Powered by Deep Web Technologies
Note: This page contains sample records for the topic "delivery hydrogen storage" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Hydrogen Storage Technologies Hydrogen Delivery  

E-Print Network (OSTI)

Hydrogen Storage Technologies Roadmap Hydrogen Delivery Technical Team Roadmap June 2013 #12;This.................................................................................. 13 6. Hydrogen Storage and Innovation for Vehicle efficiency and Energy sustainability) is a voluntary, nonbinding, and nonlegal

2

Bulk Hydrogen Storage - Strategic Directions for Hydrogen Delivery Workshop  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen Hydrogen Storage Strategic Directions for Hydrogen Delivery Workshop May 7-8, 2003 Crystal City, Virginia Breakout Session - Bulk Hydrogen Storage Main Themes/Caveats Bulk Storage = Anything not on the vehicle 10's of Tons -- End use point 50-100 Tons - Terminals/City Gates 1000's Tons - Between Production Facility and Terminal/City Gate Bulk storage requirements less restrictive and different from on-board storage Uncertainty about evolution of infrastructure requires multiple pathways to be considered Bulk storage is an economic solution to address supply/demand imbalance Breakout Session - Bulk Hydrogen Storage Targets/Objectives Hard to quantify - scenario & end-use dependent Storage Materials (solid state) and container require different targets

3

Autothermal hydrogen storage and delivery systems  

DOE Patents (OSTI)

Processes are provided for the storage and release of hydrogen by means of dehydrogenation of hydrogen carrier compositions where at least part of the heat of dehydrogenation is provided by a hydrogen-reversible selective oxidation of the carrier. Autothermal generation of hydrogen is achieved wherein sufficient heat is provided to sustain the at least partial endothermic dehydrogenation of the carrier at reaction temperature. The at least partially dehydrogenated and at least partially selectively oxidized liquid carrier is regenerated in a catalytic hydrogenation process where apart from an incidental employment of process heat, gaseous hydrogen is the primary source of reversibly contained hydrogen and the necessary reaction energy.

Pez, Guido Peter (Allentown, PA); Cooper, Alan Charles (Macungie, PA); Scott, Aaron Raymond (Allentown, PA)

2011-08-23T23:59:59.000Z

4

Hydrogen Delivery  

NLE Websites -- All DOE Office Websites (Extended Search)

Mark Paster Energy Efficiency and Renewable Energy Hydrogen, Fuel Cells and Infrastructure Technology Program Hydrogen Production and Delivery Team Hydrogen Delivery Goal Hydrogen Delivery Goal Liquid H 2 & Chem. Carriers Gaseous Pipeline Truck Hydrides Liquid H 2 - Truck - Rail Other Carriers Onsite reforming Develop Develop hydrogen fuel hydrogen fuel delivery delivery technologies that technologies that enable the introduction and enable the introduction and long long - - term viability of term viability of hydrogen as an energy hydrogen as an energy carrier for transportation carrier for transportation and stationary power. and stationary power. Delivery Options * End Game - Pipelines - Other as needed * Breakthrough Hydrogen Carriers * Truck: HP Gas & Liquid Hydrogen

5

A Cassette Based System for Hydrogen Storage and Delivery  

DOE Green Energy (OSTI)

A hydrogen storage system is described and evaluated. This is based upon a cassette, that is a container for managing hydrogen storage materials. The container is designed to be safe, modular, adaptable to different chemistries, inexpensive, and transportable. A second module receives the cassette and provides the necessary infrastructure to deliver hydrogen from the cassette according to enduser requirements. The modular concept has a number of advantages over approaches that are all in one stand alone systems. The advantages of a cassette based system are discussed, along with results from model and laboratory testing.

Britton Wayne E.

2006-11-29T23:59:59.000Z

6

Hydrogen Storage  

Science Conference Proceedings (OSTI)

Oct 10, 2012 ... Energy Storage: Materials, Systems and Applications: Hydrogen Storage Program Organizers: Zhenguo "Gary" Yang, Pacific Northwest...

7

FCT Hydrogen Storage: Hydrogen Storage R&D Activities  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen Storage R&D Activities Hydrogen Storage R&D Activities to someone by E-mail Share FCT Hydrogen Storage: Hydrogen Storage R&D Activities on Facebook Tweet about FCT Hydrogen Storage: Hydrogen Storage R&D Activities on Twitter Bookmark FCT Hydrogen Storage: Hydrogen Storage R&D Activities on Google Bookmark FCT Hydrogen Storage: Hydrogen Storage R&D Activities on Delicious Rank FCT Hydrogen Storage: Hydrogen Storage R&D Activities on Digg Find More places to share FCT Hydrogen Storage: Hydrogen Storage R&D Activities on AddThis.com... Home Basics Current Technology DOE R&D Activities National Hydrogen Storage Compressed/Liquid Hydrogen Tanks Testing and Analysis Quick Links Hydrogen Production Hydrogen Delivery Fuel Cells Technology Validation Manufacturing Codes & Standards

8

Management of Leaks in Hydrogen Production, Delivery, and Storage Systems  

DOE Green Energy (OSTI)

A systematic approach to manage hydrogen leakage from components is presented. Methods to evaluate the quantity of hydrogen leakage and permeation from a system are provided by calculation and testing sensitivities. The following technology components of a leak management program are described: (1) Methods to evaluate hydrogen gas loss through leaks; (2) Methods to calculate opening areas of crack like defects; (3) Permeation of hydrogen through metallic piping; (4) Code requirements for acceptable flammability limits; (5) Methods to detect flammable gas; (6) Requirements for adequate ventilation in the vicinity of the hydrogen system; (7) Methods to calculate dilution air requirements for flammable gas mixtures; and (8) Concepts for reduced leakage component selection and permeation barriers.

Rawls, G

2006-04-27T23:59:59.000Z

9

Hydrogen Storage  

Science Conference Proceedings (OSTI)

Applied Neutron Scattering in Engineering and Materials Science Research: Hydrogen Storage Sponsored by: Metallurgical Society of the Canadian Institute of...

10

Hydrogen Storage  

Fuel Cell Technologies Publication and Product Library (EERE)

This 2-page fact sheet provides a brief introduction to hydrogen storage technologies. Intended for a non-technical audience, it explains the different ways in which hydrogen can be stored, as well a

11

FCT Hydrogen Storage: Current Technology  

NLE Websites -- All DOE Office Websites (Extended Search)

Current Technology to someone Current Technology to someone by E-mail Share FCT Hydrogen Storage: Current Technology on Facebook Tweet about FCT Hydrogen Storage: Current Technology on Twitter Bookmark FCT Hydrogen Storage: Current Technology on Google Bookmark FCT Hydrogen Storage: Current Technology on Delicious Rank FCT Hydrogen Storage: Current Technology on Digg Find More places to share FCT Hydrogen Storage: Current Technology on AddThis.com... Home Basics Current Technology Gaseous and Liquid Hydrogen Storage Materials-Based Hydrogen Storage Hydrogen Storage Challenges Status of Hydrogen Storage Technologies DOE R&D Activities Quick Links Hydrogen Production Hydrogen Delivery Fuel Cells Technology Validation Manufacturing Codes & Standards Education Systems Analysis Contacts Current Technology

12

FCT Hydrogen Delivery: Current Technology  

NLE Websites -- All DOE Office Websites (Extended Search)

Current Technology to someone Current Technology to someone by E-mail Share FCT Hydrogen Delivery: Current Technology on Facebook Tweet about FCT Hydrogen Delivery: Current Technology on Twitter Bookmark FCT Hydrogen Delivery: Current Technology on Google Bookmark FCT Hydrogen Delivery: Current Technology on Delicious Rank FCT Hydrogen Delivery: Current Technology on Digg Find More places to share FCT Hydrogen Delivery: Current Technology on AddThis.com... Home Basics Current Technology R&D Activities Quick Links Hydrogen Production Hydrogen Storage Fuel Cells Technology Validation Manufacturing Codes & Standards Education Systems Analysis Contacts Current Technology Today, hydrogen is transported from the point of production to the point of use via pipeline, over the road in cryogenic liquid trucks or gaseous tube

13

FCT Hydrogen Delivery: Hydrogen Delivery R&D Activities  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen Delivery R&D Activities to someone by E-mail Share FCT Hydrogen Delivery: Hydrogen Delivery R&D Activities on Facebook Tweet about FCT Hydrogen Delivery: Hydrogen Delivery...

14

FCT Hydrogen Storage: Contacts  

NLE Websites -- All DOE Office Websites (Extended Search)

Contacts to someone by E-mail Share FCT Hydrogen Storage: Contacts on Facebook Tweet about FCT Hydrogen Storage: Contacts on Twitter Bookmark FCT Hydrogen Storage: Contacts on...

15

Hydrogen Storage  

NLE Websites -- All DOE Office Websites (Extended Search)

Objectives - Develop and verify: On-board hydrogen storage systems achieving: 1.5 kWhkg (4.5 wt%), 1.2 kWhL, and 6kWh by 2005 2 kWhkg (6 wt%), 1.5 kWhL, and 4kWh by...

16

Hydrogen Storage- Overview  

NLE Websites -- All DOE Office Websites (Extended Search)

- - Overview George Thomas, Hydrogen Consultant to SNL * and Jay Keller, Hydrogen Program Manager Sandia National Laboratories H 2 Delivery and Infrastructure Workshop May 7-8, 2003 * Most of this presentation has been extracted from George Thomas' invited BES Hydrogen Workshop presentation (May 13-14, 2003) Sandia National Laboratories 4/14/03 2 Sandia National Laboratories From George Thomas, BES workshop 5/13/03 H 2 storage is a critical enabling technology for H 2 use as an energy carrier The low volumetric density of gaseous fuels requires a storage method which compacts the fuel. Hence, hydrogen storage systems are inherently more complex than liquid fuels. Storage technologies are needed in all aspects of hydrogen utilization. production distribution utilization

17

Energy Storage & Delivery  

Science Conference Proceedings (OSTI)

Energy Storage & Delivery. Summary: Schematic of Membrane Molecular Structure The goal of the project is to develop ...

2013-07-23T23:59:59.000Z

18

Joint Meeting on Hydrogen Delivery Modeling and Analysis Meeting...  

NLE Websites -- All DOE Office Websites (Extended Search)

on Hydrogen Delivery Modeling and Analysis FreedomCAR and Fuels Partnership Hydrogen Delivery, Storage and Fuel Pathway Integration Tech Teams May 8-9, 2007 Energetics...

19

Delivery of Hydrogen Produced from Natural Gas  

NLE Websites -- All DOE Office Websites (Extended Search)

Identify and evaluate the most promising approaches and options for economic storage, handling and delivery of hydrogen. Office of Fossil Energy Milestone * 2006: Define a...

20

Hydrogen Delivery Infrastructure Option Analysis  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen Delivery Infrastructure Hydrogen Delivery Infrastructure Option Analysis Option Analysis DOE and FreedomCAR & Fuel Partnership Hydrogen Delivery and On-Board Storage Analysis Workshop January 25, 2005 Washington DC This presentation does not contain any proprietary or confidential information Tan-Ping Chen Nexant Jim Campbell Bhadra Grover Air Liquide Stefan Unnasch TIAX Glyn Hazelden GTI Graham Moore Chevron Matt Ringer NREL Ray Hobbs Pinnacle West 2 Presentation Outline Project Background Knowledge Collected and Preliminary Results for Each Delivery Option Summary of Observations Next Step Project Background Project Background 4 Delivery Options Option 1* GH delivery by new pipelines Option 2 Converting NG/oil pipelines for GH delivery Option 3 Blending GH into NG pipelines Option 4* GH tube trailers

Note: This page contains sample records for the topic "delivery hydrogen storage" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

FCT Hydrogen Storage: The 'National Hydrogen Storage Project...  

NLE Websites -- All DOE Office Websites (Extended Search)

The 'National Hydrogen Storage Project' to someone by E-mail Share FCT Hydrogen Storage: The 'National Hydrogen Storage Project' on Facebook Tweet about FCT Hydrogen Storage: The...

22

Metal?organic frameworks for the storage and delivery of biologically active hydrogen sulfide  

SciTech Connect

Hydrogen sulfide is an extremely toxic gas that is also of great interest for biological applications when delivered in the correct amount and at the desired rate. Here we show that the highly porous metal-organic frameworks with the CPO-27 structure can bind the hydrogen sulfide relatively strongly, allowing the storage of the gas for at least several months. Delivered gas is biologically active in preliminary vasodilation studies of porcine arteries, and the structure of the hydrogen sulfide molecules inside the framework has been elucidated using a combination of powder X-ray diffraction and pair distribution function analysis.

Allan, Phoebe K.; Wheatley, Paul S.; Aldous, David; Mohideen, M. Infas; Tang, Chiu; Hriljac, Joseph A.; Megson, Ian L.; Chapman, Karena W.; De Weireld, Guy; Vaesen, Sebastian; Morris, Russell E. (St Andrews)

2012-04-02T23:59:59.000Z

23

FCT Hydrogen Storage: Basics  

NLE Websites -- All DOE Office Websites (Extended Search)

Basics to someone by E-mail Share FCT Hydrogen Storage: Basics on Facebook Tweet about FCT Hydrogen Storage: Basics on Twitter Bookmark FCT Hydrogen Storage: Basics on Google...

24

Energy Dense, Lighweight, Durable, Systems for Storage and Delivery of Hydrogen  

Science Conference Proceedings (OSTI)

The work presented in this report summarizes the current state-of-the-art in on-board storage on compressed gaseous hydrogen as well as the development of analysis tools, methods, and theoretical data for devising high performance design configurations for hydrogen storage. The state-of-the-art in the area of compressed hydrogen storage reveals that the current configuration of the hydrogen storage tank is a seamless cylindrical part with two end domes. The tank is composed of an aluminum liner overwrapped with carbon fibers. Such a configuration was proved to sustain internal pressures up to 350 bars (5,000 psi). Finite-element stress analyses were performed on filament-wound hydrogen storage cylindrical tanks under the effect of internal pressure of 700 bars (10,000 psi). Tank deformations, stress fields, and intensities induced at the tank wall were examined. The results indicated that the aluminum liner can not sustain such a high pressure and initiate the tank failure. Thus, hydrogen tanks ought to be built entirely out of composite materials based on carbon fibers or other innovative composite materials. A spherical hydrogen storage tank was suggested within the scope of this project. A stress reduction was achieved by this change of the tank geometry, which allows for increasing the amount of the stored hydrogen and storage energy density. The finite element modeling of both cylindrical and spherical tank design configurations indicate that the formation of stress concentration zones in the vicinity of the valve inlet as well as the presence of high shear stresses in this area. Therefore, it is highly recommended to tailor the tank wall design to be thicker in this region and tapered to the required thickness in the rest of the tank shell. Innovative layout configurations of multiple tanks for enhanced conformability in limited space have been proposed and theoretically modeled using 3D finite element analysis. Optimum tailoring of fiber orientations and lay-ups are needed to relieve the high stress in regions of high stress concentrations between intersecting tanks/ tank sections. Filament winding process is the most suitable way for producing both cylindrical and spherical hydrogen storage tanks with high industrial quality. However, due to the unavailability of such equipment at West Virginia University and limited funding, the composite structures within this work were produced by hand layup and bag molding techniques. More advanced manufacturing processes can significantly increase the structural strength of the tank and enhances its performance and also further increase weight saving capabilities. The concept of using a carbon composite liner seems to be promising in overcoming the low strength of the aluminum liner at internal high pressures. This could be further enhanced by using MetPreg filament winding to produce such a liner. Innovative designs for the polar boss of the storage tanks and the valve connections are still needed to reduce the high stress formed in these zones to allow for the tank to accommodate higher internal pressures. The Continuum Damage Mechanics (CDM) approach was applied for fault-tolerant design and efficient maintenance of lightweight automotive structures made of composite materials. Potential effects of damage initiation and accumulation are formulated for various design configurations, with emphasis on lightweight fiber-reinforced composites. The CDM model considers damage associated with plasticity and fatigue.

Jacky Pruez; Samir Shoukry; Gergis William; Thomas Evans; Hermann Alcazar

2008-12-31T23:59:59.000Z

25

FCT Hydrogen Delivery: Basics  

NLE Websites -- All DOE Office Websites (Extended Search)

distributed production facilities have relatively low delivery costs, but the hydrogen production costs are likely to be higher-lower volume production means higher equipment...

26

Delivery of Hydrogen Produced from Natural Gas  

E-Print Network (OSTI)

for economic storage, handling and delivery of hydrogen. Office of Fossil Energy Milestone · 2006: Define & Petroleum Technology Office of Fossil Energy June 3, 2003 Hydrogen Coordination Meeting #12;Key NearDelivery of Hydrogen Produced from Natural Gas Christopher Freitas Office of Natural Gas

27

Measurements for Hydrogen Storage Materials  

Science Conference Proceedings (OSTI)

Measurements for Hydrogen Storage Materials. Summary: ... Hydrogen is promoted as petroleum replacement in the Hydrogen Economy. ...

2013-07-02T23:59:59.000Z

28

Fuel Cell Technologies Office: Hydrogen Storage  

NLE Websites -- All DOE Office Websites (Extended Search)

Fuel Cell Technologies Office: Hydrogen Storage to Fuel Cell Technologies Office: Hydrogen Storage to someone by E-mail Share Fuel Cell Technologies Office: Hydrogen Storage on Facebook Tweet about Fuel Cell Technologies Office: Hydrogen Storage on Twitter Bookmark Fuel Cell Technologies Office: Hydrogen Storage on Google Bookmark Fuel Cell Technologies Office: Hydrogen Storage on Delicious Rank Fuel Cell Technologies Office: Hydrogen Storage on Digg Find More places to share Fuel Cell Technologies Office: Hydrogen Storage on AddThis.com... Home Basics Current Technology DOE R&D Activities Quick Links Hydrogen Production Hydrogen Delivery Fuel Cells Technology Validation Manufacturing Codes & Standards Education Systems Analysis Contacts On-board hydrogen storage for transportation applications continues to be

29

Potential Carriers and Approaches for Hydrogen Delivery  

NLE Websites -- All DOE Office Websites (Extended Search)

Carriers and Potential Carriers and Carriers and Potential Carriers and Approaches for Hydrogen Approaches for Hydrogen Delivery Delivery TIAX LLC 1601 S. D Anza Blvd. Cupertino CA, 95014 Tel. 408-517-1550 Reference: D0348 © 2007 TIAX LLC Hydrogen Delivery Analysis Meeting May 8-9, 2007 Columbia, Maryland Matthew Hooks Stefan Unnasch Stephen Lasher 1 Novel Hydrogen Carriers Project Overview Cost Density (wt. and vol.) Energy requirements Forecourt storage requirements Codes and standards H H 2 2 Plant, Liquefier, LH Plant, Liquefier, LH 2 2 storage storage H H 2 2 Tube Trailer Tube Trailer LH 2 2 Tank/ Fueling Station LH Tank/ Fueling Station The efficient delivery of hydrogen is necessary for the adoption of hydrogen as a transportation fuel, but numerous challenges must be met. 2 "Conventional" delivery options are limited by volumetric density,

30

Hydrogen & Fuel Cells - Hydrogen - Hydrogen Storage  

NLE Websites -- All DOE Office Websites (Extended Search)

University of Chicago team. On-board hydrogen storage is critical to the development of future high energy efficiency transportation technologies, such as hydrogen-powered fuel...

31

U.S. Army Energy and Environmental Requirements and Goals: Opportunities for Fuel Cells and Hydrogen - Facility Locations and Hydrogen Storage/Delivery Logistics  

NLE Websites -- All DOE Office Websites (Extended Search)

US Army Corps US Army Corps of Engineers ® Engineer Research and Development Center U.S. Army Energy and Environmental Requirements and Goals: Opportunities for Fuel Cells and Hydrogen Facility Locations and Hydrogen Storage/Delivery Logistics Nicholas M. Josefik 217-373-4436 N-josefik@cecer.army.mil www.dodfuelcell.com Franklin H. Holcomb Project Leader, Fuel Cell Team 27 OCT 08 Distributed Generation H 2 Generation & Storage Material Handling H2 Vehicles 2 US Army Corps of Engineers ® Engineer Research and Development Center Presentation Outline * DoD Energy Use * Federal Facilities Goals and Requirements * Federal Vehicles and Fuel Goals * Opportunities & Conclusions 3 US Army Corps of Engineers ® Engineer Research and Development Center Where Does the Energy Go? * Tactical and Combat Vehicles (Jets,

32

Hydrogen Delivery Options and Issues  

NLE Websites -- All DOE Office Websites (Extended Search)

Options and Issues Options and Issues Mark Paster DOE August, 2006 Scope * From the end point of central or distributed production (300 psi H2) to and including the dispenser at a refueling station or stationary power site - GH2 Pipelines and Trucks, LH2 Trucks, Carriers <$1.00/kg of Hydrogen by 2017 Hydrogen Delivery H2 Delivery Current Status * Technology - GH2 Tube Trailers: ~340 kg, ~2600 psi - LH2 Trucks: ~3900 kg - Pipelines: up to 1500 psi (~630 miles in the U.S.) - Refueling Site Operations (compression, storage dispensing): Demonstration projects * Cost (Does NOT include refueling Site Operations) - Trucks: $4-$12/kg - Pipeline: <$2/kg H2A Analysis * Consistent, comparable, transparent approach to hydrogen production and delivery cost analysis * Excel spreadsheet tools with common economic

33

Fuel Cell Technologies Office: Hydrogen Delivery  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

| Consumer Information Hydrogen Delivery Search Search Help Hydrogen Delivery EERE Fuel Cell Technologies Office Hydrogen Delivery Printable Version Share this resource...

34

Development of High Pressure Hydrogen Storage Tank for Storage and Gaseous Truck Delivery - DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report  

NLE Websites -- All DOE Office Websites (Extended Search)

2 2 DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report Jon Knudsen (Primary Contact), Don Baldwin Lincoln Composites 5117 N.W. 40 th Street Lincoln, NE 68524 Phone: (402) 470-5039 Email: jknudsen@lincolncomposites.com DOE Managers HQ: Erika Sutherland Phone: (202) 586-3152 Email: Erika.Sutherland@ee.doe.gov GO: Katie Randolph Phone: (720) 356-1759 Email: Katie.Randolph@go.doe.gov Contract Number: DE-FG36-08GO18062 Project Start Date: July 1, 2008 Project End Date: April 30, 2013 Fiscal Year (FY) 2012 Objectives The objective of this project is to design and develop the most effective bulk hauling and storage solution for hydrogen in terms of: Cost * Safety * Weight * Volumetric Efficiency * Technical Barriers This project addresses the following technical barriers

35

Ultrafine hydrogen storage powders  

DOE Patents (OSTI)

A method of making hydrogen storage powder resistant to fracture in service involves forming a melt having the appropriate composition for the hydrogen storage material, such, for example, LaNi.sub.5 and other AB.sub.5 type materials and AB.sub.5+x materials, where x is from about -2.5 to about +2.5, including x=0, and the melt is gas atomized under conditions of melt temperature and atomizing gas pressure to form generally spherical powder particles. The hydrogen storage powder exhibits improved chemcial homogeneity as a result of rapid solidfication from the melt and small particle size that is more resistant to microcracking during hydrogen absorption/desorption cycling. A hydrogen storage component, such as an electrode for a battery or electrochemical fuel cell, made from the gas atomized hydrogen storage material is resistant to hydrogen degradation upon hydrogen absorption/desorption that occurs for example, during charging/discharging of a battery. Such hydrogen storage components can be made by consolidating and optionally sintering the gas atomized hydrogen storage powder or alternately by shaping the gas atomized powder and a suitable binder to a desired configuration in a mold or die.

Anderson, Iver E. (Ames, IA); Ellis, Timothy W. (Doylestown, PA); Pecharsky, Vitalij K. (Ames, IA); Ting, Jason (Ames, IA); Terpstra, Robert (Ames, IA); Bowman, Robert C. (La Mesa, CA); Witham, Charles K. (Pasadena, CA); Fultz, Brent T. (Pasadena, CA); Bugga, Ratnakumar V. (Arcadia, CA)

2000-06-13T23:59:59.000Z

36

Hydrogen Delivery Roadmap  

NLE Websites -- All DOE Office Websites (Extended Search)

Delivery Delivery Technical Team Roadmap June 2013 This roadmap is a document of the U.S. DRIVE Partnership. U.S. DRIVE (United States Driving Research and Innovation for Vehicle efficiency and Energy sustainability) is a voluntary, non-binding, and nonlegal partnership among the U.S. Department of Energy; United States Council for Automotive Research (USCAR), representing Chrysler Group LLC, Ford Motor Company, and General Motors; Tesla Motors; five energy companies - BPAmerica, Chevron Corporation, Phillips 66 Company, ExxonMobil Corporation, and Shell Oil Products US; two utilities - Southern California Edison and DTE Energy; and the Electric Power Research Institute (EPRI). The Hydrogen Delivery Technical Team is one of 12 U.S. DRIVE technical teams ("tech teams") whose

37

A Brief Overview of Hydrogen Storage Issues and Needs  

NLE Websites -- All DOE Office Websites (Extended Search)

Brief Overview of Hydrogen Storage Issues and Needs George Thomas and Sunita Satyapal Joint Tech Team Meeting Delivery, Storage and Fuels Pathway Tech Teams May 8-9, 2007 Storage...

38

Hydrogen & Fuel Cells - Hydrogen - Hydrogen Storage  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen Storage Systems Modeling and Analysis Hydrogen Storage Systems Modeling and Analysis Several different approaches are being pursued to develop on-board hydrogen storage systems for light-duty vehicle applications. The different approaches have different characteristics, such as: the thermal energy and temperature of charge and discharge kinetics of the physical and chemical process steps involved requirements for the materials and energy interfaces between the storage system and the fuel supply system on one hand, and the fuel user on the other Other storage system design and operating parameters influence the projected system costs as well. Argonne researchers are developing thermodynamic, kinetic, and engineering models of the various hydrogen storage systems to understand the characteristics of storage systems based on these approaches and to evaluate their potential to meet the DOE targets for on-board applications. The DOE targets for 2015 include a system gravimetric capacity of 1.8 kWh/kg (5.5 wt%) and a system volumetric capacity of 1.3 kWh/L (40 g/L). We then use these models to identify significant component and performance issues, and evaluate alternative system configurations and design and operating parameters.

39

Hydrogen storage and integrated fuel cell assembly  

DOE Patents (OSTI)

Hydrogen is stored in materials that absorb and desorb hydrogen with temperature dependent rates. A housing is provided that allows for the storage of one or more types of hydrogen-storage materials in close thermal proximity to a fuel cell stack. This arrangement, which includes alternating fuel cell stack and hydrogen-storage units, allows for close thermal matching of the hydrogen storage material and the fuel cell stack. Also, the present invention allows for tailoring of the hydrogen delivery by mixing different materials in one unit. Thermal insulation alternatively allows for a highly efficient unit. Individual power modules including one fuel cell stack surrounded by a pair of hydrogen-storage units allows for distribution of power throughout a vehicle or other electric power consuming devices.

Gross, Karl J. (Fremont, CA)

2010-08-24T23:59:59.000Z

40

NREL: Learning - Hydrogen Storage  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen Storage Hydrogen Storage On the one hand, hydrogen's great asset as a renewable energy carrier is that it is storable and transportable. On the other hand, its very low natural density requires storage volumes that are impractical for vehicles and many other uses. Current practice is to compress the gas in pressurized tanks, but this still provides only limited driving range for vehicles and is bulkier than desirable for other uses as well. Liquefying the hydrogen more than doubles the fuel density, but uses up substantial amounts of energy to lower the temperature sufficiently (-253°C at atmospheric pressure), requires expensive insulated tanks to maintain that temperature, and still falls short of desired driving range. One possible way to store hydrogen at higher density is in the spaces within the crystalline

Note: This page contains sample records for the topic "delivery hydrogen storage" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

DOE Hydrogen and Fuel Cells Program: Hydrogen Storage  

NLE Websites -- All DOE Office Websites (Extended Search)

Energy Search help Home > Hydrogen Storage Printable Version Hydrogen Storage Hydrogen storage is a key enabling technology for the advancement of hydrogen and fuel cell power...

42

Hydrogen Delivery Infrastructure Options Analysis  

Fuel Cell Technologies Publication and Product Library (EERE)

This report, by the Nexant team, documents an in-depth analysis of seven hydrogen delivery options to identify the most cost-effective hydrogen infrastructure for the transition and long term. The pro

43

Hydrogen Distribution and Delivery Infrastructure  

Fuel Cell Technologies Publication and Product Library (EERE)

This 2-page fact sheet provides a brief introduction to hydrogen delivery technologies. Intended for a non-technical audience, it explains how hydrogen is transported and delivered today, the challen

44

Fuel Cell Technologies Office: Hydrogen Storage  

NLE Websites -- All DOE Office Websites (Extended Search)

Storage Storage On-board hydrogen storage for transportation applications continues to be one of the most technically challenging barriers to the widespread commercialization of hydrogen-fueled vehicles. The EERE hydrogen storage activity focuses primarily on the applied research and development (R&D) of low-pressure, materials-based technologies to allow for a driving range of more than 300 miles (500 km) while meeting packaging, cost, safety, and performance requirements to be competitive with current vehicles. While automakers have recently demonstrated progress with some prototype vehicles traveling more than 300 miles on a single fill, this driving range must be achievable across different vehicle models and without compromising space, performance, or cost. In addition, hydrogen storage will be needed for both other niche vehicular applications and off-board uses such as for stationary power generation and for hydrogen delivery and refueling infrastructure.

45

Hydrogen Delivery Analysis Models  

NLE Websites -- All DOE Office Websites (Extended Search)

model for delivery system component costs and performance: Components Model Delivery scenario model for Urban and Rural Interstate markets and demand levels (Mkt....

46

Fuel Cell Technologies Office: Hydrogen Storage  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

| Consumer Information Hydrogen Storage Search Search Help Hydrogen Storage EERE Fuel Cell Technologies Office Hydrogen Storage Printable Version Share this resource Send...

47

Hydrogen Delivery Model for H2A Analysis: A Spreadsheet Model For Hydrogen Delivery Scenarios  

E-Print Network (OSTI)

FINAL REPORT HYDROGEN DELIVERY MODEL FOR H2AA SPREADSHEET MODEL FOR HYDROGEN DELIVERY SCENARIOS Joan M.Department of Energy Hydrogen, Fuel Cells and Infrastructure

Ogden, Joan

2004-01-01T23:59:59.000Z

48

Hydrogen Delivery Model for H2A Analysis: A Spreadsheet Model for Hydrogen Delivery Scenarios  

E-Print Network (OSTI)

FINAL REPORT HYDROGEN DELIVERY MODEL FOR H2AA SPREADSHEET MODEL FOR HYDROGEN DELIVERY SCENARIOS Joan M.Department of Energy Hydrogen, Fuel Cells and Infrastructure

Ogden, Joan M

2004-01-01T23:59:59.000Z

49

Nanostructured materials for hydrogen storage  

DOE Patents (OSTI)

A system for hydrogen storage comprising a porous nano-structured material with hydrogen absorbed on the surfaces of the porous nano-structured material. The system of hydrogen storage comprises absorbing hydrogen on the surfaces of a porous nano-structured semiconductor material.

Williamson, Andrew J. (Pleasanton, CA); Reboredo, Fernando A. (Pleasanton, CA)

2007-12-04T23:59:59.000Z

50

Gaseous Hydrogen Delivery Breakout - Strategic Directions for Hydrogen Delivery Workshop  

NLE Websites -- All DOE Office Websites (Extended Search)

Gaseous Hydrogen Gaseous Hydrogen Delivery Breakout Strategic Directions for Hydrogen Delivery Workshop May 7-8, 2003 Crystal City, Virginia Breakout Session Name Targets/Objectives More work is needed to better define delivery target metrics Assumptions about targets for costs and energy efficiency need to be qualified Technology improvements likely to lower costs, but may not have major impact on total cost A significant impact on cost would come through permitting policy changes, e.g., use of public land Breakout Session Name Priority Barriers System Issues: need to assess delivery options in context of total system Materials: corrosion, H2 permeability Construction: welding, joining Maintenance and Operation: leak detection Pipeline Safety: odorants, flame visibility

51

Hydrogen Delivery Technology Roadmap, November 2005  

Fuel Cell Technologies Publication and Product Library (EERE)

Document describing plan for research into and development of hydrogen delivery technology for transportation applications.

52

Gas storage materials, including hydrogen storage materials  

DOE Patents (OSTI)

A material for the storage and release of gases comprises a plurality of hollow elements, each hollow element comprising a porous wall enclosing an interior cavity, the interior cavity including structures of a solid-state storage material. In particular examples, the storage material is a hydrogen storage material such as a solid state hydride. An improved method for forming such materials includes the solution diffusion of a storage material solution through a porous wall of a hollow element into an interior cavity.

Mohtadi, Rana F; Wicks, George G; Heung, Leung K; Nakamura, Kenji

2013-02-19T23:59:59.000Z

53

Enhancing hydrogen spillover and storage  

DOE Patents (OSTI)

Methods for enhancing hydrogen spillover and storage are disclosed. One embodiment of the method includes doping a hydrogen receptor with metal particles, and exposing the hydrogen receptor to ultrasonification as doping occurs. Another embodiment of the method includes doping a hydrogen receptor with metal particles, and exposing the doped hydrogen receptor to a plasma treatment.

Yang, Ralph T. (Ann Arbor, MI); Li, Yingwel (Ann Arbor, MI); Lachawiec, Jr., Anthony J. (Ann Arbor, MI)

2011-05-31T23:59:59.000Z

54

Enhancing hydrogen spillover and storage  

DOE Patents (OSTI)

Methods for enhancing hydrogen spillover and storage are disclosed. One embodiment of the method includes doping a hydrogen receptor with metal particles, and exposing the hydrogen receptor to ultrasonication as doping occurs. Another embodiment of the method includes doping a hydrogen receptor with metal particles, and exposing the doped hydrogen receptor to a plasma treatment.

Yang, Ralph T; Li, Yingwei; Lachawiec, Jr., Anthony J

2013-02-12T23:59:59.000Z

55

Chemical Hydrogen Storage Center Center of Excellence  

E-Print Network (OSTI)

Source Hydrogen H2 storage Hydrogen Stored Energy Point-of-use Chemical hydrogen storage #12;5 ChemicalChemical Hydrogen Storage Center Center of Excellence for Chemical Hydrogen Storage William Tumas proprietary or confidential information #12;2 Chemical Hydrogen Storage Center Overview Project Start Date: FY

Carver, Jeffrey C.

56

Hydrogen Delivery: An Option to Ease the Transition  

NLE Websites -- All DOE Office Websites (Extended Search)

Delivery: Delivery: An Option to Ease the Transition Presentation at: The DOE Hydrogen and Fuel Cells Coordination Meeting Washington, D.C. June 3, 2003 John C. Winslow, Product Manager, Coal Fuels & Hydrogen National Energy Technology Laboratory Descriptor - include initials, /org#/date Hydrogen Delivery Today * Hydrogen infrastructure exists only for small merchant hydrogen markets in the chemical and refining industries * Current natural gas infrastructure consists of: - Pipelines - intermediate product storage - import terminals - rail, barge, and truck delivery U.S. Pipeline Mileage 0.7 2000 279 0 1000 2000 3000 Oil Nat Gas Hydrogen thousand miles Source: APCI, EIA, NEP Descriptor - include initials, /org#/date Comparison of Alternative Delivery Pathways Central H 2 production (coal)

57

Hydrogen Delivery Liquefaction & Compression  

E-Print Network (OSTI)

SEPARATION PLANTS NITROGEN OXYGEN INDUSTRIAL AREA GALVESTON BAY GULF OF MEXICO BAYTOWN MONT BELVIEU Refrigeration GN2 to N2 Liquefier To Feed H2 Flash Compressor H2 Recycle Compressor LN2 Add. To Storage/Fill #12

58

Advanced Concepts for Hydrogen Storage  

NLE Websites -- All DOE Office Websites (Extended Search)

Framework", Nature, 402, 276-279 (1999). Mesoporous Organosilica Material benzene-silica hybrid material Hydrogen storage behavior? S. Inagaki, S. Guan, T. Ohsuna, and...

59

Powertech: Hydrogen Expertise Storage Needs  

NLE Websites -- All DOE Office Websites (Extended Search)

- Stations 700 bar Retail Stations 700 bar Retail Stations (Shell Newport Beach) Hydrogen Energy Storage Projects (BC Hydro Renewable Power - HARP) Lightweight Transport Trailers...

60

Liquid Hydrogen Delivery - Strategic Directions for Hydrogen Delivery Workshop  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen Hydrogen Delivery Strategic Directions for Hydrogen Delivery Workshop May 7-8, 2003 Crystal City, Virginia Main Themes/Caveats Will be challenging (if not impossible) to meet the 2010 cost target with today's technology Without significant growth in product demand, progress will likely be slow even with incremental technology Group a little light on technical expertise, but feel captured main ideas required Less "weeding" of ideas, but more divergent thinking Targets/Objectives 2003 Status: $1.11/kg May be a bit lower than actual costs Baseline needs to be revisited 2005 Target: $1.01/kg Technically (10% improvement) could be met, but unlikely demand drivers will be present to encourage meeting target Likely no plant will be built in 2005

Note: This page contains sample records for the topic "delivery hydrogen storage" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Hydrogen-based electrochemical energy storage - Energy ...  

An energy storage device (100) providing high storage densities via hydrogen storage. The device (100) includes a counter electrode (110), a storage ...

62

Hydrogen Storage Materials Database Demonstration  

NLE Websites -- All DOE Office Websites (Extended Search)

| Fuel Cell Technologies Program Source: US DOE 4/25/2011 eere.energy.gov | Fuel Cell Technologies Program Source: US DOE 4/25/2011 eere.energy.gov Hydrogen Storage Materials Database Demonstration FUEL CELL TECHNOLOGIES PROGRAM Ned Stetson Storage Tech Team Lead Fuel Cell Technologies Program U.S. Department of Energy 12/13/2011 Hydrogen Storage Materials Database Marni Lenahan December 13, 2011 Database Background * The Hydrogen Storage Materials Database was built to retain information from DOE Hydrogen Storage funded research and make these data more accessible. * Data includes properties of hydrogen storage materials investigated such as synthesis conditions, sorption and release conditions, capacities, thermodynamics, etc. http://hydrogenmaterialssearch.govtools.us Current Status * Data continues to be collected from DOE funded research.

63

NREL: Hydrogen and Fuel Cells Research - Hydrogen Production and Delivery  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen Production and Delivery Hydrogen Production and Delivery Most of the hydrogen in the United States is produced by steam reforming of natural gas. For the near term, this production method will continue to dominate. Researchers at NREL are developing advanced processes to produce hydrogen economically from sustainable resources. NREL's hydrogen production and delivery R&D efforts, which are led by Huyen Dinh, focus on the following topics: Biological Water Splitting Fermentation Conversion of Biomass and Wastes Photoelectrochemical Water Splitting Solar Thermal Water Splitting Renewable Electrolysis Hydrogen Dispenser Hose Reliability Hydrogen Production and Delivery Pathway Analysis. Biological Water Splitting Certain photosynthetic microbes use light energy to produce hydrogen from

64

Complex Hydrides for Hydrogen Storage  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrides for Hydrides for Hydrogen Storage George Thomas, Consultant Sandia National Laboratories G. J. Thomas Efficient onboard hydrogen storage is a critical enabling technology for the use of hydrogen in vehicles * The low volumetric density of gaseous fuels requires a storage method which densifies the fuel. - This is particularly true for hydrogen because of its lower energy density relative to hydrocarbon fuels. * Storage methods result in additional weight and volume above that of the fuel. How do we achieve adequate stored energy in an efficient, safe and cost-effective system? G. J. Thomas However, the storage media must meet certain requirements: - reversible hydrogen uptake/release - lightweight - low cost - cyclic stability - rapid kinetic properties - equilibrium properties (P,T) consistent

65

Hydrogen Storage Requirements for Fuel Cell Vehicles  

NLE Websites -- All DOE Office Websites (Extended Search)

GENERAL MOTORS GENERAL MOTORS HYDROGEN STORAGE REQUIREMENTS FOR FUEL CELL VEHICLES Brian G. Wicke GM R&D and Planning DOE Hydrogen Storage Workshop August 14-15, 2002 Argonne National Laboratory General Motors Fuel Cell Vehicles * GM fuel cell vehicle Goal - be the first to profitably sell one million fuel cell vehicles * Fuel cell powerplant must be suitable for a broad range of light-duty vehicles (not just niche) * UNCOMPROMISED performance & reliability are REQUIRED * SAFETY IS A GIVEN * Evolutionary and Revolutionary vehicle designs are included-GM AUTONOMY-as long as the customer is (more than) satisfied GENERAL MOTORS AUTONOMY GENERAL MOTORS AUTONOMY General Motors Fuel Cell Vehicles * Focus on PEM fuel cell technology * Must consider entire hydrogen storage & (unique) fuel delivery systems,

66

Fuel Cell Technologies Office: Hydrogen Delivery  

NLE Websites -- All DOE Office Websites (Extended Search)

Basics Current Technology R&D Activities Quick Links Hydrogen Production Hydrogen Storage Fuel Cells Technology Validation Manufacturing Codes & Standards Education Systems...

67

Ultrafine hydrogen storage powders - Energy Innovation Portal  

A method of making hydrogen storage powder resistant to fracture in service involves forming a melt having the appropriate composition for the hydrogen storage ...

68

Ultrafine Hydrogen Storage Powders - Energy Innovation Portal  

Patent 6,074,453: Ultrafine hydrogen storage powders A method of making hydrogen storage powder resistant to fracture in service involves forming a melt having the ...

69

Hydrogen Compression, Storage, and Dispensing Cost Reduction...  

NLE Websites -- All DOE Office Websites (Extended Search)

of Materials. Storage Respondents submitted additional needs for R&D in the area of hydrogen storage: Advanced metal alloys in order to lower the cost of hydrogen...

70

Fuel Cell Technologies Office: Hydrogen Compression, Storage...  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen Compression, Storage, and Dispensing Cost Reduction Workshop to someone by E-mail Share Fuel Cell Technologies Office: Hydrogen Compression, Storage, and Dispensing Cost...

71

Inexpensive Delivery of Compressed Hydrogen with Advanced Vessel Technology  

NLE Websites -- All DOE Office Websites (Extended Search)

delivery of compressed hydrogen delivery of compressed hydrogen with advanced vessel technology Gene Berry Andrew Weisberg Salvador M. Aceves Lawrence Livermore National Laboratory (925) 422-0864 saceves@LLNL.GOV DOE and FreedomCar & Fuel Partnership Hydrogen Delivery and On-Board Storage Analysis Workshop Washington, DC January 25, 2006 LLNL is developing innovative concepts for efficient containment of hydrogen in light duty vehicles concepts may offer advantages for hydrogen delivery Conformable containers efficiently use available space in the vehicle. We are pursuing multiple approaches to conformability High Strength insulated pressure vessels extend LH 2 dormancy 10x, eliminate boiloff, and enable efficiencies of flexible refueling (compressed/cryogenic H 2 /(L)H 2 ) The PVT properties of H

72

Catalyzed borohydrides for hydrogen storage  

Science Conference Proceedings (OSTI)

A hydrogen storage material and process is provided in which alkali borohydride materials are created which contain effective amounts of catalyst(s) which include transition metal oxides, halides, and chlorides of titanium, zirconium, tin, and combinations of the various catalysts. When the catalysts are added to an alkali borodydride such as a lithium borohydride, the initial hydrogen release point of the resulting mixture is substantially lowered. Additionally, the hydrogen storage material may be rehydrided with weight percent values of hydrogen at least about 9 percent.

Au, Ming (Augusta, GA)

2012-02-28T23:59:59.000Z

73

Complex Hydrides for Hydrogen Storage  

DOE Green Energy (OSTI)

This report describes research into the use of complex hydrides for hydrogen storage. The synthesis of a number of alanates, (AIH4) compounds, was investigated. Both wet chemical and mechano-chemical methods were studied.

Slattery, Darlene; Hampton, Michael

2003-03-10T23:59:59.000Z

74

Hydrogen storage gets new hope  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen storage gets new hope Hydrogen storage gets new hope Hydrogen storage gets new hope A new method for "recycling" hydrogen-containing fuel materials could open the door to economically viable hydrogen-based vehicles. September 1, 2009 Los Alamos National Laboratory sits on top of a once-remote mesa in northern New Mexico with the Jemez mountains as a backdrop to research and innovation covering multi-disciplines from bioscience, sustainable energy sources, to plasma physics and new materials. Los Alamos National Laboratory sits on top of a once-remote mesa in northern New Mexico with the Jemez mountains as a backdrop to research and innovation covering multi-disciplines from bioscience, sustainable energy sources, to plasma physics and new materials. Contact James E. Rickman

75

Hydrogen Storage Technologies Roadmap, November 2005  

Fuel Cell Technologies Publication and Product Library (EERE)

Document describing plan for research into and development of hydrogen storage technology for transportation applications.

76

Layered Graphene Sheets Could Solve Hydrogen Storage ...  

