National Library of Energy BETA

Sample records for deep anode ground

  1. Ground-water hydraulics of the deep-basin brine aquifer, Palo Duro Basin, Texas panhandle

    SciTech Connect (OSTI)

    Smith, D.A.

    1985-01-01

    The Deep-Basin Brine aquifer of the Palo Duro Basin (Texas Panhandle) underlies thick Permian bedded evaporites that are being evaluated as a potential high-level nuclear waste isolation repository. Potentiometric surface maps of 5 units of the Deep-Basin Brine aquifer were drawn using drill-stem test (DST) pressure data, which were analyzed by a geostatistical technique (kriging) to smooth the large variation in the data. The potentiometric surface maps indicate that the Deep-Basin Brine aquifer could be conceptually modeled as 5 aquifer units; a Lower Permian (Wolfcamp) aquifer, upper and lower Pennsylvanian aquifers, a pre-Pennsylvanian aquifer, and a Pennsylvanian to Wolfcampian granite-wash aquifer. The hydraulic head maps indicate that ground-water flow in each of the units is west to east with a minor northerly component near the Amarillo Uplift, the northern structural boundary of the basin. The Wolfcamp potentiometric surface indicates the strongest component of northerly flow. Inferred flow direction in Pennsylvanian aquifers is easterly, and in the pre-Pennsylvanian aquifer near its pinch-out in the basin center, flow is inferred to be to the north. In the granite-wash aquifer the inferred flow direction is east across the northern edge of the basin and southeast along the Amarillo Uplift.

  2. Anode initiated surface flashover switch

    DOE Patents [OSTI]

    Brainard, John P.; Koss, Robert J.

    2003-04-29

    A high voltage surface flashover switch has a pair of electrodes spaced by an insulator. A high voltage is applied to an anode, which is smaller than the opposing, grounded, cathode. When a controllable source of electrons near the cathode is energized, the electrons are attracted to the anode where they reflect to the insulator and initiate anode to cathode breakdown.

  3. Porosity distribution in Wolfcamp strata, Palo Duro basin, Texas panhandle: implications for deep-basin ground-water flow

    SciTech Connect (OSTI)

    Conti, R.D.; Wirojanagud, P.

    1984-04-01

    Average-porosity distributions in the Wolfcamp deep-basin aquifer are critical to discernment of the geographic trends in effective-porosity in the Palo Duro basin. Precise data are used to improved resolution of porosity values for computer-simulated areal ground-water modeling. Assessing vertical distributions of lithology and porosity in each well studied involves analysis of crossplotted neutron- and density-porosity log responses. This method more accurately identifies lithology and porosity than does the commonly employed crossplotted neutron-porosity and sonic (interval travel time) responses. Log-derived average-porosity distributions yield information about effective pore volume (i.e., movable water) in the Wolfcamp aquifer and enhance the accuracy of estimated of travel times and velocities of brines in basinwide traverses. Mathematical analysis of average travel time and total effective pore volume yield estimates of the rates of annual discharge from the Wolfcamp aquifer in the Palo Duro basin. Based on average flush rates between 2.2 and 1.5 m.y., annual discharge rates from the Wolfcamp aquifer across the northern and eastern basin boundaries, are about 3.6 x 10/sup 5/ m/sup 3/ year/sup -1/ to 5.3 x 10/sup 5/m/sup 3/ year/sup -1/.

  4. Numerical modeling of regional ground-water flow in the deep-basin brine aquifer of the Palo Duro Basin, Texas Panhandle

    SciTech Connect (OSTI)

    Wirojanagud, P.; Kreitler, C.W.; Smith, D.A.

    1986-01-01

    Bedded Permian-age evaporite sequences in the Palo Duro Basin are being considered for a permanent nuclear waste repository by the U.S. Department of Energy. The purpose of this modeling study is to provide an understanding of regional ground-water flow in the formations beneath the Permian evaporite section. From this understanding, more detailed, smaller scale studies can be designed. This study is also intended to provide a better understanding of the boundary conditions and permeabilities of the aquifer and aquitard system as well as provide estimates of ground-water travel times across the basin. Numerical simulations were made of the Wolfcamp aquifer modeled as a single layer and of the entire Deep-Basin Brine aquifer system, including the Wolfcamp aquifer, modeled as a single layer.

  5. FLUORINE CELL ANODE ASSEMBLY

    DOE Patents [OSTI]

    Cable, R.E.; Goode, W.B. Jr.; Henderson, W.K.; Montillon, G.H.

    1962-06-26

    An improved anode assembly is deslgned for use in electrolytlc cells ln the productlon of hydrogen and fluorlne from a moIten electrolyte. The anode assembly comprises a copper post, a copper hanger supported by the post, a plurality of carbon anode members, and bolt means for clamplng half of the anode members to one slde of the hanger and for clamplng the other half of the anode members to the other slde of the hanger. The heads of the clamplng bolts are recessed withln the anode members and carbon plugs are inserted ln the recesses above the bolt heads to protect the boIts agalnst corroslon. A copper washer is provided under the head of each clamplng boIt such that the anode members can be tightly clamped to the hanger with a resultant low anode jolnt resistance. (AEC)

  6. Carbonate fuel cell anodes

    DOE Patents [OSTI]

    Donado, R.A.; Hrdina, K.E.; Remick, R.J.

    1993-04-27

    A molten alkali metal carbonates fuel cell porous anode of lithium ferrite and a metal or metal alloy of nickel, cobalt, nickel/iron, cobalt/iron, nickel/iron/aluminum, cobalt/iron/aluminum and mixtures thereof wherein the total iron content including ferrite and iron of the composite is about 25 to about 80 percent, based upon the total anode, provided aluminum when present is less than about 5 weight percent of the anode. A process is described for production of the lithium ferrite containing anode by slipcasting.

  7. Carbonate fuel cell anodes

    DOE Patents [OSTI]

    Donado, Rafael A. (Chicago, IL); Hrdina, Kenneth E. (Glenview, IL); Remick, Robert J. (Bolingbrook, IL)

    1993-01-01

    A molten alkali metal carbonates fuel cell porous anode of lithium ferrite and a metal or metal alloy of nickel, cobalt, nickel/iron, cobalt/iron, nickel/iron/aluminum, cobalt/iron/aluminum and mixtures thereof wherein the total iron content including ferrite and iron of the composite is about 25 to about 80 percent, based upon the total anode, provided aluminum when present is less than about 5 weight percent of the anode. A process for production of the lithium ferrite containing anode by slipcasting.

  8. Results from a pilot cell test of cermet anodes

    SciTech Connect (OSTI)

    Windisch, Jr, C F; Strachan, D M; Henager, Jr, C H; Greenwell, E N; Alcorn, T R

    1992-08-01

    Goal was to develop long-lasting, energy-efficient anodes for Hall-Heroult cells used to produce Al metal. The anodes were made from a ceramic/metal composite consisting of NiO and NiFe{sub 2}O{sub 4} and a Cu/Ni metal phase. Thirteen cermet anodes were tested at Reynolds Metals Co., Muscle Shoals, AL. All anodes corroded severely during the pilot test. Electrolyte components were found deep within the anodes. However, there were many deficiencies in the pilot cell test, mainly the failure to maintain optimal operating conditions. It is concluded that there is a variety of fabrication and operational considerations that need to be addressed carefully in any future testing. 118 figs, 16 tabs, 17 refs.(DLC)

  9. Anodes for alkaline electrolysis

    DOE Patents [OSTI]

    Soloveichik, Grigorii Lev

    2011-02-01

    A method of making an anode for alkaline electrolysis cells includes adsorption of precursor material on a carbonaceous material, conversion of the precursor material to hydroxide form and conversion of precursor material from hydroxide form to oxy-hydroxide form within the alkaline electrolysis cell.

  10. Inert Anode Report

    SciTech Connect (OSTI)

    none,

    1999-07-01

    This ASME report provides a broad assessment of open literature and patents that exist in the area of inert anodes and their related cathode systems and cell designs, technologies that are relevant for the advanced smelting of aluminum. The report also discusses the opportunities, barriers, and issues associated with these technologies from a technical, environmental, and economic viewpoint.

  11. Movable anode x-ray source with enhanced anode cooling

    DOE Patents [OSTI]

    Bird, Charles R.; Rockett, Paul D.

    1987-01-01

    An x-ray source having a cathode and a disc-shaped anode with a peripheral surface at constant radius from the anode axis opposed to the cathode. The anode has stub axle sections rotatably carried in heat conducting bearing plates which are mounted by thermoelectric coolers to bellows which normally bias the bearing plates to a retracted position spaced from opposing anode side faces. The bellows cooperate with the x-ray source mounting structure for forming closed passages for heat transport fluid. Flow of such fluid under pressure expands the bellows and brings the bearing plates into heat conducting contact with the anode side faces. A worm gear is mounted on a shaft and engages serrations in the anode periphery for rotating the anode when flow of coolant is terminated between x-ray emission events.

  12. Movable anode x-ray source with enhanced anode cooling

    DOE Patents [OSTI]

    Bird, C.R.; Rockett, P.D.

    1987-08-04

    An x-ray source is disclosed having a cathode and a disc-shaped anode with a peripheral surface at constant radius from the anode axis opposed to the cathode. The anode has stub axle sections rotatably carried in heat conducting bearing plates which are mounted by thermoelectric coolers to bellows which normally bias the bearing plates to a retracted position spaced from opposing anode side faces. The bellows cooperate with the x-ray source mounting structure for forming closed passages for heat transport fluid. Flow of such fluid under pressure expands the bellows and brings the bearing plates into heat conducting contact with the anode side faces. A worm gear is mounted on a shaft and engages serrations in the anode periphery for rotating the anode when flow of coolant is terminated between x-ray emission events. 5 figs.

  13. ANODIC TREATMENT OF URANIUM

    DOE Patents [OSTI]

    Kolodney, M.

    1959-02-01

    A method is presented for effecting eloctrolytic dissolution of a metallic uranium article at a uniform rate. The uranium is made the anode in an aqueous phosphoric acid solution containing nitrate ions furnished by either ammonium nitrate, lithium nitrate, sodium nitrate, or potassium nitrate. A stainless steel cathode is employed and electrolysls carried out at a current density of about 0.1 to 1 ampere per square inch.

  14. Nickel anode electrode

    DOE Patents [OSTI]

    Singh, Prabhakar (Bethel, CT); Benedict, Mark (Monroe, CT)

    1987-01-01

    A nickel anode electrode fabricated by oxidizing a nickel alloying material to produce a material whose exterior contains nickel oxide and whose interior contains nickel metal throughout which is dispersed the oxide of the alloying material and by reducing and sintering the oxidized material to form a product having a nickel metal exterior and an interior containing nickel metal throughout which is dispersed the oxide of the alloying material.

  15. Thin film buried anode battery

    DOE Patents [OSTI]

    Lee, Se-Hee; Tracy, C. Edwin; Liu, Ping

    2009-12-15

    A reverse configuration, lithium thin film battery (300) having a buried lithium anode layer (305) and process for making the same. The present invention is formed from a precursor composite structure (200) made by depositing electrolyte layer (204) onto substrate (201), followed by sequential depositions of cathode layer (203) and current collector (202) on the electrolyte layer. The precursor is subjected to an activation step, wherein a buried lithium anode layer (305) is formed via electroplating a lithium anode layer at the interface of substrate (201) and electrolyte film (204). The electroplating is accomplished by applying a current between anode current collector (201) and cathode current collector (202).

  16. Anode film formation and control

    DOE Patents [OSTI]

    Koski, Oscar; Marschman, Steven C.

    1990-01-01

    A protective film is created about the anode within a cryolite-based electrolyte during electrolytic production of aluminum from alumina. The film function to minimize corrosion of the anode by the cryolitic electrolyte and thereby extend the life of the anode. Various operating parameters of the electrolytic process are controlled to maintain the protective film about the anode in a protective state throughout the electrolytic reduction of alumina. Such parameters include electrolyte temperature, electrolyte ratio, current density, and Al.sub.2 O.sub.3 concentration. An apparatus is also disclosed to enable identification of the onset of anode corrosion due to disruption of the film to provide real time information regarding the state of the film.

  17. Anode film formation and control

    DOE Patents [OSTI]

    Koski, O.; Marschman, S.C.

    1990-05-01

    A protective film is created about the anode within a cryolite-based electrolyte during electrolytic production of aluminum from alumina. The film functions to minimize corrosion of the anode by the cryolitic electrolyte and thereby extend the life of the anode. Various operating parameters of the electrolytic process are controlled to maintain the protective film about the anode in a protective state throughout the electrolytic reduction of alumina. Such parameters include electrolyte temperature, electrolyte ratio, current density, and Al[sub 2]O[sub 3] concentration. An apparatus is also disclosed to enable identification of the onset of anode corrosion due to disruption of the film to provide real time information regarding the state of the film. 3 figs.

  18. Nanotube Composite Anode Materials | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nanotube Composite Anode Materials Technology available for licensng: A composite material suitable for use in an anode for a lithium-ion battery Reduces manufacturing costs. ...

  19. Multi-anode ionization chamber

    DOE Patents [OSTI]

    Bolotnikov, Aleksey E.; Smith, Graham; Mahler, George J.; Vanier, Peter E.

    2010-12-28

    The present invention includes a high-energy detector having a cathode chamber, a support member, and anode segments. The cathode chamber extends along a longitudinal axis. The support member is fixed within the cathode chamber and extends from the first end of the cathode chamber to the second end of the cathode chamber. The anode segments are supported by the support member and are spaced along the longitudinal surface of the support member. The anode segments are configured to generate at least a first electrical signal in response to electrons impinging thereon.

  20. Nanostructured Metal Oxide Anodes (Presentation)

    SciTech Connect (OSTI)

    Dillon, A. C.; Riley, L. A.; Lee, S.-H.; Kim, Y.-H.; Ban, C.; Gillaspie, D. T.; Pesaran, A.

    2009-05-01

    This summarizes NREL's FY09 battery materials research activity in developing metal oxide nanostructured anodes to enable high-energy, durable and affordable li-ion batteries for HEVs and PHEVs.

  1. Nano structural anodes for radiation detectors

    SciTech Connect (OSTI)

    Cordaro, Joseph V.; Serkiz, Steven M.; McWhorter, Christopher S.; Sexton, Lindsay T.; Retterer, Scott T.

    2015-07-07

    Anodes for proportional radiation counters and a process of making the anodes is provided. The nano-sized anodes when present within an anode array provide: significantly higher detection efficiencies due to the inherently higher electric field, are amenable to miniaturization, have low power requirements, and exhibit a small electromagnetic field signal. The nano-sized anodes with the incorporation of neutron absorbing elements (e.g., .sup.10B) allow the use of neutron detectors that do not use .sup.3He.

  2. Methods for making anodes for lithium ion batteries (Patent)...

    Office of Scientific and Technical Information (OSTI)

    Data Explorer Search Results Methods for making anodes for lithium ion batteries Title: Methods for making anodes for lithium ion batteries Methods for making composite anodes, ...

  3. Novel Lithium Ion Anode Structures: Overview of New DOE BATT...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Lithium Ion Anode Structures: Overview of New DOE BATT Anode Projects Novel Lithium Ion ... Nanoscale Heterostructures and Thermoplastic Resin Binders: Novel Lithium-Ion Anodes

  4. Jeff Grounds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Jeff Grounds Jeff Grounds jeffgrounds-sm.jpg Jeff Grounds Facilities Manager JTGrounds@lbl.gov Phone: (510) 486-7197 Mobile: (510) 207-2273 Last edited: 2016-04-29 11:34:57

  5. Silicon-Graphene Anodes | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Silicon-Graphene Anodes Technology available for licensing: Provides low-cost production process. Advanced gas phase deposition process yields anodes with five times the specific energy of carbon-made anodes, a longer cycle life and improved capacity PDF icon slicon-graphene_electrodes

  6. Anodes for Rechargeable Lithium-Sulfur Batteries

    SciTech Connect (OSTI)

    Cao, Ruiguo; Xu, Wu; Lu, Dongping; Xiao, Jie; Zhang, Jiguang

    2015-04-10

    In this work, we will review the recent developments on the protection of Li metal anode in Li-S batteries. Various strategies used to minimize the corrosion of Li anode and reducing its impedance increase will be analyzed. Other potential anodes used in sulfur based rechargeable batteries will also be discussed.

  7. Electrochemical cell with calcium anode

    DOE Patents [OSTI]

    Cooper, John F.; Hosmer, Pamela K.; Kelly, Benjamin E.

    1979-01-01

    An electrochemical cell comprising a calcium anode and a suitable cathode in an alkaline electrolyte consisting essentially of an aqueous solution of an hydroxide and a chloride. Specifically disclosed is a mechanically rechargeable calcium/air fuel cell with an aqueous NaOH/NaCl electrolyte.

  8. Fabrication of advanced design (grooved) cermet anodes

    SciTech Connect (OSTI)

    Windisch, C.F. Jr. ); Huettig, F.R. )

    1993-05-01

    Attempts were made to fabricate full-size anodes with advanced, or grooved, design using isostatic pressing, slip casting injection molding. Of the three approaches, isostatic pressing produced an anode with dimensions nearest to the target specifications, without serious macroscopic flaws. This approach is considered the most promising for making advanced anodes for aluminum smelting. However, significant work still remains to optimize the physical properties and microstructure of the anode, both of which were significantly different from that of previous anodes. Injection molding and slip casting yielded anode materials with serious deficiencies, including cracks and holes. Injection molding gave cermet material with the best intrinsic microstructure, i.e., the microstructure of the material between macroscopic flaws was very similar to that of anodes previously made at PNL. Reason for the similarity may have to do with amount of residual binder in the material prior to sintering.

  9. Microbial fuel cell with improved anode

    DOE Patents [OSTI]

    Borole, Abhijeet P.

    2010-04-13

    The present invention relates to a method for preparing a microbial fuel cell, wherein the method includes: (i) inoculating an anodic liquid medium in contact with an anode of the microbial fuel cell with one or more types of microorganisms capable of functioning by an exoelectrogenic mechanism; (ii) establishing a biofilm of the microorganisms on and/or within the anode along with a substantial absence of planktonic forms of the microorganisms by substantial removal of the planktonic microorganisms during forced flow and recirculation conditions of the anodic liquid medium; and (iii) subjecting the microorganisms of the biofilm to a growth stage by incorporating one or more carbon-containing nutritive compounds in the anodic liquid medium during biofilm formation or after biofilm formation on the anode has been established.

  10. Deep Lysimeter

    DOE Patents [OSTI]

    Hubbell, Joel M.; Sisson, James B.

    2004-06-01

    A deep lysimeter including a hollow vessel having a chamber, a fill conduit extending into the chamber through apertures, a semi-permeable member mounted on the vessel and in fluid communication with the fill conduit, and a line connection for retrieving the lysimeter.

  11. Anode Sheath Switching in a Carbon Nanotube Arc Plasma

    SciTech Connect (OSTI)

    Abe Fetterman, Yevgeny Raitses, and Michael Keidar

    2008-04-08

    The anode ablation rate is investigated as a function of anode diameter for a carbon nanotube arc plasma. It is found that anomalously high ablation occurs for small anode diameters. This result is explained by the formation of a positive anode sheath. The increased ablation rate due to this positive anode sheath could imply greater production rate for carbon nanotubes.

  12. Nanocomposite protective coatings for battery anodes (Patent...

    Office of Scientific and Technical Information (OSTI)

    Nanocomposite protective coatings for battery anodes Title: Nanocomposite protective ... USDOE Country of Publication: United States Language: English Subject: 25 ENERGY STORAGE

  13. Surface modifications for carbon lithium intercalation anodes

    DOE Patents [OSTI]

    Tran, Tri D. (Livermore, CA); Kinoshita, Kimio (Cupertino, CA)

    2000-01-01

    A prefabricated carbon anode containing predetermined amounts of passivating film components is assembled into a lithium-ion rechargeable battery. The modified carbon anode enhances the reduction of the irreversible capacity loss during the first discharge of a cathode-loaded cell. The passivating film components, such as Li.sub.2 O and Li.sub.2 CO.sub.3, of a predetermined amount effective for optimal passivation of carbon, are incorporated into carbon anode materials to produce dry anodes that are essentially free of battery electrolyte prior to battery assembly.

  14. Anode composite for molten carbonate fuel cell

    DOE Patents [OSTI]

    Iacovangelo, Charles D.; Zarnoch, Kenneth P.

    1983-01-01

    An anode composite useful for a molten carbonate fuel cell comprised of a porous sintered metallic anode component having a porous bubble pressure barrier integrally sintered to one face thereof, said barrier being comprised of metal coated ceramic particles sintered together and to said anode by means of said metal coating, said metal coating enveloping said ceramic particle and being selected from the group consisting of nickel, copper and alloys thereof, the median pore size of the barrier being significantly smaller than that of the anode.

  15. Iron-lithium anode for thermal battery

    SciTech Connect (OSTI)

    Winchester, C.S.

    1987-06-23

    This patent describes a lithium anode for use in a thermal battery having a composite material comprising lithium and a particulate metal capable of being wetted by molten lithium, but only slightly or not alloyable with the lithium. The composite anode material is positioned adjacent a metal collector element the improvement comprising: a metal screen positioned between and substantially co-extensive with the anode composite and the metal collector element. The anode is thereby spaced apart from the element but is in electrical contact and the screen is electrically conductive.

