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Sample records for bv dl deltak

  1. ARM - Instrument - dl

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to hear from you Send us a note below or call us at 1-888-ARM-DATA. Send Instrument : Doppler Lidar (DL) Instrument Categories Cloud Properties Picture of the Doppler Lidar...

  2. Innogrow BV | Open Energy Information

    Open Energy Info (EERE)

    Jump to: navigation, search Name: Innogrow BV Place: Utrecht, Netherlands Zip: 3503 RK Product: Innogrow has developed a greenhouse product for gardening and thermal energy source....

  3. Doppler Lidar (DL) Handbook

    SciTech Connect (OSTI)

    Newsom, RK


    The Doppler lidar (DL) is an active remote sensing instrument that provides range- and time-resolved measurements of radial velocity and attenuated backscatter. The principle of operation is similar to radar in that pulses of energy are transmitted into the atmosphere; the energy scattered back to the transceiver is collected and measured as a time-resolved signal. From the time delay between each outgoing transmitted pulse and the backscattered signal, the distance to the scatterer is inferred. The radial or line-of-sight velocity of the scatterers is determined from the Doppler frequency shift of the backscattered radiation. The DL uses a heterodyne detection technique in which the return signal is mixed with a reference laser beam (i.e., local oscillator) of known frequency. An onboard signal processing computer then determines the Doppler frequency shift from the spectra of the heterodyne signal. The energy content of the Doppler spectra can also be used to determine attenuated backscatter.

  4. Solland Solar Energy BV | Open Energy Information

    Open Energy Info (EERE)

    Energy BV Jump to: navigation, search Name: Solland Solar Energy BV Place: Heerlen, Netherlands Zip: NL 6422RL Sector: Solar Product: Dutch manufacturer of crystalline silicon...

  5. Dutch Space BV | Open Energy Information

    Open Energy Info (EERE)

    Dutch Space BV Jump to: navigation, search Name: Dutch Space BV Place: Leiden, Netherlands Zip: 2333 Sector: Solar Product: Leiden-based supplier of subsystems for the European...

  6. Eurus Energy Europe BV | Open Energy Information

    Open Energy Info (EERE)

    Eurus Energy Europe BV Jump to: navigation, search Name: Eurus Energy Europe BV Place: London, United Kingdom Zip: SW1Y 4QT Sector: Wind energy Product: European arm of Japanese...

  7. RGS Development BV | Open Energy Information

    Open Energy Info (EERE)

    to: navigation, search Name: RGS Development BV Place: Netherlands Sector: Solar Product: Joint venture between the Energy Research Centre of the Netherlands, Deutsche Solar and...

  8. Ubbink Solar Modules BV | Open Energy Information

    Open Energy Info (EERE)

    Solar Modules BV Place: Cologne, North Rhine-Westphalia, Germany Zip: 50933 Product: German manufacturer of PV modules, main customer was Ecostream that has agreed to purchase...

  9. Deltak LLC | Open Energy Information

    Open Energy Info (EERE)

    (HRSGs) for gas turbine combined-cycle power generation and specialty boilers for waste heat recovery applications Coordinates: 44.979035, -93.264929 Show Map Loading map......

  10. DL-36361 UC-414 I

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    DL-36361 UC-414 I * Discovery of the Most Distant Supernovae and the Quest for L l Gerson Goldhaber and Saul Perlmutter Lawrence Berkeley Laboratory and Center for Particle Astrophysics University of California, Berkeley, CA 94720 Silvia Gabi, Ariel Goobar, Alex Kim, Mathew Kim, and Reynald Pain Lawrence Berkeley Laboratory, University of California Berkeley, CA 94720 Carl Pennypacker and Ivan Small Lawrence Berkeley Laboratory and Space Sciences Laboratory University of California, Berkeley, CA

  11. Solland Solar Cells BV Shanghai | Open Energy Information

    Open Energy Info (EERE)

    Cells BV Shanghai Jump to: navigation, search Name: Solland Solar Cells BV (Shanghai) Place: Shanghai, Shanghai Municipality, China Zip: 200030 Sector: Solar Product:...

  12. Tss4U BV formerly Holecsol R S Renewable Energy Systems and Shell...

    Open Energy Info (EERE)

    Tss4U BV formerly Holecsol R S Renewable Energy Systems and Shell Solar Energy Jump to: navigation, search Name: Tss4U BV (formerly Holecsol, R&S Renewable Energy Systems and Shell...

  13. GiraSolar Inc formerly GiraSolar BV | Open Energy Information

    Open Energy Info (EERE)

    BV) Place: Deventer, Netherlands Zip: 7418EV Product: Manufacturer of silicon photovoltaic modules. Coordinates: 52.251034, 6.159899 Show Map Loading map......


    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    U.S. Dl?PARThIENT OFFNFRGY EERE PROJECT MANAGEMENT CETER NlPA DFllNATION ... publication and distribution, and classroom training and informational programs), ...


    SciTech Connect (OSTI)

    Joner, Michael D.; Taylor, Benjamin J.; Laney, C. David; Van Wyk, Francois


    New BV(RI){sub C} measurements of Praesepe made at the South African Astronomical Observatory (SAAO) are presented. When those measurements are combined with those reported in previous papers in this series, it is found that they support previously determined V zero points for Praesepe, M67, and the Hyades. Support is also found for joint (V - R){sub C} and (R - I){sub C} zero points established previously for Praesepe and NGC 752. For the SAAO system of standard stars, a B - V correction to the Johnson system of about -9 mmag appears to be reasonably well established. The preferred (though not definitive) V correction is about +7 mmag. For the Landolt V system, zero-point identity with the Johnson system at a 2{sigma} level of 4.8 mmag is found, and no color term as large as 4 mmag (mag){sup -1} is detected. Updated CDS data files for Praesepe are briefly described.

  16. dlCC Opt: Optimization Software for Renewable Energy Projects - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovation Portal Wind Energy Wind Energy Solar Thermal Solar Thermal Solar Photovoltaic Solar Photovoltaic Energy Analysis Energy Analysis Find More Like This Return to Search dlCC Opt: Optimization Software for Renewable Energy Projects National Renewable Energy Laboratory Contact NREL About This Technology Technology Marketing Summary There are numerous options for renewable energy systems development. Location, size, type of system, and a number of other criteria need to be considered.


    SciTech Connect (OSTI)

    Contreras Pena, C.; Catelan, M.; Grundahl, F.; Stephens, A. W.; Smith, H. A. E-mail:


    We present BV photometry of the Galactic globular cluster NGC 6402 (M14), based on 65 V frames and 67 B frames, reaching two magnitudes below the turnoff level. This represents, to the best of our knowledge, the deepest color-magnitude diagram (CMD) of NGC 6402 available in the literature. Statistical decontamination of field stars as well as differential reddening corrections are performed in order to derive a precise ridgeline and hence physical parameters of the cluster. We discuss previous attempts at deriving a reddening value for the cluster, and argue in favor of a value E(B - V) = 0.57 {+-} 0.02, which is significantly higher than indicated by either the Burstein and Heiles or Schlegel et al. (corrected according to Bonifacio et al.) interstellar dust maps. Differential reddening across the face of the cluster, which we find to be present at the level of {Delta}E(B - V) Almost-Equal-To 0.17 mag, is taken into account in our analysis. We measure several metallicity indicators based on the position of the red giant branch (RGB) in the cluster CMD. These give a metallicity of [Fe/H] = -1.38 {+-} 0.07 on the Zinn and West scale and [Fe/H] = -1.28 {+-} 0.08 on the new Carretta et al. (UVES) scale. We also provide measurements of other important photometric parameters for this cluster, including the position of the RGB luminosity function ''bump'' and the horizontal branch morphology. We compare the NGC 6402 ridgeline with that of NGC 5904 (M5) derived by Sandquist et al., and find evidence that NGC 6402 and M5 have approximately the same age to within the uncertainties, although the possibility that M14 may be slightly older cannot be ruled out.

  18. Evelop BV | Open Energy Information

    Open Energy Info (EERE)

    projects in the Netherlands and abroad, especially in Western Europe, Eastern Europe and Latin America. Coordinates: 52.088932, 5.115405 Show Map Loading map......

  19. Intivation BV | Open Energy Information

    Open Energy Info (EERE)

    Solar Product: Netherlands-based manufacturer of solar-powered consumer products for electronics, notably solar handsets and chargers. Coordinates: 52.37312, 4.893195 Show Map...

  20. D.S. Kim1,* H.L. Smith1, J.L. Niedziela2, C.W. Li3, D.L. Abernathy4, and B. Fultz1

    Office of Scientific and Technical Information (OSTI)

    in Silicon from 100 to 1500 K D.S. Kim1,* H.L. Smith1, J.L. Niedziela2, C.W. Li3, D.L. Abernathy4, and B. Fultz1 1 California Institute of Technology, Department of Applied Physics and Materials Science, Pasadena, California 91125, USA 2 Instrument and Source Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, USA 3 Materials Science and Technology Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, USA 4 Quantum Condensed Matter Division, Oak Ridge National

  1. Futech BvBa | Open Energy Information

    Open Energy Info (EERE)

    Place: Leuven, Belgium Zip: 3001 Product: Belgium-based project development and distribution company. Coordinates: 50.879385, 4.70367 Show Map Loading map......

  2. Pillar Group BV | Open Energy Information

    Open Energy Info (EERE)

    Holding company; subsidiary Silicio Solar makes monosilicon wafers through the Cz process. Coordinates: 50.429447, 30.546693 Show Map Loading map......

  3. TEAM0.5DL.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Closing the session Set TEM mode if different Set magnification at x10K Close column valve Complete log book Name ... Date...

  4. CM200DL-Final.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Core Status: new users must complete 2 trouble free training sessions and pass the drivers test to work independently during Core sessions. Flex Status: core users must complete 5...

  5. Microsoft Word - mitchell-dl.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ice crystals of maximum dimension D, P(D) is the projected area for a crystal of maximum dimension D, and N(D) is the ice-crystal particle size distribution. N(D) has units of...

  6. SunConnex International BV | Open Energy Information

    Open Energy Info (EERE)

    Sector: Solar Product: Dutch PV installer established in 1989; supplier of modules, inverters, and components necessary to build solar plants. References: SunConnex International...


    Office of Legacy Management (LM)

    slucs - NO, Ra Oil PH Be Th Sample No. 7573p Hour Sample Description 1355 CZ Orxxator sets slul: into place, closes shield over machine S starts &ill. oil coolant flows ...

  8. Feed Processing and Handling DL2 Final Report

    SciTech Connect (OSTI)

    Elliott, Douglas C.; Magnuson, Jon K.; Wend, Christopher F.


    This milestone report is the deliverable for our Feed Processing and Handling project. It includes results of wet biomass feedstock analysis, slurry pumping information, fungal processing to produce a lignin-rich biorefinery residue and two subcontracted efforts to quantify the amount of wet biomass feedstocks currently available within the corn processing and paper processing industries.

  9. Formation of dl-limonene in used tire vacuum pyrolysis oils. [dipentene

    SciTech Connect (OSTI)

    Pakdel, H.; Roy, C.; Aubin, H.; Jean, G. ); Coulombe, S. )


    Tire recycling has become an important environmental issue recently due to the huge piles of tires that threaten the environment. Thermal decomposition of tire, a synthetic rubber material, enables the recovery of carbon black and liquid hydrocarbon oils. Both have potential economic values. Pyrolysis oils obtained under vacuum conditions contain a significant portion of a volatile, naptha-like fraction with an octane number similar to petroleum naphtha fraction, in addition, contains approximately 15% limonene. Potential applications of vacuum pyrolysis oil and carbon black have been investigated. However, the process economics is greatly influenced by the quality of the oil and carbon black products. This paper discusses limonene formation during used tire vacuum pyrolysis and its postulated reaction mechanism. The limonene separation method from pyrolysis oil, as well as its purification in laboratory scale, and structural characterization are discussed. Large-scale limonene separation and purification is under investigation.


    Office of Legacy Management (LM)

    OUR' tiIn - . BUREAU OF R&DllmcN tROTElOH ' 1 , jBD 5cOTCH ROAD. R%obi. fd. 1. 08628 .' - . - . . : Ssrterrjer 27, 1977 - ,. :.- ,..I L . x- a-. JEC):...

  11. Hennepin County, Minnesota: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Corporation Deltak LLC Despatch Industries EcoSystem Corporation Ecologic Analytics Emerald Renewable Energy FC3 Group FreEner-g Freener g Genmar Holdings Inc Geothermal Bore...

  12. Minnesota's 5th congressional district: Energy Resources | Open...

    Open Energy Info (EERE)

    Delphi Financial Corporation Deltak LLC Despatch Industries EcoSystem Corporation Emerald Renewable Energy FC3 Group FreEner-g Freener g Genmar Holdings Inc Great Plains...

  13. Coherent rho 0 photoproduction in bulk matter at high energies

    SciTech Connect (OSTI)

    Couderc, Elsa; Klein, Spencer


    The momentum transfer {Delta}k required for a photon to scatter from a target and emerge as a {rho}{sup 0} decreases as the photon energy k rises. For k > 3 x 10{sup 14} eV, {Delta}k is small enough that the interaction cannot be localized to a single nucleus. At still higher energies, photons may coherently scatter elastically from bulk matter and emerge as a {rho}{sup 0}, in a manner akin to kaon regeneration. Constructive interference from the different nuclei coherently raises the cross section and the interaction probability rises linearly with energy. At energies above 10{sup 23} eV, coherent conversion is the dominant process; photons interact predominantly as {rho}{sup 0}. We compute the coherent scattering probabilities in slabs of lead, water and rock, and discuss the implications of the increased hadronic interaction probabilities for photons on ultra-high energy shower development.

  14. The application of a logic framework for fatigue crack growth analyses to microstructural effects

    SciTech Connect (OSTI)

    Xu, J.G.; Liu, H.W.


    {Delta}K has been widely used to correlate da/dN data. The relation between da/dN and {Delta}K is usually found empirically. However, fatigue crack growth relations can also be derived theoretically. Three fatigue crack growth theories are derived for the state of small scale yielding and plane strain. These three theories constitute a logic framework useful for fatigue crack growth analyses. The application of the logic framework to the analyses of microstructural effects on fatigue crack growth is illustrated. The fatigue crack growth curve of 7075-T651 aluminum alloy has five distinct regions. A fatigue crack grows by crack-tip shear decohesion forming striations and by brittle fractures of particles followed by localized shear decohesion at these microcracks forming dimples. The logic framework helps to relate the fatigue crack growth behaviors in these five regions to the fractures of inclusions and to the resistance of grain boundaries and dispersoids to shear decohesion.

  15. Company Name Company Name Address Place Zip Sector Product Website

    Open Energy Info (EERE)

    Industries GmbH SunCoal Industries GmbH K nigs Wusterhausen Germany Producer of bio coal SunConnex International BV SunConnex International BV Amsterdam Netherlands Solar Dutch...

  16. Electro-Magnetic Dipole Properties of The Even-Even {sup 160}Gd Nucleus in The Spectroscopic Region

    SciTech Connect (OSTI)

    Ertugral, Filiz; Kuliev, Ali; Guliyev, Ekber


    In this study result of calculations using rotational, translational and Galilean invariant quasiparticle random-phase approximation is presented for the low lying dipole excitations in the even-even {sup 60}Gd nucleus. To make detail structure analysis for electric and magnetic dipole states, calculations carried out for both {delta}K = 1 and {delta}K = 0 branches. The analysis shows that almost all transitions with {delta}K = 1 are magnetic character in 2.4 divide 4 MeV energy interval. However, the calculations indicate the presence of a few prominent negative parity K{sup {pi}} = 1 states in the investigated energy interval, one of them with rather high E1 strength B(E1) = 7.1{center_dot}10{sup -3} e{sup 2} fm{sup 2} at energy 3.2 MeV. Calculated M1 dipole strength of the scissors mode K{sup {pi}} = 1{sup +} excitations clustered in two groups around 2.7 and 3.3 MeV. A similar situation arises for the experimentally obtained states two bumps around {omega}{sub i} = 2.7 MeV and {omega}{sub i} = 3.3 MeV. It has been shown that main part of spin-1 states, observed at energy 2.4 divide 4 MeV in {sup 160}Gd may be attributed to have M1 character and may be interpreted as main fragments of the scissors mode. However, it is apparent that the experimental data exceeds the calculation results for the summed B(M1) by a factor of 1.13 for M1 transitions.

  17. NREL: Photovoltaics Research - David L. Young, Ph.D.

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    p. 073502. Young, D.L., B. Egaas, S. Pinegar, and P. Stradins. A new real-time quantum efficiency measurement system. in 33rd IEEE PVSC 2008. San Diego, CA: IEEE. Young, D.L.,...

  18. A Metal Fuel Core Concept for 1000 MWt Advanced Burner Reactor

    SciTech Connect (OSTI)

    Yang, W.S.; Kim, T.K.; Grandy, C.


    This paper describes the core design and performance characteristics of a metal fuel core concept for a 1000 MWt Advanced Burner Reactor. A ternary metal fuel form of U-TRU-Zr was assumed with weapons grade plutonium feed for the startup core and TRU recovered from LWR spent fuel for the recycled equilibrium core. A compact burner core was developed by trade-off between the burnup reactivity loss and TRU conversion ratio, with a fixed cycle length of one-year. In the startup core, the average TRU enrichment is 15.5%, the TRU conversion ratio is 0.81, and the burnup reactivity loss over a cycle is 3.6% {delta}k. The heavy metal and TRU inventories are 13.1 and 2.0 metric tons, respectively. The average discharge burnup is 93 MWd/kg, and the TRU consumption rate is 55.5 kg/year. For the recycled equilibrium core, the average TRU enrichment is 22.1 %, the TRU conversion ratio is 0.73, and the burnup reactivity loss is 2.2% {delta}k. The TRU inventory and consumption rate are 2.9 metric tons and 81.6 kg/year, respectively. The evaluated reactivity coefficients provide sufficient negative feedbacks. The control systems provide shutdown margins that are more than adequate. The integral reactivity parameters for quasi-static reactivity balance analysis indicate favorable passive safety features, although detailed safety analyses are required to verify passive safety behavior. (authors)

  19. Lubrication Systems Market : Mining & Mineral Processing Industry...

    Open Energy Info (EERE)

    Groeneveld Groep B.V., SKF AB, Bijur Delimon, Castrol-Lubecon, Changzhou Huali Hydraulic Lubrication Equipment Co., Ltd., Changhua Chen Ying Oil Machine Co., Ltd., Equipment...

  20. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... (HG) (United States) USDOE Office of Human Resources and Administration (HR) (United ... of the SOL plasma density was obtained. (C) 2009 Elsevier B.V. All rights reserved. ...

  1. Phase 2 Study of Docetaxel, Cisplatin, and Concurrent Radiation...

    Office of Scientific and Technical Information (OSTI)

    ... B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: ... DNA; FAILURES; FEEDING; HEAD; HUMAN POPULATIONS; KIDNEYS; METASTASES; NECK; ...

  2. Template synthesis of Ag/AgCl microrods and their efficient visible...

    Office of Scientific and Technical Information (OSTI)

    Resource Relation: Journal Name: Materials Research Bulletin; Journal Volume: 57; Other Information: Copyright (c) 2014 Elsevier Science B.V., Amsterdam, The Netherlands, All ...

  3. Mechanisms of G1 cell cycle arrest and apoptosis in myeloma cells...

    Office of Scientific and Technical Information (OSTI)

    Journal Volume: 434; Journal Issue: 3; Other Information: Copyright (c) 2013 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input:...

  4. Fibroblast growth factor 10 protects neuron against oxygen-glucose...

    Office of Scientific and Technical Information (OSTI)

    Journal Volume: 456; Journal Issue: 1; Other Information: Copyright (c) 2014 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input:...

  5. Fluorescent tracking of nickel ions in human cultured cells ...

    Office of Scientific and Technical Information (OSTI)

    Fluorescent tracking of nickel ions in human cultured cells Citation Details In-Document ... B.V., Amsterdam, The Netherlands, All rights reserved; Country of input: International ...

  6. Nickel decreases cellular iron level and converts cytosolic aconitase...

    Office of Scientific and Technical Information (OSTI)

    the mechanism for the observed effects, human embryonic kidney (HEK) cells over ... B.V., Amsterdam, The Netherlands, All rights reserved; Country of input: International ...

  7. Effects of 12 metal ions on iron regulatory protein 1 (IRP-1...

    Office of Scientific and Technical Information (OSTI)

    ... since this represents a major route of human environmental and occupational exposure to ... B.V., Amsterdam, The Netherlands, All rights reserved; Country of input: International ...

  8. Long-term in-vivo tumorigenic assessment of human culture-expanded...

    Office of Scientific and Technical Information (OSTI)

    Journal Volume: 318; Journal Issue: 4; Other Information: Copyright (c) 2011 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input:...

  9. Interleukin-4 enhances trafficking and functional activities...

    Office of Scientific and Technical Information (OSTI)

    Journal Volume: 317; Journal Issue: 15; Other Information: Copyright (c) 2011 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input:...

  10. The new ternary pnictides Er{sub 12}Ni{sub 30}P{sub 21} and Er...

    Office of Scientific and Technical Information (OSTI)

    ... (c) 2010 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved. Country of Publication: United States Language: English Subject: 36 MATERIALS SCIENCE; ...

  11. LOCO with Constraints and Improved Fitting Technique

    SciTech Connect (OSTI)

    Huang, Xiaobiao; Safranek, James; Portmann, Greg; /LBL, Berkeley


    LOCO has been a powerful beam-based diagnostics and optics control method for storage rings and synchrotrons worldwide ever since it was established at NSLS by J. Safranek. This method measures the orbit response matrix and optionally the dispersion function of the machine. The data are then fitted to a lattice model by adjusting parameters such as quadrupole and skew quadrupole strengths in the model, BPM gains and rolls, corrector gains and rolls of the measurement system. Any abnormality of the machine that affects the machine optics can then be identified. The resulting lattice model is equivalent to the real machine lattice as seen by the BPMs. Since there are usually two or more BPMs per betatron period in modern circular accelerators, the model is often a very accurate representation of the real machine. According to the fitting result, one can correct the machine lattice to the design lattice by changing the quadrupole and skew quadrupole strengths. LOCO is so important that it is routinely performed at many electron storage rings to guarantee machine performance, especially after the Matlab-based LOCO code became available. However, for some machines, LOCO is not easy to carry out. In some cases, LOCO fitting converges to an unrealistic solution with large changes to the quadrupole strengths {Delta}K. The quadrupole gradient changes can be so large that the resulting lattice model fails to find a closed orbit and subsequent iterations become impossible. In cases when LOCO converges, the solution can have {Delta}K that is larger than realistic and often along with a spurious zigzag pattern between adjacent quadrupoles. This degeneracy behavior of LOCO is due to the correlation between the fitting parameters - usually between neighboring quadrupoles. The fitting scheme is therefore less restrictive over certain patterns of changes to these quadrupoles with which the correlated quadrupoles fight each other and the net effect is very inefficient {chi}{sup 2} reduction, i.e., small {chi}{sup 2} reduction with large changes of {Delta}K. Under effects of random noise, the fitting solution tends to crawl toward these patterns and ends up with unrealistically large {Delta}K. Such a solution is not very useful in optics correction because after the solution is dialed in, the quadrupoles will not respond as predicted by the lattice model due to magnet hysteresis. We will show that adding constraints to the fitting parameters is an effective way to combat this problem of LOCO. In fact, it improves optics calibration precision even for machines that don't show severe degeneracy behavior. LOCO fitting is essentially to solve a nonlinear least square problem with an iterative approach. The linear least square technique is applied in each iteration to move the solution toward the minimum. This approach is commonly referred to as the Gauss-Newton method. By using singular value decomposition (SVD) to invert the Jacobian matrix, this method has generally been very successful for LOCO. However, this method is based on a linear expansion of the residual vector over the fitting parameters which is valid only when the starting solution is sufficiently close to the real minimum. The fitting algorithm can have difficulties to converge when the initial guess is too far off. For example, it's possible for the {chi}{sup 2} merit function to increase after an iteration instead of decrease. This situation can be improved by using more robust nonlinear least square fitting algorithms, such as the Levenberg-Marquardt method. We will discuss the degeneracy problem in section 2 and then show how the constrained fitting can help in section 3. The application of Levenberg-Marquadt method to LOCO is shown in section 4. A summary is given in section 5.

  12. A Unified Approach for Reporting ARM Measurement Uncertainties...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    0 A Unified Approach for Reporting ARM Measurement Uncertainties Technical Report E Campos DL Sisterson October 2015 DISCLAIMER This report was prepared as an account of work ...

  13. INDIA

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    View Plots AOS Aerosol Observing System Measurement Type: Aerosol View Plots DL Doppler Lidar Measurement Type: Cloud Properties View Plots GNDRAD Ground Radiometers on...

  14. ARM - Field Campaign - Observations and Modeling of the Green...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Particle Counter Browse Data Browse Plots CSPHOT Cimel Sunphotometer Browse Data DL Doppler Lidar Browse Data ECOR Eddy Correlation Flux Measurement System Browse Data Browse...

  15. ARM - Measurement - Vertical velocity

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    assurance purposes. ARM Instruments CO2FLX : Carbon Dioxide Flux Measurement Systems DL : Doppler Lidar ECOR : Eddy Correlation Flux Measurement System KAZR : Ka ARM Zenith Radar...

  16. ARM - Site Instruments

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Disdrometer Surface Meteorology Browse Plots Browse Data Single installation DL Doppler Lidar Cloud Properties Browse Plots Browse Data Installed at 2 facilities EBBR...

  17. ARM - AMF3 Baseline Instruments

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Profiler (RWP), 915-MHz for U.S. deployments, 1290-MHz for deployments outside the U.S. Doppler Lidar (DL) Raman Lidar (RL) Radiometers Atmospheric Emitted Radiance...

  18. ARM - Site Instruments

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cimel Sunphotometer Aerosols, Radiometric Browse Data Installed at 2 facilities DL Doppler Lidar Cloud Properties Browse Data Single installation ECOR Eddy Correlation...

  19. INDIA

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ARM instruments on top of the ARIES Observatory in Nainital Doppler Lidar (DL) Shortwave Array Spectroradiometers, both Hemispheric and Zenith (SASHE and SASZE) Shortwave Array...

  20. ARM - Field Campaign - Ganges Valley Aerosol Experiment (GVAX...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CPC Condensation Particle Counter Browse Data CSPHOT Cimel Sunphotometer Browse Data DL Doppler Lidar Browse Data ECOR Eddy Correlation Flux Measurement System Browse Data GNDRAD...

  1. ARM - Site Instruments

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Disdrometer Surface Meteorology Browse Plots Browse Data Single installation DL Doppler Lidar Cloud Properties Browse Data Single installation ECOR Eddy Correlation...

  2. ARM - Measurement - Backscatter depolarization ratio

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    those recorded for diagnostic or quality assurance purposes. ARM Instruments DL : Doppler Lidar HSRL : High Spectral Resolution Lidar RL : Raman Lidar Field Campaign...

  3. EERE PowerPoint 97-2004 Template: Green Version

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Reservior Technology Research Development and Demonstration ( 2001). Gallup, DL. Ore Geology Reviews(1998) 3 | US DOE Geothermal Office Impact of Research: Robust...

  4. Temperature coefficients for PV modules and arrays: Measurement...

    Office of Scientific and Technical Information (OSTI)

    methods, difficulties, and results King, D.L.; Kratochvil, J.A.; Boyson, W.E. 14 SOLAR ENERGY; SOLAR CELL ARRAYS; SOLAR CELLS; MEASURING METHODS; TEMPERATURE DEPENDENCE;...

  5. Fermi Observations of High-Energy Gamma-Ray Emission from GRB...

    Office of Scientific and Technical Information (OSTI)

    Cruz ; Axelsson, M. ; Stockholm U., OKC Stockholm U. ; Baldini, L. ; INFN, Pisa ; Ballet, J. ; DAPNIA, Saclay ; Band, D.L. ; NASA, Goddard NASA, Goddard ; Barbiellini,...

  6. Fermi Observations of High-Energy Gamma-Ray Emission From GRB...

    Office of Scientific and Technical Information (OSTI)

    Cruz ; Axelsson, M. ; Stockholm U. Stockholm U., OKC ; Baldini, L. ; INFN, Pisa ; Ballet, J. ; DAPNIA, Saclay ; Band, D.L. ; NASA, Goddard ; Barbiellini, G. ; INFN, Trieste...

  7. P

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site


  8. ASC eNews Quarterly Newsletter September 2012 | National Nuclear...

    National Nuclear Security Administration (NNSA)

    ... Maniadis, P., Lookman, T., Saxena, A., Smith, D.L. (2012). "Proposal for Manipulating Functional Interface Properties of Composite Organic Semiconductors with Addition of Designed ...

  9. Synthesis and characterisation of hexagonal molybdenum nitrides...

    Office of Scientific and Technical Information (OSTI)

    DOI: 10.1016j.jssc.2006.05.025; PII: S0022-4596(06)00310-0; Copyright (c) 2006 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved; Country of input: ...

  10. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Area of Research: Aerosol Properties Working Group(s): Aerosol Life Cycle Journal Reference: China S, G Kulkarni, BV Scarnato, N Sharma, M Pekour, JE Shilling, J Wilson, A ...

  11. Hydrogen production from water decomposition by redox of Fe{sub...

    Office of Scientific and Technical Information (OSTI)

    DOI: 10.1016j.jssc.2010.03.017; PII: S0022-4596(10)00095-2; Copyright (c) 2010 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved. Country of...

  12. Synthesis of low loss, thermally stable Ce{sub x}Y{sub 1-x}TiTaO...

    Office of Scientific and Technical Information (OSTI)

    10.1016j.materresbull.2008.06.005; PII: S0025-5408(08)00207-9; Copyright (c) 2008 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved; Country of input:...

  13. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... (HG) (United States) USDOE Office of Human Resources and Administration (HR) (United ... with an average diameter of approximate to 20 nm. 2014 Elsevier B.V. All rights reserved. ...


    Office of Legacy Management (LM)


  15. BPA-2013-00017-FOIA Request

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    kFCiVEI) BV BPA FOLk OFFICE TILTS DATE: DUE DATE: LOG Description of Request: Corona and Field Effects Version 3.0 software program Preferred format: electronic via email...

  16. Econcern GmbH | Open Energy Information

    Open Energy Info (EERE)

    Econcern GmbH Jump to: navigation, search Name: Econcern GmbH Place: Germany Product: German company for the local activities of Econcern BV. References: Econcern GmbH1 This...

  17. Pipe diffusion at dislocations in UO2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of pipe diffusion to the overall O 2 and U 4+ diffusion is also discussed. 2014 Elsevier B.V. All rights reserved. 1. Introduction During its lifetime in-pile nuclear fuel...

  18. Dynamics of particle production by strong electric fields in non-Abelian plasmas

    SciTech Connect (OSTI)

    Dawson, John F.; Mihaila, Bogdan; Cooper, Fred


    We develop methods for computing the dynamics of fermion pair production by strong color electric fields including backreaction using the semiclassical Boltzmann-Vlasov (B-V) equation. We implement the Schwinger pair production by inserting a source term in the B-V equation which includes Pauli-Blocking effects. We present numerical results for a model with SU(2) symmetries in (1+1) Cartesian dimensions.

  19. Coronal electron confinement by double layers

    SciTech Connect (OSTI)

    Li, T. C.; Drake, J. F.; Swisdak, M.


