National Library of Energy BETA

Sample records for butyl ether plants

  1. Control Study of Ethyl tert-Butyl Ether Reactive Distillation Muhammad A. Al-Arfaj

    E-Print Network [OSTI]

    Al-Arfaj, Muhammad A.

    -butyl ether (ETBE) for gasoline blending as a replacement for methyl tert-butyl ether (MTBE) because and be blended with ETBE in the gasoline pool. Even for neat operation, if the conversion is low, the unconverted

  2. State Restrictions on Methyl Tertiary Butyl Ether (released in AEO2006)

    Reports and Publications (EIA)

    2006-01-01

    By the end of 2005, 25 states had barred, or passed laws banning, any more than trace levels of methyl tertiary butyl ether (MTBE) in their gasoline supplies, and legislation to ban MTBE was pending in 4 others. Some state laws address only MTBE; others also address ethers such as ethyl tertiary butyl ether (ETBE) and tertiary amyl methyl ether (TAME). Annual Energy Outlook 2006 assumes that all state MTBE bans prohibit the use of all ethers for gasoline blending.

  3. Accurate Computer Simulation of Phase Equilibrium for Complex Fluid Mixtures. Application to Binaries Involving Isobutene, Methanol, Methyl tert-Butyl Ether, and

    E-Print Network [OSTI]

    Lisal, Martin

    to Binaries Involving Isobutene, Methanol, Methyl tert-Butyl Ether, and n-Butane Martin Li´sal,*,, William R + methyl tert-butyl ether (MTBE) and the binaries formed by methanol with isobutene, MTBE, and n

  4. IDENTIFYING THE USAGE PATTERNS OF METHYL TERT-BUTYL ETHER (MTBE) AND OTHER OXYGENATES IN GASOLINE USING GASOLINE

    E-Print Network [OSTI]

    IDENTIFYING THE USAGE PATTERNS OF METHYL TERT-BUTYL ETHER (MTBE) AND OTHER OXYGENATES IN GASOLINE USING GASOLINE SURVEYS By Michael J. Moran, Rick M. Clawges, and John S. Zogorski U.S. Geological Survey 1608 Mt. View Rapid City, SD 57702 Methyl tert-butyl ether (MTBE) is commonly added to gasoline

  5. Whole-Genome Analysis of Methyl tert-Butyl Ether-Degrading Beta-Proteobacterium Methylibium petroleiphilum PM1

    E-Print Network [OSTI]

    2007-01-01

    Sato, and N. Kato. 2003. Propane monooxygenase and NAD + -alcohol dehydrogenase in propane metabolism by Gordonia sp.tert-butyl ether by propane-grown Mycobacterium vaccae JOB5.

  6. Methyl tert-butyl ether and ethyl tert-butyl ether: A comparison of properties, synthesis techniques, and operating conditions

    SciTech Connect (OSTI)

    Sneesby, M.G.; Tade, M.O.; Datta, R.

    1996-12-31

    MTBE is currently the most industrially significant oxygenate but some of the properties of ETBE and the EPA ethanol mandate suggest that ETBE could become a viable competitor. Similar synthesis techniques are used for both ethers but the phase behaviour of the ETBE system requires slightly different operating conditions and creates some alternatives for product recovery. The process control strategy for both systems must address some unusual challenges. 9 refs., 1 tab.

  7. Ethyl-tertiary-butyl-ether (ETBE) as an aviation fuel: Eleventh international symposium on alcohol fuels

    SciTech Connect (OSTI)

    Maben, G.D.; Shauck, M.E.; Zanin, M.G.

    1996-12-31

    This paper discusses the preliminary flight testing of an aircraft using neat burning ethyl-tertiary-butyl-ether (ETBE) as a fuel. No additional changes were made to the fuel delivery systems which had previously been modified to provide the higher fuel flow rates required to operate the engine on neat ethanol. Air-fuel ratios were manually adjusted with the mixture control. This system allows the pilot to adjust the mixture to compensate for changes in air density caused by altitude, pressure and temperature. The engine was instrumented to measure exhaust gas temperatures (EGT), cylinder head temperatures (CHT), and fuel flows, while the standard aircraft instruments were used to collect aircraft performance data. Baseline engine data for ETBE and Avgas are compared. Preliminary data indicates the technical and economic feasibility of using ETBE as an aviation fuel for the piston engine fleet. Furthermore, the energy density of ETBE qualifies it as a candidate for a turbine engine fuel of which 16.2 billion gallons are used in the US each year.

  8. Methyl tert-butyl ether (MTBE) is a volatile organic com-pound (VOC) derived from natural gas that is added to gas-

    E-Print Network [OSTI]

    Methyl tert-butyl ether (MTBE) is a volatile organic com- pound (VOC) derived from natural gas Water in Urban and Agricultural Areas made from methanol, which is derived primarily from natural gas that is added to gas- oline either seasonally or year round in many parts of the United States to increase

  9. Manipulation of the HIF–Vegf pathway rescues methyl tert-butyl ether (MTBE)-induced vascular lesions

    SciTech Connect (OSTI)

    Bonventre, Josephine A., E-mail: josephine.bonventre@oregonstate.edu [Rutgers, The State University of New Jersey, Joint Graduate Program in Toxicology, 170 Frelinghuysen Road, Piscataway, NJ 08854 (United States); Rutgers, The State University of New Jersey, Department of Biochemistry and Microbiology, 76 Lipman Dr., New Brunswick, NJ 08901 (United States); Oregon State University, Department of Environmental and Molecular Toxicology, 1011 Agricultural and Life Sciences Bldg, Corvallis, OR 97331 (United States); Kung, Tiffany S., E-mail: tiffany.kung@rutgers.edu [Rutgers, The State University of New Jersey, Joint Graduate Program in Toxicology, 170 Frelinghuysen Road, Piscataway, NJ 08854 (United States); Rutgers, The State University of New Jersey, Department of Biochemistry and Microbiology, 76 Lipman Dr., New Brunswick, NJ 08901 (United States); White, Lori A., E-mail: lawhite@aesop.rutgers.edu [Rutgers, The State University of New Jersey, Joint Graduate Program in Toxicology, 170 Frelinghuysen Road, Piscataway, NJ 08854 (United States); Rutgers, The State University of New Jersey, Department of Biochemistry and Microbiology, 76 Lipman Dr., New Brunswick, NJ 08901 (United States); Cooper, Keith R., E-mail: cooper@aesop.rutgers.edu [Rutgers, The State University of New Jersey, Joint Graduate Program in Toxicology, 170 Frelinghuysen Road, Piscataway, NJ 08854 (United States); Rutgers, The State University of New Jersey, Department of Biochemistry and Microbiology, 76 Lipman Dr., New Brunswick, NJ 08901 (United States)

    2013-12-15

    Methyl tert-butyl ether (MTBE) has been shown to be specifically anti-angiogenic in piscine and mammalian model systems at concentrations that appear non-toxic in other organ systems. The mechanism by which MTBE targets developing vascular structures is unknown. A global transcriptome analysis of zebrafish embryos developmentally exposed to 0.00625–5 mM MTBE suggested that hypoxia inducible factor (HIF)-regulated pathways were affected. HIF-driven angiogenesis via vascular endothelial growth factor (vegf) is essential to the developing vasculature of an embryo. Three rescue studies were designed to rescue MTBE-induced vascular lesions: pooled blood in the common cardinal vein (CCV), cranial hemorrhages (CH), and abnormal intersegmental vessels (ISV), and test the hypothesis that MTBE toxicity was HIF–Vegf dependent. First, zebrafish vegf-a over-expression via plasmid injection, resulted in significantly fewer CH and ISV lesions, 46 and 35% respectively, in embryos exposed to 10 mM MTBE. Then HIF degradation was inhibited in two ways. Chemical rescue by N-oxaloylglycine significantly reduced CCV and CH lesions by 30 and 32% in 10 mM exposed embryos, and ISV lesions were reduced 24% in 5 mM exposed zebrafish. Finally, a morpholino designed to knock-down ubiquitin associated von Hippel–Lindau protein, significantly reduced CCV lesions by 35% in 10 mM exposed embryos. In addition, expression of some angiogenesis related genes altered by MTBE exposure were rescued. These studies demonstrated that MTBE vascular toxicity is mediated by a down regulation of HIF–Vegf driven angiogenesis. The selective toxicity of MTBE toward developing vasculature makes it a potentially useful chemical in the designing of new drugs or in elucidating roles for specific angiogenic proteins in future studies of vascular development. - Highlights: • Global gene expression of MTBE exposed zebrafish suggested altered HIF1 signaling. • Over expression of zebrafish vegf-a rescues MTBE-induced vascular lesions. • Inhibiting PHD or knocking down VHL rescues MTBE-induced vascular lesions. • HIF1-Vegf driven angiogenesis is a target for MTBE vascular toxicity.

  10. Divinyl ether synthase gene and protein, and uses thereof

    DOE Patents [OSTI]

    Howe, Gregg A. (East Lansing, MI); Itoh, Aya (Tsuruoka, JP)

    2011-09-13

    The present invention relates to divinyl ether synthase genes, proteins, and methods of their use. The present invention encompasses both native and recombinant wild-type forms of the synthase, as well as mutants and variant forms, some of which possess altered characteristics relative to the wild-type synthase. The present invention also relates to methods of using divinyl ether synthase genes and proteins, including in their expression in transgenic organisms and in the production of divinyl ether fatty acids, and to methods of suing divinyl ether fatty acids, including in the protection of plants from pathogens.

  11. Crown ethers in graphene

    SciTech Connect (OSTI)

    Guo, Junjie; Lee, Jaekwang; Contescu, Cristian I; Gallego, Nidia C; Pantelides, Sokrates T.; Pennycook, Stephen J; Moyer, Bruce A; Chisholm, Matthew F

    2014-01-01

    Crown ethers, introduced by Pedersen1, are at their most basic level neutral rings constructed of oxygen atoms linked by two- or three-carbon chains. They have attracted special attention for their ability to selectively incorporate various atoms2 or molecules within the cavity formed by the ring3-6. This property has led to the use of crown ethers and their compounds in a wide range of chemical and biological applications7,8. However, crown ethers are typically highly flexible, frustrating efforts to rigidify them for many uses that demand higher binding affinity and selectivity9,10. In this Letter, we report atomic-resolution images of the same basic structures of the original crown ethers embedded in graphene. This arrangement constrains the crown ethers to be rigid and planar and thus uniquely suited for the many applications that crown ethers are known for. First-principles calculations show that the close similarity of the structures seen in graphene with those of crown ether molecules also extends to their selectivity towards specific metal cations depending on the ring size. Atoms (or molecules) incorporated within the crown ethers in graphene offer a simple environment that can be easily and systematically probed and modeled. Thus, we expect that this discovery will introduce a new wave of investigations and applications of chemically functionalized graphene.

  12. Propenyl ether monomers for photopolymerization

    DOE Patents [OSTI]

    Crivello, J.V.

    1996-10-22

    Propenyl ether monomers of formula A(OCH{double_bond}CHCH{sub 3}){sub n} wherein n is an integer from one to six and A is selected from cyclic ethers, polyether and alkanes are disclosed. The monomers are readily polymerized in the presence of cationic photoinitiators, when exposed to actinic radiation, to form poly(propenyl ethers) that are useful for coatings, sealants, varnishes and adhesives. Compositions for preparing polymeric coatings comprising the compounds of the above formula together with particular cationic photoinitiators are also disclosed, as are processes for making the monomers from allyl halides and readily available alcohols. The process involves rearranging the resulting allyl ethers to propenyl ethers.

  13. amine methanol, ether . Amine amine CO2

    E-Print Network [OSTI]

    Hong, Deog Ki

    IP [2012] 7 C O 2 (CO2) . CO2 amine methanol, ether . Amine amine CO2 CO2 .Amine CO2 (functional group) amine amine+ +promoter .Amine CO2 CO2 . . , methanol ether methanol, ether promoter CO2 CO2 H2S, COS CO2 . Methanol rectisol process, di-methylene ether polypropylene glycol selexol (-30oC) . CO2

  14. Treatment of Methyl tert-Butyl Ether Contaminated Water Using a Dense

    E-Print Network [OSTI]

    Dandy, David

    -massspectrometryandgaschromatography-thermal conductivity techniques. A rate law is developed for the removal of MTBE from an aqueous solution in the DMP of water in which alkyl groups have replaced both hydrogen atoms. In fact, the C-O-C bond angle is only, causing nationwide concern. Advanced oxidation technologies (AOTs) are techniques that involve an input

  15. Treatment of Methyl tert-Butyl Ether Vapors in Biotrickling Filters. 1.

    E-Print Network [OSTI]

    byproducts in either the gas or the liquid phase. They also exhibited a very high specific degradation and leaking pipe- lines. In the past few years, several studies have been conducted to determine if natural, ethyl benzene, and xylene (BTEX) plumes, with in most cases no clear signs of natural attenuation (2

  16. Use of ethyl-t-butyl ether (ETBE) as a gasoline blending component

    SciTech Connect (OSTI)

    Shiblom, C.M.; Schoonveld, G.A.; Riley, R.K.; Pahl, R.H.

    1990-01-01

    The U.S. Treasury Department recently ruled that the ethanol blenders tax credit applies to ethanol used to make ETBE for blending with gasoline. As a result, ETBE may soon become a popular gasoline blending component. Like MTBE ETBE adds oxygen to the fuel while contributing to other performance properties of the gasoline. Phillips Petroleum Company has completed limited driveability and material compatibility studies on gasolines containing ETBE and has determined the effect on various performance parameters such as octane, volatility, and distillation of ETBE in gasoline. Levels of ETBE ranging from 0.0 to 23.5 volume percent (3.7 weight percent oxygen) in gasoline were included in the investigation. Use in gasoline is currently limited to only 12.7 volume percent (2.0 weight percent oxygen) by the gasoline substantially similar rule. No detrimental effects of the ETBE on metal or elastomeric parts common to gasoline delivery and fueling system were found. Also, several favorable blending properties of eTBE in gasoline are apparent as compared to either MTBE or ethanol. This paper presents details of these results.

  17. Aza crown ether compounds as anion receptors

    DOE Patents [OSTI]

    Lee, H.S.; Yang, X.O.; McBreen, J.

    1998-08-04

    A family of aza-ether based compounds including linear, multi-branched and aza-crown ethers is provided. When added to non-aqueous battery electrolytes, the new family of aza-ether based compounds acts as neutral receptors to complex the anion moiety of the electrolyte salt thereby increasing the conductivity and the transference number of LI{sup +} ion in alkali metal batteries. 3 figs.

  18. Hydroxylated and Methoxylated Polybrominated Diphenyl Ethers in a

    E-Print Network [OSTI]

    Gobas, Frank

    Research Hydroxylated and Methoxylated Polybrominated Diphenyl Ethers in a Canadian Arctic Marine of hydroxylated (OH-) and methoxylated (MeO-) polybrominated diphenyl ethers (PBDEs) have been previously detected

  19. Alternative Fuels lDimethyl Ether Rheology and Materials Studies...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuels lDimethyl Ether Rheology and Materials Studies Alternative Fuels lDimethyl Ether Rheology and Materials Studies 2004 Diesel Engine Emissions Reduction (DEER) Conference...

  20. Impacts of Ethanol on Anaerobic Production of Tert-Butyl Alcohol (TBA) from Methyl Tert-Butyl Ether (MTBE) in Groundwater

    E-Print Network [OSTI]

    Scow, K M; MacKay, Douglas

    2008-01-01

    Project title: Impacts of Ethanol on Anaerobic Production oftert-butanol (TBA). As ethanol is being promoted as ainvestigate the effect of ethanol release on existing MTBE

  1. Dimethyl ether fuel proposed as an alternative to LNG

    SciTech Connect (OSTI)

    Kikkawa, Yoshitsugi; Aoki, Ichizo

    1998-04-06

    To cope with the emerging energy demand in Asia, alternative fuels to LNG must be considered. Alternative measures, which convert the natural gas to liquid fuel, include the Fischer-Tropsch conversion, methanol synthesis, and dimethyl ether (DME) synthesis. Comparisons are evaluated based on both transportation cost and feed-gas cost. The analysis will show that DME, one alternative to LNG as transportation fuel, will be more economical for longer distances between the natural-gas source and the consumer. LNG requires a costly tanker and receiving terminal. The break-even distance will be around 5,000--7,000 km and vary depending on the transported volume. There will be risk, however, since there has never been a DME plant the size of an LNG-equivalent plant [6 million metric tons/year (mty)].

  2. Whole-Genome Analysis of Methyl tert-Butyl Ether-Degrading Beta-Proteobacterium Methylibium petroleiphilum PM1

    E-Print Network [OSTI]

    2007-01-01

    degradation pathways. PM1 contains an operon (mpeA0814-0821) likely encoding for conversion of benzene to phenol (

  3. HORTSCIENCE 44(3):770773. 2009. Petroleum Ether Separation

    E-Print Network [OSTI]

    Etxeberria, Edgardo

    HORTSCIENCE 44(3):770­773. 2009. Petroleum Ether Separation and Seedcoat Removal Enhance Seed studied. Petroleum ether separation improved germination by dividing seeds into floaters and sinkers sinkers except for one source of C. cunninghamiana. In sorted hybrid seeds, petroleum ether separation

  4. Maternal Anesthesia via Isoflurane or Ether Differentially

    E-Print Network [OSTI]

    Maternal Anesthesia via Isoflurane or Ether Differentially Affects Pre-and Postnatal Behavior Program in Occupational Therapy Washington University School of Medicine St. Louis, MO 63108 Jeffrey R: Our understanding of prenatal behavior has been significantly advanced by techniques for direct

  5. Process for making propenyl ethers and photopolymerizable compositions containing them

    DOE Patents [OSTI]

    Crivello, J.V.

    1996-01-23

    Propenyl ether monomers of formula A(OCH{double_bond}CHCH{sub 3}){sub n} (V) wherein n is an integer from one to six and A is selected from cyclic ethers, polyether, and alkanes are disclosed. The monomers are readily polymerized in the presence of cationic photoinitiators, when exposed to actinic radiation, to form poly(propenyl ethers) that are useful for coatings, sealants, varnishes and adhesives. Compositions for preparing polymeric coatings comprising the compounds of formula V together with particular cationic photoinitiators are also disclosed, as are processes for making the monomers from allyl halides and readily available alcohols. The process involves rearranging the resulting allyl ethers to propenyl ethers.

  6. Vacuum structure and ether-drift experiments

    E-Print Network [OSTI]

    M. Consoli; L. Pappalardo

    2009-05-12

    In the data of the ether-drift experiments there might be sizable fluctuations superposed on the smooth sinusoidal modulations due to the Earth's rotation and orbital revolution. These fluctuations might reflect the stochastic nature of the underlying "quantum ether" and produce vanishing averages for all vectorial quantities extracted from a naive Fourier analysis of the data. By comparing the typical stability limits of the individual optical resonators with the amplitude of their relative frequency shift, the presently observed signal, rather than being spurious experimental noise, might also express fundamental properties of a physical vacuum similar to a superfluid in a turbulent state of motion. In this sense, the situation might be similar to the discovery of the CMBR that was first interpreted as mere instrumental noise.

  7. Crown Ethers Flatten in Graphene for Strong, Specific Binding...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2011 2010 News Home | ORNL | News | Features | 2014 SHARE Crown Ethers Flatten in Graphene for Strong, Specific Binding ORNL discovery holds potential for separations, sensors,...

  8. Alternative Fuels Data Center: Dimethyl Ether

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center Home Page on Digg FindPortsas a VehicleNaturalDimethyl Ether to

  9. Butyl Fuel LLC formerly Environmental Energy Inc | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar Energy LLC JumpBiossenceBrunswick, Maine:IAEA CooperationSolarButyl Fuel LLC

  10. Network Structure of Cellulose Ethers Used in Pharmaceutical Applications

    E-Print Network [OSTI]

    Peppas, Nicholas A.

    Network Structure of Cellulose Ethers Used in Pharmaceutical Applications during Swelling cellulose ethers that differ in their type and degree of substitution and to elucidate the network structure hydrogels of cellulose derivatives, such as the polymer volume frac- tion in the swollen state, 2,S

  11. Process for producing dimethyl ether form synthesis gas

    DOE Patents [OSTI]

    Pierantozzi, Ronald (Macungie, PA)

    1985-01-01

    This invention pertains to a Fischer Tropsch process for converting synthesis gas to an oxygenated hydrocarbon with particular emphasis on dimethyl ether. Synthesis gas comprising carbon monoxide and hydrogen are converted to dimethyl ether by carrying out the reaction in the presence of an alkali metal-manganese-iron carbonyl cluster incorporated onto a zirconia-alumina support.

  12. Emergent gravity and ether-drift experiments

    E-Print Network [OSTI]

    M. Consoli; L. Pappalardo

    2010-05-04

    According to several authors, gravity might be a long-wavelength phenomenon emerging in some 'hydrodynamic limit' from the same physical, flat-space vacuum viewed as a form of superfluid medium. In this framework, light might propagate in an effective acoustic geometry and exhibit a tiny anisotropy that could be measurable in the present ether-drift experiments. By accepting this view of the vacuum, one should also consider the possibility of sizeable random fluctuations of the signal that reflect the stochastic nature of the underlying `quantum ether' and could be erroneously interpreted as instrumental noise. To test the present interpretation, we have extracted the mean amplitude of the signal from various experiments with different systematics, operating both at room temperature and in the cryogenic regime. They all give the same consistent value = O (10^{-15}) which is precisely the magnitude expected in an emergent-gravity approach, for an apparatus placed on the Earth's surface. Since physical implications could be substantial, it would be important to obtain more direct checks from the instantaneous raw data and, possibly, with new experimental set-ups operating in gravity-free environments.

  13. Origin of mechanical modifications in poly (ether ether ketone)/carbon nanotube composite

    SciTech Connect (OSTI)

    Pavlenko, Ekaterina; Puech, Pascal; Bacsa, Wolfgang; Boyer, François; Olivier, Philippe; Sapelkin, Andrei; King, Stephen; Heenan, Richard; Pons, François; Gauthier, Bénédicte; Cadaux, Pierre-Henri

    2014-06-21

    Variations in the hardness of a poly (ether ether ketone) beam electrically modified with multi-walled carbon nanotubes (MWCNT, 0.5%-3%) are investigated. It is shown that both rupture and hardness variations correlate with the changes in carbon nanotube concentration when using micro indentation and extended Raman imaging. Statistical analysis of the relative spectral intensities in the Raman image is used to estimate local tube concentration and polymer crystallinity. We show that the histogram of the Raman D band across the image provides information about the amount of MWCNTs and the dispersion of MWCNTs in the composite. We speculate that we have observed a local modification of the ordering between pure and modified polymer. This is partially supported by small angle neutron scattering measurements, which indicate that the agglomeration state of the MWCNTs is the same at the concentrations studied.

  14. A sulfonated poly (aryl ether ether ketone ketone) isomer: synthesis and DMFC performance

    SciTech Connect (OSTI)

    Kim, Yu Seung [Los Alamos National Laboratory; Liu, Baijun [JILIN UNIV.; Hu, Wei [JILIN UNIV.; Jiang, Zhenhua [JILIN UNIV.; Robertson, Gilles [CANADA NRC; Guiver, Michael [CANADA NRC

    2009-01-01

    A sulfonated poly(aryl ether ether ketone ketone) (PEEKK) having a well-defined rigid homopolymer-like chemical structure was synthesized from a readily-prepared PEEKK post-sulfonation with concentrated sulfuric acid at room temperature within several hours. The polymer electrolyte membrane (PEM) cast from the resulting polymer exhibited an excellent combination of thermal resistance, oxidative and dimensional stability, low methanol fuel permeability and high proton conductivity. Furthermore, membrane electrode assemblies (MEAs) were successfully fabricated and good direct methanol fuel cell (DMFC) performance was observed. At 2 M MeOH feed, the current density at 0.5 V reached 165 mA/cm, which outperformed our reported analogues and eveluated Nafion membranes.

  15. Development of specialty chemicals from dimethyl ether

    SciTech Connect (OSTI)

    Tartamella, T.L.; Lee, S.

    1996-12-31

    Dimethyl ether (DME) may be efficiently produced from coal-bases syngas in a high pressure, mechanically agitated slurry reactor. DME synthesis occurs in the liquid phase using a dual catalyst. By operating in a dual catalyst mode, DME may be converted from in-situ produced methanol resulting in higher methyl productivities and syngas conversions over methanol conversion alone. The feasibility of utilizing DME as a building block for more valuable specialty chemicals has been examined. A wide variety of petrochemicals may be produced from DME including light olefins, gasoline range hydrocarbons, oxygenates, and glycol precursors. These chemicals represent an important part of petroleum industries inventory of fine chemicals. Carbonylation, hydrocarbonylation, and oxidative dimerization are but a few of the reactions in which DME may undergo conversion. DME provides an additional route for the production of industrially important petrochemicals.

  16. High pressure injection of dimethyl ether

    SciTech Connect (OSTI)

    Glensvig, M.; Sorenson, S.C.; Abata, D.

    1996-12-31

    Partially oxygenated hydrocarbons produced from natural gas have been shown to be viable alternate fuels for the diesel engine, showing favorable combustion characteristics similar to that of diesel fuel but without exhaust particulates and with significantly reduced NO{sub x} emissions and lower engine noise. Further, engine studies have demonstrated that such compounds, like dimethyl ether (DME), can be injected at much lower pressures than conventional diesel fuel with better overall performance. This experimental study compares the injection of DME to that of conventional diesel fuel. Both fuels were injected into a quiescent high pressure chamber containing Nitrogen at pressures up to 25 atmospheres at room temperature with a pintle nozzle and jerk pump. Comparisons were obtained with high speed photography using a Hycam camera. Results indicate that there are significant differences in spray geometry and penetration which are not predictable with analytical models currently used for diesel fuels.

  17. Identification of volatile butyl rubber thermal-oxidative degradation products by cryofocusing gas chromatography/mass spectrometry (cryo-GC/MS).

    SciTech Connect (OSTI)

    Smith, Jonell Nicole; White, Michael Irvin; Bernstein, Robert; Hochrein, James Michael

    2013-02-01

    Chemical structure and physical properties of materials, such as polymers, can be altered as aging progresses, which may result in a material that is ineffective for its envisioned intent. Butyl rubber formulations, starting material, and additives were aged under thermal-oxidative conditions for up to 413 total days at up to 124 %C2%B0C. Samples included: two formulations developed at Kansas City Plant (KCP) (%236 and %2310), one commercially available formulation (%2321), Laxness bromobutyl 2030 starting material, and two additives (polyethylene AC-617 and Vanax MBM). The low-molecular weight volatile thermal-oxidative degradation products that collected in the headspace over the samples were preconcentrated, separated, and detected using cryofocusing gas chromatography mass spectrometry (cryo-GC/MS). The majority of identified degradation species were alkanes, alkenes, alcohols, ketones, and aldehydes. Observations for Butyl %2310 aged in an oxygen-18 enriched atmosphere (18O2) were used to verify when the source of oxygen in the applicable degradation products was from the gaseous environment rather than the polymeric mixture. For comparison purposes, Butyl %2310 was also aged under non-oxidative thermal conditions using an argon atmosphere.

  18. Catalytic rearrangement of the chloroallyl ethers of p-cresol

    SciTech Connect (OSTI)

    Andreev, N.A.; Bunina-Krivorukova, L.I.; Levashova, V.I.

    1986-07-20

    The rearrangement of a series of p-cresol ethers (..beta..- and ..gamma..-chloro-, ..beta gamma..- and ..beta gamma..,..gamma..-trichloroallyl), catalyzed by boron trifluoride etherate, was studied. Increase in the number of chlorine atoms in the allyl unit of the ether hinders the rearrangement, and its mechanism changes in the investigated series of ethers from intramolecular (3,3)-sigmatropic (with inversion of the allyl unit) to intermolecular, which corresponds to electrophilic substitution in the aromatic ring (without inversion). The presence of the chlorine atom at the ..beta.. position of the allyl unit promotes rearrangement by a concerted intramolecular mechanism, while a chlorine atom at the ..gamma.. position promotes rearrangement by an intermolecular stage mechanism. Two chlorine atoms at the ..gamma.. position give rise mainly to the intermolecular rearrangement path.

  19. A kinetic investigation of the reaction of dibutyl sodiophosphonate with n-butyl bromide 

    E-Print Network [OSTI]

    Shaffer, James Howard

    1955-01-01

    LIBRARY A A N COLLEGE OF TEXAS A KINETIC INVESTIGATION OI" TIIE RFACTION OF DIBUTYL SODIOITIOSPHONATE II'ITH N BUTYL BROIIllDE A Thesis By James Howard Shaffer Submitted to the Oraduate School of the Agricultural and Mechanical College... of Texn~ in partial fulfillment of the requirements for the de ree of MASTER OF SCIENCE August 1955 Major Subject: Chemistry A KINETIC INVESTIGATION OF THE REACTION OF DIBUTYL SODIOPHOSPHONATE WITH N-BUTYL BROMIDE A Thesis By James Howard Shaffer...

  20. Atmospheric and combustion chemistry of dimethyl ether

    SciTech Connect (OSTI)

    Nielsen, O.J.; Egsgaard, H.; Larsen, E.; Sehested, J.; Wallington, T.J.

    1997-12-31

    It has been demonstrated that dimethyl ether (DME) is an ideal diesel fuel alternative. DME, CH{sub 3}OCH{sub 3}, combines good fuel properties with low exhaust emissions and low combustion noise. Large scale production of this fuel can take place using a single step catalytic process converting CH{sub 4} to DME. The fate of DME in the atmosphere has previously been studied. The atmospheric degradation is initiated by the reaction with hydroxyl radicals, which is also a common feature of combustion processes. Spectrokinetic investigations and product analysis were used to demonstrate that the intermediate oxy radical, CH{sub 3}OCH{sub 2}O, exhibits a novel reaction pathway of hydrogen atom ejection. The application of tandem mass spectrometry to chemi-ions based on supersonic molecular beam sampling has recently been demonstrated. The highly reactive ionic intermediates are sampled directly from the flame and identified by collision activation mass spectrometry and ion-molecule reactions. The mass spectrum reflects the distribution of the intermediates in the flame. The atmospheric degradation of DME as well as the unique fuel properties of a oxygen containing compound will be discussed.

  1. Copoly(arlene ether)s containing pendant sulfonic acid groups as proton exchange membrane

    SciTech Connect (OSTI)

    Kim, Yu Seung [Los Alamos National Laboratory; Kim, Dae Sik [CANADA NRC; Robertson, Gilles [CANADA NRC; Guiver, Michael [CANADA NRC

    2008-01-01

    A copoly(arylene ether) (PAE) with high fluorine content and a copoly(arylene ether nitrile) (PAEN) with high nitrile content, each containing pendant phenyl sulfonic acids were synthesized. The P AE and PAEN were prepared from decafluorobiphenyl (DFBP) and difluorobenzonitrile (DFBN) respectively, by polycondensation with 2-phenylhydroquinone (PHQ) by conventional aromatic nucleophilic substitution reactions. The sulfonic acid groups were introduced by mild post-sulfonation exclusively on the para-position of the pendant phenyl ring in PHQ. The membrane properties of the resulting sulfonated copolymers sP AE and sP AEN were compared for fuel cell applications. The copolymers sPAE and sPAEN, each having a degree of sulfonation (DS) of 1.0 had high ion exchange capacities (IEC{sub v}(wet) (volume-based, wet state)) of 1.77 and 2.55 meq./cm{sup 3}, high proton conductivities of 135.4 and 140.1 mS/cm at 80 C, and acceptable volume-based water uptake of 44.5-51.9 vol% at 80 C, respectively, compared to Nafion. The data points of these copolymer membranes are located in the area of outstanding properties in the trade-off plot of alternative hydrocarbon polyelectrolyte membranes (PEM) for the relationship between proton conductivity versus water uptake (weight based or volume based). Furthermore, the relative selectivity derived from proton conductivity and methanol permeability is higher than that of Nafion.

  2. Solvent extraction of technetium from alkaline waste media using bis-4,4{prime}(5{prime})[(tert-butyl)cyclohexano]-18-crown-6

    SciTech Connect (OSTI)

    Bonnesen, P.V.; Presley, D.J.; Moyer, B.A.

    1995-07-01

    The crown ether bis-4,4`(5`)[(tert-butyl)cyclohexano]-18-crown-6 can be utilized in a solvent-extraction process for the removal of technetium as pertechnetate ion, TcO{sub 4}{sup {minus}} from solutions simulating highly radioactive alkaline defense wastes (``tank wastes``) stored at several sites in the United States. The process employs non-halogenated and non-volatile diluents and modifiers and includes an efficient stripping procedure using only water. More than 95% of the pertechnetate present at 6 {times} 10{sup {minus}5} M in Melton Valley (Oak Ridge, TN) and Hanford (Washington) tank-waste simulants was removed following two cross-current extraction contacts using 0.02 M bis-4,4`(5`)[(tertbutyl)cyclohexano]- 18-crown-6 in 2:1 vol/vol TBP/Isopar{reg_sign} M diluent at 25 C. Similarly, for both simulants, more than 98% of the pertechnetate contained in the solvent was back-extracted following two cross-current stripping contacts using deionized water.

  3. Copoly(arylene ether)s containing pendant sulfonic acid groups as proton exchange membranes

    SciTech Connect (OSTI)

    Dae Sik, Kim [Los Alamos National Laboratory; Yu Seung, Kim [Los Alamos National Laboratory; Gilles, Robertson [CANADA-NRC; Guiver, Michael D [CANADA-NRC

    2009-01-01

    A copoly(arylene ether) (PAE) with high fluorine content and a copoly(arylene ether nitrile) (PAEN) with high nitrile content, each containing pendant phenyl sulfonic acids were synthesized. The PAE and P AEN were prepared from decafluorobiphenyl (DFBP) and difluorobenzonitrile (DFBN) respectively, by polycondensation with 2phenylhydroquinone (PHQ) by conventional aromatic nucleophilic substitution reactions. sulfonic acid groups were introduced by mild post-sulfonation exclusively on the para-position of the pendant phenyl ring in PHQ. The membrane properties of the resulting sulfonated copolymers sPAE and sPAEN were compared for fuel cell applications. The copolymers sPAE and sPAEN, each having a degree of sulfonation (OS) of 1.0 had high ion exchange capacities (IEC{sub v})(wet) (volume-based, wet state) of 1.77 and 2.55 meq./cm3, high proton conductivities of 135.4 and 140.1 mS/cm at 80 C, and acceptable volume-based water uptake of 44.5 -51.9 vol% at 80 C, respectively, compared to Nafion. The data points of these copolymer membranes are located in the upper left-hand corner in the trade-off plot of alternative hydrocarbon polyelectrolyte membranes (PEM) for the relationship between proton conductivity versus water uptake (weight based or volume based), i.e., high proton conductivity and low water uptake. Furthermore, the relative selectivity derived from proton conductivity and methanol permeability is higher than that of Nafion.

  4. RELATIONS BETWEEN THE DETECTION OF METHYL TERT-BUTYL ETHER (MTBE) IN SURFACE AND GROUND WATER AND ITS CONTENT IN GASOLINE

    E-Print Network [OSTI]

    AND ITS CONTENT IN GASOLINE By Michael J. Moran, Mike J. Halde, Rick M. Clawges and John S. Zogorski U in the United States as an octane enhancer and oxygenate in gasoline. Octane enhancement began in the late 1970's with the phase-out of tetraethyl lead from gasoline. The use of oxygenates was expanded

  5. Li-air batteries having ether-based electrolytes

    DOE Patents [OSTI]

    Amine, Khalil; Curtiss, Larry A; Lu, Jun; Lau, Kah Chun; Zhang, Zhengcheng; Sun, Yang-Kook

    2015-03-03

    A lithium-air battery includes a cathode including a porous active carbon material, a separator, an anode including lithium, and an electrolyte including a lithium salt and polyalkylene glycol ether, where the porous active carbon material is free of a metal-based catalyst.

  6. Direct Dimethyl Ether Polymer Electrolyte Fuel Cells for Portable Applications

    E-Print Network [OSTI]

    Mench, Matthew M.

    . Chance, and C. Y. Wang* Electrochemical Engine Center and Department of Mechanical and Nuclear Engineering, The Pennsylvania State University, University Park, Pennsylvania 16802, USA Dimethyl ether DME at atmospheric pressure. It is typically stored as a liquid at 0.6 MPa 75 psig in standard propane tanks. DME

  7. Batch polymerization of styrene and isoprene by n-butyl lithium initiator 

    E-Print Network [OSTI]

    Hasan, Sayeed

    1970-01-01

    BATCN ?OLYMERIZATION OF STYRENE AND ISO?RENE BY n-BUTYL LITHIUM INITIATOR A Thesis SAYEED IIASAV Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement for the d pre of IJASTER OF SCIFNCE... ler) CP3 MV gse P . January 1970 9&ZS&8 ABSTRACT Batch Polymerization of Styrene and Isoprene By n-Butyl Lithium Initiator. (January 1970) Sayeed 1Iasan, B. Sc. , East Pakistan University of Engineering and Technology, Dacca Directed by: Dr...

  8. Batch polymerization of styrene initiated by n-butyl lithium in a cyclohexane solvent 

    E-Print Network [OSTI]

    Landon, Thomas Rodman

    1971-01-01

    Committee ea Depa tment Mem er Mem er em er August 1971 ABSTRACT Batch Polymerization of Styrene Initiated by N-Butyl Lithium in Cyclohexane Solvent. (August 19 71) Thomas Rodman Landon, B, S. , Te x as A (&M Un i ve rs i ty Directed by: Dr.... Rayford G. Anthony Styrene is polymerized by n-butyl lithium with cyclo- hexane as the solvent. The polymerization is carried out in an isothermal batch reactors at three temperature 30, 40, and 50'C. The proposed reaction proceeds by a homo- geneous...

  9. Butyl acetate replaces toluene to remove phenol from water

    SciTech Connect (OSTI)

    Hodel, A.E.

    1993-03-01

    Plastics Engineering Co. manufactures phenol formaldehyde resins and molding compounds at a plant in Sheboygan, WI. Process water from the plant, containing 7% phenol and 1% methanol, requires treatment prior to discharge to the sewer. Toluene was used as a solvent in a countercurrent liquid-liquid extraction column. A vacuum distillation of the extract separated the phenol and toluene. The raffinate (1% methanol, 98% water and 1% toluene) was stripped to recover the toluene and remove methanol from the bottoms prior to discharge. Methanol was not recovered. Disposal costs for the waste methanol (with about 10% toluene as an azeotrope) were high.

  10. Palladium/Tris(tert-butyl)phosphine-Catalyzed Suzuki Cross-Couplings in the Presence of Water

    E-Print Network [OSTI]

    Lou, Sha

    Dipalladiumtris(dibenzylideneacetone)/tris(tert-butyl)phosphonium tetrafluoroborate/potassium fluoride dihydrate [Pd2(dba)3/[HP(t-Bu)3]BF4/KF?2?H2O] serves as a mild, robust, and user-friendly method for the efficient ...

  11. Dark matter, Mach's ether and the QCD vacuum

    E-Print Network [OSTI]

    Cohen-Tannoudji, Gilles

    2015-01-01

    Here is proposed the idea of linking the dark matter issue, (considered as a major problem of contemporary research in physics) with two other open theoretical questions, one, almost centenary about the existence of an unavoidable ether in general relativity agreeing with the Mach's principle, and one more recent about the properties of the quantum vacuum of the quantum field theory of strong interactions, QuantumChromodynamics (QCD). According to this idea, on the one hand, dark matter and dark energy that, according to the current standard model of cosmology represent about 95% of the universe content, can be considered as two distinct forms of the Mach's ether, and, on the other hand, dark matter, as a perfect fluid emerging from the QCD vacuum could be modeled as a Bose Einstein condensate.

  12. CATALYSTS FOR HIGH CETANE ETHERS AS DIESEL FUELS

    SciTech Connect (OSTI)

    Kamil Klier; Richard G. Herman; James G.C. Shen; Qisheng Ma

    2000-08-31

    A novel 1,2-ethanediol, bis(hydrogen sulfate), disodium salt precursor-based solid acid catalyst with a zirconia substrate was synthesized and demonstrated to have significantly enhanced activity and high selectivity in producing methyl isobutyl ether (MIBE) or isobutene from methanol-isobutanol mixtures. The precursor salt was synthesized and provided by Dr. T. H. Kalantar of the M.E. Pruitt Research Center, Dow Chemical Co., Midland, MI 48674. Molecular modeling of the catalyst synthesis steps and of the alcohol coupling reaction is being carried out. A representation of the methyl transfer from the surface activated methanol molecule (left) to the activated oxygen of the isobutanol molecule (right) to form an ether linkage to yield MIBE is shown.

  13. Mechanistic Investigation of Acid-Catalyzed Cleavage of Aryl-Ether Linkages: Implications for Lignin Depolymerization

    SciTech Connect (OSTI)

    Sturgeon, M. R.; Kim, S.; Chmely, S. C.; Foust, T. D.; Beckham, G. T.

    2013-01-01

    Carbon-oxygen bonds are the primary inter-monomer linkages lignin polymers in plant cell walls, and as such, catalyst development to cleave these linkages is of paramount importance to deconstruct biomass to its constituent monomers for the production of renewable fuels and chemicals. For many decades, acid catalysis has been used to depolymerize lignin. Lignin is a primary component of plant cell walls, which is connected primarily by aryl-ether linkages, and the mechanism of its deconstruction by acid is not well understood, likely due to its heterogeneous and complex nature compared to cellulose. For effective biomass conversion strategies, utilization of lignin is of significant relevance and as such understanding the mechanisms of catalytic lignin deconstruction to constituent monomers and oligomers is of keen interest. Here, we present a comprehensive experimental and theoretical study of the acid catalysis of a range of dimeric species exhibiting the b-O-4 linkage, the most common inter-monomer linkage in lignin. We demonstrate that the presence of a phenolic species dramatically increases the rate of cleavage in acid at 150 degrees C. Quantum mechanical calculations on dimers with the para-hydroxyl group demonstrate that this acid-catalyzed pathway differs from the nonphenolic dimmers. Importantly, this result implies that depolymerization of native lignin in the plant cell wall will proceed via an unzipping mechanism wherein b-O-4 linkages will be cleaved from the ends of the branched, polymer chains inwards toward the center of the polymer. To test this hypothesis further, we synthesized a homopolymer of b-O-4 with a phenolic hydroxyl group, and demonstrate that it is cleaved in acid from the end containing the phenolic hydroxyl group. This result suggests that genetic modifications to lignin biosynthesis pathways in plants that will enable lower severity processes to fractionate lignin for upgrading and for easier access to the carbohydrate fraction of the plant cell wall.

  14. Thermodynamics of Hydrogen Production from Dimethyl Ether Steam Reforming and Hydrolysis

    SciTech Connect (OSTI)

    T.A. Semelsberger

    2004-10-01

    The thermodynamic analyses of producing a hydrogen-rich fuel-cell feed from the process of dimethyl ether (DME) steam reforming were investigated as a function of steam-to-carbon ratio (0-4), temperature (100 C-600 C), pressure (1-5 atm), and product species: acetylene, ethanol, methanol, ethylene, methyl-ethyl ether, formaldehyde, formic acid, acetone, n-propanol, ethane and isopropyl alcohol. Results of the thermodynamic processing of dimethyl ether with steam indicate the complete conversion of dimethyl ether to hydrogen, carbon monoxide and carbon dioxide for temperatures greater than 200 C and steam-to-carbon ratios greater than 1.25 at atmospheric pressure (P = 1 atm). Increasing the operating pressure was observed to shift the equilibrium toward the reactants; increasing the pressure from 1 atm to 5 atm decreased the conversion of dimethyl ether from 99.5% to 76.2%. The order of thermodynamically stable products in decreasing mole fraction was methane, ethane, isopropyl alcohol, acetone, n-propanol, ethylene, ethanol, methyl-ethyl ether and methanol--formaldehyde, formic acid, and acetylene were not observed. The optimal processing conditions for dimethyl ether steam reforming occurred at a steam-to-carbon ratio of 1.5, a pressure of 1 atm, and a temperature of 200 C. Modeling the thermodynamics of dimethyl ether hydrolysis (with methanol as the only product considered), the equilibrium conversion of dimethyl ether is limited. The equilibrium conversion was observed to increase with temperature and steam-to-carbon ratio, resulting in a maximum dimethyl ether conversion of approximately 68% at a steam-to-carbon ratio of 4.5 and a processing temperature of 600 C. Thermodynamically, dimethyl ether processed with steam can produce hydrogen-rich fuel-cell feeds--with hydrogen concentrations exceeding 70%. This substantiates dimethyl ether as a viable source of hydrogen for PEM fuel cells.