  16. Quantifying the effect of anode surface roughness on diagnostic x-ray spectra using Monte Carlo simulation

    SciTech Connect (OSTI)

    Mehranian, A.; Ay, M. R.; Alam, N. Riyahi; Zaidi, H.

    2010-02-15

    Purpose: The accurate prediction of x-ray spectra under typical conditions encountered in clinical x-ray examination procedures and the assessment of factors influencing them has been a long-standing goal of the diagnostic radiology and medical physics communities. In this work, the influence of anode surface roughness on diagnostic x-ray spectra is evaluated using MCNP4C-based Monte Carlo simulations. Methods: An image-based modeling method was used to create realistic models from surface-cracked anodes. An in-house computer program was written to model the geometric pattern of cracks and irregularities from digital images of focal track surface in order to define the modeled anodes into MCNP input file. To consider average roughness and mean crack depth into the models, the surface of anodes was characterized by scanning electron microscopy and surface profilometry. It was found that the average roughness (R{sub a}) in the most aged tube studied is about 50 {mu}m. The correctness of MCNP4C in simulating diagnostic x-ray spectra was thoroughly verified by calling its Gaussian energy broadening card and comparing the simulated spectra with experimentally measured ones. The assessment of anode roughness involved the comparison of simulated spectra in deteriorated anodes with those simulated in perfectly plain anodes considered as reference. From these comparisons, the variations in output intensity, half value layer (HVL), heel effect, and patient dose were studied. Results: An intensity loss of 4.5% and 16.8% was predicted for anodes aged by 5 and 50 {mu}m deep cracks (50 kVp, 6 deg. target angle, and 2.5 mm Al total filtration). The variations in HVL were not significant as the spectra were not hardened by more than 2.5%; however, the trend for this variation was to increase with roughness. By deploying several point detector tallies along the anode-cathode direction and averaging exposure over them, it was found that for a 6 deg. anode, roughened by 50 {mu}m deep

  17. Remote control for anode-cathode adjustment

    DOE Patents [OSTI]

    Roose, Lars D.

    1991-01-01

    An apparatus for remotely adjusting the anode-cathode gap in a pulse power machine has an electric motor located within a hollow cathode inside the vacuum chamber of the pulse power machine. Input information for controlling the motor for adjusting the anode-cathode gap is fed into the apparatus using optical waveguides. The motor, controlled by the input information, drives a worm gear that moves a cathode tip. When the motor drives in one rotational direction, the cathode is moved toward the anode and the size of the anode-cathode gap is diminished. When the motor drives in the other direction, the cathode is moved away from the anode and the size of the anode-cathode gap is increased. The motor is powered by batteries housed in the hollow cathode. The batteries may be rechargeable, and they may be recharged by a photovoltaic cell in combination with an optical waveguide that receives recharging energy from outside the hollow cathode. Alternatively, the anode-cathode gap can be remotely adjusted by a manually-turned handle connected to mechanical linkage which is connected to a jack assembly. The jack assembly converts rotational motion of the handle and mechanical linkage to linear motion of the cathode moving toward or away from the anode.

  18. A new low-voltage plateau of Na₃V₂(PO₄)₃ as an anode for Na-ion batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jian, Zelang; Sun, Yang; Ji, Xiulei

    2015-04-04

    A low-voltage plateau at ~0.3 V is discovered during the deep sodiation of Na₃V₂(PO₄)₃ by combined computational and experimental studies. This new low-voltage plateau doubles the sodiation capacity of Na₃V₂(PO₄)₃, turning it into a promising anode for Na-ion batteries.

  19. Microbial fuel cell with improved anode (Patent) | DOEPatents

    Office of Scientific and Technical Information (OSTI)

    Microbial fuel cell with improved anode Title: Microbial fuel cell with improved anode The present invention relates to a method for preparing a microbial fuel cell, wherein the ...

  20. Lithium ion batteries with titania/graphene anodes (Patent) ...

    Office of Scientific and Technical Information (OSTI)

    Title: Lithium ion batteries with titaniagraphene anodes Lithium ion batteries having an anode comprising at least one graphene layer in electrical communication with titania to ...

  1. High Rate and Stable Cycling of Lithium Metal Anode (Journal...

    Office of Scientific and Technical Information (OSTI)

    Title: High Rate and Stable Cycling of Lithium Metal Anode Lithium (Li) metal is an ideal anode material for rechargeable batteries. However, dendritic Li growth and limited ...

  2. Low cost fuel cell diffusion layer configured for optimized anode...

    Office of Scientific and Technical Information (OSTI)

    for optimized anode water management Citation Details In-Document Search Title: Low cost fuel cell diffusion layer configured for optimized anode water management A fuel cell ...

  3. Preparation of lithium-ion battery anodes using lignin (Journal...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Preparation of lithium-ion battery anodes using lignin Citation Details In-Document Search Title: Preparation of lithium-ion battery anodes using lignin Authors:...

  4. Novel Approach to Advanced Direct Methanol Fuel Cell Anode Catalysts...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Approach to Advanced Direct Methanol Fuel Cell Anode Catalysts Novel Approach to Advanced Direct Methanol Fuel Cell Anode Catalysts Presented at the Department of Energy Fuel Cell ...

  5. Energy storage devices having anodes containing Mg and electrolytes...

    Office of Scientific and Technical Information (OSTI)

    Energy storage devices having anodes containing Mg and electrolytes utilized therein Title: Energy storage devices having anodes containing Mg and electrolytes utilized therein For ...

  6. Synthesis and Characterization of Silicon Clathrates for Anode...

    Broader source: Energy.gov (indexed) [DOE]

    More Documents & Publications Synthesis and Characterization of Silicon Clathrates for Anode Applications in Lithium-Ion Batteries Novel Lithium Ion Anode Structures: Overview of ...

  7. Silicon Nanowire Anodes for Next Generation Energy Storage

    Office of Environmental Management (EM)

    Silicon Nanowire Anodes for Next Generation Energy Storage Ionel C. Stefan, Principal ... Cell Manufacturing Optimize system Scale up anode manufacturing Balance of cell ...

  8. ITP Aluminum: Technical Working Group on Inert Anode Technologies...

    Energy Savers [EERE]

    ITP Aluminum: Technical Working Group on Inert Anode Technologies ITP Aluminum: Technical Working Group on Inert Anode Technologies inertech.pdf (8.16 MB) More Documents & ...

  9. Lithium Metal Anodes for Rechargeable Batteries - Joint Center...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    March 3, 2014, Research Highlights Lithium Metal Anodes for Rechargeable Batteries (a) ... Li metal is an ideal anode material for rechargeable batteries beyond Li ion The review ...

  10. Nanocomposite Carbon/Tin Anodes for Lithium Ion Batteries - Energy...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nanocomposite CarbonTin Anodes for Lithium Ion Batteries Lawrence Berkeley National ... Applications and Industries Anodes for lithium ion batteries More InformationFOR MORE ...

  11. Clean Anodic Lithium Films for Longer Life, Rechargeable Lithium...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Storage Energy Storage Find More Like This Return to Search Clean Anodic Lithium ... polymer electrolytes are used to prepare clean anodic lithium films for use in safe, ...

  12. The Nitrogen-Nitride Anode.

    SciTech Connect (OSTI)

    Delnick, Frank M.

    2014-10-01

    Nitrogen gas N 2 can be reduced to nitride N -3 in molten LiCl-KCl eutectic salt electrolyte. However, the direct oxidation of N -3 back to N 2 is kinetically slow and only occurs at high overvoltage. The overvoltage for N -3 oxidation can be eliminated by coordinating the N -3 with BN to form the dinitridoborate (BN 2 -3 ) anion which forms a 1-D conjugated linear inorganic polymer with -Li-N-B-N- repeating units. This polymer precipitates out of solution as Li 3 BN 2 which becomes a metallic conductor upon delithiation. Li 3 BN 2 is oxidized to Li + + N 2 + BN at about the N 2 /N -3 redox potential with very little overvoltage. In this report we evaluate the N 2 /N -3 redox couple as a battery anode for energy storage.

  13. Synthesis and Characterization of Structured Si-Carbon Nanocomposite Anodes

    Broader source: Energy.gov (indexed) [DOE]

    and Functional Polymer Binders | Department of Energy 7_wang_2012_p.pdf (2.21 MB) More Documents & Publications Novel Lithium Ion Anode Structures: Overview of New DOE BATT Anode Projects Synthesis and Characterization of Structured Si-Carbon Nanocomposite Anodes and Functional Polymer Binders Development of High Capacity Anode for Li-ion Batteries

  14. Reduction of ahead of schedule anodes through anode rod quality control

    SciTech Connect (OSTI)

    Baillargeon, F.; Menard, Y.; Perron, C.; Proulx, A.L.

    1996-10-01

    One of the major causes of ahead of schedule anodes reported in recent years by the P155 potroom operation was related to the inherent weakness in the rod welded joints. The development and implementation of an apparatus and procedure to measure, detect and reject the faulty rods prior to anode rodding, will be presented and discussed. The technology has not only significantly reduced the number of ahead of schedule anodes, it has also provided useful information concerning other process improvements.

  15. Pilot demonstration of cerium oxide coated anodes

    SciTech Connect (OSTI)

    Gregg, J.S.; Frederick, M.S.; Shingler, M.J.; Alcorn, T.R.

    1992-10-01

    Cu cermet anodes were tested for 213 to 614 hours with an in-situ deposited CEROX coating in a pilot cell operated by Reynolds Manufacturing Technology Laboratory. At high bath ratio ([approximately]1.5) and low current density (0.5 A/cm[sup 2]), a [ge]1 mm thick dense CEROX coating was deposited on the anodes. At lower bath ratios and higher current density, the CEROX coating was thinner and less dense, but no change in corrosion rate was noted. Regions of low current density on the anodes and sides adjacent to the carbon anode sometimes had thin or absent CEROX coatings. Problems with cracking and oxidation of the cermet substrates led to higher corrosion rates in a pilot cell than would be anticipated from lab scale results.

  16. New High-Energy Nanofiber Anode Materials

    SciTech Connect (OSTI)

    Zhang, Xiangwu; Fedkiw, Peter; Khan, Saad; Huang, Alex; Fan, Jiang

    2013-11-15

    The overall goal of the proposed work was to use electrospinning technology to integrate dissimilar materials (lithium alloy and carbon) into novel composite nanofiber anodes, which simultaneously had high energy density, reduced cost, and improved abuse tolerance. The nanofiber structure allowed the anodes to withstand repeated cycles of expansion and contraction. These composite nanofibers were electrospun into nonwoven fabrics with thickness of 50 μm or more, and then directly used as anodes in a lithium-ion battery. This eliminated the presence of non-active materials (e.g., conducting carbon black and polymer binder) and resulted in high energy and power densities. The nonwoven anode structure also provided a large electrode-electrolyte interface and, hence, high rate capacity and good lowtemperature performance capability. Following are detailed objectives for three proposed project periods. • During the first six months: Obtain anodes capable of initial specific capacities of 650 mAh/g and achieve ~50 full charge/discharge cycles in small laboratory scale cells (50 to 100 mAh) at the 1C rate with less than 20 percent capacity fade; • In the middle of project period: Assemble, cycle, and evaluate 18650 cells using proposed anode materials, and demonstrate practical and useful cycle life (750 cycles of ~70% state of charge swing with less than 20% capacity fade) in 18650 cells with at least twice improvement in the specific capacity than that of conventional graphite electrodes; • At the end of project period: Deliver 18650 cells containing proposed anode materials, and achieve specific capacities greater than 1200 mAh/g and cycle life longer than 5000 cycles of ~70% state of charge swing with less than 20% capacity fade.

  17. Chemical enhancement of metallized zinc anode performance

    SciTech Connect (OSTI)

    Bennett, J.

    1998-12-31

    Galvanic current delivered to reinforced concrete by a metallized zinc anode was studied relative to the humidity of its environment and periodic direct wetting. Current decreased quickly at low humidity to values unlikely to meet accepted cathodic protection criteria, but could be easily restored by direct wetting of the anode. Thirteen chemicals were screened for their ability to enhance galvanic current. Such chemicals, when applied to the exterior surface of the anode, are easily transported by capillary action to the anode-concrete interface where they serve to maintain the interface conductive and the zinc electrochemically active. The most effective chemicals were potassium and lithium bromide, acetate, chloride and nitrate, which increased galvanic current by a factor of 2--15, depending on relative humidity and chloride contamination of the concrete. This new technique is expected to greatly expand the number of concrete structures which can be protected by simple galvanic cathodic protection, The use of lithium-based chemicals together with metallized zinc anode is also proposed for mitigation of existing problems due to ASR. In this case, lithium which prevents or inhibits expansion due to ASR can be readily injected into the concrete. A new process, electrochemical maintenance of concrete (EMC), is also proposed to benefit reinforced concrete structures suffering from chloride-induced corrosion.

  18. Electrolytic Cell For Production Of Aluminum Employing Planar Anodes.

    DOE Patents [OSTI]

    Barnett, Robert J.; Mezner, Michael B.; Bradford, Donald R

    2004-10-05

    A method of producing aluminum in an electrolytic cell containing alumina dissolved in an electrolyte, the method comprising providing a molten salt electrolyte having alumina dissolved therein in an electrolytic cell. A plurality of anodes and cathodes having planar surfaces are disposed in a generally vertical orientation in the electrolyte, the anodes and cathodes arranged in alternating or interleaving relationship to provide anode planar surfaces disposed opposite cathode planar surfaces, the anode comprised of carbon. Electric current is passed through anodes and through the electrolyte to the cathodes depositing aluminum at the cathodes and forming carbon containing gas at the anodes.

  19. Nanocomposite protective coatings for battery anodes

    DOE Patents [OSTI]

    Lemmon, John P; Xiao, Jie; Liu, Jun

    2014-01-21

    Modified surfaces on metal anodes for batteries can help resist formation of malfunction-inducing surface defects. The modification can include application of a protective nanocomposite coating that can inhibit formation of surface defects. such as dendrites, on the anode during charge/discharge cycles. For example, for anodes having a metal (M'), the protective coating can be characterized by products of chemical or electrochemical dissociation of a nanocomposite containing a polymer and an exfoliated compound (M.sub.a'M.sub.b''X.sub.c). The metal, M', comprises Li, Na, or Zn. The exfoliated compound comprises M' among lamella of M.sub.b''X.sub.c, wherein M'' is Fe, Mo, Ta, W, or V, and X is S, O, or Se.

  20. An Insoluble Titanium-Lead Anode for Sulfate Electrolytes

    SciTech Connect (OSTI)

    Ferdman, Alla

    2005-05-11

    The project is devoted to the development of novel insoluble anodes for copper electrowinning and electrolytic manganese dioxide (EMD) production. The anodes are made of titanium-lead composite material produced by techniques of powder metallurgy, compaction of titanium powder, sintering and subsequent lead infiltration. The titanium-lead anode combines beneficial electrochemical behavior of a lead anode with high mechanical properties and corrosion resistance of a titanium anode. In the titanium-lead anode, the titanium stabilizes the lead, preventing it from spalling, and the lead sheathes the titanium, protecting it from passivation. Interconnections between manufacturing process, structure, composition and properties of the titanium-lead composite material were investigated. The material containing 20-30 vol.% of lead had optimal combination of mechanical and electrochemical properties. Optimal process parameters to manufacture the anodes were identified. Prototypes having optimized composition and structure were produced for testing in operating conditions of copper electrowinning and EMD production. Bench-scale, mini-pilot scale and pilot scale tests were performed. The test anodes were of both a plate design and a flow-through cylindrical design. The cylindrical anodes were composed of cylinders containing titanium inner rods and fitting over titanium-lead bushings. The cylindrical design allows the electrolyte to flow through the anode, which enhances diffusion of the electrolyte reactants. The cylindrical anodes demonstrate higher mass transport capabilities and increased electrical efficiency compared to the plate anodes. Copper electrowinning represents the primary target market for the titanium-lead anode. A full-size cylindrical anode performance in copper electrowinning conditions was monitored over a year. The test anode to cathode voltage was stable in the 1.8 to 2.0 volt range. Copper cathode morphology was very smooth and uniform. There was no

  1. A new low-voltage plateau of Na3V2(PO4)(3) as an anode for Na-ion batteries

    SciTech Connect (OSTI)

    Jian, ZL; Sun, Y; Ji, XL

    2015-01-01

    A low-voltage plateau at similar to 0.3 V is discovered for the deep sodiation of Na3V2(PO4)(3) by combined computational and experimental studies. This new low-voltage plateau doubles the sodiation capacity of Na3V2(PO4)(3), thus turning it into a promising anode for Na-ion batteries.

  2. Nanostructured Anodes for Lithium-Ion Batteries - Energy Innovation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Advanced Materials Find More Like This Return to Search Nanostructured Anodes for Lithium-Ion Batteries New Anodes for Lithium-ion Batteries Increase Energy Density Four-Fold...

  3. Fuel cell system shutdown with anode pressure control

    DOE Patents [OSTI]

    Clingerman, Bruce J.; Doan, Tien M.; Keskula, Donald H.

    2002-01-01

    A venting methodology and pressure sensing and vent valving arrangement for monitoring anode bypass valve operating during the normal shutdown of a fuel cell apparatus of the type used in vehicle propulsion systems. During a normal shutdown routine, the pressure differential between the anode inlet and anode outlet is monitored in real time in a period corresponding to the normal closing speed of the anode bypass valve and the pressure differential at the end of the closing cycle of the anode bypass valve is compared to the pressure differential at the beginning of the closing cycle. If the difference in pressure differential at the beginning and end of the anode bypass closing cycle indicates that the anode bypass valve has not properly closed, a system controller switches from a normal shutdown mode to a rapid shutdown mode in which the anode inlet is instantaneously vented by rapid vents.

  4. Self-cleaning rotating anode x-ray source

    DOE Patents [OSTI]

    Paulikas, A.P.

    1987-06-02

    A self-cleaning rotating anode x-ray source comprising and evacuable housing, a rotatable cylindrical anode within the housing, a source of electrons within the housing which electrons are caused to impinge upon the anode to produce x-rays, and means for ionizing residual particles within the housing and accelerating such ions so as to impinge upon the anode to sputter impurities from the surface thereof. 2 figs.

  5. Dissipation factor as a predictor of anodic coating performance

    DOE Patents [OSTI]

    Panitz, Janda K. G.

    1995-01-01

    A dissipation factor measurement is used to predict as-anodized fixture performance prior to actual use of the fixture in an etching environment. A dissipation factor measurement of the anodic coating determines its dielectric characteristics and correlates to the performance of the anodic coating in actual use. The ability to predict the performance of the fixture and its anodized coating permits the fixture to be repaired or replaced prior to complete failure.

  6. Self-cleaning rotating anode X-ray source

    DOE Patents [OSTI]

    Paulikas, Arvydas P.

    1989-01-01

    A self-cleaning rotating anode x-ray source comprising an evacuable housing, a rotatable cylindrical anode within the housing, a source of electrons within the housing which electrons are caused to impinge upon the anode to produce x-rays, and means for ionizing residual particles within the housing and accelerating such ions so as to impinge upon the anode to sputter impurities from the surface thereof.

  7. Oxide-based SOFC Anode Materials - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Oxide-based SOFC Anode Materials Pacific Northwest National Laboratory Contact PNNL About This Technology Shown in green, the ceria-based anode materials provide excellent conductivity with resilience not offered in traditional metal oxides. Shown in green, the ceria-based anode materials provide excellent conductivity with resilience not offered in traditional metal oxides. Technology Marketing Summary In a solid-oxide fuel cell (SOFC), the anode facilitates the reaction between hydrogen,

  8. Hybrid anode for semiconductor radiation detectors

    SciTech Connect (OSTI)

    Yang, Ge; Bolotnikov, Aleksey E; Camarda, Guiseppe; Cui, Yonggang; Hossain, Anwar; Kim, Ki Hyun; James, Ralph B

    2013-11-19

    The present invention relates to a novel hybrid anode configuration for a radiation detector that effectively reduces the edge effect of surface defects on the internal electric field in compound semiconductor detectors by focusing the internal electric field of the detector and redirecting drifting carriers away from the side surfaces of the semiconductor toward the collection electrode(s).

  9. Anode materials for lithium-ion batteries

    DOE Patents [OSTI]

    Sunkara, Mahendra Kumar; Meduri, Praveen; Sumanasekera, Gamini

    2014-12-30

    An anode material for lithium-ion batteries is provided that comprises an elongated core structure capable of forming an alloy with lithium; and a plurality of nanostructures placed on a surface of the core structure, with each nanostructure being capable of forming an alloy with lithium and spaced at a predetermined distance from adjacent nanostructures.

  10. Superconducting transition temperature in anodized aluminum

    SciTech Connect (OSTI)

    Leemann, C.; Elliott, J.H.; Deutscher, G.; Orbach, R.; Wolf, S.A.

    1983-08-01

    We have measured the superconducting transition temperature of anodized aluminum films of grain sizes ranging from less than 100 to 3000 A. The transition temperature is 1.8 K for films of grain size 100 A and decreases monotonically with increasing grain size to 1.2 K for 3000-A grains. The effect depends only on the volume of the grains.

