Sample records for demonstration bulk vitrification

  1. Summary - Demonstration Bulk Vitrification System (DBVS) for...

    Office of Environmental Management (EM)

    vitrification is an in-container melting process where the LAW is mixed with soil and glass formers and melted in a 50 cubic yard roll-off container. At the time of this review...

  2. A COMPREHENSIVE TECHNICAL REVIEW OF THE DEMONSTRATION BULK VITRIFICATION SYSTEM

    SciTech Connect (OSTI)

    SCHAUS, P.S.

    2006-09-29T23:59:59.000Z

    In May 2006, CH2M Hill Hanford Group, Inc. chartered an Expert Review Panel (ERP) to review the current status of the Demonstration Bulk Vitrification System (DBVS). It is the consensus of the ERP that bulk vitrification is a technology that requires further development and evaluation to determine its potential for meeting the Hanford waste stabilization mission. No fatal flaws (issues that would jeopardize the overall DBVS mission that cannot be mitigated) were found, given the current state of the project. However, a number of technical issues were found that could significantly affect the project's ability to meet its overall mission as stated in the project ''Justification of Mission Need'' document, if not satisfactorily resolved. The ERP recognizes that the project has changed from an accelerated schedule demonstration project to a formally chartered project that must be in full compliance with DOE 413.3 requirements. The perspective of the ERP presented herein, is measured against the formally chartered project as stated in the approved Justification of Mission Need document. A justification of Mission Need document was approved in July 2006 which defined the objectives for the DBVS Project. In this document, DOE concluded that bulk vitrification is a viable technology that requires additional development to determine its potential applicability to treatment of a portion of the Hanford low activity waste. The DBVS mission need statement now includes the following primary objectives: (1) process approximately 190,000 gallons of Tank S-109 waste into fifty 100 metric ton boxes of vitrified product; (2) store and dispose of these boxes at Hanford's Integrated Disposal Facility (IDF); (3) evaluate the waste form characteristics; (4) gather pilot plant operability data, and (5) develop the overall life cycle system performance of bulk vitrification and produce a comparison of the bulk vitrification process to building a second LAW Immobilization facility or other supplemental treatment alternatives as provided in M-62-08.

  3. Hanford Bulk Vitrification Technology Status

    SciTech Connect (OSTI)

    Witwer, Keith S.; Dysland, Eric J.; Bagaasen, Larry M.; Schlahta, Stephan N.; Kim, Dong-Sang; Schweiger, Michael J.; Hrma, Pavel R.

    2007-01-25T23:59:59.000Z

    Research and testing was initiated in 2003 to support the selection of a supplemental treatment technology for Hanford low-activity wastes (LAWs). AMEC’s bulk vitrification process was chosen for full-scale demonstration, and the Demonstration Bulk Vitrification System (DBVS) project was started in 2004. Also known as in-container vitrification™ (ICV™), the bulk vitrification process combines soil, liquid LAW, and additives (B2O3 and ZrO2); dries the mixture; and then vitrifies the material in a batch feed-while-melt process in a refractory lined steel container. The DBVS project was initiated with the intent to engineer, construct, and operate a full-scale bulk vitrification pilot-plant to treat LAW from Tank 241-S-109 at the U.S. Department of Energy (DOE) Hanford Site. AMEC is adapting its ICV™ technology for this application with technical and analytical support from Pacific Northwest National Laboratory (PNNL). The DBVS project is funded by the DOE Office of River Protection and administered by CH2M HILL Hanford Group, Inc. Since the beginning of the selection process in 2003, testing has utilized crucible-scale, engineering-scale, and full-scale bulk vitrification equipment. Crucible-scale testing, coupled with engineering-scale testing, helps establish process limitations of selected glass formulations. Full-scale testing provides critical design verification of the ICV™ process both before and during operation of the demonstration facility. Initial testing focused on development and validation of the baseline equipment configuration and glass formulation. Subsequent testing was focused on improvements to the baseline configuration. Many improvements have been made to the bulk vitrification system equipment configuration and operating methodology since its original inception. Challenges have been identified and met as part of the parallel testing and design process. A 100% design package for the pilot plant is complete and has been submitted to DOE for review. Additional testing will be performed to support both the DBVS project and LAW treatment for the full Hanford mission. In the near term, this includes testing some key equipment components such as the waste feed dryer and other integrated subsystems, as well as waste form process improvements. Additional testing will be conducted to verify that the system is adaptive to changing feed streams. This paper discusses the progress of the bulk vitrification system from its inception to its current state-of-the-art. Specific attention will be given to the testing and process design improvements that have been completed over the last year. These include the completion of full-scale ICV™ Test FS38C as well as process improvements to the feeding method, temperature control, and molten ionic salt separation control.

  4. Hanford bulk vitrification technology status

    SciTech Connect (OSTI)

    Witwer, K.S.; Dysland, E.J. [AMEC Nuclear Holdings Ltd., GeoMelt Division, Richland, Washington (United States); Bagaasen, L.M.; Schlahta, S.; Kim, D.S.; Schweiger, M.J.; Hrma, P. [Pacific Northwest National Laboratory, Richland, Washington (United States)

    2007-07-01T23:59:59.000Z

    Research and testing was initiated in 2003 to support the selection of a supplemental treatment technology for Hanford low-activity wastes (LAWs). AMEC's bulk vitrification process was chosen for full-scale demonstration, and the Demonstration Bulk Vitrification System (DBVS) project was started in 2004. Also known as In-Container Vitrification{sup TM} (ICV{sup TM}), the bulk vitrification process combines soil, liquid LAW, and additives (B{sub 2}O{sub 3} and ZrO{sub 2}); dries the mixture; and then vitrifies the material in a batch feed-while-melt process within a disposable, refractory-lined steel container. The DBVS project was initiated with the intent to engineer, construct, and operate a full-scale bulk vitrification pilot-plant to treat LAW from Tank 241-S-109 at the U.S. Department of Energy (DOE) Hanford Site. Since the beginning of the selection process in 2003, testing has utilized crucible-scale, engineering-scale, and full-scale bulk vitrification equipment. Crucible-scale testing, coupled with engineering-scale testing, helps establish process limitations of selected glass formulations. Full-scale testing provides critical design verification of the ICV{sup TM} process both before and during operation of the demonstration facility. Initial testing focused on development and validation of the melt container and the glass formulation. Subsequent testing was focused on improvements to the baseline configuration. Challenges have been identified and met as part of the parallel testing and design process. A 100% design package for the pilot plant is complete and has been submitted to DOE for review. Additional testing will be performed to support both the DBVS project and LAW treatment for the full Hanford mission. In the near term, this includes testing some key equipment components such as the waste feed mixer-dryer and other integrated subsystems, as well as waste form process improvements. Additional testing will be conducted to verify that the system is adaptive to changing feed streams. This paper discusses the progress of the bulk vitrification system from its inception to its current state-of- the-art. Specific attention will be given to the testing and process design improvements that have been completed over the last year. These include the completion of full-scale ICV{sup TM} Test FS38C as well as process improvements to the feeding method, temperature control, and molten ionic salt separation control. AMEC is adapting its ICV{sup TM} technology for this application with technical and analytical support from Pacific Northwest National Laboratory (PNNL) and design support from DMJN H and N. CH2M HILL Hanford Group, Inc. is the Prime Contractor for the DOE Office of River Protection for the DBVS contract. (authors)

  5. Bulk Vitrification Castable Refractory Block Protection Study

    SciTech Connect (OSTI)

    Hrma, Pavel R.; Bagaasen, Larry M.; Beck, Andrew E.; Brouns, Thomas M.; Caldwell, Dustin D.; Elliott, Michael L.; Matyas, Josef; Minister, Kevin BC; Schweiger, Michael J.; Strachan, Denis M.; Tinsley, Bronnie P.; Hollenberg, Glenn W.

    2005-05-01T23:59:59.000Z

    Bulk vitrification (BV) was selected for a pilot-scale test and demonstration facility for supplemental treatment to accelerate the cleanup of low-activity waste (LAW) at the Hanford U.S. DOE Site. During engineering-scale (ES) tests, a small fraction of radioactive Tc (and Re, its nonradioactive surrogate) were transferred out of the LAW glass feed and molten LAW glass, and deposited on the surface and within the pores of the castable refractory block (CRB). Laboratory experiments were undertaken to understand the mechanisms of the transport Tc/Re into the CRB during vitrification and to evaluate various means of CRB protection against the deposition of leachable Tc/Re. The tests used Re as a chemical surrogate for Tc. The tests with the baseline CRB showed that the molten LAW penetrates into CRB pores before it converts to glass, leaving deposits of sulfates and chlorides when the nitrate components decompose. Na2O from the LAW reacts with the CRB to create a durable glass phase that may contain Tc/Re. Limited data from a single CRB sample taken from an ES experiment indicate that, while a fraction of Tc/Re is present in the CRB in a readily leachable form, most of the Tc/Re deposited in the refractory is retained in the form of a durable glass phase. In addition, the molten salts from the LAW, mainly sulfates, chlorides, and nitrates, begin to evaporate from BV feeds at temperatures below 800 C and condense on solid surfaces at temperatures below 530 C. Three approaches aimed at reducing or preventing the deposition of soluble Tc/Re within the CRB were proposed: metal lining, sealing the CRB surface with a glaze, and lining the CRB with ceramic tiles. Metal liners were deemed unsuitable because evaluations showed that they can cause unacceptable distortions of the electric field in the BV system. Sodium silicate and a low-alkali borosilicate glaze were selected for testing. The glazes slowed down molten salt condensate penetration, but did little to reduce the penetration of molten salt. Out of several refractory tile candidates, only greystone and fused-cast alumina-zirconia-silica (AZS) refractory remained intact and well bonded to the CRB after firing to 1000 C. The deformation of the refractory-tile composite was avoided by prefiring the greystone tile to 800 C. Condensed vapors did not penetrate the tiles, but Re salts condensed on their surface. Refractory corrosion tests indicated that a 0.25-inch-thick greystone tile would not corrode during a BV melt. Tiles can reduce both vapor penetration and molten salt penetration, but vapor deposition above the melt line will occur even on tiles. The Tc/Re transport scenario was outlined as follows. At temperatures below 700 C, molten ionic salt (MIS) that includes all the Tc/Re penetrates, by capillarity, from the feed into the CRB open porosity. At approximately 750 C, the MIS decomposes through the loss of NOx, leaving mainly sulfate and chloride salts. The Na2O formed in the decomposition of the nitrates reacts with insoluble grains in the feed and with the aluminosilicates in the CRB to form more viscous liquids that reduce further liquid penetration into the CRB. At 800 to 1000 C, a continuous glass phase traps the remains of the MIS in the form of inclusions in the bulk glass melt. At 1000 to 1200 C, the salt inclusions in the glass slowly dissolve but also rise to the surface. The Tc/Re salts also evaporate from the free surface of the glass melt that is rapidly renewed by convective currents. The vapors condense on cooler surfaces in the upper portion of the CRB, the box lid, and the off-gas system.

  6. Hanford ETR Bulk Vitrification System - Demonstration Bulk Vitrification

    Broader source: Energy.gov (indexed) [DOE]

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  7. Vitrification facility at the West Valley Demonstration Project

    SciTech Connect (OSTI)

    DesCamp, V.A.; McMahon, C.L.

    1996-07-01T23:59:59.000Z

    This report is a description of the West Valley Demonstration Project`s vitrification facilities from the establishment of the West Valley, NY site as a federal and state cooperative project to the completion of all activities necessary to begin solidification of radioactive waste into glass by vitrification. Topics discussed in this report include the Project`s background, high-level radioactive waste consolidation, vitrification process and component testing, facilities design and construction, waste/glass recipe development, integrated facility testing, and readiness activities for radioactive waste processing.

  8. Feed Variability and Bulk Vitrification Glass Performance Assessment

    SciTech Connect (OSTI)

    Mahoney, Lenna A.; Vienna, John D.

    2005-01-10T23:59:59.000Z

    The supplemental treatment (ST) bulk vitrification process will obtain its feed, consisting of low-activity waste (LAW), from more than one source. One purpose of this letter report is to describe the compositional variability of the feed to ST. The other is to support the M-62-08 decision by providing a preliminary assessment of the effectiveness of bulk vitrification (BV), the process that has been selected to perform supplemental treatment, in handling the ST feed envelope. Roughly nine-tenths of the ST LAW feed will come from the Waste Treatment Plant (WTP) pretreatment. This processed waste is expected to combine (1) a portion of the same LAW feed sent to the WTP melters and (2) a dilute stream that is the product of the condensate from the submerged-bed scrubber (SBS) and the drainage from the electrostatic precipitator (WESP), both of which are part of the LAW off-gas system. The manner in which the off-gas-product stream is concentrated to reduce its volume, and the way in which the excess LAW and off-gas product streams are combined, are part of the interface between WTP and ST and have not been determined. This letter report considers only one possible arrangement, in which half of the total LAW is added to the off-gas product stream, giving an estimated ST feed stream from WTP. (Total LAW equals that portion of LAW sent to the WTP LAW vitrification plant (WTP LAW) plus the LAW not currently treatable in the LAW vitrification plant due to capacity limitations (excess)).

  9. Corrosion of Metal Inclusions In Bulk Vitrification Waste Packages

    SciTech Connect (OSTI)

    Bacon, Diana H.; Pierce, Eric M.; Wellman, Dawn M.; Strachan, Denis M.; Josephson, Gary B.

    2006-07-31T23:59:59.000Z

    The primary purpose of the work reported here is to analyze the potential effect of the release of technetium (Tc) from metal inclusions in bulk vitrification waste packages once they are placed in the Integrated Disposal Facility (IDF). As part of the strategy for immobilizing waste from the underground tanks at Hanford, selected wastes will be immobilized using bulk vitrification. During analyses of the glass produced in engineering-scale tests, metal inclusions were found in the glass product. This report contains the results from experiments designed to quantify the corrosion rates of metal inclusions found in the glass product from AMEC Test ES-32B and simulations designed to compare the rate of Tc release from the metal inclusions to the release of Tc from glass produced with the bulk vitrification process. In the simulations, the Tc in the metal inclusions was assumed to be released congruently during metal corrosion as soluble TcO4-. The experimental results and modeling calculations show that the metal corrosion rate will, under all conceivable conditions at the IDF, be dominated by the presence of the passivating layer and corrosion products on the metal particles. As a result, the release of Tc from the metal particles at the surfaces of fractures in the glass releases at a rate similar to the Tc present as a soluble salt. The release of the remaining Tc in the metal is controlled by the dissolution of the glass matrix. To summarize, the release of 99Tc from the BV glass within precipitated Fe is directly proportional to the diameter of the Fe particles and to the amount of precipitated Fe. However, the main contribution to the Tc release from the iron particles is over the same time period as the release of the soluble Tc salt. For the base case used in this study (0.48 mass% of 0.5 mm diameter metal particles homogeneously distributed in the BV glass), the release of 99Tc from the metal is approximately the same as the release from 0.3 mass% soluble Tc salt in the castable refractory block and it is released over the same time period as the salt. Therefore, to limit the impact of precipitated Fe on the release of 99Tc, both the amount of precipitated Fe in the BV glass and the diameter of these particles should be minimized.

  10. STATUS & DIRECTION OF THE BULK VITRIFICATION PROGRAM FOR THE SUPPLEMENTAL TREATMENT OF LOW ACTIVITY TANK WASTE AT HANFORD

    SciTech Connect (OSTI)

    RAYMOND, R.E.

    2005-01-12T23:59:59.000Z

    The DOE Office of River Protection (ORP) is managing a program at the Hanford site that will retrieve and treat more than 200 million liters (53 million gal.) of radioactive waste stored in underground storage tanks. The waste was generated over the past 50 years as part of the nation's defense programs. The project baseline calls for the waste to be retrieved from the tanks and partitioned to separate the highly radioactive constituents from the large volumes of chemical waste. These highly radioactive components will be vitrified into glass logs in the Waste Treatment Plant (WTP), temporarily stored on the Hanford Site, and ultimately disposed of as high-level waste in the offsite national repository. The less radioactive chemical waste, referred to as low-activity waste (LAW), is also planned to be vitrified by the WTP, and then disposed of in approved onsite trenches. However, additional treatment capacity is required in order to complete the pretreatment and immobilization of the tank waste by 2028, which represents a Tri-Party Agreement milestone. To help ensure that the treatment milestones will be met, the Supplemental Treatment Program was undertaken. The program, managed by CH2M HILL Hanford Group, Inc., involves several sub-projects each intended to supplement part of the treatment of waste being designed into the WTP. This includes the testing, evaluation, design, and deployment of supplemental LAW treatment and immobilization technologies, retrieval and treatment of mixed TRU waste stored in the Hanford Tanks, and supplemental pre-treatment. Applying one or more supplemental treatment technologies to the LAW has several advantages, including providing additional processing capacity, reducing the planned loading on the WTP, and reducing the need for double-shell tank space for interim storage of LAW. In fiscal year 2003, three potential supplemental treatment technologies were evaluated including grout, steam reforming and bulk vitrification using AMEC's In-Container Vitrification{trademark} process. As an outcome of this work, the hulk vitrification process was recommended for further evaluation. In fiscal year 2004, a follow-on bulk vitrification project was initiated to design, procure, assemble and operate a full-scale bulk vitrification pilot-plant to treat low activity tank waste from Hanford tank 241-S-109 under a Research, Development and Demonstration permit. That project is referred to as the Demonstration Bulk Vitrification System (or DBVS). The DBVS project will provide a full-scale bulk vitrification demonstration facility that can be used to assess the effectiveness of the bulk vitrification process under actual operating conditions. The pilot-plant is scheduled to commence operations in late 2005. The Supplemental Treatment Program represents a major element of the ORP's strategy to complete the pretreatment and immobilization of tank wastes by 2028. This paper will provide an overview of the bulk vitrification process and the progress in establishing the pilot-plant.

  11. BULK VITRIFICATION TECHNOLOGY FOR THE TREATMENT AND IMMOBILIZATION OF LOW-ACTIVITY WASTE

    SciTech Connect (OSTI)

    ARD KE

    2011-04-11T23:59:59.000Z

    This report is one of four reports written to provide background information regarding immobilization technologies under consideration for supplemental immobilization of Hanford's low-activity waste. This paper is intended to provide the reader with general understanding of Bulk Vitrification and how it might be applied to immobilization of Hanford's low-activity waste.

  12. DESIGN OF THE DEMOSNTRATION BULK VITRIFICATION SYSTEM FOR THE SUPPLEMENTAL TREATMENT OF LOW ACTIVITY TANK WASTE AT HANFORD

    SciTech Connect (OSTI)

    VAN BEEK JE

    2008-02-14T23:59:59.000Z

    In June 2004, the Demonstration Bulk Vitrification System (DBVS) was initiated with the intent to design, construct, and operate a full-scale bulk vitrification pilot-plant to treat low-activity tank waste from Hanford Tank 241-S-109. The DBVS facility uses In-Container Vitrification{trademark} (ICV{trademark}) at the core of the treatment process. The basic process steps combine liquid low-activity waste (LAW) and glassformers; dry the mixture; and then vitrify the mixture in a batch feed-while-melt process in a refractory lined steel container. Off-gases are processed through a state-of-the-art air pollution control system including sintered-metal filtration, thermal oxidation, acid gas scrubbing, and high-efficiency particulate air (HEPA) and high-efficiency gas adsorber (HEGA) filtration. Testing has focused on development and validation of the waste dryer, ICV, and sintered-metal filters (SMFs) equipment, operations enhancements, and glass formulation. With a parallel testing and design process, testing has allowed improvements to the DBVS equipment configuration and operating methodology, since its original inception. Design improvements include optimization of refractory panels in the ICV, simplifying glassformer addition equipment, increasing the number of waste feed chutes to the ICV, and adding capability for remote clean-out of piping, In addition, the U.S. Department of Energy (DOE) has provided an independent review of the entire DBVS process. While the review did not find any fatal flaws, some technical issues were identified that required a re-evaluation of the DBVS design and subsequent changes to the design. A 100 percent design package for the pilot plant will be completed and submitted to DOE for review in early 2008 that incorporates process improvements substantiated through testing and reviews. This paper provides a description of the bulk vitrification process and a discussion of major equipment design changes that have occurred based on full-scale testing over the past two years and DOE reviews.

  13. Nuclear Waste Glasses: Continuous Melting and Bulk Vitrification

    SciTech Connect (OSTI)

    Hrma, Pavel R.; Kruger, Albert A.

    2008-02-25T23:59:59.000Z

    This contribution addresses various aspects of nuclear waste vitrification. Nuclear wastes have a variety of components and composition ranges. For each waste composition, the glass must be formulated to possess acceptable processing and product behavior defined in terms of physical and chemical properties that guarantee that the glass can be easily made and resist environmental degradation. Glass formulation is facilitated by developing property-composition models, and the strategy of model development and application is reviewed. However, the large variability of waste compositions presents numerous additional challenges: insoluble solids and molten salts may segregate; foam may hinder heat transfer and slow down the process; molten salts may accumulate in container refractory walls; on cooling, the glass may precipitate crystalline phases. These problems need targeted exploratory research. Examples of specific problems and their possible solutions are discussed.

  14. Nuclear Waste Glasses: Continuous Melting and Bulk Vitrification

    SciTech Connect (OSTI)

    Hrma, Pavel R.; Kruger, Albert A.

    2009-01-15T23:59:59.000Z

    This contribution addresses various aspects of nuclear waste vitrification. Composition of nuclear wastes varies in the number of components and their composition ranges. For each waste composition, the glass must be formulated to possess acceptable processing and product behavior defined in terms of physical and chemical properties that guarantee that the glass is easily made and resists environmental degradation. Glass formulation is facilitated by developing property-composition models. The strategy of model development and application is reviewed. However, the large variability of waste composition presents numerous additional challenges: insoluble solids and molten salts may segregate; foam may hinder heat transfer and slows down the process; molten salts may accumulate in container refractory walls; on cooling, the glass may precipitate crystalline phases. These problems need targeted exploratory research. Examples of specific problems and their possible solutions are discussed.

  15. Hanford ETR Bulk Vitrification System - Demonstration Bulk Vitrification System (DBVS) Review Report

    Office of Environmental Management (EM)

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  16. TECHNICAL ASSESSMENT OF BULK VITRIFICATION PROCESS & PRODUCT FOR TANK WASTE TREATMENT AT THE DEPARTMENT OF ENERGY HANFORD SITE

    SciTech Connect (OSTI)

    SCHAUS, P.S.

    2006-07-21T23:59:59.000Z

    At the U.S. Department of Energy (DOE) Hanford Site, the Waste Treatment Plant (WTP) is being constructed to immobilize both high-level waste (IUW) for disposal in a national repository and low-activity waste (LAW) for onsite, near-surface disposal. The schedule-controlling step for the WTP Project is vitrification of the large volume of LAW, current capacity of the WTP (as planned) would require 50 years to treat the Hanford tank waste, if the entire LAW volume were to be processed through the WTP. To reduce the time and cost for treatment of Hanford Tank Waste, and as required by the Tank Waste Remediation System Environmental Impact Statement Record of Decision and the Hanford Federal Facility Consent Agreement (Tn-Party Agreement), DOE plans to supplement the LAW treatment capacity of the WTP. Since 2002, DOE, in cooperation with the Environmental Protection Agency and State of Washington Department of Ecology has been evaluating technologies that could provide safe and effective supplemental treatment of LAW. Current efforts at Hanford are intended to provide additional information to aid a joint agency decision on which technology will be used to supplement the WTP. A Research, Development and Demonstration permit has been issued by the State of Washington to build and (for a limited time) operate a Demonstration Bulk Vitrification System (DBVS) facility to provide information for the decision on a supplemental treatment technology for up to 50% of the LAW. In the Bulk Vitrification (BV) process, LAW, soil, and glass-forming chemicals are mixed, dried, and placed in a refractory-lined box, Electric current, supplied through two graphite electrodes in the box, melts the waste feed, producing a durable glass waste-form. Although recent modifications to the process have resulted in significant improvements, there are continuing technical concerns.

  17. Bulk Vitrification Performance Enhancement: Refractory Lining Protection Against Molten Salt Penetration

    SciTech Connect (OSTI)

    Hrma, Pavel R.; Bagaasen, Larry M.; Schweiger, Michael J.; Evans, Michael B.; Smith, Benjamin T.; Arrigoni, Benjamin M.; Kim, Dong-Sang; Rodriguez, Carmen P.; Yokuda, Satoru T.; Matyas, Josef; Buchmiller, William C.; Gallegos, Autumn B.; Fluegel, Alexander

    2007-08-06T23:59:59.000Z

    Bulk vitrification (BV) is a process that heats a feed material that consists of glass-forming solids and dried low-activity waste (LAW) in a disposable refractory-lined metal box using electrical power supplied through carbon electrodes. The feed is heated to the point that the LAW decomposes and combines with the solids to generate a vitreous waste form. This study supports the BV design and operations by exploring various methods aimed at reducing the quantities of soluble Tc in the castable refractory block portion of the refractory lining, which limits the effectiveness of the final waste form.

  18. Progress Report on the Laboratory Testing of the Bulk Vitrification Cast Refractory

    SciTech Connect (OSTI)

    Pierce, Eric M.; McGrail, B PETER.; Bagaasen, Larry M.; Wellman, Dawn M.; Crum, J V.; Geiszler, Keith N.; Baum, Steven R.

    2004-11-15T23:59:59.000Z

    The Hanford Site in southeastern Washington State has been used extensively to produce nuclear materials for the U. S. strategic defense arsenal by the U. S. Department of Energy (DOE). A large inventory of radioactive and mixed waste has accumulated in 177 single- and double-shell tanks. Liquid waste recovered from the tanks will be pre-treated to separate the low-activity fraction from the high-level and transuranic wastes. Currently, the DOE Office of River Protection (ORP) is evaluating several options for immobilization of low-activity tank wastes for eventual disposal in a shallow subsurface facility at the Hanford Site. A significant portion of the waste will be converted into immobilized low-activity waste (ILAW) glass with a conventional Joule-heated ceramic melter. In addition to ILAW glass, supplemental treatment technologies are under consideration by the DOE to treat a portion of the low activity waste. The reason for using this alternative treatment technology is to accelerate the overall cleanup mission at the Hanford site. The ORP selected Bulk Vitrification (BV) for further development and testing. Work in FY03 on engineered and large scale tests of the BV process suggested that approximately 0.3 to as much as 3 wt% of the waste stream 99Tc inventory would end up in a soluble form deposited in a vesicular layer located at the top of the BV melt and in the sand used as an insulator after vitrification. In the FY03 risk assessment (RA) (Mann et al., 2003), the soluble Tc salt in the BV waste packages creates a 99Tc concentration peak at early times in the groundwater extracted from a 100-meter down-gradient well. This peak differs from the presently predicted baseline WTP glass performance, which shows an asymptotic rise to a constant release rate. Because of the desire by regulatory agencies to achieve essentially equivalent performance to WTP glass with supplemental treatment technologies, the BV process was modified in FY04 in an attempt to minimize deposition of soluble 99Tc salts by including a castable refractory block (CRB) in place of a portion of the refractory sand layer and using a bottom-up melting technique to eliminate the vesicular glass layer at the top. However, the refractory block is still porous and there is the potential for leachable 99Tc to deposit in the pores of the CRB. The purpose of this progress report is to document the status of a laboratory testing program being conducted at Pacific Northwest National Laboratory (PNNL) for CH2M Hill Hanford Group in support of the LAW Supplemental Treatment Technologies Demonstration project. The objective of these tests was to provide an initial estimate of the leachable fraction of key contaminants of concern (Cs, Re [chemical analogue for 99Tc], and 99Tc) that could condense within the BV CRB. This information will be used to guide development of additional modifications to the BV process to further reduce the soluble 99Tc levels in the BV waste package.

  19. Integrated DWPF Melter System (IDMS) campaign report: Hanford Waste Vitrification Plan (HWVP) process demonstration

    SciTech Connect (OSTI)

    Hutson, N.D.

    1992-08-10T23:59:59.000Z

    Vitrification facilities are being developed worldwide to convert high-level nuclear waste to a durable glass form for permanent disposal. Facilities in the United States include the Department of Energy`s Defense Waste Processing Facility (DWPF) at the Savannah River Site, the Hanford Waste Vitrification Plant (HWVP) at the Hanford Site and the West Valley Demonstration Project (WVDP) at West Valley, NY. At each of these sites, highly radioactive defense waste will be vitrified to a stable borosilicate glass. The DWPF and WVDP are near physical completion while the HWVP is in the design phase. The Integrated DWPF Melter System (IDMS) is a vitrification test facility at the Savannah River Technology Center (SRTC). It was designed and constructed to provide an engineering-scale representation of the DWPF melter and its associated feed preparation and off-gas treatment systems. Because of the similarities of the DWPF and HWVP processes, the IDMS facility has also been used to characterize the processing behavior of a reference NCAW simulant. The demonstration was undertaken specifically to determine material balances, to characterize the evolution of offgas products (especially hydrogen), to determine the effects of noble metals, and to obtain general HWVP design data. The campaign was conducted from November, 1991 to February, 1992.

  20. Hanford Waste Vitrification Plant technical background document for best available radionuclide control technology demonstration

    SciTech Connect (OSTI)

    Carpenter, A.B.; Skone, S.S.; Rodenhizer, D.G.; Marusich, M.V. (Ebasco Services, Inc., Bellevue, WA (USA))

    1990-10-01T23:59:59.000Z

    This report provides the background documentation to support applications for approval to construct and operate new radionuclide emission sources at the Hanford Waste Vitrification Plant (HWVP) near Richland, Washington. The HWVP is required to obtain permits under federal and state statutes for atmospheric discharges of radionuclides. Since these permits must be issued prior to construction of the facility, draft permit applications are being prepared, as well as documentation to support these permits. This report addresses the applicable requirements and demonstrates that the preferred design meets energy, environmental, and economic criteria for Best Available Radionuclide Control Technology (BARCT) at HWVP. 22 refs., 11 figs., 25 tabs.

  1. Investigation of Tc Migration Mechanism During Bulk Vitrification Process Using Re Surrogate

    SciTech Connect (OSTI)

    Kim, Dong-Sang; Bagaasen, Larry M.; Crum, Jarrod V.; Fluegel, Alex; Gallegos, Autumn B.; Martinez, Baudelio; Matyas, Josef; Meyer, Perry A.; Paulsen, Dan; Riley, Brian J.; Schweiger, Michael J.; Stewart, Charles W.; Swoboda, Robert G.; Yeager, John D.

    2006-12-04T23:59:59.000Z

    As a part of Bulk vitrification (BV) performance enhancement tasks, Laboratory scoping tests were performed in FY 2004-2005 to explore possible ways to reduce the amount of soluble Tc in the BV waste package. Theses scoping tests helped identify which mechanisms play an important role in the migration of Tc in the BV process (Hrma et al. 2005 and Kim et al. 2005). Based on the results from these scoping tests, additional tests were identified that will improve the understanding of Tc migration and to clearly identify the dominant mechanisms. The additional activities identified from previous studies were evaluated and prioritized for planning for Tasks 29 and 30 conducted in FY2006. Task 29 focused on the improved understanding of Tc migration mechanisms, and Task 30 focused on identifying the potential process changes that might reduce Tc/Re migration into the castable refractory block (CRB). This report summarizes the results from the laboratory- and crucible-scale tests in the lab for improved Tc migration mechanism understanding utilizing Re as a surrogate performed in Task 29.

  2. Transport of Technetium and Rhenium into Refractory Materials during Bulk Vitrification

    SciTech Connect (OSTI)

    Bagaasen, Larry M.; Brouns, Thomas M.; Elliott, Michael L.; Hrma, Pavel R.; Kim, Dong-Sang; Matyas, Josef; Pierce, Eric M.; McGrail, B. Peter; Schweiger, Michael J.; Campbell, Brett E.; Beck, Andrew E.

    2006-02-21T23:59:59.000Z

    Bulk vitrification (BV) was selected as a potential supplemental treatment to accelerate the cleanup of low-activity waste (LAW) at the U.S. Department of Energy Hanford Site. In the BV process, low-activity waste, soil, and glass forming chemicals are mixed, dried and placed in a metal box lined with a castable refractory block (CRB). Electric current, supplied by two graphite electrodes in the box, melts the waste feed and produces a durable glass waste form. During engineering-scale (ES) tests of BV, a small fraction of radioactive technetium-99 (Tc) (and rhenium [Re], a nonradioactive surrogate) were transferred out of the LAW glass feed and molten LAW glass, and deposited on the surface and within the pores of the CRB. Tc is a primary risk driver for long-term performance of immobilized LAW; therefore, even small fractions of Tc present in a readily leachable form rather than immobilized in a glass matrix can impact long-term performance.

  3. Development of analytical cell support for vitrification at the West Valley Demonstration Project. Topical report

    SciTech Connect (OSTI)

    Barber, F.H.; Borek, T.T.; Christopher, J.Z. [and others

    1997-12-01T23:59:59.000Z

    Analytical and Process Chemistry (A&PC) support is essential to the high-level waste vitrification campaign at the West Valley Demonstration Project (WVDP). A&PC characterizes the waste, providing information necessary to formulate the recipe for the target radioactive glass product. High-level waste (HLW) samples are prepared and analyzed in the analytical cells (ACs) and Sample Storage Cell (SSC) on the third floor of the main plant. The high levels of radioactivity in the samples require handling them in the shielded cells with remote manipulators. The analytical hot cells and third floor laboratories were refurbished to ensure optimal uninterrupted operation during the vitrification campaign. New and modified instrumentation, tools, sample preparation and analysis techniques, and equipment and training were required for A&PC to support vitrification. Analytical Cell Mockup Units (ACMUs) were designed to facilitate method development, scientist and technician training, and planning for analytical process flow. The ACMUs were fabricated and installed to simulate the analytical cell environment and dimensions. New techniques, equipment, and tools could be evaluated m in the ACMUs without the consequences of generating or handling radioactive waste. Tools were fabricated, handling and disposal of wastes was addressed, and spatial arrangements for equipment were refined. As a result of the work at the ACMUs the remote preparation and analysis methods and the equipment and tools were ready for installation into the ACs and SSC m in July 1995. Before use m in the hot cells, all remote methods had been validated and four to eight technicians were trained on each. Fine tuning of the procedures has been ongoing at the ACs based on input from A&PC technicians. Working at the ACs presents greater challenges than had development at the ACMUs. The ACMU work and further refinements m in the ACs have resulted m in a reduction m in analysis turnaround time (TAT).

  4. Transport of Technetium and Rhenium into Refractory Materials during Bulk Vitrification

    SciTech Connect (OSTI)

    Bagaasen, L.M.; Brouns, T.M.; Elliott, M.L.; Hrma, P.R.; Kim, D.S.; Matyas, J.; Pierce, E.M.; McGrail, B.P.; Schweiger, M.J.; Beck, A.E. [Pacific Northwest National Laboratory, P.O. Box 999, Richland, WA 99352 (United States); Campbell, B.E. [AMEC Earth and Environmental, Inc., GeoMelt Division, 1135 Jadwin Ave., Richland, WA 99352 (United States)

    2006-07-01T23:59:59.000Z

    Bulk vitrification (BV) was selected as a potential supplemental waste treatment process to support the commitment for cleanup of low-activity waste (LAW) stored in large waste storage tanks at the U.S. Department of Energy's Hanford Site. In the BV process, LAW, soil, and glass-forming chemicals are mixed, dried, and placed within a castable refractory block (CRB) and sand, all within a metal box. Electric current, supplied through two graphite electrodes in the box, melts the waste feed and produces a durable glass waste form. During engineering-scale tests of By, a small fraction of radioactive technetium-99 (Tc) and rhenium (Re) (a nonradioactive surrogate) were transferred out of the LAW glass feed and molten LAW glass and deposited on the surface and within the pores of the CRB. Tc is a primary risk driver for long-term performance of immobilized LAW; therefore, even small fractions of Tc present in a readily leachable form rather than immobilized in a glass matrix can impact long-term performance of the immobilized waste. Laboratory and engineering-scale studies were undertaken to reduce or eliminate the readily leachable Tc in the CRB. These studies focused on 1) understanding the mechanisms of the transport of Tc/Re into the CRB during vitrification, and 2) evaluating various means of protecting the CRB against the deposition of leachable Tc/Re. The tests used either Re as a chemical surrogate for Tc, or Re and Tc together. A conceptual Tc/Re transport model was developed based on observed laboratory experiments to attempt to explain the transport behavior seen in engineering-scale tests. At temperatures below 650 deg. C, molten ionic salt (MIS) containing Tc and Re penetrates by capillarity from the feed into the CRB open porosity. At approximately 650 to 750 deg. C, the MIS decomposes through the loss of NO{sub x}, leaving mainly sulfate and chloride salts. The Na{sub 2}O formed during decomposition of the nitrates reacts with insoluble grains in the feed and the aluminosilicates in the CRB to form more viscous liquids that reduce further liquid penetration into the CRB. At 750 to 950 deg. C, a continuous glass phase traps the remains of the MIS in the form of inclusions in the bulk glass melt. At 950 to 1200 deg. C, the salt inclusions in the glass slowly dissolve but also rise to the surface. The Tc/Re salts also evaporate from the free surface of the glass melt that is rapidly renewed by convective currents. The vapors condense on cooler surfaces in the upper portion of the CRB, the box lid, and the off gas system. Results of the engineering-scale tests helped to validate the conceptual transport model of Tc/Re deposition and improved the understanding of likely mechanisms of deposition in the CRB. As a result, there is increased potential that Tc deposition can be controlled and reduced to ensure that the BV waste form will provide acceptable performance. (authors)

  5. Operating experience during high-level waste vitrification at the West Valley Demonstration Project

    SciTech Connect (OSTI)

    Valenti, P.J.; Elliott, D.I.

    1999-01-01T23:59:59.000Z

    This report provides a summary of operational experiences, component and system performance, and lessons learned associated with the operation of the Vitrification Facility (VF) at the West Valley Demonstration Project (WVDP). The VF was designed to convert stored high-level radioactive waste (HLW) into a stable waste form (borosilicate glass) suitable for disposal in a federal repository. Following successful completion on nonradioactive test, HLW processing began in July 1995. Completion of Phase 1 of HLW processing was reached on 10 June 1998 and represented the processing of 9.32 million curies of cesium-137 (Cs-137) and strontium-90 (Sr-90) to fill 211 canisters with over 436,000 kilograms of glass. With approximately 85% of the total estimated curie content removed from underground waste storage tanks during Phase 1, subsequent operations will focus on removal of tank heel wastes.

  6. Environmental Compliance at the West Valley Demonstration Project: The Vitrification Permitting Program

    SciTech Connect (OSTI)

    L. C. Salvatori; C. B. Banzer; W. T. Watters

    1996-05-28T23:59:59.000Z

    The major environmental laws that apply to the West Valley Demonstration Project (WVDP) are the: Resource Conservation and Recovery Act (RCRA), Clean Air Act (CAA), Clean Water Act (CWA), Safe Drinking Water Act (SDWA), Toxic Substances Control Act (TSCA), National Environmental Policy Act (NEPA), and Emergency Planning and Community Right-To-Know Act (EPCRA). Regulations developed in accordance with these laws are administered by the New York State Department of Environmental Conservation (NYSDEC) and the U.S. Environmental Protection Agency (EPA) through state and federal programs, and regulatory requirements such as permitting. The Environmental Permits & Reports (EP&R) Group of the Environmental Affairs (EA) Department has the primary responsibility for developing a site-wide permitting program for the WVDP and obtaining the necessary permits. This report discusses the permits and the permitting process associated with the Vitrification Facility (VF).

  7. West Valley Demonstration Project vitrification process equipment Functional and Checkout Testing of Systems (FACTS)

    SciTech Connect (OSTI)

    Carl, D.E.; Paul, J.; Foran, J.M.; Brooks, R.

    1990-09-30T23:59:59.000Z

    The Vitrification Facility (VF) at the West Valley Demonstration Project was designed to convert stored radioactive waste into a stable glass for disposal in a federal repository. The Functional and Checkout Testing of Systems (FACTS) program was conducted from 1984 to 1989. During this time new equipment and processes were developed, installed, and implemented. Thirty-seven FACTS tests were conducted, and approximately 150,000 kg of glass were made by using nonradioactive materials to simulate the radioactive waste. By contrast, the planned radioactive operation is expected to produce approximately 500,000 kg of glass. The FACTS program demonstrated the effectiveness of equipment and procedures in the vitrification system, and the ability of the VF to produce quality glass on schedule. FACTS testing also provided data to validate the WVNS waste glass qualification method and verify that the product glass would meet federal repository acceptance requirements. The system was built and performed to standards which would have enabled it to be used in radioactive service. As a result, much of the VF tested, such as the civil construction, feed mixing and holding vessels, and the off-gas scrubber, will be converted for radioactive operation. The melter was still in good condition after being at temperature for fifty-eight of the sixty months of FACTS. However, the melter exceeded its recommended design life and will be replaced with a similar melter. Components that were not designed for remote operation and maintenance will be replaced with remote-use items. The FACTS testing was accomplished with no significant worker injury or environmental releases. During the last FACTS run, the VF processes approximated the remote-handling system that will be used in radioactive operations. Following this run the VF was disassembled for conversion to a radioactive process. Functional and checkout testing of new components will be performed prior to radioactive operation.

  8. Method to Reduce Molten Salt Penetration into Bulk Vitrification Refractory Materials

    SciTech Connect (OSTI)

    Bagaasen, L.M.; Hrma, P.R.; Kim, D.S.; Schweiger, M.J.; Matyas, J.; Rodriguez, C.P. [Pacific Northwest National Laboratory, Richland WA (United States); Witwer, K.S. [AMEC Nuclear Holdings Ltd., GeoMelt Division, Richland, WA (United States)

    2008-07-01T23:59:59.000Z

    Bulk vitrification (BV) is a process that heats a feed material consisting of glass-forming solids and dried low-activity waste (LAW) in a disposable refractory-lined metal box using electrical power supplied through carbon electrodes. The feed is heated to the point that the LAW decomposes and combines with the solids to generate a vitreous waste form. However, the castable refractory block (CRB) portion of the refractory lining has sufficient porosity to allow the low-viscosity molten ionic salt (MIS), which contains technetium (Tc) in a soluble form, to penetrate the CRB. This limits the effectiveness of the final waste form. This paper describes tests conducted to develop a method aimed at reducing the quantities of soluble Tc in the CRB. Tests showed that MIS formed in significant quantities at temperatures above 300 deg. C, remained stable until roughly 550 deg. C where it began to thermally decompose, and was completely decomposed by 800 deg. C. The estimated volume fraction of MIS in the feed was greater than 40%, and the CRB material contained 11 to 15% open porosity, a combination allowing a large quantity of MIS to migrate through the feed and penetrate the open porosity of the CRB. If the MIS is decomposed at temperatures below 300 deg. C or can be contained in the feed until it fully decomposes by 800 deg. C, MIS migration into the CRB can be avoided. Laboratory and crucible-scale experiments showed that a variety of methods, individually or in combination, can decrease MIS penetration into the CRB. Modifying the CRB to block MIS penetration was not deemed practical as a method to prevent the large quantities of MIS penetration seen in the full-scale tests, but it may be useful to reduce the impacts of lower levels of MIS penetration. Modifying the BV feed materials to better contain the MIS proved to be more successful. A series of qualitative and quantitative crucible tests were developed that allowed screening of feed modifications that might be used to reduce MIS penetration. These tests showed that increasing the specific surface area of the soil (used as the primary glass-forming solid in the baseline process) by grinding stopped MIS penetration nearly entirely for feeds that contained waste simulants with lower quantities of nitrate salts. Grinding soil significantly reduced MIS penetration in feeds with higher nitrate quantities, but it was necessary to add carbohydrates (sucrose or cellulose) to destroy a portion of the nitrate at low temperatures to reach the same low levels of MIS penetration seen for the lower nitrate feeds. Developing feeds to reduce MIS penetration in full-scale BV applications resulted in two additional refinements. Soil-grinding to the necessary levels proved to be difficult and expensive, so the fine soil was replaced with readily available fine-grained glass-forming minerals. Cellulose was shown to have less impact on dryer operation than sucrose and was chosen as the carbohydrate source to use in subsequent engineering- and full-scale tests. (authors)

  9. Method to Reduce Molten Salt Penetration into Bulk Vitrification Refractory Materials

    SciTech Connect (OSTI)

    Bagaasen, Larry M.; Hrma, Pavel R.; Kim, Dong-Sang; Schweiger, Michael J.; Matyas, Josef; Rodriguez, Carmen P.; Witwer, Keith S.

    2008-01-18T23:59:59.000Z

    Bulk vitrification (BV) is a process that heats a feed material that consists of glass-forming solids and dried low-activity waste (LAW) in a disposable refractory-lined metal box using electrical power supplied through carbon electrodes. The feed is heated to the point that the LAW decomposes and combines with the solids to generate a vitreous waste form. However, the castable refractory block (CRB) portion of the refractory lining has sufficient porosity to allow the low-viscosity molten ionic salt (MIS), which contains technetium (Tc) in a soluble form, to penetrate the CRB. This limits the effectiveness of the final waste form. This paper describes tests conducted to develop a method aimed at reducing the quantities of soluble Tc in the CRB. Tests showed that MIS formed in significant quantities at temperatures above 300°C, remained stable until roughly 550°C where it began to thermally decompose, and was completely decomposed by 800°C. The estimated volume fraction of MIS in the feed was greater than 40%, and the CRB material contained 11 to 15% open porosity, a combination allowing a large quantity of MIS to migrate through the feed and penetrate the open porosity of the CRB. If the MIS is decomposed at temperatures below 300°C or can be contained in the feed until it fully decomposes by 800°C, MIS migration into the CRB can be avoided. Laboratory and crucible-scale experiments showed that a variety of methods, individually or in combination, can decrease MIS penetration into the CRB. Modifying the CRB to block MIS penetration was not deemed practical as a method to prevent the large quantities of MIS penetration seen in the full-scale tests, but it may be useful to reduce the impacts of lower levels of MIS penetration. Modifying the BV feed materials to better contain the MIS proved to be more successful. A series of qualitative and quantitative crucible tests were developed that allowed screening of feed modifications that might be used to reduce MIS penetration. These tests showed that increasing the specific surface area of the soil (used as the primary glass-forming solid in the baseline process) by grinding stopped MIS penetration nearly entirely for feeds that contained waste simulants with lower quantities of nitrate salts. Grinding soil significantly reduced MIS penetration in feeds with higher nitrate quantities, but it was necessary to add carbohydrates (sucrose or cellulose) to destroy a portion of the nitrate at low temperatures to reach the same low levels of MIS penetration seen for the lower nitrate feeds. Developing feeds to reduce MIS penetration in full-scale BV applications resulted in two additional refinements. Soil-grinding to the necessary levels proved to be difficult and expensive, so the fine soil was replaced with readily available fine-grained glass-forming minerals. Cellulose was shown to have less impact on dryer operation than sucrose and was chosen as the carbohydrate source to use in subsequent engineering- and full-scale tests.

  10. Subsurface Planar Vitrification Treatment of Problematic TRU Wastes: Status of a Technology Demonstration Program

    SciTech Connect (OSTI)

    Morse, M.K.; Nowack, B.R.; Thompson, L.E. [AMEC, 1135 Jadwin Avenue, Richland, WA 99352 (United States)

    2006-07-01T23:59:59.000Z

    This paper provides a status of the In Situ Transuranic Waste Delineation and Removal Project in which the GeoMelt{sup R} Subsurface Planar Vitrification{sup TM} (SPV{sup TM}) process is being evaluated for the in situ treatment of burial sites containing remote handled mixed transuranic (TRU) waste. The GeoMelt{sup R} SPV{sup TM} process was invented and patented by Geosafe Corporation. AMEC holds the exclusive worldwide license to use this technology. The current project is part of a three-phase demonstration program to evaluate the effectiveness of the GeoMelt{sup R} SPV{sup TM} process to treat waste contained in vertical pipe units (VPUs) and caissons that were used for the disposal of remote handled transuranic wastes located at Hanford's 618-10 and 618-11 burial grounds. This project is being performed for the US Department of Energy (DOE) for use at the Hanford site and other DOE installations. The Phase I evaluation determined that removal and treatment of the 618-10/11 VPUs are beyond what can be safely accomplished using conventional excavation methods. Accordingly, a careful stepwise non-intrusive delineation approach and treatment using the GeoMelt{sup R} SPV{sup TM} technology, followed by removal, characterization, and disposal of the resulting inert vitrified mass was identified as the preferred alternative. Phase II of the project, which started in July 2004, included a full-scale non-radioactive demonstration of AMEC's GeoMelt{sup R} SPV{sup TM} process on a mock VPU configured to match the actual VPUs. The non-radioactive demonstration (completed in May 2005) was performed to confirm the approach and design before proceeding to a radioactive ('hot') demonstration on an actual VPU. This demonstration took approximately 130 hours, processed the entire mock VPU, and resulted in a vitrified monolith weighing an estimated 90 tonnes. [1] Plans for a radioactive demonstration on an actual VPU are being developed for CY 2006. In addition to demonstrating GeoMelt{sup R} SPV{sup TM}, delineation techniques are being evaluated as part of the project to confirm the locations of the actual VPUs and to progressively determine their physical and chemical contents. The initial calibration and testing activities were completed in December 2005. The techniques included non-intrusive geophysical measurements from adjacent boreholes (ground penetrating radar, neutron-gamma radiography, etc.). Other methods available for use, on an as needed basis, include gas headspace sampling and boro-scope examinations inside the VPUs/caissons. (authors)

  11. Hanford Waste Vitrification Plant technical background document for toxics best available control technology demonstration

    SciTech Connect (OSTI)

    none,

    1992-10-01T23:59:59.000Z

    This document provides information on toxic air pollutant emissions to support the Notice of Construction for the proposed Hanford Waste Vitrification Plant (HWVP) to be built at the the Department of Energy Hanford Site near Richland, Washington. Because approval must be received prior to initiating construction of the facility, state and federal Clean Air Act Notices of construction are being prepared along with necessary support documentation.

  12. In situ vitrification demonstration at Pit 1, Oak Ridge National Laboratory. Volume 1: Results of treatability study

    SciTech Connect (OSTI)

    Spalding, B.P.; Naney, M.T.; Cline, S.R.; Bogle, M.A. [Oak Ridge National Lab., TN (United States). Environmental Sciences Div.; Tixier, J.S. [Pacific Northwest National Lab., Richland, WA (United States)

    1997-12-01T23:59:59.000Z

    A treatability study was initiated in October 1993 to apply in situ vitrification (ISV) to at least two segments of Oak Ridge National Laboratory (ORNL) seepage Pit 1 by the end of fiscal year (FY) 1995. This treatability study was later extended to include all of Pit 1 and was performed to support a possible Interim Record of Decision or removal action for closure of one or more of the seepage pits and trenches beginning as early as FY 1997. This treatability study was carried out to establish the field-scale technical performance of ISV for (1) attaining the required depth, nominally 15 ft, to incorporate source contamination within and beneath the pits; (2) demonstrating field capability for the overlap of melt settings which will be necessary to achieve fused, melted segments of the source contamination; (3) demonstrating off-gas handling technology for accommodating and minimizing the volatilization of {sup 137}Cs; (4) demonstrating adequate site characterization techniques to predict ISV melting kinetics, processing temperatures, and product durability; and (5) promoting public acceptance of ISV technology by demonstrating its safety, implementability, site impacts, and air emissions and by coordinating the treatability study within the regulatory closure process. In April 1996 an expulsion of an estimated 10% of the 196 Mg (216 tons) melt body occurred resulting in significant damage to ISV equipment and, ultimately, led to an indefinite suspension of further ISV operations at Pit 1. This report summarizes the technical accomplishments and status of the project in fulfilling these objectives through September 1997.

  13. Summary - Demonstration Bulk Vitrification System (DBVS) for Low-Actvity Waste at Hanford

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 1112011 Strategic2Uranium Transferon the Passing of AdmiraltheOil and Less CO2Caustic

  14. Design and operating features of the high-level waste vitrification system for the West Valley demonstration project

    SciTech Connect (OSTI)

    Siemens, D.H.; Beary, M.M.; Barnes, S.M.; Berger, D.N.; Brouns, R.A.; Chapman, C.C.; Jones, R.M.; Peters, R.D.; Peterson, M.E.

    1986-03-01T23:59:59.000Z

    A liquid-fed joule-heated ceramic melter system is the reference process for immobilization of the high-level liquid waste in the US and several foreign countries. This system has been under development for over ten years at Pacific Northwest Laboratory and other national laboratories operated for the US Department of Energy. Pacific Northwest Laboratory contributed to this research through its Nuclear Waste Treatment Program and used applicable data to design and test melters and related systems using remote handling of simulated radioactive wastes. This report describes the equipment designed in support of the high-level waste vitrification program at West Valley, New York. Pacific Northwest Laboratory worked closely with West Valley Nuclear Services Company to design a liquid-fed ceramic melter, a liquid waste preparation and feed tank and pump, an off-gas treatment scrubber, and an enclosed turntable for positioning the waste canisters. Details of these designs are presented including the rationale for the design features and the alternatives considered.

  15. Innovative vitrification for soil remediation

    SciTech Connect (OSTI)

    Jetta, N.W.; Patten, J.S.; Hart, J.G.

    1995-12-01T23:59:59.000Z

    The objective of this DOE demonstration program is to validate the performance and operation of the Vortec Cyclone Melting System (CMS{trademark}) for the processing of LLW contaminated soils found at DOE sites. This DOE vitrification demonstration project has successfully progressed through the first two phases. Phase 1 consisted of pilot scale testing with surrogate wastes and the conceptual design of a process plant operating at a generic DOE site. The objective of Phase 2, which is scheduled to be completed the end of FY 95, is to develop a definitive process plant design for the treatment of wastes at a specific DOE facility. During Phase 2, a site specific design was developed for the processing of LLW soils and muds containing TSCA organics and RCRA metal contaminants. Phase 3 will consist of a full scale demonstration at the DOE gaseous diffusion plant located in Paducah, KY. Several DOE sites were evaluated for potential application of the technology. Paducah was selected for the demonstration program because of their urgent waste remediation needs as well as their strong management and cost sharing financial support for the project. During Phase 2, the basic nitrification process design was modified to meet the specific needs of the new waste streams available at Paducah. The system design developed for Paducah has significantly enhanced the processing capabilities of the Vortec vitrification process. The overall system design now includes the capability to shred entire drums and drum packs containing mud, concrete, plastics and PCB`s as well as bulk waste materials. This enhanced processing capability will substantially expand the total DOE waste remediation applications of the technology.

  16. Vitrification testing of soil fines from contaminated Hanford 100 Area and 300 Area soils

    SciTech Connect (OSTI)

    Ludowise, J.D.

    1994-05-01T23:59:59.000Z

    The suitability of Hanford soil for vitrification is well known and has been demonstrated extensively in other work. The tests reported here were carried out to confirm the applicability of vitrification to the soil fines (a subset of the Hanford soil potentially different in composition from the bulk soil) and to provide data on the performance of actual, vitrified soil fines. It was determined that the soil fines were generally similar in composition to the bulk Hanford soil, although the fraction <0.25 mm in the 100 Area soil sample appears to differ somewhat from the bulk soil composition. The soil fines are readily melted into a homogeneous glass with the simple additions of CaO and/or Na{sub 2}O. The vitrified waste (plus additives) occupies only 60% of the volume of the initial untreated waste. Leach testing has shown the glasses made from the soil fines to be very durable relative to natural and man-made glasses and has demonstrated the ability of the vitrified waste to greatly reduce the release of radionuclides to the environment. Viscosity and electrical conductivity measurements indicate that the soil fines will be readily processable, although with levels of additives slightly greater than used in the radioactive melts. These tests demonstrate the applicability of vitrification to the contaminated soil fines and the exceptional performance of the waste form resulting from the vitrification of contaminated Hanford soils.

  17. Vitrification Facility integrated system performance testing report

    SciTech Connect (OSTI)

    Elliott, D.

    1997-05-01T23:59:59.000Z

    This report provides a summary of component and system performance testing associated with the Vitrification Facility (VF) following construction turnover. The VF at the West Valley Demonstration Project (WVDP) was designed to convert stored radioactive waste into a stable glass form for eventual disposal in a federal repository. Following an initial Functional and Checkout Testing of Systems (FACTS) Program and subsequent conversion of test stand equipment into the final VF, a testing program was executed to demonstrate successful performance of the components, subsystems, and systems that make up the vitrification process. Systems were started up and brought on line as construction was completed, until integrated system operation could be demonstrated to produce borosilicate glass using nonradioactive waste simulant. Integrated system testing and operation culminated with a successful Operational Readiness Review (ORR) and Department of Energy (DOE) approval to initiate vitrification of high-level waste (HLW) on June 19, 1996. Performance and integrated operational test runs conducted during the test program provided a means for critical examination, observation, and evaluation of the vitrification system. Test data taken for each Test Instruction Procedure (TIP) was used to evaluate component performance against system design and acceptance criteria, while test observations were used to correct, modify, or improve system operation. This process was critical in establishing operating conditions for the entire vitrification process.

  18. Vitrification of high sulfate wastes

    SciTech Connect (OSTI)

    Merrill, R.A.; Whittington, K.F.; Peters, R.D.

    1994-09-01T23:59:59.000Z

    The US Department of Energy (DOE) through the Mixed Waste Integrated Program (MWIP) is investigating the application of vitrification technology to mixed wastes within the DOE system This work involves identifying waste streams, laboratory testing to identify glass formulations and characterize the vitrified product, and demonstration testing with the actual waste in a pilot-scale system. Part of this program is investigating process limits for various waste components, specifically those components that typically create problems for the application of vitrification, such as sulfate, chloride, and phosphate. This work describes results from vitrification testing for a high-sulfate waste, the 183-H Solar Evaporation Basin waste at Hanford. A low melting phosphate glass formulation has been developed for a waste stream high in sodium and sulfate. At melt temperatures in the range of 1,000 C to 1,200 C, sulfate in the waste is decomposed to gaseous oxides and driven off during melting, while the remainder of the oxides stay in the melt. Decomposition of the sulfates eliminates the processing problems typically encountered in vitrification of sulfate-containing wastes, resulting in separation of the sulfate from the remainder of the waste and allowing the sulfate to be collected in the off-gas system and treated as a secondary waste stream. Both the vitreous product and intentionally devitrified samples are durable when compared to reference glasses by TCLP and DI water leach tests. Simple, short tests to evaluate the compatibility of the glasses with potential melter materials found minimal corrosion with most materials.

  19. EV-16 Vitrification Trials with MnO{sub 2} and Surrogate B{ampersand}C Pond Sludge

    SciTech Connect (OSTI)

    Cicero-Herman, C.A. [Westinghouse Savannah River Company, AIKEN, SC (United States); Erich, D.L.; Overcamp, T.J.; Harden, J.M.

    1998-02-17T23:59:59.000Z

    The Savannah River Technology Center has demonstrated the feasibility of using the Transportable Vitrification System for the treatment of Low-Level Mixed Wastes.

  20. Innovative vitrification for soil remediation

    SciTech Connect (OSTI)

    Jetta, N.W.; Patten, J.S.; Hnat, J.G. [Vortec Corp., Collegeville, PA (United States)

    1995-10-01T23:59:59.000Z

    The objective of this DOE demonstration program is to validate the performance and operation of the Vortec Cyclone Melting System (CMS{trademark}) for the processing of LLW contaminated soils found at DOE sites. This DOE vitrification demonstration project has successfully progressed through the first two phases. Phase I consisted of pilot scale testing with surrogate wastes and the conceptual design of a process plant operating at a generic DOE site. The objective of Phase 2, which is scheduled to be completed the end of FY 95, is to develop a definitive process plant design for the treatment of wastes at a specific DOE facility. During Phase 2, a site specific design was developed for the processing of LLW soils and muds containing TSCA organics and RCRA metal contaminants. Phase 3 will consist of a full scale demonstration at the DOE gaseous diffusion plant located in Paducah, KY. Several DOE sites were evaluated for potential application of the technology. Paducah was selected for the demonstration program because of their urgent waste remediation needs as well as their strong management and cost sharing financial support for the project.

