anthropology by Tara Ann Maguire Committee in Charge:Stephen Parish Copyright Tara Ann Maguire, 2011 All RightsReserved. The Thesis of Tara Ann Maguire is approved and it

  11. Alcohol and Other Drugs Education and Prevention

    E-Print Network [OSTI]

    's constitution allows for specific legal use, possession and growing of marijuana under certain circumstances prohibited under federal law, the use, possession and growing of marijuana on campus is prohibited. Student, because of Mines' status as a federal contractor and grant recipient and because marijuana use is still

  12. Alcohol fuels bibliography, 1901-March 1980

    SciTech Connect (OSTI)

    Not Available

    1981-04-01T23:59:59.000Z

    This annotated bibliography is subdivided by subjects, as follows: general; feedstocks-general; feedstocks-sugar; feedstocks-starch; feedstocks-cellulose crops and residues; production; coproducts; economics; use as vehicle fuel; government policies; and environmental effects and safety. (MHR)

  13. Alcohol Fuels - Combustion Energy Frontier Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadapInactiveVisiting the TWP TWP RelatedCellulase C. bescii CelA, adefaultRuns for CY2.4 June

  14. Alternatives to traditional transportation fuels 1994. Volume 1

    SciTech Connect (OSTI)

    NONE

    1996-02-01T23:59:59.000Z

    In this report, alternative and replacement fuels are defined in accordance with the EPACT. Section 301 of the EPACT defines alternative fuels as: methanol, denatured ethanol, and other alcohols; mixtures containing 85% or more (or such other percentage, but not less than 70%, as determined by the Secretary of Energy, by rule, to provide for requirements relating to cold start, safety, or vehicle functions) by volume of methanol, denatured ethanol, and other alcohols with gasoline or other fuels; natural gas; liquefied petroleum gas; hydrogen; coal-derived liquid fuels; fuels (other than alcohol) derived from biological materials; electricity (including electricity from solar energy); and any other fuel the Secretary determines, by rule, is substantially not petroleum and would yield substantial energy security benefits and substantial environmental benefits. The EPACT defines replacement fuels as the portion of any motor fuel that is methanol, ethanol, or other alcohols, natural gas, liquefied petroleum gas, hydrogen, coal-derived liquid fuels, fuels (other than alcohol) derived from biological materials, electricity (including electricity from solar energy), ethers, or any other fuel the Secretary of Energy determines, by rule, is substantially not petroleum and would yield substantial energy security benefits and substantial environmental benefits. This report covers only those alternative and replacement fuels cited in the EPACT that are currently commercially available or produced in significant quantities for vehicle demonstration purposes. Information about other fuels, such as hydrogen and biodiesel, will be included in later reports as those fuels become more widely used. Annual data are presented for 1992 to 1996. Data for 1996 are based on plans or projections for 1996.

  15. NMR Characterization of the Aliphatic / Pairing for Recognition of A,T/T,A Base Pairs in the Minor Groove of DNA

    E-Print Network [OSTI]

    Mrksich, Milan

    Laboratories of Chemical Synthesis, California Institute of Technology, Pasadena, California 91125 Recei been inserted to reset the register. Complexes of three pyrrole-imidazole polyamides of sequence

  16. Substantially isotactic, linear, alternating copolymers of carbon monoxide and an olefin

    DOE Patents [OSTI]

    Sen, A.; Jiang, Z.

    1996-05-28T23:59:59.000Z

    The compound, [Pd(Me-DUPHOS)(MeCN){sub 2}](BF{sub 4}){sub 2}, [Me-DUPHOS: 1,2-bis(2,5-dimethylphospholano)benzene] is an effective catalyst for the highly enantioselective, alternating copolymerization of olefins, such as aliphatic {alpha}-olefins, with carbon monoxide to form optically active, isotactic polymers which can serve as excellent starting materials for the synthesis of other classes of chiral polymers. For example, the complete reduction of a propylene-carbon monoxide copolymer resulted in the formation of a novel, optically active poly(1,4-alcohol). Also, the previously described catalyst is a catalyst for the novel alternating isomerization cooligomerization of 2-butene with carbon monoxide to form optically active, isotactic poly(1,5-ketone).