Science Conference Proceedings (OSTI)

Layered Graphene Sheets Could Solve Hydrogen Storage Issues. For Immediate Release: March 16, 2010. ...

2011-11-28T23:59:59.000Z

77

DOE Hydrogen and Fuel Cells Program: 2007 Annual Progress Report - Delivery  

NLE Websites -- All DOE Office Websites (Extended Search)

Delivery Delivery Printable Version 2007 Annual Progress Report III. Delivery This section of the 2007 Progress Report for the DOE Hydrogen Program focuses on delivery. Each technical report is available as an individual Adobe Acrobat PDF. Download Adobe Reader. Hydrogen Delivery Sub-Program Overview, Mark Paster, U.S. Department of Energy (PDF 182 KB) A. Analysis Hydrogen Delivery Infrastructure Options Analysis, Tan-Ping Chen, Nexant, Inc. (PDF 620 KB) B. Liquefaction Innovative Hydrogen Liquefaction Cycle, Martin A. Shimko, Gas Equipment Engineering Corp. (PDF 514 KB) C. Carriers Reversible Liquid Carriers for an Integrated Production, Storage and Delivery of Hydrogen, Guido P. Pez, Air Products & Chemicals, Inc. (PDF 528 KB) D. Storage Inexpensive Delivery of Compressed Hydrogen with Advanced Vessel

78

Hydrogen Storage atHydrogen Storage at Lawrence Berkeley National LaboratoryLawrence Berkeley National Laboratory  

E-Print Network (OSTI)

Hydrogen Storage atHydrogen Storage at Lawrence Berkeley National LaboratoryLawrence Berkeley National Laboratory Presentation at thePresentation at the Hydrogen Storage Grand ChallengeHydrogen Storage expertise to hydrogen storage, fuel cells, and system integration issues ­Novel membranes and other

79

Technical Assessment: Cryo-Compressed Hydrogen Storage  

E-Print Network (OSTI)

Technical Assessment: Cryo-Compressed Hydrogen Storage for Vehicular Applications October 30, 2006* U.S. Department of Energy Hydrogen Program *Revised June, 2008 #12;Table of Contents Introduction .....................................................................................................................................................................8 APPENDIX A: Review of Cryo-Compressed Hydrogen Storage Systems

80

Fuel Cell Technologies Office: Hydrogen Storage  

NLE Websites -- All DOE Office Websites (Extended Search)

Current Technology DOE R&D Activities Quick Links Hydrogen Production Hydrogen Delivery Fuel Cells Technology Validation Manufacturing Codes & Standards Education Systems...

Note: This page contains sample records for the topic "delivery hydrogen storage" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

DOE Hydrogen and Fuel Cells Program: Hydrogen Delivery  

NLE Websites -- All DOE Office Websites (Extended Search)

refueling stations or stationary power facilities. Due to its relatively low volumetric energy density, transportation, storage and final delivery to the point of use can be one...

82

Improvements to Hydrogen Delivery Scenario Analysis Model (HDSAM) and Results  

NLE Websites -- All DOE Office Websites (Extended Search)

to Hydrogen to Hydrogen Delivery Scenario Analysis Model (HDSAM) and Results May 8, 2007 Amgad Elgowainy Argonne National Laboratory Comparison of Delivery Pathways- V1.0 vs. V2.0 2 1 3 i delivery by a Loading, the plant Version 1.0 character zed components for 3 pathways with single mode. conditioning and storage are at or adjacent to Liquid Hydrogen (LH) Truck H2 Production 100 or 1500 kg/d Compressed H2 (CH) Truck H2 Production 3 or 7 kpsi 100 or 1500 kg/d H2 Production Gaseous H2 Pipeline 100 or 1500 kg/d HDSAM V1.0 Estimates Delivery Cost for 3 Pathways 4 H2 H2 1 2 3 H2 Distribution and Ci I. Liquid H2 Distribution: HDSAM V2.0 Simulates Nine Pathways Production Production LH Terminal LH Terminal Production LH Terminal Transmission Transmission Distribution

83

Implementing a Hydrogen Energy Infrastructure: Storage Options and System Design  

E-Print Network (OSTI)

challenge. Hydrogen energy storage density has been steadilya Hydrogen Energy Infrastructure: Storage Options and Systema Hydrogen Energy Infrastructure: Storage Options and System

Ogden, J; Yang, Christopher

2005-01-01T23:59:59.000Z

84

Implementing a Hydrogen Energy Infrastructure: Storage Options and System Design  

E-Print Network (OSTI)

as a key challenge. Hydrogen energy storage density has beena Hydrogen Energy Infrastructure: Storage Options and Systema Hydrogen Energy Infrastructure: Storage Options and System

Ogden, J; Yang, Christopher

2005-01-01T23:59:59.000Z

85

NREL: Hydrogen and Fuel Cells Research - Hydrogen Storage  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen Storage Storing hydrogen for renewable energy technologies can be challenging, especially for intermittent resources such as solar and wind. Whether for stationary,...

86

High Capacity Hydrogen Storage Nanocomposite - Energy ...  

Energy Storage Advanced Materials High Capacity Hydrogen Storage Nanocomposite Processes to add metal hydrideds to nanocarbon structures to yield high capacity ...

87

Hydrogen Storage II - Programmaster.org  

Science Conference Proceedings (OSTI)

Aug 3, 2010 ... Symposium L: Energy Generation, Harvesting and Storage Materials: Hydrogen Storage II Program Organizers: Jian-Feng Nie, Monash...

88

NIST: Neutron Tomography of Hydrogen Storage Bed  

Science Conference Proceedings (OSTI)

... Future hydrogen fuel cell vehicles will require hydrogen storage vessels that ... will require understanding the coupled heat and mass transport system ...

2013-07-23T23:59:59.000Z

89

Status & Direction for Onboard Hydrogen Storage  

NLE Websites -- All DOE Office Websites (Extended Search)

Economy Manufacturing for the Hydrogen Economy Status & Direction for Onboard Hydrogen Storage Andy Abele Quantum Fuel Systems Technologies Worldwide, Inc. July 2005 This...

90

NIST Hydrogen Storage in Thin Films  

Science Conference Proceedings (OSTI)

Hydrogen Storage Optimization in Thin Film Combinatorial Alloys. ... Magnesium Thin Films," International Journal of Hydrogen Energy, doi:10.1016/j ...

2013-04-01T23:59:59.000Z

91

NIST: Neutron Imaging Facility - Hydrogen Storage  

Science Conference Proceedings (OSTI)

Hydrogen Storage. Ultimately if a fuel cell vehicle is to function efficiently it must have an efficient means of storing and delivering hydrogen. ...

92

NREL: Learning - Energy Delivery and Storage Basics  

NLE Websites -- All DOE Office Websites (Extended Search)

Energy Delivery and Storage Basics Helping secure a clean energy future for the nation and the world isn't just about reducing energy usage or producing clean energy. It is about...

93

Carbon Aerogels for Hydrogen Storage  

DOE Green Energy (OSTI)

This effort is focused on the design of new nanostructured carbon-based materials that meet the DOE 2010 targets for on-board vehicle hydrogen storage. Carbon aerogels (CAs) are a unique class of porous materials that possess a number of desirable structural features for the storage of hydrogen, including high surface areas (over 3000 m{sup 2}/g), continuous and tunable porosities, and variable densities. In addition, the flexibility associated with CA synthesis allows for the incorporation of modifiers or catalysts into the carbon matrix in order to alter hydrogen sorption enthalpies in these materials. Since the properties of the doped CAs can be systematically modified (i.e. amount/type of dopant, surface area, porosity), novel materials can be fabricated that exhibit enhanced hydrogen storage properties. We are using this approach to design new H{sub 2} sorbent materials that can storage appreciable amounts of hydrogen at room temperature through a process known as hydrogen spillover. The spillover process involves the dissociative chemisorption of molecular hydrogen on a supported metal catalyst surface (e.g. platinum or nickel), followed by the diffusion of atomic hydrogen onto the surface of the support material. Due to the enhanced interaction between atomic hydrogen and the carbon support, hydrogen can be stored in the support material at more reasonable operating temperatures. While the spillover process has been shown to increase the reversible hydrogen storage capacities at room temperature in metal-loaded carbon nanostructures, a number of issues still exist with this approach, including slow kinetics of H{sub 2} uptake and capacities ({approx} 1.2 wt% on carbon) below the DOE targets. The ability to tailor different structural aspects of the spillover system (i.e. the size/shape of the catalyst particle, the catalyst-support interface and the support morphology) should provide valuable mechanistic information regarding the critical aspects of the spillover process (i.e. kinetics of hydrogen dissociation, diffusion and recombination) and allow for optimization of these materials to meet the DOE targets for hydrogen storage. In a parallel effort, we are also designing CA materials as nanoporous scaffolds for metal hydride systems. Recent work by others has demonstrated that nanostructured metal hydrides show enhanced kinetics for reversible hydrogen storage relative to the bulk materials. This effect is diminished, however, after several hydriding/dehydriding cycles, as the material structure coarsens. Incorporation of the metal hydride into a porous scaffolding material can potentially limit coarsening and, therefore, preserve the enhanced kinetics and improved cycling behavior of the nanostructured metal hydride. Success implementation of this approach, however, requires the design of nanoporous solids with large accessible pore volumes (> 4 cm{sup 3}/g) to minimize the gravimetric and volumetric capacity penalties associated with the use of the scaffold. In addition, these scaffold materials should be capable of managing thermal changes associated with the cycling of the incorporated metal hydride. CAs are promising candidates for the design of such porous scaffolds due to the large pore volumes and tunable porosity of aerogel framework. This research is a joint effort with HRL Laboratories, a member of the DOE Metal Hydride Center of Excellence. LLNL's efforts have focused on the design of new CA materials that can meet the scaffolding requirements, while metal hydride incorporation into the scaffold and evaluation of the kinetics and cycling performance of these composites is performed at HRL.

Baumann, T F; Worsley, M; Satcher, J H

2008-08-11T23:59:59.000Z

94

NREL Advances Spillover Materials for Hydrogen Storage (Fact...  

NLE Websites -- All DOE Office Websites (Extended Search)

8 * December 2010 NREL Advances Spillover Materials for Hydrogen Storage Project: Hydrogen Sorption Center of Excellence - Hydrogen Sorption via Spillover Team: Hydrogen Storage...

95

DOE Hydrogen Analysis Repository: Hydrogen for Energy Storage  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen for Energy Storage Hydrogen for Energy Storage Project Summary Full Title: Cost and GHG Implications of Hydrogen for Energy Storage Project ID: 260 Principal Investigator: Darlene Steward Brief Description: The levelized cost of energy (LCOE) of the most promising and/or mature energy storage technologies was compared with the LCOE of several hydrogen energy storage configurations. In addition, the cost of using the hydrogen energy storage system to produce excess hydrogen was evaluated. The use of hydrogen energy storage in conjunction with an isolated wind power plant-and its effect on electricity curtailment, credit for avoided GHG emissions, and LCOE-was explored. Keywords: Energy storage; Hydrogen; Electricity Performer Principal Investigator: Darlene Steward

96

Cost Analysis of Hydrogen Storage Systems  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen Cost Analysis of Hydrogen Storage Systems Storage Systems TIAX LLC 15 Acorn Park Cambridge, MA 02140-2390 Tel. 617- 498-5000 Fax 617-498-7200 www.TIAXLLC.com Reference:...

97

Cryo-Hydrogen Storage Workshop Welcome  

NLE Websites -- All DOE Office Websites (Extended Search)

Cryo-Hydrogen Storage Workshop Ned T. Stetson Acting Hydrogen Storage Team Lead Fuel Cells Technologies Program U.S. Department of Energy February 15, 2011 Crystal Gateway Marriott...

98

Integrated Hydrogen Storage System Model  

NLE Websites -- All DOE Office Websites (Extended Search)

WSRC-TR-2007-00440, REVISION 0 WSRC-TR-2007-00440, REVISION 0 Keywords: Hydrogen Kinetics, Hydrogen Storage Vessel Metal Hydride Retention: Permanent Integrated Hydrogen Storage System Model Bruce J. Hardy November 16, 2007 Washington Savannah River Company Savannah River Site Aiken, SC 29808 Prepared for the U.S. Department of Energy Under Contract Number DEAC09-96-SR18500 DISCLAIMER This report was prepared for the United States Department of Energy under Contract No. DE-AC09-96SR18500 and is an account of work performed under that contract. Neither the United States Department of Energy, nor WSRC, nor any of their employees makes any warranty, expressed or implied, or assumes any legal liability or responsibility for accuracy, completeness, or usefulness, of any information,

99

Some Examples in Hydrogen Storage, Thermoelectrics and  

Science Conference Proceedings (OSTI)

Presentation Title, Computational Phase-stability Research and Education in Energy Materials: Some Examples in Hydrogen Storage, Thermoelectrics and...

100

Fuel Cells, Hydrogen Storage, Ferroelectrics, Wind Energy  

Science Conference Proceedings (OSTI)

Mar 15, 2012 ... Energy Nanomaterials: Fuel Cells, Hydrogen Storage, Ferroelectrics, Wind Energy Sponsored by: The Minerals, Metals and Materials Society,...

Note: This page contains sample records for the topic "delivery hydrogen storage" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Hydrogen Storage in Microporous Coordination Solids with ...  

Science Conference Proceedings (OSTI)

... Hydrogen Storage in Microporous Coordination Solids with Exposed Metal Sites. Jeffrey R. Long, Dept. of Chemistry, University ...

102

Hydrogen Storage in Wind Turbine Towers  

DOE Green Energy (OSTI)

Low-cost hydrogen storage is recognized as a cornerstone of a renewables-hydrogen economy. Modern utility-scale wind turbine towers are typically conical steel structures that, in addition to supporting the rotor, could be used to store hydrogen. This study has three objectives: (1) Identify the paramount considerations associated with using a wind turbine tower for hydrogen storage; (2)Propose and analyze a cost-effective design for a hydrogen-storing tower; and (3) Compare the cost of storage in hydrogen towers to the cost of storage in conventional pressure vessels. The paramount considerations associated with a hydrogen tower are corrosion (in the form of hydrogen embrittlement) and structural failure (through bursting or fatigue life degradation). Although hydrogen embrittlement (HE) requires more research, it does not appear to prohibit the use of turbine towers for hydrogen storage. Furthermore, the structural modifications required to store hydrogen in a tower are not cost prohibitive.

Kottenstette, R.; Cotrell, J.

2003-09-01T23:59:59.000Z

103

INTEGRATED HYDROGEN STORAGE SYSTEM MODEL  

DOE Green Energy (OSTI)

Hydrogen storage is recognized as a key technical hurdle that must be overcome for the realization of hydrogen powered vehicles. Metal hydrides and their doped variants have shown great promise as a storage material and significant advances have been made with this technology. In any practical storage system the rate of H2 uptake will be governed by all processes that affect the rate of mass transport through the bed and into the particles. These coupled processes include heat and mass transfer as well as chemical kinetics and equilibrium. However, with few exceptions, studies of metal hydrides have focused primarily on fundamental properties associated with hydrogen storage capacity and kinetics. A full understanding of the complex interplay of physical processes that occur during the charging and discharging of a practical storage system requires models that integrate the salient phenomena. For example, in the case of sodium alanate, the size of NaAlH4 crystals is on the order of 300nm and the size of polycrystalline particles may be approximately 10 times larger ({approx}3,000nm). For the bed volume to be as small as possible, it is necessary to densely pack the hydride particles. Even so, in packed beds composed of NaAlH{sub 4} particles alone, it has been observed that the void fraction is still approximately 50-60%. Because of the large void fraction and particle to particle thermal contact resistance, the thermal conductivity of the hydride is very low, on the order of 0.2 W/m-{sup o}C, Gross, Majzoub, Thomas and Sandrock [2002]. The chemical reaction for hydrogen loading is exothermic. Based on the data in Gross [2003], on the order of 10{sup 8}J of heat of is released for the uptake of 5 kg of H{sub 2}2 and complete conversion of NaH to NaAlH{sub 4}. Since the hydride reaction transitions from hydrogen loading to discharge at elevated temperatures, it is essential to control the temperature of the bed. However, the low thermal conductivity of the hydride makes it difficult to remove the heat of reaction, especially in the relatively short target refueling times, see Attachment 3. This document describes a detailed numerical model for general metal hydride beds that couples reaction kinetics with heat and mass transfer, for both hydriding and dehydriding of the bed. The detailed model is part of a comprehensive methodology for the design, evaluation and modification of hydrogen storage systems. In Hardy [2007], scoping models for reaction kinetics, bed geometry and heat removal parameters are discussed. The scoping models are used to perform a quick assessment of storage systems and identify those which have the potential to meet DOE performance targets. The operational characteristics of successful candidate systems are then evaluated with the more detailed models discussed in this document. The detailed analysis for hydrogen storage systems is modeled in either 2 or 3-dimensions, via the general purpose finite element solver COMSOL Multiphysics{reg_sign}. The two-dimensional model serves to provide rapid evaluation of bed configurations and physical processes, while the three-dimensional model, which requires a much longer run time, is used to investigate detailed effects that do not readily lend themselves to two-dimensional representations. The model is general and can be adapted to any geometry or storage media. In this document, the model is applied to a modified cylindrical shell and tube geometry with radial fins perpendicular to the axis, see Figures 4.1-1 and 4.1-2. Sodium alanate, NaAlH{sub 4}, is used as the hydrogen storage medium. The model can be run on any DOS, LINUX or Unix based system.

Hardy, B

2007-11-16T23:59:59.000Z

104

Hydrogen Delivery Technologies and Pipeline Transmission of Hydrogen  

E-Print Network (OSTI)

Hydrogen Delivery Technologies and Systems Pipeline Transmission of Hydrogen Strategic Initiatives, and Infrastructure Technologies Program #12;Pipeline Transmission of Hydrogen --- 2 Copyright: Design & Operation Standards Relevant Design and Operating Standards ANSI/ASME B31.8 49 CFR 192 CGA H2 Pipeline Standard (in

105

Hydrogen Delivery Liquefaction and Compression  

NLE Websites -- All DOE Office Websites (Extended Search)

to Praxair Hydrogen Liquefaction Hydrogen Compression 3 Praxair at a Glance The largest industrial gas company in North and South America Only U.S. Hydrogen Supplier in All Sizes...

106

Measurement Quality in Hydrogen Storage R&D  

Science Conference Proceedings (OSTI)

Measurement Quality in Hydrogen Storage R&D. Summary: No existing hydrogen storage material satisfies the Department ...

2012-10-01T23:59:59.000Z

107

Purchase, Delivery, and Storage of Gases  

NLE Websites -- All DOE Office Websites (Extended Search)

Purchase, Delivery, and Storage of Gases Print Purchase, Delivery, and Storage of Gases Print ALS users should follow Berkeley Lab policy, as described below, for the purchase, delivery, storage, and use of all gases at the ALS. See Shipping and Receiving for information on any non-gas deliveries. Contacts: Gas purchase or delivery: ALS Receiving, 510-486-4494 Gas use and storage: Experiment Coordination, 510-486-7222, This e-mail address is being protected from spambots. You need JavaScript enabled to view it Gas Storage: Berkeley Lab Chemical Inventory All gas bottles and cylinders at the ALS must be identified with bar code and logged into the Berkeley Lab Chemical Inventory by ALS staff. The inventory will be updated periodically; for more information contact Experiment Coordination. Gases are stored either in the racks between buildings 6 and 7; toxic and corrosive gases are stored in Building 6, room 6C across the walkway from beamline 10.0.

108

Hydrogen Permeability and Integrity of Hydrogen Delivery Pipelines  

NLE Websites -- All DOE Office Websites (Extended Search)

Permeability and Permeability and Integrity of Hydrogen Delivery Pipelines Z. Feng*, L.M. Anovitz*, J.G. Blencoe*, S. Babu*, and P. S. Korinko** * Oak Ridge National Laboratory * Savannah River National Laboratory August 30, 2005 2 OAK RIDGE NATIONAL LABORATORY U. S. DEPARTMENT OF ENERGY Partners and Collaborators * Oak Ridge National Laboratory - Project lead * Savannah River National Laboratory - Low H 2 pressure permeation test * Edison Welding Institute - Pipeline materials * Lincoln Electric Company - Welding electrode and weld materials for pipelines * Trans Canada - Commercial welding of pipelines and industry expectations * DOE Pipeline Working Group and Tech Team activities - FRP Hydrogen Pipelines - Materials Solutions for Hydrogen Delivery in Pipelines - Natural Gas Pipelines for Hydrogen Use

109

Hydrogen Production and Delivery Research  

DOE Green Energy (OSTI)

In response to DOE's Solicitation for Grant Applications DE-PS36-03GO93007, 'Hydrogen Production and Delivery Research', SRI International (SRI) proposed to conduct work under Technical Topic Area 5, Advanced Electrolysis Systems; Sub-Topic 5B, High-Temperature Steam Electrolysis. We proposed to develop a prototype of a modular industrial system for low-cost generation of H{sub 2} (<$2/kg) by steam electrolysis with anodic depolarization by CO. Water will be decomposed electrochemically into H{sub 2} and O{sub 2} on the cathode side of a high-temperature electrolyzer. Oxygen ions will migrate through an oxygen-ion-conductive solid oxide electrolyte. Gas mixtures on the cathode side (H{sub 2} + H{sub 2}O) and on the anode side (CO + CO{sub 2}) will be reliably separated by the solid electrolyte. Depolarization of the anodic process will decrease the electrolysis voltage, and thus the electricity required for H{sub 2} generation and the cost of produced H{sub 2}. The process is expected to be at least 10 times more energy-efficient than low-temperature electrolysis and will generate H{sub 2} at a cost of approximately $1-$1.5/kg. The operating economics of the system can be made even more attractive by deploying it at locations where waste heat is available; using waste heat would reduce the electricity required for heating the system. Two critical targets must be achieved: an H{sub 2} production cost below $2/kg, and scalable design of the pilot H{sub 2} generation system. The project deliverables would be (1) a pilot electrolysis system for H{sub 2} generation, (2) an economic analysis, (3) a market analysis, and (4) recommendations and technical documentation for field deployment. DOE was able to provide only 200K out of 1.8M (or about 10% of awarded budget), so project was stopped abruptly.

Iouri Balachov, PhD

2007-10-15T23:59:59.000Z

110

Fuel Cell Technologies Office: Hydrogen Delivery and Fueling (Text  

NLE Websites -- All DOE Office Websites (Extended Search)

Delivery and Delivery and Fueling (Text Alternative Version) to someone by E-mail Share Fuel Cell Technologies Office: Hydrogen Delivery and Fueling (Text Alternative Version) on Facebook Tweet about Fuel Cell Technologies Office: Hydrogen Delivery and Fueling (Text Alternative Version) on Twitter Bookmark Fuel Cell Technologies Office: Hydrogen Delivery and Fueling (Text Alternative Version) on Google Bookmark Fuel Cell Technologies Office: Hydrogen Delivery and Fueling (Text Alternative Version) on Delicious Rank Fuel Cell Technologies Office: Hydrogen Delivery and Fueling (Text Alternative Version) on Digg Find More places to share Fuel Cell Technologies Office: Hydrogen Delivery and Fueling (Text Alternative Version) on AddThis.com... Publications Program Publications

111

Analyses of Hydrogen Storage Materials and On-Board Systems  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen Analyses of Hydrogen Hydrogen Analyses of Hydrogen Storage Materials and On Storage Materials and On - - Board Systems Board Systems TIAX LLC 15 Acorn Park Cambridge, MA 02140-2390 Tel. 617- 498-6108 Fax 617-498-7054 www.TIAXLLC.com Reference: D0268 © 2007 TIAX LLC Hydrogen Delivery Analysis Meeting May 8, 2007 Stephen Lasher Kurtis McKenney Yong Yang Bob Rancatore Stefan Unnasch Matt Hooks This presentation does not contain any proprietary or confidential information Overview 1 SL/042007/D0268 ST32_Lasher_H2 Storage_v1.ppt Start date: June 2004 End date: Sept 2009 41% Complete Timeline Barriers addressed B. Cost C. Efficiency K. System Life Cycle Assessments Barriers Total project funding DOE share = $1.5M No cost share FY06 = $275k FY07 = $300k (plan) Budget Argonne and other National

112

Catalyzed alanates for hydrogen storage  

DOE Green Energy (OSTI)

The discovery that hydrogen can be reversibly absorbed and desorbed from complex hydrides (the alanates) by the addition of catalysts has created an entirely new prospect for lightweight hydrogen storage. Unlike the interstitial intermetallic hydrides, these compounds release hydrogen through a series of decomposition/recombination reactions e.g.: NaAlH{sub 4} {Leftrightarrow} 1/3Na{sub 3}AlH{sub 6} + 2/3Al + H{sub 2} {Leftrightarrow} NaH + Al + 3/2H{sub 2}. Initial work resulted in improved catalysts, advanced methods of preparation and a better understanding of the hydrogen absorption and desorption processes. Recent studies have clarified some of the fundamental material properties as well as the engineering characteristics of catalyst enhanced sodium alanate. Phase transitions observed real-time through in situ X-ray powder diffraction demonstrate that the decomposition reactions occur through long-range transport of metal species. SEM imaging and EDS analysis verify aluminum segregation to the surface of the material during decomposition. The equilibrium thermodynamics of decomposition have now been measured down to room temperature. They show a plateau pressure for the first reaction of 1 atm at 33 C, which suggest that, thermodynamically, this material is ideally suited to onboard hydrogen storage for fuel cell vehicles. Room temperature desorption with slow but measurable kinetics has been recorded for the first time. Studies at elevated temperatures (125-165 C), approaching that found in fuel cell operations, were performed on a scaled-up test bed. The bed demonstrated surprisingly good kinetics and other positive material properties. However, these studies also pointed to the need to develop new non-alkoxide based catalysts and doping methods to increase capacity and reduce the level of hydrocarbon impurities found in the desorbed hydrogen. For this reason, new Ti-Cl catalysts and doping processes are being developed which show higher capacities and improved kinetics. An overview of the current state-of-the-art will be presented along with our own studies and the implications for the viability of these materials in on-board hydrogen storage applications.

K. J. Gross; G. J. Thomas; C. Jensen

2000-11-01T23:59:59.000Z

113

Hydrogen-based electrochemical energy storage  

DOE Patents (OSTI)

An energy storage device (100) providing high storage densities via hydrogen storage. The device (100) includes a counter electrode (110), a storage electrode (130), and an ion conducting membrane (120) positioned between the counter electrode (110) and the storage electrode (130). The counter electrode (110) is formed of one or more materials with an affinity for hydrogen and includes an exchange matrix for elements/materials selected from the non-noble materials that have an affinity for hydrogen. The storage electrode (130) is loaded with hydrogen such as atomic or mono-hydrogen that is adsorbed by a hydrogen storage material such that the hydrogen (132, 134) may be stored with low chemical bonding. The hydrogen storage material is typically formed of a lightweight material such as carbon or boron with a network of passage-ways or intercalants for storing and conducting mono-hydrogen, protons, or the like. The hydrogen storage material may store at least ten percent by weight hydrogen (132, 134) at ambient temperature and pressure.

Simpson, Lin Jay

2013-08-06T23:59:59.000Z

114

Hydrogen Delivery Analysis Plus Meeting  

E-Print Network (OSTI)

Advanced Distinct ConventionalConventionalConventional Gasification Coal Gasif w/CO2 SeqCoal Gasification w/CO2 SequestrationGasification #12;Note: All cases include assessment of current, mid-term, and long · Estimates the cost of H2 delivery ($/kg) · Assumes 2005 delivery technologies · We can insert our Research

115

Hydrogen Storage Sub-Program Overview - DOE Hydrogen and Fuel...  

NLE Websites -- All DOE Office Websites (Extended Search)

FY 2012 Annual Progress Report DOE Hydrogen and Fuel Cells Program IntroductIon The Hydrogen Storage sub-program supports research and development (R&D) of materials and...

116

Materials for Hydrogen Production, Separation, and Storage  

Science Conference Proceedings (OSTI)

Mar 13, 2012 ... Materials in Clean Power Systems VII: Clean Coal-, Hydrogen ... and Fuel Cells: Materials for Hydrogen Production, Separation, and Storage .... Mixed Conducting Molten Salt Electrolyte for Na/NiCl2 Cell: Tannaz Javadi1;...

117

NETL: Hydrogen & Clean Fuels - Abstract : Hydrogen Storage on...  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen Storage on Carbon Nanotubes Single-walled carbon nanotubes are remarkable forms of elemental carbon. Their unique properties have stimulated the imaginations of many...

118

Activated Aluminum Hydride Hydrogen Storage Compositions ...  

Aluminum hydride is the best known alane and has been known for over 60 years. It is potentially a very attractive medium for onboard automotive hydrogen storage ...

119

Activated aluminum hydride hydrogen storage compositions and ...  

In one aspect, the invention relates to activated aluminum hydride hydrogen storage compositions containing aluminum hydride in the presence of, or absence of ...

120

Summary of DOE Hydrogen Storage Workshop  

NLE Websites -- All DOE Office Websites (Extended Search)

DOE Hydrogen Storage Workshop Argonne National Laboratory August 14-15, 2002 About one hundred representatives from DOE, the national laboratories, industry and universities...

Note: This page contains sample records for the topic "delivery hydrogen storage" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Fuel Cell Technologies Office: Hydrogen Compression, Storage...  

NLE Websites -- All DOE Office Websites (Extended Search)

of Energy's (DOE's) Argonne National Laboratory (ANL) held a Hydrogen Compression, Storage, and Dispensing Cost Reduction Workshop on March 20-21, 2013, in Argonne, Illinois....

122

Nanocomposite for High Capacity Hydrogen Storage  

Researchers at Berkeley Lab have designed a new composite material for hydrogen storage. The nanocomposite materials rapidly absorbs and releases hydr ...

123

Hydrogen storage composition and method  

DOE Patents (OSTI)

A hydrogen storage composition based on a metal hydride dispersed in an aerogel prepared by a sol-gel process. The starting material for the aerogel is an organometallic compound, including the alkoxysilanes, organometals of the form M(OR){sub X} where R is an organic ligand of the form C{sub n}H{sub 2n+1}, and organometals of the form MO{sub x}Ry where R is an alkyl group, where M is an oxide-forming metal, n, x and y are integers and y is two less than the valence of M. A sol is prepared by combining the starting material, alcohol, water, and an acid. The sol is conditioned to the proper viscosity and a hydride in the form of a fine powder is added. The mixture is polymerized and dried under supercritical conditions. The final product is a composition having a hydride uniformly dispersed throughout an inert, stable and highly porous matrix. It is capable of absorbing up to 30 motes of hydrogen per kilogram at room temperature and pressure, rapidly and reversibly. Hydrogen absorbed by the composition can be readily be recovered by heat or evacuation.

Wicks, G.G.; Heung, L.K.

1994-01-01T23:59:59.000Z

124

24/07/20031 Hydrogen Storage  

E-Print Network (OSTI)

24/07/20031 Slide no. Hydrogen Storage with Emphasis on Metal Hydrides Allan Schrøder Pedersen. A need for energy storage may be foreseen if we will not rely on fossils · Buffer between consumption and production · Transport · Hydrogen may well be such an intermediate energy carrier #12;24/07/20037 Slide no

125

Examination of Terminal Land Requirements for Hydrogen Delivery  

NLE Websites -- All DOE Office Websites (Extended Search)

May 8, 2007 Jerry Gillette Examination of Terminal Land Requirements for Hydrogen Hydrogen Delivery Analysis Meeting Argonne National Laboratory A Variety of Terminal...

126

DOE Hydrogen Analysis Repository: H2 Delivery Infrastructure...  

NLE Websites -- All DOE Office Websites (Extended Search)

carriers. Keywords: Hydrogen delivery; Hydrogen infrastructure; tube trailers; pipelines Purpose This project will conduct an in-depth comparative analysis of the various...

127

DOE Hydrogen Analysis Repository: Hydrogen Storage Systems Cost Analysis  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen Storage Systems Cost Analysis Hydrogen Storage Systems Cost Analysis Project Summary Full Title: Cost Analysis of Hydrogen Storage Systems Project ID: 207 Principal Investigator: Stephen Lasher Keywords: Hydrogen storage; costs Purpose The purpose of this analysis is to help guide researchers and developers toward promising R&D and commercialization pathways by evaluating the various on-board hydrogen storage technologies on a consistent basis. Performer Principal Investigator: Stephen Lasher Organization: TIAX, LLC Address: 15 Acorn Park Cambridge, MA 02140 Telephone: 617-498-6108 Email: lasher.stephen@tiaxllc.com Additional Performers: Matt Hooks, TIAX, LLC; Mark Marion, TIAX, LLC; Kurtis McKenney, TIAX, LLC; Bob Rancatore, TIAX, LLC; Yong Yang, TIAX, LLC Sponsor(s) Name: Sunita Satyapal

128

Hydrogen Delivery Technologies and Systems - Pipeline Transmission of Hydrogen  

NLE Websites -- All DOE Office Websites (Extended Search)

Technologies and Technologies and Systems Pipeline Transmission of Hydrogen Strategic Initiatives for Hydrogen Delivery Workshop May 7- 8, 2003 U.S. Department of Energy ■ Hydrogen, Fuel Cells, and Infrastructure Technologies Program Pipeline Transmission of Hydrogen --- 2 Copyright: Design & Operation Standards Relevant Design and Operating Standards ANSI/ASME B31.8 49 CFR 192 CGA H 2 Pipeline Standard (in development) Pipeline Transmission of Hydrogen --- 3 Copyright: Future H 2 Infrastructure Wind Powered Electrolytic Separation Local Reformers Users Stationary Power Sources Vehicle Fueling Stations Distance from Source to User (Miles) <500 0-5 <2,000 <50 Off-peak Hydroelectric Powered Electrolytic Separation Large Reformers (scale economies) Pipeline Transmission of Hydrogen

129

Fundamental Studies of Diffusion and Reactions in Hydrogen Storage Materials  

E-Print Network (OSTI)

energy production and use [1,2], but adequate hydrogen storageEnergy Fundamental studies of diffusion and reactions in hydrogen storageEnergy 010 "Fundamental studies of diffusion and reactions in hydrogen storage

Van de Walle, Chris G; Peles, Amra; Janotti, Anderson; Wilson-Short, Gareth

2008-01-01T23:59:59.000Z

130

Implementing a Hydrogen Energy Infrastructure: Storage Options and System Design  

E-Print Network (OSTI)

Natural Gas Based Hydrogen Infrastructure Optimizingof the 2005 National Hydrogen Association Meeting,the lowest-cost Hydrogen delivery mode , Manuscript

Ogden, Joan M; Yang, Christopher

2005-01-01T23:59:59.000Z

131

Combinatorial Approaches for Hydrogen Storage Materials (presentation)  

NLE Websites -- All DOE Office Websites (Extended Search)

approaches for approaches for hydrogen storage materials Leonid Bendersky Materials Science and Engineering Laboratory NIST, Gaithersburg MD Contributors: G. Downing, E. Mackey, R. Paul, R. Greenberg (NIST:CSTL); L. Cook, M. Green (NIST:MSEL) R. Cavicchi (NIST:CSTL); I. Takeuchi, H. Oguchi (UMd) Two Main Challenges to Combinatorial Analysis of Hydrogen Storage Materials Design and fabrication of appropriate materials libraries Rapid, quantitative measurements of hydrogenation

132

DOE Hydrogen Analysis Repository: H2A Delivery Components Model  

NLE Websites -- All DOE Office Websites (Extended Search)

Investigator: Matt Ringer Keywords: Hydrogen delivery; tube trailers; costs; pipelines Performer Principal Investigator: Matt Ringer Organization: National Renewable...

133

Hydrogen spillover: Its "diffusion" from catalysis to hydrogen storage community  

DOE Green Energy (OSTI)

Dissociative adsorption of hydrogen on catalyst sites followed by surface diffusion (spillover) to a carbon support was first reported for Pt-carbon catalysts (Robell, 1964) and was soon accepted as a valid step of numerous catalytic reactions. However, the concept of metal-assisted hydrogen storage (Schwarz, 1988) based on spillover entered much later the hydrogen community (Lueking and Yang, 2002) and is gaining recognition slowly as an alternate approach for enhancing hydrogen storage capacity of microporous materials for fuel-cell powered vehicles. This talk will analyze the significance and limits of the spillover mechanism for adsorptive storage of hydrogen, with examples of enhanced hydrogen uptake on Pd-containing activated carbon fibers. Evidence of the atomic nature of spilt-over hydrogen will be presented based on experimental results from inelastic neutron spectroscopy studies. Research sponsored by the Division of Materials Sciences and Engineering, U.S. Department of Energy under contract with UT-Battelle, LLC.

Contescu, Cristian I [ORNL; Bhat, Vinay V [ORNL; Gallego, Nidia C [ORNL

2009-01-01T23:59:59.000Z

134

Fuel Cell Technologies Office: Strategic Directions for Hydrogen...  

NLE Websites -- All DOE Office Websites (Extended Search)

Glossary Quick Links Hydrogen Production Hydrogen Delivery Hydrogen Storage Fuel Cells Technology Validation Manufacturing Codes & Standards Education Systems Analysis...

135

Hydrogen Production  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen Production DELIVERY FUEL CELLS STORAGE PRODUCTION TECHNOLOGY VALIDATION CODES & STANDARDS SYSTEMS INTEGRATION ANALYSES SAFETY EDUCATION RESEARCH & DEVELOPMENT Economy...

136

Hydrogen Storage Properties of a Nanostructured Palladium Alloy ...  

Science Conference Proceedings (OSTI)

Additionally, results on hydrogen storage capacity and hydrogen absorption kinetics will ... Birnessite MnO2 Nanoflakes for Efficient Energy Storage at Elevated...

137

Ca, Li and Mg Based Lightweight Intermetallics for Hydrogen Storage  

Science Conference Proceedings (OSTI)

... Nanoparticle Catalysts for Hydrogen Production from Methanol and Methane Ca, Li and Mg Based Lightweight Intermetallics for Hydrogen Storage.

138

Iron 'Veins' Are Secret of Promising New Hydrogen Storage ...  

Science Conference Proceedings (OSTI)

Iron 'Veins' Are Secret of Promising New Hydrogen Storage Material. ... International Journal of Hydrogen Energy, 36 (2011), pp. ...

2012-10-18T23:59:59.000Z

139

Fuel Cell Technologies Office: Strategic Directions for Hydrogen Delivery  

NLE Websites -- All DOE Office Websites (Extended Search)

Strategic Directions for Hydrogen Delivery Workshop Strategic Directions for Hydrogen Delivery Workshop The U.S. Department of Energy sponsored a Hydrogen Delivery Workshop in Washington, DC, May 7-8, 2003. Attendees included researchers, government officials, and industry members. A key element of the overall hydrogen energy infrastructure is the delivery system that moves the hydrogen from its point of production to an end-use device. The DOE's Fuel Cell Technologies Office will initiate, in fiscal year 2004, a research program targeted specifically at addressing hydrogen transportation and delivery. This special workshop was held to outline the future technology and research needs for developing cost-effective, reliable, and safe hydrogen delivery systems. The proceedings of the Hydrogen Delivery Workshop, which include the presentations and the recommendations of the four breakout groups, are available as Adobe Acrobat PDFs. Download Adobe Reader.

140

Designing Microporus Carbons for Hydrogen Storage Systems  

DOE Green Energy (OSTI)

An efficient, cost-effective hydrogen storage system is a key enabling technology for the widespread introduction of hydrogen fuel cells to the domestic marketplace. Air Products, an industry leader in hydrogen energy products and systems, recognized this need and responded to the DOE 'Grand Challenge' solicitation (DOE Solicitation DE-PS36-03GO93013) under Category 1 as an industry partner and steering committee member with the National Renewable Energy Laboratory (NREL) in their proposal for a center-of-excellence on Carbon-Based Hydrogen Storage Materials. This center was later renamed the Hydrogen Sorption Center of Excellence (HSCoE). Our proposal, entitled 'Designing Microporous Carbons for Hydrogen Storage Systems,' envisioned a highly synergistic 5-year program with NREL and other national laboratory and university partners.

Alan C. Cooper

2012-05-02T23:59:59.000Z

Note: This page contains sample records for the topic "delivery hydrogen storage" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Final Report - Hydrogen Delivery Infrastructure Options Analysis  

NLE Websites -- All DOE Office Websites (Extended Search)

The Power of Experience The Power of Experience Final Report Hydrogen Delivery Infrastructure Options Analysis DOE Award Number: DE-FG36-05GO15032 Project director/principal investigator: Tan-Ping Chen Consortium/teaming Partners: Air Liquide, Chevron Technology Venture, Gas Technology Institute, NREL, Tiax, ANL Hydrogen Delivery Infrastructure Options Analysis ii TABLE OF CONTENTS SECTION 1 EXECUTIVE SUMMARY ........................................................................... 1-1 1.1 HOW THE RESEARCH ADDS TO THE UNDERSTANDING OF THE AREA INVESTIGATED. 1-1 1.2 TECHNICAL EFFECTIVENESS AND ECONOMIC FEASIBILITY OF THE METHODS OR TECHNIQUES INVESTIGATED OR DEMONSTRATED .................................................... 1-1 1.3 HOW THE PROJECT IS OF BENEFIT TO THE PUBLIC..................................................... 1-1

142

Hydrogen energy for tomorrow: Advanced hydrogen transport and storage technologies  

DOE Green Energy (OSTI)

The future use of hydrogen to generate electricity, heat homes and businesses, and fuel vehicles will require the creation of a distribution infrastructure of safe, and cost-effective transport and storage. Present storage methods are too expensive and will not meet the performance requirements of future applications. Transport technologies will need to be developed based on the production and storage systems that come into use as the hydrogen energy economy evolves. Different applications will require the development of different types of storage technologies. Utility electricity generation and home and office use will have storage fixed in one location--stationary storage--and size and weight will be less important than energy efficiency and costs of the system. Fueling a vehicle, however, will require hydrogen storage in an ``on-board`` system--mobile storage--with weight and size similar to the gasoline tank in today`s vehicle. Researchers are working to develop physical and solid-state storage systems that will meet these diverse future application demands. Physical storage systems and solid-state storage methods (metal hydrides, gas-on-solids adsorption, and glass microspheres) are described.

NONE

1995-08-01T23:59:59.000Z

143

High Pressure Hydrogen Storage in Carbon Nanotubes - Energy ...  

Hydrogen storage for transportation is one of the most important problems faced in implementing a hydrogen economy. Hydrogen can be produced in many ...

144

High Pressure Hydrogen Storage in Carbon Nanotubes - Energy ...  

Hydrogen storage for transportation is one of the most important problems faced in implementing a hydrogen economy. Hydrogen can be produced in many ways, but ...

145

DOE Hydrogen and Fuel Cells Program Record 5037: Hydrogen Storage...  

NLE Websites -- All DOE Office Websites (Extended Search)

37 Date: May 22, 2006 Title: Hydrogen Storage Materials - 2004 vs 2006 Originator: Sunita Satyapal Approved by: JoAnn Milliken Date: May 22, 2006 Item: "Identified materials with...

146

Small Fuel Cell Systems with Hydrogen Storage  

NLE Websites -- All DOE Office Websites (Extended Search)

eere.energy.gov H 2 and FC Technologies Manufacturing R&D Workshop Renaissance Hotel, Washington, DC August 11-12, 2011 Small Fuel Cell Systems with Hydrogen Storage Ned T....

147

Stationary High-Pressure Hydrogen Storage  

NLE Websites -- All DOE Office Websites (Extended Search)

Stationary High-Pressure Hydrogen Storage Zhili Feng Oak Ridge National Laboratory 2 Managed by UT-Battelle for the U.S. Department of Energy Technology Gap Analysis for Bulk...

148

DOE Hydrogen Analysis Repository: Hydrogen Storage Systems Analysis  

NLE Websites -- All DOE Office Websites (Extended Search)

Storage Systems Analysis Storage Systems Analysis Project Summary Full Title: System Level Analysis of Hydrogen Storage Options Project ID: 202 Principal Investigator: Rajesh K. Ahluwalia Keywords: Hydrogen storage; compressed hydrogen tanks Purpose ANL is developing models to understand the characteristics of storage systems based on approaches with unique characteristics (thermal energy and temperature of charge and discharge, kinetics of the physical and chemical process steps involved) and to evaluate their potential to meet DOE targets for on-board applications. Performer Principal Investigator: Rajesh K. Ahluwalia Organization: Argonne National Laboratory (ANL) Address: 9700 S. Cass Ave. Argonne, IL 60439 Telephone: 630-252-5979 Email: walia@anl.gov Additional Performers: T.Q. Hua, Argonne National Laboratory; Romesh Kumar, Argonne National Laboratory; J-C Peng, Argonne National Laboratory

149

Porous polymeric materials for hydrogen storage  

DOE Patents (OSTI)

A porous polymer, poly-9,9'-spirobifluorene and its derivatives for storage of H.sub.2 are prepared through a chemical synthesis method. The porous polymers have high specific surface area and narrow pore size distribution. Hydrogen uptake measurements conducted for these polymers determined a higher hydrogen storage capacity at the ambient temperature over that of the benchmark materials. The method of preparing such polymers, includes oxidatively activating solids by CO.sub.2/steam oxidation and supercritical water treatment.

