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Note: This page contains sample records for the topic "butyl ether na" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Control Study of Ethyl tert-Butyl Ether Reactive Distillation Muhammad A. Al-Arfaj  

E-Print Network (OSTI)

-butyl ether (ETBE) for gasoline blending as a replacement for methyl tert-butyl ether (MTBE) because and be blended with ETBE in the gasoline pool. Even for neat operation, if the conversion is low, the unconverted

Al-Arfaj, Muhammad A.

2

State Restrictions on Methyl Tertiary Butyl Ether (released in AEO2006)  

Reports and Publications (EIA)

By the end of 2005, 25 states had barred, or passed laws banning, any more than trace levels of methyl tertiary butyl ether (MTBE) in their gasoline supplies, and legislation to ban MTBE was pending in 4 others. Some state laws address only MTBE; others also address ethers such as ethyl tertiary butyl ether (ETBE) and tertiary amyl methyl ether (TAME). Annual Energy Outlook 2006 assumes that all state MTBE bans prohibit the use of all ethers for gasoline blending.

2006-01-01T23:59:59.000Z

3

Atmospheric chemistry of diethyl ether and ethyl tert-butyl ether  

SciTech Connect

The mechanisms for the Cl-initiated and OH-initiated atmospheric oxidation of diethyl ether and ethyl tert-butyl ether (ETBE) have been determined. For diethyl ether the products are ethyl formate and formaldehyde and its atmospheric oxidation can be represented by C{sub 2}H{sub 5}OC{sub 2}H{sub 5} + OH + 2NO {yields} C{sub 2}H{sub 5}OC(O)H + HCHO + 2NO{sub 2} + HO{sub 2}. The mechanism for the atmospheric oxidation of ETBE is more complex, with 80% of the reaction being accounted for in terms of tert-butyl formate and formaldehyde. The remaining 20% the authors ascribe to 2-ethoxy-2-methylpropanal. The atmospheric oxidation of ETBE can be represented by ETBE + OH + 1.8NO {yields} 0.8HCOOC(CH{sub 3}){sub 3} + 0.2C{sub 2}H{sub 5}OC(CH{sub 3}){sub 2}CHO + HO{sub 2} + 0.8HCHO + 1.8NO{sub 2}. THe subsequent atmospheric chemistry of 2-ethoxy-2-methylpropanal the authors estimate to be represented by C{sub 2}H{sub 5}OC(CH{sub 3}){sub 2}CHO + OH + 3NO {yields} CO{sub 2} + H{sub 2}CO + C{sub 2}H{sub 5}OC(O)CH{sub 3} + HO{sub 2} + 3NO{sub 2}. These results are discussed in terms of the reactivity of these compounds in urban atmospheres.

Wallington, T.J.; Japar, S.M. (Ford Motor Company, Dearborn, MI (USA))

1991-03-01T23:59:59.000Z

4

Separation of methyl t-butyl ether from close boiling C[sub 5] hydrocarbons by extractive distillation  

SciTech Connect

A method for recovering methyl t-butyl ether from a mixture of methyl t-butyl ether and 1-pentene which comprises distilling a mixture of methyl t-butyl ether and 1-pentene in the presence of about one part of an extractive agent per part of methyl t-butyl ether -- 1-pentene mixture, recovering the 1-pentene as overhead product and obtaining the methyl t-butyl ether and the extractive agent from the still pot, wherein said extractive agent consists of one material selected from the group consisting of sulfolane, nitroethane, t-butanol, ethylene glycol diacetate, 1-methoxy-2-propanol acetate, methyl isoamyl ketone, ethylene glycol methyl ether, propylene glycol phenyl ether and diethyl malonate.

Berg, L.

1993-07-20T23:59:59.000Z

5

IDENTIFYING THE USAGE PATTERNS OF METHYL TERT-BUTYL ETHER (MTBE) AND OTHER OXYGENATES IN GASOLINE USING GASOLINE  

E-Print Network (OSTI)

IDENTIFYING THE USAGE PATTERNS OF METHYL TERT-BUTYL ETHER (MTBE) AND OTHER OXYGENATES IN GASOLINE USING GASOLINE SURVEYS By Michael J. Moran, Rick M. Clawges, and John S. Zogorski U.S. Geological Survey 1608 Mt. View Rapid City, SD 57702 Methyl tert-butyl ether (MTBE) is commonly added to gasoline

6

Whole-Genome Analysis of Methyl tert-Butyl Ether-Degrading Beta-Proteobacterium Methylibium petroleiphilum PM1  

E-Print Network (OSTI)

Sato, and N. Kato. 2003. Propane monooxygenase and NAD + -alcohol dehydrogenase in propane metabolism by Gordonia sp.tert-butyl ether by propane-grown Mycobacterium vaccae JOB5.

2007-01-01T23:59:59.000Z

7

Dynamic Simulation of Startup in Ethyl tert-Butyl Ether Reactive Distillation with Input Multiplicity  

Science Journals Connector (OSTI)

Dynamic Simulation of Startup in Ethyl tert-Butyl Ether Reactive Distillation with Input Multiplicity ... However, smaller internal rates inside the column that result from lower reboiler and condenser duty could increase the potential risk of flooding in the column and reduce the availability of reactants in the reactive section. ... Column simulations performed using both Pro/II and SpeedUp showed excellent agreement with previously published exptl. ...

Budi H. Bisowarno; Moses O. Tadé

2000-05-09T23:59:59.000Z

8

Detection and Quantification of Methyl tert-Butyl Ether-Degrading Strain PM1 by Real-Time TaqMan PCR  

Science Journals Connector (OSTI)

...purification Fresh Water microbiology Geologic...Polymerase metabolism Water Pollution, Chemical...bioremediation detection ethers ground water hydrocarbons methyl tert-butyl...pollutants pollution remediation sampling water resources...

Krassimira R. Hristova; Christian M. Lutenegger; Kate M. Scow

2001-11-01T23:59:59.000Z

9

Methyl tert-butyl ether (MTBE) is a volatile organic com-pound (VOC) derived from natural gas that is added to gas-  

E-Print Network (OSTI)

Methyl tert-butyl ether (MTBE) is a volatile organic com- pound (VOC) derived from natural gas Water in Urban and Agricultural Areas made from methanol, which is derived primarily from natural gas that is added to gas- oline either seasonally or year round in many parts of the United States to increase

10

E-Print Network 3.0 - anhydride-vinyl methyl ether Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

4-Methyl-2-pentanol Other secondary alcohols... - quire handling with precautions. Acrolein tert-Butyl methyl ether Di(1-propynl) ether n... Methoxy-1,3,5,7- cyclooctatetraene...

11

Ditertiary butyl peroxide recovery  

SciTech Connect

A process is described wherein a feed material comprising significant amounts of tertiary butyl hydroperoxide and tertiary butyl alcohol and minor amounts of ditertiary butyl peroxide and other impurities is charged to a reactor together with propylene and a soluble epoxidation catalyst. At least a portion of the tertiary butyl hydroperoxide is reacted in the reactor with the propylene to form a reaction product composed of unreacted feed components, propylene oxide, an additional quantity of tertiary butyl alcohol, and impurities, including a minor amount of ditertiary butyl peroxide. The improvement for recovering substantially pure ditertiary butyl peroxide from the reaction product after the reaction product is discharged from the reactor comprises the steps of: charging the reaction product to a first distillation zone and separating therein a first unreacted propylene distillate recycle fraction, charging the remaining heavier components of the reaction product from the first distillation zone to a second distillation zone and separating a second propylene oxide distillate product fraction therein charging the heavier components from the second distillation zone to a third distillation zone and separating a third distillate fraction comprising a major amount of tertiary butyl alcohol and a minor amount of ditertiary butyl peroxide, and recovering the second propylene oxide distillate fraction, the heavier tertiary butyl alcohol product fraction and the ditertiary butyl peroxide raffinate fraction.

Sanderson, J.R.; Meyer, R.A.; Smith, W.A.; Marquis, E.T.

1989-03-07T23:59:59.000Z

12

Thermodynamic properties of organic oxygen compounds XLIII. Vapour pressures of some ethers  

Science Journals Connector (OSTI)

Vapour pressures of methyl propyl, isopropyl methyl, butyl methyl, ethyl propyl, t-butyl methyl, dipropyl, di-isopropyl, di-t-butyl, and decyl methyl ethers were measured at pressures up to 205 kPa. The measured values were fitted by Antoine and by Chebyshev equations, values already published from this laboratory for three aromatic ethers were recomputed uniformly with the present results, and published values for four additional compounds were incorporated in a scheme for correlation of the vapour pressures of ethers. Estimates were made of the vapour pressures of 10 other ethers. Between 5 and 200 kPa the vapour pressures of ethers may be represented by a single equation in which carbon number or an effective carbon number is a parameter. Chebyshev equations are given for interpolation between the upper bounds of the measurements and the critical pressures of 11 ethers for which this property has been previously determined.

D Ambrose; J.H Ellender; C.H.S Sprake; R Townsend

1976-01-01T23:59:59.000Z

13

Production of methyl tert-alkyl ethers  

SciTech Connect

The transition to the use of unleaded gasolines has required the replacement of tetraethyl lead by oxygen-containing compounds such as methanol, ethanol, and ethers, which are termed {open_quotes}oxygenates{close_quotes} in the technical literature. These may be used in commercial gasolines in amounts of 10-15% by volume, equivalent to 2% oxygen by weight. When methyl tert-butyl ether (MTBE) is used, the oxygen content may amount to 2.7% by weight. This oxygenate gives a significant improvement of knock resistance of naphtha fractions, the greatest effects being observed for straight-run naphthas and reformer naphthas produced under normal conditions; the MTBE also improves the engine power and economy characteristics and lowers the carbon monoxide content in the exhaust by 15-30% and the hydrocarbon content by 7-8%. This paper describes methods for the production of MTBE and also methyl tert-alkyl ethers.

Trofimov, V.A.

1995-01-01T23:59:59.000Z

14

E-Print Network 3.0 - alkyl-tert alkyl ethers Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

> >> 1 7198 J. Org. Chem. 1995,60, 7198-7208 Gas Phase Decomposition of Conjugate Acid Ions of Simple Summary: of ProtonatedAlkyl tert-ButylEthers RO(H)C(CH&+ (To.6 Values in meV...

15

Reaction Pathways and Energetics of Etheric C?O Bond Cleavage Catalyzed by Lanthanide Triflates  

SciTech Connect

Efficient and selective cleavage of etheric C?O bonds is crucial for converting biomass into platform chemicals and liquid transportation fuels. In this contribution, computational methods at the DFT B3LYP level of theory are employed to understand the efficacy of lanthanide triflate catalysts (Ln(OTf)3, Ln = La, Ce, Sm, Gd, Yb, and Lu) in cleaving etheric C?O bonds. In agreement with experiment, the calculations indicate that the reaction pathway for C?O cleavage occurs via a C?H ? O?H proton transfer in concert with weakening of the C?O bond of the coordinated ether substrate to ultimately yield a coordinated alkenol. The activation energy for this process falls as the lanthanide ionic radius decreases, reflecting enhanced metal ion electrophilicity. Details of the reaction mechanism for Yb(OTf)3-catalyzed ring opening are explored in depth, and for 1-methyl-d3-butyl phenyl ether, the computed primary kinetic isotope effect of 2.4 is in excellent agreement with experiment (2.7), confirming that etheric ring-opening pathway involves proton transfer from the methyl group alpha to the etheric oxygen atom, which is activated by the electrophilic lanthanide ion. Calculations of the catalytic pathway using eight different ether substrates indicate that the more rapid cleavage of acyclic versus cyclic ethers is largely due to entropic effects, with the former C?O bond scission processes increasing the degrees of freedom/particles as the transition state is approached.

Assary, Rajeev S.; Atesin, Abdurrahman C.; Li, Zhi; Curtiss, Larry A.; Marks, Tobin J.

2013-07-15T23:59:59.000Z

16

Propenyl ether monomers for photopolymerization  

DOE Patents (OSTI)

Propenyl ether monomers of formula A(OCH{double_bond}CHCH{sub 3}){sub n} wherein n is an integer from one to six and A is selected from cyclic ethers, polyether and alkanes are disclosed. The monomers are readily polymerized in the presence of cationic photoinitiators, when exposed to actinic radiation, to form poly(propenyl ethers) that are useful for coatings, sealants, varnishes and adhesives. Compositions for preparing polymeric coatings comprising the compounds of the above formula together with particular cationic photoinitiators are also disclosed, as are processes for making the monomers from allyl halides and readily available alcohols. The process involves rearranging the resulting allyl ethers to propenyl ethers.

Crivello, J.V.

1996-10-22T23:59:59.000Z

17

Use of superconductor type catalysts in the preparation of tertiary butyl alcohol from tertiary butyl hydroperoxide  

SciTech Connect

In a method wherein a solution of a tertiary butyl hydroperoxide charge stock in tertiary butyl alcohol is brought into contact with a catalytically effective amount of a hydroperoxide decomposition catalyst in a hydroperoxide decomposition reaction zone in liquid phase with agitation to convert said tertiary butyl hydroperoxide to decomposition products, principally tertiary butyl alcohol, the improvement is described which comprises: (a) using a superconductor as said hydroperoxide decomposition catalyst, and (b) recovering tertiary butyl alcohol from the products of said hydroperoxide decomposition reaction.

Sanderson, J.R.; Stockton, M.E.

1993-08-17T23:59:59.000Z

18

Process for producing high purity isoolefins and dimers thereof by dissociation of ethers  

DOE Patents (OSTI)

Alkyl tertiary butyl ether or alkyl tertiary amyl ether is dissociated by vapor phase contact with a cation acidic exchange resin at temperatures in the range of 150 to 250 F at LHSV of 0.1 to 20 to produce a stream consisting of unreacted ether, isobutene or isoamylene and an alcohol corresponding to the alkyl radical. After the alcohol is removed, the ether/isoolefin stream may be fractionated to obtain a high purity isoolefin (99+%) or the ether/isoolefin stream can be contacted in liquid phase with a cation acidic exchange resin to selectively dimerize the isoolefin in a highly exothermic reaction, followed by fractionation of the dimerization product to produce high purity diisoolefin (97+%). In the case where the alkyl is C[sub 3] to C[sub 6] and the corresponding alcohol is produced on dissociation of the ether, combined dissociation-distillation may be carried out such that isoolefin is the overhead product and alcohol the bottom. 2 figs.

Smith, L.A. Jr.; Jones, E.M. Jr.; Hearn, D.

1984-05-08T23:59:59.000Z

19

Accelerated aging of EPDM and butyl elastomers  

SciTech Connect

This study was composed of three parts: a post cure study to optimize final properties of an ethylene-propylene-diene (EPDM) formulation, an accelerated aging study to compare the stress relaxation behavior of a butyl and an EPDM elastomer under compression, and a cursory evaluation of a new 70 Shore A EPDM. The optimum postcure for the EPDM was found to be 2 to 4 hours at 182{degrees}C in a vacuum. The EPDM was also shown to have superior aging characteristics compared to the butyl and is recommended for use instead of the butyl material. The physical properties for new 70 Shore A EPDM are satisfactory, and the stress relaxation behavior was only slightly inferior to the other EPDM.

Wilson, M.H.

1996-06-01T23:59:59.000Z

20

Use of ethers as high-octane components of gasolines  

SciTech Connect

This article reports on a study of the possible utilization of methyl tert-amyl ether (MTAE) as an automotive gasoline component, both by itself and in combination with methyl tert-butyl ether (MTBE). The naphtha used in these studies consisted of 80% reformer naphtha produced under severe conditions and 20% straight-run IBP-62/sup 0/C cut. The physicochemical properties of the MTAE, the MTBE, and the naphtha base stock are given. It is determined that MTAE, which has a slightly poorer knock resistance than MTBE, is fully equal to MTBE in all other respects and can be used as an automotive gasoline component; that a gasoline blend prepared from 89% naphtha base stock, 5.5% MTAE, and 5.5% MTBE meets all of the requirements of the standard GOST 2084-77 for Grade AI-93 gasoline; and that the use of MTAE offers a means for expanding the resources of high-octane components, lowering the toxicity of the gasolines and the exhaust gas (in comparison with organometallic antiknock agents), and bringing non-petroleum raw materials into the fuel production picture.

Gureev, A.A.; Baranova, G.N.; Korotkov, I.V.; Levinson, G.I.

1984-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "butyl ether na" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

E-Print Network 3.0 - alkyl tert-butyl ether Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

> >> 1 7198 J. Org. Chem. 1995,60, 7198-7208 Gas Phase Decomposition of Conjugate Acid Ions of Simple Summary: .S.Patent 5,091,590,1992. 0 1995American Chemical Society...

22

Treatment of Methyl tert-Butyl Ether Vapors in Biotrickling Filters. 1.  

E-Print Network (OSTI)

because of its low cost and blending characteristics. Depending on the season, reformulated gasoline of reactor per hour, a value comparable to other gasoline constituents. Such high performance could enhancer in gasoline. The use of MTBE increased rapidly after the 1990 Clean Air Act Amendments required

23

Environmental Microbiology (2001) 3(6), 407416 Methyl tert-butyl ether (MTBE) degradation by a  

E-Print Network (OSTI)

Tank (LUFT) remediation programme. A recent USGS study has estimated that as many as 9000 community, remediation actions are implemented at costs usually 10± 30% higher than those at sites without MTBE contamina- tion. The evaluation of innovative and cost-effective treatment such as bioremediation for MTBE spills

24

Biodegradation of Methyl tert-Butyl Ether by a Pure Bacterial Culture  

Science Journals Connector (OSTI)

...identify cost-effective remediation technologies. Relatively...treated with ENV735 as a remediation biocatalyst, but the strain...through the Small Business Innovative Research program (grant...situ bioaugmentation for remediation of chlorinated solvents in...

Paul B. Hatzinger; Kevin McClay; Simon Vainberg; Marina Tugusheva; Charles W. Condee; Robert J. Steffan

2001-12-01T23:59:59.000Z

25

Treatment of Methyl tert-Butyl Ether Contaminated Water Using a Dense  

E-Print Network (OSTI)

discharge of organic compounds require that new, innovative tech- nologies and methods of remediation dioxide, making the DMP reactor a promising tool in the future remediation of water. Chemical and physical is transformed into a more toxic material or a substance that is more difficult to remediate, the treatment

Dandy, David

26

High octane ethers from synthesis gas-derived alcohols. Final technical report, September 25, 1990--December 24, 1993  

SciTech Connect

The objective of the research was to develop the methodology for the catalytic synthesis of ethers, primarily methyl isobutyl ether (MIBE) and methyl tertiary butyl ether (MTBE), directly from alcohol mixtures that are rich in methanol and 2-methyl-1-propanol (isobutanol). The overall scheme involves gasification of coal, purification and shifting of the synthesis gas, higher alcohol synthesis, and direct synthesis of ethers. The last stage of the synthesis involves direct coupling of synthesis gas-derived methanol and isobutanol that has been previously demonstrated by us to occur over superacid catalysts to yield MIBE and smaller amounts of MTBE at moderate pressures and a mixture of methanol and isobutene at low pressures. A wide range of organic resin catalysts and inorganic oxide and zeolite catalysts have been investigated for activity and selectivity in directly coupling alcohols, principally methanol and isobutanol, to form ethers and in the dehydration of isobutanol to isobutene in the presence of methanol. All of these catalysts are strong acids, and it was found that the organic and inorganic catalysts operate in different, but overlapping, temperature ranges, i.e. mainly 60--120{degrees}C for the organic resins and 90--175{degrees}C for the inorganic catalysts. For both types of catalysts, the presence of strong acid centers is required for catalytic activity, as was demonstrated by lack of activity of fully K{sup +} ion exchanged Nafion resin and zirconia prior to being sulfated by treatment with sulfuric acid.

Klier, K.; Herman, R.G.

1994-05-01T23:59:59.000Z

27

Catalytic distillation for the synthesis of tertiary butyl alcohol.  

E-Print Network (OSTI)

??Catalytic Distillation for the synthesis of tertiary butyl alcohol (TBA) is investigated in this thesis. The solvent, ethylene glycol, is proposed as a means of… (more)

Safinski, Tomasz

2005-01-01T23:59:59.000Z

28

Near-Infrared Electrochromism in Electroactive Pentacenediquinone-Containing Poly(aryl ether)s  

E-Print Network (OSTI)

Near-Infrared Electrochromism in Electroactive Pentacenediquinone-Containing Poly(aryl etherVed October 21, 2005 The synthesis and near-infrared electrochromic properties of pentacenediquinone-infrared electrochromic properties of pentacenediquinone-containing poly(aryl ether)s were studied

Wan, Xin-hua

29

E-Print Network 3.0 - ammoniated glycyrrhizin butylated Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

ammoniated glycyrrhizin butylated Search Powered by Explorit Topic List Advanced Search Sample search results for: ammoniated glycyrrhizin butylated Page: << < 1 2 3 4 5 > >> 1...

30

Crown Ethers in Graphene Bring Strong, Selective Binding | ornl...  

NLE Websites -- All DOE Office Websites (Extended Search)

Materials Characterization Crown Ethers in Graphene Bring Strong, Selective Binding November 14, 2014 Schematic showing a graphene sheet containing an array of ideal crown ethers....

31

Ethers have good gasoline-blending attributes  

SciTech Connect

Because of their compatibility with hydrocarbon gasoline-blending components, their high octane blending values, and their low volatility blending values, ethers will grow in use as gasoline blending components. This article discusses the properties of ethers as blending components, and environmental questions.

Unzelman, G.H.

1989-04-10T23:59:59.000Z

32

Purification of aqueous cellulose ethers  

SciTech Connect

Manufacture of cellulose ethers usually involves high amounts of salt by-products. For application of the product, salt must be removed. In this work, we have studied the injection of high-pressure CO{sub 2} into an aqueous polymer-salt solution; we find that upon addition of isopropanol in addition to CO{sub 2}, the solution separates into two phases. One phase is rich in polymer and water, and the other phase contains mostly isopropanol, water and CO{sub 2}. The salt distributes between the two phases, thereby offering interesting possibilities for development of a new purification process for water-soluble polymers. This work presents experimental phase-equilibrium data for hydroxyethyl cellulose and sodium carboxymethyl cellulose with sodium acetate and potassium sulfate, respectively, in the region 40{degree}C and 30 to 80 bar. Based on these data, we suggest a process for the manufacture and purification of water-soluble cellulose ethers. 15 refs., 14 figs., 9 tabs.

Bartscherer, K.A.; de Pablo, J.J.; Bonnin, M.C.; Prausnitz, J.M.

1990-07-01T23:59:59.000Z

33

Impacts of Ethanol on Anaerobic Production of Tert-Butyl Alcohol (TBA) from Methyl Tert-Butyl Ether (MTBE) in Groundwater  

E-Print Network (OSTI)

Project title: Impacts of Ethanol on Anaerobic Production oftert-butanol (TBA). As ethanol is being promoted as ainvestigate the effect of ethanol release on existing MTBE

Scow, K M; MacKay, Douglas

2008-01-01T23:59:59.000Z

34

A thermodynamic model of nitric acid extraction by tri-n-butyl phosphate  

SciTech Connect

A thermodynamic model is presented for nitric acid extraction by tri-n-butyl phosphate (TBP). This model is based on the formation of the organic phase species: TBP.HNO/sub 3/ and (TBP)/sub 2/.HNO/sub 3/. The model works successfully at TBP concentrations of 5 to 100 vol% and was found to be effective at predicting the extraction of HNO/sub 3/ from HNO/sub 3//NaNO/sub 3/ and HNO/sub 3//LiNO/sub 3/ solutions. Within the TBP concentration range of 5 to 30%, a single set of extraction constants was sufficient to fit extraction data. Stoichiometric activity coefficients of nitric acid in HNO/sub 3//NaNO/sub 3/ and HNO/sub 3//LiNO/sub 3/ mixtures were calculated using a model developed by Bromley.

Chaiko, D.J.; Vandegrift, G.F.

1988-07-01T23:59:59.000Z

35

Biodegradation of Methyl tert-Butyl Ether and Other Fuel Oxygenates by a New Strain, Mycobacterium austroafricanum IFP 2012  

Science Journals Connector (OSTI)

...and the O2 consumption rate was measured with a 12-mm...France). The measured rates were corrected for endogenous...Cells were broken by three passes through a French press...from 105 to 200C at a rate of 10C/min. Helium...flushed with a Spectra-Physics SCM 400 vacuum flusher...

Alan François; Hugues Mathis; Davy Godefroy; Pascal Piveteau; Françoise Fayolle; Frédéric Monot

2002-06-01T23:59:59.000Z

36

Induction of Methyl Tertiary Butyl Ether (MTBE)-Oxidizing Activity in Mycobacterium vaccae JOB5 by MTBE  

Science Journals Connector (OSTI)

...directly from the culture vessels. In experiments that followed...time course of organic acid consumption as well as MTBE oxidation...determine the extent of MTBE consumption and the accumulation of TBA...detectable growth or MTBE consumption occurred when cells were incubated...

Erika L. Johnson; Christy A. Smith; Kirk T. O'Reilly; Michael R. Hyman

2004-02-01T23:59:59.000Z

37

Enhancing Transport of Hydrogenophaga flava ENV735 for Bioaugmentation of Aquifers Contaminated with Methyl tert-Butyl Ether  

Science Journals Connector (OSTI)

...column was washed with the surfactant solution. d The sand was prewashed with the surfactant solution, and the cells...washed with BSM without surfactant. This work was supported...bacteria through a sandy soil. Appl. Environ. Microbiol...

Sheryl H. Streger; Simon Vainberg; Hailiang Dong; Paul B. Hatzinger

2002-11-01T23:59:59.000Z

38

Treatment of methyl t-butyl ether contaminated water using a dense medium plasma reactor, a mechanistic and kinetic investigation  

E-Print Network (OSTI)

, a mechanistic and kinetic investigation Derek C. Johnson1 , Vasgen A. Shamamian2 , John H. Callahan2 , Ferencz S in the future remediation of water. Chemical and physical mechanisms, together with carbon balances, are used

Dandy, David

39

Effects of Gasoline Formulation on Methyl tert-Butyl Ether (MTBE) Contamination in Private Wells near Gasoline Stations  

Science Journals Connector (OSTI)

New York State Department of Health, Bureau of Environmental Exposure Investigation, 547 River Street, Room 300, Troy, New York 12180, and New York State Department of Health, Wadsworth Center for Laboratories and Research, P.O. ... Wells with contamination of ?20 ?g/L were scheduled for periodic or follow-up sampling by local county health departments or scheduled for remedial action, as appropriate. ... (13)?Delzer, G. C.; Zogorski, J. S.; Lopes, T. J.; Bosshart, R. L. Occurrence of the gasoline Oxygenate MTBE and BTEX compounds in urban stormwater in the United States, 1991?1995; U.S. Geologic Survey Water-Resources Investigations Report, WRIR 96-4145, Rapid City, SD, 1996. ...

Daniel P. Lince; Lloyd R. Wilson; Gordon A. Carlson; Anthony Bucciferro

2001-02-10T23:59:59.000Z

40

Enhancing Transport of Hydrogenophaga flava ENV735 for Bioaugmentation of Aquifers Contaminated with Methyl tert-Butyl Ether  

Science Journals Connector (OSTI)

...National Science Foundation Small Business Innovative Research (SBIR) program (award no...Ontario, Canada. Ground Water Monit. Remediation 18: 113-122. 52 Scholl, M. A...evaluation of in situ bioaugmentation for remediation of chlorinated solvents in groundwater...

Sheryl H. Streger; Simon Vainberg; Hailiang Dong; Paul B. Hatzinger

2002-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "butyl ether na" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Measurement of Trihalomethanes and Methyl Tertiary-Butyl Ether in Tap Water Using Solid-Phase Microextraction GC-MS  

Science Journals Connector (OSTI)

......ductive age living in Corpus Christi, Texas and Cobb...micro extraction with gas chromatography-mass...determinations using gas chromatog- raphy...of fulvic acids in natural waters. Env. Sci...trihalomethane by headspace-gas chromatog- raphy......

Frederick L. Cardinali; David L. Ashley; John C. Morrow; Deborah M. Moll; Benjamin C. Blount

2004-04-01T23:59:59.000Z

42

The Thermal Decomposition of Diethyl Ether. V. The Production of Ethanol from Diethyl Ether and the Pyrolysis of Ethanol  

Science Journals Connector (OSTI)

...The Thermal Decomposition of Diethyl Ether. V. The Production of Ethanol from Diethyl Ether and the Pyrolysis of Ethanol G. R. Freeman The two modes of decomposition of ethanol at 525 degrees C, namely dehydration and dehydrogenation, are affected...

1958-01-01T23:59:59.000Z

43

Process for making propenyl ethers and photopolymerizable compositions containing them  

DOE Patents (OSTI)

Propenyl ether monomers of formula A(OCH{double_bond}CHCH{sub 3}){sub n} (V) wherein n is an integer from one to six and A is selected from cyclic ethers, polyether, and alkanes are disclosed. The monomers are readily polymerized in the presence of cationic photoinitiators, when exposed to actinic radiation, to form poly(propenyl ethers) that are useful for coatings, sealants, varnishes and adhesives. Compositions for preparing polymeric coatings comprising the compounds of formula V together with particular cationic photoinitiators are also disclosed, as are processes for making the monomers from allyl halides and readily available alcohols. The process involves rearranging the resulting allyl ethers to propenyl ethers.

Crivello, J.V.

1996-01-23T23:59:59.000Z

44

Crown Ethers Flatten in Graphene for Strong, Specific Binding...  

NLE Websites -- All DOE Office Websites (Extended Search)

Crown Ethers Flatten in Graphene for Strong, Specific Binding ORNL discovery holds potential for separations, sensors, batteries, biotech and more This sheet of graphene contains...

45

Densities and isobaric vapor-liquid equilibria for the mixtures formed by four butyl esters and 1-butanol  

SciTech Connect

Densities of 298.15 K and the vapor-liquid equilibria for 1-butanol + butyl methanoate, + butyl ethanoate, + butyl propanoate, and + butyl butanoate have been measured at 101.32 kPa in small capacity ebulliometer. All results were found to be thermodynamically consistent with a point-to-point test. The mixtures containing butyl methanoate and butyl ethanoate show azeotropes at T = 379.14 K, x = 0.871 and T = 389.64 K, x = 0.222, respectively. Different group-contribution methods were applied to these mixtures.

Gonzalez, E.; Ortega, J. [Univ. of Las Palmas de Gran Canaria (Spain)] [Univ. of Las Palmas de Gran Canaria (Spain)

1996-01-01T23:59:59.000Z

46

Solvent Effects on Metal Complexation with Crown Ethers from Liquid to Supercritical Fluids (DE-FG07-98ER 149 13)  

SciTech Connect

The purpose of this project is to study the salvation effects of metal-crown ether complexation in different solvents. It has been suggested in the literature that supercritical fluid carbon dioxide (SF-CO2) is a tunable solvent because its salvation environment can be varied with the fluid density. In this project, spectroscopic techniques including nuclear magnetic resonance (NMR) and Fourier Transform Infrared (FTIR) were used to evaluate salvation effects of metal crown complexation in organic solvents and in SF-CO2. In most solvent extraction systems, water is often involved in the extraction processes. We have carried out extensive studies of water-crown ether interactions in different solvents and in SF-CO2 using NMR and FTIR techniques. Water molecules can be attached to crown ethers through hydrogen bonding of H-0-H to the oxygen atoms of crown ether cavities. This type of interaction is like a Lewis acid-Lewis base complexation. During the course of this project, we noticed that some CO2 soluble Lewis base such as tri-n-butyl-phosphate (TBP) can also form such Lewis acid-Lewis base complexes with water and other inorganic acids including nitric acid and hydrochloric acid. Inorganic acids (e.g. nitric acid) are normally not soluble in SF-CO2. However, because TBP is highly soluble in SF-CO2, an inorganic acid bound to TBP via hydrogen bonding becomes CO2 soluble. This Lewis acid-Lewis base complex approach provides a method of introducing inorganic acids into supercritical fluid CO2 for chemical reactions.

Wai, C.M.

2002-06-01T23:59:59.000Z

47

Crown Ethers in Nonaqueous Electrolytes for Lithium/Air Batteries  

SciTech Connect

The effects of three crown ethers, 12-crown-4, 15-crown-5, and 18-crown-6, as additives and co-solvents in non-aqueous electrolytes on the cell performance of primary Li/air batteries operated in a dry air environment were investigated. Crown ethers have large effects on the discharge performance of non-aqueous electrolytes in Li/air batteries. A small amount (normally less than 10% by weight or volume in electrolytes) of 12-Crown-4 and 15-crown-5 reduces the battery performance and a minimum discharge capacity appears at the crown ether content of ca. 5% in the electrolytes. However, when the content increases to about 15%, both crown ethers improve the capacity of Li/air cells by about 28% and 16%, respectively. 15-Crown-5 based electrolytes even show a maximum discharge capacity in the crown ether content range from 10% to 15%. On the other hand, the increase of 18-crown-6 amount in the electrolytes continuously lowers of the cell performance. The different battery performances of these three crown ethers in electrolytes are explained by the combined effects from the electrolytes’ contact angle, oxygen solubility, viscosity, ionic conductivity, and the stability of complexes formed between crown ether molecules and lithium ions.

Xu, Wu; Xiao, Jie; Wang, Deyu; Zhang, Jian; Zhang, Jiguang

2010-02-04T23:59:59.000Z

48

Shear viscosity measurements in the binary mixture butyl cellosolve-water near its upper and lower critical consolute points  

E-Print Network (OSTI)

has been measured for a two-component critical liquid system, butyl cellosolve-water, in the region to report measurements of the shear viscosity of critical binary mixture butyl cello- solve (2-n353 Shear viscosity measurements in the binary mixture butyl cellosolve-water near its upper

Boyer, Edmond

49

Properties Investigation of Sulfonated Poly(ether ether ketone)/Polyacrylonitrile Acid–Base Blend Membrane for Vanadium Redox Flow Battery Application  

Science Journals Connector (OSTI)

Acid–base blend membrane prepared from sulfonated poly(ether ether ketone) (SPEEK) and polyacrylonitrile (PAN) was detailedly evaluated for vanadium redox flow battery (VRFB) application. SPEEK/PAN blend membrane exhibited dense and homogeneous cross-...

Zhaohua Li; Wenjing Dai; Lihong Yu; Le Liu; Jingyu Xi; Xinping Qiu; Liquan Chen

2014-10-15T23:59:59.000Z

50

Atmospheric and combustion chemistry of dimethyl ether  

SciTech Connect

It has been demonstrated that dimethyl ether (DME) is an ideal diesel fuel alternative. DME, CH{sub 3}OCH{sub 3}, combines good fuel properties with low exhaust emissions and low combustion noise. Large scale production of this fuel can take place using a single step catalytic process converting CH{sub 4} to DME. The fate of DME in the atmosphere has previously been studied. The atmospheric degradation is initiated by the reaction with hydroxyl radicals, which is also a common feature of combustion processes. Spectrokinetic investigations and product analysis were used to demonstrate that the intermediate oxy radical, CH{sub 3}OCH{sub 2}O, exhibits a novel reaction pathway of hydrogen atom ejection. The application of tandem mass spectrometry to chemi-ions based on supersonic molecular beam sampling has recently been demonstrated. The highly reactive ionic intermediates are sampled directly from the flame and identified by collision activation mass spectrometry and ion-molecule reactions. The mass spectrum reflects the distribution of the intermediates in the flame. The atmospheric degradation of DME as well as the unique fuel properties of a oxygen containing compound will be discussed.

Nielsen, O.J.; Egsgaard, H.; Larsen, E.; Sehested, J. [Risoe National Lab., Roskilde (Denmark); Wallington, T.J. [Ford Motor Co., Dearborn, MI (United States)

1997-12-31T23:59:59.000Z

51

Kinetic mechanism of dimethyl ether production process using syngas from integrated gasification combined cycle power plant  

Science Journals Connector (OSTI)

In a 1-step synthesis gas-to-dimethyl ether process, synthesis gas is converted into dimethyl ether (DME) in a single reactor. Three reactions are involved in this process: methanol synthesis, methanol dehydra...

Hee-Woo Park; Jin-Kuk Ha; Euy Soo Lee

2014-07-01T23:59:59.000Z

52

Hydrogen Generation from Dimethyl Ether for Fuel Cell Auxiliary Power Units  

Science Journals Connector (OSTI)

Hydrogen Generation from Dimethyl Ether for Fuel Cell Auxiliary Power Units ... Vehicle manufacturers are rushing ahead with research into alternative fuels such as dimethyl ether (DME), biodiesel, methanol, ethanol, and hydrogen. ...

Marita Nilsson; Lars J. Pettersson; Bård Lindström

2006-07-29T23:59:59.000Z

53

Effects of simulant mixed waste on EPDM and butyl rubber  

SciTech Connect

The authors have developed a Chemical Compatibility Testing Program for the evaluation of plastic packaging components which may be used in transporting mixed waste forms. In this program, they have screened 10 plastic materials in four liquid mixed waste simulants. These plastics were butadiene-acrylonitrile copolymer (Nitrile) rubber, cross-linked polyethylene, epichlorohydrin rubber, ethylene-propylene (EPDM) rubber, fluorocarbons (Viton and Kel-F{trademark}), polytetrafluoro-ethylene (Teflon), high-density polyethylene, isobutylene-isoprene copolymer (Butyl) rubber, polypropylene, and styrene-butadiene (SBR) rubber. The selected simulant mixed wastes were (1) an aqueous alkaline mixture of sodium nitrate and sodium nitrite; (2) a chlorinated hydrocarbon mixture; (3) a simulant liquid scintillation fluid; and (4) a mixture of ketones. The screening testing protocol involved exposing the respective materials to approximately 3 kGy of gamma radiation followed by 14-day exposures to the waste simulants at 60 C. The rubber materials or elastomers were tested using Vapor Transport Rate measurements while the liner materials were tested using specific gravity as a metric. The authors have developed a chemical compatibility program for the evaluation of plastic packaging components which may be incorporated in packaging for transporting mixed waste forms. From the data analyses performed to date, they have identified the thermoplastic, polychlorotrifluoroethylene, as having the greatest chemical compatibility after having been exposed to gamma radiation followed by exposure to the Hanford Tank simulant mixed waste. The most striking observation from this study was the poor performance of polytetrafluoroethylene under these conditions. In the evaluation of the two elastomeric materials they have concluded that while both materials exhibit remarkable resistance to these environmental conditions, EPDM has a greater resistance to this corrosive simulant mixed waste.

Nigrey, P.J.; Dickens, T.G.

1997-11-01T23:59:59.000Z

54

The Effect of the Di-Tertiary Butyl Peroxide (DTBP) additive on HCCI Combustion of Fuel Blends of Ethanol and Diethyl Ether  

E-Print Network (OSTI)

Ignition Using Isooctane, Ethanol and Natural Gas - AModel for High Temperature Ethanol Oxidation," Internationalof Bio-Derived Carbon from Ethanol-in-Diesel Blends in the

Mack, John Hunter; Buchholz, Bruce A; Flowers, Daniel L; Dibble, Robert W

2005-01-01T23:59:59.000Z

55

RELATIONS BETWEEN THE DETECTION OF METHYL TERT-BUTYL ETHER (MTBE) IN SURFACE AND GROUND WATER AND ITS CONTENT IN GASOLINE  

E-Print Network (OSTI)

AND ITS CONTENT IN GASOLINE By Michael J. Moran, Mike J. Halde, Rick M. Clawges and John S. Zogorski U in the United States as an octane enhancer and oxygenate in gasoline. Octane enhancement began in the late 1970's with the phase-out of tetraethyl lead from gasoline. The use of oxygenates was expanded

56

Synthesis of Medium Ring Ethers. 5. The Synthesis of (+)-Laurencin  

Science Journals Connector (OSTI)

The eight-membered medium ring ether natural product (+)-laurencin 1 is the prototypical member of a growing family of marine natural product cyclic ethers isolated from red algae and those marine organisms which feed on Laurencia species. ... The reaction mixture immediately became yellow and gradually turned dark red as gas was evolved. ... We thank the Engineering and Physical Sciences Research Council (EPSRC) UK for a research grant, Pfizer Central Research, and Corpus Christi College Cambridge for the award of a studentship and a Junior Research Fellow ship (J.W.B.), the Cambridge European Overseas Trust, Ciba (Novartis) and the Swiss Foundation for Gifted Students (scholarship to S.D.), and the Commission of the European Communities (TMR award to T.C.S.) for generous financial support. ...

Jonathan W. Burton; J. Stephen Clark; Sam Derrer; Thomas C. Stork; Justin G. Bendall; Andrew B. Holmes

1997-08-13T23:59:59.000Z

57

Dimethyl Ether Autoignition at Engine-Relevant Conditions  

Science Journals Connector (OSTI)

† Key Laboratory for Power Machinery and Engineering of M.O.E., Shanghai Jiao Tong University, Shanghai 200240, People’s Republic of China ... The autoignition of dimethyl ether (DME), an alternative diesel engine fuel, has been studied at elevated pressures. ... In addition to studies aimed at ascertaining the performance of compression–ignition internal combustion engines fuel with DME,(2, 3) there have been a number of studies focused on experimental characterization of fundamental combustion properties for DME. ...

Zhenhua Li; Weijing Wang; Zhen Huang; Matthew A. Oehlschlaeger

2013-04-01T23:59:59.000Z

58

2' and 3' Carboranyl uridines and their diethyl ether adducts  

DOE Patents (OSTI)

There is disclosed a process for preparing carboranyl uridine nucleoside compounds and their diethyl ether adducts, which exhibit a tenfold increase in boron content over prior art boron containing nucleoside compounds. Said carboranyl uridine nucleoside compounds exhibit enhanced lipophilicity and hydrophilic properties adequate to enable solvation in aqueous media for subsequent incorporation of said compounds in methods for boron neutron capture therapy in mammalian tumor cells.

Soloway, Albert H. (Worthington, OH); Barth, Rolf F. (Columbus, OH); Anisuzzaman, Abul K. (Columbus, OH); Alam, Fazlul (Anaheim, CA); Tjarks, Werner (Columbus, OH)

1992-01-01T23:59:59.000Z

59

Palladium/Tris(tert-butyl)phosphine-Catalyzed Suzuki Cross-Couplings in the Presence of Water  

E-Print Network (OSTI)

Dipalladiumtris(dibenzylideneacetone)/tris(tert-butyl)phosphonium tetrafluoroborate/potassium fluoride dihydrate [Pd2(dba)3/[HP(t-Bu)3]BF4/KF?2?H2O] serves as a mild, robust, and user-friendly method for the efficient ...

Lou, Sha

60

The interactions of water and perfluorodiethyl ether on Ru(100)  

SciTech Connect

We have studied the interactions of water and perfluorodiethyl ether on Ru(100) in order to model the effects of surface structure and humidity on the bonding and decomposition of perfluoroalkyl ether lubricants with metal surfaces. In order to understand the interactions on Ru(100), we have first investigated the interactions of each of these adsorbates alone on the clean surface. The interactions of water with Ru(100) have been studied using both thermal desorption spectroscopy (TDS) and electron energy loss spectroscopy (EELS). From these studies we conclude that a small amount of water dissociates on this surface (5--10% of a monolayer), but water is adsorbed in a predominantly molecular form on this surface with an increasing degree of hydrogen-bonding with increasing coverage. The effects of hydrogen and oxygen coadsorption on the interactions of water with this surface have also been studied using TDS. Finally, the interactions of coadsorbed water and perfluorodiethyl ether on Ru(100) have been investigated using TDS.

Leavitt, P.

1990-09-21T23:59:59.000Z

Note: This page contains sample records for the topic "butyl ether na" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Thermodynamics of Hydrogen Production from Dimethyl Ether Steam Reforming and Hydrolysis  

SciTech Connect

The thermodynamic analyses of producing a hydrogen-rich fuel-cell feed from the process of dimethyl ether (DME) steam reforming were investigated as a function of steam-to-carbon ratio (0-4), temperature (100 C-600 C), pressure (1-5 atm), and product species: acetylene, ethanol, methanol, ethylene, methyl-ethyl ether, formaldehyde, formic acid, acetone, n-propanol, ethane and isopropyl alcohol. Results of the thermodynamic processing of dimethyl ether with steam indicate the complete conversion of dimethyl ether to hydrogen, carbon monoxide and carbon dioxide for temperatures greater than 200 C and steam-to-carbon ratios greater than 1.25 at atmospheric pressure (P = 1 atm). Increasing the operating pressure was observed to shift the equilibrium toward the reactants; increasing the pressure from 1 atm to 5 atm decreased the conversion of dimethyl ether from 99.5% to 76.2%. The order of thermodynamically stable products in decreasing mole fraction was methane, ethane, isopropyl alcohol, acetone, n-propanol, ethylene, ethanol, methyl-ethyl ether and methanol--formaldehyde, formic acid, and acetylene were not observed. The optimal processing conditions for dimethyl ether steam reforming occurred at a steam-to-carbon ratio of 1.5, a pressure of 1 atm, and a temperature of 200 C. Modeling the thermodynamics of dimethyl ether hydrolysis (with methanol as the only product considered), the equilibrium conversion of dimethyl ether is limited. The equilibrium conversion was observed to increase with temperature and steam-to-carbon ratio, resulting in a maximum dimethyl ether conversion of approximately 68% at a steam-to-carbon ratio of 4.5 and a processing temperature of 600 C. Thermodynamically, dimethyl ether processed with steam can produce hydrogen-rich fuel-cell feeds--with hydrogen concentrations exceeding 70%. This substantiates dimethyl ether as a viable source of hydrogen for PEM fuel cells.

T.A. Semelsberger

2004-10-01T23:59:59.000Z

62

E-Print Network 3.0 - allyl glycidyl ether Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

Science 15 () Trichloromethane ()1,1,2,2-1,1,2,2-Tetrachloroethane Summary: ;() Acrolein () Acrylic acid () Allyl zlcohol () Allyl chloride () Allyl glycidyl ether(AGE) ()2-...

63

POLYCHLORINATED BIPHENYLS AND POLYBROMINATED DIPHENYL ETHERS IN GALAPAGOS SEA LIONS (ZALOPHUS WOLLEBAEKI)  

E-Print Network (OSTI)

), polybrominated diphenyl ethers (PBDEs), polychlorinated dibenzo-p- dioxins (PCDDs), and polychlorinated dibenzo-p-dioxins (PCDDs), and polychlorinated dibenzofurans (PCDFs) repre- sent persistent

Gobas, Frank

64

Development of a Dimethyl Ether (DME)-Fueled Shuttle Bus | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

More Documents & Publications Alternative Fuels lDimethyl Ether Rheology and Materials Studies Liquid Fuels from Biomass BiodieselFuelManagementBestPracticesReport.pdf...

65

Polybrominated diphenyl ether flame retardants in the antarctic environment  

E-Print Network (OSTI)

, the historical record of dioxins, PCBs and DDTs in the same cores showed a decreasing trend. At present, PBDEs are recognized as a worldwide pollution problem since they have reached remote areas such as the deep ocean, the Arctic and Antarctica (de Boer et al... that cheerful and warm Brazilian spirit. You are my Aggie family! viii NOMENCLATURE #1; critical value of a statistical test used to reject the null hypothesis ANOVA Analysis of Variance BDE Brominated Diphenyl Ether BFR Brominated Flame Retardant DC...

Yogui, Gilvan Takeshi

2009-05-15T23:59:59.000Z

66

Extraction of Plutonium into 30 Percent Tri-Butyl Phosphate from Nitric Acid Solution Containing Fluoride, Aluminum, and Boron  

SciTech Connect

This work consists of experimental batch extraction data for plutonium into 30 volume-percent tri-butyl phosphate at ambient temperature from such a solution matrix and a model of this data using complexation constants from the literature.

Kyser, E.A.

2000-01-06T23:59:59.000Z

67

Structure and Reactivity of Alkyl Ethers Adsorbed on CeO2(111) Model Catalysts  

SciTech Connect

The effect of surface hydroxyls on the adsorption of ether on ceria was explored. Adsorption of dimethyl ether (DME) and diethyl ether (DEE) on oxidized and reduced CeO{sub 2}(111) films was studied and compared with Ru(0001) using RAIRS and sXPS within a UHV environment. On Ru(0001) the ethers adsorb weakly with the molecular plane close to parallel to the surface plane. On the ceria films, the adsorption of the ethers was stronger than on the metal surface, presumably due to stronger interaction of the ether oxygen lone pair electrons with a cerium cation. This interaction causes the ethers to tilt away from the surface plane compared to the Ru(0001) surface. No pronounced differences were found between oxidized (CeO{sub 2}) and reduced (CeOx) films. The adsorption of the ethers was found to be perturbed by the presence of OH groups on hydroxylated CeOx. In the case of DEE, the geometry of adsorption resembles that found on Ru, and in the case of dimethyl ether DME is in between that one found on clean CeOx and the metal surface. Decomposition of the DEE was observed on the OH/CeOx surface following high DEE exposure at 300 K and higher temperatures. Ethoxides and acetates were identified as adsorbed species on the surface by means of RAIRS and ethoxides and formates by s-XPS. No decomposition of dimethyl ether was observed on the OH/CeOx at these higher temperatures, implying that the dissociation of the C-O bond from ethers requires the presence of {beta}-hydrogen.