    In observations of flare-heated electrons in the solar corona, a longstanding problem is the unexplained prolonged lifetime of the electrons compared to their transit time across the source. This suggests confinement. Recent particle-in-cell (PIC) simulations, which explored the transport of pre-accelerated hot electrons through ambient cold plasma, showed that the formation of a highly localized electrostatic potential drop, in the form of a double layer (DL), significantly inhibited the transport of hot electrons. The effectiveness of confinement by a DL is linked to the strength of the DL as defined by its potential drop. In this work, we investigate the scaling of the DL strength with the hot electron temperature by PIC simulations and find a linear scaling. We demonstrate that the strength is limited by the formation of parallel shocks. Based on this, we analytically determine the maximum DL strength, and also find a linear scaling with the hot electron temperature. The DL strength obtained from the analytic calculation is comparable to that from the simulations. At the maximum strength, the DL is capable of confining a significant fraction of hot electrons in the source.

  20. Lead in human blood from children living in Campania, Italy

    SciTech Connect (OSTI)

    Amodio-Cocchieri, R.; Arnese, A.; Prospero, E.; Roncioni, A.


    Blood lead (PbB) levels were determined in children living Campania (in Naples and in a rural zone in the district of Caserta). Atmospheric lead (PbA) concentration in these considered areas was monitored for 1 yr (1993-1994). The children tested were questioned about common sources of lead, other than atmospheric relating to their living and dietary habits. The PbB levels in children living in Naples were at the 50th percentile, 18.8 {mu}g/dl in males and 13.7 {mu}g/dl in females; in children living in the rural area the median PbB levels were 8.9{mu}g/dl in males, and 9.9 {mu}g/dl in females. The annual mean values of atmospheres lead were 1.15 {plus_minus} 0.24 {mu}g/dl in Naples and 0.23 {plus_minus} 0.07 {mu}g/dl in the rural area. Significant and congruent mean differences between urban and rural sites were found in children`s blood and concurrent air lead. Considering the PbB level of 10 {mu}g/dl as the maximum level that is not associated any known adverse effect in children, the Neapolitan group can be considered at risk of chronic intoxication by lead. 18 refs., 3 figs., 4 tabs.

  1. The Sloan Digital Sky Survey Monitor Telescope Pipeline (Journal...

    Office of Scientific and Technical Information (OSTI)

    Authors: Tucker, D.L. ; Kent, S. ; Richmond, M.W. ; Annis, J. ; Smith, J.A. ; Allam, S.S. ; Rodgers, C.T. ; Stute, J.L. ; Adelman-McCarthy, Jennifer K. ; Brinkmann, J. ; Doi, M. ;...

  2. BPA-2011-00611-FOIA Request

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    9, 2011 . C1IVEas tip' BPA OIA OFI "E THIS %TE:: 'f 1 Ms. Christina Munro :;L;E D."l s- FOIA Office Bonneville Power Administration ' Routing: DK-7 ,x ; P.O. Box 3621 f,4 ,...

  3. ILDS

    Energy Science and Technology Software Center (OSTI)

    003176IBMPC00 Intelligent Leak Detection System

  4. ARM - Measurement - Radar Doppler

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    quality assurance purposes. ARM Instruments CSAPR : C-Band ARM Precipitation Radar DL : Doppler Lidar KAZR : Ka ARM Zenith Radar KASACR : Ka-Band Scanning ARM Cloud Radar MWACR :...

  5. ARM - Instruments

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Light Absorption Photometer AWR, MAO, NSA, PGH, PVC, SGP 2011.03.01 2016.09.30 Z dl Doppler Lidar AWR, ENA, MAO, NSA, OLI, PGH, PVC, SGP, TWP 2010.10.21 2016.09.30 Z ecor...

  6. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Kehoe, KE (1) Lijegren, JC (1) Long, CN (1) Macduff, MC (1) Mather, JH (1) McCord, RA (1) Moore, ST (1) Nitschke, DL (1) Orr, BW (1) Peppler, RA (1) Perez, RC (1) Save Results Save ...

  7. Reactive Distillation for Esterification of Bio-based Organic...

    Office of Scientific and Technical Information (OSTI)

    ... Vetenskaps-Academiens nya Handlingar, 1 Stockholm (1780) 116-124. 33. Hartmann, M.H. in: Kaplan, D.L. (Ed.), Biopolymers from Renewal Resources, Springer-Verlag, Berlin, 1998, pp. ...

  8. ARM - Publications: Science Team Meeting Documents

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Treatment Using a Single-Column Model and ARM Observations Iacobellis, S.F. (a), Mitchell, D.L. (b), and Somerville, R.C.J. (a), Scripps Institution of Oceanography (a),...


    Open Energy Info (EERE)

    affects the wall rock at distances of 5 to 10 feet beyond the fracture. Authors Dilley, L.M.; Newman, D.L. ; McCulloch and J.; Published PROCEEDINGS, Thirtieth Workshop on...

  10. Fluid Inclusion Stratigraphy: Interpretation of New Wells in...

    Open Energy Info (EERE)

    to moderate producers, problem producers, injectors, and non producers Authors Dilley, L.M.; Newman, D.L. ; McCulloch, J.; Wiggett and G. Published Geothermal Resource Council...

  11. Newbie here. Is there any software/site which can poll my utility...

    Open Energy Info (EERE)

    Newbie here. Is there any softwaresite which can poll my utility to DL my green data file and email it to me? Home My provider is JEA. They only provide the Green Data download...

  12. ARM - Publications: Science Team Meeting Documents

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Infrared Radiative Properties Stackhouse, P.W., Jr. (a), Mitchell, D.L. (b), and Yang, P. (c), NASA Langley Research Center (a), Desert Research Institute (b), NASA Goddard...

  13. ARM - Publications: Science Team Meeting Documents

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Retrieval of Ice Water Path, Ice Particle Size, and Shape Mitchell, D.L., Arnott, W.P., and Ivanova, D.C., Desert Research Institute Twelfth Atmospheric Radiation Measurement (ARM)...


    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ...Material Handling Systems 2.1% Reduced surface preparation and peripheral trim Use of ... cap. 8 DL save an hour. 3D Projected Laser Guidelines for Layup and Fixture Location ...

  15. ARM - Publications: Science Team Meeting Documents

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Impact of a Revised Treatment of Cirrus Microphysics on the Radiation Budget of the Unified Model Edwards, J.M. (a), Mitchell, D.L. (b), Ivanova, D. (b), and Wilson, D.R. (a), ...

  16. Borehole geophysics evaluation of the Raft River geothermal reservoir...

    Open Energy Info (EERE)

    HYDROTHERMAL SYSTEMS; NORTH AMERICA; PACIFIC NORTHWEST REGION; USA Authors Applegate, J.K.; Donaldson, P.R.; Hinkley, D.L.; Wallace and T.L. Published Journal Geophysics, 21...

  17. Pi

    National Nuclear Security Administration (NNSA)

    Pi .,,,..,,,,,E', EGG 10617-2195 ENERGY MEASUREMENTS uc-814 YUCCA MOUNTAIN ... Tortoise Section Section Section R. A. Green C.A. Wills D.L. Rakestraw Manager Manager ...

  18. Household Vehicles Energy Consumption 1994

    U.S. Energy Information Administration (EIA) Indexed Site

    DC, October 1995), Table DL-1B. 5. "Chained dollars" is a measure used to express real prices. Real prices are those that have been adjusted to remove the effect of changes...


    U.S. Energy Information Administration (EIA) Indexed Site

    DC, October 1995), Table DL-1B. 5. "Chained dollars" is a measure used to express real prices. Real prices are those that have been adjusted to remove the effect of changes...

  20. CamSemi | Open Energy Information

    Open Energy Info (EERE)

    CamSemi Jump to: navigation, search Name: CamSemi Place: Cambridge, United Kingdom Zip: CB4 1DL Product: CamSemi is developing a new generation of highly-intelligent, single chip...

  1. Residential

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    MacDonald and D.L. White. Oak Ridge National Laboratory. ORNLCON-304.(5-91) InfiltrationVentilation Measurements in RCDP Manufactured Homes. Pacific Northwest Laboratory, D....

  2. ARM - Publications: Science Team Meeting Documents

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Retrieval of Ice Water Path Using Thermal Channels Mitchell, D.L. (a), d'Entremont, R.P. (b), Stackhouse, P.W., Jr. (c), and Heymsfield, A.J. (d), Desert Research Institute (a),...

  3. MIT Plasma Science & Fusion Center: research, alcator, publications...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Winslow, D.L. - Edge Fluctuation Measurements with a Triple Probe on Alcator C-Mod, FRC, Univ. of TX Elder, J.D. - Univ. of Toronto Poster PDF (4.9MB) Terry, J.L. -...

  4. Docker File System Isolation By Darrin Schmitz David Huff Destiny...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Docker File System Isolation By Darrin Schmitz David Huff Destiny Velasquez 1 LA-UR-15-25911 Specifications * HP ProLiant DL380p Gen8 servers * Head node has 32 cores and 32 GB RAM...

  5. Center for Inverse Design Highlight: Enabling Practical p-Type...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and hence enable unopposed p-type doping in easily grown materials. Reference: J.D. Perkins, T.R. Paudel, A. Zakutayev, P.F. Ndione, P.A. Parilla, D.L. Young, S. Lany, D.S....

  6. Laser Wakefield Particle Acceleration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in new capability for rapid data exploration and analysis. Investigators: Cameron Geddes, Jean-Luc Vay, Carl Schroeder, E. Cormier-Michel, E. Esarey, W.P. Leemans (LBNL); D.L....

  7. MICROX-2 cross section library based on ENDF/B-VII

    SciTech Connect (OSTI)

    Hou, J.; Ivanov, K.; Choi, H.


    New cross section libraries of a neutron transport code MICROX-2 have been generated for advanced reactor design and fuel cycle analyses. A total of 386 nuclides were processed, including 10 thermal scattering nuclides, which are available in ENDF/B-VII release 0 nuclear data. The NJOY system and MICROR code were used to process nuclear data and convert them into MICROX-2 format. The energy group structure of the new library was optimized for both the thermal and fast neutron spectrum reactors based on Contributon and Point-wise Cross Section Driven (CPXSD) method, resulting in a total of 1173 energy groups. A series of lattice cell level benchmark calculations have been performed against both experimental measurements and Monte Carlo calculations for the effective/infinite multiplication factor and reaction rate ratios. The results of MICROX-2 calculation with the new library were consistent with those of 15 reference cases. The average errors of the infinite multiplication factor and reaction rate ratio were 0.31% {delta}k and 1.9%, respectively. The maximum error of reaction rate ratio was 8% for {sup 238}U-to-{sup 235}U fission of ZEBRA lattice against the reference calculation done by MCNP5. (authors)

  8. Fatigue crack growth behavior of Ti-1100 at elevated temperature

    SciTech Connect (OSTI)

    Maxwell, D.C.; Nicholas, T.


    Effects of temperature, frequency, and cycles with superimposed hold times are evaluated in Ti-1100 in order to study the complex creep-fatigue-environment interactions in this material. Crack growth rate tests conducted at cyclic loading frequency of 1.0 Hz show that raising the temperature from 593 to 650 C has only a slightly detrimental effect on crack growth rate, although these temperatures produce growth rates significantly higher than at room temperature. From constant {Delta}K tests, the effects of temperature at constant frequency show a minimum crack growth rate at 250 C. From the minimum crack growth rate at 250 C, the crack growth rate increases linearly with temperature. Increases in frequency at constant temperatures of 593 and 650 C produce a continuous decrease in growth rate in going from 0.001 to 1.0 Hz, although the behavior is primarily cycle dependent in this region. Tests at 1.0 Hz with superimposed hold times from 1 to 1,000 s are used to evaluate creep-fatigue-environment interactions. Hold times at maximum load are found to initially decrease and then increase the cyclic crack growth rate with increasing duration. This is attributed to crack-tip blunting during short hold times and environmental degradation at long hold times. Hold times at minimum load show no change in growth rates, indicating that there is no net environmental degradation to the bulk material beyond that experienced during the baseline 1 Hz cycling.

  9. Systems, methods and computer-readable media to model kinetic performance of rechargeable electrochemical devices

    DOE Patents [OSTI]

    Gering, Kevin L.


    A system includes an electrochemical cell, monitoring hardware, and a computing system. The monitoring hardware samples performance characteristics of the electrochemical cell. The computing system determines cell information from the performance characteristics. The computing system also analyzes the cell information of the electrochemical cell with a Butler-Volmer (BV) expression modified to determine exchange current density of the electrochemical cell by including kinetic performance information related to pulse-time dependence, electrode surface availability, or a combination thereof. A set of sigmoid-based expressions may be included with the modified-BV expression to determine kinetic performance as a function of pulse time. The determined exchange current density may be used with the modified-BV expression, with or without the sigmoid expressions, to analyze other characteristics of the electrochemical cell. Model parameters can be defined in terms of cell aging, making the overall kinetics model amenable to predictive estimates of cell kinetic performance along the aging timeline.

  10. Bulk Vitrification Performance Enhancement: Refractory Lining Protection Against Molten Salt Penetration

    SciTech Connect (OSTI)

    Hrma, Pavel R.; Bagaasen, Larry M.; Schweiger, Michael J.; Evans, Michael B.; Smith, Benjamin T.; Arrigoni, Benjamin M.; Kim, Dong-Sang; Rodriguez, Carmen P.; Yokuda, Satoru T.; Matyas, Josef; Buchmiller, William C.; Gallegos, Autumn B.; Fluegel, Alexander


    Bulk vitrification (BV) is a process that heats a feed material that consists of glass-forming solids and dried low-activity waste (LAW) in a disposable refractory-lined metal box using electrical power supplied through carbon electrodes. The feed is heated to the point that the LAW decomposes and combines with the solids to generate a vitreous waste form. This study supports the BV design and operations by exploring various methods aimed at reducing the quantities of soluble Tc in the castable refractory block portion of the refractory lining, which limits the effectiveness of the final waste form.


    National Nuclear Security Administration (NNSA)

    I~' CONTRACT ID CODE IPAGE OF PAGES DE-NR0000031 . 1 I 1 2. AMENDMENT/MODIFICATION NO. 3. EFFECTIVE DATE 4. REQUISITION/PURCHASE REQ. NO. I 5. PROJECT NO. (If applicable) 003 Same as Block 16G . N~ 6. ISSUED BV CODE 7. ADMINISTERED BV (If other than Item 6) Code I U.S. Department of Energy Pittsburgh Naval Reactors Office P.O. Box 109 West Mifflin, PA 15122-0109 8. NAME AND ADDRESS OF CONTRACTOR (No. street, county, State and ZIP Code) (*...) 9.A. AMENDMENT OF SOLICITATION NO. Bechtel Marine

  12. ACBEDGF1DIH P Q2RSTDVU@DVW RYX1`bacSedVagf ShFiSpaqSTr1Hs...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    & WvD HkwdD r1H Spaqr1acUSpHa UWvrBEr1H rW HbDrwBvWvrH @jh B k l &22; m n dr1p UDo dr1wbUTDr pqq rWbDW D...

  13. Laboratory Testing of Bulk Vitrified Low-Activity Waste Forms to Support the 2005 Integrated Disposal Facility Performance Assessment

    SciTech Connect (OSTI)

    Pierce, Eric M.; McGrail, B. Peter; Bagaasen, Larry M.; Rodriguez, Elsa A.; Wellman, Dawn M.; Geiszler, Keith N.; Baum, Steven R.; Reed, Lunde R.; Crum, Jarrod V.; Schaef, Herbert T.


    The purpose of this report is to document the results from laboratory testing of the bulk vitri-fied (BV) waste form that was conducted in support of the 2005 integrated disposal facility (IDF) performance assessment (PA). Laboratory testing provides a majority of the key input data re-quired to assess the long-term performance of the BV waste package with the STORM code. Test data from three principal methods, as described by McGrail et al. (2000a; 2003a), are dis-cussed in this testing report including the single-pass flow-through test (SPFT) and product con-sistency test (PCT). Each of these test methods focuses on different aspects of the glass corrosion process. See McGrail et al. (2000a; 2003a) for additional details regarding these test methods and their use in evaluating long-term glass performance. In addition to evaluating the long-term glass performance, this report discusses the results and methods used to provided a recommended best estimate of the soluble fraction of 99Tc that can be leached from the engineer-ing-scale BV waste package. These laboratory tests are part of a continuum of testing that is aimed at improving the performance of the BV waste package.

  14. Laboratory Testing of Bulk Vitrified Low-Activity Waste Forms to Support the 2005 Integrated Disposal Facility Performance Assessment

    SciTech Connect (OSTI)

    Pierce, Eric M.; McGrail, B. Peter; Bagaasen, Larry M.; Rodriguez, Elsa A.; Wellman, Dawn M.; Geiszler, Keith N.; Baum, Steven R.; Reed, Lunde R.; Crum, Jarrod V.; Schaef, Herbert T.


    The purpose of this report is to document the results from laboratory testing of the bulk vitri-fied (BV) waste form that was conducted in support of the 2005 integrated disposal facility (IDF) performance assessment (PA). Laboratory testing provides a majority of the key input data re-quired to assess the long-term performance of the BV waste package with the STORM code. Test data from three principal methods, as described by McGrail et al. (2000a; 2003a), are dis-cussed in this testing report including the single-pass flow-through test (SPFT) and product con-sistency test (PCT). Each of these test methods focuses on different aspects of the glass corrosion process. See McGrail et al. (2000a; 2003a) for additional details regarding these test methods and their use in evaluating long-term glass performance. In addition to evaluating the long-term glass performance, this report discusses the results and methods used to provided a recommended best estimate of the soluble fraction of 99Tc that can be leached from the engineer-ing-scale BV waste package. These laboratory tests are part of a continuum of testing that is aimed at improving the performance of the BV waste package.

  15. BPA-2012-00330-FOIA Request

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    10512011 1004 Daniel C. APLC FA O8 998 8975 P.0011011 DANIEL C. MINUTILLO Professional Law Corporation rED BV BP 941 Blossom Hill Road, Suite 205 FOIL OtFCCE T 1 i i P.O. Box...

  16. Monitoring external beam radiotherapy using real-time beam visualization

    SciTech Connect (OSTI)

    Jenkins, Cesare H.; Naczynski, Dominik J.; Yu, Shu-Jung S.; Xing, Lei


    Purpose: To characterize the performance of a novel radiation therapy monitoring technique that utilizes a flexible scintillating film, common optical detectors, and image processing algorithms for real-time beam visualization (RT-BV). Methods: Scintillating films were formed by mixing Gd{sub 2}O{sub 2}S:Tb (GOS) with silicone and casting the mixture at room temperature. The films were placed in the path of therapeutic beams generated by medical linear accelerators (LINAC). The emitted light was subsequently captured using a CMOS digital camera. Image processing algorithms were used to extract the intensity, shape, and location of the radiation field at various beam energies, dose rates, and collimator locations. The measurement results were compared with known collimator settings to validate the performance of the imaging system. Results: The RT-BV system achieved a sufficient contrast-to-noise ratio to enable real-time monitoring of the LINAC beam at 20 fps with normal ambient lighting in the LINAC room. The RT-BV system successfully identified collimator movements with sub-millimeter resolution. Conclusions: The RT-BV system is capable of localizing radiation therapy beams with sub-millimeter precision and tracking beam movement at video-rate exposure.

  17. Elastic properties, sp fraction, and Raman scattering in low and high pressure synthesized diamond-like boron rich carbides

    SciTech Connect (OSTI)

    Zinin, Pavel V.; Burgess, Katherine; Jia, Ruth; Sharma, Shiv; Ming, Li-Chung; Liu, Yongsheng; Ciston, Jim; Hong, Shiming


    Dense BC{sub x} phases with high boron concentration are predicted to be metastable, superhard, and conductors or superconductors depending on boron concentration. However, up to this point, diamond-like boron rich carbides BC{sub x} (dl-BC{sub x}) phases have been thought obtainable only through high pressure and high temperature treatment, necessitating small specimen volume. Here, we use electron energy loss spectroscopy combined with transmission electron microscopy, Raman spectroscopy, surface Brillouin scattering, laser ultrasonics (LU) technique, and analysis of elastic properties to demonstrate that low pressure synthesis (chemical vapor deposition) of BC{sub x} phases may also lead to the creation of diamond-like boron rich carbides. The elastic properties of the dl-BC{sub x} phases depend on the carbon spversus sp content, which decreases with increasing boron concentration, while the boron bonds determine the shape of the Raman spectra of the dl-BC{sub x} after high pressure-high temperature treatment. Using the estimation of the density value based on the sp fraction, the shear modulus ? of dl-BC?, containing 10% carbon atoms with sp bonds, and dl-B?C?, containing 38% carbon atoms with sp bonds, were found to be ? = 19.3 GPa and ? = 170 GPa, respectively. The presented experimental data also imply that boron atoms lead to a creation of sp bonds during the deposition processes.

  18. Lessons Learned In Technology Development for Supplemental Treatment of Low-Activity Waste at Hanford

    SciTech Connect (OSTI)

    Biyani, R.K. [Washington State Department of Ecology, Richland, WA (United States)


    Hanford needs supplemental technology treatment of low-activity waste (LAW) in addition to the Waste Treatment Plant (WTP). The Washington State Department of Ecology requires that supplemental technology provide the same protection to human health and the environment as WTP LAW glass. In 2002, the U.S. Department of Energy (US DOE) evaluated supplemental treatment technologies for LAW treatment and looked more closely at three: bulk vitrification (BV), steam reforming, and tailored cementitious stabilization. US DOE with Ecology's support chose to design and test BV because it believed BV would offer rapid deployment, low cost, and waste stream versatility. This paper will describe the path taken in choosing and developing technologies for additional LAW treatment capacity and, more importantly, the lessons learned along the way. In conclusion: Contractors' off-the-shelf vitrification technology that worked elsewhere may not apply easily to Hanford's waste challenges. The BV development process could have been improved by first identifying and then focusing on primary areas of concern. Continuing integrated tests at the Horn Rapids facility offers a convenient option to test both the dryer and the SMF. But the plan for development of the SMF must be short term with well defined success criteria. US DOE has the responsibility to carefully evaluate each proposal and make critical decisions that will make optimum use of limited funds. The ERP provided valuable technical guidance on improving BV's design. This must be complemented by a similar study of cost effectiveness of a process. We must have a better understanding of life cycle costs before a path for supplemental treatment is chosen. US DOE has now gained five years of experience in developing BV. It is time for US DOE to make defensible economic evaluations before further funding towards developing supplemental treatment. It must reevaluate if the projected advantages of rapid deployment, low cost, and waste stream versatility are still valid. The decision-making methodology US DOE uses to approve designs as part of its Critical Decision Process appears rigorous and useful. Looking ahead, Ecology expects US DOE will use lessons learned from BV and other testing in a concerted manner as part of their decision-making process. The success of Hanford's cleanup depends on it. (authors)

  19. Worker lead exposures during renovation of homes with lead-based paint

    SciTech Connect (OSTI)

    Sussell, A.; Gittleman, J.; Singal, M.


    The authors evaluated lead exposures among full-time home renovators and part-time volunteers working primarily in pre-1960 homes with lead-based paint. Potentially hazardous lead exposures were measured during two tasks: exterior dry scraping and wet scraping. Maximum exposures were 120 and 63 {micro}g/m{sup 3}, respectively. Exposures during other tasks, including general repair, weatherization, exterior scraping/painting, window replacement, demolition, and plumbing, were low, as were all 13 full-shift personal exposures. Blood lead levels for full-time workers ranged up to 17.5 {micro}g/dl, with a GM of 5.2 {micro}g/dl; the GM for volunteers was 3.2 {micro}g/dl. All of the paint samples collected from work surfaces had detectable amounts of lead, with 65% of the work surfaces tested having an average lead concentration of >0.5%.

  20. Criticality Safety Validation of Scale 6.1

    SciTech Connect (OSTI)

    Marshall, William BJ J; Rearden, Bradley T


    The computational bias of criticality safety computer codes must be established through the validation of the codes to critical experiments. A large collection of suitable experiments has been vetted by the International Criticality Safety Benchmark Experiment Program (ICSBEP) and made available in the International Handbook of Evaluated Criticality Safety Benchmark Experiments (IHECSBE). A total of more than 350 cases from this reference have been prepared and reviewed within the Verified, Archived Library of Inputs and Data (VALID) maintained by the Reactor and Nuclear Systems Division at Oak Ridge National Laboratory. The performance of the KENO V.a and KENO-VI Monte Carlo codes within the Scale 6.1 code system with ENDF/B-VII.0 cross-section data in 238-group and continuous energy is assessed using the VALID models of benchmark experiments. The TSUNAMI tools for sensitivity and uncertainty analysis are utilized to examine some systems further in an attempt to identify potential causes of unexpected results. The critical experiments available for validation of the KENO V.a code cover eight different broad categories of systems. These systems use a range of fissile materials including a range of uranium enrichments, various plutonium isotopic vectors, and mixed uranium-plutonium oxides. The physical form of the fissile material also varies and is represented as metal, solutions, or arrays of rods or plates in a water moderator. The neutron energy spectra of the systems also vary and cover both fast and thermal spectra. Over 300 of the total cases used utilize the KENO V.a code. The critical experiments available for the validation of the KENO-VI code cover three broad categories of systems. The fissile materials in the systems vary and include high and intermediate-enrichment uranium and mixed uranium/plutonium oxides. The physical form of the fissile material is either metal or rod arrays in water. As with KENO V.a, both fast and thermal neutron energy spectra are represented in the systems considered. The results indicate generally good performance of both the KENO V.a and KENO-VI codes across the range of systems analyzed. The bias of calculated k{sub eff} from expected values is less than 0.9% {Delta}k in all cases. All eight categories of experiments show biases of less than 0.5% {Delta}k in KENO V.a with the exception of intermediate enrichment metal systems using the 238-group library. The continuous energy library generally manifests lower biases than the multi-group data. The KENO-VI results show slightly larger biases, though this may primarily be the result of modeling systems with more geometric complexity, which are more difficult to describe accurately, even with a generalized geometry code like KENO-VI. Several additional conclusions can be drawn from the results of this validation effort. These conclusions include that the TSUNAMI tools can be used successfully to explain the cause of aberrant results, that some evaluations in the IHECSBE should be updated to provide more rigorous expected k{sub eff} values and uncertainties, and that potential cross-section errors can be identified by detailed review of the results of this validation. It also appears that the overall cross-section uncertainty as quantified through the Scale covariance library is overestimated. Overall, the KENO V.a and KENO-VI codes are shown to provide consistent, low bias results for a wide range of physical systems of potential interest in criticality safety applications.

  1. Tunable infrared source employing Raman mixing

    DOE Patents [OSTI]

    Byer, Robert L.; Herbst, Richard L.


    A tunable source of infrared radiation is obtained by irradiating an assemblage of Raman active gaseous atoms or molecules with a high intensity pumping beam of coherent radiation at a pump frequency .omega..sub.p to stimulate the generation of Stokes wave energy at a Stokes frequency .omega..sub.s and to stimulate the Raman resonant mode at the Raman mode frequency .omega..sub.R within the irradiated assemblage where the pump frequency .omega..sub.p minus the Stokes frequency .omega..sub.s is equal to the Raman mode frequency .omega..sub.R. The stimulated assemblage is irradiated with a tunable source of coherent radiation at a frequency .omega..sub.i to generate the output infrared radiation of the frequency .omega..sub.0 which is related to the Raman mode frequency .omega..sub.R and the input wave .omega..sub.i by the relation .omega..sub.0 In one embodiment the interaction between the pump wave energy .omega..sub.p and the tunable input wave energy .omega..sub.i is collinear and the ratio of the phase velocity mismatch factor .DELTA.k to the electric field exponential gain coefficient T is within the range of 0.1 to 5. In another embodiment the pump wave energy .omega..sub.p and the tunable input wave energy .omega..sub.i have velocity vectors k.sub.p and k.sub.i which cross at an angle to each other to compensate for phase velocity mismatches in the medium. In another embodiment, the Stokes wave energy .omega..sub.s is generated by pump energy .omega..sub.p in a first Raman cell and .omega..sub.s, .omega..sub.i and .omega..sub.p are combined in a second Raman mixing cell to produce the output at .omega..sub.i.

  2. Corrosion fatigue crack growth in clad low-alloy steel. Part 2, Water flow rate effects in high sulfur plate steel

    SciTech Connect (OSTI)

    James, L.A; Lee, H.B.; Wire, G.L.; Novak, S.R.; Cullen, W.H.


    Corrosion fatigue crack propagation tests were conducted on a high- sulfur ASTM A302-B plate steel overlaid with weld-deposited Alloy EN82H cladding. The specimens featured semi-elliptical surface cracks penetrating approximately 6.3 mm of cladding into the underlying steel. The initial crack sizes were relatively large with surface lengths of 22.8--27.3 mm, and depths of 10.5--14.1 mm. The experiments were initiated in a quasi-stagnant low-oxygen (O{sub 2} < 10 ppb) aqueous environment at 243{degrees}C, under loading conditions ({Delta}K, R, cyclic frequency) conducive to environmentally-assisted cracking (EAC) under quasi-stagnant conditions. Following fatigue testing under quasi-stagnant conditions where EAC was observed, the specimens were then fatigue tested under conditions where active water flow of either 1.7 m/sec. or 4.7 m/sec. was applied parallel to the crack. Earlier experiments on unclad surface-cracked specimens of the same steel exhibited EAC under quasi- stagnant conditions, but water flow rates at 1.7 m/sec. and 5.0 m/sec. parallel to the crack mitigated EAC. In the present experiments on clad specimens, water flow at approximately the same as the lower of these velocities did not mitigate EAC, and a free stream velocity approximately the same as the higher of these velocities resulted in sluggish mitigation of EAC. The lack of robust EAC mitigation was attributed to the greater crack surface roughness in the cladding interfering with flow induced within the crack cavity. An analysis employing the computational fluid dynamics code, FIDAP, confirmed that frictional forces associated with the cladding crack surface roughness reduced the interaction between the free stream and the crack cavity.


    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ARM-TR-101 Doppler Lidar (DL) Handbook RK Newsom February 2012 Work supported by the U.S. Department of Energy, Office of Science, Office of Biological and Environmental Research RK Newsom, February 2012, DOE/SC-ARM-TR-101 iii Acronyms and Abbreviations AGL above ground level AMF ARM Mobile Facility AMFDL AMF Doppler Lidar ARM Atmospheric Radiation Measurement DL Doppler Lidar DMF Data Management Facility DOE U.S. Department of Energy DQO Data Quality Office GVAX Ganges Valley Aerosol Experiment

  4. Double layer -- a particle accelerator in the magnetosphere

    SciTech Connect (OSTI)

    Fu, Xiangrong


    Slides present the material under the following topics: Introduction (What is a double layer (DL)? Why is it important? Key unsolved problems); Theory -- time-independent solutions of 1D Vlasov--Poisson system; Particle-in-cell simulations (Current-driven DLs); and Electron acceleration by DL (Betatron acceleration). Key problems include the generation mechanism, stability, and electron acceleration. In summary, recent observations by Van Allen Probes show large number of DLs in the outer radiation belt, associated with enhanced flux of relativistic electrons. Simulations show that ion acoustic double layers can be generated by field-aligned currents. Thermal electrons can gain energy via betatron acceleration in a dipole magnetic field.