  17. Substantially isotactic, linear, alternating copolymers of carbon monoxide and an olefin

    DOE Patents [OSTI]

    Sen, Ayusman (State College, PA); Jiang, Zhaozhong (State College, PA)

    1996-01-01T23:59:59.000Z

    The compound, [Pd(Me-DUPHOS)(MeCN).sub.2 ](BF.sub.4).sub.2, [Me-DUPHOS: 1,2-bis(2,5-dimethylphospholano)benzene] is an effective catalyst for the highly enantioselective, alternating copolymerization of olefins, such as aliphatic .alpha.-olefins, with carbon monoxide to form optically active, isotactic polymers which can serve as excellent starting materials for the synthesis of other classes of chiral polymers. For example, the complete reduction of a propylene-carbon monoxide copolymer resulted in the formation of a novel, optically active poly(1,4-alcohol). Also, the previously described catalyst is a catalyst for the novel alternating isomerization cooligomerization of 2-butene with carbon monoxide to form optically active, isotactic poly(1,5-ketone)

  18. Method and apparatus for synthesizing hydrocarbons

    DOE Patents [OSTI]

    Colmenares, C.A.; Somorjai, G.A.; Maj, J.J.

    1985-04-16T23:59:59.000Z

    A method and apparatus for synthesizing a mixture of aliphatic alcohols having five carbons or less is disclosed. An equal molar ratio of CO and H/sub 2/ gases is caused to pass through a ThO/sub 2/ catalyst having a surface area of about 80 to 125 m/sup 2//g. The catalyst further optionally includes Na ions present as substitutional cations in an amount of about 5 to 10 atom %. At a temperature of about 570 to 630/sup 0/K, and at pressures of about 20 to 50 atm, methanol and isobutanol are the predominant products and are produced in amounts of about 90 wt % of the total hydrocarbon mixture. 6 figs.

  19. N,N'-DICYCLOHEXYL-N"-ISOTRIDECYLGUANIDINE AS SUPPRESSOR FOR THE NEXT GENERATION CAUSTIC SIDE SOLVENT EXTRACTION (NG-CSSX) PROCESS

    SciTech Connect (OSTI)

    Duncan, Nathan C [ORNL; Roach, Benjamin D [ORNL; Williams, Neil J [ORNL; Bonnesen, Peter V [ORNL; Rajbanshi, Arbin [ORNL; Moyer, Bruce A [ORNL

    2012-01-01T23:59:59.000Z

    ABSTRACT The purity, concentration, and source of the N,N'-dicyclohexyl-N"-isotridecylguanidine (DCiTG) suppressor (guanidine) used in the NG-CSSX process were found to influence solvent performance. As the starting isotridecanol used in the preparation of DCiTG is comprised of a mixture of branched-chain aliphatic alcohols, varying in composition with manufacturer, the resulting DCiTG itself is a mixture. Thus, it is necessary to address how the solvent performance will be affected by the different preparations of the DCiTG solvent component. In this study, four preparations of DCiTG from three sources were analyzed and evaluated for purity and performance, both in the absence and presence of an anionic surfactant impurity.

  20. Solute retention in column liquid chromatography. X. Determination of solute infinite-dilution activity coefficients in methanol, water, and their mixtures, by combined gas-liquid and liquid-liquid chromatography

    SciTech Connect (OSTI)

    Djerki, R.A.; Laub, R.J.

    1988-01-01T23:59:59.000Z

    The Raoult's-law activity coefficients of 3- to 7-carbon aliphatic aldehyde, ketone, ester, and alcohol solutes at infinite dilution in methanol, water, and mixtures of the two and in polydimethysiloxane, all at 293-308 K, have been determined for the first time by appropriate combination of GLC and LLC retention data. The latter data are reported in terms of mole factions, while the former are given in concentration units of molality. However, interpretation of the data is difficult because of the multiplicity of the retention mechanisms. Nevertheless, the combined GLC/LLC technique, which had been applied previously only to pure solvents, is said to offer a number of advantages over static techniques for the determination of solute infinite-dilution activity coefficients with volatile solvents, especially with mixtures of solvents.