National Library of Energy BETA

Sample records for deep anode ground

  1. Anode initiated surface flashover switch

    DOE Patents [OSTI]

    Brainard, John P. (Albuquerque, NM); Koss, Robert J. (Albuquerque, NM)

    2003-04-29

    A high voltage surface flashover switch has a pair of electrodes spaced by an insulator. A high voltage is applied to an anode, which is smaller than the opposing, grounded, cathode. When a controllable source of electrons near the cathode is energized, the electrons are attracted to the anode where they reflect to the insulator and initiate anode to cathode breakdown.

  2. Carbonate fuel cell anodes

    DOE Patents [OSTI]

    Donado, Rafael A. (Chicago, IL); Hrdina, Kenneth E. (Glenview, IL); Remick, Robert J. (Bolingbrook, IL)

    1993-01-01

    A molten alkali metal carbonates fuel cell porous anode of lithium ferrite and a metal or metal alloy of nickel, cobalt, nickel/iron, cobalt/iron, nickel/iron/aluminum, cobalt/iron/aluminum and mixtures thereof wherein the total iron content including ferrite and iron of the composite is about 25 to about 80 percent, based upon the total anode, provided aluminum when present is less than about 5 weight percent of the anode. A process for production of the lithium ferrite containing anode by slipcasting.

  3. Carbonate fuel cell anodes

    DOE Patents [OSTI]

    Donado, R.A.; Hrdina, K.E.; Remick, R.J.

    1993-04-27

    A molten alkali metal carbonates fuel cell porous anode of lithium ferrite and a metal or metal alloy of nickel, cobalt, nickel/iron, cobalt/iron, nickel/iron/aluminum, cobalt/iron/aluminum and mixtures thereof wherein the total iron content including ferrite and iron of the composite is about 25 to about 80 percent, based upon the total anode, provided aluminum when present is less than about 5 weight percent of the anode. A process is described for production of the lithium ferrite containing anode by slipcasting.

  4. Results from a pilot cell test of cermet anodes

    SciTech Connect (OSTI)

    Windisch, Jr, C F; Strachan, D M; Henager, Jr, C H; Greenwell, E N; Alcorn, T R

    1992-08-01

    Goal was to develop long-lasting, energy-efficient anodes for Hall-Heroult cells used to produce Al metal. The anodes were made from a ceramic/metal composite consisting of NiO and NiFe{sub 2}O{sub 4} and a Cu/Ni metal phase. Thirteen cermet anodes were tested at Reynolds Metals Co., Muscle Shoals, AL. All anodes corroded severely during the pilot test. Electrolyte components were found deep within the anodes. However, there were many deficiencies in the pilot cell test, mainly the failure to maintain optimal operating conditions. It is concluded that there is a variety of fabrication and operational considerations that need to be addressed carefully in any future testing. 118 figs, 16 tabs, 17 refs.(DLC)

  5. Anodes for alkaline electrolysis

    DOE Patents [OSTI]

    Soloveichik, Grigorii Lev (Latham, NY)

    2011-02-01

    A method of making an anode for alkaline electrolysis cells includes adsorption of precursor material on a carbonaceous material, conversion of the precursor material to hydroxide form and conversion of precursor material from hydroxide form to oxy-hydroxide form within the alkaline electrolysis cell.

  6. Movable anode x-ray source with enhanced anode cooling

    DOE Patents [OSTI]

    Bird, C.R.; Rockett, P.D.

    1987-08-04

    An x-ray source is disclosed having a cathode and a disc-shaped anode with a peripheral surface at constant radius from the anode axis opposed to the cathode. The anode has stub axle sections rotatably carried in heat conducting bearing plates which are mounted by thermoelectric coolers to bellows which normally bias the bearing plates to a retracted position spaced from opposing anode side faces. The bellows cooperate with the x-ray source mounting structure for forming closed passages for heat transport fluid. Flow of such fluid under pressure expands the bellows and brings the bearing plates into heat conducting contact with the anode side faces. A worm gear is mounted on a shaft and engages serrations in the anode periphery for rotating the anode when flow of coolant is terminated between x-ray emission events. 5 figs.

  7. Movable anode x-ray source with enhanced anode cooling

    DOE Patents [OSTI]

    Bird, Charles R. (Ypsilanti, MI); Rockett, Paul D. (Ann Arbor, MI)

    1987-01-01

    An x-ray source having a cathode and a disc-shaped anode with a peripheral surface at constant radius from the anode axis opposed to the cathode. The anode has stub axle sections rotatably carried in heat conducting bearing plates which are mounted by thermoelectric coolers to bellows which normally bias the bearing plates to a retracted position spaced from opposing anode side faces. The bellows cooperate with the x-ray source mounting structure for forming closed passages for heat transport fluid. Flow of such fluid under pressure expands the bellows and brings the bearing plates into heat conducting contact with the anode side faces. A worm gear is mounted on a shaft and engages serrations in the anode periphery for rotating the anode when flow of coolant is terminated between x-ray emission events.

  8. Nickel anode electrode

    DOE Patents [OSTI]

    Singh, Prabhakar (Bethel, CT); Benedict, Mark (Monroe, CT)

    1987-01-01

    A nickel anode electrode fabricated by oxidizing a nickel alloying material to produce a material whose exterior contains nickel oxide and whose interior contains nickel metal throughout which is dispersed the oxide of the alloying material and by reducing and sintering the oxidized material to form a product having a nickel metal exterior and an interior containing nickel metal throughout which is dispersed the oxide of the alloying material.

  9. Thin film buried anode battery

    DOE Patents [OSTI]

    Lee, Se-Hee (Lakewood, CO); Tracy, C. Edwin (Golden, CO); Liu, Ping (Denver, CO)

    2009-12-15

    A reverse configuration, lithium thin film battery (300) having a buried lithium anode layer (305) and process for making the same. The present invention is formed from a precursor composite structure (200) made by depositing electrolyte layer (204) onto substrate (201), followed by sequential depositions of cathode layer (203) and current collector (202) on the electrolyte layer. The precursor is subjected to an activation step, wherein a buried lithium anode layer (305) is formed via electroplating a lithium anode layer at the interface of substrate (201) and electrolyte film (204). The electroplating is accomplished by applying a current between anode current collector (201) and cathode current collector (202).

  10. Intermetallic Anodes | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    10 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon es062_thackeray_2010_p.pdf More Documents & Publications Intermetallic Anodes High Capacity Composite Carbon Anodes Fabricated by Autogenic Reactions High Capacity Composite Carbon

  11. Intermetallic Anodes | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    09 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon es_31_thackeray.pdf More Documents & Publications Intermetallic Anodes Develop Improved Methods of Making Intermetallic Anodes Improved Methods for Making Intermetallic

  12. Anode film formation and control

    DOE Patents [OSTI]

    Koski, O.; Marschman, S.C.

    1990-05-01

    A protective film is created about the anode within a cryolite-based electrolyte during electrolytic production of aluminum from alumina. The film functions to minimize corrosion of the anode by the cryolitic electrolyte and thereby extend the life of the anode. Various operating parameters of the electrolytic process are controlled to maintain the protective film about the anode in a protective state throughout the electrolytic reduction of alumina. Such parameters include electrolyte temperature, electrolyte ratio, current density, and Al[sub 2]O[sub 3] concentration. An apparatus is also disclosed to enable identification of the onset of anode corrosion due to disruption of the film to provide real time information regarding the state of the film. 3 figs.

  13. Anode film formation and control

    DOE Patents [OSTI]

    Koski, Oscar (Richland, WA); Marschman, Steven C. (Richland, WA)

    1990-01-01

    A protective film is created about the anode within a cryolite-based electrolyte during electrolytic production of aluminum from alumina. The film function to minimize corrosion of the anode by the cryolitic electrolyte and thereby extend the life of the anode. Various operating parameters of the electrolytic process are controlled to maintain the protective film about the anode in a protective state throughout the electrolytic reduction of alumina. Such parameters include electrolyte temperature, electrolyte ratio, current density, and Al.sub.2 O.sub.3 concentration. An apparatus is also disclosed to enable identification of the onset of anode corrosion due to disruption of the film to provide real time information regarding the state of the film.

  14. Silicon-Graphene Anodes | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Silicon-Graphene Anodes Technology available for licensing: Provides low-cost production process. Advanced gas phase deposition process yields anodes with five times the specific...

  15. Multi-anode ionization chamber

    DOE Patents [OSTI]

    Bolotnikov, Aleksey E. (South Setauket, NY); Smith, Graham (Port Jefferson, NY); Mahler, George J. (Rocky Point, NY); Vanier, Peter E. (Setauket, NY)

    2010-12-28

    The present invention includes a high-energy detector having a cathode chamber, a support member, and anode segments. The cathode chamber extends along a longitudinal axis. The support member is fixed within the cathode chamber and extends from the first end of the cathode chamber to the second end of the cathode chamber. The anode segments are supported by the support member and are spaced along the longitudinal surface of the support member. The anode segments are configured to generate at least a first electrical signal in response to electrons impinging thereon.

  16. Nanostructured Metal Oxide Anodes | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    10 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon es064_dillon_2010_p.pdf More Documents & Publications Atomic Layer Deposition for Stabilization of Amorphous Silicon Anodes Nanostructured Metal Oxide Anodes Novel Lithium Ion Anode Structures: Overview of New DOE BATT Anode Projects

  17. Nanostructured Metal Oxide Anodes (Presentation)

    SciTech Connect (OSTI)

    Dillon, A. C.; Riley, L. A.; Lee, S.-H.; Kim, Y.-H.; Ban, C.; Gillaspie, D. T.; Pesaran, A.

    2009-05-01

    This summarizes NREL's FY09 battery materials research activity in developing metal oxide nanostructured anodes to enable high-energy, durable and affordable li-ion batteries for HEVs and PHEVs.

  18. Nano structural anodes for radiation detectors

    DOE Patents [OSTI]

    Cordaro, Joseph V.; Serkiz, Steven M.; McWhorter, Christopher S.; Sexton, Lindsay T.; Retterer, Scott T.

    2015-07-07

    Anodes for proportional radiation counters and a process of making the anodes is provided. The nano-sized anodes when present within an anode array provide: significantly higher detection efficiencies due to the inherently higher electric field, are amenable to miniaturization, have low power requirements, and exhibit a small electromagnetic field signal. The nano-sized anodes with the incorporation of neutron absorbing elements (e.g., .sup.10B) allow the use of neutron detectors that do not use .sup.3He.

  19. Jeff Grounds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Jeff Grounds Jeff Grounds jeffgrounds-sm.jpg Jeff Grounds Facilities Manager JTGrounds@lbl.gov Phone: (510) 486-7197 Mobile: (510) 207-2273 Last edited: 2016-02-01 08:07:03

  20. Novel Lithium Ion Anode Structures: Overview of New DOE BATT...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Lithium Ion Anode Structures: Overview of New DOE BATT Anode Projects Novel Lithium Ion Anode Structures: Overview of New DOE BATT Anode Projects 2011 DOE Hydrogen and Fuel Cells...

  1. Patent: Methods for making anodes for lithium ion batteries | DOEpatents

    Office of Scientific and Technical Information (OSTI)

    Methods for making anodes for lithium ion batteries Citation Details Title: Methods for making anodes for lithium ion batteries

  2. Nanotube Composite Anode Materials | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nanotube Composite Anode Materials Technology available for licensng: A composite material suitable for use in an anode for a lithium-ion battery Reduces manufacturing costs. Provides increase capacity, safety, long-term stability and reliability. Potential to exceed technical specifications for electric vehicles. PDF icon nanotube-composite_anode_materials

  3. Deep Lysimeter

    DOE Patents [OSTI]

    Hubbell, Joel M. (Idaho Falls, ID); Sisson, James B. (Idaho Falls, ID)

    2004-06-01

    A deep lysimeter including a hollow vessel having a chamber, a fill conduit extending into the chamber through apertures, a semi-permeable member mounted on the vessel and in fluid communication with the fill conduit, and a line connection for retrieving the lysimeter.

  4. Microbial fuel cell with improved anode

    DOE Patents [OSTI]

    Borole, Abhijeet P.

    2010-04-13

    The present invention relates to a method for preparing a microbial fuel cell, wherein the method includes: (i) inoculating an anodic liquid medium in contact with an anode of the microbial fuel cell with one or more types of microorganisms capable of functioning by an exoelectrogenic mechanism; (ii) establishing a biofilm of the microorganisms on and/or within the anode along with a substantial absence of planktonic forms of the microorganisms by substantial removal of the planktonic microorganisms during forced flow and recirculation conditions of the anodic liquid medium; and (iii) subjecting the microorganisms of the biofilm to a growth stage by incorporating one or more carbon-containing nutritive compounds in the anodic liquid medium during biofilm formation or after biofilm formation on the anode has been established.

  5. Developing High Capacity, Long Life Anodes | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Life Anodes Developing High Capacity, Long Life Anodes 2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon es020_amine_2011_p.pdf More Documents & Publications Developing A New High Capacity Anode With Long Cycle Life Developing High Capacity, Long Life Anodes Development of High Capacity Anode for Li-ion Batteries

  6. Spherical Carbon Anodes Fabricated by Autogenic Reactions | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Spherical Carbon Anodes Fabricated by Autogenic Reactions Spherical Carbon Anodes Fabricated by Autogenic Reactions 2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon es114_thackeray_2011_p.pdf More Documents & Publications High Capacity Composite Carbon Anodes High Capacity Composite Carbon Anodes Fabricated by Autogenic Reactions Intermetallic Anodes

  7. Anode Sheath Switching in a Carbon Nanotube Arc Plasma

    SciTech Connect (OSTI)

    Abe Fetterman, Yevgeny Raitses, and Michael Keidar

    2008-04-08

    The anode ablation rate is investigated as a function of anode diameter for a carbon nanotube arc plasma. It is found that anomalously high ablation occurs for small anode diameters. This result is explained by the formation of a positive anode sheath. The increased ablation rate due to this positive anode sheath could imply greater production rate for carbon nanotubes.

  8. Surface modifications for carbon lithium intercalation anodes

    DOE Patents [OSTI]

    Tran, Tri D. (Livermore, CA); Kinoshita, Kimio (Cupertino, CA)

    2000-01-01

    A prefabricated carbon anode containing predetermined amounts of passivating film components is assembled into a lithium-ion rechargeable battery. The modified carbon anode enhances the reduction of the irreversible capacity loss during the first discharge of a cathode-loaded cell. The passivating film components, such as Li.sub.2 O and Li.sub.2 CO.sub.3, of a predetermined amount effective for optimal passivation of carbon, are incorporated into carbon anode materials to produce dry anodes that are essentially free of battery electrolyte prior to battery assembly.

  9. Remote control for anode-cathode adjustment

    DOE Patents [OSTI]

    Roose, Lars D. (Albuquerque, NM)

    1991-01-01

    An apparatus for remotely adjusting the anode-cathode gap in a pulse power machine has an electric motor located within a hollow cathode inside the vacuum chamber of the pulse power machine. Input information for controlling the motor for adjusting the anode-cathode gap is fed into the apparatus using optical waveguides. The motor, controlled by the input information, drives a worm gear that moves a cathode tip. When the motor drives in one rotational direction, the cathode is moved toward the anode and the size of the anode-cathode gap is diminished. When the motor drives in the other direction, the cathode is moved away from the anode and the size of the anode-cathode gap is increased. The motor is powered by batteries housed in the hollow cathode. The batteries may be rechargeable, and they may be recharged by a photovoltaic cell in combination with an optical waveguide that receives recharging energy from outside the hollow cathode. Alternatively, the anode-cathode gap can be remotely adjusted by a manually-turned handle connected to mechanical linkage which is connected to a jack assembly. The jack assembly converts rotational motion of the handle and mechanical linkage to linear motion of the cathode moving toward or away from the anode.

  10. A new low-voltage plateau of Na₃V₂(PO₄)₃ as an anode for Na-ion batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jian, Zelang; Sun, Yang; Ji, Xiulei

    2015-04-04

    A low-voltage plateau at ~0.3 V is discovered during the deep sodiation of Na₃V₂(PO₄)₃ by combined computational and experimental studies. This new low-voltage plateau doubles the sodiation capacity of Na₃V₂(PO₄)₃, turning it into a promising anode for Na-ion batteries.

  11. Preparation of lithium-ion battery anodes using lignin (Journal...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Preparation of lithium-ion battery anodes using lignin Citation Details In-Document Search Title: Preparation of lithium-ion battery anodes using lignin Authors:...

  12. Novel Approach to Advanced Direct Methanol Fuel Cell Anode Catalysts...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Approach to Advanced Direct Methanol Fuel Cell Anode Catalysts Novel Approach to Advanced Direct Methanol Fuel Cell Anode Catalysts Presented at the Department of Energy Fuel Cell...

  13. Low cost fuel cell diffusion layer configured for optimized anode...

    Office of Scientific and Technical Information (OSTI)

    for optimized anode water management Citation Details In-Document Search Title: Low cost fuel cell diffusion layer configured for optimized anode water management A fuel cell ...

  14. Vehicle Technologies Office Merit Review 2014: Novel Anode Materials...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Materials Vehicle Technologies Office Merit Review 2015: First Principles Modeling of SEI Formation on Bare and SurfaceAdditive Modified Silicon Anodes Novel Anode Materials

  15. The Nitrogen-Nitride Anode.

    SciTech Connect (OSTI)

    Delnick, Frank M.

    2014-10-01

    Nitrogen gas N 2 can be reduced to nitride N -3 in molten LiCl-KCl eutectic salt electrolyte. However, the direct oxidation of N -3 back to N 2 is kinetically slow and only occurs at high overvoltage. The overvoltage for N -3 oxidation can be eliminated by coordinating the N -3 with BN to form the dinitridoborate (BN 2 -3 ) anion which forms a 1-D conjugated linear inorganic polymer with -Li-N-B-N- repeating units. This polymer precipitates out of solution as Li 3 BN 2 which becomes a metallic conductor upon delithiation. Li 3 BN 2 is oxidized to Li + + N 2 + BN at about the N 2 /N -3 redox potential with very little overvoltage. In this report we evaluate the N 2 /N -3 redox couple as a battery anode for energy storage.

  16. High Capacity Composite Carbon Anodes | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Capacity Composite Carbon Anodes High Capacity Composite Carbon Anodes 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon es114_pol_2012_o.pdf More Documents & Publications High Capacity Composite Carbon Anodes Fabricated by Autogenic Reactions Spherical Carbon Anodes Fabricated by Autogenic Reactions Vehicle Technologies Office Merit Review 2014: Metal-Based High Capacity Li-Ion Anodes

  17. New High-Energy Nanofiber Anode Materials

    SciTech Connect (OSTI)

    Zhang, Xiangwu; Fedkiw, Peter; Khan, Saad; Huang, Alex; Fan, Jiang

    2013-11-15

    The overall goal of the proposed work was to use electrospinning technology to integrate dissimilar materials (lithium alloy and carbon) into novel composite nanofiber anodes, which simultaneously had high energy density, reduced cost, and improved abuse tolerance. The nanofiber structure allowed the anodes to withstand repeated cycles of expansion and contraction. These composite nanofibers were electrospun into nonwoven fabrics with thickness of 50 ?m or more, and then directly used as anodes in a lithium-ion battery. This eliminated the presence of non-active materials (e.g., conducting carbon black and polymer binder) and resulted in high energy and power densities. The nonwoven anode structure also provided a large electrode-electrolyte interface and, hence, high rate capacity and good lowtemperature performance capability. Following are detailed objectives for three proposed project periods. During the first six months: Obtain anodes capable of initial specific capacities of 650 mAh/g and achieve ~50 full charge/discharge cycles in small laboratory scale cells (50 to 100 mAh) at the 1C rate with less than 20 percent capacity fade; In the middle of project period: Assemble, cycle, and evaluate 18650 cells using proposed anode materials, and demonstrate practical and useful cycle life (750 cycles of ~70% state of charge swing with less than 20% capacity fade) in 18650 cells with at least twice improvement in the specific capacity than that of conventional graphite electrodes; At the end of project period: Deliver 18650 cells containing proposed anode materials, and achieve specific capacities greater than 1200 mAh/g and cycle life longer than 5000 cycles of ~70% state of charge swing with less than 20% capacity fade.

  18. Chemical enhancement of metallized zinc anode performance

    SciTech Connect (OSTI)

    Bennett, J.

    1998-12-31

    Galvanic current delivered to reinforced concrete by a metallized zinc anode was studied relative to the humidity of its environment and periodic direct wetting. Current decreased quickly at low humidity to values unlikely to meet accepted cathodic protection criteria, but could be easily restored by direct wetting of the anode. Thirteen chemicals were screened for their ability to enhance galvanic current. Such chemicals, when applied to the exterior surface of the anode, are easily transported by capillary action to the anode-concrete interface where they serve to maintain the interface conductive and the zinc electrochemically active. The most effective chemicals were potassium and lithium bromide, acetate, chloride and nitrate, which increased galvanic current by a factor of 2--15, depending on relative humidity and chloride contamination of the concrete. This new technique is expected to greatly expand the number of concrete structures which can be protected by simple galvanic cathodic protection, The use of lithium-based chemicals together with metallized zinc anode is also proposed for mitigation of existing problems due to ASR. In this case, lithium which prevents or inhibits expansion due to ASR can be readily injected into the concrete. A new process, electrochemical maintenance of concrete (EMC), is also proposed to benefit reinforced concrete structures suffering from chloride-induced corrosion.

  19. Electrolytic Cell For Production Of Aluminum Employing Planar Anodes.

    DOE Patents [OSTI]

    Barnett, Robert J. (Goldendale, WA); Mezner, Michael B. (Sandy, OR); Bradford, Donald R (Underwood, WA)

    2004-10-05

    A method of producing aluminum in an electrolytic cell containing alumina dissolved in an electrolyte, the method comprising providing a molten salt electrolyte having alumina dissolved therein in an electrolytic cell. A plurality of anodes and cathodes having planar surfaces are disposed in a generally vertical orientation in the electrolyte, the anodes and cathodes arranged in alternating or interleaving relationship to provide anode planar surfaces disposed opposite cathode planar surfaces, the anode comprised of carbon. Electric current is passed through anodes and through the electrolyte to the cathodes depositing aluminum at the cathodes and forming carbon containing gas at the anodes.

  20. Nanocomposite protective coatings for battery anodes

    DOE Patents [OSTI]

    Lemmon, John P; Xiao, Jie; Liu, Jun

    2014-01-21

    Modified surfaces on metal anodes for batteries can help resist formation of malfunction-inducing surface defects. The modification can include application of a protective nanocomposite coating that can inhibit formation of surface defects. such as dendrites, on the anode during charge/discharge cycles. For example, for anodes having a metal (M'), the protective coating can be characterized by products of chemical or electrochemical dissociation of a nanocomposite containing a polymer and an exfoliated compound (M.sub.a'M.sub.b''X.sub.c). The metal, M', comprises Li, Na, or Zn. The exfoliated compound comprises M' among lamella of M.sub.b''X.sub.c, wherein M'' is Fe, Mo, Ta, W, or V, and X is S, O, or Se.

  1. A new low-voltage plateau of Na3V2(PO4)(3) as an anode for Na-ion batteries

    SciTech Connect (OSTI)

    Jian, ZL; Sun, Y; Ji, XL

    2015-01-01

    A low-voltage plateau at similar to 0.3 V is discovered for the deep sodiation of Na3V2(PO4)(3) by combined computational and experimental studies. This new low-voltage plateau doubles the sodiation capacity of Na3V2(PO4)(3), thus turning it into a promising anode for Na-ion batteries.

  2. A Better Anode Design to Improve Lithium-Ion Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Better Anode Design to Improve Lithium-Ion Batteries A Better Anode Design to Improve ... 8.0.1 show a lower "lowest unoccupied molecular orbital" for the new Berkeley Lab ...

  3. Fuel cell system shutdown with anode pressure control

    DOE Patents [OSTI]

    Clingerman, Bruce J. (Palmyra, NY); Doan, Tien M. (Columbia, MD); Keskula, Donald H. (Webster, NY)

    2002-01-01

    A venting methodology and pressure sensing and vent valving arrangement for monitoring anode bypass valve operating during the normal shutdown of a fuel cell apparatus of the type used in vehicle propulsion systems. During a normal shutdown routine, the pressure differential between the anode inlet and anode outlet is monitored in real time in a period corresponding to the normal closing speed of the anode bypass valve and the pressure differential at the end of the closing cycle of the anode bypass valve is compared to the pressure differential at the beginning of the closing cycle. If the difference in pressure differential at the beginning and end of the anode bypass closing cycle indicates that the anode bypass valve has not properly closed, a system controller switches from a normal shutdown mode to a rapid shutdown mode in which the anode inlet is instantaneously vented by rapid vents.

  4. ITP Aluminum: Inert Anodes Roadmap | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Inert Anodes Roadmap ITP Aluminum: Inert Anodes Roadmap PDF icon inertroad.pdf More Documents & Publications U.S. Energy Requirements for Aluminum Production Ultrahigh-Efficiency Aluminum Production Cells

  5. High Rate and Stable Cycling of Lithium Metal Anode (Journal...

    Office of Scientific and Technical Information (OSTI)

    High Rate and Stable Cycling of Lithium Metal Anode Citation Details In-Document Search Title: High Rate and Stable Cycling of Lithium Metal Anode Lithium (Li) metal is an ideal ...

  6. Self-cleaning rotating anode X-ray source

    DOE Patents [OSTI]

    Paulikas, Arvydas P.

    1989-01-01

    A self-cleaning rotating anode x-ray source comprising an evacuable housing, a rotatable cylindrical anode within the housing, a source of electrons within the housing which electrons are caused to impinge upon the anode to produce x-rays, and means for ionizing residual particles within the housing and accelerating such ions so as to impinge upon the anode to sputter impurities from the surface thereof.

  7. Self-cleaning rotating anode x-ray source

    DOE Patents [OSTI]

    Paulikas, A.P.

    1987-06-02

    A self-cleaning rotating anode x-ray source comprising and evacuable housing, a rotatable cylindrical anode within the housing, a source of electrons within the housing which electrons are caused to impinge upon the anode to produce x-rays, and means for ionizing residual particles within the housing and accelerating such ions so as to impinge upon the anode to sputter impurities from the surface thereof. 2 figs.

  8. Improved Methods for Making Intermetallic Anodes | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Methods for Making Intermetallic Anodes Improved Methods for Making Intermetallic Anodes 2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon es022_jansen_2010_o.pdf More Documents & Publications Develop Improved Methods of Making Intermetallic Anodes Develop Improved Methods for Making Intermetallic Anodes FY 2011 Annual Progress Report for Energy Storage R&D

  9. Atomic Layer Deposition for Stabilization of Amorphous Silicon Anodes |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Atomic Layer Deposition for Stabilization of Amorphous Silicon Anodes Atomic Layer Deposition for Stabilization of Amorphous Silicon Anodes 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon es145_dillon_2012_p.pdf More Documents & Publications Nanostructured Metal Oxide Anodes Atomic Layer Deposition for Stabilization of Silicon Anodes Development of Industrially Viable Battery Electrode

  10. Composite Electrolyte to Stabilize Metallic Lithium Anodes | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Electrolyte to Stabilize Metallic Lithium Anodes Composite Electrolyte to Stabilize Metallic Lithium Anodes 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon es157_dudney_2012_p.pdf More Documents & Publications Composite Electrolytes to Stabilize Metallic Linium Anodes Vehicle Technologies Office Merit Review 2015: Composite Electrolytes to Stabilize Metallic Lithium Anodes Long-Living Polymer

  11. Three Dimensional Anodes and Architectures | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Three Dimensional Anodes and Architectures Three Dimensional Anodes and Architectures 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon es143_vaughey_2012_p.pdf More Documents & Publications Novel Anode Materials Vehicle Technologies Office Merit Review 2014: Novel Anode Materials Vehicle Technologies Office: 2013 Energy Storage R&D Progress Report, Sections 1-3

  12. Synthesis and Characterization of Structured Si-Carbon Nanocomposite Anodes

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Functional Polymer Binders | Department of Energy 2 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon es147_wang_2012_p.pdf More Documents & Publications Novel Lithium Ion Anode Structures: Overview of New DOE BATT Anode Projects Synthesis and Characterization of Structured Si-Carbon Nanocomposite Anodes and Functional Polymer Binders Development of High Capacity Anode for Li-ion Batteries

  13. Composite Electrolytes to Stabilize Metallic Linium Anodes | Department of

    Office of Environmental Management (EM)

    Energy Composite Electrolytes to Stabilize Metallic Linium Anodes Composite Electrolytes to Stabilize Metallic Linium Anodes 2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon es182_dudney_2013_o.pdf More Documents & Publications Composite Electrolyte to Stabilize Metallic Lithium Anodes Vehicle Technologies Office Merit Review 2015: Composite Electrolytes to Stabilize Metallic Lithium Anodes Polymers For

  14. Hybrid anode for semiconductor radiation detectors

    DOE Patents [OSTI]

    Yang, Ge; Bolotnikov, Aleksey E; Camarda, Guiseppe; Cui, Yonggang; Hossain, Anwar; Kim, Ki Hyun; James, Ralph B

    2013-11-19

    The present invention relates to a novel hybrid anode configuration for a radiation detector that effectively reduces the edge effect of surface defects on the internal electric field in compound semiconductor detectors by focusing the internal electric field of the detector and redirecting drifting carriers away from the side surfaces of the semiconductor toward the collection electrode(s).

  15. Anode materials for lithium-ion batteries

    DOE Patents [OSTI]

    Sunkara, Mahendra Kumar; Meduri, Praveen; Sumanasekera, Gamini

    2014-12-30

    An anode material for lithium-ion batteries is provided that comprises an elongated core structure capable of forming an alloy with lithium; and a plurality of nanostructures placed on a surface of the core structure, with each nanostructure being capable of forming an alloy with lithium and spaced at a predetermined distance from adjacent nanostructures.

  16. Search for New Anode Materials | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    New Anode Materials Search for New Anode Materials 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon es_29_goodenough.pdf More Documents & Publications Solid Electrolyte Batteries Cathodes Developing High Capacity, Long Life Anodes

  17. Develop Improved Methods for Making Intermetallic Anodes | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy for Making Intermetallic Anodes Develop Improved Methods for Making Intermetallic Anodes 2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon es022_jansen_2011_p.pdf More Documents & Publications Improved Methods for Making Intermetallic Anodes Develop Improved Methods of

  18. Develop Improved Methods of Making Intermetallic Anodes | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy of Making Intermetallic Anodes Develop Improved Methods of Making Intermetallic Anodes 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon esp_16_jansen.pdf More Documents & Publications Improved Methods for Making Intermetallic Anodes Develop Improved Methods for

  19. Deep Web video

    ScienceCinema (OSTI)

    None Available

    2012-03-28

    To make the web work better for science, OSTI has developed state-of-the-art technologies and services including a deep web search capability. The deep web includes content in searchable databases available to web users but not accessible by popular search engines, such as Google. This video provides an introduction to the deep web search engine.

  20. Deep Web video

    SciTech Connect (OSTI)

    None Available

    2009-06-01

    To make the web work better for science, OSTI has developed state-of-the-art technologies and services including a deep web search capability. The deep web includes content in searchable databases available to web users but not accessible by popular search engines, such as Google. This video provides an introduction to the deep web search engine.

  1. Fuel cell anode configuration for CO tolerance

    DOE Patents [OSTI]

    Uribe, Francisco A.; Zawodzinski, Thomas A.

    2004-11-16

    A polymer electrolyte fuel cell (PEFC) is designed to operate on a reformate fuel stream containing oxygen and diluted hydrogen fuel with CO impurities. A polymer electrolyte membrane has an electrocatalytic surface formed from an electrocatalyst mixed with the polymer and bonded on an anode side of the membrane. An anode backing is formed of a porous electrically conductive material and has a first surface abutting the electrocatalytic surface and a second surface facing away from the membrane. The second surface has an oxidation catalyst layer effective to catalyze the oxidation of CO by oxygen present in the fuel stream where at least the layer of oxidation catalyst is formed of a non-precious metal oxidation catalyst selected from the group consisting of Cu, Fe, Co, Tb, W, Mo, Sn, and oxides thereof, and other metals having at least two low oxidation states.

  2. High performance anode for advanced Li batteries

    SciTech Connect (OSTI)

    Lake, Carla

    2015-11-02

    The overall objective of this Phase I SBIR effort was to advance the manufacturing technology for ASIs Si-CNF high-performance anode by creating a framework for large volume production and utilization of low-cost Si-coated carbon nanofibers (Si-CNF) for the battery industry. This project explores the use of nano-structured silicon which is deposited on a nano-scale carbon filament to achieve the benefits of high cycle life and high charge capacity without the consequent fading of, or failure in the capacity resulting from stress-induced fracturing of the Si particles and de-coupling from the electrode. ASIs patented coating process distinguishes itself from others, in that it is highly reproducible, readily scalable and results in a Si-CNF composite structure containing 25-30% silicon, with a compositionally graded interface at the Si-CNF interface that significantly improve cycling stability and enhances adhesion of silicon to the carbon fiber support. In Phase I, the team demonstrated the production of the Si-CNF anode material can successfully be transitioned from a static bench-scale reactor into a fluidized bed reactor. In addition, ASI made significant progress in the development of low cost, quick testing methods which can be performed on silicon coated CNFs as a means of quality control. To date, weight change, density, and cycling performance were the key metrics used to validate the high performance anode material. Under this effort, ASI made strides to establish a quality control protocol for the large volume production of Si-CNFs and has identified several key technical thrusts for future work. Using the results of this Phase I effort as a foundation, ASI has defined a path forward to commercialize and deliver high volume and low-cost production of SI-CNF material for anodes in Li-ion batteries.

  3. Lithium Metal Anodes for Rechargeable Batteries

    SciTech Connect (OSTI)

    Xu, Wu; Wang, Jiulin; Ding, Fei; Chen, Xilin; Nasybulin, Eduard N.; Zhang, Yaohui; Zhang, Jiguang

    2014-01-01

    Rechargeable lithium metal batteries have much higher energy density than those of lithium ion batteries using graphite anode. Unfortunately, uncontrollable dendritic lithium growth inherent in these batteries (upon repeated charge/discharge cycling) and limited Coulombic efficiency during lithium deposition/striping has prevented their practical application over the past 40 years. With the emerging of post Li-ion batteries, safe and efficient operation of lithium metal anode has become an enabling technology which may determine the fate of several promising candidates for the next generation of energy storage systems, including rechargeable Li-air battery, Li-S battery, and Li metal battery which utilize lithium intercalation compounds as cathode. In this work, various factors which affect the morphology and Coulombic efficiency of lithium anode will be analyzed. Technologies used to characterize the morphology of lithium deposition and the results obtained by modeling of lithium dendrite growth will also be reviewed. At last, recent development in this filed and urgent need in this field will also be discussed.

  4. Digging Crystal Deep

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Digging Crystal Deep 1663 Los Alamos science and technology magazine Latest Issue:October 2015 past issues All Issues » submit Digging Crystal Deep Los Alamos reengineers the insensitive high explosive responsible for keeping the B61 nuclear weapon safe against accidental detonation at the nanoscale-crystal level. October 25, 2015 Digging Crystal Deep The B61 aircraft-launched nuclear weapon New computer simulations make detailed predictions about how the explosive will behave and when it must

  5. Nanostructured Anodes for Lithium-Ion Batteries - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Storage Energy Storage Advanced Materials Advanced Materials Find More Like This Return to Search Nanostructured Anodes for Lithium-Ion Batteries New Anodes for Lithium-ion Batteries Increase Energy Density Four-Fold Savannah River National Laboratory Contact SRNL About This Technology Technology Marketing Summary Savannah River Nuclear Solutions (SRNS), managing contractor of the Savannah River Site (SRS) for the Department of Energy, has developed new anodes for lithium-ion batteries

  6. Designing Silicon Nanostructures for High Energy Lithium Ion Battery Anodes

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy Designing Silicon Nanostructures for High Energy Lithium Ion Battery Anodes Designing Silicon Nanostructures for High Energy Lithium Ion Battery Anodes 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon es148_cui_2012_p.pdf More Documents & Publications Wiring up Silicon Nanoparticles for High Performance Lithium-ion Battery Anodes Vehicle Technologies Office Merit Review 2014: Wiring

  7. Vehicle Technologies Office Merit Review 2014: Novel Anode Materials |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Novel Anode Materials Vehicle Technologies Office Merit Review 2014: Novel Anode Materials Presentation given by Argonne National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about novel anode materials. PDF icon es143_vaughey_2014_p.pdf More Documents & Publications Vehicle Technologies Office Merit Review 2014: First Principles Calculations and NMR Spectroscopy of Electrode

  8. Synthesis and Characterization of Silicon Clathrates for Anode Applications

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    in Lithium-Ion Batteries | Department of Energy Silicon Clathrates for Anode Applications in Lithium-Ion Batteries Synthesis and Characterization of Silicon Clathrates for Anode Applications in Lithium-Ion Batteries 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon es149_chan_2012_p.pdf More Documents & Publications Synthesis and Characterization of Silicon Clathrates for Anode Applications in Lithium-Ion

  9. Vehicle Technologies Office Merit Review 2014: Silicon Nanowire Anodes for

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Next Generation Energy Storage | Department of Energy Silicon Nanowire Anodes for Next Generation Energy Storage Vehicle Technologies Office Merit Review 2014: Silicon Nanowire Anodes for Next Generation Energy Storage Presentation given by Amprius, Inc. at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about silicon nanowire anodes for next generation energy storage. PDF icon es126_stefan_2014_p.pdf More Documents

  10. Synthesis and Characterization of Silicon Clathrates for Anode...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Batteries Synthesis and Characterization of Silicon Clathrates for Anode Applications in Lithium-Ion Batteries 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies...

  11. Establish and Expand Commercial Production of Graphite Anode...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Expand Commercial Production of Graphite Anode Materials for High Performance Lithium-ion Batteries 2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies...

  12. Oxide-based SOFC Anode Materials - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    offered in traditional metal oxides. Technology Marketing SummaryIn a solid-oxide fuel cell (SOFC), the anode facilitates the reaction between hydrogen, carbon monoxide and...

  13. Low cost fuel cell diffusion layer configured for optimized anode...

    Office of Scientific and Technical Information (OSTI)

    Patent: Low cost fuel cell diffusion layer configured for optimized anode water management Citation Details In-Document Search Title: Low cost fuel cell diffusion layer configured...

  14. Cooling for a rotating anode X-ray tube

    DOE Patents [OSTI]

    Smither, Robert K. (Hinsdale, IL)

    1998-01-01

    A method and apparatus for cooling a rotating anode X-ray tube. An electromagnetic motor is provided to rotate an X-ray anode with cooling passages in the anode. These cooling passages are coupled to a cooling structure located adjacent the electromagnetic motor. A liquid metal fills the passages of the cooling structure and electrical power is provided to the motor to rotate the anode and generate a rotating magnetic field which moves the liquid metal through the cooling passages and cooling structure.

  15. Ground water and energy

    SciTech Connect (OSTI)

    Not Available

    1980-11-01

    This national workshop on ground water and energy was conceived by the US Department of Energy's Office of Environmental Assessments. Generally, OEA needed to know what data are available on ground water, what information is still needed, and how DOE can best utilize what has already been learned. The workshop focussed on three areas: (1) ground water supply; (2) conflicts and barriers to ground water use; and (3) alternatives or solutions to the various issues relating to ground water. (ACR)

  16. Ground difference compensating system

    DOE Patents [OSTI]

    Johnson, Kris W.; Akasam, Sivaprasad

    2005-10-25

    A method of ground level compensation includes measuring a voltage of at least one signal with respect to a primary ground potential and measuring, with respect to the primary ground potential, a voltage level associated with a secondary ground potential. A difference between the voltage level associated with the secondary ground potential and an expected value is calculated. The measured voltage of the at least one signal is adjusted by an amount corresponding to the calculated difference.

  17. Electrolytic production of high purity aluminum using inert anodes

    DOE Patents [OSTI]

    Ray, Siba P. (Murrysville, PA); Liu, Xinghua (Monroeville, PA); Weirauch, Jr., Douglas A. (Murrysville, PA)

    2001-01-01

    A method of producing commercial purity aluminum in an electrolytic reduction cell comprising inert anodes is disclosed. The method produces aluminum having acceptable levels of Fe, Cu and Ni impurities. The inert anodes used in the process preferably comprise a cermet material comprising ceramic oxide phase portions and metal phase portions.

  18. Electrolytic production of high purity aluminum using ceramic inert anodes

    DOE Patents [OSTI]

    Ray, Siba P. (Murrysville, PA); Liu, Xinghua (Monroeville, PA); Weirauch, Douglas A. (Murrysville, PA); DiMilia, Robert A. (Baton Rouge, LA); Dynys, Joseph M. (New Kensington, PA); Phelps, Frankie E. (Apollo, PA); LaCamera, Alfred F. (Trafford, PA)

    2002-01-01

    A method of producing commercial purity aluminum in an electrolytic reduction cell comprising ceramic inert anodes is disclosed. The method produces aluminum having acceptable levels of Fe, Cu and Ni impurities. The ceramic inert anodes used in the process may comprise oxides containing Fe and Ni, as well as other oxides, metals and/or dopants.

  19. Carbon paint anode for reinforced concrete bridges in coastal environments

    SciTech Connect (OSTI)

    Cramer, Stephen D.; Bullard, Sophie J.; Covino, Bernard S., Jr.; Holcomb, Gordon R.; Russell, James H.; Cryer, C.B.; Laylor, H.M.

