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Note: This page contains sample records for the topic "butyl ether eu" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Control Study of Ethyl tert-Butyl Ether Reactive Distillation Muhammad A. Al-Arfaj  

E-Print Network [OSTI]

-butyl ether (ETBE) for gasoline blending as a replacement for methyl tert-butyl ether (MTBE) because and be blended with ETBE in the gasoline pool. Even for neat operation, if the conversion is low, the unconverted

Al-Arfaj, Muhammad A.

2

State Restrictions on Methyl Tertiary Butyl Ether (released in AEO2006)  

Reports and Publications (EIA)

By the end of 2005, 25 states had barred, or passed laws banning, any more than trace levels of methyl tertiary butyl ether (MTBE) in their gasoline supplies, and legislation to ban MTBE was pending in 4 others. Some state laws address only MTBE; others also address ethers such as ethyl tertiary butyl ether (ETBE) and tertiary amyl methyl ether (TAME). Annual Energy Outlook 2006 assumes that all state MTBE bans prohibit the use of all ethers for gasoline blending.

2006-01-01T23:59:59.000Z

3

Atmospheric chemistry of diethyl ether and ethyl tert-butyl ether  

SciTech Connect (OSTI)

The mechanisms for the Cl-initiated and OH-initiated atmospheric oxidation of diethyl ether and ethyl tert-butyl ether (ETBE) have been determined. For diethyl ether the products are ethyl formate and formaldehyde and its atmospheric oxidation can be represented by C{sub 2}H{sub 5}OC{sub 2}H{sub 5} + OH + 2NO {yields} C{sub 2}H{sub 5}OC(O)H + HCHO + 2NO{sub 2} + HO{sub 2}. The mechanism for the atmospheric oxidation of ETBE is more complex, with 80% of the reaction being accounted for in terms of tert-butyl formate and formaldehyde. The remaining 20% the authors ascribe to 2-ethoxy-2-methylpropanal. The atmospheric oxidation of ETBE can be represented by ETBE + OH + 1.8NO {yields} 0.8HCOOC(CH{sub 3}){sub 3} + 0.2C{sub 2}H{sub 5}OC(CH{sub 3}){sub 2}CHO + HO{sub 2} + 0.8HCHO + 1.8NO{sub 2}. THe subsequent atmospheric chemistry of 2-ethoxy-2-methylpropanal the authors estimate to be represented by C{sub 2}H{sub 5}OC(CH{sub 3}){sub 2}CHO + OH + 3NO {yields} CO{sub 2} + H{sub 2}CO + C{sub 2}H{sub 5}OC(O)CH{sub 3} + HO{sub 2} + 3NO{sub 2}. These results are discussed in terms of the reactivity of these compounds in urban atmospheres.

Wallington, T.J.; Japar, S.M. (Ford Motor Company, Dearborn, MI (USA))

1991-03-01T23:59:59.000Z

4

Separation of methyl t-butyl ether from close boiling C[sub 5] hydrocarbons by extractive distillation  

SciTech Connect (OSTI)

A method for recovering methyl t-butyl ether from a mixture of methyl t-butyl ether and 1-pentene which comprises distilling a mixture of methyl t-butyl ether and 1-pentene in the presence of about one part of an extractive agent per part of methyl t-butyl ether -- 1-pentene mixture, recovering the 1-pentene as overhead product and obtaining the methyl t-butyl ether and the extractive agent from the still pot, wherein said extractive agent consists of one material selected from the group consisting of sulfolane, nitroethane, t-butanol, ethylene glycol diacetate, 1-methoxy-2-propanol acetate, methyl isoamyl ketone, ethylene glycol methyl ether, propylene glycol phenyl ether and diethyl malonate.

Berg, L.

1993-07-20T23:59:59.000Z

5

IDENTIFYING THE USAGE PATTERNS OF METHYL TERT-BUTYL ETHER (MTBE) AND OTHER OXYGENATES IN GASOLINE USING GASOLINE  

E-Print Network [OSTI]

IDENTIFYING THE USAGE PATTERNS OF METHYL TERT-BUTYL ETHER (MTBE) AND OTHER OXYGENATES IN GASOLINE USING GASOLINE SURVEYS By Michael J. Moran, Rick M. Clawges, and John S. Zogorski U.S. Geological Survey 1608 Mt. View Rapid City, SD 57702 Methyl tert-butyl ether (MTBE) is commonly added to gasoline

6

Whole-Genome Analysis of Methyl tert-Butyl Ether-Degrading Beta-Proteobacterium Methylibium petroleiphilum PM1  

E-Print Network [OSTI]

Sato, and N. Kato. 2003. Propane monooxygenase and NAD + -alcohol dehydrogenase in propane metabolism by Gordonia sp.tert-butyl ether by propane-grown Mycobacterium vaccae JOB5.

2007-01-01T23:59:59.000Z

7

Dynamic Simulation of Startup in Ethyl tert-Butyl Ether Reactive Distillation with Input Multiplicity  

Science Journals Connector (OSTI)

Dynamic Simulation of Startup in Ethyl tert-Butyl Ether Reactive Distillation with Input Multiplicity ... However, smaller internal rates inside the column that result from lower reboiler and condenser duty could increase the potential risk of flooding in the column and reduce the availability of reactants in the reactive section. ... Column simulations performed using both Pro/II and SpeedUp showed excellent agreement with previously published exptl. ...

Budi H. Bisowarno; Moses O. Tadé

2000-05-09T23:59:59.000Z

8

Detection and Quantification of Methyl tert-Butyl Ether-Degrading Strain PM1 by Real-Time TaqMan PCR  

Science Journals Connector (OSTI)

...purification Fresh Water microbiology Geologic...Polymerase metabolism Water Pollution, Chemical...bioremediation detection ethers ground water hydrocarbons methyl tert-butyl...pollutants pollution remediation sampling water resources...

Krassimira R. Hristova; Christian M. Lutenegger; Kate M. Scow

2001-11-01T23:59:59.000Z

9

Methyl tert-butyl ether (MTBE) is a volatile organic com-pound (VOC) derived from natural gas that is added to gas-  

E-Print Network [OSTI]

Methyl tert-butyl ether (MTBE) is a volatile organic com- pound (VOC) derived from natural gas Water in Urban and Agricultural Areas made from methanol, which is derived primarily from natural gas that is added to gas- oline either seasonally or year round in many parts of the United States to increase

10

E-Print Network 3.0 - anhydride-vinyl methyl ether Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

4-Methyl-2-pentanol Other secondary alcohols... - quire handling with precautions. Acrolein tert-Butyl methyl ether Di(1-propynl) ether n... Methoxy-1,3,5,7- cyclooctatetraene...

11

Ditertiary butyl peroxide recovery  

SciTech Connect (OSTI)

A process is described wherein a feed material comprising significant amounts of tertiary butyl hydroperoxide and tertiary butyl alcohol and minor amounts of ditertiary butyl peroxide and other impurities is charged to a reactor together with propylene and a soluble epoxidation catalyst. At least a portion of the tertiary butyl hydroperoxide is reacted in the reactor with the propylene to form a reaction product composed of unreacted feed components, propylene oxide, an additional quantity of tertiary butyl alcohol, and impurities, including a minor amount of ditertiary butyl peroxide. The improvement for recovering substantially pure ditertiary butyl peroxide from the reaction product after the reaction product is discharged from the reactor comprises the steps of: charging the reaction product to a first distillation zone and separating therein a first unreacted propylene distillate recycle fraction, charging the remaining heavier components of the reaction product from the first distillation zone to a second distillation zone and separating a second propylene oxide distillate product fraction therein charging the heavier components from the second distillation zone to a third distillation zone and separating a third distillate fraction comprising a major amount of tertiary butyl alcohol and a minor amount of ditertiary butyl peroxide, and recovering the second propylene oxide distillate fraction, the heavier tertiary butyl alcohol product fraction and the ditertiary butyl peroxide raffinate fraction.

Sanderson, J.R.; Meyer, R.A.; Smith, W.A.; Marquis, E.T.

1989-03-07T23:59:59.000Z

12

Thermodynamic properties of organic oxygen compounds XLIII. Vapour pressures of some ethers  

Science Journals Connector (OSTI)

Vapour pressures of methyl propyl, isopropyl methyl, butyl methyl, ethyl propyl, t-butyl methyl, dipropyl, di-isopropyl, di-t-butyl, and decyl methyl ethers were measured at pressures up to 205 kPa. The measured values were fitted by Antoine and by Chebyshev equations, values already published from this laboratory for three aromatic ethers were recomputed uniformly with the present results, and published values for four additional compounds were incorporated in a scheme for correlation of the vapour pressures of ethers. Estimates were made of the vapour pressures of 10 other ethers. Between 5 and 200 kPa the vapour pressures of ethers may be represented by a single equation in which carbon number or an effective carbon number is a parameter. Chebyshev equations are given for interpolation between the upper bounds of the measurements and the critical pressures of 11 ethers for which this property has been previously determined.

D Ambrose; J.H Ellender; C.H.S Sprake; R Townsend

1976-01-01T23:59:59.000Z

13

Production of methyl tert-alkyl ethers  

SciTech Connect (OSTI)

The transition to the use of unleaded gasolines has required the replacement of tetraethyl lead by oxygen-containing compounds such as methanol, ethanol, and ethers, which are termed {open_quotes}oxygenates{close_quotes} in the technical literature. These may be used in commercial gasolines in amounts of 10-15% by volume, equivalent to 2% oxygen by weight. When methyl tert-butyl ether (MTBE) is used, the oxygen content may amount to 2.7% by weight. This oxygenate gives a significant improvement of knock resistance of naphtha fractions, the greatest effects being observed for straight-run naphthas and reformer naphthas produced under normal conditions; the MTBE also improves the engine power and economy characteristics and lowers the carbon monoxide content in the exhaust by 15-30% and the hydrocarbon content by 7-8%. This paper describes methods for the production of MTBE and also methyl tert-alkyl ethers.

Trofimov, V.A.

1995-01-01T23:59:59.000Z

14

E-Print Network 3.0 - alkyl-tert alkyl ethers Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

> >> 1 7198 J. Org. Chem. 1995,60, 7198-7208 Gas Phase Decomposition of Conjugate Acid Ions of Simple Summary: of ProtonatedAlkyl tert-ButylEthers RO(H)C(CH&+ (To.6 Values in meV...

15

Reaction Pathways and Energetics of Etheric C?O Bond Cleavage Catalyzed by Lanthanide Triflates  

SciTech Connect (OSTI)

Efficient and selective cleavage of etheric C?O bonds is crucial for converting biomass into platform chemicals and liquid transportation fuels. In this contribution, computational methods at the DFT B3LYP level of theory are employed to understand the efficacy of lanthanide triflate catalysts (Ln(OTf)3, Ln = La, Ce, Sm, Gd, Yb, and Lu) in cleaving etheric C?O bonds. In agreement with experiment, the calculations indicate that the reaction pathway for C?O cleavage occurs via a C?H ? O?H proton transfer in concert with weakening of the C?O bond of the coordinated ether substrate to ultimately yield a coordinated alkenol. The activation energy for this process falls as the lanthanide ionic radius decreases, reflecting enhanced metal ion electrophilicity. Details of the reaction mechanism for Yb(OTf)3-catalyzed ring opening are explored in depth, and for 1-methyl-d3-butyl phenyl ether, the computed primary kinetic isotope effect of 2.4 is in excellent agreement with experiment (2.7), confirming that etheric ring-opening pathway involves proton transfer from the methyl group alpha to the etheric oxygen atom, which is activated by the electrophilic lanthanide ion. Calculations of the catalytic pathway using eight different ether substrates indicate that the more rapid cleavage of acyclic versus cyclic ethers is largely due to entropic effects, with the former C?O bond scission processes increasing the degrees of freedom/particles as the transition state is approached.

Assary, Rajeev S.; Atesin, Abdurrahman C.; Li, Zhi; Curtiss, Larry A.; Marks, Tobin J.

2013-07-15T23:59:59.000Z

16

Propenyl ether monomers for photopolymerization  

DOE Patents [OSTI]

Propenyl ether monomers of formula A(OCH{double_bond}CHCH{sub 3}){sub n} wherein n is an integer from one to six and A is selected from cyclic ethers, polyether and alkanes are disclosed. The monomers are readily polymerized in the presence of cationic photoinitiators, when exposed to actinic radiation, to form poly(propenyl ethers) that are useful for coatings, sealants, varnishes and adhesives. Compositions for preparing polymeric coatings comprising the compounds of the above formula together with particular cationic photoinitiators are also disclosed, as are processes for making the monomers from allyl halides and readily available alcohols. The process involves rearranging the resulting allyl ethers to propenyl ethers.

Crivello, J.V.

1996-10-22T23:59:59.000Z

17

Use of superconductor type catalysts in the preparation of tertiary butyl alcohol from tertiary butyl hydroperoxide  

SciTech Connect (OSTI)

In a method wherein a solution of a tertiary butyl hydroperoxide charge stock in tertiary butyl alcohol is brought into contact with a catalytically effective amount of a hydroperoxide decomposition catalyst in a hydroperoxide decomposition reaction zone in liquid phase with agitation to convert said tertiary butyl hydroperoxide to decomposition products, principally tertiary butyl alcohol, the improvement is described which comprises: (a) using a superconductor as said hydroperoxide decomposition catalyst, and (b) recovering tertiary butyl alcohol from the products of said hydroperoxide decomposition reaction.

Sanderson, J.R.; Stockton, M.E.

1993-08-17T23:59:59.000Z

18

Process for producing high purity isoolefins and dimers thereof by dissociation of ethers  

DOE Patents [OSTI]

Alkyl tertiary butyl ether or alkyl tertiary amyl ether is dissociated by vapor phase contact with a cation acidic exchange resin at temperatures in the range of 150 to 250 F at LHSV of 0.1 to 20 to produce a stream consisting of unreacted ether, isobutene or isoamylene and an alcohol corresponding to the alkyl radical. After the alcohol is removed, the ether/isoolefin stream may be fractionated to obtain a high purity isoolefin (99+%) or the ether/isoolefin stream can be contacted in liquid phase with a cation acidic exchange resin to selectively dimerize the isoolefin in a highly exothermic reaction, followed by fractionation of the dimerization product to produce high purity diisoolefin (97+%). In the case where the alkyl is C[sub 3] to C[sub 6] and the corresponding alcohol is produced on dissociation of the ether, combined dissociation-distillation may be carried out such that isoolefin is the overhead product and alcohol the bottom. 2 figs.

Smith, L.A. Jr.; Jones, E.M. Jr.; Hearn, D.

1984-05-08T23:59:59.000Z

19

Accelerated aging of EPDM and butyl elastomers  

SciTech Connect (OSTI)

This study was composed of three parts: a post cure study to optimize final properties of an ethylene-propylene-diene (EPDM) formulation, an accelerated aging study to compare the stress relaxation behavior of a butyl and an EPDM elastomer under compression, and a cursory evaluation of a new 70 Shore A EPDM. The optimum postcure for the EPDM was found to be 2 to 4 hours at 182{degrees}C in a vacuum. The EPDM was also shown to have superior aging characteristics compared to the butyl and is recommended for use instead of the butyl material. The physical properties for new 70 Shore A EPDM are satisfactory, and the stress relaxation behavior was only slightly inferior to the other EPDM.

Wilson, M.H.

1996-06-01T23:59:59.000Z

20

Use of ethers as high-octane components of gasolines  

SciTech Connect (OSTI)

This article reports on a study of the possible utilization of methyl tert-amyl ether (MTAE) as an automotive gasoline component, both by itself and in combination with methyl tert-butyl ether (MTBE). The naphtha used in these studies consisted of 80% reformer naphtha produced under severe conditions and 20% straight-run IBP-62/sup 0/C cut. The physicochemical properties of the MTAE, the MTBE, and the naphtha base stock are given. It is determined that MTAE, which has a slightly poorer knock resistance than MTBE, is fully equal to MTBE in all other respects and can be used as an automotive gasoline component; that a gasoline blend prepared from 89% naphtha base stock, 5.5% MTAE, and 5.5% MTBE meets all of the requirements of the standard GOST 2084-77 for Grade AI-93 gasoline; and that the use of MTAE offers a means for expanding the resources of high-octane components, lowering the toxicity of the gasolines and the exhaust gas (in comparison with organometallic antiknock agents), and bringing non-petroleum raw materials into the fuel production picture.