  1. Vitrification publication bibliography

    SciTech Connect (OSTI)

    Schmieman, E.; Johns, W.E.

    1996-02-01T23:59:59.000Z

    This document was compiled by a group of about 12 graduate students in the Department of Mechanical Engineering and Material Science at Washington State University and was funded by the U.S. Department of Energy. The literature search resulting in the compilation of this bibliography was designed to be an exhaustive search for research and development work involving the vitrification of mixed wastes, published by domestic and foreign researchers, primarily during 1989-1994. The search techniques were dominated by electronic methods and this bibliography is also available in electronic format, Windows Reference Manager.

  2. Vitrification of waste

    DOE Patents [OSTI]

    Wicks, George G. (Aiken, SC)

    1999-01-01T23:59:59.000Z

    A method for encapsulating and immobilizing waste for disposal. Waste, preferably, biologically, chemically and radioactively hazardous, and especially electronic wastes, such as circuit boards, are placed in a crucible and heated by microwaves to a temperature in the range of approximately 300.degree. C. to 800.degree. C. to incinerate organic materials, then heated further to a temperature in the range of approximately 1100.degree. C. to 1400.degree. C. at which temperature glass formers present in the waste will cause it to vitrify. Glass formers, such as borosilicate glass, quartz or fiberglass can be added at the start of the process to increase the silicate concentration sufficiently for vitrification.

  3. Vitrification of waste

    DOE Patents [OSTI]

    Wicks, G.G.

    1999-04-06T23:59:59.000Z

    A method is described for encapsulating and immobilizing waste for disposal. Waste, preferably, biologically, chemically and radioactively hazardous, and especially electronic wastes, such as circuit boards, are placed in a crucible and heated by microwaves to a temperature in the range of approximately 300 C to 800 C to incinerate organic materials, then heated further to a temperature in the range of approximately 1100 C to 1400 C at which temperature glass formers present in the waste will cause it to vitrify. Glass formers, such as borosilicate glass, quartz or fiberglass can be added at the start of the process to increase the silicate concentration sufficiently for vitrification.

  4. vitrification.PDF

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual Siteof Energy 2,AUDIT REPORT Americium/Curium Vitrification Project At The Savannah River

  5. Vitrification development plan for US Department of Energy mixed wastes

    SciTech Connect (OSTI)

    Peters, R. [Pacific Northwest Lab., Richland, WA (United States); Lucerna, J. [EG and G Rocky Flats, Inc., Golden, CO (United States); Plodinec, M.J. [Westinghouse Savannah River Co., Aiken, SC (United States)

    1993-10-01T23:59:59.000Z

    This document is a general plan for conducting vitrification development for application to mixed wastes owned by the US Department of Energy. The emphasis is a description and discussion of the data needs to proceed through various stages of development. These stages are (1) screening at a waste site to determine which streams should be vitrified, (2) waste characterization and analysis, (3) waste form development and treatability studies, (4) process engineering development, (5) flowsheet and technical specifications for treatment processes, and (6) integrated pilot-scale demonstration. Appendices provide sample test plans for various stages of the vitrification development process. This plan is directed at thermal treatments which produce waste glass. However, the study is still applicable to the broader realm of thermal treatment since it deals with issues such as off-gas characterization and waste characterization that are not necessarily specific to vitrification. The purpose is to provide those exploring or considering vitrification with information concerning the kinds of data that are needed, the way the data are obtained, and the way the data are used. This will provide guidance to those who need to prioritize data needs to fit schedules and budgets. Knowledge of data needs also permits managers and planners to estimate resource requirements for vitrification development.

  6. Innovative technology summary report: Transportable vitrification system

    SciTech Connect (OSTI)

    NONE

    1998-09-01T23:59:59.000Z

    At the end of the cold war, many of the Department of Energy`s (DOE`s) major nuclear weapons facilities refocused their efforts on finding technically sound, economic, regulatory compliant, and stakeholder acceptable treatment solutions for the legacy of mixed wastes they had produced. In particular, an advanced stabilization process that could effectively treat the large volumes of settling pond and treatment sludges was needed. Based on this need, DOE and its contractors initiated in 1993 the EM-50 sponsored development effort required to produce a deployable mixed waste vitrification system. As a consequence, the Transportable Vitrification System (TVS) effort was undertaken with the primary requirement to develop and demonstrate the technology and associated facility to effectively vitrify, for compliant disposal, the applicable mixed waste sludges and solids across the various DOE complex sites. After 4 years of development testing with both crucible and pilot-scale melters, the TVS facility was constructed by Envitco, evaluated and demonstrated with surrogates, and then successfully transported to the ORNL ETTP site and demonstrated with actual mixed wastes in the fall of 1997. This paper describes the technology, its performance, the technology applicability and alternatives, cost, regulatory and policy issues, and lessons learned.

  7. Pretreatment of americium/curium solutions for vitrification

    SciTech Connect (OSTI)

    Rudisill, T.S. [Westinghouse Savannah River Company, AIKEN, SC (United States)

    1996-03-18T23:59:59.000Z

    Vitrification will be used to stabilize an americium/curium (Am/Cm) solution presently stored in F-Canyon for eventual transport to the heavy isotope programs at Oak Ridge National Laboratory. Prior to vitrification, an in-tank oxalate precipitation and a series of oxalic/nitric acid washes will be used to separate these elements and lanthanide fission products from the bulk of the uranium and metal impurities present in the solution. Pretreatment development experiments were performed to understand the behavior of the lanthanides and the metal impurities during the oxalate precipitation and properties of the precipitate slurry. The results of these experiments will be used to refine the target glass composition allowing optimization of the primary processing parameters and design of the solution transfer equipment.

  8. Vitrification of ion exchange resins

    DOE Patents [OSTI]

    Cicero-Herman, Connie A. (Aiken, SC); Workman, Rhonda Jackson (North Augusta, SC)

    2001-01-01T23:59:59.000Z

    The present invention relates to vitrification of ion exchange resins that have become loaded with hazardous or radioactive wastes, in a way that produces a homogenous and durable waste form and reduces the disposal volume of the resin. The methods of the present invention involve directly adding borosilicate glass formers and an oxidizer to the ion exchange resin and heating the mixture at sufficient temperature to produce homogeneous glass.

  9. INNOVATIVE FOSSIL FUEL FIRED VITRIFICATION TECHNOLOGY FOR SOIL REMEDIATION

    SciTech Connect (OSTI)

    J. Hnat; L.M. Bartone; M. Pineda

    2001-07-13T23:59:59.000Z

    This Summary Report summarizes the progress of Phases 3, 3A and 4 of a waste technology Demonstration Project sponsored under a DOE Environmental Management Research and Development Program and administered by the U.S. Department of Energy National Energy Technology Laboratory-Morgantown (DOE-NETL) for an ''Innovative Fossil Fuel Fired Vitrification Technology for Soil Remediation''. The Summary Reports for Phases 1 and 2 of the Program were previously submitted to DOE. The total scope of Phase 3 was to have included the design, construction and demonstration of Vortec's integrated waste pretreatment and vitrification process for the treatment of low level waste (LLW), TSCA/LLW and mixed low-level waste (MLLW). Due to funding limitations and delays in the project resulting from a law suit filed by an environmental activist and the extended time for DOE to complete an Environmental Assessment for the project, the scope of the project was reduced to completing the design, construction and testing of the front end of the process which consists of the Material Handling and Waste Conditioning (MH/C) Subsystem of the vitrification plant. Activities completed under Phases 3A and 4 addressed completion of the engineering, design and documentation of the Material Handling and Conditioning System such that final procurement of the remaining process assemblies can be completed and construction of a Limited Demonstration Project be initiated in the event DOE elects to proceed with the construction and demonstration testing of the MH/C Subsystem.

  10. Preliminary hazards analysis -- vitrification process

    SciTech Connect (OSTI)

    Coordes, D.; Ruggieri, M.; Russell, J.; TenBrook, W.; Yimbo, P. [Science Applications International Corp., Pleasanton, CA (United States)] [Science Applications International Corp., Pleasanton, CA (United States)

    1994-06-01T23:59:59.000Z

    This paper presents a Preliminary Hazards Analysis (PHA) for mixed waste vitrification by joule heating. The purpose of performing a PHA is to establish an initial hazard categorization for a DOE nuclear facility and to identify those processes and structures which may have an impact on or be important to safety. The PHA is typically performed during and provides input to project conceptual design. The PHA is then followed by a Preliminary Safety Analysis Report (PSAR) performed during Title 1 and 2 design. The PSAR then leads to performance of the Final Safety Analysis Report performed during the facility`s construction and testing. It should be completed before routine operation of the facility commences. This PHA addresses the first four chapters of the safety analysis process, in accordance with the requirements of DOE Safety Guidelines in SG 830.110. The hazards associated with vitrification processes are evaluated using standard safety analysis methods which include: identification of credible potential hazardous energy sources; identification of preventative features of the facility or system; identification of mitigative features; and analyses of credible hazards. Maximal facility inventories of radioactive and hazardous materials are postulated to evaluate worst case accident consequences. These inventories were based on DOE-STD-1027-92 guidance and the surrogate waste streams defined by Mayberry, et al. Radiological assessments indicate that a facility, depending on the radioactive material inventory, may be an exempt, Category 3, or Category 2 facility. The calculated impacts would result in no significant impact to offsite personnel or the environment. Hazardous materials assessment indicates that a Mixed Waste Vitrification facility will be a Low Hazard facility having minimal impacts to offsite personnel and the environment.

  11. Glass melter system technologies for vitrification of high-sodium-content low-level, radioactive, liquid wastes: Phase 1, SBS demonstration with simulated low-level waste. Final test report

    SciTech Connect (OSTI)

    Holmes, M.J.; Scotto, M.V.; Shiao, S.Y. [Babcock & Wilcox, Alliance, OH (United States) Research Center

    1995-12-31T23:59:59.000Z

    The attached vendor report was prepared for Westinghouse Hanford Company by Babcock & Wilcox as documentation of the Phase I Final Test Report, Cyclone Combustion Melter Demonstration.

  12. Hanford waste vitrification systems risk assessment

    SciTech Connect (OSTI)

    Miller, W.C.; Hamilton, D.W.; Holton, L.K.; Bailey, J.W.

    1991-09-01T23:59:59.000Z

    A systematic Risk Assessment was performed to identify the technical, regulatory, and programmatic uncertainties and to quantify the risks to the Hanford Site double-shell tank waste vitrification program baseline (as defined in December 1990). Mitigating strategies to reduce the overall program risk were proposed. All major program elements were evaluated, including double-shell tank waste characterization, Tank Farms, retrieval, pretreatment, vitrification, and grouting. Computer-based techniques were used to quantify risks to proceeding with construction of the Hanford Waste Vitrification Plant on the present baseline schedule. Risks to the potential vitrification of single-shell tank wastes and cesium and strontium capsules were also assessed. 62 refs., 38 figs., 26 tabs.

  13. INNOVATIVE FOSSIL FUEL FIRED VITRIFICATION TECHNOLOGY FOR SOIL REMEDIATION

    SciTech Connect (OSTI)

    J. Hnat; L.M. Bartone; M. Pineda

    2001-10-31T23:59:59.000Z

    This Final Report summarizes the progress of Phases 3,3A and 4 of a waste technology Demonstration Project sponsored under a DOE Environmental Management Research and Development Program and administered by the U.S. Department of Energy National Energy Technology Laboratory-Morgantown (DOE-NETL) for an ''Innovative Fossil Fuel Fired Vitrification Technology for Soil Remediation''. The Summary Reports for Phases 1 and 2 of the Program were previously submitted to DOE. The total scope of Phase 3 was to have included the design, construction and demonstration of Vortec's integrated waste pretreatment and vitrification process for the treatment of low level waste (LLW), TSCA/LLW and mixed low-level waste (MLLW). Due to funding limitations and delays in the project resulting from a law suit filed by an environmental activist and the extended time for DOE to complete an Environmental Assessment for the project, the scope of the project was reduced to completing the design, construction and testing of the front end of the process which consists of the Material Handling and Waste Conditioning (MH/C) Subsystem of the vitrification plant. Activities completed under Phases 3A and 4 addressed completion of the engineering, design and documentation of the MH/C System such that final procurement of the remaining process assemblies can be completed and construction of a Limited Demonstration Project be initiated in the event DOE elects to proceed with the construction and demonstration testing of the MH/C Subsystem. Because of USEPA policies and regulations that do not require treatment of low level or low-level/PCB contaminated wastes, DOE terminated the project because there is no purported need for this technology.

  14. Underground tank vitrification: A pilot-scale in situ vitrification test of a tank containing a simulated mixed waste sludge

    SciTech Connect (OSTI)

    Thompson, L.E.; Powell, T.D.; Tixier, J.S.; Miller, M.C. [Pacific Northwest Lab., Richland, WA (United States); Owczarski, P.C. [Science Applications International Corp., Richland, WA (United States)

    1993-09-01T23:59:59.000Z

    This report documents research on sludge vitrification. The first pilot scale in-situ vitrification test of a simulated underground tank was successfully completed by researchers at Pacific Northwest Laboratory. The vitrification process effectively immobilized the vast majority of radionuclides simulants and toxic metals were retained in the melt and uniformly distributed throughout the monolith.

  15. In-situ vitrification of waste materials

    DOE Patents [OSTI]

    Powell, J.R.; Reich, M.; Barletta, R.

    1997-10-14T23:59:59.000Z

    A method for the in-situ vitrification of waste materials in a disposable can that includes an inner container and an outer container is disclosed. The method includes the steps of adding frit and waste materials to the inner container, removing any excess water, heating the inner container such that the frit and waste materials melt and vitrify after cooling, while maintaining the outer container at a significantly lower temperature than the inner container. The disposable can is then cooled to ambient temperatures and stored. A device for the in-situ vitrification of waste material in a disposable can is also disclosed. 7 figs.

  16. Underground tank vitrification: Engineering-scale test results

    SciTech Connect (OSTI)

    Campbell, B.E.; Timmerman, C.L.; Bonner, W.F.

    1990-06-01T23:59:59.000Z

    Contamination associated with underground tanks at US Department of Energy sites and other sites may be effectively remediated by application of in situ vitrification (ISV) technology. In situ vitrification converts contaminated soil and buried wastes such as underground tanks into a glass and crystalline block, similar to obsidian with crystalline phases. A radioactive engineering-scale test performed at Pacific Northwest Laboratory in September 1989 demonstrated the feasibility of using ISV for this application. A 30-cm-diameter (12-in.-diameter) buried steel and concrete tank containing simulated tank sludge was vitrified, producing a solid block. The tank sludge used in the test simulated materials in tanks at Oak Ridge National Laboratory. Hazardous components of the tank sludge were immobilized or removed and captured in the off-gas treatment system. The steel tank was converted to ingots near the bottom of the block and the concrete walls were dissolved into the resulting glass and crystalline block. Although one of the four moving electrodes froze'' in place about halfway into the test, operations were able to continue. The test was successfully completed and all the tank sludge was vitrified. 7 refs., 12 figs., 5 tabs.

  17. Nuclear waste vitrification efficiency: cold cap reactions

    SciTech Connect (OSTI)

    Hrma, Pavel R.; Kruger, Albert A.; Pokorny, Richard

    2012-12-15T23:59:59.000Z

    The cost and schedule of nuclear waste treatment and immobilization are greatly affected by the rate of glass production. Various factors influence the performance of a waste-glass melter. One of the most significant, and also one of the least understood, is the process of batch melting. Studies are being conducted to gain fundamental understanding of the batch reactions, particularly those that influence the rate of melting, and models are being developed to link batch makeup and melter operation to the melting rate. Batch melting takes place within the cold cap, i.e., a batch layer floating on the surface of molten glass. The conversion of batch to glass consists of various chemical reactions, phase transitions, and diffusion-controlled processes. These include water evaporation (slurry feed contains as high as 60% water), gas evolution, the melting of salts, the formation of borate melt, reactions of borate melt with molten salts and with amorphous oxides (Fe2O3 and Al2O3), the formation of intermediate crystalline phases, the formation of a continuous glass-forming melt, the growth and collapse of primary foam, and the dissolution of residual solids. To this list we also need to add the formation of secondary foam that originates from molten glass but accumulates on the bottom of the cold cap. This study presents relevant data obtained for a high-level-waste melter feed and introduces a one-dimensional (1D) mathematical model of the cold cap as a step toward an advanced three-dimensional (3D) version for a complete model of the waste glass melter. The 1D model describes the batch-to-glass conversion within the cold cap as it progresses in a vertical direction. With constitutive equations and key parameters based on measured data, and simplified boundary conditions on the cold-cap interfaces with the glass melt and the plenum space of the melter, the model provides sensitivity analysis of the response of the cold cap to the batch makeup and melter conditions. The model demonstrates that batch foaming has a decisive influence on the rate of melting. Understanding the dynamics of the foam layer at the bottom of the cold cap and the heat transfer through it appears crucial for a reliable prediction of the rate of melting as a function of the melter-feed makeup and melter operation parameters. Although the study is focused on a batch for waste vitrification, the authors expect that the outcome will also be relevant for commercial glass melting.

  18. NUCLEAR WASTE VITRIFICATION EFFICIENCY COLD CAP REACTIONS

    SciTech Connect (OSTI)

    KRUGER AA; HRMA PR; POKORNY R

    2011-07-29T23:59:59.000Z

    The cost and schedule of nuclear waste treatment and immobilization are greatly affected by the rate of glass production. Various factors influence the performance of a waste-glass melter. One of the most significant, and also one of the least understood, is the process of batch melting. Studies are being conducted to gain fundamental understanding of the batch reactions, particularly those that influence the rate of melting, and models are being developed to link batch makeup and melter operation to the melting rate. Batch melting takes place within the cold cap, i.e., a batch layer floating on the surface of molten glass. The conversion of batch to glass consists of various chemical reactions, phase transitions, and diffusion-controlled processes. These include water evaporation (slurry feed contains as high as 60% water), gas evolution, the melting of salts, the formation of borate melt, reactions of borate melt with molten salts and with amorphous oxides (Fe{sub 2}O{sub 3} and Al{sub 2}O{sub 3}), the formation of intermediate crystalline phases, the formation of a continuous glass-forming melt, the growth and collapse of primary foam, and the dissolution of residual solids. To this list we also need to add the formation of secondary foam that originates from molten glass but accumulates on the bottom of the cold cap. This study presents relevant data obtained for a high-level-waste melter feed and introduces a one-dimensional (1D) mathematical model of the cold cap as a step toward an advanced three-dimensional (3D) version for a complete model of the waste glass melter. The 1D model describes the batch-to-glass conversion within the cold cap as it progresses in a vertical direction. With constitutive equations and key parameters based on measured data, and simplified boundary conditions on the cold-cap interfaces with the glass melt and the plenum space of the melter, the model provides sensitivity analysis of the response of the cold cap to the batch makeup and melter conditions. The model demonstrates that batch foaming has a decisive influence on the rate of melting. Understanding the dynamics of the foam layer at the bottom of the cold cap and the heat transfer through it appears crucial for a reliable prediction of the rate of melting as a function of the melter-feed makeup and melter operation parameters. Although the study is focused on a batch for waste vitrification, the authors expect that the outcome will also be relevant for commercial glass melting.

  19. Vitrification of Simulated LILW Using Induction Cold Crucible Melter Technology

    SciTech Connect (OSTI)

    Kim, C.W.; Park, J.K.; Shin, S.W.; Hwang, T.W.; Ha, J.H.; Song, M.J. [Nuclear Environment Technology Institute (NETEC), Korea Hydro and Nuclear Power Co., LTD, 150 Dukjin, Yuseong, Daejeon 305-600 (Korea, Republic of)

    2006-07-01T23:59:59.000Z

    Vitrification destroys hazardous organics, and immobilizes heavy metals and radioactive elements to form a chemically durable and highly leach-resistant vitrified form. The vitrification process provides exceptional volume reduction and is attractive for minimizing disposal volume. A pilot plant test using an induction Cold Crucible Melter (CCM) fitted with an off-gas treatment system (OGTS) has been conducted to vitrify a simulated low-and intermediate-level radioactive waste (LILW) generated from Korean nuclear power plants. The CCM process is based on the use of a water-cooled metallic structure assembled in sectors which is transparent to the electromagnetic field supplied by a high-frequency generator. A solidified glass layer because of the water-cooled structure of the CCM protects the structure against corrosion. By creating the solidified glass auto-crucible on the inner surface of the wall, corrosion damage to the steel in contact with the molten glass is prevented. In order to start-up the CCM, the glass frits were loaded in the CCM. The glass melting was initiated by heating of a short-circuited titanium ring in an electromagnetic field followed by ring burnout and incorporation of the titania in the glass frits. The melter has one drain that exits through the bottom. It is a direct bottom drain from the floor of the melt tank. It is sealed by the solidified glass layer and can be activated by removing the water cooling system. This drain is used if it is desired to drain the melter. The melter employs oxygen bubbling to promote mixing and to increase the melting rate. The bubblers are desired to produce a curtain of bubbles rising from the melter floor. In addition to mixing, the bubbling of oxygen tends to keep the melt well oxidized. The top of the melter is equipped with a number of ports. These provide access for feed, viewing, off-gas discharge, etc. The normal method of feeding is dry feeding through a feed pipe mounted through the top of the melter. The HFG power and operating frequency were applied in the ranges of 100{approx}200 kW and 250{approx}270 kHz, respectively. The simulated mixed waste vitrification test using the pilot scale plant consisting of the CCM and the OGTS at NETEC has demonstrated its good workability, reliability, and high productivity. The mixed waste was easily vitrified at a maximum rate of 20 kg per hour. The product quality of the glass such as chemical durability, phase stability, etc. was satisfactory. All regulated gases in the stack were well below the environmental regulation limits. (authors)

  20. Competition between vitrification and crystallization of methanol at high pressure

    E-Print Network [OSTI]

    Vos, Willem L.

    Competition between vitrification and crystallization of methanol at high pressure Marco J. P methanol at high pressure up to 33 GPa at room temperature with x-ray diffraction, optical polarization and vitrification is observed when methanol is superpressed beyond the freezing pressure of 3.5 GPa: between 5

  1. Vitrification and solidification remedial treatment and disposal costs

    SciTech Connect (OSTI)

    Gimpel, R.F.

    1992-03-12T23:59:59.000Z

    Solidification (making concrete) and vitrification (making glass) are frequently the treatment methods recommended for treating inorganic or radioactive wastes. Solidification is generally perceived as the most economical treatment method. Whereas, vitrification is considered (by many) as the most effective of all treatment methods. Unfortunately, vitrification has acquired the stigma that it is too expensive to receive further consideration as an alternative to solidification in high volume treatment applications. Ironically, economic studies, as presented in this paper, show that vitrification may be more competitive in some high volume applications. Ex-situ solidification and vitrification are the competing methods for treating in excess of 450,000 m{sup 3} of low-level radioactive and mixed waste at the Fernald Environmental Management Project (FEMP or simply, Fernald) located near Cincinnati, Ohio. This paper summarizes a detailed study done to: compare the economics of the solidification and vitrification processes, determine if the stigma assigned to vitrification is warranted and, determine if investing millions of dollars into vitrification development, along with solidification development, at the Fernald is warranted.

  2. Vitrification of organics-containing wastes

    DOE Patents [OSTI]

    Bickford, D.F.

    1995-01-01T23:59:59.000Z

    A process for stabilizing organics-containing waste materials and recovery metals therefrom, and a waste glass product made according to the process are described. Vitrification of wastes such as organic ion exchange resins, electronic components and the like can be accomplished by mixing at least one transition metal oxide with the wastes, and, if needed, glass formers to compensate for a shortage of silicates or other glass formers in the wastes. The transition metal oxide increases the rate of oxidation of organic materials in the wastes to improve the composition of the glass-forming mixture: at low temperatures, the oxide catalyzes oxidation of a portion of the organics in the waste; at higher temperatures, the oxide dissolves and the resulting oxygen ions oxidize more of the organics; and at vitrification temperatures, the metal ions conduct oxygen into the melt to oxidize the remaining organics. In addition, the transition metal oxide buffers the redox potential of the glass melt so that metals such as Au, Pt, Ag, and Cu separate form the melt in the metallic state and can be recovered. After the metals are recovered, the remainder of the melt is allowed to cool and may subsequently be disposed of. The product has good leaching resistance and can be disposed of in an ordinary landfill, or, alternatively, used as a filler in materials such as concrete, asphalt, brick and tile.

  3. Vitrification of organics-containing wastes

    DOE Patents [OSTI]

    Bickford, D.F.

    1997-09-02T23:59:59.000Z

    A process is described for stabilizing organics-containing waste materials and recovering metals therefrom, and a waste glass product made according to the process is also disclosed. Vitrification of wastes such as organic ion exchange resins, electronic components and the like can be accomplished by mixing at least one transition metal oxide with the wastes, and, if needed, glass formers to compensate for a shortage of silicates or other glass formers in the wastes. The transition metal oxide increases the rate of oxidation of organic materials in the wastes to improve the composition of the glass-forming mixture: at low temperatures, the oxide catalyzes oxidation of a portion of the organics in the waste; at higher temperatures, the oxide dissolves and the resulting oxygen ions oxidize more of the organics; and at vitrification temperatures, the metal ions conduct oxygen into the melt to oxidize the remaining organics. In addition, the transition metal oxide buffers the redox potential of the glass melt so that metals such as Au, Pt, Ag, and Cu separate from the melt in the metallic state and can be recovered. After the metals are recovered, the remainder of the melt is allowed to cool and may subsequently be disposed of. The product has good leaching resistance and can be disposed of in an ordinary landfill, or, alternatively, used as a filler in materials such as concrete, asphalt, brick and tile. 1 fig.

  4. Vitrification of organics-containing wastes

    DOE Patents [OSTI]

    Bickford, Dennis F. (Aiken, SC)

    1997-01-01T23:59:59.000Z

    A process for stabilizing organics-containing waste materials and recovering metals therefrom, and a waste glass product made according to the process. Vitrification of wastes such as organic ion exchange resins, electronic components and the like can be accomplished by mixing at least one transition metal oxide with the wastes, and, if needed, glass formers to compensate for a shortage of silicates or other glass formers in the wastes. The transition metal oxide increases the rate of oxidation of organic materials in the wastes to improve the composition of the glass-forming mixture: at low temperatures, the oxide catalyzes oxidation of a portion of the organics in the waste; at higher temperatures, the oxide dissolves and the resulting oxygen ions oxidize more of the organics; and at vitrification temperatures, the metal ions conduct oxygen into the melt to oxidize the remaining organics. In addition, the transition metal oxide buffers the redox potential of the glass melt so that metals such as Au, Pt, Ag, and Cu separate from the melt in the metallic state and can be recovered. After the metals are recovered, the remainder of the melt is allowed to cool and may subsequently be disposed of. The product has good leaching resistance and can be disposed of in an ordinary landfill, or, alternatively, used as a filler in materials such as concrete, asphalt, brick and tile.

  5. PNL vitrification technology development project glass formulation strategy for LLW vitrification

    SciTech Connect (OSTI)

    Kim, D.; Hrma, P.R.; Westsik, J.H. Jr.

    1996-03-01T23:59:59.000Z

    This Glass Formulation Strategy describes development approaches to optimize glass compositions for Hanford`s low-level waste vitrification between now and the projected low-level waste facility start-up in 2005. The objectives of the glass formulation task are to develop optimized glass compositions with satisfactory long-term durability, acceptable processing characteristics, adequate flexibility to handle waste variations, maximize waste loading to practical limits, and to develop methodology to respond to further waste variations.

  6. Apparatus for in situ heating and vitrification

    DOE Patents [OSTI]

    Buelt, J.L.; Oma, K.H.; Eschbach, E.A.

    1994-05-31T23:59:59.000Z

    An apparatus for decontaminating ground areas where toxic chemicals are buried includes a plurality of spaced electrodes located in the ground and to which a voltage is applied for bringing about current flow. Power delivered to the ground volatilizes the chemicals that are then collected and directed to a gas treatment system. A preferred form of the invention employs high voltage arc discharge between the electrodes for heating a ground region to relatively high temperatures at relatively low power levels. Electrodes according to the present invention are provided with preferentially active lower portions between which current flows for the purpose of soil heating or for soil melting and vitrification. Promoting current flow below ground level avoids predominantly superficial treatment and increases electrode life. 15 figs.

  7. LFCM vitrification technology. Quarterly progress report, October-December 1985

    SciTech Connect (OSTI)

    Burkholder, H.C.; Jarrett, J.H.; Minor, J.E. (comps.)

    1986-09-01T23:59:59.000Z

    This report is compiled by the Nuclear Waste Treatment Program and the Hanford Waste Vitrification Program at Pacific Northwest Laboratory to document progress on liquid-fed ceramic melter (LFCM) vitrification technology. Progress in the following technical subject areas during the first quarter of FY 1986 is discussed: melting process chemistry and glass development, feed preparation and transfer systems, melter systems, canister filling and handling systems, off-gas systems, process/product modeling and control, and supporting studies.

  8. Process for treating alkaline wastes for vitrification

    DOE Patents [OSTI]

    Hsu, C.L.W.

    1995-07-25T23:59:59.000Z

    A process is described for treating alkaline wastes for vitrification. The process involves acidifying the wastes with an oxidizing agent such as nitric acid, then adding formic acid as a reducing agent, and then mixing with glass formers to produce a melter feed. The nitric acid contributes nitrates that act as an oxidant to balance the redox of the melter feed, prevent reduction of certain species to produce conducting metals, and lower the pH of the wastes to a suitable level for melter operation. The formic acid reduces mercury compounds to elemental mercury for removal by steam stripping, and MnO{sub 2} to the Mn(II) ion to prevent foaming of the glass melt. The optimum amounts of nitric acid and formic acid are determined in relation to the composition of the wastes, including the concentrations of mercury (II) and MnO{sub 2}, noble metal compounds, nitrates, formates and so forth. The process minimizes the amount of hydrogen generated during treatment, while producing a redox-balanced feed for effective melter operation and a quality glass product. 4 figs.

  9. Process for treating alkaline wastes for vitrification

    DOE Patents [OSTI]

    Hsu, Chia-lin W. (Augusta, GA)

    1995-01-01T23:59:59.000Z

    A process for treating alkaline wastes for vitrification. The process involves acidifying the wastes with an oxidizing agent such as nitric acid, then adding formic acid as a reducing agent, and then mixing with glass formers to produce a melter feed. The nitric acid contributes nitrates that act as an oxidant to balance the redox of the melter feed, prevent reduction of certain species to produce conducting metals, and lower the pH of the wastes to a suitable level for melter operation. The formic acid reduces mercury compounds to elemental mercury for removal by steam stripping, and MnO.sub.2 to the Mn(II) ion to prevent foaming of the glass melt. The optimum amounts of nitric acid and formic acid are determined in relation to the composition of the wastes, including the concentrations of mercury (II) and MnO.sub.2, noble metal compounds, nitrates, formates and so forth. The process minimizes the amount of hydrogen generated during treatment, while producing a redox-balanced feed for effective melter operation and a quality glass product.

  10. Process for treating alkaline wastes for vitrification

    DOE Patents [OSTI]

    Hsu, Chia-lin W.

    1994-01-01T23:59:59.000Z

    According to its major aspects and broadly stated, the present invention is a process for treating alkaline waste materials, including high level radioactive wastes, for vitrification. The process involves adjusting the pH of the wastes with nitric acid, adding formic acid (or a process stream containing formic acid) to reduce mercury compounds to elemental mercury and MnO{sub 2} to the Mn(II) ion, and mixing with class formers to produce a melter feed. The process minimizes production of hydrogen due to noble metal-catalyzed formic acid decomposition during, treatment, while producing a redox-balanced feed for effective melter operation and a quality glass product. An important feature of the present invention is the use of different acidifying and reducing, agents to treat the wastes. The nitric acid acidifies the wastes to improve yield stress and supplies acid for various reactions; then the formic acid reduces mercury compounds to elemental mercury and MnO{sub 2}) to the Mn(II) ion. When the pH of the waste is lower, reduction of mercury compounds and MnO{sub 2}) is faster and less formic acid is needed, and the production of hydrogen caused by catalytically-active noble metals is decreased.

  11. Feasibility Study for Vitrification of Sodium-Bearing Waste

    SciTech Connect (OSTI)

    J. J. Quigley; B. D. Raivo; S. O. Bates; S. M. Berry; D. N. Nishioka; P. J. Bunnell

    2000-09-01T23:59:59.000Z

    Treatment of sodium-bearing waste (SBW) at the Idaho Nuclear Technology and Engineering Center (INTEC) within the Idaho National Engineering and Environmental Laboratory is mandated under a Settlement Agreement between the Department of Energy and the State of Idaho. One of the requirements of the Settlement Agreement is the complete calcination (i.e., treatment) of all SBW by December 31, 2012. One of the proposed options for treatment of SBW is vitrification. This study will examine the viability of SBW vitrification. This study describes the process and facilities to treat the SBW, from beginning waste input from INTEC Tank Farm to the final waste forms. Schedules and cost estimates for construction and operation of a Vitrification Facility are included. The study includes a facility layout with drawings, process description and flow diagrams, and preliminary equipment requirements and layouts.

  12. Evaluation of melter technologies for vitrification of Hanford site low-level tank waste - phase 1 testing summary report

    SciTech Connect (OSTI)

    Wilson, C.N., Westinghouse Hanford

    1996-06-27T23:59:59.000Z

    Following negotiation of the fourth amendment to the Tri- Party Agreement for Hanford Site cleanup, commercially available melter technologies were tested during 1994 and 1995 for vitrification of the low-level waste (LLW) stream to be derived from retrieval and pretreatment of the radioactive defense wastes stored in 177 underground tanks. Seven vendors were selected for Phase 1 testing to demonstrate vitrification of a high-sodium content liquid LLW simulant. The tested melter technologies included four Joule-heated melters, a carbon electrode melter, a combustion melter, and a plasma melter. Various dry and slurry melter feed preparation processes also were tested. The technologies and Phase 1 testing results were evaluated and a preliminary technology down-selection completed. This report describes the Phase 1 LLW melter vendor testing and the tested technologies, and summarizes the testing results and the preliminary technology recommendations.

  13. Progress achieved in HLW vitrification techniques at INE

    SciTech Connect (OSTI)

    Grunewald, W.; Roth, G.; Tobie, W.; Weisenburger, S. [Kernforschungszentrum Karlsruhe GmbH (Germany). Inst. fuer Nucleare Entsorgungstechnik

    1993-12-31T23:59:59.000Z

    The progress in the liquid-fed ceramic waste glass melter process for high level waste vitrification is described. The technique has been used in the PAMELA plant in Mol/Belgium from 1985 to 1991. Currently three programs are underway at INE (Institut fuer Nukleare Entsorgungstechnik): a technology program for optimizing the process for noble metals containing high level waste (HLW), a vitrification technology transfer project with China, and a research project on noble metals behavior in an engineering scale melter which is funded by the US Department of Energy with oversight by the Pacific Northwest Laboratory (PNL) in Richland, WA. The status of the programs and results available are described.

  14. Hanford Waste Vitrification Plant technical manual

    SciTech Connect (OSTI)

    Larson, D.E. [ed.; Watrous, R.A.; Kruger, O.L. [and others

    1996-03-01T23:59:59.000Z

    A key element of the Hanford waste management strategy is the construction of a new facility, the Hanford Waste Vitrification Plant (HWVP), to vitrify existing and future liquid high-level waste produced by defense activities at the Hanford Site. The HWVP mission is to vitrify pretreated waste in borosilicate glass, cast the glass into stainless steel canisters, and store the canisters at the Hanford Site until they are shipped to a federal geological repository. The HWVP Technical Manual (Manual) documents the technical bases of the current HWVP process and provides a physical description of the related equipment and the plant. The immediate purpose of the document is to provide the technical bases for preparation of project baseline documents that will be used to direct the Title 1 and Title 2 design by the A/E, Fluor. The content of the Manual is organized in the following manner. Chapter 1.0 contains the background and context within which the HWVP was designed. Chapter 2.0 describes the site, plant, equipment and supporting services and provides the context for application of the process information in the Manual. Chapter 3.0 provides plant feed and product requirements, which are primary process bases for plant operation. Chapter 4.0 summarizes the technology for each plant process. Chapter 5.0 describes the engineering principles for designing major types of HWVP equipment. Chapter 6.0 describes the general safety aspects of the plant and process to assist in safe and prudent facility operation. Chapter 7.0 includes a description of the waste form qualification program and data. Chapter 8.0 indicates the current status of quality assurance requirements for the Manual. The Appendices provide data that are too extensive to be placed in the main text, such as extensive tables and sets of figures. The Manual is a revision of the 1987 version.

  15. Vitrification of cesium-contaminated organic ion exchange resin

    SciTech Connect (OSTI)

    Sargent, T.N. Jr. [Clemson Univ., SC (United States)

    1994-08-01T23:59:59.000Z

    Vitrification has been declared by the Environmental Protection Agency (USEPA) as the Best Demonstrated Available Technology (BDAT) for the permanent disposal of high-level radioactive waste. Savannah River Site currently uses a sodium tetraphenylborate (NaTPB) precipitation process to remove Cs-137 from a wastewater solution created from the processing of nuclear fuel. This process has several disadvantages such as the formation of a benzene waste stream. It has been proposed to replace the precipitation process with an ion exchange process using a new resorcinol-formaldehyde resin developed by Savannah River Technical Center (SRTC). Preliminary tests, however, showed that problems such as crust formation and a reduced final glass wasteform exist when the resin is placed in the melter environment. The newly developed stirred melter could be capable of overcoming these problems. This research explored the operational feasibility of using the stirred tank melter to vitrify an organic ion exchange resin. Preliminary tests included crucible studies to determine the reducing potential of the resin and the extent of oxygen consuming reactions and oxygen transfer tests to approximate the extent of oxygen transfer into the molten glass using an impeller and a combination of the impeller and an external oxygen transfer system. These preliminary studies were used as a basis for the final test which was using the stirred tank melter to vitrify nonradioactive cesium loaded organic ion exchange resin. Results from this test included a cesium mass balance, a characterization of the semi-volatile organic compounds present in the off gas as products of incomplete combustion (PIC), a qualitative analysis of other volatile metals, and observations relating to the effect the resin had on the final redox state of the glass.

  16. LFCM vitrification technology: Quarterly progress report, July-September 1987

    SciTech Connect (OSTI)

    Brouns, R.A.; Allen, C.R.; Powell, J.A. (comps.); Bates, S.O.; Bray, L.A.; Budden, M.J.; Dierks, R.D.; Elliott, M.L.; Elmore, M.R.; Faletti, D.W.; Farnsworth, R.K.; Holton, L.K. Jr.; Kuhn, W.L.; Mellinger, G.B.; Nakaoka, R.K.; Peterson, M.E.; Piepel, G.F.; Powell, J.A.; Pulsipher, B.A.; Reimus, M.A.H.; Surma, J.E.; Wiemers, K.D.

    1988-09-01T23:59:59.000Z

    This report describes the progress in developing, testing, applying and documenting liquid-fed ceramic melter vitrification technology. Progress in the following technical subject areas during the fourth quarter of FY 1987 is discussed: melting process chemistry and glass development, feed preparation and transfer systems, canister filling and handling systems, and process/product modeling and control.

  17. Informal Report IN-SITU VITRIFICATION (ISV)ORGANIC-SURROGATE

    E-Print Network [OSTI]

    and sizingof contentsof a "typical"BNL glass hole, Table 1was constructedto emulatethe glass bottle sizes, void bottles,oPDCHin H20lacetone solutionin glass bottles, and PMCPin H20 and HzOIacetone solution in 4 metal;Introduction Pilot tests of a commercial soil vitrification process forentombingAnimaVChemical and Glass Hole

  18. Vitrification of M-Area Mixed (Hazardous and Radioactive) F006 Wastes: I. Sludge and Supernate Characterization

    SciTech Connect (OSTI)

    Jantzen, C.M.

    2001-10-05T23:59:59.000Z

    Technologies are being developed by the US Department of Energy's (DOE) Nuclear Facility sites to convert low-level and mixed (hazardous and radioactive) wastes to a solid stabilized waste form for permanent disposal. One of the alternative technologies is vitrification into a borosilicate glass waste form. The Environmental Protection Agency (EPA) has declared vitrification the Best Demonstrated Available Technology (BDAT) for high-level radioactive mixed waste and produced a Handbook of Vitrification Technologies for Treatment of Hazardous and Radioactive Waste. The DOE Office of Technology Development (OTD) has taken the position that mixed waste needs to be stabilized to the highest level reasonably possible to ensure that the resulting waste forms will meet both current and future regulatory specifications. Stabilization of low level and hazardous wastes in glass are in accord with the 1988 Savannah River Technology Center (SRTC), then the Savannah River Laboratory (SRL), Professional Planning Committee (PPC) recommendation that high nitrate containing (low-level) wastes be incorporated into a low temperature glass (via a sol-gel technology). The investigation into this new technology was considered timely because of the potential for large waste volume reduction compared to solidification into cement.

  19. Development of a combined soil-wash/in-furnace vitrification system for soil remediation at DOE sites. Final report

    SciTech Connect (OSTI)

    Pegg, I.L.; Guo, Y.; Lahoda, E.J.; Lai, Shan-Tao; Muller, I.S.; Ruller, J. [GTS Duratek, Columbia, MD (United States); Grant, D.C. [Westinghouse Electric Corp., Pittsburgh, PA (United States). Science and Technology Center

    1993-01-01T23:59:59.000Z

    This report addresses research and development of technologies for treatment of radioactive and hazardous waste streams at DOE sites. Weldon Spring raffinate sludges were used in a direct vitrification study to investigate their use as fluxing agents in glass formulations when blended with site soil. Storm sewer sediments from the Oak Ridge, TN, Y-12 facility were used for soil washing followed by vitrification of the concentrates. Both waste streams were extensively characterized. Testing showed that both mercury and uranium could be removed from the Y-12 soil by chemical extraction resulting in an 80% volume reduction. Thermal desorption was used on the contaminant-enriched minority fraction to separate the mercury from the uranium. Vitrification tests demonstrated that high waste loading glasses could be produced from the radioactive stream and from the Weldon Spring wastes which showed very good leach resistance, and viscosities and electrical conductivities in the range suitable for joule-heated ceramic melter (JHCM) processing. The conceptual process described combines soil washing, thermal desorption, and vitrification to produce clean soil (about 90% of the input waste stream), non-radioactive mercury, and a glass wasteform; the estimated processing costs for that system are about $260--$400/yd{sup 3}. Results from continuous melter tests performed using Duratek`s advanced JHCM (Duramelter) system are also presented. Since life cycle cost estimates are driven largely by volume reduction considerations, the large volume reductions possible with these multi-technology, blended waste stream approaches can produce a more leach resistant wasteform at a lower overall cost than alternative technologies such as cementation.

  20. Test plan for BWID Phase 2 electric arc melter vitrification tests

    SciTech Connect (OSTI)

    Soelberg, N.R.; Turner, P.C.; Oden, L.L.; Anderson, G.L.

    1994-10-01T23:59:59.000Z

    This test plan describes the Buried Waste Integrated Demonstration (BWID), Phase 2, electric arc melter, waste treatment evaluation tests to be performed at the US Bureau of Mines (USBM) Albany Research Center. The BWID Arc Melter Vitrification Project is being conducted to evaluate and demonstrate existing industrial arc melter technology for thermally treating mixed transuranic-contaminated wastes and soils. Phase 1 baseline tests, performed during fiscal year 1993 at the USBM, were conducted on waste feeds representing incinerated buried mixed wastes and soils. In Phase 2, surrogate feeds will be processed that represent actual as-retrieved buried wastes from the Idaho National Engineering Laboratory`s Subsurface Disposal Area at the Radioactive Waste Management Complex.

  1. Fiscal year 1997 final report for task plan SR-16WT-31 task B, vitrification of ion exchange material

    SciTech Connect (OSTI)

    Ferrara, D.; Andrews, M.K.; Harbour, J.R.; Fellinger, T.L.; Herman, D.T.; Marshall, K.M.; Workman, P.J.

    1997-09-30T23:59:59.000Z

    In Fiscal Year 1997, the Department of Energy Tanks Focus Area (TFA) funded the Savannah River Technology Center (SRTC) to develop and demonstrate the vitrification of a CST ion exchange material loaded with radioactive cesium from one of the Melton Valley Storage Tanks at the Oak Ridge National Laboratory (ORNL). SRTC developed a patent-pending glass formulation that can be used to vitrify CST sorbent producing a quality borosilicate glass waste form. SRTC demonstrated this formulation by vitrifying the radioactive CST in the SRTC shielded cells melter.In addition to the formulation developed for vitrification of the `CST-only` glass waste form, SRTC also developed formulations for vitrification of CST coupled with High-Level Waste (HLW) sludges. A Defense Waste Processing Facility (DWPF) coupled feed formulation has been developed with up to 10 weight percent CST and 28 weight percent DWPF sludge oxides. A coupled Hanford formulation has also been developed for producing quality glass waste forms with up to 10 weight percent CST and 45 weight percent Hanford sludge oxides. The significant accomplishments of this project were then development of CST-only glass formulations incorporating up to 65 weight-percent CST, development of techniques for delivering a slurry or dry feed to a joule-heated melter, demonstration of a CST-only glass formulation in a continuous melter operation, demonstration of compliance with the Nevada Test Site (NTS) Waste Acceptance Criteria (WAC), development of CST-sludge glass formulations incorporating up to 10 weight percent CST and 28 weight percent DWPF sludges oxides, demonstration of CST-sludge glass formulations using radioactive sludge and radioactive CST, development of CST-sludge glass formulations incorporating up to 10 weight percent CST and 45 weight percent. All commitments made to the TFA have been met as indicated by the associated milestones. Milestones and the month in which they were completed: Initiate Immobilization of CST in Glass (completed 8/97); Demonstrate that Sludge-CST Glass Satisfied PC Specs in WAPS (completed 9/97); Determine Process Parameters of Sludge-CST Glass (completed 8/97); Demonstrate that CST-Only Glass Satisfied PC Specs in WAPS (completed 9/97); Determine Process Parameters of CST-Only Glass (completed 9/97). The results for Task B of Task Plan SR-16WT-31 have been documented in reports that have been included as attachments. The following is a summary of the attachments from the CST vitrification project.

  2. Development of a remote bushing for actinide vitrification

    SciTech Connect (OSTI)

    Schumacher, R.F.; Ramsey, W.G.; Johnson, F.M. [and others

    1996-12-31T23:59:59.000Z

    The Savannah River Site (SRS) and the Savannah River Technology Center (SRTC) are combining their existing experience in handling highly radioactive, special nuclear materials with commercial glass fiberization technology in order to assemble a small vitrification system for radioactive actinide solutions. The vitrification system or {open_quotes}brushing{close_quotes}, is fabricated from platinum-rhodium alloy and is based on early marble remelt fiberization technology. Advantages of this unique system include its relatively small size, reliable operation, geometrical safety (nuclear criticality), and high temperature capability. The bushing design should be capable of vitrifying a number of the actinide nuclear materials, including solutions of americium/curium, neptunium, and possibly plutonium. State of the art, mathematical and oil model studies are being combined with basic engineering evaluations to verify and improve the thermal and mechanical design concepts.

  3. Evaluation of vitrification factors from DWPF's macro-batch 1

    SciTech Connect (OSTI)

    Edwards, T.B.

    2000-01-25T23:59:59.000Z

    The Defense Waste Processing Facility (DWPF) is evaluating new sampling and analytical methods that may be used to support future Slurry Mix Evaporator (SME) batch acceptability decisions. This report uses data acquired during DWPF's processing of macro-batch 1 to determine a set of vitrification factors covering several SME and Melter Feed Tank (MFT) batches. Such values are needed for converting the cation measurements derived from the new methods to a ``glass'' basis. The available data from macro-batch 1 were used to examine the stability of these vitrification factors, to estimate their uncertainty over the course of a macro-batch, and to provide a recommendation on the use of a single factor for an entire macro-batch. The report is in response to Technical Task Request HLW/DWPF/TTR-980015.

  4. The role of troublesome components in plutonium vitrification

    SciTech Connect (OSTI)

    Li, Hong; Vienna, J.D.; Peeler, D.K.; Hrma, P.; Schweiger, M.J. [Pacific Northwest National Lab., Richland, WA (United States)

    1996-05-01T23:59:59.000Z

    One option for immobilizing surplus plutonium is vitrification in a borosilicate glass. Two advantages of the glass form are (1) high tolerance to feed variability and, (2) high solubility of some impurity components. The types of plutonium-containing materials in the United States inventory include: pits, metals, oxides, residues, scrap, compounds, and fuel. Many of them also contain high concentrations of carbon, chloride, fluoride, phosphate, sulfate, and chromium oxide. To vitrify plutonium-containing scrap and residues, it is critical to understand the impact of each component on glass processing and chemical durability of the final product. This paper addresses glass processing issues associated with these troublesome components. It covers solubility limits of chlorine, fluorine, phosphate, sulfate, and chromium oxide in several borosilicate based glasses, and the effect of each component on vitrification (volatility, phase segregation, crystallization, and melt viscosity). Techniques (formulation, pretreatment, removal, and/or dilution) to mitigate the effect of these troublesome components are suggested.

  5. Scaling considerations for modeling the in situ vitrification process

    SciTech Connect (OSTI)

    Langerman, M.A.; MacKinnon, R.J.

    1990-09-01T23:59:59.000Z

    Scaling relationships for modeling the in situ vitrification waste remediation process are documented based upon similarity considerations derived from fundamental principles. Requirements for maintaining temperature and electric potential field similarity between the model and the prototype are determined as well as requirements for maintaining similarity in off-gas generation rates. A scaling rationale for designing reduced-scale experiments is presented and the results are assessed numerically. 9 refs., 6 figs.

  6. Integration of pneumatic fracturing and in situ vitrification in the soil subsurface

    SciTech Connect (OSTI)

    Luey, J.; Seiler, D.K. [Pacific Northwest Lab., Richland, WA (United States); Schuring, J.R.

    1995-02-01T23:59:59.000Z

    Pacific Northwest Laboratory is evaluating ways to increase the applicability of the in situ vitrification (ISV) process at hazardous and radioactive waste sites. One innovation is the placement of a conductive material that will facilitate initiating the ISV process at a target depth. A series of laboratory tests performed at the New Jersey Institute of Technology (NJIT) assessed the feasibility of pneumatic fracturing (PF) in the highly permeable soils of the Hanford Site. The NJIT tests included an analysis of Hanford soils, a series of PF injection tests, and a parametric analysis to determine how soil properties affect the PF process. Results suggest that the PF process can be applied to Hanford soils and that dry medium (e.g., conductive material such as graphite flake) can be injected into the fracture. This paper describes the laboratory testing performed at NJIT, its results, and the application of those results to plans for a field demonstration at Hanford.

  7. Independent engineering review of the Hanford Waste Vitrification System

    SciTech Connect (OSTI)

    Not Available

    1991-10-01T23:59:59.000Z

    The Hanford Waste Vitrification Plant (HWVP) was initiated in June 1987. The HWVP is an essential element of the plan to end present interim storage practices for defense wastes and to provide for permanent disposal. The project start was justified, in part, on efficient technology and design information transfer from the prototype Defense Waste Processing Facility (DWPF). Development of other serial Hanford Waste Vitrification System (HWVS) elements, such as the waste retrieval system for the double-shell tanks (DSTs), and the pretreatment system to reduce the waste volume converted into glass, also was required to accomplish permanent waste disposal. In July 1991, at the time of this review, the HWVP was in the Title 2 design phase. The objective of this technical assessment is to determine whether the status of the technology development and engineering practice is sufficient to provide reasonable assurance that the HWVP and the balance of the HWVS system will operate in an efficient and cost-effective manner. The criteria used to facilitate a judgment of potential successful operation are: vitrification of high-level radioactive waste from specified DSTs on a reasonably continuous basis; and glass produced with physical and chemical properties formally acknowledge as being acceptable for disposal in a repository for high-level radioactive waste. The criteria were proposed specifically for the Independent Engineering Review to focus that assessment effort. They are not represented as the criteria by which the Department will judge the prudence of the Project. 78 refs., 10 figs., 12 tabs.

  8. Method for initiating in-situ vitrification using an impregnated cord

    DOE Patents [OSTI]

    Carter, John G. (Richland, WA)

    1991-01-01T23:59:59.000Z

    In-situ vitrification of soil is initiated by placing a cord of dielectric material impregnated with conductive material in thermally-conductive contact with the soil, and energizing the cord with an electric current for heating the cord and starting the vitrification process.

  9. Review of FY 2001 Development Work for Vitrification of Sodium Bearing Waste

    SciTech Connect (OSTI)

    Taylor, Dean Dalton; Barnes, Charles Marshall

    2002-09-01T23:59:59.000Z

    Treatment of sodium-bearing waste (SBW) at the Idaho Nuclear Technology and Engineering Center (INTEC) within the Idaho National Engineering and Environmental Laboratory is mandated by the Settlement Agreement between the Department of Energy and the State of Idaho. This report discusses significant findings from vitrification technology development during 2001 and their impacts on the design basis for SBW vitrification.

  10. Product Demonstrations

    Broader source: Energy.gov [DOE]

    The Consortium will pursue a number of demonstrations following the general procedure used by DOE's GATEWAY demonstration program. Specific products to be featured in a demonstration may be...

  11. Technical letter report: Submerged bed scrubber sediment resuspension testing for the Hanford Waste Vitrification Plant

    SciTech Connect (OSTI)

    Schmidt, A.J.; Herrington, M.G.

    1996-03-01T23:59:59.000Z

    During-vitrification operations in the Hanford Waste Vitrification Plant (HWVP), some feed components will be vented from the melter to the melter offgas cleaning equipment. The current HWVP reference process for melter off.-gas treatment includes a submerged bed scrubber (SBS) to provide the first stage of off-gas scrubbing and quenching. During most melter/off-gas test runs at Pacific Northwest Laboratory (PNL) with the Pilot Scale Ceramic Melter (PSCM) and at the West Valley Demonstration Project (WVDP), no significant quantities of sedimentation were accumulated in the SBS scrub tank. However, during test run SF-12, conducted at West Valley, approximately 6 in. of sedimentation accumulated in the scrub tank. This raised concerns that a similar accumulation could occur with the HWVP SBS, If such an accumulation rate occurred during a sustained melter run, the SBS would soon cease to function. To alleviate the potential for sedimentation buildup, the HWVP SBS design includes a sparge ring at the bottom of the scrub tank. The sparge ring will be operated intermittently to prevent buildup of solids which could interfere with circulation with the SBS Scrub tank. This report presents the results of testing conducted to evaluate the effectiveness of the HWVP sparge ring design. Section 2 contains-the conclusions and recommendations; Section 3 summarizes the objectives; Section 4 describes the equipment and materials used; Section 5 gives the experimental approach; and Section 6 discusses the results. The appendices contain procedures for sediment resuspension testing and particle size distribution data for silica and sediment.

  12. Idaho Waste Vitrification Facilities Project Vitrified Waste Interim Storage Facility

    SciTech Connect (OSTI)

    Bonnema, Bruce Edward

    2001-09-01T23:59:59.000Z

    This feasibility study report presents a draft design of the Vitrified Waste Interim Storage Facility (VWISF), which is one of three subprojects of the Idaho Waste Vitrification Facilities (IWVF) project. The primary goal of the IWVF project is to design and construct a treatment process system that will vitrify the sodium-bearing waste (SBW) to a final waste form. The project will consist of three subprojects that include the Waste Collection Tanks Facility, the Waste Vitrification Facility (WVF), and the VWISF. The Waste Collection Tanks Facility will provide for waste collection, feed mixing, and surge storage for SBW and newly generated liquid waste from ongoing operations at the Idaho Nuclear Technology and Engineering Center. The WVF will contain the vitrification process that will mix the waste with glass-forming chemicals or frit and turn the waste into glass. The VWISF will provide a shielded storage facility for the glass until the waste can be disposed at either the Waste Isolation Pilot Plant as mixed transuranic waste or at the future national geological repository as high-level waste glass, pending the outcome of a Waste Incidental to Reprocessing determination, which is currently in progress. A secondary goal is to provide a facility that can be easily modified later to accommodate storage of the vitrified high-level waste calcine. The objective of this study was to determine the feasibility of the VWISF, which would be constructed in compliance with applicable federal, state, and local laws. This project supports the Department of Energy’s Environmental Management missions of safely storing and treating radioactive wastes as well as meeting Federal Facility Compliance commitments made to the State of Idaho.

  13. Technology status report: In situ vitrification applied to buried wastes

    SciTech Connect (OSTI)

    Thompson, L.E. [Pacific Northwest Lab., Richland, WA (United States); Bates, S.O. [EG and G Idaho, Inc., Idaho Falls, ID (United States); Hansen, J.E. [Geosafe Corp., Richland, WA (United States)

    1992-09-01T23:59:59.000Z

    This document is a technical status report on In Situ Vitrification (ISV) as applied to buried waste; the report takes both technical and institutional concerns into perspective. The ISV process involves electrically melting such contaminated solid media as soil, sediment, sludge, and mill tailings. The resultant product is a high-quality glass-and-crystalline waste form that possesses high resistance to corrosion and leaching and is capable of long-term environmental exposure without significant degradation. The process also significantly reduces the volume of the treated solid media due to the removal of pore spaces in the soil.

  14. Hanford Waste Vitrification Plant Project Waste Form Qualification Program Plan

    SciTech Connect (OSTI)

    Randklev, E.H.

    1993-06-01T23:59:59.000Z

    The US Department of Energy has created a waste acceptance process to help guide the overall program for the disposal of high-level nuclear waste in a federal repository. This Waste Form Qualification Program Plan describes the hierarchy of strategies used by the Hanford Waste Vitrification Plant Project to satisfy the waste form qualification obligations of that waste acceptance process. A description of the functional relationship of the participants contributing to completing this objective is provided. The major activities, products, providers, and associated scheduling for implementing the strategies also are presented.

  15. Evaluation of Vitrification Processing Step for Rocky Flats Incinerator Ash

    SciTech Connect (OSTI)

    Wigent, W.L.; Luey, J.K.; Scheele, R.D.; Li, H.

    1999-04-08T23:59:59.000Z

    In 1997, Pacific Northwest National Laboratory (PNNL) staff developed a processing option for incinerator ash at the Rocky Flats Environmental Technology Sites (RFETS). This work was performed with support from Los Alamos National Laboratory (LANL) and Safe Sites of Colorado (SSOC). A description of the remediation needs for the RFETS incinerator ash is provided in a report summarizing the recommended processing option for treatment of the ash (Lucy et al. 1998). The recommended process flowsheet involves a calcination pretreatment step to remove carbonaceous material followed by a vitrification processing step for a mixture of glass tit and calcined incinerator ash. Using the calcination pretreatment step to remove carbonaceous material reduced process upsets for the vitrification step, allowed for increased waste loading in the final product, and improved the quality of the final product. Figure 1.1 illustrates the flow sheet for the recommended processing option for treatment of RFETS incinerator ash. In 1998, work at PNNL further developed the recommended flow sheet through a series of studies to better define the vitrification operating parameters and to address secondary processing issues (such as characterizing the offgas species from the calcination process). Because a prototypical rotary calciner was not available for use, studies to evaluate the offgas from the calcination process were performed using a benchtop rotary calciner and laboratory-scale equipment (Lucy et al. 1998). This report focuses on the vitrification process step after ash has been calcined. Testing with full-scale containers was performed using ash surrogates and a muffle furnace similar to that planned for use at RFETS. Small-scale testing was performed using plutonium-bearing incinerator ash to verify performance of the waste form. Ash was not obtained from RFETS because of transportation requirements to calcine the incinerator ash prior to shipment of the material. Because part of PNNL's work was to characterize the ash prior to calcination and to investigate the effect of calcination on product quality, representative material was obtained from LANL. Ash obtained from LANL was selected based on its similarity to that currently stored at RFETS. The plutonium-bearing ashes obtained from LANL are likely from a RFETS incinerator, but the exact origin was not identified.