F Calaza; T Chen; D Mullins; S Overbury

2011-12-31T23:59:59.000Z

68

Structure and Reactivity of Alkyl Ethers Adsorbed on CeO(2)(111) Model Catalysts  

SciTech Connect

The effect of surface hydroxyls on the adsorption of ether on ceria was explored. Adsorption of dimethyl ether (DME) and diethyl ether (DEE) on oxidized and reduced CeO{sub 2}(111) films was studied and compared with Ru(0001) using RAIRS and sXPS within a UHV environment. On Ru(0001) the ethers adsorb weakly with the molecular plane close to parallel to the surface plane. On the ceria films, the adsorption of the ethers was stronger than on the metal surface, presumably due to stronger interaction of the ether oxygen lone pair electrons with a cerium cation. This interaction causes the ethers to tilt away from the surface plane compared to the Ru(0001) surface. No pronounced differences were found between oxidized (CeO{sub 2}) and reduced (CeOx) films. The adsorption of the ethers was found to be perturbed by the presence of OH groups on hydroxylated CeOx. In the case of DEE, the geometry of adsorption resembles that found on Ru, and in the case of dimethyl ether DME is in between that one found on clean CeOx and the metal surface. Decomposition of the DEE was observed on the OH/CeOx surface following high DEE exposure at 300 K and higher temperatures. Ethoxides and acetates were identified as adsorbed species on the surface by means of RAIRS and ethoxides and formates by s-XPS. No decomposition of dimethyl ether was observed on the OH/CeOx at these higher temperatures, implying that the dissociation of the C-O bond from ethers requires the presence of {beta}-hydrogen.

Calaza, Florencia C [ORNL; Chen, Tsung-Liang [ORNL; Mullins, David R [ORNL; Overbury, Steven {Steve} H [ORNL

2011-01-01T23:59:59.000Z

69

Aging of Weapon Seals – An Update on Butyl O-ring Issues  

SciTech Connect

During testing under the Enhanced Surveillance Campaign in 2001, preliminary data detected a previously unknown and potentially serious concern with recently procured butyl o-rings on several programs. All butyl o-rings molded from a proprietary formulation throughout the period circa 1999 through 2001 had less than a full cure. Engineering judgment was that under curing is detrimental and could possibly lead to sub-optimum performance or, in the worst case, premature seal failure. An aging study was undertaken to ensure that suspect o-rings installed in the stockpile will retain sufficient sealing force for a minimum ten-year service life. A new prediction model developed for this study indicates suspect o-rings do not need to be replaced before the ten-year service life. Long-term testing results are reported on a yearly basis to validate the prediction model. This report documents the aging results for the period September 2002 to January 2011.

Wilson, Mark H.

2011-07-13T23:59:59.000Z

70

Reverse osmosis performance with solutions containing tri-n-butyl phosphate  

SciTech Connect

Tests were conducted to determine whether the reverse osmosis (RO) units at the F/H Effluent Treatment Facility (ETF) at the Savannah River could be made to process solutions containing tri-n-butyl phosphate (TBP). It was desired to test whether operation at a feed pH other than neutral would improve performance. Test results are discussed in this report and indicate that little improvement in the water flux can be expected at other pH values.

Siler, J.L.

1991-10-22T23:59:59.000Z

71

Batch polymerization of styrene initiated by n-butyl lithium in a cyclohexane solvent  

E-Print Network (OSTI)

anionic mechanism. A mathematical model is de- veloped and the predicted values are compared with their corresponding experimental values. Initiator and monomer concentrations are varied and their conversion time profiles are studied. A G&el... and Storage Vessels Purification of Monomer Purification of Solvent Polymerization Reaction Scavenger Level Analysis o f Butyl Lithium Analysis of Molecular Weight Distributions by the Use of Gel Permeation Technique 10 19 19 ZO Zl ZZ 24 25 25...

Landon, Thomas Rodman

1971-01-01T23:59:59.000Z

72

Decomposition of Ethanol and Dimethyl Ether During Chemical Vapour deposition Synthesis  

E-Print Network (OSTI)

1 Decomposition of Ethanol and Dimethyl Ether During Chemical Vapour deposition Synthesis of Single-phase thermal decomposition of ethanol and dimethyl ether (DME) at typical SWNT growth conditions using to the predicted decomposition mechanism. Signature peak intensities indicated concentrations of both ethanol

Maruyama, Shigeo

73

Composition and Digestibility of the Ether Extract of Hays and Fodders.  

E-Print Network (OSTI)

556-712-5m TEXAS AGRICULTURAL EXPERIMENT STATIONS. BULLETIN NO . 150 AUGUST , 1912. Division o f Chemistry TECHNICAL BULLETIN Composition and Digestibility of the Ether Extract of Hays and Fodders By G S. FRAPS and J. B. RATHER POSTOFFICE... Digestibility of the Constituents............................................................. 23 Summary and Conclusions.......................................................................29 BLANK PAGE IN ORIGINAL Composition and Digestibility of the Ether...

Fraps, G. S.; Rather, J. B.

1912-01-01T23:59:59.000Z

74

Proton-conducting polymer electrolyte membranes based on fluoropolymers incorporating perfluorovinyl ether sulfonic acids and fluoroalkenes  

E-Print Network (OSTI)

acids. A novel synthetic route describing the preparation of perfluorovinyl ether monomer containing. The radical (co) and terpolymerization of 4-[(,,-trifluorovinyl)oxy]benzene sulfonyl chloride (TFVOBSC) with 1,1-difluoroethylene (or vinylidene fluoride, VDF), hexafluoropropene (HFP), and perfluoromethyl vinyl ether (PMVE

Paris-Sud XI, Université de

75

Modelling the fate of polybrominated diphenyl ethers (PBDEs) during the municipal sewage treatment process  

Science Journals Connector (OSTI)

Sewage treatment plants (STPs) are an important source to the environment for many chemicals of concern (COCs). Polybrominated diphenyl ethers (PBDEs) are one such group of COCs of present day concern for which studies on fate and transport during the ... Keywords: chemical fate and transport, mass balance model, polybrominated diphenyl ethers, risk assessment, sewage treatment, water and wastewater management

Kerry N. McPhedran; Rajesh Seth

2007-08-01T23:59:59.000Z

76

Comb-shaped single ion conductors based on polyacrylate ethers and lithium  

NLE Websites -- All DOE Office Websites (Extended Search)

Comb-shaped single ion conductors based on polyacrylate ethers and lithium Comb-shaped single ion conductors based on polyacrylate ethers and lithium alkyl sulfonate Title Comb-shaped single ion conductors based on polyacrylate ethers and lithium alkyl sulfonate Publication Type Journal Article Year of Publication 2005 Authors Sun, Xiao-Guang, Jun Hou, and John B. Kerr Journal Electrochimica Acta Volume 50 Pagination 1139-1147 Keywords ionic conductivity, plasticizer, polyacrylate ethers, single ion conductor Abstract Comb-shaped single ion conductors have been synthesized by sulfonation of small molecule chloroethyleneglycols, which, after ion exchange to the Li+ salt were then converted to the acrylate by reaction with acryloyl chloride and copolymerized with polyethylene glycol monomethyl ether acrylate (Mn = 454, n = 8) (PAE8-co-E3SO3Li);

77

Kinetic measurements of the gas-phase reactions of OH radicals with hydroxy ethers, hydroxy ketones, and keto ethers  

SciTech Connect

Absolute rate constants were determined for the gas-phase reactions of hydroxyl radicals with a series of hydroxy ethers as well as the simplest hydroxy ketone and keto ether with use of the flash photolysis resonance fluorescence technique. At 298 K, the measured rate constants were as follows (in units of 10{sup {minus}12} cm{sup 3} molecule{sup {minus}1} s{sup {minus}1}): 2-methoxyethanol, 12.5 {plus minus} 0.7; 2-ethoxyethanol, 18.7 {plus minus} 2.0; 2-butoxyethanol, 23.1 {plus minus} 0.9; 3-ethoxy-1-propanol, 22.0 {plus minus} 1.3; 3-methoxy-l-butanol, 23.6 {plus minus} 1.6; acetol, 3.0 {plus minus} 0.3; and methoxyacetone, 6.8 {plus minus} 0.6. The kinetic data for 2-methoxyethanol obtained between 240 and 440 K were used to derive the following Arrhenius expression: k{sub 1} = (4.5 {plus minus} 1.4) {times} 10{sup {minus}12} exp((325 {plus minus} 100)/T) (cm{sup 3} molecule{sup {minus}1} s{sup {minus}1}). The results for all seven reactants are discussed in terms of the prediction of OH rate constants for oxygenated organic compounds.

Dagaut, P.; Liu, R.; Wallington, T.J.; Kurylo, M.J. (National Institute of Standards and Technology, Gaithersburg, MD (USA))

1989-11-16T23:59:59.000Z

78

Test of Orientation/Stretch-Induced Reduction of Friction via Primitive Chain Network Simulations for Polystyrene, Polyisoprene, and Poly(n-butyl acrylate)  

Science Journals Connector (OSTI)

Test of Orientation/Stretch-Induced Reduction of Friction via Primitive Chain Network Simulations for Polystyrene, Polyisoprene, and Poly(n-butyl acrylate) ...

Yuichi Masubuchi; Yumi Matsumiya; Hiroshi Watanabe

2014-09-24T23:59:59.000Z

79

Synthesis and Evaluation of 3',5'-Di-tert-butyl-4'-hydroxyflavones as Potential Inhibitors of Low Density Lipoprotein (LDL) Oxidation  

Science Journals Connector (OSTI)

Synthesis and Evaluation of 3',5'-Di-tert-butyl-4'-hydroxyflavones as Potential Inhibitors of Low Density Lipoprotein (LDL) Oxidation ...

Guy Lewin; Yves Rolland; Sylvie Privat; Christine Breugnot; Albert Lenaers; Jean Paul Vilaine; Jean-Pierre Baltaze; Jacques Poisson

1995-12-01T23:59:59.000Z

80

Batch polymerization of styrene and isoprene by n-butyl lithium initiator  

E-Print Network (OSTI)

-20). Analysis of products consists of determining the point at which no free lithium alkyl remains. Thus if a butyl lithium initiated polymerization were terminated with water, butane would be evolved as long as the initiator were present. The butane...? agent were evaporated under a hood. Finally the polymer. was dried in a vacuum oven at about 50'C and under a vacuum of 30 inches of gg for about 30 hours. The weight of polymer formed was determined by final weighing. 25 The monomer conversion...

Hasan, Sayeed

1970-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "butyl ether na" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Isobaric vapor-liquid equilibria in the system methyl propanoate + n-butyl alcohol  

SciTech Connect

Isobaric vapor-liquid equilibria were determined at 74.66, 101.32, and 127.99 kPa for binary mixtures containing methyl propanoate + n-butyl alcohol by using a dynamic still with vapor and liquid circulation. No azeotrope was detected. The data were found to be thermodynamically consistent according to the point to point test. Application of the group-contribution models ASOG, UNIFAC, and modified UNIFAC to the activity coefficients at the three pressures studied gives average errors of less than 10%, 11%, and 3%, respectively.

Susial, P.; Ortega, J. (Univ. de Las Palmas de Gran Canaria, Canary Islands (Spain). Lab. de Termodinamica y Fisicoquimica)

1993-10-01T23:59:59.000Z

82

E-Print Network 3.0 - acid-labile cholesterol-vinyl ether-peg...  

NLE Websites -- All DOE Office Websites (Extended Search)

Crystallization of Recombinant Crithidia fasciculata Tryparedoxin Summary: of 30% polyethylene glycol monomethyl ether (PEG MME) 2000, 0.1 M TrisHCl, pH 8.2, 1% dimethyl Source:...

83

Polybrominated diphenyl ethers in combusted residues and soils from an open burning site of electronic wastes  

Science Journals Connector (OSTI)

Polybrominated diphenyl ethers (PBDEs) are ubiquitous environmental contaminants due to their extensive use. Combusted residue from electronic waste (e-waste) combustion is one of the contamination sources ... tr...

Qian Luo; Ming Hong Wong; Zijian Wang; Zongwei Cai

2013-08-01T23:59:59.000Z

84

Solvent Effects on Cesium Complexation with Crown Ethers from Liquid to Supercritical Fluids  

SciTech Connect

Nuclear magnetic resonance (NMR) techniques were used to study crown ether-water interactions in solvents of low dielectric constants such as chloroform and carbon tetrachloride. Water forms a 1:1 complex with a number of crown ethers including 12-crown-4, 15-crown-5, 18-crown-6, dicyclohexano-18=crown-6, dicyclohexano-24-crown 8, and dibenzl-24-crown-8 in chloroform. Among these crown ethers, the 18-crown-6-H2 complex has the largest equilibrium constant (K=545) and 97% of the crown is complexed to water in chloroform. Addition of carbon tetrachloride to chloroform lowers the equilibrium constants of the crown-water complexes. The partition coefficients of crown ethers (D=crown in water/crown in solvent) between water and organic solvent also vary with solvent composition.

Chien M. Wai; Anne Rustenholtz; Shaofen Wang; Su-Chen Lee; Jamie Herman; Richard A. Porter

2004-03-15T23:59:59.000Z

85

Atmospheric chemistry of automotive fuel additives: Diisopropyl ether  

SciTech Connect

To quantify the atmospheric reactivity of diisopropyl ether (DIPE), we have conducted a study of the kinetics and mechanism of reaction 1: OH + DIPE {r_arrow} products. Kinetic measurements of reaction 1 were made using both relative (at 295 K) and absolute techniques (over the temperature range 240-440 K). Rate data from both techniques can be represented by the following: k{sub 1} = (2.2{sub -0.8}{sup +14}) x 10{sup -12} exp[(445 {plus_minus} 145)/T] cm{sup 3} molecule{sup -1}s{sup -1}. At 298 K, k{sub 1} = 9.8 x 10{sup -12} cm{sup 3} molecule{sup -1}s{sup -1}. The products of the simulated atmospheric oxidation of DIPE were identified using FT-IR spectroscopy; isopropyl acetate and HCHO were the main products. The atmospheric oxidation of DIPE can be represented by i-C{sub 3}H{sub 7}O-i-C{sub 3}H{sub 7} + OH + 2NO {r_arrow} HCHO + i-C{sub 3}H{sub 7}OC(O)CH{sub 3} + HO{sub 2} + 2NO{sub 2}. Our kinetic and mechanistic data were incorporated into a 1-day simulation of atmospheric chemistry to quantify the relative incremental reactivity of DIPE. Results are compared with other oxygenated fuel additives. 30 refs., 9 figs.

Wallington, T.J.; Andino, J.M.; Potts, A.R. [Ford Motor Company, Dearborn, MI (United States)] [and others

1993-01-01T23:59:59.000Z

86

Nonlinear viscoelastic response of carbon black-filled butyl rubber and implications for o-ring aging  

SciTech Connect

Butyl rubber, unfortunately, has pronounced nonlinear viscoelastic behavior, which may be modelled by a separable KBKZ formalism. While these effects seem to have minimal impact on accelerated sealing force measurements, they do severely impact compression set tests. Therefore, a new test is suggested for evaluating field-return o-rings which is free from such confounding effects.

Adolf, D.

1997-11-01T23:59:59.000Z

87

Rate dependent finite deformation stressstrain behavior of an ethylene methacrylic acid copolymer and an ethylene methacrylic acid butyl  

E-Print Network (OSTI)

Rate dependent finite deformation stress­strain behavior of an ethylene methacrylic acid copolymer and an ethylene methacrylic acid butyl acrylate copolymer S. Deschanel a,*, B.P. Greviskes a , K. Bertoldi a , S dependence a b s t r a c t The large strain deformation behaviors of an ethylene methacrylic acid (EMAA

88

Liquid phase oxidation of thiophene compounds by tert-butyl hydroperoxide  

SciTech Connect

Oxidative instability problems in both shale and petroleum-derived middle distillate fuels are related to the presence of hydroperoxides. Although a good body of knowledge exists concerning the formation of peroxides in the liquid phase, relatively little is known about the reaction/decomposition pathways when other functional groups are present. One of the significant and undesirable problems is the formation of solid deposits which can plug nozzles and filters and coal heat exchanger surfaces. Deposit formation in fuels is triggered by autoxidation reactions and is closely associated with elemental oxygen and/or hydroperoxide concentration. This paper reports on the reaction between a primary autoxidation product, a hydroperoxide, and sulfur compounds of the type present in petroleum-derived middle distillate fuels. Specifically, we examine the t-butyl hydroperoxide oxidation of thiophene, 2, 5-dimethylthiophene, tetrahydrothiophene and benzothiophene in a deaerated model fuel, tetradecane, at 120{degree}C.

Mushrush, G.W.; Watkins, J.M. Jr.; Hazlett, R.N.; Hardy, D.R.; Eaton, H.G. (Naval Research Laboratory, Washington, DC (USA))

1987-08-01T23:59:59.000Z

89

Fuel instability studies; Liquid phase oxidation of tetrahydrothiophene by tert-butyl hydroperoxide  

SciTech Connect

The reactions that lead to fuel instability are the subject of conflicting reports in the literature. Confusion results from the difficulty in relating differences in fuel composition, temperature, surface effects and dissolved oxygen content that comprise the multitude of reported studies. Model studies offer a means by chic the mechanism of an individual reaction can be related to a simple system and then extended to the more complex fuel media. This paper reports a model oxidation study of a species, t-butyl hydroperoxide under mild reaction conditions, 120{degrees}C, in a tetradecane model fuel. The major oxidation product was tetrahydrothiophene sulfoxide from the sulfide and t-butanol from the hydroperoxide. The complete suite of products is reported.

Mushrush, G.W.; Pellenbarg, R.E.; Hazlett, R.N.; Morris, R.E.; Hardy, D.R. (Fuels Section, Code 6180, Naval Research Lab., Washington, DC (US))

1991-01-01T23:59:59.000Z

90

Tests for mutagenic effects of ammoniated glycyrrhizin, butylated hydroxytoluene, and gum arabic in roden germ cells  

SciTech Connect

Ammoniated glycyrrhizin, butylated hydroxytoluene, and gum Arabic are generally recognized as safe (GRAS) substances that are used primarily as additives in foods. These substances were incorporated into rodent diets and fed to male rats and mice for 10 and 8 wk, respectively. The treated male mice and rats were then tested for dominant lethal effects. The mice were also tested for induced heritable translocation. Results of the rat studies indicated a statistically significant dominant lethal effect of each of the compounds tested; however, the biological significance of this response is not known. Results of the mouse dominant lethal and heritable translocation studies, on the other hand, indicated no adverse effects of the compounds tested.

Sheu, C.W.; Cain, K.T.; Rushbrook, C.J.; Jorgenson, T.A.; Generoso, W.M.

1986-01-01T23:59:59.000Z

91

Butyl rubber O-ring seals: Revision of test procedures for stockpile materials  

SciTech Connect

Extensive testing showed little correlation between test slab and O-ring performance. New procedures, comparable to those used with the traditional test slabs, were defined for hardness, compression set, and tensile property testing on sacrificial O-ring specimens. Changes in target performance values were made as needed and were, in one case, tightened to reflect the O-ring performance data. An additional study was carried out on O-ring and slab performance vs cure cycle and showed little sensitivity of material performance to large changes in curing time. Aging and spectra of certain materials indicated that two sets of test slabs from current vendor were accidently made from EPDM rather than butyl rubber. Random testing found no O-rings made from EPDM. As a result, and additional spectroscope test will be added to the product acceptance procedures to verify the type of rubber compound used.

Domeier, L.A.; Wagter, K.R.

1996-12-01T23:59:59.000Z

92

Initiation Temperature for Runaway Tri-n-Butyl Phosphate/Nitric Acid Reaction  

SciTech Connect

In a review of the safety basis for solvent extraction processes at the Department of Energy's Savannah River Site, a question was raised concerning the safety margin associated with a postulated accident involving a runaway tri-n-butyl phosphate (TBP)/nitric acid reaction due to the inadvertent heating of a tank. The safety margin was based on studies which showed the maximum temperature would not exceed 128 degrees Celsius compared to 130 degrees Celsius, the minimum initiation temperature for runaway reaction established in the 1950's following damaging incidents at the Savannah River and Hanford Sites. The reviewers were concerned the minimum temperature was not conservative since data for solutions containing 20 wt percent dissolved solids showed initiation temperatures at or below 130 degrees Celsius and process solutions normally contain some dissolved solids.

Rudisill, T.S.

2001-09-14T23:59:59.000Z

93

DIMETHYL ETHER (DME)-FUELED SHUTTLE BUS DEMONSTRATION PROJECT  

SciTech Connect

The objectives of this research and demonstration program are to convert a campus shuttle bus to operation on dimethyl ether, a potential ultra-clean alternative diesel fuel. To accomplish this objective, this project includes laboratory evaluation of a fuel conversion strategy, as well as, field demonstration of the DME-fueled shuttle bus. Since DME is a fuel with no lubricity (i.e., it does not possess the lubricating quality of diesel fuel), conventional fuel delivery and fuel injection systems are not compatible with dimethyl ether. Therefore, to operate a diesel engine on DME one must develop a fuel-tolerant injection system, or find a way to provide the necessary lubricity to the DME. In this project, they have chosen the latter strategy in order to achieve the objective with minimal need to modify the engine. Their strategy is to blend DME with diesel fuel, to obtain the necessary lubricity to protect the fuel injection system and to achieve low emissions. The bulk of the efforts over the past year were focused on the conversion of the campus shuttle bus. This process, started in August 2001, took until April 2002 to complete. The process culminated in an event to celebrate the launching of the shuttle bus on DME-diesel operation on April 19, 2002. The design of the system on the shuttle bus was patterned after the system developed in the engine laboratory, but also was subjected to a rigorous failure modes effects analysis (FMEA, referred to by Air Products as a ''HAZOP'' analysis) with help from Dr. James Hansel of Air Products. The result of this FMEA was the addition of layers of redundancy and over-pressure protection to the system on the shuttle bus. The system became operational in February 2002. Preliminary emissions tests and basic operation of the shuttle bus took place at the Pennsylvania Transportation Institute's test track facility near the University Park airport. After modification and optimization of the system on the bus, operation on the campus shuttle route began in early June 2002. However, the work and challenges continued as it has been difficult to maintain operability of the shuttle bus due to fuel and component difficulties. In late June 2002, the pump head itself developed operational problems (loss of smooth function) leading to excessive stress on the magnetic coupling and excessive current draw to operate. A new pump head was installed on the system to alleviate this problem and the shuttle bus operated successfully on DME blends from 10-25 vol% on the shuttle bus loop until September 30, 2002. During the period of operation on the campus loop, the bus was pulled from service, operated at the PTI test track and real-time emissions measurements were obtained using an on-board emissions analyzer from Clean Air Technologies International, Inc. Particulate emissions reductions of 60% and 80% were observed at DME blend ratios of 12 vol.% and 25 vol.%, respectively, as the bus was operated over the Orange County driving cycle. Increases in NOx, CO and HC emissions were observed, however. In summary, the conversion of the shuttle bus was successfully accomplished, particulate emissions reductions were observed, but there were operational challenges in the field. Nonetheless, they were able to demonstrate reliable operation of the shuttle bus on DME-diesel blends.

Elana M. Chapman; Shirish Bhide; Jennifer Stefanik; Howard Glunt; Andre L. Boehman; Allen Homan; David Klinikowski

2003-04-01T23:59:59.000Z

94

Ab initio calculations of various protonation sites in perfluorodiethyl ether: Models for high temperature lubricant decomposition?  

SciTech Connect

Although perfluoropolyether (PFPE) lubricants have found successful application in spacecraft mechanisms and computer hard drives, there eventual breakdown is irksome, and the mechanism of decomposition is the subject of much scrutiny. However, very little notice is taken of the monomer ethers on which the polymer lubricants are based. Recently, concerted studies of the Lewis base properties of various fluorinated ethers have been performed, both from an experimental and a theoretical viewpoint. As an extension of the theoretical work, this study presents ab initio theoretical consideration of the multiple potential basic sites within perfluorodiethyl ether, (CF{sub 3}CF{sub 2}){sub 2}O, by way of the proton affinity of the molecule at various possible protonation sites (i.e., oxygen and fluorine atoms). The results indicate that although protonation at the oxygen is more energetically favored, protonation at the fluorine is not much higher in energy and provides for formation of an excellent leaving group, HF.

Ball, D.W. [Cleveland State Univ., OH (United States). Dept. of Chemistry

1995-04-01T23:59:59.000Z

95

Catalyst system and process for benzyl ether fragmentation and coal liquefaction  

DOE Patents (OSTI)

Dibenzyl ether can be readily cleaved to form primarily benzaldehyde and toluene as products, along with minor amounts of bibenzyl and benzyl benzoate, in the presence of a catalyst system comprising a Group 6 metal, preferably molybdenum, a salt, and an organic halide. Although useful synthetically for the cleavage of benzyl ethers, this cleavage also represents a key model reaction for the liquefaction of coal; thus this catalyst system and process should be useful in coal liquefaction with the advantage of operating at significantly lower temperatures and pressures.

Zoeller, Joseph Robert (Kingsport, TN)

1998-04-28T23:59:59.000Z

96

The Total Fatty Acids and Other Ether-Soluable Constituents of Feedstuffs.  

E-Print Network (OSTI)

586-914-10m TEXAS AGRICULTURAL EXPERIMENT STATION BULLETIN NO. 169 SEPTEMBER, 19I4 DIVISION OF CHEMISTRY The Total Fatty Acids and Other Ether-Soluble Constituents of Feedstuffs BY J. B. RATHER Assistant Chemist POSTOFFICE COLLEGE STATION... IS T .* In previous publications of this Experiment Station (Fraps and Bather, Bulletins Nos. 150 and 162) it has been shown that the un? saponifiable matter in the ether extract of hays and fodders averages about 58 per cent. Of the total extract, and is of much...

Rather, J. B. (James Burness)

1914-01-01T23:59:59.000Z

97

Toxicity of polychlorinated diphenyl ethers in Hydra attenuata and in rat whole embryo culture  

E-Print Network (OSTI)

TOXICITY OF POLYCHLORINATED DIPHENYL ETHERS IN HYDRA A?TENUATA AND IN RAT WHOLE EMBRYO CULTURE A Thesis by MARION CAROL BECKER Submitted to the Office of Graduate Studies of Texas A8cM University in partial fulfillment of the requirements... for the degree of MASTER OF SCIENCE May 1991 Major Subject: Toxicology TOXICITY OF POLYCHLORINATED DIPHENYL ETHERS IN HYDRA A1TENUATA AND IN RAT WHOLE EMBRYO CULTURE by MARION CAROL BECKER Approved as to style and content by: Stephen H. S (Ca...

Becker, Marion Carol

2012-06-07T23:59:59.000Z

98

Hydrolysis of cellulose to produce glucose with solid acid catalysts in 1-butyl-3-methyl-imidazolium chloride ([bmIm][Cl]) with sequential water addition  

Science Journals Connector (OSTI)

Selective glucose production by cellulose hydrolysis with initial or sequential water addition in the presence of solid acid catalysts in 1-butyl-3-methyl-imidazolium chloride ([bmIm][Cl]) under microwave irra...

Kaori Ishida; Shiho Matsuda; Masaru Watanabe…

2014-12-01T23:59:59.000Z

99

Anhydrous aluminum chloride as an alkylation catalyst: identification of mono- and dialkyl-benzenes from the condensation of tertiary butyl alcohol with benzene.  

E-Print Network (OSTI)

LIBRARY a a w c"I. I. SI - O~ TI:YAf ANHYDROUS ALUMINUM CHLORIDE AS AN ALKYLATION CATALYST: IDENTIFICATION OF MONO- AND DIALKYIZENZENES FROM THE CONDENSATION QF TERTIARY BUTYL ALCOHOL WITH BENKENE IACEY EUGENE SCOGGINS 4 A Thesis Submitted...: IDENTIFICATION OF MONO- AND DI~NZZNES FROM THE CONDENSATION OF TERTIARY BUTYL ALCOHOL WITH BENZENE A Thesis By LACEY EUGENE SCOGGINS Approved as to style and content hy: Chairman of Committee Head of Chemistry Department 1959 ACKNOWLEDGME1VTS The author...

Scoggins, Lacey E

1959-01-01T23:59:59.000Z

100

Initiation Temperature for Runaway Tri-n-Butyl Phosphate/Nitric Acid Reaction  

SciTech Connect

During a review of the H-Canyon authorization basis, Defense Nuclear Facility Safety Board (DNFSB) staff members questioned the margin of safety associated with a postulated tri-n-butyl phosphate (TBP)/nitric acid runaway reaction due to the inadvertent heating of a canyon tank containing greater than 3000 lbs (1362 kg) of TBP. The margin of safety was partially based on experiments and calculations performed by the Actinide Technology Section (ATS) to support deletion of indication of tank agitation as a Safety Class System. In the technical basis for deletion of this system, ATS personnel conservatively calculated the equilibrium temperature distribution of a canyon tank containing TBP and nitric acid layers which were inadvertently heated by a steam jet left on following a transfer. The maximum calculated temperature (128 degrees C) was compared to the minimum initiation temperature for a runaway reaction (greater than 130 degrees C) documented by experimental work in the mid 195 0s. In this work, the initiation temperature as a function of nitric acid concentration was measured for 0 and 20 wt percent dissolved solids. The DNFSB staff members were concerned that data for 0 wt percent dissolved solids were not conservative given the facts that data for 20 wt percent dissolved solids show initiation temperatures at or below 130 degrees C and H-Canyon solutions normally contained a small amount of dissolved solids.

Rudisill, T.S.

2000-11-28T23:59:59.000Z

Note: This page contains sample records for the topic "butyl ether na" from the National Library of EnergyBeta (NLEBeta).
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they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Thorium ions transport across Tri-n-butyl phosphate-benzene based supported liquid membranes  

SciTech Connect

Transport of Th(IV) ions across tri-n-butyl phosphate (TBP) benzene based liquid membranes supported in microporous hydrophobic polypropylene film (MHPF) has been studied. Various parameters such as variation of nitric acid concentration in the feed, TBP concentration in the membrane, and temperature on the given metal ions transport have been investigated. The effects of nitric acid and TBP concentrations on the distribution coefficient were also studied, and the data obtained were used to determine the Th ions-TBP complex diffusion coefficient in the membrane. Permeability coefficients of Th(IV) ions were also determined as a function of the TBP and nitric acid concentrations. The optimal conditions for the transport of Th(IV) ions across the membrane are 6 mol{sm_bullet}dm{sup -3} HNO{sub 3} concentration, 2.188 mol {center_dot} dm{sup -3} TBP concentration, and 25{degrees}C. The stoichiometry of the chemical species involved in chemical reaction during the transport of Th(IV) ions has also been studied.

Rasul, G.; Chaudry, M.A. [Pakistan Institute of Nuclear Chemistry, Islamabad (Pakistan); Afzal, M. [Quaid-I-Azam Univ., Islamabad (Pakistan)

1995-12-01T23:59:59.000Z

102

Dimethyl ether (DME) from coal as a household cooking fuel in China  

E-Print Network (OSTI)

technologies. Given China's rich coal resources, the production and use of coal-derived DME as a cooking fuelDimethyl ether (DME) from coal as a household cooking fuel in China Eric D. Larson Princeton gas (LPG) as a household cooking fuel. As such, DME is an attractive fuel for clean cooking. DME can

103

Nuclear magnetic relaxation dispersion investigations1 of water retention mechanism by cellulose ethers in mortars2  

E-Print Network (OSTI)

Nuclear magnetic relaxation dispersion investigations1 of water retention mechanism by cellulose : 10.1016/j.cemconres.2012.06.002 #12;2 ABSTRACT22 23 We show how nuclear magnetic spin-lattice relaxation dispersion of protons-water24 (NMRD) can be used to elucidate the effect of cellulose ethers

Boyer, Edmond

104

The influence of propylene glycol ethers on base diesel properties and emissions from a diesel engine  

Science Journals Connector (OSTI)

Abstract The oxygenated additives propylene glycol methyl ether (PGME), propylene glycol ethyl ether (PGEE), dipropylene glycol methyl ether (DPGME) were studied to determine their influence on both the base diesel fuel properties and the exhaust emissions from a diesel engine (CO, NOx, unburnt hydrocarbons and smoke). For diesel blends with low oxygen content (?4.0 wt.%), the addition of these compounds to base diesel fuel decreases aromatic content, kinematic viscosity, cold filter plugging point and Conradson carbon residue. Also, each compound modifies the distillation curve at temperatures below the corresponding oxygenated compound boiling point, the distillate percentage being increased. The blend cetane number depends on the type of propylene glycol ether added, its molecular weight, and the oxygen content of the fuel. The addition of PGME decreased slightly diesel fuel cetane number, while PGEE and DPGME increased it. Base diesel fuel-propylene glycol ether blends with 1.0 and 2.5 wt.% oxygen contents were used in order to determine the performance of the diesel engine and its emissions at both full and medium loads and different engine speeds (1000, 2500 and 4000 rpm). In general, at full load and in comparison with base diesel fuel, the blends show a slight reduction of oxygen-free specific fuel consumption. CO emissions are reduced appreciably for 2.5 wt.% of oxygen blends, mainly for PGEE and DPGME. \\{NOx\\} emissions are reduced slightly, but not the smoke. Unburnt hydrocarbon emissions decrease at 1000 and 2500 rpm, but not at 4000 rpm. At medium load, the effect of the additives is much less significant, due to the fact that the ratio oxygen from additive/oxygen from air is much lower.

F. Gómez-Cuenca; M. Gómez-Marín; M.B. Folgueras-Díaz

2013-01-01T23:59:59.000Z

105

Linking Low-Level Stable Isotope Fractionation to Expression of the Cytochrome P450 Monooxygenase-Encoding ethB Gene for Elucidation of Methyl tert-Butyl Ether Biodegradation in Aerated Treatment Pond Systems  

Science Journals Connector (OSTI)

...application of CSIA in field investigations to detect biodegradation...52). An alternative remedial strategy could be the use...application of CSIA in field investigations to detect biodegradation may lead to...application of CSIA in field investigations to detect biodegradation...

Sven Jechalke; Mònica Rosell; Paula M. Martínez-Lavanchy; Paola Pérez-Leiva; Thore Rohwerder; Carsten Vogt; Hans H. Richnow

2010-12-10T23:59:59.000Z

106

MTBE Production Economics (Released in the STEO April 2001)  

Reports and Publications (EIA)

The purpose of this analysis is to evaluate the causes of methyl tertiary butyl ether (MTBE) price increases in 2000.

2001-01-01T23:59:59.000Z

107

Kinetics of liquid phase catalytic dehydration of methanol to dimethyl ether  

SciTech Connect

This paper reports the kinetics of the liquid phase catalytic dehydration of methanol to dimethyl ether investigated. The experiments were carried out under low concentrations of feed in a 1-L stirred autoclave, according to a statistical experimental design. The inert liquid phase used for this investigation was a 78:22 blend of paraffinic and naphthenic mineral oils. A complete thermodynamic analysis was carried out in order to determine the liquid phase concentrations of the dissolved species. A global kinetic model was developed for the rate of dimethyl ether synthesis in terms of the liquid phase concentration of methanol. The activation energy of the reaction was found to be 18,830 cal/gmol. Based on a step-wise linear regression analysis of the kinetic data, the order of the reaction which gave the best fit was 0.28 with respect to methanol.

Gogate, M.R.; Lee, B.G.; Lee, S. (Akron Univ., OH (USA). Dept. of Chemical Engineering); Kulik, C.J. (Electric Power Research Inst., Palo Alto, CA (USA))

1990-01-01T23:59:59.000Z

108

Process to convert biomass and refuse derived fuel to ethers and/or alcohols  

DOE Patents (OSTI)

A process is described for conversion of a feedstock selected from the group consisting of biomass and refuse derived fuel (RDF) to provide reformulated gasoline components comprising a substantial amount of materials selected from the group consisting of ethers, alcohols, or mixtures thereof, comprising: drying said feedstock; subjecting said dried feedstock to fast pyrolysis using a vortex reactor or other means; catalytically cracking vapors resulting from said pyrolysis using a zeolite catalyst; condensing any aromatic byproduct fraction; catalytically alkylating any benzene present in said vapors after condensation; catalytically oligomerizing any remaining ethylene and propylene to higher olefins; isomerizing said olefins to reactive iso-olefins; and catalytically reacting said iso-olefins with an alcohol to form ethers or with water to form alcohols. 35 figs.

Diebold, J.P.; Scahill, J.W.; Chum, H.L.; Evans, R.J.; Rejai, B.; Bain, R.L.; Overend, R.P.

1996-04-02T23:59:59.000Z

109

Process to convert biomass and refuse derived fuel to ethers and/or alcohols  

DOE Patents (OSTI)

A process for conversion of a feedstock selected from the group consisting of biomass and refuse derived fuel (RDF) to provide reformulated gasoline components comprising a substantial amount of materials selected from the group consisting of ethers, alcohols, or mixtures thereof, comprising: drying said feedstock; subjecting said dried feedstock to fast pyrolysis using a vortex reactor or other means; catalytically cracking vapors resulting from said pyrolysis using a zeolite catalyst; condensing any aromatic byproduct fraction; catalytically alkylating any benzene present in said vapors after condensation; catalytically oligomerizing any remaining ethylene and propylene to higher olefins; isomerizing said olefins to reactive iso-olefins; and catalytically reacting said iso-olefins with an alcohol to form ethers or with water to form alcohols.

Diebold, James P. (Lakewood, CO); Scahill, John W. (Evergreen, CO); Chum, Helena L. (Arvada, CO); Evans, Robert J. (Lakewood, CO); Rejai, Bahman (Lakewood, CO); Bain, Richard L. (Golden, CO); Overend, Ralph P. (Lakewood, CO)

1996-01-01T23:59:59.000Z

110

Soluble, Infrared-Absorbing Croconate Dyes from 2,6-Di-tert-butyl-4-methylchalcogenopyrylium Salts  

Science Journals Connector (OSTI)

1 Although many squarylium dyes have limited solubility in organic solvents or in coated organic films, squarylium dyes 1 (Chart 1) derived from 2,6-di-tert-butyl-4-methylchalcogenopyrylium salts (2)3 are soluble and have been coated in organic thin films for a variety of applications. ... The croconates are readily prepared, are soluble in organic solvents, and have absorption maxima that cover a broad range of laser emission lines from gallium?arsenide diode lasers (?820 nm) to the neodinium-YAG laser (1064 nm). ... The reaction mixture was poured into water (50 mL), and the product was extracted with hexanes (3 × 25 mL). ...

Todd P. Simard; Jian H. Yu; Jennifer M. Zebrowski-Young; Neil F. Haley; Michael R. Detty

2000-03-03T23:59:59.000Z

111

Molecular modeling of the morphology and transport properties of two direct methanol fuel cell membranes: phenylated sulfonated poly(ether ether ketone ketone) versus Nafion  

SciTech Connect

We have used molecular dynamics simulations to examine membrane morphology and the transport of water, methanol and hydronium in phenylated sulfonated poly ether ether ketone ketone (Ph-SPEEKK) and Nafion membranes at 360 K for a range of hydration levels. At comparable hydration levels, the pore diameter is smaller, the sulfonate groups are more closely packed, the hydronium ions are more strongly bound to sulfonate groups, and the diffusion of water and hydronium is slower in Ph-SPEEKK relative to the corresponding properties in Nafion. The aromatic carbon backbone of Ph-SPEEKK is less hydrophobic than the fluorocarbon backbone of Nafion. Water network percolation occurs at a hydration level ({lambda}) of {approx}8 H{sub 2}O/SO{sub 3}{sup -}. At {lambda} = 20, water, methanol and hydronium diffusion coefficients were 1.4 x 10{sup -5}, 0.6 x 10{sup -5} and 0.2 x 10{sup -5} cm{sup 2}/s, respectively. The pore network in Ph-SPEEKK evolves dynamically and develops wide pores for {lambda} > 20, which leads to a jump in methanol crossover and ion transport. This study demonstrates the potential of aromatic membranes as low-cost challengers to Nafion for direct methanol fuel cell applications and the need to develop innovative strategies to combat methanol crossover at high hydration levels.

Devanathan, Ramaswami; Idupulapati, Nagesh B.; Dupuis, Michel

2012-08-14T23:59:59.000Z

112

2[prime] and 3[prime] Carboranyl uridines and their diethyl ether adducts  

DOE Patents (OSTI)

A process is described for preparing carboranyl uridine nucleoside compounds and their diethyl ether adducts, which exhibit a tenfold increase in boron content over prior art boron containing nucleoside compounds. The carboranyl uridine nucleoside compounds exhibit enhanced lipophilicity and hydrophilic properties adequate to enable solvation in aqueous media for subsequent incorporation of the compounds in methods for boron neutron capture therapy in mammalian tumor cells. No Drawings

Soloway, A.H.; Barth, R.F.; Anisuzzaman, A.K.; Alam, F.; Tjarks, W.

1992-12-15T23:59:59.000Z

113

Effect of solvents on the radiation-induced polymerization of ethyl and isopropyl vinyl ethers  

SciTech Connect

The effect of solvents on the radiation-induced cationic polymerization of ethyl and isopropyl vinyl ethers (EVE and IPVE, respectively) was investigated. EVE and IPVE polymerizations were carried out in bulk and in solution under superdry conditions in which polar impurities, especially water, have been reduced to negligible levels. This was accomplished by means of a sodium mirror technique using joint free baked out glass equipment and high vacuum. Plots of the monomer conversions and irradiation times were obtained for EVE and IPVE polymerizations in bulk and in benzene solution at constant monomer concentrations. The monomer concentration dependence of the polymerization rate was studied for EVE polymerization in bulk and in benzene, diethlyl ether, diglyme and methylene chloride, and for IPVE polymerization in bulk and in benzene. Solvent effect on the estimated propagating rate constants was examined for EVE and IPVE polymerization in bulk and in solution. The effect of temperature on the polymerization rate was also investigated for EVE polymerization in bulk ad in benzene, diethyl and diisopropyl ethers, methylene chloride and nitromethane, and for IPVE ploymerization in bulk and in benzene.

Hsieh, W.C.

1981-01-01T23:59:59.000Z

114

Report from NA49  

E-Print Network (OSTI)

The signatures of the onset of deconfinement, found by the NA49 experiment at low SPS energies, are confronted with new results from the Beam Energy Scan (BES) program at BNL RHIC and CERN LHC results. Additionally, new NA49 results on chemical (particle ratio) fluctuations, azimuthal angle fluctuations, intermittency of di-pions, etc. are presented.

Katarzyna Grebieszkow; for the NA49 Collaboration

2011-12-04T23:59:59.000Z

115

A laser and molecular beam mass spectrometer study of low-pressure dimethyl ether flames  

SciTech Connect

The oxidation of dimethyl ether (DME) is studied in low-pressure flames using new molecular beam mass spectrometer and laser diagnostics. Two 30.0-Torr, premixed DME/oxygen/argon flames are investigated with stoichiometries of 0.98 and 1.20. The height above burner profiles of nine stable species and two radicals are measured. These results are compared to the detailed chemical reaction mechanism of Curran and coworkers. Generally good agreement is found between the model and data. The largest discrepancies are found for the methyl radical profiles where the model predicts qualitatively different trends in the methyl concentration with stoichiometry than observed in the experiment.

Andrew McIlroy; Toby D. Hain; Hope A. Michelsen; Terrill A. Cool

2000-12-15T23:59:59.000Z

116

High octane ethers from synthesis gas-derived alcohols. Quarterly technical progress report, April--June 1993  

SciTech Connect

The results shown in Figures 10 and 11 demonstrate that the formation of butenes was very sensitive to the alcohol partial pressure. A small elevation of the alcohol pressure suppressed the formation of butenes rather drastically at both 90 and 117{degree}C. The synthesis rates of DME, MIBE, and MTBE ethers were not significantly affected at 90{degree}C, although there was a trend to increase the space time yield of DME as the alcohol pressure was increased. At the reaction temperature of 117{degree}C, all of the ethers showed increasing productivities as the pressure of the reactants was increased (Figure 11). An isotope labelling experiment was carried out to provide mechanistic insight into the manner in which methanol and isobutanol react together to form DME, MIBE, and MTBE ethers and to determine if MTBE were derived from MIBE.

Klier, K.; Herman, R.G.; Menszak, J.; Johansson, M.A.; Feeley, O.C.; Kim, D.

1993-07-01T23:59:59.000Z

117

Commercial-scale demonstration of the Liquid Phase Methanol (LPMEOH{trademark}) Process. Peroxide formation of dimethyl ether in methanol mixtures  

SciTech Connect

Organic peroxides could form when dimethyl ether in methanol is stored for three to six months at a time. The objective of this work was to determine the level of peroxide formation from dimethyl ether in reagent grade methanol and raw methanol at room temperature under 3 atmospheres (45 psig) of air. Raw methanol is methanol made from syngas by the LPMEOH Process without distillation. Aliphatic ethers tend to react slowly with oxygen from the air to form unstable peroxides. However, there are no reports on peroxide formation from dimethyl ether. After 172 days of testing, dimethyl ether in either reagent methanol or raw methanol at room temperature and under 60--70 psig pressure of air does not form detectable peroxides. Lack of detectable peroxides suggests that dimethyl ether or dimethyl ether and methanol may be stored at ambient conditions. Since the compositions of {approximately} 1.3 mol% or {approximately} 4.5 mol% dimethyl ether in methanol do not form peroxides, these compositions can be considered for diesel fuel or an atmospheric turbine fuel, respectively.

Waller, F.J.

1997-11-01T23:59:59.000Z

118

Flash photolysis resonance fluorescence investigation of the gas-phase reactions of hydroxyl radicals with cyclic ethers  

SciTech Connect

Absolute rate constants were measured for the gas-phase reactions of hydroxyl radicals with a series of dioxanes and other cyclic ethers by using the flash photolysis resonance fluorescence technique. Kinetic data for 1,3-dioxane and 1,4-dioxane, reactions 1 and 2, over the temperature range 240-440 K were used to derive the Arrhenius expressions. These results are compared to our earlier measurements for aliphatic ethers and are discussed in terms of reaction mechanisms and the prediction of reaction rates for such compounds from group reactivity values.

Dagaut, P.; Liu, R.; Wallington, T.J.; Kurylo, M.J. (National Institute of Standards and Technology, Gaithersburg, MD (USA))

1990-03-08T23:59:59.000Z

119

Calixarene crown ether solvent composition and use thereof for extraction of cesium from alkaline waste solutions  

DOE Patents (OSTI)

A solvent composition and corresponding method for extracting cesium (Cs) from aqueous neutral and alkaline solutions containing Cs and perhaps other competing metal ions is described. The method entails contacting an aqueous Cs-containing solution with a solvent consisting of a specific class of lipophilic calix[4]arene-crown ether extractants dissolved in a hydrocarbon-based diluent containing a specific class of alkyl-aromatic ether alcohols as modifiers. The cesium values are subsequently recovered from the extractant, and the solvent subsequently recycled, by contacting the Cs-containing organic solution with an aqueous stripping solution. This combined extraction and stripping method is especially useful as a process for removal of the radionuclide cesium-137 from highly alkaline waste solutions which are also very concentrated in sodium and potassium. No pre-treatment of the waste solution is necessary, and the cesium can be recovered using a safe and inexpensive stripping process using water, dilute (millimolar) acid solutions, or dilute (millimolar) salt solutions. An important application for this invention would be treatment of alkaline nuclear tank wastes. Alternatively, the invention could be applied to decontamination of acidic reprocessing wastes containing cesium-137.

Moyer, Bruce A. (Oak Ridge, TN); Sachleben, Richard A. (Knoxville, TN); Bonnesen, Peter V. (Knoxville, TN); Presley, Derek J. (Ooltewah, TN)

2001-01-01T23:59:59.000Z

120

Title: Decomposition of ethanol and dimethyl-ether during CVD synthesis of single-walled carbon nanotubes  

E-Print Network (OSTI)

of ethanol and dimethyl-ether during CVD synthesis of single-walled carbon nanotubes Author list: Bo Hou (single-walled carbon nanotubes) was investigated. Gas-phase thermal decomposition of ethanol and DME ethanol and DME decomposition, confirming expected reaction trends and primary byproducts. Peak

Maruyama, Shigeo

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121

Environmental actions of agrochemicals 2. Histological effects of the herbicide/insecticide dinoseb-acetate (2-sec-butyl-4,6-dinitrophenyl acetate) on the spider miteTetranychus urticae (Acari: Tetranychidae) reared on herbicidetreatedPhaseolus vulgaris  

Science Journals Connector (OSTI)

The pure herbicidal compound dinoseb-acetate (2-sec-butyl-4,6-dinitrophenyl acetate) and its commercial formulation Aretit® were tested for their effects on the spider miteTetranychus urticae L. (Acari, Tetranych...

Ursula Mothes-Wagner; Harald K. Reitze…

1990-10-01T23:59:59.000Z

122

Densities and isobaric vapor-liquid equilibria of butyl esters (methanoate to butanoate) with ethanol at 101.32 kPa  

SciTech Connect

Vapor-liquid equilibrium and densities at 101.32 kPa have been determined for the binary systems formed by four butyl esters (from methanoate to butanoate) with ethanol. The four systems exhibit positive deviations from ideal behavior, and all data (p-T-x-y) were found to be thermodynamically consistent. The activity coefficients and the dimensionless function G{sup E}/RT of the solution were correlated with its concentration by different equations. Am azeotrope was found in the mixture butyl methanoate (1) + ethanol (2) at T = 350.9 K and x{sub 1} = y{sub 1} = 0.088. The group contribution models ASOG and modified UNIFAC gave fair predictions.