    2002-01-01

    Solvent-based acrylic carbon paint anodes were installed on the north approach spans of the Yaquina Bay Bridge (Newport OR) in 1985. The anodes continue to perform satisfactorily after more than 15 years service. The anodes were inexpensive to apply and field repairs are easily made. Depolarization potentials are consistently above 100 mV with long-term current densities around 2 mA/m 2. Bond strength remains adequate, averaging 0.50 MPa (73 psi). Some deterioration of the anode-concrete interface has occurred in the form of cracks and about 4% of the bond strength measurements indicated low or no bond. Carbon anode consumption appears low. The dominant long-term anode reaction appears to be chlorine evolution, which results in limited further acidification of the anode-concrete interface. Chloride profiles were depressed compared to some other coastal bridges suggesting chloride extraction by the CP system. Further evidence of outward chloride migration was a flat chloride profile between the anode and the outer rebar.

  20. Low cost fuel cell diffusion layer configured for optimized anode water

    Office of Scientific and Technical Information (OSTI)

    management (Patent) | SciTech Connect Patent: Low cost fuel cell diffusion layer configured for optimized anode water management Citation Details In-Document Search Title: Low cost fuel cell diffusion layer configured for optimized anode water management A fuel cell comprises a cathode gas diffusion layer, a cathode catalyst layer, an anode gas diffusion layer, an anode catalyst layer and an electrolyte. The diffusion resistance of the anode gas diffusion layer when operated with anode fuel

  1. Deep Sky Astronomical Image Database

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Deep Sky Astronomical Image Database Deep Sky Astronomical Image Database Key Challenges: Develop, store, analyze, and make available an astronomical image database of...

  2. Deep Vadose Zone - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Long-Range Deep Vadose Zone Program Plan, (Rev. 0) - (PDF) Implementation Plan for the Deep Vadose Zone Applied Field Research Center (DVZ-AFRC) - (PDF) Ecology's groundwater...

  3. Virtual cathode microwave generator having annular anode slit

    DOE Patents [OSTI]

    Kwan, Thomas J. T.; Snell, Charles M.

    1988-01-01

    A microwave generator is provided for generating microwaves substantially from virtual cathode oscillation. Electrons are emitted from a cathode and accelerated to an anode which is spaced apart from the cathode. The anode has an annular slit therethrough effective to form the virtual cathode. The anode is at least one range thickness relative to electrons reflecting from the virtual cathode. A magnet is provided to produce an optimum magnetic field having the field strength effective to form an annular beam from the emitted electrons in substantial alignment with the annular anode slit. The magnetic field, however, does permit the reflected electrons to axially diverge from the annular beam. The reflected electrons are absorbed by the anode in returning to the real cathode, such that substantially no reflexing electrons occur. The resulting microwaves are produced with a single dominant mode and are substantially monochromatic relative to conventional virtual cathode microwave generators.

  4. Focused cathode design to reduce anode heating during vircator operation

    SciTech Connect (OSTI)

    Lynn, Curtis F.; Dickens, James C.; Neuber, Andreas A.

    2013-10-15

    Virtual cathode oscillators, or vircators, are a type of high power microwave device which operates based on the instability of a virtual cathode, or cloud of electrons, which forms when electron current injected into the drift tube exceeds the space charge limited current within the drift tube. Anode heating by the electron beam during vircator operation ultimately limits achievable pulse lengths, repetition rates, and the duration of burst mode operation. This article discusses a novel cathode design that focuses electrons through holes in the anode, thus significantly reducing anode heating by the electrons emitted from the cathode during the first transit through the A-K gap. Reflexing electrons continue to deposit energy on the anode; however, the discussed minimization of anode heating by main beam electrons has the potential to enable higher repetition rates as well as efficiency and longer diode lifetime. A simulation study of this type of cathode design illustrates possible advantages.

  5. Material and Energy Flows in the Production of Cathode and Anode...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Material and Energy Flows in the Production of Cathode and Anode Materials for Lithium Ion Batteries Title Material and Energy Flows in the Production of Cathode and Anode...

  6. Exploration for deep coal

    SciTech Connect (OSTI)

    2008-12-15

    The most important factor in safe mining is the quality of the roof. The article explains how the Rosebud Mining Co. conducts drilling and exploration in 11 deep coal mine throughout Pennsylvania and Ohio. Rosebud uses two Atlas Copco CS10 core drilling rigs mounted on 4-wheel drive trucks. The article first appeared in Atlas Copco's in-house magazine, Deep Hole Driller. 3 photos.

  7. Carbonaceous materials as lithium intercalation anodes

    SciTech Connect (OSTI)

    Tran, T.D.; Feikert, J.H.; Mayer, S.T.; Song, X.; Kinoshita, K.

    1994-10-01

    Commercial and polymer-derived carbonaceous materials were examined as lithium intercalation anodes in propylene carbonate (pyrolysis < 1350C, carbons) and ethylene carbonate/dimethyl carbonate (graphites) electrolytes. The reversible capacity (180--355 mAh/g) and the irreversible capacity loss (15--200 % based on reversible capacity) depend on the type of binder, carbon type, morphology, and phosphorus doping concentration. A carbon-based binder was chosen for electrode fabrication, producing mechanically and chemically stable electrodes and reproducible results. Several types of graphites had capacity approaching LiC{sub 6}. Petroleum fuel green cokes doped with phosphorous gave more than a 20 % increase in capacity compared to undoped samples. Electrochemical characteristics are related to SEM, TEM, XRD and BET measurements.

  8. ZIRCONIUM OXIDE NANOSTRUCTURES PREPARED BY ANODIC OXIDATION

    SciTech Connect (OSTI)

    Dang, Y. Y.; Bhuiyan, M.S.; Paranthaman, M. P.

    2008-01-01

    Zirconium oxide is an advanced ceramic material highly useful for structural and electrical applications because of its high strength, fracture toughness, chemical and thermal stability, and biocompatibility. If highly-ordered porous zirconium oxide membranes can be successfully formed, this will expand its real-world applications, such as further enhancing solid-oxide fuel cell technology. Recent studies have achieved various morphologies of porous zirconium oxide via anodization, but they have yet to create a porous layer where nanoholes are formed in a highly ordered array. In this study, electrochemical methods were used for zirconium oxide synthesis due to its advantages over other coating techniques, and because the thickness and morphology of the ceramic fi lms can be easily tuned by the electrochemical parameters, such as electrolyte solutions and processing conditions, such as pH, voltage, and duration. The effects of additional steps such as pre-annealing and post-annealing were also examined. Results demonstrate the formation of anodic porous zirconium oxide with diverse morphologies, such as sponge-like layers, porous arrays with nanoholes ranging from 40 to 75 nm, and nanotube layers. X-ray powder diffraction analysis indicates a cubic crystallographic structure in the zirconium oxide. It was noted that increased voltage improved the ability of the membrane to stay adhered to the zirconium substrate, whereas lower voltages caused a propensity for the oxide fi lm to fl ake off. Further studies are needed to defi ne the parameters windows that create these morphologies and to investigate other important characteristics such as ionic conductivity.

  9. Cu-Ni-Fe anodes having improved microstructure

    DOE Patents [OSTI]

    Bergsma, S. Craig; Brown, Craig W.

    2004-04-20

    A method of producing aluminum in a low temperature electrolytic cell containing alumina dissolved in an electrolyte. The method comprises the steps of providing a molten electrolyte having alumina dissolved therein in an electrolytic cell containing the electrolyte. A non-consumable anode and cathode is disposed in the electrolyte, the anode comprised of Cu--Ni--Fe alloys having single metallurgical phase. Electric current is passed from the anode, through the electrolyte to the cathode thereby depositing aluminum on the cathode, and molten aluminum is collected from the cathode.

  10. A Better Anode Design to Improve Lithium-Ion Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Better Anode Design to Improve Lithium-Ion Batteries Print Lithium-ion batteries are in smart phones, laptops, most other consumer electronics, and the newest electric cars. Good as these batteries are, the need for energy storage in batteries is surpassing current technologies. In a lithium-ion battery, charge moves from the cathode to the anode, a critical component for storing energy. A team of Berkeley Lab scientists has designed a new kind of anode that absorbs eight times the lithium of

  11. A Better Anode Design to Improve Lithium-Ion Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Better Anode Design to Improve Lithium-Ion Batteries Print Lithium-ion batteries are in smart phones, laptops, most other consumer electronics, and the newest electric cars. Good as these batteries are, the need for energy storage in batteries is surpassing current technologies. In a lithium-ion battery, charge moves from the cathode to the anode, a critical component for storing energy. A team of Berkeley Lab scientists has designed a new kind of anode that absorbs eight times the lithium of

  12. A Better Anode Design to Improve Lithium-Ion Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Better Anode Design to Improve Lithium-Ion Batteries Print Lithium-ion batteries are in smart phones, laptops, most other consumer electronics, and the newest electric cars. Good as these batteries are, the need for energy storage in batteries is surpassing current technologies. In a lithium-ion battery, charge moves from the cathode to the anode, a critical component for storing energy. A team of Berkeley Lab scientists has designed a new kind of anode that absorbs eight times the lithium of

  13. A Better Anode Design to Improve Lithium-Ion Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Better Anode Design to Improve Lithium-Ion Batteries Print Lithium-ion batteries are in smart phones, laptops, most other consumer electronics, and the newest electric cars. Good as these batteries are, the need for energy storage in batteries is surpassing current technologies. In a lithium-ion battery, charge moves from the cathode to the anode, a critical component for storing energy. A team of Berkeley Lab scientists has designed a new kind of anode that absorbs eight times the lithium of

  14. A Better Anode Design to Improve Lithium-Ion Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Better Anode Design to Improve Lithium-Ion Batteries Print Lithium-ion batteries are in smart phones, laptops, most other consumer electronics, and the newest electric cars. Good as these batteries are, the need for energy storage in batteries is surpassing current technologies. In a lithium-ion battery, charge moves from the cathode to the anode, a critical component for storing energy. A team of Berkeley Lab scientists has designed a new kind of anode that absorbs eight times the lithium of

  15. A Better Anode Design to Improve Lithium-Ion Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Better Anode Design to Improve Lithium-Ion Batteries A Better Anode Design to Improve Lithium-Ion Batteries Print Friday, 23 March 2012 13:53 Lithium-ion batteries are in smart phones, laptops, most other consumer electronics, and the newest electric cars. Good as these batteries are, the need for energy storage in batteries is surpassing current technologies. In a lithium-ion battery, charge moves from the cathode to the anode, a critical component for storing energy. A team of Berkeley Lab

  16. A Better Anode Design to Improve Lithium-Ion Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Better Anode Design to Improve Lithium-Ion Batteries Print Lithium-ion batteries are in smart phones, laptops, most other consumer electronics, and the newest electric cars. Good as these batteries are, the need for energy storage in batteries is surpassing current technologies. In a lithium-ion battery, charge moves from the cathode to the anode, a critical component for storing energy. A team of Berkeley Lab scientists has designed a new kind of anode that absorbs eight times the lithium of

  17. A Better Anode Design to Improve Lithium-Ion Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Better Anode Design to Improve Lithium-Ion Batteries Print Lithium-ion batteries are in smart phones, laptops, most other consumer electronics, and the newest electric cars. Good as these batteries are, the need for energy storage in batteries is surpassing current technologies. In a lithium-ion battery, charge moves from the cathode to the anode, a critical component for storing energy. A team of Berkeley Lab scientists has designed a new kind of anode that absorbs eight times the lithium of

  18. A Better Anode Design to Improve Lithium-Ion Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Better Anode Design to Improve Lithium-Ion Batteries Print Lithium-ion batteries are in smart phones, laptops, most other consumer electronics, and the newest electric cars. Good as these batteries are, the need for energy storage in batteries is surpassing current technologies. In a lithium-ion battery, charge moves from the cathode to the anode, a critical component for storing energy. A team of Berkeley Lab scientists has designed a new kind of anode that absorbs eight times the lithium of

  19. Short time proton dynamics in bulk ice and in porous anode solid oxide fuel cell materials

    SciTech Connect (OSTI)

    Basoli, Francesco; Senesi, Roberto; Kolesnikov, Alexander I; Licoccia, Silvia

    2014-01-01

    Oxygen reduction and incorporation into solid electrolytes and the reverse reaction of oxygen evolution play a cru-cial role in Solid Oxide Fuel Cell (SOFC) applications. However a detailed un derstanding of the kinetics of the cor-responding reactions, i.e. on reaction mechanisms, rate limiting steps, reaction paths, electrocatalytic role of materials, is still missing. These include a thorough characterization of the binding potentials experienced by protons in the lattice. We report results of Inelastic Neutron Scattering (INS) measurements of the vibrational state of the protons in Ni- YSZ highly porous composites (75% to 90% ), a ceramic-metal material showing a high electrical conductivity and ther mal stability, which is known to be most effectively used as anodes for solid ox ide fuel cells. The results are compared with INS and Deep Inelastic Neutron Scattering (DINS) experiments on the proton binding states in bulk ice.

  20. Deep Secrets of the Neutrino: Physics Underground

    SciTech Connect (OSTI)

    Rowson, P.C.

    2010-03-23

    Among the many beautiful, unexpected and sometimes revolutionary discoveries to emerge from subatomic physics, probably none is more bizarre than an elementary particle known as the 'neutrino'. More than a trillion of these microscopic phantoms pass unnoticed through our bodies every second, and indeed, through the entire Earth - but their properties remain poorly understood. In recent years, exquisitely sensitive experiments, often conducted deep below ground, have brought neutrino physics to the forefront. In this talk, we will explore the neutrino - what we know, what we want to know, and how one experiment in a New Mexico mine is trying to get there.

  1. A Better Anode Design to Improve Lithium-Ion Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Better Anode Design to Improve Lithium-Ion Batteries Print Lithium-ion batteries are in ... 8.0.1 show a lower "lowest unoccupied molecular orbital" for the new Berkeley Lab ...

  2. A Better Anode Design to Improve Lithium-Ion Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Better Anode Design to Improve Lithium-Ion Batteries Print Lithium-ion batteries are in ... 8.0.1 show a lower "lowest unoccupied molecular orbital" for the new Berkeley Lab ...

  3. A Better Anode Design to Improve Lithium-Ion Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Better Anode Design to Improve Lithium-Ion Batteries Print Lithium-ion batteries are in smart phones, laptops, most other consumer electronics, and the newest electric cars. Good...

  4. Lithium-Titanium-Oxide Anodes Improve Battery Safety and Performance...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lithium-Titanium-Oxide Anodes Improve Battery Safety and Performance Technology available for licensing: Li4Ti5O12 spinel is a promising alternative to graphite electrodes with...

  5. Fluoroethylene carbonate and %22silicon oxide%22 on silicon anodes:

    Office of Scientific and Technical Information (OSTI)

    modeling SEI reaction mechanisms. (Conference) | SciTech Connect Fluoroethylene carbonate and %22silicon oxide%22 on silicon anodes: modeling SEI reaction mechanisms. Citation Details In-Document Search Title: Fluoroethylene carbonate and %22silicon oxide%22 on silicon anodes: modeling SEI reaction mechanisms. Abstract not provided. Authors: Leung, Kevin Publication Date: 2013-05-01 OSTI Identifier: 1115631 Report Number(s): SAND2013-3743C 479901 DOE Contract Number: AC04-94AL85000 Resource

  6. Fuel cell having dual electrode anode or cathode

    DOE Patents [OSTI]

    Findl, E.

    1984-04-10

    A fuel cell that is characterized by including a dual electrode anode that is operable to simultaneously electro-oxidize a gaseous fuel and a liquid fuel. In alternative embodiments, a fuel cell having a single electrode anode is provided with a dual electrode cathode that is operable to simultaneously reduce a gaseous oxidant and a liquid oxidant to electro-oxidize a fuel supplied to the cell.

  7. Multilayer Graphene-Silicon Structures for Lithium Ion Battery Anodes -

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Innovation Portal Multilayer Graphene-Silicon Structures for Lithium Ion Battery Anodes Lawrence Berkeley National Laboratory Contact LBL About This Technology Publications: PDF Document Publication Ji, L., Zheng, H., Ismach, A., Tan, Z., Xun, S., Lin, E., Battaglia, V., Srinivasan, V., Zhang, Y., "Graphene/Si multilayer structure anodes for advanced half and full lithium-ion cells," Nano Energy, August 27, 2011. (1,629 KB) PDF Document Publication Ji, L., Zhang, X.,

  8. Nanocomposite Carbon/Tin Anodes for Lithium Ion Batteries - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovation Portal Nanocomposite Carbon/Tin Anodes for Lithium Ion Batteries Lawrence Berkeley National Laboratory Contact LBL About This Technology Technology Marketing SummaryAn approach developed by Robert Kostecki and Marek Marcinek of Berkeley Lab has given rise to a new generation of nanostructured carbon-tin films that can be produced quickly, efficiently, and inexpensively. These binderless carbon/tin thin-film anodes provide enhanced charge capacity and excellent cycleability in

  9. Lithium-Titanium-Oxide Anodes Improve Battery Safety and Performance |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Argonne National Laboratory Lithium-Titanium-Oxide Anodes Improve Battery Safety and Performance Technology available for licensing: Li4Ti5O12 spinel is a promising alternative to graphite electrodes with enhanced conductivity, voltage and energy density. Enhanced stability at lower cost Li4Ti5O12 spinel is a promising alternative to graphite electrodes with enhanced conductivity, voltage and energy density PDF icon LTO_anodes

  10. Establish and Expand Commercial Production of Graphite Anode Materials for

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High Performance Lithium-ion Batteries | Department of Energy Establish and Expand Commercial Production of Graphite Anode Materials for High Performance Lithium-ion Batteries Establish and Expand Commercial Production of Graphite Anode Materials for High Performance Lithium-ion Batteries 2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon arravt012_es_mcchesney_2011_p.pdf More Documents & Publications Pyrotek

  11. Fuel cell having dual electrode anode or cathode

    DOE Patents [OSTI]

    Findl, Eugene (Coram, NY)

    1985-01-01

    A fuel cell that is characterized by including a dual electrode anode that is operable to simultaneously electro-oxidize a gaseous fuel and a liquid fuel. In alternative embodiments, a fuel cell having a single electrode anode is provided with a dual electrode cathode that is operable to simultaneously reduce a gaseous oxidant and a liquid oxidant to electro-oxidize a fuel supplied to the cell.

  12. Synthesis and Characterization of Structured Si-Carbon Nanocomposite Anodes

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Functional Polymer Binders | Department of Energy 3 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon es147_wang_2013_o.pdf More Documents & Publications Vehicle Technologies Office Merit Review 2014: Synthesis and Characterization of Structured Si-Carbon Nanocomposite Anodes and Functional Polymer Binders Synthesis and Characterization of Structured Si-Carbon Nanocomposite Anodes and Functional Polymer

  13. Hyper-dendritic nanoporous zinc foam anodes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chamoun, Mylad; Hertzberg, Benjamin J.; Gupta, Tanya; Davies, Daniel; Bhadra, Shoham; Van Tassell, Barry.; Erdonmez, Can; Steingart, Daniel A.

    2015-04-24

    The low cost, significant reducing potential, and relative safety of the zinc electrode is a common hope for a reductant in secondary batteries, but it is limited mainly to primary implementation due to shape change. In this work we exploit such shape change for the benefit of static electrodes through the electrodeposition of hyper-dendritic nanoporous zinc foam. Electrodeposition of zinc foam resulted in nanoparticles formed on secondary dendrites in a three-dimensional network with a particle size distribution of 54.1 - 96.0 nm. The nanoporous zinc foam contributed to highly oriented crystals, high surface area and more rapid kinetics in contrastmore » to conventional zinc in alkaline mediums. The anode material presented had a utilization of ~ 88% at full depth-of-discharge at various rates indicating a superb rate-capability. The rechargeability of Zn⁰/Zn²⁺ showed significant capacity retention over 100 cycles at a 40% depth-of-discharge to ensure that the dendritic core structure was imperforated. The dendritic architecture was densified upon charge-discharge cycling and presented superior performance compared to bulk zinc electrodes.« less

  14. Process for anodizing a robotic device

    DOE Patents [OSTI]

    Townsend, William T. (Weston, MA)

    2011-11-08

    A robotic device has a base and at least one finger having at least two links that are connected in series on rotary joints with at least two degrees of freedom. A brushless motor and an associated controller are located at each joint to produce a rotational movement of a link. Wires for electrical power and communication serially connect the controllers in a distributed control network. A network operating controller coordinates the operation of the network, including power distribution. At least one, but more typically two to five, wires interconnect all the controllers through one or more joints. Motor sensors and external world sensors monitor operating parameters of the robotic hand. The electrical signal output of the sensors can be input anywhere on the distributed control network. V-grooves on the robotic hand locate objects precisely and assist in gripping. The hand is sealed, immersible and has electrical connections through the rotary joints for anodizing in a single dunk without masking. In various forms, this intelligent, self-contained, dexterous hand, or combinations of such hands, can perform a wide variety of object gripping and manipulating tasks, as well as locomotion and combinations of locomotion and gripping.

  15. New Layered Nanolaminates for Use in Lithium Battery Anodes | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Layered Nanolaminates for Use in Lithium Battery Anodes New Layered Nanolaminates for Use in Lithium Battery Anodes 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon es146_gogotsi_2012_p.pdf More Documents & Publications New Layered Nanolaminates for Use in Lithium Battery Anodes 2012 Annual Merit Review Results Report - Acronyms Novel Lithium Ion Anode Structures: Overview of New DOE BATT Anode

  16. Stainless steel anodes for alkaline water electrolysis and methods of making

    DOE Patents [OSTI]

    Soloveichik, Grigorii Lev

    2014-01-21

    The corrosion resistance of stainless steel anodes for use in alkaline water electrolysis was increased by immersion of the stainless steel anode into a caustic solution prior to electrolysis. Also disclosed herein are electrolyzers employing the so-treated stainless steel anodes. The pre-treatment process provides a stainless steel anode that has a higher corrosion resistance than an untreated stainless steel anode of the same composition.

  17. Metal-Based, High-Capacity Lithium-Ion Anodes | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Based, High-Capacity Lithium-Ion Anodes Metal-Based, High-Capacity Lithium-Ion Anodes 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon es063_whittingham_2012_p.pdf More Documents & Publications Metal-Based, High-Capacity Lithium-Ion Anodes Nanostructured Materials as Anodes Vehicle Technologies Office Merit Review 2014: Metal-Based High Capacity Li-Ion Anodes

  18. Deep Energy Retrofits & State Applications

    Broader source: Energy.gov [DOE]

    This presentation, given through the DOE's Technical Assitance Program (TAP), provides information on Deep Energy Retrofits & State Applications

  19. Nervana Neon - Scalable Deep Learning library

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Neon Nervana Neon - Scalable Deep Learning library Description and Overview neon is an easy to use, python-based scalable Deep Learning library. Deep Learning has recently achieved...

  20. Deep Energy Retrofits

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High Performance High Performance Enclosure Strategies: Part I Existing Home Part I, Existing Home Deep Energy Retrofits Anastasia Herk IBACOS Project Partners Manufacturers, Contractors, NYSERDA, Engineers 2 Goals of Research Project: * Evaluate cost and performance trade offs between: - Spray-foam exterior walls - Rigid foam exterior walls - Home Performance with Energy Star Home (HPwES) on steroids * 50% peak load and annual heating load reduction * R-30Target for Center of Wall * .25 CFM50

  1. In situ characterization of nanoscale catalysts during anodic redox processes

    SciTech Connect (OSTI)

    Sharma, Renu National Institute of Standards and Technology; Crozier, Peter Arizona State University; Adams, James Arizona State University

    2013-09-19

    Controlling the structure and composition of the anode is critical to achieving high efficiency and good long-term performance. In addition to being a mixed electronic and ionic conductor, the ideal anode material should act as an efficient catalyst for oxidizing hydrogen, carbon monoxide and dry hydrocarbons without de-activating through either sintering or coking. It is also important to develop novel anode materials that can operate at lower temperatures to reduce costs and minimized materials failure associated with high temperature cycling. We proposed to synthesize and characterize novel anode cermets materials based on ceria doped with Pr and/or Gd together with either a Ni or Cu metallic components. Ceria is a good oxidation catalyst and is an ionic conductor at room temperature. Doping it with trivalent rare earths such as Pr or Gd retards sintering and makes it a mixed ion conductor (ionic and electronic). We have developed a fundamental scientific understanding of the behavior of the cermet material under reaction conditions by following the catalytic oxidation process at the atomic scale using a powerful Environmental Scanning Transmission Electron Microscope (ESTEM). The ESTEM allowed in situ monitoring of structural, chemical and morphological changes occurring at the cermet under conditions approximating that of typical fuel-cell operation. Density functional calculations were employed to determine the underlying mechanisms and reaction pathways during anode oxidation reactions. The dynamic behavior of nanoscale catalytic oxidation of hydrogen and methane were used to determine: ? Fundamental processes during anodic reactions in hydrogen and carbonaceous atmospheres ? Interfacial effects between metal particles and doped ceria ? Kinetics of redox reaction in the anode material

  2. Low cost fuel cell diffusion layer configured for optimized anode water management

    DOE Patents [OSTI]

    Owejan, Jon P; Nicotera, Paul D; Mench, Matthew M; Evans, Robert E

    2013-08-27

    A fuel cell comprises a cathode gas diffusion layer, a cathode catalyst layer, an anode gas diffusion layer, an anode catalyst layer and an electrolyte. The diffusion resistance of the anode gas diffusion layer when operated with anode fuel is higher than the diffusion resistance of the cathode gas diffusion layer. The anode gas diffusion layer may comprise filler particles having in-plane platelet geometries and be made of lower cost materials and manufacturing processes than currently available commercial carbon fiber substrates. The diffusion resistance difference between the anode gas diffusion layer and the cathode gas diffusion layer may allow for passive water balance control.

  3. Ground potential rise monitor

    DOE Patents [OSTI]

    Allen, Zachery Warren; Zevenbergen, Gary Allen

    2012-07-17

    A device and method for detecting ground potential rise (GPR) comprising a first electrode, a second electrode, and a voltage attenuator. The first electrode and the second electrode are both electrically connected to the voltage attenuator. A means for determining the presence of a dangerous ground potential is connected to the voltage attenuator. The device and method further comprises a means for enabling one or more alarms upon the detection of the dangerous ground potential. Preferably, a first transmitter/receiver is connected to the means for enabling one or more alarms. Preferably, a second transmitter/receiver, comprising a button, is electromagnetically connected to the first transmitter/receiver. Preferably, the means for determining the presence of a dangerous ground potential comprises a means for determining the true RMS voltage at the output of the voltage attenuator, a transient detector connected to the output of the voltage attenuator, or a combination thereof.

  4. Battery with modular air cathode and anode cage

    DOE Patents [OSTI]

    Niksa, Marilyn J. (Painesville, OH); Pohto, Gerald R. (Mentor, OH); Lakatos, Leslie K. (Mentor, OH); Wheeler, Douglas J. (Cleveland Heights, OH); Niksa, Andrew J. (Painesville, OH); Schue, Thomas J. (Huntsburg, OH); Turk, Thomas R. (Mentor, OH)

    1988-01-01

    A battery assembly of the consumable metal anode type has now been constructed for ready assembly as well as disassembly. In a non-conductive and at least substantially inert cell body, space is provided for receiving an open-structured, non-consumable anode cage. The cage has an open top for facilitating insertion of an anode. A modular cathode is used, comprising a peripheral current conductor frame clamped about a grid reinforced air cathode in sheet form. The air cathode may be double gridded. The cathode frame can be sealed, during assembly, with electrolyte-resistant-sealant as well as with adhesive. The resulting cathode module can be assembled outside the cell body and readily inserted therein, or can later be easily removed therefrom.

  5. Battery with modular air cathode and anode cage

    DOE Patents [OSTI]

    Niksa, Marilyn J. (Painesville, OH); Pohto, Gerald R. (Mentor, OH); Lakatos, Leslie K. (Mentor, OH); Wheeler, Douglas J. (Cleveland Heights, OH); Niksa, Andrew J. (Painesville, OH); Schue, Thomas J. (Huntsburg, OH)

    1987-01-01

    A battery assembly of the consumable metal anode type has now been constructed for ready assembly as well as disassembly. In a non-conductive and at least substantially inert cell body, space is provided for receiving an open-structured, non-consumable anode cage. The cage has an open top for facilitating insertion of an anode. A modular cathode is used, comprising a peripheral current conductor frame clamped about a grid reinforced air cathode in sheet form. The air cathode may be double gridded. The cathode frame can be sealed, during assembly, with electrolyte-resistant-sealant as well as with adhesive. The resulting cathode module can be assembled outside the cell body and readily inserted therein, or can later be easily removed therefrom.

  6. The possibility of forming a sacrificial anode coating for Mg

    SciTech Connect (OSTI)

    Dudney, Nancy J; Li, Juchuan; Sacci, Robert L; Thomson, Jeffery K

    2014-01-01

    Mg is the most active engineering metal, and is often used as a sacrificial anode/coating to protect other engineering metals from corrosion attack. So far no sacrificial anode coating has been developed or considered for Mg. This study explores the possibility of forming a sacrificial coating for Mg. A lithiated carbon coating and a metaphosphated coating are applied on the Mg surface, respectively, and their open-circuit-potentials are measured in saturated Mg(OH)2 solution. They exhibit more negative potentials than bare Mg. SEM reveals that the metaphosphated coating offers more effective and uniform protection for Mg than the lithiated carbon coating. These preliminary results indicate that development of a sacrificial anode coating for Mg is indeed possible.

  7. Color Anodizing of Titanium Coated Rolled Carbon Steel Plate

    SciTech Connect (OSTI)

    Sarajan, Zohair; Mobarakeh, Hooman Nikbakht; Namiranian, Sohrab

    2011-12-26

    As an important kind of structural materials, the titanium cladded steel plates have the advantages of both metals and have been applied in aviation, spaceflight, chemical and nuclear industries. In this study, the specimens which were prepared under soldering mechanism during rolling were anodized by electrochemical process under a given conditions. The color anodizing takes place by physical phenomenon of color interference. Part of incident light on the titanium oxide is reflected and the other part reflects inside coated titanium layer. Major part of the light which reflects from titanium-oxide interface, reflects again inside of the oxide layer.

  8. Electrolytic production of metals using a resistant anode

    DOE Patents [OSTI]

    Tarcy, G.P.; Gavasto, T.M.; Ray, S.P.

    1986-11-04

    An electrolytic process is described comprising evolving oxygen on an anode in a molten salt, the anode comprising an alloy comprising a first metal and a second metal, both metals forming oxides, the oxide of the first metal being more resistant than the second metal to attack by the molten salt, the oxide of the second metal being more resistant than the first metal to the diffusion of oxygen. The electrode may also be formed of CuAlO[sub 2] and/or Cu[sub 2]O. 2 figs.

  9. Oxygen-producing inert anodes for SOM process

    DOE Patents [OSTI]

    Pal, Uday B

    2014-02-25

    An electrolysis system for generating a metal and molecular oxygen includes a container for receiving a metal oxide containing a metallic species to be extracted, a cathode positioned to contact a metal oxide housed within the container; an oxygen-ion-conducting membrane positioned to contact a metal oxide housed within the container; an anode in contact with the oxygen-ion-conducting membrane and spaced apart from a metal oxide housed within the container, said anode selected from the group consisting of liquid metal silver, oxygen stable electronic oxides, oxygen stable crucible cermets, and stabilized zirconia composites with oxygen stable electronic oxides.

  10. Overview of SOFC Anode Interactions with Coal Gas Impurities

    SciTech Connect (OSTI)

    O. A. Marina; L. R. Pederson; R. Gemmen; K. Gerdes; H. Finklea; I. B. Celik

    2010-03-01

    An overview of the results of SOFC anode interactions with phosphorus, arsenic, selenium, sulfur, antimony, and hydrogen chloride as single contaminants or in combinations is discussed. Tests were performed using both anode- and electrolyte-supported cells in synthetic and actual coal gas for periods greater than 1000 hours. Post-test analyses were performed to identify reaction products formed and their distribution, and compared to phases expected from thermochemical modeling. The ultimate purpose of this work is to establish maximum permissible concentrations for impurities in coal gas, to aid in the selection of appropriate coal gas clean-up technologies.

  11. Overview of SOFC Anode Interactions with Coal Gas Impurities

    SciTech Connect (OSTI)

    Marina, Olga A.; Pederson, Larry R.; Gemmen, Randall; Gerdes, Kirk; Finklea, Harry; Celik, Ismail B.

    2010-05-01

    An overview of the results of SOFC anode interactions with phosphorus, arsenic, selenium, sulfur, antimony, and hydrogen chloride as single contaminants or in combinations is discussed. Tests were performed using both anode- and electrolyte-supported cells in synthetic and actual coal gas for periods greater than 1000 hours. Post-test analyses were performed to identify reaction products formed and their distribution, and compared to phases expected from thermochemical modeling. The ultimate purpose of this work is to establish maximum permissible concentrations for impurities in coal gas, to aid in the selection of appropriate coal gas clean-up technologies.

  12. Protective lithium ion conducting ceramic coating for lithium metal anodes and associate method

    DOE Patents [OSTI]

    Bates, John B. (Oak Ridge, TN)

    1994-01-01

    A battery structure including a cathode, a lithium metal anode and an electrolyte disposed between the lithium anode and the cathode utilizes a thin-film layer of lithium phosphorus oxynitride overlying so as to coat the lithium anode and thereby separate the lithium anode from the electrolyte. If desired, a preliminary layer of lithium nitride may be coated upon the lithium anode before the lithium phosphorous oxynitride is, in turn, coated upon the lithium anode so that the separation of the anode and the electrolyte is further enhanced. By coating the lithium anode with this material lay-up, the life of the battery is lengthened and the performance of the battery is enhanced.

  13. Solid state thin film battery having a high temperature lithium alloy anode

    DOE Patents [OSTI]

    Hobson, David O. (Oak Ridge, TN)

    1998-01-01

    An improved rechargeable thin-film lithium battery involves the provision of a higher melting temperature lithium anode. Lithium is alloyed with a suitable solute element to elevate the melting point of the anode to withstand moderately elevated temperatures.

  14. Novel Approach to Advanced Direct Methanol Fuel Cell Anode Catalysts (Presentation)

    SciTech Connect (OSTI)

    Dinh, H.; Gennett, T.

    2010-06-11

    This presentation is a summary of a Novel Approach to Advanced Direct Methanol Fuel Cell Anode Catalysts.

  15. Developing A New High Capacity Anode With Long Cycle Life | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy A New High Capacity Anode With Long Cycle Life Developing A New High Capacity Anode With Long Cycle Life 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon es020_amine_2012_o.pdf More Documents & Publications Developing High Capacity, Long Life Anodes Developing High Capacity, Long Life Anodes FY 2011 Annual Progress Report for Energy Storage R&D

  16. Developing a new high capacity anode with long life | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    a new high capacity anode with long life Developing a new high capacity anode with long life 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon esp_11_amine.pdf More Documents & Publications Developing High Capacity, Long Life, and High Power Anodes New High Power Li2MTi6O14Anode Material Cathodes

  17. Development of Si-based High Capacity Anodes | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Si-based High Capacity Anodes Development of Si-based High Capacity Anodes 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon es144_zhang_2012_p.pdf More Documents & Publications Synthesis and Characterization of Structured Si-Carbon Nanocomposite Anodes and Functional Polymer Binders Development of Si-based High Capacity Anodes Vehicle Technologies Office Merit Review 2014: Synthesis and Characterization of

  18. A deep earthquake goes supershear

    SciTech Connect (OSTI)

    Wilson, R. Mark

    2014-09-01

    Seismic analysis of an aftershock off Russias Kamchatka Peninsula offers evidence that deep earthquakes are more complicated than geoscientists realized.

  19. Deep Vadose Zone Field Activities

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    HANFORD ADVISORY BOARD, RAP March 6, 2013 Presented by: John Morse DEEP VADOSE ZONE ACTIVITIES Page 2 Deep Vadose Zone Areas Page 3 Deep Vadose Zone Field Activities FY 2014 Fieldwork Began in 2011 Page 4 Deep Vadose Zone Field Activities, Continued Page 5 0 20,000 40,000 60,000 80,000 100,000 120,000 0 500 1,000 1,500 2,000 2,500 3,000 Cumulative Gallons Removed Weekly Gallons Removed Perched Water Removal Shut down to address increased contamination levels and replace submersible pump Page 6 0

  20. Method of deep drilling

    DOE Patents [OSTI]

    Colgate, Stirling A. (4616 Ridgeway, Los Alamos, NM 87544)

    1984-01-01

    Deep drilling is facilitated by the following steps practiced separately or in any combination: (1) Periodically and sequentially fracturing zones adjacent the bottom of the bore hole with a thixotropic fastsetting fluid that is accepted into the fracture to overstress the zone, such fracturing and injection being periodic as a function of the progression of the drill. (2) Casing the bore hole with ductile, pre-annealed casing sections, each of which is run down through the previously set casing and swaged in situ to a diameter large enough to allow the next section to run down through it. (3) Drilling the bore hole using a drill string of a low density alloy and a high density drilling mud so that the drill string is partially floated.

  1. Pd/Ni-WO3 anodic double layer gasochromic device

    DOE Patents [OSTI]

    Lee, Se-Hee; Tracy, C. Edwin; Pitts, J. Roland; Liu, Ping

    2004-04-20

    An anodic double layer gasochromic sensor structure for optical detection of hydrogen in improved response time and with improved optical absorption real time constants, comprising: a glass substrate; a tungsten-doped nickel oxide layer coated on the glass substrate; and a palladium layer coated on the tungsten-doped nickel oxide layer.

  2. High Rate and Stable Cycling of Lithium Metal Anode

    SciTech Connect (OSTI)

    Qian, Jiangfeng; Henderson, Wesley A.; Xu, Wu; Bhattacharya, Priyanka; Engelhard, Mark H.; Borodin, Oleg; Zhang, Jiguang

    2015-02-20

    Lithium (Li) metal is an ideal anode material for rechargeable batteries. However, dendritic Li growth and limited Coulombic efficiency (CE) during repeated Li deposition/stripping processes have prevented the application of this anode in rechargeable Li metal batteries, especially for use at high current densities. Herein, we report that the use of highly concentrated electrolytes composed of ether solvents and the lithium bis(fluorosulfonyl)imide (LiFSI) salt enables the high rate cycling of a Li metal anode at high CE (up to 99.1 %) without dendrite growth. With 4 M LiFSI in 1,2-dimethoxyethane (DME) as the electrolyte, a Li|Li cell can be cycled at high rates (10 mA cm-2) for more than 6000 cycles with no increase in the cell impedance, and a Cu|Li cell can be cycled at 4 mA cm-2 for more than 1000 cycles with an average CE of 98.4%. These excellent high rate performances can be attributed to the increased solvent coordination and increased availability of Li+ concentration in the electrolyte. Further development of this electrolyte may lead to practical applications for Li metal anode in rechargeable batteries. The fundamental mechanisms behind the high rate ion exchange and stability of the electrolytes also shine light on the stability of other electrochemical systems.

  3. Sulfur tolerant molten carbonate fuel cell anode and process

    DOE Patents [OSTI]

    Remick, Robert J. (Naperville, IL)

    1990-01-01

    Molten carbonate fuel cell anodes incorporating a sulfur tolerant carbon monoxide to hydrogen water-gas-shift catalyst provide in situ conversion of carbon monoxide to hydrogen for improved fuel cell operation using fuel gas mixtures of over about 10 volume percent carbon monoxide and up to about 10 ppm hydrogen sulfide.

  4. New High-Energy Nanofiber Anode Materials | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon es010_zhang_2011_p.pdf More Documents & Publications New High-Energy Nanofiber Anode Materials FY 2011 Annual Progress Report for Energy Storage R&D FY 2012 Annual Progress Report for Energy Storage R&D

  5. Synthesis and characterization of anodized titanium-oxide nanotube arrays

    SciTech Connect (OSTI)

    Hu, Michael Z.; Lai, Peng; Bhuiyan, Md S; Tsouris, Costas; Gu, Baohua; Paranthaman, Mariappan Parans; Gabitto, Jorge; Harrison, L. D.

    2009-01-01

    Anodized titanium-oxide containing highly ordered, vertically oriented TiO2 nanotube arrays is a nanomaterial architecture that shows promise for diverse applications. In this paper, an anodization synthesis using HF-free aqueous solution is described. The anodized TiO2 film samples (amorphous, anatase, and rutile) on titanium foils were characterized with scanning electron microscopy, X-ray diffraction, and Raman spectroscopy. Additional characterization in terms of photocurrent generated by an anode consisting of a titanium foil coated by TiO2 nanotubes was performed using an electrochemical cell. A platinum cathode was used in the electrochemical cell. Results were analyzed in terms of the efficiency of the current generated, defined as the ratio of the difference between the electrical energy output and the electrical energy input divided by the input radiation energy, with the goal of determining which phase of TiO2 nanotubes leads to more efficient hydrogen production. It was determined that the anatase crystalline structure converts light into current more efficiently and is therefore a better photocatalytic material for hydrogen production via photoelectrochemical splitting of water.

  6. Protection of Li Anodes Using Dual Phase Electrolytes | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy 1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon es012_mikhaylik_2011_p.pdf More Documents & Publications Protection of Li Anodes Using Dual Phase Electrolytes Progress of DOE Materials, Manufacturing Process R&D, and ARRA Battery Manufacturing Grants FY 2011 Annual Prog

  7. Protection of Li Anodes Using Dual Phase Electrolytes | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy 0 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon es012_mikhaylik_2010_o.pdf More Documents & Publications Protection of Li Anodes Using Dual Phase Electrolytes Progress of DOE Materials, Manufacturing Process R&D, and ARRA Battery Manufacturing Grant

  8. Anode Materials for Rechargeable Li-Ion Batteries

    SciTech Connect (OSTI)

    Fultz, B.

    2001-01-12

    This research is on materials for anodes and cathodes in electrochemical cells. The work is a mix of electrochemical measurements and analysis of the materials by transmission electron microscopy and x-ray diffractometry. At present, our experimental work involves only materials for Li storage, but we have been writing papers from our previous work on hydrogen-storage materials.