  16. Volume reduction and vitrification of nuclear waste with thermal plasma

    SciTech Connect (OSTI)

    Hoffelner, W. [Moser-Glaser and Co., Muttenz (Switzerland); Chrubasik, A. [NUKEM GmbH, Alzenau (Germany); Eschenbach, R.C. [RETECH Inc., Ukiah, CA (United States)

    1993-12-31T23:59:59.000Z

    A process for efficient and safe destruction of organics and vitrification of low/medium level radioactive waste is presented. A transferred arc plasma torch is employed as the heat source. The process handles several types of feed: combustibles, inorganic materials and metals. A non-leaching glassy solid which can be stored without further treatment is obtained as the final product. High volume-reduction factors can be achieved with this process. A wet gas cleaning system leads to extremely clean off-gas.

  17. Bulk Viscosity of Interacting Hadrons

    E-Print Network [OSTI]

    A. Wiranata; M. Prakash

    2009-09-16T23:59:59.000Z

    We show that first approximations to the bulk viscosity $\\eta_v$ are expressible in terms of factors that depend on the sound speed $v_s$, the enthalpy, and the interaction (elastic and inelastic) cross section. The explicit dependence of $\\eta_v$ on the factor $(\\frac 13 - v_s^2)$ is demonstrated in the Chapman-Enskog approximation as well as the variational and relaxation time approaches. The interesting feature of bulk viscosity is that the dominant contributions at a given temperature arise from particles which are neither extremely nonrelativistic nor extremely relativistic. Numerical results for a model binary mixture are reported.

  18. Corrosion assessment of refractory materials for high temperature waste vitrification

    SciTech Connect (OSTI)

    Marra, J.C.; Congdon, J.W.; Kielpinski, A.L. [and others

    1995-11-01T23:59:59.000Z

    A variety of vitrification technologies are being evaluated to immobilize radioactive and hazardous wastes following years of nuclear materials production throughout the Department of Energy (DOE) complex. The compositions and physical forms of these wastes are diverse ranging from inorganic sludges to organic liquids to heterogeneous debris. Melt and off-gas products can be very corrosive at the high temperatures required to melt many of these waste streams. Ensuring material durability is required to develop viable treatment processes. Corrosion testing of materials in some of the anticipated severe environments is an important aspect of the materials identification and selection process. Corrosion coupon tests on typical materials used in Joule heated melters were completed using glass compositions with high salt contents. The presence of chloride in the melts caused the most severe attack. In the metal alloys, oxidation was the predominant corrosion mechanism, while in the tested refractory material enhanced dissolution of the refractory into the glass was observed. Corrosion testing of numerous different refractory materials was performed in a plasma vitrification system using a surrogate heterogeneous debris waste. Extensive corrosion was observed in all tested materials.

  19. Glass formulation for phase 1 high-level waste vitrification

    SciTech Connect (OSTI)

    Vienna, J.D.; Hrma, P.R.

    1996-04-01T23:59:59.000Z

    The purpose of this study is to provide potential glass formulations for prospective Phase 1 High-Level Waste (HLW) vitrification at Hanford. The results reported here will be used to aid in developing a Phase 1 HLW vitrification request for proposal (RFP) and facilitate the evaluation of ensuing proposals. The following factors were considered in the glass formulation effort: impact on total glass volume of requiring the vendor to process each of the tank compositions independently versus as a blend; effects of imposing typical values of B{sub 2}O{sub 3} content and waste loading in HLW borosilicate glasses as restrictions on the vendors (according to WAPS 1995, the typical values are 5--10 wt% B{sub 2}O{sub 3} and 20--40 wt% waste oxide loading); impacts of restricting the processing temperature to 1,150 C on eventual glass volume; and effects of caustic washing on any of the selected tank wastes relative to glass volume.

  20. Defense waste vitrification studies during FY-1981. Summary report

    SciTech Connect (OSTI)

    Bjorklund, W.J. (comp.)

    1982-09-01T23:59:59.000Z

    Both simulated alkaline defense wastes and simulated acidic defense wastes (formed by treating alkaline waste with formic acid) were successfully vitrified in direct liquid-fed melter experiments. The vitrification process was improved while using the formate-treated waste. Leach resistance was essentially the same. Off-gas entrainment was the primary mechanism for material exiting the melter. When formate waste was vitrified, the flow behavior of the off gas from the melter changed dramatically from an erratic surging behavior to a more quiet, even flow. Hydrogen and CO were detectable while processing formate feed; however, levels exceeding the flamability limits in air were never approached. Two types of melter operation were tested during the year, one involving boost power. Several boosting methods located within the melter plenum were tested. When lid heating was being used, water spray cooling in the off gas was required. Countercurrent spray cooling was more effective than cocurrent spray cooling. Materials of construction for the off-gas system were examined. Inconel-690 is preferred in the plenum area. Inspection of the pilot-scale melter found that corrosion of the K-3 refractory and Inconel-690 electrodes was minimal. An overheating incident occurred with the LFCM in which glass temperatures up to 1480/sup 0/C were experienced. Lab-scale vitrification tests to study mercury behavior were also completed this year. 53 figures, 63 tables.

  1. In situ vitrification model development and implementation plan

    SciTech Connect (OSTI)

    MacKinnon, R.J.; Murray, P.E.; Johnson, R.W.; Hagrman, D.L.; Slater, C.E.; Marwil, E.S.

    1990-08-01T23:59:59.000Z

    This document describes the In Situ Vitrification (ISV) Analysis Package being developed at the INEL to provide analytical support for (ISV) safety analysis and treatment performance predictions. Mathematical models and features which comprise this analysis package are presented and the proposed approach to model development and implementation is outlined. The objective of this document is two fold: to define preliminary design information and modeling objectives so that ISV modeling personnel can effectively modify existing models and formulate new models which are consistent with the objectives of the ISV treatability study and to provide sufficient technical information for internal and external reviewers to detect any shortcomings in model development and implementation plans. 27 refs., 17 figs., 3 tabs.

  2. LFCM (liquid-fed ceramic melter) vitrification technology: Quarterly progress report, January--March 1987

    SciTech Connect (OSTI)

    Brouns, R. A.; Allen, C. R.; Powell, J. A. (comps.)

    1988-05-01T23:59:59.000Z

    This report is compiled by the Nuclear Waste Treatment Program and the Hanford Waste Vitrification Program at Pacific Northwest Laboratory to describe the progress in developing, testing, applying and documenting liquid-fed ceramic melter vitrification technology. Progress in the following technical subject areas during the second quarter of FY 1987 is discussed: melting process chemistry and glass development, feed preparation and transfer systems, melter systems, canister filling and handling systems, and process/product modeling. 23 refs., 14 figs., 10 tabs.

  3. Comparison of conventional freezing and vitrification for cryopreservation of equine embryos

    E-Print Network [OSTI]

    Bruemmer, Jason Edward

    1991-01-01T23:59:59.000Z

    COMPARISON OF CONVENTIONAL FREEZING AND VITRIFICATION FOR CRYOPRESERVATION OF EQUINE EMBRYOS A Thesis by JASON EDWARD BRUEMMER Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements... for the degree of MASTER OF SCIENCE May 1991 Major Subject: Physiology of Reproduction COMPARISON OF CONVENTIONAL FREEZING AND VITRIFICATION FOR CRYOPRESERVATION OF EQUINE EMBRYOS A Thesis by JASON EDWARD BRUEMMER Approved as to style and content by: J...

  4. LFCM (liquid-fed ceramic melter) vitrification technology: Quarterly progress report, April-June 1986

    SciTech Connect (OSTI)

    Burkholder, H.C.; Allen, C.R. (comps.)

    1987-02-01T23:59:59.000Z

    This report is compiled by the Nuclear Waste Treatment Program and the Hanford Waste Vitrification Program at Pacific Northwest Laboratory to document progress on liquid-fed ceramic melter (LFCM) vitrification technology. Progress in the following technical subject areas during the third quarter of FY 1986 is discussed: melting process chemistry and glass development, feed preparation and transfer systems, melter systems, canister filling and handling systems, off-gas systems, and process/product modeling and control.

  5. Processing constraints on high-level nuclear waste glasses for Hanford Waste Vitrification Plant

    SciTech Connect (OSTI)

    Hrma, P. [Pacific Northwest Lab., Richland, WA (United States)

    1993-12-31T23:59:59.000Z

    The work presented in this paper is a part of a major technology program supported by the US Department of Energy (DOE) in preparation for the planned operation of the Hanford Waste Vitrification Plant (HWVP). Because composition of Hanford waste varies greatly, processability is a major concern for successful vitrification. This paper briefly surveys general aspects of waste glass processability and then discusses their ramifications for specific examples of Hanford waste streams.

  6. Vitrification of noble metals containing NCAW simulant with an engineering scale melter (ESM): Campaign report

    SciTech Connect (OSTI)

    Grunewald, W.; Roth, G.; Tobie, W.; Weisenburger, S.; Weiss, K.; Elliott, M.; Eyler, L.L.

    1996-03-01T23:59:59.000Z

    ESM has been designed as a 10th-scale model of the DWPF-type melter, currently the reference melter for nitrification of Hanford double shell tankwaste. ESM and related equipment have been integrated to the existing mockup vitrification plant VA-WAK at KfK. On June 2-July 10, 1992, a shakedown test using 2.61 m{sup 3} of NCAW (neutralized current acid waste) simulant without noble metals was performed. On July 11-Aug. 30, 1992, 14.23 m{sup 3} of the same simulant with nominal concentrations of Ru, Rh, and Pd were vitrified. Objective was to investigate the behavior of such a melter with respect to discharge of noble metals with routine glass pouring via glass overflow. Results indicate an accumulation of noble metals in the bottom area of the flat-bottomed ESM. About 65 wt% of the noble metals fed to the melter could be drained out, whereas 35 wt% accumulated in the melter, based on analysis of glass samples from glass pouring stream in to the canisters. After the melter was drained at the end of the campaign through a bottom drain valve, glass samples were taken from the residual bottom layer. The samples had significantly increased noble metals content (factor of 20-45 to target loading). They showed also a significant decrease of the specific electric resistance compared to bulk glass (factor of 10). A decrease of 10- 15% of the resistance between he power electrodes could be seen at the run end, but the total amount of noble metals accumulated was not yet sufficient enough to disturb the Joule heating of the glass tank severely.

  7. Bulk viscosity and r-modes of neutron stars

    E-Print Network [OSTI]

    Debarati Chatterjee; Debades Bandyopadhyay

    2008-08-08T23:59:59.000Z

    The bulk viscosity due to the non-leptonic process involving hyperons in $K^-$ condensed matter is discussed here. We find that the bulk viscosity is modified in a superconducting phase. Further, we demonstrate how the exotic bulk viscosity coefficient influences $r$-modes of neutron stars which might be sources of detectable gravitational waves.

  8. Release model for in situ vitrification large-field test off-gas treatment system

    SciTech Connect (OSTI)

    Pafford, D.J.; Tung, V.X.

    1992-03-01T23:59:59.000Z

    A conceptual model for the vapor and aerosol transport and deposition in the in situ vitrification large-field test off-gas system (OGS) has been developed. This model can be used to predict the emissions from the OGS under normal and off-normal conditions. Results generated by the model can be used to evaluate design and/or procedural modifications, define tests, and predict results. The OGS vapor and aerosol transport and deposition is modeled using the PULSE/MOD-ISV/VER 1.0.0 developmental computer code. Input data requirements for this code include the specific geometries of the OGS components; the composition, rate, and temperature of the vapors and aerosols entering the OGS; and the OGS component surface temperatures or heat fluxes. Currently, not all of these model inputs are available. Therefore, conceptual input parameters are developed. Using this input data, preliminary calculations with the code have been performed. These calculations include a demonstration that the code predicts convergent results, a comparison of predicted results with performance data for one of the OGS components, and a preliminary sensitivity study of the complete model.

  9. Vitrification and testing of a Hanford high-level waste sample. Part 1: Glass fabrication, and chemical and radiochemical analysis

    SciTech Connect (OSTI)

    Hrma, Pavel R.; Crum, Jarrod V.; Bates, Derrick J.; Bredt, Paul; Greenwood, Lawrence R.; Smith, H D.

    2005-10-01T23:59:59.000Z

    The Hanford radioactive tank waste will be separated into low-activity waste and high-level waste that will both be vitrified into borosilicate glasses. To demonstrate the feasibility of vitrification and the durability of the high-level waste glass, a high-level waste sample from Tank AZ-101 was processed to glass in a hot cell and analyzed with respect to chemical composition, radionuclide content, waste loading, and the presence of crystalline phases and then tested for leachability. The glass was analyzed with inductively coupled plasma-atomic emission spectroscopy, inductively coupled plasma-mass spectrometry, ? energy spectrometry, ? spectrometry, and liquid scintillation counting. The WISE Uranium Project calculator was used to calculate the main sources of radioactivity to the year 3115. The observed crystallinity and the results of leachability testing of the glass will be reported in Part 2 of this paper.

  10. GATEWAY Demonstrations

    Broader source: Energy.gov [DOE]

    DOE GATEWAY demonstrations showcase high-performance LED products for general illumination in a variety of commercial and residential applications. Demonstration results provide real-world experience and data on state-of-the-art solid-state lighting (SSL) product performance and cost effectiveness. These results connect DOE technology procurement efforts with large-volume purchasers and provide buyers with reliable data on product performance.

  11. Large area bulk superconductors

    DOE Patents [OSTI]

    Miller, Dean J. (Darien, IL); Field, Michael B. (Jersey City, NJ)

    2002-01-01T23:59:59.000Z

    A bulk superconductor having a thickness of not less than about 100 microns is carried by a polycrystalline textured substrate having misorientation angles at the surface thereof not greater than about 15.degree.; the bulk superconductor may have a thickness of not less than about 100 microns and a surface area of not less than about 50 cm.sup.2. The textured substrate may have a thickness not less than about 10 microns and misorientation angles at the surface thereof not greater than about 15.degree.. Also disclosed is a process of manufacturing the bulk superconductor and the polycrystalline biaxially textured substrate material.

  12. Use of noninvasive geophysical techniques for the in situ vitrification program

    SciTech Connect (OSTI)

    Josten, N.E.; Marts, S.T.; Carpenter, G.S.

    1991-11-01T23:59:59.000Z

    In situ vitrification (ISV) is a waste pit remediation technology that can potentially eliminate the need for pit excavation. The ISV program at the Idaho National Engineering Laboratory (INEL) funded this study to evaluate geophysical techniques that might be useful for performing detailed screening of the materials, soil conditions, and local geology of waste pits targeted for remediation. The evaluation focusses on a specific set of characterization objectives developed by ISV engineers. The objectives are based on their assessment of safety, environmental, and cost efficiency issues associated with the ISV process. A literature review of geophysical case histories was conducted and a geophysical survey was performed at the INEL simulated waste pit so that the evaluation could be based on demonstrable results. The literature review shows that all the ISV objectives are theoretically achievable because they involve physical properties (such as electrical conductivity, density, or magnetization) that can be sensed by geophysical instruments. However, most of the ISV objectives require substantially higher resolution than is achieved in typical waste site investigations, or than has been demonstrated by researches using state-of-the-art techniques. The survey at the INEL simulated waste pit yielded useful, qualitative information on subsurface materials and boundaries; but quantitative information, such as depth, size, or composition of buried materials, was subject to significant uncertainty. For ISV, the usefulness of geophysical characterization depends both on the capabilities of geophysical methods and on an assessment of the amount of uncertainty that is acceptable. Based on a preliminary assessment of these factors, the location of trench boundaries and detection of massive metallic objects are the important achievable objectives using current technology.

  13. Use of noninvasive geophysical techniques for the in situ vitrification program. Volume 3, Discussion and recommendations

    SciTech Connect (OSTI)

    Josten, N.E.; Marts, S.T.; Carpenter, G.S.

    1991-11-01T23:59:59.000Z

    In situ vitrification (ISV) is a waste pit remediation technology that can potentially eliminate the need for pit excavation. The ISV program at the Idaho National Engineering Laboratory (INEL) funded this study to evaluate geophysical techniques that might be useful for performing detailed screening of the materials, soil conditions, and local geology of waste pits targeted for remediation. The evaluation focusses on a specific set of characterization objectives developed by ISV engineers. The objectives are based on their assessment of safety, environmental, and cost efficiency issues associated with the ISV process. A literature review of geophysical case histories was conducted and a geophysical survey was performed at the INEL simulated waste pit so that the evaluation could be based on demonstrable results. The literature review shows that all the ISV objectives are theoretically achievable because they involve physical properties (such as electrical conductivity, density, or magnetization) that can be sensed by geophysical instruments. However, most of the ISV objectives require substantially higher resolution than is achieved in typical waste site investigations, or than has been demonstrated by researches using state-of-the-art techniques. The survey at the INEL simulated waste pit yielded useful, qualitative information on subsurface materials and boundaries; but quantitative information, such as depth, size, or composition of buried materials, was subject to significant uncertainty. For ISV, the usefulness of geophysical characterization depends both on the capabilities of geophysical methods and on an assessment of the amount of uncertainty that is acceptable. Based on a preliminary assessment of these factors, the location of trench boundaries and detection of massive metallic objects are the important achievable objectives using current technology.

  14. Hanford Waste Vitrification program pilot-scale ceramic melter Test 23

    SciTech Connect (OSTI)

    Goles, R.W.; Nakaoka, R.K.

    1990-02-01T23:59:59.000Z

    The pilot-scale ceramic melter test, was conducted to determine the vitrification processing characteristics of simulated Hanford Waste Vitrification Plant process slurries and the integrated performance of the melter off-gas treatment system. Simulated melter feed was prepared and processed to produce glass. The vitrification system, achieved an on-stream efficiency of greater than 98%. The melter off-gas treatment system included a film cooler, submerged bed scrubber, demister, high-efficiency mist eliminator, preheater, and high-efficiency particulate air filter (HEPA). Evaluation of the off-gas system included the generation, nature, and capture efficiency of gross particulate, semivolatile, and noncondensible melter products. 17 refs., 48 figs., 61 tabs.

  15. System for enhanced destruction of hazardous wastes by in situ vitrification of soil

    DOE Patents [OSTI]

    Timmerman, Craig L. (Richland, WA)

    1991-01-01T23:59:59.000Z

    The present invention comprises a system for promoting the destruction of volatile and/or hazardous contaminants present in waste materials during in situ vitrification processes. In accordance with the present invention, a cold cap (46) comprising a cohesive layer of resolidified material is formed over the mass of liquefied soil and waste (40) present between and adjacent to the electrodes (10, 12, 14, 16) during the vitrification process. This layer acts as a barrier to the upward migration of any volatile type materials thereby increasing their residence time in proximity to the heated material. The degree of destruction of volatile and/or hazardous contaminants by pyrolysis is thereby improved during the course of the vitrification procedure.

  16. Interaction analysis method for the Hanford Waste Vitrification Plant

    SciTech Connect (OSTI)

    Grant, P.R.; Deshotels, R.L. [Fluor Daniel, Inc., Irvine, CA (United States); Van Katwijk, C. [Westinghouse Hanford Co., Richland, WA (United States)

    1993-08-01T23:59:59.000Z

    In order to anticipate potential problems as early as possible during the design effort, a method for interaction analysis was developed to meet the specific hazards of the Hanford Waste Vitrification Plant (HWVP). The requirement for interaction analysis is given in DOE Order 6430.1B and DOE-STD-1021-92. The purpose of the interaction analysis is to ensure that non-safety class items will not fail in a manner that will adversely affect the ability of any safety class item to perform its safety function. In the HWVP there are few structures, equipment, or controls that are safety class. In addition to damage due to failure of non-safety class items as a result of natural phenomena, threats to HWVP safety class items include the following: room flooding from firewater, leakage of chemically reactive liquids, high-pressure gas impingement from leaking piping, rocket-type impact from broken pressurized gas cylinders, loss of control of mobile equipment, cryogenic liquid spill, fire, and smoke. The time needed to perform the interaction analysis is minimized by consolidating safety class items into segregated areas. Each area containing safety class items is evaluated, and any potential threat to the safety functions is noted. After relocation of safety class items is considered, items that pose a threat are generally upgraded to eliminate the threat to the safety class items. Upgrading is the preferred option when relocation is not possible. An example will illustrate the method and application in the phased design, procurement, and construction environment of the HWVP.

  17. Flammability Control In A Nuclear Waste Vitrification System

    SciTech Connect (OSTI)

    Zamecnik, John R.; Choi, Alexander S.; Johnson, Fabienne C.; Miller, Donald H.; Lambert, Daniel P.; Stone, Michael E.; Daniel, William E. Jr.

    2013-07-25T23:59:59.000Z

    The Defense Waste Processing Facility at the Savannah River Site processes high-level radioactive waste from the processing of nuclear materials that contains dissolved and precipitated metals and radionuclides. Vitrification of this waste into borosilicate glass for ultimate disposal at a geologic repository involves chemically modifying the waste to make it compatible with the glass melter system. Pretreatment steps include removal of excess aluminum by dissolution and washing, and processing with formic and nitric acids to: 1) adjust the reduction-oxidation (redox) potential in the glass melter to reduce radionuclide volatility and improve melt rate; 2) adjust feed rheology; and 3) reduce by steam stripping the amount of mercury that must be processed in the melter. Elimination of formic acid in pretreatment has been studied to eliminate the production of hydrogen in the pretreatment systems, which requires nuclear grade monitoring equipment. An alternative reductant, glycolic acid, has been studied as a substitute for formic acid. However, in the melter, the potential for greater formation of flammable gases exists with glycolic acid. Melter flammability is difficult to control because flammable mixtures can be formed during surges in offgases that both increase the amount of flammable species and decrease the temperature in the vapor space of the melter. A flammable surge can exceed the 60% of the LFL with no way to mitigate it. Therefore, careful control of the melter feed composition based on scaled melter surge testing is required. The results of engineering scale melter tests with the formic-nitric flowsheet and the use of these data in the melter flammability model are presented.

  18. Preliminary Glass Development and Testing for In-Container Vitrification of Hanford Low-Activity Waste

    SciTech Connect (OSTI)

    Vienna, John D.; Kim, Dong-Sang; Schweiger, Michael J.; Hrma, Pavel R.; Matyas, Josef; Crum, Jarrod V.; Smith, Donald E.

    2004-01-01T23:59:59.000Z

    Roughly 50 million gallons of high-level waste (HLW) are stored at the Hanford site. This waste will be separated into HLW and low-activity waste (LAW) fractions and each fraction will be immobilized for final storage/disposal. The US Department of Energy (DOE) Office of River Protection (ORP) is constructing a Waste Treatment and Immobilization Plant (WTP) which will be capable of separating the waste, vitrifying the entire HLW fraction of the waste and vitrifying roughly 50% the LAW fraction. The remaining fraction of LAW will be immobilized by one of a number of possible technologies. ORP is currently evaluating options for LAW immobilization. One possible option is In-Container Vitrification (ICV) of the LAW. ICV is a technology developed by AMEC, GeoMelt Division, for treatment of hazardous, radioactive, and mixed wastes. The ICV process, as applied to Hanford LAW, includes the blending of liquid waste with additives (primarily composed of local soil) and drying to a granular state. The dried material is loaded into a refractory lined steel box and melted by passing a current through the material between two graphite electrodes. The box containing the molten waste/additive mixture is cooled, backfilled, and disposed of. The purpose of the study was to develop a glass composition suitable for the demonstration of ICV on Hanford LAW at full scale. Testing included crucible-scale tests with simulants and actual Hanford LAW. Following the crucible-scale tests, engineering-scale and large-scale melts were performed with LAW simulants. This paper discusses the formulation and testing of glass compositions for ICV of Hanford LAW at crucible scale. The results from process scale-up test are reported elsewhere.

  19. NEXT GENERATION MELTER(S) FOR VITRIFICATION OF HANFORD WASTE STATUS AND DIRECTION

    SciTech Connect (OSTI)

    RAMSEY WG; GRAY MF; CALMUS RB; EDGE JA; GARRETT BG

    2011-01-13T23:59:59.000Z

    Vitrification technology has been selected to treat high-level waste (HLW) at the Hanford Site, the West Valley Demonstration Project and the Savannah River Site (SRS), and low activity waste (LAW) at Hanford. In addition, it may potentially be applied to other defense waste streams such as sodium bearing tank waste or calcine. Joule-heated melters (already in service at SRS) will initially be used at the Hanford Site's Waste Treatment and Immobilization Plant (WTP) to vitrify tank waste fractions. The glass waste content and melt/production rates at WTP are limited by the current melter technology. Significant reductions in glass volumes and mission life are only possible with advancements in melter technology coupled with new glass formulations. The Next Generation Melter (NGM) program has been established by the U.S. Department of Energy's (DOE's), Environmental Management Office of Waste Processing (EM-31) to develop melters with greater production capacity (absolute glass throughput rate) and the ability to process melts with higher waste fractions. Advanced systems based on Joule-Heated Ceramic Melter (JHCM) and Cold Crucible Induction Melter (CCIM) technologies will be evaluated for HLW and LAW processing. Washington River Protection Solutions (WRPS), DOE's tank waste contractor, is developing and evaluating these systems in cooperation with EM-31, national and university laboratories, and corporate partners. A primary NGM program goal is to develop the systems (and associated flowsheets) to Technology Readiness Level 6 by 2016. Design and testing are being performed to optimize waste glass process envelopes with melter and balance of plant requirements. A structured decision analysis program will be utilized to assess the performance of the competing melter technologies. Criteria selected for the decision analysis program will include physical process operations, melter performance, system compatibility and other parameters.

  20. Bulk Power Transmission Study

    E-Print Network [OSTI]

    John, T.

    BULK POWER TRANSMISSION STUDY TOMMY JOH~ P. E. Manager of Resource Recovery Waste Management of North America, Inc. Houston, Texas Texans now have a choice. We can become more efficient and maintain our standard of living, or we can... continue business as usual and watch our standard of living erode from competition from other regions. In the past, except for improving reliability, there was no need for a strong transmission system. When Texas generation was primarily gas fueled...

  1. R and D Programs and Policy within the CEA-AREVA Joint Vitrification Lab (LCV) - 13592

    SciTech Connect (OSTI)

    Piroux, Jean Christophe [AREVA NC Marcoule LCV (France)] [AREVA NC Marcoule LCV (France); Paradis, Luc; Ladirat, Christian [CEA Marcoule LCV (France)] [CEA Marcoule LCV (France); Brueziere, Jerome; Chauvin, Eric [AREVA NC Paris La Defense (France)] [AREVA NC Paris La Defense (France)

    2013-07-01T23:59:59.000Z

    Waste management is a key issue for the reprocessing industry; furthermore, vitrification is considered as the reference for nuclear waste management. In order to further improve and strengthen their historical cooperation in high temperature waste management, the CEA, R and D organization, and AREVA, Industrial Operator, decided, in September 2010, to create a Joint Vitrification Laboratory within the framework of a strategic partnership. The main objectives of the CEA-AREVA Joint Vitrification Laboratory (LCV) are (i) support AREVA's activities, notably in its La Hague plants and for new projects, (ii) strengthen the CEA's lead as a reference laboratory in the field of waste conditioning. The LCV is mandated to provide strong, innovative solutions through the performance of R and D on processes and materials for vitrification, fusion and incineration, for high, intermediate and low level waste. The activities carried out in the LCV include academic research on containment matrices (formulation, long-term behaviour), and the improvement of current technologies/development of new ones in lab-scale to full-scale pilot facilities, in non-radioactive and radioactive conditions, including modelling and experimental tools. This paper focuses on the programs and policy managed within the LCV, as well as the means employed by the CEA and AREVA to meet common short-,mid- and long-term challenges, from a scientific and industrial point of view. Among other things, we discuss the technical support provided for the La Hague vitrification facilities on hot melter and CCIM technologies, the start-up of new processes (decommissioning effluents, UMo FP) with CCIM, the preparation of future processes by means of an assessment of new technologies and containment matrices (improved glasses, ceramics, etc.), as well as incineration/vitrification for organic and metallic mixed waste or metallic fusion. The close relationship between the R and D teams and industrial operators enables the LCV to propose attractive waste management solutions, with appropriate schedules and optimized development costs, making allowance for R and D constraints, engineering requirements and the industrial environment. (authors)

  2. Photonic integration in a commercial scaled bulk-CMOS process

    E-Print Network [OSTI]

    Kaertner, Franz X.

    We demonstrate the first photonic chip designed for a commercial bulk CMOS process (65 nm-node) using standard process layers combined with post-processing, enabling dense photonic integration with high-performance ...

  3. High temperature materials for radioactive waste incineration and vitrification. Revision 1

    SciTech Connect (OSTI)

    Bickford, D F; Ondrejcin, R S; Salley, L

    1986-01-01T23:59:59.000Z

    Incineration or vitrification of radioactive waste subjects equipment to alkaline or acidic fluxing, oxidation, sulfidation, carburization, and thermal shock. It is necessary to select appropriate materials of construction and control operating conditions to avoid rapid equipment failure. Nickel- and cobalt-based alloys with high chromium or aluminum content and aluminum oxide/chromium oxide refractories with high chromium oxide content have provided the best service in pilot-scale melter tests. Inconel 690 and Monofrax K-3 are being used for waste vitrification. Haynes 188 and high alumina refractory are undergoing pilot scale tests for incineration equipment. Laboratory tests indicate that alloys and refractories containing still higher concentrations of chromium or chromium oxide, such as Inconel 671 and Monofrax E, may provide superior resistance to attack in glass melter environments.

  4. Vitrification of ion-exchange (IEX) resins: Advantages and technical challenges

    SciTech Connect (OSTI)

    Jantzen, C.M.; Peeler, D.K.; Cicero, C.A.

    1995-12-31T23:59:59.000Z

    Technologies are being developed by the US Department of Energy`s (DOE) Savannah River Site (SRS) in conjunction with the Electric Power Research Institute (EPRI) and the commercial sector to convert low-level radioactive ion exchange (IEX) resin wastes from the nuclear utilities to solid stabilized waste forms for permanent disposal. One of the alternative waste stabilization technologies is vitrification of the resin into glass. Wastes can be vitrified at elevated temperatures by thermal treatment. One alternative thermal treatment is conventional Joule heated melting. Vitrification of wastes into glass is an attractive option because it atomistically bonds both hazardous and radioactive species in the glass structure, and volume reduces the wastes by 70-80%. The large volume reductions allow for large associated savings in disposal and/or long term storage costs.

  5. Hanford tank waste simulants specification and their applicability for the retrieval, pretreatment, and vitrification processes

    SciTech Connect (OSTI)

    GR Golcar; NG Colton; JG Darab; HD Smith

    2000-04-04T23:59:59.000Z

    A wide variety of waste simulants were developed over the past few years to test various retrieval, pretreatment and waste immobilization technologies and unit operations. Experiments can be performed cost-effectively using non-radioactive waste simulants in open laboratories. This document reviews the composition of many previously used waste simulants for remediation of tank wastes at the Hanford reservation. In this review, the simulants used in testing for the retrieval, pretreatment, and vitrification processes are compiled, and the representative chemical and physical characteristics of each simulant are specified. The retrieval and transport simulants may be useful for testing in-plant fluidic devices and in some cases for filtration technologies. The pretreatment simulants will be useful for filtration, Sr/TRU removal, and ion exchange testing. The vitrification simulants will be useful for testing melter, melter feed preparation technologies, and for waste form evaluations.

  6. Selection of melter systems for the DOE/Industrial Center for Waste Vitrification Research

    SciTech Connect (OSTI)

    Bickford, D.F.

    1993-12-31T23:59:59.000Z

    The EPA has designated vitrification as the best developed available technology for immobilization of High-Level Nuclear Waste. In a recent federal facilities compliance agreement between the EPA, the State of Washington, and the DOE, the DOE agreed to vitrify all of the Low Level Radioactive Waste resulting from processing of High Level Radioactive Waste stored at the Hanford Site. This is expected to result in the requirement of 100 ton per day Low Level Radioactive Waste melters. Thus, there is increased need for the rapid adaptation of commercial melter equipment to DOE`s needs. DOE has needed a facility where commercial pilot scale equipment could be operated on surrogate (non-radioactive) simulations of typical DOE waste streams. The DOE/Industry Center for Vitrification Research (Center) was established in 1992 at the Clemson University Department of Environmental Systems Engineering, Clemson, SC, to address that need. This report discusses some of the characteristics of the melter types selected for installation of the Center. An overall objective of the Center has been to provide the broadest possible treatment capability with the minimum number of melter units. Thus, units have been sought which have broad potential application, and which had construction characteristics which would allow their adaptation to various waste compositions, and various operating conditions, including extreme variations in throughput, and widely differing radiological control requirements. The report discusses waste types suitable for vitrification; technical requirements for the application of vitrification to low level mixed wastes; available melters and systems; and selection of melter systems. An annotated bibliography is included.

  7. Development of Vitrification Process and Glass Formulation for Nuclear Waste Conditioning

    SciTech Connect (OSTI)

    Petitjean, V.; Fillet, C.; Boen, R.; Veyer, C.; Flament, T.

    2002-02-26T23:59:59.000Z

    The vitrification of high-level waste is the internationally recognized standard to minimize the impact to the environment resulting from waste disposal as well as to minimize the volume of conditioned waste to be disposed of. COGEMA has been vitrifying high-level waste industrially for over 20 years and is currently operating three commercial vitrification facilities based on a hot metal crucible technology, with outstanding records of safety, reliability and product quality. To further increase the performance of vitrification facilities, CEA and COGEMA have been developing the cold crucible melter technology since the beginning of the 1980s. This type of melter is characterized by a virtually unlimited equipment service life and a great flexibility in dealing with various types of waste and allowing development of high temperature matrices. In complement of and in parallel with the vitrification process, a glass formulation methodology has been developed by the CEA in order to tailor matrices for the wastes to be conditioned while providing the best adaptation to the processing technology. The development of a glass formulation is a trade-off between material properties and qualities, technical feasibility, and disposal safety criteria. It involves non-radioactive and radioactive laboratories in order to achieve a comprehensive matrix qualification. Several glasses and glass ceramics have thus been studied by the CEA to be compliant with industrial needs and waste characteristics: glasses or other matrices for a large spectrum of fission products, or for high contents of specifics elements such as sodium, phosphate, iron, molybdenum, or actinides. New glasses or glass-ceramics designed to minimize the final wasteform volume for solutions produced during the reprocessing of high burnup fuels or to treat legacy wastes are now under development and take benefit from the latest CEA hot-laboratories and technology development. The paper presents the CEA state-of-the-art in developing matrices or glasses and provides several examples.

  8. SRS vitrification studies in support of the U.S. program for disposition of excess plutonium

    SciTech Connect (OSTI)

    Wicks, G.G.; McKibben, J.M.; Plodinec, M.J.; Ramsey, W.G.

    1995-09-01T23:59:59.000Z

    Many thousands of nuclear weapons are being retired in the U.S. and Russian as a result of nuclear disarmament activities. These efforts are expected to produce a surplus of about 50 MT of weapons grade plutonium (Pu) in each country. In addition to this inventory, the U.S. Department of Energy (DOE) has more than 20 MT of Pu scrap, residue, etc., and Russian is also believed to have at least as much of this type of material. The entire surplus Pu inventories in the U.S. and Russian present a clear and immediate danger to national and international security. It is important that a solution be found to secure and manage this material effectively and that such an effort be implemented as quickly as possible. One option under consideration is vitrification of Pu into a safe, durable, accountable and proliferation-resistant form. As a result of decades to experience within the DOE community involving vitrification of a variety of hazardous and radioactive wastes, this existing technology can now be expanded to include mobilization of large amounts of Pu. This technology can then be implemented rapidly using the many existing resources currently available. An overall strategy to vitrify many different types of Pu will be already developed throughout the waste management community can be used in a staged Pu vitrification effort. This approach uses the flexible vitrification technology already available and can even be made portable so that it may be brought to the source and ultimately, used to produce a consistent and common borosilicate glass composition for the vitrified Pu. The final composition of this product can be made similar to nationally and internationally accepted HLW glasses.

  9. Tank Waste Remediation System tank waste pretreatment and vitrification process development testing requirements assessment

    SciTech Connect (OSTI)

    Howden, G.F.

    1994-10-24T23:59:59.000Z

    A multi-faceted study was initiated in November 1993 to provide assurance that needed testing capabilities, facilities, and support infrastructure (sampling systems, casks, transportation systems, permits, etc.) would be available when needed for process and equipment development to support pretreatment and vitrification facility design and construction schedules. This first major report provides a snapshot of the known testing needs for pretreatment, low-level waste (LLW) and high-level waste (HLW) vitrification, and documents the results of a series of preliminary studies and workshops to define the issues needing resolution by cold or hot testing. Identified in this report are more than 140 Hanford Site tank waste pretreatment and LLW/HLW vitrification technology issues that can only be resolved by testing. The report also broadly characterizes the level of testing needed to resolve each issue. A second report will provide a strategy(ies) for ensuring timely test capability. Later reports will assess the capabilities of existing facilities to support needed testing and will recommend siting of the tests together with needed facility and infrastructure upgrades or additions.

  10. Vitrification as a low-level radioactive mixed waste treatment technology at Argonne National Laboratory

    SciTech Connect (OSTI)

    Mazer, J.J.; No, Hyo J.

    1995-08-01T23:59:59.000Z

    Argonne National Laboratory-East (ANL-E) is developing plans to use vitrification to treat low-level radioactive mixed wastes (LLMW) generated onsite. The ultimate objective of this project is to install a full-scale vitrification system at ANL-E capable of processing the annual generation and historic stockpiles of selected LLMW streams. This project is currently in the process of identifying a range of processible glass compositions that can be produced from actual mixed wastes and additives, such as boric acid or borax. During the formulation of these glasses, there has been an emphasis on maximizing the waste content in the glass (70 to 90 wt %), reducing the overall final waste volume, and producing a stabilized low-level radioactive waste glass. Crucible glass studies with actual mixed waste streams have produced alkali borosilicate glasses that pass the Toxic Characteristic Leaching Procedure (TCLP) test. These same glass compositions, spiked with toxic metals well above the expected levels in actual wastes, also pass the TCLP test. These results provide compelling evidence that the vitrification system and the glass waste form will be robust enough to accommodate expected variations in the LLMW streams from ANL-E. Approximately 40 crucible melts will be studied to establish a compositional envelope for vitrifying ANL-E mixed wastes. Also being determined is the identity of volatilized metals or off-gases that will be generated.

  11. Creating bulk nanocrystalline metal.

    SciTech Connect (OSTI)

    Fredenburg, D. Anthony (Georgia Institute of Technology, Atlanta, GA); Saldana, Christopher J. (Purdue University, West Lafayette, IN); Gill, David D.; Hall, Aaron Christopher; Roemer, Timothy John (Ktech Corporation, Albuquerque, NM); Vogler, Tracy John; Yang, Pin

    2008-10-01T23:59:59.000Z

    Nanocrystalline and nanostructured materials offer unique microstructure-dependent properties that are superior to coarse-grained materials. These materials have been shown to have very high hardness, strength, and wear resistance. However, most current methods of producing nanostructured materials in weapons-relevant materials create powdered metal that must be consolidated into bulk form to be useful. Conventional consolidation methods are not appropriate due to the need to maintain the nanocrystalline structure. This research investigated new ways of creating nanocrystalline material, new methods of consolidating nanocrystalline material, and an analysis of these different methods of creation and consolidation to evaluate their applicability to mesoscale weapons applications where part features are often under 100 {micro}m wide and the material's microstructure must be very small to give homogeneous properties across the feature.

  12. A COMPLETE HISTORY OF THE HIGH-LEVEL WASTE PLANT AT THE WEST VALLEY DEMONSTRATION PROJECT

    SciTech Connect (OSTI)

    Petkus, Lawrence L.; Paul, James; Valenti, Paul J.; Houston, Helene; May, Joseph

    2003-02-27T23:59:59.000Z

    The West Valley Demonstration Project (WVDP) vitrification melter was shut down in September 2002 after being used to vitrify High Level Waste (HLW) and process system residuals for six years. Processing of the HLW occurred from June 1996 through November 2001, followed by a program to flush the remaining HLW through to the melter. Glass removal and shutdown followed. The facility and process equipment is currently in a standby mode awaiting deactivation. During HLW processing operations, nearly 24 million curies of radioactive material were vitrified into 275 canisters of HLW glass. At least 99.7% of the curies in the HLW tanks at the WVDP were vitrified using the melter. Each canister of HLW holds approximately 2000 kilograms of glass with an average contact dose rate of over 2600 rem per hour. After vitrification processing ended, two more cans were filled using the Evacuated Canister Process to empty the melter at shutdown. This history briefly summarizes the initial stages of process development and earlier WVDP experience in the design and operation of the vitrification systems, followed by a more detailed discussion of equipment availability and failure rates during six years of operation. Lessons learned operating a system that continued to function beyond design expectations also are highlighted.

  13. Evaluation of alternative chemical additives for high-level waste vitrification feed preparation processing

    SciTech Connect (OSTI)

    Seymour, R.G.

    1995-06-07T23:59:59.000Z

    During the development of the feed processing flowsheet for the Defense Waste Processing Facility (DWPF) at the Savannah River Site (SRS), research had shown that use of formic acid (HCOOH) could accomplish several processing objectives with one chemical addition. These objectives included the decomposition of tetraphenylborate, chemical reduction of mercury, production of acceptable rheological properties in the feed slurry, and controlling the oxidation state of the glass melt pool. However, the DEPF research had not shown that some vitrification slurry feeds had a tendency to evolve hydrogen (H{sub 2}) and ammonia (NH{sub 3}) as the result of catalytic decomposition of CHOOH with noble metals (rhodium, ruthenium, palladium) in the feed. Testing conducted at Pacific Northwest Laboratory and later at the Savannah River Technical Center showed that the H{sub 2} and NH{sub 3} could evolve at appreciable rates and quantities. The explosive nature of H{sub 2} and NH{sub 3} (as ammonium nitrate) warranted significant mitigation control and redesign of both facilities. At the time the explosive gas evolution was discovered, the DWPF was already under construction and an immediate hardware fix in tandem with flowsheet changes was necessary. However, the Hanford Waste Vitrification Plant (HWVP) was in the design phase and could afford to take time to investigate flowsheet manipulations that could solve the problem, rather than a hardware fix. Thus, the HWVP began to investigate alternatives to using HCOOH in the vitrification process. This document describes the selection, evaluation criteria, and strategy used to evaluate the performance of the alternative chemical additives to CHOOH. The status of the evaluation is also discussed.

  14. Arc melter demonstration baseline test results

    SciTech Connect (OSTI)

    Soelberg, N.R.; Chambers, A.G.; Anderson, G.L.; Oden, L.L.; O`Connor, W.K.; Turner, P.C.

    1994-07-01T23:59:59.000Z

    This report describes the test results and evaluation for the Phase 1 (baseline) arc melter vitrification test series conducted for the Buried Waste Integrated Demonstration program (BWID). Phase 1 tests were conducted on surrogate mixtures of as-incinerated wastes and soil. Some buried wastes, soils, and stored wastes at the INEL and other DOE sites, are contaminated with transuranic (TRU) radionuclides and hazardous organics and metals. The high temperature environment in an electric arc furnace may be used to process these wastes to produce materials suitable for final disposal. An electric arc furnace system can treat heterogeneous wastes and contaminated soils by (a) dissolving and retaining TRU elements and selected toxic metals as oxides in the slag phase, (b) destroying organic materials by dissociation, pyrolyzation, and combustion, and (c) capturing separated volatilized metals in the offgas system for further treatment. Structural metals in the waste may be melted and tapped separately for recycle or disposal, or these metals may be oxidized and dissolved into the slag. The molten slag, after cooling, will provide a glass/ceramic final waste form that is homogeneous, highly nonleachable, and extremely durable. These features make this waste form suitable for immobilization of TRU radionuclides and toxic metals for geologic timeframes. Further, the volume of contaminated wastes and soils will be substantially reduced in the process.

  15. Commercial LFCM vitrification technology. Quarterly progress report, October-December 1984

    SciTech Connect (OSTI)

    Burkholder, H.C.; Jarrett, J.H. (comps.)

    1985-07-01T23:59:59.000Z

    This report is the first in a series of quarterly reports compiled by the Nuclear Waste Treatment Program Office at Pacific Northwest Laboratory to document progress on commercial liquid-fed ceramic melter (LFCM) vitrification technology. Progress in the following technical subject areas during the first quarter of FY 1985 is discussed: pretreatment systems, melting process chemistry, glass development and characterization, feed preparation and transfer systems, melter systems, canister filling and handling systems, off-gas systems, process/product modeling and control, and supporting studies. 33 figs., 12 tabs.

  16. Hanford Waste Vitrification Plant full-scale feed preparation testing with water and process simulant slurries

    SciTech Connect (OSTI)

    Gaskill, J.R.; Larson, D.E.; Abrigo, G.P. [and others] [and others

    1996-03-01T23:59:59.000Z

    The Hanford Waste Vitrification Plant was intended to convert selected, pretreated defense high-level waste and transuranic waste from the Hanford Site into a borosilicate glass. A full-scale testing program was conducted with nonradioactive waste simulants to develop information for process and equipment design of the feed-preparation system. The equipment systems tested included the Slurry Receipt and Adjustment Tank, Slurry Mix Evaporator, and Melter-Feed Tank. The areas of data generation included heat transfer (boiling, heating, and cooling), slurry mixing, slurry pumping and transport, slurry sampling, and process chemistry. 13 refs., 129 figs., 68 tabs.

  17. Critique of Hanford Waste Vitrification Plant off-gas sampling requirements

    SciTech Connect (OSTI)

    Goles, R.W.

    1996-03-01T23:59:59.000Z

    Off-gas sampling and monitoring activities needed to support operations safety, process control, waste form qualification, and environmental protection requirements of the Hanford Waste Vitrification Plant (HWVP) have been evaluated. The locations of necessary sampling sites have been identified on the basis of plant requirements, and the applicability of Defense Waste Processing Facility (DWPF) reference sampling equipment to these HWVP requirements has been assessed for all sampling sites. Equipment deficiencies, if present, have been described and the bases for modifications and/or alternative approaches have been developed.

  18. Vitrification of contaminated soils from the Charleston Naval Complex

    SciTech Connect (OSTI)

    O'Connor, William K.; Turner, Paul C.; Brosnan, D.A. (CECM, CLemson Univ.); Mussro, R. (CECM, Clemson Univ.); Addison, G.W. (AJT Enterprises, Inc.); Jackson, V.B. (AJT Enterprises, Inc.); Teaster, G.F. (AJT Enterprises, Inc.)

    1998-05-01T23:59:59.000Z

    Demonstration melting tests for vitrifying chrome- and lead-bearing wastes from the Charleston Naval Complex, and organic-contaminated dredging spoils from the Ashley River (part of the greater Charleston Harbor), were conducted in a 3-phase AC, graphite electrode arc furnace located at the Albany Research Center (ALRC) of the U.S. Department of Energy (DOE). These tests were conducted in cooperation with the Center for Engineering Ceramic Manufacturing (CECM) of Clemson University, and AJT Enterprises, Inc., of Charleston, South Carolina, and were funded by the DOE Office of Environmental Restoration. The two waste streams were composited into separate furance feed mixtures by blending and agglomeration with readily available industrial minerals. Over 11,340 kg (25,000 lb) of feed was processed during the demonstration melting test, at feed rates up to 523 kg/h (1,150 lb/h). Continuous feeding and glass tapping was achieved for both the dredging spoils feed mixture and the naval complex mixture. Roughly 85% of all feed reported to the glass products, which readily passed the Environmental Protection Agency (EPA) Toxicity Characteristic Leaching Procedure (TCLP). ASTM aggregate tests using the vitrified aggregate in concrete and asphaltic cements indicated a potential for utilization of these materials in concentrations from 5-15% of the total aggregate, without negative impact on the mix. Toxicological tests performed on the galss products found that this material appears to be nonhazardous and its use is not likely to result in a public health risk.

  19. Phosphate Glasses for Vitrification of Waste with High Sulfur Content

    SciTech Connect (OSTI)

    Kim, Dong-Sang; Vienna, John D.; Hrma, Pavel R.; Cassingham, Nathan J.

    2002-10-31T23:59:59.000Z

    The low solubility of sulfate in silicate-based glasses, approximately 1 mass% as SO3, limits the loading of high-level waste (HLW) and low-activity waste (LAW) containing high concentrations of sulfur. Based on crucible melting studies, we have shown that the phosphate glasses may incorporate more than 5 mass% SO3; hence, the waste loading can be increased until another constraint is met, such as glass durability. A high-sulfate HLW glass has been formulated and tested to demonstrate the advantages of phosphate glasses. The effect of waste loading on the chemical durability of quenched and slow-cooled phosphate glasses was determined using the Product Consistency Test.

  20. Quality assurance program description: Hanford Waste Vitrification Plant, Part 1. Revision 3

    SciTech Connect (OSTI)

    Not Available

    1992-12-31T23:59:59.000Z

    This document describes the Department of Energy`s Richland Field Office (DOE-RL) quality assurance (QA) program for the processing of high-level waste as well as the Vitrification Project Quality Assurance Program for the design and construction of the Hanford Waste Vitrification Plant (HWVP). It also identifies and describes the planned activities that constitute the required quality assurance program for the HWVP. This program applies to the broad scope of quality-affecting activities associated with the overall HWVP Facility. Quality-affecting activities include designing, purchasing, fabricating, handling, shipping, storing, cleaning, erecting, installing, inspecting, testing, maintaining, repairing, and modifying. Also included are the development, qualification, and production of waste forms which may be safely used to dispose of high-level radioactive waste resulting from national defense activities. The HWVP QA program is made up of many constituent programs that are being implemented by the participating organizations. This Quality Assurance program description is intended to outline and define the scope and application of the major programs that make up the HWVP QA program. It provides a means by which the overall program can be managed and directed to achieve its objectives. Subsequent parts of this description will identify the program`s objectives, its scope, application, and structure.

  1. Experienced gained with the dismantling of large components of the Pamela vitrification plant

    SciTech Connect (OSTI)

    Luycx, P.; Demonie, M.; Snoeckx, M.; Baeten, L.

    1996-12-31T23:59:59.000Z

    Belgoprocess acquired valuable experience during the dismantling of four large components of its vitrification plant at Dessel, Belgium. The four components, a ceramic melter, the vitromet equipment, the wet dust scrubber and the container lifting and weighing carriage, had to be dismantled in view of recommissioning the plant for a second vitrification programme. The dismantling strategy and operations were determined by the existing plant and equipment and by the available staff and experience. A strict programme of quality assurance was implemented. The work was completed within the scheduled time period of 2.5 years and largely within the cost estimate. Total manhours amounted to 25,000. Some 30 t of dismantling waste was conditioned into cement in 187 stainless steel drums of 200 liters. 5 t of low-level dismantling waste was sent to treatment facilities onsite. Total costs amounted to $3.5 million. The collective occupational radiation dose amounted to 48 mSv and was mainly due to repair and maintenance jobs. Dismantling costs and occupational doses can be substantially lowered by taking into account dismantling requirements at the design phase of plant and equipment.

  2. Summary Of Cold Crucible Vitrification Tests Results With Savannah River Site High Level Waste Surrogates

    SciTech Connect (OSTI)

    Stefanovsky, Sergey; Marra, James; Lebedev, Vladimir

    2014-01-13T23:59:59.000Z

    The cold crucible inductive melting (CCIM) technology successfully applied for vitrification of low- and intermediate-level waste (LILW) at SIA Radon, Russia, was tested to be implemented for vitrification of high-level waste (HLW) stored at Savannah River Site, USA. Mixtures of Sludge Batch 2 (SB2) and 4 (SB4) waste surrogates and borosilicate frits as slurries were vitrified in bench- (236 mm inner diameter) and full-scale (418 mm inner diameter) cold crucibles. Various process conditions were tested and major process variables were determined. Melts were poured into 10L canisters and cooled to room temperature in air or in heat-insulated boxes by a regime similar to Canister Centerline Cooling (CCC) used at DWPF. The products with waste loading from ~40 to ~65 wt.% were investigated in details. The products contained 40 to 55 wt.% waste oxides were predominantly amorphous; at higher waste loadings (WL) spinel structure phases and nepheline were present. Normalized release values for Li, B, Na, and Si determined by PCT procedure remain lower than those from EA glass at waste loadings of up to 60 wt.%.

  3. Strategy for addressing composition uncertainties in a Hanford high-level waste vitrification plant

    SciTech Connect (OSTI)

    Bryan, M.F.; Piepel, G.F.

    1996-03-01T23:59:59.000Z

    Various requirements will be imposed on the feed material and glass produced by the high-level waste (HLW) vitrification plant at the Hanford Site. A statistical process/product control system will be used to control the melter feed composition and to check and document product quality. Two general types of uncertainty are important in HLW vitrification process/product control: model uncertainty and composition uncertainty. Model uncertainty is discussed by Hrma, Piepel, et al. (1994). Composition uncertainty includes the uncertainties inherent in estimates of feed composition and other process measurements. Because feed composition is a multivariate quantity, multivariate estimates of composition uncertainty (i.e., covariance matrices) are required. Three components of composition uncertainty will play a role in estimating and checking batch and glass attributes: batch-to-batch variability, within-batch uncertainty, and analytical uncertainty. This document reviews the techniques to be used in estimating and updating composition uncertainties and in combining these composition uncertainties with model uncertainty to yield estimates of (univariate) uncertainties associated with estimates of batch and glass properties.

  4. Recent Device Developments with Advanced Bulk Thermoelectric...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Device Developments with Advanced Bulk Thermoelectric Materials at RTI Recent Device Developments with Advanced Bulk Thermoelectric Materials at RTI Reviews work in engineered...

  5. Thermoelectric Bulk Materials from the Explosive Consolidation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Bulk Materials from the Explosive Consolidation of Nanopowders Thermoelectric Bulk Materials from the Explosive Consolidation of Nanopowders Describes technique of explosively...

  6. Nanostructured High Temperature Bulk Thermoelectric Energy Conversion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High Temperature Bulk Thermoelectric Energy Conversion for Efficient Waste Heat Recovery Nanostructured High Temperature Bulk Thermoelectric Energy Conversion for Efficient Waste...

  7. Design alternatives report for the cesium removal demonstration

    SciTech Connect (OSTI)

    Walker, J.F. Jr.; Youngblood, E.L.

    1995-09-01T23:59:59.000Z

    The Cesium Removal Demonstration (CRD) project will use liquid low-level waste (LLLW) stored in the Oak Ridge National Laboratory Melton Valley Storage Tanks to demonstrate cesium removal from sodium nitrate-based supernates. This report presents the results of a conceptual design study to scope the alternatives for conducting the demonstration at ORNL. Factors considered included (1) sorbent alternatives, (2) facility alternatives, (3) process alternatives, (4) process disposal alternatives, and (5) relative cost comparisons. Recommendations included (1) that design of the CRD system move forward based on information obtained to date from tests with Savannah River Resin, (2) that the CRD system be designed so it could use crystalline silicotitanates (CST) if an engineered form of CST becomes available prior to the CRD, (3) that the system be designed without the capability for resin regeneration, (4) that the LLLW solidification facility be used for the demonstration (5) that vitrification of the loaded resins from the CRD be demonstrated at the Savannah River Site, and (6) that permanent disposal of the loaded and/or vitrified resin at the Nevada Test Site be pursued.

  8. Charm contribution to bulk viscosity

    E-Print Network [OSTI]

    M. Laine; Kiyoumars A. Sohrabi

    2015-02-24T23:59:59.000Z

    In the range of temperatures reached in future heavy ion collision experiments, hadronic pair annihilations and creations of charm quarks may take place within the lifetime of the plasma. As a result, charm quarks may increase the bulk viscosity affecting the early stages of hydrodynamic expansion. Assuming thermalization, we estimate the charm contribution to bulk viscosity within the same effective kinetic theory framework in which the light parton contribution has been computed previously. The time scale at which this physics becomes relevant is related to the width of the transport peak associated with the trace anomaly correlator, and is found to be 600 MeV.

  9. Technology Demonstration Partnership Policy

    Broader source: Energy.gov [DOE]

    This City Council memorandum establishes a framework for engaging in and evaluating demonstration partnerships with the goal of developing, testing, and demonstrating emerging technologies, product, and service innovations.

  10. Summary of in situ vitrification modeling and analysis accomplishments for fiscal year 1991

    SciTech Connect (OSTI)

    Slater, C.E.

    1991-11-01T23:59:59.000Z

    The in situ vitrification (ISV) modeling activities encompass a variety of both modeling development efforts and analysis applications in support of the ISV project. The model development effort is directed toward modifying or developing a set of computer codes to simulate the ISV process. These codes are used to perform safety and environmental hazards analyses, assist in experimental test planning and design, assist in equipment design and development of operating procedures, and provide enhanced understanding of the ISV process. This report presents a summary description of the accomplishments in Fiscal Year 1991 for both the model development and analysis areas. Brief descriptions of the models that were developed and the more important conclusions from the analytical studies are presented.

  11. First Commercial US Mixed Waste Vitrification Facility: Permits, Readiness Reviews, and Delisting of Final Wasteform

    SciTech Connect (OSTI)

    Pickett, J.B. [Westinghouse Savannah River Company, AIKEN, SC (United States); Norford, S.W.; Diener, G.A.

    1998-06-01T23:59:59.000Z

    Westinghouse Savannah River Co. (WSRC) contracted GTS Duratek (Duratek) to construct and operate the first commercial vitrification facility to treat an F-006 mixed (radioactive/hazardous) waste in the United States. The permits were prepared and submitted to the South Carolina state regulators by WSRC - based on a detailed design by Duratek. Readiness Assessments were conducted by WSRC and Duratek at each major phase of the operation (sludge transfer, construction, cold and radioactive operations, and a major restart) and approved by the Savannah River Department of Energy prior to proceeding. WSRC prepared the first `Upfront Delisting` petition for a vitrified mixed waste. Lessons learned with respect to the permit strategy, operational assessments, and delisting from this `privatization` project will be discussed.

  12. Final technical report: Atmospheric emission analysis for the Hanford Waste Vitrification plant

    SciTech Connect (OSTI)

    Andrews, G.L.; Rhoads, K.C.

    1996-03-01T23:59:59.000Z

    This report is an assessment of chemical and radiological effluents that are expected to be released to the atmosphere from the Hanford Waste Vitrification Plant (HWVP). The report is divided into two sections. In the first section, the impacts of carbon monoxide (CO) and nitrogen oxides as NO{sub 2} have been estimated for areas within the Hanford Site boundary. A description of the dispersion model used to-estimate CO and NO{sub 2} average concentrations and Hanford Site meteorological data has been included in this section. In the second section, calculations were performed to estimate the potential radiation doses to a maximally exposed off-site individual. The model used to estimate the horizontal and vertical dispersion of radionuclides is also discussed.

  13. Process Options Description for Vitrification Flowsheet Model of INEEL Sodium Bearing Waste

    SciTech Connect (OSTI)

    Nichols, Todd Travis; Taylor, Dean Dalton; Lauerhass, Lance; Barnes, Charles Marshall

    2001-02-01T23:59:59.000Z

    The purpose of this document is to provide the technical information to Savannah River Site (SRS) personnel that is required for the development of a basic steady-state process simulation of the vitrification treatment train of sodium bearing waste (SBW) at Idaho National Engineering and nvironmental Laboratory (INEEL). INEEL considers simulation to have an important role in the integration/optimization of treatment process trains for the High Level Waste (HLW) Program. This project involves a joint Technical Task Plan (TTP ID77WT31, Subtask C) between SRS and INEEL. The work scope of simulation is different at the two sites. This document addresses only the treatment of SBW at INEEL. The simulation model(s) is to be built by SRS for INEEL in FY-2001.

  14. Cold-cap reactions in vitrification of nuclear waste glass: experiments and modeling

    SciTech Connect (OSTI)

    Chun, Jaehun; Pierce, David A.; Pokorny, Richard; Hrma, Pavel R.