Yu, Luping; Liu, Di-Jia; Yuan, Shengwen; Yang, Junbing

2013-04-02T23:59:59.000Z

150

Systems and methods for facilitating hydrogen storage using ...  

Systems and methods for facilitating hydrogen storage using naturally occurring nanostructure assemblies United States Patent

151

Hydrogen Storage DOI: 10.1002/anie.200801163  

E-Print Network (OSTI)

dissociation energy · hydrogen storage · metal­ H2 binding · metal­ organic frameworks · microporous materialsHydrogen Storage DOI: 10.1002/anie.200801163 Hydrogen Storage in Microporous Metal endeavor. Many reports have dealt with the use of hydrogen as a fuel and its storage in different solid

152

Hydrogen/halogen energy storage system  

DOE Green Energy (OSTI)

The hydrogen/chlorine energy storage system has been considered at BNL for large scale energy storage. In FY1978 work included an assessment of system safety and cost, investigations of cell performance under conditions elevated pressure and temperature, determination of the transport properties of Nafion membranes and electrochemical engineering studies. Results are summarized.

Spaziante, P M; Sioli, G C; Trotta, R; Perego, A; McBreen, J

1978-01-01T23:59:59.000Z

153

Hydrogen fuel closer to reality because of storage advances  

E-Print Network (OSTI)

.S. Department of Energy's Chemical Hydrogen Storage Center of Excellence describe a significant advance- 1 - Hydrogen fuel closer to reality because of storage advances March 21, 2012 Drive toward hydrogen vehicles just got shorter A significant advance in hydrogen storage could make hydrogen a more

Kurien, Susan

154

Fuel Cell Technologies Office: Hydrogen Storage (Text Alternative Version)  

NLE Websites -- All DOE Office Websites (Extended Search)

Storage (Text Storage (Text Alternative Version) to someone by E-mail Share Fuel Cell Technologies Office: Hydrogen Storage (Text Alternative Version) on Facebook Tweet about Fuel Cell Technologies Office: Hydrogen Storage (Text Alternative Version) on Twitter Bookmark Fuel Cell Technologies Office: Hydrogen Storage (Text Alternative Version) on Google Bookmark Fuel Cell Technologies Office: Hydrogen Storage (Text Alternative Version) on Delicious Rank Fuel Cell Technologies Office: Hydrogen Storage (Text Alternative Version) on Digg Find More places to share Fuel Cell Technologies Office: Hydrogen Storage (Text Alternative Version) on AddThis.com... Publications Program Publications Technical Publications Educational Publications Newsletter Program Presentations Multimedia Conferences & Meetings

155

LIGHT-WEIGHT NANOCRYSTALLINE HYDROGEN STORAGE MATERIALS  

DOE Green Energy (OSTI)

During Phase I of this SBIR Program, Advanced Materials Corporation has addressed two key issues concerning hydrogen storage: 1. We have conducted preliminary studies on the effect of certain catalysts in modifying the hydrogen absorption characteristics of nanocrystalline magnesium. 2. We have also conducted proof-of-concept design and construction of a prototype instrument that would rapidly screen materials for hydrogen storage employing chemical combinatorial technique in combination with a Pressure-Composition Isotherm Measurement (PCI) instrument. 3. Preliminary results obtained in this study approach are described in this report.

S. G. Sankar; B. Zande; R.T. Obermyer; S. Simizu

2005-11-21T23:59:59.000Z

156

Prediction of Novel Hydrogen Storage Reactions  

NLE Websites -- All DOE Office Websites (Extended Search)

Kazutoshi Kazutoshi Miwa Computational Physics Lab. Toyota Central R&D Labs., Inc. Theory Focus Session on Hydrogen Storage Materials, 18 MAY 2006 Prediction of Novel Hydrogen Storage Reactions 0 40 80 120 160 200 0 5 10 15 20 mass%H kgH 2 NaBH 4 Li H MgH 2 MgCaH 3.7 Mg 2 FeH 6 (Ti,Cr,V)H 1.9 Mg 2 NiH 4 Zr(CrFe) 2 H 3.4 TiFeH 1.7 (Ti,Cr,V)H 1.1 LaNi 5 H 6 /m 3 Hydrogen storage alloys Complex hydrides LiBH 4 NaAlH 4 Mg(NH 2 ) 2 +4LiH 2003- NEDO project of "Development for Safe Utilization and Infrastructure of Hydrogen" LiNH 2 LiAlH 4 Hydrogen Storage Materials Target: 5.5 mass %, < 150℃ (2010), 9 mass % < 150 ℃ (2020) Lithium Borohydride, LiBH 4 Advantages ☆ light weight ☆ high capacity of hydrogen storage (14 mass %) Disadvantages ★ thermodynamically too stability (> 600 K) ★ poor reaction kinetics

157

Cryogenic Hydrogen Storage Systems Workshop Agenda  

NLE Websites -- All DOE Office Websites (Extended Search)

Tuesday, February 15, 2011 - Cryogenic Hydrogen Storage Systems Tuesday, February 15, 2011 - Cryogenic Hydrogen Storage Systems Purpose: Identify R&D needs and technical pathways associated with the continued development and validation of cryo-compressed and cryo-sorption hydrogen storage technologies, highlighting those aspects common to both technologies as well as identifying their unique requirements and issues that should be addressed. 8:30 Welcome/Introductions/Workshop objectives/Recap of previous day Ned Stetson, DOE 9:00 OEM Perspective on Cryogenic H 2 Storage (20 min presentation/20 min discussion) Tobias Brunner, BMW 9:40 Performance Comparison and Cost Review (20 min presentation/20 min discussion) Rajesh Ahluwalia, ANL 10:20 Break (10 minutes) 10:30 Expert Panel Discussion (Members will each have 15 minutes for presentations)

158

Hydrogen storage technology for metal hydrides  

DOE Green Energy (OSTI)

The advantages of using hydrogen as a secondary energy carrier are stated, and numerous factors pertinent to the technology of hydrogen storage via metal hydrides are briefly described. The technology is centered on iron-titanium hydride, FeTiH/sub x/, as the most practical choice for the safe and compact storage of hydrogen. Uses of hydride hydrogen as a fuel or energy carrier are given. The features of hydride reservoir designs are explained, and some performance data are given for two reservoirs constructed at BNL. Results of tests on the long-term behavior of FeTiH/sub x/ are presented along with information on pressure drop in a hydride bed. Two methods of accommodating hydride expansion are described. Other topics include: container materials selection, safety testing of FeTiH/sub x/, hydride materials development, storage systems work at BNL, the proposed Hydrogen-Halogen Energy Storage System, a proposed technique of storing hydrogen in hollow glass microspheres at very high pressure, and information on the commercial availability of materials and equipment for hydride hydrogen. Current development needs are included in the various sections.

Strickland, G

1978-06-01T23:59:59.000Z

159

Hydrogen Storage in Carbon Nanotubes  

NLE Websites -- All DOE Office Websites (Extended Search)

STORAGE IN CARBON NANOTUBES JOHN E. FISCHER UNIVERSITY OF PENNSYLVANIA * SOME BASIC NOTIONS * BINDING SITES AND ENERGIES * PROCESSING TO ENHANCE CAPACITY: EX: ELECTROCHEMICAL Li...

160

Standardized Testing Program for Solid-State Hydrogen Storage Technologies  

DOE Green Energy (OSTI)

In the US and abroad, major research and development initiatives toward establishing a hydrogen-based transportation infrastructure have been undertaken, encompassing key technological challenges in hydrogen production and delivery, fuel cells, and hydrogen storage. However, the principal obstacle to the implementation of a safe, low-pressure hydrogen fueling system for fuel-cell powered vehicles remains storage under conditions of near-ambient temperature and moderate pressure. The choices for viable hydrogen storage systems at the present time are limited to compressed gas storage tanks, cryogenic liquid hydrogen storage tanks, chemical hydrogen storage, and hydrogen absorbed or adsorbed in a solid-state material (a.k.a. solid-state storage). Solid-state hydrogen storage may offer overriding benefits in terms of storage capacity, kinetics and, most importantly, safety.The fervor among the research community to develop novel storage materials had, in many instances, the unfortunate consequence of making erroneous, if not wild, claims on the reported storage capacities achievable in such materials, to the extent that the potential viability of emerging materials was difficult to assess. This problem led to a widespread need to establish a capability to accurately and independently assess the storage behavior of a wide array of different classes of solid-state storage materials, employing qualified methods, thus allowing development efforts to focus on those materials that showed the most promise. However, standard guidelines, dedicated facilities, or certification programs specifically aimed at testing and assessing the performance, safety, and life cycle of these emergent materials had not been established. To address the stated need, the Testing Laboratory for Solid-State Hydrogen Storage Technologies was commissioned as a national-level focal point for evaluating new materials emerging from the designated Materials Centers of Excellence (MCoE) according to established and qualified standards. Working with industry, academia, and the U.S. government, SwRI set out to develop an accepted set of evaluation standards and analytical methodologies. Critical measurements of hydrogen sorption properties in the Laboratory have been based on three analytical capabilities: 1) a high-pressure Sievert-type volumetric analyzer, modified to improve low-temperature isothermal analyses of physisorption materials and permit in situ mass spectroscopic analysis of the samples gas space; 2) a static, high-pressure thermogravimetric analyzer employing an advanced magnetic suspension electro-balance, glove-box containment, and capillary interface for in situ mass spectroscopic analysis of the samples gas space; and 3) a Laser-induced Thermal Desorption Mass Spectrometer (LTDMS) system for high thermal-resolution desorption and mechanistic analyses. The Laboratory has played an important role in down-selecting materials and systems that have emerged from the MCoEs.

Miller, Michael A. [Southwest Research Institute; Page, Richard A. [Southwest Research Institute

2012-07-30T23:59:59.000Z

Note: This page contains sample records for the topic "delivery hydrogen storage" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Hydrogen Storage by Polylithiated Molecules and  

E-Print Network (OSTI)

We study polylithiated molecules as building blocks for hydrogen storage materials, using first-principles calculations. CLi4 and OLi2 bind 12 and 10 hydrogen molecules, respectively, with an average binding energy of 0.10 and 0.13 eV, leading to gravimetric densities of 37.8 and 40.3 weight % H. Bonding between Li and C or O is strongly polar and H2 molecules attach to the partially charged Li atoms without dissociating, which is favorable for (de)hydrogenation kinetics. CLin and OLim molecules can be chemically bonded to graphene sheets to hinder the aggregation of such molecules. In particular B or Be doped graphene strongly bind the molecules without seriously affecting the hydrogen binding energy. It still leads to a hydrogen storage capacity in the range 5-8.5 wt. % H.

Sleyman Er; Gilles A. De Wijs; Geert Brocks

2009-01-01T23:59:59.000Z

162

Materials Solutions for Hydrogen Delivery in Pipelines  

NLE Websites -- All DOE Office Websites (Extended Search)

Solutions for Solutions for Hydrogen Delivery in Pipelines Dr. Subodh K. Das Secat, Inc. September 26, 2007 This presentation does not contain any proprietary, confidential, or otherwise restricted information Project Team SECAT (KY) Project Manager Oregon Steel Mills (OR) Steel Pipe Producer Columbia Gas of Kentucky (KY) NG transporter Schott North America (PA) Glass coatings supplier Chemical Composite Coatings (GA) Composites coatings Advanced Technology Corp. (TN) ABI technology provider ASME (NY) Codes and Standards DGS Metallurgical Solutions (OR) Steel consulting University of Illinois (IL) Basic embrittlement studies Oak Ridge National Laboratory (TN) Applied research Objective and Deliverables Objective: ∑ Develop materials technologies to minimize embrittlement of

163

ALUMINUM HYDRIDE: A REVERSIBLE STORAGE MATERIAL FOR HYDROGEN STORAGE  

DOE Green Energy (OSTI)

One of the challenges of implementing the hydrogen economy is finding a suitable solid H{sub 2} storage material. Aluminium (alane, AlH{sub 3}) hydride has been examined as a potential hydrogen storage material because of its high weight capacity, low discharge temperature, and volumetric density. Recycling the dehydride material has however precluded AlH{sub 3} from being implemented due to the large pressures required (>10{sup 5} bar H{sub 2} at 25 C) and the thermodynamic expense of chemical synthesis. A reversible cycle to form alane electrochemically using NaAlH{sub 4} in THF been successfully demonstrated. Alane is isolated as the triethylamine (TEA) adduct and converted to unsolvated alane by heating under vacuum. To complete the cycle, the starting alanate can be regenerated by direct hydrogenation of the dehydrided alane and the alkali hydride (NaH) This novel reversible cycle opens the door for alane to fuel the hydrogen economy.

Zidan, R; Christopher Fewox, C; Brenda Garcia-Diaz, B; Joshua Gray, J

2009-01-09T23:59:59.000Z

164

DOE Hydrogen Analysis Repository: Emissions Analysis of Electricity Storage  

NLE Websites -- All DOE Office Websites (Extended Search)

Emissions Analysis of Electricity Storage with Hydrogen Emissions Analysis of Electricity Storage with Hydrogen Project Summary Full Title: Emissions Analysis of Electricity Storage with Hydrogen Project ID: 269 Principal Investigator: Amgad Elgowainy Brief Description: Argonne National Laboratory examined the potential fuel cycle energy and emissions benefits of integrating hydrogen storage with renewable power generation. ANL also examined the fuel cycle energy use and emissions associated with alternative energy storage systems, including pumped hydro storage (PHS), compressed air energy storage (CAES), and vanadium-redox batteries (VRB). Keywords: Hydrogen; Emissions; Greenhouse gases (GHG); Energy storage; Life cycle analysis Performer Principal Investigator: Amgad Elgowainy Organization: Argonne National Laboratory (ANL)

165

Rethinking hydrogen fueling insights from delivery modeling.  

SciTech Connect

Over the past century gasoline fueling has evolved from being performed by a variety of informal, diverse methods to being performed through the use of a standardized, highly automated system that exploits the fuel's benefits and mitigates its hazards. Any effort to transition to another fuel with different properties--with both advantages and disadvantages--must make similar adjustments. This paper discusses the existing gasoline refueling infrastructure and its evolution. It then describes the hydrogen delivery scenario analysis model, an Excel-based tool that calculates the levelized cost of delivering hydrogen from a central production facility to a vehicle by the use of currently available technologies and a typical profile of vehicle use and fueling demand. The results are shown for a status quo, or gasoline-centric case, in which demand reflects the current gasoline-based system and supply responds accordingly, and a hydrogen-centric case, in which some of those patterns are altered. The paper highlights fueling requirements that are particularly problematic for hydrogen and concludes with a discussion of alternative fueling paradigms.

Mintz, M.; Elgowainy, A.; Gardiner, M.; Energy Systems; U. S. DOE

2009-01-01T23:59:59.000Z

166

Hydrogen storage on activated carbon. Final report  

DOE Green Energy (OSTI)

The project studied factors that influence the ability of carbon to store hydrogen and developed techniques to enhance that ability in naturally occurring and factory-produced commercial carbon materials. During testing of enhanced materials, levels of hydrogen storage were achieved that compare well with conventional forms of energy storage, including lead-acid batteries, gasoline, and diesel fuel. Using the best materials, an electric car with a modern fuel cell to convert the hydrogen directly to electricity would have a range of over 1,000 miles. This assumes that the total allowable weight of the fuel cell and carbon/hydrogen storage system is no greater than the present weight of batteries in an existing electric vehicle. By comparison, gasoline cars generally are limited to about a 450-mile range, and battery-electric cars to 40 to 60 miles. The project also developed a new class of carbon materials, based on polymers and other organic compounds, in which the best hydrogen-storing factors discovered earlier were {open_quotes}molecularly engineered{close_quotes} into the new materials. It is believed that these new molecularly engineered materials are likely to exceed the performance of the naturally occurring and manufactured carbons seen earlier with respect to hydrogen storage.

Schwarz, J.A. [Syracuse Univ., NY (United States). Dept. of Chemical Engineering and Materials Science

1994-11-01T23:59:59.000Z

167

Final Report: Metal Perhydrides for Hydrogen Storage  

DOE Green Energy (OSTI)

Hydrogen is a promising energy source for the future economy due to its environmental friendliness. One of the important obstacles for the utilization of hydrogen as a fuel source for applications such as fuel cells is the storage of hydrogen. In the infrastructure of the expected hydrogen economy, hydrogen storage is one of the key enabling technologies. Although hydrogen possesses the highest gravimetric energy content (142 KJ/g) of all fuels, its volumetric energy density (8 MJ/L) is very low. It is desired to increase the volumetric energy density of hydrogen in a system to satisfy various applications. Research on hydrogen storage has been pursed for many years. Various storage technologies, including liquefaction, compression, metal hydride, chemical hydride, and adsorption, have been examined. Liquefaction and high pressure compression are not desired due to concerns related to complicated devices, high energy cost and safety. Metal hydrides and chemical hydrides have high gravimetric and volumetric energy densities but encounter issues because high temperature is required for the release of hydrogen, due to the strong bonding of hydrogen in the compounds. Reversibility of hydrogen loading and unloading is another concern. Adsorption of hydrogen on high surface area sorbents such as activated carbon and organic metal frameworks does not have the reversibility problem. But on the other hand, the weak force (primarily the van der Waals force) between hydrogen and the sorbent yields a very small amount of adsorption capacity at ambient temperature. Significant storage capacity can only be achieved at low temperatures such as 77K. The use of liquid nitrogen in a hydrogen storage system is not practical. Perhydrides are proposed as novel hydrogen storage materials that may overcome barriers slowing advances to a hydrogen fuel economy. In conventional hydrides, e.g. metal hydrides, the number of hydrogen atoms equals the total valence of the metal ions. One LiH molecule contains one hydrogen atom because the valence of a Li ion is +1. One MgH2 molecule contains two hydrogen atoms because the valence of a Mg ion is +2. In metal perhydrides, a molecule could contain more hydrogen atoms than expected based on the metal valance, i.e. LiH1+n and MgH2+n (n is equal to or greater than 1). When n is sufficiently high, there will be plenty of hydrogen storage capacity to meet future requirements. The existence of hydrogen clusters, Hn+ (n = 5, 7, 9, 11, 13, 15) and transition metal ion-hydrogen clusters, M+(H2)n (n = 1-6), such as Sc(H2)n+, Co(H2)n+, etc., have assisted the development of this concept. Clusters are not stable species. However, their existence stimulates our approach on using electric charges to enhance the hydrogen adsorption in a hydrogen storage system in this study. The experimental and modeling work to verify it are reported here. Experimental work included the generation of cold hydrogen plasma through a microwave approach, synthesis of sorbent materials, design and construction of lab devices, and the determination of hydrogen adsorption capacities on various sorbent materials under various electric field potentials and various temperatures. The results consistently show that electric potential enhances the adsorption of hydrogen on sorbents. NiO, MgO, activated carbon, MOF, and MOF and platinum coated activated carbon are some of the materials studied. Enhancements up to a few hundred percents have been found. In general, the enhancement increases with the electrical potential, the pressure applied, and the temperature lowered. Theoretical modeling of the hydrogen adsorption on the sorbents under the electric potential has been investigated with the density functional theory (DFT) approach. It was found that the interaction energy between hydrogen and sorbent is increased remarkably when an electric field is applied. This increase of binding energy offers a potential solution for DOE when looking for a compromise between chemisorption and physisorption for hydrogen storage. Bonding of chemisorption is too

Hwang, J-Y.; Shi, S.; Hackney, S.; Swenson, D.; Hu, Y.

2011-07-26T23:59:59.000Z

168

Porous polymeric materials for hydrogen storage  

SciTech Connect

Porous polymers, tribenzohexazatriphenylene, poly-9,9'-spirobifluorene, poly-tetraphenyl methane and their derivatives for storage of H.sub.2 prepared through a chemical synthesis method. The porous polymers have high specific surface area and narrow pore size distribution. Hydrogen uptake measurements conducted for these polymers determined a higher hydrogen storage capacity at the ambient temperature over that of the benchmark materials. The method of preparing such polymers, includes oxidatively activating solids by CO.sub.2/steam oxidation and supercritical water treatment.

Yu, Luping (Hoffman Estates, IL); Liu, Di-Jia (Naperville, IL); Yuan, Shengwen (Chicago, IL); Yang, Junbing (Westmont, IL)

2011-12-13T23:59:59.000Z

169

Porous polymeric materials for hydrogen storage  

DOE Patents (OSTI)

Porous polymers, tribenzohexazatriphenylene, poly-9,9'-spirobifluorene, poly-tetraphenyl methane and their derivatives for storage of H.sub.2 prepared through a chemical synthesis method. The porous polymers have high specific surface area and narrow pore size distribution. Hydrogen uptake measurements conducted for these polymers determined a higher hydrogen storage capacity at the ambient temperature over that of the benchmark materials. The method of preparing such polymers, includes oxidatively activating solids by CO.sub.2/steam oxidation and supercritical water treatment.

Yu, Luping (Hoffman Estates, IL); Liu, Di-Jia (Naperville, IL); Yuan, Shengwen (Chicago, IL); Yang, Junbing (Westmont, IL)

2011-12-13T23:59:59.000Z

170

Activated aluminum hydride hydrogen storage compositions and uses thereof  

DOE Patents (OSTI)

In one aspect, the invention relates to activated aluminum hydride hydrogen storage compositions containing aluminum hydride in the presence of, or absence of, hydrogen desorption stimulants. The invention particularly relates to such compositions having one or more hydrogen desorption stimulants selected from metal hydrides and metal aluminum hydrides. In another aspect, the invention relates to methods for generating hydrogen from such hydrogen storage compositions.

Sandrock, Gary (Ringwood, NJ); Reilly, James (Bellport, NY); Graetz, Jason (Mastic, NY); Wegrzyn, James E. (Brookhaven, NY)

2010-11-23T23:59:59.000Z

171

news and views A key issue for hydrogen storage materi-  

E-Print Network (OSTI)

news and views A key issue for hydrogen storage materi- als is that the hydrogenation and dehydro be possible to discover stable hydrogen hydrates with higher storage Hydrogen Posture Plan www.eere.energy.gov/hydrogenandfuelcells/pdfs/ hydrogen_posture_plan.pdf 7. Kuhs, W

Palumbi, Stephen

172

Hydrogen Storage Options: Technologies and Comparisons for Light-Duty Vehicle Applications  

E-Print Network (OSTI)

Storage of Hydrogen in Microspheres, 15 th World Hydrogen Energyhydrogen in storage varies between the various energy storagethe energy storage characteristics of the various hydrogen

Burke, Andy; Gardiner, Monterey

2005-01-01T23:59:59.000Z

173

Hydrogen Electrochemical Energy Storage Device  

very high energy density of approximately 30,000 Watt-hour per kilogram (Wh/kg). Comparatively, state of the art Li-Ion batteries have energy densities of about 400 Wh/kg. While hydrogen fuel cells have been heavily investigated as an alternative ...

174

Hydrogen Storage property of sandwiched magnesium hydride naoparticle...  

NLE Websites -- All DOE Office Websites (Extended Search)

Storage property of sandwiched magnesium hydride naoparticle thin film Title Hydrogen Storage property of sandwiched magnesium hydride naoparticle thin film Publication Type...

175

Hydrogen and Fuel Cell Technologies Program: Storage Fact Sheet  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

FUEL CELL TECHNOLOGIES PROGRAM FUEL CELL TECHNOLOGIES PROGRAM Hydrogen and Fuel Cell Technologies Program: Storage Hydrogen Storage Developing safe, reliable, compact, and cost-effective hydrogen storage tech- nologies is one of the most technically challenging barriers to the widespread use of hydrogen as a form of energy. To be competitive with conventional vehicles, hydrogen-powered cars must be able to travel more than 300 mi between fills. This is a challenging goal because hydrogen has physical characteristics that make it difficult to store in large quantities without taking up a significant amount of space. Where and How Will Hydrogen be Stored? Hydrogen storage will be required

176

A High-Pressure Hydrogen Storage Design for Substation Applications  

Low-cost off-board bulk stationary storage of hydrogen is a critical part in the hydrogen infrastructure, ... recognized in the DOE Fuel Cell Technologies Program ...

177

Implementing a Hydrogen Energy Infrastructure: Storage Options and System Design  

E-Print Network (OSTI)

Gas Based Hydrogen Infrastructure Optimizing Transitionseconomies and lower infrastructure costs. REFERENCES 1. NRC,a Hydrogen Energy Infrastructure: Storage Options and System

Ogden, Joan M; Yang, Christopher

2005-01-01T23:59:59.000Z

178

Fuel Cell Technologies Office: Hydrogen Storage Workshop Proceedings  

NLE Websites -- All DOE Office Websites (Extended Search)

Proceedings to someone by E-mail Share Fuel Cell Technologies Office: Hydrogen Storage Workshop Proceedings on Facebook Tweet about Fuel Cell Technologies Office: Hydrogen...

179

High Througput Combinatorial Techniques in Hydrogen Storage Materials...  

NLE Websites -- All DOE Office Websites (Extended Search)

THROUGHPUTCOMBINATORIAL TECHNIQUES IN HYDROGEN STORAGE MATERIALS R&D WORKSHOP U.S. Department of Energy Office of Hydrogen, Fuel Cells and Infrastructure Technologies June 26,...

180

Modified borohydrides for reversible hydrogen storage  

DOE Green Energy (OSTI)

In attempt to develop lithium borohydrides as the reversible hydrogen storage materials with the high capacity, the feasibility to reduce dehydrogenation temperature of the lithium borohydride and moderate rehydrogenation condition has been explored. The commercial available lithium borohydride has been modified by ball milling with metal oxides and metal chlorides as the additives. The modified lithium borohydrides release 9 wt% hydrogen starting from 473K. The dehydrided modified lithium borohydrides absorb 7-9 wt% hydrogen at 873K and 7 MPa. The additive modification reduces dehydriding temperature from 673K to 473K and moderates rehydrogenation conditions to 923K and 15 MPa. XRD and SEM analysis discovered the formation of the intermediate compound TiB{sub 2} that may plays the key role in change the reaction path resulting the lower dehydriding temperature and reversibility. The reversible hydrogen storage capacity of the oxide modified lithium borohydrides decreases gradually during hydriding-dehydriding cycling due to the lost of the boron during dehydrogenation. But, it can be prevented by selecting the suitable additive, forming intermediate boron compounds and changing the reaction path. The additives reduce dehydriding temperature and improve the reversibility, it also reduces the hydrogen storage capacity. The best compromise can be reached by optimization of the additive loading and introducing new process other than ball milling.

Au, Ming

2005-08-29T23:59:59.000Z

Note: This page contains sample records for the topic "delivery hydrogen storage" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

NREL Advances Spillover Materials for Hydrogen Storage (Fact Sheet)  

DOE Green Energy (OSTI)

This fact sheet describes NREL's accomplishments in advancing spillover materials for hydrogen storage and improving the reproducible synthesis, long-term durability, and material costs of hydrogen storage materials. Work was performed by NREL's Chemical and Materials Science Center.

Not Available

2010-12-01T23:59:59.000Z

182

Modeling leaks from liquid hydrogen storage systems.  

DOE Green Energy (OSTI)

This report documents a series of models for describing intended and unintended discharges from liquid hydrogen storage systems. Typically these systems store hydrogen in the saturated state at approximately five to ten atmospheres. Some of models discussed here are equilibrium-based models that make use of the NIST thermodynamic models to specify the states of multiphase hydrogen and air-hydrogen mixtures. Two types of discharges are considered: slow leaks where hydrogen enters the ambient at atmospheric pressure and fast leaks where the hydrogen flow is usually choked and expands into the ambient through an underexpanded jet. In order to avoid the complexities of supersonic flow, a single Mach disk model is proposed for fast leaks that are choked. The velocity and state of hydrogen downstream of the Mach disk leads to a more tractable subsonic boundary condition. However, the hydrogen temperature exiting all leaks (fast or slow, from saturated liquid or saturated vapor) is approximately 20.4 K. At these temperatures, any entrained air would likely condense or even freeze leading to an air-hydrogen mixture that cannot be characterized by the REFPROP subroutines. For this reason a plug flow entrainment model is proposed to treat a short zone of initial entrainment and heating. The model predicts the quantity of entrained air required to bring the air-hydrogen mixture to a temperature of approximately 65 K at one atmosphere. At this temperature the mixture can be treated as a mixture of ideal gases and is much more amenable to modeling with Gaussian entrainment models and CFD codes. A Gaussian entrainment model is formulated to predict the trajectory and properties of a cold hydrogen jet leaking into ambient air. The model shows that similarity between two jets depends on the densimetric Froude number, density ratio and initial hydrogen concentration.

Winters, William Stanley, Jr.

2009-01-01T23:59:59.000Z

183

Hydrogen storage based on physisorption.  

DOE Green Energy (OSTI)

Physisorption of molecular hydrogen based on neutral and negatively charged aromatic molecular systems has been evaluated using ab initio calculations to estimate the binding energy, {Delta}H, and {Delta}G at 298 ({approx}77 bar) and 77 K (45 bar) in order to compare calculated results with experimental measurements of hydrogen adsorption. The molecular systems used in this study were corannulene (C{sub 20}H{sub 10}), dicyclopenta[def,jkl]triphenylene (C{sub 20}H{sub 10}), 5,8-dioxo-5,8-dihydroindeno[2,1-c]fluorene (C{sub 20}H{sub 10}O{sub 2}), 6-hexyl-5,8-dioxo-5,8-dihydroindeno[2,1-c]fluorene (C{sub 26}H{sub 22}O{sub 2}), coronene (C{sub 24}H{sub 12}), dilithium phthalocyanine (Li{sub 2}Pc, C{sub 32}H{sub 16}Li{sub 2}N{sub 8}), tetrabutylammonium lithium phthalocyanine (TBA-LiPc, C{sub 48}H{sub 52}LiN{sub 9}), and tetramethylammonium lithium phthalocyanine (TMA-LiPc, C{sub 36}H{sub 28}LiN{sub 9}). It was found (a) that the calculated term that corrects 0 K electronic energies to give Gibbs energies (thermal correction to Gibbs energy, TCGE) serves as a good approximation of the adsorbent binding energy required in order for a physisorption process to be thermodynamically allowed and (b) that the binding energy for neutral aromatic molecules varies as a function of curvature (e.g., corannulene versus coronene) or if electron-withdrawing or -donating groups are part of the adsorbent. A negatively charged aromatic ring, the lithium phthalocyanine complex anion, [LiPc]{sup -}, introduces charge-induced dipole interactions into the adsorption process, resulting in a doubling of the binding energy of Li{sub 2}Pc relative to corannulene. Experimental hydrogen adsorption results for Li{sub 2}Pc, which are consistent with MD simulation results using x-Li{sub 2}Pc to simulate the adsorbent, suggest that only one side of the phthalocyanine ring is used in the adsorption process. The introduction of a tetrabutylammonium cation as a replacement for one lithium ion in Li{sub 2}Pc has the effect of increasing the number of hydrogen molecules adsorbed from 10 (3.80 wt %) for Li{sub 2}Pc to 24 (5.93 wt %) at 77 K and 45 bar, suggesting that both sides of the phthalocyanine ring are available for hydrogen adsorption. MD simulations of layered tetramethylammonium lithium phthalocyanine molecular systems illustrate that doubling the wt % H{sub 2} adsorbed is possible via such a system. Ab initio calculations also suggest that layered or sandwich structures can result in significant reductions in the pressure required for hydrogen adsorption.

Scanlon, L. G.; Feld, W. A.; Balbuena, P. B.; Sandi, G.; Duan, F.; Underwood, K. A.; Hunter, N.; Mack, J.; Rottmayer, M. A.; Tsao, M; Chemical Sciences and Engineering Division; Wright-Patterson Air Force Base; Wright State Univ.; Texas A& M Univ.; Univ. of Cincinnati

2009-04-09T23:59:59.000Z

184

Li-Mg Solid Solution Alloy for Reversible Hydrogen Storage  

Science Conference Proceedings (OSTI)

Symposium, Hydrogen Storage in Materials: Theory and Experiment ... processes such as rapid solidification and high energy mechanical alloying. The results...

185

Instrumentation & control architecture applied for a hydrogen isotopes storage system  

Science Conference Proceedings (OSTI)

The properties of hydrogen storage used materials refers to their ability to high "connect" hydrogen, to have a large storage capacity, to be easily achievable and, if necessary, to allow its easy recovery. The metals and intermetallic compounds are ... Keywords: architecture, control system, hydrogen, isotopes, storage

Eusebiu Ilarian Ionete; Bogdan Monea

2011-09-01T23:59:59.000Z

186

Executive Summaries Hydrogen Storage Materials Centers of Excellence  

E-Print Network (OSTI)

of Energy April 2012 #12;2 #12;3 Primary Authors: Chemical Hydrogen Storage (CHSCoE): Kevin Ott, Los of the three Materials Centers of Excellence and the Department of Energy Hydrogen Storage Team in the Office hydrogen storage technologies that offer high specific energy and energy density at acceptable costs

187

Sustainable Energy Science and Engineering Center Hydrogen Storage  

E-Print Network (OSTI)

Sustainable Energy Science and Engineering Center Hydrogen Storage #12;Sustainable Energy Science 1990 2000 2010 2020 Hydrogen pellets Mg(NH3)6Cl2 Hydrogen Storage Source: Ian Edwards, ITI Energy, May. Portable applications including: computing, cell-phones and cameras (the 3 `C's'). Main Energy Storage

Krothapalli, Anjaneyulu

188

Development and Testing of Hydrogen Storage System(s)  

E-Print Network (OSTI)

Development and Testing of Hydrogen Storage System(s) for Capturing Intermittent Renewable Energy ­ Analysis of Test Results for Hydrogen Storage Systems By Hawaii Natural Energy Institute School of Ocean of Kahua Ranch Hydrogen Storage System 3 3.1 Kahua Ranch Power System 3 3.2 Electrolyzer Experimental

189

Hydrogen Storage in Metal-Organic Frameworks  

DOE Green Energy (OSTI)

Conventional storage of large amounts of hydrogen in its molecular form is difficult and expensive because it requires employing either extremely high pressure gas or very low temperature liquid. Because of the importance of hydrogen as a fuel, the DOE has set system targets for hydrogen storage of gravimetric (5.5 wt%) and volumetric (40 g L-1) densities to be achieved by 2015. Given that these are system goals, a practical material will need to have higher capacity when the weight of the tank and associated cooling or regeneration system is considered. The size and weight of these components will vary substantially depending on whether the material operates by a chemisorption or physisorption mechanism. In the latter case, metal-organic frameworks (MOFs) have recently been identified as promising adsorbents for hydrogen storage, although little data is available for their sorption behavior. This grant was focused on the study of MOFs with these specific objectives. (1) To examine the effects of functionalization, catenation, and variation of the metal oxide and organic linkers on the low-pressure hydrogen adsorption properties of MOFs. (2) To develop a strategy for producing MOFs with high surface area and porosity to reduce the dead space and increase the hydrogen storage capacity per unit volume. (3) To functionalize MOFs by post synthetic functionalization with metals to improve the adsorption enthalpy of hydrogen for the room temperature hydrogen storage. This effort demonstrated the importance of open metal sites to improve the adsorption enthalpy by the systematic study, and this is also the origin of the new strategy, which termed isoreticular functionalization and metalation. However, a large pore volume is still a prerequisite feature. Based on our principle to design highly porous MOFs, guest-free MOFs with ultrahigh porosity have been experimentally synthesized. MOF-210, whose BET surface area is 6240 m2 g-1 (the highest among porous solids), takes up 15 wt% of total H2 uptake at 80 bar and 77 K. More importantly, the total H2 uptake by MOF-210 was 2.7 wt% at 80 bar and 298 K, which is the highest number reported for physisorptive materials.

Omar M. Yaghi

2012-04-26T23:59:59.000Z

190

Hydrogen, Fuel Cells, and Infrastructure Technologies FY 2002 Progress Report Section III. Hydrogen Storage  

E-Print Network (OSTI)

. Hydrogen Storage #12;Hydrogen, Fuel Cells, and Infrastructure Technologies FY 2002 Progress Report 200 #12 square inch (psi) 7.5 wt % and 8.5 wt% Type IV composite hydrogen storage tanks of specified sizes for DOE Future Truck and Nevada hydrogen bus programs · Demonstrate 10,000 psi storage tanks Approach

191

Hydrogen Storage Systems Analysis Working Group Meeting 2007 Hydrogen Program Annual Review  

E-Print Network (OSTI)

they have initiated on solid state hydride tanks for hydrogen storage and other energy conversionHydrogen Storage Systems Analysis Working Group Meeting 2007 Hydrogen Program Annual Review Crystal Laboratory and Elvin Yuzugullu Sentech, Inc. June 28, 2007 #12;SUMMARY REPORT Hydrogen Storage

192

Hydrogen fuel closer to reality because of storage advances  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen fuel closer to reality because of storage advances Hydrogen fuel closer to reality because of storage advances Hydrogen fuel closer to reality because of storage advances Advances made in rechargeable solid hydrogen fuel storage tanks. March 21, 2012 Field experiments on the Alamosa Canyon How best to achieve the benchmark of 300 miles of travel without refueling? It may be to use the lightweight compound ammonia-borane to carry the hydrogen. With hydrogen accounting for almost 20 percent of its weight, this stable, non-flammable compound is one of the highest-capacity materials for storing hydrogen. In a car, the introduction of a chemical catalyst would release the hydrogen as needed, thus avoiding on-board storage of large quantities of flammable hydrogen gas. When the ammonia-borane fuel is depleted of hydrogen, it would be regenerated at a

193

Durability study of a vehicle-scale hydrogen storage system.  

DOE Green Energy (OSTI)

Sandia National Laboratories has developed a vehicle-scale demonstration hydrogen storage system as part of a Work for Others project funded by General Motors. This Demonstration System was developed based on the properties and characteristics of sodium alanates which are complex metal hydrides. The technology resulting from this program was developed to enable heat and mass management during refueling and hydrogen delivery to an automotive system. During this program the Demonstration System was subjected to repeated hydriding and dehydriding cycles to enable comparison of the vehicle-scale system performance to small-scale sample data. This paper describes the experimental results of life-cycle studies of the Demonstration System. Two of the four hydrogen storage modules of the Demonstration System were used for this study. A well-controlled and repeatable sorption cycle was defined for the repeated cycling, which began after the system had already been cycled forty-one times. After the first nine repeated cycles, a significant hydrogen storage capacity loss was observed. It was suspected that the sodium alanates had been affected either morphologically or by contamination. The mechanisms leading to this initial degradation were investigated and results indicated that water and/or air contamination of the hydrogen supply may have lead to oxidation of the hydride and possibly kinetic deactivation. Subsequent cycles showed continued capacity loss indicating that the mechanism of degradation was gradual and transport or kinetically limited. A materials analysis was then conducted using established methods including treatment with carbon dioxide to react with sodium oxides that may have formed. The module tubes were sectioned to examine chemical composition and morphology as a function of axial position. The results will be discussed.

Johnson, Terry Alan; Dedrick, Daniel E.; Behrens, Richard, Jr.

2010-11-01T23:59:59.000Z

194

Hydrogen Fuel Cells and Storage Technology: Fundamental Research for Optimization of Hydrogen Storage and Utilization  

SciTech Connect

Design and development of improved low-cost hydrogen fuel cell catalytic materials and high-capacity hydrogenn storage media are paramount to enabling the hydrogen economy. Presently, effective and durable catalysts are mostly precious metals in pure or alloyed form and their high cost inhibits fuel cell applications. Similarly, materials that meet on-board hydrogen storage targets within total mass and volumetric constraints are yet to be found. Both hydrogen storage performance and cost-effective fuel cell designs are intimately linked to the electronic structure, morphology and cost of the chosen materials. The FCAST Project combined theoretical and experimental studies of electronic structure, chemical bonding, and hydrogen adsorption/desorption characteristics of a number of different nanomaterials and metal clusters to develop better fundamental understanding of hydrogen storage in solid state matrices. Additional experimental studies quantified the hydrogen storage properties of synthesized polyaniline(PANI)/Pd composites. Such conducting polymers are especially interesting because of their high intrinsic electron density and the ability to dope the materials with protons, anions, and metal species. Earlier work produced contradictory results: one study reported 7% to 8% hydrogen uptake while a second study reported zero hydrogen uptake. Cost and durability of fuel cell systems are crucial factors in their affordability. Limits on operating temperature, loss of catalytic reactivity and degradation of proton exchange membranes are factors that affect system durability and contribute to operational costs. More cost effective fuel cell components were sought through studies of the physical and chemical nature of catalyst performance, characterization of oxidation and reduction processes on system surfaces. Additional development effort resulted in a new hydrocarbon-based high-performance sulfonated proton exchange membrane (PEM) that can be manufactured at low cost and accompanied by improved mechanical and thermal stability.

Perret, Bob; Heske, Clemens; Nadavalath, Balakrishnan; Cornelius, Andrew; Hatchett, David; Bae, Chusung; Pang, Tao; Kim, Eunja; Hemmers, Oliver

2011-03-28T23:59:59.000Z

195

Amineborane Based Chemical Hydrogen Storage - Final Report  

SciTech Connect

The development of efficient and safe methods for hydrogen storage is a major hurdle that must be overcome to enable the use of hydrogen as an alternative energy carrier. The objectives of this project in the DOE Center of Excellence in Chemical Hydride Storage were both to develop new methods for on-demand, low temperature hydrogen release from chemical hydrides and to design high-conversion off-board methods for chemical hydride regeneration. Because of their reactive protic (N-H) and hydridic (B-H) hydrogens and high hydrogen contents, amineboranes such as ammonia borane, NH3BH3 (AB), 19.6-wt% H2, and ammonia triborane NH3B3H7 (AT), 17.7-wt% H2, were initially identified by the Center as promising, high-capacity chemical hydrogen storage materials with the potential to store and deliver molecular hydrogen through dehydrogenation and hydrolysis reactions. In collaboration with other Center partners, the Penn project focused both on new methods to induce amineborane H2-release and on new strategies for the regeneration the amineborane spent-fuel materials. The Penn approach to improving amineborane H2-release focused on the use of ionic liquids, base additives and metal catalysts to activate AB dehydrogenation and these studies successfully demonstrated that in ionic liquids the AB induction period that had been observed in the solid-state was eliminated and both the rate and extent of AB H2-release were significantly increased. These results have clearly shown that, while improvements are still necessary, many of these systems have the potential to achieve DOE hydrogen-storage goals. The high extent of their H2-release, the tunability of both their H2 materials weight-percents and release rates, and their product control that is attained by either trapping or suppressing unwanted volatile side products, such as borazine, continue to make AB/ionic-liquid based systems attractive candidates for chemical hydrogen storage applications. These studies also demonstrated that H2-release from chemical hydrides can occur by a number of different mechanistic pathways and strongly suggest that optimal chemical hydride based H2release systems may require the use of synergistic dehydrogenation methods to induce H2-loss from chemically different intermediates formed during release reactions. The efficient regeneration of ammonia borane from BNHx spent fuel is one of the most challenging problems that will have to be overcome in order to utilize AB-based hydrogen storage. Three Center partners, LANL, PNNL and Penn, each took different complimentary approaches to AB regeneration. The Penn approach focused on a strategy involving spent-fuel digestion with superacidic acids to produce boron-halides (BX3) that could then be converted to AB by coordination/reduction/displacement processes. While the Penn boron-halide reduction studies successfully demonstrated that a dialkylsulfide-based coordination/reduction/displacement process gave quantitative conversions of BBr3 to ammonia borane with efficient and safe product separations, the fact that AB spent-fuels could not be digested in good yields to BX3 halides led to a No-Go decision on this overall AB-regeneration strategy.

Sneddon, Larry G.

2011-04-21T23:59:59.000Z

196

NREL Wind to Hydrogen Project: Renewable Hydrogen Production for Energy Storage & Transportation (Presentation)  

DOE Green Energy (OSTI)

Presentation about NREL's Wind to Hydrogen Project and producing renewable hydrogen for both energy storage and transporation, including the challenges, sustainable pathways, and analysis results.

Ramsden, T.; Harrison, K.; Steward, D.

2009-11-16T23:59:59.000Z

197

MODIFIED BOROHYDRIDES FOR REVERSIBLE HYDROGEN STORAGE  

DOE Green Energy (OSTI)

This paper reports the results in the effort to destabilize lithium borohydride for reversible hydrogen storage. A number of metals, metal hydrides, metal chlorides and complex hydrides were selected and evaluated as the destabilization agents for reducing dehydriding temperature and generating dehydriding-rehydriding reversibility. It is found that some additives are effective. The Raman spectroscopic analysis shows the change of B-H binding nature.

Au, Ming

2006-05-10T23:59:59.000Z

198

Theoretical Studies of Hydrogen Storage Alloys.  