Gureev, A.A.; Baranova, G.N.; Korotkov, I.V.; Levinson, G.I.

1984-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "butyl ether eu" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

E-Print Network 3.0 - alkyl tert-butyl ether Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

> >> 1 7198 J. Org. Chem. 1995,60, 7198-7208 Gas Phase Decomposition of Conjugate Acid Ions of Simple Summary: .S.Patent 5,091,590,1992. 0 1995American Chemical Society...

22

Treatment of Methyl tert-Butyl Ether Vapors in Biotrickling Filters. 1.  

E-Print Network [OSTI]

because of its low cost and blending characteristics. Depending on the season, reformulated gasoline of reactor per hour, a value comparable to other gasoline constituents. Such high performance could enhancer in gasoline. The use of MTBE increased rapidly after the 1990 Clean Air Act Amendments required

23

Environmental Microbiology (2001) 3(6), 407416 Methyl tert-butyl ether (MTBE) degradation by a  

E-Print Network [OSTI]

Tank (LUFT) remediation programme. A recent USGS study has estimated that as many as 9000 community, remediation actions are implemented at costs usually 10± 30% higher than those at sites without MTBE contamina- tion. The evaluation of innovative and cost-effective treatment such as bioremediation for MTBE spills

24

Biodegradation of Methyl tert-Butyl Ether by a Pure Bacterial Culture  

Science Journals Connector (OSTI)

...identify cost-effective remediation technologies. Relatively...treated with ENV735 as a remediation biocatalyst, but the strain...through the Small Business Innovative Research program (grant...situ bioaugmentation for remediation of chlorinated solvents in...

Paul B. Hatzinger; Kevin McClay; Simon Vainberg; Marina Tugusheva; Charles W. Condee; Robert J. Steffan

2001-12-01T23:59:59.000Z

25

Treatment of Methyl tert-Butyl Ether Contaminated Water Using a Dense  

E-Print Network [OSTI]

discharge of organic compounds require that new, innovative tech- nologies and methods of remediation dioxide, making the DMP reactor a promising tool in the future remediation of water. Chemical and physical is transformed into a more toxic material or a substance that is more difficult to remediate, the treatment

Dandy, David

26

The EU Foreign Policy.  

E-Print Network [OSTI]

?? This dissertations aims to examine the EU Foreign Policy, and more precisely map the High Representative (HR) and his impact on the Common Foreign… (more)

Petersson, Emmy

2007-01-01T23:59:59.000Z

27

EU | OpenEI  

Open Energy Info (EERE)

EU EU Dataset Summary Description These datasets include GHG and CO2 emissions statistics for the European Union (EU). The statistics are available from the European Commission. Source European Commission Date Released Unknown Date Updated Unknown Keywords Biofuels CO2 emissions EU GHG emissions Data application/vnd.ms-excel icon Total GHG and CO2 Emissions for EU (xls, 853.5 KiB) application/vnd.ms-excel icon GHG Emissions by Sector, all member countries (xls, 2 MiB) application/vnd.ms-excel icon GHG Emissions from Transport, all member countries (xls, 1.3 MiB) application/vnd.ms-excel icon CO2 emissions by sector, all member countries (xls, 2.1 MiB) application/vnd.ms-excel icon CO2 emissions by transport, all member countries (xls, 1.5 MiB) Quality Metrics

28

High octane ethers from synthesis gas-derived alcohols. Final technical report, September 25, 1990--December 24, 1993  

SciTech Connect (OSTI)

The objective of the research was to develop the methodology for the catalytic synthesis of ethers, primarily methyl isobutyl ether (MIBE) and methyl tertiary butyl ether (MTBE), directly from alcohol mixtures that are rich in methanol and 2-methyl-1-propanol (isobutanol). The overall scheme involves gasification of coal, purification and shifting of the synthesis gas, higher alcohol synthesis, and direct synthesis of ethers. The last stage of the synthesis involves direct coupling of synthesis gas-derived methanol and isobutanol that has been previously demonstrated by us to occur over superacid catalysts to yield MIBE and smaller amounts of MTBE at moderate pressures and a mixture of methanol and isobutene at low pressures. A wide range of organic resin catalysts and inorganic oxide and zeolite catalysts have been investigated for activity and selectivity in directly coupling alcohols, principally methanol and isobutanol, to form ethers and in the dehydration of isobutanol to isobutene in the presence of methanol. All of these catalysts are strong acids, and it was found that the organic and inorganic catalysts operate in different, but overlapping, temperature ranges, i.e. mainly 60--120{degrees}C for the organic resins and 90--175{degrees}C for the inorganic catalysts. For both types of catalysts, the presence of strong acid centers is required for catalytic activity, as was demonstrated by lack of activity of fully K{sup +} ion exchanged Nafion resin and zirconia prior to being sulfated by treatment with sulfuric acid.

Klier, K.; Herman, R.G.

1994-05-01T23:59:59.000Z

29

Catalytic distillation for the synthesis of tertiary butyl alcohol.  

E-Print Network [OSTI]

??Catalytic Distillation for the synthesis of tertiary butyl alcohol (TBA) is investigated in this thesis. The solvent, ethylene glycol, is proposed as a means of… (more)

Safinski, Tomasz

2005-01-01T23:59:59.000Z

30

Near-Infrared Electrochromism in Electroactive Pentacenediquinone-Containing Poly(aryl ether)s  

E-Print Network [OSTI]

Near-Infrared Electrochromism in Electroactive Pentacenediquinone-Containing Poly(aryl etherVed October 21, 2005 The synthesis and near-infrared electrochromic properties of pentacenediquinone-infrared electrochromic properties of pentacenediquinone-containing poly(aryl ether)s were studied

Wan, Xin-hua

31

Complexation of Eu3+ with a macrocyclic lactam receptor: Experimental and theoretical study  

Science Journals Connector (OSTI)

From extraction experiments and ?-activity measurements, the extraction constant corresponding to the equilibrium Eu3+(aq) + 3A?(aq) + 1 (nb) ? 1·Eu3+(nb) + 3A?(nb) taking place in the two-phase water–nitrobenzene system ( A - = CF 3 SO 3 - ; 1 = macrocyclic lactam receptor – see Scheme 1; aq = aqueous phase, nb = nitrobenzene phase) was evaluated as log Kex (1·Eu3+, 3A?) = ?4.1 ± 0.1. Further, the stability constant of the 1·Eu3+ cationic complex in nitrobenzene saturated with water was calculated for a temperature of 25 °C: log ?nb (1·Eu3+) = 9.0 ± 0.1. Finally, by using DFT calculations, the most probable structure of the cationic complex species 1·Eu3+ was derived. In the resulting 1·Eu3+ complex, the “central” cation Eu3+ is bound by five bond interactions to two ethereal oxygen atoms and two carbonyl oxygens, as well as to one carbon atom of the corresponding benzene ring of the parent macrocyclic lactam receptor 1 via cation–? interaction.

Emanuel Makrlík; Stanislav Záliš; Zde?ka Sedláková; Petr Va?ura

2013-01-01T23:59:59.000Z

32

E-Print Network 3.0 - ammoniated glycyrrhizin butylated Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ammoniated glycyrrhizin butylated Search Powered by Explorit Topic List Advanced Search Sample search results for: ammoniated glycyrrhizin butylated Page: << < 1 2 3 4 5 > >> 1...

33

Crown Ethers in Graphene Bring Strong, Selective Binding | ornl...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Materials Characterization Crown Ethers in Graphene Bring Strong, Selective Binding November 14, 2014 Schematic showing a graphene sheet containing an array of ideal crown ethers....

34

Ethers have good gasoline-blending attributes  

SciTech Connect (OSTI)

Because of their compatibility with hydrocarbon gasoline-blending components, their high octane blending values, and their low volatility blending values, ethers will grow in use as gasoline blending components. This article discusses the properties of ethers as blending components, and environmental questions.

Unzelman, G.H.

1989-04-10T23:59:59.000Z

35

Purification of aqueous cellulose ethers  

SciTech Connect (OSTI)

Manufacture of cellulose ethers usually involves high amounts of salt by-products. For application of the product, salt must be removed. In this work, we have studied the injection of high-pressure CO{sub 2} into an aqueous polymer-salt solution; we find that upon addition of isopropanol in addition to CO{sub 2}, the solution separates into two phases. One phase is rich in polymer and water, and the other phase contains mostly isopropanol, water and CO{sub 2}. The salt distributes between the two phases, thereby offering interesting possibilities for development of a new purification process for water-soluble polymers. This work presents experimental phase-equilibrium data for hydroxyethyl cellulose and sodium carboxymethyl cellulose with sodium acetate and potassium sulfate, respectively, in the region 40{degree}C and 30 to 80 bar. Based on these data, we suggest a process for the manufacture and purification of water-soluble cellulose ethers. 15 refs., 14 figs., 9 tabs.

Bartscherer, K.A.; de Pablo, J.J.; Bonnin, M.C.; Prausnitz, J.M.

1990-07-01T23:59:59.000Z

36

Impacts of Ethanol on Anaerobic Production of Tert-Butyl Alcohol (TBA) from Methyl Tert-Butyl Ether (MTBE) in Groundwater  

E-Print Network [OSTI]

Project title: Impacts of Ethanol on Anaerobic Production oftert-butanol (TBA). As ethanol is being promoted as ainvestigate the effect of ethanol release on existing MTBE

Scow, K M; MacKay, Douglas

2008-01-01T23:59:59.000Z

37

Biodegradation of Methyl tert-Butyl Ether and Other Fuel Oxygenates by a New Strain, Mycobacterium austroafricanum IFP 2012  

Science Journals Connector (OSTI)

...and the O2 consumption rate was measured with a 12-mm...France). The measured rates were corrected for endogenous...Cells were broken by three passes through a French press...from 105 to 200C at a rate of 10C/min. Helium...flushed with a Spectra-Physics SCM 400 vacuum flusher...

Alan François; Hugues Mathis; Davy Godefroy; Pascal Piveteau; Françoise Fayolle; Frédéric Monot

2002-06-01T23:59:59.000Z

38

Induction of Methyl Tertiary Butyl Ether (MTBE)-Oxidizing Activity in Mycobacterium vaccae JOB5 by MTBE  

Science Journals Connector (OSTI)

...directly from the culture vessels. In experiments that followed...time course of organic acid consumption as well as MTBE oxidation...determine the extent of MTBE consumption and the accumulation of TBA...detectable growth or MTBE consumption occurred when cells were incubated...

Erika L. Johnson; Christy A. Smith; Kirk T. O'Reilly; Michael R. Hyman

2004-02-01T23:59:59.000Z

39

Enhancing Transport of Hydrogenophaga flava ENV735 for Bioaugmentation of Aquifers Contaminated with Methyl tert-Butyl Ether  

Science Journals Connector (OSTI)

...column was washed with the surfactant solution. d The sand was prewashed with the surfactant solution, and the cells...washed with BSM without surfactant. This work was supported...bacteria through a sandy soil. Appl. Environ. Microbiol...

Sheryl H. Streger; Simon Vainberg; Hailiang Dong; Paul B. Hatzinger

2002-11-01T23:59:59.000Z

40

Treatment of methyl t-butyl ether contaminated water using a dense medium plasma reactor, a mechanistic and kinetic investigation  

E-Print Network [OSTI]

, a mechanistic and kinetic investigation Derek C. Johnson1 , Vasgen A. Shamamian2 , John H. Callahan2 , Ferencz S in the future remediation of water. Chemical and physical mechanisms, together with carbon balances, are used

Dandy, David

Note: This page contains sample records for the topic "butyl ether eu" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Effects of Gasoline Formulation on Methyl tert-Butyl Ether (MTBE) Contamination in Private Wells near Gasoline Stations  

Science Journals Connector (OSTI)

New York State Department of Health, Bureau of Environmental Exposure Investigation, 547 River Street, Room 300, Troy, New York 12180, and New York State Department of Health, Wadsworth Center for Laboratories and Research, P.O. ... Wells with contamination of ?20 ?g/L were scheduled for periodic or follow-up sampling by local county health departments or scheduled for remedial action, as appropriate. ... (13)?Delzer, G. C.; Zogorski, J. S.; Lopes, T. J.; Bosshart, R. L. Occurrence of the gasoline Oxygenate MTBE and BTEX compounds in urban stormwater in the United States, 1991?1995; U.S. Geologic Survey Water-Resources Investigations Report, WRIR 96-4145, Rapid City, SD, 1996. ...

Daniel P. Lince; Lloyd R. Wilson; Gordon A. Carlson; Anthony Bucciferro

2001-02-10T23:59:59.000Z

42

Enhancing Transport of Hydrogenophaga flava ENV735 for Bioaugmentation of Aquifers Contaminated with Methyl tert-Butyl Ether  

Science Journals Connector (OSTI)

...National Science Foundation Small Business Innovative Research (SBIR) program (award no...Ontario, Canada. Ground Water Monit. Remediation 18: 113-122. 52 Scholl, M. A...evaluation of in situ bioaugmentation for remediation of chlorinated solvents in groundwater...

Sheryl H. Streger; Simon Vainberg; Hailiang Dong; Paul B. Hatzinger

2002-11-01T23:59:59.000Z

43

Measurement of Trihalomethanes and Methyl Tertiary-Butyl Ether in Tap Water Using Solid-Phase Microextraction GC-MS  

Science Journals Connector (OSTI)

......ductive age living in Corpus Christi, Texas and Cobb...micro extraction with gas chromatography-mass...determinations using gas chromatog- raphy...of fulvic acids in natural waters. Env. Sci...trihalomethane by headspace-gas chromatog- raphy......

Frederick L. Cardinali; David L. Ashley; John C. Morrow; Deborah M. Moll; Benjamin C. Blount

2004-04-01T23:59:59.000Z

44

The Thermal Decomposition of Diethyl Ether. V. The Production of Ethanol from Diethyl Ether and the Pyrolysis of Ethanol  

Science Journals Connector (OSTI)

...The Thermal Decomposition of Diethyl Ether. V. The Production of Ethanol from Diethyl Ether and the Pyrolysis of Ethanol G. R. Freeman The two modes of decomposition of ethanol at 525 degrees C, namely dehydration and dehydrogenation, are affected...

1958-01-01T23:59:59.000Z

45

Process for making propenyl ethers and photopolymerizable compositions containing them  

DOE Patents [OSTI]

Propenyl ether monomers of formula A(OCH{double_bond}CHCH{sub 3}){sub n} (V) wherein n is an integer from one to six and A is selected from cyclic ethers, polyether, and alkanes are disclosed. The monomers are readily polymerized in the presence of cationic photoinitiators, when exposed to actinic radiation, to form poly(propenyl ethers) that are useful for coatings, sealants, varnishes and adhesives. Compositions for preparing polymeric coatings comprising the compounds of formula V together with particular cationic photoinitiators are also disclosed, as are processes for making the monomers from allyl halides and readily available alcohols. The process involves rearranging the resulting allyl ethers to propenyl ethers.

Crivello, J.V.

1996-01-23T23:59:59.000Z

46

EU competition law on electricity sector liberalisation  

Science Journals Connector (OSTI)

This paper aims to study how competition law helps facilitate the process of EU electricity liberalisation and study the use of competition law on the liberalised EU energy market. This paper provides an overview of competition law regarding to purposes of EU competition law and articles 101, 102 and 106 of EC Treaty on the Functioning of the European Union. The paper explores the role of competition law on EU electricity market liberalisation and focuses on the three main directive packages that transform EU electricity market towards competition. It further explores competition law enforcement that facilitates the structural change in EU electricity sector and discusses how the EU Competition Commission utilise the competition law to decrease market barriers in EU electricity sector. Finally the paper focuses on possible issues for competition law on EU electricity sector, especially on merger and acquisition cases. The last part provides conclusion of the paper.

Pornchai Wisuttisak

2014-01-01T23:59:59.000Z

47

Hyperfine Structure of EuI  

Science Journals Connector (OSTI)

14 December 1965 research-article Hyperfine Structure of EuI Y. Bordarier B. R. Judd M. Klapisch A theoretical analysis is made of the hyperfine structure of the twelve levels of Eu I...