    2013-05-01T23:59:59.000Z

    Cold-cap reactions are multiple overlapping reactions that occur in the waste-glass melter during the vitrification process when the melter feed is being converted to molten glass. In this study, we used differential scanning calorimetry (DSC) to investigate cold-cap reactions in a high-alumina high-level waste melter feed. To separate the reaction heat from both sensible heat and experimental instability, we employed the run/rerun method, which enabled us to define the degree of conversion based on the reaction heat and to estimate the heat capacity of the reacting feed. Assuming that the reactions are nearly independent and can be approximated by the nth order kinetics, we obtained the kinetic parameters using the Kissinger method combined with least squares analysis. The resulting mathematical simulation of the cold-cap reactions provides a key element for the development of an advanced cold-cap model.

  15. Test plan for glass melter system technologies for vitrification of high-sodium content low-level radioactive liquid waste, Project No. RDD-43288

    SciTech Connect (OSTI)

    Higley, B.A.

    1995-03-15T23:59:59.000Z

    This document provides a test plan for the conduct of combustion fired cyclone vitrification testing by a vendor in support of the Hanford Tank Waste Remediation System, Low-Level Waste Vitrification Program. The vendor providing this test plan and conducting the work detailed within it is the Babcock & Wilcox Company Alliance Research Center in Alliance, Ohio. This vendor is one of seven selected for glass melter testing.

  16. Bulk viscosity and deflationary universes

    E-Print Network [OSTI]

    J. A. S. Lima; R. Portugal; I. Waga

    2007-08-24T23:59:59.000Z

    We analyze the conditions that make possible the description of entropy generation in the new inflationary model by means of a nearequilibrium process. We show that there are situations in which the bulk viscosity cannot describe particle production during the coherent field oscillations phase.

  17. Bulk Hydrogen Strategic Directions for

    E-Print Network [OSTI]

    Economics Storage Performance Issues Market and Institutional Issues Storage Devices and Technologies-board) Develop new materials to address unique H2 leakage and Embrittlement Considerations Develop Smart Sensors Formations. #12;Breakout Session - Bulk Hydrogen Storage "Take home" messages Economics Cost of Storage vis

  18. A preliminary study of the controls on melting during in situ vitrification

    SciTech Connect (OSTI)

    Solomon, A.D.; Nyquist, J.E.; Alexiades, V.; Jacobs, G.K.; Lenhart, S.M.

    1991-12-01T23:59:59.000Z

    In situ vitrification (ISV), developed by Pacific Northwest Laboratory and patented for the US Department of Energy, is one method used to stabilize contaminated soils in place. ISV involves inserting four electrodes in a square array into contaminated soil and applying an electrical potential to the electrodes. The soil is heated to above its melting point, and the molten zone expands with time to encompass the contaminated zone. After cooling, the resulting solid material is usually a mixture of glass and crystalline material that has a significantly higher resistance to leaching than did the original soils. Nonvolatile elements (most radionuclides and metals) are dissolved into the melt or encapsulated in glass if their solubility in the melt is low. Organic compounds tends to be pyrolyzed, with the decomposition products diffusing to the surface and combusting on exiting the molten zone. A hood is placed over the vitrification zone to collect off-gas particulates and volatiles into a processing trailer that scrubs contaminants from the off-gas. The current study identified key parameters and processes in the ISV melt cycle and developed an improved understanding of ISV. Analytical approximations for several properties of molten soil were determined from available data. Using a simplified geometrical approximation for melt geometry, an analytical approximation for the rate of melting (depth) vs time was derived that is consistent with data from field experiments. At small times, the depth of melting increases linearly with time. After approximately 10 h in large-scale tests, however, the depth increases as the square root of time. Existing data is also consistent with a relationship that shows the volumetric growth rate of the melt to be directly proportional to time. These conclusions suggest that heat transfer processes controlling the ISV process may be at the transition between weak convection and conduction.

  19. A preliminary study of the controls on melting during in situ vitrification. Environmental Restoration Program

    SciTech Connect (OSTI)

    Solomon, A.D.; Nyquist, J.E.; Alexiades, V.; Jacobs, G.K.; Lenhart, S.M.

    1991-12-01T23:59:59.000Z

    In situ vitrification (ISV), developed by Pacific Northwest Laboratory and patented for the US Department of Energy, is one method used to stabilize contaminated soils in place. ISV involves inserting four electrodes in a square array into contaminated soil and applying an electrical potential to the electrodes. The soil is heated to above its melting point, and the molten zone expands with time to encompass the contaminated zone. After cooling, the resulting solid material is usually a mixture of glass and crystalline material that has a significantly higher resistance to leaching than did the original soils. Nonvolatile elements (most radionuclides and metals) are dissolved into the melt or encapsulated in glass if their solubility in the melt is low. Organic compounds tends to be pyrolyzed, with the decomposition products diffusing to the surface and combusting on exiting the molten zone. A hood is placed over the vitrification zone to collect off-gas particulates and volatiles into a processing trailer that scrubs contaminants from the off-gas. The current study identified key parameters and processes in the ISV melt cycle and developed an improved understanding of ISV. Analytical approximations for several properties of molten soil were determined from available data. Using a simplified geometrical approximation for melt geometry, an analytical approximation for the rate of melting (depth) vs time was derived that is consistent with data from field experiments. At small times, the depth of melting increases linearly with time. After approximately 10 h in large-scale tests, however, the depth increases as the square root of time. Existing data is also consistent with a relationship that shows the volumetric growth rate of the melt to be directly proportional to time. These conclusions suggest that heat transfer processes controlling the ISV process may be at the transition between weak convection and conduction.

  20. Hanford High-Level Waste Vitrification Program at the Pacific Northwest National Laboratory: technology development - annotated bibliography

    SciTech Connect (OSTI)

    Larson, D.E.

    1996-09-01T23:59:59.000Z

    This report provides a collection of annotated bibliographies for documents prepared under the Hanford High-Level Waste Vitrification (Plant) Program. The bibliographies are for documents from Fiscal Year 1983 through Fiscal Year 1995, and include work conducted at or under the direction of the Pacific Northwest National Laboratory. The bibliographies included focus on the technology developed over the specified time period for vitrifying Hanford pretreated high-level waste. The following subject areas are included: General Documentation; Program Documentation; High-Level Waste Characterization; Glass Formulation and Characterization; Feed Preparation; Radioactive Feed Preparation and Glass Properties Testing; Full-Scale Feed Preparation Testing; Equipment Materials Testing; Melter Performance Assessment and Evaluations; Liquid-Fed Ceramic Melter; Cold Crucible Melter; Stirred Melter; High-Temperature Melter; Melter Off-Gas Treatment; Vitrification Waste Treatment; Process, Product Control and Modeling; Analytical; and Canister Closure, Decontamination, and Handling

  1. LIMB Demonstration Project Extension and Coolside Demonstration

    SciTech Connect (OSTI)

    Goots, T.R.; DePero, M.J.; Nolan, P.S.

    1992-11-10T23:59:59.000Z

    This report presents results from the limestone Injection Multistage Burner (LIMB) Demonstration Project Extension. LIMB is a furnace sorbent injection technology designed for the reduction of sulfur dioxide (SO[sub 2]) and nitrogen oxides (NO[sub x]) emissions from coal-fired utility boilers. The testing was conducted on the 105 Mwe, coal-fired, Unit 4 boiler at Ohio Edison's Edgewater Station in Lorain, Ohio. In addition to the LIMB Extension activities, the overall project included demonstration of the Coolside process for S0[sub 2] removal for which a separate report has been issued. The primary purpose of the DOE LIMB Extension testing, was to demonstrate the generic applicability of LIMB technology. The program sought to characterize the S0[sub 2] emissions that result when various calcium-based sorbents are injected into the furnace, while burning coals having sulfur content ranging from 1.6 to 3.8 weight percent. The four sorbents used included calcitic limestone, dolomitic hydrated lime, calcitic hydrated lime, and calcitic hydrated lime with a small amount of added calcium lignosulfonate. The results include those obtained for the various coal/sorbent combinations and the effects of the LIMB process on boiler and plant operations.

  2. Modelling of bulk superconductor magnetization

    E-Print Network [OSTI]

    Ainslie, M. D.; Fujishiro, H.

    2015-03-30T23:59:59.000Z

    synchronous motor. It may also be possible to use superconducting materials of different Tcs and a dual cooling system to develop an in-situ FC magnetization process for YBCO bulk plates using the superconducting stator coils of an electric machine... . Furthermore, the relative ease of fabrication of MgB2 materials, as well as their long coherence length [10], lower anisotropy and strongly linked supercurrent flow in untextured polycrystalline samples [11,12], has enabled a number of different processing...

  3. Plant Decontamination as a Precondition of the Remote Dismantling Concept of the Karlsruhe Vitrification Plant VEK - 12206

    SciTech Connect (OSTI)

    Dux, Joachim; Fleisch, Joachim; Latzko, Bernhard; Rohleder, Norbert [WAK Rueckbau- und Entsorgungs- GmbH, P.O.Box 12 63, 76339 Eggenstein-Leopoldshafen (Germany)

    2012-07-01T23:59:59.000Z

    Vitrification of the high-active liquid waste concentrates (HAWC) was a major milestone in the WAK decommissioning project (StiWAK). From September 2009 to June 2010, about 56 m{sup 3} of HAWC were vitrified at the Karlsruhe vitrification facility (VEK) and filled into 123 canisters. HAWC vitrification was followed by an extensive rinsing and shutdown program, in the course of which both the VEK process installations and the facilities for the storage and evaporation of high-active fission product solutions (LAVA) are prepared specifically for dismantling. Finally the rinsing programme leads to an overall reduction of the remaining contamination in the installations by a factor of approx. 5 - 10. The amount of liquids arisen from this program has been vitrified and another 17 canisters have been filled. In total, 140 canisters were packed into 5 CASTOR casks that were already transported to the Zwischenlager Nord (interim store North) of EWN GmbH (ZLN) in the mid of February 2011. The melter of the VEK was already shut down in the late November 2010. (authors)

  4. Vitrification treatment options for disposal of greater-than-Class-C low-level waste in a deep geologic repository

    SciTech Connect (OSTI)

    Fullmer, K.S.; Fish, L.W.; Fischer, D.K.

    1994-11-01T23:59:59.000Z

    The Department of Energy (DOE), in keeping with their responsibility under Public Law 99-240, the Low-Level Radioactive Waste Policy Amendments Act of 1985, is investigating several disposal options for greater-than-Class C low-level waste (GTCC LLW), including emplacement in a deep geologic repository. At the present time vitrification, namely borosilicate glass, is the standard waste form assumed for high-level waste accepted into the Civilian Radioactive Waste Management System. This report supports DOE`s investigation of the deep geologic disposal option by comparing the vitrification treatments that are able to convert those GTCC LLWs that are inherently migratory into stable waste forms acceptable for disposal in a deep geologic repository. Eight vitrification treatments that utilize glass, glass ceramic, or basalt waste form matrices are identified. Six of these are discussed in detail, stating the advantages and limitations of each relative to their ability to immobilize GTCC LLW. The report concludes that the waste form most likely to provide the best composite of performance characteristics for GTCC process waste is Iron Enriched Basalt 4 (IEB4).

  5. Strategy Guideline: Demonstration Home

    SciTech Connect (OSTI)

    Savage, C.; Hunt, A.

    2012-12-01T23:59:59.000Z

    This guideline will provide a general overview of the different kinds of demonstration home projects, a basic understanding of the different roles and responsibilities involved in the successful completion of a demonstration home, and an introduction into some of the lessons learned from actual demonstration home projects. Also, this guideline will specifically look at the communication methods employed during demonstration home projects. And lastly, we will focus on how to best create a communication plan for including an energy efficient message in a demonstration home project and carry that message to successful completion.

  6. LIMB demonstration project extension

    SciTech Connect (OSTI)

    Not Available

    1990-09-21T23:59:59.000Z

    The purpose of the DOE limestone injection multistage burner (LIMB) Demonstration Project Extension is to extend the data base on LIMB technology and to expand DOE's list of Clean Coal Technologies by demonstrating the Coolside process as part of the project. The main objectives of this project are: to demonstrate the general applicability of LIMB technology by testing 3 coals and 4 sorbents (total of 12 coal/sorbent combinations) at the Ohio Edison Edgewater plant; and to demonstrate that Coolside is a viable technology for improving precipitator performance and reducing sulfur dioxide emissions while acceptable operability is maintained. Progress is reported. 3 figs.

  7. Scanning Tunneling Macroscopy, Black Holes, and AdS/CFT Bulk Locality

    E-Print Network [OSTI]

    Soo-Jong Rey; Vladimir Rosenhaus

    2014-06-02T23:59:59.000Z

    We establish resolution bounds on reconstructing a bulk field from boundary data on a timelike hypersurface. If the bulk only supports propagating modes, reconstruction is complete. If the bulk also supports evanescent modes, local reconstruction is not achievable unless one has exponential precision in knowledge of the boundary data. Without exponential precision, for a Minkowski bulk, one can reconstruct a spatially coarse-grained bulk field, but only out to a depth set by the coarse-graining scale. For an asymptotically AdS bulk, reconstruction is limited to a spatial coarse-graining proper distance set by the AdS scale. AdS black holes admit evanescent modes. We study the resolution bound in the large AdS black hole background and provide a dual CFT interpretation. Our results demonstrate that, if there is a black hole of any size in the bulk, then sub-AdS bulk locality is no longer well-encoded in boundary data in terms of local CFT operators. Specifically, in order to probe the bulk on sub-AdS scales using only boundary data in terms of local operators, one must either have such data to exponential precision or make further assumptions about the bulk state.

  8. Evaluation of defense-waste glass produced by full-scale vitrification equipment

    SciTech Connect (OSTI)

    Lukacs, J.M.; Petkus, L.L.; Mellinger, G.B.

    1981-09-01T23:59:59.000Z

    Three full-scale vitrification processes at the Pacific Northwest Laboratory produced over 67,000 kg of simulated nuclear-waste glass from March 1979 to August 1980. Samples were analyzed to monitor process operation and evaluate the resulting glass product. These processes are: Spray Calciner/In-Can Melter (SC/ICM); Spray Calciner/Calcine-Fed Ceramic Melter (SC/CFCM); and Liquid-Fed Ceramic Melter (LFCM). Waste components in the process feed varied less than +- 10%. The SC/ICM and SC/CFCM which use separate waste and frit feed systems showed larger glass compositional variation than the LFCM, which processed only premixed feed during this period. The SC/ICM and SC/CFCM product contained significant amounts of acmite crystals, while the LFCM product was largely amorphous. In addition, the lower portion of all SC/ICM-filled canisters contained a zone rich in waste components. A product chemical durability as determined by pH4 and soxhlet leach tests varied considerably. Aside from increased durability under pH4 conditions with decreasing waste content, glass composition, microstructure and melting process did not correlate with glass durability. For all samples analyzed, the weight loss under pH4 conditions ranged from 17.7 to 85.2 wt %. Soxhlet conditions produced weight losses from 1.78 to 3.56 wt %.

  9. Interim data quality objectives for waste pretreatment and vitrification. Revision 1

    SciTech Connect (OSTI)

    Kupfer, M.J.; Conner, J.M.; Kirkbride, R.A.; Mobley, J.R.

    1994-09-15T23:59:59.000Z

    The Tank Waste Remediation System (TWRS) is responsible for storing, processing, and immobilizing the Hanford Site tank wastes. Characterization information on the tank wastes is needed so that safety concerns can be addressed, and retrieval, pretreatment, and immobilization processes can be designed, permitted, and implemented. This document describes the near-term tank waste sampling and characterization needs of the Pretreatment, High-Level Waste (HLW) Disposal, and Low-Level Waste (LLW) Disposal Programs to support the TWRS disposal mission. The final DQO (Data Quality Objective) will define specific waste tanks to be sampled, sample timing requirements, an appropriate analytical scheme, and a list of required analytes. This interim DQO, however, focuses primarily on the required analytes since the tanks to be sampled in FY 1994 and early FY 1995 are being driven most heavily by other considerations, particularly safety. The major objective of this Interim DQO is to provide guidance for tank waste characterization requirements for samples taken before completion of the final DQO. The characterization data needs defined herein will support the final DQO to help perform the following: Support the TWRS technical strategy by identification of the chemical and physical composition of the waste in the tanks and Guide development efforts to define waste pretreatment processes, which will in turn define HLW and LLW feed to vitrification processes.

  10. Materials selection for process equipment in the Hanford waste vitrification plant

    SciTech Connect (OSTI)

    Elmore, M R; Jensen, G A

    1991-07-01T23:59:59.000Z

    The Hanford Waste Vitrification Plant (HWVP) is being designed to vitrify defense liquid high-level wastes and transuranic wastes stored at Hanford. The HWVP Functional Design Criteria (FDC) requires that materials used for fabrication of remote process equipment and piping in the facility be compatible with the expected waste stream compositions and process conditions. To satisfy FDC requirements, corrosion-resistant materials have been evaluated under simulated HWVP-specific conditions and recommendations have been made for HWVP applications. The materials recommendations provide to the project architect/engineer the best available corrosion rate information for the materials under the expected HWVP process conditions. Existing data and sound engineering judgement must be used and a solid technical basis must be developed to define an approach to selecting suitable construction materials for the HWVP. This report contains the strategy, approach, criteria, and technical basis developed for selecting materials of construction. Based on materials testing specific to HWVP and on related outside testing, this report recommends for constructing specific process equipment and identifies future testing needs to complete verification of the performance of the selected materials. 30 refs., 7 figs., 11 tabs.

  11. Process Options Description for Vitrification Flowsheet Model of INEEL Sodium Bearing Waste

    SciTech Connect (OSTI)

    Nichols, T.T.; Taylor, D.D.; Lauerhass, L.; Barnes, C.M.

    2002-02-21T23:59:59.000Z

    The technical information required for the development of a basic steady-state process simulation of the vitrification treatment train of sodium bearing waste (SBW) at Idaho National Engineering and Environmental Laboratory (INEEL) is presented. The objective of the modeling effort is to provide the predictive capability required to optimize an entire treatment train and assess system-wide impacts of local changes at individual unit operations, with the aim of reducing the schedule and cost of future process/facility design efforts. All the information required a priori for engineers to construct and link unit operation modules in a commercial software simulator to represent the alternative treatment trains is presented. The information is of a mid- to high-level nature and consists of the following: (1) a description of twenty-four specific unit operations--their operating conditions and constraints, primary species and key outputs, and the initial modeling approaches that will be used in the first year of the simulation's development; (2) three potential configurations of the unit operations (trains) and their interdependencies via stream connections; and (3) representative stream compositional makeups.

  12. First-order study of property/composition relationships for Hanford Waste Vitrification Plant glasses

    SciTech Connect (OSTI)

    Piepel, G.F.; Hrma, P.R.; Bates, S.O.; Schweiger, M.J.; Smith, D.E.

    1993-01-01T23:59:59.000Z

    A first-order composition variability study (CVS-I) was conducted for the Hanford Waste Vitrification Plant (HWVP) program to preliminarily characterize the effects on key glass properties of variations i selected glass (waste and frit) components. The components selected were Si0{sub 2},B{sub 2}O{sub 3},A1{sub 2}O{sub 3}, Fe{sub 2}O{sub 3}, ZrO{sub 2}, Na{sub 2}O,Li{sub 2}O,CaO,MgO, and Others (all remaining waste components). A glass composition region was selected for study based on the expected range of glass compositions and the results of a previous series of scoping and solubility studies. Then, a 23-glass statistically-designed mixture experiment was conducted and data obtained for viscosity, electrical conductivity, glass transition temperature, thermal expansion, crystallinity, and durability [Materials Characterization Center (MCC-1) 28-day leach test and the 7-day Product Consistency Test (PCT)]. These data were modeled using first-order functions of composition, and the models were used to investigate the effects of the components on glass and melt properties. The CVS-I data and models will also be used to support the second-order composition variability study (CVS-II).

  13. First-order study of property/composition relationships for Hanford Waste Vitrification Plant glasses

    SciTech Connect (OSTI)

    Piepel, G.F.; Hrma, P.R.; Bates, S.O.; Schweiger, M.J.; Smith, D.E.

    1993-01-01T23:59:59.000Z

    A first-order composition variability study (CVS-I) was conducted for the Hanford Waste Vitrification Plant (HWVP) program to preliminarily characterize the effects on key glass properties of variations i selected glass (waste and frit) components. The components selected were Si0[sub 2],B[sub 2]O[sub 3],A1[sub 2]O[sub 3], Fe[sub 2]O[sub 3], ZrO[sub 2], Na[sub 2]O,Li[sub 2]O,CaO,MgO, and Others (all remaining waste components). A glass composition region was selected for study based on the expected range of glass compositions and the results of a previous series of scoping and solubility studies. Then, a 23-glass statistically-designed mixture experiment was conducted and data obtained for viscosity, electrical conductivity, glass transition temperature, thermal expansion, crystallinity, and durability [Materials Characterization Center (MCC-1) 28-day leach test and the 7-day Product Consistency Test (PCT)]. These data were modeled using first-order functions of composition, and the models were used to investigate the effects of the components on glass and melt properties. The CVS-I data and models will also be used to support the second-order composition variability study (CVS-II).

  14. Metal recovery from fly ash generated from vitrification process for MSW ash

    SciTech Connect (OSTI)

    Izumikawa, Chiaki [Dowa Mining Co. Ltd., Chiyoda, Tokyo (Japan)] [Dowa Mining Co. Ltd., Chiyoda, Tokyo (Japan)

    1996-12-31T23:59:59.000Z

    Metal-bearing wastes have to be carefully treated because heavy metals could be leached out under uncontrolled conditions when disposed of in a landfill. Consequently, heavy metals should be principally recovered and recycled forever. From this standpoint, the author has been trying to develop a technology to recover heavy metals from toxic vitrification fly ash for recycling to smelters. After a number of laboratory-scale experiments, pilot plant tests were successfully carried out and the developed process has been proven to be commercially realized. The main features of the process are that it recovers almost 100% of the heavy metals, simultaneously separating the metals which are recovered in a lead smelter from those in a zinc smelter, and that the output of the process are only metallurgical products recyclable for smelters and the effluent water which can be released into the environment. The process is considered an ideal one for the treatment of toxic fly ash from the viewpoint of not only natural resources but also environmental conservation.

  15. Bulk viscous cosmology: statefinder and entropy

    E-Print Network [OSTI]

    M. Hu; Xin He Meng

    2005-11-23T23:59:59.000Z

    The statefinder diagnostic pair is adopted to differentiate viscous cosmology models and it is found that the trajectories of these viscous cosmology models on the statefinder pair $s-r$ plane are quite different from those of the corresponding non-viscous cases. Particularly for the quiessence model, the singular properties of state parameter $w=-1$ are obviously demonstrated on the statefinder diagnostic pair planes. We then discuss the entropy of the viscous / dissipative cosmology system which may be more practical to describe the present cosmic observations as the perfect fluid is just a global approximation to the complicated cosmic media in current universe evolution. When the bulk viscosity takes the form of $\\zeta=\\zeta_{1}\\dot{a}/a$($\\zeta_{1}$ is constant), the relationship between the entropy $S$ and the redshift $z$ is explicitly given out. We find that the entropy of the viscous cosmology is always increasing and consistent with the thermodynamics arrow of time for the universe evolution. With the parameter constraints from fitting to the 157 gold data of supernova observations, it is demonstrated that this viscous cosmology model is rather well consistent to the observational data at the lower redshifts, and together with the diagnostic statefinder pair analysis it is concluded that the viscous cosmic models tend to the favored $\\Lambda$CDM model in the later cosmic evolution, agreeable to lots of cosmological simulation results, especially to the fact of confidently observed current accelerating cosmic expansion.

  16. Core Drilling Demonstration

    Broader source: Energy.gov [DOE]

    Tank Farms workers demonstrate core drilling capabilities for Hanford single-shell tanks. Core drilling is used to determine the current condition of each tank to assist in the overall assessment...

  17. Nanofluidics, from bulk to interfaces

    E-Print Network [OSTI]

    Lyderic Bocquet; Elisabeth Charlaix

    2009-09-03T23:59:59.000Z

    Nanofluidics has emerged recently in the footsteps of microfluidics, following the quest of scale reduction inherent to nanotechnologies. By definition, nanofluidics explores transport phenomena of fluids at the nanometer scales. Why is the nanometer scale specific ? What fluid properties are probed at nanometric scales ? In other words, why 'nanofluidics' deserves its own brand name ? In this critical review, we will explore the vast manifold of length scales emerging for the fluid behavior at the nanoscales, as well as the associated mechanisms and corresponding applications. We will in particular explore the interplay between bulk and interface phenomena. The limit of validity of the continuum approaches will be discussed, as well as the numerous surface induced effects occuring at these scales, from hydrodynamic slippage to the various electro-kinetic phenomena originating from the couplings between hydrodynamics and electrostatics. An enlightening analogy between ion transport in nanochannels and transport in doped semi-conductors will be discussed.

  18. Hanford Waste Vitrification Program process development: Melt testing subtask, pilot-scale ceramic melter experiment, run summary

    SciTech Connect (OSTI)

    Nakaoka, R.K.; Bates, S.O.; Elmore, M.R.; Goles, R.W.; Perez, J.M.; Scott, P.A.; Westsik, J.H.

    1996-03-01T23:59:59.000Z

    Hanford Waste Vitrification Program (HWVP) activities for FY 1985 have included engineering and pilot-scale melter experiments HWVP-11/HBCM-85-1 and HWVP-12/PSCM-22. Major objectives designated by HWVP fo these tests were to evaluate the processing characteristics of the current HWVP melter feed during actual melter operation and establish the product quality of HW-39 borosilicate glass. The current melter feed, defined during FY 85, consists of reference feed (HWVP-RF) and glass-forming chemicals added as frit.

  19. Radiative cooling of bulk silicon by incoherent light pump

    SciTech Connect (OSTI)

    Malyutenko, V. K., E-mail: malyut@isp.kiev.ua; Bogatyrenko, V. V.; Malyutenko, O. Yu. [V. E. Lashkaryov Institute of Semiconductor Physics, 03028 Kiev (Ukraine)] [V. E. Lashkaryov Institute of Semiconductor Physics, 03028 Kiev (Ukraine)

    2013-12-23T23:59:59.000Z

    In contrast to radiative cooling by light up conversion caused exclusively by a low-entropy laser pump and employing thermally assisted fluorescence/luminescence as a power out, we demonstrate light down conversion cooling by incoherent pumps, 0.47–0.94??m light emitting diodes, and employing thermal emission (TE) as a power out. We demonstrate ?3.5?K bulk cooling of Si at 450?K because overall energy of multiple below bandgap TE photons exceeds the energy of a single above bandgap pump photon. We show that using large entropy TE as power out helps avoid careful tuning of an incoherent pump wavelength and cool indirect-bandgap semiconductors.

  20. Commercialization of Bulk Thermoelectric Materials for Power...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    & Publications Commercialization of Bulk Thermoelectric Materials for Power Generation Hydrogen Embrittlement of Pipeline Steels: Causes and Remediation Distributed Bio-Oil...

  1. Bulk viscosity in kaon condensed matter

    E-Print Network [OSTI]

    Debarati Chatterjee; Debades Bandyopadhyay

    2007-05-30T23:59:59.000Z

    We investigate the effect of $K^-$ condensed matter on bulk viscosity and r-mode instability in neutron stars. The bulk viscosity coefficient due to the non-leptonic process $n \\rightleftharpoons p + K^-$ is studied here. In this connection, equations of state are constructed within the framework of relativistic field theoretical models where nucleon-nucleon and kaon-nucleon interactions are mediated by the exchange of scalar and vector mesons. We find that the bulk viscosity coefficient due to the non-leptonic weak process in the condensate is suppressed by several orders of magnitude. Consequently, kaon bulk viscosity may not damp the r-mode instability in neutron stars.

  2. Inorganic Nanocrystal Bulk Heterojunctions - Energy Innovation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Solar Photovoltaic Solar Photovoltaic Find More Like This Return to Search Inorganic Nanocrystal Bulk Heterojunctions Brookhaven National Laboratory Contact BNL About This...

  3. Hyperon bulk viscosity in strong magnetic fields

    E-Print Network [OSTI]

    Monika Sinha; Debades Bandyopadhyay

    2009-06-06T23:59:59.000Z

    We study the bulk viscosity of neutron star matter including $\\Lambda$ hyperons in the presence of quantizing magnetic fields. Relaxation time and bulk viscosity due to both the non-leptonic weak process involving $\\Lambda$ hyperons and direct Urca processes are calculated here. In the presence of a strong magnetic field of $10^{17}$ G, the hyperon bulk viscosity coefficient is reduced whereas bulk viscosity coefficients due to direct Urca processes are enhanced compared with their field free cases when many Landau levels are populated by protons, electrons and muons.

  4. New Technology Demonstration Program

    E-Print Network [OSTI]

    New Technology Demonstration Program Technical Brief FEMPFederal Energy Management Program Tom for saving energy in refrigerated walk-in coolers, and to evaluate the potential for this technology in Federal facilities. The focus of this study was on a single manufacturer of the technology, Nevada Energy

  5. MAJORANA Demonstrator Motivation

    E-Print Network [OSTI]

    Washington at Seattle, University of - Department of Physics, Electroweak Interaction Research Group

    1 #12;OVERVIEW MAJORANA Demonstrator Motivation Neutrinoless double beta decay Search for axions: MAJORANA Collaboration #12;NEUTRINOLESS DOUBLE BETA DECAY Emission of 2 electrons from Ge-76 and application to neutrinoless double beta decay search in Ge- 76." Journal of Instrumentation 6 (2011).13 #12

  6. GATEWAY Demonstration Special Reports

    Broader source: Energy.gov [DOE]

    DOE shares the results of completed GATEWAY demonstration projects, publishing detailed reports that include analysis of data collected, projected energy savings, economic analyses, and user feedback. Report briefs summarize key findings in a quick-scan format. Both the reports and briefs are available as Adobe Acrobat PDFs.

  7. Permanent magnet with MgB{sub 2} bulk superconductor

    SciTech Connect (OSTI)

    Yamamoto, Akiyasu, E-mail: yamamoto@appchem.t.u-tokyo.ac.jp [The University of Tokyo, 7-3-1 Hongo, Bunkyo, Tokyo 113-8656 (Japan); JST-PRESTO, 4-1-8 Honcho, Kawaguchi, Saitama 332-0012 (Japan); Ishihara, Atsushi; Tomita, Masaru [Railway Technical Research Institute, 2-8-38 Hikari, Kokubunji, Tokyo 185-8540 (Japan); Kishio, Kohji [The University of Tokyo, 7-3-1 Hongo, Bunkyo, Tokyo 113-8656 (Japan)

    2014-07-21T23:59:59.000Z

    Superconductors with persistent zero-resistance currents serve as permanent magnets for high-field applications requiring a strong and stable magnetic field, such as magnetic resonance imaging. The recent global helium shortage has quickened research into high-temperature superconductors (HTSs)—materials that can be used without conventional liquid-helium cooling to 4.2?K. Herein, we demonstrate that 40-K-class metallic HTS magnesium diboride (MgB{sub 2}) makes an excellent permanent bulk magnet, maintaining 3?T at 20?K for 1 week with an extremely high stability (<0.1 ppm/h). The magnetic field trapped in this magnet is uniformly distributed, as for single-crystalline neodymium-iron-boron. Magnetic hysteresis loop of the MgB{sub 2} permanent bulk magnet was determined. Because MgB{sub 2} is a simple-binary-line compound that does not contain rare-earth metals, polycrystalline bulk material can be industrially fabricated at low cost and with high yield to serve as strong magnets that are compatible with conventional compact cryocoolers, making MgB{sub 2} bulks promising for the next generation of Tesla-class permanent-magnet applications.

  8. Tracer-level radioactive pilot-scale test of in situ vitrification for the stabilization of contaminated soil sites at ORNL

    SciTech Connect (OSTI)

    Spalding, B.P.; Jacobs, G.K.; Naney, M.T. [Oak Ridge National Lab., TN (United States); Dunbar, N.W. [New Mexico Bureau of Mines and Mineral Resources, Socorro, NM (United States); Tixier, J.S.; Powell, T.D. [Pacific Northwest Lab., Richland, WA (United States)

    1992-11-01T23:59:59.000Z

    A field demonstration of in situ vitrification (ISV) was completed in May 1991, and produced approximately 12 Mg of melted earthen materials containing 12.7 mCi of radioactivity within 500 g of sludge in amodel of an old seepage trench waste disposal unit. Past waste disposal operations at Oak Ridge National Laboratory have left several contaminated seepage sites. In planning for remediation of such sites, ISV technology has been identified as a leading candidate because of the high risks associated with any retrieval option and because of the usual high quality of vitreous waste form. Major isotopes placed in the test trench were {sup 137}Cs and {sup 90}Sr, with lesser amounts of {sup 6O}Co, {sup 241}Am, and {sup 239,240}Pu. A total of 29 MWh of electrical power was delivered to the ground over a 5-day period producing a melt depth of 8.5 ft. During melting, 2.4% of the {sup 137}Cs volatilized from the melt into an off-gas containment hood and was captured quantitatively on a high efficiency particulate air filter. No volatilization of {sup 90}Sr, {sup 241}Am, or {sup 239,240}Pu was detected and > 99.993% retention of these isotopes in the melt was estimated. The use of added rare earth tracers (Ce, La, and Nd), as surrogates for transuranic isotopes, led to estimated melt retentions of >99.9995% during the test. The molten material, composed of the native soil and dolomitic limestone used for filling the test trench, reached a processing temperature of 1500{degrees}C. Standardized leaching procedures using Product Consistency Testing indicated that the ISV product has excellent characteristics relative to other vitreous nuclear waste forms.

  9. Tracer-level radioactive pilot-scale test of in situ vitrification for the stabilization of contaminated soil sites at ORNL

    SciTech Connect (OSTI)

    Spalding, B.P.; Jacobs, G.K.; Naney, M.T. (Oak Ridge National Lab., TN (United States)); Dunbar, N.W. (New Mexico Bureau of Mines and Mineral Resources, Socorro, NM (United States)); Tixier, J.S.; Powell, T.D. (Pacific Northwest Lab., Richland, WA (United States))

    1992-11-01T23:59:59.000Z

    A field demonstration of in situ vitrification (ISV) was completed in May 1991, and produced approximately 12 Mg of melted earthen materials containing 12.7 mCi of radioactivity within 500 g of sludge in amodel of an old seepage trench waste disposal unit. Past waste disposal operations at Oak Ridge National Laboratory have left several contaminated seepage sites. In planning for remediation of such sites, ISV technology has been identified as a leading candidate because of the high risks associated with any retrieval option and because of the usual high quality of vitreous waste form. Major isotopes placed in the test trench were [sup 137]Cs and [sup 90]Sr, with lesser amounts of [sup 6O]Co, [sup 241]Am, and [sup 239,240]Pu. A total of 29 MWh of electrical power was delivered to the ground over a 5-day period producing a melt depth of 8.5 ft. During melting, 2.4% of the [sup 137]Cs volatilized from the melt into an off-gas containment hood and was captured quantitatively on a high efficiency particulate air filter. No volatilization of [sup 90]Sr, [sup 241]Am, or [sup 239,240]Pu was detected and > 99.993% retention of these isotopes in the melt was estimated. The use of added rare earth tracers (Ce, La, and Nd), as surrogates for transuranic isotopes, led to estimated melt retentions of >99.9995% during the test. The molten material, composed of the native soil and dolomitic limestone used for filling the test trench, reached a processing temperature of 1500[degrees]C. Standardized leaching procedures using Product Consistency Testing indicated that the ISV product has excellent characteristics relative to other vitreous nuclear waste forms.

  10. AVNG system demonstration

    SciTech Connect (OSTI)

    Thron, Jonathan Louis [Los Alamos National Laboratory; Mac Arthur, Duncan W [Los Alamos National Laboratory; Kondratov, Sergey [VNIIEF; Livke, Alexander [VNIIEF; Razinkov, Sergey [VNIIEF

    2010-01-01T23:59:59.000Z

    An attribute measurement system (AMS) measures a number of unclassified attributes of potentially classified material. By only displaying these unclassified results as red or green lights, the AMS protects potentially classified information while still generating confidence in the measurement result. The AVNG implementation that we describe is an AMS built by RFNC - VNIIEF in Sarov, Russia. To provide additional confidence, the AVNG was designed with two modes of operation. In the secure mode, potentially classified measurements can be made with only the simple red light/green light display. In the open mode, known unclassified material can be measured with complete display of the information collected from the radiation detectors. The AVNG demonstration, which occurred in Sarov, Russia in June 2009 for a joint US/Russian audience, included exercising both modes of AVNG operation using a number of multi-kg plutonium sources. In addition to describing the demonstration, we will show photographs and/or video taken of AVNG operation.

  11. LIMB Demonstration Project Extension

    SciTech Connect (OSTI)

    Not Available

    1988-09-15T23:59:59.000Z

    The basic goal of the Limestone Injection Multistage Burner (LIMB) demonstration is to extend LIMB technology development to a full-scale application on a representative wall-fired utility boiler. The successful retrofit of LIMB to an existing boiler is expected to demonstrate that (a) reductions of 50 percent or greater in SO and NO emissions can be achieved at a fraction of the cost of add-on FGD systems, (b) boiler reliability, operability, and steam production can be maintained at levels existing prior to LIMB retrofit, and (c) technical difficulties attributable to LIMB operation, such as additional slagging and fouling, changes in ash disposal requirements, and an increased particulate load, can be resolved in a cost-effective manner. The primary fuel to be used will be an Ohio bituminous coal having a nominal sulfur content of 3 percent or greater.

  12. LIMB Demonstration Project Extension

    SciTech Connect (OSTI)

    Not Available

    1989-06-15T23:59:59.000Z

    The basic goal of the Limestone Injection Multistage Burner (LIMB) demonstration is to extend LIMB technology development to a full- scale application on a representative wall-fired utility boiler. The successful retrofit of LIMB to an existing boiler is expected to demonstrate that (a) reductions of 50 percent or greater in SO{sub x} and NO{sub x} emissions can be achieved at a fraction of the cost of add-on FGD systems, (b) boiler reliability, operability, and steam production can be maintained at levels existing prior to LIMB retrofit, and (c) technical difficulties attributable to LIMB operation, such as additional slagging and fouling, changes in ash disposal requirements, and an increased particulate load, can be resolved in a cost-effective manner. The primary fuel to be used will be an Ohio bituminous coal having a nominal sulfur content of 3 percent or greater.

  13. LIMB Demonstration Project Extension

    SciTech Connect (OSTI)

    Not Available

    1989-11-15T23:59:59.000Z

    The basic goal of the Limestone Injection Mitigation Burner (LIMB) demonstration is to extend LIMB technology development to a full- scale application on a representative wall-fired utility boiler. The successful retrofit of LIMB to an existing boiler is expected to demonstrate that (a) reductions of 50 percent or greater in SO{sub x} and NO{sub x} emissions can be achieved at a fraction of the cost of add-on FGD systems, (b) boiler reliability, operability, and steam production can be maintained at levels existing prior to LIMB retrofit, and (c) technical difficulties attributable to LIMB operation, such as additional slagging and fouling, changes in ash disposal requirements, and an increased particulate load, can be resolved in a cost-effective manner. The primary fuel to be used will be an Ohio bituminous coal having a nominal sulfur content of 3 percent or greater.

  14. LIMB Demonstration Project Extension

    SciTech Connect (OSTI)

    Not Available

    1988-12-15T23:59:59.000Z

    The basic goal of the Limestone Injection Multistage Burner (LIMB) demonstration is to extend LIMB technology development to a full- scale application on a representative wall-fired utility boiler. The successful retrofit of LIMB to an existing boiler is expected to demonstrate that (a) reductions of 50 percent or greater in SO{sub x} and NO{sub x} emissions can be achieved at a fraction of the cost of add-on FGD systems, (b) boiler reliability, operability, and steam production can be maintained at levels existing prior to LIMB retrofit, and (c) technical difficulties attributable to LIMB operation, such as additional slagging and fouling, changes in ash disposal requirements, and an increased particulate load, can be resolved in a cost-effective manner. The primary fuel to be used will be an Ohio bituminous coal having a nominal sulfur content of 3 percent or greater.

  15. LIMB Demonstration Project Extension

    SciTech Connect (OSTI)

    Not Available

    1988-03-15T23:59:59.000Z

    The basic goal of the Limestone Injection Multistage Burner (LIMB) demonstration is to extend LIMB technology development to a full-scale application on a representative wall-fired utility boiler. The successful retrofit of LIMB to an existing boiler is expected to demonstrate that (a) reductions of 50 percent or greater in SO{sub x} and NO{sub x} emissions can be achieved at a fraction of the cost of add-on FGD systems, (b) boiler reliability, operability, and steam production can be maintained at levels existing prior to LIMB retrofit, and (c) technical difficulties attributable to LIMB operation, such as additional slagging and fouling, changes in ash disposal requirements, and an increased particulate load, can be resolved in a cost-effective manner. The primary fuel to be used will be an Ohio bituminous coal having a nominal sulfur content of 3 percent or greater.

  16. LIMB Demonstration Project Extension

    SciTech Connect (OSTI)

    Not Available

    1989-03-15T23:59:59.000Z

    The basic goal of the Limestone Injection Multistage Burner (LIMB) demonstration is to extend LIMB technology development to a full- scale application on a representative wall-fired utility boiler. The successful retrofit of LIMB to an existing boiler is expected to demonstrate that (a) reductions of 50 percent or greater in SO{sub x} and NO{sub x} emissions can be achieved at a fraction of the cost of add-on FGD systems, (b) boiler reliability, operability, and steam production can be maintained at levels existing prior to LIMB retrofit, and (c) technical difficulties attributable to LIMB operation, such as additional slagging and fouling, changes in ash disposal requirements, and an increased particulate load, can be resolved in a cost-effective manner. The primary fuel to be used will be an Ohio bituminous coal having a nominal sulfur content of 3 percent or greater.

  17. Nucla CFB Demonstration Project

    SciTech Connect (OSTI)

    Not Available

    1990-12-01T23:59:59.000Z

    This report documents Colorado-Ute Electric Association's Nucla Circulating Atmospheric Fluidized-Bed Combustion (AFBC) demonstration project. It describes the plant equipment and system design for the first US utility-size circulating AFBC boiler and its support systems. Included are equipment and system descriptions, design/background information and appendices with an equipment list and selected information plus process flow and instrumentation drawings. The purpose of this report is to share the information gathered during the Nucla circulating AFBC demonstration project and present it so that the general public can evaluate the technical feasibility and cost effectiveness of replacing pulverized or stoker-fired boiler units with circulating fluidized-bed boiler units. (VC)

  18. LIMB Demonstration Project Extension

    SciTech Connect (OSTI)

    Not Available

    1991-09-15T23:59:59.000Z

    The basic goal of the Limestone Injection Multistage Burner (LIMB) demonstration is to extend LIMB technology development to a full- scale application on a representative wall-fired utility boiler. The successful retrofit of LIMB to an existing boiler is expected to demonstrate that (1) reductions of 50 percent or greater in SO{sub x} and NO{sub x} emissions can be achieved at a fraction of the cost of add-on FGD systems; (2) boiler reliability, operability, and steam production can be maintained at levels existing prior to LIMB retrofit; and (3) technical difficulties attributable to LIMB operation, such as additional slagging and fouling, changes in ash disposal requirements, and an increased particulate load, can be resolved in a cost-effective manner. The primary fuel to be used will be an Ohio bituminous coal having a nominal sulfur content of 3 percent or greater. The demonstration project consists of several distinct phases: a preliminary phase to develop the LIMB process design applicable to the host boiler, a construction and start-up phase, and an operating and evaluation phase. The first major activity, the development of the Edgewater LIMB design, was completed in January 1986 and detailed engineering is now complete. Major boiler-related components were installed during a September 1986 boiler outage. Start-up activities began in March of 1987 with tuning of the low NO{sub x} burners. Sorbent injection activities were underway as of July 1987. 3 figs.

  19. LIMB Demonstration Project Extension

    SciTech Connect (OSTI)

    Not Available

    1990-09-21T23:59:59.000Z

    The DOE LIMB Demonstration Project Extension is a continuation of the EPA Limestone Injection Multistage Burner (LIMB) Demonstration. EPA ultimately expects to show that LIMB is a low cost control technology capable of producing moderate SO{sub x} and NO{sub x} control (50--60 percent) with applicability for retrofit to the major portion of the existing coal-fired boiler population. The current EPA Wall-Fired LIMB Demonstration is a four-year project that includes design and installation of a LIMB system at the 105-MW Unit 4 boiler at Ohio Edison's Edgewater Station in Lorain, Ohio. LIMB Extension testing continued during the quarter with lignosulfonated hydrated lime, pulverized limestone, and hydrated dolomitic lime while firing 1.8% and 3% sulfur coals. Sulfur dioxide removal efficiencies were equivalent to the results found during EPA, base LIMB testing. Sulfur dioxide removal efficiencies were lower than expected while testing with pulverized limestone without humidification. A slight increase in sulfur capture was noted while injecting pulverized limestone at the 187' elevation and with the humidifier outlet temperature at 145{degree}F.

  20. In situ vitrification application to buried waste: Final report of intermediate field tests at Idaho National Engineering Laboratory

    SciTech Connect (OSTI)

    Callow, R.A.; Weidner, J.R.; Loehr, C.A.; Bates, S.O. (EG and G Idaho, Inc., Idaho Falls, ID (United States)); Thompson, L.E.; McGrail, B.P. (Pacific Northwest Lab., Richland, WA (United States))

    1991-08-01T23:59:59.000Z

    This report describes two in situ vitrification field tests conducted on simulated buried waste pits during June and July 1990 at the Idaho National Engineering Laboratory. In situ vitrification, an emerging technology for in place conversion of contaminated soils into a durable glass and crystalline waste form, is being investigated as a potential remediation technology for buried waste. The overall objective of the two tests was to access the general suitability of the process to remediate waste structures representative of buried waste found at Idaho National Engineering Laboratory. In particular, these tests, as part of a treatability study, were designed to provide essential information on the field performance of the process under conditions of significant combustible and metal wastes and to test a newly developed electrode feed technology. The tests were successfully completed, and the electrode feed technology successfully processed the high metal content waste. Test results indicate the process is a feasible technology for application to buried waste. 33 refs., 109 figs., 39 tabs.

  1. Interim Letter Report - Verification Survey Results for Activities Performed in March 2009 for the Vitrification Test Facility Warehouse at the West Valley Demonstration Project, Ashford, New York

    SciTech Connect (OSTI)

    B.D. Estes

    2009-04-24T23:59:59.000Z

    The objective of the verification activities was to provide independent radiological surveys and data for use by the Department of Energy (DOE) to ensure that the building satisfies the requirements for release without radiological controls.

  2. Bulk Storage Program Compliance Written Program

    E-Print Network [OSTI]

    Pawlowski, Wojtek

    Bulk Storage Program Compliance Written Program Cornell University 5/8/2013 #12;Bulk Storage.......................................................... 5 4.2.2 Aboveground Petroleum Storage Tanks­ University activities/operations designed to prevent releases of oil from Aboveground Petroleum Storage Tanks (ASTs) required to comply with following

  3. Testing and Disposal Strategy for Secondary Wastes from Vitrification of Sodium-Bearing Waste at Idaho Nuclear Technology and Engineering Center

    SciTech Connect (OSTI)

    Herbst, Alan K.

    2002-01-02T23:59:59.000Z

    The Idaho National Engineering and Environmental Laboratory (INEEL) is considering vitrification to process liquid sodium-bearing waste. Preliminary studies were completed to evaluate the potential secondary wastes comprise acidic and caustic scrubber solutions, HEPA filters, activated carbon, and ion exchange media. Possible treatment methods, waste forms, and disposal sites are evaluated from radiological and mercury contamination estimates.

  4. Testing and Disposal Strategy for Secondary Wastes from Vitrification of Sodium-Bearing Waste at the Idaho Nuclear Technology and Engineering Center

    SciTech Connect (OSTI)

    Herbst, Alan Keith

    2002-01-01T23:59:59.000Z

    The Idaho National Engineering and Environmental Laboratory (INEEL) is considering vitrification to process liquid sodium-bearing waste. Preliminary studies were completed to evaluate the potential secondary wastes comprise acidic and caustic scrubber solutions, HEPA filters, activated carbon, and ion exchange media. Possible treatment methods, waste forms, and disposal sites are evaluated from radiological and mercury contamination estimates.

  5. NAVAJO ELECTRIFICATION DEMONSTRATION PROJECT

    SciTech Connect (OSTI)

    Terry W. Battiest

    2008-06-11T23:59:59.000Z

    The Navajo Electrification Demonstration Project (NEDP) is a multi-year project which addresses the electricity needs of the unserved and underserved Navajo Nation, the largest American Indian tribe in the United States. The program serves to cumulatively provide off-grid electricty for families living away from the electricty infrastructure, line extensions for unserved families living nearby (less than 1/2 mile away from) the electricity, and, under the current project called NEDP-4, the construction of a substation to increase the capacity and improve the quality of service into the central core region of the Navajo Nation.

  6. Front-end planning and evaluation for West Valley Demonstration Project completion

    SciTech Connect (OSTI)

    Gramling, J.; Sharma, V. [West Valley Nuclear Services Company, West Valley, NY (United States); Marschke, S. [Raytheon Nuclear, Inc., New York, NY (United States)

    1995-12-31T23:59:59.000Z

    In December 1988, the U.S. Department of Energy and the New York State Energy Research and Development Authority announced their intent to prepare a joint environmental impact statement (EIS) to evaluate alternatives for West Valley Demonstration Project (WVDP) completion and closure and/or long-term maintenance of the Western New York Nuclear Service Center (WNYNSC) in West Valley, New York. Planning was initiated for the eventual closure of the site, even though vitrification of the high-level waste (HLW) stored at the site was, at that time, a number of years in the future. West Valley Nuclear Services Company (WVNSC), the WVDP management and operations contractor, and their architect/engineer, Raytheon Nuclear Incorporated, were authorized to develop characterization studies and engineering evaluations of closure alternatives for the various facilities of the WNYNSC. This paper presents a summary of the status of that effort, including the resolution of unique problems.

  7. Residential Transactive Control Demonstration

    SciTech Connect (OSTI)

    Widergren, Steven E.; Fuller, Jason C.; Marinovici, Maria C.; Somani, Abhishek

    2014-02-19T23:59:59.000Z

    Arguably the most exciting aspect of the smart grid vision is the full participation of end-use resources with all forms of generation and energy storage in the reliable and efficient operation of an electric power system. Engaging all of these resources in a collaborative manner that respects the objectives of each resource, is sensitive to the system and local constraints of electricity flow, and scales to the large number of devices and systems participating is a grand challenge. Distributed decision-making system approaches have been presented and experimentation is underway. This paper reports on the preliminary findings of a residential demand response demonstration that uses the bidding transactions of supply and end-use air conditioning resources communicating with a real-time, 5 minute market to balance the various needs of the participants on a distribution feeder. The nature of the demonstration, the value streams being explored, and the operational scenarios implemented to characterize the system response are summarized along with preliminary findings.

  8. Fuel Cell Demonstration Program

    SciTech Connect (OSTI)

    Gerald Brun

    2006-09-15T23:59:59.000Z

    In an effort to promote clean energy projects and aid in the commercialization of new fuel cell technologies the Long Island Power Authority (LIPA) initiated a Fuel Cell Demonstration Program in 1999 with six month deployments of Proton Exchange Membrane (PEM) non-commercial Beta model systems at partnering sites throughout Long Island. These projects facilitated significant developments in the technology, providing operating experience that allowed the manufacturer to produce fuel cells that were half the size of the Beta units and suitable for outdoor installations. In 2001, LIPA embarked on a large-scale effort to identify and develop measures that could improve the reliability and performance of future fuel cell technologies for electric utility applications and the concept to establish a fuel cell farm (Farm) of 75 units was developed. By the end of October of 2001, 75 Lorax 2.0 fuel cells had been installed at the West Babylon substation on Long Island, making it the first fuel cell demonstration of its kind and size anywhere in the world at the time. Designed to help LIPA study the feasibility of using fuel cells to operate in parallel with LIPA's electric grid system, the Farm operated 120 fuel cells over its lifetime of over 3 years including 3 generations of Plug Power fuel cells (Lorax 2.0, Lorax 3.0, Lorax 4.5). Of these 120 fuel cells, 20 Lorax 3.0 units operated under this Award from June 2002 to September 2004. In parallel with the operation of the Farm, LIPA recruited government and commercial/industrial customers to demonstrate fuel cells as on-site distributed generation. From December 2002 to February 2005, 17 fuel cells were tested and monitored at various customer sites throughout Long Island. The 37 fuel cells operated under this Award produced a total of 712,635 kWh. As fuel cell technology became more mature, performance improvements included a 1% increase in system efficiency. Including equipment, design, fuel, maintenance, installation, and decommissioning the total project budget was approximately $3.7 million.

  9. Jennings Demonstration PLant

    SciTech Connect (OSTI)

    Russ Heissner

    2010-08-31T23:59:59.000Z

    Verenium operated a demonstration plant with a capacity to produce 1.4 million gallons of cellulosic ethanol from agricultural resiues for about two years. During this time, the plant was able to evaluate the technical issues in producing ethanol from three different cellulosic feedstocks, sugar cane bagasse, energy cane, and sorghum. The project was intended to develop a better understanding of the operating parameters that would inform a commercial sized operation. Issues related to feedstock variability, use of hydrolytic enzymes, and the viability of fermentative organisms were evaluated. Considerable success was achieved with pretreatment processes and use of enzymes but challenges were encountered with feedstock variability and fermentation systems. Limited amounts of cellulosic ethanol were produced.

  10. Fusion Power Demonstration III

    SciTech Connect (OSTI)

    Lee, J.D. (ed.)

    1985-07-01T23:59:59.000Z

    This is the third in the series of reports covering the Fusion Power Demonstration (FPD) design study. This volume considers the FPD-III configuration that incorporates an octopole end plug. As compared with the quadrupole end-plugged designs of FPD-I and FPD-II, this octopole configuration reduces the number of end cell magnets and shortens the minimum ignition length of the central cell. The end-cell plasma length is also reduced, which in turn reduces the size and cost of the end cell magnets and shielding. As a contiuation in the series of documents covering the FPD, this report does not stand alone as a design description of FPD-III. Design details of FPD-III subsystems that do not differ significantly from those of the FPD-II configuration are not duplicated in this report.

  11. The Bulk Viscosity of a Pion Gas

    E-Print Network [OSTI]

    Egang Lu; Guy D. Moore

    2011-01-31T23:59:59.000Z

    We compute the bulk viscosity of a gas of pions at temperatures below the QCD crossover temperature, for the physical value of pion mass, to lowest order in chiral perturbation theory. Bulk viscosity is controlled by number-changing processes which become exponentially slow at low temperatures when the pions become exponentially dilute, leading to an exponentially large bulk viscosity zeta ~ (F_0^8/m_\\pi^5) exp(2m_\\pi/T), where F_0 = 93 MeV is the pion decay constant.

  12. Bulk viscosity of N=2* plasma

    E-Print Network [OSTI]

    Alex Buchel; Chris Pagnutti

    2009-03-02T23:59:59.000Z

    We use gauge theory/string theory correspondence to study the bulk viscosity of strongly coupled, mass deformed SU(N_c) N=4 supersymmetric Yang-Mills plasma, also known as N=2^* gauge theory. For a wide range of masses we confirm the bulk viscosity bound proposed in arXiv:0708.3459. For a certain choice of masses, the theory undergoes a phase transition with divergent specific heat c_V ~ |1-T_c/T|^(-1/2). We show that, although bulk viscosity rapidly grows as T -> T_c, it remains finite in the vicinity of the critical point.

  13. INVESTIGATION OF BULK POWER MIDWEST REGION

    E-Print Network [OSTI]

    Laughlin, Robert B.

    INVESTIGATION OF BULK POWER MARKETS MIDWEST REGION November 1, 2000 The analyses and conclusions Energy Regulatory Commission, any individual Commissioner, or the Commission itself #12;3-i Contents Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-3 A. Description of the Midwest

  14. Decision Models for Bulk Energy Transportation Networks

    E-Print Network [OSTI]

    Tesfatsion, Leigh

    emissions prices? How would CO2 regulations impact coal, gas, electricity, & SO2 markets? 3. Disruptions1 Decision Models for Bulk Energy Transportation Networks Electrical Engineering Professor Jim Mc: · integrated fuel, electricity networks · environmental impacts · electricity commodity markets · behavior

  15. Bulk viscous matter-dominated Universes: asymptotic properties

    SciTech Connect (OSTI)

    Avelino, Arturo [Departamento de Física, Campus León, Universidad de Guanajuato, León, Guanajuato (Mexico); García-Salcedo, Ricardo [Centro de Investigacion en Ciencia Aplicada y Tecnologia Avanzada - Legaria del IPN, México D.F. (Mexico); Gonzalez, Tame [Departamento de Ingeniería Civil, División de Ingeniería, Universidad de Guanajuato, Guanajuato (Mexico); Nucamendi, Ulises [Instituto de Física y Matemáticas, Universidad Michoacana de San Nicolás de Hidalgo, Edificio C-3, Ciudad Universitaria, CP. 58040 Morelia, Michoacán (Mexico); Quiros, Israel, E-mail: avelino@fisica.ugto.mx, E-mail: rigarcias@ipn.mx, E-mail: tamegc72@gmail.com, E-mail: ulises@ifm.umich.mx, E-mail: iquiros6403@gmail.com [Departamento de Matemáticas, Centro Universitario de Ciencias Exactas e Ingenierías (CUCEI), Corregidora 500 S.R., Universidad de Guadalajara, 44420 Guadalajara, Jalisco (Mexico)

    2013-08-01T23:59:59.000Z

    By means of a combined use of the type Ia supernovae and H(z) data tests, together with the study of the asymptotic properties in the equivalent phase space — through the use of the dynamical systems tools — we demonstrate that the bulk viscous matter-dominated scenario is not a good model to explain the accepted cosmological paradigm, at least, under the parametrization of bulk viscosity considered in this paper. The main objection against such scenarios is the absence of conventional radiation and matter-dominated critical points in the phase space of the model. This entails that radiation and matter dominance are not generic solutions of the cosmological equations, so that these stages can be implemented only by means of unique and very specific initial conditions, i. e., of very unstable particular solutions. Such a behavior is in marked contradiction with the accepted cosmological paradigm which requires of an earlier stage dominated by relativistic species, followed by a period of conventional non-relativistic matter domination, during which the cosmic structure we see was formed. Also, we found that the bulk viscosity is positive just until very late times in the cosmic evolution, around z < 1. For earlier epochs it is negative, been in tension with the local second law of thermodynamics.

  16. Application of evolved gas analysis to cold-cap reactions of melter feeds for nuclear waste vitrification

    SciTech Connect (OSTI)

    Kruger, Albert A.; Chun, Jaehun; Hrma, Pavel R.; Rodriguez, Carmen P.; Schweiger, Michael J.

    2014-04-30T23:59:59.000Z

    In the vitrification of nuclear wastes, the melter feed (a mixture of nuclear waste and glass-forming and modifying additives) experiences multiple gas-evolving reactions in an electrical glass-melting furnace. We employed the thermogravimetry-gas chromatography-mass spectrometry (TGA-GC-MS) combination to perform evolved gas analysis (EGA). Apart from identifying the gases evolved, we performed quantitative analysis relating the weighed sum of intensities of individual gases linearly proportional with the differential themogravimetry. The proportionality coefficients were obtained by three methods based on the stoichiometry, least squares, and calibration. The linearity was shown to be a good first-order approximation, in spite of the complicated overlapping reactions.

  17. Application of evolved gas analysis to cold-cap reactions of melter feeds for nuclear waste vitrification

    SciTech Connect (OSTI)

    Rodriguez, Carmen P.; Chun, Jaehun; Schweiger, Michael J.; Kruger, Albert A.; Hrma, Pavel R.