  11. Methods for making anodes for lithium ion batteries

    SciTech Connect (OSTI)

    Xu, Wu; Canfield, Nathan L.; Zhang, Ji-Guang; Liu, Wei; Xiao, Jie; Wang, Deyu; Yang, Z. Gary

    2015-05-26

    Methods for making composite anodes, such as macroporous composite anodes, are disclosed. Embodiments of the methods may include forming a tape from a slurry including a substrate metal precursor, an anode active material, a pore-forming agent, a binder, and a solvent. A laminated structure may be prepared from the tape and sintered to produce a porous structure, such as a macroporous structure. The macroporous structure may be heated to reduce a substrate metal precursor and/or anode active material. Macroporous composite anodes formed by some embodiments of the disclosed methods comprise a porous metal and an anode active material, wherein the anode active material is both externally and internally incorporated throughout and on the surface of the macroporous structure.

  12. Deep Web video

    SciTech Connect (OSTI)

    None Available

    2009-06-01

    To make the web work better for science, OSTI has developed state-of-the-art technologies and services including a deep web search capability. The deep web includes content in searchable databases available to web users but not accessible by popular search engines, such as Google. This video provides an introduction to the deep web search engine.

  13. Deep Web video

    ScienceCinema (OSTI)

    None Available

    2012-03-28

    To make the web work better for science, OSTI has developed state-of-the-art technologies and services including a deep web search capability. The deep web includes content in searchable databases available to web users but not accessible by popular search engines, such as Google. This video provides an introduction to the deep web search engine.

  14. Corrosion of tin oxide at anodic potentials

    SciTech Connect (OSTI)

    Cachet, H.; Froment, M.; Zenia, F.

    1996-02-01

    Tin dioxide electrodes are used as anodes for the electrochemical destruction of organic pollutants in wastewater. The lifetime of such electrodes is limited because of corrosion phenomena which are shown to take place under anodic polarization. These corrosion processes are studied by quartz microbalance experiments, impedance measurements, transmission electron microscopy and scanning electron microscopy observations, carried out on sprayed SnO{sub 2} layers. Localized corrosion phenomena are observed and related to the reaction of radical species with the oxide surface. The extent and the morphology of the attack is shown to depend on the doping (F, Sb) of the SnO{sub 2} electrodes, the solution pH, and the concentration of chloride ions. it is also shown that because of corrosion the conduction band energy level is shifted toward much more positive potentials, allowing the SnO{sub 2} electrode to be activated for oxygen evolution.

  15. Fuel cell anode configuration for CO tolerance

    DOE Patents [OSTI]

    Uribe, Francisco A.; Zawodzinski, Thomas A.

    2004-11-16

    A polymer electrolyte fuel cell (PEFC) is designed to operate on a reformate fuel stream containing oxygen and diluted hydrogen fuel with CO impurities. A polymer electrolyte membrane has an electrocatalytic surface formed from an electrocatalyst mixed with the polymer and bonded on an anode side of the membrane. An anode backing is formed of a porous electrically conductive material and has a first surface abutting the electrocatalytic surface and a second surface facing away from the membrane. The second surface has an oxidation catalyst layer effective to catalyze the oxidation of CO by oxygen present in the fuel stream where at least the layer of oxidation catalyst is formed of a non-precious metal oxidation catalyst selected from the group consisting of Cu, Fe, Co, Tb, W, Mo, Sn, and oxides thereof, and other metals having at least two low oxidation states.

  16. High performance anode for advanced Li batteries

    SciTech Connect (OSTI)

    Lake, Carla

    2015-11-02

    The overall objective of this Phase I SBIR effort was to advance the manufacturing technology for ASI’s Si-CNF high-performance anode by creating a framework for large volume production and utilization of low-cost Si-coated carbon nanofibers (Si-CNF) for the battery industry. This project explores the use of nano-structured silicon which is deposited on a nano-scale carbon filament to achieve the benefits of high cycle life and high charge capacity without the consequent fading of, or failure in the capacity resulting from stress-induced fracturing of the Si particles and de-coupling from the electrode. ASI’s patented coating process distinguishes itself from others, in that it is highly reproducible, readily scalable and results in a Si-CNF composite structure containing 25-30% silicon, with a compositionally graded interface at the Si-CNF interface that significantly improve cycling stability and enhances adhesion of silicon to the carbon fiber support. In Phase I, the team demonstrated the production of the Si-CNF anode material can successfully be transitioned from a static bench-scale reactor into a fluidized bed reactor. In addition, ASI made significant progress in the development of low cost, quick testing methods which can be performed on silicon coated CNFs as a means of quality control. To date, weight change, density, and cycling performance were the key metrics used to validate the high performance anode material. Under this effort, ASI made strides to establish a quality control protocol for the large volume production of Si-CNFs and has identified several key technical thrusts for future work. Using the results of this Phase I effort as a foundation, ASI has defined a path forward to commercialize and deliver high volume and low-cost production of SI-CNF material for anodes in Li-ion batteries.

  17. Lithium Metal Anodes for Rechargeable Batteries

    SciTech Connect (OSTI)

    Xu, Wu; Wang, Jiulin; Ding, Fei; Chen, Xilin; Nasybulin, Eduard N.; Zhang, Yaohui; Zhang, Jiguang

    2013-10-29

    Rechargeable lithium metal batteries have much higher energy density than those of lithium ion batteries using graphite anode. Unfortunately, uncontrollable dendritic lithium growth inherent in these batteries (upon repeated charge/discharge cycling) and limited Coulombic efficiency during lithium deposition/striping has prevented their practical application over the past 40 years. With the emerging of post Li-ion batteries, safe and efficient operation of lithium metal anode has become an enabling technology which may determine the fate of several promising candidates for the next generation of energy storage systems, including rechargeable Li-air battery, Li-S battery, and Li metal battery which utilize lithium intercalation compounds as cathode. In this work, various factors which affect the morphology and Coulombic efficiency of lithium anode will be analyzed. Technologies used to characterize the morphology of lithium deposition and the results obtained by modeling of lithium dendrite growth will also be reviewed. At last, recent development in this filed and urgent need in this field will also be discussed.

  18. Vehicle Technologies Office Merit Review 2014: Silicon Nanowire Anodes for

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Next Generation Energy Storage | Department of Energy Silicon Nanowire Anodes for Next Generation Energy Storage Vehicle Technologies Office Merit Review 2014: Silicon Nanowire Anodes for Next Generation Energy Storage Presentation given by Amprius, Inc. at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about silicon nanowire anodes for next generation energy storage. es126_stefan_2014_p.pdf (1.09 MB) More Documents

  19. Anode Materials for Lithium Ion Batteries | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Anode Materials for Lithium Ion Batteries Technology available for licensing: Composite anode material for Lithium Ion Battery High reversible capacity and improved cyclability with minimal volume change with cycling IN-10-013 US 9054373B2 Availability: Technology available for license to organizations with commercial interest. Collaborative research is available under a Cooperative Research and Development Agreement (CRADA). Contact: 800-627-2596; partners@anl.gov PDF icon Anode Materials

  20. Cooling for a rotating anode X-ray tube

    DOE Patents [OSTI]

    Smither, Robert K. (Hinsdale, IL)

    1998-01-01

    A method and apparatus for cooling a rotating anode X-ray tube. An electromagnetic motor is provided to rotate an X-ray anode with cooling passages in the anode. These cooling passages are coupled to a cooling structure located adjacent the electromagnetic motor. A liquid metal fills the passages of the cooling structure and electrical power is provided to the motor to rotate the anode and generate a rotating magnetic field which moves the liquid metal through the cooling passages and cooling structure.

  1. Lithium Ion Solvation and Intercalation at Anode-Electrolyte...

    Office of Scientific and Technical Information (OSTI)

    Title: Lithium Ion Solvation and Intercalation at Anode-Electrolyte Interface from First Principles Authors: Ong, M T ; Lordi, V ; Draeger, E W ; Pask, J E Publication Date: ...

  2. Anode for a secondary, high-temperature electrochemical cell...

    Office of Scientific and Technical Information (OSTI)

    The anode includes a porous substrate formed of, for instance, a compacted mass of ... substrate; formed; instance; compacted; mass; entangled; metallic; fibers; providing; ...

  3. Lithium Ion Solvation and Intercalation at Anode-Electrolyte...

    Office of Scientific and Technical Information (OSTI)

    Interface from First Principles Citation Details In-Document Search Title: Lithium Ion Solvation and Intercalation at Anode-Electrolyte Interface from First ...

  4. Vehicle Technologies Office Merit Review 2014: Novel Anode Materials

    Broader source: Energy.gov [DOE]

    Presentation given by Argonne National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about novel anode...

  5. Methods for making anodes for lithium ion batteries (Patent)...

    Office of Scientific and Technical Information (OSTI)

    Data Explorer Search Results Methods for making anodes for lithium ion batteries Title: ... A laminated structure may be prepared from the tape and sintered to produce a porous ...

  6. A Better Anode Design to Improve Lithium-Ion Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... this composite anode exhibits the best performance so far in lithium-ion batteries, while retaining an economical cost and compatibility with existing manufacturing ...

  7. Novel Electrolyte Enables Stable Graphite Anodes in Lithium Ion...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Novel Electrolyte Enables Stable Graphite Anodes in Lithium Ion Batteries Lawrence ... Coulombic Efficiency for Lithium Ion Batteries," Journal of the Electrochemical ...

  8. Next Generation Batteries with Metal Anodes - Joint Center for...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    August 3, 2015, Accomplishments Next Generation Batteries with Metal Anodes Promising electrolytes for the magnesium battery consist of salts dissolved in liquid solvents. Recent ...

  9. New Electrode Materials for Magnesium Batteries and Metal Anodes...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Return to Search New Electrode Materials for Magnesium Batteries and Metal Anodes Beyond ... Technology Marketing Summary Magnesium ion batteries present a viable alternative to ...

  10. Longer Life Lithium Ion Batteries with Silicon Anodes - Energy...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Longer Life Lithium Ion Batteries with Silicon Anodes Lawrence Berkeley National ... Researchers have developed a new technology to advance the life of lithium-ion batteries. ...

  11. Ground difference compensating system

    DOE Patents [OSTI]

    Johnson, Kris W.; Akasam, Sivaprasad

    2005-10-25

    A method of ground level compensation includes measuring a voltage of at least one signal with respect to a primary ground potential and measuring, with respect to the primary ground potential, a voltage level associated with a secondary ground potential. A difference between the voltage level associated with the secondary ground potential and an expected value is calculated. The measured voltage of the at least one signal is adjusted by an amount corresponding to the calculated difference.

  12. Ground water and energy

    SciTech Connect (OSTI)

    Not Available

    1980-11-01

    This national workshop on ground water and energy was conceived by the US Department of Energy's Office of Environmental Assessments. Generally, OEA needed to know what data are available on ground water, what information is still needed, and how DOE can best utilize what has already been learned. The workshop focussed on three areas: (1) ground water supply; (2) conflicts and barriers to ground water use; and (3) alternatives or solutions to the various issues relating to ground water. (ACR)

  13. Carbon paint anode for reinforced concrete bridges in coastal environments

    SciTech Connect (OSTI)

    Cramer, Stephen D.; Bullard, Sophie J.; Covino, Bernard S., Jr.; Holcomb, Gordon R.; Russell, James H.; Cryer, C.B.; Laylor, H.M.

    2002-01-01

    Solvent-based acrylic carbon paint anodes were installed on the north approach spans of the Yaquina Bay Bridge (Newport OR) in 1985. The anodes continue to perform satisfactorily after more than 15 years service. The anodes were inexpensive to apply and field repairs are easily made. Depolarization potentials are consistently above 100 mV with long-term current densities around 2 mA/m 2. Bond strength remains adequate, averaging 0.50 MPa (73 psi). Some deterioration of the anode-concrete interface has occurred in the form of cracks and about 4% of the bond strength measurements indicated low or no bond. Carbon anode consumption appears low. The dominant long-term anode reaction appears to be chlorine evolution, which results in limited further acidification of the anode-concrete interface. Chloride profiles were depressed compared to some other coastal bridges suggesting chloride extraction by the CP system. Further evidence of outward chloride migration was a flat chloride profile between the anode and the outer rebar.

  14. Electrolytic production of high purity aluminum using ceramic inert anodes

    DOE Patents [OSTI]

    Ray, Siba P.; Liu, Xinghua; Weirauch, Douglas A.; DiMilia, Robert A.; Dynys, Joseph M.; Phelps, Frankie E.; LaCamera, Alfred F.

    2002-01-01

    A method of producing commercial purity aluminum in an electrolytic reduction cell comprising ceramic inert anodes is disclosed. The method produces aluminum having acceptable levels of Fe, Cu and Ni impurities. The ceramic inert anodes used in the process may comprise oxides containing Fe and Ni, as well as other oxides, metals and/or dopants.

  15. Electrolytic production of high purity aluminum using inert anodes

    DOE Patents [OSTI]

    Ray, Siba P.; Liu, Xinghua; Weirauch, Jr., Douglas A.

    2001-01-01

    A method of producing commercial purity aluminum in an electrolytic reduction cell comprising inert anodes is disclosed. The method produces aluminum having acceptable levels of Fe, Cu and Ni impurities. The inert anodes used in the process preferably comprise a cermet material comprising ceramic oxide phase portions and metal phase portions.

  16. Focused cathode design to reduce anode heating during vircator operation

    SciTech Connect (OSTI)

    Lynn, Curtis F.; Dickens, James C.; Neuber, Andreas A.

    2013-10-15

    Virtual cathode oscillators, or vircators, are a type of high power microwave device which operates based on the instability of a virtual cathode, or cloud of electrons, which forms when electron current injected into the drift tube exceeds the space charge limited current within the drift tube. Anode heating by the electron beam during vircator operation ultimately limits achievable pulse lengths, repetition rates, and the duration of burst mode operation. This article discusses a novel cathode design that focuses electrons through holes in the anode, thus significantly reducing anode heating by the electrons emitted from the cathode during the first transit through the A-K gap. Reflexing electrons continue to deposit energy on the anode; however, the discussed minimization of anode heating by main beam electrons has the potential to enable higher repetition rates as well as efficiency and longer diode lifetime. A simulation study of this type of cathode design illustrates possible advantages.

  17. Virtual cathode microwave generator having annular anode slit

    DOE Patents [OSTI]

    Kwan, Thomas J. T.; Snell, Charles M.

    1988-01-01

    A microwave generator is provided for generating microwaves substantially from virtual cathode oscillation. Electrons are emitted from a cathode and accelerated to an anode which is spaced apart from the cathode. The anode has an annular slit therethrough effective to form the virtual cathode. The anode is at least one range thickness relative to electrons reflecting from the virtual cathode. A magnet is provided to produce an optimum magnetic field having the field strength effective to form an annular beam from the emitted electrons in substantial alignment with the annular anode slit. The magnetic field, however, does permit the reflected electrons to axially diverge from the annular beam. The reflected electrons are absorbed by the anode in returning to the real cathode, such that substantially no reflexing electrons occur. The resulting microwaves are produced with a single dominant mode and are substantially monochromatic relative to conventional virtual cathode microwave generators.

  18. Chemical Bonding In Amorphous Si Coated-carbon Nanotube As Anodes...

    Office of Scientific and Technical Information (OSTI)

    Nanotube As Anodes For Li ion Batteries: A XANES Study The chemical bonding ... are crucial in designing further improved Si-C composite anode for lithium ion battery. ...

  19. Material and Energy Flows in the Production of Cathode and Anode...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Material and Energy Flows in the Production of Cathode and Anode Materials for Lithium Ion Batteries Title Material and Energy Flows in the Production of Cathode and Anode...

  20. Carbonaceous materials as lithium intercalation anodes

    SciTech Connect (OSTI)

    Tran, T.D.; Feikert, J.H.; Mayer, S.T.; Song, X.; Kinoshita, K.

    1994-10-01

    Commercial and polymer-derived carbonaceous materials were examined as lithium intercalation anodes in propylene carbonate (pyrolysis < 1350C, carbons) and ethylene carbonate/dimethyl carbonate (graphites) electrolytes. The reversible capacity (180--355 mAh/g) and the irreversible capacity loss (15--200 % based on reversible capacity) depend on the type of binder, carbon type, morphology, and phosphorus doping concentration. A carbon-based binder was chosen for electrode fabrication, producing mechanically and chemically stable electrodes and reproducible results. Several types of graphites had capacity approaching LiC{sub 6}. Petroleum fuel green cokes doped with phosphorous gave more than a 20 % increase in capacity compared to undoped samples. Electrochemical characteristics are related to SEM, TEM, XRD and BET measurements.

  1. Deep Sky Astronomical Image Database

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Deep Sky Astronomical Image Database Deep Sky Astronomical Image Database Key Challenges: Develop, store, analyze, and make available an astronomical image database of...

  2. Deep Vadose Zone - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Long-Range Deep Vadose Zone Program Plan, (Rev. 0) - (PDF) Implementation Plan for the Deep Vadose Zone Applied Field Research Center (DVZ-AFRC) - (PDF) Ecology's groundwater...

  3. ZIRCONIUM OXIDE NANOSTRUCTURES PREPARED BY ANODIC OXIDATION

    SciTech Connect (OSTI)

    Dang, Y. Y.; Bhuiyan, M.S.; Paranthaman, M. P.

    2008-01-01

    Zirconium oxide is an advanced ceramic material highly useful for structural and electrical applications because of its high strength, fracture toughness, chemical and thermal stability, and biocompatibility. If highly-ordered porous zirconium oxide membranes can be successfully formed, this will expand its real-world applications, such as further enhancing solid-oxide fuel cell technology. Recent studies have achieved various morphologies of porous zirconium oxide via anodization, but they have yet to create a porous layer where nanoholes are formed in a highly ordered array. In this study, electrochemical methods were used for zirconium oxide synthesis due to its advantages over other coating techniques, and because the thickness and morphology of the ceramic fi lms can be easily tuned by the electrochemical parameters, such as electrolyte solutions and processing conditions, such as pH, voltage, and duration. The effects of additional steps such as pre-annealing and post-annealing were also examined. Results demonstrate the formation of anodic porous zirconium oxide with diverse morphologies, such as sponge-like layers, porous arrays with nanoholes ranging from 40 to 75 nm, and nanotube layers. X-ray powder diffraction analysis indicates a cubic crystallographic structure in the zirconium oxide. It was noted that increased voltage improved the ability of the membrane to stay adhered to the zirconium substrate, whereas lower voltages caused a propensity for the oxide fi lm to fl ake off. Further studies are needed to defi ne the parameters windows that create these morphologies and to investigate other important characteristics such as ionic conductivity.

  4. Deep Vadose Zone

    Broader source: Energy.gov [DOE]

    The Mission of the Deep Vadose Zone Applied Field Research Initiative is to protect water resources across the DOE complex over the long-term by developing effective solutions to solve DOE’s most...

  5. Exploration for deep coal

    SciTech Connect (OSTI)

    2008-12-15

    The most important factor in safe mining is the quality of the roof. The article explains how the Rosebud Mining Co. conducts drilling and exploration in 11 deep coal mine throughout Pennsylvania and Ohio. Rosebud uses two Atlas Copco CS10 core drilling rigs mounted on 4-wheel drive trucks. The article first appeared in Atlas Copco's in-house magazine, Deep Hole Driller. 3 photos.

  6. Cu-Ni-Fe anodes having improved microstructure

    DOE Patents [OSTI]

    Bergsma, S. Craig; Brown, Craig W.

    2004-04-20

    A method of producing aluminum in a low temperature electrolytic cell containing alumina dissolved in an electrolyte. The method comprises the steps of providing a molten electrolyte having alumina dissolved therein in an electrolytic cell containing the electrolyte. A non-consumable anode and cathode is disposed in the electrolyte, the anode comprised of Cu--Ni--Fe alloys having single metallurgical phase. Electric current is passed from the anode, through the electrolyte to the cathode thereby depositing aluminum on the cathode, and molten aluminum is collected from the cathode.

  7. A Better Anode Design to Improve Lithium-Ion Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Better Anode Design to Improve Lithium-Ion Batteries Print Lithium-ion batteries are in smart phones, laptops, most other consumer electronics, and the newest electric cars. Good as these batteries are, the need for energy storage in batteries is surpassing current technologies. In a lithium-ion battery, charge moves from the cathode to the anode, a critical component for storing energy. A team of Berkeley Lab scientists has designed a new kind of anode that absorbs eight times the lithium of

  8. A Better Anode Design to Improve Lithium-Ion Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Better Anode Design to Improve Lithium-Ion Batteries Print Lithium-ion batteries are in smart phones, laptops, most other consumer electronics, and the newest electric cars. Good as these batteries are, the need for energy storage in batteries is surpassing current technologies. In a lithium-ion battery, charge moves from the cathode to the anode, a critical component for storing energy. A team of Berkeley Lab scientists has designed a new kind of anode that absorbs eight times the lithium of

  9. A Better Anode Design to Improve Lithium-Ion Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Better Anode Design to Improve Lithium-Ion Batteries Print Lithium-ion batteries are in smart phones, laptops, most other consumer electronics, and the newest electric cars. Good as these batteries are, the need for energy storage in batteries is surpassing current technologies. In a lithium-ion battery, charge moves from the cathode to the anode, a critical component for storing energy. A team of Berkeley Lab scientists has designed a new kind of anode that absorbs eight times the lithium of

  10. A Better Anode Design to Improve Lithium-Ion Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Better Anode Design to Improve Lithium-Ion Batteries Print Lithium-ion batteries are in smart phones, laptops, most other consumer electronics, and the newest electric cars. Good as these batteries are, the need for energy storage in batteries is surpassing current technologies. In a lithium-ion battery, charge moves from the cathode to the anode, a critical component for storing energy. A team of Berkeley Lab scientists has designed a new kind of anode that absorbs eight times the lithium of

  11. A Better Anode Design to Improve Lithium-Ion Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Better Anode Design to Improve Lithium-Ion Batteries Print Lithium-ion batteries are in smart phones, laptops, most other consumer electronics, and the newest electric cars. Good as these batteries are, the need for energy storage in batteries is surpassing current technologies. In a lithium-ion battery, charge moves from the cathode to the anode, a critical component for storing energy. A team of Berkeley Lab scientists has designed a new kind of anode that absorbs eight times the lithium of

  12. A Better Anode Design to Improve Lithium-Ion Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Better Anode Design to Improve Lithium-Ion Batteries Print Lithium-ion batteries are in smart phones, laptops, most other consumer electronics, and the newest electric cars. Good as these batteries are, the need for energy storage in batteries is surpassing current technologies. In a lithium-ion battery, charge moves from the cathode to the anode, a critical component for storing energy. A team of Berkeley Lab scientists has designed a new kind of anode that absorbs eight times the lithium of

  13. A Better Anode Design to Improve Lithium-Ion Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Better Anode Design to Improve Lithium-Ion Batteries A Better Anode Design to Improve Lithium-Ion Batteries Print Friday, 23 March 2012 13:53 Lithium-ion batteries are in smart phones, laptops, most other consumer electronics, and the newest electric cars. Good as these batteries are, the need for energy storage in batteries is surpassing current technologies. In a lithium-ion battery, charge moves from the cathode to the anode, a critical component for storing energy. A team of Berkeley Lab

  14. Inert Anode Life in Low Temperature Reduction Process

    SciTech Connect (OSTI)

    Bradford, Donald R.