1965-01-01T23:59:59.000Z

48

Crown Ethers Flatten in Graphene for Strong, Specific Binding...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Crown Ethers Flatten in Graphene for Strong, Specific Binding ORNL discovery holds potential for separations, sensors, batteries, biotech and more This sheet of graphene contains...

49

Densities and isobaric vapor-liquid equilibria for the mixtures formed by four butyl esters and 1-butanol  

SciTech Connect (OSTI)

Densities of 298.15 K and the vapor-liquid equilibria for 1-butanol + butyl methanoate, + butyl ethanoate, + butyl propanoate, and + butyl butanoate have been measured at 101.32 kPa in small capacity ebulliometer. All results were found to be thermodynamically consistent with a point-to-point test. The mixtures containing butyl methanoate and butyl ethanoate show azeotropes at T = 379.14 K, x = 0.871 and T = 389.64 K, x = 0.222, respectively. Different group-contribution methods were applied to these mixtures.

Gonzalez, E.; Ortega, J. [Univ. of Las Palmas de Gran Canaria (Spain)] [Univ. of Las Palmas de Gran Canaria (Spain)

1996-01-01T23:59:59.000Z

50

Solvent Effects on Metal Complexation with Crown Ethers from Liquid to Supercritical Fluids (DE-FG07-98ER 149 13)  

SciTech Connect (OSTI)

The purpose of this project is to study the salvation effects of metal-crown ether complexation in different solvents. It has been suggested in the literature that supercritical fluid carbon dioxide (SF-CO2) is a tunable solvent because its salvation environment can be varied with the fluid density. In this project, spectroscopic techniques including nuclear magnetic resonance (NMR) and Fourier Transform Infrared (FTIR) were used to evaluate salvation effects of metal crown complexation in organic solvents and in SF-CO2. In most solvent extraction systems, water is often involved in the extraction processes. We have carried out extensive studies of water-crown ether interactions in different solvents and in SF-CO2 using NMR and FTIR techniques. Water molecules can be attached to crown ethers through hydrogen bonding of H-0-H to the oxygen atoms of crown ether cavities. This type of interaction is like a Lewis acid-Lewis base complexation. During the course of this project, we noticed that some CO2 soluble Lewis base such as tri-n-butyl-phosphate (TBP) can also form such Lewis acid-Lewis base complexes with water and other inorganic acids including nitric acid and hydrochloric acid. Inorganic acids (e.g. nitric acid) are normally not soluble in SF-CO2. However, because TBP is highly soluble in SF-CO2, an inorganic acid bound to TBP via hydrogen bonding becomes CO2 soluble. This Lewis acid-Lewis base complex approach provides a method of introducing inorganic acids into supercritical fluid CO2 for chemical reactions.

Wai, C.M.

2002-06-01T23:59:59.000Z

51

Crown Ethers in Nonaqueous Electrolytes for Lithium/Air Batteries  

SciTech Connect (OSTI)

The effects of three crown ethers, 12-crown-4, 15-crown-5, and 18-crown-6, as additives and co-solvents in non-aqueous electrolytes on the cell performance of primary Li/air batteries operated in a dry air environment were investigated. Crown ethers have large effects on the discharge performance of non-aqueous electrolytes in Li/air batteries. A small amount (normally less than 10% by weight or volume in electrolytes) of 12-Crown-4 and 15-crown-5 reduces the battery performance and a minimum discharge capacity appears at the crown ether content of ca. 5% in the electrolytes. However, when the content increases to about 15%, both crown ethers improve the capacity of Li/air cells by about 28% and 16%, respectively. 15-Crown-5 based electrolytes even show a maximum discharge capacity in the crown ether content range from 10% to 15%. On the other hand, the increase of 18-crown-6 amount in the electrolytes continuously lowers of the cell performance. The different battery performances of these three crown ethers in electrolytes are explained by the combined effects from the electrolytes’ contact angle, oxygen solubility, viscosity, ionic conductivity, and the stability of complexes formed between crown ether molecules and lithium ions.

Xu, Wu; Xiao, Jie; Wang, Deyu; Zhang, Jian; Zhang, Jiguang

2010-02-04T23:59:59.000Z

52

Shear viscosity measurements in the binary mixture butyl cellosolve-water near its upper and lower critical consolute points  

E-Print Network [OSTI]

has been measured for a two-component critical liquid system, butyl cellosolve-water, in the region to report measurements of the shear viscosity of critical binary mixture butyl cello- solve (2-n353 Shear viscosity measurements in the binary mixture butyl cellosolve-water near its upper

Boyer, Edmond

53

EU Energy Wind Limited | Open Energy Information  

Open Energy Info (EERE)

energy Product: The company will be concentrating initially on bringing an innovative composite wind tower to market. References: EU Energy (Wind) Limited1 This article is a...

54

Properties Investigation of Sulfonated Poly(ether ether ketone)/Polyacrylonitrile Acid–Base Blend Membrane for Vanadium Redox Flow Battery Application  

Science Journals Connector (OSTI)

Acid–base blend membrane prepared from sulfonated poly(ether ether ketone) (SPEEK) and polyacrylonitrile (PAN) was detailedly evaluated for vanadium redox flow battery (VRFB) application. SPEEK/PAN blend membrane exhibited dense and homogeneous cross-...

Zhaohua Li; Wenjing Dai; Lihong Yu; Le Liu; Jingyu Xi; Xinping Qiu; Liquan Chen

2014-10-15T23:59:59.000Z

55

Atmospheric and combustion chemistry of dimethyl ether  

SciTech Connect (OSTI)

It has been demonstrated that dimethyl ether (DME) is an ideal diesel fuel alternative. DME, CH{sub 3}OCH{sub 3}, combines good fuel properties with low exhaust emissions and low combustion noise. Large scale production of this fuel can take place using a single step catalytic process converting CH{sub 4} to DME. The fate of DME in the atmosphere has previously been studied. The atmospheric degradation is initiated by the reaction with hydroxyl radicals, which is also a common feature of combustion processes. Spectrokinetic investigations and product analysis were used to demonstrate that the intermediate oxy radical, CH{sub 3}OCH{sub 2}O, exhibits a novel reaction pathway of hydrogen atom ejection. The application of tandem mass spectrometry to chemi-ions based on supersonic molecular beam sampling has recently been demonstrated. The highly reactive ionic intermediates are sampled directly from the flame and identified by collision activation mass spectrometry and ion-molecule reactions. The mass spectrum reflects the distribution of the intermediates in the flame. The atmospheric degradation of DME as well as the unique fuel properties of a oxygen containing compound will be discussed.

Nielsen, O.J.; Egsgaard, H.; Larsen, E.; Sehested, J. [Risoe National Lab., Roskilde (Denmark); Wallington, T.J. [Ford Motor Co., Dearborn, MI (United States)

1997-12-31T23:59:59.000Z

56

De-Carbonizing California and the EU  

E-Print Network [OSTI]

biofuel Yearly vehicle tax Bio fuel car subsidy EU specific200) subsidy when purchasing a bio fuel car Emission tradingincreasing electric use and bio-fuels . The total fuel use

Berck, Peter; Brannlund, Runar

2008-01-01T23:59:59.000Z

57

Reduction of Eu{sup 3+} to Eu{sup 2+} in aluminoborosilicate glasses under ionizing radiation  

SciTech Connect (OSTI)

Eu{sub 2}O{sub 3}-doped aluminoborosilicate glasses were prepared by melting in air at high temperature ({approx}1500 {sup o}C). It was shown by luminescence and Electron Paramagnetic Resonance (EPR) measurements that both Eu{sup 3+} and Eu{sup 2+} ions can exist simultaneously in the glass matrix studied after glass synthesis as well as after exposure to ionizing radiation. Increase of total Eu{sub 2}O{sub 3} concentration leads to the increase of Eu{sup 3+} luminescence intensity while the luminescence intensity of Eu{sup 2+} ions tends to decrease. In contrast the EPR indicates that the amount of Eu{sup 2+} ions in the glass increases with total Eu{sub 2}O{sub 3} concentration. The difference in the results of the two spectroscopies is explained in terms of energy transfer from Eu{sup 2+} to Eu{sup 3+} leading to an Eu{sup 2+} luminescence quenching. Irradiation results in the increase of reduced Eu{sup 2+} quantity detected by EPR measurements. It was shown that Eu{sup 2+} ions are located in both high (g {approx} 4.6) and low symmetry ('U' spectrum) sites in the structure of aluminoborosilicate glasses. The increase of Eu{sup 2+} content by the increase of the irradiation dose manifests the strong reduction process Eu{sup 3+} {yields} Eu{sup 2+}.

Malchukova, E., E-mail: genia@poly.polytechnique.fr [Laboratoire des Solides Irradies, UMR 7642 CEA-CNRS-Ecole Polytechnique, 91128 Palaiseau Cedex (France); Boizot, B. [Laboratoire des Solides Irradies, UMR 7642 CEA-CNRS-Ecole Polytechnique, 91128 Palaiseau Cedex (France)] [Laboratoire des Solides Irradies, UMR 7642 CEA-CNRS-Ecole Polytechnique, 91128 Palaiseau Cedex (France)

2010-09-15T23:59:59.000Z

58

The economic impact of the upcoming EU emissions trading system on airlines and EU Member States—an empirical estimation  

Science Journals Connector (OSTI)

In February 2009, the European Union’s (EU) Directive for the inclusion of aviation into the EU Emissions Trading Scheme (EU-ETS) for CO2-emissions came into force. From 2012 onwards, the EU-ETS will cover virtua...

Martin Schaefer; Janina Scheelhaase; Wolfgang Grimme…

2010-12-01T23:59:59.000Z

59

Kinetic mechanism of dimethyl ether production process using syngas from integrated gasification combined cycle power plant  

Science Journals Connector (OSTI)

In a 1-step synthesis gas-to-dimethyl ether process, synthesis gas is converted into dimethyl ether (DME) in a single reactor. Three reactions are involved in this process: methanol synthesis, methanol dehydra...

Hee-Woo Park; Jin-Kuk Ha; Euy Soo Lee

2014-07-01T23:59:59.000Z

60

Hydrogen Generation from Dimethyl Ether for Fuel Cell Auxiliary Power Units  

Science Journals Connector (OSTI)

Hydrogen Generation from Dimethyl Ether for Fuel Cell Auxiliary Power Units ... Vehicle manufacturers are rushing ahead with research into alternative fuels such as dimethyl ether (DME), biodiesel, methanol, ethanol, and hydrogen. ...

Marita Nilsson; Lars J. Pettersson; Bård Lindström

2006-07-29T23:59:59.000Z

Note: This page contains sample records for the topic "butyl ether eu" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Effects of simulant mixed waste on EPDM and butyl rubber  

SciTech Connect (OSTI)

The authors have developed a Chemical Compatibility Testing Program for the evaluation of plastic packaging components which may be used in transporting mixed waste forms. In this program, they have screened 10 plastic materials in four liquid mixed waste simulants. These plastics were butadiene-acrylonitrile copolymer (Nitrile) rubber, cross-linked polyethylene, epichlorohydrin rubber, ethylene-propylene (EPDM) rubber, fluorocarbons (Viton and Kel-F{trademark}), polytetrafluoro-ethylene (Teflon), high-density polyethylene, isobutylene-isoprene copolymer (Butyl) rubber, polypropylene, and styrene-butadiene (SBR) rubber. The selected simulant mixed wastes were (1) an aqueous alkaline mixture of sodium nitrate and sodium nitrite; (2) a chlorinated hydrocarbon mixture; (3) a simulant liquid scintillation fluid; and (4) a mixture of ketones. The screening testing protocol involved exposing the respective materials to approximately 3 kGy of gamma radiation followed by 14-day exposures to the waste simulants at 60 C. The rubber materials or elastomers were tested using Vapor Transport Rate measurements while the liner materials were tested using specific gravity as a metric. The authors have developed a chemical compatibility program for the evaluation of plastic packaging components which may be incorporated in packaging for transporting mixed waste forms. From the data analyses performed to date, they have identified the thermoplastic, polychlorotrifluoroethylene, as having the greatest chemical compatibility after having been exposed to gamma radiation followed by exposure to the Hanford Tank simulant mixed waste. The most striking observation from this study was the poor performance of polytetrafluoroethylene under these conditions. In the evaluation of the two elastomeric materials they have concluded that while both materials exhibit remarkable resistance to these environmental conditions, EPDM has a greater resistance to this corrosive simulant mixed waste.

Nigrey, P.J.; Dickens, T.G.

1997-11-01T23:59:59.000Z

62

The Effect of the Di-Tertiary Butyl Peroxide (DTBP) additive on HCCI Combustion of Fuel Blends of Ethanol and Diethyl Ether  

E-Print Network [OSTI]

Ignition Using Isooctane, Ethanol and Natural Gas - AModel for High Temperature Ethanol Oxidation," Internationalof Bio-Derived Carbon from Ethanol-in-Diesel Blends in the

Mack, John Hunter; Buchholz, Bruce A; Flowers, Daniel L; Dibble, Robert W

2005-01-01T23:59:59.000Z

63

RELATIONS BETWEEN THE DETECTION OF METHYL TERT-BUTYL ETHER (MTBE) IN SURFACE AND GROUND WATER AND ITS CONTENT IN GASOLINE  

E-Print Network [OSTI]

AND ITS CONTENT IN GASOLINE By Michael J. Moran, Mike J. Halde, Rick M. Clawges and John S. Zogorski U in the United States as an octane enhancer and oxygenate in gasoline. Octane enhancement began in the late 1970's with the phase-out of tetraethyl lead from gasoline. The use of oxygenates was expanded

64

Synthesis of Medium Ring Ethers. 5. The Synthesis of (+)-Laurencin  

Science Journals Connector (OSTI)

The eight-membered medium ring ether natural product (+)-laurencin 1 is the prototypical member of a growing family of marine natural product cyclic ethers isolated from red algae and those marine organisms which feed on Laurencia species. ... The reaction mixture immediately became yellow and gradually turned dark red as gas was evolved. ... We thank the Engineering and Physical Sciences Research Council (EPSRC) UK for a research grant, Pfizer Central Research, and Corpus Christi College Cambridge for the award of a studentship and a Junior Research Fellow ship (J.W.B.), the Cambridge European Overseas Trust, Ciba (Novartis) and the Swiss Foundation for Gifted Students (scholarship to S.D.), and the Commission of the European Communities (TMR award to T.C.S.) for generous financial support. ...

Jonathan W. Burton; J. Stephen Clark; Sam Derrer; Thomas C. Stork; Justin G. Bendall; Andrew B. Holmes

1997-08-13T23:59:59.000Z

65

Japan, EU reach basic agreement over ITER The Yomiuri Shimbun  

E-Print Network [OSTI]

Japan, EU reach basic agreement over ITER The Yomiuri Shimbun The government and the European Union to the unsuccessful candidate country. Japan and France, the EU's candidate, have been bidding to host the facility bidder's country. The ITER project participants--Japan, China, the EU, Russia, South Korea and the United

66

EU Verbraucherrechte Apple One-Year Limited  

E-Print Network [OSTI]

EU Verbraucherrechte Apple One-Year Limited Warranty AppleCare Protection Plan CC Service Pack, Kabel. Zusätzlich bei allen Macs: 1x Time Capsule oder 1x Airport Gerät sowie 1x Apple Display Macs u sowie 1x Apple Display Material- u. Herstellungsfehler. Keine Leistung für Verschlei�teile wie Akku

Fiebig, Peter

67

Dimethyl Ether Autoignition at Engine-Relevant Conditions  

Science Journals Connector (OSTI)

† Key Laboratory for Power Machinery and Engineering of M.O.E., Shanghai Jiao Tong University, Shanghai 200240, People’s Republic of China ... The autoignition of dimethyl ether (DME), an alternative diesel engine fuel, has been studied at elevated pressures. ... In addition to studies aimed at ascertaining the performance of compression–ignition internal combustion engines fuel with DME,(2, 3) there have been a number of studies focused on experimental characterization of fundamental combustion properties for DME. ...