    2014-09-01T23:59:59.000Z

    In the vitrification of nuclear wastes, the melter feed (a mixture of nuclear waste and glass forming and modifying additives) experiences multiple gas-evolving reactions in an electrical glass-melting furnace. Foams from the residual gases can significantly alter the melting rate through mass and heat transfers. We employed the thermogravimetry-gas chromatography-mass spectrometry (TGA-GC-MS) combination to perform quantitative evolved gas analysis (EGA) and developed a simple calibration model which correlates the overall mass loss rate with the evolution rates for individual gases. The model parameters are obtained from the least squares analysis, assuming that the gas-evolving reactions are independent. Thus, the EGA adds the ‘chemical identity’ to the reactions indicated by the ‘phenomenological’ kinetic model.

  18. FABRICATION OF A TITANIUM MICROELECTRODE CHIP TO INVESTIGATE BULK TITANIUM

    E-Print Network [OSTI]

    MacDonald, Noel C.

    FABRICATION OF A TITANIUM MICROELECTRODE CHIP TO INVESTIGATE BULK TITANIUM MICROMACHININING, USA Abstract Bulk titanium has a number of attractive characteristics that are favorable of a microelectrode chip for particle trapping and fundamental microfluidic studies. Keywords: bulk titanium

  19. Technology Demonstrations | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Demonstrations Technology Demonstrations Efficient new building technologies can help meet our country's energy goals, stimulate U.S. manufacturing, create jobs, and improve the...

  20. High Heat Flux Thermoelectric Module Using Standard Bulk Material...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Heat Flux Thermoelectric Module Using Standard Bulk Material High Heat Flux Thermoelectric Module Using Standard Bulk Material Presents high heat flux thermoelectric module design...

  1. Regulatory Roadmap Workshop for Federal Bulk Transmission Regulations...

    Open Energy Info (EERE)

    for bulk transmission. Date: Tuesday, 29 July, 2014 - 09:30 - 15:30 Location: NREL Education Center Auditorium Golden, Colorado Groups: Federal Bulk Transmission Regulatory...

  2. Nanostructured High-Temperature Bulk Thermoelectric Energy Conversion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High-Temperature Bulk Thermoelectric Energy Conversion for Efficient Automotive Waste Heat Recovery Nanostructured High-Temperature Bulk Thermoelectric Energy Conversion for...

  3. The influence of molecular orientation on organic bulk heterojunction...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The influence of molecular orientation on organic bulk heterojunction solar cells The influence of molecular orientation on organic bulk heterojunction solar cells Print Monday, 28...

  4. Bulk Hydrogen Storage - Strategic Directions for Hydrogen Delivery...

    Broader source: Energy.gov (indexed) [DOE]

    Bulk Hydrogen Storage - Strategic Directions for Hydrogen Delivery Workshop Bulk Hydrogen Storage - Strategic Directions for Hydrogen Delivery Workshop Targets, barriers and...

  5. Micro benchtop optics by bulk silicon micromachining

    DOE Patents [OSTI]

    Lee, Abraham P. (Walnut Creek, CA); Pocha, Michael D. (Livermore, CA); McConaghy, Charles F. (Livermore, CA); Deri, Robert J. (Pleasanton, CA)

    2000-01-01T23:59:59.000Z

    Micromachining of bulk silicon utilizing the parallel etching characteristics of bulk silicon and integrating the parallel etch planes of silicon with silicon wafer bonding and impurity doping, enables the fabrication of on-chip optics with in situ aligned etched grooves for optical fibers, micro-lenses, photodiodes, and laser diodes. Other optical components that can be microfabricated and integrated include semi-transparent beam splitters, micro-optical scanners, pinholes, optical gratings, micro-optical filters, etc. Micromachining of bulk silicon utilizing the parallel etching characteristics thereof can be utilized to develop miniaturization of bio-instrumentation such as wavelength monitoring by fluorescence spectrometers, and other miniaturized optical systems such as Fabry-Perot interferometry for filtering of wavelengths, tunable cavity lasers, micro-holography modules, and wavelength splitters for optical communication systems.

  6. Modeling the steady-state ISV (in situ vitrification) process: A 3-D finite element analysis of coupled thermal-electric fields

    SciTech Connect (OSTI)

    Langerman, M.A.

    1990-09-01T23:59:59.000Z

    Steady-state modeling considerations for simulating the in situ vitrification (ISV) process are documented based upon the finite element numerical approach. Recommendations regarding boundary condition specifications and mesh discretization are presented. The effects of several parameters on the ISV process response are calculated and the results discussed. The parameters investigated include: (1) electrode depth, (2) ambient temperature, (3) supplied current, (4) electrical conductivity, (5) electrode separation, and (6) soil/waste characterization. 13 refs., 29 figs., 1 tab.

  7. Thermal relics in cosmology with bulk viscosity

    E-Print Network [OSTI]

    A. Iorio; G. Lambiase

    2014-11-28T23:59:59.000Z

    In this paper we discuss some consequences of cosmological models in which the primordial cosmic matter is described by a relativistic imperfect fluid. The latter takes into account the dissipative effects (bulk viscosity) arising from different cooling rates of the fluid components in the expanding Universe. We discuss, in particular, the effects of the bulk viscosity on Big Bang Nucleosynthesis and on the thermal relic abundance of particles, looking at recent results of PAMELA experiment. The latter has determined an anomalous excess of positron events, that cannot be explained by the conventional cosmology and particle physics.

  8. RADIOACTIVE DEMONSTRATIONS OF FLUIDIZED BED STEAM REFORMING AS A SUPPLEMENTARY TREATMENT FOR HANFORD'S LOW ACTIVITY WASTE AND SECONDARY WASTES

    SciTech Connect (OSTI)

    Jantzen, C.; Crawford, C.; Cozzi, A.; Bannochie, C.; Burket, P.; Daniel, G.

    2011-02-24T23:59:59.000Z

    The U.S. Department of Energy's Office of River Protection (ORP) is responsible for the retrieval, treatment, immobilization, and disposal of Hanford's tank waste. Currently there are approximately 56 million gallons of highly radioactive mixed wastes awaiting treatment. A key aspect of the River Protection Project (RPP) cleanup mission is to construct and operate the Waste Treatment and Immobilization Plant (WTP). The WTP will separate the tank waste into high-level and low-activity waste (LAW) fractions, both of which will subsequently be vitrified. The projected throughput capacity of the WTP LAW Vitrification Facility is insufficient to complete the RPP mission in the time frame required by the Hanford Federal Facility Agreement and Consent Order, also known as the Tri-Party Agreement (TPA), i.e. December 31, 2047. Therefore, Supplemental Treatment is required both to meet the TPA treatment requirements as well as to more cost effectively complete the tank waste treatment mission. The Supplemental Treatment chosen will immobilize that portion of the retrieved LAW that is not sent to the WTP's LAW Vitrification facility into a solidified waste form. The solidified waste will then be disposed on the Hanford site in the Integrated Disposal Facility (IDF). In addition, the WTP LAW vitrification facility off-gas condensate known as WTP Secondary Waste (WTP-SW) will be generated and enriched in volatile components such as Cs-137, I-129, Tc-99, Cl, F, and SO4 that volatilize at the vitrification temperature of 1150 C in the absence of a continuous cold cap. The current waste disposal path for the WTP-SW is to recycle it to the supplemental LAW treatment to avoid a large steady state accumulation in the pretreatment-vitrification loop. Fluidized Bed Steam Reforming (FBSR) offers a moderate temperature (700-750 C) continuous method by which LAW and/or WTP-SW wastes can be processed irrespective of whether they contain organics, nitrates, sulfates/sulfides, chlorides, fluorides, volatile radionuclides or other aqueous components. The FBSR technology can process these wastes into a crystalline ceramic (mineral) waste form. The mineral waste form that is produced by co-processing waste with kaolin clay in an FBSR process has been shown to be as durable as LAW glass. Monolithing of the granular FBSR product is being investigated to prevent dispersion during transport or burial/storage but is not necessary for performance. A Benchscale Steam Reformer (BSR) was designed and constructed at the Savannah River National Laboratory (SRNL) to treat actual radioactive wastes to confirm the findings of the non-radioactive FBSR pilot scale tests and to qualify the waste form for applications at Hanford. Radioactive testing commenced in 2010 with a demonstration of Hanford's WTP-SW where Savannah River Site (SRS) High Level Waste (HLW) secondary waste from the Defense Waste Processing Facility (DWPF) was shimmed with a mixture of I-125/129 and Tc-99 to chemically resemble WTP-SW. Ninety six grams of radioactive product were made for testing. The second campaign commenced using SRS LAW chemically trimmed to look like Hanford's LAW. Six hundred grams of radioactive product were made for extensive testing and comparison to the non-radioactive pilot scale tests. The same mineral phases were found in the radioactive and non-radioactive testing.

  9. New Approachesfor Bulk Power System Restoration

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    New Approachesfor Bulk Power System Restoration by AbbasKETABI M.Sc in Electrical EngineeringUniversity of Technology Department of Electrical Engineering, Teheran, Iran Supervisors: SHARIF Professor: Ali M. RANJBAR and complexity. Both factors increase the risk of major power outages. After a blackout, power needs

  10. Bulk viscosity in a cold CFL superfluid

    E-Print Network [OSTI]

    Cristina Manuel; Felipe Llanes-Estrada

    2007-07-18T23:59:59.000Z

    We compute one of the bulk viscosity coefficients of cold CFL quark matter in the temperature regime where the contribution of mesons, quarks and gluons to transport phenomena is Boltzmann suppressed. In that regime dissipation occurs due to collisions of superfluid phonons, the Goldstone modes associated to the spontaneous breaking of baryon symmetry. We first review the hydrodynamics of relativistic superfluids, and remind that there are at least three bulk viscosity coefficients in these systems. We then compute the bulk viscosity coefficient associated to the normal fluid component of the superfluid. In our analysis we use Son's effective field theory for the superfluid phonon, amended to include scale breaking effects proportional to the square of the strange quark mass m_s. We compute the bulk viscosity at leading order in the scale breaking parameter, and find that it is dominated by collinear splitting and joining processes. The resulting transport coefficient is zeta=0.011 m_s^4/T, growing at low temperature T until the phonon fluid description stops making sense. Our results are relevant to study the rotational properties of a compact star formed by CFL quark matter.

  11. JOURNAL OF MICROELECTROMECHANICAL SYSTEMS, VOL. 16, NO. 2, APRIL 2007 289 Bulk Micromachined Titanium Microneedles

    E-Print Network [OSTI]

    Titanium Microneedles E. R. Parker, M. P. Rao, K. L. Turner, C. D. Meinhart, and N. C. MacDonald Abstract used. In this paper, we demonstrate titanium-based microneedle devices developed to address-aspect-ratio titanium bulk microma- chining and multilayer lamination techniques. These devices include embedded

  12. Development And Initial Testing Of Off-Gas Recycle Liquid From The WTP Low Activity Waste Vitrification Process - 14333

    SciTech Connect (OSTI)

    McCabe, Daniel J.; Wilmarth, William R.; Nash, Charles A.; Taylor-Pashow, Kathryn M.; Adamson, Duane J.; Crawford, Charles L.; Morse, Megan M.

    2014-01-07T23:59:59.000Z

    The Waste Treatment and Immobilization Plant (WTP) process flow was designed to pre-treat feed from the Hanford tank farms, separate it into a High Level Waste (HLW) and Low Activity Waste (LAW) fraction and vitrify each fraction in separate facilities. Vitrification of the waste generates an aqueous condensate stream from the off-gas processes. This stream originates from two off-gas treatment unit operations, the Submerged Bed Scrubber (SBS) and the Wet Electrospray Precipitator (WESP). Currently, the baseline plan for disposition of the stream from the LAW melter is to recycle it to the Pretreatment facility where it gets evaporated and processed into the LAW melter again. If the Pretreatment facility is not available, the baseline disposition pathway is not viable. Additionally, some components in the stream are volatile at melter temperatures, thereby accumulating to high concentrations in the scrubbed stream. It would be highly beneficial to divert this stream to an alternate disposition path to alleviate the close-coupled operation of the LAW vitrification and Pretreatment facilities, and to improve long-term throughput and efficiency of the WTP system. In order to determine an alternate disposition path for the LAW SBS/WESP Recycle stream, a range of options are being studied. A simulant of the LAW Off-Gas Condensate was developed, based on the projected composition of this stream, and comparison with pilot-scale testing. The primary radionuclide that vaporizes and accumulates in the stream is Tc-99, but small amounts of several other radionuclides are also projected to be present in this stream. The processes being investigated for managing this stream includes evaporation and radionuclide removal via precipitation and adsorption. During evaporation, it is of interest to investigate the formation of insoluble solids to avoid scaling and plugging of equipment. Key parameters for radionuclide removal include identifying effective precipitation or ion adsorption chemicals, solid-liquid separation methods, and achievable decontamination factors. Results of the radionuclide removal testing indicate that the radionuclides, including Tc-99, can be removed with inorganic sorbents and precipitating agents. Evaporation test results indicate that the simulant can be evaporated to fairly high concentration prior to formation of appreciable solids, but corrosion has not yet been examined.

  13. Direct vitrification of plutonium-containing materials (PCM`s) with the glass material oxidation and dissolution system (GMODS)

    SciTech Connect (OSTI)

    Forsberg, C.W. Beahm, E.C.; Parker, G.W.; Rudolph, J.C.; Haas, P.A.; Malling, G.F.; Elam, K.; Ott, L.

    1995-10-30T23:59:59.000Z

    The end of the cold war has resulted in excess PCMs from nuclear weapons and associated production facilities. Consequently, the US government has undertaken studies to determine how best to manage and dispose of this excess material. The issues include (a) ensurance of domestic health, environment, and safety in handling, storage, and disposition, (b) international arms control agreements with Russia and other countries, and (c) economics. One major set of options is to convert the PCMs into glass for storage or disposal. The chemically inert characteristics of glasses make them a desirable chemical form for storage or disposal of radioactive materials. A glass may contain only plutonium, or it may contain plutonium along with other radioactive materials and nonradioactive materials. GMODS is a new process for the direct conversion of PCMs (i.e., plutonium metal, scrap, and residues) to glass. The plutonium content of these materials varies from a fraction of a percent to pure plutonium. GMODS has the capability to also convert other metals, ceramics, and amorphous solids to glass, destroy organics, and convert chloride-containing materials into a low-chloride glass and a secondary clean chloride salt strewn. This report is the initial study of GMODS for vitrification of PCMs as input to ongoing studies of plutonium management options. Several tasks were completed: initial analysis of process thermodynamics, initial flowsheet analysis, identification of equipment options, proof-of-principle experiments, and identification of uncertainties.

  14. A computational model for viscous fluid flow, heat transfer, and melting in in situ vitrification melt pools

    SciTech Connect (OSTI)

    McHugh, P.R.; Ramshaw, J.D.

    1991-11-01T23:59:59.000Z

    MAGMA is a FORTRAN computer code designed to viscous flow in in situ vitrification melt pools. It models three-dimensional, incompressible, viscous flow and heat transfer. The momentum equation is coupled to the temperature field through the buoyancy force terms arising from the Boussinesq approximation. All fluid properties, except density, are assumed variable. Density is assumed constant except in the buoyancy force terms in the momentum equation. A simple melting model based on the enthalpy method allows the study of the melt front progression and latent heat effects. An indirect addressing scheme used in the numerical solution of the momentum equation voids unnecessary calculations in cells devoid of liquid. Two-dimensional calculations can be performed using either rectangular or cylindrical coordinates, while three-dimensional calculations use rectangular coordinates. All derivatives are approximated by finite differences. The incompressible Navier-Stokes equations are solved using a new fully implicit iterative technique, while the energy equation is differenced explicitly in time. Spatial derivatives are written in conservative form using a uniform, rectangular, staggered mesh based on the marker and cell placement of variables. Convective terms are differenced using a weighted average of centered and donor cell differencing to ensure numerical stability. Complete descriptions of MAGMA governing equations, numerics, code structure, and code verification are provided. 14 refs.

  15. Documentation of Hanford Site independent review of the Hanford Waste Vitrification Plant Preliminary Safety Analysis Report. Revision 3

    SciTech Connect (OSTI)

    Herborn, D.I.

    1993-11-01T23:59:59.000Z

    Westinghouse Hanford Company (WHC) is the Integrating Contractor for the Hanford Waste Vitrification Plant (HWVP) Project, and as such is responsible for preparation of the HWVP Preliminary Safety Analysis Report (PSAR). The HWVP PSAR was prepared pursuant to the requirements for safety analyses contained in US Department of Energy (DOE) Orders 4700.1, Project Management System (DOE 1987); 5480.5, Safety of Nuclear Facilities (DOE 1986a); 5481.lB, Safety Analysis and Review System (DOE 1986b) which was superseded by DOE order 5480-23, Nuclear Safety Analysis Reports, for nuclear facilities effective April 30, 1992 (DOE 1992); and 6430.lA, General Design Criteria (DOE 1989). The WHC procedures that, in large part, implement these DOE requirements are contained in WHC-CM-4-46, Nonreactor Facility Safety Analysis Manual. This manual describes the overall WHC safety analysis process in terms of requirements for safety analyses, responsibilities of the various contributing organizations, and required reviews and approvals.

  16. Modeling direct interband tunneling. I. Bulk semiconductors

    SciTech Connect (OSTI)

    Pan, Andrew, E-mail: pandrew@ucla.edu [Department of Electrical Engineering, University of California, Los Angeles, Los Angeles, California 90095 (United States); Chui, Chi On [Department of Electrical Engineering, University of California, Los Angeles, Los Angeles, California 90095 (United States); California NanoSystems Institute, University of California, Los Angeles, Los Angeles, California 90095 (United States)

    2014-08-07T23:59:59.000Z

    Interband tunneling is frequently studied using the semiclassical Kane model, despite uncertainty about its validity. Revisiting the physical basis of this formula, we find that it neglects coupling to other bands and underestimates transverse tunneling. As a result, significant errors can arise at low and high fields for small and large gap materials, respectively. We derive a simple multiband tunneling model to correct these defects analytically without arbitrary parameters. Through extensive comparison with band structure and quantum transport calculations for bulk InGaAs, InAs, and InSb, we probe the accuracy of the Kane and multiband formulas and establish the superiority of the latter. We also show that the nonlocal average electric field should be used when applying either of these models to nonuniform potentials. Our findings are important for efficient analysis and simulation of bulk semiconductor devices involving tunneling.

  17. Microfabricated bulk wave acoustic bandgap device

    DOE Patents [OSTI]

    Olsson, Roy H.; El-Kady, Ihab F.; McCormick, Frederick; Fleming, James G.; Fleming leg, Carol

    2010-06-08T23:59:59.000Z

    A microfabricated bulk wave acoustic bandgap device comprises a periodic two-dimensional array of scatterers embedded within the matrix material membrane, wherein the scatterer material has a density and/or elastic constant that is different than the matrix material and wherein the periodicity of the array causes destructive interference of the acoustic wave within an acoustic bandgap. The membrane can be suspended above a substrate by an air or vacuum gap to provide acoustic isolation from the substrate. The device can be fabricated using microelectromechanical systems (MEMS) technologies. Such microfabricated bulk wave phononic bandgap devices are useful for acoustic isolation in the ultrasonic, VHF, or UHF regime (i.e., frequencies of order 1 MHz to 10 GHz and higher, and lattice constants of order 100 .mu.m or less).

  18. Microfabricated bulk wave acoustic bandgap device

    DOE Patents [OSTI]

    Olsson, Roy H. (Albuquerque, NM); El-Kady, Ihab F. (Albuquerque, NM); McCormick, Frederick (Albuquerque, NM); Fleming, James G. (Albuquerque, NM); Fleming, legal representative, Carol (Albuquerque, NM)

    2010-11-23T23:59:59.000Z

    A microfabricated bulk wave acoustic bandgap device comprises a periodic two-dimensional array of scatterers embedded within the matrix material membrane, wherein the scatterer material has a density and/or elastic constant that is different than the matrix material and wherein the periodicity of the array causes destructive interference of the acoustic wave within an acoustic bandgap. The membrane can be suspended above a substrate by an air or vacuum gap to provide acoustic isolation from the substrate. The device can be fabricated using microelectromechanical systems (MEMS) technologies. Such microfabricated bulk wave phononic bandgap devices are useful for acoustic isolation in the ultrasonic, VHF, or UHF regime (i.e., frequencies of order 1 MHz to 10 GHz and higher, and lattice constants of order 100 .mu.m or less).

  19. Bulk viscosity in heavy ion collision

    E-Print Network [OSTI]

    Victor Roy; A. K. Chaudhuri

    2012-01-20T23:59:59.000Z

    The effect of a temperature dependent bulk viscosity to entropy density ratio~($\\zeta/s$) along with a constant shear viscosity to entropy density ratio~($\\eta/s$) on the space time evolution of the fluid produced in high energy heavy ion collisions have been studied in a relativistic viscous hydrodynamics model. The boost invariant Israel-Stewart theory of causal relativistic viscous hydrodynamics is used to simulate the evolution of the fluid in 2 spatial and 1 temporal dimension. The dissipative correction to the freezeout distribution for bulk viscosity is calculated using Grad's fourteen moment method. From our simulation we show that the method is applicable only for $\\zeta/s<0.004$.

  20. Shubnikov-de Haas Oscillations in the Bulk Rashba Semiconductor BiTeI

    SciTech Connect (OSTI)

    Bell, C.; Bahramy, M.S.; Murakawa, H.; Checkelsky, J.G.; Arita, R.; Kaneko, Y.; Onose, Y.; Nagaosa, N.; Tokura, Y.; Hwang, H.Y.

    2012-07-11T23:59:59.000Z

    Bulk magnetoresistance quantum oscillations are observed in high quality single crystal samples of BiTeI. This compound shows an extremely large internal spin-orbit coupling, associated with the polarity of the alternating Bi, Te, and I layers perpendicular to the c-axis. The corresponding areas of the inner and outer Fermi surfaces around the A-point show good agreement with theoretical calculations, demonstrating that the intrinsic bulk Rashba-type splitting is nearly 360 meV, comparable to the largest spin-orbit coupling generated in heterostructures and at surfaces.

  1. Demand Response Spinning Reserve Demonstration

    E-Print Network [OSTI]

    2007-01-01T23:59:59.000Z

    F) Enhanced ACP Date RAA ACP Demand Response – SpinningReserve Demonstration Demand Response – Spinning Reservesupply spinning reserve. Demand Response – Spinning Reserve

  2. Manufacturing Demonstration Facility Workshop Videos

    Broader source: Energy.gov [DOE]

    Session recordings from the Manufacturing Demonstration Facility Workshop held in Chicago, Illinois, on March 12, 2012, and simultaneously broadcast as a webinar.

  3. DECONTAMINATION AND BENEFICIAL REUSE OF DREDGED ESTUARINE SEDIMENT: THE WESTINGHOUSE PLASMA VITRIFICATION PROCESS

    E-Print Network [OSTI]

    Brookhaven National Laboratory

    DECONTAMINATION AND BENEFICIAL REUSE OF DREDGED ESTUARINE SEDIMENT: THE WESTINGHOUSE PLASMA of the New York/New Jersey Harbor requires regular dredging. The offshore dumping facility has been closed, dredged material disposal, demonstration testing, process design. 1 McLaughlin, D. F., Fellow Engineer

  4. Ultraviolet laser-induced poling inhibition produces bulk domains in MgO-doped lithium niobate crystals

    SciTech Connect (OSTI)

    Boes, Andreas, E-mail: s3363819@student.rmit.edu.au; Steigerwald, Hendrik; Sivan, Vijay; Mitchell, Arnan [School of Electrical and Computer Engineering, RMIT University, Melbourne, Victoria 3001 (Australia); ARC Center for Ultra-high Bandwidth Devices for Optical Systems (CUDOS), RMIT University, Melbourne, Victoria 3001 (Australia); Yudistira, Didit [School of Electrical and Computer Engineering, RMIT University, Melbourne, Victoria 3001 (Australia); Wade, Scott [Faculty of Science, Engineering and Technology, Swinburne University of Technology, Hawthorn, Victoria 3122 (Australia); Mailis, Sakellaris [Optoelectronics Research Centre, University of Southampton, Highfield, Southampton SO17 1BJ (United Kingdom); Soergel, Elisabeth [Institute of Physics, University of Bonn, Wegelerstr. 8, 53115 Bonn (Germany)

    2014-09-01T23:59:59.000Z

    We report the realization of high-resolution bulk domains achieved using a shallow, structured, domain inverted surface template obtained by UV laser-induced poling inhibition in MgO-doped lithium niobate. The quality of the obtained bulk domains is compared to those of the template and their application for second harmonic generation is demonstrated. The present method enables domain structures with a period length as small as 3??m to be achieved. Furthermore, we propose a potential physical mechanism that leads to the transformation of the surface template into bulk domains.

  5. Hydrogen isotope separation utilizing bulk getters

    DOE Patents [OSTI]

    Knize, Randall J. (Los Angeles, CA); Cecchi, Joseph L. (Lawrenceville, NJ)

    1990-01-01T23:59:59.000Z

    Tritium and deuterium are separated from a gaseous mixture thereof, derived from a nuclear fusion reactor or some other source, by providing a casing with a bulk getter therein for absorbing the gaseous mixture to produce an initial loading of the getter, partially desorbing the getter to produce a desorbed mixture which is tritium-enriched, pumping the desorbed mixture into a separate container, the remaining gaseous loading in the getter being deuterium-enriched, desorbing the getter to a substantially greater extent to produce a deuterium-enriched gaseous mixture, and removing the deuterium-enriched mixture into another container. The bulk getter may comprise a zirconium-aluminum alloy, or a zirconium-vanadium-iron alloy. The partial desorption may reduce the loading by approximately fifty percent. The basic procedure may be extended to produce a multistage isotope separator, including at least one additional bulk getter into which the tritium-enriched mixture is absorbed. The second getter is then partially desorbed to produce a desorbed mixture which is further tritium-enriched. The last-mentioned mixture is then removed from the container for the second getter, which is then desorbed to a substantially greater extent to produce a desorbed mixture which is deuterium-enriched. The last-mentioned mixture is then removed so that the cycle can be continued and repeated. The method of isotope separation is also applicable to other hydrogen isotopes, in that the method can be employed for separating either deuterium or tritium from normal hydrogen.

  6. Hydrogen isotope separation utilizing bulk getters

    DOE Patents [OSTI]

    Knize, Randall J. (Los Angeles, CA); Cecchi, Joseph L. (Lawrenceville, NJ)

    1991-01-01T23:59:59.000Z

    Tritium and deuterium are separated from a gaseous mixture thereof, derived from a nuclear fusion reactor or some other source, by providing a casing with a bulk getter therein for absorbing the gaseous mixture to produce an initial loading of the getter, partially desorbing the getter to produce a desorbed mixture which is tritium-enriched, pumping the desorbed mixture into a separate container, the remaining gaseous loading in the getter being deuterium-enriched, desorbing the getter to a substantially greater extent to produce a deuterium-enriched gaseous mixture, and removing the deuterium-enriched mixture into another container. The bulk getter may comprise a zirconium-aluminum alloy, or a zirconium-vanadium-iron alloy. The partial desorption may reduce the loading by approximately fifty percent. The basic procedure may be extended to produce a multistage isotope separator, including at least one additional bulk getter into which the tritium-enriched mixture is absorbed. The second getter is then partially desorbed to produce a desorbed mixture which is further tritium-enriched. The last-mentioned mixture is then removed from the container for the second getter, which is then desorbed to a substantially greater extent to produce a desorbed mixture which is deuterium-enriched. The last-mentioned mixture is then removed so that the cycle can be continued and repeated. The method of isotope separation is also applicable to other hydrogen isotopes, in that the method can be employed for separating either deuterium or tritium from normal hydrogen.

  7. Accelerating universes driven by bulk particles

    SciTech Connect (OSTI)

    Brito, F.A. [Departamento de Fisica, Universidade Federal de Campina Grande, 58109-970 Campina Grande, Paraiba (Brazil); Cruz, F.F.; Oliveira, J.F.N. [Departamento de Matematica, Universidade Regional do Cariri, 63040-000 Juazeiro do Norte, Ceara (Brazil)

    2005-04-15T23:59:59.000Z

    We consider our universe as a 3d domain wall embedded in a 5d dimensional Minkowski space-time. We address the problem of inflation and late time acceleration driven by bulk particles colliding with the 3d domain wall. The expansion of our universe is mainly related to these bulk particles. Since our universe tends to be permeated by a large number of isolated structures, as temperature diminishes with the expansion, we model our universe with a 3d domain wall with increasing internal structures. These structures could be unstable 2d domain walls evolving to fermi-balls which are candidates to cold dark matter. The momentum transfer of bulk particles colliding with the 3d domain wall is related to the reflection coefficient. We show a nontrivial dependence of the reflection coefficient with the number of internal dark matter structures inside the 3d domain wall. As the population of such structures increases the velocity of the domain wall expansion also increases. The expansion is exponential at early times and polynomial at late times. We connect this picture with string/M-theory by considering BPS 3d domain walls with structures which can appear through the bosonic sector of a five-dimensional supergravity theory.

  8. Hydrogen isotope separation utilizing bulk getters

    DOE Patents [OSTI]

    Knize, R.J.; Cecchi, J.L.

    1991-08-20T23:59:59.000Z

    Tritium and deuterium are separated from a gaseous mixture thereof, derived from a nuclear fusion reactor or some other source, by providing a casing with a bulk getter therein for absorbing the gaseous mixture to produce an initial loading of the getter, partially desorbing the getter to produce a desorbed mixture which is tritium-enriched, pumping the desorbed mixture into a separate container, the remaining gaseous loading in the getter being deuterium-enriched, desorbing the getter to a substantially greater extent to produce a deuterium-enriched gaseous mixture, and removing the deuterium-enriched mixture into another container. The bulk getter may comprise a zirconium-aluminum alloy, or a zirconium-vanadium-iron alloy. The partial desorption may reduce the loading by approximately fifty percent. The basic procedure may be extended to produce a multistage isotope separator, including at least one additional bulk getter into which the tritium-enriched mixture is absorbed. The second getter is then partially desorbed to produce a desorbed mixture which is further tritium-enriched. The last-mentioned mixture is then removed from the container for the second getter, which is then desorbed to a substantially greater extent to produce a desorbed mixture which is deuterium-enriched. The last-mentioned mixture is then removed so that the cycle can be continued and repeated. The method of isotope separation is also applicable to other hydrogen isotopes, in that the method can be employed for separating either deuterium or tritium from normal hydrogen. 4 figures.

  9. The Economic Case for Bulk Energy Storage in Transmission Systems

    E-Print Network [OSTI]

    The Economic Case for Bulk Energy Storage in Transmission Systems with High Percentages to Engineer the Future Electric Energy System #12;#12;The Economic Case for Bulk Energy Storage Economic Case for Bulk Energy Storage in Transmission Sys- tems with High Percentages of Renewable

  10. Bulk viscosity of gauge theory plasma at strong coupling

    E-Print Network [OSTI]

    Alex Buchel

    2007-09-01T23:59:59.000Z

    We propose a lower bound on bulk viscosity of strongly coupled gauge theory plasmas. Using explicit example of the N=2^* gauge theory plasma we show that the bulk viscosity remains finite at a critical point with a divergent specific heat. We present an estimate for the bulk viscosity of QGP plasma at RHIC.

  11. Towards bulk based preconditioning for quantum dotcomputations

    SciTech Connect (OSTI)

    Dongarra, Jack; Langou, Julien; Tomov, Stanimire; Channing,Andrew; Marques, Osni; Vomel, Christof; Wang, Lin-Wang

    2006-05-25T23:59:59.000Z

    This article describes how to accelerate the convergence of Preconditioned Conjugate Gradient (PCG) type eigensolvers for the computation of several states around the band gap of colloidal quantum dots. Our new approach uses the Hamiltonian from the bulk materials constituent for the quantum dot to design an efficient preconditioner for the folded spectrum PCG method. The technique described shows promising results when applied to CdSe quantum dot model problems. We show a decrease in the number of iteration steps by at least a factor of 4 compared to the previously used diagonal preconditioner.

  12. Bulk viscosity effects on elliptic flow

    E-Print Network [OSTI]

    G. S. Denicol; T. Kodama; T. Koide; Ph. Mota

    2009-09-30T23:59:59.000Z

    The effects of bulk viscosity on the elliptic flow $v_{2}$ are studied using realistic equation of state and realistic transport coefficients. We find that thebulk viscosity acts in a non trivial manner on $v_{2}$. At low $p_{T}$, the reduction of $v_{2}$ is even more effective compared to the case of shear viscosity, whereas at high $p_{T}$, an enhancement of $v_{2}$ compared to the ideal case is observed. We argue that this is caused by the competition of the critical behavior of the equation of state and the transport coefficients.

  13. Active neutron multiplicity counting of bulk uranium

    SciTech Connect (OSTI)

    Ensslin, N.; Krick, M.S.; Langner, D.G.; Miller, M.C.

    1991-01-01T23:59:59.000Z

    This paper describes a new nondestructive assay technique being developed to assay bulk uranium containing kilogram quantities of {sup 235}U. The new technique uses neutron multiplicity analysis of data collected with a coincidence counter outfitted with AmLi neutron sources. We have calculated the expected neutron multiplicity count rate and assay precision for this technique and will report on its expected performance as a function of detector design characteristics, {sup 235 }U sample mass, AmLi source strength, and source-to-sample coupling. 11 refs., 2 figs., 2 tabs.

  14. RAPID/Bulk Transmission | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere I GeothermalPotentialBiopowerSolidGenerationMethod JumpGeorgia: EnergyOnline Permitting SystemsBulk

  15. MECHANISMS OF PHASE FORMATION IN THE VITRIFICATION OF HIGH-FERROUS SAVANNAH RIVER SITE SB2 HLW SLUDGE SURROGATE - 9300

    SciTech Connect (OSTI)

    Marra, J

    2008-08-27T23:59:59.000Z

    Phase formation mechanisms associated with the vitrification of high-ferrous Savannah River Site (SRS) Sludge Batch 2 (SB2) high level waste surrogate were studied by infrared spectroscopy (IRS) and X-ray diffraction (XRD). Two mixtures at 50 wt% waste loading with commercially available Frit 320 (Li{sub 2}O - 8 wt %, B{sub 2}O{sub 3} - 8 wt %, Na{sub 2}O - 12 wt %, SiO{sub 2} - 72 wt %) and batch chemicals (LiOH {center_dot} H{sub 2}O, H{sub 3}BO{sub 3}, NaNO{sub 3}, SiO{sub 2}) to represent the frit formulation were prepared as slurries with a water content of {approx}50 wt%. The mixtures were air-dried at a temperature of 115 C and heat-treated at 500, 700, 900, 1000, 1100, 1200, and 1300 C for 1 hr at each temperature. Infrared spectra and XRD patterns of the products produced at each temperature were recorded. In both mixtures prepared using frit and batch chemicals to represent the frit, phase formation reactions were completed within the temperature range between 900 and 1000 C. However, residual quartz was still present in glass produced from the mixture with batch chemicals even at 1100 C. Although, the phase composition and structure of the glassy products obtained from both mixtures at temperatures over 1000 C were similar, the products obtained from the mixture using actual frit were more homogeneous than those from the mixture with batch chemicals. Thus, the use of frit rather than batch chemicals reduced the temperature range of phase formation and provided for production of higher quality glass.

  16. Balancing Cost and Risk by Optimizing the High-Level Waste and Low-Activity Waste Vitrification

    SciTech Connect (OSTI)

    Hrma, Pavel R.; Vienna, John D.

    2000-02-23T23:59:59.000Z

    In the currently used melters, the waste loading for nearly all high-level waste (HLW) is limited by crystallization. Above a certain level of waste loading, precipitation, settling, and accumulation of crystalline phases can cause severe processing problems and shorten the melter lifetime. To decrease the cost without putting the vitrification process at an unreasonable risk, several options, such as developing melters that operate above the liquidus temperature of glass, can be considered. Alternatively, if the melter is stirred, either mechanically, by bubbling, or by temperature gradients in induction heating, the melt can contain a substantial fraction of a crystalline phase that would not settle because it would be removed from the melter with glass. In addition, an induction melter can be nearly completely drained. For current melters that operate at a fixed temperature of 1150C, optimized glass formulation within currently accepted constaints has been developed. This approach is based on mathematically formulated relationships between glass properties and glass composition. Finally, re-evaluating the liquidus-temperature constraint, which may be unnecessarily restrictive for some HLWs, has recently been investigated. An attempt is being made to assess the rate of settling of crystalline phases in the melter and evaluate the risk for melter operation. Based on a reliable estimate of such a risk, waste loading could be increased, and a substantial saving can accrue. For low-activity waste (LAW), the waste loading in glass is limited either by the product quality or by segregation of sulfate during melting. The formulation of constraints on LAW glass in terms of relevant properties has not been completed, and no property-composition relationships have been established so far for this type of waste glass.

  17. RADIOACTIVE DEMONSTRATIONS OF FLUIDIZED BED STEAM REFORMING WITH ACUTAL HANFORD LOW ACTIVITY WASTES VERIFYING FBSR AS A SUPPLEMENTARY TREATMENT

    SciTech Connect (OSTI)

    Jantzen, C.; Crawford, C.; Burket, P.; Bannochie, C.; Daniel, G.; Nash, C.; Cozzi, A.; Herman, C.

    2012-01-12T23:59:59.000Z

    The U.S. Department of Energy's Office of River Protection is responsible for the retrieval, treatment, immobilization, and disposal of Hanford's tank waste. Currently there are approximately 56 million gallons of highly radioactive mixed wastes awaiting treatment. A key aspect of the River Protection Project cleanup mission is to construct and operate the Waste Treatment and Immobilization Plant (WTP). The WTP will separate the tank waste into high-level waste (HLW) and low-activity waste (LAW) fractions, both of which will subsequently be vitrified. The projected throughput capacity of the WTP LAW Vitrification Facility is insufficient to complete the cleanup mission in the time frame required by the Hanford Federal Facility Agreement and Consent Order, also known as the Tri-Party Agreement (TPA). Therefore, Supplemental Treatment is required both to meet the TPA treatment requirements as well as to more cost effectively complete the tank waste treatment mission. Fluidized Bed Steam Reforming (FBSR) is one of the supplementary treatments being considered. FBSR offers a moderate temperature (700-750 C) continuous method by which LAW and other secondary wastes can be processed irrespective of whether they contain organics, nitrates/nitrites, sulfates/sulfides, chlorides, fluorides, and/or radio-nuclides like I-129 and Tc-99. Radioactive testing of Savannah River LAW (Tank 50) shimmed to resemble Hanford LAW and actual Hanford LAW (SX-105 and AN-103) have produced a ceramic (mineral) waste form which is the same as the non-radioactive waste simulants tested at the engineering scale. The radioactive testing demonstrated that the FBSR process can retain the volatile radioactive components that cannot be contained at vitrification temperatures. The radioactive and nonradioactive mineral waste forms that were produced by co-processing waste with kaolin clay in an FBSR process are shown to be as durable as LAW glass.

  18. Toms Creek IGCC Demonstration Project

    SciTech Connect (OSTI)

    Virr, M.J.

    1992-01-01T23:59:59.000Z

    The Toms Creek Integrated Gasification Combined Cycle (IGCC) Demonstration Project was selected by DOE in September 1991 to participate in Round Four of the Clean Coal Technology Demonstration Program. The project will demonstrate a simplified IGCC process consisting of an air-blown, fluidized-bed gasifier (Tampella U-Gas), a gas cooler/steam generator, and a hot gas cleanup system in combination with a gas turbine modified for use with a low-Btu content fuel and a conventional steam bottoming cycle. The demonstration plant will be located at the Toms Creek coal mine near Coeburn, Wise County, Virginia. Participants in the project are Tampella Power Corporation and Coastal Power Production Company. The plant will use 430 tons per day of locally mined bituminous coal to produce 55 MW of power from the gasification section of the project. A modern pulverized coal fired unit will be located adjacent to the Demonstration Project producing an additional 150 MW. A total 190 MW of power will be delivered to the electric grid at the completion of the project. In addition, 50,000 pounds per hour of steam will be exported to be used in the nearby coal preparation plant. Dolomite is used for in-bed gasifier sulfur capture and downs cleanup is accomplished in a fluidized-bed of regenerative zinc titanate. Particulate clean-up, before the gas turbine, will be performed by high temperature candle filters (1020[degree]F). The demonstration plant heat rate is estimated to be 8,700 Btu/kWh. The design of the project goes through mid 1995, with site construction activities commencing late in 1995 and leading to commissioning and start-up by the end of 1997. This is followed by a three year demonstration period.

  19. Toms Creek IGCC Demonstration Project

    SciTech Connect (OSTI)

    Virr, M.J.

    1992-11-01T23:59:59.000Z

    The Toms Creek Integrated Gasification Combined Cycle (IGCC) Demonstration Project was selected by DOE in September 1991 to participate in Round Four of the Clean Coal Technology Demonstration Program. The project will demonstrate a simplified IGCC process consisting of an air-blown, fluidized-bed gasifier (Tampella U-Gas), a gas cooler/steam generator, and a hot gas cleanup system in combination with a gas turbine modified for use with a low-Btu content fuel and a conventional steam bottoming cycle. The demonstration plant will be located at the Toms Creek coal mine near Coeburn, Wise County, Virginia. Participants in the project are Tampella Power Corporation and Coastal Power Production Company. The plant will use 430 tons per day of locally mined bituminous coal to produce 55 MW of power from the gasification section of the project. A modern pulverized coal fired unit will be located adjacent to the Demonstration Project producing an additional 150 MW. A total 190 MW of power will be delivered to the electric grid at the completion of the project. In addition, 50,000 pounds per hour of steam will be exported to be used in the nearby coal preparation plant. Dolomite is used for in-bed gasifier sulfur capture and downs cleanup is accomplished in a fluidized-bed of regenerative zinc titanate. Particulate clean-up, before the gas turbine, will be performed by high temperature candle filters (1020{degree}F). The demonstration plant heat rate is estimated to be 8,700 Btu/kWh. The design of the project goes through mid 1995, with site construction activities commencing late in 1995 and leading to commissioning and start-up by the end of 1997. This is followed by a three year demonstration period.

  20. The Bulk Channel in Thermal Gauge Theories

    E-Print Network [OSTI]

    Harvey B. Meyer

    2010-02-17T23:59:59.000Z

    We investigate the thermal correlator of the trace of the energy-momentum tensor in the SU(3) Yang-Mills theory. Our goal is to constrain the spectral function in that channel, whose low-frequency part determines the bulk viscosity. We focus on the thermal modification of the spectral function, $\\rho(\\omega,T)-\\rho(\\omega,0)$. Using the operator-product expansion we give the high-frequency behavior of this difference in terms of thermodynamic potentials. We take into account the presence of an exact delta function located at the origin, which had been missed in previous analyses. We then combine the bulk sum rule and a Monte-Carlo evaluation of the Euclidean correlator to determine the intervals of frequency where the spectral density is enhanced or depleted by thermal effects. We find evidence that the thermal spectral density is non-zero for frequencies below the scalar glueball mass $m$ and is significantly depleted for $m\\lesssim\\omega\\lesssim 3m$.

  1. LIMB demonstration project extension and Coolside demonstration: A DOE assessment

    SciTech Connect (OSTI)

    National Energy Technology Laboratory

    2000-04-30T23:59:59.000Z

    The goal of the US Department of Energy (DOE) Clean Coal Technology (CCT) program is to furnish the energy marketplace with a number of advanced, more efficient, and environmentally responsible coal utilization technologies through demonstration projects. These projects seek to establish the commercial feasibility of the most promising advanced coal technologies that have already reached the proof-of-concept stage. This document serves as a DOE post-project assessment of the CCT Round 1 project ``LIMB Demonstration Project Extension and Coolside Demonstration'', described in a report to Congress (Babcock and Wilcox 1987), a paper by DePero et al. (1992), and in a report by Goots et al. (1992). The original limestone injection multistage burner (LIMB) demonstration work was conducted by Babcock and Wilcox Company (B and W) beginning in 1984, under the sponsorship of the US Environmental Protection Agency (EPA) and the State of Ohio Coal Development Office (OCDO). In 1987, B and W and the Ohio Edison Company agreed to extend the full-scale demonstration of LIMB technology under the sponsorship of DOE through its CCT Program, and with support from OCDO and Consolidation Coal Company, now known as CONSOL. In a separate effort, CONSOL had been developing another flue gas desulfurization (FGD) technology known as the Coolside process. Both LIMB and Coolside use sorbent injection to remove SO{sub 2}. The LIMB process injects the sorbent into the furnace and the Coolside injects the sorbent into the flue gas duct. In addition, LIMB uses low-NO{sub x} burners to reduce NO{sub x} emissions; hence it is categorized as a combination SO{sub 2}/NO{sub x} control technology. To take advantage of synergism between the two processes, the CCT project was structured to incorporate demonstration of both the LIMB and Coolside processes. Coolside testing was accomplished between July 1989 and February 1990, and the LIMB Extension test program was conducted between April 1990 and August 1991. The host site for both tests was the 105 MWe coal-fired Unit 4 at Ohio Edison's Edgewater Station in Lorain, Ohio. The major performance objectives of this project were successfully achieved, with SO{sub 2} emissions reductions of up to 70% demonstrated in both processes.

  2. Buried Waste Integrated Demonstration Plan

    SciTech Connect (OSTI)

    Kostelnik, K.M.

    1991-12-01T23:59:59.000Z

    This document presents the plan of activities for the Buried Waste Integrated Demonstration (BWID) program which supports the environmental restoration (ER) objectives of the Department of Energy (DOE) Complex. Discussed in this plan are the objectives, organization, roles and responsibilities, and the process for implementing and managing BWID. BWID is hosted at the Idaho National Engineering Laboratory (INEL), but involves participants from throughout the DOE Complex, private industry, universities, and the international community. These participants will support, demonstrate, and evaluate a suite of advanced technologies representing a comprehensive remediation system for the effective and efficient remediation of buried waste. The processes for identifying technological needs, screening candidate technologies for applicability and maturity, selecting appropriate technologies for demonstration, field demonstrating, evaluation of results and transferring technologies to environmental restoration programs are also presented. This document further describes the elements of project planning and control that apply to BWID. It addresses the management processes, operating procedures, programmatic and technical objectives, and schedules. Key functions in support of each demonstration such as regulatory coordination, safety analyses, risk evaluations, facility requirements, and data management are presented.

  3. Vitrification of cesium-loaded crystalline silicotitanate (CST) in the shielded cells melter

    SciTech Connect (OSTI)

    Andrews, M.K. [Westinghouse Savannah River Company, AIKEN, SC (United States); Fellinger, T.L.; Ferrara, D.M.; Harbour, J.R.; Herman, D.T.

    1997-09-30T23:59:59.000Z

    Through the Tanks Focus Area, the Savannah River Technology Center (SRTC) and the Oak Ridge National Laboratory participated in a joint project in which supernate waste from the Melton Valley Storage Tanks at Oak Ridge was treated by passage through a crystalline silicotitanate (CST) ion exchange column. CST was designed to sorb Cs- 137, Sr-90 and several other radionuclides from highly alkaline solutions containing large quantities of sodium.2 After demonstrating the effectiveness of CST as an ion exchange medium, ORNL shipped some of the loaded sorbent to SRTC where it was mixed with glass formers and processed in a joule-heated melter within the SRTC Shielded Cells. This report details the results of the melter run, along with the preparations that were required to complete the campaign.

  4. Propane Vehicle Demonstration Grant Program

    SciTech Connect (OSTI)

    Jack Mallinger

    2004-08-27T23:59:59.000Z

    Project Description: Propane Vehicle Demonstration Grants The Propane Vehicle Demonstration Grants was established to demonstrate the benefits of new propane equipment. The US Department of Energy, the Propane Education & Research Council (PERC) and the Propane Vehicle Council (PVC) partnered in this program. The project impacted ten different states, 179 vehicles, and 15 new propane fueling facilities. Based on estimates provided, this project generated a minimum of 1,441,000 new gallons of propane sold for the vehicle market annually. Additionally, two new off-road engines were brought to the market. Projects originally funded under this project were the City of Portland, Colorado, Kansas City, Impco Technologies, Jasper Engines, Maricopa County, New Jersey State, Port of Houston, Salt Lake City Newspaper, Suburban Propane, Mutual Liquid Propane and Ted Johnson.

  5. HIGH LEVEL WASTE (HLW) VITRIFICATION EXPERIENCE IN THE US: APPLICATION OF GLASS PRODUCT/PROCESS CONTROL TO OTHERHLW AND HAZARDOUS WASTES

    SciTech Connect (OSTI)

    Jantzen, C; James Marra, J

    2007-09-17T23:59:59.000Z

    Vitrification is currently the most widely used technology for the treatment of high level radioactive wastes (HLW) throughout the world. At the Savannah River Site (SRS) actual HLW tank waste has successfully been processed to stringent product and process constraints without any rework into a stable borosilicate glass waste since 1996. A unique 'feed forward' statistical process control (SPC) has been used rather than statistical quality control (SQC). In SPC, the feed composition to the melter is controlled prior to vitrification. In SQC, the glass product is sampled after it is vitrified. Individual glass property models form the basis for the 'feed forward' SPC. The property models transform constraints on the melt and glass properties into constraints on the feed composition. The property models are mechanistic and depend on glass bonding/structure, thermodynamics, quasicrystalline melt species, and/or electron transfers. The mechanistic models have been validated over composition regions well outside of the regions for which they were developed because they are mechanistic. Mechanistic models allow accurate extension to radioactive and hazardous waste melts well outside the composition boundaries for which they were developed.

  6. LIMB Demonstration Project Extension and Coolside Demonstration. [Final report

    SciTech Connect (OSTI)

    Goots, T.R.; DePero, M.J.; Nolan, P.S.

    1992-11-10T23:59:59.000Z

    This report presents results from the limestone Injection Multistage Burner (LIMB) Demonstration Project Extension. LIMB is a furnace sorbent injection technology designed for the reduction of sulfur dioxide (SO{sub 2}) and nitrogen oxides (NO{sub x}) emissions from coal-fired utility boilers. The testing was conducted on the 105 Mwe, coal-fired, Unit 4 boiler at Ohio Edison`s Edgewater Station in Lorain, Ohio. In addition to the LIMB Extension activities, the overall project included demonstration of the Coolside process for S0{sub 2} removal for which a separate report has been issued. The primary purpose of the DOE LIMB Extension testing, was to demonstrate the generic applicability of LIMB technology. The program sought to characterize the S0{sub 2} emissions that result when various calcium-based sorbents are injected into the furnace, while burning coals having sulfur content ranging from 1.6 to 3.8 weight percent. The four sorbents used included calcitic limestone, dolomitic hydrated lime, calcitic hydrated lime, and calcitic hydrated lime with a small amount of added calcium lignosulfonate. The results include those obtained for the various coal/sorbent combinations and the effects of the LIMB process on boiler and plant operations.

  7. Rotary adsorbers for continuous bulk separations

    DOE Patents [OSTI]

    Baker, Frederick S. (Oak Ridge, TN)

    2011-11-08T23:59:59.000Z

    A rotary adsorber for continuous bulk separations is disclosed. The rotary adsorber includes an adsorption zone in fluid communication with an influent adsorption fluid stream, and a desorption zone in fluid communication with a desorption fluid stream. The fluid streams may be gas streams or liquid streams. The rotary adsorber includes one or more adsorption blocks including adsorbent structure(s). The adsorbent structure adsorbs the target species that is to be separated from the influent fluid stream. The apparatus includes a rotary wheel for moving each adsorption block through the adsorption zone and the desorption zone. A desorption circuit passes an electrical current through the adsorbent structure in the desorption zone to desorb the species from the adsorbent structure. The adsorbent structure may include porous activated carbon fibers aligned with their longitudinal axis essentially parallel to the flow direction of the desorption fluid stream. The adsorbent structure may be an inherently electrically-conductive honeycomb structure.

  8. DEVELOPMENT OF THE BULK TRITIUM SHIPPING PACKAGING

    SciTech Connect (OSTI)

    Blanton, P.; Eberl, K.

    2008-09-14T23:59:59.000Z

    A new radioactive shipping packaging for transporting bulk quantities of tritium, the Bulk Tritium Shipping Package (BTSP), has been designed for the Department of Energy (DOE) as a replacement for a package designed in the early 1970s. This paper summarizes significant design features and describes how the design satisfies the regulatory safety requirements of the Code of Federal Regulations and the International Atomic Energy Agency. The BTSP design incorporates many improvements over its predecessor by implementing improved testing, handling, and maintenance capabilities, while improving manufacturability and incorporating new engineered materials. This paper also discusses the results from testing of the BTSP to 10 CFR 71 Normal Conditions of Transport and Hypothetical Accident Condition events. The programmatic need of the Department of Energy (DOE) to ship bulk quantities of tritium has been satisfied since the late 1970s by the UC-609 shipping package. The current Certificate of Conformance for the UC-609, USA/9932/B(U) (DOE), will expire in late 2011. Since the UC-609 was not designed to meet current regulatory requirements, it will not be recertified and thereby necessitates a replacement Type B shipping package for continued DOE tritium shipments in the future. A replacement tritium packaging called the Bulk Tritium Shipping Package (BTSP) is currently being designed and tested by Savannah River National Laboratory (SRNL). The BTSP consists of two primary assemblies, an outer Drum Assembly and an inner Containment Vessel Assembly (CV), both designed to mitigate damage and to protect the tritium contents from leaking during the regulatory Hypothetical Accident Condition (HAC) events and during Normal Conditions of Transport (NCT). During transport, the CV rests on a silicone pad within the Drum Liner and is covered with a thermal insulating disk within the insulated Drum Assembly. The BTSP packaging weighs approximately 500 lbs without contents and is 50-1/2 inches high by 24-1/2 inches in outside diameter. With contents the gross weight of the BTSP is 650 lbs. The BTSP is designed for the safe shipment of 150 grams of tritium in a solid or gaseous state. To comply with the federal regulations that govern Type B shipping packages, the BTSP is designed so that it will not lose tritium at a rate greater than the limits stated in 10CFR 71.51 of 10{sup -6} A2 per hour for the 'Normal Conditions of Transport' (NCT) and an A2 in 1 week under 'Hypothetical Accident Conditions' (HAC). Additionally, since the BTSP design incorporates a valve as part of the tritium containment boundary, secondary containment features are incorporated in the CV Lid to protect against gas leakage past the valve as required by 10CFR71.43(e). This secondary containment boundary is designed to provide the same level of containment as the primary containment boundary when subjected to the HAC and NCT criteria.

  9. Organic hybrid planar-nanocrystalline bulk heterojunctions

    DOE Patents [OSTI]

    Forrest, Stephen R.; Yang, Fan

    2013-04-09T23:59:59.000Z

    A photosensitive optoelectronic device having an improved hybrid planar bulk heterojunction includes a plurality of photoconductive materials disposed between the anode and the cathode. The photoconductive materials include a first continuous layer of donor material and a second continuous layer of acceptor material. A first network of donor material or materials extends from the first continuous layer toward the second continuous layer, providing continuous pathways for conduction of holes to the first continuous layer. A second network of acceptor material or materials extends from the second continuous layer toward the first continuous layer, providing continuous pathways for conduction of electrons to the second continuous layer. The first network and the second network are interlaced with each other. At least one other photoconductive material is interspersed between the interlaced networks. This other photoconductive material or materials has an absorption spectra different from the donor and acceptor materials.

  10. On bulk viscosity and moduli decay

    E-Print Network [OSTI]

    M. Laine

    2010-11-21T23:59:59.000Z

    This pedagogically intended lecture, one of four under the header "Basics of thermal QCD", reviews an interesting relationship, originally pointed out by Bodeker, that exists between the bulk viscosity of Yang-Mills theory (of possible relevance to the hydrodynamics of heavy ion collision experiments) and the decay rate of scalar fields coupled very weakly to a heat bath (appearing in some particle physics inspired cosmological scenarios). This topic serves, furthermore, as a platform on which a number of generic thermal field theory concepts are illustrated. The other three lectures (on the QCD equation of state and the rates of elastic as well as inelastic processes experienced by heavy quarks) are recapitulated in brief encyclopedic form.

  11. DEPLOYMENT OF THE BULK TRITIUM SHIPPING PACKAGE

    SciTech Connect (OSTI)

    Blanton, P.

    2013-10-10T23:59:59.000Z

    A new Bulk Tritium Shipping Package (BTSP) was designed by the Savannah River National Laboratory to be a replacement for a package that has been used to ship tritium in a variety of content configurations and forms since the early 1970s. The BTSP was certified by the National Nuclear Safety Administration in 2011 for shipments of up to 150 grams of Tritium. Thirty packages were procured and are being delivered to various DOE sites for operational use. This paper summarizes the design features of the BTSP, as well as associated engineered material improvements. Fabrication challenges encountered during production are discussed as well as fielding requirements. Current approved tritium content forms (gas and tritium hydrides), are reviewed, as well as, a new content, tritium contaminated water on molecular sieves. Issues associated with gas generation will also be discussed.

  12. Organic hybrid planar-nanocrystalline bulk heterojunctions

    DOE Patents [OSTI]

    Forrest, Stephen R. (Ann Arbor, MI); Yang, Fan (Piscataway, NJ)

    2011-03-01T23:59:59.000Z

    A photosensitive optoelectronic device having an improved hybrid planar bulk heterojunction includes a plurality of photoconductive materials disposed between the anode and the cathode. The photoconductive materials include a first continuous layer of donor material and a second continuous layer of acceptor material. A first network of donor material or materials extends from the first continuous layer toward the second continuous layer, providing continuous pathways for conduction of holes to the first continuous layer. A second network of acceptor material or materials extends from the second continuous layer toward the first continuous layer, providing continuous pathways for conduction of electrons to the second continuous layer. The first network and the second network are interlaced with each other. At least one other photoconductive material is interspersed between the interlaced networks. This other photoconductive material or materials has an absorption spectra different from the donor and acceptor materials.

  13. NUCLEAR WASTE GLASSES CONTINUOUS MELTING AND BULK VITRIFICAITON

    SciTech Connect (OSTI)

    KRUGER AA; HRMA PR

    2008-03-24T23:59:59.000Z

    This contribution addresses various aspects of nuclear waste vitrification. Nuclear wastes have a variety of components and composition ranges. For each waste composition, the glass must be formulated to possess acceptable processing and product behavior defined in terms of physical and chemical properties that guarantee the glass can be easily made and resist environmental degradation. Glass formulation is facilitated by developing property-composition models, and the strategy of model development and application is reviewed. However, the large variability of waste compositions presents numerous additional challenges: insoluble solids and molten salts may segregate; foam may hinder heat transfer and slow down the process; molten salts may accumulate in container refractory walls; the glass on cooling may precipitate crystalline phases. These problems need targeted exploratory research. Examples of specific problems and their possible solutions are discussed.

  14. Macroscopic and direct light propulsion of bulk graphene material

    E-Print Network [OSTI]

    Zhang, Tengfei; Wu, Yingpeng; Xiao, Peishuang; Yi, Ningbo; Lu, Yanhong; Ma, Yanfeng; Huang, Yi; Zhao, Kai; Yan, Xiao-Qing; Liu, Zhi-Bo; Tian, Jian-Guo; Chen, Yongsheng

    2015-01-01T23:59:59.000Z

    It has been a great challenge to achieve the direct light manipulation of matter on a bulk scale. In this work, the direct light propulsion of matter was observed on a macroscopic scale for the first time using a bulk graphene based material. The unique structure and properties of graphene and the morphology of the bulk graphene material make it capable of not only absorbing light at various wavelengths but also emitting energetic electrons efficiently enough to drive the bulk material following Newtonian mechanics. Thus, the unique photonic and electronic properties of individual graphene sheets are manifested in the response of the bulk state. These results offer an exciting opportunity to bring about bulk scale light manipulation with the potential to realize long-sought proposals in areas such as the solar sail and space transportation driven directly by sunlight.

  15. Jump Chaotic Behaviour of Ultra Low Loss Bulk Acoustic Wave Cavities

    E-Print Network [OSTI]

    Maxim Goryachev; Warrick G. Farr; Serge Galliou; Michael E. Tobar

    2014-06-16T23:59:59.000Z

    We demonstrate a previously unobserved nonlinear phenomenon in an ultra-low loss quartz Bulk Acoustic Wave cavity ($Q>3\\times10^9$), which only occurs below 20 milli-Kelvin in temperature and under relatively weak pumping. The phenomenon reveals the emergence of several stable equilibria (at least two foci and two nodes) and jumps between these quasi states at random times. The degree of this randomness as well as separations between levels can be controlled by the frequency of the incident carrier signal. It is demonstrated that the nature of the effect lays beyond the standard Duffing model.