    2005-06-30

    The production of aluminum metal by low temperature electrolysis utilizing metal non-consumable anodes and ceramic cathodes was extensively investigated. Tests were performed with traditional sodium fluoride--aluminum fluoride composition electrolytes, potassium fluoride-- aluminum fluoride electrolytes, and potassium fluoride--sodium fluoride--aluminum fluoride electrolytes. All of the Essential First-Tier Requirements of the joint DOE-Aluminum Industry Inert Anode Road Map were achieved and those items yet to be resolved for commercialization of this technology were identified. Methods for the fabrication and welding of metal alloy anodes were developed and tested. The potential savings of energy and energy costs were determined and potential environmental benefits verified.

  15. Short time proton dynamics in bulk ice and in porous anode solid oxide fuel cell materials

    SciTech Connect (OSTI)

    Basoli, Francesco; Senesi, Roberto; Kolesnikov, Alexander I; Licoccia, Silvia

    2014-01-01

    Oxygen reduction and incorporation into solid electrolytes and the reverse reaction of oxygen evolution play a cru-cial role in Solid Oxide Fuel Cell (SOFC) applications. However a detailed un derstanding of the kinetics of the cor-responding reactions, i.e. on reaction mechanisms, rate limiting steps, reaction paths, electrocatalytic role of materials, is still missing. These include a thorough characterization of the binding potentials experienced by protons in the lattice. We report results of Inelastic Neutron Scattering (INS) measurements of the vibrational state of the protons in Ni- YSZ highly porous composites (75% to 90% ), a ceramic-metal material showing a high electrical conductivity and ther mal stability, which is known to be most effectively used as anodes for solid ox ide fuel cells. The results are compared with INS and Deep Inelastic Neutron Scattering (DINS) experiments on the proton binding states in bulk ice.

  16. Recent Development on Anodes for Na-Ion Batteries

    SciTech Connect (OSTI)

    Bommier, C; Ji, XL

    2015-01-23

    New discoveries in anode materials for sodium ion batteries (NIBs) are highly necessary to achieve the goals of widespread applications, such as electric vehicles (EVs) and grid-level energy storage. Carbon-based materials are critical for this task as they are inexpensive, abundant, and versatile. They contain a plethora of structures and morphologies, ranging from highly ordered graphite or nanotubes to highly disordered amorphous carbon, thus making them very attractive for electrochemical energy storage. This review attempts to cover past and recent progress in the development of carbon-based anode materials for NIBs. To give a larger context, the article will briefly cover other anode materials for NIBs as well. The aim of this paper is to provide a timely update for researchers currently involved in the respective fields or to serve as a starting point for individuals who would like to gain a greater knowledge of new NIB anode materials.

  17. A Better Anode Design to Improve Lithium-Ion Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... The secret to the newly-designed anode is a tailored polymer that conducts electricity and ... At top, spectra of a series of polymers obtained with soft x-ray absorption spectroscopy ...

  18. A Better Anode Design to Improve Lithium-Ion Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Better Anode Design to Improve Lithium-Ion Batteries Print Lithium-ion batteries are in ... 8.0.1 show a lower "lowest unoccupied molecular orbital" for the new Berkeley Lab ...

  19. Lithium-Titanium-Oxide Anodes Improve Battery Safety and Performance...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lithium-Titanium-Oxide Anodes Improve Battery Safety and Performance Technology available for licensing: Li4Ti5O12 spinel is a promising alternative to graphite electrodes with ...

  20. A Better Anode Design to Improve Lithium-Ion Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Better Anode Design to Improve Lithium-Ion Batteries Print Lithium-ion batteries are in smart phones, laptops, most other consumer electronics, and the newest electric cars. Good...

  1. Nanocomposite anode materials for sodium-ion batteries

    DOE Patents [OSTI]

    Manthiram, Arumugam; Kim Il, Tae; Allcorn, Eric

    2016-06-14

    The disclosure relates to an anode material for a sodium-ion battery having the general formula AO.sub.x--C or AC.sub.x--C, where A is aluminum (Al), magnesium (Mg), titanium (Ti), vanadium (V), chromium (Cr), manganese (Mn), iron (Fe), cobalt (Co), nickel (Ni), zirconium (Zr), molybdenum (Mo), tungsten (W), niobium (Nb), tantalum (Ta), silicon (Si), or any combinations thereof. The anode material also contains an electrochemically active nanoparticles within the matrix. The nanoparticle may react with sodium ion (Na.sup.+) when placed in the anode of a sodium-ion battery. In more specific embodiments, the anode material may have the general formula M.sub.ySb-M'O.sub.x--C, Sb-MO.sub.x--C, M.sub.ySn-M'C.sub.x--C, or Sn-MC.sub.x--C. The disclosure also relates to rechargeable sodium-ion batteries containing these materials and methods of making these materials.

  2. A Better Anode Design to Improve Lithium-Ion Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Better Anode Design to Improve Lithium-Ion Batteries ... In a lithium-ion battery, charge moves from the cathode to the ... characterization, and simulation in a novel approach to ...

  3. A Better Anode Design to Improve Lithium-Ion Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Better Anode Design to Improve Lithium-Ion Batteries ... In a lithium-ion battery, charge moves from the cathode to the ... characterization, and simulation in a novel approach to ...

  4. A Better Anode Design to Improve Lithium-Ion Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Better Anode Design to Improve Lithium-Ion ... In a lithium-ion battery, charge moves from the cathode to the ... characterization, and simulation in a novel approach to ...

  5. A Better Anode Design to Improve Lithium-Ion Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Better Anode Design to Improve Lithium-Ion Batteries Print Lithium-ion batteries are in smart phones, laptops, most other consumer electronics, and the newest electric cars. Good ...

  6. Novel Approach to Advanced Direct Methanol Fuel Cell Anode Catalysts |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Approach to Advanced Direct Methanol Fuel Cell Anode Catalysts Novel Approach to Advanced Direct Methanol Fuel Cell Anode Catalysts Presented at the Department of Energy Fuel Cell Projects Kickoff Meeting, September 1 - October 1, 2009 dinh-gennett_topic_5a_dmfc_nrel_kickoff.pdf (1.41 MB) More Documents & Publications Advanced Materials and Concepts for Portable Power Fuel Cells Introduction to DMFCs - Advanced Materials and Concepts for Portable Power Fuel Cells

  7. Lithium-Titanium-Oxide Anodes Improve Battery Safety and Performance |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Argonne National Laboratory Lithium-Titanium-Oxide Anodes Improve Battery Safety and Performance Technology available for licensing: Li4Ti5O12 spinel is a promising alternative to graphite electrodes with enhanced conductivity, voltage and energy density. Enhanced stability at lower cost Li4Ti5O12 spinel is a promising alternative to graphite electrodes with enhanced conductivity, voltage and energy density PDF icon LTO_anodes

  8. Fuel cell having dual electrode anode or cathode

    DOE Patents [OSTI]

    Findl, Eugene

    1985-01-01

    A fuel cell that is characterized by including a dual electrode anode that is operable to simultaneously electro-oxidize a gaseous fuel and a liquid fuel. In alternative embodiments, a fuel cell having a single electrode anode is provided with a dual electrode cathode that is operable to simultaneously reduce a gaseous oxidant and a liquid oxidant to electro-oxidize a fuel supplied to the cell.

  9. Fuel cell having dual electrode anode or cathode

    DOE Patents [OSTI]

    Findl, E.

    1984-04-10

    A fuel cell that is characterized by including a dual electrode anode that is operable to simultaneously electro-oxidize a gaseous fuel and a liquid fuel. In alternative embodiments, a fuel cell having a single electrode anode is provided with a dual electrode cathode that is operable to simultaneously reduce a gaseous oxidant and a liquid oxidant to electro-oxidize a fuel supplied to the cell.

  10. Stainless steel anodes for alkaline water electrolysis and methods of making

    DOE Patents [OSTI]

    Soloveichik, Grigorii Lev

    2014-01-21

    The corrosion resistance of stainless steel anodes for use in alkaline water electrolysis was increased by immersion of the stainless steel anode into a caustic solution prior to electrolysis. Also disclosed herein are electrolyzers employing the so-treated stainless steel anodes. The pre-treatment process provides a stainless steel anode that has a higher corrosion resistance than an untreated stainless steel anode of the same composition.

  11. Hyper-dendritic nanoporous zinc foam anodes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chamoun, Mylad; Hertzberg, Benjamin J.; Gupta, Tanya; Davies, Daniel; Bhadra, Shoham; Van Tassell, Barry.; Erdonmez, Can; Steingart, Daniel A.

    2015-04-24

    The low cost, significant reducing potential, and relative safety of the zinc electrode is a common hope for a reductant in secondary batteries, but it is limited mainly to primary implementation due to shape change. In this work we exploit such shape change for the benefit of static electrodes through the electrodeposition of hyper-dendritic nanoporous zinc foam. Electrodeposition of zinc foam resulted in nanoparticles formed on secondary dendrites in a three-dimensional network with a particle size distribution of 54.1 - 96.0 nm. The nanoporous zinc foam contributed to highly oriented crystals, high surface area and more rapid kinetics in contrastmore » to conventional zinc in alkaline mediums. The anode material presented had a utilization of ~ 88% at full depth-of-discharge at various rates indicating a superb rate-capability. The rechargeability of Zn⁰/Zn²⁺ showed significant capacity retention over 100 cycles at a 40% depth-of-discharge to ensure that the dendritic core structure was imperforated. The dendritic architecture was densified upon charge-discharge cycling and presented superior performance compared to bulk zinc electrodes.« less

  12. Process for anodizing a robotic device

    DOE Patents [OSTI]

    Townsend, William T.

    2011-11-08

    A robotic device has a base and at least one finger having at least two links that are connected in series on rotary joints with at least two degrees of freedom. A brushless motor and an associated controller are located at each joint to produce a rotational movement of a link. Wires for electrical power and communication serially connect the controllers in a distributed control network. A network operating controller coordinates the operation of the network, including power distribution. At least one, but more typically two to five, wires interconnect all the controllers through one or more joints. Motor sensors and external world sensors monitor operating parameters of the robotic hand. The electrical signal output of the sensors can be input anywhere on the distributed control network. V-grooves on the robotic hand locate objects precisely and assist in gripping. The hand is sealed, immersible and has electrical connections through the rotary joints for anodizing in a single dunk without masking. In various forms, this intelligent, self-contained, dexterous hand, or combinations of such hands, can perform a wide variety of object gripping and manipulating tasks, as well as locomotion and combinations of locomotion and gripping.

  13. Deep Secrets of the Neutrino: Physics Underground

    SciTech Connect (OSTI)

    Rowson, P.C.

    2010-03-23

    Among the many beautiful, unexpected and sometimes revolutionary discoveries to emerge from subatomic physics, probably none is more bizarre than an elementary particle known as the 'neutrino'. More than a trillion of these microscopic phantoms pass unnoticed through our bodies every second, and indeed, through the entire Earth - but their properties remain poorly understood. In recent years, exquisitely sensitive experiments, often conducted deep below ground, have brought neutrino physics to the forefront. In this talk, we will explore the neutrino - what we know, what we want to know, and how one experiment in a New Mexico mine is trying to get there.

  14. Electrical grounding prong socket

    DOE Patents [OSTI]

    Leong, Robert

    1991-01-01

    The invention is a socket for a grounding prong used in a three prong electrical plug and a receptacle for the three prong plug. The socket being sufficiently spacious to prevent the socket from significantly stretching when a larger, U-shaped grounding prong is inserted into the socket, and having a ridge to allow a snug fit when a smaller tubular shape grounding prong is inserted into the socket.

  15. In situ characterization of nanoscale catalysts during anodic redox processes

    SciTech Connect (OSTI)

    Sharma, Renu; Crozier, Peter; Adams, James

    2013-09-19

    Controlling the structure and composition of the anode is critical to achieving high efficiency and good long-term performance. In addition to being a mixed electronic and ionic conductor, the ideal anode material should act as an efficient catalyst for oxidizing hydrogen, carbon monoxide and dry hydrocarbons without de-activating through either sintering or coking. It is also important to develop novel anode materials that can operate at lower temperatures to reduce costs and minimized materials failure associated with high temperature cycling. We proposed to synthesize and characterize novel anode cermets materials based on ceria doped with Pr and/or Gd together with either a Ni or Cu metallic components. Ceria is a good oxidation catalyst and is an ionic conductor at room temperature. Doping it with trivalent rare earths such as Pr or Gd retards sintering and makes it a mixed ion conductor (ionic and electronic). We have developed a fundamental scientific understanding of the behavior of the cermet material under reaction conditions by following the catalytic oxidation process at the atomic scale using a powerful Environmental Scanning Transmission Electron Microscope (ESTEM). The ESTEM allowed in situ monitoring of structural, chemical and morphological changes occurring at the cermet under conditions approximating that of typical fuel-cell operation. Density functional calculations were employed to determine the underlying mechanisms and reaction pathways during anode oxidation reactions. The dynamic behavior of nanoscale catalytic oxidation of hydrogen and methane were used to determine: ? Fundamental processes during anodic reactions in hydrogen and carbonaceous atmospheres ? Interfacial effects between metal particles and doped ceria ? Kinetics of redox reaction in the anode material

  16. Deep Energy Retrofits & State Applications

    Broader source: Energy.gov [DOE]

    This presentation, given through the DOE's Technical Assitance Program (TAP), provides information on Deep Energy Retrofits & State Applications

  17. Nervana Neon - Scalable Deep Learning library

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Neon Nervana Neon - Scalable Deep Learning library Description and Overview neon is an easy to use, python-based scalable Deep Learning library. Deep Learning has recently achieved...

  18. METHOD OF LOCATING GROUNDS

    DOE Patents [OSTI]

    Macleish, K.G.

    1958-02-11

    ABS>This patent presents a method for locating a ground in a d-c circult having a number of parallel branches connected across a d-c source or generator. The complete method comprises the steps of locating the ground with reference to the mildpoint of the parallel branches by connecting a potentiometer across the terminals of the circuit and connecting the slider of the potentiometer to ground through a current indicating instrument, adjusting the slider to right or left of the mildpoint so as to cause the instrument to indicate zero, connecting the terminal of the network which is farthest from the ground as thus indicated by the potentiometer to ground through a condenser, impressing a ripple voltage on the circuit, and then measuring the ripple voltage at the midpoint of each parallel branch to find the branch in which is the lowest value of ripple voltage, and then measuring the distribution of the ripple voltage along this branch to determine the point at which the ripple voltage drops off to zero or substantially zero due to the existence of a ground. The invention has particular application where a circuit ground is present which will disappear if the normal circuit voltage is removed.

  19. Low cost fuel cell diffusion layer configured for optimized anode water management

    DOE Patents [OSTI]

    Owejan, Jon P; Nicotera, Paul D; Mench, Matthew M; Evans, Robert E

    2013-08-27

    A fuel cell comprises a cathode gas diffusion layer, a cathode catalyst layer, an anode gas diffusion layer, an anode catalyst layer and an electrolyte. The diffusion resistance of the anode gas diffusion layer when operated with anode fuel is higher than the diffusion resistance of the cathode gas diffusion layer. The anode gas diffusion layer may comprise filler particles having in-plane platelet geometries and be made of lower cost materials and manufacturing processes than currently available commercial carbon fiber substrates. The diffusion resistance difference between the anode gas diffusion layer and the cathode gas diffusion layer may allow for passive water balance control.

  20. Battery with modular air cathode and anode cage

    DOE Patents [OSTI]

    Niksa, Marilyn J.; Pohto, Gerald R.; Lakatos, Leslie K.; Wheeler, Douglas J.; Niksa, Andrew J.; Schue, Thomas J.

    1987-01-01

    A battery assembly of the consumable metal anode type has now been constructed for ready assembly as well as disassembly. In a non-conductive and at least substantially inert cell body, space is provided for receiving an open-structured, non-consumable anode cage. The cage has an open top for facilitating insertion of an anode. A modular cathode is used, comprising a peripheral current conductor frame clamped about a grid reinforced air cathode in sheet form. The air cathode may be double gridded. The cathode frame can be sealed, during assembly, with electrolyte-resistant-sealant as well as with adhesive. The resulting cathode module can be assembled outside the cell body and readily inserted therein, or can later be easily removed therefrom.

  1. Battery with modular air cathode and anode cage

    DOE Patents [OSTI]

    Niksa, Marilyn J.; Pohto, Gerald R.; Lakatos, Leslie K.; Wheeler, Douglas J.; Niksa, Andrew J.; Schue, Thomas J.; Turk, Thomas R.

    1988-01-01

    A battery assembly of the consumable metal anode type has now been constructed for ready assembly as well as disassembly. In a non-conductive and at least substantially inert cell body, space is provided for receiving an open-structured, non-consumable anode cage. The cage has an open top for facilitating insertion of an anode. A modular cathode is used, comprising a peripheral current conductor frame clamped about a grid reinforced air cathode in sheet form. The air cathode may be double gridded. The cathode frame can be sealed, during assembly, with electrolyte-resistant-sealant as well as with adhesive. The resulting cathode module can be assembled outside the cell body and readily inserted therein, or can later be easily removed therefrom.

  2. The possibility of forming a sacrificial anode coating for Mg

    SciTech Connect (OSTI)

    Dudney, Nancy J; Li, Juchuan; Sacci, Robert L; Thomson, Jeffery K

    2014-01-01

    Mg is the most active engineering metal, and is often used as a sacrificial anode/coating to protect other engineering metals from corrosion attack. So far no sacrificial anode coating has been developed or considered for Mg. This study explores the possibility of forming a sacrificial coating for Mg. A lithiated carbon coating and a metaphosphated coating are applied on the Mg surface, respectively, and their open-circuit-potentials are measured in saturated Mg(OH)2 solution. They exhibit more negative potentials than bare Mg. SEM reveals that the metaphosphated coating offers more effective and uniform protection for Mg than the lithiated carbon coating. These preliminary results indicate that development of a sacrificial anode coating for Mg is indeed possible.

  3. Ground potential rise monitor

    DOE Patents [OSTI]

    Allen, Zachery Warren; Zevenbergen, Gary Allen

    2012-07-17

    A device and method for detecting ground potential rise (GPR) comprising a first electrode, a second electrode, and a voltage attenuator. The first electrode and the second electrode are both electrically connected to the voltage attenuator. A means for determining the presence of a dangerous ground potential is connected to the voltage attenuator. The device and method further comprises a means for enabling one or more alarms upon the detection of the dangerous ground potential. Preferably, a first transmitter/receiver is connected to the means for enabling one or more alarms. Preferably, a second transmitter/receiver, comprising a button, is electromagnetically connected to the first transmitter/receiver. Preferably, the means for determining the presence of a dangerous ground potential comprises a means for determining the true RMS voltage at the output of the voltage attenuator, a transient detector connected to the output of the voltage attenuator, or a combination thereof.

  4. Overview of SOFC Anode Interactions with Coal Gas Impurities

    SciTech Connect (OSTI)

    O. A. Marina; L. R. Pederson; R. Gemmen; K. Gerdes; H. Finklea; I. B. Celik

    2010-03-01

    An overview of the results of SOFC anode interactions with phosphorus, arsenic, selenium, sulfur, antimony, and hydrogen chloride as single contaminants or in combinations is discussed. Tests were performed using both anode- and electrolyte-supported cells in synthetic and actual coal gas for periods greater than 1000 hours. Post-test analyses were performed to identify reaction products formed and their distribution, and compared to phases expected from thermochemical modeling. The ultimate purpose of this work is to establish maximum permissible concentrations for impurities in coal gas, to aid in the selection of appropriate coal gas clean-up technologies.

  5. Overview of SOFC Anode Interactions with Coal Gas Impurities

    SciTech Connect (OSTI)

    Marina, Olga A.; Pederson, Larry R.; Gemmen, Randall; Gerdes, Kirk; Finklea, Harry; Celik, Ismail B.

