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Note: This page contains sample records for the topic "byproducts aromatic extracts" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Improved procedure for extraction of aromatic bases from synfuel materials. [Aromatic amines; azaarenes  

SciTech Connect

The present study was undertaken to evaluate the conventional aqueous acidbase extraction procedures and to explore alternate conditions for optimizing recovery of aromatic bases. For four procedures the recoveries were measured for 13 components in a mixture containing phenols, polynuclear aromatic hydrocarbons(PAH), primary aromatic amines (PAA), and azaarenes (AA) representative of the types of compounds found in synfuel materials. The results demonstrated that recoveries of hydrophobic 3 to 5 ring PAA and AA can be dramatically increased by using methanol as a cosolvent. The modified procedure is highly efficient for extraction of larger PAA and AA, and does not lead to emulsions when extracting samples of coal-derived materials. 2 figures, 2 tables.

Boparai, A.S.; Haugen, D.A.; Schneider, J.F.

1981-01-01T23:59:59.000Z

2

Extraction agents for the removal of polycyclic aromatic hydrocarbons (PAHs) from soil in soil washing technologies  

Science Journals Connector (OSTI)

Abstract Polycyclic aromatic hydrocarbons (PAHs) in soil have been recognised as a serious health and environmental issue due to their carcinogenic, mutagenic and teratogenic properties. One of the commonly employed soil remediation techniques to clean up such contamination is soil washing or solvent extraction. The main factor which governs the efficiency of this process is the solubility of \\{PAHs\\} in the extraction agent. Past field-scale soil washing treatments for PAH-contaminated soil have mainly employed organic solvents or water which is either toxic and costly or inefficient in removing higher molecular weight PAHs. Thus, the present article aims to provide a review and discussion of the alternative extraction agents that have been studied, including surfactants, biosurfactants, microemulsions, natural surfactants, cyclodextrins, vegetable oil and solution with solid phase particles. These extraction agents have been found to remove \\{PAHs\\} from soil at percentages ranging from 47 to 100% for various PAHs.

Ee Von Lau; Suyin Gan; Hoon Kiat Ng; Phaik Eong Poh

2014-01-01T23:59:59.000Z

3

E-Print Network 3.0 - aromatic hydrocarbons extracted Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

of Toxic Contamination Summary: called aromatic hydrocarbons. These include harmful pollutants like dioxins, PCBs and a group called... polycyclic aromatic hydrocarbons (PAHs)....

4

Silica Scale Management: Lowering Operating Costs through Improved Scale Control, and Adding Value by Extracting Marketable By-Products  

SciTech Connect

We are using laboratory and field experiments to design modeling tools and technology that will improve silica scale management practices in geothermal plants. Our work will help to lower operating costs through improved scale prediction and add new revenue streams from sale of mineral byproducts extracted from geothermal fluids. Improving the economics and effectiveness of scale control programs and/or extraction systems in geothermal operations requires a coupled kinetic-thermodynamic model of silica behavior. Silica scale precipitation is a multi-step process, involving a nucleation-related induction period, aqueous polymerization, condensation of polymers to form colloids, and deposition onto a solid surface. Many chemical and physical variables influence the rates of these steps and their impacts must be quantified and predictable in order to optimally control silica behavior. To date, in laboratory studies, we have quantified the effects on silica polymerization of the following set of chemical variables: Na at 500 and 2000 ppm, pH values from 5 to 9, temperatures of 25 and 50 C, and silica saturation values from 1.2 to 6 at initial dissolved silica concentrations of 600 ppm. Lowering pH both increases the induction time prior to polymerization and decreases the polymerization rate. We have successfully used a multiple regression model to predict polymerization rates from these variables. Geothermal fluids contain significant dissolved concentrations of potentially valuable mineral resources such as zinc, lithium, cesium and rubidium, but silica fouling interferes with traditional extraction methods. We are developing customized and new technologies to extract the silica as a commercial-grade commodity as well as the valuable metals. We are conducting field testing of some of these techniques at a Mammoth, CA geothermal plant using a reverse osmosis unit to concentrate the fluid, adding a commercial agglomerating agent to promote silica precipitation, and then removing the silica using a tangential flow ultrafilter. The particle size, surface area and trace impurities of the silica are characterized for comparison with commercial-grade silica products. We are also testing ion exchange resins and other functionalized materials to extract potentially economic concentrations of lithium, cesium, and rubidium that are enriched in the reverse osmosis concentrate.

Burton, E A; Bourcier, W L; Wallce, A; Bruton, C J; Leif, R

2003-06-18T23:59:59.000Z

5

Extraction of aromatics from petroleum naphtha reformate by a 1-cyclohexyl-2-pyrrolidone/ethylene carbonate mixed solvent  

SciTech Connect

The phase equilibria for the extraction of aromatics from petroleum naphtha reformate (with a boiling range of 338--403 K) using a mixed solvent of 1-cyclohexyl-2-pyrrolidone (CHP) and ethylene carbonate (EC) have been correlated using the universal function-group activity coefficients model (UNIFAC). The interaction parameters of CHP and EC with different hydrocarbon groups present in the reformate such as CH{sub 2} (paraffinic CH{sub 2}), ACH (aromatic CH), ACCH{sub 2} (aromatic CCH{sub 2}), and each of the two solvents have been fitted to experimental concentrations of three ternary systems that contain these groups. The extraction runs have been carried out at different temperatures, solvent compositions, and solvent-to-feed ratios. Experimental results compared favorably with those predicted from the UNIFAC method. The optimum extraction conditions were determined by calculation of the minimum energy of separation. In this study these conditions were found to be at a mixed solvent composition of 65% EC (by weight) and 35% CHP. The solvent-to-feed ratio was 1.8 on a volume basis, and the extraction temperature was 329 K.

Radwan, G.M.; Al-Muhtaseb, S.A.; Dowaidar, A.M.; Fahim, M.A. [United Arab Emirates Univ., Al-Ain (United Arab Emirates). Chemical and Petroleum Engineering Dept.] [United Arab Emirates Univ., Al-Ain (United Arab Emirates). Chemical and Petroleum Engineering Dept.

1997-02-01T23:59:59.000Z

6

Extraction of Lignite Coal Fly Ash for Polynuclear Aromatic Hydrocarbons: Modified and Unmodified Supercritical Fluid Extraction, Enhanced-Fluidity Solvents, and Accelerated Solvent Extraction  

Science Journals Connector (OSTI)

......7440-44-0 Carbon | Carbon analysis chemistry Coal analysis Coal Ash Gas Chromatography-Mass...Hydrocarbons, Aromatic analysis chemistry Industrial Waste analysis Particulate...particles on the interaction of coal combustion stack ash with organic matter......

Donald V. Kenny; Susan V. Olesik

1998-02-01T23:59:59.000Z

7

Synergistic selective extraction of actinides(III) over lanthanides from nitric acid using new aromatic diorganyldithiophosphinic acids and neutral organophosphorus compounds  

SciTech Connect

New aromatic dithiophosphinic acids (R{sub 2}PSSH) with R = C{sub 6}H{sub 5{sup {minus}}}, ClC{sub 6}H{sub 4{sup {minus}}}, FC{sub 6}H{sub 4{sup {minus}}} and CH{sub 3}C{sub 6}H{sub 4{sup {minus}}} were synthesized, characterized and tested as potential separating agents for trivalent actinides over lanthanides. The extraction of Am(III), Eu(III) and other lanthanides was carried out from nitric acid medium with mixtures of R{sub 2}PSSHs and neutral organophosphorus compounds. There was no detectable extraction when R{sub 2}PSSHs were used alone as extractants for either Am(III) or Eu(III) (D{sub Am,Eu} < 10{sup {minus}3}) under the experimental conditions used in this study. High separation factors (D{sub Am}/D{sub Eu} > 20) with D{sub Am} > 1 were achieved in the nitric acid range 0.1--1 mol/L by means of a synergistic mixture of bis(chlorophenyl)dithiophosphinic acid + tributylphosphate (TBP), trioctylphosphine oxide (TOPO) or tributylphosphine oxide (TBPO). The high radiation resistance (up to 10{sup 6} Gy absorbed {gamma}-doses) of the extractants was also demonstrated.

Modolo, G.; Odoj, R. [Forschungszentrum Juelich GmbH (Germany). Inst. fuer Sicherheitsforschung und Reaktortechnik

1999-01-01T23:59:59.000Z

8

Development of a new sorptive extraction method based on simultaneous direct and headspace sampling modes for the screening of polycyclic aromatic hydrocarbons in water samples  

Science Journals Connector (OSTI)

Abstract A new straightforward and inexpensive sample screening method for both EPA and EU priority polycyclic aromatic hydrocarbons (PAHs) in water has been developed. The method is based on combined direct immersion and headspace (DIHS) sorptive extraction, using low-cost disposable material, coupled to ultraperformance liquid chromatography with fluorescence and UV detection (UPLC-FD-UV). Extraction parameters, such as the sampling mode, extraction time and ionic strength were investigated in detail and optimized. Under optimized conditions, water samples (16 mL) were concentrated in silicone disks by headspace (HS) and direct immersion (DI) modes simultaneously, at room temperature for 9 h for the majority of the 24 studied compounds. Ultrasound-assisted desorption of extracted analytes in acetonitrile was carried out also at room temperature. The optimized chromatographic method provided a good linearity (R?0.9991) and a broad linear range for all studied PAHs. The proposed analytical procedure exhibited a good precision level with relative standard deviations below 15% for all analytes. Quantification limits between 0.7 and 2.3 µg L?1 and 0.16 and 3.90 ng L?1 were obtained for compounds analyzed by UV (acenaphtylene, cyclopenta[c,d]pyrene and benzo[j]fluoranthene) and fluorescence, respectively. Finally, the proposed method was applied to the determination of \\{PAHs\\} in different real tap, river and wastewater samples.

Sara Trińanes; Ma Teresa Pena; Ma Carmen Casais; Ma Carmen Mejuto

2015-01-01T23:59:59.000Z

9

By-Products Utilization  

E-Print Network (OSTI)

Center for By-Products Utilization CLEAN COAL BY-PRODUCTS UTILIZATION IN ROADWAY, EMBANKMENTS-fueled plants, particularly use of eastern coals, has lead to the use of clean coal and using advanced sulfur dioxide control technologies. Figure 1 shows clean coal technology benefits(2) . In 1977, the concept

Wisconsin-Milwaukee, University of

10

E-Print Network 3.0 - aromatic hydrocarbon exposure Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Aust. J. Mar. Freshw. Res., 1984, 35, 119-28 Aromatic Hydrocarbons in Waters of Port Phillip Bay... of aromatic hydrocarbons in coastal waters, using solvent extraction and...

11

E-Print Network 3.0 - aromatic hydrocarbons phahs Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

WH, Caton JE. 1983. Extraction of polycyclic aromatic hydrocarbons for qualitative analysis. In... : Handbook of Polycyclic Aromatic ... Source: Rock, Chris - Department of...

12

By-Products Utilization  

E-Print Network (OSTI)

%) were used in producing the concrete mixtures. The water to cementitious materials ratio was kept with and without by-products, and soil and groundwater remediation technologies including bioremediation. ACI

Wisconsin-Milwaukee, University of

13

Combustion Byproducts Recycling Consortium  

SciTech Connect

Each year, over 100 million tons of solid byproducts are produced by coal-burning electric utilities in the United States. Annual production of flue gas desulfurization (FGD) byproducts continues to increase as the result of more stringent sulfur emission restrictions. In addition, stricter limits on NOx emissions mandated by the 1990 Clean Air Act have resulted in utility burner/boiler modifications that frequently yield higher carbon concentrations in fly ash, which restricts the use of the ash as a cement replacement. Controlling ammonia in ash is also of concern. If newer, 'clean coal' combustion and gasification technologies are adopted, their byproducts may also present a management challenge. The objective of the Combustion Byproducts Recycling Consortium (CBRC) is to develop and demonstrate technologies to address issues related to the recycling of byproducts associated with coal combustion processes. A goal of CBRC is that these technologies, by the year 2010, will lead to an overall ash utilization rate from the current 34% to 50% by such measures as increasing the current rate of FGD byproduct use and increasing in the number of uses considered 'allowable' under state regulations. Another issue of interest to the CBRC would be to examine the environmental impact of both byproduct utilization and disposal. No byproduct utilization technology is likely to be adopted by industry unless it is more cost-effective than landfilling. Therefore, it is extremely important that the utility industry provide guidance to the R&D program. Government agencies and private-sector organizations that may be able to utilize these materials in the conduct of their missions should also provide input. The CBRC will serve as an effective vehicle for acquiring and maintaining guidance from these diverse organizations so that the proper balance in the R&D program is achieved.

Paul Ziemkiewicz; Tamara Vandivort; Debra Pflughoeft-Hassett; Y. Paul Chugh; James Hower

2008-08-31T23:59:59.000Z

14

Combustion Byproducts Recycling Consortium  

SciTech Connect

Each year, over 100 million tons of solid byproducts are produced by coal-burning electric utilities in the United States. Annual production of flue gas desulfurization (FGD) byproducts continues to increase as the result of more stringent sulfur emission restrictions. In addition, stricter limits on NOx emissions mandated by the 1990 Clean Air Act have resulted in utility burner/boiler modifications that frequently yield higher carbon concentrations in fly ash, which restricts the use of the ash as a cement replacement. Controlling ammonia in ash is also of concern. If newer, “clean coal” combustion and gasification technologies are adopted, their byproducts may also present a management challenge. The objective of the Combustion Byproducts Recycling Consortium (CBRC) is to develop and demonstrate technologies to address issues related to the recycling of byproducts associated with coal combustion processes. A goal of CBRC is that these technologies, by the year 2010, will lead to an overall ash utilization rate from the current 34% to 50% by such measures as increasing the current rate of FGD byproduct use and increasing in the number of uses considered “allowable” under state regulations. Another issue of interest to the CBRC would be to examine the environmental impact of both byproduct utilization and disposal. No byproduct utilization technology is likely to be adopted by industry unless it is more cost-effective than landfilling. Therefore, it is extremely important that the utility industry provide guidance to the R&D program. Government agencies and privatesector organizations that may be able to utilize these materials in the conduct of their missions should also provide input. The CBRC will serve as an effective vehicle for acquiring and maintaining guidance from these diverse organizations so that the proper balance in the R&D program is achieved.

Ziemkiewicz, Paul; Vandivort, Tamara; Pflughoeft-Hassett, Debra; Chugh, Y Paul; Hower, James

2008-08-31T23:59:59.000Z

15

Synthesis of g-C3N4/Fe3O4 nanocomposites and application as a new sorbent for solid phase extraction of polycyclic aromatic hydrocarbons in water samples  

Science Journals Connector (OSTI)

Abstract An easy preparation of g-C3N4/Fe3O4 nanocomposites by chemical co-precipitation has been demonstrated. The as-prepared materials were characterized by X-ray diffraction, transmission electron microscopy, Fourier transform infrared spectroscopy and thermogravimetric analysis. The high affinity of g-C3N4 toward polycyclic aromatic hydrocarbons and the magnetic behavior of Fe3O4 were combined to provide an efficient and simple magnetic solid phase extraction (MSPE). The adsorption and desorption of polycyclic aromatic hydrocarbons on g-C3N4/Fe3O4 were examined. Different factors affecting the magnetic solid phase extraction of polycyclic aromatic hydrocarbons were assessed in terms of adsorption, desorption, and recovery. Under the optimized conditions, the proposed method showed good limits of detection (LOD, S/N=3) in the range of 0.05–0.1 ng mL?1 and precision in the range of 1.8–5.3% (RSDs, n=3). This method was also successfully applied to the analysis of real water samples; good spiked recoveries over the range of 80.0–99.8% were obtained.

Man Wang; Shihai Cui; Xiaodi Yang; Wentao Bi

2015-01-01T23:59:59.000Z

16

By-Products Utilization  

E-Print Network (OSTI)

ECONOMICAL SELF-COMPACTING CONCRETE By Tarun R. Naik, Rudolph N. Kraus, Yoon-moon Chun, Fethullah Canpolat #12;USE OF FLY ASH AND LIMESTONE QUARRY BY-PRODUCTS FOR DEVELOPING ECONOMICAL SELF-COMPACTING CONCRETE material in the development of economical self-compacting concrete (SCC). Class C fly ash was also used

Wisconsin-Milwaukee, University of

17

By-Products Utilization  

E-Print Network (OSTI)

SELF-COMPACTING CONCRETE By Tarun R. Naik, Rudolph N. Kraus, and Yoon-moon Chun Report No. CBU-2004 of Limestone Quarry By-Products for Developing Economical Self-Compacting Concrete Principle Investigator Name. For this proposed project, self-compacting concrete mixtures will be developed for prototype production that utilize

Wisconsin-Milwaukee, University of

18

By-Products Utilization  

E-Print Network (OSTI)

Center for By-Products Utilization SELF-COMPACTING CONCRETE (SCC) OR SELF- LEVELING CONCRETE (SLC - MILWAUKEE #12;2 SELF-COMPACTING CONCRETE (SCC) OR SELF ­LEVELING CONCRETE (SLC) INTRODUCTION Self-compacting as the concrete which can be placed and compacted into every corner of a form work, purely by means of its self

Wisconsin-Milwaukee, University of

19

By-Products Utilization  

E-Print Network (OSTI)

SELF-COMPACTING CONCRETE By Tarun R. Naik, Rudolph N. Kraus, Yoon-moon Chun, Fethullah Canpolat ECONOMICAL SELF-COMPACTING CONCRETE by Tarun R. Naik* , Rudolph N. Kraus** , Yoon-moon Chun*** , Fethullah of limestone-quarry by-product material in the development of economical self-compacting concrete (SCC). Class

Wisconsin-Milwaukee, University of

20

By-Products Utilization  

E-Print Network (OSTI)

SELF-COMPACTING CONCRETE By Tarun R. Naik and Rakesh Kumar Report No. CBU-2003-15 REP-509 April 2003 CONCRETE April 2003 REP-509 #12;ii Use of Limestone Quarry By-Products for Developing Economical Self-Compacting in the production of economical self-compacting concrete. OBJECTIVE: The primary objective of this project

Wisconsin-Milwaukee, University of

Note: This page contains sample records for the topic "byproducts aromatic extracts" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

By-Products Utilization  

E-Print Network (OSTI)

Center for By-Products Utilization USE OF CLEAN COAL ASH AS SETTING TIME REGULATOR IN PORTLAND OF WISCONSIN ­ MILWAUKEE #12;2 Use of Clean Coal Ash as Setting Time Regulator in Portland Cement by Zichao Wu as setting time regulator for portland cement production. In this paper a source of clean coal ash (CCA

Wisconsin-Milwaukee, University of

22

By-Products Utilization  

E-Print Network (OSTI)

of coal in conventional and/ or advanced clean coal technology combustors. These include fly ash, bottom ash, boiler slag, and flue gas desulfurization (FGD) by-products from advanced clean coal technology clean coal technology combustors. Over 60% of the CCBs are generated as fly ash. An estimate

Wisconsin-Milwaukee, University of

23

By-Products Utilization  

E-Print Network (OSTI)

Center for By-Products Utilization HIGH-STRENGTH HVFA CONCRETE CONTAINING CLEAN COAL ASH By Tarun R #12;1 HIGH-STRENGTH HVFA CONCRETE CONTAINING CLEAN COAL ASH By Tarun R. Naik, Shiw S. Singh, and Bruce for manufacture of cement-based products using ashes generated from combustion of high-sulfur coals. A clean coal

Wisconsin-Milwaukee, University of

24

By-Products Utilization  

E-Print Network (OSTI)

shrinkage; durability; freezing and thawing; recycling; sludge; wastewater treatment; wood cellulose fibersCenter for By-Products Utilization RECYCLING OF PULP AND PAPER MILL RESIDUALS TO INCREASE FREEZING College of Engineering and Applied Science THE UNIVERSITY OF WISCONSIN ­ MILWAUKEE #12;Recycling of Pulp

Wisconsin-Milwaukee, University of

25

By-Products Utilization  

E-Print Network (OSTI)

Center for By-Products Utilization GREENER CONCRETE FROM WOOD FLY ASH AND COAL FLY ASH By Tarun R CONCRETE FROM WOOD FLY ASH AND COAL FLY ASH By Tarun R. Naik, Rudolph N. Kraus, Shiw S. Singh, Lori-Lynn C mixtures were developed using blends of wood FA and Class C coal FA. Two levels of blended ash

Wisconsin-Milwaukee, University of

26

By-Products Utilization  

E-Print Network (OSTI)

Fellow at the UWM-CBU. His research interests include the use of coal fly ash, coal bottom ash, and usedCenter for By-Products Utilization USE OF UNDER-UTILIZED COAL- COMBUSTION PRODUCTS IN PERMEABLE-Utilized Coal-Combustion Products in Permeable Roadway Base Construction 1 (MS #LV-R67) Use of Under

Wisconsin-Milwaukee, University of

27

By-Products Utilization  

E-Print Network (OSTI)

) coal-ash and by replacing up to 9% of aggregates with wet-collected, low-lime, coarse coal-ash. Cast of coal fly ash, coal bottom ash, and used foundry sand in concrete and cast-concrete productsCenter for By-Products Utilization PROPERTIES OF CAST-CONCRETE PRODUCTS MADE WITH FBC ASH

Wisconsin-Milwaukee, University of

28

By-Products Utilization  

E-Print Network (OSTI)

Center for By-Products Utilization USE OF CLASS F FLY ASH AND CLEAN-COAL ASH BLENDS FOR CAST Report No.CBU-1996-07 July 1996 Presented and Published at the American Coal Ash Association's Twelfth International Coal Ash Use Symposium, Orlando, FL, January 26-30, 1997. Department of Civil Engineering

Wisconsin-Milwaukee, University of

29

By-Products Utilization  

E-Print Network (OSTI)

Center for By-Products Utilization GREENER CONCRETE FROM WOOD FLY ASH AND COAL FLY ASH By Tarun R OF WISCONSIN­MILWAUKEE #12;1 GREENER CONCRETE FROM WOOD FLY ASH AND COAL FLY ASH Synopsis: This investigation coal FA. Two levels of blended ash of approximately 25% and 35% were used. The effect of source of wood

Wisconsin-Milwaukee, University of

30

By-Products Utilization  

E-Print Network (OSTI)

Center for By-Products Utilization PROPERTIES OF CONCRETE CONTAINING SCRAP TIRE RUBBER in a variety of rubber and plastic products, thermal incineration of waste tires for production of electricity rubber in asphalt mixes, (ii) thermal incineration of worn-out tires for the production of electricity

Wisconsin-Milwaukee, University of

31

By-Products Utilization  

E-Print Network (OSTI)

Center for By-Products Utilization APPLICATION OF SCRAP TIRE RUBBER IN ASPHALTIC MATERIALS: STATE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 2. PRODUCING CRUMB RUBBER MODIFIER (CRM) FROM USED TIRES . . . . . 3 2.1 PRODUCTION OF CRM THE UNIVERSITY OF WISCONSIN - MILWAUKEE #12;APPLICATION OF SCRAP TIRE RUBBER IN ASPHALTIC MATERIALS: STATE

Wisconsin-Milwaukee, University of

32

By-Products Utilization  

E-Print Network (OSTI)

include workability, water requirement, bleeding, segregation, air content, time of set, and temperature with and without by-products, and soil and groundwater remediation technologies including bioremediation. ACI for power production. Its combustion in electric power plants produces large amounts of fly ash and bottom

Wisconsin-Milwaukee, University of

33

By-Products Utilization  

E-Print Network (OSTI)

-strength materials (CLSM); and, future research needs. The fresh concrete properties discussed are workability, water with and without by-products, and soil and groundwater remediation technologies including bioremediation. ACI for power production. Its combustion in electric power plants produces large amounts of fly ash and bottom

Wisconsin-Milwaukee, University of

34

By-Products Utilization  

E-Print Network (OSTI)

in a combination with a number of fuels including coal, petroleum coke, natural gas, etc. In the mid 1990s, the unit was firing a combination of coal and petroleum coke to generate energy. It has been established;1 PROJECT 1 - COAL COMBUSTION BY-PRODUCTS: CHARACTERIZATION AND USE OPTIONS Introduction An AFBC system

Wisconsin-Milwaukee, University of

35

By-Products Utilization  

E-Print Network (OSTI)

wood with supplementary fuels such as coal, oil, natural gas, and coke by pulp and paper mills and wood, knots, chips, etc. with other supplementary fuels such as coal, oil, natural gas, and coke to generateCenter for By-Products Utilization DEVELOPMENT OF CLSM USING COAL ASH AND WOOD ASH, A SOURCE OF NEW

Wisconsin-Milwaukee, University of

36

By-Products Utilization  

E-Print Network (OSTI)

with supplementary fuels such as coal, oil, natural gas, and coke by pulp and paper mills and wood, such as bark, twigs, knots, chips, etc. with other supplementary fuels such as coal, oil, natural gas, and cokeCenter for By-Products Utilization CLSM CONTAINING MIXTURES OF COAL ASH AND A NEW POZZOLANIC

Wisconsin-Milwaukee, University of

37

adherent polycyclic aromatic: Topics by E-print Network  

NLE Websites -- All DOE Office Websites (Extended Search)

Risk in First Nations People Exposed to Polycyclic Aromatic Hydrocarbons Near In-situ Bitumen Extraction in Cold Lake, Alberta . Open Access Theses and Dissertations Summary:...

38

By-Products Utilization  

E-Print Network (OSTI)

Center for By-Products Utilization USE OF FBC ASH AND PONDED COAL-ASH IN READY-MIXED CONCRETE #12;Naik, Kraus, Chun, & Botha Use of FBC ash and Ponded Coal-Ash in Ready-Mixed Concrete 1 MS# M8-60. FINAL. October 2005. Use of FBC Ash and Ponded Coal-Ash in Ready-Mixed Concrete by Tarun R. Naik

Wisconsin-Milwaukee, University of

39

Sorptive extraction using polydimethylsiloxane/metal–organic framework coated stir bars coupled with high performance liquid chromatography-fluorescence detection for the determination of polycyclic aromatic hydrocarbons in environmental water samples  

Science Journals Connector (OSTI)

Abstract In this work, metal–organic frameworks (MOFs, Al-MIL-53-NH2) were synthesized via the hydrothermal method, and novel polydimethylsiloxane/metal–organic framework (PDMS/MOFs, PDMS/Al-MIL-53-NH2)-coated stir bars were prepared by the sol–gel technique. The preparation reproducibility of the PDMS/MOFs-coated stir bar was good, with relative standard deviations (RSDs) ranging from 4.8% to 14.9% (n = 7) within one batch and from 6.2% to 16.9% (n = 6) among different batches. Based on this fact, a new method of PDMS/MOFs-coated stir bar sorptive extraction (SBSE) and ultrasonic-assisted liquid desorption (UALD) coupled with high performance liquid chromatography-fluorescence detection (HPLC-FLD) was developed for the determination of polycyclic aromatic hydrocarbons (PAHs) in environmental water samples. To obtain the best extraction performance for PAHs, several parameters affecting SBSE, such as extraction time, stirring rate, and extraction temperature, were investigated. Under optimal experimental conditions, wide linear ranges and good \\{RSDs\\} (n = 7) were obtained. With enrichment factors (EFs) of 16.1- to 88.9-fold (theoretical EF, 142-fold), the limits of detection (LODs, S/N = 3) of the developed method for the target \\{PAHs\\} were found to be in the range of 0.05–2.94 ng/L. The developed method was successfully applied to the analysis of \\{PAHs\\} in Yangtze River and East Lake water samples.

Cong Hu; Man He; Beibei Chen; Cheng Zhong; Bin Hu

2014-01-01T23:59:59.000Z

40

NETL: IEP - Coal Utilization By-Products: Consortium Byproducts Recycling  

NLE Websites -- All DOE Office Websites (Extended Search)

Combustion Byproducts Recycling Consortium (CBRC) Combustion Byproducts Recycling Consortium (CBRC) The mission of the Combustion Byproducts Recycling Consortium (CBRC) is to promote and support the commercially viable and environmentally sound recycling of coal combustion byproducts for productive uses through scientific research, development, and field testing. The overall goals of CBRC are to: Increase the overall national rate of byproduct use by to ~ 50 % by 2010 Increase the number of “allowable” byproduct uses under state regulations by ~ 25% Double of the current rate of FGD byproduct use CBRC is a unique partnership that integrates the electric power industry, State and Federal regulatory agencies, and academia to form a strong, cohesive consortium to guide the national and regional research priorities of the CBRC. CBRC is managed by the West Virginia Water Research Institute at West Virginia University and is administered by regional centers at the University of Kentucky (Eastern Region), Southern Illinois University (Midwest Region) and the University of North Dakota (Western Region). Primary funding for CBRC is provided by the U.S. Department of Energy’s National Energy Technology Laboratory (DOE-NETL).

Note: This page contains sample records for the topic "byproducts aromatic extracts" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Feeding Corn Milling Byproducts to Feedlot Cattle  

Science Journals Connector (OSTI)

Corn milling byproducts are expected to increase dramatically in supply as the ethanol industry expands. Distillers grains, corn gluten feed, or a combination of both byproducts offer many feeding options when included in feedlot rations. These byproduct feeds may effectively improve cattle performance and operation profitability. When these byproducts are fed in feedlot diets, adjustments to grain processing method and roughage level may improve cattle performance. Innovative storage methods for wet byproducts and the use of dried byproducts offer small operations flexibility when using byproducts. As new byproducts are developed by ethanol plants, they should be evaluated with performance data to determine their product-specific feeding values.

Terry J. Klopfenstein; Galen E. Erickson; Virgil R. Bremer

2007-01-01T23:59:59.000Z

42

Combustion Byproducts Recycling Consortium  

SciTech Connect

The Combustion Byproducts Recycling Consortium (CBRC) program was developed as a focused program to remove and/or minimize the barriers for effective management of over 123 million tons of coal combustion byproducts (CCBs) annually generated in the USA. At the time of launching the CBRC in 1998, about 25% of CCBs were beneficially utilized while the remaining was disposed in on-site or off-site landfills. During the ten (10) year tenure of CBRC (1998-2008), after a critical review, 52 projects were funded nationwide. By region, the East, Midwest, and West had 21, 18, and 13 projects funded, respectively. Almost all projects were cooperative projects involving industry, government, and academia. The CBRC projects, to a large extent, successfully addressed the problems of large-scale utilization of CCBs. A few projects, such as the two Eastern Region projects that addressed the use of fly ash in foundry applications, might be thought of as a somewhat smaller application in comparison to construction and agricultural uses, but as a novel niche use, they set the stage to draw interest that fly ash substitution for Portland cement might not attract. With consideration of the large increase in flue gas desulfurization (FGD) gypsum in response to EPA regulations, agricultural uses of FGD gypsum hold promise for large-scale uses of a product currently directed to the (currently stagnant) home construction market. Outstanding achievements of the program are: (1) The CBRC successfully enhanced professional expertise in the area of CCBs throughout the nation. The enhanced capacity continues to provide technology and information transfer expertise to industry and regulatory agencies. (2) Several technologies were developed that can be used immediately. These include: (a) Use of CCBs for road base and sub-base applications; (b) full-depth, in situ stabilization of gravel roads or highway/pavement construction recycled materials; and (c) fired bricks containing up to 30%-40% F-fly ash. Some developed technologies have similar potential in the longer term. (3) Laboratory studies have been completed that indicate that much higher amounts of fly ash could be added in cement-concrete applications under some circumstances. This could significantly increase use of fly ash in cement-concrete applications. (4) A study of the long-term environmental effects of structural fills in a surface mine in Indiana was completed. This study has provided much sought after data for permitting large-volume management options in both beneficial as well as non-beneficial use settings. (5) The impact of CBRC on CCBs utilization trends is difficult to quantify. However it is fair to say that the CBRC program had a significant positive impact on increased utilization of CCBs in every region of the USA. Today, the overall utilization of CCBs is over 43%. (6) CBRC-developed knowledge base led to a large number of other projects completed with support from other sources of funding. (7) CBRC research has also had a large impact on CCBs management across the globe. Information transfer activities and visitors from leading coal producing countries such as South Africa, Australia, England, India, China, Poland, Czech Republic and Japan are truly noteworthy. (8) Overall, the CBRC has been a truly successful, cooperative research program. It has brought together researchers, industry, government, and regulators to deal with a major problem facing the USA and other coal producing countries in the world.

Paul Ziemkiewicz; Tamara Vandivort; Debra Pflughoeft-Hassett; Y. Paul Chugh; James Hower

2008-08-31T23:59:59.000Z

43

Coal extraction  

SciTech Connect

Coal is extracted using a mixed solvent which includes a substantially aromatic component and a substantially naphthenic component, at a temperature of 400/sup 0/ to 500/sup 0/C. Although neither component is an especially good solvent for coal by itself, the use of mixed solvent gives greater flexibility to the process and offers efficiency gains.

Clarke, J.W.; Kimber, G.M.; Rantell, T.D.; Snape, C.E.

1985-06-04T23:59:59.000Z

44

Multicomponent isolation and analysis of polynuclear aromatics  

SciTech Connect

Semi-preparative scale high-pressure liquid chromatography using bonded normal-phase columns offers an attractive alternative to the classical solvent partition/adsorption column chromatographic procedure for obtaining polycyclic aromatic hydrocarbons (PAH) or a polycyclic aromatic amines (PAA) fraction of purity suitable for analysis by gas chromatography. Sample matrices ranging from fossil fuels to air particulate extracts can be fractionated successfully if the appropriate polarity column is chosen. The apparatus is low-cost, gives reproducible results, does not require an expensive solvent gradient programmer, and can operate unattended.

Tomkins, B.A.; Griest, W.H.; Caton, J.E.; Reagan, R.R.

1981-01-01T23:59:59.000Z

45

Aromatics, Narcotics, Stimulants, Spices  

Science Journals Connector (OSTI)

This rather heterogeneous chapter includes native psycho-active plants and aromatics, as well as industrially highly developed stimulants and spices. We have refrained from discussing the many drugs and halluc...

Prof. Dr. Heinz Brücher

1989-01-01T23:59:59.000Z

46

Aromatics Extraction Plant Design Using Synthesis Techniques  

E-Print Network (OSTI)

and process modifications can make even larger savings possible. Table 1 summarizes the substantially reduced energy cost as successively more process synthesis techniques were applied. Paybacks are very shorl because the total capital cost remained nearly... utility target multiplied by the cost of hot utility plus the cold utility target multiplied by the cost of cold utility. The annual capital cost target is calculaled as follows: The area target above the pinch is divided by the number of units target...

Wilcox, R. J.; Nedwick, R.

47

Coal Combustion By-Products (Maryland)  

Energy.gov (U.S. Department of Energy (DOE))

The Department of the Environment is responsible for regulating fugitive air emissions from the transportation of coal combustion by-products and the permissible beneficial uses of these by...

48

Center for By-Products Utilization CO2 SEQUESTRATION  

E-Print Network (OSTI)

Center for By-Products Utilization CO2 SEQUESTRATION IN NON-AIR ENTRAINED CONCRETE By Tarun R. Naik. Maximize environmental benefits: resource conservation, clean water, and clean air. #12;Center for By-Products, Italy, June 30, 2010. #12;Center for By-Products Utilization UWM Center for By-Products Utilization

Saldin, Dilano

49

SOLVENT FIRE BY-PRODUCTS  

SciTech Connect

Southwest Research Institute (SwRI) conducted a burn test of the Caustic-Side Solvent Extraction (CSSX) solvent to determine the combustion products. The testing showed hydrogen fluoride gas is not a combustion product from a solvent fire when up to 70% of the solvent is consumed. The absence of HF in the combustion gases may reflect concentration of the modifier containing the fluoride groups in the unburned portion. SwRI reported results for other gases (CO, HCN, NOx, formaldehyde, and hydrocarbons). The results, with other supporting information, can be used for evaluating the consequences of a facility fire involving the CSSX solvent inventory.

Walker, D; Samuel Fink, S

2006-05-22T23:59:59.000Z

50

E-Print Network 3.0 - avoiding by-product formation Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

78 By-Products Utilization Summary: Center for By-Products Utilization ECONOMICAL SELF-CONSOLIDATING CONCRETE FOR THE WISCONSIN... production using by-product materials to...

51

Process for removing halogenated aliphatic and aromatic compounds from petroleum products  

DOE Patents (OSTI)

A process is described for removing halogenated aliphatic and aromatic compounds, e.g., polychlorinated biphenyls, from petroleum products by solvent extraction. The halogenated aliphatic and aromatic compounds are extracted from a petroleum product into a polar solvent by contacting the petroleum product with the polar solvent. The polar solvent is characterized by a high solubility for the extracted halogenated aliphatic and aromatic compounds, a low solubility for the petroleum product and considerable solvent power for polyhydroxy compound. The preferred polar solvent is dimethylformamide. A miscible compound, such as, water or a polyhydroxy compound, is added to the polar extraction solvent to increase the polarity of the polar extraction solvent. The halogenated aliphatic and aromatic compounds are extracted from the highly-polarized mixture of water or polyhydroxy compound and polar extraction solvent into a low polar or nonpolar solvent by contacting the water or polyhydroxy compound-polar solvent mixture with the low polar or nonpolar solvent. The halogenated aliphatic and aromatic compounds and the low polar or nonpolar solvent are separated by physical means, e.g., vacuum evaporation. The polar and nonpolar solvents are recovered from recycling. The process can easily be designed for continuous operation. Advantages of the process include that the polar solvent and a major portion of the nonpolar solvent can be recycled, the petroleum products are reclaimable and the cost for disposing of waste containing polychlorinated biphenyls is significantly reduced. 1 fig.

Googin, J.M.; Napier, J.M.; Travaglini, M.A.

1983-09-20T23:59:59.000Z

52

Center for By-Products Utilization Environment, Energy, and  

E-Print Network (OSTI)

benefits: resource conservation, clean water, and clean air. #12;Center for By-Products Utilization Basic;Center for By-Products Utilization RESOURCE CONSERVATION CLEAN WATER and CLEAN AIR "The earth, the seaCenter for By-Products Utilization Environment, Energy, and Economic Benefits of Using Recyclable

Saldin, Dilano

53

Detection of chlorinated aromatic compounds  

DOE Patents (OSTI)

A method for making a composition for measuring the concentration of chloated aromatic compounds in aqueous fluids, and an optical probe for use with the method. The composition comprises a hydrophobic polymer matrix, preferably polyamide, with a fluorescent indicator uniformly dispersed therein. The indicator fluoresces in the presence of the chlorinated aromatic compounds with an intensity dependent on the concentration of these compounds in the fluid of interest, such as 8-amino-2-naphthalene sulfonate. The probe includes a hollow cylindrical housing that contains the composition in its distal end. The probe admits an aqueous fluid to the probe interior for exposure to the composition. An optical fiber transmits excitation light from a remote source to the composition while the indicator reacts with chlorinated aromatic compounds present in the fluid. The resulting fluorescence light signal is reflected to a second optical fiber that transmits the light to a spectrophotometer for analysis.

Ekechukwu, Amy A. (Augusta, GA)

1996-01-01T23:59:59.000Z

54

Producing Beneficial Materials from Biomass and Biodiesel Byproducts...  

NLE Websites -- All DOE Office Websites (Extended Search)

Biomass and Biofuels Biomass and Biofuels Find More Like This Return to Search Producing Beneficial Materials from Biomass and Biodiesel Byproducts Lawrence Berkeley National...

55

Process for removing halogenated aliphatic and aromatic compounds from petroleum products. [Polychlorinated biphenyls; methylene chloride; perchloroethylene; trichlorofluoroethane; trichloroethylene; chlorobenzene  

DOE Patents (OSTI)

A process for removing halogenated aliphatic and aromatic compounds, e.g., polychlorinated biphenyls, from petroleum products by solvent extraction. The halogenated aliphatic and aromatic compounds are extracted from a petroleum product into a polar solvent by contracting the petroleum product with the polar solvent. The polar solvent is characterized by a high solubility for the extracted halogenated aliphatic and aromatic compounds, a low solubility for the petroleum product and considerable solvent power for polyhydroxy compound. The preferred polar solvent is dimethylformamide. A miscible polyhydroxy compound, such as, water, is added to the polar extraction solvent to increase the polarity of the polar extraction solvent. The halogenated aliphatic and aromatic compounds are extracted from the highly-polarized mixture of polyhydroxy compound and polar extraction solvent into a low polar or nonpolar solvent by contacting the polyhydroxy compound-polar solvent mixture with the low polar or nonpolar solvent. The halogenated aliphatic and aromatic compounds in the low polar or nonpolar solvent by physical means, e.g., vacuum evaporation. The polar and nonpolar solvents are recovered for recycling. The process can easily be designed for continuous operation. Advantages of the process include that the polar solvent and a major portion of the nonpolar solvent can be recycled, the petroleum products are reclaimable and the cost for disposing of waste containing polychlorinated biphenyls is significantly reduced. 2 tables.

Googin, J.M.; Napier, J.M.; Travaglini, M.A.

1982-03-31T23:59:59.000Z

56

Table 3.5 Selected Byproducts in Fuel Consumption, 2002  

U.S. Energy Information Administration (EIA) Indexed Site

5 Selected Byproducts in Fuel Consumption, 2002;" 5 Selected Byproducts in Fuel Consumption, 2002;" " Level: National Data and Regional Totals; " " Row: NAICS Codes; Column: Energy Sources;" " Unit: Trillion Btu." " "," "," "," "," "," "," "," ","Waste"," ",," " " "," "," ","Blast"," "," ","Pulping Liquor"," ","Oils/Tars","RSE" "NAICS"," "," ","Furnace/Coke","Waste","Petroleum","or","Wood Chips,","and Waste","Row"

57

CONSTRUCTION MATERIALS MADE WITH COAL COMBUSTION BY-PRODUCTS  

E-Print Network (OSTI)

ash and bottom ash are produced as by-products of coal-fired electricity generation. In many countries coal ashes are by-products of the coal combustion, their properties are influenced by the nature of understanding behavior of masonry products made from coal ashes. The objective of this research program

Wisconsin-Milwaukee, University of

58

Center for By-Products Utilization Sustainable Concrete with  

E-Print Network (OSTI)

landfilling them but also leads to the reduction of the the environmental pollution. #12;Center for ByCenter for By-Products Utilization Sustainable Concrete with Industrial and Post-Consumer By Construction Materials and Technologies, Ancona, Italy, June 2010 #12;Center for By-Products Utilization Why

Saldin, Dilano

59

Alkylation of organic aromatic compounds  

DOE Patents (OSTI)

Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C[sub 2] to C[sub 10] olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80 C to 500 C, using as the catalyst a mole sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene below the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms. 1 fig.

Smith, L.A. Jr.

1989-07-18T23:59:59.000Z

60

Alkylation of organic aromatic compounds  

DOE Patents (OSTI)

Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C.sub.2 to C.sub.10 olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80.degree. C. to 500.degree. C., using as the catalyst a mole sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene below the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms.

Smith, Jr., Lawrence A. (Houston, TX)

1989-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "byproducts aromatic extracts" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Alkylation of organic aromatic compounds  

DOE Patents (OSTI)

Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C.sub.2 to C.sub.10 olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80.degree. C. to 500.degree. C., using as the catalyst a mole sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene below the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms.

Smith, Jr., Lawrence A. (Bellaire, TX); Arganbright, Robert P. (Seabrook, TX); Hearn, Dennis (Houston, TX)

1994-01-01T23:59:59.000Z

62

Alkylation of organic aromatic compounds  

DOE Patents (OSTI)

Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C[sub 2] to C[sub 10] olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80 C to 500 C, using as the catalyst a molecular sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene to about the mid point of the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms. 1 figures.

Smith, L.A. Jr.; Arganbright, R.P.; Hearn, D.

1993-09-07T23:59:59.000Z

63

Alkylation of organic aromatic compounds  

DOE Patents (OSTI)

Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C[sub 2] to C[sub 10] olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80 C to 500 C, using as the catalyst a molecular sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene below the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms. 1 fig.

Smith, L.A. Jr.; Arganbright, R.P.; Hearn, D.

1994-06-14T23:59:59.000Z

64

Alkylation of organic aromatic compounds  

DOE Patents (OSTI)

Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C.sub.2 to C.sub.10 olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80.degree. C. to 500.degree. C., using as the catalyst a mole sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene to about the mid point of the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms.

Smith, Jr., Lawrence A. (Bellaire, TX); Arganbright, Robert P. (Seabrook, TX); Hearn, Dennis (Houston, TX)

1993-01-01T23:59:59.000Z

65

The utilization of flue gas desulfurization waste by-products in construction brick.  

E-Print Network (OSTI)

??Millions of tons of waste by-products from Texas coal burning plants are produced each year. Two common byproducts are the fuel ashes and calcium sulfate… (more)

Berryman, Charles Wayne

2012-01-01T23:59:59.000Z

66

Studies on the Applicability of Biomarkers in Estimating the Systemic Bioavailability of Polynuclear Aromatic Hydrocarbons from Manufactured Gas Plant Tar-Contaminated Soils  

Science Journals Connector (OSTI)

The systemic bioavailability of polynuclear aromatic hydrocarbons (PAH) from ingested soils containing manufactured gas plant (MGP) tar was evaluated in mice. Soil and organic extract of each soil were incorporated into a diet and fed to mice for two ...

Aruna Koganti; Deborah A. Spina; Kimberly Rozett; Bing-Li Ma; Eric H. Weyand; Barbara B. Taylor; David M. Mauro

1998-08-25T23:59:59.000Z

67

Prediction of Solid Polycyclic Aromatic Hydrocarbons Solubility in Water with the NRTL-PR Model  

E-Print Network (OSTI)

processes of PAH with subcritical water [5,6] since it provides the extractability limit which can be used groups, for the representation of the solubility of solid PAH in subcritical water. These hal-00872639Prediction of Solid Polycyclic Aromatic Hydrocarbons Solubility in Water with the NRTL-PR Model

Paris-Sud XI, Université de

68

Polycyclic Aromatic Triptycenes: Oxygen Substitution Cyclization Strategies  

E-Print Network (OSTI)

The cyclization and planarization of polycyclic aromatic hydrocarbons with concomitant oxygen substitution was achieved through acid catalyzed transetherification and oxygen-radical reactions. The triptycene scaffold ...

VanVeller, Brett

69

Fuel strategies, coal supply, dust control, and byproduct utilization  

SciTech Connect

This book contains articles presented at the 1990 International Joint Power Generation Conference. Included are the following papers: Waste management on hard coal fired power plants; Acid rain legislation FGD by-product concerns; Innovative transport modes; coal slurry pipelines.