  16. Jump chaotic behaviour of ultra low loss bulk acoustic wave cavities

    SciTech Connect (OSTI)

    Goryachev, Maxim, E-mail: maxim.goryachev@uwa.edu.au; Farr, Warrick G.; Tobar, Michael E. [ARC Centre of Excellence for Engineered Quantum Systems, University of Western Australia, 35 Stirling Highway, Crawley WA 6009 (Australia); Galliou, Serge [Department of Time and Frequency, FEMTO-ST Institute, ENSMM, 26 Chemin de l'Épitaphe 25000 Besançon (France)

    2014-08-11T23:59:59.000Z

    We demonstrate a previously unobserved nonlinear phenomenon in an ultra-low loss quartz bulk acoustic wave cavity (Q>3>10{sup 9}), which only occurs below 20 mK in temperature and under relatively weak pumping. The phenomenon reveals the emergence of several stable equilibria (at least two foci and two nodes) and jumps between these quasi states at random times. The degree of this randomness as well as separations between levels can be controlled by the frequency of the incident carrier signal. It is demonstrated that the nature of the effect lies beyond the standard Duffing model.

  17. ENVIRONMENTAL BIOTECHNOLOGY Effect of bulk liquid BOD concentration on activity

    E-Print Network [OSTI]

    Nerenberg, Robert

    BOD. FISH results indicated increasing abundance of heterotrophs with increasing bulk liquid BOD); however, competition of heterotrophs and nitrifiers in biofilm systems limits nitrification rates

  18. Optimization Online - Real-Time Dispatchability of Bulk Power ...

    E-Print Network [OSTI]

    Wei Wei

    2015-03-16T23:59:59.000Z

    Mar 16, 2015 ... Real-Time Dispatchability of Bulk Power Systems with Volatile Renewable Generations. Wei Wei (wei-wei04 ***at*** mails.tsinghua.edu.cn)

  19. Economic manufacturing of bulk metallic glass compositions by microalloying

    DOE Patents [OSTI]

    Liu, Chain T.

    2003-05-13T23:59:59.000Z

    A method of making a bulk metallic glass composition includes the steps of:a. providing a starting material suitable for making a bulk metallic glass composition, for example, BAM-11; b. adding at least one impurity-mitigating dopant, for example, Pb, Si, B, Sn, P, to the starting material to form a doped starting material; and c. converting the doped starting material to a bulk metallic glass composition so that the impurity-mitigating dopant reacts with impurities in the starting material to neutralize deleterious effects of the impurities on the formation of the bulk metallic glass composition.

  20. New nano structure approaches for bulk thermoelectric materials

    E-Print Network [OSTI]

    Kim, Jeonghoon

    2010-01-01T23:59:59.000Z

    in bulk thermoelectric materials", M. Mater. Res. Soc.Thermoelectricity", Materials Reserach Society Symposium,Johnson, D. C. , Eds. Materials Research Society: Boston,

  1. Factors influencing photocurrent generation in organic bulk heterojunc...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Factors influencing photocurrent generation in organic bulk heterojunction solar cells: interfacial energetics and blend microstructure April 29, 2009 at 3pm36-428 Jenny Nelson...

  2. Nanostructured High-Temperature Bulk Thermoelectric Energy Conversion...

    Broader source: Energy.gov (indexed) [DOE]

    Nanostructured High-Temperature Bulk Thermoelectric Energy Conversion for Efficient Automotive Waste Heat Recovery Vehicle Technologies Office Merit Review 2014: Nanostructured...

  3. Bulk viscosity of QCD matter near the critical temperature

    E-Print Network [OSTI]

    D. Kharzeev; K. Tuchin

    2007-05-29T23:59:59.000Z

    Kubo's formula relates bulk viscosity to the retarded Green's function of the trace of the energy-momentum tensor. Using low energy theorems of QCD for the latter we derive the formula which relates the bulk viscosity to the energy density and pressure of hot matter. We then employ the available lattice QCD data to extract the bulk viscosity as a function of temperature. We find that close to the deconfinement temperature bulk viscosity becomes large, with viscosity-to-entropy ratio zeta/s about 1.

  4. On Eling-Oz formula for the holographic bulk viscosity

    E-Print Network [OSTI]

    Alex Buchel

    2011-05-09T23:59:59.000Z

    Recently Eling and Oz [1] proposed a simple formula for the bulk viscosity of holographic plasma. They argued that the formula is valid in the high temperature (near-conformal) regime, but is expected to break down at low temperatures. We point out that the formula is in perfect agreement with the previous computations of the bulk viscosity of the cascading plasma [2,3], as well as with the previous computations of the bulk viscosity of N=2^* plasma [4,5]. In the latter case it correctly reproduces the critical behaviour of the bulk viscosity in the vicinity of the critical point with the vanishing speed of sound.

  5. Light-Emitting Diodes on Semipolar Bulk Gallium Nitride Substrate...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    semipolar light-emitting diodes (LEDs) on low-defect bulk gallium nitride (GaN) substrates. Peak internal quantum efficiency (IQE) values of greater than 80% are...

  6. The Edgewater Coolside process demonstration

    SciTech Connect (OSTI)

    McCoy, D.C.; Scandrol, R.O.; Statnick, R.M.; Stouffer, M.R.; Winschel, R.A.; Withum, J.A.; Wu, M.M.; Yoon, H. [CONSOL, Inc., Pittsburgh, PA (United States)

    1992-02-01T23:59:59.000Z

    The Edgewater Coolside process demonstration met the program objectives which were to determine Coolside SO{sub 2} removal performance, establish short-term process operability, and evaluate the economics of the process versus a limestone wet scrubber. On a flue gas produced from the combustion of 3% sulfur coal, the Coolside process achieved 70% SO{sub 2} removal using commercially-available hydrated lime as the sorbent. The operating conditions were Ca/S mol ratio 2.0, Na/Ca mol ratio 0.2, and 20{degree}F approach to adiabatic saturation temperature ({del}T). During tests using fresh plus recycle sorbent, the recycle sorbent exhibited significant capacity for additional SO{sub 2} removal. The longest steady state operation was eleven days at nominally Ca/S = 2, Na/Ca = 0.22, {del}T = 20--22{degree}F, and 70% SO{sub 2} removal. The operability results achieved during the demonstration indicate that with the recommended process modifications, which are discussed in the Coolside process economic analysis, the process could be designed as a reliable system for utility application. Based on the demonstration program, the Coolside process capital cost for a hypothetical commercial installation was minimized. The optimization consisted of a single, large humidifier, no spare air compressor, no isolation dampers, and a 15 day on-site hydrated lime storage. The levelized costs of the Coolside and the wet limestone scrubbing processes were compared. The Coolside process is generally economically competitive with wet scrubbing for coals containing up to 2.5% sulfur and plants under 350 MWe. Site-specific factors such as plant capacity factor, SO{sub 2} emission limit, remaining plant life, retrofit difficulty, and delivered sorbent cost affect the scrubber-Coolside process economic comparison.

  7. The Edgewater Coolside process demonstration

    SciTech Connect (OSTI)

    McCoy, D.C.; Scandrol, R.O.; Statnick, R.M.; Stouffer, M.R.; Winschel, R.A.; Withum, J.A.; Wu, M.M.; Yoon, H. (CONSOL, Inc., Pittsburgh, PA (United States))

    1992-02-01T23:59:59.000Z

    The Edgewater Coolside process demonstration met the program objectives which were to determine Coolside SO[sub 2] removal performance, establish short-term process operability, and evaluate the economics of the process versus a limestone wet scrubber. On a flue gas produced from the combustion of 3% sulfur coal, the Coolside process achieved 70% SO[sub 2] removal using commercially-available hydrated lime as the sorbent. The operating conditions were Ca/S mol ratio 2.0, Na/Ca mol ratio 0.2, and 20[degree]F approach to adiabatic saturation temperature ([del]T). During tests using fresh plus recycle sorbent, the recycle sorbent exhibited significant capacity for additional SO[sub 2] removal. The longest steady state operation was eleven days at nominally Ca/S = 2, Na/Ca = 0.22, [del]T = 20--22[degree]F, and 70% SO[sub 2] removal. The operability results achieved during the demonstration indicate that with the recommended process modifications, which are discussed in the Coolside process economic analysis, the process could be designed as a reliable system for utility application. Based on the demonstration program, the Coolside process capital cost for a hypothetical commercial installation was minimized. The optimization consisted of a single, large humidifier, no spare air compressor, no isolation dampers, and a 15 day on-site hydrated lime storage. The levelized costs of the Coolside and the wet limestone scrubbing processes were compared. The Coolside process is generally economically competitive with wet scrubbing for coals containing up to 2.5% sulfur and plants under 350 MWe. Site-specific factors such as plant capacity factor, SO[sub 2] emission limit, remaining plant life, retrofit difficulty, and delivered sorbent cost affect the scrubber-Coolside process economic comparison.

  8. Commercial Building Demonstration and Deployment

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny: Theof"Wave the WhiteNational Broadbandof theCommercial Building Demonstration

  9. Bentonite mat demonstration. Final report

    SciTech Connect (OSTI)

    Serrato, M.G.

    1994-12-30T23:59:59.000Z

    The Bentonite Mat Demonstration was developed to provide the Environmental Restoration Department with field performance characteristics and engineering data for an alternative closure cover system configuration. The demonstration was initiated in response to regulatory concerns regarding the use of an alternative cover system for future design configurations. These design considerations are in lieu of the US Environmental Protection Agency (EPA) Recommended Design for Closure Cover Systems and specifically a single compacted kaolin clay layer with a hydraulic conductivity of 1 {times} 10{sup {minus}7} cm/sec. This alternative configuration is a composite geosynthetic material hydraulic barrier consisting from bottom to top: 2 ft compacted sandy clay layer (typical local Savannah River Site soil type) that is covered by a bentonite mat--geosynthetic clay liner (GCL) and is overlaid by a 40 mil High Density Polyethylene (HDPE) geomembrane--flexible membrane liner. This effort was undertaken to obtain and document the necessary field performance/engineering data for future designs and meet regulatory technical requirements for an alternative cover system configuration. The composite geosynthetic materials hydraulic barrier is the recommended alternative cover system configuration for containment of hazardous and low level radiological waste layers that have a high potential of subsidence to be used at the Savannah River Site (SRS). This alternative configuration mitigates subsidence effects in providing a flexible, lightweight cover system to maintain the integrity of the closure. The composite geosynthetic materials hydraulic barrier is recommended for the Sanitary Landfill and Low Level Radiological Waste Disposal Facility (LLRWDF) Closures.

  10. Engineering scale electrostatic enclosure demonstration

    SciTech Connect (OSTI)

    Meyer, L.C.

    1993-09-01T23:59:59.000Z

    This report presents results from an engineering scale electrostatic enclosure demonstration test. The electrostatic enclosure is part of an overall in-depth contamination control strategy for transuranic (TRU) waste recovery operations. TRU contaminants include small particles of plutonium compounds associated with defense-related waste recovery operations. Demonstration test items consisted of an outer Perma-con enclosure, an inner tent enclosure, and a ventilation system test section for testing electrostatic curtain devices. Three interchangeable test fixtures that could remove plutonium from the contaminated dust were tested in the test section. These were an electret filter, a CRT as an electrostatic field source, and an electrically charged parallel plate separator. Enclosure materials tested included polyethylene, anti-static construction fabric, and stainless steel. The soil size distribution was determined using an eight stage cascade impactor. Photographs of particles containing plutonium were obtained with a scanning electron microscope (SEM). The SEM also provided a second method of getting the size distribution. The amount of plutonium removed from the aerosol by the electrostatic devices was determined by radiochemistry from input and output aerosol samplers. The inner and outer enclosures performed adequately for plutonium handling operations and could be used for full scale operations.

  11. Parker Hybrid Hydraulic Drivetrain Demonstration

    SciTech Connect (OSTI)

    Collett, Raymond [Parker-Hannifin Corporation, Cleveland, OH (United States); Howland, James [Parker-Hannifin Corporation, Cleveland, OH (United States); Venkiteswaran, Prasad [National Energy Technology Lab. (NETL), Morgantown, WV (United States)

    2014-03-31T23:59:59.000Z

    This report examines the benefits of Parker Hannifin hydraulic hybrid brake energy recovery systems used in commercial applications for vocational purposes. A detailed background on the problem statement being addressed as well as the solution set specific for parcel delivery will be provided. Objectives of the demonstration performed in high start & stop applications included opportunities in fuel usage reduction, emissions reduction, vehicle productivity, and vehicle maintenance. Completed findings during the demonstration period and parallel investigations with NREL, CALSTART, along with a literature review will be provided herein on this research area. Lastly, results identified in the study by third parties validated the savings potential in fuel reduction of on average of 19% to 52% over the baseline in terms of mpg (Lammert, 2014, p11), Parker data for parcel delivery vehicles in the field parallels this at a range of 35% - 50%, emissions reduction of 17.4% lower CO2 per mile and 30.4% lower NOx per mile (Gallo, 2014, p15), with maintenance improvement in the areas of brake and starter replacement, while leaving room for further study in the area of productivity in terms of specific metrics that can be applied and studied.

  12. Thermodynamic properties of bulk and confined water

    SciTech Connect (OSTI)

    Mallamace, Francesco, E-mail: francesco.mallamace@unime.it [Dipartimento di Fisica e Scienza della Terra Università di Messina and CNISM, I-98168 Messina (Italy); Department of Nuclear Science and Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States); Center for Polymer Studies and Department of Physics, Boston University, Boston, Massachusetts 02215 (United States); Corsaro, Carmelo [Dipartimento di Fisica e Scienza della Terra Università di Messina and CNISM, I-98168 Messina (Italy); Mallamace, Domenico [Dipartimento di Scienze dell'Ambiente, della Sicurezza, del Territorio, degli Alimenti e della Salute, Università di Messina, I-98166 Messina (Italy); Vasi, Sebastiano; Vasi, Cirino [IPCF-CNR, I-98166 Messina (Italy); Stanley, H. Eugene [Center for Polymer Studies and Department of Physics, Boston University, Boston, Massachusetts 02215 (United States)

    2014-11-14T23:59:59.000Z

    The thermodynamic response functions of water display anomalous behaviors. We study these anomalous behaviors in bulk and confined water. We use nuclear magnetic resonance (NMR) to examine the configurational specific heat and the transport parameters in both the thermal stable and the metastable supercooled phases. The data we obtain suggest that there is a behavior common to both phases: that the dynamics of water exhibit two singular temperatures belonging to the supercooled and the stable phase, respectively. One is the dynamic fragile-to-strong crossover temperature (T{sub L} ? 225 K). The second, T{sup *} ? 315 ± 5 K, is a special locus of the isothermal compressibility K{sub T}(T, P) and the thermal expansion coefficient ?{sub P}(T, P) in the P–T plane. In the case of water confined inside a protein, we observe that these two temperatures mark, respectively, the onset of protein flexibility from its low temperature glass state (T{sub L}) and the onset of the unfolding process (T{sup *})

  13. Material Profile Influences in Bulk-Heterojunctions

    SciTech Connect (OSTI)

    Roehling, John D.; Rochester, Christopher W.; Ro, Hyun W.; Wang, Peng; Majewski, Jaroslaw; Batenburg, Kees J.; Arslan, Ilke; Delongchamp, Dean M.; Moule, Adam J.

    2014-10-01T23:59:59.000Z

    he morphology in mixed bulk-heterojunction films are compared using three different quantitative measurement techniques. We compare the vertical composition changes using high-angle annular dark-field scanning transmission electron microscopy with electron tomography and neutron and x-ray reflectometry. The three measurement techniques yield qualita-tively comparable vertical concentration measurements. The presence of a metal cathode during thermal annealing is observed to alter the fullerene concentration throughout the thickness of the film for all measurements. However, the abso-lute vertical concentration of fullerene is quantitatively different for the three measurements. The origin of the quantitative measurement differences is discussed. The authors thank Luna Innovations, Inc. for donating the endohedral fullerenes used in this study and Plextronics for the P3HT. They are gratefully thank the National Science Foundation Energy for Sustainability Program, Award No. 0933435. This work benefited from the use of the Lujan Neutron Scattering Center at Los Alamos Neutron Science Center funded by the DOE Office of Basic Energy Sciences and Los Alamos National Laboratory under DOE Contract DE-AC52-06NA25396. This research was also supported in part by Laboratory Directed Research & Development program at PNNL. The Pacific Northwest National Laboratory is operated by Battelle for the US Department of Energy under contract DE-AC05-76RL01830.

  14. Improving Bulk Microphysics Parameterizations in Simulations of Aerosol Effects

    SciTech Connect (OSTI)

    Wang, Yuan; Fan, Jiwen; Zhang, Renyi; Leung, Lai-Yung R.; Franklin, Charmaine N.

    2013-06-05T23:59:59.000Z

    To improve the microphysical parameterizations for simulations of the aerosol indirect effect (AIE) in regional and global climate models, a double-moment bulk microphysical scheme presently implemented in the Weather Research and Forecasting (WRF) model is modified and the results are compared against atmospheric observations and simulations produced by a spectral bin microphysical scheme (SBM). Rather than using prescribed aerosols as in the original bulk scheme (Bulk-OR), a prognostic doublemoment aerosol representation is introduced to predict both the aerosol number concentration and mass mixing ratio (Bulk-2M). The impacts of the parameterizations of diffusional growth and autoconversion and the selection of the embryonic raindrop radius on the performance of the bulk microphysical scheme are also evaluated. Sensitivity modeling experiments are performed for two distinct cloud regimes, maritime warm stratocumulus clouds (SC) over southeast Pacific Ocean from the VOCALS project and continental deep convective clouds (DCC) in the southeast of China from the Department of Energy/ARM Mobile Facility (DOE/AMF) - China field campaign. The results from Bulk-2M exhibit a much better agreement in the cloud number concentration and effective droplet radius in both the SC and DCC cases with those from SBM and field measurements than those from Bulk-OR. In the SC case particularly, Bulk-2M reproduces the observed drizzle precipitation, which is largely inhibited in Bulk-OR. Bulk-2M predicts enhanced precipitation and invigorated convection with increased aerosol loading in the DCC case, consistent with the SBM simulation, while Bulk-OR predicts the opposite behaviors. Sensitivity experiments using four different types of autoconversion schemes reveal that the autoconversion parameterization is crucial in determining the raindrop number, mass concentration, and drizzle formation for warm 2 stratocumulus clouds. An embryonic raindrop size of 40 ?m is determined as a more realistic setting in the autoconversion parameterization. The saturation adjustment employed in calculating condensation/evaporation in the bulk scheme is identified as the main factor responsible for the large discrepancies in predicting cloud water in the SC case, suggesting that an explicit calculation of diffusion growth with predicted supersaturation is necessary for further improvements of the bulk microphysics scheme. Lastly, a larger rain evaporation rate below cloud is found in the bulk scheme in comparison to the SBM simulation, which could contribute to a lower surface precipitation in the bulk scheme.

  15. Controlled Hydrogen Fleet and Infrastructure Demonstration and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Controlled Hydrogen Fleet and Infrastructure Demonstration and Validation Project Solicitation Controlled Hydrogen Fleet and Infrastructure Demonstration and Validation Project...

  16. Controlled Hydrogen Fleet and Infrastructure Demonstration and...

    Office of Environmental Management (EM)

    Controlled Hydrogen Fleet and Infrastructure Demonstration and Validation Project Controlled Hydrogen Fleet and Infrastructure Demonstration and Validation Project 2009 DOE...

  17. Distributed Energy Technology Simulator: Microturbine Demonstration...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Simulator: Microturbine Demonstration, October 2001 Distributed Energy Technology Simulator: Microturbine Demonstration, October 2001 This 2001 paper discusses the National Rural...

  18. Industrial Scale Demonstration of Smart Manufacturing Achieving...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Scale Demonstration of Smart Manufacturing Achieving Transformational Energy Productivity Gains Industrial Scale Demonstration of Smart Manufacturing Achieving...

  19. Research Initiative Will Demonstrate Low Temperature Geothermal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Research Initiative Will Demonstrate Low Temperature Geothermal Electrical Power Generation Systems Using Oilfield Fluids Research Initiative Will Demonstrate Low Temperature...

  20. Better Buildings Residential Program Solution Center Demonstration...

    Energy Savers [EERE]

    Better Buildings Residential Program Solution Center Demonstration Better Buildings Residential Program Solution Center Demonstration Better Buildings Residential Program Solution...

  1. Grid Connectivity Research, Development & Demonstration Projects...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Connectivity Research, Development & Demonstration Projects Grid Connectivity Research, Development & Demonstration Projects 2013 DOE Hydrogen and Fuel Cells Program and Vehicle...

  2. SPIDERS Joint Capability Technology Demonstration Industry Day...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    SPIDERS Joint Capability Technology Demonstration Industry Day Presentations SPIDERS Joint Capability Technology Demonstration Industry Day Presentations Presentations from the...

  3. Navy fuel cell demonstration project.

    SciTech Connect (OSTI)

    Black, Billy D.; Akhil, Abbas Ali

    2008-08-01T23:59:59.000Z

    This is the final report on a field evaluation by the Department of the Navy of twenty 5-kW PEM fuel cells carried out during 2004 and 2005 at five Navy sites located in New York, California, and Hawaii. The key objective of the effort was to obtain an engineering assessment of their military applications. Particular issues of interest were fuel cell cost, performance, reliability, and the readiness of commercial fuel cells for use as a standalone (grid-independent) power option. Two corollary objectives of the demonstration were to promote technological advances and to improve fuel performance and reliability. From a cost perspective, the capital cost of PEM fuel cells at this stage of their development is high compared to other power generation technologies. Sandia National Laboratories technical recommendation to the Navy is to remain involved in evaluating successive generations of this technology, particularly in locations with greater environmental extremes, and it encourages their increased use by the Navy.

  4. Looking beyond the demonstration plants

    SciTech Connect (OSTI)

    Bajura, R.A.; Halow, J.S. (U.S. Dept. of Energy, Morgantown Energy Technology Center, Morgantown, MV (US))

    1988-01-01T23:59:59.000Z

    Atmospheric fluidized-bed combustion (AFBC), pressurized fluidized-bed combustion (PFBC), and integrated gasification combined-cycle (IGCC) systems, near-term, coal-based technology options for new, base-load capacity additions are being demonstrated in projects currently underway. Longer-term technology options can be envisioned that potentialy will have lower capital, operating, and maintenance costs particularly for small increments of new capacity, higher efficiencies, the ability to economically meet increasingly stringent environmental standards, shorter construction times, higher reliability, improved load-response characteristics, tolerance to a wide range of coal feed-stocks, and infrastructure acceptability. Candidate longer-term technologies include gas turbine-based systems using air-blown, entrained flow gasifiers coupled with novel cleanup processes; PFBC systems utilizing a topping combustor; coal gasification/fuel cell systems; and coal-fueled gas turbines. This paper discusses the advantages and market niches of these longer-term technology options.

  5. UDC Demonstrates Phosphorescent OLED Systems

    Broader source: Energy.gov [DOE]

    Universal Display Corporation (UDC), along with project partners Armstrong World Industries and the universities of Michigan and Southern California, have successfully demonstrated two phosphorescent OLED (PHOLED™) luminaire systems, the first of their kind in the U.S. This achievement marks a critical step in the development of practical OLED lighting in a complete luminaire system, including decorative housing, power supply, mounting, and maintenance provisions. Each luminaire has overall dimensions of approximately 15x60 cm and is comprised of four 15x15 cm phosphorescent OLED panels. With a combined power supply and lamp efficacy of 51 lm/W, the prototype luminaire is about twice as efficient as the market-leading halogen-based systems. In addition, the prototype OLED lighting system snaps into Armstrong's TechZone™ Ceiling System, which is commercially available in the U.S.x

  6. Pilot Scale Advanced Fogging Demonstration

    SciTech Connect (OSTI)

    Demmer, Rick L. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Fox, Don T. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Archiblad, Kip E. [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2015-01-01T23:59:59.000Z

    Experiments in 2006 developed a useful fog solution using three different chemical constituents. Optimization of the fog recipe and use of commercially available equipment were identified as needs that had not been addressed. During 2012 development work it was noted that low concentrations of the components hampered coverage and drying in the United Kingdom’s National Nuclear Laboratory’s testing much more so than was evident in the 2006 tests. In fiscal year 2014 the Idaho National Laboratory undertook a systematic optimization of the fogging formulation and conducted a non-radioactive, pilot scale demonstration using commercially available fogging equipment. While not as sophisticated as the equipment used in earlier testing, the new approach is much less expensive and readily available for smaller scale operations. Pilot scale testing was important to validate new equipment of an appropriate scale, optimize the chemistry of the fogging solution, and to realize the conceptual approach.

  7. Demonstration of integrated optimization software

    SciTech Connect (OSTI)

    NONE

    2008-01-01T23:59:59.000Z

    NeuCO has designed and demonstrated the integration of five system control modules using its proprietary ProcessLink{reg_sign} technology of neural networks, advanced algorithms and fuzzy logic to maximize performance of coal-fired plants. The separate modules control cyclone combustion, sootblowing, SCR operations, performance and equipment maintenance. ProcessLink{reg_sign} provides overall plant-level integration of controls responsive to plant operator and corporate criteria. Benefits of an integrated approach include NOx reduction improvement in heat rate, availability, efficiency and reliability; extension of SCR catalyst life; and reduced consumption of ammonia. All translate into cost savings. As plant complexity increases through retrofit, repowering or other plant modifications, this integrated process optimization approach will be an important tool for plant operators. 1 fig., 1 photo.

  8. Clean Coal Diesel Demonstration Project

    SciTech Connect (OSTI)

    Robert Wilson

    2006-10-31T23:59:59.000Z

    A Clean Coal Diesel project was undertaken to demonstrate a new Clean Coal Technology that offers technical, economic and environmental advantages over conventional power generating methods. This innovative technology (developed to the prototype stage in an earlier DOE project completed in 1992) enables utilization of pre-processed clean coal fuel in large-bore, medium-speed, diesel engines. The diesel engines are conventional modern engines in many respects, except they are specially fitted with hardened parts to be compatible with the traces of abrasive ash in the coal-slurry fuel. Industrial and Municipal power generating applications in the 10 to 100 megawatt size range are the target applications. There are hundreds of such reciprocating engine power-plants operating throughout the world today on natural gas and/or heavy fuel oil.

  9. Performance Demonstration Program Management Plan

    SciTech Connect (OSTI)

    Carlsbad Field Office

    2005-07-01T23:59:59.000Z

    To demonstrate compliance with the Waste Isolation Pilot Plant (WIPP) waste characterization program, each testing and analytical facility performing waste characterization activities participates in the Performance Demonstration Program (PDP). The PDP serves as a quality control check against expected results and provides information about the quality of data generated in the characterization of waste destined for WIPP. Single blind audit samples are prepared and distributed by an independent organization to each of the facilities participating in the PDP. There are three elements within the PDP: analysis of simulated headspace gases, analysis of solids for Resource Conservation and Recovery Act (RCRA) constituents, and analysis for transuranic (TRU) radionuclides using nondestructive assay (NDA) techniques. Because the analysis for TRU radionuclides using NDA techniques involves both the counting of drums and standard waste boxes, four PDP plans are required to describe the activities of the three PDP elements. In accordance with these PDP plans, the reviewing and approving authority for PDP results and for the overall program is the CBFO PDP Appointee. The CBFO PDP Appointee is responsible for ensuring the implementation of each of these plans by concurring with the designation of the Program Coordinator and by providing technical oversight and coordination for the program. The Program Coordinator will designate the PDP Manager, who will coordinate the three elements of the PDP. The purpose of this management plan is to identify how the requirements applicable to the PDP are implemented during the management and coordination of PDP activities. The other participants in the program (organizations that perform site implementation and activities under CBFO contracts or interoffice work orders) are not covered under this management plan. Those activities are governed by the organization’s quality assurance (QA) program and procedures or as otherwise directed by CBFO.

  10. BULK MICROMACHINED TITANIUM MICROMIRROR DEVICE WITH SLOPING ELECTRODE GEOMETRY

    E-Print Network [OSTI]

    MacDonald, Noel C.

    BULK MICROMACHINED TITANIUM MICROMIRROR DEVICE WITH SLOPING ELECTRODE GEOMETRY Masa P. Rao1 , Marco micromachined hybrid torsional micromirror device composed of titanium mirror structures bonded to an underlying time, high aspect ratio micromachining capability in bulk titanium; and 2) the High Aspect Ratio

  11. MORPHOLOGY DEPENDENT SHORT CIRCUIT CURRENT IN BULK HETEROJUNCTION SOLAR CELL

    E-Print Network [OSTI]

    Alam, Muhammad A.

    MORPHOLOGY DEPENDENT SHORT CIRCUIT CURRENT IN BULK HETEROJUNCTION SOLAR CELL Biswajit Ray, Pradeep, West Lafayette, Indiana, USA ABSTRACT Polymer based bulk heterostructure (BH) solar cell offers a relatively inexpensive option for the future solar cell technology, provided its efficiency increases beyond

  12. Role of Cavitation in Bulk Ultrasound Ablation: A Histologic Study

    E-Print Network [OSTI]

    Mast, T. Douglas

    Role of Cavitation in Bulk Ultrasound Ablation: A Histologic Study Chandra Priya Karunakaran, Mark of Cincinnati, Cincinnati, Ohio Abstract. The role of cavitation in bulk ultrasound ablation has been evaluated-ablate probe at 31 W/cm2 for 20 minutes under normal and elevated ambient pressures. A 1 MHz passive cavitation

  13. Silicon bulk micromachined hybrid dimensional artifact.

    SciTech Connect (OSTI)

    Claudet, Andre A.; Tran, Hy D.; Bauer, Todd Marks; Shilling, Katherine Meghan; Oliver, Andrew David

    2010-03-01T23:59:59.000Z

    A mesoscale dimensional artifact based on silicon bulk micromachining fabrication has been developed and manufactured with the intention of evaluating the artifact both on a high precision coordinate measuring machine (CMM) and video-probe based measuring systems. This hybrid artifact has features that can be located by both a touch probe and a video probe system with a k=2 uncertainty of 0.4 {micro}m, more than twice as good as a glass reference artifact. We also present evidence that this uncertainty could be lowered to as little as 50 nm (k=2). While video-probe based systems are commonly used to inspect mesoscale mechanical components, a video-probe system's certified accuracy is generally much worse than its repeatability. To solve this problem, an artifact has been developed which can be calibrated using a commercially available high-accuracy tactile system and then be used to calibrate typical production vision-based measurement systems. This allows for error mapping to a higher degree of accuracy than is possible with a glass reference artifact. Details of the designed features and manufacturing process of the hybrid dimensional artifact are given and a comparison of the designed features to the measured features of the manufactured artifact is presented and discussed. Measurement results from vision and touch probe systems are compared and evaluated to determine the capability of the manufactured artifact to serve as a calibration tool for video-probe systems. An uncertainty analysis for calibration of the artifact using a CMM is presented.

  14. Design and performance of a 100-kg/h, direct calcine-fed electric-melter system for nuclear-waste vitrification

    SciTech Connect (OSTI)

    Dierks, R.D.

    1980-11-01T23:59:59.000Z

    This report describes the physical characteristics of a ceramic-lined, joule-heated glass melter that is directly connected to the discharge of a spray calciner and is currently being used to study the vitrification of simulated nuclear-waste slurries. Melter performance characteristics and subsequent design improvements are described. The melter contains 0.24 m/sup 3/ of glass with a glass surface area of 0.76 m/sup 2/, and is heated by the flow of an alternating current (ranging from 600 to 1200 amps) between two Inconel-690 slab-type electrodes immersed in the glass at either end of the melter tank. The melter was maintained at operating temperature (900 to 1260/sup 0/C) for 15 months, and produced 62,000 kg of glass. The maximum sustained operating period was 122 h, during which glass was produced at the rate of 70 kg/h.

  15. Baseline milestone HWVP-87-V110202F: Preliminary evaluation of noble metal behavior in the Hanford waste vitrification plant reference glass HW-39

    SciTech Connect (OSTI)

    Geldart, R.W.; Bates, S.O.; Jette, S.J.

    1996-03-01T23:59:59.000Z

    The precipitation and aggregation of ruthenium (Ru), rhodium (RLh) and palladium (Pd) in the Hanford Waste Vitrification Plant (HWVP) low chromium reference glass HLW-39 were investigated to determine if there is a potential for formation of a noble metal sludge in the HWVP ceramic melter. Significant noble metal accumulations on the floor of the melter will result in the electrical shorting of the electrodes and premature failure of the melter. The purpose of this study was to obtain preliminary information on the characteristics of noble metals in a simulated HWVP glass. Following a preliminary literature view to obtain information concerning the noble metals behavior, a number of variability studies were initiated. The effects of glass redox conditions, melt temperature, melting time and noble metal concentration on the phase characteristics of these noble metals were examined.

  16. Carbon nanotubes grown on bulk materials and methods for fabrication

    DOE Patents [OSTI]

    Menchhofer, Paul A. (Clinton, TN); Montgomery, Frederick C. (Oak Ridge, TN); Baker, Frederick S. (Oak Ridge, TN)

    2011-11-08T23:59:59.000Z

    Disclosed are structures formed as bulk support media having carbon nanotubes formed therewith. The bulk support media may comprise fibers or particles and the fibers or particles may be formed from such materials as quartz, carbon, or activated carbon. Metal catalyst species are formed adjacent the surfaces of the bulk support material, and carbon nanotubes are grown adjacent the surfaces of the metal catalyst species. Methods employ metal salt solutions that may comprise iron salts such as iron chloride, aluminum salts such as aluminum chloride, or nickel salts such as nickel chloride. Carbon nanotubes may be separated from the carbon-based bulk support media and the metal catalyst species by using concentrated acids to oxidize the carbon-based bulk support media and the metal catalyst species.

  17. Vitrification of Low-Activity Radioactive Waste Streams and a High-Level Radioactive Waste Stream in Support of the Hanford River Protection Program

    SciTech Connect (OSTI)

    Crawford, C.L.

    2002-07-10T23:59:59.000Z

    Hanford tank waste consists of about 190 million curies in 54 million gallons of highly radioactive and mixed hazardous waste stored in underground storage tanks at the Hanford Site in Washington State. The tank waste includes solids (sludge), liquids (supernatant), and salt cake (dried salts that dissolve in water to form supernatant). The tank waste will be remediated through treatment and immobilization to protect the environment and meet regulatory requirements. The U.S. Department of Energy's (DOE's) preferred alternative to remediate the Hanford tank waste is to pretreat the waste by separating it into low-activity waste (LAW) and high-level waste (HLW), followed by immobilization of the LAW for on-site disposal and immobilization of the HLW for ultimate disposal in a national repository. This paper describes the crucible-scale vitrification and associated wasteform product tests in support of the WTP at Hanford. The two different LAW glasses produced in this study were from pretreated Envelope A (Tank 241-AN-103) and Envelope C (Tank 241-AN-102) waste. The HLW glass was produced from Tank C-106 HLW sludge and the HLW radionuclide products separated from Hanford Site tank samples AN-103, AN-102 and AZ-102. Pretreatment of these three supernates consisted of characterization, strontium and transuranics removal by precipitation and filtration, and final Cs-137 and Tc-99 removal by ion exchange (IX). The glasses were produced from formulations supplied by Vitreous State Laboratory of the Catholic University of America (CUA). Formulations were based on previous surrogate testing and the actual characterization data from the radioactive feed streams. Crucible-scale vitrifications were performed in platinum/gold crucibles in a custom-designed furnace fit with an offgas containment system. Both LAW and HLW melter feed slurries were evaporated, calcined, and then melted at 1150 degrees C. The LAW and HLW glasses were heat-treated per a modeled centerline cooling curve for the LAW canister and HLW canister, respectively.

  18. Design of Vitrification Machine

    E-Print Network [OSTI]

    McDonald, Todd William

    2009-11-30T23:59:59.000Z

    ), and if it is capable of reliably and repeatedly controlling the Petri Dish Tray. These tests will serve to evaluate both the machine’s physical design as well as its software design. Along with the machine’s actual function, its overall design will be evaluated... the specimen is then moved through of series of Petri dishes containing cryo-protectant fluids, generally up to four (personal interview, Medical Advisor, Dr. Kim), using tweezers (alternatively, a pipette system may be employed). The technician must monitor...

  19. Final Vitrification Melter Evaluation

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directed offOCHCO2: FinalOffers New Training on Energy6 FederalofE: Bibliography of(PEIS) | Department

  20. Running heading: Bulk density of a clayey subsoil Increase in the bulk density of a Grey Clay subsoil by

    E-Print Network [OSTI]

    Boyer, Edmond

    1 Running heading: Bulk density of a clayey subsoil Increase in the bulk density of a Grey Clay of the prisms were coated by material similar in composition to the topsoil and separated from as the profile dries over summer leading to widening of cracks between prismatic peds, (2) infilling of cracks

  1. Thermal conductivity of bulk nanostructured lead telluride

    SciTech Connect (OSTI)

    Hori, Takuma [Department of Mechanical Engineering, The University of Tokyo, Bunkyo, Tokyo 113-8656 (Japan); Chen, Gang [Department of Mechanical Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States); Shiomi, Junichiro, E-mail: shiomi@photon.t.u-tokyo.ac.jp [Department of Mechanical Engineering, The University of Tokyo, Bunkyo, Tokyo 113-8656 (Japan); PRESTO, Japan Science and Technology Agency, Kawaguchi, Saitama 332-0012 (Japan)

    2014-01-13T23:59:59.000Z

    Thermal conductivity of lead telluride with embedded nanoinclusions was studied using Monte Carlo simulations with intrinsic phonon transport properties obtained from first-principles-based lattice dynamics. The nanoinclusion/matrix interfaces were set to completely reflect phonons to model the maximum interface-phonon-scattering scenario. The simulations with the geometrical cross section and volume fraction of the nanoinclusions matched to those of the experiment show that the experiment has already reached the theoretical limit of thermal conductivity. The frequency-dependent analysis further identifies that the thermal conductivity reduction is dominantly attributed to scattering of low frequency phonons and demonstrates mutual adaptability of nanostructuring and local disordering.

  2. Brane-Bulk energy exchange and agegraphic dark energy

    E-Print Network [OSTI]

    Ahmad Sheykhi

    2010-02-06T23:59:59.000Z

    We consider the agegraphic models of dark energy in a braneworld scenario with brane-bulk energy exchange. We assume that the adiabatic equation for the dark matter is satisfied while it is violated for the agegraphic dark energy due to the energy exchange between the brane and the bulk. Our study shows that with the brane-bulk interaction, the equation of state parameter of agegraphic dark energy on the brane, $w_D$, can have a transition from normal state where $w_D >-1 $ to the phantom regime where $w_D energy always satisfies $w^{\\mathrm{eff}}_D\\geq-1$.

  3. Neutrino mass, bulk majoron and neutrinoless double beta decay

    E-Print Network [OSTI]

    R. N. Mohapatra; A. Perez-Lorenzana; C. A. de S. Pires

    2000-08-15T23:59:59.000Z

    A new economical model for neutrino masses is proposed in the context of brane bulk scenarios for particle physics, where global B-L symmetry of the standard model is broken spontaneously by a gauge singlet Higgs field in the bulk. This leads to a bulk majoron whose KK excitations may make it visible if neutrinoless double beta decay if the string scale is close to a TeV. It also leads to neutron-anti-neutron oscillation process with transition times which can be in the range accessible to proposed experiments.

  4. Bulk viscosity, chemical equilibration and flow at RHIC

    E-Print Network [OSTI]

    Thomas Schaefer; Kevin Dusling

    2012-10-15T23:59:59.000Z

    We study the effects of bulk viscosity on p_T spectra and elliptic flow in heavy ion collisions at RHIC. We argue that direct effect of the bulk viscosity on the evolution of the velocity field is small, but corrections to the freezeout distributions can be significant. These effects are dominated by chemical non-equilibration in the hadronic phase. We show that a non-zero bulk viscosity in the range $\\zeta/s \\lsim 0.05$ improves the description of spectra and flow at RHIC.

  5. GROWDERS Demonstration of Grid Connected Electricity Systems...

    Open Energy Info (EERE)

    GROWDERS Demonstration of Grid Connected Electricity Systems (Smart Grid Project) (Spain) Jump to: navigation, search Project Name GROWDERS Demonstration of Grid Connected...

  6. Hydrogen Storage Materials Database Demonstration Webinar (Text...

    Broader source: Energy.gov (indexed) [DOE]

    Database Demonstration Webinar (Text Version) Hydrogen Storage Materials Database Demonstration Webinar (Text Version) Below is the text version of the webinar titled "Hydrogen...

  7. California: Next-Generation Geothermal Demonstration Launched...

    Office of Environmental Management (EM)

    Next-Generation Geothermal Demonstration Launched California: Next-Generation Geothermal Demonstration Launched August 21, 2013 - 12:00am Addthis At the outer edges of the largest...

  8. Daemen Alternative Energy/Geothermal Technologies Demonstration...

    Broader source: Energy.gov (indexed) [DOE]

    Daemen Alternative EnergyGeothermal Technologies Demonstration Program Erie County Daemen Alternative EnergyGeothermal Technologies Demonstration Program Erie County Project...

  9. Better Buildings Residential Program Solution Center Demonstration...

    Broader source: Energy.gov (indexed) [DOE]

    Demonstration webinar slides for Better Buildings Residential Program Solution Center, November 19, 2014. Solution Center Demonstration Webinar Slides More Documents & Publications...

  10. Hydrogen Vehicle and Infrastructure Demonstration and Validation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Vehicle and Infrastructure Demonstration and Validation Hydrogen Vehicle and Infrastructure Demonstration and Validation 2009 DOE Hydrogen Program and Vehicle Technologies Program...

  11. Joint Capability Technology Demonstration (JCTD) Industry Day...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Joint Capability Technology Demonstration (JCTD) Industry Day Agenda Joint Capability Technology Demonstration (JCTD) Industry Day Agenda Agenda outlines the activities of the 2014...

  12. Three Offshore Wind Advanced Technology Demonstration Projects...

    Office of Environmental Management (EM)

    Offshore Wind Advanced Technology Demonstration Projects Receive Phase 2 Funding Three Offshore Wind Advanced Technology Demonstration Projects Receive Phase 2 Funding September...

  13. Mechanical Properties of Bulk Metallic Glasses and Composites

    E-Print Network [OSTI]

    Lee, M.L.

    We have studied the mechanical properties of monolithic bulk metallic glasses and composite in the La based alloys. La???yAl??(Cu, Ni)y (y=24 to 32) alloy systems was used to cast the ...

  14. High-power-density spot cooling using bulk thermoelectrics

    E-Print Network [OSTI]

    Zhang, Y; Shakouri, A; Zeng, G H

    2004-01-01T23:59:59.000Z

    model, the cooling power densities of the devices can alsothe cooling power densities 2–24 times. Experimentally, the14 4 OCTOBER 2004 High-power-density spot cooling using bulk

  15. Structural and economic analysis of capesize bulk carriers

    E-Print Network [OSTI]

    Hadjiyiannis, Nicholas

    2010-01-01T23:59:59.000Z

    Structural failures of bulk carriers continue to account for the loss of many lives every year. Capes are particularly vulnerable to cracking because of their large length, their trade in high density cargos, and the high ...

  16. New nano structure approaches for bulk thermoelectric materials

    E-Print Network [OSTI]

    Kim, Jeonghoon

    2010-01-01T23:59:59.000Z

    developments in bulk thermoelectric materials", M. Mater.and M. D. Drsselhaus, "Thermoelectric figure of merit of aO'Quinn, " Thin-film thermoelectric devices with high room-

  17. Bulk Viscosity Effects in Event-by-Event Relativistic Hydrodynamics

    E-Print Network [OSTI]

    Jacquelyn Noronha-Hostler; Gabriel S. Denicol; Jorge Noronha; Rone P. G. Andrade; Frederique Grassi

    2013-05-10T23:59:59.000Z

    Bulk viscosity effects on the collective flow harmonics in heavy ion collisions are investigated, on an event by event basis, using a newly developed 2+1 Lagrangian hydrodynamic code named v-USPhydro which implements the Smoothed Particle Hydrodynamics (SPH) algorithm for viscous hydrodynamics. A new formula for the bulk viscous corrections present in the distribution function at freeze-out is derived starting from the Boltzmann equation for multi-hadron species. Bulk viscosity is shown to enhance the collective flow Fourier coefficients from $v_2(p_T)$ to $v_5(p_T)$ when $% p_{T}\\sim 1-3$ GeV even when the bulk viscosity to entropy density ratio, $% \\zeta/s$, is significantly smaller than $1/(4\\pi)$.

  18. Bulk viscosity in nuclear and quark matter: A short review

    E-Print Network [OSTI]

    Hui Dong; Nan Su; Qun Wang

    2007-03-05T23:59:59.000Z

    The history and recent progresses in the study of bulk viscosity in nuclear and quark matter are reviewed. The constraints from baryon number conservation and electric neutrality in quark matter on particle densities and fluid velocity divergences are discussed.

  19. Efficient Bulk Data Replication for the Earth System Grid

    E-Print Network [OSTI]

    Sim, Alex

    2010-01-01T23:59:59.000Z

    Bulk Data Replication for the Earth System Grid Alex Sim 1 ,CA 94720, USA Abstract The Earth System Grid (ESG) communityNetLogger 1. Introduction The Earth System Grid (ESG) [1

  20. abdominal bulking mass: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Y. Burnier; M. Laine 2013-11-13 4 Neutrino mass, bulk majoron and neutrinoless double beta decay HEP - Phenomenology (arXiv) Summary: A new economical model for neutrino...

  1. Supply chain management in the dry bulk shipping industry

    E-Print Network [OSTI]

    Nicholson, Bryan E. (Bryan Edward)

    2006-01-01T23:59:59.000Z

    This paper is intended to show the importance of supply chain management in the dry-bulk shipping industry. A hypothetical company, the Texas Grain and Bakery Corporation, was created. The values and calculations used are ...

  2. Bulk viscosity and the conformal anomaly in the pion gas

    E-Print Network [OSTI]

    D. Fernandez-Fraile; A. Gomez Nicola

    2009-02-27T23:59:59.000Z

    We calculate the bulk viscosity of the massive pion gas within Unitarized Chiral Perturbation Theory. We obtain a low temperature peak arising from explicit conformal breaking due to the pion mass and another peak near the critical temperature, dominated by the conformal anomaly through gluon condensate terms. The correlation between bulk viscosity and conformal breaking supports a recent QCD proposal. We discuss the role of resonances, heavier states and large-$N_c$ counting.

  3. Costs, Savings and Financing Bulk Tanks on Texas Dairy Farms.

    E-Print Network [OSTI]

    Moore, Donald S.; Stelly, Randall; Parker, Cecil A.

    1958-01-01T23:59:59.000Z

    \\ BULLETIN 904 MAY 1958 .t(. :a ,s - / cwdh\\@ Costs, Savi~gs;.itd Financing Bulk Tanks on Texas Dairy Farms . ?. I I 1 i I I ! ,:ravings in hauling - 10 cents I \\ \\ 1 \\ savings in hauling - 15 cents -----------____--- 'savings... in hauling - 20 cents Annual production, 1,000 pounds Estimated number of years required for savings from a bulk tank to equal additional costs at different levels of production and savings in hauling costs. TEXAS AGRICULTURAL EXPERIMEN'T STATION R. D...

  4. Cosmic No Hair for Braneworlds with a Bulk Dilaton Field

    E-Print Network [OSTI]

    James E. Lidsey; David Seery

    2005-09-22T23:59:59.000Z

    Braneworld cosmology supported by a bulk scalar field with an exponential potential is developed. A general class of separable backgrounds for both single and two-brane systems is derived, where the bulk metric components are given by products of world-volume and bulk coordinates and the world-volumes represent any anisotropic and inhomogeneous solution to an effective four-dimensional Brans-Dicke theory of gravity. We deduce a cosmic no hair theorem for all ever expanding, spatially homogeneous Bianchi world-volumes and find that the spatially flat and isotropic inflationary scaling solution represents a late-time attractor when the bulk potential is sufficiently flat. The dependence of this result on the separable nature of the bulk metric is investigated by applying the techniques of Hamilton-Jacobi theory to five-dimensional Einstein gravity. We employ the spatial gradient expansion method to determine the asymptotic form of the bulk metric up to third-order in spatial gradients. It is found that the condition for the separable form of the metric to represent the attractor of the system is precisely the same as that for the four-dimensional world-volume to isotropize. We also derive the fourth-order contribution to the Hamilton-Jacobi generating functional. Finally, we conclude by placing our results within the context of the holographic approach to braneworld cosmology.

  5. ABPDU - Advanced Biofuels Process Demonstration Unit

    SciTech Connect (OSTI)

    None

    2011-01-01T23:59:59.000Z

    Lawrence Berkeley National Lab opened its Advanced Biofuels Process Demonstration Unit on Aug. 18, 2011.

  6. Manufacturing Demonstration Facilities Workshop Agenda, March...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Manufacturing Demonstration Facility Workshop Critical Materials Workshop Agenda Innovative Manufacturing Initiatives Recognition Day...

  7. Reversible piezomagnetoelectric switching in bulk polycrystalline ceramics

    SciTech Connect (OSTI)

    Stevenson, T., E-mail: t.j.stevenson@leeds.ac.uk; Bennett, J.; Brown, A. P.; Wines, T.; Bell, A. J.; Comyn, T. P. [Institute for Materials Research, University of Leeds, Leeds LS2 9JT (United Kingdom); Smith, R. I. [ISIS Neutron Facility, Rutherford Appleton Laboratory, Didcot OX11 0QX (United Kingdom)

    2014-08-01T23:59:59.000Z

    Magnetoelectric (ME) coupling in materials offer tremendous advantages in device functionality enabling technologies including advanced electronic memory, combining electronic speed, and efficiency with magnetic robustness. However, low cost polycrystalline ME materials are excluded from most commercial applications, operating only at cryogenic temperatures, impractically large electric/magnetic fields, or with low ME coefficients (1-100 mV/cm?Oe). Despite this, the technological potential of single compound ME coupling has continued to drive research into multiferroics over the last two decades. Here we show that by manipulating the large induced atomic strain within the polycrystalline, room temperature multiferroic compound 0.7BiFeO{sub 3}–0.3PbTiO{sub 3}, we can induce a reversible, piezoelectric strain controlled ME effect. Employing an in situ neutron diffraction experiment, we have demonstrated that this piezomagnetoelectric effect manifests with an applied electric field >8 kV/mm at the onset of piezoelectric strain, engineered in to the compound by crystallographic phase mixing. This produces a remarkable intrinsic ME coefficient of 1276 mV/cm?Oe, due to a strain driven modification to the oxygen sub-lattice, inducing an increase in magnetic moment per Fe{sup 3+} ion of +0.142 ?{sub B}. This work provides a framework for investigations into strain engineered nanostructures to realize low-cost ME devices designed from the atoms up, as well as contributing to the deeper understanding of single phase ME coupling mechanisms.

  8. Advance Resource Provisioning in Bulk Data Scheduling

    SciTech Connect (OSTI)

    Balman, Mehmet

    2012-10-01T23:59:59.000Z

    Today?s scientific and business applications generate mas- sive data sets that need to be transferred to remote sites for sharing, processing, and long term storage. Because of increasing data volumes and enhancement in current net- work technology that provide on-demand high-speed data access between collaborating institutions, data handling and scheduling problems have reached a new scale. In this paper, we present a new data scheduling model with ad- vance resource provisioning, in which data movement operations are defined with earliest start and latest comple- tion times. We analyze time-dependent resource assign- ment problem, and propose a new methodology to improve the current systems by allowing researchers and higher-level meta-schedulers to use data-placement as-a-service, so they can plan ahead and submit transfer requests in advance. In general, scheduling with time and resource conflicts is NP-hard. We introduce an efficient algorithm to organize multiple requests on the fly, while satisfying users? time and resource constraints. We successfully tested our algorithm in a simple benchmark simulator that we have developed, and demonstrated its performance with initial test results.

  9. Macromolecular Reaction Engineering Control of Bulk Propylene Polymerizations Operated with Multiple Catalysts through

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Macromolecular Reaction Engineering Control of Bulk Propylene Polymerizations Operated: Control of Bulk Propylene Polymerizations Operated with Multiple Catalysts through Controller: Abstract: This article presents a model to describe the dynamic behavior of bulk propylene polymerizations

  10. Report of the Bulk Working Group

    SciTech Connect (OSTI)

    Tobin, J G

    2010-02-09T23:59:59.000Z

    The world in general and the USA in particular are facing an oncoming energy shortage. One key mechanism to provide carbon-free energy is nuclear fission. At this point, 20% of the US electrical power grid is supplied by nuclear energy. (Interestingly, it is 50% in Illinois.) European nations such as Sweden (50% nuclear electricity) and France (80% nuclear electricity) are pushing ahead with permanent radioactive waste storage and processing. If nothing else, the USA needs to provide the scientific foundation for improving its nuclear-power generation facilities. One key issue and how the APS could affect it are discussed below. (This discussion of this issue is not meant to be a comprehension argument in support of a facility but merely an example of the sort of science that could be pursued. An exhaustive collection of arguments would take more time and effort.) The modification of various zones inside a nuclear fuel is an important issue. This includes microscopic re-crystallization, stress, fission gas production, He bubble formation and the intermixing, depletion and enrichment of various chemical, daughter and other isotopic species. For example, past studies of the ternary nuclear fuel UPuZr have demonstrated constituent redistribution when irradiated or with thermal treatment. The concentration variations shown above are of significant concern. Driven in part by the thermal gradient within the nuclear fuel, these variations can affect reactor performance and fuel burn-up levels. Similar gradients were observed in samples that were not irradiated but underwent thermal gradient treatments. From measurement such as these, kinetic parameters such as effective inter-diffusion coefficients were derived. The amount of such experimental data is very limited. Interaction of the fuel constituents with cladding and coolant are also important. At present, INL scientists pursue a number of measurements on-site at INL and off-site to address issues such as this. Here, we will propose two key examples of how a new facility at the APS could impact this technological issue.

  11. Solar Cells: Spin-Cast Bulk Heterojunction Solar Cells: A Dynamical...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Solar Cells: Spin-Cast Bulk Heterojunction Solar Cells: A Dynamical Investigation Solar Cells: Spin-Cast Bulk Heterojunction Solar Cells: A Dynamical Investigation Print Wednesday,...

  12. NREL Certifies First All-Quantum-Dot Photovoltaic Cell; Demonstrates Stability, Performance (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2011-02-01T23:59:59.000Z

    Researchers at the National Renewable Energy Laboratory (NREL) have certified the first all-quantum-dot photovoltaic cell, which was based on lead sulfide and demonstrated reasonable quantum dot solar cell performance for an initial efficiency measurement along with good stability. The certified open-circuit voltage of the quantum dot cell is greater than that possible from bulk lead sulfide because of quantum confinement.

  13. Dark goo: Bulk viscosity as an alternative to dark energy

    E-Print Network [OSTI]

    Jean-Sebastien Gagnon; Julien Lesgourgues

    2011-09-16T23:59:59.000Z

    We present a simple (microscopic) model in which bulk viscosity plays a role in explaining the present acceleration of the universe. The effect of bulk viscosity on the Friedmann equations is to turn the pressure into an "effective" pressure containing the bulk viscosity. For a sufficiently large bulk viscosity, the effective pressure becomes negative and could mimic a dark energy equation of state. Our microscopic model includes self-interacting spin-zero particles (for which the bulk viscosity is known) that are added to the usual energy content of the universe. We study both background equations and linear perturbations in this model. We show that a dark energy behavior is obtained for reasonable values of the two parameters of the model (i.e. the mass and coupling of the spin-zero particles) and that linear perturbations are well-behaved. There is no apparent fine tuning involved. We also discuss the conditions under which hydrodynamics holds, in particular that the spin-zero particles must be in local equilibrium today for viscous effects to be important.

  14. Dark goo: Bulk viscosity as an alternative to dark energy

    E-Print Network [OSTI]

    Gagnon, Jean-Sebastien

    2011-01-01T23:59:59.000Z

    We present a simple (microscopic) model in which bulk viscosity plays a role in explaining the present acceleration of the universe. The effect of bulk viscosity on the Friedmann equations is to turn the pressure into an "effective" pressure containing the bulk viscosity. For a sufficiently large bulk viscosity, the effective pressure becomes negative and could mimic a dark energy equation of state. Our microscopic model includes self-interacting spin-zero particles (for which the bulk viscosity is known) that are added to the usual energy content of the universe. We study both background equations and linear perturbations in this model. We show that a dark energy behavior is obtained for reasonable values of the two parameters of the model (i.e. the mass and coupling of the spin-zero particles) and that linear perturbations are well-behaved. There is no apparent fine tuning involved. We also discuss the conditions under which hydrodynamics holds, in particular that the spin-zero particles must be in local eq...

  15. Bulk emission of scalars by a rotating black hole

    E-Print Network [OSTI]

    M. Casals; S. R. Dolan; P. Kanti; E. Winstanley

    2008-07-17T23:59:59.000Z

    We study in detail the scalar-field Hawking radiation emitted into the bulk by a higher-dimensional, rotating black hole. We numerically compute the angular eigenvalues, and solve the radial equation of motion in order to find transmission factors. The latter are found to be enhanced by the angular momentum of the black hole, and to exhibit the well-known effect of superradiance. The corresponding power spectra for scalar fields show an enhancement with the number of dimensions, as in the non-rotating case. We compute the total mass loss rate of the black hole for a variety of black-hole angular momenta and bulk dimensions, and find that, in all cases, the bulk emission remains significantly smaller than the brane emission. The angular-momentum loss rate is also computed and found to have a smaller value in the bulk than on the brane. We present accurate bulk-to-brane emission ratios for a range of scenarios.

  16. Bayesian nonparametric reward learning from demonstration

    E-Print Network [OSTI]

    Michini, Bernard (Bernard J.)

    2013-01-01T23:59:59.000Z

    Learning from demonstration provides an attractive solution to the problem of teaching autonomous systems how to perform complex tasks. Demonstration opens autonomy development to non-experts and is an intuitive means of ...

  17. HTI retrieval demonstration project execution plan

    SciTech Connect (OSTI)

    Ellingson, D.R.

    1997-09-04T23:59:59.000Z

    This plan describes the process for demonstrating the retrieval of difficult Hanford tank waste forms utilizing commercial technologies and the private sector to conduct the operations. The demonstration is to be conducted in Tank 241-C-106.

  18. 2015 Joint Capability Technology Demonstration Industry Day

    Broader source: Energy.gov [DOE]

    The Smart Power Infrastructure Demonstration for Energy Reliability and Security (SPIDERS) Joint Capability Technology Demonstration (JCTD) Phase 3 Industry Day will be on August 27, 2015, from 8 a.m. to noon at the Hawaii Convention Center.

  19. SPIDERS Joint Capability Technology Demonstration Industry Day

    Broader source: Energy.gov [DOE]

    The Smart Power Infrastructure Demonstration for Energy Reliability and Security (SPIDERS) Joint Capability Technology Demonstration (JCTD) Industry Day occurred April 22, 2014, from 8 a.m. to 1:30 p.m. at Fort Carson, Colorado.

  20. Anomalous absorption of bulk shear sagittal acoustic waves in a layered structure with viscous fluid

    E-Print Network [OSTI]

    Dmitri K. Gramotnev; Melissa L. Mather; Timo A. Nieminen

    2005-09-05T23:59:59.000Z

    It is demonstrated theoretically that the absorptivity of bulk shear sagittal waves by an ultra-thin layer of viscous fluid between two different elastic media has a strong maximum (in some cases as good as 100%) at an optimal layer thickness. This thickness is usually much smaller than the penetration depths and lengths of transverse and longitudinal waves in the fluid. The angular dependencies of the absorptivity are demonstrated to have significant and unusual structure near critical angles of incidence. The effect of non-Newtonian properties and non-uniformities of the fluid layer on the absorptivity is also investigated. In particular, it is shown that the absorption in a thin layer of viscous fluid is much more sensitive to non-zero relaxation time(s) in the fluid layer than the absorption at an isolated solid-fluid interface.