Zhenhua Li; Weijing Wang; Zhen Huang; Matthew A. Oehlschlaeger

2013-04-01T23:59:59.000Z

68

2' and 3' Carboranyl uridines and their diethyl ether adducts  

DOE Patents [OSTI]

There is disclosed a process for preparing carboranyl uridine nucleoside compounds and their diethyl ether adducts, which exhibit a tenfold increase in boron content over prior art boron containing nucleoside compounds. Said carboranyl uridine nucleoside compounds exhibit enhanced lipophilicity and hydrophilic properties adequate to enable solvation in aqueous media for subsequent incorporation of said compounds in methods for boron neutron capture therapy in mammalian tumor cells.

Soloway, Albert H. (Worthington, OH); Barth, Rolf F. (Columbus, OH); Anisuzzaman, Abul K. (Columbus, OH); Alam, Fazlul (Anaheim, CA); Tjarks, Werner (Columbus, OH)

1992-01-01T23:59:59.000Z

69

Palladium/Tris(tert-butyl)phosphine-Catalyzed Suzuki Cross-Couplings in the Presence of Water  

E-Print Network [OSTI]

Dipalladiumtris(dibenzylideneacetone)/tris(tert-butyl)phosphonium tetrafluoroborate/potassium fluoride dihydrate [Pd2(dba)3/[HP(t-Bu)3]BF4/KF?2?H2O] serves as a mild, robust, and user-friendly method for the efficient ...

Lou, Sha

70

The interactions of water and perfluorodiethyl ether on Ru(100)  

SciTech Connect (OSTI)

We have studied the interactions of water and perfluorodiethyl ether on Ru(100) in order to model the effects of surface structure and humidity on the bonding and decomposition of perfluoroalkyl ether lubricants with metal surfaces. In order to understand the interactions on Ru(100), we have first investigated the interactions of each of these adsorbates alone on the clean surface. The interactions of water with Ru(100) have been studied using both thermal desorption spectroscopy (TDS) and electron energy loss spectroscopy (EELS). From these studies we conclude that a small amount of water dissociates on this surface (5--10% of a monolayer), but water is adsorbed in a predominantly molecular form on this surface with an increasing degree of hydrogen-bonding with increasing coverage. The effects of hydrogen and oxygen coadsorption on the interactions of water with this surface have also been studied using TDS. Finally, the interactions of coadsorbed water and perfluorodiethyl ether on Ru(100) have been investigated using TDS.

Leavitt, P.

1990-09-21T23:59:59.000Z

71

AirShares EU Carbon Allowances Fund | Open Energy Information  

Open Energy Info (EERE)

AirShares EU Carbon Allowances Fund AirShares EU Carbon Allowances Fund Jump to: navigation, search Name AirShares EU Carbon Allowances Fund Place New York, New York Zip 10170 Product AirShares is a commodity pool for exchange-traded futures contracts for EUAs. References AirShares EU Carbon Allowances Fund[1] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. AirShares EU Carbon Allowances Fund is a company located in New York, New York . References ↑ "AirShares EU Carbon Allowances Fund" Retrieved from "http://en.openei.org/w/index.php?title=AirShares_EU_Carbon_Allowances_Fund&oldid=341942" Categories: Clean Energy Organizations Companies Organizations Stubs What links here Related changes

72

Thermodynamics of Hydrogen Production from Dimethyl Ether Steam Reforming and Hydrolysis  

SciTech Connect (OSTI)

The thermodynamic analyses of producing a hydrogen-rich fuel-cell feed from the process of dimethyl ether (DME) steam reforming were investigated as a function of steam-to-carbon ratio (0-4), temperature (100 C-600 C), pressure (1-5 atm), and product species: acetylene, ethanol, methanol, ethylene, methyl-ethyl ether, formaldehyde, formic acid, acetone, n-propanol, ethane and isopropyl alcohol. Results of the thermodynamic processing of dimethyl ether with steam indicate the complete conversion of dimethyl ether to hydrogen, carbon monoxide and carbon dioxide for temperatures greater than 200 C and steam-to-carbon ratios greater than 1.25 at atmospheric pressure (P = 1 atm). Increasing the operating pressure was observed to shift the equilibrium toward the reactants; increasing the pressure from 1 atm to 5 atm decreased the conversion of dimethyl ether from 99.5% to 76.2%. The order of thermodynamically stable products in decreasing mole fraction was methane, ethane, isopropyl alcohol, acetone, n-propanol, ethylene, ethanol, methyl-ethyl ether and methanol--formaldehyde, formic acid, and acetylene were not observed. The optimal processing conditions for dimethyl ether steam reforming occurred at a steam-to-carbon ratio of 1.5, a pressure of 1 atm, and a temperature of 200 C. Modeling the thermodynamics of dimethyl ether hydrolysis (with methanol as the only product considered), the equilibrium conversion of dimethyl ether is limited. The equilibrium conversion was observed to increase with temperature and steam-to-carbon ratio, resulting in a maximum dimethyl ether conversion of approximately 68% at a steam-to-carbon ratio of 4.5 and a processing temperature of 600 C. Thermodynamically, dimethyl ether processed with steam can produce hydrogen-rich fuel-cell feeds--with hydrogen concentrations exceeding 70%. This substantiates dimethyl ether as a viable source of hydrogen for PEM fuel cells.

T.A. Semelsberger

2004-10-01T23:59:59.000Z

73

E-Print Network 3.0 - allyl glycidyl ether Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Science 15 () Trichloromethane ()1,1,2,2-1,1,2,2-Tetrachloroethane Summary: ;() Acrolein () Acrylic acid () Allyl zlcohol () Allyl chloride () Allyl glycidyl ether(AGE) ()2-...

74

POLYCHLORINATED BIPHENYLS AND POLYBROMINATED DIPHENYL ETHERS IN GALAPAGOS SEA LIONS (ZALOPHUS WOLLEBAEKI)  

E-Print Network [OSTI]

), polybrominated diphenyl ethers (PBDEs), polychlorinated dibenzo-p- dioxins (PCDDs), and polychlorinated dibenzo-p-dioxins (PCDDs), and polychlorinated dibenzofurans (PCDFs) repre- sent persistent

Gobas, Frank

75

Development of a Dimethyl Ether (DME)-Fueled Shuttle Bus | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

More Documents & Publications Alternative Fuels lDimethyl Ether Rheology and Materials Studies Liquid Fuels from Biomass BiodieselFuelManagementBestPracticesReport.pdf...

76

Understanding fuel switching under the EU ETS  

Science Journals Connector (OSTI)

Since the creation of the European Union Emission Trading Scheme (EU ETS), European power producers have monitored carbon emissions resulting from the composition of their production. Fuel switching is the main short-term abatement measure under the EU ETS. It consists in substituting combined cycle gas turbines (CCGTs) for hard-coal plants in off-peak power generation. Thereby coal plants run for shorter periods, allowing power producers to reduce their CO2 emissions. The aim of this paper is two-fold. First, we summarise the main characteristics of fuel switching under the EU ETS. Second, we show how differences in the energy/environmental efficiency of power plants impact the marginal cost of fuel switching. We demonstrate that the level of switching effort influences the dependence of the marginal cost of switching on fuel prices. The marginal cost of switching is shown to be increasingly dependent on the gas price as the switching effort increases, whereas the net effect is undetermined for the coal price. All the conclusions are summarised in several illustrative examples.

Vincent Bertrand

2012-01-01T23:59:59.000Z

77

Polybrominated diphenyl ether flame retardants in the antarctic environment  

E-Print Network [OSTI]

, the historical record of dioxins, PCBs and DDTs in the same cores showed a decreasing trend. At present, PBDEs are recognized as a worldwide pollution problem since they have reached remote areas such as the deep ocean, the Arctic and Antarctica (de Boer et al... that cheerful and warm Brazilian spirit. You are my Aggie family! viii NOMENCLATURE #1; critical value of a statistical test used to reject the null hypothesis ANOVA Analysis of Variance BDE Brominated Diphenyl Ether BFR Brominated Flame Retardant DC...

Yogui, Gilvan Takeshi

2009-05-15T23:59:59.000Z

78

Extraction of Plutonium into 30 Percent Tri-Butyl Phosphate from Nitric Acid Solution Containing Fluoride, Aluminum, and Boron  

SciTech Connect (OSTI)

This work consists of experimental batch extraction data for plutonium into 30 volume-percent tri-butyl phosphate at ambient temperature from such a solution matrix and a model of this data using complexation constants from the literature.

Kyser, E.A.

2000-01-06T23:59:59.000Z

79

Structure and Reactivity of Alkyl Ethers Adsorbed on CeO2(111) Model Catalysts  

SciTech Connect (OSTI)

The effect of surface hydroxyls on the adsorption of ether on ceria was explored. Adsorption of dimethyl ether (DME) and diethyl ether (DEE) on oxidized and reduced CeO{sub 2}(111) films was studied and compared with Ru(0001) using RAIRS and sXPS within a UHV environment. On Ru(0001) the ethers adsorb weakly with the molecular plane close to parallel to the surface plane. On the ceria films, the adsorption of the ethers was stronger than on the metal surface, presumably due to stronger interaction of the ether oxygen lone pair electrons with a cerium cation. This interaction causes the ethers to tilt away from the surface plane compared to the Ru(0001) surface. No pronounced differences were found between oxidized (CeO{sub 2}) and reduced (CeOx) films. The adsorption of the ethers was found to be perturbed by the presence of OH groups on hydroxylated CeOx. In the case of DEE, the geometry of adsorption resembles that found on Ru, and in the case of dimethyl ether DME is in between that one found on clean CeOx and the metal surface. Decomposition of the DEE was observed on the OH/CeOx surface following high DEE exposure at 300 K and higher temperatures. Ethoxides and acetates were identified as adsorbed species on the surface by means of RAIRS and ethoxides and formates by s-XPS. No decomposition of dimethyl ether was observed on the OH/CeOx at these higher temperatures, implying that the dissociation of the C-O bond from ethers requires the presence of {beta}-hydrogen.

F Calaza; T Chen; D Mullins; S Overbury

2011-12-31T23:59:59.000Z

80

Structure and Reactivity of Alkyl Ethers Adsorbed on CeO(2)(111) Model Catalysts  

SciTech Connect (OSTI)

The effect of surface hydroxyls on the adsorption of ether on ceria was explored. Adsorption of dimethyl ether (DME) and diethyl ether (DEE) on oxidized and reduced CeO{sub 2}(111) films was studied and compared with Ru(0001) using RAIRS and sXPS within a UHV environment. On Ru(0001) the ethers adsorb weakly with the molecular plane close to parallel to the surface plane. On the ceria films, the adsorption of the ethers was stronger than on the metal surface, presumably due to stronger interaction of the ether oxygen lone pair electrons with a cerium cation. This interaction causes the ethers to tilt away from the surface plane compared to the Ru(0001) surface. No pronounced differences were found between oxidized (CeO{sub 2}) and reduced (CeOx) films. The adsorption of the ethers was found to be perturbed by the presence of OH groups on hydroxylated CeOx. In the case of DEE, the geometry of adsorption resembles that found on Ru, and in the case of dimethyl ether DME is in between that one found on clean CeOx and the metal surface. Decomposition of the DEE was observed on the OH/CeOx surface following high DEE exposure at 300 K and higher temperatures. Ethoxides and acetates were identified as adsorbed species on the surface by means of RAIRS and ethoxides and formates by s-XPS. No decomposition of dimethyl ether was observed on the OH/CeOx at these higher temperatures, implying that the dissociation of the C-O bond from ethers requires the presence of {beta}-hydrogen.

Calaza, Florencia C [ORNL; Chen, Tsung-Liang [ORNL; Mullins, David R [ORNL; Overbury, Steven {Steve} H [ORNL

2011-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "butyl ether eu" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Aging of Weapon Seals – An Update on Butyl O-ring Issues  

SciTech Connect (OSTI)

During testing under the Enhanced Surveillance Campaign in 2001, preliminary data detected a previously unknown and potentially serious concern with recently procured butyl o-rings on several programs. All butyl o-rings molded from a proprietary formulation throughout the period circa 1999 through 2001 had less than a full cure. Engineering judgment was that under curing is detrimental and could possibly lead to sub-optimum performance or, in the worst case, premature seal failure. An aging study was undertaken to ensure that suspect o-rings installed in the stockpile will retain sufficient sealing force for a minimum ten-year service life. A new prediction model developed for this study indicates suspect o-rings do not need to be replaced before the ten-year service life. Long-term testing results are reported on a yearly basis to validate the prediction model. This report documents the aging results for the period September 2002 to January 2011.

Wilson, Mark H.

2011-07-13T23:59:59.000Z

82

Reverse osmosis performance with solutions containing tri-n-butyl phosphate  

SciTech Connect (OSTI)

Tests were conducted to determine whether the reverse osmosis (RO) units at the F/H Effluent Treatment Facility (ETF) at the Savannah River could be made to process solutions containing tri-n-butyl phosphate (TBP). It was desired to test whether operation at a feed pH other than neutral would improve performance. Test results are discussed in this report and indicate that little improvement in the water flux can be expected at other pH values.

Siler, J.L.

1991-10-22T23:59:59.000Z

83

Batch polymerization of styrene initiated by n-butyl lithium in a cyclohexane solvent  

E-Print Network [OSTI]

anionic mechanism. A mathematical model is de- veloped and the predicted values are compared with their corresponding experimental values. Initiator and monomer concentrations are varied and their conversion time profiles are studied. A G&el... and Storage Vessels Purification of Monomer Purification of Solvent Polymerization Reaction Scavenger Level Analysis o f Butyl Lithium Analysis of Molecular Weight Distributions by the Use of Gel Permeation Technique 10 19 19 ZO Zl ZZ 24 25 25...

Landon, Thomas Rodman

1971-01-01T23:59:59.000Z

84

Changing the rules of the game – An analysis of EU influence on electricity and gas liberalization, with a focus on the Baltic Sea region, and future challenges to EU energy market regulation.  

E-Print Network [OSTI]

??This study analyses the expansion of the EU into energy market regulation. It shows that the limits to EU influence and, thereby, EU energy market… (more)

Khiar, I L

2011-01-01T23:59:59.000Z

85

Decomposition of Ethanol and Dimethyl Ether During Chemical Vapour deposition Synthesis  

E-Print Network [OSTI]

1 Decomposition of Ethanol and Dimethyl Ether During Chemical Vapour deposition Synthesis of Single-phase thermal decomposition of ethanol and dimethyl ether (DME) at typical SWNT growth conditions using to the predicted decomposition mechanism. Signature peak intensities indicated concentrations of both ethanol

Maruyama, Shigeo

86

Composition and Digestibility of the Ether Extract of Hays and Fodders.  

E-Print Network [OSTI]

556-712-5m TEXAS AGRICULTURAL EXPERIMENT STATIONS. BULLETIN NO . 150 AUGUST , 1912. Division o f Chemistry TECHNICAL BULLETIN Composition and Digestibility of the Ether Extract of Hays and Fodders By G S. FRAPS and J. B. RATHER POSTOFFICE... Digestibility of the Constituents............................................................. 23 Summary and Conclusions.......................................................................29 BLANK PAGE IN ORIGINAL Composition and Digestibility of the Ether...

Fraps, G. S.; Rather, J. B.