Gonzalez, E.; Ortega, J. [Univ. of Las Palmas de Gran Canaria (Spain)

1995-11-01T23:59:59.000Z

123

Direct hydro-liquefaction of sawdust in petroleum ether and comprehensive bio-oil products analysis  

Science Journals Connector (OSTI)

Abstract The effect of temperature, time, hydrogen pressure and amount of catalyst on production distribution and the bio-oil yield obtained from the direct liquefaction of sawdust in the petroleum ether (60–90 °C) are investigated. The highest sawdust conversion obtained was 72.32% with a bio-oil yield of 47.69% were obtained at 370 °C, 40 min and 5wt.% catalyst content with the initial H2 pressure of 3.0 MPa. Fourier transform ion cyclotron resonance mass spectrometry (FTICR-MS) approach was utilized to analyze the non-volatile fraction. In this study, the composition of bio-oil could be analyzed in an unprecedented detail through a combination of GC–MS and FT-ICR MS techniques.

Dong Liu; Linhua Song; Pingping Wu; Yan Liu; Qingyin Li; Zifeng Yan

2014-01-01T23:59:59.000Z

124

Process for the production of ethylidene diacetate from dimethyl ether using a heterogeneous catalyst  

DOE Patents (OSTI)

This invention relates to a process for producing ethylidene diacetate by the reaction of dimethyl ether, acetic acid, hydrogen and carbon monoxide at elevated temperatures and pressures in the presence of an alkyl halide and a heterogeneous, bifunctional catalyst that is stable to hydrogenation and comprises an insoluble polymer having pendant quaternized heteroatoms, some of which heteroatoms are ionically bonded to anionic Group VIII metal complexes, the remainder of the heteroatoms being bonded to iodide. In contrast to prior art processes, no accelerator (promoter) is necessary to achieve the catalytic reaction and the products are easily separated from the catalyst by filtration. The catalyst can be recycled for 3 consecutive runs without loss in activity.

Ramprasad, D.; Waller, F.J.

1998-04-28T23:59:59.000Z

125

Use of aluminum phosphate as the dehydration catalyst in single step dimethyl ether process  

DOE Patents (OSTI)

The present invention pertains to a process for the coproduction of methanol and dimethyl ether (DME) directly from a synthesis gas in a single step (hereafter, the "single step DME process"). In this process, the synthesis gas comprising hydrogen and carbon oxides is contacted with a dual catalyst system comprising a physical mixture of a methanol synthesis catalyst and a methanol dehydration catalyst. The present invention is an improvement to this process for providing an active and stable catalyst system. The improvement comprises the use of an aluminum phosphate based catalyst as the methanol dehydration catalyst. Due to its moderate acidity, such a catalyst avoids the coke formation and catalyst interaction problems associated with the conventional dual catalyst systems taught for the single step DME process.

Peng, Xiang-Dong (Allentown, PA); Parris, Gene E. (Coopersburg, PA); Toseland, Bernard A. (Allentown, PA); Battavio, Paula J. (Allentown, PA)

1998-01-01T23:59:59.000Z

126

Process for the production of ethylidene diacetate from dimethyl ether using a heterogeneous catalyst  

DOE Patents (OSTI)

This invention relates to a process for producing ethylidene diacetate by the reaction of dimethyl ether, acetic acid, hydrogen and carbon monoxide at elevated temperatures and pressures in the presence of an alkyl halide and a heterogeneous, bifunctional catalyst that is stable to hydrogenation and comprises an insoluble polymer having pendant quaternized heteroatoms, some of which heteroatoms are ionically bonded to anionic Group VIII metal complexes, the remainder of the heteroatoms being bonded to iodide. In contrast to prior art processes, no accelerator (promoter) is necessary to achieve the catalytic reaction and the products are easily separated from the catalyst by filtration. The catalyst can be recycled for 3 consecutive runs without loss in activity.

Ramprasad, Dorai (Allentown, PA); Waller, Francis Joseph (Allentown, PA)

1998-01-01T23:59:59.000Z

127

Using Heteropolyacids in the Anode Catalyst Layer of Dimethyl Ether PEM Fuel Cells  

SciTech Connect

In this study, polarization experiments were performed on a direct dimethyl ether fuel cell (DMEFC). The experimental setup allowed for independent control of water and DME flow rates. Thus the DME flow rate, backpressure, and water flow rate were optimized. Three heteropoly acids, phosphomolybdic acid (PMA), phosphotungstic acid (PTA), and silicotungstic acid (STA) were incorporated into the anode catalyst layer in combination with Pt/C. Both PTA-Pt and STA-Pt showed higher performance than the Pt control at 30 psig of backpressure. Anodic polarizations were also performed, and Tafel slopes were extracted from the data. The trends in the Tafel slope values are in agreement with the polarization data. The addition of phosphotungstic acid more than doubled the power density of the fuel cell, compared to the Pt control.

Ferrell III, J. R.; Turner, J. A.; Herring, A. M.

2008-01-01T23:59:59.000Z

128

Use of ferric sulfate: acid media for the desulfurization of model compounds of coal. [Dibenzothiophene, diphenyl sulfide, di-n-butyl sulfide  

SciTech Connect

The objective of this work has been to investigate the ability of ferric sulfate-acid leach systems to oxidize the sulfur in model compounds of coal. Ferric iron-acid leach systems have been shown to be quite effective at removal of inorganic sulfur in coal. In this study, the oxidative effect of ferric iron in acid-leach systems was studied using dibenzothiophene, diphenyl sulfide, and di-n-butyl sulfide as models of organic sulfur groups in coal. Nitrogen and oxygen, as well as various transition metal catalysts and oxidants, were utilized in this investigation. Dibenzothiophene was found to be quite refractory to oxidation, except in the case where metavanadate was added, where it appears that 40% oxidation to sulfone could have occurred per hour at 150/sup 0/C and mild oxygen pressure. Diphenyl sulfide was selectively oxidized to sulfoxide and sulfone in an iron and oxygen system. Approximately 15% conversion to sulfone occurred per hour under these conditions. Some of the di-n-butyl sulfide was cracked to 1-butene and 1-butanethiol under similar conditions. Zinc chloride and ferric iron were used at 200/sup 0/C in an attempt to desulfonate dibenzothiophene sulfone, diphenyl sulfone, and di-n-butyl sulfone. Di-n-butyl sulfone was completely desulfurized on one hour and fragmented to oxidized parafins, while dibenzothiophene sulfone and diphenyl sulfone were unaffected. These results suggest that an iron-acid leach process could only selectively oxidize aryl sulfides under mild conditions, representing only 20% of the organic sulfur in coal (8% of the total sulfur). Removal through desulfonation once selective sulfur oxidation had occurred was only demonstrated for alkyl sulfones, with severe oxidation of the fragmented paraffins also occurring in one hour.

Clary, L.R.; Vermeulen, T.; Lynn, S.

1980-12-01T23:59:59.000Z

129

Identification of volatile butyl rubber thermal-oxidative degradation products by cryofocusing gas chromatography/mass spectrometry (cryo-GC/MS).  

SciTech Connect

Chemical structure and physical properties of materials, such as polymers, can be altered as aging progresses, which may result in a material that is ineffective for its envisioned intent. Butyl rubber formulations, starting material, and additives were aged under thermal-oxidative conditions for up to 413 total days at up to 124 %C2%B0C. Samples included: two formulations developed at Kansas City Plant (KCP) (%236 and %2310), one commercially available formulation (%2321), Laxness bromobutyl 2030 starting material, and two additives (polyethylene AC-617 and Vanax MBM). The low-molecular weight volatile thermal-oxidative degradation products that collected in the headspace over the samples were preconcentrated, separated, and detected using cryofocusing gas chromatography mass spectrometry (cryo-GC/MS). The majority of identified degradation species were alkanes, alkenes, alcohols, ketones, and aldehydes. Observations for Butyl %2310 aged in an oxygen-18 enriched atmosphere (18O2) were used to verify when the source of oxygen in the applicable degradation products was from the gaseous environment rather than the polymeric mixture. For comparison purposes, Butyl %2310 was also aged under non-oxidative thermal conditions using an argon atmosphere.

Smith, Jonell Nicole; White, Michael Irvin; Bernstein, Robert; Hochrein, James Michael

2013-02-01T23:59:59.000Z

130

Sulfobutyl Ether b-Cyclodextrin (SBE-b-CD) in Eyedrops Improves the Tolerability of a Topically Applied Pilocarpine Prodrug in Rabbits  

E-Print Network (OSTI)

The effects of a novel, modified ?-cyclodextrin (SBE4-?-CD; a variably substituted sulfobutyl ether with an average degree of substitution of four) on eye irritation and miotic response of an ophthalmically applied pilocarpine ...

Stella, Valentino J.; Jä rvinen, Tomi; Jä rvinen, Kristina; Thompson, Diame; Urtti, Arto

1995-01-01T23:59:59.000Z

131

E-Print Network 3.0 - algorithm na ordenacao Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

Historic Houses College of Charleston Summary: Related Deaths 90 Wentworth Street-House 0 0 NA NA NA NA NA NA 92 Wentworth Street-House 0 0 NA NA... NA NA NA NA...

132

Solvent Extraction Behavior of Neptunium (IV) Ions between Nitric Acid and Diluted 30% Tri-butyl Phosphate in the Presence of Simple Hydroxamic Acids  

SciTech Connect

Formo- and aceto-hydroxamic acids are very effective reagents for stripping tetravalent actinide ions such as Np(IV) and Pu(IV) ions from a tri-butyl phosphate phase into nitric acid. Distribution data for Np(IV) in the presence of these hydroxamate ions have now been accumulated and trends established. Stability constants for aceto-hydroxamate complexes of Np(IV) and Np(V) ions have also been determined in a perchlorate medium, and these reaffirm the affinity of hydroxamate ligands for actinide (IV) ions over actinyl (V,VI) ions.

Taylor, Robin J.; Sinkov, Sergey I.; Choppin, Gregory R.; May, Iain

2008-01-15T23:59:59.000Z

133

An evaluation of the 3M Organic Vapor Monitor #3500 as a short term exposure limit sampling device for acetone, methyl ethyl ketone, and methyl iso butyl ketone  

E-Print Network (OSTI)

. An exploded view of the monitor is illustrated in Figure 1. The theory of diffusive sampling considers a concentration gra- dient between the ambient air and the adsorbent to be the driving force for sampling. For the adsorption to be controlled by diffu...AN EVALUATION OF THE 3M ORGANIC VAPOR MONITOR 43500 AS A SHOR'I TERM EXPOSURE LIMIT SAMPLING DEVICE FOR ACETONE, METHYL ETHYL KETONE, AND METHYL ISO BUTYL KETONE A Thesis by LLOYD B. ANDREW III Submitted to the Graduate College of Texas ASM...

Andrew, Lloyd B.

2012-06-07T23:59:59.000Z

134

A New Flow Control Technique Using Diluted Epinephrine in the N-butyl-2-cyanoacrylate Embolization of Visceral Artery Pseudoaneurysms Secondary to Chronic Pancreatitis  

SciTech Connect

Although n-butyl-2-cyanoacrylate (NBCA) has been used as an effective liquid embolization material, its indication for pseudoaneurysms has seemingly been limited because of the technical difficulties of using NBCA, such as reflux to the parent artery and causing significant infarction. Thus, considerable skill in using NBCA or a device to control blood flow during its polymerization is required to achieve embolization without severe complications. We report our new technique for controlling blood flow using diluted epinephrine in transcatheter arterial NBCA embolization of five pseudoaneurysms in four cases secondary to hemosuccus pancreaticus.

Morishita, Hiroyuki, E-mail: hmorif@koto.kpu-m.ac.jp [Japan Red Cross Kyoto Daiichi Hospital, Department of Diagnostic Radiology (Japan); Yamagami, Takuji [Kyoto Prefectural University of Medicine, Department of Radiology, Graduate School of Medical Science (Japan); Takeuchi, Yoshito [National Cancer Center, Division of Diagnostic Radiology (Japan); Matsumoto, Tomohiro; Asai, Shunsuke; Masui, Koji [Japan Red Cross Kyoto Daiichi Hospital, Department of Diagnostic Radiology (Japan); Sato, Hideki [Japan Red Cross Kyoto Daiichi Hospital, Department of Gastroenterology (Japan); Taniguchi, Fumihiro [Japan Red Cross Kyoto Daiichi Hospital, Department of Surgery (Japan); Sato, Osamu [Japan Red Cross Kyoto Daiichi Hospital, Department of Diagnostic Radiology (Japan); Nishimura, Tsunehiko [Kyoto Prefectural University of Medicine, Department of Radiology, Graduate School of Medical Science (Japan)

2012-08-15T23:59:59.000Z

135

Word Pro - Untitled1  

U.S. Energy Information Administration (EIA) Indexed Site

1 1 Table 10.5 Estimated Number of Alternative-Fueled Vehicles in Use and Fuel Consumption, 1992-2010 Year Alternative and Replacement Fuels 1 Liquefied Petroleum Gases Compressed Natural Gas Liquefied Natural Gas Methanol, 85 Percent (M85) 3 Methanol, Neat (M100) 4 Ethanol, 85 Percent (E85) 3,5 Ethanol, 95 Percent (E95) 3 Elec- tricity 6 Hydro- gen Other Fuels 7 Subtotal Oxygenates 2 Bio- diesel 10 Total Methyl Tertiary Butyl Ether 8 Ethanol in Gasohol 9 Total Alternative-Fueled Vehicles in Use 11 (number) 1992 NA 23,191 90 4,850 404 172 38 1,607 NA NA NA NA NA NA NA NA 1993 NA 32,714 299 10,263 414 441 27 1,690 NA NA NA NA NA NA NA NA 1994 NA 41,227 484 15,484 415 605 33 2,224 NA NA NA NA NA NA NA NA 1995 172,806 50,218 603 18,319 386 1,527

136

Ethoxyresorufin O-deethylase induction of polychlorinated diphenyl ethers in H4IIE cells  

SciTech Connect

The ethoxyresorufin O-deethylase (EROD) induction potencies of 29 polychlorinated diphenyl ethers were determined in the rat hepatoma H4IIE cell bioassay and compared with that of 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD). Two polychlorinated biphenyls (PCBs) were included as additional reference substances. PCDE congeners tested were PCDEs 47, 66, 77, 85, 99, 105, 118, 126, 128, 137, 138, 140, 147, 153, 154, 156, 157, 167, 170, 180, 181, 182, 190, 194, 195, 196, 197, 203 and 206. The purity of these congeners was > 99%. Because several of these congeners induced EROD activity when tested at high concentrations, the amount of PCDD and PCDF impurities of these active PCDEs was determined by gas chromatography/mass spectrometry. The activity of the active PCDEs was concluded to be mainly due to contamination with 2,3,7,8-chloro substituted PCDFS, because after an additional clean-up on a Florisil column, which removes PCDDs and PCDFs, only three PCDEs (156, 180, 194) remained active. The potencies of PCDEs 156, 180 and 194 (TEF {approximately} 10{sup {minus}6}), however, were about 100-fold less than that of PCB 77 (TEF {approximately} 10{sup {minus}4}). The poor induction potencies of the non- and mono-ortho-PCDEs indicates that PCDEs do not have structure-activity relationships analogous to those of PCBs. If the authors use EROD inducing potency in H4IIE cells as a relative measure of potential Ah receptor-mediated toxic potency, the PCDEs in the study would be expected to be less toxic than analogous PCBs and considerably less-toxic than certain PCDDs and PCDFs.

Koistinen, J.; Sanderson, J.T.; Giesy, J.P. [Michigan State Univ., East Lansing, MI (United States); Nevalainen, T.; Paasivirta, J. [Univ. of Jyvaskyla (Finland)

1995-12-31T23:59:59.000Z

137

Mechanistic Investigation of Acid-Catalyzed Cleavage of Aryl-Ether Linkages: Implications for Lignin Depolymerization  

SciTech Connect

Carbon-oxygen bonds are the primary inter-monomer linkages lignin polymers in plant cell walls, and as such, catalyst development to cleave these linkages is of paramount importance to deconstruct biomass to its constituent monomers for the production of renewable fuels and chemicals. For many decades, acid catalysis has been used to depolymerize lignin. Lignin is a primary component of plant cell walls, which is connected primarily by aryl-ether linkages, and the mechanism of its deconstruction by acid is not well understood, likely due to its heterogeneous and complex nature compared to cellulose. For effective biomass conversion strategies, utilization of lignin is of significant relevance and as such understanding the mechanisms of catalytic lignin deconstruction to constituent monomers and oligomers is of keen interest. Here, we present a comprehensive experimental and theoretical study of the acid catalysis of a range of dimeric species exhibiting the b-O-4 linkage, the most common inter-monomer linkage in lignin. We demonstrate that the presence of a phenolic species dramatically increases the rate of cleavage in acid at 150 degrees C. Quantum mechanical calculations on dimers with the para-hydroxyl group demonstrate that this acid-catalyzed pathway differs from the nonphenolic dimmers. Importantly, this result implies that depolymerization of native lignin in the plant cell wall will proceed via an unzipping mechanism wherein b-O-4 linkages will be cleaved from the ends of the branched, polymer chains inwards toward the center of the polymer. To test this hypothesis further, we synthesized a homopolymer of b-O-4 with a phenolic hydroxyl group, and demonstrate that it is cleaved in acid from the end containing the phenolic hydroxyl group. This result suggests that genetic modifications to lignin biosynthesis pathways in plants that will enable lower severity processes to fractionate lignin for upgrading and for easier access to the carbohydrate fraction of the plant cell wall.

Sturgeon, M. R.; Kim, S.; Chmely, S. C.; Foust, T. D.; Beckham, G. T.

2013-01-01T23:59:59.000Z

138

The lightness of being: mass, ether, and unification of the forces  

SciTech Connect

How can an electron be both a wave and a particle? At the same time? Because it is a quantum field. That key insight seems to be underappreciated, given the awe and mysticism that permeate most nontechnical discussions of modern physics. Perhaps the root of the problem is that most popularizations of quantum mechanics and of particle physics shy away from quantized fields, the natural language for microscopic phenomena. In 'The Lightness of Being: Mass, Ether, and the Unification of Forces', Frank Wilczek confronts quantum field theory head on, demystifying not only wave-particle duality but also the origin of mass for hadrons (that is, everyday matter). Wilczek is the Herman Feshbach Professor of Physics at MIT and a co-recipient of the 2004 Nobel Prize in Physics. His research has spanned almost all aspects of theoretical particle physics, with significant forays into condensed-matter physics and dense nuclear matter (condensed quark matter, one might say). Recurring themes are the richness of quantum chromodynamics (QCD) and the alluring ideas of unification. His breadth and depth make him a sought after speaker for colloquia and public lectures. Wilczek also contributes an occasional Reference Frame column to 'Physics Today'. The material in 'The Lightness of Being' reflects the scope of the author's research. The book consists of three parts: the quantum fields of QCD (the ether that makes mass), gravitation (the ether that feels mass), and unification. Part 1, which traces notions of mass from Isaac Newton's time through theoretical and computational results of the past 40 years, is the most substantial and original; it is rich, modern, and rooted in observed phenomena. Part 2 continues in the same vein as it connects gravity, also an observed phenomenon, to QCD. Part 3 is more conventional, for a popularization of particle physics, in its focus on speculative ideas that (still) await direct experimental tests. Readers of 'Physics Today' will know that Wilczek can write with wit, grace, and an uncanny facility for using lightweight language to express heavy-duty ideas. They will find much of that kind of writing in 'The Lightness of Being'. Wilczek addresses subtle ideas with vim and vigor. He avoids some of the jargon of quantum field theory; for example, he calls the vertex in a Feynman diagram a hub. In more ambitious terminology, he refers to space-filling, everfluctuating quantum fields--be they electrons, quarks, gluons, or gravity--as 'the Grid'. The term is supposed to be short and familiar, evoking the ubiquitous electric grid (and soon-to-beubiquitous computing grid). It also, for the expert, cleverly alludes to lattice gauge theory. Indeed, after vividly explaining how the dynamics of QCD and the constraints of Heisenberg uncertainty conspire to create mass from the Grid, Wilczek emphasizes that the picture is backed by lattice QCD computations of 'heroic' proportions. Unfortunately, too much of 'The Lightness' is laden with clunky affectation: silly names (a pulsed electron accelerator is called the 'ultrastroboscopic nanomicroscope'), sophomoric jokes ('hadron' is 'not a typo'), references to pop culture (Wilczek might have called quantum fields 'the Matrix, but the sequels tarnished that candidate'), and many pointless footnotes. In a public lecture the audience may guffaw at such jokes, but on the printed page they fall flat. Wilczek explains physics so well that the inappropriate humor is the biggest unexplained puzzle of the book. It is fine to be silly, even crude, as long as the reader's path to understanding is made easier. A joke can inform with an unexpected perspective or simply give the mind a pause to refresh. Some of the humor achieves such aims, but too many gags impede the pace of the otherwise fine exposition. Three appendices, a glossary, and a set of endnotes are crisp and sober. They are excellent. 'The Lightness of Being' is not unbearable, but it is weighed down with too much clutter to rank as a masterpiece. It's a pity: Wilczek's best writing--some of it in this book--is l

Kronfeld, Andreas S.

2009-03-01T23:59:59.000Z

139

Distribution of glycerol ether lipids in the oxygen minimum zone of the Eastern Tropical North Pacific Ocean  

Science Journals Connector (OSTI)

Abstract The distributions of microbial glycerol ether lipids in suspended particulate matter in the oxygen minimum zone (OMZ) of the Eastern Tropical North Pacific Ocean (ETNP) were investigated. Nine groups of glycerol ether core lipids were detected and quantified: isoprenoid glycerol dialkyl glycerol tetraethers (GDGTs) (iso-GDGTs), isoprenoid glycerol dialkanol diethers (iso-GDDs) and hydroxylated isoprenoid \\{GDGTs\\} and \\{GDDs\\} (OH-GDGTs and OH-GDDs) of archaeal origin; branched glycerol dialkyl glycerol tetraethers (br-GDGTs) of bacterial origin and overly branched \\{GDGTs\\} (OB-GDGTs), sparsely branched \\{GDGTs\\} (SB-GDGTs), hybrid isoprenoid/branched \\{GDGTs\\} (IB-GDGTs) and a tentatively assigned H-shaped GDGT (H-1020) of unknown biological origin. The archaeal iso-GDGTs were the most abundant core lipids (89% of total), followed by iso-GDDs (4%), br-GDGTs (2%) and OH-GDGTs (1%). Archaeal intact polar \\{GDGTs\\} (IP GDGTs), including both mono- and diglycosidic iso-GDGTs, had depth profiles similar to OH-GDGTs and OH-GDDs, with a maximum concentration in the upper OMZ and secondary peaks in the mid and lower OMZ, suggesting similar but multiple planktonic sources. Core lipids of iso-GDGTs and other glycerol ethers showed deviating concentration profiles compared with IP \\{GDGTs\\} and OH-GDGTs and were most abundant in the mid OMZ. This is the first report of OH-GDDs, OB-GDGTs, SB-GDGTs, IB-GDGTs and H-1020 in the marine water column and the distribution patterns of these “orphan lipids” suggest that anaerobic planktonic microbes are their main source.

Sitan Xie; Xiao-Lei Liu; Florence Schubotz; Stuart G. Wakeham; Kai-Uwe Hinrichs

2014-01-01T23:59:59.000Z

140

E-Print Network 3.0 - allyl methacrylate styrene Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Tetrachloroethylene () Cyclohexanol () Cyclohexanone ()1- 1-Butyl alcohol ()2... ;() Acrolein () Acrylic acid () Allyl zlcohol () Allyl chloride () Allyl glycidyl ether(AGE) ()2-...

Note: This page contains sample records for the topic "butyl ether na" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

TABLE33.CHP:Corel VENTURA  

Annual Energy Outlook 2012 (EIA)

products are reported by the PAD District of entry. b Includes crude oil imported for storage in the Strategic Petroleum Reserve. c Includes ethyl tertiary butyl ether (ETBE),...

142

TABLE34.CHP:Corel VENTURA  

Gasoline and Diesel Fuel Update (EIA)

products are reported by the PAD District of entry. b Includes crude oil imported for storage in the Strategic Petroleum Reserve. c Includes ethyl tertiary butyl ether (ETBE),...

143

Original article Soybean impairs Na  

E-Print Network (OSTI)

flour (HSF), or ethanol heat-treated soybean protein concentrate (SPC). The Na+ -dependent glucose co. In conclusion, soybean contains ethanol-sensitive heat-insensitive compounds impairing Na+ -dependent glucose absorption in the jejunum and ileum, and ethanol- and heat-insensitive compounds causing an acute impairment

Boyer, Edmond

144

Use of Nonionic Poly(Ethylene glycol) p-Isooctyl-Phenyl Ether (Triton X-100) Surfactant Mobile Phases in the Thin-Layer Chromatography of Heavy-Metal Cations  

Science Journals Connector (OSTI)

......Article The analytical potential of poly(ethylene glycol) p-isooctyl-phenyl ether...40, March 2002 Use of Nonionic Poly(Ethylene glycol) p-Isooctyl-Phenyl Ether...Bidlingmeyer, S.N. Deming, W.P. Price, B. Sachok, and M. Petrusek. Retention......

Ali Mohammad; Eram Iraqi; Iftkhar Alam Khan

2002-03-01T23:59:59.000Z

145

Chemical Recycling of Carbon Dioxide to Methanol and Dimethyl Ether: From Greenhouse Gas to Renewable, Environmentally Carbon Neutral Fuels and Synthetic Hydrocarbons  

Science Journals Connector (OSTI)

Chemical Recycling of Carbon Dioxide to Methanol and Dimethyl Ether: From Greenhouse Gas to Renewable, Environmentally Carbon Neutral Fuels and Synthetic Hydrocarbons ... (1, 3-6) Methanol and derived dimethyl ether (DME) are also excellent fuels in internal combustion engines (ICE) and in a new generation of direct oxidation methanol fuel cells (DMFC), as well as convenient starting materials for producing light olefins (ethylene and propylene) and subsequently practically any derived hydrocarbon product. ... Methanol produced this way was used in the 19th century for lighting, cooking, and heating purposes but was later replaced by cheaper fuels, especially kerosene. ...

George A. Olah; Alain Goeppert; G. K. Surya Prakash

2008-12-08T23:59:59.000Z

146

Experimental investigation on thermal barrier coated diesel engine fueled with diesel-biodiesel-ethanol-diethyl ether blends  

Science Journals Connector (OSTI)

In the present work diesel-biodiesel-ethanol (DBE) and diesel-biodiesel-diethyl ether (DBD) fuels are tested with normal diesel engine and the diesel engine coated with the layers of aluminum oxide (Al 2O3) of 0.3?mm and yttria-stabilized zirconia of 0.2?mm. The various performance and emission parameters are analyzed and determined. The experimental work was carried out in a single cylinder water cooled engine coupled with eddy current dynamometer. The AVL make five gas analyzer and smoke meter were used to measure the different exhaust pollutants. The result shows that the brake thermal efficiency of coated engine is more than that of base diesel at high loads. The thermal barrier coated engine using fuel as diesel biodiesel and ethanol (TDBE) produces the lowest carbon monoxide (CO) emissions among all the fuels that are selected. In addition it produces the lowest carbon dioxide (CO2) at higher loads. Both the thermal barrier coated engine using fuel as diesel biodiesel and diethyl ether (TDBD) and TDBE have higher NOx emissions among almost all the fuels used. The TDBE and TDBD have higher smoke emissions at initial loads but eventually show lower smoke emissions at higher loads. The thermal barrier coated diesel engine fueled with DBE and DBD shows an increase in engine power and specific fuel consumption as well as significant improvements in exhaust gas emissions except NOx.

2013-01-01T23:59:59.000Z

147

Modeling of the simultaneous extraction of nitric acid and uranyl nitrate with tri-n-butyl phosphate. Application to extraction operation  

SciTech Connect

A mathematical model developed for the equilibrium HNO{sub 3}-UO{sub 2}(NO{sub 3}){sub 2}-tri-n-butyl phosphate (TBP)-diluent is the basis of the computation of distribution isotherms. The isotherms are used to study the influence of TBP concentration on two chosen operation parameters, distribution coefficients and number of theoretical stages, for the selected flow sheets. It is established that an increase in TBP concentration leads to a decrease in the number of theoretical stages for the extraction flow sheets but to their increase for the striping flow sheets. Given diagrams can be used to determine the efficiency of extraction processes. Agreement with available literature calculations on the number of theoretical stages supports the use of the model in the computation of distribution isotherms, of the system quoted above, in a wide range of nitric acid, uranyl nitrate, and TBP concentrations.

Comor, J.J.; Tolic, A.S.; Kopecni, M.M.; Petkovic, D.M. [Vinca Inst. of Nuclear Sciences, Belgrade (Yugoslavia). Chemical Dynamics Lab.] [Vinca Inst. of Nuclear Sciences, Belgrade (Yugoslavia). Chemical Dynamics Lab.

1999-01-01T23:59:59.000Z

148

(2/94)(2-4,9/95)(7/97)(11,12/98)(1,9,11/99) Neuman Chapter 3 Haloalkanes, Alcohols, Ethers, and Amines  

E-Print Network (OSTI)

, Ethers, and Amines from Organic Chemistry by Robert C. Neuman, Jr. Professor of Chemistry, emeritus://web.chem.ucsb.edu/~neuman/orgchembyneuman/> Chapter Outline of the Book ************************************************************************************** I. Foundations 1. Organic Molecules and Chemical Bonding 2. Alkanes and Cycloalkanes 3. Haloalkanes

Reed, Christopher A.

149

Role of Endocytosis in the Action of Ether Lipids on WEHI-3B, HL60, and FDCP-Mix A4 Cells  

Science Journals Connector (OSTI)

...Lipid by WEHI-3B Cells Has an Energy- dependent and an Energy-independent Component. Uptake...protective agents, suggested that the energy-dependent component of ether...of ET-18-OCH., by FDCP-mix A4 cells was measured, it was...

G. W. Bazill and T. M. Dexter

1990-12-01T23:59:59.000Z

150

Reactions of 15-crown-5 and bis-15-crown-5 ethers with metal acetylacetonate ions in the gas phase  

SciTech Connect

A study was carried out on the ion-molecule reactions of ions arising in the dissociation of ferric, cobaltic, chromic, manganous, neodymium(II), gallium(III), and indium(III) acetylacetonates upon electron impact with 15-crown-5 and bis-15-crown-5. The ratio of the yields of (acac)x-1 /SUP M+L/ ions is determined by the case of reduction of M /SUP x+1+/ to M /SUP x+/ and for (acac)/sub 3/M complexes, this ratio decreases in the series Nd, In, GA > Cr > Fe, Co. The rate constant for the formation of acacCoL/sup +/ ions is greater than for acacFeL/sup +/ ions. The possibility of fixing transition metals in unstable oxidation states by crown ethers is demonstrated in the case of nickel.

Timofeev, O.S.; Bogatskii, A.V.; Gren, A.I.; Lobach, A.V.; Nekarsov, Y.S.; Zagorevskii, D.V.

1985-05-20T23:59:59.000Z

151

Single-Step Syngas-to-Distillates (S2D) Synthesis via Methanol and Dimethyl Ether Intermediates: Final Report  

SciTech Connect

The objective of the work was to enhance price-competitive, synthesis gas (syngas)-based production of transportation fuels that are directly compatible with the existing vehicle fleet (i.e., vehicles fueled by gasoline, diesel, jet fuel, etc.). To accomplish this, modifications to the traditional methanol-to-gasoline (MTG) process were investigated. In this study, we investigated direct conversion of syngas to distillates using methanol and dimethyl ether intermediates. For this application, a Pd/ZnO/Al2O3 (PdZnAl) catalyst previously developed for methanol steam reforming was evaluated. The PdZnAl catalyst was shown to be far superior to a conventional copper-based methanol catalyst when operated at relatively high temperatures (i.e., >300°C), which is necessary for MTG-type applications. Catalytic performance was evaluated through parametric studies. Process conditions such as temperature, pressure, gas-hour-space velocity, and syngas feed ratio (i.e., hydrogen:carbon monoxide) were investigated. PdZnAl catalyst formulation also was optimized to maximize conversion and selectivity to methanol and dimethyl ether while suppressing methane formation. Thus, a PdZn/Al2O3 catalyst optimized for methanol and dimethyl ether formation was developed through combined catalytic material and process parameter exploration. However, even after compositional optimization, a significant amount of undesirable carbon dioxide was produced (formed via the water-gas-shift reaction), and some degree of methane formation could not be completely avoided. Pd/ZnO/Al2O3 used in combination with ZSM-5 was investigated for direct syngas-to-distillates conversion. High conversion was achieved as thermodynamic constraints are alleviated when methanol and dimethyl are intermediates for hydrocarbon formation. When methanol and/or dimethyl ether are products formed separately, equilibrium restrictions occur. Thermodynamic relaxation also enables the use of lower operating pressures than what would be allowed for methanol synthesis alone. Aromatic-rich hydrocarbon liquid (C5+), containing a significant amount of methylated benzenes, was produced under these conditions. However, selectivity control to liquid hydrocarbons was difficult to achieve. Carbon dioxide and methane formation was problematic. Furthermore, saturation of the olefinic intermediates formed in the zeolite, and necessary for gasoline production, occurred over PdZnAl. Thus, yield to desirable hydrocarbon liquid product was limited. Evaluation of other oxygenate-producing catalysts could possibly lead to future advances. Potential exists with discovery of other types of catalysts that suppress carbon dioxide and light hydrocarbon formation. Comparative techno-economics for a single-step syngas-to-distillates process and a more conventional MTG-type process were investigated. Results suggest operating and capital cost savings could only modestly be achieved, given future improvements to catalyst performance. Sensitivity analysis indicated that increased single-pass yield to hydrocarbon liquid is a primary need for this process to achieve cost competiveness.

Dagle, Robert A.; Lebarbier, Vanessa MC; Lizarazo Adarme, Jair A.; King, David L.; Zhu, Yunhua; Gray, Michel J.; Jones, Susanne B.; Biddy, Mary J.; Hallen, Richard T.; Wang, Yong; White, James F.; Holladay, Johnathan E.; Palo, Daniel R.

2013-11-26T23:59:59.000Z

152

Single-Step Syngas-to-Dimethyl Ether Processes for Optimal Productivity, Minimal Emissions, and Natural Gas-Derived Syngas  

Science Journals Connector (OSTI)

Single-step conversion of synthesis gas (syngas, H2/CO mixture) to dimethyl ether (DME, CH3OCH3) is very attractive as a route for indirect coal liquefaction, natural gas utilization, and production of synthetic liquid fuels, fuel additives, and chemicals. ... The main driving force for developing a single-step syngas-to-DME process is to produce DME at a cost lower than that from the commercially available two-step process, namely, syngas-to-methanol followed by methanol dehydration in sequential reactors. ... Furthermore, the composition of most commercially available syngas (except that produced by a CO2?methane reformer) is not the optimal composition (1:1 H2:CO) for the syngas-to-DME reactor. ...

X. D. Peng; A. W. Wang; B. A. Toseland; P. J. A. Tijm

1999-09-28T23:59:59.000Z

153

Ethynyl terminated ethers. Synthesis and thermal characterization of 2,2 bis (ethynyl-4-phenylcarbonyl-4-phenoxy-4-phenyl) propane and 2,2 bis (ethynyl-4-phenylsulfonyl-4-phenoxy-4-phenyl) propane  

Science Journals Connector (OSTI)

Two ethynyl end-capped ethers 2,2 Bis [ethynyl-4-phenylsulfonyl-4-phenoxy-4-phenyl] propane and 2,2 Bis [ethynyl-4-phenylcarbonyl-4-phenoxy-4-phenyl] propane have been prepared by a three steps...

Georges Lucotte; Laurent Cormier; Bruno Delfort

1990-12-01T23:59:59.000Z

154

Efficient production of 5-hydroxymethylfurfural through the dehydration of sugars with caprolactam hydrogen sulfate ([CPL]HSO4) ionic liquid catalyst in a water/proprylene glycol monomethyl ether mixed solvent  

Science Journals Connector (OSTI)

Efficient production of 5-hydroxymethylfurfural (HMF) through the dehydration of sugars...4) ionic liquid or using metal halide as the co-catalyst in a new water/proprylene glycol monomethyl ether solvent system....

Pingzhen Huang; Aijuan Gu; Jinxing Wang

2014-04-01T23:59:59.000Z

155

Fluctuating micro-heterogeneity in water–tert-butyl alcohol mixtures and lambda-type divergence of the mean cluster size with phase transition-like multiple anomalies  

SciTech Connect

Water–tert-butyl alcohol (TBA) binary mixture exhibits a large number of thermodynamic and dynamic anomalies. These anomalies are observed at surprisingly low TBA mole fraction, with x{sub TBA} ? 0.03–0.07. We demonstrate here that the origin of the anomalies lies in the local structural changes that occur due to self-aggregation of TBA molecules. We observe a percolation transition of the TBA molecules at x{sub TBA} ? 0.05. We note that “islands” of TBA clusters form even below this mole fraction, while a large spanning cluster emerges above that mole fraction. At this percolation threshold, we observe a lambda-type divergence in the fluctuation of the size of the largest TBA cluster, reminiscent of a critical point. Alongside, the structure of water is also perturbed, albeit weakly, by the aggregation of TBA molecules. There is a monotonic decrease in the tetrahedral order parameter of water, while the dipole moment correlation shows a weak nonlinearity. Interestingly, water molecules themselves exhibit a reverse percolation transition at higher TBA concentration, x{sub TBA} ? 0.45, where large spanning water clusters now break-up into small clusters. This is accompanied by significant divergence of the fluctuations in the size of largest water cluster. This second transition gives rise to another set of anomalies around. Both the percolation transitions can be regarded as manifestations of Janus effect at small molecular level.

Banerjee, Saikat; Furtado, Jonathan; Bagchi, Biman, E-mail: bbagchi@sscu.iisc.ernet.in [SSCU, Indian Institute of Science, Bangalore 560012 (India)] [SSCU, Indian Institute of Science, Bangalore 560012 (India)

2014-05-21T23:59:59.000Z

156

Transport study of hafnium(IV) and zirconium(IV) ions mutual separation by using Tri-n-butyl phosphate-xylene-based supported liquid membranes  

SciTech Connect

A Hf transport study through supported liquid membranes has been carried out to determine flux and permeability data for this metal ion. Tri-n-butyl phosphate (TBP)-xylene-based liquid membranes supported in polypropylene hydrophobic microporous film have been used. These data for hafnium and the previous data for zirconium have furnished the Zr to Hf flux ratio (S) as a function of nitric acid and TBP concentrations of the order of 12 in a single stage at room temperature. Optimum conditions for the separation of these two metal ions appear to 5-6 TBP mol/dm{sup 3} HNO{sub 3}, concentrations {le} 2.93 mol/dm{sup 3}, and 10C. The value of S from an aqueous solution containing 2.4% Hf with respect to Zr has been found to be >125 at 10C and 1.78 mol/dm{sup 3} TBP concentration in the membrane. The technique appears to be feasible for purification of Zr respect to Hf or vice versa.

Chaudry, M.A.; Ahmed, B. (Pakistan Inst. of Nuclear Science and Technology, Islamabad (Pakistan))

1992-02-01T23:59:59.000Z

157

Low-temperature CVD of iron, cobalt, and nickel nitride thin films from bis[di(tert-butyl)amido]metal(II) precursors and ammonia  

SciTech Connect

Thin films of late transition metal nitrides (where the metal is iron, cobalt, or nickel) are grown by low-pressure metalorganic chemical vapor deposition from bis[di(tert-butyl)amido]metal(II) precursors and ammonia. These metal nitrides are known to have useful mechanical and magnetic properties, but there are few thin film growth techniques to produce them based on a single precursor family. The authors report the deposition of metal nitride thin films below 300?°C from three recently synthesized M[N(t-Bu){sub 2}]{sub 2} precursors, where M?=?Fe, Co, and Ni, with growth onset as low as room temperature. Metal-rich phases are obtained with constant nitrogen content from growth onset to 200?°C over a range of feedstock partial pressures. Carbon contamination in the films is minimal for iron and cobalt nitride, but similar to the nitrogen concentration for nickel nitride. X-ray photoelectron spectroscopy indicates that the incorporated nitrogen is present as metal nitride, even for films grown at the reaction onset temperature. Deposition rates of up to 18?nm/min are observed. The film morphologies, growth rates, and compositions are consistent with a gas-phase transamination reaction that produces precursor species with high sticking coefficients and low surface mobilities.

Cloud, Andrew N.; Abelson, John R., E-mail: abelson@illinois.edu [Department of Materials Science and Engineering, University of Illinois at Urbana-Champaign, 201 Materials Science and Engineering Building, 1304 W. Green St., Urbana, Illinois 61801 (United States); Davis, Luke M.; Girolami, Gregory S., E-mail: girolami@scs.illinois.edu [School of Chemical Sciences, University of Illinois at Urbana-Champaign, 600 S. Mathews Ave., Urbana, Illinois 61801 (United States)

2014-03-15T23:59:59.000Z

158

Fluctuating micro-heterogeneity in water - tert-butyl alcohol mixtures and lambda-type divergence of the mean cluster size with phase transition-like multiple anomalies  

E-Print Network (OSTI)

Water - tert-butyl alcohol (TBA) binary mixture exhibits a large number of thermodynamic and dynamic anomalies. These anomalies are observed at surprisingly low TBA mole fraction, with $x_{\\text{TBA}} \\approx 0.03 - 0.07$. We demonstrate here that the origin of the anomalies lies in the local structural changes that occur due to self-aggregation of TBA molecules. We observe a percolation transition of the TBA molecules at $x_{\\text{TBA}} \\approx 0.05$. We note that "islands" of TBA clusters form even below this mole fraction, while a large spanning cluster emerges above that mole fraction. At this percolation threshold, we observe a lambda-type divergence in the fluctuation of the size of the largest TBA cluster, reminiscent of a critical point. Alongside, the structure of water is also perturbed, albeit weakly, by the aggregation of TBA molecules. There is a monotonic decrease in the tetrahedral order parameter of water, while the dipole moment correlation shows a weak non-linearity. Interestingly, water molecules themselves exhibit a reverse percolation transition at higher TBA concentration, $x_{\\text{TBA}} \\approx 0.45$, where large spanning water clusters now break-up into small clusters. This is accompanied by significant divergence of the fluctuations in the size of largest water cluster. This second transition gives rise to another set of anomalies around. Both the percolation transitions can be regarded as manifestations of Janus effect at small molecular level.

Saikat Banerjee; Jonathan Furtado; Biman Bagchi

2014-02-20T23:59:59.000Z

159

Advances in the design of co-poly(ether-imide) membranes for CO2 separations. Influence of aromatic rigidity on crystallinity, phase segregation and gas transport  

Science Journals Connector (OSTI)

Abstract In our previous works, it was observed a clear relationship between the structure and the properties for different copoly(ether-imide)s, besides a good relation was found between SAXS characterization and permeability results. Here, a series of aliphatic aromatic copoly(ether-imide)s, based on an aromatic diamine (ODA), a diamine terminated poly(ethylene oxide) (PEO2000) of a molecular weight of 2000 g/mol and different aromatic dianhydrides (BPDA, BKDA (or BTDA) and PMDA) has been synthesized and characterized. The permeability for O2, N2, CO2 and CH4, increased with the rigidity of the monomers (BKDA CO2/N2 separation. This work gives indications on how to design advanced materials for this separation with the increasing possibilities of controlled structure and properties.

Alberto Tena; Ángel Marcos-Fernández; Mónica de la Viuda; Laura Palacio; Pedro Prádanos; Ángel E. Lozano; Javier de Abajo; Antonio Hernández

2015-01-01T23:59:59.000Z

160

Polybrominated Diphenyl Ethers in U.S. Sewage Sludges and Biosolids: Temporal and Geographical Trends and Uptake by Corn Following Land Application  

Science Journals Connector (OSTI)

Robert C. Hale *, Mark J. La Guardia , Ellen Harvey , Da Chen , Thomas M. Mainor , and Drew R. Luellen , ... An internal standard (decachlorodiphenyl ether) was added and the final extracts were analyzed by gas chromatography/mass spectrometry (GC/MS) with electron-capture negative chemical ionization (EC-NCI). ... This work surveyed PBDE in spruce needles and air (gaseous and particle-bound) over an annual cycle to model PBDE accumulation in vegetation. ...

Robert C. Hale; Mark J. La Guardia; Ellen Harvey; Da Chen; Thomas M. Mainor; Drew R. Luellen; Lakhwinder S. Hundal

2012-01-26T23:59:59.000Z

Note: This page contains sample records for the topic "butyl ether na" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

LABORATRIOS NA RUA 26 de Novembro, segunda  

E-Print Network (OSTI)

LABORAT�RIOS NA RUA 26 de Novembro, segunda IST Alameda ­ Anfiteatro do Complexo Interdisciplinar ORGANIZA��O �MBITO LABORAT�RIOS NA RUA ­ IST Breve apresentação dos Laboratórios na Rua ­ uma plataforma universitária, sem fins lucrativos, de voluntariado e intervenção social LABORAT�RIOS NA RUA ­ IST Exemplos de

Instituto de Sistemas e Robotica

162

Design and synthesis of the next generation of crown ethers for waste separations: An inter-laboratory comprehensive proposal. 1998 annual progress report  

SciTech Connect

'The purpose of this task is to undertake the design, synthesis, and characterization of the next generation of crown ethers for metal-ion separations applicable to USDOE''s environmental needs. Target problems include: Li{sup +} ions leaching from burial sites at the Oak Ridge Y-12 Plant; fission products 90 Sr and {sup 137}Cs contaminating high-level tank wastes at Hanford, INEEL, and Savannah River; and radium in wastes at the Niagara Falls Storage Site. Unfortunately, the technologies needed to address these problems either do not exist or exhibit substantial deficiencies. Separation techniques such as solvent extraction and ion exchange promise to play a strong role, especially as enhanced with highly selective crown ethers and calixarenes. This project is midway through year 2 of a 3-year effort. Below is given a summary of progress in the approximate period September, 1997, to May, 1998, for each of the four co-investigators at Pacific Northwest National Laboratory (PNNL), Argonne National Laboratory (ANL), Oak Ridge National Laboratory (ORNL), and the University of Tennessee (UTK). The overall approach entails utilization of theory and molecular modeling (PNNL), organic synthesis of novel crown compounds (ORNL), solvent extraction studies (ORNL and ANL), and studies of polymer-immobilized crown ethers (UTK).'

Moyer, B.A.; Hay, B.P.; Dietz, M.L.; Alexandratos, S.D.; Sachleben, R.A.; Chiarizia, R.

1998-06-01T23:59:59.000Z

163

Promoting effect of polyoxyethylene octylphenol ether on Cu/ZnO catalysts for low-temperature methanol synthesis  

Science Journals Connector (OSTI)

Cu/ZnO catalysts were prepared by the co-precipitation method with the addition of OP-10 (polyoxyethylene octylphenol ether) and were chemically and structurally characterized by means of XRD, BET, H2-TPR, CO-TPD and N2O-titration. The effect of OP-10 addition on the activity of Cu/ZnO for the slurry phase methanol synthesis at 150 °C was evaluated. The results showed that Cu/ZnO prepared with addition of 8% OP-10 (denoted as C8) exhibited the promoted activity for the methanol synthesis. The conversion of CO and the STY (space time yield) of methanol were 42.5% and 74.6% higher than those of Cu/ZnO prepared without addition of OP-10 (denoted as C0), respectively. The precursor of C8 contained more aurichalcite and rosasite, and the concerted effect of Cu-Zn in C8 was found to be stronger than that in C0. Compared with C0, C8 showed smaller particle size, lower reduction temperature and larger BET and Cu surface areas.

Ling Liu; Tiansheng Zhao; Qingxiang Ma; Yufang Shen

2009-01-01T23:59:59.000Z

164

Ethoxyresorufin-O-deethylase induction potency of polychlorinated diphenyl ethers in H4IIE rat hepatoma cells  

SciTech Connect

Polychlorinated diphenyl ethers (PCDEs) are structurally similar to polychlorinated biphenyls (PCBs), and some PCDE congeners have been reported to cause toxic responses similar to those caused by some of the non-ortho-substituted PCBs, which are mediated by the aryl hydrocarbon receptor (AhR). Twenty-nine PCDEs were tested for their potency as AhR agonists relative to 2,3,7,8-tetrachlorodibenzo-p-dioxin (2,3,7,8-TCDD) by measuring their ability to induce the cytochrome P-450 1A1-associated enzyme activity, ethoxyresorufin-O-deethylase (EROD), in the H4IIE rat hepatoma cell bioassay. All PCDE congeners tested were found to be inactive as EROD inducers except for PCDE 156, which was a weak EROD inducer with a 2,3,7,8-TCDD equivalency factor of about 1.2 {times} 10{sup {minus}5}. During this study the authors determined that small amounts of polychlorinated dibenzofurans (PCDFs) that occurred as impurities in the PCDE preparations were the cause of the apparent EROD induction initially measured in their experiments. Once the PCDF impurities were removed by purification on florisil, little or no activity could be attributed to the PCDEs.