Aananson, M.L. (Philadelphia Electric Co. (US)); Krishna, K. (Burns and McDonnell (US)); Mahr, D. (Burns and Roe Enterprises (US)); Nechvatal, T.M. (Wisconsin Electric Power Co. (US))

1990-01-01T23:59:59.000Z

70

Biodegradation of Aromatic Hydrocarbons in an Extremely Acidic Environment  

Science Journals Connector (OSTI)

...biodegradation of aromatic hydrocarbons can occur in environments...Polycyclic aromatic hydrocarbons (PAHs) occur as common...formed by incomplete combustion of fossil fuels...enrichments with aromatic hydrocarbons, mineralization assays...lysis was initiated by heat and sodium dodecyl...

Raymond D. Stapleton; Dwayne C. Savage; Gary S. Sayler; Gary Stacey

1998-11-01T23:59:59.000Z

71

High Levels of Carcinogenic Polycyclic Aromatic Hydrocarbons in Mate Drinks  

Science Journals Connector (OSTI)

...polycyclic aromatic hydrocarbons| Introduction Esophageal...polycyclic aromatic hydrocarbon (PAH) content. PAHs...usually exposed to combustion products from burning...SRM 2260a Aromatic Hydrocarbons in Toluene, SRM 2269...dichloromethane; heat: preheat cell at 100C...

Farin Kamangar; Michele M. Schantz; Christian C. Abnet; Renato B. Fagundes; and Sanford M. Dawsey

2008-05-01T23:59:59.000Z

72

High Levels of Carcinogenic Polycyclic Aromatic Hydrocarbons in Mate Drinks  

Science Journals Connector (OSTI)

...polycyclic aromatic hydrocarbons (PAH), including...polycyclic aromatic hydrocarbons| Introduction...mechanism. However, data on the association...polycyclic aromatic hydrocarbon (PAH) content...usually exposed to combustion products from burning...dichloromethane; heat: preheat cell...

Farin Kamangar; Michele M. Schantz; Christian C. Abnet; Renato B. Fagundes; and Sanford M. Dawsey

2008-05-01T23:59:59.000Z

73

High Levels of Carcinogenic Polycyclic Aromatic Hydrocarbons in Mate Drinks  

Science Journals Connector (OSTI)

...polycyclic aromatic hydrocarbons (PAH), including...80C) or cold (5C) water. Measurements were...polycyclic aromatic hydrocarbons in mate drinks. | Drinking...polycyclic aromatic hydrocarbons (PAH), including...cold (5 degrees C) water. Measurements were...

Farin Kamangar; Michele M. Schantz; Christian C. Abnet; Renato B. Fagundes; and Sanford M. Dawsey

2008-05-01T23:59:59.000Z

74

Leaching of FGD Byproducts Using a CSTX  

SciTech Connect

Leaching studies of coal utilization byproducts (CUB) are often performed to determine the compatibility of the material in a particular end-use or disposal environment. Typically, these studies are conducted using either a batch or a fixed-bed column technique. Fixed-bed columns offer the advantage of a continuous flow of effluent that provides elution profiles with changing elution volume and pH. Unfortunately, clogs can form in fixed-bed leaching columns, either because of cementitious properties of the material itself, such as is seen for fluidized bed combustion (FBC) fly ash, or because of precipitate formation, such as can occur when a high-calcium ash is subjected to sulfate-containing leachates. Also, very fine-grained materials, such as gypsum, do not provide sufficient permeability for study in a fixed-bed column. A continuous, stirred-tank extractor (CSTX) is being used as an alternative technique that can provide the elution profile of column leaching but without the low permeability problems. The CSTX has been successfully employed in the leaching of flue gas desulfurization products that would not be sufficiently permeable under traditional column leaching conditions. The results indicate that the leaching behavior depends on a number of factors, including (but not limited to) solubility and neutralization capacity of the mineral phases present, sorption properties of these phases, behavior of the solubilized material in the tank, and the type of species in solution. In addition, leaching to near-exhaustion of a wallboard produced from FGD gypsum has allowed the isolation of a highly adsorptive phase. This phase appears to be present in at least some FGD gypsums and accounts for the immobilization of trace metals such as arsenic, cobalt, lead, and mercury.

Kairies, C.L.; Schroeder, K.T.; Cardone, C.R.

2005-09-01T23:59:59.000Z

75

Computer Simulations Reveal Multiple Functions for Aromatic  

E-Print Network (OSTI)

Computer Simulations Reveal Multiple Functions for Aromatic Residues in Cellulase Enzymes NREL researchers use high-performance computing to demonstrate fundamental roles of aromatic residues in cellulase enzyme tunnels. National Renewable Energy Laboratory (NREL) computer simulations of a key indus- trial

76

Alkylation of organic aromatic compounds  

DOE Patents (OSTI)

Aromatic compounds are alkylated in a combination reactor/distillation column comprising a vessel suitable for operating between 70 C and 500 C and from 0.5 to 20 atmospheres pressure; an inert distillation packing in the lower one-third of said vessel; solid acidic catalytic material such as zeolites or an acidic cation exchange resin supported in the middle one-third of said vessel; and inert distillation packing in the upper one-third of said vessel. A benzene inlet is located near the upper end of the vessel; an olefin inlet is juxtaposed with said solid acidic catalytic material; a bottoms outlet is positioned near the bottom of said vessel for removing said cumene and ethyl benzene; and an overhead outlet is placed at the top of said vessel for removing any unreacted benzene and olefin.

Smith, L.A. Jr.; Arganbright, R.P.; Hearn, D.

1993-01-05T23:59:59.000Z

77

Advanced Gasification By-Product Utilization  

SciTech Connect

With the passing of legislation designed to permanently cap and reduce mercury emissions from coal-fired utilities, it is more important than ever to develop and improve upon methods of controlling mercury emissions. One promising technique is carbon sorbent injection into the flue gas of the coal-fired power plant. Currently, this technology is very expensive as costly commercially activated carbons are used as sorbents. There is also a significant lack of understanding of the interaction between mercury vapor and the carbon sorbent, which adds to the difficulty of predicting the amount of sorbent needed for specific plant configurations. Due to its inherent porosity and adsorption properties as well as on-site availability, carbons derived from gasifiers are potential mercury sorbent candidates. Furthermore, because of the increasing restricted use of landfilling, the coal industry is very interested in finding uses for these materials as an alternative to the current disposal practice. The results of laboratory investigations and supporting technical assessments conducted under DOE Subcontract No. DE-FG26-03NT41795 are reported. This contract was with the University of Kentucky Research Foundation, which supports work with the University of Kentucky Center for Applied Energy Research and The Pennsylvania State University Energy Institute. The worked described was part of a project entitled ''Advanced Gasification By-Product Utilization''. This work involved the development of technologies for the separation and characterization of coal gasification slags from operating gasification units, activation of these materials to increase mercury and nitrogen oxide capture efficiency, assessment of these materials as sorbents for mercury and nitrogen oxides, assessment of the potential for leaching of Hg captured by the carbons, analysis of the slags for cement applications, and characterization of these materials for use as polymer fillers. The objectives of this collaborative effort between the University of Kentucky Center for Applied Energy Research (CAER), The Pennsylvania State University Energy Institute, and industry collaborators supplying gasifier char samples were to investigate the potential use of gasifier slag carbons as a source of low cost sorbent for Hg and NOX capture from combustion flue gas, concrete applications, polymer fillers and as a source of activated carbons. Primary objectives were to determine the relationship of surface area, pore size, pore size distribution, and mineral content on Hg storage of gasifier carbons and to define the site of Hg capture. The ability of gasifier slag carbon to capture NOX and the effect of NOX on Hg adsorption were goals. Secondary goals were the determination of the potential for use of the slags for cement and filler applications. Since gasifier chars have already gone through a devolatilization process in a reducing atmosphere in the gasifier, they only required to be activated to be used as activated carbons. Therefore, the principal objective of the work at PSU was to characterize and utilize gasification slag carbons for the production of activated carbons and other carbon fillers. Tests for the Hg and NOX adsorption potential of these activated gasifier carbons were performed at the CAER. During the course of this project, gasifier slag samples chemically and physically characterized at UK were supplied to PSU who also characterized the samples for sorption characteristics and independently tested for Hg-capture. At the CAER as-received slags were tested for Hg and NOX adsorption. The most promising of these were activated chemically. The PSU group applied thermal and steam activation to a representative group of the gasifier slag samples separated by particle sizes. The activated samples were tested at UK for Hg-sorption and NOX capture and the most promising Hg adsorbers were tested for Hg capture in a simulated flue gas. Both UK and PSU tested the use of the gasifier slag samples as fillers. The CAER analyzed the slags for possible use in cement applications

Rodney Andrews; Aurora Rubel; Jack Groppo; Brock Marrs; Ari Geertsema; Frank Huggins; M. Mercedes Maroto-Valer; Brandie M. Markley; Zhe Lu; Harold Schobert

2006-08-31T23:59:59.000Z

78

Grain Sorghum By-Product Feeds for Farm Animals.  

E-Print Network (OSTI)

of feeding trials with farm animals from 1945 throug 1951 to determine the nutritional value and feed usage of the$ bv-products. These experiments were supported in part h grants-in-aid and gifts of by-product feeds from the Cor Products Refining Company... by grants-in-aid from the Corn Products Refining Company. GRAIN SORGHUM BY-PRODUCT FEEDS FOR FARM ANIMALS GRAIN SORGHUM 80.5 million bu. I\\ \\I 30.55% total \\ WHEAT 59.6 million bu. 27.16 % total CORN / 64.3 million bu. Figure 3. Ten-year average...

1951-01-01T23:59:59.000Z

79

Resource recovery - a byproduct of hazardous waste incineration  

SciTech Connect

Three principal areas of a chlorinated hydrocarbon waste disposal system for a typical vinyl chloride monomer (VCM) facility are described: the incinerator, the energy-recovery system, and the byproduct-recovery system. The overall efficiency of the energy- and *byproduct-recovery systems is dependent on the optimization of the primary combustor. An example is presented in table form which lists typical waste quantities for the plant and operating costs, including utility requirements for the incinerator system, the quench, absorber and scrubber. Savings that can result by the addition of the energy- and acid-recovery systems can pay for the waste disposal system and return money to the plant.

Santoleri, J.J.

1982-11-01T23:59:59.000Z

80

Leaching of Phase II Mercury Control Technology By-Products  

SciTech Connect

The U.S. EPA has issued a final regulation for control of mercury from coal-fired power plants. An NETL research, development and demonstration program under DOE/Fossil Energy Innovations for Existing Plants is directed toward the improvement of the performance and economics of mercury control from coal-fired plants. The current Phase II of the RD&D program emphasizes the evaluation of performance and cost of control technologies through slip-stream and full scale field testing while continuing the development of novel concepts. One of the concerns of the NETL program is the fate of the captured flue gas mercury which is transferred to the condensed phase by-product stream. These adulterated by-products, both ashes and FGD material, represent the greatest challenge to the DOE goal of increased utilization of by-products. The degree of stability of capture by-products and their potential for release of mercury can have a large economic impact on material sales or the approach to disposal. One of the considerations for mercury control technology is the potential trade-off between effective but temporary mercury capture and less effective but more permanent sequestration. As part of a greater characterization effort of Phase II facility baseline and control technology sample pairs, NETL in-house laboratories have performed aqueous leaching procedures on a select subset of the available sample pairs. This report describes batch leaching results for mercury, arsenic, and selenium.

Hesbach, P.A.; Kachur, E.K.

2007-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "byproducts aromatic extracts" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Chemical production from industrial by-product gases: Final report  

SciTech Connect

The potential for conservation of natural gas is studied and the technical and economic feasibility and the implementation of ventures to produce such chemicals using carbon monoxide and hydrogen from byproduct gases are determined. A survey was performed of potential chemical products and byproduct gas sources. Byproduct gases from the elemental phosphorus and the iron and steel industries were selected for detailed study. Gas sampling, preliminary design, market surveys, and economic analyses were performed for specific sources in the selected industries. The study showed that production of methanol or ammonia from byproduct gas at the sites studied in the elemental phosphorus and the iron and steel industries is technically feasible but not economically viable under current conditions. Several other applications are identified as having the potential for better economics. The survey performed identified a need for an improved method of recovering carbon monoxide from dilute gases. A modest experimental program was directed toward the development of a permselective membrane to fulfill that need. A practical membrane was not developed but further investigation along the same lines is recommended. (MCW)

Lyke, S.E.; Moore, R.H.

1981-04-01T23:59:59.000Z

82

Coal combustion by-products: State regulatory overview  

SciTech Connect

Coal combustion by-products (CCBs) are generated from the combustion of coal for energy production. Approximately 82 million tons of CCBs are produced each year by electric utilities. (1991 Coal Combustion By-Product Production and Use, American Coal Ash Association, 1992.) There are several common types of CCBs produced by coal combustion--fly ash, bottom ash, boiler slag, flue gas desulfurization material (FGD) and fluidized bed combustion byproducts (FBC). Some CCBs, such as fly ash, have pozzolanic properties and may have cementitious properties, both of which are advantageous for engineering, construction and waste remediation applications. The American Society for Testing Materials (ASTM) in ASTM C-618 has created two classifications of useful and quality coal ash, Class F ash and Class C ash. Each class of coal ash has different pozzolanic and cementitious characteristics. Coal ash can be utilized in many manufacturing, mining, agricultural, engineering, construction and waste remediation applications. This is a review by state of regulations concerning coal combustion by-products.

Jagiella, D. [Howard and Howard Attorneys, Peoria, IL (United States)

1996-11-01T23:59:59.000Z

83

JASPERSE CHEM 341 TEST 4 VERSION 1 Conjugation, Diels-Alder, Aromaticity, Aromatic Reactions  

E-Print Network (OSTI)

Hybridization Basicity Na Nb Nc Nd Heat of Hydrogenation O O O Reactivity Towards Br BrBr Reactivity toward SN21 JASPERSE CHEM 341 TEST 4 VERSION 1 Conjugation, Diels-Alder, Aromaticity, Aromatic Reactions 1 #12;2 5. Synthesis Reactions. Draw the feature product of the following reactions (need not show any

Jasperse, Craig P.

84

Rapid Batch Characterization of Coal Utilization By-Products  

NLE Websites -- All DOE Office Websites (Extended Search)

Batch Characterization Batch Characterization of Coal Utilization By-Products Peter A. Hesbach 1 *, Alexander S. P. Abel 2 Ann G. Kim 3 , and Steven C. Lamey 4 1 U.S. Department of Energy, National Energy Technology Laboratory, 3610 Collins Ferry Road, P.O. Box 880, Morgantown, WV 26507-0880 USA; 2 NETL Site Support Contractor, Parsons, 3610 Collins Ferry Road, Morgantown, WV 26505 USA; 3 U.S. Department of Energy, National Energy Technology Laboratory Post-Doctoral Fellow, 626 Cochrans Mill Road, P.O. Box 10940, Pittsburgh, PA 15236-0940 USA; 4 retired, U.S. Department of Energy, National Energy Technology Laboratory, Morgantown, WV USA (* author for correspondence, phone: 304-285-4443, fax: 304-285-4487, e-mail: peter.hesbach@netl.doe.gov) KEYWORDS: leaching methods, ash characterization, coal utilization by-products

85

Mineral Sequestration Utilizing Industrial By-Products, Residues, and Minerals  

NLE Websites -- All DOE Office Websites (Extended Search)

J. Fauth and Yee Soong J. Fauth and Yee Soong U.S. Department of Energy National Energy Technology Laboratory Pittsburgh PA, 15236-0940 Mineral Sequestration Workshop National Energy Technology Laboratory August 8, 2001 Mineral Sequestration Utilizing Industrial By-Products, Residues, and Minerals Mineral Sequestration Workshop, U.S. Department of Energy, NETL, August 8, 2001 Overview * Introduction - Objective - Goals - NETL Facilities * Effect of Solution Chemistry on Carbonation Efficiency - Buffered Solution + NaCl - Buffered Solution + MEA * Effect of Pretreatment on Carbonation Efficiency - Thermal Treatments - Chemical Treatments * Carbonation Reaction with Ultramafic Minerals - Serpentine - Olivine Mineral Sequestration Workshop, U.S. Department of Energy, NETL, August 8, 2001 Overview * Carbonation Reaction with Industrial By-products

86

Table 3.5 Selected Byproducts in Fuel Consumption, 2010;  

U.S. Energy Information Administration (EIA) Indexed Site

5 Selected Byproducts in Fuel Consumption, 2010; 5 Selected Byproducts in Fuel Consumption, 2010; Level: National and Regional Data; Row: NAICS Codes; Column: Energy Sources; Unit: Trillion Btu. Blast Pulping Liquor NAICS Furnace/Coke Petroleum or Wood Chips, Code(a) Subsector and Industry Total Oven Gases Waste Gas Coke Black Liquor Bark Total United States 311 Food 11 0 7 0 0 1 3112 Grain and Oilseed Milling 5 0 2 0 0 * 311221 Wet Corn Milling * 0 * 0 0 0 31131 Sugar Manufacturing * 0 * 0 0 * 3114 Fruit and Vegetable Preserving and Specialty Foods 1 0 1 0 0 0 3115 Dairy Products 1 0 1 0 0 0 3116 Animal Slaughtering and Processing 4 0 4 0 0 * 312 Beverage and Tobacco Products 3 0 2 0 0 1 3121 Beverages 3 0 2 0 0 1 3122 Tobacco 0 0 0 0 0 0 313 Textile Mills 0 0 0 0 0 0 314 Textile Product Mills

87

Utilization of by-product gypsum in construction  

E-Print Network (OSTI)

as a by-product (called phosphogypsum) during acidulation of phosphate rock in the manufacture phosphoric acid. The sulfate is produced in either a dihydrate or a hemihydrate form depending on the operating conditions. Phosphogypsum produced... by Mobil Chemi- cal Company (Pasadena, Texas) is in the dihydrate form and was previously studied. Phosphogypsum produced by Occidental Chemical Company (White Springs, Florida), on the other hand, is produced in a hemihydrate form and transforms...

Stephenson, Angela Lorraine

2012-06-07T23:59:59.000Z

88

Estimation method for the thermochemical properties of polycyclic aromatic molecules  

E-Print Network (OSTI)

Polycyclic aromatic molecules, including polycyclic aromatic hydrocarbons (PAHs) have attracted considerable attention in the past few decades. They are formed during the incomplete combustion of hydrocarbon fuels and are ...

Yu, Joanna

2005-01-01T23:59:59.000Z

89

Metabolism of Polycyclic Aromatic Hydrocarbons in Cell Cultures  

Science Journals Connector (OSTI)

...metabolism of polycyclic aromatic hydrocarbons to water-soluble and organic-soluble...metabolism of polycyclic aromatic hydrocarbons to water-soluble and organic-soluble...cytotoxicity and conversion of hydrocarbons to water-soluble products (Chart...

Eliezer Huberman; James K. Selkirk; and Charles Heidelberger

1971-12-01T23:59:59.000Z

90

aromatic hydrocarbons coated: Topics by E-print Network  

NLE Websites -- All DOE Office Websites (Extended Search)

Summary: ??Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous environmental pollutants, known human lung carcinogens, and potent mammary carcinogens in animal models....

91

E-Print Network 3.0 - aromatic hydrocarbon phenanthrene Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

Abstract Polycyclic aromatic hydrocarbons (PAHs) and dioxins are lipophilic organic pollutants occurring... absorption, pig INTRODUCTION Polycyclic aromatic hydrocarbons (PAHs)...

92

E-Print Network 3.0 - aromatic hydrocarbons based Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Aromatic Hydrocarbons Volatile Organic... Compounds Toxic Organic Halogenated Dioxins Furans (dioxins) Polycyclic Aromatic Hydrocarbons found... Rana Novini ATOC 3500 Burn...

93

E-Print Network 3.0 - acidic polycyclic aromatic Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Abstract Polycyclic aromatic hydrocarbons (PAHs) and dioxins are lipophilic organic pollutants occurring... absorption, pig INTRODUCTION Polycyclic aromatic hydrocarbons (PAHs)...

94

E-Print Network 3.0 - airborne polycyclic aromatic Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Aromatic Hydrocarbons Volatile Organic... Compounds Toxic Organic Halogenated Dioxins Furans (dioxins) Polycyclic Aromatic Hydrocarbons found... has been criticized for...

95

E-Print Network 3.0 - aromatic hydrocarbons assessment Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

Aromatic Hydrocarbons Volatile Organic... Compounds Toxic Organic Halogenated Dioxins Furans (dioxins) Polycyclic Aromatic Hydrocarbons found... of airborne soot. The air...

96

A Novel, Green Technology for the Production of Aromatic Thiol from Aromatic Sulfonyl Chloride  

E-Print Network (OSTI)

Functional Theory (DFT), a quantum mechanical method, was used to investigate the new aromatic thiol production technology at the molecular level in aspects including reaction species adsorption and transition state determination. Plant design methods...

Atkinson, Bradley R.

2010-01-16T23:59:59.000Z

97

Optimization of Jatropha Oil Extraction and Its By-Product Utilization by Pyrolysis Method  

E-Print Network (OSTI)

Bio-Energy Testing and Analysis Laboratory EERE Energy Efficiency and Renewable Energy EIA Energy Information Administration FC Fixed Carbon GC Gas Chromatography HID Helium Ionization Detector LSD Least Significant Difference NTP Normal..., resulting in 50 wt.% oil yield, 23 wt.% char, 17 wt.% gas and ash. 20 CHAPTER III METHODOLOGY All experiments of this study were performed at the Bio-Energy Testing and Analysis Laboratory (BETA Lab) of the Biological and Agricultural...

Kongkasawan, Jinjuta 1987-

2012-08-20T23:59:59.000Z

98

Removal of trace olefins from aromatic hydrocarbons  

SciTech Connect

A process is described for treating a hydrocarbon process stream by converting trace quantities of olefinic impurities to nonolefinic hydrocarbons. The process comprises contacting the process stream, which contains trace olefins in an amount of from about 50 to about 2000 as measured by Bromine Index and at least 80% by weight of aromatic and naphthenic hydrocarbons having from 6 to 20 carbon atoms per molecule, at reaction conditions which ensure liquid phase operation with a solid catalyst composite comprising a crystalline aluminosilicate zeolite and a refractory inorganic oxide. A catalytic olefin-consuming alkylation reaction then produces an essentially olefinfree product stream with approximately the same quantity and distribution of aromatic and naphthenic hydrocarbons as contained in the process stream.

Sachtler, J.W.A.; Barger, P.T.

1989-01-03T23:59:59.000Z

99

E-Print Network 3.0 - arc-induced toxic by-products Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

as by-products and thus be affected by an allocation coefficient. Indeed, in LCA when a produc- tion Source: Ecole Polytechnique, Centre de mathmatiques Collection:...

100

E-Print Network 3.0 - advanced byproduct recovery Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Dryer Wastes", EPRI CS-5782, May 1988. (5) ICF... Center for By-Products Utilization CLEAN COAL ... Source: Wisconsin-Milwaukee, University of - Department of Civil Engineering and...

Note: This page contains sample records for the topic "byproducts aromatic extracts" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

NETL: IEP - Coal Utilization By-Products : Regulatory Drivers  

NLE Websites -- All DOE Office Websites (Extended Search)

Regulatory Drivers Regulatory Drivers Since 1993, Federal Regulations have treated the four major large-volume CUB's -- fly ash, bottom ash, boiler slag, and flue gas desulfurization (FGD) byproducts -- as solid wastes that do not warrant regulation as hazardous wastes under Subtitle C of RCRA, as long as these CUBÂ’s were not co-managed with other waste materials. On May 22, 2000, EPA published a final Regulatory Determination [PDF-320KB] that retained the hazardous waste exemption for coal utilization by-products. EPA has concluded that fossil fuel combustion wastes do not warrant regulation as hazardous under Subtitle C of RCRA and is retaining the hazardous waste exemption for these wastes. However, the Agency has determined that national non-hazardous waste regulations under RCRA Subtitle D are needed for coal combustion wastes disposed in surface impoundments and landfills and used as minefilling. EPA also concluded beneficial uses of these wastes, other than for minefilling, pose no significant risk and no additional national regulations are needed. This determination affects more than 110 million tons of fossil fuel combustion wastes that are generated each year, virtually all from burning coal.

102

Evaluation of the Effects of Green Tea Extracts on Bone Homeostasis in the Ts65Dn Down Syndrome Mouse Model  

E-Print Network (OSTI)

Evaluation of the Effects of Green Tea Extracts on Bone Homeostasis in the Ts65Dn Down Syndrome- gallate (EGCG), an aromatic polyphenol found in high concentrations in green tea, is a known inhibitor

Zhou, Yaoqi

103

Device for aqueous detection of nitro-aromatic compounds  

DOE Patents (OSTI)

This invention relates to a compact and portable detection apparatus for nitro-aromatic based chemical compounds, such as nitrotoluenes, dinitrotoluenes, and trinitrotoluene (TNT). The apparatus is based upon the use of fiber optics using filtered light. The preferred process of the invention relies upon a reflective chemical sensor and optical and electronic components to monitor a decrease in fluorescence when the nitro-aromatic molecules in aqueous solution combine and react with a fluorescent polycyclic aromatic compound. 4 figures.

Reagen, W.K.; Schulz, A.L.; Ingram, J.C.; Lancaster, G.D.; Grey, A.E.

1994-04-26T23:59:59.000Z

104

Table N5.1. Selected Byproducts in Fuel Consumption, 1998  

U.S. Energy Information Administration (EIA) Indexed Site

1. Selected Byproducts in Fuel Consumption, 1998;" 1. Selected Byproducts in Fuel Consumption, 1998;" " Level: National Data and Regional Totals; " " Row: NAICS Codes; Column: Energy Sources;" " Unit: Trillion Btu." " "," "," "," "," "," "," "," ","Waste"," ",," " " "," "," ","Blast"," "," ","Pulping Liquor"," ","Oils/Tars","RSE" "NAICS"," "," ","Furnace/Coke"," ","Petroleum","or","Wood Chips,","and Waste","Row"

105

Selective Conversion of Lignin into Simple Aromatic Compounds...  

NLE Websites -- All DOE Office Websites (Extended Search)

of Lignin into Simple Aromatic Compounds Great Lakes Bioenergy Research Center Contact GLBRC About This Technology Technology Marketing Summary Lignin is a major component of...

106

NETL: IEP - Coal Utilization By-Products - Utilization Projects -  

NLE Websites -- All DOE Office Websites (Extended Search)

University of North Dakota, EERC - Table of Contents University of North Dakota, EERC - Table of Contents Coal Ash Resources Research Consortium Stabilizing Feedlots Using Coal Ash Environmental Evaluation for Utilization of Ash in Soil Stabilization Coal Ash Resources Research Consortium Background CAEEC is a cooperation among industry, government, and the research community to work together to solve CCB- related problems and promote the environmentally safe, technically sound, and economically viable utilization and disposal of CCBs. Objectives To improve the technical and economic aspects of coal combustion by-product (CCB) management. Description CARRC tasks fall into three general categories: Member-prioritized research tasks, Technical and administrative tasks, and Special projects that support CARRC objectives and strengthen and increase the availability of sound technical data for CARRC use.

107

Clean coal technology. Coal utilisation by-products  

SciTech Connect

The need to remove the bulk of ash contained in flue gas from coal-fired power plants coupled with increasingly strict environmental regulations in the USA result in increased generation of solid materials referred to as coal utilisation by-products, or CUBs. More than 40% of CUBs were sold or reused in the USA in 2004 compared to less than 25% in 1996. A goal of 50% utilization has been established for 2010. The American Coal Ash Association (ACCA) together with the US Department of Energy's Power Plant Improvement Initiative (PPPI) and Clean Coal Power Initiative (CCPI) sponsor a number of projects that promote CUB utilization. Several are mentioned in this report. Report sections are: Executive summary; Introduction; Where do CUBs come from?; Market analysis; DOE-sponsored CUB demonstrations; Examples of best-practice utilization of CUB materials; Factors limiting the use of CUBs; and Conclusions. 14 refs., 1 fig., 5 tabs., 14 photos.

NONE

2006-08-15T23:59:59.000Z

108

Wastes and by-products - alternatives for agricultural use  

SciTech Connect

Top address a growing national problem with generation of wastes and by-products, TVA has been involved for several years with developing and commercializing environmentally responsible practices for eliminating, minimizing, or utilizing various wastes/by-products. In many cases, reducing waste generation is impractical, but the wastes/by-products can be converted into other environmentally sound products. In some instances, conversion of safe, value-added agricultural products in the best or only practical alternative. TVA is currently involved with a diversity of projects converting wastes/by-products into safe, economical, and agriculturally beneficial products. Environmental improvement projects have involved poultry litter, cellulosic wastes, used battery acid, ammonium sulfate fines, lead smelting effluents, deep-welled sulfuric acid/ammonium bisulfate solutions, wood ash, waste magnesium ammonium sulfate slurry from recording tape production, and ammunition plant waste sodium nitrate/ammonium nitrate streams.

Boles, J.L.; Craft, D.J.; Parker, B.R.

1994-10-01T23:59:59.000Z

109

Structural analysis of extracts from spent hydroprocessing catalysts  

SciTech Connect

Solvent extracts from spent commercial naphtha and gas oil hydrotreating catalysts were examined in order to elucidate the structure of adsorbed poisons. Amides were identified in the extracts and made up 20-30% of the basic compounds. The oxygen content of the extracts was as high as 28% by weight. Some of this oxygen may be associated with metal complexes or present as inorganic material. Infrared spectroscopic analysis revealed very strong absorptions due to carbonyls, suggesting that compounds such as ketones and carboxylic acids were present. The extracted compounds consisted of saturated (paraffinic and naphthenic) structures and aromatic groups, with >50% boiling at +343/sup 0/c. These results suggest polymerization of species on the surface of the catalyst, rather than condensation of aromatic structures to form coke.

Choi, J.H.K.; Gray, M.R.

1988-09-01T23:59:59.000Z

110

Aromatics oxidation and soot formation in flames  

SciTech Connect

This project is concerned with the kinetics and mechanisms of aromatics oxidation and soot and fullerenes formation in flames. The scope includes detailed measurements of profiles of stable and radical species concentrations in low-pressure one-dimensional premixed flames. Intermediate species identifications and mole fractions, fluxes, and net reaction rates calculated from the measured profiles are used to test postulated reaction mechanisms. Particular objectives are to identify and to determine or confirm rate constants for the main benzene oxidation reactions in flames, and to characterize fullerenes and their formation mechanisms and kinetics.

Howard, J.B.; Pope, C.J.; Shandross, R.A.; Yadav, T. [Massachusetts Institute of Technology, Cambridge (United States)

1993-12-01T23:59:59.000Z

111

Removal of selected heavy metals from aqueous solutions using a solid by-product from the Jordanian oil shale refining  

Science Journals Connector (OSTI)

...?The potential use of treated solid by-product of oil shale to treat aqueous solutions containing several heavy ... Results indicate that the solid by-product of oil shale removes Cd(II), Cu(II),...

W. Y. Abu-El-Sha'r; S. H. Gharaibeh; M. M. Al-Kofahi

1999-12-01T23:59:59.000Z

112

Mutagenicity of Soot and Associated Polycyclic Aromatic Hydrocarbons to Salmonella typhimurium  

Science Journals Connector (OSTI)

...polycyclic aromatic hydrocarbons were quantitatively...polycyclic aromatic hydrocarbon constituent in a kerosene...polycyclic aromatic hydrocarbon fraction in terms of...formed by the incomplete combustion of organic material...and sediments (1), heat and power generation...

Debra A. Kaden; Ronald A. Hites; and William G. Thilly

1979-10-01T23:59:59.000Z

113

Formation mechanism for polycyclic aromatic hydrocarbons in methane flames  

E-Print Network (OSTI)

aromatic hydrocarbons PAHs up to 788 amu (C64H20) were detected in the combustion gases. Only the most applications including heating systems and gas turbines for electric power generation.62­64 The combustionFormation mechanism for polycyclic aromatic hydrocarbons in methane flames K. Siegmanna) Swiss

Sattler, Klaus

114

High levels of carcinogenic polycyclic aromatic hydrocarbons in mate drinks  

Science Journals Connector (OSTI)

...carcinogenic polycyclic aromatic hydrocarbons in mate drinks Farin Kamangar...exposure to polycyclic aromatic hydrocarbons (PAHs), including known...80 oC) or cold (4 oC) water and two commonly used brands...Infusions were made by adding water to the leaves, steeping for...

Farin Kamangar; Michele Schantz; Christian Abnet; Renato Fagundes; and Sanford Dawsey

2008-05-01T23:59:59.000Z

115

E-Print Network 3.0 - ambient polycyclic aromatic Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Adducts in Mothers Summary: . Exposure to genotoxins present in ambient air in Bangkok, Thailand: particle associated polycyclic aromatic... DNA Damage from Polycyclic Aromatic...

116

E-Print Network 3.0 - aromatic compounds Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

of Science, Office of Summary: Sciences. Renewable Aromatics and Olefins from Solid Biomass by Catalytic Fast Pyrolysis: Design of New... into aromatics and olefins with...

117

E-Print Network 3.0 - aromatic rings synthesis Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

of Science, Office of Summary: Sciences. Renewable Aromatics and Olefins from Solid Biomass by Catalytic Fast Pyrolysis: Design of New... into aromatics and olefins with...

118

E-Print Network 3.0 - aromatic compounds part Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

for Energy Innovation, an Energy... Sciences. Renewable Aromatics and Olefins from Solid Biomass by Catalytic Fast Pyrolysis: Design of New... into aromatics and olefins with...

119

E-Print Network 3.0 - aromatic compounds derived Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

of Science, Office of Summary: Sciences. Renewable Aromatics and Olefins from Solid Biomass by Catalytic Fast Pyrolysis: Design of New... into aromatics and olefins with...

120

E-Print Network 3.0 - aromatic molecules suggested Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

results have shown that these new... Sciences. Renewable Aromatics and Olefins from Solid Biomass by Catalytic Fast Pyrolysis: Design of New... into aromatics and olefins with...

Note: This page contains sample records for the topic "byproducts aromatic extracts" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

E-Print Network 3.0 - aromatic compounds progress Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

of Science, Office of Summary: Sciences. Renewable Aromatics and Olefins from Solid Biomass by Catalytic Fast Pyrolysis: Design of New... into aromatics and olefins with...

122

E-Print Network 3.0 - aromatic compounds effects Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

of Science, Office of Summary: Sciences. Renewable Aromatics and Olefins from Solid Biomass by Catalytic Fast Pyrolysis: Design of New... into aromatics and olefins with...

123

E-Print Network 3.0 - aromatic geranyl derivatives Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

of Science, Office of Summary: Sciences. Renewable Aromatics and Olefins from Solid Biomass by Catalytic Fast Pyrolysis: Design of New... into aromatics and olefins with...

124

E-Print Network 3.0 - aromatic substitution reaction Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

of Science, Office of Summary: Sciences. Renewable Aromatics and Olefins from Solid Biomass by Catalytic Fast Pyrolysis: Design of New... into aromatics and olefins with...

125

E-Print Network 3.0 - aromatic reactive intermediates Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

and allene as intermediates... Sciences. Renewable Aromatics and Olefins from Solid Biomass by Catalytic Fast Pyrolysis: Design of New... into aromatics and olefins with...

126

E-Print Network 3.0 - aromatic molecules application Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

results have shown that these new... Sciences. Renewable Aromatics and Olefins from Solid Biomass by Catalytic Fast Pyrolysis: Design of New... into aromatics and olefins with...

127

E-Print Network 3.0 - aromatic hydrocarbon contamination Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

Summary: called aromatic hydrocarbons. These include harmful pollutants like dioxins, PCBs and a group called... polycyclic aromatic hydrocarbons (PAHs). PAHs are...

128

E-Print Network 3.0 - aromatic hydrocarbon-exposed lung Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

in non-smoking and smoking lung cancer... of the fetus. These mutageniccarcinogenic pollutants include aromatic compounds such as polycyclic aromatic... of transplacental exposure...

129

Disinfection byproducts in swimming pool: Occurrences, implications and future needs  

Science Journals Connector (OSTI)

Abstract Disinfection of swimming pool water is essential to deactivate pathogenic microorganisms. Many swimming pools apply chlorine or bromine based disinfectants to prevent microbial growth. The chlorinated swimming pool water contains higher chlorine residual and is maintained at a higher temperature than a typical drinking water distribution system. It constitutes environments with high levels of disinfection by-products (DBPs) in water and air as a consequence of continuous disinfection and constant organic loading from the bathers. Exposure to those \\{DBPs\\} is inevitable for any bather or trainer, while such exposures can have elevated risks to human health. To date, over 70 peer-reviewed publications have reported various aspects of swimming pool, including types and quantities of DBPs, organic loads from bathers, factors affecting \\{DBPs\\} formation in swimming pool, human exposure and their potential risks. This paper aims to review the state of research on swimming pool including with the focus of \\{DBPs\\} in swimming pools, understand their types and variability, possible health effects and analyze the factors responsible for the formation of various \\{DBPs\\} in a swimming pool. The study identifies the current challenges and future research needs to minimize \\{DBPs\\} formation in a swimming pool and their consequent negative effects to bathers and trainers.

Shakhawat Chowdhury; Khalid Alhooshani; Tanju Karanfil

2014-01-01T23:59:59.000Z

130

NETL: IEP - Coal Utilization By-Products Current Regulations Governing Coal  

NLE Websites -- All DOE Office Websites (Extended Search)

Products Products Current Regulations Governing Coal Combustion By-Products - Database of State Regulations Database of State Regulations Affecting Disposal and Utilization of Coal Combustion By-Products A Summary Provided by the National Energy Technology Laboratory and the American Coal Ash Association Coal Combustion By-Products (CCBs) are generated when coal is used to generate electricity and power industrial processes. Tens of millions of tons of these materials are produced each year. Many uses of these byproducts are possible, but currently most of them wind up in landfills. Previous work at the National Energy Technology Laboratory (NETL) identified regulatory issues as one factor preventing more widespread reuse of CCBs. CCBs are generally regulated by state authorities, and the various states have developed widely differing rules. This web site was developed as one way to help CCB generators, users, and regulators share information across state boundaries.

131

Case Study of Optimal Byproduct Gas Distribution in Integrated Steel Mill Using Multi-Period Optimization  

E-Print Network (OSTI)

? ? ? Case Study of Optimal Byproduct Gas Distribution in Integrated Steel Mill Using Multi-Period Optimization KIMMO M?KINEN BUSINESS MANAGER TONI KYM?L?INEN PRODUCT MANAGER JAAKKO JUNTTILA SALES MANAGER ABB OY HELSINKI FINLAND...

Makinen, K.; Kymalainen, T.; Junttila, J.

2012-01-01T23:59:59.000Z

132

PRODUCTION OF LOW-ENERGY, 100% BY-PRODUCT CEMENT UTILIZING COAL COMBUSTION PRODUCTS.  

E-Print Network (OSTI)

??The ever-increasing quantity of by-products generated from burning coal in the production of electricity has brought about the need for new areas of utilization. This… (more)

Rust, David E.

2008-01-01T23:59:59.000Z

133

Structure of aluminum hydroxide powders obtained as a byproduct of hydrogen fuel production  

Science Journals Connector (OSTI)

The structure of aluminum hydroxide powders obtained as byproducts of hydrogen fuel production was investigated. One of the main initial components comprised aluminum-magnesium chips with 0.6, 6 and 12 wt.% ma...

A. D. Shlyapin; A. Yu. Omarov; V. P. Tarasovskii; Yu. G. Trifonov

2013-09-01T23:59:59.000Z

134

Optimization of compost fermentation of glycerol by-product discharged from biodiesel fuel production process  

Science Journals Connector (OSTI)

Development of a cheap system for reuse of glycerol by-product discharged from the biodiesel fuel (BDF) production process is needed in parallel with development of ... in the compost. Finally, a material cost evaluation

Yuta Sadano; Ryota Toshimitsu; Jiro Kohda…

2010-11-01T23:59:59.000Z

135

Strontium Isotope Study of Coal Untilization By-products Interacting with Environmental Waters  

SciTech Connect

Sequential leaching experiments on coal utilization by-products (CUB) were coupled with chemical and strontium (Sr) isotopic analyses to better understand the influence of coal type and combustion processes on CUB properties and the release of elements during interaction with environmental waters during disposal. Class C fly ash tended to release the highest quantity of minor and trace elements—including alkaline earth elements, sodium, chromium, copper, manganese, lead, titanium, and zinc—during sequential extraction, with bottom ash yielding the lowest. Strontium isotope ratios ({sup 87}Sr/{sup 86}Sr) in bulk-CUB samples (total dissolution of CUB) are generally higher in class F ash than in class C ash. Bulk-CUB ratios appear to be controlled by the geologic source of the mineral matter in the feed coal, and by Sr added during desulfurization treatments. Leachates of the CUB generally have Sr isotope ratios that are different than the bulk value, demonstrating that Sr was not isotopically homogenized during combustion. Variations in the Sr isotopic composition of CUB leachates were correlated with mobility of several major and trace elements; the data suggest that arsenic and lead are held in phases that contain the more radiogenic (high-{sup 87}Sr/{sup 86}Sr) component. A changing Sr isotope ratio of CUB-interacting waters in a disposal environment could forecast the release of certain strongly bound elements of environmental concern. This study lays the groundwork for the application of Sr isotopes as an environmental tracer for CUB–water interaction.

Spivak-Birndorf, Lev J; Stewart, Brian W; Capo, Rosemary C; Chapman, Elizabeth C; Schroeder, Karl T; Brubaker, Tonya M

2011-09-01T23:59:59.000Z

136

Optimum energy and by-product recovery in chlorinated hydrocarbon disposal systems  

SciTech Connect

This paper covers the three principal areas of a chlorinated hydrocarbon waste disposal system for a typical vinyl chloride monomer facility. These are the incineration, the energy recovery system, and the by-product recovery system. It is shown that the overall efficiency of the energy and by-product recovery systems is dependent on the optimization of the primary combustor (incineration system). 11 refs.

Santoleri, J.J.

1982-01-01T23:59:59.000Z

137

DNA Extraction  

NLE Websites -- All DOE Office Websites (Extended Search)

DNA Extraction DNA Extraction Being able to extract deoxyribonucleic acid (DNA) is important for a number of reasons. By studying DNA, scientists can identify genetic disorders or diseases, and they can also possibly find cures for them by manipulating or experimenting with this DNA. At the Laboratory, researchers have studied DNA to detect biothreat agents in environmental and forensic samples. Scientists also are studying how human DNA may be destroyed by certain types of electromagnetic waves at certain frequencies. Classroom Activity: This activity is about the extraction of DNA from strawberries. Strawberries are a great fruit to use for this lesson because each student can work on his or her own. Strawberries are recommended because they yield more DNA than any other fruit. Strawberries are octoploid, which means that they have eight copies of each

138

E-Print Network 3.0 - aromatic hydrocarbon emission Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

emission Search Powered by Explorit Topic List Advanced Search Sample search results for: aromatic hydrocarbon emission...

139

Aromatic Interactions in Proteins, DNA and Synthetic Receptors  

Science Journals Connector (OSTI)

...research-article Aromatic Interactions in Proteins, DNA and Synthetic Receptors C. A. Hunter Non-covalent interactions between...and three-dimensional structure in double-helical DNA. The - interaction model has been used to calculate the...

1993-01-01T23:59:59.000Z

140

Modeling the biodegradability and physicochemical properties of polycyclic aromatic hydrocarbons  

E-Print Network (OSTI)

and methylated PAHs containing up to four aromatic rings were biodegraded individually by Sphingomonas paucimobilis strain EPA505, and Monod-type kinetic coefficients were estimated for each PAH using the integral method. Estimated extant kinetic parameters...

Dimitriou-Christidis, Petros

2006-10-30T23:59:59.000Z

Note: This page contains sample records for the topic "byproducts aromatic extracts" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Biodegradability of select polycyclic aromatic hydrocarbon (pah) mixtures  

E-Print Network (OSTI)

Polycyclic aromatic hydrocarbons (PAHs) are environmentally significant because of their ubiquity and the toxicity of some. Their recalcitrance and persistence makes them problematic environmental contaminants. Microbial degradation is considered...

Desai, Anuradha M.

2007-04-25T23:59:59.000Z

142

THE HEATS OF COMBUSTION OF AROMATIC HYDROCARBONS AND HEXAMETHYLENE.  

Science Journals Connector (OSTI)

THE HEATS OF COMBUSTION OF AROMATIC HYDROCARBONS AND HEXAMETHYLENE. ... Citation data is made available by participants in CrossRef's Cited-by Linking service. ... Experimental methods included adiabatic heat-capacity calorimetry (5 K to 420 K), comparative ... ...

Theodore W. Richards; Frederick Barry

1915-01-01T23:59:59.000Z

143

Determination of polynuclear aromatic hydrocarbons in seafood by liquid chromatography with fluorescence detection  

SciTech Connect

Modification of a previously published method for determination of polynuclear aromatic hydrocarbons (PAHs) produces very clean seafood extracts in less than half the time. After alkaline digestion of the seafood, PAHs were partitioned into 1,2,3-trichlorotrifluoroethane. The resulting extract was cleaned up by solid-phase extraction on alumina, silica, and C{sub 18} adsorbents and then analyzed by gradient reversed-phase liquid chromatography with programmable fluorescence detection. Average recoveries of 12 PAHs [acenaphthene, anthracene, fluoranthene, pyrene, benz(a)anthracene, chrysene, benzo(b)fluoranthene, benzo(k)-fluoranthene, benzo(k)-fluoranthene, benzo(a)pyrene, dibenz(a,h)anthracene, benzo(ghi)perylene, and indeno(1,2,3-cd)pyrene] from 5 different matrixes (mussels, oysters, clams, crabmeat, and salmon)spiked at low parts-per-billion levels ranged from 76 to 94%. Estimated limits of quantitation ranged from 0.01 to 0.6 ppb PAHs in extracts that were free of matrix interferences. Results of analyses of a mussels standard reference material obtained from the National Institute of Standards and Technology were in good agreement with the certified values. 16 refs., 3 figs., 4 tabs.

Perfetti, G.A.; Nyman, P.J.; Fisher, S.; Joe, F.L. Jr.; Diachenko, G.W. [Food and Drug Administration, Washington, DC (United States)

1992-09-01T23:59:59.000Z

144

Emission of polycyclic aromatic hydrocarbons in China  

SciTech Connect

Emission of 16 polycyclic aromatic hydrocarbons (PAHs) listed as U.S. Environmental Protection Agency (U.S. EPA) priority pollutants from major sources in China were compiled. Geographical distribution and temporal change of the PAH emission, as well as emission profiles, are discussed. It was estimated that the total PAH emission in China was 25,300 tons in 2003. The emission profile featured a relatively higher portion of high molecular weight (HMW) species with carcinogenic potential due to large contributions of domestic coal and coking industry. Among various sources, biomass burning, domestic coal combustion, and the coking industry contributed 60%, 20%, and 16% of the total emission, respectively. Total emission, emission density, emission intensity, and emission per capita showed geographical variations. In general, the southeastern provinces were characterized by higher emission density, while those in western and northern China featured higher emission intensity and population-normalized emission. Although energy consumption in China went up continuously during the past two decades, annual emission of PAHs fluctuated depending on the amount of domestic coal consumption, coke production, and the efficiency of energy utilization. 47 refs., 6 figs.