    2010-05-01

    An overview of the results of SOFC anode interactions with phosphorus, arsenic, selenium, sulfur, antimony, and hydrogen chloride as single contaminants or in combinations is discussed. Tests were performed using both anode- and electrolyte-supported cells in synthetic and actual coal gas for periods greater than 1000 hours. Post-test analyses were performed to identify reaction products formed and their distribution, and compared to phases expected from thermochemical modeling. The ultimate purpose of this work is to establish maximum permissible concentrations for impurities in coal gas, to aid in the selection of appropriate coal gas clean-up technologies.

  6. Color Anodizing of Titanium Coated Rolled Carbon Steel Plate

    SciTech Connect (OSTI)

    Sarajan, Zohair; Mobarakeh, Hooman Nikbakht; Namiranian, Sohrab

    2011-12-26

    As an important kind of structural materials, the titanium cladded steel plates have the advantages of both metals and have been applied in aviation, spaceflight, chemical and nuclear industries. In this study, the specimens which were prepared under soldering mechanism during rolling were anodized by electrochemical process under a given conditions. The color anodizing takes place by physical phenomenon of color interference. Part of incident light on the titanium oxide is reflected and the other part reflects inside coated titanium layer. Major part of the light which reflects from titanium-oxide interface, reflects again inside of the oxide layer.

  7. Oxygen-producing inert anodes for SOM process

    DOE Patents [OSTI]

    Pal, Uday B

    2014-02-25

    An electrolysis system for generating a metal and molecular oxygen includes a container for receiving a metal oxide containing a metallic species to be extracted, a cathode positioned to contact a metal oxide housed within the container; an oxygen-ion-conducting membrane positioned to contact a metal oxide housed within the container; an anode in contact with the oxygen-ion-conducting membrane and spaced apart from a metal oxide housed within the container, said anode selected from the group consisting of liquid metal silver, oxygen stable electronic oxides, oxygen stable crucible cermets, and stabilized zirconia composites with oxygen stable electronic oxides.

  8. Electrolytic production of metals using a resistant anode

    DOE Patents [OSTI]

    Tarcy, G.P.; Gavasto, T.M.; Ray, S.P.

    1986-11-04

    An electrolytic process is described comprising evolving oxygen on an anode in a molten salt, the anode comprising an alloy comprising a first metal and a second metal, both metals forming oxides, the oxide of the first metal being more resistant than the second metal to attack by the molten salt, the oxide of the second metal being more resistant than the first metal to the diffusion of oxygen. The electrode may also be formed of CuAlO[sub 2] and/or Cu[sub 2]O. 2 figs.

  9. Sulfur-tolerant anode material for direct hydrocarbon solid oxide fuel cells

    DOE Patents [OSTI]

    Chen, Fanglin; Yang, Chenghao; Yang, Zhibin

    2016-08-02

    In one aspect, the present subject matter is directed to a composite anode for a hydrocarbon solid oxide fuel cell, the anode comprising a layered perovskite ceramic and a bi-metallic alloy.

  10. Solid state thin film battery having a high temperature lithium alloy anode

    DOE Patents [OSTI]

    Hobson, David O.

    1998-01-01

    An improved rechargeable thin-film lithium battery involves the provision of a higher melting temperature lithium anode. Lithium is alloyed with a suitable solute element to elevate the melting point of the anode to withstand moderately elevated temperatures.

  11. Protective lithium ion conducting ceramic coating for lithium metal anodes and associate method

    DOE Patents [OSTI]

    Bates, John B.

    1994-01-01

    A battery structure including a cathode, a lithium metal anode and an electrolyte disposed between the lithium anode and the cathode utilizes a thin-film layer of lithium phosphorus oxynitride overlying so as to coat the lithium anode and thereby separate the lithium anode from the electrolyte. If desired, a preliminary layer of lithium nitride may be coated upon the lithium anode before the lithium phosphorous oxynitride is, in turn, coated upon the lithium anode so that the separation of the anode and the electrolyte is further enhanced. By coating the lithium anode with this material lay-up, the life of the battery is lengthened and the performance of the battery is enhanced.

  12. Effect of the Anion Activity on the Stability of Li Metal Anodes...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Li Metal Anodes in Lithium-Sulfur Batteries The lithium metal anode (bottom) ... Significance and Impact Identified one reason behind Li-S batteries failing to hold a ...

  13. Novel Approach to Advanced Direct Methanol Fuel Cell Anode Catalysts (Presentation)

    SciTech Connect (OSTI)

    Dinh, H.; Gennett, T.

    2010-06-11

    This presentation is a summary of a Novel Approach to Advanced Direct Methanol Fuel Cell Anode Catalysts.

  14. Structural micro-porous carbon anode for rechargeable lithium-ion batteries

    DOE Patents [OSTI]

    Delnick, F.M.; Even, W.R. Jr.; Sylwester, A.P.; Wang, J.C.F.; Zifer, T.

    1995-06-20

    A secondary battery having a rechargeable lithium-containing anode, a cathode and a separator positioned between the cathode and anode with an organic electrolyte solution absorbed therein is provided. The anode comprises three-dimensional microporous carbon structures synthesized from polymeric high internal phase emulsions or materials derived from this emulsion source, i.e., granules, powders, etc. 6 figs.

  15. Structural micro-porous carbon anode for rechargeable lithium-ion batteries

    DOE Patents [OSTI]

    Delnick, Frank M.; Even, Jr., William R.; Sylwester, Alan P.; Wang, James C. F.; Zifer, Thomas

    1995-01-01

    A secondary battery having a rechargeable lithium-containing anode, a cathode and a separator positioned between the cathode and anode with an organic electrolyte solution absorbed therein is provided. The anode comprises three-dimensional microporous carbon structures synthesized from polymeric high internal phase emulsions or materials derived from this emulsion source, i.e., granules, powders, etc.

  16. Reduced temperature aluminum production in an electrolytic cell having an inert anode

    DOE Patents [OSTI]

    Dawless, Robert K.; Ray, Siba P.; Hosler, Robert B.; Kozarek, Robert L.; LaCamera, Alfred F.

    2000-01-01

    Aluminum is produced by electrolytic reduction of alumina in a cell having a cathode, an inert anode and a molten salt bath containing metal fluorides and alumina. The inert anode preferably contains copper, silver and oxides of iron and nickel. Reducing the molten salt bath temperature to about 900-950.degree. C. lowers corrosion on the inert anode constituents.

  17. New High-Energy Nanofiber Anode Materials | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    0_zhang_2011_p.pdf (472.78 KB) More Documents & Publications New High-Energy Nanofiber Anode Materials FY 2011 Annual Progress Report for Energy Storage R&D FY 2012 Annual Progress Report for Energy Storage R&D

  18. Synthesis and characterization of anodized titanium-oxide nanotube arrays

    SciTech Connect (OSTI)

    Hu, Michael Z.; Lai, Peng; Bhuiyan, Md S; Tsouris, Costas; Gu, Baohua; Paranthaman, Mariappan Parans; Gabitto, Jorge; Harrison, L. D.

    2009-01-01

    Anodized titanium-oxide containing highly ordered, vertically oriented TiO2 nanotube arrays is a nanomaterial architecture that shows promise for diverse applications. In this paper, an anodization synthesis using HF-free aqueous solution is described. The anodized TiO2 film samples (amorphous, anatase, and rutile) on titanium foils were characterized with scanning electron microscopy, X-ray diffraction, and Raman spectroscopy. Additional characterization in terms of photocurrent generated by an anode consisting of a titanium foil coated by TiO2 nanotubes was performed using an electrochemical cell. A platinum cathode was used in the electrochemical cell. Results were analyzed in terms of the efficiency of the current generated, defined as the ratio of the difference between the electrical energy output and the electrical energy input divided by the input radiation energy, with the goal of determining which phase of TiO2 nanotubes leads to more efficient hydrogen production. It was determined that the anatase crystalline structure converts light into current more efficiently and is therefore a better photocatalytic material for hydrogen production via photoelectrochemical splitting of water.

  19. Anode Materials for Rechargeable Li-Ion Batteries

    SciTech Connect (OSTI)

    Fultz, B.

    2001-01-12

    This research is on materials for anodes and cathodes in electrochemical cells. The work is a mix of electrochemical measurements and analysis of the materials by transmission electron microscopy and x-ray diffractometry. At present, our experimental work involves only materials for Li storage, but we have been writing papers from our previous work on hydrogen-storage materials.

  20. High Rate and Stable Cycling of Lithium Metal Anode

    SciTech Connect (OSTI)

    Qian, Jiangfeng; Henderson, Wesley A.; Xu, Wu; Bhattacharya, Priyanka; Engelhard, Mark H.; Borodin, Oleg; Zhang, Jiguang

    2015-02-20

    Lithium (Li) metal is an ideal anode material for rechargeable batteries. However, dendritic Li growth and limited Coulombic efficiency (CE) during repeated Li deposition/stripping processes have prevented the application of this anode in rechargeable Li metal batteries, especially for use at high current densities. Herein, we report that the use of highly concentrated electrolytes composed of ether solvents and the lithium bis(fluorosulfonyl)imide (LiFSI) salt enables the high rate cycling of a Li metal anode at high CE (up to 99.1 %) without dendrite growth. With 4 M LiFSI in 1,2-dimethoxyethane (DME) as the electrolyte, a Li|Li cell can be cycled at high rates (10 mA cm-2) for more than 6000 cycles with no increase in the cell impedance, and a Cu|Li cell can be cycled at 4 mA cm-2 for more than 1000 cycles with an average CE of 98.4%. These excellent high rate performances can be attributed to the increased solvent coordination and increased availability of Li+ concentration in the electrolyte. Further development of this electrolyte may lead to practical applications for Li metal anode in rechargeable batteries. The fundamental mechanisms behind the high rate ion exchange and stability of the electrolytes also shine light on the stability of other electrochemical systems.

  1. Aerogel and xerogel composites for use as carbon anodes

    DOE Patents [OSTI]

    Cooper, John F.; Tillotson, Thomas M.; Hrubesh, Lawrence W.

    2008-08-12

    Disclosed herein are aerogel and xerogel composite materials suitable for use as anodes in fuel cells and batteries. Precursors to the aerogel and xerogel compounds are infused with inorganic polymeric materials or carbon particles and then gelled. The gels are then pyrolyzed to form composites with internal structural support.

  2. Sulfur tolerant molten carbonate fuel cell anode and process

    DOE Patents [OSTI]

    Remick, Robert J.

    1990-01-01

    Molten carbonate fuel cell anodes incorporating a sulfur tolerant carbon monoxide to hydrogen water-gas-shift catalyst provide in situ conversion of carbon monoxide to hydrogen for improved fuel cell operation using fuel gas mixtures of over about 10 volume percent carbon monoxide and up to about 10 ppm hydrogen sulfide.

  3. High rate and stable cycling of lithium metal anode

    SciTech Connect (OSTI)

    Qian, Jiangfeng; Henderson, Wesley A.; Xu, Wu; Bhattacharya, Priyanka; Engelhard, Mark H.; Borodin, Oleg; Zhang, Jiguang

    2015-02-20

    Lithium (Li) metal is an ideal anode material for rechargeable batteries. However, dendritic Li growth and limited Coulombic efficiency (CE) during repeated Li deposition/stripping processes have prevented the application of this anode in rechargeable Li metal batteries, especially for use at high current densities. Here, we report that the use of highly concentrated electrolytes composed of ether solvents and the lithium bis(fluorosulfonyl)imide (LiFSI) salt enables the high rate cycling of a Li metal anode at high CE (up to 99.1 %) without dendrite growth. With 4 M LiFSI in 1,2-dimethoxyethane (DME) as the electrolyte, a Li|Li cell can be cycled at high rates (10 mA cm-2) for more than 6000 cycles with no increase in the cell impedance, and a Cu|Li cell can be cycled at 4 mA cm-2 for more than 1000 cycles with an average CE of 98.4%. These excellent high rate performances can be attributed to the increased solvent coordination and increased availability of Li+ concentration in the electrolyte. Lastly, further development of this electrolyte may lead to practical applications for Li metal anode in rechargeable batteries. The fundamental mechanisms behind the high rate ion exchange and stability of the electrolytes also shine light on the stability of other electrochemical systems.

  4. High rate and stable cycling of lithium metal anode

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Qian, Jiangfeng; Henderson, Wesley A.; Xu, Wu; Bhattacharya, Priyanka; Engelhard, Mark H.; Borodin, Oleg; Zhang, Jiguang

    2015-02-20

    Lithium (Li) metal is an ideal anode material for rechargeable batteries. However, dendritic Li growth and limited Coulombic efficiency (CE) during repeated Li deposition/stripping processes have prevented the application of this anode in rechargeable Li metal batteries, especially for use at high current densities. Here, we report that the use of highly concentrated electrolytes composed of ether solvents and the lithium bis(fluorosulfonyl)imide (LiFSI) salt enables the high rate cycling of a Li metal anode at high CE (up to 99.1 %) without dendrite growth. With 4 M LiFSI in 1,2-dimethoxyethane (DME) as the electrolyte, a Li|Li cell can be cycledmore » at high rates (10 mA cm-2) for more than 6000 cycles with no increase in the cell impedance, and a Cu|Li cell can be cycled at 4 mA cm-2 for more than 1000 cycles with an average CE of 98.4%. These excellent high rate performances can be attributed to the increased solvent coordination and increased availability of Li+ concentration in the electrolyte. Lastly, further development of this electrolyte may lead to practical applications for Li metal anode in rechargeable batteries. The fundamental mechanisms behind the high rate ion exchange and stability of the electrolytes also shine light on the stability of other electrochemical systems.« less

  5. Pd/Ni-WO3 anodic double layer gasochromic device

    DOE Patents [OSTI]

    Lee, Se-Hee; Tracy, C. Edwin; Pitts, J. Roland; Liu, Ping

    2004-04-20

    An anodic double layer gasochromic sensor structure for optical detection of hydrogen in improved response time and with improved optical absorption real time constants, comprising: a glass substrate; a tungsten-doped nickel oxide layer coated on the glass substrate; and a palladium layer coated on the tungsten-doped nickel oxide layer.

  6. Substation grounding programs

    SciTech Connect (OSTI)

    Meliopoulos, A.P.S. . Electric Power Lab.)

    1992-05-01

    This document is a users manual and applications guide for the software package SGA. This package comprises four computer programs, namely SOMIP, SMECC, SGSYS, and TGRND. The first three programs are analysis models which are to be used in the design process of substation grounding systems. The fourth program, TGRND, is an analysis program for determining the transient response of a grounding system. This report, Volume 5, is an applications guide of the three computer programs. SOMIP, SMECC, and SGSYS, for the purpose of designing a safe substation grounding system. The applications guide utilizes four example substation grounding systems for the purpose of illustrating the application of the programs, SOMIP, SMECC, and SGSYS. The examples are based on data provided by four contributing utilities, namely, Houston Lighting and Power Company, Southern Company Services, Puget Sound Power and Light Company, and Arizona Public Service Company. For the purpose of illustrating specific capabilities of the computer programs, the data have been modified. As a result, the final designs of the four systems do not necessarily represent actual grounding system designs by these utilities. The example system 1 is a 138 kV/35 kV distribution substation. The example system 2 is a medium size 230 kV/115 kV transmission substation. The third example system is a generation substation while the last is a large 525 kV/345 kV/230 kV transmission substation. The four examples cover most of the practical problems that a user may encounter in the design of substation grounding systems.

  7. Optimization and Domestic Sourcing of Lithium Ion Battery Anode Materials

    SciTech Connect (OSTI)

    Wood, III, D. L.; Yoon, S.

    2012-10-25

    The purpose of this Cooperative Research and Development Agreement (CRADA) between ORNL and A123Systems, Inc. was to develop a low-temperature heat treatment process for natural graphite based anode materials for high-capacity and long-cycle-life lithium ion batteries. Three major problems currently plague state-of-the-art lithium ion battery anode materials. The first is the cost of the artificial graphite, which is heat-treated well in excess of 2000°C. Because of this high-temperature heat treatment, the anode active material significantly contributes to the cost of a lithium ion battery. The second problem is the limited specific capacity of state-of-the-art anodes based on artificial graphites, which is only about 200-350 mAh/g. This value needs to be increased to achieve high energy density when used with the low cell-voltage nanoparticle LiFePO4 cathode. Thirdly, the rate capability under cycling conditions of natural graphite based materials must be improved to match that of the nanoparticle LiFePO4. Natural graphite materials contain inherent crystallinity and lithium intercalation activity. They hold particular appeal, as they offer huge potential for industrial energy savings with the energy costs essentially subsidized by geological processes. Natural graphites have been heat-treated to a substantially lower temperature (as low as 1000-1500°C) and used as anode active materials to address the problems described above. Finally, corresponding graphitization and post-treatment processes were developed that are amenable to scaling to automotive quantities.

  8. Deep drawing of uranium metal

    SciTech Connect (OSTI)

    Jackson, R J; Lundberg, M R

    1987-01-19

    A procedure was developed to fabricate uranium forming blanks with high ''draw-ability'' so that cup shapes could be easily and uniformly deep drawn. The overall procedure involved a posttreatment to develop optimum mechanical and structural properties in the deep-drawn cups. The fabrication sequence is casting high-purity logs, pucking cast logs, cross-rolling pucks to forming blanks, annealing and outgassing forming blanks, cold deep drawing to hemispherical shapes, and stress relieving, outgassing, and annealing deep-drawn parts to restore ductility and impart dimensional stability. The fabrication development and the resulting fabrication procedure are discussed in detail. The mechanical properties and microstructural properties are discussed.

  9. A deep earthquake goes supershear

    SciTech Connect (OSTI)

    Wilson, R. Mark

    2014-09-01

    Seismic analysis of an aftershock off Russias Kamchatka Peninsula offers evidence that deep earthquakes are more complicated than geoscientists realized.

  10. Method of deep drilling

    DOE Patents [OSTI]

    Colgate, Stirling A.

    1984-01-01

    Deep drilling is facilitated by the following steps practiced separately or in any combination: (1) Periodically and sequentially fracturing zones adjacent the bottom of the bore hole with a thixotropic fastsetting fluid that is accepted into the fracture to overstress the zone, such fracturing and injection being periodic as a function of the progression of the drill. (2) Casing the bore hole with ductile, pre-annealed casing sections, each of which is run down through the previously set casing and swaged in situ to a diameter large enough to allow the next section to run down through it. (3) Drilling the bore hole using a drill string of a low density alloy and a high density drilling mud so that the drill string is partially floated.

  11. Battery Anodes > Batteries & Fuel Cells > Research > The Energy Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Center at Cornell Anodes Introduction The anode is the negative electrode of a primary cell and is always associated with the oxidation or the release of electrons into the external circuit. In a rechargeable cell, the anode is the negative pole during discharge and the positive pole during charge. Lithium Anode The anode in the battery deserves an equal say in the overall performance of a battery. For an effective development of a high energy density battery, the use of high capacity

  12. Anodes for Rechargeable Lithium-Sulfur Batteries - Joint Center for Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Storage Research 0, 2015, Research Highlights Anodes for Rechargeable Lithium-Sulfur Batteries Recent developments on the protection of the Li metal anode in Li-S batteries are reviewed. Scientific Achievement Recent developments on the protection of the Li metal anode in Li-S batteries are reviewed. The degradation mechanism of Li metal anode in Li-S batteries were analyzed and discussed. Various strategies used to minimize the corrosion of the Li anode and to mitigate the effect of the

  13. Double hull grounding experiments

    SciTech Connect (OSTI)

    Rodd, J.L.; Sikora, J.P.

    1995-12-31

    In the last few years the public and governments of many nations have become increasingly aware of the need for improving oil tanker safety. The requirements for double hull tankers are an attempt to address this need through legislation. Even though a number of investigations on the mechanics of collisions have been done in the past, until recently very little research supported the development of structural improvements to reduce oil tanker damage during grounding and stranding accidents. An aggressive evaluation of double hull tanker crashworthiness in stranding and grounding accidents is underway at CD/NSWC (formerly the David Taylor Research Center). The ability to predict damage from grounding accidents accurately is not currently available. The objective of this paper is to present qualitatively the structural failure mechanisms associated with stranding and grounding events for candidate double hull tanker structures and to present some simple methods for comparing damage scenarios. A comparison of the structural performance of key features in several very different designs will provide useful information toward this understanding.

  14. Modular anode assemblies and methods of using the same for electrochemical reduction

    SciTech Connect (OSTI)

    Wiedmeyer, Stanley G; Barnes, Laurel A; Williamson, Mark A; Willit, James L

    2015-02-17

    Modular anode assemblies are used in electrolytic oxide reduction systems for scalable reduced metal production via electrolysis. Assemblies include a channel frame connected to several anode rods extending into an electrolyte. An electrical system powers the rods while being insulated from the channel frame. A cooling system removes heat from anode rods and the electrical system. An anode guard attaches to the channel frame to prevent accidental electrocution or damage during handling or repositioning. Each anode rod may be divided into upper and lower sections to permit easy repair and swapping out of lower sections. The modular assemblies may have standardized components to permit placement at multiple points within a reducing system. Example methods may operate an electrolytic oxide reduction system by positioning the modular anode assemblies in the reduction system and applying electrical power to the plurality of anode assemblies.

  15. The anodic surface film and hydrogen evolution on Mg

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Song, Guang -Ling; Unocic, Kinga A.