  15. Versatile assembly of p-carboxylatocalix[4]arene-O-alkyl ethers

    E-Print Network [OSTI]

    Kennedy, Stuart

    2011-01-01

    Chem. , 2007, 72, 1675; j) S. Kennedy, S. J. Dalgarno, Chem.0-alkyl ethers Stuart Kennedy," Simon J. Teat* and Scott J.

  16. Aging of Weapon Seals – An Update on Butyl O-ring Issues

    SciTech Connect (OSTI)

    Wilson, Mark H.

    2011-07-13

    During testing under the Enhanced Surveillance Campaign in 2001, preliminary data detected a previously unknown and potentially serious concern with recently procured butyl o-rings on several programs. All butyl o-rings molded from a proprietary formulation throughout the period circa 1999 through 2001 had less than a full cure. Engineering judgment was that under curing is detrimental and could possibly lead to sub-optimum performance or, in the worst case, premature seal failure. An aging study was undertaken to ensure that suspect o-rings installed in the stockpile will retain sufficient sealing force for a minimum ten-year service life. A new prediction model developed for this study indicates suspect o-rings do not need to be replaced before the ten-year service life. Long-term testing results are reported on a yearly basis to validate the prediction model. This report documents the aging results for the period September 2002 to January 2011.

  17. New clean fuel from coal -- Direct dimethyl ether synthesis from hydrogen and carbon monoxide

    SciTech Connect (OSTI)

    Ogawa, T.; Ono, M.; Mizuguchi, M.; Tomura, K.; Shikada, T.; Ohono, Y.; Fujimoto, K.

    1997-12-31

    Dimethyl ether (DME), which has similar physical properties to propane and is easily liquefied at low pressure, has a significant possibility as a clean and non-toxic fuel from coal or coal bed methane. Equilibrium calculation also shows a big advantage of high carbon monoxide conversion of DME synthesis compared to methanol synthesis. By using a 50 kg/day DME bench scale test plant, direct synthesis of DME from hydrogen and carbon monoxide has been studied with newly developed catalysts which are very fine particles. This test plant features a high pressure three-phase slurry reactor and low temperature DME separator. DME is synthesized at temperatures around 533--553 K and at pressures around 3--5 MPa. According to the reaction stoichiometry, the same amount of hydrogen and carbon monoxide react to DME and carbon dioxide. Carbon conversion to DME is one third and the rest of carbon is converted to carbon dioxide. As a result of the experiments, make-up CO conversion is 35--50% on an once-through basis, which is extremely high compared to that of methanol synthesis from hydrogen and carbon monoxide. DME selectivity is around 60 c-mol %. Most of the by-product is CO{sub 2} with a small amount of methanol and water. No heavy by-products have been recognized. Effluent from the reactor is finally cooled to 233--253 K in a DME separator and liquid DME is recovered as a product.

  18. Bisphenol A Diglycidyl Ether Induces Adipogenic Differentiation of Multipotent Stromal Stem Cells through a Peroxisome Proliferator-Activated Receptor Gamma-Independent Mechanism

    E-Print Network [OSTI]

    2012-01-01

    Hla T, Warner TD. 2000. Bisphenol A diglycidyl ether (BADGE)C, et al. 2008. Migration of BADGE (bisphenol A diglycidyl-ether) and BFDGE (bisphenol F diglycidyl-ether) in canned

  19. Bisphenol A diglycidyl ether induces adipogenic differentiation of multipotent stromal stem cells through a peroxisome proliferator-activated receptor gamma-independent mechanism

    E-Print Network [OSTI]

    2012-01-01

    Hla T, Warner TD. 2000. Bisphenol A diglycidyl ether (BADGE)C, et al. 2008. Migration of BADGE (bisphenol A diglycidyl-ether) and BFDGE (bisphenol F diglycidyl-ether) in canned

  20. A Model of Electrons, Photons and the Ether

    E-Print Network [OSTI]

    Robert L. McCarthy

    2008-07-24

    This is an attempt to construct a classical microscopic model of the electron which underlies quantum mechanics. An electron is modeled, not as a point particle, but as the end of an electromagnetic string, a line of flux. These lines stretch across cosmic distances, but are almost unobservable because they condense into pairs--which form the ether. Photons are modeled to propagate on these line pairs, which act effectively as wave guides. These line pairs are also responsible for the force of gravity--which is electromagnetic in character.

  1. DIMETHYL ETHER (DME)-FUELED SHUTTLE BUS DEMONSTRATION PROJECT

    SciTech Connect (OSTI)

    Elana M. Chapman; Shirish Bhide; Andre L. Boehman; David Klinikowski

    2003-04-01

    The objectives of this research and demonstration program are to convert a campus shuttle bus to operation on dimethyl ether, a potential ultra-clean alternative diesel fuel. To accomplish this objective, this project includes laboratory evaluation of a fuel conversion strategy, as well as field demonstration of the DME-fueled shuttle bus. Since DME is a fuel with no lubricity (i.e., it does not possess the lubricating quality of diesel fuel), conventional fuel delivery and fuel injection systems are not compatible with dimethyl ether. Therefore, to operate a diesel engine on DME one must develop a fuel-tolerant injection system, or find a way to provide the necessary lubricity to the DME. In this project, they have chosen the latter strategy in order to achieve the objective with minimal need to modify the engine. The strategy is to blend DME with diesel fuel, to obtain the necessary lubricity to protect the fuel injection system and to achieve low emissions. Within the Combustion Laboratory of the Penn State Energy Institute, they have installed and equipped a Navistar V-8 direct-injection turbodiesel engine for measurement of gaseous and particulate emissions and examination of the impact of fuel composition on diesel combustion. They have also reconfigured a high-pressure viscometer for studies of the viscosity, bulk modulus (compressibility) and miscibility of blends of diesel fuel, dimethyl ether and lubricity additives. The results include baseline emissions, performance and combustion measurements on the Navistar engine for operation on a federal low sulfur diesel fuel (300 ppm S). Most recently, they have examined blends of an oxygenated fuel additive (a liquid fuel called CETANER{trademark}) produced by Air Products, for comparison with dimethyl ether blended at the same weight of oxygen addition, 2 wt.%. While they have not operated the engine on DME yet, they are now preparing to do so. A fuel system for delivery of DME/Diesel blends has been configured and initial investigations at low DME blend ratios (around 5-10 vol%) will begin shortly. They have also performed viscosity measurements on diesel fuel, DME and 50-50 blends of DME in diesel. These tests have verified that DME has a much lower viscosity than the diesel fuel and that the viscosity of the blended fuel is also much lower than the diesel base fuel. This has implications for the injection and atomization of the DME/diesel blends.

  2. Interactions between Ether Phospholipids and Cholesterol as Determined by Scattering and Molecular Dynamics Simulations

    SciTech Connect (OSTI)

    Pan, Jianjun [ORNL; Cheng, Xiaolin [ORNL; Heberle, Frederick A [ORNL; Mostofian, Barmak [ORNL; Kucerka, Norbert [Canadian Neutron Beam Centre and Comelius University (Slovakia); Drazba, Paul [ORNL; Katsaras, John [ORNL

    2012-01-01

    Cholesterol and ether lipids are ubiquitous in mammalian cell membranes, and their interactions are crucial in ether lipid mediated cholesterol trafficking. We report on cholesterol s molecular interactions with ether lipids as determined using a combination of small-angle neutron and Xray scattering, and all-atom molecular dynamics (MD) simulations. A scattering density profile model for an ether lipid bilayer was developed using MD simulations, which was then used to simultaneously fit the different experimental scattering data. From analysis of the data the various bilayer structural parameters were obtained. Surface area constrained MD simulations were also performed to reproduce the experimental data. This iterative analysis approach resulted in good agreement between the experimental and simulated form factors. The molecular interactions taking place between cholesterol and ether lipids were then determined from the validated MD simulations. We found that in ether membranes cholesterol primarily hydrogen bonds with the lipid headgroup phosphate oxygen, while in their ester membrane counterparts cholesterol hydrogen bonds with the backbone ester carbonyls. This different mode of interaction between ether lipids and cholesterol induces cholesterol to reside closer to the bilayer surface, dehydrating the headgroup s phosphate moiety. Moreover, the three-dimensional lipid chain spatial density distribution around cholesterol indicates anisotropic chain packing, causing cholesterol to tilt. These insights lend a better understanding of ether lipid-mediated cholesterol trafficking and the roles that the different lipid species have in determining the structural and dynamical properties of membrane associated biomolecules.

  3. Ether sulfones with additives for electrolytes in rechargeable lithium ion batteries

    E-Print Network [OSTI]

    Angell, C. Austen

    Ether sulfones with additives for electrolytes in rechargeable lithium ion batteries Xiao-Guang Sun in rechargeable lithium ion battery [1-5]. In a previous publication [6] we described a series of ether sulfones electrolytes, can yield lithium button cells ?batteries with very favorable characteristics. (Refs to VC

  4. Laser Light-Scattering Study of Novel Thermoplastics. 1. Phenolphthalein Poly(aryl ether ketone)

    E-Print Network [OSTI]

    Wu, Chi

    Laser Light-Scattering Study of Novel Thermoplastics. 1. Phenolphthalein Poly(aryl ether ketone(ether ketone) (PEK), are widely used as engineering thermoplastics or matrix resins in advanced composite, the processing and application of these thermoplastics have been greatly hindered by their low solubility

  5. Decomposition of Ethanol and Dimethyl Ether During Chemical Vapour deposition Synthesis

    E-Print Network [OSTI]

    Maruyama, Shigeo

    1 Decomposition of Ethanol and Dimethyl Ether During Chemical Vapour deposition Synthesis of Single-phase thermal decomposition of ethanol and dimethyl ether (DME) at typical SWNT growth conditions using to the predicted decomposition mechanism. Signature peak intensities indicated concentrations of both ethanol

  6. Rational Design of Cesium-Selective Ionophores and Chemosensors: Dihydrocalix[4]arene Crown-6 Ethers

    SciTech Connect (OSTI)

    Sachleben, Richard A.; Bryan, Jeffrey C.; Brown, Gilbert M.; Engle, Nancy L.; Haverlock, Tamara J.; Hay, Benjamin P.; Urvoas, Agathe; Moyer, Bruce A.

    2003-12-15

    Molecular mechanics calculations performed on calix[4]arene crown-6 ethers predict that the 1,3-dihydro derivatives will exhibit greater complementarity for potassium and cesium ions than the parent 1,3-dialkoxy calix crowns. The X-ray crystal structures of 1,3-alt bis-octyloxycalix[4]arene benzocrown-6 ether, dihydrocalix[4]arene benzocrown-6 ether, and the cesium nitrate complex of dihydrocalix[4]arene benzocrown-6 ether were determined. The cesium complex structure corresponds closely to the structure predicted by molecular mechanics. The dihydrocalix[4]arene crown-6 ethers exhibit enhanced cesium selectivity in the extraction of alkali metal salts and provide a platform for a highly sensitive and selective cesium chemosensor.

  7. Dimethyl ether synthesis from syngas in slurry phase

    SciTech Connect (OSTI)

    Han, Y.Z.; Fujimoto, K.; Shikata, T.

    1997-12-31

    Dimethyl ether (DME) is one of the important chemicals derived from synthesis gas. It can be widely used in syngas conversion, production of olefins, or MTG gasoline. Recently, is has been noticed as a substitute of LPG used as home fuel. In the present study, dimethyl ether was effectively synthesized from CO rich syngas (H{sub 2}/CO=1/1) over hybrid catalyst containing a Cu-Zn-Al(O) based methanol synthesis catalyst and {gamma}-alumina in an agitated slurry reactor under relatively mild reaction conditions: temperature 230--300 C, pressure 2.0--5.0 MPa, contact time 2.0--10 gram-cat.-h/mol. The catalysts used as the methanol active components were commercially available Cu-Zn-Al(O) based catalysts, BASF S385 and ICI 51-2. Two kinds of {gamma}-alumina ALO4 (standard catalyst of the Catalysis Society of Japan) and N612N (NIKKI Co., Japan) were used as the methanol dehydration components. The slurry was prepared by mixing the fine powder (<100 mesh) of catalyst components with purified n-hexadecane. The catalysts were reduced by a mixing gas containing 20% syngas and 80% nitrogen with a three-hour programmed temperature raising from room temperature to the final temperature. All products were analyzed by gas chromatographs. Results are given and discussed.

  8. Role of acid catalysis in dimethyl ether conversion processes

    SciTech Connect (OSTI)

    Tartamella, T.L.; Lee, S.

    1996-12-31

    Acidity plays an important role in the conversion of methanol and dimethyl ether (DME) to hydrocarbons and oxygenates. In the conversion to hydrocarbons over zeolite catalyst, Broensted acidity is the main contributor to the first hydrocarbon formed. Here, acidity is also an important factor in determining olefin, paraffin, and aromatic content in the final product distribution. Catalyst life has also been found to be related to acidity content in zeolites. DME conversion to oxygenates is especially dependent on high acidity catalysts. Superacids like BF{sub 3}, HF-BF{sub 3}, and CF{sub 3}COOH have been used in the past for conversion of DME in carbonylation reactions to form methyl acetate and acetic acid at high pressures. Recently, heteropoly acids and their corresponding metal substituted salts have been used to convert DME to industrially important petrochemicals resulting in shorter reaction times and without the use of harsh operating conditions.

  9. DIMETHYL ETHER (DME)-FUELED SHUTTLE BUS DEMONSTRATION PROJECT

    SciTech Connect (OSTI)

    Elana M. Chapman; Shirish Bhide; Jennifer Stefanik; Andre L. Boehman; David Klinikowski

    2003-04-01

    The objectives of this research and demonstration program are to convert a campus shuttle bus to operation on dimethyl ether, a potential ultra-clean alternative diesel fuel. To accomplish this objective, this project includes laboratory evaluation of a fuel conversion strategy, as well as, field demonstration of the DME-fueled shuttle bus. Since DME is a fuel with no lubricity (i.e., it does not possess the lubricating quality of diesel fuel), conventional fuel delivery and fuel injection systems are not compatible with dimethyl ether. Therefore, to operate a diesel engine on DME one must develop a fuel-tolerant injection system, or find a way to provide the necessary lubricity to the DME. In this project, they have chosen the latter strategy in order to achieve the objective with minimal need to modify the engine. The strategy is to blend DME with diesel fuel, to obtain the necessary lubricity to protect the fuel injection system and to achieve low emissions. The laboratory studies have included work with a Navistar V-8 turbodiesel engine, demonstration of engine operation on DME-diesel blends and instrumentation for evaluating fuel properties. The field studies have involved performance, efficiency and emissions measurements with the Champion Motorcoach ''Defender'' shuttle bus which will be converted to DME-fueling. The results include baseline emissions, performance and combustion measurements on the Navistar engine for operation on a federal low sulfur diesel fuel (300 ppm S). Most recently, they have completed engine combustion studies on DME-diesel blends up to 30 wt% DME addition.

  10. Power Plant Power Plant

    E-Print Network [OSTI]

    Stillwater Power Plant Wabuska Power Plant Casa Diablo Power Plant Glass Mountain Geothermal Area Lassen Geothermal Area Coso Hot Springs Power Plants Lake City Geothermal Area Thermo Geothermal Area Lakeview Geothermal Area Raft River Geothermal Area Cove Fort Power Plant Roosevelt Power Plant Borax Lake

  11. Toxicity of polychlorinated diphenyl ethers in Hydra attenuata and in rat whole embryo culture 

    E-Print Network [OSTI]

    Becker, Marion Carol

    1991-01-01

    TOXICITY OF CHLORINATED DIPHENYL ETHERS IN HYDRA . . 34 Materials and Methods Results Discussion 36 37 43 IV EXPERIMENTAL ASSESSMENT OF DEVELOPMENTAL TOXICITY OF CHLORINATED DIPHENYL ETHERS IN THE RAT, 46 Materials and Methods Results Discussion... and little is known about their potential for causing developmental defects. Because the PCDEs are closely related to the chlorinated dibenzo-p-dioxins and the PCBs, it is of interest to review studies conducted to determine the developmental toxicity...

  12. Metal ion complexation by ionizable crown ethers. Final report, January 1, 1988--June 30, 1994

    SciTech Connect (OSTI)

    Bartsch, R.A.

    1994-12-31

    During the report period a variety of new lipophilic ionizable crown ethers with pendent proton-ionizable groups has been synthesized. The ligands possess one or more ionizable group (carboxylic acid, phosphonic acid monoethyl ester, para-nitrophenol, phosphonic acid) attached to crown ether, monoazacrown ether or diazacrown ether frameworks. These novel chelating agents have either pendent or inward-facing proton-ionizable groups. Such lipophilic proton-ionizable crown ethers are designed for use in multiphase metal ion separations (solvent extraction, liquid membrane transport). In addition a series of proton-ionizable crown ethers without lipophilic groups was prepared to study how structural variations within the ligand influence metal ion complexation in homogeneous media as assessed by NMR spectroscopy or titration calorimetry. A third class of new metal ion-complexing agents is a series of lipophilic acyclic polyether dicarboxylic acids. Competitive solvent extractions of alkali metal and alkaline earth cations and of the mixed species have been conducted to reveal the influence of ring size, nature and attachment site of the lipophilic group, sidearm length, and proton-ionizable group identity and location upon the selectivity and efficiency of metal ion complexation. In addition to such studies of structural variation within the lipophilic proton-ionizable crown ether, the effect of changing the organic solvent and variation of the stripping conditions have been assessed. The influence of structural variations within lipophilic acyclic polyether dicarboxylic acids upon competitive solvent extraction of alkaline earth cations has been probed. Also a new chromogenic, di-ionizable crown ether with extremely high selectivity for Hg{sup 2+} has been discovered.

  13. An Explanation of Dayton Miller's Anomalous "Ether Drift" Result

    E-Print Network [OSTI]

    Thomas J. Roberts

    2006-10-15

    In 1933 Dayton Miller published in this journal the results of his voluminous observations using his ether drift interferometer, and proclaimed that he had determined the "absolute motion of the earth". This result is in direct conflict with the prediction of Special Relativity, and also with numerous related experiments that found no such signal or "absolute motion". This paper presents a complete explanation for his anomalous result by: a) showing that his results are not statistically significant, b) describing in detail how flaws in his analysis procedure produced a false signal with precisely the properties he expected, and c) presenting a quantitative model of his systematic drift that shows there is no real signal in his data. In short, this is every experimenter's nightmare: he was unknowingly looking at statistically insignificant patterns in his systematic drift that mimicked the appearance of a real signal. An upper limit on "absolute motion" of 6 km/sec is derived from his raw data, fully consistent with similar experimental results and the prediction of Special Relativity. The key point of this paper is the need for a comprehensive and quantitative error analysis. The concepts and techniques used in this analysis were not available in Miller's day, but are now standard. These problems also apply to the famous measurements of Michelson and Morley, and to most if not all similar experiments; appendices are provided discussing several such experiments.

  14. Wide range modeling study of dimethyl ether oxidation

    SciTech Connect (OSTI)

    Pitz, W.J.; Marinov, N.M.; Westbrook, C.K.; Dagaut, P.; Boettner, J-C; Cathonnet, M.

    1997-04-01

    A detailed chemical kinetic model has been used to study dimethyl ether (DME) oxidation over a wide range of conditions. Experimental results obtained in a jet-stirred reactor (JSR) at I and 10 atm, 0.2 < 0 < 2.5, and 800 < T < 1300 K were modeled, in addition to those generated in a shock tube at 13 and 40 bar, 0 = 1.0 and 650 :5 T :5 1300 K. The JSR results are particularly valuable as they include concentration profiles of reactants, intermediates and products pertinent to the oxidation of DME. These data test the Idnetic model severely, as it must be able to predict the correct distribution and concentrations of intermediate and final products formed in the oxidation process. Additionally, the shock tube results are very useful, as they were taken at low temperatures and at high pressures, and thus undergo negative temperature dependence (NTC) behavior. This behavior is characteristic of the oxidation of saturated hydrocarbon fuels, (e.g. the primary reference fuels, n-heptane and iso- octane) under similar conditions. The numerical model consists of 78 chemical species and 336 chemical reactions. The thermodynamic properties of unknown species pertaining to DME oxidation were calculated using THERM.

  15. Green polymer electrolytes based on chitosan and 1-butyl-3-methylimidazolium acetate

    SciTech Connect (OSTI)

    Shamsudin, Intan Juliana [Chemistry Department, Centre for Defence Foundation Studies, National Defence University of Malaysia, 57000 Kuala Lumpur (Malaysia); Ahmad, Azizan; Hassan, Nur Hasyareeda [School of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600, Bangi, Selangor Darul Ehsan (Malaysia)

    2014-09-03

    Green polymer electrolytes based on chitosan as the polymer matrix and ionic liquid 1-butyl-3-methylimidazolium acetate [Bmim][OAc] as charge carriers were prepared by solution casting technique. Complexes with various amount of ionic liquid loading were investigated as possible ionic conducting polymers. The ionic conductivity was found to increase with increasing weight percent of ionic liquid. The highest ionic conductivity of the charged chitosan-[Bmim][OAc] was 2.44 × 10{sup ?3} S cm{sup ?1} at 90 wt.% of [Bmim][OAc] content at ambient temperature. Attenuated Total Reflection Fourier Transform infrared (ATR-FTIR) spectroscopy has proven the interaction between chitosan and [Bmim][OAc]. X-ray Diffraction (XRD) has shown that the amorphosity of the complexes increase as the amount of [Bmim][OAc] increase.

  16. Extraction of short-lived zirconium and hafnium isotopes using crown ethers: A model system for the study of rutherfordium

    E-Print Network [OSTI]

    2005-01-01

    Extraction of short-lived zirconium and hafnium isotopesReceived: ; Accepted: Zirconium / Hafnium / Crown ether /The extraction of zirconium and hafnium from hydrochloric

  17. DIMETHYL ETHER (DME)-FUELED SHUTTLE BUS DEMONSTRATION PROJECT

    SciTech Connect (OSTI)

    Elana M. Chapman; Shirish Bhide; Jennifer Stefanik; Howard Glunt; Andre L. Boehman; Allen Homan; David Klinikowski

    2003-04-01

    The objectives of this research and demonstration program are to convert a campus shuttle bus to operation on dimethyl ether, a potential ultra-clean alternative diesel fuel. To accomplish this objective, this project includes laboratory evaluation of a fuel conversion strategy, as well as, field demonstration of the DME-fueled shuttle bus. Since DME is a fuel with no lubricity (i.e., it does not possess the lubricating quality of diesel fuel), conventional fuel delivery and fuel injection systems are not compatible with dimethyl ether. Therefore, to operate a diesel engine on DME one must develop a fuel-tolerant injection system, or find a way to provide the necessary lubricity to the DME. In this project, they have chosen the latter strategy in order to achieve the objective with minimal need to modify the engine. Their strategy is to blend DME with diesel fuel, to obtain the necessary lubricity to protect the fuel injection system and to achieve low emissions. The bulk of the efforts over the past year were focused on the conversion of the campus shuttle bus. This process, started in August 2001, took until April 2002 to complete. The process culminated in an event to celebrate the launching of the shuttle bus on DME-diesel operation on April 19, 2002. The design of the system on the shuttle bus was patterned after the system developed in the engine laboratory, but also was subjected to a rigorous failure modes effects analysis (FMEA, referred to by Air Products as a ''HAZOP'' analysis) with help from Dr. James Hansel of Air Products. The result of this FMEA was the addition of layers of redundancy and over-pressure protection to the system on the shuttle bus. The system became operational in February 2002. Preliminary emissions tests and basic operation of the shuttle bus took place at the Pennsylvania Transportation Institute's test track facility near the University Park airport. After modification and optimization of the system on the bus, operation on the campus shuttle route began in early June 2002. However, the work and challenges continued as it has been difficult to maintain operability of the shuttle bus due to fuel and component difficulties. In late June 2002, the pump head itself developed operational problems (loss of smooth function) leading to excessive stress on the magnetic coupling and excessive current draw to operate. A new pump head was installed on the system to alleviate this problem and the shuttle bus operated successfully on DME blends from 10-25 vol% on the shuttle bus loop until September 30, 2002. During the period of operation on the campus loop, the bus was pulled from service, operated at the PTI test track and real-time emissions measurements were obtained using an on-board emissions analyzer from Clean Air Technologies International, Inc. Particulate emissions reductions of 60% and 80% were observed at DME blend ratios of 12 vol.% and 25 vol.%, respectively, as the bus was operated over the Orange County driving cycle. Increases in NOx, CO and HC emissions were observed, however. In summary, the conversion of the shuttle bus was successfully accomplished, particulate emissions reductions were observed, but there were operational challenges in the field. Nonetheless, they were able to demonstrate reliable operation of the shuttle bus on DME-diesel blends.

  18. Method for photochemical reduction of uranyl nitrate by tri-N-butyl phosphate and application of this method to nuclear fuel reprocessing

    DOE Patents [OSTI]

    De Poorter, Gerald L. (Los Alamos, NM); Rofer-De Poorter, Cheryl K. (Los Alamos, NM)

    1978-01-01

    Uranyl ion in solution in tri-n-butyl phosphate is readily photochemically reduced to U(IV). The product U(IV) may effectively be used in the Purex process for treating spent nuclear fuels to reduce Pu(IV) to Pu(III). The Pu(III) is readily separated from uranium in solution in the tri-n-butyl phosphate by an aqueous strip.

  19. Anhydrous aluminum chloride as an alkylation catalyst: identification of mono- and dialkyl-benzenes from the condensation of tertiary butyl alcohol with benzene. 

    E-Print Network [OSTI]

    Scoggins, Lacey E

    1959-01-01

    - alkyl and polyalkyl derivatives. The percentage yield, of monoalkyl derivatives is dependent upon the alcohol, dehydrating agent and. the activation of the aromatic nuclei Anhydrous ferric and alusdnum chloride, hydrogen fluoride with phosphorous...-butyl alcohol with 'benzene in the presence of i'erric chloride and. a 5g yield using aluminum chloride under the same conditions. Simons and. Archer5 reacted t-butyl alcohol with 'benzene using hydrogen fluoride as an alkylation catalyst, obtaining 4Q...

  20. Features of the spectral dependences of transmittance of organic semiconductors based on tert-butyl substituted lutetium phthalocyanine molecules

    SciTech Connect (OSTI)

    Belogorokhov, I. A.; Tikhonov, E. V.; Dronov, M. A.; Belogorokhova, L. I.; Ryabchikov, Yu. V.; Tomilova, L. G.; Khokhlov, D. R.

    2011-11-15

    Vibronic properties of organic semiconductors based on tert-butyl substituted phthalocyanine lutetium diphthalocyanine molecules are studied by IR and Raman spectroscopy. It is shown that substitution of several carbon atoms in initial phthalocyanine (Pc) ligands with {sup 13}C isotope atoms causes a spectral shift in the main absorption lines attributed to benzene, isoindol, and peripheral C-H groups. A comparison of spectral characteristics showed that the shift can vary from 3 to 1 cm{sup -1}.

  1. DIMETHYL ETHER (DME)-FUELED SHUTTLE BUS DEMONSTRATION PROJECT

    SciTech Connect (OSTI)

    Elana M. Chapman; Shirish Bhide; Jennifer Stefanik; Howard Glunt; Andre L. Boehman; Allen Homan; David Klinikowski

    2003-04-01

    The objectives of this research and demonstration program are to convert a campus shuttle bus to operation on dimethyl ether, a potential ultra-clean alternative diesel fuel. To accomplish this objective, this project includes laboratory evaluation of a fuel conversion strategy, as well as, field demonstration of the DME-fueled shuttle bus. Since DME is a fuel with no lubricity (i.e., it does not possess the lubricating quality of diesel fuel), conventional fuel delivery and fuel injection systems are not compatible with dimethylether. Therefore, to operate a diesel engine on DME one must develop a fuel-tolerant injection system, or find a way to provide the necessary lubricity to the DME. In this project, they have chosen the latter strategy in order to achieve the objective with minimal need to modify the engine. The strategy is to blend DME with diesel fuel, to obtain the necessary lubricity to protect the fuel injection system and to achieve low emissions. The bulk of the efforts over the past year were focused on the conversion of the campus shuttle bus. This process, started in August 2001, took until April 2002 to complete. The process culminated in an event to celebrate the launching of the shuttle bus on DME-diesel operation on April 19, 2002. The design of the system on the shuttle bus was patterned after the system developed in the engine laboratory, but also was subjected to a rigorous failure modes effects analysis with help from Dr. James Hansel of Air Products. The result of this FMEA was the addition of layers of redundancy and over-pressure protection to the system on the shuttle bus. The system became operation in February 2002. Preliminary emissions tests and basic operation of the shuttle bus took place at the Pennsylvania Transportation institute's test track facility near the University Park airport. After modification and optimization of the system on the bus, operation on the campus shuttle route began in early June 2002. However, the work and challenges have continued as it has been difficult to maintain operability of the shuttle bus due to fuel and component difficulties. As of late June 2002, it appears that the pump head itself developed operational problems (loss of smooth function) leading to excessive stress on the magnetic coupling and excessive current draw to operate. A new pump head is being installed on the system to alleviate this problem and get the shuttle bus back in operation. In summary, the conversion is completed but there have been operational challenges in the field. They continue to work to make the shuttle bus as reliable to operate on DME-diesel blends as possible.

  2. Photochemical dimerization and functionalization of alkanes, ethers, primary and secondary alcohols, phosphine oxides and silanes

    DOE Patents [OSTI]

    Crabtree, R.H.; Brown, S.H.

    1989-10-17

    The space-time yield and/or the selectivity of the photochemical dimerization of alkanes, ethers, primary and secondary alcohols, phosphine oxides and primary, secondary and tertiary silanes with Hg and U.V. light is enhanced by refluxing the substrate in the irradiated reaction zone at a temperature at which the dimer product condenses and remains condensed promptly upon its formation. Cross-dimerization of the alkanes, ethers and silanes with primary alcohols is disclosed, as is the functionalization to aldehydes of the alkanes with carbon monoxide.

  3. Catalyst system and process for benzyl ether fragmentation and coal liquefaction

    DOE Patents [OSTI]

    Zoeller, Joseph Robert (Kingsport, TN)

    1998-04-28

    Dibenzyl ether can be readily cleaved to form primarily benzaldehyde and toluene as products, along with minor amounts of bibenzyl and benzyl benzoate, in the presence of a catalyst system comprising a Group 6 metal, preferably molybdenum, a salt, and an organic halide. Although useful synthetically for the cleavage of benzyl ethers, this cleavage also represents a key model reaction for the liquefaction of coal; thus this catalyst system and process should be useful in coal liquefaction with the advantage of operating at significantly lower temperatures and pressures.

  4. Multiprobe Spectroscopic Evidence for "Hyperpolarity" within 1-Butyl-3-methylimidazolium Hexafluorophosphate Mixtures with Tetraethylene Glycol

    SciTech Connect (OSTI)

    Sarkar, Abhra [Indian Institute of Technology, Delhi; Trivedi, Shruti [Indian Institute of Technology, Delhi; Baker, Gary A [ORNL; Pandey, Siddharth [Indian Institute of Technology, Delhi

    2008-01-01

    A hybrid, potentially green solvent system composed of tetraethylene glycol (TEG) and the ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate ([bmim][PF6]) was investigated across all mole fractions with regard to the solvent properties of the mixture. For this purpose, a suite of absorbance- and fluorescence-based solvatochromic probes were utilized to explore solute-solvent and solvent-solvent interactions existing within the [bmim][PF6] + TEG system. These studies revealed an interesting and unusual synergistic solvent effect. In particular, a remarkable hyperpolarity was observed in which the ET value, comprising dipolarity/polarizability and hydrogen bond donor (HBD) acidity contributions, at intermediate mole fractions of the binary mixture well exceeded that of the most polar pure component (i.e., [bmim][PF6]). Independently determined dipolarity/polarizability ( *) and HBD acidity (R) Kamlet-Taft values for the [bmim][PF6] + TEG mixtures were also observed to be anomalously high at intermediate mole fractions, whereas hydrogen bond acceptor (HBA) basicities ( values) were much more in line with the ideal arithmetic values predicted on a mole fraction basis.

  5. N-butyl Cyanoacrylate Glue Embolization of Arterial Networks to Facilitate Hepatic Arterial Skeletonization before Radioembolization

    SciTech Connect (OSTI)

    Samuelson, Shaun D.; Louie, John D.; Sze, Daniel Y.

    2013-06-15

    Purpose. Avoidance of nontarget microsphere deposition via hepatoenteric anastomoses is essential to the safety of yttrium-90 radioembolization (RE). The hepatic hilar arterial network may remain partially patent after coil embolization of major arteries, resulting in persistent risk. We retrospectively reviewed cases where n-butyl cyanoacrylate (n-BCA) glue embolization was used to facilitate endovascular hepatic arterial skeletonization before RE. Methods. A total of 543 RE procedures performed between June 2004 and March 2012 were reviewed, and 10 were identified where n-BCA was used to embolize hepatoenteric anastomoses. Arterial anatomy, prior coil embolization, and technical details were recorded. Outcomes were reviewed to identify subsequent complications of n-BCA embolization or nontarget RE. Results. The rate of complete technical success was 80 % and partial success 20 %, with one nontarget embolization complication resulting in a minor change in treatment plan. No evidence of gastrointestinal or biliary ischemia or infarction was identified, and no microsphere-related gastroduodenal ulcerations or other evidence of nontarget RE were seen. Median volume of n-BCA used was <0.1 ml. Conclusion. n-BCA glue embolization is useful to eliminate hepatoenteric networks that may result in nontarget RE, especially in those that persist after coil embolization of major vessels such as the gastroduodenal and right gastric arteries.

  6. MTBE Production Economics (Released in the STEO April 2001)

    Reports and Publications (EIA)

    2001-01-01

    The purpose of this analysis is to evaluate the causes of methyl tertiary butyl ether (MTBE) price increases in 2000.

  7. Ether Phospholipids and Glycosylinositolphospholipids Are Not Required for Amastigote Virulence or for Inhibition of Macrophage

    E-Print Network [OSTI]

    Beverley, Stephen M.

    im- plicated in virulence, such as lipophosphoglycan (LPG), smaller glycosylinositolphospholipids plasmalogens, LPG, and GIPLs. Leishmania ads1 thus represents the first ether lipid-synthesizing eukaryote (detergent- resistant membranes). In virulence tests it closely re- sembled LPG-deficient L. major, including

  8. Structural Requirements and Reaction Pathways in Dimethyl Ether Combustion Catalyzed by Supported Pt Clusters

    E-Print Network [OSTI]

    Iglesia, Enrique

    of the elementary steps required for catalytic combustion of dimethyl ether (DME) on Pt clusters were determined in developing economies. Recent studies have addressed steam reforming of DME on supported metal catalysts4-7 and its homogeneous combustion pathways via radical intermedi- ates.8,9 Here, we explore the catalytic

  9. Kinetics and Mechanism of Dimethyl Ether Oxidation to Formaldehyde on Supported Molybdenum Oxide Domains

    E-Print Network [OSTI]

    Iglesia, Enrique

    Kinetics and Mechanism of Dimethyl Ether Oxidation to Formaldehyde on Supported Molybdenum Oxide to formaldehyde (HCHO) on MoOx/Al2O3. The reaction intermediates and elementary steps established a redox to alkenes and oxygenates too costly for practical implementation. Oxygenates, such as formaldehyde (HCHO

  10. Lithium Hexamethyldisilazide-Mediated Ketone Enolization: The Influence of Hindered Dialkyl Ethers and Isostructural

    E-Print Network [OSTI]

    Collum, David B.

    Lithium Hexamethyldisilazide-Mediated Ketone Enolization: The Influence of Hindered Dialkyl Ethers of the enolization of 2-methylcyclohexanone mediated by lithium hexameth- yldisilazide (LiHMDS; TMS2NLi) solvated- bine to make lithium hexamethyldisilazide (LiHMDS) one of the most important Bro¨nsted bases in organic

  11. Mild and General Palladium-Catalyzed Synthesis of Methyl Aryl Ethers Enabled by the Use of a Palladacycle Precatalyst

    E-Print Network [OSTI]

    Cheung, Chi Wai

    A general method for the Pd-catalyzed coupling of methanol with (hetero)aryl halides is described. The reactions proceed under mild conditions with a wide range of aryl and heteroaryl halides to give methyl aryl ethers in ...

  12. Ureteric Embolization for Lower Urinary Tract Fistulae: Use of Two Amplatzer Vascular Plugs and N-Butyl Cyanoacrylate Employing the 'Sandwich' Technique

    SciTech Connect (OSTI)

    Saad, Wael E. A., E-mail: ws6r@virginia.edu; Kalagher, S.; Turba, U. C.; Sabri, S. S.; Park, A.-W.; Stone, J.; Angle, J. F.; Matsumoto, A. H. [University of Virginia Health System, Department of Radiology and Medical Imaging, Division of Vascular Interventional Radiology (United States)

    2013-08-01

    PurposeThis study describes and evaluated the effectiveness of occluding distal ureters in the clinical setting of urinary vaginal (vesicovaginal or enterovesicovaginal) fistulae utilizing a new technique which combines Amplatzer vascular plugs and N-butyl cyanoacrylate.MaterialsThis is a retrospective study (January 2007-December 2010) of patients with urinary-vaginal fistulae undergoing distal ureter embolization utilizing an Amplatzer- N-butyl cyanoacrylate-Amplatzer sandwich technique. An 8-12-mm type-I or type-II Amplatzer vascular plug was delivered using the sheath and deployed in the ureter distal to the pelvic brim. Instillation of 0.8-1.5 cc of N-butyl cyanoacrylate into ureter proximal to the Amplatzer plug was performed. This was followed by another set of 8-12-mm type-I or type-II Amplatzer vascular plugs in a technique referred to as the 'sandwich technique.'ResultsFive ureters in three patients were occluded utilizing the above-described technique during the 4-year study period. Mean maximum size Amplatzer used per ureter was 10.8 mm (range, 8-12). One ureter required three Amplatzer plugs and the rest required two. Two patients (3 ureters) were clinically successful with complete resolution of symptoms in 36-48 h. The third patient (2 ureters) was partly successful and required a second Amplatzer- N-butyl cyanoacrylate sandwich technique embolization. The mean clinical follow-up was 11.3 months (range, 1.7-29.2).ConclusionsThe Amplatzer- N-butyl cyanoacrylate-Amplatzer sandwich technique for occluding the distal ureter is safe and effective with a quick (probably due to the N-butyl cyanoacrylate) and durable (probably due to the Amplatzer plugs) clinical response.

  13. Molecular Simulation of Water Extraction into a Tri-n-Butyl-Phosphate/n-Dodecane Solution

    SciTech Connect (OSTI)

    de Almeida, Valmor F [ORNL] [ORNL; Ye, Xianggui [ORNL] [ORNL; Cui, Shengting [ORNL] [ORNL; Khomami, Bamin [ORNL] [ORNL

    2013-01-01

    Abstract: Molecular dynamics simulations were performed to investigate water extraction into a solution of 30 vol% tri-n-butyl-phosphate (TBP) in n-dodecane. This solvent extraction mixture is commonly used in hydrometallurgical and nuclear fuel recycling operations for recovering metals from aqueous streams. It is known that water is coextracted in the organic phase and that it competes with metal ions for the available extractant agent (TBP). Therefore investigating pure water extraction provides a realistic prototype to test molecular simulation methods for the first time in this area. Our computational results indicate that the TBP electric dipole moment has a significant effect on the predicted water solubility. A larger TBP dipole moment decreases the aqueous-organic interfacial tension, leading to increased roughness of the aqueous-organic interface. Interfacial roughness has a significant effect on disrupting the interfacial water hydrogen bonding structure, resulting in a greater number of dangling water molecules at the interface. This enhances the probability of water molecules to break away from the aqueous phase and to migrate into the bulk of the organic phase. Therefore, the magnitude of the TBP dipole moment is a crucial factor in controlling water hydrogen bond breaking at the aqueous-organic interface. By slightly lowering the atomic partial charges of the TBP atoms, to produce a dipole moment that better agrees with experimental data, we were able to predict water solubility in close agreement with experimental measurements. Hence we demonstrate that a molecular modeling and simulation approach may provide quantitative support to experimental programs in this area. In addition, our simulation results shed light into the molecular mechanism of water extraction, the critical role of TBP, and the structural forms of water molecules both at the interface and in the bulk of the organic phase. Specifically, it is found that water molecules are extracted either as single molecules or as clusters. Furthermore, within the organic phase, the extracted water forms clusters with up to 20 water molecules, however, more than 70% of these water clusters contain less than 5 water molecules when the water extraction process reaches saturation.

  14. Process to convert biomass and refuse derived fuel to ethers and/or alcohols

    DOE Patents [OSTI]

    Diebold, J.P.; Scahill, J.W.; Chum, H.L.; Evans, R.J.; Rejai, B.; Bain, R.L.; Overend, R.P.

    1996-04-02

    A process is described for conversion of a feedstock selected from the group consisting of biomass and refuse derived fuel (RDF) to provide reformulated gasoline components comprising a substantial amount of materials selected from the group consisting of ethers, alcohols, or mixtures thereof, comprising: drying said feedstock; subjecting said dried feedstock to fast pyrolysis using a vortex reactor or other means; catalytically cracking vapors resulting from said pyrolysis using a zeolite catalyst; condensing any aromatic byproduct fraction; catalytically alkylating any benzene present in said vapors after condensation; catalytically oligomerizing any remaining ethylene and propylene to higher olefins; isomerizing said olefins to reactive iso-olefins; and catalytically reacting said iso-olefins with an alcohol to form ethers or with water to form alcohols. 35 figs.

  15. Process to convert biomass and refuse derived fuel to ethers and/or alcohols

    DOE Patents [OSTI]

    Diebold, James P. (Lakewood, CO); Scahill, John W. (Evergreen, CO); Chum, Helena L. (Arvada, CO); Evans, Robert J. (Lakewood, CO); Rejai, Bahman (Lakewood, CO); Bain, Richard L. (Golden, CO); Overend, Ralph P. (Lakewood, CO)

    1996-01-01

    A process for conversion of a feedstock selected from the group consisting of biomass and refuse derived fuel (RDF) to provide reformulated gasoline components comprising a substantial amount of materials selected from the group consisting of ethers, alcohols, or mixtures thereof, comprising: drying said feedstock; subjecting said dried feedstock to fast pyrolysis using a vortex reactor or other means; catalytically cracking vapors resulting from said pyrolysis using a zeolite catalyst; condensing any aromatic byproduct fraction; catalytically alkylating any benzene present in said vapors after condensation; catalytically oligomerizing any remaining ethylene and propylene to higher olefins; isomerizing said olefins to reactive iso-olefins; and catalytically reacting said iso-olefins with an alcohol to form ethers or with water to form alcohols.

  16. The Total Fatty Acids and Other Ether-Soluable Constituents of Feedstuffs. 

    E-Print Network [OSTI]

    Rather, J. B. (James Burness)

    1914-01-01

    . Percentage of Fatty Acids in Feedstuffs and Excrements by Various Methods. Labora? tory No. Ether extract. Fatty acids in ether extract. ?a.3 ? g S | . 2 5 a a'-"a _ Differ? ence (B-A) Diges? tion Method. Precipi? tation Method. O O... Q'S'o'cS ? "3 Is E-i . c *= =? a J=! ^ c3 12996 3.79 3.08 0.37 3.45 4.43 0 98 12999 4.31 3.77 0.16 3.93 4.34 0 41 13021 15.23 13.82 0.69 14.51 14.46 -0 05 13023 7.75 6 .2 1 0.39 6.60 8 . 1 0 1 50 13030 3.22 2.05 0.37 2.42 2.92 0 50 13045...