Shanshan Xu; Wenxin Liu; Shu Tao [Peking University, Beijing (China). Laboratory for Earth Surface Processes, College of Environmental Sciences

2006-02-01T23:59:59.000Z

145

Environmentally Safe, Large Volume Utilization Applications for Gasification Byproducts  

SciTech Connect

Samples of gasification by-products produced at Polk Station and Eastman Chemical were obtained and characterized. Bulk samples were prepared for utilization studies by screening at the appropriate size fractions where char and vitreous frit distinctly partitioned. Vitreous frit was concentrated in the +20 mesh fraction while char predominated in the -20+100 mesh fraction. The vitreous frit component derived from each gasifier slag source was evaluated for use as a pozzolan and as aggregate. Pozzolan testing required grinding the frit to very fine sizes which required a minimum of 60 kwhr/ton. Grinding studies showed that the energy requirement for grinding the Polk slag were slightly higher than for the Eastman slag. Fine-ground slag from both gasifiers showed pozzoalnic activity in mortar cube testing and met the ASTM C618 strength requirements after only 3 days. Pozzolanic activity was further examined using British Standard 196-5, and results suggest that the Polk slag was more reactive than the Eastman slag. Neither aggregate showed significant potential for undergoing alkali-silica reactions when used as concrete aggregate with ASTM test method 1260. Testing was conducted to evaluate the use of the frit product as a component of cement kiln feed. The clinker produced was comprised primarily of the desirable components Ca{sub 3}SiO{sub 5} and Ca{sub 2}SiO{sub 4} after raw ingredient proportions were adjusted to reduce the amount of free lime present in the clinker. A mobile processing plant was designed to produce 100 tons of carbon from the Eastman slag to conduct evaluations for use as recycle fuel. The processing plant was mounted on a trailer and hauled to the site for use. Two product stockpiles were generated; the frit stockpile contained 5% LOI while the carbon stockpile contained 62% LOI. The products were used to conduct recycle fuel tests. A processing plant was designed to separate the slag produced at Eastman into 3 usable products. The coarse frit has been shown to be suitable for use as clinker feed for producing Portland cement. The intermediate-size product is enriched in carbon (58-62% C) and may be used as recycle fuel either in the gasifier or in a PC boiler. The fines product contains 30-40% C and may also be used as a recycle gasifier fuel, as is presently done at TECO's Polk Station, however, due to gasifier operating requirements for the production of syngas, this is not feasible at Eastman.

J.G. Groppo; R. Rathbone

2008-06-30T23:59:59.000Z

146

Design manual for management of solid by-products from advanced coal technologies  

SciTech Connect

Developing coal conversion technologies face major obstacles in byproduct management. This project has developed several management strategies based on field trials of small-scale landfills in an earlier phase of the project, as well as on published/unpublished sources detailing regulatory issues, current industry practice, and reuse opportunities. Field testing, which forms the basis for several of the disposal alternatives presented in this design manual, was limited to byproducts from Ca-based dry SO{sub 2} control technologies, circulating fluidized bed combustion ash, and bubbling bed fluidized bed combustion ash. Data on byproducts from other advanced coal technologies and on reuse opportunities are drawn from other sources (citations following Chapter 3). Field results from the 5 test cases examined under this project, together with results from other ongoing research, provide a basis for predictive modeling of long-term performance of some advanced coal byproducts on exposure to ambient environment. This manual is intended to provide a reference database and development plan for designing, permitting, and operating facilities where advanced coal technology byproducts are managed.

NONE

1994-10-01T23:59:59.000Z

147

Technical support for the Ohio Coal Technology Program. Volume 1, Baseline of knowledge concerning by-product characteristics: Final report  

SciTech Connect

This report was prepared for the Ohio Coal Development Office (OCDO) under Grant Agreement No. CDO/R-88-LRl and comprises two volumes. Volume I presents data on the chemical, physical, and leaching characteristics of by-products from a wide variety of clean coal combustion processes. Volume II consists of a discussion of (a) process modification waste minimization opportunities and stabilization considerations; (b) research and development needs and issues relating to clean coal combustion technologies and by-products; (c) the market potential for reusing or recycling by-product materials; and (d) regulatory considerations relating to by-product disposal or reuse.

Olfenbuttel, R.; Clark, S.; Helper, E.; Hinchee, R.; Kuntz, C.; Means, J.; Oxley, J.; Paisley, M.; Rogers, C.; Sheppard, W.; Smolak, L. [Battelle, Columbus, OH (United States)

1989-08-28T23:59:59.000Z

148

Predicting the yield of coking byproducts on the basis of elementary and petrographic analysis of the coal batch  

Science Journals Connector (OSTI)

Mathematical models are developed for predicting the yield of coking byproducts on the basis of elementary and petrographic analysis of the coal batch.

M. B. Golovko; I. D. Drozdnik; D. V. Miroshnichenko; Yu. S. Kaftan

2012-06-01T23:59:59.000Z

149

Removal and degradation of aromatic compounds from a highly polluted site by coupling soil washing with photocatalysis  

Science Journals Connector (OSTI)

The possible application of two environmental remediation technologies – soil washing and photocatalysis – to remove and decompose various aromatic pollutants present in excavated soils of a contaminated industrial site has been investigated. Aqueous solutions containing the non-ionic surfactant Brij 35 were used to extract the contaminants from the soil samples. The photocatalytic treatment of the obtained washing wastes, performed in the presence of TiO2 suspensions irradiated with simulated sunlight, showed a slow abatement of the toxic compounds due to the relevant concentrations of organics in the waste. A neat improvement of the process performances, obtained by operating in the presence of added potassium peroxydisulfate, suggests a feasible treatment route.

D. Fabbri; A. Bianco Prevot; V. Zelano; M. Ginepro; E. Pramauro

2008-01-01T23:59:59.000Z

150

IGCC and PFBC By-Products: Generation, Characteristics, and Management Practices  

SciTech Connect

The following report is a compilation of data on by-products/wastes from clean coal technologies, specifically integrated gasification combined cycle (IGCC) and pressurized fluidized-bed combustion (PFBC). DOE had two objectives in providing this information to EPA: (1) to familiarize EPA with the DOE CCT program, CCT by-products, and the associated efforts by DOE contractors in the area of CCT by-product management and (2) to provide information that will facilitate EPA's effort by complementing similar reports from industry groups, including CIBO (Council of Industrial Boiler Owners) and EEI USWAG (Edison Electric Institute Utility Solid Waste Activities Group). The EERC cooperated and coordinated with DOE CCT contractors and industry groups to provide the most accurate and complete data on IGCC and PFBC by-products, although these technologies are only now being demonstrated on the commercial scale through the DOE CCT program.

Pflughoeft-Hassett, D.F.

1997-09-01T23:59:59.000Z

151

Determination of Polycyclic Aromatic Hydrocarbons in Fresh Milk by Hollow Fiber Liquid-Phase Microextraction–Gas Chromatography Mass Spectrometry  

Science Journals Connector (OSTI)

......Polycyclic Aromatic Hydrocarbons in Fresh Milk by...polycyclic aromatic hydrocarbons (PAHs) in fresh...more volatile and heat sensitive. The...Polycyclic aromatic hydrocarbons (PAHs) are compounds...the incomplete combustion of carbon-containing...respectively. Data were collected......

Mohd Marsin Sanagi; Saw Hong Loh; Wan Aini Wan Ibrahim; Mohamed Noor Hasan; Hassan Y. Aboul Enein

2013-02-01T23:59:59.000Z

152

Hepatic coenzyme Q redox balance of fishes as a potential bioindicator of environmental contamination by polycyclic aromatic hydrocarbons  

Science Journals Connector (OSTI)

...at the land-water interface are...polycyclic aromatic hydrocarbon (PAH) contamination...Markers 0 Polycyclic Hydrocarbons, Aromatic 0 Water Pollutants, Chemical...metabolism Polycyclic Hydrocarbons, Aromatic toxicity...Ubiquinone metabolism Water Pollutants, Chemical...

2011-01-01T23:59:59.000Z

153

Mechanisms for formation of organic and inorganic by-products and their control in nonthermal plasma chemical processing of VOCs  

Science Journals Connector (OSTI)

This paper presents the major by-products derived from Nonthermal Plasma (NTP) chemical processing of different types of Volatile Organic Compounds (VOCs), mechanisms for their formation, effects of reactor types and additives such as water and gaseous oxygen on by-product distribution, and safe operations of NTP reactors for the removal of VOCs.

Shigeru Futamura; Masami Sugasawa

2008-01-01T23:59:59.000Z

154

The Emissions of Major Aromatic Voc as Landfill Gas from Urban Landfill Sites in Korea  

Science Journals Connector (OSTI)

In this study, concentrations of major aromatic VOCs were determined from landfill gas (LFG) at a total of five...?1 (WJ in wintertime). The LFG flux values of aromatic VOC, when compared to the contribution of n...

Ki-Hyun Kim; Sung Ok Baek; Ye-Jin Choi…

2006-07-01T23:59:59.000Z

155

Advanced Byproduct Recovery: Direct Catalytic Reduction of Sulfur Dioxide to Elemental Sulfur.  

SciTech Connect

More than 170 wet scrubber systems applied, to 72,000 MW of U.S., coal-fired, utility boilers are in operation or under construction. In these systems, the sulfur dioxide removed from the boiler flue gas is permanently bound to a sorbent material, such as lime or limestone. The sulfated sorbent must be disposed of as a waste product or, in some cases, sold as a byproduct (e.g. gypsum). Due to the abundance and low cost of naturally occurring gypsum, and the costs associated with producing an industrial quality product, less than 7% of these scrubbers are configured to produce usable gypsum (and only 1% of all units actually sell the byproduct). The disposal of solid waste from each of these scrubbers requires a landfill area of approximately 200 to 400 acres. In the U.S., a total of 19 million tons of disposable FGD byproduct are produced, transported and disposed of in landfills annually. The use of regenerable sorbent technologies has the potential to reduce or eliminate solid waste production, transportation and disposal. In a regenerable sorbent system, the sulfur dioxide in the boiler flue gas is removed by the sorbent in an adsorber. The S0{sub 2}s subsequently released, in higher concentration, in a regenerator. All regenerable systems produce an off-gas stream from the regenerator that must be processed further in order to obtain a salable byproduct, such as elemental sulfur, sulfuric acid or liquid S0{sub 2}.

NONE

1997-06-01T23:59:59.000Z

156

E-Print Network 3.0 - aromatic hydrocarbons biodegradation Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

to simulate the degradation of aromatic ... Source: Lovley, Derek - Department of Microbiology, University of Massachusetts at Amherst Collection: Environmental Management...

157

E-Print Network 3.0 - aromatic hydrocarbon biodegradation Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

to simulate the degradation of aromatic ... Source: Lovley, Derek - Department of Microbiology, University of Massachusetts at Amherst Collection: Environmental Management...

158

E-Print Network 3.0 - aromatic hydrocarbons fluorene Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrocarbons... Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous organic pollutants in urban environments... in the urbanized and rapidly urbanizing areas. Keywords...

159

E-Print Network 3.0 - aromatic hydrocarbons Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrocarbons... Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous organic pollutants in urban environments... in the urbanized and rapidly urbanizing areas. Keywords...

160

E-Print Network 3.0 - aromatic hydrocarbons pah5 Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

hydrocarbons (PAHs) are ubiquitous, recalcitrant, and potentially carcinogenic pollutants. Plants Summary: 1461 Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous,...

Note: This page contains sample records for the topic "byproducts aromatic extracts" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

E-Print Network 3.0 - aromatic hydrocarbons inenvironmental Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrocarbons... Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous organic pollutants in urban environments... in the urbanized and rapidly urbanizing areas. Keywords...

162

E-Print Network 3.0 - aromatic hydrocarbon o-quinones Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrocarbons... Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous organic pollutants in urban environments... in the urbanized and rapidly urbanizing areas. Keywords...

163

E-Print Network 3.0 - astronomical polycyclic aromatic Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrocarbons... Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous organic pollutants in urban environments... in the urbanized and rapidly urbanizing areas. Keywords...

164

Mineral and Fuel Extraction: Health Consequences  

Science Journals Connector (OSTI)

Activities associated with mining and fuel extraction may present a range of potential health risks for nearby communities. The environmental legacy of mining and fuel extraction is extensive, with millions of active and abandoned mines globally. Evaluation of community risks from mineral and fuel extraction is often a complex task, given the variety of products produced, multiple potential exposure contexts, routes of contact, and health impacts. Adverse health outcomes that may arise from mineral-related processes include release of toxicants such as metals, metalloids, and mineral dusts, and indirect effects such as the increased potential of vectorborne disease. The ongoing processing and end-use of minerals also produce gas emissions (such as carbon dioxide and sulfur dioxide), often on a large scale. Polycyclic aromatic hydrocarbons (PAHs) are substances of particular concern arising from conventional crude oil and coal extraction, oil sands/shales wastes, and tailings water, and are classified as either proven or suspected carcinogens. The geotechnical and structural aspects of mine sites must also be considered, including the risk of major hazardous events such as release of tailings dam contents. Indirect or delayed effects of mineral and fuel extraction include those that act to affect community health through contamination or disruption of water supplies and food sources (e.g., crops). As with many industries, the balance between risks and benefits of mining must be carefully calibrated.

A. Cook; R.B. Finkelman; A. Fourie

2011-01-01T23:59:59.000Z

165

Phase behavior of CO{sub 2}/crude oil mixtures in supercritical fluid extraction system: Experimental data and modeling  

SciTech Connect

Continuous multiple-contact extractions of a crude oil were carried out with supercritical CO{sub 2} in order to assess the effect of the density and critical point of a solvent on the extraction performance as a function of process variables. Most of the extraction performance was solvent density dependent. In the vicinity of the critical point of CO{sub 2}, however, the solvent density was not the only parameter that governed extraction yields. The results of simulated distillation and gas chromatography-mass spectrometry analyses of extracts represented that the earlier extracts contained lighter compounds and the latter extracts contained progressively heavier compounds. As the extraction proceeded, relatively greater amounts of paraffinic compounds and lesser amounts of naphthenic and aromatic compounds were extracted. This compositional change occurring during a dynamic extraction was also ascertained by phase equilibrium calculations using the Soave-Redlich-Kwong equation of state and a component-lumping procedure.

Hwang, J. [Kyung In Energy Co., Inchon (Korea, Republic of). R and D Center; Park, S.J. [Dongguk Univ., Seoul (Korea, Republic of). Dept. of Chemical Engineering; Deo, M.D.; Hanson, F.V. [Univ. of Utah, Salt Lake City, UT (United States). Dept. of Chemical and Fuels Engineering

1995-04-01T23:59:59.000Z

166

Chiral Aromaticities. A Topological Exploration of Möbius Homoaromaticity  

Science Journals Connector (OSTI)

A series of C2-symmetric homoderivatives of the cyclo C9H9+ cation first identified by Schleyer as Möbius aromatic are shown to themselves sustain Möbius 4n-?-electron homoaromaticity. Analogous double-twist Möbius bis-homoaromatics follow a 4n+2 electron ...

Charlotte S. M. Allan; Henry S. Rzepa

2008-10-15T23:59:59.000Z

167

High Levels of Carcinogenic Polycyclic Aromatic Hydrocarbons in Mate Drinks  

Science Journals Connector (OSTI)

...leaves and/or exposure to combustion products or formation of ash...analysis of the mainstream smoke chemistry of samples of the U.S. cigarette...comparison of the tumors induced by coal tar and benzo[a]pyrene...Spectrometry Ilex paraguariensis chemistry Polycyclic Hydrocarbons, Aromatic...

Farin Kamangar; Michele M. Schantz; Christian C. Abnet; Renato B. Fagundes; and Sanford M. Dawsey

2008-05-01T23:59:59.000Z

168

Epoxy Coenzyme A Thioester Pathways for Degradation of Aromatic Compounds  

Science Journals Connector (OSTI)

...Fe-O-Fe center in stearoyl-ACP desaturase. Primary sequence identity with other diiron-oxo proteins. Biochemistry 33 :12776-12786. 29. Fuchs, G , M Boll and J Heider. 2011. Microbial degradation of aromatic compounds-from one strategy to four...

Wael Ismail; Johannes Gescher

2012-05-11T23:59:59.000Z

169

FROM INTERSTELLAR POLYCYCLIC AROMATIC HYDROCARBONS AND ICE TO ASTROBIOLOGY  

E-Print Network (OSTI)

photolysis of these ices produces a host of new compounds, some of which show intriguing prebiotic behavior1 FROM INTERSTELLAR POLYCYCLIC AROMATIC HYDROCARBONS AND ICE TO ASTROBIOLOGY LOUIS J. ALLAMANDOLA, the concept of ices in dense molecular clouds ignored, and the notion of large, abundant, gas phase, carbon

170

1 Solvent-Extractable Polycyclic Aromatic Hydrocarbons in Biochar: 2 Influence of Pyrolysis Temperature and Feedstock  

E-Print Network (OSTI)

combustion (or 30 pyrolysis) of plant biomass are important natural constituents 31 of soils and sediments.1 45 different starting materials. 46 Pyrolysis of biomass is known to produce a wide variety of 47 low and high molecular weight (LMW and HMW, respectively) 48 PAHs depending on the biomass type, pyrolysis

171

Bacterial mutagenicity of polycyclic aromatic hydrocarbons in reconstituted mixtures and crude coal tar extracts and fractions  

E-Print Network (OSTI)

factors which assume additive interactions between individual PAHS. The mutagenic interactions of PAH mixtures were investigated using the Salmonellalmicrosome assay. Two groups of samples included PAH mixtures modeling a coal tar and an environmental...

Onufrock, Amy Mildred

2012-06-07T23:59:59.000Z

172

Polycyclic Aromatic Hydrocarbons in C8 Isomer Aromatic Feed: Analysis by GC, GC/MS, and GC/FTIR Techniques  

Science Journals Connector (OSTI)

......in fossil fuels, combustion products, and automotive...understanding the chemistry of the formation...The analytical chemistry of P A H compounds...PAHs present in coal-derived hydrocarbons...Hazardous chemicals from coal conversion process...Bartle. Analytical Chemistry of Polycyclic Aromatic......

V.N. Garg; B.D. Bhatt; V.K. Kaushik; K.R. Murthy

1987-06-01T23:59:59.000Z

173

Polycyclic Aromatic Hydrocarbons in C8 Isomer Aromatic Feed: Analysis by GC, GC/MS, and GC/FTIR Techniques  

Science Journals Connector (OSTI)

......anthracene. Because aromatic car- * Author to whom correspondence...a growing interest in alternative sources of energy and environ mental quality...conditions: ionization energy of the mass spectra...by GC/MS as recently car ried out by Tong and......

V.N. Garg; B.D. Bhatt; V.K. Kaushik; K.R. Murthy

1987-06-01T23:59:59.000Z

174

Polycyclic Aromatic Hydrocarbons in C8 Isomer Aromatic Feed: Analysis by GC, GC/MS, and GC/FTIR Techniques  

Science Journals Connector (OSTI)

......the concentrated hydrocarbon residue of C 8...Polycyclic aromatic hydrocarbons (PAHs) are recognized...fossil fuels, combustion products, and...monocyclic aro matic hydrocarbons like benzene or...feed-effluent heat exchangers (16...and a Shimadzu data pro cessor (C-R......

V.N. Garg; B.D. Bhatt; V.K. Kaushik; K.R. Murthy

1987-06-01T23:59:59.000Z

175

WATER AND BY-PRODUCT ISSUES IN THE ELECTRIC-UTILITY INDUSTRY  

NLE Websites -- All DOE Office Websites (Extended Search)

and Power Conference in conjunction with 2 and Power Conference in conjunction with 2 nd Joint U.S.-People's Republic of China Conference on Clean Energy, November 17-19, 2003, Washington, DC A DOE R&D RESPONSE TO EMERGING COAL BY-PRODUCT AND WATER ISSUES IN THE ELECTRIC-UTILITY INDUSTRY Thomas J. Feeley, III Technology Manager U.S. Department of Energy - Office of Fossil Energy National Energy Technology Laboratory Pittsburgh, PA ABSTRACT While the regulation and control of air emissions will continue to be of primary concern to the electric-utility industry over the next several decades, other environmental-related issues may also impact the operation of existing and new coal-based power systems. Coal by-products are one such issue. Coal-fired power plants generate nearly 118 million tons of fly ash, flue gas

176

Management of dry flue gas dsulfurization by-products in underground mines - an update  

SciTech Connect

In 1993, the U.S. produced about 100 million tons of coal combustion by-products (CCBs) primarily from conventional coal-fired boilers. The requirement to reduce SO{sub x} and NO{sub x} emissions to comply with the 1990 Clean Air Act Amendments (CAAA) force utilities to adopt advanced combustion and flue gas desulfurization (FGD) technologies, such as wet scrubbers, fluidized bed combustion (FBC), dry sorbent duct or furnace injection. These technologies will double to triple the amount of FGD by-products while only slightly increasing the amounts of conventional combustion residues, such as fly ash, bottom ash and boiler slag. This paper describes a program concerned with the underground disposal of combustion products in abandoned underground coal mines.

Chugh, Y.P.; Thomasson, E.M. [Southern Illinois Univ., Carbondale, IL (United States)

1996-09-01T23:59:59.000Z

177

Solar Grade Silicon from Agricultural By-products  

SciTech Connect

In this project, Mayaterials developed a low cost, low energy and low temperature method of purifying rice hull ash to high purity (5-6Ns) and converting it by carbothermal reduction to solar grade quality silicon (Sipv) using a self-designed and built electric arc furnace (EAF). Outside evaluation of our process by an independent engineering firm confirms that our technology greatly lowers estimated operating expenses (OPEX) to $5/kg and capital expenses (CAPEX) to $24/kg for Sipv production, which is well below best-in-class plants using a Siemens process approach (OPEX of 14/kg and CAPEX of $87/kg, respectively). The primary limiting factor in the widespread use of photovoltaic (PV) cells is the high cost of manufacturing, compared to more traditional sources to reach 6 g Sipv/watt (with averages closer to 8+g/watt). In 2008, the spot price of Sipv rose to $450/kg. While prices have since dropped to a more reasonable $25/kg; this low price level is not sustainable, meaning the longer-term price will likely return to $35/kg. The 6-8 g Si/watt implies that the Sipv used in a module will cost $0.21-0.28/watt for the best producers (45% of the cost of a traditional solar panel), a major improvement from the cost/wafer driven by the $50/kg Si costs of early 2011, but still a major hindrance in fulfilling DOE goal of lowering the cost of solar energy below $1/watt. The solar cell industry has grown by 40% yearly for the past eight years, increasing the demand for Sipv. As such, future solar silicon price spikes are expected in the next few years. Although industry has invested billions of dollars to meet this ever-increasing demand, the technology to produce Sipv remains largely unchanged requiring the energy intensive, and chlorine dependent Siemens process or variations thereof. While huge improvements have been made, current state-of-the-art industrial plant still use 65 kWh/kg of silicon purified. Our technology offers a key distinction to other technologies as it starts one step upstream from all other Sipv production efforts. Our process starts by producing high purity SiO2/C feedstocks from which Sipv can be produced in a single, chlorine free, final EAF step. Specifically, our unique technology, and the resultant SiO2/C product can serve as high purity feedstocks to existing metallurgical silicon (Simet) producers, allowing them to generate Sipv with existing US manufacturing infrastructure, reducing the overall capital and commissioning schedule. Our low energy, low CAPEX and OPEX process purifies the silica and carbon present in rice hull ash (RHA) at low temperatures (< 200C) to produce high purity (5-6 Ns) feedstock for production of Sipv using furnaces similar to those used to produce Simet. During the course of this project we partnered with Wadham Energy LP (Wadham), who burns 220k ton of rice hulls (RH)/yr generating 200 GWh of electricity/yr and >30k ton/yr RHA. The power generation step produces much more energy (42 kWh/kg of final silicon produced) than required to purify the RHA (5 kWh/kg of Sipv, compared to 65 kWh/kg noted above. Biogenic silica offers three very important foundations for producing high purity silicon. First, wastes from silica accumulating plants, such as rice, corn, many grasses, algae and grains, contain very reactive, amorphous silica from which impurities are easily removed. Second, plants take up only a limited set of, and minimal quantities of the heavy metals present in nature, meaning fewer minerals must be removed. Third, biomass combustion generates a product with intrinsic residual carbon, mixed at nanometer length scales with the SiO2. RHA is 80-90 wt% high surface area (20 m2/g), amorphous SiO2 with some simple mineral content mixed intimately with 5-15 wt% carbon. The mineral content is easily removed by low cost, acid washes using Mayaterials IP, leading to purified rice hull ash (RHAclean) at up to 6N purity. This highly reactive silica is partially extracted from RHAclean at 200 C in an environmentally benign process to adjust SiO2:C ratios to those needed in EA

Richard M. Laine

2012-08-20T23:59:59.000Z

178

Subcritical water extraction of lipids from wet algae for biodiesel production  

Science Journals Connector (OSTI)

Abstract An energy efficient extraction of algal lipids from wet algal biomass was performed at subcritical conditions of water. This was achieved using microwave assisted heating as well as conventional heating. The conventional heating subcritical water (C-SCW) extraction and microwave assisted subcritical water (MW-SCW) experiments were designed and conducted to study the effects of extraction temperature, time, and biomass loading on lipid extraction. The Response surface methodology was used to optimize the parameters for maximum extraction of lipids. The influence of extraction temperature is more when compared to other experimental parameters in both processes. The maximum extraction efficiencies were achieved at 220 °C using conventional heating and 205 °C using microwave heating. Complete extraction of lipids was observed with microwave assisted heating and 70% extraction efficiency was achieved using conventional heating. The energy required for extraction is greatly reduced (2–8 folds) when compared to the conventional solvent extraction. The potential by-products like protein rich residual algae, omega-3 fatty acids, and sugars in residual water phase were identified. The biomass and the crude extracts were characterized using GC–MS, Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS), and thermogravimetric analysis (TGA).

Harvind K. Reddy; Tapaswy Muppaneni; Yingqiang Sun; Yin Li; Sundaravadivelnathan Ponnusamy; Prafulla D. Patil; Peter Dailey; Tanner Schaub; F. Omar Holguin; Barry Dungan; Peter Cooke; Peter Lammers; Wayne Voorhies; Xiuyang Lu; Shuguang Deng

2014-01-01T23:59:59.000Z

179

Long-Term Column Leaching of Phase II Mercury Control Technology By-Products  

SciTech Connect

An NETL research, development and demonstration program under DOE/Fossil Energy Innovations for Existing Plants is directed toward the improvement of the performance and economics of mercury control from coal-fired plants. The current Phase II of the RD&D program emphasizes the evaluation of performance and cost of control technologies through slip-stream and full scale field testing while continuing the development of novel concepts. One of the concerns of the NETL program is the fate of the captured flue gas mercury which is transferred to the condensed phase by-product stream. The stability of mercury and any co-captured elements in the by-products could have a large economic impact if it reduced by-product sales or increasing their disposal costs. As part of a greater characterization effort of Phase II facility baseline and control technology sample pairs, NETL in-house laboratories have performed continuous leaching of a select subset of the available sample pairs using four leachants: water (pH=5.7), dilute sulfuric acid (pH=1.2), dilute acetic acid (pH=2.9), and sodium carbonate (pH=11.1). This report describes results obtained for mercury, arsenic, and selenium during the 5-month leaching experiments.

Schroeder, K.T.; Cardone, C.R.; White, Fredrick; Rohar, P.C.; Kim, A.G

2007-07-01T23:59:59.000Z

180

Management of dry flue gas desulfurization by-products in underground mines  

SciTech Connect

Disposal of coal combustion by-products (CCBs) in an environmentally sound manner is a major issue facing the coal and utility industries in the US today. Disposal into abandoned sections of underground coal mines may overcome many of the surface disposal problems along with added benefits such as mitigation of subsidence and acid mine drainage. However, many of the abandoned underground coal mines are located far from power plants, requiring long distance hauling of by-products which will significantly contribute to the cost of disposal. For underground disposal to be economically competitive, the transportation and handling cost must be minimized. This requires careful selection of the system and optimal design for efficient operation. The materials handling and system economics research addresses these issues. Transportation and handling technologies for CCBs were investigated from technical, environmental and economic points of view. Five technologies were found promising: (1) Pneumatic Trucks, (2) Pressure Differential Rail Cars, (3) Collapsible Intermodal Containers, (4) Cylindrical Intermodal Tanks, and (5) Coal Hopper Cars with Automatic Retractable Tarping. The first two technologies are currently being utilized in transporting by-products from power plants to disposal sites, whereas the next three are either in development or in conceptualization phases. In this research project, engineering design and cost models were developed for the first four technologies. The engineering design models are in the form of spreadsheets and serve the purpose of determining efficient operating schedules and sizing of system components.

Sevim, H.

1997-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "byproducts aromatic extracts" from the National Library of EnergyBeta (NLEBeta).
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they are not comprehensive nor are they the most current set.
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181

Case-Control Study of Colon and Rectal Cancers and Chlorination By-Products in Treated Water  

Science Journals Connector (OSTI)

...Articles Case-Control Study of Colon and Rectal Cancers and Chlorination By-Products in Treated Water 1 Will D. King 2 Loraine D. Marrett Christy G. Woolcott Department of Community Health and Epidemiology, Queens University, Kingston, Ontario...

Will D. King; Loraine D. Marrett; Christy G. Woolcott

2000-08-01T23:59:59.000Z

182

Department of Energy plan for recovery and utilization of nuclear byproducts from defense wastes. Volume 1. Executive summary  

SciTech Connect

Nuclear byproducts are a major national resource that has yet to be incorporated into the economy. The current Defense Byproducts Program is designed to match specific military and commercial needs with the availability of valuable products which are currently treated as waste at considerable expense in waste management costs. This program plan focuses on a few specific areas with the greatest potential for near-term development and application. It also recognizes the need for a continuing effort to develop new applications for byproducts and to continue to assess the impacts on waste management. The entire program has been, and will continue to be structured so as to ensure the safety of the public and maintain the purity of the environment. Social and institutional concerns have been recognized and will be handled appropriately. A significant effort will be undertaken to inform the public of the benefits of byproduct use and of the care being taken to ensure safe, efficient operation.

None

1983-08-01T23:59:59.000Z

183

THE INFRARED SPECTROSCOPY OF NEUTRAL POLYCYCLIC AROMATIC HYDROCARBON CLUSTERS  

SciTech Connect

The mid-infrared spectra of neutral homogeneous polycyclic aromatic hydrocarbon (PAH) clusters have been computed using density functional theory including an empirical correction for dispersion. The C-H out-of-plane bending modes are redshifted for all the clusters considered in this work. The magnitude of the redshift and the peak broadening are dependent on PAH size, shape, and on the PAH arrangement in the cluster.

Ricca, Alessandra [Carl Sagan Center, SETI Institute, 189 Bernardo Avenue, Suite 100, Mountain View, CA 94043 (United States); Bauschlicher, Charles W. Jr. [Entry Systems and Technology Division, Mail Stop 230-3, NASA Ames Research Center, Moffett Field, CA 94035 (United States); Allamandola, Louis J., E-mail: Alessandra.Ricca-1@nasa.gov, E-mail: Charles.W.Bauschlicher@nasa.gov [Space Science Division, Mail Stop 245-6, NASA Ames Research Center, Moffett Field, CA 94035 (United States)

2013-10-10T23:59:59.000Z

184

Polycyclic aromatic hydrocarbon distributions in Mississippi Fan sediments  

E-Print Network (OSTI)

. Sandberg, B. A. , University of Colorado Chairman of Advisory Committee: Dr. James M. Brooks Polycyclic aromatic hydrocarbon (PAH) distributions in Upper Pleistocene sediments of the Mississippi Fan and two intraslope basins in the Gulf of Mexico... chemistries is separate phase migration driven by hydrodynamic flow upward along fault planes. The same variables at intraslope basin sites are highly altered, possibly due to extensive gravity slump faulting. High- performance liquid chromatography...

Sandberg, William Allan

2012-06-07T23:59:59.000Z

185

Utilizing the heat content of gas-to-liquids by-product streams for commercial power generation  

E-Print Network (OSTI)

and sulphur. They have no aromatics due to the isomerisation of the highly paraffinic Fischer-Tropsch liquids into GTL fuels and are practically100%iso-paraffinic,thustheyhaveveryhighcetaneratings. The... and sulphur. They have no aromatics due to the isomerisation of the highly paraffinic Fischer-Tropsch liquids into GTL fuels and are practically100%iso-paraffinic,thustheyhaveveryhighcetaneratings. The...

Adegoke, Adesola Ayodeji

2006-10-30T23:59:59.000Z

186

Method of upgrading oils containing hydroxyaromatic hydrocarbon compounds to highly aromatic gasoline  

DOE Patents (OSTI)

The present invention is a multi-stepped method of converting an oil which is produced by various biomass and coal conversion processes and contains primarily single and multiple ring hydroxyaromatic hydrocarbon compounds to highly aromatic gasoline. The single and multiple ring hydroxyaromatic hydrocarbon compounds in a raw oil material are first deoxygenated to produce a deoxygenated oil material containing single and multiple ring aromatic compounds. Then, water is removed from the deoxygenated oil material. The next step is distillation to remove the single ring aromatic compounds as gasoline. In the third step, the multiple ring aromatics remaining in the deoxygenated oil material are cracked in the presence of hydrogen to produce a cracked oil material containing single ring aromatic compounds. Finally, the cracked oil material is then distilled to remove the single ring aromatics as gasoline.

Baker, E.G.; Elliott, D.C.

1993-01-19T23:59:59.000Z

187

Aggregation of dialkyl-substituted diphosphonic acids and its effect on metal ion extraction.  

SciTech Connect

Solvent extraction reagents containing the diphosphonic acid group exhibit an extraordinary affinity for tri-, tetra- and hexavalent actinides. Their use has been considered for actinide separation and pre-concentration procedures. Solvent extraction data obtained with P,P{prime}-di(2-ethylhexyl) methane-, ethane- and butanediphosphonic acids exhibit features that are difficult to explain without Knowledge of the aggregation state of the extractants. Information about the aggregation of the dialkyl-substituted diphosphonic acids in aromatic diluents has been obtained using the complementary techniques of vapor pressure osmometry (VPO), small angle neutron scattering (SANS), infrared spectroscopy and molecular mechanics. The results from these techniques provide an understanding of the aggregation behavior of these extractants that is fully compatible with the solvent extraction data. The most important results and their relevance to solvent extraction are reviewed in this paper.

Chiarizia, R.; Barrans, R. E., Jr.; Ferraro, J. R. Herlinger, A. W.; McAlister, D. R.

1999-10-22T23:59:59.000Z

188

E-Print Network 3.0 - aromatic thiol monolayers Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

of Applied Physics, Yale University Collection: Materials Science ; Engineering 23 Modification and Stability of Aromatic Self-Assembled Monolayers upon Irradiation with Energetic...

189

E-Print Network 3.0 - aromatic diamine curing Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

Mathematics 3 Oxidation Potentials Correlate with Conductivities of Aromatic Molecular Jordan R. Quinn, Frank W. Foss Jr., Latha Venkataraman,* and Ronald Breslow* Summary: these...

190

Characterizing and Biological Monitoring of Polycyclic Aromatic Hydrocarbons in Exposures to Diesel Exhaust  

Science Journals Connector (OSTI)

Characterizing and Biological Monitoring of Polycyclic Aromatic Hydrocarbons in Exposures to Diesel Exhaust ... Diesel and Gasoline Engine Exhausts and Some Nitroarenes; IARC:? Lyon, France 1989. ...

Wei Huang; Thomas J. Smith; Long Ngo; Tong Wang; Hongqiao Chen; Fanggu Wu; Robert F. Herrick; David C. Christiani; Hui Ding

2007-03-16T23:59:59.000Z

191

E-Print Network 3.0 - aromatic hydrocarbon exhaust Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Page: << < 1 2 3 4 5 > >> 1 Quantification of Local Ozone Production Attributable to Automobile Hydrocarbon Emissions Summary: : Acetylenes: Aromatics: 57 15 2 26 A breakdown of 17...

192

E-Print Network 3.0 - aromatic sulfur heterocycles Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

distribution in the oil fractions obtained by thermal cracking of Jordanian El-Lajjun oil Shale Summary: . Polycyclic aromatic sulfur heterocycles IV. Determination of polycyclic...

193

E-Print Network 3.0 - aromatic non-basmati rice Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

that can modulate susceptibility include proliferation rates... but greater indoor coal use). Biomarkers were: WBC aromatic-DNA adducts by 32 P-postlabeling and PAH Source:...

194

Calculation of the heats of combustion of aromatic hydrocarbons contained in power-generating fuel  

Science Journals Connector (OSTI)

The additive method of group contributions is used for the calculation of the heats of combustion of aromatic hydrocarbons of different structures.

E. V. Sagadeev; V. V. Sagadeev

2006-07-01T23:59:59.000Z

195

E-Print Network 3.0 - aromatic hydrocarbon diol-epoxide Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

with a DNA... ), a polycyclic aromatic hydrocarbon. A residue of fuel and tobacco combustion and frequently ingested by humans... , BP is metabolized in mammals to...

196

E-Print Network 3.0 - aromatic hydrocarbon pah-degrading Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

degradation Summary: Removal of polycyclic aromatic hydrocarbons (PAHs) from sewage sludge by anaerobic degradation N... , terminate in the sludge, and can be released to the...

197

E-Print Network 3.0 - aromatic hydrocarbon clusters Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

aliphatic chains as key intermediates for the nucleation Summary: to macromolecular building blocks (nanoparticles) that eventually turn into soot. Polycyclic aromatic...

198

E-Print Network 3.0 - aromatic white spirit Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

white spirit Search Powered by Explorit Topic List Advanced Search Sample search results for: aromatic white spirit Page: << < 1 2 3 4 5 > >> 1 International Journal of Mass...

199

Polycyclic Aromatic Hydrocarbons Formation in Sludge Incineration by Fluidised Bed and Rotary Kiln Furnace  

Science Journals Connector (OSTI)

Polycyclic Aromatic Hydrocarbons (PAHs) are typical pollutants arising from incineration. They are produced in any incomplete combustion principally due to inhomogeneities in a combustion chamber. The effects ...

Giuseppe Mininni; Andrea Sbrilli; Ettore Guerriero…

2004-05-01T23:59:59.000Z

200

Polycyclic aromatic hydrocarbon (PAH) in four fish species from different trophic levels in the Persian Gulf  

Science Journals Connector (OSTI)

Concentration of ten polycyclic aromatic hydrocarbon (PAH) compounds were determined in liver of four fish species from different trophic levels (Aurigequula fasciata, omnivore; Alepes djedaba, carnivore; Liza ab...

Shirin Rahmanpour; Nasrin Farzaneh Ghorghani…

2014-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "byproducts aromatic extracts" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

E-Print Network 3.0 - aromatic hydrocarbon removal Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Intrinsic Exciton Probe M. Adil Khan,, Chris Neale,| Catherine Michaux, Regis Pomes,|,@ Gilbert G. Prive,|, Robert W. Woody, and Summary: aromatic rings. The resulting...

202

E-Print Network 3.0 - aromatic hydrocarbon compounds Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

bases in Iraq and Afghanistan that lack Summary: Compounds Toxic Organic Halogenated Dioxins Furans (dioxins) Polycyclic Aromatic Hydrocarbons found... and detected all of the...

203

E-Print Network 3.0 - aromatic polycyclic hydrocarbons Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

coal, oil, gas... called aromatic hydrocarbons. These include harmful pollutants like dioxins, PCBs and a group called Source: Rock, Chris - Department of Biological Sciences,...

204

E-Print Network 3.0 - atmospheric polycyclic aromatic Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

burning of coal, oil, gas... called aromatic hydrocarbons. These include harmful pollutants like dioxins, PCBs and a group called... by atmospheric currents and ocean currents...

205

E-Print Network 3.0 - aromatic hydrocarbons modulate Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

S0045-6535(02)00145-5 Summary: Abstract Polycyclic aromatic hydrocarbons (PAHs) and dioxins are lipophilic organic pollutants occurring... absorption, pig INTRODUCTION...

206

E-Print Network 3.0 - aromatic hydrocarbon tracers Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

S0045-6535(02)00145-5 Summary: Abstract Polycyclic aromatic hydrocarbons (PAHs) and dioxins are lipophilic organic pollutants occurring... absorption, pig INTRODUCTION...

207

E-Print Network 3.0 - aromatic pollutants exit Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

of Toxic Contamination Summary: called aromatic hydrocarbons. These include harmful pollutants like dioxins, PCBs and a group called... the Pacific Ocean carry evidence of...

208

E-Print Network 3.0 - aromatic hydrocarbon water-soluble Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

S0045-6535(02)00145-5 Summary: Abstract Polycyclic aromatic hydrocarbons (PAHs) and dioxins are lipophilic organic pollutants occurring... with their lipophilicity and water...

209

E-Print Network 3.0 - aromatic hydrocarbon receptor Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

aromatic hydrocarbons... the aryl hydrocarbon receptor (AHR), through which dioxins and dioxin-like compounds cause altered gene... -methylcholanthrene AHH: aryl...

210

E-Print Network 3.0 - aromatic organic compounds Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

bases in Iraq and Afghanistan that lack Summary: Compounds Toxic Organic Halogenated Dioxins Furans (dioxins) Polycyclic Aromatic Hydrocarbons found... and detected all of the...

211

E-Print Network 3.0 - aromatic chemical compounds Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

bases in Iraq and Afghanistan that lack Summary: Compounds Toxic Organic Halogenated Dioxins Furans (dioxins) Polycyclic Aromatic Hydrocarbons found... in burn pits include, but...

212

E-Print Network 3.0 - aromatic hydrocarbon-contaminated soil...  

NLE Websites -- All DOE Office Websites (Extended Search)

soil... hydrocarbon degraders, and polycyclic aromatic ... Source: Ma, Lena - Soil and Water Science Department, University of Florida Collection: Environmental Sciences and...

213

E-Print Network 3.0 - aromatic polyamide films Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

California Institute of Technology Collection: Chemistry 4 Effect of Water Sorption on Oxygen-Barrier Properties of Aromatic Polyamides Summary: Effect of Water Sorption...

214

E-Print Network 3.0 - alcohols aromatic tertiary Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Summary: in their synthesis include the use of a nucleophilic aromatic substitution reaction to construct the chiral tertiary... of 13-membered macrolactams that possess a...

215

E-Print Network 3.0 - aromatic tertiary alcohols Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Summary: in their synthesis include the use of a nucleophilic aromatic substitution reaction to construct the chiral tertiary... of 13-membered macrolactams that possess a...

216

E-Print Network 3.0 - aromatic hydrocarbon-degrading bacteria...  

NLE Websites -- All DOE Office Websites (Extended Search)

ydrocarbonDegradation It was hypothesized... aromatic hydrocarbon degradation. Hypothesis Test Result Groundwater stimulates Fe(lll) reduction Cell... Hydrocarbon Degradation At...

217

Examination of polycyclic aromatic hydrocarbons in an urban stormwater system and bioaccumulation in Odonata.  

E-Print Network (OSTI)

??Polycyclic aromatic hydrocarbons (PAHs) are toxic organic pollutants produced from combustion processes. Associated with urban runoff they have been detected worldwide in urban wetlands. PAH… (more)

Heintzman, Lucas

2013-01-01T23:59:59.000Z

218

E-Print Network 3.0 - aromatic-radical oxidation chemistry Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

chemistry Search Powered by Explorit Topic List Advanced Search Sample search results for: aromatic-radical oxidation chemistry Page: << < 1 2 3 4 5 > >> 1 Predicting Preignition...

219

E-Print Network 3.0 - aromatic nucleophilic substitution Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

aromatic nucleophilic substitution Page: << < 1 2 3 4 5 > >> 1 October CUME Organic Chemistry Summary: , Thomas H. Fisher, and Debbie B. Saebo, A Low-Temperature Internal...

220

E-Print Network 3.0 - aromatic ring-hydroxylating dioxygenase...  

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et al... was mainly based on two facts: the mass production of CF3 aromatics as agrochemicals and the ... Source: Hemminga, Marcus A. - Department of Molecular Physics,...

Note: This page contains sample records for the topic "byproducts aromatic extracts" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Potential for by-product recovery in geothermal energy operations issue paper  

SciTech Connect

This document identifies and discusses the significant issues raised by the idea of recovering useful by-products from wastes (primarily spent brine) generated during geothermal power production. The physical availability of numerous valuable materials in geothermal brines has captured the interest of geothermal resource developers and other parties ever since their presence was known. The prospects for utilizing huge volumes of highly-saline geothermal brines for electricity generation in the Imperial Valley of California have served to maintain this interest in both private sector and government circles.

None

1982-07-01T23:59:59.000Z

222

Electricity from coal and utilization of coal combustion by-products  

SciTech Connect

Most electricity in the world is conventionally generated using coal, oil, natural gas, nuclear energy, or hydropower. Due to environmental concerns, there is a growing interest in alternative energy sources for heat and electricity production. The major by-products obtained from coal combustion are fly ash, bottom ash, boiler slag, and flue gas desulfurization (FGD) materials. The solid wastes produced in coal-fired power plants create problems for both power-generating industries and environmentalists. The coal fly ash and bottom ash samples may be used as cementitious materials.

Demirbas, A. [Sila Science, Trabzon (Turkey)

2008-07-01T23:59:59.000Z

223

Management of dry flue gas desulfurization by-products in underground mines. Topical report, October 1, 1993--March 31, 1998  

SciTech Connect

The DESEVAL-TRANS program is developed for the purpose of helping the engineer to design and economically evaluate coal combustion byproduct transportation systems that will operate between the power plant and the disposal site. The objective of the research project was to explore the technical, environmental and economic feasibility of disposing coal combustion byproducts in underground mines in Illinois. The DESEVAL-TRANS (short for Design and Evaluation of Transportation Systems) was developed in the Materials Handling and Systems Economics branch of the overall project. Four types of coal combustion byproducts were targeted for transportation and handling: Conventional fly ash; Scrubber sludge; Fluidized Bed Combustion (FBC) fly ash; and Spent-bed ash. Several transportation and handling systems that could handle these byproducts were examined. These technologies were classified under three general categories: Truck; Rail; and Container. The purpose of design models is to determine the proper number of transport units, silo capacity, loading and unloading rates, underground placement capacity, number of shifts, etc., for a given case, defined by a distance-tonnage combination. The cost computation models were developed for the determination of the operating and capital costs. An economic evaluation model, which is common to all categories, was also developed to establish the cost-per-ton of byproduct transported.