    2015-06-04

    This paper clarifies that the inner and outer layers of the anodic film consist of a nano/micro-porous MgO+Mg(OH)2 mixture. The film becomes thicker and more porous with increasing potential. It can rupture when potential is too positive in a non-corrosive Mg(OH)2 solution. Hydrogen evolution becomes more intensive as polarization potential increases, particularly when the potential at the film-covered Mg surface is close to or more positive than the hydrogen equilibrium potential, suggesting that an “anodic hydrogen evolution” (AHE) reaction occurs on the substrate Mg in film pores, and the significantly intensified AHE causes film rupture at high potential.

  16. Electrocatalyst for alcohol oxidation at fuel cell anodes

    DOE Patents [OSTI]

    Adzic, Radoslav; Kowal, Andrzej

    2011-11-02

    In some embodiments a ternary electrocatalyst is provided. The electrocatalyst can be used in an anode for oxidizing alcohol in a fuel cell. In some embodiments, the ternary electrocatalyst may include a noble metal particle having a surface decorated with clusters of SnO.sub.2 and Rh. The noble metal particles may include platinum, palladium, ruthenium, iridium, gold, and combinations thereof. In some embodiments, the ternary electrocatalyst includes SnO.sub.2 particles having a surface decorated with clusters of a noble metal and Rh. Some ternary electrocatalysts include noble metal particles with clusters of SnO.sub.2 and Rh at their surfaces. In some embodiments the electrocatalyst particle cores are nanoparticles. Some embodiments of the invention provide a fuel cell including an anode incorporating the ternary electrocatalyst. In some aspects a method of using ternary electrocatalysts of Pt, Rh, and SnO.sub.2 to oxidize an alcohol in a fuel cell is described.

  17. Lithium-boron anodes in nitrate thermal battery cells

    SciTech Connect (OSTI)

    McManis III, G. E.; Fletcher, A. N.; Miles, M. H.

    1985-08-13

    A thermally activated electrochemical cell utilizes a lithium-boron anode and a molten nitrate electrolyte selected from the group consisting of lithium nitrate, a mixture of lithium nitrate and sodium nitrate, a mixture of lithium nitrate and potassium nitrate, and a mixture of lithium nitrate and sodium nitrate with potassium nitrate, to provide improved cell electrical performance. The electrolyte is contained on a fiberglass separator and the electrolyte adjacent to the cathode may contain silver nitrate as well. Current densities over 300 mA/cm/sup 2/ with a usable temperature range of over 150/sup 0/ C. have been obtained. Anode open circuit potentials of about 3.2 V were found with little polarization at 100 mA/cm/sup 2/ and with very slight polarization at 300 mA/cm/sup 2/.

  18. Nanotube composite anode materials improve lithium-ion battery performance

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (ANL-09-034) - Energy Innovation Portal Vehicles and Fuels Vehicles and Fuels Energy Storage Energy Storage Find More Like This Return to Search Nanotube composite anode materials improve lithium-ion battery performance (ANL-09-034) Argonne National Laboratory Contact ANL About This Technology Technology Marketing Summary Rechargeable lithium-ion batteries are a critical technology for many applications, including consumer electronics and electric vehicles. As the demand for hybrid and

  19. "Plasma Thruster with Magnetically Insulated Anode: Inventor Yevgeny

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Raitses | Princeton Plasma Physics Lab Plasma Thruster with Magnetically Insulated Anode: Inventor Yevgeny Raitses This invention relates to a new plasma thruster for space applications. The key innovations of this thruster allow it to effectively ionize different propellants, including gases, liquids and solids, at different flow rates, and to operate with wallout losses. Due to these characteristics and the design simplicity, this thruster can be miniaturized to operate at low power

  20. Interfacial morphology of low-voltage anodic aluminium oxide

    SciTech Connect (OSTI)

    Hu, Naiping; Dongcinn, Xuecheng; He, Xueying; Argekar, Sandip; Zhang, Yan; Browning, Jim; Schaefer, Dale

    2013-01-01

    X-ray reflectivity (XRR) and neutron reflectivity (NR), as well as ultra-smallangle X-ray scattering (USAXS), are used to examine the in-plane and surfacenormal structure of anodic films formed on aluminium alloy AA2024 and pure aluminium. Aluminium and alloy films up to 3500 A thick were deposited on Si wafers by electron beam evaporation of ingots. Porous anodic aluminium oxide (AAO) films are formed by polarizing at constant voltage up to 20 V noble to the open circuit potential. The voltage sweet spot (5 V) appropriate for constant-voltage anodization of such thin films was determined for both alloy and pure Al. In addition, a new concurrent voltage- and current-control protocol was developed to prepare films with larger pores (voltages higher than 5 V), but formed at a controlled current so that pore growth is slow enough to avoid stripping the aluminium substrate layer. USAXS shows that the pore size and interpore spacing are fixed in the first 10 s after initiation of anodization. Pores then grow linearly in time, at constant radius and interpore spacing. Using a combination of XRR and NR, the film density and degree of hydration of the films were determined from the ratio of scattering length densities. Assuming a chemical formula Al2O3xH2O, it was found that x varies from 0.29 for the native oxide to 1.29 for AAO grown at 20 V under concurrent voltage and current control. The average AAO film density of the porous film at the air surface is 2.45 (20) g cm3. The density of the barrier layer at the metal interface is 2.9 (4) g cm3, which indicates that this layer is also quite porous

  1. Electrocatalyst for Alcohol Oxidation at Fuel Cell Anodes - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovation Portal Alcohol Oxidation at Fuel Cell Anodes Brookhaven National Laboratory Contact BNL About This Technology Publications: PDF Document Publication Ternary Pt/Rh/SnO2 electrocatalysts for oxidizing ethanol to CO2 (2,641 KB) <p> Scanning transmission electron micrograph showing uniform dispersion of the catalyst particles (bright spots) on the carbon support (dark background). The average particle size is about 1.5&nbsp;nm.</p> Scanning transmission electron

  2. Thermal Neutron Detectors with Discrete Anode Pad Readout

    SciTech Connect (OSTI)

    Yu,B.; Schaknowski, N.A., Smith, G.C., DeGeronimo, G., Vernon, E.O.

    2008-10-19

    A new two-dimensional thermal neutron detector concept that is capable of very high rates is being developed. It is based on neutron conversion in {sup 3}He in an ionization chamber (unity gas gain) that uses only a cathode and anode plane; there is no additional electrode such as a Frisch grid. The cathode is simply the entrance window, and the anode plane is composed of discrete pads, each with their own readout electronics implemented via application specific integrated circuits. The aim is to provide a new generation of detectors with key characteristics that are superior to existing techniques, such as higher count rate capability, better stability, lower sensitivity to background radiation, and more flexible geometries. Such capabilities will improve the performance of neutron scattering instruments at major neutron user facilities. In this paper, we report on progress with the development of a prototype device that has 48 x 48 anode pads and a sensitive area of 24cm x 24cm.

  3. Inward Lithium-Ion Breathing of Hierarchically Porous Silicon Anodes

    SciTech Connect (OSTI)

    Xiao, Qiangfeng; Gu, Meng; Yang, Hui; Li, Bing; Zhang, Cunman; Liu, Yang; Liu, Fang; Dai, Fang; Yang, Li; Liu, Zhongyi; Xiao, Xingcheng; Liu, Gao; Zhao, Peng; Zhang, Sulin; Wang, Chong M.; Lu, Yunfeng; Cai, Mei

    2015-11-05

    Silicon has been identified as one of the most promising candidates as anode for high performance lithium-ion batteries. The key challenge for Si anodes is the large volume change induced chemomechanical fracture and subsequent rapid capacity fading upon cyclic charge and discharge. Improving capacity retention thus critically relies on smart accommodation of the volume changes through nanoscale structural design. In this work, we report a novel fabrication method for hierarchically porous Si nanospheres (hp-SiNSs), which consist of a porous shell and a hollow core. Upon charge/discharge cycling, the hp-SiNSs accommodate the volume change through reversible inward expansion/contraction with negligible particle-level outward expansion. Our mechanics analysis revealed that such a unique volume-change accommodation mechanism is enabled by the much stiffer modulus of the lithiated layer than the unlithiated porous layer and the low flow stress of the porous structure. Such inward expansion shields the hp-SiNSs from fracture, opposite to the outward expansion in solid Si during lithiation. Lithium ion battery assembled with this new nanoporous material exhibits high capacity, high power, long cycle life and high coulombic efficiency, which is superior to the current commercial Si-based anode materials. The low cost synthesis approach reported here provides a new avenue for the rational design of hierarchically porous structures with unique materials properties.

  4. Inward Lithium-Ion Breathing of Hierarchically Porous Silicon Anodes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Xiao, Qiangfeng; Gu, Meng; Yang, Hui; Li, Bing; Zhang, Cunman; Liu, Yang; Liu, Fang; Dai, Fang; Yang, Li; Liu, Zhongyi; et al

    2015-11-05

    Silicon has been identified as one of the most promising candidates as anode for high performance lithium-ion batteries. The key challenge for Si anodes is the large volume change induced chemomechanical fracture and subsequent rapid capacity fading upon cyclic charge and discharge. Improving capacity retention thus critically relies on smart accommodation of the volume changes through nanoscale structural design. In this work, we report a novel fabrication method for hierarchically porous Si nanospheres (hp-SiNSs), which consist of a porous shell and a hollow core. Upon charge/discharge cycling, the hp-SiNSs accommodate the volume change through reversible inward expansion/contraction with negligible particle-levelmore » outward expansion. Our mechanics analysis revealed that such a unique volume-change accommodation mechanism is enabled by the much stiffer modulus of the lithiated layer than the unlithiated porous layer and the low flow stress of the porous structure. Such inward expansion shields the hp-SiNSs from fracture, opposite to the outward expansion in solid Si during lithiation. Lithium ion battery assembled with this new nanoporous material exhibits high capacity, high power, long cycle life and high coulombic efficiency, which is superior to the current commercial Si-based anode materials. We find the low cost synthesis approach reported here provides a new avenue for the rational design of hierarchically porous structures with unique materials properties.« less

  5. Inward Lithium-Ion Breathing of Hierarchically Porous Silicon Anodes

    SciTech Connect (OSTI)

    Xiao, Qiangfeng; Gu, Meng; Yang, Hui; Li, Bing; Zhang, Cunman; Liu, Yang; Liu, Fang; Dai, Fang; Yang, Li; Liu, Zhongyi; Xiao, Xingcheng; Liu, Gao; Zhao, Peng; Zhang, Sulin; Wang, Chong M.; Lu, Yunfeng; Cai, Mei

    2015-11-05

    Silicon has been identified as one of the most promising candidates as anode for high performance lithium-ion batteries. The key challenge for Si anodes is the large volume change induced chemomechanical fracture and subsequent rapid capacity fading upon cyclic charge and discharge. Improving capacity retention thus critically relies on smart accommodation of the volume changes through nanoscale structural design. In this work, we report a novel fabrication method for hierarchically porous Si nanospheres (hp-SiNSs), which consist of a porous shell and a hollow core. Upon charge/discharge cycling, the hp-SiNSs accommodate the volume change through reversible inward expansion/contraction with negligible particle-level outward expansion. Our mechanics analysis revealed that such a unique volume-change accommodation mechanism is enabled by the much stiffer modulus of the lithiated layer than the unlithiated porous layer and the low flow stress of the porous structure. Such inward expansion shields the hp-SiNSs from fracture, opposite to the outward expansion in solid Si during lithiation. Lithium ion battery assembled with this new nanoporous material exhibits high capacity, high power, long cycle life and high coulombic efficiency, which is superior to the current commercial Si-based anode materials. We find the low cost synthesis approach reported here provides a new avenue for the rational design of hierarchically porous structures with unique materials properties.

  6. Deep Sludge Gas Release Event Analytical Evaluation

    SciTech Connect (OSTI)

    Sams, Terry L.

    2013-08-15

    Long Abstract. Full Text. The purpose of the Deep Sludge Gas Release Event Analytical Evaluation (DSGRE-AE) is to evaluate the postulated hypothesis that a hydrogen GRE may occur in Hanford tanks containing waste sludges at levels greater than previously experienced. There is a need to understand gas retention and release hazards in sludge beds which are 200 -300 inches deep. These sludge beds are deeper than historical Hanford sludge waste beds, and are created when waste is retrieved from older single-shell tanks (SST) and transferred to newer double-shell tanks (DST).Retrieval of waste from SSTs reduces the risk to the environment from leakage or potential leakage of waste into the ground from these tanks. However, the possibility of an energetic event (flammable gas accident) in the retrieval receiver DST is worse than slow leakage. Lines of inquiry, therefore, are (1) can sludge waste be stored safely in deep beds; (2) can gas release events (GRE) be prevented by periodically degassing the sludge (e.g., mixer pump); or (3) does the retrieval strategy need to be altered to limit sludge bed height by retrieving into additional DSTs? The scope of this effort is to provide expert advice on whether or not to move forward with the generation of deep beds of sludge through retrieval of C-Farm tanks. Evaluation of possible mitigation methods (e.g., using mixer pumps to release gas, retrieving into an additional DST) are being evaluated by a second team and are not discussed in this report. While available data and engineering judgment indicate that increased gas retention (retained gas fraction) in DST sludge at depths resulting from the completion of SST 241-C Tank Farm retrievals is not expected and, even if gas releases were to occur, they would be small and local, a positive USQ was declared (Occurrence Report EM-RP--WRPS-TANKFARM-2012-0014, "Potential Exists for a Large Spontaneous Gas Release Event in Deep Settled Waste Sludge"). The purpose of this technical

  7. Position-sensitive proportional counter with low-resistance metal-wire anode

    DOE Patents [OSTI]

    Kopp, Manfred K.

    1980-01-01

    A position-sensitive proportional counter circuit is provided which allows the use of a conventional (low-resistance, metal-wire anode) proportional counter for spatial resolution of an ionizing event along the anode of the counter. A pair of specially designed active-capacitance preamplifiers are used to terminate the anode ends wherein the anode is treated as an RC line. The preamplifiers act as stabilized active capacitance loads and each is composed of a series-feedback, low-noise amplifier, a unity-gain, shunt-feedback amplifier whose output is connected through a feedback capacitor to the series-feedback amplifier input. The stabilized capacitance loading of the anode allows distributed RC-line position encoding and subsequent time difference decoding by sensing the difference in rise times of pulses at the anode ends where the difference is primarily in response to the distributed capacitance along the anode. This allows the use of lower resistance wire anodes for spatial radiation detection which simplifies the counter construction and handling of the anodes, and stabilizes the anode resistivity at high count rates (>10.sup.6 counts/sec).

  8. Analysis of Cadmium in Undissolved Anode Materials of Mark-IV Electrorefiner

    SciTech Connect (OSTI)

    Tae-Sic Yoo; Guy L. Fredrickson; DeeEarl Vaden; Brian R. Westphal

    2013-10-01

    The Mark-IV electrorefiner (Mk-IV ER) contains an electrolyte/molten cadmium system for refining uranium electrochemically. Typically, the anode of the Mk-IV ER consists of the chopped sodium-bonded metallic driver fuels, which have been primarily U-10Zr binary fuels. Chemical analysis of the residual anode materials after electrorefining indicates that a small amount of cadmium is removed from the Mk-IV ER along with the undissolved anode materials. Investigation of chemical analysis data indicates that the amount of cadmium in the undissolved anode materials is strongly correlated with the anode rotation speeds and the residence time of the anode in the Mk-IV ER. Discussions are given to explain the prescribed correlation.

  9. Cu--Ni--Fe anode for use in aluminum producing electrolytic cell

    DOE Patents [OSTI]

    Bergsma, S. Craig; Brown, Craig W.; Bradford, Donald R; Barnett, Robert J.; Mezner, Michael B.

    2006-07-18

    A method of producing aluminum in an electrolytic cell containing alumina dissolved in an electrolyte, the method comprising the steps of providing a molten salt electrolyte at a temperature of less than 900.degree. C. having alumina dissolved therein in an electrolytic cell having a liner for containing the electrolyte, the liner having a bottom and walls extending upwardly from said bottom. A plurality of non-consumable Cu--Ni--Fe anodes and cathodes are disposed in a vertical direction in the electrolyte, the cathodes having a plate configuration and the anodes having a flat configuration to compliment the cathodes. The anodes contain apertures therethrough to permit flow of electrolyte through the apertures to provide alumina-enriched electrolyte between the anodes and the cathodes. Electrical current is passed through the anodes and through the electrolyte to the cathodes, depositing aluminum at the cathodes and producing gas at the anodes.

  10. Electrochemical aging of humectant-treated thermal-sprayed zinc anodes for cathodic protection

    SciTech Connect (OSTI)

    Covino, B.S. Jr.; Holcomb, G.R.; Bullard, S.J.; Russell, J.H.; Cramer, S.D.; Bennett, J.E.; Laylor, H.M.

    1999-07-01

    Humectants, substances that promote the retention of moisture, were studied to determine their effectiveness in improving the performance and extending the service life of both new and previously-aged thermal-sprayed Zn anodes used in impressed current (ICCP) and galvanic cathodic protection (GCP) systems for steel-reinforced concrete structures. Potassium acetate, lithium nitrate, and lithium bromide were applied to a series of thermal-sprayed Zn-coated concrete slabs before starting the ICCP or GCP experiment. All of the humectants altered the behavior of the thermal-sprayed Zn anodes. LiNO{sub 3} was the most beneficial for ICCP anodes and LiBr was the most beneficial for GCP anodes. Circuit resistances for ICCP anodes and galvanic current density for GCP anodes are compared on the basis of electrochemical aging, humidity, and type of humectant.

  11. Exciton quenching at PEDOT:PSS anode in polymer blue-light-emitting diodes

    SciTech Connect (OSTI)

    Abbaszadeh, D.; Wetzelaer, G. A. H.; Nicolai, H. T.

    2014-12-14

    The quenching of excitons at the poly(3,4-ethylenedioxythiophene):poly(styrenesulfonic acid) (PEDOT:PSS) anode in blue polyalkoxyspirobifluorene-arylamine polymer light-emitting diodes is investigated. Due to the combination of a higher electron mobility and the presence of electron traps, the recombination zone shifts from the cathode to the anode with increasing voltage. The exciton quenching at the anode at higher voltages leads to an efficiency roll-off. The voltage dependence of the luminous efficiency is reproduced by a drift-diffusion model under the condition that quenching of excitons at the PEDOT:PSS anode and metallic cathode is of equal strength. Experimentally, the efficiency roll-off at high voltages due to anode quenching is eliminated by the use of an electron-blocking layer between the anode and the light-emitting polymer.

  12. Surface-Modified Copper Current Collector for Lithium Ion Battery Anode -

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Innovation Portal Copper Current Collector for Lithium Ion Battery Anode Lawrence Berkeley National Laboratory Contact LBL About This Technology Technology Marketing Summary A team of Berkeley Lab researchers led by Gao Liu has developed an innovative approach to improve the adhesion of anode laminate to copper current collectors in lithium ion batteries. This nanotechnology directly addresses delamination of graphite anode material from the collectors, a common result of cyclical

  13. Method to Reduce Camber in Anode-Supported SOFCs - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Vehicles and Fuels Vehicles and Fuels Energy Storage Energy Storage Advanced Materials Advanced Materials Find More Like This Return to Search Method to Reduce Camber in Anode-Supported SOFCs Pacific Northwest National Laboratory Contact PNNL About This Technology A) Typical camber developed in 7 cm x 7 cm anode-supported SOFC. B) Details on matched TEC backing layer opposite electrolyte surface for camber control (Invention 13536). A) Typical camber developed in 7 cm x 7 cm anode-supported

  14. Simulations of Anodic Nanopore Growth Using the Smoothed Boundary and Level

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Set Methods - Joint Center for Energy Storage Research January 11, 2016, Research Highlights Simulations of Anodic Nanopore Growth Using the Smoothed Boundary and Level Set Methods The electric potential in the anodic alumina nanopore at the start of a simulation (left) and after 100 s of simulated time (right), with the surface of the alumina film shown in white. Scientific Achievement A new numerical approach for simulating the growth of nanopores during the anodization (electrochemical

  15. Process and apparatus for recovery of fissionable materials from spent reactor fuel by anodic dissolution

    DOE Patents [OSTI]

    Tomczuk, Zygmunt; Miller, William E.; Wolson, Raymond D.; Gay, Eddie C.

    1991-01-01

    An electrochemical process and apparatus for the recovery of uranium and plutonium from spent metal clad fuel pins is disclosed. The process uses secondary reactions between U.sup.+4 cations and elemental uranium at the anode to increase reaction rates and improve anodic efficiency compared to prior art processes. In another embodiment of the process, secondary reactions between Cd.sup.+2 cations and elemental uranium to form uranium cations and elemental cadmium also assists in oxidizing the uranium at the anode.

  16. Effects of anode materials on resistive characteristics of NiO thin films

    SciTech Connect (OSTI)

    Jia, Ze; Wang, Linkai; Zhang, Naiwen; Ren, Tianling; Liou, Juin J.

    2013-01-28

    This letter shows that the NiO-based structure with different anodes has different resistive switching properties. A conical conductive filament (CF) model is proposed for oxygen vacancies distributed in NiO films. Modeling analysis reveals much larger dissolution velocity of CF near anodes than near cathodes during the reset process. Different interfaces shown in Auger electron spectroscopy can be bound with the model to reveal that CF is dissolved in the structure with Pt or Au as anodes, while CF remains constant if the anode material is Ti or Al, which can explain whether switching properties occur in the specific NiO-based structures.