1912-01-01T23:59:59.000Z

87

Proton-conducting polymer electrolyte membranes based on fluoropolymers incorporating perfluorovinyl ether sulfonic acids and fluoroalkenes  

E-Print Network [OSTI]

acids. A novel synthetic route describing the preparation of perfluorovinyl ether monomer containing. The radical (co) and terpolymerization of 4-[(,,-trifluorovinyl)oxy]benzene sulfonyl chloride (TFVOBSC) with 1,1-difluoroethylene (or vinylidene fluoride, VDF), hexafluoropropene (HFP), and perfluoromethyl vinyl ether (PMVE

Paris-Sud XI, Université de

88

Modelling the fate of polybrominated diphenyl ethers (PBDEs) during the municipal sewage treatment process  

Science Journals Connector (OSTI)

Sewage treatment plants (STPs) are an important source to the environment for many chemicals of concern (COCs). Polybrominated diphenyl ethers (PBDEs) are one such group of COCs of present day concern for which studies on fate and transport during the ... Keywords: chemical fate and transport, mass balance model, polybrominated diphenyl ethers, risk assessment, sewage treatment, water and wastewater management

Kerry N. McPhedran; Rajesh Seth

2007-08-01T23:59:59.000Z

89

Comb-shaped single ion conductors based on polyacrylate ethers and lithium  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Comb-shaped single ion conductors based on polyacrylate ethers and lithium Comb-shaped single ion conductors based on polyacrylate ethers and lithium alkyl sulfonate Title Comb-shaped single ion conductors based on polyacrylate ethers and lithium alkyl sulfonate Publication Type Journal Article Year of Publication 2005 Authors Sun, Xiao-Guang, Jun Hou, and John B. Kerr Journal Electrochimica Acta Volume 50 Pagination 1139-1147 Keywords ionic conductivity, plasticizer, polyacrylate ethers, single ion conductor Abstract Comb-shaped single ion conductors have been synthesized by sulfonation of small molecule chloroethyleneglycols, which, after ion exchange to the Li+ salt were then converted to the acrylate by reaction with acryloyl chloride and copolymerized with polyethylene glycol monomethyl ether acrylate (Mn = 454, n = 8) (PAE8-co-E3SO3Li);

90

The UK's negotiation of its EU budget rebate.  

E-Print Network [OSTI]

??This thesis is an investigation of Britain’s negotiations of its EU budget rebate. It attempts to answer the main question of why Britain decided to… (more)

Lee, Chung Hee

2011-01-01T23:59:59.000Z

91

Microsoft Word - EU-US Smart Grid assessment - final report ...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Smart Homes etc.) and provides reliable and sustainable electricity services (demand response, VPP, dispatching, integration of RES etc.). Policy drivers EU The overarching...

92

Rusland-Ukraine-EU Trianglen - strategier og konflikter.  

E-Print Network [OSTI]

??Projektet søger at belyse hvilke strategier og interesser der ligger bag Rusland og EU's udenrigspolitiske tilgang til Ukraine samt hvordan disse konflikter med hinanden. Dette… (more)

Abild, Kasper

2008-01-01T23:59:59.000Z

93

CMI hosts EU, Japan discuss global critical materials strategy...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

CMI hosts EU, Japan discuss global critical materials strategy Insider Finding ways to ensure the planet's supply of rare earths and other materials necessary for clean energy...

94

Kinetic measurements of the gas-phase reactions of OH radicals with hydroxy ethers, hydroxy ketones, and keto ethers  

SciTech Connect (OSTI)

Absolute rate constants were determined for the gas-phase reactions of hydroxyl radicals with a series of hydroxy ethers as well as the simplest hydroxy ketone and keto ether with use of the flash photolysis resonance fluorescence technique. At 298 K, the measured rate constants were as follows (in units of 10{sup {minus}12} cm{sup 3} molecule{sup {minus}1} s{sup {minus}1}): 2-methoxyethanol, 12.5 {plus minus} 0.7; 2-ethoxyethanol, 18.7 {plus minus} 2.0; 2-butoxyethanol, 23.1 {plus minus} 0.9; 3-ethoxy-1-propanol, 22.0 {plus minus} 1.3; 3-methoxy-l-butanol, 23.6 {plus minus} 1.6; acetol, 3.0 {plus minus} 0.3; and methoxyacetone, 6.8 {plus minus} 0.6. The kinetic data for 2-methoxyethanol obtained between 240 and 440 K were used to derive the following Arrhenius expression: k{sub 1} = (4.5 {plus minus} 1.4) {times} 10{sup {minus}12} exp((325 {plus minus} 100)/T) (cm{sup 3} molecule{sup {minus}1} s{sup {minus}1}). The results for all seven reactants are discussed in terms of the prediction of OH rate constants for oxygenated organic compounds.

Dagaut, P.; Liu, R.; Wallington, T.J.; Kurylo, M.J. (National Institute of Standards and Technology, Gaithersburg, MD (USA))

1989-11-16T23:59:59.000Z

95

Norway and Emissions Trading: From Global Front-Runner to EU Follower  

Science Journals Connector (OSTI)

A striking convergence has taken place in the design of the Norwegian and EU greenhouse gas emissions trading systems from 1998 to 2004. This article ... the EU trading system and resulted in EU emissions trading

Ingvild Andreassen Sæverud; Jørgen Wettestad

2006-03-01T23:59:59.000Z

96

Test of Orientation/Stretch-Induced Reduction of Friction via Primitive Chain Network Simulations for Polystyrene, Polyisoprene, and Poly(n-butyl acrylate)  

Science Journals Connector (OSTI)

Test of Orientation/Stretch-Induced Reduction of Friction via Primitive Chain Network Simulations for Polystyrene, Polyisoprene, and Poly(n-butyl acrylate) ...

Yuichi Masubuchi; Yumi Matsumiya; Hiroshi Watanabe

2014-09-24T23:59:59.000Z

97

Synthesis and Evaluation of 3',5'-Di-tert-butyl-4'-hydroxyflavones as Potential Inhibitors of Low Density Lipoprotein (LDL) Oxidation  

Science Journals Connector (OSTI)

Synthesis and Evaluation of 3',5'-Di-tert-butyl-4'-hydroxyflavones as Potential Inhibitors of Low Density Lipoprotein (LDL) Oxidation ...

Guy Lewin; Yves Rolland; Sylvie Privat; Christine Breugnot; Albert Lenaers; Jean Paul Vilaine; Jean-Pierre Baltaze; Jacques Poisson

1995-12-01T23:59:59.000Z

98

What (Economic) Constitution Does the EU Need ? Janvier 2007  

E-Print Network [OSTI]

What (Economic) Constitution Does the EU Need ? N° 2007-04 Janvier 2007 Eloi Laurent OFCE-FNSP eloi2014 #12;2 What (Economic) Constitution Does the EU Need? * �loi Laurent (OFCE/FNSP)1 Jacques Le in this debate by identifying what is essentially wrong with the economic provisions of the EUT, which we

Boyer, Edmond

99

E.U. environmental policies: a document - based qualitative research  

Science Journals Connector (OSTI)

Climate change has become a reality with many consequences in different fields. The European Union (EU) has been at the forefront of international action to combat climate change since 1990, when the UN Intergovernmental Panel on Climate Change's (IPCC) ... Keywords: EU policy, European legislation, climate change, environment, greenhouse gas emissions, qualitative research

Iuliana Pop; Madalina-Teodora Andrei; Charlotte Valentine Ene; Florin Vartolomei; Petronela-Sonia Nedea; Radita Alexe

2011-02-01T23:59:59.000Z

100

Japan rejects EU ITER deal 02 February 2005  

E-Print Network [OSTI]

News Japan rejects EU ITER deal 02 February 2005 An offer from the EU for Japan to drop its bid preferential issuance of orders to Japanese companies. Japan had previously proposed to issue about $Y57 authority to issue orders to Japanese firms and a distinct difference between the two proposals. Japan

Note: This page contains sample records for the topic "butyl ether eu" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

ITER: Japan to assign 20 percent of construction work to EU firms; Proposal for EU official to assume chief executive  

E-Print Network [OSTI]

ITER: Japan to assign 20 percent of construction work to EU firms; Proposal for EU official to assume chief executive position MAINICHI (Top Play) (Lead para.) December 7, 2004 Japan and the European Experimental Reactor (ITER). Japan yesterday revealed the details of a proposal to host the project. Tokyo has

102

Batch polymerization of styrene and isoprene by n-butyl lithium initiator  

E-Print Network [OSTI]

-20). Analysis of products consists of determining the point at which no free lithium alkyl remains. Thus if a butyl lithium initiated polymerization were terminated with water, butane would be evolved as long as the initiator were present. The butane...? agent were evaporated under a hood. Finally the polymer. was dried in a vacuum oven at about 50'C and under a vacuum of 30 inches of gg for about 30 hours. The weight of polymer formed was determined by final weighing. 25 The monomer conversion...

Hasan, Sayeed

1970-01-01T23:59:59.000Z

103

Isobaric vapor-liquid equilibria in the system methyl propanoate + n-butyl alcohol  

SciTech Connect (OSTI)

Isobaric vapor-liquid equilibria were determined at 74.66, 101.32, and 127.99 kPa for binary mixtures containing methyl propanoate + n-butyl alcohol by using a dynamic still with vapor and liquid circulation. No azeotrope was detected. The data were found to be thermodynamically consistent according to the point to point test. Application of the group-contribution models ASOG, UNIFAC, and modified UNIFAC to the activity coefficients at the three pressures studied gives average errors of less than 10%, 11%, and 3%, respectively.

Susial, P.; Ortega, J. (Univ. de Las Palmas de Gran Canaria, Canary Islands (Spain). Lab. de Termodinamica y Fisicoquimica)

1993-10-01T23:59:59.000Z

104

Russian energy in the EU market: Bolstered institutionsand their effects  

Science Journals Connector (OSTI)

Abstract The article examines institutional changes in EU–Russian energy relations since 2000. The article explores the ability of transformed institutions to limit the politicisation of energy and to reconcile the EU competitive-market approach with Russian state capitalism. More specifically, the article focuses on changes in intergovernmental, transgovernmental and transnational interactions. The article demonstrates that the gradual strengthening of transgovernmental and transnational institutions has inhibited the politicisation of energy relations and facilitated regulative cooperation between the EU and Russia. However, the potential of shared institutions is constrained by internal institutions on both sides. In Russia, these obstacles are insufficient top-down delegation of responsibilities in the government and its great power aspirations. In the EU, key barriers include inter-institutional rivalries, the EU’s propensity to impose its legislation on external partners and the integration of energy policy with foreign policy. The article presents several policy implications. First, it is futile to institutionally impose the regulative paradigm of one partner on the other; rather, mutual dialogue is needed. Thus, institutions should be structured appropriately. Second, current depoliticisation will require the involvement of not only the EU and Russia but also transit countries, such as Ukraine. Third, transgovernmental and transnational cooperation should be nurtured because this is a useful channel for both information exchange and a regulative convergence of policy implementing mechanisms. Finally, this incremental regulative convergence is the only option available today for the EU and Russia; this is also a way to further depoliticise energy relations.

Tatiana Romanova

2014-01-01T23:59:59.000Z

105

E-Print Network 3.0 - acid-labile cholesterol-vinyl ether-peg...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Crystallization of Recombinant Crithidia fasciculata Tryparedoxin Summary: of 30% polyethylene glycol monomethyl ether (PEG MME) 2000, 0.1 M TrisHCl, pH 8.2, 1% dimethyl Source:...

106

Polybrominated diphenyl ethers in combusted residues and soils from an open burning site of electronic wastes  

Science Journals Connector (OSTI)

Polybrominated diphenyl ethers (PBDEs) are ubiquitous environmental contaminants due to their extensive use. Combusted residue from electronic waste (e-waste) combustion is one of the contamination sources ... tr...

Qian Luo; Ming Hong Wong; Zijian Wang; Zongwei Cai

2013-08-01T23:59:59.000Z

107

Solvent Effects on Cesium Complexation with Crown Ethers from Liquid to Supercritical Fluids  

SciTech Connect (OSTI)

Nuclear magnetic resonance (NMR) techniques were used to study crown ether-water interactions in solvents of low dielectric constants such as chloroform and carbon tetrachloride. Water forms a 1:1 complex with a number of crown ethers including 12-crown-4, 15-crown-5, 18-crown-6, dicyclohexano-18=crown-6, dicyclohexano-24-crown 8, and dibenzl-24-crown-8 in chloroform. Among these crown ethers, the 18-crown-6-H2 complex has the largest equilibrium constant (K=545) and 97% of the crown is complexed to water in chloroform. Addition of carbon tetrachloride to chloroform lowers the equilibrium constants of the crown-water complexes. The partition coefficients of crown ethers (D=crown in water/crown in solvent) between water and organic solvent also vary with solvent composition.

Chien M. Wai; Anne Rustenholtz; Shaofen Wang; Su-Chen Lee; Jamie Herman; Richard A. Porter

2004-03-15T23:59:59.000Z

108

Atmospheric chemistry of automotive fuel additives: Diisopropyl ether  

SciTech Connect (OSTI)

To quantify the atmospheric reactivity of diisopropyl ether (DIPE), we have conducted a study of the kinetics and mechanism of reaction 1: OH + DIPE {r_arrow} products. Kinetic measurements of reaction 1 were made using both relative (at 295 K) and absolute techniques (over the temperature range 240-440 K). Rate data from both techniques can be represented by the following: k{sub 1} = (2.2{sub -0.8}{sup +14}) x 10{sup -12} exp[(445 {plus_minus} 145)/T] cm{sup 3} molecule{sup -1}s{sup -1}. At 298 K, k{sub 1} = 9.8 x 10{sup -12} cm{sup 3} molecule{sup -1}s{sup -1}. The products of the simulated atmospheric oxidation of DIPE were identified using FT-IR spectroscopy; isopropyl acetate and HCHO were the main products. The atmospheric oxidation of DIPE can be represented by i-C{sub 3}H{sub 7}O-i-C{sub 3}H{sub 7} + OH + 2NO {r_arrow} HCHO + i-C{sub 3}H{sub 7}OC(O)CH{sub 3} + HO{sub 2} + 2NO{sub 2}. Our kinetic and mechanistic data were incorporated into a 1-day simulation of atmospheric chemistry to quantify the relative incremental reactivity of DIPE. Results are compared with other oxygenated fuel additives. 30 refs., 9 figs.

Wallington, T.J.; Andino, J.M.; Potts, A.R. [Ford Motor Company, Dearborn, MI (United States)] [and others

1993-01-01T23:59:59.000Z

109

EU Energy Statistics 2010 (1990 - 2007) | OpenEI  

Open Energy Info (EERE)

43 43 Varnish cache server Browse Upload data GDR 429 Throttled (bot load) Error 429 Throttled (bot load) Throttled (bot load) Guru Meditation: XID: 2142278043 Varnish cache server EU Energy Statistics 2010 (1990 - 2007) Dataset Summary Description These two datasets include energy statistics for the European Union (EU). The statistics are available from the European Commission. The data includes detailed information about: production, net imports, gross inland consumption, and electricity generation for the EU as a whole, as well as the individual member countries, for the period between 1990 and 2007. Also included is annual gross electricity generation from renewables (hydro, pumped storage, wind, biomass, PV, and geothermal) for all EU member countries, 1990 - 2007.

110

Plug-in electric vehicle introduction in the EU  

E-Print Network [OSTI]

Plug-in electric vehicles (PEVs) could significantly reduce gasoline consumption and greenhouse gas (GHG) emissions in the EU's transport sector. However, PEV well-towheel (WTW) emissions depend on improvements in vehicle ...

Sisternes, Fernando J. de $q (Fernando José Sisternes Jiménez)

2010-01-01T23:59:59.000Z

111

Forschung und EU-Hochschulbro, Technologietransfer Februar 2012  

E-Print Network [OSTI]

, Safety and Radiation Protection ­ neuer Aufruf 9 2.9. Allgemeines zum 7. Forschungsrahmenprogramm 9 2: Reliably Secure Software Systems ­ RS3 (SPP 1496) 21 9. Ingenieurwissenschaften 21 9.1.1. EU: Intelligente

Nejdl, Wolfgang

112

Nonlinear viscoelastic response of carbon black-filled butyl rubber and implications for o-ring aging  

SciTech Connect (OSTI)

Butyl rubber, unfortunately, has pronounced nonlinear viscoelastic behavior, which may be modelled by a separable KBKZ formalism. While these effects seem to have minimal impact on accelerated sealing force measurements, they do severely impact compression set tests. Therefore, a new test is suggested for evaluating field-return o-rings which is free from such confounding effects.

Adolf, D.