DOE Green Energy (OSTI)

Theoretical calculations were carried out to search for lightweight alloys that can be used to reversibly store hydrogen in mobile applications, such as automobiles. Our primary focus was on magnesium based alloys. While MgH{sub 2} is in many respects a promising hydrogen storage material, there are two serious problems which need to be solved in order to make it useful: (i) the binding energy of the hydrogen atoms in the hydride is too large, causing the release temperature to be too high, and (ii) the diffusion of hydrogen through the hydride is so slow that loading of hydrogen into the metal takes much too long. In the first year of the project, we found that the addition of ca. 15% of aluminum decreases the binding energy to the hydrogen to the target value of 0.25 eV which corresponds to release of 1 bar hydrogen gas at 100 degrees C. Also, the addition of ca. 15% of transition metal atoms, such as Ti or V, reduces the formation energy of interstitial H-atoms making the diffusion of H-atoms through the hydride more than ten orders of magnitude faster at room temperature. In the second year of the project, several calculations of alloys of magnesium with various other transition metals were carried out and systematic trends in stability, hydrogen binding energy and diffusivity established. Some calculations of ternary alloys and their hydrides were also carried out, for example of Mg{sub 6}AlTiH{sub 16}. It was found that the binding energy reduction due to the addition of aluminum and increased diffusivity due to the addition of a transition metal are both effective at the same time. This material would in principle work well for hydrogen storage but it is, unfortunately, unstable with respect to phase separation. A search was made for a ternary alloy of this type where both the alloy and the corresponding hydride are stable. Promising results were obtained by including Zn in the alloy.

Jonsson, Hannes

2012-03-22T23:59:59.000Z

199

Toward new solid and liquid phase systems for the containment, transport and delivery of hydrogen  

NLE Websites -- All DOE Office Websites (Extended Search)

new solid and liquid phase systems new solid and liquid phase systems for the containment, transport and delivery of hydrogen By Guido P. Pez Hydrogen Energy Infrastructure for Fuel Cell Vehicle Transportation Scenario A: Distributed H 2 from a Large Scale Plant (150-230 tonne/day) Large Scale H 2 Plant (300-800 psi H 2 ) H 2 Buffer Storage Tube Trailer Liquid H 2 Truck H 2 Pipeline Multi-vehicle filling stations Feedstock: N. gas, Coal, Biomass Pet. Coke, Resids. Future: Carbon sequestration Storage: Underground well? Output: Depends on the vehicle's H 2 storage technology Currently H 2 up to >6000 psi for 5000 psi tanks Scenario B: Hydrogen by a small scale reforming of pipeline natural gas and compression Natural Gas Pipeline Reformer Liquid H 2 Backup Compressor H 2 (>6000 psig) H 2 Production: 100-400 kg/day; 4-5Kg H

200

Analysis of Cost-Effective Off-Board Hydrogen Storage and Refueling Stations  

DOE Green Energy (OSTI)

This report highlights design and component selection considerations for compressed gas hydrogen fueling stations operating at 5000 psig or 350 bar. The primary focus is on options for compression and storage in terms of practical equipment options as well as various system configurations and how they influence delivery performance and station economics.

Ted Barnes; William Liss

2008-11-14T23:59:59.000Z

Note: This page contains sample records for the topic "delivery hydrogen storage" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Microporous Metal Organic Materials for Hydrogen Storage  

DOE Green Energy (OSTI)

We have examined a number of Metal Organic Framework Materials for their potential in hydrogen storage applications. Results obtained in this study may, in general, be summarized as follows: (1) We have identified a new family of porous metal organic framework materials with the compositions M (bdc) (ted){sub 0.5}, {l_brace}M = Zn or Co, bdc = biphenyl dicarboxylate and ted = triethylene diamine{r_brace} that adsorb large quantities of hydrogen ({approx}4.6 wt%) at 77 K and a hydrogen pressure of 50 atm. The modeling performed on these materials agree reasonably well with the experimental results. (2) In some instances, such as in Y{sub 2}(sdba){sub 3}, even though the modeling predicted the possibility of hydrogen adsorption (although only small quantities, {approx}1.2 wt%, 77 K, 50 atm. hydrogen), our experiments indicate that the sample does not adsorb any hydrogen. This may be related to the fact that the pores are extremely small or may be attributed to the lack of proper activation process. (3) Some samples such as Zn (tbip) (tbip = 5-tert butyl isophthalate) exhibit hysteresis characteristics in hydrogen sorption between adsorption and desorption runs. Modeling studies on this sample show good agreement with the desorption behavior. It is necessary to conduct additional studies to fully understand this behavior. (4) Molecular simulations have demonstrated the need to enhance the solid-fluid potential of interaction in order to achieve much higher adsorption amounts at room temperature. We speculate that this may be accomplished through incorporation of light transition metals, such as titanium and scandium, into the metal organic framework materials.

S. G. Sankar; Jing Li; Karl Johnson

2008-11-30T23:59:59.000Z

202

Hydrogen Storage Options: Technologies and Comparisons for Light-Duty Vehicle Applications  

E-Print Network (OSTI)

hydrogen in storage varies between the various energy storagethe energy storage characteristics of the various hydrogenthat the energy densities of hydrogen storage technologies

Burke, Andrew; Gardnier, Monterey

2005-01-01T23:59:59.000Z

203

Down Select Report of Chemical Hydrogen Storage Materials, Catalysts, and Spent Fuel Regeneration Processes - May 2008  

Fuel Cell Technologies Publication and Product Library (EERE)

Chemical Hydrogen Storage Center of Excellence FY2008 Second Quarter Milestone Report: Technical report describing assessment of hydrogen storage materials and progress towards meeting DOEs hydrogen

204

Hydrogen Storage Options: Technologies and Comparisons for Light-Duty Vehicle Applications  

E-Print Network (OSTI)

New Methods for the Storage of Hydrogen in Microspheres,15 th World Hydrogen Energy Conference, Yokohama, Japan,Uhlemann, M. , etals. , Hydrogen Storage in Different Carbon

Burke, Andy; Gardiner, Monterey

2005-01-01T23:59:59.000Z

205

DOE Hydrogen and Fuel Cells Program: 2008 Annual Progress Report - Delivery  

NLE Websites -- All DOE Office Websites (Extended Search)

Delivery Delivery Printable Version 2008 Annual Progress Report III. Delivery This section of the 2008 Progress Report for the DOE Hydrogen Program focuses on delivery. Each technical report is available as an individual Adobe Acrobat PDF. Download Adobe Reader. Hydrogen Delivery Sub-Program Overview, Rick Farmer, U.S. Department of Energy (PDF 218 KB) Hydrogen Delivery Infrastructure Options Analysis, TP Chen, Nexant, Inc. (PDF 242 KB) Hydrogen Delivery Infrastructure Analysis, Marrianne Mintz, Argonne National Laboratory (PDF 324 KB) Hydrogen Embrittlement of Pipelines: Fundamentals, Experiments, Modeling, Petros Sofronis, University of Illinois, Urbana-Champaign (PDF 686 KB) Materials Solutions for Hydrogen Delivery in Steel Pipeline, Subodh Das, Secat, Inc. (PDF 691 KB)

206

Hydrogen Storage Materials Requirements to Meet the 2017 On Board Hydrogen Storage Technical Targets  

NLE Websites -- All DOE Office Websites (Extended Search)

Materials Materials Requirements to Meet the 2017 On Board Hydrogen Storage Technical Targets Donald Anton Savannah River National Laboratory Troy Semelsberger Don Siegel Los Alamos National Laboratory University of Michigan Bruce Hardy Kriston Brooks Savannah River National Laboratory Pacific Northwest National Laboratory Materials Requirements Webinar June 25, 2013 2 Webinar Objective Give guidance to the materials development community as to the important materials characteristic for both adsorbent and chemical hydrides required to meet the DoE Technical Targets for Onboard Hydrogen Storage Systems This work has been fully funded by the U.S. Department of Energy, through the Office of Energy Efficiency and Renewable Energy, Fuel Cell Technologies Office 3

207

Hydrogen Storage on Metal-Doped Ordered Mesoporous Carbons  

E-Print Network (OSTI)

Hydrogen Storage on Metal-Doped Ordered Mesoporous Carbons Shuguang Deng New Mexico State Meeting, May 18, 2010 #12;Outline · Research group · Hydrogen storage: background and status · Synthesis Adsorption in Ordered Mesoporous Carbon through Clathrate Formation" Int. J. Hydrogen Energy, 34, 8583

Nishiguchi, Michele

208

Chemical Hydride Slurry for Hydrogen Production and Storage  

Science Conference Proceedings (OSTI)

The purpose of this project was to investigate and evaluate the attractiveness of using a magnesium chemical hydride slurry as a hydrogen storage, delivery, and production medium for automobiles. To fully evaluate the potential for magnesium hydride slurry to act as a carrier of hydrogen, potential slurry compositions, potential hydrogen release techniques, and the processes (and their costs) that will be used to recycle the byproducts back to a high hydrogen content slurry were evaluated. A 75% MgH2 slurry was demonstrated, which was just short of the 76% goal. This slurry is pumpable and storable for months at a time at room temperature and pressure conditions and it has the consistency of paint. Two techniques were demonstrated for reacting the slurry with water to release hydrogen. The first technique was a continuous mixing process that was tested for several hours at a time and demonstrated operation without external heat addition. Further work will be required to reduce this design to a reliable, robust system. The second technique was a semi-continuous process. It was demonstrated on a 2 kWh scale. This system operated continuously and reliably for hours at a time, including starts and stops. This process could be readily reduced to practice for commercial applications. The processes and costs associated with recycling the byproducts of the water/slurry reaction were also evaluated. This included recovering and recycling the oils of the slurry, reforming the magnesium hydroxide and magnesium oxide byproduct to magnesium metal, hydriding the magnesium metal with hydrogen to form magnesium hydride, and preparing the slurry. We found that the SOM process, under development by Boston University, offers the lowest cost alternative for producing and recycling the slurry. Using the H2A framework, a total cost of production, delivery, and distribution of $4.50/kg of hydrogen delivered or $4.50/gge was determined. Experiments performed at Boston University have demonstrated the technical viability of the process and have provided data for the cost analyses that have been performed. We also concluded that a carbothermic process could also produce magnesium at acceptable costs. The use of slurry as a medium to carry chemical hydrides has been shown during this project to offer significant advantages for storing, delivering, and distributing hydrogen: Magnesium hydride slurry is stable for months and pumpable. The oils of the slurry minimize the contact of oxygen and moisture in the air with the metal hydride in the slurry. Thus reactive chemicals, such as lithium hydride, can be handled safely in the air when encased in the oils of the slurry. Though magnesium hydride offers an additional safety feature of not reacting readily with water at room temperatures, it does react readily with water at temperatures above the boiling point of water. Thus when hydrogen is needed, the slurry and water are heated until the reaction begins, then the reaction energy provides heat for more slurry and water to be heated. The reaction system can be relatively small and light and the slurry can be stored in conventional liquid fuel tanks. When transported and stored, the conventional liquid fuel infrastructure can be used. The particular metal hydride of interest in this project, magnesium hydride, forms benign byproducts, magnesium hydroxide (Milk of Magnesia) and magnesium oxide. We have estimated that a magnesium hydride slurry system (including the mixer device and tanks) could meet the DOE 2010 energy density goals. ? During the investigation of hydriding techniques, we learned that magnesium hydride in a slurry can also be cycled in a rechargeable fashion. Thus, magnesium hydride slurry can act either as a chemical hydride storage medium or as a rechargeable hydride storage system. Hydrogen can be stored and delivered and then stored again thus significantly reducing the cost of storing and delivering hydrogen. Further evaluation and development of this concept will be performed as follow-on work under a

McClaine, Andrew W.

2008-09-30T23:59:59.000Z

209

Some recent efforts in chemical hydrogen storage at Loa Alamos  

DOE Green Energy (OSTI)

Within the transportation sector, a necessity towards realizing the use of hydrogen (H{sub 2}) as an alternative fuel, is its storage for controlled delivery. The U.S. DOE's Centers of Excellence (CoE) in H{sub 2} storage have pursued different methodologies (metal hydrides, chemical hydrides, and sorbents), for the express purpose of supplanting gasoline's current > 300 mile driving range. Chemical H{sub 2} storage has been dominated by one material, ammonia borane (H3B-NH3, AB), due to its high gravimetric capacity of H{sub 2} (19.6 wt %) and low molecular weight (30.7 g mol{sup -1} ). As such, a number of publications have described H{sub 2} release from amine boranes, yielding various rates depending on the method applied. The viability of any storage system is also dependent on efficient recyclability. Within our CoE we have thus endeavored to find efficient base-metal catalyzed AB dehydrogenation pathways and regeneration schemes for the spent fuel from H{sub 2} depleted AB. We will present some recent results in these areas in this vein.

Gordon, John C [Los Alamos National Laboratory; Davis, Benjamin L [Los Alamos National Laboratory; Burrell, Anthony K [Los Alamos National Laboratory; Nakagawa, Tessui [Los Alamos National Laboratory; Ott, Kevin C [Los Alamos National Laboratory; Smythe, Nathan C [Los Alamos National Laboratory; Sutton, Andrew D [Los Alamos National Laboratory; Henson, Neil J [Los Alamos National Laboratory; Baker, R. Thomas [U. OTTAWA; Hamilton, Charles W [OD VISION, INC.; Dixon, David A [U. ALABAMA; Garner Ill, Edward B [U. ALABAMA; Vasiliu, Monica [U. ALABAMA

2010-12-08T23:59:59.000Z

210

Strategic Directions for Hydrogen Delivery Workshop Proceedings  

NLE Websites -- All DOE Office Websites (Extended Search)

W W W o o r r k k s s h h o o p p P P r r o o c c e e e e d d i i n n g g s s M M a a y y 7 7 - - 8 8 , , 2 2 0 0 0 0 3 3 C C r r y y s s t t a a l l C C i i t t y y M M a a r r r r i i o o t t t t A A r r l l i i n n g g t t o o n n , , V V A A S S p p o o n n s s o o r r e e d d b b y y U U . . S S . . D D e e p p a a r r t t m m e e n n t t o o f f E E n n e e r r g g y y O O f f f f i i c c e e o o f f E E n n e e r r g g y y E E f f f f i i c c i i e e n n c c y y a a n n d d R R e e n n e e w w a a b b l l e e E E n n e e r r g g y y O O f f f f i i c c e e o o f f H H y y d d r r o o g g e e n n , , F F u u e e l l C C e e l l l l s s , , a a n n d d I I n n f f r r a a s s t t r r u u c c t t u u r r e e T T e e c c h h n n o o l l o o g g i i e e s s P P r r o o g g r r a a m m Strategic Directions for Hydrogen Delivery Workshop i May 2003 Table of Contents INTRODUCTION ...........................................................................................................................................................................................1 BACKGROUND.............................................................................................................................................................................................1

211

Neutron Characterization in Support of the DOE Hydrogen Storage...  

NLE Websites -- All DOE Office Websites (Extended Search)

gained from these studies will be applied toward the design and synthesis of hydrogen-storage materials that meet the following DOE 2017 storage targets: Specific energy: 1.8 kWh...

212

Hydrogen storage of energy for small power supply systems  

E-Print Network (OSTI)

Power supply systems for cell phone base stations using hydrogen energy storage, fuel cells or hydrogen-burning generators, and a backup generator could offer an improvement over current power supply systems. Two categories ...

Monaghan, Rory F. D. (Rory Francis Desmond)

2005-01-01T23:59:59.000Z

213

Summary Report from DOE Theory Focus Session on Hydrogen Storage...  

NLE Websites -- All DOE Office Websites (Extended Search)

DOE Theory Focus Session on Hydrogen Storage Materials San Francisco, 24 March 2008 In conjunction with the Spring 2008 Materials Research Society Meeting Assessment of Modeling...

214

Hydrogen storage materials and method of making by dry homogenation  

DOE Green Energy (OSTI)

Dry homogenized metal hydrides, in particular aluminum hydride compounds, as a material for reversible hydrogen storage is provided. The reversible hydrogen storage material comprises a dry homogenized material having transition metal catalytic sites on a metal aluminum hydride compound, or mixtures of metal aluminum hydride compounds. A method of making such reversible hydrogen storage materials by dry doping is also provided and comprises the steps of dry homogenizing metal hydrides by mechanical mixing, such as be crushing or ball milling a powder, of a metal aluminum hydride with a transition metal catalyst. In another aspect of the invention, a method of powering a vehicle apparatus with the reversible hydrogen storage material is provided.

Jensen, Craig M. (Kailua, HI); Zidan, Ragaiy A. (Honolulu, HI)

2002-01-01T23:59:59.000Z

215

Fuel Cell Technologies Office: Hydrogen Storage Materials Requirements...  

NLE Websites -- All DOE Office Websites (Extended Search)

(Text Version) to someone by E-mail Share Fuel Cell Technologies Office: Hydrogen Storage Materials Requirements (Text Version) on Facebook Tweet about Fuel Cell Technologies...

216

Fuel Cell Technologies Office: Hydrogen Storage Materials Database...  

NLE Websites -- All DOE Office Websites (Extended Search)

(Text Version) to someone by E-mail Share Fuel Cell Technologies Office: Hydrogen Storage Materials Database Demonstration Webinar (Text Version) on Facebook Tweet about Fuel...

217

High Throughput/Combinatorial Screening of Hydrogen Storage Materials...  

NLE Websites -- All DOE Office Websites (Extended Search)

Workshop HIGH THROUGHPUTCOMBINATORIAL SCREENING OF HYDROGEN STORAGE MATERIALS June 26, 2007 Tom Boussie Symyx Technologies Symyx develops and applies proprietary high-throughput...

218

In Situ Neutron Powder Diffraction on Hydrogen Storage Materials  

Science Conference Proceedings (OSTI)

Abstract Scope, In order to pursue hydrogen storage research on powder samples ... A Case Study in Future Energy Challenges: Towards In Situ Hard X-

219

A New Platform for Hydrogen Storage and Carbon Capture  

Science Conference Proceedings (OSTI)

Presentation Title, Evaluating Chemical Adsorption on Nanodiamonds: A New Platform for Hydrogen Storage and Carbon Capture. Author(s), Lin Lai, Amanda...

220

In-situ Chemistry Mapping of Hydrogen Storage Materials by ...  

Science Conference Proceedings (OSTI)

In the first case, sodium alanate based hydrogen storage is a vehicle-scale candidate system developed by Sandia/GM. Neutron scattering was used to...

Note: This page contains sample records for the topic "delivery hydrogen storage" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Fuel Cell Technologies Office: Hydrogen Delivery  

NLE Websites -- All DOE Office Websites (Extended Search)

at a refueling station or stationary power site. Infrastructure includes the pipelines, trucks, storage facilities, compressors, and dispensers involved in the process of...

222

Strategic Initiatives for Hydrogen Delivery Workshop  

NLE Websites -- All DOE Office Websites (Extended Search)

Renewable Energy Hydrogen, Fuel Cells, and Infrastructure Technologies Program DOE Pipeline Working Group Workshop i September 2005 Table of Contents 1. INTRODUCTION......

223

Materials Solutions for Hydrogen Delivery in Pipelines  

NLE Websites -- All DOE Office Websites (Extended Search)

welding filler wires and processes that would be suitable for construction of new pipeline infrastructure - To develop barrier coatings for minimizing hydrogen permeation in...

224

Modular Energy Storage System for Hydrogen Fuel Cell Vehicles  

SciTech Connect

The objective of the project is to develop technologies, specifically power electronics, energy storage electronics and controls that provide efficient and effective energy management between electrically powered devices in alternative energy vehicles ?? plug-in electric vehicles, hybrid vehicles, range extended vehicles, and hydrogen-based fuel cell vehicles. The in-depth research into the complex interactions between the lower and higher voltage systems from data obtained via modeling, bench testing and instrumented vehicle data will allow an optimum system to be developed from a performance, cost, weight and size perspective. The subsystems are designed for modularity so that they may be used with different propulsion and energy delivery systems. This approach will allow expansion into new alternative energy vehicle markets.

Janice Thomas

2010-05-31T23:59:59.000Z

225

BIMETALLIC LITHIUM BOROHYDRIDES TOWARD REVERSIBLE HYDROGEN STORAGE  

DOE Green Energy (OSTI)

Borohydrides such as LiBH{sub 4} have been studied as candidates for hydrogen storage because of their high hydrogen contents (18.4 wt% for LiBH{sub 4}). Limited success has been made in reducing the dehydrogenation temperature by adding reactants such as metals, metal oxides and metal halides. However, full rehydrogenation has not been realized because of multi-step decomposition processes and the stable intermediate species produced. It is suggested that adding second cation in LiBH{sub 4} may reduce the binding energy of B-H. The second cation may also provide the pathway for full rehydrogenation. In this work, several bimetallic borohydrides were synthesized using wet chemistry, high pressure reactive ball milling and sintering processes. The investigation found that the thermodynamic stability was reduced, but the full rehydrogenation is still a challenge. Although our experiments show the partial reversibility of the bimetallic borohydrides, it was not sustainable during dehydriding-rehydriding cycles because of the accumulation of hydrogen inert species.

Au, M.

2010-10-21T23:59:59.000Z

226

Basic Research for Hydrogen Production, Storage and Use  

NLE Websites -- All DOE Office Websites (Extended Search)

DOE Hydrogen and Fuel Cells DOE Hydrogen and Fuel Cells Coordination Meeting 6/2/2003 DOE DOE - - BES Sponsored Workshop on BES Sponsored Workshop on Basic Research for Hydrogen Basic Research for Hydrogen Production, Storage and Use Production, Storage and Use Walter J. Stevens Walter J. Stevens Director Director Chemical Sciences, Geosciences, and Biosciences Division Chemical Sciences, Geosciences, and Biosciences Division Office of Basic Energy Sciences Office of Basic Energy Sciences Workshop dates: May 13-15, 2003 A follow-on workshop to BESAC-sponsored workshop on "Basic Research Needs to Assure a Secure Energy Future" Basic Energy Sciences Basic Energy Sciences Workshop on Hydrogen Production, Storage, and Use Workshop on Hydrogen Production, Storage, and Use DOE Hydrogen and Fuel Cells

227

Hydrogen Storage in Wind Turbine Towers: Design Considerations; Preprint  

DOE Green Energy (OSTI)

The paramount considerations associated with a hydrogen tower are corrosion (in the form of hydrogen embrittlement) and structural failure (through bursting or fatigue life degradation). Although hydrogen embrittlement (HE) requires more research and experimentation, it does not appear to prohibit the use of turbine towers for hydrogen storage. Furthermore, the structural modifications required to store hydrogen in a tower are technically feasible. We discovered that hydrogen towers have a''crossover pressure'' at which their critical mode of failure crosses over from fatigue to bursting. The crossover pressure for many turbine towers is between 10 and 15 atm. The cost of hydrogen storage per unit of storage capacity is lowest near the crossover pressure. Above the crossover pressure, however, storage costs rise quickly.

Kottenstette, R.; Cotrell, J.

2003-09-01T23:59:59.000Z

228

An Assessment of the Near-Term Costs of Hydrogen Refueling Stations and Station Components  

E-Print Network (OSTI)

Storage Dispenser Delivery and Installation Cost Hydrogen Cost Natural GasNatural Gas Cost ($/MMBTU, HHV) Electricity Cost ($/kWh) Production Volume StorageNatural Gas Reformer Reformate Hydrogen H2 Purifier High -pressure hydrogen compressor Compressed hydrogen storage

Weinert, Jonathan X.; Lipman, Timothy

2006-01-01T23:59:59.000Z

229

Hydrogen Peroxide Storage in Small Sealed Tanks  

DOE Green Energy (OSTI)

Unstabilized hydrogen peroxide of 85% concentration has been prepared in laboratory quantities for testing material compatibility and long term storage on a small scale. Vessels made of candidate tank and liner materials ranged in volume from 1 cc to 2540 cc. Numerous metals and plastics were tried at the smallest scales, while promising ones were used to fabricate larger vessels and liners. An aluminum alloy (6061-T6) performed poorly, including increasing homogeneous decay due to alloying elements entering solution. The decay rate in this high strength aluminum was greatly reduced by anodizing. Better results were obtained with polymers, particularly polyvinylidene fluoride. Data reported herein include ullage pressures as a function of time with changing decay rates, and contamination analysis results.

Whitehead, J.

1999-10-20T23:59:59.000Z

230

Amineborane Based Chemical Hydrogen Storage - Final Report  

DOE Green Energy (OSTI)

The efficient regeneration of ammonia borane from BNHx spent fuel is one of the most challenging problems that will have to be overcome in order to utilize AB-based hydrogen storage. Three Center partners, LANL, PNNL and Penn, each took different complimentary approaches to AB regeneration. The Penn approach focused on a strategy involving spent-fuel digestion with superacidic acids to produce boron-halides (BX3) that could then be converted to AB by coordination/reduction/displacement processes. While the Penn boron-halide reduction studies successfully demonstrated that a dialkylsulfide-based coordination/reduction/displacement process gave quantitative conversions of BBr3 to ammonia borane with efficient and safe product separations, the fact that AB spent-fuels could not be digested in good yields to BX3 halides led to a No-Go decision on this overall AB-regeneration strategy.

Sneddon, Larry G.

2011-04-21T23:59:59.000Z

231

Hydrogen Storage Systems Analysis Working Group Meeting: Summary Report  

NLE Websites -- All DOE Office Websites (Extended Search)

Held in Conjunction with the DOE Hydrogen Program Annual Merit Review Crystal Gateway Marriott, Arlington, VA June 11, 2008 SUMMARY REPORT Compiled by Romesh Kumar Argonne National Laboratory and Elvin Yzugullu Sentech, Inc. July 18, 2008 SUMMARY REPORT Hydrogen Storage Systems Analysis Working Group Meeting June 11, 2008 Crystal Gateway Marriott, Arlington, VA Meeting Objectives This meeting was one of a continuing series of biannual meetings of the Hydrogen Storage Systems Analysis Working Group (SSAWG). The objective of these meetings is to bring together the DOE research community involved in systems analysis of hydrogen storage materials and processes for information exchange and to update the researchers on related

232

Chemical Hydrides for Hydrogen Storage in Fuel Cell Applications  

Science Conference Proceedings (OSTI)

Due to its high hydrogen storage capacity (up to 19.6% by weight for the release of 2.5 molar equivalents of hydrogen gas) and its stability under typical ambient conditions, ammonia borane (AB) is a promising material for chemical hydrogen storage for fuel cell applications in transportation sector. Several systems models for chemical hydride materials such as solid AB, liquid AB and alane were developed and evaluated at PNNL to determine an optimal configuration that would meet the 2010 and future DOE targets for hydrogen storage. This paper presents an overview of those systems models and discusses the simulation results for various transient drive cycle scenarios.

Devarakonda, Maruthi N.; Brooks, Kriston P.; Ronnebro, Ewa; Rassat, Scot D.; Holladay, Jamelyn D.

2012-04-16T23:59:59.000Z

233

Hydrogen Storage Systems Analysis Meeting: Summary Report, March 29, 2005  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen Storage Systems Analysis Meeting Hydrogen Storage Systems Analysis Meeting 955 L'Enfant Plaza North, SW, Suite 6000 Washington, DC 20024-2168 March 29, 2005 SUMMARY REPORT Compiled by Romesh Kumar Argonne National Laboratory June 20, 2005 SUMMARY REPORT Hydrogen Storage Systems Analysis Meeting March 29, 2005 955 L'Enfant Plaza, North, SW, Suite 6000 Washington, DC 20024-2168 Meeting Objectives The objective of this meeting was to familiarize the DOE research community involved in hydrogen storage materials and process development with the systems analysis work being carried out within the DOE program. In particular, Argonne National Laboratory (ANL) has been tasked to develop models of on-board and off-board hydrogen storage systems based on the various materials and technologies being developed at the DOE Centers of Excellence and

234

Hydrogen Storage Systems Analysis Working Group Meeting: Summary Report  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen Storage Systems Analysis Working Group Meeting Hydrogen Storage Systems Analysis Working Group Meeting Argonne DC Offices L'Enfant Plaza, Washington, DC December 4, 2007 SUMMARY REPORT Compiled by Romesh Kumar Argonne National Laboratory and Kristin Deason Sentech, Inc. January 16, 2008 SUMMARY REPORT Hydrogen Storage Systems Analysis Working Group Meeting December 4, 2007 Argonne DC Offices, L'Enfant Plaza, Washington, DC Meeting Objectives This meeting was one of a continuing series of biannual meetings of the Hydrogen Storage Systems Analysis Working Group (SSAWG). The objective of these meetings is to bring together the DOE research community involved in systems analysis of hydrogen storage materials and processes for information exchange and to update the researchers on related developments within the DOE program. A major thrust of these meetings is to leverage

235

Summary Report from Theory Focus Session on Hydrogen Storage Materials  

NLE Websites -- All DOE Office Websites (Extended Search)

Theory Focus Session on Hydrogen Storage Materials DOE Hydrogen Program Assessment of Modeling Needs for Hydrogen Storage This report provides a summary of feedback from co-organizers, speakers and participants of the Department of Energy's (DOE) Theory Focus Session on Hydrogen Storage Materials, held Thursday, May 18, 2006, Crystal City, VA, in conjunction with the DOE Hydrogen Program Annual Merit Review, May 16-19, 2006. Session co-organizers: Chris Wolverton (Ford), Karl Johnson (University of Pittsburgh), Maciek Gutowski (Pacific Northwest National Laboratory) Goal of focus session: Identify critical areas, key barriers and gaps in current theory/modeling approaches for hydrogen storage materials and technologies Role of modeling and simulation in design of H

236

Combinatorial Approach for Hydrogen Storage Materials (presentation)  

NLE Websites -- All DOE Office Websites (Extended Search)

Approach for Approach for Hydrogen Storage Materials Grigorii Soloveichik, John Lemmon, Jun Cui, Yan Gao, Tom Raber, Job Rijssenbeek, Gosia Rubinzstajn, J.C. Zhao 2 Outline Approach: Parallel synthesis accompanied by high throughput screening for a desired property. - Methods * Preparation/parallel synthesis * Analytical techniques * Scale-up - Selected results * Al-Li-Si system * Al-Mg-Ti system * AlH 3 + Si * Mg(BH 4 ) 2 - Summary 3 Down-selection of the combi process High energy 96-well Shaker Production of multiple compositions HTS Analytical Tools Thermography ToF-SIMS Co-sputtering Diffusion multiples WO 3 sensor 4 -3.9dC 3.7dC -2 0 2 Hydrogen Sorption in Diffusion Multiples Traditional DM w/ LaNi several new concepts. Activation 80 °C / 100psi H 2 Cycling 80 °C / 100psi H 2 Na Mg Na Na Al Na Li Li Na Vial 1

237

Recommended Best Practices for the Characterization of Storage Properties of Hydrogen Storage Materials  

Fuel Cell Technologies Publication and Product Library (EERE)

This is a reference guide to common methodologies and protocols for measuring critical performance properties of advanced hydrogen storage materials. It helps users to communicate clearly the relevan

238

Characterization and High Throughput Analysis of Metal Hydrides for Hydrogen Storage  

E-Print Network (OSTI)

low volume, energy efficient hydrogen storage system if fuelof Energy (DOE) for on-board hydrogen storage. However,hydrogen storage system as defined by the Department of Energy.

Barcelo, Steven James

2009-01-01T23:59:59.000Z

239

Overview of geologic storage of natural gas with an emphasis on assessing the feasibility of storing hydrogen.  

DOE Green Energy (OSTI)

In many regions across the nation geologic formations are currently being used to store natural gas underground. Storage options are dictated by the regional geology and the operational need. The U.S. Department of Energy (DOE) has an interest in understanding theses various geologic storage options, the advantages and disadvantages, in the hopes of developing an underground facility for the storage of hydrogen as a low cost storage option, as part of the hydrogen delivery infrastructure. Currently, depleted gas/oil reservoirs, aquifers, and salt caverns are the three main types of underground natural gas storage in use today. The other storage options available currently and in the near future, such as abandoned coal mines, lined hard rock caverns, and refrigerated mined caverns, will become more popular as the demand for natural gas storage grows, especially in regions were depleted reservoirs, aquifers, and salt deposits are not available. The storage of hydrogen within the same type of facilities, currently used for natural gas, may add new operational challenges to the existing cavern storage industry, such as the loss of hydrogen through chemical reactions and the occurrence of hydrogen embrittlement. Currently there are only three locations worldwide, two of which are in the United States, which store hydrogen. All three sites store hydrogen within salt caverns.

Lord, Anna Snider

2009-09-01T23:59:59.000Z

240

Chemisorption On Nanoparticles: An Alternative Mechanism For Hydrogen Storage  

DOE Green Energy (OSTI)

We present first principles, computational predictions of a porous, nano-structured semiconductor material that will reversibly store hydrogen for fuel cell applications. The material is competitive with current metal hydride storage materials, but contains only carbon and silicon, reducing both its cost and environmental impact. Additionally, unlike metal hydrides, the core skeleton structure of this material is unaltered when cycling from full hydrogen storage to full hydrogen depletion, removing engineering complications associated with expansion/contraction of the material.

Williamson, A; Reboredo, F; Galli, G

2004-04-09T23:59:59.000Z

Note: This page contains sample records for the topic "delivery hydrogen storage" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Electron Charged Graphite-based Hydrogen Storage Material  

DOE Green Energy (OSTI)

The electron-charge effects have been demonstrated to enhance hydrogen storage capacity using materials which have inherent hydrogen storage capacities. A charge control agent (CCA) or a charge transfer agent (CTA) was applied to the hydrogen storage material to reduce internal discharge between particles in a Sievert volumetric test device. GTI has tested the device under (1) electrostatic charge mode; (2) ultra-capacitor mode; and (3) metal-hydride mode. GTI has also analyzed the charge distribution on storage materials. The charge control agent and charge transfer agent are needed to prevent internal charge leaks so that the hydrogen atoms can stay on the storage material. GTI has analyzed the hydrogen fueling tank structure, which contains an air or liquid heat exchange framework. The cooling structure is needed for hydrogen fueling/releasing. We found that the cooling structure could be used as electron-charged electrodes, which will exhibit a very uniform charge distribution (because the cooling system needs to remove heat uniformly). Therefore, the electron-charge concept does not have any burden of cost and weight for the hydrogen storage tank system. The energy consumption for the electron-charge enhancement method is quite low or omitted for electrostatic mode and ultra-capacitor mode in comparison of other hydrogen storage methods; however, it could be high for the battery mode.

Dr. Chinbay Q. Fan; D Manager

2012-03-14T23:59:59.000Z

242

Borazine-boron nitride hybrid hydrogen storage system  

DOE Patents (OSTI)

A hybrid hydrogen storage composition includes a first phase and a second phase adsorbed on the first phase, the first phase including BN for storing hydrogen by physisorption and the second phase including a borazane-borazine system for storing hydrogen in combined form as a hydride.

Narula, Chaitanya K. (Knoxville, TN); Simonson, J. Michael (Knoxville, TN); Maya, Leon (Knoxville, TN); Paine, Robert T. (Albuquerque, NM)

2008-04-22T23:59:59.000Z

243

Design and evaluation of seasonal storage hydrogen peak electricity supply system  

E-Print Network (OSTI)

The seasonal storage hydrogen peak electricity supply system (SSHPESS) is a gigawatt-year hydrogen storage system which stores excess electricity produced as hydrogen during off-peak periods and consumes the stored hydrogen ...

Oloyede, Isaiah Olanrewaju

2011-01-01T23:59:59.000Z

244

Hydrogen Storage: U.S. Department of Energy Hydrogen and Fuel...  

NLE Websites -- All DOE Office Websites (Extended Search)

ST-019: Multiply Surface-Functionalized Nanoporous Carbon for Vehicular Hydrogen Storage Peter Pfeifer; University of Missouri Brief Summary of Project: The objective of this...

245

Hydrogen storage in sodium aluminum hydride.  

DOE Green Energy (OSTI)

Sodium aluminum hydride, NaAlH{sub 4}, has been studied for use as a hydrogen storage material. The effect of Ti, as a few mol. % dopant in the system to increase kinetics of hydrogen sorption, is studied with respect to changes in lattice structure of the crystal. No Ti substitution is found in the crystal lattice. Electronic structure calculations indicate that the NaAlH{sub 4} and Na{sub 3}AlH{sub 6} structures are complex-ionic hydrides with Na{sup +} cations and AlH{sub 4}{sup -} and AlH{sub 6}{sup 3-} anions, respectively. Compound formation studies indicate the primary Ti-compound formed when doping the material at 33 at. % is TiAl{sub 3} , and likely Ti-Al compounds at lower doping rates. A general study of sorption kinetics of NaAlH{sub 4}, when doped with a variety of Ti-halide compounds, indicates a uniform response with the kinetics similar for all dopants. NMR multiple quantum studies of solution-doped samples indicate solvent interaction with the doped alanate. Raman spectroscopy was used to study the lattice dynamics of NaAlH{sub 4}, and illustrated the molecular ionic nature of the lattice as a separation of vibrational modes between the AlH{sub 4}{sup -} anion-modes and lattice-modes. In-situ Raman measurements indicate a stable AlH{sub 4}{sup -} anion that is stable at the melting temperature of NaAlH{sub 4}, indicating that Ti-dopants must affect the Al-H bond strength.

Ozolins, Vidvuds; Herberg, J.L. (Lawrence Livermore National Laboratories, Livermore, CA); McCarty, Kevin F.; Maxwell, Robert S. (Lawrence Livermore National Laboratories, Livermore, CA); Stumpf, Roland Rudolph; Majzoub, Eric H.

2005-11-01T23:59:59.000Z

246

Hydrogen Storage … DOE Program/Targets and Workshop Objectives  

NLE Websites -- All DOE Office Websites (Extended Search)

Argonne National Laboratory Argonne National Laboratory August 14, 2002 JoAnn Milliken Neil Rossmeissl Hydrogen, Fuel Cells & Infrastructure Technologies Program Energy Efficiency and Renewable Energy (EERE) Hydrogen Storage - DOE Program/Targets and Workshop Objectives Outline * The Hydrogen, Fuel Cells, and Infrastructure Program * Role of FreedomCAR * R&D Priorities * DOE Fuel Cell & Hydrogen Activities * DOE Targets/Status * Workshop Objectives Hydrogen and Fuel Cells are a High Priority within EERE Hydrogen Vision/Roadmap Workshops held Nov 2001 & April 2002 with industry stakeholders * Hydrogen Vision complete * Hydrogen Roadmap draft completed * www.eren.doe.gov/hydrogen/features.html Technology development for hydrogen fuel cell vehicles is the thrust of the

247

Materials Solutions for Hydrogen Delivery in Pipelines  

SciTech Connect

The main objective of the study is as follows: Identify steel compositions/microstructures suitable for construction of new pipeline infrastructure and evaluate the potential use of the existing steel pipeline infrastructure in high pressure gaseous hydrogen applications. The microstructures of four pipeline steels were characterized and tensile testing was conducted in gaseous hydrogen and helium at pressures of 5.5 MPa (800 psi), 11 MPa (1600 psi) and 20.7 MPa (3000 psi). Based on reduction of area, two of the four steels that performed the best across the pressure range were selected for evaluation of fracture and fatigue performance in gaseous hydrogen at 5.5 MPa (800 psi) and 20.7 MPa (3000 psi). The basic format for this phase of the study is as follows: Microstructural characterization of volume fraction of phases in each alloy; Tensile testing of all four alloys in He and H{sub 2} at 5.5 MPa (800 psi), 11 MPa (1600 psi), and 20.7 MPa (3000 psi). RA performance was used to choose the two best performers for further mechanical property evaluation; Fracture testing (ASTM E1820) of two best tensile test performers in H{sub 2} at 5.5 MPa (800 psi) and 20.7 MPa (3000 psi); Fatigue testing (ASTM E647) of two best tensile test performers in H2 at 5.5 MPa (800 psi) and 20.7 MPa (3000 psi) with frequency =1.0 Hz and R-ratio=0.5 and 0.1.

Ningileri, Shridas T.; Boggess, Todd A; Stalheim, Douglas

2013-01-02T23:59:59.000Z

248

Electric utility applications of hydrogen energy storage systems  

DOE Green Energy (OSTI)

This report examines the capital cost associated with various energy storage systems that have been installed for electric utility application. The storage systems considered in this study are Battery Energy Storage (BES), Superconducting Magnetic Energy Storage (SMES) and Flywheel Energy Storage (FES). The report also projects the cost reductions that may be anticipated as these technologies come down the learning curve. This data will serve as a base-line for comparing the cost-effectiveness of hydrogen energy storage (HES) systems in the electric utility sector. Since pumped hydro or compressed air energy storage (CAES) is not particularly suitable for distributed storage, they are not considered in this report. There are no comparable HES systems in existence in the electric utility sector. However, there are numerous studies that have assessed the current and projected cost of hydrogen energy storage system. This report uses such data to compare the cost of HES systems with that of other storage systems in order to draw some conclusions as to the applications and the cost-effectiveness of hydrogen as a electricity storage alternative.

Swaminathan, S.; Sen, R.K.

1997-10-15T23:59:59.000Z

249

Hydrogen storage-bed design for tritium systems test assembly  

DOE Green Energy (OSTI)

The Los Alamos National Laboratory has completed the design of a hydrogen storage bed for the Tritium Systems Test Assembly (TSTA). Our objective is to store hydrogen isotopes as uranium hydrides and recover them by dehydriding. The specific use of the storage bed is to store DT gas as U(D,T)/sub 3/ when it is required for the TSTA. The hydrogen storage bed consists of a primary container in which uranium powder is stored and a secondary container for a second level of safety in gas confinement. The primary container, inlet and outlet gas lines, cartridge heaters, and instrumentation are assembled in the secondary container. The design of the hydrogen storage bed is presented, along with the modeling and analysis of the bed behavior during hydriding-dehydriding cycles.

Cullingford, H.S.; Wheeler, M.G.; McMullen, J.W.

1981-01-01T23:59:59.000Z

250

Process for synthesis of ammonia borane for bulk hydrogen storage  

The AB product shows promise as a chemical hydrogen storage material for fuel cell powered ... Contract DE-AC0676RLO-1830 awarded by the U.S. Department of Energy.

251

Palladium Coated Kieselghuhr for Simultaneous Separation and Storage of Hydrogen  

DOE Green Energy (OSTI)

This paper will discuss characteristics of the palladium-coated kieselguhr or diatomaceous earth, design and operation of the FTB, and results of performance tests such as separation efficiency, hydrogen storage capacity and system heat transfer characteristics.

Hsu, R.H.

2001-10-19T23:59:59.000Z

252

High-Throughput/Combinatorial Techniques in Hydrogen Storage...  

NLE Websites -- All DOE Office Websites (Extended Search)

High-ThroughputCombinatorial Techniques in Hydrogen Storage Materials R&D Ned Stetson, Larry Blair 1 , Grace Ordaz, Carole Read, George Thomas 2 , and Sunita Satyapal Suite 900,...

253

Fuel Cell Technologies Office: Hydrogen Storage Workshop Proceedings  

NLE Websites -- All DOE Office Websites (Extended Search)

Thoughts on Fundamentals (PDF 255 KB), P. Teagan and M. Rona, TIAX Hydrogen Storage in Carbon Nanotubes (PDF 1.19 MB), Jack E. Fischer, University of Pennsylvania Advanced...

254

Fuel Cell Technologies Office: Hydrogen Production  

NLE Websites -- All DOE Office Websites (Extended Search)

Basics Current Technology R&D Activities Quick Links Hydrogen Delivery Hydrogen Storage Fuel Cells Technology Validation Manufacturing Codes & Standards Education Systems...