  17. solved in an organic solvent and diethyl ether was the most appropriate. The solvent

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    , the growth was hampe- red by a too large portion of wax. For detecting spores in beeswax, the wax was put into water (wax/water 1:10). The receptacle was placed into a water bath hea- ted up to 90 °C for 6 min, under the wax dissolved in diethyl ether. 80 ?L of this solution was smeared onto a plate with MYP

  18. 2[prime] and 3[prime] Carboranyl uridines and their diethyl ether adducts

    DOE Patents [OSTI]

    Soloway, A.H.; Barth, R.F.; Anisuzzaman, A.K.; Alam, F.; Tjarks, W.

    1992-12-15

    A process is described for preparing carboranyl uridine nucleoside compounds and their diethyl ether adducts, which exhibit a tenfold increase in boron content over prior art boron containing nucleoside compounds. The carboranyl uridine nucleoside compounds exhibit enhanced lipophilicity and hydrophilic properties adequate to enable solvation in aqueous media for subsequent incorporation of the compounds in methods for boron neutron capture therapy in mammalian tumor cells. No Drawings

  19. Molecular modeling of the morphology and transport properties of two direct methanol fuel cell membranes: phenylated sulfonated poly(ether ether ketone ketone) versus Nafion

    SciTech Connect (OSTI)

    Devanathan, Ramaswami; Idupulapati, Nagesh B.; Dupuis, Michel

    2012-08-14

    We have used molecular dynamics simulations to examine membrane morphology and the transport of water, methanol and hydronium in phenylated sulfonated poly ether ether ketone ketone (Ph-SPEEKK) and Nafion membranes at 360 K for a range of hydration levels. At comparable hydration levels, the pore diameter is smaller, the sulfonate groups are more closely packed, the hydronium ions are more strongly bound to sulfonate groups, and the diffusion of water and hydronium is slower in Ph-SPEEKK relative to the corresponding properties in Nafion. The aromatic carbon backbone of Ph-SPEEKK is less hydrophobic than the fluorocarbon backbone of Nafion. Water network percolation occurs at a hydration level ({lambda}) of {approx}8 H{sub 2}O/SO{sub 3}{sup -}. At {lambda} = 20, water, methanol and hydronium diffusion coefficients were 1.4 x 10{sup -5}, 0.6 x 10{sup -5} and 0.2 x 10{sup -5} cm{sup 2}/s, respectively. The pore network in Ph-SPEEKK evolves dynamically and develops wide pores for {lambda} > 20, which leads to a jump in methanol crossover and ion transport. This study demonstrates the potential of aromatic membranes as low-cost challengers to Nafion for direct methanol fuel cell applications and the need to develop innovative strategies to combat methanol crossover at high hydration levels.

  20. Barrierless proton transfer across weak CH?O hydrogen bonds in dimethyl ether dimer

    SciTech Connect (OSTI)

    Yoder, Bruce L. West, Adam H. C.; Signorell, Ruth; Bravaya, Ksenia B.; Bodi, Andras; Sztáray, Bálint

    2015-03-21

    We present a combined computational and threshold photoelectron photoion coincidence study of two isotopologues of dimethyl ether, (DME ? h{sub 6}){sub n} and (DME ? d{sub 6}){sub n}n = 1 and 2, in the 9–14 eV photon energy range. Multiple isomers of neutral dimethyl ether dimer were considered, all of which may be present, and exhibited varying C–H?O interactions. Results from electronic structure calculations predict that all of them undergo barrierless proton transfer upon photoionization to the ground electronic state of the cation. In fact, all neutral isomers were found to relax to the same radical cation structure. The lowest energy dissociative photoionization channel of the dimer leads to CH{sub 3}OHCH{sub 3}{sup +} by the loss of CH{sub 2}OCH{sub 3} with a 0 K appearance energy of 9.71 ± 0.03 eV and 9.73 ± 0.03 eV for (DME ? h{sub 6}){sub 2} and deuterated (DME ? d{sub 6}){sub 2}, respectively. The ground state threshold photoelectron spectrum band of the dimethyl ether dimer is broad and exhibits no vibrational structure. Dimerization results in a 350 meV decrease of the valence band appearance energy, a 140 meV decrease of the band maximum, thus an almost twofold increase in the ground state band width, compared with DME ? d{sub 6} monomer.

  1. Improvement of performance and emissions of a compression ignition methanol engine with dimethyl ether

    SciTech Connect (OSTI)

    Guo, J.; Chikahisa, Takemi; Murayama, Tadashi; Miyano, Masaharu

    1994-10-01

    Dimethyl ether (DME) has very good compression ignition characteristics and can be converted from methanol using a {gamma}-alumina catalyst. In this study a torch ignition chamber (TIC) head with TIC close to the center of the main combustion chamber was designed for the TIC method. The possibility of improvements in reducing the quantities of DME and emission were investigated by optimizing the TIC position, methanol injection timing, DME injection timing, and intake and exhaust throttling. It was found that the necessary amount of DME was greatly reduced when optimizing methanol and DME injection timings. 2 refs., 16 figs., 1 tab.

  2. A laser and molecular beam mass spectrometer study of low-pressure dimethyl ether flames

    SciTech Connect (OSTI)

    Andrew McIlroy; Toby D. Hain; Hope A. Michelsen; Terrill A. Cool

    2000-12-15

    The oxidation of dimethyl ether (DME) is studied in low-pressure flames using new molecular beam mass spectrometer and laser diagnostics. Two 30.0-Torr, premixed DME/oxygen/argon flames are investigated with stoichiometries of 0.98 and 1.20. The height above burner profiles of nine stable species and two radicals are measured. These results are compared to the detailed chemical reaction mechanism of Curran and coworkers. Generally good agreement is found between the model and data. The largest discrepancies are found for the methyl radical profiles where the model predicts qualitatively different trends in the methyl concentration with stoichiometry than observed in the experiment.

  3. High octane ethers from synthesis gas-derived alcohols. Quarterly technical progress report, April--June 1993

    SciTech Connect (OSTI)

    Klier, K.; Herman, R.G.; Menszak, J.; Johansson, M.A.; Feeley, O.C.; Kim, D.

    1993-07-01

    The results shown in Figures 10 and 11 demonstrate that the formation of butenes was very sensitive to the alcohol partial pressure. A small elevation of the alcohol pressure suppressed the formation of butenes rather drastically at both 90 and 117{degree}C. The synthesis rates of DME, MIBE, and MTBE ethers were not significantly affected at 90{degree}C, although there was a trend to increase the space time yield of DME as the alcohol pressure was increased. At the reaction temperature of 117{degree}C, all of the ethers showed increasing productivities as the pressure of the reactants was increased (Figure 11). An isotope labelling experiment was carried out to provide mechanistic insight into the manner in which methanol and isobutanol react together to form DME, MIBE, and MTBE ethers and to determine if MTBE were derived from MIBE.

  4. Mechanistic details of acid-catalyzed reactions and their role in the selective synthesis of triptane and isobutane from dimethyl ether

    E-Print Network [OSTI]

    Iglesia, Enrique

    and dimethyl ether (DME) to hydro- carbons provides a potential route to transportation fuels from C1 Transportation fuels a b s t r a c t We report here kinetic and isotopic evidence for the elementary steps involved in dimethyl ether (DME) homologation and for their role in the preferential synthesis of 2

  5. Calixarene crown ether solvent composition and use thereof for extraction of cesium from alkaline waste solutions

    DOE Patents [OSTI]

    Moyer, Bruce A. (Oak Ridge, TN); Sachleben, Richard A. (Knoxville, TN); Bonnesen, Peter V. (Knoxville, TN); Presley, Derek J. (Ooltewah, TN)

    2001-01-01

    A solvent composition and corresponding method for extracting cesium (Cs) from aqueous neutral and alkaline solutions containing Cs and perhaps other competing metal ions is described. The method entails contacting an aqueous Cs-containing solution with a solvent consisting of a specific class of lipophilic calix[4]arene-crown ether extractants dissolved in a hydrocarbon-based diluent containing a specific class of alkyl-aromatic ether alcohols as modifiers. The cesium values are subsequently recovered from the extractant, and the solvent subsequently recycled, by contacting the Cs-containing organic solution with an aqueous stripping solution. This combined extraction and stripping method is especially useful as a process for removal of the radionuclide cesium-137 from highly alkaline waste solutions which are also very concentrated in sodium and potassium. No pre-treatment of the waste solution is necessary, and the cesium can be recovered using a safe and inexpensive stripping process using water, dilute (millimolar) acid solutions, or dilute (millimolar) salt solutions. An important application for this invention would be treatment of alkaline nuclear tank wastes. Alternatively, the invention could be applied to decontamination of acidic reprocessing wastes containing cesium-137.

  6. Catalyst activity maintenance study for the liquid phase dimethyl ether process

    SciTech Connect (OSTI)

    Peng, X.D.; Toseland, B.A.; Underwood, R.P.

    1995-12-31

    The co-production of dimethyl ether (DME) and methanol from syngas is a process of considerable commercial attractiveness. DME coproduction can double the productivity of a LPMEOH process when using coal-derived syngas. This in itself may offer chemical producers and power companies increased flexibility and more profitable operation. DME is also known as a clean burning liquid fuel; Amoco and Haldor-Topsoe have recently announced the use of DME as an alternative diesel fuel. Moreover, DME can be an interesting intermediate in the production of chemicals such as olefins and vinyl acetate. The current APCl liquid phase dimethyl ether (LPDME) process utilizes a physical mixture of a commercial methanol synthesis catalyst and a dehydration catalyst (e.g., {gamma}-alumina). While this arrangement provides a synergy that results in much higher syngas conversion per pass compared to the methanol-only process, the stability of the catalyst system suffers. The present project is aimed at reducing catalyst deactivation both by understanding the cause(s) of catalyst deactivation and by developing modified catalyst systems. This paper describes the current understanding of the deactivation mechanism.

  7. Thesis proposal CSF Brazil 2014 Synthesis of new cellulose ethers using metathesis reactions -Study of their properties

    E-Print Network [OSTI]

    Bordenave, Charles

    , hydroxyle or amine functions. Their synthesis process generally needs a pre-treatment of the cellulose, hydroxyle or amine functions. Their synthesis process generally needs a pre-treatment of the cellulose of the hydroxyl of cellulose ethers, which are commercially available or described in the literature

  8. Laser Light-Scattering Study of Novel Thermoplastics. 2. Phenolphthalein Poly(ether sulfone) (PES-C)

    E-Print Network [OSTI]

    Wu, Chi

    Laser Light-Scattering Study of Novel Thermoplastics. 2. Phenolphthalein Poly(ether sulfone) (PES with that obtained from static laser light-scattering measurements. Introduction High-performance thermoplastics be dissolved in concentrated H2SO4, HSO3Cl, and CH3SO3H.6,7 Previously, we have studied a thermoplastic: phe

  9. Rate-Dependent Adhesion between Opposed Perfluoropoly(alkyl ether) Layers: Dependence on Chain-End Functionality and Chain Length

    E-Print Network [OSTI]

    Granick, Steve

    Rate-Dependent Adhesion between Opposed Perfluoropoly(alkyl ether) Layers: Dependence on Chain, UniVersity of Illinois, Urbana-Champaign, Urbana, Illinois 61801 ReceiVed: February 27, 1998 Adhesion, with particular attention to the dependence of the adhesion on chain-end functionality and chain length

  10. Title: Decomposition of ethanol and dimethyl-ether during CVD synthesis of single-walled carbon nanotubes

    E-Print Network [OSTI]

    Maruyama, Shigeo

    of ethanol and dimethyl-ether during CVD synthesis of single-walled carbon nanotubes Author list: Bo Hou (single-walled carbon nanotubes) was investigated. Gas-phase thermal decomposition of ethanol and DME ethanol and DME decomposition, confirming expected reaction trends and primary byproducts. Peak

  11. Bifunctional pathways mediated by Pt clusters and Al2O3 in the catalytic combustion of dimethyl ether{

    E-Print Network [OSTI]

    Iglesia, Enrique

    generation with small turbines or fuel cells.5­7 We have recently examined the catalytic combustion of DME Mixtures of Pt clusters dispersed on c-Al2O3 and additional c-Al2O3 led to much higher DME combustion. The physical properties of dimethyl ether (DME) resemble those of liquefied petroleum gas (LPG), making

  12. Physical Plant Power Plant - 32 

    E-Print Network [OSTI]

    Unknown

    2005-06-30

    Historically, a fixed cooling concept is used in the design of evaporative heat rejection systems for process and power plants. In the fixed cooling mode, a plant is designed for maximum output at the design summer wet bulb temperature...

  13. Process for the production of ethylidene diacetate from dimethyl ether using a heterogeneous catalyst

    DOE Patents [OSTI]

    Ramprasad, D.; Waller, F.J.

    1998-04-28

    This invention relates to a process for producing ethylidene diacetate by the reaction of dimethyl ether, acetic acid, hydrogen and carbon monoxide at elevated temperatures and pressures in the presence of an alkyl halide and a heterogeneous, bifunctional catalyst that is stable to hydrogenation and comprises an insoluble polymer having pendant quaternized heteroatoms, some of which heteroatoms are ionically bonded to anionic Group VIII metal complexes, the remainder of the heteroatoms being bonded to iodide. In contrast to prior art processes, no accelerator (promoter) is necessary to achieve the catalytic reaction and the products are easily separated from the catalyst by filtration. The catalyst can be recycled for 3 consecutive runs without loss in activity.

  14. Process for the production of ethylidene diacetate from dimethyl ether using a heterogeneous catalyst

    DOE Patents [OSTI]

    Ramprasad, Dorai (Allentown, PA); Waller, Francis Joseph (Allentown, PA)

    1998-01-01

    This invention relates to a process for producing ethylidene diacetate by the reaction of dimethyl ether, acetic acid, hydrogen and carbon monoxide at elevated temperatures and pressures in the presence of an alkyl halide and a heterogeneous, bifunctional catalyst that is stable to hydrogenation and comprises an insoluble polymer having pendant quaternized heteroatoms, some of which heteroatoms are ionically bonded to anionic Group VIII metal complexes, the remainder of the heteroatoms being bonded to iodide. In contrast to prior art processes, no accelerator (promoter) is necessary to achieve the catalytic reaction and the products are easily separated from the catalyst by filtration. The catalyst can be recycled for 3 consecutive runs without loss in activity.

  15. Use of aluminum phosphate as the dehydration catalyst in single step dimethyl ether process

    DOE Patents [OSTI]

    Peng, Xiang-Dong (Allentown, PA); Parris, Gene E. (Coopersburg, PA); Toseland, Bernard A. (Allentown, PA); Battavio, Paula J. (Allentown, PA)

    1998-01-01

    The present invention pertains to a process for the coproduction of methanol and dimethyl ether (DME) directly from a synthesis gas in a single step (hereafter, the "single step DME process"). In this process, the synthesis gas comprising hydrogen and carbon oxides is contacted with a dual catalyst system comprising a physical mixture of a methanol synthesis catalyst and a methanol dehydration catalyst. The present invention is an improvement to this process for providing an active and stable catalyst system. The improvement comprises the use of an aluminum phosphate based catalyst as the methanol dehydration catalyst. Due to its moderate acidity, such a catalyst avoids the coke formation and catalyst interaction problems associated with the conventional dual catalyst systems taught for the single step DME process.

  16. Using Heteropolyacids in the Anode Catalyst Layer of Dimethyl Ether PEM Fuel Cells

    SciTech Connect (OSTI)

    Ferrell III, J. R.; Turner, J. A.; Herring, A. M.

    2008-01-01

    In this study, polarization experiments were performed on a direct dimethyl ether fuel cell (DMEFC). The experimental setup allowed for independent control of water and DME flow rates. Thus the DME flow rate, backpressure, and water flow rate were optimized. Three heteropoly acids, phosphomolybdic acid (PMA), phosphotungstic acid (PTA), and silicotungstic acid (STA) were incorporated into the anode catalyst layer in combination with Pt/C. Both PTA-Pt and STA-Pt showed higher performance than the Pt control at 30 psig of backpressure. Anodic polarizations were also performed, and Tafel slopes were extracted from the data. The trends in the Tafel slope values are in agreement with the polarization data. The addition of phosphotungstic acid more than doubled the power density of the fuel cell, compared to the Pt control.

  17. Methanol with dimethyl ether ignition promotor as fuel for compression ignition engines

    SciTech Connect (OSTI)

    Brook, D.L.; Cipolat, D.; Rallis, C.J.

    1984-08-01

    Reduction of the world dependence upon crude oil necessitates the use of long term alternative fuels for internal combustion engines. Alcohols appear to offer a solution as in the short term they can be manufactured from natural gas and coal, while ultimately they may be produced from agricultural products. A fair measure of success has been achieved in using alcohols in spark ignition engines. However the more widely used compression ignition engines cannot utilize unmodified pure alcohols. The current techniques for using alcohol fuels in compression ignition engines all have a number of shortcomings. This paper describes a novel technique where an ignition promotor, dimethyl ether (DME), is used to increase the cetane rating of methanol. The systems particular advantage is that the DME can be catalyzed from the methanol base fuel, in situ. This fuel system matches the performance characteristics of diesel oil fuel.

  18. Hydrogen production from the steam reforming of Dinethyl Ether and Methanol

    SciTech Connect (OSTI)

    Semelsberger, T. A.; Borup, R. L.

    2004-01-01

    This study investigates dimethyl ether (DME) steam reforming for the generation of hydrogen rich fuel cell feeds for fuel cell applications. Methanol has long been considered as a fuel for the generation of hydrogen rich fuel cell feeds due to its high energy density, low reforming temperature, and zero impurity content. However, it has not been accepted as the fuel of choice due its current limited availability, toxicity and corrosiveness. While methanol steam reforming for the generation of hydrogen rich fuel cell feeds has been extensively studied, the steam reforming of DME, CH{sub 3}OCH{sub 3} + 3H{sub 2}O = 2CO{sub 2} + 6H{sub 2}, has had limited research effort. DME is the simplest ether (CH{sub 3}OCH{sub 3}) and is a gas at ambient conditions. DME has physical properties similar to those of LPG fuels (i.e. propane and butane), resulting in similar storage and handling considerations. DME is currently used as an aerosol propellant and has been considercd as a diesel substitute due to the reduced NOx, SOx and particulate emissions. DME is also being considered as a substitute for LPG fuels, which is used extensively in Asia as a fuel for heating and cooking, and naptha, which is used for power generation. The potential advantages of both methanol and DME include low reforming temperature, decreased fuel proccssor startup energy, environmentally benign, visible flame, high heating value, and ease of storage and transportation. In addition, DME has the added advantages of low toxicity and being non-corrosive. Consequently, DME may be an ideal candidate for the generation of hydrogen rich fuel cell feeds for both automotive and portable power applications. The steam reforming of DME has been demonstrated to occur through a pair of reactions in series, where the first reaction is DME hydration followed by MeOH steam reforming to produce a hydrogen rich stream.

  19. Characterization of the influence of 1-butyl-3-methylimidazolium chloride on the structure and thermal stability of green fluorescent protein

    SciTech Connect (OSTI)

    Heller, William T [ORNL; O'Neill, Hugh Michael [ORNL; Zhang, Qiu [ORNL; Baker, Gary A [ORNL

    2010-01-01

    Ionic liquids (ILs) are finding a vast array of applications as novel solvents for a wide variety of processes that include enzymatic chemistry, particularly as more biocompatible ILs are designed and discovered. While it is assumed that a native or near-native structure is required for enzymatic activity, there is some evidence that ILs alter protein structure and oligomerization states in a manner than can negatively impact function. The IL 1-butyl-3-methylimidazolium chloride, [bmim]Cl, is a well-studied, water-miscible member of the popular 1-alkyl-3-methylimidazolium IL family. To improve our understanding of the impact of water-miscible ILs on proteins, we have characterized the structure and oligomerization state of green fluorescent protein (GFP) in aqueous solutions containing 25 and 50 vol % [bmim]Cl using a combination of optical spectroscopy and small-angle neutron scattering (SANS). Measurements were also performed as a function of temperature to provide insight into the effect of the IL on the thermal stability of GFP. While GFP exists as a dimer in water, the presence of 25 vol % [bmim]Cl causes GFP to transition to a monomeric state. The SANS data indicate that GFP is a great deal less compact in 50 vol % [bmim]Cl than in neat water, indicative of unfolding from the native structure. The oligomerization state of the protein in IL-containing aqueous solution changes from a dimer to a monomer in response to the IL, but does not change as a function of temperature in the IL-containing solution. The SANS and spectroscopic results also demonstrate that the addition of [bmim]Cl to the solution decreases the thermal stability of GFP, allowing the protein to unfold at lower temperatures than in aqueous solution.

  20. Portal Vein Embolization before Right Hepatectomy: Improved Results Using n-Butyl-Cyanoacrylate Compared to Microparticles Plus Coils

    SciTech Connect (OSTI)

    Guiu, Boris Bize, Pierre; Gunthern, Daniel; Demartines, Nicolas; Halkic, Nermin; Denys, Alban

    2013-10-15

    Background: There is currently no consensus in the literature on which embolic agent induces the greatest degree of liver hypertrophy after portal vein embolization (PVE). Only experimental results in a pig model have demonstrated an advantage of n-butyl-cyanoacrylate (NBCA) over 3 other embolic materials (hydrophilic gel, small and large polyvinyl alcohol particles) for PVE. Therefore, the aim of this human study was to retrospectively compare the results of PVE using NBCA with those using spherical microparticles plus coils. Methods: A total of 34 patients underwent PVE using either NBCA (n = 20), or spherical microparticles plus coils (n = 14). PVE was decided according to preoperative volumetry on the basis of contrast-enhanced CT. Groups were compared for age, sex, volume of the left lobe before PVE and future remnant liver ratio (FRL) (volume of the left lobe/total liver volume - tumor volume). The primary end point was the increase in left lobe volume 1 month after PVE. Secondary end points were procedure complications and biological tolerance. Results: Both groups were similar in terms of age, sex ratio, left lobe volume, and FRL before PVE. NBCA induced a greater increase in volume after PVE than did microparticles plus coils (respectively, +74 {+-} 69 % and +23 {+-} 14 %, p < 0.05). The amount of contrast medium used for the procedure was significantly larger when microparticles and coils rather than NBCA were used (respectively, 264 {+-} 43 ml and 162 {+-} 34 ml, p < 0.01). The rate of PVE complications as well as the biological tolerance was similar in both groups. Conclusion: NBCA seems more effective than spherical microparticles plus coils to induce left-lobe hypertrophy.

  1. Zirconia-Supported MoOx Catalysts for the Selective Oxidation of Dimethyl Ether to Formaldehyde: Structure, Redox Properties, and Reaction Pathways

    E-Print Network [OSTI]

    Iglesia, Enrique

    Zirconia-Supported MoOx Catalysts for the Selective Oxidation of Dimethyl Ether to Formaldehyde* Department of Chemical Engineering, UniVersity of California at Berkeley, Berkeley, California 94720 Recei

  2. Modified cellulose synthase gene from Arabidopsis thaliana confers herbicide resistance to plants

    DOE Patents [OSTI]

    Somerville, Chris R. (Portola Valley, CA); Scheible, Wolf (Golm, DE)

    2007-07-10

    Cellulose synthase ("CS"), a key enzyme in the biosynthesis of cellulose in plants is inhibited by herbicides comprising thiazolidinones such as 5-tert-butyl-carbamoyloxy-3-(3-trifluromethyl)phenyl-4-thiazolidinone (TZ), isoxaben and 2,6-dichlorobenzonitrile (DCB). Two mutant genes encoding isoxaben and TZ-resistant cellulose synthase have been isolated from isoxaben and TZ-resistant Arabidopsis thaliana mutants. When compared with the gene coding for isoxaben or TZ-sensitive cellulose synthase, one of the resistant CS genes contains a point mutation, wherein glycine residue 998 is replaced by an aspartic acid. The other resistant mutation is due to a threonine to isoleucine change at amino acid residue 942. The mutant CS gene can be used to impart herbicide resistance to a plant; thereby permitting the utilization of the herbicide as a single application at a concentration which ensures the complete or substantially complete killing of weeds, while leaving the transgenic crop plant essentially undamaged.

  3. Modified cellulose synthase gene from 'Arabidopsis thaliana' confers herbicide resistance to plants

    SciTech Connect (OSTI)

    Somerville, Chris R.; Scieble, Wolf

    2000-10-11

    Cellulose synthase ('CS'), a key enzyme in the biosynthesis of cellulose in plants is inhibited by herbicides comprising thiazolidinones such as 5-tert-butyl-carbamoyloxy-3-(3-trifluromethyl) phenyl-4-thiazolidinone (TZ), isoxaben and 2,6-dichlorobenzonitrile (DCB). Two mutant genes encoding isoxaben and TZ-resistant cellulose synthase have been isolated from isoxaben and TZ-resistant Arabidopsis thaliana mutants. When compared with the gene coding for isoxaben or TZ-sensitive cellulose synthase, one of the resistant CS genes contains a point mutation, wherein glycine residue 998 is replaced by an aspartic acid. The other resistant mutation is due to a threonine to isoleucine change at amino acid residue 942. The mutant CS gene can be used to impart herbicide resistance to a plant; thereby permitting the utilization of the herbicide as a single application at a concentration which ensures the complete or substantially complete killing of weeds, while leaving the transgenic crop plant essentially undamaged.

  4. The use of dimethyl ether as a starting aid for methanol-fueled SI engines at low temperatures

    SciTech Connect (OSTI)

    Kozole, K.H.; Wallace, J.S

    1988-01-01

    Methanol-fueled SI engines have proven to be difficult to start at ambient temperatures below approximately 10/sup 0/C. The use of dimethyl ether (DME) is proposed to improve the cold starting performance of methanol-fueled SI engines. Tests to evaluate this idea were carried out with a modified single-cylinder CFR research engine having a compression ratio of 12:1. The engine was fueled with combinations of gaseous dimethyl ether and liquid methanol having DME mass fractions of 30%, 40%, 60% and 70%. For comparison, tests were also carried out with 100% methanol and with winter grade premium unleaded gasoline. Overall stoichiometric mixtures were used in all tests.

  5. Synthesis of dimethyl ether and alternative fuels in the liquid phase from coal-derived synthesis gas. Final technical report

    SciTech Connect (OSTI)

    Not Available

    1993-02-01

    Through the mid-1980s, Air Products has brought the liquid phase approach to a number of other synthesis gas reactions where effective heat management is a key issue. In 1989, in response to DOE`s PRDA No. DE-RA22-88PC88805, Air Products proposed a research and development program entitled ``Synthesis of Dimethyl Ether and Alternative Fuels in the Liquid Phase from Coal Derived Syngas.`` The proposal aimed at extending the LPMEOH experience to convert coal-derived synthesis gas to other useful fuels and chemicals. The work proposed included development of a novel one-step synthesis of dimethyl ether (DME) from syngas, and exploration of other liquid phase synthesis of alternative fuel directly from syngas. The one-step DME process, conceived in 1986 at Air Products as a means of increasing syngas conversion to liquid products, envisioned the concept of converting product methanol in situ to DME in a single reactor. The slurry reactor based liquid phase technology is ideally suited for such an application, since the second reaction (methanol to DME) can be accomplished by adding a second catalyst with dehydration activity to the methanol producing reactor. An area of exploration for other alternative fuels directly from syngas was single-step slurry phase synthesis of hydrocarbons via methanol and DME as intermediates. Other possibilities included the direct synthesis of mixed alcohols and mixed ethers in a slurry reactor.

  6. A fluorescence-based method for rapid and direct determination of polybrominated diphenyl ethers in water

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shan, Huimei; Liu, Chongxuan; Wang, Zheming; Ma, Teng; Shang, Jianying; Pan, Duoqiang

    2015-01-01

    A new method was developed for rapid and direct measurement of polybrominated diphenyl ethers (PBDEs) in aqueous samples using fluorescence spectroscopy. The fluorescence spectra of tri- to deca-BDE (BDE 28, 47, 99, 153, 190, and 209) commonly found in environment were measured at variable emission and excitation wavelengths. The results revealed that the PBDEs have distinct fluorescence spectral profiles and peak positions that can be exploited to identify these species and determine their concentrations in aqueous solutions. The detection limits as determined in deionized water spiked with PBDEs are 1.71-5.82 ng/L for BDE 28, BDE 47, BDE 190, and BDEmore »209 and 45.55–69.95 ng/L for BDE 99 and BDE 153. The effects of environmental variables including pH, humic substance, and groundwater chemical composition on PBDEs measurements were also investigated. These environmental variables affected fluorescence intensity, but their effect can be corrected through linear additivity and separation of spectral signal contribution. Compared with conventional GC-based analytical methods, the fluorescence spectroscopy method is more efficient as it only uses a small amount of samples (2-4 mL), avoids lengthy complicated concentration and extraction steps, and has a low detection limit of a few ng/L.« less

  7. A fluorescence-based method for rapid and direct determination of polybrominated diphenyl ethers in water

    SciTech Connect (OSTI)

    Shan, Huimei; Liu, Chongxuan; Wang, Zheming; Ma, Teng; Shang, Jianying; Pan, Duoqiang

    2015-01-01

    A new method was developed for rapid and direct measurement of polybrominated diphenyl ethers (PBDEs) in aqueous samples using fluorescence spectroscopy. The fluorescence spectra of tri- to deca-BDE (BDE 28, 47, 99, 153, 190, and 209) commonly found in environment were measured at variable emission and excitation wavelengths. The results revealed that the PBDEs have distinct fluorescence spectral profiles and peak positions that can be exploited to identify these species and determine their concentrations in aqueous solutions. The detection limits as determined in deionized water spiked with PBDEs are 1.71-5.82 ng/L for BDE 28, BDE 47, BDE 190, and BDE 209 and 45.55–69.95 ng/L for BDE 99 and BDE 153. The effects of environmental variables including pH, humic substance, and groundwater chemical composition on PBDEs measurements were also investigated. These environmental variables affected fluorescence intensity, but their effect can be corrected through linear additivity and separation of spectral signal contribution. Compared with conventional GC-based analytical methods, the fluorescence spectroscopy method is more efficient as it only uses a small amount of samples (2-4 mL), avoids lengthy complicated concentration and extraction steps, and has a low detection limit of a few ng/L.

  8. A Fluorescence-Based Method for Rapid and Direct Determination of Polybrominated Diphenyl Ethers in Water

    SciTech Connect (OSTI)

    Shan, Huimei [China Univ. of Geosciences, Wuhan (China). Lab of Basin and Wetland Eco-Restoration; Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Liu, Chongxuan [China Univ. of Geosciences, Wuhan (China). Lab of Basin and Wetland Eco-Restoration; Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Wang, Zheming [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Ma, Teng [China Univ. of Geosciences, Wuhan (China). Lab of Basin and Wetland Eco-Restoration and State Key Lab. of Biogeology and Environmental Geology; Shang, Jianying [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Pan, Duoqiang [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2015-01-01

    A new method was developed for rapid and direct measurement of polybrominated diphenyl ethers (PBDEs) in aqueous samples using fluorescence spectroscopy. The fluorescence spectra of tri- to deca-BDE (BDE 28, 47, 99, 153, 190, and 209) commonly found in environment were measured at variable emission and excitation wavelengths. The results revealed that the PBDEs have distinct fluorescence spectral profiles and peak positions that can be exploited to identify these species and determine their concentrations in aqueous solutions. The detection limits as determined in deionized water spiked with PBDEs are 1.71-5.82 ng/L for BDE 28, BDE 47, BDE 190, and BDE 209 and 45.55–69.95 ng/L for BDE 99 and BDE 153. The effects of environmental variables including pH, humic substance, and groundwater chemical composition on PBDEs measurements were also investigated. These environmental variables affected fluorescence intensity, but their effect can be corrected through linear additivity and separation of spectral signal contribution. Compared with conventional GC-based analytical methods, the fluorescence spectroscopy method is more efficient as it only uses a small amount of samples (2-4 mL), avoids lengthy complicated concentration and extraction steps, and has a low detection limit of a few ng/L.

  9. Study on systems based on coal and natural gas for producing dimethyl ether

    SciTech Connect (OSTI)

    Zhou, L.; Hu, S.Y.; Chen, D.J.; Li, Y.R.; Zhu, B.; Jin, Y.

    2009-04-15

    China is a coal-dependent country and will remain so for a long time. Dimethyl ether (DME), a potential substitute for liquid fuel, is a kind of clean diesel motor fuel. The production of DME from coal is meaningful and is studied in this article. Considering the C/H ratios of coal and natural gas (NG), the cofeed (coal and NG) system (CFS), which does not contain the water gas shift process, is studied. It can reduce CO{sub 2} emission and increase the conversion rate of carbon, producing more DME. The CFS is simulated and compared with the coal-based and NG-based systems with different recycling ratios. The part of the exhaust gas that is not recycled is burned, producing electricity. On the basis of the simulation results, the thermal efficiency, economic index, and CO{sub 2} emission ratio are calculated separately. The CFS with a 100% recycling ratio has the best comprehensive evaluation index, while the energy, economy, and environment were considered at the same time.

  10. Experimental and Computational Study of Nonpremixed Ignition of Dimethyl Ether in Counterflow

    SciTech Connect (OSTI)

    Zheng, X L; Lu, T F; Law, C K; Westbrook, C K

    2003-12-19

    The ignition temperature of nitrogen-diluted dimethyl ether (DME) by heated air in counterflow was experimentally determined for DME concentration from 5.9 to 30%, system pressure from 1.5 to 3.0 atmospheres, and pressure-weighted strain rate from 110 to 170/s. These experimental data were compared with two mechanisms that were respectively available in 1998 and 2003, with the latter being a substantially updated version of the former. The comparison showed that while the 1998-mechanism uniformly over-predicted the ignition temperature, the 2003-mechanism yielded surprisingly close agreement for all experimental data. Sensitivity analysis for the near-ignition state based on both mechanisms identified the deficiencies of the 1998-mechanism, particularly the specifics of the low-temperature cool flame chemistry in effecting ignition at higher temperatures, as the fuel stream is being progressively heated from its cold boundary to the high-temperature ignition region around the hot-stream boundary. The 2003-mechanism, consisting of 79 species and 398 elementary reactions, was then systematically simplified by using the directed relation graph method to a skeletal mechanism of 49 species and 251 elementary reactions, which in turn was further simplified by using computational singular perturbation method and quasi-steady-state species assumption to a reduced mechanism consisting of 33 species and 28 lumped reactions. It was demonstrated that both the skeletal and reduced mechanisms mimicked the performance of the detailed mechanism with high accuracy.

  11. Slurry phase synthesis of dimethyl ether from syngas -- A reactor model simulation

    SciTech Connect (OSTI)

    Mizuguchi, Masatsugu; Ogawa, Takashi; Ono, Masami,; Tomura, Keiji; Shikada, Tsutomu; Ohno, Yotaro; Fujimoto, Kaoru

    1998-12-31

    Dimethyl ether (DME) would be an attractive alternative fuel for diesel, domestic use, and power generation, if it is economically synthesized directly from syngas (derived from coal gasification or natural gas reforming). DME, which is a colorless gas with a boiling point of {minus}25 C, is chemically stable and easily liquefied under pressure. Since the properties of DME are similar to LPG, it can be handled and stored with the same manner as LPG. The authors have performed the slurry phase DME synthesis by using the 50 kg/day bench-scale unit. DME was synthesized at high yield from syngas (H{sub 2}+CO) with the newly developed catalyst system. To establish the scale-up methodology, the reactor simulation technique is essential. The authors developed a mathematical model of the slurry phase bubble column reactor for DME synthesis, which is based on their experimental results. The performance of a commercial-scale DME reactor was simulated by this model, and the results were discussed.

  12. Impact of Renewable Fuels Standard/MTBE Provisions of S. 517 Requested by Sens. Daschle & Murkowski

    Reports and Publications (EIA)

    2002-01-01

    Additional analysis of the impact of the Renewable Fuels Standard (RFS) and methyl tertiary butyl ether (MTBE) ban provisions of S. 517.

  13. TABLE33.CHP:Corel VENTURA

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    products are reported by the PAD District of entry. b Includes crude oil imported for storage in the Strategic Petroleum Reserve. c Includes ethyl tertiary butyl ether (ETBE),...

  14. TABLE34.CHP:Corel VENTURA

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    products are reported by the PAD District of entry. b Includes crude oil imported for storage in the Strategic Petroleum Reserve. c Includes ethyl tertiary butyl ether (ETBE),...

  15. Physical Plant Power Plant - 43 

    E-Print Network [OSTI]

    Unknown

    2005-06-30

    with higher efficiency / R&D Climate friendly Power Plants Build coal fired Power Plants with CCS-technology 4 B a c k u p va W GGEHEN ESL-IC-08-10-27 Proceedings of the Eighth International Conference for Enhanced Building Operations, Berlin, Germany..., October 20-22, 2008 RWE Energy / Energieeffizienz bei Immobilien / U. K?nig / ICEBO '08 SEITE 9 Electricity Production: All Energy Sources have to be included! Lignite Power Plant (BoA) produces 8,8 TWh = appr. 12% of the annual demand for electricity...

  16. ULEV potential of a DI/TCI diesel passenger car engine operated on dimethyl ether

    SciTech Connect (OSTI)

    Kapus, P.E.; Cartellieri, W.P.

    1995-12-31

    This paper describes a feasibility test program on a 2 liter, 4 cylinder DI/TCI passenger car engine operated on the new alternative fuel Dimethyl Ether (DME) with the aim of demonstrating its potential of meeting ULEV (ultra low emission vehicle) emissions (0.2 g/mi NOx in the FTP 75 test cycle) when installed in a full size passenger car. Special attention is drawn to the fuel injection equipment (FIE) as well as combustion system requirements towards the reduction of NOx and combustion noise while keeping energetic fuel consumption at the level of he baseline DI/TCI diesel engine. FIE and combustion system parameters were optimized on the steady state dynamometer by variation of a number of parameters, such as rate of injection, number of nozzle holes, compression ratio, piston bowl shape and exhaust gas recirculation. The paper presents engine test results achieved with DME under various operating conditions and compares these results to those achieved with the diesel version of the same engine.The FTP 75 cycle results were projected from steady state engine maps using a vehicle simulation program taking into account vehicle data and road resistance data of a given vehicle.The cycle results are also compared to actual chassis dynamometer results achieved with the diesel version of the same engine installed in the same vehicle.the passenger car DI/TCI engine adapted for and operated on DME shows very promising results with respect to meeting ULEV NOx emissions without any soot emissions and without the need for a DENOX catalyst. DME fuel consumption on energy basis can be kept very close to the DI diesel value. An oxidation catalyst will be necessary to meet the stringent CO and HC ULEV emission limits.

  17. Ligand-Thickness Effect Leads to Enhanced Preference for Large Anions in Alkali Metal Extraction by Crown Ethers

    SciTech Connect (OSTI)

    Haverlock, T.J.; Moyer, B.A.; Sachleben, R.A.

    1999-07-11

    Jean-Marie Lehn (Nobel laureate, 1987) suggested ligand thickness to be an important consideration in the design of host molecules for cation recognition. We have recently expanded the role of this simple ligand property by demonstrating a case in which ligand thickness contributes significantly to anion discrimination. It was found that in the extraction of sodium nitrate and perchlorate by a simple crown ether, bis(t-octylbenzo)-14-crown-4 (BOB 14C4), the normal preference for perchlorate is almost completely lost when the complex cation has the open-face sandwich vs. the sandwich structure.

  18. Primitive Land Plants 37 PRIMITIVE LAND PLANTS

    E-Print Network [OSTI]

    Koptur, Suzanne

    appeared at this time. Both of these groups of plants had life cycles, involving two generations. One of the year these mosses will produce tiny sporophytes. Prior to this generation, the tiny plants producedPrimitive Land Plants 37 PRIMITIVE LAND PLANTS These are the plants that were present soon after

  19. Determination of optical conductivity and different optical energy losses for non-crystalline Vanadyl tetra tert-butyl 2,3 Naphthalocyanine thinfilms

    SciTech Connect (OSTI)

    Dhanya, I.; Menon, C. S. [School of Pure and Applied Physics, Mahatma Gandhi University, Priyadarshini Hills, Kottayam, Kerala, 686 560 (India)

    2011-10-20

    Amorphous Vanadyl Tetra Tert Butyl 2, 3 naphthalocyanine thin films (VTTBNc) have been deposited using Physical Vapor Deposition technique. By analyzing the X-ray diffraction, the structure of as deposited films is found to be non-crystalline. Different optical properties of these thin films have been investigated by means of optical absorption and reflection spectra. Various optical constants like band gap energy, E{sub g} the width of band tails of localized states into the gap, E{sub U} and steepness parameter, {beta} gets calculated and the variation of different optical parameters like refractive index, extinction coefficient, dielectric constants, optical conductivity and surface and volume energy losses with photon energy are estimated.

  20. Development of alternative fuels from coal derived syngas. Topical report: Task 2.2, Demonstration of a one-step slurry-phase process for the production of dimethyl ether/methanol mixtures at the LaPorte Alternative Fuels Development Unit

    SciTech Connect (OSTI)

    Not Available

    1993-06-01

    This report documents engineering, modification, and operations efforts of demonstration of dimethyl-ether/methanol coproduction in a slurry-phase reactor, carried out in a 2-ft diameter bubble column reactor. Equipment modifications made it possible to remove the product DME and by-product CO{sub 2} from the reactor effluent. Coproduction of dimethyl-ether (DME) and methanol (MeOH) was accomplished in the slurry reactor by physically mixing two different catalysts. The catalyst used to produce MeOH from syngas was manufactured by BASF (type S3-86); the catalyst used to convert MeOH to DME was Catapal {gamma}-alumina. Ratio of MeOH to DME catalysts determined the selectivity towards DME. The demonstration sought to study effect of cocatalyst ratio on product selectivity. Three different proportions of DME catalyst were examined: 0, 6.6, and 19.3 wt % alumina. At each catalyst proportion, the plant was operated at two different gas space velocities. Some process variables were maintained at fixed conditions; most important variables included: reactor temperature (482F), reactor pressure (750 psig), and reactor feed gas composition (35% H{sub 2}, 51% CO,13% CO{sub 2} 1% other, nominal-molar basis).

  1. Coupling of alcohols to ethers: The dominance of the surface S{sub N}2 reaction pathway

    SciTech Connect (OSTI)

    Klier, K.; Feeley, O.C.; Johansson, M.; Herman, R.G.

    1996-12-31

    Coupling of alcohols to ethers, important high value oxygenates, proceeds on acid catalysts via general pathways that uniquely control product composition, oxygen retention, chirality inversion, and kinetics. The dominant pathway is the S{sub N}2 reaction with competition of the alcohols for the surface acid sites. This is exemplified by formation of methyl(ethyl) isobutylether (M(E)IBE) from methanol(ethanol)/isobutanol mixtures, retention of oxygen ({sup 18}O) of the heavier alcohol, and optimum rate as a function of concentration of either reactant alcohol. The S{sub N}2 pathway in the confinement of zeolite pores exhibits additional features of a near-100% selectivity to dimethylether (DME) in H-mordenite and a near-100% selectivity to chiral inversion in 2-pentanol/ethanol coupling to 2-ethoxypentane in HZSM-5. A minor reaction pathway entails olefin or carbenium intermediates, as exemplified by the formation of methyl tertiarybutyl ether (MTBE) from methanol/isobutanol mixtures with oxygen retention of the lighter alcohol. Calculations of transition state and molecular modeling of the oxonium-involving pathways dramatically demonstrate how the reaction path selects the products.