Koistinen, J.; Sanderson, J.T.; Giesy, J.P. [Michigan State Univ., East Lansing, MI (United States); Nevalainen, T.; Paasivirta, J. [Univ. of Jyvaeskylae (Finland). Dept. of Chemistry

1996-11-01T23:59:59.000Z

165

Investigation of HCCI Combustion of Diethyl Ether and Ethanol Mixtures Using Carbon 14 Tracing and Numerical Simulations  

SciTech Connect

Despite the rapid combustion typically experienced in Homogeneous Charge Compression Ignition (HCCI), components in fuel mixtures do not ignite in unison or burn equally. In our experiments and modeling of blends of diethyl ether (DEE) and ethanol (EtOH), the DEE led combustion and proceeded further toward completion, as indicated by {sup 14}C isotope tracing. A numerical model of HCCI combustion of DEE and EtOH mixtures supports the isotopic findings. Although both approaches lacked information on incompletely combusted intermediates plentiful in HCCI emissions, the numerical model and {sup 14}C tracing data agreed within the limitations of the single zone model. Despite the fact that DEE is more reactive than EtOH in HCCI engines, they are sufficiently similar that we did not observe a large elongation of energy release or significant reduction in inlet temperature required for light-off, both desired effects for the combustion event. This finding suggests that, in general, HCCI combustion of fuel blends may have preferential combustion of some of the blend components.

Mack, J H; Dibble, R W; Buchholz, B A; Flowers, D L

2004-01-16T23:59:59.000Z

166

Calcitriol inhibits Ether-a go-go potassium channel expression and cell proliferation in human breast cancer cells  

SciTech Connect

Antiproliferative actions of calcitriol have been shown to occur in many cell types; however, little is known regarding the molecular basis of this process in breast carcinoma. Ether-a-go-go (Eag1) potassium channels promote oncogenesis and are implicated in breast cancer cell proliferation. Since calcitriol displays antineoplastic effects while Eag1 promotes tumorigenesis, and both factors antagonically regulate cell cycle progression, we investigated a possible regulatory effect of calcitriol upon Eag1 as a mean to uncover new molecular events involved in the antiproliferative activity of this hormone in human breast tumor-derived cells. RT real-time PCR and immunocytochemistry showed that calcitriol suppressed Eag1 expression by a vitamin D receptor (VDR)-dependent mechanism. This effect was accompanied by inhibition of cell proliferation, which was potentiated by astemizole, a nonspecific Eag1 inhibitor. Immunohistochemistry and Western blot demonstrated that Eag1 and VDR abundance was higher in invasive-ductal carcinoma than in fibroadenoma, and immunoreactivity of both proteins was located in ductal epithelial cells. Our results provide evidence of a novel mechanism involved in the antiproliferative effects of calcitriol and highlight VDR as a cancer therapeutic target for breast cancer treatment and prevention.

Garcia-Becerra, Rocio [Department of Reproductive Biology, Instituto Nacional de Ciencias Medicas y Nutricion Salvador Zubiran, Vasco de Quiroga No. 15, Tlalpan 14000 Mexico, D.F. (Mexico)] [Department of Reproductive Biology, Instituto Nacional de Ciencias Medicas y Nutricion Salvador Zubiran, Vasco de Quiroga No. 15, Tlalpan 14000 Mexico, D.F. (Mexico); Diaz, Lorenza, E-mail: lorenzadiaz@gmail.com [Department of Reproductive Biology, Instituto Nacional de Ciencias Medicas y Nutricion Salvador Zubiran, Vasco de Quiroga No. 15, Tlalpan 14000 Mexico, D.F. (Mexico)] [Department of Reproductive Biology, Instituto Nacional de Ciencias Medicas y Nutricion Salvador Zubiran, Vasco de Quiroga No. 15, Tlalpan 14000 Mexico, D.F. (Mexico); Camacho, Javier [Department of Pharmacology, Centro de Investigacion y de Estudios Avanzados, Instituto Politecnico Nacional, Av. Instituto Politecnico Nacional 2508, San Pedro Zacatenco 07360, Mexico, D.F. (Mexico)] [Department of Pharmacology, Centro de Investigacion y de Estudios Avanzados, Instituto Politecnico Nacional, Av. Instituto Politecnico Nacional 2508, San Pedro Zacatenco 07360, Mexico, D.F. (Mexico); Barrera, David; Ordaz-Rosado, David; Morales, Angelica [Department of Reproductive Biology, Instituto Nacional de Ciencias Medicas y Nutricion Salvador Zubiran, Vasco de Quiroga No. 15, Tlalpan 14000 Mexico, D.F. (Mexico)] [Department of Reproductive Biology, Instituto Nacional de Ciencias Medicas y Nutricion Salvador Zubiran, Vasco de Quiroga No. 15, Tlalpan 14000 Mexico, D.F. (Mexico); Ortiz, Cindy Sharon [Department of Pathology, Instituto Nacional de Ciencias Medicas y Nutricion Salvador Zubiran, Vasco de Quiroga No. 15, Tlalpan 14000 Mexico, D.F. (Mexico)] [Department of Pathology, Instituto Nacional de Ciencias Medicas y Nutricion Salvador Zubiran, Vasco de Quiroga No. 15, Tlalpan 14000 Mexico, D.F. (Mexico); Avila, Euclides [Department of Reproductive Biology, Instituto Nacional de Ciencias Medicas y Nutricion Salvador Zubiran, Vasco de Quiroga No. 15, Tlalpan 14000 Mexico, D.F. (Mexico)] [Department of Reproductive Biology, Instituto Nacional de Ciencias Medicas y Nutricion Salvador Zubiran, Vasco de Quiroga No. 15, Tlalpan 14000 Mexico, D.F. (Mexico); Bargallo, Enrique [Department of Breast Tumors, Instituto Nacional de Cancerologia, Av. San Fernando No. 22, Tlalpan 14080, Mexico, D.F. (Mexico)] [Department of Breast Tumors, Instituto Nacional de Cancerologia, Av. San Fernando No. 22, Tlalpan 14080, Mexico, D.F. (Mexico); Arrecillas, Myrna [Department of Pathology, Instituto Nacional de Cancerologia, Av. San Fernando No. 22, Tlalpan 14080, Mexico, D.F. (Mexico)] [Department of Pathology, Instituto Nacional de Cancerologia, Av. San Fernando No. 22, Tlalpan 14080, Mexico, D.F. (Mexico); Halhali, Ali; Larrea, Fernando [Department of Reproductive Biology, Instituto Nacional de Ciencias Medicas y Nutricion Salvador Zubiran, Vasco de Quiroga No. 15, Tlalpan 14000 Mexico, D.F. (Mexico)] [Department of Reproductive Biology, Instituto Nacional de Ciencias Medicas y Nutricion Salvador Zubiran, Vasco de Quiroga No. 15, Tlalpan 14000 Mexico, D.F. (Mexico)

2010-02-01T23:59:59.000Z

167

Monodisperse porous polymer particles containing macrocyclic ether as a new class of sorbent for SR(II) separation  

SciTech Connect

Strontium{sup 90} is one of the typical fission products that may be found in high level liquid waste (HLLW). Separation of Sr{sup 90} prior to the vitrification is beneficial to the final treatment of solid radioactive waste. In this study, a new class of sorbent for Sr(II) was developed by loading the macrocyclic ether DtBuCH18C6 into the monodisperse porous polymer particles (MPPPs). The MPPPs are well-known as a promising chromatographic material due to the uniform particle size, porous morphology, good compatibility with organic extractants, and rigid matrix. The structure and micro-morphology of the sorbent particles were characterized. The adsorption behavior towards Sr(II) in HNO{sub 3} media was investigated by both batch and column experiments. High adsorption efficiency and selective separation of Sr(II) was obtained. The sorbent particles can be recycled for at least several times before obvious lose of the adsorption ability. This kind of sorbent possesses the potential to be used for strontium separation in radioactive liquid waste.

Leng, Yuxiao; Bai, Feifei [Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084 (China); Faculty of Chemical Science and Engineering, China University of Petroleum, Beijing 100084 (China); Ye, Gang; Wei, Jichao; Wang, Jianchen; Chen, Jing [Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084 (China)

2013-07-01T23:59:59.000Z

168

Synergistic effect of mixing dimethyl ether with methane, ethane, propane, and ethylene fuels on polycyclic aromatic hydrocarbon and soot formation  

SciTech Connect

Characteristics of polycyclic aromatic hydrocarbon (PAH) and soot formation in counterflow diffusion flames of methane, ethane, propane, and ethylene fuels mixed with dimethyl ether (DME) have been investigated. Planar laser-induced incandescence and fluorescence techniques were employed to measure relative soot volume fractions and PAH concentrations, respectively. Results showed that even though DME is known to be a clean fuel in terms of soot formation, DME mixture with ethylene fuel increases PAH and soot formation significantly as compared to the pure ethylene case, while the mixture of DME with methane, ethane, and propane decreases PAH and soot formation. Numerical calculations adopting a detailed kinetics showed that DME can be decomposed to produce a relatively large number of methyl radicals in the low-temperature region where PAH forms and grows; thus the mixture of DME with ethylene increases CH{sub 3} radicals significantly in the PAH formation region. Considering that the increase in the concentration of O radicals is minimal in the PAH formation region with DME mixture, the enhancement of PAH and soot formation in the mixture flames of DME and ethylene can be explained based on the role of methyl radicals in PAH and soot formation. Methyl radicals can increase the concentration of propargyls, which could enhance incipient benzene ring formation through the propargyl recombination reaction and subsequent PAH growth. Thus, the result substantiates the importance of methyl radicals in PAH and soot formation, especially in the PAH formation region of diffusion flames. (author)

Yoon, S.S. [Corporate Research and Development Division, Hyundai-Kia Motors, Gyeonggi-do 445-706 (Korea); Anh, D.H. [Korea Electric Power Research Institute, Daejeon 305-380 (Korea); Chung, S.H. [School of Mechanical and Aerospace Engineering, Seoul National University, Seoul 151-742 (Korea)

2008-08-15T23:59:59.000Z

169

Life cycle study of coal-based dimethyl ether as vehicle fuel for urban bus in China  

Science Journals Connector (OSTI)

With life cycle assessment (LCA) methodology, a life cycle model of coal-based dimethyl ether (CBDME) as a vehicle fuel is established for China. Its life cycle from well to wheel are divided into three phases. They are feedstock extraction, fuel production and fuel consumption in vehicle. The primary energy consumption (PEC) and global warming potential (GWP) of CBDME pathway are analyzed and compared with coal-based diesel (CBD) as a latent rival to replace conventional petroleum-based diesel (CPBD). This study demonstrates that the LCA methodology is very suitable and effective for the choice of vehicle fuels. One result is that the greenhouse gases (GHGs) emission of coal-based vehicle fuel pathways is usually concentrated on fuel production stage. The percentages of CBDME and CBD pathways both exceed 60%. The application of carbon capture and storage (CCS) is helpful for coal-based vehicle fuel pathways to improve their global warming effect dramatically. Compared with CBD pathway, CBDME pathway consumes less PEC and emits less \\{GHGs\\} emission as well. Even though the CCS and CH4-fired generation are used, the advantages of CBDME are still kept. For saving petroleum energy and reducing global warming effect, CBDME has greater potential than CBD to substitute CPBD under current fuel synthesis technologies. If the hurdles such as the maturity of engine and vehicle technologies, corresponding regulations and standards and infrastructures are reliably solved, CBDME will have better prospect in China.

Liang Zhang; Zhen Huang

2007-01-01T23:59:59.000Z

170

Solubility of carbon dioxide, nitrous oxide, ethane, and nitrogen in 1-butyl-1-methylpyrrolidinium and trihexyl(tetradecyl)phosphonium tris(pentafluoroethyl)trifluorophosphate (eFAP) ionic liquids  

Science Journals Connector (OSTI)

The density and viscosity of the ionic liquids 1-butyl-1-methylpyrrolidinium tris(pentafluoroethyl)trifluorophosphate [C1C4Pyrro][eFAP] and trihexyl(tetradecyl)phosphonium tris(pentafluoroethyl)trifluorophosphate [P66614][eFAP] were measured as a function of temperature and pressure and as a function of temperature, respectively. These two ionic liquids are more viscous than those based in the same anion associated to imidazolium cations. The effect of the addition of water on the density and viscosity of [P66614][eFAP] was studied at pressures close to atmospheric and as a function of the temperature. This ionic liquid is only partially miscible with water, its solubility being of around X H 2 O = 0.2 in the range of (303 to 315) K. Experimental values of the solubility of carbon dioxide, nitrous oxide, ethane, and nitrogen were obtained as a function of temperature and at pressures close to atmospheric. Carbon dioxide and nitrous oxide are the more soluble gases with mole fraction solubilities up to 7 · 10?2. Ethane is four times and 1.3 times less soluble than carbon dioxide in [C1C4Pyrro][eFAP] and [P66614][eFAP], respectively. Nitrogen is one order of magnitude less soluble than the others gases in the two ionic liquids studied. In order to understand behavior of the different gases with these ionic liquids, the thermodynamic functions of solvation such as enthalpy and entropy were calculated from the variation of the Henry’s law constant with temperature. It is shown that the more favorable interactions of the gases with the ionic liquid explain the larger solubility of carbon dioxide and nitrous oxide in [C1C4Pyrro][eFAP]. In the case of [P66614][eFAP], it is the less favorable entropic contribution that explains the lower solubility of ethane in this ionic liquid.

S. Stevanovic; M.F. Costa Gomes

2013-01-01T23:59:59.000Z

171

2012 Annual Workforce Analysis and Staffing Plan Report - NNSA NA-00 and NA-10  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Last printed 1/24/2013 10:50:00 AM Page 1 of 12 Last printed 1/24/2013 10:50:00 AM Page 1 of 12 Part 1. NA-00/NA-10/NA-15 Input Annual Workforce Analysis and Staffing Plan Report As of December 31, 2012 Reporting Offices: NNSA NA-10 HQ (including NA-15 inputs) and NA-00 (while transitioning to new organizational structure) Section One: Current Mission(s) of the Organization and Potential Changes NNSA Mission: To strengthen United States security through the military application of nuclear energy. NNSA Vision: To be an integrated nuclear security enterprise operating an efficient and agile nuclear weapons complex, recognized as preeminent in technical leadership and program management. Organizational Changes: NNSA is in the final phase of another re-organization that will split NA- 10 and establish an independent office, NA-00, to oversee the NNSA sites and other non-weapons-

172

New Improved Equations For Na-K, Na-Li And Sio2 Geothermometers By Outlier  

Open Energy Info (EERE)

Improved Equations For Na-K, Na-Li And Sio2 Geothermometers By Outlier Improved Equations For Na-K, Na-Li And Sio2 Geothermometers By Outlier Detection And Rejection Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: New Improved Equations For Na-K, Na-Li And Sio2 Geothermometers By Outlier Detection And Rejection Details Activities (1) Areas (1) Regions (0) Abstract: We present new improved equations for three still widely used Na/K, Na/Li and SiO2 geothermometers (obtained by statistical treatment of the data and application of outlier detection and rejection as well as theory of error propagation) and compare them with those by Fournier and others. New equations are also developed for estimating errors associated with the use of these new geothermometric equations and comparing them with the performance of the original equations. The errors in the use of the new

173

Synthesis of Methanol and Dimethyl Ether from Syngas over Pd/ZnO/Al2O3 Catalysts  

SciTech Connect

A Pd/ZnO/Al2O3 catalyst was developed for the synthesis of methanol and dimethyl ether (DME) from syngas. Studied were temperatures of operation ranging from 250°C to 380°C. High temperatures (e.g. 380°C) are necessary when combining methanol and DME synthesis with a methanol to gasoline (MTG) process in a single reactor bed. A commercial Cu/ZnO/Al2O3 catalyst, utilized industrially for the synthesis of methanol at 220-280°C, suffers from a rapid deactivation when the reaction is conducted at high temperature (>320°C). On the contrary, a Pd/ZnO/Al2O3 catalyst was found to be highly stable for methanol and DME synthesis at 380°C. The Pd/ZnO/Al2O3 catalyst was thus further investigated for methanol and DME synthesis at P=34-69 bars, T= 250-380°C, GHSV= 5 000-18 000 h-1, and molar feeds H2/CO= 1, 2, and 3. Selectivity to DME increased with decreasing operating temperature, and increasing operating pressure. Increased GHSV’s and H2/CO syngas feed ratios also enhanced DME selectivity. Undesirable CH4 formation was observed, however, can be minimized through choice of process conditions and by catalyst design. By studying the effect of the Pd loading and the Pd:Zn molar ratio the formulation of the Pd/ZnO/Al2O3 catalyst was optimized. A catalyst with 5% Pd and a Pd:Zn molar ratio of 0.25:1 has been identified as the preferred catalyst. Results indicate that PdZn particles are more active than Pdº particles for the synthesis of methanol and less active for CH4 formation. A correlation between DME selectivity and the concentration of acid sites of the catalysts has been established. Hence, two types of sites are required for the direct conversion of syngas to DME: 1) PdZn particles are active for the synthesis of methanol from syngas, and 2) acid sites which are active for the conversion of methanol to DME. Additionally, CO2 formation was problematic as PdZn was found to be active for the water-gas-shift (WGS) reaction, under all the conditions evaluated.

Lebarbier, Vanessa MC; Dagle, Robert A.; Kovarik, Libor; Lizarazo Adarme, Jair A.; King, David L.; Palo, Daniel R.

2012-10-01T23:59:59.000Z

174

Effect of in-situ bonding system and surface modification of montmorillonite on the properties of butyl rubber/MMT composites  

Science Journals Connector (OSTI)

Isobutylene-isoprene rubber (IIR)/nanoclay composites were prepared by solution intercalation method. Cloisite Na + nanoclays and organo-modified montmorillonite (OMT) Cloisite 10 A .15 A and 20 A were used in this study. The effect of In-situ bonding system HRH (hexametylene tetramine: resorcinol: hydrated silica) on the dispersion of used nanoclays in the rubber matrix were examined by X-ray diffraction and atomic force microscopy (AFM). Characterization of the prepared composites was performed by studying the rheometeric and mechanical properties. The burning out behavior of the nanocomposites with and without the bonding system was also measured.

2012-01-01T23:59:59.000Z

175

Um novo paradigma na medicina DESENVOLVEU UMA METODOLOGIA DISRUPTIVA BASEADA NA INTEGRAO DE AVANADAS TECNOLOGIAS  

E-Print Network (OSTI)

Um novo paradigma na medicina do coração DESENVOLVEU UMA METODOLOGIA DISRUPTIVA BASEADA NA M�DICOS A MELHORAR DIAGN�STICOS NA MEDICINA DO CORA��O. #12;Depois do aperfeiçoamento das tecnologias pa medicina. A utilização dos resultados da genéti- ca como meio auxiliar de diagnóstico clínico é já uma

Instituto de Sistemas e Robotica

176

Na double-edge magneto-optic filter for Na lidar profiling of wind and temperature in the  

E-Print Network (OSTI)

proposed by one of the authors (Williams), originating from the Na magneto-optic filter in solar-edge magneto-optic fil- ter (Na-DEMOF). It has advantages over the FPIs and iodine filters because of its magnetic field across the Na cell causes the Zeeman splitting of Na energy levels, which shifts

Chu, Xinzhao

177

APPENDXD.CHP:Corel VENTURA  

Gasoline and Diesel Fuel Update (EIA)

Report The Form EIA-819, "Monthly Oxygenate Report" provides production data for fuel ethanol and methyl tertiary butyl ether (MTBE). End-of-month stock data held at ethanol...

178

The feasibility of ethanol production in Texas  

E-Print Network (OSTI)

Agricultural interests across Texas are looking at the possibility of an ethanol industry in Texas. Continued conflict in the Middle East, the ban of methyl tertiary butyl ether (MTBE) in California, and low commodity prices have all lead...

Herbst, Brian Keith

2012-06-07T23:59:59.000Z

179

Second Sound in NaF  

Science Journals Connector (OSTI)

Propagation of heat pulses in NaF has been studied to higher temperatures in a purer crystal than studied by McNelly et al. At the highest temperatures the second-sound velocity fails to level off at the theoretically predicted limiting value.

Howard E. Jackson; Charles T. Walker; Thomas F. McNelly

1970-07-06T23:59:59.000Z

180

master's degree NaNotechNology  

E-Print Network (OSTI)

master's degree NaNotechNology When choosing a Master's programme, it is wise to look one step topical, incorporating the latest developments in applied physics, nanotechnology, chemical engineering projects will be carried out at the MESA+ institute for nanotechnology, or the MIRA institute

Twente, Universiteit

Note: This page contains sample records for the topic "butyl ether na" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

DIFFUSION OF Na AND Cs IN MONTMORILLONITE  

Science Journals Connector (OSTI)

...Na-montmorillonite, is used to backfill emplacement tunnels (Nagra...the low permeability of the backfill material inhibits the advective...are retained in the bentonite buffer long enough to let radioactive...minerals. Pp. 19-68 in: Handbook of Clay Science (F. Bergaya...

Georg Kosakowski; Sergey V. Churakov; Tres Thoenen

182

Synthesis, structures, and properties of novel aminodisilanes bearing bulky substituents: 1,2-bis(1,1,2-trimethylpropyl)-1,1,2,2-tetrakis(diethylamino) disilane and 1,2-di-tert-butyl-1,1,2,2-tetrakis(diethylamino) disilane  

Science Journals Connector (OSTI)

Two novel tetraaminodisilanes, 1,2-bis(1,1,2-trimethylpropyl)-1,1,2,2-tetrakis(diethylamino)disilane (1) and 1,2-di-tert-butyl-1,1,2,2-tetrakis(diethylamino)disilane (2) were synthesized and X-ray crystallography analyses of these compounds were carried out. Reflecting the steric congestion, the Si?Si bonds are very long: 2.539(2) Å for bis(1,1,2-trimethylpropyl)disilane, and 2.4764(9) Å for di-tert-butyl-disilane. UV spectra and oxidation potentials of several tetraaminodialkyldisilanes are compared and discussed. In addition, in the chlorination of 1 with HCl, 1,1,2,2-tetrachloro-1,2-bis(1,1,2-trimethylpropyl)disilane (6) was obtained with a 72% yield.

Masafumi Unno; Mina Saito; Hideyuki Matsumoto

1995-01-01T23:59:59.000Z

183

SPME in Environmental Analysis: Biotransformation Pathways  

Science Journals Connector (OSTI)

......SPMEGCMS to study the degradation of ethyl benzene using...methyl-t-butyl ether and its degradation products, t-butyl...food by determining degradation products and other released...Bitumen is a fossil fuel rich in sulfur, which...Aliquots of the cell suspension (2 mL......

Annamaria Halasz; Jalal Hawari

2006-08-01T23:59:59.000Z

184

Gas transport properties of reverse-selective poly(ether-b-amide6)/[Emim][BF4] gel membranes for CO2/light gases separation  

Science Journals Connector (OSTI)

Abstract The present research investigates deeply effect of 1-ethyl-3 methylimidazolium tetrafluoroborate ([Emim][BF4]) ionic liquid on separation performance and transport properties of poly(ether-b-amide6)(Pebax1657) at different operating pressures from 2 to 20 bar and temperatures from 25 to 65 °C. [Emim][BF4] showed interesting separation factor for CO2/light gases as a solvent and it was expected that its addition to Pebax1657 leads more amorphous structure, thereby diffusion and permeability of gases increase. [Emim][BF4] was added to the polymer solution up to 100 wt.% of Pebax1657 weight and permeation coefficients of CO2, H2, CH4 and N2 through the prepared membranes were measured. The results showed remarkable increment in permeation of all the tested gases, particularly CO2 and ideal selectivity of CO2/H2 enhanced significantly due to high solubility selectivity of the added compound. Effect of operating conditions on solubility coefficients were also investigated, thus sorption isotherms and activation energies of permeability, solubility and diffusion were calculated. In addition, the membranes were characterized by SEM, DSC, FT-IR spectroscopy and Tensile analysis to inspect changes in their physical and thermal properties, precisely.

Hesamoddin Rabiee; Ali Ghadimi; Toraj Mohammadi

2014-01-01T23:59:59.000Z

185

Lattice Dynamics of NaF  

Science Journals Connector (OSTI)

The results of an extended calculation of the normal modes of the NaF lattice are presented. Three models have been considered: a "rigid-ion" (RI) model, a "deformation-dipole" model with central F--F- short-range interactions (DDNNN), and a "deformation-dipole" model including both central F--F- interactions and a noncentral component in the first-neighbor, short-range interactions [DDNNN(NC)]. For each of these models we have derived frequency spectra for both 300 and 0°K input parameters, the associated dispersion curves for symmetry directions, Debye characteristic temperatures ?D, moment functions ?D(n), and the Na+ and F- Debye-Waller parameters B1 and B2 and their ratio B1B2. Of the three models, the two DD variations give good agreement with the observed dispersion curves, the DDNNN models being slightly better and giving somewhat closer agreement with the observed B values.

Arnold M. Karo and John R. Hardy

1969-05-15T23:59:59.000Z

186

2011 Annual Planning Summary for Defense Nuclear Nonproliferation (NA-20)  

Energy.gov (U.S. Department of Energy (DOE))

The ongoing and projected Environmental Assessments and Environmental Impact Statements for 2011 and 2012 within Defense Nuclear Nonproliferation (NA-20).

187

Technical Design Report, CERN NA63  

E-Print Network (OSTI)

We summarize the status and plans for the 2015 run for the CERN NA63 collaboration. First, we review the motivation for our proposed experiments with the scheduled Ar18+ beam of Feb/Mar 2015. We also show some slightly updated versions of our calculations that better reflect the experimental situation. Then we turn to a detailed description of the detector setup, focusing on the deployment of the MIMOSA detectors.

Mikkelsen, RE; Wistisen, TN

2014-01-01T23:59:59.000Z

188

Multiphonon Optical Spectrum of NaF  

Science Journals Connector (OSTI)

The high-frequency exponential wing of the reststrahlen band of NaF is decomposed into a number of N-phonon absorption spectra (N=2,3,4,5) by means of a temperature analysis. Overall agreement of the individual spectra with recent theoretical predictions is good, except for a fairly pronounced structure which indicates particularly strong contributions from certain frequencies of the TO and LO phonon branches.

Thomas F. McNelly and Dieter W. Pohl

1974-06-10T23:59:59.000Z

189

Gua para a Sustentabilidade Ambiental na UDC  

E-Print Network (OSTI)

#12;#12;#12;Guía para a Sustentabilidade Ambiental na UDC #12;Redacción Dolores Árias Vázquez Juan Introdución 23 Indicadores de sustentabilidade 27 O contorno natural e humanizado 35 Caracterización dos Ambientalización curricular 101 Outros servizos da udC relacionados coa sustentabilidade 105 O medio ambiente

Fraguela, Basilio B.

190

E-Print Network 3.0 - arteriais na cirurgia Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

na Universidade de Braslia: Prof. Dr. Csar Augusto... na UnB: Ailson Aristarco de Sousa - Secretrio de Recursos Humanos Adlia Betty Ludovico de Almeida... Corporativa na...

191

E-Print Network 3.0 - antimicrobiana na cirurgia Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

na Universidade de Braslia: Prof. Dr. Csar Augusto... na UnB: Ailson Aristarco de Sousa - Secretrio de Recursos Humanos Adlia Betty Ludovico de Almeida... Corporativa na...

192

E-Print Network 3.0 - autogeno na cirurgia Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

na Universidade de Braslia: Prof. Dr. Csar Augusto... na UnB: Ailson Aristarco de Sousa - Secretrio de Recursos Humanos Adlia Betty Ludovico de Almeida... Corporativa na...

193

The effect of Na+ montmorillonite (NaMMT) nanoclay on thermal properties of medium density fiberboard (MDF)  

Science Journals Connector (OSTI)

In this study, the potential use of nanotechnology was evaluated to improve the thermal properties of medium density fiberboard (MDF). For this, Na+ montmorillonite (NaMMT) nanoclay was added to urea formaldehyde...

Reza Zahedsheijani; Mehdi Faezipour…

2012-09-01T23:59:59.000Z

194

Comparative studies of etching mechanisms of CR-39 in NaOH/H2O and NaOH/ethanol  

E-Print Network (OSTI)

Comparative studies of etching mechanisms of CR-39 in NaOH/H2O and NaOH/ethanol K.C.C. Tse, D Avenue, Kowloon Tong, Hong Kong Available online 13 May 2007 Abstract The bulk etch rate for CR-39 in NaOH/ethanol accumulates on the surface of CR-39 detector during etching in NaOH/ethanol, which is absent during etching

Yu, K.N.

195

Partial Pressure of Saturated Sodium Nitrite Vapor over the System NaNO2-NaNO3  

Science Journals Connector (OSTI)

The partial pressure of sodium nitrite was measured in the system NaNO2-NaNO3...at temperatures of 798, 823, and 848 K and the logarithm of the NaNO2 pressure was obtained as a function of inverse temperature. Th...

V. I. Glazov; G. P. Dukhanin; M. Kh. Dkhaibe…

2004-02-01T23:59:59.000Z

196

Gamow-Teller strength in Na23(n,p) and a comparison to Na23(?-,?)  

Science Journals Connector (OSTI)

We report measurements of the Na23(n,p) differential cross section at an incident energy of 198 MeV and angles from 0° to 24° using the TRIUMF Charge Exchange Facility. From these data we determine Gamow-Teller (GT) transition probabilities to low lying 1/2+, 3/2+, and 5/2+ Ne23 states and the GT+ strength distribution up to 25 MeV excitation energy. The values of BGT+ to discrete states, and the GT+ strength below 10 MeV, are found to be in reasonable agreement with a full 1s-0d shell model calculation with a normalization factor of about 0.74. The GT+ strength above 10 MeV suggests the removal of strength from lower to higher excitation energies. We also compare the Na23(n,p) data with Na23(?-,?) data and find agreement between the values of BGT+ to discrete levels extracted from the (n,p) and (?-,?) reactions. The general consistency of the (n,p) and (?-,?) data, and the full 1s-0d shell model calculation, give confidence in a recent extraction of the weak pseudoscalar coupling from ?- capture on Na23. Finally, using both ?--decay and ?- capture data, we obtain unit cross sections from the Na23(n,p) measurement.

B. Siebels; T. P. Gorringe; W. P. Alford; J. Bauer; J. Evans; S. El-Kateb; K. P. Jackson; A. Trudel; S. Yen

1995-09-01T23:59:59.000Z

197

Workforce Statistics - NA-30 | National Nuclear Security Administration  

National Nuclear Security Administration (NNSA)

NA-30 | National Nuclear Security Administration NA-30 | National Nuclear Security Administration Our Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Continuing Management Reform Countering Nuclear Terrorism About Us Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Media Room Congressional Testimony Fact Sheets Newsletters Press Releases Speeches Events Social Media Video Gallery Photo Gallery NNSA Archive Federal Employment Apply for Our Jobs Our Jobs Working at NNSA Blog Workforce Statistics - NA-30 Home > About Us > Our Operations > Management and Budget > Office of Civil Rights > Workforce Statistics > Workforce Statistics - NA-30 Workforce Statistics - NA-30 Workforce Statistics - Naval Reactors

198

Workforce Statistics - NA 1 | National Nuclear Security Administration  

National Nuclear Security Administration (NNSA)

| National Nuclear Security Administration | National Nuclear Security Administration Our Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Continuing Management Reform Countering Nuclear Terrorism About Us Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Media Room Congressional Testimony Fact Sheets Newsletters Press Releases Speeches Events Social Media Video Gallery Photo Gallery NNSA Archive Federal Employment Apply for Our Jobs Our Jobs Working at NNSA Blog Workforce Statistics - NA 1 Home > About Us > Our Operations > Management and Budget > Office of Civil Rights > Workforce Statistics > Workforce Statistics - NA 1 Workforce Statistics - NA 1 NA 1 FY12 NA 1 Semi Annual Report

199

" East North Central",751,"NA",539,650,639,792.21608  

U.S. Energy Information Administration (EIA) Indexed Site

" 60 Years or More","NA","NA",451,554,570,655.17061 "Race of Householder1" " White",723,"NA",547,647,670,787.95276 " Black ",869,"NA",579,695,655,735.14449 " Other...

200

" East North Central",627,"NA",550,553,574,585.28553  

U.S. Energy Information Administration (EIA) Indexed Site

" 60 Years or More","NA","NA",460,466,495,493.22529 "Race of Householder1" " White",610,"NA",556,546,581,592.79398 " Black ",734,"NA",581,578,564,564.24899 " Other...

Note: This page contains sample records for the topic "butyl ether na" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Neutron halos in the Na isotopes  

Science Journals Connector (OSTI)

The neutron and proton density distributions of the Na isotopes out to the proton and neutron drip lines are calculated in the spherical Hartree-Fock model with a wide variety of density-dependent Skyrme interactions. The results are compared to recent experimental data for the interaction cross sections and for the rms radii. We discuss the role of the deformed intruder states and the problems associated with predicting the location of the neutron drip line for this mass region. © 1996 The American Physical Society.

B. A. Brown and W. A. Richter

1996-08-01T23:59:59.000Z

202

Multiphonon Absorption in NaF  

Science Journals Connector (OSTI)

The infrared absorption in NaF at the two CO2 laser wavelengths 10.6 and 9.3 ?m was measured between 4 and 400 K. The results complement the previously measured absorption for higher temperatures, and allow for a detailed comparison with theoretical predictions. The experimental temperature dependence at 10.6 ?m can be excellently fitted by a curve expected for three-phonon processes in the whole temperature range; the absorption at 9.3 ?m fits a mixture of three- and four-phonon processes.

Dieter W. Pohl and Peter F. Meier

1974-01-14T23:59:59.000Z

203

Text na web Zprva esitele o vsledcch esen projektu  

E-Print Network (OSTI)

Text na web Zpr�va esitele o v�sledc�ch esen� projektu ,,Digitalizace a zvysov�n� kvality v�ch pep�nac. 1 #12;Text na web 6. Financn� prostedky pl�novan� na rozs�en� on-line p�stupu do studijn Web of Knowledge, ACM Digital Library, AMS Books Online, MathSciNet, SpringerLink eBooks atd.), kter

Cerveny, Vlastislav

204

Crnica: "A horta na cidade" (Primavera Ambiental 2013)  

E-Print Network (OSTI)

Crónica: "A horta na cidade" (Primavera Ambiental 2013) O pasado mércores 10 de abril tivo lugar na con ADEGA. A actividade que leva por título "A horta na cidade" consistiu nunha conferencia a cargo de, Isabel Barrio explicounos os pros e contras dos diferentes tipos de hortas urbanas, dende as máis básicas

Fraguela, Basilio B.

205

Experimentally determined dissolution kinetics of Na-rich borosilicate...  

NLE Websites -- All DOE Office Websites (Extended Search)

Experimentally determined dissolution kinetics of Na-rich borosilicate glass at far from equilibrium conditions: Implications Experimentally determined dissolution kinetics of...

206

Crnica I Encontro Solar na UDC O pasado mrcores 24 de abril tivo lugar na Praza da Fraga (Campus da  

E-Print Network (OSTI)

Crónica I Encontro Solar na UDC O pasado mércores 24 de abril tivo lugar na Praza da Fraga (Campus da Zapateira) a primeira edición do Encontro Solar na UDC. Esta era a terceira das actividades exposición de aparellos solares, un obradoiro de gastronomía solar, un Roteiro solar pola UDC e un mercadiño

Fraguela, Basilio B.

207

Supporting Information Electric Field Reversal of Na2SO4, (NH4)2SO4, and Na2CO3 relative to CaCl2  

E-Print Network (OSTI)

water 1 M Na2 CO3 1 M Na2 SO4 1 M (NH4 )2 SO4 2 M CaCl2 2 M NaCl Re (2) (a.u.) Incident Infrared (cm -1.8 M CaCl2, 1.8 M NaCl, 1.1 M Na2CO3, 1.1 M Na2SO4, and 1.1 M (NH4)2SO4 salt solutions. ExperimentalS1 Supporting Information Electric Field Reversal of Na2SO4, (NH4)2SO4, and Na2CO3 relative to CaCl

208

Branching ratios for the beta decay of Na-21  

E-Print Network (OSTI)

We have measured the beta-decay branching ratio for the transition from Na-21 to the first excited state of Ne-21. A recently published test of the standard model, which was based on a measurement of the beta-nu correlation in the decay of Na-21...

Iacob, V. E.; Hardy, John C.; Gagliardi, Carl A.; Goodwin, J.; Nica, N.; Park, H. I.; Tabacaru, G.; Trache, L.; Tribble, Robert E.; Zhai, Y.; Towner, I. S.

2006-01-01T23:59:59.000Z

209

Influence of Salt Purity on Na+ and Palmitic Acid Interactions  

E-Print Network (OSTI)

frequency generation (VSFG) spectroscopy. Ultrapure (UP) and ACS grade NaCl salts are used for aqueous the interfacial water structure. These results suggest that the alkali salt grade even after pretreatment to many chemical, biochemical, and atmospheric processes.1-8 Particularly, Na+ and K+ , as the two most

210

Topical Review Voltage Dependence of the Na/K Pump  

E-Print Network (OSTI)

or ``ion well'' hy- pothesis. There are only two ways that net transport can be voltage dependent. Either of the external Na+ and K+ bind- ing sites within the membrane field. This access channel or ``ion well produced by applying a blocking Key words: Na,K-ATPase -- Membrane potential -- Access channel -- Ion well

Gadsby, David

211

Workforce Statistics - NA 20 | National Nuclear Security Administration  

National Nuclear Security Administration (NNSA)

20 | National Nuclear Security Administration 20 | National Nuclear Security Administration Our Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Continuing Management Reform Countering Nuclear Terrorism About Us Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Media Room Congressional Testimony Fact Sheets Newsletters Press Releases Speeches Events Social Media Video Gallery Photo Gallery NNSA Archive Federal Employment Apply for Our Jobs Our Jobs Working at NNSA Blog Workforce Statistics - NA 20 Home > About Us > Our Operations > Management and Budget > Office of Civil Rights > Workforce Statistics > Workforce Statistics - NA 20 Workforce Statistics - NA 20 NA 20 FY12 NA 20 Semi Annual Report

212

Workforce Statistics - NA 40 | National Nuclear Security Administration  

National Nuclear Security Administration (NNSA)

40 | National Nuclear Security Administration 40 | National Nuclear Security Administration Our Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Continuing Management Reform Countering Nuclear Terrorism About Us Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Media Room Congressional Testimony Fact Sheets Newsletters Press Releases Speeches Events Social Media Video Gallery Photo Gallery NNSA Archive Federal Employment Apply for Our Jobs Our Jobs Working at NNSA Blog Workforce Statistics - NA 40 Home > About Us > Our Operations > Management and Budget > Office of Civil Rights > Workforce Statistics > Workforce Statistics - NA 40 Workforce Statistics - NA 40 NA40 FY12 NA 40 Semi Annual Report

213

Workforce Statistics - NA 10 | National Nuclear Security Administration  

National Nuclear Security Administration (NNSA)

0 | National Nuclear Security Administration 0 | National Nuclear Security Administration Our Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Continuing Management Reform Countering Nuclear Terrorism About Us Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Media Room Congressional Testimony Fact Sheets Newsletters Press Releases Speeches Events Social Media Video Gallery Photo Gallery NNSA Archive Federal Employment Apply for Our Jobs Our Jobs Working at NNSA Blog Workforce Statistics - NA 10 Home > About Us > Our Operations > Management and Budget > Office of Civil Rights > Workforce Statistics > Workforce Statistics - NA 10 Workforce Statistics - NA 10 NA 10 FY12 NA 10 Semi Annual Report

214

Otoczenie spoleczne i jego wplyw na wyniki ekonomiczne przedsibiorstwa na przykladzie instytucji nonprofit wiadczcej uslugi lecznicze i rehabilitacyjne.  

E-Print Network (OSTI)

_wyniki_ekonomiczne_przedsi_biorstwa_na_przyk_adzie_instytucji_nonpr ofit_wiadcz_cej_us_ugi_lecznicze_i_rehabilitacyjne_autorstwa_K_Szagdaja_A_Miks a/888478 Recenzja 2: N_wyniki_ekonomiczne_przedsi_biorstwa_na_przyk_adzie_instytucji_nonpr ofit_wiadcz_cej_us_ugi_lecznicze_i_rehabilitacyjne_autorstwa_K_Szagdaja_Recenzj a_2_N_Wenc_a/888477 hal

Paris-Sud XI, Université de

215

On the 21Na(p,gamma)22Mg thermonuclear rate for 22Na production in novae  

E-Print Network (OSTI)

Classical novae are potential sources of gamma-rays, like the 1.275 MeV gamma emission following 22Na beta decay, that could be detected by appropriate instruments on board of future satellites like INTEGRAL. It has been shown that the production of 22Na by novae is affected by the uncertainty on the 21Na(p,gamma)22Mg rate and in particular by the unknown partial widths of the Ex = 5.714 MeV, J^pi = 2^+, 22Mg level. To reduce these uncertainties, we performed shell model calculations with the OXBASH code, compared the results with available spectroscopic data and calculated the missing partial widths. Finally, we discuss the influence of these results on the 21Na(p,gamma)22Mg reaction rate and 22Na synthesis.

Nadya A. Smirnova; Alain Coc

2000-08-16T23:59:59.000Z

216

LANXESS Global Butyl Rubber Research Facility  

E-Print Network (OSTI)

Park, in partnership with Surface Science Western $10million City of London Investment in Fraunhofer- fraunhofer Agreement chosen to highlight celebrations for 40th Anniversary of Canada-Germany cooperation fuel cluster in Sarnia-Lambton, said Sarnia Mayor Mike Bradley, noting the Bioindustrial Innovation

Denham, Graham

217

EA-372 GDF Suez Energy Marketing NA, Inc. | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

2 GDF Suez Energy Marketing NA, Inc. EA-372 GDF Suez Energy Marketing NA, Inc. Order authorizing GDF Suez Energy Marketing NA, Inc. to export electric energy to Canada EA-372 GDF...

218

E-Print Network 3.0 - anseniformes ocorrido na Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

de maior intensidade e freqncia esto na periferia das placas tectnicas. O Brasil se situa numa... posio privilegiada, ou seja, na poro central da Placa...

219

E-Print Network 3.0 - auxilio na descoberta Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

Na ltima dcada, o Projeto Peixes de Bonito junto com vrias... universidades do Brasil e do exterior revelaram numerosos achados. Os mais recentes aconteceram na Expedio...

220

E-Print Network 3.0 - aceleradores na ciencia Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

na ciencia Search Powered by Explorit Topic List Advanced Search Sample search results for: aceleradores na ciencia Page: << < 1 2 3 4 5 > >> 1 ARTIGO INTERNET Aceleradores...

Note: This page contains sample records for the topic "butyl ether na" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Low-Frequency Dielectric Constant of LiF, NaF, NaCl, NaBr, KCl, and KBr by the Method of Substitution  

Science Journals Connector (OSTI)

The 1000-Hz 300°K dielectric constants of some alkali halides were measured to an accuracy of 0.01% by the method of substitution. Reproducibly different values for various crystals of the same type were obtained which varied beyond the experimental error. The ranges of results for various crystals of each type measured are LiF, 9.0355-9.0360; NaF, 5.0719-5.0722; NaCl, 5.8940-5.8956; NaBr, 6.3957-6.3974; KCl, 4.8112-4.8182; and KBr, 4.8735-4.8762. The spread for each type of crystal is thought to be attributable to random trace impurities. The numbers are discussed in the light of past values.

Carl Andeen; John Fontanella; Donald Schuele

1970-12-15T23:59:59.000Z

222

ON RACK COHOMOLOGY P. ETINGOF & M. GRA"NA  

E-Print Network (OSTI)

ON RACK COHOMOLOGY P. ETINGOF & M. GRA"NA Abstract.We prove that the lower bounds for Betti numbers of the rack, qu-theoretical interpretation of t* *he second cohomology group for racks. 1.Introduction

Graña, Matías

223

Surface-polishing process for NaI crystals  

SciTech Connect

Darkening of large arrays of NaI used in high energy physics experiments at SLAC has prompted an investigation of methods for annealing radiation damage. As part of this research, it has been necessary to repolish the flat faces of the NaI crystals. The final polishing parameters are given in this document as well as an indication of some techniques which did not work.

Francis, J.

1982-09-01T23:59:59.000Z

224

Nuclear Double Resonance Study of Na First-Order Quadrupole Splittings in a NaF-LiF Mixed Crystal  

Science Journals Connector (OSTI)

A nuclear magnetic double resonance experiment has been performed to measure the high-field first-order quadrupole splittings of Na23 nuclei located in the vicinity of Li+ substitutional impurities in a single crystal of NaF. The observed quadrupole-shifted frequency of those Na23 nuclei located at (1,0,1)-type sites [relative to the Li+ impurity at the (0,0,0) lattice site] was e2qQh=±(544±10) kHz with an asymmetry parameter ?=0.65±0.05. For those Na23 nuclei at (0,0,2)-type sites, e2qQh=±(856±10) kHz with ?=0. The values of eq and ? thus obtained are compared with theoretical calculations. A mathematical analysis of the high-field double resonance process as it applies to rare, quadrupole-interacting nuclei is also presented.

Kyler F. Nelson and W. D. Ohlsen

1969-04-10T23:59:59.000Z

225

A Complete Basis Set Estimate of Cation-p Bond Strengths: Na+(ethylene) and Na+(benzene)  

SciTech Connect

Large scale second order perturbation theory and couple cluster theory calculations were performed on the Na+(ethylene) and Na+(benzene) complexes in an effort to estimate binding enthalpies in the complete basis set limit. The resulting best estimates are DH0[Na+(ethylene)] = -13.7 ? 0.2 kcal/mol and DH0[Na+(benzene)] = -23.9 ? 0.3 kcal/mol, which include small corrections for core/valence correlation effects. The former value can be compared to a measurement of -10.3 ? 1.0 kcal/mol obtained from collision induced dissociation, while the latter value is approximately midway between the two existing experimental values which differed by 6.5 kcal/mol. For the basis sets considered in this study, the counterpoise-corrected binding energies were found to be in much worse agreement with the complete basis set limit than the raw values.

Feller, David F.

2000-06-02T23:59:59.000Z

226

Effects of Point Defects and Impurities on Kinetics in NaAlH4  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Alanate * Viable hydrogen storage material (5.6 wt%) NaAlH 4 13 Na 3 AlH 6 + 23 Al + H 2 Na 3 AlH 6 3 NaH + Al + 32 H 2 * But: reactions slow - Only happen at too...

227

" East North Central",9.3,"NA",10.1,10.7,11.6,11.85822  

U.S. Energy Information Administration (EIA) Indexed Site

" 60 Years or More","NA","NA",7.9,8.5,9.3,9.47261 "Race of Householder1" " White",9.3,"NA",10.2,10.6,11.5,11.86841 " Black ",9.8,"NA",10.8,11.2,11.2,12.05862 " Other...

228

" East North Central",21.3,"NA",26,27.6,29,32.4  

U.S. Energy Information Administration (EIA) Indexed Site

" 60 Years or More","NA","NA",14.3,23.1,24.9,30.3 "Race of Householder1" " White",115.3,"NA",132.2,135.3,138.6,149.5 " Black ",11,"NA",10.6,12.8,11.2,16.6 " Other...

229

DE-RP52-08NA28091  

NLE Websites -- All DOE Office Websites (Extended Search)

8NA28091 8NA28091 [Submit in Volume I, TAB 2] Attachment L-1 Page 1 of 4 CORPORATE, PARTNERSHIP, JOINT VENTURE CERTIFICATES If the offer is submitted by a corporation, partnership or a Joint Venture, the applicable form provided on the following pages must be completed and submitted in Volume I of the proposal. In the alternative, other evidence must be submitted to substantiate the authority of the person signing the offer. If a corporation, the same officer shall not execute both the offer and the certificate. DE-RP52-08NA28091 [Submit in Volume I, TAB 2] Attachment L-1 Page 2 of 4 CORPORATE CERTIFICATE I, _______________________________________________, certify that I am the Secretary of the

230

Measurement of low-energy Na^+ -- Na total collision rate in an ion--neutral hybrid trap  

E-Print Network (OSTI)

We present measurements of the total elastic and resonant charge-exchange ion-atom collision rate coefficient $k_\\mathrm{ia}$ of cold sodium (\\ce{Na}) with optically-dark low energy \\ce{Na+} ions in a hybrid ion-neutral trap. To determine $k_\\mathrm{ia}$, we measured the trap loading and loss from both a \\ce{Na} magneto-optical trap (MOT) and a linear radio frequency quadrupole Paul trap. We found the total rate coefficient to be $7.4 \\pm 1.9 \\times 10^{-8}$ cm$^3$/s for the type I \\ce{Na} MOT immersed within an $\\approx 140$ K ion cloud and $1.10 \\pm 0.25 \\times 10^{-7}$ cm$^3$/s for the type II \\ce{Na} MOT within an $\\approx 1070$ K ion cloud. Our measurements show excellent agreement with previously reported theoretical fully quantal \\textit{ab initio} calculations. In the process of determining the total rate coefficient, we demonstrate that a MOT can be used to probe an optically dark ion cloud's spatial distribution within a hybrid trap.