255

Low-Cost Precursors to Novel Hydrogen Storage Materials  

DOE Green Energy (OSTI)

From 2005 to 2010, The Dow Chemical Company (formerly Rohm and Haas Company) was a member of the Department of Energy Center of Excellence on Chemical Hydrogen Storage, which conducted research to identify and develop chemical hydrogen storage materials having the potential to achieve DOE performance targets established for on-board vehicular application. In collaboration with Center co-leads Los Alamos National Laboratory (LANL) and Pacific Northwest National Laboratory (PNNL), and other Center partners, Dow's efforts were directed towards defining and evaluating novel chemistries for producing chemical hydrides and processes for spent fuel regeneration. In Phase 1 of this project, emphasis was placed on sodium borohydride (NaBH{sub 4}), long considered a strong candidate for hydrogen storage because of its high hydrogen storage capacity, well characterized hydrogen release chemistry, safety, and functionality. Various chemical pathways for regenerating NaBH{sub 4} from spent sodium borate solution were investigated, with the objective of meeting the 2010/2015 DOE targets of $2-3/gal gasoline equivalent at the pump ($2-3/kg H{sub 2}) for on-board hydrogen storage systems and an overall 60% energy efficiency. With the September 2007 No-Go decision for NaBH{sub 4} as an on-board hydrogen storage medium, focus was shifted to ammonia borane (AB) for on-board hydrogen storage and delivery. However, NaBH{sub 4} is a key building block to most boron-based fuels, and the ability to produce NaBH{sub 4} in an energy-efficient, cost-effective, and environmentally sound manner is critical to the viability of AB, as well as many leading materials under consideration by the Metal Hydride Center of Excellence. Therefore, in Phase 2, research continued towards identifying and developing a single low-cost NaBH4 synthetic route for cost-efficient AB first fill, and conducting baseline cost estimates for first fill and regenerated AB using a variety of synthetic routes. This project utilized an engineering-guided R&D approach, which involved the rapid down-selection of a large number of options (chemical pathways to NaBH{sub 4}) to a smaller, more manageable number. The research began by conducting an extensive review of the technical and patent literature to identify all possible options. The down-selection was based on evaluation of the options against a set of metrics, and to a large extent occurred before experimentation was initiated. Given the vast amount of literature and patents that has evolved over the years, this approach helped to focus efforts and resources on the options with the highest technical and commercial probability of success. Additionally, a detailed engineering analysis methodology was developed for conducting the cost and energy-efficiency calculations. The methodology utilized a number of inputs and tools (Aspen PEA{trademark}, FCHTool, and H2A). The down-selection of chemical pathways to NaBH{sub 4} identified three options that were subsequently pursued experimentally. Metal reduction of borate was investigated in Dow's laboratories, research on electrochemical routes to NaBH{sub 4} was conducted at Pennsylvania State University, and Idaho National Laboratory researchers examined various carbothermal routes for producing NaBH{sub 4} from borate. The electrochemical and carbothermal studies did not yield sufficiently positive results. However, NaBH{sub 4} was produced in high yields and purities by an aluminum-based metal reduction pathway. Solid-solid reactive milling, slurry milling, and solution-phase approaches to metal reduction were investigated, and while both reactive milling and solution-phase routes point to fully recyclable processes, the scale-up of reactive milling processes to produce NaBH{sub 4} is expected to be difficult. Alternatively, a low-cost solution-phase approach to NaBH{sub 4} has been identified that is based on conventional process unit operations and should be amenable to scale-up. Numerous advances in AB synthesis have been made in recent years to improve AB yields and purities

Suzanne W. Linehan; Arthur A. Chin; Nathan T. Allen; Robert Butterick; Nathan T. Kendall; I. Leo Klawiter; Francis J. Lipiecki; Dean M. Millar; David C. Molzahn; Samuel J. November; Puja Jain; Sara Nadeau; Scott Mancroni

2010-12-31T23:59:59.000Z

256

U.S. Department of Energy Hydrogen Storage Cost Analysis  

SciTech Connect

The overall objective of this project is to conduct cost analyses and estimate costs for on- and off-board hydrogen storage technologies under development by the U.S. Department of Energy (DOE) on a consistent, independent basis. This can help guide DOE and stakeholders toward the most-promising research, development and commercialization pathways for hydrogen-fueled vehicles. A specific focus of the project is to estimate hydrogen storage system cost in high-volume production scenarios relative to the DOE target that was in place when this cost analysis was initiated. This report and its results reflect work conducted by TIAX between 2004 and 2012, including recent refinements and updates. The report provides a system-level evaluation of costs and performance for four broad categories of on-board hydrogen storage: (1) reversible on-board metal hydrides (e.g., magnesium hydride, sodium alanate); (2) regenerable off-board chemical hydrogen storage materials(e.g., hydrolysis of sodium borohydride, ammonia borane); (3) high surface area sorbents (e.g., carbon-based materials); and 4) advanced physical storage (e.g., 700-bar compressed, cryo-compressed and liquid hydrogen). Additionally, the off-board efficiency and processing costs of several hydrogen storage systems were evaluated and reported, including: (1) liquid carrier, (2) sodium borohydride, (3) ammonia borane, and (4) magnesium hydride. TIAX applied a â??bottom-upâ? costing methodology customized to analyze and quantify the processes used in the manufacture of hydrogen storage systems. This methodology, used in conjunction with DFMA?® software and other tools, developed costs for all major tank components, balance-of-tank, tank assembly, and system assembly. Based on this methodology, the figure below shows the projected on-board high-volume factory costs of the various analyzed hydrogen storage systems, as designed. Reductions in the key cost drivers may bring hydrogen storage system costs closer to this DOE target. In general, tank costs are the largest component of system cost, responsible for at least 30 percent of total system cost, in all but two of the 12 systems. Purchased BOP cost also drives system cost, accounting for 10 to 50 percent of total system cost across the various storage systems. Potential improvements in these cost drivers for all storage systems may come from new manufacturing processes and higher production volumes for BOP components. In addition, advances in the production of storage media may help drive down overall costs for the sodium alanate, SBH, LCH2, MOF, and AX-21 systems.

Law, Karen; Rosenfeld, Jeffrey; Han, Vickie; Chan, Michael; Chiang, Helena; Leonard, Jon

2013-03-11T23:59:59.000Z

257

Analyses of Compressed Hydrogen On-Board Storage Systems  

NLE Websites -- All DOE Office Websites (Extended Search)

Compressed Compressed Hydrogen On-Board Storage Systems © 2010 TIAX LLC Compressed and Cryo-Compressed Hydrogen Storage Workshop February 14, 2011 Jeff Rosenfeld Karen Law Jayanti Sinha TIAX LLC 35 Hartwell Ave Lexington, MA 02421-3102 Tel. 781-879-1708 Fax 781-879-1201 www.TIAXLLC.com Reference: D0268 Overview Project Objectives Project Objectives Description Overall Help guide DOE and developers toward promising R&D and commercialization pathways by evaluating the status of the various on-board hydrogen storage technologies on a consistent basis On-Board Storage System Assessment Evaluate or develop system-level designs for the on-board storage system to project bottom-up factory costs Off-Board Fuel Cycle Assessment Evaluate or develop designs and cost inputs for the fuel cycle to

258

Chemical Hydride Slurry for Hydrogen Production and Storage  

DOE Green Energy (OSTI)

?\tDuring the investigation of hydriding techniques, we learned that magnesium hydride in a slurry can also be cycled in a rechargeable fashion. Thus, magnesium hydride slurry can act either as a chemical hydride storage medium or as a rechargeable hydride storage system. Hydrogen can be stored and delivered and then stored again thus significantly reducing the cost of storing and delivering hydrogen. Further evaluation and development of this concept will be performed as follow-on work under a

McClaine, Andrew W.

2008-09-30T23:59:59.000Z

259

Hydrogen transport and storage in engineered glass microspheres  

DOE Green Energy (OSTI)

New, high-strength, hollow, glass microspheres filled with pressurized hydrogen exhibit storage densities which make them attractive for bulk hydrogen storage and transport. The hoop stress at failure of our engineered glass microspheres is about 150,000 psi, permitting a three-fold increase in pressure limit and storage capacity above commercial microspheres, which fail at wall stresses of 50,000 psi. For this project, microsphere material and structure will be optimized for storage capacity and charge/discharge kinetics to improve their commercial practicality. Microsphere production scale up will be performed, directed towards large-scale commercial use. Our analysis relating glass microspheres for hydrogen transport with infrastructure and economics` indicate that pressurized microspheres can be economically competitive with other forms of bulk rail and truck transport such as hydride beds, cryocarbons and pressurized tube transports. For microspheres made from advanced materials and processes, analysis will also be performed to identify the appropriate applications of the microspheres considering property variables, and different hydrogen infrastructure, end use, production and market scenarios. This report presents some of the recent modelling results for large beds of glass microspheres in hydrogen storage applications. It includes plans for experiments to identify the properties relevant to large-bed hydrogen transport and storage applications, of the best, currently producible, glass microspheres. This work began in March, 1994. Project successes will be manifest in the matching of cur-rent glass microspheres with a useful application in hydrogen bulk transport and storage, and in developing microsphere materials and processes that increase the storage density and reduce the storage energy requirement.

Rambach, G.D.

1994-04-20T23:59:59.000Z

260

DEVELOPMENT OF DOPED NANOPOROUS CARBONS FOR HYDROGEN STORAGE  

DOE Green Energy (OSTI)

Hydrogen storage materials based on the hydrogen spillover mechanism onto metal-doped nanoporous carbons are studied, in an effort to develop materials that store appreciable hydrogen at ambient temperatures and moderate pressures. We demonstrate that oxidation of the carbon surface can significantly increase the hydrogen uptake of these materials, primarily at low pressure. Trace water present in the system plays a role in the development of active sites, and may further be used as a strategy to increase uptake. Increased surface density of oxygen groups led to a significant enhancement of hydrogen spillover at pressures less than 100 milibar. At 300K, the hydrogen uptake was up to 1.1 wt. % at 100 mbar and increased to 1.4 wt. % at 20 bar. However, only 0.4 wt% of this was desorbable via a pressure reduction at room temperature, and the high lowpressure hydrogen uptake was found only when trace water was present during pretreatment. Although far from DOE hydrogen storage targets, storage at ambient temperature has significant practical advantages oner cryogenic physical adsorbents. The role of trace water in surface modification has significant implications for reproducibility in the field. High-pressure in situ characterization of ideal carbon surfaces in hydrogen suggests re-hybridization is not likely under conditions of practical interest. Advanced characterization is used to probe carbon-hydrogen-metal interactions in a number of systems and new carbon materials have been developed.

Angela D. Lueking; Qixiu Li; John V. Badding; Dania Fonseca; Humerto Gutierrez; Apurba Sakti; Kofi Adu; Michael Schimmel

2010-03-31T23:59:59.000Z

Note: This page contains sample records for the topic "delivery hydrogen storage" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Model based design of an automotive-scale, metal hydride hydrogen storage system.  

SciTech Connect

Sandia and General Motors have successfully designed, fabricated, and experimentally operated a vehicle-scale hydrogen storage system using the complex metal hydride sodium alanate. Over the 6 year project, the team tackled the primary barriers associated with storage and delivery of hydrogen including mass, volume, efficiency and cost. The result was the hydrogen storage demonstration system design. The key technologies developed for this hydrogen storage system include optimal heat exchange designs, thermal properties enhancement, a unique catalytic hydrogen burner and energy efficient control schemes. The prototype system designed, built, and operated to demonstrate these technologies consists of four identical hydrogen storage modules with a total hydrogen capacity of 3 kg. Each module consists of twelve stainless steel tubes that contain the enhanced sodium alanate. The tubes are arranged in a staggered, 4 x 3 array and enclosed by a steel shell to form a shell and tube heat exchanger. Temperature control during hydrogen absorption and desorption is accomplished by circulating a heat transfer fluid through each module shell. For desorption, heat is provided by the catalytic oxidation of hydrogen within a high efficiency, compact heat exchanger. The heater was designed to transfer up to 30 kW of heat from the catalytic reaction to the circulating heat transfer fluid. The demonstration system module design and the system control strategies were enabled by experiment-based, computational simulations that included heat and mass transfer coupled with chemical kinetics. Module heat exchange systems were optimized using multi-dimensional models of coupled fluid dynamics and heat transfer. Chemical kinetics models were coupled with both heat and mass transfer calculations to design the sodium alanate vessels. Fluid flow distribution was a key aspect of the design for the hydrogen storage modules and computational simulations were used to balance heat transfer with fluid pressure requirements. An overview of the hydrogen storage system will be given, and examples of these models and simulation results will be described and related to component design. In addition, comparisons of demonstration system experimental results to model predictions will be reported.

Johnson, Terry Alan; Kanouff, Michael P.; Jorgensen, Scott W. (General Motors R& D); Dedrick, Daniel E.; Evans, Gregory Herbert

2010-11-01T23:59:59.000Z

262

Hydrogen Storage Using Electric Field Enhanced Adsorption  

Science Conference Proceedings (OSTI)

About this Abstract. Meeting, 2010 TMS Annual Meeting & Exhibition. Symposium , Materials in Clean Power Systems V: Clean Coal-, Hydrogen...

263

The Influence of Graphene Curvature on Hydrogen Adsorption: Towards Hydrogen Storage Devices  

E-Print Network (OSTI)

The ability of atomic hydrogen to chemisorb on graphene makes the latter a promising material for hydrogen storage. Based on scanning tunneling microscopy techniques, we report on site-selective adsorption of atomic hydrogen on convexly curved regions of monolayer graphene grown on SiC(0001). This system exhibits an intrinsic curvature owing to the interaction with the substrate. We show that at low coverage hydrogen is found on convex areas of the graphene lattice. No hydrogen is detected on concave regions. These findings are in agreement with theoretical models which suggest that both binding energy and adsorption barrier can be tuned by controlling the local curvature of the graphene lattice. This curvature-dependence combined with the known graphene flexibility may be exploited for storage and controlled release of hydrogen at room temperature making it a valuable candidate for the implementation of hydrogen-storage devices.

Goler, Sarah; Tozzini, Valentina; Piazza, Vincenzo; Mashoff, Torge; Beltram, Fabio; Pellegrini, Vittorio; Heun, Stefan

2013-01-01T23:59:59.000Z

264

Optimization of compression and storage requirements at hydrogen refueling stations.  

SciTech Connect

The transition to hydrogen-powered vehicles requires detailed technical and economic analyses of all aspects of hydrogen infrastructure, including refueling stations. The cost of such stations is a major contributor to the delivered cost of hydrogen. Hydrogen refueling stations require not only dispensers to transfer fuel onto a vehicle, but also an array of such ancillary equipment as a cascade charging system, storage vessels, compressors and/or pumps/evaporators. This paper provides detailed information on design requirements for gaseous and liquid hydrogen refueling stations and their associated capital and operating costs, which in turn impact hydrogen selling price at various levels of hydrogen demand. It summarizes an engineering economics approach which captures the effect of variations in station size, seasonal, daily and hourly demand, and alternative dispensing rates and pressures on station cost. Tradeoffs in the capacity of refueling station compressors, storage vessels, and the cascade charging system result in many possible configurations for the station. Total costs can be minimized by optimizing that configuration. Using a methodology to iterate among the costs of compression, storage and cascade charging, it was found that the optimum hourly capacity of the compressor is approximately twice the station's average hourly demand, and the optimum capacity of the cascade charging system is approximately 15% of the station's average daily demand. Further, for an hourly demand profile typical of today's gasoline stations, onsite hydrogen storage equivalent to at least 1/3 of the station's average daily demand is needed to accommodate peak demand.

Elgowainy, A.; Mintz, M.; Kelly, B.; Hooks, M.; Paster, M. (Energy Systems); (Nexant, Inc.); (TIAX LLC)

2008-01-01T23:59:59.000Z

265

DOE Hydrogen and Fuel Cells Program: 2005 Annual Progress Report - Delivery  

NLE Websites -- All DOE Office Websites (Extended Search)

Delivery Delivery Printable Version 2005 Annual Progress Report V. Delivery This section of the 2005 Progress Report for the DOE Hydrogen Program focuses on delivery. Each technical report is available as an individual Adobe Acrobat PDF. Download Adobe Reader. Hydrogen Delivery Sub-program Overview, Mark Paster, Department of Energy (PDF 159 KB) A. Pipelines Hydrogen Permeability and Integrity of Hydrogen Transfer Pipelines, Zhili Feng, Oak Ridge National Laboratory (PDF 596 KB) New Materials for Hydrogen Pipelines, Barton Smith, Oak Ridge National Laboratory (PDF 562 KB) Materials Solutions for Hydrogen Delivery in Pipelines, Subodh K. Das, SECAT Inc (PDF 248 KB) Evaluation of Natural Gas Pipeline Materials for Hydrogen/Mixed Hydrogen-natural Gas Service, Thad M. Adams, Savannah River National

266

Executive Summaries for the Hydrogen Storage Materials Center of Excellence - Chemical Hydrogen Storage CoE, Hydrogen Sorption CoE, and Metal Hydride CoE  

NLE Websites -- All DOE Office Websites (Extended Search)

Executive Summaries Executive Summaries for the Hydrogen Storage Materials Centers of Excellence Chemical Hydrogen Storage CoE, Hydrogen Sorption CoE, and Metal Hydride CoE Period of Performance: 2005-2010 Fuel Cell Technologies Program Office of Energy Efficiency and Renewable Energy U. S. Department of Energy April 2012 2 3 Primary Authors: Chemical Hydrogen Storage (CHSCoE): Kevin Ott, Los Alamos National Laboratory Hydrogen Sorption (HSCoE): Lin Simpson, National Renewable Energy Laboratory Metal Hydride (MHCoE): Lennie Klebanoff, Sandia National Laboratory Contributors include members of the three Materials Centers of Excellence and the Department of Energy Hydrogen Storage Team in the Office of Energy Efficiency and Renewable Energy's Fuel Cell Technologies Program.

267

Materials for Hydrogen Production, Storage, and Distribution  

Science Conference Proceedings (OSTI)

Feb 16, 2010 ... Co-Production of Pure Hydrogen and Electricity from Coal Syngas via the .... and plastic deformations in the crack tip energy rate formulate.

268

Hydrogen Storage Characteristics of Nanograined Free-Standing  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen Storage Characteristics of Nanograined Free-Standing Hydrogen Storage Characteristics of Nanograined Free-Standing Magnesium-Nickel Films Title Hydrogen Storage Characteristics of Nanograined Free-Standing Magnesium-Nickel Films Publication Type Journal Article Year of Publication 2009 Authors Rogers, Matthew, Steven J. Barcelo, Xiaobo Chen, Thomas J. Richardson, Vincent Berube, Gang Chen, Mildred S. Dresselhaus, Costas P. Grigoropoulos, and Samuel S. Mao Journal Applied Physics A Volume 96 Start Page 349 Issue 2 Pagination 349-352 Date Published 08/2009 ISSN 1432-0630 Keywords 68.43.Mn, 68.43.Nr, 68.55.-a Abstract Free-standing magnesium-nickel (Mg-Ni) films with extensive nanoscale grain structures were fabricated using a combination of pulsed laser deposition and film delaminating processes. Hydrogen sorption and desorption properties of the films, free from the influence of substrates, were investigated. Oxidation of the material was reduced through the use of a sandwiched free-standing film structure in which the top and bottom layers consist of nanometer-thick Pd layers, which also acted as a catalyst to promote hydrogen uptake and release. Hydrogen storage characteristics were studied at three temperatures, 296, 232, and 180°C, where multiple sorption/desorption cycles were measured gravimetrically. An improvement in hydrogen storage capacity over the bulk Mg-Ni target material was found for the free-standing films. As shown from a Van't Hoff plot, the thermodynamic stability of the nanograined films is similar to that of Mg2Ni. These results suggest that free-standing films, of which better control of material compositions and microstructures can be realized than is possible for conventional ball-milled powders, represent a useful materials platform for solid-state hydrogen storage research.

269

DOE Theory Focus Session on Hydrogen Storage Materials  

NLE Websites -- All DOE Office Websites (Extended Search)

U.S. Department of Energy U.S. Department of Energy Theory Focus Session on Hydrogen Storage Materials DOE Hydrogen Program Basic Energy Sciences (Office of Science) and Office of Hydrogen, Fuel Cells and Infrastructure Technologies (Energy Efficiency and Renewable Energy) Thursday, May 18, 2006 (1 pm to 6 pm) Crystal Gateway Marriott, Crystal City, VA (In conjunction with the DOE Hydrogen Program Annual Merit Review, May 16-19) Co-organizers: Chris Wolverton (Ford), Karl Johnson (U. of Pittsburgh), Maciek Gutowski (Pacific Northwest National Laboratory) DOE Contacts: Sunita Satyapal and Dale Koelling Objectives: * Identify critical areas, key barriers and gaps in current theory/modeling approaches for hydrogen storage materials and technologies * Provide an overview of current state of the art and most recent technical progress

270

Iron titanium manganase alloy hydrogen storage  

DOE Patents (OSTI)

A three component alloy capable of reversible sorption of hydrogen having the chemical formula TiFe.sub.1-x Mn.sub.x where x is in the range of about 0.02 to 0.5 and the method of storing hydrogen using said alloy.

Reilly, James J. (Bellport, NY); Wiswall, Jr., Richard H. (Brookhaven, NY)

1979-01-01T23:59:59.000Z

271

Metal-Containing Organic and Carbon Aerogels for Hydrogen Storage  

SciTech Connect

This document and the accompanying manuscript summarize the technical accomplishments of our one-year LDRD-ER effort. Hydrogen storage and hydrogen fuel cells are important components of the 2003 Hydrogen Fuel Initiative focused on the reduction of America's dependence on oil. To compete with oil as an energy source, however, one must be able to transport and utilize hydrogen at or above the target set by DOE (6 wt.% H{sub 2}) for the transportation sector. Other than liquid hydrogen, current technology falls well short of this DOE target. As a result, a variety of materials have recently been investigated to address this issue. Carbon nanostructures have received significant attention as hydrogen storage materials due to their low molecular weight, tunable microporosity and high specific surface areas. For example, the National Renewable Energy Laboratory (NREL) achieved 5 to 10 wt.% H{sub 2} storage using metal-doped carbon nanotubes. That study showed that the intimate mix of metal nanoparticles with graphitic carbon resulted in the unanticipated hydrogen adsorption at near ambient conditions. The focus of our LDRD effort was the investigation of metal-doped carbon aerogels (MDCAs) as hydrogen storage materials. In addition to their low mass densities, continuous porosities and high surface areas, these materials are promising candidates for hydrogen storage because MDCAs contain a nanometric mix of metal nanoparticles and graphitic nanostructures. For FY04, our goals were to: (1) prepare a variety of metal-doped CAs (where the metal is cobalt, nickel or iron) at different densities and carbonization temperatures, (2) characterize the microstructure of these materials and (3) initiate hydrogen adsorption/desorption studies to determine H2 storage properties of these materials. Since the start of this effort, we have successfully prepared and characterized Ni- and Co-doped carbon aerogels at different densities and carbonization temperatures. The bulk of this work is described in the attached manuscript entitled 'Formation of Carbon Nanostructures in Cobalt- and Nickel- Doped Carbon Aerogels'. This one-year effort has lead to our incorporation into the DOE Carbon-based Hydrogen Storage Center of Excellence at NREL, with funding from DOE's Energy Efficiency and Renewable Energy (EERE) Program starting in FY05.

Satcher, Jr., J H; Baumann, T F; Herberg, J L

2005-01-10T23:59:59.000Z

272

Hydrogen Delivery Infrastructure Analysis - DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report  

NLE Websites -- All DOE Office Websites (Extended Search)

3 3 FY 2012 Annual Progress Report DOE Hydrogen and Fuel Cells Program Amgad Elgowainy (Primary Contact), Marianne Mintz and Krishna Reddi Argonne National Laboratory 9700 South Cass Avenue Argonne, IL 60439 Phone: (630) 252-3074 Email: aelgowainy@anl.gov DOE Manager HQ: Erika Sutherland Phone: (202) 586-3152 Email: Erika.Sutherland@ee.doe.gov Project Start Date: October 2007 Project End Date: Project continuation and direction determined annually by DOE Fiscal Year (FY) 2012 Objectives Identify cost drivers of current technologies for hydrogen * delivery to early market applications of fuel cells Evaluate role of high-pressure tube-trailers in reducing * hydrogen delivery cost Identify and evaluate benefits of synergies between *

273

LANL Virtual Center for Chemical Hydrogen Storage: Chemical Hydrogen Storage Using Ultra-high Surface Area Main Group Materials  

SciTech Connect

The focus of the project was to design and synthesize light element compounds and nanomaterials that will reversibly store molecular hydrogen for hydrogen storage materials. The primary targets investigated during the last year were amine and hydrogen terminated silicon (Si) nanoparticles, Si alloyed with lighter elements (carbon (C) and boron (B)) and boron nanoparticles. The large surface area of nanoparticles should facilitate a favorable weight to volume ratio, while the low molecular weight elements such as B, nitrogen (N), and Si exist in a variety of inexpensive and readily available precursors. Furthermore, small NPs of Si are nontoxic and non-corrosive. Insights gained from these studies will be applied toward the design and synthesis of hydrogen storage materials that meet the DOE 2010 hydrogen storage targets: cost, hydrogen capacity and reversibility. Two primary routes were explored for the production of nanoparticles smaller than 10 nm in diameter. The first was the reduction of the elemental halides to achieve nanomaterials with chloride surface termination that could subsequently be replaced with amine or hydrogen. The second was the reaction of alkali metal Si or Si alloys with ammonium halides to produce hydrogen capped nanomaterials. These materials were characterized via X-ray powder diffraction, TEM, FTIR, TG/DSC, and NMR spectroscopy.

Susan M. Kauzlarich; Phillip P. Power; Doinita Neiner; Alex Pickering; Eric Rivard; Bobby Ellis, T. M.; Atkins, A. Merrill; R. Wolf; Julia Wang

2010-09-05T23:59:59.000Z

274

Hydrogen Storage -Overview George Thomas, Hydrogen Consultant to SNL*  

E-Print Network (OSTI)

75 100 125 hydrogen m ethane ethane propane butane pentane hexane heptane octane (gasoline) cetane (diesel) octane (gasoline) heptane hexane pentane butane ethane propane ethanol m ethane m ethanol am m

275

DOE Hydrogen and Fuel Cells Program Record 13013: Hydrogen Delivery Cost Projections - 2013  

NLE Websites -- All DOE Office Websites (Extended Search)

3013 Date: September 26, 2013 3013 Date: September 26, 2013 Title: H 2 Delivery Cost Projections - 2013 Originator: E. Sutherland, A. Elgowainy and S. Dillich Approved by: R. Farmer and S. Satyapal Date: December 18, 2013 Item: Reported herein are past 2005 and 2011 estimates, current 2013 estimates, 2020 projected cost estimates and the 2015 and 2020 target costs for delivering and dispensing (untaxed) H 2 to 10%- 15% of vehicles within a city population of 1.2M from a centralized H 2 production plant located 100 km from the city gate. The 2011 volume cost estimates are based on the H2A Hydrogen Delivery Scenario Analysis Model (HDSAM) V2.3 projections and are employed as the basis for defining the cost and technical targets of delivery components in Table 3.2.4 in the 2012 Delivery

276

Hydrogen Storage I - Programmaster.org  

Science Conference Proceedings (OSTI)

Aug 3, 2010 ... For instances, Mg/MmM5 multi-layer film can reversibly absorb about 5 mass% hydrogen at 473 K. The Mg-Re(rare earth metals) based alloys...

277

Hydrogen Storage Materials Workshop Proceedings Workshop, October...  

NLE Websites -- All DOE Office Websites (Extended Search)

Research (USCAR) Southfield, MI Sponsored by the U.S. Department of Energy Office of Hydrogen, Fuel Cells and Infrastructure Technologies Table of Contents A A c c k k n n o o w w...

278

On-board hydrogen storage system using metal hydride  

DOE Green Energy (OSTI)

A hydrogen powered hybrid electric bus has been developed for demonstration in normal city bus service in the City of Augusta, Georgia, USA. The development team, called H2Fuel Bus Team, consists of representatives from government, industry and research institutions. The bus uses hydrogen to fuel an internal combustion engine which drives an electric generator. The generator charges a set of batteries which runs the electric bus. The hydrogen fuel and the hybrid concept combine to achieve the goal of near-zero emission and high fuel efficiency. The hydrogen fuel is stored in a solid form using an on-board metal hydride storage system. The system was designed for a hydrogen capacity of 25 kg. It uses the engine coolant for heat to generate a discharge pressure higher than 6 atm. The operation conditions are temperature from ambient to 70 degrees C, hydrogen discharge rate to 6 kg/hr, and refueling time 1.5 hours. Preliminary tests showed that the performance of the on-board storage system exceeded the design requirements. Long term tests have been planned to begin in 2 months. This paper discusses the design and performance of the on-board hydrogen storage system.

Heung, L.K.

1997-07-01T23:59:59.000Z

279

Recommended Best Practices for the Characterization of Storage Properties of Hydrogen Storage Materials - Section 6 Thermal Properties of Hydrogen Storage Materials  

NLE Websites -- All DOE Office Websites (Extended Search)

82 82 Recommended Best Practices for Characterizing Engineering Properties of Hydrogen Storage Materials. V150: February 4, 2013 Recommended Best Practices for Characterizing Engineering Properties of Hydrogen Storage Materials Karl J. Gross, H2 Technology Consulting LLC Bruce Hardy, of Savannah River National Laboratory We gratefully acknowledge assistance and financial support from the U.S. Department of Energy Office of Energy Efficiency and Renewable Energy Hydrogen Storage Program. National Renewable Energy Laboratory Contract No. 147388 Contract Technical Monitor: Dr. Philip Parilla H2 Technology Consulting, LLC kgross@h2techconsulting.com tel: (510) 468-7515 Table of Contents Page 2 of 282 Recommended Best Practices for Characterizing

280

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY Accepted June 2008 HYDROGEN STORAGE FOR MIXED WIND-NUCLEAR POWER PLANTS IN  

E-Print Network (OSTI)

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY Accepted June 2008 1 HYDROGEN STORAGE FOR MIXED WIND evaluation of hydrogen production and storage for a mixed wind-nuclear power plant considering some new of a combined nuclear-wind-hydrogen system is discussed first, where the selling and buying of electricity

Cañizares, Claudio A.

Note: This page contains sample records for the topic "delivery hydrogen storage" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Technical System Targets: Onboard Hydrogen Storage for Light-Duty Fuel Cell Vehicles  

E-Print Network (OSTI)

is to be determined. e Onboard efficiency is the energy efficiency for delivering hydrogen from the storage systemTechnical System Targets: Onboard Hydrogen Storage for Light-Duty Fuel Cell Vehicles a Storage to the powerplant divided by the total mass/volume of the complete storage system, including all stored hydrogen

282

Hydrogen Storage Systems Analysis Working Group Meeting Held in Conjunction with the  

E-Print Network (OSTI)

Hydrogen Storage Systems Analysis Working Group Meeting Held in Conjunction with the DOE Hydrogen REPORT Hydrogen Storage Systems Analysis Working Group Meeting June 11, 2008 Crystal Gateway Marriott of the Hydrogen Storage Systems Analysis Working Group (SSAWG). The objective of these meetings is to bring

283

Thermodynamically Tuned Nanophase Materials for reversible Hydrogen storage  

DOE Green Energy (OSTI)

This program was devoted to significantly extending the limits of hydrogen storage technology for practical transportation applications. To meet the hydrogen capacity goals set forth by the DOE, solid-state materials consisting of light elements were developed. Many light element compounds are known that have high capacities. However, most of these materials are thermodynamically too stable, and they release and store hydrogen much too slowly for practical use. In this project we developed new light element chemical systems that have high hydrogen capacities while also having suitable thermodynamic properties. In addition, we developed methods for increasing the rates of hydrogen exchange in these new materials. The program has significantly advanced (1) the application of combined hydride systems for tuning thermodynamic properties and (2) the use of nanoengineering for improving hydrogen exchange. For example, we found that our strategy for thermodynamic tuning allows both entropy and enthalpy to be favorably adjusted. In addition, we demonstrated that using porous supports as scaffolds to confine hydride materials to nanoscale dimensions could improve rates of hydrogen exchange by > 50x. Although a hydrogen storage material meeting the requirements for commercial development was not achieved, this program has provided foundation and direction for future efforts. More broadly, nanoconfinment using scaffolds has application in other energy storage technologies including batteries and supercapacitors. The overall goal of this program was to develop a safe and cost-effective nanostructured light-element hydride material that overcomes the thermodynamic and kinetic barriers to hydrogen reaction and diffusion in current materials and thereby achieve > 6 weight percent hydrogen capacity at temperatures and equilibrium pressures consistent with DOE target values.

Ping Liu; John J. Vajo

2010-02-28T23:59:59.000Z

284

HYDROGEN CONCENTRATIONS DURING STORAGE OF 3013 OXIDE SAMPLES  

DOE Green Energy (OSTI)

As part of a surveillance program intended to ensure the safe storage of plutonium bearing nuclear materials in the Savannah River Site (SRS) K-Area Materials Storage (KAMS), samples of these materials are shipped to Savannah River National Laboratory (SRNL) for analysis. These samples are in the form of solids or powders which will have absorbed moisture. Potentially flammable hydrogen gas is generated due to radiolysis of the moisture. The samples are shipped for processing after chemical analysis. To preclude the possibility of a hydrogen deflagration or detonation inside the shipping containers, the shipping times are limited to ensure that hydrogen concentration in the vapor space of every layer of confinement is below the lower flammability limit of 4 volume percent (vol%). This study presents an analysis of the rate of hydrogen accumulation due to radiolysis and calculation of allowable shipping times for typical KAMS materials.

Hensel, S.; Askew, N.; Laurinat, J.

2011-03-14T23:59:59.000Z

285

ALUMINUM HYDRIDE: A REVERSIBLE MATERIAL FOR HYDROGEN STORAGE  

DOE Green Energy (OSTI)

Hydrogen storage is one of the challenges to be overcome for implementing the ever sought hydrogen economy. Here we report a novel cycle to reversibly form high density hydrogen storage materials such as aluminium hydride. Aluminium hydride (AlH{sub 3}, alane) has a hydrogen storage capacity of 10.1 wt% H{sub 2}, 149 kg H{sub 2}/m{sup 3} volumetric density and can be discharged at low temperatures (< 100 C). However, alane has been precluded from use in hydrogen storage systems because of the lack of practical regeneration methods. The direct hydrogenation of aluminium to form AlH{sub 3} requires over 10{sup 5} bars of hydrogen pressure at room temperature and there are no cost effective synthetic means. Here we show an unprecedented reversible cycle to form alane electrochemically, using alkali metal alanates (e.g. NaAlH{sub 4}, LiAlH{sub 4}) in aprotic solvents. To complete the cycle, the starting alanates can be regenerated by direct hydrogenation of the dehydrided alane and the alkali hydride being the other compound formed in the electrochemical cell. The process of forming NaAlH{sub 4} from NaH and Al is well established in both solid state and solution reactions. The use of adducting Lewis bases is an essential part of this cycle, in the isolation of alane from the mixtures of the electrochemical cell. Alane is isolated as the triethylamine (TEA) adduct and converted to pure, unsolvated alane by heating under vacuum.

Zidan, R; Christopher Fewox, C; Brenda Garcia-Diaz, B; Joshua Gray, J

2009-01-09T23:59:59.000Z

286

ALUMINUM HYDRIDE: A REVERSIBLE MATERIAL FOR HYDROGEN STORAGE  

DOE Green Energy (OSTI)

Hydrogen storage is one of the greatest challenges for implementing the ever sought hydrogen economy. Here we report a novel cycle to reversibly form high density hydrogen storage materials such as aluminium hydride. Aluminium hydride (AlH{sub 3}, alane) has a hydrogen storage capacity of 10.1 wt% H{sub 2}, 149 kg H{sub 2}/m{sup 3} volumetric density and can be discharged at low temperatures (< 100 C). However, alane has been precluded from use in hydrogen storage systems because of the lack of practical regeneration methods; the direct hydrogenation of aluminium to form AlH{sub 3} requires over 10{sup 5} bars of hydrogen pressure at room temperature and there are no cost effective synthetic means. Here we show an unprecedented reversible cycle to form alane electrochemically, using alkali alanates (e.g. NaAlH{sub 4}, LiAlH{sub 4}) in aprotic solvents. To complete the cycle, the starting alanates can be regenerated by direct hydrogenation of the dehydrided alane and the alkali hydride being the other compound formed in the electrochemical cell. The process of forming NaAlH{sub 4} from NaH and Al is well established in both solid state and solution reactions. The use of adducting Lewis bases is an essential part of this cycle, in the isolation of alane from the mixtures of the electrochemical cell. Alane is isolated as the triethylamine (TEA) adduct and converted to pure, unsolvated alane by heating under vacuum.

Fewox, C; Ragaiy Zidan, R; Brenda Garcia-Diaz, B

2008-12-31T23:59:59.000Z

287

Research and Development Strategies for Compressed & Cryo-Hydrogen Storage Systems - Workshop Summary Report  

NLE Websites -- All DOE Office Websites (Extended Search)

and Development and Development Strategies for Compressed & Cryo-Hydrogen Storage Systems Workshop Summary Report Prepared by: Fuel Cell Technologies Program Compressed & Cryo-Hydrogen Storage Systems Workshops February 14-15, 2011 Crystal City, Virginia Compressed and Cryo-Hydrogen Storage Systems Workshop Summary Report 2 Research and Development Strategies for Compressed & Cryo- Hydrogen Storage Systems Summary: On February 14-15, 2011, the Systems Integration group of the National Renewable Energy Laboratory, in conjunction with the Hydrogen Storage team of the EERE Fuel Cell Technologies Program, hosted two days of workshops on compressed and cryo- hydrogen storage systems in Crystal City, VA. The overarching objective was to

288

Direct Hydrogenation Magnesium Boride to Magnesium Borohydride: Demonstration of >11 Weight Percent Reversible Hydrogen Storage  

DOE Green Energy (OSTI)

We here for the first time demonstrate direct hydrogenation of magnesium boride, MgB2, to magnesium borohydride, Mg(BH4)2 at 900 bar H2-pressures and 400C. Upon 14.8wt% hydrogen release, the end-decomposition product of Mg(BH4)2 is MgB2, thus, this is a unique reversible path here obtaining >11wt% H2 which implies promise for a fully reversible hydrogen storage material.

Severa, Godwin; Ronnebro, Ewa; Jensen, Craig M.

2010-11-16T23:59:59.000Z

289

Ammonia as an Alternative Energy Storage Medium for Hydrogen Fuel Cells: Scientific and Technical Review for Near-Term Stationary Power Demonstration Projects, Final Report  

E-Print Network (OSTI)

Alternative Energy Storage Medium for Hydrogen Fuel Cells:Alternative Energy Storage Medium for Hydrogen Fuel Cells:based energy storage system to produce hydrogen for a fuel

Lipman, Tim; Shah, Nihar

2007-01-01T23:59:59.000Z

290

Technical assessment of cryo-compressed hydrogen storage tank systems for automotive applications.  

DOE Green Energy (OSTI)

On-board and off-board performance and cost of cryo-compressed hydrogen storage has been assessed and compared to the DOE 2010, 2015 and ultimate targets for automotive applications. The Gen-3 prototype system of Lawrence Livermore National Laboratory was modeled to project the performance of a scaled-down 5.6-kg usable hydrogen storage system. The on-board performance of the system and high-volume manufacturing cost were determined for liquid hydrogen refueling with a single-flow nozzle and a pump that delivers 1.5 kg/min of liquid H{sub 2} to the insulated cryogenic tank capable of being pressurized to 272 atm (4000 psi). The off-board performance and cost of delivering liquid hydrogen were determined for two scenarios in which hydrogen is produced by central steam methane reforming (SMR) and by central electrolysis using electricity from renewable sources. The main conclusions from the assessment are that the cryo-compressed storage system has the potential of meeting the ultimate target for system gravimetric capacity and the 2015 target for system volumetric capacity (see Table I). The system compares favorably with targets for durability and operability although additional work is needed to understand failure modes for combined pressure and temperature cycling. The system may meet the targets for hydrogen loss during dormancy under certain conditions of minimum daily driving. The high-volume manufacturing cost is projected to be 2-4 times the current 2010 target of $4/kWh. For the reference conditions considered most applicable, the fuel cost for the SMR hydrogen production and liquid H{sub 2} delivery scenario is 60%-140% higher than the current target of $2-$3/gge while the well-to-tank efficiency is well short of the 60% target specified for off-board regenerable materials.

Ahluwalia, R. K.; Hua, T. Q.; Peng, J.-K.; Lasher, S.; McKenney, K.; Sinha, J.; Nuclear Engineering Division; TIAX LLC

2010-03-03T23:59:59.000Z

291

U.S. Department of Energy Theorty Focus Session on Hydrogen Storage...  

NLE Websites -- All DOE Office Websites (Extended Search)

Theory Focus Session on Hydrogen Storage Materials Office of Hydrogen, Fuel Cells and Infrastructure Technologies, Energy Efficiency and Renewable Energy Office of Basic Energy...

292

Hydrogen Delivery Sub-Program Overview - DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report  

NLE Websites -- All DOE Office Websites (Extended Search)

FY 2012 Annual Progress Report DOE Hydrogen and Fuel Cells Program IntroductIon The Hydrogen Delivery sub-program supports research and development (R&D) of technologies that enable low-cost, efficient, and safe delivery of hydrogen to the end-user in order to achieve a threshold cost of $2-$4 per gallon gasoline equivalent (gge) of hydrogen (produced, delivered, and dispensed), which represents the cost at which hydrogen fuel cell electric vehicles (FCEVs) are projected to become competitive on a cost- per-mile basis with competing vehicles (gasoline-powered hybrid-electric vehicles) in 2020. 1 The Hydrogen Delivery sub-program addresses all hydrogen distribution activities from the point of production to the point

293

DOE Hydrogen and Fuel Cells Program Record 9014: Hydrogen Storage Materials: 2007 … 2009  

NLE Websites -- All DOE Office Websites (Extended Search)

RCB (12/02/09) RCB (12/02/09) 1 DOE Hydrogen and Fuel Cells Program Record Record #: 9014 Date: December 02, 2009 Title: Hydrogen Storage Materials: 2007 - 2009 Originator: Robert C. Bowman, Ned T. Stetson Approved by: Sunita Satyapal Date: December 02, 2009 Item: This record summarizes the status of hydrogen (H 2 ) storage capacities that were determined for materials investigated between 2007 and 2009 within the Hydrogen Storage sub-program. Figure 1 shows the current status of materials development in terms of their gravimetric (in wt.%) capacities for just the materials themselves as a function of H 2 release or uptake temperature. The system targets for weight and temperatures as recently revised [1] for the 2015 and ultimate metrics are the areas enclosed by dashed lines in Figure 1. The arrow within the "windows"

294

Fueling up with Hydrogen: New Approaches to Hydrogen Storage (433rd Brookhaven Lecture)  

DOE Green Energy (OSTI)

Hydrogen, the most abundant element in the universe, burns excellently and cleanly, with only pure water as a byproduct. NASA has used hydrogen as fuel for years in the space program. So, why not use hydrogen to fuel cars? The bottleneck of developing hydrogen-fueled vehicles has been identified: the greatest problem is storage. The conventional storage method, compressed hydrogen gas, requires a large tank volume, and the possibility of a tank rupture poses a significant safety risk. Another method, low temperature liquid storage, is expensive and impractical for most automotive applications. An alternative is to store the hydrogen in the solid state. In his talk, Jason Graetz will describe the new approaches to hydrogen storage being studied by his group at BNL. These include using kinetically stabilized hydrides, bialkali alanates and reversible metal-organic hydrides. The researchers are also using novel synthesis approaches, state-of-the-art characterization and first principles modeling, all providing a better fundamental understanding of these interesting and useful new materials.

Graetz, Jason (Energy Sciences and Technology Dept)

2008-02-20T23:59:59.000Z

295

Second Generation MOF's for Hydrogen Storage  

DOE Green Energy (OSTI)

This final technical report summarizes work exploring strategies to generate second generation metal organic frameworks (MOFs). These strategies were (a) the formation of interpenetrated frameworks and (b) the generation of coordinatively unsaturated metal centers (open metal sites). In the first phase of the project the effectiveness of these strategies was evaluated experimentally by measuring the saturation hydrogen uptake at high pressure and low temperature of 14 MOFs. The results of these studies demonstrated that surface area is the most useful parameter that correlates with ultimate hydrogen capacity. The strategy of interpenetration has so far failed to produce MOFs with high surface areas and therefore high saturation capacities for hydrogen have not been achieved. The incorporation of coordinatively unsaturated metal centers, however, is a promising strategy that allows higher heats of H2 adsorption to be realized without compromising surface area. Based on these initial findings, research efforts in phase two have concentrated on the discovery of new ultrahigh surface area materials with metal centers capable of supporting coordinative unsaturation without structural collapse. One approach has been the synthesis of new organic linkers that have more exposed edges, which is a factor that contributes to increasing surface area, at least when considering subunits of graphene sheets. Another strategy has been to synthesize MOFs with reduced symmetry linkers in order to generate structure types that are less likely to interpenetrate. Successful implementation of these strategies has resulted in the synthesis of 7 new compounds one of which is the highest surface area Cu based MOF reported to date.

Adam Matzger

2008-05-31T23:59:59.000Z

296

CATALYTICALLY ENCHANCED SYSTEMS FOR HYDROGEN STORAGE  

DOE Green Energy (OSTI)

Previous U.S. DOE sponsored research at the University of Hawaii resulted in the development of methods of doping of sodium aluminum hydride, NaAlH4 with titanium, zirconium and other catalysts such that: dehydriding occurs at temperatures as low as 100C; rehydriding requires less than 1 h; and >4 weight percent hydrogen can be repeatedly cycled through dehydriding/rehydriding. These materials appeared to be on the threshold of practical viability as hydrogen carriers for onboard fuel cells. However, it was apparent that further kinetic enhancement was required to achieve commercial viability. Thus, one of the primary goals of this project was to develop the requisite improved catalysts. Over the course of this project, a variety of titanium and zirconium dopant precursors were investigated. Moreover, the approach was to conduct guided search for improved catalysts by obtaining a fundamental understanding of the chemical nature of the titanium dopants and their mechanism of action. Therefore, the projected also aimed to determined the chemical nature of the titanium species that are formed upon mechanical milling of NaAlH4 with the dopant precursors through synchrotron X-ray and neutron diffraction as well as transmission electron microscopy, scanning electron microscopy, and electron paramagnetic resonance (EPR) spectroscopy. In addition to kinetic studies, insight into the mechanism of action of the dopants was gained through studies of the destabilization of hydrogen in NaAlH4 by the dopants through infrared, NMR, and anelastic spectroscopy.

Craig M. Jensen

2007-04-23T23:59:59.000Z

297

Life-Cycle Cost Analysis Highlights Hydrogen's Potential for Electrical Energy Storage (Fact Sheet)  

DOE Green Energy (OSTI)

This fact sheet describes NREL's accomplishments in analyzing life-cycle costs for hydrogen storage in comparison with other energy storage technologies. Work was performed by the Hydrogen Technologies and Systems Center.