1997-11-01T23:59:59.000Z

113

Rate dependent finite deformation stressstrain behavior of an ethylene methacrylic acid copolymer and an ethylene methacrylic acid butyl  

E-Print Network [OSTI]

Rate dependent finite deformation stress­strain behavior of an ethylene methacrylic acid copolymer and an ethylene methacrylic acid butyl acrylate copolymer S. Deschanel a,*, B.P. Greviskes a , K. Bertoldi a , S dependence a b s t r a c t The large strain deformation behaviors of an ethylene methacrylic acid (EMAA

114

Liquid phase oxidation of thiophene compounds by tert-butyl hydroperoxide  

SciTech Connect (OSTI)

Oxidative instability problems in both shale and petroleum-derived middle distillate fuels are related to the presence of hydroperoxides. Although a good body of knowledge exists concerning the formation of peroxides in the liquid phase, relatively little is known about the reaction/decomposition pathways when other functional groups are present. One of the significant and undesirable problems is the formation of solid deposits which can plug nozzles and filters and coal heat exchanger surfaces. Deposit formation in fuels is triggered by autoxidation reactions and is closely associated with elemental oxygen and/or hydroperoxide concentration. This paper reports on the reaction between a primary autoxidation product, a hydroperoxide, and sulfur compounds of the type present in petroleum-derived middle distillate fuels. Specifically, we examine the t-butyl hydroperoxide oxidation of thiophene, 2, 5-dimethylthiophene, tetrahydrothiophene and benzothiophene in a deaerated model fuel, tetradecane, at 120{degree}C.

Mushrush, G.W.; Watkins, J.M. Jr.; Hazlett, R.N.; Hardy, D.R.; Eaton, H.G. (Naval Research Laboratory, Washington, DC (USA))

1987-08-01T23:59:59.000Z

115

Fuel instability studies; Liquid phase oxidation of tetrahydrothiophene by tert-butyl hydroperoxide  

SciTech Connect (OSTI)

The reactions that lead to fuel instability are the subject of conflicting reports in the literature. Confusion results from the difficulty in relating differences in fuel composition, temperature, surface effects and dissolved oxygen content that comprise the multitude of reported studies. Model studies offer a means by chic the mechanism of an individual reaction can be related to a simple system and then extended to the more complex fuel media. This paper reports a model oxidation study of a species, t-butyl hydroperoxide under mild reaction conditions, 120{degrees}C, in a tetradecane model fuel. The major oxidation product was tetrahydrothiophene sulfoxide from the sulfide and t-butanol from the hydroperoxide. The complete suite of products is reported.

Mushrush, G.W.; Pellenbarg, R.E.; Hazlett, R.N.; Morris, R.E.; Hardy, D.R. (Fuels Section, Code 6180, Naval Research Lab., Washington, DC (US))

1991-01-01T23:59:59.000Z

116

Tests for mutagenic effects of ammoniated glycyrrhizin, butylated hydroxytoluene, and gum arabic in roden germ cells  

SciTech Connect (OSTI)

Ammoniated glycyrrhizin, butylated hydroxytoluene, and gum Arabic are generally recognized as safe (GRAS) substances that are used primarily as additives in foods. These substances were incorporated into rodent diets and fed to male rats and mice for 10 and 8 wk, respectively. The treated male mice and rats were then tested for dominant lethal effects. The mice were also tested for induced heritable translocation. Results of the rat studies indicated a statistically significant dominant lethal effect of each of the compounds tested; however, the biological significance of this response is not known. Results of the mouse dominant lethal and heritable translocation studies, on the other hand, indicated no adverse effects of the compounds tested.

Sheu, C.W.; Cain, K.T.; Rushbrook, C.J.; Jorgenson, T.A.; Generoso, W.M.

1986-01-01T23:59:59.000Z

117

Butyl rubber O-ring seals: Revision of test procedures for stockpile materials  

SciTech Connect (OSTI)

Extensive testing showed little correlation between test slab and O-ring performance. New procedures, comparable to those used with the traditional test slabs, were defined for hardness, compression set, and tensile property testing on sacrificial O-ring specimens. Changes in target performance values were made as needed and were, in one case, tightened to reflect the O-ring performance data. An additional study was carried out on O-ring and slab performance vs cure cycle and showed little sensitivity of material performance to large changes in curing time. Aging and spectra of certain materials indicated that two sets of test slabs from current vendor were accidently made from EPDM rather than butyl rubber. Random testing found no O-rings made from EPDM. As a result, and additional spectroscope test will be added to the product acceptance procedures to verify the type of rubber compound used.

Domeier, L.A.; Wagter, K.R.

1996-12-01T23:59:59.000Z

118

Initiation Temperature for Runaway Tri-n-Butyl Phosphate/Nitric Acid Reaction  

SciTech Connect (OSTI)

In a review of the safety basis for solvent extraction processes at the Department of Energy's Savannah River Site, a question was raised concerning the safety margin associated with a postulated accident involving a runaway tri-n-butyl phosphate (TBP)/nitric acid reaction due to the inadvertent heating of a tank. The safety margin was based on studies which showed the maximum temperature would not exceed 128 degrees Celsius compared to 130 degrees Celsius, the minimum initiation temperature for runaway reaction established in the 1950's following damaging incidents at the Savannah River and Hanford Sites. The reviewers were concerned the minimum temperature was not conservative since data for solutions containing 20 wt percent dissolved solids showed initiation temperatures at or below 130 degrees Celsius and process solutions normally contain some dissolved solids.

Rudisill, T.S.

2001-09-14T23:59:59.000Z

119

A thermodynamic model of nitric acid extraction by tri-n-butyl phosphate  

SciTech Connect (OSTI)

A thermodynamic model is presented for nitric acid extraction by tri-n-butyl phosphate (TBP). This model is based on the formation of the organic phase species: TBP.HNO/sub 3/ and (TBP)/sub 2/.HNO/sub 3/. The model works successfully at TBP concentrations of 5 to 100 vol% and was found to be effective at predicting the extraction of HNO/sub 3/ from HNO/sub 3//NaNO/sub 3/ and HNO/sub 3//LiNO/sub 3/ solutions. Within the TBP concentration range of 5 to 30%, a single set of extraction constants was sufficient to fit extraction data. Stoichiometric activity coefficients of nitric acid in HNO/sub 3//NaNO/sub 3/ and HNO/sub 3//LiNO/sub 3/ mixtures were calculated using a model developed by Bromley.

Chaiko, D.J.; Vandegrift, G.F.

1988-07-01T23:59:59.000Z

120

DIMETHYL ETHER (DME)-FUELED SHUTTLE BUS DEMONSTRATION PROJECT  

SciTech Connect (OSTI)

The objectives of this research and demonstration program are to convert a campus shuttle bus to operation on dimethyl ether, a potential ultra-clean alternative diesel fuel. To accomplish this objective, this project includes laboratory evaluation of a fuel conversion strategy, as well as, field demonstration of the DME-fueled shuttle bus. Since DME is a fuel with no lubricity (i.e., it does not possess the lubricating quality of diesel fuel), conventional fuel delivery and fuel injection systems are not compatible with dimethyl ether. Therefore, to operate a diesel engine on DME one must develop a fuel-tolerant injection system, or find a way to provide the necessary lubricity to the DME. In this project, they have chosen the latter strategy in order to achieve the objective with minimal need to modify the engine. Their strategy is to blend DME with diesel fuel, to obtain the necessary lubricity to protect the fuel injection system and to achieve low emissions. The bulk of the efforts over the past year were focused on the conversion of the campus shuttle bus. This process, started in August 2001, took until April 2002 to complete. The process culminated in an event to celebrate the launching of the shuttle bus on DME-diesel operation on April 19, 2002. The design of the system on the shuttle bus was patterned after the system developed in the engine laboratory, but also was subjected to a rigorous failure modes effects analysis (FMEA, referred to by Air Products as a ''HAZOP'' analysis) with help from Dr. James Hansel of Air Products. The result of this FMEA was the addition of layers of redundancy and over-pressure protection to the system on the shuttle bus. The system became operational in February 2002. Preliminary emissions tests and basic operation of the shuttle bus took place at the Pennsylvania Transportation Institute's test track facility near the University Park airport. After modification and optimization of the system on the bus, operation on the campus shuttle route began in early June 2002. However, the work and challenges continued as it has been difficult to maintain operability of the shuttle bus due to fuel and component difficulties. In late June 2002, the pump head itself developed operational problems (loss of smooth function) leading to excessive stress on the magnetic coupling and excessive current draw to operate. A new pump head was installed on the system to alleviate this problem and the shuttle bus operated successfully on DME blends from 10-25 vol% on the shuttle bus loop until September 30, 2002. During the period of operation on the campus loop, the bus was pulled from service, operated at the PTI test track and real-time emissions measurements were obtained using an on-board emissions analyzer from Clean Air Technologies International, Inc. Particulate emissions reductions of 60% and 80% were observed at DME blend ratios of 12 vol.% and 25 vol.%, respectively, as the bus was operated over the Orange County driving cycle. Increases in NOx, CO and HC emissions were observed, however. In summary, the conversion of the shuttle bus was successfully accomplished, particulate emissions reductions were observed, but there were operational challenges in the field. Nonetheless, they were able to demonstrate reliable operation of the shuttle bus on DME-diesel blends.

Elana M. Chapman; Shirish Bhide; Jennifer Stefanik; Howard Glunt; Andre L. Boehman; Allen Homan; David Klinikowski

2003-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "butyl ether eu" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Application of Spin-Wave Theory to EuS  

Science Journals Connector (OSTI)

Magnetization data for EuS powder in zero field and at liquid-helium temperatures has been obtained by nuclear magnetic resonance of both the Eu151 and Eu153 nuclei. These data are considered simultaneously with those for the specific heat of EuS powder obtained by McCollum and Callaway in order to provide a more definitive application of the spin-wave theory to this material. The theory is that given by Holstein and Primakoff and special attention is given to the effects of magnetic dipolar coupling on the spin-wave energy and moment. The calculation was carried out by summation over the exact Brillouin zone. Values of the nearest-neighbor exchange interaction J1 and second-neighbor exchange J2, as well as an effective field H which simultaneously produced reasonable agreement between calculation and experiment are J1=0.20±0.01°K, J2=-0.08?0.02°K and H=4.0±0.2 kOe. These values are fairly consistent with other parameters known for EuS.

S. H. Charap and E. L. Boyd

1964-02-03T23:59:59.000Z

122

Ab initio calculations of various protonation sites in perfluorodiethyl ether: Models for high temperature lubricant decomposition?  

SciTech Connect (OSTI)

Although perfluoropolyether (PFPE) lubricants have found successful application in spacecraft mechanisms and computer hard drives, there eventual breakdown is irksome, and the mechanism of decomposition is the subject of much scrutiny. However, very little notice is taken of the monomer ethers on which the polymer lubricants are based. Recently, concerted studies of the Lewis base properties of various fluorinated ethers have been performed, both from an experimental and a theoretical viewpoint. As an extension of the theoretical work, this study presents ab initio theoretical consideration of the multiple potential basic sites within perfluorodiethyl ether, (CF{sub 3}CF{sub 2}){sub 2}O, by way of the proton affinity of the molecule at various possible protonation sites (i.e., oxygen and fluorine atoms). The results indicate that although protonation at the oxygen is more energetically favored, protonation at the fluorine is not much higher in energy and provides for formation of an excellent leaving group, HF.

Ball, D.W. [Cleveland State Univ., OH (United States). Dept. of Chemistry

1995-04-01T23:59:59.000Z

123

Catalyst system and process for benzyl ether fragmentation and coal liquefaction  

DOE Patents [OSTI]

Dibenzyl ether can be readily cleaved to form primarily benzaldehyde and toluene as products, along with minor amounts of bibenzyl and benzyl benzoate, in the presence of a catalyst system comprising a Group 6 metal, preferably molybdenum, a salt, and an organic halide. Although useful synthetically for the cleavage of benzyl ethers, this cleavage also represents a key model reaction for the liquefaction of coal; thus this catalyst system and process should be useful in coal liquefaction with the advantage of operating at significantly lower temperatures and pressures.

Zoeller, Joseph Robert (Kingsport, TN)

1998-04-28T23:59:59.000Z

124

The Total Fatty Acids and Other Ether-Soluable Constituents of Feedstuffs.  

E-Print Network [OSTI]

586-914-10m TEXAS AGRICULTURAL EXPERIMENT STATION BULLETIN NO. 169 SEPTEMBER, 19I4 DIVISION OF CHEMISTRY The Total Fatty Acids and Other Ether-Soluble Constituents of Feedstuffs BY J. B. RATHER Assistant Chemist POSTOFFICE COLLEGE STATION... IS T .* In previous publications of this Experiment Station (Fraps and Bather, Bulletins Nos. 150 and 162) it has been shown that the un? saponifiable matter in the ether extract of hays and fodders averages about 58 per cent. Of the total extract, and is of much...

Rather, J. B. (James Burness)

1914-01-01T23:59:59.000Z

125

Toxicity of polychlorinated diphenyl ethers in Hydra attenuata and in rat whole embryo culture  

E-Print Network [OSTI]

TOXICITY OF POLYCHLORINATED DIPHENYL ETHERS IN HYDRA A?TENUATA AND IN RAT WHOLE EMBRYO CULTURE A Thesis by MARION CAROL BECKER Submitted to the Office of Graduate Studies of Texas A8cM University in partial fulfillment of the requirements... for the degree of MASTER OF SCIENCE May 1991 Major Subject: Toxicology TOXICITY OF POLYCHLORINATED DIPHENYL ETHERS IN HYDRA A1TENUATA AND IN RAT WHOLE EMBRYO CULTURE by MARION CAROL BECKER Approved as to style and content by: Stephen H. S (Ca...

Becker, Marion Carol

2012-06-07T23:59:59.000Z

126

Grid4EU (Smart Grid Project) (Italy) | Open Energy Information  

Open Energy Info (EERE)

Grid4EU (Smart Grid Project) (Italy) Grid4EU (Smart Grid Project) (Italy) Jump to: navigation, search Project Name Grid4EU Country Italy Coordinates 41.910454°, 12.65625° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":41.910454,"lon":12.65625,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

127

Ferromagnetic and Paramagnetic Resonance in EuS  

Science Journals Connector (OSTI)

Ferromagnetic and paramagnetic resonance has been observed in single crystals of EuS. A standard microwave spectrometer, operating near 22 Gc/sec, was used to measure the power absorption at 1.4 and 300°K. The resonance line width, 75 Oe at 1.4°K, was found to be approximately 1200 Oe at room temperature. An upper limit of 30 Oe has been established for the magnitude of the magnetocrystalline anisotropy field, in contrast to the value of - 190 Oe found for EuO. The paramagnetic line width is explained solely on the basis of spin-spin interactions. The anisotropy results are understood in terms of crystal-field perturbations of the magnetic Eu2+ ion.

S. von Molnar and A. W. Lawson

1965-08-30T23:59:59.000Z

128

Hydrolysis of cellulose to produce glucose with solid acid catalysts in 1-butyl-3-methyl-imidazolium chloride ([bmIm][Cl]) with sequential water addition  

Science Journals Connector (OSTI)

Selective glucose production by cellulose hydrolysis with initial or sequential water addition in the presence of solid acid catalysts in 1-butyl-3-methyl-imidazolium chloride ([bmIm][Cl]) under microwave irra...

Kaori Ishida; Shiho Matsuda; Masaru Watanabe…

2014-12-01T23:59:59.000Z

129

Optically induced magnetic polarons in EuTe  

SciTech Connect (OSTI)

Direct measurements of the photoinduced magnetization in EuTe, using a two color pump-and-probe technique, are presented. The photoinduced effect was pumped using photons of above-the-bandgap energy, and detected by the Faraday rotation of a probe beam of energy below-the-bandgap. The photoinduced Faraday rotation changes sign, as expected from our model for the optically induced magnetic polaron. The EuTe spin-flop transition at low fields is also detected as a sharp step in the photoinduced Faraday rotation, and its observation provides additional supports for the photoinduced polaron model.

Henriques, A. B.; Galgano, G. D. [Instituto de Física, Universidade de São Paulo, Caixa Postal 66318, 05315-970, São Paulo (Brazil); Abramof, E.; Rappl, P. H. O. [LAS - INPE, Av. Dos Astronautas, 1758, 12227-010, São José dos Campos (Brazil)

2013-12-04T23:59:59.000Z

130

Anhydrous aluminum chloride as an alkylation catalyst: identification of mono- and dialkyl-benzenes from the condensation of tertiary butyl alcohol with benzene.  