Goodman, D S; Kwolek, J M; Blümel, R; Narducci, F A; Smith, W W

2014-01-01T23:59:59.000Z

231

Investigation of thermonuclear $^{18}$Ne($?$,$p$)$^{21}$Na rate via resonant elastic scattering of $^{21}$Na+$p$  

E-Print Network (OSTI)

The $^{18}$Ne($\\alpha$,$p$)$^{21}$Na reaction is thought to be one of the key breakout reactions from the hot CNO cycles to the rp-process in type I x-ray bursts. In this work, the resonant properties of the compound nucleus $^{22}$Mg have been investigated by measuring the resonant elastic scattering of $^{21}$Na+$p$. An 89 MeV $^{21}$Na radioactive beam delivered from the CNS Radioactive Ion Beam Separator bombarded an 8.8 mg/cm$^2$ thick polyethylene (CH$_{2}$)$_{n}$ target. The $^{21}$Na beam intensity was about 2$\\times$10$^{5}$ pps, with a purity of about 70% on target. The recoiled protons were measured at the center-of-mass scattering angles of $\\theta_{c.m.}$$\\approx$175.2${^\\circ}$, 152.2${^\\circ}$, and 150.5${^\\circ}$ by three sets of $\\Delta E$-$E$ telescopes, respectively. The excitation function was obtained with the thick-target method over energies $E_x$($^{22}$Mg)=5.5--9.2 MeV. In total, 23 states above the proton-threshold in $^{22}$Mg were observed, and their resonant parameters were determined via an $R$-matrix analysis of the excitation functions. We have made several new $J^{\\pi}$ assignments and confirmed some tentative assignments made in previous work. The thermonuclear $^{18}$Ne($\\alpha$,$p$)$^{21}$Na rate has been recalculated based on our recommended spin-parity assignments. The astrophysical impact of our new rate has been investigated through one-zone postprocessing x-ray burst calculations. We find that the $^{18}$Ne($\\alpha$,$p$)$^{21}$Na rate significantly affects the peak nuclear energy generation rate, reaction fluxes, as well as the onset temperature of this breakout reaction in these astrophysical phenomena.

L. Y. Zhang; J. J. He; A. Parikh; S. W. Xu; H. Yamaguchi; D. Kahl; S. Kubono; P. Mohr; J. Hu; P. Ma; S. Z. Chen; Y. Wakabayashi; H. W. Wang; W. D. Tian; R. F. Chen; B. Guo; T. Hashimoto; Y. Togano; S. Hayakawa; T. Teranishi; N. Iwasa; T. Yamada; T. Komatsubara; Y. H. Zhang; X. H. Zhou

2014-03-19T23:59:59.000Z

232

Solid-State NMR Molecular Dynamics Characterization of aHighly Chlorine-Resistant Disulfonated Poly(arylene ether sulfone) Random Copolymer Blended with Poly(ethylene glycol) Oligomers for Reverse Osmosis Applications  

Science Journals Connector (OSTI)

(3) However, PAs show a critical weakness to chlorine (e.g., NaOCl) that is added as an oxidizing biocide to remove microorganisms that accumulate on the membrane surface, blocking water flux. ... (6, 10, 11) Hence, BPS-20K, a relatively low DS material, was considered as an alternative RO membrane material owing to its excellent NaCl separation property being similar to that of commercial PA (>99%). ...

Chang Hyun Lee; Justin Spano; James E. McGrath; Joseph Cook; Benny D. Freeman; Sungsool Wi

2011-05-11T23:59:59.000Z

233

Velocity of Second Sound in NaF  

Science Journals Connector (OSTI)

The velocity of drifting second sound and the heat capacity per unit volume are calculated for NaF for temperatures from 0 to 40 °K. The velocity of second sound decreases by 24% as the temperature is increased from 10 to 30 °K, because of the dispersion of the phonon frequency spectrum.

Robert J. Hardy and S. S. Jaswal

1971-06-15T23:59:59.000Z

234

AMERINDIA n35, 2011 La nominalisation en kali'na  

E-Print Network (OSTI)

'na est une langue relativement bien connue grâce aux travaux de Hoff sur le Carib du Surinam (variété du origine commune. Par ailleurs, Hoff (2009) décrit, pour le Carib du Surinam, les constructions

Paris-Sud XI, Université de

235

BIOLOGICAL SAFETY O N/A Biosafety Cabinets  

E-Print Network (OSTI)

: _________________________________________________ _________________________________________________ _________________________________________________ RADIATION SAFETY O N/A ___RS-1 Radioactive Material Inventory / Use Logs out of date ___RS-2 Radioactive Material waste inventory cards improperly filled out ___RS-3 Stock radioactive material not secure ___RS-4 __Accelerator __PressureVessels __HiReactMaterials __Rad Material __PwIndV / __PwTools __>55g Oil __X

Entekhabi, Dara

236

Grant Title: STARR FOUNDATION Funding Opportunity Number: N/A  

E-Print Network (OSTI)

Grant Title: STARR FOUNDATION Funding Opportunity Number: N/A Agency/Department: Starr Foundation Grants Program. Area of Research: The foundation makes grants in the following areas: education, medicine and post-secondary schools. Grants for medicine and health care include capital grants to hospitals

Farritor, Shane

237

Exploring Neutron-Rich Oxygen Isotopes with MoNA  

E-Print Network (OSTI)

The Modular Neutron Array (MoNA) was used in conjunction with a large-gap dipole magnet (Sweeper) to measure neutron-unbound states in oxygen isotopes close to the neutron dripline. While no excited states were observed in 24O, a resonance at 45(2) keV above the neutron separation energy was observed in 23O.

N. Frank; T. Baumann; D. Bazin; J. Brown; P. A. DeYoung; J. E. Finck; A. Gade; J. Hinnefeld; R. Howes; J. -L. Lecouey; B. Luther; W. A. Peters; H. Scheit; A. Schiller; M. Thoennessen

2007-08-20T23:59:59.000Z

238

Investigation of thermonuclear $^{18}$Ne($\\alpha$,$p$)$^{21}$Na rate via resonant elastic scattering of $^{21}$Na+$p$  

E-Print Network (OSTI)

The $^{18}$Ne($\\alpha$,$p$)$^{21}$Na reaction is thought to be one of the key breakout reactions from the hot CNO cycles to the rp-process in type I x-ray bursts. In this work, the resonant properties of the compound nucleus $^{22}$Mg have been investigated by measuring the resonant elastic scattering of $^{21}$Na+$p$. An 89 MeV $^{21}$Na radioactive beam delivered from the CNS Radioactive Ion Beam Separator bombarded an 8.8 mg/cm$^2$ thick polyethylene (CH$_{2}$)$_{n}$ target. The $^{21}$Na beam intensity was about 2$\\times$10$^{5}$ pps, with a purity of about 70% on target. The recoiled protons were measured at the center-of-mass scattering angles of $\\theta_{c.m.}$$\\approx$175.2${^\\circ}$, 152.2${^\\circ}$, and 150.5${^\\circ}$ by three sets of $\\Delta E$-$E$ telescopes, respectively. The excitation function was obtained with the thick-target method over energies $E_x$($^{22}$Mg)=5.5--9.2 MeV. In total, 23 states above the proton-threshold in $^{22}$Mg were observed, and their resonant parameters were determ...

Zhang, L Y; Parikh, A; Xu, S W; Yamaguchi, H; Kahl, D; Kubono, S; Mohr, P; Hu, J; Ma, P; Chen, S Z; Wakabayashi, Y; Wang, H W; Tian, W D; Chen, R F; Guo, B; Hashimoto, T; Togano, Y; Hayakawa, S; Teranishi, T; Iwasa, N; Yamada, T; Komatsubara, T; Zhang, Y H; Zhou, X H

2014-01-01T23:59:59.000Z

239

Thermal stability of the endohedral fullerenes NaC60, NaC70, and PaC60  

Science Journals Connector (OSTI)

Nitrogen and phosphorus atoms enclosed in fullerenes keep their atomic ground-state configuration, and no charge transfer or covalent bonding to the cage occurs. These systems can be dissolved in organic solvents and reacted with addends without losing the atomic character of the guest atom. In this paper, we present a detailed study of the annealing behavior of NaC60, NaC70, PaC60, and of some NaC60 adducts. The disintegration of these systems, as recorded by electron paramagnetic resonance measurements, occurs in the temperature range between 400 K and 600 K. The results are in qualitative agreement with potential energy calculations and confirm the proposed escape mechanism that proceeds via bond formation of the trapped atom with the cage. It is found that other combinations of group-V elements with fullerenes, e.g., NaC84, PaC70, and AsaC60 are not stable at room temperature. The escape mechanism and the possibility of disabling this path are discussed.

M. Waiblinger; K. Lips; W. Harneit; A. Weidinger; E. Dietel; A. Hirsch

2001-01-09T23:59:59.000Z

240

Adsorptive removal of tetrahydrothiophene (THT) and tert-butylmercaptan (TBM) using Na-Y and AgNa-Y zeolites for fuel cell applications  

Science Journals Connector (OSTI)

Adsorptive removal of tetrahydrothiophene (THT) and tert-butylmercaptan (TBM) that are widely used sulfur odorants in pipeline natural gas was studied using AgNa-Y zeolites at ambient temperature and atmospheric pressure. The AgNa-Y were obtained via Ag+-exchange with Na+ of Na-Y at various exchange levels, and the contributions of formed adsorption sites (Ag+, Na+, Ag0, H+, and Ag2O) in the THT and TBM adsorption uptake and selectivity were characterized. THT adsorption strength on these sites followed an order of Ag+ > Na+ ? Ag0 > H+ > Ag2O. The adsorption strength of THT on Na+ sites was sufficiently high, thus an increase in the Ag+-exchange level did not lead to a notable increase in the breakthrough THT uptake. Differently, adsorption of TBM on Na+ sites was weak, whereas that on Ag+ sites was strong. This resulted in a marked increase in the breakthrough TBM uptake with an increase in the Ag+-exchange level, showing an order of magnitude higher uptake on AgNa-Y compared with that on Na-Y. Noticeably, the adsorption strength of THT on these adsorption sites was higher than that of TBM. This resulted in an almost 100% adsorption selectivity for THT over TBM, when these two sulfur species coexisted in the feed stream.

Doohwan Lee; Eun-Yong Ko; Hyun Chul Lee; Soonho Kim; Eun Duck Park

2008-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "butyl ether na" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

E-Print Network 3.0 - atmosfera controlada na Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

for: atmosfera controlada na Page: << < 1 2 3 4 5 > >> 1 coleo explorando o ensino o brasil e o meio ambiente antrtico Summary: Antrtica pgina 15 Aquecimento global na...

242

Thin Porous Metal Sheet-Supported NaA Zeolite Membrane for Water...  

NLE Websites -- All DOE Office Websites (Extended Search)

Thin Porous Metal Sheet-Supported NaA Zeolite Membrane for WaterEthanol Separation. Thin Porous Metal Sheet-Supported NaA Zeolite Membrane for WaterEthanol Separation. Abstract:...

243

Impact of Biodiesel-Based Na on the Selective Catalytic Reduction...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Impact of Biodiesel-Based Na on the Selective Catalytic Reduction (SCR) of NOx Using Cu-zeolite Impact of Biodiesel-Based Na on the Selective Catalytic Reduction (SCR) of NOx Using...

244

Postdoctoral positions fall/winter 2014 Na,K-ATPase turnover and ATP dependence.  

E-Print Network (OSTI)

Postdoctoral positions fall/winter 2014 Na,K-ATPase turnover and ATP and consumption of ATP in relation to Na,K- ATPase activity in neurons and renal epithelial cell systems. Develop

Haviland, David

245

E-Print Network 3.0 - anos na cidade Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

A juventude no o impediu de seguir para a EADS, empresa lder na... disponvel para uso mdico na Europa at 2006. Lus Rocha 38 anos, engenheiro informtico Com 12 anos...

246

In Situ 13C and 23Na Magic Angle Spinning NMR Investigation of...  

NLE Websites -- All DOE Office Websites (Extended Search)

In Situ 13C and 23Na Magic Angle Spinning NMR Investigation of Supercritical CO2 Incorporation in Smectite-Natural Organic In Situ 13C and 23Na Magic Angle Spinning NMR...

247

Low-Angle Neutron Scattering Analysis of Na/K—Atpase in Detergent Solution  

Science Journals Connector (OSTI)

The Na/K—ATPase is a membrane-bound enzyme system found in all eucaryotic cells. This enzyme regulates Na and K concentrations and energy metabolism, as well as controlling the transport of other cellular cons...

J. M. Pachence; B. P. Schoenborn; I. S. Edelman

1984-01-01T23:59:59.000Z

248

E-Print Network 3.0 - atleta na sociedade Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

atleta na sociedade Search Powered by Explorit Topic List Advanced Search Sample search results for: atleta na sociedade Page: << < 1 2 3 4 5 > >> 1 MAC 5710 -Estruturas de Dados e...

249

Fiscalizao e Controle: O Poder Legislativo na Argentina e no Brasil Contemporneos  

E-Print Network (OSTI)

1 Fiscalização e Controle: O Poder Legislativo na Argentina e no Brasil Contemporâneos Charles na Argentina e no Brasil Contemporâneos "La société a le droit de demander compte à tout agent public concentrar-se na análise das novas instituições de controle externo no Brasil e na Argentina, de acordo com o

Paris-Sud XI, Université de

250

Na sup + -K sup + -ATPase-dependent sodium flux in cortical collecting tubule  

SciTech Connect

The instantaneous rate of efflux of intracellular Na was studied in rabbit isolated cortical collecting tubules (CCT) as a function of temperature and intracellular Na concentration ((Na){sub i}). (Na){sub i} of microdissected CCT was increased by cold and K-free exposure in the presence of {sup 22}Na and the extracellular tracer ({sup 3}H)sorbitol. (Na){sub i} rose rapidly to 40 mM at 30 min, after which it rose more slowly, reaching 120-140 mM at 6 h. Kinetics of Na efflux were studied after rapid rewarming, using a special device allowing measurements at 20-s intervals. Under control conditions, the total Na load was extruded in <8 min, whereas, in the presence of 10{sup {minus}4} M ouabain, only 50% of the load was extruded during this period of time. Ouabain-sensitive Na efflux was first evident at 13{degree}C and gradually increased between 13 and 35{degree}C. At 37{degree}C, Na{sup +}-K{sup +}-ATPase-dependent Na efflux was dependent on (Na){sub i}. This efflux gradually increased, from 0.05 to 0.5 peq{center dot}nl tubular volume{sup {minus}1}{center dot}s{sup {minus}1} as a function of (Na){sub i} and reached a plateau at 70 mM (Na){sub i}. It is concluded that (Na){sub i} is a major modulator of the pump activity in CCT; at normal levels of (Na){sub i}, the pump is operating at only a small fraction of its total capacity.

Blot-Chabaud, M.; Jaisser, F.; Gingold, M.; Bonvalet, J.P.; Farman, N. (CEntre d'Etudes Nucleaires de Saclay, Gif sur Yvette (France))

1988-10-01T23:59:59.000Z

251

Caustic Recycle from Hanford Tank Waste Using Large Area NaSICON Structures (LANS)  

SciTech Connect

This report presents the results of a 5-day test of an electrochemical bench-scale apparatus using a proprietary (NAS-GY) material formulation of a (Na) Super Ion Conductor (NaSICON) membrane in a Large Area NaSICON Structures (LANS) configuration. The primary objectives of this work were to assess system performance, membrane seal integrity, and material degradation while removing Na from Group 5 and 6 tank waste from the Hanford Site.

Fountain, Matthew S.; Sevigny, Gary J.; Balagopal, S.; Bhavaraju, S.

2009-03-31T23:59:59.000Z

252

Properties of F Centers in NaF  

Science Journals Connector (OSTI)

A weak intensity emission, centered at 785 m?, is identified as the F photoluminescence in NaF. The temperature dependence of photoionization and photoluminescence of F centers is investigated. Two thermal activation energies are found: ?EL=0.06 eV for the photoluminescence, and ?E1=0.12 eV for the photoionization efficiency. The nature of the quenching mechanism of the F luminescence is discussed.

P. Podini

1966-01-14T23:59:59.000Z

253

Cosmogenic radionuclide production in NaI(Tl) crystals  

E-Print Network (OSTI)

The production of long-lived radioactive isotopes in materials due to the exposure to cosmic rays on Earth surface can be an hazard for experiments demanding ultra-low background conditions, typically performed deep underground. Production rates of cosmogenic isotopes in all the materials present in the experimental set-up, as well as the corresponding cosmic rays exposure history, must be both well known in order to assess the relevance of this effect in the achievable sensitivity of a given experiment. Although NaI(Tl) scintillators are being used in experiments aiming at the direct detection of dark matter since the first nineties of the last century, very few data about cosmogenic isotopes production rates have been published up to date. In this work we present data from two 12.5 kg NaI(Tl) detectors, developed in the frame of the ANAIS project, which were installed inside a convenient shielding at the Canfranc Underground Laboratory just after finishing surface exposure to cosmic rays. The very fast start of data taking allowed to identify and quantify isotopes with half-lives of the order of tens of days. Initial activities underground have been measured and then production rates at sea level have been estimated following the history of detectors; values of about a few tens of nuclei per kg and day for Te isotopes and 22Na and of a few hundreds for I isotopes have been found. These are the first direct estimates of production rates of cosmogenic nuclides in NaI crystals. A comparison of the so deduced rates with calculations using typical cosmic neutron flux at sea level and a carefully selected description of excitation functions will be also presented together with an estimate of the corresponding contribution to the background at low and high energies, which can be relevant for experiments aiming at rare events searches.

J. Amaré; S. Cebrián; C. Cuesta; E. García; C. Ginestra; M. Martínez; M. A. Oliván; Y. Ortigoza; A. Ortiz de Solórzano; C. Pobes; J. Puimedón; M. L. Sarsa; J. A. Villar; P. Villar

2015-01-16T23:59:59.000Z

254

Benchmarking EUV mask inspection beyond 0.25 NA  

SciTech Connect

The SEMATECH Berkeley Actinic Inspection Tool (AIT) is an EUV-wavelength mask inspection microscope designed for direct aerial image measurements, and pre-commercial EUV mask research. Operating on a synchrotron bending magnet beamline, the AIT uses an off-axis Fresnel zoneplate lens to project a high-magnification EUV image directly onto a CCD camera. We present the results of recent system upgrades that have improved the imaging resolution, illumination uniformity, and partial coherence. Benchmarking tests show image contrast above 75% for 100-nm mask features, and significant improvements and across the full range of measured sizes. The zoneplate lens has been replaced by an array of user-selectable zoneplates with higher magnification and NA values up to 0.0875, emulating the spatial resolution of a 0.35-NA 4 x EUV stepper. Illumination uniformity is above 90% for mask areas 2-{micro}m-wide and smaller. An angle-scanning mirror reduces the high coherence of the synchrotron beamline light source giving measured {sigma} values of approximately 0.125 at 0.0875 NA.

Goldberg, Kenneth A.; Mochi, Iacopo; Anderson, Erik H.; Rekawa, Seno B.; Kemp, Charles D.; Huh, S.; Han, H.-S.; Naulleau, P.; Gunion, R.F.

2008-09-18T23:59:59.000Z

255

Actinic EUV mask inspection beyond 0.25 NA  

SciTech Connect

The SEMATECH Berkeley Actinic Inspection Tool (AIT) is an EUV-wavelength mask inspection microscope designed for direct aerial image measurements, and pre-commercial EUV mask research. Operating on a synchrotron bending magnet beamline, the AIT uses an off-axis Fresnel zoneplate lens to project a high-magnification EUV image directly onto a CCD camera. We present the results of recent system upgrades that have improved the imaging resolution, illumination uniformity, and partial coherence. Benchmarking tests show image contrast above 75% for 100-nm mask features, and significant improvements and across the full range of measured sizes. The zoneplate lens has been replaced by an array of user-selectable zoneplates with higher magnification and NA values up to 0.0875, emulating the spatial resolution of a 0.35-NA 4x EUV stepper. Illumination uniformity is above 90% for mask areas 2-{micro}m-wide and smaller. An angle-scanning mirror reduces the high coherence of the synchrotron beamline light source giving measured {sigma} values of approximately 0.125 at 0.0875 NA.

Goldberg, Kenneth A.; Mochi, Iacopo; Anderson, Erik H.; Rekawa, Seno. B.; Kemp, Charles D.; Huh, S.; Han, H.-S.; Naulleau, P.; Huh, S.

2008-03-24T23:59:59.000Z

256

Adsorption of NaCl Vapor at Elevated Temperature on Mineral Adsorbents  

Science Journals Connector (OSTI)

All adsorbents were crunched and sieved to ?1.00–1.25 mm adsorbent granularity used in the experiments. ... NaCl vapor was adsorbed at 1123 K for 5 h by each adsorbent. ... In the presence of chemical adsorption Na+ and Cl? would selectively adsorb and Na+ and Cl? would exist with a different molecule. ...

Yili Li; Jian Li; Shuiyuan Cheng; Wenjun Liang; Yuquan Jin; Youqing Wu; Jinsheng Gao

2007-09-21T23:59:59.000Z

257

Synthesis of na-doped lithium metatitanate and its absorption for carbon dioxide  

Science Journals Connector (OSTI)

Na-doped lithium metatitanate (Na-doped Li2TiO3) absorbent was doped with Na2CO3 and lithium metatitanate (Li2TiO3) was prepared by a solid-state reaction method from mixture of TiO2 ...

Liu Zhirong, Zhang Huan, Wang Yun, Zhan Xinxing

2014-01-01T23:59:59.000Z

258

mTOR Regulates Lysosomal ATP-Sensitive Two-Pore Na+  

E-Print Network (OSTI)

mTOR Regulates Lysosomal ATP-Sensitive Two-Pore Na+ Channels to Adapt to Metabolic State Chunlei cytosolic ATP levels is not well understood. Here, we identify an endolysosomal ATP-sensitive Na+ channel (lysoNaATP). The channel is a complex formed by two-pore channels (TPC1 and TPC2), ion channels

Clapham, David E.

259

E-Print Network 3.0 - ansa-tsirkonotsenov na ikh Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Donata Oertel Summary: saline that contained (in mM) 130 NaCl, 3 KCl, 1.2 KH2PO4, 2.4 CaCl2, 1.3 MgSO4, 20 NaHCO3, 3 HEPES... (Tris salt), 4 ATP (Na salt), and 0.3 GTP (tris...

260

Fairytale Cynicism in the Kingdom of Plastic Bags: Mapping Power and Powerlessness in Chelnochovsk-na-Dniestre, Ukraine  

E-Print Network (OSTI)

Chelnochovsk-na-Dniestre, Ukraine Diana R. Blank Berkeley PChelnochovsk-na-Dniestre, Ukraine Diana R. Blank Spring 2003emerging ethnography on Ukraine is based, and perhaps, in

Blank, Diana R.

2003-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "butyl ether na" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

High Temperature, Low Relative Humidity, Polymer-type Membranes Based on Disulfonated Poly(arylene ether) Block and Random Copolymers Optionally Incorporating Protonic Conducting Layered Water insoluble Zirconium Fillers  

SciTech Connect

Our research group has been engaged in the past few years in the synthesis of biphenol based partially disulfonated poly(arylene ether sulfone) random copolymers as potential PEMs. This series of polymers are named as BPSH-xx, where BP stands for biphenol, S stands for sulfonated, H stands for acidified and xx represents the degree of disulfonation. All of these sulfonated copolymers phase separate to form nano scale hydrophilic and hydrophobic morphological domains. The hydrophilic phase containing the sulfonic acid moieties causes the copolymer to absorb water. Water confined in hydrophilic pores in concert with the sulfonic acid groups serve the critical function of proton (ion) conduction and water transport in these systems. Both Nafion and BPSH show high proton conductivity at fully hydrated conditions. However proton transport is especially limited at low hydration level for the BPSH random copolymer. It has been observed that the diffusion coefficients of both water and protons change with the water content of the pore. This change in proton and water transport mechanisms with hydration level has been attributed to the solvation of the acid groups and the amount of bound and bulk-like water within a pore. At low hydration levels most of the water is tightly associated with sulfonic groups and has a low diffusion coefficient. This tends to encourage isolated domain morphology. Thus, although there may be significant concentrations of protons, the transport is limited by the discontinuous morphological structure. Hence the challenge lies in how to modify the chemistry of the polymers to obtain significant protonic conductivity at low hydration levels. This may be possible if one can alter the chemical structure to synthesize nanophase separated ion containing block copolymers. Unlike the BPSH copolymers, where the sulfonic acid groups are randomly distributed along the chain, the multiblock copolymers will feature an ordered sequence of hydrophilic and hydrophobic segments. If, like in Nafion, connectivity is established between the hydrophilic domains in these multiblock copolymers, they will not need as much water, and hence will show much better protonic conductivity than the random copolymers (with similar degree of sulfonation, or IEC) at partially hydrated conditions. The goal of this research is to develop a material suitable for use as a polymer electrolyte membrane which by the year 2010 will meet all the performance requirements associated with fuel cell operation at high temperatures and low relative humidity, and will out-perform the present standard Nafion{reg_sign}. In particular, it is our objective to extend our previous research based on the use of thermally, oxidatively, and hydrolytically, ductile, high Tg ion containing polymers based on poly(arylene ethers) to the production of polymer electrolyte membranes which will meet all the performance requirements in addition to having an areal resistance of < 0.05 ohm-cm{sup 2} at a temperature of up to 120 C, relative humidity of 25 to 50%, and up to 2.5 atm total pressure. In many instances, our materials already out performs Nafion{reg_sign}, and it is expected that with some modification by either combining with conductive inorganic fillers and/or synthesizing as a block copolymer it will meet the performance criteria at high temperatures and low relative humidity. A key component in improving the performance of the membranes (and in particular proton conductivity) and meeting the cost requirements of $40/m{sup 2} is our development of a film casting process, which shows promise for generation of void free thin films of uniform thickness with controlled polymer alignment and configuration.

McGrath, James E.; Baird, Donald G.

2010-06-03T23:59:59.000Z

262

Beta-Gamma-Angular Correlation in Na-20  

E-Print Network (OSTI)

I r' 2.2 fhm l diameter. The collimators were separated by 5 mm and the second one was located 1.6 mm from the catcher foil. Five catcher foils were attached to a foil holder assembly (see Fig. 1) with a spac- ing of 72' between each foil...-jet technique through a Teflon capillary 1.78 mm in diameter and ~3 m long. The experimental geometry is shown in Fig. 1. The source was produced by depositing the "Na activity on 0.0064 mm aluminized Mylar catcher foils. The source size was defined by a...

Tribble, Robert E.; May, D. P.; Tanner, D. M.

1981-01-01T23:59:59.000Z

263

NA Standards | Valence Geometries | Bond Angles-Furanose Rings  

NLE Websites -- All DOE Office Websites (Extended Search)

angles in Furanose Rings angles in Furanose Rings ----------------------------------------------------- ribose deoxyribose ----------------------------------------------------- angle mean esd N mean esd N value value ----------------------------------------------------- C1'-C2'-C3' 101.5 (0.9, 80) 102.7 (1.4, 47) C2'-C3'-C4' 102.7 (1.0, 80) 103.2 (1.0, 47) C3'-C4'-O4' 105.5 (1.4, 80) 105.6 (1.0, 47) C4'-O4'-C1' 109.6 (0.9, 80) 109.7 (1.4, 47) O4'-C1'-C2' 106.4 (1.4, 80) 106.1 (1.0, 47) C1'-C2'-O2' 110.6 (3.0, 80) na C3'-C2'-O2' 113.3 (2.9, 80) na C2'-C3'-O3' 111.0 (2.8, 80) 110.6 (2.7, 47) C4'-C3'-O3' 110.6 (2.6, 80) 110.3 (2.2, 47) C5'-C4'-C3' 115.5 (1.5, 80) 114.7 (1.5, 47)

264

Simultaneous Efficiency, NOx, and Smoke Improvements through Diesel/Gasoline Dual-Fuel Operation in a Diesel Engine  

E-Print Network (OSTI)

or liquefied petroleum gas, natural gas, biogas, hydrogen, and alcohols such as methanol, ethanol, iso-propanol, and n-butanol), and fuel additives (MTBE or methyl tertiary-butyl ether, H2O2 or hydrogen peroxide, 2-EHN or ethylhexyl nitrate and DTBP or di...

Sun, Jiafeng

2014-08-05T23:59:59.000Z

265

Drinking Water Problems: MTBE  

E-Print Network (OSTI)

Methyl tertiary-butyl ether, a gasoline additive commonly known as MTBE, can contaminate ground water and cause health problems for those exposed to it for a long time. However, filtering devices can remove this and other additives from well water...

Dozier, Monty; Lesikar, Bruce J.

2008-08-28T23:59:59.000Z

266

Role of Volatilization in Changing TBA and MTBE Concentrations at  

E-Print Network (OSTI)

a low affinity for gasoline (low Kfw, Table 1). Therefore, minute amounts of TBA in the MTBE blended tertiary butyl ether (MTBE) added to gasoline. Frequent observations of high TBA, and especially rising TBA/MTBE concentration ratios, in groundwater at gasoline spill sites are generally attributed to microbial conversion

267

Water Research 37 (2003) 37563766 Seasonal and daily variations in concentrations of methyl-  

E-Print Network (OSTI)

by volume to gasoline from November to February, and blending 11% MTBE by volume during the rest of the year; accepted 24 March 2003 Abstract Methyl-tertiary-butyl ether (MTBE), an additive used to oxygenate gasoline of gasoline-powered watercraft. This paper documents and explains both seasonal and daily variations in MTBE

Toran, Laura

268

Critical Reviews in Environmental Science and Technology, 00(0):000000 (2001) 1064-3389/01/$.50  

E-Print Network (OSTI)

-3389/01/$.50 © 2001 by CRC Press LLC The Transport and Fate of Ethanol and BTEX in Groundwater Contaminated by Gasohol water contamination by methyl tert-butyl ether (MTBE) have made policymakers more cognizant of the need). It has been discovered that MTBE is a ubiquitous contaminant in surface and ground waters throughout

Alvarez, Pedro J.

269

UMass builds bugs to eat MTBE ByAuriaCimino  

E-Print Network (OSTI)

a toxic gasoline component might be just what the doctor ordered for Maine's con- taminated groundwater with methyl tertiary butyl ether (MTBE), which is found in gasoline. Once the first field trial is complete out of the reformulated gasoline pro- gram (RFG) .The gasoline, which con- tains 11 percent MTBE

Lovley, Derek

270

Motor Gasoline Outlook and State MTBE Bans  

Reports and Publications (EIA)

The U.S. is beginning the summer 2003 driving season with lower gasoline inventories and higher prices than last year. Recovery from this tight gasoline market could be made more difficult by impending state bans on the blending of methyl tertiary butyl ether (MTBE) into gasoline that are scheduled to begin later this year.

2003-01-01T23:59:59.000Z

271

Water Research Institute Annual Technical Report  

E-Print Network (OSTI)

Air Act mandated oxygenated gasoline containing methyl tert-butyl ether (MtBE) in certain areas percent. The State of Maine elected to use reformulated gasoline (RFG) that contained at least 11 percent and by 1995, oxygenated gasoline use was common in the northeast. Soon after the widespread use of gasoline

272

Bulk and track etch properties of CR-39 SSNTD etched in NaOH/ethanol  

E-Print Network (OSTI)

Bulk and track etch properties of CR-39 SSNTD etched in NaOH/ethanol K.F. Chan, F.M.F. Ng, D. described the use of NaOH/ethanol as an etchant for the CR-39 detector, and have determined the corre and track etch properties of CR- 39 in NaOH/ethanol were derived from direct measurements. The bulk etch

Yu, K.N.

273

Determination of the composition of H2 O-NaCl-CaCl2  

E-Print Network (OSTI)

Determination of the composition of H2 O-NaCl-CaCl2 fluid inclusions based on microthermometric fluids in which NaCl and CaCl2 are the two most abundant salts and which may be adequately described by the system H2 O-NaCl-CaCl2 are common in many geologic environments. The best source of information

Bodnar, Robert J.

274

2012 Annual Workforce Analysis and Staffing Plan Report - NNSA NA-40  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

2 2 Reporting Office: NNSA NA-40 Section One - Current Mission (s) of the Organization and Potential Changes. 1. The Office of Emergency Operations (NA-40) administers and directs DOE and NNSA programs for emergency response capabilities to ensure availability and viability to respond to emergencies at DOE and NNSA facilities and field sites, and to nuclear and radiological emergencies within the United States and abroad. NA-40 is also responsible for the development of Departmental policy and guidance, technical assistance, and supporting implementation of emergency management planning, preparedness, readiness assurance, and response activities within DOE and NNSA. 2. NA-40 has no nuclear or radiological facilities under its cognizance; however,

275

E-Print Network 3.0 - agem na demanda Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

Collection: Mathematics 2 Descrio original: Chaetodon tricolor Bloch, 1795, tipo do Brasil. CARACTERSTICAS DIAGNOSTIC CHARACTERS Summary: filamento na extremidade de cada lobo,...

276

E-Print Network 3.0 - abordagem multiescala na Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Sciences 2 Analise de formas representadas por marcos Summary: oria Natural do Brasil", 23) 2.2 Tipos de Dados em Morfometria Apesar da principal abordagem na...

277

E-Print Network 3.0 - armas brasileiras na Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

Collection: Engineering 2 Metas Brasileiras de Reduo de Emisses de GEE Summary: no Brasil 1. Metas Brasileiras Cenrio com Meta de Reduo do Desmatamento na Amaznia...

278

E-Print Network 3.0 - ambiental na costa Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

for Systems and Robotics, Lisboa Collection: Engineering 3 coleo explorando o ensino o brasil e o meio ambiente antrtico Summary: Dados Internacionais de Catalogao na...

279

E-Print Network 3.0 - anomalia geologica na Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

Wancura Barbieri 1 Summary: a variabilidade da precipitao na regio Sul do Brasil podendo ser responsveis por anomalias positivas e... . Para a definio das...

280

E-Print Network 3.0 - aplicacao na medida Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

Energia em Clusters Web Dorgival Guedes , Wagner Meira Jr. , Diego Nogueira , Rodrigo Pereira Summary: na Figura 2. Os tres elemen- tos principais sao a aplicacao...

Note: This page contains sample records for the topic "butyl ether na" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

E-Print Network 3.0 - aleitamento materno na Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

Anthology Collection: Computer Technologies and Information Sciences 2 ROBERTA MARIA PEREIRA LEITE CICLO ESTRAL E MENSTRUAL: REPERCUSSO DA Summary: em ambos os grupos. Na...

282

E-Print Network 3.0 - adultos na coorte Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

tem 2400 m de cerca e quer cercar um campo retangular que est na margem ... Source: Pereira, Marcone Corra - Departamento de Matemtica, Universidade de So Paulo...

283

E-Print Network 3.0 - atendidas na rede Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

Aplicacoes P2P Emilio Francesquini, Francisco Reverbel Summary: robustas. Mesmo entre redes do mesmo tipo, existem diferencas significativas na maneira pela qual elas... IP...

284

E-Print Network 3.0 - aspectos na tomografia Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

desenvolvimento da Tomografia Acustica Oceanica (ing. OAT, Ocean Acoustic Tomogra- phy) na forma de MFT ou MFI... passiva e localizacao de navios e submarinos,...

285

Formation and Structural Analysis of a Surface Alloy: Al(111)-(2 × 2)-Na  

Science Journals Connector (OSTI)

The Al(111)-(2 × 2)-Na phase formed by adsorption of one-half monolayer Na at 300 K is shown to be a surface alloy. Quantitative agreement is achieved between the results of structure determinations by low energy electron diffraction, surface extended x-ray adsorption fine structure, and total energy calculations. The first four layers of the structure are shown to consist of a Na-Al-Na sandwich on a reconstructed Al substrate layer. It is suggested that the formation of the structure involves surface steps as sources of Al atoms.

J. Burchhardt; M. M. Nielsen; D. L. Adams; E. Lundgren; J. N. Andersen; C. Stampfl; M. Scheffler; A. Schmalz; S. Aminpirooz; J. Haase

1995-02-27T23:59:59.000Z

286

E-Print Network 3.0 - alta energia na Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

e coalescem, dever ser um dos... fenmenos mais tremendos na natureza. Vtor Cardoso e o seu grupo ... Source: Institute for Systems and Robotics, Lisboa Collection:...

287

E-Print Network 3.0 - arsenazo iii na Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

Phototriggerable Diplasmalogen Liposomes Summary: a (Bchl), Arsenazo III (AIII), NaCl, CaCl2, human fibrinogen (93% clottable), tissue transglutaminase... + was no longer detected...

288

E-Print Network 3.0 - adubo na perspectiva Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

Computer Technologies and Information Sciences 30 Vitor Barata Ribeiro Blanco Barroso Gerao de Sombras em Tempo Real para Modelos CAD Summary: perspectiva, como na idia...

289

E-Print Network 3.0 - ao cultural na Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

DO SUL INSTITUTO DE INFORM ' Summary: -orientador Porto Alegre, outubro de 1994. 12; 2 CIP - CATALOGA C AO NA PUBLICA C AO Bordini, Rafael Heitor... Bandeira da Silva)...

290

E-Print Network 3.0 - amendoim forrageiro na Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

autorais (Lei n 9.610). Dados Internacionais de Catalogao na Publicao (CIP) ... Source: Instituto Nacional de Pesquisas Espaciais, Laboratrio Associado de...

291

E-Print Network 3.0 - auto-estima na funcionalidade Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

das melhores prticas da... destacar o crescimento significativo da certificao ISO 9001 ABNT, 1994 na indstria de ... Source: Endler, Markus - Departamento de...

292

High Energy Density Na-S/NiCl2 Hybrid Battery  

SciTech Connect

High temperature (250-350°C) sodium-beta alumina batteries (NBBs) are attractive energy storage devices for renewable energy integration and other grid related applications. Currently, two technologies are commercially available in NBBs, e.g., sodium-sulfur (Na-S) battery and sodium-metal halide (ZEBRA) batteries. In this study, we investigated the combination of these two chemistries with a mixed cathode. In particular, the cathode of the cell consisted of molten NaAlCl4 as a catholyte and a mixture of Ni, NaCl and Na2S as active materials. During cycling, two reversible plateaus were observed in cell voltage profiles, which matched electrochemical reactions for Na-S and Na-NiCl2 redox couples. An irreversible reaction between sulfur species and Ni was identified during initial charge at 280°C, which caused a decrease in cell capacity. The final products on discharge included Na2Sn with 1< n < 3, which differed from Na2S3 found in traditional Na-S battery. Reduction of sulfur in the mixed cathode led to an increase in overall energy density over ZEBRA batteries. Despite of the initial drop in cell capacity, the mixed cathode demonstrated relatively stable cycling with more than 95% of capacity retained over 60 cycles under 10mA/cm2. Optimization of the cathode may lead to further improvements in battery performance.

Lu, Xiaochuan; Lemmon, John P.; Kim, Jin Yong; Sprenkle, Vincent L.; Yang, Zhenguo (Gary) [Gary

2013-02-15T23:59:59.000Z

293

Impact of Biodiesel-Based Na on the Selective Catalytic Reduction...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

in B100 * Potential NaK emissions control effects - Ash accumulation in DPF - Alkali absorption into monolith walls * possible weakening of monolith - Catalyst poisoning...

294

E-Print Network 3.0 - amazonicus characidae na Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Epipedobates trivittatus Peru AF128570 AF128569 AF128571 NA Dendrobates arboreus Panama AF128611 Source: Brown, Jason - Department of Ecology and Evolutionary Biology,...

295

2011 Annual Planning Summary for NNSA, Infrastructure and Environment (NA-50)  

Energy.gov (U.S. Department of Energy (DOE))

The ongoing and projected Environmental Assessments and Environmental Impact Statements for 2011 and 2012 within NNSA, Infrastructure and Environment (NA-50).

296

E-Print Network 3.0 - adquirida aspectos na Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

valorizados na apreciao qualitativa que os ... Source: Instituto de Sistemas e Robotica - Polo de Lisboa (Institute for Systems and Robotics, Lisbon pole) Portugal...

297

E-Print Network 3.0 - atendidos na unidade Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

...42 3.3 Problemas enfrentados pelas Unidades na Execuo do PAA 2005 e sugestes encaminhadas ... ... Source: Ayala-Rincn, Mauricio - Departamento...

298

E-Print Network 3.0 - aplicacao na padronizacao Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

em producao na construcao de dezenas de aplicacoes entregues a ind'ustria. Neste ... Source: Endler, Markus - Departamento de Informtica, Pontifcia Universidade...

299

E-Print Network 3.0 - albopictus skuse na Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

by Explorit Topic List Advanced Search Sample search results for: albopictus skuse na Page: << < 1 2 3 4 5 > >> 1 Biological Invasions 3: 151166, 2001. 2002 Kluwer Academic...

300

E-Print Network 3.0 - aedes albopictus na Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

by Explorit Topic List Advanced Search Sample search results for: aedes albopictus na Page: << < 1 2 3 4 5 > >> 1 Biological Invasions 3: 151166, 2001. 2002 Kluwer Academic...

Note: This page contains sample records for the topic "butyl ether na" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

E-Print Network 3.0 - abordagem interdisciplinar na Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

do Programa. 2. DO NMERO DE... : a) - Pluralismo Jurdico e Direito Achado na Rua (Linha de ... Source: Maier, Rudolf Richard - Departamento de Matemtica, Universidade...

302

Structure of the F Center in NaF  

Science Journals Connector (OSTI)

The electron-nuclear double resonance (ENDOR) method is applied to the study of the structure of the F center in NaF. Hyperfine interactions between the F-center electron and a number of the surrounding nuclear shells are presented and compared with the results of earlier experiments and with theory. It is found that the resolved hyperfine structure is not due to the predominance of the first-shell interaction, as has been thought, but it arises from the fortuitous equality of the first- and second-shell isotropic hyperfine interactions. Electron paramagnetic resonance (EPR) absorption measurements of the resolved structure confirms an expected 31-line resolved pattern. The exceptional resolution found in the ENDOR spectrum permits the identification of interactions with nuclei well beyond the eighth shell. Although the samples also contained large numbers of M centers, no evidence for a paramagnetic M center was found in either the EPR or ENDOR spectra.

William T. Doyle

1963-07-15T23:59:59.000Z

303

High precision measurements of Na-26 beta(-) decay  

E-Print Network (OSTI)

PHYSICAL REVIEW C 71, 044309 (2005) High precision measurements of 26Na ?? decay G. F. Grinyer,1,? C. E. Svensson,1 C. Andreoiu,1 A. N. Andreyev,2 R. A. E. Austin,3,? G. C. Ball,2 R. S. Chakrawarthy,2 P. Finlay,1 P. E. Garrett,1,2 G. Hackman,2 J.... C. Hardy,4 B. Hyland,1 V. E. Iacob,4 K. A. Koopmans,3 W. D. Kulp,5 J. R. Leslie,6 J. A. Macdonald,2 A. C. Morton,2 W. E. Ormand,7 C. J. Osborne,2 C. J. Pearson,2 A. A. Phillips,1 F. Sarazin,2,? M. A. Schumaker,1 H. C. Scraggs,2,? J. Schwarzenberg,8...

Grinyer, GF; Svensson, CE; Andreoiu, C.; Andreyev, AN; Austin, RAE; Ball, GC; Chakrawarthy, RS; Finlay, P.; Garrett, PE; Hackman, G.; Hardy, John C.; Hyland, B.; Iacob, VE; Koopmans, KA; Kulp, WD; Leslie, JR; Macdonald, JA; Morton, AC; Ormand, WE; Osborne, CJ; Pearson, CJ; Phillips, AA; Sarazin, F.; Schumaker, MA; Scraggs, HC; Schwarzenberg, J.; Smith, MB; Valiente-Dobon, JJ; Waddington, JC; Wood, JL; Zganjar, EF.

2005-01-01T23:59:59.000Z

304

NA-ASC-100R-04-Vol.1-Rev.0  

National Nuclear Security Administration (NNSA)

100R-04-Vol.1-Rev.0 100R-04-Vol.1-Rev.0 August 2004 SAND 2004-3740P Issued by Sandia National Laboratories for NNSA's Office of Advanced Simulation & Computing, NA-114. For more information, contact Dr. Dimitri Kusnezov at dimitri.kusnezov@nnsa.doe.gov ON THE COVER: These experimental images show the evolution of three gaseous cylinders (seeded with a tracer gas) that have been accelerated by a planar shock wave. The flow fields are dominated by vortices created by the shock acceleration, so the swirling red flows are the SF6 gas being entrained by the vortices. The yellow is air. Each photo consists of two snapshots of the flow at two times (with time interval about 200 microseconds). These images are produced by a laser-induced fluorescence technique. In each image the structures are traveling from left to right at speeds of 100 m/s.

305

Mechanisms of gas permeation through polymer membranes. Progress report, July 1, 1985-May 31, 1986. [CH/sub 4/, C/sub 2/H/sub 6/, n-C/sub 4/H/sub 10/, CO/sub 2/ in poly(n-butyl methacrylate)  

SciTech Connect

The work described is concerned with the significant changes in these mechanisms in the glass-transition range. Permeability, diffusion, and solubility coefficients for CH/sub 4/, C/sub 2/H/sub 4/, C/sub 2/H/sub 6/, and n-C/sub 4/H/sub 10/ in poly(n-butyl methacrylate) (PnBMA) were determined at pressures up to 25 atm and from -14/sup 0/ to 50/sup 0/C. Solubility was also determined for CO/sub 2/ in PnBMA at pressures up to 25 atm and at -10/sup 0/ and 30/sup 0/C. No significant changes were observed in the pressure (or concentration) and temperature dependence of the permeability, diffusion, and solubility coefficients for CH/sub 4/, C/sub 2/H/sub 6/, and n-C/sub 4/H/sub 10/ in the glass-transition range of PnBMA, or when the temperature was lowered below T/sub g/. Moreover, these gas/polymer systems do not exhibit below T/sub g/ the usual ''dual-mode'' sorption behavior of gases in glassy polymers. The solubility isotherm for CO/sub 2/ in PnBMA at -10/sup 0/C and lower pressures suggests incipient dual-mode sorption. Results are exceptions to dual-mode sorption behavior and may be due to small difference in the coefficients of thermal expansion of PnBMA above and below T/sub g/. This indicates that the unrelaxed domains in glassy PnBMA are very small. A ''free-volume'' mechanism describes the dependence of C/sub 2/H/sub 6/ permeability on P, T both above and below the glass transition of PnBMA. Adsorption/desorption kinetics are Fickian.

Stern, S.A.; Vakil, U.; Zhou, S.

1986-05-01T23:59:59.000Z

306

Table Definitions, Sources, and Explanatory Notes  

Gasoline and Diesel Fuel Update (EIA)

Ethanol Plant Production Ethanol Plant Production Definitions Key Terms Definition Barrel A unit of volume equal to 42 U.S. gallons. Fuel Ethanol An anhydrous alcohol (ethanol with less than 1% water) intended for gasoline blending as described in the Oxygenates definition. Oxygenates Substances which, when added to gasoline, increase the amount of oxygen in that gasoline blend. Ethanol, Methyl Tertiary Butyl Ether (MTBE), Ethyl Tertiary Butyl Ether (ETBE), and methanol are common oxygenates. Fuel Ethanol: Blends of up to 10 percent by volume anhydrous ethanol (200 proof) (commonly referred to as the "gasohol waiver"). Methanol: Blends of methanol and gasoline-grade tertiary butyl alcohol (GTBA) such that the total oxygen content does not exceed 3.5 percent by weight and the ratio of methanol to GTBA is less than or equal to 1. It is also specified that this blended fuel must meet ASTM volatility specifications (commonly referred to as the "ARCO" waiver).

307

n-Selective Single Capture Following Xe{sup 18+} And Xe{sup 54+} Impact On Na(3s) And Na*(3p)  

SciTech Connect

State selective single charge exchange n-level cross sections are calculated for collisions of Xe18+ and Xe54+ ions with Na(3s) and Na*(3p) over the energy range of 0.1 to 10.0 keV/amu. The CTMC method is used which includes all two-body interactions. Experimental state-selective cross sections and their corresponding transverse momentum spectra for Xe18+ are found to be in reasonable accord with the calculations.

Otranto, S. [CONICET and Dto. de Fisica, Universidad Nacional del Sur, 8000 Bahia Blanca (Argentina); Olson, R. E. [Physics Department, Missouri University of Science and Technology, Rolla, MO 65401 (United States); Hasan, V. G.; Hoekstra, R. [KVI-Atomic and Molecular Physics, University of Groeningen (Netherlands)

2011-06-01T23:59:59.000Z

308

Molecular dynamics investigation of Na{sup +} in Na{sub 2}Ni{sub 2}TeO{sub 6}  

SciTech Connect

An inter-atomic potential for Na{sub 2}Ni{sub 2}TeO{sub 6} in the Parrinello- Rahman-Vashishta (PRV) model is parameterized empirically. The potential reproduces variety of structural and transport properties of that material in good agreement with recent experimental results. The study provides fresh insights on the migration channels and mechanism of Na{sup +} in the system.

Sau, Kartik, E-mail: padmakumarp@iitg.ernet.in; Kumar, P. Padma, E-mail: padmakumarp@iitg.ernet.in [Department of Physics, Indian Institute of Technology Guwahati, Guwahati-781039 (India)

2014-04-24T23:59:59.000Z

309

Grant Title: DOLLAR GENERAL LITERACY GRANTS Funding Opportunity Number: N/A  

E-Print Network (OSTI)

Grant Title: DOLLAR GENERAL LITERACY GRANTS Funding Opportunity Number: N/A Agency/Department: Dollar General. Area of Research: Literacy grants. Release and Expiration: N/A Application Deadline: Family Literacy: Annually in March. Adult Literacy Grants: Annually in March. Youth Literacy Grants

Farritor, Shane

310

Born?Oppenheimer Molecular Dynamics of the Hydration of Na+ in a Water Cluster  

Science Journals Connector (OSTI)

Born?Oppenheimer Molecular Dynamics of the Hydration of Na+ in a Water Cluster ... The hydration of Na+ in a water cluster is studied through all-electron Born?Oppenheimer molecular dynamics. ... The method chosen in the present study was all-electron, density functional theory based, Born?Oppenheimer molecular dynamics (BOMD). ...