Not Available

2010-11-01T23:59:59.000Z

298

Go No-Go Recommendation for Sodium Borohydride for On-Board Vehicular Hydrogen Storage  

Fuel Cell Technologies Publication and Product Library (EERE)

Independent review panel recommendation for go/no go decision on use of hydrolysis of sodium borohydride for hydrogen storage.

299

Hydrogen Storage Systems Analysis Meeting 955 L'Enfant Plaza North, SW, Suite 6000  

E-Print Network (OSTI)

Hydrogen Storage Systems Analysis Meeting 955 L'Enfant Plaza North, SW, Suite 6000 Washington, DC, 2005 #12;SUMMARY REPORT Hydrogen Storage Systems Analysis Meeting March 29, 2005 955 L'Enfant Plaza was to familiarize the DOE research community involved in hydrogen storage materials and process development

300

Mathematical Modelling of a Metal Hydride Hydrogen Storage System Brendan David MacDonald  

E-Print Network (OSTI)

Member Abstract In order for metal hydride hydrogen storage systems to compete with existing energyMathematical Modelling of a Metal Hydride Hydrogen Storage System by Brendan David MacDonald B Hydrogen Storage System by Brendan David MacDonald B.A.Sc., University of Waterloo, 2004 Supervisory

Victoria, University of

Note: This page contains sample records for the topic "delivery hydrogen storage" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Hydrogen Composite Tank Program Principal Investigator: Dr. Neel Sirosh, Director of Fuel Storage  

E-Print Network (OSTI)

Hydrogen Composite Tank Program Principal Investigator: Dr. Neel Sirosh, Director of Fuel Storage-effective and efficient high-pressure hydrogen storage systems. World's premier automotive OEMs developing fuel cell vehicles have demonstrated significant interest in compressed hydrogen storage systems developed

302

Hydrogen Storage Systems Analysis Working Group Meeting Argonne National Laboratory DC Offices  

E-Print Network (OSTI)

Hydrogen Storage Systems Analysis Working Group Meeting Argonne National Laboratory DC Offices 955 REPORT Hydrogen Storage Systems Analysis Working Group Meeting December 12, 2006 955 L'Enfant Plaza research community involved in systems analysis of hydrogen storage materials and processes for information

303

Basic Energy SciencesBasic Energy Sciences DOE/EERE Hydrogen Storage  

E-Print Network (OSTI)

Basic Energy SciencesBasic Energy Sciences DOE/EERE Hydrogen Storage Pre-Solicitation Meeting, June Energy SciencesBasic Energy Sciences Workshop on Hydrogen Production, Storage, and Use Energy SciencesBasic Energy Sciences Workshop on Hydrogen Production, Storage, and Use

304

Ris-PhD-21(EN) Hydrogen Storage Materials with Focus  

E-Print Network (OSTI)

, are explored in relation to hydrogen storage. After briefly reviewing the major energy related problemsRisø-PhD-21(EN) Hydrogen Storage Materials with Focus on Main Group I-II Elements Anders Andreasen Risø National Laboratory Roskilde Denmark October 2005 #12;Hydrogen storage materials with focus

305

Destabilized and catalyzed borohydride for reversible hydrogen storage  

SciTech Connect

A process of forming a hydrogen storage material, including the steps of: providing a first material of the formula M(BH.sub.4).sub.X, where M is an alkali metal or an alkali earth metal, providing a second material selected from M(AlH.sub.4).sub.x, a mixture of M(AlH.sub.4).sub.x and MCl.sub.x, a mixture of MCl.sub.x and Al, a mixture of MCl.sub.x and AlH.sub.3, a mixture of MH.sub.x and Al, Al, and AlH.sub.3. The first and second materials are combined at an elevated temperature and at an elevated hydrogen pressure for a time period forming a third material having a lower hydrogen release temperature than the first material and a higher hydrogen gravimetric density than the second material.

Mohtadi, Rana F. (Northville, MI); Nakamura, Kenji (Toyota, JP); Au, Ming (Martinez, GA); Zidan, Ragaiy (Alken, SC)

2012-01-31T23:59:59.000Z

306

Lifecycle Cost Analysis of Hydrogen Versus Other Technologies for Electrical Energy Storage  

Science Conference Proceedings (OSTI)

This report presents the results of an analysis evaluating the economic viability of hydrogen for medium- to large-scale electrical energy storage applications compared with three other storage technologies: batteries, pumped hydro, and compressed air energy storage (CAES).

Steward, D.; Saur, G.; Penev, M.; Ramsden, T.

2009-11-01T23:59:59.000Z

307

Hydrogen Storage Options: Technologies and Comparisons for Light-Duty Vehicle Applications  

E-Print Network (OSTI)

B. , and Ovshinsky, S.R. , A Hydrogen ICE Vehicle Powered byM. , and Stetson, N. , Solid Hydrogen Storage Systems forpaper from Texaco Ovonic Hydrogen Systems, Rochester Hills,

Burke, Andrew; Gardnier, Monterey

2005-01-01T23:59:59.000Z

308

Lithium hydride and lithium amide for hydrogen storage J. Engbk, G. Nielsen, I. Chorkendorff  

E-Print Network (OSTI)

Lithium hydride and lithium amide for hydrogen storage J. Engbæk, G. Nielsen, I. Chorkendorff 1 interest. Lithium amid has a high hydrogen storage capability; 10.4wt.% hydrogen. In this study surface reactions of thin films of lithium with hydrogen and ammonia is studied under well controlled conditions

Mosegaard, Klaus

309

Modeling of Hydrogen Storage Materials: A Reactive Force Field for NaH  

E-Print Network (OSTI)

is the fall in potential energy surface during heating. Keywords: hydrogen storage, reactive force fieldModeling of Hydrogen Storage Materials: A Reactive Force Field for NaH Ojwang' J.G.O.*, Rutger van governing hydrogen desorption in NaH. During the abstraction process of surface molecular hydrogen charge

Goddard III, William A.

310

DOE Hydrogen and Fuel Cells Program: 2006 Annual Progress Report - Storage  

NLE Websites -- All DOE Office Websites (Extended Search)

Storage Storage Printable Version 2006 Annual Progress Report IV. Storage This section of the 2006 Progress Report for the DOE Hydrogen Program focuses on storage. Each technical report is available as an individual Adobe Acrobat PDF. Download Adobe Reader. Hydrogen Storage Sub-Program Overview, Sunita Satyapal, Storage Team Lead, DOE Hydrogen Program (PDF 298 KB) A. Metal Hydrides High Density Hydrogen Storage System Demonstration Using NaAlH4 Based Complex Compound Hydrides, Dan Mosher, United Technologies Research Center (PDF 763 KB) Discovery of Novel Complex Metal Hydrides for Hydrogen Storage through Molecular Modeling and Combinatorial Methods, David Lesch, UOP LLC (PDF 780 KB) Complex Hydride Compounds with Enhanced Hydrogen Storage Capacity, Dan Mosher, United Technologies Research Center (PDF 678 KB)

311

Polymeric hydrogen diffusion barrier, high-pressure storage tank so equipped, method of fabricating a storage tank and method of preventing hydrogen diffusion  

DOE Patents (OSTI)

An electrochemically active hydrogen diffusion barrier which comprises an anode layer, a cathode layer, and an intermediate electrolyte layer, which is conductive to protons and substantially impermeable to hydrogen. A catalytic metal present in or adjacent to the anode layer catalyzes an electrochemical reaction that converts any hydrogen that diffuses through the electrolyte layer to protons and electrons. The protons and electrons are transported to the cathode layer and reacted to form hydrogen. The hydrogen diffusion barrier is applied to a polymeric substrate used in a storage tank to store hydrogen under high pressure. A storage tank equipped with the electrochemically active hydrogen diffusion barrier, a method of fabricating the storage tank, and a method of preventing hydrogen from diffusing out of a storage tank are also disclosed.

Lessing, Paul A. (Idaho Falls, ID)

2008-07-22T23:59:59.000Z

312

Low Cost, High Efficiency, High Pressure Hydrogen Storage  

DOE Green Energy (OSTI)

A technical and design evaluation was carried out to meet DOE hydrogen fuel targets for 2010. These targets consisted of a system gravimetric capacity of 2.0 kWh/kg, a system volumetric capacity of 1.5 kWh/L and a system cost of $4/kWh. In compressed hydrogen storage systems, the vast majority of the weight and volume is associated with the hydrogen storage tank. In order to meet gravimetric targets for compressed hydrogen tanks, 10,000 psi carbon resin composites were used to provide the high strength required as well as low weight. For the 10,000 psi tanks, carbon fiber is the largest portion of their cost. Quantum Technologies is a tier one hydrogen system supplier for automotive companies around the world. Over the course of the program Quantum focused on development of technology to allow the compressed hydrogen storage tank to meet DOE goals. At the start of the program in 2004 Quantum was supplying systems with a specific energy of 1.1-1.6 kWh/kg, a volumetric capacity of 1.3 kWh/L and a cost of $73/kWh. Based on the inequities between DOE targets and Quantums then current capabilities, focus was placed first on cost reduction and second on weight reduction. Both of these were to be accomplished without reduction of the fuel systems performance or reliability. Three distinct areas were investigated; optimization of composite structures, development of smart tanks that could monitor health of tank thus allowing for lower design safety factor, and the development of Cool Fuel technology to allow higher density gas to be stored, thus allowing smaller/lower pressure tanks that would hold the required fuel supply. The second phase of the project deals with three additional distinct tasks focusing on composite structure optimization, liner optimization, and metal.

Mark Leavitt

2010-03-31T23:59:59.000Z

313

Hydrogen & Our Energy Future  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen Program Hydrogen Program www.hydrogen.energy.gov Hydrogen & Our Energy Future  | HydrOgEn & Our EnErgy FuturE U.S. Department of Energy Hydrogen Program www.hydrogen.energy.gov u.S. department of Energy |  www.hydrogen.energy.gov Hydrogen & Our Energy Future Contents Introduction ................................................... p.1 Hydrogen - An Overview ................................... p.3 Production ..................................................... p.5 Delivery ....................................................... p.15 Storage ........................................................ p.19 Application and Use ........................................ p.25 Safety, Codes and Standards ............................... p.33

314

Hydrogen Storage Needs for Early Motive Fuel Cell Markets  

DOE Green Energy (OSTI)

The National Renewable Energy Laboratory's (NREL) objective for this project is to identify performance needs for onboard energy storage of early motive fuel cell markets by working with end users, manufacturers, and experts. The performance needs analysis is combined with a hydrogen storage technology gap analysis to provide the U.S. Department of Energy (DOE) Fuel Cell Technologies Program with information about the needs and gaps that can be used to focus research and development activities that are capable of supporting market growth.

Kurtz, J.; Ainscough, C.; Simpson, L.; Caton, M.

2012-11-01T23:59:59.000Z

315

Hydrogen Storage Systems Anlaysis Working Group Meeting, December 12, 2006  

NLE Websites -- All DOE Office Websites (Extended Search)

Argonne National Laboratory DC Offices 955 L'Enfant Plaza, North, SW, Suite 6000 Washington, DC December 12, 2006 SUMMARY REPORT Compiled by Romesh Kumar Argonne National Laboratory and Laura Verduzco Sentech, Inc. February 28, 2007 SUMMARY REPORT Hydrogen Storage Systems Analysis Working Group Meeting December 12, 2006 955 L'Enfant Plaza, North, SW, Suite 6000, Washington, DC Meeting Objectives This meeting was one of a continuing series of biannual meetings of this Working Group. The objective of these meetings is to bring together the DOE research community involved in systems analysis of hydrogen storage materials and processes for information exchange and to update the researchers on related developments within the DOE program. A major thrust of

316

Advanced Hydrogen Storage: A System's Perspective and Some Thoughts on Fundamentals  

NLE Websites -- All DOE Office Websites (Extended Search)

90246.00 90246.00 Advanced Hydrogen Storage: A System's Perspective and Some Thoughts on Fundamentals Presentation for DOE Workshop on Hydrogen Storage August 14-15, 2002 1/16 WPT MR 90246.00 In the development of attractive hydrogen storage options, fundamental materials properties and their impact on system design are both critical. * Compact, light, and efficient hydrogen storage technology is a key enabling technology for fuel cell vehicles and the use of renewable energy in vehicles * Due to system-level limitations current hydrogen storage systems meet some of the requirements but none meet all of the requirements - Current storage materials do not offer clear advantages over compressed or liquid hydrogen storage - Improving storage capacity will require improvement in material performance such

317

Boron-nitrogen-hydrogen (BNH) compounds: recent developments in hydrogen storage, applications in hydrogenation and catalysis, and new syntheses  

Science Conference Proceedings (OSTI)

The strong efforts devoted to the exploration of BNH compounds for hydrogen storage have led to impressive advances in the field of boron chemistry. This review summarizes progress in this field from three aspects. It starts with the most recent developments in using BNH compounds for hydrogen storage, covering NH3BH3, B3H8 containing compounds, and CBN compounds. The following section then highlights interesting applications of BNH compounds in hydrogenation and catalysis. The last part is focused on breakthroughs in the syntheses and discovery of new BNH organic analogues. The role of N?H?+H?-?B dihydrogen interactions in molecule packing, thermal hydrogen evolution, and syntheses is also discussed within the review. Part of this research is supported by the U.S. Department of Energys Basic Energy Sciences, Division of Chemical Sciences, Biosciences and Geosciences. Pacific Northwest National Laboratory is operated by Battelle.

Huang, Zhenguo; Autrey, Thomas

2012-11-15T23:59:59.000Z

318

Vehicular hydrogen storage using lightweight tanks (regenerative fuel cell systems)  

DOE Green Energy (OSTI)

Energy storage systems with extremely high specific energy (>400 Wh/kg) have been designed that use lightweight tankage to contain the gases generated by reversible (unitized) regenerative fuel cells (URFCs). Lawrence Livermore National Laboratory (LLNL) will leverage work for aerospace applications supported by other sponsors (including BMDO, NASA, and USAF) to develop URFC systems for transportation and utility applications. Lightweight tankage is important for primary fuel cell powered vehicles that use on-board storage of hydrogen. Lightweight pressure vessels with state-of-the-art performance factors were designed, and prototypes are being fabricated to meet the DOE 2000 goals (4000 Wh/kg, 12% hydrogen by weight, 700 Wh/liter, and $20/kWh in high volume production). These pressure vessels use technologies that are easily adopted by industrial partners. Advanced liners provide permeation barriers for gas storage and are mandrels for composite overwrap. URFCs are important to the efficient use of hydrogen as a transportation fuel and enabler of renewable energy. H{sub 2}/halogen URFCs may be advantageous for stationary applications whereas H{sub 2}/O{sub 2} or H{sub 2}/air URFCs are advantageous for vehicular applications. URFC research and development is required to improve performance (efficiency), reduce catalyst loading, understand engineering operation, and integrate systems. LLNL has the experimental equipment and advanced URFC membrane electrode assemblies (some with reduced catalyst loading) for evaluating commercial hardware (not funded by DOE in FY1999).

Mitlitsky, F; Myers, B; Weisberg, A H

1999-06-01T23:59:59.000Z

319

ACCEPTABILITY ENVELOPE FOR METAL HYDRIDE-BASED HYDROGEN STORAGE SYSTEMS  

DOE Green Energy (OSTI)

The design and evaluation of media based hydrogen storage systems requires the use of detailed numerical models and experimental studies, with significant amount of time and monetary investment. Thus a scoping tool, referred to as the Acceptability Envelope, was developed to screen preliminary candidate media and storage vessel designs, identifying the range of chemical, physical and geometrical parameters for the coupled media and storage vessel system that allow it to meet performance targets. The model which underpins the analysis allows simplifying the storage system, thus resulting in one input-one output scheme, by grouping of selected quantities. Two cases have been analyzed and results are presented here. In the first application the DOE technical targets (Year 2010, Year 2015 and Ultimate) are used to determine the range of parameters required for the metal hydride media and storage vessel. In the second case the most promising metal hydrides available are compared, highlighting the potential of storage systems, utilizing them, to achieve 40% of the 2010 DOE technical target. Results show that systems based on Li-Mg media have the best potential to attain these performance targets.

Hardy, B.; Corgnale, C.; Tamburello, D.; Garrison, S.; Anton, D.

2011-07-18T23:59:59.000Z

320

NREL Wind to Hydrogen Project: Renewable Hydrogen Production for Energy Storage & Transportation  

NLE Websites -- All DOE Office Websites (Extended Search)

Wind to Hydrogen Project: Wind to Hydrogen Project: Renewable Hydrogen Production for Energy Storage & Transportation NREL Hydrogen Technologies and Systems Center Todd Ramsden, Kevin Harrison, Darlene Steward November 16, 2009 NREL/PR-560-47432 NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy, operated by the Alliance for Sustainable Energy, LLC. NREL Wind2H2 RD&D Project * The National Renewable Energy Laboratory in partnership with Xcel Energy and DOE has designed, operates, and continues to perform testing on the wind-to-hydrogen (Wind2H2) project at the National Wind Technology Center in Boulder * The Wind2H2 project integrates wind turbines, PV arrays and electrolyzers to produce from renewable energy

Note: This page contains sample records for the topic "delivery hydrogen storage" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Hydrogen Storage Needs for Early Motive Fuel Cell Markets  

NLE Websites -- All DOE Office Websites (Extended Search)

Storage Needs for Storage Needs for Early Motive Fuel Cell Markets J. Kurtz, C. Ainscough, L. Simpson, and M. Caton Technical Report NREL/TP-5600-52783 November 2012 NREL is a national laboratory of the U.S. Department of Energy, Office of Energy Efficiency & Renewable Energy, operated by the Alliance for Sustainable Energy, LLC. National Renewable Energy Laboratory 15013 Denver West Parkway Golden, Colorado 80401 303-275-3000 * www.nrel.gov Contract No. DE-AC36-08GO28308 Hydrogen Storage Needs for Early Motive Fuel Cell Markets J. Kurtz, C. Ainscough, L. Simpson, and M. Caton Prepared under Task No. H272.4410 Technical Report NREL/TP-5600-52783 November 2012 NOTICE This report was prepared as an account of work sponsored by an agency of the United States government.

322

Hydrogen Delivery Pipeline Working Group Workshop September 25-26, 2007 Center for Hydrogen Research, Aiken, GA  

E-Print Network (OSTI)

Hydrogen Delivery Pipeline Working Group Workshop September 25-26, 2007 Center for Hydrogen.............................................................................................................. 1 2. Pipeline Working Group Plans for Round Robin Testing and Routine Research Testing...................................................................................................... 2 3. Facilitated Discussion on Planned DOE Steel Pipeline Routine Research Testing: ASME and PWG

323

Down Select Report of Chemical Hydrogen Storage Materials, Catalysts, and Spent Fuel Regeneration Processes  

DOE Green Energy (OSTI)

The DOE Hydrogen Storage Program is focused on identifying and developing viable hydrogen storage systems for onboard vehicular applications. The program funds exploratory research directed at identifying new materials and concepts for storage of hydrogen having high gravimetric and volumetric capacities that have the potential to meet long term technical targets for onboard storage. Approaches currently being examined are reversible metal hydride storage materials, reversible hydrogen sorption systems, and chemical hydrogen storage systems. The latter approach concerns materials that release hydrogen in endothermic or exothermic chemical bond-breaking processes. To regenerate the spent fuels arising from hydrogen release from such materials, chemical processes must be employed. These chemical regeneration processes are envisioned to occur offboard the vehicle.

Ott, Kevin; Linehan, Sue; Lipiecki, Frank; Aardahl, Christopher L.

2008-08-24T23:59:59.000Z

324

DOE Hydrogen and Fuel Cells Program: 2005 Annual Progress Report - Storage  

NLE Websites -- All DOE Office Websites (Extended Search)

Storage Storage Printable Version 2005 Annual Progress Report VI. Storage This section of the 2005 Progress Report for the DOE Hydrogen Program focuses on storage. Each technical report is available as an individual Adobe Acrobat PDF. Download Adobe Reader. Hydrogen Storage Sub-program Overview, Sunita Satyapal, Department of Energy (PDF 244 KB) A. Metal Hydrides Catalytically Enhanced Hydrogen Storage Systems, Craig M. Jensen, University of Hawaii (PDF 441 KB) High Density Hydrogen Storage System Demonstration using NaAlH4 Based Complex Compound Hydrides, Donald L. Anton, United Technologies Research Center (PDF 633 KB) Discovery of Novel Complex Metal Hydrides for Hydrogen Storage through Molecular Modeling and Combinatorial Methods, David A. Lesch, UOP LLC (PDF 308 KB)

325

Hydrogen storage in metalorganic frameworksw Leslie J. Murray, Mircea Dinca and Jeffrey R. Long*  

E-Print Network (OSTI)

Hydrogen storage in metal­organic frameworksw Leslie J. Murray, Mircea Dinca and Jeffrey R. Long. In this critical review we provide an overview of the current status of hydrogen storage within such compounds. In particular, hydrogen is an attractive energy carrier because it is carbon-free, abundantly available from

326

Storage of Hydrogen, Methane, and Carbon Dioxide in Highly Porous Covalent Organic Frameworks for Clean Energy  

E-Print Network (OSTI)

Storage of Hydrogen, Methane, and Carbon Dioxide in Highly Porous Covalent Organic Frameworks projects aimed at using hydrogen as a clean fuel for automobiles and producing clean energy by designing achieve higher storage capacities for hydrogen, (1) (a) Leaf, D.; Verolmec, H. J. H.; Hunt, W. F., Jr. En

Yaghi, Omar M.

327

Studies of solid state hydrogen storage materials by SAXS and QENS Qing Shi a, b  

E-Print Network (OSTI)

Studies of solid state hydrogen storage materials by SAXS and QENS Qing Shi a, b , Hjalte S on the Earth; moreover, the chemical energy per weight of hydrogen (142MJ/kg) is at least three times larger than that of other chemical fuels1 . However, hydrogen storage is still a key problem remaining

328

Hydrogen energy storage materials based on conducting polymers and their nanocomposites  

Science Conference Proceedings (OSTI)

Novel hydrogen energy storage materials based on electrically conducting polymers and their nanocompistes are reported. The synthesis and hydrogen adsorption properties of polypyrrole and its composites with nanotubes were investigated. The prepared ... Keywords: conducting polymers, hydrogen energy storage materials, nanocomposites, polypyrrole

Kurt E. Geckeler

2011-07-01T23:59:59.000Z

329

Hydrogen Storage in a Microporous Metal-Organic Framework with Exposed Mn2+ Coordination Sites  

E-Print Network (OSTI)

Hydrogen Storage in a Microporous Metal-Organic Framework with Exposed Mn2+ Coordination Sites and 90 bar, which at 60 g H2/L provides a storage density 85% of that of liquid hydrogen. The material-358. (2) EERE: Hydrogen, Fuel Cells, & Infrastructure Technologies Program Homepage, www.eere.energy

330

HIGH-THROUGHPUT/COMBINATORIAL TECHNIQUES IN HYDROGEN STORAGE MATERIALS R&D WORKSHOP  

E-Print Network (OSTI)

HIGH-THROUGHPUT/COMBINATORIAL TECHNIQUES IN HYDROGEN STORAGE MATERIALS R&D WORKSHOP U.S. Department of Energy Office of Hydrogen, Fuel Cells and Infrastructure Technologies June 26, 2007 Bethesda, MD On June 26, 2007, DOE's Hydrogen Storage Program held a one-day High- Throughput/Combinatorial Techniques

331

Vehicular Storage of Hydrogen in Insulated Pressure Vessels  

DOE Green Energy (OSTI)

This paper describes the development of an alternative technology for storing hydrogen fuel onboard automobiles. Insulated pressure vessels are cryogenic-capable pressure vessels that can accept cryogenic liquid fuel, cryogenic compressed gas or compressed gas at ambient temperature. Insulated pressure vessels offer advantages over conventional H{sub 2} storage approaches. Insulated pressure vessels are more compact and require less carbon fiber than GH{sub 2} vessels. They have lower evaporative losses than LH{sub 2} tanks, and are much lighter than metal hydrides. After outlining the advantages of hydrogen fuel and insulated pressure vessels, the paper describes the experimental and analytical work conducted to verify that insulated pressure vessels can be used safely for vehicular H{sub 2} storage. The paper describes tests that have been conducted to evaluate the safety of insulated pressure vessels. Insulated pressure vessels have successfully completed a series of DOT, ISO and SAE certification tests. A draft procedure for insulated pressure vessel certification has been generated to assist in a future commercialization of this technology. An insulated pressure vessel has been installed in a hydrogen fueled truck and it is currently being subjected to extensive testing.

Aceves, S M; Berry, G D; Martinez-Frias, J; Espinosa-Loza, F

2005-01-03T23:59:59.000Z

332

ENERGY Hydrogen Pipeline Material Testing Facility  

Science Conference Proceedings (OSTI)

... enable safe and economical transport, delivery and storage of hydrogen fuel, an abun- dant, clean-burning alternative to conventional fossil fuels. ...

2013-01-31T23:59:59.000Z

333

Fuel Cell & Hydrogen Technologies | Clean Energy | ORNL  

NLE Websites -- All DOE Office Websites (Extended Search)

cell systems and for the practical generation, storage, and delivery of hydrogen as an energy carrier. The lab's Fuel Cell Technologies Program conducts its research and...

334

Hydrogen, Fuel Cells, & Infrastructure - Program Areas - Energy...  

NLE Websites -- All DOE Office Websites (Extended Search)

fuel cell Welcome> Program Areas> Program Areas Hydrogen, Fuel Cells & Infrastructure Production & Delivery | Storage | Fuel Cell R&D | Systems Integration & Analysis | Safety...

335

Analyses of HydrogenAnalyses of Hydrogen Storage Materials and OnStorage Materials and On--  

E-Print Network (OSTI)

Excluded from DOE Cost Estimate OEM ­ Original Equipment Manufacturer G&A ­ General and Administration Manufacturing Processes and Equipment ·Determine Material and Processing Costs ·Develop Bulk Cost Assumptions basis On-Board Cost Estimate Estimate Bill-of-Material factory costs for the on-board storage system

336

Hydrogen Storage at Ambient Temperature by the Spillover Mechanism  

DOE Green Energy (OSTI)

The goal of this project was to develop new nanostructured sorbent materials, using the hydrogen spillover mechanism that could meet the DOE 2010 system targets for on-board vehicle hydrogen storage. Hydrogen spillover may be broadly defined as the transport (i.e., via surface diffusion) of dissociated hydrogen adsorbed or formed on a first surface onto another surface. The first surface is typically a metal (that dissociates H2) and the second surface is typically the support on which the metal is doped. Hydrogen spillover is a well documented phenomenon in the catalysis literature, and has been known in the catalysis community for over four decades, although it is still not well understood.1, 2 Much evidence has been shown in the literature on its roles played in catalytic reactions. Very little has been studied on hydrogen storage by spillover at ambient temperature. However, it is also known to occur at such temperature, e.g., direct evidence has been shown for spillover on commercial fuel-cell, highly dispersed Pt/C, Ru/C and PtRu/C catalysts by inelastic neutron scattering.3 To exploit spillover for storage, among the key questions are whether spillover is reversible at ambient temperature and if the adsorption (refill) and desorption rates at ambient temperature are fast enough for automotive applications. In this project, we explored new sorbents by using a transition metal (e.g., Pt, Ru, Pd and Ni) as the H2 dissociation source and sorbents as the hydrogen receptor. The receptors included superactivated carbons (AX-21 and Maxsorb), metal organic frameworks (MOFs) and zeolites. Different metal doping methods have been used successfully to achieve high metal dispersion thereby allowing significant spillover enhancements, as well as a bridging technique used for bridging to MOFs. Among the metals tested, Pt is the hardest to achieve high metal dispersion (and consequently spillover) while Ru is the easiest to disperse. By properly dispersing Pt on superactivated carbons (by following detailed doping and activation conditions given in our publications, e.g., Ref. 12), the storage capacities are increased two-fold (doubled) while slightly more than doubled by Ru doping. The bridging technique remains highly empirical and sample-to-sample consistency is difficult to achieve; however, significant enhancements by spillover can be achieved if the synthesis and pretreatment are done properly. Pitfalls in sample syntheses for both metal doped and bridged sorbents are pointed out in the report; deviations from the synthesis and pretreatment conditions will lead to diminished or no spillover effects. Due to the high bulk densities of zeolites, metal doped zeolites are shown to be most promising for achieving high volumetric storage capacities by spillover. Kinetics of both spillover and reverse spillover (i.e., desorption) at ambient temperature are also studied. This report summarizes the progress made in the project.

Yang , Ralph T.

2011-02-04T23:59:59.000Z

337

Material synthesis and hydrogen storage of palladium-rhodium alloy.  

DOE Green Energy (OSTI)

Pd and Pd alloys are candidate material systems for Tr or H storage. We have actively engaged in material synthesis and studied the material science of hydrogen storage for Pd-Rh alloys. In collaboration with UC Davis, we successfully developed/optimized a supersonic gas atomization system, including its processing parameters, for Pd-Rh-based alloy powders. This optimized system and processing enable us to produce {le} 50-{mu}m powders with suitable metallurgical properties for H-storage R&D. In addition, we studied hydrogen absorption-desorption pressure-composition-temperature (PCT) behavior using these gas-atomized Pd-Rh alloy powders. The study shows that the pressure-composition-temperature (PCT) behavior of Pd-Rh alloys is strongly influenced by its metallurgy. The plateau pressure, slope, and H/metal capacity are highly dependent on alloy composition and its chemical distribution. For the gas-atomized Pd-10 wt% Rh, the absorption plateau pressure is relatively high and consistent. However, the absorption-desorption PCT exhibits a significant hysteresis loop that is not seen from the 30-nm nanopowders produced by chemical precipitation. In addition, we observed that the presence of hydrogen introduces strong lattice strain, plastic deformation, and dislocation networking that lead to material hardening, lattice distortions, and volume expansion. The above observations suggest that the H-induced dislocation networking is responsible for the hysteresis loop seen in the current atomized Pd-10 wt% Rh powders. This conclusion is consistent with the hypothesis suggested by Flanagan and others (Ref 1) that plastic deformation or dislocations control the hysteresis loop.

Lavernia, Enrique J. (University of California, Davis); Yang, Nancy Y. C.; Ong, Markus D. (Whithworth University, Spokane, WA)

2011-08-01T23:59:59.000Z

338

Destabilized and catalyzed borohydride for reversible hydrogen storage  

SciTech Connect

A process of forming a hydrogen storage material, including the steps of: providing a borohydride material of the formula: M(BH.sub.4).sub.x where M is an alkali metal or an alkaline earth metal and 1.ltoreq.x.ltoreq.2; providing an alanate material of the formula: M.sub.1(AlH.sub.4).sub.x where M.sub.1 is an alkali metal or an alkaline earth metal and 1.ltoreq.x.ltoreq.2; providing a halide material of the formula: M.sub.2Hal.sub.x where M.sub.2 is an alkali metal, an alkaline earth metal or transition metal and Hal is a halide and 1.ltoreq.x.ltoreq.4; combining the borohydride, alanate and halide materials such that 5 to 50 molar percent from the borohydride material is present forming a reaction product material having a lower hydrogen release temperature than the alanate material.

Mohtadi, Rana F. (Northville, MI); Zidan, Ragaiy (Aiken, SC); Gray, Joshua (Aiken, SC); Stowe, Ashley C. (Knoxville, TN); Sivasubramanian, Premkumar (Aiken, SC)

2012-02-28T23:59:59.000Z

339

Hydrogen Trailer Storage Facility (Building 878). Consequence analysis  

DOE Green Energy (OSTI)

The Department of Energy Order 5500.3A requires facility-specific hazards assessments be prepared, maintained, and used for emergency planning purposes. This consequence analysis documents the impact that a hydrogen accident could have to employees, the general public, and nearby facilities. The computer model ARCHIE was utilized to determine discharge rates, toxic vapor dispersion analyses, flammable vapor cloud hazards, explosion hazards, and flame jets for the Hydrogen Trailer Storage Facility located at Building 878. To determine over pressurization effects, hand calculations derived from the Department of the Air Force Manual, ``Structures to Resist the Effects of Accidental Explosions,`` were utilized. The greatest distances at which a postulated facility event will produce the Lower Flammability and the Lower Detonation Levels are 1,721 feet and 882 feet, respectively. The greatest distance at which 10.0 psi overpressure (i.e., total building destruction) is reached is 153 feet.

Banda, Z.; Wood, C.L.

1994-12-01T23:59:59.000Z

340

Inorganic Chemistry in Hydrogen Storage and Biomass Catalysis  

DOE Green Energy (OSTI)

Making or breaking C-H, B-H, C-C bonds has been at the core of catalysis for many years. Making or breaking these bonds to store or recover energy presents us with fresh challenges, including how to catalyze these transformations in molecular systems that are 'tuned' to minimize energy loss and in molecular and material systems present in biomass. This talk will discuss some challenging transformations in chemical hydrogen storage, and some aspects of the inorganic chemistry we are studying in the development of catalysts for biomass utilization.

Thorn, David [Los Alamos National Laboratory

2012-06-13T23:59:59.000Z

Note: This page contains sample records for the topic "delivery hydrogen storage" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Electrolysis-based hydrogen storage systems. Annual report, January 1, 1978-December 31, 1978  

DOE Green Energy (OSTI)

Contract management, technical monitoring and in-house research conducted by Brookhaven National Laboratory for the US Department of Energy, Division of Energy Storage as described. The status of each project within four major areas of investigation is summarize. Activities deal with: (1) Electrolytic Production of Hydrogen; (2) Hydrogen Storage Systems; (3) Hydrogen Storage Materials; and (4) Systems Studies/End-Use Applications. The BNL programmatic responsibilities encompass the direction of 17 contractors and a $3,200,000 budget.

Not Available

1979-04-01T23:59:59.000Z

342

Hydrogen-Bromine Flow Battery: Hydrogen Bromine Flow Batteries for Grid Scale Energy Storage  

SciTech Connect

GRIDS Project: LBNL is designing a flow battery for grid storage that relies on a hydrogen-bromine chemistry which could be more efficient, last longer and cost less than todays lead-acid batteries. Flow batteries are fundamentally different from traditional lead-acid batteries because the chemical reactants that provide their energy are stored in external tanks instead of inside the battery. A flow battery can provide more energy because all that is required to increase its storage capacity is to increase the size of the external tanks. The hydrogen-bromine reactants used by LBNL in its flow battery are inexpensive, long lasting, and provide power quickly. The cost of the design could be well below $100 per kilowatt hour, which would rival conventional grid-scale battery technologies.

2010-10-01T23:59:59.000Z

343

Lifecycle Cost Analysis of Hydrogen Versus Other Technologies for Electrical Energy Storage  

Fuel Cell Technologies Publication and Product Library (EERE)

This report presents the results of an analysis evaluating the economic viability of hydrogen for medium- to large-scale electrical energy storage applications compared with three other storage techno

344

Technical Assessment of Organic Liquid Carrier Hydrogen Storage Systems for Automotive Applications  

Fuel Cell Technologies Publication and Product Library (EERE)

In 2007-2009, the DOE Hydrogen Program conducted a technical assessment of organic liquid carrier based hydrogen storage systems for automotive applications, consistent with the Programs Multiyear Re

345

Lifecycle Cost and GHG Implications of a Hydrogen Energy Storage Scenario (Presentation)  

Science Conference Proceedings (OSTI)

Overview of life cycle cost and green house gas implications of a hydrogen energy storage scenario presented at the National Hydrogen Association Conference & Expo, Long Beach, CA, May 3-6, 2010

Steward, D. M.

2010-05-01T23:59:59.000Z

346

Analysis of Hydrogen and Competing Technologies for Utility-Scale Energy Storage (Presentation)  

SciTech Connect

Presentation about the National Renewable Energy Laboratory's analysis of hydrogen energy storage scenarios, including analysis framework, levelized cost comparison of hydrogen and competing technologies, analysis results, and conclusions drawn from the analysis.

Steward, D.

2010-02-11T23:59:59.000Z

347

Analysis of Hydrogen and Competing Technologies for Utility-Scale Energy Storage (Presentation)  

DOE Green Energy (OSTI)

Presentation about the National Renewable Energy Laboratory's analysis of hydrogen energy storage scenarios, including analysis framework, levelized cost comparison of hydrogen and competing technologies, analysis results, and conclusions drawn from the analysis.

Steward, D.

2010-02-11T23:59:59.000Z

348

High-Capacity Hydrogen-Based Green-Energy Storage Solutions for ...  

Science Conference Proceedings (OSTI)

Integrating intermittent renewable energy sources, by safe and cost-effective energy storage systems based on solid state hydrogen is today achievable thanks...

349

Go No-Go Decision: Pure, Undoped, Single Walled Carbon Nanotubes for Vehicular Hydrogen Storage  

Fuel Cell Technologies Publication and Product Library (EERE)

This document provides information about the go/no-go decision on pure, undoped single walled carbon nanotubes for vehicular hydrogen storage.

350

Hydrogen Storage in Nano-Phase Diamond at High Temperature and Its Release  

DOE Green Energy (OSTI)

The objectives of this proposed research were: 91) Separation and storage of hydrogen on nanophase diamonds. It is expected that the produced hydrogen, which will be in a mixture, can be directed to a nanophase diamond system directly, which will not only store the hydrogen, but also separate it from the gas mixture, and (2) release of the stored hydrogen from the nanophase diamond.

Tushar K Ghosh

2008-10-13T23:59:59.000Z

351

Hydrogen storage material and process using graphite additive with metal-doped complex hydrides  

DOE Patents (OSTI)

A hydrogen storage material having improved hydrogen absorbtion and desorption kinetics is provided by adding graphite to a complex hydride such as a metal-doped alanate, i.e., NaAlH.sub.4. The incorporation of graphite into the complex hydride significantly enhances the rate of hydrogen absorbtion and desorption and lowers the desorption temperature needed to release stored hydrogen.

Zidan, Ragaiy (Aiken, SC); Ritter, James A. (Lexington, SC); Ebner, Armin D. (Lexington, SC); Wang, Jun (Columbia, SC); Holland, Charles E. (Cayce, SC)

2008-06-10T23:59:59.000Z

352

Joint Meeting on Hydrogen Delivery Modeling and Analysis, May...  

NLE Websites -- All DOE Office Websites (Extended Search)

Delivery Model: Discussion Items, Comments, and Follow-up Actions 1. Pipeline Pressures: Transmission, Trunk, and Distribution lines - Early on it may be difficult to do anything...

353

DOE Hydrogen Analysis Repository: H2A Delivery Scenario Analysis...  

NLE Websites -- All DOE Office Websites (Extended Search)

Scenario Analysis Model (HDSAM) Project Summary Full Title: H2A Delivery Scenario Analysis Model (HDSAM) Project ID: 218 Principal Investigator: Marianne Mintz Keywords: Models;...

354

DOE Hydrogen and Fuel Cells Program Record 9017: On-Board Hydrogen Storage Systems … Projected Performance and Cost Parameters  

NLE Websites -- All DOE Office Websites (Extended Search)

DOE Hydrogen and Fuel Cells Program Record DOE Hydrogen and Fuel Cells Program Record Record #: 9017 Date: July 02, 2010 Title: On-Board Hydrogen Storage Systems - Projected Performance and Cost Parameters Originators: Robert C. Bowman and Ned Stetson Approved by: Sunita Satyapal Date: August 10, 2010 This record summarizes the current technical assessments of hydrogen (H 2 ) storage system capacities and projected manufacturing costs for the scenario of high-volume production (i.e., 500,000 units/year) for various types of "on-board" vehicular storage systems. These analyses were performed within the Hydrogen Storage sub-program of the DOE Fuel Cell Technologies (FCT) program of the Office of Energy Efficiency and Renewable Energy. Item: It is important to note that all system capacities are "net useable capacities" able to be delivered to the

355

Hydrogen Fueling Systems and Infrastructure  

E-Print Network (OSTI)

Hydrogen Fueling Systems and Infrastructure Storage & Delivery Production Conversion & Application emissions: renewable based feedstock · Flexibility #12;Targets and Status Hydrogen Delivery 858280%Energyk1.2M1.4M$/mileTrunk lines Hydrogen Gas Pipelines 877065%Energy efficiency 0.531.011.11$/kg H2Cost

356

Hydrogen Pathways: Cost, Well-to-Wheels Energy Use, and Emissions for the Current Technology Status of Seven Hydrogen Production, Delivery, and Distribution Scenarios  

DOE Green Energy (OSTI)

Report of levelized cost in 2005 U.S. dollars, energy use, and GHG emission benefits of seven hydrogen production, delivery, and distribution pathways.

Ruth, M.; Laffen, M.; Timbario, T. A.

2009-09-01T23:59:59.000Z

357

Hydrogen Pathways: Cost, Well-to-Wheels Energy Use, and Emissions for the Current Technology Status of Seven Hydrogen Production, Delivery, and Distribution Scenarios  

Fuel Cell Technologies Publication and Product Library (EERE)

Report of levelized cost in 2005 U.S. dollars, energy use, and GHG emission benefits of seven hydrogen production, delivery, and distribution pathways.

358

Hydrogen Storage Properties of Magnesium Base Nanostructured Composite Materials  

DOE Green Energy (OSTI)

In this work, nanostructured composite materials have been synthesized using the mechanical alloying process. The new materials produced have been investigated by X-ray diffraction (XRD), transition electron microscope (TEM), scanning electron microscope (SEM) and electron energy dispersion spectrum (EDS) for their phase compositions, crystal structure, grain size, particle morphology and the distribution of catalyst element. Hydrogen storage capacities and the hydriding-dehydriding kinetics of the new materials have been measured at different temperatures using a Sieverts apparatus. It is observed that mechanical alloying accelerates the hydrogenation kinetics of the magnesium based materials at low temperature, but a high temperature must be provided to release the absorbed hydrogen from the hydrided magnesium based materials. It is believed that the dehydriding temperature is largely controlled by the thermodynamic configuration of magnesium hydride. Doping Mg-Ni nano/amorphous composite materials with lanthanum reduces the hydriding and dehydriding temperature. Although the stability of MgH2 can not be easily reduced by ball milling alone, the results suggest the thermodynamic properties of Mg-Ni nano/amorphous composite materials can be alternated by additives such as La or other effective elements. Further investigation toward understanding the mechanism of additives will be rewarded.

AU, M

2004-04-30T23:59:59.000Z

359

Systems and methods for facilitating hydrogen storage using naturally occurring nanostructure assemblies  

SciTech Connect

Some or all of the needs above can be addressed by embodiments of the invention. According to embodiments of the invention, systems and methods for facilitating hydrogen storage using naturally occurring nanostructure assemblies can be implemented. In one embodiment, a method for storing hydrogen can be provided. The method can include providing diatoms comprising diatomaceous earth or diatoms from a predefined culture. In addition, the method can include heating the diatoms in a sealed environment in the presence of at least one of titanium, a transition metal, or a noble metal to provide a porous hydrogen storage medium. Furthermore, the method can include exposing the porous hydrogen storage medium to hydrogen. In addition, the method can include storing at least a portion of the hydrogen in the porous hydrogen storage medium.

Fliermans; , Carl B. (Augusta, GA)

2012-08-07T23:59:59.000Z

360

Method and System for Hydrogen Evolution and Storage  

DOE Patents (OSTI)

A method and system for storing and evolving hydrogen employ chemical compounds that can be hydrogenated to store hydrogen and dehydrogenated to evolve hydrogen. A catalyst lowers the energy required for storing and evolving hydrogen. The method and system can provide hydrogen for devices that consume hydrogen as fuel.

Thorn, David L. (Los Alamos, NM); Tumas, William (Los Alamos, NM); Hay, P. Jeffrey (Los Alamos, NM); Schwarz, Daniel E. (Los Alamos, NM); Cameron, Thomas M. (Los Alamos, NM)

2008-10-21T23:59:59.000Z

Note: This page contains sample records for the topic "delivery hydrogen storage" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Method and system for hydrogen evolution and storage  

DOE Patents (OSTI)

A method and system for storing and evolving hydrogen (H.sub.2) employ chemical compounds that can be hydrogenated to store hydrogen and dehydrogenated to evolve hydrogen. A catalyst lowers the energy required for storing and evolving hydrogen. The method and system can provide hydrogen for devices that consume hydrogen as fuel.

Thorn, David L.; Tumas, William; Hay, P. Jeffrey; Schwarz, Daniel E.; Cameron, Thomas M.

2012-12-11T23:59:59.000Z

362

Method and system for hydrogen evolution and storage - Energy ...  

A method and system for storing and evolving hydrogen employ chemical compounds that can be hydrogenated to store hydrogen and dehydrogenated to ...