  5. Ms. Maria Galanti Site Coordinator

    Energy Savers [EERE]

    ? 5 2011 PPPO-03-1251788-11 Ohio Environmental Protection Agency Southeast District Office 2195 Front Street Logan, Ohio 43138 Dear Ms. Galanti: TRANSMITTAL OF Dl CONSTRUCTION COMPLETION REPORT FOR PHASES I AND II OF THE REMOVAL OF THE X-760 CHEMICAL ENGINEERING BUILDING AT THE PORTSMOUTH GASEOUS DIFFUSION PLANT, PIKETON, OHIO (DOE/PPPO/03-0196&Dl) Reference: Letter from M. Galanti to J. Bradbume, "Construction Completion Report for Phases I and II ofthe Removal of the X-760 Chemical

  6. Polaron Coherence Condensation in Layered Colossal Resistive...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    when the temperature is close to the Curie point, TC 120 K, for LSMO and the critical point, Tc 83 K, for BiSCCO2212. BiSCCO2212 data from D.L. Feng et al., Science 289, 277...

  7. Slide 1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Equation (1) (2) (3) (4) (5) Tank Model Recycling Ratio A IF A OF dp dl qV Ag dp q g HD HA T S n T S - + 1 1 V dPW HA HD MFD MFD dPW MFD P E + - dPW A...

  8. Atmospheric measurements of carbonyl sulfide, dimethyl sulfide, and carbon disulfide using the electron capture sulfur detector

    SciTech Connect (OSTI)

    Johnson, J.E.; Bates, T.S. [NOAA, Seattle, WA (United States)


    Measurements of atmospheric dimethyl sulfide (DMS), carbonyl sulfide (COS), and carbon disulfide (CS2) were conducted over the Atlantic Ocean on board the NASA Electra aircraft during the Chemical Instrumentation Test and Evaluation (CITE 3) project using the electron capture sulfur detector (ECD-S). The system employed cryogenic preconcentration of air samples, gas chromatographic separation, catalytic fluorination, and electron capture detection. Samples collected for DMS analysis were scrubbed of oxidants with NaOH impregnated glass fiber filters to preconcentration. The detection limits (DL) of the system for COS, DMS, and CS2 were 5, 5, and 2 ppt, respectively. COS concentrations ranged from 404 to 603 ppt with a mean of 489 ppt for measurements over the North Atlantic Ocean (31 deg N to 41 deg N), and from 395 to 437 ppt with a mean of 419 ppt for measurements over the Tropical Atlantic Ocean (11 deg S to 2 deg N). DMS concentrations in the lower marine boundary layer, below 600-m altitude, ranged from below DL to 150 ppt from flights over the North Atlantic, and from 9 to 104 ppt over the Tropical Atlantic. CS2 concentrations ranged from below DL to 29 ppt over the North Atlantic. Almost all CS2 measurements over the Tropical Atlantic were below DL.

  9. Lamp Divisions

    Office of Legacy Management (LM)

    ... Very truly yours, ' Division kdministrator Accident Prevention I' ,RIr: .DRAl::S . Letters A TRri' &dL; i Sanple LOt:' ;1s : TWO Dra i n L i neS liemaed -m ' I CA"?ED WITH 6" I ...

  10. Dynamics of double layers, ion acceleration, and heat flux suppression during solar flares

    SciTech Connect (OSTI)

    Li, T. C.; Drake, J. F.; Swisdak, M.


    Observations of flare-heated electrons in the corona typically suggest confinement of electrons. The confinement mechanism, however, remains unclear. The transport of coronal hot electrons into ambient plasma was recently investigated by particle-in-cell (PIC) simulations. Electron transport was significantly suppressed by the formation of a highly localized, nonlinear electrostatic potential in the form of a double layer (DL). In this work large-scale PIC simulations are performed to explore the dynamics of DLs in larger systems where, instead of a single DL, multiple DLs are generated. The primary DL accelerates return current electrons, resulting in high velocity electron beams that interact with ambient ions. This forms a Buneman unstable system that spawns more DLs. Trapping of heated return current electrons between multiple DLs strongly suppresses electron transport. DLs also accelerate ambient ions and produce strong ion flows over an extended region. This clarifies the mechanism by which hot electrons in the corona couple to and accelerate ions to form the solar wind. These new dynamics in larger systems reveal a more likely picture of DL development and their impact on the ambient plasma in the solar corona. They are applicable to the preparation for in situ coronal space missions like the Solar Probe Plus.

  11. I

    Office of Legacy Management (LM)

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  12. Supplement Analysis of Environmental Effects of Changes in DOE...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  13. Microsoft Word - APP VI, Rev 3 _03-19-20

    National Nuclear Security Administration (NNSA)

    ... Bowen, S.M., D.L. Finnegan, J.L. Thompson, C.M. Miller, P.L. Baca, L.F. Olivas, C.G. Geoffrion, D.K. Smith, W. Goishi, B.K. Esser, J.W. Meadows, N. Namboodiri, and J.F. Wild. 2001. ...

  14. Technical Basis Agreement Document for UGTA CAU 99 RM/SM

    National Nuclear Security Administration (NNSA)

    D.L. Finnegan, J.L. Thompson, C.M. Miller, P.L. Baca, L.F. Olivas, C.G. Geoffrion, D.K. Smith, W. Goishi, B.K. Esser, J.W. Meadows, N. Namboodiri, J.F. Wild. 2001. Nevada Test Site...

  15. Letter

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  16. BPA-2011-00122-FOIA Request

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  17. Direct Kinetic Measurements of a Criegee Intermediate

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    J.D. Savee, D.L. Osborn, S.S. Vasu, C.J. Percival, D.E. Shallcross, and C.A. Taatjes, "Direct Kinetic Measurements of Criegee Intermediate (CH2OO) Formed by Reaction of CH2I...

  18. Radioactive Lysine in Protein Metabolism Studies

    DOE R&D Accomplishments [OSTI]

    Miller, L. L.; Bale, W. F.; Yuile, C. L.; Masters, R. E.; Tishkoff, G. H.; Whipple,, G. H.


    Studies of incorporation of DL-lysine in various body proteins of the dog; the time course of labeled blood proteins; and apparent rate of disappearance of labeled plasma proteins for comparison of behavior of the plasma albumin and globulin fractions; shows more rapid turn over of globulin fraction.

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    Office of Legacy Management (LM)

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  20. V, Ii. Pat-SC&~, Ciructor, Elvision of Techdcal Jkitiseru

    Office of Legacy Management (LM)

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  1. Progress Report on the Laboratory Testing of the Bulk Vitrification Cast Refractory

    SciTech Connect (OSTI)

    Pierce, Eric M.; McGrail, B PETER.; Bagaasen, Larry M.; Wellman, Dawn M.; Crum, J V.; Geiszler, Keith N.; Baum, Steven R.


    The Hanford Site in southeastern Washington State has been used extensively to produce nuclear materials for the U. S. strategic defense arsenal by the U. S. Department of Energy (DOE). A large inventory of radioactive and mixed waste has accumulated in 177 single- and double-shell tanks. Liquid waste recovered from the tanks will be pre-treated to separate the low-activity fraction from the high-level and transuranic wastes. Currently, the DOE Office of River Protection (ORP) is evaluating several options for immobilization of low-activity tank wastes for eventual disposal in a shallow subsurface facility at the Hanford Site. A significant portion of the waste will be converted into immobilized low-activity waste (ILAW) glass with a conventional Joule-heated ceramic melter. In addition to ILAW glass, supplemental treatment technologies are under consideration by the DOE to treat a portion of the low activity waste. The reason for using this alternative treatment technology is to accelerate the overall cleanup mission at the Hanford site. The ORP selected Bulk Vitrification (BV) for further development and testing. Work in FY03 on engineered and large scale tests of the BV process suggested that approximately 0.3 to as much as 3 wt% of the waste stream 99Tc inventory would end up in a soluble form deposited in a vesicular layer located at the top of the BV melt and in the sand used as an insulator after vitrification. In the FY03 risk assessment (RA) (Mann et al., 2003), the soluble Tc salt in the BV waste packages creates a 99Tc concentration peak at early times in the groundwater extracted from a 100-meter down-gradient well. This peak differs from the presently predicted baseline WTP glass performance, which shows an asymptotic rise to a constant release rate. Because of the desire by regulatory agencies to achieve essentially equivalent performance to WTP glass with supplemental treatment technologies, the BV process was modified in FY04 in an attempt to minimize deposition of soluble 99Tc salts by including a castable refractory block (CRB) in place of a portion of the refractory sand layer and using a bottom-up melting technique to eliminate the vesicular glass layer at the top. However, the refractory block is still porous and there is the potential for leachable 99Tc to deposit in the pores of the CRB. The purpose of this progress report is to document the status of a laboratory testing program being conducted at Pacific Northwest National Laboratory (PNNL) for CH2M Hill Hanford Group in support of the LAW Supplemental Treatment Technologies Demonstration project. The objective of these tests was to provide an initial estimate of the leachable fraction of key contaminants of concern (Cs, Re [chemical analogue for 99Tc], and 99Tc) that could condense within the BV CRB. This information will be used to guide development of additional modifications to the BV process to further reduce the soluble 99Tc levels in the BV waste package.

  2. Tc Reductant Chemistry and Crucible Melting Studies with Simulated Hanford Low-Activity Waste

    SciTech Connect (OSTI)

    Kim, Dong-Sang; Soderquist, Chuck Z.; Icenhower, Jonathan P.; McGrail, B PETER.; Scheele, Randall D.; McNamara, Bruce K.; Bagaasen, Larry M.; Schweiger, Michael J.; Crum, Jarrod V.; Yeager, John D.; Matyas, Josef; Darnell, Lori P.; Schaef, Herbert T.; Owen, Antionette T.; Kozelisky, Anne E.; Snow, Lanee A.; Steele, Marilyn J.


    The FY 2003 risk assessment (RA) of bulk vitrification (BV) waste packages used 0.3 wt% of the technetium (Tc) inventory as a leachable salt and found it sufficient to create a significant peak in the groundwater concentration in a 100-meter down-gradient well. Although this peak met regulatory limits, considering uncertainty in the actual Tc salt fraction, peak concentrations could exceed the maximum concentration limit (MCL) under some scenarios so reducing the leachable salt inventory is desirable. The main objective of this study was to reduce the mobile Tc species available within a BV disposal package by reducing the oxidation state of the Tc in the waste feed and/or during melting because Tc in its reduced form of Tc(IV) has a much lower volatility than Tc(VII). Reduced Tc volatility has a secondary benefit of increasing the Tc retention in glass.

  3. 1.9 kV AlGaN/GaN Lateral Schottky Barrier Diodes on Silicon

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhu, Mingda; Song, Bo; Qi, Meng; Hu, Zongyang; Nomoto, Kazuki; Yan, Xiaodong; Cao, Yu; Johnson, Wayne; Kohn, Erhard; Jena, Debdeep; et al


    In this letter, we present AlGaN/GaN lateral Schottky barrier diodes on silicon with recessed anodes and dual field plates. A low specific on-resistance RON,SP (5.12 mΩ · cm2), a low turn-on voltage (<0.7 V) and a high reverse breakdown voltage BV (>1.9 kV), were simultaneously achieved in devices with a 25 μm anode/cathode separation, resulting in a power figure-of-merit (FOM) BV2/RON,SP of 727 MW·cm2. The record high breakdown voltage of 1.9 kV is attributed to the dual field plate structure.

  4. Iii;.} An Ann

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Iii;.} An Ann otated Bibli ography of the Red - Coc kaded Woodpecker bv * Jerom e A. Jack son A Publi cati on of the Sava nnah River Plonl Notional En... ironmentol Research Pork PrOQ rom United Stales Dep ortment of Ene r gy An Annotated Bibliography of the Red-Cockaded Woodpecker, Picoides borealis Jerome A. Jackson Department of Biological Sciences Mississippi State University Mississippi State, Mississippi A Publication of the Savannah River National Environmental Research Park Prepared


    SciTech Connect (OSTI)



    A fractional crystallization (FC) process is being developed to supplement tank waste pretreatment capabilities provided by the Waste Treatment and Immobilization Plant (WTP). FC can process many tank wastes, separating wastes into a low-activity fraction (LAW) and high-activity fraction (HLW). The low-activity fraction can be immobilized in a glass waste form by processing in the bulk vitrification (BV) system.

  6. Final Technical Report: Genetic and Molecular Analysis of a new control pathway in assimilate partitioning.

    SciTech Connect (OSTI)

    Bush, Daniel, R.


    Assimilate partitioning refers to the systemic distribution of photoassimilate from sites of primary assimilation (source tissue) to import-dependent tissues and organs (sinks). One of the defining questions in this area is how plants balance source productivity with sink demand. We discovered a sucrose-sensing signal transduction pathway that controls the activity of BvSUT1, a proton-sucrose symporter in sugar beet leaf tissue. Sucrose symporters are responsible for sucrose accumulation in the phloem of many plants and, therefore, they mediate the pivotal step in the long-distance transport of photoassimilate to non-photosynthetic tissues, such as roots and seed. We previously showed that sucrose transport activity is directly proportional to the transcription rate of BvSUT1 and that symporter mRNA and protein have high rates of turnover with half-lives on the order of 2 h. We further demonstrated that symporter transcription is regulated by sucrose levels in the leaf and that sucrose-dependent regulation of BvSUT1 transcription is mediated, at least in part, by a protein phosphorylation relay pathway. The goal of the experiments during this current grant were to use genetic and molecular approaches to identify essential components of this vital regulatory system. The initial objectives were to: (1) to characterize Arabidopsis mutants we've isolated that are resistant to growth inhibition by sucrose analogues that are recognized by the sucrose-sensor, (2) to screen for loss of function mutants in BvSUT1-promoter:luciferase transgenic plants that no longer respond to sucrose accumulation in the leaf using non-destructive visualization of luciferase activity, (3) to use gel mobility-shift assays and nuclease protection experiments to identify cis elements in the symporter promoter and DNA-binding proteins that are involved in sucrose regulation of symporter expression.

  7. Reduced repair capacity of a DNA clustered damage site comprised of 8-oxo-7,8-dihydro-2'-deoxyguanosine and 2-deoxyribonolactone results in an increased mutagenic potential of these lesions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Cunniffe, Siobhan; O’Neill, Peter; Greenberg, Marc M.; Lomax, Martine E.


    A signature of ionizing radiation is the induction of DNA clustered damaged sites. Non-double strand break (DSB) clustered damage has been shown to compromise the base excision repair pathway, extending the lifetimes of the lesions within the cluster, compared to isolated lesions. This increases the likelihood the lesions persist to replication and thus increasing the mutagenic potential of the lesions within the cluster. Lesions formed by ionizing radiation include 8-oxo-7,8-dihydro-2'-deoxyguanosine (8-oxodGuo) and 2-deoxyribonolactone (dL). dL poses an additional challenge to the cell as it is not repaired by the short-patch base excision repair pathway. Here we show recalcitrant dL repairmore » is reflected in mutations observed when DNA containing it and a proximal 8-oxodGuo is replicated in Escherichia coli. 8-oxodGuo in close proximity to dL on the opposing DNA strand results in an enhanced frequency of mutation of the lesions within the cluster and a 20 base sequence flanking the clustered damage site in an E. coli based plasmid assay. In vitro repair of a dL lesion is reduced when compared to the repair of an abasic (AP) site and a tetrahydrofuran (THF), and this is due mainly to a reduction in the activity of polymerase β, leading to retarded FEN1 and ligase 1 activities. This study has given insights in to the biological effects of clusters containing dL.« less

  8. Investigation of Tc Migration Mechanism During Bulk Vitrification Process Using Re Surrogate

    SciTech Connect (OSTI)

    Kim, Dong-Sang; Bagaasen, Larry M.; Crum, Jarrod V.; Fluegel, Alex; Gallegos, Autumn B.; Martinez, Baudelio; Matyas, Josef; Meyer, Perry A.; Paulsen, Dan; Riley, Brian J.; Schweiger, Michael J.; Stewart, Charles W.; Swoboda, Robert G.; Yeager, John D.


    As a part of Bulk vitrification (BV) performance enhancement tasks, Laboratory scoping tests were performed in FY 2004-2005 to explore possible ways to reduce the amount of soluble Tc in the BV waste package. Theses scoping tests helped identify which mechanisms play an important role in the migration of Tc in the BV process (Hrma et al. 2005 and Kim et al. 2005). Based on the results from these scoping tests, additional tests were identified that will improve the understanding of Tc migration and to clearly identify the dominant mechanisms. The additional activities identified from previous studies were evaluated and prioritized for planning for Tasks 29 and 30 conducted in FY2006. Task 29 focused on the improved understanding of Tc migration mechanisms, and Task 30 focused on identifying the potential process changes that might reduce Tc/Re migration into the castable refractory block (CRB). This report summarizes the results from the laboratory- and crucible-scale tests in the lab for improved Tc migration mechanism understanding utilizing Re as a surrogate performed in Task 29.

  9. Effects of heavy metals on biomarkers for oxidative stress in Griffon vulture (Gyps fulvus)

    SciTech Connect (OSTI)

    Espn, Silvia; Martnez-Lpez, Emma; Jimnez, Pedro; Mara-Mojica, Pedro; Garca-Fernndez, Antonio J.


    Metals are involved in the formation of reactive oxygen species (ROS) which may result in metal-related oxidative stress that can lead to oxidative damage to lipids, DNA and proteins. It is necessary to understand the mechanisms of metal toxicity in wild birds, and the concentrations that cause effects on oxidative stress biomarkers. The aim of this study is to assess the concentrations of lead (Pb), cadmium (Cd), mercury (Hg), copper (Cu) and zinc (Zn) with regards to oxidative stress in blood samples of 66 Griffon vultures (Gyps fulvus) from two areas of the Autonomous Community of Valencia (East of Spain). The two study areas (Alcoy n=36 and Cinctorres n=30) were selected as random locations of interest that had not yet been studied, and are feeding stations where supplementary food, mainly of pork origin, is provided for vultures. Given that the two study areas are not considered polluted sites, we expected to find low metal concentrations. However, there are no known threshold concentrations at which metals can affect antioxidant systems, and low metal levels may have an effect on antioxidant biomolecules. In this study, since sampling was done at the beginning of the hunting season, the low Pb levels found in most Griffon vultures from Alcoy and Cinctorres (median=12.37 and 16.26 ?g/dl, respectively) are suggestive of background levels usually found in vultures that feed on pork carcasses all year round. The ingestion of game meat with bullet fragments in carcasses or with Pb shots embedded in the flesh could be the cause of the high blood Pb concentrations found in three vultures from Cinctorres (83, 290 and 362 ?g/dl). Griffon vultures feeding in Cinctorres had enhanced CAT and GST activities and tGSH concentrations, which may be interpreted as protective response against the higher TBARS levels. This study provides threshold concentrations at which metals affect antioxidant system derived from 66 samples of Griffon vulture. Blood Cd concentrations greater than 0.05 ?g/dl produced an induction of 33% in GPx and of 44% in CAT activity in erythrocytes of vultures from Alcoy. Hg concentrations in blood higher than 3 ?g/dl produced an induction of 10% in SOD activity. Concentrations of Pb above 15 g/dl in blood produced an inhibition of 12.5% in GPx and 11.3% in CAT activity, and a TBARS induction of 10.7% in erythrocytes of Griffon vultures. - Highlights: Except for 3 Griffon vultures, lead levels could be considered background levels. Three vultures may be exposed to meat with bullet fragments (blood Pb=83362 ?g/dl). Blood Cd levels?0.05 ?g/dl caused an induction of GPx and CAT activity (33% and 44%). Blood Hg levels?3 ?g/dl caused an induction of 10% in SOD activity. Blood Pb?15 g/dl caused an inhibition of GPx and CAT activity and a TBARS induction.


    SciTech Connect (OSTI)

    Nash, C.; Duignan, M.


    This report presents data on batch contact and column testing tasks for spherical resorcinol-formaldehyde (sRF) resin. The testing used a non-radioactive simulant of SRS Tank 2F dissolved salt, as well as an actual radioactive waste sample of similar composition, which are both notably high in sodium (6 M). The resin was Microbeads batch 5E-370/641 which had been made on the hundred gallon scale. Equilibrium batch contact work focused on cesium at a temperature of 25 C due to the lack of such data to better benchmark existing isotherm models. Two campaigns were performed with small-scale ion exchange columns, first with Tank 2F simulant, then with actual dissolved salt in the Shielded Cells. An extrapolation of the batch contact results with radioactive waste over-predicted the cesium loaded onto the IX sRF resin bed by approximately 11%. This difference is not unexpected considering uncertainties from measurement and extrapolation and because the ion exchange that occurs when waste flows through a resin bed probably cannot reach the same level of equilibrium as when waste and resin are joined in a long term batch contact. Resin was also characterized to better understand basic chemistry issues such as holdup of trace transition metals present in the waste feed streams. The column tests involved using two beds of sRF resin in series, with the first bed referred to as the Lead column and the second bed as the Lag column. The test matrix included two complete IX cycles for both the simulant and actual waste phases. A cycle involves cesium adsorption, until the resin in the Lead column reaches saturation, and then regenerating the sRF resin, which includes eluting the cesium. Both the simulated and the actual wastes were treated with two cycles of operation, and the resin beds that were used in the Lead and Lag columns of simulant test phase were regenerated and reused in the actual waste test phase. This task is the first to demonstrate the treatment of SRS waste with sRF resin and the tests clearly demonstrated cesium decontamination for actual waste. The results of the column tests were similar for both the simulated and the actual waste and demonstrated Cs removal with sRF from both wastes. For a flowrate of 1.4 bed volumes (BV)/hour at 25 C those results with sRF resin were: (1) Simulant and actual waste results are equivalent; (2) Cs breakthrough began between 200 and 250 BV; (3) Cs breakthrough reached 100% at around 400 BV; (4) Cs breakthrough curve from 5% to 100% is approximately linear; (5) Cs elution with 0.5 M HNO3 starts at 2 BV and ends at 6BV; (6) Most, if not all, of Cs adsorbed during treatment is released during elution; (7) At 100% breakthrough of Cs the resin bed adsorbs approximately 85% of full capacity before detection in the effluent; the remaining 15% is adsorbed at saturation; (8) Approximately 90% of resin bed changes (color and volume) are complete by 6 BV; and (9) During elution the resin shrinks to about 80% of its fully working (sodium form) BV.

  11. A double-layer based model of ion confinement in electron cyclotron resonance ion source

    SciTech Connect (OSTI)

    Mascali, D. Neri, L.; Celona, L.; Castro, G.; Gammino, S.; Ciavola, G.; Torrisi, G.; Universit Mediterranea di Reggio Calabria, Dipartimento di Ingegneria dellInformazione, delle Infrastrutture e dellEnergia Sostenibile, Via Graziella, I-89100 Reggio Calabria ; Sorbello, G.; Universit degli Studi di Catania, Dipartimento di Ingegneria Elettrica Elettronica ed Informatica, Viale Andrea Doria 6, 95125 Catania


    The paper proposes a new model of ion confinement in ECRIS, which can be easily generalized to any magnetic configuration characterized by closed magnetic surfaces. Traditionally, ion confinement in B-min configurations is ascribed to a negative potential dip due to superhot electrons, adiabatically confined by the magneto-static field. However, kinetic simulations including RF heating affected by cavity modes structures indicate that high energy electrons populate just a thin slab overlapping the ECR layer, while their density drops down of more than one order of magnitude outside. Ions, instead, diffuse across the electron layer due to their high collisionality. This is the proper physical condition to establish a double-layer (DL) configuration which self-consistently originates a potential barrier; this barrier confines the ions inside the plasma core surrounded by the ECR surface. The paper will describe a simplified ion confinement model based on plasma density non-homogeneity and DL formation.

  12. Dynamical consequences of a constraint on the Langevin thermostat in molecular cluster simulation

    SciTech Connect (OSTI)

    Stinson, Jake L.; Kathmann, Shawn M.; Ford, Ian J.


    We investigate some unusual behaviour observed while performing molecular dynamics simulations with the DL_POLY_4.03 code. Under the standard Langevin thermostat, atoms appear to be thermalised to different temperatures, depending on their mass and on the total number of particles in the system. We find that an imposed constraint whereby no thermal noise acts on the centre of mass of the system is the cause of the unexpected behaviour. This is demonstrated by solving the stochastic dynamics for the constrained thermostat and comparing the results with simulation data. The effect of the constraint can be considerable for small systems with disparate masses. By removing the constraint the Langevin thermostat may be restored to its intended behaviour and this has been implemented as an option in DL_POLY_4.05. SMK was supported by the U.S. Department of Energy, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences, and Biosciences.

  13. 1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Impact of Forward Scattering Spectrometer Probe Measured Ice Crystals on the Community Atmospheric Model D.L. Mitchell, and D. Ivanova Desert Research Institute Reno, Nevada P. Rasch National Center for Atmospheric Research Boulder, Colorado G. McFarquhar and T. Nousiainen University of Illinois Urbana, Illinois Comparison of Mid-Latitude and Tropical Anvil Size Distribution Schemes There is growing evidence that the concentrations of small ice crystals (D < 70 μm) exceed peak concentrations

  14. 1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Developments and Accomplishments at the ARM Climate Research Facility Southern Great Plains Site During 2005 B.W. Orr and D.L. Sisterson Argonne National Laboratory Argonne, Illinois D.J. Rusk ARM Climate Research Facility/Southern Great Plains Cherokee Nation Distributors Stilwell, Oklahoma New Instruments New instruments were installed at the ARM Climate Research Facility (ACRF) in 2005. This paper discusses these developments as well as accomplishments that occurred during the year. W-Band

  15. Conditions for diffusion-limited and reaction-limited recombination in nanostructured solar cells

    SciTech Connect (OSTI)

    Ansari-Rad, Mehdi; Department of Physics, University of Shahrood, Shahrood ; Anta, Juan A.; Arzi, Ezatollah


    The performance of Dye-sensitized solar cells (DSC) and related devices made of nanostructured semiconductors relies on a good charge separation, which in turn is achieved by favoring charge transport against recombination. Although both processes occur at very different time scales, hence ensuring good charge separation, in certain cases the kinetics of transport and recombination can be connected, either in a direct or an indirect way. In this work, the connection between electron transport and recombination in nanostructured solar cells is studied both theoretically and by Monte Carlo simulation. Calculations using the Multiple-Trapping model and a realistic trap distribution for nanostructured TiO{sub 2} show that for attempt-to-jump frequencies higher than 10{sup 11}10{sup 13} Hz, the system adopts a reaction limited (RL) regime, with a lifetime which is effectively independent from the speed of the electrons in the transport level. For frequencies lower than those, and depending on the concentration of recombination centers in the material, the system enters a diffusion-limited regime (DL), where the lifetime increases if the speed of free electrons decreases. In general, the conditions for RL or DL recombination depend critically on the time scale difference between recombination kinetics and free-electron transport. Hence, if the former is too rapid with respect to the latter, the system is in the DL regime and total thermalization of carriers is not possible. In the opposite situation, a RL regime arises. Numerical data available in the literature, and the behavior of the lifetime with respect to (1) density of recombination centers and (2) probability of recombination at a given center, suggest that a typical DSC in operation stays in the RL regime with complete thermalization, although a transition to the DL regime may occur for electrolytes or hole conductors where recombination is especially rapid or where there is a larger dispersion of energies of electron acceptors.

  16. Mr. Carl Schafer Director of Environmental Policy

    Office of Legacy Management (LM)

    Designeoguns and nuclear projectiles. Radioactive material involvement in the operations is unknown. Believed to have assembled bomb compone$s. Identified on 1954 Accountable Station Lists. /,, i: .; ." , !: ' .. 12. 13. ENCLOSURE 2 (Cont'dl DEPARTMENT OF THE DEFENSE INSTALLATIONS/FACILITIES Installation/Facility MED/AEC Activity Naval Research Laboratory (Former Anacostia Naval Air Station) Washington,. DC Nellis Air Force,Base (*I Las Vegas, NV Conducted research and.development

  17. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Most Systematic Errors in Climate Models Appear in Only a Few Days of Model Integration Download a printable PDF Submitter: Ma, H., Lawrence Livermore National Laboratory Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Life Cycle Journal Reference: Ma H, S Xie, SA Klein, KD Williams, JS Boyle, S Bony, H Douville, S Fermepin, B Medeiros, S Tyteca, M Watanabe, and DL Williamson. 2014. "On the correspondence between mean forecast errors and climate errors in

  18. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Weather Prediction and Climate Simulation: a Meeting of the Models Submitter: Xie, S., Lawrence Livermore National Laboratory Area of Research: General Circulation and Single Column Models/Parameterizations Working Group(s): Cloud Modeling Journal Reference: Phillips, T. J. G.L. Potter, D.L. Williamson, R.T. Cederwall, J.S. Boyle, M. Fiorino, J.J. Hnilo, J.G. Olson, S. Xie, J.J. Yio, Evaluating Parameterizations in General Circulation Models: Climate Simulation Meets Weather Prediction, Bulletin

  19. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Partial Mechanistic Understanding of the North American Monsoon Download a printable PDF Submitter: Erfani, E., Desert Research Institute Area of Research: Atmospheric Thermodynamics and Vertical Structures Working Group(s): Cloud-Aerosol-Precipitation Interactions Journal Reference: Erfani E and DL Mitchell. 2014. "A partial mechanistic understanding of the North American monsoon." Journal of Geophysical Research - Atmospheres, 119(23), 10.1002/2014JD022038. a) Dependence of

  20. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ice Particle Projected Area- and Mass-Dimension Expressions for Cirrus Clouds Download a printable PDF Submitter: Mitchell, D. L., Desert Research Institute Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Life Cycle Journal Reference: Erfani E and DL Mitchell. 2015. "Developing and bounding ice particle mass- and area-dimension expressions for use in atmospheric models and remote sensing." Atmospheric Chemistry and Physics, 15(20),

  1. Publications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sensors and Sensing Technologies Sensors and Sensing Technologies Publications Journal articles on Sensors and Sensing Technologies Contact Institute Director Charles Farrar (505) 663-5330 Email UCSD EI Director Michael Todd (858) 534-5951 Professional Staff Assistant Ellie Vigil (505) 667-2818 Email Administrative Assistant Rebecca Duran (505) 665-8899 Email Journal Articles Stull, C.J., Taylor, S. G., Wren, J., Mascarenas, D.L., Farrar, C. R., "Real-Time Condition Assessment of the Raptor

  2. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Surface Summertime Radiative Forcing by Shallow Cumuli at the ARM SGP Download a printable PDF Submitter: Berg, L., Pacific Northwest National Laboratory Area of Research: Radiation Processes Working Group(s): Cloud Life Cycle Journal Reference: Berg LK, EI Kassianov, CN Long, and DL Mills. 2011. "Surface summertime radiative forcing by shallow cumuli at the ARM SGP." Journal of Geophysical Research - Atmospheres, 116, D01202, 10.1029/2010JD014593. Histogram of hourly average shortwave

  3. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Possible Impact of Homogeneous Freezing Nucleation on in Situ Measurements Download a printable PDF Submitter: Mitchell, D. L., Desert Research Institute Mishra, S., DOE - SunShot Initiative, AAAS S&T Policy Fellow Area of Research: Cloud Distributions/Characterizations Working Group(s): Cloud Life Cycle, Cloud-Aerosol-Precipitation Interactions Journal Reference: Mitchell DL, S Mishra, and RP Lawson. 2011. Cirrus Clouds and Climate Engineering: New Findings on Ice Nucleation and Theoretical

  4. ARM Mentor Selection Process

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 ARM Mentor Selection Process Revision 1 DL Sisterson October 2015 DOE/SC-ARM-13-003 DISCLAIMER This report was prepared as an account of work sponsored by the U.S. Government. Neither the United States nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe

  5. ARM Mentor Selection Process

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 ARM Mentor Selection Process DL Sisterson October 2015 DOE/SC-ARM-TR-171 DISCLAIMER This report was prepared as an account of work sponsored by the U.S. Government. Neither the United States nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately

  6. Ms. Maria Galanti Site Coordinator

    Energy Savers [EERE]

    3 0 2015 Ohio Environmental Protection Agency Southeast District Office 2195 Front Street Logan, Ohio 43138 Dear Ms. Galanti: PPP0-03-3065331-15 FINAL RECORD OF DECISION FOR THE PROCESS BUILDINGS AND COMPLEX FACILITIES DECONTAMINATION AND DECOMMISSIONING EVALUATION PROJECT AT THE PORTSMOUTH GASEOUS DIFFUSION PLANT, PIKETON, OHIO (DOE/PPP0/03-0425&Dl) References: 1. Letter from W. Murphie to M. Galanti, "Record of Decision for the Process Buildings and Complex Facilities Decontamination

  7. NMMSS News-October/November 2005

    National Nuclear Security Administration (NNSA)

    OCTOBER/NOVEMBER 2005 SPONSORED BY DOE AND NRC PREPARED BY NAC INTERNATIONAL Office of Security and Safety Performance Assurance Reorganized On October 21, 2005, the DOE Office of Security and Safety Performance Assurance (SSA) announced its new Office of Material Control and Accountability (SP-70) with D.L. Whaley as the acting director. The Office of Material Control and Accountability is responsible for all aspects of SSA's material control and accountability (MC&A) and sealed source

  8. Draft - DOE G 410.2-1, Nuclear Material Disposition

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    This document provides a roadmap for implementing the requirements for disposition of nuclear material as outlined in the U.S. Department of Energy (DOE) Order 410.2, Management of Nuclear Materials, and DOE Order 474.2, Nuclear Material Control and Accountability. This Guide provides the basic framework for the nuclear material disposition process, includes information related to the Programmatic Value Determination (PVD) process, and identifies Discard Limits (DL) for specific low-equity nuclear materials.