  1. Achieving and Demonstrating Vehicle Technologies Engine Fuel...

    Broader source: Energy.gov (indexed) [DOE]

    Engine Fuel Efficiency Milestones Achieving and Demonstrating Vehicle Technologies Engine Fuel Efficiency Milestones 2009 DOE Hydrogen Program and Vehicle Technologies...

  2. Webinar: Hydrogen Storage Materials Database Demonstration

    Broader source: Energy.gov [DOE]

    Video recording and text version of the webinar, Hydrogen Storage Materials Database Demonstration, originally presented on December 13, 2011.

  3. Frequently Asked Questions About the Technology Demonstration...

    Energy Savers [EERE]

    installationinterfacecontrol issues. Qualitative performance is investigated via feedback surveys of the relevant user communities. Demonstration results are widely shared and...

  4. Webinar: National Hydrogen Learning Demonstration Status

    Broader source: Energy.gov [DOE]

    Video recording and text version of the webinar, "National Hydrogen Learning Demonstration Status," originally presented on February 6, 2012.

  5. Industrial Scale Demonstration of Smart Manufacturing Achieving...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Scale Demonstration of Smart Manufacturing Achieving Transformational Energy Productivity Gains Development of an Open Architecture, Widely Applicable Smart Manufacturing...

  6. Kinetics of Cold-Cap Reactions for Vitrification of Nuclear Waste Glass Based on Simultaneous Differential Scanning Calorimetry - Thermogravimetry (DSC-TGA) and Evolved Gas Analysis (EGA)

    SciTech Connect (OSTI)

    Rodriguez, Carmen P. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); ; Pierce, David A. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); ; Schweiger, Michael J. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); ; Kruger, Albert A. [USDOE Office of River Protection, Richland, WA (United States); Chun, Jaehun [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); ; Hrma, Pavel R. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States);

    2013-12-03T23:59:59.000Z

    For vitrifying nuclear waste glass, the feed, a mixture of waste with glass-forming and modifying additives, is charged onto the cold cap that covers 90-100% of the melt surface. The cold cap consists of a layer of reacting molten glass floating on the surface of the melt in an all-electric, continuous glass melter. As the feed moves through the cold cap, it undergoes chemical reactions and phase transitions through which it is converted to molten glass that moves from the cold cap into the melt pool. The process involves a series of reactions that generate multiple gases and subsequent mass loss and foaming significantly influence the mass and heat transfers. The rate of glass melting, which is greatly influenced by mass and heat transfers, affects the vitrification process and the efficiency of the immobilization of nuclear waste. We studied the cold-cap reactions of a representative waste glass feed using both the simultaneous differential scanning calorimetry thermogravimetry (DSC-TGA) and the thermogravimetry coupled with gas chromatography-mass spectrometer (TGA-GC-MS) as complementary tools to perform evolved gas analysis (EGA). Analyses from DSC-TGA and EGA on the cold-cap reactions provide a key element for the development of an advanced cold-cap model. It also helps to formulate melter feeds for higher production rate.

  7. Quality Assurance Project Plan for the treatability study of in situ vitrification of Seepage Pit 1 in Waste Area Grouping 7 at Oak Ridge National Laboratory

    SciTech Connect (OSTI)

    NONE

    1995-07-01T23:59:59.000Z

    This Quality Assurance Project Plan (QAPjP) establishes the quality assurance procedures and requirements to be implemented for the control of quality-related activities for Phase 3 of the Treatability Study (TS) of In Situ Vitrification (ISV) of Seepage Pit 1, ORNL Waste Area Grouping 7. This QAPjP supplements the Quality Assurance Plan for Oak Ridge National Laboratory Environmental Restoration Program by providing information specific to the ISV-TS. Phase 3 of the TS involves the actual ISV melt operations and posttest monitoring of Pit 1 and vicinity. Previously, Phase 1 activities were completed, which involved determining the boundaries of Pit 1, using driven rods and pipes and mapping the distribution of radioactivity using logging tools within the pipes. Phase 2 involved sampling the contents, both liquid and solids, in and around seepage Pit 1 to determine their chemical and radionuclide composition and the spatial distribution of these attributes. A separate QAPjP was developed for each phase of the project. A readiness review of the Phase 3 activities presented QAPjP will be conducted prior to initiating field activities, and an Operational Acceptance, Test (OAT) will also be conducted with no contamination involved. After, the OAT is complete, the ISV process will be restarted, and the melt will be allowed to increase with depth and incorporate the radionuclide contamination at the bottom of Pit 1. Upon completion of melt 1, the equipment will be shut down and mobilized to an adjacent location at which melt 2 will commence.

  8. Technical evaluation summary of the in situ vitrification melt expulsion at the Oak Ridge National Laboratory on April 21, 1996, Oak Ridge, Tennessee

    SciTech Connect (OSTI)

    NONE

    1996-07-01T23:59:59.000Z

    On April 21, 1996, at 6:12 PM, about 20 tons of molten glass were expelled from a 216-ton body of molten (1600 C) radioactively contaminated soil (containing 2.4 Ci {sup 137}Cs) at an ORNL site. This was caused by pressurized steam venting rapidly through, rather than around, the molten body. During the previous 17 days, an old seepage pit was undergoing in situ vitrification to convert porous, leachable soil into an impermeable waste form. Analyses revealed that 0.13 {mu}Ci of {sup 137}Cs could have been released and would have delivered a hypothetical, unmeasurable dose of 0.02 {mu}rem to the nearest private residence outside the Oak Ridge Reservation. The expelled glass particles, having a uniform specific activity of 1.2E-08 Ci/g, contained no smearable or transferrable activity. Thus, the overall environmental impact was insignificant. Fire damage was completely limited to the off-gas hood. Techniques were identified to minimize the probability of future melt expulsions.

  9. Volatility and entrainment of feed components and product glass characteristics during pilot-scale vitrification of simulated Hanford site low-level waste

    SciTech Connect (OSTI)

    Shade, J.W.

    1996-05-03T23:59:59.000Z

    Commercially available melter technologies were tested for application to vitrification of Hanford site low-level waste (LLW). Testing was conducted at vendor facilities using a non-radioactive LLW simulant. Technologies tested included four Joule-heated melter types, a carbon electrode melter, a cyclone combustion melter, and a plasma torch-fired melter. A variety of samples were collected during the vendor tests and analyzed to provide data to support evaluation of the technologies. This paper describes the evaluation of melter feed component volatility and entrainment losses and product glass samples produced during the vendor tests. All vendors produced glasses that met minimum leach criteria established for the test glass formulations, although in many cases the waste oxide loading was less than intended. Entrainment was much lower in Joule-heated systems than in the combustion or plasma torch-fired systems. Volatility of alkali metals, halogens, B, Mo, and P were severe for non-Joule-heated systems. While losses of sulfur were significant for all systems, the volatility of other components was greatly reduced for some configurations of Joule-heated melters. Data on approaches to reduce NO{sub x} generation, resulting from high nitrate and nitrite content in the double-shell slurry feed, are also presented.

  10. Preparation of bulk superhard B-C-N nanocomposite compact

    DOE Patents [OSTI]

    Zhao, Yusheng (Los Alamos, NM); He, Duanwei (Sichuan, CN)

    2011-05-10T23:59:59.000Z

    Bulk, superhard, B--C--N nanocomposite compacts were prepared by ball milling a mixture of graphite and hexagonal boron nitride, encapsulating the ball-milled mixture at a pressure in a range of from about 15 GPa to about 25 GPa, and sintering the pressurized encapsulated ball-milled mixture at a temperature in a range of from about 1800-2500 K. The product bulk, superhard, nanocomposite compacts were well sintered compacts with nanocrystalline grains of at least one high-pressure phase of B--C--N surrounded by amorphous diamond-like carbon grain boundaries. The bulk compacts had a measured Vicker's hardness in a range of from about 41 GPa to about 68 GPa.

  11. Bulk Viscosity and Particle Creation in the Inflationary Cosmology

    E-Print Network [OSTI]

    Mehdi Eshaghi; Nematollah Riazi; Ahmad Kiasatpour

    2015-04-29T23:59:59.000Z

    We study particle creation in the presence of bulk viscosity of cosmic fluid in the early universe within the framework of open thermodynamical systems. Since the first-order theory of non-equilibrium thermodynamics is non-causal and unstable, we try to solve the bulk viscosity equation of the cosmic fluid with particle creation through the full causal theory. By adopting an appropriate function for particle creation rate of "Creation of Cold Dark Matter" model, we obtain analytical solutions which do not suffer from the initial singularity and are in agreement with equivalent solutions of Lambda-CDM model. We constrain the free parameter of particle creation in our model based on recent Planck data. It is also found that the inflationary solution is driven by bulk viscosity with or without particle creation.

  12. Bulk Viscosity, Decaying Dark Matter, and the Cosmic Acceleration

    E-Print Network [OSTI]

    James R. Wilson; Grant J. Mathews; George M. Fuller

    2006-09-25T23:59:59.000Z

    We discuss a cosmology in which cold dark-matter particles decay into relativistic particles. We argue that such decays could lead naturally to a bulk viscosity in the cosmic fluid. For decay lifetimes comparable to the present hubble age, this bulk viscosity enters the cosmic energy equation as an effective negative pressure. We investigate whether this negative pressure is of sufficient magnitude to account fo the observed cosmic acceleration. We show that a single decaying species in a flat, dark-matter dominated cosmology without a cosmological constant cannot reproduce the observed magnitude-redshift relation from Type Ia supernovae. However, a delayed bulk viscosity, possibly due to a cascade of decaying particles may be able to account for a significant fraction of the apparent cosmic acceleration. Possible candidate nonrelativistic particles for this scenario include sterile neutrinos or gauge-mediated decaying supersymmetric particles.

  13. Bulk Viscosity and Particle Creation in the Inflationary Cosmology

    E-Print Network [OSTI]

    Eshaghi, Mehdi; Kiasatpour, Ahmad

    2015-01-01T23:59:59.000Z

    We study particle creation in the presence of bulk viscosity of cosmic fluid in the early universe within the framework of open thermodynamical systems. Since the first-order theory of non-equilibrium thermodynamics is non-causal and unstable, we try to solve the bulk viscosity equation of the cosmic fluid with particle creation through the full causal theory. By adopting an appropriate function for particle creation rate of "Creation of Cold Dark Matter" model, we obtain analytical solutions which do not suffer from the initial singularity and are in agreement with equivalent solutions of Lambda-CDM model. We constrain the free parameter of particle creation in our model based on recent Planck data. It is also found that the inflationary solution is driven by bulk viscosity with or without particle creation.

  14. Quasiparticle theory of shear and bulk viscosities of hadronic matter

    SciTech Connect (OSTI)

    Chakraborty, P.; Kapusta, J. I. [School of Physics and Astronomy, University of Minnesota, Minneapolis, Minnesota 55455 (United States)

    2011-01-15T23:59:59.000Z

    A theoretical framework for the calculation of shear and bulk viscosities of hadronic matter at finite temperature is presented. The framework is based on the quasiparticle picture. It allows for an arbitrary number of hadron species with pointlike interactions, and allows for both elastic and inelastic collisions. Detailed balance is ensured. The particles have temperature-dependent masses arising from mean-field or potential effects, which maintains self-consistency between the equation of state and the transport coefficients. As an example, we calculate the shear and bulk viscosity in the linear {sigma} model. The ratio of shear viscosity to entropy density shows a minimum in the vicinity of a rapid crossover transition, whereas the ratio of bulk viscosity to entropy density shows a maximum.

  15. Properties of Bulk Sintered Silver As a Function of Porosity

    SciTech Connect (OSTI)

    Wereszczak, Andrew A [ORNL; Vuono, Daniel J [ORNL; Wang, Hsin [ORNL; Ferber, Mattison K [ORNL; Liang, Zhenxian [ORNL

    2012-06-01T23:59:59.000Z

    This report summarizes a study where various properties of bulk-sintered silver were investigated over a range of porosity. This work was conducted within the National Transportation Research Center's Power Device Packaging project that is part of the DOE Vehicle Technologies Advanced Power Electronics and Electric Motors Program. Sintered silver, as an interconnect material in power electronics, inherently has porosity in its produced structure because of the way it is made. Therefore, interest existed in this study to examine if that porosity affected electrical properties, thermal properties, and mechanical properties because any dependencies could affect the intended function (e.g., thermal transfer, mechanical stress relief, etc.) or reliability of that interconnect layer and alter how its performance is modeled. Disks of bulk-sintered silver were fabricated using different starting silver pastes and different sintering conditions to promote different amounts of porosity. Test coupons were harvested out of the disks to measure electrical resistivity and electrical conductivity, thermal conductivity, coefficient of thermal expansion, elastic modulus, Poisson's ratio, and yield stress. The authors fully recognize that the microstructure of processed bulk silver coupons may indeed not be identical to the microstructure produced in thin (20-50 microns) layers of sintered silver. However, measuring these same properties with such a thin actual structure is very difficult, requires very specialized specimen preparation and unique testing instrumentation, is expensive, and has experimental shortfalls of its own, so the authors concluded that the herein measured responses using processed bulk sintered silver coupons would be sufficient to determine acceptable values of those properties. Almost all the investigated properties of bulk sintered silver changed with porosity content within a range of 3-38% porosity. Electrical resistivity, electrical conductivity, thermal conductivity, elastic modulus, Poisson's ratio, and yield stress all depended on the porosity content in bulk-sintered silver. The only investigated property that was independent of porosity in that range was coefficient of thermal expansion.

  16. FINAL REPORT MELTER TESTS WITH AZ-101 HLW SIMULANT USING A DURAMELTER 100 VITRIFICATION SYSTEM VSL-01R10N0-1 REV 1 2/25/02

    SciTech Connect (OSTI)

    KRUGER AA; MATLACK KS; KOT WK; PEGG IL

    2011-12-29T23:59:59.000Z

    This report provides data, analyses, and conclusions from a series of tests that were conducted at the Vitreous State Laboratory of The Catholic of America (VSL) to determine the processing rates that are achievable with AZ-101 HLW simulants and corresponding melter feeds on a DuraMelter 100 (DM100) vitrification system. One of the most critical pieces of information in determining the required size of the RPP-WTP HLW melter is the specific glass production rate in terms of the mass of glass that can be produced per unit area of melt surface per unit time. The specific glass production rate together with the waste loading (essentially, the ratio of waste-in to glass-out, which is determined from glass formulation activities) determines the melt area that is needed to achieve a given waste processing rate with due allowance for system availability. Tests conducted during Part B1 (VSL-00R2590-2) on the DM1000 vitrification system installed at the Vitreous State Laboratory of The Catholic University of America showed that, without the use of bubblers, glass production rates with AZ-101 and C-106/AY-102 simulants were significantly lower than the Project design basis rate of 0.4 MT/m{sup 2}/d. Conversely, three-fold increases over the design basis rate were demonstrated with the use of bubblers. Furthermore, an un-bubbled control test using a replica of the melter feed used in cold commissioning tests at West Valley reproduced the rates that were observed with that feed on the WVDP production melter. More recent tests conducted on the DM1200 system, which more closely represents the present RPP-WTP design, are in general agreement with these earlier results. Screening tests conducted on the DM10 system have provided good indications of the larger-scale processing rates with bubblers (for both HL W and LAW feeds) but significantly overestimated the DM1000 un-bubbled rate observed for C-106/AY-102 melter feeds. This behavior is believed to be a consequence of the role of heat transfer in rate attainment and the much greater role of wall effects in heat transfer when the melt pool is not agitated. The DM100 melter used for the present tests has a surface area of 0.108 m{sup 2}, which is approximately 5 times larger than that of the DM10 (0.021 m{sup 2}) and approximately 11 times smaller than that of the DM1000 (1.2 m{sup 2}) (the DM1000 has since been replaced by a pilot-scale prototypical HLW melter, designated the DM1200, which has the same surface area as the DM1000). Testing on smaller melters is the most economical method for obtaining data over a wide range of operating conditions (particularly at extremes) and for guiding the more expensive tests that are performed at pilot-scale. Thus, one objective of these tests was to determine whether the DM100 melters are sufficiently large to reproduce the un-bubbled melt rates observed at the DM1000 scale, or to determine the extent of any off-set. DM100-scale tests can then be used to screen feed chemistry variations that may serve to increase the un-bubbled production rates prior to confirmation at pilot scale. Finally, extensive characterization data obtained on simulated HLW melter feeds formed from various glass forming additives indicated that there may be advantages in terms of feed rheology and stability to the replacement of some of the hydroxides by carbonates. A further objective of the present tests was therefore to identify any deleterious processing effects of such a change before adopting the carbonate feed as the baseline. Data from the WVDP melter using acidified (nitrated) feeds, and without bubbling, showed productions rates that are higher than those observed with the alkaline RPP feeds at the VSL. Therefore, the effect of feed acidification on production rate also was investigated. This work was performed under Test Specification, 'TSP-W375-00-00019, Rev 0, 'HLW-DM10 and DM100 Melter Tests' dated November 13, 2000 and the corresponding Test Plan. It should be noted, however, that the RPP-WTP Project directed a series of changes to the Test Plan as the result

  17. Bulk torsion fields in theories with large extra dimensions

    E-Print Network [OSTI]

    Biswarup Mukhopadhyaya; Somasri Sen; Soumitra SenGupta

    2002-04-25T23:59:59.000Z

    We study the consequences of spacetime torsion coexisting with gravity in the bulk in scenarios with large extra dimensions. Having linked torsion with the Kalb-Ramond antisymmetric tensor field arising in string theories, we examine its artifacts on the visible 3-brane when the extra dimensions are compactified. It is found that while torsion would have led to parity violation in a 4-dimensional framework, all parity violating effects disappear on the visible brane when the torsion originates in the bulk. However, such a scenario is found to have characteristics of its own, some of which can be phenomenologically significant.

  18. Bulk-edge correspondence for two-dimensional topological insulators

    E-Print Network [OSTI]

    G. M. Graf; M. Porta

    2013-03-19T23:59:59.000Z

    Topological insulators can be characterized alternatively in terms of bulk or edge properties. We prove the equivalence between the two descriptions for two-dimensional solids in the single-particle picture. We give a new formulation of the $\\mathbb{Z}_{2}$-invariant, which allows for a bulk index not relying on a (two-dimensional) Brillouin zone. When available though, that index is shown to agree with known formulations. The method also applies to integer quantum Hall systems. We discuss a further variant of the correspondence, based on scattering theory.

  19. Bulk viscosity of strongly coupled plasmas with holographic duals

    E-Print Network [OSTI]

    Steven S. Gubser; Silviu S. Pufu; Fabio D. Rocha

    2008-06-02T23:59:59.000Z

    We explain a method for computing the bulk viscosity of strongly coupled thermal plasmas dual to supergravity backgrounds supported by one scalar field. Whereas earlier investigations required the computation of the leading dissipative term in the dispersion relation for sound waves, our method requires only the leading frequency dependence of an appropriate Green's function in the low-frequency limit. With a scalar potential chosen to mimic the equation of state of QCD, we observe a slight violation of the lower bound on the ratio of the bulk and shear viscosities conjectured in arXiv:0708.3459.

  20. ENVIRONMENTAL SAMPLING USING LOCATION SPECIFIC AIR MONITORING IN BULK HANDLING FACILITIES

    SciTech Connect (OSTI)

    Sexton, L.; Hanks, D.; Degange, J.; Brant, H.; Hall, G.; Cable-Dunlap, P.; Anderson, B.

    2011-06-07T23:59:59.000Z

    Since the introduction of safeguards strengthening measures approved by the International Atomic Energy Agency (IAEA) Board of Governors (1992-1997), international nuclear safeguards inspectors have been able to utilize environmental sampling (ES) (e.g. deposited particulates, air, water, vegetation, sediments, soil and biota) in their safeguarding approaches at bulk uranium/plutonium handling facilities. Enhancements of environmental sampling techniques used by the IAEA in drawing conclusions concerning the absence of undeclared nuclear materials or activities will soon be able to take advantage of a recent step change improvement in the gathering and analysis of air samples at these facilities. Location specific air monitoring feasibility tests have been performed with excellent results in determining attribute and isotopic composition of chemical elements present in an actual test-bed sample. Isotopic analysis of collected particles from an Aerosol Contaminant Extractor (ACE) collection, was performed with the standard bulk sampling protocol used throughout the IAEA network of analytical laboratories (NWAL). The results yielded bulk isotopic values expected for the operations. Advanced designs of air monitoring instruments such as the ACE may be used in gas centrifuge enrichment plants (GCEP) to detect the production of highly enriched uranium (HEU) or enrichments not declared by a State. Researchers at Savannah River National Laboratory in collaboration with Oak Ridge National Laboratory are developing the next generation of ES equipment for air grab and constant samples that could become an important addition to the international nuclear safeguards inspector's toolkit. Location specific air monitoring to be used to establish a baseline environmental signature of a particular facility employed for comparison of consistencies in declared operations will be described in this paper. Implementation of air monitoring will be contrasted against the use of smear ES when used during unannounced inspections, design information verification, limited frequency unannounced access, and complementary access visits at bulk handling facilities. Analysis of technical features required for tamper indication and resistance will demonstrate the viability of successful application of the system in taking ES within a bulk handling location. Further exploration of putting this technology into practice is planned to include mapping uranium enrichment facilities for the identification of optimal for installation of air monitoring devices.

  1. Security-Constrained Adequacy Evaluation of Bulk Power System Reliability

    E-Print Network [OSTI]

    Security-Constrained Adequacy Evaluation of Bulk Power System Reliability Fang Yang, Student Member. Stefopoulos, Student Member, IEEE Abstract -- A framework of security-constrained adequacy evaluation (SCAE electric load while satisfying security constraints. It encompasses three main steps: (a) critical

  2. A phase space analysis for nonlinear bulk viscous cosmology

    E-Print Network [OSTI]

    Acquaviva, Giovanni

    2015-01-01T23:59:59.000Z

    We consider a Friedmann-Robertson-Walker spacetime filled with both viscous radiation and nonviscous dust. The former has a bulk viscosity which is proportional to an arbitrary power of the energy density, i.e. $\\zeta \\propto \\rho_v^{\

  3. A phase space analysis for nonlinear bulk viscous cosmology

    E-Print Network [OSTI]

    Giovanni Acquaviva; Aroonkumar Beesham

    2015-05-08T23:59:59.000Z

    We consider a Friedmann-Robertson-Walker spacetime filled with both viscous radiation and nonviscous dust. The former has a bulk viscosity which is proportional to an arbitrary power of the energy density, i.e. $\\zeta \\propto \\rho_v^{\

  4. Computing hypersurfaces which minimize surface energy plus bulk energy

    E-Print Network [OSTI]

    Sullivan, John M.

    such energies is an important step in the definition of flat curvature flows [ATW]. By modifying the bulk energy this precise by working in the context of currents, as in [ATW] or [S].) Here, if S and S0 are contained

  5. BULK TITANIUM MICROFLUIDIC NETWORKS FOR PROTEIN SELF-ASSEMBLY STUDIES

    E-Print Network [OSTI]

    MacDonald, Noel C.

    BULK TITANIUM MICROFLUIDIC NETWORKS FOR PROTEIN SELF-ASSEMBLY STUDIES E.R. Parker1 , L.S. Hirst2 developed micromachining technique to fabricate microfluidic networks in thin titanium foils. These devices been integrated into the fabrication process in order to minimize protein adsorption to the titanium

  6. TECHNICAL POLLUTION PREVENTION GUIDE FOR DRY BULK TERMINALS

    E-Print Network [OSTI]

    Practices 24 4.4 4.5 Pollutants 26 4.4.1 Fugitive Dust 26 4.4.2 Commodity Spillage 27 4.4.3 Oil, lubricant#12;TECHNICAL POLLUTION PREVENTION GUIDE FOR DRY BULK TERMINALS IN THE LOWER FRASER BASIN DOE FRAP 1996-19 Prepared for: Enviromnent Canada Environmental Protection Fraser Pollution Abatement North

  7. Development of Bulk Nanocrystalline Cemented Tungsten Carbide for Industrial Applicaitons

    SciTech Connect (OSTI)

    Z. Zak Fang, H. Y. Sohn

    2009-03-10T23:59:59.000Z

    This report contains detailed information of the research program entitled "Development of Bulk Nanocrystalline Cemented Tungsten Carbide Materials for Industrial Applications". The report include the processes that were developed for producing nanosized WC/Co composite powders, and an ultrahigh pressure rapid hot consolidation process for sintering of nanosized powders. The mechanical properties of consolidated materials using the nanosized powders are also reported.

  8. Learning Demonstration Progress Report -- Spring 2008

    SciTech Connect (OSTI)

    Wipke, K.; Sprik, S.; Kurtz, J.

    2008-04-01T23:59:59.000Z

    This report documents key results from DOE's Controlled Hydrogen Fleet and Infrastructure Validation and Demonstration Project based on data through December 2007.

  9. Selection Criteria for Demonstration Projects | Department of...

    Broader source: Energy.gov (indexed) [DOE]

    and Logistical Challenges to Smart Grid Implementation Demonstration and Deployment Workshop Day 1 Offshore Resource Assessment and Design Conditions Public Meeting Summary Report...

  10. Oak Ridge City Center Technology Demonstration Project

    Broader source: Energy.gov (indexed) [DOE]

    Oak Ridge City Center Technology Demonstration Project David Thrash, Principal Investigator Oak Ridge City Center, LLC Track Name May 18, 2010 This presentation does not contain...

  11. Commercial Building Demonstration and Deployment Overview - 2014...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Office's Commercial Building Demonstration and Deployment activities. Through robust feedback, the BTO Program Peer Review enhances existing efforts and improves future designs....

  12. The Smithsonian American Art Museum GATEWAY Demonstration

    Broader source: Energy.gov [DOE]

    View the video about using LEDs in a GATEWAY demonstration at the Smithsonian American Art Museum in Washington, DC, including an interview with lighting designer Scott Rosenfeld.

  13. Achieving and Demonstrating Vehicle Technologies Engine Fuel...

    Broader source: Energy.gov (indexed) [DOE]

    Vehicle Technologies Engine Fuel Efficiency Milestones Achieving and Demonstrating Vehicle Technologies Engine Fuel Efficiency Milestones 2010 DOE Vehicle Technologies and Hydrogen...

  14. Independent Oversight Review, West Valley Demonstration Project...

    Office of Environmental Management (EM)

    West Valley Demonstration Project - December 2014 3Q CY2005 (PDF), Facility Representative Program Performance Indicators Quarterly Report EA-1552: Final Environmental Assessment...

  15. Enterprise Assessments Review, West Valley Demonstration Project...

    Energy Savers [EERE]

    conducted an independent oversight review of activity-level implementation of the radiation protection program at the West Valley Demonstration Project. The onsite review...

  16. Innovative Breakthrough Demonstrated for Biological Ethanol Production...

    Office of Environmental Management (EM)

    for Biological Ethanol Production June 30, 2015 - 11:43am Addthis Advanced Biofuels Process Demonstration Unit at Lawrence Berkeley National Laboratory. Photo credit:...

  17. Daemen Alternative Energy/Geothermal Technologies Demonstration...

    Broader source: Energy.gov (indexed) [DOE]

    Daemen Alternative EnergyGeothermal Technologies Demonstration Program Erie County Robert C. Beiswanger, Jr. Daemen College May 20, 2010 This presentation does not contain any...

  18. Test and Demonstration Assets of New Mexico

    SciTech Connect (OSTI)

    None

    2008-03-31T23:59:59.000Z

    This document was developed by the Arrowhead Center of New Mexico State University as part of the National Security Preparedness Project (NSPP), funded by a DOE/NNSA grant. The NSPP has three primary components: business incubation, workforce development, and technology demonstration and validation. The document contains a survey of test and demonstration assets in New Mexico available for external users such as small businesses with security technologies under development. Demonstration and validation of national security technologies created by incubator sources, as well as other sources, are critical phases of technology development. The NSPP will support the utilization of an integrated demonstration and validation environment.

  19. National Hydrogen Learning Demonstration Status Webinar (Text...

    Broader source: Energy.gov (indexed) [DOE]

    Energy Association. Today, Mr. Wipke is here to talk to us about work on hydrogen fuel cell vehicles and the Controlled Hydrogen Fleet and Infrastructure Demonstration and...

  20. Honeywell Demonstrates Automated Demand Response Benefits for...

    Broader source: Energy.gov (indexed) [DOE]

    Honeywell's Smart Grid Investment Grant (SGIG) project demonstrates utility-scale performance of a hardwaresoftware platform for automated demand response (ADR). This project...

  1. Independent Activity Report, West Valley Demonstration Project...

    Broader source: Energy.gov (indexed) [DOE]

    July 2012 Operational Awareness Oversight of the West Valley Demonstration Project HIAR WVDP-2012-07-30 This Independent Activity Report documents an operational awareness...

  2. Demonstrating Fuel Consumption and Emissions Reductions with...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel Consumption and Emissions Reductions with Next Generation Model-Based Diesel Engine Control Demonstrating Fuel Consumption and Emissions Reductions with Next Generation...

  3. Smart Grid Demonstration Funding Opportunity Announcement DE...

    Broader source: Energy.gov (indexed) [DOE]

    Frequently asked questions about the Smart Grid Demonstration and Energy Storage Funding Opportunity Announcement released as part of the American Recovery and Reinvestment Act,...

  4. Energy Department Announces Offshore Wind Demonstration Awardees...

    Broader source: Energy.gov (indexed) [DOE]

    demonstration partnerships with broad consortia that are developing breakthrough offshore wind energy generation projects. The primary goals of these projects are to...

  5. Demonstration/Development of Reactivity Controlled Compression...

    Broader source: Energy.gov (indexed) [DOE]

    DemonstrationDevelopment of Reactivity Controlled Compression Ignition (RCCI) Combustion for High Efficiency, Low Emissions Vehicle Applications Dr. Rolf Reitz Wisconsin Engine...

  6. Electric Drive Vehicle Demonstration and Vehicle Infrastructure...

    Broader source: Energy.gov (indexed) [DOE]

    vs. Utility Meter Utilize communication strategies to alter EVSE operation - Demand Response demonstration Approach EVSE Utility HARDWARE DEPLOYMENT 7,871 Level 2...

  7. WEST VALLEY DEMONSTRATION PROJECT ANNUAL SITE ENVIRONMENTAL REPORT CALENDAR YEAR 2002

    SciTech Connect (OSTI)

    NONE

    2003-09-12T23:59:59.000Z

    This annual environmental monitoring report for the West Valley Demonstration Project (WVDP or Project) is published to inform those with interest about environmental conditions at the WVDP. In accordance with U.S. Department of Energy (DOE) Order 231.1, Environment, Safety, and Health Reporting, the report summarizes calendar year (CY) 2002 environmental monitoring data so as to describe the performance of the WVDP's environmental management system, confirm compliance with standards and regulations, and highlight important programs. In 2002, the West Valley Demonstration Project, the site of a DOE environmental cleanup activity operated by West Valley Nuclear Services Co. (WVNSCO), was in the final stages of stabilizing high-level radioactive waste (HLW) that remained at the site after commercial nuclear fuel reprocessing had been discontinued in the early 1970s. The Project is located in western New York State, about 30 miles south of Buffalo, within the New York State-owned Western New York Nuclear Service Center (WNYNSC). The WVDP is being conducted in cooperation with the New York State Energy Research and Development Authority (NYSERDA). Ongoing work activities at the WVDP during 2002 included: (1) completing HLW solidification and melter shutdown; (2) shipping low-level radioactive waste off-site for disposal; (3) constructing a facility where large high-activity components can be safely packaged for disposal; (4) packaging and removing spent materials from the vitrification facility; (5) preparing environmental impact statements for future activities; (6) removing as much of the waste left behind in waste tanks 8D-1 and 8D-2 as was reasonably possible; (7) removing storage racks, canisters, and debris from the fuel receiving and storage pool, decontaminating pool walls, and beginning shipment of debris for disposal; (8) ongoing decontamination in the general purpose cell and the process mechanical cell (also referred to as the head end cells); (9) planning for cleanup of waste in the plutonium purification cell (south) and extraction cell number 2 in the main plant; (10) ongoing characterization of facilities such as the waste tank farm and process cells; (11) monitoring the environment and managing contaminated areas within the Project facility premises; and (12) flushing and rinsing HLW solidification facilities.

  8. Vitrification and Product Testing of C-104 and AZ-102 Pretreated Sludge Mixed with Flowsheet Quantities of Secondary Wastes

    SciTech Connect (OSTI)

    Smith, Gary L.; Bates, Derrick J.; Goles, Ronald W.; Greenwood, Lawrence R.; Lettau, Ralph C.; Piepel, Gregory F.; Schweiger, Michael J.; Smith, Harry D.; Urie, Michael W.; Wagner, Jerome J.

    2001-02-01T23:59:59.000Z

    The U.S. Department of Energy (DOE) Office of River Protection (ORP) has acquired Hanford tank waste treatment services at a demonstration scale. The River Protection Project Waste Treatment Plant (RPP-WTP) team is responsible for producing an immobilized (vitrified) high-level waste (IHLW) waste form. Pacific Northwest National Laboratory, hereafter referred to as PNNL, has been contracted to produce and test a vitrified IHLW waste form from two Envelope D high-level waste (HLW) samples previously supplied to the RPP-WTP project by DOE.

  9. CALDERON COKEMAKING PROCESS/DEMONSTRATION PROJECT

    SciTech Connect (OSTI)

    Albert Calderon

    1999-06-23T23:59:59.000Z

    This project deals with the demonstration of a coking process using proprietary technology of Calderon, with the following objectives geared to facilitate commercialization: (1) making coke of such quality as to be suitable for use in hard-driving, large blast furnaces; (2) providing proof that such process is continuous and environmentally closed to prevent emissions; (3) demonstrating that high-coking-pressure (non-traditional) coal blends which cannot be safely charged into conventional by-product coke ovens can be used in the Calderon process; (4) conducting a blast furnace test to demonstrate the compatibility of the coke produced; and (5) demonstrating that coke can be produced economically, at a level competitive with coke imports. The activities of the past quarter were focused on the following: Detailed studies of LTV's site for the installation of the commercial Demonstration Unit with site specific layouts; Environmental Work; Firm commitments for funding from the private sector; and Federal funding to complement the private contribution.

  10. Buried waste integrated demonstration technology integration process

    SciTech Connect (OSTI)

    Ferguson, J.S.; Ferguson, J.E.

    1992-04-01T23:59:59.000Z

    A Technology integration Process was developed for the Idaho National Energy Laboratories (INEL) Buried Waste Integrated Demonstration (BWID) Program to facilitate the transfer of technology and knowledge from industry, universities, and other Federal agencies into the BWID; to successfully transfer demonstrated technology and knowledge from the BWID to industry, universities, and other Federal agencies; and to share demonstrated technologies and knowledge between Integrated Demonstrations and other Department of Energy (DOE) spread throughout the DOE Complex. This document also details specific methods and tools for integrating and transferring technologies into or out of the BWID program. The document provides background on the BWID program and technology development needs, demonstrates the direction of technology transfer, illustrates current processes for this transfer, and lists points of contact for prospective participants in the BWID technology transfer efforts. The Technology Integration Process was prepared to ensure compliance with the requirements of DOE's Office of Technology Development (OTD).

  11. Buried waste integrated demonstration technology integration process

    SciTech Connect (OSTI)

    Ferguson, J.S.; Ferguson, J.E.

    1992-04-01T23:59:59.000Z

    A Technology integration Process was developed for the Idaho National Energy Laboratories (INEL) Buried Waste Integrated Demonstration (BWID) Program to facilitate the transfer of technology and knowledge from industry, universities, and other Federal agencies into the BWID; to successfully transfer demonstrated technology and knowledge from the BWID to industry, universities, and other Federal agencies; and to share demonstrated technologies and knowledge between Integrated Demonstrations and other Department of Energy (DOE) spread throughout the DOE Complex. This document also details specific methods and tools for integrating and transferring technologies into or out of the BWID program. The document provides background on the BWID program and technology development needs, demonstrates the direction of technology transfer, illustrates current processes for this transfer, and lists points of contact for prospective participants in the BWID technology transfer efforts. The Technology Integration Process was prepared to ensure compliance with the requirements of DOE`s Office of Technology Development (OTD).

  12. High Efficiency m-plane LEDs on Low Defect Density Bulk GaN Substrates

    SciTech Connect (OSTI)

    David, Aurelien

    2012-10-15T23:59:59.000Z

    Solid-state lighting is a key technology for reduction of energy consumption in the US and worldwide. In principle, by replacing standard incandescent bulbs and other light sources with sources based on light-emitting diodes (LEDs), ultimate energy efficiency can be achieved. The efficiency of LEDs has improved tremendously over the past two decades, however further progress is required for solid- state lighting to reach its full potential. The ability of an LED at converting electricity to light is quantified by its internal quantum efficiency (IQE). The material of choice for visible LEDs is Gallium Nitride (GaN), which is at the basis of blue-emitting LEDs. A key factor limiting the performance of GaN LEDs is the so-called efficiency droop, whereby the IQE of the LED decreases significantly at high current density. Despite decades of research, efficiency droop remains a major issue. Since high-current operation is necessary for practical lighting applications, reducing droop is a major challenge for the scientific community and the LED industry. Our approach to solving the droop issue is the use of newly available low-defect-density bulk GaN non-polar substrates. In contrast to the standard foreign substrates (sapphire, silicon carbide, silicon) used in the industry, we have employed native bulk GaN substrates with very low defect density, thus ensuring exquisite material quality and high IQE. Whereas all commercial LEDs are grown along the c-plane crystal direction of GaN, we have used m-plane non-polar substrates; these drastically modify the physical properties of the LED and enable a reduction of droop. With this approach, we have demonstrated very high IQE performance and low droop. Our results focused on violet and blue LEDs. For these, we have demonstrated very high peak IQEs and current droops of 6% and 10% respectively (up to a high current density of 200A.cm-2). All these results were obtained under electrical operation. These high IQE and low droop values are in line with the program’s milestones. They demonstrate that bulk non-polar GaN substrates represent a disruptive technology for LED performance. Application of this technology to real-world products is feasible, provided that the cost of GaN substrates is compatible with the market’s requirement.

  13. Local and bulk 13C hyperpolarization in NV-centered diamonds at variable fields and orientations

    E-Print Network [OSTI]

    Gonzalo A. Alvarez; Christian O. Bretschneider; Ran Fischer; Paz London; Hisao Kanda; Shinobu Onoda; Junichi Isoya; David Gershoni; Lucio Frydman

    2014-12-30T23:59:59.000Z

    Polarizing nuclear spins is of fundamental importance in biology, chemistry and physics. Methods for hyperpolarizing 13C nuclei from free electrons in bulk, usually demand operation at cryogenic temperatures. Room-temperature approaches targeting diamonds with nitrogen-vacancy (NV) centers could alleviate this need, but hitherto proposed strategies lack generality as they demand stringent conditions on the strength and/or alignment of the magnetic field. We report here an approach for achieving efficient electron->13C spin alignment transfers, compatible with a broad range of magnetic field strengths and field orientations with respect to the diamond crystal. This versatility results from combining coherent microwave- and incoherent laser-induced transitions between selected energy states of the coupled electron-nuclear spin manifold. 13C-detected Nuclear Magnetic Resonance (NMR) experiments demonstrate that this hyperpolarization can be transferred via first-shell or via distant 13Cs, throughout the nuclear bulk ensemble. This method opens new perspectives for applications of diamond NV centers in NMR, and in quantum information processing.

  14. Marketing Plan for Demonstration and Validation Assets

    SciTech Connect (OSTI)

    None

    2008-05-30T23:59:59.000Z

    The National Security Preparedness Project (NSPP), is to be sustained by various programs, including technology demonstration and evaluation (DEMVAL). This project assists companies in developing technologies under the National Security Technology Incubator program (NSTI) through demonstration and validation of technologies applicable to national security created by incubators and other sources. The NSPP also will support the creation of an integrated demonstration and validation environment. This report documents the DEMVAL marketing and visibility plan, which will focus on collecting information about, and expanding the visibility of, DEMVAL assets serving businesses with national security technology applications in southern New Mexico.

  15. Vitrification and testing of a Hanford high-level waste sample, Part 2: Phase identification and waste form leachability

    SciTech Connect (OSTI)

    Hrma, Pavel R.; Crum, Jarrod V.; Bredt, Paul; Greenwood, Lawrence R.; Smith, H D.

    2005-10-01T23:59:59.000Z

    A sample of Hanford high-level radioactive waste from Tank AZ-101 was vitrified into borosilicate glass and tested to demonstrate its compliance with regulatory requirements. Compositional aspects of this study were reported in Part 1 of this paper. This second and last part presents results of crystallinity and leachability testing. Crystallinity was quantified in a glass sample heat treated according to the cooling curve of glass at the centerline of a Hanford Waste Treatment Plant canister. By quantitative X-ray diffraction analysis and image analysis applied to scanning electron microscopy micrographs, the sample contained 7 mass% of spinel, predominantly trevorite. Glass leachability was measured with the product consistency test and the toxicity characteristic leaching procedure. Measured data and model estimates were in reasonable agreement. Leachability results were close to those obtained for the nonradioactive simulant. Models were used to elucidate the effects of glass composition of spinel formation and to estimate effects of spinel formation on glass leachability.

  16. Method of fabricating an optoelectronic device having a bulk heterojunction

    DOE Patents [OSTI]

    Shtein, Max (Ann Arbor, MI); Yang, Fan (Princeton, NJ); Forrest, Stephen R. (Princeton, NJ)

    2008-10-14T23:59:59.000Z

    A method of fabricating an optoelectronic device comprises: depositing a first layer having protrusions over a first electrode, in which the first layer comprises a first organic small molecule material; depositing a second layer on the first layer such that the second layer is in physical contact with the first layer; in which the smallest lateral dimension of the protrusions are between 1 to 5 times the exciton diffusion length of the first organic small molecule material; and depositing a second electrode over the second layer to form the optoelectronic device. A method of fabricating an organic optoelectronic device having a bulk heterojunction is also provided and comprises: depositing a first layer with protrusions over an electrode by organic vapor phase deposition; depositing a second layer on the first layer where the interface of the first and second layers forms a bulk heterojunction; and depositing another electrode over the second layer.

  17. Bulk-Brane Interaction and Holographic Dark Energy

    E-Print Network [OSTI]

    M R Setare

    2006-12-14T23:59:59.000Z

    In this paper we consider the bulk-brane interaction to obtain the equation of state for the holographic energy density in non-flat universe enclosed by the event horizon measured from the sphere of horizon named $L$. We assumes that the cold dark matter energy density on the brane is conserved, but the holographic dark energy density on the brane is not conserved due to brane-bulk energy exchange. Our calculation show, taking $\\Omega_{\\Lambda}=0.73$ for the present time, the lower bound of $w_{\\rm \\Lambda}^{eff}$ is -0.9. This implies that one can not generate phantom-like equation of state from an interacting holographic dark energy model in non-flat universe.

  18. Bulk from Bi-locals in Thermo Field CFT

    E-Print Network [OSTI]

    Jevicki, Antal

    2015-01-01T23:59:59.000Z

    We study the Large $N$ dynamics of the $O(N)$ field theory in the Thermo field approach. Concentrating on the singlet bi-local space within the systematic $1/N$ framework of collective field theory we discuss the emergent bulk space-time and construct the associated (Higher spin) fields. We note the presence of `evanescent' modes in this construction and also the mixing of spins at finite temperature.

  19. Bulk from Bi-locals in Thermo Field CFT

    E-Print Network [OSTI]

    Antal Jevicki; Junggi Yoon

    2015-03-29T23:59:59.000Z

    We study the Large $N$ dynamics of the $O(N)$ field theory in the Thermo field approach. Concentrating on the singlet bi-local space within the systematic $1/N$ framework of collective field theory we discuss the emergent bulk space-time and construct the associated (Higher spin) fields. We note the presence of `evanescent' modes in this construction and also the mixing of spins at finite temperature.

  20. Magnetization of 2-G Coils and Artificial Bulks

    E-Print Network [OSTI]

    Coombs, T. A.; Fagnard, J. F.; Matsuda, K.

    2014-06-27T23:59:59.000Z

    or bulks. ? Index Terms—HTS, racetrack, YBCO, magnetisation I. INTRODUCTION BCO has been available, in various forms, since shortly after the initial discovery of high temperature superconductors by Bednorz and Mueller. All forms of YBCO have... those available from conventional materials such as copper (wires) or NdFeB (magnetic field) there remain relatively few industrial applications and the barriers to widespread adoption remain high. Devices such as Fault Current Limiters, cables...

  1. Comment on "Accelerating cosmological expansion from shear and bulk viscosity"

    E-Print Network [OSTI]

    Giovannini, Massimo

    2015-01-01T23:59:59.000Z

    In a recent Letter [Phys. Rev. Lett. 114 091301 (2105)] the cause of the acceleration of the present Universe has been identified with the shear viscosity of an imperfect relativistic fluid even in the absence of any bulk viscous contribution. The gist of this comment is that the shear viscosity, if anything, can only lead to an accelerated expansion over sufficiently small scales well inside the Hubble radius.

  2. Comparison of bulk- and surface-micromachined pressure sensors

    SciTech Connect (OSTI)

    Eaton, W.P.; Smith, J.H. [Sandia National Labs., Albuquerque, NM (United States); Monk, D.J.; O`Brien, G.; Miller, T.F. [Motorola, Phoenix, AZ (United States)

    1998-08-01T23:59:59.000Z

    Two piezoresistive micromachined pressure sensors were compared: a commercially available bulk-micromachined (BM) pressure sensor and an experimental surface-micromachined (SM) pressure sensor. While the SM parts had significantly smaller die sizes, they were outperformed in most areas by the BM parts. This was due primarily to the smaller piezoresistive gauge factor in the polysilicon piezoresistors in the SM parts compared to the single crystal strain gauge used in the BM parts.

  3. Demonstration of chalcogenide glass racetrack microresonators

    E-Print Network [OSTI]

    Kimerling, Lionel C.

    We have demonstrated what we believe to be the first chalcogenide glass racetrack microresonator using a complementary metal-oxide semiconductor-compatible lift-off technique with thermally evaporated As[subscript 2]S[subscript ...

  4. CALDERON COKEMAKING PROCESS/DEMONSTRATION PROJECT

    SciTech Connect (OSTI)

    Albert Calderon

    1999-09-22T23:59:59.000Z

    This project deals with the demonstration of a coking process using proprietary technology of Calderon, with the following objectives geared to facilitate commercialization: (1) making coke of such quality as to be suitable for use in hard-driving, large blast furnaces; (2) providing proof that such process is continuous and environmentally closed to prevent emissions; (3) demonstrating that high-coking-pressure (non-traditional) coal blends which cannot be safely charged into conventional by-product coke ovens can be used in the Calderon process; (4) conducting a blast furnace test to demonstrate the compatibility of the coke produced; and (5) demonstrating that coke can be produced economically, at a level competitive with coke imports. The activities of the past quarter were focused on the following: Detailed workings of the team; Proposal to FETC for Phase II; Permitting and Environmental Work; and Engineering Progress.

  5. Calderon Cokemaking Process/Demonstration Project

    SciTech Connect (OSTI)

    None

    1998-04-08T23:59:59.000Z

    This project deals with the demonstration of a coking process using proprietary technology of Calderon with the following objectives in order to enable its commercialization: (i) making coke of such quality as to be suitable for use in high driving (highly productive) blast furnaces; (ii) providing proof that such process is continuous and environmentally closed to prevent emissions; and (iii) demonstrating that high-coking-pressure (non-traditional) coal blends which cannot be safely charged into conventional by-product coke ovens can be used in the Calderon process. The activities of the past quarter were entirely focused on operating the Calderon Process Development Unit (PDU-I) in Alliance, Ohio conducting a series of tests under steady state using coal from Bethlehem Steel and U.S. Steel in order to demonstrate the above. The objectives mentioned above were successfully demonstrated.

  6. Technoclimat- Green Technologies Demonstration Program (Quebec, Canada)

    Broader source: Energy.gov [DOE]

    The Green technologies demonstration program aiming to reduce greenhouse gas emissions is a product of Measure 20 of the 2006-2012 Climate Change Action Plan (CCAP). This CCAP measure encourages...

  7. National Hydrogen Learning Demonstration Status (Presentation)

    SciTech Connect (OSTI)

    Wipke, K.; Sprik, S.; Kurtz, J.; Ramsden, T.; Ainscough, C.; Saur, G.

    2012-02-01T23:59:59.000Z

    This presentation discusses U.S. DOE Learning Demonstration Project goals, fuel cell vehicle and H2 station deployment status, and technical highlights of vehicle and infrastructure analysis results and progress.

  8. Demonstration and Deployment Strategy Workshop: Summary

    Broader source: Energy.gov [DOE]

    This report is based on the proceedings of the U.S. DOE’s Bioenergy Technologies Office Demonstration and Deployment Strategy Workshop, held on March 12–13, 2014, at Argonne National Laboratory.

  9. Status of the MAJORANA DEMONSTRATOR experiment

    SciTech Connect (OSTI)

    Martin, R. D. [Nuclear Science Division, Lawrence Berkeley National Laboratory, Berkeley, CA, USA and Department of Physics, University of South Dakota, Vermillion, SD (United States); Abgrall, N.; Chan, Y-D.; Hegai, A.; Mertens, S.; Poon, A. W. P.; Vetter, K. [Nuclear Science Division, Lawrence Berkeley National Laboratory, Berkeley, CA (United States); Aguayo, E.; Fast, J. E.; Hoppe, E. W.; Kouzes, R. T.; LaFerriere, B. D.; Orrell, J. L.; Overman, N. R.; Soin, A. [Pacific Northwest National Laboratory, Richland, WA (United States); Avignone III, F. T. [Department of Physics and Astronomy, University of South Carolina, Columbia, SC, USA and Oak Ridge National Laboratory, Oak Ridge, TN (United States); Barabash, A. S.; Konovalov, S. I.; Yumatov, V. [Institute for Theoretical and Experimental Physics, Moscow (Russian Federation); Bertrand, F. E. [Oak Ridge National Laboratory, Oak Ridge, TN (United States); and others

    2014-06-24T23:59:59.000Z

    The MAJORANA DEMONSTRATOR neutrinoless double beta-decay experiment is currently under construction at the Sanford Underground Research Facility in South Dakota, USA. An overview and status of the experiment are given.

  10. EFFECTIVE POROSITY IMPLIES EFFECTIVE BULK DENSITY IN SORBING SOLUTE TRANSPORT

    SciTech Connect (OSTI)

    Flach, G.

    2012-02-27T23:59:59.000Z

    The concept of an effective porosity is widely used in solute transport modeling to account for the presence of a fraction of the medium that effectively does not influence solute migration, apart from taking up space. This non-participating volume or ineffective porosity plays the same role as the gas phase in single-phase liquid unsaturated transport: it increases pore velocity, which is useful towards reproducing observed solute travel times. The prevalent use of the effective porosity concept is reflected by its prominent inclusion in popular texts, e.g., de Marsily (1986), Fetter (1988, 1993) and Zheng and Bennett (2002). The purpose of this commentary is to point out that proper application of the concept for sorbing solutes requires more than simply reducing porosity while leaving other material properties unchanged. More specifically, effective porosity implies the corresponding need for an effective bulk density in a conventional single-porosity model. The reason is that the designated non-participating volume is composed of both solid and fluid phases, both of which must be neglected for consistency. Said another way, if solute does not enter the ineffective porosity then it also cannot contact the adjoining solid. Conceptually neglecting the fluid portion of the non-participating volume leads to a lower (effective) porosity. Likewise, discarding the solid portion of the non-participating volume inherently leads to a lower or effective bulk density. In the author's experience, practitioners virtually never adjust bulk density when adopting the effective porosity approach.

  11. Standard practice for bulk sampling of liquid uranium hexafluoride

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2001-01-01T23:59:59.000Z

    1.1 This practice covers methods for withdrawing representative samples of liquid uranium hexafluoride (UF6) from bulk quantities of the material. Such samples are used for determining compliance with the applicable commercial specification, for example Specification C787 and Specification C996. 1.2 It is assumed that the bulk liquid UF6 being sampled comprises a single quality and quantity of material. This practice does not address any special additional arrangements that might be required for taking proportional or composite samples, or when the sampled bulk material is being added to UF6 residues already in a container (“heels recycle”). 1.3 The number of samples to be taken, their nominal sample weight, and their disposition shall be agreed upon between the parties. 1.4 The scope of this practice does not include provisions for preventing criticality incidents. 1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of th...

  12. Dynamics of dendritic polymers in the bulk and under confinement

    SciTech Connect (OSTI)

    Chrissopoulou, K. [Foundation for Research and Technology-Hellas, Institute of Electronic Structure and Laser, P.O. Box 1527, 711 10, Heraklion Crete (Greece); Fotiadou, S. [Foundation for Research and Technology-Hellas, Institute of Electronic Structure and Laser, P.O. Box 1527, 711 10, Heraklion Crete, Greece and Aristotle University of Thessaloniki, Department of Chemical Engineering, Thessaloniki (Greece); Androulaki, K.; Anastasiadis, S. H. [Foundation for Research and Technology-Hellas, Institute of Electronic Structure and Laser, P.O. Box 1527, 711 10, Heraklion Crete, Greece and University of Crete, Department of Chemistry, Heraklion Crete (Greece); Tanis, I.; Karatasos, K. [Aristotle University of Thessaloniki, Department of Chemical Engineering, Thessaloniki (Greece); Prevosto, D.; Labardi, M. [CNR-IPCF, Department of Physics, University of Pisa, Pisa (Italy); Frick, B. [ILL-Institut Laue-Langevin, Grenoble (France)

    2014-05-15T23:59:59.000Z

    The structure and dynamics of a hyperbranched polyesteramide (Hybrane® S 1200) polymer and its nanocomposites with natural montmorillonite (Na{sup +}-MMT) are investigated by XRD, DSC, QENS, DS and Molecular Dynamics (MD) simulation. In bulk, the energy-resolved elastically scattered intensity from the polymer exhibits two relaxation steps, one attributed to sub-T{sub g} motions and one observed at temperatures above the glass transition, T{sub g}. The QENS spectra measured over the complete temperature range are consistent with the elastic measurements and can be correlated to the results emerging from the detailed description afforded by the atomistic simulations, which predict the existence of three relaxation processes. Moreover, dielectric spectroscopy shows the sub- T{sub g} beta process as well as the segmental relaxation. For the nanocomposites, XRD reveals an intercalated structure for all hybrids with distinct interlayer distances due to polymer chains residing within the galleries of the Na{sup +}-MMT. The polymer chains confined within the galleries show similarities in the behavior with that of the polymer in the bulk for temperatures below the bulk polymer T{sub g}, whereas they exhibit frozen dynamics under confinement at temperatures higher than that.

  13. Bulk Viscosity and Cavitation in Boost-Invariant Hydrodynamic Expansion

    E-Print Network [OSTI]

    Krishna Rajagopal; Nilesh Tripuraneni

    2010-02-16T23:59:59.000Z

    We solve second order relativistic hydrodynamics equations for a boost-invariant 1+1-dimensional expanding fluid with an equation of state taken from lattice calculations of the thermodynamics of strongly coupled quark-gluon plasma. We investigate the dependence of the energy density as a function of proper time on the values of the shear viscosity, the bulk viscosity, and second order coefficients, confirming that large changes in the values of the latter have negligible effects. Varying the shear viscosity between zero and a few times s/(4 pi), with s the entropy density, has significant effects, as expected based on other studies. Introducing a nonzero bulk viscosity also has significant effects. In fact, if the bulk viscosity peaks near the crossover temperature Tc to the degree indicated by recent lattice calculations in QCD without quarks, it can make the fluid cavitate -- falling apart into droplets. It is interesting to see a hydrodynamic calculation predicting its own breakdown, via cavitation, at the temperatures where hadronization is thought to occur in ultrarelativistic heavy ion collisions.

  14. Electrometallurgical treatment demonstration at ANL-West

    SciTech Connect (OSTI)

    Goff, K. M.; Benedict, R. W.; Johnson, S. G.; Mariani, R. D.; Simpson, M. F.; Westphal, B. R.

    2000-03-20T23:59:59.000Z

    Electrometallurgical treatment (EMT) was developed by Argonne National Laboratory (ANL) to ready sodium-bonded spent nuclear fuel for geological disposal. A demonstration of this technology was successfully completed in August 1999. EMT was used to condition irradiated EBR-II driver and blanket fuel at ANL-West. The results of this demonstration, including the production of radioactive high-level waste forms, are presented.

  15. Local and bulk 13C hyperpolarization in NV-centered diamonds at variable fields and orientations

    E-Print Network [OSTI]

    Alvarez, Gonzalo A; Fischer, Ran; London, Paz; Kanda, Hisao; Onoda, Shinobu; Isoya, Junichi; Gershoni, David; Frydman, Lucio

    2014-01-01T23:59:59.000Z

    Polarizing nuclear spins is of fundamental importance in biology, chemistry and physics. Methods for hyperpolarizing 13C nuclei from free electrons in bulk, usually demand operation at cryogenic temperatures. Room-temperature approaches targeting diamonds with nitrogen-vacancy (NV) centers could alleviate this need, but hitherto proposed strategies lack generality as they demand stringent conditions on the strength and/or alignment of the magnetic field. We report here an approach for achieving efficient electron->13C spin alignment transfers, compatible with a broad range of magnetic field strengths and field orientations with respect to the diamond crystal. This versatility results from combining coherent microwave- and incoherent laser-induced transitions between selected energy states of the coupled electron-nuclear spin manifold. 13C-detected Nuclear Magnetic Resonance (NMR) experiments demonstrate that this hyperpolarization can be transferred via first-shell or via distant 13Cs, throughout the nuclear ...

  16. Guidance manual for conducting technology demonstration activities

    SciTech Connect (OSTI)

    Jolley, R.L.; Morris, M.I.; Singh, S.P.N.

    1991-12-01T23:59:59.000Z

    This demonstration guidance manual has been prepared to assist Martin Marietta Energy Systems, Inc. (Energy Systems), staff in conducting demonstrations. It is prepared in checklist style to facilitate its use and assumes that Energy Systems personnel have project management responsibility. In addition to a detailed step-by-step listing of procedural considerations, a general checklist, logic flow diagram, and several examples of necessary plans are included to assist the user in developing an understanding of the many complex activities required to manage technology demonstrations. Demonstrations are pilot-scale applications of often innovative technologies to determine the commercial viability of the technologies to perform their designed function. Demonstrations are generally conducted on well-defined problems for which existing technologies or processes are less than satisfactory in terms of effectiveness, cost, and/or regulatory compliance. Critically important issues in demonstration management include, but are not limited to, such factors as communications with line and matrix management and with the US Department of Energy (DOE) and Energy Systems staff responsible for management oversight, budgetary and schedule requirements, regulatory compliance, and safety.

  17. What is the Federal Demonstration Project

    SciTech Connect (OSTI)

    Not Available

    1990-01-01T23:59:59.000Z

    The Federal Demonstration Project is a cooperative effort between a number of universities, a private research institute, and several federal agencies to increase research productivity by eliminating unnecessary administrative procedures and by streamlining and standardizing needed controls. The Project aims to locate responsibility for decision-making as close as possible to principal investigators while maintaining necessary institutional and agency oversight to ensure accountability. By freeing researchers from some of their paperwork burden, more efficient research administration systems will enable investigators to spend more of their time doing science and engineering. The Federal Demonstration Project is an outgrowth of an earlier activity sponsored by five major federal R D agencies at the Florida State University System and the University of Miami. In Florida, the focus was on standardizing and streamlining procedures for administering research grants after the grants had been awarded to the universities. (See Attachment 1 for descriptions of the demonstrations carried out under the Florida Demonstration Project). In May 1988, the most successful of the demonstrated procedures were approved by the US Office of Management and Budget for use in grants awarded by any federal agency to any research organization. The new procedures give agencies authority to waive requirements that grantees obtain federal approval prior to taking a number of administrative actions with respect to grant management. The FDP institutions together with the participating federal agencies are designing and demonstrating innovative research administration procedures and are assessing the impact of those new procedures.