  17. Self-assembled Ni/TiO{sub 2} nanocomposite anodes synthesized...

    Office of Scientific and Technical Information (OSTI)

    Ni(core)TiOsub 2(shell) nanocomposite anodes were fabricated on three-dimensional, self-assembled nanotemplates of Tobacco mosaic virus using atomic layer deposition, exhibiting ...

  18. Anodization control for barrier-oxide thinning and 3D interconnected...

    Office of Scientific and Technical Information (OSTI)

    Anodization control for barrier-oxide thinning and 3D interconnected pores and direct electrodeposition of nanowire networks on native aluminium substrates Citation Details...

  19. Buried anode lithium thin film battery and process for forming the same

    DOE Patents [OSTI]

    Lee, Se-Hee; Tracy, C. Edwin; Liu, Ping

    2004-10-19

    A reverse configuration, lithium thin film battery (300) having a buried lithium anode layer (305) and process for making the same. The present invention is formed from a precursor composite structure (200) made by depositing electrolyte layer (204) onto substrate (201), followed by sequential depositions of cathode layer (203) and current collector (202) on the electrolyte layer. The precursor is subjected to an activation step, wherein a buried lithium anode layer (305) is formed via electroplating a lithium anode layer at the interface of substrate (201) and electrolyte film (204). The electroplating is accomplished by applying a current between anode current collector (201) and cathode current collector (202).

  20. Material and Energy Flows in the Production of Cathode and Anode...

    Office of Scientific and Technical Information (OSTI)

    and Energy Flows in the Production of Cathode and Anode Materials for Lithium Ion Batteries Citation Details In-Document Search Title: Material and Energy Flows in the ...

  1. Using SiO Anodes for High Capacity, High Rate Electrodes for...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Using SiO Anodes for High Capacity, High Rate Electrodes for Lithium Ion Batteries ... areal capacities and good capacity retention for application in lithium ion batteries. ...

  2. FORT UNION DEEP

    SciTech Connect (OSTI)

    Lyle A. Johnson Jr.

    2002-03-01

    Coalbed methane (CBM) is currently the hottest area of energy development in the Rocky Mountain area. The Powder River Basin (PRB) is the largest CBM area in Wyoming and has attracted the majority of the attention because of its high permeability and relatively shallow depth. Other Wyoming coal regions are also being targeted for development, but most of these areas have lower permeability and deeper coal seams. This project consists of the development of a CBM stimulation system for deep coal resources and involves three work areas: (1) Well Placement, (2) Well Stimulation, and (3) Production Monitoring and Evaluation. The focus of this project is the Washakie Basin. Timberline Energy, Inc., the cosponsor, has a project area in southern Carbon County, Wyoming, and northern Moffat County, Colorado. The target coal is found near the top of the lower Fort Union formation. The well for this project, Evans No.1, was drilled to a depth of 2,700 ft. Three coal seams were encountered with sandstone and some interbedded shale between seams. Well logs indicated that the coal seams and the sandstone contained gas. For the testing, the upper seam at 2,000 ft was selected. The well, drilled and completed for this project, produced very little water and only occasional burps of methane. To enhance the well, a mild severity fracture was conducted to fracture the coal seam and not the adjacent sandstone. Fracturing data indicated a fracture half-length of 34 ft, a coal permeability of 0.2226 md, and permeability of 15.3 md. Following fracturing, the gas production rate stabilized at 10 Mscf/day within water production of 18 bpd. The Western Research Institute (WRI) CBM model was used to design a 14-day stimulation cycle followed by a 30-day production period. A maximum injection pressure of 1,200 psig to remain well below the fracture pressure was selected. Model predictions were 20 Mscf/day of air injection for 14 days, a one-day shut-in, then flowback. The predicted flowback

  3. FORT UNION DEEP

    SciTech Connect (OSTI)

    Lyle A. Johnson Jr.

    2002-09-01

    Coalbed methane (CBM) is currently the hottest area of energy development in the Rocky Mountain area. The Powder River Basin (PRB) is the largest CBM area in Wyoming and has attracted the majority of the attention because of its high permeability and relatively shallow depth. Other Wyoming coal regions are also being targeted for development, but most of these areas have lower permeability and deeper coal seams. This project consists of the development of a CBM stimulation system for deep coal resources and involves three work areas: (1) Well Placement, (2) Well Stimulation, and (3) Production Monitoring and Evaluation. The focus of this project is the Washakie Basin. Timberline Energy, Inc., the cosponsor, has a project area in southern Carbon County, Wyoming, and northern Moffat County, Colorado. The target coal is found near the top of the lower Fort Union formation. The well for this project, Evans No.1, was drilled to a depth of 2,700 ft. Three coal seams were encountered with sandstone and some interbedded shale between seams. Well logs indicated that the coal seams and the sandstone contained gas. For the testing, the upper seam at 2,000 ft was selected. The well, drilled and completed for this project, produced very little water and only occasional burps of methane. To enhance the well, a mild severity fracture was conducted to fracture the coal seam and not the adjacent sandstone. Fracturing data indicated a fracture half-length of 34 ft, a coal permeability of 0.2226 md, and permeability of 15.3 md. Following fracturing, the gas production rate stabilized at 10 Mscf/day within water production of 18 bpd. The Western Research Institute (WRI) CBM model was used to design a 14-day stimulation cycle followed by a 30-day production period. A maximum injection pressure of 1,200 psig to remain well below the fracture pressure was selected. Model predictions were 20 Mscf/day of air injection for 14 days, a one-day shut-in, then flowback. The predicted flowback

  4. Grounded Renewable Energy | Open Energy Information

    Open Energy Info (EERE)

    Grounded Renewable Energy Jump to: navigation, search Name: Grounded Renewable Energy Place: Carbondale, Colorado Zip: 81623 Sector: Renewable Energy, Solar Product: Grounded...

  5. Category:Ground Magnetics | Open Energy Information

    Open Energy Info (EERE)

    Ground Magnetics Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Geothermalpower.jpg Looking for the Ground Magnetics page? For detailed information on Ground...

  6. Structural transformation of nickel hydroxide films during anodic oxidation

    SciTech Connect (OSTI)

    Crocker, R.W.; Muller, R.H.

    1992-05-01

    The transformation of anodically formed nickel hydroxide/oxy-hydroxide electrodes has been investigated. A mechanism is proposed for the anodic oxidation reaction, in which the reaction interface between the reduced and oxidized phases of the electrode evolves in a nodular topography that leads to inefficient utilization of the active electrode material. In the proposed nodular transformation model for the anodic oxidation reaction, nickel hydroxide is oxidized to nickel oxy-hydroxide in the region near the metal substrate. Since the nickel oxy-hydroxide is considerably more conductive than the surrounding nickel hydroxide, as further oxidation occurs, nodular features grow rapidly to the film/electrolyte interface. Upon emerging at the electrolyte interface, the reaction boundary between the nickel hydroxide and oxy-hydroxide phases spreads laterally across the film/electrolyte interface, creating an overlayer of nickel oxy-hydroxide and trapping uncharged regions of nickel hydroxide within the film. The nickel oxy-hydroxide overlayer surface facilitates the oxygen evolution side reaction. Scanning tunneling microscopy of the electrode in its charged state revealed evidence of 80 {endash} 100 Angstrom nickel oxy-hydroxide nodules in the nickel hydroxide film. In situ spectroscopic ellipsometer measurements of films held at various constant potentials agree quantitatively with optical models appropriate to the nodular growth and subsequent overgrowth of the nickel oxy-hydroxide phase. A two-dimensional, numerical finite difference model was developed to simulate the current distribution along the phase boundary between the charged and uncharged material. The model was used to explore the effects of the physical parameters that govern the electrode behavior. The ratio of the conductivities of the nickel hydroxide and oxy-hydroxide phases was found to be the dominant parameter in the system.

  7. Ground potential rise monitor

    DOE Patents [OSTI]

    Allen, Zachery W.; Zevenbergen, Gary A.

    2012-04-03

    A device and method for detecting ground potential rise (GPR) comprising positioning a first electrode and a second electrode at a distance from each other into the earth. The voltage of the first electrode and second electrode is attenuated by an attenuation factor creating an attenuated voltage. The true RMS voltage of the attenuated voltage is determined creating an attenuated true RMS voltage. The attenuated true RMS voltage is then multiplied by the attenuation factor creating a calculated true RMS voltage. If the calculated true RMS voltage is greater than a first predetermined voltage threshold, a first alarm is enabled at a local location. If user input is received at a remote location acknowledging the first alarm, a first alarm acknowledgment signal is transmitted. The first alarm acknowledgment signal is then received at which time the first alarm is disabled.

  8. Forming gas treatment of lithium ion battery anode graphite powders

    DOE Patents [OSTI]

    Contescu, Cristian Ion; Gallego, Nidia C; Howe, Jane Y; Meyer, III, Harry M; Payzant, Edward Andrew; Wood, III, David L; Yoon, Sang Young

    2014-09-16

    The invention provides a method of making a battery anode in which a quantity of graphite powder is provided. The temperature of the graphite powder is raised from a starting temperature to a first temperature between 1000 and 2000.degree. C. during a first heating period. The graphite powder is then cooled to a final temperature during a cool down period. The graphite powder is contacted with a forming gas during at least one of the first heating period and the cool down period. The forming gas includes H.sub.2 and an inert gas.

  9. Ni/YSZ Anode Interactions with Impurities in Coal Gas

    SciTech Connect (OSTI)

    Marina, Olga A.; Pederson, Larry R.; Coyle, Christopher A.; Thomsen, Edwin C.; Coffey, Greg W.

    2009-10-16

    Performance of solid oxide fuel cell (SOFC) with nickel/zirconia anodes on synthetic coal gas in the presence of low levels of phosphorus, arsenic, selenium, sulfur, hydrogen chloride, and antimony impurities were evaluated. The presence of phosphorus and arsenic led to the slow and irreversible SOFC degradation due to the formation of secondary phases with nickel, particularly close to the gas inlet. Phosphorus and antimony surface adsorption layers were identified as well. Hydrogen chloride and sulfur interactions with the nickel were limited to the surface adsorption only, whereas selenium exposure also led to the formation of nickel selenide for highly polarized cells.

  10. Advanced Hybrid Batteries with a Magnesium Metal Anode and Spinel

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    LiMn₂O₄ Cathode - Joint Center for Energy Storage Research July 11, 2016, Research Highlights Advanced Hybrid Batteries with a Magnesium Metal Anode and Spinel LiMn₂O₄ Cathode Two Mg-Li dual salt hybrid electrolytes were successfully developed and can enable rechargeable Mg-LiMn2O4 batteries Scientific Achievement Two Mg-Li dual salt hybrid electrolytes were developed with excellent oxidative stability up to around 3.8 V (vs Mg/Mg2+) on a aluminum current collector, enabling the

  11. High capacity anode materials for lithium ion batteries

    DOE Patents [OSTI]

    Lopez, Herman A.; Anguchamy, Yogesh Kumar; Deng, Haixia; Han, Yongbon; Masarapu, Charan; Venkatachalam, Subramanian; Kumar, Suject

    2015-11-19

    High capacity silicon based anode active materials are described for lithium ion batteries. These materials are shown to be effective in combination with high capacity lithium rich cathode active materials. Supplemental lithium is shown to improve the cycling performance and reduce irreversible capacity loss for at least certain silicon based active materials. In particular silicon based active materials can be formed in composites with electrically conductive coatings, such as pyrolytic carbon coatings or metal coatings, and composites can also be formed with other electrically conductive carbon components, such as carbon nanofibers and carbon nanoparticles. Additional alloys with silicon are explored.

  12. Conductive polymeric cable anodes for pipelines with deteriorating coatings

    SciTech Connect (OSTI)

    Gibson, W.F.; Pikas, J.L. )

    1993-03-01

    Deteriorating pipeline coating systems have been a dilemma in the industry for many years. The interaction between coatings and cathodic protection (CP) is based on the type of coating and the amount of deterioration. There are two primary strategies to approach the problem: recoat, which is very expensive and may require taking the line out of service and cause loss of revenue; or install additional conventional CP groundbed systems. This article presents a state-of-the-art groundbed system using close-coupled conductive polymeric cable anodes that eliminate the problems of conventional groundbeds.

  13. Selective niobium anodization process for fabricating Josephson tunnel junctions

    SciTech Connect (OSTI)

    Kroger, H.; Smith, L.N.; Jillie, D.W.

    1981-08-01

    A novel process for fabricating refractory sperconducting tunnel junctions is described, which is useful with both deposited and native oxide barriers. The distinguishing feature of the method is that the entire superconductor-barrier-superconductor sandwich is formed before the patterning of any layer. Isolated Josephson junctions are then formed by anodizing through the upper electrode, while the devices themselves are protected by a photoresist mask. Using this process, Nb-Si:H-Nb junctions have been fabricated, whose product of critical current and subgap resistance exceeds 10 mV and whose critical current density varies by about 50% over a 2-in. diameter wafer.

  14. Overview of SOFC Anode Interactions with Coal Gas Impurities

    SciTech Connect (OSTI)

    Marina, Olga A.; Pederson, Larry R.; Gemmen, Randall; Gerdes, Kirk; Finklea, Harry; Celik, Ismail B.

    2009-08-11

    Efficiencies greater than 50 percent (higher heating value) have been projected for solid oxide fuel cell (SOFC) systems fueled with gasified coal, even with carbon sequestration. Multiple minor and trace components are present in coal that could affect fuel cell performance, however, which vary widely depending on coal origin and type. Minor and trace components have been classified into three groups: elements with low volatility that are likely to remain in the ash, elements that will partition between solid and gas phases, and highly volatile elements that are unlikely to condense. Those in the second group are of most concern. In the following, an overview of the results of SOFC anode interactions with phosphorus, arsenic, selenium, sulfur, antimony, and hydrogen chloride as single contaminants or in combinations is discussed. Tests were performed using both anode- and electrolyte-supported cells in synthetic coal gas. The ultimate purpose of this work is to establish maximum permissible concentrations for impurities in coal gas, to aid in the selection of appropriate coal gas clean-up technologies.

  15. Field test of platinized titanium anodes for hypochlorite cells

    SciTech Connect (OSTI)

    Asaki, T.; Kamegaya, Y.; Takayasu, K.

    1985-08-01

    The demand for chlorine for water and waste treatment is increasing because of the increase of water consumption, a large amount of waste water discharge, and governmental regulations. Transportation and handling of chlorine cylinders and containers are strictly controlled to avoid hazard. As a result, on-site electrolytic production of hypochlorite becomes important for disinfection of drinking water, oxidation of sewage, chlorination of cooling water in process plants, and other uses. There are now a number of publications and patents on hypochlorite cells and the electrodes to be used. A hypochlorite cell must be simple in operation with minimum maintenance for a year or more. The energy consumption is also an important factor. In an electric power station located by the sea, saline water containing some 3% NaCl is fed to the hypochlorite cell and is chlorinated prior to being sent to the heat exchangers in the plant. Because of the low salt concentration, oxygen evolution occurs, and this reduces chlorine current efficiency. Also, sea water contains Mg and Ca ions, which deposit at the cathode, resulting in high cell voltage. Periodic acid cleaning removes the scale, but affects the electrodes, especially the anode coating, and in some cases the electrode activity is not restored. Pretreatment of sea water prior to electrolysis is preferable, but it is expensive and complicated. Therefore, durable anodes having such characteristics as low chlorine overvoltage and high oxygen overvoltage in sea water must be developed to improve the operating performance of hypochlorite cells.

  16. Aerogel and xerogel composites for use as carbon anodes

    DOE Patents [OSTI]

    Cooper, John F.; Tillotson, Thomas M.; Hrubesh, Lawrence W.

    2010-10-12

    A method for forming a reinforced rigid anode monolith and fuel and product of such method. The method includes providing a solution of organic aerogel or xerogel precursors including at least one of a phenolic resin, phenol (hydroxybenzene), resorcinol(1,3-dihydroxybenzene), or catechol(1,2-dihydroxybenzene); at least one aldehyde compound selected from the group consisting of formaldehyde, acetaldehyde, and furfuraldehyde; and an alkali carbonate or phosphoric acid catalyst; adding internal reinforcement materials comprising carbon to said precursor solution to form a precursor mixture; gelling said precursor mixture to form a composite gel; drying said composite gel; and pyrolyzing said composite gel to form a wettable aerogel/carbon composite or a wettable xerogel/carbon composite, wherein said composites comprise chars and said internal reinforcement materials, and wherein said composite is suitable for use as an anode with the chars being fuel capable of being combusted in a molten salt electrochemical fuel cell in the range from 500 C to 800 C to produce electrical energy. Additional methods and systems/compositions are also provided.

  17. Realisation of an anode supported planar SOFC system

    SciTech Connect (OSTI)

    Buchkremer, H.P.; Stoever, D.; Diekmann, U.

    1996-12-31

    Lowering the operating temperature of S0FCs to below 800{degrees}C potentially lowers production costs of a SOFC system because of a less expensive periphery and is able to guarantee sufficient life time of the stack. One way of achieving lower operating temperatures is the development of new high conductive electrolyte materials. The other way, still based on state-of-the-art material, i.e. yttria-stabilized zirconia (YSZ) electrolyte, is the development of a thin film electrolyte concept. In the Forschungszentrum Julich a program was started to produce a supported planar SOFC with an YSZ electrolyte thickness between 10 to 20 put. One of the electrodes, i.e. the anode, was used as support, in order not to increase the number of components in the SOFC. The high electronic conductivity of the anode-cermet allows the use of relatively thick layers without increasing the cell resistance. An additional advantage of the supported planar concept is the possibility to produce single cells larger than 10 x 10 cm x cm, that is with an effective electrode cross area of several hundred cm{sup 2}.

  18. Modeling and Performance of Anode-Supported SOFC

    SciTech Connect (OSTI)

    Chick, Lawrence A.; Stevenson, Jeffry W.; Meinhardt, Kerry D.; Simner, Steven P.; Jaffe, John E.; Williford, Rick E.

    2001-02-28

    A "one-dimensional", steady-state model of an SOFC stack was needed to support the design of balance-of-plant components for a 5 kW mobile SOFC system. This "stack module" was required to predict appropriate stack voltage responses to changes in fuel composition, fuel flow rate, stack temperature and current demand, with response characteristics that were adjustable to changes in stack component materials and dimensions as well as to electrode porosity. The spreadsheet-based stack module was derived from the work by Kim, Virkar et al (see J. Electrochem. Soc. 146(1) 69-78 (1999)), with modifications suggested by Riess and Schoonman, p291 in CRC Handbook of Electrochemistry (1997) CRC Press. The usual overpotential terms account for ohmic resistance of the cell components, losses due to charge transfer at the electrodes, and losses due to diffusion of reactants into and products out of the porous electrodes. Response of the module is compared to published cell and stack data. After fitting adjustable parameters to match particular cell performance characteristics, the module responds reasonably well to changes in temperature and fuel concentration. The module is used to analyze the performance of anode-supported cells that were fabricated at PNNL (see abstract submitted by Stevenson, Meinhardt, Simner, Habeger and Canfield, "Fabrication and Testing of Anode-Supported SOFC").

  19. Ground Magnetics | Open Energy Information

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Technique: Ground Magnetics Details Activities (25) Areas (19) Regions (0) NEPA(1) Exploration...

  20. Deep Vadose Zone Field Activities

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Deep Insights from Thin Layers Deep Insights from Thin Layers March 13, 2014 - 4:08pm Addthis The Linac Coherent Light Source will create 3D images of single molecules using ultrafast pulses of very intense hard X-rays. | Image courtesy of SLAC. The Linac Coherent Light Source will create 3D images of single molecules using ultrafast pulses of very intense hard X-rays. | Image courtesy of SLAC. Charles Rousseaux Charles Rousseaux Senior Communications Specialist (detailee) How does it work? A

  1. A Comparative Study of Anodized Titania Nanotube Architectures in Aqueous and Nonaqueous Solutions

    SciTech Connect (OSTI)

    Sturgeon, Matthew R; Lai, Peng; Hu, Michael Z.

    2011-01-01

    The unique and highly utilized properties of TiO2 nanotubes are a direct result of nanotube architecture. In order to create different engineered architectures, the effects of electrolyte solution, time, and temperature on the anodization of titanium foil were studied along with the resultant anodized titanium oxide (ATO) nanotube architectures encompassing nanotube length, pore diameter, wall thickness, smoothness, and ordered array structure. Titanium foil was anodized in three different electrolyte solutions: one aqueous (consisting of NH4F and (NH4)2SO4)) and two nonaqueous (glycerin or ethylene glycol, both containing NH4F) at varying temperatures and anodization times. Variation in anodization applied voltage, initial current, and effect of F- ion concentration on ATO nanotube architecture were also studied. Anodization in the aqueous electrolyte produced short, rough nanotube arrays, whereas anodization in organic electrolytes produced long, smooth nanotube arrays greater than 10 m in length. Anodization in glycerin at elevated temperatures for several hours presents the possibility of producing freely dispersed individual nanotubes.

  2. Solid state thin film battery having a high temperature lithium alloy anode

    DOE Patents [OSTI]

    Hobson, D.O.

    1998-01-06

    An improved rechargeable thin-film lithium battery involves the provision of a higher melting temperature lithium anode. Lithium is alloyed with a suitable solute element to elevate the melting point of the anode to withstand moderately elevated temperatures. 2 figs.