  2. Landscape Plants: Fertilizing & Watering

    E-Print Network [OSTI]

    Ishida, Yuko

    Landscape Plants: Fertilizing & Watering Landscape Plants: Fertilizing & Watering Prevent runoff and shrubs, either through directly killing plants or making them more prone to disease. Fertilizer runoff into storm drains pollutes waterways. Maintain plant health and protect water quality by fertilizing

  3. Polybrominated diphenyl ethers in e-waste: Level and transfer in a typical e-waste recycling site in Shanghai, Eastern China

    SciTech Connect (OSTI)

    Li, Yue; Duan, Yan-Ping, E-mail: duanyanping@tongji.edu.cn; Huang, Fan; Yang, Jing; Xiang, Nan; Meng, Xiang-Zhou; Chen, Ling

    2014-06-01

    Highlights: • PBDEs were detected in the majority of e-waste. • PBDEs were found in TVs made in China after 1990. • The levels of ?PBDEs in e-waste made in Japan far exceed the threshold limit of RoHS. • The inappropriate recycling and disposal of e-waste is an important source of PBDEs. - Abstract: Very few data for polybrominated diphenyl ethers (PBDEs) were available in the electronic waste (e-waste) as one of the most PBDEs emission source. This study reported concentrations of PBDEs in e-waste including printer, rice cooker, computer monitor, TV, electric iron and water dispenser, as well as dust from e-waste, e-waste dismantling workshop and surface soil from inside and outside of an e-waste recycling plant in Shanghai, Eastern China. The results showed that PBDEs were detected in the majority of e-waste, and the concentrations of ?PBDEs ranged from not detected to 175 g/kg, with a mean value of 10.8 g/kg. PBDEs were found in TVs made in China after 1990. The mean concentrations of ?PBDEs in e-waste made in Korea, Japan, Singapore and China were 1.84 g/kg, 20.5 g/kg, 0.91 g/kg, 4.48 g/kg, respectively. The levels of ?PBDEs in e-waste made in Japan far exceed the threshold limit of RoHS (1.00 g/kg). BDE-209 dominated in e-waste, accounting for over 93%. The compositional patterns of PBDEs congeners resembled the profile of Saytex 102E, indicating the source of deca-BDE. Among the samples of dust and surface soil from a typical e-waste recycling site, the highest concentrations of ?{sub 18}PBDEs and BDE-209 were found in dust in e-waste, ranging from 1960 to 340,710 ng/g and from 910 to 320,400 ng/g, which were 1–2 orders of magnitude higher than other samples. It suggested that PBDEs released from e-waste via dust, and then transferred to surrounding environment.

  4. ENVIRONMENTAL ENGINEERING SCIENCE Volume 20, Number 5, 2003

    E-Print Network [OSTI]

    Chu, Kung-Hui "Bella"

    -butyl ether (MTBE) is the most widely used oxygenate in gasoline, followed by ethanol. Widespread use in certain urban regions to reduce air pollution from motor vehi- cles. To meet the requirements of the CAAA), and diisopropyl ether (DIPE). Alcohol oxy- genates include ethanol (EtOH), tert-butyl alcohol (TBA), and methanol

  5. Plant Operational Status - Pantex Plant

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.Theory ofDid youOxygen Generation | Center for GasPhysics Physics PrintPicturePlant

  6. Single-Step Syngas-to-Distillates (S2D) Synthesis via Methanol and Dimethyl Ether Intermediates: Final Report

    SciTech Connect (OSTI)

    Dagle, Robert A.; Lebarbier, Vanessa MC; Lizarazo Adarme, Jair A.; King, David L.; Zhu, Yunhua; Gray, Michel J.; Jones, Susanne B.; Biddy, Mary J.; Hallen, Richard T.; Wang, Yong; White, James F.; Holladay, Johnathan E.; Palo, Daniel R.

    2013-11-26

    The objective of the work was to enhance price-competitive, synthesis gas (syngas)-based production of transportation fuels that are directly compatible with the existing vehicle fleet (i.e., vehicles fueled by gasoline, diesel, jet fuel, etc.). To accomplish this, modifications to the traditional methanol-to-gasoline (MTG) process were investigated. In this study, we investigated direct conversion of syngas to distillates using methanol and dimethyl ether intermediates. For this application, a Pd/ZnO/Al2O3 (PdZnAl) catalyst previously developed for methanol steam reforming was evaluated. The PdZnAl catalyst was shown to be far superior to a conventional copper-based methanol catalyst when operated at relatively high temperatures (i.e., >300°C), which is necessary for MTG-type applications. Catalytic performance was evaluated through parametric studies. Process conditions such as temperature, pressure, gas-hour-space velocity, and syngas feed ratio (i.e., hydrogen:carbon monoxide) were investigated. PdZnAl catalyst formulation also was optimized to maximize conversion and selectivity to methanol and dimethyl ether while suppressing methane formation. Thus, a PdZn/Al2O3 catalyst optimized for methanol and dimethyl ether formation was developed through combined catalytic material and process parameter exploration. However, even after compositional optimization, a significant amount of undesirable carbon dioxide was produced (formed via the water-gas-shift reaction), and some degree of methane formation could not be completely avoided. Pd/ZnO/Al2O3 used in combination with ZSM-5 was investigated for direct syngas-to-distillates conversion. High conversion was achieved as thermodynamic constraints are alleviated when methanol and dimethyl are intermediates for hydrocarbon formation. When methanol and/or dimethyl ether are products formed separately, equilibrium restrictions occur. Thermodynamic relaxation also enables the use of lower operating pressures than what would be allowed for methanol synthesis alone. Aromatic-rich hydrocarbon liquid (C5+), containing a significant amount of methylated benzenes, was produced under these conditions. However, selectivity control to liquid hydrocarbons was difficult to achieve. Carbon dioxide and methane formation was problematic. Furthermore, saturation of the olefinic intermediates formed in the zeolite, and necessary for gasoline production, occurred over PdZnAl. Thus, yield to desirable hydrocarbon liquid product was limited. Evaluation of other oxygenate-producing catalysts could possibly lead to future advances. Potential exists with discovery of other types of catalysts that suppress carbon dioxide and light hydrocarbon formation. Comparative techno-economics for a single-step syngas-to-distillates process and a more conventional MTG-type process were investigated. Results suggest operating and capital cost savings could only modestly be achieved, given future improvements to catalyst performance. Sensitivity analysis indicated that increased single-pass yield to hydrocarbon liquid is a primary need for this process to achieve cost competiveness.

  7. Low-temperature CVD of iron, cobalt, and nickel nitride thin films from bis[di(tert-butyl)amido]metal(II) precursors and ammonia

    SciTech Connect (OSTI)

    Cloud, Andrew N.; Abelson, John R., E-mail: abelson@illinois.edu [Department of Materials Science and Engineering, University of Illinois at Urbana-Champaign, 201 Materials Science and Engineering Building, 1304 W. Green St., Urbana, Illinois 61801 (United States); Davis, Luke M.; Girolami, Gregory S., E-mail: girolami@scs.illinois.edu [School of Chemical Sciences, University of Illinois at Urbana-Champaign, 600 S. Mathews Ave., Urbana, Illinois 61801 (United States)

    2014-03-15

    Thin films of late transition metal nitrides (where the metal is iron, cobalt, or nickel) are grown by low-pressure metalorganic chemical vapor deposition from bis[di(tert-butyl)amido]metal(II) precursors and ammonia. These metal nitrides are known to have useful mechanical and magnetic properties, but there are few thin film growth techniques to produce them based on a single precursor family. The authors report the deposition of metal nitride thin films below 300?°C from three recently synthesized M[N(t-Bu){sub 2}]{sub 2} precursors, where M?=?Fe, Co, and Ni, with growth onset as low as room temperature. Metal-rich phases are obtained with constant nitrogen content from growth onset to 200?°C over a range of feedstock partial pressures. Carbon contamination in the films is minimal for iron and cobalt nitride, but similar to the nitrogen concentration for nickel nitride. X-ray photoelectron spectroscopy indicates that the incorporated nitrogen is present as metal nitride, even for films grown at the reaction onset temperature. Deposition rates of up to 18?nm/min are observed. The film morphologies, growth rates, and compositions are consistent with a gas-phase transamination reaction that produces precursor species with high sticking coefficients and low surface mobilities.

  8. Waste Treatment Plant Overview

    Office of Environmental Management (EM)

    contracted Bechtel National, Inc., to design and build the world's largest radioactive waste treatment plant. The Waste Treatment and Immobilization Plant (WTP), also known as the...

  9. Vapor-liquid equilibrium for methanol + 1,1-dimethylpropyl methyl ether at (288.15, 308.15, and 328.15) K

    SciTech Connect (OSTI)

    Moessner, F.; Coto, B.; Pando, C.; Rubio, R.G.; Renuncio, J.A.R. [Universidad Complutense, Madrid (Spain). Departamento de Quimica Fisica 1] [Universidad Complutense, Madrid (Spain). Departamento de Quimica Fisica 1

    1996-05-01

    Oxygenated compounds are being used as additives to gasoline because of their antiknock effects. Vapor-liquid equilibria for methanol + 1,1-dimethylpropyl methyl ether (tert-amyl methyl ether or TAME) have been measured at (288.15, 308.15, and 328.15) K. A Gibbs-Van Ness type apparatus for total vapor pressure measurements has been used. The system shows positive deviations from Raoult`s law with an azeotrope, whose coordinates are reported at the three temperatures studied. Results have been analyzed in terms of the UNIQUAC model, several versions of the UNIFAC model, and the modified-Huron-Vidal second-order (MHV2) group contribution equation of state.

  10. Involvement of reactive oxygen species in brominated diphenyl ether-47-induced inflammatory cytokine release from human extravillous trophoblasts in vitro

    SciTech Connect (OSTI)

    Park, Hae-Ryung, E-mail: heaven@umich.edu; Kamau, Patricia W.; Loch-Caruso, Rita

    2014-01-15

    Polybrominated diphenyl ethers (PBDEs) are widely used flame retardant compounds. Brominated diphenyl ether (BDE)-47 is one of the most prevalent PBDE congeners found in human breast milk, serum and placenta. Despite the presence of PBDEs in human placenta, effects of PBDEs on placental cell function are poorly understood. The present study investigated BDE-47-induced reactive oxygen species (ROS) formation and its role in BDE-47-stimulated proinflammatory cytokine release in a first trimester human extravillous trophoblast cell line, HTR-8/SVneo. Exposure of HTR-8/SVneo cells for 4 h to 20 ?M BDE-47 increased ROS generation 1.7 fold as measured by the dichlorofluorescein (DCF) assay. Likewise, superoxide anion production increased approximately 5 fold at 10 and 15 ?M and 9 fold at 20 ?M BDE-47 with a 1-h exposure, as measured by cytochrome c reduction. BDE-47 (10, 15 and 20 ?M) decreased the mitochondrial membrane potential by 47–64.5% at 4, 8 and 24 h as assessed with the fluorescent probe Rh123. Treatment with 15 and 20 ?M BDE-47 stimulated cellular release and mRNA expression of IL-6 and IL-8 after 12 and 24-h exposures: the greatest increases were a 35-fold increased mRNA expression at 12 h and a 12-fold increased protein concentration at 24 h for IL-6. Antioxidant treatments (deferoxamine mesylate, (±)?-tocopherol, or tempol) suppressed BDE-47-stimulated IL-6 release by 54.1%, 56.3% and 37.7%, respectively, implicating a role for ROS in the regulation of inflammatory pathways in HTR-8/SVneo cells. Solvent (DMSO) controls exhibited statistically significantly decreased responses compared with non-treated controls for IL-6 release and IL-8 mRNA expression, but these responses were not consistent across experiments and times. Nonetheless, it is possible that DMSO (used to dissolve BDE-47) may have attenuated the stimulatory actions of BDE-47 on cytokine responses. Because abnormal activation of proinflammatory responses can disrupt trophoblast functions necessary for placental development and successful pregnancy, further investigation is warranted of the impact of ROS and BDE-47 on trophoblast cytokine responses. - Highlights: • BDE-47 induced ROS overproduction and mitochondrial dysfunction. • BDE-47 stimulated production of proinflammatory cytokines. • Antioxidant treatment reduced BDE-47-stimulated ROS generation and cytokine release.

  11. Polyhydroxyalkanoate synthesis in plants

    DOE Patents [OSTI]

    Srienc, Friedrich (Lake Elmo, MN); Somers, David A. (Roseville, MN); Hahn, J. J. (New Brighton, MN); Eschenlauer, Arthur C. (Circle Pines, MN)

    2000-01-01

    Novel transgenic plants and plant cells are capable of biosynthesis of polyhydroxyalkanoate (PHA). Heterologous enzymes involved in PHA biosynthesis, particularly PHA polymerase, are targeted to the peroxisome of a transgenic plant. Transgenic plant materials that biosynthesize short chain length monomer PHAs in the absence of heterologous .beta.-ketothiolase and acetoacetyl-CoA reductase are also disclosed.

  12. Ethylene insensitive plants

    DOE Patents [OSTI]

    Ecker, Joseph R. (Carlsbad, CA); Nehring, Ramlah (La Jolla, CA); McGrath, Robert B. (Philadelphia, PA)

    2007-05-22

    Nucleic acid and polypeptide sequences are described which relate to an EIN6 gene, a gene involved in the plant ethylene response. Plant transformation vectors and transgenic plants are described which display an altered ethylene-dependent phenotype due to altered expression of EIN6 in transformed plants.

  13. Poisonous Plant Management. 

    E-Print Network [OSTI]

    McGinty, Allan

    1985-01-01

    range specialist, The Texas A&M University System . 2 DIAGNOSING POISONOOS PLANT PROBLEMS Accurate diagnosis of poisonous plant problems can be extremely difficult. Many cases of livestock poisoning by plants have been improperly diagnosed... Agricultural Extension Service ~-P~,IJ& H~iN!/ P~,IJ&--------------- poisonous Plant ___ Management_ ..... Texas Agricultural Extension Service. The Texas A&M University System. College Station, Texas POISONO(]S PLANT MANAGEMENT Allan McGinty* Poisonous...

  14. Plant fatty acid hydroxylases

    DOE Patents [OSTI]

    Somerville, Chris (Portola Valley, CA); Broun, Pierre (Burlingame, CA); van de Loo, Frank (Lexington, KY)

    2001-01-01

    This invention relates to plant fatty acyl hydroxylases. Methods to use conserved amino acid or nucleotide sequences to obtain plant fatty acyl hydroxylases are described. Also described is the use of cDNA clones encoding a plant hydroxylase to produce a family of hydroxylated fatty acids in transgenic plants. In addition, the use of genes encoding fatty acid hydroxylases or desaturases to alter the level of lipid fatty acid unsaturation in transgenic plants is described.

  15. Synergistic effect of mixing dimethyl ether with methane, ethane, propane, and ethylene fuels on polycyclic aromatic hydrocarbon and soot formation

    SciTech Connect (OSTI)

    Yoon, S.S.; Anh, D.H.; Chung, S.H.

    2008-08-15

    Characteristics of polycyclic aromatic hydrocarbon (PAH) and soot formation in counterflow diffusion flames of methane, ethane, propane, and ethylene fuels mixed with dimethyl ether (DME) have been investigated. Planar laser-induced incandescence and fluorescence techniques were employed to measure relative soot volume fractions and PAH concentrations, respectively. Results showed that even though DME is known to be a clean fuel in terms of soot formation, DME mixture with ethylene fuel increases PAH and soot formation significantly as compared to the pure ethylene case, while the mixture of DME with methane, ethane, and propane decreases PAH and soot formation. Numerical calculations adopting a detailed kinetics showed that DME can be decomposed to produce a relatively large number of methyl radicals in the low-temperature region where PAH forms and grows; thus the mixture of DME with ethylene increases CH{sub 3} radicals significantly in the PAH formation region. Considering that the increase in the concentration of O radicals is minimal in the PAH formation region with DME mixture, the enhancement of PAH and soot formation in the mixture flames of DME and ethylene can be explained based on the role of methyl radicals in PAH and soot formation. Methyl radicals can increase the concentration of propargyls, which could enhance incipient benzene ring formation through the propargyl recombination reaction and subsequent PAH growth. Thus, the result substantiates the importance of methyl radicals in PAH and soot formation, especially in the PAH formation region of diffusion flames. (author)

  16. Calcitriol inhibits Ether-a go-go potassium channel expression and cell proliferation in human breast cancer cells

    SciTech Connect (OSTI)

    Garcia-Becerra, Rocio [Department of Reproductive Biology, Instituto Nacional de Ciencias Medicas y Nutricion Salvador Zubiran, Vasco de Quiroga No. 15, Tlalpan 14000 Mexico, D.F. (Mexico)] [Department of Reproductive Biology, Instituto Nacional de Ciencias Medicas y Nutricion Salvador Zubiran, Vasco de Quiroga No. 15, Tlalpan 14000 Mexico, D.F. (Mexico); Diaz, Lorenza, E-mail: lorenzadiaz@gmail.com [Department of Reproductive Biology, Instituto Nacional de Ciencias Medicas y Nutricion Salvador Zubiran, Vasco de Quiroga No. 15, Tlalpan 14000 Mexico, D.F. (Mexico)] [Department of Reproductive Biology, Instituto Nacional de Ciencias Medicas y Nutricion Salvador Zubiran, Vasco de Quiroga No. 15, Tlalpan 14000 Mexico, D.F. (Mexico); Camacho, Javier [Department of Pharmacology, Centro de Investigacion y de Estudios Avanzados, Instituto Politecnico Nacional, Av. Instituto Politecnico Nacional 2508, San Pedro Zacatenco 07360, Mexico, D.F. (Mexico)] [Department of Pharmacology, Centro de Investigacion y de Estudios Avanzados, Instituto Politecnico Nacional, Av. Instituto Politecnico Nacional 2508, San Pedro Zacatenco 07360, Mexico, D.F. (Mexico); Barrera, David; Ordaz-Rosado, David; Morales, Angelica [Department of Reproductive Biology, Instituto Nacional de Ciencias Medicas y Nutricion Salvador Zubiran, Vasco de Quiroga No. 15, Tlalpan 14000 Mexico, D.F. (Mexico)] [Department of Reproductive Biology, Instituto Nacional de Ciencias Medicas y Nutricion Salvador Zubiran, Vasco de Quiroga No. 15, Tlalpan 14000 Mexico, D.F. (Mexico); Ortiz, Cindy Sharon [Department of Pathology, Instituto Nacional de Ciencias Medicas y Nutricion Salvador Zubiran, Vasco de Quiroga No. 15, Tlalpan 14000 Mexico, D.F. (Mexico)] [Department of Pathology, Instituto Nacional de Ciencias Medicas y Nutricion Salvador Zubiran, Vasco de Quiroga No. 15, Tlalpan 14000 Mexico, D.F. (Mexico); Avila, Euclides [Department of Reproductive Biology, Instituto Nacional de Ciencias Medicas y Nutricion Salvador Zubiran, Vasco de Quiroga No. 15, Tlalpan 14000 Mexico, D.F. (Mexico)] [Department of Reproductive Biology, Instituto Nacional de Ciencias Medicas y Nutricion Salvador Zubiran, Vasco de Quiroga No. 15, Tlalpan 14000 Mexico, D.F. (Mexico); Bargallo, Enrique [Department of Breast Tumors, Instituto Nacional de Cancerologia, Av. San Fernando No. 22, Tlalpan 14080, Mexico, D.F. (Mexico)] [Department of Breast Tumors, Instituto Nacional de Cancerologia, Av. San Fernando No. 22, Tlalpan 14080, Mexico, D.F. (Mexico); Arrecillas, Myrna [Department of Pathology, Instituto Nacional de Cancerologia, Av. San Fernando No. 22, Tlalpan 14080, Mexico, D.F. (Mexico)] [Department of Pathology, Instituto Nacional de Cancerologia, Av. San Fernando No. 22, Tlalpan 14080, Mexico, D.F. (Mexico); Halhali, Ali; Larrea, Fernando [Department of Reproductive Biology, Instituto Nacional de Ciencias Medicas y Nutricion Salvador Zubiran, Vasco de Quiroga No. 15, Tlalpan 14000 Mexico, D.F. (Mexico)] [Department of Reproductive Biology, Instituto Nacional de Ciencias Medicas y Nutricion Salvador Zubiran, Vasco de Quiroga No. 15, Tlalpan 14000 Mexico, D.F. (Mexico)

    2010-02-01

    Antiproliferative actions of calcitriol have been shown to occur in many cell types; however, little is known regarding the molecular basis of this process in breast carcinoma. Ether-a-go-go (Eag1) potassium channels promote oncogenesis and are implicated in breast cancer cell proliferation. Since calcitriol displays antineoplastic effects while Eag1 promotes tumorigenesis, and both factors antagonically regulate cell cycle progression, we investigated a possible regulatory effect of calcitriol upon Eag1 as a mean to uncover new molecular events involved in the antiproliferative activity of this hormone in human breast tumor-derived cells. RT real-time PCR and immunocytochemistry showed that calcitriol suppressed Eag1 expression by a vitamin D receptor (VDR)-dependent mechanism. This effect was accompanied by inhibition of cell proliferation, which was potentiated by astemizole, a nonspecific Eag1 inhibitor. Immunohistochemistry and Western blot demonstrated that Eag1 and VDR abundance was higher in invasive-ductal carcinoma than in fibroadenoma, and immunoreactivity of both proteins was located in ductal epithelial cells. Our results provide evidence of a novel mechanism involved in the antiproliferative effects of calcitriol and highlight VDR as a cancer therapeutic target for breast cancer treatment and prevention.

  17. Toxicity of polychlorinated diphenyl ethers in hydra attenuata and in rat whole-embryo culture. Master's thesis

    SciTech Connect (OSTI)

    Becker, M.C.

    1991-05-01

    Polychlorinated diphenyl ethers (PCDEs) are a class of biaryl compounds that have little commercial application, but appear to be widespread in the environment. They have been found in wood preservative waste dumpsites and in fly ash from municipal waste incinerators. They have been detected in bird eggs and tissues, fish, and other edible marine organisms in the United States, Canada, and Europe. There are limited reports in the extant literature on the toxicity of PCDEs. This study was designed to evaluate the toxicity of selected PCDEs in cultures of Hydra attenuata and post-implantation rat whole embryos. The toxicity of several closely related polychlorinated biphenyls (PCBs) was evaluated in both cultures and 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD) was evaluated in whole embryo culture. Embryonic growth and development parameters (yolk sac diameter, crown-rump length, somite count, and DNA and protein content) and gross morphology were determined. Findings indicated that these chemicals were neither embryotoxic nor teratogenic. Thus, the PCDEs, which elicit other diverse toxic and biochemical responses in rodents, are relatively inactive in these bioassays for developmental toxicity.

  18. On the competition between hydrogen abstraction versus C-O bond fission in initiating dimethyl ether combustion

    SciTech Connect (OSTI)

    Francisco, J.

    1999-07-01

    There has been a growing interest in the potential use of dimethyl ether (DME) as a diesel fuel in compression ignition engines. There are two initiation steps involved in the combustion of DME, one involving C-O bond fission and the other involving hydrogen abstraction by molecular oxygen. The kinetics and thermodynamics of C-O bond fission were explored computationally in a previous paper. The present paper addresses the competing process--hydrogen abstraction by molecular oxygen. Ab initio molecular orbital calculations are used to study the structures and energetics of the reactants, products, and the transition state for the CH{sub 3}OCH{sub 3} + O{sub 2} reaction. The calculations predict a barrier for hydrogen abstraction from CH{sub 3}OCH{sub 3} by O{sub 2} of 47.4 kcal/mol. This is lower than the barrier height for C-O bond fission previously calculated to be 81.1 kcal/mol. The results support values used in current models for the combustion of DME. Moreover, an examination of rates for C-O bond fission versus hydrogen abstraction by O{sub 2} suggests that the bimolecular process is the dominant pathway.

  19. Department of Plant Sciences and Plant Pathology

    E-Print Network [OSTI]

    Maxwell, Bruce D.

    Crop Science Option The challenge for crop scientists is to implement crop and soil management systems, weed science, and entomology. Graduates find careers in farming and ranching; as crop productionDepartment of Plant Sciences and Plant Pathology Unique, hands-on study programs for students

  20. Plant Phenotype Characterization System

    SciTech Connect (OSTI)

    Daniel W McDonald; Ronald B Michaels

    2005-09-09

    This report is the final scientific report for the DOE Inventions and Innovations Project: Plant Phenotype Characterization System, DE-FG36-04GO14334. The period of performance was September 30, 2004 through July 15, 2005. The project objective is to demonstrate the viability of a new scientific instrument concept for the study of plant root systems. The root systems of plants are thought to be important in plant yield and thus important to DOE goals in renewable energy sources. The scientific study and understanding of plant root systems is hampered by the difficulty in observing root activity and the inadequacy of existing root study instrumentation options. We have demonstrated a high throughput, non-invasive, high resolution technique for visualizing plant root systems in-situ. Our approach is based upon low-energy x-ray radiography and the use of containers and substrates (artificial soil) which are virtually transparent to x-rays. The system allows us to germinate and grow plant specimens in our containers and substrates and to generate x-ray images of the developing root system over time. The same plant can be imaged at different times in its development. The system can be used for root studies in plant physiology, plant morphology, plant breeding, plant functional genomics and plant genotype screening.

  1. Geothermal Demonstration Plant

    Office of Scientific and Technical Information (OSTI)

    configuration by the preparation of process flow diagrams for the initial plant operating condition and the 1-2 mid-range plant operating condition. have been revised and expanded...

  2. Plant centromere compositions

    DOE Patents [OSTI]

    Mach; Jennifer M. (Chicago, IL), Zieler; Helge (Del Mar, CA), Jin; RongGuan (Chesterfield, MO), Keith; Kevin (Three Forks, MT), Copenhaver; Gregory P. (Chapel Hill, NC), Preuss; Daphne (Chicago, IL)

    2011-11-22

    The present invention provides for the nucleic acid sequences of plant centromeres. This will permit construction of stably inherited recombinant DNA constructs and minichromosomes which can serve as vectors for the construction of transgenic plant and animal cells.

  3. Plant centromere compositions

    DOE Patents [OSTI]

    Mach, Jennifer (Chicago, IL); Zieler, Helge (Chicago, IL); Jin, James (Chicago, IL); Keith, Kevin (Chicago, IL); Copenhaver, Gregory (Chapel Hill, NC); Preuss, Daphne (Chicago, IL)

    2006-06-26

    The present invention provides for the nucleic acid sequences of plant centromeres. This will permit construction of stably inherited recombinant DNA constructs and minichromosomes which can serve as vectors for the construction of transgenic plant and animal cells.

  4. Plant centromere compositions

    DOE Patents [OSTI]

    Mach, Jennifer M. (Chicago, IL); Zieler, Helge (Del Mar, CA); Jin, RongGuan (Chesterfield, MO); Keith, Kevin (Three Forks, MT); Copenhaver, Gregory P. (Chapel Hill, NC); Preuss, Daphne (Chicago, IL)

    2011-08-02

    The present invention provides for the nucleic acid sequences of plant centromeres. This will permit construction of stably inherited recombinant DNA constructs and minichromosomes which can serve as vectors for the construction of transgenic plant and animal cells.

  5. Plant centromere compositions

    DOE Patents [OSTI]

    Mach, Jennifer (Chicago, IL); Zieler, Helge (Chicago, IL); Jin, RongGuan (Chicago, IL); Keith, Kevin (Chicago, IL); Copenhaver, Gregory (Chapel Hill, NC); Preuss, Daphne (Chicago, IL)

    2007-06-05

    The present invention provides for the nucleic acid sequences of plant centromeres. This will permit construction of stably inherited recombinant DNA constructs and minichromosomes which can serve as vectors for the construction of transgenic plant and animal cells.

  6. Plant centromere compositions

    DOE Patents [OSTI]

    Keith, Kevin; Copenhaver, Gregory; Preuss, Daphne

    2006-10-10

    The present invention provides for the nucleic acid sequences of plant centromeres. This will permit construction of stably inherited recombinant DNA constructs and minichromosomes which can serve as vectors for the construction of transgenic plant and animal cells.

  7. HYDROCARBONS & ENERGY FROM PLANTS

    E-Print Network [OSTI]

    Nemethy, E.K.

    2011-01-01

    LBL-8596 itr-t C,d.. HYDROCARBONS & ENERGY FROM PLANTS jmethods of isolating the hydrocarbon-like material from I.privatelyownedrights. HYDROCARBONS AND ENERGY FROM PLANTS

  8. Auto-ignition during instationary jet evolution of dimethyl ether (DME) in a high-pressure atmosphere

    SciTech Connect (OSTI)

    Fast, G.; Kuhn, D.; Class, A.G.; Maas, U.

    2009-01-15

    The auto-ignition process during transient injection of gaseous dimethyl ether (DME) in a constant high-pressure atmosphere is studied experimentally by laser-optical methods and compared with numerical calculations. With different non-intrusive measurement techniques jet properties and auto-ignition are investigated at high temporal and spatial resolution. The open jet penetrates a constant pressure oxidative atmosphere of up to 4 MPa. During the transient evolution, the fuel jet entrains air at up to 720 K. The subsequent auto-ignition of the ignitable part of the jet occurs simultaneously over a wide spatial extension. The ignition delay times are not affected by variation of the nozzle exit velocity. Thus, the low-temperature oxidation is slow compared with the shorter time scales of mixing, so that chemical kinetics is dominating the process. The typical two-stage ignition is resolved optically with high-speed shadowgraphy at a sampling rate of 10 kHz. The 2D fields of jet velocity and transient mixture fraction are measured phase-coupled with Particle Image Velocimetry (PIV) and Tracer Laser Induced Fluorescence (LIF) during the time-frame of ignition. The instationary Probability Density Functions (PDF) of mixture fraction are described very well by Beta functions within the complete area of the open jet. Additional 1D flamelet simulations of the auto-ignition process are computed with a detailed reaction mechanism for DME [S. Fischer, F. Dryer, H. Curran, Int. J. Chem. Kinet. 32 (12) (2000) 713-740; H. Curran, S. Fischer, F. Dryer, Int. J. Chem. Kinet. 32 (12) (2000) 741-759]. Calculated ignition delay times are in very good agreement with the measured mean ignition delay times of 3 ms. Supplemental flamelet simulations address the influence of DME and air temperature, pressure and strain. Underneath a critical strain rate the air temperature is identified to be the most sensitive factor on ignition delay time. (author)

  9. Synthesis of dimethyl ether and alternative fuels in the liquid phase from coal-derived synthesis gas

    SciTech Connect (OSTI)

    Bhatt, B.L.

    1992-09-01

    As part of the DOE-sponsored contract for the Synthesis of Dimethyl Ether (DME) and Alternative Fuels in the Liquid Phase from Coal- Derived Syngas, the single-step, slurry phase DME synthesis process was developed. The development involved screening of catalyst systems, process variable studies, and catalyst life studies in two 300 ml stirred autoclaves. As a spin-off of the Liquid Phase Methanol (LPMEOH*) process, the new process significantly improves the syngas conversion efficiency of the LPMEOH process. This improvement can be achieved by replacing a portion of methanol catalyst with a dehydration catalyst in the reactor, resulting in the product methanol being converted to DME, thus avoiding the thermodynamic equilibrium constraint of the methanol reaction. Overall, this increases syngas conversion per-pass. The selectivity and productivity of DME and methanol are affected by the catalyst system employed as well as operating conditions. A preferred catalyst system, consisting of a physical mixture of a methanol catalyst and a gamma alumina, was identified. An improvement of about 50% in methanol equivalent productivity was achieved compared to the LPMEOH process. Results from the process variable study indicate that higher pressure and CO[sub 2] removal benefit the process significantly. Limited life studies performed on the preferred catalyst system suggest somewhat higher than expected deactivation rate for the methanol catalyst. Several DME/methanol mixtures were measured for their key properties as transportation fuels. With small amounts of DME added, significant improvements in both flash points and Reid Vapor Pressure (RVP) were observed over the corresponding values of methanol alone.

  10. Acute toxicity of smoke screen materials to aquatic organisms, white phosphorus-felt, red phosphorus-butyl rubber and SGF No. 2 fog oil. Final report

    SciTech Connect (OSTI)

    Poston, T.M.; McFadden, K.M.; Bean, R.M.; Clark, M.L.; Thomas, B.L.; Killand, B.W.; Prohammer, L.A.; Kalkwarf, D.R.

    1986-04-01

    The acute toxicity of three obscurants was determined for nine freshwater organisms. The materials tested were white phosphorus-felt smoke, red phosphorus-butyl rubber (RP-BR) smoke, and smoke generator fuel (SGF) No. 2 fog oil (bulk and vaporized). The chemistry of WP-F and RP-BR smoke in water and the resulting effects on aquatic organisms are similar. Combustion of these two obscurants and their deposition in water leads to the formation of many complex oxy-phosphoric acids. Rates of hydrolysis of these complex products to ortho-phosphate were inconsistent and unpredictable over time. These products acidify water and produce toxic effects after exhausting the buffering capacity of the water. Acute 96 hr tests using Daphnia magna with neutralized and nonneutralized exposure solutions indicated that the presence of unidentified toxic component(s) acted independently of pH. At pH levels of 6.0 to 7.0, phosphorus combustion products precipitated out of solution leading to a bimodal toxic response in extended 96-hr tests with Daphnia magna. Most components of fog oil had low solubility in water. Saturation was apparent at approximately 0.1 to 0.3 mg/L total oil. Vaporization had no demonstrable effect on the chemistry or toxicity of the fog oil. Neither the bulk fog oil nor the vaporized fog oil was acutely toxic to freshwater animals at concentrations less than 10 mg/L total oil. In oil-water mixes in excess of 1.0 mg/L total oil, fog oil quickly separated and floated to the surface. The primary hazard associated with vaporized and bulk fog oil was the physical effect of oil fouling the organisms. Photolysis increased the concentration of water-soluble components of the fog oil. Acute toxicity was demonstrated in oil-water mixes (approx.10 mg/L total oil) of photolyzed bulk and vaporized fog oil. No difference in toxicity was observed between photolyzed and non-photolyzed dilutions of OWM at comparable levels of total oil.

  11. Plant evolution The Evolution

    E-Print Network [OSTI]

    Rieseberg, Loren

    Plant evolution The Evolution of Plants by Kathy J. Willis and Jenny C. McElwain. Oxford University Press, 2002. $40.00/£22.99 pbk (378 pages) ISBN 0 19 850065 3 Developmental Genetics and Plant Evolution is observed for treatments of evolution and development. Titles of major monographs on the subject imply

  12. Power Plant Cycling Costs

    SciTech Connect (OSTI)

    Kumar, N.; Besuner, P.; Lefton, S.; Agan, D.; Hilleman, D.

    2012-07-01

    This report provides a detailed review of the most up to date data available on power plant cycling costs. The primary objective of this report is to increase awareness of power plant cycling cost, the use of these costs in renewable integration studies and to stimulate debate between policymakers, system dispatchers, plant personnel and power utilities.

  13. NUCLEAR PLANT AND CONTROL

    E-Print Network [OSTI]

    NUCLEAR PLANT OPERATIONS AND CONTROL KEYWORDS: software require- ments, safety analysis, formal for the digital protection systems of a nuclear power plant. When spec- ifying requirements for software and CRSA processes are described using shutdown system 2 of the Wolsong nuclear power plants as the digital

  14. Simulation Modeling of Plants and Plant Przemyslaw Prusinkiewicz

    E-Print Network [OSTI]

    Prusinkiewicz, Przemyslaw

    Simulation Modeling of Plants and Plant Ecosystems Przemyslaw Prusinkiewicz Reference Przemyslaw Prusinkiewicz: Simulation Modeling of Plants and Plant Ecosystems. Communications of the ACM vol. 43 no. 7, pp The modeling of plants and plant ecosystems has the captivating appeal of reproducing the visual beauty

  15. PLANT DISEASES IN SOUTH CAROLINA

    E-Print Network [OSTI]

    Stuart, Steven J.

    INDEX OF PLANT DISEASES IN SOUTH CAROLINA James H. Blake, Ed.D. Director, Home & Garden Information to compile a list of plant diseases occurring on cultivated and native plants in South Carolina. The data or conclusive list of the diseases of plants in South Carolina. New plants as well as new plant pathogens

  16. Synthesis of Methanol and Dimethyl Ether from Syngas over Pd/ZnO/Al2O3 Catalysts

    SciTech Connect (OSTI)

    Lebarbier, Vanessa MC; Dagle, Robert A.; Kovarik, Libor; Lizarazo Adarme, Jair A.; King, David L.; Palo, Daniel R.

    2012-10-01

    A Pd/ZnO/Al2O3 catalyst was developed for the synthesis of methanol and dimethyl ether (DME) from syngas. Studied were temperatures of operation ranging from 250°C to 380°C. High temperatures (e.g. 380°C) are necessary when combining methanol and DME synthesis with a methanol to gasoline (MTG) process in a single reactor bed. A commercial Cu/ZnO/Al2O3 catalyst, utilized industrially for the synthesis of methanol at 220-280°C, suffers from a rapid deactivation when the reaction is conducted at high temperature (>320°C). On the contrary, a Pd/ZnO/Al2O3 catalyst was found to be highly stable for methanol and DME synthesis at 380°C. The Pd/ZnO/Al2O3 catalyst was thus further investigated for methanol and DME synthesis at P=34-69 bars, T= 250-380°C, GHSV= 5 000-18 000 h-1, and molar feeds H2/CO= 1, 2, and 3. Selectivity to DME increased with decreasing operating temperature, and increasing operating pressure. Increased GHSV’s and H2/CO syngas feed ratios also enhanced DME selectivity. Undesirable CH4 formation was observed, however, can be minimized through choice of process conditions and by catalyst design. By studying the effect of the Pd loading and the Pd:Zn molar ratio the formulation of the Pd/ZnO/Al2O3 catalyst was optimized. A catalyst with 5% Pd and a Pd:Zn molar ratio of 0.25:1 has been identified as the preferred catalyst. Results indicate that PdZn particles are more active than Pdº particles for the synthesis of methanol and less active for CH4 formation. A correlation between DME selectivity and the concentration of acid sites of the catalysts has been established. Hence, two types of sites are required for the direct conversion of syngas to DME: 1) PdZn particles are active for the synthesis of methanol from syngas, and 2) acid sites which are active for the conversion of methanol to DME. Additionally, CO2 formation was problematic as PdZn was found to be active for the water-gas-shift (WGS) reaction, under all the conditions evaluated.

  17. Conditional sterility in plants

    DOE Patents [OSTI]

    Meagher, Richard B. (Athens, GA); McKinney, Elizabeth (Athens, GA); Kim, Tehryung (Taejeon, KR)

    2010-02-23

    The present disclosure provides methods, recombinant DNA molecules, recombinant host cells containing the DNA molecules, and transgenic plant cells, plant tissue and plants which contain and express at least one antisense or interference RNA specific for a thiamine biosynthetic coding sequence or a thiamine binding protein or a thiamine-degrading protein, wherein the RNA or thiamine binding protein is expressed under the regulatory control of a transcription regulatory sequence which directs expression in male and/or female reproductive tissue. These transgenic plants are conditionally sterile; i.e., they are fertile only in the presence of exogenous thiamine. Such plants are especially appropriate for use in the seed industry or in the environment, for example, for use in revegetation of contaminated soils or phytoremediation, especially when those transgenic plants also contain and express one or more chimeric genes which confer resistance to contaminants.

  18. SC Johnson Waxdale Plant

    SciTech Connect (OSTI)

    2010-01-01

    This is a combined heat and power (CHP) project profile on a 6.4 MW CHP application at SC Johnson Waxdale Plant in Racine, Wisconsin.

  19. HYDROCARBONS & ENERGY FROM PLANTS

    E-Print Network [OSTI]

    Nemethy, E.K.

    2011-01-01

    17 harvest was 19 rainfall contributed 5.6" water. Harvest.harvest 29 Aug~st, when plants began to flower, approximately 15 irrigation water

  20. Modulating lignin in plants

    DOE Patents [OSTI]

    Apuya, Nestor; Bobzin, Steven Craig; Okamuro, Jack; Zhang, Ke

    2013-01-29

    Materials and methods for modulating (e.g., increasing or decreasing) lignin content in plants are disclosed. For example, nucleic acids encoding lignin-modulating polypeptides are disclosed as well as methods for using such nucleic acids to generate transgenic plants having a modulated lignin content.

  1. Plant pathogen resistance

    DOE Patents [OSTI]

    Greenberg, Jean T; Jung, Ho Won; Tschaplinski, Timothy

    2012-11-27

    Azelaic acid or its derivatives or analogs induce a robust and a speedier defense response against pathogens in plants. Azelaic acid treatment alone does not induce many of the known defense-related genes but activates a plant's defense signaling upon pathogen exposure.

  2. Plant fatty acid hydroxylase

    DOE Patents [OSTI]

    Somerville, Chris (Portola Valley, CA); van de Loo, Frank (Lexington, KY)

    2000-01-01

    The present invention relates to the identification of nucleic acid sequences and constructs, and methods related thereto, and the use of these sequences and constructs to produce genetically modified plants for the purpose of altering the composition of plant oils, waxes and related compounds.

  3. NUCLEAR PLANT OPERATIONS AND

    E-Print Network [OSTI]

    Demazière, Christophe

    NUCLEAR PLANT OPERATIONS AND CONTROL KEYWORDS: moderator temper ature coefficient, reactivity co reactor Unit 4 of the Ringhals Nuclear Power Plant (Sweden) during fuel cycle 16 is analyzed of Reactor Physics SE-41296 Gothenburg, Sweden GABOR PÓR Budapest University of Technology and Economics H

  4. NUCLEAR PLANT OPERATIONS AND

    E-Print Network [OSTI]

    Pázsit, Imre

    NUCLEAR PLANT OPERATIONS AND CONTROL KEYWORDS: moderator temper- ature coefficient, reactivity co reactor Unit 4 of the Ringhals Nuclear Power Plant (Sweden) during fuel cycle 16 is analyzed of Reactor Physics SE-41296 Gothenburg, Sweden GABOR PÓR Budapest University of Technology and Economics H

  5. Modeling plant growth and development Przemyslaw Prusinkiewicz

    E-Print Network [OSTI]

    Prusinkiewicz, Przemyslaw

    Modeling plant growth and development Przemyslaw Prusinkiewicz Department of Computer Science plant models or "virtual plants" are increasingly seen as a useful tool for comprehending complex relationships between gene function, plant physiology, plant development, and the resulting plant form

  6. Proposed plant will turn wood residues into synfuel

    SciTech Connect (OSTI)

    Not Available

    1981-01-01

    A group of entrepreneurs plan to have a plant operating in Burney, CA. The projected facility will produce an estimated 21,000 gallons of oil per day, converting about 300 tons of raw material. Converting cellulose into synthetic fuel is superior to alcohol production. The process yields approximately 84 gallons of synthetic fuel per ton of raw material. The entire LHG (liquid hydrogen gas) patented facility is self-sufficient and releases only carbon dioxide into the atmosphere. Synfuel production is a three-phase process. First, butyl alcohol (butanol) and acetone are produced from a portion of the raw material. This is facilitated by adding to the raw material a bacteria culture. The planned facility in Burney will have thirty-five 2100 gallon fermentation tanks and will produce 1.25 million gallons of butanol. Next, organic material is blended with water and is pumped into patented LHG catalytic converters, charged with carbon monoxide gas as a catalyst and then heated to 350 degrees C at 2000 to 5000 psi. Here, the organic material is converted to No. 4 oil with bituminous tar as a residue. A patented gasifier system produces the carbon monoxide catalyst plus COH (carbon hydroxide) gas. The COH is used to power a gas turbine driving a 100 kW generator and a central hydraulic pump. The facility, which will be energy self-sufficient, will have approximately 50 kW of excess power to sell to the local utility power grid. Finally, the No. 4 oil, butanol and liquified COH gas are blended to produce any grade fuel oil or a gasoline substitute of very high octane.