  9. Aerogel and xerogel composites for use as carbon anodes

    DOE Patents [OSTI]

    Cooper, John F. (Oakland, CA); Tillotson, Thomas M. (Tracy, CA); Hrubesh, Lawrence W. (Pleasanton, CA)

    2008-08-12

    Disclosed herein are aerogel and xerogel composite materials suitable for use as anodes in fuel cells and batteries. Precursors to the aerogel and xerogel compounds are infused with inorganic polymeric materials or carbon particles and then gelled. The gels are then pyrolyzed to form composites with internal structural support.

  10. Structural micro-porous carbon anode for rechargeable lithium-ion batteries

    DOE Patents [OSTI]

    Delnick, F.M.; Even, W.R. Jr.; Sylwester, A.P.; Wang, J.C.F.; Zifer, T.

    1995-06-20

    A secondary battery having a rechargeable lithium-containing anode, a cathode and a separator positioned between the cathode and anode with an organic electrolyte solution absorbed therein is provided. The anode comprises three-dimensional microporous carbon structures synthesized from polymeric high internal phase emulsions or materials derived from this emulsion source, i.e., granules, powders, etc. 6 figs.

  11. Structural micro-porous carbon anode for rechargeable lithium-ion batteries

    DOE Patents [OSTI]

    Delnick, Frank M. (Albuquerque, NM); Even, Jr., William R. (Livermore, CA); Sylwester, Alan P. (Washington, DC); Wang, James C. F. (Livermore, CA); Zifer, Thomas (Manteca, CA)

    1995-01-01

    A secondary battery having a rechargeable lithium-containing anode, a cathode and a separator positioned between the cathode and anode with an organic electrolyte solution absorbed therein is provided. The anode comprises three-dimensional microporous carbon structures synthesized from polymeric high internal phase emulsions or materials derived from this emulsion source, i.e., granules, powders, etc.

  12. Reduced temperature aluminum production in an electrolytic cell having an inert anode

    DOE Patents [OSTI]

    Dawless, Robert K. (Monroeville, PA); Ray, Siba P. (Murrysville, PA); Hosler, Robert B. (Sarver, PA); Kozarek, Robert L. (Apollo, PA); LaCamera, Alfred F. (Trafford, PA)

    2000-01-01

    Aluminum is produced by electrolytic reduction of alumina in a cell having a cathode, an inert anode and a molten salt bath containing metal fluorides and alumina. The inert anode preferably contains copper, silver and oxides of iron and nickel. Reducing the molten salt bath temperature to about 900-950.degree. C. lowers corrosion on the inert anode constituents.

  13. Optimization and Domestic Sourcing of Lithium Ion Battery Anode Materials

    SciTech Connect (OSTI)

    Wood, III, D. L.; Yoon, S.

    2012-10-25

    The purpose of this Cooperative Research and Development Agreement (CRADA) between ORNL and A123Systems, Inc. was to develop a low-temperature heat treatment process for natural graphite based anode materials for high-capacity and long-cycle-life lithium ion batteries. Three major problems currently plague state-of-the-art lithium ion battery anode materials. The first is the cost of the artificial graphite, which is heat-treated well in excess of 2000C. Because of this high-temperature heat treatment, the anode active material significantly contributes to the cost of a lithium ion battery. The second problem is the limited specific capacity of state-of-the-art anodes based on artificial graphites, which is only about 200-350 mAh/g. This value needs to be increased to achieve high energy density when used with the low cell-voltage nanoparticle LiFePO4 cathode. Thirdly, the rate capability under cycling conditions of natural graphite based materials must be improved to match that of the nanoparticle LiFePO4. Natural graphite materials contain inherent crystallinity and lithium intercalation activity. They hold particular appeal, as they offer huge potential for industrial energy savings with the energy costs essentially subsidized by geological processes. Natural graphites have been heat-treated to a substantially lower temperature (as low as 1000-1500C) and used as anode active materials to address the problems described above. Finally, corresponding graphitization and post-treatment processes were developed that are amenable to scaling to automotive quantities.

  14. Development of High Capacity Anode for Li-ion Batteries | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy High Capacity Anode for Li-ion Batteries Development of High Capacity Anode for Li-ion Batteries 2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon es065_zhang_2010_p.pdf More Documents & Publications Novel Lithium Ion Anode Structures: Overview of New DOE BATT Anode Projects Hybrid Nano Carbon Fiber/Graphene Platelet-Based High-Capacity Anodes for Lithium Ion Batteries Hybrid Nano Carbon

  15. Battery Anodes > Batteries & Fuel Cells > Research > The Energy Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Center at Cornell Anodes Introduction The anode is the negative electrode of a primary cell and is always associated with the oxidation or the release of electrons into the external circuit. In a rechargeable cell, the anode is the negative pole during discharge and the positive pole during charge. Lithium Anode The anode in the battery deserves an equal say in the overall performance of a battery. For an effective development of a high energy density battery, the use of high capacity

  16. Modular anode assemblies and methods of using the same for electrochemical reduction

    DOE Patents [OSTI]

    Wiedmeyer, Stanley G; Barnes, Laurel A; Williamson, Mark A; Willit, James L

    2015-02-17

    Modular anode assemblies are used in electrolytic oxide reduction systems for scalable reduced metal production via electrolysis. Assemblies include a channel frame connected to several anode rods extending into an electrolyte. An electrical system powers the rods while being insulated from the channel frame. A cooling system removes heat from anode rods and the electrical system. An anode guard attaches to the channel frame to prevent accidental electrocution or damage during handling or repositioning. Each anode rod may be divided into upper and lower sections to permit easy repair and swapping out of lower sections. The modular assemblies may have standardized components to permit placement at multiple points within a reducing system. Example methods may operate an electrolytic oxide reduction system by positioning the modular anode assemblies in the reduction system and applying electrical power to the plurality of anode assemblies.

  17. Deep Sludge Gas Release Event Analytical Evaluation

    SciTech Connect (OSTI)

    Sams, Terry L.

    2013-08-15

    Long Abstract. Full Text. The purpose of the Deep Sludge Gas Release Event Analytical Evaluation (DSGRE-AE) is to evaluate the postulated hypothesis that a hydrogen GRE may occur in Hanford tanks containing waste sludges at levels greater than previously experienced. There is a need to understand gas retention and release hazards in sludge beds which are 200 -300 inches deep. These sludge beds are deeper than historical Hanford sludge waste beds, and are created when waste is retrieved from older single-shell tanks (SST) and transferred to newer double-shell tanks (DST).Retrieval of waste from SSTs reduces the risk to the environment from leakage or potential leakage of waste into the ground from these tanks. However, the possibility of an energetic event (flammable gas accident) in the retrieval receiver DST is worse than slow leakage. Lines of inquiry, therefore, are (1) can sludge waste be stored safely in deep beds; (2) can gas release events (GRE) be prevented by periodically degassing the sludge (e.g., mixer pump); or (3) does the retrieval strategy need to be altered to limit sludge bed height by retrieving into additional DSTs? The scope of this effort is to provide expert advice on whether or not to move forward with the generation of deep beds of sludge through retrieval of C-Farm tanks. Evaluation of possible mitigation methods (e.g., using mixer pumps to release gas, retrieving into an additional DST) are being evaluated by a second team and are not discussed in this report. While available data and engineering judgment indicate that increased gas retention (retained gas fraction) in DST sludge at depths resulting from the completion of SST 241-C Tank Farm retrievals is not expected and, even if gas releases were to occur, they would be small and local, a positive USQ was declared (Occurrence Report EM-RP--WRPS-TANKFARM-2012-0014, "Potential Exists for a Large Spontaneous Gas Release Event in Deep Settled Waste Sludge"). The purpose of this technical report is to (1) present and discuss current understandings of gas retention and release mechanisms for deep sludge in U.S. Department of Energy (DOE) complex waste storage tanks; and (2) to identify viable methods/criteria for demonstrating safety relative to deep sludge gas release events (DSGRE) in the near term to support the Hanford C-Farm retrieval mission. A secondary purpose is to identify viable methods/criteria for demonstrating safety relative to DSGREs in the longer term to support the mission to retrieve waste from the Hanford Tank Farms and deliver it to the Waste Treatment and Immobilization Plant (WTP). The potential DSGRE issue resulted in the declaration of a positive Unreviewed Safety Question (USQ). C-Farm retrievals are currently proceeding under a Justification for Continued Operation (JCO) that only allows tanks 241-AN-101 and 241-AN-106 sludge levels of 192 inches and 195 inches, respectively. C-Farm retrievals need deeper sludge levels (approximately 310 inches in 241-AN-101 and approximately 250 inches in 241-AN-106). This effort is to provide analytical data and justification to continue retrievals in a safe and efficient manner.

  18. Electrocatalyst for alcohol oxidation at fuel cell anodes

    DOE Patents [OSTI]

    Adzic, Radoslav (East Setauket, NY); Kowal, Andrzej (Cracow, PL)

    2011-11-02

    In some embodiments a ternary electrocatalyst is provided. The electrocatalyst can be used in an anode for oxidizing alcohol in a fuel cell. In some embodiments, the ternary electrocatalyst may include a noble metal particle having a surface decorated with clusters of SnO.sub.2 and Rh. The noble metal particles may include platinum, palladium, ruthenium, iridium, gold, and combinations thereof. In some embodiments, the ternary electrocatalyst includes SnO.sub.2 particles having a surface decorated with clusters of a noble metal and Rh. Some ternary electrocatalysts include noble metal particles with clusters of SnO.sub.2 and Rh at their surfaces. In some embodiments the electrocatalyst particle cores are nanoparticles. Some embodiments of the invention provide a fuel cell including an anode incorporating the ternary electrocatalyst. In some aspects a method of using ternary electrocatalysts of Pt, Rh, and SnO.sub.2 to oxidize an alcohol in a fuel cell is described.

  19. New High-Energy Nanofiber Anode Materials | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    0 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon es010_zhang_2010_o.pdf More Documents & Publications New High-Energy Nanofiber Anode Materials FY 2011 Annual Progress Report for Energy Storage R&D Vehicle Technologies Office: 2010 Energy Storage R&D Annual Progress Report

  20. Electrocatalyst for Alcohol Oxidation at Fuel Cell Anodes - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovation Portal Alcohol Oxidation at Fuel Cell Anodes Brookhaven National Laboratory Contact BNL About This Technology Publications: PDF Document Publication Ternary Pt/Rh/SnO2 electrocatalysts for oxidizing ethanol to CO2 (2,641 KB) <p> Scanning transmission electron micrograph showing uniform dispersion of the catalyst particles (bright spots) on the carbon support (dark background). The average particle size is about 1.5&nbsp;nm.</p> Scanning transmission electron

  1. Nanotube composite anode materials improve lithium-ion battery performance

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (ANL-09-034) - Energy Innovation Portal Vehicles and Fuels Vehicles and Fuels Energy Storage Energy Storage Find More Like This Return to Search Nanotube composite anode materials improve lithium-ion battery performance (ANL-09-034) Argonne National Laboratory Contact ANL About This Technology Technology Marketing Summary Rechargeable lithium-ion batteries are a critical technology for many applications, including consumer electronics and electric vehicles. As the demand for hybrid and

  2. Longer Life Lithium Ion Batteries with Silicon Anodes - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Portal Longer Life Lithium Ion Batteries with Silicon Anodes Lawrence Berkeley National Laboratory Contact LBL About This Technology Technology Marketing Summary Researchers have developed a new technology to advance the life of lithium-ion batteries. A catechol-based polymer binder, developed at Berkeley Lab, interacting with the oxide layer on the surface of commercial silicon (Si), generates powerful adhesion strength and maintains electrode integrity during the drastic volume changes

  3. Innovative lithium-titanium-oxide anodes improve battery safety and

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    performance (IN-98-069) - Energy Innovation Portal Energy Storage Energy Storage Advanced Materials Advanced Materials Find More Like This Return to Search Innovative lithium-titanium-oxide anodes improve battery safety and performance (IN-98-069) Argonne National Laboratory Contact ANL About This Technology Two orders of magnitude conductivity enhancement in Li4Ti5O12 with magnesium doping with no change in capacity or insertion potential.<br /> Two orders of magnitude conductivity

  4. Silicon Nanowire Anodes for Next Generation Energy Storage

    Energy Savers [EERE]

    Silicon Nanowire Anodes for Next Generation Energy Storage Ionel C. Stefan, Principal Investigator Yoni Cohen, Program Manager Amprius, Inc. June 16-20, 2014 ES126 This presentation does not contain any proprietary, confidential, or otherwise restricted information 2 * Start date: October 2011 * End date: September 2014 * Percent complete: 85% * Performance - Energy Density - Specific Energy - Power * Life - Cycle life - Shelf life * Total project funding: $8,215,077 - DOE share: $4,998,336 -

  5. Inward Lithium-Ion Breathing of Hierarchically Porous Silicon Anodes

    SciTech Connect (OSTI)

    Xiao, Qiangfeng; Gu, Meng; Yang, Hui; Li, Bing; Zhang, Cunman; Liu, Yang; Liu, Fang; Dai, Fang; Yang, Li; Liu, Zhongyi; Xiao, Xingcheng; Liu, Gao; Zhao, Peng; Zhang, Sulin; Wang, Chong M.; Lu, Yunfeng; Cai, Mei

    2015-11-05

    Silicon has been identified as one of the most promising candidates as anode for high performance lithium-ion batteries. The key challenge for Si anodes is the large volume change induced chemomechanical fracture and subsequent rapid capacity fading upon cyclic charge and discharge. Improving capacity retention thus critically relies on smart accommodation of the volume changes through nanoscale structural design. In this work, we report a novel fabrication method for hierarchically porous Si nanospheres (hp-SiNSs), which consist of a porous shell and a hollow core. Upon charge/discharge cycling, the hp-SiNSs accommodate the volume change through reversible inward expansion/contraction with negligible particle-level outward expansion. Our mechanics analysis revealed that such a unique volume-change accommodation mechanism is enabled by the much stiffer modulus of the lithiated layer than the unlithiated porous layer and the low flow stress of the porous structure. Such inward expansion shields the hp-SiNSs from fracture, opposite to the outward expansion in solid Si during lithiation. Lithium ion battery assembled with this new nanoporous material exhibits high capacity, high power, long cycle life and high coulombic efficiency, which is superior to the current commercial Si-based anode materials. The low cost synthesis approach reported here provides a new avenue for the rational design of hierarchically porous structures with unique materials properties.

  6. Thermal Neutron Detectors with Discrete Anode Pad Readout

    SciTech Connect (OSTI)

    Yu,B.; Schaknowski, N.A., Smith, G.C., DeGeronimo, G., Vernon, E.O.

    2008-10-19

    A new two-dimensional thermal neutron detector concept that is capable of very high rates is being developed. It is based on neutron conversion in {sup 3}He in an ionization chamber (unity gas gain) that uses only a cathode and anode plane; there is no additional electrode such as a Frisch grid. The cathode is simply the entrance window, and the anode plane is composed of discrete pads, each with their own readout electronics implemented via application specific integrated circuits. The aim is to provide a new generation of detectors with key characteristics that are superior to existing techniques, such as higher count rate capability, better stability, lower sensitivity to background radiation, and more flexible geometries. Such capabilities will improve the performance of neutron scattering instruments at major neutron user facilities. In this paper, we report on progress with the development of a prototype device that has 48 x 48 anode pads and a sensitive area of 24cm x 24cm.

  7. Position-sensitive proportional counter with low-resistance metal-wire anode

    DOE Patents [OSTI]

    Kopp, Manfred K. (Oak Ridge, TN)

    1980-01-01

    A position-sensitive proportional counter circuit is provided which allows the use of a conventional (low-resistance, metal-wire anode) proportional counter for spatial resolution of an ionizing event along the anode of the counter. A pair of specially designed active-capacitance preamplifiers are used to terminate the anode ends wherein the anode is treated as an RC line. The preamplifiers act as stabilized active capacitance loads and each is composed of a series-feedback, low-noise amplifier, a unity-gain, shunt-feedback amplifier whose output is connected through a feedback capacitor to the series-feedback amplifier input. The stabilized capacitance loading of the anode allows distributed RC-line position encoding and subsequent time difference decoding by sensing the difference in rise times of pulses at the anode ends where the difference is primarily in response to the distributed capacitance along the anode. This allows the use of lower resistance wire anodes for spatial radiation detection which simplifies the counter construction and handling of the anodes, and stabilizes the anode resistivity at high count rates (>10.sup.6 counts/sec).

  8. FORT UNION DEEP

    SciTech Connect (OSTI)

    Lyle A. Johnson Jr.

    2002-03-01

    Coalbed methane (CBM) is currently the hottest area of energy development in the Rocky Mountain area. The Powder River Basin (PRB) is the largest CBM area in Wyoming and has attracted the majority of the attention because of its high permeability and relatively shallow depth. Other Wyoming coal regions are also being targeted for development, but most of these areas have lower permeability and deeper coal seams. This project consists of the development of a CBM stimulation system for deep coal resources and involves three work areas: (1) Well Placement, (2) Well Stimulation, and (3) Production Monitoring and Evaluation. The focus of this project is the Washakie Basin. Timberline Energy, Inc., the cosponsor, has a project area in southern Carbon County, Wyoming, and northern Moffat County, Colorado. The target coal is found near the top of the lower Fort Union formation. The well for this project, Evans No.1, was drilled to a depth of 2,700 ft. Three coal seams were encountered with sandstone and some interbedded shale between seams. Well logs indicated that the coal seams and the sandstone contained gas. For the testing, the upper seam at 2,000 ft was selected. The well, drilled and completed for this project, produced very little water and only occasional burps of methane. To enhance the well, a mild severity fracture was conducted to fracture the coal seam and not the adjacent sandstone. Fracturing data indicated a fracture half-length of 34 ft, a coal permeability of 0.2226 md, and permeability of 15.3 md. Following fracturing, the gas production rate stabilized at 10 Mscf/day within water production of 18 bpd. The Western Research Institute (WRI) CBM model was used to design a 14-day stimulation cycle followed by a 30-day production period. A maximum injection pressure of 1,200 psig to remain well below the fracture pressure was selected. Model predictions were 20 Mscf/day of air injection for 14 days, a one-day shut-in, then flowback. The predicted flowback was a four-fold increase over the prestimulation rate with production essentially returning to prestimulation rates after 30 days. The physical stimulation was conducted over a 14-day period. Problems with the stimulation injection resulted in a coal bed fire that was quickly quenched when production was resumed. The poststimulation, stabilized production was three to four times the prestimulation rate. The methane content was approximately 45% after one day and increased to 65% at the end of 30 days. The gas production rate was still two and one-half times the prestimulation rate at the end of the 30-day test period. The field results were a good match to the numerical simulator predictions. The physical stimulation did increase the production, but did not produce a commercial rate.

  9. FORT UNION DEEP

    SciTech Connect (OSTI)

    Lyle A. Johnson Jr.

    2002-09-01

    Coalbed methane (CBM) is currently the hottest area of energy development in the Rocky Mountain area. The Powder River Basin (PRB) is the largest CBM area in Wyoming and has attracted the majority of the attention because of its high permeability and relatively shallow depth. Other Wyoming coal regions are also being targeted for development, but most of these areas have lower permeability and deeper coal seams. This project consists of the development of a CBM stimulation system for deep coal resources and involves three work areas: (1) Well Placement, (2) Well Stimulation, and (3) Production Monitoring and Evaluation. The focus of this project is the Washakie Basin. Timberline Energy, Inc., the cosponsor, has a project area in southern Carbon County, Wyoming, and northern Moffat County, Colorado. The target coal is found near the top of the lower Fort Union formation. The well for this project, Evans No.1, was drilled to a depth of 2,700 ft. Three coal seams were encountered with sandstone and some interbedded shale between seams. Well logs indicated that the coal seams and the sandstone contained gas. For the testing, the upper seam at 2,000 ft was selected. The well, drilled and completed for this project, produced very little water and only occasional burps of methane. To enhance the well, a mild severity fracture was conducted to fracture the coal seam and not the adjacent sandstone. Fracturing data indicated a fracture half-length of 34 ft, a coal permeability of 0.2226 md, and permeability of 15.3 md. Following fracturing, the gas production rate stabilized at 10 Mscf/day within water production of 18 bpd. The Western Research Institute (WRI) CBM model was used to design a 14-day stimulation cycle followed by a 30-day production period. A maximum injection pressure of 1,200 psig to remain well below the fracture pressure was selected. Model predictions were 20 Mscf/day of air injection for 14 days, a one-day shut-in, then flowback. The predicted flowback was a four-fold increase over the prestimulation rate with production essentially returning to prestimulation rates after 30 days. The physical stimulation was conducted over a 14-day period. Problems with the stimulation injection resulted in a coal bed fire that was quickly quenched when production was resumed. The poststimulation, stabilized production was three to four times the prestimulation rate. The methane content was approximately 45% after one day and increased to 65% at the end of 30 days. The gas production rate was still two and one-half times the prestimulation rate at the end of the 30-day test period. The field results were a good match to the numerical simulator predictions. The physical stimulation did increase the production, but did not produce a commercial rate.

  10. Cu--Ni--Fe anode for use in aluminum producing electrolytic cell

    DOE Patents [OSTI]

    Bergsma, S. Craig; Brown, Craig W.; Bradford, Donald R; Barnett, Robert J.; Mezner, Michael B.

    2006-07-18

    A method of producing aluminum in an electrolytic cell containing alumina dissolved in an electrolyte, the method comprising the steps of providing a molten salt electrolyte at a temperature of less than 900.degree. C. having alumina dissolved therein in an electrolytic cell having a liner for containing the electrolyte, the liner having a bottom and walls extending upwardly from said bottom. A plurality of non-consumable Cu--Ni--Fe anodes and cathodes are disposed in a vertical direction in the electrolyte, the cathodes having a plate configuration and the anodes having a flat configuration to compliment the cathodes. The anodes contain apertures therethrough to permit flow of electrolyte through the apertures to provide alumina-enriched electrolyte between the anodes and the cathodes. Electrical current is passed through the anodes and through the electrolyte to the cathodes, depositing aluminum at the cathodes and producing gas at the anodes.

  11. Electrochemical aging of humectant-treated thermal-sprayed zinc anodes for cathodic protection

    SciTech Connect (OSTI)

    Covino, B.S. Jr.; Holcomb, G.R.; Bullard, S.J.; Russell, J.H.; Cramer, S.D.; Bennett, J.E.; Laylor, H.M.

    1999-07-01

    Humectants, substances that promote the retention of moisture, were studied to determine their effectiveness in improving the performance and extending the service life of both new and previously-aged thermal-sprayed Zn anodes used in impressed current (ICCP) and galvanic cathodic protection (GCP) systems for steel-reinforced concrete structures. Potassium acetate, lithium nitrate, and lithium bromide were applied to a series of thermal-sprayed Zn-coated concrete slabs before starting the ICCP or GCP experiment. All of the humectants altered the behavior of the thermal-sprayed Zn anodes. LiNO{sub 3} was the most beneficial for ICCP anodes and LiBr was the most beneficial for GCP anodes. Circuit resistances for ICCP anodes and galvanic current density for GCP anodes are compared on the basis of electrochemical aging, humidity, and type of humectant.

  12. Exciton quenching at PEDOT:PSS anode in polymer blue-light-emitting diodes

    SciTech Connect (OSTI)

    Abbaszadeh, D.; Wetzelaer, G. A. H.; Nicolai, H. T.

    2014-12-14

    The quenching of excitons at the poly(3,4-ethylenedioxythiophene):poly(styrenesulfonic acid) (PEDOT:PSS) anode in blue polyalkoxyspirobifluorene-arylamine polymer light-emitting diodes is investigated. Due to the combination of a higher electron mobility and the presence of electron traps, the recombination zone shifts from the cathode to the anode with increasing voltage. The exciton quenching at the anode at higher voltages leads to an efficiency roll-off. The voltage dependence of the luminous efficiency is reproduced by a drift-diffusion model under the condition that quenching of excitons at the PEDOT:PSS anode and metallic cathode is of equal strength. Experimentally, the efficiency roll-off at high voltages due to anode quenching is eliminated by the use of an electron-blocking layer between the anode and the light-emitting polymer.

  13. Analysis of Cadmium in Undissolved Anode Materials of Mark-IV Electrorefiner

    SciTech Connect (OSTI)

    Tae-Sic Yoo; Guy L. Fredrickson; DeeEarl Vaden; Brian R. Westphal

    2013-10-01

    The Mark-IV electrorefiner (Mk-IV ER) contains an electrolyte/molten cadmium system for refining uranium electrochemically. Typically, the anode of the Mk-IV ER consists of the chopped sodium-bonded metallic driver fuels, which have been primarily U-10Zr binary fuels. Chemical analysis of the residual anode materials after electrorefining indicates that a small amount of cadmium is removed from the Mk-IV ER along with the undissolved anode materials. Investigation of chemical analysis data indicates that the amount of cadmium in the undissolved anode materials is strongly correlated with the anode rotation speeds and the residence time of the anode in the Mk-IV ER. Discussions are given to explain the prescribed correlation.

  14. New High Power Li2MTi6O14Anode Material | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High Power Li2MTi6O14Anode Material New High Power Li2MTi6O14Anode Material 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon esp_21_amine.pdf More Documents & Publications Developing High Capacity, Long Life, and High Power Anodes Cathodes Engineering of high energy cathode material

  15. Self-assembled Ni/TiO{sub 2} nanocomposite anodes synthesized via

    Office of Scientific and Technical Information (OSTI)

    electroless plating and atomic layer deposition on biological scaffolds (Journal Article) | SciTech Connect Self-assembled Ni/TiO{sub 2} nanocomposite anodes synthesized via electroless plating and atomic layer deposition on biological scaffolds Citation Details In-Document Search Title: Self-assembled Ni/TiO{sub 2} nanocomposite anodes synthesized via electroless plating and atomic layer deposition on biological scaffolds Ni(core)/TiO{sub 2}(shell) nanocomposite anodes were fabricated on

  16. Method to Reduce Camber in Anode-Supported SOFCs - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Vehicles and Fuels Vehicles and Fuels Energy Storage Energy Storage Advanced Materials Advanced Materials Find More Like This Return to Search Method to Reduce Camber in Anode-Supported SOFCs Pacific Northwest National Laboratory Contact PNNL About This Technology A) Typical camber developed in 7 cm x 7 cm anode-supported SOFC. B) Details on matched TEC backing layer opposite electrolyte surface for camber control (Invention 13536). A) Typical camber developed in 7 cm x 7 cm anode-supported

  17. Cell Analysis … High-Energy Density Cathodes and Anodes | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Cell Analysis … High-Energy Density Cathodes and Anodes Cell Analysis … High-Energy Density Cathodes and Anodes 2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon es053_richardson_2010_p.pdf More Documents & Publications First Principles Calculations of Electrode Materials Vehicle Technologies Office Merit Review 2015: A Commercially Scalable Process for Silicon Anode Prelithiation

  18. Process and apparatus for recovery of fissionable materials from spent reactor fuel by anodic dissolution

    DOE Patents [OSTI]

    Tomczuk, Zygmunt (Orland Park, IL); Miller, William E. (Naperville, IL); Wolson, Raymond D. (Lockport, IL); Gay, Eddie C. (Park Forest, IL)

    1991-01-01

    An electrochemical process and apparatus for the recovery of uranium and plutonium from spent metal clad fuel pins is disclosed. The process uses secondary reactions between U.sup.+4 cations and elemental uranium at the anode to increase reaction rates and improve anodic efficiency compared to prior art processes. In another embodiment of the process, secondary reactions between Cd.sup.+2 cations and elemental uranium to form uranium cations and elemental cadmium also assists in oxidizing the uranium at the anode.

  19. Grounded Renewable Energy | Open Energy Information

    Open Energy Info (EERE)

    Grounded Renewable Energy Jump to: navigation, search Name: Grounded Renewable Energy Place: Carbondale, Colorado Zip: 81623 Sector: Renewable Energy, Solar Product: Grounded...

  20. Category:Ground Magnetics | Open Energy Information

    Open Energy Info (EERE)

    Ground Magnetics Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Geothermalpower.jpg Looking for the Ground Magnetics page? For detailed information on Ground...

  1. Chemical Bonding In Amorphous Si Coated-carbon Nanotube As Anodes...

    Office of Scientific and Technical Information (OSTI)

    Title: Chemical Bonding In Amorphous Si Coated-carbon Nanotube As Anodes For Li ion Batteries: A XANES Study The chemical bonding nature and its evolution upon electrochemical ...

  2. Self-assembled Ni/TiO{sub 2} nanocomposite anodes synthesized...

    Office of Scientific and Technical Information (OSTI)

    Ni(core)TiOsub 2(shell) nanocomposite anodes were fabricated on three-dimensional, self-assembled nanotemplates of Tobacco mosaic virus using atomic layer deposition, exhibiting ...

  3. Anodization control for barrier-oxide thinning and 3D interconnected...

    Office of Scientific and Technical Information (OSTI)

    Anodization control for barrier-oxide thinning and 3D interconnected pores and direct electrodeposition of nanowire networks on native aluminium substrates Citation Details...

  4. Buried anode lithium thin film battery and process for forming the same

    DOE Patents [OSTI]

    Lee, Se-Hee; Tracy, C. Edwin; Liu, Ping

    2004-10-19

    A reverse configuration, lithium thin film battery (300) having a buried lithium anode layer (305) and process for making the same. The present invention is formed from a precursor composite structure (200) made by depositing electrolyte layer (204) onto substrate (201), followed by sequential depositions of cathode layer (203) and current collector (202) on the electrolyte layer. The precursor is subjected to an activation step, wherein a buried lithium anode layer (305) is formed via electroplating a lithium anode layer at the interface of substrate (201) and electrolyte film (204). The electroplating is accomplished by applying a current between anode current collector (201) and cathode current collector (202).

  5. Deep Vadose Zone | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Deep Vadose Zone Deep Vadose Zone The Mission of the Deep Vadose Zone Applied Field Research Initiative is to protect water resources across the DOE complex over the long-term by developing effective solutions to solve DOE's most challenging deep vadose zone characterization, remediation, monitoring, and prediction challenges. PDF icon Deep Vadose Zone More Documents & Publications Remediation of Mercury and Industrial Contaminants Hanford Site C Tank Farm Meeting Summary - May 2010 Advanced

  6. Ground potential rise monitor

    DOE Patents [OSTI]

    Allen, Zachery W. (Mandan, ND); Zevenbergen, Gary A. (Arvada, CO)

    2012-04-03

    A device and method for detecting ground potential rise (GPR) comprising positioning a first electrode and a second electrode at a distance from each other into the earth. The voltage of the first electrode and second electrode is attenuated by an attenuation factor creating an attenuated voltage. The true RMS voltage of the attenuated voltage is determined creating an attenuated true RMS voltage. The attenuated true RMS voltage is then multiplied by the attenuation factor creating a calculated true RMS voltage. If the calculated true RMS voltage is greater than a first predetermined voltage threshold, a first alarm is enabled at a local location. If user input is received at a remote location acknowledging the first alarm, a first alarm acknowledgment signal is transmitted. The first alarm acknowledgment signal is then received at which time the first alarm is disabled.

  7. Structural transformation of nickel hydroxide films during anodic oxidation

    SciTech Connect (OSTI)

    Crocker, R.W.; Muller, R.H.

    1992-05-01

    The transformation of anodically formed nickel hydroxide/oxy-hydroxide electrodes has been investigated. A mechanism is proposed for the anodic oxidation reaction, in which the reaction interface between the reduced and oxidized phases of the electrode evolves in a nodular topography that leads to inefficient utilization of the active electrode material. In the proposed nodular transformation model for the anodic oxidation reaction, nickel hydroxide is oxidized to nickel oxy-hydroxide in the region near the metal substrate. Since the nickel oxy-hydroxide is considerably more conductive than the surrounding nickel hydroxide, as further oxidation occurs, nodular features grow rapidly to the film/electrolyte interface. Upon emerging at the electrolyte interface, the reaction boundary between the nickel hydroxide and oxy-hydroxide phases spreads laterally across the film/electrolyte interface, creating an overlayer of nickel oxy-hydroxide and trapping uncharged regions of nickel hydroxide within the film. The nickel oxy-hydroxide overlayer surface facilitates the oxygen evolution side reaction. Scanning tunneling microscopy of the electrode in its charged state revealed evidence of 80 {endash} 100 Angstrom nickel oxy-hydroxide nodules in the nickel hydroxide film. In situ spectroscopic ellipsometer measurements of films held at various constant potentials agree quantitatively with optical models appropriate to the nodular growth and subsequent overgrowth of the nickel oxy-hydroxide phase. A two-dimensional, numerical finite difference model was developed to simulate the current distribution along the phase boundary between the charged and uncharged material. The model was used to explore the effects of the physical parameters that govern the electrode behavior. The ratio of the conductivities of the nickel hydroxide and oxy-hydroxide phases was found to be the dominant parameter in the system.

  8. High capacity anode materials for lithium ion batteries

    DOE Patents [OSTI]

    Lopez, Herman A.; Anguchamy, Yogesh Kumar; Deng, Haixia; Han, Yongbon; Masarapu, Charan; Venkatachalam, Subramanian; Kumar, Suject

    2015-11-19

    High capacity silicon based anode active materials are described for lithium ion batteries. These materials are shown to be effective in combination with high capacity lithium rich cathode active materials. Supplemental lithium is shown to improve the cycling performance and reduce irreversible capacity loss for at least certain silicon based active materials. In particular silicon based active materials can be formed in composites with electrically conductive coatings, such as pyrolytic carbon coatings or metal coatings, and composites can also be formed with other electrically conductive carbon components, such as carbon nanofibers and carbon nanoparticles. Additional alloys with silicon are explored.

  9. Forming gas treatment of lithium ion battery anode graphite powders

    DOE Patents [OSTI]

    Contescu, Cristian Ion; Gallego, Nidia C; Howe, Jane Y; Meyer, III, Harry M; Payzant, Edward Andrew; Wood, III, David L; Yoon, Sang Young

    2014-09-16

    The invention provides a method of making a battery anode in which a quantity of graphite powder is provided. The temperature of the graphite powder is raised from a starting temperature to a first temperature between 1000 and 2000.degree. C. during a first heating period. The graphite powder is then cooled to a final temperature during a cool down period. The graphite powder is contacted with a forming gas during at least one of the first heating period and the cool down period. The forming gas includes H.sub.2 and an inert gas.

  10. Conductive polymeric cable anodes for pipelines with deteriorating coatings

    SciTech Connect (OSTI)

    Gibson, W.F.; Pikas, J.L. )

    1993-03-01

    Deteriorating pipeline coating systems have been a dilemma in the industry for many years. The interaction between coatings and cathodic protection (CP) is based on the type of coating and the amount of deterioration. There are two primary strategies to approach the problem: recoat, which is very expensive and may require taking the line out of service and cause loss of revenue; or install additional conventional CP groundbed systems. This article presents a state-of-the-art groundbed system using close-coupled conductive polymeric cable anodes that eliminate the problems of conventional groundbeds.

  11. Ni/YSZ Anode Interactions with Impurities in Coal Gas

    SciTech Connect (OSTI)

    Marina, Olga A.; Pederson, Larry R.; Coyle, Christopher A.; Thomsen, Edwin C.; Coffey, Greg W.

    2009-10-16

    Performance of solid oxide fuel cell (SOFC) with nickel/zirconia anodes on synthetic coal gas in the presence of low levels of phosphorus, arsenic, selenium, sulfur, hydrogen chloride, and antimony impurities were evaluated. The presence of phosphorus and arsenic led to the slow and irreversible SOFC degradation due to the formation of secondary phases with nickel, particularly close to the gas inlet. Phosphorus and antimony surface adsorption layers were identified as well. Hydrogen chloride and sulfur interactions with the nickel were limited to the surface adsorption only, whereas selenium exposure also led to the formation of nickel selenide for highly polarized cells.

  12. STIMULATION TECHNOLOGIES FOR DEEP WELL COMPLETIONS

    SciTech Connect (OSTI)

    Stephen Wolhart

    2003-06-01

    The Department of Energy (DOE) is sponsoring a Deep Trek Program targeted at improving the economics of drilling and completing deep gas wells. Under the DOE program, Pinnacle Technologies is conducting a project to evaluate the stimulation of deep wells. The objective of the project is to assess U.S. deep well drilling & stimulation activity, review rock mechanics & fracture growth in deep, high pressure/temperature wells and evaluate stimulation technology in several key deep plays. Phase 1 was recently completed and consisted of assessing deep gas well drilling activity (1995-2007) and an industry survey on deep gas well stimulation practices by region. Of the 29,000 oil, gas and dry holes drilled in 2002, about 300 were drilled in the deep well; 25% were dry, 50% were high temperature/high pressure completions and 25% were simply deep completions. South Texas has about 30% of these wells, Oklahoma 20%, Gulf of Mexico Shelf 15% and the Gulf Coast about 15%. The Rockies represent only 2% of deep drilling. Of the 60 operators who drill deep and HTHP wells, the top 20 drill almost 80% of the wells. Six operators drill half the U.S. deep wells. Deep drilling peaked at 425 wells in 1998 and fell to 250 in 1999. Drilling is expected to rise through 2004 after which drilling should cycle down as overall drilling declines.

  13. Aerogel and xerogel composites for use as carbon anodes

    DOE Patents [OSTI]

    Cooper, John F.; Tillotson, Thomas M.; Hrubesh, Lawrence W.

    2010-10-12

    A method for forming a reinforced rigid anode monolith and fuel and product of such method. The method includes providing a solution of organic aerogel or xerogel precursors including at least one of a phenolic resin, phenol (hydroxybenzene), resorcinol(1,3-dihydroxybenzene), or catechol(1,2-dihydroxybenzene); at least one aldehyde compound selected from the group consisting of formaldehyde, acetaldehyde, and furfuraldehyde; and an alkali carbonate or phosphoric acid catalyst; adding internal reinforcement materials comprising carbon to said precursor solution to form a precursor mixture; gelling said precursor mixture to form a composite gel; drying said composite gel; and pyrolyzing said composite gel to form a wettable aerogel/carbon composite or a wettable xerogel/carbon composite, wherein said composites comprise chars and said internal reinforcement materials, and wherein said composite is suitable for use as an anode with the chars being fuel capable of being combusted in a molten salt electrochemical fuel cell in the range from 500 C to 800 C to produce electrical energy. Additional methods and systems/compositions are also provided.

  14. Overview of SOFC Anode Interactions with Coal Gas Impurities

    SciTech Connect (OSTI)

    Marina, Olga A.; Pederson, Larry R.; Gemmen, Randall; Gerdes, Kirk; Finklea, Harry; Celik, Ismail B.

    2009-08-11

    Efficiencies greater than 50 percent (higher heating value) have been projected for solid oxide fuel cell (SOFC) systems fueled with gasified coal, even with carbon sequestration. Multiple minor and trace components are present in coal that could affect fuel cell performance, however, which vary widely depending on coal origin and type. Minor and trace components have been classified into three groups: elements with low volatility that are likely to remain in the ash, elements that will partition between solid and gas phases, and highly volatile elements that are unlikely to condense. Those in the second group are of most concern. In the following, an overview of the results of SOFC anode interactions with phosphorus, arsenic, selenium, sulfur, antimony, and hydrogen chloride as single contaminants or in combinations is discussed. Tests were performed using both anode- and electrolyte-supported cells in synthetic coal gas. The ultimate purpose of this work is to establish maximum permissible concentrations for impurities in coal gas, to aid in the selection of appropriate coal gas clean-up technologies.

  15. Ground Magnetics | Open Energy Information

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Technique: Ground Magnetics Details Activities (25) Areas (19) Regions (0) NEPA(1) Exploration...

  16. Going Deep vs. Going Wide

    Broader source: Energy.gov [DOE]

    Going Deep vs. Going Wide, from the Residential Energy Efficiency Solutions Conference 2012. Provides an overview on the progress of four energy efficiency programs: Clean Energy Works Oregon, Efficiency Maine, Energy Upgrade California Flex Path, and EcoHouse Loan Program.

  17. Stimulation Technologies for Deep Well Completions

    SciTech Connect (OSTI)

    Stephen Wolhart

    2005-06-30

    The Department of Energy (DOE) is sponsoring the Deep Trek Program targeted at improving the economics of drilling and completing deep gas wells. Under the DOE program, Pinnacle Technologies conducted a study to evaluate the stimulation of deep wells. The objective of the project was to review U.S. deep well drilling and stimulation activity, review rock mechanics and fracture growth in deep, high-pressure/temperature wells and evaluate stimulation technology in several key deep plays. This report documents results from this project.

  18. Solid state thin film battery having a high temperature lithium alloy anode

    DOE Patents [OSTI]

    Hobson, D.O.

    1998-01-06

    An improved rechargeable thin-film lithium battery involves the provision of a higher melting temperature lithium anode. Lithium is alloyed with a suitable solute element to elevate the melting point of the anode to withstand moderately elevated temperatures. 2 figs.

  19. A Comparative Study of Anodized Titania Nanotube Architectures in Aqueous and Nonaqueous Solutions

    SciTech Connect (OSTI)

    Sturgeon, Matthew R; Lai, Peng; Hu, Michael Z.

    2011-01-01

    The unique and highly utilized properties of TiO2 nanotubes are a direct result of nanotube architecture. In order to create different engineered architectures, the effects of electrolyte solution, time, and temperature on the anodization of titanium foil were studied along with the resultant anodized titanium oxide (ATO) nanotube architectures encompassing nanotube length, pore diameter, wall thickness, smoothness, and ordered array structure. Titanium foil was anodized in three different electrolyte solutions: one aqueous (consisting of NH4F and (NH4)2SO4)) and two nonaqueous (glycerin or ethylene glycol, both containing NH4F) at varying temperatures and anodization times. Variation in anodization applied voltage, initial current, and effect of F- ion concentration on ATO nanotube architecture were also studied. Anodization in the aqueous electrolyte produced short, rough nanotube arrays, whereas anodization in organic electrolytes produced long, smooth nanotube arrays greater than 10 m in length. Anodization in glycerin at elevated temperatures for several hours presents the possibility of producing freely dispersed individual nanotubes.