N. Galamba; B. J. Costa Cabral

2009-11-23T23:59:59.000Z

311

Modeling of Hydrogen Storage Materials: A Reactive Force Field for NaH  

E-Print Network (OSTI)

Modeling of Hydrogen Storage Materials: A Reactive Force Field for NaH Ojwang' J.G.O.*, Rutger van is the fall in potential energy surface during heating. Keywords: hydrogen storage, reactive force field governing hydrogen desorption in NaH. During the abstraction process of surface molecular hydrogen charge

Goddard III, William A.

312

Temperature effect on U(VI) sorption onto Na-bentonite1 Ziqian Yang a  

E-Print Network (OSTI)

1 Temperature effect on U(VI) sorption onto Na-bentonite1 Ziqian Yang a , Lei Huang a , Zhijun Guo Nantes/Université de5 Nantes, 4 rue Alfred Kastler, BP 20722, 44307 Nantes, France6 Sorption / U(VI ) / Na-bentonite / Temperature effect / Surface complexation model7 Summary8 U(VI) sorption on a purified

Boyer, Edmond

313

The Catalytic Chemistry of HCN+NO over Na- and Ba-Y, FAU: An...  

NLE Websites -- All DOE Office Websites (Extended Search)

The Catalytic Chemistry of HCN+NO over Na- and Ba-Y, FAU: An In Situ FTIR and TPDTPR Study. The Catalytic Chemistry of HCN+NO over Na- and Ba-Y, FAU: An In Situ FTIR and TPDTPR...

314

Stability of graphene band structures against an external periodic perturbation: Na on graphene  

Science Journals Connector (OSTI)

The electronic structure of Na-adsorbed graphenes formed on the 6H-SiC(0001) substrate was studied using angle-resolved photoemission spectroscopy with synchrotron photons and ab initio pseudopotential calculations. It was found that the band of the graphenes sensitively changes upon Na adsorption especially at low temperature. With increasing Na dose, the ? band appears to be quickly diffused into the background at 85 K whereas it becomes significantly enhanced with its spectral intensity at room temperature (RT). A new parabolic band centered at k?1.15?Å?1 also forms near Fermi energy with Na at 85 K while no such band was observed at RT. Such changes in the band structure are found to be reversible with temperature. The changes in the ? band of graphene are mainly driven by the Na-induced potential especially at low temperature where the potential becomes periodic due to the crystallized Na overlayer. The new parabolic band turns out to be the ? band of the underlying buffer layer partially filled by the charge transfer from Na adatoms. The increase in the hopping rate of Na adatoms at RT by 5 orders of magnitude prevents such a charge transfer, explaining the absence of the new band at RT.

C. G. Hwang; S. Y. Shin; Seon-Myeong Choi; N. D. Kim; S. H. Uhm; H. S. Kim; C. C. Hwang; D. Y. Noh; Seung-Hoon Jhi; J. W. Chung

2009-03-27T23:59:59.000Z

315

Application Of An Artificial Neural Network Model To A Na-K Geothermometer  

Open Energy Info (EERE)

Application Of An Artificial Neural Network Model To A Na-K Geothermometer Application Of An Artificial Neural Network Model To A Na-K Geothermometer Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: Application Of An Artificial Neural Network Model To A Na-K Geothermometer Details Activities (3) Areas (2) Regions (0) Abstract: A new geothermometer model is proposed by applying data obtained from a known Na-K geothermometer to an artificial neural network. In this model, Na and K values were implemented as input signals and geothermometers as the output signal. Multi-layer perceptrons and back propagation were used as training algorithms for the artificial neural network. Reservoir temperatures of some geothermal fields in Turkey determined by this method are in accord with those determined from other methods.

316

A New Improved Na-K Geothermometer By Artificial Neural Networks | Open  

Open Energy Info (EERE)

Improved Na-K Geothermometer By Artificial Neural Networks Improved Na-K Geothermometer By Artificial Neural Networks Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: A New Improved Na-K Geothermometer By Artificial Neural Networks Details Activities (0) Areas (0) Regions (0) Abstract: A new Na/K geothermometer equation has been developed. The temperature function is:Concentrations are in mg/kg. The new improved geothermometer equation was developed by artificial neural networks. The normalized mean square error (NMSE) used in the new improved Na/K equation for temperatures ranging from 94 to 345°C is 0.179, which is lower than the corresponding NMSE 0.226, 0.598, 0.656, 0.268, 0.328 and 0.225 for the equations of Arnorsson et al. (1983; Geochim. Cosmochim. Acta 47, 567-577), Truesdell (1975; Proc. 2nd UN Symposium), Tonani (1980; Proc. Adv. Eur.

317

Concentration and precipitation of NaCl and KCl from salt cake leach solutions by electrodialysis  

SciTech Connect

Electrodialysis was investigated for cost-effective recovery of salt from salt cake leach solutions. (Salt cake is a waste stream generated by the aluminum industry during treatment of aluminum drosses and scrap.) We used a pilot-scale electrodialysis stack of 5 membrane pairs, each with an effective area of 0.02 m{sup 2}. The diluate stream contained synthetic NaCl, KCl,mixtures of NaCl and KCl, and actual salt cake leach solutions (mainly NaCl and KCl, with small amounts of MgCl{sub 2}). We concentrated and precipitated NaCl and KCl salts from the concentrate steam when the initial diluate stream concentration was 21.5 to 28.8 wt% NaCl and KCl. We found that water transferring through the membranes was a significant factor in overall efficiency of salt recovery by electrodialysis.

Sreenivasarao, K; Patsiogiannis, F.; Hryn, J.N.

1997-02-09T23:59:59.000Z

318

What the NA60 dilepton data can tell  

E-Print Network (OSTI)

The NA60 experiment has studied low-mass muon pair production in In-In collisions at 158 AGeV with unprecedented precision. Thus, there is hope that the in-medium modifications of the vector meson spectral function can be constrained more thoroughly than from previous experiments. Towards this goal, we present a study comparing different models for the in-medium modification of vector mesons. In particular, we investigate what can be learned about collisional broadening by a medium at finite temperature and baryon density and what model independent constraints can be obtained from the data. Of special relevance is a comparison to $p_T$-cuts of the dilepton spectra. Those not only provide independent tests of the evolution model and $p_T$-dependence of the spectral function but also unambiguously decide if the observed yield in the higher mass spectrum $M > 1 {\\rm GeV}$ is mainly due to the hot phase of the evolution or four pion annihilation processes.

Thorsten Renk; Jorg Ruppert

2006-05-11T23:59:59.000Z

319

Der Briefwechsel zwischen Sidonie Na?dherny? und Albert Bloch : September 1947-September 1950 : mit einer Einfu?hrung in die Widmungsgedichte von Karl Kraus an Sidonie Na?dherny?  

E-Print Network (OSTI)

Die Aufgabe dieser Arbeit besteht darin, Sidonie Na?dherny? Einfluß auf das Werk von Karl Kraus, vor allem auf seine Lyrik, an Hand der Albert Bloch/Sidonie Na?dherny?-Korrespondenz auszuwerten. Neben den eigentlichen ...

Champion, Elke Lorenz

1998-01-01T23:59:59.000Z

320

" East North Central",21.3,"NA",26,27.6,29,32.4  

U.S. Energy Information Administration (EIA) Indexed Site

Number of Vehicles, Selected Survey Years (Millions)" Number of Vehicles, Selected Survey Years (Millions)" ,"Survey Years" ,1983,1985,1988,1991,1994,2001 "Total",129.3,137.3,147.5,151.2,156.8,191 "Household Characteristics" "Census Region and Division" " Northeast",23.9,"NA",26.6,27,26.6,31.7 " New England",6.6,"NA",6.6,6.5,7.6,10 " Middle Atlantic ",17.3,"NA",20.1,20.5,19,21.7 " Midwest ",32.5,"NA",37.8,38.4,41.1,47.1 " East North Central",21.3,"NA",26,27.6,29,32.4 " West North Central ",11.3,"NA",11.8,10.8,12.1,14.7 " South",45.1,"NA",50.6,52.7,56,70.2 " South Atlantic",22.2,"NA",25.9,26.6,28.4,38.8

Note: This page contains sample records for the topic "butyl ether na" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

" East North Central",751,"NA",539,650,639,792.21608  

U.S. Energy Information Administration (EIA) Indexed Site

Fuel Expenditures per Vehicle, Selected Survey Years (Nominal Dollars) " Fuel Expenditures per Vehicle, Selected Survey Years (Nominal Dollars) " ,"Survey Years" ,1983,1985,1988,1991,1994,2001 "Total",736,722,550,650,668,787 "Household Characteristics" "Census Region and Division" " Northeast",731,"NA",532,660,647,766.42074 " New England",706,"NA",526,687,637,810.19092 " Middle Atlantic ",740,"NA",534,651,651,746.41162 " Midwest ",738,"NA",539,651,644,792.60265 " East North Central",751,"NA",539,650,639,792.21608 " West North Central ",714,"NA",538,654,656,793.45498 " South",758,"NA",575,663,673,775.63816 " South Atlantic",772,"NA",559,639,676,755.54606

322

" East North Central",627,"NA",550,553,574,585.28553  

U.S. Energy Information Administration (EIA) Indexed Site

Fuel Consumption per Vehicle, Selected Survey Years (Gallons) " Fuel Consumption per Vehicle, Selected Survey Years (Gallons) " ,"Survey Years" ,1983,1985,1988,1991,1994,2001 "Total",621,611,559,548,578,592 "Household Characteristics" "Census Region and Division" " Northeast",609,"NA",525,523,545,571.15003 " New England",582,"NA",517,541,542,585.83989 " Middle Atlantic ",619,"NA",528,517,545,564.4347 " Midwest ",620,"NA",550,554,580,588.14092 " East North Central",627,"NA",550,553,574,585.28553 " West North Central ",607,"NA",550,557,592,594.43665 " South",644,"NA",585,566,598,615.25944 " South Atlantic",647,"NA",563,542,601,602.53752

323

Inhibition of Na -P/sub i/ cotransporter in small gut brush border by phosphonocarboxylic acids  

SciTech Connect

The authors examined the effect of phosphonoformic acid (PFA) and phosphonoacetic acid (PAA) upon Na -P/sub i/ cotransport in brush-border membrane (BBM) from small gut of rat. Both PFA and PAA inhibited the Na gradient-dependent uptake of TSP/sub i/ by BBM vesicles (BBMV) prepared from intestinal mucosa but had no effect on Na -dependent uptakes of D-(TH)glucose, L-(TH)proline, or ( UC)succinate. The uptake in the absence of Na gradient, or uptake at equilibrium period (180 min), was not affected by PFA or by PAA. A chemical analogue of PFA and PAA, phosphonopropionic acid, had only a minor inhibitory effect and phenylphosphonic acid was inactive. Neither PFA nor PAA influenced the activity of rat intestinal BBM alkaline phosphatase. The BBMV from rat jejunum had a much higher capacity for Na gradient-dependent uptake of TSP/sub i/ than BBMV from duodenum or ileum. The inhibition of BBMV TSP/sub i/ transport across rat jejunum by PFA is competitive. They suggest that PFA and PAA are specific inhibitors of Na gradient-dependent uptake of P/sub i/ by BBMV from small intestinal mucosa and that they could serve as useful experimental tools for the studies of intestinal Na -P/sub i/ cotransport.

Loghman-Adham, M.; Szczepsanska-Konkel, M.; Yusufi, A.N.K.; Van Scoy, M.; Dousa, T.P.

1987-02-01T23:59:59.000Z

324

Investigation of the Effects of Biodiesel-based Na on Emissions Control Components  

SciTech Connect

A single-cylinder diesel engine was used to investigate the impact of biodiesel-based Na on emissions control components using specially blended 20% biodiesel fuel (B20). The emissions control components investigated were a diesel oxidation catalyst (DOC), a Cu-zeolite-based NH{sub 3}-SCR (selective catalytic reduction) catalyst, and a diesel particulate filter (DPF). Both light-duty vehicle, DOC-SCR-DPF, and heavy-duty vehicle, DOC-DPF-SCR, emissions control configurations were employed. The accelerated Na aging is achieved by introducing elevated Na levels in the fuel, to represent full useful life exposure, and periodically increasing the exhaust temperature to replicate DPF regeneration. To assess the validity of the implemented accelerated Na aging protocol, engine-aged lean NO{sub x} traps (LNTs), DOCs and DPFs are also evaluated. To fully characterize the impact on the catalytic activity the LNT, DOC and SCR catalysts were evaluated using a bench flow reactor. The evaluation of the aged DOC samples and LNT show little to no deactivation as a result of Na contamination. However, the SCR in the light-duty configuration (DOC-SCR-DPF) was severely affected by Na contamination, especially when NO was the only fed NO{sub x} source. In the heavy-duty configuration (DOC-DPF-SCR), no impact is observed in the SCR NO{sub x} reduction activity. Electron probe micro-analysis (EPMA) reveals that Na contamination on the LNT, DOC, and SCR samples is present throughout the length of the catalysts with a higher concentration on the washcoat surface. In both the long-term engine-aged DPF and the accelerated Na-aged DPFs, there is significant Na ash present in the upstream channels; however, in the engine-aged sample lube oil-based ash is the predominant constituent.

Brookshear, D. William [University of Tennessee, Knoxville (UTK); Nguyen, Ke [University of Tennessee, Knoxville (UTK); Toops, Todd J [ORNL; Bunting, Bruce G [ORNL; Howe, Janet E [ORNL

2012-01-01T23:59:59.000Z

325

Balancing SoNaR: IPR versus Processing Issues in a 500-Million-Word Written Dutch Reference Corpus  

E-Print Network (OSTI)

Balancing SoNaR: IPR versus Processing Issues in a 500-Million-Word Written Dutch Reference Corpus included in SoNaR will have its IPR issues settled to the largest extent possible. This data collection lead to the creation of two corpora: a gigaword SoNaR, IPR-cleared for research purposes

Tilburg, Universiteit van

326

Intracellular Sequestration of Sodium by a Novel Na /H Exchanger in Yeast Is Enhanced by Mutations in the  

E-Print Network (OSTI)

membrane Na /K -ATPase, a P-type ion pump, that drives Na ions out of the cell in exchange for K ions (1). The resultant Na gradient serves as the primary energy source for the transport of other ions and metabolites threat to agricultural production worldwide (4, 5). Because of a basic similarity in ion transport

Rao, Rajini

327

Synthesis and characterization of hybrid materials based on 1-butyl-3-methylimidazolium tetrafluoroborate ionic liquid and Dawson-type tungstophosphate K{sub 7}[H{sub 4}PW{sub 18}O{sub 62}].18H{sub 2}O and K{sub 6}[P{sub 2}W{sub 18}O{sub 62}].13H{sub 2}O  

SciTech Connect

In this study, we synthesized hybrid materials using well-Dawson polyoxometalates (POMs), K{sub 7}[H{sub 4}PW{sub 18}O{sub 62}].18H{sub 2}O or K{sub 6}[P{sub 2}W{sub 18}O{sub 62}].13H{sub 2}O and a room temperature ionic liquid 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIM][BF{sub 4}]). K, W, P and CHN elemental analysis showed that one mole of [H{sub 4}PW{sub 18}O{sub 62}]{sup 7-} reacts with 6 moles of BMIM{sup +} and one mole of [P{sub 2}W{sub 18}O{sub 62}]{sup 6-} reacts with 4 moles of BMIM{sup +} to form, respectively, K[BMIM]{sub 6}H{sub 4}PW{sub 18}O{sub 62} and K{sub 2}[BMIM]{sub 4}P{sub 2}W{sub 18}O{sub 62}. X-ray diffraction illustrated amorphous structure of the hybrid materials. FT-IR spectra showed the presence of both 1-butyl-3-methylimidazolium cation and the Dawson anion. TG analysis displayed a relative thermal stability of the hybrid materials compared to the parents Dawson POMs. Cyclic voltammetry showed that the reduction peak potentials of the Dawson anion in the hybrid materials shift towards negative values and the shift is more pronounced for K[BMIM]{sub 6}H{sub 4}PW{sub 18}O{sub 62} compared to K{sub 2}[BMIM]{sub 4}P{sub 2}W{sub 18}O{sub 62}. This was attributed to a decrease in the acidity of the Dawson POM anion in the hybrid material. -- Graphical abstract: Powder XRD patterns of (a) PW{sub 18}, (b) K[BMIM]{sub 6}H{sub 4}PW{sub 18}O{sub 62}, (c) P{sub 2}W{sub 18}, and (d) K{sub 2}[BMIM]{sub 4}P{sub 2}W{sub 18}O{sub 62}. Display Omitted Research highlights: {yields} 1-butyl-3-methylimidazolium tetrafluoroborate([BMIM][BF{sub 4}]) reacts with K{sub 7}[H{sub 4}PW{sub 18}O{sub 62}].18H{sub 2}O to form K[BMIM]{sub 6}H{sub 4}PW{sub 18}O{sub 62}. {yields} [BMIM][BF{sub 4}] reacts with K{sub 6}[P{sub 2}W{sub 18}O{sub 62}].13H{sub 2}O to form K{sub 2}[BMIM]{sub 4}P{sub 2}W{sub 18}O{sub 62}. {yields} K[BMIM]{sub 6}H{sub 4}PW{sub 18}O{sub 62} and K{sub 2}[BMIM]{sub 4}P{sub 2}W{sub 18}O{sub 62} displayed amorphous structures. {yields} K[BMIM]{sub 6}H{sub 4}PW{sub 18}O{sub 62} and K{sub 2}[BMIM]{sub 4}P{sub 2}W{sub 18}O{sub 62} illustrated low water content. {yields} K[BMIM]{sub 6}H{sub 4}PW{sub 18}O{sub 62} and K{sub 2}[BMIM]{sub 4}P{sub 2}W{sub 18}O{sub 62} showed improved thermal stability.

Ammam, Malika, E-mail: m78ammam@yahoo.f [Department of Metallurgy and Materials Engineering (MTM), K.U Leuven, Kasteelpark Arenberg 44, B-3001 Heverlee (Belgium); Fransaer, Jan [Department of Metallurgy and Materials Engineering (MTM), K.U Leuven, Kasteelpark Arenberg 44, B-3001 Heverlee (Belgium)

2011-04-15T23:59:59.000Z

328

Reactivity of the Quinone Methide of Butylated hydroxytoluene in Solution  

E-Print Network (OSTI)

BHT is a common antioxidant in pharmaceutical formulations and when oxidized it forms a quinone methide (QM). QM is a highly reactive electrophilic species which can undergo nucleophilic addition. This research investigated ...

Willcockson, Maren Gulsrud

2011-08-31T23:59:59.000Z

329

2012 Annual Workforce Analysis and Staffing Plan Report - NNSA for Safety and Health - NA-26  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

1 Annual Workforce Analysis and Staffing Plan Report Draft as of December 31, 2012 Reporting Office: _NA-26 Office of Fissile Material Disposition at SRS____ Section 1: Current Mission(s) of the Organization and Potential Changes 1. The Office of Fissile Material Disposition (NA-26) is part of the National Nuclear Security Administration (NNSA). NA-26 supports NNSA Strategic Plan Goal #2, "Provide technical leadership to limit or prevent the spread of materials, technology, and expertise relating to weapons of mass destruction; advance the technologies to detect the proliferation of weapons of mass destruction worldwide, and eliminate or secure inventories of surplus materials and infrastructure usable for nuclear weapons." The NA-26 organization focuses on the safe and secure disposition of

330

NNSA selects Lindsey VanNess as NA-00 Inaugural Employee of the Year |  

National Nuclear Security Administration (NNSA)

selects Lindsey VanNess as NA-00 Inaugural Employee of the Year | selects Lindsey VanNess as NA-00 Inaugural Employee of the Year | National Nuclear Security Administration Our Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Continuing Management Reform Countering Nuclear Terrorism About Us Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Media Room Congressional Testimony Fact Sheets Newsletters Press Releases Speeches Events Social Media Video Gallery Photo Gallery NNSA Archive Federal Employment Apply for Our Jobs Our Jobs Working at NNSA Blog Home > NNSA Blog > NNSA selects Lindsey VanNess as NA-00 Inaugural ... NNSA selects Lindsey VanNess as NA-00 Inaugural Employee of the Year Posted By Office of Public Affairs

331

INDECOMPOSABLE RACKS OF ORDER p2 MAT'IAS GRA"NA  

E-Print Network (OSTI)

INDECOMPOSABLE RACKS OF ORDER p2 MAT'IAS GRA"NA Abstract.We classify indecomposable racks of order p2(p a prime). There a of prime order is trivial. 1.Introduction Racks and quandles have

Graña, Matías

332

Plasma spectroscopy of H, Li, and Na in plumes resulting from laser-induced droplet explosion  

Science Journals Connector (OSTI)

The plasma emission resulting from laser-induced breakdown of large transparent H2O droplets (with and without NaCl or LiCl) has been spectrally and spatially resolved along...

Eickmans, Johannes H; Hsieh, Wen-Feng; Chang, Richard K

1987-01-01T23:59:59.000Z

333

E-Print Network 3.0 - achados na artroscopia Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

Page: << < 1 2 3 4 5 > >> 1 Tera-feira, 17 de maio de 2011 Summary: universidades do Brasil e do exterior revelaram numerosos achados. Os mais recentes aconteceram na Expedio...

334

E-Print Network 3.0 - achados na tomografia Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

Page: << < 1 2 3 4 5 > >> 1 Tera-feira, 17 de maio de 2011 Summary: universidades do Brasil e do exterior revelaram numerosos achados. Os mais recentes aconteceram na Expedio...

335

E-Print Network 3.0 - anjos na escola Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

Ttulo do trabalho Eixo Situao Summary: na escola. 6 Aceito 8 MARIA DE FTIMA PEREIRA DE FREITAS No consta o ttulo 4 Aceito 9 MARILEA DE... Reestruturao do ensino...

336

E-Print Network 3.0 - atendidos na rede Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

espcies no topo e na base das teias trficas Dinmica II Estrutura e dinmica de redes... Guimares JrJr DFMCDFMC -- IFGWIFGW -- UnicampUnicamp Estrutura e dinmica de...

337

High resolution observations of interstellar Ca II and Na I in the 30 Doradus nebula  

Science Journals Connector (OSTI)

......associated with 30 Dor in the Large Magellanic Cloud; for the brightest source in the nebula, namely R136, complementary Na Iions have been made. All sight-lines show complex interstellar profiles with three principal components occurring between +239......

J. C. Blades

1980-01-01T23:59:59.000Z

338

Ultracold Fermionic Feshbach Molecules of [superscript 23]Na[superscript 40]K  

E-Print Network (OSTI)

We report on the formation of ultracold weakly bound Feshbach molecules of [superscript 23]Na[superscript 40]K, the first fermionic molecule that is chemically stable in its absolute ground state. The lifetime of the nearly ...

Wu, Cheng-Hsun

339

Termination and complexity bounds for SAFE programs Salvador Lucas Ricardo Pe~na  

E-Print Network (OSTI)

Termination and complexity bounds for SAFE programs Salvador Lucas Ricardo Pe~na Dep. de Sistemas partially supported by the EU (FEDER) and the Spanish MEC, under grant TIN 2004-7943- C04. Salvador Lucas

Lucas, Salvador

340

Effects of Point Defects and Impurities on Kinetics in NaAlH4  

Energy.gov (U.S. Department of Energy (DOE))

A presentation showing that point defects play an important role in the kinetics of NaAlH4 including vacancies and interstitials consistent with observed effects of Ti.

Note: This page contains sample records for the topic "butyl ether na" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

At-Wavelength Interferometry of High-NA Diffraction-Limited EUV Optics  

E-Print Network (OSTI)

-reflective, Mo/Si-multilayer-coated EUV imaging optics have included two-mirror Schwarzschild designs [1 optical systems, called the Micro Exposure Tool (MET), are two-mirror, 0.3 NA, axially-symmetric systems

Bokor, Jeffrey

342

Using Na+MMT nanoclay as a secondary filler in plywood manufacturing  

Science Journals Connector (OSTI)

Eight adhesive formulations were developed using two types of resin by urea–formaldehyde (UF) and melamine-urea formaldehyde (MUF) resins and four levels of sodium montmorillonite (Na+MMT) nanoclay by 0, 2.5, 5, ...

Kazem Doosthoseini; Hamid Zarea-Hosseinabadi

2010-12-01T23:59:59.000Z

343

Esophageal desalination is mediated by Na+ exchanger-2 in the gulf  

E-Print Network (OSTI)

Esophageal desalination is mediated by Na+ , H+ exchanger-2 in the gulf toadfish (Opsanus beta Intestinal water transport Osmoregulation Chloride Esophageal desalination is a crucial step (-subunit), suggesting that esophageal desalination is less flexible in response to osmotic stress than

Grosell, Martin

344

Thermochemistry of phosphorus oxynitrides: PON and LiNaPON glasses  

SciTech Connect

High-temperature solution calorimetry has been very useful in elucidating the energetics of many oxide materials. Recently, a sodium molybdate melt, 3Na{sub 2}O{center{underscore}dot}4MoO{sub 3}, has been shown to be very effective for nitride calorimetry. This methodology has now been used to determine the energetics of formation of phosphorus oxynitride PON samples and of a series of LiNaPON oxynitride glasses. The magnitude of the energetics of nitrogen/oxygen substitution within PON and LiNaPON glasses has been correctly evaluated by using N-N, O-O, P-N, and P-O bond strengths. The in-situ precipitation of metallic particles from corresponding oxides in LiNaPON glasses has been predicted from high-temperature solution calorimetry results and appropriate thermodynamic cycles. The results constitute the first set of energetic data on nitridophosphates.

Tessier, F.; Navrotsky, A.; Le Sauze, A.; Marchand, R.

2000-01-01T23:59:59.000Z

345

Catalytic Effect of Ti for Hydrogen Cycling in NaAlH4  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

+ 2AlH 3 3 NaAlH 4 M. Mamula et al., Coll. Czechoslov. Chem. Commun. 32, 884 (1967). Atomic Hydrogen Interacting with Al Surfaces "H adsorption and the formation of alane...

346

Preparação de híbridos metal/carbono por carbonização hidrotérmica para aplicação na oxidação eletroquímica de metanol.  

E-Print Network (OSTI)

??Neste trabalho foram preparados híbridos PtRu/Carbono e Ni/Carbono pelo método da carbonização hidrotérmica para aplicação na oxidação eletroquímica do metanol. Nesse processo, uma fonte de… (more)

Marcelo Marques Tusi

2010-01-01T23:59:59.000Z

347

E-Print Network 3.0 - anemia materna na Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

page (22-502 Summary: STUDIES OF FERRITIN-LIKE IRON I N RED BLOOD CELLS OF THALASSEMIA, SICKLE-CELL ANEMIA AND HEMOGLOBIN... . Aucune quan- tit6 de fer du type ferritine n'a btC...

348

An effect of chloride on (Na + K) co-transport in human red blood cells  

Science Journals Connector (OSTI)

... the phloretin- and furosemide-sensitive (Na-Li) counter-transport system identified in RBC by Tosteson and co-workers9. Third, there is the extensive work by Wieth on anion and ...

A. R. Chipperfield

1980-07-17T23:59:59.000Z

349

E-Print Network 3.0 - atheriniformes atherinopsidae na Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

(RS; bp), number of alleles (NA), average observed heterozygosity (HO), and average FIS and FST... This study Primer Sequence (5-3; Feldheim et al. in prep.) TA (C) RN RS...

350

E-Print Network 3.0 - anp na reducao Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

BY ANP high Na intake volume expansion normal L 2 0 IL- , 11----y7 --, 1 10 100 ANP infusion r-ate (rig... Physiological concentrations of ANP exert a dual regulatory influence...

351

An Empirical Na-K-Ca Geothermometer For Natural Waters | Open Energy  

Open Energy Info (EERE)

Empirical Na-K-Ca Geothermometer For Natural Waters Empirical Na-K-Ca Geothermometer For Natural Waters Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: An Empirical Na-K-Ca Geothermometer For Natural Waters Details Activities (0) Areas (0) Regions (0) Abstract: An empirical method of estimating the last temperature of water-rock interaction has been devised. It is based upon molar Na, K and Ca concentrations in natural waters from temperature environments ranging from 4 to 340°C. The data for most geothermal waters cluster near a straight line when plotted as the function vs reciprocal of absolute temperature, where Β is either or depending upon whether the water equilibrated above or below 100°C. For most waters tested, the method gives better results than the methods suggested by other workers. The ratio

352

ISSN 0103-1538 4231 MONITORAMENTO DOS FOCOS DE CALOR NA REGIO SUL DO BRASIL  

E-Print Network (OSTI)

ISSN 0103-1538 4231 MONITORAMENTO DOS FOCOS DE CALOR NA REGI�O SUL DO BRASIL Instituto Nacional de monitorar a distribuição dos focos de calor na região sul do Brasil, entre os anos de 2003 a 2007, através, Geotecnologias, Região Sul do Brasil. RESUMEN Las quemadas pueden ser causadas de forma natural o por influencia

353

SISTEMATIZAO DE OCORRNCIAS DE DESASTRES NATURAIS NA REGIO SUL DO BRASIL EM 2011  

E-Print Network (OSTI)

Página1 SISTEMATIZA��O DE OCORR�NCIAS DE DESASTRES NATURAIS NA REGI�O SUL DO BRASIL EM 2011 Janete Aplicação de Geotecnologias para Desastres Naturais e Eventos Extremos para a Região Sul do Brasil e forma, a pesquisa tem como objetivo analisar os eventos de desastres naturais na Região Sul do Brasil em

354

Supporting information for: Na-doped p-type ZnO , Faxian Xiu2  

E-Print Network (OSTI)

S1 Supporting information for: Na-doped p-type ZnO microwires Wei Liu1* , Faxian Xiu2 , Ke Sun1 flow was switched to argon followed by cooling to room temperature. After the growth, high-density Zn distribution of the Na Doped ZnO microwire 1.3 EDX line scans spectra #12;S3 Figure S3 a) a typical TEM image

Yang, Zheng

355

Carbon monoxide adsorption/desorption processes over NaX zeolite and supported ruthenium catalyst  

SciTech Connect

The binding states of CO on NaX zeolite and RuNaX were investigated by thermal desorption spectroscopy. Desorption peaks centered at around 390, 430, 490, and 520 K were observed from NaX following room-temperature adsorption of CO. The activation energy values corresponding to these peaks were calculated to be 41.4, 45.7, 53.8, and 57.7 kJ mol{sup {minus}1}, respectively. These peaks were also observed in desorption profiles from RuNaX although their temperatures were higher by 10 to 20 K. In addition, the desorption spectra from RuNaX also comprise two high-temperature peaks at around 575 and 640 K. With both the RuNaX and the NaX samples the temperature and relative intensities of the desorption peaks depended on pretreatment conditions and on the lapsed time between CO exposure to the sample and the commencement of programmed heating. Mass spectral analysis revealed that the gas desorbed at 300-500 K consisted mainly of CO while at higher temperatures CO{sub 2} was the main component. The desorption peaks below 500 K are attributed to the release of carbon monoxide from structural and intragranular or intergranular zeolitic pores. Lewis sites on the zeolite surface are found to facilitate activation of CO, resulting in its transformation to CO{sub 2}. The initial adsorption of carbon monoxide in zeolite pores and subsequent diffusion to metal sites leading to its disproportionation/oxidation is found to play an important role in the CO adsorption/desorption process on RuNaX.

Kamble, V.S.; Gupta, N.M.; Iyer, R.M. (Bhabha Atomic Research Centre, Bombay (India))

1988-10-01T23:59:59.000Z

356

Crnica da III Feira da Sustentabilidade na UDC. Feira de Nadal 2012  

E-Print Network (OSTI)

Crónica da III Feira da Sustentabilidade na UDC. Feira de Nadal 2012 O pasado mércores 12 de universitaria a asistir á III Feira de Sustentabilidade que tivo lugar na Facultade de Economía e Empresa Sustentabilidade foi unha charla-debate en que Raúl Asegurado, presidente da Asociación Fiare Galiza, explicou en

Fraguela, Basilio B.

357

Cell volume variation under different concentrations of saline solution (NaCL)  

Science Journals Connector (OSTI)

RESUMENIntroducción: Dentro de las prácticas clínicas, es de suma importancia conocer la relación volumétrica entre la contracción celular y la concentración de solución salina (NaCl). Métodos: Muestras de sangre por parte de voluntarios que gozan de buena salud fueron expuestas a diferentes concentraciones de NaCl, las cuales oscilan entre 0.42% a 11.70%, observándose la variación resultante en el hematocrito. Se estudió la variación del volumen celular como función de la correspondiente concentración de NaCl. Se llegó a establecer una ecuación que predice teóricamente el comportamiento observado. Resultados: Examinamos 53 muestras de sangre provenientes de 12 voluntarios sanos. La relación entre la contracción celular y la concentración de NaCl muestra que la máxima contracción del volumen celular se obtiene cuando el NaCl está en alrededor de 5.85%. Se resume el modelo matemático resultante en la ecuación. ?V denota la variación celular a la correspondiente concentración de NaCl. Este modelo presenta un coeficiente de regresión lineal de 0.996 y aplicando el Chi-square goodness of fit test [es una prueba estadística] se observa un nivel de confianza superior a 99.5%. Igualmente, es menester mencionar que las concentraciones de NaCl iguales o superiores a 7.02% provoca cierto grado de hemólisis. Conclusiones: No hay razón para utilizar concentraciones de NaCl superiores a 5.85%. Concentraciones más altas no inducen una mayor contracción del volumen celular, pero sí provocan lesión celular.41CV=?

Mario J. García; Angel M. Ardila

2009-01-01T23:59:59.000Z

358

Selective catalytic reduction of NO{sub 2} with urea in nanocrystalline NaY zeolite  

SciTech Connect

In this study, the selective catalytic reduction (SCR) of NO{sub 2} with urea in nanocrystalline NaY zeolite was investigated with in situ transmission Fourier transform infrared (FTIR) spectroscopy and solid-state nuclear magnetic resonance spectroscopy. At T=473 K, the reaction rate for urea-SCR of NO{sub 2} in nanocrystalline NaY zeolite was significantly greater than that in commercial NaY zeolite with a larger crystal size. In addition, a dramatic decrease in the concentration of undesirable surface species, including biuret and cyanuric acid, was observed in nanocrystalline NaY compared with commercial NaY after urea-SCR of NO{sub 2} at T=473 K. The increased reactivity for urea-SCR of NO{sub 2} was attributed to silanol groups and extra-framework aluminum species located on the external surface of nanocrystalline NaY. Specifically, NOx storage as nitrate and nitrite on the internal zeolite surface was coupled to reactive deNOx sites on the external surface. Isotopic labeling combined with IR analysis suggest that NN bond formation involved both an N-atom originating from NO{sub 2} and an N-atom originating from urea. This is the first clear example demonstrating that the increased external surface area (up to 40% of total surface area) of nanocrystalline zeolites can be used as a reactive surface with unique active sites for catalysis.

Gonghu Li; Conrad A. Jones; Vicki H. Grassian; Sarah C. Larsen [University of Iowa, Iowa City, IA (United States). Department of Chemistry

2005-09-10T23:59:59.000Z

359

Synthesis and characterization of NaMt biocomposites with corn cob xylan in aqueous media  

Science Journals Connector (OSTI)

In this study synthesis and characterization of biopolymer/clay biocomposites was aimed using naturally occurring polysaccharide (xylan) as biopolymer and montmorillonite type clay (NaMt). Xylan was extracted from corn cobs via alkaline oxidative treatment. Maximum solubility of xylan was determined as 1% (w/v) in water at room temperature. Thus synthesis was realized following two routes; first NaMt concentration was kept constant at 2.0 × 10?2 g/ml and xylan concentration was changed. Latter xylan concentration was kept constant at 1.0 × 10?2 g/ml and NaMt concentration was changed. Natural xylan, NaMt and biocomposites were examined in terms of their spectral, electrokinetic, rheologic, morphologic and thermal properties. Results showed that lower amounts of xylan interacted with NaMt on the surface, however, when the xylan amount was increased also intercalation of NaMt has occurred. Biocomposites showed better thermal and rheologic behaviors with respect to the starting materials.

Cüneyt H. Ünlü; Ebru Günister; Oya At?c?

2009-01-01T23:59:59.000Z

360

EFFECT OF NaF AND SnO{sub 2} ON PORTLAND CEMENT CLINKER FABRICATION  

SciTech Connect

The paper aimed at studying the effect of NaF and SnO{sub 2} employed as mineralisers on Portland cement clinker fabrication. In order to do this, the raw mix included in turn 0.5% NaF, 0.5% SnO{sub 2}, and a combination of 0.5% NaF and 0.5% SnO{sub 2}, all expressed as weight percentages of the raw mix. The effects of the presence of NaF and SnO{sub 2} mineralisers on the raw mix were studied by investigations of the loss on ignition at 700 deg. C and 800 deg. C with calculating the corresponding decarbonation ratio of the raw mix, determination of free lime and XRD analysis. NaF was found to have a positive effect both during the decarbonation of the raw mix and during the formation of minerals in clinker. On the other hand, SnO{sub 2} has but a little effect on the decarbonation process. Finally, the combined use of NaF and SnO{sub 2} modifies the kinetics of binding the free lime to the effect of accelerating the process as compared to the separate use of each mineraliser.

Paceagiu, Jenica; Amzica, Florin; Chendrean, Teofil; Paraschiv, Tatiana [CEPROCIM SA, Bucharest (Romania)

2008-08-28T23:59:59.000Z

Note: This page contains sample records for the topic "butyl ether na" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Gestational and early postnatal dietary NaCl levels affect NaCl intake, but not stimulated water intake, by adult rats  

E-Print Network (OSTI)

intake, by adult rats Kathleen S. Curtis, Eric G. Krause, Donna L. Wong, and Robert J. Contreras affect NaCl intake, but not stimulated water intake, by adult rats. Am J Physiol Regul Integr Comp examined body fluid regulation by weanling (21­25 days) and adult ( 60 days) male rats that were offspring

Hull, Elaine

362

Ozone-forming potential of a series of oxygenated organic compounds  

SciTech Connect

An incremental reactivity approach has been used to assess the relative ozone-forming potentials of various important oxygenated fuels/fuel additives, i.e., tert-butyl alcohol (TBA), dimethyl ether (DME), diethyl ether (DEE), methyl tert-butyl ether (MTBE), and ethyl tert-butyl ether (ETBE), in a variety of environments. Calculations were performed using a single-cell trajectory model, combined with the Lurmann-Carter-Coyner chemical mechanism, with (NMOC)/(NO{sub x}) ratios ranging from 4 to 20. This work provides the first quantitative assessment of the air quality impact of release of these important oxygenated compounds. ETBE and DEE are the two most reactive compounds on a per carbon equivalent basis, while TBA is the least reactive species. At a (NMOC)/(NO{sub x}) ratio of 8, which is generally typical of polluted urban areas in the United States, TBA, DME, MTBE, and ETBE all have incremental reactivities less than or equal to that of the urban NMHC mix. Thus, use of these additives in fuels may have a beneficial impact on urban ozone levels.

Japar, S.M.; Wallington, T.J.; Rudy, S.J.; Chang, Tai Y. (Ford Motor Company, Dearborn, MI (USA))

1991-03-01T23:59:59.000Z

363

Catalytic Effect of Ti for Hydrogen Cycling in NaAlH4  

NLE Websites -- All DOE Office Websites (Extended Search)

Effect of Ti for Effect of Ti for Hydrogen Cycling in NaAlH 4 Mei-Yin Chou School of Physics Georgia Institute of Technology (DE-FG02-05ER46229) Acknowledgment: Yan Wang, Roland Stumpf Why is NaAlH 4 interesting? A viable candidate for hydrogen-storage material: High theoretical weight-percent hydrogen content of 5.55% and low cost But (before 1997) Dehydrogenation occurs at high temperature; rehydrogenation is difficult. Bogdanovic and Schwickardi, 1997 Hydrogen can be reversibly absorbed and desorbed from NaAlH 4 under moderate conditions by the addition of catalysts (compounds containing Ti, Zr, etc.) High Hydrogen Contents in Complex Hydrides Hydride wt% Hydride wt% Be(BH 4 ) 2 20.8 Mg(AlH 4 ) 2 9.3 LiBH 4 18.2 Ca(AlH 4 ) 2 7.9 Mg(BH 4 ) 2 14.9 KBH 4 7.5 Ca(BH 4 ) 2 11.6 NaAlH 4 7.5 NaBH4 10.7 Ga(AlH

364

Lead-free piezoelectric ceramics with composition of (0.97?x)Na1/2Bi1/2TiO3-0.03NaNbO3-xBaTiO3  

Science Journals Connector (OSTI)

Compositions in (Na1/2Bi1/2)TiO3 based ternary system, (0.97 ? x) (Na1/2Bi1/2)TiO3-0.03NaNbO3-xBaTiO3 (x = 0, 0.01, 0.02, 0.04, 0.05, 0.06, 0.08) are synthesized using conventional solid state reaction method. In...

Yugong Wu; Huili Zhang; Yue Zhang; Jinyi Ma; Daohua Xie

365

At-wavelength interferometry of high-NA diffraction-limited EUV optics  

SciTech Connect

Recent advances in all-reflective diffraction-limited optical systems designed for extreme ultraviolet (EUV) lithography have pushed numerical aperture (NA) values from 0.1 to 0.3, providing Rayleigh resolutions of 27-nm. Worldwide, several high-NA EUV optics are being deployed to serve in the development of advanced lithographic techniques required for EUV lithography, including the creation and testing of new, high-resolution photoresists. One such system is installed on an undulator beamline at Lawrence Berkeley National Laboratory's Advanced Light Source. Sub{angstrom}-accuracy optical testing and alignment techniques, developed for use with the previous generations of EUV lithographic optical systems, are being extended for use at high NA. Considerations for interferometer design and use are discussed.

Goldberg, Kenneth A.; Naulleau, Patrick; Rekawa, Senajith; Denham, Paul; Liddle, J. Alexander; Anderson, Erik; Jackson, Keith; Bokor, Jeffrey; Attwood, David

2003-08-01T23:59:59.000Z

366

Caustic Recycle from Hanford Tank Waste Using NaSICON Ceramic Membrane Salt Splitting Process  

SciTech Connect

A family of inorganic ceramic materials, called sodium (Na) Super Ion Conductors (NaSICON), has been studied at Pacific Northwest National Laboratory (PNNL) to investigate their ability to separate sodium from radioactively contaminated sodium salt solutions for treating U.S. Department of Energy (DOE) tank wastes. Ceramatec Inc. developed and fabricated a membrane containing a proprietary NAS-GY material formulation that was electrochemically tested in a bench-scale apparatus with both a simulant and a radioactive tank-waste solution to determine the membrane performance when removing sodium from DOE tank wastes. Implementing this sodium separation process can result in significant cost savings by reducing the disposal volume of low-activity wastes and by producing a NaOH feedstock product for recycle into waste treatment processes such as sludge leaching, regenerating ion exchange resins, inhibiting corrosion in carbon-steel tanks, or retrieving tank wastes.

Fountain, Matthew S.; Kurath, Dean E.; Sevigny, Gary J.; Poloski, Adam P.; Pendleton, J.; Balagopal, S.; Quist, M.; Clay, D.

2009-02-20T23:59:59.000Z

367

Two-dimensional charge fluctuation in ?-Na0.33V2O5  

Science Journals Connector (OSTI)

We have investigated the critical phenomena of the metal-to-insulator (MI) transition of ?-Na0.33V2O5. The critical exponent ? of 0.226(3) and anisotropic diffuse scattering suggest that the MI transition of ?-Na0.33V2O5 is two dimensional in nature and that the dimension of the order parameter is not Ising. The non-Ising-like order parameter indicates that the MI transition is not a simple order-disorder type such as that of ??-NaV2O5 but charge-density-wave like, where the valence at each V site is continuous and the arrangement is modulated. This closely corresponds to the situation predicted by neutron diffraction measurements [Nagai et al., J. Phys. Soc. Jpn. 74, 1297 (2005)] and NMR measurements [Itoh et al., Phys. Rev. B 74, 054434 (2006)].

Kenji Ohwada, Touru Yamauchi, Yasuhiko Fujii, and Yutaka Ueda

2012-04-06T23:59:59.000Z

368

An Evaluation of the NaS Battery Storage Potential for Providing Regulation Service in California  

SciTech Connect

Sodium sulfur (NaS) batteries can provide energy storage, real-time dispatch, regulation, frequency response, and other essential services to the power grids. This study presents the technical characteristics, modeling approach, methodologies, and results for providing regulation services in the California Independent System Operator (CAISO) market. Two different scenarios were studied and compared: a scenario without intermittent renewable-energy resource penetration (base case) and a scenario with significant renewable-energy resource penetration (including wind) reaching 20% of CAISO’s energy supply. In addition, breakeven cost analyses were developed for four cases. Based on the results of the technical and cost analyses, the opportunities for the NaS battery providing the regulation services are discussed, design improvements for the battery’s physical characteristics are recommended, and modifications of the regulation signals sent to NaS batteries are proposed.

Lu, Ning; Weimar, Mark R.; Makarov, Yuri V.; Loutan, Clyde

2011-03-23T23:59:59.000Z

369

Thermodynamic and kinetic analyses of the CO2 chemisorption mechanism on Na2TiO3: Experimental and theoretical evidences  

SciTech Connect

ABSTRACT: Sodium metatitanate (Na2TiO3) was successfully synthesized via a solid-state reaction. The Na2TiO3 structure and microstructure were characterized using X-ray diffraction, scanning and transmission electron microscopy, and N2 adsorption. Then, the CO2 chemisorption mechanism on Na2TiO3 was systematically analyzed to determine the influence of temperature. The CO2 chemisorption capacity of Na2TiO3 was evaluated both dynamically and isothermally, and the products were reanalyzed to elucidate the Na2TiO3?CO2 reaction mechanism. Different chemical species (Na2CO3, Na2O, and Na4Ti5O12 or Na16Ti10O28) were identified during the CO2 capture process in Na2TiO3. In addition, some CO2 chemisorption kinetic parameters were determined. The ?H? was found to be 140.9 kJ/mol, to the Na2TiO3?CO2 system, between 600 and 780 °C. Results evidenced that CO2 chemisorption on Na2TiO3 highly depends on the reaction temperature. Furthermore, the experiments were theoretically supported by different thermodynamic calculations. The calculated thermodynamic properties of CO2 capture reactions by (Na2TiO3, Na4Ti5O12, and Na16Ti10O28) sodium titanates were fully investigated.

Duan, Yuhua [U.S. DOE

2014-01-01T23:59:59.000Z

370

Differential thermal analysis of the liquidus relations in the system NaCl-H sub 2 O to 6 kbar  

SciTech Connect

The liquidus relations in the system NaCl-H{sub 2}O were investigated between 300 and 925C and between 0.4 and 6 kbar for compositions between 27.6 and 100 mol% NaCl by high-pressure differential thermal analysis. The PT slope of the liquidus increases from 10.5C/kbar for a composition with 27.6 mol% NaCl to 20.8C/kbar with 90 mol% NaCl to 21.8C/kbar with pure NaCl. The PT slope of the vapor saturation surface at the composition with 27.6 mol% NaCl is linear over the pressure range investigated and has a slope of 294C/kbar. On the basis of the experiments the composition of the liquids along the NaCl-rich part of the three-phase assemblage halite + liquid + vapor was determined: the liquid composition varies nearly linearly to within 0.5 wt% NaCl at temperatures above 480C, following the expression wt% (NaCl) = 0.1412T (C) - 12.96.

Koster van Groos, A.F. (Univ. of Illinois, Chicago (United States))

1991-10-01T23:59:59.000Z

371

Estimativa do recurso contingente dos folhelhos oleígenos da Formação Tremembé, Bacia de Taubaté, na região de Tremembé-Pindamonhangaba, SP.  

E-Print Network (OSTI)

??Esta dissertação tem como objetivo apresentar uma estimativa preliminar do volume de recurso contingente não-convencionais de folhelhos oleígenos (oil shale) na Formação Tremembé através de… (more)

Leonardo Simões Pimentel

2012-01-01T23:59:59.000Z

372

Efficient near-infrared quantum cutting in NaYF4: Ho3+, Yb3+ for solar photovoltaics  

Science Journals Connector (OSTI)

Quantum cutting converting a ultraviolet photon into two near-infrared photons has been demonstrated by spectroscopic measurements in NaYF4:Ho3+,Yb3+...