  7. BIOENERGIZEME INFOGRAPHIC CHALLENGE: Photosynthesis: Plants Making...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Photosynthesis: Plants Making Fuel BIOENERGIZEME INFOGRAPHIC CHALLENGE: Photosynthesis: Plants Making Fuel BIOENERGIZEME INFOGRAPHIC CHALLENGE: Photosynthesis: Plants Making Fuel...

  8. Understanding chemical reactions of CO{sub 2} and its isoelectronic molecules with 1-butyl-3-methylimidazolium acetate by changing the nature of the cation: The case of CS{sub 2} in 1-butyl-1-methylpyrrolidinium acetate studied by NMR spectroscopy and density functional theory calculations

    SciTech Connect (OSTI)

    Cabaço, M. Isabel, E-mail: isabelcabaco@ist.utl.pt [Departamento de Física, Instituto Superior Técnico, UTL, Av. Rovisco Pais 1049-001 Lisboa (Portugal); Centro de Física Atómica da UL, Av. Prof. Gama Pinto 2, 1649-003 Lisboa (Portugal); Besnard, Marcel; Danten, Yann [GSM Institut des Sciences Moléculaires, CNRS (UMR 5255), Université de Bordeaux, 351, Cours de la Libération 33405 Talence Cedex (France); Chávez, Fabián Vaca [Centro de Física da Matéria Condensada da UL, Av. Prof. Gama Pinto 2, 1694-003 Lisboa (Portugal); Pinaud, Noël [CESAMO Institut des Sciences Moléculaires, CNRS (UMR 5255), Université de Bordeaux, 351, Cours de la Libération 33405 Talence Cedex (France); Sebastião, Pedro J. [Departamento de Física, Instituto Superior Técnico, UTL, Av. Rovisco Pais 1049-001 Lisboa (Portugal); Centro de Física da Matéria Condensada da UL, Av. Prof. Gama Pinto 2, 1694-003 Lisboa (Portugal); Coutinho, João A. P. [CICECO, Departamento de Química, Universidade de Aveiro 3810-193 Aveiro (Portugal)

    2014-06-28

    NMR spectroscopy ({sup 1}H, {sup 13}C, {sup 15}N) shows that carbon disulfide reacts spontaneously with 1-butyl-1-methylpyrrolidinium acetate ([BmPyrro][Ac]) in the liquid phase. It is found that the acetate anions play an important role in conditioning chemical reactions with CS{sub 2} leading, via coupled complex reactions, to the degradation of this molecule to form thioacetate anion (CH{sub 3}COS{sup ?}), CO{sub 2}, OCS, and trithiocarbonate (CS{sub 3}{sup 2?}). In marked contrast, the cation does not lead to the formation of any adducts allowing to conclude that, at most, its role consists in assisting indirectly these reactions. The choice of the [BmPyrro]{sup +} cation in the present study allows disentangling the role of the anion and the cation in the reactions. As a consequence, the ensemble of results already reported on CS{sub 2}-[Bmim][Ac] (1), OCS-[Bmim][Ac] (2), and CO{sub 2}-[Bmim][Ac] (3) systems can be consistently rationalized. It is argued that in system (1) both anion and cation play a role. The CS{sub 2} reacts with the acetate anion leading to the formation of CH{sub 3}COS{sup ?}, CO{sub 2}, and OCS. After these reactions have proceeded the nascent CO{sub 2} and OCS interact with the cation to form imidazolium-carboxylate ([Bmim] CO{sub 2}) and imidazolium-thiocarboxylate ([Bmim] COS). The same scenario also applies to system (2). In contrast, in the CO{sub 2}-[Bmim] [Ac] system a concerted cooperative process between the cation, the anion, and the CO{sub 2} molecule takes place. A carbene issued from the cation reacts to form the [Bmim] CO{sub 2}, whereas the proton released by the ring interacts with the anion to produce acetic acid. In all these systems, the formation of adduct resulting from the reaction between the solute molecule and the carbene species originating from the cation is expected. However, this species was only observed in systems (2) and (3). The absence of such an adduct in system (1) has been theoretically investigated using DFT calculations. The values of the energetic barrier of the reactions show that the formation of [Bmim] CS{sub 2} is unfavoured and that the anion offers a competitive reactive channel via an oxygen-sulphur exchange mechanism with the solute in systems (1) and (2)

  9. Plant Phenotype Characterization System | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Plant Phenotype Characterization System Plant Phenotype Characterization System New X-Ray Technology Accelerates Plant Research The ability to analyze plant root structure and...

  10. Petroleum Supply Monthly

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    butyl ether). Blends up to 15.0 percent by volume MTBE which must meet the ASTM D4814 specifications. Blenders must take precautions that the blends are not used as base...

  11. untitled

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    butyl ether). Blends up to 15.0 percent by volume MTBE which must meet the ASTM D4814 specifications. Blenders must take precautions that the blends are not used as base...

  12. Modulators of Toll-like Receptors-4 and -2

    E-Print Network [OSTI]

    Wu, Wenyan

    2009-08-31

    ?OEt2 – boron trifluoride diethyl etherate BnBr – benzyl bromide br - broad Boc – di-tert-butyl carbonate BPI – bactericidal permeability increasing protein CH3CN – acetonitrile C15H31COCl – palmitoyl chloride CTL – cytotoxic T lymphocyte DAB...

  13. Preparations for Meeting New York and Connecticut MTBE Bans

    Reports and Publications (EIA)

    2003-01-01

    In response to a Congressional request, the Energy Information Administration examined the progress being made to meet the bans on the use of methyl tertiary butyl ether (MTBE) being implemented in New York and Connecticut at the end of 2003.

  14. Iowa Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    Iowa nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear net...

  15. Illinois Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    Illinois nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear...

  16. Arkansas Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear net...

  17. Nebraska Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    Nebraska nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear...

  18. Washington Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    Washington nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State...

  19. Mississippi Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    Mississippi nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State...

  20. Connecticut Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    Connecticut nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State...

  1. Maryland Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear net...

  2. Missouri Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear net...

  3. Virginia Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear net...

  4. Arizona Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear net...

  5. Pennsylvania Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    Pennsylvania nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State...

  6. Florida Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    Florida nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear...

  7. Ohio Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    Ohio nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear net...

  8. Michigan Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear net...

  9. California Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    California nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State...

  10. Alabama Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear net...

  11. Tennessee Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    Tennessee nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear...

  12. Massachusetts Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear net...

  13. Georgia Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear net...

  14. Vermont Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear net...

  15. Kansas Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    Kansas nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear...

  16. Texas Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear net...

  17. Minnesota Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    Minnesota nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear...

  18. Wisconsin Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    Wisconsin nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear...

  19. Synthesis of dimethyl ether and alternative fuels in the liquid phase from coal-derived syngas; Quarterly technical progress report No. 3, 1 July--30 September 1990

    SciTech Connect (OSTI)

    1991-01-25

    Contract objectives are: development of a one-step liquid phase dimethyl ether/methanol process; and investigation of the potential of liquid phase synthesis of alternative fuels from coal-derived synthesis gas. Definition of Preferred Catalyst System was completed after several commercial methanol catalysts and dehydration catalysts were tested. BASF S3-86 and Catapal gamma alumina is the preferred catalyst system of choice. Process Variable Scans on the Preferred Catalyst System was started with Shell gas. Data were obtained at various pressures (750 to 1400 psig), temperatures (250 to 280{degrees}C), and space velocities (5000 to 9000 sl/kg-hr). Increase in system pressure seems to have a very significant benefit to both DME and methanol formation. Both Texaco and Shell gases were evaluated. A ``stoichiometric`` feed composition (50% CO, 50% H{sub 2}) that yields maximum DME productivity at equilibrium was evaluated with a fresh batch of the optimum catalyst system. Productivities with the ``stoichiometric`` gas were much higher compared to Shell or Texaco gas. Following that test, Dow gas was evaluated (41% CO, 41% H{sub 2}, 16% CO{sub 2} and 2% N{sub 2}) using the same catalyst to study the effect of CO{sub 2}. Three DME/MEOH (1--4% DME) mixtures were evaluated by SWRI for their fuel properties. Results indicate that, with small amounts of DME added, significant improvements in both flash point and RVP are possible over the properties of LaPorte MEOH. the slurry-phase dehydration of alcohols to ethers was investigated by feeding 10 mol% mixed alcohols in N{sub 2} over an alumina catalyst suspended in mineral oil. Two alcohol mixture compositions were chosen for this study. One mixture contained methanol, ethanol, and 1-propanol in proportions representative of those in IFP Substifuel, while the other mixture contained methanol, ethanol, and isobutanol in proportions representative of those in Lurgi Octamix. 21 figs., 13 tabs.

  20. GEOTHERMAL POWER GENERATION PLANT

    Broader source: Energy.gov [DOE]

    Project objectives: Drilling a deep geothermal well on the Oregon Institute of Technology campus, Klamath Falls, OR. Constructing a geothermal power plant on the Oregon Institute of Technology campus.

  1. Plant Site Refrigeration Upgrade 

    E-Print Network [OSTI]

    Zdrojewski, R.; Healy, M.; Ramsey, J.

    1999-01-01

    Bayer Corporation operates a multi-division manufacturing facility in Bushy Park, South Carolina. Low temperature refrigeration (-4°F) is required by many of the chemical manufacturing areas and is provided by a Plant Site Refrigeration System...

  2. HYDROCARBONS & ENERGY FROM PLANTS

    E-Print Network [OSTI]

    Nemethy, E.K.

    2011-01-01

    categories: I. Methods of extraction of the dried plants.d) Processing methods: optimum extraction procedures;is the traditional method of extraction for rUbber-pr~duci

  3. Heating Plant Emergency Instructions

    E-Print Network [OSTI]

    de Leon, Alex R.

    Heating Plant Emergency Instructions In the event of an EMERGENCY dial 403-220-5333 for Campus room, closet or hallway (ground floor, if possible) Stay away from outside walls, windows and doors

  4. Plant Vascular Biology 2010

    SciTech Connect (OSTI)

    Ding, Biao

    2014-11-17

    This grant supported the Second International Conference on Plant Vascular Biology (PVB 2010) held July 24-28, 2010 on the campus of Ohio State University, Columbus, Ohio. Biao Ding (Ohio State University; OSU) and David Hannapel (Iowa State University; ISU) served as co-chairs of this conference. Biao Ding served as the local organizer. PVB is defined broadly here to include studies on the biogenesis, structure and function of transport systems in plants, under conditions of normal plant growth and development as well as of plant interactions with pathogens. The transport systems cover broadly the xylem, phloem, plasmodesmata and vascular cell membranes. The PVB concept has emerged in recent years to emphasize the integrative nature of the transport systems and approaches to investigate them.

  5. & Immobilization Plant Project

    Office of Environmental Management (EM)

    and monitoring challenges at the Waste Treatment Plant (WTP) in Hanford. The "black cell" design concept and the use of Power Fluidic Pulse Jet Mixer technology on which WTP is...

  6. GEOTHERMAL POWER GENERATION PLANT

    SciTech Connect (OSTI)

    Boyd, Tonya

    2013-12-01

    Oregon Institute of Technology (OIT) drilled a deep geothermal well on campus (to 5,300 feet deep) which produced 196oF resource as part of the 2008 OIT Congressionally Directed Project. OIT will construct a geothermal power plant (estimated at 1.75 MWe gross output). The plant would provide 50 to 75 percent of the electricity demand on campus. Technical support for construction and operations will be provided by OIT’s Geo-Heat Center. The power plant will be housed adjacent to the existing heat exchange building on the south east corner of campus near the existing geothermal production wells used for heating campus. Cooling water will be supplied from the nearby cold water wells to a cooling tower or air cooling may be used, depending upon the type of plant selected. Using the flow obtained from the deep well, not only can energy be generated from the power plant, but the “waste” water will also be used to supplement space heating on campus. A pipeline will be construction from the well to the heat exchanger building, and then a discharge line will be construction around the east and north side of campus for anticipated use of the “waste” water by facilities in an adjacent sustainable energy park. An injection well will need to be drilled to handle the flow, as the campus existing injection wells are limited in capacity.

  7. Geothermal Plant Capacity Factors

    SciTech Connect (OSTI)

    Greg Mines; Jay Nathwani; Christopher Richard; Hillary Hanson; Rachel Wood

    2015-01-01

    The capacity factors recently provided by the Energy Information Administration (EIA) indicated this plant performance metric had declined for geothermal power plants since 2008. Though capacity factor is a term commonly used by geothermal stakeholders to express the ability of a plant to produce power, it is a term frequently misunderstood and in some instances incorrectly used. In this paper we discuss how this capacity factor is defined and utilized by the EIA, including discussion on the information that the EIA requests from operations in their 923 and 860 forms that are submitted both monthly and annually by geothermal operators. A discussion is also provided regarding the entities utilizing the information in the EIA reports, and how those entities can misinterpret the data being supplied by the operators. The intent of the paper is to inform the facility operators as the importance of the accuracy of the data that they provide, and the implications of not providing the correct information.

  8. DESIGN AND SYNTHESIS OF THE NEXT GENERATION OF CROWN ETHERS FOR WASTE SEPARATIONS: AN INTER-LABORATORY COMPREHENSIVE PROPOSAL

    SciTech Connect (OSTI)

    Moyer, Bruce A.

    2000-12-31

    The objectives of this project were to develop the techniques, materials, and fundamental understanding necessary to solve difficult separations problems of the USDOE in the 21st century. The specific goals included developing new, powerful molecular modeling tools for ligand design, performing computational and structural studies to reveal fundamental properties of ligand-metal ion interactions, studying solvent extraction behavior to provide basic understanding of solution speciation and equilibria, and preparing new ion-exchange resins for the separation of metal ions of environmental significance to the USDOE. Contaminants of special interest included alkali and alkaline-earth metal ions, especially, lithium, cesium, and strontium. For example, Li+ ions contaminate the groundwater at the Oak Ridge Y-12 Plant; Cs+ and Sr2+ represent fission products in groundwater (e.g., INEEL, Hanford), stored waste (e.g., Savannah River Site, Hanford tanks), and process-water streams (e. g., ORNL).

  9. Chemicals, fuels and electricity from coal. A proposed tri-generation concept for utilization of CO{sub 2} from power plants

    SciTech Connect (OSTI)

    Song, C.

    1999-07-01

    A tri-generation concept is proposed for the 21st century for making liquid fuels and chemicals along with electricity using CO{sub 2} from flue gases of coal-based electric power plants. The CO{sub 2} from flue gas in the power plant can be converted with CH{sub 4} (natural gas) to form synthesis gas (CO and H{sub 2} mixture) using the waste heat in the power plant. The H{sub 2}O and O{sub 2} in the flue gas will be used as co-reactants and need not be separated from the flue gas. The hot synthesis gas can be used as feedstock for fuel cells for electricity generation (such as MCFC and SOFC). The hot synthesis gas can also be used for gas turbines to generate electricity. The synthesis gas at moderate temperature can be converted into chemicals and fuels, e.g., methanol and mixed alcohols for chemical and fuel uses, dimethylether (DME) and mixed ethers for diesel fuel, dimethyl carbonate and acetic acid for chemicals. The fuels thus produced may be used either for conventional IC engines or in fuel cell-driven vehicles. This concept could also be applied, in principle, for natural gas-based power plants and IGCC power plants.

  10. NUCLEAR PLANT OPERATIONS AND

    E-Print Network [OSTI]

    Pázsit, Imre

    NUCLEAR PLANT OPERATIONS AND CONTROL KEYWORDS: neutron flux, cur- rent noise, vibration diagnostics, localization algorithm LOCALIZATION OF A VIBRATING CONTROL ROD PIN IN PRESSURIZED WATER REACTORS USING. The possibility of the localization of a vibrating control rod pin in a pressurized water reactor control assembly

  11. Mechanisms in Plant Development

    SciTech Connect (OSTI)

    Hake, Sarah

    2013-08-21

    This meeting has been held every other year for the past twenty-two years and is the only regularly held meeting focused specifically on plant development. Topics covered included: patterning in developing tissues; short and long distance signaling; differentiation of cell types; the role of epigenetics in development; evolution; growth.

  12. Top 10 plant pathogenic bacteria in molecular plant pathology.

    E-Print Network [OSTI]

    2012-01-01

    Foster, G.D. (2012) The top 10 fungal pathogens in molecularBLACKWELL PUBLISHING LTD Top 10 plant pathogenic bacteriaC. and Foster, G.D. (2011) Top 10 plant viruses in molecular

  13. Production of virus resistant plants

    DOE Patents [OSTI]

    Dougherty, William G. (Philomath, OR); Lindbo, John A. (Kent, WA)

    1996-01-01

    A method of suppressing virus gene expression in plants using untranslatable plus sense RNA is disclosed. The method is useful for the production of plants that are resistant to virus infection.

  14. Louisiana Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    Louisiana nuclear power plants, summer capacity and net generation, 2010" "Plant NameTotal Reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear...

  15. Production of virus resistant plants

    DOE Patents [OSTI]

    Dougherty, W.G.; Lindbo, J.A.

    1996-12-10

    A method of suppressing virus gene expression in plants using untranslatable plus sense RNA is disclosed. The method is useful for the production of plants that are resistant to virus infection. 9 figs.

  16. Gene encoding plant asparagine synthetase

    DOE Patents [OSTI]

    Coruzzi, Gloria M. (New York, NY); Tsai, Fong-Ying (New York, NY)

    1993-10-26

    The identification and cloning of the gene(s) for plant asparagine synthetase (AS), an important enzyme involved in the formation of asparagine, a major nitrogen transport compound of higher plants is described. Expression vectors constructed with the AS coding sequence may be utilized to produce plant AS; to engineer herbicide resistant plants, salt/drought tolerant plants or pathogen resistant plants; as a dominant selectable marker; or to select for novel herbicides or compounds useful as agents that synchronize plant cells in culture. The promoter for plant AS, which directs high levels of gene expression and is induced in an organ specific manner and by darkness, is also described. The AS promoter may be used to direct the expression of heterologous coding sequences in appropriate hosts.

  17. Getting Inside Plants | Jefferson Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ability to use additional CO2, how plants pass on additional CO2 to bacteria in the soil (carbon sequestration), and in what ways potential biofuel-producing plants can be...

  18. Independent Oversight Evaluation, Pantex Plant - November 2000...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Evaluation, Pantex Plant - November 2000 Independent Oversight Evaluation, Pantex Plant - November 2000 November 2000 Evaluation of the Pantex Plant Emergency Response Exercise...

  19. Fate of Radionuclides in Wastewater Treatment Plants

    E-Print Network [OSTI]

    Shabani Samgh Abadi, Farzaneh

    2013-01-01

    21 3. NUCLEAR POWER PLANTS……………………………………………….. 23 3.1-25 3.2- WASTES FROM NUCLEAR POWER PLANTS………………………… 28 4.radionuclides 3. Nuclear Power Plants, which includes some

  20. Fate of Radionuclides in Wastewater Treatment Plants

    E-Print Network [OSTI]

    Shabani Samgh Abadi, Farzaneh

    2013-01-01

    concerns about nuclear power plants safety after the Threedoubts regarding nuclear power plants safety. 3.1- Nuclearof nuclear power plants in order to meet safety requirements

  1. US prep plant census 2008

    SciTech Connect (OSTI)

    Fiscor, S.

    2008-10-15

    Each year Coal Age conducts a fairly comprehensive survey of the industry to produce the US coal preparation plant survey. This year's survey shows how many mergers and acquisitions have given coal operators more coal washing capacity. The plants are tabulated by state, giving basic details including company owner, plant name, raw feed, product ash %, quality, type of plant builder and year built. 1 tab., 1 photo.

  2. Regulating nutrient allocation in plants

    DOE Patents [OSTI]

    Udvardi, Michael; Yang, Jiading; Worley, Eric

    2014-12-09

    The invention provides coding and promoter sequences for a VS-1 and AP-2 gene, which affects the developmental process of senescence in plants. Vectors, transgenic plants, seeds, and host cells comprising heterologous VS-1 and AP-2 genes are also provided. Additionally provided are methods of altering nutrient allocation and composition in a plant using the VS-1 and AP-2 genes.

  3. Plant Microbiology Lab SYLLABUS 2014

    E-Print Network [OSTI]

    Brown, Sally

    of beneficial microorganisms on plants. Assays will include colonization of the plants, N stress alleviation for sequencing Mon Mar 3 Measure seedlings (5 wk data). Other plant phys expts? Early in the week: your sequencing results will be emailed to you Fri Mar 7 Lab write-up #2 on Strai

  4. North City Water Reclamation Plant

    E-Print Network [OSTI]

    Prevedouros, Panos D.

    -Site Cogeneration Methane Power Plant Methane piped in from: Miramar LandfillMiramar Landfill Metropolitan BiosolidsNorth City Water Reclamation Plant Maja Caroee Diana Lee Niko Salvador #12;What is Water% for plant operation 25% sold to local power grid #12;Technical Issues & Innovations COMNET Clean water

  5. Integrated turbomachine oxygen plant

    SciTech Connect (OSTI)

    Anand, Ashok Kumar; DePuy, Richard Anthony; Muthaiah, Veerappan

    2014-06-17

    An integrated turbomachine oxygen plant includes a turbomachine and an air separation unit. One or more compressor pathways flow compressed air from a compressor through one or more of a combustor and a turbine expander to cool the combustor and/or the turbine expander. An air separation unit is operably connected to the one or more compressor pathways and is configured to separate the compressed air into oxygen and oxygen-depleted air. A method of air separation in an integrated turbomachine oxygen plant includes compressing a flow of air in a compressor of a turbomachine. The compressed flow of air is flowed through one or more of a combustor and a turbine expander of the turbomachine to cool the combustor and/or the turbine expander. The compressed flow of air is directed to an air separation unit and is separated into oxygen and oxygen-depleted air.

  6. Grasses and Forage Plants

    E-Print Network [OSTI]

    Pittuck, B. C.

    1898-01-01

    State. A large number of the grasses, including many of the common culti? vated clovers and legumes, and many rare hay plants, on our experi? mental plots during 1897, were gathered and supplied by special agents of the United States Agricultural...), Trifolium hybridum (Alsike Clover), Large Red Clover, Trifolium repens (White Dutch Clover), suffered from the drouth and sun, but have made better growth at this place than during previous years. SPOROBOLUS. 8. wrighti*?Perennial. Germinated April 2...

  7. Pinellas Plant Environmental Baseline Report

    SciTech Connect (OSTI)

    Not Available

    1997-06-01

    The Pinellas Plant has been part of the Department of Energy`s (DOE) nuclear weapons complex since the plant opened in 1957. In March 1995, the DOE sold the Pinellas Plant to the Pinellas County Industry Council (PCIC). DOE has leased back a large portion of the plant site to facilitate transition to alternate use and safe shutdown. The current mission is to achieve a safe transition of the facility from defense production and prepare the site for alternative uses as a community resource for economic development. Toward that effort, the Pinellas Plant Environmental Baseline Report (EBR) discusses the current and past environmental conditions of the plant site. Information for the EBR is obtained from plant records. Historical process and chemical usage information for each area is reviewed during area characterizations.

  8. HYDROCARBONS FROM PLANTS: ANALYTICAL METHODS AND OBSERVATIONS

    E-Print Network [OSTI]

    Calvin, Melvin

    2013-01-01

    the green plant to capture and store solar energy, is Brazilsolar energy capturing machine we know, namely, the green plant,

  9. COURSE INFORMATION Plant Diversity and Evolution

    E-Print Network [OSTI]

    Chen, Kuang-Yu

    and experimental tools used to understand plant diversity. 4. "Vocabulary" of plant description (see list list) 7. Distinctive features of land plant diversity 8. The history of land plants through time #12COURSE INFORMATION Fall 2009 Plant Diversity and Evolution (11:704:411) and Advanced Plant

  10. Propagation of Ornamental Plants

    E-Print Network [OSTI]

    DeWerth, A. F.

    1955-01-01

    . Whenever possible, sow the seed of most After the seed have germinated, place th~ Texas ornamentals in flats or pots than container where the seedlings will get an abw directly in the open ground. dance of light. If kept in a shady location, leg...!! weak plants will result. Be sure there are cracks or holes in the bot- tom of the flat or that the hole in the bottom - Water from below whenever the soil becomP of the flower pot is kept open to allow excess water to pass quickly out of the soil...

  11. Nuclear Plant Data Bank

    SciTech Connect (OSTI)

    Booker, C.P.; Turner, M.R.; Spore, J.W.

    1986-01-01

    The Nuclear Plant Data Bank (NPDB) is being developed at the Los Alamos National Laboratory to assist analysts in the rapid and accurate creation of input decks for reactor transient analysis. The NPDB will reduce the time and cost of the creation or modification of a typical input deck. This data bank will be an invaluable tool in the timely investigation of recent and ongoing nuclear reactor safety analysis. This paper discusses the status and plans for the NPDB development and describes its anticipated structure and capabilities.

  12. Propagation of Ornamental Plants

    E-Print Network [OSTI]

    DeWerth, A. F.

    1955-01-01

    '~ihtenecl with a fine mist spray of water, since an important factor in rooting cuttings is to keep the cuttings moist. There are many advantages in the use of mist by the home gardener. A cutting continues to lose water by transpiration after... it is removed from the parent plant. It is impossible for the cuttings to take up sufficient water to replace that lost by rapid transpiration until new roots are formed. The mist system prevents ex- cessive loss of water by the cutting. Maintain- ing...

  13. Better Buildings, Better Plants:

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i n c i p a l De p uBUSEnergy|| Department ofBuildings, Better Plants: AMO

  14. Gasification Plant Databases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverse (Journal Article)ForthcomingGENERALProblems I n QEstimatesPlant Databases

  15. Plants & Animals

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformationJesseworkSURVEYI/OPerformancePi Day Pi Day Pi Day isPlanning forPlants &

  16. Perspectives on plant vulnerabilities & other plant and containment improvements

    SciTech Connect (OSTI)

    LaChance, J.; Kolaczkowski, A.; Kahn, J. [and others

    1996-01-01

    The primary goal of the Individual Plant Examination (IPE) Program was for licensees to identify plant-unique vulnerabilities and actions to address these vulnerabilities. A review of these vulnerabilities and plant improvements that were identified in the IPEs was performed as part of the IPE Insights Program sponsored by the U.S. Nuclear Regulatory Commission (NRC). The purpose of this effort was to characterize the identified vulnerabilities and the impact of suggested plant improvements. No specific definition for {open_quotes}vulnerability{close_quotes} was provided in NRC Generic Letter 88-20 or in the subsequent NRC IPE submittal guidance documented in NUREG-1335. Thus licensees were left to use their own definitions. Only 20% of the plants explicitly stated that they had vulnerabilities. However, most licensees identified other plant improvements to address issues not explicitly classified as vulnerabilities, but pertaining to areas in which overall plant safety could potentially be increased. The various definitions of {open_quotes}vulnerability{close_quotes} used by the licensees, explicitly identified vulnerabilities, proposed plant improvements to address these vulnerabilities, and other plant improvements are summarized and discussed.

  17. Plant–herbivore interactions mediated by plant toxicity

    E-Print Network [OSTI]

    2008-03-25

    Dec 17, 2007 ... O. Box 249118, Coral Gables, FL 33124, United States. .... Per capital death rate of herbivore unrelated to plant toxicity. 2. Analysis of the ...

  18. The SONATRACH jumbo LPG plant

    SciTech Connect (OSTI)

    Ahmed Khodja, A.; Bennaceur, A.

    1988-01-01

    The authors aim is to give to the 17 TH world gas conference a general idea on SONATRACH LPG PLANT which is located in the ARZEW area. They develop this communication as follows: general presentation of LPG plant: During the communication, the author's will give the assistance all the information concerning the contractions the erection's date and the LPG PLANT process, start-up of the plant: In this chapter, the authors's will describe the start-up condition, the performance test result, the flexibility test result and the total mechanical achievement of the plant; operation by SONATRACH: After the success that obtained during the mechanical achievement and performance test, the contractor handed over the plant to SONATRACH.

  19. Plant Physiology: Manipulating Plant Growth with Solar Radiation Dennis Decoteau, Ph.D.

    E-Print Network [OSTI]

    Decoteau, Dennis R.

    Plant Physiology: Manipulating Plant Growth with Solar Radiation Dennis Decoteau, Ph.D. Department of light that surrounds the plant. Light ­ Radiant Energy All light is made up of energy. Light to plants (Villee, 1977). Plant Uses Of Radiant Energy And Plant "Vision" Plants utilize specialized pigments

  20. Better Buildings, Better Plants Program

    SciTech Connect (OSTI)

    2011-12-08

    The Better Buildings, Better Plants Program is part of a national leadership initiative calling on business leaders and others to create American jobs through energy efficiency.

  1. Power Plant Modeling and Simulation

    ScienceCinema (OSTI)

    None

    2010-01-08

    The National Energy Technology Laboratory's Office of Research and Development provides open source tools and expetise for modeling and simulating power plants and carbon sequestration technologies.

  2. MHD plant turn down considerations

    SciTech Connect (OSTI)

    Lineberry, J.T.; Chapman, J.N.

    1991-01-01

    The topic of part load operation of the MHD power plant is assessed. Current and future planned MHD research is reviewed in terms of addressing topping and bottoming cycle integration needs. The response of the MHD generator to turn up and down scenarios is reviewed. The concept of turning the MHD power to met changes in plant load is discussed. The need for new ideas and focused research to study MHD plant integration and problems of plant turn down and up is cited. 7 refs., 5 figs., 1 tab.

  3. Better Plants | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Partners and welcomed more than 20 manufacturers into the program at the World Energy Engineering Congress on October 2, 2014. Read more Better Plants Program Logo Leading...

  4. Nuclear Power Plant Design Project

    E-Print Network [OSTI]

    Nuclear Power Plant Design Project A Response to the Environmental and Economic Challenge Of Global) .................................................................... 14 4.4 High Temperature Gas Reactor

  5. Power Plant Modeling and Simulation

    SciTech Connect (OSTI)

    2008-07-21

    The National Energy Technology Laboratory's Office of Research and Development provides open source tools and expetise for modeling and simulating power plants and carbon sequestration technologies.

  6. Planting and Mulching Trees and Shrubs Selecting healthy plants

    E-Print Network [OSTI]

    New Hampshire, University of

    Planting and Mulching Trees and Shrubs Selecting healthy plants Take a step back to examine swollen nodules at the container edge, rather than circling like in a plastic container. The nodules store with soil or mulch ­ ignore these and find the first permanent woody root growing radially out from

  7. Ownership Change, Incentives and Plant Efficiency: The Divestiture of U.S. Electric Generation Plants

    E-Print Network [OSTI]

    Bushnell, James B.; Wolfram, Catherine

    2005-01-01

    ciency of Electric Generating Plants: A Stochastic Frontierthe existing stock of electricity generating plants. Betweenover 300 electric generating plants in the US, accounting

  8. Master Plant List for Texas Range and Pasture Plant Identification Contests 

    E-Print Network [OSTI]

    Ragsdale, Bobby

    2000-05-03

    Entrants in range and pasture plant identification contests will find this reference useful. It includes explanations of plant characteristics and a master list of plants....

  9. Next Generation Geothermal Power Plants

    SciTech Connect (OSTI)

    Brugman, John; Hattar, Mai; Nichols, Kenneth; Esaki, Yuri

    1995-09-01

    A number of current and prospective power plant concepts were investigated to evaluate their potential to serve as the basis of the next generation geothermal power plant (NGGPP). The NGGPP has been envisaged as a power plant that would be more cost competitive (than current geothermal power plants) with fossil fuel power plants, would efficiently use resources and mitigate the risk of reservoir under-performance, and minimize or eliminate emission of pollutants and consumption of surface and ground water. Power plant concepts were analyzed using resource characteristics at ten different geothermal sites located in the western United States. Concepts were developed into viable power plant processes, capital costs were estimated and levelized busbar costs determined. Thus, the study results should be considered as useful indicators of the commercial viability of the various power plants concepts that were investigated. Broadly, the different power plant concepts that were analyzed in this study fall into the following categories: commercial binary and flash plants, advanced binary plants, advanced flash plants, flash/binary hybrid plants, and fossil/geothed hybrid plants. Commercial binary plants were evaluated using commercial isobutane as a working fluid; both air-cooling and water-cooling were considered. Advanced binary concepts included cycles using synchronous turbine-generators, cycles with metastable expansion, and cycles utilizing mixtures as working fluids. Dual flash steam plants were used as the model for the commercial flash cycle. The following advanced flash concepts were examined: dual flash with rotary separator turbine, dual flash with steam reheater, dual flash with hot water turbine, and subatmospheric flash. Both dual flash and binary cycles were combined with other cycles to develop a number of hybrid cycles: dual flash binary bottoming cycle, dual flash backpressure turbine binary cycle, dual flash gas turbine cycle, and binary gas turbine cycle. Results of this study indicate that dual flash type plants are preferred at resources with temperatures above 400 F. Closed loop (binary type) plants are preferred at resources with temperatures below 400 F. A rotary separator turbine upstream of a dual flash plant can be beneficial at Salton Sea, the hottest resource, or at high temperature resources where there is a significant variance in wellhead pressures from well to well. Full scale demonstration is required to verify cost and performance. Hot water turbines that recover energy from the spent brine in a dual flash cycle improve that cycle's brine efficiency. Prototype field tests of this technology have established its technical feasibility. If natural gas prices remain low, a combustion turbine/binary hybrid is an economic option for the lowest temperature sites. The use of mixed fluids appear to be an attractive low risk option. The synchronous turbine option as prepared by Barber-Nichols is attractive but requires a pilot test to prove cost and performance. Dual flash binary bottoming cycles appear promising provided that scaling of the brine/working fluid exchangers is controllable. Metastable expansion, reheater, Subatmospheric flash, dual flash backpressure turbine, and hot dry rock concepts do not seem to offer any cost advantage over the baseline technologies. If implemented, the next generation geothermal power plant concept may improve brine utilization but is unlikely to reduce the cost of power generation by much more than 10%. Colder resources will benefit more from the development of a next generation geothermal power plant than will hotter resources. All values presented in this study for plant cost and for busbar cost of power are relative numbers intended to allow an objective and meaningful comparison of technologies. The goal of this study is to assess various technologies on an common basis and, secondarily, to give an approximate idea of the current costs of the technologies at actual resource sites. Absolute costs at a given site will be determined by the specifics of a given pr

  10. Refinery, petrochemical plant injuries decline

    SciTech Connect (OSTI)

    Not Available

    1994-07-25

    The National Petroleum Refiners Association (NPRA) reports a 7% reduction in workplace injury and illness incidence rates for refineries in 1993, and a 21% decrease for petrochemical plants. The report summarizes data from 135 of the 162 US member refineries, and 117 of the 172 US member petrochemical plants. This paper summarizes the report findings.

  11. Do Plants Sweat? Core Content

    E-Print Network [OSTI]

    Kessler, Bruce

    in the bright sun and others are grouped together and are regularly sprinkled with water. You begin to wonder plant distribution where you see this principle in action? -Can you predict the effect of seasons data/graph] Three plants are grown in the same greenhouse with the same air temperature, amount

  12. CONSTRUCTION OF NUCLEAR POWER PLANTS

    E-Print Network [OSTI]

    CONSTRUCTION OF NUCLEAR POWER PLANTS A Workshop on "NUCLEAR ENERGY RENAISSANCE" Addressing OF ST. LUCIE-2 at FLORIDA POWER & LIGHT COMPANY · Robert E. Uhrig 1974-1986 ­ Vice President, Nuclear IN CONSTRUCTION OF ST. LUCIE-2 #12;LESSONS LEARNED FROM St. Lucie-2 NUCLEAR POWER PLANTS CAN BE BUILT

  13. Overview of enrichment plant safeguards

    SciTech Connect (OSTI)

    Swindle, D.W. Jr.; Wheeler, L.E.

    1982-01-01

    The relationship of enrichment plant safeguards to US nonproliferation objectives and to the operation and management of enrichment facilities is reviewed. During the review, the major components of both domestic and international safeguards systems for enrichment plants are discussed. In discussing domestic safeguards systems, examples of the technology currently in use to support nuclear materials accountability are described including the measurement methods, procedures and equipment used for weighing, sampling, chemical and isotopic analyses and nondestructive assay techniques. Also discussed is how the information obtained as part of the nuclear material accountancy task is useful to enrichment plant operations. International material accountancy verification and containment/surveillance concepts for enrichment plants are discussed, and the technologies presently being developed for international safeguards in enrichment plants are identified and the current development status is reported.

  14. Graduate Programs in Plant Biology and

    E-Print Network [OSTI]

    Wildermuth, Mary C

    not re- biochemistry, cell and molecular biology (B22). pmb.berkeley.edu Plant&Microbial Biology #12;The to the environment will continue to fuel the expansion of plant research well into the future. The plant biology program focuses on contemporary ba- sic plant research, design of biotechnologies, and plant-microbe

  15. Native Plants and PollinatorsNative Plants and PollinatorsNative Plants and PollinatorsNative Plants and Pollinators of Loney Meadowof Loney Meadowof Loney Meadowof Loney Meadow

    E-Print Network [OSTI]

    Ishida, Yuko

    Native Plants and PollinatorsNative Plants and PollinatorsNative Plants and PollinatorsNative Plants and Pollinators of Loney Meadowof Loney Meadowof Loney Meadowof Loney Meadow A walk with Dr.footwear. No dogs please.footwear. No dogs please. For more information please call: Kathy Van Zuuk, PlantFor more

  16. NRES 725 PLANT PHYSIOLOGICAL ECOLOGY Spring 2006

    E-Print Network [OSTI]

    Nowak, Robert S.

    1 NRES 725 ­ PLANT PHYSIOLOGICAL ECOLOGY Spring 2006 Reading List ­ Water Balance of Plants I) Water Balance of Plants A) Water potential B) Soil, plant, air continuum C) Physiological control 1 Kramer & Boyer (95) pp 16-41 & 42-83 Kramer & Boyer (95) pp 201-256 *Steudle (01) Ann Rev Plant Phy Mol

  17. Quercetin 3-O-methyl ether protects FL83B cells from copper induced oxidative stress through the PI3K/Akt and MAPK/Erk pathway

    SciTech Connect (OSTI)

    Tseng, Hsiao-Ling, E-mail: lily1001224@gmail.com [Department of Life Sciences, Tzu Chi University, Hualien, Taiwan (China)] [Department of Life Sciences, Tzu Chi University, Hualien, Taiwan (China); Li, Chia-Jung, E-mail: 97751101@stmail.tcu.edu.tw [Institute of Medical Sciences, Tzu Chi University, Hualien, Taiwan (China)] [Institute of Medical Sciences, Tzu Chi University, Hualien, Taiwan (China); Huang, Lin-Huang, E-mail: yg1236@yahoo.com.tw [School of Medicine, Institute of Traditional Medicine, National Yang-Ming University, Taipei, Taiwan (China)] [School of Medicine, Institute of Traditional Medicine, National Yang-Ming University, Taipei, Taiwan (China); Chen, Chun-Yao, E-mail: cychen@mail.tcu.edu.tw [Department of Life Sciences, Tzu Chi University, Hualien, Taiwan (China)] [Department of Life Sciences, Tzu Chi University, Hualien, Taiwan (China); Tsai, Chun-Hao, E-mail: 100726105@stmail.tcu.edu.tw [Department of Life Sciences, Tzu Chi University, Hualien, Taiwan (China)] [Department of Life Sciences, Tzu Chi University, Hualien, Taiwan (China); Lin, Chun-Nan, E-mail: lincna@cc.kmu.edu.tw [Faculty of Pharmacy, College of Pharmacy, Kaohsiung Medical University, Kaohsiung, Taiwan (China) [Faculty of Pharmacy, College of Pharmacy, Kaohsiung Medical University, Kaohsiung, Taiwan (China); Department of Biological Science and Technology, School of Medicine, China Medical University, Taichung, Taiwan (China); Hsu, Hsue-Yin, E-mail: hsueyin@mail.tcu.edu.tw [Department of Life Sciences, Tzu Chi University, Hualien, Taiwan (China)] [Department of Life Sciences, Tzu Chi University, Hualien, Taiwan (China)

    2012-10-01

    Quercetin is a bioflavonoid that exhibits several biological functions in vitro and in vivo. Quercetin 3-O-methyl ether (Q3) is a natural product reported to have pharmaceutical activities, including antioxidative and anticancer activities. However, little is known about the mechanism by which it protects cells from oxidative stress. This study was designed to investigate the mechanisms by which Q3 protects against Cu{sup 2+}-induced cytotoxicity. Exposure to Cu{sup 2+} resulted in the death of mouse liver FL83B cells, characterized by apparent apoptotic features, including DNA fragmentation and increased nuclear condensation. Q3 markedly suppressed Cu{sup 2+}-induced apoptosis and mitochondrial dysfunction, characterized by reduced mitochondrial membrane potential, caspase-3 activation, and PARP cleavage, in Cu{sup 2+}-exposed cells. The involvement of PI3K, Akt, Erk, FOXO3A, and Mn-superoxide dismutase (MnSOD) was shown to be critical to the survival of Q3-treated FL83B cells. The liver of both larval and adult zebrafish showed severe damage after exposure to Cu{sup 2+} at a concentration of 5 ?M. Hepatic damage induced by Cu{sup 2+} was reduced by cotreatment with Q3. Survival of Cu{sup 2+}-exposed larval zebrafish was significantly increased by cotreatment with 15 ?M Q3. Our results indicated that Cu{sup 2+}-induced apoptosis in FL83B cells occurred via the generation of ROS, upregulation and phosphorylation of Erk, overexpression of 14-3-3, inactivation of Akt, and the downregulation of FOXO3A and MnSOD. Hence, these results also demonstrated that Q3 plays a protective role against oxidative damage in zebrafish liver and remarked the potential of Q3 to be used as an antioxidant for hepatocytes. Highlights: ? Protective effects of Q3 on Cu{sup 2+}-induced oxidative stress in vitro and in vivo. ? Cu{sup 2+} induced apoptosis in FL83B cells via ROS and the activation of Erk. ? Q3 abolishes Cu{sup 2+}-induced apoptosis through the PI3K/Akt and MAPK/Erk pathway.

  18. Plant maintenance and plant life extension issue, 2007

    SciTech Connect (OSTI)

    Agnihotri, Newal (ed.)

    2007-03-15

    The focus of the March-April issue is on plant maintenance and plant life extension. Major articles/reports in this issue include: Three proposed COLs expected in 2007, by Dale E. Klein, U.S. Nuclear Regulatory Commission; Delivering behaviors that our customers value, by Jack Allen, Westinghouse Electric Company; Facilitating high-level and fuel waste disposal technologies, by Malcolm Gray, IAEA, Austria; Plant life management and long-term operation, by Pal Kovacs, OECD-NEA, France; Measuring control rod position, by R. Taymanov, K. Sapozhnikova, I. Druzhinin, D.I. Mendeleyev, Institue for Metrology, Russia; and, 'Modernization' means higher safety, by Svetlana Genova, Kozluduy NPP plc, Bulgaria.

  19. EARLY ENTRANCE COPRODUCTION PLANT

    SciTech Connect (OSTI)

    Lalit S. Shah; William K. Davis

    2000-05-01

    The overall objective of this project is the three phase development of an Early Entrance Coproduction Plant (EECP) which produces at least one product from at least two of the following three categories: (1) electric power (or heat), (2) fuels, and (3) chemicals. The objective is to have these products produced by technologies capable of using synthesis gas derived from coal or coal in combination with some other carbonaceous feedstock. The objective of Phase I is to determine the feasibility and define the concept for the EECP located at a specific site and to develop a Research, Development, and Test Plan (RD and T) for implementation in Phase II. The objective of Phase II is to conduct RD and T as outlined in the Phase I RD and T Plan to enhance the development and commercial acceptance of Coproduction technology that produces high-value products, particularly those that are critical to our domestic fuel and power requirements. The project will resolve critical knowledge and technology gaps on the integration of gasification and downstream processing to coproduce some combination of power, fuels, and chemicals from coal and other feedstocks. The objective of Phase III is to develop an engineering design package and a financing plan for an EECP located at a specific site. The project's intended result is to provide the necessary technical, economic, and environmental information that will be needed to move the EECP forward to detailed design, construction, and operation by industry.