    SciTech Connect (OSTI)

    Bianco, F. B.; Modjaz, M. [Center for Cosmology and Particle Physics, New York University, 4 Washington Place, New York, NY 10003 (United States); Hicken, M.; Friedman, A.; Kirshner, R. P.; Challis, P.; Marion, G. H. [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Bloom, J. S. [Department of Astronomy, University of California, Berkeley, CA 94720-3411 (United States); Wood-Vasey, W. M. [PITT PACC, Department of Physics and Astronomy, 3941 O'Hara Street, University of Pittsburgh, Pittsburgh, PA 15260 (United States); Rest, A., E-mail: [Space Telescope Science Institute, 3700 San Martin Drive, Baltimore, MD 21218 (United States)


    We present a densely sampled, homogeneous set of light curves of 64 low-redshift (z ? 0.05) stripped-envelope supernovae (SNe of Type IIb, Ib, Ic, and Ic-BL). These data were obtained between 2001 and 2009 at the Fred L. Whipple Observatory (FLWO) on Mount Hopkins in Arizona, with the optical FLWO 1.2 m and the near-infrared (NIR) Peters Automated Infrared 1.3 m telescopes. Our data set consists of 4543 optical photometric measurements on 61 SNe, including a combination of U BV RI, U BV r{sup ?}i{sup ?}, and u{sup ?} BV r{sup ?}i{sup ?}, and 1919 JHK{sub s} NIR measurements on 25 SNe. This sample constitutes the most extensive multi-color data set of stripped-envelope SNe to date. Our photometry is based on template-subtracted images to eliminate any potential host-galaxy light contamination. This work presents these photometric data, compares them with data in the literature, and estimates basic statistical quantities: date of maximum, color, and photometric properties. We identify promising color trends that may permit the identification of stripped-envelope SN subtypes from their photometry alone. Many of these SNe were observed spectroscopically by the Harvard-Smithsonian Center for Astrophysics (CfA) SN group, and the spectra are presented in a companion paper. A thorough exploration that combines the CfA photometry and spectroscopy of stripped-envelope core-collapse SNe will be presented in a follow-up paper.


    SciTech Connect (OSTI)

    Kyser, E.; King, W.


    Non-radioactive cerium (Ce) and radioactive plutonium (Pu) anion exchange column experiments using scaled HB-Line designs were performed to investigate the feasibility of using either gadolinium nitrate (Gd) or boric acid (B as H{sub 3}BO{sub 3}) as a neutron poison in the H-Canyon dissolution process. Expected typical concentrations of probable impurities were tested and the removal of these impurities by a decontamination wash was measured. Impurity concentrations are compared to two specifications - designated as Column A or Column B (most restrictive) - proposed for plutonium oxide (PuO{sub 2}) product shipped to the Mixed Oxide (MOX) Fuel Fabrication Facility (MFFF). Use of Gd as a neutron poison requires a larger volume of wash for the proposed Column A specification. Since boron (B) has a higher proposed specification and is more easily removed by washing, it appears to be the better candidate for use in the H-Canyon dissolution process. Some difficulty was observed in achieving the Column A specification due to the limited effectiveness that the wash step has in removing the residual B after {approx}4 BV's wash. However a combination of the experimental 10 BV's wash results and a calculated DF from the oxalate precipitation process yields an overall DF sufficient to meet the Column A specification. For those impurities (other than B) not removed by 10 BV's of wash, the impurity is either not expected to be present in the feedstock or process, or recommendations have been provided for improvement in the analytical detection/method or validation of calculated results. In summary, boron is recommended as the appropriate neutron poison for H-Canyon dissolution and impurities are expected to meet the Column A specification limits for oxide production in HB-Line.


    SciTech Connect (OSTI)

    Kyser, E. A.; King, W. D.


    Non-radioactive cerium (Ce) and radioactive plutonium (Pu) anion exchange column experiments using scaled HB-Line designs were performed to investigate the feasibility of using either gadolinium nitrate (Gd) or boric acid (B as H{sub 3}BO{sub 3}) as a neutron poison in the H-Canyon dissolution process. Expected typical concentrations of probable impurities were tested and the removal of these impurities by a decontamination wash was measured. Impurity concentrations are compared to two specifications - designated as Column A or Column B (most restrictive) - proposed for plutonium oxide (PuO{sub 2}) product shipped to the Mixed Oxide (MOX) Fuel Fabrication Facility (MFFF). Use of Gd as a neutron poison requires a larger volume of wash for the proposed Column A specification. Since boron (B) has a higher proposed specification and is more easily removed by washing, it appears to be the better candidate for use in the H-Canyon dissolution process. Some difficulty was observed in achieving the Column A specification due to the limited effectiveness that the wash step has in removing the residual B after ~4 BV's wash. However a combination of the experimental 10 BV's wash results and a calculated DF from the oxalate precipitation process yields an overall DF sufficient to meet the Column A specification. For those impurities (other than B) not removed by 10 BV's of wash, the impurity is either not expected to be present in the feedstock or process, or recommendations have been provided for improvement in the analytical detection/method or validation of calculated results. In summary, boron is recommended as the appropriate neutron poison for H-Canyon dissolution and impurities are expected to meet the Column A specification limits for oxide production in HB-Line.

  12. Highly transparent ammonothermal bulk GaN substrates

    SciTech Connect (OSTI)

    Jiang, WK; Ehrentraut, D; Downey, BC; Kamber, DS; Pakalapati, RT; Do Yoo, H; D'Evelyn, MP


    A novel apparatus has been employed to grow ammonothermal (0001) gallium nitride (GaN) with diameters up to 2 in The crystals have been characterized by x-ray diffraction rocking-curve (XRC) analysis, optical and scanning electron microscopy (SEM), cathodoluminescence (CL), and optical spectroscopy. High crystallinity GaN with FWHM values about 20-50 arcsec and dislocation densities below 1 x 10(5) cm(-2) have been obtained. High optical transmission was achieved with an optical absorption coefficient below 1 cm(-1) at a wavelength of 450 nm. (C) 2014 Elsevier B.V. All rights reserved.

  13. Synthesis of high magnetization Fe and FeCo nanoparticles by high temperature chemical reduction

    SciTech Connect (OSTI)

    Kandapallil, B; Colborn, RE; Bonitatibus, PJ; Johnson, F


    Fe and FeCo ferromagnetic nanoparticles in the 5-10 nm size regimes featuring high magnetization were synthesized using a modified chemical reduction method. The structure and morphology of these nanoparticles were confirmed by XRD and TOM analysis. These small, monodisperse and phase pure nanoparticles exhibited magnetic saturation of 210 emu/g (Fe) and 220 emu/g (Fe+Co) for Fe and FeCo nanoparticles respectively. The magnetization was found to be dependent on the temperature at which the reducing agent was introduced. (C) 2014 Elsevier B.V. All rights reserved,

  14. Biomimicry in metal-organic materials

    SciTech Connect (OSTI)

    Zhang, MW; Gu, ZY; Bosch, M; Perry, Z; Zhou, HC


    Nature has evolved a great number of biological molecules which serve as excellent constructional or functional units for metal-organic materials (MOMs). Even though the study of biomimetic MOMs is still at its embryonic stage, considerable progress has been made in the past few years. In this critical review, we will highlight the recent advances in the design, development and application of biomimetic MOMs, and illustrate how the incorporation of biological components into MOMs could further enrich their structural and functional diversity. More importantly, this review will provide a systematic overview of different methods for rational design of MOMs with biomimetic features. Published by Elsevier B.V.

  15. ORIGINAL ARTICLE Radionuclide Concentrations in Benthic Invertebrates

    Office of Legacy Management (LM)

    Environ Monit Assess (2007) 128:329-341 DO1 10.1007/~10661-006-93 I 6 4 ORIGINAL ARTICLE - Radionuclide Concentrations in Benthic Invertebrates from Amchitka and Kiska Islands in the Aleutian Chain, Alaska Joanna Burger Michael Gochfeld Stephen C. Jewett Received: 8 March 2006 /Accepted: 8 May 2006 1 Published online: 21 October 2006 0 Springer Science + Business Media B.V. 2006 Abstract Concentrations of 13 radionuclides 1291, 60co, 1 5 2 ~ ~ , 9 0 s r , 9 9 ~ ~ , 2 4 1 ~ ~ , 238pu, 239249pu, 2

  16. Formation of lithium fluoride/metal nanocomposites for energy storage through solid state reduction of metal fluorides

    SciTech Connect (OSTI)

    Amatucci, GG; Pereira, N; Badway, F; Sina, M; Cosandey, F; Ruotolo, M; Cao, C


    In order to utilize high energy metal fluoride electrode materials as direct replacement electrode materials for lithium ion batteries in the future, a methodology to prelithiate the cathode or anode must be developed. Herein, we introduce the use of a solid state Li(3)N route to achieve the lithiation and mechanoreduction of metal fluoride based nanocomposites. The resulting prelithiation was found to be effective with the formation of xLiF:Me structures of very fine nanodimensions analogous to what is found by electrochemical lithiation. Physical and electrochemical properties of these nanocomposites for the bismuth and iron lithium fluoride systems are reported. (C) 2011 Elsevier B.V. All rights reserved.

  17. Finite-size scaling analysis of spin correlations and fluctuations of two quantum dots in a T-shape geometry

    SciTech Connect (OSTI)

    Heidrich-Meisner, Fabian; Martins, G. B.; Al Hassanieh, Khaled A; Feiguin, A. E.; Dagotto, Elbio R


    The study of interacting nanostructures such as quantum dots is a playground for several novel numerical approaches. Recently developed methods such as the time-dependent density matrix renormalization approach or the embedded-cluster approximation rely on the numerical solution of clusters of finite-size. For the interpretation of numerical results, it is important to understand finite-size and boundary effects. Here, we study spin fluctuations and spin spin correlations of two dots coupled in a T-shape geometry. Depending on odd even effects, quite different results emerge from clusters that do not differ much in size. r 2007 Elsevier B.V. All rights reserved.

  18. Measuring Broadband IR Irradiance in the Direct Solar Beam (Poster), NREL (National Renewable Energy Laboratory)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Broadband IR Irradiance in the Direct Solar Beam Ibrahim Reda 1 , Jörgen Konings 2 , Yu Xie 1 , Mike Dooraghi 1 , Manajit Sengupta 1 1 National Renewable Energy Laboratory (NREL), 2 Hukseflux Thermal Sensors B.V. Atmospheric System Research (ASR) Science Team Meeting, March 12-16, 2015 in Crystal City, Virginia NREL/PO-3B10-63754 This work is funded by DOE/ASR program, NREL's PV program, and NREL's Metrology Laboratory Abstract: Solar and atmospheric science radiometers, e.g. pyranometers,

  19. U. S. Government purposes. ANL-HEP-CP-88-42

    Office of Scientific and Technical Information (OSTI)

    authored bv a comracior>oi the U. S. Government under contract No. W-31-109-ENG-38, Accordingly, the U. S. Government retains a nonexclusive, royalty-tree license to publish or reproduce the published form of this contribution, or allow others to do so, for U. S. Government purposes. ANL-HEP-CP-88-42 DE89 003647 NUCLEAR DEPENDENCE OF STRUCTURE FUNCTIONS IN THE SHADOWING REGION OF DEEP INELASTIC SCATTERING* EDMOND L. BERGER and JIANWEI QIU High Energy Physics Division, Argonne Natiorjd

  20. Predicting susceptibility of alloy 600 to intergranular stress corrosion cracking using a modified electrochemical potentiokinetic reactivation test

    SciTech Connect (OSTI)

    Ahn, M.K.; Kwon, H.S.; Lee, J.H.


    Modified double-loop electrochemical potentiokinetic reactivation (DL-EPR) tests were applied to evaluate the degree of sensitization (DOS) for alloy 600 aged at 700 C. Results of the modified DL-EPR test were compared to intergranular stress corrosion cracking (IGSCC) susceptibilities determined in deaerated 0.01 M sodium tetrathionate under deformation at a constant strain rate of 0.93 {times} 10{sup {minus}6}/s. By analyzing the effects of solution concentration, temperature, and scan rate on the electrochemical response in the EPR tests and the morphologies, the optimal modified DL-EPR test condition for alloy 600 was obtained in 0.01 M sulfuric acid + 10 ppm potassium thiocyanate at 25 C and at a scan rate of 0.5 mV/s. The standard DL-EPR test, performed under conditions of 0.5 M H{sub 2}SO{sub 4} + 0.01 M KCNS at 30 C and a scan rate of 1.67 mV/s, provided very poor discriminating power for various DOS of alloy 600 because general and pitting corrosion occurred, in addition to intergranular corrosion. The modified test, however, was highly discriminating because of its highly selective corrosion attack at grain boundaries. IGSCC occurred in samples of alloy 600 aged for < 20 h, and susceptibility to IGSCC{sub s} increased with decreasing aging times up to 1 h, showing maximum IGSCC{sub s} in the sample aged for 1 h. IGSCC{sub s} for the alloy was found to be associated closely with the chromium-depleted profile across grain boundaries. The deeper and narrower chromium-depleted zone produced greater IGSCC{sub s}. It was demonstrated that DOS measured by the modified DL-EPR test was correlated more closely with IGSCC{sub s} than was DOS measured by the standard EPR test. This correlation resulted from the fact that the modified EPR test selectively attacked the more deeply chromium-depleted regions in comparison to the standard EPR test.

  1. Finite field-dependent symmetries in perturbative quantum gravity

    SciTech Connect (OSTI)

    Upadhyay, Sudhaker


    In this paper we discuss the absolutely anticommuting nilpotent symmetries for perturbative quantum gravity in general curved spacetime in linear and non-linear gauges. Further, we analyze the finite field-dependent BRST (FFBRST) transformation for perturbative quantum gravity in general curved spacetime. The FFBRST transformation changes the gauge-fixing and ghost parts of the perturbative quantum gravity within functional integration. However, the operation of such symmetry transformation on the generating functional of perturbative quantum gravity does not affect the theory on physical ground. The FFBRST transformation with appropriate choices of finite BRST parameter connects non-linear CurciFerrari and Landau gauges of perturbative quantum gravity. The validity of the results is also established at quantum level using BatalinVilkovisky (BV) formulation. -- Highlights: The perturbative quantum gravity is treated as gauge theory. BRST and anti-BRST transformations are developed in linear and non-linear gauges. BRST transformation is generalized by making it finite and field dependent. Connection between linear and non-linear gauges is established. Using BV formulation the results are established at quantum level also.

  2. Applications of large-eddy simulation: Synthesis of neutral boundary layer models

    SciTech Connect (OSTI)

    Ohmstede, W.D.


    The object of this report is to describe progress made towards the application of large-eddy simulation (LES), in particular, to the study of the neutral boundary layer (NBL). The broad purpose of the study is to provide support to the LES project currently underway at LLNL. The specific purpose of this study is to lay the groundwork for the simulation of the SBL through the establishment and implementation of model criteria for the simulation of the NBL. The idealistic NBL is never observed in the atmosphere and therefore has little practical significance. However, it is of considerable theoretical interest for several reasons. The report discusses the concept of Rossby-number similarity theory as it applies to the NBL. A particular implementation of the concept is described. Then, the results from prior simulations of the NBL are summarized. Model design criteria for two versions of the Brost LES (BLES) model are discussed. The general guidelines for the development of Version 1 of the Brost model (BV1) were to implement the model with a minimum of modifications which would alter the design criteria as established by Brost. Two major modifications of BLES incorporated into BV1 pertain to the initialization/parameterization of the model and the generalization of the boundary conditions at the air/earth interface. 18 refs., 4 figs.

  3. Numerical simulations used for a validity check on the laser induced photo-detachment diagnostic method in electronegative plasmas

    SciTech Connect (OSTI)

    Oudini, N.; Taccogna, F.; Aanesland, A.


    Laser photo-detachment is used as a method to measure or determine the negative ion density and temperature in electronegative plasmas. In essence, the method consists of producing an electropositive channel (negative ion free region) via pulsed laser photo-detachment within an electronegative plasma bulk. Electrostatic probes placed in this channel measure the change in the electron density. A second pulse might be used to track the negative ion recovery. From this, the negative ion density and temperature can be determined. We study the formation and relaxation of the electropositive channel via a two-dimensional Particle-In-Cell/Mote Carlo collision model. The simulation is mainly carried out in a Hydrogen plasma with an electronegativity of ??=?1, with a parametric study for ? up to 20. The temporal and spatial evolution of the plasma potential and the electron densities shows the formation of a double layer (DL) confining the photo-detached electrons within the electropositive channel. This DL evolves into two fronts that move in the opposite directions inside and outside of the laser spot region. As a consequence, within the laser spot region, the background and photo-detached electron energy distribution function relaxes/thermalizes via collisionless effects such as Fermi acceleration and Landau damping. Moreover, the simulations show that collisional effects and the DL electric field strength might play a non-negligible role in the negative ion recovery within the laser spot region, leading to a two-temperature negative ion distribution. The latter result might have important effects in the determination of the negative ion density and temperature from laser photo detachment diagnostic.

  4. Low Background Counting at LBNL

    Office of Scientific and Technical Information (OSTI)

    1 (2015) 787 - 795 Physics Procedia Low Background Counting at LBNL A.R. Smitha, K.J. Thomasb'a, E.B. Normanb'a, Y.D. Chana, K.T. Leskoc, D.L. Hurleya aNuclear Science Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720 bDepartment of Nuclear Engineering, University of California, Berkeley, CA 94720 cPhysics Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720 Abstract The Low Background Facility (LBF) at Lawrence Berkeley National Laboratory in Berkeley,

  5. EC Publications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    al1.pdf filesize 544.75 kB Version 1 date 6-10 July 1998 Downloaded 55 times Category Energy Security, Manual, Photovoltaic, Renewable Energy, Solar Energy, Technology Validation author D.L. King, W.E. Boyson, B.R. Hansen, and W.I. Bower, Sandia event 2nd World Conference and Exhibition on Photovoltaic Solar Energy Conversion location Vienna, Austria Accurate measurements of broadband (full spectrum) solar irradiance are fundamental to the successful implementation of solar power systems, both

  6. EC Publications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    al.pdf filesize 544.75 kB Version 1 date 6-10 July 1998 Downloaded 89 times Category Energy Security, Manual, Photovoltaic, Renewable Energy, Solar Energy, Technology Validation event 2nd World Conference and Exhibition on Photovoltaic Solar Energy Conversion location Vienna, Austria year 1998 author D.L. King, W.E. Boyson, B.R. Hansen, W.I. Bower Thousands of photovoltaic systems, large and small, are now being installed worldwide. As a result, there is a growing demand for inexpensive devices


    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Document(s) responsive to Item 1 TOC-ENV-NOT-2013-0019 Rev. 0 ENVIRONMENTAL NOTIFICATION FORM Date: 02/15/2013 Notification No.: TOC-ENV-NOT- 2013-0019 Name: D.L. Dyekman Revision No. 0 Section 1. Spills NA M ChemicalName: see section 3 below MSDS No.: n/a Regulated per 40 CFR 302: Yes 0 No 13EPCRA EHS: Yes Z No E3 CAS No.: n/ a Quantity Released: up to 300gal/yr Reportable Quantity (RO):_________ CAS No.: ________Quantity Released: ___________Reportable Quantity (RO):__________ CAS No.:

  8. Mr. Carl Schafer Director of Environmental Policy

    Office of Legacy Management (LM)

    Cont'dl DEPARTMENT OF THE DEFENSE INSTALLATIONS/FACILITIES Installation/Facility MED/AEC Activity Naval Research Laboratory (Former Anacostia Naval Air Station) Washington,. DC Nellis Air Force,Base (*I Las Vegas, NV Conducted research and.development activi,ties on thermal diffusion. A.pilot plant (S-50 Plant).was built at the former Anacostia Naval ./Y Air Station to separate uranium isotopes by ;,~!,c liquid thermal diffusion. A letter dated 26 Aug 1969 from the Commanding Officer, Lake Mead


    Office of Legacy Management (LM)

    ' PLEAEERUSH ANALYTICAL DA-~-A SHEET ' ANALYTICAL DEPT. - HEALTH AhD SAFETY DlVlSlON 1956 Industrial Hygiene or Medical Dept. 1. H.#~~Sample Nos. 3 --Date Collected~~by-CESS-.Route to CBS LocationTITANIUM Type of Sample airnalyzed for F Alpham Remarks NIAGARA pALI+S* N.Y. U Beta Bldg. 103 - furnace room - -NO, Ra Oil PH Be Th Sample No. Hour Sample Description I I I--- R ) T 1 Q I I I 7392 1100 GA Induction furnace area duri-nn ----l----- mDeriod;.02; 151 .3 while furnace was charged with UOT_-


    Office of Legacy Management (LM)

    PRODUCTIOR"OF TRORI~JW~IETALIWES PROCESS F6R RB)IJCIRO T&Old 2 ': am wm ..,. :I.::. ? ; \: :.:, .,, : ,. / 1. ..ri:,:,.:, :/ I 8yblBOLa PPaJPT i: >. ,,;.;~:,,; ,;.. !,., ,ip; ,,,:. ;., -. , ^ , . . 3 '>) ! .,:<;:,,..,. ; : :..,, ,,.+ -../ ,:,; I,:;?: ..: : ,, ,,: ; !. (' '; ::, Durine,~~~v%eit'to Amae &8Htate~Coliegd on Mar6h 4 and 2 to dl&ni& prinalpally~~asl~~prd~ess~~~1 also r&&&d wltlvDii 8. Wilhelm and Dr. D. Peterson of An~?e Iowa State College

  11. SITES ELIHlNAlED FRCil FUW' ~1WWk'l ffi LY

    Office of Legacy Management (LM)

    SITES ELIHlNAlED FRCil FUW' ~1WWk'l ffi LY Lfcfi0n 31, I?%7 STGTE m rtE!xm ICmFIED cm&B fi re3xf.H ROJECT TIM #% HER M JWDlCTICd Cf M W.&f&t ff NIF, Ml TtE FKILIIY If0 LICWSES TO WRE ffiDliXClIVE tt%iML. IVJ R&w mm IS h-m. STTE S#W MC&TED W P4DlOKTIVIN kmvi t+mi BkcTmam

  12. Revised for pdf of instruments 8.5x11 (2)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)


  13. S P

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    S P 0 s 00 0 t 4 ENVIRONMENTAL PROTECTION DlVMON OF ENVIRONMENTAL PROTECTION Leo M. Drozdofi flE.,Adrninistral b e - protecting the future for generations o + August 2,2006 Ms. Angela P. Colarusso, Acting Federal Project Director Waste Management Project National Nuclear Security Administration Nevada Site Office P.O. Box 9851 8 Las Vegas, NV 891 93-851 8 Re: Regulatory Position Regarding Void Space The Nevada Division of Environmental Protection, Bureau of Federal Facilities (NDEP) has been

  14. Hemoglobin Labeled by Radioactive Lysine

    DOE R&D Accomplishments [OSTI]

    Bale, W. F.; Yuile, C. L.; DeLaVergne, L.; Miller, L. L.; Whipple, G. H.


    This paper reports on the utilization of tagged epsilon carbon of DL-lysine by a dog both anemic and hypoproteinemic due to repeated bleeding plus a diet low in protein. The experiment extended over period of 234 days, a time sufficient to indicate an erythrocyte life span of at least 115 days based upon the rate of replacement of labeled red cell proteins. The proteins of broken down red cells seem not to be used with any great preference for the synthesis of new hemoglobin.


    U.S. Energy Information Administration (EIA) Indexed Site


  16. United States Government

    Office of Legacy Management (LM)

    DOE F t325.8 (s8s) Dl? l 36-z EFG (07-90) United States Government m e m o randum Department of Energy DATE: LUG 2 ' 3 1394 ",cl,'," EM-421 (W. A. W illiams, 427-1719) SUBJECT: Elimination of the Sites from the Formerly Utilized Sites Remedial Action Program To' The File In 1990, with the assistance of M r. Doug Tonkay and Ms. M ichelle Landis, I reviewed a number of sites that had formerly provided goods and/or services to the Fernald facility as subcontractors. For 24 of these sites,

  17. z

    Office of Legacy Management (LM)

    ,,:,z !8,!,. i ,OCT 2 8 1981 .., : $... . ,, .., ., ? conversation of October 14,.1981.~sb&ween Dr. My& A. Whitman regarding the collection of samples and infnm , to'verify the results of the decontamination effortc nf '1.. : asreported in their. final radioloalcal PIIIWW N ^- : .' ..' -:'.& dlSCUS& &ring the me&in; it DOE Headq&&~S on-Se$&&'i, lg& ;' . . ,'~ :~ ' with Dr. R. Wmveen. Mr. W. Smfth. and yourself, we concur wfth the'schedile of actfvftfes

  18. CENTRAL NEVADA-16 January

    Office of Legacy Management (LM)

    CENTRAL NEVADA-16 January 1970 UNITED STATES DEPARTMENT OF THE Dl"'TERIOR GEOLOGICAL SURVEY Federal Center. Denver. Colorado 80225 PRELIMINARY REPORT ON TliE GEOLOGIC EFFECTS OF THE FAULTLESS EVENT By ,'. USGS-474-65 F. A. McKeown. D. D. Dickey and W. L. Ellis ABSTRACT The Faultless event. an intermediate-yield nucl~ar explosion, produced fractures as much as thousands of feet in length, most of which are along preevent lineaments. Vertical displacements on the fractures are as much as

  19. Q&A About Electric Vehicle Flow Battery Technology | GE Global Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Q LA-UR- " " " 3 tos Alamos National Laboratoty is operated by the University of California for the United States Department of Energy under contract W-7405-ENG-36. TITLE: Klystron Beam-Bunching Lecture AUTHOR(S): B. E. Carlsten SUBMIITED TO: 1 996 US/CERN/JAPAN Accelerator School 1)lem*'$!@4 OF WiS DOCU!JENT tS UNti!dlED B otthis contribution, or to ailow others to do so, for U.S. Government purposes. acceptance of this article, the publisher recognizes that the U.S. Government

  20. R

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    R e p o r t CTSL28 \i "r $ CAI;IFORNIA INSTITUTE OF TE Synchrotron Laboratory Pasadena, California 3e GAUGE THEORIES OF VECTOR ' Sheldon L . Glashow- A p r i l 24, 1961 c - 4 *I r and the U r e d P. Slow Foundation. The research was begun while the authors vere National Science Foundation Fellows . DlSCLAfMER This report was prepared a s an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their

  1. RFP_WhitePaper_v4

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    White paper for 2014 FESAC Strategic Planning Aug. 2014 1 Opportunities and Context for Reversed Field Pinch Research J.S. Sarff 1 , A.F. Almagri, J.K. Anderson, D.L. Brower, B.E. Chapman, D. Craig, D.R. Demers, D.J. Den Hartog, W. Ding, C.B. Forest, J.A. Goetz, K.J. McCollam, M.D. Nornberg, C.R. Sovinec, P.W. Terry, and Collaborators Research on reversed-field pinch (RFP) plasmas contributes in unique ways to the advancement of both fusion and basic plasma science. The behavior of RFP plasmas

  2. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Validating Single Column Models with ARM Data Submitter: Somerville, R. C., Scripps Institution of Oceanography Area of Research: General Circulation and Single Column Models/Parameterizations Working Group(s): Cloud Modeling Journal Reference: Iacobellis, S.F., McFarquhar, G.M., Mitchell, D.L., and Somerville, R.C.J., 2003: "The Sensitivity of Radiative Fluxes to Parameterized Cloud Microphysics," J. Climate 16(18): 2979-2996. Scientists validated the results of both models by

  3. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Icy Business of Calculating Cirrus Clouds Submitter: Somerville, R. C., Scripps Institution of Oceanography Area of Research: General Circulation and Single Column Models/Parameterizations Working Group(s): Cloud Modeling Journal Reference: McFarquhar, G.M., S. Iacobellis, and R.C.J. Somerville, 2003: "SCM simulations of tropical ice clouds using observationally based parameterizations of microphysics," J. Climate 16(11):1643-1664. Iacobellis, S.F., G.M. McFarquhar, D.L. Mitchell, and

  4. Microsoft PowerPoint - 02XEPO-0_Lustre.pptx

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lustre File System Lustre File System Customer Documentation and Training Cray XT/XE Systems I/O Support - The compute nodes usually hand off I/O to the SIO or XIO (service I/O) nodes Th li ti l h h dl tdi - The aprun application launcher handles stdin, stdout, and stderr Refer to the Cray XT Programming Environment User's Guide y g g (S-2396), "I/O Support" in the "Catamount Programming Considerations" section 10/18/2010 2 Cray Private Cray I/O Architecture A li ti Login

  5. DOE/OR/07-2247&D1

    Energy Savers [EERE]

    f 8}.~11 Ohio Environmental Protection Agency Southeast District Office 2195 Front Street Logan, Ohio 43138 Dear Ms. Galanti: PPPO-03-1335655-12 REMOVAL ACTION COMPLETION REPORT FOR THE X-I03 AUXILIARY OFFICE BUILDING AT THE PORTSMOUTH GASEOUS DIFFUSION PLANT, PIKETON, OHIO Enclosed for your review and concurrence, please find the Removal Action Completion Report for the X-J 03 Auxiliary Office Building at the Portsmouth Gaseous Diffusion Plant, Piketon, Ohio (DOE/PPPOI03-0223&Dl). This

  6. Ed Jascevsky Safety Division ChIcago Operations Office MIT CONTFACT INFCE"ATION

    Office of Legacy Management (LM)

    ;/:4,4 (; . 1.; e octo: ' J : 18, 1976 Ed Jascevsky Safety Division ChIcago Operations Office MIT CONTFACT INFCE"ATION During the discussions on October 8, 1976, you iquired about information relative to work done by MIT as background infomation for survey planning. The enclosed information is parephrased frorc an unpublished history of program work carried out by the Process Eevclopncnt Group of the Dl.ti,si.on of Raw Katerids, I believe this work was done under contract nuder AT(30-1)956.