NONE

1998-09-01T23:59:59.000Z

224

LARGE ABUNDANCES OF POLYCYCLIC AROMATIC HYDROCARBONS IN TITAN'S UPPER ATMOSPHERE  

SciTech Connect

In this paper, we analyze the strong unidentified emission near 3.28 {mu}m in Titan's upper daytime atmosphere recently discovered by Dinelli et al. We have studied it by using the NASA Ames PAH IR Spectroscopic Database. The polycyclic aromatic hydrocarbons (PAHs), after absorbing UV solar radiation, are able to emit strongly near 3.3 {mu}m. By using current models for the redistribution of the absorbed UV energy, we have explained the observed spectral feature and have derived the vertical distribution of PAH abundances in Titan's upper atmosphere. PAHs have been found to be present in large concentrations, about (2-3) Multiplication-Sign 10{sup 4} particles cm{sup -3}. The identified PAHs have 9-96 carbons, with a concentration-weighted average of 34 carbons. The mean mass is {approx}430 u; the mean area is about 0.53 nm{sup 2}; they are formed by 10-11 rings on average, and about one-third of them contain nitrogen atoms. Recently, benzene together with light aromatic species as well as small concentrations of heavy positive and negative ions have been detected in Titan's upper atmosphere. We suggest that the large concentrations of PAHs found here are the neutral counterpart of those positive and negative ions, which hence supports the theory that the origin of Titan main haze layer is located in the upper atmosphere.

Lopez-Puertas, M.; Funke, B.; Garcia-Comas, M. [Instituto de Astrofisica de Andalucia (CSIC), E-18080 Granada (Spain); Dinelli, B. M. [ISAC-CNR, I-40129 Bologna (Italy); Adriani, A.; D'Aversa, E. [IAPS-INAF, I-00133 Rome (Italy); Moriconi, M. L. [ISAC-CNR, I-00133 Rome (Italy); Boersma, C.; Allamandola, L. J., E-mail: puertas@iaa.es [NASA Ames Research Center, Moffett Field, CA 94035-1000 (United States)

2013-06-20T23:59:59.000Z

225

Mutagenicity of photochemically-transformed polycyclic aromatic amines  

SciTech Connect

Polycyclic aromatic amines (PAA) constitute a class of suspect genotoxic chemicals found in certain energy-related complex organic mixtures. A variety of studies are reported on the photochemical transformation (oxidation) of polycyclic aromatic amines and the increase in genotoxicity of the resulting complex mixtures of radiation-generated products. Biological endpoints of cytotoxicity and mutagenicity were measured in the Ames/Salmonella standard-plate assay. Chemical fractionation and identification of various photoproducts was accomplished with h.p.l.c., uv and ir spectroscopic and mass spectrometric techniques. The benchmark PAA in these studies was aminofluorene (2-AF). Photooxidation of 2-AF can occur at both the exocyclic nitrogen and certain ring positions resulting in the formation of direct-acting and potent bacterial mutagens, including 2-nitrosofluorene, 2-nitrofluorene, and 2-nitrofluoren-9-one. UVA-irradiated 2-AF solutions also contain promutagenic compounds, i.e., is 2-aminofluoren-9-one. These results support the hypothesis that the critical step in the activation of major, identified direct-acting mutagenic 2-AF photoproducts is their reduction by bacterial nitroreductase enzymes to reactive hydroxylamines. Photochemical oxidation is an alternative mechanism of transforming PAA into direct-acting genotoxins. 24 refs., 5 figs.

Strniste, G.F.; Nickols, J.W.; Okinaka, R.T.; Whaley, T.W.

1985-01-01T23:59:59.000Z

226

NETL: Hg Control – The Effects on By-products: What Do We Know and Where  

NLE Websites -- All DOE Office Websites (Extended Search)

Hg Control – The Effects on By-products: Hg Control – The Effects on By-products: What Do We Know and Where Do We Go? Table of Contents Foreword Disclaimer Papers and Presentations Introductions Field Demonstrations Laboratory Studies Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government or any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof. The views and opinions of authors expressed herein do not necessarily state or reflect those of the United States Government or any agency thereof.

227

Succinic Acid as a Byproduct in a Corn-based Ethanol Biorefinery  

SciTech Connect

MBI endeavored to develop a process for succinic acid production suitable for integration into a corn-based ethanol biorefinery. The project investigated the fermentative production of succinic acid using byproducts of corn mill operations. The fermentation process was attuned to include raw starch, endosperm, as the sugar source. A clean-not-sterile process was established to treat the endosperm and release the monomeric sugars. We developed the fermentation process to utilize a byproduct of corn ethanol fermentations, thin stillage, as the source of complex nitrogen and vitamin components needed to support succinic acid production in A. succinogenes. Further supplementations were eliminated without lowering titers and yields and a productivity above 0.6 g l-1 hr-1was achieved. Strain development was accomplished through generation of a recombinant strain that increased yields of succinic acid production. Isolation of additional strains with improved features was also pursued and frozen stocks were prepared from enriched, characterized cultures. Two recovery processes were evaluated at pilot scale and data obtained was incorporated into our economic analyses.

MBI International

2007-12-31T23:59:59.000Z

228

Gas treatment and by-products recovery of Thailand`s first coke plant  

SciTech Connect

Coke is needed in the blast furnace as the main fuel and chemical reactant and the main product of a coke plant. The second main product of the coke plant is coke oven gas. During treatment of the coke oven gas some coal chemicals like tar, ammonia, sulphur and benzole can be recovered as by-products. Since the market prices for these by-products are rather low and often erratic it does not in most cases justify the investment to recover these products. This is the reason why modern gas treatment plants only remove those impurities from the crude gas which must be removed for technical and environmental reasons. The cleaned gas, however, is a very valuable product as it replaces natural gas in steel work furnaces and can be used by other consumers. The surplus can be combusted in the boiler of a power plant. A good example for an optimal plant layout is the new coke oven facility of Thai Special Steel Industry (TSSI) in Rayong. The paper describes the TSSI`s coke oven gas treatment plant.

Diemer, P.E.; Seyfferth, W. [Krupp Uhde GmbH, Dortmund (Germany)

1997-12-31T23:59:59.000Z

229

Reuse of coal combustion by-products: A new profit center  

SciTech Connect

Coal combustion by-products (CCBs) are generated from the combustion of coal for energy production. Approximately 82 million tons of CCBs are produced each year by electric utilities. There are several common types of CCBs produced by coal combustion--fly ash, bottom ash, boiler slag, flue gas desulfurization material (FGD) and fluidized bed combustion byproducts (FBC). Some CCBs such as fly ash, have pozzolanic properties and may have cementitious properties, both of which are advantageous for engineering, construction and waste remediation applications. The American Society for Testing Materials (ASTM) in ASTM C-618 has created two classifications of useful and quality coal ash, Class F ash and Class C ash. Each class of coal ash has different pozzolanic and cementitious characteristics. Coal ash can be utilized in many manufacturing, mining, agricultural, engineering, construction and waste remediation applications. These potential applications may provide a new revenue source for utilities. The profitability of these applications can, however, be limited by applicable state regulations. Prior to initiating any reuse application, a utility should ensure regulatory approval of the proposed use. Approval may be apparent from a review of state law and regulations. Often times, further regulatory analysis and consultations may be necessary.

Jagiella, D. [Howard and Howard Attorneys, Peoria, IL (United States)

1997-09-01T23:59:59.000Z

230

Mutagenicity of Soot and Associated Polycyclic Aromatic Hydrocarbons to Salmonella typhimurium  

Science Journals Connector (OSTI)

...polycyclic aromatic hydrocarbon fraction in terms...by the incomplete combustion of organic material...sediments (1), heat and power generation...PAH from fuel combustion found in the atmosphere...polycyclic aromatic hydrocarbons; PMS, postmitochondrial...amounts of mutation (data not presented...

Debra A. Kaden; Ronald A. Hites; and William G. Thilly

1979-10-01T23:59:59.000Z

231

QSPR models of boiling point, octanolwater partition coefficient and retention time index of polycyclic aromatic hydrocarbons  

E-Print Network (OSTI)

QSPR models of boiling point, octanol­water partition coefficient and retention time index of polycyclic aromatic hydrocarbons Fabiana Alves de Lima Ribeiro, Ma´rcia Miguel Castro Ferreira* Laborato Structure­Property Relationship (QSPR) analysis and study of polycyclic aromatic hydrocarbons (PAHs

Ferreira, Márcia M. C.

232

Polycyclic aromatic hydrocarbons: a QSPR study Marcia M.C. Ferreira  

E-Print Network (OSTI)

Polycyclic aromatic hydrocarbons: a QSPR study Marcia M.C. Ferreira UNICAMP Instituto de Quõmica studies such as the boiling temperature (Tb), the retention index (RI), n-octanol/water partition coecient; Chemometrics 1. Introduction The polycyclic aromatic hydrocarbons (PAH) have been, for a long time, a focus

Ferreira, Márcia M. C.

233

PARTICLE-ASSOCIATED POLYCYCLIC AROMATIC HYDROCARBONS IN THE ATMOSPHERE OF HONG KONG  

E-Print Network (OSTI)

PARTICLE-ASSOCIATED POLYCYCLIC AROMATIC HYDROCARBONS IN THE ATMOSPHERE OF HONG KONG M. ZHENG and M Technology, Clear Water Bay, Hong Kong, China ( present address: Graduate School of Oceanography, University@ust.hk) (Received 3 June 1998; accepted 22 December 1998) Abstract. Polycyclic aromatic hydrocarbons (PAHs) in total

Zheng, Mei

234

Faraday Discuss., 1998, 109, 417436 Evidence for the extraterrestrial origin of polycyclic aromatic  

E-Print Network (OSTI)

aromatic hydrocarbons in the Martian meteorite ALH84001 Simon J. Clemett, Maria T. Dulay, J. Seb Gillette for the obser- vation of polycyclic aromatic hydrocarbons (PAHs) in the Martian meteor- ite ALH84001 be largely the result of terrestrial contamination by Antarctic ice melt water and that a minor

Zare, Richard N.

235

Liquid--liquid equilibria by use of UNIFAC for gasohol extraction systems  

SciTech Connect

A synthetic naphtha cut composed of a mixture of paraffinic, aromatic, and naphthenic hydrocarbons has been studied as a solvent to directly produce gasohol. The equilibria in these highly nonideal liquid mixtures has been estimated by the UNIFAC group contribution method. The process would appear to be simple and direct to produce gasohol by liquid--liquid extraction with this naphtha and could compete with existing azeotropic distillation processes.

Furzer, I.A.

1984-04-01T23:59:59.000Z

236

Biological Monitoring of Fire Fighters: Sister Chromatid Exchange and Polycyclic Aromatic Hydrocarbon-DNA Adducts in Peripheral Blood Cells  

Science Journals Connector (OSTI)

...polycyclic aromatic hydrocarbon-DNA adduct levels...exposure to carcinogenic combustion products. Cytoge...polycyclic aromatic hydrocarbon; CI, confidence interval...estimating exposures to combustion and pyrolysis products...into water, briefly heat denatured (100 Cfor...

Saou-Hsing Liou; David Jacobson-Kram; Miriam C. Poirier; Dung Nguyen; Paul T. Strickland; and Melvyn S. Tockman

1989-09-01T23:59:59.000Z

237

Biological Monitoring of Fire Fighters: Sister Chromatid Exchange and Polycyclic Aromatic Hydrocarbon-DNA Adducts in Peripheral Blood Cells  

Science Journals Connector (OSTI)

...polycyclic aromatic hydrocarbon-DNA adduct levels...to carcinogenic combustion products. Cytoge...polycyclic aromatic hydrocarbon; CI, confidence...controlled for during data analysis. Collection...estimating exposures to combustion and pyrolysis products...water, briefly heat denatured (100...

Saou-Hsing Liou; David Jacobson-Kram; Miriam C. Poirier; Dung Nguyen; Paul T. Strickland; and Melvyn S. Tockman

1989-09-01T23:59:59.000Z

238

Double molecular imprinting – a new sensor concept for improving selectivity in the detection of polycyclic aromatic hydrocarbons (PAHs) in water  

Science Journals Connector (OSTI)

...Highly selective and robust polymer coatings for the detection of polycyclic aromatic hydrocarbons (PAHs) in liquid media have been ... of aromatic rings. Measurements of PAHs in water were also performed with...

Franz L. Dickert; Paul Achatz…

2001-09-01T23:59:59.000Z

239

Levels of Tobacco-Specific Nitrosamines and Polycyclic Aromatic Hydrocarbons in Mainstream Smoke from Different Tobacco Varieties  

Science Journals Connector (OSTI)

...carcinogenic polycyclic aromatic hydrocarbons in mainstream cigarette...21 U.S. EPA. Ambient Water Quality Criteria for Polynuclear Aromatic Hydrocarbons. EPA 440/5-80-069...Quality Criteria for Water; EPA 440/5-86-001...

Yan S. Ding; Liqin Zhang; Ram B. Jain; Ntasha Jain; Richard Y. Wang; David L. Ashley; and Clifford H. Watson

2008-12-01T23:59:59.000Z

240

Estimation of Individual C8 to C10 Aromatic Hydrocarbons in Naphthas and Motor Gasolines by Capillary Gas Chromatography  

Science Journals Connector (OSTI)

......naphthas and motor gasolines is o f great importance...C10 aromatics in straight run, processed naphtha...reformed, and motor gasolines), or i n aromatic...analysis in any straight run, reformed naphthas, and gasolines with final boiling......

Basant Kumar; R.K. Kuchhal; Pradeep Kumar; P.L. Gupta

1986-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "byproducts aromatic extracts" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Acidic soil amendment with a magnesium-containing fluidized bed combustion by-product  

SciTech Connect

Removal of SO{sub 2} from the emissions of coal-fired boilers produces by-products that often consist of CaSO{sub 4}, residual alkalinity, and coal ash. These by-products could be beneficial to acidic soils because of their alkalinity and the ability of gypsum (CaSO{sub 4}{center{underscore}dot}2H{sub 2}O) to reduce Al toxicity in acidic subsoils. A 3-yr field experiment was conducted to determine the liming efficacy of a fluidized bed combustion boiler by-product (FBC) that contained 129 g Mg kg{sup {minus}1} as CaMg(CO{sub 3}){sub 2} and MgO and its effects on surface and subsurface soil chemistry. The FBC was mixed in the surface 10 cm of two acidic soils (Wooster silt loam, an Oxyaquic Fragiudalf, and Coshocton silt loam, an Aquultic Hapludalf) at rates of 0, 0.5, 1, and 2 times each soil's lime requirement (LR). Soils were sampled in 10-cm increments to depths ranging from 20 to 110 cm, and corn (Zea mays L.) and alfalfa (Medicago sativa L.) were grown. Application of Mg-FBC increased alfalfa yields in all six site-years, whereas it had no effect on corn grain yield in five site-years and decreased grain yield in one site-year. Plant tissue concentrations of Mg, S, and Mo were increased by Mg-FBC, while most trace elements were either unaffected or decreased. Application of Mg-FBC at one or two times LR increased surface soil pH to near 7 within 1 wk. Although surface soil pH remained near 7 for 2 yr, there was minimal effect on subjacent soil pH. Application of Mg-FBC increased surface soil concentrations of Ca, Mg, and S, which promoted downward movement of Mg and SO{sub 4}. This had different effects on subsoil chemistry in the two soils: in the high-Ca-status Wooster subsoil, exchangeable Ca was decreased and exchangeable Al was increased, whereas in the high-Al-status Coshocton subsoil, exchangeable Al was decreased and exchangeable Mg was increased. The Mg-FBC was an effective liming material and, because of the presence of both Mg and SO{sub 4}, may be more effective than gypsum in ameliorating subsoil Al phytotoxicity.

Stehouwer, R.C.; Dick, W.A.; Sutton, P.

1999-02-01T23:59:59.000Z

242

Polynuclear aromatic hydrocarbons (PAHs) in fish from the Arabian Gulf  

SciTech Connect

Emphasis has been placed upon the identification and qualification of compounds with potential adverse health effects on humans. Prominent among this group are polynuclear aromatic hydrocarbons (PAHs), several of which are known or suspected carcinogens. PAHs enter the marine environment from a variety of sources including petroleum pollution, industrial and domestic effluents, atmospheric particles, and biosynthesis by plants and microorganisms. Although one-third of the world's oil is produced around the Arabian Gulf, no detailed analysis have been conducted to determine PAHs in this region. Nevertheless, numerous investigations have shown the ability of marine organisms including fish to accumulation PAHs from solution or dispersion in seawater. When fish are harvested, a human health hazard may result. In the present communication, high performance liquid chromatography (HPLC) was used to identify and measure sixteen PAHs priority pollutants issued by US Environmental Protection Agency (EPA) in fourteen species of commercially significant fish from the NW Arabian Gulf.

DouAbdul, A.A.Z.; Abaychi, J.K.; Al-Edanee, T.E.; Ghani, A.A.; Al-Saad, H.T.

1987-03-01T23:59:59.000Z

243

Distribution of polycyclic aromatic hydrocarbons (PAH's) in marsh sediments, Iraq  

SciTech Connect

Recently there has been a growing concern in the release of harmful organics into the environment. Carcinogenic polycyclic aromatic hydrocarbons (PAH's) are a class of compounds of interset due to their possible harmful effects to man as well as organisms. Anthropogenic PAH's may reach aquatic environment as a result of both industrial and domestic effluents, deposition of airborne particles, surface runoff and oil spillage. Having a relatively low water solubility and high affinity to sorb to the suspended particulate matter, most of the PAH's introduced to the aquatic environment tend to accumulate in bottom sediments. Sedimentary PAH's may thus provide a record of the input and history of these pollutants. Consequently, the distribution of PAH's in aquatic sediments have received considerable attention. The purpose of the present work was to establish the distribution of PAH's in the sediments of the marsh region located in southern Iraq.

Al-Saad, H.T.; Al-Timari, A.A. (Univ. of Basrah (Iraq))

1989-12-01T23:59:59.000Z

244

Environmental chamber measurements of mercury flux from coal utilization by-products  

SciTech Connect

An environmental chamber was constructed to measure the mercury flux from coal utilization by-product (CUB) samples. Samples of fly ash, FGD gypsum, and wallboard made from FGD gypsum were tested under both dark and illuminated conditions with or without the addition of water to the sample. Mercury releases varied widely, with 7-day experiment averages ranging from -6.8 to 73 ng/m2 h for the fly ash samples and -5.2 to 335 ng/m2 h for the FGD/wallboard samples. Initial mercury content, fly ash type, and light exposure had no observable consistent effects on the mercury flux. For the fly ash samples, the effect of a mercury control technology was to decrease the emission. For three of the four pairs of FGD gypsum and wallboard samples, the wallboard sample released less (or absorbed more) mercury than the gypsum.

Pekney, N.J.; Martello, D.V.; Schroeder, K.T.; Granite, E.J.

2009-05-01T23:59:59.000Z

245

Methanol production with elemental phosphorus byproduct gas: technical and economic feasibility  

SciTech Connect

The technical and economic feasibility of using a typical, elemental, phosphorus byproduct gas stream in methanol production is assessed. The purpose of the study is to explore the potential of a substitute for natural gas. The first part of the study establishes economic tradeoffs between several alternative methods of supplying the hydrogen which is needed in the methanol synthesis process to react with CO from the off gas. The preferred alternative is the Battelle Process, which uses natural gas in combination with the off gas in an economically sized methanol plant. The second part of the study presents a preliminary basic design of a plant to (1) clean and compress the off gas, (2) return recovered phosphorus to the phosphorus plant, and (3) produce methanol by the Battelle Process. Use of elemental phosphorus byproduct gas in methanol production appears to be technically feasible. The Battelle Process shows a definite but relatively small economic advantage over conventional methanol manufacture based on natural gas alone. The process would be economically feasible only where natural gas supply and methanol market conditions at a phosphorus plant are not significantly less favorable than at competing methanol plants. If off-gas streams from two or more phosphorus plants could be combined, production of methanol using only offgas might also be economically feasible. The North American methanol market, however, does not seem likely to require another new methanol project until after 1990. The off-gas cleanup, compression, and phosphorus-recovery system could be used to produce a CO-rich stream that could be economically attractive for production of several other chemicals besides methanol.

Lyke, S.E.; Moore, R.H.

1981-01-01T23:59:59.000Z

246

Advanced Byproduct Recovery: Direct Catalytic Reduction of Sulfur Dioxide to Elemental Sulfur. Fifth quarterly technical progress report, December 1996  

SciTech Connect

More than 170 wet scrubber systems applied, to 72,000 MW of U.S., coal-fired, utility boilers are in operation or under construction. In these systems, the sulfur dioxide removed from the boiler flue gas is permanently bound to a sorbent material, such as lime or limestone. The sulfated sorbent must be disposed of as a waste product or, in some cases, sold as a byproduct (e.g. gypsum). Due to the abundance and low cost of naturally occurring gypsum, and the costs associated with producing an industrial quality product, less than 7% of these scrubbers are configured to produce usable gypsum (and only 1% of all units actually sell the byproduct). The disposal of solid waste from each of these scrubbers requires a landfill area of approximately 200 to 400 acres. In the U.S., a total of 19 million tons of disposable FGD byproduct are produced, transported and disposed of in landfills annually. The use of regenerable sorbent technologies has the potential to reduce or eliminate solid waste production, transportation and disposal. In a regenerable sorbent system, the sulfur dioxide in the boiler flue gas is removed by the sorbent in an adsorber. The S0{sub 2}s subsequently released, in higher concentration, in a regenerator. All regenerable systems produce an off-gas stream from the regenerator that must be processed further in order to obtain a salable byproduct, such as elemental sulfur, sulfuric acid or liquid S0{sub 2}.

NONE

1996-12-01T23:59:59.000Z

247

Advanced Byproduct Recovery: Direct Catalytic Reduction of Sulfur Dioxide to Elemental Sulfur. Sixth quarterly technical progress report, January - March 1997  

SciTech Connect

More than 170 wet scrubber systems applied, to 72,000 MW of U.S., coal-fired, utility boilers are in operation or under construction. In these systems, the sulfur dioxide removed from the boiler flue gas is permanently bound to a sorbent material, such as lime or limestone. The sulfated sorbent must be disposed of as a waste product or, in some cases, sold as a byproduct (e.g. gypsum). Due to the abundance and low cost of naturally occurring gypsum, and the costs associated with producing an industrial quality product, less than 7% of these scrubbers are configured to produce usable gypsum (and only 1% of all units actually sell the byproduct). The disposal of solid waste from each of these scrubbers requires a landfill area of approximately 200 to 400 acres. In the U.S., a total of 19 million tons of disposable FGD byproduct are produced, transported and disposed of in landfills annually. The use of regenerable sorbent technologies has the potential to reduce or eliminate solid waste production, transportation and disposal. In a regenerable sorbent system, the sulfur dioxide in the boiler flue gas is removed by the sorbent in an adsorber. The S0{sub 2}s subsequently released, in higher concentration, in a regenerator. All regenerable systems produce an off-gas stream from the regenerator that must be processed further in order to obtain a salable byproduct, such as elemental sulfur, sulfuric acid or liquid S0{sub 2}.

NONE

1997-03-01T23:59:59.000Z

248

Management of dry gas desulfurization by-products in underground mines. Quarterly report, October 1--December 31, 1996  

SciTech Connect

The objective is to develop and demonstrate two technologies for the placement of coal combustion by-products in abandoned underground coal mines, and to assess the environmental impact of these technologies for the management of coal combustion by-products. The two technologies for the underground placement that will be developed and demonstrated are: (1) pneumatic placement using virtually dry coal combustion by-products, and (2) hydraulic placement using a paste mixture of combustion by-products with about 70% solids. Phase 2 of the overall program began April 1, 1996. The principal objective of Phase 2 is to develop and fabricate the equipment for both the pneumatic and hydraulic placement technologies, and to conduct a limited, small-scale shakedown test of the pneumatic and hydraulic placement equipment. The shakedown test originally was to take place on the surface, in trenches dug for the tests. However, after a thorough study it was decided, with the concurrence of DOE-METC, to drill additional injection wells and conduct the shakedown tests underground. This will allow a more thorough test of the placement equipment.

NONE

1996-12-31T23:59:59.000Z

249

Task 1.13 - Data Collection and Database Development for Clean Coal Technology By-Product Characteristics and Management Practices  

SciTech Connect

U.S. Department of Energy Federal Energy Technology Center-Morgantown (DOE FETC) efforts in the areas of fossil fuels and clean coal technology (CCT) have included involvement with both conventional and advanced process coal conversion by-products. In 1993, DOE submitted a Report to Congress on "Barriers to the Increased Utilization of Coal Combustion Desulfurization Byproducts by Governmental and Commercial Sectors" that provided an outline of activities to remove the barriers identified in the report. DOE charged itself with participation in this process, and the work proposed in this document facilitates DOE's response to its own recommendations for action. The work reflects DOE's commitment to the coal combustion by-product (CCB) industry, to the advancement of clean coal technology, and to cooperation with other government agencies. Information from DOE projects and commercial endeavors in fluidized-bed combustion (FBC) and coal gasification is the focus of this task. The primary goal is to provide an easily accessible compilation of characterization information on the by-products from these processes to government agencies and industry to facilitate sound regulatory and management decisions. Additional written documentation will facilitate the preparation of an updated final version of background information collected for DOE in preparation of the Report to Congress on barriers to CCB utilization.

Debra F. Pflughoeft-Hassett

1998-02-01T23:59:59.000Z

250

Re-refining of waste mineral insulating oil by extraction with N-methyl-2-pyrrolidone  

Science Journals Connector (OSTI)

Extraction with N-methyl-2-pyrrolidone (NMP) via the three-stage mixer–settler operation was studied as possible process for re-refining of waste mineral insulating oil. The following extraction process parameters were investigated systematically in order to determine their optimum values: amount of water as co-solvent in NMP, extraction temperature and solvent/oil ratio. The process parameters and resulting oil chemical compositions were found to influence the electrical properties and the oxidation stability of the re-refined oil. The levels of aromatic, paraffinic and polycyclic aromatic hydrocarbons were determined using IR spectroscopy and HPLC, while other relevant chemical and electrical properties of waste and re-refined oil were determined according to IEC, ISO and ASTM standards. Extraction using NMP was found to be an adequate method for waste mineral insulating oil re-refining, according to the application properties of the re-refined oil. Moderate extraction temperature, 1% water in NMP and a low solvent/oil ratio (0.5) were determined to be the optimum process parameters.

Jelena Luki?; Aleksandar Orlovi?; Michael Spiteller; Jovan Jovanovi?; Dejan Skala

2006-01-01T23:59:59.000Z

251

Concentration of marc extracts by membrane techniques  

Science Journals Connector (OSTI)

By-products obtained from red currant processing still contain large amounts of useful components, e.g. pectin. Pectin was extracted from red currant marc with water at a solid/liquid ratio of 1:10. To reduce the operating costs of further possessing, we concentrated the pectin solution by membrane separation, i.e. nanofiltration (NF) and reverse osmosis (RO). The objectives of our work were to study the effects of the operating pressure and cross-volume flow rate on the flux and on the membrane separation concentration ratio in order to establish the optimum operating conditions and to evaluate the contributions of the fouling, cake and membrane resistances to the overall resistance. Flat-sheet RO and a spiral-wound NF membrane were applied in the work. The conductivity, the color, the viscosity and the TSS of the permeate and the concentrate were followed during the measurements. Concentration by RO resulted in an increase of the TSS content to 4.28°Brix; for NF the corresponding level was 8.88°Brix. The membrane resistance and the fouling resistance were the determinant relative to the gel resistance.

C. Hodúr; Sz. Kertész; S. Beszédes; Zs. László; G. Szabó

2009-01-01T23:59:59.000Z

252

Coal extraction process  

SciTech Connect

Sub-divided coal is extracted under non-thermally destructive conditions with a solvent liquid containing a compound having the general formula:

Hammack, R. W.; Sears, J. T.; Stiller, A. H.

1981-06-09T23:59:59.000Z

253

Fission Product Extraction Process  

ScienceCinema (OSTI)

A new INL technology can simultaneously extract cesium and strontium for reuse. For more information about INL research, visit http://www.facebook.com/idahonationallaboratory.

None

2013-05-28T23:59:59.000Z

254

Fission Product Extraction Process  

SciTech Connect

A new INL technology can simultaneously extract cesium and strontium for reuse. For more information about INL research, visit http://www.facebook.com/idahonationallaboratory.

None

2011-01-01T23:59:59.000Z

255

Metabolism of mixtures of polycyclic aromatic hydrocarbons (PAHs) by Cunninghamella elegans  

E-Print Network (OSTI)

Polycyclic aromatic hydrocarbons (PAHs) are environmentally significant compounds due to the toxicity of some members. They are ubiquitous and are persistent bioaccumulative toxins(PBTs). The toxicity of PAHs represents a risk to human health...

Olatubi, Oluwaseun Alfred

2007-04-25T23:59:59.000Z

256

Noncovalent ????? interaction between graphene and aromatic molecule: Structure, energy, and nature  

SciTech Connect

Noncovalent ????? interactions between graphene and aromatic molecules have been studied by using density functional theory with empirical dispersion correction (?B97X-D) combined with zeroth-order symmetry adapted perturbation theory (SAPT0). Excellent agreement of the interaction energies computed by means of ?B97X-D and spin component scaled (SCS) SAPT0 methods, respectively, shows great promise for the two methods in the study of the adsorption of aromatic molecules on graphene. The other important finding in this study is that, according to SCS-SAPT0 analyses, ????? interactions between graphene and aromatic molecules are largely dependent on both dispersion and electrostatic type interactions. It is also noticed that ????? interactions become stronger and more dispersive (less electrostatic) upon substitution of the very electronegative fluorine atoms onto the aromatic molecules.

Wang, Weizhou, E-mail: wzw@lynu.edu.cn, E-mail: ybw@gzu.edu.cn; Zhang, Yu [College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022 (China)] [College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022 (China); Wang, Yi-Bo, E-mail: wzw@lynu.edu.cn, E-mail: ybw@gzu.edu.cn [Department of Chemistry and Key Laboratory of Guizhou High Performance Computational Chemistry, Guizhou University, Guiyang 550025 (China)] [Department of Chemistry and Key Laboratory of Guizhou High Performance Computational Chemistry, Guizhou University, Guiyang 550025 (China)

2014-03-07T23:59:59.000Z

257

E-Print Network 3.0 - aromatic substitution photo-nocas Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

and to structural differences in the aliphatic... (a) and HMBC (b) spectra for TCV oil as an example. The degree of substitution of the aromatic... MS and the degree of...

258

E-Print Network 3.0 - aromatic hydrocarbons concentrations Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

Materials Science ; Chemistry 52 0600B5--Brooks-McCall Cruise 05 MAY 30-JUN 1 2010 ****DATA SOURCE**** Summary: Aromatic Hydrocarbons | 8270M BTHIOPHNE Benzo(b)thiophene...

259

E-Print Network 3.0 - aromatic hydrocarbon bioremediation Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

Collection: Biotechnology 78 0600B5--Brooks-McCall Cruise 05 MAY 30-JUN 1 2010 ****DATA SOURCE**** Summary: Aromatic Hydrocarbons | 8270M BTHIOPHNE Benzo(b)thiophene...

260

E-Print Network 3.0 - aromatic hydrocarbon concentrations Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

Materials Science ; Chemistry 52 0600B5--Brooks-McCall Cruise 05 MAY 30-JUN 1 2010 ****DATA SOURCE**** Summary: Aromatic Hydrocarbons | 8270M BTHIOPHNE Benzo(b)thiophene...

Note: This page contains sample records for the topic "byproducts aromatic extracts" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Sources and bioavailability of polynuclear aromatic hydrocarbons in Galveston Bay, Texas  

Science Journals Connector (OSTI)

Oyster and sediment samples collected from six sites in Galveston Bay from 1986 to 1998 were analyzed for polynuclear aromatic hydrocarbons (PAHs). Total concentrations of parent PAHs in oysters ranged from 20...

Yaorong Qian; Terry L. Wade; Jose L. Sericano

2001-12-01T23:59:59.000Z

262

Photoinduced Hydrogen Abstraction from Phenols by Aromatic Ketones. A New Mechanism for Hydrogen Abstraction by  

E-Print Network (OSTI)

Photoinduced Hydrogen Abstraction from Phenols by Aromatic Ketones. A New Mechanism for Hydrogen carried out of the kinetics of inter- and intramolecular phenolic hydrogen abstraction phenolic hydrogen, which yields the corresponding phenoxyl-hemipinacol biradical. The biradicals have also

Leigh, William J.

263

Black carbon in marine sediments : quantification and implications for the sorption of polycyclic aromatic hydrocarbons  

E-Print Network (OSTI)

Sorption is a key factor in determining the fate of polycyclic aromatic hydrocarbons (PAHs) in the environment. Here, PAH sorption is proposed as the sum of two mechanisms: absorption into a biogenic, organic carbon (OC) ...

Accardi-Dey, AmyMarie, 1976-

2003-01-01T23:59:59.000Z

264

Biodegradation of polycyclic Aromatic hydrocarbons by a bacterial consortium from Marine environment; -.  

E-Print Network (OSTI)

??newlinePolycyclic aromatic hydrocarbons PAHs are ubiquitous, newlineCarcinogenic mutagenic and persistent environmental pollutants generated by newlinenatural combustion processes as well as from human activities newlineAnthropogenic inputs… (more)

Arulazhagan, P

2014-01-01T23:59:59.000Z

265

Temperature dependence of IR absorption spectra of water in aromatic hydrocarbons  

Science Journals Connector (OSTI)

The influence of the temperature of a medium on the IR absorption spectra of water dissolved in aromatic hydrocarbons was studied. It was found that the ... of the determination of the quantity of dissolved water

Sh. I. Seidov; L. I. Prokhvatilova

2008-07-01T23:59:59.000Z

266

E-Print Network 3.0 - aromatic polyamide membranes Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Topic List Advanced Search Sample search results for: aromatic polyamide membranes Page: << < 1 2 3 4 5 > >> 1 Desalination, 95 (1994) 325-345 Elsevier Science B.V....

267

Particle Phase Concentrations of Polycyclic Aromatic Hydrocarbons in the Atmospheric Environment of Jinámar, Gran Canaria  

Science Journals Connector (OSTI)

Airborne concentrations of 8 polycyclic aromatic hydrocarbons (PAHs): fluoranthene, Flt, Pyrene, Pyr, benzo(a)anthracene, BaA, chrysene, Chr, benzo(b)fluoranthene + benzo(k)fluoranthene,B(b + k)F, benzo(a)pyrene,...

José A. López Cancio; Antonio Vera Castellano…

2002-05-01T23:59:59.000Z

268

Presence of Polycyclic Aromatic Hydrocarbons in Surface Waters Used for the Production of Drinking Water  

Science Journals Connector (OSTI)

Two methods widely applied for isolating PAH from surface water have been compared: solvent extraction using cyclohexane and solid surface extraction. Higher recoveires were obtained through solvent extraction...

F. Van Hoof; S. Aerts

1988-01-01T23:59:59.000Z

269

RESIDUES FROM COAL CONVERSION AND UTILIZATION: ADVANCED MINERALOGICAL CHARACTERIZATION AND DISPOSED BYPRODUCT DIAGENESIS  

SciTech Connect

Prior to the initiation of this study, understanding of the long-term behavior of environmentally-exposed Coal Combustion By-Products (CCBs) was lacking in (among others) two primary areas addressed in this work. First, no method had been successfully applied to achieve full quantitative analysis of the partitioning of chemical constituents into reactive or passive crystalline or noncrystalline compounds. Rather, only semi-quantitative methods were available, with large associated errors. Second, our understanding of the long-term behavior of various CCBs in contact with the natural environment was based on a relatively limited set of study materials. This study addressed these areas with two objectives, producing (1) a set of protocols for fully quantitative phase analysis using the Rietveld Quantitative X-ray Diffraction (RQXRD) method and (2) greater understanding of the hydrologic and geochemical nature of the long-term behavior of disposed and utilized CCBs. The RQXRD technique was initially tested using (1) mixtures of National Institute of Standards and Technology (NIST) crystalline standards, and (2) mixtures of synthetic reagents simulating various CCBs, to determine accuracy and precision of the method, and to determine the most favorable protocols to follow in order to efficiently quantify multi-phase mixtures. Four sets of borehole samples of disposed or utilized CCBs were retrieved and analyzed by RQXRD according to the protocols developed under the first objective. The first set of samples, from a Class F ash settling pond in Kentucky disposed for up to 20 years, showed little mineralogical alteration, as expected. The second set of samples, from an embankment in Indiana containing a mixture of chain-grate (stoker) furnace ash and fluidized bed combustion (FBC) residues, showed formation of the mineral thaumasite, as observed in previously studied exposed FBC materials. Two high-calcium CCBs studied, including a dry-process flue gas desulfurization (FGD) by-product disposed in the Midwest, and a mixture of Class C fly ash and wet process FGD by-product codisposed in North Dakota, appeared relatively unchanged mineralogically over the up to 5 and 17 years of emplacement, respectively. Each of these two materials contained mineralogies consistent with short-term hydration products of their respective starting (dry) materials. The hydration product ettringite persisted throughout the duration of emplacement at each site, and the diagenetic ash alteration product thaumasite did not form at either site. Explanations for the absence of thaumasite in these two sites include a lack of significant carbonate, sulfate, and alkalinity sources in the case of the North Dakota site, and a lack of sulfate, alkalinity, and sufficient moisture in the Midwest site. Potential for future thaumasite formation in these materials may exist if placed in contact with cold, wet materials containing the missing components listed above. In the presence of the sulfite scrubber mineral hannebachite, the ettringites formed had crystallographic unit cell dimensions smaller than those of pure sulfate ettringite, suggesting either incorporation of sulfite ions into the ettringite structure, or incorporation of silicon and carbonate ions, forming a solid solution towards thaumasite.

Gregory J. McCarthy; Dean G. Grier

2001-01-01T23:59:59.000Z

270

Chemometric optimization of dispersive suspended microextraction followed by gas chromatography–mass spectrometry for the determination of polycyclic aromatic hydrocarbons in natural waters  

Science Journals Connector (OSTI)

Abstract A dispersive suspended microextraction (DSME) method coupled with gas chromatography–mass spectrometry (GC–MS) was developed and validated for the simultaneous determination of ten polycyclic aromatic hydrocarbons in real water samples. The optimization of the method was achieved with a 27–4 Plackett–Burman design, while the significant factors were optimized using a central composite design (CCD). The parameters that were studied included the sample volume, organic solvent volume, extraction time, restoration time and organic solvent. The optimum experimental conditions for the proposed method comprised 4.3 mL of the water sample, 93 ?L of toluene as the extraction solvent, a 104-s extraction time and a 10-min restoration time. The recoveries varied from 70 to 111%. Chrysene was the least recovered compound, while anthracene displayed the highest extraction efficiency. The analytical method (DSME) was shown to be linear (R2 > 0.993) over the studied range of concentrations, exhibiting satisfactory precision (RSD% < 10.6%) and reaching limits of detection between 8 and 46 ng L?1.

Nikolaos P. Petridis; Vasilios A. Sakkas; Triantafyllos A. Albanis

2014-01-01T23:59:59.000Z

271

Polycyclic aromatic hydrocarbons and fatal ischemic heart disease  

SciTech Connect

Several toxicologic and epidemiologic studies have produced evidence that occupational exposure to polycyclic aromatic hydrocarbons (PAH) is a risk factor for ischemic heart disease (IHD). However, a clear exposure-response relation has not been demonstrated. We studied a relation between exposure to PAH and mortality from IHD (418 cases) in a cohort of 12,367 male asphalt workers from Denmark, Finland, France, Germany, Israel, The Netherlands and Norway. Exposures to benzo(a)pyrene were assessed quantitatively using measurement-driven exposure models. Exposure to coal tar was assessed in a semiquantitative manner on the basis of information supplied by company representatives. We carried out sensitivity analyses to assess potential confounding by tobacco smoking. Both cumulative and average exposure indices for benzo(a)pyrene were positively associated with mortality from IHD. The highest relative risk for fatal IHD was observed for average benzo(a)pyrene exposures of 273 ng/m{sup 3} or higher, for which the relative risk was 1.64(95% confidence interval = 1.13-2.38). Similar results were obtained for coal tar exposure. Sensitivity analysis indicated that even in a realistic scenario of confounding by smoking, we would observe approximately 20% to 40% excess risk in IHD in the highest PAH-exposure categories. Our results lend support to the hypothesis that occupational PAH exposure causes fatal IHD and demonstrate a consistent exposure-response relation for this association.

Burstyn, I.; Kromhout, H.; Partanen, T.; Svane, O.; Langard, S.; Ahrens, W.; Kauppinen, T.; Stucker, I.; Shaham, J.; Heederik, D.; Ferro, G.; Heikkila, P.; Hooiveld, M.; Johansen, C.; Randem, B.G.; Boffetta, P. [International Agency for Research on Cancer, Lyon (France)

2005-11-01T23:59:59.000Z

272

Regressing Gas/Particle Partitioning Data for Polycyclic Aromatic Hydrocarbons  

Science Journals Connector (OSTI)

Regressing Gas/Particle Partitioning Data for Polycyclic Aromatic Hydrocarbons ... Although PAHs can be emitted to the environment as a result of natural combustion processes (e.g., forest fires and volcanoes), human activities are believed to dominate global PAH emissions, because high atmospheric concentrations of PAHs are usually observed in urban and industrial areas where vehicle traffic, aluminum smelting, residential heating, and other activities emit PAHs into the atmosphere (4, 5). ... One of the earliest approaches to describing the G/P partitioning equilibrium of PAHs, known as the Junge?Pankow model, relates ? to PL using the following: The parameter A in this equation is sometimes interpreted as the product of two terms c and ?. ? is the surface area of particles in a unit volume of air (cm2·cm-3) and c (Pa·cm) is a substance-specific factor depending on ambient temper ature, compound, sorption sites, and the heats of desorption from surface and vaporization from the liquid compound (7, 10, 14). ...

Yushan Su; Ying Duan Lei; Frank Wania; Mahiba Shoeib; Tom Harner

2006-04-22T23:59:59.000Z

273

Year/PAD District Alkylates Aromatics Road Oil  

U.S. Energy Information Administration (EIA) Indexed Site

Alkylates Alkylates Aromatics Road Oil and Lubricants Petroleum Coke (MMcfd) Hydrogen Sulfur (short tons/day) Production Capacity Asphalt Isomers Marketable Table 7. Operable Production Capacity of Petroleum Refineries, January 1, 1981 to January 1, 2013 (Thousand Barrels per Stream Day, Except Where Noted) a JAN 1, 1981 974 299 765 131 234 276 2,054 NA JAN 1, 1982 984 290 740 162 242 267 1,944 NA JAN 1, 1983 960 237 722 212 241 296 2,298 NA JAN 1, 1984 945 218 800 208 241 407 2,444 NA JAN 1, 1985 917 215 767 219 243 424 2,572 NA JAN 1, 1986 941 276 804 258 246 356 2,357 NA JAN 1, 1987 974 287 788 326 250 364 2,569 23,806 JAN 1, 1988 993 289 788 465 232 368 2,418 27,639 JAN 1, 1989 1,015 290 823 469 230 333 2,501 28,369 JAN 1, 1990 1,030 290 844 456 232 341 2,607 24,202

274

Environmental diagnostic analysis of ground water bacteria and their involvement in utilization of aromatic compounds  

SciTech Connect

The objective of this study was to examine the hypothesis that select functional groups of bacteria from pristine sites have an innate ability to degrade synthetic aromatics that often contaminate groundwater environments,due to exposure to naturally occurring recalcitrant aromatics in their environment. This study demonstrates that subsurface microbial communities are capable of utilizing lignin and humic acid breakdown products. Utilizers of these compounds were found to be present in most all the wells tested. Even the deepest aquifer tested had utilizers present for all six of the aromatics tested. Highest counts for the aromatics tested were observed with the naturally occurring breakdown products of either lignin or humic acid. Carboxylic acids were found to be an important sole carbon source for groundwater bacteria possibly explained by the fact that they are produced by the oxidative cleavage of aromatic ring structures. The carbohydrate sole carbon sources that demonstrated the greatest densities were ones commonly associated with humics. This study indicates that utilization of naturally occurring aromatic compounds in the subsurface is an important nutritional source for groundwater bacteria. In addition, it suggests that adaptation to naturally occurring recalcitrant substrates is the origin of degradative pathways for xenobiotic compounds with analogous structure. This work has important implications for in situ bioremediation as a method of environmental cleanup.

Wear, J.E. Jr.

1993-05-01T23:59:59.000Z

275

Heterogeneous distribution of trace elements and fluorine in phosphogypsum by-product  

Science Journals Connector (OSTI)

Phosphogypsum (PG), a by-product from phosphate fertilizer production, is composed mainly of gypsum (CaSO4·2H2O) but also contains minor quantities of trace elements (TE), rare earth elements (REE) and F. Some elements may be elevated in quantities to be of environmental concern. This study determined the distribution of TE, REE and F among three size fractions (53 ?m) in \\{PGs\\} derived from three different phosphate rock sources. Fine fraction PG (<20 ?m) composed of <10% of total PG mass but was highly enriched in TE, REE and F compared to unfractionated PG. For PG derived from Idaho rock, Se in the fine fraction was enriched 830 times over soil and 415 times over shale while Cd was enriched in the fine fraction 70-fold over shale and soil. Fluorine was elevated 37 times in the fine fraction compared to shale. The same trends were observed for PG derived from Togo and Florida rocks. Elevated elemental concentrations in fine particles and particle sorting during PG deposition may contribute to chemical heterogeneity of PG repositories, and make elements more susceptible to mobilization processes, such as leaching and erosion. Removal of fines will improve the utilization of PG in other industries, such as for use as an amendment to agricultural soils.

J.M. Arocena; P.M. Rutherford; M.J. Dudas

1995-01-01T23:59:59.000Z

276

FGD Additives to Segregate and Sequester Mercury in Solid Byproducts - Final Report  

SciTech Connect

Many mercury control strategies for U.S. coal-fired power generating plants involve co-benefit capture of oxidized mercury from flue gases treated by wet flue gas desulfurization (FGD) systems. For these processes to be effective at overall mercury control, the captured mercury must not be re-emitted to the atmosphere or into surface or ground water. The project sought to identify scrubber additives and FGD operating conditions under which mercury re-emissions would decrease and mercury would remain in the liquor and be blown down from the system in the chloride purge stream. After exiting the FGD system, mercury would react with precipitating agents to form stable solid byproducts and would be removed in a dewatering step. The FGD gypsum solids, free of most of the mercury, could then be disposed or processed for reuse as wallboard or in other beneficial reuse. The project comprised extensive bench-scale FGD scrubber tests in Phases I and II. During Phase II, the approaches developed at the bench scale were tested at the pilot scale. Laboratory wastewater treatment tests measured the performance of precipitating agents in removing mercury from the chloride purge stream. Finally, the economic viability of the approaches tested was evaluated.