  20. Plant Energy Cost Optimization Program (PECOP) 

    E-Print Network [OSTI]

    Robinson, A. M.

    1980-01-01

    The Plant Energy Cost Optimization Program (PECOP) is a Management System designed to reduce operating cost in a continuous operating multi product plant by reviewing all cost factors and selecting plant wide production schedules which are most...

  1. SENSIBLE HEAT STORAGE FOR A SOLAR THERMAL POWER PLANT

    E-Print Network [OSTI]

    Baldwin, Thomas F.

    2011-01-01

    of the Proposed Solar Power Plant Design The Impact ofof the Thesis SOLAR POWER PLANT DESIGN , Study Guidelines a.Reference Solar Power Plant Design e. Power Plant

  2. SENSIBLE HEAT STORAGE FOR A SOLAR THERMAL POWER PLANT

    E-Print Network [OSTI]

    Baldwin, Thomas F.

    2011-01-01

    storage can provide solar power plant energy storage for aconfiguration for a solar power plant without energy storagefor a solar power plant greatly influences the plant energy

  3. LANXESS Global Butyl Rubber Research Facility

    E-Print Network [OSTI]

    Denham, Graham

    or improve existing petrochemical products. They're then used for plastics, fragrance and cosmetics," Hartmann said.BioAmber's process is cheaper than conventional petroleum-based routes, he said. It

  4. Enterprise Assessments Review, Waste Isolation Pilot Plant -...

    Office of Environmental Management (EM)

    Enterprise Assessments Review, Waste Isolation Pilot Plant - December 2014 Enterprise Assessments Review, Waste Isolation Pilot Plant - December 2014 December, 2014 Review of the...

  5. Independent Oversight Inspection, Pantex Plant - August 2005...

    Energy Savers [EERE]

    August 2005 Independent Oversight Inspection, Pantex Plant - August 2005 August 2005 Inspection of Emergency Management at the Pantex Site Office and the Pantex Plant This report...

  6. New Jersey Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear net...

  7. New York Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear net...

  8. North Carolina Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    Carolina nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State nuclear...

  9. South Carolina Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    South Carolina nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (mw)","Net generation (thousand mwh)","Share of State...

  10. New Hampshire Nuclear Profile - Power Plants

    U.S. Energy Information Administration (EIA) Indexed Site

    nuclear power plants, summer capacity and net generation, 2010" "Plant nametotal reactors","Summer capacity (nw)","Net generation (thousand mwh)","Share of State nuclear net...

  11. Pre-In-Plant Training Webinar (Steam)

    Broader source: Energy.gov [DOE]

    This pre-In-Plant training webinar for the Better Plants Program covers how to find energy savings in steam systems.

  12. Independent Oversight Review, Portsmouth Gaseous Diffusion Plant...

    Office of Environmental Management (EM)

    January 2013 Independent Oversight Review, Portsmouth Gaseous Diffusion Plant - January 2013 January 2013 Review of the Portsmouth Gaseous Diffusion Plant Work Planning and Control...

  13. Independent Activity Report, Portsmouth Gaseous Diffusion Plant...

    Office of Environmental Management (EM)

    Portsmouth Gaseous Diffusion Plant - August 2011 Independent Activity Report, Portsmouth Gaseous Diffusion Plant - August 2011 August 2011 Orientation Visit to the Portsmouth...

  14. HYDROCARBONS FROM PLANTS: ANALYTICAL METHODS AND OBSERVATIONS

    E-Print Network [OSTI]

    Calvin, Melvin

    2013-01-01

    molecular weights of various hydrocarbon materials for fuelof oil and alcohol from hydrocarbon-producing plants. Into Die Naturwissenschaften HYDROCARBONS FROM PLANTS: METHODS

  15. EARLY ENTRANCE COPRODUCTION PLANT

    SciTech Connect (OSTI)

    John H. Anderson; William K. Davis; Thomas W. Sloop

    2001-03-21

    As part of the Department of Energy's (DOE) Gasification Technologies and Transportation Fuels and Chemicals programs, DOE and Texaco are partners through Cooperative Agreement DE-FC26-99FT40658 to determine the feasibility of developing, constructing and operating an Early Entrance Coproduction Plant (EECP). The overall objective of the project is the three-phase development of an EECP that produces at least one product from at least two of the following three categories: Electric power (or heat); Fuels; and Chemicals. The objective is to have these products produced by technologies capable of using synthesis gas derived from coal and/or some other carbonaceous feedstock, such as petroleum coke. The objective of Phase I was to determine the feasibility and define the concept for the EECP located at a specific site and to develop a Research, Development, and Testing (RD and T) Plan for implementation in Phase II. This objective has now been accomplished. A specific site, Motiva Refinery in Port Arthur, Texas, has been selected as the location best suited for the EECP. The specific work requirements of Phase I included: Prepare an EECP Preliminary Concept Report covering Tasks 2-8 specified in the Cooperative Agreement; Develop a Research, Development, and Testing (RD and T) Plan as specified in Task 9 of the Cooperative Agreement for implementation in Phase II; and Develop a Preliminary Project Financing Plan for the EECP Project as specified in Task 10 of the Cooperative Agreement. This document is the Preliminary Project Financing Plan for the design, construction, and operation of the EECP at the Motiva Port Arthur Refinery.

  16. Plant salt-tolerance mechanisms

    SciTech Connect (OSTI)

    Deinlein, Ulrich; Stephan, Aaron B.; Horie, Tomoaki; Luo, Wei; Xu, Guohua; Schroeder, Julian I.

    2014-06-01

    Crop performance is severely affected by high salt concentrations in soils. To engineer more salt-tolerant plants it is crucial to unravel the key components of the plant salt-tolerance network. Here we review our understanding of the core salt-tolerance mechanisms in plants. Recent studies have shown that stress sensing and signaling components can play important roles in regulating the plant salinity stress response. We also review key Na+ transport and detoxification pathways and the impact of epigenetic chromatin modifications on salinity tolerance. In addition, we discuss the progress that has been made towards engineering salt tolerance in crops, including marker-assisted selection and gene stacking techniques. We also identify key open questions that remain to be addressed in the future.

  17. The Annual Growth In Plants

    E-Print Network [OSTI]

    Courtright, J. E.

    1903-01-01

    KU ScholarWorks | The University of Kansas Pre-1923 Dissertations and Theses Collection The Annual Growth In Plants 1903 by J. E. Courtright This work was digitized by the Scholarly Communications program staff in the KU Libraries’ Center...

  18. Water Filtration Using Plant Xylem

    E-Print Network [OSTI]

    Boutilier, Michael Stephen Ha

    Effective point-of-use devices for providing safe drinking water are urgently needed to reduce the global burden of waterborne disease. Here we show that plant xylem from the sapwood of coniferous trees – a readily available, ...

  19. USF PHYSICAL PLANT VEHICLE MAINTENANCE

    E-Print Network [OSTI]

    Meyers, Steven D.

    USF PHYSICAL PLANT VEHICLE MAINTENANCE TELEPHONE NO. 974-2500 GAS PUMP AUTHORIZATION FORM PLEASE. _____ THE FOLLOWING PERSONNEL ARE AUTHORIZED BY THIS DOCUMENT TO PUMP GASOLINE/DIESEL FUEL FOR OUR USF OWNED VEHICLES

  20. A neighborhood alternative energy plant

    E-Print Network [OSTI]

    Brooks, Douglas James

    1982-01-01

    A design that proposes the redefinition of the role of a power plant facility within a community by creating a humane environment for recreation, education, community gathering, living, and energy production; rather than ...

  1. Computer Control of Unattended Plants 

    E-Print Network [OSTI]

    Vinson, D. R.; Chatterjee, N.

    1984-01-01

    Providing a cost-effective and reliable computer monitoring, control, and optimization package is a greater challenge for small, unattended plants than for large energy intensive facilities. This paper describes the successful application of a...

  2. Development of BWR plant analyzer

    SciTech Connect (OSTI)

    Wulff, W.; Cheng, H.S.; Lekach, S.V.; Stritar, A.; Mallen, A.N.

    1984-01-01

    The BWR Plant Analyzer has been developed for realistic and accurate simulations of normal and severe abnormal transients in BWR power plants at high simulation speeds, low capital and operating costs and with outstanding user conveniences. The simulation encompasses neutron kinetics, heat conduction in fuel structures, nonequilibrium, nonhomogeneous coolant dynamics, steam line acoustics, and the dynamics of turbines, condensers, feedwater pumps and heaters, of the suppression pool, the control systems and the plant protection systems. These objectives have been achieved. Advanced modeling, using extensively analytical integration and dynamic evaluation of analytical solutions, has been combined with modern minicomputer technology for high-speed simulation of complex systems. The High-Speed Interactive Plant Analyzer code HIPA-BWR has been implemented on the AD10 peripheral parallel processor.

  3. Morris Plant Energy Efficiency Program 

    E-Print Network [OSTI]

    Betczynski, M. T.

    2004-01-01

    to existing operating practices. Plant management also takes an active role in recognizing accomplishments and holding personnel accountable for continued improvement in energy efficiency. The control systems group at Equistar has integrated an Aspen...

  4. Upgrading coal plant damper drives

    SciTech Connect (OSTI)

    Hood, N.R.; Simmons, K. [Alamaba Power (United States)

    2009-11-15

    The replacement of damper drives on two coal-fired units at the James H. Miller Jr. electric generating plant by Intelligent Contrac electric rotary actuators is discussed. 2 figs.

  5. Plant salt-tolerance mechanisms

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Deinlein, Ulrich; Stephan, Aaron B.; Horie, Tomoaki; Luo, Wei; Xu, Guohua; Schroeder, Julian I.

    2014-06-01

    Crop performance is severely affected by high salt concentrations in soils. To engineer more salt-tolerant plants it is crucial to unravel the key components of the plant salt-tolerance network. Here we review our understanding of the core salt-tolerance mechanisms in plants. Recent studies have shown that stress sensing and signaling components can play important roles in regulating the plant salinity stress response. We also review key Na+ transport and detoxification pathways and the impact of epigenetic chromatin modifications on salinity tolerance. In addition, we discuss the progress that has been made towards engineering salt tolerance in crops, including marker-assisted selectionmore »and gene stacking techniques. We also identify key open questions that remain to be addressed in the future.« less

  6. Scale Insects on Ornamental Plants 

    E-Print Network [OSTI]

    Muegge, Mark A.; Merchant, Michael E.

    2000-08-21

    Scale insects damage landscape plants, shrubs and trees. This publication explains how to control scale insects economically without damaging the environment, including sampling for scale crawlers, using natural enemies and applying pesticides....

  7. COKEMASTER: Coke plant management system

    SciTech Connect (OSTI)

    Johanning, J.; Reinke, M. [Krupp Koppers GmbH, Essen (Germany)

    1996-12-31

    To keep coke utilization in ironmaking as competitive as possible, the potential to improve the economics of coke production has to be utilized. As one measure to meet this need of its customers, Krupp Koppers has expanded its existing ECOTROL computer system for battery heating control to a comprehensive Coke Plant Management System. Increased capacity utilization, lower energy consumption, stabilization of plant operation and ease of operation are the main targets.

  8. Researching power plant water recovery

    SciTech Connect (OSTI)

    NONE

    2008-04-01

    A range of projects supported by NETl under the Innovations for Existing Plant Program are investigating modifications to power plant cooling systems for reducing water loss, and recovering water from the flue gas and the cooling tower. This paper discusses two technologies showing particular promise condense water that is typically lost to evaporation, SPX technologies' Air2Air{sup trademark} condenses water from a cooling tower, while Lehigh University's process condenses water and acid in flue gas. 3 figs.

  9. Common Aquatic Plants -- Identification, Control. 

    E-Print Network [OSTI]

    Klussmann, Wallace G. (Wallace Glenn); Lowman, Fred G.

    1964-01-01

    root. Duckweed float freely and are moved by wind current. Often they can be removed mechanically by net or similar device when plants are crowded against the shore by a strong wind. Use Chemical Control No.8. FLOATING PLANTS WATER STAR GRASS.... The genus Potamogeton J commonly called pond weeds, includes many species common to Texas waters. Group characteristics include alternate leaves with flowers and fruits in spikes or heads. Many have two kinds of leaves: (1) floating and firm textured and (2...

  10. Controlling Diseases on Ornamental Plants

    E-Print Network [OSTI]

    Horne, C. Wendell; Johnson, Jerral D.; Walla, Walter J.

    1979-01-01

    on elms and other shade trees. Mushroom-type fu ngal growths appear on trunk, limbs or roots near the soil surface. Rots may be present for several years before mushrooms ap pear. Tree becomes sus ceptible to wi nd damage. Plants may die back..., irises, lilies, narcissus and tulips. ROOT DISEASES Disease Cotton root rot (fungi) Crown gall Mushroom root rot Symptoms Small flowering plants die within a few days. Shrubs and trees die more slowly. Large trees may die within several...

  11. EARLY ENTRANCE COPRODUCTION PLANT

    SciTech Connect (OSTI)

    Fred D. Brent; Lalit Shah; Earl Berry; Charles H. Schrader; John Anderson; Ming He; James F. Stevens; Centha A. Davis; Michael Henley; Jerome Mayer; Harry Tsang; Jimell Erwin; Jennifer Adams; Michael Tillman; Chris Taylor; Marjan J. Roos; Robert F. Earhart

    2004-01-27

    The overall objective of this project is the three phase development of an Early Entrance Coproduction Plant (EECP) which uses petroleum coke to produce at least one product from at least two of the following three categories: (1) electric power (or heat), (2) fuels, and (3) chemicals using ChevronTexaco's proprietary gasification technology. The objective of Phase I is to determine the feasibility and define the concept for the EECP located at a specific site; develop a Research, Development, and Testing (RD&T) Plan to mitigate technical risks and barriers; and prepare a Preliminary Project Financing Plan. The objective of Phase II is to implement the work as outlined in the Phase I RD&T Plan to enhance the development and commercial acceptance of coproduction technology. The objective of Phase III is to develop an engineering design package and a financing and testing plan for an EECP located at a specific site. The project's intended result is to provide the necessary technical, economic, and environmental information needed by industry to move the EECP forward to detailed design, construction, and operation. The partners in this project are Texaco Energy Systems LLC or TES (a subsidiary of ChevronTexaco), General Electric (GE), Praxair, and Kellogg Brown & Root (KBR) in addition to the U.S. Department of Energy (DOE). TES is providing gasification technology and Fischer-Tropsch (F-T) technology developed by Rentech, GE is providing combustion turbine technology, Praxair is providing air separation technology, and KBR is providing engineering. Each of the EECP subsystems was assessed for technical risks and barriers. A plan was developed to mitigate the identified risks (Phase II RD&T Plan, October 2000). The potential technical and economic risks to the EECP from Task 2.5 can be mitigated by demonstrating that the end-use products derived from the upgrading of the F-T synthesis total liquid product can meet or exceed current specifications for the manufacture of ethylene and propylene chemicals from F-T naphtha, for the generation of hydrogen from F-T naphtha to power fuel cells, for direct blending of F-T diesels into transportation fuels, for the conversion of F-T heavy product wax to transportation fuels, and the conversion of F-T Heavy product wax to a valuable high melting point food-grade specialty wax product. Product evaluations conducted under Task 2.5 of Phase II successfully mitigated the above technical and economic risks to the EECP with the development of product yields and product qualities for the production of chemicals, transportation fuels, and specialty food-grade waxes from the F-T synthesis products.

  12. EARLY ENTRANCE COPRODUCTION PLANT

    SciTech Connect (OSTI)

    John Anderson; Charles Schrader

    2004-01-26

    In 1999, the U. S. Department of Energy (DOE) awarded a Cooperative Agreement to Texaco Energy Systems Inc. to provide a preliminary engineering design of an Early Entrance Coproduction Plant (EECP). Since the award, continuous and diligent work has been undertaken to achieve the design of an economical facility that makes strides toward attaining the goal of DOE's Vision 21 Program. The objective of the EECP is to convert coal and/or petroleum coke to power while coproducing transportation fuels, chemicals, and useful utilities such as steam. This objective is being pursued in a three-phase effort through the partnership of the DOE with prime contractor Texaco Energy Systems, LLC. (TES), the successor to Texaco Energy Systems, Inc. The key subcontractors to TES include General Electric (GE), Praxair, and Kellogg Brown and Root. ChevronTexaco provided gasification technology and Rentech Inc.'s Fischer-Tropsch (F-T) technology that has been developed for non-natural gas sources. GE provided gas turbine technology for the combustion of low energy content gas. Praxair provided air separation technology and KBR provided engineering to integrate the facility. A conceptual design was completed in Phase I and the report was accepted by the DOE in May 2001. The Phase I work identified risks and critical research, development, and testing that would improve the probability of technical success of the EECP. The objective of Phase II was to mitigate the risks by executing research, development, and testing. Results from the Phase II work are the subject of this report. As the work of Phase II concluded, it became evident that sufficient, but not necessarily complete, technical information and data would be available to begin Phase III - Preliminary Engineering Design. Work in Phase II requires additional technical development work to correctly apply technology at a specific site. The project's intended result is to provide the necessary technical, economic, and environmental information needed by industry to move the EECP forward to detailed design, construction, and operation. The decision to proceed with Phase III centers on locating a new site and favorable commercial and economic factors.

  13. EARLY ENTRANCE COPRODUCTION PLANT

    SciTech Connect (OSTI)

    David Storm; Govanon Nongbri; Steve Decanio; Ming He; Lalit Shah; Charles Schrader; Earl Berry; Peter Ricci; Belma Demirel; Charles Benham; Mark Bohn

    2004-01-12

    The overall objective of this project is the three phase development of an Early Entrance Coproduction Plant (EECP) which uses petroleum coke to produce at least one product from at least two of the following three categories: (1) electric power (or heat), (2) fuels, and (3) chemicals using ChevronTexaco's proprietary gasification technology. The objective of Phase I is to determine the feasibility and define the concept for the EECP located at a specific site; develop a Research, Development, and Testing (RD&T) Plan to mitigate technical risks and barriers; and prepare a Preliminary Project Financing Plan. The objective of Phase II is to implement the work as outlined in the Phase I RD&T Plan to enhance the development and commercial acceptance of coproduction technology. The objective of Phase III is to develop an engineering design package and a financing and testing plan for an EECP located at a specific site. The project's intended result is to provide the necessary technical, economic, and environmental information needed by industry to move the EECP forward to detailed design, construction, and operation. The partners in this project are Texaco Energy Systems LLC or TES (a subsidiary of ChevronTexaco), General Electric (GE), Praxair, and Kellogg Brown & Root (KBR) in addition to the U.S. Department of Energy (DOE). TES is providing gasification technology and Fischer-Tropsch (F-T) technology developed by Rentech, Inc., GE is providing combustion turbine technology, Praxair is providing air separation technology, and KBR is providing engineering. During Phase I, a design basis for the Fischer-Tropsch Synthesis section was developed based on limited experience with the specified feed gas and operating conditions. The objective of this Task in Phase II RD&T work was to confirm the performance of the F-T reactor at the set design conditions. Although much of the research, development, and testing work were done by TES outside of this project, several important issues were addressed in this phase of the project. They included Rejuvenation/Regeneration of the Fischer-Tropsch Catalyst, online Catalyst Withdrawal and Addition from the synthesis reactor, and the Fischer-Tropsch Design Basis Confirmation. In Phase III the results from these RD&T work will be incorporated in developing the engineering design package. This Topical Report documents the Phase II RD&T work that was completed for this task.

  14. EARLY ENTRANCE COPRODUCTION PLANT

    SciTech Connect (OSTI)

    Fred D. Brent; Lalit Shah; Earl Berry; Charles H. Schrader; John Anderson; J. Erwin; Matthew G. Banks; Terry L. Ullman

    2004-01-12

    The overall objective of this project is the three phase development of an Early Entrance Coproduction Plant (EECP) which uses petroleum coke to produce at least one product from at least two of the following three categories: (1) electric power (or heat), (2) fuels, and (3) chemicals using ChevronTexaco's proprietary gasification technology. The objective of Phase I is to determine the feasibility and define the concept for the EECP located at a specific site; develop a Research, Development, and Testing (RD&T) Plan to mitigate technical risks and barriers; and prepare a Preliminary Project Financing Plan. The objective of Phase II is to implement the work as outlined in the Phase I RD&T Plan to enhance the development and commercial acceptance of coproduction technology. The objective of Phase III is to develop an engineering design package and a financing and testing plan for an EECP located at a specific site. The project's intended result is to provide the necessary technical, economic, and environmental information needed by industry to move the EECP forward to detailed design, construction, and operation. The partners in this project are Texaco Energy Systems LLC or TES (a subsidiary of ChevronTexaco), General Electric (GE), Praxair, and Kellogg Brown & Root (KBR) in addition to the U.S. Department of Energy (DOE). TES is providing gasification technology and Fischer-Tropsch (F-T) technology developed by Rentech, GE is providing combustion turbine technology, Praxair is providing air separation technology, and KBR is providing engineering. Each of the EECP subsystems was assessed for technical risks and barriers. A plan was developed to mitigate the identified risks (Phase II RD&T Plan, October 2000). Phase II RD&T Task 2.6 identified as potential technical risks to the EECP the fuel/engine performance and emissions of the F-T diesel fuel products. Hydrotreating the neat F-T diesel product reduces potentially reactive olefins, oxygenates, and acids levels and alleviates corrosion and fuel stability concerns. Future coproduction plants can maximize valuable transportation diesel by hydrocracking the F-T Synthesis wax product to diesel and naphtha. The upgraded neat F-T diesel, hydrotreater F-T diesel, and hydrocracker F-T diesel products would be final blending components in transportation diesel fuel. Phase II RD&T Task 2.6 successfully carried out fuel lubricity property testing, fuel response to lubricity additives, and hot-start transient emission tests on a neat F-T diesel product, a hydrocracker F-T diesel product, a blend of hydrotreater and hydrocracker F-T diesel products, and a Tier II California Air Resources Board (CARB)-like diesel reference fuel. Only the neat F-T diesel passed lubricity inspection without additive while the remaining three fuel candidates passed with conventional additive treatment. Hot-start transient emission tests were conducted on the four fuels in accordance with the U.S. Environmental Protection Agency (EPA) Federal Test Procedure (FTP) specified in Code of Federal Regulations, Title 40, Part 86, and Subpart N on a rebuilt 1991 Detroit Diesel Corporation Series 60 heavy-duty diesel engine. Neat F-T diesel fuel reduced oxides of nitrogen (NO{sub x}), total particulate (PM), hydrocarbons (HC), carbon monoxide (CO), and the Soluble Organic Fraction (SOF) by 4.5%, 31%, 50%, 29%, and 35%, respectively, compared to the Tier II CARB-like diesel. The hydrocracker F-T diesel product and a blend of hydrocracker and hydrotreater F-T diesel products also reduced NO{sub x}, PM, HC, CO and SOF by 13%, 16% to 17%, 38% to 63%, 17% to 21% and 21% to 39% compared to the Tier II CARB-like diesel. The fuel/engine performance and emissions of the three F-T diesel fuels exceed the performance of a Tier II CARB-like diesel. Phase II RD&T Task 2.6 successfully met the lubricity property testing and F-T diesel fuel hot-start transient emissions test objectives. The results of the testing help mitigate potential economic risks on obtaining a premium price for the F-T diesel fuel

  15. 12-11-24 7:47 PMModernity, the Cold War, and New Whig Histories of Ideas, Pt. 3 Ether Wave Propaganda Page 1 of 6http://etherwave.wordpress.com/2012/11/17/modernity-the-cold-war-and-new-whig-histories-of-ideas-pt-3/

    E-Print Network [OSTI]

    Solovey, Mark

    12-11-24 7:47 PMModernity, the Cold War, and New Whig Histories of Ideas, Pt. 3 « Ether Wave Propaganda Page 1 of 6http://etherwave.wordpress.com/2012/11/17/modernity-the-cold-war-and-new-whig-histories-of-ideas-pt-3/ Modernity, the Cold War, and New Whig Histories of Ideas, Pt. 3 November 17, 2012 Posted

  16. 13-03-09 9:32 PMModernity, the Cold War, and New Whig Histories of Ideas, Pt. 1 | Ether Wave Propaganda Page 1 of 6http://etherwave.wordpress.com/2012/09/22/modernity-the-cold-war-and-new-whig-histories-of-ideas-pt-1/

    E-Print Network [OSTI]

    Solovey, Mark

    13-03-09 9:32 PMModernity, the Cold War, and New Whig Histories of Ideas, Pt. 1 | Ether Wave Propaganda Page 1 of 6http://etherwave.wordpress.com/2012/09/22/modernity-the-cold-war-and-new-whig-histories-of-ideas-pt-1/ Modernity, the Cold War, and New Whig Histories of Ideas, Pt. 1 September 22, 2012 Posted

  17. 13-03-09 9:37 PMModernity, the Cold War, and New Whig Histories of Ideas, Pt. 2 | Ether Wave Propaganda Page 1 of 4http://etherwave.wordpress.com/2012/10/21/modernity-the-cold-war-and-new-whig-histories-of-ideas-pt-2/

    E-Print Network [OSTI]

    Solovey, Mark

    13-03-09 9:37 PMModernity, the Cold War, and New Whig Histories of Ideas, Pt. 2 | Ether Wave Propaganda Page 1 of 4http://etherwave.wordpress.com/2012/10/21/modernity-the-cold-war-and-new-whig-histories-of-ideas-pt-2/ Modernity, the Cold War, and New Whig Histories of Ideas, Pt. 2 October 21, 2012 Posted

  18. Pilot Plant Options for the MFE Roadmap

    E-Print Network [OSTI]

    Pilot Plant Options for the MFE Roadmap Hutch Neilson Princeton Plasma Physics Laboratory International Workshop MFE Roadmapping for the ITER Era Princeton, NJ 10 September 2011 #12;Outline 2 · Pilot plant ­ mission, motivation, and description. · Role of pilot plants on the Roadmap to Demo. Pilot Plant

  19. Fate of Radionuclides in Wastewater Treatment Plants

    E-Print Network [OSTI]

    Shabani Samgh Abadi, Farzaneh

    2013-01-01

    nuclear facility accident was the 2011 Fukushima Daiichi power plant accident in Japan, following the tsunami.

  20. Plant Pathology 290 Graduate Seminar Series

    E-Print Network [OSTI]

    Ishida, Yuko

    Plant Pathology 290 Graduate Seminar Series Fall 2014 CRN: 57411 Mondays 9:00-10:00am 115 Hutchison Storer Seminar Speaker Professor, Plant Pathology University of Wisconsin-Madison Multi-gene copy number Detection of plant diseases by smell. October 27 Jeremy Warren, PhD Candidate, Plant Pathology Exit Seminar

  1. Biochemical Conversion Pilot Plant (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2012-06-01

    This fact sheet provides information about Biochemical Conversion Pilot Plant capabilities and resources at NREL.

  2. Method of identifying plant pathogen tolerance

    DOE Patents [OSTI]

    Ecker, Joseph R. (Erial, NJ); Staskawicz, Brian J. (Castro Valley, CA); Bent, Andrew F. (Piedmont, CA); Innes, Roger W. (Bloomington, IN)

    1997-10-07

    A process for identifying a plant having disease tolerance comprising administering to a plant an inhibitory amount of ethylene and screening for ethylene insensitivity, thereby identifying a disease tolerant plant, is described. Plants identified by the foregoing process are also described.

  3. Method of identifying plant pathogen tolerance

    DOE Patents [OSTI]

    Ecker, J.R.; Staskawicz, B.J.; Bent, A.F.; Innes, R.W.

    1997-10-07

    A process for identifying a plant having disease tolerance comprising administering to a plant an inhibitory amount of ethylene and screening for ethylene insensitivity, thereby identifying a disease tolerant plant, is described. Plants identified by the foregoing process are also described. 7 figs.

  4. Fate of Radionuclides in Wastewater Treatment Plants

    E-Print Network [OSTI]

    Shabani Samgh Abadi, Farzaneh

    2013-01-01

    by Aerobic Treatment. Journal (Water Pollution ControlWastewater Treatment Plants. Journal (Water Pollution

  5. Waste Treatment Plant - 12508

    SciTech Connect (OSTI)

    Harp, Benton; Olds, Erik

    2012-07-01

    The Waste Treatment Plant (WTP) will immobilize millions of gallons of Hanford's tank waste into solid glass using a proven technology called vitrification. The vitrification process will turn the waste into a stable glass form that is safe for long-term storage. Our discussion of the WTP will include a description of the ongoing design and construction of this large, complex, first-of-a-kind project. The concept for the operation of the WTP is to separate high-level and low-activity waste fractions, and immobilize those fractions in glass using vitrification. The WTP includes four major nuclear facilities and various support facilities. Waste from the Tank Farms is first pumped to the Pretreatment Facility at the WTP through an underground pipe-in-pipe system. When construction is complete, the Pretreatment Facility will be 12 stories high, 540 feet long and 215 feet wide, making it the largest of the four major nuclear facilities that compose the WTP. The total size of this facility will be more than 490,000 square feet. More than 8.2 million craft hours are required to construct this facility. Currently, the Pretreatment Facility is 51 percent complete. At the Pretreatment Facility the waste is pumped to the interior waste feed receipt vessels. Each of these four vessels is 55-feet tall and has a 375,000 gallon capacity, which makes them the largest vessels inside the Pretreatment Facility. These vessels contain a series of internal pulse-jet mixers to keep incoming waste properly mixed. The vessels are inside the black-cell areas, completely enclosed behind thick steel-laced, high strength concrete walls. The black cells are designed to be maintenance free with no moving parts. Once hot operations commence the black-cell area will be inaccessible. Surrounded by black cells, is the 'hot cell canyon'. The hot cell contains all the moving and replaceable components to remove solids and extract liquids. In this area, there is ultrafiltration equipment, cesium-ion exchange columns, evaporator boilers and recirculation pumps, and various mechanical process pumps for transferring process fluids. During the first phase of pretreatment, the waste will be concentrated using an evaporation process. Solids will be filtered out, and the remaining soluble, highly radioactive isotopes will be removed using an ion-exchange process. The high-level solids will be sent to the High-Level Waste (HLW) Vitrification Facility, and the low activity liquids will be sent to the Low-Activity Waste (LAW) Vitrification Facility for further processing. The high-level waste will be transferred via underground pipes to the HLW Facility from the Pretreatment Facility. The waste first arrives at the wet cell, which rests inside a black-cell area. The pretreated waste is transferred through shielded pipes into a series of melter preparation and feed vessels before reaching the melters. Liquids from various facility processes also return to the wet cell for interim storage before recycling back to the Pretreatment Facility. (authors)

  6. EARLY ENTRANCE COPRODUCTION PLANT

    SciTech Connect (OSTI)

    Abdalla H. Ali; Raj Kamarthi; John H. Anderson; Earl R. Berry; Charles H. Schrader; Lalit S. Shah

    2003-04-16

    The overall objective of this project is the three phase development of an Early Entrance Coproduction Plant (EECP) which produces at least one product from at least two of the following three categories: (1) electric power (or heat), (2) fuels, and (3) chemicals using ChevronTexaco's proprietary gasification technology. The objective of Phase I is to determine the feasibility and define the concept for the EECP located at a specific site; develop a Research, Development, and Testing (RD&T) Plan to mitigate technical risks and barriers; and prepare a Preliminary Project Financing Plan. The objective of Phase II is to implement the work as outlined in the Phase I RD&T Plan to enhance the development and commercial acceptance of coproduction technology. The objective of Phase III is to develop an engineering design package and a financing and testing plan for an EECP located at a specific site. The project's intended result is to provide the necessary technical, economic, and environmental information needed by industry to move the EECP forward to detailed design, construction, and operation. The partners in this project are TES (a subsidiary of ChevronTexaco), General Electric (GE), Praxair, and Kellogg Brown & Root (KBR) in addition to the U.S. Department of Energy (DOE). TES is providing gasification technology and Fischer-Tropsch (F-T) technology developed by Rentech, GE is providing combustion turbine technology, Praxair is providing air separation technology, and KBR is providing engineering. During Phase I the team identified the integration of the water produced in the F-T synthesis section with the gasification section as an area of potential synergy. By utilizing the F-T water in the petroleum coke slurry for the gasifier, the EECP can eliminate a potential waste stream and reduce capital costs. There is a low technical risk for this synergy, however, the economic risk, particularly in regards to the water, can be high. The economic costs include the costs of treating the water to meet the locally applicable environmental standards. This option may require expensive chemicals and treatment facilities. EECP Phase II included tests conducted to confirm the viability of integrating F-T water in the slurry feed for the gasifier. Testing conducted at ChevronTexaco's Montebello Technology Center (MTC) included preparing slurries made using petroleum coke with F-T water collected at the LaPorte Alternative Fuels Development Unit (AFDU). The work included bench scale tests to determine the slurry ability of the petroleum coke and F-T water. The results of the tests show that F-T water does not adversely affect slurries for the gasifier. There are a few cases where in fact the addition of F-T water caused favorable changes in viscosity of the slurries. This RD&T task was executed in Phase II and results are reported herein.

  7. EARLY ENTRANCE COPRODUCTION PLANT

    SciTech Connect (OSTI)

    Randy Roberts

    2003-04-25

    The overall objective of this project is the three phase development of an Early Entrance Coproduction Plant (EECP) which produces at least one product from at least two of the following three categories: (1) electric power (or heat), (2) fuels, and (3) chemicals using petroleum coke and ChevronTexaco's proprietary gasification technology. The objective of Phase I was to determine the feasibility and define the concept for the EECP located at a specific site; develop a Research, Development, and Testing (RD&T) Plan to mitigate technical risks and barriers; and prepare a Preliminary Project Financing Plan. The objective of Phase II is to implement the work as outlined in the Phase I RD&T Plan to enhance the development and commercial acceptance of coproduction technology. The objective of Phase III is to develop an engineering design package and a financing and testing plan for an EECP located at a specific site. The project's intended result is to provide the necessary technical, economic, and environmental information needed by industry to move the EECP forward to detailed design, construction, and operation. The partners in this project are Texaco Energy Systems LLC. (a subsidiary of ChevronTexaco), General Electric (GE), Praxair, and Kellogg Brown & Root (KBR) in addition to the U.S. Department of Energy (DOE). ChevronTexaco is providing gasification technology and Fischer-Tropsch technology developed by Rentech, GE is providing combustion turbine technology, Praxair is providing air separation technology and KBR is providing engineering. Each of the EECP subsystems were assessed for technical risks and barriers. A plan was identified to mitigate the identified risks (Phase II RD&T Plan, October 2000). The RD&T Plan identified F-T reactor scale-up as a potential technical risk. The objective of Task 2.3 was to confirm engineering models that allow scale-up to commercial slurry phase bubble column (SPBC) reactors operating in the churn-turbulent flow regime. In developmental work outside the scope of this project, historical data, literature references, and a scale-up from a 1 1/2-in. (3.8 cm) to 6-ft (1.8 m) SPBC reactor have been reviewed. This review formed the background for developing scale-up models for a SPBC reactor operating in the churn-turbulent flow regime. The necessary fundamental physical parameters have been measured and incorporated into the mathematical catalyst/kinetic model developed from the SPBC and CSTR work outside the scope of this EECP project. The mathematical catalyst/kinetic model was used to compare to experimental data obtained at Rentech during the EECP Fischer-Tropsch Confirmation Run (Task 2.1; reported separately). The prediction of carbon monoxide (CO) conversion as a function of days on stream compares quite closely to the experimental data.

  8. Expression of multiple proteins in transgenic plants

    DOE Patents [OSTI]

    Vierstra, Richard D. (Madison, WI); Walker, Joseph M. (Madison, WI)

    2002-01-01

    A method is disclosed for the production of multiple proteins in transgenic plants. A DNA construct for introduction into plants includes a provision to express a fusion protein of two proteins of interest joined by a linking domain including plant ubiquitin. When the fusion protein is produced in the cells of a transgenic plant transformed with the DNA construction, native enzymes present in plant cells cleave the fusion protein to release both proteins of interest into the cells of the transgenic plant. Since the proteins are produced from the same fusion protein, the initial quantities of the proteins in the cells of the plant are approximately equal.

  9. The Water Circuit of the Plants - Do Plants have Hearts ?

    E-Print Network [OSTI]

    Wolfgang Kundt; Eva Gruber

    2006-03-17

    There is a correspondence between the circulation of blood in all higher animals and the circulation of sap in all higher plants - up to heights h of 140 m - through the xylem and phloem vessels. Plants suck in water from the soil, osmotically through the roothair zone, and subsequently lift it osmotically again, and by capillary suction (via their buds, leaves, and fruits) into their crowns. In between happens a reverse osmosis - the endodermis jump - realized by two layers of subcellular mechanical pumps in the endodermis walls which are powered by ATP, or in addition by two analogous layers of such pumps in the exodermis. The thus established root pressure helps forcing the absorbed ground water upward, through the whole plant, and often out again, in the form of guttation, or exudation.

  10. Plants having modified response to ethylene

    DOE Patents [OSTI]

    Meyerowitz, E.M.; Chang, C.; Bleecker, A.B.

    1997-11-18

    The invention includes transformed plants having at least one cell transformed with a modified ETR nucleic acid. Such plants have a phenotype characterized by a decrease in the response of at least one transformed plant cell to ethylene as compared to a plant not containing the transformed plant cell. Tissue and/or temporal specificity for expression of the modified ETR nucleic acid is controlled by selecting appropriate expression regulation sequences to target the location and/or time of expression of the transformed nucleic acid. The plants are made by transforming at least one plant cell with an appropriate modified ETR nucleic acid, regenerating plants from one or more of the transformed plant cells and selecting at least one plant having the desired phenotype. 31 figs.

  11. Plants having modified response to ethylene

    DOE Patents [OSTI]

    Meyerowitz, Elliot M. (Pasadena, CA); Chang, Caren (Pasadena, CA); Bleecker, Anthony B. (Madison, WI)

    1998-01-01

    The invention includes transformed plants having at least one cell transformed with a modified ETR nucleic acid. Such plants have a phenotype characterized by a decrease in the response of at least one transformed plant cell to ethylene as compared to a plant not containing the transformed plant cell. Tissue and/or temporal specificity for expression of the modified ETR nucleic acid is controlled by selecting appropriate expression regulation sequences to target the location and/or time of expression of the transformed nucleic acid. The plants are made by transforming at least one plant cell with an appropriate modified ETR nucleic acid, regenerating plants from one or more of the transformed plant cells and selecting at least one plant having the desired phenotype.

  12. Plants having modified response to ethylene

    DOE Patents [OSTI]

    Meyerowitz, Elliott M. (Pasadena, CA); Chang, Caren (Pasadena, CA); Bleecker, Anthony B. (Madison, WI)

    1997-01-01

    The invention includes transformed plants having at least one cell transformed with a modified ETR nucleic acid. Such plants have a phenotype characterized by a decrease in the response of at least one transformed plant cell to ethylene as compared to a plant not containing the transformed plant cell. Tissue and/or temporal specificity for expression of the modified ETR nucleic acid is controlled by selecting appropriate expression regulation sequences to target the location and/or time of expression of the transformed nucleic acid. The plants are made by transforming at least one plant cell with an appropriate modified ETR nucleic acid, regenerating plants from one or more of the transformed plant cells and selecting at least one plant having the desired phenotype.

  13. Plants having modified response to ethylene

    DOE Patents [OSTI]

    Meyerowitz, E.M.; Chang, C.; Bleecker, A.B.

    1998-10-20

    The invention includes transformed plants having at least one cell transformed with a modified ETR nucleic acid. Such plants have a phenotype characterized by a decrease in the response of at least one transformed plant cell to ethylene as compared to a plant not containing the transformed plant cell. Tissue and/or temporal specificity for expression of the modified ETR nucleic acid is controlled by selecting appropriate expression regulation sequences to target the location and/or time of expression of the transformed nucleic acid. The plants are made by transforming at least one plant cell with an appropriate modified ETR nucleic acid, regenerating plants from one or more of the transformed plant cells and selecting at least one plant having the desired phenotype. 67 figs.

  14. NRES 725 PLANT PHYSIOLOGICAL ECOLOGY Reading List Water Balance of Plants

    E-Print Network [OSTI]

    Nowak, Robert S.

    1 NRES 725 ­ PLANT PHYSIOLOGICAL ECOLOGY Fall 2008 Reading List ­ Water Balance of Plants I) Water Balance of Plants A) Water potential B) Soil, plant, air continuum C) Physiological control 1) Roots-256 *Steudle (01) Ann Rev Plant Phy Mol Biol 52:847-875 Kirkham (05) pp 207-216 Kramer & Boyer (95) pp 115

  15. NUCLEAR POWER PLANT Nuclear power plants have safety and security procedures in place and

    E-Print Network [OSTI]

    NUCLEAR POWER PLANT ACCIDENTS Nuclear power plants have safety and security procedures in place and are closely monitored by the Nuclear Regulatory Commission (NRC). An accident at a nuclear power plant could of nuclear power plant accidents? Radioactive materials in the plume from the nuclear power plant can settle

  16. EARLY ENTRANCE COPRODUCTION PLANT

    SciTech Connect (OSTI)

    Abdalla H. Ali; John H. Anderson; Earl R. Berry; Charles H. Schrader; Lalit S. Shah

    2003-04-16

    The overall objective of this project is the three phase development of an Early Entrance Coproduction Plant (EECP) which produces at least one product from at least two of the following three categories: (1) electric power (or heat), (2) fuels, and (3) chemicals using ChevronTexaco's proprietary gasification technology. The objective of Phase I is to determine the feasibility and define the concept for the EECP located at a specific site; develop a Research, Development, and Testing (RD&T) Plan to mitigate technical risks and barriers; and prepare a Preliminary Project Financing Plan. The objective of Phase II is to implement the work as outlined in the Phase I RD&T Plan to enhance the development and commercial acceptance of coproduction technology. The objective of Phase III is to develop an engineering design package and a financing and testing plan for an EECP located at a specific site. The project's intended result is to provide the necessary technical, economic, and environmental information needed by industry to move the EECP forward to detailed design, construction, and operation. The partners in this project are TES (a subsidiary of ChevronTexaco), General Electric (GE), Praxair, and Kellogg Brown & Root (KBR) in addition to the U.S. Department of Energy (DOE). TES is providing gasification technology and Fischer-Tropsch (F-T) technology developed by Rentech, GE is providing combustion turbine technology, Praxair is providing air separation technology, and KBR is providing engineering. Each of the EECP subsystems were assessed for technical risks and barriers. A plan was identified to mitigate the identified risks (Phase II RD&T Plan, October 2000). The RD&T Plan identified petroleum coke characteristics as a potential technical risk. The composition of petroleum coke varies from one refinery to another. Petroleum coke characteristics are a function of the crude oil slate available at the refinery and the coker operating parameters. The specific petroleum coke characteristics at a refinery affect the design of the Gasification and Acid Gas Removal (AGR) subsystems. Knowing the petroleum coke composition provides the necessary data to proceed to the EECP Phase III engineering design of the gasification process. Based on ChevronTexaco's experience, the EECP team ranked the technical, economic, and overall risks of the petroleum coke composition related to the gasification subsystem as low. In Phase I of the EECP Project, the Motiva Port Arthur Refinery had been identified as the potential EECP site. As a result of the merger between Texaco and Chevron in October 2001, Texaco was required to sell its interest in the Motiva Enterprises LLC joint venture to Shell Oil Company and Saudi Refining Inc. To assess the possible impact of moving the proposed EECP host site to a ChevronTexaco refinery, samples of petroleum coke from two ChevronTexaco refineries were sent to MTC for bench-scale testing. The results of the analysis of these samples were compared to the Phase I EECP Gasification Design Basis developed for Motiva's Port Arthur Refinery. The analysis confirms that if the proposed EECP is moved to a new refinery site, the Phase I EECP Gasification Design Basis would have to be updated. The lower sulfur content of the two samples from the ChevronTexaco refineries indicates that if one of these sites were selected, the Sulfur Recovery Unit (SRU) might be sized smaller than the current EECP design. This would reduce the capital expense of the SRU. Additionally, both ChevronTexaco samples have a higher hydrogen to carbon monoxide ratio than the Motiva Port Arthur petroleum coke. The higher hydrogen to carbon monoxide ratio could give a slightly higher F-T products yield from the F-T Synthesis Reactor. However, the EECP Gasification Design Basis can not be updated until the site for the proposed EECP site is finalized. Until the site is finalized, the feedstock (petroleum coke) characteristics are a low risk to the EECP project.