363

Determining the lowest-cost hydrogen delivery mode  

E-Print Network (OSTI)

transport due to primary energy usage (from electricity andFor this analysis, the energy usage for liquefaction (11tent. Reducing the energy usage for hydrogen distribution

Yang, Christopher; Ogden, Joan M

2007-01-01T23:59:59.000Z

364

Determining the Lowest-Cost Hydrogen Delivery Mode  

E-Print Network (OSTI)

For this analysis, the energy usage for liquefaction (11sum of the rate of energy usage of the various components ofcontent. Reducing the energy usage for hydrogen distribution

Yang, Christopher; Ogden, Joan M

2008-01-01T23:59:59.000Z

365

Summary status of advanced water electrolysis and hydrogen storage/transport R and D  

SciTech Connect

Major projects within the framework of the U.S. DOE Chemical/Hydrogen Energy Systems Program are described. Goals, accomplishments and status of investigations into advanced water electrolysis and hydrogen storage/transport are summarized. Electrolytic hydrogen production systems include: SPE electrolyzers; static feed water electrolysis; high temperature electrolysis; and other advanced concepts. Hydrogen transport studies have emphasized the characterization of hydrogen embrittlement effects on conventional natural gas pipeline steels.

Mezzina, A.

1984-04-01T23:59:59.000Z

366

Porous iron and ferric oxide pellets for hydrogen storage: texture and transport characteristics  

Science Conference Proceedings (OSTI)

Materials for hydrogen storage based on the recovery reduction of Fe3O4 to iron and back iron oxidation to Fe3O4 by water vapor were studied. The preparation conditions for cylindrical pellets from ferric oxide/aluminium ... Keywords: hydrogen storage, inverse gas chromatography, steam iron process, transport parameters

Karel Soukup; Jan Rogut; Jacek Grabowski; Marian Wiatowski; Magdalena Ludwik-Parda?a; Petr Schneider; Olga olcov

2010-11-01T23:59:59.000Z

367

Uranium for hydrogen storage applications : a materials science perspective.  

DOE Green Energy (OSTI)

Under appropriate conditions, uranium will form a hydride phase when exposed to molecular hydrogen. This makes it quite valuable for a variety of applications within the nuclear industry, particularly as a storage medium for tritium. However, some aspects of the U+H system have been characterized much less extensively than other common metal hydrides (particularly Pd+H), likely due to radiological concerns associated with handling. To assess the present understanding, we review the existing literature database for the uranium hydride system in this report and identify gaps in the existing knowledge. Four major areas are emphasized: {sup 3}He release from uranium tritides, the effects of surface contamination on H uptake, the kinetics of the hydride phase formation, and the thermal desorption properties. Our review of these areas is then used to outline potential avenues of future research.

Shugard, Andrew D.; Tewell, Craig R.; Cowgill, Donald F.; Kolasinski, Robert D.

2010-08-01T23:59:59.000Z

368

Hydrogen production and delivery analysis in US markets : cost, energy and greenhouse gas emissions.  

DOE Green Energy (OSTI)

Hydrogen production cost conclusions are: (1) Steam Methane Reforming (SMR) is the least-cost production option at current natural gas prices and for initial hydrogen vehicle penetration rates, at high production rates, SMR may not be the least-cost option; (2) Unlike coal and nuclear technologies, the cost of natural gas feedstock is the largest contributor to SMR production cost; (3) Coal- and nuclear-based hydrogen production have significant penalties at small production rates (and benefits at large rates); (4) Nuclear production of hydrogen is likely to have large economies of scale, but because fixed O&M costs are uncertain, the magnitude of these effects may be understated; and (5) Given H2A default assumptions for fuel prices, process efficiencies and labor costs, nuclear-based hydrogen is likely to be more expensive to produce than coal-based hydrogen. Carbon taxes and caps can narrow the gap. Hydrogen delivery cost conclusions are: (1) For smaller urban markets, compressed gas delivery appears most economic, although cost inputs for high-pressure gas trucks are uncertain; (2) For larger urban markets, pipeline delivery is least costly; (3) Distance from hydrogen production plant to city gate may change relative costs (all results shown assume 100 km); (4) Pipeline costs may be reduced with system 'rationalization', primarily reductions in service pipeline mileage; and (5) Liquefier and pipeline capital costs are a hurdle, particularly at small market sizes. Some energy and greenhouse gas Observations: (1) Energy use (per kg of H2) declines slightly with increasing production or delivery rate for most components (unless energy efficiency varies appreciably with scale, e.g., liquefaction); (2) Energy use is a strong function of production technology and delivery mode; (3) GHG emissions reflect the energy efficiency and carbon content of each component in a production-delivery pathway; (4) Coal and natural gas production pathways have high energy consumption and significant GHG emissions (in the absence of carbon caps, taxes or sequestration); (5) Nuclear pathway is most favorable from energy use and GHG emissions perspective; (6) GH2 Truck and Pipeline delivery have much lower energy use and GHG emissions than LH2 Truck delivery; and (7) For LH2 Truck delivery, the liquefier accounts for most of the energy and GHG emissions.

Mintz, M.; Gillette, J.; Elgowainy, A. (Decision and Information Sciences); ( ES)

2009-01-01T23:59:59.000Z

369

DOE to Invest up to $8.2 Million for Hydrogen Storage Research | Department  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

up to $8.2 Million for Hydrogen Storage Research up to $8.2 Million for Hydrogen Storage Research DOE to Invest up to $8.2 Million for Hydrogen Storage Research April 12, 2007 - 12:36pm Addthis WASHINGTON, DC - U.S. Department of Energy (DOE) Secretary Samuel W. Bodman today announced DOE plans to provide up to $8.2 million, over four years (FY'07-'10), for six hydrogen storage research projects, directly supporting President Bush's Advanced Energy Initiative (AEI). The AEI aims to increase our energy security and reduce our reliance on imported oil by changing the way we power our cars, homes and businesses. These projects, subject to negotiation of scope and funding, are also integral to the President's Hydrogen Fuel Initiative. "As a clean energy technology, hydrogen has great potential to help reduce

370

HT Combinatorial Screening of Novel Materials for High Capacity Hydrogen Storage  

NLE Websites -- All DOE Office Websites (Extended Search)

FLORIDA SOLAR ENERGY CENTER FLORIDA SOLAR ENERGY CENTER Creating Energy Independence Since 1975 A Research Institute of the University of Central Florida HT Combinatorial Screening of HT Combinatorial Screening of Novel Materials for High Capacity Novel Materials for High Capacity Hydrogen Storage Hydrogen Storage Ali T Ali T - - Raissi Raissi Director, Hydrogen & Fuel Cell R&D Director, Hydrogen & Fuel Cell R&D Division Division High Throughput/Combinatorial Analysis of Hydrogen Storage High Throughput/Combinatorial Analysis of Hydrogen Storage Materials Workshop, Bethesda, MD Materials Workshop, Bethesda, MD 26 June 2007 26 June 2007 This presentation does not contain any proprietary or confidential information 2 Objectives Objectives Develop (i.e. design, build, test and verify) a high

371

DOE to Invest up to $8.2 Million for Hydrogen Storage Research | Department  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

to Invest up to $8.2 Million for Hydrogen Storage Research to Invest up to $8.2 Million for Hydrogen Storage Research DOE to Invest up to $8.2 Million for Hydrogen Storage Research April 12, 2007 - 12:36pm Addthis WASHINGTON, DC - U.S. Department of Energy (DOE) Secretary Samuel W. Bodman today announced DOE plans to provide up to $8.2 million, over four years (FY'07-'10), for six hydrogen storage research projects, directly supporting President Bush's Advanced Energy Initiative (AEI). The AEI aims to increase our energy security and reduce our reliance on imported oil by changing the way we power our cars, homes and businesses. These projects, subject to negotiation of scope and funding, are also integral to the President's Hydrogen Fuel Initiative. "As a clean energy technology, hydrogen has great potential to help reduce

372

Manufacturing Cost Analysis of Novel Steel/Concrete Composite Vessel for Stationary Storage of High-Pressure Hydrogen  

SciTech Connect

A novel, low-cost, high-pressure, steel/concrete composite vessel (SCCV) technology for stationary storage of compressed gaseous hydrogen (CGH2) is currently under development at Oak Ridge National Laboratory (ORNL) sponsored by DOE s Fuel Cell Technologies (FCT) Program. The SCCV technology uses commodity materials including structural steels and concretes for achieving cost, durability and safety requirements. In particular, the hydrogen embrittlement of high-strength low-alloy steels, a major safety and durability issue for current industry-standard pressure vessel technology, is mitigated through the use of a unique layered steel shell structure. This report presents the cost analysis results of the novel SCCV technology. A high-fidelity cost analysis tool is developed, based on a detailed, bottom-up approach which takes into account the material and labor costs involved in each of the vessel manufacturing steps. A thorough cost study is performed to understand the SCCV cost as a function of the key vessel design parameters, including hydrogen pressure, vessel dimensions, and load-carrying ratio. The major conclusions include: The SCCV technology can meet the technical/cost targets set forth by DOE s FCT Program for FY2015 and FY2020 for all three pressure levels (i.e., 160, 430 and 860 bar) relevant to the hydrogen production and delivery infrastructure. Further vessel cost reduction can benefit from the development of advanced vessel fabrication technologies such as the highly automated friction stir welding (FSW). The ORNL-patented multi-layer, multi-pass FSW can not only reduce the amount of labor needed for assembling and welding the layered steel vessel, but also make it possible to use even higher strength steels for further cost reductions and improvement of vessel structural integrity. It is noted the cost analysis results demonstrate the significant cost advantage attainable by the SCCV technology for different pressure levels when compared to the industry-standard pressure vessel technology. The real-world performance data of SCCV under actual operating conditions is imperative for this new technology to be adopted by the hydrogen industry for stationary storage of CGH2. Therefore, the key technology development effort in FY13 and subsequent years will be focused on the fabrication and testing of SCCV mock-ups. The static loading and fatigue data will be generated in rigorous testing of these mock-ups. Successful tests are crucial to enabling the near-term impact of the developed storage technology on the CGH2 storage market, a critical component of the hydrogen production and delivery infrastructure. In particular, the SCCV has high potential for widespread deployment in hydrogen fueling stations.

Feng, Zhili [ORNL; Zhang, Wei [ORNL; Wang, Jy-An John [ORNL; Ren, Fei [ORNL

2012-09-01T23:59:59.000Z

373

HYDROGEN PRODUCTION AND DELIVERY INFRASTRUCTURE AS A COMPLEX ADAPTIVE SYSTEM  

Science Conference Proceedings (OSTI)

An agent-based model of the transition to a hydrogen transportation economy explores influences on adoption of hydrogen vehicles and fueling infrastructure. Attention is given to whether significant penetration occurs and, if so, to the length of time required for it to occur. Estimates are provided of sensitivity to numerical values of model parameters and to effects of alternative market and policy scenarios. The model is applied to the Los Angeles metropolitan area In the benchmark simulation, the prices of hydrogen and non-hydrogen vehicles are comparable. Due to fuel efficiency, hydrogen vehicles have a fuel savings advantage of 9.8 cents per mile over non-hydrogen vehicles. Hydrogen vehicles account for 60% of new vehicle sales in 20 years from the initial entry of hydrogen vehicles into show rooms, going on to 86% in 40 years and reaching still higher values after that. If the fuel savings is 20.7 cents per mile for a hydrogen vehicle, penetration reaches 86% of new car sales by the 20th year. If the fuel savings is 0.5 cents per mile, market penetration reaches only 10% by the 20th year. To turn to vehicle price difference, if a hydrogen vehicle costs $2,000 less than a non-hydrogen vehicle, new car sales penetration reaches 92% by the 20th year. If a hydrogen vehicle costs $6,500 more than a non-hydrogen vehicle, market penetration is only 6% by the 20th year. Results from other sensitivity runs are presented. Policies that could affect hydrogen vehicle adoption are investigated. A tax credit for the purchase of a hydrogen vehicle of $2,500 tax credit results in 88% penetration by the 20th year, as compared with 60% in the benchmark case. If the tax credit is $6,000, penetration is 99% by the 20th year. Under a more modest approach, the tax credit would be available only for the first 10 years. Hydrogen sales penetration then reach 69% of sales by the 20th year with the $2,500 credit and 79% with the $6,000 credit. A carbon tax of $38 per metric ton is not large enough to noticeably affect sales penetration. A tax of $116 per metric ton makes centrally produced hydrogen profitable in the very first year but results in only 64% penetration by year 20 as opposed to the 60% penetration in the benchmark case. Provision of 15 seed stations publicly provided at the beginning of the simulation, in addition to the 15 existing stations in the benchmark case, gives sales penetration rates very close to the benchmark after 20 years, namely, 63% and 59% depending on where they are placed.

Tolley, George S

2010-06-29T23:59:59.000Z

374

DOE Hydrogen and Fuel Cells Program: Hydrogen Analysis Resource Center  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen Production Hydrogen Production Hydrogen Delivery Hydrogen Storage Hydrogen Manufacturing Fuel Cells Applications/Technology Validation Safety Codes and Standards Education Basic Research Systems Analysis Analysis Repository H2A Analysis Hydrogen Analysis Resource Center Scenario Analysis Well-to-Wheels Analysis Systems Integration U.S. Department of Energy Search help Home > Systems Analysis > Hydrogen Analysis Resource Center Printable Version Hydrogen Analysis Resource Center The Hydrogen Analysis Resource Center provides consistent and transparent data that can serve as the basis for hydrogen-related calculations, modeling, and other analytical activities. This new site features the Hydrogen Data Book with data pertinent to hydrogen infrastructure analysis; links to external databases related to

375

A National Vision of America's Transition to a Hydrogen Economy...  

NLE Websites -- All DOE Office Websites (Extended Search)

Involves thermal, electrolytic, and photolytic processes Delivery The distribution of hydrogen from production and storage sites Involves pipelines, trucks, barges, and fueling...

376

Hydrogen Storage in Wind Turbine Towers: Cost Analysis and Conceptual Design; Preprint  

Science Conference Proceedings (OSTI)

Low-cost hydrogen storage is recognized as a cornerstone of a renewables-hydrogen economy. Modern utility-scale wind turbine towers are typically conical steel structures that, in addition to supporting the rotor, could be used to store hydrogen. The most cost-effective hydrogen tower design would use substantially all of its volume for hydrogen storage and be designed at its crossover pressure. An 84-m tall hydrogen tower for a 1.5-MW turbine would cost an additional $84,000 (beyond the cost of the conventional tower) and would store 950 kg of hydrogen. The resulting incremental storage cost of $88/kg is approximately 30% of that for conventional pressure vessels.

Kottenstette, R.; Cotrell, J.

2003-09-01T23:59:59.000Z

377

Overview of Two Hydrogen Energy Storage Studies: Wind Hydrogen in California and Blending in Natural Gas Pipelines (Presentation)  

DOE Green Energy (OSTI)

This presentation provides an overview of two NREL energy storage studies: Wind Hydrogen in California: Case Study and Blending Hydrogen Into Natural Gas Pipeline Networks: A Review of Key Issues. The presentation summarizes key issues, major model input assumptions, and results.

Melaina, M. W.

2013-05-01T23:59:59.000Z

378

Chemical bridges for enhancing hydrogen storage by spillover and methods for forming the same  

SciTech Connect

A composition for hydrogen storage includes a source of hydrogen atoms, a receptor, and a chemical bridge formed between the source and the receptor. The chemical bridge is formed from a precursor material. The receptor is adapted to receive hydrogen spillover from the source.

Yang, Ralph T.; Li, Yingwei; Qi, Gongshin; Lachawiec, Jr., Anthony J.

2012-12-25T23:59:59.000Z

379

Determining the lowest-cost hydrogen delivery mode  

E-Print Network (OSTI)

pressure b Storage Gas truck station (G) 30% a,b Liquid H 2for compressed gas truck stations compared to pipelineplant Compressed gas trucks Refueling station a (compressor,

Yang, Christopher; Ogden, Joan M

2007-01-01T23:59:59.000Z

380

Hydrogen Delivery Analysis Plus Meeting: DTT, STT, HPTT, Other...  

NLE Websites -- All DOE Office Websites (Extended Search)

vehicle storage and the role for H2A tools. * Present the HyPro and Hytrans Transition Scenario models * Define next steps for H2A models relative to overall HFI analysis needs...

Note: This page contains sample records for the topic "delivery hydrogen storage" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Thermodynamically Tuned Nanophase Materials for Reversible Hydrogen Storage: Structure and Kinetics of Nanoparticle and Model System Materials  

DOE Green Energy (OSTI)

This is the final report of our program on hydrogen storage in thin film and nanoparticle metal hydrides.

Bruce M. Clemens

2010-08-26T23:59:59.000Z

382

Impact of Metal and Anion Substitutions on the Hydrogen Storage Properties of MBTT Metal-Organic Frameworks  

E-Print Network (OSTI)

of Energy (DoE) system performance targets for mobile hydrogen storage systems,3 which specify minimumImpact of Metal and Anion Substitutions on the Hydrogen Storage Properties of MBTT Metal-organic frameworks are a class of materials being vigorously investigated for mobile hydrogen storage applications

383

Hydrogen Absorption in Fluids: An Unexplored Solution for Onboard Hydrogen Storage  

DOE Green Energy (OSTI)

Adoption of hydrogen (H{sub 2}) vehicles has been advocated for decades as an ecological ideal, capable of eliminating petroleum consumption as well as tail-pipe air pollution and carbon dioxide (CO{sub 2}) from automobiles. Storing sufficient hydrogen fuel onboard still remains a great technological challenge, despite recent advances in lightweight automotive materials, hybrid-electric drivetrains and fuel cells enabling 60-100 mpg equivalent H{sub 2}-fueled automobiles. Future onboard hydrogen storage choices will be pivotal, with lasting strategic consequences for the eventual scale, shape, security, investment requirements, and energy intensity of the H{sub 2} refueling infrastructure, in addition to impacts on automotive design, cost, range, performance, and safety. Multiple hydrogen storage approaches have been examined and deployed onboard prototype automobiles since the 1970's. These include storing H{sub 2} as a cryogenic liquid (LH{sub 2}) at temperatures of 20-25 Kelvin, compressing room temperature H{sub 2} gas to pressures as high as 10,000 psi, and reversible chemical absorption storage within powdered metal hydrides (e.g. LaNi{sub 5}H{sub 6}, TiFeH{sub 2}, MgH{sub 2}, NaAlH{sub 4}) which evolve H{sub 2} when warmed. Each of these approaches face well-known fundamental physical limits (thermal endurance, volume, and weight, respectively). This report details preliminary experiments investigating the potential of a new approach to H{sub 2} storage: absorption in fluids, specifically liquid nitrogen (LN{sub 2}). N{sub 2} was chosen for this study because it offers unique advantages as an inert but lightweight solvent with high hydrogen solubility and is an abundant atmospheric component. H{sub 2} absorbed in liquid nitrogen (LN{sub 2}) can be lighter than metal hydrides, with greater thermal endurance than cryogenic H{sub 2} or LH{sub 2}, while being more compact than ambient compressed H{sub 2}. Previous researchers have examined H{sub 2} mixed with a variety of simple molecular fluids (N{sub 2}, Ar, CH{sub 4}, CO). These studies were mainly aimed at the general problem of fluid phase equilibria of H{sub 2} mixtures, and focused on identification and prediction of fluid/liquid phase boundary pressures and temperatures. In contrast, the present experiments are aimed at measuring the PVT properties of H{sub 2}/N{sub 2} mixtures with a view toward evaluating the applicability of these mixtures for onboard automotive H{sub 2} storage. To our knowledge, the experiments conducted for this project are the first systematic density measurements of H{sub 2}/N{sub 2} mixtures at cryogenic temperatures. H{sub 2}/N{sub 2} mixtures containing 50, 60, and 70% mole fraction H{sub 2} were examined at temperatures of 77 K, 87 K, and 273 K, under pressures ranging from 500 to 30,000 psi (from 34 to 2000 atm), corresponding to molar densities of 15-30 moles per liter.

Berry, G D

2005-02-10T23:59:59.000Z

384

Materials Dow Select Decisions Made Within DOEs Chemical Hydrogen Storage Center of Excellence  

NLE Websites -- All DOE Office Websites (Extended Search)

Down Select Report of Chemical Hydrogen Down Select Report of Chemical Hydrogen Storage Materials, Catalysts, and Spent Fuel Regeneration Processes Chemical Hydrogen Storage Center of Excellence FY2008 Second Quarter Milestone Report Submitted by: The Chemical Hydrogen Storage Center of Excellence Coordinating Council Authors: Kevin C. Ott, Los Alamos National Laboratory Sue Linehan, Rohm and Haas Company Frank Lipiecki, Rohm and Haas Company Christopher L. Aardahl, Pacific Northwest National Laboratory May 2008 Acknowledgements The authors of this report wish to thank all of the partners of the Chemical Hydrogen Storage Center of Excellence. Without their dedication, technical contributions and teamwork, and the hard work of the students and postdocs involved in this work, this Center would not have been

385

HIERARCHICAL METHODOLOGY FOR MODELING HYDROGEN STORAGE SYSTEMS PART II: DETAILED MODELS  

DOE Green Energy (OSTI)

There is significant interest in hydrogen storage systems that employ a media which either adsorbs, absorbs or reacts with hydrogen in a nearly reversible manner. In any media based storage system the rate of hydrogen uptake and the system capacity is governed by a number of complex, coupled physical processes. To design and evaluate such storage systems, a comprehensive methodology was developed, consisting of a hierarchical sequence of models that range from scoping calculations to numerical models that couple reaction kinetics with heat and mass transfer for both the hydrogen charging and discharging phases. The scoping models were presented in Part I [1] of this two part series of papers. This paper describes a detailed numerical model that integrates the phenomena occurring when hydrogen is charged and discharged. A specific application of the methodology is made to a system using NaAlH{sub 4} as the storage media.

Hardy, B; Donald L. Anton, D

2008-12-22T23:59:59.000Z

386

Hydrogen, Fuel Cells & Infrastructure Technologies Research  

E-Print Network (OSTI)

generation, storage, and delivery of hydrogen as an energy carrier. Hydrogen Production & Delivery Research and Electricity Energy Delivery (i.e., the "Super Grid" concept) · · · · · · · · · · · Development of Efficient Research Center has just begun operation of a UTC phosphoric acid fuel cell to provide heating, cooling

387

Enabling Utility-Scale Electrical Energy Storage through Underground Hydrogen-Natural Gas Co-Storage.  

E-Print Network (OSTI)

??Energy storage technology is needed for the storage of surplus baseload generation and the storage of intermittent wind power, because it can increase the flexibility (more)

Peng, Dan

2013-01-01T23:59:59.000Z

388

Abstract--A novel methodology for economic evaluation of hydrogen storage for a mixed wind-nuclear power plant is  

E-Print Network (OSTI)

Abstract--A novel methodology for economic evaluation of hydrogen storage for a mixed wind-nuclear of the operation of the combined nuclear-wind-hydrogen system is discussed first, where the selling and buying.e. transmission congestion. Index Terms--wind power, nuclear power, hydrogen storage, Hydrogen Economy, power

Cañizares, Claudio A.

389

Room Temperature Hydrogen Storage in Nano-Confined Liquids -...  

NLE Websites -- All DOE Office Websites (Extended Search)

measurements of * hydrogen solubility in volatile liquid solvents in both bulk form and nano-confined liquidscaffold composites. Demonstrate volumetric measurements of hydrogen *...

390

NMR Study of Borohydrides for Hydrogen Storage Applications.  

E-Print Network (OSTI)

??There is great interest today in developing a hydrogen economy, and hydrogen powered vehicles to replace vehicles powered by fossil fuels. This presents many challenges (more)

Shane, David

2011-01-01T23:59:59.000Z

391

Hydrogen Storage in Carbon Nanotubes Through Formation of C-H Bonds  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen Storage in Carbon Hydrogen Storage in Carbon Nanotubes Through Formation of C-H Bonds Hydrogen Storage in Carbon Nanotubes Through Formation of C-H Bonds Print Wednesday, 28 June 2006 00:00 Two of the major challenges for humanity in the next 20 years are the shrinking availability of fossil fuels and the global warming and potential climate changes that result from their ever-increasing use. One possible solution to these problems is to use an energy carrier such as hydrogen, and ways to produce and store hydrogen in electric power plants and vehicles is a major research focus for materials scientists and chemists. To realize hydrogen-powered transport, for example, it is necessary to find ways to store hydrogen onboard vehicles efficiently and safely. Nanotechnology in the form of single-walled carbon nanotubes provides a candidate storage medium. A U.S., German, and Swedish collaboration led by researchers from the Stanford Synchrotron Radiation Laboratory (SSRL) used ALS Beamline 11.0.2 and SSRL Beamline 5-1 to investigate the chemical interaction of hydrogen with single-walled carbon nanotubes (SWCNs). Their findings demonstrate substantial hydrogen storage is both feasible and reversible.

392

Fuel Cell Technologies Program Multi-Year Research, Development and Demonstration Plan - Section 3.2 Hydrogen Delivery  

NLE Websites -- All DOE Office Websites (Extended Search)

Technical Plan - Delivery Technical Plan - Delivery Multi-Year Research, Development and Demonstration Plan Page 3.2 - 1 3.2 Hydrogen Delivery Delivery is an essential component of any future hydrogen infrastructure. It encompasses those processes needed to transport hydrogen from a central or semi-central production facility to the final point of use and those required to load the energy carrier directly onto a given fuel cell system. Successful commercialization of hydrogen-fueled fuel cell systems, including those used in vehicles, back-up power sources, and distributed power generators, will likely depend on a hydrogen delivery infrastructure that provides the same level of safety, convenience, and functionality as existing liquid and gaseous fossil

393

Novel Molecular Materials for Hydrogen Storage Applications - DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report  

NLE Websites -- All DOE Office Websites (Extended Search)

6 6 DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report Maddury Somayazulu (Primary Contact), Timothy Strobel, Robert Potter, Raja Chellappa, Viktor Struzhkin, Russell J Hemley Geophysical Laboratory Carnegie Institution of Washington 5251 Broad Branch Rd NW Washington, D.C. 20015 Phone: (202) 478-8911 Email: zulu@gl.ciw.edu DOE Program Manager: Dr. P. Thiyagarajan Phone: (301) 903-9706 Email: P.Thiyagarajan@science.doe.gov Objectives Discover, identify and characterize novel hydrogen-rich * compounds that can be used for hydrogen storage or as agents for rehydrogenation of hydrogen storage materials at high pressures. Investigate high pressure routes to rehydrogenating * ammonia borane and polymeric complexes of ammonia borane. Investigate interaction of hydrogen with metallo-organic *

394

2H2A Hydrogen Delivery Infrastructure Analysis Models and Conventional Pathway Options Analysis Results - Interim Report  

NLE Websites -- All DOE Office Websites (Extended Search)

H2A Hydrogen Delivery Infrastructure Analysis Models and H2A Hydrogen Delivery Infrastructure Analysis Models and Conventional Pathway Options Analysis Results DE-FG36-05GO15032 Interim Report Nexant, Inc., Air Liquide, Argonne National Laboratory, Chevron Technology Venture, Gas Technology Institute, National Renewable Energy Laboratory, Pacific Northwest National Laboratory, and TIAX LLC May 2008 Contents Section Page Executive Summary ................................................................................................................... 1-9 Delivery Options ...................................................................................................................... 1-9 Evaluation of Options 2 and 3 ................................................................................................. 1-9

395

Computational studies of hydrogen interactions with storage materials - DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report  

NLE Websites -- All DOE Office Websites (Extended Search)

6 6 DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report Chris G. Van de Walle (Primary Contact), Lars Ismer, Anindya Roy, and Anderson Janotti Materials Department, University of California Santa Barbara, CA 93106-5050 Phone: (805) 893-7144 Email: vandewalle@mrl.ucsb.edu DOE Program Officer: James Davenport Phone: (301) 903-0035 Email: James.Davenport@science.doe.gov Objectives Building on our accumulated knowledge of hydrogen interactions with semiconductors and insulators we have been conducting computational studies with the goal of developing new insights for hydrogen interactions with hydrogen storage materials. Using state-of-the-art density functional calculations, our research addresses the energetics

396

Implementing a Hydrogen Energy Infrastructure: Storage Options and System Design  

E-Print Network (OSTI)

hydrogen as for a future transportation fuel. Several recentattention as a future transportation fuel. Fuel cell

Ogden, J; Yang, Christopher

2005-01-01T23:59:59.000Z

397

DOE Hydrogen and Fuel Cells Program Record 12001: H2 Production and Delivery Cost Apportionment  

NLE Websites -- All DOE Office Websites (Extended Search)

01 Date: May 14, 2012 01 Date: May 14, 2012 Title: H 2 Production and Delivery Cost Apportionment Originator: Scott Weil, Sara Dillich, Fred Joseck, and Mark Ruth Approved by: Sunita Satyapal and Rick Farmer Date: December 14, 2012 Item: The hydrogen threshold cost is defined as the untaxed cost of hydrogen (H 2 ) (produced, delivered, and dispensed) at which hydrogen fuel cell electric vehicles (FCEVs) are projected to become competitive on a $/mile basis with competing vehicles [gasoline in hybrid-electric vehicles (HEVs)] in 2020. As established in Record 11007 [1], this cost ranges from $2.00-$4.00/gge a of H 2 (based on $2007). The threshold cost can be apportioned into its constituent H 2 production and delivery costs, which can then serve as the respective cost targets for multi-year planning of the Fuel Cell Technologies (FCT)

398

Technical Assessment of Compressed Hydrogen Storage Tank Systems for Automotive Applications  

Fuel Cell Technologies Publication and Product Library (EERE)

This technical report describes DOE's assessment of the performance and cost of compressed hydrogen storage tank systems for automotive applications. The on-board performance (by Argonne National Lab)

399

Synthesis and characterization of metal hydride/carbon aerogel composites for hydrogen storage  

Science Conference Proceedings (OSTI)

Two materials currently of interest for onboard lightweight hydrogen storage applications are sodium aluminum hydride (NaAlH4), a complex metal hydride, and carbon aerogels (CAs), a light porous material connected by several spherical nanoparticles. ...

Kuen-Song Lin; Yao-Jen Mai; Su-Wei Chiu; Jing-How Yang; Sammy L. I. Chan

2012-01-01T23:59:59.000Z

400

High Density Hydrogen Storage System Demonstration Using NaAlH4 Based Complex Compound Hydrides  

DOE Green Energy (OSTI)

This final report describes the motivations, activities and results of the hydrogen storage independent project "High Density Hydrogen Storage System Demonstration Using NaAlH4 Based Complex Compound Hydrides" performed by the United Technologies Research Center under the Department of Energy Hydrogen Program, contract # DE-FC36-02AL67610. The objectives of the project were to identify and address the key systems technologies associated with applying complex hydride materials, particularly ones which differ from those for conventional metal hydride based storage. This involved the design, fabrication and testing of two prototype systems based on the hydrogen storage material NaAlH4. Safety testing, catalysis studies, heat exchanger optimization, reaction kinetics modeling, thermochemical finite element analysis, powder densification development and material neutralization were elements included in the effort.

Daniel A. Mosher; Xia Tang; Ronald J. Brown; Sarah Arsenault; Salvatore Saitta; Bruce L. Laube; Robert H. Dold; Donald L. Anton

2007-07-27T23:59:59.000Z

Note: This page contains sample records for the topic "delivery hydrogen storage" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

F-3: Hydrogen Storage Properties of Graphite-modified MgNiCe ...  

Science Conference Proceedings (OSTI)

Abstract Scope, The Mg17Ni1.5Ce0.5 hydrogen storage composites with different contents of graphite were prepared by a new method of mechanical milling...

402

Hydrogen Storage in Carbon Nanotubes Through Formation of C-H...  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen Storage in Carbon Nanotubes Through Formation of C-H Bonds Print Two of the major challenges for humanity in the next 20 years are the shrinking availability of fossil...

403

System Level Analysis of Hydrogen Storage Options - DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report  

NLE Websites -- All DOE Office Websites (Extended Search)

4 4 DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report Rajesh K. Ahluwalia (Primary Contact), T. Q. Hua, J-K Peng, Hee Seok Roh, and Romesh Kumar Argonne National Laboratory 9700 South Cass Avenue Argonne, IL 60439 Phone: (630) 252-5979 Email: walia@anl.gov DOE Manager HQ: Grace Ordaz Phone: (202) 586-8350 Email: Grace.Ordaz@ee.doe.gov Start Date: October 1, 2004 Projected End Date: September 30, 2014 Objective The overall objective of this effort is to support DOE with independent system level analyses of various H 2 storage approaches, to help to assess and down-select options, and to determine the feasibility of meeting DOE targets. Fiscal Year (FY) 2012 Objectives Model various developmental hydrogen storage systems. * Provide results to Hydrogen Storage Engineering Center *

404

Hydrogen Storage Cost Analysis, Preliminary Results - DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report  

NLE Websites -- All DOE Office Websites (Extended Search)

2 2 DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report Brian D. James (Primary Contact), Andrew B. Spisak, Whitney G. Colella Strategic Analysis, Inc. 4075 Wilson Blvd. Suite 200 Arlington, VA 22203 Phone: (703) 778-7114 E-mail: bjames@sainc.com DOE Managers HQ: Grace Ordaz Phone: (202) 586-8350 Email: Grace.Ordaz@ee.doe.gov GO: Katie Randolph Phone: (720) 356-1759 Email: Katie.Randolph@go.doe.gov Contract Number: DE-EE0005253 Project Start Date: September 30, 2012 Project End Date: September 29, 2016 Fiscal Year (FY) 2012 Objectives Develop cost models of carbon fiber hydrogen storage * pressure vessels. Explore the sensitivity of pressure vessel cost to design * parameters including hydrogen storage quantity, storage

405

A Basic, and Slightly Acidic, Solution to Hydrogen Storage | Department of  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

A Basic, and Slightly Acidic, Solution to Hydrogen Storage A Basic, and Slightly Acidic, Solution to Hydrogen Storage A Basic, and Slightly Acidic, Solution to Hydrogen Storage March 23, 2012 - 2:17pm Addthis Brookhaven researchers Etsuko Fujita, Jonathan Hull, and James Muckerman developed a new catalyst that reversibly converts hydrogen gas and carbon dioxide to a liquid under very mild conditions. Their findings were published in the March 18th issue of Nature Chemistry. | Photo courtesy of Brookhaven National Lab. Brookhaven researchers Etsuko Fujita, Jonathan Hull, and James Muckerman developed a new catalyst that reversibly converts hydrogen gas and carbon dioxide to a liquid under very mild conditions. Their findings were published in the March 18th issue of Nature Chemistry. | Photo courtesy of Brookhaven National Lab.

406

Tank Farm Contractor Phase 1 Feed Delivery and Storage and Disposal Mission Summary for 2006 Hot Start Extended Order  

SciTech Connect

This is the level one logic diagram for the River Protection Project (RPP), Tank Farm Contractor, Phase 1, Feed Delivery Storage and Disposal Mission Summary for 2006 Hot Start.

DAVIS, T.J.

2000-04-24T23:59:59.000Z

407

DOE Hydrogen and Fuel Cells Program: News Archives - 2007  

NLE Websites -- All DOE Office Websites (Extended Search)

7 7 January February April May June July August September October November December January DOE Announces New Funding Opportunity for Hydrogen Production and Delivery Research DOE Issues Federal Register Notice Soliciting Input on Sodium Borohydride for Hydrogen Storage Research DOE Releases Hydrogen Posture Plan Online Course Focuses on Hydrogen Safety for First Responders February DOE Announces Funding Opportunities for Hydrogen and Fuel Cell Analysis Workshop Focuses on Hydrogen Sensors April DOE Announces R&D Solicitation Selections for Hydrogen Storage DOE Requests Information on Early Markets for Hydrogen and Fuel Cells DOE Requests Information on Planned Hydrogen Storage Engineering Science Center of Excellence New DOE Employment Opportunity Available in Hydrogen Production

408

Underground hydrogen storage. Final report. [Salt caverns, excavated caverns, aquifers and depleted fields  

DOE Green Energy (OSTI)

The technical and economic feasibility of storing hydrogen in underground storage reservoirs is evaluated. The past and present technology of storing gases, primarily natural gas is reviewed. Four types of reservoirs are examined: salt caverns, excavated caverns, aquifers, and depleted fields. A technical investigation of hydrogen properties reveals that only hydrogen embrittlement places a limit on the underground storage by hydrogen. This constraint will limit reservoir pressures to 1200 psi or less. A model was developed to determine economic feasibility. After making reasonable assumptions that a utility might make in determining whether to proceed with a new storage operation, the model was tested and verified on natural gas storage. A parameteric analysis was made on some of the input parameters of the model to determine the sensitivity of the cost of service to them. Once the model was verified it was used to compute the cost of service of storing hydrogen in the four reservoir types. The costs of service for hydrogen storage ranged from 26 to 150% of the cost of the gas stored. The study concludes that it is now both safe and economic to store hydrogen in underground reservoirs.

Foh, S.; Novil, M.; Rockar, E.; Randolph, P.

1979-12-01T23:59:59.000Z

409

Electrolysis based hydrogen storage systems. Annual report, January 1, 1976--December 31, 1976  

SciTech Connect

This report describes work completed during the period January 1, 1976 to December 31, 1976, on an ERDA-sponsored program aimed at improvement in the cost and efficiency of electrolytic hydrogen production and development of the technique of using metal hydrides for hydrogen storage for stationary and transportation applications. The work on electrolytic hydrogen production includes work on advanced barrier materials for alkaline cells, studies of nickel alloy based and oxide catalysts for oxygen evolution. Related work on the program involving the H/sub 2/--Cl/sub 2/ electrochemical cell for energy storage is described. Work on hydrogen storage subsystems involving storage reservoir designs for the Hydrogen Technology Advanced-Component Test System (HYTACTS), engineering and metal hydride material test beds and tests of candidate container materials is presented. Progress on the development of new metal hydride materials and tailoring and testing of new alloy systems is summarized. This work emphasizes improvement in the initial activation step, high-cycle test of selected materials and the physical characteristics of cycled materials. The efforts on natural gas supplementation, hydrogen storage systems analysis and the project management of the ERDA Hydrogen Program by BNL are summarized.

Salzano, F J

1977-01-01T23:59:59.000Z

410

Complex Hydride Compounds with Enhanced Hydrogen Storage Capacity  

DOE Green Energy (OSTI)

The United Technologies Research Center (UTRC), in collaboration with major partners Albemarle Corporation (Albemarle) and the Savannah River National Laboratory (SRNL), conducted research to discover new hydride materials for the storage of hydrogen having on-board reversibility and a target gravimetric capacity of ? 7.5 weight percent (wt %). When integrated into a system with a reasonable efficiency of 60% (mass of hydride / total mass), this target material would produce a system gravimetric capacity of ? 4.5 wt %, consistent with the DOE 2007 target. The approach established for the project combined first principles modeling (FPM - UTRC) with multiple synthesis methods: Solid State Processing (SSP - UTRC), Solution Based Processing (SBP - Albemarle) and Molten State Processing (MSP - SRNL). In the search for novel compounds, each of these methods has advantages and disadvantages; by combining them, the potential for success was increased. During the project, UTRC refined its FPM framework which includes ground state (0 Kelvin) structural determinations, elevated temperature thermodynamic predictions and thermodynamic / phase diagram calculations. This modeling was used both to precede synthesis in a virtual search for new compounds and after initial synthesis to examine reaction details and options for modifications including co-reactant additions. The SSP synthesis method involved high energy ball milling which was simple, efficient for small batches and has proven effective for other storage material compositions. The SBP method produced very homogeneous chemical reactions, some of which cannot be performed via solid state routes, and would be the preferred approach for large scale production. The MSP technique is similar to the SSP method, but involves higher temperature and hydrogen pressure conditions to achieve greater species mobility. During the initial phases of the project, the focus was on higher order alanate complexes in the phase space between alkaline metal hydrides (AmH), Alkaline earth metal hydrides (AeH2), alane (AlH3), transition metal (Tm) hydrides (TmHz, where z=1-3) and molecular hydrogen (H2). The effort started first with variations of known alanates and subsequently extended the search to unknown compounds. In this stage, the FPM techniques were developed and validated on known alanate materials such as NaAlH4 and Na2LiAlH6. The coupled predictive methodologies were used to survey over 200 proposed phases in six quaternary spaces, formed from various combinations of Na, Li Mg and/or Ti with Al and H. A wide range of alanate compounds was examined using SSP having additions of Ti, Cr, Co, Ni and Fe. A number of compositions and reaction paths were identified having H weight fractions up to 5.6 wt %, but none meeting the 7.5 wt%H reversible goal. Similarly, MSP of alanates produced a number of interesting compounds and general conclusions regarding reaction behavior of mixtures during processing, but no alanate based candidates meeting the 7.5 wt% goal. A novel alanate, LiMg(AlH4)3, was synthesized using SBP that demonstrated a 7.0 wt% capacity with a desorption temperature of 150C. The deuteride form was synthesized and characterized by the Institute for Energy (IFE) in Norway to determine its crystalline structure for related FPM studies. However, the reaction exhibited exothermicity and therefore was not reversible under acceptable hydrogen gas pressures for on-board recharging. After the extensive studies of alanates, the material class of emphasis was shifted to borohydrides. Through SBP, several ligand-stabilized Mg(BH4)2 complexes were synthesized. The Mg(BH4)2*2NH3 complex was found to change behavior with slightly different synthesis conditions and/or aging. One of the two mechanisms was an amine-borane (NH3BH3) like dissociation reaction which released up to 16 wt %H and more conservatively 9 wt%H when not including H2 released from the NH3. From FPM, the stability of the Mg(BH4)2*2NH3 compound was found to increase with the inclusion of NH3 groups in the inner-Mg coordination

Mosher, Daniel A.; Opalka, Susanne M.; Tang, Xia; Laube, Bruce L.; Brown, Ronald J.; Vanderspurt, Thomas H.; Arsenault, Sarah; Wu, Robert; Strickler, Jamie; Anton, Donald L.; Zidan, Ragaiy; Berseth, Polly

2008-02-18T23:59:59.000Z

411

ass combustion CO2 capture coal conversion mat on biofuels geologic storage hydrogen renewables  

E-Print Network (OSTI)

ass combustion CO2 capture coal conversion mat on biofuels geologic storage hydrogen renewables storage fuel cells CO2 capture photovoltaics ma conversion biofuels batteries conversion biofuels stion CO Stanford University About GCEP #12;Explored novel approaches for enhanced biofuel production, such as

Nur, Amos

412

Hydrogen Storage in Carbon Nanotubes Through Formation of C-H Bonds  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen Storage in Carbon Nanotubes Through Formation of C-H Bonds Print Hydrogen Storage in Carbon Nanotubes Through Formation of C-H Bonds Print Two of the major challenges for humanity in the next 20 years are the shrinking availability of fossil fuels and the global warming and potential climate changes that result from their ever-increasing use. One possible solution to these problems is to use an energy carrier such as hydrogen, and ways to produce and store hydrogen in electric power plants and vehicles is a major research focus for materials scientists and chemists. To realize hydrogen-powered transport, for example, it is necessary to find ways to store hydrogen onboard vehicles efficiently and safely. Nanotechnology in the form of single-walled carbon nanotubes provides a candidate storage medium. A U.S., German, and Swedish collaboration led by researchers from the Stanford Synchrotron Radiation Laboratory (SSRL) used ALS Beamline 11.0.2 and SSRL Beamline 5-1 to investigate the chemical interaction of hydrogen with single-walled carbon nanotubes (SWCNs). Their findings demonstrate substantial hydrogen storage is both feasible and reversible.

413

Hydrogen Storage in Carbon Nanotubes Through Formation of C-H Bonds  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen Storage in Carbon Nanotubes Through Formation of C-H Bonds Print Hydrogen Storage in Carbon Nanotubes Through Formation of C-H Bonds Print Two of the major challenges for humanity in the next 20 years are the shrinking availability of fossil fuels and the global warming and potential climate changes that result from their ever-increasing use. One possible solution to these problems is to use an energy carrier such as hydrogen, and ways to produce and store hydrogen in electric power plants and vehicles is a major research focus for materials scientists and chemists. To realize hydrogen-powered transport, for example, it is necessary to find ways to store hydrogen onboard vehicles efficiently and safely. Nanotechnology in the form of single-walled carbon nanotubes provides a candidate storage medium. A U.S., German, and Swedish collaboration led by researchers from the Stanford Synchrotron Radiation Laboratory (SSRL) used ALS Beamline 11.0.2 and SSRL Beamline 5-1 to investigate the chemical interaction of hydrogen with single-walled carbon nanotubes (SWCNs). Their findings demonstrate substantial hydrogen storage is both feasible and reversible.

414

Hydrogen Storage in Carbon Nanotubes Through Formation of C-H Bonds  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen Storage in Carbon Nanotubes Through Formation of C-H Bonds Print Hydrogen Storage in Carbon Nanotubes Through Formation of C-H Bonds Print Two of the major challenges for humanity in the next 20 years are the shrinking availability of fossil fuels and the global warming and potential climate changes that result from their ever-increasing use. One possible solution to these problems is to use an energy carrier such as hydrogen, and ways to produce and store hydrogen in electric power plants and vehicles is a major research focus for materials scientists and chemists. To realize hydrogen-powered transport, for example, it is necessary to find ways to store hydrogen onboard vehicles efficiently and safely. Nanotechnology in the form of single-walled carbon nanotubes provides a candidate storage medium. A U.S., German, and Swedish collaboration led by researchers from the Stanford Synchrotron Radiation Laboratory (SSRL) used ALS Beamline 11.0.2 and SSRL Beamline 5-1 to investigate the chemical interaction of hydrogen with single-walled carbon nanotubes (SWCNs). Their findings demonstrate substantial hydrogen storage is both feasible and reversible.