  20. Durability Prediction of Solid Oxide Fuel Cell Anode Material under Thermo-Mechanical and Fuel Gas Contaminants Effects

    SciTech Connect (OSTI)

    Iqbal, Gulfam; Guo, Hua; Kang , Bruce S.; Marina, Olga A.

    2011-01-10

    Solid Oxide Fuel Cells (SOFCs) operate under harsh environments, which cause deterioration of anode material properties and service life. In addition to electrochemical performance, structural integrity of the SOFC anode is essential for successful long-term operation. The SOFC anode is subjected to stresses at high temperature, thermal/redox cycles, and fuel gas contaminants effects during long-term operation. These mechanisms can alter the anode microstructure and affect its electrochemical and structural properties. In this research, anode material degradation mechanisms are briefly reviewed and an anode material durability model is developed and implemented in finite element analysis. The model takes into account thermo-mechanical and fuel gas contaminants degradation mechanisms for prediction of long-term structural integrity of the SOFC anode. The proposed model is validated experimentally using a NexTech ProbostatTM SOFC button cell test apparatus integrated with a Sagnac optical setup for simultaneously measuring electrochemical performance and in-situ anode surface deformation.

  1. Solid oxide fuel cell power plant with an anode recycle loop turbocharger

    DOE Patents [OSTI]

    Saito, Kazuo; Skiba, Tommy; Patel, Kirtikumar H.

    2015-07-14

    An anode exhaust recycle turbocharger (100) has a turbocharger turbine (102) secured in fluid communication with a compressed oxidant stream within an oxidant inlet line (218) downstream from a compressed oxidant supply (104), and the anode exhaust recycle turbocharger (100) also includes a turbocharger compressor (106) mechanically linked to the turbocharger turbine (102) and secured in fluid communication with a flow of anode exhaust passing through an anode exhaust recycle loop (238) of the solid oxide fuel cell power plant (200). All or a portion of compressed oxidant within an oxidant inlet line (218) drives the turbocharger turbine (102) to thereby compress the anode exhaust stream in the recycle loop (238). A high-temperature, automotive-type turbocharger (100) replaces a recycle loop blower-compressor (52).

  2. Anode shroud for off-gas capture and removal from electrolytic oxide reduction system

    DOE Patents [OSTI]

    Bailey, James L.; Barnes, Laurel A.; Wiedmeyer, Stanley G.; Williamson, Mark A.; Willit, James L.

    2014-07-08

    An electrolytic oxide reduction system according to a non-limiting embodiment of the present invention may include a plurality of anode assemblies and an anode shroud for each of the anode assemblies. The anode shroud may be used to dilute, cool, and/or remove off-gas from the electrolytic oxide reduction system. The anode shroud may include a body portion having a tapered upper section that includes an apex. The body portion may have an inner wall that defines an off-gas collection cavity. A chimney structure may extend from the apex of the upper section and be connected to the off-gas collection cavity of the body portion. The chimney structure may include an inner tube within an outer tube. Accordingly, a sweep gas/cooling gas may be supplied down the annular space between the inner and outer tubes, while the off-gas may be removed through an exit path defined by the inner tube.

  3. Anode-cathode power distribution systems and methods of using the same for electrochemical reduction

    DOE Patents [OSTI]

    Koehl, Eugene R; Barnes, Laurel A; Wiedmeyer, Stanley G; Williamson, Mark A; Willit, James L

    2014-01-28

    Power distribution systems are useable in electrolytic reduction systems and include several cathode and anode assembly electrical contacts that permit flexible modular assembly numbers and placement in standardized connection configurations. Electrical contacts may be arranged at any position where assembly contact is desired. Electrical power may be provided via power cables attached to seating assemblies of the electrical contacts. Cathode and anode assembly electrical contacts may provide electrical power at any desired levels. Pairs of anode and cathode assembly electrical contacts may provide equal and opposite electrical power; different cathode assembly electrical contacts may provide different levels of electrical power to a same or different modular cathode assembly. Electrical systems may be used with an electrolyte container into which the modular cathode and anode assemblies extend and are supported above, with the modular cathode and anode assemblies mechanically and electrically connecting to the respective contacts in power distribution systems.

  4. Regional analysis of ground and above-ground climate

    SciTech Connect (OSTI)

    Not Available

    1981-12-01

    The regional suitability of underground construction as a climate control technique is discussed with reference to (1) a bioclimatic analysis of long-term weather data for 29 locations in the United States to determine appropriate above ground climate control techniques, (2) a data base of synthesized ground temperatures for the coterminous United States, and (3) monthly dew point ground temperature comparisons for identifying the relative likelihood of condensation from one region to another. It is concluded that the suitability of earth tempering as a practice and of specific earth-sheltered design stereotypes varies geographically; while the subsurface almost always provides a thermal advantage on its own terms when compared to above ground climatic data, it can, nonetheless, compromise the effectiveness of other, regionally more important climate control techniques. Also contained in the report are reviews of above and below ground climate mapping schemes related to human comfort and architectural design, and detailed description of a theoretical model of ground temperature, heat flow, and heat storage in the ground. Strategies of passive climate control are presented in a discussion of the building bioclimatic analysis procedure which has been applied in a computer analysis of 30 years of weather data for each of 29 locations in the United States.

  5. Process for mitigating corrosion and increasing the conductivity of steel studs in soderberg anodes of aluminum reduction cells

    DOE Patents [OSTI]

    Oden, Laurance L. (Albany, OR); White, Jack C. (Albany, OR); Ramsey, James A. (The Dalles, OR)

    1994-01-01

    A corrosion resistant electrically conductive coating on steel anode studs used in the production of aluminum by electrolysis.

  6. Deep Borehole Disposal Research: Demonstration Site Selection...

    Office of Environmental Management (EM)

    The deep borehole disposal concept consists of drilling a borehole on the order of 5,000 m deep, emplacing waste canisters in the lower part of the borehole, and sealing the upper ...

  7. Lithium ion batteries with titania/graphene anodes

    DOE Patents [OSTI]

    Liu, Jun; Choi, Daiwon; Yang, Zhenguo; Wang, Donghai; Graff, Gordon L; Nie, Zimin; Viswanathan, Vilayanur V; Zhang, Jason; Xu, Wu; Kim, Jin Yong

    2013-05-28

    Lithium ion batteries having an anode comprising at least one graphene layer in electrical communication with titania to form a nanocomposite material, a cathode comprising a lithium olivine structure, and an electrolyte. The graphene layer has a carbon to oxygen ratio of between 15 to 1 and 500 to 1 and a surface area of between 400 and 2630 m.sup.2/g. The nanocomposite material has a specific capacity at least twice that of a titania material without graphene material at a charge/discharge rate greater than about 10 C. The olivine structure of the cathode of the lithium ion battery of the present invention is LiMPO.sub.4 where M is selected from the group consisting of Fe, Mn, Co, Ni and combinations thereof.

  8. Parallel vacuum arc discharge with microhollow array dielectric and anode

    SciTech Connect (OSTI)

    Feng, Jinghua; Zhou, Lin; Fu, Yuecheng; Zhang, Jianhua; Xu, Rongkun; Chen, Faxin; Li, Linbo; Meng, Shijian

    2014-07-15

    An electrode configuration with microhollow array dielectric and anode was developed to obtain parallel vacuum arc discharge. Compared with the conventional electrodes, more than 10 parallel microhollow discharges were ignited for the new configuration, which increased the discharge area significantly and made the cathode eroded more uniformly. The vacuum discharge channel number could be increased effectively by decreasing the distances between holes or increasing the arc current. Experimental results revealed that plasmas ejected from the adjacent hollow and the relatively high arc voltage were two key factors leading to the parallel discharge. The characteristics of plasmas in the microhollow were investigated as well. The spectral line intensity and electron density of plasmas in microhollow increased obviously with the decease of the microhollow diameter.

  9. Anode reactive bleed and injector shift control strategy

    DOE Patents [OSTI]

    Cai, Jun [Rochester, NY; Chowdhury, Akbar [Pittsford, NY; Lerner, Seth E [Honeoye Falls, NY; Marley, William S [Rush, NY; Savage, David R [Rochester, NY; Leary, James K [Rochester, NY

    2012-01-03

    A system and method for correcting a large fuel cell voltage spread for a split sub-stack fuel cell system. The system includes a hydrogen source that provides hydrogen to each split sub-stack and bleed valves for bleeding the anode side of the sub-stacks. The system also includes a voltage measuring device for measuring the voltage of each cell in the split sub-stacks. The system provides two levels for correcting a large stack voltage spread problem. The first level includes sending fresh hydrogen to the weak sub-stack well before a normal reactive bleed would occur, and the second level includes sending fresh hydrogen to the weak sub-stack and opening the bleed valve of the other sub-stack when the cell voltage spread is close to stack failure.

  10. Electrochemical Aging of Thermal-Sprayed Zinc Anodes on Concrete

    SciTech Connect (OSTI)

    Holcomb, G.R.; Bullard, S.J.; Covino, B.S. Jr.; Cramer, S.D.; Cryer, C.B.; McGill, G.E.

    1996-10-01

    Thermal-sprayed zinc anodes are used in impressed current cathodic protection systems for some of Oregon's coastal reinforced concrete bridges. Electrochemical aging of zinc anodes results in physical and chemical changes at the zinc-concrete interface. Concrete surfaces heated prior to thermal-spraying had initial adhesion strengths 80 pct higher than unheated surfaces. For electrochemical aging greater than 200 kC/m{sup 2} (5.2 A h/ft{sup 2}), there was no difference in adhesion strengths for zinc on preheated and unheated concrete. Adhesion strengths decreased monotonically after about 400 to 600 kC/m{sup 2} (10.4 to 15.6 A-h/ft{sup 2}) as a result of the reaction zones at the zinc-concrete interface. A zone adjacent to the metallic zinc (and originally part of the zinc coating) was primarily zincite (ZnO), with minor constituents of wulfingite (Zn(OH){sub 2}), simonkolleite (Zn{sub 5}(OH) {sub 8}C{sub l2}{sup .}H{sub 2}O), and hydrated zinc hydroxide sulfates (Zn{sub 4}SO{sub 4}(OH){sub 6}{sup .}xH{sub 2}O). This zone is the locus for cohesive fracture when the zinc coating separates from the concrete during adhesion tests. Zinc ions substitute for calcium in the cement paste adjacent to the coating as the result of secondary mineralization. The initial estimate of the coating service life based on adhesion strength measurements in accelerated impressed current cathodic protection tests is about 27 years.

  11. Development of metal-coated ceramic anodes for molten carbonate fuel cells. Final report

    SciTech Connect (OSTI)

    Khandkar, A.C.; Elangovan, S.; Marianowski, L.G.

    1990-03-01

    This report documents the developmental efforts on metal coating of various ceramic substrates (LiAlO{sub 2}, SrTiO{sub 3}, and LiFeO{sub 2}) and the critical issues associated with fabricating anodes using metal-coated LiAlO{sub 2} substrates. Electroless Ni and Cu coating technology was developed to achieve complete metal coverage on LiAlO{sub 2} powder substrates. Metal coated SrTiO{sub 3} powders were fabricated into anodes by a process identical to that reported in the GE literature. Microstructural examination revealed that the grains of the ceramic had fused together, with the metal having dewetted from the surface of the ceramic. Alternate substrates that might allow for better wetting of the metal on the ceramic such as LiFeO{sub 2} and Li{sub 2}MnO{sub 3} were identified. Cu/Ni-coated (50:50 mol ratio, 50 w/o metal loading) LiFeO{sub 2} anodes were optimized to meet the MCFC anode specifications. Metal-coated gamma-LiAlO{sub 2} substrates were also developed. By using suitable chemical surface modification methods, the gamma-UAlO{sub 2} substrate surface may be modified to allow a stable metal coated anode to be fabricated. Creep testing of the metal coated ceramic anodes were conducted at IGT. It was determined that the predominant creep mechanism is due to particle rearrangement. The anode porosity, and mean pore size had significant effect on the creep of the anode. Lower porosity and pore size consistent with performance criteria are desired to reduce creep. Lower metal loading with uniformity of coverage will result in lower creep behavior of the anode. Of the two substrates evaluated, LiFeO{sub 2} in general exhibited lower creep which was attributed to superior metal adhesion.

  12. Development of metal-coated ceramic anodes for molten carbonate fuel cells

    SciTech Connect (OSTI)

    Khandkar, A.C.; Elangovan, S.; Marianowski, L.G.

    1990-03-01

    This report documents the developmental efforts on metal coating of various ceramic substrates (LiAlO{sub 2}, SrTiO{sub 3}, and LiFeO{sub 2}) and the critical issues associated with fabricating anodes using metal-coated LiAlO{sub 2} substrates. Electroless Ni and Cu coating technology was developed to achieve complete metal coverage on LiAlO{sub 2} powder substrates. Metal coated SrTiO{sub 3} powders were fabricated into anodes by a process identical to that reported in the GE literature. Microstructural examination revealed that the grains of the ceramic had fused together, with the metal having dewetted from the surface of the ceramic. Alternate substrates that might allow for better wetting of the metal on the ceramic such as LiFeO{sub 2} and Li{sub 2}MnO{sub 3} were identified. Cu/Ni-coated (50:50 mol ratio, 50 w/o metal loading) LiFeO{sub 2} anodes were optimized to meet the MCFC anode specifications. Metal-coated gamma-LiAlO{sub 2} substrates were also developed. By using suitable chemical surface modification methods, the gamma-UAlO{sub 2} substrate surface may be modified to allow a stable metal coated anode to be fabricated. Creep testing of the metal coated ceramic anodes were conducted at IGT. It was determined that the predominant creep mechanism is due to particle rearrangement. The anode porosity, and mean pore size had significant effect on the creep of the anode. Lower porosity and pore size consistent with performance criteria are desired to reduce creep. Lower metal loading with uniformity of coverage will result in lower creep behavior of the anode. Of the two substrates evaluated, LiFeO{sub 2} in general exhibited lower creep which was attributed to superior metal adhesion.

  13. Ground Penetrating Radar, Barrow, Alaska

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    John Peterson

    2015-03-06

    This is 500 MHz Ground Penetrating Radar collected along the AB Line in Intensive Site 1 beginning in October 2012 and collected along L2 in Intensive Site 0 beginning in September 2011. Both continue to the present.

  14. Inert anode containing base metal and noble metal useful for the electrolytic production of aluminum

    DOE Patents [OSTI]

    Ray, Siba P. (Murrysville, PA); Liu, Xinghua (Monroeville, PA)

    2000-01-01

    An inert anode for production of metals such as aluminum is disclosed. The inert anode comprises a base metal selected from Cu and Ag, and at least one noble metal selected from Ag, Pd, Pt, Au, Rh, Ru, Ir and Os. The inert anode may optionally be formed of sintered particles having interior portions containing more base metal than noble metal and exterior portions containing more noble metal than base metal. In a preferred embodiment, the base metal comprises Cu, and the noble metal comprises Ag, Pd or a combination thereof.

  15. Chemical Bonding In Amorphous Si Coated-carbon Nanotube As Anodes For Li

    Office of Scientific and Technical Information (OSTI)

    ion Batteries: A XANES Study (Journal Article) | SciTech Connect Chemical Bonding In Amorphous Si Coated-carbon Nanotube As Anodes For Li ion Batteries: A XANES Study Citation Details In-Document Search Title: Chemical Bonding In Amorphous Si Coated-carbon Nanotube As Anodes For Li ion Batteries: A XANES Study The chemical bonding nature and its evolution upon electrochemical cycling in amorphous Si coated-carbon nanotube (Si-CNT) anode has been investigated using comprehensive X-ray

  16. Chemically modified thermal-spray zinc anodes for galvanic cathodic protection

    SciTech Connect (OSTI)

    Covino, B.S. Jr.; Bullard, S.J.; Holcomb, G.R.; Russell, J.H.; Cramer, S.D.; Bennett, J.E.; Laylor, H.M.

    1999-12-01

    Humectants, substances that promote the retention of moisture, were applied to new and previously aged thermal-sprayed Zn anodes to improve the performance of galvanic cathodic protection systems. Anodes on steel-reinforced concrete were treated with aqueous solutions of the humectants lithium nitrate (LiNO{sub 3}) and lithium bromide (LiBr). LiBr was the most beneficial humectant, increasing the average galvanic current density of new thermal-sprayed Zn anodes by as much as a factor of six.

  17. Developing High Capacity, Long Life, and High Power Anodes | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Life, and High Power Anodes Developing High Capacity, Long Life, and High Power Anodes 2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon es020_amine_2010_o.pdf More Documents & Publications Developing a new high capacity anode with long life Vehicle Technologies Office: 2010 Energy Storage R&D Annual Progress Report Vehicle Technologies Office: 2009 Energy Storage R&D Annual

  18. Non-consumable anode and lining for aluminum electrolytic reduction cell

    DOE Patents [OSTI]

    Beck, Theodore R. (Seattle, WA); Brooks, Richard J. (Seattle, WA)

    1994-01-01

    An oxidation resistant, non-consumable anode, for use in the electrolytic reduction of alumina to aluminum, has a composition comprising copper, nickel and iron. The anode is part of an electrolytic reduction cell comprising a vessel having an interior lined with metal which has the same composition as the anode. The electrolyte is preferably composed of a eutectic of AlF.sub.3 and either (a) NaF or (b) primarily NaF with some of the NaF replaced by an equivalent molar amount of KF or KF and LiF.

  19. Ground Source Solutions | Open Energy Information

    Open Energy Info (EERE)

    Kingdom Zip: NG22 9GW Sector: Buildings Product: UK-based installer of ground source energy systems to domestic and commercial buildings. References: Ground Source...

  20. Colorado Ground Water Commission | Open Energy Information

    Open Energy Info (EERE)

    Colorado Ground Water Commission Jump to: navigation, search Name: Colorado Ground Water Commission Place: Colorado Website: water.state.co.usgroundwater References: Colorado...

  1. Inert anode containing oxides of nickel iron and cobalt useful for the electrolytic production of metals

    DOE Patents [OSTI]

    Ray, Siba P. (Murrysville, PA); Liu, Xinghua (Monroeville, PA); Weirauch, Jr., Douglas A. (Murrysville, PA)

    2002-01-01

    An inert anode for the electrolytic production of metals such as aluminum is disclosed. The inert anode includes a ceramic oxide material preferably made from NiO, Fe.sub.2 O.sub.3 and CoO. The inert anode composition may comprise the following mole fractions of NiO, Fe.sub.2 O.sub.3 and CoO: 0.15 to 0.99 NiO; 0.0001 to 0.85 Fe.sub.2 O.sub.3 ; and 0.0001 to 0.45 CoO. The inert anode may optionally include other oxides and/or at least one metal phase, such as Cu, Ag, Pd, Pt, Au, Rh, Ru, Ir and/or Os. The Ni--Fe--Co--O ceramic material exhibits very low solubility in Hall cell baths used to produce aluminum.

  2. Vehicle Technologies Office Merit Review 2015: High Energy Anode Material Development for Li-ion Batteries

    Broader source: Energy.gov [DOE]

    Presentation given by Sinode Systems at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about high energy anode material...

  3. Vehicle Technologies Office Merit Review 2015: Si Alloy Anode: Sudden Fade Challenge

    Broader source: Energy.gov [DOE]

    Presentation given by 3M at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about Si alloy anode: sudden fade challenge.

  4. Inert anode containing oxides of nickel, iron and zinc useful for the electrolytic production of metals

    DOE Patents [OSTI]

    Ray, Siba P.; Weirauch, Jr., Douglas A.; Liu, Xinghua

    2002-01-01

    An inert anode for the electrolytic production of metals such as aluminum is disclosed. The inert anode includes a ceramic oxide material preferably made from NiO, Fe.sub.2 O.sub.3 and ZnO. The inert anode composition may comprise the following mole fractions of NiO, Fe.sub.2 O.sub.3 and ZnO: 0.2 to 0.99 NiO; 0.0001 to 0.8 Fe.sub.2 O.sub.3 ; and 0.0001 to 0.3 ZnO. The inert anode may optionally include other oxides and/or at least one metal phase, such as Cu, Ag, Pd, Pt, Au, Rh, Ru, Ir and/or Os. The Ni--Fe--Co--O ceramic material exhibits very low solubility in Hall cell baths used to produce aluminum.

  5. For cermet inert anode containing oxide and metal phases useful for the electrolytic production of metals

    DOE Patents [OSTI]

    Ray, Siba P. (Murrysville, PA); Liu, Xinghua (Monroeville, PA); Weirauch, Douglas A. (Murrysville, PA)

    2002-01-01

    A cermet inert anode for the electrolytic production of metals such as aluminum is disclosed. The inert anode comprises a ceramic phase including an oxide of Ni, Fe and M, where M is at least one metal selected from Zn, Co, Al, Li, Cu, Ti, V, Cr, Zr, Nb, Ta, W, Mo, Hf and rare earths, preferably Zn and/or Co. Preferred ceramic compositions comprise Fe.sub.2 O.sub.3, NiO and ZnO or CoO. The cermet inert anode also comprises a metal phase such as Cu, Ag, Pd, Pt, Au, Rh, Ru, Ir and/or Os. A preferred metal phase comprises Cu and Ag. The cermet inert anodes may be used in electrolytic reduction cells for the production of commercial purity aluminum as well as other metals.

  6. Argonne and CalBattery strike deal for silicon-graphene anode...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    today that they have signed a licensing agreement for an Argonne-developed, silicon-graphene composite anode material for high-energy lithium batteries. CalBattery plans to...

  7. Anode protection system for shutdown of solid oxide fuel cell system

    DOE Patents [OSTI]

    Li, Bob X; Grieves, Malcolm J; Kelly, Sean M

    2014-12-30

    An Anode Protection Systems for a SOFC system, having a Reductant Supply and safety subsystem, a SOFC anode protection subsystem, and a Post Combustion and slip stream control subsystem. The Reductant Supply and safety subsystem includes means for generating a reducing gas or vapor to prevent re-oxidation of the Ni in the anode layer during the course of shut down of the SOFC stack. The underlying ammonia or hydrogen based material used to generate a reducing gas or vapor to prevent the re-oxidation of the Ni can be in either a solid or liquid stored inside a portable container. The SOFC anode protection subsystem provides an internal pressure of 0.2 to 10 kPa to prevent air from entering into the SOFC system. The Post Combustion and slip stream control subsystem provides a catalyst converter configured to treat any residual reducing gas in the slip stream gas exiting from SOFC stack.

  8. Material and Energy Flows in the Production of Cathode and Anode...

    Office of Scientific and Technical Information (OSTI)

    Material and Energy Flows in the Production of Cathode and Anode Materials for Lithium Ion Batteries Citation Details In-Document Search Title: Material and Energy Flows in the ...

  9. Chemically Etched Silicon Nanowires as Anodes for Lithium-Ion Batteries

    SciTech Connect (OSTI)

    West, Hannah Elise

    2015-08-01

    This study focused on silicon as a high capacity replacement anode for Lithium-ion batteries. The challenge of silicon is that it expands ~270% upon lithium insertion which causes particles of silicon to fracture, causing the capacity to fade rapidly. To account for this expansion chemically etched silicon nanowires from the University of Maine were studied as anodes. They were built into electrochemical half-cells and cycled continuously to measure the capacity and capacity fade.

  10. Material and Energy Flows in the Production of Cathode and Anode Materials

    Office of Scientific and Technical Information (OSTI)

    for Lithium Ion Batteries (Technical Report) | SciTech Connect SciTech Connect Search Results Technical Report: Material and Energy Flows in the Production of Cathode and Anode Materials for Lithium Ion Batteries Citation Details In-Document Search Title: Material and Energy Flows in the Production of Cathode and Anode Materials for Lithium Ion Batteries Authors: Dunn, Jennifer B. ; James, Christine ; Gaines, L G ; Gallagher, Kevin Publication Date: 2014-09-30 OSTI Identifier: 1172039 Report

  11. Material and Energy Flows in the Production of Cathode and Anode Materials

    Office of Scientific and Technical Information (OSTI)

    for Lithium Ion Batteries (Technical Report) | SciTech Connect Technical Report: Material and Energy Flows in the Production of Cathode and Anode Materials for Lithium Ion Batteries Citation Details In-Document Search Title: Material and Energy Flows in the Production of Cathode and Anode Materials for Lithium Ion Batteries The Greenhouse gases, Regulated Emissions and Energy use in Transportation (GREET) model has been expanded to include four new cathode materials that can be used in the

  12. Material and Energy Flows in the Production of Cathode and Anode Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for Lithium Ion Batteries | Argonne National Laboratory Material and Energy Flows in the Production of Cathode and Anode Materials for Lithium Ion Batteries Title Material and Energy Flows in the Production of Cathode and Anode Materials for Lithium Ion Batteries Publication Type Report Year of Publication 2015 Authors Dunn, JB, James, C, Gaines, LL, Gallagher, K, Dai, Q, Kelly, JC Pagination 56 Date Published 09152015 Institution Argonne National Laboratory City Argonne, IL USA Report

  13. Rutherford backscattering analysis of the failure of chlorine anodes

    SciTech Connect (OSTI)

    Vallet, C.E.; Tilak, B.V.

    1996-06-01

    Rutherford Backscattering Spectrometry, carried out at the ORNL Surface Modification And Characterization Collaborative Research Center (SMAC) facility, has been applied to the nondestructive analysis of RuO[sub 2]-TiO[sub 2] electrodes of 5000 Angstroms, which mimic the DSA anodes in composition and the method of preparation. Occidental Chemical Corporation provided electrodes, which had been subjected to life time testing in H[sub 2]S04 solution, for analysis by ORNL. The results were used to test the hypothesis of degradation of theses, and similar electrodes, from a process involving a decrease in the RuO[sub 2]:TiO[sub 2] ratio at and near the electrode surface and the related decrease in the electrode electrical conductivity. The drop in electrode activity is closely linked to a decrease in Ru content, and the measured profiles show that the loss takes place across the thin RuO[sub 2]-TiO[sub 2] coating. No build up of a pure TiO[sub 2] layer is apparent. The data agree quantitatively with the critical concentration previously reported by ORNL for materials produced by ion implantation and characterized by Rutherford Backscattering Spectrometry and Photoacoustic Spectrometry. The study has brought a better understanding of the degradation process in electrodes of great technological importance, and has given a more solid background in designing new fabrication procedures for improved electrodes.

  14. Mitigation of Sulfur Poisoning of Ni/Zirconia SOFC Anodes by Antimony and Tin

    SciTech Connect (OSTI)

    Marina, Olga A.; Coyle, Christopher A.; Engelhard, Mark H.; Pederson, Larry R.

    2011-02-28

    Surface Ni/Sb and Ni/Sb alloys were found to efficiently minimize the negative effects of sulfur on the performance of Ni/zirconia anode-supported solid oxide fuel cells (SOFC). Prior to operating on fuel gas containing low concentrations of H2S, the nickel/zirconia anodes were briefly exposed to antimony or tin vapor, which only slightly affected the SOFC performance. During the subsequent exposures to 1 and 5 ppm H2S, increases in anodic polarization losses were minimal compared to those observed for the standard nickel/zirconia anodes. Post-test XPS analyses showed that Sb and Sn tended to segregate to the surface of Ni particles, and further confirmed a significant reduction of adsorbed sulfur on the Ni surface in Ni/Sn and Ni/Sb samples compared to the Ni. The effect may be the result of weaker sulfur adsorption on bimetallic surfaces, adsorption site competition between sulfur and Sb or Sn on Ni, or other factors. The use of dilute binary alloys of Ni-Sb or Ni-Sn in the place of Ni, or brief exposure to Sb or Sn vapor, may be effective means to counteract the effects of sulfur poisoning in SOFC anodes and Ni catalysts. Other advantages, including suppression of coking or tailoring the anode composition for the internal reforming, are also expected.

  15. Transportation Energy Futures: Combining Strategies for Deep...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ENERGY FUTURES Combining Strategies for Deep Reductions in Energy Consumption and GHG Emissions Significant Energy Consumption - and Opportunities for Reduction Transportation is...

  16. DeepStream Technologies | Open Energy Information

    Open Energy Info (EERE)

    Place: Bangor, United Kingdom Zip: LL57 4EZ Product: DeepStream Technologies produces digital sensors and controls that measure, monitor, and manage energy usage. References:...

  17. Phase III Advanced Anodes and Cathodes Utilized in Energy Efficient Aluminum Production Cells

    SciTech Connect (OSTI)

    R.A. Christini; R.K. Dawless; S.P. Ray; D.A. Weirauch, Jr.

    2001-11-05

    During Phase I of the present program, Alcoa developed a commercial cell concept that has been estimated to save 30% of the energy required for aluminum smelting. Phase ii involved the construction of a pilot facility and operation of two pilots. Phase iii of the Advanced Anodes and Cathodes Program was aimed at bench experiments to permit the resolution of certain questions to be followed by three pilot cells. All of the milestones related to materials, in particular metal purity, were attained with distinct improvements over work in previous phases of the program. NiO additions to the ceramic phase and Ag additions to the Cu metal phase of the cermet improved corrosion resistance sufficiently that the bench scale pencil anodes met the purity milestones. Some excellent metal purity results have been obtained with anodes of the following composition: Further improvements in anode material composition appear to be dependent on a better understanding of oxide solubilities in molten cryolite. For that reason, work was commissioned with an outside consultant to model the MeO - cryolite systems. That work has led to a better understanding of which oxides can be used to substitute into the NiO-Fe2O3 ceramic phase to stabilize the ferrites and reduce their solubility in molten cryolite. An extensive number of vertical plate bench electrolysis cells were run to try to find conditions where high current efficiencies could be attained. TiB2-G plates were very inconsistent and led to poor wetting and drainage. Pure TiB2 did produce good current efficiencies at small overlaps (shadowing) between the anodes and cathodes. This bench work with vertical plate anodes and cathodes reinforced the importance of good cathode wetting to attain high current efficiencies. Because of those conclusions, new wetting work was commissioned and became a major component of the research during the third year of Phase III. While significant progress was made in several areas, much work needs to be done. The anode composition needs further improvements to attain commercial purity targets. At the present corrosion rate, the vertical plate anodes will wear too rapidly leading to a rapidly increasing anode-cathode gap and thermal instabilities in the cell. Cathode wetting as a function of both cathode plate composition and bath composition needs to be better understood to ensure that complete drainage of the molten aluminum off the plates occurs. Metal buildup appears to lead to back reaction and low current efficiencies.

  18. Coring in deep hardrock formations

    SciTech Connect (OSTI)

    Drumheller, D.S.

    1988-08-01

    The United States Department of Energy is involved in a variety of scientific and engineering feasibility studies requiring extensive drilling in hard crystalline rock. In many cases well depths extend from 6000 to 20,000 feet in high-temperature, granitic formations. Examples of such projects are the Hot Dry Rock well system at Fenton Hill, New Mexico and the planned exploratory magma well near Mammoth Lakes, California. In addition to these programs, there is also continuing interest in supporting programs to reduce drilling costs associated with the production of geothermal energy from underground sources such as the Geysers area near San Francisco, California. The overall progression in these efforts is to drill deeper holes in higher temperature, harder formations. In conjunction with this trend is a desire to improve the capability to recover geological information. Spot coring and continuous coring are important elements in this effort. It is the purpose of this report to examine the current methods used to obtain core from deep wells and to suggest projects which will improve existing capabilities. 28 refs., 8 figs., 2 tabs.

  19. Ground control for highwall mining

    SciTech Connect (OSTI)

    Zipf, R.K.; Mark, C.

    2007-09-15

    Perhaps the greatest risk to both equipment and personnel associated with highwall mining is from ground control. The two most significant ground control hazards are rock falls from highwall and equipment entrapment underground. In the central Appalachians, where the majority of highwall mining occurs in the USA, hillseams (or mountain cracks) are the most prominent structure that affects highwall stability. The article discusses measures to minimise the risk of failure associated with hillstreams. A 'stuck' or trapped highwall miner, and the ensuring retrieval or recovery operation, can be extremely disruptive to the highwall mining process. Most entrapment, are due to roof falls in the hole. The options for recovery are surface retrieval, surface excavation or underground recovery. Proper pillar design is essential to maintain highwall stability and prevent entrapments. NIOSH has developed the Analysis of Retreat Mining Pillar stability-Highwall Mining (ARMPS-HWM) computer program to help mine planners with this process. 10 figs.

  20. In-Ground Radiation Detection

    SciTech Connect (OSTI)

    McCormick, Kathleen R.; Stromswold, David C.; Woodring, Mitchell L.; Ely, James H.; Siciliano, Edward R.; Caggiano, Joseph A.; Hensley, Walter K.

    2006-10-29

    Vertically oriented radiation detectors may not provide sufficient screening in rail or aviation applications. Railcars can be heavily shielded on the sides, reducing the sensitivity of vertically mounted monitors. For aviation, the distance required for wingspan clearance reduces a vertical detectors coverage of the fuselage. To surmount these, and other, challenging operational and sensitivity issues, we have investigated the use of in-ground radiation detectors. (PIET-43741-TM-605).

  1. Inverter Ground Fault Overvoltage Testing

    SciTech Connect (OSTI)

    Hoke, Andy; Nelson, Austin; Chakraborty, Sudipta; Chebahtah, Justin; Wang, Trudie; McCarty, Michael

    2015-08-12

    This report describes testing conducted at NREL to determine the duration and magnitude of transient overvoltages created by several commercial PV inverters during ground fault conditions. For this work, a test plan developed by the Forum on Inverter Grid Integration Issues (FIGII) has been implemented in a custom test setup at NREL. Load rejection overvoltage test results were reported previously in a separate technical report.

  2. Inverter Ground Fault Overvoltage Testing

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Inverter Ground Fault Overvoltage Testing Andy Hoke, Austin Nelson, and Sudipta Chakraborty National Renewable Energy Laboratory Justin Chebahtah, Trudie Wang, and Michael McCarty SolarCity Corporation Technical Report NREL/TP-5D00-64173 August 2015 NREL is a national laboratory of the U.S. Department of Energy Office of Energy Efficiency & Renewable Energy Operated by the Alliance for Sustainable Energy, LLC This report is available at no cost from the National Renewable Energy Laboratory

  3. GPG Green Proving Ground Program

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    GSA Green Proving Ground Program Technology Overview of Federal Technology Demonstration Programs Eleni Reed GSA Public Buildings Service August 11, 2015 GPG Program Overview FEDERAL MANDATES SET THE PACE Efficiency results from innovation and policy Executive Order 13693, 2015 2.5% annual reduction in EUI through 2025, over 2015 levels Net zero energy (water/waste where feasible) * New construction designs starting 2020 & percentage of existing buildings Energy Independence and Security

  4. CX-005369: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Replacement of Big Hill Deep Anode Ground Bed Site for Cavern 103CX(s) Applied: B1.3Date: 02/22/2011Location(s): TexasOffice(s): Strategic Petroleum Reserve Field Office

  5. Graphdiyne as a high-capacity lithium ion battery anode material

    SciTech Connect (OSTI)

    Jang, Byungryul; Koo, Jahyun; Park, Minwoo; Kwon, Yongkyung; Lee, Hoonkyung; Lee, Hosik; Nam, Jaewook

    2013-12-23

    Using the first-principles calculations, we explored the feasibility of using graphdiyne, a 2D layer of sp and sp{sup 2} hybrid carbon networks, as lithium ion battery anodes. We found that the composite of the Li-intercalated multilayer ?-graphdiyne was C{sub 6}Li{sub 7.31} and that the calculated voltage was suitable for the anode. The practical specific/volumetric capacities can reach up to 2719?mAh?g{sup ?1}/2032?mAh?cm{sup ?3}, much greater than the values of ?372?mAh?g{sup ?1}/?818?mAh?cm{sup ?3}, ?1117?mAh?g{sup ?1}/?1589?mAh?cm{sup ?3}, and ?744?mAh?g{sup ?1} for graphite, graphynes, and ?-graphdiyne, respectively. Our calculations suggest that multilayer ?-graphdiyne can serve as a promising high-capacity lithium ion battery anode.

  6. Method for providing uranium articles with a corrosion resistant anodized coating

    DOE Patents [OSTI]

    Waldrop, Forrest B. (Powell, TN); Washington, Charles A. (Oak Ridge, TN)

    1982-01-01

    Uranium articles are provided with anodized oxide coatings in an aqueous solution of an electrolyte selected from the group consisting of potassium phosphate, potassium hydroxide, ammonium hydroxide, and a mixture of potassium tetraborate and boric acid. The uranium articles are anodized at a temperature greater than about 75.degree. C. with a current flow of less than about 0.036 A/cm.sup.2 of surface area while the pH of the solution is maintained in a range of about 2 to 11.5. The pH values of the aqueous solution and the low current density utilized during the electrolysis prevent excessive dissolution of the uranium and porosity in the film or watering. The relatively high temperature of the electrolyte bath inhibits hydration and the attendant deleterious pitting so as to enhance corrosion resistance of the anodized coating.

  7. Manipulating surface reactions in lithium-sulphur batteries using hybrid anode structures

    SciTech Connect (OSTI)

    Huang, C; Xiao, J; Shao, YY; Zheng, JM; Bennett, WD; Lu, DP; Saraf, LV; Engelhard, M; Ji, LW; Zhang, J; Li, XL; Graff, GL; Liu, J

    2014-01-09

    Lithium-sulphur batteries have high theoretical energy density and potentially low cost, but significant challenges such as severe capacity degradation prevent its widespread adoption. Here we report a new design of lithium-sulphur battery using electrically connected graphite and lithium metal as a hybrid anode to control undesirable surface reactions on lithium. Lithiated graphite placed in front of the lithium metal functions as an artificial, self-regulated solid electrolyte interface layer to actively control the electrochemical reactions and minimize the deleterious side reactions, leading to significant performance improvements. Lithium-sulphur cells incorporating this hybrid anodes deliver capacities of >800 mAhg(-1) for 400 cycles at a high rate of 1,737mAg(-1), with only 11% capacity fade and a Coulombic efficiency >99%. This simple hybrid concept may also provide scientific strategies for protecting metal anodes in other energy-storage devices.

  8. Method for providing uranium articles with a corrosion-resistant anodized coating

    DOE Patents [OSTI]

    Waldrop, F.B.; Washington, C.A.

    1981-01-07

    Uranium articles are provided with anodized oxide coatings in an aqueous solution of an electrolyte selected from the group consisting of potassium phosphate, potassium hydroxide, ammonium hydroxide, and a mixture of potassium tetraborate and boric acid. The uranium articles are anodized at a temperature greater than about 75/sup 0/C with a current flow of less than about 0.036 A/cm/sup 2/ of surface area while the pH of the solution is maintained in a range of about 2 to 11.5. The pH values of the aqueous solution and the low current density utilized during the electrolysis prevent excessive dissolution of the uranium and porosity in the film or watering. The relatively high temperature of the electrolyte bath inhibits hydration and the attendant deleterious pitting so as to enhance corrosion resistance of the anodized coating.

  9. NATURAL GAS RESOURCES IN DEEP SEDIMENTARY BASINS

    SciTech Connect (OSTI)

    Thaddeus S. Dyman; Troy Cook; Robert A. Crovelli; Allison A. Henry; Timothy C. Hester; Ronald C. Johnson; Michael D. Lewan; Vito F. Nuccio; James W. Schmoker; Dennis B. Riggin; Christopher J. Schenk

    2002-02-05

    From a geological perspective, deep natural gas resources are generally defined as resources occurring in reservoirs at or below 15,000 feet, whereas ultra-deep gas occurs below 25,000 feet. From an operational point of view, ''deep'' is often thought of in a relative sense based on the geologic and engineering knowledge of gas (and oil) resources in a particular area. Deep gas can be found in either conventionally-trapped or unconventional basin-center accumulations that are essentially large single fields having spatial dimensions often exceeding those of conventional fields. Exploration for deep conventional and unconventional basin-center natural gas resources deserves special attention because these resources are widespread and occur in diverse geologic environments. In 1995, the U.S. Geological Survey estimated that 939 TCF of technically recoverable natural gas remained to be discovered or was part of reserve appreciation from known fields in the onshore areas and State waters of the United. Of this USGS resource, nearly 114 trillion cubic feet (Tcf) of technically-recoverable gas remains to be discovered from deep sedimentary basins. Worldwide estimates of deep gas are also high. The U.S. Geological Survey World Petroleum Assessment 2000 Project recently estimated a world mean undiscovered conventional gas resource outside the U.S. of 844 Tcf below 4.5 km (about 15,000 feet). Less is known about the origins of deep gas than about the origins of gas at shallower depths because fewer wells have been drilled into the deeper portions of many basins. Some of the many factors contributing to the origin of deep gas include the thermal stability of methane, the role of water and non-hydrocarbon gases in natural gas generation, porosity loss with increasing thermal maturity, the kinetics of deep gas generation, thermal cracking of oil to gas, and source rock potential based on thermal maturity and kerogen type. Recent experimental simulations using laboratory pyrolysis methods have provided much information on the origins of deep gas. Technologic problems are one of the greatest challenges to deep drilling. Problems associated with overcoming hostile drilling environments (e.g. high temperatures and pressures, and acid gases such as CO{sub 2} and H{sub 2}S) for successful well completion, present the greatest obstacles to drilling, evaluating, and developing deep gas fields. Even though the overall success ratio for deep wells is about 50 percent, a lack of geological and geophysical information such as reservoir quality, trap development, and gas composition continues to be a major barrier to deep gas exploration. Results of recent finding-cost studies by depth interval for the onshore U.S. indicate that, on average, deep wells cost nearly 10 times more to drill than shallow wells, but well costs and gas recoveries vary widely among different gas plays in different basins. Based on an analysis of natural gas assessments, many topical areas hold significant promise for future exploration and development. One such area involves re-evaluating and assessing hypothetical unconventional basin-center gas plays. Poorly-understood basin-center gas plays could contain significant deep undiscovered technically-recoverable gas resources.