Deng, Kaimo; Gong, Tao; Hu, Lingxun; Wei, Xiantao; Chen, Yonghu; Yin, Min

2011-01-01T23:59:59.000Z

373

Impact of Biodiesel-Based Na on the Selective Catalytic Reduction (SCR) of NOx Using Cu-zeolite  

Energy.gov (U.S. Department of Energy (DOE))

Discusses the impact of Na in biodiesel on three emission control devices: the diesel particulate filter, diesel oxidation catalyst, and zeolyte-based SCR catalyst

374

Static and dynamic polarizabilities of Na? within a variationally stable coupled-channel hyperspherical method  

Science Journals Connector (OSTI)

Using a model potential representation combined with a variationally stable method, we present a precise calculation of the electric dipole polarizabilities of the sodium negative ion (Na?). The effective two-electron eigensolutions for Na? are obtained from a hyperspherical coupled-channel calculation. This approach allows efficient error control and insight into the system’s properties through one-dimensional potential curves. Our result of 1018.3a.u. for the static dipole polarizability is in agreement with previous calculations and supports our results for the dynamic polarizability, which has scarcely been investigated hitherto.

Mauro Masili and J. J. De Groote

2004-11-17T23:59:59.000Z

375

Chemical and Electrochemical Differences in Nonaqueous Li–O2 and Na–O2 Batteries  

Science Journals Connector (OSTI)

The most intriguing difference between the two batteries is their respective galvanostatic charging overpotentials: a Na–O2 battery exhibits a low overpotential throughout most of its charge, whereas a Li–O2 battery has a low initial overpotential that continuously increases to very high voltages by the end of charge. ... Li metal was purchased from FMC, Na metal was purchased from GalliumSource, P50 Avcarb carbon paper was purchased from the Fuel Cell Store, and Whatman glass fiber filters (QM-A grade) were used as the separator. ...

Bryan D. McCloskey; Jeannette M. Garcia; Alan C. Luntz

2014-03-17T23:59:59.000Z

376

Off-center Tl and Na dopant centers in CsI  

SciTech Connect

We use density functional theory calculations to characterize the electronic and structural properties of the Tl and Na dopant centers in CsI. We nd that the Tl and Na centers can accept one or two electrons and couple to long-range relaxations in the surrounding crystal lattice to distort strongly off-center to multiple distinct minima, even without a triplet excitation. The long-range distortions are a mechanism to couple to phonon modes in the crystal, and are expected to play an important role in the phonon-assisted transport of polarons in activated CsI and subsequent light emission in this scintillator.

Van Ginhoven, Renee M.; Schultz, P. A.

2013-12-11T23:59:59.000Z

377

POST-OPERATIONAL TREATMENT OF RESIDUAL NA COOLLANT IN EBR-2 USING CARBONATION  

SciTech Connect

At the end of 2002, the Experimental Breeder Reactor Two (EBR-II) facility became a U.S. Resource Conservation and Recovery Act (RCRA) permitted site, and the RCRA permit1 compelled further treatment of the residual sodium in order to convert it into a less reactive chemical form and remove the by-products from the facility, so that a state of RCRA 'closure' for the facility may be achieved (42 U.S.C. 6901-6992k, 2002). In response to this regulatory driver, and in recognition of project budgetary and safety constraints, it was decided to treat the residual sodium in the EBR-II primary and secondary sodium systems using a process known as 'carbonation.' In early EBR-II post-operation documentation, this process is also called 'passivation.' In the carbonation process (Sherman and Henslee, 2005), the system containing residual sodium is flushed with humidified carbon dioxide (CO{sub 2}). The water vapor in the flush gas reacts with residual sodium to form sodium hydroxide (NaOH), and the CO{sub 2} in the flush gas reacts with the newly formed NaOH to make sodium bicarbonate (NaHCO{sub 3}). Hydrogen gas (H{sub 2}) is produced as a by-product. The chemical reactions occur at the exposed surface of the residual sodium. The NaHCO{sub 3} layer that forms is porous, and humidified carbon dioxide can penetrate the NaHCO{sub 3} layer to continue reacting residual sodium underneath. The rate of reaction is controlled by the thickness of the NaHCO{sub 3} surface layer, the moisture input rate, and the residual sodium exposed surface area. At the end of carbonation, approximately 780 liters of residual sodium in the EBR-II primary tank ({approx}70% of original inventory), and just under 190 liters of residual sodium in the EBR-II secondary sodium system ({approx}50% of original inventory), were converted into NaHCO{sub 3}. No bare surfaces of residual sodium remained after treatment, and all remaining residual sodium deposits are covered by a layer of NaHCO{sub 3}. From a safety standpoint, the inventory of residual sodium in these systems was greatly reduced by using the carbonation process. From a regulatory standpoint, the process was not able to achieve deactivation of all residual sodium, and other more aggressive measures will be needed if the remaining residual sodium must also be deactivated to meet the requirements of the existing environmental permit. This chapter provides a project history and technical summary of the carbonation of EBR-II residual sodium. Options for future treatment are also discussed.

Sherman, S.; Knight, C.

2011-03-08T23:59:59.000Z

378

Heterovalent substitutions in Na2M2TeO6 family: Crystal structure, fast sodium ion conduction and phase transition of Na2LiFeTeO6  

Science Journals Connector (OSTI)

Abstract A new solid electrolyte Na2LiFeTeO6 has been prepared by solid-state reactions in air at 700 °C and characterized by powder X-ray diffraction, redox titration and impedance measurements on ceramic samples. It is a new superstructure type of the well-known hexagonal layered P2 type with complete ordering of Li, Fe and Te in octahedral brucite-like layers: orthorhombic, P212121, a = 5.2109(1), b = 8.9791(2), c = 11.2389(2) Å, Z = 4. At room temperature, sodium ions in the interlayer gap are concentrated in two of the six non-equivalent trigonal prisms; at elevated temperatures, they exhibit high ionic conductivity, e.g., 4 S/m at 300 °C. Orthorhombic distortion decreases on heating, presumably due to sodium movement, and vanishes at ca. 400 °C giving rise to the hexagonal Na2Co2TeO6-type structure. Analogous Na2LiRTeO6 (R = Al or Ga), Na2LiFeWO6, Na2Mn2TeO6, Na2M2WO6 (M = Ni or Cu), Na2NiMSbO6 (M = Al or Fe) and Na2NiAlTO6 (T = Nb or Ta) could not be prepared.

V.B. Nalbandyan; ?.?. Petrenko; M.A. Evstigneeva

2013-01-01T23:59:59.000Z

379

Photovoltaic mechanism in Na-substituted BiFeO3 films  

Science Journals Connector (OSTI)

Na-substituted BiFeO3 films were prepared on FTO/glass substrates using the sol–gel method. XRD results showed that all films adopted random orientation and an R3m perovskite structure. UV–Vis absorption results indicated that the films exhibited intense absorbance around 450 nm. The band gaps were 2.59 eV, 2.63 eV, 2.62 eV and 2.52 eV for the films substituted with 0%, 5%, 10% and 20% Na, respectively. A substantially enhanced photovoltaic effect was observed in the 20% Na substituted BiFeO3 film; its short-circuit current density was 1.26 µA cm?2 and the open circuit voltage was ?0.66 V. Meanwhile, polarization-modulated Jsc and Voc were observed in the 20% Na substituted BiFeO3 film and the mechanism was studied using the Schottky barrier combined with the ferroelectric polarization model.

Chengyan Wang; Xingyun Liu; Su Sheng; Yong Zhou; Hongri Liu; Yuxia Sun

2014-01-01T23:59:59.000Z

380

Results from DAMA/NaI and perspectives for DAMA/LIBRA  

E-Print Network (OSTI)

The about 100 kg highly radiopure NaI(Tl) set-up of the DAMA project (DAMA/NaI) took data over seven annual cycles up to July 2002 and has achieved results on various rare processes. Its main aim has actually been the exploitation of the model independent WIMP annual modulation signature. After this conference the total exposure, collected during the seven annual cycles, was released. This cumulative exposure (107731 kg day) has given a model independent evidence for the presence of a Dark Matter particle component in the galactic halo at 6.3 sigma C.L.; this main result is summarised here. Some of the many possible corollary model dependent quests for the candidate particle are mentioned. At present, after about five years of new developments, a second generation low background set-up (DAMA/LIBRA with a mass of about 250 kg NaI(Tl)) was built and is taking data since March 2003. New R&D efforts toward a possible NaI(Tl) ton set-up, we proposed in 1996, have been funded and started in 2003.

R. Bernabei; P. Belli; F. Cappella; F. Montecchia; F. Nozzoli; A. Incicchitti; D. Prosperi; R. Cerulli; C. J. Dai; H. H. Kuang; J. M. Ma; Z. P. Ye

2003-11-03T23:59:59.000Z

Note: This page contains sample records for the topic "butyl ether na" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Hydrogen embrittlement of a bimaterial C. Ayas, N.A. Fleck, V.S. Deshpande  

E-Print Network (OSTI)

Hydrogen embrittlement of a bimaterial C. Ayas, N.A. Fleck, V.S. Deshpande Department, or increase susceptibility to corrosion or hydrogen embrittlement (Sireesha et al., 2000). The weld strength. Hydrogen embrittlement is a recognised threat for welded joints since hy- drogen take-up can arise during

Fleck, Norman A.

382

Super-Elastic and Plastic Shock Waves Generated by Lasers N.A. Inogamov a,1  

E-Print Network (OSTI)

Super-Elastic and Plastic Shock Waves Generated by Lasers N.A. Inogamov a,1 , V.V. Zhakhovsky b,3 fortov@ihed.ras.ru, i oleynik@usf.edu Keywords: Femtosecond laser-matter interactions, elastic-plastic there is an elastic shock wave (SW), which propagates before the strong plastic shock with plastic pressures of up

Fominov, Yakov

383

E-Print Network 3.0 - alongamento mesenterial na Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

mutant... in Annexin V binding buffer (0.01 M Hepes, pH 7.4; 0.14 mM NaCl; 2.5 mM CaCl2). Two hundred microliters Source: Littman, Dan - Skirball Institute of Biomolecular...

384

E-Print Network 3.0 - alloiococcus otitidis na Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

the frequency of the NotI target site. In contrast... H 7.6), 20 mM NaCl, and 1 mM CaCl2. Crystals of the apo enzyme were grown (2.0 M (NH4)2SO4, 100 mM MES Source: Stoddard,...

385

E-Print Network 3.0 - anodo na oxidacao Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

(i.e., a biofilm that can efficiently transfer electrons... , 0.25-1.0 g; NH4Cl, 0.2 g; CaCl2,2H2O, 0.15 g; KCl, 0.33 g; NaCl, 0.30 g; MgCl2, 3.15 g; K2HPO4, 1... ). If methanogens...

386

Loanwords in Kali'na, a Cariban language of French Guyana Odile Renault-Lescure  

E-Print Network (OSTI)

. It is constituted by the five Guianas: Venezuelan Guiana, (formerly British) Guyana, Suriname, French Guiana distributed in these countries. 11.141 live in Venezuela, 3000 in Guyana (Forte 2000), 3000 in Suriname (Boven% in Suriname; there is no precise data for French Guiana, but the rate is high). The Kali'na people speak

Boyer, Edmond

387

Non-Born-Oppenheimer molecular dynamics of NaFH photodissociation Ahren W. Jaspera  

E-Print Network (OSTI)

Non-Born-Oppenheimer molecular dynamics of Na¯FH photodissociation Ahren W. Jaspera Combustion 20 November 2007 The accuracy of non-Born-Oppenheimer electronically nonadiabatic semiclassical are re- stricted to a single Born-Oppenheimer electronic state typi- cally, the ground electronic state

Truhlar, Donald G

388

Na K -pump ligands modulate gating of palytoxin-induced ion channels  

E-Print Network (OSTI)

proteins that mediate transport of ions across cell membranes, they traditionally have been viewed as very to the extracellular surface. The 3Na 2K -exchange transport cycle is completed when two extracellular K ions bind ensure the vectorial nature of net transport. The occluded-ion conformations, with binding sites

Gadsby, David

389

ION CHANNELS The Na/K-ATPase/Src complex and cardiotonic  

E-Print Network (OSTI)

machine for the ATP-dependent and -coupled transport of Na+ and K+ across the plasma membrane of a living sarcoplasmic reticulum Ca-ATPase Introduction The P-type ATPases control ion fluxes across the cell membrane;allow the movement of ions across the cell membrane. They could also alter the function

Brand, Paul H.

390

Na,K-ATPase Subunits as Markers for Epithelial-Mesenchymal Transition in Cancer and Fibrosis  

Science Journals Connector (OSTI)

...Cancer and Fibrosis Sigrid A. Rajasekaran 1 Thu P. Huynh 2 Daniel G. Wolle 1 Cromwell E. Espineda 2 Landon J. Inge 2 Anna...junction-associated proteins. J Biol Chem 2007;282:12127-34. 22 Violette MI , Madan P, Watson AJ. Na+/K+ -ATPase regulates tight...

Sigrid A. Rajasekaran; Thu P. Huynh; Daniel G. Wolle; Cromwell E. Espineda; Landon J. Inge; Anna Skay; Charles Lassman; Susanne B. Nicholas; Jeffrey F. Harper; Anna E. Reeves; Mansoor M. Ahmed; James M. Leatherman; James M. Mullin; and Ayyappan K. Rajasekaran

2010-06-01T23:59:59.000Z

391

Influence of NaCl on cathode performance of solid oxide fuel cells  

Science Journals Connector (OSTI)

Degradation induced by sodium chloride in air was...0.8Sr0.2)0.98MnO3(LSM) and La0.6Sr0.4Co0.2Fe0.8O3(LSCF) cathodes in solid oxide fuel cells(SOFC). Cell performance was measured by volatilizing NaCl to...2...fo...

Run-ru Liu; De-jun Wang; Jing Leng

2013-08-01T23:59:59.000Z

392

Grant Title: VERIZON FOUNDATION EDUCATION GRANTS Funding Opportunity Number: N/A  

E-Print Network (OSTI)

Grant Title: VERIZON FOUNDATION EDUCATION GRANTS Funding Opportunity Number: N/A Agency and Accessibility, Internet Safety). Grant applicants are required to select one or more outcomes and results for grants in each of their Funding Priorities. Detailed Information: http://foundation.verizon.com/grant

Farritor, Shane

393

Grant Title: IBM GRANTS PROGRAM Funding Opportunity Number: N/A  

E-Print Network (OSTI)

Grant Title: IBM GRANTS PROGRAM Funding Opportunity Number: N/A Agency/Department: IBM Grants.S. Internal Revenue Code. Summary: The main focus of the IBM Grants Program is on education due to the power Giving. Detailed Information: http://www.ibm.com/ibm/ibmgives/grant/grantapp.shtml #12;

Farritor, Shane

394

Grant Title: WILLIAM T. GRANT INVESTIGATOR INITIATED GRANTS Funding Opportunity Number: N/A  

E-Print Network (OSTI)

Grant Title: WILLIAM T. GRANT INVESTIGATOR INITIATED GRANTS Funding Opportunity Number: N/A Agency/Department: William T. Grant Foundation. Area of Research: The Foundation supports high-quality research January, early April, and early September for investigator-initiated research grants. Amount: The amount

Farritor, Shane

395

Grant Title: LAWRENCE FOUNDATION GRANTS PROGRAM Funding Opportunity Number: N/A  

E-Print Network (OSTI)

Grant Title: LAWRENCE FOUNDATION GRANTS PROGRAM Funding Opportunity Number: N/A Agency/Department: The Lawrence Foundation. Area of Reseach: Grants to support environmental, education, human services and other and libraries are eligible for contributions or grants. Summary: The foundation is focused on making grants

Farritor, Shane

396

Grant Title: CURE AUTISM NOW FOUNDATION Funding Opportunity Number: N/A  

E-Print Network (OSTI)

Grant Title: CURE AUTISM NOW FOUNDATION Funding Opportunity Number: N/A Agency/Department: Autism: Deadline varies for each grant. All proposals must be submitted online via the Autism Speaks grants-level research grant: $150,000/year maximum. For a pilot-level research grant: $60,000/year maximum. Length

Farritor, Shane

397

Grant Title: FACULTY SEED GRANTS Funding Opportunity Number: N/A  

E-Print Network (OSTI)

Grant Title: FACULTY SEED GRANTS Funding Opportunity Number: N/A Agency/Department: UNL, Office support. Faculty Seed Grants are available to scholars from all disciplines and can be used for whatever will be given to non-tenured junior faculty and to those who have not received a Grant-In-Aid or Faculty Seed

Farritor, Shane

398

Grant Title: PUBLIC WELFARE FOUNDATION Funding Opportunity Number: N/A  

E-Print Network (OSTI)

Grant Title: PUBLIC WELFARE FOUNDATION Funding Opportunity Number: N/A Agency, and November 18 annually. Amount: Grants range from $1,000-500,000. Length of Support: Most grants cover-year grants. Eligible Applicants: The Public Welfare Foundation does not accept requests to fund scholarships

Farritor, Shane

399

Grant Title: MARCH OF DIMES RESEARCH GRANTS Funding Opportunity Number: N/A  

E-Print Network (OSTI)

Grant Title: MARCH OF DIMES RESEARCH GRANTS Funding Opportunity Number: N/A Agency Research Awards are due annually on March 10. Amount: For a general March of Dimes Research Grant, the average grant is approximately $100,000 per year. Basil O'Connor Starter Scholar Research Awards are $150

Farritor, Shane

400

Grant Title: LINCOLN COMMUNITY FOUNDATION Funding Opportunity Number: N/A  

E-Print Network (OSTI)

Grant Title: LINCOLN COMMUNITY FOUNDATION Funding Opportunity Number: N/A Agency Quick Response Grant amount is $1000. Length of Support: From 1 to multiple years, based on scope: Competitive grants often include, but are not limited to, the arts and culture, children and youth, basic

Farritor, Shane

Note: This page contains sample records for the topic "butyl ether na" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Grant Title: DOW COMPANY -Education Grants Funding Opportunity Number: N/A  

E-Print Network (OSTI)

Grant Title: DOW COMPANY - Education Grants Funding Opportunity Number: N/A Agency boards. Summary: The Education Grants category includes yearly grants for Education. Dow is proud through the companyGIVES Education Grants Program. The program is a competitive grant process that allows

Farritor, Shane

402

Grant Title: GARTH BROOKS TEAMMATES FOR KIDS FOUNDATION Funding Opportunity Number: N/A  

E-Print Network (OSTI)

Grant Title: GARTH BROOKS TEAMMATES FOR KIDS FOUNDATION Funding Opportunity Number: N/A Agency prioritizes: grants that emphasize prevention and/or recovery from health problems; grants that enhance the health of needy children by promoting healthy lifestyles; and grants that provide access to medicine

Farritor, Shane

403

Grant Title: PACIFIC LIFE FOUNDATION GRANTS Funding Opportunity Number: N/A  

E-Print Network (OSTI)

Grant Title: PACIFIC LIFE FOUNDATION GRANTS Funding Opportunity Number: N/A Agency is made in early November, with payment intended to be made before the end of January. Award of a grant does not mean that future support will automatically be available. Amount: General grants range from $5

Farritor, Shane

404

Grant Title: AMERICAN FOUNDATION FOR SUICIDE PREVENTION Funding Opportunity Number: N/A  

E-Print Network (OSTI)

Grant Title: AMERICAN FOUNDATION FOR SUICIDE PREVENTION Funding Opportunity Number: N/A Agency: Distinguished Investigator Grants for up to $100,000 over the grant period. Standard Research Grants: Up to $75,000 over the grant period. Linked Standard Research Grants: Up to $225,000 over the grant period. Young

Farritor, Shane

405

Grant Title: GRAMMY FOUNDATION GRANTS Funding Opportunity Number: N/A  

E-Print Network (OSTI)

Grant Title: GRAMMY FOUNDATION GRANTS Funding Opportunity Number: N/A Agency/Department: The GRAMMY Applicants: The GRAMMY Foundation Grant Program awards grants to organizations and individuals to support to the impact of music on the human condition. Summary: The GRAMMY Foundation Grant Program awards grants

Farritor, Shane

406

Grant Title: ALFRED P. SLOAN FOUNDATION Funding Opportunity Number: N/A  

E-Print Network (OSTI)

Grant Title: ALFRED P. SLOAN FOUNDATION Funding Opportunity Number: N/A Agency/Department: Alfred P of inquiry will be contacted and invited to submit a formal grant proposal. Amount: For grant requests of $50,000 or less, no overhead costs are permitted. For grant requests larger than $50,000, overhead costs may total

Farritor, Shane

407

Grant Title: FORD FOUNDATION GRANTS Funding Opportunity Number: N/A  

E-Print Network (OSTI)

Grant Title: FORD FOUNDATION GRANTS Funding Opportunity Number: N/A Agency/Department: The Ford for a grant by visiting the Grants section of the Foundation's website and submitting an online grant inquiry: Not listed. Eligible Applicants: Activities supported by grants and program-related investments must

Farritor, Shane

408

Grant Title: THE AMERICAN PHILOSOPHICAL SOCIETY FELLOWSHIP AND GRANTS Funding Opportunity Number: N/A  

E-Print Network (OSTI)

Grant Title: THE AMERICAN PHILOSOPHICAL SOCIETY FELLOWSHIP AND GRANTS Funding Opportunity Number: N/A Agency/Department: The American Philosophical Society. Area of Research: Fellowships and grants: September 1; Franklin Research Grants: October 1 and December 1; Lewis and Clark Fund for Exploration

Farritor, Shane

409

Roles for Mitochondrial and Reverse Mode Na /Ca2 and the Plasmalemma Ca2  

E-Print Network (OSTI)

Roles for Mitochondrial and Reverse Mode Na /Ca2 Exchange and the Plasmalemma Ca2 ATPase in Post the processes regulating presynaptic cal- cium concentration ([Ca2 ]i ) in the generation of post-tetanic potentiation (PTP) at crayfish neuromuscular junctions, using spectrophotometric dyes to measure changes in [Ca

Zucker, Robert S.

410

Enhancement of direct sulfation of limestone by Na2CO3 addition  

Science Journals Connector (OSTI)

For an oxy-fuel circulating fluidized bed combustion system, the limestone calcination is normally prevented due to excessive CO2 partial pressures and the limestone is subject to a direct sulfation reaction. The enhancement of the direct sulfation of limestone by Na2CO3 was investigated under high CO2 partial pressure in a thermogravimetric apparatus (TGA) and scanning electron microscope (SEM) analysis method. A commercial limestone with a mean size of 18.8 ?m was used. Experimental results indicate that the incorporation of Na+ ions in solid product CaSO4 lattice structures results in formation of more extrinsic point defects in the crystal lattices of CaSO4 and a significantly increased solid-state diffusivity/mobility in the solid product. So the direct sulfation of Na2CO3-doped limestone shows higher rate and higher degree of conversion in the later stage of sulfation, in comparison with the direct sulfation of original limestone. The reaction changes from diffusional control to chemical reaction control in the presence of Na2CO3 because of the effect of foreign ions on accelerating the solid-state diffusion.

Chuanmin Chen; Ye Zhuang; Chunbo Wang

2009-01-01T23:59:59.000Z

411

Upper limit on the cross section for reactor antineutrinos changing 22Na decay rates  

E-Print Network (OSTI)

In this paper we present results of a long-term observation of the decay of 22Na in the presence of a nuclear fission reactor. The measurements were made outside the containment wall of and underneath the Koeberg nuclear power plant near Cape Town, South Africa. Antineutrino fluxes ranged from ~5*10^11 to 1.6*10^13 cm^-2 s^-1 during this period. We show that the coincidence summing technique provides a sensitive tool to measure a change in the total decay constant as well as the branching ratio between EC and beta+ decay of 22Na to the first excited state in 22Ne. We observe a relative change in count rate between reactor-ON and reactor-OFF equal to (-0.51+/-0.11)*10^-4. After evaluating possible systematic uncertainties we conclude that the effect is either due to a hidden instrumental cause or due to an interaction between antineutrinos and the 22Na nucleus. An upper limit of ~0.03 barn has been deduced for observing any change in the decay rate of 22Na due to antineutrino interactions.

de Meijer, R J

2014-01-01T23:59:59.000Z

412

Upper limit on the cross section for reactor antineutrinos changing 22Na decay rates  

E-Print Network (OSTI)

In this paper we present results of a long-term observation of the decay of 22Na in the presence of a nuclear fission reactor. The measurements were made outside the containment wall of and underneath the Koeberg nuclear power plant near Cape Town, South Africa. Antineutrino fluxes ranged from ~5*10^11 to 1.6*10^13 cm^-2 s^-1 during this period. We show that the coincidence summing technique provides a sensitive tool to measure a change in the total decay constant as well as the branching ratio between EC and beta+ decay of 22Na to the first excited state in 22Ne. We observe a relative change in count rate between reactor-ON and reactor-OFF equal to (-0.51+/-0.11)*10^-4. After evaluating possible systematic uncertainties we conclude that the effect is either due to a hidden instrumental cause or due to an interaction between antineutrinos and the 22Na nucleus. An upper limit of ~0.03 barn has been deduced for observing any change in the decay rate of 22Na due to antineutrino interactions.

R. J. de Meijer; S. W. Steyn

2014-09-23T23:59:59.000Z

413

LANL surveillance requirements management and surveillance requirements from NA-12 tasking memo  

SciTech Connect

Surveillance briefing to NNSA to support a tasking memo from NA-12 on Surveillance requirements. This talk presents the process for developing surveillance requirements, discusses the LANL requirements that were issued as part of that tasking memo, and presents recommendations on Component Evaluation and Planning Committee activities for FY11.

Hills, Charles R [Los Alamos National Laboratory

2011-01-25T23:59:59.000Z

414

Measurement of (n,a) reactions on 147 Sm using a lead  

E-Print Network (OSTI)

of Mechanical, Aerospace and Nuclear Engineering, Rensselaer Polytechnic Institute, Troy, New York 12180, USA b 12180, USA c Los Alamos Neutron Science Center Los Alamos National Laboratory, Los Alamos, New Mexico of the (n,a) cross section on 147 Sm and perform measurements on 149 Sm over the energy range 0.1 eV­10 ke

Danon, Yaron

415

Biomaterials 28 (2007) 49014911 Stresscorrosion crack growth of SiNaKMgCaPO bioactive  

E-Print Network (OSTI)

Elsevier Ltd. All rights reserved. Keywords: Stress corrosion; Bioactive glass; Subcritical crack growthBiomaterials 28 (2007) 4901­4911 Stress­corrosion crack growth of Si­Na­K­Mg­Ca­P­O bioactive Available online 21 August 2007 Abstract This paper describes research on the stress­corrosion crack growth

Ritchie, Robert

416

Erratum: High-NA aberration retrieval with the Extended Nijboer-Zernike  

E-Print Network (OSTI)

of Technology, Lorentzweg 1, NL-2628 CJ Delft, The Netherlands P. Dirksen, A.J.E.M. Janssen Philips Research Europe, Professor Holstlaan 4, NL-5656 AA Eindhoven, The Netherlands In the paper "High-NA aberration regrettable notation errors are present in Eq.(10), page 06004-3. The expression gives the azimuthal Fourier

417

Temperature induced immiscibility in the NaCl?H[subscript 2]O system at high pressure  

SciTech Connect

High-pressure polymorphs of H{sub 2}O are a major component in many outer planets, extra solar bodies, and icy satellites. This study sought to examine the influence of ionic impurities on the phase stability, thermal expansion, and melting curve of ice VII. Powder diffraction patterns of ice VII formed from pure H{sub 2}O and 5 wt.% NaCl aqueous solutions were taken at room temperature up to 11.1 {+-} 0.3 and 26.6 {+-} 0.4 GPa, respectively. Thermal expansions, {alpha}, of all ice VII samples were recorded and modeled up to the melting point of the samples. Ice VII formed from a NaCl-bearing aqueous solution at pressures greater than 2.2 GPa and less than 500 K can be indexed by ice VII only, whereas at temperatures greater than 500 K, diffraction lines indicative of halite (NaCl) are observed and become more intense with increasing temperature and only disappear at the melting point of the high-pressure ice. This phenomenon was observed in all NaCl-bearing ice samples that were heated to greater than 500 K. The melting curves of ice VII formed from pure H{sub 2}O and a 5 wt.% NaCl aqueous solution suggest that the presence of Na{sup +} and Cl{sup -} in the ice VII structure results in a depression of the melting curve by approximately 40 K. The exsolution of halite from the NaCl-doped ice VII and the depression of the ice VII melting curve suggest that the presence of ionic impurities in ice VII may promote the formation of a self-segregating zone deep within ice-rich bodies. This zone could initiate the formation of solute-rich melt pockets that may ascend toward the surface and result in surface manifestations such as solute-bearing aqueous vents, unexplained domes/diapirism, and/or salt-rich regions.

Frank, M.R.; Scott, H.P.; Maglio, S.J.; Prakapenka, V.B.; Shen, G. (NIU); (CIW); (UC); (Indiana)

2008-10-09T23:59:59.000Z

418

Na, Mg, Ni and Cs distribution and speciation after long-term alteration of a simulated nuclear waste glass  

E-Print Network (OSTI)

distribution and speciation of Na, Mg, Ni and Cs in a simulated (inactive) nuclear waste glass were studied and Cs represent dose determining long-lived radionuclides (59 Ni, 135 Cs) in vitrified nuclear wasteNa, Mg, Ni and Cs distribution and speciation after long-term alteration of a simulated nuclear

419

Experimental and Theoretical Investigations of the NMR Line Shapes of LiF and NaF Single Crystals  

Science Journals Connector (OSTI)

Experimental cw line shapes have been obtained for Li7, Na23, and F19 nuclei in NaF and LiF single crystals, and compared with several line-shape theories. A new line-shape theory is described which gives better results than previous ones for these two crystal systems.

Ben T. Gravely and J. D. Memory

1971-05-15T23:59:59.000Z

420

Calcite dissolution and Ca/Na ion-exchange reactions in columns with different flow rates through high ESR soil  

E-Print Network (OSTI)

The leaching of a Na?-affected calcareous soil with water results in two concurrent recesses: (i) CaCO? dissolution, and (ii) replacement of Na? on the cation-exchange complex by Ca²?. In the current study, Woodward soil (coarse-silty, mixed...

Navarre, Audrey

2012-06-07T23:59:59.000Z

Note: This page contains sample records for the topic "butyl ether na" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Advances in X-Ray Chemical Analysis, Japan, 45 (2014) ISSN 0911-7806 Color Center in NaCl  

E-Print Network (OSTI)

. In addition, the color of NaCl changes to pale purple when irradiated with 405 nm laser after X-ray irradiation and to light brown when irradiated with 532 nm laser after X-ray irradiation. The colorCl, Sodium chloride, X-ray irradiation, Laser irradiation, White fluorescent lamp irradiation X X NaCl X X X

Jun, Kawai

422

Improved Hydrogen Storage Kinetics of Nanoconfined NaAlH4 Catalyzed with TiCl3 Nanoparticles  

Science Journals Connector (OSTI)

Improved Hydrogen Storage Kinetics of Nanoconfined NaAlH4 Catalyzed with TiCl3 Nanoparticles ... We demonstrate that NaAlH4 confined within the nanopores of a titanium-functionalized metal–organic framework (MOF) template MOF-74(Mg) can reversibly store hydrogen with minimal loss of capacity. ...

Thomas K. Nielsen; Marek Polanski; Dariusz Zasada; Payam Javadian; Flemming Besenbacher; Jerzy Bystrzycki; Jørgen Skibsted; Torben R. Jensen

2011-03-29T23:59:59.000Z

423

Modeling the sorption dynamics of NaH using a reactive force field J. G. O. Ojwang,1,a  

E-Print Network (OSTI)

Modeling the sorption dynamics of NaH using a reactive force field J. G. O. Ojwang,1,a Rutger van that the fall in potential energy is associated with either cluster fragmentation or de- sorption of molecular ReaxFFNaAlH4 to study the structural and dynamical details of hydrogen ab de sorption processes in Na

Goddard III, William A.

424

Cleaning residual NaK in the fast flux test facility fuel storage cooling system  

SciTech Connect

The Fast Flux Test Facility (FFTF), located on the U.S. Department of Energy's Hanford Reservation, is a liquid metal-cooled test reactor. The FFTF was constructed to support the U.S. Liquid Metal Fast Breeder Reactor Program. The bulk of the alkali metal (sodium and NaK) has been drained and will be stored onsite prior to final disposition. Residual NaK needed to be removed from the pipes, pumps, heat exchangers, tanks, and vessels in the Fuel Storage Facility (FSF) cooling system. The cooling system was drained in 2004 leaving residual NaK in the pipes and equipment. The estimated residual NaK volume was 76 liters in the storage tank, 1.9 liters in the expansion tank, and 19-39 liters in the heat transfer loop. The residual NaK volume in the remainder of the system was expected to be very small, consisting of films, droplets, and very small pools. The NaK in the FSF Cooling System was not radiologically contaminated. The portions of the cooling system to be cleaned were divided into four groups: 1. The storage tank, filter, pump, and associated piping; 2. The heat exchanger, expansion tank, and associated piping; 3. Argon supply piping; 4. In-vessel heat transfer loop. The cleaning was contracted to Creative Engineers, Inc. (CEI) and they used their superheated steam process to clean the cooling system. It has been concluded that during the modification activities (prior to CEI coming onsite) to prepare the NaK Cooling System for cleaning, tank T-914 was pressurized relative to the In-Vessel NaK Cooler and NaK was pushed from the tank back into the Cooler and that on November 6, 2005, when the gas purge through the In-Vessel NaK Cooler was increased from 141.6 slm to 283.2 slm, NaK was forced from the In-Vessel NaK Cooler and it contacted water in the vent line and/or scrubber. The gases from the reaction then traveled back through the vent line coating the internal surface of the vent line with NaK and NaK reaction products. The hot gases also exited the scrubber through the stack and due to the temperature of the gas, the hydrogen auto ignited when it mixed with the oxygen in the air. There was no damage to equipment, no injuries, and no significant release of hazardous material. Even though the FSF Cooling System is the only system at FFTF that contains residual NaK, there are lessons to be learned from this event that can be applied to future residual sodium removal activities. The lessons learned are: - Before cleaning equipment containing residual alkali metal the volume of alkali metal in the equipment should be minimized to the extent practical. As much as possible, reconfirm the amount and location of the alkali metal immediately prior to cleaning, especially if additional evolutions have been performed or significant time has passed. This is especially true for small diameter pipe (<20.3 centimeters diameter) that is being cleaned in place since gas flow is more likely to move the alkali metal. Potential confirmation methods could include visual inspection (difficult in all-metal systems), nondestructive examination (e.g., ultrasonic measurements) and repeating previous evolutions used to drain the system. Also, expect to find alkali metal in places it would not reasonably be expected to be. - Staff with an intimate knowledge of the plant equipment and the bulk alkali metal draining activities is critical to being able to confirm the amount and locations of the alkali metal residuals and to safely clean the residuals. - Minimize the potential for movement of alkali metal during cleaning or limit the distance and locations into which alkali metal can move. - Recognize that when working with alkali metal reactions, occasional pops and bangs are to be anticipated. - Pre-plan emergency responses to unplanned events to assure responses planned for an operating reactor are appropriate for the deactivation phase.

Burke, T.M.; Church, W.R. [Fluor Hanford, PO Box 1000, Richland, Washington, 99352 (United States); Hodgson, K.M. [Fluor Government Group, PO Box 1050, Richland, Washington, 99352 (United States)

2008-01-15T23:59:59.000Z

425

Investigations to convert CO2, NaCl and H2O into Na2CO3 and \\{HCl\\} by thermal solar energy with high solar efficiency  

Science Journals Connector (OSTI)

Abstract Exhaust CO2, NaCl and H2O can be converted to Na2CO3 and \\{HCl\\} by the MgCl2/MgO modified ammonia soda process at a maximum temperature of 525 °C. Such a temperature is easily reached by solar troughs. Subsequently this process stores thermal solar energy as chemical energy and concomitantly CO2 can be removed from the environment. The process has been investigated theoretically and experimentally to further enhance its solar efficiency. It is shown theoretically that Mg-compounds are unique for this process and that the MgCl2/MgO modification is optimal. Experiments demonstrate that by splitting the main reaction of this process into two steps the solar efficiency can be enhanced to 21.5% and very highly concentrated \\{HClaq\\} can be obtained. The yield of the main chemical reaction exceeds 95% at 525 °C. Suggestions are given for an improved thermal solar trough system to perform the main chemical reaction.

Martin Forster

2014-01-01T23:59:59.000Z

426

K{sub 2}NaOsO{sub 5.5} and K{sub 3}NaOs{sub 2}O{sub 9}: The first osmium perovskites containing alkali cations at the 'A' site  

SciTech Connect

K{sub 2}NaOsO{sub 5.5} and K{sub 3}NaOs{sub 2}O{sub 9} were obtained from solid-state reactions of potassium superoxide, sodium peroxide and osmium metal at elevated oxygen pressures. K{sub 2}NaOsO{sub 5.5} crystallizes as an oxygen-deficient cubic double perovskite in space group Fm3{sup Macron }m with a=8.4184(5) A and contains isolated OsO{sub 6} octahedra. K{sub 3}NaOs{sub 2}O{sub 9} crystallizes hexagonally in P6{sub 3}/mmc with a=5.9998(4) A and c=14.3053(14) A. K{sub 3}NaOs{sub 2}O{sub 9} consists of face sharing Os{sub 2}O{sub 9} pairs of octahedra. According to magnetic measurements K{sub 2}NaOsO{sub 5.5} is diamagnetic, whereas K{sub 3}NaOs{sub 2}O{sub 9} displays strong antiferromagnetic coupling (T{sub N}=140 K), indicating enhanced magnetic interactions within the octahedral pair. - Graphical abstract: High oxidation states of Os, obtained by high oxygen pressure synthesis, are accommodated in double and triple perovskite matrices. K{sub 3}NaOs{sub 2}O{sub 9} displays enhanced magnetic interactions. Highlights: Black-Right-Pointing-Pointer New osmates containing highly oxidized Os were obtained by high O{sub 2} pressure synthesis. Black-Right-Pointing-Pointer High oxidation states of Os are accommodated in double and triple perovskite matrices. Black-Right-Pointing-Pointer Both compounds represent the first Os perovskites with an alkali metal at the A site. Black-Right-Pointing-Pointer K{sub 3}NaOs{sub 2}O{sub 9} displays enhanced magnetic interactions within the octahedral pair.

Mogare, Kailash M.; Klein, Wilhelm [Stuttgart, Max-Planck-Institut fuer Festkoerperforschung, Heisenbergstrasse 1, 70569 Stuttgart (Germany); Jansen, Martin, E-mail: M.Jansen@fkf.mpg.de [Stuttgart, Max-Planck-Institut fuer Festkoerperforschung, Heisenbergstrasse 1, 70569 Stuttgart (Germany)

2012-07-15T23:59:59.000Z

427

Synthesis, structure and properties of new chain cuprates, Na{sub 3}Cu{sub 2}O{sub 4} and Na{sub 8}Cu{sub 5}O{sub 10}  

SciTech Connect

Na{sub 3}Cu{sub 2}O{sub 4} and Na{sub 8}Cu{sub 5}O{sub 10} were prepared via the azide/nitrate route from stoichiometric mixtures of the precursors CuO, NaN{sub 3} and NaNO{sub 3}. Single crystals have been grown by subsequent annealing of the as prepared powders at 500 deg. C for 2000h in silver crucibles, which were sealed in glass ampoules under dried Ar. According to the X-ray analysis of the crystal structures (Na{sub 3}Cu{sub 2}O{sub 4}: P2{sub 1}/n, Z=4, a=5.7046(2), b=11.0591(4), c=8.0261(3)A, {beta}=108.389(1){sup o}, 2516 independent reflections, R{sub 1}(all)=0.0813, wR{sub 2} (all)=0.1223; Na{sub 8}Cu{sub 5}O{sub 10}: Cm, Z=2, a=8.228(1), b=13.929(2), c=5.707(1)A, {beta}=111.718(2){sup o}, 2949 independent reflections, R{sub 1}(all)=0.0349, wR{sub 2} (all)=0.0850), the main feature of both crystal structures are CuO{sub 2} chains built up from planar, edge-sharing CuO{sub 4} squares. From the analysis of the Cu-O bond lengths, the valence states of either +2 or +3 can be unambiguously assigned to each copper atom. In Na{sub 3}Cu{sub 2}O{sub 4} these ions alternate in the chains, in Na{sub 8}Cu{sub 5}O{sub 10} the periodically repeated part consists of five atoms according to Cu{sup II}-Cu{sup II}-Cu{sup III}-Cu{sup II}-Cu{sup III}. The magnetic susceptibilities show the dominance of antiferromagnetic interactions. At high temperatures the compounds exhibit Curie-Weiss behaviour (Na{sub 3}Cu{sub 2}O{sub 4}: {mu}=1.7{mu}{sub B}, {theta}=-160K, Na{sub 8}Cu{sub 5}O{sub 10}: {mu}=1.8{mu}{sub B}, {theta}=-58K, magnetic moments per divalent copper ion). Antiferromagmetic ordering is observed to occur in these compounds below 13K (Na{sub 3}Cu{sub 2}O{sub 4}) and 24K (Na{sub 8}Cu{sub 5}O{sub 10})

Sofin, Mikhail [Max-Planck-Institut fuer Festkoerperforschung, Heisenbergstr. 1, D-70569 Stuttgart (Germany); Peters, Eva-Maria [Max-Planck-Institut fuer Festkoerperforschung, Heisenbergstr. 1, D-70569 Stuttgart (Germany); Jansen, Martin [Max-Planck-Institut fuer Festkoerperforschung, Heisenbergstr. 1, D-70569 Stuttgart (Germany)]. E-mail: jansen@fkf.mpg.de

2005-12-15T23:59:59.000Z

428

2011 Annual Workforce Analysis and Staffing Plan Report - NNSA HQ NA-10  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

printed 2/17/2012 2:23:00 PM Page 1 of 8 printed 2/17/2012 2:23:00 PM Page 1 of 8 Annual Workforce Analysis and Staffing Plan Report As of December 31, 2011 Reporting Office: NNSA NA-10 HQ (including NA-15 inputs) Section One: Current Mission(s) of the Organization and Potential Changes NNSA Mission: To strengthen United States security through the military application of nuclear energy. NNSA Vision: To be an integrated nuclear security enterprise operating an efficient and agile nuclear weapons complex, recognized as preeminent in technical leadership and program management. Organizational Changes: NNSA is in the final phase of re-organizing. This plan reflects known changes that resulted from the elimination of the ABQ Service Center and re-distribution of the functions and personnel, some of whom were part of the TQP Program. The plan has also

429

MHK Projects/Ocean Navitas NaREC | Open Energy Information  

Open Energy Info (EERE)

Navitas NaREC Navitas NaREC < MHK Projects Jump to: navigation, search << Return to the MHK database homepage Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":5,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"500px","height":"350px","centre":false,"title":"","label":"","icon":"File:Aquamarine-marker.png","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":55.1294,"lon":-1.50652,"alt":0,"address":"","icon":"http:\/\/prod-http-80-800498448.us-east-1.elb.amazonaws.com\/w\/images\/7\/74\/Aquamarine-marker.png","group":"","inlineLabel":"","visitedicon":""}]}

430

OFFICE OF CIVIL RIGHTS NA-1.2 VIDEO LIBRARY Item Title  

National Nuclear Security Administration (NNSA)

OFFICE OF CIVIL RIGHTS NA-1.2 OFFICE OF CIVIL RIGHTS NA-1.2 VIDEO LIBRARY Item # Title # of copies DVD / CD Length Year Publisher 1 A Clear Picture - Harassment in the Public Sector- Una Imagen Clara Acosoen el Sector Publico 1 DVD 2008 Coastal Training Technologies Corp. A Dupont Company 2 Harassment Hurts: It's Personal 1 DVD 16 min 2009 ATS Media 3 Harassment Is .. (government version) 1 DVD 21 min 2005 Coastal Training Technologies Corp. A Dupont Company 4 Harassment Made Simple 1 DVD 6 min 2011 TrainingABC 5 Harassment Training for Supervisors: Let's Face It. Capacitaci ón contra el Hostigamiento para Supervisores Enfrent émoslo 1 DVD 58 min 2007 Coastal Training Technologies Corp. A Dupont Company 6 It's UP to You: Stopping Sexual Harassment for Managers 1 DVD 27 min 2005 ATS Media 7 OpenLines: Exploring Harassment

431

Defective graphene as promising anode material for Na-ion battery and Ca-ion battery  

E-Print Network (OSTI)

We have investigated adsorption of Na and Ca on graphene with divacancy (DV) and Stone-Wales (SW) defect. Our results show that adsorption is not possible on pristine graphene. However, their adsorption on defective sheet is energetically favorable. The enhanced adsorption can be attributed to the increased charge transfer between adatoms and underlying defective sheet. With the increase in defect density until certain possible limit, maximum percentage of adsorption also increases giving higher battery capacity. For maximum possible DV defect, we can achieve maximum capacity of 1459 mAh/g for Na-ion batteries (NIBs) and 2900 mAh/g for Ca-ion batteries (CIBs). For graphene full of SW defect, we find the maximum capacity of NIBs and CIBs is around 1071 mAh/g and 2142 mAh/g respectively. Our results will help create better anode materials with much higher capacity and better cycling performance for NIBs and CIBs.

Datta, Dibakar; Shenoy, Vivek B

2013-01-01T23:59:59.000Z

432

Low-energy positron-diffraction study of NaF and LiF  

Science Journals Connector (OSTI)

Using a magnetically transported beam of slow positrons, we have measured the elastic backscattering probability versus energy for positrons normally incident on air-cleaved and vacuum-cleaved (100) surfaces of NaF and LiF. We observe enormous first-order Bragg peaks and several higher-order peaks, the positions of which imply an inner potential of -0.5±0.2 and -0.1±0.2 eV for NaF and LiF, respectively. The atomic plane spacings are equal to the bulk values within 1/2%. There are only slight differences between the data obtained using the freshly air-cleaved and the vacuum-cleaved surfaces. Surface disorder may be responsible for the presence of some weak Bragg reflections corresponding to directions that would otherwise be inaccessible to the incident positron beam. The temperature dependence indicates that the disorder would not have a thermal origin.

A. P. Mills; Jr. and W. S. Crane

1985-03-15T23:59:59.000Z

433

DALI2: A NaI(Tl) detector array for measurements of $?$ rays from fast nuclei  

E-Print Network (OSTI)

A NaI(Tl) detector array called DALI2 (Detector Array for Low Intensity radiation 2) has been constructed for in-beam $\\gamma$-ray spectroscopy experiments with fast radioactive isotope (RI) beams. It consists typically of 186 NaI(Tl) scintillators covering polar angles from $\\sim$15$^{\\circ}$ to $\\sim$160$^{\\circ}$ with an average angular resolution of 6$^{\\circ}$ in full width at half maximum. Its high granularity (good angular resolution) enables Doppler-shift corrections that result in, for example, 10% energy resolution and 20% full-energy photopeak efficiency for 1-MeV $\\gamma$ rays emitted from fast-moving nuclei (velocities of $v/c \\simeq 0.6$). DALI2 has been employed successfully in numerous experiments using fast RI beams with velocities of $v/c = 0.3 - 0.6$ provided by the RIKEN RI Beam Factory.

S. Takeuchi; T. Motobayashi; Y. Togano; M. Matsushita; N. Aoi; K. Demichi; H. Hasegawa; H. Murakami

2014-06-24T23:59:59.000Z

434

MHK Projects/University of Manchester Phase 1 and 2 NaREC | Open Energy  

Open Energy Info (EERE)

University of Manchester Phase 1 and 2 NaREC University of Manchester Phase 1 and 2 NaREC < MHK Projects Jump to: navigation, search << Return to the MHK database homepage Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":5,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"500px","height":"350px","centre":false,"title":"","label":"","icon":"File:Aquamarine-marker.png","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":55.1294,"lon":-1.50652,"alt":0,"address":"","icon":"http:\/\/prod-http-80-800498448.us-east-1.elb.amazonaws.com\/w\/images\/7\/74\/Aquamarine-marker.png","group":"","inlineLabel":"","visitedicon":""}]}

435

Short-Range Layered A-Site Ordering in Double Perovskites NaLaBB?O6 (B = Mn, Fe; B? = Nb, Ta)  

Science Journals Connector (OSTI)

The magnetic exchange interactions in NaLaFeTaO6 and NaLaFeNbO6 are antiferromagnetic, while they are ferromagnetic in NaLaMnTaO6 and NaLaMnNbO6. ... This work has benefited from the use of HIPD at the Lujan Center at Los Alamos Neutron Science Center, funded by DOE Office of Basic Energy Sciences. ...

Walid Dachraoui; Tao Yang; Chang Liu; Graham King; Joke Hadermann; Gustaaf Van Tendeloo; Anna Llobet; Martha Greenblatt

2011-04-14T23:59:59.000Z

436

Sistematizao de ocorrncias de desastres naturais na regio Sul do Brasil Silvia Midori Saito1  

E-Print Network (OSTI)

Sistematização de ocorrências de desastres naturais na região Sul do Brasil Silvia Midori Saito1 - GEODESASTRES-SUL Caixa Postal 5021 - CEP: 97110-970, Santa Maria, RS, Brasil {silvia.saito; camila próximo artigo 39 Anais XIV Simpósio Brasileiro de Sensoriamento Remoto, Natal, Brasil, 25-30 abril 2009

437

LIVROS DIDTICOS E SUAS FUNES PARA O PROFESSOR DE MATEMTICA NO BRASIL E NA FRANA.  