415

Hydrogen Storage in Carbon Nanotubes Through Formation of C-H Bonds  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen Storage in Carbon Nanotubes Through Formation of C-H Bonds Print Hydrogen Storage in Carbon Nanotubes Through Formation of C-H Bonds Print Two of the major challenges for humanity in the next 20 years are the shrinking availability of fossil fuels and the global warming and potential climate changes that result from their ever-increasing use. One possible solution to these problems is to use an energy carrier such as hydrogen, and ways to produce and store hydrogen in electric power plants and vehicles is a major research focus for materials scientists and chemists. To realize hydrogen-powered transport, for example, it is necessary to find ways to store hydrogen onboard vehicles efficiently and safely. Nanotechnology in the form of single-walled carbon nanotubes provides a candidate storage medium. A U.S., German, and Swedish collaboration led by researchers from the Stanford Synchrotron Radiation Laboratory (SSRL) used ALS Beamline 11.0.2 and SSRL Beamline 5-1 to investigate the chemical interaction of hydrogen with single-walled carbon nanotubes (SWCNs). Their findings demonstrate substantial hydrogen storage is both feasible and reversible.

416

Hydrogen Storage in Carbon Nanotubes Through Formation of C-H Bonds  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen Storage in Carbon Nanotubes Through Formation of C-H Bonds Print Hydrogen Storage in Carbon Nanotubes Through Formation of C-H Bonds Print Two of the major challenges for humanity in the next 20 years are the shrinking availability of fossil fuels and the global warming and potential climate changes that result from their ever-increasing use. One possible solution to these problems is to use an energy carrier such as hydrogen, and ways to produce and store hydrogen in electric power plants and vehicles is a major research focus for materials scientists and chemists. To realize hydrogen-powered transport, for example, it is necessary to find ways to store hydrogen onboard vehicles efficiently and safely. Nanotechnology in the form of single-walled carbon nanotubes provides a candidate storage medium. A U.S., German, and Swedish collaboration led by researchers from the Stanford Synchrotron Radiation Laboratory (SSRL) used ALS Beamline 11.0.2 and SSRL Beamline 5-1 to investigate the chemical interaction of hydrogen with single-walled carbon nanotubes (SWCNs). Their findings demonstrate substantial hydrogen storage is both feasible and reversible.

417

Electrolysis based hydrogen storage system. Semiannual report, January 1--June 30, 1977  

SciTech Connect

The work described in this report was accomplished during the period January 1 to June 30, 1977 on an ERDA-sponsored program aimed at improving the cost and efficiency of electrolytic hydrogen production and at developing the technique of using metal-hydride hydrogen storage for stationary and transportation applications. The related work of organizations having subcontracts with BNL is included; and the effort on natural-gas supplementation, systems analysis, and project management of the ERDA Hydrogen Program by BNL are summarized. Work in the hydrogen production area includes hardware development and cell materials testing for both acid and alkaline water electrolyzers. Also reported is related work on development of the reversible H/sub 2/-Cl/sub 2/ electrochemical cell which is the key component in an electrical energy storage system proposed for utility use. In the area of Hydrogen Storage Subsystems, the progress is reported on solutions to the hydride expansion problem, design of the Hydrogen Technology Advanced Component Test System, design of two hydrogen reservoirs, improved Fe-Ti-based hydrides, and studies on the recovery of storage capacity following poisoning by impurities in the hydrogen.

Salzano, F.J.

1977-10-01T23:59:59.000Z

418

Influence of the pore size in multi-walled carbon nanotubes on the hydrogen storage behaviors  

SciTech Connect

Activated multi-walled carbon nanotubes (A-MWCNTs) were prepared using a chemical activation method to obtain well-developed pore structures for use as hydrogen storage materials. The microstructure and crystallinity of the A-MWCNTs were evaluated by X-ray diffraction and Fourier transform Raman spectroscopy. The textural properties of the A-MWCNTs were investigated by nitrogen gas sorption analysis at 77 K. The hydrogen storage capacity of the A-MWCNTs was evaluated at 77 K and 1 bar. The results showed that the specific surface area of the MWCNTs increased from 327 to 495 m{sup 2}/g as the activation temperature was increased. The highest hydrogen storage capacity was observed in the A-MWCNTs sample activated at 900 Degree-Sign C (0.54 wt%). This was attributed to it having the narrowest microporosity, which is a factor closely related to the hydrogen storage capacity. This shows that the hydrogen storage behaviors depend on the pore volume. Although a high pore volume is desirable for hydrogen storage, it is also severely affected if the pore size in the A-MWCNTs for the hydrogen molecules is suitable for creating the activation process. Highlights: Black-Right-Pointing-Pointer The AT-800 and AT-900 samples were prepared by a chemical activation method at activation temperature of 800 and 900 Degree-Sign C, respectively. Black-Right-Pointing-Pointer The AT-900 sample has the narrowest peak in comparison with the AT-800 sample, resulting from the overlap of the two peaks (Peak I and Peak II). Black-Right-Pointing-Pointer This overlapping effect is due to the newly created micropores or shrinkages of pores in Peak II. So, these determining characteristics are essential for designing materials that are suitable for molecular hydrogen storage.

Lee, Seul-Yi [Department of Chemistry, Inha University, 253, Nam-gu, Incheon 402-751 (Korea, Republic of)] [Department of Chemistry, Inha University, 253, Nam-gu, Incheon 402-751 (Korea, Republic of); Park, Soo-Jin, E-mail: sjpark@inha.ac.kr [Department of Chemistry, Inha University, 253, Nam-gu, Incheon 402-751 (Korea, Republic of)] [Department of Chemistry, Inha University, 253, Nam-gu, Incheon 402-751 (Korea, Republic of)

2012-10-15T23:59:59.000Z

419

Economic analysis of large-scale hydrogen storage for renewable utility applications.  

DOE Green Energy (OSTI)

The work reported here supports the efforts of the Market Transformation element of the DOE Fuel Cell Technology Program. The portfolio includes hydrogen technologies, as well as fuel cell technologies. The objective of this work is to model the use of bulk hydrogen storage, integrated with intermittent renewable energy production of hydrogen via electrolysis, used to generate grid-quality electricity. In addition the work determines cost-effective scale and design characteristics and explores potential attractive business models.

Schoenung, Susan M.

2011-08-01T23:59:59.000Z

420

Scenario Development and Analysis of Hydrogen as a Large-Scale Energy Storage Medium (Presentation)  

DOE Green Energy (OSTI)

The conclusions from this report are: (1) hydrogen has several important advantages over competing technologies, including - very high storage energy density (170 kWh/m{sup 3} vs. 2.4 for CAES and 0.7 for pumped hydro) which allows for potential economic viability of above-ground storage and relatively low environmental impact in comparison with other technologies; and (2) the major disadvantage of hydrogen energy storage is cost but research and deployment of electrolyzers and fuel cells may reduce cost significantly.

Steward, D. M.

2009-06-10T23:59:59.000Z

Note: This page contains sample records for the topic "delivery hydrogen storage" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Thermodynamic Guidelines for the Prediction of Hydrogen Storage Reactions and Their Application to Destabillzed Hydride Mixtures  

NLE Websites -- All DOE Office Websites (Extended Search)

Thermodynamic guidelines for the prediction of hydrogen Thermodynamic guidelines for the prediction of hydrogen storage reactions and their application to destabilized hydride mixtures Hydrogen Storage & Nanoscale Modeling Group Ford Motor Company Don Siegel dsiegel2@ford.com Phys. Rev. B 76, 134102 (2007) 1 Acknowledgements C. Wolverton V. Ozolins Computation Northwestern UCLA J. Yang A. Sudik Experiments Ford Ford 2 Computational Methodology * Atomistic computer simulations based on quantum mechanics (Density Functional Theory) * First-principles approach: - Only empirical input are crystal structure and fundamental physical constants - VASP code - PAW potentials - PW91 GGA - Temperature-dependent thermodynamic contributions evaluated within harmonic approximation * "Direct method" for construction of dynamical matrix

422

High Density Hydrogen Storage Systems Demonstration Using NaAIH4  

NLE Websites -- All DOE Office Websites (Extended Search)

Density Hydrogen Storage Density Hydrogen Storage System Demonstration Using NaAlH 4 Complex Compound Hydrides D. Mosher, X. Tang, S. Arsenault, B. Laube, M. Cao, R. Brown, S. Saitta, J. Costello United Technologies Research Center East Hartford, Connecticut Report to the U.S. Department of Energy (DOE) Contract Number: DE-FC36-02AL-67610 December 19, 2006 * * Presented to the DOE and the FreedomCAR & Fuel Partnership Hydrogen Storage Tech Team This presentation does not contain proprietary or confidential information 2 Overview Objective: Identify and overcome the critical technical barriers in developing complex hydride based storage systems, especially those which differ from conventional metal hydride systems, to meet DOE system targets. Approach: Design, fabricate and test a sequence of subscale and full scale

423

High Level Computational Chemistry Approaches to the Prediction of Energetic Properties of Chemical Hydrogen Storage Systems  

NLE Websites -- All DOE Office Websites (Extended Search)

Level Computational Chemistry Approaches Level Computational Chemistry Approaches to the Prediction of the Energetic Properties of Chemical Hydrogen Storage Systems David A. Dixon Chemistry, University of Alabama, Tuscaloosa, AL Cast: Myrna Hernandez-Matus, Daniel Grant, Jackson Switzer, Jacob Batson, Ronita Folkes, Minh Nguyen Anthony J. Arduengo & co-workers Maciej Gutowski (PNNL) Robert Ramsay Chair Fund Shelby Hall Funding provided in part by the Department of Energy, Office of Energy Efficiency and Renewable Energy under the Hydrogen Storage Grand Challenge, Solicitation No. DE-PS36- 03GO93013 Chemical H 2 Storage Center of Excellence The Promise of Chemical Hydrogen Storage * Chemical reaction releases H 2 at suitable pressures and temperatures - Reaction thermodynamics dictate max. H 2 pressure as function of T -

424

HIERARCHICAL METHODOLOGY FOR MODELING HYDROGEN STORAGE SYSTEMS. PART I: SCOPING MODELS  

DOE Green Energy (OSTI)

Detailed models for hydrogen storage systems provide essential design information about flow and temperature distributions, as well as, the utilization of a hydrogen storage media. However, before constructing a detailed model it is necessary to know the geometry and length scales of the system, along with its heat transfer requirements, which depend on the limiting reaction kinetics. More fundamentally, before committing significant time and resources to the development of a detailed model, it is necessary to know whether a conceptual storage system design is viable. For this reason, a hierarchical system of models progressing from scoping models to detailed analyses was developed. This paper, which discusses the scoping models, is the first in a two part series that presents a collection of hierarchical models for the design and evaluation of hydrogen storage systems.

Hardy, B; Donald L. Anton, D

2008-12-22T23:59:59.000Z

425

Technical Assessment of Organic Liquid Carrier Hydrogen Storage Systems for Automotive Applications  

NLE Websites -- All DOE Office Websites (Extended Search)

Technical Assessment of Organic Liquid Carrier Hydrogen Storage Systems for Technical Assessment of Organic Liquid Carrier Hydrogen Storage Systems for Automotive Applications R. K. Ahluwalia, T. Q. Hua, and J-K Peng Argonne National Laboratory, Argonne, IL 60439 M. Kromer, S. Lasher, K. McKenney, K. Law, and J. Sinha TIAX LLC, Lexington, MA 02421 June 21, 2011 Executive Summary In 2007-2009, the DOE Hydrogen Program conducted a technical assessment of organic liquid carrier based hydrogen storage systems for automotive applications, consistent with the Program's Multiyear Research, Development, and Demonstration Plan. This joint performance (ANL) and cost analysis (TIAX) report summarizes the results of this assessment. These results should be considered only in conjunction with the assumptions used in selecting, evaluating, and

426

FUNDAMENTAL SAFETY TESTING AND ANALYSIS OF HYDROGEN STORAGE MATERIALS AND SYSTEMS  

DOE Green Energy (OSTI)

Hydrogen is seen as the future automobile energy storage media due to its inherent cleanliness upon oxidation and its ready utilization in fuel cell applications. Its physical storage in light weight, low volume systems is a key technical requirement. In searching for ever higher gravimetric and volumetric density hydrogen storage materials and systems, it is inevitable that higher energy density materials will be studied and used. To make safe and commercially acceptable systems, it is important to understand quantitatively, the risks involved in using and handling these materials and to develop appropriate risk mitigation strategies to handle unforeseen accidental events. To evaluate these materials and systems, an IPHE sanctioned program was initiated in 2006 partnering laboratories from Europe, North America and Japan. The objective of this international program is to understanding the physical risks involved in synthesis, handling and utilization of solid state hydrogen storage materials and to develop methods to mitigate these risks. This understanding will support ultimate acceptance of commercially high density hydrogen storage system designs. An overview of the approaches to be taken to achieve this objective will be given. Initial experimental results will be presented on environmental exposure of NaAlH{sub 4}, a candidate high density hydrogen storage compound. The tests to be shown are based on United Nations recommendations for the transport of hazardous materials and include air and water exposure of the hydride at three hydrogen charge levels in various physical configurations. Additional tests developed by the American Society for Testing and Materials were used to quantify the dust cloud ignition characteristics of this material which may result from accidental high energy impacts and system breach. Results of these tests are shown along with necessary risk mitigation techniques used in the synthesis and fabrication of a prototype hydrogen storage system.

Anton, D

2007-05-01T23:59:59.000Z

427

Cryo-Compressed Hydrogen Storage: Performance and Cost Review  

NLE Websites -- All DOE Office Websites (Extended Search)

from Gen2 Reduced insulation Better packaging Vacuum valve box eliminated In-tank heat exchanger 4000-psi pressure vessel rating 4 System Analysis of Physical Storage...

428

Improved Ion Mobility Is Key to New Hydrogen Storage ...  

Science Conference Proceedings (OSTI)

... The abundant element hydrogen could play a role in replacing carbon-based fuels for transportation in the future, but researchers first must develop ...

2011-07-15T23:59:59.000Z

429

Analysis of hydrogen vehicles with cryogenic high pressure storage  

DOE Green Energy (OSTI)

Insulated pressure vessels are cryogenic-capable pressure vessels that can be fueled with liquid hydrogen (LIQ) or ambient-temperature compressed hydrogen (CH2). Insulated pressure vessels offer the advantages of liquid hydrogen tanks (low weight and volume), with reduced disadvantages (lower energy requirement for hydrogen liquefaction and reduced evaporative losses). This paper shows an evaluation of the applicability of the insulated pressure vessels for light-duty vehicles. The paper shows an evaluation of evaporative losses and insulation requirements and a description of the current experimental plans for testing insulated pressure vessels. The results show significant advantages to the use of insulated pressure vessels for light-duty vehicles.

Aceves, S. M.; Berry, G. D.

1998-06-19T23:59:59.000Z

430

A High Density Polarized Hydrogen Gas Target for Storage Rings  

E-Print Network (OSTI)

in a storage ring to study the target characteristics (nuclear polarization, target thickness, radiation 10 13 ~ H/cm 2 . The target polarization was unaffected by prolonged exposure of the target to beams in the use of polarized gases as internal targets in particle storage rings 1 . The first application

431

Global Assessment of Hydrogen Technologies Tasks 3 & 4 Report Economic, Energy, and Environmental Analysis of Hydrogen Production and Delivery Options in Select Alabama Markets: Preliminary Case Studies  

Science Conference Proceedings (OSTI)

This report documents a set of case studies developed to estimate the cost of producing, storing, delivering, and dispensing hydrogen for light-duty vehicles for several scenarios involving metropolitan areas in Alabama. While the majority of the scenarios focused on centralized hydrogen production and pipeline delivery, alternative delivery modes were also examined. Although Alabama was used as the case study for this analysis, the results provide insights into the unique requirements for deploying hydrogen infrastructure in smaller urban and rural environments that lie outside the DOEs high priority hydrogen deployment regions. Hydrogen production costs were estimated for three technologies steam-methane reforming (SMR), coal gasification, and thermochemical water-splitting using advanced nuclear reactors. In all cases examined, SMR has the lowest production cost for the demands associated with metropolitan areas in Alabama. Although other production options may be less costly for larger hydrogen markets, these were not examined within the context of the case studies.

Fouad, Fouad H.; Peters, Robert W.; Sisiopiku, Virginia P.; Sullivan Andrew J.; Gillette, Jerry; Elgowainy, Amgad; Mintz, Marianne

2007-12-01T23:59:59.000Z

432

Ultra-high hydrogen storage capacity of Li-decorated graphyne: A first-principles prediction  

SciTech Connect

Graphyne, consisting of sp- and sp{sup 2}-hybridized carbon atoms, is a new member of carbon allotropes which has a natural porous structure. Here, we report our first-principles calculations on the possibility of Li-decorated graphyne as a hydrogen storage medium. We predict that Li-doping significantly enhances the hydrogen storage ability of graphyne compared to that of pristine graphyne, which can be attributed to the polarization of H{sub 2} molecules induced by the charge transfer from Li atoms to graphyne. The favorite H{sub 2} molecules adsorption configurations on a single side and on both sides of a Li-decorated graphyne layer are determined. When Li atoms are adsorbed on one side of graphyne, each Li can bind four H{sub 2} molecules, corresponding to a hydrogen storage capacity of 9.26 wt. %. The hydrogen storage capacity can be further improved to 15.15 wt. % as graphyne is decorated by Li atoms on both sides, with an optimal average binding energy of 0.226 eV/H{sub 2}. The results show that the Li-decorated graphyne can serve as a high capacity hydrogen storage medium.

Zhang Hongyu; Zhang Meng; Zhao Lixia; Luo Youhua [Department of Physics, East China University of Science and Technology, Shanghai 200237 (China); Zhao Mingwen; Bu Hongxia; He Xiujie [School of Physics and State Key Laboratory of Crystal Materials, Shandong University, Jinan, 250100 Shandong (China)

2012-10-15T23:59:59.000Z

433

Hydrogen--halogen energy storage system. Annual report, January--December 1977  

DOE Green Energy (OSTI)

Work at Brookhaven National Laboratory on the electrochemically regenerative hydrogen--chlorine energy storage system has included electrochemical investigations, materials studies, and technoeconomic assessment. Electrochemical studies have confirmed the reversibility of the cell reactions and the possibility of using the same cell in the electrolysis and fuel cell mode. The hydrogen--chlorine cell differs from most batteries in that the open circuit potential varies appreciably with temperature and depth of discharge. The temperature variation of the open circuit potential reflects the large negative entropy of formation of HCl. A detailed heat and mass balance analysis has been carried out for the H/sub 2//Cl/sub 2/ system for one method of reactant storage and two schemes of heat exchange between the hydrochloric acid storage subsystem and the reactant storage subsystems. Characterization of Nafion membranes in H/sub 2//Cl/sub 2/ cells is reported. From a cost comparison on a 20 MW/200 MWh electrochemically regenerative hydrogen--halogen system it was concluded that the use of either clorine or bromine or alternative methods of chlorine storage had an insignificant effect on the overall cost of the system. The most cost effective method of hydrogen storage is very dependent on the cost of activated metal hydrides.

McBreen, J.; Srinivasan, S.; Salzano, F.J.; Beaufrere, A.H.

1978-09-01T23:59:59.000Z

434

Sub-Nanostructured Non Transition Metal Complex Grids for Hydrogen Storage  

DOE Green Energy (OSTI)

This project involved growing sub-nanostructured metal grids to increase dynamic hydrogen storage capacity of metal hydride systems. The nano particles of any material have unique properties unlike its bulk form. Nano-structuring metal hydride materials can result in: {sm_bullet}Increased hydrogen molecule dissociation rate, {sm_bullet} Increased hydrogen atom transport rate, {sm_bullet} Decreased decrepitation caused by cycling, {sm_bullet} Increased energy transfer in the metal matrix, {sm_bullet} Possible additional contribution by physical adsorption, and {sm_bullet} Possible additional contribution by quantum effects The project succeeded in making nano-structured palladium using electrochemical growth in templates including zeolites, mesoporous silica, polycarbonate films and anodized alumina. Other metals were used to fine-tune the synthesis procedures. Palladium was chosen to demonstrate the effects of nano-structuring since its bulk hydrogen storage capacity and kinetics are well known. Reduced project funding was not sufficient for complete characterization of these materials for hydrogen storage application. The project team intends to seek further funding in the future to complete the characterization of these materials for hydrogen storage.

Dr. Orhan Talu; Dr. Surendra N. Tewari

2007-10-27T23:59:59.000Z

435

Systems Modeling, Simulation and Material Operating Requirements for Chemical Hydride Based Hydrogen Storage  

Science Conference Proceedings (OSTI)

Research on ammonia borane (AB, NH3BH3) has shown it to be a promising material for chemical hydride based hydrogen storage. AB was selected by DOE's Hydrogen Storage Engineering Center of Excellence (HSECoE) as the initial chemical hydride of study because of its high hydrogen storage capacity (up to 19.6% by weight for the release of {approx}2.5 molar equivalents of hydrogen gas) and its stability under typical ambient conditions. A new systems concept based on augers, ballast tank, hydrogen heat exchanger and H2 burner was designed and implemented in simulation. In this design, the chemical hydride material was assumed to produce H2 on the augers itself, thus minimizing the size of ballast tank and reactor. One dimensional models based on conservation of mass, species and energy were used to predict important state variables such as reactant and product concentrations, temperatures of various components, flow rates, along with pressure, in various components of the storage system. Various subsystem components in the models were coded as C language S-functions and implemented in Matlab/Simulink environment. The control variable AB (or alane) flow rate was determined through a simple expression based on the ballast tank pressure, H2 demand from the fuel cell and hydrogen production from AB (or alane) in the reactor. System simulation results for solid AB, liquid AB and alane for both steady state and transient drive cycle cases indicate the usefulness of the model for further analysis and prototype development.

Devarakonda, Maruthi N.; Brooks, Kriston P.; Ronnebro, Ewa; Rassat, Scot D.

2012-02-01T23:59:59.000Z

436

The feasibility and application of multilayer vacuum insulation for cryogenic hydrogen storage / Hodgman J.H.  

E-Print Network (OSTI)

??A need was identified to test multilayer vacuum super insulation (MLVSI) used in cryogenic applications for hydrogen storage. The study focuses on the application of (more)

Hodgman, Jacobus Henry

2011-01-01T23:59:59.000Z

437

Automotive storage of hydrogen using modified magnesium hydrides. Final report, March 1976-March 1978  

DOE Green Energy (OSTI)

Metal hydrides can store more hydrogen per unit volume than normal high pressure or cryogenic techniques. Little energy is required to store the hydrogen in the hydride, and high stability at room temperature ensures low losses over long storage periods. Safety features of metal hydride storage are favorable. Because of its low weight and high hydrogen storage densities, modified magnesium hydride offers the greatest potential for automotive storage of hydrogen. Experimental and analytical work in this program has been directed toward the optimization of this storage system. Due to the relative stability of MgH/sub 2/, modifications of the MgMH/sub x/ (M = metal ion) have been made to decrease the dissociation temperature while retaining high hydrogen capacity. This parameter is crucial since vehicle exhaust will supply the thermal energy to dissociate the hydride in an automobile. System studies indicate that hydride dissociation temperature (T/sub D/) should be 200/sup 0/C to ensure uninterrupted fuel flow at all driving and idle conditions. From experimental data developed in this four task study, we conclude that alloys comprised of Mg, Cu and Ni have come closest to meeting the dissociation temperature goal. Small additions of rare-earth elements to the basic alloy also contribute to a reduction of T/sub D/. The best alloy developed in this program exhibits a T/sub D/ = 223/sup 0/C and a hydrogen capacity near four weight percent compared to a theoretical 7.65 percent for MgH/sub 2/. That alloy has been characterized for dissociation temperature, hydrogen capacity, kinetics, and P-C-T relationships. Dissociation temperature, hydrogen capacity and material cost are reported for each alloy tested in this program.

Rohy, D. A.; Nachman, J. F.; Hammer, A. N.; Duffy, T. E.

1979-01-01T23:59:59.000Z

438

Integrated technical and economic assessments of transport and storage of hydrogen  

DOE Green Energy (OSTI)

Transportation will be a major market for hydrogen because of its great size and the value of energy at the wheels of a vehicle in comparison to its heating value. Hydrogen also offers important potential efficiency gains over hydrocarbon fuels. However, hydrogen end-use technologies will not develop without a reliable hydrogen supply infrastructure. By the same token, reliable infrastructures will not develop without end-use demand. Our task is to analyze the costs of various infrastructure options for providing hydrogen, as the number of vehicles serviced increased from very small numbers initially, to moderate numbers in the mid-term and to determine if a smooth transition may be possible. We will determine viable market sizes for transport and storage options by examining the technologies and the capital and operating costs of these systems, as well as related issues such as safety, construction time, etc. The product of our work will be data based scenarios of the likely transitions to hydrogen fuel, beginning with small and progressing to larger numbers of vehicles. We are working closely with the suppliers of relevant technologies to (1) determine realistic component costs, and (2) to assure availability of our analyses to business. Preliminary analyses indicate that the cost of transport and storage is as important as production cost in determining the cost of hydrogen fuel to the consumer, and that home electrolysis and centrally processed liquid hydrogen may provide hydrogen in the initial stages.

Berry, G.D. [Lawrence Livermore National Lab., CA (United States)]|[Illinois Univ., Urbana, IL (United States); Smith, J.R. [Lawrence Livermore National Lab., CA (United States)

1994-04-01T23:59:59.000Z

439

FCT Hydrogen Production: Current Technology  

NLE Websites -- All DOE Office Websites (Extended Search)

Current Technology to Current Technology to someone by E-mail Share FCT Hydrogen Production: Current Technology on Facebook Tweet about FCT Hydrogen Production: Current Technology on Twitter Bookmark FCT Hydrogen Production: Current Technology on Google Bookmark FCT Hydrogen Production: Current Technology on Delicious Rank FCT Hydrogen Production: Current Technology on Digg Find More places to share FCT Hydrogen Production: Current Technology on AddThis.com... Home Basics Current Technology Thermal Processes Electrolytic Processes Photolytic Processes R&D Activities Quick Links Hydrogen Delivery Hydrogen Storage Fuel Cells Technology Validation Manufacturing Codes & Standards Education Systems Analysis Contacts Current Technology The development of clean, sustainable, and cost-competitive hydrogen

440

FCT Hydrogen Production: Hydrogen Production R&D Activities  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen Production R&D Hydrogen Production R&D Activities to someone by E-mail Share FCT Hydrogen Production: Hydrogen Production R&D Activities on Facebook Tweet about FCT Hydrogen Production: Hydrogen Production R&D Activities on Twitter Bookmark FCT Hydrogen Production: Hydrogen Production R&D Activities on Google Bookmark FCT Hydrogen Production: Hydrogen Production R&D Activities on Delicious Rank FCT Hydrogen Production: Hydrogen Production R&D Activities on Digg Find More places to share FCT Hydrogen Production: Hydrogen Production R&D Activities on AddThis.com... Home Basics Current Technology R&D Activities Quick Links Hydrogen Delivery Hydrogen Storage Fuel Cells Technology Validation Manufacturing Codes & Standards Education Systems Analysis Contacts

Note: This page contains sample records for the topic "delivery hydrogen storage" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Cryogenic, compressed, and liquid hydrogen fuel storage in vehicles  

E-Print Network (OSTI)

Hydrogen is the viable energy carrier of future energy and transportation systems due to its clean emissions, light weight, and abundance. Its extremely low volumetric density, however, presents significant challenges to ...

Reyes, Allan B

2007-01-01T23:59:59.000Z

442

Thermomechanics of hydrogen storage in metallic hydrides: modeling and analysis  

E-Print Network (OSTI)

A thermodynamically consistent mathematical model for hydrogen adsorption in metal hydrides is proposed. Beside hydrogen diffusion, the model accounts for phase transformation accompanied by hysteresis, swelling, temperature and heat transfer, strain, and stress. We prove existence of solutions of the ensuing system of partial differential equations by a carefully-designed, semi-implicit approximation scheme. A generalization for a drift-diffusion of multi-component ionized "gas" is outlined, too.

Tomas Roubicek; Giuseppe Tomassetti

2013-09-12T23:59:59.000Z

443

A life cycle cost analysis framework for geologic storage of hydrogen : a user's tool.  

DOE Green Energy (OSTI)

The U.S. Department of Energy (DOE) has an interest in large scale hydrogen geostorage, which could offer substantial buffer capacity to meet possible disruptions in supply or changing seasonal demands. The geostorage site options being considered are salt caverns, depleted oil/gas reservoirs, aquifers and hard rock caverns. The DOE has an interest in assessing the geological, geomechanical and economic viability for these types of geologic hydrogen storage options. This study has developed an economic analysis methodology and subsequent spreadsheet analysis to address costs entailed in developing and operating an underground geologic storage facility. This year the tool was updated specifically to (1) incorporate more site-specific model input assumptions for the wells and storage site modules, (2) develop a version that matches the general format of the HDSAM model developed and maintained by Argonne National Laboratory, and (3) incorporate specific demand scenarios illustrating the model's capability. Four general types of underground storage were analyzed: salt caverns, depleted oil/gas reservoirs, aquifers, and hard rock caverns/other custom sites. Due to the substantial lessons learned from the geological storage of natural gas already employed, these options present a potentially sizable storage option. Understanding and including these various geologic storage types in the analysis physical and economic framework will help identify what geologic option would be best suited for the storage of hydrogen. It is important to note, however, that existing natural gas options may not translate to a hydrogen system where substantial engineering obstacles may be encountered. There are only three locations worldwide that currently store hydrogen underground and they are all in salt caverns. Two locations are in the U.S. (Texas), and are managed by ConocoPhillips and Praxair (Leighty, 2007). The third is in Teeside, U.K., managed by Sabic Petrochemicals (Crotogino et al., 2008; Panfilov et al., 2006). These existing H{sub 2} facilities are quite small by natural gas storage standards. The second stage of the analysis involved providing ANL with estimated geostorage costs of hydrogen within salt caverns for various market penetrations for four representative cities (Houston, Detroit, Pittsburgh and Los Angeles). Using these demand levels, the scale and cost of hydrogen storage necessary to meet 10%, 25% and 100% of vehicle summer demands was calculated.

Kobos, Peter Holmes; Lord, Anna Snider; Borns, David James; Klise, Geoffrey T.

2011-09-01T23:59:59.000Z

444

Hydrogen Storage Properties of the Tetrahydrofuran Treated Magnesium  

DOE Green Energy (OSTI)

The electronic structure, crystalline feature and morphology of the tetrahydrofuran (THF) treated magnesium, along with its hydriding and dehydriding properties have been investigated. The THF treated magnesium absorbs 6.3 wt per cent hydrogen at 723K and 3.5 MPa. After hydrogenation, in addition to the expected MgH2, a new less-stable hydride phase appears at 673K, but not at a lower temperature. Desorption produces 5.5 wt per cent hydrogen at 723K against a back pressure of 1.3 Pa after 20 cycles of hydriding-dehydriding. The THF treatment improves the kinetics of hydrogen absorption and desorption significantly. From 723K to 623K, the THF treated Mg demonstrates acceptable reaction rates. XPS studies show that tetrahydrofuran treatment causes the electronic energy state of the magnesium surface atoms to change, but the XRD studies show the crystal structure remains unchanged. Metallographic observation of the bulk hydrides of THF treated magnesium reveal they are poly-crystalline wi th the wide-spreading slip bands and twins within the crystals, indicating the phase transformation upon hydriding causes serious stress and distortion. It appears this microstructural deformation explains the much higher energy requirements (higher pressure and temperature) for magnesium hydrogenation than the simple lattice expansion that accompany hydrogen uptake for LaNi5 and FeTi.

AU, MING

2004-05-25T23:59:59.000Z

445

Hydrogen storage via metal hydrides for utility and automotive energy storage applications. [HCl electrolysis for H/sub 2/--Cl/sub 2/ fuel cells  

DOE Green Energy (OSTI)

Brookhaven National Laboratory is currently supported by ERDA to develop the technology and techniques for storing hydrogen via metal hydrides. Hydrogen is able to react with a wide variety of metal and metal alloy materials to form hydride compounds of hydrogen and metals. These compounds differ in stability--some are relatively unstable and can be readily formed and decomposed at low temperatures. The use of these systems for hydrogen storage involves the design of heat exchanger and mass transfer systems, i.e., removal of heat during the charging reaction and addition of heat during the discharge reaction. The most notable example of a metal hydride material is iron titanium which shows promise of being economical for a number of near term hydrogen storage applications. Recent work and progress on the development of metal hydrides for hydrogen storage connected with utility energy storage applications and natural gas supplementation are discussed and electric-to-electric storage system is described in some detail. A system of energy storage involving the electrolysis of hydrochloric acid is described which would utilize metal hydrides to store the hydrogen. In addition, the use of metal hydrides for hydrogen storage in automotive systems is described.

Salzano, F J; Braun, C; Beaufrere, A; Srinivasan, S; Strickland, G; Reilly, J J; Waide, C

1976-08-01T23:59:59.000Z

446

Chemical/hydrogen energy storage systems. Annual report, January 1, 1979-December 31, 1979  

SciTech Connect

The progress made in 1979 in the Chemical/Hydrogen Energy Storage Systems Program is described. The program is managed by Brookhaven National Laboratory for the Division of Energy Storage Systems of the Department of Energy. The program consists of research and development activities in the areas of Hydrogen Production, Storage and Materials, End-Use Applications/Systems Studies, and in Chemical Heat Pumps. The report outlines the progress made by key industrial contractors such as General Electric in the development of SPE water electrolyzers; INCO in the studies of surface poisoning (and reactivation) of metal hydrides; and Air Products and Chemicals in the evaluation of hydrogen production at small hydropower sites. The BNL in-house supporting research, as well as that at universities and other national laboratories for which BNL has technical oversight, is also described.

1980-05-01T23:59:59.000Z

447

Theory of Hydrogen Storage in Complex Hydrides - DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report  

NLE Websites -- All DOE Office Websites (Extended Search)

53 53 FY 2012 Annual Progress Report DOE Hydrogen and Fuel Cells Program Christopher Wolverton Department of Materials Science & Engineering, Northwestern University 2220 Campus Drive, Room 2036 Evanston, IL 60208-3108 Phone: (734) 678-6319 Email: c-wolverton@northwestern.edu Vidvuds Ozolins Department of Materials Science & Engineering, University of California, Los Angeles DOE Program Officer: James Davenport Program Manager Theoretical Condensed Matter Physics Office of Basic Energy Sciences Email: James.Davenport@science.doe.gov Phone: (301) 903-0035 Objectives Using first-principles methods, determine the atomic- level processes that are rate limiting in hydrogen storage

448

Development of a Practical Hydrogen Storage System Based on Liquid Organic Hydrogen Carriers and a Homogeneous Catalyst - DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report  

NLE Websites -- All DOE Office Websites (Extended Search)

5 5 FY 2012 Annual Progress Report DOE Hydrogen and Fuel Cells Program Craig Jensen 1 (Primary Contact), Daniel Brayton 1 , and Scott Jorgensen 2 1 Hawaii Hydrogen Carriers, LLC 531 Cooke Street Honolulu, HI 96813 Phone: (808) 339-1333 Email: hhcllc@hotmail.com 2 General Motors Technical Center DOE Managers HQ: Ned Stetson Phone: (202) 586-9995 Email: Ned.Stetson@ee.doe.gov GO: Katie Randolph Phone: (720) 356-1759 Email: Katie.Randolph@go.doe.gov Contract Number: DE-EE0005020 Project Start Date: July 1, 2011 Project End Date: June 30, 2013 *Congressionally directed project Fiscal Year (FY) 2012 Objectives The objective of this project is to optimize a hydrogen storage media based on a liquid organic carrier (LOC) for hydrogen and design a commercially viable hydrogen

449

Hydrogen Pathways: Cost, Well-to-Wheels Energy Use, and Emissions for the Current Technology Status of Seven Hydrogen Production, Delivery, and Distribution Scenarios  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen Pathways: Cost, Hydrogen Pathways: Cost, Well-to-Wheels Energy Use, and Emissions for the Current Technology Status of Seven Hydrogen Production, Delivery, and Distribution Scenarios Mark Ruth National Renewable Energy Laboratory Melissa Laffen and Thomas A. Timbario Alliance Technical Services, Inc. Technical Report NREL/TP-6A1-46612 September 2009 Technical Report Hydrogen Pathways: Cost, NREL/TP-6A1-46612 Well-to-Wheels Energy Use, September 2009 and Emissions for the Current Technology Status of Seven Hydrogen Production, Delivery, and Distribution Scenarios Mark Ruth National Renewable Energy Laboratory Melissa Laffen and Thomas A. Timbario Alliance Technical Services, Inc. Prepared under Task No. HS07.1002 National Renewable Energy Laboratory 1617 Cole Boulevard, Golden, Colorado 80401-3393

450

Mechanism for high hydrogen storage capacity on metal-coated carbon nanotubes: A first principle analysis  

Science Conference Proceedings (OSTI)

The hydrogen adsorption and binding mechanism on metals (Ca, Sc, Ti and V) decorated single walled carbon nanotubes (SWCNTs) are investigated using first principle calculations. Our results show that those metals coated on SWCNTs can uptake over 8 wt% hydrogen molecules with binding energy range -0.2--0.6 eV, promising potential high density hydrogen storage material. The binding mechanism is originated from the electrostatic Coulomb attraction, which is induced by the electric field due to the charge transfer from metal 4s to 3d. Moreover, we found that the interaction between the H{sub 2}-H{sub 2} further lowers the binding energy. - Graphical abstract: Five hydrogen molecules bound to individual Ca decorated (8, 0) SWCNT : a potential hydrogen-storage material. Highlights: Black-Right-Pointing-Pointer Each transition metal atom can adsorb more than four hydrogen molecules. Black-Right-Pointing-Pointer The interation between metal and hydrogen molecule is electrostatic coulomb attraction. Black-Right-Pointing-Pointer The electric field is induced by the charge transfer from metal 4s to metal 3d. Black-Right-Pointing-Pointer The adsorbed hydrogen molecules which form supermolecule can further lower the binding energy.

Lu, Jinlian; Xiao, Hong [Department of Physics and Institute for nanophysics and Rare-earth Luminescence, Xiangtan University, Xiangtan, Hunan Province 411105 (China)] [Department of Physics and Institute for nanophysics and Rare-earth Luminescence, Xiangtan University, Xiangtan, Hunan Province 411105 (China); Cao, Juexian, E-mail: jxcao@xtu.edu.cn [Department of Physics and Institute for nanophysics and Rare-earth Luminescence, Xiangtan University, Xiangtan, Hunan Province 411105 (China)] [Department of Physics and Institute for nanophysics and Rare-earth Luminescence, Xiangtan University, Xiangtan, Hunan Province 411105 (China)

2012-12-15T23:59:59.000Z

451

Pressure Relief Devices for High-Pressure Gaseous Storage Systems: Applicability to Hydrogen Technology  

DOE Green Energy (OSTI)

Pressure relief devices (PRDs) are viewed as essential safety measures for high-pressure gas storage and distribution systems. These devices are used to prevent the over-pressurization of gas storage vessels and distribution equipment, except in the application of certain toxic gases. PRDs play a critical role in the implementation of most high-pressure gas storage systems and anyone working with these devices should understand their function so they can be designed, installed, and maintained properly to prevent any potentially dangerous or fatal incidents. As such, the intention of this report is to introduce the reader to the function of the common types of PRDs currently used in industry. Since high-pressure hydrogen gas storage systems are being developed to support the growing hydrogen energy infrastructure, several recent failure incidents, specifically involving hydrogen, will be examined to demonstrate the results and possible mechanisms of a device failure. The applicable codes and standards, developed to minimize the risk of failure for PRDs, will also be reviewed. Finally, because PRDs are a critical component for the development of a successful hydrogen energy infrastructure, important considerations for pressure relief devices applied in a hydrogen gas environment will be explored.

Kostival, A.; Rivkin, C.; Buttner, W.; Burgess, R.

2013-11-01T23:59:59.000Z

452

Dynamic Modeling and Simulation Based Analysis of an Ammonia Borane (AB) Reactor System for Hydrogen Storage  

DOE Green Energy (OSTI)

Research on ammonia borane (AB, NH3BH3) has shown it to be a promising material for chemical hydrogen storage in PEM fuel cell applications. AB was selected by DOEs Hydrogen Storage Engineering Center of Excellence (HSECoE) as the initial chemical hydride of study because of its high hydrogen storage capacity (up to 19.6% by weight for the release of three molar equivalents of hydrogen gas) and its stability under typical ambient conditions. A model of a bead reactor system which includes feed and product tanks, hot and cold augers, a ballast tank/reactor, a H2 burner and a radiator was developed to study AB system performance in an automotive application and estimate the energy, mass, and volume requirements for this off-board regenerable hydrogen storage material. Preliminary system simulation results for a start-up case and for a transient drive cycle indicate appropriate trends in the reactor system dynamics. A new controller was developed and validated in simulation for a couple of H2 demand cases.

Devarakonda, Maruthi N.; Holladay, Jamelyn D.; Brooks, Kriston P.; Rassat, Scot D.; Herling, Darrell R.

2010-10-02T23:59:59.000Z

453

Carbide-Derived Carbons with Tunable Porosity Optimized for Hydrogen Storage  

Science Conference Proceedings (OSTI)

On-board hydrogen storage is a key requirement for fuel cell-powered cars and trucks. Porous carbon-based materials can in principle adsorb more hydrogen per unit weight at room temperature than liquid hydrogen at -176 oC. Achieving this goal requires interconnected pores with very high internal surface area, and binding energies between hydrogen and carbon significantly enhanced relative to H2 on graphite. In this project a systematic study of carbide-derived carbons, a novel form of porous carbon, was carried out to discover a high-performance hydrogen sorption material to meet the goal. In the event we were unable to improve on the state of the art in terms of stored hydrogen per unit weight, having encountered the same fundamental limit of all porous carbons: the very weak interaction between H2 and the carbon surface. On the other hand we did discover several strategies to improve storage capacity on a volume basis, which should be applicable to other forms of porous carbon. Further discoveries with potentially broader impacts include Proof that storage performance is not directly related to pore surface area, as had been previously claimed. Small pores (supercapacitors with record high specific capacitance, and perm-selective membranes which bind cytokines for control of infections and possibly hemodialysis filters.

Fisher, John E.; Gogotsi, Yury; Yildirim, Taner

2010-01-07T23:59:59.000Z

454

Hydrogen Storage by Novel CBN Heterocycle Materials - DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report  

NLE Websites -- All DOE Office Websites (Extended Search)

4 4 DOE Hydrogen and Fuel Cells Program FY 2012 Annual Progress Report Shih-Yuan Liu University of Oregon Department of Chemistry 1253 University of Oregon Eugene, OR 97403-1253 Phone: (541) 346-5573 Email: lsy@uoregon.edu DOE Managers HQ: Grace Ordaz Phone: (202) 586-8350 Email: Grace.Ordaz@ee.doe.gov GO: Katie Randolph Phone: (720) 356-1759 Email: Katie.Randolph@go.doe.gov Contract Number: DE-FG36-08GO18143 Project Start Date: September 1, 2008 Project End Date: September 30, 2012 Fiscal Year (FY) 2012 Objectives The objective of this project is to develop novel boron- nitrogen heterocycles as liquid-phase hydrogen storage materials with storage capacities and thermodynamic properties that have the potential to lead to rechargeable systems capable of meeting DOE targets. We seek to:

455

Hydrogen Storage Materials Requirements to Meet the 2017 On Board...  

NLE Websites -- All DOE Office Websites (Extended Search)

Electric Fan (Puller) Nylon 1 5.9 INS-11 Temperature sensor 0.1 0.02 V-5 Control Valve Brass 1.7 0.75 Hydrogen Discharge FT-1 Coalescing Filter SS 1.2 0.34 RD-2 Gas Radiator 304...

456

Hydrogen Storage Technologies Long-term commercialization approach  

E-Print Network (OSTI)

/diesel in generator BA55 series batteries AA battery Power vs. cost per unit power helps show the market space AA battery Lessdifficult(smallerunits) Less difficult (cost tolerant market) #12;Propane in generator/diesel in generator BA55 series batteries AA battery Auto Develop and commercialize high-cost/low-power hydrogen fuel

457

FCT Hydrogen Production: Basics  

NLE Websites -- All DOE Office Websites (Extended Search)

Basics to someone by E-mail Basics to someone by E-mail Share FCT Hydrogen Production: Basics on Facebook Tweet about FCT Hydrogen Production: Basics on Twitter Bookmark FCT Hydrogen Production: Basics on Google Bookmark FCT Hydrogen Production: Basics on Delicious Rank FCT Hydrogen Production: Basics on Digg Find More places to share FCT Hydrogen Production: Basics on AddThis.com... Home Basics Central Versus Distributed Production Current Technology R&D Activities Quick Links Hydrogen Delivery Hydrogen Storage Fuel Cells Technology Validation Manufacturing Codes & Standards Education Systems Analysis Contacts Basics Photo of hydrogen production in photobioreactor Hydrogen, chemical symbol "H", is the simplest element on earth.