  10. Composit, Nanoparticle-Based Anode material for Li-ion Batteries Applied in Hybrid Electric (HEV's)

    SciTech Connect (OSTI)

    Dr. Malgorzata Gulbinska

    2009-08-24

    Lithium-ion batteries are promising energy storage devices in hybrid and electric vehicles with high specific energy values ({approx}150 Wh/kg), energy density ({approx}400 Wh/L), and long cycle life (>15 years). However, applications in hybrid and electric vehicles require increased energy density and improved low-temperature (<-10 C) performance. Silicon-based anodes are inexpensive, environmentally benign, and offer excellent theoretical capacity values ({approx}4000 mAh/g), leading to significantly less anode material and thus increasing the overall energy density value for the complete battery (>500 Wh/L). However, tremendous volume changes occur during cycling of pure silicon-based anodes. The expansion and contraction of these silicon particles causes them to fracture and lose electrical contact to the current collector ultimately severely limiting their cycle life. In Phase I of this project Yardney Technical Products, Inc. proposed development of a carbon/nano-silicon composite anode material with improved energy density and silicon's cycleability. In the carbon/nano-Si composite, silicon nanoparticles were embedded in a partially-graphitized carbonaceous matrix. The cycle life of anode material would be extended by decreasing the average particle size of active material (silicon) and by encapsulation of silicon nanoparticles in a ductile carbonaceous matrix. Decreasing the average particle size to a nano-region would also shorten Li-ion diffusion path and thus improve rate capability of the silicon-based anodes. Improved chemical inertness towards PC-based, low-temperature electrolytes was expected as an additional benefit of a thin, partially graphitized coating around the active electrode material.

  11. Ground Source Heat Pumps | Open Energy Information

    Open Energy Info (EERE)

    heating andor cooling system that takes advantage of the relatively constant year-round ground temperature to pump heat to or from the ground. Other definitions:Wikipedia Reegle...

  12. Deep Borehole Disposal of Spent Fuel. (Conference) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    Deep Borehole Disposal of Spent Fuel. Citation Details In-Document Search Title: Deep Borehole Disposal of Spent Fuel. Abstract not provided. Authors: Brady, Patrick V. Publication...

  13. Test of factorization in diffractive deep inelastic scattering...

    Office of Scientific and Technical Information (OSTI)

    Test of factorization in diffractive deep inelastic scattering and photoproduction at HERA Citation Details In-Document Search Title: Test of factorization in diffractive deep ...

  14. Deep Sky Astronomical Image Database Project at NERSC

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Deep Sky Astronomical Image Database Deep Sky Astronomical Image Database Key Challenges: Develop, store, analyze, and make available an astronomical image database of...

  15. Deep Borehole Disposal Research: Geological Data Evaluation Alternativ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Deep Borehole Disposal Research: Geological Data Evaluation Alternative Waste Forms and Borehole Seals Citation Details In-Document Search Title: Deep Borehole Disposal Research:...

  16. Presentation at the Weatherization Program Deep Dive Briefing...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Presentation at the Weatherization Program Deep Dive Briefing, November 4, 2009 Presentation at the Weatherization Program Deep Dive Briefing, November 4, 2009 U.S. Department of...

  17. Whole-House Solutions Case Study: Sunnyvale Marine Climate Deep...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Whole-House Solutions Case Study: Sunnyvale Marine Climate Deep Retrofit Whole-House Solutions Case Study: Sunnyvale Marine Climate Deep Retrofit The Alliance for Residential ...

  18. Deep Borehole Disposal of Nuclear Waste: Science Needs. (Conference...

    Office of Scientific and Technical Information (OSTI)

    Deep Borehole Disposal of Nuclear Waste: Science Needs. Citation Details In-Document Search Title: Deep Borehole Disposal of Nuclear Waste: Science Needs. Abstract not provided. ...

  19. Research Development and Demonstration Roadmap for Deep Borehole...

    Office of Scientific and Technical Information (OSTI)

    Research Development and Demonstration Roadmap for Deep Borehole Disposal. Citation Details In-Document Search Title: Research Development and Demonstration Roadmap for Deep...

  20. MHK Technologies/Deep Green | Open Energy Information

    Open Energy Info (EERE)

    MHK TechnologiesDeep Green < MHK Technologies Jump to: navigation, search << Return to the MHK database homepage Deep Green.jpg Technology Profile Primary Organization Minesto AB...

  1. National Library of Energy : Main View : Deep Federated Search

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    National Library of Energy Search Powered By Deep Web Technologies New Search Preferences Powered by Deep Web Technologies energy.gov Office of Scientific and Technical Information...

  2. Deep Borehole Disposal Research: Geological Data Evaluation Alternativ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    much of the enhanced geothermal focus on stimulating fracture development (e.g., fracking) at depth is not directly relevant to deep borehole disposal. For deep borehole...

  3. Tanzania-Developing Energy Enterprises Project (DEEP) | Open...

    Open Energy Info (EERE)

    Developing Energy Enterprises Project (DEEP) Jump to: navigation, search Logo: Tanzania-Developing Energy Enterprises Project (DEEP) Name Tanzania-Developing Energy Enterprises...

  4. Uganda-Developing Energy Enterprises Project (DEEP) | Open Energy...

    Open Energy Info (EERE)

    Developing Energy Enterprises Project (DEEP) Jump to: navigation, search Logo: Uganda-Developing Energy Enterprises Project (DEEP) Name Uganda-Developing Energy Enterprises Project...

  5. Kenya-Developing Energy Enterprises Project (DEEP) | Open Energy...

    Open Energy Info (EERE)

    Developing Energy Enterprises Project (DEEP) Jump to: navigation, search Logo: Kenya-Developing Energy Enterprises Project (DEEP) Name Kenya-Developing Energy Enterprises Project...

  6. Deep Borehole Disposal of Nuclear Waste. (Conference) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    Deep Borehole Disposal of Nuclear Waste. Citation Details In-Document Search Title: Deep Borehole Disposal of Nuclear Waste. Abstract not provided. Authors: Arnold, Bill Walter ;...

  7. Method and apparatus for injecting particulate media into the ground

    DOE Patents [OSTI]

    Dwyer, Brian P.; Dwyer, Stephen F.; Vigil, Francine S.; Stewart, Willis E.

    2004-12-28

    An improved method and apparatus for injecting particulate media into the ground for constructing underground permeable reactive barriers, which are used for environmental remediation of subsurface contaminated soil and water. A media injector sub-assembly attached to a triple wall drill string pipe sprays a mixture of active particulate media suspended in a carrier fluid radially outwards from the sub-assembly, at the same time that a mixing fluid is sprayed radially outwards. The media spray intersects the mixing spray at a relatively close distance from the point of injection, which entrains the particulate media into the mixing spray and ensures a uniform and deep dispersion of the active media in the surrounding soil. The media injector sub-assembly can optionally include channels for supplying compressed air to an attached down-the-hole hammer drive assembly for use during drilling.

  8. Buried Anode Device Development: Cooperative Research and Development Final Report, CRADA Number CRD-11-451

    SciTech Connect (OSTI)

    Tenent, R.

    2015-03-01

    The possibility of a reflecting electrochromic device is very attractive, and the 'Buried Anode' architecture developed at NREL could yield such a device. The subject of this cooperative agreement will be the development and refinement of a Buried Anode device process. This development will require the active involvement of NREL and US e-Chromic personnel, and will require the use of NREL equipment as much as possible. When this effort is concluded, US e-Chromic will have enough information to construct a pilot production line, where further development can continue.

  9. Hard carbon nanoparticles as high-capacity, high-stability anodic materials

    Office of Scientific and Technical Information (OSTI)

    for Na-ion batteries (Journal Article) | SciTech Connect Hard carbon nanoparticles as high-capacity, high-stability anodic materials for Na-ion batteries Citation Details In-Document Search Title: Hard carbon nanoparticles as high-capacity, high-stability anodic materials for Na-ion batteries Hard carbon nanoparticles (HCNP) were synthesized by the pyrolysis of a polyaniline precursor. The measured Na+ cation diffusion coefficient (10-13-10-15cm2s-1) in the HCNP obtained at 1150 °C is two

  10. In-situ TEM study of sodiation and failure mechanism of Sb anodes.

    Office of Scientific and Technical Information (OSTI)

    (Conference) | SciTech Connect In-situ TEM study of sodiation and failure mechanism of Sb anodes. Citation Details In-Document Search Title: In-situ TEM study of sodiation and failure mechanism of Sb anodes. Abstract not provided. Authors: XueHai Tan ; Jungjohann, Katherine Leigh ; Mook, William ; David Mitlin Publication Date: 2014-09-01 OSTI Identifier: 1241666 Report Number(s): SAND2014-18008D 537710 DOE Contract Number: AC04-94AL85000 Resource Type: Conference

  11. Fabrication of copper-based anodes via atmosphoric plasma spraying techniques

    DOE Patents [OSTI]

    Lu, Chun (Monroeville, PA)

    2012-04-24

    A fuel electrode anode (18) for a solid oxide fuel cell is made by presenting a solid oxide fuel cell having an electrolyte surface (15), mixing copper powder with solid oxide electrolyte in a mixing step (24, 44) to provide a spray feedstock (30,50) which is fed into a plasma jet (32, 52) of a plasma torch to melt the spray feed stock and propel it onto an electrolyte surface (34, 54) where the spray feed stock flattens into lamellae layer upon solidification, where the layer (38, 59) is an anode coating with greater than 35 vol. % based on solids volume.

  12. Transparent TiO2 nanotube array photoelectrodes prepared via two-step anodization

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kim, Jin Young; Zhu, Kai; Neale, Nathan R.; Frank, Arthur J.

    2014-04-04

    Two-step anodization of transparent TiO2 nanotube arrays has been demonstrated with aid of a Nb-doped TiO2 buffer layer deposited between the Ti layer and TCO substrate. Enhanced physical adhesion and electrochemical stability provided by the buffer layer has been found to be important for successful implementation of the two-step anodization process. As a result, with the proposed approach, the morphology and thickness of NT arrays could be controlled very precisely, which in turn, influenced their optical and photoelectrochemical properties.

  13. Anodic activation of niobium and tantalum in phosphate-fluoride solutions

    SciTech Connect (OSTI)

    Bairachnyi, B.I.; Stepanova, I.I.

    1988-01-10

    An analysis of the polarization curves for the anodic dissolution of niobium and tantalum in the coordinates showed they are described by Fafel's equation with a slop of the linear sections of -0.125 for niobium and -0.123 for tantalum. In solutions that contained hydrofluoric acid the anodic-anionic polarization of niobium and tantalum was accompanied by the destruction of the oxide film by the fluoride ions and dissolution of the metal phase. Effects of polishing and glossing of the surface of the investigated metals were observed at certain conditions.

  14. Material and Energy Flows in the Production of Cathode and Anode Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for Lithium Ion Batteries (Technical Report) | SciTech Connect Material and Energy Flows in the Production of Cathode and Anode Materials for Lithium Ion Batteries Citation Details In-Document Search Title: Material and Energy Flows in the Production of Cathode and Anode Materials for Lithium Ion Batteries Authors: Dunn, Jennifer B. ; James, Christine ; Gaines, L G ; Gallagher, Kevin Publication Date: 2014-09-30 OSTI Identifier: 1172039 Report Number(s): ANL/ESD-14/10 108520 DOE Contract

  15. Geek-Up[08.20.10] -- Turning Trash Bags into Battery Anodes and Researching

    Office of Environmental Management (EM)

    the Gut Microbiome | Department of Energy 8.20.10] -- Turning Trash Bags into Battery Anodes and Researching the Gut Microbiome Geek-Up[08.20.10] -- Turning Trash Bags into Battery Anodes and Researching the Gut Microbiome August 20, 2010 - 5:18pm Addthis Elizabeth Meckes Elizabeth Meckes Director of User Experience & Digital Technologies, Office of Public Affairs What are the key facts? An Argonne Scholar has figured out a way to convert grocery bags into carbon nanotubes that can be

  16. Energy storage devices having anodes containing Mg and electrolytes utilized therein

    DOE Patents [OSTI]

    Shao, Yuyan; Liu, Jun

    2015-08-18

    For a metal anode in a battery, the capacity fade is a significant consideration. In energy storage devices having an anode that includes Mg, the cycling stability can be improved by an electrolyte having a first salt, a second salt, and an organic solvent. Examples of the organic solvent include diglyme, triglyme, tetraglyme, or a combination thereof. The first salt can have a magnesium cation and be substantially soluble in the organic solvent. The second salt can enhance the solubility of the first salt and can have a magnesium cation or a lithium cation. The first salt, the second salt, or both have a BH.sub.4 anion.

  17. Hard Carbon Materials for High-Capacity Li-ion Battery Anodes | Department

    Office of Environmental Management (EM)

    of Energy Hard Carbon Materials for High-Capacity Li-ion Battery Anodes Hard Carbon Materials for High-Capacity Li-ion Battery Anodes 2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon es104_dai_2011_o.pdf More Documents & Publications Vehicle Technologies Office Merit Review 2015: A Combined Experimental and Modeling Approach for the Design of High Coulombic Efficiency Si Electrodes In situ Characterizations of New

  18. North Village Ground Source Heat Pumps

    Broader source: Energy.gov [DOE]

    Overview: Installation of Ground Source Heat Pumps. Replacement of Aging Heat Pumps. Alignment with Furmans Sustainability Goals.

  19. Ground Magnetics (Nannini, 1986) | Open Energy Information

    Open Energy Info (EERE)

    to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Ground Magnetics (Nannini, 1986) Exploration Activity Details Location Unspecified Exploration...

  20. Tritium Ground Water Issues | Department of Energy

    Office of Environmental Management (EM)

    Ground Water Issues Tritium Ground Water Issues Presentation from the 35th Tritium Focus Group Meeting held in Princeton, New Jersey on May 05-07, 2015. PDF icon Tritium Ground Water Issues More Documents & Publications Managing Uncertainty and Demonstrating Compliance EA-1356: Final Environmental Assessment SRS FTF Section 3116 Basis for Determination

  1. p-Type semiconducting nickel oxide as an efficiency-enhancing anodal interfacial layer in bulk heterojunction solar cells

    DOE Patents [OSTI]

    Irwin, Michael D; Buchholz, Donald B; Marks, Tobin J; Chang, Robert P. H.

    2014-11-25

    The present invention, in one aspect, relates to a solar cell. In one embodiment, the solar cell includes an anode, a p-type semiconductor layer formed on the anode, and an active organic layer formed on the p-type semiconductor layer, where the active organic layer has an electron-donating organic material and an electron-accepting organic material.

  2. Parasitic corrosion resistant anode for use in metal/air or metal/O.sub.2 cells

    DOE Patents [OSTI]

    Joy, Richard W.; Smith, David F.

    1983-01-01

    A consumable metal anode which is used in refuelable electrochemical cells and wherein at least a peripheral edge portion of the anode is protected against a corrosive alkaline environment of the cell by the application of a thin metal coating, the coating being formed of metals such as nickel, silver, and gold.

  3. Parasitic corrosion-resistant anode for use in metal/air or metal/O/sub 2/ cells

    DOE Patents [OSTI]

    Joy, R.W.; Smith, D.F.

    1982-09-20

    A consumable metal anode is described which is used in refuelable electrochemical cells and wherein at least a peripheral edge portion of the anode is protected against a corrosive alkaline environment of the cell by the application of a thin metal coating, the coating being formed of metals such as nickel, silver, and gold.

  4. Silicon-tin oxynitride glassy composition and use as anode for lithium-ion battery

    DOE Patents [OSTI]

    Neudecker, Bernd J. (Knoxville, TN); Bates, John B. (Oak Ridge, TN)

    2001-01-01

    Disclosed are silicon-tin oxynitride glassy compositions which are especially useful in the construction of anode material for thin-film electrochemical devices including rechargeable lithium-ion batteries, electrochromic mirrors, electrochromic windows, and actuators. Additional applications of silicon-tin oxynitride glassy compositions include optical fibers and optical waveguides.

  5. Manipulating the Surface Reactions in Lithium Sulfur Batteries Using Hybrid Anode Structures

    SciTech Connect (OSTI)

    Huang, Cheng; Xiao, Jie; Shao, Yuyan; Zheng, Jianming; Bennett, Wendy D.; Lu, Dongping; Saraf, Laxmikant V.; Engelhard, Mark H.; Ji, Liwen; Zhang, Jiguang; Li, Xiaolin; Graff, Gordon L.; Liu, Jun

    2014-01-09

    Lithium-sulfur (Li-S) batteries have recently attracted extensive attention due to the high theoretical energy density and potential low cost. Even so, significant challenges prevent widespread adoption, including continuous dissolution and consumption of active sulfur during cycling. Here we present a fundamentally new design using electrically connected graphite and lithium metal as a hybrid anode to control undesirable surface reactions on the anode. The lithiated graphite placed in front of the lithium metal functions as an artificial self-regulated solid electrolyte interface (SEI) layer to actively control the electrochemical reaction while minimizing the deleterious side reactions on the surface and bulk lithium metal. Continuous corrosion and contamination of lithium anode by dissolved polysulfides is largely mitigated. Excellent electrochemical performance has been observed. Li-S cell incorporating the hybrid design retain a capacity of more than 800 mAh g-1 for 400 cycles, corresponding to only 11% fade and a Coulombic efficiency above 99%. This simple hybrid concept may also provide new lessons for protecting metal anodes in other energy storage devices.

  6. Uncertainty Studies of Real Anode Surface Area in Computational Analysis for Molten Salt Electrorefining

    SciTech Connect (OSTI)

    Sungyeol Choi; Jaeyeong Park; Robert O. Hoover; Supathorn Phongikaroon; Michael F. Simpson; Kwang-Rag Kim; Il Soon Hwang

    2011-09-01

    This study examines how much cell potential changes with five differently assumed real anode surface area cases. Determining real anode surface area is a significant issue to be resolved for precisely modeling molten salt electrorefining. Based on a three-dimensional electrorefining model, calculated cell potentials compare with an experimental cell potential variation over 80 hours of operation of the Mark-IV electrorefiner with driver fuel from the Experimental Breeder Reactor II. We succeeded to achieve a good agreement with an overall trend of the experimental data with appropriate selection of a mode for real anode surface area, but there are still local inconsistencies between theoretical calculation and experimental observation. In addition, the results were validated and compared with two-dimensional results to identify possible uncertainty factors that had to be further considered in a computational electrorefining analysis. These uncertainty factors include material properties, heterogeneous material distribution, surface roughness, and current efficiency. Zirconium's abundance and complex behavior have more impact on uncertainty towards the latter period of electrorefining at given batch of fuel. The benchmark results found that anode materials would be dissolved from both axial and radial directions at least for low burn-up metallic fuels after active liquid sodium bonding was dissolved.

  7. Field performance of sprayed zinc anodes in controlling corrosion of steel reinforced concrete

    SciTech Connect (OSTI)

    Tinnea, J.

    1998-12-31

    The deterioration of concrete structures often results from the corrosion of their steel reinforcement. Cathodic protection (CP) is a proven means to stop rebar corrosion. One anode material gaining acceptance in the infrastructure corrosion fight is zinc thermal spray coating. This paper discusses an investigation of such CP systems.

  8. Deep Energy Retrofits & State Applications | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Deep Energy Retrofits & State Applications Deep Energy Retrofits & State Applications This presentation, given through the DOE's Technical Assitance Program (TAP), provides information on Deep Energy Retrofits & State Applications PDF icon deepenergyretrofitsandstateapplications.pdf More Documents & Publications Deep Energy Retrofits & State Applications Energy Efficiency In Correctional Facilities & Opportunities for State Energy Office Engagement

  9. Generic Deep Geologic Disposal Safety Case | Department of Energy

    Office of Environmental Management (EM)

    Deep Geologic Disposal Safety Case Generic Deep Geologic Disposal Safety Case The Generic Deep Geologic Disposal Safety Case presents generic information that is of use in understanding potential deep geologic disposal options in the U.S. for used nuclear fuel (UNF) from reactors and high-level radioactive waste (HLW). Potential disposal options include mined disposal in a variety of geologic media (e.g., salt, shale, granite), and deep borehole disposal in basement rock. The Generic Safety Case

  10. New proppant for deep hydraulic fracturing

    SciTech Connect (OSTI)

    Underdown, D.R.; Das, K.

    1982-01-01

    Much work has been done in the development and evaluation of various materials for use as proppants for hydraulic fracturing. Sand is most often used as a frac proppant in shallow wells. Deep wells having high closure stresses require a proppant such as sintered bauxite which will not crush under such adverse conditions. Proppants such as ceramic and zirconium oxide beads and resin coated sand have been developed for deep hydraulic fracturing; however, use of these materials has been limited. A new frac proppant has been developed which exhibits the properties necessary for use in deep hydraulic fracturing. This frac proppant is produced by precuring a specially modified phenol-formaldehyde resin onto sand. The new frac proppant maintains conductivity and resists crushing, similar to that of sintered bauxite at high closure stress. 11 references.

  11. New proppant for deep hydraulic fracturing

    SciTech Connect (OSTI)

    Das, K.; Underdown, D.R.

    1985-01-01

    Much work has focused on developing and evaluating various materials for use as proppants for hydraulic fracturing. Sand is used most often as a fracturing proppant in shallow wells. Deep wells with high closure stresses require a proppant, such as sintered bauxite, that will not crush under adverse conditions. Ceramic and zirconium oxide beads and resin-coated sand proppants also have been developed for deep hydraulic fracturing. A new fracturing proppant has been developed that exhibits the properties necessary for use in deep hydraulic fracturing. This proppant is produced by precuring a specially modified phenolformaldehyde resin onto sand. The new proppant maintains conductivity and resists crushing much better than does sand. The new proppant was compared to intermediate-density sintered bauxitic proppants and cured-in-place proppants and the tests were confirmed by an independent laboratory.

  12. On using rational enzyme redesign to improve enzyme-mediated microbial dehalogenation of recalcitrant substances in deep-subsurface environments

    SciTech Connect (OSTI)

    Ornstein, R.L.

    1993-06-01

    Heavily halogenated hydrocarbons are one of the most prevalent classes of man-made recalcitrant environmental contaminants and often make their way into subsurface environments. Biodegradation of heavily chlorinated compounds in the deep subsurface often occurs at extremely slow rates because native enzymes of indigenous microbes are unable to efficiently metabolize such synthetic substances. Cost-effective engineering solutions do not exist for dealing with disperse and recalcitrant pollutants in the deep subsurface (i.e., ground water, soils, and sediments). Timely biodegradation of heavily chlorinated compounds in the deep subsurface may be best accomplished by rational redesign of appropriate enzymes that enhance the ability of indigenous microbes to metabolize these substances. The isozyme family cytochromes P450 are catalytically very robust and are found in all aerobic life forms and may be active in may anaerobes as well. The author is attempting to demonstrate proof-of-principle rational enzyme redesign of cytochromes P450 to enhance biodehalogenation.

  13. Deep Energy Retrofit Case Studies: Lessons Learned

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Deep Energy Retrofit Case Studies: Lessons Learned. Alea German Alliance for Residential Building Innovation June 25, 2014 Davis Energy Group | June 25, 2014 ‹#› Agenda * Background / motivation * Results from 3 CA retrofits - Sonoma Passive House Retrofit - Stockton Hot Dry Retrofit - Sunnyvale Marine Deep Retrofit Davis Energy Group | June 25, 2014 ‹#› Background * >60 million homes in the U.S. over 30 yrs old * Huge potential - Energy savings ‹#› Davis Energy Group | June 25,

  14. Promising Technology: Ground Source Heat Pumps

    Broader source: Energy.gov [DOE]

    Ground source heat pumps (GSHP) use the constant temperature of the Earth as the heat exchange medium instead of the outside air temperature. During the winter, a GSHP uses the ground as a heat source to provide heating, and during the summer, a GSHP uses the ground as a heat sink to provide cooling. Although more expensive than air-source heat pumps, GSHP’s are much more efficient, especially in cold temperatures.

  15. Remediation of Uranium-Contaminated Ground Water

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    costs, are highly energy efficient, and require no surface facilities or ground water pumpingrecharge (Freethey et al., 2002; Morrison and Spangler, 1992; Shoemaker et al., 1995). ...

  16. Posters Ground-Based Radiometric Observations

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    data have also complemented other remote sensors such as K-band cloud Doppler radar and Doppler lidar. In addition, radiometric observations compose a database of ground- truth...

  17. Pacific Northwest National Laboratory Grounds Maintenance

    SciTech Connect (OSTI)

    2009-08-05

    FEMP Water Efficiency Best Management Practice #4 and #5: Case study overview of the grounds maintenance program for Pacific Northwest National Laboratory.

  18. Ground Gravity Survey | Open Energy Information

    Open Energy Info (EERE)

    Et Al., 2000) Dixie Valley Geothermal Area 1999 2000 Precise Gravimetry and Geothermal Reservoir Management Ground Gravity Survey At Dixie Valley Geothermal Area (Blackwell, Et...

  19. Ground Control Progress Continues at WIPP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    December 4, 2015 Ground Control Progress Continues at WIPP Underground Operations Personnel at the Waste Isolation Pilot Plant (WIPP) have made significant progress since resuming...

  20. Enclosed ground-flare incinerator

    DOE Patents [OSTI]

    Wiseman, Thomas R. (Calgary, CA)

    2000-01-01

    An improved ground flare is provided comprising a stack, two or more burner assemblies, and a servicing port so that some of the burner assemblies can be serviced while others remain in operation. The burner assemblies comprise a burner conduit and nozzles which are individually fitted to the stack's burner chamber and are each removably supported in the chamber. Each burner conduit is sealed to and sandwiched between a waste gas inlet port and a matching a closure port on the other side of the stack. The closure port can be opened for physically releasing the burner conduit and supplying sufficient axial movement room for extracting the conduit from the socket, thereby releasing the conduit for hand removal through a servicing port. Preferably, the lower end of the stack is formed of one or more axially displaced lower tubular shells which are concentrically spaced for forming annular inlets for admitting combustion air. An upper tubular exhaust stack, similarly formed, admits additional combustion air for increasing the efficiency of combustion, increasing the flow of exhausted for improved atmospheric dispersion and for cooling the upper stack.

  1. Stepped frequency ground penetrating radar

    DOE Patents [OSTI]

    Vadnais, Kenneth G.; Bashforth, Michael B.; Lewallen, Tricia S.; Nammath, Sharyn R.

    1994-01-01

    A stepped frequency ground penetrating radar system is described comprising an RF signal generating section capable of producing stepped frequency signals in spaced and equal increments of time and frequency over a preselected bandwidth which serves as a common RF signal source for both a transmit portion and a receive portion of the system. In the transmit portion of the system the signal is processed into in-phase and quadrature signals which are then amplified and then transmitted toward a target. The reflected signals from the target are then received by a receive antenna and mixed with a reference signal from the common RF signal source in a mixer whose output is then fed through a low pass filter. The DC output, after amplification and demodulation, is digitized and converted into a frequency domain signal by a Fast Fourier Transform. A plot of the frequency domain signals from all of the stepped frequencies broadcast toward and received from the target yields information concerning the range (distance) and cross section (size) of the target.

  2. Chemically Bonded Phosphorus/Graphene Hybrid as a High Performance Anode for Sodium-Ion Batteries

    SciTech Connect (OSTI)

    Song, Jiangxuan; Yu, Zhaoxin; Gordin, Mikhail; Hu, Shilin; Yi, Ran; Tang, Duihai; Walter, Timothy; Regula, Michael; Choi, Daiwon; Li, Xiaolin; Manivannan, Ayyakkannu; Wang, Donghai

    2014-11-12

    Room temperature sodium-ion batteries are of great interest for high-energy-density energy storage systems because of low-cost, natural abundance of sodium. Here, we report a novel graphene nanosheets-wrapped phosphorus composite as an anode for high performance sodium-ion batteries though a facile ball-milling of red phosphorus and graphene nanosheets. Not only can the graphene nanosheets significantly improve the electrical conductivity, but they also serve as a buffer layer to accommodate the large volume change of phosphorus in the charge-discharge process. As a result, the graphene wrapped phosphorus composite anode delivers a high reversible capacity of 2077 mAh/g with excellent cycling stability (1700 mAh/g after 60 cycles) and high Coulombic efficiency (>98%). This simple synthesis approach and unique nanostructure can potentially extend to other electrode materials with unstable solid electrolyte interphases in sodium-ion batteries.

  3. NANOSTRUCTURED METAL OXIDES FOR ANODES OF LI-ION RECHARGEABLE BATTERIES

    SciTech Connect (OSTI)

    Au, M.

    2009-12-04

    The aligned nanorods of Co{sub 3}O{sub 4} and nanoporous hollow spheres (NHS) of SnO{sub 2} and Mn{sub 2}O{sub 3} were investigated as the anodes for Li-ion rechargeable batteries. The Co{sub 3}O{sub 4} nanorods demonstrated 1433 mAh/g reversible capacity. The NHS of SnO{sub 2} and Mn{sub 2}O{sub 3} delivered 400 mAh/g and 250 mAh/g capacities respectively in multiple galvonastatic discharge-charge cycles. It was found that high capacity of NHS of metal oxides is sustainable attributed to their unique structure that maintains material integrity during cycling. The nanostructured metal oxides exhibit great potential as the new anode materials for Li-ion rechargeable batteries with high energy density, low cost and inherent safety.

  4. Using Heteropolyacids in the Anode Catalyst Layer of Dimethyl Ether PEM Fuel Cells

    SciTech Connect (OSTI)

    Ferrell III, J. R.; Turner, J. A.; Herring, A. M.

    2008-01-01

    In this study, polarization experiments were performed on a direct dimethyl ether fuel cell (DMEFC). The experimental setup allowed for independent control of water and DME flow rates. Thus the DME flow rate, backpressure, and water flow rate were optimized. Three heteropoly acids, phosphomolybdic acid (PMA), phosphotungstic acid (PTA), and silicotungstic acid (STA) were incorporated into the anode catalyst layer in combination with Pt/C. Both PTA-Pt and STA-Pt showed higher performance than the Pt control at 30 psig of backpressure. Anodic polarizations were also performed, and Tafel slopes were extracted from the data. The trends in the Tafel slope values are in agreement with the polarization data. The addition of phosphotungstic acid more than doubled the power density of the fuel cell, compared to the Pt control.

  5. Effect of entropy of lithium intercalation in cathodes and anodes on Li-ion battery thermal management

    SciTech Connect (OSTI)

    Viswanathan, Vilayanur V; Choi, Daiwon; Wang, Donghai; Xu, Wu; Towne, Silas A; Williford, Ralph E; Zhang, Jiguang; Liu, Jun; Yang, Zhenguo

    2010-06-01

    The entropy changes (ΔS) in various cathode and anode materials, as well as complete Li-ion batteries, were measured using an electrochemical thermodynamic measurement system (ETMS). LiCoO2 has a much larger entropy change than electrodes based on LiNixCoyMnzO2 and LiFePO4, while lithium titanate based anode has lower entropy change compared to graphite anodes. Reversible heat generation rate was found to be a significant portion of the total heat generation rate. The appropriate combinations of cathode and anode were investigated to minimize reversible heat.

  6. Hanford Progresses in Burial Ground Cleanup

    Broader source: Energy.gov [DOE]

    RICHLAND, Wash. – EM’s Richland Operations Office (RL) and cleanup contractor Washington Closure Hanford (WCH) are making tremendous progress cleaning up Hanford’s 618-10 Burial Ground, one of the most hazardous burial grounds in the EM complex.

  7. Procedures for ground-water investigations

    SciTech Connect (OSTI)

    Not Available

    1992-12-01

    This manual was developed by the Pacific Northwest Laboratory (PNL) to document the procedures used to carry out and control the technical aspects of ground-water investigations at the PNL. Ground-water monitoring procedures are developed and used in accordance with the PNL Quality Assurance Program.

  8. Hybrid Nano Carbon Fiber/Graphene Platelet-Based High-Capacity Anodes for

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Lithium Ion Batteries | Department of Energy 1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon es009_jang_2011_o.pdf More Documents & Publications Hybrid Nano Carbon Fiber/Graphene Platelet-Based High-Capacity Anodes for Lithium Ion Batteries Progress of DOE Materials, Manufacturing Process R&D, and ARRA Battery Manufacturing Grants 2010 DOE EERE Vehicle Technologies Program Merit Review - Energy Storage

  9. Chemically Bonded Phosphorus/Graphene Hybrid as a High Performance Anode

    Office of Scientific and Technical Information (OSTI)

    for Sodium-Ion Batteries (Journal Article) | SciTech Connect Room temperature sodium-ion batteries are of great interest for high-energy-density energy storage systems because of low-cost, natural abundance of sodium. Here, we report a novel graphene nanosheets-wrapped phosphorus composite as an anode for high performance sodium-ion batteries though a facile ball-milling of red phosphorus and graphene nanosheets. Not only can the graphene nanosheets significantly improve the electrical

  10. Using SiO Anodes for High Capacity, High Rate Electrodes for Lithium Ion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Batteries - Energy Innovation Portal Using SiO Anodes for High Capacity, High Rate Electrodes for Lithium Ion Batteries Lawrence Berkeley National Laboratory Contact LBL About This Technology Technology Marketing Summary Berkeley Lab developed an elegant and inexpensive fabrication method for high performance electrodes with unmatched specific / areal capacities and good capacity retention for application in lithium ion batteries. Description A team of Berkeley Lab researchers led by Gao Liu

  11. Thermal-sprayed zinc anodes for cathodic protection of steel-reinforced concrete bridges

    SciTech Connect (OSTI)

    Bullard, Sophie J.; Covino, Bernard S., Jr.; Cramer, Stephen D.; McGill, Galen E.

    1996-01-01

    Thermal-sprayed zinc anodes are being used in Oregon in impressed current cathodic protection (ICCP) systems for reinforced concrete bridges. The U.S. Department of Energy, Albany Research Center, is collaborating with the Oregon Department of Transportation (ODOT) to evaluate the long-term performance and service life of these anodes. Laboratory studies were conducted on concrete slabs coated with 0.5 mm (20 mil) thick, thermal-sprayed zinc anodes. The slabs were electrochemically aged at an accelerated rate using an anode current density of 0.032 A/m2 (3mA/ft2). Half the slabs were preheated before thermal-spraying with zinc; the other half were unheated. Electrochemical aging resulted in the formation at the zinc-concrete interface of a thin, low pH zone (relative to cement paste) consisting primarily of ZnO and Zn(OH)2, and in a second zone of calcium and zinc aluminates and silicates formed by secondary mineralization. Both zones contained elevated concentrations of sulfate and chloride ions. The original bond strength of the zinc coating decreased due to the loss of mechanical bond to the concrete with the initial passage of electrical charge (aging). Additional charge led to an increase in bond strength to a maximum as the result of secondary mineralization of zinc dissolution products with the cement paste. Further charge led to a decrease in bond strength and ultimately coating disbondment as the interfacial reaction zones continued to thicken. This occurred at an effective service life of 27 years at the 0.0022 A/m2 (0.2 mA/ft2) current density typically used by ODOT in ICCP systems for coastal bridges. Zinc coating failure under tensile stress was primarily cohesive within the thickening reaction zones at the zinc-concrete interface. There was no difference between the bond strength of zinc coatings on preheated and unheated concrete surfaces after long service times.

  12. Better Ham & Cheese: Enhanced Anodes and Cathodes for Fuel Cells > Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Highlights > Research > The Energy Materials Center at Cornell Research Highlights In This Section The Structural Evolution and Diffusion During the Chemical Transformation from Cobalt to Cobalt Phosphide Nanoparticles Joint Density-Functional Theory of Electrochemistry Double-band Electrode Channel Flow DEMS Cell Sulfur@Carbon Cathodes for Lithium Sulfur Batteries Better Ham & Cheese: Enhanced Anodes and Cathodes for Fuel Cells Epitaxial Single Crystal Nanostructures for Batteries

  13. Final Report: Novel ALD-Coated Nanoparticle Anodes for Enhanced Performance Lithium-Ion Batteries

    SciTech Connect (OSTI)

    Groner, Markus

    2009-04-16

    The Phase I effort is described in detail in the Phase I report given below. The key accomplishments of the Phase I project were (1) the demonstration of high stability LiCoO2 cathodes using ALD-coated LiCoO2 particles, as well as on ALD-coated LiCoO2 electrodes and (2) the demonstration of high stability of graphite anodes using ALD-coated graphite electrodes.

  14. Cerium-modified doped strontium titanate compositions for solid oxide fuel cell anodes and electrodes for other electrochemical devices

    DOE Patents [OSTI]

    Marina, Olga A [Richland, WA; Stevenson, Jeffry W [Richland, WA

    2010-03-02

    The present invention provides novel compositions that find advantageous use in making electrodes for electrochemical cells and electrochemical devices such as solid oxide fuel cells, electrolyzers, sensors, pumps and the like, the compositions comprising cerium-modified doped strontium titanate. The invention also provides novel methods for making and using anode material compositions and solid oxide fuel cells and solid oxide fuel cell assemblies having anodes comprising the compositions.

  15. Cerium-modified doped strontium titanate compositions for solid oxide fuel cell anodes and electrodes for other electrochemical devices

    DOE Patents [OSTI]

    Marina, Olga A [Richland, WA; Stevenson, Jeffry W [Richland, WA

    2010-11-23

    The present invention provides novel compositions that find advantageous use in making electrodes for electrochemical cells and electrochemical devices such as solid oxide fuel cells, electrolyzers, sensors, pumps and the like, the compositions comprising cerium-modified doped strontium titanate. The invention also provides novel methods for making and using anode material compositions and solid oxide fuel cells and solid oxide fuel cell assemblies having anodes comprising the compositions.

  16. Composite solid oxide fuel cell anode based on ceria and strontium titanate

    DOE Patents [OSTI]

    Marina, Olga A. (Richland, WA); Pederson, Larry R. (Richland, WA)

    2008-12-23

    An anode and method of making the same wherein the anode consists of two separate phases, one consisting of a doped strontium titanate phase and one consisting of a doped cerium oxide phase. The strontium titanate phase consists of Sr.sub.1-xM.sub.xTiO.sub.3-.delta., where M is either yttrium (Y), scandium (Sc), or lanthanum (La), where "x" may vary typically from about 0.01 to about 0.5, and where .delta. is indicative of some degree of oxygen non-stoichiometry. A small quantity of cerium may also substitute for titanium in the strontium titanate lattice. The cerium oxide consists of N.sub.yCe.sub.1-yO.sub.2-.delta., where N is either niobium (Nb), vanadium (V), antimony (Sb) or tantalum (Ta) and where "y" may vary typically from about 0.001 to about 0.1 and wherein the ratio of Ti in said first phase to the sum of Ce and N in the second phase is between about 0.2 to about 0.75. Small quantities of strontium, yttrium, and/or lanthanum may additionally substitute into the cerium oxide lattice. The combination of these two phases results in better performance than either phase used separately as an anode for solid oxide fuel cell or other electrochemical device.

  17. Porous Si spheres encapsulated in carbon shells with enhanced anodic performance in lithium-ion batteries

    SciTech Connect (OSTI)

    Wang, Hui; Wu, Ping, E-mail: zjuwuping@njnu.edu.cn; Shi, Huimin; Lou, Feijian; Tang, Yawen; Zhou, Tongge; Zhou, Yiming, E-mail: zhouyiming@njnu.edu.cn; Lu, Tianhong

    2014-07-01

    Highlights: In situ magnesiothermic reduction route for the formation of porous Si@C spheres. Unique microstructural characteristics of both porous sphere and carbon matrix. Enhanced anodic performance in term of cycling stability for lithium-ion batteries. - Abstract: A novel type of porous SiC micro/nano-hybrids, i.e., porous Si spheres encapsulated in carbon shells (porous Si@C spheres), has been constructed through the pyrolysis of polyvinylidene fluoride (PVDF) and subsequent magnesiothermic reduction methodology by using SiO{sub 2} spheres as precursors. The as-synthesized porous Si@C spheres have been applied as anode materials for lithium-ion batteries (LIBs), and exhibit enhanced anodic performance in term of cycling stability compared with bare Si spheres. For example, the porous Si@C spheres are able to exhibit a high reversible capacity of 900.0 mA h g{sup ?1} after 20 cycles at a current density of 0.05 C (1 C = 4200 mA g{sup ?1}), which is much higher than that of bare Si spheres (430.7 mA h g{sup ?1})

  18. Basic properties of a liquidt in anode solid oxide fuel cell

    SciTech Connect (OSTI)

    Harry Abernathy; RandallGemmen; KirkGerdes; Mark Koslowske; ThomasTao

    2010-12-17

    An unconventional high temperature fuel cell system, the liquidt in anode solid oxide fuel cell(LTA-SOFC), is discussed. A thermodynamic analysis of a solid oxide fuel cell with a liquid metal anode is developed. Pertinent thermo chemical and thermo physical properties of liquid tin in particular are detailed. An experimental setup for analysis of LTA-SOFC anode kinetics is described, and data for a planar cell under hydrogen indicated an effective oxygen diffusion coefficient of 5.310?5 cm2 s?1 at 800 ?C and 8.910?5 cm2 s?1 at 900 ?C. This value is similar to previously reported literature values for liquid tin. The oxygen conductivity through the tin, calculated from measured diffusion coefficients and theoretical oxygen solubility limits, is found to be on the same order of thatofyttria-stabilizedzirconia(YSZ), a traditional SOFC electrolyte material. As such,the ohmicloss due to oxygen transport through the tin layer must be considered in practical system cell design since the tin layer will usually be at least as thick as the electrolyte.

  19. Generalized Bohms criterion and negative anode voltage fall in electric discharges

    SciTech Connect (OSTI)

    Londer, Ya. I.; Ulyanov, K. N.