  18. Thermodynamic Relationships for Bulk Crystalline and Liquid Phases in the Phase-Field Crystal Model

    E-Print Network [OSTI]

    Victor W. L. Chan; Nirand Pisutha-Arnond; Katsuyo Thornton

    2015-02-06T23:59:59.000Z

    We present thermodynamic relationships between the free energy of the phase-field crystal (PFC) model and thermodynamic state variables for bulk phases under hydrostatic pressure. This relationship is derived based on the thermodynamic formalism for crystalline solids of Larch\\'e and Cahn [Larch\\'e and Cahn, Acta Metallurgica, Vol. 21, 1051 (1973)]. We apply the relationship to examine the thermodynamic processes associated with varying the input parameters of the PFC model: temperature, lattice spacing, and the average value of the PFC order parameter, $\\bar{n}$. The equilibrium conditions between bulk crystalline solid and liquid phases are imposed on the thermodynamic relationships for the PFC model to obtain a procedure for determining solid-liquid phase coexistence. The resulting procedure is found to be in agreement with the method commonly used in the PFC community, justifying the use of the common-tangent construction to determine solid-liquid phase coexistence in the PFC model. Finally, we apply the procedure to an eighth-order-fit (EOF) PFC model that has been parameterized to body-centered-cubic ($bcc$) Fe [Jaatinen et al., Physical Review E 80, 031602 (2009)] to demonstrate the procedure as well as to develop physical intuition about the PFC input parameters. We demonstrate that the EOF-PFC model parameterization does not predict stable $bcc$ structures with positive vacancy densities. This result suggests an alternative parameterization of the PFC model, which requires the primary peak position of the two-body direct correlation function to shift as a function of $\\bar{n}$.

  19. Effects of bulk charged impurities on the bulk and surface transport in three-dimensional topological insulators

    SciTech Connect (OSTI)

    Skinner, B.; Chen, T.; Shklovskii, B. I., E-mail: shklovsk@physics.spa.umn.edu [University of Minnesota, Fine Theoretical Physics Institute (United States)

    2013-09-15T23:59:59.000Z

    In the three-dimensional topological insulator (TI), the physics of doped semiconductors exists literally side-by-side with the physics of ultrarelativistic Dirac fermions. This unusual pairing creates a novel playground for studying the interplay between disorder and electronic transport. In this mini-review, we focus on the disorder caused by the three-dimensionally distributed charged impurities that are ubiquitous in TIs, and we outline the effects it has on both the bulk and surface transport in TIs. We present self-consistent theories for Coulomb screening both in the bulk and at the surface, discuss the magnitude of the disorder potential in each case, and present results for the conductivity. In the bulk, where the band gap leads to thermally activated transport, we show how disorder leads to a smaller-than-expected activation energy that gives way to variable-range hopping at low temperatures. We confirm this enhanced conductivity with numerical simulations that also allow us to explore different degrees of impurity compensation. For the surface, where the TI has gapless Dirac modes, we present a theory of disorder and screening of deep impurities, and we calculate the corresponding zero-temperature conductivity. We also comment on the growth of the disorder potential in passing from the surface of the TI into the bulk. Finally, we discuss how the presence of a gap at the Dirac point, introduced by some source of time-reversal symmetry breaking, affects the disorder potential at the surface and the mid-gap density of states.

  20. Buried Waste Integrated Demonstration Plan. Revision 1

    SciTech Connect (OSTI)

    Kostelnik, K.M.

    1991-12-01T23:59:59.000Z

    This document presents the plan of activities for the Buried Waste Integrated Demonstration (BWID) program which supports the environmental restoration (ER) objectives of the Department of Energy (DOE) Complex. Discussed in this plan are the objectives, organization, roles and responsibilities, and the process for implementing and managing BWID. BWID is hosted at the Idaho National Engineering Laboratory (INEL), but involves participants from throughout the DOE Complex, private industry, universities, and the international community. These participants will support, demonstrate, and evaluate a suite of advanced technologies representing a comprehensive remediation system for the effective and efficient remediation of buried waste. The processes for identifying technological needs, screening candidate technologies for applicability and maturity, selecting appropriate technologies for demonstration, field demonstrating, evaluation of results and transferring technologies to environmental restoration programs are also presented. This document further describes the elements of project planning and control that apply to BWID. It addresses the management processes, operating procedures, programmatic and technical objectives, and schedules. Key functions in support of each demonstration such as regulatory coordination, safety analyses, risk evaluations, facility requirements, and data management are presented.

  1. Decision support software technology demonstration plan

    SciTech Connect (OSTI)

    SULLIVAN,T.; ARMSTRONG,A.

    1998-09-01T23:59:59.000Z

    The performance evaluation of innovative and alternative environmental technologies is an integral part of the US Environmental Protection Agency's (EPA) mission. Early efforts focused on evaluating technologies that supported the implementation of the Clean Air and Clean Water Acts. In 1986 the Agency began to demonstrate and evaluate the cost and performance of remediation and monitoring technologies under the Superfund Innovative Technology Evaluation (SITE) program (in response to the mandate in the Superfund Amendments and Reauthorization Act of 1986 (SARA)). In 1990, the US Technology Policy was announced. This policy placed a renewed emphasis on making the best use of technology in achieving the national goals of improved quality of life for all Americans, continued economic growth, and national security. In the spirit of the technology policy, the Agency began to direct a portion of its resources toward the promotion, recognition, acceptance, and use of US-developed innovative environmental technologies both domestically and abroad. Decision Support Software (DSS) packages integrate environmental data and simulation models into a framework for making site characterization, monitoring, and cleanup decisions. To limit the scope which will be addressed in this demonstration, three endpoints have been selected for evaluation: Visualization; Sample Optimization; and Cost/Benefit Analysis. Five topics are covered in this report: the objectives of the demonstration; the elements of the demonstration plan; an overview of the Site Characterization and Monitoring Technology Pilot; an overview of the technology verification process; and the purpose of this demonstration plan.

  2. SLUDGE WASHING AND DEMONSTRATION OF THE DWPF FLOWSHEET IN THE SRNL SHIELDED CELLS FOR SLUDGE BATCH 7A QUALIFICATION

    SciTech Connect (OSTI)

    Pareizs, J.; Billings, A.; Click, D.

    2011-07-08T23:59:59.000Z

    Waste Solidification Engineering (WSE) has requested that characterization and a radioactive demonstration of the next batch of sludge slurry (Sludge Batch 7a*) be completed in the Shielded Cells Facility of the Savannah River National Laboratory (SRNL) via a Technical Task Request (TTR). This characterization and demonstration, or sludge batch qualification process, is required prior to transfer of the sludge from Tank 51 to the Defense Waste Processing Facility (DWPF) feed tank (Tank 40). The current WSE practice is to prepare sludge batches in Tank 51 by transferring sludge from other tanks. Discharges of nuclear materials from H Canyon are often added to Tank 51 during sludge batch preparation. The sludge is washed and transferred to Tank 40, the current DWPF feed tank. Prior to transfer of Tank 51 to Tank 40, SRNL simulates the Tank Farm and DWPF processes with a Tank 51 sample (referred to as the qualification sample). Sludge Batch 7a (SB7a) is composed of portions of Tanks 4, 7, and 12; the Sludge Batch 6 heel in Tank 51; and a plutonium stream from H Canyon. SRNL received the Tank 51 qualification sample (sample ID HTF-51-10-125) following sludge additions to Tank 51. This report documents: (1) The washing (addition of water to dilute the sludge supernate) and concentration (decanting of supernate) of the SB7a - Tank 51 qualification sample to adjust sodium content and weight percent insoluble solids to Tank Farm projections. (2) The performance of a DWPF Chemical Process Cell (CPC) simulation using the washed Tank 51 sample. The simulation included a Sludge Receipt and Adjustment Tank (SRAT) cycle, where acid was added to the sludge to destroy nitrite and reduce mercury, and a Slurry Mix Evaporator (SME) cycle, where glass frit was added to the sludge in preparation for vitrification. The SME cycle also included replication of five canister decontamination additions and concentrations. Processing parameters were based on work with a non-radioactive simulant. (3) Vitrification of a portion of the SME product and characterization and durability testing (as measured by the Product Consistency Test (PCT)) of the resulting glass. (4) Rheology measurements of the initial slurry samples and samples after each phase of CPC processing. This program was controlled by a Task Technical and Quality Assurance Plan (TTQAP), and analyses were guided by an Analytical Study Plan. This work is Technical Baseline Research and Development (R&D) for the DWPF. It should be noted that much of the data in this document has been published in interoffice memoranda. The intent of this technical report is bring all of the SB7a related data together in a single permanent record and to discuss the overall aspects of SB7a processing.

  3. Notes 10. A thermohydrodynamic bulk-flow model for fluid film bearings 

    E-Print Network [OSTI]

    San Andres, Luis

    2009-01-01T23:59:59.000Z

    The complete set of bulk-flow equations for the analysis of turbulent flow fluid film bearings. Importance of thermal effects in process fluid applications. A CFD method for solution of the bulk-flow equations....

  4. Characterization of Surface and Bulk Nitrates of ?-Al2O3...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Surface and Bulk Nitrates of ?-Al2O3-Supported Alkaline Earth Oxides using Density Functional Theory. Characterization of Surface and Bulk Nitrates of ?-Al2O3-Supported...

  5. Analysis and forecast of the capesize bulk carriers shipping market using Artificial Neural Networks

    E-Print Network [OSTI]

    Voudris, Athanasios V

    2006-01-01T23:59:59.000Z

    Investing in the bulk carrier market constitutes a rather risky investment due to the volatility of the bulk carrier freight rates. In this study it is attempted to uncover the benefits of using Artificial Neural Networks ...

  6. Final report for the cryogenic retrieval demonstration

    SciTech Connect (OSTI)

    Valentich, D.J.; Yokuda, E.L.

    1992-09-01T23:59:59.000Z

    This report documents a demonstration of a proposed buried transuranic waste retrieval concept that uses cryogenic ground freezing and remote excavation. At the Idaho National Engineering Laboratory (INEL), there are over 8 million ft{sup 3} of intermingled soil and transuranic (TRU) wastes in shallow land burial, and retrieval of the material is one of the options being considered by the Buried Waste Integrated Demonstration for the Environmental Restoration program. Cryogenically freezing contaminated soil and buried waste has been proposed as a way to greatly reduce or eliminate the climate the threat of contamination spread during retrieval activities. In support of this idea, a demonstration of an innovative ground freezing and retrieval technology was performed at the INEL. This initial demonstration was held near the Radioactive Waste Management Complex at a ``cold test pit`` that was built in 1988 as a test bed for the demonstration of retrieval contamination control technologies. This pit is not contaminated with any radioactive or hazardous wastes. Barrels and boxes filled with metals, plastics, tools, paper, cloth, etc. configured in the same manner as expected in contaminated pits and trenches are buried at the cold test pit. After design, fabrication, and shop testing, Sonsub mobilized to the field in early July 1992 to perform the field demonstration. It was planned to freeze and extract four pits, each 9 {times} 9 {times} 10 ft. Each pit represented a different configuration of buried waste (stacked boxes, stacked barrels, random dumped barrels and boxes, and random dumped barrels). Sonsub`s proposed technology consisted of driving a series of freeze pipes into the soil and waste, using liquid nitrogen to freeze the mass, and extracting the soil and debris using a series of remote operated, bridge crane mounted tools. In conjunction with the freezing and removal activities, temperature and moisture measurements, and air monitoring were performed.

  7. Final report for the cryogenic retrieval demonstration

    SciTech Connect (OSTI)

    Valentich, D.J.; Yokuda, E.L.

    1992-09-01T23:59:59.000Z

    This report documents a demonstration of a proposed buried transuranic waste retrieval concept that uses cryogenic ground freezing and remote excavation. At the Idaho National Engineering Laboratory (INEL), there are over 8 million ft[sup 3] of intermingled soil and transuranic (TRU) wastes in shallow land burial, and retrieval of the material is one of the options being considered by the Buried Waste Integrated Demonstration for the Environmental Restoration program. Cryogenically freezing contaminated soil and buried waste has been proposed as a way to greatly reduce or eliminate the climate the threat of contamination spread during retrieval activities. In support of this idea, a demonstration of an innovative ground freezing and retrieval technology was performed at the INEL. This initial demonstration was held near the Radioactive Waste Management Complex at a cold test pit'' that was built in 1988 as a test bed for the demonstration of retrieval contamination control technologies. This pit is not contaminated with any radioactive or hazardous wastes. Barrels and boxes filled with metals, plastics, tools, paper, cloth, etc. configured in the same manner as expected in contaminated pits and trenches are buried at the cold test pit. After design, fabrication, and shop testing, Sonsub mobilized to the field in early July 1992 to perform the field demonstration. It was planned to freeze and extract four pits, each 9 [times] 9 [times] 10 ft. Each pit represented a different configuration of buried waste (stacked boxes, stacked barrels, random dumped barrels and boxes, and random dumped barrels). Sonsub's proposed technology consisted of driving a series of freeze pipes into the soil and waste, using liquid nitrogen to freeze the mass, and extracting the soil and debris using a series of remote operated, bridge crane mounted tools. In conjunction with the freezing and removal activities, temperature and moisture measurements, and air monitoring were performed.

  8. Experimental demonstration of superdirective dielectric antenna

    SciTech Connect (OSTI)

    Krasnok, Alexander E.; Filonov, Dmitry S.; Belov, Pavel A. [National Research University of Information Technologies, Mechanics and Optics (ITMO), St. Petersburg 197101 (Russian Federation); Simovski, Constantin R. [National Research University of Information Technologies, Mechanics and Optics (ITMO), St. Petersburg 197101 (Russian Federation); Aalto University, School of Electric and Electronic Engineering, Aalto FI76000 (Finland); Kivshar, Yuri S. [National Research University of Information Technologies, Mechanics and Optics (ITMO), St. Petersburg 197101 (Russian Federation); Nonlinear Physics Center, Research School of Physics and Engineering, Australian National University, Canberra ACT 0200 (Australia)

    2014-03-31T23:59:59.000Z

    We propose and demonstrate experimentally a simple approach for achieving superdirectivity of emitted radiation for electrically small antennas based on a spherical dielectric resonator with a notch excited by a dipole source. Superdirectivity is achieved without using complex antenna arrays and for a wide range of frequencies. We also demonstrate the steering effect for a subwavelength displacement of the source. Finally, unlike previously known superdirective antennas, our design has significantly smaller losses, at the operation frequency radiation efficiency attains 80%, and matching holds in the 3%-wide frequency band without any special matching technique.

  9. Development and Demonstration of Ultrafiltration Simulants

    SciTech Connect (OSTI)

    Russell, Renee L.; Billing, Justin M.; Peterson, Reid A.; Rinehart, Donald E.; Smith, Harry D.

    2009-02-24T23:59:59.000Z

    According to Bechtel National, Inc. (BNI) Test Specification 24590-PTF-TSP-RT-06-006, Rev 0, Simulant Development to Support the Development and Demonstration of Leaching and Ultrafiltration Pretreatment Processes,” simulants for boehmite, gibbsite, and filtration are to be developed that can be used in subsequent bench and integrated testing of the leaching/filtration processes for the waste treatment plant (WTP). These simulants will then be used to demonstrate the leaching process and to help refine processing conditions which may impact safety basis considerations (Smith 2006). This report documents the results of the filtration simulant development.

  10. Learning Demonstration Interim Progress Report -- July 2010

    SciTech Connect (OSTI)

    Wipke, K.; Spirk, S.; Kurtz, J.; Ramsden, T.

    2010-09-01T23:59:59.000Z

    This report discusses key results based on data through December 2009 from the U.S. Department of Energy's (DOE) Controlled Hydrogen Fleet and Infrastructure Validation and Demonstration Project, also referred to as the National Fuel Cell Electric Vehicle (FCEV) Learning Demonstration. The report serves to help transfer knowledge and lessons learned within various parts of DOE's hydrogen program, as well as externally to other stakeholders. It is the fourth such report in a series, with previous reports being published in July 2007, November 2007, and April 2008.

  11. JEA successfully completes world's largest CFB demonstration

    SciTech Connect (OSTI)

    NONE

    2005-09-30T23:59:59.000Z

    JEA (formerly the Jacksonville Electric Authority) has successfully completed an eighth year landmark demonstration project that continues in baseload commercial operation. It scales up atmospheric fluidized-bed technology demonstration to the near-300-MW size, providing important data on a technology that can achieve > 90% SO{sub 2} removal and 60% NOx reduction at relatively high efficiencies and at costs comparable to those of conventional pulverized coal plants. The article recounts the history of the project. Performance tests showed a blend of coal and petcoke were most efficient as a feedstock. 3 figs.

  12. Result Demonstration: A Method That Works

    E-Print Network [OSTI]

    Boleman, Chris; Dromgoole, Darrell A.

    2007-05-24T23:59:59.000Z

    E-449 05-07 ?A producer doing a result demonstration on his or her personal property is the ultimate in education: Hands-on and remembered! Don?t stop and file it. You?ve educated one, now educate the masses! Let the world know about it. Put.... County Extension educators in San Patri- cio County, in cooperation with the local Field Crops Committee, implemented several in-depth demonstration/applied research and educa- tional programs to help the local producers more effectively manage...

  13. Notes 10. A thermohydrodynamic bulk-flow model for fluid film bearings

    E-Print Network [OSTI]

    San Andres, Luis

    2009-01-01T23:59:59.000Z

    Notes 10. THERMOHYDRODYNAMIC BULK-FLOW MODEL IN THIN FILM LUBRICATION ? Dr. Luis San Andr?s (2009) 1 Notes 10. Thermohydrodynamic Bulk-Flow Model in Thin Film Lubrication General flow characteristics in oil lubricated fluid film... regimes Notes 10. THERMOHYDRODYNAMIC BULK-FLOW MODEL IN THIN FILM LUBRICATION ? Dr. Luis San Andr?s (2009) 2 Bulk-Flow Equations for Thin Fluid Films The fluid flow within a thin film region, see Fig.1, is governed by the continuity...

  14. Generalized Test Plan for the Vitrification of Simulated High-Level -Waste Calcine in the Idaho National Laboratory‘s Bench -Scale Cold Crucible Induction Melter

    SciTech Connect (OSTI)

    Vince Maio

    2011-08-01T23:59:59.000Z

    This Preliminary Idaho National Laboratory (INL) Test Plan outlines the chronological steps required to initially evaluate the validity of vitrifying INL surrogate (cold) High-Level-Waste (HLW) solid particulate calcine in INL's Cold Crucible Induction Melter (CCIM). Its documentation and publication satisfies interim milestone WP-413-INL-01 of the DOE-EM (via the Office of River Protection) sponsored work package, WP 4.1.3, entitled 'Improved Vitrification' The primary goal of the proposed CCIM testing is to initiate efforts to identify an efficient and effective back-up and risk adverse technology for treating the actual HLW calcine stored at the INL. The calcine's treatment must be completed by 2035 as dictated by a State of Idaho Consent Order. A final report on this surrogate/calcine test in the CCIM will be issued in May 2012-pending next fiscal year funding In particular the plan provides; (1) distinct test objectives, (2) a description of the purpose and scope of planned university contracted pre-screening tests required to optimize the CCIM glass/surrogate calcine formulation, (3) a listing of necessary CCIM equipment modifications and corresponding work control document changes necessary to feed a solid particulate to the CCIM, (4) a description of the class of calcine that will be represented by the surrogate, and (5) a tentative tabulation of the anticipated CCIM testing conditions, testing parameters, sampling requirements and analytical tests. Key FY -11 milestones associated with this CCIM testing effort are also provided. The CCIM test run is scheduled to be conducted in February of 2012 and will involve testing with a surrogate HLW calcine representative of only 13% of the 4,000 m3 of 'hot' calcine residing in 6 INL Bin Sets. The remaining classes of calcine will have to be eventually tested in the CCIM if an operational scale CCIM is to be a feasible option for the actual INL HLW calcine. This remaining calcine's make-up is HLW containing relatively high concentrations of zirconium and aluminum, representative of the cladding material of the reprocessed fuel that generated the calcine. A separate study to define the CCIM testing needs of these other calcine classifications in currently being prepared under a separate work package (WP-0) and will be provided as a milestone report at the end of this fiscal year.

  15. High temperature magnetic properties of SmCo5/-Fe(Co) bulk nanocomposite magnets

    E-Print Network [OSTI]

    Liu, J. Ping

    High temperature magnetic properties of SmCo5/-Fe(Co) bulk nanocomposite magnets Chuanbing Rong://apl.aip.org/about/rights_and_permissions #12;High temperature magnetic properties of SmCo5/a-Fe(Co) bulk nanocomposite magnets Chuanbing Rong,1 containing no heavy rare earths for power applications, SmCo5/Fe bulk nanocomposite magnets with enhanced

  16. Corrosion of, and cellular responses to MgZnCa bulk metallic glasses Xuenan Gu a

    E-Print Network [OSTI]

    Zheng, Yufeng

    Corrosion of, and cellular responses to Mg­Zn­Ca bulk metallic glasses Xuenan Gu a , Yufeng Zheng a: Magnesium alloy Bulk metallic glass Mechanical property Corrosion Cytotoxicity a b s t r a c t Mg­Zn­Ca bulk, mechanical testing, corrosion and cytotoxicity tests. It was found that the Mg66Zn30Ca4 sample presents

  17. Bulk viscosity of superfluid hyperon stars Mikhail E. Gusakov and Elena M. Kantor

    E-Print Network [OSTI]

    Bulk viscosity of superfluid hyperon stars Mikhail E. Gusakov and Elena M. Kantor Ioffe Physical; published 14 October 2008) We calculate the bulk viscosity due to nonequilibrium weak processes bulk viscosity coefficients, with only three of them being independent. In addition, we correct

  18. SINGLE-MASK, HIGH ASPECT RATIO, 3-D MICROMACHINING OF BULK TITANIUM , M. F. Aimi2

    E-Print Network [OSTI]

    MacDonald, Noel C.

    SINGLE-MASK, HIGH ASPECT RATIO, 3-D MICROMACHINING OF BULK TITANIUM M. P. Rao1 , M. F. Aimi2 , E. R profiles in bulk titanium. The method relies on the exploitation of Reactive Ion Etching Lag (RIE Lag for application in bulk micromachined titanium micromirror devices. 1. INTRODUCTION The recent development

  19. RADIOACTIVE DEMONSTRATION OF FINAL MINERALIZED WASTE FORMS FOR HANFORD WASTE TREATMENT PLANT SECONDARY WASTE BY FLUIDIZED BED STEAM REFORMING USING THE BENCH SCALE REFORMER PLATFORM

    SciTech Connect (OSTI)

    Crawford, C.; Burket, P.; Cozzi, A.; Daniel, W.; Jantzen, C.; Missimer, D.

    2012-02-02T23:59:59.000Z

    The U.S. Department of Energy's Office of River Protection (ORP) is responsible for the retrieval, treatment, immobilization, and disposal of Hanford's tank waste. Currently there are approximately 56 million gallons of highly radioactive mixed wastes awaiting treatment. A key aspect of the River Protection Project (RPP) cleanup mission is to construct and operate the Waste Treatment and Immobilization Plant (WTP). The WTP will separate the tank waste into high-level and low-activity waste (LAW) fractions, both of which will subsequently be vitrified. The projected throughput capacity of the WTP LAW Vitrification Facility is insufficient to complete the RPP mission in the time frame required by the Hanford Federal Facility Agreement and Consent Order, also known as the Tri-Party Agreement (TPA), i.e. December 31, 2047. Therefore, Supplemental Treatment is required both to meet the TPA treatment requirements as well as to more cost effectively complete the tank waste treatment mission. In addition, the WTP LAW vitrification facility off-gas condensate known as WTP Secondary Waste (WTP-SW) will be generated and enriched in volatile components such as {sup 137}Cs, {sup 129}I, {sup 99}Tc, Cl, F, and SO{sub 4} that volatilize at the vitrification temperature of 1150 C in the absence of a continuous cold cap (that could minimize volatilization). The current waste disposal path for the WTP-SW is to process it through the Effluent Treatment Facility (ETF). Fluidized Bed Steam Reforming (FBSR) is being considered for immobilization of the ETF concentrate that would be generated by processing the WTP-SW. The focus of this current report is the WTP-SW. FBSR offers a moderate temperature (700-750 C) continuous method by which WTP-SW wastes can be processed irrespective of whether they contain organics, nitrates, sulfates/sulfides, chlorides, fluorides, volatile radionuclides or other aqueous components. The FBSR technology can process these wastes into a crystalline ceramic (mineral) waste form. The mineral waste form that is produced by co-processing waste with kaolin clay in an FBSR process has been shown to be as durable as LAW glass. Monolithing of the granular FBSR product is being investigated to prevent dispersion during transport or burial/storage, but is not necessary for performance. A Benchscale Steam Reformer (BSR) was designed and constructed at the SRNL to treat actual radioactive wastes to confirm the findings of the non-radioactive FBSR pilot scale tests and to qualify the waste form for applications at Hanford. BSR testing with WTP SW waste surrogates and associated analytical analyses and tests of granular products (GP) and monoliths began in the Fall of 2009, and then was continued from the Fall of 2010 through the Spring of 2011. Radioactive testing commenced in 2010 with a demonstration of Hanford's WTP-SW where Savannah River Site (SRS) High Level Waste (HLW) secondary waste from the Defense Waste Processing Facility (DWPF) was shimmed with a mixture of {sup 125/129}I and {sup 99}Tc to chemically resemble WTP-SW. Prior to these radioactive feed tests, non-radioactive simulants were also processed. Ninety six grams of radioactive granular product were made for testing and comparison to the non-radioactive pilot scale tests. The same mineral phases were found in the radioactive and non-radioactive testing.

  20. CubeSat deformable mirror demonstration

    E-Print Network [OSTI]

    Cahoy, Kerri

    The goal of the CubeSat Deformable Mirror Demonstration (DeMi) is to characterize the performance of a small deformable mirror over a year in low-Earth orbit. Small form factor deformable mirrors are a key technology needed ...

  1. CALDERON COKEMAKING PROCESS/DEMONSTRATION PROJECT

    SciTech Connect (OSTI)

    Albert Calderon

    2000-03-22T23:59:59.000Z

    This project deals with the demonstration of a coking process using proprietary technology of Calderon, with the following objectives geared to facilitate commercialization: (i) making coke of such quality as to be suitable for use in hard-driving, large blast furnaces; (ii) providing proof that such process is continuous and environmentally closed to prevent emissions; (iii) demonstrating that high-coking-pressure (non-traditional) coal blends which cannot be safely charged into conventional by-product coke ovens can be used in the Calderon process; (iv) conducting a blast furnace test to demonstrate the compatibility of the coke produced; and (v) demonstrating that coke can be produced economically, at a level competitive with coke imports. The activities of the past quarter continued to be focused on the following: Concluding the Negotiation and completing Contracts among Stakeholders of the Team; Revision of Final Report for Phase I; Engineering Design Progress; Selection of Systems Associates, Inc. for design of Control System; Conclusion of Secrecy Agreement with Carborundum (St. Gobain); and Permitting Work and Revisions.

  2. Calderon cokemaking process/demonstration project

    SciTech Connect (OSTI)

    Albert Calderon

    1999-12-21T23:59:59.000Z

    This project deals with the demonstration of a coking process using proprietary technology of Calderon, with the following objectives geared to facilitate commercialization: (1) making coke of such quality as to be suitable for use in hard-driving, large blast furnaces; (2) providing proof that such a process is continuous and environmentally closed to prevent emissions; (3) demonstrating that high-coking-pressure (non-traditional) coal blends which cannot be safely charged into conventional by-product coke ovens can be used in the Calderon process; (4) conducting a blast furnace test to demonstrate the compatibility of the coke produced; and (5) demonstrating that coke can be produced economically, at a level competitive with coke imports. The activities of the past quarter continued to be focused on the following: Drafting of Contracts among the Stakeholders of the Team, Completion and Delivery of Proposal for Phase 2 Permitting and Environmental Work Engineering Progress Preparation of Final Report for Phase 1 DCAA Audit Funding for Phase 2.

  3. CALDERON COKEMAKING PROCESS/DEMONSTRATION PROJECT

    SciTech Connect (OSTI)

    Albert Calderon

    2000-06-21T23:59:59.000Z

    This project deals with the demonstration of a coking process using proprietary technology of Calderon, with the following objectives geared to facilitate commercialization: (i) making coke of such quality as to be suitable for use in hard-driving, large blast furnaces; (ii) providing proof that such process is continuous and environmentally closed to prevent emissions; (iii) demonstrating that high-coking-pressure (non-traditional) coal blends which cannot be safely charged into conventional by-product coke ovens can be used in the Calderon process; (iv) conducting a blast furnace test to demonstrate the compatibility of the coke produced; and (v) demonstrating that coke can be produced economically, at a level competitive with coke imports. The activities of the past quarter continued to be focused on the following: Concluding the Negotiation and completing Contracts among Stakeholders of the Team; Revision of Final Report for Phase I; Engineering Design Progress; Selection of Systems Associates, Inc. for design of Control System; Conclusion of Secrecy Agreement with Carborundum (St. Gobain); and Permitting Work and Revisions.

  4. CALDERON COKEMAKING PROCESS/DEMONSTRATION PROJECT

    SciTech Connect (OSTI)

    Albert Calderon

    1999-03-19T23:59:59.000Z

    This project deals with the demonstration of a coking process using proprietary technology of Calderon, with the following objectives geared to facilitate commercialization: (1) making coke of such quality as to be suitable for use in hard-driving, large blast furnaces; (2) providing proof that such process is continuous and environmentally closed to prevent emissions; (3) demonstrating that high-coking-pressure (non-traditional) coal blends which cannot be safely charged into conventional by-product coke ovens can be used in the Calderon process; and (4) demonstrating that coke can be produced economically, at a level competitive with coke imports. The activities of the past quarter were focused on the following: Consolidation of the team of stakeholders; Move the site for the commercial demonstration to LTV Steel, Cleveland, Ohio; Permitting for new site; Site specific engineering; Cost update of the project as it relates to the Cleveland location; FETC update; DCAA audit; and Updated endorsement of Calderon process by Ohio EPA and U.S. EPA, Region 5.

  5. THE REQUIREMENTS OF A FUSION DEMONSTRATION

    E-Print Network [OSTI]

    Najmabadi, Farrokh

    and will analyze the strategies, facilities, and prior testing requirements needed to demonstrate electric power Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes constitute or imply its endorsement, recommendation, or favoring by the United States Government or any

  6. Title: Robot Arm Demonstration Supervisor: Alexander Frster

    E-Print Network [OSTI]

    Krause, Rolf

    UROP 2009 Title: Robot Arm Demonstration Supervisor: Alexander Förster Sponsor: Luca Gambardella / UROP Keywords: programming language C++, Qt-framework, Katana robot arm, computer vision Prerequisites based controlled robot arm. The computer vision system has to detect the position and orientation

  7. Encouraging Industrial Demonstrations of Fuel Cell Applications 

    E-Print Network [OSTI]

    Anderson, J. M.

    1986-01-01T23:59:59.000Z

    Fuel Cell technology has advanced from a space-age curiosity to near commercial status within the last few years. Both the electric and the gas utilities in the United States have conducted ambitious programs to demonstrate the practicality of fuel...

  8. Demonstrations: sound source for Doppler shift

    E-Print Network [OSTI]

    Boal, David

    of the Universe Doppler effect The technique for measuring the velocities of very remote galaxies is based uponDemonstrations: ·sound source for Doppler shift ·big balloon and labels Text: Mod. Phys. 8.A, 8.B, 8.C Problems: 1, 3, 6, 7 from Ch. 8 What's important: ·Doppler shift ·Hubble's law ·age

  9. Energy Harvesting Communication Networks: Optimization and Demonstration

    E-Print Network [OSTI]

    Gesbert, David

    ) and the UK (Imperial College London). Index Terms--energy harvesting; energy packet net- works; Markov models harvesting devices. EH capability can scavenge ambient energy, such as vibrations, thermal gradients or solar1 Energy Harvesting Communication Networks: Optimization and Demonstration (The E-CROPS Project

  10. Bulk effects in the coherent inelastic scattering of ultracold neutrons

    E-Print Network [OSTI]

    A. L. Barabanov; S. T. Belyaev

    2005-09-20T23:59:59.000Z

    With the use of theory developed earlier, bulk effects in ultracold neutron coherent inelastic scattering are considered both for solid and liquid target samples related to energy and momentum exchange with phonon and diffusion-like modes. For the neutron in a material trap, differential and integral probabilities for the energy transfer per bounce are presented in a simple analytic form which exhibits the parameter dependence. As an example, the theoretical values for the ultracold neutron loss rate from a storage bottle with Fomblin coated walls and stainless steel walls are evaluated. Possible contribution from incoherent inelastic scattering on hydrogen contamination is discussed.

  11. Elastic Moduli Inheritance and Weakest Link in Bulk Metallic Glasses

    SciTech Connect (OSTI)

    Stoica, Alexandru Dan [ORNL; Wang, Xun-Li [ORNL; Lu, Z.P. [University of Science and Technology, Beijing; Clausen, Bjorn [Los Alamos National Laboratory (LANL); Brown, Donald [Los Alamos National Laboratory (LANL)

    2012-01-01T23:59:59.000Z

    We show that a variety of bulk metallic glasses (BMGs) inherit their Young s modulus and shear modulus from the solvent components. This is attributed to preferential straining of locally solvent-rich configurations among tightly bonded atomic clusters, which constitute the weakest link in an amorphous structure. This aspect of inhomogeneous deformation, also revealed by our in-situ neutron diffraction studies of an elastically deformed BMG, suggests a scenario of rubber-like viscoelasticity owing to a hierarchy of atomic bonds in BMGs.

  12. Bulk viscosity in a plasma of confining gluons

    E-Print Network [OSTI]

    Wojciech Florkowski; Radoslaw Ryblewski; Nan Su; Konrad Tywoniuk

    2015-04-13T23:59:59.000Z

    We investigate dynamic properties of a plasma whose constituents are confining gluons resulting from the Gribov quantization. In a static formulation, this system reproduces qualitatively the pure-glue equation of state and thereby encodes crucial features of the phase transition. The dynamic description proposed in this work allows us to study non-equilibrium transport phenomena with the inclusion of confinement effects. In particular, we determine the non-equilibrium behaviour of the interaction measure (trace anomaly) and find the form of the bulk viscosity coefficient. The latter may be used in phenomenological applications to heavy-ion collisions.

  13. Bulk Viscosity of a Gas of Massless Pions

    E-Print Network [OSTI]

    Jiunn-Wei Chen; Juven Wang

    2009-03-31T23:59:59.000Z

    In the hadronic phase, the dominant configuration of QCD with two flavors of massless quarks is a gas of massless pions. We calculate the bulk viscosity (zeta) using the Boltzmann equation with the kinetic theory generalized to incorporate the trace anomaly. We find that the dimensionless ratio zeta/s, s being the entropy density, is monotonic increasing below T=120 MeV, where chiral perturbation theory is applicable. This, combined with previous results, shows that zeta/s reaches its maximum near the phase transition temperature Tc, while eta/s, eta being the shear viscosity, reaches its minimum near Tc in QCD with massless quarks.

  14. Bulk viscosity in a plasma of confining gluons

    E-Print Network [OSTI]

    Florkowski, Wojciech; Su, Nan; Tywoniuk, Konrad

    2015-01-01T23:59:59.000Z

    We investigate dynamic properties of a plasma whose constituents are confining gluons resulting from the Gribov quantization. In a static formulation, this system reproduces qualitatively the pure-glue equation of state and thereby encodes crucial features of the phase transition. The dynamic description proposed in this work allows us to study non-equilibrium transport phenomena with the inclusion of confinement effects. In particular, we determine the non-equilibrium behaviour of the interaction measure (trace anomaly) and find the form of the bulk viscosity coefficient. The latter may be used in phenomenological applications to heavy-ion collisions.

  15. Non-Brownian molecular self-diffusion in bulk water

    E-Print Network [OSTI]

    Janez Stepišnik; Aleš Mohori?; Igor Serša

    2010-10-06T23:59:59.000Z

    The paper presents the velocity autocorrelation spectrum of bulk water measured by a new technique of NMR modulated gradient spin echo method. This technique is unprecedented for the spectrum measurement in the frequency interval between a few Hz to about 100 kHz with respect to directness and clarity of results and shows that a simple model of Brownian self-diffusion is not applicable to describe the diffusion dynamics of water molecules. The observed temperature dependant spectra of water show the existence of a slow chain-like dynamics in water, which we explain by coupling of diffusing molecule to broken bonds in the hydrogen bond network.

  16. Tilting the Primordial Power Spectrum with Bulk Viscosity

    E-Print Network [OSTI]

    James E. Lidsey

    1993-12-16T23:59:59.000Z

    Within the context of the cold dark matter model, current observations suggest that inflationary models which generate a tilted primordial power spectrum with negligible gravitational waves provide the most promising mechanism for explaining large scale clustering. The general form of the inflationary potential which produces such a spectrum is a hyperbolic function and is interpreted physically as a bulk viscous stress contribution to the energy-momentum of a perfect baryotropic fluid. This is equivalent to expanding the equation of state as a truncated Taylor series. Particle physics models which lead to such a potential are discussed.

  17. Federal Bulk Transmission Regulatory Roadmapping | OpenEI Community

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand JumpConceptual Model,DOEHazelPennsylvania:57427°, -89.4742177° Show Map LoadingFayston,Federal Bulk

  18. Robbins Corn & Bulk Services | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to:Ezfeedflag JumpID-f < RAPID‎ |Rippey Jump to: navigation, searchRobbins Corn & Bulk

  19. Newberry Volcano EGS Demonstration - Phase I Results

    SciTech Connect (OSTI)

    William L. Osborn, Susan Petty, Trenton T. Cladouhos, Joe Iovenitti, Laura Nofziger, Owen Callahan, Douglas S. Perry and Paul L. Stern

    2011-10-23T23:59:59.000Z

    Phase I of the Newberry Volcano Enhanced Geothermal System (EGS) Demonstration included permitting, community outreach, seismic hazards analysis, initial microseismic array deployment and calibration, final MSA design, site characterization, and stimulation planning. The multi-disciplinary Phase I site characterization supports stimulation planning and regulatory permitting, as well as addressing public concerns including water usage and induced seismicity. A review of the project'Ã?Â?Ã?Â?s water usage plan by an independent hydrology consultant found no expected impacts to local stakeholders, and recommended additional monitoring procedures. The IEA Protocol for Induced Seismicity Associated with Enhanced Geothermal Systems was applied to assess site conditions, properly inform stakeholders, and develop a comprehensive mitigation plan. Analysis of precision LiDAR elevation maps has concluded that there is no evidence of recent faulting near the target well. A borehole televiewer image log of the well bore revealed over three hundred fractures and predicted stress orientations. No natural, background seismicity has been identified in a review of historic data, or in more than seven months of seismic data recorded on an array of seven seismometers operating around the target well. A seismic hazards and induced seismicity risk assessment by an independent consultant concluded that the Demonstration would contribute no additional risk to residents of the nearest town of La Pine, Oregon. In Phase II of the demonstration, an existing deep hot well, NWG 55-29, will be stimulated using hydroshearing techniques to create an EGS reservoir. The Newberry Volcano EGS Demonstration is allowing geothermal industry and academic experts to develop, validate and enhance geoscience and engineering techniques, and other procedures essential to the expansion of EGS throughout the country. Successful development will demonstrate to the American public that EGS can play a significant role in reducing foreign energy dependence, and provide clean, renewable, baseload geothermal power generation in the State of Oregon.

  20. DOE`s annealing prototype demonstration projects

    SciTech Connect (OSTI)

    Warren, J.; Nakos, J.; Rochau, G.

    1997-02-01T23:59:59.000Z

    One of the challenges U.S. utilities face in addressing technical issues associated with the aging of nuclear power plants is the long-term effect of plant operation on reactor pressure vessels (RPVs). As a nuclear plant operates, its RPV is exposed to neutrons. For certain plants, this neutron exposure can cause embrittlement of some of the RPV welds which can shorten the useful life of the RPV. This RPV embrittlement issue has the potential to affect the continued operation of a number of operating U.S. pressurized water reactor (PWR) plants. However, RPV material properties affected by long-term irradiation are recoverable through a thermal annealing treatment of the RPV. Although a dozen Russian-designed RPVs and several U.S. military vessels have been successfully annealed, U.S. utilities have stated that a successful annealing demonstration of a U.S. RPV is a prerequisite for annealing a licensed U.S. nuclear power plant. In May 1995, the Department of Energy`s Sandia National Laboratories awarded two cost-shared contracts to evaluate the feasibility of annealing U.S. licensed plants by conducting an anneal of an installed RPV using two different heating technologies. The contracts were awarded to the American Society of Mechanical Engineers (ASME) Center for Research and Technology Development (CRTD) and MPR Associates (MPR). The ASME team completed its annealing prototype demonstration in July 1996, using an indirect gas furnace at the uncompleted Public Service of Indiana`s Marble Hill nuclear power plant. The MPR team`s annealing prototype demonstration was scheduled to be completed in early 1997, using a direct heat electrical furnace at the uncompleted Consumers Power Company`s nuclear power plant at Midland, Michigan. This paper describes the Department`s annealing prototype demonstration goals and objectives; the tasks, deliverables, and results to date for each annealing prototype demonstration; and the remaining annealing technology challenges.

  1. The detection of bulk explosives using nuclear-based techniques

    SciTech Connect (OSTI)

    Morgado, R.E.; Gozani, T.; Seher, C.C.

    1988-01-01T23:59:59.000Z

    In 1986 we presented a rationale for the detection of bulk explosives based on nuclear techniques that addressed the requirements of civil aviation security in the airport environment. Since then, efforts have intensified to implement a system based on thermal neutron activation (TNA), with new work developing in fast neutron and energetic photon reactions. In this paper we will describe these techniques and present new results from laboratory and airport testing. Based on preliminary results, we contended in our earlier paper that nuclear-based techniques did provide sufficiently penetrating probes and distinguishable detectable reaction products to achieve the FAA operational goals; new data have supported this contention. The status of nuclear-based techniques for the detection of bulk explosives presently under investigation by the US Federal Aviation Administration (FAA) is reviewed. These include thermal neutron activation (TNA), fast neutron activation (FNA), the associated particle technique, nuclear resonance absorption, and photoneutron activation. The results of comprehensive airport testing of the TNA system performed during 1987-88 are summarized. From a technical point of view, nuclear-based techniques now represent the most comprehensive and feasible approach for meeting the operational criteria of detection, false alarms, and throughput. 9 refs., 5 figs., 2 tabs.

  2. Hydrogen fueling station development and demonstration

    SciTech Connect (OSTI)

    Edeskuty, F.J.; Daney, D.; Daugherty, M.; Hill, D.; Prenger, F.C.

    1996-09-01T23:59:59.000Z

    This is the final report of a one-year, Laboratory-Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL). This project sought to develop and demonstrate a hydrogen fueling station for vehicles. Such stations are an essential infrastructural element in the practical application of hydrogen as vehicle fuel, and a number of issues such as safety, efficiency, design, and operating procedures can only be accurately addressed by a practical demonstration. Regardless of whether the vehicle is powered by an internal combustion engine or fuel cell, or whether the vehicle has a liquid or gaseous fuel tank, the fueling station is a critical technology that is the link between the local storage facility and the vehicle.

  3. Nucla circulating atmospheric fluidized bed demonstration project

    SciTech Connect (OSTI)

    Keith, Raymond E.

    1991-10-01T23:59:59.000Z

    Colorado-Ute Electric Association began a study to evaluate options for upgrading and extending the life of its Nucla power station in 1982. Located in southwestern Colorado near the town of Nucla, this station was commissioned in 1959 with a local bituminous coal as its design fuel for three identical stoker-fired units, each rated at 12.6 MW(e). Poor station efficiency, high fuel costs, and spiraling boiler maintenance costs forced the Nucla Station into low priority in the CUEA dispatch order as early as 1981. Among the options CUEA considered was to serve as a host utility to demonstrate Atmospheric Fluidized Bed Combustion (AFBC) technology. The anticipated environmental benefits and apparent attractive economics of a circulating AFBC led to Colorado-Ute's decision to proceed with the design and construction of a demonstration project in 1984 at the Nucla facility.

  4. Implementation of the buried waste integrated demonstration

    SciTech Connect (OSTI)

    Kostelnik, K.M.; Merrill, S.K.

    1992-09-01T23:59:59.000Z

    The Department of Energy (DOE), Office of Technology Development (OTD) has initiated the Buried Waste Integrated Demonstration (BWID) to resolve technological deficiencies associated with the remediation of radioactive and hazardous buried waste. The BWID mission is to identify, demonstrate, and transfer innovative technologies for the remediation of DOE buried waste. To accomplish the mission, BWID is using a systems approach which supports the development of a suite of advanced and innovative technologies for the effective and efficient remediation of buried waste. This systems approach includes technologies for theentire remediation cycle. Specifically, BWID sponsors technology development in the following technology categories: site and waste characterization, retrieval, preprocessing, ex situ treatment, packaging, transportation, storage, disposal, and post-disposal monitoring.

  5. Implementation of the buried waste integrated demonstration

    SciTech Connect (OSTI)

    Kostelnik, K.M.; Merrill, S.K.

    1992-01-01T23:59:59.000Z

    The Department of Energy (DOE), Office of Technology Development (OTD) has initiated the Buried Waste Integrated Demonstration (BWID) to resolve technological deficiencies associated with the remediation of radioactive and hazardous buried waste. The BWID mission is to identify, demonstrate, and transfer innovative technologies for the remediation of DOE buried waste. To accomplish the mission, BWID is using a systems approach which supports the development of a suite of advanced and innovative technologies for the effective and efficient remediation of buried waste. This systems approach includes technologies for theentire remediation cycle. Specifically, BWID sponsors technology development in the following technology categories: site and waste characterization, retrieval, preprocessing, ex situ treatment, packaging, transportation, storage, disposal, and post-disposal monitoring.

  6. Los Alamos Team Demonstrates Bottle Scanner Technology

    ScienceCinema (OSTI)

    Espy, Michelle; Schultz, Larry

    2014-06-02T23:59:59.000Z

    Los Alamos scientists are demonstrating a Nuclear Magnetic Resonance Imaging (NMR) technology that may provide a breakthrough for screening liquids at airport security. By adding low-power X-ray data to the NMR mix, scientists believe they have unlocked a new detection technology. Funded in part by the Department of Homeland Security's Science and Technology Directorate, the new technology is called MagRay.

  7. NUCLA Circulating Atmospheric Fluidized Bed Demonstration Project

    SciTech Connect (OSTI)

    Not Available

    1992-02-01T23:59:59.000Z

    The objective of this DOE Cooperative Agreement is to conduct a cost-shared clean coal technology project to demonstrate the feasibility of circulating fluidized bed combustion technology and to evaluate economic, environmental, and operational benefits of CFB steam generators on a utility scale. At the conclusion of the Phase 2 program, testing related to satisfying these objectives was completed. Data analysis and reporting are scheduled for completion by October 1991. (VC)

  8. Encouraging Industrial Demonstrations of Fuel Cell Applications

    E-Print Network [OSTI]

    Anderson, J. M.

    ENCOURAGING INDUSTRIAL DEMONSTRATIONS OF FUEL CELL APPLICATIONS Joseph M~ Anderson, P.E. INDUSTRIAL FUEL CELL ASSOCIATION Lake Charles, Louisiana ABSTRACT Fuel Cell technology has advanced from a space-age curiosity to near commercial status... within the last few years. Both the electric and the gas utilities in the United States have conducted ambitious programs to oemonstrate the practicality of fuel cell power plants in a number of applications. The Japanese have been equally active...

  9. Experimental demonstration of photonic quantum ratchet

    E-Print Network [OSTI]

    Chi Zhang; Chuan-Feng Li; Guang-Can Guo

    2012-09-10T23:59:59.000Z

    We created a potential for light with a phase mirror and then experimentally realized a photonic quantum ratchet in an all-optical system, in which ratchet effects can be observed with the naked eye up to more than 22 steps, and quantum resonance can be demonstrated. Our method also provides a new means to simulate quantum particles with classical light, and it can be applied to investigate many other quantum phenomena.

  10. Lithium-Polysulfide Flow Battery Demonstration

    SciTech Connect (OSTI)

    Zheng, Wesley

    2014-06-30T23:59:59.000Z

    In this video, Stanford graduate student Wesley Zheng demonstrates the new low-cost, long-lived flow battery he helped create. The researchers created this miniature system using simple glassware. Adding a lithium polysulfide solution to the flask immediately produces electricity that lights an LED. A utility version of the new battery would be scaled up to store many megawatt-hours of energy.

  11. Lithium-Polysulfide Flow Battery Demonstration

    ScienceCinema (OSTI)

    Zheng, Wesley

    2014-07-16T23:59:59.000Z

    In this video, Stanford graduate student Wesley Zheng demonstrates the new low-cost, long-lived flow battery he helped create. The researchers created this miniature system using simple glassware. Adding a lithium polysulfide solution to the flask immediately produces electricity that lights an LED. A utility version of the new battery would be scaled up to store many megawatt-hours of energy.

  12. Buffalo river dredging demonstration. Final report

    SciTech Connect (OSTI)

    Averett, D.E.; Zappi, P.A.; Tatem, H.E.; Gibson, A.C.; Tominey, E.A.

    1996-02-01T23:59:59.000Z

    The Corps of Engineers Buffalo District conducted a demonstration of equipment for dredging contaminated sediments. Several thousand cubic yards of sediment were removed from outside the Buffalo River Federal navigation channel limits using three dredge types: (1) open bucket, (2) enclosed bucket, and (3) submersible pump. The effectiveness of a silt screen deployed downstream of the dredge to reduce suspended sediment transport was also evaluated. Extensive sediment and water column monitoring and sampling were conducted during the 2-week demonstration as part of the effort to determine sediment resuspension rates and contaminant releases associated with the dredging operations. Water column samples were analyzed for total suspended solids, total organic carbon, PCBs, PAHs, metals, ammonia, and pH. A water column bioassay test using Daphnia magna was also performed to assess toxicity effects of the dredging operation. Results of this study were used to assess and refine techniques and laboratory tests that have been previously developed by the Corps of Engineers to predict sediment resuspension rates and contaminant releases. In another phase of the study, the Bureau of Mines demonstrated the use of polyelectrolytes for rapid removal of suspended solids from a dilute dredged material slurry.

  13. CALDERON COKEMAKING PROCESS/DEMONSTRATION PROJECT

    SciTech Connect (OSTI)

    ALBERT CALDERON

    1998-06-22T23:59:59.000Z

    This project deals with the demonstration of a coking process using proprietary technology of Calderon, with the following objectives geared to facilitating commercialization: (1) making coke of such quality as to be suitable for use in hard-driving, large blast furnaces; (2) providing proof that such process is continuous and environmentally closed to prevent emissions; (3) demonstrating that high-coking-pressure (non-traditional) coal blends which cannot be safely charged into conventional by-product coke ovens can be used in the Calderon process; and (4) demonstrating that coke can be produced economically, at a level competitive with coke imports. The activities of the past quarter were focused on three main activities: Continuation of design of the coking reactor; Raising funds from the private sector; and Detailed analysis of the tests conducted in Alliance, Ohio. The design of the reactor work centered on the provision for the capability to inspect and maintain the internals of the reactor. The activities relating to raising funds from the steel industry have been fruitful. Bethlehem Steel has agreed to contribute funds. The collected data from the tests at Alliance were analyzed and a detailed report was completed and presented to the International Iron & Steel Institute by invitation.

  14. CALDERON COKEMAKING PROCESS/DEMONSTRATION PROJECT

    SciTech Connect (OSTI)

    ALBERT CALDERON

    1998-09-22T23:59:59.000Z

    This project deals with the demonstration of a coking process using proprietary technology of Calderon, with the following objectives geared to facilitate commercialization: (i) making coke of such quality as to be suitable for use in hard-driving, large blast furnaces; (ii) providing proof that such process is continuous and environmentally closed to prevent emissions; (iii) demonstrating that high-coking-pressure (non-traditional) coal blends which cannot be safely charged into conventional by-product coke ovens can be used in the Calderon process; and (iv) demonstrating that coke can be produced economically, at a level competitive with coke imports. The activities of the past quarter were focused on the following: ? Consolidation of the project team-players; ? Recruiting Koppers Industries as an additional stakeholder; ? Developing a closed system for the production of binder pitch from tar in the Calderon coking process as the incentive for Koppers to join the team; ? Gathering appropriate equipment for conducting a set of experiments at bench scale to simulate tar quality produced from the Calderon coking process for the production of binder pitch; and ? Further progress made in the design of the commercial coking reactor.

  15. Innovative grout/retrieval demonstration final report

    SciTech Connect (OSTI)

    Loomis, G.G.; Thompson, D.N.

    1995-01-01T23:59:59.000Z

    This report presents the results of an evaluation of an innovative retrieval technique for buried transuranic waste. Application of this retrieval technique was originally designed for full pit retrieval; however, it applies equally to a hot spot retrieval technology. The technique involves grouting the buried soil waste matrix with a jet grouting procedure, applying an expansive demolition grout to the matrix, and retrieving the debris. The grouted matrix provides an agglomeration of fine soil particles and contaminants resulting in an inherent contamination control during the dusty retrieval process. A full-scale field demonstration of this retrieval technique was performed on a simulated waste pit at the Idaho National Engineering Laboratory. Details are reported on all phases of this proof-of-concept demonstration including pit construction, jet grouting activities, application of the demolition grout, and actual retrieval of the grouted pit. A quantitative evaluation of aerosolized soils and rare earth tracer spread is given for all phases of the demonstration, and these results are compared to a baseline retrieval activity using conventional retrieval means. 8 refs., 47 figs., 10 tabs.

  16. Baltimore residential assistance demonstration project: Final report

    SciTech Connect (OSTI)

    NONE

    1998-09-01T23:59:59.000Z

    At the request of the City of Baltimore for assistance in developing the Global Action Plan (GAP) EcoTeam Program, DOE Office of Energy Efficiency and Renewable Energy provided GAP with $10,000 for a one-year demonstration project. The results of this action are as follows: four EcoTeams were established representing 28 households and 47 people; the self reported resource savings to date per household are on average: energy savings--9%, auto emission reduction--16%, solid waste reduction--52%, water savings--25%, dollar savings--$174; the initial seed team (prior to this funding) replicated and started 2 new teams, one of those teams replicated and started 2 more teams, the other team did not replicate; 4 volunteer coaches were recruited to coach each of these teams; a volunteer coordinator was recruited to provide local guidance for this demonstration project and help GAP reach out to the Fairfield low-income neighborhood, the volunteer coordinator was unable to establish any EcoTeams in this neighborhood as their priorities were establishing a neighborhood action team and addressing immediate health-related environmental issues; the volunteers have communicated information about this demonstration project among many community and Baltimore government leaders to solicit support for a full campaign and to assess the level of that support.

  17. CHP Fuel Cell Durability Demonstration - Final Report

    SciTech Connect (OSTI)

    Petrecky, James; Ashley, Christopher J

    2014-07-21T23:59:59.000Z

    Plug Power has managed a demonstration project that has tested multiple units of its high-temperature, PEM fuel cell system in micro-combined heat and power (?-CHP) applications in California. The specific objective of the demonstration project was to substantiate the durability of GenSys Blue, and, thereby, verify its technology and commercial readiness for the marketplace. In the demonstration project, Plug Power, in partnership with the National Fuel Cell Research Center (NFCRC) at the University of California, Irvine (UCI), and Sempra, will execute two major tasks: • Task 1: Internal durability/reliability fleet testing. Six GenSys Blue units will be built and will undergo an internal test regimen to estimate failure rates. This task was modified to include 3 GenSys Blue units installed in a lab at UCI. • Task 2: External customer testing. Combined heat and power units will be installed and tested in real-world residential and/or light commercial end user locations in California.

  18. Results From The Salt Disposition Project Next Generation Solvent Demonstration Plan

    SciTech Connect (OSTI)

    Peters, T. B.; Fondeur, F. F.; Taylor-Pashow, K. M.L.

    2014-04-02T23:59:59.000Z

    Strip Effluent Hold Tank (SEHT), Decontaminated Salt Solution Hold Tank (DSSHT), Caustic Wash Tank (CWT) and Solvent Hold Tank (SHT) samples were taken throughout the Next Generation Solvent (NGS) Demonstration Plan. These samples were analyzed and the results are reported. SHT: The solvent behaved as expected, with no bulk changes in the composition over time, with the exception of the TOA and TiDG. The TiDG depletion is higher than expected, and consideration must be taken on the required rate of replenishment. Monthly sampling of the SHT is warranted. If possible, additional SHT samples for TiDG analysis (only) would help SRNL refine the TiDG degradation model. CWT: The CWT samples show the expected behavior in terms of bulk chemistry. The 137Cs deposited into the CWT varies somewhat, but generally appears to be lower than during operations with the BOBCalix solvent. While a few minor organic components were noted to be present in the Preliminary sample, at this time these are thought to be artifacts of the sample preparation or may be due to the preceding solvent superwash. DSSHT: The DSSHT samples show the predicted bulk chemistry, although they point towards significant dilution at the front end of the Demonstration. The 137Cs levels in the DSSHT are much lower than during the BOBCalix operations, which is the expected observation. SEHT: The SEHT samples represent the most different output of all four of the outputs from MCU. While the bulk chemistry is as expected, something is causing the pH of the SEHT to be higher than what would be predicted from a pure stream of 0.01 M boric acid. There are several possible different reasons for this, and SRNL is in the process of investigating. Other than the pH issue, the SEHT is as predicted. In summary, the NGS Demonstration Plan samples indicate that the MCU system, with the Blend Solvent, is operating as expected. The only issue of concern regards the pH of the SEHT, and SRNL is in the process of investigating this. SRNL results support the transition to routine operations.

  19. A new measurement of the bulk flow of X-ray luminous clusters of galaxies

    E-Print Network [OSTI]

    A. Kashlinsky; F. Atrio-Barandela; H. Ebeling; A. Edge; D. Kocevski

    2010-03-11T23:59:59.000Z

    We present new measurements of the large-scale bulk flows of galaxy clusters based on 5-year WMAP data and a significantly expanded X-ray cluster catalogue. Our method probes the flow via measurements of the kinematic Sunyaev-Zeldovich (SZ) effect produced by the hot gas in moving clusters. It computes the dipole in the cosmic microwave background (CMB) data at cluster pixels, which preserves the SZ component while integrating down other contributions. Our improved catalog of over 1,000 clusters enables us to further investigate possible systematic effects and, thanks to a higher median cluster redshift, allows us to measure the bulk flow to larger scales. We present a corrected error treatment and demonstrate that the more X-ray luminous clusters, while fewer in number, have much larger optical depth, resulting in a higher dipole and thus a more accurate flow measurement. This results in the observed correlation of the dipole derived at the aperture of zero monopole with the monopole measured over the cluster central regions. This correlation is expected if the dipole is produced by the SZ effect and cannot be caused by unidentified systematics (or primary cosmic microwave background anisotropies). We measure that the flow is consistent with approximately constant velocity out to at least 800 Mpc. The significance of the measured signal peaks around 500 Mpc, most likely because the contribution from more distant clusters becomes progressively more diluted by the WMAP beam. We can, however, at present not rule out that these more distant clusters simply contribute less to the overall motion.

  20. Pacific Northwest Smart GridPacific Northwest Smart Grid Demonstration ProjectDemonstration Project

    E-Print Network [OSTI]

    customers to choose to control their energy usage ­ Smart meters ­ Home/building/industrial energy controls and displays · Automated home energy use 4 #12;The End-user is the Centerpiece of the Smart Grid 5Pacific Northwest Smart GridPacific Northwest Smart Grid Demonstration ProjectDemonstration Project