  17. Co-treatment of VOCs in low-pH sulfide biofilters

    SciTech Connect (OSTI)

    Devinny, J.S.; Chitwood, D.E.; Choi, D.S.

    1999-07-01

    Biofiltration of off-gases from wastewater treatment plants requires removal of sulfides and volatile organic compounds. Sulfides are readily removed in low-pH biofilters filled with inorganic media. If the same biofilter could simultaneously remove the volatile organic compounds, an efficient single-step system would be possible. Laboratory work on co-treatment of toluene and sulfides, and fieldwork on several volatile compounds indicate that this is possible. Removals of over 90% of toluene, xylene, acetone, methanol, and ethylbenzene should be possible with an empty bed contact time of 60 s. Methyl tert-butyl ether, isopentane, chloroform and methylene chloride were removed with lower but still substantial efficiencies. Biofilters operated at steady state but non-neutral pHs represent a promising avenue of research.

  18. Water Filtration Using Plant Xylem

    E-Print Network [OSTI]

    Lee, Jongho; Chambers, Valerie; Venkatesh, Varsha; Karnik, Rohit

    2013-01-01

    Effective point-of-use devices for providing safe drinking water are urgently needed to reduce the global burden of waterborne disease. Here we show that plant xylem from the sapwood of coniferous trees - a readily available, inexpensive, biodegradable, and disposable material - can remove bacteria from water by simple pressure-driven filtration. Approximately 3 cm3 of sapwood can filter water at the rate of several liters per day, sufficient to meet the clean drinking water needs of one person. The results demonstrate the potential of plant xylem to address the need for pathogen-free drinking water in developing countries and resource-limited settings.

  19. Automating An Industrial Power Plant 

    E-Print Network [OSTI]

    Williams, D. R.; McCowen, R. R.

    1987-01-01

    ,OOO/year. The upgrading process began with a search for a design/ build contractor that could provide complete turn key capability, beginning with a site survey and ending with operator acceptanoe. The contractor was selected through. a group...ATING AN INDUSTRIAL POWER PLANT DAVID R. WILLIAMS, P.E. Energy Coordi?nator John Deere Component Works Waterloo, Iowa ABSTRACT The need for an upgrade of boiler and turbine controls in the 15 MW coal-fired cogeneration plant at the John Deere Component Works...

  20. PLANT DIAGNOSTIC LABORATORY The Plant Diagnostic Laboratory is a

    E-Print Network [OSTI]

    Goodman, Robert M.

    Lilac - Fungus and Mold Identification Green - Plant Identification Gray - Nematode Soil Assay 2 Identification · Fungus and Mold Identification · Nematode Assays · Acremonium Endophyte Screening · Fungicide Resistance Screening · Other Services Available by Contract Take the NJ Turnpike to Exit 9. Take Rt. 18 North

  1. Thermodynamics -2 A cogeneration plant (plant which provides both electricity and thermal energy) executes a cycle

    E-Print Network [OSTI]

    Virginia Tech

    Thermodynamics - 2 A cogeneration plant (plant which provides both electricity and thermal energy] Determine the rate of heat addition in the steam generator. Now consider an ideal, reversible cogeneration 1 2 3 45 6 Cogeneration Plant Boundary #12;

  2. Methodology for Scaling Fusion Power Plant Availability

    SciTech Connect (OSTI)

    Lester M. Waganer

    2011-01-04

    Normally in the U.S. fusion power plant conceptual design studies, the development of the plant availability and the plant capital and operating costs makes the implicit assumption that the plant is a 10th of a kind fusion power plant. This is in keeping with the DOE guidelines published in the 1970s, the PNL report1, "Fusion Reactor Design Studies - Standard Accounts for Cost Estimates. This assumption specifically defines the level of the industry and technology maturity and eliminates the need to define the necessary research and development efforts and costs to construct a one of a kind or the first of a kind power plant. It also assumes all the "teething" problems have been solved and the plant can operate in the manner intended. The plant availability analysis assumes all maintenance actions have been refined and optimized by the operation of the prior nine or so plants. The actions are defined to be as quick and efficient as possible. This study will present a methodology to enable estimation of the availability of the one of a kind (one OAK) plant or first of a kind (1st OAK) plant. To clarify, one of the OAK facilities might be the pilot plant or the demo plant that is prototypical of the next generation power plant, but it is not a full-scale fusion power plant with all fully validated "mature" subsystems. The first OAK facility is truly the first commercial plant of a common design that represents the next generation plant design. However, its subsystems, maintenance equipment and procedures will continue to be refined to achieve the goals for the 10th OAK power plant.

  3. Disease Management in Organic Plantings

    E-Print Network [OSTI]

    Isaacs, Rufus

    cooling or proper drying · Clean harvesting and processing equipment · Control insects that may createGard (Gliocladium virens) Blight Ban (Pseudomonas fluorescens) PlantShield (Trichoderma harzianum) Agri Antibiotics for control of bacterial diseases #12;Effect of Trichoderma hamatum (T382) in potting mix

  4. Advanced nuclear plant control complex

    DOE Patents [OSTI]

    Scarola, Kenneth (Windsor, CT); Jamison, David S. (Windsor, CT); Manazir, Richard M. (North Canton, CT); Rescorl, Robert L. (Vernon, CT); Harmon, Daryl L. (Enfield, CT)

    1993-01-01

    An advanced control room complex for a nuclear power plant, including a discrete indicator and alarm system (72) which is nuclear qualified for rapid response to changes in plant parameters and a component control system (64) which together provide a discrete monitoring and control capability at a panel (14-22, 26, 28) in the control room (10). A separate data processing system (70), which need not be nuclear qualified, provides integrated and overview information to the control room and to each panel, through CRTs (84) and a large, overhead integrated process status overview board (24). The discrete indicator and alarm system (72) and the data processing system (70) receive inputs from common plant sensors and validate the sensor outputs to arrive at a representative value of the parameter for use by the operator during both normal and accident conditions, thereby avoiding the need for him to assimilate data from each sensor individually. The integrated process status board (24) is at the apex of an information hierarchy that extends through four levels and provides access at each panel to the full display hierarchy. The control room panels are preferably of a modular construction, permitting the definition of inputs and outputs, the man machine interface, and the plant specific algorithms, to proceed in parallel with the fabrication of the panels, the installation of the equipment and the generic testing thereof.

  5. AQUATIC PLANT CONTROL RESEARCH PROGRAM

    E-Print Network [OSTI]

    US Army Corps of Engineers

    . PERSONAL AUTHOR(S) Twillev Robert R.· 1301. TYPE OF REPORT Barko John W. r3b. TIME COVERED r4. DATE. Plants were grown in microcosms (1.2 m ) under ambient photoperiod adjusted to 50 and 8 percent of solar radiation. The culture solution in five pairs of tanks was gradually adjusted to salinities of 0, 2, 4, 6

  6. Glutathione-S-conjugate transport in plants

    DOE Patents [OSTI]

    Rea, Philip A. (Ardmore, PA); Lu, Yu-Ping (Havertown, PA); Li, Ze-Sheng (Prospect Park, PA)

    2000-01-01

    The invention includes an isolated DNA encoding a plant GS-X pump polypeptide and an isolated preparation of a plant GS-X pump polypeptide. Also included is an isolated preparation of a nucleic acid which is antisense in orientation to a portion or all of a plant GS-X pump gene. The invention also includes a cells, vectors and transgenic plants having an isolated DNA encoding a plant GS-X pump and methods of use thereof. In addition, the invention relates to plant GS-X pump promoter sequences and the uses thereof.

  7. Methodology and application of surrogate plant PRA analysis to the Rancho Seco Power Plant: Final report

    SciTech Connect (OSTI)

    Gore, B.F.; Huenefeld, J.C.

    1987-07-01

    This report presents the development and the first application of generic probabilistic risk assessment (PRA) information for identifying systems and components important to public risk at nuclear power plants lacking plant-specific PRAs. A methodology is presented for using the results of PRAs for similar (surrogate) plants, along with plant-specific information about the plant of interest and the surrogate plants, to infer important failure modes for systems of the plant of interest. This methodology, and the rationale on which it is based, is presented in the context of its application to the Rancho Seco plant. The Rancho Seco plant has been analyzed using PRA information from two surrogate plants. This analysis has been used to guide development of considerable plant-specific information about Rancho Seco systems and components important to minimizing public risk, which is also presented herein.

  8. Growing plants on atoll soils

    SciTech Connect (OSTI)

    Stone, E L; Migvar, L; Robison, W L

    2000-02-16

    Many years ago people living on atolls depended entirely on foods gathered from the sea and reefs and grown on land. Only a few plants, such as coconut (ni), Pandanus (bob), and arrowroot (mok-mok), could be grown on the lower rainfall atolls, although adequate groundwater conditions also allowed taro (iaraj, kotak, wot) to be cultivated. On higher rainfall atolls, breadfruit (ma) was a major food source, and banana (binana, kepran), lime (laim), and taros (iaraj, kotak, wot) could be grown. The early atoll populations were experts in growing plants that were vital to sustaining their nutrition requirements and to providing materials for thatch, basketry, cordage, canoe construction, flowers, and medicine. They knew which varieties of food plants grew well or poorly on their atolls, how to propagate them, and where on their atoll they grew best. They knew the uses of most native plants and what the various woods were well suited for. Many varieties of Pandanus (bob) and breadfruit (ma) grew well with high rainfall, but only a few produced well on drier atolls. Such information had been passed down through the generations although some of it has been lost in the last century. Today there are new plants and new varieties of existing plants that can be grown on atolls. There are also new materials and information on how to grow both the old and new plants more effectively. However, there are also introduced weeds and pests to control. Today, there is also an acute need to grow more of the useful plants adapted to atolls. Increasing numbers of people living on an atoll without an equal increase in income or food production stretches the available food supplies. Much has been written about the poor conditions for plant growth on atolls. As compared with many places in the world where crops are grown, however, atolls can provide some highly favorable conditions. For instance, the driving force for plant growth is sunlight, and on atolls light is abundant throughout the year. Except on the driest of atolls, air temperature and humidity range only within limits set by the surrounding sea. There are no cold seasons, no frosts, no cold soils, no dry winds, and no periodic plagues of insects or diseases moving from miles away. Problems of soil drainage or salinity are few and easily recognized. Nor are there problems with acid soils, soil crusting, or erosion that challenge cultivators in many other areas. On the contrary, some of the black soils at the center of wide islands rank with the best soils of Russia and the American Midwest, except for their shortage of potassium and the uncertainties of rainfall. Some of these atoll soils contain more total nitrogen than many of the world's most productive agricultural soils and, in some, the total phosphorus content is so high as to be almost unbelievable--two to five tons of the element per acre. Certainly, problems exist in growing plants on atolls. There are also some special concerns not encountered in other environments, such as the wind and salt spray near shore. The two major physical limitations, however, are inadequate rainfall in some years and in many places, and soil fertility limitations. The alkaline or ''limy'' make-up of atoll soils means that a few plant nutrients, especially iron, limit growth of many introduced plants, and this is difficult to correct. As elsewhere in the world, many--but not all--atoll soils lack enough nitrogen and/or phosphorus for high yield, and all lack sufficient potassium. There is no practical way of overcoming drought except by use of tolerant plants such as coconut (ni) and Pandanus (bob), plus collection and careful use of whatever water is available. There are opportunities to overcome nutritional limitations mentioned above, first, by intensive use of all organic debris and household wastes in small gardens and, second, by use of commercial fertilizers. Imported fertilizers are expensive, certainly, but much less so on a family basis than the equivalent costs of imported food.

  9. Steam Conservation and Boiler Plant Efficiency Advancements 

    E-Print Network [OSTI]

    Fiorino, D. P.

    2000-01-01

    This paper examines several cost-effective steam conservation and boiler plant efficiency advancements that were implemented during a recently completed central steam boiler plant replacement project at a very large semiconductor manufacturing...

  10. Method to improve drought tolerance in plants

    DOE Patents [OSTI]

    Schroeder, Julian I.; Kwak, June Myoung

    2003-10-21

    A method to increase drought resistance in plants is provided. The method comprises inhibiting or disabling inward-rectifying K.sup.+ (K.sup.+.sub.in) channels in the stomatal guard cells of the plant.

  11. Review: Rare Plants of Washington State

    E-Print Network [OSTI]

    Miller, Ryder W.

    2013-01-01

    to the Rare Plants of Washington Pamela Camp and John G.John G. , eds. Field Guide to the Rare Plants of Washington.Seattle, WA: University of Washington Press, 2011. 408pp.

  12. Pioneering Gasification Plants | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    to the electric grid - the power plant is one of the world's cleanest. The plant's gas cleaning technology removes more than 98 percent of the sulfur in coal, converting it...

  13. Wood Burning Combined Cycle Power Plant 

    E-Print Network [OSTI]

    Culley, J. W.; Bourgeois, H. S.

    1984-01-01

    of the major components of the power plant. The cycle configuration is based on maximum fuel efficiency with minimum capital equipment risk. The cycle discussion includes design point performance of the power plant. The design represents a significant step...

  14. Modeling water use at thermoelectric power plants

    E-Print Network [OSTI]

    Rutberg, Michael J. (Michael Jacob)

    2012-01-01

    The withdrawal and consumption of water at thermoelectric power plants affects regional ecology and supply security of both water and electricity. The existing field data on US power plant water use, however, is of limited ...

  15. HYDROCARBONS FROM PLANTS: ANALYTICAL METHODS AND OBSERVATIONS

    E-Print Network [OSTI]

    Calvin, Melvin

    2013-01-01

    solid fuels (such as coal) to liquid fuels (petroleum) orliquid~ asked to transform our power plants from coal (liquid fuel. We have been using the green plants' stored energy in the form of coal,

  16. Essential and Fixed Oils of Kansas Plants

    E-Print Network [OSTI]

    Wellington, Earl J.

    1908-01-01

    The following report deals with those Kansas plants (one or two trees included) which are known to yield or are suspected of yielding essential and fixed oils . No cultivated plants have been considered. Bernard B, ...

  17. Interdisciplinary Research and Training Program in the Plant Sciences

    SciTech Connect (OSTI)

    Wolk, C.P.

    1992-01-01

    Research on plants continued. Topics include: Molecular basis of symbiotic plant-microbe interations; enzymatic mechanisms and regulation of plant cell wall biosynthesis; molecular mechanisms that regulate the expression of genes in plants; resistance of plants to environmental stress; studies on hormone biosynthesis and action; plant cell wall proteins; interaction of nuclear and organelle genomes; sensor transduction in plants; molecular mechanisms of trafficking in the plant cell; regulation of lipid metabolism; molecular bases of plant disease resistance mechanisms; biochemical and molecular aspects of plant pathogenesis; developmental biology of nitrogen-fixing cyanobacteria; environmental control of plant development and its relation to plant hormones.

  18. Conservation Screening Curves to Compare Efficiency Investments to Power Plants

    E-Print Network [OSTI]

    Koomey, J.G.

    2008-01-01

    Efficiency Investments to Power Plants J. Koorney, A.H.Efficiency Investments to Power Plants Jonathan Koorney,Pollution, and Avoid Power Plant Construction. Testimony

  19. Experience curves for power plant emission control technologies

    E-Print Network [OSTI]

    Rubin, Edward S.; Yeh, Sonia; Hounshell, David A; Taylor, Margaret R

    2007-01-01

    technologies applicable to power plant gas streams) and thecapacity of power plants whose flue gases are treated withat some power plants burning oil or natural gas, including

  20. Enhancing Plant Growth and Stress Tolerance through Use of Fungi...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Enhancing Plant Growth and Stress Tolerance through Use of Fungi and Bacteria that Comprise Plant Microbiomes Enhancing Plant Growth and Stress Tolerance through Use of Fungi and...

  1. Experience curves for power plant emission control technologies

    E-Print Network [OSTI]

    Rubin, Edward S.; Yeh, Sonia; Hounshell, David A; Taylor, Margaret R

    2007-01-01

    2004) ‘Experience curves for power plant emission controlLtd. Experience curves for power plant emission controlInc. Experience curves for power plant emission control

  2. Multiple soil nutrient competition between plants, microbes,...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Multiple soil nutrient competition between plants, microbes, and mineral surfaces: model development, parameterization, and example applications in several...

  3. Bayou Cogeneration Plant- A Case Study 

    E-Print Network [OSTI]

    Bray, M. E.; Mellor, R.; Bollinger, J. M.

    1985-01-01

    PLANT - A CASE STUDY Michael E. Bray Roy Mellor Joseph M. Bollinger ABSTRACT The Bayou Cogeneration Plant is a prime example of the high fuel efficiency and consequent energy savings an industrial company can realize from cogeneration. A joint..., General Electric was responsible for the entire project from cycle engineering through start up and is currently operating and maintain ing the plant. This paper describes the factors which led Big Three Industries to build a cogeneration power plant...

  4. Plant Pathology 290 Graduate Seminar Series

    E-Print Network [OSTI]

    Ishida, Yuko

    Plant Pathology 290 Graduate Seminar Series Winter 2015, CRN 87368 Seminars: Mondays, 9:00am-10:00am 115 Hutchison Date Speaker Title January 5 Steve Whitham, Professor Department of Plant Pathology, Phakopsora pachyrhizi January 12 Andy Jackson, Professor Emeritus Department of Plant and Microbial Biology

  5. Departments of Plant Pathology, Entomology and

    E-Print Network [OSTI]

    Ishida, Yuko

    Departments of Plant Pathology, Entomology and Nematology Hutchison Hall, Robbins Hall, and Armstrong Field Station Reviewed and Revised: November 2013 #12;UC DAVIS Plant Pathology and Nematology by the University of California, Plant Pathology and Nematology departments in accordance with University Policy

  6. Plant Pathology 290 Graduate Seminar Series

    E-Print Network [OSTI]

    Ishida, Yuko

    Plant Pathology 290 Graduate Seminar Series Spring 2015 Seminars: 9:00am - Mondays 115 Hutchison CRN 47034 Date Speaker Title March 30 Venkatesan Sundaresan, Professor Department of Plant Biology UC of grapevine diseases. May 18 Margaret Lloyd, Ph.D. Candidate Department of Plant Pathology, Gordon Lab UC

  7. Transgenic plants with altered senescence characteristics

    DOE Patents [OSTI]

    Amasino, Richard M. (Madison, WI); Gan, Susheng (Lexington, KY); Noh, Yoo-Sun (Madison, WI)

    2002-03-19

    The identification of senescence-specific promoters from plants is described. Using information from the first senescence-specific promoter, SAG12 from Arabidopsis, other homologous promoters from another plant have been identified. Such promoters may be used to delay senescence in commercially important plants.

  8. Steam Plant Conversion Eliminating Campus Coal Use

    E-Print Network [OSTI]

    Dai, Pengcheng

    Steam Plant Conversion Eliminating Campus Coal Use at the Steam Plant #12;· Flagship campus region produce 14% of US coal (TN only 0.2%) Knoxville and the TN Valley #12;· UT is one of about 70 U.S. colleges and universities w/ steam plant that burns coal · Constructed in 1964, provides steam for

  9. Ownership Change, Incentives and Plant Efficiency: The Divestiture of U.S. Electric Generation Plants

    E-Print Network [OSTI]

    Sadoulet, Elisabeth

    Ownership Change, Incentives and Plant Efficiency: The Divestiture of U.S. Electric Generation generating plants. Between 1998 and 2001, over 300 electric generating plants in the US, accounting Plants James B. Bushnell and Catherine Wolfram March 2005 Abstract Electric industry restructuring

  10. Plant Molecular Biology 43: 621633, 2000. Dirk Inz (Ed.), The Plant Cell Cycle.

    E-Print Network [OSTI]

    Murray, J.A.H.

    Plant Molecular Biology 43: 621­633, 2000. Dirk Inzé (Ed.), The Plant Cell Cycle. © 2000 Kluwer Academic Publishers. Printed in the Netherlands. 621 The role and regulation of D-type cyclins in the plant.murray@biotech.cam.ac.uk) Key words: D-type cyclins, differentiation, G1/S control, plant cell cycle, proliferation

  11. Update on Biochemistry of Plant Volatiles Biochemistry of Plant Volatiles1

    E-Print Network [OSTI]

    Pichersky, Eran

    to be emitted from plants, al- though a comprehensive list is available only for floral volatiles (Knudsen et alUpdate on Biochemistry of Plant Volatiles Biochemistry of Plant Volatiles1 Natalia Dudareva*, Eran, Beutenberg Campus, D­007745 Jena, Germany (J.G.) Plants have a penchant for perfuming the atmo- sphere around

  12. Financing Solar Thermal Power Plants

    SciTech Connect (OSTI)

    Price, H. W.; Kistner, R.

    1999-11-01

    The commercialization of concentrating solar power technology took a major step forward in the mid 1980s and early 1990s with the development of the SEGS plants in California. Over the years they have proven that parabolic trough power technologies are the most cost-effective approach for commercial scale solar power generation in the sunbelt countries of the world. However, the question must be asked why no additional solar power plants have been build following the bankruptcy of the developer of the SEGS projects, LUZ International Limited. Although many believe the SEGS projects were a success as a result of parabolic trough technology they employ, in truth, the SEGS projects were developed simply because they represented an attractive opportunity for investors. Simply stated, no additional projects have been developed because no one has been able to put together a similarly attractive financial package to potential investors. More than $1.2 billion in private capital was raised i n debt and equity financing for the nine SEGS plants. Investors and bankers who make these investments are the real clients for solar power technologies. They are not interested in annual solar to electric efficiencies, but in risk, return on investments, and coverage ratios. This paper will take a look at solar power projects from the financier's perspective. The challenge in moving forward is to attract private investors, commercial lenders, and international development agencies and to find innovative solutions to the difficult issues that investment in the global power market poses for solar power technologies.

  13. Financing solar thermal power plants

    SciTech Connect (OSTI)

    Kistner, R.; Price, H.

    1999-07-01

    The commercialization of concentrating solar power technology took a major step forward in the mid 1980s and early 1990s with the development of the SEGS plants in California. Over the years they have proven that parabolic trough power technologies are the most cost-effective approach for commercial scale solar power generation in the sunbelt countries of the world. However, the question must be asked why no additional solar power plants have been built following the bankruptcy of the developer of the SEGS projects, LUZ International Limited. Although many believe the SEGS projects were a success as a result of parabolic trough technology they employ, in truth, the SEGS projects were developed simply because they represented an attractive opportunity for investors. Simply states, no additional projects have been developed because no one has been able to put together a similarly attractive financial package to potential investors. More than $1.2 billion in private capital was raised in debt and equity financing for the nine SEGS plants. Investors and bankers who make these investments are the real clients for solar power technologies. They are not interested in annual solar to electric efficiencies, but in risk, return on investments, and coverage ratios. This paper will take a look at solar power projects form the financier's perspective. The challenge in moving forward is to attract private investors, commercial lenders, and international development agencies and to find innovative solutions to the difficult issues that investment in the global power market poses for solar power technologies.

  14. Engineered plant biomass feedstock particles

    DOE Patents [OSTI]

    Dooley, James H. (Federal Way, WA); Lanning, David N. (Federal Way, WA); Broderick, Thomas F. (Lake Forest Park, WA)

    2012-04-17

    A new class of plant biomass feedstock particles characterized by consistent piece size and shape uniformity, high skeletal surface area, and good flow properties. The particles of plant biomass material having fibers aligned in a grain are characterized by a length dimension (L) aligned substantially parallel to the grain and defining a substantially uniform distance along the grain, a width dimension (W) normal to L and aligned cross grain, and a height dimension (H) normal to W and L. In particular, the L.times.H dimensions define a pair of substantially parallel side surfaces characterized by substantially intact longitudinally arrayed fibers, the W.times.H dimensions define a pair of substantially parallel end surfaces characterized by crosscut fibers and end checking between fibers, and the L.times.W dimensions define a pair of substantially parallel top and bottom surfaces. The L.times.W surfaces of particles with L/H dimension ratios of 4:1 or less are further elaborated by surface checking between longitudinally arrayed fibers. The length dimension L is preferably aligned within 30.degree. parallel to the grain, and more preferably within 10.degree. parallel to the grain. The plant biomass material is preferably selected from among wood, agricultural crop residues, plantation grasses, hemp, bagasse, and bamboo.

  15. Kansas City Plant Celebrates Safety Milestone

    ScienceCinema (OSTI)

    None

    2010-09-01

    A gang of motorcycle riders arrived at the NNSA's Kansas City Plant on July 1 to help celebrate a significant safety achievement - working nearly five million hours, covering a one-year period without a lost-time injury. The bikers -- some of whom are plant employees -- represent Bikers Against Child Abuse, the local nonprofit selected to receive a $5,000 donation as part of the plant's safety achievement celebration. The organization was selected because it aligns with the plant's community outreach focus on Family Safety & Security and partnership with the plant's union members.

  16. Supercritical plants to come online in 2009

    SciTech Connect (OSTI)

    Spring, N.

    2009-07-15

    A trio of coal-fired power plants using supercritical technology set to enter service this year. These are: We Energies is Elm Road Generating Station in Wisconsin, a two-unit, 1,230 MW supercritical plant that will burn bituminous coal; a 750 MW supercritical coal-fired power plant at the Comanche Generating Station in Pueblo, Colo., the third unit at the site; and Luminant's Oak Grove plant in Texas which will consist of two supercritical, lignite-fueled power generation units. When complete, the plant will deliver about 1,6000 MW. Some details are given on each of these projects. 2 photos.

  17. BWR plant analyzer development at BNL

    SciTech Connect (OSTI)

    Cheng, H.S.; Wulff, W.; Mallen, A.N.; Lekach, S.V.; Stritar, A.; Cerbone, R.J.

    1985-01-01

    Advanced technology for high-speed interactive nuclear power plant simulations is of great value for timely resolution of safety issues, for plant monitoring, and for computer-aided emergency responses to an accident. Presented is the methodology employed at BNL to develop a BWR plant analyzer capable of simulating severe plant transients at much faster than real-time process speeds. Five modeling principles are established and a criterion is given for selecting numerical procedures and efficient computers to achieve the very high simulation speeds. Typical results are shown to demonstrate the modeling fidelity of the BWR plant analyzer.

  18. Methods of saccharification of polysaccharides in plants

    DOE Patents [OSTI]

    Howard, John; Fake, Gina

    2014-04-29

    Saccharification of polysaccharides of plants is provided, where release of fermentable sugars from cellulose is obtained by adding plant tissue composition. Production of glucose is obtained without the need to add additional .beta.-glucosidase. Adding plant tissue composition to a process using a cellulose degrading composition to degrade cellulose results in an increase in the production of fermentable sugars compared to a process in which plant tissue composition is not added. Using plant tissue composition in a process using a cellulose degrading enzyme composition to degrade cellulose results in decrease in the amount of cellulose degrading enzyme composition or exogenously applied cellulase required to produce fermentable sugars.

  19. Proximity and Investment: Evidence from Plant-Level Data

    E-Print Network [OSTI]

    Giroud, Xavier

    Proximity to plants makes it easier for headquarters to monitor and acquire information about plants. In this article, I estimate the effects of headquarters’ proximity to plants on plant-level investment and productivity. ...

  20. Garbage In, Power Out: South Carolina BMW Plant Demonstrates...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The plant BMW plant in Greer, South Carolina is home to the world's largest fleet of fuel cell forklifts. | Photo courtesy of BMW Manufacturing. The plant BMW plant in Greer,...

  1. Small Power Plant Exemption (06-SPPE-1) Imperial County

    E-Print Network [OSTI]

    Small Power Plant Exemption (06-SPPE-1) Imperial County NILAND GAS TURBINE PLANT PRESIDINGMEMBER (06-SPPE-1) Imperial County NILAND GAS TURBINE PLANT PRESIDINGMEMBER Exemption (SPPE). The Energy Commission Committee assigned to the Niland Gas Turbine Plant Project

  2. Genomic Aspects of Research Involving Polyploid Plants

    SciTech Connect (OSTI)

    Yang, Xiaohan [ORNL; Ye, Chuyu [ORNL; Tschaplinski, Timothy J [ORNL; Wullschleger, Stan D [ORNL; Tuskan, Gerald A [ORNL

    2011-01-01

    Almost all extant plant species have spontaneously doubled their genomes at least once in their evolutionary histories, resulting in polyploidy which provided a rich genomic resource for evolutionary processes. Moreover, superior polyploid clones have been created during the process of crop domestication. Polyploid plants generated by evolutionary processes and/or crop domestication have been the intentional or serendipitous focus of research dealing with the dynamics and consequences of genome evolution. One of the new trends in genomics research is to create synthetic polyploid plants which provide materials for studying the initial genomic changes/responses immediately after polyploid formation. Polyploid plants are also used in functional genomics research to study gene expression in a complex genomic background. In this review, we summarize the recent progress in genomics research involving ancient, young, and synthetic polyploid plants, with a focus on genome size evolution, genomics diversity, genomic rearrangement, genetic and epigenetic changes in duplicated genes, gene discovery, and comparative genomics. Implications on plant sciences including evolution, functional genomics, and plant breeding are presented. It is anticipated that polyploids will be a regular subject of genomics research in the foreseeable future as the rapid advances in DNA sequencing technology create unprecedented opportunities for discovering and monitoring genomic and transcriptomic changes in polyploid plants. The fast accumulation of knowledge on polyploid formation, maintenance, and divergence at whole-genome and subgenome levels will not only help plant biologists understand how plants have evolved and diversified, but also assist plant breeders in designing new strategies for crop improvement.

  3. 13-03-09 9:30 PMCold War Social Science and the Rubric of the "Cold War" | Ether Wave Propaganda Page 1 of 6http://etherwave.wordpress.com/2012/09/06/cold-war-social-science-and-the-rubric-of-the-cold-war/

    E-Print Network [OSTI]

    Solovey, Mark

    13-03-09 9:30 PMCold War Social Science and the Rubric of the "Cold War" | Ether Wave Propaganda Page 1 of 6http://etherwave.wordpress.com/2012/09/06/cold-war-social-science-and-the-rubric-of-the-cold-war/ Cold War Social Science and the Rubric of the "Cold War" September 6, 2012 Posted by Will Thomas in EWP

  4. SENSIBLE HEAT STORAGE FOR A SOLAR THERMAL POWER PLANT

    E-Print Network [OSTI]

    Baldwin, Thomas F.

    2011-01-01

    Solar Power Plant . . Important Sources of Cost Estimation Datasolar power plant. These data were used to estimate costs

  5. A Continuous Solar Thermochemical Hydrogen Production Plant Design

    E-Print Network [OSTI]

    Luc, Wesley Wai

    thermochemical plant. Solar thermal energy is harnessed bya solar thermal plant built by the Department of Energy in

  6. How to Collect, Press, Mount and Store Plants 

    E-Print Network [OSTI]

    Ragsdale, Bobby

    2002-02-02

    Creating a plant collection is easy with these simple instructions. Photographs illustrate the steps involved in pressing plants successfully.

  7. Biomass IBR Fact Sheet: Archer Daniels Midland

    Broader source: Energy.gov [DOE]

    Archer Daniels Midland will develop a pilot plant to demonstrate the continuous production of cellulosic ethanol and butyl acrylate from densified corn stover.

  8. Small Power Plant Exemption (06-SPPE-1) Imperial County

    E-Print Network [OSTI]

    Small Power Plant Exemption (06-SPPE-1) Imperial County NILAND GAS TURBINE PLANT COMMISSIONDECISION ENERGY COMMISSION Small Power Plant Exemption (06-SPPE-1) Imperial County NILAND GAS TURBINE PLANT GAS TURBINE PLANT SMALL POWER PLANT EXEMPTION DOCKET NO. 06-SPPE-1 The California Energy Commission

  9. Texas Plants Poisonous to Livestock. 

    E-Print Network [OSTI]

    Sperry, Omer Edison

    1964-01-01

    as wide and have somewhat thickened margins. DISTRIBUTION. Guajillo grows in great density in Texas, especially in the southern part of the Edwards Plateau and in the central and northern parts of the South Texas Plains. It extends from Terrell County... on the north to Webb County on the south and east- ward into Bee County. Scattered plants and small patches of guajillo are found in areas adjacent to the South Texas Plains and the Edwards Plateau and in the Trans-Pecos, especially in the Chisos Mountains...

  10. Better Plants | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data Center HomeVehicle ReplacementStatesA Case Study fromWorkingBetterPlants

  11. UC Davis Policies and Practices for Work with Transgenic Plants and Plant Pathogens 1 | P a g e

    E-Print Network [OSTI]

    Ishida, Yuko

    UC Davis Policies and Practices for Work with Transgenic Plants and Plant Pathogens 1 | P a g e rev. 9110 Work with recombinant DNA organisms (transgenic plants, animal and microbes) and plant contamination or soiling of street clothes and dissemination of plant material or plant pathogens outside

  12. Sabotage at Nuclear Power Plants

    SciTech Connect (OSTI)

    Purvis, James W.

    1999-07-21

    Recently there has been a noted worldwide increase in violent actions including attempted sabotage at nuclear power plants. Several organizations, such as the International Atomic Energy Agency and the US Nuclear Regulatory Commission, have guidelines, recommendations, and formal threat- and risk-assessment processes for the protection of nuclear assets. Other examples are the former Defense Special Weapons Agency, which used a risk-assessment model to evaluate force-protection security requirements for terrorist incidents at DOD military bases. The US DOE uses a graded approach to protect its assets based on risk and vulnerability assessments. The Federal Aviation Administration and Federal Bureau of Investigation conduct joint threat and vulnerability assessments on high-risk US airports. Several private companies under contract to government agencies use formal risk-assessment models and methods to identify security requirements. The purpose of this paper is to survey these methods and present an overview of all potential types of sabotage at nuclear power plants. The paper discusses emerging threats and current methods of choice for sabotage--especially vehicle bombs and chemical attacks. Potential consequences of sabotage acts, including economic and political; not just those that may result in unacceptable radiological exposure to the public, are also discussed. Applicability of risk-assessment methods and mitigation techniques are also presented.

  13. Using Soluble Calcium to Stimulate Plant Growth 

    E-Print Network [OSTI]

    Feagley, Sam E.; Fenn, Lloyd B.

    1998-09-09

    the season (Fig. 3). Perhaps the most beneficial effect of applying calci- um with ammonium is that plants change their normal pattern of depositing energy stores (carbohydrates, metabolites) (Figs. 4, 5). As Figure 4 shows, rice plants had... of the flag leaf?s energy production being transported to the filling seeds (as opposed to 5 percent without calcium). Rice weights increased 14 percent when extra calcium was applied at seed fill. L-5212 9-98 Using Soluble Calcium to Stimulate Plant...

  14. RNA silencing in plants: Flash report!

    E-Print Network [OSTI]

    Mosher, Rebecca A; Lewsey, Mathew G; Shivaprasad, Padubidri V

    2010-06-30

    different nutrient conditions. Several Department of Plant Sciences, University of Cambridge, Cambridge, CB2 3EA, UK Full list of author information is available at the end of the article Mosher et al. Silence 2010, 1:13 http... Department of Plant Sciences, University of Cambridge, Cambridge, CB2 3EA, UK and 2Plant Biology Laboratory, The Salk Institute for Biological Studies, La Jolla, CA 92037, USA References 1. Fire A, Xu S, Montgomery MK, Kostas SA, Driver SE, Mello CC: Potent...

  15. Plant nitrogen regulatory P-PII genes

    DOE Patents [OSTI]

    Coruzzi, Gloria M. (New York, NY); Lam, Hon-Ming (Hong Kong, HK); Hsieh, Ming-Hsiun (Woodside, NY)

    2001-01-01

    The present invention generally relates to plant nitrogen regulatory PII gene (hereinafter P-PII gene), a gene involved in regulating plant nitrogen metabolism. The invention provides P-PII nucleotide sequences, expression constructs comprising said nucleotide sequences, and host cells and plants having said constructs and, optionally expressing the P-PII gene from said constructs. The invention also provides substantially pure P-PII proteins. The P-PII nucleotide sequences and constructs of the

  16. Waste Isolation Pilot Plant Transportation Security | Department...

    Office of Environmental Management (EM)

    Accident Investigation of the February 5, 2014, Underground Salt Haul Truck Fire at the Waste Isolation Pilot Plant, Carlsbad NM Accident Investigation Report - Fire...

  17. Pascagoula Plant comes on-line

    SciTech Connect (OSTI)

    Neilsen, R.A.; Petty, L.; Chen, R.; Elliot, D.

    1999-07-01

    The Pascagoula Gas Processing Plant was designed with the following goals: assure the residue gas meets pipeline specification at all times; provide value enhancement through NGL recovery; achieve low life cycle cost; and be a safe and environmentally responsible member of the community. These project goals were achieved through a creative design allowing the plant unique flexibility and reliability. The plant is capable of operating in five operating modes: ethane recovery, ethane rejection, dew point control, single compressor operation and 12 Rvp. These operating modes allow the plant to operate in a wide range of economic environments and a variety of operational upsets including NGL pipeline outage.

  18. Fuel Cell Power Plant Experience Naval Applications

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    reliable, efficient, ultra-clean Fuel Cell Power Plant Experience Naval Applications US Department of Energy Office of Naval Research Shipboard Fuel Cell Workshop Washington, DC...

  19. Portsmouth Gaseous Diffusion Plant Director's Final Findings...

    Office of Environmental Management (EM)

    Portsmouth Gaseous Diffusion Plant Director's Final Findings and Orders, October 4, 1995 State Ohio Agreement Type Federal Facility Agreement Legal Driver(s) FFCAct Scope Summary...

  20. Wisconsin Nuclear Profile - Point Beach Nuclear Plant

    U.S. Energy Information Administration (EIA) Indexed Site

    Point Beach Nuclear Plant" "Unit","Summer capacity (mw)","Net generation (thousand mwh)","Summer capacity factor (percent)","Type","Commercial operation date","License expiration...

  1. Tennessee Nuclear Profile - Watts Bar Nuclear Plant

    U.S. Energy Information Administration (EIA) Indexed Site

    Watts Bar Nuclear Plant" "Unit","Summer capacity (mw)","Net generation (thousand mwh)","Summer capacity factor (percent)","Type","Commercial operation date","License expiration...

  2. Waste Treatment and Immobilation Plant Pretreatment Facility

    Office of Environmental Management (EM)

    7 Technology Readiness Assessment for the Waste Treatment and Immobilization Plant (WTP) Pretreatment Facility L. Holton D. Alexander M. Johnson H. Sutter August 2007 Prepared by...

  3. Tracking New Coal-Fired Power Plants

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    January 8, 2010 National Energy Technology Laboratory Office of Systems Analyses and Planning Erik Shuster 2 Tracking New Coal-Fired Power Plants This report is intended to...

  4. Healthcare Energy: Spotlight on Chiller Plants

    Broader source: Energy.gov [DOE]

    The Building Technologies Office conducted a healthcare energy end-use monitoring project for two sites. Read details about the chiller plant energy results.

  5. Independent Oversight Review, Portsmouth Gaseous Diffusion Plant...

    Office of Environmental Management (EM)

    April 2013 Independent Oversight Review, Portsmouth Gaseous Diffusion Plant - April 2013 April 2013 Review of the Integrated Safety Management System Phase I Verification Review at...

  6. Independent Activity Report, Hanford Plutonium Finishing Plant...

    Broader source: Energy.gov (indexed) [DOE]

    May 2012 Criticality Safety Information Meeting for the Hanford Plutonium Finishing Plant HIAR-RL-2012-05-14 This Independent Activity Report documents an oversight activity...

  7. ,"Natural Gas Plant Liquids Proved Reserves"

    U.S. Energy Information Administration (EIA) Indexed Site

    ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Natural Gas Plant Liquids Proved Reserves",49,"Annual",2013,"06301979" ,"Release...

  8. ,"Texas Natural Gas Plant Fuel Consumption (MMcf)"

    U.S. Energy Information Administration (EIA) Indexed Site

    ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Texas Natural Gas Plant Fuel Consumption (MMcf)",1,"Annual",2014 ,"Release Date:","930...

  9. ENVIRONMENTAL SCIENCES; SAVANNAH RIVER PLANT; ENVIRONMENTAL EFFECTS...

    Office of Scientific and Technical Information (OSTI)

    5 audit of SRP radioactive waste Ashley, C. 05 NUCLEAR FUELS; 54 ENVIRONMENTAL SCIENCES; SAVANNAH RIVER PLANT; ENVIRONMENTAL EFFECTS; RADIOACTIVE EFFLUENTS; EMISSION; HIGH-LEVEL...

  10. Independent Oversight Inspection, Pantex Plant, Summary Report...

    Office of Environmental Management (EM)

    Summary Report - November 2002 November 2002 Inspection of Environment, Safety, and Health and Emergency Management at the Pantex Plant This report provides the more detailed...

  11. Use of NAP gene to manipulate leaf senescence in plants

    DOE Patents [OSTI]

    Gan, Susheng; Guo, Yongfeng

    2013-04-16

    The present invention discloses transgenic plants having an altered level of NAP protein compared to that of a non-transgenic plant, where the transgenic plants display an altered leaf senescence phenotype relative to a non-transgenic plant, as well as mutant plants comprising an inactivated NAP gene, where mutant plants display a delayed leaf senescence phenotype compared to that of a non-mutant plant. The present invention also discloses methods for delaying leaf senescence in a plant, as well as methods of making a mutant plant having a decreased level of NAP protein compared to that of a non-mutant plant, where the mutant plant displays a delayed leaf senescence phenotype relative to a non-mutant plant. Methods for causing precocious leaf senescence or promoting leaf senescence in a plant are also disclosed. Also disclosed are methods of identifying a candidate plant suitable for breeding that displays a delayed leaf senescence and/or enhanced yield phenotype.

  12. Optimization and operation of a cementation plant in the Atucha I Nuclear Power Plant

    SciTech Connect (OSTI)

    Schifferdecker, H. [Kraftanlagen Energie- und Industrieanlagen Heidelberg (Germany)

    1995-12-31

    The quality of conditioned radioactive waste must constantly be improved to keep pace with technical progress. To meet these ever-increasing demands it is necessary to modernize existing plants for the treatment of radioactive waste. The Atucha I NPP has been in operation since 1974 and the cementation plant no longer conformed with today`s requirements regarding safe operation and product quality. The optimization of the plant mainly involved the execution of the following points: Dismantling of existing plant sections to enable the installation of new and supplementary components; Installation of new and supplementary plant sections (components); Integration of the new system into the existing plant; and Commissioning of the new plant and operation of the plant using the optimized process for the duration of 60 calendar days. 200 barrels were to be cemented during this period.

  13. Nuclear power plant performance assessment pertaining to plant aging in France and the United States

    E-Print Network [OSTI]

    Guyer, Brittany (Brittany Leigh)

    2013-01-01

    The effect of aging on nuclear power plant performance has come under increased scrutiny in recent years. The approaches used to make an assessment of this effect strongly influence the economics of nuclear power plant ...

  14. Efficiency combined cycle power plant

    SciTech Connect (OSTI)

    Pavel, J.; Meyers, G.A.; Baldwin, T.S.

    1990-06-12

    This patent describes a method of operating a combined cycle power plant. It comprises: flowing exhaust gas from a combustion turbine through a heat recovery steam generator (HRSG); flowing feed water through an economizer section of the HRSG at a flow rate and providing heated feed water; flowing a first portion of the heated feed water through an evaporator section of the HRSG and producing saturated steam at a production rate, the flow rate of the feed water through the economizer section being greater than required to sustain the production rate of steam in the evaporator section; flowing fuel for the turbine through a heat exchanger; and, flowing a second portion of the heated feed water provided by the economizer section through the heat exchanger then to an inlet of the economizer section, thereby heating the fuel flowing through the heat exchanger.