Searcy, K.; Bltyhe, G.M.; Steen, W.A.

2012-02-28T23:59:59.000Z

277

Variability of chlorination by-product occurrence in water of indoor and outdoor swimming pools  

Science Journals Connector (OSTI)

Swimming is one of the most popular aquatic activities. Just like natural water, public pool water may contain microbiological and chemical contaminants. The purpose of this study was to study the presence of chemical contaminants in swimming pools, in particular the presence of disinfection by-products (DBPs) such as trihalomethanes (THMs), haloacetic acids (HAAs) and inorganic chloramines (CAMi). Fifty-four outdoor and indoor swimming pools were investigated over a period of one year (monthly or bi-weekly sampling, according to the type of pool) for the occurrence of DBPs. The results showed that DBP levels in swimming pools were greater than DBP levels found in drinking water, especially for HAAs. Measured concentrations of \\{THMs\\} (97.9 vs 63.7 ?g/L in average) and \\{HAAs\\} (807.6 vs 412.9 ?g/L in average) were higher in outdoor pools, whereas measured concentrations of \\{CAMi\\} (0.1 vs 0.8 mg/L in average) were higher in indoor pools. Moreover, outdoor pools with heated water contained more \\{DBPs\\} than unheated pools. Finally, there was significant variability in tTHM, HAA9 and \\{CAMi\\} levels in pools supplied by the same municipal drinking water network, suggesting that individual pool characteristics (number of swimmers) and management strategies play a major role in DBP formation.

Sabrina Simard; Robert Tardif; Manuel J. Rodriguez

2013-01-01T23:59:59.000Z

278

TREATMENT OF METAL-LADEN HAZARDOUS WASTES WITH ADVANCED CLEAN COAL TECHNOLOGY BY-PRODUCTS  

SciTech Connect

Metal-laden wastes can be stabilized and solidified using advanced clean coal technology by-products (CCTBs)--fluid bed combustor ash and spray drier solids. These utility-generated treatment chemicals are available for purchase through brokers, and commercial applications of this process are being practiced by treaters of metal-laden hazardous waste. A complex of regulations governs this industry, and sensitivities to this complex has discouraged public documentation of treatment of metal-laden hazardous wastes with CCTBs. This report provides a comprehensive public documentation of laboratory studies that show the efficacy of the stabilization and solidification of metal-laden hazardous wastes--such as lead-contaminated soils and sandblast residues--through treatment with CCTBs. It then describes the extensive efforts that were made to obtain the permits allowing a commercial hazardous waste treater to utilize CCTBs as treatment chemicals and to install the equipment required to do so. It concludes with the effect of this lengthy process on the ability of the treatment company to realize the practical, physical outcome of this effort, leading to premature termination of the project.

James T. Cobb, Jr.

2003-09-12T23:59:59.000Z

279

Utilization of low NO{sub x} coal combustion by-products. Quarterly report, April--June 1995  

SciTech Connect

This project is studying a beneficiation process to make power plant fly ash a more useful by-product. The tasks include: (1) Laboratory characterization: Sample collection; Material characterization; and Lab testing of ash processing operations; (2) Pilot plant testing of the separation of carbon from fly ash; (3) Product testing: Concrete testing and Plastic fillers; and (4) Market and economic analysis. Appendices present information on material characterization, laboratory testing of a flotation process, pilot runs, and concrete testing results.

NONE

1995-07-01T23:59:59.000Z

280

Management of dry flue gas desulfurization by-products in underground mines. Quarterly report, April 1--June 30, 1996  

SciTech Connect

On September 30, 1993, the US Department of Energy - Morgantown Energy Technology Center (DOE-METC) and Southern Illinois University at Carbondale (SIUC) entered into a cooperative research agreement entitled {open_quotes}Management of Dry Flue Gas Desulfurization By-Products in Underground Mines{close_quotes} (DE-FC21-93MC30252). Under the agreement Southern Illinois University at Carbondale will develop and demonstrate two technologies for the placement of coal combustion residues in abandoned underground coal mines, and will assess the environmental impact of these technologies for the management of coal combustion by-products. The two technologies for the underground placement that will be developed and demonstrated are: (1) pneumatic placement, using virtually dry materials, and (2) hydraulic placement, using a {open_quotes}paste{close_quotes} mixture of materials with about 70% solids. Phase II of the overall program began April 1, 1996. The principal objective of Phase II is to develop and fabricate the equipment for placing the coal combustion by-products underground, and to conduct a demonstration of the technologies on the surface. Therefore, this quarter has been largely devoted to developing specifications for equipment components, visiting fabrication plants throughout Southern Illinois to determine their capability for building the equipment components in compliance with the specifications, and delivering the components in a timely manner.

NONE

1997-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "byproducts aromatic extracts" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Sorption characteristics of polycyclic aromatic hydrocarbons in aluminum smelter residues  

SciTech Connect

High temperature carbon oxidation in primary aluminum smelters results in the release of polycyclic aromatic hydrocarbons (PAH) into the environment. The main source of PAH are the anodes, which are composed of petroleum coke (black carbon, BC) and coal tar pitch. To elucidate the dominant carbonaceous phase controlling the environmental fate of PAH in aluminum smelter residues (coke BC and/or coal tar), the sorptive behavior of PAHs has been determined, using passive samplers and infinite-sink desorption methods. Samples directly from the wet scrubber were studied as well as ones from an adjacent 20-year old storage lagoon and roof dust from the smelter. Carbon-normalized distribution coefficients of native PAHs were 2 orders of magnitude higher than expected based on amorphous organic carbon (AOC)/water partitioning, which is in the same order of magnitude as reported literature values for soots and charcoals. Sorption isotherms of laboratory-spiked deuterated phenanthrene showed strong (about 100 times stronger than AOC) but nonetheless linear sorption in both fresh and aged aluminum smelter residues. The absence of nonlinear behavior typical for adsorption to BC indicates that PAH sorption in aluminum smelter residues is dominated by absorption into the semi-solid coal tar pitch matrix. Desorption experiments using Tenax showed that fresh smelter residues had a relatively large rapidly desorbing fraction of PAH (35-50%), whereas this fraction was strongly reduced (11-16%) in the lagoon and roof dust material. Weathering of the coal tar residue and/or redistribution of PAH between coal tar and BC phases could explain the reduced availability in aged samples. 38 refs., 5 figs., 1 tab.

Gijs D. Breedveld; Emilien Pelletier; Richard St. Louis; Gerard Cornelissen [Norwegian Geotechnical Institute, Oslo (Norway)

2007-04-01T23:59:59.000Z

282

Kinetics and mechanisms of reactions involving small aromatic reactive intermediates  

SciTech Connect

Small aromatic radicals such as C{sub 6}H{sub 5}, C{sub 6}H{sub 5}O and C{sub 6}H{sub 4} are key prototype species of their homologs. C{sub 6}H{sub 5} and its oxidation product, C{sub 6}H{sub 5}O are believed to be important intermediates which play a pivotal role in hydrocarbon combustion, particularly with regard to soot formation. Despite their fundamental importance, experimental data on the reaction mechanisms and reactivities of these species are very limited. For C{sub 6}H{sub 5}, most kinetic data except its reactions with NO and NO{sub 2}, were obtained by relative rate measurements. For C{sub 6}H{sub 5}O, the authors have earlier measured its fragmentation reaction producing C{sub 5}H{sub 5} + CO in shock waves. For C{sub 6}H{sub 4}, the only rate constant measured in the gas phase is its recombination rate at room temperature. The authors have proposed to investigate systematically the kinetics and mechanisms of this important class of molecules using two parallel laser diagnostic techniques--laser resonance absorption (LRA) and resonance enhanced multiphoton ionization mass spectrometry (REMPI/MS). In the past two years, study has been focused on the development of a new multipass adsorption technique--the {open_quotes}cavity-ring-down{close_quotes} technique for kinetic applications. The preliminary results of this study appear to be quite good and the sensitivity of the technique is at least comparable to that of the laser-induced fluorescence method.

Lin, M.C. [Emory Univ., Atlanta, GA (United States)

1993-12-01T23:59:59.000Z

283

Utilizing Bioenergy By-products in Beef Production Systems The newly expanded renewable fuels standard requires 36 billion gallons of renewable  

E-Print Network (OSTI)

Utilizing Bioenergy By-products in Beef Production Systems The newly expanded renewable fuels studies. Current research focuses on impacts of feeding by-prod- ucts of the bioenergy industry on Animal

284

Dekker PMIS Extraction Utility  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

0907. The Extraction Utility is used for retrieving project 0907. The Extraction Utility is used for retrieving project management data from a variety of source systems for upload into Dekker PMIS(tm) (Dekker iPursuit®, Dekker iProgram(tm), or DOE PARSII). This release incorporates a number of new features and updates focused to improve existing functionality. The quality of each Dekker PMIS(tm) Extraction Utility release is a primary consideration at Dekker, Ltd. Since every customer environment is unique, Dekker strongly recommends that each implementation validate any software update prior to its release into the production environment. Dekker continually strives to enhance the features and capabilities of the Dekker PMIS(tm) Extraction Utility. We are very excited about this update and look forward to its implementation in your

285

Dekker PMIS Extraction Utility  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

1217. The Extraction Utility is used for retrieving project 1217. The Extraction Utility is used for retrieving project management data from a variety of source systems for upload into the Dekker PMIS(tm) (Dekker iPursuit®, Dekker iProgram(tm), or DOE PARSII). This release incorporates a number of new features and updates primarily focused to improve the existing functionality. The quality of each Dekker PMIS(tm) Extraction Utility release is a primary consideration at Dekker, Ltd. Since every customer environment is unique, Dekker strongly recommends that each implementation site validate all software updates prior to release into the production environment. Dekker continually strives to enhance the features and capabilities of the Dekker PMIS(tm) Extraction Utility. We are very excited about this update and look forward to its implementation in your

286

Liquid chromatographic extraction medium  

DOE Patents (OSTI)

A method and apparatus are disclosed for extracting strontium and technetium values from biological, industrial and environmental sample solutions using a chromatographic column. An extractant medium for the column is prepared by generating a solution of a diluent containing a Crown ether and dispersing the solution on a resin substrate material. The sample solution is highly acidic and is introduced directed to the chromatographic column and strontium or technetium is eluted using deionized water. 1 fig.

Horwitz, E.P.; Dietz, M.L.

1994-09-13T23:59:59.000Z

287

Liquid chromatographic extraction medium  

DOE Patents (OSTI)

A method and apparatus for extracting strontium and technetium values from biological, industrial and environmental sample solutions using a chromatographic column is described. An extractant medium for the column is prepared by generating a solution of a diluent containing a Crown ether and dispersing the solution on a resin substrate material. The sample solution is highly acidic and is introduced directed to the chromatographic column and strontium or technetium is eluted using deionized water.

Horwitz, E. Philip (Naperville, IL); Dietz, Mark L. (Evanston, IL)

1994-01-01T23:59:59.000Z

288

New perspectives on the cancer risks of trichloroethylene, its metabolites, and chlorination by-products  

SciTech Connect

Scientific developments in the 1990`s have important implications for the assessment of cancer risks posed by exposures to trichloroethylene (TCE). These new developments include: epidemiological studies; experimental studies of TCE carcinogenicity, metabolism and metabolite carcinogenicity; applications of new physiologically based pharmacokinetic (PBPK) models for TCE; and new pharmacodynamic data obtained for TCE and its rhetabolites. Following a review of previous assessments of TCE carcinogenicity, each of these new sets of developments is summarized. The new epidemiological data do not provide evidence of TCE carcinogenicity in humans, and the new pharmacodynamic data support the hypothesis that TCE carcinogenicity is caused by TCE-induced cytotoxicity. Based on this information, PBPK-based estimates for likely no-adverse effect levels (NOAELs) for human exposures to TCE are calculated to be 16 ppb for TCE in air respired 24 hr/day, and 210 ppb for TCE in drinking water. Cancer risks of zero are predicted for TCE exposures below these calculated NOAELs. For comparison, hypothetical cancer risks posed by lifetime ingestive and multiroute household exposures to TCE in drinking water, at the currently enforced Maximum Contaminant Level (MCL) concentration of 5 ppb are extrapolated from animal bioassay data using a conservative, linear dose-response model. These TCE-related risks are compared to corresponding ones associated with concentrations of chlorination by-products (CBP) in household water. It is shown that, from the standpoint of comparative hypothetical cancer risks, based on conservative linear dose-response extrapolations, there would likely be no health benefit, and more likely a possible health detriment, associated with any switch from a household water supply containing <375 ppb TCE to one containing CBP at levels corresponding to the currently proposed 80-ppb MCL for total trihalomethanes.

Bogen, K.T. [Lawrence Livermore National Lab., CA (United States); Slone, T.; Gold, L.S.; Manley, N.; Revzan, K. [Lawrence Berkeley Lab., CA (United States)

1994-12-08T23:59:59.000Z

289

Distribution of polycyclic aromatic hydrocarbons in fly ash during coal and residual char combustion in a pressurized fluidized bed  

SciTech Connect

To investigate the distribution of polycyclic aromatic hydrocarbons (PAHs) in fly ash, the combustion of coal and residual char was performed in a pressurized spouted fluidized bed. After Soxhlet extraction and Kuderna-Danish (K-D) concentration, the contents of 16 PAHs recommended by the United States Environmental Protection Agency (U.S. EPA) in coal, residual char, and fly ash were analyzed by a high-performance liquid chromatography (HPLC) coupled with fluorescence and diode array detection. The experimental results show that the combustion efficiency is lower and the carbon content in fly ash is higher during coal pressurized combustion, compared to the residual char pressurized combustion at the pressure of 0.3 MPa. Under the same pressure, the PAH amounts in fly ash produced from residual char combustion are lower than that in fly ash produced from coal combustion. The total PAHs in fly ash produced from coal and residual char combustion are dominated by three- and four-ring PAHs. The amounts of PAHs in fly ash produced from residual char combustion increase and then decrease with the increase of pressure in a fluidized bed. 21 refs., 1 fig., 4 tabs.

Hongcang Zhou; Baosheng Jin; Rui Xiao; Zhaoping Zhong; Yaji Huang [Nanjing University of Information Science and Technology, Nanjing (China)

2009-04-15T23:59:59.000Z

290

Chemical and morphological characterization of soot and soot precursors generated in an inverse diffusion flame with aromatic and aliphatic fuels  

SciTech Connect

Knowledge of the chemical and physical structure of young soot and its precursors is very useful in understanding the paths leading to soot particle inception. This paper presents chemical and morphological characterization of the products generated in ethylene and benzene inverse diffusion flames (IDF) using different analytical techniques. The trend in the data indicates that the soot precursor material and soot particles generated in the benzene IDF have a higher degree of complexity than the samples obtained in the ethylene IDF, which is reflected by an increase in the aromaticity of the chloroform extracts observed by {sup 1}H NMR and FT-IR, and shape and size of soot particles obtained by TEM and HR-TEM. It is important to highlight that the soot precursor material obtained at the lower positions in the ethylene IDF has a significant contribution of aliphatic groups, which play an important role in the particle inception and mass growth processes during the early stages of soot formation. However, these groups progressively disappear in the samples taken at higher positions in the flame, due to thermal decomposition processes. (author)

Santamaria, Alexander; Mondragon, Fanor [Institute of Chemistry, University of Antioquia, AA 1226, Medellin (Colombia); Yang, Nancy [Sandia National Laboratories, Livermore, CA 94551-0969 (United States); Eddings, Eric [Department of Chemical Engineering, University of Utah, Salt Sake City, UT 84112 (United States)

2010-01-15T23:59:59.000Z

291

Evaluation of pitches and cokes from solvent-extracted coal materials  

SciTech Connect

Three initial coal-extracted (C-E) samples were received from the West Virginia University (WVU) Chemical Engineering Department. Two samples had been hydrogenated to obtain pitches that satisfy Theological requirements. One of the hydrogenated (HC-E) samples had been extracted by toluene to remove ash and higher molecular weight aromatic compounds. We were unable to measure the softening point and viscosity of the non-hydro treated solid extract sample, Positive characteristics in the HC-E materials were softening points of 113-119{degrees}C, low sulfur and ash. The oxygen and nitrogen content of the HC-E samples may limit future usage in premium carbon and graphite products. Coking values were similar to petroleum pitches. Laboratory anode testing indicates that in combination with standard coal-tar pitch, the HC-E material can be used as a binder pitch.

McHenry, E.R.

1996-12-01T23:59:59.000Z

292

Modern approaches to the analysis of disinfection by-products in drinking water  

Science Journals Connector (OSTI)

...with organic nitrogen in the pool...in drinking water with ozone...inherent aqueous solubility of many of...organic-nitrogen precursors...Annual Conf. (Water Quality...capillary column gas chromatography...inherent aqueous solubility of many of...extraction from water difficult...Monitoring methods Gas Chromatography-Mass...

2009-01-01T23:59:59.000Z

293

Solvent extraction studies of holmium with acidic extractants  

SciTech Connect

Liquid-liquid extraction studies of holmium with 2-ethylhexyl phosphoric acid mono-2-ethylhexyl ester, naphthenic, and Versatic 10 acids have been carried out. The nature of the extracted species and the extraction equilibrium constants of these systems have been determined from aqueous nitrate solution. The extraction mechanism and complexation models have been proposed. 11 refs., 8 figs.

Gaikwad, A.G.; Damodaran, A.D. (CSIR, Trivandrum (India))

1993-03-01T23:59:59.000Z

294

Partitioning of Crude Oil Polycyclic Aromatic Hydrocarbons in Aquatic Systems  

Science Journals Connector (OSTI)

Environmental and Water Resources Division, Civil Engineering Department, Texas A&M University, College Station, Texas 77843-3136, Conrad Blucher Institute for Surveying and Science, Texas A&M UniversityCorpus Christi, 6300 Ocean Drive, Corpus Christi, Texas 78412, and Environmental Engineering Department, Texas A&M UniversityKingsville, Kingsville, Texas 78363 ... In natural water systems, entrainment and mixing result primarily from wind and current stresses. ... For compound analysis, a 1-?L aliquot of the extracted sample was injected into a Hewlett-Packard 5890 Series II gas chromatograph (GC) interfaced to a Hewlett-Packard 5972 mass selective (MS) detector and operated using Hewlett-Packard MS Chemstation software. ...

Michael C. Sterling, Jr.; James S. Bonner; Cheryl A. Page; Christopher B. Fuller; Andrew N. S. Ernest; Robin L. Autenrieth

2003-09-06T23:59:59.000Z

295

DNA Damage from Polycyclic Aromatic Hydrocarbons Measured by Benzo[a]pyrene-DNA Adducts in Mothers and Newborns from Northern Manhattan, The World Trade Center Area, Poland, and China  

Science Journals Connector (OSTI)

...exposure to polycyclic aromatic hydrocarbons may disproportionately increase...adducts|polycyclic aromatic hydrocarbons|cancer|susceptibility...Introduction Polycyclic aromatic hydrocarbons (PAH) are common environmental...air, food, and drinking water from incomplete combustion...

Frederica Perera; Deliang Tang; Robin Whyatt; Sally Ann Lederman; and Wieslaw Jedrychowski

2005-03-01T23:59:59.000Z

296

Determination of aromatics and naphthenes in straight run gasoline by 1H NMR spectroscopy. Part I  

Science Journals Connector (OSTI)

A 1H NMR-based method has been developed for determining the composition (aromatics, naphthenes and paraffins) of straight run gasoline fractions. The equations required for the calculations have been derived based on the assignment of the overlapped 1H NMR spectra of the samples with particular emphasis on signals from naphthenes and iso-paraffins. The 1H NMR results have been compared with those obtained from GC method. The absolute standard deviations between the NMR and GC methods are1.7 and 2.1% for total aromatics and naphthenes, respectively.

G.S. Kapur; A.P. Singh; A.S. Sarpal

2000-01-01T23:59:59.000Z

297

Le Bail Intensity Extraction  

NLE Websites -- All DOE Office Websites (Extended Search)

Le Bail Intensity Extraction Le Bail Intensity Extraction Presentation Goal Introduce the concepts behind LeBail fitting; why it is useful and how to perform a Le Bail fit with GSAS. Format: PDF slides or a RealPlayer video of the slides with accompanying audio and a demo video that shows how a Le Bail fit is performed. Presentation Outline What is the Le Bail method? Other approaches Why use the Le Bail method? Parameter fitting with Le Bail intensity extraction Le Bail refinement strategies Avoiding problems with background fitting: BKGEDIT Demo: an example Le Bail fit Links Le Bail lecture Slides (as PDF file) FlashMovie presentation with index (best viewed with 1024x768 or better screen resolution) FlashMovie file (800x600 pixels) Le Bail demo FlashMovie presentation with index (best viewed with 1024x768 or

298

Extracting the Eliashberg Function  

NLE Websites -- All DOE Office Websites (Extended Search)

Extracting the Eliashberg Extracting the Eliashberg Function Extracting the Eliashberg Function Print Wednesday, 23 February 2005 00:00 A multitude of important chemical, physical, and biological phenomena are driven by violations of the Born-Oppenheimer approximation (BOA), which decouples electronic from nuclear motion in quantum calculations of solids. Recent advances in experimental techniques combined with ever-growing theoretical capabilities now hold the promise of presenting an unprecedented picture of these violations. By means of high-resolution angle-resolved photoemission at the ALS and theoretical calculations, a multi-institutional collaboration that includes researchers from Oak Ridge National Laboratory, the University of Tennessee, Stanford University, and the ALS has obtained the first high-resolution spectroscopic images of the specific vibrational modes that couple to a given electronic state.

299

Activated carbon and biochar amendments decrease pore-water concentrations of polycyclic aromatic hydrocarbons (PAHs) in sewage sludge  

E-Print Network (OSTI)

hydrocarbons (PAHs) in sewage sludge Patryk Oleszczuk a,b, , Sarah E. Hale a , Johannes Lehmann c , Gerard Polycyclic aromatic hydrocarbons Bioavailability Sewage sludge a b s t r a c t The aim of the research of polycyclic aromatic hydrocarbons (PAHs) in sewage sludge. Two different biochars (MSB and PMW) and two ACs

Lehmann, Johannes

300

Path Analysis of Biomarkers of Exposure and Early Biological Effects among Coke-Oven Workers Exposed to Polycyclic Aromatic Hydrocarbons  

Science Journals Connector (OSTI)

...8-diol of benzo(a)pyrene to more water-soluble trans-dihydrodiols, which...workers exposed to polycyclic aromatic hydrocarbons in engine repair workshops. Mutat Res...determination of exposure to polycyclic aromatic hydrocarbons. Int Arch Occup Environ Health 2002...

Li Qiu; Shuguang Leng; Zhongxu Wang; Yufei Dai; Yuxin Zheng; and Zengzhen Wang

2007-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "byproducts aromatic extracts" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

ADVANCED BYPRODUCT RECOVERY: DIRECT CATALYTIC REDUCTION OF SO2 TO ELEMENTAL SULFUR  

SciTech Connect

Arthur D. Little, Inc., together with its commercialization partner, Engelhard Corporation, and its university partner Tufts, investigated a single-step process for direct, catalytic reduction of sulfur dioxide from regenerable flue gas desulfurization processes to the more valuable elemental sulfur by-product. This development built on recently demonstrated SO{sub 2}-reduction catalyst performance at Tufts University on a DOE-sponsored program and is, in principle, applicable to processing of regenerator off-gases from all regenerable SO{sub 2}-control processes. In this program, laboratory-scale catalyst optimization work at Tufts was combined with supported catalyst formulation work at Engelhard, bench-scale supported catalyst testing at Arthur D. Little and market assessments, also by Arthur D. Little. Objectives included identification and performance evaluation of a catalyst which is robust and flexible with regard to choice of reducing gas. The catalyst formulation was improved significantly over the course of this work owing to the identification of a number of underlying phenomena that tended to reduce catalyst selectivity. The most promising catalysts discovered in the bench-scale tests at Tufts were transformed into monolith-supported catalysts at Engelhard. These catalyst samples were tested at larger scale at Arthur D. Little, where the laboratory-scale results were confirmed, namely that the catalysts do effectively reduce sulfur dioxide to elemental sulfur when operated under appropriate levels of conversion and in conditions that do not contain too much water or hydrogen. Ways to overcome those limitations were suggested by the laboratory results. Nonetheless, at the end of Phase I, the catalysts did not exhibit the very stringent levels of activity or selectivity that would have permitted ready scale-up to pilot or commercial operation. Therefore, we chose not to pursue Phase II of this work which would have included further bench-scale testing, scale-up, pilot-scale (0.5 MW{sub e}) testing at conditions representative of various regenerable SO{sub 2}-control systems, preparation of a commercial process design, and development of a utility-scale demonstration plan.

Robert S. Weber

1999-05-01T23:59:59.000Z

302

Mercury and Air Toxic Element Impacts of Coal Combustion By-Product Disposal and Utilizaton  

SciTech Connect

The University of North Dakota Energy & Environmental Research Center (EERC) conducted a multiyear study to evaluate the impact of mercury and other air toxic elements (ATEs) on the management of coal combustion by-products (CCBs). The ATEs evaluated in this project were arsenic, cadmium, chromium, lead, nickel, and selenium. The study included laboratory tasks to develop measurement techniques for mercury and ATE releases, sample characterization, and release experiments. A field task was also performed to measure mercury releases at a field site. Samples of fly ash and flue gas desulfurization (FGD) materials were collected preferentially from full-scale coal-fired power plants operating both without and with mercury control technologies in place. In some cases, samples from pilot- and bench-scale emission control tests were included in the laboratory studies. Several sets of 'paired' baseline and test fly ash and FGD materials collected during full-scale mercury emission control tests were also included in laboratory evaluations. Samples from mercury emission control tests all contained activated carbon (AC) and some also incorporated a sorbent-enhancing agent (EA). Laboratory release experiments focused on measuring releases of mercury under conditions designed to simulate CCB exposure to water, ambient-temperature air, elevated temperatures, and microbes in both wet and dry conditions. Results of laboratory evaluations indicated that: (1) Mercury and sometimes selenium are collected with AC used for mercury emission control and, therefore, present at higher concentrations than samples collected without mercury emission controls present. (2) Mercury is stable on CCBs collected from systems both without and with mercury emission controls present under most conditions tested, with the exception of vapor-phase releases of mercury exposed to elevated temperatures. (3) The presence of carbon either from added AC or from unburned coal can result in mercury being sorbed onto the CCB when exposed to ambient-temperature air. The environmental performance of the mercury captured on AC used as a sorbent for mercury emission control technologies indicated that current CCB management options will continue to be sufficiently protective of the environment, with the potential exception of exposure to elevated temperatures. The environmental performance of the other ATEs investigated indicated that current management options will be appropriate to the CCBs produced using AC in mercury emission controls.

David Hassett; Loreal Heebink; Debra Pflughoeft-Hassett; Tera Buckley; Erick Zacher; Mei Xin; Mae Sexauer Gustin; Rob Jung

2007-03-31T23:59:59.000Z

303

Prediction of the digestible and metabolizable energy content of wheat milling by-products for growing pigs from chemical composition  

Science Journals Connector (OSTI)

Abstract Thirty samples of wheat milling by-products (wheat bran, wheat middlings, wheat shorts, wheat red dog, wheat feed flour), collected from 11 flour mills, were fed to growing pigs to determine their digestible energy (DE) and metabolizable energy (ME) content and to establish equations for predicting their DE and ME content based on chemical analysis. The basal diet was based on corn and soybean meal while the other 30 experimental diets contained 290.4 g/kg wheat milling by-products added at the expense of corn and soybean meal. The 31 diets were fed to 96 growing pigs (BW = 61.9 ± 3.2 kg) according to a completely randomized design during two successive periods. During each period, the 30 experimental diets were fed to three pigs and the basal diet was fed to six pigs, resulting in 6 replications per experimental diet and 12 replications for the basal diet over the two periods. The chemical composition of the 30 samples was variable, and starch and fiber content had a strong negative correlation (r = ?0.96 to ?0.99 for CF and ADF, respectively). The DE content of wheat feed flour, wheat red dog, wheat shorts, wheat middlings and wheat bran averaged 17.4, 16.9, 15.2, 12.5 and 12.0 MJ/kg DM, respectively. From the stepwise regression analysis, a series of DE and ME prediction equations were generated. The best fit equations for wheat milling by-products were: DE (MJ/kg DM) = 19.2 ? (0.016×aNDF) with R2 = 0.94, RSD = 0.58 and Pcontent varied substantially and various correlated single predictors (aNDF, ash, CF, starch, etc.) can be used to accurately predict the DE and ME content when fed to growing pigs.

Q. Huang; C.X. Shi; Y.B. Su; Z.Y. Liu; D.F. Li; L. Liu; C.F. Huang; X.S. Piao; C.H. Lai

2014-01-01T23:59:59.000Z

304

DOE/EA-1498: Advanced Coal Utilization Byproduct Beneficiation Processing Plant Ghent Power Station, Carroll County, Kentucky (01/05)  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

EA-1498 EA-1498 Advanced Coal Utilization Byproduct Beneficiation Processing Plant Ghent Power Station, Carroll County, Kentucky Final Environmental Assessment January 2005 Note: No comments were received during the public comment period from September 25 to October 25, 2004. Therefore, no changes to the Draft Environmental Assessment were necessary. National Environmental Policy Act (NEPA) Compliance Cover Sheet Proposed Action: The proposed Federal action is to provide funding, through a cooperative agreement with the University of Kentucky Research Foundation (UKRF), Center for Applied Energy Research (CAER), for the design, construction, and operation of an advanced coal ash beneficiation processing plant at Kentucky Utilities (KU) Ghent Power Station in Carroll County, Kentucky.

305

A Second Generation Biofuel from Cellulosic Agricultural By-product Fermentation Using Clostridium Species for Electricity Generation  

Science Journals Connector (OSTI)

Abstract The production of second generation biofuel is essential for limiting food versus fuel competition. Butanol is one of the important biofuel for the future. Agricultural by-products namely bagasse and potato peel were hydrolyzed to produce readily fermented sugar for butanol fermentation. The butanol concentration was 1 – 2 g/l. To test the electricity generation, a customized generator was used for butanol combustion. The electricity produced was up to 1300 watts. Further improvements are needed in the hydrolysis method, medium composition, and generator design. This research has demonstrated that bagasse and potato peel are potential feedstock for producing butanol for generating electricity

Yalun Arifin; Ellen Tanudjaja; Arbi Dimyati; Reinhard Pinontoan

2014-01-01T23:59:59.000Z

306

Extracting Correlations Yuval Ishai #  

E-Print Network (OSTI)

, an equipment grant from Intel, and an Okawa Research award. Keywords­randomness extractors secure computationExtracting Correlations Yuval Ishai # Computer Science Dept. Technion and UCLA yuvali@cs.technion.ac.il Eyal Kushilevitz + Computer Science Dept. Technion and UCLA eyalk@cs.technion.ac.il Rafail Ostrovsky

Ostrovsky, Rafail

307

Extracting Correlations Yuval Ishai  

E-Print Network (OSTI)

, an equipment grant from Intel, and an Okawa Research award. Keywords-randomness extractors; secure computationExtracting Correlations Yuval Ishai Computer Science Dept. Technion and UCLA yuvali@cs.technion.ac.il Eyal Kushilevitz Computer Science Dept. Technion and UCLA eyalk@cs.technion.ac.il Rafail Ostrovsky CS

Sahai, Amit

308

Analysis of Polycyclic Aromatic Hydrocarbons in the Particulate Phase of Cigarette Smoke Using a Gas Chromatographic-High-Resolution Mass Spectrometric Technique  

Science Journals Connector (OSTI)

......polycyclic aromatic hydrocarbons (PAHs) from...previously reported data. Introduction Polycyclic aromatic hydrocarbons (PAHs) are present in the combustion products of many...reported literature data (9,11...polycyclic aromatic hydrocarbons in tobacco smoke...cigarette which heats but not burn......

Q. Zha; N.X. Qian; S.C. Moldoveanu

2002-08-01T23:59:59.000Z

309

Hydrolysis of aromatic ?-glucosides by non-pathogenic bacteria confers a chemical weapon against predators  

Science Journals Connector (OSTI)

...research-article Research articles 1001 200 70 60 Hydrolysis of aromatic beta-glucosides by non-pathogenic bacteria confers a chemical weapon against predators Robert Sonowal 1 Krithi Nandimath 1 Sucheta S. Kulkarni 2 Sandhya P. Koushika 2 3 Vidyanand Nanjundiah 1...

2013-01-01T23:59:59.000Z

310

Can Metallapyrimidines Be Aromatic? A Computational Study into a New Class of Metallacycles  

E-Print Network (OSTI)

density functional theory. Nucleus independent chemical shifts (NICS) placed above the ring (NICS(1)zz are a cornerstone of electronic structure theory. Aromaticity is so fundamental that introductory chemistry books that fascinates experimental and theoretical chemists alike.2 The bonding theories developed to explain benzene

Schlegel, H. Bernhard

311

A new carbon-13 method for determining aromatic, naphthenic and paraffinic carbon  

SciTech Connect

The determination of the relative percentages of aromatic, naphthenic and paraffinic carbon in samples of natural origin is important for many petroleum related studies including processing, geological studies, and certain product specifications. The normal method is the n-d-M method which requires the measurement of refractive index, density and molecular weight and a ternary correlation diagram to obtain the relative carbon percentages. It is difficult or inconvenient to make n-d-M measurements of very heavy products and the presence of significant amounts of polar materials makes n-d-M results inaccurate. The average molecular parameters determinable by a number of NMR techniques are directly or indirectly related to the percentage of various carbon types present in the mixture. Unfortunately, all the standard techniques we have examined have some built-in assumption which does not allow the accurate calculation of relative carbon percentages. For example, any proton technique applicable to aromatic fractions will give potentially low values for naphthenic carbon because naphthenic carbon is normally determined from the ..beta..-CH/sub 2/ region of tetralin-type structures (1.65-1.9 ppm). This is a very specific kind of naphthenic structure and to the extent that more than one saturate ring is asymmetrically condensed to the aromatic ring or that the saturate rings are not directly condensed to the aromatic rings, the method will fail.

Galya, L.G.; Young, D.C.

1983-09-01T23:59:59.000Z

312

Oil sands development contributes polycyclic aromatic compounds to the Athabasca River and its tributaries  

Science Journals Connector (OSTI)

...upgraded by using heat, pressure...polycyclic aromatic hydrocarbons+ dibenzothiophene...volatile and combustion-derived PAC [i...volatilized by heat or particulates produced by combustion. The dominance...perdeuterated hydrocarbon surrogate standards...and stored in heat-sealed Ziploc...

Erin N. Kelly; Jeffrey W. Short; David W. Schindler; Peter V. Hodson; Mingsheng Ma; Alvin K. Kwan; Barbra L. Fortin

2009-01-01T23:59:59.000Z

313

Role of dissolution rate and solubility in biodegradation of aromatic compounds.  

Science Journals Connector (OSTI)

...transfer rates and solubility. The rates of mass...were determined by gas chromatography...immediately in a water bath set at 29 C...radioactivity. For gas chromatographic analyses...respectively. The nitrogen flow was maintained...minations each time. The solubility of the aromatic compounds...

G Stucki; M Alexander

1987-02-01T23:59:59.000Z

314

Identification of Sediment Organic Carbon Location and Association with Polycyclic Aromatic Hydrocarbons (PAHs) in Contaminated Sediment  

E-Print Network (OSTI)

Identification of Sediment Organic Carbon Location and Association with Polycyclic Aromatic Hydrocarbons (PAHs) in Contaminated Sediment Upal Ghosh1 , Richard G. Luthy1 , J. Seb Gillette2 , and Richard N long-term issue confronting sediment bioremediation is the lack of understanding of contaminant-sediment

315

Aromatization of propane: Techno-economic analysis by multiscale “kinetics-to-process” simulation  

Science Journals Connector (OSTI)

Abstract This paper addresses the techno-economic analysis of the propane aromatization process, by adopting a novel kinetics-to-process approach. The recent interest in this technological route derives from the development of new third generation biorefinery concepts, in which, algal oil is subjected to catalytic hydrodeoxygenation processes for the production of (Hydrotreated Renewable Jet) HRJ fuels. Beside biofuels, co-production of large amounts of propane is observed, which can be upgraded by a catalytic conversion to aromatics on zeolites. Kinetic studies of propane aromatization over H-ZSM-5 zeolite in a wide range of conversions are reported in the literature. Based on these results, a general kinetic model of propane aromatization has been developed. The revised kinetic scheme is then embedded in a process simulation, performed with the commercial code SimSci PRO/II by Schneider Electric. Basing on the process simulation and on available price assessments, a techno-economic analysis has been performed to show limits as well as potentialities of the proposed layout.

Michele Corbetta; Flavio Manenti; Carlo Pirola; Mark V. Tsodikov; Andrey V. Chistyakov

2014-01-01T23:59:59.000Z

316

Removal of polycyclic aromatic hydrocarbons (PAHs) from sewage sludge by anaerobic degradation  

E-Print Network (OSTI)

for treatment in EU, followed by spreading on land, which accounted for 37% of the sewage sludge produced allow recycling of nutrients. Hence, bioprocessed sewage sludge application on agricultural soilRemoval of polycyclic aromatic hydrocarbons (PAHs) from sewage sludge by anaerobic degradation N

317

Oil sands development contributes polycyclic aromatic compounds to the Athabasca River and its tributaries  

Science Journals Connector (OSTI)

...and viscous hydrocarbon, that is recovered...upgraded by using heat, pressure...12). RAMP data are not publicly...polycyclic aromatic hydrocarbons+ dibenzothiophene...volatile and combustion-derived PAC...and geologic data, and calculate...perdeuterated hydrocarbon surrogate standards...and stored in heat-sealed Ziploc...

Erin N. Kelly; Jeffrey W. Short; David W. Schindler; Peter V. Hodson; Mingsheng Ma; Alvin K. Kwan; Barbra L. Fortin

2009-01-01T23:59:59.000Z

318

Aromatic hydrocarbon metabolism by Rhodococcus sp. I24 : computational, biochemical and transcriptional analysis  

E-Print Network (OSTI)

Rhodococcus sp. 124 is a Gram-positive soil bacterium being developed for the manufacture of (-)cis-(1S,2R)-1-aminoindan-2-ol, a key precursor in the production of the HIV-1 protease inhibitor CrixivanTM, from the aromatic ...

Parker, Jefferson A. (Jefferson Alexander), 1974-

2004-01-01T23:59:59.000Z

319

J. Mol. Biol. (1988) 201, 751-754 Aromatic Rings Act as Hydrogen  

E-Print Network (OSTI)

J. Mol. Biol. (1988) 201, 751-754 Aromatic Rings Act as Hydrogen Bond Acceptors Michael Levitt that there is a significant interaction between a hydrogen bond donor (like the > NH group) and the centre of a benzene ring, which acts as a hydrogen bond acceptor. This interaction, hvdrogen bond, which is about half as strong

Levitt, Michael

320

UV Resonance Raman Characterization of Polycyclic Aromatic Hydrocarbons in Coal Liquid Distillates*  

E-Print Network (OSTI)

UV Resonance Raman Characterization of Polycyclic Aromatic Hydrocarbons in Coal Liquid Distillates samples, such as petroleum and coal, or for man-made samples, such as coal liquids, a major desire- nique for studying coal-liquid samples. 1-4 We demon- strated that the Raman spectra of polycyclic

Asher, Sanford A.

Note: This page contains sample records for the topic "byproducts aromatic extracts" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Environmental Research 105 (2007) 101118 Polycyclic aromatic hydrocarbon (PAH) contamination in  

E-Print Network (OSTI)

(6.8 million, US Census Bureau, 2000) and urbanized region and is subject to polycyclic aromatic congestion in the US (TTI, 2003). The Bay receives freshwater inflow primarily from the Delta.10.007 Ă?Corresponding author. Fax: +1 510 746 7300. E-mail address: john@sfei.org (J.R.M. Ross). #12;wastewater

322

Magnetic birefringence in mixtures of a nematic aromatic polyester and PAA  

E-Print Network (OSTI)

L-329 Magnetic birefringence in mixtures of a nematic aromatic polyester and PAA J. M. Gilli, G'un cristal liquide de petites molécules (PAA) et d'un polymère nématique. La constante de Cotton-Mouton (CM birefringence was measured in a mixture of a small molecule liquid crystal (PAA) and a nematic polymer

Boyer, Edmond

323

X-ray scattering study of the average polycyclic aromatic unit in Ledo coal  

Science Journals Connector (OSTI)

Through an X-ray scattering analysis, the short-range structural features, the relationship(s) between the aryl/alkyl carbon ratio, and the size of the average polycyclic aromatic unit in Ledo coal from Makum coalfield, Assam, India, are elucidated.

Boruah, R.K.

2008-01-16T23:59:59.000Z

324

Nitrated and oxygenated derivatives of polycyclic aromatic hydrocarbons in the ambient air of two  

E-Print Network (OSTI)

polycyclic aromatic hydrocarbons; Size distribution; Atmospheric pollution; POVA (POllution des Vallées, published in "Atmospheric Environment 42, 173 (2008) 55 à 64" DOI : 10.1016/j.atmosenv.2007.10.008 #12 was determined during the intensive sampling campaigns of the POVA (POllution des Vallées Alpines) research

Boyer, Edmond

325

FORMATION OF CARBON-CARBON BONDS IN THE PHOTOCHEMICAL ALKYLATION OF POLYCYCLIC AROMATIC  

E-Print Network (OSTI)

HYDROCARBONS TANIA B. MAHAJAN1, JAMIE E. ELSILA1, DAVID W. DEAMER2 and RICHARD N. ZARE1 1 Department July 2002) Abstract. The reaction of polycyclic aromatic hydrocarbons (PAHs) with alkanes was examined films in contact with simulated ocean water, and in matrices simulating ISM conditions. Photoalkylation

Zare, Richard N.

326

Determination of Aromatic Acids and Nitrophenols in Atmospheric Aerosols by Capillary Electrophoresis  

Science Journals Connector (OSTI)

......one day containing 25 sample runs had an RSD of 2.6%), these...wavelength cell capillary Straight capillary Compound (nm...range of compounds in a single run. However, the advantages of...Seinfeld. Aromatics, reformulated gasoline, and atmo- spheric organic......

Jochen Rudolph; Jacek Stupak

2002-04-01T23:59:59.000Z

327

Extraction Utility Design Specification  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Extraction Extraction Utility Design Specification May 13, 2013 Document Version 1.10 1 Revision History Date Version Section and Titles Author Summary of Change January 15, 2010 1.0 All Eric Morgan, Dekker, Ltd. Initial Draft Document January 19, 2010 1.1 All Igor Pedan, Dekker, Ltd. Document update with EM team review notes January 20, 2010 1.2 2.1.1 EM Project Team Document Review January 27, 2010 1.3 All Bruce Bartells Final Draft Review May 10, 2010 1.4.1 2.8 Igor Pedan, Dekker, Ltd. Section Update May 14, 2010 1.4.2 2.3.1 Igor Pedan, Dekker, Ltd. System Tables Added May 17, 2010 1.4.3 2.3 Igor Pedan, Dekker, Ltd. Enhancements Update June 29, 2010 1.5 All Igor Pedan, Dekker, Ltd. Revised for Version

328

Extracting the Eliashberg Function  

NLE Websites -- All DOE Office Websites (Extended Search)

Extracting the Eliashberg Function Print Extracting the Eliashberg Function Print A multitude of important chemical, physical, and biological phenomena are driven by violations of the Born-Oppenheimer approximation (BOA), which decouples electronic from nuclear motion in quantum calculations of solids. Recent advances in experimental techniques combined with ever-growing theoretical capabilities now hold the promise of presenting an unprecedented picture of these violations. By means of high-resolution angle-resolved photoemission at the ALS and theoretical calculations, a multi-institutional collaboration that includes researchers from Oak Ridge National Laboratory, the University of Tennessee, Stanford University, and the ALS has obtained the first high-resolution spectroscopic images of the specific vibrational modes that couple to a given electronic state.

329

PRODUCTION OF CARBON PRODUCTS USING A COAL EXTRACTION PROCESS  

SciTech Connect

This Department of Energy National Energy Technology Laboratory sponsored project developed carbon products, using mildly hydrogenated solvents to extract the organic portion of coal to create synthetic pitches, cokes, carbon foam and carbon fibers. The focus of this effort was on development of lower cost solvents, milder hydrogenation conditions and improved yield in order to enable practical production of these products. This technology is needed because of the long-term decline in production of domestic feedstocks such as petroleum pitch and coal tar pitch. Currently, carbon products represents a market of roughly 5 million tons domestically, and 19 million tons worldwide. Carbon products are mainly derived from feedstocks such as petroleum pitch and coal tar pitch. The domestic supply of petroleum pitch is declining because of the rising price of liquid fuels, which has caused US refineries to maximize liquid fuel production. As a consequence, the long term trend has a decline in production of petroleum pitch over the past 20 years. The production of coal tar pitch, as in the case of petroleum pitch, has likewise declined significantly over the past two decades. Coal tar pitch is a byproduct of metallurgical grade coke (metcoke) production. In this industry, modern metcoke facilities are recycling coal tar as fuel in order to enhance energy efficiency and minimize environmental emissions. Metcoke production itself is dependent upon the production requirements for domestic steel. Hence, several metcoke ovens have been decommissioned over the past two decades and have not been replaced. As a consequence sources of coal tar are being taken off line and are not being replaced. The long-term trend is a reduction in coal tar pitch production. Thus import of feedstocks, mainly from Eastern Europe and China, is on the rise despite the relatively large transportation cost. To reverse this trend, a new process for producing carbon products is needed. The process must be economically competitive with current processes, and yet be environmentally friendly as well. The solvent extraction process developed uses mild hydrogenation of low cost oils to create powerful solvents that can dissolve the organic portion of coal. The insoluble portion, consisting mainly of mineral matter and fixed carbon, is removed via centrifugation or filtration, leaving a liquid solution of coal chemicals and solvent. This solution can be further refined via distillation to meet specifications for products such as synthetic pitches, cokes, carbon foam and fibers. The most economical process recycles 85% of the solvent, which itself is obtained as a low-cost byproduct from industrial processes such as coal tar or petroleum refining. Alternatively, processes have been developed that can recycle 100% of the solvent, avoiding any need for products derived from petroleum or coal tar.