  3. Ni modified ceramic anodes for direct-methane solid oxide fuel cells

    DOE Patents [OSTI]

    Xiao, Guoliang; Chen, Fanglin

    2016-01-19

    In accordance with certain embodiments of the present disclosure, a method for fabricating a solid oxide fuel cell is described. The method includes synthesizing a composition having a perovskite present therein. The method further includes applying the composition on an electrolyte support to form an anode and applying Ni to the composition on the anode.

  4. Durability Prediction of Solid Oxide Fuel Cell Anode Material under Thermo-Mechanical and Fuel Gas Contaminants Effects

    SciTech Connect (OSTI)

    Iqbal, Gulfam; Guo, Hua; Kang , Bruce S.; Marina, Olga A.

    2011-01-10

    Solid Oxide Fuel Cells (SOFCs) operate under harsh environments, which cause deterioration of anode material properties and service life. In addition to electrochemical performance, structural integrity of the SOFC anode is essential for successful long-term operation. The SOFC anode is subjected to stresses at high temperature, thermal/redox cycles, and fuel gas contaminants effects during long-term operation. These mechanisms can alter the anode microstructure and affect its electrochemical and structural properties. In this research, anode material degradation mechanisms are briefly reviewed and an anode material durability model is developed and implemented in finite element analysis. The model takes into account thermo-mechanical and fuel gas contaminants degradation mechanisms for prediction of long-term structural integrity of the SOFC anode. The proposed model is validated experimentally using a NexTech ProbostatTM SOFC button cell test apparatus integrated with a Sagnac optical setup for simultaneously measuring electrochemical performance and in-situ anode surface deformation.

  5. Solid oxide fuel cell power plant with an anode recycle loop turbocharger

    SciTech Connect (OSTI)

    Saito, Kazuo; Skiba, Tommy; Patel, Kirtikumar H.

    2015-07-14

    An anode exhaust recycle turbocharger (100) has a turbocharger turbine (102) secured in fluid communication with a compressed oxidant stream within an oxidant inlet line (218) downstream from a compressed oxidant supply (104), and the anode exhaust recycle turbocharger (100) also includes a turbocharger compressor (106) mechanically linked to the turbocharger turbine (102) and secured in fluid communication with a flow of anode exhaust passing through an anode exhaust recycle loop (238) of the solid oxide fuel cell power plant (200). All or a portion of compressed oxidant within an oxidant inlet line (218) drives the turbocharger turbine (102) to thereby compress the anode exhaust stream in the recycle loop (238). A high-temperature, automotive-type turbocharger (100) replaces a recycle loop blower-compressor (52).

  6. Anode-cathode power distribution systems and methods of using the same for electrochemical reduction

    SciTech Connect (OSTI)

    Koehl, Eugene R; Barnes, Laurel A; Wiedmeyer, Stanley G; Williamson, Mark A; Willit, James L

    2014-01-28

    Power distribution systems are useable in electrolytic reduction systems and include several cathode and anode assembly electrical contacts that permit flexible modular assembly numbers and placement in standardized connection configurations. Electrical contacts may be arranged at any position where assembly contact is desired. Electrical power may be provided via power cables attached to seating assemblies of the electrical contacts. Cathode and anode assembly electrical contacts may provide electrical power at any desired levels. Pairs of anode and cathode assembly electrical contacts may provide equal and opposite electrical power; different cathode assembly electrical contacts may provide different levels of electrical power to a same or different modular cathode assembly. Electrical systems may be used with an electrolyte container into which the modular cathode and anode assemblies extend and are supported above, with the modular cathode and anode assemblies mechanically and electrically connecting to the respective contacts in power distribution systems.

  7. Anode shroud for off-gas capture and removal from electrolytic oxide reduction system

    DOE Patents [OSTI]

    Bailey, James L.; Barnes, Laurel A.; Wiedmeyer, Stanley G.; Williamson, Mark A.; Willit, James L.

    2014-07-08

    An electrolytic oxide reduction system according to a non-limiting embodiment of the present invention may include a plurality of anode assemblies and an anode shroud for each of the anode assemblies. The anode shroud may be used to dilute, cool, and/or remove off-gas from the electrolytic oxide reduction system. The anode shroud may include a body portion having a tapered upper section that includes an apex. The body portion may have an inner wall that defines an off-gas collection cavity. A chimney structure may extend from the apex of the upper section and be connected to the off-gas collection cavity of the body portion. The chimney structure may include an inner tube within an outer tube. Accordingly, a sweep gas/cooling gas may be supplied down the annular space between the inner and outer tubes, while the off-gas may be removed through an exit path defined by the inner tube.

  8. STIMULATION TECHNOLOGIES FOR DEEP WELL COMPLETIONS

    SciTech Connect (OSTI)

    Stephen Wolhart

    2003-06-01

    The Department of Energy (DOE) is sponsoring a Deep Trek Program targeted at improving the economics of drilling and completing deep gas wells. Under the DOE program, Pinnacle Technologies is conducting a project to evaluate the stimulation of deep wells. The objective of the project is to assess U.S. deep well drilling & stimulation activity, review rock mechanics & fracture growth in deep, high pressure/temperature wells and evaluate stimulation technology in several key deep plays. Phase 1 was recently completed and consisted of assessing deep gas well drilling activity (1995-2007) and an industry survey on deep gas well stimulation practices by region. Of the 29,000 oil, gas and dry holes drilled in 2002, about 300 were drilled in the deep well; 25% were dry, 50% were high temperature/high pressure completions and 25% were simply deep completions. South Texas has about 30% of these wells, Oklahoma 20%, Gulf of Mexico Shelf 15% and the Gulf Coast about 15%. The Rockies represent only 2% of deep drilling. Of the 60 operators who drill deep and HTHP wells, the top 20 drill almost 80% of the wells. Six operators drill half the U.S. deep wells. Deep drilling peaked at 425 wells in 1998 and fell to 250 in 1999. Drilling is expected to rise through 2004 after which drilling should cycle down as overall drilling declines.

  9. Going Deep vs. Going Wide

    Broader source: Energy.gov [DOE]

    Going Deep vs. Going Wide, from the Residential Energy Efficiency Solutions Conference 2012. Provides an overview on the progress of four energy efficiency programs: Clean Energy Works Oregon, Efficiency Maine, Energy Upgrade California Flex Path, and EcoHouse Loan Program.

  10. Process for mitigating corrosion and increasing the conductivity of steel studs in soderberg anodes of aluminum reduction cells

    DOE Patents [OSTI]

    Oden, Laurance L.; White, Jack C.; Ramsey, James A.

    1994-01-01

    A corrosion resistant electrically conductive coating on steel anode studs used in the production of aluminum by electrolysis.

  11. Stimulation Technologies for Deep Well Completions

    SciTech Connect (OSTI)

    Stephen Wolhart

    2005-06-30

    The Department of Energy (DOE) is sponsoring the Deep Trek Program targeted at improving the economics of drilling and completing deep gas wells. Under the DOE program, Pinnacle Technologies conducted a study to evaluate the stimulation of deep wells. The objective of the project was to review U.S. deep well drilling and stimulation activity, review rock mechanics and fracture growth in deep, high-pressure/temperature wells and evaluate stimulation technology in several key deep plays. This report documents results from this project.

  12. Regional analysis of ground and above-ground climate

    SciTech Connect (OSTI)

    Not Available

    1981-12-01

    The regional suitability of underground construction as a climate control technique is discussed with reference to (1) a bioclimatic analysis of long-term weather data for 29 locations in the United States to determine appropriate above ground climate control techniques, (2) a data base of synthesized ground temperatures for the coterminous United States, and (3) monthly dew point ground temperature comparisons for identifying the relative likelihood of condensation from one region to another. It is concluded that the suitability of earth tempering as a practice and of specific earth-sheltered design stereotypes varies geographically; while the subsurface almost always provides a thermal advantage on its own terms when compared to above ground climatic data, it can, nonetheless, compromise the effectiveness of other, regionally more important climate control techniques. Also contained in the report are reviews of above and below ground climate mapping schemes related to human comfort and architectural design, and detailed description of a theoretical model of ground temperature, heat flow, and heat storage in the ground. Strategies of passive climate control are presented in a discussion of the building bioclimatic analysis procedure which has been applied in a computer analysis of 30 years of weather data for each of 29 locations in the United States.

  13. Anode reactive bleed and injector shift control strategy

    DOE Patents [OSTI]

    Cai, Jun [Rochester, NY; Chowdhury, Akbar [Pittsford, NY; Lerner, Seth E [Honeoye Falls, NY; Marley, William S [Rush, NY; Savage, David R [Rochester, NY; Leary, James K [Rochester, NY

    2012-01-03

    A system and method for correcting a large fuel cell voltage spread for a split sub-stack fuel cell system. The system includes a hydrogen source that provides hydrogen to each split sub-stack and bleed valves for bleeding the anode side of the sub-stacks. The system also includes a voltage measuring device for measuring the voltage of each cell in the split sub-stacks. The system provides two levels for correcting a large stack voltage spread problem. The first level includes sending fresh hydrogen to the weak sub-stack well before a normal reactive bleed would occur, and the second level includes sending fresh hydrogen to the weak sub-stack and opening the bleed valve of the other sub-stack when the cell voltage spread is close to stack failure.

  14. Parallel vacuum arc discharge with microhollow array dielectric and anode

    SciTech Connect (OSTI)

    Feng, Jinghua; Zhou, Lin; Fu, Yuecheng; Zhang, Jianhua; Xu, Rongkun; Chen, Faxin; Li, Linbo; Meng, Shijian

    2014-07-15

    An electrode configuration with microhollow array dielectric and anode was developed to obtain parallel vacuum arc discharge. Compared with the conventional electrodes, more than 10 parallel microhollow discharges were ignited for the new configuration, which increased the discharge area significantly and made the cathode eroded more uniformly. The vacuum discharge channel number could be increased effectively by decreasing the distances between holes or increasing the arc current. Experimental results revealed that plasmas ejected from the adjacent hollow and the relatively high arc voltage were two key factors leading to the parallel discharge. The characteristics of plasmas in the microhollow were investigated as well. The spectral line intensity and electron density of plasmas in microhollow increased obviously with the decease of the microhollow diameter.

  15. Lithium ion batteries with titania/graphene anodes

    DOE Patents [OSTI]

    Liu, Jun; Choi, Daiwon; Yang, Zhenguo; Wang, Donghai; Graff, Gordon L; Nie, Zimin; Viswanathan, Vilayanur V; Zhang, Jason; Xu, Wu; Kim, Jin Yong

    2013-05-28

    Lithium ion batteries having an anode comprising at least one graphene layer in electrical communication with titania to form a nanocomposite material, a cathode comprising a lithium olivine structure, and an electrolyte. The graphene layer has a carbon to oxygen ratio of between 15 to 1 and 500 to 1 and a surface area of between 400 and 2630 m.sup.2/g. The nanocomposite material has a specific capacity at least twice that of a titania material without graphene material at a charge/discharge rate greater than about 10 C. The olivine structure of the cathode of the lithium ion battery of the present invention is LiMPO.sub.4 where M is selected from the group consisting of Fe, Mn, Co, Ni and combinations thereof.

  16. Electrochemical Aging of Thermal-Sprayed Zinc Anodes on Concrete

    SciTech Connect (OSTI)

    Holcomb, G.R.; Bullard, S.J.; Covino, B.S. Jr.; Cramer, S.D.; Cryer, C.B.; McGill, G.E.

    1996-10-01

    Thermal-sprayed zinc anodes are used in impressed current cathodic protection systems for some of Oregon's coastal reinforced concrete bridges. Electrochemical aging of zinc anodes results in physical and chemical changes at the zinc-concrete interface. Concrete surfaces heated prior to thermal-spraying had initial adhesion strengths 80 pct higher than unheated surfaces. For electrochemical aging greater than 200 kC/m{sup 2} (5.2 A h/ft{sup 2}), there was no difference in adhesion strengths for zinc on preheated and unheated concrete. Adhesion strengths decreased monotonically after about 400 to 600 kC/m{sup 2} (10.4 to 15.6 A-h/ft{sup 2}) as a result of the reaction zones at the zinc-concrete interface. A zone adjacent to the metallic zinc (and originally part of the zinc coating) was primarily zincite (ZnO), with minor constituents of wulfingite (Zn(OH){sub 2}), simonkolleite (Zn{sub 5}(OH) {sub 8}C{sub l2}{sup .}H{sub 2}O), and hydrated zinc hydroxide sulfates (Zn{sub 4}SO{sub 4}(OH){sub 6}{sup .}xH{sub 2}O). This zone is the locus for cohesive fracture when the zinc coating separates from the concrete during adhesion tests. Zinc ions substitute for calcium in the cement paste adjacent to the coating as the result of secondary mineralization. The initial estimate of the coating service life based on adhesion strength measurements in accelerated impressed current cathodic protection tests is about 27 years.

  17. Deep Borehole Disposal Research: Demonstration Site Selection...

    Office of Environmental Management (EM)

    The deep borehole disposal concept consists of drilling a borehole on the order of 5,000 m deep, emplacing waste canisters in the lower part of the borehole, and sealing the upper ...

  18. Development of metal-coated ceramic anodes for molten carbonate fuel cells

    SciTech Connect (OSTI)

    Khandkar, A.C.; Elangovan, S.; Marianowski, L.G.

    1990-03-01

    This report documents the developmental efforts on metal coating of various ceramic substrates (LiAlO{sub 2}, SrTiO{sub 3}, and LiFeO{sub 2}) and the critical issues associated with fabricating anodes using metal-coated LiAlO{sub 2} substrates. Electroless Ni and Cu coating technology was developed to achieve complete metal coverage on LiAlO{sub 2} powder substrates. Metal coated SrTiO{sub 3} powders were fabricated into anodes by a process identical to that reported in the GE literature. Microstructural examination revealed that the grains of the ceramic had fused together, with the metal having dewetted from the surface of the ceramic. Alternate substrates that might allow for better wetting of the metal on the ceramic such as LiFeO{sub 2} and Li{sub 2}MnO{sub 3} were identified. Cu/Ni-coated (50:50 mol ratio, 50 w/o metal loading) LiFeO{sub 2} anodes were optimized to meet the MCFC anode specifications. Metal-coated gamma-LiAlO{sub 2} substrates were also developed. By using suitable chemical surface modification methods, the gamma-UAlO{sub 2} substrate surface may be modified to allow a stable metal coated anode to be fabricated. Creep testing of the metal coated ceramic anodes were conducted at IGT. It was determined that the predominant creep mechanism is due to particle rearrangement. The anode porosity, and mean pore size had significant effect on the creep of the anode. Lower porosity and pore size consistent with performance criteria are desired to reduce creep. Lower metal loading with uniformity of coverage will result in lower creep behavior of the anode. Of the two substrates evaluated, LiFeO{sub 2} in general exhibited lower creep which was attributed to superior metal adhesion.

  19. Development of metal-coated ceramic anodes for molten carbonate fuel cells. Final report

    SciTech Connect (OSTI)

    Khandkar, A.C.; Elangovan, S.; Marianowski, L.G.

    1990-03-01

    This report documents the developmental efforts on metal coating of various ceramic substrates (LiAlO{sub 2}, SrTiO{sub 3}, and LiFeO{sub 2}) and the critical issues associated with fabricating anodes using metal-coated LiAlO{sub 2} substrates. Electroless Ni and Cu coating technology was developed to achieve complete metal coverage on LiAlO{sub 2} powder substrates. Metal coated SrTiO{sub 3} powders were fabricated into anodes by a process identical to that reported in the GE literature. Microstructural examination revealed that the grains of the ceramic had fused together, with the metal having dewetted from the surface of the ceramic. Alternate substrates that might allow for better wetting of the metal on the ceramic such as LiFeO{sub 2} and Li{sub 2}MnO{sub 3} were identified. Cu/Ni-coated (50:50 mol ratio, 50 w/o metal loading) LiFeO{sub 2} anodes were optimized to meet the MCFC anode specifications. Metal-coated gamma-LiAlO{sub 2} substrates were also developed. By using suitable chemical surface modification methods, the gamma-UAlO{sub 2} substrate surface may be modified to allow a stable metal coated anode to be fabricated. Creep testing of the metal coated ceramic anodes were conducted at IGT. It was determined that the predominant creep mechanism is due to particle rearrangement. The anode porosity, and mean pore size had significant effect on the creep of the anode. Lower porosity and pore size consistent with performance criteria are desired to reduce creep. Lower metal loading with uniformity of coverage will result in lower creep behavior of the anode. Of the two substrates evaluated, LiFeO{sub 2} in general exhibited lower creep which was attributed to superior metal adhesion.

  20. Generic Deep Geologic Disposal Safety Case

    Broader source: Energy.gov [DOE]

    The Generic Deep Geologic Disposal Safety Case presents generic information that is of use in understanding potential deep geologic disposal options (e.g., salt, shale, granite, deep borehole) in the U.S. for used nuclear fuel (UNF) from reactors and high-level radioactive waste (HLW).

  1. Non-consumable anode and lining for aluminum electrolytic reduction cell

    DOE Patents [OSTI]

    Beck, Theodore R.; Brooks, Richard J.

    1994-01-01

    An oxidation resistant, non-consumable anode, for use in the electrolytic reduction of alumina to aluminum, has a composition comprising copper, nickel and iron. The anode is part of an electrolytic reduction cell comprising a vessel having an interior lined with metal which has the same composition as the anode. The electrolyte is preferably composed of a eutectic of AlF.sub.3 and either (a) NaF or (b) primarily NaF with some of the NaF replaced by an equivalent molar amount of KF or KF and LiF.

  2. Effect of the Anion Activity on the Stability of Li Metal Anodes in

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lithium-Sulfur Batteries - Joint Center for Energy Storage Research March 29, 2016, Research Highlights Effect of the Anion Activity on the Stability of Li Metal Anodes in Lithium-Sulfur Batteries The lithium metal anode (bottom) corrodes after just 35 cycles in the LiFSI electrolyte, while the lithium anode (top) stays relatively stable in the LiTFSI electrolyte after more than 200 cycles. Scientific Achievement Discovered why the salt LiTFSI - when added to the electrolyte of a Li-S

  3. Chemically modified thermal-spray zinc anodes for galvanic cathodic protection

    SciTech Connect (OSTI)

    Covino, B.S. Jr.; Bullard, S.J.; Holcomb, G.R.; Russell, J.H.; Cramer, S.D.; Bennett, J.E.; Laylor, H.M.

    1999-12-01

    Humectants, substances that promote the retention of moisture, were applied to new and previously aged thermal-sprayed Zn anodes to improve the performance of galvanic cathodic protection systems. Anodes on steel-reinforced concrete were treated with aqueous solutions of the humectants lithium nitrate (LiNO{sub 3}) and lithium bromide (LiBr). LiBr was the most beneficial humectant, increasing the average galvanic current density of new thermal-sprayed Zn anodes by as much as a factor of six.

  4. Inert anode containing base metal and noble metal useful for the electrolytic production of aluminum

    DOE Patents [OSTI]

    Ray, Siba P.; Liu, Xinghua

    2000-01-01

    An inert anode for production of metals such as aluminum is disclosed. The inert anode comprises a base metal selected from Cu and Ag, and at least one noble metal selected from Ag, Pd, Pt, Au, Rh, Ru, Ir and Os. The inert anode may optionally be formed of sintered particles having interior portions containing more base metal than noble metal and exterior portions containing more noble metal than base metal. In a preferred embodiment, the base metal comprises Cu, and the noble metal comprises Ag, Pd or a combination thereof.

  5. Inverter Ground Fault Overvoltage Testing

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Task Force on Effective Grounding, ITFEG), led by Brian Lydic of Fronius USA, for providing the test plan that served as the basis for the test procedure used in this study. ...

  6. Ground Penetrating Radar, Barrow, Alaska

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    John Peterson

    2015-03-06

    This is 500 MHz Ground Penetrating Radar collected along the AB Line in Intensive Site 1 beginning in October 2012 and collected along L2 in Intensive Site 0 beginning in September 2011. Both continue to the present.

  7. Ground-water in Texas

    SciTech Connect (OSTI)

    Ward-McLemore, E.

    1985-01-01

    Amount 61% of the water used by Texans is ground-water. Some areas, both municipal and rural, depend entirely on ground-water. In many areas long term withdrawal is lowering the water levels, causing surface land subsidence, salt-water encroachment, and reducing future reservoir availability. The increasing probability of seepage from radioactive and toxic wastes, herbicide residues, septic systems, and oilfield brines is threatening dangerous contamination of fresh ground-water reservoirs. The Texas Department of Water Resources, the Texas Department of Health, State and private colleges and universities, the US Geological Survey, the Environmental Protection Agency, various underground water districts, among others, are cooperating with concerned hydrologists in a concentrated program to increase the efficiency of ground-water use and development, preserve the aquifer reservoirs, and decrease the pollution potential. 88 references.

  8. Document Number Q0029500 Ground Water Model 3.0 Ground Water...

    Office of Legacy Management (LM)

    Ground Water Model 3.0 Ground Water Model This section presents a steady-state ground water flow model and a coupled solute transport model (ground water model) for the alluvial ...

  9. Tritium Ground Water Issues | Department of Energy

    Office of Environmental Management (EM)

    Ground Water Issues Tritium Ground Water Issues Presentation from the 35th Tritium Focus Group Meeting held in Princeton, New Jersey on May 05-07, 2015. Tritium Ground Water Issues ...

  10. Vehicle Technologies Office Merit Review 2015: High Energy Anode Material Development for Li-ion Batteries

    Broader source: Energy.gov [DOE]

    Presentation given by Sinode Systems at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about high energy anode material...