E-Print Network [OSTI]

LIBRARY a a w c"I. I. SI - O~ TI:YAf ANHYDROUS ALUMINUM CHLORIDE AS AN ALKYLATION CATALYST: IDENTIFICATION OF MONO- AND DIALKYIZENZENES FROM THE CONDENSATION QF TERTIARY BUTYL ALCOHOL WITH BENKENE IACEY EUGENE SCOGGINS 4 A Thesis Submitted...: IDENTIFICATION OF MONO- AND DI~NZZNES FROM THE CONDENSATION OF TERTIARY BUTYL ALCOHOL WITH BENZENE A Thesis By LACEY EUGENE SCOGGINS Approved as to style and content hy: Chairman of Committee Head of Chemistry Department 1959 ACKNOWLEDGME1VTS The author...

Scoggins, Lacey E

1959-01-01T23:59:59.000Z

131

Energy transfer in Eu3+ doped scheelites: use as thermographic phosphor  

Science Journals Connector (OSTI)

In this paper the luminescence of the scheelite-based CaGd2(1-x)Eu2x(WO4)4 solid solutions is investigated as a function of the Eu content...

Meert, Katrien W; Morozov, Vladimir A; Abakumov, Artem M; Hadermann, Joke; Poelman, Dirk; Smet, Philippe F

2014-01-01T23:59:59.000Z

132

Reforming the EU: The Future of European Law and Policy IV CONFERENCE PROGRAMME  

E-Print Network [OSTI]

Reforming the EU: The Future of European Law and Policy IV CONFERENCE session "Reforming the EU" Chair: Dr Luca Rubini, Deputy Director Institute Rubini Reforming European competition law: should the European Commission have

Birmingham, University of

133

Mission Impossible !? On the Harmonization of National Allocation Plans under the EU Emissions Trading Directive  

Science Journals Connector (OSTI)

Starting in 2005, the EU will implement a CO2 emissions trading scheme. We show that the outspoken objectives ... adjustments to the current prescriptions of the EU emissions trading system in order to achieve ha...

Christoph Böhringer; Andreas Lange

2005-01-01T23:59:59.000Z

134

The EU ETS: CO2 prices drivers during the learning experience (2005-2007)  

E-Print Network [OSTI]

Union Allowances (EUAs), valid for compliance under the European Union Emissions Trading Scheme (EU ETS of the European Union Emissions Trading Scheme (EU ETS) is to regulate CO2 emissions from the most energy

Paris-Sud XI, Université de

135

ANNUAL TRILATERAL U.S. - EU - JAPAN CONFERENCE ON CRITICAL MATERIALS...  

Broader source: Energy.gov (indexed) [DOE]

ANNUAL TRILATERAL U.S. - EU - JAPAN CONFERENCE ON CRITICAL MATERIALS FOR A CLEAN ENERGY FUTURE, SEPTEMBER 8-9, 2014 ANNUAL TRILATERAL U.S. - EU - JAPAN CONFERENCE ON CRITICAL...

136

The future role of renewable energy sources in European electricity supply : A model-based analysis for the EU-15.  

E-Print Network [OSTI]

??Ambitious targets for the use of renewable electricity (RES-E) have been formulated by the EU Commission and the EU Member States. Taking into account technical,… (more)

Rosen, Johannes

2008-01-01T23:59:59.000Z

137

Initiation Temperature for Runaway Tri-n-Butyl Phosphate/Nitric Acid Reaction  

SciTech Connect (OSTI)

During a review of the H-Canyon authorization basis, Defense Nuclear Facility Safety Board (DNFSB) staff members questioned the margin of safety associated with a postulated tri-n-butyl phosphate (TBP)/nitric acid runaway reaction due to the inadvertent heating of a canyon tank containing greater than 3000 lbs (1362 kg) of TBP. The margin of safety was partially based on experiments and calculations performed by the Actinide Technology Section (ATS) to support deletion of indication of tank agitation as a Safety Class System. In the technical basis for deletion of this system, ATS personnel conservatively calculated the equilibrium temperature distribution of a canyon tank containing TBP and nitric acid layers which were inadvertently heated by a steam jet left on following a transfer. The maximum calculated temperature (128 degrees C) was compared to the minimum initiation temperature for a runaway reaction (greater than 130 degrees C) documented by experimental work in the mid 195 0s. In this work, the initiation temperature as a function of nitric acid concentration was measured for 0 and 20 wt percent dissolved solids. The DNFSB staff members were concerned that data for 0 wt percent dissolved solids were not conservative given the facts that data for 20 wt percent dissolved solids show initiation temperatures at or below 130 degrees C and H-Canyon solutions normally contained a small amount of dissolved solids.

Rudisill, T.S.

2000-11-28T23:59:59.000Z

138

Thorium ions transport across Tri-n-butyl phosphate-benzene based supported liquid membranes  

SciTech Connect (OSTI)

Transport of Th(IV) ions across tri-n-butyl phosphate (TBP) benzene based liquid membranes supported in microporous hydrophobic polypropylene film (MHPF) has been studied. Various parameters such as variation of nitric acid concentration in the feed, TBP concentration in the membrane, and temperature on the given metal ions transport have been investigated. The effects of nitric acid and TBP concentrations on the distribution coefficient were also studied, and the data obtained were used to determine the Th ions-TBP complex diffusion coefficient in the membrane. Permeability coefficients of Th(IV) ions were also determined as a function of the TBP and nitric acid concentrations. The optimal conditions for the transport of Th(IV) ions across the membrane are 6 mol{sm_bullet}dm{sup -3} HNO{sub 3} concentration, 2.188 mol {center_dot} dm{sup -3} TBP concentration, and 25{degrees}C. The stoichiometry of the chemical species involved in chemical reaction during the transport of Th(IV) ions has also been studied.

Rasul, G.; Chaudry, M.A. [Pakistan Institute of Nuclear Chemistry, Islamabad (Pakistan); Afzal, M. [Quaid-I-Azam Univ., Islamabad (Pakistan)

1995-12-01T23:59:59.000Z

139

Transatlantic trade and investment partnership: sectoral and macroeconomic perspectives for Germany, the EU and the US  

Science Journals Connector (OSTI)

The EU and the US have started negotiations on a Transatlantic Trade and Investment Partnership Agreement (TTIP)...

Paul J. J. Welfens; Tony Irawan

2014-09-01T23:59:59.000Z

140

Dimethyl ether (DME) from coal as a household cooking fuel in China  

E-Print Network [OSTI]

technologies. Given China's rich coal resources, the production and use of coal-derived DME as a cooking fuelDimethyl ether (DME) from coal as a household cooking fuel in China Eric D. Larson Princeton gas (LPG) as a household cooking fuel. As such, DME is an attractive fuel for clean cooking. DME can

Note: This page contains sample records for the topic "butyl ether eu" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Nuclear magnetic relaxation dispersion investigations1 of water retention mechanism by cellulose ethers in mortars2  

E-Print Network [OSTI]

Nuclear magnetic relaxation dispersion investigations1 of water retention mechanism by cellulose : 10.1016/j.cemconres.2012.06.002 #12;2 ABSTRACT22 23 We show how nuclear magnetic spin-lattice relaxation dispersion of protons-water24 (NMRD) can be used to elucidate the effect of cellulose ethers

Boyer, Edmond

142

Copyright reform on the EU level European Network for Copyright in support of  

E-Print Network [OSTI]

a copyright reform on the EU level? Rainer Kuhlen University of Konstanz, HumboldtUniversity Berlin, IPR;Copyright reform on the EU level Extension of IPR in time Extension of IPR to living objects and other objects in nature Extension of IPR to software (still controversial, at least in the EU) Introduction

Kuhlen, Rainer

143

EU BIOFUEL USE AND AGRICULTURAL COMMODITY PRICES: A REVIEW OF THE EVIDENCE BASE  

E-Print Network [OSTI]

EU BIOFUEL USE AND AGRICULTURAL COMMODITY PRICES: A REVIEW OF THE EVIDENCE BASE Report prepared: Kretschmer, B, Bowyer, C and Buckwell, A (2012) EU Biofuel Use and Agricultural Commodity Prices: A Review............................................................................................................. 8 2 EU POLICY DRIVING BIOFUELS DEMAND AND OUTLOOK FOR THIS DEMAND TO 2020. 9 2.1 What is the current

144

Oxygen off-stoichiometry and phase separation in EuO thin films  

SciTech Connect (OSTI)

We report on our study on the influence of the growth conditions on the europium/oxygen stoichiometry, morphology, magnetic properties, and electrical conductivity of EuO thin films. SQUID magnetometry and x-ray photoelectron spectroscopy were utilized as complementary techniques to determine the oxygen content of EuO{sub 1{+-}x} thin films grown by molecular beam epitaxy with and without the employment of the so-called Eu distillation process. We found indications for phase separation to occur in Eu-rich as well as in over-oxidized EuO for films grown at substrate temperatures below the Eu distillation temperature. Only a fraction of the excess Eu contributes to the metal-insulator transition in Eu-rich films grown under these conditions. We also observed that the surfaces of these films were ill defined and may even contain more Eu excess than the film average. Only EuO films grown under distillation conditions are guaranteed to have the same magnetic and electrical properties as stoichiometric bulk EuO, and to have surfaces with the proper Eu/O stoichiometry and electronic structure.

Altendorf, S. G.; Efimenko, A.; Oliana, V. [II. Physikalisches Institut, Universitaet zu Koeln, Zuelpicher Str. 77, DE-50937 Koeln (Germany); Max Planck Institute for Chemical Physics of Solids, Noethnitzerstr. 40, DE-01187 Dresden (Germany); Kierspel, H. [II. Physikalisches Institut, Universitaet zu Koeln, Zuelpicher Str. 77, DE-50937 Koeln (Germany); Rata, A. D.; Tjeng, L. H. [Max Planck Institute for Chemical Physics of Solids, Noethnitzerstr. 40, DE-01187 Dresden (Germany)

2011-10-15T23:59:59.000Z

145

MERCOSUR-European Union Trade: How Important is EU Trade Liberalisation for MERCOSUR's  

E-Print Network [OSTI]

MERCOSUR-European Union Trade: How Important is EU Trade Liberalisation for MERCOSUR's Exports: + 34 - 964 - 72 86 16 1 #12;MERCOSUR-European Union Trade: How Important is EU Trade Liberalisation's exports' growth potential in a liberalised EU market. A sectoral study is considered indispensable since

Krivobokova, Tatyana

146

Sorption of Eu(III) on Attapulgite Studied by Batch, XPS and EXAFS Techniques  

E-Print Network [OSTI]

Sorption of Eu(III) on Attapulgite Studied by Batch, XPS and EXAFS Techniques Q.H. FAN,, , X.L. TANH, ionic strength and temperature on sorption of Eu(III) on attapulgite were investigated in the presence and absence of fulvic acid (FA) and humic acid (HA). The results indicated that the sorption of Eu

Boyer, Edmond

147

EU STRATEGY AGAINST PROLIFERATION OF WEAPONS OF MASS DESTRUCTION  

E-Print Network [OSTI]

EU STRATEGY AGAINST PROLIFERATION OF WEAPONS OF MASS DESTRUCTION At Thessaloniki, the European Council adopted a Declaration on non-proliferation of Weapons of Mass Destruction. Member States made. The proliferation of weapons of mass destruction and their means of delivery such as ballistic missiles

Sussex, University of

148

Past and Future EU Water Policy from a German Perspective  

E-Print Network [OSTI]

/271/EEC concerning urban waste-water treatment -> most expensive EEC-directive ever, but also veryPast and Future EU Water Policy from a German Perspective Dr. Fritz Holzwarth #12;Water Protection Community (EEC) with the focus on economic issues (reduction of trade barriers, free movement of goods

Wehrli, Bernhard

149

Investing in the EU Benelux as a Gateway  

E-Print Network [OSTI]

law - Starting points - The Intellectual Property types · Protection (registration) at the national Investing in the EU: Environmental aspects 3 1 · Introduction to Belgian regional environmental law International investment financing and Project finance 3 1 · Introduction: Origin, definition, why choose

Einmahl, Uwe

150

EU Enlargement and industrial relocation within the CEECs Matthieu Crozet  

E-Print Network [OSTI]

of economic activity in a country. The problematic lies in the context of the EU enlargement process and of its impact on the location of economic activity inside each of the accessing countries. We develop a new economic geography model based on the original Krugman (1991) model, and show that trade

Paris-Sud XI, Université de

151

EU in the Views of Asia-Pacific Elites  

E-Print Network [OSTI]

: a comparative study (www.europe.canterbury.ac.nz/ appp). Results of the first two stages of the project from the Atlantic Ocean to the Carpathian Mountains, the European Union (EU) is a new "giant political arena, a skilful international negotiator, a power with a `soft' touch, a model for international

Hickman, Mark

152

The influence of propylene glycol ethers on base diesel properties and emissions from a diesel engine  

Science Journals Connector (OSTI)

Abstract The oxygenated additives propylene glycol methyl ether (PGME), propylene glycol ethyl ether (PGEE), dipropylene glycol methyl ether (DPGME) were studied to determine their influence on both the base diesel fuel properties and the exhaust emissions from a diesel engine (CO, NOx, unburnt hydrocarbons and smoke). For diesel blends with low oxygen content (?4.0 wt.%), the addition of these compounds to base diesel fuel decreases aromatic content, kinematic viscosity, cold filter plugging point and Conradson carbon residue. Also, each compound modifies the distillation curve at temperatures below the corresponding oxygenated compound boiling point, the distillate percentage being increased. The blend cetane number depends on the type of propylene glycol ether added, its molecular weight, and the oxygen content of the fuel. The addition of PGME decreased slightly diesel fuel cetane number, while PGEE and DPGME increased it. Base diesel fuel-propylene glycol ether blends with 1.0 and 2.5 wt.% oxygen contents were used in order to determine the performance of the diesel engine and its emissions at both full and medium loads and different engine speeds (1000, 2500 and 4000 rpm). In general, at full load and in comparison with base diesel fuel, the blends show a slight reduction of oxygen-free specific fuel consumption. CO emissions are reduced appreciably for 2.5 wt.% of oxygen blends, mainly for PGEE and DPGME. \\{NOx\\} emissions are reduced slightly, but not the smoke. Unburnt hydrocarbon emissions decrease at 1000 and 2500 rpm, but not at 4000 rpm. At medium load, the effect of the additives is much less significant, due to the fact that the ratio oxygen from additive/oxygen from air is much lower.

F. Gómez-Cuenca; M. Gómez-Marín; M.B. Folgueras-Díaz

2013-01-01T23:59:59.000Z

153

Linking Low-Level Stable Isotope Fractionation to Expression of the Cytochrome P450 Monooxygenase-Encoding ethB Gene for Elucidation of Methyl tert-Butyl Ether Biodegradation in Aerated Treatment Pond Systems  

Science Journals Connector (OSTI)

...application of CSIA in field investigations to detect biodegradation...52). An alternative remedial strategy could be the use...application of CSIA in field investigations to detect biodegradation may lead to...application of CSIA in field investigations to detect biodegradation...

Sven Jechalke; Mònica Rosell; Paula M. Martínez-Lavanchy; Paola Pérez-Leiva; Thore Rohwerder; Carsten Vogt; Hans H. Richnow

2010-12-10T23:59:59.000Z

154

Single YVO4:Eu nanoparticle emission spectra using direct Eu3+ ion excitation with a sum-frequency 465-nm solid-state laser  

Science Journals Connector (OSTI)

We report emission spectrum measurements on single YxEu1-xVO4 nanoparticles. The inhomogeneous widths of the emission peaks are identical for single...

Nguyên, Thanh-Liêm; Castaing, Marc; Gacoin, Thierry; Boilot, Jean-Pierre; Balembois, François; Georges, Patrick; Alexandrou, Antigoni

2014-01-01T23:59:59.000Z

155

MTBE Production Economics (Released in the STEO April 2001)  

Reports and Publications (EIA)

The purpose of this analysis is to evaluate the causes of methyl tertiary butyl ether (MTBE) price increases in 2000.