Dady Dadyburjor; Philip R. Biedler; Chong Chen; L. Mitchell Clendenin; Manoj Katakdaunde; Elliot B. Kennel; Nathan D. King; Liviu Magean; Peter G. Stansberry; Alfred H. Stiller; John W. Zondlo

2004-08-31T23:59:59.000Z

330

Information extraction from broadcast news  

Science Journals Connector (OSTI)

...Royal Society and the British Academy Information extraction from broadcast news Yoshihiko...presented: the first represents name class information as a word attribute; the second represents...American broadcast news. Named entity|Information extraction|Language modelling| Information...

2000-01-01T23:59:59.000Z

331

DOE/NETL's R&D Response to Emerging Coal By-Product and Water Issues  

NLE Websites -- All DOE Office Websites (Extended Search)

R&D Response to Emerging R&D Response to Emerging Coal By-Product and Water Issues Clean Coal and Power Conference in conjunction with 2 nd Joint U.S.-People's Republic of China Conference on Clean Energy Washington, DC November 17-19, 2003 Thomas J. Feeley, III National Energy Technology Laboratory Feeley_CC&P Conf. 11/03 Electric Power Using Coal Clean Liquid Fuels Natural Gas Coal Production Environmental Control V21 Next Generation Carbon Sequestration Exploration & Production Refining & Delivery Alternative Fuels Exploration & Production Pipelines & Storage Fuel Cells Combustion Turbines NETL Plays Key Role in Fossil Energy Supply, Delivery, and Use Technologies Future Fuels Photo of hydrogen fueled car: Warren Gretz, NREL Feeley_CC&P Conf. 11/03 Innovations for Existing Plants Program

332

Modeling personal particle-bound polycyclic aromatic hydrocarbon (pb-pah) exposure in human subjects in Southern California  

E-Print Network (OSTI)

Health 2012, 11:47 http://www.ehjournal.net/content/11/1/47 Introduction Airborne polycyclic aromatic hydrocarbons (PAH) are produced from incomplete combustion of fossil fuels

Wu, Jun; Tjoa, Thomas; Li, Lianfa; Jaimes, Guillermo; Delfino, Ralph J

2012-01-01T23:59:59.000Z

333

Determination of Polycyclic Aromatic Hydrocarbons in Fresh Milk by Hollow Fiber Liquid-Phase Microextraction–Gas Chromatography Mass Spectrometry  

Science Journals Connector (OSTI)

......my 1 Department of Chemistry, Faculty of Science...Pharmaceutical and Medicinal Chemistry, National Research...products of the incomplete combustion of carbon-containing material, such as coal, oil or municipal waste...aromatic hydrocarbons: Chemistry and analysis. (2000......

Mohd Marsin Sanagi; Saw Hong Loh; Wan Aini Wan Ibrahim; Mohamed Noor Hasan; Hassan Y. Aboul Enein

2013-02-01T23:59:59.000Z

334

Screening and isolation of antibiotic resistance inhibitors from herb materials-resistance inhibition of volatile components of korean aromatic herbs  

Science Journals Connector (OSTI)

The resistance inhibitory activities of 54 odorant mixtures(essential oil) from 41 Korean aromatic herbs were tested against multi-drug resistantStaphylococcus aureus SA2, which has resistances to 10 usual antibi...

Chung Kyu Lee; Hyekyung Kim; Kyung Ho Moon; Kuk Hyun Shin

1998-02-01T23:59:59.000Z

335

Polycyclic aromatic hydrocarbons in the centralized wastewater treatment plant of a chemical industry zone: Removal, mass balance and source analysis  

Science Journals Connector (OSTI)

Increased attention has been given to the fate of pollutants such as polycyclic aromatic hydrocarbons (PAHs) introduced to the wastewater treatment plants. Dissolved and adsorbed PAHs were detected in the central...

Min Yao; XingWang Zhang; LeCheng Lei

2012-03-01T23:59:59.000Z

336

Long-Range Atmospheric Transport of Polycyclic Aromatic Hydrocarbons: A Global 3-D Model Analysis Including Evaluation of Arctic Sources  

E-Print Network (OSTI)

We use the global 3-D chemical transport model GEOS-Chem to simulate long-range atmospheric transport of polycyclic aromatic hydrocarbons (PAHs). To evaluate the model’s ability to simulate PAHs with different volatilities, ...

Friedman, Carey

337

Determination of Volatile Organic and Polycyclic Aromatic Hydrocarbons in Crude Oil with Efficient Gas-Chromatographic Methods  

Science Journals Connector (OSTI)

......in crude oil samples showed little change after 3 months of storage in glass bottles. Calibration for 2-methyl butane, n-pentane...determination HPLC for polycyclic aromatic hydrocarbons in seawater samples and its application to Japan Sea. Chemical Pharmaceutical......

Haijing Wang; Helmut Geppert; Thomas Fischer; Wolfgang Wieprecht; Detlev Möller

2014-09-01T23:59:59.000Z

338

Transport method for determining the association constants of complexes formed between aromatic hydrocarbons and?- and?-cyclodextrin in water  

Science Journals Connector (OSTI)

The association constants of 1 : 1 complexes formed in water between six aromatic hydrocarbons (o-,m-, andp-xylene, naphthalene, anthracene, and pyrene) and?- and?-cyclodextrin were determined by the transport me...

Bo-Long Poh; Yoke Mooi Chow

1992-01-01T23:59:59.000Z

339

Identification and quantification of pesticides and polycyclic aromatic hydrocarbons in water and food by gas chromatography-mass spectrometry  

Science Journals Connector (OSTI)

Chances are examined for the identification and determination of pesticides of different types and polycyclic aromatic hydrocarbons, 46 items, in water and food by means of gas chromatography ... make from 2 to 1...

V. G. Amelin; T. B. Nikeshina; A. V. Tret’yakov

2011-10-01T23:59:59.000Z

340

A comparison of biologically active filters for the removal of ozone by-products, turbidity, and particles  

SciTech Connect

Biofiltration tests were performed at the Metropolitan Water District of Southern California`s 5.5-mgd (21,000 m{sup 3}d) demonstration plant using two 400 ft{sup 2} (37 m{sup 2}) anthracite/sand filters and a 6 ft{sup 2} (0.56 m{sup 2}) granular activated carbon (GAC)/sand filter operated in parallel. The empty-bed contact time (EBCT) within the GAC and anthracite ranged from 2.1-3.1 min. The filters were evaluated based on (1) conventional filtration performance (turbidity, particle removal, and headloss); (2) removal of biodegradable ozone by-products (assimilable organic carbon [AOC], aldehydes, and aldoketoacids) after startup; (3) removal of biodegradable ozone by-products at steady state; and (4) resistance to short-term process upsets such as intermittent chlorination or filter out-of-service time. Approximately 80 percent formaldehyde removal was achieved by the anthracite/sand filter operated at a 2.1-min EBCT (6 gpm/ft{sup 2} [15 m/h]) within 8 days of ozone operation. The GAC/sand filter operated at the same rate achieved 80 percent removal within 1 day, possibly as an additive effect of adsorption and biological removal. In-depth aldehyde monitoring at four depths (0.5-min EBCT intervals) provided additional insight into the removal kinetics. During periods of warmer water temperature, from 20 to 48 percent of the AOC was removed in the flocculation/sedimentation basins by 40-75 percent. This percentage removal typically resulted in AOC concentrations within 40 {mu}g C/L of the raw, unozonated water levels.

Coffey, B.M.; Krasner, S.W.; Sclimenti, M.J.; Hacker, P.A.; Gramith, J.T. [Metropolitan Water District of Southern California, La Verne, CA (United States)

1996-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "byproducts aromatic extracts" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Polycyclic aromatic hydrocarbons (PAH) in top soil, leachate and groundwater from Ruseifa solid waste landfill, Jordan  

Science Journals Connector (OSTI)

The distribution profiles and pathways of polynuclear aromatic hydrocarbons in the surroundings of Ruseifa landfill area in Jordan were investigated for surface sediments, leachate, and groundwater. The total concentration of 16 polycyclic aromatic hydrocarbons (PAHs) in sediments ranged from 286 to 1704 ppm with an average value of 751 ppm. Meanwhile, concentrations of PAH in groundwater ranged between 7.1 and 12.6 ppm with an average value of 9.1 ppm. The PAH in leachate varied between 0.10 and 0.40 with an average value of 0.29 ppm. The overall PAH distribution profiles appeared to be similar for leachate and groundwater dominated by 2â??3 rings system molecules. While, the sediments profile was dominated by 4â??6 rings system molecules which indicated the loss of low molecular weight compounds of PAH and accumulation of higher molecular weight of PAH under prevailing semiarid and hot climatic conditions.

Anwar Jiries; Omar Rimawi; Jutta Lintelmann; Mufeed Batarseh

2005-01-01T23:59:59.000Z

342

Extraction Utility Design Specification  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Extraction Utility Extraction Utility Design Specification January 11, 2011 Document Version 1.9 1 Revision History Date Version Section and Titles Author Summary of Change January 15, 2010 1.0 All Eric Morgan, Dekker, Ltd. Initial Draft Document January 19, 2010 1.1 All Igor Pedan, Dekker, Ltd. Document update with EM team review notes January 20, 2010 1.2 2.1.1 EM Project Team Document Review January 27, 2010 1.3 All Bruce Bartells Final Draft Review May 10, 2010 1.4.1 2.8 Igor Pedan, Dekker, Ltd. Section Update May 14, 2010 1.4.2 2.3.1 Igor Pedan, Dekker, Ltd. System Tables Added May 17, 2010 1.4.3 2.3 Igor Pedan, Dekker, Ltd. Enhancements Update June 29, 2010 1.5 All Igor Pedan, Dekker, Ltd. Revised for Version 8.0.20100628 July 14, 2010 1.5.1 2.8 Igor Pedan,

343

Solubility and Solubility Modeling of Polycyclic Aromatic Hydrocarbons in Subcritical Water  

Science Journals Connector (OSTI)

Solubility and Solubility Modeling of Polycyclic Aromatic Hydrocarbons in Subcritical Water ... A static analytical equilibrium method was used to measure the binary and ternary solubilities of anthracene and p-terphenyl in subcritical water between 393 and 473 K and at 50 and 150 bar. ... Nitrogen gas preset to 54 bar was allowed to contact the solution in the equilibrium vessel via valve V3. ...

Wen Hui Teoh; Raffaella Mammucari; Silvio A. B. Vieira de Melo; Neil R. Foster

2013-03-22T23:59:59.000Z

344

Structure of middle distillate fuels on the atomic carbon and hydrogen to carbon ratio at alpha position to aromatic rings  

SciTech Connect

The alkyl, naphthenic, or total carbon atoms of the functional groups at alpha position to aromatic rings and their hydrogen to carbon ratio are some of the important parameters for structural analysis of fossil fuel products. In this paper, the authors present a number of novel formula-structure relationships for precise determination of different carbon atom types at alpha position to aromatic rings and the average number of hydrogens per alpha-carbon.

Glavincevski, B.; Gulder, O.L.; Gardner, L

1988-01-01T23:59:59.000Z

345

Extraction of fossil fuel with guanadine extracting agent  

SciTech Connect

Subdivided coal, oil shale or tar sands is extracted under non-thermally destructive conditions with a solvent liquid containing a compound having the general formula: (R1-)2 N-C(=N-R)-N(-R2)2 Where R, R/sub 1/, and R/sub 2/ are each hydrogen atoms, lower alkyl (C/sub 1/-C/sub 4/) groups, or phenyl groups; provided that the compound has a decomposition temperature higher than the temperature of the extraction, and the extraction temperature is below the softening or decomposition temperature of the material being extracted.

Case, G.D.; Bekowies, P.J.; Panson, A.G.; Stiller, A.H.

1984-09-04T23:59:59.000Z

346

Advanced coal technology by-products: Long-term results from landfill test cells and their implications for reuse or disposal applications  

SciTech Connect

New air pollution regulations under the 1991 Clean Air Act and other legislation are motivating continued development and implementation, of cleaner, more efficient processes for converting coal to electrical power. These clean coal processes produce solid by-products which differ in important respects from conventional pulverized coal combustion ash. Clean coal by-products` contain both residual sorbent and captured SO{sub 2} control products, as well as the mineral component of the coal. The Department of Energy/Morgantown Energy Technology Center has contracted Radian Corporation to construct and monitor landfill test cells with a several different advanced coal combustion by-products at three locations around the US; data from these sites provide a unique picture of the long-term field behavior of clean coal combustion by-products. The field testing sites were located in western Colorado, northern Ohio, and central Illinois. Fluidized bed combustion and lime injection residues are characterized by high lime and calcium sulfate contents` contributed by reacted and unreacted sorbent materials, and produce an leachate, when wetted. Compared with conventional coal fly ash, the clean coal technology ashes have been noted for potential difficulties when wetted, including corrosivity, heat generation, cementation, and swelling on hydration. On the other hand, the high lime content and chemical reactivity of clean coal residues offer potential benefits in reuse as a cementitious material.The results of three years of data collection suggest a fairly consistent pattern of behavior for the calcium-based dry sorbent systems involved in the project, despite differences in the initial of the by-products, differences in the methods of placement, and differences in climate at the test sites.

Weinberg, A. [Radian Corp., Austin, TX (United States); Harness, J.L. [USDOE, Washington, DC (United States)

1994-06-01T23:59:59.000Z

347

Time-Resolved NMR: Extracting the Topology of Complex Enzyme Networks  

NLE Websites -- All DOE Office Websites (Extended Search)

Resolved Resolved NMR: Extracting the Topology of Complex Enzyme Networks Yingnan Jiang, † Tyler McKinnon, † Janani Varatharajan, † John Glushka, † James H. Prestegard, † Andrew T. Sornborger, ‡§ Heinz-Bernd Schu ¨ ttler, { and Maor Bar-Peled † * † Complex Carbohydrate Research Center, ‡ Department of Mathematics, § Faculty of Engineering, and { Department of Physics and Astronomy, University of Georgia, Athens, Georgia ABSTRACT The use of nondestructive NMR spectroscopy for enzymatic studies offers unique opportunities to identify nearly all enzymatic byproducts and detect unstable short-lived products or intermediates at the molecular level; however, numerous challenges must be overcome before it can become a widely used tool. The biosynthesis of acetyl-coenzyme A (acetyl-CoA) by acetyl-CoA synthetase is used here as a case study for the development of

348

DEVELOPMENT OF CONTINUOUS SOLVENT EXTRACTION PROCESSES FOR COAL DERIVED CARBON PRODUCTS  

SciTech Connect

The purpose of this DOE-funded effort is to develop continuous processes for solvent extraction of coal for the production of carbon products. These carbon products include materials used in metals smelting, especially in the aluminum and steel industries, as well as porous carbon structural material referred to as ''carbon foam'' and carbon fibers. Table 1 provides an overview of the major markets for carbon products. Current sources of materials for these processes generally rely on petroleum distillation products or coal tar distillates obtained as a byproduct of metcoke production facilities. In the former case, the American materials industry, just as the energy industry, is dependent upon foreign sources of petroleum. In the latter case, metcoke production is decreasing every year due to the combined difficulties associated with poor economics and a significant environmental burden. Thus, a significant need exists for an environmentally clean process which can used domestically obtained raw materials and which can still be very competitive economically.

Elliot B. Kennel; Chong Chen; Dady Dadyburjor; Liviu Magean; Peter G. Stansberry; Alfred H. Stiller; John W. Zondlo

2005-04-13T23:59:59.000Z

349

Calixarene crown ether solvent composition and use thereof for extraction of cesium from alkaline waste solutions  

DOE Patents (OSTI)

A solvent composition and corresponding method for extracting cesium (Cs) from aqueous neutral and alkaline solutions containing Cs and perhaps other competing metal ions is described. The method entails contacting an aqueous Cs-containing solution with a solvent consisting of a specific class of lipophilic calix[4]arene-crown ether extractants dissolved in a hydrocarbon-based diluent containing a specific class of alkyl-aromatic ether alcohols as modifiers. The cesium values are subsequently recovered from the extractant, and the solvent subsequently recycled, by contacting the Cs-containing organic solution with an aqueous stripping solution. This combined extraction and stripping method is especially useful as a process for removal of the radionuclide cesium-137 from highly alkaline waste solutions which are also very concentrated in sodium and potassium. No pre-treatment of the waste solution is necessary, and the cesium can be recovered using a safe and inexpensive stripping process using water, dilute (millimolar) acid solutions, or dilute (millimolar) salt solutions. An important application for this invention would be treatment of alkaline nuclear tank wastes. Alternatively, the invention could be applied to decontamination of acidic reprocessing wastes containing cesium-137.

Moyer, Bruce A. (Oak Ridge, TN); Sachleben, Richard A. (Knoxville, TN); Bonnesen, Peter V. (Knoxville, TN); Presley, Derek J. (Ooltewah, TN)

2001-01-01T23:59:59.000Z

350

Gas chromatographic determination of polycyclic aromatic hydrocarbons in water and smoked rice samples after solid-phase microextraction using multiwalled carbon nanotube loaded hollow fiber  

Science Journals Connector (OSTI)

Abstract A novel solid-phase microextraction fiber was prepared based on multiwalled carbon nanotubes (MWCNTs) loaded on hollow fiber membrane pores. Stainless steel wire was used as unbreakable support. The major advantages of the proposed fiber are its (a) high reproducibility due to the uniform structure of the hollow fiber membranes, (b) high extraction capacity related to the porous structure of the hollow fiber and outstanding adsorptive characteristics of MWCNTs. The proposed fiber was applied for the microextraction of five representative polycyclic aromatic hydrocarbons (PAHs) from aqueous media (river and hubble–bubble water) and smoked rice samples followed by gas chromatographic determination. Analytical merits of the method, including high correlation coefficients [(0.9963–0.9992) and (0.9982–0.9999)] and low detection limits [(9.0–13.0 ng L?1) and (40.0–150.0 ng kg?1)] for water and rice samples, respectively, made the proposed method suitable for the ultra-trace determination of PAHs.

Amir Abbas Matin; Pourya Biparva; Mohammad Gheshlaghi

2014-01-01T23:59:59.000Z

351

Sources and Deposition of Polycyclic Aromatic Hydrocarbons to Western U.S. National Parks  

Science Journals Connector (OSTI)

Sources and Deposition of Polycyclic Aromatic Hydrocarbons to Western U.S. National Parks ... Department of Chemistry and Department of Environmental & Molecular Toxicology, Oregon State University, Corvallis, Oregon 97331, Department of Chemistry, University of Otago, Dunedin 9014 New Zealand, United States Department of Agriculture - Forest Service, Pacific Northwest Region Air Program, Corvallis, Oregon 97330, US Geological Survey - Water Resources Division, Denver Federal Center, Lakewood, Colorado, Environmental Radioactivity Research Centre, University of Liverpool, Liverpool L69 3BX, U.K., United States Environmental Protection Agency - Western Ecology Division, Corvallis, Oregon 97333 ...

Sascha Usenko; Staci L. Massey Simonich; Kimberly J. Hageman; Jill E. Schrlau; Linda Geiser; Don H. Campbell; Peter G. Appleby; Dixon H. Landers

2010-05-14T23:59:59.000Z

352

Indoor Levels of Polycyclic Aromatic Hydrocarbons in Homes with or without Wood Burning for Heating  

Science Journals Connector (OSTI)

Indoor Levels of Polycyclic Aromatic Hydrocarbons in Homes with or without Wood Burning for Heating ... One wood-burning home had a boiler located in a shelter outside the house and was excluded from the study. ... The concentrations of BaP in the wood-burning homes (0.52 ng/m3) were within the range reported for an American home during operation of different airtight wood stoves (20) and for seven homes during wood burning in airtight wood stoves (21). ...

Pernilla Gustafson; Conny Östman; Gerd Sällsten

2008-06-07T23:59:59.000Z

353

Room-temperature phosphorescence of hydroxyl-substituted aromatics adsorbed on solid surfaces  

SciTech Connect

Several polymer-salt mixtures were examined as solid surfaces for room-temperature phosphorescence (RTP). A variety of hydroxyl-substituted aromatic compounds were observed to give RTP when absorbed on poly(acrylic acid) (PAA)-sodium halide mixtures and filter paper. A solid-sample holding plate was used with a spectrodensitometer for solid surface luminescence detection of components on powder and filter paper adsorbents. RTP analytical data, including linear ranges of calibration curves and limits of detection for several compounds, were compared for 1% PAA-NaBr powder and filter paper.

Dalterio, R.A.; Hurtubise, R.J.

1982-02-01T23:59:59.000Z

354

Advanced byproduct recovery: Direct catalytic reduction of sulfur dioxide to elemental sulfur. Fourth quarterly technical progress report  

SciTech Connect

The team of Arthur D. Little, Tufts University and Engelhard Corporation are conducting Phase 1 of a four and a half year, two-phase effort to develop and scale-up an advanced byproduct recovery technology that is a direct, single-stage, catalytic process for converting sulfur dioxide to elemental sulfur. This catalytic process reduces SO{sub 2} over a fluorite-type oxide (such as ceria and zirconia). The catalytic activity can be significantly promoted by active transition metals, such as copper. More than 95% elemental sulfur yield, corresponding to almost complete sulfur dioxide conversion, was obtained over a Cu-Ce-O oxide catalyst as part of an on-going DOE-sponsored, University Coal Research Program. This type of mixed metal oxide catalyst has stable activity, high selectivity for sulfur production, and is resistant to water and carbon dioxide poisoning. Tests with CO and CH{sub 4} reducing gases indicate that the catalyst has the potential for flexibility with regard to the composition of the reducing gas, making it attractive for utility use. The performance of the catalyst is consistently good over a range of SO{sub 2} inlet concentration (0.1 to 10%) indicating its flexibility in treating SO{sub 2} tail gases as well as high concentration streams.

NONE

1997-01-01T23:59:59.000Z

355

Process for using alkyl substituted C8-C10 aromatic hydrocarbons as preferential physical solvents for selective processing of hydrocarbon gas streams  

SciTech Connect

This patent describes a process for the removal of hydrocarbon gas liquids, comprising hydrocarbons heavier than methane, from a hydrocarbon gas stream. The improvement consists of selectively extracting the hydrocarbon gas liquids from the hydrocarbon gas stream with a preferential physical solvent which provides selective capability for recovery according to the selected degree of (a) ethane in amounts ranging from 2-98%, (b) propane in amounts ranging from 2-99%, (c) butane in amounts ranging from 2-100%, or (d) pentanes and higher molecular weight hydrocarbons in amounts ranging up to 100% which comprises: A. selectively extracting and stripping the hydrocarbon gas stream with the physical solvent to produce a residue hydrocarbon gas stream of pipeline specifications and a rich solvent stream containing ethane and heavier hydrocarbon components, the preferential physical solvent being: (1) rich in C/sub 8/-C/sub 10/ aromatic compounds having methyl, ethyl, or propyl aliphatic groups and (2) selective for ethane and heavier hydrocarbon components of the gas stream such that: (a) the relative volatility of methane over ethane is at least 5.0 and the hydrocarbon loading capacity, defined as solubility of ethane in solvent, is at least 0.25 standard cubic feet of ethane per gallon of solvent, or (b) the preferential factor determined by the multiplication of relative volatility of methane over ethane by the solubility of ethane in solvent, in standard cubic feet of ethane per gallon of solvent, of at least 1.25; and B. distilling the rich solvent to produce the hydrocarbon gas liquids and the physical solvent.

Mehra, Y.R.

1987-09-08T23:59:59.000Z

356

Preliminary evaluation of the use of the greater confinement disposal concept for the disposal of Fernald 11e(2) byproduct material at the Nevada Test Site  

SciTech Connect

This report documents a preliminary evaluation of the ability of the greater confinement disposal boreholes at the Nevada Test Site to provide long-term isolation of radionuclides from the disposal of vitrified byproduct material. The byproduct material is essentially concentrated residue from processing uranium ore that contains a complex mixture of radionuclides, many of which are long-lived and present in concentrations greater than 100,000 picoCuries per gram. This material has been stored in three silos at the fernald Environmental Management Project since the early 1950s and will be vitrified into 6,000 yd{sup 3} (4,580 m{sup 3}) of glass gems prior to disposal. This report documents Sandia National Laboratories` preliminary evaluation for disposal of the byproduct material and includes: the selection of quantitative performance objectives; a conceptual model of the disposal system and the waste; results of the modeling; identified issues, and activities necessary to complete a full performance assessment.

Cochran, J.R.; Brown, T.J.; Stockman, H.W.; Gallegos, D.P.; Conrad, S.H. [Sandia National Labs., Albuquerque, NM (United States)] [Sandia National Labs., Albuquerque, NM (United States); Price, L.L. [Sandia National Labs., Albuquerque, NM (United States)] [Sandia National Labs., Albuquerque, NM (United States); [Beta Inc. (United States)

1997-09-01T23:59:59.000Z

357

Emerging issues on degradation by-products deriving from personal care products and pharmaceuticals during disinfection processes of water used in swimming pools  

Science Journals Connector (OSTI)

Abstract The use of disinfection substances in the sanitation and disinfection processes of artificial water used for sports amenities and swimming pools has recently raised some serious concerns. Recreational Water Illnesses (RWIs) can put at serious risk the health of bathers and swimmers due to adverse effects caused by the use of disinfection chemicals, such as chlorine, chloramine, ozone and UV radiation, as well as their by-products. Remarkable documented evidence is available on the impact of Disinfection By-Products (DBPs), such as chloroform and other trihalomethanes, haloacetic acids and chlorophenols, deriving from the oxidation of common organic pollutants dissolved in raw, drinking, waste and artificial waters. Appropriate countermeasures, aimed at avoiding bathers' exposures to these chemicals, have been developed and adopted in public and private structures, also through important scientific contributions and technical provisions issued by the WHO and some national health authorities. On the other hand, it has been demonstrated that high reactive disinfection agents may transform other undesirable chemicals released by bathers, namely pharmaceuticals, sunscreens and other Pharmaceuticals and Personal Care Products (PPCPs) into chlorinated and oxidized compounds and nitrosamine precursors. The first symptoms of potentially adverse health effects on human subjects of these largely unknown by-products should be adequately taken into consideration and investigated.

Paola Bottoni; Lucia Bonadonna; Mattea Chirico; Sergio Caroli; Gyula Záray

2014-01-01T23:59:59.000Z

358

DEVELOPMENT OF CONTINUOUS SOLVENT EXTRACTION PROCESSES FOR COAL DERIVED CARBON PRODUCTS  

SciTech Connect

The purpose of this DOE-funded effort is to develop continuous processes for solvent extraction of coal for the production of carbon products. These carbon products include materials used in metals smelting, especially in the aluminum and steel industries, as well as porous carbon structural material referred to as ''carbon foam'' and carbon fibers. A process has been developed which results in high quality binder pitch suitable for use in graphite electrodes or carbon anodes. A detailed description of the protocol is given by Clendenin. Briefly, aromatic heavy oils are hydro-treated under mild conditions in order to increase their ability to dissolve coal. An example of an aromatic heavy oil is Koppers Carbon Black Base (CBB) oil. CBB oil has been found to be an effective solvent and acceptably low cost (i.e., significantly below the market price for binder pitch, or about $280 per ton at the time of this writing). It is also possible to use solvents derived from hydrotreated coal and avoid reliance on coke oven recovery products completely if so desired.

Elliot B. Kennel; Philip L. Biedler; Chong Chen; Dady Dadyburjor; Liviu Magean; Peter G. Stansberry; Alfred H. Stiller; John W. Zondlo

2005-04-13T23:59:59.000Z

359

A study on the coagulation of polycyclic aromatic hydrocarbon clusters to determine their collision efficiency  

SciTech Connect

This paper presents a theoretical study on the physical interaction between polycyclic aromatic hydrocarbons (PAHs) and their clusters of different sizes in laminar premixed flames. Two models are employed for this study: a detailed PAH growth model, referred to as the kinetic Monte Carlo - aromatic site (KMC-ARS) model [Raj et al., Combust. Flame 156 (2009) 896-913]; and a multivariate PAH population balance model, referred to as the PAH - primary particle (PAH-PP) model. Both the models are solved by kinetic Monte Carlo methods. PAH mass spectra are generated using the PAH-PP model, and compared to the experimentally observed spectra for a laminar premixed ethylene flame. The position of the maxima of PAH dimers in the spectra and their concentrations are found to depend strongly on the collision efficiency of PAH coagulation. The variation in the collision efficiency with various flame and PAH parameters is studied to determine the factors on which it may depend. A correlation for the collision efficiency is proposed by comparing the computed and the observed spectra for an ethylene flame. With this correlation, a good agreement between the computed and the observed spectra for a number of laminar premixed ethylene flames is found. (author)

Raj, Abhijeet; Sander, Markus; Janardhanan, Vinod; Kraft, Markus [Department of Chemical Engineering and Biotechnology, University of Cambridge, New Museums Site, Pembroke Street, Cambridge CB2 3RA (United Kingdom)

2010-03-15T23:59:59.000Z

360

Biomarker sensitivity for polynuclear and halogenated aromatic hydrocarbon contamination in fish species from Galveston Bay  

SciTech Connect

The Galveston Bay estuary exhibits a contamination gradient for polynuclear aromatic hydrocarbons (PAHs) and halogenated aromatic hydrocarbons, which is useful for comparing biomarker response sensitivity in fish taken from different bay locations. Two fish species, hardhead catfish (Arius felis) and Atlantic croaker (Micropogon undulatus), were collected from four stations where sediment total PAHs ranged from 68 to > 1,000 ng/g. Hardhead catfish showed no consistent CYP1A mediated responses (hepatic ethoxyresorufin-O-deethylase activity (EROD), CYP1A mRNA levels, or CYP1A immunoreactive protein) in the field collected fish or in fish dosed with up to 15 mg/kg benzo(a)pyrene (BaP). Significant differences were seen in field collected hardhead catfish in biliary concentrations of naphthalene, phenanthrene, and BaP metabolites. Conversely, in croakers taken from the same four Galveston Bay locations, there were significant elevations IN EROD and glutathione-S-transferase activities, CYP1A immunoreactive protein, and biliary PAH metabolites at the contaminated stations. These studies suggest that croaker is a good monitoring species especially with respect to induction of CYP1A mediated responses by PAHs. Biliary PAH metabolites and PAH-DNA adducts were sensitive to PAH contamination in both species.

Willett, K.; McDonald, S.; Steinberg, M.; Beatty, K.; Safe, S. [Texas A and M Univ., College Station, TX (United States)

1995-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "byproducts aromatic extracts" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Ocean Thermal Extractable Energy Visualization: Final Technical...  

Office of Environmental Management (EM)

Ocean Thermal Extractable Energy Visualization: Final Technical Report Ocean Thermal Extractable Energy Visualization: Final Technical Report Report about the Ocean Thermal...

362

Compounds having aromatic rings and side-chain amide-functionality and a method for transporting monovalent anions across biological membranes using the same  

DOE Patents (OSTI)

A compound containing at least two aromatic rings covalently bonded together, with each aromatic ring containing at least one oxyacetamide-based side chain, the compound being capable of forming a chloride ion channel across a lipid bilayer, and transporting chloride ion across the lipid bilayer.

Davis, Jeffery T. (College Park, MD); Sidorov, Vladimir (Richmond, VA); Kotch, Frank W. (New Phila., PA)

2008-04-08T23:59:59.000Z

363

Actions of Mycobacterium sp. Strain AP1 on the Saturated- and Aromatic-Hydrocarbon Fractions of Fuel Oil in a Marine Medium  

Science Journals Connector (OSTI)

...Aromatic-Hydrocarbon Fractions of Fuel Oil in a Marine Medium Published ahead...Biodegradation of TPHs of fuel oil by Mycobacterium sp. strain AP1 in marine medium. Strain AP1...aromatic-hydrocarbon fractions of fuel oil in a marine medium. | The pyrene-degrading...

Joaquim Vila; Magdalena Grifoll

2009-08-07T23:59:59.000Z

364

Management of dry flue gas desulfurization by-products in underground mines. Quarterly report, August 1--October 31, 1997  

SciTech Connect

The objective of this project was to develop and demonstrate two technologies for the placement of coal combustion by-products in abandoned underground coal mines, and to assess the environmental impact of these technologies for the management of CCB materials. The two technologies for the underground placement that were to be developed and demonstrated are: (1) pneumatic placement using virtually dry CCB products, and (2) hydraulic placement using a paste mixture of CCB products with about 70% solids. The period covered by this report is the second quarter of Phase 3 of the overall program. During this period over 8,000 tons of CCB mixtures was injected using the hydraulic paste technology. This amount of material virtually filled the underground opening around the injection well, and was deemed sufficient to demonstrate fully the hydraulic injection technology. By the end of this quarter about 2,000 tons of fly ash had been placed underground using the pneumatic placement technology. While the rate of injection of about 50 tons per hour met design criteria, problems were experienced in the delivery of fly ash to the pneumatic demonstration site. The source of the fly ash, the Archer Daniels Midland Company power plant at Decatur, Illinois is some distance from the demonstration site, and often sufficient tanker trucks are not available to haul enough fly ash to fully load the injection equipment. Further, on some occasions fly ash from the plant was not available. The injection well was plugged three times during the demonstration. This typically occurred due to cementation of the FBC ash in contact with water. After considerable deliberations and in consultation with the technical project officer, it was decided to stop further injection of CCB`s underground using the developed pneumatic technology.

Chugh, Y.P.

1997-12-31T23:59:59.000Z

365

Advanced byproduct recovery: Direct catalytic reduction of sulfur dioxide to elemental sulfur. Quarterly report, April 1--June 30, 1997  

SciTech Connect

The team of Arthur D. Little, Tufts University and Engelhard Corporation are conducting Phase 1 of a four and a half year, two-phase effort to develop and scale-up an advanced byproduct recovery technology that is a direct, single-stage, catalytic process for converting sulfur dioxide to elemental sulfur. This catalytic process reduces SO{sub 2} over a fluorite-type oxide (such as ceria and zirconia). The catalytic activity can be significantly promoted by active transition metals, such as copper. More than 95% elemental sulfur yield, corresponding to almost complete sulfur dioxide conversion, was obtained over a Cu-Ce-O oxide catalyst as part of an on-going DOE-sponsored, University Coal Research Program. This type of mixed metal oxide catalyst has stable activity, high selectivity for sulfur production, and is resistant to water and carbon dioxide poisoning. Tests with CO and CH{sub 4} reducing gases indicate that the catalyst has the potential for flexibility with regard to the composition of the reducing gas, making it attractive for utility use. The performance of the catalyst is consistently good over a range of SO{sub 2} inlet concentration (0.1 to 10%) indicating its flexibility in treating SO{sub 2} tail gases as well as high concentration streams. The principal objective of the Phase 1 program is to identify and evaluate the performance of a catalyst which is robust and flexible with regard to choice of reducing gas. In order to achieve this goal, the authors have planned a structured program including: Market/process/cost/evaluation; Lab-scale catalyst preparation/optimization studies; Lab-scale, bulk/supported catalyst kinetic studies; Bench-scale catalyst/process studies; and Utility review. Progress is reported from all three organizations.

NONE

1997-12-31T23:59:59.000Z

366

Powder River Basin coalbed methane: The USGS role in investigating this ultimate clean coal by-product  

SciTech Connect

For the past few decades, the Fort Union Formation in the Powder River Basin has supplied the Nation with comparatively clean low ash and low sulfur coal. However, within the past few years, coalbed methane from the same Fort Union coal has become an important energy by-product. The recently completed US Geological Survey coal resource assessment of the Fort Union coal beds and zones in the northern Rocky Mountains and Great Plains (Fort Union Coal Assessment Team, 1999) has added useful information to coalbed methane exploration and development in the Powder River Basin in Wyoming and Montana. Coalbed methane exploration and development in the Powder River Basin has rapidly accelerated in the past three years. During this time more than 800 wells have been drilled and recent operator forecasts projected more than 5,000 additional wells to be drilled over the next few years. Development of shallow (less than 1,000 ft. deep) Fort Union coal-bed methane is confined to Campbell and Sheridan Counties, Wyoming, and Big Horn County, Montana. The purpose of this paper is to report on the US Geological Survey's role on a cooperative coalbed methane project with the US Bureau of Land Management (BLM), Wyoming Reservoir Management Group and several gas operators. This paper will also discuss the methodology that the USGS and the BLM will be utilizing for analysis and evaluation of coalbed methane reservoirs in the Powder River Basin. The USGS and BLM need additional information of coalbed methane reservoirs to accomplish their respective resource evaluation and management missions.

Stricker, G.D.; Flores, R.M.; Ochs, A.M.; Stanton, R.W.

2000-07-01T23:59:59.000Z

367

POWDERED ACTIVATED CARBON FROM NORTH DAKOTA LIGNITE: AN OPTION FOR DISINFECTION BY-PRODUCT CONTROL IN WATER TREATMENT PLANTS  

SciTech Connect

New federal drinking water regulations have been promulgated to restrict the levels of disinfection by-products (DBPs) in finished public water supplies. DBPs are suspected carcinogens and are formed when organic material is partially oxidized by disinfectants commonly used in the water treatment industry. Additional federal mandates are expected in the near future that will further affect public water suppliers with respect to DBPs. Powdered activated carbon (PAC) has traditionally been used by the water treatment industry for the removal of compounds contributing to taste and odor problems. PAC also has the potential to remove naturally occurring organic matter (NOM) from raw waters prior to disinfection, thus controlling the formation of regulated DBPs. Many small water systems are currently using PAC for taste and odor control and have the potential to use PAC for controlling DBPs. This project, a cooperative effort between the Energy & Environmental Research Center (EERC), the Grand Forks Water Treatment Plant, and the University of North Dakota Department of Civil Engineering, consists of several interrelated tasks. The objective of the research was to evaluate a cost-effective PAC produced from North Dakota lignite for removing NOM from water and reducing trihalomethane formation potential. The research approach was to develop a statistically valid testing protocol that can be used to compare dose-response relationships between North Dakota lignite-derived PAC and commercially available PAC products. A statistical analysis was performed to determine whether significant correlations exist between operating conditions, water properties, PAC properties, and dose-response behavior. Pertinent physical and chemical properties were also measured for each of the waters and each of the PACs.

Daniel J. Stepan; Thomas A. Moe; Melanie D. Hetland; Margaret L. Laumb

2001-06-01T23:59:59.000Z

368

Extractant composition including crown ether and calixarene extractants  

DOE Patents (OSTI)

An extractant composition comprising a mixed extractant solvent consisting of calix[4] arene-bis-(tert-octylbenzo)-crown-6 ("BOBCalixC6"), 4',4',(5')-di-(t-butyldicyclo-hexano)-18-crown-6 ("DtBu18C6"), and at least one modifier dissolved in a diluent. The DtBu18C6 may be present at from approximately 0.01M to approximately 0.4M, such as at from approximately 0.086 M to approximately 0.108 M. The modifier may be 1-(2,2,3,3-tetrafluoropropoxy)-3-(4-sec-butylphenoxy)-2-propanol ("Cs-7SB") and may be present at from approximately 0.01M to approximately 0.8M. In one embodiment, the mixed extractant solvent includes approximately 0.15M DtBu18C6, approximately 0.007M BOBCalixC6, and approximately 0.75M Cs-7SB modifier dissolved in an isoparaffinic hydrocarbon diluent. The extractant composition further comprises an aqueous phase. The mixed extractant solvent may be used to remove cesium and strontium from the aqueous phase.

Meikrantz, David H. (Idaho Falls, ID); Todd, Terry A. (Aberdeen, ID); Riddle, Catherine L. (Idaho Falls, ID); Law, Jack D. (Pocalello, ID); Peterman, Dean R. (Idaho Falls, ID); Mincher, Bruce J. (Idaho Falls, ID); McGrath, Christopher A. (Blackfoot, ID); Baker, John D. (Blackfoot, ID)

2009-04-28T23:59:59.000Z

369

Cesium and strontium extraction using a mixed extractant solvent including crown ether and calixarene extractants  

DOE Patents (OSTI)

A mixed extractant solvent including calix[4]arene-bis-(tert-octylbenzo)-crown-6 ("BOBCalixC6"), 4',4',(5')-di-(t-butyldicyclo-hexano)-18-crown-6 ("DtBu18C6"), and at least one modifier dissolved in a diluent. The mixed extractant solvent may be used to remove cesium and strontium from an acidic solution. The DtBu18C6 may be present from approximately 0.01 M to approximately 0.4M, such as from approximately 0.086 M to approximately 0.108 M. The modifier may be 1-(2,2,3,3-tetrafluoropropoxy)-3-(4-sec-butylphenoxy)-2-propanol ("Cs-7SB") and may be present from approximately 0.01M to approximately 0.8M. In one embodiment, the mixed extractant solvent includes approximately 0.15M DtBu18C6, approximately 0.007M BOBCalixC6, and approximately 0.75M Cs-7SB modifier dissolved in an isoparaffinic hydrocarbon diluent. The mixed extractant solvent may form an organic phase in an extraction system that also includes an aqueous phase. Methods of extracting cesium and strontium as well as strontium alone are also disclosed.

Meikrantz, David H. (Idaho Falls, ID); Todd, Terry A. (Aberdeen, ID); Riddle, Catherine L. (Idaho Falls, ID); Law, Jack D. (Pocatello, ID); Peterman, Dean R. (Idaho Falls, ID); Mincher, Bruce J. (Idaho Falls, ID); McGrath, Christopher A. (Blackfoot, ID); Baker, John D. (Blackfoot, ID)

2007-11-06T23:59:59.000Z

370

Determination of Polycyclic Aromatic Hydrocarbons (PAH’S) at the Low ng/l Level in the Biesbosch Water Storage Reservoirs (NETH.) for the Study of the Degradation of Chemicals in Surface Waters  

Science Journals Connector (OSTI)

The concentrations of six polycyclic aromatic hydrocarbons (PAH’s) in water of the storage reservoirs of the Dutch...

N. Van Den Hoed; Ms M. T. H. Halmans…

1982-01-01T23:59:59.000Z

371

Laser mass spectrometric detection of extraterrestrial aromatic molecules: Mini-review and examination of pulsed heating effects  

Science Journals Connector (OSTI)

...space and atmospheric entry heating...Titan, the largest moon of Saturn...exposed to cold plasma inductively coupled to an RF source to...composition. Thermal gradients generated...PAHs in the area of interest...expectation that atmospheric entry heating...desorption of non-volatile compounds...grains and large aromatic molecules...

Maegan K. Spencer; Matthew R. Hammond; Richard N. Zare

2008-01-01T23:59:59.000Z

372

MHUG process for production of low sulfur and low aromatic diesel fuel. [Medium-pressure Hydro UpGrading  

SciTech Connect

A new hydro-upgrading process operated under medium pressure has been developed to reduce the sulfur and the aromatics content in light cycle oil (LCO). Two catalysts were used in series in this technology. The commercial RN-1 catalyst, which is known as having high activity in hydrodenitrogenation, desulfurization and aromatic saturation, was chosen as the first catalyst. The second one was a nickel-tungsten zeolite catalyst, named RT-5, which was developed by RIPP specially for hydrogenolysis of naphthenic and aromatic hydrocarbons. The pilot plant tests showed that high quality diesel oil with aromatics content less than 20 v% and sulfur content less than 0.05 wt% could be produced from various LCO/straight-run-gas-oil (SRGO) blended feedstocks under hydrogen partial pressure of 6.4 MPa. The reaction temperature and overall space velocity (S.V.) varied in the range of 350--380 C and 0.6--1.2 h[sup [minus]1], respectively, depending on the properties of the feedstocks to be processed and the upgrading depth required. Several examples presented also illustrated that this technology could be used to prepare catalytic reforming feedstock as well, which is in urgent need in China. A life test operated in relatively high severity for 3,000 hr. indicated that the catalysts possessed excellent stability. A commercial demonstration unit has been running well since the last Oct 1.

Shi, Yu Lin; Shi, Jian Wen; Zhang, Xin Wei; Shi, Ya Hua; Li, Da Dong (SINOPEC, Beijing (China). Research Inst. of Petroleum Processing)

1993-01-01T23:59:59.000Z

373

Involuntary Tobacco Smoke Exposure and Urinary Levels of Polycyclic Aromatic Hydrocarbons in the United States, 1999 to 2002  

Science Journals Connector (OSTI)

...environment as a result of incomplete combustion of natural and man-made organic materials...polycyclic aromatic hydrocarbons in a coal-burning environment. Sci Total Environ...Jenkins RA, Guerin MR, Tomkins BA. The chemistry of environmental tobacco smoke: composition...

Plernpit Suwan-ampai; Ana Navas-Acien; Paul T. Strickland; and Jacqueline Agnew

2009-03-01T23:59:59.000Z

374

NMR Determination of Carbon Aromatization during Hydrous Pyrolysis of Coals from the Mesaverde Group, Greater Green River Basin  

Science Journals Connector (OSTI)

NMR Determination of Carbon Aromatization during Hydrous Pyrolysis of Coals from the Mesaverde Group, Greater Green River Basin ... This process is thought to activate capillary seals and could lead to abnormally pressured compartments, which represent a new class of hydrocarbon gas resources. ...

Francis P. Miknis; Daniel A. Netzel; Ronald C. Surdam

1996-01-18T23:59:59.000Z

375

QSAR model of the phototoxicity of polycyclic aromatic hydrocarbons Fabiana Alves de Lima Ribeiro, Marcia Miguel Castro Ferreira*  

E-Print Network (OSTI)

of carcinogenic and toxic potential. These chemicals are well known as water, sediment, soil and air contaminants [1­5]. They are predominant in urban and rural areas, due to the burning of wood and coal, exhaust molecular masses, including even methane, may act as precursors for the polycyclic aromatic compounds. Low

Ferreira, Márcia M. C.

376

Estimating Exposure to Polycyclic Aromatic Hydrocarbons: A Comparison of Survey, Biological Monitoring, and Geographic Information System–Based Methods  

Science Journals Connector (OSTI)

...geographic information system|polycyclic aromatic...evaluating exposure to vehicle exhaust for epidemiologic...geographic information system (GIS). It is not...personal exposures to vehicle exhaust or how they...Performance and Monitoring System of the U.S. Department...average number of vehicles per day traveling...

Robert B. Gunier; Peggy Reynolds; Susan E. Hurley; Sauda Yerabati; Andrew Hertz; Paul Strickland; and Pamela L. Horn-Ross

2006-07-01T23:59:59.000Z

377

Monitoring of Polycyclic Aromatic Hydrocarbons in Bees (Apis mellifera) and Honey in Urban Areas and Wildlife Reserves  

Science Journals Connector (OSTI)

Monitoring of Polycyclic Aromatic Hydrocarbons in Bees (Apis mellifera) and Honey in Urban Areas and Wildlife Reserves ... In fact, rain and wind can clean the flowers and transfer the pollutants to other environmental sectors, and it is also important to consider that the nectar flow, which is usually greater in the spring than in the summer and autumn, could dilute the pollutants. ...