    2013-10-15

    The value of the voltage fall across the anode sheath is found as a function of the current density. Analytic solutions are obtained in a wide range of the ratio of the directed velocity of plasma electrons v{sub 0} to their thermal velocity v{sub T}. It is shown that the voltage fall in a one-dimensional collisionless anode sheath is always negative. At the small values of v{sub 0}/v{sub T}, the obtained expression asymptotically transforms into the Langmuir formula. Generalized Bohms criterion for an electric discharge with allowance for the space charge density ?(0), electric field E(0), ion velocity v{sub i}(0), and ratio v{sub 0}/v{sub T} at the plasma-sheath interface is formulated. It is shown that the minimum value of the ion velocity v{sub i}{sup *}(0) corresponds to the vanishing of the electric field at one point inside the sheath. The dependence of v{sub i}{sup *} (0) on ?(0), E(0), and v{sub 0}/v{sub T} determines the boundary of the existence domain of stationary solutions in the sheath. Using this criterion, the maximum possible degree of contraction of the electron current at the anode is determined for a short high-current vacuum arc discharge.

  20. Molecular-Level Insights into the Reactivity of Siloxane-Based Electrolytes at a Lithium-Metal Anode

    SciTech Connect (OSTI)

    Assary, Rajeev S.; Lu, Jun; Luo, Xiangyi; Zhang, Xiaoyi; Ren, Yang; Wu, Huiming; Albishri, Hassan M.; El-Hady, D. A.; Al-Bogami, A. S.; Curtiss, Larry A.; Amine, Khalil

    2014-07-21

    A molecular-level understanding of the reactions that occur at the lithium-metal anode/electrolyte interphase is essential to improve the performance of LiO2 batteries. Experimental and computational techniques are applied to explore the reactivity of tri(ethylene glycol)-substituted trimethylsilane (1NM3), a siloxane-based ether electrolyte, at the lithium-metal anode. In situ/ex situ X-ray diffraction and Fourier-transform infrared spectroscopy studies provide evidence of the formation of lithium hydroxide and lithium carbonates at the anode upon gradual degradation of the metallic lithium anode and the solvent molecules in the presence of oxygen. Density functional calculations performed to obtain a mechanistic understanding of the reductive decomposition of 1NM3 indicate that the decomposition does not require any apparent barrier to produce lithium hydroxide and lithium carbonates when the reduced 1NM3 solvent molecules interact with the oxygen crossing over from the cathode. This study indicates that degradation may be more significant in the case of the 1NM3 solvent, compared to linear ethers such as tetraglyme or dioxalone, because of its relatively high electron affinity. Also, both protection of the lithium metal and prevention of oxygen crossover to the anode are essential for minimizing electrolyte and anode decomposition.

  1. Document Number Q0029500 Ground Water Model 3.0 Ground Water Model

    Office of Legacy Management (LM)

    Ground Water Model 3.0 Ground Water Model This section presents a steady-state ground water flow model and a coupled solute transport model (ground water model) for the alluvial aquifer within OU 111 of the MMTS. Transport of uranium is simulated for a 50-yr period beginning October 2002. Uranium was selected among site COCs for transport modeling because it is the principal contributor to potential risk to human health. The model assumes stable ground water flow since completion of site

  2. Energy Department selects Battelle team for a deep borehole field...

    Energy Savers [EERE]

    Battelle team for a deep borehole field test in North Dakota Energy Department selects Battelle team for a deep borehole field test in North Dakota January 5, 2016 - 5:31pm ...

  3. Deep East Texas Elec Coop Inc | Open Energy Information

    Open Energy Info (EERE)

    Deep East Texas Elec Coop Inc Jump to: navigation, search Name: Deep East Texas Elec Coop Inc Place: Texas Phone Number: 1-800-392-5986 Website: www.deepeast.com Facebook: https:...

  4. Co2 Deep Store Ltd | Open Energy Information

    Open Energy Info (EERE)

    Deep Store Ltd Jump to: navigation, search Name: Co2 Deep Store Ltd Place: Scotland, United Kingdom Zip: AB11 7LH Sector: Carbon Product: UK based organization focused on the...

  5. NERSC, Berkeley Lab Explore Frontiers of Deep Learning for Science

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NERSC, Berkeley Lab Explore Frontiers of Deep Learning for Science NERSC, Berkeley Lab Explore Frontiers of Deep Learning for Science Computational Researchers Test Advanced Machine Learning Tools for HPC December 8, 2015 Contact: Kathy Kincade, kkincade@lbl.gov, 510-495-2124 braindeeplearning Researchers in Berkeley Lab's Biological Systems and Engineering Division are using a deep learning library to analyze recordings of the human brain during speech production. Image: Kris Bouchard Deep

  6. Presentation at the Weatherization Program Deep Dive Briefing, November 4,

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2009 | Department of Energy Presentation at the Weatherization Program Deep Dive Briefing, November 4, 2009 Presentation at the Weatherization Program Deep Dive Briefing, November 4, 2009 U.S. Department of Energy (DOE) Office of Energy Efficiency and Renewable Energy (EERE) Weatherization Assistance Program presentation at Weatherization Deep Dive meeting, November 4, 2009. PDF icon wap_deep_dive.pdf More Documents & Publications Designing Effective Incentives to Drive Residential

  7. Building America Webinar: A National Summary of Deep Energy Retrofits |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy A National Summary of Deep Energy Retrofits Building America Webinar: A National Summary of Deep Energy Retrofits This presentation by Brennan Less is included in the Building America webinar, Who's Successfully Doing Deep Energy Retrofits?, on June 25, 2014. PDF icon BA Webinar_less_6-25-14.pdf More Documents & Publications Building America Whole-House Solutions for Existing Homes: National Grid Deep Energy Retrofit Pilot, Massachusetts and Rhode Island (Fact Sheet)

  8. Building America Webinar: Deep Energy Retrofit Case Studies: Lessons

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Learned | Department of Energy Deep Energy Retrofit Case Studies: Lessons Learned Building America Webinar: Deep Energy Retrofit Case Studies: Lessons Learned This presentation by Alea German is included in the Building America webinar, Who's Successfully Doing Deep Energy Retrofits?, on June 25, 2014. PDF icon BA Webinar_german_6-25-14.pdf More Documents & Publications Building America Webinar: Introduction - Who's Successfully Doing Deep Energy Retrofits? Critical Question #8: When are

  9. Deep Challenges for Foundation Performance at Savannah River Site |

    Office of Environmental Management (EM)

    Department of Energy Deep Challenges for Foundation Performance at Savannah River Site Deep Challenges for Foundation Performance at Savannah River Site Deep Challenges for Foundation Performance at Savannah River Site Frank H. Syms and Brent Gutierrez October 22, 2014 PDF icon Deep Challenges for Foundation Performance at Savannah River Site More Documents & Publications H-Tank Farm Waste Determination SRS FTF Section 3116 Basis for Determination F-Tank Farm Performance Assessment, Rev

  10. Small diameter, deep bore optical inspection system

    DOE Patents [OSTI]

    Lord, David E. (Livermore, CA); Petrini, Richard R. (Livermore, CA); Carter, Gary W. (Livermore, CA)

    1981-01-01

    An improved rod optic system for inspecting small diameter, deep bores. The system consists of a rod optic system utilizing a curved mirror at the end of the rod lens such that the optical path through the system is bent 90.degree. to minimize optical distortion in examining the sides of a curved bore. The system is particularly useful in the examination of small bores for corrosion, and is capable of examining 1/16 inch diameter and up to 4 inch deep drill holes, for example. The positioning of the curved mirror allows simultaneous viewing from shallow and right angle points of observation of the same artifact (such as corrosion) in the bore hole. The improved rod optic system may be used for direct eye sighting, or in combination with a still camera or a low-light television monitor; particularly low-light color television.

  11. Benchmark field study of deep neutron penetration

    SciTech Connect (OSTI)

    Morgan, J.F.; Sale, K. ); Gold, R.; Roberts, J.H.; Preston, C.C. )

    1991-06-10

    A unique benchmark neutron field has been established at the Lawrence Livermore National Laboratory (LLNL) to study deep penetration neutron transport. At LLNL, a tandem accelerator is used to generate a monoenergetic neutron source that permits investigation of deep neutron penetration under conditions that are virtually ideal to model, namely the transport of mono-energetic neutrons through a single material in a simple geometry. General features of the Lawrence Tandem (LATAN) benchmark field are described with emphasis on neutron source characteristics and room return background. The single material chosen for the first benchmark, LATAN-1, is a steel representative of Light Water Reactor (LWR) Pressure Vessels (PV). Also included is a brief description of the Little Boy replica, a critical reactor assembly designed to mimic the radiation doses from the atomic bomb dropped on Hiroshima, and its us in neutron spectrometry. 18 refs.

  12. License for the Konrad Deep Geological Repository

    SciTech Connect (OSTI)

    Biurrun, E.; Hartje, B.

    2003-02-24

    Deep geological disposal of long-lived radioactive waste is currently considered a major challenge. Until present, only three deep geological disposal facilities have worldwide been operated: the Asse experimental repository (1967-1978) and the Morsleben repository (1971-1998) in Germany as well as the Waste Isolation Pilot Plant (WIPP) in the USA (1999 to present). Recently, the licensing procedure for the fourth such facility, the German Konrad repository, ended with a positive ''Planfeststellung'' (plan approval). With its plan approval decision, the licensing authority, the Ministry of the Environment of the state of Lower Saxony, approved the single license needed pursuant to German law to construct, operate, and later close down this facility.

  13. 118-K-1 Burial Ground - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    18-K-1 Burial Ground About Us About Hanford Cleanup Hanford History Hanford Site Wide Programs Contact Us 100 Area 118-K-1 Burial Ground 200 Area 222-S Laboratory 242-A Evaporator 300 Area 324 Building 325 Building 400 Area/Fast Flux Test Facility 618-10 and 618-11 Burial Grounds 700 Area B Plant B Reactor C Reactor Canister Storage Building and Interim Storage Area Canyon Facilities Cold Test Facility D and DR Reactors Effluent Treatment Facility Environmental Restoration Disposal Facility F

  14. Quantitative damage evaluation of localized deep pitting

    SciTech Connect (OSTI)

    Al Beed, A.A.; Al Garni, M.A.

    2000-04-01

    Localized deep pitting is considered difficult to precisely measure and evaluate using simple techniques and daily-use analysis approaches. A case study was made of carbon steel heat exchangers in a typical fresh cooling water environment that experienced severe pitting. To effectively and precisely evaluate the encountered pitting damage, a simple measurement and analyses approach was devised. In this article, the pitting measurement technique and the damage evaluation approach are presented and discussed in detail.

  15. Hawaii Deep Water Cable Program: Executive Summary

    SciTech Connect (OSTI)

    1990-09-01

    The Hawaii Deep Water Cable Program has succeeded unequivocally in determining the feasibility of deploying a submarine power cable system between the islands of Hawaii and Oahu. Major accomplishments of the program include designing, fabricating and testing an appropriate power cable, developing an integrated system to control all aspects of the cable laying operation, and testing all deployment systems at sea in the most challenging sections of the route.

  16. Completion practices in deep sour Tuscaloosa wells

    SciTech Connect (OSTI)

    Huntoon, G.G.

    1984-01-01

    Successful development of the Tuscaloosa trend in Louisiana has required unique completion practices to produce the trend's deep sour formations. Amoco's operations in the Tuscaloosa formation are between 16,000 and 21,000 ft (4877 and 6400 m), and a range of pressure environments, high temperatures, and corrosive elements is encountered. Application of proved completion practices and equipment has resulted in several techniques that enhance the safety, longevity, and production capacity of these wells. The design of deep Tuscaloosa completions is assisted by a series of correlations developed to project bottomhole and surface shut-in tubing pressures, temperature gradients, and flow capacities for deep sour wells. This paper discusses material selection, completion practices, completion fluids, wellhead equipment, packer designs, corrosion-inhibition systems, and safety and monitoring equipment used in the Tuscaloosa trend. The design of a wellhead surface installation used to detect equipment failure, to pump kill fluids, and to circulate corrosion inhibitors is reviewed. A case study illustrates the methods used in completing a Tuscaloosa well with surface pressures exceeding 16,000 psi (110.3 MPa). Deep high-pressure sour-gas wells can be completed safely if all the elements of the environment that will affect the mechanical integrity of the wellbore are considered in the completion designs. The development of higher-strength material capable of withstanding SSC is needed if wells are completed in formations deeper than 22,000 ft (6700 m). Further research is necessary on the use of alloy steels and nonferrous metals for sour service. Effective high-temperature corrosion inhibitors for heavy zinc bromide completion fluids must be developed before these brines can be used in the Tuscaloosa. The testing of new inhibitors for use in highpressure sour-gas completions should be continued.

  17. Top-emission Si-based phosphor organic light emitting diode with Au doped ultrathin n-Si film anode and bottom Al mirror

    SciTech Connect (OSTI)

    Li, Y. Z.; Xu, W. J.; Ran, G. Z. [State Key Laboratory for Mesoscopic Physics, School of Physics, Peking University, Beijing 100871 (China); Qin, G. G. [State Key Laboratory for Mesoscopic Physics, School of Physics, Peking University, Beijing 100871 (China); Key Lab of Semiconductor Materials, CAS, Beijing 100083 (China)

    2009-07-20

    We report a highly efficient top-emission Si-based phosphor organic light emitting diode (PhOLED) with an ultrathin polycrystalline n-Si:Au film anode and a bottom Al mirror. This anode is formed by magnetron sputtering followed by Ni induced crystallization and then Au diffusion. By optimizing the thickness of the n-Si:Au film anode, the Au diffusion temperature, and the other parameters of the PhOLED, the highest current and power efficiencies of the n-Si:Au film anode PhOLED reached 85{+-}9 cd/A and 80{+-}8 lm/W, respectively, corresponding to an external quantum efficiency of 21{+-}2% and a power conversion efficiency of 15{+-}2%, respectively, which are about 60% and 110% higher than those of the indium tin oxide anode counterpart and 70% and 50% higher than those of the bulk n{sup +}-Si:Au anode counterpart, respectively.

  18. Doped Yttrium Chromite-Ceria Composite as a Redox-Stable and Sulfur-Tolerant Anode for Solid Oxide Fuel Cells

    SciTech Connect (OSTI)

    Yoon, Kyung J.; Coyle, Christopher A.; Marina, Olga A.

    2011-12-11

    A Ca- and Co-doped yttrium chromite (YCCC) - samaria-doped ceria (SDC) composite was studied in relation to a potential use as a solid oxide fuel cell (SOFC) anode material. Tests performed using the yttria-stabilized zirconia (YSZ) electrolyte-supported cells revealed that the electrocatalytic activity of the YCCC-SDC anode towards hydrogen oxidation at 800 C was comparable to that of the Ni-YSZ anode. In addition, the YCCC-SDC anode exhibited superior sulfur tolerant characteristics showing less than 10% increase in a polarization resistance, fully reversible, upon exposure to 20 ppm H2S at 800 C. No performance degradation was observed during multiple reduction-oxidation (redox) cycles when the anode was intentionally exposed to the air environment followed by the reduction in hydrogen. The redox tolerance of the YCCC-SDC anode was attributed to the dimensional and chemical stability of the YCCC exhibiting minimal isothermal chemical expansion upon redox cycling.

  19. Ground Source Heat Pumps | Open Energy Information

    Open Energy Info (EERE)

    efficient when cooling your home. Not only does this save energy and money, it reduces air pollution. GSHP System Ground source heat pump systems consist of three parts: the...

  20. Solid waste burial grounds interim safety analysis

    SciTech Connect (OSTI)

    Saito, G.H.

    1994-10-01

    This Interim Safety Analysis document supports the authorization basis for the interim operation and restrictions on interim operations for the near-surface land disposal of solid waste in the Solid Waste Burial Grounds. The Solid Waste Burial Grounds Interim Safety Basis supports the upgrade progress for the safety analysis report and the technical safety requirements for the operations in the Solid Waste Burial Grounds. Accident safety analysis scenarios have been analyzed based on the significant events identified in the preliminary hazards analysis. The interim safety analysis provides an evaluation of the operations in the Solid Waste Burial Grounds to determine if the radiological and hazardous material exposures will be acceptable from an overall health and safety standpoint to the worker, the onsite personnel, the public, and the environment.

  1. Natural radionuclides in ground waters and cores

    SciTech Connect (OSTI)

    Laul, J.C.; Smith, M.R.; Maiti, T.C.

    1988-01-01

    Investigations of natural radionuclides of uranium and thorium decay series in site-specific ground waters and cores (water/rock interaction) can provide information on the expected migration behavior of their radioactive waste and analog radionuclides in the unlikely event of radioactive releases from a repository. These data in ground waters can provide in situ retardation and sorption/desorption parameters for transport models and their associated kinetics (residence time). These data in cores can also provide information on migration or leaching up to a period of about one million years. Finally, the natural radionuclide data can provide baseline information for future monitoring of possible radioactive waste releases. The natural radionuclides of interest are {sup 238}U, {sup 234}Th, {sup 234}U, {sup 230}Th, {sup 226}Ra, {sup 222}Rn, {sup 210}Pb, {sup 210}Bi, {sup 210}Po, {sup 232}Th, {sup 228}Ra, {sup 228}Th, and {sup 224}Ra. The half-lives of the daughter radionuclides range from 3 days to 2.5 x 10{sup 5} yr. The data discussed are for low ionic strength ground waters from the Hanford (basalt) site and briny ground waters (high ionic strength) and cores from the Deaf Smith salt site. Similar applications of the natural radionuclide data can be extended to the Nevada Tuff repository site and subseabed disposal site. The concentrations of uranium, thorium, radium, lead, and polonium radionuclides are generally very low in ground waters. However, significant differences in disequilibrium exist between basalt and briny ground waters.

  2. Particle-in-cell modeling for MJ scale dense plasma focus with varied anode shape

    SciTech Connect (OSTI)

    Link, A. Halvorson, C. Schmidt, A.; Hagen, E. C.; Rose, D. V.; Welch, D. R.

    2014-12-15

    Megajoule scale dense plasma focus (DPF) Z-pinches with deuterium gas fill are compact devices capable of producing 10{sup 12} neutrons per shot but past predictive models of large-scale DPF have not included kinetic effects such as ion beam formation or anomalous resistivity. We report on progress of developing a predictive DPF model by extending our 2D axisymmetric collisional kinetic particle-in-cell (PIC) simulations from the 4 kJ, 200 kA LLNL DPF to 1 MJ, 2 MA Gemini DPF using the PIC code LSP. These new simulations incorporate electrodes, an external pulsed-power driver circuit, and model the plasma from insulator lift-off through the pinch phase. To accommodate the vast range of relevant spatial and temporal scales involved in the Gemini DPF within the available computational resources, the simulations were performed using a new hybrid fluid-to-kinetic model. This new approach allows single simulations to begin in an electron/ion fluid mode from insulator lift-off through the 5-6 ?s run-down of the 50+ cm anode, then transition to a fully kinetic PIC description during the run-in phase, when the current sheath is 2-3 mm from the central axis of the anode. Simulations are advanced through the final pinch phase using an adaptive variable time-step to capture the fs and sub-mm scales of the kinetic instabilities involved in the ion beam formation and neutron production. Validation assessments are being performed using a variety of different anode shapes, comparing against experimental measurements of neutron yield, neutron anisotropy and ion beam production.

  3. Anodes Improve Safety and Performance in Lithium-ion Batteries - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovation Portal Advanced Materials Advanced Materials Find More Like This Return to Search Anodes Improve Safety and Performance in Lithium-ion Batteries Argonne National Laboratory Contact ANL About This Technology <span style="font-family: &quot;Cambria&quot;,&quot;serif&quot;; font-size: 12pt; mso-fareast-font-family: Calibri; mso-bidi-font-family: &quot;Times New Roman&quot;; mso-ansi-language: EN-US; mso-fareast-language: EN-US; mso-bidi-language:

  4. Hybrid Nano Carbon Fiber/Graphene Platelet-Based High-Capacity Anodes for

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Lithium Ion Batteries | Department of Energy 0 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon es009_jang_2010_o.pdf More Documents & Publications Hybrid Nano Carbon Fiber/Graphene Platelet-Based High-Capacity Anodes for Lithium Ion Batteries 2010 DOE EERE Vehicle Technologies Program Merit Review - Energy Storage Progress of DOE Materials, Manufacturing Process R&D, and ARRA Battery

  5. A high performance hybrid battery based on aluminum anode and LiFePO4 cathode

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sun, Xiao-Guang; Bi, Zhonghe; Liu, Hansan; Bridges, Craig A.; Paranthaman, Mariappan Parans; Dai, Sheng; Brown, Gilbert M.

    2015-10-07

    A unique battery hybrid utilizes an aluminum anode, a LiFePO4 cathode and an acidic ionic liquid electrolyte based on 1-ethyl-3-methylimidazolium chloride (EMImCl) and aluminum trichloride (AlCl 3) (EMImCl-AlCl 3, 1-1.1 in molar ratio) with or without LiAlCl4 is proposed. This hybrid ion battery delivers an initial high capacity of 160 mAh g-1 at a current rate of C/5. It also shows good rate capability and cycling performance.

  6. National Grid Deep Energy Retrofit Pilot

    SciTech Connect (OSTI)

    Neuhauser, K.

    2012-03-01

    Through discussion of five case studies (test homes), this project evaluates strategies to elevate the performance of existing homes to a level commensurate with best-in-class implementation of high-performance new construction homes. The test homes featured in this research activity participated in Deep Energy Retrofit (DER) Pilot Program sponsored by the electric and gas utility National Grid in Massachusetts and Rhode Island. Building enclosure retrofit strategies are evaluated for impact on durability and indoor air quality in addition to energy performance.

  7. Coiled tubing facilitates deep underbalanced workover

    SciTech Connect (OSTI)

    Adams, L.S.; Overstreet, C.C.

    1997-03-31

    A recent workover shows the technical capability and cost effectiveness of coiled tubing for cleaning out scale in a 22,611-ft, low pressure, high-temperature gas well. The well, operated by Chevron USA Production Co., is in the Fort Stockton Gas Unit 5-1 Gomez (Ellenburger) field, in West Texas. The development of reliable 100,000-psi minimal yield strength coiled tubing was a major factor that allowed this work to succeed. The methods demonstrated by this workover are becoming a standard for deep well cleanouts in the Gomez (Ellenburger) field. The paper describes coiled tubing advantages, well history, and implementation.

  8. Ground Gravity Survey At Clear Lake Area (Skokan, 1993) | Open...

    Open Energy Info (EERE)

    Ground Gravity Survey At Clear Lake Area (Skokan, 1993) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Ground Gravity Survey At Clear Lake Area...

  9. Ground Gravity Survey At Coso Geothermal Area (1980) | Open Energy...

    Open Energy Info (EERE)

    Ground Gravity Survey At Coso Geothermal Area (1980) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Ground Gravity Survey At Coso Geothermal...

  10. Ground Gravity Survey At Crump's Hot Springs Area (DOE GTP) ...

    Open Energy Info (EERE)

    Ground Gravity Survey At Crump's Hot Springs Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Ground Gravity Survey At Crump's Hot...

  11. Ground Gravity Survey At North Brawley Geothermal Area (Biehler...

    Open Energy Info (EERE)

    Ground Gravity Survey At North Brawley Geothermal Area (Biehler, 1964) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Ground Gravity Survey At...

  12. Ground Gravity Survey At Cove Fort Area - Vapor (Warpinski, Et...

    Open Energy Info (EERE)

    Ground Gravity Survey At Cove Fort Area - Vapor (Warpinski, Et Al., 2002) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Ground Gravity Survey...

  13. Ground Gravity Survey At Kilauea East Rift Geothermal Area (FURUMOTO...

    Open Energy Info (EERE)

    Ground Gravity Survey At Kilauea East Rift Geothermal Area (FURUMOTO, 1976) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Ground Gravity Survey...

  14. Ground Gravity Survey At Snake River Plain Region (DOE GTP) ...

    Open Energy Info (EERE)

    Ground Gravity Survey At Snake River Plain Region (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Ground Gravity Survey At Snake River...

  15. Ground Gravity Survey At Kilauea East Rift Geothermal Area (Thomas...

    Open Energy Info (EERE)

    Ground Gravity Survey At Kilauea East Rift Geothermal Area (Thomas, 1986) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Ground Gravity Survey...

  16. Ground Gravity Survey At Kilauea East Rift Geothermal Area (Broyles...

    Open Energy Info (EERE)

    Ground Gravity Survey At Kilauea East Rift Geothermal Area (Broyles, Et Al., 1979) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Ground Gravity...

  17. Fuel Cell Council Working Group on Aircraft and Aircraft Ground...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Council Working Group on Aircraft and Aircraft Ground Support Fuel Cell Applications Fuel Cell Council Working Group on Aircraft and Aircraft Ground Support Fuel Cell Applications...

  18. Data Analysis from Ground Source Heat Pump Demonstration Projects...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Analysis from Ground Source Heat Pump Demonstration Projects Data Analysis from Ground Source Heat Pump Demonstration Projects Comparison of building energy use before and after ...

  19. Category:Ground Electromagnetic Techniques | Open Energy Information

    Open Energy Info (EERE)

    Ground Electromagnetic Techniques Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Geothermalpower.jpg Looking for the Ground Electromagnetic Techniques page? For...

  20. Montana Ground Water Pollution Control System Permit Application...

    Open Energy Info (EERE)

    Ground Water Pollution Control System Permit Application Forms Webpage Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: Montana Ground Water Pollution...

  1. Montana Ground Water Pollution Control System Information Webpage...

    Open Energy Info (EERE)

    Ground Water Pollution Control System Information Webpage Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: Montana Ground Water Pollution Control System...

  2. EPA - Ground Water Discharges (EPA's Underground Injection Control...

    Open Energy Info (EERE)

    Ground Water Discharges (EPA's Underground Injection Control Program) webpage Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: EPA - Ground Water...

  3. Water Quality Surface and Ground | Open Energy Information

    Open Energy Info (EERE)

    Water Quality Surface and Ground Jump to: navigation, search Retrieved from "http:en.openei.orgwindex.php?titleWaterQualitySurfaceandGround&oldid612197" Feedback...

  4. Analysis of Contaminant Rebound in Ground Water in Extraction...

    Energy Savers [EERE]

    Contaminant Rebound in Ground Water in Extraction Wells at the Tuba City, Arizona, Site Analysis of Contaminant Rebound in Ground Water in Extraction Wells at the Tuba City,...

  5. An Updated Site Scale Saturated Zone Ground Water Transport Model...

    Office of Scientific and Technical Information (OSTI)

    An Updated Site Scale Saturated Zone Ground Water Transport Model for Yucca Mountain. Citation Details In-Document Search Title: An Updated Site Scale Saturated Zone Ground Water ...

  6. Breaking Ground on Computational Research and Theory Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Berkeley Lab Breaks Ground on New Computational Research Facility Breaking Ground on Computational Research and Theory Facility CRT to Foster Scientific Collaboration in...

  7. Department of Veterans Affairs, FONSI - Ground mounted solar...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ground mounted solar photovoltaic power at San Joaquin National Cemetery Department of Veterans Affairs, FONSI - Ground mounted solar photovoltaic power at San Joaquin National Cemetery ...

  8. National Grid Deep Energy Retrofit Pilot

    SciTech Connect (OSTI)

    Neuhauser, K.

    2012-03-01

    Through discussion of five case studies (test homes), this project evaluates strategies to elevate the performance of existing homes to a level commensurate with best-in-class implementation of high-performance new construction homes. The test homes featured in this research activity participated in Deep Energy Retrofit (DER) Pilot Program sponsored by the electric and gas utility National Grid in Massachusetts and Rhode Island. Building enclosure retrofit strategies are evaluated for impact on durability and indoor air quality in addition to energy performance. Evaluation of strategies is structured around the critical control functions of water, airflow, vapor flow, and thermal control. The aim of the research project is to develop guidance that could serve as a foundation for wider adoption of high performance, 'deep' retrofit work. The project will identify risk factors endemic to advanced retrofit in the context of the general building type, configuration and vintage encountered in the National Grid DER Pilot. Results for the test homes are based on observation and performance testing of recently completed projects. Additional observation would be needed to fully gauge long-term energy performance, durability, and occupant comfort.

  9. Cost reduction in deep water production systems

    SciTech Connect (OSTI)

    Beltrao, R.L.C.

    1995-12-31

    This paper describes a cost reduction program that Petrobras has conceived for its deep water field. Beginning with the Floating Production Unit, a new concept of FPSO was established where a simple system, designed to long term testing, can be upgraded, on the location, to be the definitive production unit. Regarding to the subsea system, the following projects will be considered. (1) Subsea Manifold: There are two 8-well-diverless manifolds designed for 1,000 meters presently under construction and after a value analysis, a new design was achieved for the next generation. Both projects will be discussed and a cost evaluation will also be provided. (2) Subsea Pipelines: Petrobras has just started a large program aiming to reduce cost on this important item. There are several projects such as hybrid (flexible and rigid) pipes for large diameter in deep water, alternatives laying methods, rigid riser on FPS, new material...etc. The authors intend to provide an overview of each project.

  10. Lithium/organosulfur redox cell having protective solid electrolyte barrier formed on anode and method of making same

    DOE Patents [OSTI]

    De Jonghe, Lutgard C.; Visco, Steven J.; Liu, Meilin; Mailhe, Catherine C.

    1990-01-01

    A lithium/organosulfur redox cell is disclosed which comprises a solid lium anode, a liquid organosulfur cathode, and a barrier layer formed adjacent a surface of the solid lithium anode facing the liquid organosulfur cathode consisting of a reaction product of the lithium anode with the organosulfur cathode. The organosulfur cathode comprises a material having the formula (R(S).sub.y).sub.N where y=1 to 6, n=2 to 20 and R is one or more different aliphatic or aromatic organic moieties having 1 to 20 carbon atoms, which may include one or more oxygen, sulfur, nitrogen, or fluorine atoms associated with the chain when R comprises an aliphatic chain, wherein the linear chain may be linear or branched, saturated or unsaturated, and wherein either the aliphatic chain or the aromatic ring may have substituted groups thereon.

  11. Mesoporous Silicon Sponge as an Anti-Pulverization Structure for High-Performance Lithium-ion Battery Anodes

    SciTech Connect (OSTI)

    Li, Xiaolin; Gu, Meng; Hu, Shenyang Y.; Kennard, Rhiannon; Yan, Pengfei; Chen, Xilin; Wang, Chong M.; Sailor, Michael J.; Zhang, Jiguang; Liu, Jun

    2014-07-08

    Nanostructured silicon is a promising anode material for high performance lithium-ion batteries, yet scalable synthesis of such materials, and retaining good cycling stability in high loading electrode remain significant challenges. Here, we combine in-situ transmission electron microscopy and continuum media mechanical calculations to demonstrate that large (>20 micron) mesoporous silicon sponge (MSS) prepared by the scalable anodization method can eliminate the pulverization of the conventional bulk silicon and limit particle volume expansion at full lithiation to ~30% instead of ~300% as observed in bulk silicon particles. The MSS can deliver a capacity of ~750 mAh/g based on the total electrode weight with >80% capacity retention over 1000 cycles. The first-cycle irreversible capacity loss of pre-lithiated MSS based anode is only <5%. The insight obtained from MSS also provides guidance for the design of other materials that may experience large volume variation during operations.

  12. A three-dimensional Macroporous Cu/SnO2 composite anode sheet prepared via a novel method

    SciTech Connect (OSTI)

    Xu, Wu; Canfield, Nathan L.; Wang, Deyu; Xiao, Jie; Nie, Zimin; Zhang, Jiguang

    2010-11-01

    Macroporous Cu/SnO2 composite anode sheets were prepared by a novel method which is based on slurry blending, tape casting, sintering, and reducing of metal oxides. Such composite Cu/SnO2 anode sheets have no conducting carbons and binders, and show improved discharge capacity and cycle life than the SnO2 electrode from conventional tape-casting method on Cu foil. This methodology produces limited wastes and is also adaptable to many other materials. It is easy for industrial scale production. With the optimization of particle size of the metal oxide, pore size, pore volume and other factors, this kind of macroporous Cu/SnO2 composite anode sheets could give significantly improved capacity and cycle life.

  13. Surface Coating Constraint Induced Self-Discharging of Silicon Nanoparticles as Anodes for Lithium Ion Batteries

    SciTech Connect (OSTI)

    Luo, Langli; Zhao, Peng; Yang, Hui; Liu, Borui; Zhang, Jiguang; Cui, Yi; Yu, Guihua; Zhang, Sulin; Wang, Chong M.

    2015-10-01

    One of the key challenges of Si-based anodes for lithium ion batteries is the large volume change upon lithiation and delithiation, which commonly leads to electrochemo-mechanical degradation and subsequent fast capacity fading. Recent studies have shown that applying nanometer-thick coating layers on Si nanoparticle (SiNPs) enhances cyclability and capacity retention. However, it is far from clear how the coating layer function from the point of view of both surface chemistry and electrochemo-mechanical effect. Herein, we use in situ transmission electron microscopy to investigate the lithiation/delithiation kinetics of SiNPs coated with a conductive polymer, polypyrrole (PPy). We discovered that this coating layer can lead to “self-delithiation” or “self-discharging” at different stages of lithiation. We rationalized that the self-discharging is driven by the internal compressive stress generated inside the lithiated SiNPs due to the constraint effect of the coating layer. We also noticed that the critical size of lithiation-induced fracture of SiNPs is increased from ~ 150 nm for bare SiNPs to ~ 380 nm for the PPy-coated SiNPs, showing a mechanically protective role of the coating layer. These observations demonstrate both beneficial and detrimental roles of the surface coatings, shedding light on rational design of surface coatings for silicon to retain high-power and high capacity as anode for lithium ion batteries.

  14. Can CO-tolerant Anodes be Economically Viable for PEMFC Applications with Reformates?

    SciTech Connect (OSTI)

    He, P.; Zhang, Y.; Ye., S.; Wang, J. X.

    2014-10-05

    Several years ago, the answer to this question was negative based on the criteria for an anode with <0.1 mg cm-2 of platinum group metals to perform similarly without and with 50 ppm CO in hydrogen proton exchange membrane fuel cells (PEMFCs). Now, with the amount of CO impurities reduced to 10 ppm in reformates, a <1% performance loss with a 1.5% air-bleed has become a reasonable target. The CO-tolerant catalyst also needs to be dissolution resistant up to 0.93 V, viz., the potential experienced at the anode during startup and shutdown of the fuel cells. We recently demonstrated our ability to simultaneously enhance activity and stability by using single crystalline Ru@Pt core-shell nanocatalysts. Here, we report that the performance target with reformates was met using bilayer-thick Ru@Pt core-shell nanocatalysts with 0.047 mg cm-2 Pt and 0.024 mg cm-2 Ru loading, supporting a positive prognosis for the economically viable use of reformates in PEMFC applications.

  15. Improving microstructure of silicon/carbon nanofiber composites as a Li battery anode

    SciTech Connect (OSTI)

    Howe, Jane Y; Meyer III, Harry M; Burton, David J.; Qi, Dr. Yue; Nazri, Maryam; Nazri, G. Abbas; Palmer, Andrew C.; Lake, Patrick D.

    2013-01-01

    We report the interfacial study of a silicon/carbon nanofiber (Si/CNF) nanocomposite material as a potentially high performance anode for rechargeable lithium ion batteries. The carbon nanofiber is hollow, with a graphitic interior and turbostratic exterior. Amorphous silicon layers were uniformly coated via chemical vapor deposition on both the exterior and interior surfaces of the CNF. The resulting Si/CNF composites were tested as anodes for Li ion batteries and exhibited capacities near 800 mAh g1 for 100 cycles. After cycling, we found that more Si had fallen off from the outer wall than from the innerwall of CNF. Theoretical calculations confirmed that this is due to a higher interfacial strength at the Si/Cedge interface at the inner wall than that of the Si/C-basal interface at the outer wall. Based upon the experimental analysis and theoretical calculation, we have proposed several interfacial engineering approaches to improve the performance of the electrodes by optimizing the microstructure of this nanocomposite.

  16. Advanced Surface and Microstructural Characterization of Natural Graphite Anodes for Lithium Ion Batteries

    SciTech Connect (OSTI)

    Gallego, Nidia C; Contescu, Cristian I; Meyer III, Harry M; Howe, Jane Y; Meisner, Roberta Ann; Payzant, E Andrew; Lance, Michael J; Yoon, Steve; Denlinger, Matthew; Wood III, David L

    2014-01-01

    Natural graphite powders were subjected to a series of thermal treatments in order to improve the anode irreversible capacity loss (ICL) and capacity retention during long-term cycling of lithium ion batteries. A baseline thermal treatment in inert Ar or N2 atmosphere was compared to cases with a proprietary additive to the furnace gas environment. This additive substantially altered the surface chemistry of the natural graphite powders and resulted in significantly improved long-term cycling performance of the lithium ion batteries over the commercial natural graphite baseline. Different heat-treatment temperatures were investigated ranging from 950-2900 C with the intent of achieving the desired long-term cycling performance with as low of a maximum temperature and thermal budget as possible. A detailed summary of the characterization data is also presented, which includes X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Raman spectroscopy, and temperature-programed desorption mass spectroscopy (TPD-MS). This characterization data was correlated to the observed capacity fade improvements over the course of long-term cycling at high charge-discharge rates in full lithium-ion coin cells. It is believed that the long-term performance improvements are a result of forming a more stable solid electrolyte interface (SEI) layer on the anode graphite surfaces, which is directly related to the surface chemistry modifications imparted by the proprietary gas environment during thermal treatment.

  17. Can CO-tolerant Anodes be Economically Viable for PEMFC Applications with Reformates?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    He, P.; Zhang, Y.; Ye., S.; Wang, J. X.

    2014-10-05

    Several years ago, the answer to this question was negative based on the criteria for an anode with <0.1 mg cm-2 of platinum group metals to perform similarly without and with 50 ppm CO in hydrogen proton exchange membrane fuel cells (PEMFCs). Now, with the amount of CO impurities reduced to 10 ppm in reformates, a <1% performance loss with a 1.5% air-bleed has become a reasonable target. The CO-tolerant catalyst also needs to be dissolution resistant up to 0.93 V, viz., the potential experienced at the anode during startup and shutdown of the fuel cells. We recently demonstrated ourmore » ability to simultaneously enhance activity and stability by using single crystalline Ru@Pt core-shell nanocatalysts. Here, we report that the performance target with reformates was met using bilayer-thick Ru@Pt core-shell nanocatalysts with 0.047 mg cm-2 Pt and 0.024 mg cm-2 Ru loading, supporting a positive prognosis for the economically viable use of reformates in PEMFC applications.« less

  18. Electrolyte Concentration Effect of a Photoelectrochemical Cell Consisting of TiO 2 Nanotube Anode

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ren, Kai; Gan, Yong X.; Nikolaidis, Efstratios; Sofyani, Sharaf Al; Zhang, Lihua

    2013-01-01

    The photoelectrochemical responses of a TiO 2 nanotube anode in ethylene glycol (EG), glycerol, ammonia, ethanol, urea, and Na 2 S electrolytes with different concentrations were investigated. The TiO 2 nanotube anode was highly efficient in photoelectrocatalysis in these solutions under UV light illumination. The photocurrent density is obviously affected by the concentration change. Na 2 S generated the highest photocurrent density at 0, 1, and 2 V bias voltages, but its concentration does not significantly affect the photocurrent density. Urea shows high open circuit voltage at proper concentration and low photocurrent at different concentrations. Externally applied bias voltage ismore » also an important factor that changes the photoelectrochemical reaction process. In view of the open circuit voltage, EG, ammonia, and ethanol fuel cells show the trend that the open circuit voltage (OCV) increases with the increase of the concentration of the solutions. Glycerol has the highest OCV compared with others, and it deceases with the increase in the concentration because of the high viscosity. The OCV of the urea and Na 2 S solutions did not show obvious concentration effect.« less

  19. Appendix B Ground Water Management Policy

    Office of Legacy Management (LM)

    Ground Water Management Policy for the Monticello Mill Tailings Site and Adjacent Areas This page intentionally left blank Docun~ent Number Q0029500 Appendix B State of Utah DEPARTblENT OF NATURAL RESOURCES DIVISION OF WATER RIGHTS Ground-Water Management Policy for the Mot~ticello Mill Tailings Site and Adjacent Areas The Monticello Mill Tailings Site is on the southeast portion of the tovm of Monticello in Sectton 36, T33S, K23E and Section 31, i33S. R24E, SLB&M. The mill site was used

  20. Ground Control for Emplacement Drifts for SR

    SciTech Connect (OSTI)

    Y. Sun

    2000-04-07

    This analysis demonstrates that a satisfactory ground control system can be designed for the Yucca Mountain site, and provides the technical basis for the design of ground support systems to be used in repository emplacement and non-emplacement drifts. The repository ground support design was based on analytical methods using acquired computer codes, and focused on the final support systems. A literature review of case histories, including the lessons learned from the design and construction of the ESF, the studies on the seismic damages of underground openings, and the use of rock mass classification systems in the ground support design, was conducted (Sections 6.3.4 and 6.4). This review provided some basis for determining the inputs and methodologies used in this analysis. Stability of the supported and unsupported emplacement and non-emplacement drifts was evaluated in this analysis. The excavation effects (i.e., state of the stress change due to excavation), thermal effects (i.e., due to heat output from waste packages), and seismic effects (i.e., from potential earthquake events) were evaluated, and stress controlled modes of failure were examined for two in situ stress conditions (k_0=0.3 and 1.0) using rock properties representing rock mass categories of 1 and 5. Variation of rock mass units such as the non-lithophysal (Tptpmn) and lithophysal (Tptpll) was considered in the analysis. The focus was on the non-lithophysal unit because this unit appears to be relatively weaker and has much smaller joint spacing. Therefore, the drift stability and ground support needs were considered to be controlled by the design for this rock unit. The ground support systems for both emplacement and non-emplacement drifts were incorporated into the models to assess their performance under in situ, thermal, and seismic loading conditions. Both continuum and discontinuum modeling approaches were employed in the analyses of the rock mass behavior and in the evaluation of the stability of the openings. No credit or account was given for the initial ground support in modeling the final ground support systems for both emplacement and non-emplacement drifts in this analysis.