  7. A case report of lead paint poisoning during renovation of a Victorian farmhouse

    SciTech Connect (OSTI)

    Marino, P.E.; Landrigan, P.J.; Graef, J.; Nussbaum, A.; Bayan, G.; Boch, K.; Boch, S. )


    We describe a series of four cases of childhood lead poisoning and two cases of adult lead toxicity in a professional family exposed to lead dust and fume during renovation of a rural farmhouse. Initial blood lead levels in the children ranged from 2.70 to 4.20 microM/L (56 to 87 microns/dl) and all four required chelation therapy. Lead-based paint poisoning, a well recognized entity among young children in poor, urban neighborhoods, is not confined exclusively to such areas.


    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)


  9. W E E R

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    E / E R / 033 4 2 - 4 DE89 016660 Low TemDerature and Neutron Phvsics Studies Final Progress Report for Terminal Period March 1,1986 to May 31, 1987 of Contract DE-AC02-76ERO3342.AO17-MO20 Department of Physics Massachusetts Institute of Technology Cambridge, Massachusetts 02139 T C. G. Shull, Principal Investigator July 27, 1989 The U. S . Department of Energy Agreement No. DE-AC02-76ER03342 DlSTRlSUTlON O F THIS DOCUMENT I S UNLIMITE 3 DISCLAIMER This report was prepared as an account of work


    Office of Legacy Management (LM)

    9s' RESULTS OF RADIOLOGICAL I'IEASUREMENTS HIGHT{AYS 18 AI.ID IO4 IN NIAGARA az76 rl//.ry' ORNL/RASA.85/ 40 TAKEN AT JUNCTION FALLS, NEH YORK Accesr to the information in thit rcport ir limiled to tho!' inOllateO on tho dl3tribution li3t and to OePartment ot Encrgy and Oepartmcnt ol Enotgy Gontracton This report was prepared as an account of work sponsored by an agency of the United States Government. Neitherth€ U nited StatesGovernment norany agency thereof, nor any of their employees, makes

  11. Appendix B - Control Points

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    B B Control Points B.1 Injector Control Points Qty Type Device 2 Magnet Bend magnet - DL1 bend 9 Magnet Quad magnet 10 Magnet X-Y Corrector Pair 2 Magnet Solenoid 2 Magnet Spectrometer 1 RF Gun 2 RF Accelerating Structure 1 RF Transverse RF Structure 1 TIMING Timing/Trigger System 1 Laser Gun Laser 1 Laser Alignment Laser 13 DIAG BPM 4 DIAG Wire Scanner 11 DIAG Profile Monitor 3 DIAG Toroid 1 DIAG Transverse RF BL Monitor 3 DIAG Faraday Cup 1 DIAG Energy Collimator 1 DIAG Tune-up Dump 1 VAC

  12. Corrosion of Metal Inclusions In Bulk Vitrification Waste Packages

    SciTech Connect (OSTI)

    Bacon, Diana H.; Pierce, Eric M.; Wellman, Dawn M.; Strachan, Denis M.; Josephson, Gary B.


    The primary purpose of the work reported here is to analyze the potential effect of the release of technetium (Tc) from metal inclusions in bulk vitrification waste packages once they are placed in the Integrated Disposal Facility (IDF). As part of the strategy for immobilizing waste from the underground tanks at Hanford, selected wastes will be immobilized using bulk vitrification. During analyses of the glass produced in engineering-scale tests, metal inclusions were found in the glass product. This report contains the results from experiments designed to quantify the corrosion rates of metal inclusions found in the glass product from AMEC Test ES-32B and simulations designed to compare the rate of Tc release from the metal inclusions to the release of Tc from glass produced with the bulk vitrification process. In the simulations, the Tc in the metal inclusions was assumed to be released congruently during metal corrosion as soluble TcO4-. The experimental results and modeling calculations show that the metal corrosion rate will, under all conceivable conditions at the IDF, be dominated by the presence of the passivating layer and corrosion products on the metal particles. As a result, the release of Tc from the metal particles at the surfaces of fractures in the glass releases at a rate similar to the Tc present as a soluble salt. The release of the remaining Tc in the metal is controlled by the dissolution of the glass matrix. To summarize, the release of 99Tc from the BV glass within precipitated Fe is directly proportional to the diameter of the Fe particles and to the amount of precipitated Fe. However, the main contribution to the Tc release from the iron particles is over the same time period as the release of the soluble Tc salt. For the base case used in this study (0.48 mass% of 0.5 mm diameter metal particles homogeneously distributed in the BV glass), the release of 99Tc from the metal is approximately the same as the release from 0.3 mass% soluble Tc salt in the castable refractory block and it is released over the same time period as the salt. Therefore, to limit the impact of precipitated Fe on the release of 99Tc, both the amount of precipitated Fe in the BV glass and the diameter of these particles should be minimized.

  13. Making web annotations persistent over time

    SciTech Connect (OSTI)

    Sanderson, Robert; Van De Sompel, Herbert


    As Digital Libraries (DL) become more aligned with the web architecture, their functional components need to be fundamentally rethought in terms of URIs and HTTP. Annotation, a core scholarly activity enabled by many DL solutions, exhibits a clearly unacceptable characteristic when existing models are applied to the web: due to the representations of web resources changing over time, an annotation made about a web resource today may no longer be relevant to the representation that is served from that same resource tomorrow. We assume the existence of archived versions of resources, and combine the temporal features of the emerging Open Annotation data model with the capability offered by the Memento framework that allows seamless navigation from the URI of a resource to archived versions of that resource, and arrive at a solution that provides guarantees regarding the persistence of web annotations over time. More specifically, we provide theoretical solutions and proof-of-concept experimental evaluations for two problems: reconstructing an existing annotation so that the correct archived version is displayed for all resources involved in the annotation, and retrieving all annotations that involve a given archived version of a web resource.


    DOE Patents [OSTI]

    Luce, J.S.; Smith, L.P.


    A method and apparatus are given for producing coaxial arc discharges in an evacuated enclosure and within a strong, confining magnetic field. The arcs are maintained at a high potential difference. Electrons will diffuse to the more positive arc from the negative arc, and positive ions will diffuse from the more positive arc to the negative arc. Coaxial arc discharges have the advantage that ions which return to strike the positive arc discharge will lose no energy since they do not strike a solid wall or electrode. Those discharges are useful in confining an ionized plasma between the discharges, and have the advantage of preventing impurities from the walls of the enclosure from entering ihe plasma area because of the arc barrier set up bv the cylindrical outer arc.

  15. Ethylene glycol assisted spray pyrolysis for the synthesis of hollow BaFe12O19 spheres

    SciTech Connect (OSTI)

    Xu, X; Park, J; Hong, YK; Lane, AM


    Hollow spherical BaFe12O19 particles were synthesized by spray pyrolysis from a solution containing ethylene glycol (EG) and precursors at 1000 degrees C. The effects of EG concentration on particle morphology, crystallinity and magnetic properties were investigated. The hollow spherical particles were found to consist of primary particles, and higher EG concentration led to a bigger primary particle size. EG concentration did not show much effect on the hollow particle size. Better crystallinity and higher magnetic coercivity were obtained with higher EG concentration, which is attributed to further crystallization with the heat produced from EG combustion. Saturation magnetization (emu/g) decreased with increasing EG concentration due to residual carbon from EG incomplete combustion, contributing as a non-magnetic phase to the particles. Published by Elsevier B.V.

  16. Electrochemical state and internal variables estimation using a reduced-order physics-based model of a lithium-ion cell and an extended Kalman filter

    SciTech Connect (OSTI)

    Stetzel, KD; Aldrich, LL; Trimboli, MS; Plett, GL


    This paper addresses the problem of estimating the present value of electrochemical internal variables in a lithium-ion cell in real time, using readily available measurements of cell voltage, current, and temperature. The variables that can be estimated include any desired set of reaction flux and solid and electrolyte potentials and concentrations at any set of one-dimensional spatial locations, in addition to more standard quantities such as state of charge. The method uses an extended Kalman filter along with a one-dimensional physics-based reduced-order model of cell dynamics. Simulations show excellent and robust predictions having dependable error bounds for most internal variables. (C) 2014 Elsevier B.V. All rights reserved.

  17. Two-stage epitaxial growth of vertically-aligned SnO2 nano-rods on (001) ceria

    SciTech Connect (OSTI)

    Solovyov, VF; Wu, LJ; Rupich, MW; Sathyamurthy, S; Li, XP; Li, Q


    Growth of high-aspect ratio oriented tin oxide, SnO2, nano-rods is complicated by a limited choice of matching substrates. We show that a (001) cerium oxide, CeO2, surface uniquely enables epitaxial growth of tin-oxide nano-rods via a two-stage process. First, (100) oriented nano-wires coat the ceria surface by lateral growth, forming a uniaxially-textured SnO2 deposit. Second, vertical SnO2 nano-rods nucleate on the deposit by homoepitaxy. We demonstrate growth of vertically oriented 1-2 mu m long nano-rods with an average diameter of approximate to 20 nm. 2014 Elsevier B.V. All rights reserved.

  18. Lithium-ion battery cell-level control using constrained model predictive control and equivalent circuit models

    SciTech Connect (OSTI)

    Xavier, MA; Trimboli, MS


    This paper introduces a novel application of model predictive control (MPC) to cell-level charging of a lithium-ion battery utilizing an equivalent circuit model of battery dynamics. The approach employs a modified form of the MPC algorithm that caters for direct feed-though signals in order to model near-instantaneous battery ohmic resistance. The implementation utilizes a 2nd-order equivalent circuit discrete-time state-space model based on actual cell parameters; the control methodology is used to compute a fast charging profile that respects input, output, and state constraints. Results show that MPC is well-suited to the dynamics of the battery control problem and further suggest significant performance improvements might be achieved by extending the result to electrochemical models. (C) 2015 Elsevier B.V. All rights reserved.

  19. Preparation and reactivity of macrocyclic rhodium(III) alkyl complexes

    SciTech Connect (OSTI)

    Carraher, Jack M.; Ellern, Arkady; Bakac, Andreja


    Macrocyclic rhodium(II) complexes LRh(H2O)(2+) (L = L-1 = cyclam and L-2 = meso-Me-6-cyclam) react with alkyl hydroperoxides RC(CH3)(2)OOH to generate the corresponding rhodium(III) alkyls L(H2O)RhR2+ (R = CH3, C2H5, PhCH2). Methyl and benzyl complexes can also be prepared by bimolecular group transfer from alkyl cobaloximes (dmgH)(2)(H2O) CoR and (dmgBF(2))(2)(H2O) CoR (R = CH3, PhCH2) to LRh(H2O)(2+). The new complexes were characterized by solution NMR and by crystal structure analysis. They exhibit great stability in aqueous solution at room temperature, but undergo efficient Rh-C bond cleavage upon photolysis. (C) 2013 Elsevier B.V. All rights reserved.

  20. Influence of Li ions on the oxygen reduction reaction of platinum electrocatalyst

    SciTech Connect (OSTI)

    Liu, H; Xing, YC


    A Li-air battery can provide a much higher theoretical energy density than a Li-ion battery. The use of aqueous acidic electrolytes may prevent lithium oxide deposition from aprotic electrolytes and lithium carbonate precipitation from alkaline electrolytes. The present communication reports a study on the effect of Li ions on the oxygen reduction reaction (ORR) in sulfuric acid electrolytes. It was found that the Li ions have negligible interactions with the active surface of Pt catalysts. However, significantly lower ORR activities were found when Li ions are present in the sulfuric acid. The intrinsic kinetic activities were found to decrease with the increase of Li ion concentrations, but level off when the Li ion concentrations are larger than 1.0 M. The low activities of Pt catalysts in Li ion containing electrolytes were attributed to a constraining effect of Li ions on the diffusion of oxygen in the electrolyte solution. (C) 2011 Elsevier B.V. All rights reserved.

  1. Bulk Vitrification Castable Refractory Block Protection Study

    SciTech Connect (OSTI)

    Hrma, Pavel R.; Bagaasen, Larry M.; Beck, Andrew E.; Brouns, Thomas M.; Caldwell, Dustin D.; Elliott, Michael L.; Matyas, Josef; Minister, Kevin BC; Schweiger, Michael J.; Strachan, Denis M.; Tinsley, Bronnie P.; Hollenberg, Glenn W.


    Bulk vitrification (BV) was selected for a pilot-scale test and demonstration facility for supplemental treatment to accelerate the cleanup of low-activity waste (LAW) at the Hanford U.S. DOE Site. During engineering-scale (ES) tests, a small fraction of radioactive Tc (and Re, its nonradioactive surrogate) were transferred out of the LAW glass feed and molten LAW glass, and deposited on the surface and within the pores of the castable refractory block (CRB). Laboratory experiments were undertaken to understand the mechanisms of the transport Tc/Re into the CRB during vitrification and to evaluate various means of CRB protection against the deposition of leachable Tc/Re. The tests used Re as a chemical surrogate for Tc. The tests with the baseline CRB showed that the molten LAW penetrates into CRB pores before it converts to glass, leaving deposits of sulfates and chlorides when the nitrate components decompose. Na2O from the LAW reacts with the CRB to create a durable glass phase that may contain Tc/Re. Limited data from a single CRB sample taken from an ES experiment indicate that, while a fraction of Tc/Re is present in the CRB in a readily leachable form, most of the Tc/Re deposited in the refractory is retained in the form of a durable glass phase. In addition, the molten salts from the LAW, mainly sulfates, chlorides, and nitrates, begin to evaporate from BV feeds at temperatures below 800 C and condense on solid surfaces at temperatures below 530 C. Three approaches aimed at reducing or preventing the deposition of soluble Tc/Re within the CRB were proposed: metal lining, sealing the CRB surface with a glaze, and lining the CRB with ceramic tiles. Metal liners were deemed unsuitable because evaluations showed that they can cause unacceptable distortions of the electric field in the BV system. Sodium silicate and a low-alkali borosilicate glaze were selected for testing. The glazes slowed down molten salt condensate penetration, but did little to reduce the penetration of molten salt. Out of several refractory tile candidates, only greystone and fused-cast alumina-zirconia-silica (AZS) refractory remained intact and well bonded to the CRB after firing to 1000 C. The deformation of the refractory-tile composite was avoided by prefiring the greystone tile to 800 C. Condensed vapors did not penetrate the tiles, but Re salts condensed on their surface. Refractory corrosion tests indicated that a 0.25-inch-thick greystone tile would not corrode during a BV melt. Tiles can reduce both vapor penetration and molten salt penetration, but vapor deposition above the melt line will occur even on tiles. The Tc/Re transport scenario was outlined as follows. At temperatures below 700 C, molten ionic salt (MIS) that includes all the Tc/Re penetrates, by capillarity, from the feed into the CRB open porosity. At approximately 750 C, the MIS decomposes through the loss of NOx, leaving mainly sulfate and chloride salts. The Na2O formed in the decomposition of the nitrates reacts with insoluble grains in the feed and with the aluminosilicates in the CRB to form more viscous liquids that reduce further liquid penetration into the CRB. At 800 to 1000 C, a continuous glass phase traps the remains of the MIS in the form of inclusions in the bulk glass melt. At 1000 to 1200 C, the salt inclusions in the glass slowly dissolve but also rise to the surface. The Tc/Re salts also evaporate from the free surface of the glass melt that is rapidly renewed by convective currents. The vapors condense on cooler surfaces in the upper portion of the CRB, the box lid, and the off-gas system.

  2. Eu3+ as a dual probe for the determination of IL anion donor power: A combined luminescence spectroscopic and electrochemical approach

    SciTech Connect (OSTI)

    Babai, Arash; Kopiec, Gabriel; Lackmann, Anastasia; Mallick, Bert; Pitula, Slawomir; Tang, Sifu; Mudring, Anja-Verena


    This work is aimed at giving proof that Eu(Tf2N)(3) (Tf2N = bis(trifluoromethanesulfonyl)amide) can act as both an optical and electrochemical probe for the determination of the Lewis acidity of an ionic liquid anion. For that reason the luminescence spectra and cyclic voltammograms of dilute solutions of Eu(Tf2N)(3) in various ionic liquids were investigated. The Eu2+/3+ redox potential in the investigated ILs can be related to the Lewis basicity of the IL anion. The IL cation had little influence. The lower the determined halfwave potential, the higher the IL anion basicity. The obtained ranking can be confirmed by luminescence spectroscopy where a bathochromic shift of the D-5(0) -> F-7(4) transition indicates a stronger Lewis basicity of the IL anion. (C) 2014 Published by Elsevier B.V.

  3. A high-fidelity multiphysics model for the new solid oxide iron-air redox battery part I: Bridging mass transport and charge transfer with redox cycle kinetics

    SciTech Connect (OSTI)

    Jin, XF; Zhao, X; Huang, K


    A high-fidelity two-dimensional axial symmetrical multi-physics model is described in this paper as an effort to simulate the cycle performance of a recently discovered solid oxide metal-air redox battery (SOMARB). The model collectively considers mass transport, charge transfer and chemical redox cycle kinetics occurring across the components of the battery, and is validated by experimental data obtained from independent research. In particular, the redox kinetics at the energy storage unit is well represented by Johnson-Mehl-Avrami-Kolmogorov (JIVIAK) and Shrinking Core models. The results explicitly show that the reduction of Fe3O4 during the charging cycle limits the overall performance. Distributions of electrode potential, overpotential, Nernst potential, and H-2/H2O-concentration across various components of the battery are also systematically investigated. (C) 2015 Elsevier B.V. All rights reserved.

  4. Manipulating Josephson junctions in thin-films by nearby vortices

    SciTech Connect (OSTI)

    Kogan, V G; Mints, R G


    It is shown that a vortex trapped in one of the banks of a planar edge-type Josephson junction in a narrow thin-film superconducting strip can change drastically the dependence of the junction critical current on the applied field, I-c(H). When the vortex is placed at certain discrete positions in the strip middle, the pattern I-c(H) has zero at H = 0 instead of the traditional maximum of '0-type' junctions. The number of these positions is equal to the number of vortices trapped at the same location. When the junction-vortex separation exceeds similar to W, the strip width, I-c(H) is no longer sensitive to the vortex presence. The same is true for any separation if the vortex approaches the strip edges. (C) 2014 Elsevier B.V. All rights reserved.

  5. Coordinated role of voltage-gated sodium channels and the Na{sup +}/H{sup +} exchanger in sustaining microglial activation during inflammation

    SciTech Connect (OSTI)

    Hossain, Muhammad M.; Sonsalla, Patricia K.; Richardson, Jason R.


    Persistent neuroinflammation and microglial activation play an integral role in the pathogenesis of many neurological disorders. We investigated the role of voltage-gated sodium channels (VGSC) and Na{sup +}/H{sup +} exchangers (NHE) in the activation of immortalized microglial cells (BV-2) after lipopolysaccharide (LPS) exposure. LPS (10 and 100 ng/ml) caused a dose- and time-dependent accumulation of intracellular sodium [(Na{sup +}){sub i}] in BV-2 cells. Pre-treatment of cells with the VGSC antagonist tetrodotoxin (TTX, 1 ?M) abolished short-term Na{sup +} influx, but was unable to prevent the accumulation of (Na{sup +}){sub i} observed at 6 and 24 h after LPS exposure. The NHE inhibitor cariporide (1 ?M) significantly reduced accumulation of (Na{sup +}){sub i} 6 and 24 h after LPS exposure. Furthermore, LPS increased the mRNA expression and protein level of NHE-1 in a dose- and time-dependent manner, which was significantly reduced after co-treatment with TTX and/or cariporide. LPS increased production of TNF-?, ROS, and H{sub 2}O{sub 2} and expression of gp91{sup phox}, an active subunit of NADPH oxidase, in a dose- and time-dependent manner, which was significantly reduced by TTX or TTX + cariporide. Collectively, these data demonstrate a closely-linked temporal relationship between VGSC and NHE-1 in regulating function in activated microglia, which may provide avenues for therapeutic interventions aimed at reducing neuroinflammation. - Highlights: LPS causes immediate increase in sodium through VGSC and subsequently through the NHE-1. Inhibition of VGSC reduces increases in NHE-1 and gp91{sup phox}. Inhibition of VGSC and NHE-1 reduces NADPH oxidase-mediated Tnf-?, ROS, and H{sub 2}O{sub 2} production. NHE-1 and Na{sub v}1.6 may be viable targets for therapeutic interventions to reduce neuroinflammation in neurodegenerative disease.

  6. Small-Column Cesium Ion Exchange Elution Testing of Spherical Resorcinol-Formaldehyde

    SciTech Connect (OSTI)

    Brown, Garrett N.; Russell, Renee L.; Peterson, Reid A.


    This report summarizes the work performed to evaluate multiple, cesium loading, and elution cycles for small columns containing SRF resin using a simple, high-level waste (HLW) simulant. Cesium ion exchange loading and elution curves were generated for a nominal 5 M Na, 2.4E-05 M Cs, 0.115 M Al loading solution traced with 134Cs followed by elution with variable HNO3 (0.02, 0.07, 0.15, 0.23, and 0.28 M) containing variable CsNO3 (5.0E-09, 5.0E-08, and 5.0E-07 M) and traced with 137Cs. The ion exchange system consisted of a pump, tubing, process solutions, and a single, small ({approx}15.7 mL) bed of SRF resin with a water-jacketed column for temperature-control. The columns were loaded with approximately 250 bed volumes (BVs) of feed solution at 45 C and at 1.5 to 12 BV per hour (0.15 to 1.2 cm/min). The columns were then eluted with 29+ BVs of HNO3 processed at 25 C and at 1.4 BV/h. The two independent tracers allowed analysis of the on-column cesium interaction between the loading and elution solutions. The objective of these tests was to improve the correlation between the spent resin cesium content and cesium leached out of the resin in subsequent loading cycles (cesium leakage) to help establish acid strength and purity requirements.

  7. Relationship of computed tomography perfusion and positron emission tomography to tumour progression in malignant glioma

    SciTech Connect (OSTI)

    Yeung, Timothy P C; Yartsev, Slav; Lee, Ting-Yim; Wong, Eugene; He, Wenqing; Fisher, Barbara; VanderSpek, Lauren L; Macdonald, David; Bauman, Glenn


    Introduction: This study aimed to explore the potential for computed tomography (CT) perfusion and 18-Fluorodeoxyglucose positron emission tomography (FDG-PET) in predicting sites of future progressive tumour on a voxel-by-voxel basis after radiotherapy and chemotherapy. Methods: Ten patients underwent pre-radiotherapy magnetic resonance (MR), FDG-PET and CT perfusion near the end of radiotherapy and repeated post-radiotherapy follow-up MR scans. The relationships between these images and tumour progression were assessed using logistic regression. Cross-validation with receiver operating characteristic (ROC) analysis was used to assess the value of these images in predicting sites of tumour progression. Results: Pre-radiotherapy MR-defined gross tumour; near-end-of-radiotherapy CT-defined enhancing lesion; CT perfusion blood flow (BF), blood volume (BV) and permeability-surface area (PS) product; FDG-PET standard uptake value (SUV); and SUV:BF showed significant associations with tumour progression on follow-up MR imaging (P < 0.0001). The mean sensitivity (standard deviation), specificity and area under the ROC curve (AUC) of PS were 0.64 0.15, 0.74 0.07 and 0.72 0.12 respectively. This mean AUC was higher than that of the pre-radiotherapy MR-defined gross tumour and near-end-of-radiotherapy CT-defined enhancing lesion (both AUCs = 0.6 0.1, P ? 0.03). The multivariate model using BF, BV, PS and SUV had a mean AUC of 0.8 0.1, but this was not significantly higher than the PS only model. Conclusion: PS is the single best predictor of tumour progression when compared to other parameters, but voxel-based prediction based on logistic regression had modest sensitivity and specificity.

  8. High-power radio frequency pulse generation and extration based on wakefield excited by an intense charged particle beam in dielectric-loaded waveguides.

    SciTech Connect (OSTI)

    Gao, F.; High Energy Physics; Illinois Inst. of Tech


    Power extraction using a dielectric-loaded (DL) waveguide is a way to generate high-power radio frequency (RF) waves for future particle accelerators, especially for two-beam-acceleration. In a two-beam-acceleration scheme, a low-energy, high-current particle beam is passed through a deceleration section of waveguide (decelerator), where the power from the beam is partially transferred to trailing electromagnetic waves (wakefields); then with a properly designed RF output coupler, the power generated in the decelerator is extracted to an output waveguide, where finally the power can be transmitted and used to accelerate another usually high-energy low-current beam. The decelerator, together with the RF output coupler, is called a power extractor. At Argonne Wakefield Accelerator (AWA), we designed a 7.8GHz power extractor with a circular DL waveguide and tested it with single electron bunches and bunch trains. The output RF frequency (7.8GHz) is the sixth harmonic of the operational frequency (1.3GHz) of the electron gun and the linac at AWA. In single bunch excitation, a 1.7ns RF pulse with 30MW of power was generated by a single 66nC electron bunch passing through the decelerator. In subsequent experiments, by employing different splitting-recombining optics for the photoinjector laser, electron bunch trains were generated and thus longer RF pulses could be successfully generated and extracted. In 16-bunch experiments, 10ns and 22ns RF pulses have been generated and extracted; and in 4-bunch experiments, the maximum power generated was 44MW with 40MW extracted. A 26GHz DL power extractor has also been designed to test this technique in the millimeter-wave range. A power level of 148MW is expected to be generated by a bunch train with a bunch spacing of 769ps and bunch charges of 20nC each. The arrangement for the experiment is illustrated in a diagram. Higher-order-mode (HOM) power extraction has also been explored in a dual-frequency design. By using a bunch train with a bunch spacing of 769ps and bunch charges of 50nC each, 90.4MW and 8.68MW of extracted power levels are expected to be reached at 20.8GHz and 35.1GHz, respectively. In order to improve efficiency in HOM power extraction, a novel technique has been proposed to suppress unintended modes.

  9. Pacific Northwest Laboratory annual report for 1981 to the DOE Office of the Assistant Secretary for Environmental Protection, Safety and Emergency Preparedness. Part 5. Environmental and occupational protection, assessment, and engineering

    SciTech Connect (OSTI)

    Glass, W.A.


    This report describes research in environment, health, and safety conducted during fiscal year 1981. The five parts of the report are oriented to particular segments of the program. Parts 1 to 4 report on research performed for the DOE Office of Health and Environmental Research in the Office of Energy Research. Part 5 reports progress on all research performed for the Office of the Assistant Secretary for Environmental Protection, Safety and Emergency Preparedness. The parts are: Part 1: Biomedical Sciences under Program Manager, H. Drucker; Part 2: Ecological Sciences, under Program Manager, B.E. Vaughan; Part 3: Atmospheric Sciences under Program Manager, C.E. Elderkin; Part 4: Physical Sciences under Program Manager, J.M. Nielsen; and Part 5: Environmental and Occupational Protection, Assessment, and Engineering under Program Managers, D.L. Hessel, S. Marks, and W.A. Glass.

  10. IAEA-CN-94/EX/C4-6

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    IAEA-CN-94/EX/C4-6 1 Core Fluctuations and Current Profile Dynamics in the MST Reversed-Field Pinch D.L. Brower 1), W.X. Ding 1), J. Lei 2), J.K. Anderson 3), T.M. Biewer 3), B.E. Chapman 3), K.A. Connor 2), D. Craig 3), D.R. Demers 2), C.B. Forest 3), D. Holly 3), R. O'Connell 3), S.C. Prager 3), J.S. Sarff 3), P.M. Schoch 2), S.D. Terry 1), J.C. Wright 3) 1) Electrical Engineering Department, University of California at Los Angeles, Los Angeles, California USA 2) Electrical, Computer and

  11. IAEA-F1-CN69.pdf

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CONFINEMENT IN THE RFP: LUNDQUIST NUMBER SCALING, PLASMA FLOW, AND REDUCED TRANSPORT G. Fiksel, 1 A.F. Almagri, 1 J.K. Anderson, 1 T.M. Biewer, 1 D.L. Brower, 2 C-S. Chiang, 1 B.E. Chapman, 1 J.T. Chapman, 1 D.J. Craig, 1 N.A. Crocker, 1 D.J. Den Hartog, 1 P.W. Fontana, 1 C.B. Forest, 1 Y. Jiang, 2 A.K. Hansen, 1 D. Holly, 1 N.E. Lanier, 1 K.A. Mirus, 1 S.C. Prager, 1 J.S. Sarff, 1 U. Shah, 3 J.C. Sprott, 1 M.R. Stoneking, 4 and E. Uchimoto 5 1 Department of Physics, University of

  12. Oxygen A-band Exploitation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Data Exploitation Anthony B. Davis Los Alamos Nat'l Lab ... with input from Qilong Min, SUNY-Albany/ASRC Klaus Pfeilsticker, Heidelberg University RPWG Breakout Session ARM 2008 STM Monday, 3/10/08 I ν ≡ I(k ν ) = I(0) exp[-k ν L] = I(0) p(L) 0 ∞ ∫ exp[-k ν L]dL ⇒ L q = L q p(L) 0 ∞ ∫ dL = 1 I(0) × - d dk ν ⎛ ⎝ ⎜ ⎞ ⎠ ⎟ q I k ν = 0 I ν I L = 0 = exp[- σ ν × n × L] Application : known / not : ? √ √ estimating molecular cross-sections, normally in a

  13. craig_IAEA.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    EX/P5-3 New Observations Concerning the Origin and Consequences of MHD Activity in the MST Reversed Field Pinch D. Craig 1), A.F. Almagri 1), J.K. Anderson 1), D.L. Brower 2), B.E. Chapman 1), S.H. Choi 1), D.J. Den Hartog 1), W.X. Ding 2), F. Ebrahimi 1), G. Fiksel 1), R. Fitzpatrick 3), C.B. Forest 1), P. Martin 4), L. Marrelli 4), R. O'Connell 1), P. Piovesan 4), S.C. Prager 1), J.S. Sarff 1), G. Spizzo 4) 1) University of Wisconsin, Madison, WI USA and the Center for Magnetic Self-

  14. EX/P4-01

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    EX/P4-01 1 Ion Heating and Current and Momentum Profile Relaxation During Sawtooth Crashes in the MST Reversed Field Pinch G. Fiksel 1), A.F. Almagri 1), J.K. Anderson 1), T.M. Biewer 1), A.P. Blair 1), D.L. Brower 2), B.E. Chapman 1), D. Craig 1), D.J. Den Hartog 1), W.X. Ding 2), C.B. Forest 1), C.C. Hegna 1), R. Gatto 1), J. Goetz 1), K.J. McCollam 1), V.V. Mirnov 1), R. O'Connell 1), S.C. Prager 1), J.C. Reardon 1), J.S. Sarff 1), P.W. Terry 1), S.D. Terry 2), and MST team. 1) University of

  15. EX/P5-4 Two-Fluid Hall Effect on Plasma Relaxation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    EX/P5-4 Two-Fluid Hall Effect on Plasma Relaxation in a High-Temperature Plasma W.X. Ding 1,3), V. Mirnov 2,3), A. F. Almagri 2,3), D.L. Brower 1,3), D. Craig 2,3), B.H. Deng 1,3), D. J. Den Hartog 2,3) , G. Fiksel 2,3), C.C. Hegna 2,3), S.C. Prager 2,3), J.S. Sarff 2,3) 1) University of California, Los Angeles, California 90095 USA 2) University of Wisconsin-Madison, Madison, Wisconsin 53706 USA 3) The Center for Magnetic Self-Organization in Laboratory and Astrophysical Plasmas e-mail contact

  16. Poly(lactide)-block-poly([epsilon]-caprolactone-co-[epsilon]-decalactone)-block-poly(lactide) copolymer elastomers

    SciTech Connect (OSTI)

    Schneiderman, Deborah K.; Hill, Erin M.; Martello, Mark T.; Hillmyer, Marc A.