Monia Perugini; Gabriella Di Serafino; Alessandra Giacomelli; Piotr Medrzycki; Anna Gloria Sabatini; Livia Persano Oddo; Enzo Marinelli; Michele Amorena

2009-07-23T23:59:59.000Z

378

Shape-Selective Sorption and Fluorescence Sensing of Aromatics in a Flexible Network of Tetrakis[(4-methylthiophenyl)ethynyl]silane  

E-Print Network (OSTI)

Shape-Selective Sorption and Fluorescence Sensing of Aromatics in a Flexible Network of Tetrakis[(4 entering the pores, enabling, for example, the selective sorption of benzene over hexafluorobenzene networks.1-6 Examples of sorption studies in crystalline coordination networks include selective binding

Li, Jing

379

Association of Carcinogenic Polycyclic Aromatic Hydrocarbon Emissions and Smoking with Lung Cancer Mortality Rates on a Global Scale  

Science Journals Connector (OSTI)

(2, 4) For most populations, approximately 80% of all lung cancer cases are associated with tobacco smoking and the remaining 20% have been attributed to exposure to secondhand smoke, radon (and its decay products), asbestos, some metals (including arsenic, beryllium, cadmium), organic compounds (including carcinogenic polycyclic aromatic hydrocarbons (PAHs)), radiation, and genetic susceptibility. ...

Oleksii Motorykin; Melissa M. Matzke; Katrina M. Waters; Staci L. Massey Simonich

2013-03-08T23:59:59.000Z

380

Involuntary Tobacco Smoke Exposure and Urinary Levels of Polycyclic Aromatic Hydrocarbons in the United States, 1999 to 2002  

Science Journals Connector (OSTI)

...the Internet]. U.S. Census Bureau, Housing and Household Economic Statistics Division. [updated 2008 Aug 26; cited 2008 Dec...human exposure to ambient polycyclic aromatic hydrocarbons in a coal-burning environment. Sci Total Environ 1990;92:145-54...

Plernpit Suwan-ampai; Ana Navas-Acien; Paul T. Strickland; and Jacqueline Agnew

2009-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "byproducts aromatic extracts" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

2094 J.Org. Chem. 1988,53, 2094-2099 Table 11. Bromination of Aromatic Hydrocarbons with  

E-Print Network (OSTI)

Br,/aromatic = 5; solvent: carbon tetrachloride. *Chloro- benzene. tetrachloride and 1,4-dibromonaphthalenewas from ICN Biomedicals (WoelmN-Super 1). Carbon tetrachloride was dried with calcium chloride,26, 759. (10) Kovacic, P.; Wu, C. J. Org. Chem. 1961,26, 762. mmol), 2 (30 g), and carbon tetrachloride

Hudlicky, Tomas

382

Extraction Route Trials on Sensitive Sites  

E-Print Network (OSTI)

on extraction routes. These routes must therefore be carefully constructed and maintained in order to safeguard

383

Accurate extraction of the News  

E-Print Network (OSTI)

We propose a new scheme for extracting gravitational radiation from a characteristic numerical simulation of a spacetime. This method is similar in conception to our earlier work but analytical and numerical implementation is different. The scheme is based on direct transformation to the Bondi coordinates and the gravitational waves are extracted by calculating the Bondi news function in Bondi coordinates. The entire calculation is done in a way which will make the implementation easy when we use uniform Bondi angular grid at $\\mathcal I^+$. Using uniform Bondi grid for news calculation has added advantage that we have to solve only ordinary differential equations instead of partial differential equation. For the test problems this new scheme allows us to extract gravitational radiation much more accurately than the previous schemes.

Shrirang S. Deshingkar

2006-09-14T23:59:59.000Z

384

THE NASA AMES POLYCYCLIC AROMATIC HYDROCARBON INFRARED SPECTROSCOPIC DATABASE: THE COMPUTED SPECTRA  

SciTech Connect

The astronomical emission features, formerly known as the unidentified infrared bands, are now commonly ascribed to polycyclic aromatic hydrocarbons (PAHs). The laboratory experiments and computational modeling done at the NASA Ames Research Center to create a collection of PAH IR spectra relevant to test and refine the PAH hypothesis have been assembled into a spectroscopic database. This database now contains over 800 PAH spectra spanning 2-2000 {mu}m (5000-5 cm{sup -1}). These data are now available on the World Wide Web at www.astrochem.org/pahdb. This paper presents an overview of the computational spectra in the database and the tools developed to analyze and interpret astronomical spectra using the database. A description of the online and offline user tools available on the Web site is also presented.

Bauschlicher, C. W.; Ricca, A. [NASA Ames Research Center, MS 230-3, Moffett Field, CA 94035 (United States); Boersma, C.; Mattioda, A. L.; Cami, J.; Peeters, E.; Allamandola, L. J. [NASA Ames Research Center, MS 245-6, Moffett Field, CA 94035 (United States); Sanchez de Armas, F.; Puerta Saborido, G. [SETI Institute, 515 N. Whisman Road, Mountain View, CA 94043 (United States); Hudgins, D. M., E-mail: Charles.W.Bauschlicher@nasa.go [NASA Headquarters, MS 3Y28, 300 E St. SW, Washington, DC 20546 (United States)

2010-08-15T23:59:59.000Z

385

On-line database of the spectral properties of polycyclic aromatic hydrocarbons  

E-Print Network (OSTI)

We present an on-line database of computed molecular properties for a large sample of polycyclic aromatic hydrocarbons (PAHs) in four charge states: -1, 0, +1, and +2. At present our database includes 40 molecules ranging in size from naphthalene and azulene (C10H8) up to circumovalene (C66H20). We performed our calculations in the framework of the density functional theory (DFT) and the time-dependent DFT to obtain the most relevant molecular parameters needed for astrophysical applications. For each molecule in the sample, our database presents in a uniform way the energetic, rotational, vibrational, and electronic properties. It is freely accessible on the web at http://astrochemistry.ca.astro.it/database/ and http://www.cesr.fr/~joblin/database/.

G. Malloci; C. Joblin; G. Mulas

2007-01-09T23:59:59.000Z

386

Anisotropy and Size Effects on the Optical Spectra of Polycyclic Aromatic Hydrocarbons  

E-Print Network (OSTI)

The electronic and optical properties of polycyclic aromatic hydrocarbons (PAHs) present a strong dependence on their size and geometry. We tackle this issue by analyzing the spectral features of two prototypical classes of PAHs, belonging to D6h and D2h symmetry point groups and related to coronene as multifunctional seed. While the size variation induces an overall red shift of the spectra and a redistribution of the oscillator strength between the main peaks, a lower molecular symmetry is responsible for the appearance of new optical features. Along with broken molecular orbital degeneracies, optical peaks split and dark states are activated in the low-energy part of the spectrum. Supported by a systematic analysis of the composition and the character of the optical transitions, our results contribute in shedding light to the mechanisms responsible for spectral modifications in the visible and near UV absorption bands of medium-size PAHs.

Caterina Cocchi; Deborah Prezzi; Alice Ruini; Marilia J. Caldas; Elisa Molinari

2014-09-08T23:59:59.000Z

387

Emission of Oxygenated Polycyclic Aromatic Hydrocarbons from Indoor Solid Fuel Combustion  

Science Journals Connector (OSTI)

(17) The relatively high OPAH emissions from indoor burning can be explained by the different amount of oxygen supply resulting in lower combustion efficiencies and relatively high temperature in the enclosed residential stoves due to low heat loss. ... hydrocarbon (PAH) emission source in developing countries; however, PAH emission factor (EF) data for indoor crop residue combustion, particularly field-measured data, are scarce, leading to large uncertainties in emission inventories. ... Shen, G.; Wang, W.; Yang, Y.; Zhu, C.; Min, Y.; Xue, M.; Ding, J.; Li, W.; Wang, B.; Shen, H.; Wang, R.; Wang, X.; Tao, S.Emission factors and particulate matter size distribution of polycyclic aromatic hydrocarbons from residential coal combustions in rural Northern China Atmos. ...

Guofeng Shen; Shu Tao; Wei Wang; Yifeng Yang; Junnan Ding; Miao Xue; Yujia Min; Chen Zhu; Huizhong Shen; Wei Li; Bin Wang; Rong Wang; Wentao Wang; Xilong Wang; Armistead G. Russell

2011-03-04T23:59:59.000Z

388

Air pollution from a large steel factory: polycyclic aromatic hydrocarbon emissions from coke-oven batteries  

SciTech Connect

A systematic investigation of solid and gaseous atmospheric emissions from some coke-oven batteries of one of Europe's largest integrated steel factory (Taranto, Italy) has been carried out. These emissions, predominantly diffuse, originate from oven leakages, as well as from cyclic operations of coal loading and coke unloading. In air monitoring samples, polycyclic aromatic hydrocarbons (PAHs) were consistently detected at concentrations largely exceeding threshold limit values. By means of PAHs speciation profile and benzo-(a)pyrene (BaP) equivalent dispersion modeling from diffuse sources, the study indicated that serious health risks exist not only in working areas, but also in a densely populated residential district near the factory. 30 refs., 5 figs., 3 tabs.

Lorenzo Liberti; Michele Notarnicola; Roberto Primerano; Paolo Zannetti [Technical University of Bari, Bari (Italy). Department of Environmental Engineering and Sustainable Development

2006-03-15T23:59:59.000Z

389

Distribution and sources of polycyclic aromatic hydrocarbons in surface sediments of the Hormuz strait, Persian Gulf  

Science Journals Connector (OSTI)

Abstract The concentrations of 16 polycyclic aromatic hydrocarbons (PAHs) were determined in the sediment from the Hormuz strait, Persian Gulf. The sum of 16 \\{PAHs\\} (?PAH) concentrations varied from 72.17 to 277.77 ng g?1 dry weight, with an average value of 131.20 ± 59.29 ng g?1 dry weight. An ecological risk assessment of PAHs, indicated that adverse biological effects caused by acenaphthene and acenaphthylene occasionally may take place in the sediment of Hormuz strait. PAH source identification showed that the \\{PAHs\\} in the sediments come from pyrogenic and mixed origin. Based on classification of pollution levels, sediments from Hormuz strait could be considered as low to moderately polluted with PAHs.

Shirin Rahmanpoor; Hosein Ghafourian; Seyed Mehri Hashtroudi; Kazem Darvish Bastami

2014-01-01T23:59:59.000Z

390

Rendering graphene supports hydrophilic with non-covalent aromatic functionalization for transmission electron microscopy  

SciTech Connect

Amorphous carbon films have been routinely used to enhance the preparation of frozen-hydrated samples for transmission electron microscopy (TEM), either in retaining protein concentration, providing mechanical stability or dissipating sample charge. However, strong background signal from the amorphous carbon support obstructs that of the sample, and the insulating properties of thin amorphous carbon films preclude any efficiency in dispersing charge. Graphene addresses the limitations of amorphous carbon. Graphene is a crystalline material with virtually no phase or amplitude contrast and unparalleled, high electrical carrier mobility. However, the hydrophobic properties of graphene have prevented its routine application in Cryo-TEM. This Letter reports a method for rendering graphene TEM supports hydrophilic—a convenient approach maintaining graphene's structural and electrical properties based on non-covalent, aromatic functionalization.

Pantelic, Radosav S., E-mail: pantelic@imbb.forth.gr [National Cancer Institute, 50 South Drive, Building 50, Room 4306, Bethesda, Maryland 20892 (United States); Fu, Wangyang; Schoenenberger, Christian [Department of Physics, University of Basel, Klingelbergstrasse 82, Basel CH-4056 (Switzerland); Stahlberg, Henning [Center for Cellular Imaging and NanoAnalytics, Biozentrum, University of Basel, Mattenstrasse 26, WRO-1058, Basel CH-4058 (Switzerland)

2014-03-31T23:59:59.000Z

391

THE INFRARED SPECTRA OF POLYCYCLIC AROMATIC HYDROCARBONS WITH SOME OR ALL HYDROGEN ATOMS REMOVED  

SciTech Connect

The loss of one hydrogen from C{sub 96}H{sub 24} does not significantly affect the infrared spectra of the neutral, cation, or anion. Excluding a very weak C-C stretching band at 5.1 ?m, the loss of two adjacent duo hydrogens does not significantly affect the spectra compared with the parent. Removing all of the hydrogen atoms significantly increases the intensity of the new C-C stretching band, and, for the cation, shifts it to a longer (5.2 ?m) wavelength. Observations show a feature near 5.25 ?m, which has been attributed to overtone and combination bands from polycyclic aromatic hydrocarbons (PAHs). This current work suggests that dehydrogenated PAHs might also contribute to this band, but its weakness implies that fully dehydrogenated cationic or dicationic species are very rare.

Bauschlicher, Charles W. Jr. [Entry Systems and Technology Division, Mail Stop 230-3, NASA Ames Research Center, Moffett Field, CA 94035 (United States); Ricca, Alessandra, E-mail: Charles.W.Bauschlicher@nasa.gov, E-mail: Alessandra.Ricca-1@nasa.gov [Carl Sagan Center, SETI Institute, 189 Bernardo Avenue, Mountain View, CA 94043 (United States)

2013-10-20T23:59:59.000Z

392

By-Products Utilization  

E-Print Network (OSTI)

the Dairyland Power Cooperative, La Crosse, WI; Madison Gas and Electric Company, Madison, WI; National Minerals contents or use thereof. This report does not constitute a standard, specification, or regulation

Wisconsin-Milwaukee, University of

393

By-Products Utilization  

E-Print Network (OSTI)

ash. A clean-coal ash is defined as the ash derived from SO2 control technologies. Investigations were CONTAINING CLEAN-COAL ASH AND CLASS F FLY ASH By Tarun R. Naik, Rudolph N. Kraus, Rafat Siddique, Berlin, Germany, October 2003 Department of Civil Engineering and Mechanics College of Engineering

Wisconsin-Milwaukee, University of

394

By-Products Utilization  

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at the Cement and Concrete Institute of Mexico Symposium "Worldof Concrete - Mexico," Guadalajara, Mexico, June with proper use of form oil to allow migration of released air pockets. Sand content should be increased

Wisconsin-Milwaukee, University of

395

By-Products Utilization  

E-Print Network (OSTI)

addition for mortars and concretes, especially for self-compacting concrete. This marble powder showed on self-compacting concrete mixtures (1-6). MATERIALS Portland Cement A commercial portland AND CONCRETE By Valeria Corinaldesi, Giacomo Moriconi, and Tarun R. Naik Report No. CBU-2005-09 REP-580 August

Wisconsin-Milwaukee, University of

396

By-Products Utilization  

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-dust in self-consolidating concrete (SCC). A control SCC mixture was made, in which ASTM C 618 Class C fly ash: tarun@uwm.edu (T. R. Naik). 1. Introduction Self-consolidating concrete (SCC), a relatively recent- compacting concrete, super-workable concrete, highly flowable concrete, non-vibrating concrete, and other

Wisconsin-Milwaukee, University of

397

By-Products Utilization  

E-Print Network (OSTI)

was carried out to utilize wood ash in making self- compacting controlled low-strength materials (CLSM), air and Presentation at the Seventh CANMET/ACI International Conference on Recent Advances in Concrete Technology, Las-entrained and non-air- entrained concretes, and bricks/blocks/paving stones. Initial test results indicated

Wisconsin-Milwaukee, University of

398

By-Products Utilization  

E-Print Network (OSTI)

of consistency and fluidity, self-leveling and self-compacting, contain very little portland cement, and large applications, such as Roller Compacted Concrete for industrial plants, materials handling yards, parking lots quantities of ash and water. It is believed that concrete Bricks, Blocks, and Paving Stones can also be made

Wisconsin-Milwaukee, University of

399

By-Products Utilization  

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6 concretes, especially for self-compacting concrete. This marble powder showed a very high7 Blaine AND CONCRETE By Valeria Corinaldesi, Giacomo Moriconi, and Tarun R. Naik Report No. CBU-2007-07 REP-628 #12;1 CHARACTERIZATION OF MARBLE POWDER FOR ITS USE IN1 MORTAR AND CONCRETE2 3 Valeria Corinaldesi

Wisconsin-Milwaukee, University of

400

By-Products Utilization  

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to be handled without segregation. It is also referred to as self-compacting concrete, super-workable concrete SELF- CONSOLIDATING CONCRETE By Tarun R. Naik, Rudolph N. Kraus, Yoon-moon Chun, Fethullah Canpolat-Dust in Manufacturing Economical Self-Consolidating Concrete T. R. Naika, *, R. N. Krausa , Y. Chuna , F. Canpolata , R

Wisconsin-Milwaukee, University of

Note: This page contains sample records for the topic "byproducts aromatic extracts" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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401

By-Products Utilization  

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-reinforced concrete, self-compacting concrete, ultra-high-strength concrete, conductive concrete, self-curing concrete chemical environments and complex applied loading conditions. The recent development of self-compacting-performance concrete, high-durability concrete (HDC), roller compacted concrete, high-volume fly ash concrete, fiber

Wisconsin-Milwaukee, University of

402

By-Products Utilization  

E-Print Network (OSTI)

ash. Paving applications, such as Roller Compacted Concrete for industrial plants, parking lots be used in Self-Consolidating Concrete applications. This type of concrete requires additional fines that concrete Bricks, Blocks, and Paving Stones can also be made with the Corn Products' coal ash. Additionally

Wisconsin-Milwaukee, University of

403

By-Products Utilization  

E-Print Network (OSTI)

of Self-Compactability of Fresh Concrete............................................... 6 Slump-Flow Test Energies Fly Ash for Developing Economical Self- Consolidating Concrete (by Tarun R. Naik, Yoon-moon Chun, particularly the viscosity modifying admixture (VMA), for producing an economical self- consolidating concrete

Wisconsin-Milwaukee, University of

404

By-Products Utilization  

E-Print Network (OSTI)

-leveling, self-compacting, cementitious material, which has a consistency similar to a pancake batter. CLSM can fibrous residuals from pulp and paper mills. The flowable slurry will meet ACI (American Concrete Institute) 229 recommendations for flowable Controlled Low-Strength Materials (CLSM). CLSM is a self

Wisconsin-Milwaukee, University of

405

By-Products Utilization  

E-Print Network (OSTI)

is defined as a self compacted, cementitious material used primarily as a backfill in lieu of compacted fill and published at the third CANMET/ACI International Symposium on Advances in Concrete Technology, Auckland, New of low strength fill materials and has been known by many other names. The American Concrete Institute

Wisconsin-Milwaukee, University of

406

By-Products Utilization  

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at the National Seminar on Building Materials and Technology for Sustainable Developments, CEPT-SBST, Ahmedabad a leading role in the sustainable development of the cement and concrete industry in this century. Sustainable design and construction of structures have a small impact on the environment, use "green

Wisconsin-Milwaukee, University of

407

By-Products Utilization  

E-Print Network (OSTI)

-28 REP-482 November 2002 Final Technical Report Issued to the Illinois Clean Coal Institute For Project

Wisconsin-Milwaukee, University of

408

By-Products Utilization  

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­ Milwaukee, Milwaukee, WI and Ronald H. Carty Director Illinois Clean Coal Institute Carterville, IL ABSTRACT, Naik and Singh [16] summarized various applications of fly ash generated from conventional and clean coal technologies. Uses of coal combustion by- products can be categorized into three classes: high-volum

Wisconsin-Milwaukee, University of

409

By-Products Utilization  

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.4 April 2000 A Mid-Year Project Management Report Issued to the Illinois Clean Coal Institute for Project for evaluation. Clean coal fly ash was obtained from Southern Illinois University and a wet collected Class F fly and Quarters Cumulative$ Cumulative Project Budget Total Illinois Clean Coal Institute Award $ 86,095 Estimated

Wisconsin-Milwaukee, University of

410

By-Products Utilization  

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with the combination of Class C fly ash and clean coal ash. Two percent to four percent sodium sulfate anhydrite

Wisconsin-Milwaukee, University of

411

By-Products Utilization  

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-Milwaukee, P.O. Box 784, Milwaukee, WI 53201 d Project Manager, Illinois Clean Coal Institute * Director UWM products containing clean coal ash compared to conventional coal ash. Utilization of clean coal ash is much products that utilize clean coal ash. With increasing federal regulations on power plant emissions, finding

Wisconsin-Milwaukee, University of

412

By-Products Utilization  

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-19 REP-443 November 2001 Final Technical Report Issued to the Illinois Clean Coal Institute For Project

Wisconsin-Milwaukee, University of

413

By-Products Utilization  

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), at 28 days, using various sources of ASTM Class F and clean coal fly ashes. For each reference mixture

Wisconsin-Milwaukee, University of

414

By-Products Utilization  

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-Products Utilization E-mail: ymchun@uwm.edu and F. D. Botha Project Manager, Illinois Clean Coal Institute 5776 Coal, University of Wisconsin-Milwaukee, Milwaukee, WI, USA. 4 Project Manager, Illinois Clean Coal Institute

Wisconsin-Milwaukee, University of

415

By-Products Utilization  

E-Print Network (OSTI)

at the Technical Session on Recycling Concrete and Other Materials for Sustainable Development at 2003 ACI Spring; microfiber reinforcement; pulp and paper mill residual solids; recycling; salt-scaling resistance. 1 Director - INTRODUCTION Pulp and paper mill wastewater treatment plant residuals (also called sludge) are the solid

Wisconsin-Milwaukee, University of

416

By-Products Utilization  

E-Print Network (OSTI)

; microfibers; pulp and paper mills; recycling; deicing salt scaling; sludge; wastewater treatment residuals with Recycled Materials. Yoon-moon Chun is a postdoctoral fellow at the UWM-CBU. His research interests include residuals from the pulp and paper industry in concrete. INTRODUCTION Pulp and paper mill wastewater

Wisconsin-Milwaukee, University of

417

By-Products Utilization  

E-Print Network (OSTI)

,and Bruce W. Ramme CBU-1996-08 REP-283 July 1996 Presented andPublished at the American Coal Ash Association's Twelfth International Coal Ash Use Symposium,Orlando,FL,January 26-30, 1997. Department of Civil-sulfurcoal combustionby-products generated by using both conventional and clean coal technologies. A clean coal ash

Wisconsin-Milwaukee, University of

418

By-Products Utilization  

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-specification ash generated from the combustion of high- sulfure coal. The coal combustion products used of the project indicate that high-carbon coal ash can be successfully used in porous base course applications is a Research Associate at the UWM-CBU. His research interests include the use of coal fly ash, coal bottom ash

Wisconsin-Milwaukee, University of

419

By-Products Utilization  

E-Print Network (OSTI)

interests include the use of coal fly ash, coal bottom ash, and used foundry sand in concrete and masonry led to high resistance to freezing and thawing. Ash slurry made with ASTM Class C fly ash can set too rapidly. In addition, ash slurry and sandy slurry made with Class C fly ash can develop a very high long

Wisconsin-Milwaukee, University of

420

By-Products Utilization  

E-Print Network (OSTI)

were made using ponded coal-combustion fly ash and quarry screenings (fine crushed sand). In Series 2, six mixtures of flowable slurry were made, the first five mixtures using the ponded coal-ash is a Postdoctoral Fellow at the UWM-CBU. His research interests include the use of coal fly ash, coal bottom ash

Wisconsin-Milwaukee, University of

Note: This page contains sample records for the topic "byproducts aromatic extracts" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

By-Products Utilization  

E-Print Network (OSTI)

and block. Four block and four brick mixtures were also used in combination of wood ash and coal ash with up a combination of wood ash and coal ash with up to 50% cement reduction also met strength requirements. Concrete brick mixtures containing wood ash and a combination of wood ash with coal ash also met requirements

Wisconsin-Milwaukee, University of

422

By-Products Utilization  

E-Print Network (OSTI)

), including construction materials, metal recovery, and pollution control. Landfilling is becoming very of some heavy metals, the use of wood fly ash as a soil supplement is also becoming limited; in addition

Wisconsin-Milwaukee, University of

423

By-Products Utilization  

E-Print Network (OSTI)

currently being produced by Manitowoc Public Utilities. Flowable Materials have up to 1200 psi compressive of water, and consist mostly of ash or similar materials. It is believed that concrete Bricks, Blocks in manufacturing Blended Cements. Soil stabilization or site remediation is another significant potential use

Wisconsin-Milwaukee, University of

424

By-Products Utilization  

E-Print Network (OSTI)

consume all of the ashes currently being produced by Manitowoc Public Utilities. Flowable Materials have little portland cement and a lot of water, and consist mostlyof ash or similar materials. It is believed fly ash in manufacturing Blended Cements. Soil stabilization or site remediation is another

Wisconsin-Milwaukee, University of

425

By-Products Utilization  

E-Print Network (OSTI)

would consume all of the wood ashes produced at Consolidated Papers. Flowable Materials have up to 1200 portland cement and a lot of water, and consist mostly of ash or similar materials. It is believed remediation is another significant potential use of the ashes. For example, for log-yard paving (Roller

Wisconsin-Milwaukee, University of

426

By-Products Utilization  

E-Print Network (OSTI)

of ettringite to monosulphate and hemi-sulphate was prevented. Instead, ettringite transformed to monocarbonate of aggregate. The presence of CO2 in the pastes prevents the reaction of ettringite, formed in the course of ettringite remains almost unchanged and the crystallisation of hemicarbonate, monocarbonate or both

Wisconsin-Milwaukee, University of

427

By-Products Utilization  

E-Print Network (OSTI)

U.S. Department of Energy FEDERAL ASSISTANCE PROGRAM/PROJECT STATUS REPORT OMB Burden Disclosure 2001 Fourth quarterly technical report submitted to the US Department of Energy for the Project DE- FC (1910-0400), U.S. Department of Energy, 1000 Independence Avenue, S.W., Washington, DC 20585

Wisconsin-Milwaukee, University of

428

By-Products Utilization  

E-Print Network (OSTI)

Editions Are Obsolete U.S. Department of Energy FEDERAL ASSISTANCE PROGRAM/PROJECT STATUS REPORT OMB Burden April 2001 First quarterly technical report for Year 2 submitted to the US Department of Energy Project (1910-0400), U.S. Department of Energy, 1000 Independence Avenue, S.W., Washington, DC 20585

Wisconsin-Milwaukee, University of

429

By-Products Utilization  

E-Print Network (OSTI)

of landfilling is increasing due to strict environmental regulations and limited availability of landfill space a stricter environmental regulation. In light of these, it is essential to develop beneficial uses of wood and publication at the ACI Maharastra Chapter, Mumbai, India, July 2001. Department of Civil Engineering

Wisconsin-Milwaukee, University of

430

Aromatic carboxylate effect on dimensionality of three bis(benzimidazole)-based cobalt(II) coordination polymers: Syntheses, structures and properties  

SciTech Connect

Three new metal-organic coordination polymers [Co(4-bbc){sub 2}(bbbm)] (1), [Co(3,5-pdc)(bbbm)]·2H{sub 2}O (2) and [Co(1,4-ndc)(bbbm)] (3) (4-Hbbc=4-bromobenzoic acid, 3,5-H{sub 2}pdc=3,5-pyridinedicarboxylic acid, 1,4-H{sub 2}ndc=1,4-naphthalenedicarboxylic acid and bbbm=1,1-(1,4-butanediyl)bis-1H-benzimidazole) were hydrothermally synthesized and structurally characterized. Polymer 1 is a 1D chain formed by the bbbm ligands and Co{sup II} ions. Polymer 2 exhibits a 2D network with a (3·4·5)(3{sup 2}·4·5·6{sup 2}·7{sup 4}) topology. Polymer 3 possesses a 3D three-fold interpenetrating framework. The versatile structures of title polymers indicate that the aromatic carboxylates have an important influence on the dimensionality of 1–3. Moreover, the thermal stability, electrochemical and luminescent properties of 1–3 were investigated. - graphical abstract: Three bis(benzimidazole)-based cobalt(II) coordination polymers tuned by aromatic carboxylates were hydrothermally synthesized and structurally characterized. The aromatic carboxylates play a key role in the dimensionality of three polymers. The electrochemical and luminescent properties of three polymers were investigated. Display Omitted - Highlights: • Three bis(benzimidazole)-based cobalt(II) coordination polymers tuned by aromatic carboxylates were obtained. • The aromatic carboxylates have an important influence on the dimensionality of three polymers. • The electrochemical and luminescent properties of three polymers were investigated.

Zhang, Ju-Wen; Gong, Chun-Hua; Hou, Li-Li; Tian, Ai-Xiang; Wang, Xiu-Li, E-mail: wangxiuli@bhu.edu.cn

2013-09-15T23:59:59.000Z

431

2 Extracting and trapping biogenic 3 volatile organic compounds stored  

E-Print Network (OSTI)

, Subcritical water extraction; UAE, Ultrasound-assisted extraction 36 1. Introduction Plants release

Goldstein, Allen

432

The Surface Organometallic Chemistry of Pd Electrodes: Studies with Aromatic Compounds  

E-Print Network (OSTI)

-layer electrochemistry was employed with atomically smooth polycrystalline electrodes to extract information on surface packing densities and adsorbate cross sections. Comparison of the latter with calculated values allowed the determination of the more plausible...

Cruz, Juan

2012-10-19T23:59:59.000Z

433

Barriers to the increased utilization of coal combustion/desulfurization by-products by government & commercial sectors - update 1998,7/99,3268845  

NLE Websites -- All DOE Office Websites (Extended Search)

BARRIERS TO THE INCREASED UTILIZATION BARRIERS TO THE INCREASED UTILIZATION OF COAL COMBUSTION/DESULFURIZATION BY-PRODUCTS BY GOVERNMENT AND COMMERCIAL SECTORS - UPDATE 1998 EERC Topical Report DE-FC21-93MC-30097--79 Submitted by: Debra F. Pflughoeft-Hassett Everett A. Sondreal Edward N. Steadman Kurt E. Eylands Bruce A. Dockter Energy & Environmental Research Center PO Box 9018 Grand Forks, ND 58202-9018 99-EERC-07-08 July 1999 i TABLE OF CONTENTS LIST OF FIGURES . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . iv LIST OF TABLES . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . v ACKNOWLEDGMENTS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . vi LIST OF ACRONYMS AND ABBREVIATIONS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . vii TERMINOLOGY AND DEFINITIONS . . . . . . . . . . . . . . . . . . . . . . . . . . . .

434

Black Hole Energy Extraction Problems  

Science Journals Connector (OSTI)

... non-rotating black hole the particle can be lowered to no closer than 1.14 Schwarzschild radii, and the energy extracted can be no more than 63.2 per cent ... gram of matter-and the rope could be lowered no closer than 5 x 1011 Schwarzschild radii. This seems to rule out black holes as practical sources of energy. ...

1972-11-24T23:59:59.000Z

435

Comparison of Two Extraction Methods for the Determination of Polycyclic Aromatic Hydrocarbons in Surface Soils Using Headspace SPME with GC-FID  

Science Journals Connector (OSTI)

......Lauda, Germany) was used. Inside this vessel, a 40-mL amber vial capped with a phenolic...very good reproducibility, short time consumption, and, in addition, is solvent-free...Garcia, and E. Mill n. Determination of fuel dialkyl ethers and BTEX in water using......

Dani Zuazagoitia; Esmeralda Millán; Rosa Garcia-Arrona

2009-02-01T23:59:59.000Z

436

Mechanistic and kinetic evaluation of organic disinfection by-product and assimilable organic carbon (AOC) formation during the ozonation of drinking water  

Science Journals Connector (OSTI)

Ozonation of drinking water results in the formation of low molecular weight (LMW) organic by-products. These compounds are easily utilisable by microorganisms and can result in biological instability of the water. In this study, we have combined a novel bioassay for assessment of assimilable organic carbon (AOC) with the detection of selected organic acids, aldehydes and ketones to study organic by-product formation during ozonation. We have investigated the kinetic evolution of LMW compounds as a function of ozone exposure. A substantial fraction of the organic compounds formed immediately upon exposure to ozone and organic acids comprised 60–80% of the newly formed AOC. Based on experiments performed with and without hydroxyl radical scavengers, we concluded that direct ozone reactions were mainly responsible for the formation of small organic compounds. It was also demonstrated that the laboratory-scale experiments are adequate models to describe the formation of LMW organic compounds during ozonation in full-scale treatment of surface water. Thus, the kinetic and mechanistic information gained during the laboratory-scale experiments can be utilised for upscaling to full-scale water treatment plants.

Frederik Hammes; Elisabeth Salhi; Oliver Köster; Hans-Peter Kaiser; Thomas Egli; Urs von Gunten

2006-01-01T23:59:59.000Z

437

Titanium metal: extraction to application  

SciTech Connect

In 1998, approximately 57,000 tons of titanium metal was consumed in the form of mill products (1). Only about 5% of the 4 million tons of titanium minerals consumed each year is used to produce titanium metal, with the remainder primarily used to produce titanium dioxide pigment. Titanium metal production is primarily based on the direct chlorination of rutile to produce titanium tetrachloride, which is then reduced to metal using the Kroll magnesium reduction process. The use of titanium is tied to its high strength-to-weight ratio and corrosion resistance. Aerospace is the largest application for titanium. In this paper, we discuss all aspects of the titanium industry from ore deposits through extraction to present and future applications. The methods of both primary (mining of ore, extraction, and purification) and secondary (forming and machining) operations will be analyzed. The chemical and physical properties of titanium metal will be briefly examined. Present and future applications for titanium will be discussed. Finally, the economics of titanium metal production also are analyzed as well as the advantages and disadvantages of various alternative extraction methods.

Gambogi, Joseph (USGS, Reston, VA); Gerdemann, Stephen J.

2002-09-01T23:59:59.000Z

438

Extraction of hemicelluloses from fiberized spruce wood  

Science Journals Connector (OSTI)

Abstract A novel mechanical pre-treatment method was used to separate the wood chips into fiber bundles in order to extract high molecular weight wood polymers. The mechanical pre-treatment involved chip compression in a conical plug-screw followed by defibration in a fiberizer. The fiberized wood was treated with hot water at various combinations of time and temperature in order to analyze the extraction yield of hemicelluloses at different conditions. Nearly 6 mg/g wood of galactoglucomannan was obtained at 90 °C/120 min which was about three times more than what could be extracted from wood chips. The extracted carbohydrates had molecular weight ranging up to 60 kDa. About 10% of each of the extracted material had a molecular weight above 30 kDa. The extraction liquor could also be reused for consecutive extractions with successive increase in the extraction yield of hemicelluloses.

Shoaib Azhar; Gunnar Henriksson; Hans Theliander; Mikael E. Lindström

2015-01-01T23:59:59.000Z

439

Flattening the B6H62- Octahedron. Ab Initio Prediction of a New Family of Planar All-Boron Aromatic Molecules  

Science Journals Connector (OSTI)

The structural chemistry of boron is dominated by 3D structures (polyhedra), while in carbon structural chemistry the planar aromatic structures are more abundant. In this Communication we present results of ab initio calculations showing that the ...

Anastassia N. Alexandrova; K. Alexander Birch; Alexander I. Boldyrev

2003-08-13T23:59:59.000Z

440

Synthesis of Aromatic-Rich Gasoline-Range Hydrocarbons from Biomass-Derived Syngas over a Pd-Promoted Fe/HZSM-5 Catalyst  

Science Journals Connector (OSTI)

Synthesis of Aromatic-Rich Gasoline-Range Hydrocarbons from Biomass-Derived Syngas over a Pd-Promoted Fe/HZSM-5 Catalyst ... The cool syngas was then compressed to a storage tank or sent to a burner. ...

Qiangu Yan; Yongwu Lu; Caixia Wan; Jun Han; Jose Rodriguez; Jing-jing Yin; Fei Yu

2014-02-26T23:59:59.000Z

Note: This page contains sample records for the topic "byproducts aromatic extracts" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Synthesis, Characterization, and Oxygenation Studies of Carboxylate-Bridged Diiron(II) Complexes with Aromatic Substrates Tethered to Pyridine Ligands and the Formation of a Unique Trinuclear Complex  

E-Print Network (OSTI)

In this study, diiron(II) complexes were synthesized as small molecule mimics of the reduced active sites in the hydroxylase components of bacterial multicomponent monooxygenases (BMMs). Tethered aromatic substrates were ...

Friedle, Simone

442

Polycyclic Aromatic Hydrocarbon Exposure in Household Air Pollution from Solid Fuel Combustion among the Female Population of Xuanwei and Fuyuan Counties, China  

Science Journals Connector (OSTI)

Exposure to polycyclic aromatic hydrocarbons (PAHs) from burning “smoky” (bituminous) coal has been implicated as a cause of the high lung cancer incidence in the counties of Xuanwei and Fuyuan, China. Little is known about variations in PAH exposure from ...

George S. Downward; Wei Hu; Nat Rothman; Boris Reiss; Guoping Wu; Fusheng Wei; Robert S. Chapman; Lutzen Portengen; Lan Qing; Roel Vermeulen

2014-11-13T23:59:59.000Z

443

The unusual hydrocarbon emission from the early carbon star HD 100764: The connection between aromatics and aliphatics  

E-Print Network (OSTI)

We have used the Infrared Spectrograph (IRS) on the Spitzer Space Telescope to obtain spectra of HD 100764, an apparently single carbon star with a circumstellar disk. The spectrum shows emission features from polycyclic aromatic hydrocarbons (PAHs) that are shifted to longer wavelengths than normally seen, as characteristic of ``class C'' systems in the classification scheme of Peeters et al. All seven of the known class C PAH sources are illuminated by radiation fields that are cooler than those which typically excite PAH emission features. The observed wavelength shifts are consistent with hydrocarbon mixtures containing both aromatic and aliphatic bonds. We propose that the class C PAH spectra are distinctive because the carbonaceous material has not been subjected to a strong ultraviolet radiation field, allowing relatively fragile aliphatic materials to survive.

G. C. Sloan; M. Jura; W. W. Duley; K. E. Kraemer; J. Bernard-Salas; W. J. Forrest; B. Sargent; A. Li; D. J. Barry; C. J. Bohac; D. M. Watson; J. R. Houck

2007-05-07T23:59:59.000Z

444

A correlation of water solubility in jet fuels with API gravity: aniline point percent aromatics, and temperature.  

E-Print Network (OSTI)

A CORRELATION OF WATER SOLUBILITY IN JET FUELS WITH API GRAVITY, ANILINE POINT PERCENT AROMATICS, AND TEMPERATURE A Thesis By ALONZO B YINGTON Submitted to the Graduate College of Texas A&M University in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE January, 1964 Major Subject: Petroleum Engineering A CORRELATION OF MATER SOLUBILITT IH JET FUELS WITS API GEAVITT, ANILINE POINT, PERCENT ARONATICS, AND TENPERATURE A Thesis By ALOHZO BYIHGTOH Approved...

Byington, Alonzo

2012-06-07T23:59:59.000Z

445

Nuclear reprogramming in cell–free extracts  

Science Journals Connector (OSTI)

...Gardner, M. A. Surani and D. Solter Nuclear reprogramming in cell-free extracts...reprogramming of a somatic cell using a nuclear and cytoplasmic extract derived from another...an extract from T cells is evidenced by nuclear uptake and the assembly of transcription...

2003-01-01T23:59:59.000Z

446

Terpenes as Green Solvents for Natural Products Extraction  

Science Journals Connector (OSTI)

This chapter presents a complete picture of current knowledge on useful and green bio-solvent “terpenes” obtained from aromatic plants and ... Terpenes could be a successful substitute for petroleum solvents, suc...

Chahrazed Boutekedjiret; Maryline Abert Vian…

2014-01-01T23:59:59.000Z

447

Highly efficient blue OLEDs based on diphenylaminofluorenylstyrenes end-capped with heterocyclic aromatics  

SciTech Connect

In this paper, we have designed four diphenylaminofluorenylstyrene derivatives end-capped with heterocyclic aromatic groups, such as 9-phenylcabazole, 4-dibenzofuran, 2-benzoxazole, 2-quinoxaline, respectively. These materials showed blue to red fluorescence with maximum emission wavelengths of 476–611 nm, respectively, which were dependent on the structural and electronic nature of end-capping groups. To explore the electroluminescent properties of these materials, multilayer OLEDs were fabricated in the following sequence: ITO/DNTPD (40 nm)/NPB (20 nm)/2% doped in MADN (20 nm)/Alq{sub 3} (40 nm)/Liq. (1 nm)/Al. Among those, a device exhibited a highly efficient blue emission with the maximum luminance of 14,480 cd/m{sup 2} at 9 V, the luminous efficiency of 5.38 cd/A at 20 mA/cm{sup 2}, power efficiency of 2.77 lm/W at 20 mA/cm{sup 2}, and CIE{sub x,y} coordinates of (0.147, 0.152) at 8 V, respectively.

Oh, Suhyun [Department of Chemistry, Sungkyunkwan University, Suwon 440-746 (Korea, Republic of)] [Department of Chemistry, Sungkyunkwan University, Suwon 440-746 (Korea, Republic of); Lee, Kum Hee; Kim, Young Kwan [Department of Information Display, Hongik University, Seoul 121-791 (Korea, Republic of)] [Department of Information Display, Hongik University, Seoul 121-791 (Korea, Republic of); Yoon, Seung Soo, E-mail: ssyoon@skku.edu [Department of Chemistry, Sungkyunkwan University, Suwon 440-746 (Korea, Republic of)

2012-10-15T23:59:59.000Z

448

Polycyclic aromatic hydrocarbons (PAHs) in burning and non-burning coal waste piles  

Science Journals Connector (OSTI)

The coal waste material that results from Douro Coalfield exploitation was analyzed by gas chromatography with mass spectrometry (GC–MS) for the identification and quantification of the 16 polycyclic aromatic hydrocarbons (PAHs), defined as priority pollutants. It is expected that the organic fraction of the coal waste material contains \\{PAHs\\} from petrogenic origin, and also from pyrolytic origin in burning coal waste piles. The results demonstrate some similarity in the studied samples, being phenanthrene the most abundant PAH followed by fluoranthene and pyrene. A petrogenic contribution of \\{PAHs\\} in unburned samples and a mixture of \\{PAHs\\} from petrogenic and pyrolytic sources in the burning/burnt samples were identified. The lowest values of the sum of the 16 priority \\{PAHs\\} found in burning/burnt samples and the depletion LMW \\{PAHs\\} and greater abundance of HMW \\{PAHs\\} from the unburned coal waste material relatively to the burning/burnt material demonstrate the thermal transformation attributed to the burning process. The potential environmental impact associated with the coal waste piles are related with the release of petrogenic and pyrolytic \\{PAHs\\} in particulate and gaseous forms to soils, sediments, groundwater, surface water, and biodiversity.

Joana Ribeiro; Tais Silva; Joao Graciano Mendonca Filho; Deolinda Flores

2012-01-01T23:59:59.000Z

449

A single domain thermophilic xylanase can bind insoluble xylan: evidence for surface aromatic clusters  

Science Journals Connector (OSTI)

A clone expressing xylanase activity in Escherichia coli has been selected from a genomic plasmid library of the thermophilic Bacillus strain D3. Subcloning from the 9-kb insert located the xylanase activity to a 2.7-kb HindII/BamHI fragment. The DNA sequence of this clone revealed an ORF of 367 codons encoding a single domain type-F or family 10 enzyme, which was designated as XynA. Purification of the enzyme following over-expression in E. coli produced an enzyme of 42 kDa with a temperature optimum of 75°C which can efficiently bind and hydrolyse insoluble xylan. The pH optimum of the enzyme is 6.5, but it is active over a broad pH range. A homology model of the xylanase has been constructed which reveals a series of surface aromatic residues which form hydrophobic clusters. This unusual structural feature is strikingly similar to the situation observed in the structure determined for the type-G xylanase from the Bacillus D3 strain and may constitute a common evolutionary mechanism imposed on different structural frameworks by which these xylanases may bind potential substrates and exhibit thermostability.

Ian Connerton; Nicola Cummings; Gillian W. Harris; Philippe Debeire; Christelle Breton

1999-01-01T23:59:59.000Z

450

Measurement of polynuclear aromatic hydrocarbon concentrations in the plume of Kuwait oil well fires  

SciTech Connect

Following their retreat from Kuwait during February and March of 1991, the Iraqi Army set fire to over 500 oil wells dispersed throughout the Kuwait oil fields. During the period of sampling from July to August 1991, it was estimated that between 3.29 {times} 10{sup 6} barrels per day of crude oil were combusted. The resulting fires produced several plumes of black and white smoke that coalesced to form a composite ``super`` plume. Because these fires were uncontrolled, significant quantities of organic materials were dispersed into the atmosphere and drifted throughout the Middle East. The organic particulants associated with the plume of the oil well fires had a potential to be rich in polynuclear aromatic hydrocarbon (PAH) compounds. Based on the extreme mutagenic and carcinogenic activities of PAHs found in laboratory testing, a serious health threat to the population of that region potentially existed. Furthermore, the Kuwait oil fire plumes represented a unique opportunity to study the atmospheric chemistry associated with PAHs in the plume. If samples were collected near the plume source and from the plume many kilometers downwind from the source, comparisons could be made to better understand atmospheric reactions associated with particle-bound and gas-phase PAHs. To help answer health-related concerns and to better understand the fate and transport of PAHs in an atmospheric environment, a sampling and analysis program was developed.

Olsen, K.B.; Wright, C.W.; Veverka, C. [Pacific Northwest Lab., Richland, WA (United States); Ball, J.C. [Ford Motor Co., Dearborn, MI (United States). Scientific Research Lab.; Stevens, R. [US Environmental Protection Agency (United States). Atmospheric Research and Exposure Assessment Lab.

1995-03-01T23:59:59.000Z

451

Reaction of aromatic compounds and coal-derived liquids with steam over alumina supported nickel catalysts  

SciTech Connect

The objective of this research program has been to explore and define the potential of steam reforming to produce light gases from coal-derived liquids. This was achieved through a study of the reaction of a model aromatic compound and of a coal-derived liquid with steam over an alumina supported nickel catalyst. The reaction of steam with benzene and SRC-II liquids over an alumina supported nickel-catalyst has been investigated in a plug flow reactor. The primary process variables investigated were reactor pressure and temperature, contact time, and steam/carbon ratio. A proposed reaction network was also developed to explain the data obtained in this study. The empirical rate equation for the benzene steam reforming reaction at 973 K, 300 psig, and a steam/carbon ratio of approximately 3 was r/sub C6H6/ = 1.92 x 10 TP/sub C6H6/. The activation energy was 88 KJ/mol, or 21 kcal/mol in the temperature range 748-973 K. A correlation was developed to predict product yields and hydrocarbon conversion over the range of process variables investigated. A second correlation was developed to predict the yields and conversion beyond the range of variables investigated.

Chen, I.E.

1985-01-01T23:59:59.000Z

452

POLYCYCLIC AROMATIC HYDROCARBON EMISSION IN THE PROPLYD HST10: WHAT IS THE MECHANISM BEHIND PHOTOEVAPORATION?  