  1. DOE's Deep Capabilities and Wide Possibilities Highlighted at Executive

    Energy Savers [EERE]

    Summit on Marine and Hydrokinetic Research and Development | Department of Energy Deep Capabilities and Wide Possibilities Highlighted at Executive Summit on Marine and Hydrokinetic Research and Development DOE's Deep Capabilities and Wide Possibilities Highlighted at Executive Summit on Marine and Hydrokinetic Research and Development March 4, 2016 - 2:42pm Addthis It's said that still water runs deep. But when it comes to marine and hydrokinetic technology development, the Department of

  2. The Genome of Deep-Sea Vent Chemolithoautotroph Thiomicrospiracrunogena

    Office of Scientific and Technical Information (OSTI)

    XCL-2 (Journal Article) | SciTech Connect Journal Article: The Genome of Deep-Sea Vent Chemolithoautotroph Thiomicrospiracrunogena XCL-2 Citation Details In-Document Search Title: The Genome of Deep-Sea Vent Chemolithoautotroph Thiomicrospiracrunogena XCL-2 Presented here is the complete genome sequence ofThiomicrospira crunogena XCL-2, representative of ubiquitouschemolithoautotrophic sulfur-oxidizing bacteria isolated from deep-seahydrothermal vents. This gammaproteobacterium has a single

  3. Building America Webinar: Results from Phased Deep Retrofits in Florida

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Phased Deep Retrofits in Florida D. Parker, D. Chasar, K. Sutherland, J. Montemurno, J. Kono Florida Solar Energy Center June, 2014 Phased Deep Retrofit (PDR) Project * Detailed residential field metering project in FPL Service Territory * Cooperative project between U.S. DOE and FPL * Sixty heavily metered homes evaluated over 2 years * Shallow retrofit in all & then deep retrofits in 10 * Collecting data of unique value to FPL/DOE PDR: Extensive end-use metering * January - July 2013: 60

  4. Building America Webinar: Results from Phased Deep Retrofits in Florida |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Results from Phased Deep Retrofits in Florida Building America Webinar: Results from Phased Deep Retrofits in Florida This presentation by Danny Parker is included in the Building America webinar, Who's Successfully Doing Deep Energy Retrofits?, on June 25, 2014. PDF icon BA Webinar_parker_6-25-14.pdf More Documents & Publications Building America Team (BA-PIRC) - 2014 BTO Peer Review Building America Whole-House Solutions for Existing Homes: Pilot Demonstration of

  5. Building America Efficient Solutions for Existing Homes Case Study: Deep

    Energy Savers [EERE]

    Energy Retrofit of 1910 House, Portland, Oregon | Department of Energy Deep Energy Retrofit of 1910 House, Portland, Oregon Building America Efficient Solutions for Existing Homes Case Study: Deep Energy Retrofit of 1910 House, Portland, Oregon This case study lists project information, cost and energy efficiency performance data, energy efficiency measures and lessons learned for a 100-year-old home in Portland, Oregon, audited by Pacific Northwest National Laboratory for a deep energy

  6. Building America Webinar: Who's Successfully Doing Deep Energy Retrofits? |

    Energy Savers [EERE]

    Department of Energy Who's Successfully Doing Deep Energy Retrofits? Building America Webinar: Who's Successfully Doing Deep Energy Retrofits? The webinar on June 25, 2014, focused on specific Building America projects that highlighted real-world examples of deep energy retrofits (DER) that are meeting with technical and market success. Presenters focused on technical strategies, modeled and actual performance results, and project costs. Danny Parker, Building America Partnership for

  7. Energy Department Explores Deep Direct Use | Department of Energy

    Office of Environmental Management (EM)

    Explores Deep Direct Use Energy Department Explores Deep Direct Use Cascaded uses of geothermal energy include district heating and industrial uses as well as agricultural applications like greenhouses and fisheries. Cascaded uses of geothermal energy include district heating and industrial uses as well as agricultural applications like greenhouses and fisheries. Deep Direct Use (DDU) geothermal applications utilize natural geothermal fluid for a full spectrum of cascading uses, including

  8. Deep Borehole Disposal Research: Demonstration Site Selection Guidelines,

    Office of Environmental Management (EM)

    Borehole Seals Design, and RD&D Needs | Department of Energy Deep Borehole Disposal Research: Demonstration Site Selection Guidelines, Borehole Seals Design, and RD&D Needs Deep Borehole Disposal Research: Demonstration Site Selection Guidelines, Borehole Seals Design, and RD&D Needs The U.S. Department of Energy has been investigating deep borehole disposal as one alternative for the disposal of spent nuclear fuel and other radioactive waste forms, along with research and

  9. MHK Technologies/Deep Gen Tidal Turbines | Open Energy Information

    Open Energy Info (EERE)

    Gen Tidal Turbines < MHK Technologies Jump to: navigation, search << Return to the MHK database homepage Deep Gen Tidal Turbines.jpg Technology Profile Primary Organization Tidal...

  10. NERSC, Berkeley Lab Explore Frontiers of Deep Learning for Science

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... applied for this purpose are standard machine learning approaches, which are likely ... method for recognizing patterns in brain signals, he added. "Using deep learning, our team ...

  11. MHK Technologies/Deep Ocean Water Application Facility DOWAF...

    Open Energy Info (EERE)

    the temperature differential between the warm surface and the cold deep seawater The OTEC heat engine converts the thermal energy into usable mechanical energy which in turn is...

  12. EA-1943: Long Baseline Neutrino Facility/Deep Underground Neutrino...

    Broader source: Energy.gov (indexed) [DOE]

    May 27, 2015 EA-1943: Draft Environmental Assessment Long Baseline Neutrino FacilityDeep Underground Neutrino Experiment (LBNFDUNE) at Fermilab, Batavia, Illinois and the...

  13. Big, Deep, and Smart Data in Energy Materials Research: Atomic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Big, Deep, and Smart Data in Energy Materials Research: Atomic View on Materials Functionalities Event Sponsor: Computing, Environment, and Life Sciences Seminar Start Date: Sep 22...

  14. Research Development and Demonstration Roadmap for Deep Borehole...

    Office of Scientific and Technical Information (OSTI)

    Development and Demonstration Roadmap for Deep Borehole Disposal. Arnold, Bill W.; MacKinnon, Robert J.; Brady, Patrick V. Abstract Not Provided Sandia National Laboratories USDOE...

  15. Building America Webinar: Introduction- Who's Successfully Doing Deep Energy Retrofits?

    Broader source: Energy.gov [DOE]

    This presentation provides the introduction for the Building America webinar, Who's Successfully Doing Deep Energy Retrofits, presented on June 25, 2014.

  16. Deep Geothermal Reservoir Temperatures in the Eastern Snake River...

    Office of Scientific and Technical Information (OSTI)

    ESRP. Masking much of the deep thermal potential of the ... apply the RTEst model to water compositions measured from ... on Geothermal Reservoir Engineering,Stanford,02242014,02...

  17. Application Of Electrical Resistivity And Gravimetry In Deep...

    Open Energy Info (EERE)

    Electrical Resistivity And Gravimetry In Deep Geothermal Exploration Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Application Of Electrical...

  18. CBEI: Demonstrating On-Bill Financing to Encourage Deep Retrofits...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Financing to Encourage Deep Retrofits - 2015 Peer Review Presenter: Rudy Terry, Philadelphia Industrial Development Corp. View the Presentation CBEI: Demonstrating On-Bill...

  19. Building America Webinar: A National Summary of Deep Energy Retrofits...

    Energy Savers [EERE]

    Whole-House Solutions for Existing Homes: National Grid Deep Energy Retrofit Pilot, Massachusetts and Rhode Island (Fact Sheet) 2015 Race to Zero Competition Winner Team Summaries...

  20. Analysis Procedure And Equipment For Deep Geoelectrical Soundings...

    Open Energy Info (EERE)

    A brief description is given of a digital geoelectrical acquisition data system and of some examples of data filtering relative to a deep dipole-dipole sounding...

  1. Technique Reveals Critical Physics in Deep Regions of Solar Cells...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    minority-carrier lifetime deep within photovoltaic samples to help develop more efficient solar cells. When developing a solar photovoltaic (PV) cell, designers benefit from having...

  2. Deep River, Connecticut: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Deep River, Connecticut: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 41.3856546, -72.4356422 Show Map Loading map... "minzoom":false,"mappi...

  3. Deep River Center, Connecticut: Energy Resources | Open Energy...

    Open Energy Info (EERE)

    Deep River Center, Connecticut: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 41.3729131, -72.4435674 Show Map Loading map......

  4. Deep Vadose Zone Applied Field Research Initiative (DVZ-AFRI...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Located on the Hanford Site in Richland, Washington, the Deep Vadose Zone Applied Field Research Initiative (DVZ AFRI) was established to protect water resources by addressing the ...

  5. ULTRA-DEEP WATER ADVISORY COMMITTEE FINDINGS AND

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ULTRA-DEEP WATER ADVISORY COMMITTEE FINDINGS AND RECOMMENDATIONS 2014 ULTRA-DEEPWATER ADVISORY COMMITTEE COMMITTEE FINDINGS AND RECOMMENDATIONS i Table of Contents Research and ...

  6. Using Cloud-Resolving Model Simulations of Deep Convection to...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    so extending them to a global model with many different environments is not straightforward. For example, deep convection creates abundant cloudiness and yet little is known...

  7. DISCOVERY AND CHARACTERIZATION OF AN EXTREMELY DEEP-ECLIPSING...

    Office of Scientific and Technical Information (OSTI)

    CATACLYSMIC VARIABLE: LSQ172554.8-643839 Citation Details In-Document Search Title: DISCOVERY AND CHARACTERIZATION OF AN EXTREMELY DEEP-ECLIPSING CATACLYSMIC VARIABLE: ...

  8. PV Systems Reliability Final Technical Report: Ground Fault Detection

    SciTech Connect (OSTI)

    Lavrova, Olga; Flicker, Jack David; Johnson, Jay

    2016-01-01

    We have examined ground faults in PhotoVoltaic (PV) arrays and the efficacy of fuse, current detection (RCD), current sense monitoring/relays (CSM), isolation/insulation (Riso) monitoring, and Ground Fault Detection and Isolation (GFID) using simulations based on a Simulation Program with Integrated Circuit Emphasis SPICE ground fault circuit model, experimental ground faults installed on real arrays, and theoretical equations.

  9. Record of Decision for Ground Water | Department of Energy

    Energy Savers [EERE]

    Record of Decision for Ground Water Record of Decision for Ground Water Record of Decision for Ground Water (April 1997) PDF icon Record of Decision for Ground Water More Documents & Publications EIS-0198: Record of Decision EIS-0170: Record of Decision (April 1997) EIS-0251: Second Record of Decision (May 1997)

  10. Photovoltaic module mounting clip with integral grounding

    DOE Patents [OSTI]

    Lenox, Carl J.

    2010-08-24

    An electrically conductive mounting/grounding clip, usable with a photovoltaic (PV) assembly of the type having an electrically conductive frame, comprises an electrically conductive body. The body has a central portion and first and second spaced-apart arms extending from the central portion. Each arm has first and second outer portions with frame surface-disrupting element at the outer portions.

  11. Selenium in Oklahoma ground water and soil

    SciTech Connect (OSTI)

    Atalay, A.; Vir Maggon, D.

    1991-03-30

    Selenium with a consumption of 2 liters per day (5). The objectives of this study are: (1) to determine the concentrations of Se in Oklahoma ground water and soil samples. (2) to map the geographical distribution of Se species in Oklahoma. (3) to relate groundwater depth, pH and geology with concentration of Se.

  12. Ground Source Heat Pump System Data Analysis | Department of Energy

    Energy Savers [EERE]

    Ground Source Heat Pump System Data Analysis Ground Source Heat Pump System Data Analysis Emerging Technologies Project for the 2013 Building Technologies Office's Program Peer Review PDF icon emrgtech16_liu_040313.pdf More Documents & Publications Three new/under-utilized ground loop designs being evaluated for their ground loop cost reduction potential<br /> Credit: Oak Ridge National Lab Advanced Ground Source Heat Pump Technology for Very-Low-Energy Buildings Oak Ridge City Center

  13. Programmatic Environmental Impact Statement for Ground Water | Department

    Energy Savers [EERE]

    of Energy Programmatic Environmental Impact Statement for Ground Water Programmatic Environmental Impact Statement for Ground Water Programmatic Environmental Impact Statement for Ground Water Volumes I & II (October 1996) Optical character recognition has been applied to these files, but full search capabilities are not guaranteed. PDF icon Programmatic Environmental Impact Statement for Ground Water-Volume I PDF icon Programmatic Environmental Impact Statement for Ground Water-Volume

  14. Characterization of failure modes in deep UV and deep green LEDs utilizing advanced semiconductor localization techniques.

    SciTech Connect (OSTI)

    Tangyunyong, Paiboon; Miller, Mary A.; Cole, Edward Isaac, Jr.

    2012-03-01

    We present the results of a two-year early career LDRD that focused on defect localization in deep green and deep ultraviolet (UV) light-emitting diodes (LEDs). We describe the laser-based techniques (TIVA/LIVA) used to localize the defects and interpret data acquired. We also describe a defect screening method based on a quick electrical measurement to determine whether defects should be present in the LEDs. We then describe the stress conditions that caused the devices to fail and how the TIVA/LIVA techniques were used to monitor the defect signals as the devices degraded and failed. We also describe the correlation between the initial defects and final degraded or failed state of the devices. Finally we show characterization results of the devices in the failed conditions and present preliminary theories as to why the devices failed for both the InGaN (green) and AlGaN (UV) LEDs.

  15. Green synthesis of boron doped graphene and its application as high performance anode material in Li ion battery

    SciTech Connect (OSTI)

    Sahoo, Madhumita; Sreena, K.P.; Vinayan, B.P.; Ramaprabhu, S.

    2015-01-15

    Graphical abstract: Boron doped graphene (B-G), synthesized by simple hydrogen induced reduction technique using boric acid as boron precursor, have more uneven surface as a result of smaller bonding distance of boron compared to carbon, showed high capacity and high rate capability compared to pristine graphene as an anode material for Li ion battery application. - Abstract: The present work demonstrates a facile route for the large-scale, catalyst free, and green synthesis approach of boron doped graphene (B-G) and its use as high performance anode material for Li ion battery (LIB) application. Boron atoms were doped into graphene framework with an atomic percentage of 5.93% via hydrogen induced thermal reduction technique using graphite oxide and boric acid as precursors. Various characterization techniques were used to confirm the boron doping in graphene sheets. B-G as anode material shows a discharge capacity of 548 mAh g{sup ?1} at 100 mA g{sup ?1} after 30th cycles. At high current density value of 1 A g{sup ?1}, B-G as anode material enhances the specific capacity by about 1.7 times compared to pristine graphene. The present study shows a simplistic way of boron doping in graphene leading to an enhanced Li ion adsorption due to the change in electronic states.

  16. Demonstration of a Highly Efficient Solid Oxide Fuel Cell Power System Using Adiabatic Steam Reforming and Anode Gas Recirculation

    SciTech Connect (OSTI)

    Powell, Michael R.; Meinhardt, Kerry D.; Sprenkle, Vincent L.; Chick, Lawrence A.; Mcvay, Gary L.

    2012-05-01

    Solid oxide fuel cells (SOFC) are currently being developed for a wide variety of applications because of their high efficiency at multiple power levels. Applications for SOFCs encompass a large range of power levels including 1-2 kW residential combined heat and power applications, 100-250 kW sized systems for distributed generation and grid extension, and MW-scale power plants utilizing coal. This paper reports on the development of a highly efficient, small-scale SOFC power system operating on methane. The system uses adiabatic steam reforming of methane and anode gas recirculation to achieve high net electrical efficiency. The anode exit gas is recirculated and all of the heat and water required for the endothermic reforming reaction are provided by the anode gas emerging from the SOFC stack. Although the single-pass fuel utilization is only about 55%, because of the anode gas recirculation the overall fuel utilization is up to 93%. The demonstrated system achieved gross power output of 1650 to 2150 watts with a maximum net LHV efficiency of 56.7% at 1720 watts. Overall system efficiency could be further improved to over 60% with use of properly sized blowers.

  17. Electrochemical, Structural and Surface Characterization of Nickel/Zirconia Solid Oxide Fuel Cell Anodes in Coal Gas Containing Antimony

    SciTech Connect (OSTI)

    Marina, Olga A.; Pederson, Larry R.; Coyle, Christopher A.; Thomsen, Edwin C.; Nachimuthu, Ponnusamy; Edwards, Danny J.

    2011-02-27

    The interaction of antimony with the nickel-zirconia solid oxide fuel cell (SOFC) anode has been investigated. Tests with both anode-supported and electrolyte-supported button cells were performed at 700 and 800oC in synthetic coal gas containing 10 ppb to 9 ppm antimony. Minor performance loss was observed immediately after Sb introduction to coal gas resulting in ca. 5 % power output drop. While no further degradation was observed during the following several hundred hours of testing, cells abruptly and irreversibly failed after 800-1500 hours depending on Sb concentration and test temperature. Antimony was found to interact strongly with nickel and result in extensive alteration phase formation, consistent with expectations based on thermodynamic properties. Nickel antimonide phases, NiSb and Ni5Sb2, were partially coalesced into large grains and eventually affected electronic percolation through the anode support. Initial degradation was attributed to diffusion of antimony to the active anode/electrolyte interface to form an adsorption layer.

  18. Combined Theoretical and Experimental Investigation and Design of H2S Tolerant Anode for Solid Oxide Fuel Cells

    SciTech Connect (OSTI)

    Gerardine G. Botte; Damilola Daramola; Madhivanan Muthuvel

    2009-01-07

    A solid oxide fuel cell (SOFC) is a high temperature fuel cell and it normally operates in the range of 850 to 1000 C. Coal syngas has been considered for use in SOFC systems to produce electric power, due to its high temperature and high hydrogen and carbon monoxide content. However, coal syngas also has contaminants like carbon dioxide (CO{sub 2}) and hydrogen sulfide (H{sub 2}S). Among these contaminants, H{sub 2}S is detrimental to electrode material in SOFC. Commonly used anode material in SOFC system is nickel-yttria stabilized zirconia (Ni-YSZ). The presence of H{sub 2}S in the hydrogen stream will damage the Ni anode and hinder the performance of SOFC. In the present study, an attempt was made to understand the mechanism of anode (Ni-YSZ) deterioration by H{sub 2}S. The study used computation methods such as quantum chemistry calculations and molecular dynamics to predict the model for anode destruction by H{sub 2}S. This was done using binding energies to predict the thermodynamics and Raman spectroscopy to predict molecular vibrations and surface interactions. On the experimental side, a test stand has been built with the ability to analyze button cells at high temperature under syngas conditions.

  19. Production of energetic neutral particles and low energy electrons from four anode rods ion source

    SciTech Connect (OSTI)

    Mostafa, O. A.; El-Khabeary, H.; Abdel Reheem, A. M.

    2013-11-15

    The factors affecting the energetic neutral current, the low energy electron current, and the positive ion current emerging from a four-anode-rods ion source have been studied using argon gas. The neutral and electron current were measured using a simple, new technique. It was found that the energetic neutral current and the electron current depend on the positive ion current and the gas pressure. The ratio of the neutral and electron current to the positive ion current increases by increasing the gas pressure. Also it was found that at a pressure equal to 9 10{sup ?4} mmHg, the ratio of the neutral to the positive ion current reaches 2.34 while the ratio of the electron current to the positive ion current reaches 1.7.

  20. Oxygen diffusion of anodic surface oxide film on titanium studied by Auger electron spectroscopy. [Oxygen diffusivity

    SciTech Connect (OSTI)

    Wang, P.S.; Wittberg, T.N.; Keil, R.G.

    1982-01-01

    TiO/sub 2/ films of about 1000 A were grown onto titanium foils anodically under galvanostatic conditions at 20 mA/cm/sup 2/ in saturated aqueous solutions of ammonium tetraborate. The samples were then aged at 450, 500, and 550/sup 0/C, and oxygen diffusion was observed by Auger electron spectroscopy (AES) profilings. The oxygen diffusivities were calculated by Fick's Second Law, using the Boltzmann-Matano solution, to be 9.4 x 10/sup -17/, 2.6 x 10/sup -16/, and 1.2 x 10/sup -15/ cm/sup 2//sec at 450, 500, and 550/sup 0/C, respectively. The diffusivities obtained by this method were also compared with those obtained using an exact solution to Fick's Second Law. The activation energy was calculated to be 30 kcal/mole.

  1. Anodic oxygen-transfer electrocatalysis at iron-doped lead dioxide electrodes

    SciTech Connect (OSTI)

    Feng, Jianren

    1994-10-01

    The research illustrated in this thesis was performed under the guidance of Professor Dennis C. Johnson beginning in March 1987. Chapter 2 concentrates on the development and electrocatalytic properties of iron-doped {beta}-PbO{sub 2} films on noble-metal substrates. Chapter 3 focuses attention on the preparation and characterization of iron-doped {beta}-PbO{sub 2} films on titanium substrates (Fe-PbO{sub 2}/Ti). Chapter 4 discusses anodic evolution of ozone at Fe-PbO{sub 2}/Ti electrodes. Chapter 5 describes electrochemical incineration of p-benzoquinone (BQ) at Fe-PbO{sub 2}/Ti electrodes. In addition, the Appendix includes another published paper which is a detailed study of {alpha}-PbO{sub 2} films deposited on various types of stainless steel substrates.

  2. Six Thousand Electrochemical Cycles of Double-Walled Silicon Nanotube Anodes for Lithium Ion Batteries

    SciTech Connect (OSTI)

    Wu, H

    2011-08-18

    Despite remarkable progress, lithium ion batteries still need higher energy density and better cycle life for consumer electronics, electric drive vehicles and large-scale renewable energy storage applications. Silicon has recently been explored as a promising anode material for high energy batteries; however, attaining long cycle life remains a significant challenge due to materials pulverization during cycling and an unstable solid-electrolyte interphase. Here, we report double-walled silicon nanotube electrodes that can cycle over 6000 times while retaining more than 85% of the initial capacity. This excellent performance is due to the unique double-walled structure in which the outer silicon oxide wall confines the inner silicon wall to expand only inward during lithiation, resulting in a stable solid-electrolyte interphase. This structural concept is general and could be extended to other battery materials that undergo large volume changes.

  3. Optimization design of electrodes for anode-supported solid oxide fuel cells via genetic algorithm

    SciTech Connect (OSTI)

    Shi, J.; Xue, X.

    2011-01-01

    Porous electrode is the critical component of solid-oxide fuel cells (SOFCs) and provides a functional material backbone for multi-physicochemical processes. Model based electrode designs could significantly improve SOFC performance. This task is usually performed via parameter studies for simple case and assumed property distributions for graded electrodes. When nonlinearly coupled multiparameters of electrodes are considered, it could be very difficult for the model based parameter study method to effectively and systematically search the design space. In this research, the optimization approach with a genetic algorithm is demonstrated for this purpose. An anode-supported proton conducting SOFC integrated with a fuel supply system is utilized as a physical base for the model development and the optimization design. The optimization results are presented, which are difficult to obtain for parametric study method.

  4. Deep Vadose Zone Applied Field Research Initiative (DVZ AFRI) - Overview

    SciTech Connect (OSTI)

    2011-02-01

    The Deep Vadoze Zone Applied Field Research Initiative (DVZ AFRI) was established to protect water resources and to address the challenge of preventing contamination in the deep vadose zone from reaching groundwater. This factsheet provides an overview of the initiative and the approach to integrate basic science and needs-driven applied research activities with cleanup operations.

  5. U.S. Department of Energy UMTRA Ground Water Project Ground Water Pumping and Monitoring Plan

    Office of Legacy Management (LM)

    GWMON 1.12-1 U.S. Department of Energy UMTRA Ground Water Project Ground Water Pumping and Monitoring Plan for the Land Farm Pilot Test Monument Valley, Arizona August 2000 Prepared by U.S. Department of Energy Grand Junction Ofice Grand Junction, Colorado Project Number UGW-5 1 1-001 5-21-000 Document Number U0106701 This page intentionally left blank Document Number U0106701 Contents Contents 1.0 Introduction

  6. Procedures for ground-water investigations

    SciTech Connect (OSTI)

    Not Available

    1989-09-01

    This manual was developed by the Pacific Northwest Laboratory (PNL) to document the procedures used to carry out and control the technical aspects of ground-water investigations at the PNL. Ground-water investigations are carried out to fulfill the requirements for the US Department of Energy (DOE) to meet the requirements of DOE Orders. Investigations are also performed for various clients to meet the requirements of the Resource Conservation and Recovery Act of 1976 (RCRA) and the Comprehensive Environmental Response, Compensation and Liability Act of 1980 (CERCLA). National standards including procedures published by the American Society for Testing and Materials (ASTM) and the US Geological Survey were utilized in developing the procedures contained in this manual.

  7. SRS Burial Ground Complex: Remediation in Progress

    SciTech Connect (OSTI)

    Griffin, M.; Crapse, B.; Cowan, S.

    1998-01-21

    Closure of the various areas in the Burial Ground Complex (BGC) represents a major step in the reduction of risk at the Savannah River Site (SRS) and a significant investment of resources. The Burial Ground Complex occupies approximately 195 acres in the central section of the SRS. Approximately 160 acres of the BGC consists of hazardous and radioactive waste disposal sites that require remediation. Of these source acres, one-third have been remediated while two-thirds are undergoing interim or final action. These restoration activities have been carried out in a safe and cost effective manner while minimizing impact to operating facilities. Successful completion of these activities is in large part due to the teamwork demonstrated by the Department of Energy, contractor/subcontractor personnel, and the regulatory agencies. The experience and knowledge gained from the closure of these large disposal facilities can be used to expedite closure of similar facilities.

  8. Workshop to develop deep-life continental scientific drilling projects

    SciTech Connect (OSTI)

    Kieft, T. L.; Onstott, T. C.; Ahonen, L.; Aloisi, V.; Colwell, F. S.; Engelen, B.; Fendrihan, S.; Gaidos, E.; Harms, U.; Head, I.; Kallmeyer, J.; Kiel Reese, B.; Lin, L.-H.; Long, P. E.; Moser, D. P.; Mills, H.; Sar, P.; Schulze-Makuch, D.; Stan-Lotter, H.; Wagner, D.; Wang, P.-L.; Westall, F.; Wilkins, M. J.

    2015-05-29

    The International Continental Scientific Drilling Program (ICDP) has long espoused studies of deep subsurface life, and has targeted fundamental questions regarding subsurface life, including the following: "(1) What is the extent and diversity of deep microbial life and what are the factors limiting it? (2) What are the types of metabolism/carbon/energy sources and the rates of subsurface activity? (3) How is deep microbial life adapted to subsurface conditions? (4) How do subsurface microbial communities affect energy resources? And (5) how does the deep biosphere interact with the geosphere and atmosphere?" (Horsfield et al., 2014) Many ICDP-sponsored drilling projects have included a deep-life component; however, to date, not one project has been driven by deep-life goals, in part because geomicrobiologists have been slow to initiate deep biosphere-driven ICDP projects. Therefore, the Deep Carbon Observatory (DCO) recently partnered with the ICDP to sponsor a workshop with the specific aim of gathering potential proponents for deep-life-driven ICDP projects and ideas for candidate drilling sites. Twenty-two participants from nine countries proposed projects and sites that included compressional and extensional tectonic environments, evaporites, hydrocarbon-rich shales, flood basalts, Precambrian shield rocks, subglacial and subpermafrost environments, active volcano–tectonic systems, megafan deltas, and serpentinizing ultramafic environments. The criteria and requirements for successful ICDP applications were presented. Deep-life-specific technical requirements were discussed and it was concluded that, while these procedures require adequate planning, they are entirely compatible with the sampling needs of other disciplines. As a result of this workshop, one drilling workshop proposal on the Basin and Range Physiographic Province (BRPP) has been submitted to the ICDP, and several other drilling project proponents plan to submit proposals for ICDP-sponsored drilling workshops in 2016.

  9. Workshop to develop deep-life continental scientific drilling projects

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kieft, T. L.; Onstott, T. C.; Ahonen, L.; Aloisi, V.; Colwell, F. S.; Engelen, B.; Fendrihan, S.; Gaidos, E.; Harms, U.; Head, I.; et al

    2015-05-29

    The International Continental Scientific Drilling Program (ICDP) has long espoused studies of deep subsurface life, and has targeted fundamental questions regarding subsurface life, including the following: "(1) What is the extent and diversity of deep microbial life and what are the factors limiting it? (2) What are the types of metabolism/carbon/energy sources and the rates of subsurface activity? (3) How is deep microbial life adapted to subsurface conditions? (4) How do subsurface microbial communities affect energy resources? And (5) how does the deep biosphere interact with the geosphere and atmosphere?" (Horsfield et al., 2014) Many ICDP-sponsored drilling projects have includedmore » a deep-life component; however, to date, not one project has been driven by deep-life goals, in part because geomicrobiologists have been slow to initiate deep biosphere-driven ICDP projects. Therefore, the Deep Carbon Observatory (DCO) recently partnered with the ICDP to sponsor a workshop with the specific aim of gathering potential proponents for deep-life-driven ICDP projects and ideas for candidate drilling sites. Twenty-two participants from nine countries proposed projects and sites that included compressional and extensional tectonic environments, evaporites, hydrocarbon-rich shales, flood basalts, Precambrian shield rocks, subglacial and subpermafrost environments, active volcano–tectonic systems, megafan deltas, and serpentinizing ultramafic environments. The criteria and requirements for successful ICDP applications were presented. Deep-life-specific technical requirements were discussed and it was concluded that, while these procedures require adequate planning, they are entirely compatible with the sampling needs of other disciplines. As a result of this workshop, one drilling workshop proposal on the Basin and Range Physiographic Province (BRPP) has been submitted to the ICDP, and several other drilling project proponents plan to submit proposals for ICDP-sponsored drilling workshops in 2016.« less

  10. Grounding and shielding in the accelerator environment

    SciTech Connect (OSTI)

    Kerns, Q.

    1991-12-31

    Everyday features of the accelerator environment include long cable runs, high power and low level equipment sharing building space, stray electromagnetic fields and ground voltage differences between the sending and receiving ends of an installation. This paper pictures some Fermilab installations chosen to highlight significant features and presents practices, test methods and equipment that have been helpful in achieving successful shielding. Throughout the report are numbered statements aimed at summarizing good practices and avoiding pitfalls.

  11. Compression of ground-motion data

    SciTech Connect (OSTI)

    Long, J.W.

    1981-04-01

    Ground motion data has been recorded for many years at Nevada Test Site and is now stored on thousands of digital tapes. The recording format is very inefficient in terms of space on tape. This report outlines a method to compress the data onto a few hundred tapes while maintaining the accuracy of the recording and allowing restoration of any file to the original format for future use. For future digitizing a more efficient format is described and suggested.

  12. Breaking New Ground The Answer Is....

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    New Ground The Answer Is.... NSTec enters groundbreaking science partnership. CTOS leads the way at FEMA training symposium. Middle School Science Bowl hailed a success. See page 6. See page 8. Use Restriction - What does it Mean? Since 1989, the U.S. Department of Energy Environmental Management (EM) Program has been identifying and addressing areas on the Nevada National Security Site (NNSS) that have been impacted by historical nuclear testing. To date, EM has successfully closed more than

  13. Ground-Based Microwave Radiometer Measurements

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ground-Based Microwave Radiometer Measurements and Radiosonde Comparisons During the WVIOP2000 Field Experiment D. Cimini University of L'Aquila L'Aquil, Italy E. R. Westwater Cooperative Institute for Research in the Environmental Sciences University of Colorado National Oceanic and Atmospheric Administration Environmental Technology Laboratory Boulder, Colorado Y. Han Science System Applications National Aeronautics Space Administration Goddard Space Flight Center Greenbelt, Maryland S. Keihm

  14. Mechanical interface having multiple grounded actuators

    DOE Patents [OSTI]

    Martin, Kenneth M. (Palo Alto, CA); Levin, Mike D. (Sunnyvale, CA); Rosenberg, Louis B. (Pleasanton, CA)

    1998-01-01

    An apparatus and method for interfacing the motion of a user-manipulable object with a computer system includes a user object physically contacted or grasped by a user. A 3-D spatial mechanism is coupled to the user object, such as a stylus or a medical instrument, and provides three degrees of freedom to the user object. Three grounded actuators provide forces in the three degrees of freedom. Two of the degrees of freedom are a planar workspace provided by a closed-loop linkage of members, and the third degree of freedom is rotation of the planar workspace provided by a rotatable carriage. Capstan drive mechanisms transmit forces between actuators and the user object and include drums coupled to the carriage, pulleys coupled to grounded actuators, and flexible cables transmitting force between the pulleys and the drums. The flexibility of the cable allows the drums to rotate with the carriage while the pulleys and actuators remain fixed to ground. The interface also may include a floating gimbal mechanism coupling the linkage to the user object. The floating gimbal mechanism includes rotatably coupled gimbal members that provide three degrees of freedom to the user object and capstan mechanisms coupled between sensors and the gimbal members for providing enhanced sensor resolution.

  15. Modeling Deep Burn TRISO Particle Nuclear Fuel

    SciTech Connect (OSTI)

    Besmann, Theodore M [ORNL; Stoller, Roger E [ORNL; Samolyuk, German D [ORNL; Schuck, Paul C [ORNL; Rudin, Sven [Los Alamos National Laboratory (LANL); Wills, John [Los Alamos National Laboratory (LANL); Wirth, Brian D. [University of California, Berkeley; Kim, Sungtae [University of Wisconsin, Madison; Morgan, Dane [University of Wisconsin, Madison; Szlufarska, Izabela [University of Wisconsin, Madison

    2012-01-01

    Under the DOE Deep Burn program TRISO fuel is being investigated as a fuel form for consuming plutonium and minor actinides, and for greater efficiency in uranium utilization. The result will thus be to drive TRISO particulate fuel to very high burn-ups. In the current effort the various phenomena in the TRISO particle are being modeled using a variety of techniques. The chemical behavior is being treated utilizing thermochemical analysis to identify phase formation/transformation and chemical activities in the particle, including kernel migration. First principles calculations are being used to investigate the critical issue of fission product palladium attack on the SiC coating layer. Density functional theory is being used to understand fission product diffusion within the plutonia oxide kernel. Kinetic Monte Carlo techniques are shedding light on transport of fission products, most notably silver, through the carbon and SiC coating layers. The diffusion of fission products through an alternative coating layer, ZrC, is being assessed via DFT methods. Finally, a multiscale approach is being used to understand thermal transport, including the effect of radiation damage induced defects, in a model SiC material.

  16. Constructing Hydraulic Barriers in Deep Geologic Formations

    SciTech Connect (OSTI)

    Carter, E.E.; Carter, P.E. [Technologies Co, Texas (United States); Cooper, D.C. [Ph.D. Idaho National Laboratory, Idaho Falls, ID (United States)

    2008-07-01

    Many construction methods have been developed to create hydraulic barriers to depths of 30 to 50 meters, but few have been proposed for depths on the order of 500 meters. For these deep hydraulic barriers, most methods are potentially feasible for soil but not for hard rock. In the course of researching methods of isolating large subterranean blocks of oil shale, the authors have developed a wax thermal permeation method for constructing hydraulic barriers in rock to depths of over 500 meters in competent or even fractured rock as well as soil. The technology is similar to freeze wall methods, but produces a permanent barrier; and is potentially applicable in both dry and water saturated formations. Like freeze wall barriers, the wax thermal permeation method utilizes a large number of vertical or horizontal boreholes around the perimeter to be contained. However, instead of cooling the boreholes, they are heated. After heating these boreholes, a specially formulated molten wax based grout is pumped into the boreholes where it seals fractures and also permeates radially outward to form a series of columns of wax-impregnated rock. Rows of overlapping columns can then form a durable hydraulic barrier. These barriers can also be angled above a geologic repository to help prevent influx of water due to atypical rainfall events. Applications of the technique to constructing containment structures around existing shallow waste burial sites and water shutoff for mining are also described. (authors)

  17. Ground Electromagnetic Survey At Kilauea East Rift Geothermal...

    Open Energy Info (EERE)

    the data rather than computed from a theoretical formula. This survey was good for learning about the deep resistivity structures. References James Kauahikaua, Douglas Klein...

  18. Designated Ground Water Basin Map | Open Energy Information

    Open Energy Info (EERE)

    Designated Ground Water Basin Map Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: Designated Ground Water Basin Map Abstract This webpage provides...

  19. Appendix E Supporting Information for Ground Water Modeling

    Office of Legacy Management (LM)

    Supporting Information for Ground Water Modeling This page intentionally left blank Contents Section Geologic Map of Site Area ........................................................................................................ E1.O Stream Flow Measurements ...................................................................................................... E2.0 Estimates of Ground Water Flow .............................................................................................. E3.0

  20. Deep Well #4 Backup Power Systems Project Closeout Report

    SciTech Connect (OSTI)

    Jeremy Westwood

    2010-04-01

    The project scope was to install a diesel generated power source to deep well 4 in addition to the existing commercial power source. The diesel power source and its fuel supply system shall be seismically qualified to withstand a Performance Category 4 (PC-4) seismic event. This diesel power source will permit the deep well to operate during a loss of commercial power. System design will incorporate the ability to select and transfer power between the new diesel power source and commercial power sources for the the deep well motor and TRA-672 building loads.

  1. Cooperative heat transfer and ground coupled storage system

    DOE Patents [OSTI]

    Metz, Philip D. (Rocky Point, NY)

    1982-01-01

    A cooperative heat transfer and ground coupled storage system wherein collected solar heat energy is ground stored and permitted to radiate into the adjacent ground for storage therein over an extended period of time when such heat energy is seasonally maximally available. Thereafter, when said heat energy is seasonally minimally available and has propagated through the adjacent ground a substantial distance, the stored heat energy may be retrieved by a circumferentially arranged heat transfer means having a high rate of heat transfer.

  2. Recommendation 195: Mitigation of Contamination in Bear Creek Burial Grounds

    Broader source: Energy.gov [DOE]

    The ORSSAB requests DOE provide possible remedial actions to mitigate releases of contamination from Bear Creek Burial Grounds.

  3. Coal mine ground control. 3rd ed.

    SciTech Connect (OSTI)

    Peng, S.S.

    2008-09-15

    The third edition not only completely revises and updates the original subject areas, but also is broadened to include a number of new topics such as high horizontal stresses, computer modeling, and highwall stability. The subject areas covered in this book define the current field of coal mine ground control, except for the recently emerging topic of mine seals and some conventional subjects such as coal/rock cutting and impoundment dams. It contains 1,134 references from all published sources, and archived since 1876.

  4. Photovoltaic module mounting clip with integral grounding

    DOE Patents [OSTI]

    Lenox, Carl J.

    2008-10-14

    An electrically conductive mounting/grounding clip, for use with a photovoltaic assembly of the type having an electrically conductive frame, comprises an electrically conductive body. The body has a central portion and first and second spaced-apart arms extending generally perpendicular to the central portion. Each arm has an outer portion with each outer portion having an outer end. At least one frame surface-disrupting element is at each outer end. The central portion defines a plane with the frame surface-disrupting elements pointing towards the plane. In some examples each arm extends from the central portion at an acute angle to the plane.

  5. Best Possible Strategy for Finding Ground States

    SciTech Connect (OSTI)

    Franz, Astrid; Hoffmann, Karl Heinz; Salamon, Peter

    2001-06-04

    Finding the ground state of a system with a complex energy landscape is important for many physical problems including protein folding, spin glasses, chemical clusters, and neural networks. Such problems are usually solved by heuristic search methods whose efficacy is judged by empirical performance on selected examples. We present a proof that, within the large class of algorithms that simulate a random walk on the landscape, threshold accepting is the best possible strategy. In particular, it can perform better than simulated annealing and Tsallis statistics. Our proof is the first example of a provably optimal strategy in this area.

  6. Trends and Future Challenges in Sampling the Deep Terrestrial Biosphere

    SciTech Connect (OSTI)

    Wilkins, Michael J.; Daly, Rebecca; Mouser, Paula J.; Trexler, Ryan; Sharma, Shihka; Cole, David R.; Wrighton, Kelly C.; Biddle , Jennifer F.; Denis, Elizabeth; Fredrickson, Jim K.; Kieft, Thomas L.; Onstott, T. C.; Peterson, Lee; Pfiffner, Susan M.; Phelps, Tommy J.; Schrenk, Matthew O.

    2014-09-12

    Research in the deep terrestrial biosphere is driven by interest in novel biodiversity and metabolisms, biogeochemical cycling, and the impact of human activities on this ecosystem. As this interest continues to grow, it is important to ensure that when subsurface investigations are proposed, materials recovered from the subsurface are sampled and preserved in an appropriate manner to limit contamination and ensure preservation of accurate microbial, geochemical, and mineralogical signatures. On February 20th, 2014, a workshop on “Trends and Future Challenges in Sampling The Deep Subsurface” was coordinated in Columbus, Ohio by The Ohio State University and West Virginia University faculty, and sponsored by The Ohio State University and the Sloan Foundation’s Deep Carbon Observatory. The workshop aims were to identify and develop best practices for the collection, preservation, and analysis of terrestrial deep rock samples. This document summarizes the information shared during this workshop.

  7. Visit to the Deep Underground Science and Engineering Laboratory

    SciTech Connect (OSTI)

    2009-03-31

    U.S. Department of Energy scientists and administrators join members of the National Science Foundation and South Dakotas Sanford Underground Laboratory for the deepest journey yet to the proposed site of the Deep Underground Science and Engineering Laboratory (DUSEL).