    Batch ring opening transesterification copolymerization of ?-caprolactone and ?-decalactone was used to generate statistical copolymers over a wide range of compositions and molar masses. Reactivity ratios determined for this monomer pair, rCL = 5.9 and rDL = 0.03, reveal ?-caprolactone is added preferentially regardless of the propagating chain end. Relative to poly(?-caprolactone) the crystallinity and melting point of these statistical copolymers were depressed by the addition of ?-decalactone; copolymers containing greater than 31 mol% (46 wt%) ?-decalactone were amorphous. Poly(lactide)-block-poly(?-caprolactone-co-?-decalactone)-block-poly(lactide) triblock polymers were also prepared and used to explore the influence of midblock composition on the temperature dependent Flory-Huggins interaction parameter (?). In addition, uniaxial extension tests were used to determine the effects of midblock composition, poly(lactide) content, and molar mass on the mechanical properties of these new elastomeric triblocks.

  17. Microsoft Word - SarffOV4-3Paper.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    IAEA-CN-94/OV/4-3 1 Overview of Improved Confinement and Plasma Control in the MST Reversed Field Pinch J.S. Sarff 1), A.F. Almagri 1), J.K. Anderson 1), T.M. Biewer 1), A.P. Blair 1), D.L. Brower 2), M.D. Carter 3), M. Cengher 1), B.E. Chapman 1), P.K. Chattopadhyay 1), V.I. Davydenko 6), D.J. Den Hartog 1), W.X. Ding 2), F. Ebrahimi 1), G. Fiksel 1), C.B. Forest 1), J.A. Goetz 1), R.W. Harvey 4), D. Holly 1), B. Hudson 1), A.A. Ivanov 6), T.W. Lovell 1), K.J. McCollam 1), P.D. Nonn 1), R.

  18. The Fermilab CMTF cryogenic distribution remote control system

    SciTech Connect (OSTI)

    Pei, L.; Theilacker, J.; Klebaner, A.; Martinez, A.; Bossert, R.


    The Cryomodule Test Facility (CMTF) is able to provide the necessary test bed for measuring the performance of Superconducting Radio Frequency (SRF) cavities in a cryomodule (CM). The CMTF have seven 300 KW screw compressors, two liquid helium refrigerators, and two Cryomodule Test Stands (CMTS). CMTS1 is designed for 1.3 GHz cryomodule operating in a pulsed mode (PM) and CMTS2 is for cryomodule operating in Half-Wave (HW) and Continuous Wave (CW) mode. Based on the design requirement, each subsystem has to be far away from each other and be placed in distant locations. Therefore choosing Siemens Process Control System 7-400, DL205 PLC, Synoptic and Fermilab ACNET are the ideal choices for CMTF cryogenic distribution real-time remote control system. This paper presents a method which has been successfully used by many Fermilab distribution cryogenic real-time remote control systems.

  19. Impedimetric investigation of gold nanoparticles - guanine modified electrode

    SciTech Connect (OSTI)

    Vulcu, A.; Pruneanu, S.; Berghian-Grosan, C.; Olenic, L.; Muresan, L. M.; Barbu-Tudoran, L.


    In this paper we report the preparation of a modified electrode with gold nanoparticles and guanine. The colloidal suspension of gold nanoparticles was obtained by Turkevich method and was next analyzed by UV-Vis spectroscopy and Transmission Electron Microscopy (TEM). The gold electrode was modified by self-assembling the gold nanoparticles with guanine, the organic molecule playing also the role of linker. The electrochemical characteristics of the bare and modified electrode were investigated by Electrochemical Impedance Spectroscopy (EIS). A theoretical model was developed based on an electrical equivalent circuit which contain solution resistance (R{sub s}), charge transfer resistance (R{sub ct}), Warburg impedance (Z{sub W}) and double layer capacitance (C{sub dl})

  20. Stratified-charge glow plug ignition engine experiments. Topical report

    SciTech Connect (OSTI)

    Thring, R.H.; Leet, J.A.


    An investigation was conducted to study the feasibility of operating a natural gas two-stroke engine using glow plug ignition with very lean mixtures. The term Stratified-Charge Glow Plus Ignition (SCGI) was coined to describe the engine. A JLO DL 365 single-cylinder, two-stroke, diesel engine was converted first to a natural gas fueled spark-ignited engine for the baseline tests, and then to the SCGI engine. The engine was successfully run, but was found to be sensitive to various conditions such as the glow plug temperature. The engine ran very lean, to an equivalence ratio of 0.33, offering the potential of good fuel economy and low NOx emissions. Numerous photographs, diagrams, and charts are included.

  1. Vacuum pyrolysis of waste tires with basic additives

    SciTech Connect (OSTI)

    Zhang Xinghua; Wang Tiejun Ma Longlong; Chang Jie


    Granules of waste tires were pyrolyzed under vacuum (3.5-10 kPa) conditions, and the effects of temperature and basic additives (Na{sub 2}CO{sub 3}, NaOH) on the properties of pyrolysis were thoroughly investigated. It was obvious that with or without basic additives, pyrolysis oil yield increased gradually to a maximum and subsequently decreased with a temperature increase from 450 deg. C to 600 deg. C, irrespective of the addition of basic additives to the reactor. The addition of NaOH facilitated pyrolysis dramatically, as a maximal pyrolysis oil yield of about 48 wt% was achieved at 550 deg. C without the addition of basic additives, while a maximal pyrolysis oil yield of about 50 wt% was achieved at 480 deg. C by adding 3 wt% (w/w, powder/waste tire granules) of NaOH powder. The composition analysis of pyrolytic naphtha (i.b.p. (initial boiling point) {approx}205 deg. C) distilled from pyrolysis oil showed that more dl-limonene was obtained with basic additives and the maximal content of dl-limonene in pyrolysis oil was 12.39 wt%, which is a valuable and widely-used fine chemical. However, no improvement in pyrolysis was observed with Na{sub 2}CO{sub 3} addition. Pyrolysis gas was mainly composed of H{sub 2}, CO, CH{sub 4}, CO{sub 2}, C{sub 2}H{sub 4} and C{sub 2}H{sub 6}. Pyrolytic char had a surface area comparable to commercial carbon black, but its proportion of ash (above 11.5 wt%) was much higher.

  2. Does aspartic acid racemization constrain the depth limit of the subsurface biosphere?

    SciTech Connect (OSTI)

    Onstott, T. C.; Aubrey, A.D.; Kieft, T L; Silver, B J; Phelps, Tommy Joe; Van Heerden, E.; Opperman, D. J.; Bada, J L.


    Previous studies of the subsurface biosphere have deduced average cellular doubling times of hundreds to thousands of years based upon geochemical models. We have directly constrained the in situ average cellular protein turnover or doubling times for metabolically active micro-organisms based on cellular amino acid abundances, D/L values of cellular aspartic acid, and the in vivo aspartic acid racemization rate. Application of this method to planktonic microbial communities collected from deep fractures in South Africa yielded maximum cellular amino acid turnover times of ~89 years for 1 km depth and 27 C and 1 2 years for 3 km depth and 54 C. The latter turnover times are much shorter than previously estimated cellular turnover times based upon geochemical arguments. The aspartic acid racemization rate at higher temperatures yields cellular protein doubling times that are consistent with the survival times of hyperthermophilic strains and predicts that at temperatures of 85 C, cells must replace proteins every couple of days to maintain enzymatic activity. Such a high maintenance requirement may be the principal limit on the abundance of living micro-organisms in the deep, hot subsurface biosphere, as well as a potential limit on their activity. The measurement of the D/L of aspartic acid in biological samples is a potentially powerful tool for deep, fractured continental and oceanic crustal settings where geochemical models of carbon turnover times are poorly constrained. Experimental observations on the racemization rates of aspartic acid in living thermophiles and hyperthermophiles could test this hypothesis. The development of corrections for cell wall peptides and spores will be required, however, to improve the accuracy of these estimates for environmental samples.

  3. Sex-based differences in gene expression in hippocampus following postnatal lead exposure

    SciTech Connect (OSTI)

    Schneider, J.S. Anderson, D.W.; Sonnenahalli, H.; Vadigepalli, R.


    The influence of sex as an effect modifier of childhood lead poisoning has received little systematic attention. Considering the paucity of information available concerning the interactive effects of lead and sex on the brain, the current study examined the interactive effects of lead and sex on gene expression patterns in the hippocampus, a structure involved in learning and memory. Male or female rats were fed either 1500 ppm lead-containing chow or control chow for 30 days beginning at weaning.Blood lead levels were 26.7 {+-} 2.1 {mu}g/dl and 27.1 {+-} 1.7 {mu}g/dl for females and males, respectively. The expression of 175 unique genes was differentially regulated between control male and female rats. A total of 167 unique genes were differentially expressed in response to lead in either males or females. Lead exposure had a significant effect without a significant difference between male and female responses in 77 of these genes. In another set of 71 genes, there were significant differences in male vs. female response. A third set of 30 genes was differentially expressed in opposite directions in males vs. females, with the majority of genes expressed at a lower level in females than in males. Highly differentially expressed genes in males and females following lead exposure were associated with diverse biological pathways and functions. These results show that a brief exposure to lead produced significant changes in expression of a variety of genes in the hippocampus and that the response of the brain to a given lead exposure may vary depending on sex. - Highlights: > Postnatal lead exposure has a significant effect on hippocampal gene expression patterns. > At least one set of genes was affected in opposite directions in males and females. > Differentially expressed genes were associated with diverse biological pathways.

  4. Flow and axial dispersion in a sinusoidal-walled tube: Effects of inertial and unsteady flows

    SciTech Connect (OSTI)

    Richmond, Marshall C.; Perkins, William A.; Scheibe, Timothy D.; Lambert, Adam; Wood, Brian D.


    Dispersion in porous media flows has been the subject of much experimental, theoretical and numerical study. Here we consider a wavy-walled tube (a three-dimensional tube with sinusoidally-varying diameter) as a simplified conceptualization of flow in porous media, where constrictions represent pore throats and expansions pore bodies. A theoretical model for effective (macroscopic) longitudinal dispersion in this system has been developed by volume averaging the microscale velocity field. Direct numerical simulation using computational fluid dynamics (CFD) methods was used to compute velocity fields by solving the Navier-Stokes equations, and also to numerically solve the volume averaging closure problem, for a range of Reynolds numbers (Re) spanning the low-Re to inertial flow regimes, including one simulation at Re = 449 for which unsteady flow was observed. Dispersion values were computed using both the volume averaging solution and a random walk particle tracking method, and results of the two methods were shown to be consistent. Our results are compared to experimental measurements of dispersion in porous media and to previous theoretical results for the low-Re, Stokes flow regime. In the steady inertial regime we observe an power-law increase in effective longitudinal dispersion (DL) with Re, consistent with previous results. This rapid rate of increase is caused by trapping of solute in expansions due to flow separation (eddies). For the unsteady case (Re = 449), the rate of increase of DL with Re was smaller than that observed at lower Re. Velocity fluctuations in this regime lead to increased rates of solute mass transfer between the core flow and separated flow regions, thus diminishing the amount of tailing caused by solute trapping in eddies and thereby reducing longitudinal dispersion.

  5. Method to Reduce Molten Salt Penetration into Bulk Vitrification Refractory Materials

    SciTech Connect (OSTI)

    Bagaasen, L.M.; Hrma, P.R.; Kim, D.S.; Schweiger, M.J.; Matyas, J.; Rodriguez, C.P. [Pacific Northwest National Laboratory, Richland WA (United States); Witwer, K.S. [AMEC Nuclear Holdings Ltd., GeoMelt Division, Richland, WA (United States)


    Bulk vitrification (BV) is a process that heats a feed material consisting of glass-forming solids and dried low-activity waste (LAW) in a disposable refractory-lined metal box using electrical power supplied through carbon electrodes. The feed is heated to the point that the LAW decomposes and combines with the solids to generate a vitreous waste form. However, the castable refractory block (CRB) portion of the refractory lining has sufficient porosity to allow the low-viscosity molten ionic salt (MIS), which contains technetium (Tc) in a soluble form, to penetrate the CRB. This limits the effectiveness of the final waste form. This paper describes tests conducted to develop a method aimed at reducing the quantities of soluble Tc in the CRB. Tests showed that MIS formed in significant quantities at temperatures above 300 deg. C, remained stable until roughly 550 deg. C where it began to thermally decompose, and was completely decomposed by 800 deg. C. The estimated volume fraction of MIS in the feed was greater than 40%, and the CRB material contained 11 to 15% open porosity, a combination allowing a large quantity of MIS to migrate through the feed and penetrate the open porosity of the CRB. If the MIS is decomposed at temperatures below 300 deg. C or can be contained in the feed until it fully decomposes by 800 deg. C, MIS migration into the CRB can be avoided. Laboratory and crucible-scale experiments showed that a variety of methods, individually or in combination, can decrease MIS penetration into the CRB. Modifying the CRB to block MIS penetration was not deemed practical as a method to prevent the large quantities of MIS penetration seen in the full-scale tests, but it may be useful to reduce the impacts of lower levels of MIS penetration. Modifying the BV feed materials to better contain the MIS proved to be more successful. A series of qualitative and quantitative crucible tests were developed that allowed screening of feed modifications that might be used to reduce MIS penetration. These tests showed that increasing the specific surface area of the soil (used as the primary glass-forming solid in the baseline process) by grinding stopped MIS penetration nearly entirely for feeds that contained waste simulants with lower quantities of nitrate salts. Grinding soil significantly reduced MIS penetration in feeds with higher nitrate quantities, but it was necessary to add carbohydrates (sucrose or cellulose) to destroy a portion of the nitrate at low temperatures to reach the same low levels of MIS penetration seen for the lower nitrate feeds. Developing feeds to reduce MIS penetration in full-scale BV applications resulted in two additional refinements. Soil-grinding to the necessary levels proved to be difficult and expensive, so the fine soil was replaced with readily available fine-grained glass-forming minerals. Cellulose was shown to have less impact on dryer operation than sucrose and was chosen as the carbohydrate source to use in subsequent engineering- and full-scale tests. (authors)

  6. Subsea pipeline gets welded branch without halting flow

    SciTech Connect (OSTI)

    West, A.; Hutt, G.; Starsmore, R.


    In October 1994, a 16 in. welded branch was installed without interruption to production onto Wintershall Noordzee BV`s 36-in. gas pipeline from the K13-A platform in the Dutch sector of the North Sea to Den helder, The Netherlands. The procedure is the first successfully to combine hyperbaric welding and subsea hot tapping without interruption to production. Developers of new fields can now consider exporting product without interrupting existing production and through existing infrastructure even if no convenient tie-in locations exist. Unocal evaluated export options and established that the most attractive alternative was to export gas into the Wintershall 36-in. K13-A to Den Helder pipeline. Various options for installing a branch included the following: flooding the pipeline and installing a conventional tee; stopping production and installing a welded branch followed by hot tapping; and continuing production and installing a welded branch followed by hot tapping. The chosen scheme was to retrofit a subsea side-tap assembly. This was achieved by installation of a welded branch followed by hot tapping into the 36-in. pipeline. The paper describes location determination, schedules, onshore preparation, and offshore work.

  7. SAPO-34 Membranes for N-2/CH4 separation: Preparation, characterization, separation performance and economic evaluation

    SciTech Connect (OSTI)

    Li, SG; Zong, ZW; Zhou, SJ; Huang, Y; Song, ZN; Feng, XH; Zhou, RF; Meyer, HS; Yu, M; Carreon, MA


    SAPO-34 membranes were synthesized by several routes towards N-2/CH4 separation. Membrane synthesis parameters including water content in the gel, crystallization time, support pore size, and aluminum source were investigated. High performance N-2-selective membranes were obtained on 100-nm-pore alumina tubes by using Al(i-C3H7O)(3) as aluminum source with a crystallization time of 6 h. These membranes separated N-2 from CH, with N-2 permeance as high as 500 GPU with separation selectivity of 8 at 24 degrees C. for a 50/50 N-2/CH4 mixture. Nitrogen and CH, adsorption isotherms were measured on SAPO-34 crystals. The N-2 and CH, heats of adsorption were 11 and 15 kJ/mol, respectively, which lead to a preferential adsorption of CE-H-4 over N-2 in the N-2/CH4 mixture. Despite this, the SAPO-34 membranes were selective for N-2 over CH4 in the mixture because N-2 diffuses much faster than CH4 and differences in diffusivity played a more critical role than the competitive adsorption. Preliminary economic evaluation indicates that the required N-2/CH4 selectivity would be 15 in order to maintain a CH4 loss below 10%. For small nitrogen-contaminated gas wells, our current SAPO-34 membranes have potential to compete with the benchmark technology cryogenic distillation for N-2 rejection. (C) 2015 Elsevier B.V. All rights reserved,

  8. Impact of membrane characteristics on the performance and cycling of the Br-2-H-2 redox flow cell

    SciTech Connect (OSTI)

    Tucker, MC; Cho, KT; Spingler, FB; Weber, AZ; Lin, GY


    The Br-2/H-2 redox flow cell shows promise as a high-power, low-cost energy storage device. In this paper, the effect of various aspects of material selection and processing of proton exchange membranes on the operation of the Br-2/H-2 redox flow cell is determined. Membrane properties have a significant impact on the performance and efficiency of the system. In particular, there is a tradeoff between conductivity and crossover, where conductivity limits system efficiency at high current density and crossover limits efficiency at low current density. The impact of thickness, pretreatment procedure, swelling state during cell assembly, equivalent weight, membrane reinforcement, and addition of a microporous separator layer on this tradeoff is assessed. NR212 (50 mu m) pretreated by soaking in 70 degrees C water is found to be optimal for the studied operating conditions. For this case, an energy efficiency of greater than 75% is achieved for current density up to 400 mA cm(-2), with a maximum obtainable energy efficiency of 88%. A cell with this membrane was cycled continuously for 3164 h. Membrane transport properties, including conductivity and bromine and water crossover, were found to decrease moderately upon cycling but remained higher than those for the as-received membrane. (C) 2015 Elsevier B.V. All rights reserved.

  9. Oxidative Stress and Skeletal Health with Low-Dose, Low-LET (Linear Energy Transfer) Ionizing Radiation

    SciTech Connect (OSTI)

    Globus, Ruth K.


    We performed in vivo and in vitro experiments to accomplish the following specific aims of this project: 1) determine if low dose, low LET radiation affects skeletal remodeling at structural, cellular and molecular levels and 2) determine if low dose, low LET radiation modulates skeletal health during aging via oxidative mechanisms. A third aim is supported by NASA supplement to this DOE grant focusing on the influence of high LET radiation on bone. A series of experiments were conducted at the NASA Space Radiation Laboratory at Brookhaven, NSRL-BNL, using iron (56Fe) or a sequential exposure to protons / iron / protons, and separate experiments at NASA Ames Research Center (ARC) using 137Cs. The following provides a summary of key findings. (1) Exposure of nine-week old female mice to priming doses of gamma radiation (10cGy x 5) did not significantly affect bone volume/total volume (BV/TV) or microarchitecture as analyzed by 3D microcomputed tomography. As expected, exposure to the challenge dose of 2 Gy gamma irradiation resulted in significant decreases in BV/TV. The priming dose combined with the 2Gy challenge dose had no further effect on BV/TV compared to challenge dose alone, with the sole exception of the Structural Model Index (SMI). SMI reflects the ratio of rods-to-plates in cancellous bone tissue, such that higher SMI values indicate a tendency toward a weaker structure compared to lower SMI values. Mice treated with both priming and challenge dose had 25% higher SMI values compared to sham-irradiated controls and 7% higher values compared to mice treated with the challenge dose alone. Thus, although this priming regimen had relatively modest effects on cancellous tissue, the difference in SMI suggests this fractionated priming doses have adverse, rather than beneficial, effects on bone structure. (2) In 10-week old male mice, a single exposure to 100cGy of 137Cs reduces trabecular bone number and connectivity density by 20% and 36% respectively one month after irradiation (IR). At four months post-IR, these animals were comparable to sham-treated controls with regards to the abovementioned structural parameters. Irradation at 1 or 10 cGy did not result in any significant changes in bone structural parameters. (3) Irradiation of 16-wk old male mice with high doses of 56Fe or proton (50 or 200cGy), but not at low doses (5 or 10cGy), showed a similar loss of cancellous BV/TV and trabecular number at five weeks post-IR. (4) Age-related bone loss overtook acute radiation-induced decrements in bone structure within four months post-IR with 100 cGy gamma and 12 months post-IR with 200 cGy iron. Transgenic mice globally overexpressing human catalase gene in mitochondria did not exhibit cancellous bone loss as assessed at four month post-IR with 10 cGy proton, 50 cGy iron, or in combination. (5) The cellular and molecular mechanisms responsible for loss of bone with radiation are mediated primarily through increased osteoclastogenesis. Our data provide evidence that there are increases in gene expression of TNF alpha and MCP1 in the bone marrow cells 24 hours post-IR and of osteoclastogenic differentiation factor RANKL by day 3. These cytokines in the marrow may stimulate mature osteoclasts or drive osteoclastogenesis from precursors. (6) Osteoblastogenesis from marrow progenitors evaluated ex vivo decreased following whole body 56Fe irradiation at a dose threshold between 20 and 50 cGy whereas osteoclastogenesis ex vivo increased with doses as low as 10cGy two days post-IR of mice. However, the latter finding was not observed in more than a single experiment. (7) Gamma irradiation of cells in vitro requires relatively high doses (200cGy) to disturb normal osteoblastogenesis and osteoclastogenesis as evidenced by decrements in mineralized nodule formation, osteoclast counts, and expression of osteoblast related genes such as runx2, col1a1. (8) We also investigated the effect of antioxidants on osteoblastogenesis following low dose in vitro gamma irradiation (15cGy) on day four bone marrow stromal cell cultures. Superoxide dismutase (SOD) was added to the cell culture medium for 2 or 3 days post-irradiation and cell colonies were counted on days 7 and 10. SOD treatment increased cell growth as measured by DNA content and colony forming units (CFU) in both irradiated cells and 0 cGy control groups. However, low dose radiation of 15cGy abolished SOD stimulatory effects on cell growth and CFU number. These results suggest that exogenous SOD increases osteoblast cell growth and colony formation and that low-dose radiation (15cGy) can interfere with the antioxidant effects. In summary, our findings indicate that acute, whole body irradiation at high doses (50-200 cGy) results in prompt tissue degradation and bone loss. Lower doses (<50 cGy) do not cause bone structural deterioration but may deplete stem/progenitor cell pools in the bone marrow.

  10. Advanced materials for sodium-beta alumina batteries: Status, challenges and perspectives

    SciTech Connect (OSTI)

    Lu, XC; Xia, GG; Lemmon, JP; Yang, ZG


    The increasing penetration of renewable energy and the trend toward clean, efficient transportation have spurred growing interests in sodium-beta alumina batteries that store electrical energy via sodium ion transport across a beta ''-Al(2)O(3) solid electrolyte at elevated temperatures (typically 300-350 degrees C ). Currently, the negative electrode or anode is metallic sodium in molten state during battery operation; the positive electrode or cathode can be molten sulfur (Na-S battery) or solid transition metal halides plus a liquid phase secondary electrolyte (e.g., ZEBRA battery). Since the groundbreaking works in the sodium-beta alumina batteries a few decades ago, encouraging progress has been achieved in improving battery performance, along with cost reduction. However, there remain issues that hinder broad applications and market penetration of the technologies. To better the Na-beta alumina technologies require further advancement in materials along with component and system design and engineering. This paper offers a comprehensive review on materials of electrodes and electrolytes for the Na-beta alumina batteries and discusses the challenges ahead for further technology improvement. (C) 2009 Published by Elsevier B.V.

  11. N A T I O N A L L E A D C O

    Office of Legacy Management (LM)

    ', ,, -_ L _ ---_ . . . N A T I O N A L L E A D C O . O F O H IO -- H E A L T H A S A F E T Y DIVISION industrial H y g i e n e o r Medical Dept. Analytical Chemistry Dept. 1. H . # ~ S a m p l e N o r Location, Dorr c O N D i 3 I W R e m & D a t e C o l l a c t e d ~ b y W B R o u t e to-- T y p e of S a m p l e air &llB* A n a l y z e d for - & & B M e t h o d of Analysi. bv- C o u n t i n g Data: B K G D & - G E O A N ? - 1 8 2 2 -, > ' _ \ i NATIONAL LEAD CO. OF OHIO

  12. Rate dependence of swelling in lithium-ion cells

    SciTech Connect (OSTI)

    Oh, KY; Siegel, JB; Secondo, L; Kim, SU; Samad, NA; Qin, JW; Anderson, D; Garikipati, K; Knobloch, A; Epureanu, BI; Monroe, CW; Stefanopoulou, A


    Swelling of a commercial 5 Ah lithium-ion cell with a nickel/manganese/cobalt-oxide cathode is investigated as a function of the charge state and the charge/discharge rate. In combination with sensitive displacement measurements, knowledge of the electrode configuration within this prismatic cell's interior allows macroscopic deformations of the casing to be correlated to electrochemical and mechanical transformations in individual anode/separator/cathode layers. Thermal expansion and interior charge state are both found to cause significant swelling. At low rates, where thermal expansion is negligible, the electrode sandwich dilates by as much as 1.5% as the charge state swings from 0% to 100% because of lithium-ion intercalation. At high rates a comparably large residual swelling was observed at the end of discharge. Thermal expansion caused by joule heating at high discharge rate results in battery swelling. The changes in displacement with respect to capacity at low rate correlate well with the potential changes known to accompany phase transitions in the electrode materials. Although the potential response changes minimally with the C-rate, the extent of swelling varies significantly, suggesting that measurements of swelling may provide a sensitive gauge for characterizing dynamic operating states. (C) 2014 Elsevier B.V. All rights reserved.

  13. Neutron response characterization for an EJ299-33 plastic scintillation detector

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lawrence, Chris C.; Febbraro, Michael; Massey, Thomas N.; Flaska, Marek; Becchetti, F. D.; Pozzi, Sara A.


    Organic scintillation detectors have shown promise as neutron detectors for characterizing special nuclear materials in various arms-control and homeland security applications. Recent advances have yielded a new plastic scintillator - EJ299-33 - with pulse-shape-discrimination (PSD) capability. Plastic scintillators would have a much expanded range of deployment relative to liquids and crystals. Here, we present a full characterization of pulse height response to fission-energy neutrons for an EJ299-33 detector with 7.62-by-7.62-cm cylindrical active volume, and compare with an EJ309 liquid scintillator in the same assembly. Scintillation light output relations, energy resolutions, and response matrices are presented for both detectors. A Continuousmore » spectrum neutron source, obtained via the bombardment of Al-27 with 7.44-MeV deuterons at the Edwards Accelerator Facility at Ohio University, was used for the measurement. A new procedure for evaluating and comparing PSD performance is presented which accounts for the effect of the light output relation on the ability to detect low energy neutrons. The EJ299-33 is shown to have considerable deficit in matrix condition, and in PSD figure of merit when compared to EJ309, especially when neutron energy is taken into account. Furthermore the EJ299 is likely to bring a modest PSD capability into a array of held applications that are not accessible to liquids or crystals. (C) 2014 Elsevier B.V. All rights reserved. Keywords« less

  14. Water uptake, ionic conductivity and swelling properties of anion-exchange membrane

    SciTech Connect (OSTI)

    Duan, QJ; Ge, SH; Wang, CY


    Water uptake, ionic conductivity and dimensional change of the anion-exchange membrane made by Tokuyama Corporation (A201 membrane) are investigated at different temperatures and water activities. Specifically, the amount of water taken up by membranes exposed to water vapor and membranes soaked in liquid water is determined. The water uptake of the A201 membrane increases with water content as well as temperature. In addition, water sorption data shows Schroeder's paradox for the AEMs investigated. The swelling properties of the A201 membrane exhibit improved dimensional stability compared with Nafion membrane. Water sorption of the A201 membrane occurs with a substantial negative excess volume of mixing. The threshold value of hydrophilic fraction in the A201 membrane for ionic conductivity is around 0.34, above which, the conductivity begins to rise quickly. This indicates that a change in the connectivity of the hydrophilic domains occurs when hydrophilic fraction approaches 0.34. (C) 2013 Elsevier B.V. All rights reserved.

  15. Effects of plasma {beta} on the plasmoid instability

    SciTech Connect (OSTI)

    Ni Lei; Ziegler, Udo; Huang Yimin; Lin Jun; Mei Zhixing


    The effects of the initial upstream plasma {beta} on the plasmoid instability are studied via two-dimensional resistive magnetohydrodynamic simulations. For cases with nonuniform {beta} dependent initial plasma mass density and uniform temperature, our numerical results indicate that the critical Lundquist number for onset of the plasmoid instability depends on the initial plasma {beta}. The critical Lundquist number is approximately 2000-3000 for {beta}=50 and is 8000-10 000 for {beta}=0.2. The higher the {beta}, the smaller the critical Lundquist number is. Similar to previous studies of high-{beta} systems, the average reconnection rate in low {beta} systems is found to become weakly dependent on the Lundquist number in the plasmoid-unstable regime. However, the average reconnection rate, normalized to the asymptotic value of upstream BV{sub A}, is lower in a low {beta} system than that in a high {beta} system. The magnetic energy spectral index, which characterizes fragmentation of the reconnection layer, is approximately two and is insensitive to {beta} in the high-Lunquist number regime. It is also found that the magnetic reconnection rate becomes similar for different {beta} cases, if the initial force-balance is provided by temperature gradient instead of density gradient. Therefore, it is concluded that the {beta}-dependence mentioned above may be largely attributed to the density variation.

  16. Extending the radial diffusion model of Falthammar to non-dipole background field

    SciTech Connect (OSTI)

    Cunningham, Gregory Scott


    A model for radial diffusion caused by electromagnetic disturbances was published by Falthammar (1965) using a two-parameter model of the disturbance perturbing a background dipole magnetic field. Schulz and Lanzerotti (1974) extended this model by recognizing the two parameter perturbation as the leading (non--dipole) terms of the Mead Williams magnetic field model. They emphasized that the magnetic perturbation in such a model induces an electric ield that can be calculated from the motion of field lines on which the particles are ‘frozen’. Roederer and Zhang (2014) describe how the field lines on which the particles are frozen can be calculated by tracing the unperturbed field lines from the minimum-B location to the ionospheric footpoint, and then tracing the perturbed field (which shares the same ionospheric footpoint due to the frozen -in condition) from the ionospheric footpoint back to a perturbed minimum B location. The instantaneous change n Roederer L*, dL*/dt, can then be computed as the product (dL*/dphi)*(dphi/dt). dL*/Dphi is linearly dependent on the perturbation parameters (to first order) and is obtained by computing the drift across L*-labeled perturbed field lines, while dphi/dt is related to the bounce-averaged gradient-curvature drift velocity. The advantage of assuming a dipole background magnetic field, as in these previous studies, is that the instantaneous dL*/dt can be computed analytically (with some approximations), as can the DLL that results from integrating dL*/dt over time and computing the expected value of (dL*)^2. The approach can also be applied to complex background magnetic field models like T89 or TS04, on top of which the small perturbations are added, but an analytical solution is not possible and so a numerical solution must be implemented. In this talk, I discuss our progress in implementing a numerical solution to the calculation of DL*L* using arbitrary background field models with simple electromagnetic perturbations.