SciTech Connect

Proplyds are photodissociation-region-(PDR)-like cometary cocoons around young stars which are thought to originate through photoevaporation of the central protoplanetary disk by external UV radiation from the nearby OB stars. This Letter presents spatially resolved mid-infrared imaging and spectroscopy of the proplyd HST10 obtained with the Very Large Telescope/VISIR instrument. These observations allow us to detect polycyclic aromatic hydrocarbon (PAH) emission in the proplyd PDR and to study the general properties of PAHs in proplyds for the first time. We find that PAHs in HST10 are mostly neutral and at least 50 times less abundant than typical values found for the diffuse interstellar medium or the nearby Orion Bar. With such a low PAH abundance, photoelectric heating is significantly reduced. If this low abundance pertains also to the original disk material, gas heating rates could be too low to efficiently drive photoevaporation unless other processes can be identified. Alternatively, the model behind the formation of proplyds as evaporating disks may have to be revised.

Vicente, S.; Kamp, I. [Kapteyn Astronomical Institute, Postbus 800, 9700 AV, Groningen (Netherlands); Berne, O. [Universite de Toulouse, UPS-OMP, IRAP, Toulouse (France); Tielens, A. G. G. M. [Leiden Observatory, Leiden University, Niels Bohrweg 2, NL-2333 CA Leiden (Netherlands); Huelamo, N. [CAB (INTA-CSIC), LAEFF, P.O. Box 78, E-28691 Villanueva de la Canada, Madrid (Spain); Pantin, E. [Laboratoire AIM, CEA/DSM - CNRS - Universite Paris Diderot, IRFU/SAP, F-91191 sur Yvette (France); Carmona, A. [UJF-Grenoble 1/CNRS-INSU, Institut de Planetologie et d'Astrophysique de Grenoble (IPAG) UMR 5274, Grenoble, F-38041 (France)

2013-03-10T23:59:59.000Z

453

FCC Tail Gas olefins conversion to gasoline via catalytic distillation with aromatics  

SciTech Connect

The goal of every refiner is to continually improve profitability by such means as increasing gasoline production, increasing gasoline octane pool and in cases where fuel balance becomes a problem, decreasing refinery fuel gas production. A new refinery process is currently being developed which accomplish these goals. Chemical Research and Licensing Company (CR and L) developed Catalytic Distillation technology in 1978 to produce MTBE. They have since used the Catalytic Distillation technique to produce cumene. CR and L has further developed this technology to convert olefin gases currently consumed as refinery fuel, to high octane gasoline components. The process, known as CATSTILL, alkylates olefin gases such as ethylene, propylene and butylene, present in FCC Tail Gas with light aromatics such as benzene, toluene and xylene, present in reformate, to produce additional quantities of high octane gasoline components. A portable CATSTILL demonstration plant has been constructed by Brown and Root U.S.A., under an agreement with CR and L, for placement in a refinery to further develop data necessary to design commercial plants. This paper presents current data relative to the CATSTILL development.

Partin, E.E. (Brown and Root U.S.A., Inc., Houston, TX (US))

1988-01-01T23:59:59.000Z

454

Hydrogenation of aromatics in synthetic crude distillates catalyzed by platinum supported in molecular sieves  

SciTech Connect

Catalytic hydrogenation of synthetic crude distillates from Canadian oil sands was carried out over platinum metal supported in pillared interlayered clay (PILC) and Y-zeolite. The molecular sieve supports were employed to modify the properties of dispersed platinum particles and improve their resistance to poisoning by sulfur. The objective was to reduce the distillate aromatic content to meet diesel emission control standards and cetane number requirements. Catalysts were prepared in a series of steps, and metal precursor was loaded using ion-exchange procedures. Characterization was done using X-ray diffraction, hydrogen chemisorption, and proton-induced X-ray emission elemental analysis. Catalytic hydrogenation reactions were carried out by processing distillate feedstocks both high (>100 ppm) and low (<10 ppm) in sulfur using a continuous-flow automated microreactor system. Experimental runs were performed to determine the reaction kinetics and Arrhenius parameters as a means of evaluating and comparing catalyst performance. Significant differences in catalyst activity were found. The Pt/Y-zeolite-alumina catalyst showed a much superior hydrogenation performance under conditions of high sulfur content. The extent of cracking and ring opening was also evaluated and was shown to be minimal under the operating conditions employed.

Kimbara, N.; Charland, J.P. [CANMET, Ottawa, Ontario (Canada)] [CANMET, Ottawa, Ontario (Canada); Wilson, M.F. [CANMET, Devon, Alberta (Canada)] [CANMET, Devon, Alberta (Canada)

1996-11-01T23:59:59.000Z

455

Removal of polycyclic aromatic hydrocarbons from surfactant solutions by selective sorption with organo-bentonite  

Science Journals Connector (OSTI)

Abstract Surfactant-enhanced soil washing is known to be an effective remediation approach for contaminated soils and groundwater. However, the recovery of surfactant solutions after soil washing is required for reducing the operation costs of the soil washing process. In this study, selective sorption with organo-bentonite was employed for the removal of polycyclic aromatic hydrocarbons (PAHs) from aqueous surfactant solution as a potential means of recovering surfactant solution after soil washing. The sorption of phenanthrene onto organo-bentonite from surfactant solution was well described by the pseudo-second-order kinetic model and the linear sorption isotherm model, respectively. \\{PAHs\\} can be effectively removed by organo-bentonite from surfactant solutions in a high proportion relative to the sorption loss of surfactant under all experimental conditions. The selectivity for PAH removal to surfactant sorption increased with increasing PAH hydrophobicity and surfactant hydrophilicity, but decreased with increasing surfactant concentration. However, increasing the organo-bentonite dose did not have obvious effect on the selectivity for surfactant recovery since it synchronously enhanced phenanthrene removal and surfactant sorption. The sorbent of organo-bentonite could be repeatedly used for recovering surfactant solution, which greatly reduced the sorption loss of surfactant and subsequently increased the selectivity for surfactant recovery considerably. The results suggest that selective sorption with organo-bentonite provides an alternative means of recovering surfactant solution after soil washing.

Wenjun Zhou; Xuehao Wang; Cuiping Chen; Lizhong Zhu

2013-01-01T23:59:59.000Z

456

DEVELOPMENT OF CONTINUOUS SOLVENT EXTRACTION PROCESSES FOR COAL DERIVED CARBON PRODUCTS  

SciTech Connect

The purpose of this DOE-funded effort is to develop continuous processes for solvent extraction of coal for the production of carbon products. The largest applications are those which support metals smelting, such as anodes for aluminum smelting and electrodes for arc furnaces. Other carbon products include materials used in creating fuels for the Direct Carbon Fuel Cell, metals smelting, especially in the aluminum and steel industries, as well as porous carbon structural material referred to as ''carbon foam'' and carbon fibers. During this reporting period, coking and composite fabrication continued using coal-derived samples. These samples were tested in direct carbon fuel cells. Methodology was refined for determining the aromatic character of hydro treated liquid, based on Nuclear Magnetic Resonance (NMR) and Fourier Transform Infrared (FTIR). Tests at GrafTech International showed that binder pitches produced using the WVU solvent extraction protocol can result in acceptable graphite electrodes for use in arc furnaces. These tests were made at the pilot scale.

Elliot B. Kennel; R. Michael Bergen; Stephen P. Carpenter; Dady Dadyburjor; Manoj Katakdaunde; Liviu Magean; Alfred H. Stiller; W. Morgan Summers; John W. Zondlo

2006-05-12T23:59:59.000Z

457

PRODUCTION OF FOAMS, FIBERS AND PITCHES USING A COAL EXTRACTION PROCESS  

SciTech Connect

This Department of Energy National Energy Technology Laboratory sponsored project developed processes for converting coal feedstocks to carbon products, including coal-derived pitch, coke foams and fibers based on solvent extraction processes. A key technology is the use of hydrogenation accomplished at elevated temperatures and pressures to obtain a synthetic coal pitch. Hydrogenation, or partial direct liquefaction of coal, is used to modify the properties of raw coal such that a molten synthetic pitch can be obtained. The amount of hydrogen required to produce a synthetic pitch is about an order of magnitude less than the amount required to produce synthetic crude oil. Hence the conditions for synthetic pitch production consume very little hydrogen and can be accomplished at substantially lower pressure. In the molten state, hot filtration or centrifugation can be used to separate dissolved coal chemicals from mineral matter and insolubles (inertinite), resulting in the production of a purified hydrocarbon pitch. Alternatively, if hydrogenation is not used, aromatic hydrocarbon liquids appropriate for use as precursors to carbon products can obtained by dissolving coal in a solvent. As in the case for partial direct liquefaction pitches, undissolved coal is removed via hot filtration or centrifugation. Excess solvent is boiled off and recovered. The resultant solid material, referred to as Solvent Extracted Carbon Ore or SECO, has been used successfully to produce artificial graphite and carbon foam.

Chong Chen; Elliot B. Kennel; Liviu Magean; Pete G. Stansberry; Alfred H. Stiller; John W. Zondlo

2004-06-20T23:59:59.000Z

458

Organic substances in produced and formation water from unconventional natural gas extraction in coal and shale  

Science Journals Connector (OSTI)

Abstract Organic substances in produced and formation water from coalbed methane (CBM) and gas shale plays from across the USA were examined in this study. Disposal of produced waters from gas extraction in coal and shale is an important environmental issue because of the large volumes of water involved and the variable quality of this water. Organic substances in produced water may be environmentally relevant as pollutants, but have been little studied. Results from five CBM plays and two gas shale plays (including the Marcellus Shale) show a myriad of organic chemicals present in the produced and formation water. Organic compound classes present in produced and formation water in CBM plays include: polycyclic aromatic hydrocarbons (PAHs), heterocyclic compounds, alkyl phenols, aromatic amines, alkyl aromatics (alkyl benzenes, alkyl biphenyls), long-chain fatty acids, and aliphatic hydrocarbons. Concentrations of individual compounds range from CBM samples) range from 50 to 100 ?g/L. Total dissolved organic carbon (TOC) in CBM produced water is generally in the 1–4 mg/L range. Excursions from this general pattern in produced waters from individual wells arise from contaminants introduced by production activities (oils, grease, adhesives, etc.). Organic substances in produced and formation water from gas shale unimpacted by production chemicals have a similar range of compound classes as CBM produced water, and TOC levels of about 8 mg/L. However, produced water from the Marcellus Shale using hydraulic fracturing has TOC levels as high as 5500 mg/L and a range of added organic chemicals including, solvents, biocides, scale inhibitors, and other organic chemicals at levels of 1000 s of ?g/L for individual compounds. Levels of these hydraulic fracturing chemicals and TOC decrease rapidly over the first 20 days of water recovery and some level of residual organic contaminants remain up to 250 days after hydraulic fracturing. Although the environmental impacts of the organics in produced water are not well defined, results suggest that care should be exercised in the disposal and release of produced waters containing these organic substances into the environment because of the potential toxicity of many of these substances.

William Orem; Calin Tatu; Matthew Varonka; Harry Lerch; Anne Bates; Mark Engle; Lynn Crosby; Jennifer McIntosh

2014-01-01T23:59:59.000Z

459

EXTINCTION AND POLYCYCLIC AROMATIC HYDROCARBON INTENSITY VARIATIONS ACROSS THE H II REGION IRAS 12063-6259  

SciTech Connect

The spatial variations in polycyclic aromatic hydrocarbon (PAH) band intensities are normally attributed to the physical conditions of the emitting PAHs, however in recent years it has been suggested that such variations are caused mainly by extinction. To resolve this question, we have obtained near-infrared (NIR), mid-infrared (MIR), and radio observations of the compact H II region IRAS 12063-6259. We use these data to construct multiple independent extinction maps and also to measure the main PAH features (6.2, 7.7, 8.6, and 11.2 {mu}m) in the MIR. Three extinction maps are derived: the first using the NIR hydrogen lines and case B recombination theory; the second combining the NIR data with radio data; and the third making use of the Spitzer/IRS MIR observations to measure the 9.8 {mu}m silicate absorption feature using the Spoon method and PAHFIT (as the depth of this feature can be related to overall extinction). The silicate absorption over the bright, southern component of IRAS 12063-6259 is almost absent while the other methods find significant extinction. While such breakdowns of the relationship between the NIR extinction and the 9.8 {mu}m absorption have been observed in molecular clouds, they have never been observed for H II regions. We then compare the PAH intensity variations in the Spitzer/IRS data after dereddening to those found in the original data. It was found that in most cases, the PAH band intensity variations persist even after dereddening, implying that extinction is not the main cause of the PAH band intensity variations.

Stock, D. J.; Peeters, E.; Otaguro, J. N. [Department of Physics and Astronomy, University of Western Ontario, London, ON N6A 3K7 (Canada); Tielens, A. G. G. M. [Leiden Observatory, Leiden University, P.O. Box 9513, NL-2300 RA Leiden (Netherlands); Bik, A. [Max-Planck-Institut fuer Astronomie, Koenigstuhl 17, D-69117 Heidelberg (Germany)

2013-07-01T23:59:59.000Z

460

Atmospheric distribution of polycyclic aromatic hydrocarbons and deposition to Galveston Bay, Texas, USA  

Science Journals Connector (OSTI)

Estimates of the atmospheric deposition to Galveston Bay of polycyclic aromatic hydrocarbons (PAHs) are made using precipitation and meteorological data that were collected continuously from 2 February 1995 to 6 August 1996 at Seabrook, TX, USA. Particulate and vapor phase \\{PAHs\\} in ambient air and particulate and dissolved phases in rain samples were collected and analyzed. More than 95% of atmospheric \\{PAHs\\} were in the vapor phase and about 73% of \\{PAHs\\} in the rain were in the dissolved phase. Phenanthrene and napthalene were the dominant compounds in air vapor and rain dissolved phases, respectively, while 5 and 6 ring PAH were predominant in the particulate phase of both air and rain samples. Total PAH concentrations ranged from 4 to 161 ng m?3 in air samples and from 50 to 312 ng l?1 in rain samples. Temporal variability in total PAH air concentrations were observed, with lower concentrations in the spring and fall (4–34 ng m ?3) compared to the summer and winter (37–161 ng m?3). \\{PAHs\\} in the air near Galveston Bay are derived from both combustion and petroleum vaporization. Gas exchange from the atmosphere to the surface water is estimated to be the major deposition process for \\{PAHs\\} (1211 ?g m? 2 yr? 1), relative to wet deposition (130 ?g m?2 yr? 1) and dry deposition (99 ?g m?2 yr? 1). Annual deposition of \\{PAHs\\} directly to Galveston Bay from the atmosphere is estimated as 2  t yr?1.

June-Soo Park; Terry L. Wade; Stephen Sweet

2001-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "byproducts aromatic extracts" from the National Library of EnergyBeta (NLEBeta).
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461

Polycyclic aromatic hydrocarbons in fresh and smoked fish samples from three Nigerian cities  

SciTech Connect

Nigeria is a major producer of crude oil in sub-Saharan Africa. In-shore and off-shore wells are located in richly watered creeks in the southern part of the country. Although published data on environmental impact assessment of the petroleum industry in Nigeria are lacking, there is a growing concern about the possible contamination of estuarine and coastal waters and of marine species by polycyclic aromatic hydrocarbon (PAHs). PAHs are ubiquitous priority pollutants that occur naturally in crude oil, automobile exhaust emissions and smoke condensates from incomplete combustion of carbonaceous materials. PAHs with high molecular weight are less readily biodegraded by indigenous microorganisms in some regions, and given their marked hydrophobic characteristics, may persist in the aqueous environment, thus contaminating the food chain by bioaccumulating in aquatic species like fish and mussels. Major Nigerian oil wells are located in the vicinity of breeding and harvesting sites serving the fresh-water fishing industry. Large hauls of fresh fish are normally consumed cooked in soups or smoke cured in handcrafted traditional ovens using freshly cut red mangrove (Rhizophora racemosa) wood as fuel. Though smoke curing is economical and may ensure longer conservation of fish, it undoubtedly increases the burden of PAHs in finished products as a result of partial charring and from smoke condensates or mangroves that also contain PAHs in measurable quantities as reported by Asita et al. (1991). Apart from PAHs analyzed by Emerole (1980) in smoked food samples from Ibadan using simple analytical methods, those from industrial and other anthropogenic sources have rarely been analyzed in Nigeria. We tried therefore to update the data and address this discrepancy. 14 refs., 4 figs., 2 tabs.

Akpan, V.; Lodovici, M.; Dolara, P. (Dept. of Pharmacology and Toxicology, Florence (Italy))

1994-08-01T23:59:59.000Z

462

Suppression of autophagy enhances the cytotoxicity of the DNA-damaging aromatic amine p-anilinoaniline  

SciTech Connect

p-Anilinoaniline (pAA) is an aromatic amine that is widely used in hair dying applications. It is also a metabolite of metanil yellow, an azo dye that is commonly used as a food coloring agent. Concentrations of pAA between 10 and 25 {mu}M were cytostatic to cultures of the normal human mammary epithelia cell line MCF10A. Concentrations {>=} 50 {mu}M were cytotoxic. Cytostatic concentrations induced transient G{sub 1} and S cell cycle phase arrests; whereas cytotoxic concentrations induced protracted arrests. Cytotoxic concentrations of pAA caused DNA damage, as monitored by the alkaline single-cell gel electrophoresis (Comet) assay, and morphological changes consistent with cells undergoing apoptosis and/or autophagy. Enzymatic and western blot analyses, and binding analyses of fluorescent labeled VAD-FMK, suggested that caspase family members were activated by pAA. Western blot analyses documented the conversion of LC3-I to LC3-II, a post-translational modification involved in the development of the autophagosome. Suppression of autophagosome formation, via knockdown of ATG7 with shRNA, prevented pAA-induced vacuolization, enhanced the activation of pro-caspase-3, and increased susceptibility of ATG7-deficient cells to the cytostatic and cytotoxic activities of markedly lower concentrations of pAA. Cells stably transfected with a nonsense shRNA behaved like parental MCF10A cells. Collectively, these data suggest that MCF10A cultures undergo autophagy as a pro-survival response to concentrations of pAA sufficient to induce DNA damage.

Elliott, Althea [Institute of Environmental Health Sciences, Wayne State University, Detroit, MI 48201 (United States); Reiners, John J. [Institute of Environmental Health Sciences, Wayne State University, Detroit, MI 48201 (United States)], E-mail: john.reiners.jr@wayne.edu

2008-10-15T23:59:59.000Z

463

Combined transuranic-strontium extraction process  

DOE Patents (OSTI)

The transuranic (TRU) elements neptunium, plutonium and americium can be separated together with strontium from nitric acid waste solutions in a single process. An extractant solution of a crown ether and an alkyl(phenyl)-N,N-dialkylcarbanylmethylphosphine oxide in an appropriate diluent will extract the TRU's together with strontium, uranium and technetium. The TRU's and the strontium can then be selectively stripped from the extractant for disposal.

Horwitz, E. Philip (Naperville, IL); Dietz, Mark L. (Evanston, IL)

1992-01-01T23:59:59.000Z

464

Direct enzymatic extraction of starch from corn as an energy saving alternative to production of high fructose syrup. Final executive report  

SciTech Connect

The purpose of this project was to study, test, and demonstrate a process of producing high-fructose corn syrup and protein byproducts from dry milled corn as an energy conserving alternative of the current industrial corn wet-milling process. This final report is divided into 5 sections. Section 1 deals with the process which is the main and, indeed, the final product of the energy conservation study. Section 2 deals with protein Extraction which conditions the dry-milled corn before hydrolysis. Section 3 deals with the analytical technique of GPC developed with the alpha-amylase hydrolysis of starch. Section 4 deals with immobilized glucoamylase hydrolysis. Section 5 deals with the recovery of soluble protein by ion-exchange resins. Each section has been abstracted separately for inclusion in the Energy Data Base. (DMC)

Not Available

1982-12-01T23:59:59.000Z

465

Determination of Extractives in Biomass: Laboratory Analytical...  

NLE Websites -- All DOE Office Websites (Extended Search)

Extractives in Biomass Laboratory Analytical Procedure (LAP) Issue Date: 7172005 A. Sluiter, R. Ruiz, C. Scarlata, J. Sluiter, and D. Templeton Technical Report NRELTP-510-42619...

466

Ocean Thermal Extractable Energy Visualization: Final Technical...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Approved for public release; distribution is unlimited OCEAN THERMAL EXTRACTABLE ENERGY VISUALIZATION Award DE-EE0002664 October 28, 2012 Final Technical Report Prepared by...

467

Aqueous Enzymatic Extraction Of Wheat Germ Oil.  

E-Print Network (OSTI)

??The objective of this study is to investigate the aqueous enzymatic extraction of wheat germ oil. Four enzymes (Viscozyme L, Multifect CX 13l, Multifect CX… (more)

Xie, Meizhen

2009-01-01T23:59:59.000Z

468

Nafion-H® catalyzed efficient condensation of indoles with aromatic aldehydes in PEG-water solvent system: A green approach  

Science Journals Connector (OSTI)

Abstract Nafion-H® has been used as an efficient and reusable catalyst for an improved and rapid synthesis of bis(indolyl)methanes from electrophilic substitution of indoles with aromatic aldehydes using PEG-400:water system as medium. This methodology offered remarkable improvements in the synthesis of bis(indolyl)methanes with regard to the yield of the products, operational simplicity and green aspects by avoiding the use of expensive, toxic catalysts and solvents. Also the catalyst could be recovered after the completion of reaction and reused several times without any significant loss in its catalytic potential.

Mazaahir Kidwai; Ritika Chauhan; Divya Bhatnagar

2014-01-01T23:59:59.000Z

469

Sources of local variation in polynuclear aromatic hydrocarbon and pesticide body burden in oysters (Crassostrea virginica) from Galveston Bay, Texas  

Science Journals Connector (OSTI)

1. Eggs and sperm contain significantly more PAH (polynuclear aromatic hydrocarbon) than somatic tissues in oysters (Crassostrea virginica) taken from Galveston Bay. 2. The quantity of gonadal material was the most important correlate of PAH body burden. 3. Eggs, but not sperm, were enriched in chlorinated compounds (e.g. DDD, chlordane), while both eggs and sperm were enriched in total \\{PCBs\\} relative to somatic tissue. 4. Oysters may lose up to 50% of their total body burden of certain \\{PAHs\\} and pesticides in a single spawn.

Matthew S. Ellis; Kwang-Sik Choi; Terry L. Wade; Eric N. Powell; Thomas J. Jackson; Donald H. Lewis

1993-01-01T23:59:59.000Z

470

INFRARED LUMINOSITIES AND AROMATIC FEATURES IN THE 24 {mu}m FLUX-LIMITED SAMPLE OF 5MUSES  

SciTech Connect

We study a 24 {mu}m selected sample of 330 galaxies observed with the infrared spectrograph for the 5 mJy Unbiased Spitzer Extragalactic Survey. We estimate accurate total infrared luminosities by combining mid-IR spectroscopy and mid-to-far infrared photometry, and by utilizing new empirical spectral templates from Spitzer data. The infrared luminosities of this sample range mostly from 10{sup 9} L{sub sun} to 10{sup 13.5} L{sub sun}, with 83% in the range 10{sup 10} L{sub sun} < L{sub IR} < 10{sup 12} L{sub sun}. The redshifts range from 0.008 to 4.27, with a median of 0.144. The equivalent widths of the 6.2 {mu}m aromatic feature have a bimodal distribution, probably related to selection effects. We use the 6.2 {mu}m polycyclic aromatic hydrocarbon equivalent width (PAH EW) to classify our objects as starburst (SB)-dominated (44%), SB-AGN composite (22%), and active galactic nucleus (AGN)-dominated (34%). The high EW objects (SB-dominated) tend to have steeper mid-IR to far-IR spectral slopes and lower L{sub IR} and redshifts. The low EW objects (AGN-dominated) tend to have less steep spectral slopes and higher L{sub IR} and redshifts. This dichotomy leads to a gross correlation between EW and slope, which does not hold within either group. AGN-dominated sources tend to have lower log(L{sub PAH7.7{sub {mu}m}}/L{sub PAH11.3{sub {mu}m}}) ratios than star-forming galaxies, possibly due to preferential destruction of the smaller aromatics by the AGN. The log(L{sub PAH7.7{sub {mu}m}}/L{sub PAH11.3{sub {mu}m}}) ratios for star-forming galaxies are lower in our sample than the ratios measured from the nuclear spectra of nearby normal galaxies, most probably indicating a difference in the ionization state or grain size distribution between the nuclear regions and the entire galaxy. Finally, we provide a calibration relating the monochromatic continuum or aromatic feature luminosity to L{sub IR} for different types of objects.

Wu Yanling; Helou, George; Shi Yong, E-mail: yanling@ipac.caltech.ed, E-mail: gxh@ipac.caltech.ed, E-mail: yong@ipac.caltech.ed [Infrared Processing and Analysis Center, California Institute of Technology, 1200 East California Boulevard, Pasadena, CA 91125 (United States)

2010-11-01T23:59:59.000Z

471

Multisolvent successive extractive refining of coal  

SciTech Connect

A selected group of commercial solvents, namely, anthracene oil (AO), ethylenediamine (EDA), and liquid paraffin (LP), were used for successive extraction of Assam coal. Hot AO provided a wide range of mixed solvents that dissociate chemically and interact favorably with dissociated and undissociated coal macromolecules (like dissolves like). This resulted in the enhancement of the EDA extractability of the AO-pretreated residual coal. EDA is a good swelling solvent and results in physical dissociation of coal molecules. The residual coal obtained after EDA extraction was subjected to extraction with LP, an H-donor, high-boiling (330--360 C) solvent. LP thermally dissociates coal macromolecules and interacts with the coal at its plastic stage at the free radical pockets. The mechanism and molecular dynamics of the multisolvent successive extraction of Assam coal using AO-EDA-LP solvents are discussed. In early attempts, successive extractions did not modify the extraction yield in the single solvent showing the maximum extraction. However, the AO-EDA-LP extraction resulted in the extraction of 70% coal, more than for any of the individual solvents used. Therefore, AO-EDA-LP extraction of coal affords a process yielding a superclean, high-heating value fuel from coal under milder conditions. Several uses of superclean coal have been recommended. Present studies have revealed a new concept concerning the structure of coal having 30% polyaromatic condensed entangled rings and 70% triaromatic-heterocyclic-naphthenic-aliphatic structure. The insolubility of coal is due to the polyfunctional-heterocyclic-condensed structure having a polyaromatic core with intermacromolecular entanglements.

Sharma, D.K.; Singh, S.K. [Indian Inst. of Tech., New Delhi (India)

1996-01-01T23:59:59.000Z

472

Advances in the design of co-poly(ether-imide) membranes for CO2 separations. Influence of aromatic rigidity on crystallinity, phase segregation and gas transport  

Science Journals Connector (OSTI)

Abstract In our previous works, it was observed a clear relationship between the structure and the properties for different copoly(ether-imide)s, besides a good relation was found between SAXS characterization and permeability results. Here, a series of aliphatic aromatic copoly(ether-imide)s, based on an aromatic diamine (ODA), a diamine terminated poly(ethylene oxide) (PEO2000) of a molecular weight of 2000 g/mol and different aromatic dianhydrides (BPDA, BKDA (or BTDA) and PMDA) has been synthesized and characterized. The permeability for O2, N2, CO2 and CH4, increased with the rigidity of the monomers (BKDA CO2/N2 separation. This work gives indications on how to design advanced materials for this separation with the increasing possibilities of controlled structure and properties.

Alberto Tena; Ángel Marcos-Fernández; Mónica de la Viuda; Laura Palacio; Pedro Prádanos; Ángel E. Lozano; Javier de Abajo; Antonio Hernández

2015-01-01T23:59:59.000Z

473

Review of information extraction technologies and applications  

Science Journals Connector (OSTI)

Information extraction (IE) is an important and growing field, in part because of the development of ubiquitous social media networking millions of people and producing huge collections of textual information. Mined information is being used in a wide ... Keywords: Adaptive computing, Big Data, Computational linguistics, Information extraction, Information retrieval, Machine learning, Neural computing, Web IE, Web information analysis

Sharon Gower Small, Larry Medsker

2014-09-01T23:59:59.000Z

474

Determination of absolute molecular mass distribution and other structural properties of kraft lignin samples.  

E-Print Network (OSTI)

?? Lignin is an aromatic macromolecule present in wood and also a by-product in the process of making paper. For a long time, this by-product… (more)

Chedid, Fadia

2010-01-01T23:59:59.000Z

475

Natural Gas Total Liquids Extracted  

U.S. Energy Information Administration (EIA) Indexed Site

Thousand Barrels) Thousand Barrels) Data Series: Natural Gas Processed Total Liquids Extracted NGPL Production, Gaseous Equivalent Period: Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Data Series Area 2007 2008 2009 2010 2011 2012 View History U.S. 658,291 673,677 720,612 749,095 792,481 873,563 1983-2012 Alabama 13,381 11,753 11,667 13,065 1983-2010 Alaska 22,419 20,779 19,542 17,798 18,314 18,339 1983-2012 Arkansas 126 103 125 160 212 336 1983-2012 California 11,388 11,179 11,042 10,400 9,831 9,923 1983-2012 Colorado 27,447 37,804 47,705 57,924 1983-2010 Florida 103 16 1983-2008 Illinois 38 33 24 231 705 0 1983-2012

476

Size exclusion chromatography for the unambiguous detection of aliphatics in fractions from petroleum vacuum residues, coal liquids, and standard materials, in the presence of aromatics  

SciTech Connect

A method has been developed using size exclusion chromatography (SEC) in heptane eluent that can detect aliphatics unambiguously without fractionation to remove aromatics. Spherical molecules such as colloidal silicas elute at the exclusion limit, while alkanes up to C{sub 50} elute through the porosity of the column. Detection of aliphatics was defined by use of an evaporative light scattering (ELS) detector with the simultaneous absence of UV absorbance at 300 nm. Alkanes smaller than C{sub 12} were not detected because the conditions of operation of the ELS caused their evaporation. All aromatics eluted after the permeation limit of about 25 min and were not detected until well after 45 min by their UV absorbance. The SEC method was applied to petroleum vacuum residues and coal liquids, and their fractions were soluble in pentane or heptane. High-temperature (HT) GC-MS confirmed the presence of alkanes in the pentane- and heptane-soluble fractions of petroleum vacuum residues, but did not elute any of the aromatics known to be present from SEC. Alkanes were examined in pentane-soluble fractions of a coal digest and a low-temperature coal tar; alkanes up to C{sub 40} were detected in the low-temperature tar and, although present in the digest, were masked by aromatics. No alkanes were detected by either SEC or HT GC-MS in fractions from a coal tar pitch. Aromatics in coal liquids and one petroleum residue were also examined by SEC using NMP as eluent and by UV fluorescence spectroscopy. The SEC method will find application to pentane- and heptane-soluble fractions of petroleum liquids and coal liquids where the alkanes are concentrated relative to the more abundant aromatics. 43 refs., 10 figs., 2 tabs.

Eiman M. Al-Muhareb; Fatma Karaca; Trevor J. Morgan; Alan A. Herod; Ian D. Bull; Rafael Kandiyoti [Imperial College, London (United Kingdom). Department of Chemical Engineering

2006-05-15T23:59:59.000Z

477

Biomarker sensitivity for polynuclear aromatic hydrocarbon contamination in two marine fish species collected in Galveston Bay, Texas  

SciTech Connect

The Galveston Bay estuary exhibited a contamination gradient for polynuclear aromatic hydrocarbons (PAHs) and halogenated aromatic hydrocarbons, and the comparative sensitivity of various biomarkers in fish from different bay locations were determined. Two fish species, hardhead catfish (Arius felis) and Atlantic croaker (Micropogon undulatus), were collected from four stations where sediment total PAHs ranged from 68 > 1,000 ng/g. The induction of cytochrome P4501A-(CYP1A)-dependent hepatic ethoxyresorufin-O-deethylase (EROD) activity, CYPIA mRNA levels, or CYPIA immunoreactive protein in hardhead catfish was highly variable in the field-collected fish and in fish dosed with up to 15 mg/kg benzo[a]pyrene (BaP). In contrast, significant differences were seen in biliary concentrations of naphthalene, phenanthrene, and BaP metabolites in hardhead catfish from polluted versus less polluted areas. In croakers taken from the same four Galveston Bay locations, EROD and glutathione S-transferase activities, immunoreactive CYP1A protein, biliary PAH metabolites, and PAH-DNA adducts were higher at the contaminated stations compared with less polluted locations. These studies suggest that the croaker is a good species for monitoring contaminants that induce CYP1A-mediated responses. Biliary PAH metabolites and PAH-DNA adducts were also sensitive indicators of exposure to PAH contamination in both species of fish.

Willett, K.L.; Steinberg, M.A.; Safe, S.H. [Texas A and M Univ., College Station, TX (United States). Veterinary Physiology and Pharmacology; McDonald, S.J.; Beatty, K.B.; Kennicutt, M.C. [Geochemical and Environmental Research Group, College Station, TX (United States)

1997-07-01T23:59:59.000Z

478

Free Energy Profiles of Base Flipping in Intercalative Polycyclic Aromatic Hydrocarbon-Damaged DNA Duplexes: Energetic and Structural Relationships to Nucleotide Excision Repair Susceptibility  

Science Journals Connector (OSTI)

Free Energy Profiles of Base Flipping in Intercalative Polycyclic Aromatic Hydrocarbon-Damaged DNA Duplexes: Energetic and Structural Relationships to Nucleotide Excision Repair Susceptibility ... These structural differences produce different computed van der Waals stacking interaction energies between the flipping partner base with the lesion aromatic ring system and adjacent bases; we find that the better the stacking, the higher the relative flipping free energy barrier and hence lower flipping probability. ... We emphasize, however, that the brief MD only served the purpose of equilibrating the model but is far too short for analyses of the constellation of protein–DNA interactions that stabilize the structure. ...

Yuqin Cai; Han Zheng; Shuang Ding; Konstantin Kropachev; Adam G. Schwaid; Yijin Tang; Hong Mu; Shenglong Wang; Nicholas E. Geacintov; Yingkai Zhang; Suse Broyde

2013-06-12T23:59:59.000Z

479

Design of the ILC RTML Extraction Lines  

SciTech Connect

The ILC [1] Damping Ring to the Main Linac beamline (RTML) contains three extraction lines (EL). Each EL can be used both for an emergency abort dumping of the beam and tune-up continual train-by-train extraction. Two of the extraction lines are located downstream of the first and second stages of the RTML bunch compressor, and must accept both compressed and uncompressed beam with energy spreads of 2.5% and 0.15%, respectively. In this paper we report on an optics design that allowed minimizing the length of the extraction lines while offsetting the beam dumps from the main line by the distance required for acceptable radiation levels in the service tunnel. The proposed extraction lines can accommodate beams with different energy spreads while at the same time providing the beam size acceptable for the aluminum dump window. The RTML incorporates three extraction lines, which can be used for either an emergency beam abort or for a train-by-train extraction. The first EL is located downstream of the Damping Ring extraction arc. The other two extraction lines are located downstream of each stage of the two-stage bunch compressor. The first extraction line (EL1) receives 5GeV beam with an 0.15% energy spread. The extraction line located downstream of the first stage of bunch compressor (ELBC1) receives both compressed and uncompressed beam, and therefore must accept beam with both 5 and 4.88GeV energy, and 0.15% and 2.5% energy spread, respectively. The extraction line located after the second stage of the bunch compressor (ELBC2) receives 15GeV beam with either 0.15 or 1.8% energy spread. Each of the three extraction lines is equipped with the 220kW aluminum ball dump, which corresponds to the power of the continuously dumped beam with 5GeV energy, i.e., the beam trains must be delivered to the ELBC2 dump at reduced repetition rate.

Seletskiy, S.; Tenenbaum, P.; Walz, D.; /SLAC; Solyak, N.; /Fermilab

2011-10-17T23:59:59.000Z

480

Advanced byproduct recovery: Direct catalytic reduction of SO{sub 2} to elemental sulfur. First quarterly technical progress report, [October--December 1995  

SciTech Connect

The team of Arthur D. Little, Tufts University and Engelhard Corporation will be conducting Phase I of a four and a half year, two-phase effort to develop and scale-up an advanced byproduct recovery technology that is a direct, single-stage, catalytic process for converting sulfur dioxide to elemental sulfur. this catalytic process reduces SO{sub 2} over a fluorite-type oxide (such as ceria or zirconia). The catalytic activity can be significantly promoted by active transition metals, such as copper. More than 95% elemental sulfur yield, corresponding to almost complete sulfur dioxide conversion, was obtained over a Cu-Ce-O oxide catalyst as part of an ongoing DOE-sponsored University Coal Research Program. This type of mixed metal oxide catalyst has stable activity, high selectivity for sulfur production, and is resistant to water and carbon dioxide poisoning. Tests with CO and CH{sub 4} reducing gases indicates that the catalyst has the potential for flexibility with regard to the composition of the reducing gas, making it attractive for utility use. the performance of the catalyst is consistently good over a range of SO{sub 2} inlet concentration (0.1 to 10%) indicating its flexibility in treating SO{sub 2} tail gases as well as high concentration streams.

Benedek, K. [Little (Arthur D.), Inc., Cambridge, MA (United States); Flytzani-Stephanopoulos, M. [Tufts Univ., Medford, MA (United States)

1996-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "byproducts aromatic extracts" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Fluidized bed gasification of extracted coal  

DOE Patents (OSTI)

Coal or similar carbonaceous solids are extracted by contacting the solids in an extraction zone (12) with an aqueous solution having a pH above 12.0 at a temperature between 65.degree. C. and 110.degree. C. for a period of time sufficient to remove bitumens from the coal into said aqueous solution and the extracted solids are then gasified at an elevated pressure and temperature in a fluidized bed gasification zone (60) wherein the density of the fluidized bed is maintained at a value above 160 kg/m.sup.3. In a preferred embodiment of the invention, water is removed from the aqueous solution in order to redeposit the extracted bitumens onto the solids prior to the gasification step.

Aquino, Dolores C. (Houston, TX); DaPrato, Philip L. (Westfield, NJ); Gouker, Toby R. (Baton Rouge, LA); Knoer, Peter (Houston, TX)

1986-01-01T23:59:59.000Z

482

Information Extraction from Voicemail Transcripts Martin Jansche  

E-Print Network (OSTI)

Information Extraction from Voicemail Transcripts Martin Jansche Department of Linguistics The Ohio State University Columbus, OH 43210, USA jansche.1@osu.edu Steven P. Abney AT&T Labs ­ Research 180 Park

Abney, Steven P.

483

Extraction Steam Controls at EPLA-W  

E-Print Network (OSTI)

ExxonMobil's Baton Rouge site encompasses a world-scale refinery, chemical plant and third party power station. Historically, inflexible and unreliable control systems on two high-pressure, extracting/condensing steam turbines prevented the site...

Brinker, J. L.

2004-01-01T23:59:59.000Z

484

Mechanisms of Aqueous Extraction of Soybean Oil  

Science Journals Connector (OSTI)

Mechanisms of Aqueous Extraction of Soybean Oil ... showed also that the inertial turbulent regime is inappropriate for emulsification of oils with viscosity ?500 mPa s, if drops of micrometer size are to be obtained. ...

K. A. Campbell; C. E. Glatz

2009-10-29T23:59:59.000Z

485

Extracting buried twists with polarized neutron reflectometry  

Science Journals Connector (OSTI)

Polarized neutron reflectometry can extract the depth-dependent magnetization of ... the surface. Measuring the reflectivity first with neutrons glancing off the front surface and again with neutrons glancing off...

K.V. O’Donovan; J.A. Borchers; C.F. Majkrzak; O. Hellwig…

2002-12-01T23:59:59.000Z

486

Extracting secret keys from integrated circuits  

E-Print Network (OSTI)

Modern cryptographic protocols are based on the premise that only authorized participants can obtain secret keys and access to information systems. However, various kinds of tampering methods have been devised to extract ...

Lim, Daihyun, 1976-

2004-01-01T23:59:59.000Z

487

ECG Feature Extraction Techniques - A Survey Approach  

E-Print Network (OSTI)

ECG Feature Extraction plays a significant role in diagnosing most of the cardiac diseases. One cardiac cycle in an ECG signal consists of the P-QRS-T waves. This feature extraction scheme determines the amplitudes and intervals in the ECG signal for subsequent analysis. The amplitudes and intervals value of P-QRS-T segment determines the functioning of heart of every human. Recently, numerous research and techniques have been developed for analyzing the ECG signal. The proposed schemes were mostly based on Fuzzy Logic Methods, Artificial Neural Networks (ANN), Genetic Algorithm (GA), Support Vector Machines (SVM), and other Signal Analysis techniques. All these techniques and algorithms have their advantages and limitations. This proposed paper discusses various techniques and transformations proposed earlier in literature for extracting feature from an ECG signal. In addition this paper also provides a comparative study of various methods proposed by researchers in extracting the feature from ECG signal.

Karpagachelvi, S; Sivakumar, M

2010-01-01T23:59:59.000Z

488

Urinary Excretion of Phenolic Polycyclic Aromatic Hydrocarbons (OH-PAH) in Nonsmokers and in Smokers of Cigarettes with Different ISO Tar Yields  

Science Journals Connector (OSTI)

......products of the incomplete combustion of organic materials...Tars analysis Tobacco chemistry 301 Polycyclic aromatic...products of the incomplete combustion of organic materials...during the incomplete combustion of organic materials...ambient air, and coal-tar-containing med......

Heinz-Werner Hagedorn; Gerhard Scherer; Johannes Engl; Kirsten Riedel; Francis Cheung; Graham Errington; Jim Shepperd; Mike McEwan

2009-01-01T23:59:59.000Z

489

NATIONAL PRESS RELEASE I PARIS I 30 AUGUST 2013 Brown algae contain phlorotannins, aromatic (phenolic) compounds that are unique in the plant  

E-Print Network (OSTI)

NATIONAL PRESS RELEASE I PARIS I 30 AUGUST 2013 Brown algae contain phlorotannins, aromatic elucidated the key step in the production of these compounds in Ectocarpus siliculosus, a small brown alga phlorotannins from brown algae for use in industry was a complex process, and the biosynthesis pathways

Canet, LĂ©onie

490

Biosynthesis of cis,cis-Muconic Acid and Its Aromatic Precursors, Catechol and Protocatechuic Acid, from Renewable Feedstocks by Saccharomyces cerevisiae  

Science Journals Connector (OSTI)

...Protocatechuic Acid, from Renewable Feedstocks by Saccharomyces...process requires a high energy input and further leads...synthetic route using renewable resources like glucose...it does not allow a cost-competitive industrial...aromatics from d-glucose: renewable microbial sources of...

Christian Weber; Christine Brückner; Sheila Weinreb; Claudia Lehr; Christine Essl; Eckhard Boles

2012-09-21T23:59:59.000Z

491

The Analysis of C6 to C10 Aromatic Hydrocarbons in The Presence of C1 to C11 Saturated Hydrocarbons By Open Tubular Column Gas Chromatography  

Science Journals Connector (OSTI)

......is well suited for studies of straight run naph- thas and gasolines as well as studies involving...aromatics are data of four replicate runs. The Table II. Replicate Measurements C-6836 Cut 3 Run 1 Run 2 Run 3 Run 4 Avg. Ethylbenzene......

Charles L. Stuckey

1969-03-01T23:59:59.000Z

492

Optimization of a Solvent Extraction Desalination Plant  

E-Print Network (OSTI)

OPTIHIZATION OF A SOLEENT EXTRACTION DESALINATION PLANT A Thesis by PHILLIP LEN BEIGHLE Submitted to the Graduate College of Texas ABEAM University in partial fulfillment of the requirements for the degree of NASTER OF SCIENCE May lg6...$ Najor Subject: Chemical Erugincering OPTIMI7&TION OF A SOLVENT EXTRACTION DESALINATION PLANT A Thesis By PHILLIP LEN BEIGHLE Approved as to style and content by: (Chairman of Committee) (Head of Department) (Member) (Member) (Member) (Member...

Beighle, Phillip Lew

2012-06-07T23:59:59.000Z

493

Alkaline earth cation extraction from acid solution  

DOE Patents (OSTI)

An extractant medium for extracting alkaline earth cations from an aqueous acidic sample solution is described as are a method and apparatus for using the same. The separation medium is free of diluent, free-flowing and particulate, and comprises a Crown ether that is a 4,4'(5')[C.sub.4 -C.sub.8 -alkylcyclohexano]18-Crown-6 dispersed on an inert substrate material.

Dietz, Mark (Elmhurst, IL); Horwitz, E. Philip (Naperville, IL)

2003-01-01T23:59:59.000Z

494

Ocean Thermal Extractable Energy Visualization: Final Technical Report  

Energy.gov (U.S. Department of Energy (DOE))

Report about the Ocean Thermal Extractable Energy Visualization project, which focuses on assessing the Maximum Practicably Extractable Energy from the world’s ocean thermal resources.

495

Automated data extraction from in situ protein stable isotope...  

NLE Websites -- All DOE Office Websites (Extended Search)

data extraction from in situ protein stable isotope probing studies. Automated data extraction from in situ protein stable isotope probing studies. Abstract: Protein stable isotope...

496

Louisiana Offshore Natural Gas Plant Liquids Production Extracted...  

U.S. Energy Information Administration (EIA) Indexed Site

Offshore Natural Gas Plant Liquids Production Extracted in Louisiana (Million Cubic Feet) Louisiana Offshore Natural Gas Plant Liquids Production Extracted in Louisiana (Million...

497

Alabama Offshore Natural Gas Plant Liquids Production Extracted...  

Gasoline and Diesel Fuel Update (EIA)

Plant Liquids Production Extracted in Alabama (Million Cubic Feet) Alabama Offshore Natural Gas Plant Liquids Production Extracted in Alabama (Million Cubic Feet) Decade Year-0...

498

California Onshore Natural Gas Plant Liquids Production Extracted...  

U.S. Energy Information Administration (EIA) Indexed Site

Plant Liquids Production Extracted in California (Million Cubic Feet) California Onshore Natural Gas Plant Liquids Production Extracted in California (Million Cubic Feet) Decade...

499

California Onshore Natural Gas Total Liquids Extracted in California...  

U.S. Energy Information Administration (EIA) Indexed Site

Total Liquids Extracted in California (Thousand Barrels) California Onshore Natural Gas Total Liquids Extracted in California (Thousand Barrels) Decade Year-0 Year-1 Year-2 Year-3...

500

Enhanced Geothermal in Nevada: Extracting Heat From the Earth...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Enhanced Geothermal in Nevada: Extracting Heat From the Earth to Generate Sustainable Power Enhanced Geothermal in Nevada: Extracting Heat From the Earth to Generate Sustainable...