E-Print Network (OSTI)

LIVROS DIDÁTICOS E SUAS FUN��ES PARA O PROFESSOR DE MATEMÁTICA NO BRASIL E NA FRAN�A. Clovis Gomes (França) GP 0517 Psicologia da educação matemática ­UNICAMP Campinas SP (Brasil) Jean dois países. No Brasil a compra de livros didáticos pelo governo brasileiro envolve volumes e cifras de

Paris-Sud XI, Université de

438

Technical Qualification Program Self-Assessment Report- NA-SH- 2013  

Energy.gov (U.S. Department of Energy (DOE))

The Office of the Associate Administrator for Safety and Health (NA-SH) TQP applies to those personnel who oversee defense nuclear facilities, to support the mission of NNSA. The requirement for this SA comes from DOE O 426.1A that states "Headquarters and Field Elements must conduct self-assessment of TQP and FTCP implementation within their organization at least every 4 years."

439

Two-photon absorption of color centers in NaF  

Science Journals Connector (OSTI)

Two-photon absorption cross sections of the N1 and F3+ centers in NaF have been determined by means of the luminescence excited by the two-photon absorption. The measured polarization dependence of the process led us to attribute the excitation to the Ag?Ag transition in the N1 center and to the A?E transition in the F3+ center.

M. Casalboni; U. M. Grassano; A. Tanga

1979-03-15T23:59:59.000Z

440

Introduction L'Encyclopdie des Carabes ou Encyclopdie des Kali'na du Suriname  

E-Print Network (OSTI)

Introduction « L'Encyclopédie des Caraïbes » ou Encyclopédie des Kali'na du Suriname Odile Renault Suriname, jusqu'à la deuxième moitié du 20ème siècle5, pour désigner les peuples et langues de famille étude comparée des langues de la famille caribe du Suriname, ainsi que des descriptions grammaticales et

Boyer, Edmond

Note: This page contains sample records for the topic "butyl ether na" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

{alpha}-particle optical potentials for nuclear astrophysics (NA) and nuclear technology (NT)  

SciTech Connect

The high precision of recent measurements for low-energy {alpha}-particle elastic-scattering as well as induced-reaction data makes possible the understanding of actual limits and possible improvement of the global optical model potentials parameters. Involvement of recent optical potentials for reliable description of both the elastic scattering and emission of {alpha}-particles, of equal interest for nuclear astrophysics (NA) and nuclear technology (NT) for fusion devices, is discussed in the present work.

Avrigeanu, V.; Avrigeanu, M. [Horia Hulubei National Institute for Physics and Nuclear Engineering, POBox MG-6, 077125 Magurele, Ilfov (Romania)

2012-11-20T23:59:59.000Z

442

Honeywell FM&T, LLC Contract No. DE-NA0000622  

National Nuclear Security Administration (NNSA)

FM&T, LLC FM&T, LLC Contract No. DE-NA0000622 Modification No. 016 Page 2 of 10 1. Part II - Contract Clauses. The following Section I clause is revised and replaced in its entirety as follows: I-11 52.204-4 PRINTED OR COPIED DOUBLE-SIDED ON POSTCONSUMER FIBER CONTENT PAPER (MAY 2011) (a) Definitions. As used in this clause- "Postconsumer fiber" means- (1) Paper, paperboard, and fibrous materials from retail stores, office

443

Tezaver slovenskega ljudskega jezika na Koroškem – dokaz živosti graške slavistike  

E-Print Network (OSTI)

do K, v pripravi je sedmi zvezek od L do M), v drugem pa kartografiranje posameznih diatopnih sinonimov na avstrijskem Koroškem. The article deals with the long-term dialectological project of creat- ing a lexical inventory of the Slovene... zurück gegen Norden bis an die Mur, und von Hermagor westlich hinauf bis nach Luggau, so hat die Annahme des Vorrückens Deutscher Sprache alle Jahrhundert um eine Stunde beinahe Gewissheit erlangt (Jarnik 1826). Dandanes povzro?ajo germanizacijo...

Karni?ar, Ludvik

2010-02-01T23:59:59.000Z

444

Aktivity Czech ICT Alliance na podporu inovac Michal Zlesk, Jitka Studenkov  

E-Print Network (OSTI)

Aktivity Czech ICT Alliance na podporu inovací Michal Zálesák, Jitka Studeníková Czech ICT Alliance Pedstavení Czech ICT Alliance Czech ICT Alliance je oficiální exportní aliance pro ICT vládní agentury Czech okruhy: · Aktivity v zahranicí · Aktivity v CR · Podpora inovací · Prbzné aktivity Czech ICT Alliance se

Savicky, Petr

445

Evaluation of aqueous Na{sup +}/Cs{sup +} separation by electrodialysis  

SciTech Connect

In support of the Hanford Site cleanup, electrodialysis is being investigated as a method to separate aqueous sodium (Na{sup +}) and cesium (Cs{sup +}) ions. The approach has many advantages over existing separation technologies; in particular, electrodialysis creates little secondary waste while producing usable acid and base streams. The fundamentals of electrodialysis are presented in this report to provide a foundation for interpreting experimental data. A flat-plate laboratory-scale apparatus was used to determine the feasibility of separating Na{sup +}/Cs{sup +} mixtures by electrodialysis. The results showed that Cs{sup +} is preferentially separated over Na{sup +} by a factor of 2 to 3 using a Nafion{reg_sign} 417 cationic membrane. The separation is relatively insensitive to solution ionic strength and flow-rate variations. The current efficiency of the separation ranges from 0.60 to 0.65 depending on the applied voltage. The laboratory-scale system was characterized by dimensional analysis, which demonstrated that the process could be scaled up to a size attractive for the volume of waste at the Hanford Site. Preliminary experiments on a bench-scale system were also conducted. The initial results showed that the current-voltage response of the laboratory- and the bench-scale unit is identical.

Buehler, M.F.; Lawrence, W.E.; Norton, J.D.

1993-12-01T23:59:59.000Z

446

Thermal Conductivity of LiF and NaF and the Ziman Limit  

Science Journals Connector (OSTI)

A model calculation of lattice thermal conductivity is presented and applied to measurements on LiF and NaF crystals of high purity. The treatment is in the spirit of a Callaway analysis, but at a somwhat more fundamental level: The Ziman variational principle for thermal conductivity derived from the phonon Boltzmann equation is used, with the phonon distribution function approximated by a displaced Planck part plus another term reducing the deviation from equilibrium for high-frequency phonons. An isotropic Debye approximation for the phonon spectra of LiF and NaF gives a good fit to the conductivity data, with only two semi-adjustable parameters (Grüneisen constant and a zone-edge longitudinal phonon frequency) for the anharmonic contribution. The most important feature of the calculation is the failure of the thermal conductivity to approach the Ziman limit of resistanceless phonon-phonon N processes. This is due to the important role played by high-frequency phonons in thermal conduction. Even for an infinite perfect crystal at arbitrarily low temperatures, the Ziman limit underestimates the conductivity by at least 50%. If this prediction is correct, it is not a peculiarity of LiF and NaF alone, and should be of importance for the theory of second-sound propagation in insulators.

David Benin

1972-03-15T23:59:59.000Z

447

Br-Cl-Na systematics in Illinois basin fluids: Constraints on fluid origin and evolution  

SciTech Connect

The authors present here bromide, chloride, and sodium data for fluids from reservoirs of Ordovician through Pennsylvania age in the Illinois basic which suggest that remnant marine fluids contribute significantly to fluid Cl budgets. Cl/Br and NaBr ratios for Ordovician through Devonian formation fluids are relatively uniform and near those for seawater, despite greater than a factor of ten range in Cl concentration. In contrast, fluids from Mississippian and Pennsylvanian reservoirs, separated from older reservoirs by the New Albany Shale Group, have more variable fluid Cl/Br and Na/Br ratios, most of which are significantly greater then those of seawater. The 1:1 stoichiometry of Cl and Na increases for Mississippian and Pennsylvanian formation fluids is consistent with halite dissolution. Nevertheless, Br systematics and mass-balance considerations indicate that he overall Cl budget of Illinois basin formation fluids appears to be more significantly influenced by the contribution from subaerially evaporated seawater than by halite dissolution.

Walter, L.M.; Huston, T.J. (Washington Univ., St. Louis, Missouri (USA)); Stueber, A.M. (Southern Illinois Univ., Edwardsville (USA))

1990-04-01T23:59:59.000Z

448

First principles calculations on Na and K-adsorbed diamond(100) surface  

SciTech Connect

Self-consistent, periodic, density functional theory calculations, using PW91 functional, have been performed to investigate Na and K adsorption on the C(100)(2?1) surface. Our calculations showed that Na and K adatoms preferred to occupy valley-bridge sites at the coverage (?) of 0.5ML. For the coverage of 1ML, the combination of pedestal site and valley-bridge site turned out to be energetically favored. These findings are found to be consistent with those obtained for alkali-metal adsorption on silicon and germanium surfaces. Two desorption peaks named ? and ? for K adsorption have been observed and assigned to pedestal or bridge site and valley-bridge sites experimentally, while our results showed that the ? and ? states should be ascribed to pedestal site and valley-bridge sites and the combination of bridge and valley-bridge site is not the local minima. Work function analysis showed that when Na and K are adsorbed on diamond surface, the work function will decrease linearly with increasing coverage, up to a minimum, and finally increase again because of the depolarization of the adsorbate, agreeing well with experiments.

Nie, JL; Xiao, H Y.; Zu, Xiaotao; Gao, Fei

2006-08-01T23:59:59.000Z

449

High-temperature corrosion of metallic alloys in an oxidizing atmosphere containing NaCl  

SciTech Connect

A particular heat-exchanger application involved metallic alloys exposed to flue gases of an aluminum remelt furnace. Because the flue gases might contain NaCl and other halides, the corrosion behavior of the alloys was to be investigated. Planned direct exposure of candidate alloys to the flue gases, however, was not conducted because of premature termination of the project. Complementary laboratory testing was conducted on seven commercially available alloys and two nickel aluminides. These materials were exposed to an oxidizing atmosphere containing 0.06 wt % NaCl for 1100 h at 1000/degree/C. Most of the alloy exhibited grain-boundary attack, which resulted in complete oxidation of enveloped grains. The alloys Incoloy MA-956, Incoloy 800, Inconel 625, Inconel 601, Hastelloy X, Haynes 188, and nickel aluminide IC-50 were substantially more corroded than Alloy 214 and nickel aluminide IC-221. The latter two alloys, therefore, would probably be superior to the others in application involving flue gases containing NaCl. Strength fabricability, and weldability, which are briefly discussed, would also affect selection of materials. 8 refs., 12 figs., 5 tabs.

Federer, J.I.

1989-02-01T23:59:59.000Z

450

Change Characteristics of Women boxers’ Na+,K+- ATPase, ROS and T-AOC before the Match  

Science Journals Connector (OSTI)

The author tests 24 women boxers’ Na+, K+- ATPase, ROS and T-AOC before the match. The results show that women boxers’ Na+, K+- ATPase, ROS and T-AOC (P<0.01) have a rising trend compared with control group; serum CK-NAC and LDH-L are high control group obviously (P<0.05, P<0.01). Explanation: women boxers’ Na+, K+-ATPase activity in RBC Membrane keeps high level, which has a positive role for the athletes to keep a high athletics ability.

Hua Ding; Bin Zhao

2012-01-01T23:59:59.000Z

451

Na2FeP2O7: A Safe Cathode for Rechargeable Sodium-ion Batteries  

Science Journals Connector (OSTI)

For galvanostatic charge–discharge measurements, the working electrode was formulated by mixing 80 wt % active material Na2FeP2O7, 15 wt % acetylene carbon black, and 5 wt % of polyvinylidene fluoride (PVdF) binder in a minimal amount of NMP (N-methylpyrrolidone) solvent. ... It enables the Na2FeP2O7 cathode reversible 1-electron Na (de)insertion capacity approaching 90 mAh/g involving an Fe3+/Fe2+ redox activity centered at 3.0 V (Figure 1b). ... The reversible specific capacities for the cathode and anode active materials were detd. ...

Prabeer Barpanda; Guandong Liu; Chris D. Ling; Mao Tamaru; Maxim Avdeev; Sai-Cheong Chung; Yuki Yamada; Atsuo Yamada

2013-08-15T23:59:59.000Z

452

Infrared experimental proof of the orientation of CH4 adsorbed in NaA zeolite by means of the degeneracy splitting of the 03BD3 band,  

E-Print Network (OSTI)

L-255 Infrared experimental proof of the orientation of CH4 adsorbed in NaA zeolite by means (C3v) en face d'un cation Na+. Abstract 2014 The infrared spectrum ofmethane adsorbed in NaA zeolite lattice and connected by windows of 4 A diameter [1]. The methane molecule adsorbed in these cavities

Paris-Sud XI, Université de

453

computational infrastructure for nuclear astrophysics Michael Smith, Physics Division, Oak Ridge Na:onal Lab coordinator@nucastrodata.org  

E-Print Network (OSTI)

computational infrastructure for nuclear astrophysics Michael Smith, Physics Division, Oak Ridge Na:onal Lab coordinator@nucastrodata.org #12;computational infrastructure for nuclear astrophysics system overview ·work with nuclear information, reaction rates, & simulations ·operates "in

454

Primeira-Dama Tropical: A cidade e o corpo feminino na ficção de Júlia Lopes de Almeida  

E-Print Network (OSTI)

de fornalha na atmosphera. a rua de S. cheirava a café crú.coisas, querendo aspecto dessa rua de então, havia largosmoral vigente, definir a rua universo masculino é enfatizar

Eisenhart, Vanina

2006-01-01T23:59:59.000Z

455

MembFac -Scoring Sheet 1. 12% MPD, 0.1 M Na Acetate pH 4.6, 0.1 M Sodium Chloride  

E-Print Network (OSTI)

Phosphate, 0.1 M Na Acetate pH 4.6, 0.1 M Lithium Sulfate 10. 12% PEG 6000, 0.1 M Na Acetate pH 4.6, 0.1 MMembFac - Scoring Sheet 1. 12% MPD, 0.1 M Na Acetate pH 4.6, 0.1 M Sodium Chloride 2. 12% PEG 4000, 0.1 M Na Acetate pH 4.6, 0.1 M Zinc Acetate 3. 10% PEG 4000, 0.1 M Na Acetate pH 4.6, 0.2 M Ammonium

Hill, Chris

456

Johillerit, Na(Mg, Zn)3 Cu(AsO4)3, ein neues Mineral aus Tsumeb, Namibia  

Science Journals Connector (OSTI)

Electron microprobe analysis of the new mineral johillerite gave Na2O 5.4, MgO 18.3, ZnO 5.4, CuO 15.8, and As2O5 55.8, total 100.7%. From this result, the ideal formula is given as Na(Mg, Zn)3 Cu(AsO4)3. Johille...

Prof. Dr. P. Keller; Prof. Dr. H. Hess…

1982-01-01T23:59:59.000Z

457

Investigation of the ion exchange equilibrium between NA+, Ca++, Mg++, and a sulfonated polystyrene resin at various concentrations  

E-Print Network (OSTI)

INVESTIGATiON OF THE ION EXCHANGE EQUILIBRIUM BETWEEN Na , Ca++, Mg++, AND A SULFONATED POLYSTYRENE RESIN AT VARIOUS CONCENTRATIONS A THESIS BY WILLIAM FRANKLIN McILHENNY Submitted to the Graduate School of the Agricultural and Mechanical... College of Texas in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE January 1958 MaJor Subject: Chemical Engineering INVESTIGATION OF THE ION EXCHANGE EQUILIBRIUM BFTWEEN Na+, Ca++ Mg++ AND A SULFONATED POLYSTYRENE RESIN...

McIlhenny, William Franklin

1958-01-01T23:59:59.000Z

458

Aluminium alloy based hydrogen storage tank operated with sodium aluminium hexahydride Na3AlH6  

Science Journals Connector (OSTI)

Abstract Here we present the development of an aluminium alloy based hydrogen storage tank, charged with Ti-doped sodium aluminium hexahydride Na3AlH6. This hydride has a theoretical hydrogen storage capacity of 3 mass-% and can be operated at lower pressure compared to sodium alanate NaAlH4. The tank was made of aluminium alloy EN AW 6082 T6. The heat transfer was realised through an oil flow in a bayonet heat exchanger, manufactured by extrusion moulding from aluminium alloy EN AW 6060 T6. Na3AlH6 is prepared from 4 mol-% TiCl3 doped sodium aluminium tetrahydride NaAlH4 by addition of two moles of sodium hydride NaH in ball milling process. The hydrogen storage tank was filled with 213 g of doped Na3AlH6 in dehydrogenated state. Maximum of 3.6 g (1.7 mass-% of the hydride mass) of hydrogen was released from the hydride at approximately 450 K and the same hydrogen mass was consumed at 2.5 MPa hydrogenation pressure. 45 cycle tests (rehydrogenation and dehydrogenation) were carried out without any failure of the tank or its components. Operation of the tank under real conditions indicated the possibility for applications with stationary HT-PEM fuel cell systems.

R. Urbanczyk; K. Peinecke; M. Felderhoff; K. Hauschild; W. Kersten; S. Peil; D. Bathen

2014-01-01T23:59:59.000Z

459

Dispersion relations of surface phonons in LiF(001) and NaF(001)  

Science Journals Connector (OSTI)

Recent atom-scattering experimental data have stimulated a new investigation on the surface phonons of some alkali halides. In the framework of Green's-function method applied to breathing-shell model dynamics we have calculated the dispersion curves and a few K-selected densities of states of surface phonons for the (001) surface of NaF and LiF at room temperature. Particular attention is paid to the change in ion polarizabilities occurring at the surface and its effect on the Rayleigh wave frequencies at the zone boundary.

G. Benedek; G. P. Brivio; L. Miglio; V. R. Velasco

1982-07-15T23:59:59.000Z

460

Publisher's note: Branching ratios for the beta decay of Na-21 (vol 74, pg 015501, 2006)  

E-Print Network (OSTI)

, Y. Zhai, and I. S. Towner (Received 31 July 2006; published 11 August 2006) DOI: 10.1103/PhysRevC.74.029901 PACS number(s): 27.30.+t, 23.40.?s, 99.10.Fg This paper was published online on 14 July 2006 with formatting errors in Eqs. (7) and (9...PHYSICAL REVIEW C 74, 029901(E) (2006) Publisher?s Note: Branching ratios for the ? decay of 21Na [Phys. Rev. C 74, 015501 (2006)] V. E. Iacob, J. C. Hardy, C. A. Gagliardi, J. Goodwin, N. Nica, H. I. Park, G. Tabacaru, L. Trache, R. E. Tribble...

Iacob, V. E.; Hardy, John C.; Gagliardi, Carl A.; Goodwin, J.; Nica, N.; Park, H. I.; Tabacaru, G.; Trache, L.; Tribble, Robert E.; Zhai, Y.; Towner, I. S.

2006-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "butyl ether na" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Carrier Density Enhancement in Semiconducting NaSn and CsPb  

Science Journals Connector (OSTI)

The electrical conductivity ? and thermoelectric power S data have been measured in two semiconductors that undergo a solid-state transformation to a dynamically disordered phase about 100 °C below the melting point. At the transition, ? for NaSn is reduced while that for CsPb exhibits a dramatic rise. For both semiconductors, S is reduced in magnitude and changes sign at the transition. These results are consistent with a model which explicitly allows for the interactions between mobile ions and electrons and which provides a unified explanation of the transport properties of these compounds and other fast ion conductors with appreciable electronic conductivity.

J. Fortner, Marie-Louise Saboungi, and J. E. Enderby

1995-02-20T23:59:59.000Z

462

Thermonuclear reaction rate of $^{18}$Ne($?$,$p$)$^{21}$Na from Monte-Carlo calculations  

E-Print Network (OSTI)

The $^{18}$Ne($\\alpha$,$p$)$^{21}$Na reaction impacts the break-out from the hot CNO-cycles to the $rp$-process in type I X-ray bursts. We present a revised thermonuclear reaction rate, which is based on the latest experimental data. The new rate is derived from Monte-Carlo calculations, taking into account the uncertainties of all nuclear physics input quantities. In addition, we present the reaction rate uncertainty and probability density versus temperature. Our results are also consistent with estimates obtained using different indirect approaches.

P. Mohr; R. Longland; C. Iliadis

2014-12-09T23:59:59.000Z

463

Deliquescence of NaBH4 from Density Functional Theory and Experiments  

Science Journals Connector (OSTI)

Ping Li †, Lin Yu ‡, Michael A. Matthews ‡, Wissam A. Saidi †, and J. Karl Johnson *†§ ... We have used the DFT-TS approach as implemented within VASP by Al-Saidi et al.(43, 44) We have computed adsorption energies and geometries for several H2O/NaBH4(100) configurations using each of these functionals. ... Al-Saidi, W. A.; Voora, V. K.; Jordan, K. D.An Assessment of the vdW-TS Method for Extended Systems J. Chem. ...

Ping Li; Lin Yu; Michael A. Matthews; Wissam A. Saidi; J. Karl Johnson

2013-09-10T23:59:59.000Z

464

Thermonuclear reaction rate of $^{18}$Ne($?$,$p$)$^{21}$Na from Monte-Carlo calculations  

E-Print Network (OSTI)

The $^{18}$Ne($\\alpha$,$p$)$^{21}$Na reaction impacts the break-out from the hot CNO-cycles to the $rp$-process in type I X-ray bursts. We present a revised thermonuclear reaction rate, which is based on the latest experimental data. The new rate is derived from Monte-Carlo calculations, taking into account the uncertainties of all nuclear physics input quantities. In addition, we present the reaction rate uncertainty and probability density versus temperature. Our results are also consistent with estimates obtained using different indirect approaches.

P. Mohr; R. Longland; C. Iliadis

2014-12-14T23:59:59.000Z

465

Thermonuclear reaction rate of $^{18}$Ne($\\alpha$,$p$)$^{21}$Na from Monte-Carlo calculations  

E-Print Network (OSTI)

The $^{18}$Ne($\\alpha$,$p$)$^{21}$Na reaction impacts the break-out from the hot CNO-cycles to the $rp$-process in type I X-ray bursts. We present a revised thermonuclear reaction rate, which is based on the latest experimental data. The new rate is derived from Monte-Carlo calculations, taking into account the uncertainties of all nuclear physics input quantities. In addition, we present the reaction rate uncertainty and probability density versus temperature. Our results are also consistent with estimates obtained using different indirect approaches.

Mohr, P; Iliadis, C

2014-01-01T23:59:59.000Z

466

Sorption of vapours and liquids in PDMS: novel data and analysis with the GAB model of multilayer adsorption  

Science Journals Connector (OSTI)

Abstract Novel data on the sorption of vapours and liquids in cross-linked poly(dimethylsiloxane) (PDMS) elastomer at 25–40 °C are reported together with the accurate and original way of parameterising the sorption isotherms by using the GAB (Guggenheim, Anderson and De Boer) model of multilayer adsorption. The GAB model has been found to provide a comparable or better representation of sorption isotherms than the Flory–Huggins model with a concentration-dependent interaction parameter and better than the ENSIC (Engaged Species Induced Clustering) model. This comparison holds true for poor solvents of PDMS (water, methanol), mild solvents (acetone, methyl acetate, dimethyl carbonate) and good solvents (tert-butyl methyl ether, tert-amyl methyl ether, cyclopentyl methyl ether). The GAB model provided a noticeably good assessment of the sorption of liquids and highly saturated vapours, which makes the model applicable within the entire activity range.

Ond?ej Vopi?ka; Alena Randová; Karel Friess

2014-01-01T23:59:59.000Z

467

Thermodynamic modeling of neptunium(V)-acetate complexation in concentrated NaCl media  

SciTech Connect

The complexation of neptunium(V), Np(V), with the acetate anion, Ac{sup -}, was measured in sodium chloride media to high concentration using an extraction technique. The data were interpreted using the thermodynamic formalism of Pitzer, which is valid to high electrolyte concentrations. A consistent model for the deprotonation constants of acetic acid in NaCl and NaClO{sub 4} media was developed. For the concentrations of acetate expected in a waste repository, only the neutral complex NpO{sub 2}Ac(aq) was important in describing the interactions between the neptunyl ion and acetate. The thermodynamic stability constant log {beta}{sup 0}{sub 101} for the reaction NpO{sub 2}{sup +} + Ac{sup -} {leftrightarrow} NpO{sub 2}Ac was calculated to be 1.46{plus_minus}0.11. This weak complexing behavior between the neptunyl ion and acetate indicates that acetate will not significantly enhance dissolved Np(V) concentrations in ground waters associated with nuclear waste repositories that may contain acetate.

Novak, C.F.; Borkowski, M.; Choppin, G.R.

1995-09-01T23:59:59.000Z

468

Electronic Reconstruction through the Structural and Magnetic Transitions in Detwinned NaFeAs  

SciTech Connect

We use angle-resolved photoemission spectroscopy to study twinned and detwinned iron pnictide compound NaFeAs. Distinct signatures of electronic reconstruction are observed to occur at the structural (T{sub S}) and magnetic (T{sub SDW}) transitions. At T{sub S}, C{sub 4} rotational symmetry is broken in the form of an anisotropic shift of the orthogonal d{sub xz} and d{sub yz} bands. The magnitude of this orbital anisotropy rapidly develops to near completion upon approaching T{sub SDW}, at which temperature band folding occurs via the antiferromagnetic ordering wave vector. Interestingly, the anisotropic band shift onsetting at T{sub S} develops in such a way to enhance the nesting conditions in the C{sub 2} symmetric state, hence is intimately correlated with the long range collinear AFM order. Furthermore, the similar behaviors of the electronic reconstruction in NaFeAs and Ba(Fe{sub 1-x}Co{sub x}){sub 2}As{sub 2} suggests that this rapid development of large orbital anisotropy between T{sub S} and T{sub SDW} is likely a general feature of the electronic nematic phase in the iron pnictides, and the associated orbital fluctuations may play an important role in determining the ground state properties.

Yi, M.; Lu, D.H.; Moore, R.G.; Kihou, K; Lee, C-H; Iyo, A.; Eisaki, H.; Yoshida, T; Fujimori, A; Shen, Z-X

2012-05-25T23:59:59.000Z

469

Synthesis and characterization of the layered iron-selenide Na0.8Fe1.6Se2  

Science Journals Connector (OSTI)

An iron-selenide Na0.8Fe1.6Se2 single crystal has been successfully synthesized using a self-flux method. The electrical resistivity measurement shows that this material exhibits semiconducting behavior in the whole temperature range, with an anomalous increment of resistivity at Ts?595 K. By varying the concentrations of Na and Fe, a small volume of superconducting phase could be achieved with a critical temperature of Tc?34 K. Structural characterization shows that, similarly to K0.8Fe1.6Se2, the Na0.8Fe1.6Se2 phase exhibits clear superstructure with a modulation wave vector of q=(3/5,1/5,0) caused by the Fe-vacancy order within the a-b plane.

Y. J. Long; D. M. Wang; Z. Wang; H. X. Yang; J. B. He; L. X. Zhao; P. P. Wang; M. Q. Xue; J. Q. Li; Z. A. Ren; G. F. Chen

2014-10-30T23:59:59.000Z

470

Investigation of SiO{sub 2}:Na{sub 2}O ratio as a corrosion inhibitor for metal alloys  

SciTech Connect

The silicate is one of the potential compounds used as a corrosion inhibitor for metal alloys. The mixture between silica and sodium hydroxide (NaOH) succeeded to produce the silicate product. The formulation of a silicate product normally variable depended by the different ratio of SiO{sub 2}:Na{sub 2}O. This research utilized the agriculture waste product of paddy using its rice husk. In this study, the amorphous silica content in rice husk ash was used after rice husk burnt in a muffle furnace at a certain temperature. The X-ray diffraction (XRD) analysis was done to determine the existence of amorphous phase of silica in the rice husk ash. There are several studies that recognized rice husk as an alternative source that obtained high silica content. The X-ray fluorescence (XRF) analysis was carried out to clarify the percentage amount of Si and O elements, which referred the silica compound in rice husk ash. The preparation of sodium silicate formulation were differ based on the SiO{sub 2}:Na{sub 2}O ratio (SiO{sub 2}:Na{sub 2}O ratio = 1.00, 2.00 and 3.00). These silicate based corrosion inhibitors were tested on several testing samples, which were copper (99.9%), aluminum alloy (AA 6061) and carbon steel (SAE 1045). The purpose of this study is to determine the appropriate SiO{sub 2}:Na{sub 2}O ratio and understand how this SiO{sub 2}:Na{sub 2}O ratio can affect the corrosion rate of each metal alloys immersed in acidic medium. In order to investigate this study, weight loss test was conducted in 0.5 M hydrochloric acid (HCl) for 24 hours at room temperature.

Mohamad, N.; Othman, N. K. [School of Applied Physics, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor Darul Ehsan (Malaysia); Jalar, A. [Institute of Micro Engineering and Nanoelectronics (IMEN), Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor Darul Ehsan (Malaysia)

2013-11-27T23:59:59.000Z

471

Liquefied Dimethyl Ether: An Energy-Saving, Green Extraction Solvent  

Science Journals Connector (OSTI)

Extraction is an essential procedure in the fields of food, pharmacy, and renewable bio-fuels, and it affords the recovery of desired components and the removal of undesired components from the natural feedstock....

Peng Li; Hisao Makino

2014-01-01T23:59:59.000Z

472

Alternative Fuels lDimethyl Ether Rheology and Materials Studies  

Energy.gov (U.S. Department of Energy (DOE))

2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: The Pennsylvania State University

473

Alternative Fuels Data Center: Dimethyl Ether (DME): Fuel of...  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

The AFDC is a resource of the U.S. Department of Energy's Clean Cities program. Contacts | Web Site Policies | U.S. Department of Energy | USA.gov Content Last Updated: 01022015...

474

Alternative Fuels Data Center: Dimethyl Ether (DME) as a Transportatio...  

Alternative Fuels and Advanced Vehicles Data Center (EERE)

similar to that of propane, in that both are required to be kept in pressurized storage tanks at ambient temperature. DME has several fuel properties that make it attractive for...

475

Surface Modification of Silicone Elastomer Using Perfluorinated Ether  

E-Print Network (OSTI)

of a silicone-coated substrate.29 In addition, higher molecular weight perfluoropolyethers have been included

Chaudhury, Manoj K.

476

Polybrominated Diphenyl Ether Flame Retardants in Virginia Freshwater Fishes (USA)  

Science Journals Connector (OSTI)

Robert C. Hale ,* Mark J. La Guardia , Ellen P. Harvey , T. Matteson Mainor , William H. Duff , and Michael O. Gaylor ... Following solvent exchange to hexane, the halogenated compounds in the purified extracts were separated on a gas chromatograph (GC; Varian 3400, Sugar Land, TX), equipped with a 60-m DB-5 column (J&W Scientific, Folsom, CA; 0.25 ?m film, 0.32 i.d.). ...

Robert C. Hale; Mark J. La Guardia; Ellen P. Harvey; T. Matteson Mainor; William H. Duff; Michael O. Gaylor

2001-10-30T23:59:59.000Z

477

The Ether Extract and the Chloroform Extract of Soils.  

E-Print Network (OSTI)

KNJJUG................................................................................................................Mailing Clerk STATE AGRICULTURAL EXPERIMENT STATIONS. H U M T 9 L 3L H G U . 9 Z R 11 3J X C I T P P T L I 0 Y uUM T 9 L U 9 0. B. A U P s S 3 D D ...................................................... Austin t 3 T S D T L . L D 1u U M T 9 L U 9 i 3 P P... n R r . 0 T J ......................................................Brownwood A U O O 3J J 3U L T 9 U o V H 9 3 I S P D S 9 T X Z w R dU L T ...................................................... Austin DIRECTOR OF EXPERIMENT STATIONS. B. l U...

Fraps, G. S.; Rather, J. B.

1913-01-01T23:59:59.000Z

478

Quantum-Gravity Phenomenology and the DSR Ether Theories  

E-Print Network (OSTI)

Guided primarily by versions of a theoretical framework called Doubly Special Relativity, or DSR, that are supposed to entail speeds of light that vary with energy while preserving the relativity of inertial frames, quantum-gravity phenomenologists have recently been seeking clues to quantum gravity, in hoped-for differing times of arrival, for light of differing energies, from cosmologically distant sources. However, it has long been known that signals, of arbitrarily high speed in opposing directions, could be used to observe the translational state of (absolute) rest, as could signals of a fixed speed different from c. Consequently, the above versions of DSR are nonviable.

Kenneth M. Sasaki

2010-09-20T23:59:59.000Z

479

Synthesis of Methanol and Dimethyl Ether from Syngas over Pd...  

NLE Websites -- All DOE Office Websites (Extended Search)

are necessary when combining methanol and DME synthesis with a methanol to gasoline (MTG) process in a single reactor bed. A commercial CuZnOAl2O3 catalyst, utilized...

480

Extractant composition including crown ether and calixarene extractants  

DOE Patents (OSTI)

An extractant composition comprising a mixed extractant solvent consisting of calix[4] arene-bis-(tert-octylbenzo)-crown-6 ("BOBCalixC6"), 4',4',(5')-di-(t-butyldicyclo-hexano)-18-crown-6 ("DtBu18C6"), and at least one modifier dissolved in a diluent. The DtBu18C6 may be present at from approximately 0.01M to approximately 0.4M, such as at from approximately 0.086 M to approximately 0.108 M. The modifier may be 1-(2,2,3,3-tetrafluoropropoxy)-3-(4-sec-butylphenoxy)-2-propanol ("Cs-7SB") and may be present at from approximately 0.01M to approximately 0.8M. In one embodiment, the mixed extractant solvent includes approximately 0.15M DtBu18C6, approximately 0.007M BOBCalixC6, and approximately 0.75M Cs-7SB modifier dissolved in an isoparaffinic hydrocarbon diluent. The extractant composition further comprises an aqueous phase. The mixed extractant solvent may be used to remove cesium and strontium from the aqueous phase.

Meikrantz, David H. (Idaho Falls, ID); Todd, Terry A. (Aberdeen, ID); Riddle, Catherine L. (Idaho Falls, ID); Law, Jack D. (Pocalello, ID); Peterman, Dean R. (Idaho Falls, ID); Mincher, Bruce J. (Idaho Falls, ID); McGrath, Christopher A. (Blackfoot, ID); Baker, John D. (Blackfoot, ID)

2009-04-28T23:59:59.000Z

Note: This page contains sample records for the topic "butyl ether na" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Polybrominated Diphenyl Ethers in the Sediments of the Great Lakes.  

E-Print Network (OSTI)

source of many pollutants, including PCBs and dioxins, to the Great Lakes. This has been particularly analysis demonstrated that the pattern of PBDEs in Lake Superior sediments differs from those in air from the point sources. Sediments are an important sink and reservoir of per- sistent pollutants

Rockne, Karl J.

482

Network Structure of Cellulose Ethers Used in Pharmaceutical Applications  

E-Print Network (OSTI)

, have studied these two processes (1,3­6). Significant models have been proposed by Peppas molecules dissolve in water and are released by diffusion. The processes of swelling, ero- sion, and drug mathematical models that include all interrelated parameters and that fit accurately the experimental results

Peppas, Nicholas A.

483

Comparação da eficácia antimicrobiana de sabonetes contendo óleo essencial de Tea Tree (Melaleuca alternifolia) e triclosan na higienização de mãos artificialmente contaminadas.  

E-Print Network (OSTI)

??Introdução. Os efeitos antimicrobianos dos óleos essenciais têm sido relatados na literatura científica, sobretudo referentes ao óleo essencial de Tea Tree (Melaleuca alternifolia). Tal óleo… (more)

Juliana Rizzo Gnatta

2012-01-01T23:59:59.000Z

484

An experimental investigation of the solubility and complexing of nickel in the system NiO-HCl-H?O-NaCl  

E-Print Network (OSTI)

AN EXPERIMENTAL INVESTIGATION OF THE SOLUBILITY AND COMPLEXING OF NICKEL IN THE SYSTEM NiO-HC1-H20-NaC1 A Thesis by LYNNE SHIRLEY FAHLQUIST Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirements... of Nickel in the System NiO-HC1-H20-NaCI Lynne Shirley Fahlquist, B. S. , Texas AdtM University Chairman of Advisory Committee: Dr, Robert K. Popp The solubility of NiO was determined in both NaCl-free and NaC1-bearing systems in the range 550-750'C, 2...

Fahlquist, Lynne Shirley

2012-06-07T23:59:59.000Z

485

O corpo na transversal do tempo: da sociedade disciplinar à sociedade de controle ou da analítica de "um corpo que cai.  

E-Print Network (OSTI)

??No fluxo de acontecimentos que revolveram as certezas e regimes de verdade nas últimas décadas, a tese O Corpo na Transversal do Tempo: da sociedade… (more)

Edivaldo Vieira da Silva

2006-01-01T23:59:59.000Z

486

Effects of NaCl, sucrose, and storage on rheological parameters of heat induced gels of liquid egg products  

E-Print Network (OSTI)

EFFECTS OF NaCl, SUCROSE, AND STORAGE ON RHEOLOGICAL PARAMETERS OF HEAT INDUCED GELS OF LIQUID EGG PRODUCTS A Thesis by Joan Brough Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements... and content by: C. W. Dill (Chair of Committee) F. A. Gardner (Member) R. L. Edwards (Member) G. C. Smith (Head of Department) December 1988 ABSTRACT Effects of NaC1, Sucrose, and Storage on Rheological Parameters of Heat Induced Gels of Liquid Egg...

Brough, Joan

1988-01-01T23:59:59.000Z

487

2011 Annual Workforce Analysis and Staffing Plan Report - NNSA HQ NA-70  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Annual Workforce Analysis and Staffing Plan Report Annual Workforce Analysis and Staffing Plan Report As of December 31, 2011 Reporting Office: NNSA NA-70 Section One: Current Mission(s) of the Organization and Potential Changes 1. DNS is the NNSA line management organization responsible for security direction and program management with respect to prioritization of resources, program evaluation, and funding allocation. Key management areas include security operations, resources, engineering, and technical support to NNSA field elements and facilities. Specific subject matter expertise also includes physical and personnel security, protective forces, nuclear materials control and accountability, classified and sensitive information protection, and technical security programs. DNS evaluates the status of protection programs at all NNSA facilities against National policy and

488

High Density Hydrogen Storage Systems Demonstration Using NaAIH4  

NLE Websites -- All DOE Office Websites (Extended Search)

Density Hydrogen Storage Density Hydrogen Storage System Demonstration Using NaAlH 4 Complex Compound Hydrides D. Mosher, X. Tang, S. Arsenault, B. Laube, M. Cao, R. Brown, S. Saitta, J. Costello United Technologies Research Center East Hartford, Connecticut Report to the U.S. Department of Energy (DOE) Contract Number: DE-FC36-02AL-67610 December 19, 2006 * * Presented to the DOE and the FreedomCAR & Fuel Partnership Hydrogen Storage Tech Team This presentation does not contain proprietary or confidential information 2 Overview Objective: Identify and overcome the critical technical barriers in developing complex hydride based storage systems, especially those which differ from conventional metal hydride systems, to meet DOE system targets. Approach: Design, fabricate and test a sequence of subscale and full scale

489

2012 Annual Workforce Analysis and Staffing Plan Report - NNSA NA-70  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

7 7 Annual Workforce Analysis and Staffing Plan Report As of December 31, 2012 Reporting Office: NNSA NA-70 Section One: Current Mission(s) of the Organization and Potential Changes The DNS core mission is to protect NNSA capabilities, facilities, materials, information, and employees. DNS is responsible for managing and funding the security that supports the NNSA missions, with the exception of those missions under the Office of Naval Reactors and the Office of Secure Transportation's (OST) over-the-road operations. DNS also provides unique knowledge and expertise in nuclear security for a broader set of 21st century national security needs that are synergistic with its mission, such as those in nuclear non-proliferation, homeland security, and intelligence. DNS provides the overall

490

Multiple high-temperature transitions driven by dynamical structures in NaI  

SciTech Connect

Multiple, consecutive high-temperature transitions in NaI involving dynamical order and/or localization in the energy-momentum spectrum but not in the average crystal structure are revealed by lattice dynamics, x-ray lattice spacing, and heat capacity measurements. Distinctive energy-momentum patterns and lattice distortions indicate dynamical structures forming within randomly stacked planes, rather than the isolated point-defect-like intrinsic localized modes predicted. Transition entropies are accounted for by vibrational entropy changes and the transition enthalpies are explained by the strain energy of forming stacking-fault-like planar distortions deduced from x-ray diffraction peak shifts. The vibrational entropy of the dynamical structures stabilizes surrounding elastic distortions.

Manley, Michael E [ORNL; Jeffries, Jason R [ORNL; Lee, Hohyun [Santa Clara University, California; Zabalegui, Aitor [Santa Clara University, California; Abernathy, Douglas L [ORNL

2014-01-01T23:59:59.000Z

491

Evidence for threshold effects in positron diffraction from NaF and LiF  

Science Journals Connector (OSTI)

We have measured the energy dependence of the intensity of a positron beam specularly reflected from the (100) surfaces of NaF and LiF. A 1-eV-wide peak located at an energy that decreases with increasing angle of incidence ? is qualitatively identified as a beam threshold effect. Given the known small positron affinity for the solids, the narrowness of the peak is consistent with its being due to a true surface resonance. However, the dispersion appears to depart from the expected energy versus ? trajectory parallel to the kinematic threshold. Additionally, a search in 50-meV steps did not reveal any fine structure in the peaks, possibly due to our 0.3-eV effective instrumental resolution. Further experiments to map the dispersion with greater precision, to measure the binding energies of the resonances, and to search for possible fine structure are proposed.

T. N. Horsky; G. R. Brandes; K. F. Canter; P. H. Lippel; A. P. Mills; Jr.

1989-10-15T23:59:59.000Z

492

Los Alamos National Security, LLC Contract No. DE-AC52-06NA25396  

National Nuclear Security Administration (NNSA)

Los Alamos National Security, LLC Los Alamos National Security, LLC Contract No. DE-AC52-06NA25396 Attachment to Modification No. 150 PART III - SECTION J APPENDIX G October 5, 2010 [Modified by Modification No. A009, A015, A018, A019, A021, A027, M033, M041, M042, M046, M056, M062, M069, M078, M103, M133, 150] LIST OF APPLICABLE DIRECTIVES In addition to the list of applicable directives listed below, the Contractor shall also comply with supplementary directives, (e.g., manuals) which are invoked by a Contractor Requirements Document (CRD) attached to a directive. Electronic copies of these documents are available at the following Websites: http://directives.doe.gov/cqi-bin/currentchecklist http://www.directives,doe.gov/directives/globesearch-adv.html http://www.nnsa.doe.gov/

493

Total reflection infrared spectroscopy of water-ice and frozen aqueous NaCl solutions  

SciTech Connect

Liquid-like and liquid water at and near the surface of water-ice and frozen aqueous sodium chloride films were observed using attenuated total reflection infrared spectroscopy (ATR-IR). The concentration of NaCl ranged from 0.0001 to 0.01 M and the temperature varied from the melting point of water down to 256 K. The amount of liquid brine at the interface of the frozen films with the germanium ATR crystal increased with salt concentration and temperature. Experimental spectra are compared to reflection spectra calculated for a simplified morphology of a uniform liquid layer between the germanium crystal and the frozen film. This morphology allows for the amount of liquid observed in an experimental spectrum to be converted to the thickness of a homogenous layer with an equivalent amount of liquid. These equivalent thickness ranges from a nanometer for water-ice at 260 K to 170 nm for 0.01 M NaCl close to the melting point. The amounts of brine observed are over an order of magnitude less than the total liquid predicted by equilibrium thermodynamic models, implying that the vast majority of the liquid fraction of frozen solutions may be found in internal inclusions, grain boundaries, and the like. Thus, the amount of liquid and the solutes dissolved in them that are available to react with atmospheric gases on the surfaces of snow and ice are not well described by thermodynamic equilibrium models which assume the liquid phase is located entirely at the surface.

Walker, Rachel L.; Searles, Keith; Willard, Jesse A.; Michelsen, Rebecca R. H., E-mail: RMichelsen@rmc.edu [Department of Chemistry, Randolph-Macon College, P.O. Box 5005, Ashland, Virginia 23005 (United States)] [Department of Chemistry, Randolph-Macon College, P.O. Box 5005, Ashland, Virginia 23005 (United States)

2013-12-28T23:59:59.000Z

494

Microstructural and compositional change of NaOH-activated high calcium fly ash by incorporating Na-aluminate and co-existence of geopolymeric gel and C-S-H(I)  

SciTech Connect

This study explores the reaction products of alkali-activated Class C fly ash-based aluminosilicate samples by means of high-resolution synchrotron X-ray diffraction (HSXRD), scanning electron microscope (SEM), and compressive strength tests to investigate how the readily available aluminum affects the reaction. Class C fly ash-based aluminosilicate raw materials were prepared by incorporating Na-aluminate into the original fly ashes, then alkali-activated by 10 M NaOH solution. Incorporating Na-aluminate reduced the compressive strength of samples, with the reduction magnitude relatively constant regardless of length of curing period. The HSXRD provides evidence of the co-existence of C-S-H with geopolymeric gels and strongly suggests that the C-S-H formed in the current system is C-S-H(I). The back-scattered electron images suggest that the C-S-H(I) phase exists as small grains in a finely intermixed form with geopolymeric gels. Despite providing extra source of aluminum, adding Na-aluminate to the mixes did not decrease the Si/Al ratio of the geopolymeric gel.

Oh, Jae Eun [Department of Civil and Environmental Engineering, University of California, Berkeley, CA 94720 (United States); School of Urban and Environmental Engineering, Ulsan National Institute of Science and Technology, Ulsan Metropolitan City, 689-798 (Korea, Republic of); Moon, Juhyuk [Department of Civil and Environmental Engineering, University of California, Berkeley, CA 94720 (United States); Oh, Sang-Gyun [Department of Architectural Engineering, Dong-Eui University, 995 Eomgwangro, Busanjin-Gu, Busan 614-714 (Korea, Republic of); Clark, Simon M. [Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, CA 20015 (United States); Department of Earth and Planetary Sciences, Macquarie University, Sydney, NSW 2109 (Australia); Monteiro, Paulo J.M., E-mail: monteiro@berkeley.edu [Department of Civil and Environmental Engineering, University of California, Berkeley, CA 94720 (United States)

2012-05-15T23:59:59.000Z

495

X-ray and electron diffraction studies of superlattices and long-range three-dimensional Na ordering in gamma-Na[subscript x]CoO[subscript 2] (x=0.71 and 0.84)  

E-Print Network (OSTI)

We have recently demonstrated that x=0.71 and 0.84 are the two most stable single-phase compounds above x=0.5 in gamma-Na[subscript x]CoO[subscript 2] [G. J. Shu et al., Phys. Rev. B 76, 184115 (2007); F. C. Chou et al., ...

Chou, F. C.

496

European-Scale Modeling of Concentrations and Distribution of Polybrominated Diphenyl Ethers in the Pentabromodiphenyl Ether Product  

Science Journals Connector (OSTI)

Department of Environmental Science, Institute of Environmental and Natural Sciences, Lancaster University, Lancaster LA1 4 YQ, United Kingdom ... Limited survey data in the Mediterranean (Cyprus) were surprisingly high (20); it was assumed that the advection into Europe from the south was probably lower, but this assumption needs to be tested by future field data. ... VP-derived EFs should be suited to solid?gas-phase releases (13) and may therefore describe outgassing of the lighter components of PeBDE under ambient temperatures from solid matrixes where they have been used as additives. ...

K. Prevedouros; K. C. Jones; A. J. Sweetman

2004-10-09T23:59:59.000Z

497

arXiv:1011.0897v1[math.NA]3Nov2010 EFFICIENT NUMERICAL STABILITY ANALYSIS OF DETONATION  

E-Print Network (OSTI)

arXiv:1011.0897v1[math.NA]3Nov2010 EFFICIENT NUMERICAL STABILITY ANALYSIS OF DETONATION WAVES­Stewart and Short­Stewart, the numerical evaluation of linear stability of planar detonation waves problem. Planar detonation waves can often change stability as physical parameters are varied, undergoing

Humpherys, Jeffrey

498

Solar Energy Materials & Solar Cells 58 (1999) 199}208 The behaviour of Na implanted into Mo thin "lms  

E-Print Network (OSTI)

Solar Energy Materials & Solar Cells 58 (1999) 199}208 The behaviour of Na implanted into Mo thin, As ngstro( m Solar Center, P.O. Box 534, SE-751 21 Uppsala, Sweden Department of Materials Science Mo thin "lms used as back contacts for Cu(In,Ga)Se solar cells. The samples were analysed

Rockett, Angus

499

Surface Tensions in NaCl-Water-Air Systems from MD Simulations Ranjit Bahadur, Lynn M. Russell,*, and Saman Alavi  

E-Print Network (OSTI)

Surface Tensions in NaCl-Water-Air Systems from MD Simulations Ranjit Bahadur, Lynn M. Russell, Ottawa, Ontario K1A 0R6, Canada ReceiVed: July 9, 2007; In Final Form: July 30, 2007 Surface tensions to the surface tension, while the energy-integral and test area methods provide direct estimates. At 1 atm

Russell, Lynn

500

L'identit gomtrie variable des jeunes hommes Kali'na de Mana (Guyane franaise) : sur quelle mesure ?  

E-Print Network (OSTI)

disperse au Brésil, au Surinam, jusqu'au Guyana et au Venezuela (Ethnies 1985 :14). En 1958, la population, conséquence de la guerre civile du Surinam. Aujourd'hui, les Kali'na sont entre de 2800 et 4000 individus

Paris-Sud XI, Université de