  17. Unilateral radiation pneumonitis in sheep: Physiological changes and bronchoalveolar lavage

    SciTech Connect (OSTI)

    Tillman, B.F.; Loyd, J.E.; Malcolm, A.W.; Holm, B.A.; Brigham, K.L. )


    Radiation pneumonitis is a life-threatening result of therapeutic thoracic irradiation, yet its mechanisms are poorly understood. We studied the effects of unilateral lung irradiation (3,000 rad) in sheep from the immediate response to the later development of radiation pneumonitis. We defined radiation pneumonitis by its diagnostic clinical feature, radiographic infiltration of the irradiated zone with a straight margin corresponding to the radiation port. The immediate response in the few hours after irradiation was characterized by cough, labored respiration, hypoxemia (arterial PO{sub 2} decreased 19 Torr), mild pulmonary hypertension (pulmonary arterial pressure increased 20%), and lymphopenia. Hemodynamics and gas exchange returned to normal by day 2 but became abnormal again before or during radiation pneumonitis at 32 +/- 2 days. Respiratory distress, hypoxemia, and pulmonary hypertension recurred during radiation pneumonitis. Bronchoalveolar lavage during radiation pneumonitis contained increased neutrophils (19 +/- 4%, control = 7%), increased protein (0.27 +/- 0.1 g/dl, control = 0.12 +/- 0.03), and severely impaired ability to lower surface tension. Alveolar macrophages from both lungs during unilateral radiation pneumonitis exhibited impaired generation of superoxide after phorbol myristate (only a 30% increase). Normal control alveolar macrophages increased superoxide production after stimulation greater than 400%. We conclude that unilateral lung irradiation in sheep causes a mild immediate response followed by radiation pneumonitis at 1 mo. Unilateral radiation pneumonitis in this model is associated with ipsilateral neutrophilic alveolitis, increased bronchoalveolar lavage protein, and impaired surfactant function, as well as bilateral functional abnormalities of alveolar macrophages.

  18. Updating about reductions of air and blood lead concentrations in Turin, Italy, following reductions in the lead content of gasoline

    SciTech Connect (OSTI)

    Bono, R.; Pignata, C.; Gilli, G.


    Considering its well known toxicity and the chronic human exposure to lead, international lawmakers enforced some directives or laws calling for the reduction of lead content in gasoline. All of these legislative acts aimed to reduce health risks for the general population. The aim of this study was to consider the effectiveness of these laws on air lead levels and consequently on blood lead levels in a randomly selected urban Italian population. In particular, these markers were analyzed over the course of several years, corresponding to the periods just before and after enforcements of the reductions of lead in petrol. Data presented point out some considerations: (1) enforcement of legislative measures concerning the reduction of lead in petrol has reduced atmospheric levels of lead. This result demonstrates a major environmental success in primary prevention efforts. (2) This success is clear especially considering that the actual Pb-B levels can be extended to the urbanized populations. Pb-B levels were consistently higher for drinkers, for older adults and for males. The mean of Pb-B level for the present urbanized population is higher than the U.S. overall population (6.4 vs 3 {mu}g/dl). This difference can be also explained considering the different historical period of enforcement of the restriction laws. 10 refs., 3 figs., 3 tabs.

  19. Vacuum pyrolysis of used tires

    SciTech Connect (OSTI)

    Roy, C.; Darmstadt, H.; Benallal, B.; Chaala, A.; Schwerdtfeger, A.E.


    The vacuum pyrolysis of used tires enables the recovery of useful products, such as pyrolytic oil and pyrolytic carbon black (CB{sub P}). The light part of the pyrolytic oil contains dl-limonene which has a high price on the market. The naphtha fraction can be used as a high octane number component for gasoline. The middle distillate demonstrated mechanical and lubricating properties similar to those of the commercial aromatic oil Dutrex R 729. The heavy oil was tested as a feedstock for the production of needle coke. It was found that the surface morphology of CB{sub P} produced by vacuum pyrolysis resembles that of commercial carbon black. The CB{sub P} contains a higher concentration of inorganic compounds (especially ZnO and S) than commercial carbon black. The pyrolysis process feasibility looks promising. One old tire can generate upon vacuum pyrolysis, incomes of at least $2.25 US with a potential of up to $4.83 US/tire upon further product improvement. The process has been licensed to McDermott Marketing Servicing Inc. (Houston) for its exploitation in the US.

  20. GIHPH5Q RSUT0VWSUX`Y!SUacbedDfgbihehep

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  1. A brief overview of Chinese Design Code on Fossil-Fueled Power Plants

    SciTech Connect (OSTI)

    Xu Zhongqing; He Yehong


    The Chinese Design Code on Fossil Fueled Power Plants (DL 5000-94) was issued in April 1994 by the Ministry of Electric Power Industry, P.R. China, and the English version has been drafted and will be formally published in the near future. Based on the 1984 version and the nation`s current policies, the 1994 version was formed to meet the challenges of the nation`s speedy development of electric power construction. In general, the code is primarily a directive document guiding the planning and engineering of China`s large- and medium-sized fossil-fueled power plants. The preparation of the 1984 version and the revision of it to the 1994 version were all carried out by the East China Electric Power Design Institute under the direction of Electric Power Planning and Engineering Institute. For small-sized power plants with unit rating of 25 MW and below, there is another national design code titled Code for Design of Small Sized Power Plants (GB 50049-94) issued in November 1994 jointly by the China`s National Technology Supervision Administration and the Ministry of Construction.

  2. Development of carbon-metal oxide supercapacitors from sol-gel derived carbon-ruthenium xerogels

    SciTech Connect (OSTI)

    Lin, C.; Ritter, J.A.; Popov, B.N.


    There has been increasing interest in electrochemical capacitors as energy storage systems because of their high power density and long cycle life, compared to battery devices. According to the mechanism of energy storage, there are two types of electrochemical capacitors. One type is based on double layer (dl) formation due to charge separation, and the other type is based on a faradaic process due to redox reactions. Sol-gel derived high surface area carbon-ruthenium xerogels were prepared from carbonized resorcinol-formaldehyde resins containing an electrochemically active form of ruthenium oxide. The electrochemical capacitance of these materials increased with an increase in the ruthenium content indicating the presence of pseudocapacitance associated with the ruthenium oxide undergoing reversible faradaic redox reactions. A specific capacitance of 256 F/g (single electrode) was obtained from a carbon xerogel containing 14 wt% Ru, which corresponded to more than 50% utilization of the ruthenium. The double layer accounted for 40% of this capacitance. This material was also electrochemically stable, showing no change in a cyclic voltammogram for over 2,000 cycles.

  3. STOCK: Structure mapper and online coarse-graining kit for molecular simulations

    SciTech Connect (OSTI)

    Bevc, Staš; Junghans, Christoph; Praprotnik, Matej


    We present a web toolkit STructure mapper and Online Coarse-graining Kit for setting up coarse-grained molecular simulations. The kit consists of two tools: structure mapping and Boltzmann inversion tools. The aim of the first tool is to define a molecular mapping from high, e.g. all-atom, to low, i.e. coarse-grained, resolution. Using a graphical user interface it generates input files, which are compatible with standard coarse-graining packages, e.g. VOTCA and DL_CGMAP. Our second tool generates effective potentials for coarse-grained simulations preserving the structural properties, e.g. radial distribution functions, of the underlying higher resolution model. The required distribution functions can be provided by any simulation package. Simulations are performed on a local machine and only the distributions are uploaded to the server. The applicability of the toolkit is validated by mapping atomistic pentane and polyalanine molecules to a coarse-grained representation. Effective potentials are derived for systems of TIP3P (transferable intermolecular potential 3 point) water molecules and salt solution. The presented coarse-graining web toolkit is available at

  4. Conditions for establishing quasistable double layers in the Earth's auroral upward current region

    SciTech Connect (OSTI)

    Main, D. S.; Newman, D. L.; Ergun, R. E.


    The strength and stability of simulated double layers at the ionosphere-auroral cavity boundary have been studied as a function of cold ionospheric electron temperature and density. The simulations are performed with an open boundary one-dimensional particle-in- cell (PIC) simulation and are initialized by imposing a density cavity within the simulation domain. The PIC simulation includes H{sup +} and O{sup +} ion beams, a hot H{sup +} background population, cold ionospheric electrons, and a hot electron population. It is shown that a double layer remains quasistable for a variety of initial conditions and plasma parameters. The average potential drop of the double layer is found to increase as the cold electron temperature decreases. However, in terms of cold electron density, the average potential drop of the double layer is found to increase up to some critical cold electron density and decreases above this value. Comparisons with FAST observations are made and agreement is found between simulation results and observations in the shape and width of the double layer. This study helps put a constraint on the plasma conditions in which a DL can be expected to form and remain quasistable.

  5. Crossing-over in rearranging chromosomes of Drosophila: The role of delayed pairing

    SciTech Connect (OSTI)

    Chadov, B.F.; Chadova, E.V.; Khotskina, E.A.


    A Df(2R)MS2-10 deletion of pericentromeric heterochromatin and an Is(Y;2L)419 insertion of Y material in the region 34A, as well as nondisjunction of chromosomes 2 in 2/F(2L); F(2R) females did not directly prevent chromosome arms in chromosome 2 of Drosophila from pairing. However, these events resulted in (1) two- to four-fold decrease in the rate of crossing-over in chromosome 2; (2) a decreased proportion of exchange tetrads two to three times greater for multiple-exchange tetrads than for single-exchange ones; and (3) a decreased rate of crossing-over throughout the entire chromosome arm enhanced in a proximal direction. An In(1)dl-49+B{sup M1}inversion in the X chromosome cancelled the suppression of crossing-over. Crossing-over increased due to an increasing proportion of single-exchange tretrads. The changes in crossing-over found cannot be explained by asynapsis in the chromosomes with rearrangements. According to the authors, these changes are probably accounted for by a delayed pairing of these chromosomes. The delayed pairing of individual chromosome regions or the whole chromosome is considered the most common type of pairing disturbance. It effects on meiosis are discussed. 39 refs., 6 figs., 1 tab.

  6. Health and environmental outcomes of traditional and modified practices for abatement of residential lead-based paint

    SciTech Connect (OSTI)

    Farfel, M.R.; Chisolm, J.J. Jr. )


    We evaluated traditional and modified practices for abating lead-based paint in homes of children with blood-lead concentrations (PbB) greater than 1.4 mumol/L (greater than 29 micrograms/dl). Traditional abatement resulted in acute increases in: (1) lead contaminated house dust (generally 3 to 6-fold over pre-abatement levels, but at abated sites typically 10 to 100-fold); and (2) the PbBs of nearly half of the occupant children. Modified practices represented modest short-term improvement compared to traditional practices but were also inadequate. By six months, it was clear that neither form of abatement resulted in long-term reductions of PbB or house dust lead levels, leaving children at continued risk of excessive exposure to lead and permanent adverse neurobehavioral effects. Windows were found to be high sources of lead contaminated house dust. Recommendations are made for improved abatement practices including more complete abatement of window units and more effective clean-up to remove lead-bearing dust. Thirteen million US children live in lead-painted dwellings. Research is needed to identify abatement strategies that will be practical and well suited to the current understanding of low-level lead toxicity.

  7. Transient Inverse Calibration of Site-Wide Groundwater Model to Hanford Operational Impacts from 1943 to 1996--Alternative Conceptual Model Considering Interaction with Uppermost Basalt Confined Aquifer

    SciTech Connect (OSTI)

    Vermeul, Vincent R.; Cole, Charles R.; Bergeron, Marcel P.; Thorne, Paul D.; Wurstner, Signe K.


    The baseline three-dimensional transient inverse model for the estimation of site-wide scale flow parameters, including their uncertainties, using data on the transient behavior of the unconfined aquifer system over the entire historical period of Hanford operations, has been modified to account for the effects of basalt intercommunication between the Hanford unconfined aquifer and the underlying upper basalt confined aquifer. Both the baseline and alternative conceptual models (ACM-1) considered only the groundwater flow component and corresponding observational data in the 3-Dl transient inverse calibration efforts. Subsequent efforts will examine both groundwater flow and transport. Comparisons of goodness of fit measures and parameter estimation results for the ACM-1 transient inverse calibrated model with those from previous site-wide groundwater modeling efforts illustrate that the new 3-D transient inverse model approach will strengthen the technical defensibility of the final model(s) and provide the ability to incorporate uncertainty in predictions related to both conceptual model and parameter uncertainty. These results, however, indicate that additional improvements are required to the conceptual model framework. An investigation was initiated at the end of this basalt inverse modeling effort to determine whether facies-based zonation would improve specific yield parameter estimation results (ACM-2). A description of the justification and methodology to develop this zonation is discussed.

  8. Evidence for small-molecule-mediated loop stabilization in the structure of the isolated Pin1 WW domain

    SciTech Connect (OSTI)

    Mortenson, David E.; Kreitler, Dale F.; Yun, Hyun Gi; Gellman, Samuel H., E-mail:; Forest, Katrina T., E-mail: [University of Wisconsin-Madison, Madison, WI 53706 (United States)


    Two structures of a small protein with a defined tertiary fold, the isolated Pin1 WW domain, have been determined via racemic crystallization with small-molecule additives. These additives, which are either racemic or achiral, appear to stabilize a dynamic loop region of the structure. The human Pin1 WW domain is a small autonomously folding protein that has been useful as a model system for biophysical studies of ?-sheet folding. This domain has resisted previous attempts at crystallization for X-ray diffraction studies, perhaps because of intrinsic conformational flexibility that interferes with the formation of a crystal lattice. Here, the crystal structure of the human Pin1 WW domain has been obtained via racemic crystallization in the presence of small-molecule additives. Both enantiomers of a 36-residue variant of the Pin1 WW domain were synthesized chemically, and the l- and d-polypeptides were combined to afford diffracting crystals. The structural data revealed packing interactions of small carboxylic acids, either achiral citrate or a d,l mixture of malic acid, with a mobile loop region of the WW-domain fold. These interactions with solution additives may explain our success in crystallization of this protein racemate. Molecular-dynamics simulations starting from the structure of the Pin1 WW domain suggest that the crystal structure closely resembles the conformation of this domain in solution. The structural data presented here should provide a basis for further studies of this important model system.

  9. STOCK: Structure mapper and online coarse-graining kit for molecular simulations

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bevc, Staš; Junghans, Christoph; Praprotnik, Matej


    We present a web toolkit STructure mapper and Online Coarse-graining Kit for setting up coarse-grained molecular simulations. The kit consists of two tools: structure mapping and Boltzmann inversion tools. The aim of the first tool is to define a molecular mapping from high, e.g. all-atom, to low, i.e. coarse-grained, resolution. Using a graphical user interface it generates input files, which are compatible with standard coarse-graining packages, e.g. VOTCA and DL_CGMAP. Our second tool generates effective potentials for coarse-grained simulations preserving the structural properties, e.g. radial distribution functions, of the underlying higher resolution model. The required distribution functions can be providedmore » by any simulation package. Simulations are performed on a local machine and only the distributions are uploaded to the server. The applicability of the toolkit is validated by mapping atomistic pentane and polyalanine molecules to a coarse-grained representation. Effective potentials are derived for systems of TIP3P (transferable intermolecular potential 3 point) water molecules and salt solution. The presented coarse-graining web toolkit is available at« less


    SciTech Connect (OSTI)

    SCHAUS, P.S.


    At the U.S. Department of Energy (DOE) Hanford Site, the Waste Treatment Plant (WTP) is being constructed to immobilize both high-level waste (IUW) for disposal in a national repository and low-activity waste (LAW) for onsite, near-surface disposal. The schedule-controlling step for the WTP Project is vitrification of the large volume of LAW, current capacity of the WTP (as planned) would require 50 years to treat the Hanford tank waste, if the entire LAW volume were to be processed through the WTP. To reduce the time and cost for treatment of Hanford Tank Waste, and as required by the Tank Waste Remediation System Environmental Impact Statement Record of Decision and the Hanford Federal Facility Consent Agreement (Tn-Party Agreement), DOE plans to supplement the LAW treatment capacity of the WTP. Since 2002, DOE, in cooperation with the Environmental Protection Agency and State of Washington Department of Ecology has been evaluating technologies that could provide safe and effective supplemental treatment of LAW. Current efforts at Hanford are intended to provide additional information to aid a joint agency decision on which technology will be used to supplement the WTP. A Research, Development and Demonstration permit has been issued by the State of Washington to build and (for a limited time) operate a Demonstration Bulk Vitrification System (DBVS) facility to provide information for the decision on a supplemental treatment technology for up to 50% of the LAW. In the Bulk Vitrification (BV) process, LAW, soil, and glass-forming chemicals are mixed, dried, and placed in a refractory-lined box, Electric current, supplied through two graphite electrodes in the box, melts the waste feed, producing a durable glass waste-form. Although recent modifications to the process have resulted in significant improvements, there are continuing technical concerns.

  11. Oxidation of elemental mercury vapor over gamma-Al2O3 supported CuCl2 catalyst for mercury emissions control

    SciTech Connect (OSTI)

    Liu, Zhouyang; Liu, Xin; Lee, Joo-Youp; Bolin, Trudy B.


    In our previous studies, CuCl2 demonstrated excellent Hg(0) oxidation capability and holds potential for Hg(0) oxidation in coal-fired power plants. In this study, the properties and performances of CuCl2 supported onto gamma-Al2O3 with high surface area were investigated. From various characterization techniques using XPS, XAFS, XRD, TPR, SEM and TGA, the existence of multiple copper species was identified. At low CuCl2 loadings, CuCl2 forms copper aluminate species with gamma-Al2O3 and is inactive for Hg(0) oxidation. At high loadings, amorphous CuCl2 forms onto the gamma-Al2O3 surface, working as a redox catalyst for Hg(0) oxidation by consuming Cl to be converted into CuCl and then being regenerated back into CuCl2 in the presence of O-2 and HCl gases. The 10%(wt) CuCl2/gamma-Al2O3 catalyst showed excellent Hg(0) oxidation performance and SO2 resistance at 140 degrees C under simulated flue gas conditions containing 6%(v) O-2 and 10 ppmv HCl. The oxidized Hg(0) in the form of HgCl2 has a high solubility in water and can be easily captured by other air pollution control systems such as wet scrubbers in coal-fired power plants. The CuCl2/gamma-Al2O3 catalyst can be used as a low temperature Hg(0) oxidation catalyst. (C) 2015 Elsevier B.V. All rights reserved.

  12. Microstructure and magnetic properties of (001) textured L1(0) FePt films on amorphous glass substrate

    SciTech Connect (OSTI)

    Speliotis, T; Varvaro, G; Testa, AM; Giannopoulos, G; Agostinelli, E; Li, W; Hadjipanayis, G; Niarchos, D


    L1(0) FePt thin films with an island-like morphology and magnetic perpendicular anisotropy were grown at low temperature (300 < T-dep< 375 degrees C) by magnetron sputtering on Hoya glass substrates using a 30-nm thick Cr (2 0 0) underlayer. An MgO buffer layer with a thickness of 2 nm was used to inhibit the diffusion from the Cr underlayer and promote the growth of (0 0 1) oriented L1(0) FePt films by inducing an in-plane lattice distortion. By varying the substrate temperature and the Ar sputter pressure (3.5 < P-Ar< 15 mTorr) during the deposition, the degree of chemical order, the microstructure and the magnetic properties were tuned and the best properties in term of squareness ratio (M-r/M-s similar to 0.95) and coercive field (H-c similar to 14 kOe) were observed for films deposited at T-dep = 350 degrees C and P-Ar= 5 mTorr, due to the appearance of a tensile strain, which favors the perpendicular anisotropy. The analysis of the angular dependence of remanent magnetization curves on the optimized sample suggests that the magnetization reversal is highly incoherent due to the inter-island interactions. Our results provide useful information on the low temperature growth of FePt films with perpendicular anisotropy onto glass substrates, which are relevant for a variety of technological applications, such as magnetic recording and spintronic devices. (C) 2015 Elsevier B.V. All rights reserved.

  13. APASS Landolt-Sloan BVgri photometry of Rave stars. I. Data, effective temperatures, and reddenings

    SciTech Connect (OSTI)

    Munari, U.; Siviero, A.; Henden, A.; Frigo, A.; Bienaymé, O.; Siebert, A.; Bland-Hawthorn, J.; Boeche, C.; Grebel, E. K.; Freeman, K. C.; Gibson, B. K.; Gilmore, G.; Kordopatis, G.; Helmi, A.; Levine, S. E.; Navarro, J. F.; Parker, Q. A.; Reid, W.; Seabroke, G. M.; and others


    We provide AAVSO Photometric All-Sky Survey (APASS) photometry in the Landolt BV and Sloan g'r'i' bands for all 425,743 stars included in the fourth RAVE Data Release. The internal accuracy of the APASS photometry of RAVE stars, expressed as the error of the mean of data obtained and separately calibrated over a median of four distinct observing epochs and distributed between 2009 and 2013, is 0.013, 0.012, 0.012, 0.014, and 0.021 mag for the B, V, g', r', and i' bands, respectively. The equally high external accuracy of APASS photometry has been verified on secondary Landolt and Sloan photometric standard stars not involved in the APASS calibration process and on a large body of literature data on field and cluster stars, confirming the absence of offsets and trends. Compared with the Carlsberg Meridian Catalog (CMC-15), APASS astrometry of RAVE stars is accurate to a median value of 0.098 arcsec. Brightness distribution functions for the RAVE stars have been derived in all bands. APASS photometry of RAVE stars, augmented by 2MASS JHK infrared data, has been χ{sup 2} fitted to a densely populated synthetic photometric library designed to widely explore temperature, surface gravity, metallicity, and reddening. Resulting T {sub eff} and E {sub B–V}, computed over a range of options, are provided and discussed, and will be kept updated in response to future APASS and RAVE data releases. In the process, we find that the reddening caused by a homogeneous slab of dust, extending for 140 pc on either side of the Galactic plane and responsible for E{sub B−V}{sup poles} = 0.036 ± 0.002 at the Galactic poles, is a suitable approximation of the actual reddening encountered at Galactic latitudes |b| ≥ 25°.

  14. Atomistic modeling of intrinsic and radiation-enhanced fission gas (Xe) diffusion in UO2 +/- x: Implications for nuclear fuel performance modeling

    SciTech Connect (OSTI)

    Giovanni Pastore; Michael R. Tonks; Derek R. Gaston; Richard L. Williamson; David Andrs; Richard Martineau


    Based on density functional theory (DFT) and empirical potential calculations, the diffusivity of fission gas atoms (Xe) in UO2 nuclear fuel has been calculated for a range of non-stoichiometry (i.e. UO2x), under both out-of-pile (no irradiation) and in-pile (irradiation) conditions. This was achieved by first deriving expressions for the activation energy that account for the type of trap site that the fission gas atoms occupy, which includes the corresponding type of mobile cluster, the charge state of these defects and the chemistry acting as boundary condition. In the next step DFT calculations were used to estimate migration barriers and internal energy contributions to the thermodynamic properties and calculations based on empirical potentials were used to estimate defect formation and migration entropies (i.e. pre-exponentials). The diffusivities calculated for out-of-pile conditions as function of the UO2x nonstoichiometrywere used to validate the accuracy of the diffusion models and the DFT calculations against available experimental data. The Xe diffusivity is predicted to depend strongly on the UO2x non-stoichiometry due to a combination of changes in the preferred Xe trap site and in the concentration of uranium vacancies enabling Xe diffusion, which is consistent with experiments. After establishing the validity of the modeling approach, it was used for studying Xe diffusion under in-pile conditions, for which experimental data is very scarce. The radiation-enhanced Xe diffusivity is compared to existing empirical models. Finally, the predicted fission gas diffusion rates were implemented in the BISON fuel performance code and fission gas release from a Ris fuel rod irradiation experiment was simulated. 2014 Elsevier B.V. All rights


    SciTech Connect (OSTI)

    Bourouaine, Sofiane; Chandran, Benjamin D. G.


    Spacecraft measurements show that protons undergo substantial perpendicular heating during their transit from the Sun to the outer heliosphere. In this paper, we use Helios 2 measurements to investigate whether stochastic heating by low-frequency turbulence is capable of explaining this perpendicular heating. We analyze Helios 2 magnetic field measurements in low-{beta} fast-solar-wind streams between heliocentric distances r = 0.29 AU and r = 0.64 AU to determine the rms amplitude of the fluctuating magnetic field, {delta}B{sub p}, near the proton gyroradius scale {rho}{sub p}. We then evaluate the stochastic heating rate Q{sub stoch} using the measured value of {delta}B{sub p} and a previously published analytical formula for Q{sub stoch}. Using Helios measurements we estimate the ''empirical'' perpendicular heating rate Q{sub Up-Tack emp} = (k{sub B}/m{sub p}) BV (d/dr) (T{sub Up-Tack p}/B) that is needed to explain the T{sub p} profile. We find that Q{sub stoch} {approx} Q{sub emp}, but only if a key dimensionless constant appearing in the formula for Q{sub stoch} lies within a certain range of values. This range is approximately the same throughout the radial interval that we analyze and is consistent with the results of numerical simulations of the stochastic heating of test particles in reduced magnetohydrodynamic turbulence. These results support the hypothesis that stochastic heating accounts for much of the perpendicular proton heating occurring in low-{beta} fast-wind streams.

  16. Non-dioxin-like PCBs interact with benzo[a]pyrene-induced p53-responses and inhibit apoptosis

    SciTech Connect (OSTI)

    Al-Anati, Lauy Hoegberg, Johan; Stenius, Ulla


    Non-dioxin-like polychlorinated biphenyls (NDL-PCBs) and polycyclic aromatic hydrocarbons (PAHs) are ubiquitous pollutants often co-existing in contaminated environments. However, there are few studies on the effects of co-exposure, in particular on effects of pure NDL-PCB congeners and PAHs. We have evaluated the effects of some highly purified NDL-PCBs and benzo[a]pyrene (BP) on BP-induced Raf, Erk, Mdm2, p53 signaling and on BP-induced apoptosis and cell cycle arrest. PCBs (1 {mu}M) were added to HepG2 cells 1 h prior to BP and the incubation was stopped at 24 h. Employing Western blotting we found that NDL-PCBs (28, 101 and 153) amplified the BP-induced inactivating phosphorylation of Raf (pRaf Ser 259) and decreased levels of pErk Tyr 204. This treatment also resulted in the attenuation of BP-induced Mdm2 phosphorylation at Ser166 and amplification of the p53 Ser15 response. These effects were associated with an unexpected inhibition of BP-induced apoptosis. A dioxin-like PCB (DL-PCB 126) was used as reference and gave results that were predictable from previous studies, i.e. it attenuated BP-induced p53 response and apoptosis. In an effort to explain why the NDL-PCB-induced amplification of the p53 response was associated with a decreased apoptotic response we analyzed FoxO3a, which may translocate p53 to the cytoplasm. We found that NDL-PCBs reduced the level of phosphorylated FoxO3a at Thr32. This phosphorylation promotes a cytoplasmic translocation of FoxO3a and p53 and our data suggest that NDL-PCBs may inhibit BP-induced apoptosis by preventing a FoxO3a-dependent translocation of p53 to the cytoplasm.

  17. A new 40 MA ranchero explosive pulsed power system

    SciTech Connect (OSTI)

    Goforth, James; Herrera, Dennis; Oona, Hank; Torres, David; Atchison, W L; Colgate, S A; Griego, J R; Guzik, J; Holtkamp, D B; Idzorek, G; Kaul, A; Kirkpatrick, R C; Menikoff, R; Reardon, P T; Reinovsky, R E; Rousculp, C L; Sgro, A G; Tabaka, L J; Tierney, T E; Watt, R G


    We are developing a new high explosive pulsed power (HEPP) system based on the 1.4 m long Ranchero generator which was developed in 1999 for driving solid density z-pinch loads. The new application requires approximately 40 MA to implode similar liners, but the liners cannot tolerate the 65 {micro}s, 3 MA current pulse associated with delivering the initial magnetic flux to the 200 nH generator. To circumvent this problem, we have designed a system with an internal start switch and four explosively formed fuse (EFF) opening switches. The integral start switch is installed between the output glide plane and the armature. It functions in the same manner as a standard input crowbar switch when armature motion begins, but initially isolates the load. The circuit is completed during the flux loading phase using post hole convolutes. Each convolute attaches the inner (coaxial) output transmission line to the outside of the outer coax through a penetration of the outer coaxial line. The attachment is made with the conductor of an EFF at each location. The EFFs conduct 0.75 MA each, and are actuated just after the internal start switch connects to the load. EFFs operating at these parameters have been tested in the past. The post hole convolutes must withstand as much as 80 kV at peak dl/dt during the Ranchero load current pulse. We describe the design of this new HEPP system in detail, and give the experimental results available at conference time. In addition, we discuss the work we are doing to test the upper current limits of a single standard size Ranchero module. Calculations have suggested that the generator could function at up to {approx}120 MA, the rule of thumb we follow (1 MA/cm) suggests 90 MA, and simple flux compression calculations, along with the {approx}4 MA seed current available from our capacitor bank, suggests 118 MA is the currently available upper limit.

  18. Advanced Underground Gas Storage Concepts: Refrigerated-Mined Cavern Storage, Final Report

    SciTech Connect (OSTI)


    Over the past 40 years, cavern storage of LPG's, petrochemicals, such as ethylene and propylene, and other petroleum products has increased dramatically. In 1991, the Gas Processors Association (GPA) lists the total U.S. underground storage capacity for LPG's and related products of approximately 519 million barrels (82.5 million cubic meters) in 1,122 separate caverns. Of this total, 70 are hard rock caverns and the remaining 1,052 are caverns in salt deposits. However, along the eastern seaboard of the U.S. and the Pacific northwest, salt deposits are not available and therefore, storage in hard rocks is required. Limited demand and high cost has prevented the construction of hard rock caverns in this country for a number of years. The storage of natural gas in mined caverns may prove technically feasible if the geology of the targeted market area is suitable; and economically feasible if the cost and convenience of service is competitive with alternative available storage methods for peak supply requirements. Competing methods include LNG facilities and remote underground storage combined with pipeline transportation to the area. It is believed that mined cavern storage can provide the advantages of high delivery rates and multiple fill withdrawal cycles in areas where salt cavern storage is not possible. In this research project, PB-KBB merged advanced mining technologies and gas refrigeration techniques to develop conceptual designs and cost estimates to demonstrate the commercialization potential of the storage of refrigerated natural gas in hard rock caverns. DOE has identified five regions, that have not had favorable geological conditions for underground storage development: New England, Mid-Atlantic (NY/NJ), South Atlantic (DL/MD/VA), South Atlantic (NC/SC/GA), and the Pacific Northwest (WA/OR). PB-KBB reviewed published literature and in-house databases of the geology of these regions to determine suitability of hard rock formations for siting storage caverns, and gas market area storage needs of these regions.

  19. Bone mineral density and blood metals in premenopausal women

    SciTech Connect (OSTI)

    Pollack, A.Z.; Mumford, S.L.; Wactawski-Wende, J.; Yeung, E.; Mendola, P.; Mattison, D.R.; Schisterman, E.F.


    Exposure to metals, specifically cadmium, lead, and mercury, is widespread and is associated with reduced bone mineral density (BMD) in older populations, but the associations among premenopausal women are unclear. Therefore, we evaluated the relationship between these metals in blood and BMD (whole body, total hip, lumbar spine, and non-dominant wrist) quantified by dual energy X-ray absorptiometry in 248 premenopausal women, aged 18-44. Participants were of normal body mass index (mean BMI 24.1), young (mean age 27.4), 60% were white, 20% non-Hispanic black, 15% Asian, and 6% other race group, and were from the Buffalo, New York region. The median (interquartile range) level of cadmium was 0.30 {mu}g/l (0.19-0.43), of lead was 0.86 {mu}g/dl (0.68-1.20), and of mercury was 1.10 {mu}g/l (0.58-2.00). BMD was treated both as a continuous variable in linear regression and dichotomized at the 10th percentile for logistic regression analyses. Mercury was associated with reduced odds of decreased lumbar spine BMD (0.66, 95% confidence interval: 0.44, 0.99), but overall, metals at environmentally relevant levels of exposure were not associated with reduced BMD in this population of healthy, reproductive-aged women. Further research is needed to determine if the blood levels of cadmium, lead, and mercury in this population are sufficiently low that there is no substantive impact on bone, or if effects on bone can be expected only at older ages.