  8. Visit to the Deep Underground Science and Engineering Laboratory

    SciTech Connect (OSTI)

    2009-01-01

    U.S. Department of Energy scientists and administrators join members of the National Science Foundation and South Dakotas Sanford Underground Laboratory for the deepest journey yet to the proposed site of the Deep Underground Science and Engineering Laboratory (DUSEL).

  9. Visit to the Deep Underground Science and Engineering Laboratory

    ScienceCinema (OSTI)

    None

    2010-01-08

    U.S. Department of Energy scientists and administrators join members of the National Science Foundation and South Dakotas Sanford Underground Laboratory for the deepest journey yet to the proposed site of the Deep Underground Science and Engineering Laboratory (DUSEL).

  10. Deep Water Drilling to Catalyze the Global Drilling Fluids Market...

    Open Energy Info (EERE)

    Deep Water Drilling to Catalyze the Global Drilling Fluids Market Home > Groups > Renewable Energy RFPs John55364's picture Submitted by John55364(100) Contributor 13 May, 2015 -...

  11. Nitrogen is a deep acceptor in ZnO

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tarun, M. C.; Iqbal, M. Zafar; McCluskey, M. D.

    2011-04-14

    Zinc oxide is a promising material for blue and UV solid-state lighting devices, among other applications. Nitrogen has been regarded as a potential p-type dopant for ZnO. However, recent calculations indicate that nitrogen is a deep acceptor. This paper presents experimental evidence that nitrogen is, in fact, a deep acceptor and therefore cannot produce p-type ZnO. A broad photoluminescence (PL) emission band near 1.7 eV, with an excitation onset of ~2.2 eV, was observed, in agreement with the deep-acceptor model of the nitrogen defect. Thus the deep-acceptor behavior can be explained by the low energy of the ZnO valence bandmore » relative to the vacuum level.« less

  12. Building America Webinar: Deep Energy Retrofit Case Studies:...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    This presentation by Alea German is included in the Building America webinar, Who's Successfully Doing Deep Energy Retrofits?, on June 25, 2014. PDF icon BA Webinargerman6-25-14....

  13. ULTRA-DEEP WATER ADVISORY COMMITTEE FINDINGS AND

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ULTRA-DEEP WATER ADVISORY COMMITTEE FINDINGS AND RECOMMENDATIONS 2014 ULTRA-DEEPWATER ADVISORY COMMITTEE COMMITTEE FINDINGS AND RECOMMENDATIONS i Table of Contents Research and Development Program Committee ............................................ 1 Sunset Committee .................................................................................................. 5 Advisory Committee Members ........................................................................... 7 ULTRA-DEEPWATER

  14. ARM - Field Campaign - Deep Convective Clouds and Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govCampaignsDeep Convective Clouds and Chemistry Campaign Links DC3 Experiment Comments? We would love to hear from you Send us a note below or call us at 1-888-ARM-DATA. Send...

  15. Deep drilling data Raft River geothermal area, Idaho | Open Energy...

    Open Energy Info (EERE)

    data Raft River geothermal area, Idaho Jump to: navigation, search OpenEI Reference LibraryAdd to library Report: Deep drilling data Raft River geothermal area, Idaho Abstract...

  16. Low-surface-area hard carbon anode for Na-ion batteries via graphene oxide as a dehydration agent

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Luo, Wei; Bommier, Clement; Jian, Zelang; Li, Xin; Carter, Rich; Vail, Sean; Lu, Yuhao; Lee, Jong -Jan; Ji, Xiulei

    2015-02-04

    Na-ion batteries are emerging as one of the most promising energy storage technologies, particularly for grid-level applications. Among anode candidate materials, hard carbon is very attractive due to its high capacity and low cost. However, hard carbon anodes often suffer a low first-cycle Coulombic efficiency and fast capacity fading. In this study, we discover that doping graphene oxide into sucrose, the precursor for hard carbon, can effectively reduce the specific surface area of hard carbon to as low as 5.4 m²/g. We further reveal that such doping can effectively prevent foaming during caramelization of sucrose and extend the pyrolysis burn-offmore » of sucrose caramel over a wider temperature range. Thus, the obtained low-surface-area hard carbon greatly improves the first-cycle Coulombic efficiency from 74% to 83% and delivers a very stable cyclic life with 95% of capacity retention after 200 cycles.« less

  17. Low-surface-area hard carbon anode for Na-ion batteries via graphene oxide as a dehydration agent

    SciTech Connect (OSTI)

    Luo, Wei; Bommier, Clement; Jian, Zelang; Li, Xin; Carter, Rich; Vail, Sean; Lu, Yuhao; Lee, Jong -Jan; Ji, Xiulei

    2015-02-04

    Na-ion batteries are emerging as one of the most promising energy storage technologies, particularly for grid-level applications. Among anode candidate materials, hard carbon is very attractive due to its high capacity and low cost. However, hard carbon anodes often suffer a low first-cycle Coulombic efficiency and fast capacity fading. In this study, we discover that doping graphene oxide into sucrose, the precursor for hard carbon, can effectively reduce the specific surface area of hard carbon to as low as 5.4 m/g. We further reveal that such doping can effectively prevent foaming during caramelization of sucrose and extend the pyrolysis burn-off of sucrose caramel over a wider temperature range. Thus, the obtained low-surface-area hard carbon greatly improves the first-cycle Coulombic efficiency from 74% to 83% and delivers a very stable cyclic life with 95% of capacity retention after 200 cycles.

  18. Reversible Poisoning of the Nickel/Zirconia Solid Oxide Fuel Cell Anodes by Hydrogen Chloride in Coal Gas

    SciTech Connect (OSTI)

    Marina, Olga A.; Pederson, Larry R.; Thomsen, Edwin C.; Coyle, Christopher A.; Yoon, Kyung J.

    2010-10-15

    The performance of anode-supported solid oxide fuel cells (SOFC) was evaluated in synthetic coal gas containing HCl in the temperature range 650 to 850oC. Exposure to up to 800 ppm HCl resulted in reversible poisoning of the Ni/zirconia anode by chlorine species adsorption, the magnitude of which decreased with increased temperature. Performance losses increased with the concentration of HCl to ~100 ppm, above which losses were insensitive to HCl concentration. Cell voltage had no effect on poisoning. No evidence was found for long-term degradation that can be attributed to HCl exposure. Similarly, no evidence of microstructural changes or formation of new solid phases as a result of HCl exposure was found. From thermodynamic calculations, solid nickel chloride phase formation was shown to be highly unlikely in coal gas. Further, the presence of HCl at even the highest anticipated concentrations in coal gas would minimally increase the volatility of nickel.

  19. Research, Development, and Demonstration Roadmap for Deep Borehole Disposal

    Office of Energy Efficiency and Renewable Energy (EERE)

    This roadmap is intended to advance deep borehole disposal (DBD) from its current conceptual status to potential future deployment as a disposal system for spent nuclear fuel (SNF) and high-level waste (HLW). The objectives of the DBD RD&D roadmap include providing the technical basis for fielding a DBD demonstration project, defining the scientific research activities associated with site characterization and postclosure safety, and defining the engineering demonstration activities associated with deep borehole drilling, completion, and surrogate waste canister emplacement.

  20. Rapidity divergences and deep inelastic scattering in the endpoint region

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Rapidity divergences and deep inelastic scattering in the endpoint region Citation Details In-Document Search This content will become publicly available on May 11, 2016 Title: Rapidity divergences and deep inelastic scattering in the endpoint region Authors: Fleming, Sean ; Labun, Ou Z. Publication Date: 2015-05-12 OSTI Identifier: 1179737 Grant/Contract Number: FG02-06ER41449; FG02-04ER41338 Type: Publisher's Accepted Manuscript Journal Name: Physical

  1. Arctic Stratus and Tropical Deep Convection. Integrating Measurements and

    Office of Scientific and Technical Information (OSTI)

    Simulations (Technical Report) | SciTech Connect Technical Report: Arctic Stratus and Tropical Deep Convection. Integrating Measurements and Simulations Citation Details In-Document Search Title: Arctic Stratus and Tropical Deep Convection. Integrating Measurements and Simulations Final report summarizing published material. Authors: Ann, Fridlind [1] + Show Author Affiliations NASA Goddard Institute for Space Studies, Washington, DC (United States) Publication Date: 2015-05-18 OSTI

  2. Deep Bed Adsorption Testing using Silver-Functionalized Aerogel (Technical

    Office of Scientific and Technical Information (OSTI)

    Report) | SciTech Connect Deep Bed Adsorption Testing using Silver-Functionalized Aerogel Citation Details In-Document Search Title: Deep Bed Adsorption Testing using Silver-Functionalized Aerogel Nuclear fission results in the production of fission products and activation products, some of which tend to be volatile during used fuel reprocessing and evolve in gaseous species into the reprocessing facility off-gas systems. Analyses have shown that I129, due to its radioactivity, high

  3. Deep Geothermal Reservoir Temperatures in the Eastern Snake River Plain,

    Office of Scientific and Technical Information (OSTI)

    Idaho using Multicomponent Geothermometry (Conference) | SciTech Connect Conference: Deep Geothermal Reservoir Temperatures in the Eastern Snake River Plain, Idaho using Multicomponent Geothermometry Citation Details In-Document Search Title: Deep Geothermal Reservoir Temperatures in the Eastern Snake River Plain, Idaho using Multicomponent Geothermometry The U.S. Geological survey has estimated that there are up to 4,900 MWe of undiscovered geothermal resources and 92,000 MWe of enhanced

  4. Magnetohydrodynamics and deep mixing in evolved stars. I. Two- and

    Office of Scientific and Technical Information (OSTI)

    three-dimensional analytical models for the asymptotic giant branch (Journal Article) | SciTech Connect Magnetohydrodynamics and deep mixing in evolved stars. I. Two- and three-dimensional analytical models for the asymptotic giant branch Citation Details In-Document Search Title: Magnetohydrodynamics and deep mixing in evolved stars. I. Two- and three-dimensional analytical models for the asymptotic giant branch The advection of thermonuclear ashes by magnetized domains emerging near the H

  5. Assessing 116 Deep Retrofits Across the U.S.

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ASSESSING 116 DEEP RETROFITS ACROSS THE U.S. By: Brennan Less & Iain Walker, LBNL, Residential Building Systems ACI National Home Performance Conference, Detroit, MI, 04/30/2014 Defining a Deep Energy Retrofit- Variable and Flexible 2  Comprehensive upgrades to the building enclosure, heating, cooling and hot water equipment.  Often incorporates appliance and lighting upgrades, plug load reductions, renewable energy and occupant conservation. % Reduction >50% Absolute Reduction

  6. Project Profile: Deep Eutectic Salt Formulations Suitable as Advanced Heat

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Transfer Fluids | Department of Energy Concentrating Solar Power » Project Profile: Deep Eutectic Salt Formulations Suitable as Advanced Heat Transfer Fluids Project Profile: Deep Eutectic Salt Formulations Suitable as Advanced Heat Transfer Fluids Halotechnics logo Halotechnics, under the Thermal Storage FOA, is conducting high-throughput, combinatorial research and development of salt formulations for use as highly efficient heat transfer fluids (HTFs). Approach Robotic high-throughput

  7. Test of factorization in diffractive deep inelastic scattering and

    Office of Scientific and Technical Information (OSTI)

    photoproduction at HERA (Journal Article) | SciTech Connect Test of factorization in diffractive deep inelastic scattering and photoproduction at HERA Citation Details In-Document Search Title: Test of factorization in diffractive deep inelastic scattering and photoproduction at HERA The QCD factorization theorem in diffraction is tested by comparing diffractive jet production data to QCD predictions based on fits to inclusive diffractive cross section data. H1 measured dijet production with

  8. Thermodynamic stability of actinide pyrochlore minerals in deep geologic

    Office of Scientific and Technical Information (OSTI)

    repository environments (Conference) | SciTech Connect Thermodynamic stability of actinide pyrochlore minerals in deep geologic repository environments Citation Details In-Document Search Title: Thermodynamic stability of actinide pyrochlore minerals in deep geologic repository environments Crystalline phases of pyrochlore (e.g., CaPuTi{sub 2}O{sub 7}, CaUTi{sub 2}O{sub 7}) have been proposed as a durable ceramic waste form for disposal of high level radioactive wastes including surplus

  9. Department of Energy Recognizes Cummins for Deep Energy Retrofit at

    Office of Environmental Management (EM)

    Jamestown Engine Plant | Department of Energy Cummins for Deep Energy Retrofit at Jamestown Engine Plant Department of Energy Recognizes Cummins for Deep Energy Retrofit at Jamestown Engine Plant November 6, 2014 - 9:05am Addthis NEWS MEDIA CONTACT (202) 586-4940 JAMESTOWN, N.Y. - As a part of the Administration's effort to increase energy efficiency nationwide through the Better Buildings, Better Plants Challenge, the Energy Department today recognized Cummins Inc., for demonstrating

  10. Experiments in anodic film effects during electrorefining of scrap U-10Mo fuels in support of modeling efforts

    SciTech Connect (OSTI)

    Van Kleeck, M.; Willit, J.; Williamson, M.A.; Fentiman, A.W.

    2013-07-01

    A monolithic uranium molybdenum alloy clad in zirconium has been proposed as a low enriched uranium (LEU) fuel option for research and test reactors, as part of the Reduced Enrichment for Research and Test Reactors program. Scrap from the fuel's manufacture will contain a significant portion of recoverable LEU. Pyroprocessing has been identified as an option to perform this recovery. A model of a pyroprocessing recovery procedure has been developed to assist in refining the LEU recovery process and designing the facility. Corrosion theory and a two mechanism transport model were implemented on a Mat-Lab platform to perform the modeling. In developing this model, improved anodic behavior prediction became necessary since a dense uranium-rich salt film was observed at the anode surface during electrorefining experiments. Experiments were conducted on uranium metal to determine the film's character and the conditions under which it forms. The electro-refiner salt used in all the experiments was eutectic LiCl/KCl containing UCl{sub 3}. The anodic film material was analyzed with ICP-OES to determine its composition. Both cyclic voltammetry and potentiodynamic scans were conducted at operating temperatures between 475 and 575 C. degrees to interrogate the electrochemical behavior of the uranium. The results show that an anodic film was produced on the uranium electrode. The film initially passivated the surface of the uranium on the working electrode. At high over potentials after a trans-passive region, the current observed was nearly equal to the current observed at the initial active level. Analytical results support the presence of K{sub 2}UCl{sub 6} at the uranium surface, within the error of the analytical method.

  11. Parameterizing deep convection using the assumed probability density function method

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Storer, R. L.; Griffin, B. M.; Hft, J.; Weber, J. K.; Raut, E.; Larson, V. E.; Wang, M.; Rasch, P. J.

    2015-01-06

    Due to their coarse horizontal resolution, present-day climate models must parameterize deep convection. This paper presents single-column simulations of deep convection using a probability density function (PDF) parameterization. The PDF parameterization predicts the PDF of subgrid variability of turbulence, clouds, and hydrometeors. That variability is interfaced to a prognostic microphysics scheme using a Monte Carlo sampling method.The PDF parameterization is used to simulate tropical deep convection, the transition from shallow to deep convection over land, and midlatitude deep convection. These parameterized single-column simulations are compared with 3-D reference simulations. The agreement is satisfactory except when the convective forcing is weak.moreThe same PDF parameterization is also used to simulate shallow cumulus and stratocumulus layers. The PDF method is sufficiently general to adequately simulate these five deep, shallow, and stratiform cloud cases with a single equation set. This raises hopes that it may be possible in the future, with further refinements at coarse time step and grid spacing, to parameterize all cloud types in a large-scale model in a unified way.less

  12. Parameterizing deep convection using the assumed probability density function method

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Storer, R. L.; Griffin, B. M.; Höft, J.; Weber, J. K.; Raut, E.; Larson, V. E.; Wang, M.; Rasch, P. J.

    2014-06-11

    Due to their coarse horizontal resolution, present-day climate models must parameterize deep convection. This paper presents single-column simulations of deep convection using a probability density function (PDF) parameterization. The PDF parameterization predicts the PDF of subgrid variability of turbulence, clouds, and hydrometeors. That variability is interfaced to a prognostic microphysics scheme using a Monte Carlo sampling method. The PDF parameterization is used to simulate tropical deep convection, the transition from shallow to deep convection over land, and mid-latitude deep convection. These parameterized single-column simulations are compared with 3-D reference simulations. The agreement is satisfactory except when the convective forcing ismore » weak. The same PDF parameterization is also used to simulate shallow cumulus and stratocumulus layers. The PDF method is sufficiently general to adequately simulate these five deep, shallow, and stratiform cloud cases with a single equation set. This raises hopes that it may be possible in the future, with further refinements at coarse time step and grid spacing, to parameterize all cloud types in a large-scale model in a unified way.« less

  13. Parameterizing deep convection using the assumed probability density function method

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Storer, R. L.; Griffin, B. M.; Höft, J.; Weber, J. K.; Raut, E.; Larson, V. E.; Wang, M.; Rasch, P. J.

    2015-01-06

    Due to their coarse horizontal resolution, present-day climate models must parameterize deep convection. This paper presents single-column simulations of deep convection using a probability density function (PDF) parameterization. The PDF parameterization predicts the PDF of subgrid variability of turbulence, clouds, and hydrometeors. That variability is interfaced to a prognostic microphysics scheme using a Monte Carlo sampling method. The PDF parameterization is used to simulate tropical deep convection, the transition from shallow to deep convection over land, and midlatitude deep convection. These parameterized single-column simulations are compared with 3-D reference simulations. The agreement is satisfactory except when the convective forcing ismore » weak. The same PDF parameterization is also used to simulate shallow cumulus and stratocumulus layers. The PDF method is sufficiently general to adequately simulate these five deep, shallow, and stratiform cloud cases with a single equation set. This raises hopes that it may be possible in the future, with further refinements at coarse time step and grid spacing, to parameterize all cloud types in a large-scale model in a unified way.« less

  14. Fuel Cells (Project FC-041): DOE Hydrogen Program 2011 Annual Merit Review and Peer Evaluation Report: Novel Approach to Advanced Direct Methanol Fuel Cell Anode Catalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    422 | FY 2011 Merit Review and Peer Evaluation Report Project # FC-041: Novel Approach to Advanced Direct Methanol Fuel Cell Anode Catalysts Huyen Dinh; National Renewable Energy Laboratory Brief Summary of Project: The overall objective of this project is to develop and demonstrate direct methanol fuel cell (DMFC) anode catalyst systems that meet or exceed the U.S. Department of Energy's (DOE) 2010 targets for consumer electronics applications. The specific goal is to improve the catalytic

  15. A Yolk-Shell Design for Stabilized and Scalable Li-Ion Battery Alloy Anodes

    SciTech Connect (OSTI)

    Liu, Nian; Wu, Hui; Mcdowell, Matthew T.; Yao, Yan; Wang, Chong M.; Cui, Yi

    2012-05-02

    Silicon is regarded as one of the most promising anode materials for next generation lithium-ion batteries. For use in practical applications, a Si electrode must have high capacity, long cycle life, high efficiency, and the fabrication must be industrially scalable. Here, we design and fabricate a yolk-shell structure to meet all these needs. The fabrication is carried out without special equipment and mostly at room temperature. Commercially available Si nanoparticles are completely sealed inside conformal, thin, self-supporting carbon shells, with rationally designed void space in between the particles and the shell. The well-defined void space allows the Si particles to expand freely without breaking the outer carbon shell, therefore stabilizing the solid-electrolyte interphase on the shell surface. High capacity (?2800 mAh/g at C/10), long cycle life (1000 cycles with 74% capacity retention), and high Coulombic efficiency (99.84%) have been realized in this yolk-shell structured Si electrode.

  16. Electrodeposited porous metal oxide films with interconnected nanoparticles applied as anode of lithium ion battery

    SciTech Connect (OSTI)

    Xiao, Anguo Zhou, Shibiao; Zuo, Chenggang; Zhuan, Yongbing; Ding, Xiang

    2014-12-15

    Highlights: Highly porous NiO film is prepared by a co-electrodeposition method. Porous NiO film is composed of interconnected nanoparticles. Porous structure is favorable for fast ion/electron transfer. Porous NiO film shows good lithium ion storage properties. - Abstract: Controllable synthesis of porous metal oxide films is highly desirable for high-performance electrochemical devices. In this work, a highly porous NiO film composed of interconnected nanoparticles is prepared by a simple co-electrodeposition method. The nanoparticles in the NiO film have a size ranging from 30 to 100 nm and construct large-quantity pores of 20120 nm. As an anode material for lithium ion batteries, the highly porous NiO film electrode delivers a high discharge capacity of 700 mA h g{sup ?1} at 0.2 C, as well as good high-rate performance. After 100 cycles at 0.2 C, a specific capacitance of 517 mA h g{sup ?1} is attained. The good electrochemical performance is attributed to the interconnected porous structure, which facilitates the diffusion of ion and electron, and provides large reaction surface area leading to improved performance.

  17. Tailored Recovery of Carbons from Waste Tires for Enhanced Performance as Anodes in Lithium-ion Batteries

    SciTech Connect (OSTI)

    Naskar, Amit K; Bi,; Saha, Dipendu; Chi, Miaofang; Bridges, Craig A; Paranthaman, Mariappan Parans

    2014-01-01

    Morphologically tailored pyrolysis-recovered carbon black is utilized in lithium-ion batteries as a potential solution for adding value to waste tire-rubber-derived materials. Micronized tire rubber was digested in a hot oleum bath to yield a sulfonated rubber slurry that was then filtered, washed, and compressed into a solid cake. Carbon was recovered from the modified rubber cake by pyrolysis in a nitrogen atmosphere. The chemical pretreatment of rubber produced a carbon monolith with higher yield than that from the control (a fluffy tire-rubber-derived carbon black). The carbon monolith showed a very small volume fraction of pores of widths 3 4 nm, reduced specific surface area, and an ordered assembly of graphitic domains. Electrochemical studies on the recovered-carbon-based anode revealed an improved Li-ion battery performance with higher reversible capacity than that of commercial carbon materials. Anodes made with a sulfonated tire-rubber-derived carbon and a control tire-rubber-derived carbon, respectively, exhibited an initial coulombic efficiency of 80% and 45%, respectively. The reversible capacity of the cell with the sulfonated carbon as anode was 400 mAh/g after 100 cycles, with nearly 100% coulombic efficiency. Our success in producing higher performance carbon material from waste tire rubber for potential use in energy storage applications adds a new avenue to tire rubber recycling.

  18. Role of quinones in electron transfer of PQQglucose dehydrogenase anodesmediation or orientation effect

    SciTech Connect (OSTI)

    Babanova, Sofia; Matanovic, Ivana; Chavez, Madelaine Seow; Atanassov, Plamen

    2015-06-16

    In this study, the influence of two quinones (1,2- and 1,4-benzoquinone) on the operation and mechanism of electron transfer in PQQ-sGDH anodes has been determined. Benzoquinones were experimentally explored as mediators present in the electrolyte. The electrochemical performance of the PQQsGDH anodes with and without the mediators was examined and for the first time molecular docking simulations were used to gain a fundamental understanding to explain the role of the mediator molecules in the design and operation of the enzymatic electrodes. It was proposed that the higher performance of the PQQsGDH anodes in the presence of 1,2- and 1,4-benzoquinones introduced in the solution is due to the shorter distance between these molecules and PQQ in the enzymatic molecule. It was also hypothesized that when 1,4-benzoquinone is adsorbed on a carbon support, it would play the dual role of a mediator and an orienting agent. At the same time, when 1,2-benzoquinone and ubiquinone are adsorbed on the electrode surface, the enzyme would transfer the electrons directly to the support, and these molecules would primarily play the role of an orienting agent.

  19. Characterization and Quantification of Electronic and Ionic Ohmic Overpotential and Heat Generation in a Solid Oxide Fuel Cell Anode

    SciTech Connect (OSTI)

    Grew, Kyle N.; Izzo, John R.; Chiu, Wilson K.S.

    2011-08-16

    The development of a solid oxide fuel cell (SOFC) with a higher efficiency and power density requires an improved understanding and treatment of the irreversibilities. Losses due to the electronic and ionic resistances, which are also known as ohmic losses in the form of Joule heating, can hinder the SOFC's performance. Ohmic losses can result from the bulk material resistivities as well as the complexities introduced by the cell's microstructure. In this work, two-dimensional (2D), electronic and ionic transport models are used to develop a method of quantification of the ohmic losses within the SOFC anode microstructure. This quantification is completed as a function of properties determined from a detailed microstructure characterization, namely, the tortuosity of the electronic and ionic phases, phase volume fraction, contiguity, and mean free path. A direct modeling approach at the level of the pore-scale microstructure is achieved through the use of a representative volume element (RVE) method. The correlation of these ohmic losses with the quantification of the SOFC anode microstructure are examined. It is found with this analysis that the contributions of the SOFC anode microstructure on ohmic losses can be correlated with the volume fraction, contiguity, and mean free path.

  20. Three-dimensional microstructural changes in the NiYSZ solid oxide fuel cell anode during operation

    SciTech Connect (OSTI)

    Nelson G. J.; Chu Y.; Grew, K.N.; Izzo Jr. J.R.; Lombardo, J.J.; Harris, W.M.; Faes, A.; Hessler-Wyser, A.; Van herle, J.; Wang, S.; Virkar, A.V.; Chiu, W.K.S.

    2012-04-07

    Microstructural evolution in solid oxide fuel cell (SOFC) cermet anodes has been investigated using X-ray nanotomography along with differential absorption imaging. SOFC anode supports composed of Ni and yttria-stabilized zirconia (YSZ) were subjected to extended operation and selected regions were imaged using a transmission X-ray microscope. X-ray nanotomography provides unique insight into microstructure changes of all three phases (Ni, YSZ, pore) in three spatial dimensions, and its relation to performance degradation. Statistically significant 3D microstructural changes were observed in the anode Ni phase over a range of operational times, including phase size growth and changes in connectivity, interfacial contact area and contiguous triple-phase boundary length. These observations support microstructural evolution correlated to SOFC performance. We find that Ni coarsening is driven by particle curvature as indicated by the dihedral angles between the Ni, YSZ and pore phases, and hypothesize that growth occurs primarily by means of diffusion and particle agglomeration constrained by a pinning mechanism related to the YSZ phase. The decrease in Ni phase size after extended periods of time may be the result of a second process connected to a mobility-induced decrease in the YSZ phase size or non-uniform curvature resulting in a net decrease in Ni phase size.

  1. Characterization and Quantification of Electronic and Ionic Ohmic Overpotential and Heat Generation in a Solid Oxide Fuel Cell Anode

    SciTech Connect (OSTI)

    Grew, Kyle N.; Izzo, Jr., John R.; Chiu, W. K. S.

    2011-01-01

    The development of a solid oxide fuel cell (SOFC) with a higher efficiency and power density requires an improved understanding and treatment of the irreversibilities. Losses due to the electronic and ionic resistances, which are also known as ohmic losses in the form of Joule heating, can hinder the SOFCs performance. Ohmic losses can result from the bulk material resistivities as well as the complexities introduced by the cells microstructure. In this work, two-dimensional (2D), electronic and ionic transport models are used to develop a method of quantification of the ohmic losses within the SOFC anode microstructure. This quantification is completed as a function of properties determined from a detailed microstructure characterization, namely, the tortuosity of the electronic and ionic phases, phase volume fraction, contiguity, and mean free path. A direct modeling approach at the level of the pore-scale microstructure is achieved through the use of a representative volume element (RVE) method. The correlation of these ohmic losses with the quantification of the SOFC anode microstructure are examined. It is found with this analysis that the contributions of the SOFC anode microstructure on ohmic losses can be correlated with the volume fraction, contiguity, and mean free path.

  2. MTX (Microwave Tokamak Experiment) facility and machine grounding plan

    SciTech Connect (OSTI)

    Bell, H.H.; Rice, B.W.; Petersen, D.E.; Herrera, C.H.

    1987-10-07

    A key issue in the design of fusion research experiments and their related facilities is the control of ground currents. Because of the large magnetic field, high voltages and high currents present in most of these installations, it is essential to avoid ground loops, and to control ground currents during both normal operations and fault conditions. This paper describes the grounding policy that was developed for MTX. The vault area was divided into zones, and each of the four walls was treated as a separate grounding area. Cable runs and magnet buss bars were run into the machine radially. The paper also describes the steps taken to isolate diagnostic signals and power for pumps and instruments. The paper outlines some of the field calculations used to predict problem areas, and to reveal voltage isolation levels that were required. The paper includes the active ground fault detection system used to insure the integrity of the ground system. 2 refs., 5 figs.

  3. Commissioning of the Ground Test Accelerator RFQ

    SciTech Connect (OSTI)

    Johnson, K.F.; Sander, O.R.; Atkins, W.H.; Bolme, G.O.; Brown, S.; Connolly, R.; Garnett, R.; Gilpatrick, J.D.; Guy, F.W.; Ingalls, W.B.; Little, C.; Lohson, R.A.; Lloyd, S.; Neuschaefer, G.; Power, J.; Saadatmand, K.; Sandoval, D.P.; Stevens, R.R.; Vaughn, G.; Wadlinger, E.A.; Weiss, R.; Yuan, V.

    1992-09-01

    The Ground Test Accelerator (GTA) has the objective of verifying much of the technology (physics and engineering) required for producing high-brightness, high-current H{sup {minus}} beams. GTA commissioning is staged to verify the beam dynamics design of each major accelerator component as it is brought on-line. The commissioning stages are the 35 key H{sup {minus}} injector, the 2.5 MeV Radio Frequency Quadrupole (RFQ), the Intertank Matching Section (IMS), the 3.2 MeV first 2{beta}{gamma} Drift Tube Linac (DTL-1) module, the 8.7 MeV 2{beta}{gamma} DTL (modules 1--5), and the 24 MeV GTA; all 10 DTL modules. Commissioning results from the RFQ beam experiments will be presented along with comparisons to simulations.

  4. Commissioning of the Ground Test Accelerator RFQ

    SciTech Connect (OSTI)

    Johnson, K.F.; Sander, O.R.; Atkins, W.H.; Bolme, G.O.; Brown, S.; Connolly, R.; Garnett, R.; Gilpatrick, J.D.; Guy, F.W.; Ingalls, W.B.; Little, C.; Lohson, R.A.; Lloyd, S.; Neuschaefer, G.; Power, J.; Saadatmand, K.; Sandoval, D.P.; Stevens, R.R.; Vaughn, G.; Wadlinger, E.A.; Weiss, R.; Yuan, V.

    1992-01-01

    The Ground Test Accelerator (GTA) has the objective of verifying much of the technology (physics and engineering) required for producing high-brightness, high-current H{sup {minus}} beams. GTA commissioning is staged to verify the beam dynamics design of each major accelerator component as it is brought on-line. The commissioning stages are the 35 key H{sup {minus}} injector, the 2.5 MeV Radio Frequency Quadrupole (RFQ), the Intertank Matching Section (IMS), the 3.2 MeV first 2{beta}{gamma} Drift Tube Linac (DTL-1) module, the 8.7 MeV 2{beta}{gamma} DTL (modules 1--5), and the 24 MeV GTA; all 10 DTL modules. Commissioning results from the RFQ beam experiments will be presented along with comparisons to simulations.

  5. Ground freezing for containment of hazardous waste

    SciTech Connect (OSTI)

    Sayles, F.N.; Iskandar, I.K.

    1998-07-01

    The freezing of ground for the containment of subsurface hazardous waste is a promising method that is environmentally friendly and offers a safe alternative to other methods of waste retention in many cases. The frozen soil method offers two concepts for retaining waste. One concept is to freeze the entire waste area into a solid block of frozen soil thus locking the waste in situ. For small areas where the contaminated soil does not include vessels that would rupture from frost action, this concept may be simpler to install. A second concept, of course, is to create a frozen soil barrier to confine the waste within prescribed unfrozen soil boundaries; initial research in this area was funded by EPA, Cincinnati, OH, and the Army Corps of Engineers. The paper discusses advantages and limitations, a case study from Oak Ridge, TN, and a mesh generation program that simulates the cryogenic technology.

  6. Breaking Ground in Miami-Dade

    Broader source: Energy.gov [DOE]

    Officials from Miami-Dade County and the U.S. Department of Energy were on hand Wednesday, October 13th to formally break ground on an innovative project that will help improve the energy efficiency of one of the county’s major water treatment facilities.   The project will upgrade and expand the existing power generation system at the water plant which generates electricity from digester gas produced at the plant.  Landfill gas, which is produced from the Solid Waste Department’s South Dade Landfill, will be collected and piped across a canal to the water plant where it will be mixed with digester gases.  By combining landfill and digester gases, the county will increase the amount of self-generated electricity, and reduce the county's consumption of electricity generated from fossil fuels.  

  7. Natural radionuclides in Hanford site ground waters

    SciTech Connect (OSTI)

    Smith, M.R.; Laul, J.C.; Johnson, V.G.

    1987-10-01

    Uranium, Th, Ra, Rn, Pb and Po radionuclide concentrations in ground waters from the Hanford Site indicate that U, Th, and Ra are highly sorbed. Relative to Rn, these radionuclides are low by factors of 10/sup -3/ to 10/sup -6/. Uranium sorption is likely due to its reduction from the +6 state, where it is introduced via surface waters, to the +4 state found in the confined aquifers. The distribution of radionuclides is very similar in all of the confined aquifers and significantly different from the distribution observed in the unconfined and surface waters. Barium correlates well with Ra over three orders of magnitude, indicating that stable element analogs may be useful for inferring the behavior of radioactive waste radionuclides in this candidate geologic repository. 8 refs., 7 figs., 1 tab.

  8. Two-Dimensional Ground Water Transport

    Energy Science and Technology Software Center (OSTI)

    1992-03-05

    FRACFLO computes the two-dimensional, space, time dependent, convective dispersive transport of a single radionuclide in an unbounded single or multiple parallel fracture system with constant aperture. It calculates the one-dimensional diffusive transport into the rock matrix as well as the mass flux and cumulative mass flux at any point in the fracture. Steady-state isothermal ground water flow and parallel streamlines are assumed in the fracture, and the rock matrix is considered to be fully saturatedmore » with immobile water. The model can treat a single or multiple finite patch source or a Gaussian distributed source subject to a step or band release mode.« less

  9. Wide band stepped frequency ground penetrating radar

    DOE Patents [OSTI]

    Bashforth, M.B.; Gardner, D.; Patrick, D.; Lewallen, T.A.; Nammath, S.R.; Painter, K.D.; Vadnais, K.G.

    1996-03-12

    A wide band ground penetrating radar system is described embodying a method wherein a series of radio frequency signals is produced by a single radio frequency source and provided to a transmit antenna for transmission to a target and reflection therefrom to a receive antenna. A phase modulator modulates those portions of the radio frequency signals to be transmitted and the reflected modulated signal is combined in a mixer with the original radio frequency signal to produce a resultant signal which is demodulated to produce a series of direct current voltage signals, the envelope of which forms a cosine wave shaped plot which is processed by a Fast Fourier Transform Unit 44 into frequency domain data wherein the position of a preponderant frequency is indicative of distance to the target and magnitude is indicative of the signature of the target. 6 figs.

  10. Wide band stepped frequency ground penetrating radar

    DOE Patents [OSTI]

    Bashforth, Michael B.; Gardner, Duane; Patrick, Douglas; Lewallen, Tricia A.; Nammath, Sharyn R.; Painter, Kelly D.; Vadnais, Kenneth G.

    1996-01-01

    A wide band ground penetrating radar system (10) embodying a method wherein a series of radio frequency signals (60) is produced by a single radio frequency source (16) and provided to a transmit antenna (26) for transmission to a target (54) and reflection therefrom to a receive antenna (28). A phase modulator (18) modulates those portion of the radio frequency signals (62) to be transmitted and the reflected modulated signal (62) is combined in a mixer (34) with the original radio frequency signal (60) to produce a resultant signal (53) which is demodulated to produce a series of direct current voltage signals (66) the envelope of which forms a cosine wave shaped plot (68) which is processed by a Fast Fourier Transform unit 44 into frequency domain data (70) wherein the position of a preponderant frequency is indicative of distance to the target (54) and magnitude is indicative of the signature of the target (54).

  11. Multidimensional resonance raman spectroscopy by six-wave mixing in the deep UV

    SciTech Connect (OSTI)

    Molesky, Brian P.; Giokas, Paul G.; Guo, Zhenkun; Moran, Andrew M.

    2014-09-21

    Two-dimensional (2D) resonance Raman spectroscopies hold great potential for uncovering photoinduced relaxation processes in molecules but are not yet widely applied because of technical challenges. Here, we describe a newly developed 2D resonance Raman experiment operational at the third-harmonic of a Titanium-Sapphire laser. High-sensitivity and rapid data acquisition are achieved by combining spectral interferometry with a background-free (six-pulse) laser beam geometry. The third-harmonic laser pulses are generated in a filament produced by the fundamental and second-harmonic pulses in neon gas at pressures up to 35 atm. The capabilities of the setup are demonstrated by probing ground-state wavepacket motions in triiodide. The information provided by the experiment is explored with two different representations of the signal. In one representation, Fourier transforms are carried out with respect to the two experimentally controlled delay times to obtain a 2D Raman spectrum. Further insights are derived in a second representation by dispersing the signal pulse in a spectrometer. It is shown that, as in traditional pump-probe experiments, the six-wave mixing signal spectrum encodes the wavepacket's position by way of the (time-evolving) emission frequency. Anharmonicity additionally induces dynamics in the vibrational resonance frequency. In all cases, the experimental signals are compared to model calculations based on a cumulant expansion approach. This study suggests that multi-dimensional resonance Raman spectroscopies conducted on systems with Franck-Condon active modes are fairly immune to many of the technical issues that challenge off-resonant 2D Raman spectroscopies (e.g., third-order cascades) and photon-echo experiments in the deep UV (e.g., coherence spikes). The development of higher-order nonlinear spectroscopies operational in the deep UV is motivated by studies of biological systems and elementary organic photochemistries.

  12. High Frequency Ground Motion Simulation for Seismic Hazard Analysis |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Argonne Leadership Computing Facility Orange, yellow, and white colors on this map of California reveal regions where strong ground shaking would occur during a possible magnitude-8 earthquake on the San Andreas Fault Orange, yellow, and white colors on this map of California reveal regions where strong ground shaking would occur during a possible magnitude-8 earthquake on the San Andreas Fault. The seismograms shown on the map indicate peak velocity ground motions for selected California

  13. Breaking Ground on Computational Research and Theory Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Berkeley Lab Breaks Ground on New Computational Research Facility Breaking Ground on Computational Research and Theory Facility CRT to Foster Scientific Collaboration in Energy-Efficient Setting February 1, 2012 Jon Bashor, Jbashor@lbl.gov, +1 510-486-5849 Department of Energy Secretary Steven Chu, along with Lawrence Berkeley National Laboratory (Berkeley Lab) and University of California leaders, broke ground on the Lab's Computational Research and Theory (CRT) facility, Wednesday, Feb. 1. The

  14. Cleanup Verification Package for the 618-3 Burial Ground

    SciTech Connect (OSTI)

    M. J. Appel

    2006-09-12

    This cleanup verification package documents completion of remedial action for the 618-3 Solid Waste Burial Ground, also referred to as Burial Ground Number 3 and the Dry Waste Burial Ground Number 3. During its period of operation, the 618-3 site was used to dispose of uranium-contaminated construction debris from the 311 Building and construction/demolition debris from remodeling of the 313, 303-J and 303-K Buildings.

  15. Ground Source Heat Pump Demonstration Projects | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ground Source Heat Pump Demonstration Projects Ground Source Heat Pump Demonstration Projects Below are the project presentations and respective peer review results for Ground Source Heat Pump Demonstration Projects. Two (2) 175 Ton (350 Tons total) Chiller Geothermal Heat Pumps for recently commissioned LEED Platinum Building, Terry Hoffmann, Johnson Controls National Certification Standard for the Geothermal Heat Pump Industry, John Kelly Geothermal Heat Pump Consortium Measuring the Costs and

  16. Ground Source Heat Pump Subprogram Overview | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ground Source Heat Pump Subprogram Overview Ground Source Heat Pump Subprogram Overview This overview of GTP's Ground Source Heat Pump subprogram was given at GTP's Program Peer Review on May 18, 2010. PDF icon overview_gshp.pdf More Documents & Publications TN Energy Efficient Schools Initiative GSHP Program Large Scale GSHP as Alternative Energy for American Farmers Development of Design and Simulation Tool for Hybrid Geothermal Heat Pump System

  17. Monitoring SERC Technologies -Geothermal/Ground Source Heat Pumps |

    Office of Environmental Management (EM)

    Department of Energy Monitoring SERC Technologies -Geothermal/Ground Source Heat Pumps Monitoring SERC Technologies -Geothermal/Ground Source Heat Pumps On Nov. 3, 2011, Dave Peterson, a Project Leader at the National Renewable Energy Laboratory, presented a Webinar about Geothermal/Ground Source Heat Pumps and how to properly monitor their installation. View the webinar presentation or read the transcript. More Information Some resources and tools mentioned in the presentation include: U.S.

  18. Ground Magnetics At San Francisco Volcanic Field Area (Warpinski...

    Open Energy Info (EERE)

    San Francisco Volcanic Field Area (Warpinski, Et Al., 2004) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Ground Magnetics At San Francisco...

  19. Ground Gravity Survey At San Francisco Volcanic Field Area (Warpinski...

    Open Energy Info (EERE)

    Francisco Volcanic Field Area (Warpinski, Et Al., 2004) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Ground Gravity Survey At San Francisco...

  20. Category:Ground Gravity Survey | Open Energy Information

    Open Energy Info (EERE)

    Apps Datasets Community Login | Sign Up Search Category Edit History Category:Ground Gravity Survey Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home...