  15. Preliminary design of the Carrisa Plains solar central receiver power plant. Volume II. Plant specifications

    SciTech Connect (OSTI)

    Price, R. E.

    1983-12-31

    The specifications and design criteria for all plant systems and subsystems used in developing the preliminary design of Carrisa Plains 30-MWe Solar Plant are contained in this volume. The specifications have been organized according to plant systems and levels. The levels are arranged in tiers. Starting at the top tier and proceeding down, the specification levels are the plant, system, subsystem, components, and fabrication. A tab number, listed in the index, has been assigned each document to facilitate document location.

  16. Light and Plants Plants use light to photosynthesize. Name two places that light can come from

    E-Print Network [OSTI]

    Koptur, Suzanne

    Light and Plants Plants use light to photosynthesize. Name two places that light can come from: 1 (CO2, a gas) from the air and turn it into SUGARS (food). This process is powered by energy from light plants) for energy. Photosynthetically Active Radiation (PAR) is a combination of red light and blue

  17. Postdoctoral position -UC Davis -plant-vector interactions, plant-microbe interactions, molecular biology, ecology

    E-Print Network [OSTI]

    Ishida, Yuko

    Postdoctoral position - UC Davis - plant-vector interactions, plant-microbe interactions, molecular August 2014. The primary research goal of the Casteel lab is to identify the functions of microbes- microbe or plant-insect interactions will be preferred. Candidates with a proven record of excellence

  18. HARNESSING PLANT BIOMASS FOR BIOFUELS AND BIOMATERIALS Plant surface lipid biosynthetic pathways and their utility for

    E-Print Network [OSTI]

    Kunst, Ljerka

    HARNESSING PLANT BIOMASS FOR BIOFUELS AND BIOMATERIALS Plant surface lipid biosynthetic pathways and their utility for metabolic engineering of waxes and hydrocarbon biofuels Reinhard Jetter1,2,* and Ljerka Kunst1 biosynthetic pathways can be used in metabolic engineering of plants for the production of hydrocarbon biofuels

  19. Phylogenetic Exploration of Medicinal Plant Diversity MedPlant PhD Fellowship

    E-Print Network [OSTI]

    Zürich, Universität

    MedPlant Phylogenetic Exploration of Medicinal Plant Diversity MedPlant PhD Fellowship Incense, is offering a 3-year PhD scholarship commencing spring 2014. The application deadline is November 15, 2013. The Institute of Systematic Botany, University of Zürich announces an opening for a fully funded PhD fellowship

  20. Financial Policy Manual 1106.4 PLANT ASSETS PLANT CONSTRUCTION COSTS

    E-Print Network [OSTI]

    George, Edward I.

    Financial Policy Manual Page 1 1106.4 PLANT ASSETS ­ PLANT CONSTRUCTION COSTS Effective: December PURPOSE To properly account for the costs of construction of University plant. POLICY 1. The Office of the Comptroller is responsible for accounting for all costs of construction (new building construction, building

  1. Eastman, AP start on coal unit

    SciTech Connect (OSTI)

    1995-10-25

    Eastman Chemical and Air Products and Chemicals (AP) have started construction of a $214-million, coal-to-methanol demonstration unit at Eastmans site in Kingsport, TN. The project is part of the Department of Energy`s clean coal technology program and is receiving $93 million in federal support. The demonstration unit-which will have a methanol capacity of 260 tons/day-will use novel catalyst technology for converting coal-derived synthesis gas (syngas) to methanol. Unlike conventional technology that processes syngas through a fixed bed of dry catalyst particles, the liquid-phase methanol process converts the syngas in a single vessel containing catalysts suspended in mineral oil. The companies say the innovation allows the process to better able handle the gases from coal gasifiers and is more stable and reliable than existing processes. Eastman says it will use the methanol produced by the plant as a chemical feedstock. It currently uses methanol as an intermediate in making acetic anhydride and dimethyl terephthalate. In addition, the companies say the methanol will be evaluated as a feedstock in making methyl tert-butyl ether for reformulated fuels. Eastman also says it will evaluate coproducing dimethyl ether (DME) with the methanol. DME can be used as a fuel additive or blended with methanol for a chemical feedstock, according to Eastman.

  2. GASIFICATION PLANT COST AND PERFORMANCE OPTIMIZATION

    SciTech Connect (OSTI)

    Samuel S. Tam

    2002-05-01

    The goal of this series of design and estimating efforts was to start from the as-built design and actual operating data from the DOE sponsored Wabash River Coal Gasification Repowering Project and to develop optimized designs for several coal and petroleum coke IGCC power and coproduction projects. First, the team developed a design for a grass-roots plant equivalent to the Wabash River Coal Gasification Repowering Project to provide a starting point and a detailed mid-year 2000 cost estimate based on the actual as-built plant design and subsequent modifications (Subtask 1.1). This unoptimized plant has a thermal efficiency of 38.3% (HHV) and a mid-year 2000 EPC cost of 1,681 $/kW. This design was enlarged and modified to become a Petroleum Coke IGCC Coproduction Plant (Subtask 1.2) that produces hydrogen, industrial grade steam, and fuel gas for an adjacent Gulf Coast petroleum refinery in addition to export power. A structured Value Improving Practices (VIP) approach was applied to reduce costs and improve performance. The base case (Subtask 1.3) Optimized Petroleum Coke IGCC Coproduction Plant increased the power output by 16% and reduced the plant cost by 23%. The study looked at several options for gasifier sparing to enhance availability. Subtask 1.9 produced a detailed report on this availability analyses study. The Subtask 1.3 Next Plant, which retains the preferred spare gasification train approach, only reduced the cost by about 21%, but it has the highest availability (94.6%) and produces power at 30 $/MW-hr (at a 12% ROI). Thus, such a coke-fueled IGCC coproduction plant could fill a near term niche market. In all cases, the emissions performance of these plants is superior to the Wabash River project. Subtasks 1.5A and B developed designs for single-train coal and coke-fueled power plants. This side-by-side comparison of these plants, which contain the Subtask 1.3 VIP enhancements, showed their similarity both in design and cost (1,318 $/kW for the coal plant and 1,260 $/kW for the coke plant). Therefore, in the near term, a coke IGCC power plant could penetrate the market and provide a foundation for future coal-fueled facilities. Subtask 1.6 generated a design, cost estimate and economics for a multiple train coal-fueled IGCC powerplant, also based on the Subtaks 1.3 cases. The Subtask 1.6 four gasification train plant has a thermal efficiency of 40.6% (HHV) and cost 1,066 $/kW. The single-train advanced Subtask 1.4 plant, which uses an advanced ''G/H-class'' combustion turbine, can have a thermal efficiency of 45.4% (HHV) and a plant cost of 1,096 $/kW. Multi-train plants will further reduce the cost. Again, all these plants have superior emissions performance. Subtask 1.7 developed an optimized design for a coal to hydrogen plant. At current natural gas prices, this facility is not competitive with hydrogen produced from natural gas. The preferred scenario is to coproduce hydrogen in a plant similar to Subtask 1.3, as described above. Subtask 1.8 evaluated the potential merits of warm gas cleanup technology. This study showed that selective catalytic oxidation of hydrogen sulfide (SCOHS) is promising. As gasification technology matures, SCOHS and other improvements identified in this study will lead to further cost reductions and efficiency improvements.

  3. Rangeland Risk Management for Texans: Toxic Plants 

    E-Print Network [OSTI]

    Hart, Charles R.

    2000-11-01

    Toxic plants can cause serious losses to livestock, but with the information in this leaflet producers will know how to manage grazing to minimize the danger of toxic plants. It is important to recognize problems early and know how to deal with them....

  4. Method for regulation of plant lignin composition

    DOE Patents [OSTI]

    Chapple, Clint (West Lafayette, IN)

    1999-01-01

    A method is disclosed for the regulation of lignin composition in plant tissue. Plants are transformed with a gene encoding an active F5H gene. The expression of the F5H gene results in increased levels of syringyl monomer providing a lignin composition more easily degraded with chemicals and enzymes.

  5. Ninth International Workshop on Plant Membrane Biology

    SciTech Connect (OSTI)

    Not Available

    1993-12-31

    This report is a compilation of abstracts from papers which were discussed at a workshop on plant membrane biology. Topics include: plasma membrane ATP-ases; plant-environment interactions, membrane receptors; signal transduction; ion channel physiology; biophysics and molecular biology; vaculor H+ pumps; sugar carriers; membrane transport; and cellular structure and function.

  6. A Survey of Power Plant Designs

    E-Print Network [OSTI]

    Ervin, Elizabeth K.

    to produce steam. The steam spins the turbine, which drives the generator. Source: Tennessee Valley Authority) www.ent.ohiou.edu/~thermo/ index.html The General James M Gavin Steam Power Plant near Cheshire, Ohio University #12;Combustion Turbine Power Plant Open System The turbine burns either natural gas or oil. Fuel

  7. Metal resistance sequences and transgenic plants

    DOE Patents [OSTI]

    Meagher, Richard Brian (Athens, GA); Summers, Anne O. (Athens, GA); Rugh, Clayton L. (Athens, GA)

    1999-10-12

    The present invention provides nucleic acid sequences encoding a metal ion resistance protein, which are expressible in plant cells. The metal resistance protein provides for the enzymatic reduction of metal ions including but not limited to divalent Cu, divalent mercury, trivalent gold, divalent cadmium, lead ions and monovalent silver ions. Transgenic plants which express these coding sequences exhibit increased resistance to metal ions in the environment as compared with plants which have not been so genetically modified. Transgenic plants with improved resistance to organometals including alkylmercury compounds, among others, are provided by the further inclusion of plant-expressible organometal lyase coding sequences, as specifically exemplified by the plant-expressible merB coding sequence. Furthermore, these transgenic plants which have been genetically modified to express the metal resistance coding sequences of the present invention can participate in the bioremediation of metal contamination via the enzymatic reduction of metal ions. Transgenic plants resistant to organometals can further mediate remediation of organic metal compounds, for example, alkylmetal compounds including but not limited to methyl mercury, methyl lead compounds, methyl cadmium and methyl arsenic compounds, in the environment by causing the freeing of mercuric or other metal ions and the reduction of the ionic mercury or other metal ions to the less toxic elemental mercury or other metals.

  8. Southern California Trial Plantings of Eucalyptus1

    E-Print Network [OSTI]

    Southern California Trial Plantings of Eucalyptus1 Paul W. Moore2 Following the Arab oil embargo po tential for rapid production of biomass was Eucalyptus. Three species had shown wide adaptation to California soils and microclimates. Eucalyptus globulus was widely planted as windbreaks

  9. Montana State University 1 Plant Science

    E-Print Network [OSTI]

    Maxwell, Bruce D.

    and also fits into either the Crop Science or Plant Biology options. Crop Science Option Continued. Course requirements in the Crop Science option are designed to acquaint students with the principles. Undergraduate Programs · Crop Science Option (http://catalog.montana.edu/undergraduate/ agriculture/plant-science/crop-science

  10. Lessons learned from existing biomass power plants

    SciTech Connect (OSTI)

    Wiltsee, G.

    2000-02-24

    This report includes summary information on 20 biomass power plants, which represent some of the leaders in the industry. In each category an effort is made to identify plants that illustrate particular points. The project experiences described capture some important lessons learned that lead in the direction of an improved biomass power industry.

  11. Ethylene plant commissioned at Corpus Christi

    SciTech Connect (OSTI)

    Not Available

    1984-01-01

    Ethylene Plant Commissioned at Corpus Christi. Corpus Christi Petrochemical Co. has commissioned its $600 million ethylene plant at Corpus Christi, Tex. Plant capacities include 1.2 billion lb/yr of ethylene, 560 million lb/yr of propylene, 400 million lb/yr of crude butadiene mixture, 60 million gal of benzene, 45 million gal of gasoline blending components, and 50 million gal of fuel oils. The ethylene and propylene will be transported by pipeline to Houston for further processing. At the Corpus Christi facilities, process pressures range from full vacuum to 1800 psig, and process temperatures range from -260/sup 0/ to +1600/sup 0/F. The plant uses gas oil and naphtha as feedstock, but also has some flexibility to use ethane or LPG as feedstock. Stone and Webster Engineering Corp. engineered and Brown and Root Inc. built the plant.

  12. Monitoring Biological Activity at Geothermal Power Plants

    SciTech Connect (OSTI)

    Peter Pryfogle

    2005-09-01

    The economic impact of microbial growth in geothermal power plants has been estimated to be as high as $500,000 annually for a 100 MWe plant. Many methods are available to monitor biological activity at these facilities; however, very few plants have any on-line monitoring program in place. Metal coupon, selective culturing (MPN), total organic carbon (TOC), adenosine triphosphate (ATP), respirometry, phospholipid fatty acid (PLFA), and denaturing gradient gel electrophoresis (DGGE) characterizations have been conducted using water samples collected from geothermal plants located in California and Utah. In addition, the on-line performance of a commercial electrochemical monitor, the BIoGEORGE?, has been evaluated during extended deployments at geothermal facilities. This report provides a review of these techniques, presents data on their application from laboratory and field studies, and discusses their value in characterizing and monitoring biological activities at geothermal power plants.

  13. Strategies in tower solar power plant optimization

    E-Print Network [OSTI]

    Ramos, A

    2012-01-01

    A method for optimizing a central receiver solar thermal electric power plant is studied. We parametrize the plant design as a function of eleven design variables and reduce the problem of finding optimal designs to the numerical problem of finding the minimum of a function of several variables. This minimization problem is attacked with different algorithms both local and global in nature. We find that all algorithms find the same minimum of the objective function. The performance of each of the algorithms and the resulting designs are studied for two typical cases. We describe a method to evaluate the impact of design variables in the plant performance. This method will tell us what variables are key to the optimal plant design and which ones are less important. This information can be used to further improve the plant design and to accelerate the optimization procedure.

  14. Coevolution Produces an Arms Race Among Virtual Plants

    E-Print Network [OSTI]

    Ebner, Marc

    Coevolution Produces an Arms Race Among Virtual Plants Marc Ebner, Adrian Grigore, Alexander He#11 create plants for a virtual environment. The plants are represented as context-free Lin- denmayer systems. OpenGL is used to visualize and evaluate the plants. Our plants have to collect virtual sunlight

  15. BIOL/ESRM 331, Spring 2015 Landscape Plant Recognition

    E-Print Network [OSTI]

    Brown, Sally

    parts of flowers in the field, but are not required. Written Materials A daily plant list and plant descriptions will be posted to the website. They will provide you with a list of the plants to be learned each. There are also photos of the plants available on the website. The daily plant list and descriptions

  16. Process Design and Economics for the Conversion of Lignocellulosic Biomass to Hydrocarbons via Indirect Liquefaction. Thermochemical Research Pathway to High-Octane Gasoline Blendstock Through Methanol/Dimethyl Ether Intermediates

    SciTech Connect (OSTI)

    Tan, Eric C. D.; Talmadge, Michael; Dutta, Abhijit; Hensley, Jesse; Schaidle, Josh; Biddy, Mary; Humbird, David; Snowden-Swan, Lesley J.; Ross, Jeff; Sexton, Danielle; Yap, Raymond; Lukas, John

    2015-03-01

    This report was developed as part of the U.S. Department of Energy’s Bioenergy Technologies Office’s (BETO’s) efforts to enable the development of technologies for the production of infrastructure-compatible, cost-competitive liquid hydrocarbon fuels from lignocellulosic biomass feedstocks. The research funded by BETO is designed to advance the state of technology of biomass feedstock supply and logistics, conversion, and overall system sustainability. It is expected that these research improvements will be made within the 2022 timeframe. As part of their involvement in this research and development effort, the National Renewable Energy Laboratory and the Pacific Northwest National Laboratory investigate the economics of conversion pathways through the development of conceptual biorefinery process models and techno-economic analysis models. This report describes in detail one potential conversion process for the production of high-octane gasoline blendstock via indirect liquefaction of biomass. The processing steps of this pathway include the conversion of biomass to synthesis gas or syngas via indirect gasification, gas cleanup, catalytic conversion of syngas to methanol intermediate, methanol dehydration to dimethyl ether (DME), and catalytic conversion of DME to high-octane, gasoline-range hydrocarbon blendstock product. The conversion process configuration leverages technologies previously advanced by research funded by BETO and demonstrated in 2012 with the production of mixed alcohols from biomass. Biomass-derived syngas cleanup via reforming of tars and other hydrocarbons is one of the key technology advancements realized as part of this prior research and 2012 demonstrations. The process described in this report evaluates a new technology area for the downstream utilization of clean biomass-derived syngas for the production of high-octane hydrocarbon products through methanol and DME intermediates. In this process, methanol undergoes dehydration to DME, which is subsequently converted via homologation reactions to high-octane, gasoline-range hydrocarbon products.

  17. Simultaneous optimization and heat integration for the co-production of diesel substitutes

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    consumption of the resulting process. The production of glycerol ethers increases the yield of diesel1 Simultaneous optimization and heat integration for the co-production of diesel substitutes the integration of the etherification of glycerol for the production of tert butyl glycerol with the production

  18. Impact of Renewable Fuels Standard/MTBE Provisions of S. 1766

    Reports and Publications (EIA)

    2002-01-01

    This service report addresses the Renewable Fuels Standard (RFS)/methyl tertiary butyl ether (MTBE) provisions of S. 1766. The 'S. 1766' Case reflects provisions of S. 1766 including a renewable fuels standard (RFS) reaching five billion gallons by 2012, a complete phase-out of MTBE within four years, and the option for states to waive the oxygen requirement for reformulated gasoline (RFG).

  19. Status and Impacts of State MTBE Bans

    Reports and Publications (EIA)

    2003-01-01

    This paper describes legislation passed in 16 states banning or restricting the use of methyl tertiary butyl ether (MTBE) in gasoline. Analysis of the status and impact of these state MTBE bans is provided concerning the supply and potential price changes of gasoline.

  20. Appendix: Bibliography of Technical Reports of the National Cancer Institute/ National Toxicology Program

    E-Print Network [OSTI]

    Gold, Lois Swirsky

    95 108 1978 1,3-Butadiene 288 1984 1,3-Butadiene 434 1993 2-Butoxyethanol 484 2000 tert-Butyl alcohol(bromomethyl)-1,3-propanediol 452 1996 Bis(2-chloro-1-methylethyl) ether 191 1979 #12;--2-- Bis(2-chloro-1

  1. Enhanced anaerobic biodegradation of BTEX-ethanol mixtures in aquifer columns amended with sulfate, chelated ferric iron or nitrate

    E-Print Network [OSTI]

    Alvarez, Pedro J.

    -mail: alvarez@rice.edu) Key words: anaerobic biostimulation, bioremediation, BTEX, ethanol, natural attenuation and ground water contamination by methyl tert-butyl ether (MTBE) have made policy makers more cognizant approaches. BTEX bioremediation efforts often rely on the addition of oxygen and nutrients to stimulate

  2. Role of Volatilization in Changing TBA and MTBE Concentrations at

    E-Print Network [OSTI]

    a low affinity for gasoline (low Kfw, Table 1). Therefore, minute amounts of TBA in the MTBE blended tertiary butyl ether (MTBE) added to gasoline. Frequent observations of high TBA, and especially rising TBA/MTBE concentration ratios, in groundwater at gasoline spill sites are generally attributed to microbial conversion

  3. BF3-Mediated Addition of Lithium Phenylacetylide to an Imine: Correlations of Structures and Reactivities. BF3,R3N Derivatives as

    E-Print Network [OSTI]

    Collum, David B.

    BF3-Mediated Addition of Lithium Phenylacetylide to an Imine: Correlations of Structures of lithium phenylacetylide (PhCCLi) to the N-(n-butyl)imine of cyclohexane carboxaldehyde were investigated of acetals,16 epoxides,17-22 and unstrained cyclic ethers.23,24 BF3 has been used in conjunction

  4. Biotreatment of groundwater contaminated with MTBE: interaction of common environmental co-contaminants

    E-Print Network [OSTI]

    Biotreatment of groundwater contaminated with MTBE: interaction of common environmental co of groundwater with the gasoline additive methyl tert-butyl ether (MTBE) is often accompanied by many aromatic, a laboratory-scale biotrickling filter for groundwater treatment inoculated with a microbial consortium

  5. Motor Gasoline Outlook and State MTBE Bans

    Reports and Publications (EIA)

    2003-01-01

    The U.S. is beginning the summer 2003 driving season with lower gasoline inventories and higher prices than last year. Recovery from this tight gasoline market could be made more difficult by impending state bans on the blending of methyl tertiary butyl ether (MTBE) into gasoline that are scheduled to begin later this year.

  6. Eliminating MTBE in Gasoline in 2006

    Reports and Publications (EIA)

    2006-01-01

    A review of the market implications resulting from the rapid change from methyl tertiary butyl ether (MTBE) to ethanol-blended reformulated gasoline (RFG) on the East Coast and in Texas. Strains in ethanol supply and distribution will increase the potential for price volatility in these regions this summer.

  7. Los Alamos Nuclear Plant Analyzer: an interactive power-plant simulation program

    SciTech Connect (OSTI)

    Steinke, R.; Booker, C.; Giguere, P.; Liles, D.R.; Mahaffy, J.H.; Turner, M.R.

    1984-01-01

    The Nuclear Plant Analyzer (NPA) is a computer-software interface for executing the TRAC or RELAP5 power-plant systems codes. The NPA is designed to use advanced supercomputers, long-distance data communications, and a remote workstation terminal with interactive computer graphics to analyze power-plant thermal-hydraulic behavior. The NPA interface simplifies the running of these codes through automated procedures and dialog interaction. User understanding of simulated-plant behavior is enhanced through graphics displays of calculational results. These results are displayed concurrently with the calculation. The user has the capability to override the plant's modeled control system with hardware-adjustment commands. This gives the NPA the utility of a simulator, and at the same time, the accuracy of an advanced, best-estimate, power-plant systems code for plant operation and safety analysis.

  8. Induced Release of a Plant-Defense Volatile `Deceptively' Attracts Insect Vectors to Plants Infected with a Bacterial

    E-Print Network [OSTI]

    Burns, Jacqueline K.

    , and pathogen. Pathogen-induced plant responses can include changes in volatile and nonvolatile secondary metabolites as well as major plant nutrients. Experiments were conducted to understand how a plant pathogenicInduced Release of a Plant-Defense Volatile `Deceptively' Attracts Insect Vectors to Plants

  9. Conservation screening curves to compare efficiency investments to power plants: Applications to commercial sector conservation programs

    E-Print Network [OSTI]

    Koomey, Jonathan; Rosenfeld, Arthur H.; Gadgil, Ashok J.

    2008-01-01

    EFFICIENCY INVESTMENTS TO POWER PLANTS: APPLICATIONS TOEFFICIENCY INVESTMENTS TO POWER PLANTS: APPLICATIONS TOEfficiency Investments to Power Plants: Applications to

  10. Engineered plant biomass feedstock particles

    DOE Patents [OSTI]

    Dooley, James H. (Federal Way, WA); Lanning, David N. (Federal Way, WA); Broderick, Thomas F. (Lake Forest Park, WA)

    2011-10-18

    A novel class of flowable biomass feedstock particles with unusually large surface areas that can be manufactured in remarkably uniform sizes using low-energy comminution techniques. The feedstock particles are roughly parallelepiped in shape and characterized by a length dimension (L) aligned substantially with the grain direction and defining a substantially uniform distance along the grain, a width dimension (W) normal to L and aligned cross grain, and a height dimension (H) normal to W and L. The particles exhibit a disrupted grain structure with prominent end and surface checks that greatly enhances their skeletal surface area as compared to their envelope surface area. The L.times.H dimensions define a pair of substantially parallel side surfaces characterized by substantially intact longitudinally arrayed fibers. The W.times.H dimensions define a pair of substantially parallel end surfaces characterized by crosscut fibers and end checking between fibers. The L.times.W dimensions define a pair of substantially parallel top surfaces characterized by some surface checking between longitudinally arrayed fibers. At least 80% of the particles pass through a 1/4 inch screen having a 6.3 mm nominal sieve opening but are retained by a No. 10 screen having a 2 mm nominal sieve opening. The feedstock particles are manufactured from a variety of plant biomass materials including wood, crop residues, plantation grasses, hemp, bagasse, and bamboo.

  11. Engineered plant biomass feedstock particles

    DOE Patents [OSTI]

    Dooley, James H. (Federal Way, WA); Lanning, David N. (Federal Way, WA); Broderick, Thomas F. (Lake Forest Park, WA)

    2011-10-11

    A novel class of flowable biomass feedstock particles with unusually large surface areas that can be manufactured in remarkably uniform sizes using low-energy comminution techniques. The feedstock particles are roughly parallelepiped in shape and characterized by a length dimension (L) aligned substantially with the grain direction and defining a substantially uniform distance along the grain, a width dimension (W) normal to L and aligned cross grain, and a height dimension (H) normal to W and L. The particles exhibit a disrupted grain structure with prominent end and surface checks that greatly enhances their skeletal surface area as compared to their envelope surface area. The L.times.H dimensions define a pair of substantially parallel side surfaces characterized by substantially intact longitudinally arrayed fibers. The W.times.H dimensions define a pair of substantially parallel end surfaces characterized by crosscut fibers and end checking between fibers. The L.times.W dimensions define a pair of substantially parallel top surfaces characterized by some surface checking between longitudinally arrayed fibers. The feedstock particles are manufactured from a variety of plant biomass materials including wood, crop residues, plantation grasses, hemp, bagasse, and bamboo.

  12. Experience curves for power plant emission control technologies

    E-Print Network [OSTI]

    Rubin, Edward S.; Yeh, Sonia; Hounshell, David A

    2007-01-01

    1/2, 2004 Experience curves for power plant emission controlcoal-fired electric power plants. In particular, we focus on2004) ‘Experience curves for power plant emission control

  13. SENSIBLE HEAT STORAGE FOR A SOLAR THERMAL POWER PLANT

    E-Print Network [OSTI]

    Baldwin, Thomas F.

    2011-01-01

    of the Proposed Solar Power Plant Design The Impact ofGenerated by this Solar Power Plant The Impact of StorageDesign on the Solar Power Plant III I;l f> (I Q I) II (I

  14. The hierarchical structure and mechanics of plant materials

    E-Print Network [OSTI]

    Gibson, Lorna

    The cell walls in plants are made up of just four basic building blocks: cellulose (the main structural fibre of the plant kingdom) hemicellulose, lignin and pectin. Although the microstructure of plant cell walls varies ...

  15. SENSIBLE HEAT STORAGE FOR A SOLAR THERMAL POWER PLANT

    E-Print Network [OSTI]

    Baldwin, Thomas F.

    2011-01-01

    Summary of the Proposed Solar Power Plant Design The ImpactGenerated by this Solar Power Plant The Impact of StorageVessel Design on the Solar Power Plant III I;l f> (I Q I)

  16. SENSIBLE HEAT STORAGE FOR A SOLAR THERMAL POWER PLANT

    E-Print Network [OSTI]

    Baldwin, Thomas F.

    2011-01-01

    18% of the installed solar power plant costs. The costs forthe operations and costs for this solar power plant and forenergy generation and cost, The proposed solar power plant

  17. A Boiler Plant Energy Efficiency and Load Balancing Survey 

    E-Print Network [OSTI]

    Nutter, D. W.; Murphy, D. R.

    1997-01-01

    Daily energy use data was used to perform an energy efficiency survey of a medium-sized university boiler plant. The physical plant operates centralized mechanical plants to provide both chilled water and steam for building conditioning. Steam...

  18. Rangeland Drought Management for Texans: Toxic Range Plants 

    E-Print Network [OSTI]

    Hart, Charles R.; Carpenter, Bruce B.

    2001-05-03

    Toxic plants can pose a major threat to livestock during a drought. This publication explains the importance of knowing which plants are toxic, keeping the range healthy, and preventing toxic plant problems....

  19. The effects of variable operation on RO plant performance

    E-Print Network [OSTI]

    Williams, Christopher Michael, S.M. Massachusetts Institute of Technology

    2011-01-01

    Optimizations of reverse osmosis (RO) plants typically consider steady state operation of the plant. RO plants are subject to transient factors that may make it beneficial to produce more water at one time than at another. ...

  20. SENSIBLE HEAT STORAGE FOR A SOLAR THERMAL POWER PLANT

    E-Print Network [OSTI]

    Baldwin, Thomas F.

    2011-01-01

    efficiency of a solar power plant with gas-turbine toppingon the Solar Power Plant Heat~Transfer Gas Properties Modelfor a solar power plant with Brayton-cycle gas turbine

  1. A Continuous Solar Thermochemical Hydrogen Production Plant Design

    E-Print Network [OSTI]

    Luc, Wesley Wai

    a 2,600,000 m 2 solar thermal power plant called IvanpahSolar Thermal Power? ” Proceedings of VGB Congress Power Plants,drive a power or thermochemical plant. Solar thermal energy

  2. Experience curves for power plant emission control technologies

    E-Print Network [OSTI]

    Rubin, Edward S.; Yeh, Sonia; Hounshell, David A; Taylor, Margaret R

    2007-01-01

    emissions from coal-fired power plants have been the subjectrequired on all new coal-fired power plants in the US andof FGD at coal-burning power plants can be traced back to

  3. Experience curves for power plant emission control technologies

    E-Print Network [OSTI]

    Rubin, Edward S.; Yeh, Sonia; Hounshell, David A

    2007-01-01

    a standardised coal-fired power plant (500 MWe, 3.5% sulphura standardised coal-fired power plant (500 MWe, 3.5% sulphurfor a standard coal-fired power plant (500 MWe, Another

  4. New Nissan Paint Plant Achieves 30% Energy Savings

    Broader source: Energy.gov [DOE]

    The new paint plant, which is Nissan North America’s showcase project under the Better Plants Challenge, is expected to be about 30% more efficient than the plant it is replacing.

  5. Lectin cDNA and transgenic plants derived therefrom

    DOE Patents [OSTI]

    Raikhel, Natasha V. (Okemos, MI)

    2000-10-03

    Transgenic plants containing cDNA encoding Gramineae lectin are described. The plants preferably contain cDNA coding for barley lectin and store the lectin in the leaves. The transgenic plants, particularly the leaves exhibit insecticidal and fungicidal properties.

  6. Pinellas Plant feasibility study. Final report

    SciTech Connect (OSTI)

    NONE

    1994-09-01

    The Pinellas Plant was built in 1956 to manufacture neutron generators, a principal component in nuclear weapons. In September 1990, the Department of Health and Rehabilitative Services (HRS) entered into an agreement with DOE to independently examine environmental monitoring data from the plant and health data from Pinellas County to determine if an epidemiological study is technically feasible to measure possible off-site health effects from ionizing radiation. Through normal plant operations, some radioactive materials have been released to the environment. Eighty percent of the total plant releases of 107,707 curies occurred in the early years of plant operation (1957--1960). The primary materials released were tritium gas, tritium oxide and krypton-85. Environmental monitoring for radioactive releases from the plant has been done regularly since 1975. The US Public Health Service Centers for Disease Control and Prevention (CDC), in assisting HRS, has determined that sufficient radiological data exist by which a dose reconstruction can be done. A dose reconstruction can provide an estimate of how much radiological exposure someone living in the vicinity of the Pinellas Plant may have suffered from environmental releases.

  7. LAURA HILL, PH.D. Lecturer and Research Associate, University of Vermont (UVM) Plant Biology Department

    E-Print Network [OSTI]

    Molofsky, Jane

    plants for food, medicine, clothing, and shelter, why plant biologists are concerned about invasive species and habitat fragmentation, how plants influence earth's climate, why different plant communities

  8. LBB considerations for a new plant design

    SciTech Connect (OSTI)

    Swamy, S.A.; Mandava, P.R.; Bhowmick, D.C.; Prager, D.E.

    1997-04-01

    The leak-before-break (LBB) methodology is accepted as a technically justifiable approach for eliminating postulation of Double-Ended Guillotine Breaks (DEGB) in high energy piping systems. This is the result of extensive research, development, and rigorous evaluations by the NRC and the commercial nuclear power industry since the early 1970s. The DEGB postulation is responsible for the many hundreds of pipe whip restraints and jet shields found in commercial nuclear plants. These restraints and jet shields not only cost many millions of dollars, but also cause plant congestion leading to reduced reliability in inservice inspection and increased man-rem exposure. While use of leak-before-break technology saved hundreds of millions of dollars in backfit costs to many operating Westinghouse plants, value-impacts resulting from the application of this technology for future plants are greater on a per plant basis. These benefits will be highlighted in this paper. The LBB technology has been applied extensively to high energy piping systems in operating plants. However, there are differences between the application of LBB technology to an operating plant and to a new plant design. In this paper an approach is proposed which is suitable for application of LBB to a new plant design such as the Westinghouse AP600. The approach is based on generating Bounding Analyses Curves (BAC) for the candidate piping systems. The general methodology and criteria used for developing the BACs are based on modified GDC-4 and Standard Review Plan (SRP) 3.6.3. The BAC allows advance evaluation of the piping system from the LBB standpoint thereby assuring LBB conformance for the piping system. The piping designer can use the results of the BACs to determine acceptability of design loads and make modifications (in terms of piping layout and support configurations) as necessary at the design stage to assure LBB for the, piping systems under consideration.

  9. Grazing and Browsing: How Plants are Affected 

    E-Print Network [OSTI]

    Lyons, Robert K.; Hanselka, C. Wayne

    2001-12-13

    defoliated, it may change the destination of its food products. The destination of that food varies with plant species. In some species, more food is sent to growing shoots and less to roots. This process occurs for a few days until the food-producing tissues... plant when its growing points are elevated reduces new leaf production, and therefore, the ability of the plant to produce food and tol- erate grazing. Destruction of the growing point also pre- vents seed production and production of new seedlings...

  10. Texas Plant Disease Diagnostic Lab Information Form 

    E-Print Network [OSTI]

    Barnes, Larry W.

    2009-01-16

    : _________________________________________________ variety/cultivar: ______________________________________________ Planting date: _____________________________ % of plants affected: ____________ % of area affected on the plant: ____________ Date first noticed: _________________________ Soil p...: report unless specified ? do not notify Recent pesticide & chemical application Product name Date Fertilizer(s) Fungicide(s) Insecticide(s) Herbicide(s) Other Th e T e x a s P l a n t D i s e a s e D i a g n o st i c L a b o r a t o r y ( T P D D L...

  11. Optical manufacturing requirements for an AVLIS plant

    SciTech Connect (OSTI)

    Primdahl, K.; Chow, R.; Taylor, J.R.

    1997-07-14

    A uranium enrichment plant utilizing Atomic Vapor Laser Isotope Separation (AVLIS) technology is currently being planned. Deployment of the Plant will require tens of thousands of commercial and custom optical components and subsystems. The Plant optical system will be expected to perform at a high level of optical efficiency and reliability in a high-average-power-laser production environment. During construction, demand for this large number of optics must be coordinated with the manufacturing capacity of the optical industry. The general requirements and approach to ensure supply of optical components is described. Dynamic planning and a closely coupled relationship with the optics industry will be required to control cost, schedule, and quality.

  12. Cogeneration Plant is Designed for Total Energy 

    E-Print Network [OSTI]

    Howell, H. D.; Vera, R. L.

    1987-01-01

    stream_source_info ESL-IE-87-09-45.pdf.txt stream_content_type text/plain stream_size 19371 Content-Encoding ISO-8859-1 stream_name ESL-IE-87-09-45.pdf.txt Content-Type text/plain; charset=ISO-8859-1 COGENERATION PLANT... of a 200 MW combined cycle cogeneration plant located at Occidental Chemical Corporation's Battleground chlorine-caustic plant at La Porte, Texas. This successful application of a total energy management concept utilizing combined cycle...

  13. Plant Biomechanics Conference Stockholm, August 28 September 1 2006 Twining Plants: How Thick Should their Supports Be?

    E-Print Network [OSTI]

    Neukirch, Sébastien

    5th Plant Biomechanics Conference ­ Stockholm, August 28 ­ September 1 2006 Twining Plants: How graphics (from: Knut Arild Erstad www.ii.uib.no/~knute). #12;5th Plant Biomechanics Conference ­ Stockholm

  14. Fuel-Flexible Combustion System for Refinery and Chemical Plant...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Flexible Combustion System for Refinery and Chemical Plant Process Heaters - Fact Sheet 2014 Fuel-Flexible Combustion System for Refinery and Chemical Plant Process Heaters - Fact...

  15. Combined Heat and Power (CHP) Plant fact sheet | Argonne National...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Combined Heat and Power (CHP) Plant fact sheet Argonne National Laboratory's Combined Heat and Power (CHP) plant, expected to be operational in June 2016, will provide electricity...

  16. CHP and Bioenergy for Landfills and Wastewater Treatment Plants...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for Landfills and Wastewater Treatment Plants: Market Opportunities CHP and Bioenergy for Landfills and Wastewater Treatment Plants: Market Opportunities This document explores...

  17. Avoiding a Train Wreck: Replacing Old Coal Plants with Energy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Avoiding a Train Wreck: Replacing Old Coal Plants with Energy Efficiency, August 2011 Avoiding a Train Wreck: Replacing Old Coal Plants with Energy Efficiency, August 2011 This...

  18. Waste Isolation Pilot Plant Typifies Optimizing Resources to...

    Office of Environmental Management (EM)

    Isolation Pilot Plant Typifies Optimizing Resources to Maximize Results Waste Isolation Pilot Plant Typifies Optimizing Resources to Maximize Results March 5, 2013 - 12:00pm...

  19. commentary: Is climate change making plants go up mountains?

    E-Print Network [OSTI]

    Lovett, Jon C.; Hemp, Andreas

    2010-01-01

    Plant Ecology of High Mountain Ecosystems. pp 1-344altitudinal distribution in mountain forests during themaking plants go up mountains? Paleontological evidence

  20. Project Profile: Modular and Scalable Baseload Molten Salt Plant...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Modular and Scalable Baseload Molten Salt Plant Conceptual Design and Feasibility Project Profile: Modular and Scalable Baseload Molten Salt Plant Conceptual Design and Feasibility...

  1. Oceanographic Considerations for Desalination Plants in Southern California Coastal Waters

    E-Print Network [OSTI]

    Jenkins, Scott A; Wasyl, Joseph

    2005-01-01

    water for the desalination plant will be seawater drawn fromand concentrated seawater from the desalination plant. Theseconcentrated seawater dilution for the ocean desalination

  2. Renewable Energy Plants in Your Gas Tank: From Photosynthesis...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Plants in Your Gas Tank: From Photosynthesis to Ethanol (4 Activities) Renewable Energy Plants in Your Gas Tank: From Photosynthesis to Ethanol (4 Activities) Below is information...

  3. Portsmouth Gaseous Diffusion Plant - Quadrant I Groundwater Investigat...

    Office of Environmental Management (EM)

    Portsmouth Gaseous Diffusion Plant - Quadrant I Groundwater Investigative (5-Unit) Area Plume Portsmouth Gaseous Diffusion Plant - Quadrant I Groundwater Investigative (5-Unit)...

  4. DOE Offers Support for Innovative Manufacturing Plant That Will...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Offers Support for Innovative Manufacturing Plant That Will Produce High Quality Solar Silicon at Low Cost DOE Offers Support for Innovative Manufacturing Plant That Will Produce...

  5. Enterprise Assessments Review of Waste Isolation Pilot Plant...

    Office of Environmental Management (EM)

    Waste Isolation Pilot Plant Engineering and Procurement Processes - November 2015 Enterprise Assessments Review of Waste Isolation Pilot Plant Engineering and Procurement Processes...

  6. Front-runners in plant-microbe interactions.

    E-Print Network [OSTI]

    Ronald, Pamela C; Shirasu, Ken

    2012-01-01

    Front-runners in plant–microbe interactions Editorialwww.sciencedirect.com Plants and microbes, abundant in thedetermine if the associated microbes are friends or foes,

  7. Bionic Plants | U.S. DOE Office of Science (SC)

    Office of Science (SC) Website

    The researchers then turned to living plants and used a technique called vascular infusion to deliver nanoparticles into Arabidopsis thaliana, a small flowering plant. Using...

  8. Plant stimulation of soil microbial community succession: how...

    Office of Scientific and Technical Information (OSTI)

    Plant stimulation of soil microbial community succession: how sequential expression mediates soil carbon stabilization and turnover Citation Details In-Document Search Title: Plant...

  9. Nevada's Beowawe Geothermal Plant Begins Generating Clean Energy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Nevada's Beowawe Geothermal Plant Begins Generating Clean Energy Nevada's Beowawe Geothermal Plant Begins Generating Clean Energy April 20, 2011 - 1:45pm Addthis U.S. Energy...

  10. World's Largest Concentrating Solar Power Plant Opens in California...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    World's Largest Concentrating Solar Power Plant Opens in California World's Largest Concentrating Solar Power Plant Opens in California February 19, 2014 - 12:00am Addthis Ivanpah,...

  11. The Waste Isolation Pilot Plant Hazardous Waste Facility Permit...

    Office of Environmental Management (EM)

    The Waste Isolation Pilot Plant Hazardous Waste Facility Permit, Waste Analysis Plan The Waste Isolation Pilot Plant Hazardous Waste Facility Permit, Waste Analysis Plan This...

  12. Independent Oversight Focused Review, Kansas City Plant, Summary...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Review, Kansas City Plant, Summary Report - December 2001 Independent Oversight Focused Review, Kansas City Plant, Summary Report - December 2001 December 2001 Focused Review of...

  13. Joint Venture Established Between Russian Weapons Plant And the...

    National Nuclear Security Administration (NNSA)

    Weapons Plant And the Largest Dialysis Provider in the U.S. Press Release Sep 20, 2001 Joint Venture Established Between Russian Weapons Plant And the Largest Dialysis...

  14. Waste Isolation Pilot Plant Update | Department of Energy

    Office of Environmental Management (EM)

    Update Waste Isolation Pilot Plant Update Waste Isolation Pilot Plant Update More Documents & Publications Transuranic Package Transporter (TRUPACT-III) Content Codes (TRUCON-III)...

  15. Agua Caliente, World's Largest Solar Photovoltaic Plant, Helps...

    Office of Environmental Management (EM)

    Agua Caliente, World's Largest Solar Photovoltaic Plant, Helps Advance America's Solar Leadership Agua Caliente, World's Largest Solar Photovoltaic Plant, Helps Advance America's...

  16. CHP SYSTEM AT FOOD PROCESSING PLANT INCREASES RELIABILITY AND...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CHP SYSTEM AT FOOD PROCESSING PLANT INCREASES RELIABILITY AND REDUCES EMISSIONS - CASE STUDY, 2015 CHP SYSTEM AT FOOD PROCESSING PLANT INCREASES RELIABILITY AND REDUCES EMISSIONS -...

  17. Plutonium Finishing Plant 242-Z Americium Recovery Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of the overall mission to safely and compliantly decommission and demolish Hanford's Plutonium Finishing Plant. The Plutonium Finishing Plant once produced two-thirds of the...

  18. Field trials identify more native plants suited to urban landscaping

    E-Print Network [OSTI]

    Reid, S. Karrie; Oki, Lorence R

    2008-01-01

    developed All-Stars plant lists to help visitors identifyat arboretum plant sales. From the All-Stars list as well as

  19. Source Term Analysis for the Waste Isolation Pilot Plant (WIPP...

    Office of Environmental Management (EM)

    Source Term Analysis for the Waste Isolation Pilot Plant (WIPP) Release Quantity Source Term Analysis for the Waste Isolation Pilot Plant (WIPP) Release Quantity This document was...

  20. Cook-off Experiments with Surrogate Waste Isolation Pilot Plant...

    Office of Environmental Management (EM)

    Cook-off Experiments with Surrogate Waste Isolation Pilot Plant (WIPP) Drum Contents Cook-off Experiments with Surrogate Waste Isolation Pilot Plant (WIPP) Drum Contents This...