  20. Intranuclear interactomic inhibition of NF-κB suppresses LPS-induced severe sepsis

    SciTech Connect (OSTI)

    Park, Sung-Dong; Cheon, So Yeong; Park, Tae-Yoon; Shin, Bo-Young; Oh, Hyunju; Ghosh, Sankar; Koo, Bon-Nyeo; Lee, Sang-Kyou


    Suppression of nuclear factor-κB (NF-κB) activation, which is best known as a major regulator of innate and adaptive immune responses, is a potent strategy for the treatment of endotoxic sepsis. To inhibit NF-κB functions, we designed the intra-nuclear transducible form of transcription modulation domain (TMD) of RelA (p65), called nt-p65-TMD, which can be delivered effectively into the nucleus without influencing the cell viability, and work as interactomic inhibitors via disruption of the endogenous p65-mediated transcription complex. nt-p65-TMD effectively inhibited the secretion of pro-inflammatory cytokines, including TNF-α, IL-1β, or IL-6 from BV2 microglia cells stimulated by lipopolysaccharide (LPS). nt-p65-TMD did not inhibit tyrosine phosphorylation of signaling mediators such as ZAP-70, p38, JNK, or ERK involved in T cell activation, but was capable of suppressing the transcriptional activity of NF-κB without the functional effect on that of NFAT upon T-cell receptor (TCR) stimulation. The transduced nt-p65-TMD in T cell did not affect the expression of CD69, however significantly inhibited the secretion of T cell-specific cytokines such as IL-2, IFN-γ, IL-4, IL-17A, or IL-10. Systemic administration of nt-p65-TMD showed a significant therapeutic effect on LPS-induced sepsis model by inhibiting pro-inflammatory cytokines secretion. Therefore, nt-p65-TMD can be a novel therapeutics for the treatment of various inflammatory diseases, including sepsis, where a transcription factor has a key role in pathogenesis, and further allows us to discover new functions of p65 under normal physiological condition without genetic alteration. - Highlights: • The nt-p65-TMD is intra-nuclear interactomic inhibitor of endogenous p65. • The nt-p65-TMD effectively inhibited the secretion of pro-inflammatory cytokines. • The excellent therapeutic potential of nt-p65-TMD was confirmed in sepsis model.


    SciTech Connect (OSTI)

    Mineo, S.; Rappaport, S.; Levine, A.; Homan, J.; Pooley, D.; Steinhorn, B. E-mail: E-mail: E-mail:


    We present a comprehensive study of the total X-ray emission from the colliding galaxy pair NGC2207/IC 2163, based on Chandra, Spitzer, and GALEX data. We detect 28 ultraluminous X-ray sources (ULXs), 7 of which were not detected previously because of X-ray variability. Twelve sources show significant long-term variability, with no correlated spectral changes. Seven sources are transient candidates. One ULX coincides with an extremely blue star cluster (BV = 0.7). We confirm that the global relation between the number and luminosity of ULXs and the integrated star-formation rate (SFR) of the host galaxy also holds on local scales. We investigate the effects of dust extinction and age on the X-ray binary (XRB) population on subgalactic scales. The distributions of N {sub X} and L {sub X} are peaked at L {sub IR}/L {sub NUV} ? 1, which may be associated with an age of ?10Myr for the underlying stellar population. We find that approximately one-third of the XRBs are located in close proximity to young star complexes. The luminosity function of the XRBs is consistent with that typical for high-mass XRBs and appears unaffected by variability. We disentangle and compare the X-ray diffuse spectrum with that of the bright XRBs. The hot interstellar medium dominates the diffuse X-ray emission at E ? 1keV and has a temperature kT=0.28{sub ?0.04}{sup +0.05}keV and intrinsic 0.5-2keV luminosity of 7.910{sup 40} erg s{sup ?1}, a factor of ?2.3 higher than the average thermal luminosity produced per unit SFR in local star-forming galaxies. The total X-ray output of NGC2207/IC 2163 is 1.510{sup 41} erg s{sup ?1}, and the corresponding total integrated SFR is 23.7 M {sub ?} yr{sup 1}.

  2. Carbon-14 immobilization via the Ba(OH)/sub 2/8H/sub 2/O process

    SciTech Connect (OSTI)

    Haag, G.L.; Nehls, J.W. Jr.; Young, G.C.


    The airborne release of /sup 14/C from various nuclear facilities has been identified as a potential biohazard due to the long half-life of /sup 14/C (5730 yrs) and the ease in which it may be assimilated into the biosphere. At Oak Ridge National Laboratory, technology is under development, as part of the Airborne Waste Management Program, for the removal and immobilization of this radionuclide. Prior studies have indicated that the /sup 14/C will likely exist in the oxidized form as CO/sub 2/ and will contribute slightly to the bulk CO/sub 2/ concentration of the gas stream, which is airlike in nature (approx. 330 ppMv CO/sub 2/). The technology under development utilizes the CO/sub 2/ - Ba(OH)/sub 2/ 8H/sub 2/O gas-solid reaction with the mode of gas-solid contacting being a fixed bed. The product, BaCO/sub 3/, possessing excellent thermal and chemical stability, prerequisites for the long-term disposal of nuclear wastes. For optimal process operation, studies have indicated that an operating window of adequate size does exist. When operating within the window, high CO/sub 2/ removal efficiency (effluent concentrations < 100 ppBv), high reactant utilization (> 99%), and an acceptable pressure drop across the bed (3 kPa/m at 13 cm/s superficial velocity) are possible. This paper will address three areas of experimental investigation. These areas are (1) micro-scale studies on 150-mg samples to provide information concerning surface properties, kinetics, and equilibrium vapor pressures, (2) macro-scale studies on large fixed beds (4.2 kg reactant) to determine the effects of humidity, temperature, and gas flow-rate upon bed pressure drop and CO/sub 2/ breakthrough, and (3) the design, construction, and initial operation of a pilot unit capable of continuously processing a 34 m/sup 3//h (20 ft/sup 3//min) air-based gas stream.

  3. AREVA NP next generation fresh UO{sub 2} fuel assembly shipping cask: SCALE - CRISTAL comparisons lead to safety criticality confidence

    SciTech Connect (OSTI)

    Doucet, M.; Landrieu, M.; Montgomery, R.; O' Donnell, B.


    AREVA NP as a worldwide PWR fuel provider has to have a fleet of fresh UO{sub 2} shipping casks being agreed within a lot of countries including USA, France, Germany, Belgium, Sweden, China, and South Africa - and to accommodate foreseen EPR Nuclear Power Plants fuel buildings. To reach this target the AREVA NP Fuel Sector decided to develop an up-to-date shipping cask (so called MAP project) gathering experience feedback of the today fleet and an improved safety allowing the design to comply with international regulations (NRC and IAEA) and local Safety Authorities. Based on pre design features a safety case was set up to highlight safety margins. Criticality hypothetical accidental assumptions were defined: - Preferential flooding; - Fuel rod lattice pitch expansion for full length of fuel assemblies; - Neutron absorber penalty; -... Well known computer codes, American SCALE package and French CRISTAL package, were used to check configurations reactivity and to ensure that both codes lead to coherent results. Basic spectral calculations are based on similar algorithms with specific microscopic cross sections ENDF/BV for SCALE and JEF2.2 for CRISTAL. The main differences between the two packages is on one hand SCALE's three dimensional fuel assembly geometry is described by a pin by pin model while an homogenized fuel assembly description is used by CRISTAL and on the other hand SCALE is working with either 44 or 238 neutron energy groups while CRISTAL is with a 172 neutron energy groups. Those two computer packages rely on a wide validation process helping defining uncertainties as required by regulations in force. The shipping cask with two fuel assemblies is designed to maximize fuel isolation inside a cask and with neighboring ones even for large array configuration cases. Proven industrial products are used: - Boral{sup TM} as neutron absorber; - High density polyethylene (HDPE) or Nylon as neutron moderator; - Foam as thermal and mechanical protection. The cask is designed to handle the complete AREVA NP fuel assembly types from the 14x14 to the 18x18 design with a {sup 235}U enrichment up to 5.0% enriched natural uranium (ENU) and enriched reprocessed uranium (ERU). After a brief presentation of the computer codes and the description of the shipping cask, calculation results and comparisons between SCALE and CRISTAL will be discussed. (authors)

  4. Federal Facility Agreement Annual Progress Report for Fiscal Year 1999 Oak Ridge, Tennessee

    SciTech Connect (OSTI)

    Bechtel Jacobs Company LLC


    The U.S. Department of Energy-Oak Ridge Operations (DOE-ORO) EM Program adopted a watershed approach for performing Remedial Investigations (RIs) and characterizations for ORR because it is an effective system for determining the best methods for protecting and restoring aquatic ecosystems and protecting human health. The basic concept is that water quality and ecosystem problems are best solved at the watershed level rather than at the individual water-body or discharger level. The watershed approach requires consideration of all environmental concerns, including needs to protect public health, critical habitats such as wetlands, biological integrity, and surface and ground waters. The watershed approach provides an improved basis for management decisions concerning contaminant sources and containment. It allows more direct focus by stakeholders on achieving ecological goals and water quality standards rather than a measurement of program activities based on numbers of permits or samples. The watershed approach allows better management strategies for investigations, therefore maximizing the utilization of scarce resources. Feasibility studies (FSs) evaluate various alternatives in terms of environmental standards, the protection of human health and the environment, and the costs of implementation to find the optimum solution among them. Society has to decide how much it is willing to spend to meet the standards and to be protective. Conducting FSs is the process of trading off those criteria to pick that optimum point that society wants to achieve. Performing this analysis at the watershed scale allows those trade-offs to be made meaningfully. In addition, a Land Use Control Assurance Plan for the ORR was prepared to identify the strategy for assuring the long-term effectiveness of land use controls. These land use controls will be relied upon to protect human health and the environment at areas of the ORR undergoing remediation pursuant to the Comprehensive Environmental Response, Compensation, and Liability Act and/or the Resource Conservation and Recovery Act. This plan will be implemented by means of a Memorandum of Understanding (MOU) incorporating its terms with the United States EPA and TDEC. The majority of projects described in this report are grouped into five watersheds. They are the East Tennessee Technical Park (ETTP) Watershed (formerly the K-25 Site), the Melton Valley (MV) and Bethel Valley (BV) Watersheds at the Oak Ridge National Laboratory (ORNL), and the Bear Creek Valley (BCV) and Upper East Fork Poplar Creek (UEFPC) Watersheds at the Y-12 Plant.

  5. Role of the nuclear xenobiotic receptors CAR and PXR in induction of cytochromes P450 by non-dioxinlike polychlorinated biphenyls in cultured rat hepatocytes

    SciTech Connect (OSTI)

    Gährs, Maike; Roos, Robert; Andersson, Patrik L.; Schrenk, Dieter


    Polychlorinated biphenyls (PCBs) are among the most ubiquitously detectable ‘persistent organic pollutants’. In contrast to ‘dioxinlike’ (DL) PCBs, less is known about the molecular mode of action of the larger group of the ‘non-dioxinlike’ (NDL) PCBs. Owing to the life-long exposure of the human population, a carcinogenic, i.e., tumor-promoting potency of NDL-PCBs has to be considered in human risk assessment. A major problem in risk assessment of NDL-PCBs is dioxin-like impurities that can occur in commercially available NDL-PCB standards. In the present study, we analyzed the induction of CYP2B1 and CYP3A1 in primary rat hepatocytes using a number of highly purified NDL-PCBs with various degrees of chlorination and substitution patterns. Induction of these enzymes is mediated by the nuclear xenobiotic receptors CAR (Constitutive androstane receptor) and PXR (Pregnane X receptor). For CYP2B1 induction, concentration–response analysis revealed a very narrow window of EC{sub 50} estimates, being in the range of 1–4 μM for PCBs 28 and 52, and between 0.4 and 1 μM for PCBs 101, 138, 153 and 180. CYP3A1 induction was less sensitive to NDL-PCBs, the most pronounced induction being achieved at 100 μM with the higher chlorinated congeners. Using okadaic acid and small interfering RNAs targeting CAR and PXR, we could demonstrate that CAR plays a major role and PXR a minor role in NDL-PCB-driven induction of CYPs, both effects showing no stringent structure–activity relationship. As the only obvious relevant determinant, the degree of chlorination was found to be positively correlated with the inducing potency of the congeners. - Highlights: • We analyzed six highly purified NDL-PCBs for CYP2B1 and CYP3A1 expression. • CAR plays a major, PXR a minor role in NDL-PCB-driven induction of CYPs. • The degree of chlorination seems to be the major parameter for the inducing potency. • There exists a competition between CAR and PXR. • Activated PXR may antagonize CAR binding to the CYP2B1 promoter.

  6. Investigation of nitrogen dilution effects on the laminar burning velocity and flame stability of syngas fuel at atmospheric condition

    SciTech Connect (OSTI)

    Prathap, C.; Ray, Anjan; Ravi, M.R. [Department of Mechanical Engineering, Indian Institute of Technology, Delhi, New Delhi 110016 (India)


    The objective of this investigation was to study the effect of dilution with nitrogen on the laminar burning velocity and flame stability of syngas fuel (50% H{sub 2}-50% CO by volume)-air (21% O{sub 2}-79% N{sub 2} by volume) mixtures. The syngas fuel composition considered in this work comprised x% N{sub 2} by volume and (100-x)% an equimolar mixture of CO and H{sub 2}. The proportion x (i.e., %N{sub 2}) was varied from 0 to 60% while the H{sub 2}/CO ratio was always kept as unity. Spherically expanding flames were generated by centrally igniting homogeneous fuel-air gas mixtures in a 40-L cylindrical combustion chamber fitted with optical windows. Shadowgraphy technique with a high-speed imaging camera was used to record the propagating spherical flames. Unstretched burning velocity was calculated following the Karlovitz theory for weakly stretched flames. Also, Markstein length was calculated to investigate the flame stability conditions for the fuel-air mixtures under consideration. Experiments were conducted for syngas fuel with different nitrogen proportions (0-60%) at 0.1 MPa (absolute), 302{+-}3K, and equivalence ratios ranging from 0.6 to 3.5. All the measurements were compared with the numerical predictions obtained using RUN-1DL and PREMIX with a contemporary chemical kinetic scheme. Dilution with nitrogen in different proportions in syngas resulted in (a) decrease in laminar burning velocity due to reduction in heat release and increase in heat capacity of unburned gas mixture and hence the flame temperature, (b) shift in occurrence of peak laminar burning velocity from {phi}=2.0 for 0% N{sub 2} dilution to {phi}=1.4 for 60% N{sub 2} dilution, (c) augmentation of the coupled effect of flame stretch and preferential diffusion on laminar burning velocity, and (d) shift in the equivalence ratio for transition from stable to unstable flames from {phi}=0.6 for 0% N{sub 2} dilution to {phi}=1.0 for 60% N{sub 2} dilution. The present work also indicated that if the fuel mole fraction in the wide range of fuel-air mixtures investigated is less than 22%, then those fuel mixtures are in the unstable regime with regard to preferential diffusion. (author)

  7. Delta-aminolevulinic acid dehydratase (ALAD) polymorphism in lead exposed Bangladeshi children and its effect on urinary aminolevulinic acid (ALA)

    SciTech Connect (OSTI)

    Tasmin, Saira; Furusawa, Hana; Ahmad, Sk. Akhtar; Watanabe, Chiho


    Background and objective: Lead has long been recognized as a harmful environmental pollutant. People in developing countries like Bangladesh still have a higher risk of lead exposure. Previous research has suggested that the delta-aminolevulinic acid dehydratase (ALAD) genotype can modify lead toxicity and individual susceptibility. As children are more susceptible to lead-induced toxicity, this study investigated whether the ALAD genotype influenced urinary excretion of delta-aminolevulinic acid (U-ALA) among children exposed to environmental lead in Bangladesh. Methods: Subjects were elementary schoolchildren from a semi-urban industrialized area in Bangladesh. A total of 222 children were studied. Blood and urine were collected to determine ALAD genotypes, blood lead levels and urinary aminolevulinic acid (U-ALA). Results: The mean BPb level was 9.7 µg/dl for the study children. BPb was significantly positively correlated with hemoglobin (p<0.01). In total, allele frequency for ALAD 1 and 2 was 0.83 and 0.17 respectively. The mean U-ALA concentration was lower in ALAD1-2/2-2 carriers than ALAD1-1 carriers for boys (p=0.001). But for girls, U-ALA did not differ significantly by genotype (p=0.26). When U-ALA was compared by genotype at the same exposure level in a multiple linear regression analysis, boys who were ALAD1-2/2-2 carriers still had a lower level of U-ALA compared to ALAD1-1carriers. Conclusion: This study provides information about the influence of ALAD polymorphism and its association with U-ALA in Bangladeshi children. Our results indicate that the ALAD1-2/2-2 genotype may have a protective effect in terms of U-ALA for environmentally lead exposed boys. - Highlights: • High blood lead level for the environmentally exposed schoolchildren. • BPb was significantly correlated with U-ALA and Hb. • Effect of ALAD genotype on U-ALA is differed by sex. • Lower U-ALA in ALAD2 than ALAD1 carriers only for boys at same exposure.

  8. Telomere length in children environmentally exposed to low-to-moderate levels of lead

    SciTech Connect (OSTI)

    Pawlas, Natalia; Płachetka, Anna; Kozłowska, Agnieszka; Broberg, Karin; Kasperczyk, Sławomir


    Shorter relative telomere length in peripheral blood is a risk marker for some types of cancers and cardiovascular diseases. Several environmental hazards appear to shorten telomeres, and this shortening may predispose individuals to disease. The aim of the present cross-sectional study was to assess the effect of environmental exposure to lead on relative telomere length (rTL) in children. A cohort of 99 8-year-old children was enrolled from 2007–2010. Blood lead concentrations (B-Pb) were measured by graphite furnace atomic absorption spectrometry, and blood rTL was measured by quantitative PCR. The geometric mean of B-Pb was 3.28 μg/dl (range: 0.90–14.2), and the geometric mean of rTL was 1.08 (range: 0.49–2.09). B-Pb was significantly inversely associated with rTL in the children (r{sub S} = − 0.25, p = 0.013; in further analyses both log-transformed-univariate regression analysis β = − 0.13, p = 0.026, and R{sup 2}adj 4%; and β = − 0.12, p = 0.056 when adjusting for mothers' smoking during pregnancy, Apgar score, mother's and father's ages at delivery, sex and mother's education, R{sup 2}adj 12%, p = 0.011). The effect of lead remained significant in children without prenatal tobacco exposure (N = 87, r{sub S} = − 0.24, p = 0.024; in further analyses, β = − 0.13, p = 0.029, and R{sup 2}adj 4%). rTL was not affected by sex, the concentrations of other elements in the blood (i.e., cadmium and selenium concentrations), or oxidative injury parameters (total antioxidant status, 8-hydroxydeoxyguanosine and thiobarbituric acid-reactive substances). Lead exposure in childhood appears to be associated with shorter telomeres, which might contribute to diseases, such as cardiovascular disease. The inverse association between blood lead level and the telomeres in children emphasizes the importance of further reducing lead levels in the environment. - Highlights: • This cross-sectional study analyzes the association between environmental lead exposure and telomere length in children. • Blood lead concentrations were inversely associated with relative telomere length in 8-year-old children. • Environmental lead exposure during childhood might contribute to telomere shortening, and in turn, future risk for disease.

  9. Insights into substrate specificity of NlpC/P60 cell wall hydrolases containing bacterial SH3 domains

    SciTech Connect (OSTI)

    Xu, Qingping; Mengin-Lecreulx, Dominique; Liu, Xueqian W.; Patin, Delphine; Farr, Carol L.; Grant, Joanna C.; Chiu, Hsiu -Ju; Jaroszewski, Lukasz; Knuth, Mark W.; Godzik, Adam; Lesley, Scott A.; Elsliger, Marc -André; Deacon, Ashley M.; Wilson, Ian A.


    Bacterial SH3 (SH3b) domains are commonly fused with papain-like Nlp/P60 cell wall hydrolase domains. To understand how the modular architecture of SH3b and NlpC/P60 affects the activity of the catalytic domain, three putative NlpC/P60 cell wall hydrolases were biochemically and structurally characterized. In addition, these enzymes all have γ-d-Glu-A2pm (A2pm is diaminopimelic acid) cysteine amidase (ordl-endopeptidase) activities but with different substrate specificities. One enzyme is a cell wall lysin that cleaves peptidoglycan (PG), while the other two are cell wall recycling enzymes that only cleave stem peptides with an N-terminall-Ala. Their crystal structures revealed a highly conserved structure consisting of two SH3b domains and a C-terminal NlpC/P60 catalytic domain, despite very low sequence identity. Interestingly, loops from the first SH3b domain dock into the ends of the active site groove of the catalytic domain, remodel the substrate binding site, and modulate substrate specificity. Two amino acid differences at the domain interface alter the substrate binding specificity in favor of stem peptides in recycling enzymes, whereas the SH3b domain may extend the peptidoglycan binding surface in the cell wall lysins. Remarkably, the cell wall lysin can be converted into a recycling enzyme with a single mutation.

    Peptidoglycan is a meshlike polymer that envelops the bacterial plasma membrane and bestows structural integrity. Cell wall lysins and recycling enzymes are part of a set of lytic enzymes that target covalent bonds connecting the amino acid and amino sugar building blocks of the PG network. These hydrolases are involved in processes such as cell growth and division, autolysis, invasion, and PG turnover and recycling. To avoid cleavage of unintended substrates, these enzymes have very selective substrate specificities. Our biochemical and structural analysis of three modular NlpC/P60 hydrolases, one lysin, and two recycling enzymes, show that they may have evolved from a common molecular architecture, where the substrate preference is modulated by local changes. These results also suggest that new pathways for recycling PG turnover products, such as tracheal cytotoxin, may have evolved in bacteria in the human gut microbiome that involve NlpC/P60 cell wall hydrolases.

  10. Three-Dimensional Integration Technology for Advanced Focal Planes and Integrated Circuits

    SciTech Connect (OSTI)

    Keast, Craig


    Over the last five years MIT Lincoln Laboratory (MIT-LL) has developed a three-dimensional (3D) circuit integration technology that exploits the advantages of silicon-on-insulator (SOI) technology to enable wafer-level stacking and micrometer-scale electrical interconnection of fully fabricated circuit wafers. Advanced focal plane arrays have been the first applications to exploit the benefits of this 3D integration technology because the massively parallel information flow present in 2D imaging arrays maps very nicely into a 3D computational structure as information flows from circuit-tier to circuit-tier in the z-direction. To date, the MIT-LL 3D integration technology has been used to fabricate four different focal planes including: a 2-tier 64 x 64 imager with fully parallel per-pixel A/D conversion; a 3-tier 640 x 480 imager consisting of an imaging tier, an A/D conversion tier, and a digital signal processing tier; a 2-tier 1024 x 1024 pixel, 4-side-abutable imaging modules for tiling large mosaic focal planes, and a 3-tier Geiger-mode avalanche photodiode (APD) 3-D LIDAR array, using a 30 volt APD tier, a 3.3 volt CMOS tier, and a 1.5 volt CMOS tier. Recently, the 3D integration technology has been made available to the circuit design research community through DARPA-sponsored Multiproject fabrication runs. The first Multiproject Run (3DL1) completed fabrication in early 2006 and included over 30 different circuit designs from 21 different research groups. 3D circuit concepts explored in this run included stacked memories, field programmable gate arrays (FPGAs), and mixed-signal circuits. The second Multiproject Run (3DM2) is currently in fabrication and includes particle detector readouts designed by Fermilab. This talk will provide a brief overview of MIT-LL's 3D-integration process, discuss some of the focal plane applications where the technology is being applied, and provide a summary of some of the Multiproject Run circuit results.

  11. Syngas Conversion to Hydrocarbon Fuels through Mixed Alcohol Intermediates

    SciTech Connect (OSTI)

    Dagle, Robert A.; Lebarbier, Vanessa M.; Albrecht, Karl O.; Li, Jinjing; Taylor, Charles E.; Bao, Xinhe; Wang, Yong


    Synthesis gas (syngas) can be used to synthesize a variety of fuels and chemicals. Domestic transportation and military operational interests have driven continued focus on domestic syngas-based fuels production. Liquid transportation fuels may be made from syngas via four basic processes: 1) higher alcohols, 2) Fischer-Tropsch (FT), 3) methanol-to-gasoline (MTG), and 4) methanol-to-olefins (MTO) and olefins-to-gasoline/distillate (MOGD). Compared to FT and higher alcohols, MTG and MTO-MOGD have received less attention in recent years. Due to the high capital cost of these synthetic fuel plants, the production cost of the finished fuel cannot compete with petroleum-derived fuel. Pacific Northwest National Laboratory has recently evaluated one way to potentially reduce capital cost and overall production cost for MTG by combining the methanol and MTG syntheses in a single reactor. The concept consists of mixing the conventional MTG catalyst (i.e. HZSM-5) with an alcohol synthesis catalyst. It was found that a methanol synthesis catalyst, stable at high temperature (i.e. Pd/ZnO/Al2O3) [1], when mixed with ZSM-5, was active for syngas conversion. Relatively high syngas conversion can be achieved as the equilibrium-driven conversion limitations for methanol and dimethyl ether are removed as they are intermediates to the final hydrocarbon product. However, selectivity control was difficult to achieve as formation of undesirable durene and light hydrocarbons was problematic [2]. The objective of the present study was thus to evaluate other potential composite catalyst systems and optimize the reactions conditions for the conversion of syngas to hydrocarbon fuels, through the use of mixed alcohol intermediates. Mixed alcohols are of interest as they have recently been reported to produce higher yields of gasoline compared to methanol [3]. 1. Lebarbier, V.M., Dagle, R.A., Kovarik, L., Lizarazo-Adarme, J.A., King, D.L., Palo, D.R., Catalyst Science & Technology, 2012, 2, 2116-2127. 2. Zhu, Y., Jones, S.B., Biddy, M.J., Dagle, R.A., Palo, D.P., Bioresource Technology, 2012, 117, 341-351. 3. Gujar, A.C., Guda, V.K., Nolan, M., Yan W., Toghiani, H., White, M.G., Applied Catalysis A: General, 2009, 363, 115-121.


    SciTech Connect (OSTI)

    Nestor, Daniel B.; Shapley, Alice E.; Steidel, Charles C.; Siana, Brian


    We present the results of an ultradeep, narrowband imaging survey for Lyman-continuum (LyC) emission at z {approx} 3 in the SSA22a field. We employ a custom narrowband filter centered at {lambda} = 3640 A (NB3640), which probes the LyC region for galaxies at z {>=} 3.06. We also analyze new and archival NB4980 imaging tuned to the wavelength of the Ly{alpha} emission line at z = 3.09, and archival broadband B, V, and R images of the non-ionizing UV continuum. Our NB3640 images contain 26 z {>=} 3.06 Lyman break galaxies (LBGs) as well as a set of 130 Ly{alpha} emitters (LAEs), identified by their excess NB4980 flux relative to the BV continuum. Six LBGs and 28 LAEs are detected in the NB3640 image. LBGs appear to span a range of NB3640-R colors, while LAEs appear bimodal in their NB3640-R properties. We estimate average UV-to-LyC flux density ratios, corrected for foreground contamination and intergalactic medium absorption, finding (F{sub UV}/F{sub LyC}){sup LBG}{sub corr} = 11.3{sup +10.3}{sub -5.4}, which implies an LBG LyC escape fraction f{sup LyC}{sub esc} {approx} 0.1, and (F{sub UV}/F{sub LyC}){sup LAE}{sub corr} = 2.2{sup +0.9}{sub -0.6}. The strikingly blue LAE flux density ratios defy interpretation in terms of standard stellar population models. Assuming (F{sub UV}/F{sub LyC}){sup LBG}{sub corr} applies down to L = 0.1L*, we estimate a galaxy contribution to the intergalactic hydrogen ionization rate that is consistent with independent estimates based on the Ly{alpha} forest opacity at z {approx_equal} 3. If we assume that (F{sub UV}/F{sub LyC}){sup LAE}{sub corr} holds at the faintest luminosities, the galaxy contribution significantly exceeds that inferred from the Ly{alpha} forest. We interpret our results in terms of a model where LyC photons escape over only {approx}10%-20% of solid angle. When advantageously oriented, a galaxy will exhibit a low UV-to-LyC ratio, an effect enhanced for more compact galaxies. This model, however, does not adequately explain the extremely blue NB3640-R colors measured for some LAEs in our sample. Further follow-up study of these faint LAEs is crucial, given the potentially important contribution similar objects make to the process of reionization.

  13. Characterization and use of a 2D-array of ion chambers for brachytherapy dosimetric quality assurance

    SciTech Connect (OSTI)

    Yewondwossen, Mammo


    The two-dimensional (2D) ionization chamber array MatriXX Evolution is one of the 2D ionization chamber arrays developed by IBA Dosimetry (IBA Dosimetry, Germany) for megavoltage real-time absolute 2D dosimetry and verification of intensity-modulated radiation therapy (IMRT). The purpose of this study was to (1) evaluate the performance of ion chamber array for submegavoltage range brachytherapy beam dose verification and quality assurance (QA) and (2) use the end-to-end dosimetric evaluation that mimics a patient treatment procedure and confirm the primary source strength calibration agrees in both the treatment planning system (TPS) and treatment delivery console computers. The dose linearity and energy dependence of the 2D ion chamber array was studied using kilovoltage X-ray beams (100, 180 and 300 kVp). The detector calibration factor was determined using 300 kVp X-ray beams so that we can use the same calibration factor for dosimetric verification of high-dose-rate (HDR) brachytherapy. The phantom used for this measurement consists of multiple catheters, the IBA MatriXX detector, and water-equivalent slab of RW3 to provide full scattering conditions. The treatment planning system (TPS) (Oncentra brachy version 3.3, Nucletron BV, Veenendaal, the Netherlands) dose distribution was calculated on the computed tomography (CT) scan of this phantom. The measured and TPS calculated distributions were compared in IBA Dosimetry OmniPro-I'mRT software. The quality of agreement was quantified by the gamma ({gamma}) index (with 3% delta dose and distance criterion of 2 mm) for 9 sets of plans. Using a dedicated phantom capable of receiving 5 brachytherapy intralumenal catheters a QA procedure was developed for end-to-end dosimetric evaluation for routine QA checks. The 2D ion chamber array dose dependence was found to be linear for 100-300 kVp and the detector response (k{sub user}) showed strong energy dependence for 100-300 kVp energy range. For the Ir-192 brachytherapy HDR source, dosimetric evaluation k{sub user} factor determined by photon beam of energy of 300 kVp was used. The maximum mean difference between ion chamber array measured and TPS calculated was 3.7%. Comparisons of dose distribution for different test plans have shown agreement with >94.5% for {gamma} {<=}1. Dosimetric QA can be performed with the 2D ion chamber array to confirm primary source strength calibration is properly updated in both the TPS and treatment delivery console computers. The MatriXX Evolution ionization chamber array has been found to be reliable for measurement of both absolute dose and relative dose distributions for the Ir-192 brachytherapy HDR source.