2001-01-01T23:59:59.000Z

156

Metal valence states in Eu0.7NbO3, EuNbO3, and Eu2Nb5O9 by TB-LMTO-ASA band-structure calculations and resonant photoemission spectroscopy  

Science Journals Connector (OSTI)

The electronic structures of Eu2Nb5O9, EuNbO3, and Eu0.7NbO3 have been investigated by photoemission and total-yield spectroscopy with synchrotron radiation, and in the case of Eu2Nb5O9 by tight-binding linear muffin-tin orbital (LMTO) band-structure calculations. A central question for reduced europium niobates is that of the valence of Eu and Nb. Both europium and niobium atoms can appear in different valence states so that various electronic configurations in the title compounds are possible. For this reason, the valence band was studied by the resonant Eu 4d?4f technique to determine the Eu valence. The final-state 4f6 multiplet of divalent Eu is dominant in all spectra. Since there are no 4f density of states at the Fermi level, valence fluctuations are not expected. The niobium valence states were investigated by core-level spectroscopy. We found only one 3d5/23d3/2 doublet for the Nb 3d core level in EuNbO3 and Eu0.7NbO3, while in Eu2Nb5O9, two 3d doublets have been observed, corresponding to two chemically distinct niobium atoms in this compound. The 3d5/2 peak in EuNbO3 is assigned to the +4 nominal valence state at a binding energy of 209.7 eV. The doublet of Eu0.7NbO3 is observed at 0.5 eV higher binding energy (at 210.2 eV), which then corresponds to a nominal Nb+4+? chemical state. In Eu2Nb5O9, the valence of Nb in the NbO6 octahedra is less than +5 and in the Nb6O12 clusters is close to +2 as expected. This is in accordance with the LMTO band-structure calculations.

C. Felser; J. Köhler; A. Simon; O. Jepsen; G. Svensson; S. Cramm; W. Eberhardt

1998-01-15T23:59:59.000Z

157

Eu-doped Y2O3 nanosheets and nanotubes  

SciTech Connect (OSTI)

A hydrothermal method was used to synthesize Eu-doped Y2O3 nanosheets and nanotubes. High Resolution transmission electron microscopy (HRTEM) and synchrotron x-ray diffraction were used to characterize these nanomaterials. The nanosheets were obtained using a slightly lower pH value and they were partly crystalline and partly amorphous. Using a pH value of about 10, fully crystalline nanotubes were obtained. It is anticipated that nanosheets folded themselves to form stable nanotubes.

Sun, Hongtao [Texas Tech University, Lubbock; Chaudhari, Jharna [Texas Tech University, Lubbock; Kenik, Edward A [ORNL; Zhu, H [Texas Tech University, Lubbock; Ma, Y [Texas Tech University, Lubbock

2011-01-01T23:59:59.000Z

158

Pricing mechanisms for offshore wind electricity in EU member states  

Science Journals Connector (OSTI)

The aim of the study was to evaluate the pricing mechanisms for offshore wind electricity in those EU Member States (MS) possessing an important offshore wind resource and, on this basis, to determine the economic scenario faced by potential investors in the sector. The economic and energy policy framework of each MS was reviewed to establish the main factors determining the final price accorded to electricity generated from offshore wind, including feed-in tariffs, green certificates, subsidies, tax incentives and taking into consideration other factors such as costs and obligations related to grid connection and transmission. On the basis of the information collected, an economic analysis was conducted to compare offshore wind electricity prices across the EU, for a 20-year project duration, based on a year 2001 ''snapshot'' for a typical ''first generation'' offshore wind project. The policy review showed a variety of economic frameworks in existence across the EU, with some countries choosing fixed tariff schemes as the primary instrument and others using market-based systems such as green certificates. However, it was clear that several MS are moving away from the system based solely on fixed tariffs to incorporate more market-based schemes. The economic analysis showed that, on the basis of fixed tariffs and assuming uniform investment costs across EU waters, conditions are most favourable in Belgium (proposed legislation) and Germany. It is thought that, in future, market-oriented schemes and predictability tools will play an increasingly important role in determining the economic conditions faced by offshore wind electricity producers. It should be noted that the analyses presented in this paper are based on the economic and legislatory situations in existence at the time of writing, that is, December, 2001.

Geert Palmers; Suzanne Shaw

2002-01-01T23:59:59.000Z

159

Kinetics of liquid phase catalytic dehydration of methanol to dimethyl ether  

SciTech Connect (OSTI)

This paper reports the kinetics of the liquid phase catalytic dehydration of methanol to dimethyl ether investigated. The experiments were carried out under low concentrations of feed in a 1-L stirred autoclave, according to a statistical experimental design. The inert liquid phase used for this investigation was a 78:22 blend of paraffinic and naphthenic mineral oils. A complete thermodynamic analysis was carried out in order to determine the liquid phase concentrations of the dissolved species. A global kinetic model was developed for the rate of dimethyl ether synthesis in terms of the liquid phase concentration of methanol. The activation energy of the reaction was found to be 18,830 cal/gmol. Based on a step-wise linear regression analysis of the kinetic data, the order of the reaction which gave the best fit was 0.28 with respect to methanol.

Gogate, M.R.; Lee, B.G.; Lee, S. (Akron Univ., OH (USA). Dept. of Chemical Engineering); Kulik, C.J. (Electric Power Research Inst., Palo Alto, CA (USA))

1990-01-01T23:59:59.000Z

160

Process to convert biomass and refuse derived fuel to ethers and/or alcohols  

DOE Patents [OSTI]

A process is described for conversion of a feedstock selected from the group consisting of biomass and refuse derived fuel (RDF) to provide reformulated gasoline components comprising a substantial amount of materials selected from the group consisting of ethers, alcohols, or mixtures thereof, comprising: drying said feedstock; subjecting said dried feedstock to fast pyrolysis using a vortex reactor or other means; catalytically cracking vapors resulting from said pyrolysis using a zeolite catalyst; condensing any aromatic byproduct fraction; catalytically alkylating any benzene present in said vapors after condensation; catalytically oligomerizing any remaining ethylene and propylene to higher olefins; isomerizing said olefins to reactive iso-olefins; and catalytically reacting said iso-olefins with an alcohol to form ethers or with water to form alcohols. 35 figs.

Diebold, J.P.; Scahill, J.W.; Chum, H.L.; Evans, R.J.; Rejai, B.; Bain, R.L.; Overend, R.P.

1996-04-02T23:59:59.000Z

Note: This page contains sample records for the topic "butyl ether eu" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Process to convert biomass and refuse derived fuel to ethers and/or alcohols  

DOE Patents [OSTI]

A process for conversion of a feedstock selected from the group consisting of biomass and refuse derived fuel (RDF) to provide reformulated gasoline components comprising a substantial amount of materials selected from the group consisting of ethers, alcohols, or mixtures thereof, comprising: drying said feedstock; subjecting said dried feedstock to fast pyrolysis using a vortex reactor or other means; catalytically cracking vapors resulting from said pyrolysis using a zeolite catalyst; condensing any aromatic byproduct fraction; catalytically alkylating any benzene present in said vapors after condensation; catalytically oligomerizing any remaining ethylene and propylene to higher olefins; isomerizing said olefins to reactive iso-olefins; and catalytically reacting said iso-olefins with an alcohol to form ethers or with water to form alcohols.

Diebold, James P. (Lakewood, CO); Scahill, John W. (Evergreen, CO); Chum, Helena L. (Arvada, CO); Evans, Robert J. (Lakewood, CO); Rejai, Bahman (Lakewood, CO); Bain, Richard L. (Golden, CO); Overend, Ralph P. (Lakewood, CO)

1996-01-01T23:59:59.000Z

162

Soluble, Infrared-Absorbing Croconate Dyes from 2,6-Di-tert-butyl-4-methylchalcogenopyrylium Salts  

Science Journals Connector (OSTI)

1 Although many squarylium dyes have limited solubility in organic solvents or in coated organic films, squarylium dyes 1 (Chart 1) derived from 2,6-di-tert-butyl-4-methylchalcogenopyrylium salts (2)3 are soluble and have been coated in organic thin films for a variety of applications. ... The croconates are readily prepared, are soluble in organic solvents, and have absorption maxima that cover a broad range of laser emission lines from gallium?arsenide diode lasers (?820 nm) to the neodinium-YAG laser (1064 nm). ... The reaction mixture was poured into water (50 mL), and the product was extracted with hexanes (3 × 25 mL). ...

Todd P. Simard; Jian H. Yu; Jennifer M. Zebrowski-Young; Neil F. Haley; Michael R. Detty

2000-03-03T23:59:59.000Z

163

Radioactive contamination of SrI2(Eu) crystal scintillator  

E-Print Network [OSTI]

A strontium iodide crystal doped by europium (SrI2(Eu)) was produced by using the Stockbarger growth technique. The crystal was subjected to characterisation that included relative photoelectron output and energy resolution for gamma quanta. The intrinsic radioactivity of SrI2(Eu) crystal scintillator was tested both in scintillation mode and by using ultra-low background HPGe gamma spectrometry deep underground. The response of the SrI2(Eu) detector to alpha particles (alpha/beta ratio and pulse shape) was estimated by analysing the 226Ra trace contamination internal to the crystal. We have found alpha/beta=0.55 and no difference in scintillation decay for alpha particles and gamma quanta. The application of the obtained results in the search for the double electron capture and electron capture with positron emission in 84Sr has been investigated at a level of sensitivity T_1/2 \\sim 10^15-10^16 yr. The results of these studies demonstrate the potentiality of this material for a variety of scintillation appli...

Belli, P; Cerulli, R; Danevich, F A; Galenin, E; Gektin, A; Incicchitti, A; Isaienko, V; Kobychev, V V; Laubenstein, M; Nagorny, S S; Podviyanuk, R B; Tkachenko, S; Tretyak, V I

2011-01-01T23:59:59.000Z

164

Molecular modeling of the morphology and transport properties of two direct methanol fuel cell membranes: phenylated sulfonated poly(ether ether ketone ketone) versus Nafion  

SciTech Connect (OSTI)

We have used molecular dynamics simulations to examine membrane morphology and the transport of water, methanol and hydronium in phenylated sulfonated poly ether ether ketone ketone (Ph-SPEEKK) and Nafion membranes at 360 K for a range of hydration levels. At comparable hydration levels, the pore diameter is smaller, the sulfonate groups are more closely packed, the hydronium ions are more strongly bound to sulfonate groups, and the diffusion of water and hydronium is slower in Ph-SPEEKK relative to the corresponding properties in Nafion. The aromatic carbon backbone of Ph-SPEEKK is less hydrophobic than the fluorocarbon backbone of Nafion. Water network percolation occurs at a hydration level ({lambda}) of {approx}8 H{sub 2}O/SO{sub 3}{sup -}. At {lambda} = 20, water, methanol and hydronium diffusion coefficients were 1.4 x 10{sup -5}, 0.6 x 10{sup -5} and 0.2 x 10{sup -5} cm{sup 2}/s, respectively. The pore network in Ph-SPEEKK evolves dynamically and develops wide pores for {lambda} > 20, which leads to a jump in methanol crossover and ion transport. This study demonstrates the potential of aromatic membranes as low-cost challengers to Nafion for direct methanol fuel cell applications and the need to develop innovative strategies to combat methanol crossover at high hydration levels.

Devanathan, Ramaswami; Idupulapati, Nagesh B.; Dupuis, Michel

2012-08-14T23:59:59.000Z

165

2[prime] and 3[prime] Carboranyl uridines and their diethyl ether adducts  

DOE Patents [OSTI]

A process is described for preparing carboranyl uridine nucleoside compounds and their diethyl ether adducts, which exhibit a tenfold increase in boron content over prior art boron containing nucleoside compounds. The carboranyl uridine nucleoside compounds exhibit enhanced lipophilicity and hydrophilic properties adequate to enable solvation in aqueous media for subsequent incorporation of the compounds in methods for boron neutron capture therapy in mammalian tumor cells. No Drawings

Soloway, A.H.; Barth, R.F.; Anisuzzaman, A.K.; Alam, F.; Tjarks, W.

1992-12-15T23:59:59.000Z

166

Effect of solvents on the radiation-induced polymerization of ethyl and isopropyl vinyl ethers  

SciTech Connect (OSTI)

The effect of solvents on the radiation-induced cationic polymerization of ethyl and isopropyl vinyl ethers (EVE and IPVE, respectively) was investigated. EVE and IPVE polymerizations were carried out in bulk and in solution under superdry conditions in which polar impurities, especially water, have been reduced to negligible levels. This was accomplished by means of a sodium mirror technique using joint free baked out glass equipment and high vacuum. Plots of the monomer conversions and irradiation times were obtained for EVE and IPVE polymerizations in bulk and in benzene solution at constant monomer concentrations. The monomer concentration dependence of the polymerization rate was studied for EVE polymerization in bulk and in benzene, diethlyl ether, diglyme and methylene chloride, and for IPVE polymerization in bulk and in benzene. Solvent effect on the estimated propagating rate constants was examined for EVE and IPVE polymerization in bulk and in solution. The effect of temperature on the polymerization rate was also investigated for EVE polymerization in bulk ad in benzene, diethyl and diisopropyl ethers, methylene chloride and nitromethane, and for IPVE ploymerization in bulk and in benzene.

Hsieh, W.C.

1981-01-01T23:59:59.000Z

167

Eu{sub 3}F{sub 4}S{sub 2}: Synthesis, crystal structure, and magnetic properties of the mixed-valent europium(II,III) fluoride sulfide EuF{sub 2}.(EuFS){sub 2}  

SciTech Connect (OSTI)

Using the method to synthesize rare-earth metal(III) fluoride sulfides MFS (M=Y, La, Ce-Lu), in some cases we were able to obtain mixed-valent compounds such as Yb{sub 3}F{sub 4}S{sub 2} instead. With Eu{sub 3}F{sub 4}S{sub 2} another isotypic representative has now been synthesized. Eu{sub 3}F{sub 4}S{sub 2} (tetragonal, I4/mmm, a=400.34(2), c=1928.17(9) pm, Z=2) is obtained from the reaction of metallic europium, elemental sulfur, and europium trifluoride in a molar ratio of 5:6:4 within seven days at 850 deg. C in silica-jacketed gas-tightly sealed platinum ampoules. The single-phase product consists of black plate-shaped single crystals with a square cross section, which can be obtained from a flux using equimolar amounts of NaCl as fluxing agent. The crystal structure is best described as an intergrowth structure, in which one layer of CaF{sub 2}-type EuF{sub 2} is followed by two layers of PbFCl-type EuFS when sheeted parallel to the (001) plane. Accordingly there are two chemically and crystallographically different europium cations present. One of them (Eu{sup 2+}) is coordinated by eight fluoride anions in a cubic fashion, the other one (Eu{sup 3+}) exhibits a monocapped square antiprismatic coordination sphere with four F{sup -} and five S{sup 2-} anions. Although the structural ordering of the different charged europium cations is plausible, a certain amount of charge delocalization with some polaron activity has to take place, which is suggested by the black color of the title compound. Temperature dependent magnetic susceptibility measurements of Eu{sub 3}F{sub 4}S{sub 2} show Curie-Weiss behavior with an experimental magnetic moment of 8.19(5) mu{sub B} per formula unit and a paramagnetic Curie temperature of 0.3(2) K. No magnetic ordering is observed down to 4.2 K. In accordance with an ionic formula splitting like (Eu{sup II})(Eu{sup III}){sub 2}F{sub 4}S{sub 2} only one third of the europium centers in Eu{sub 3}F{sub 4}S{sub 2} carry permanent magnetic moments. {sup 151}Eu-Moessbauer spectroscopic experiments at 4.2 K show one signal at an isomer shift of -12.4(1) mm/s and a second one at 0.42(4) mm/s. These signals occur in a ratio of 1:2 and correspond to Eu{sup 2+} and Eu{sup 3+}, respectively. The spectra at 78 and 298 K are similar, thus no change in the Eu{sup 2+}/Eu{sup 3+} fraction can be detected. - Graphical abstract: Crystal structure and {sup 151}Eu-Moessbauer spectra of mixed-valent Eu{sub 3}F{sub 4}S{sub 2}.

Grossholz, Hagen; Hartenbach, Ingo [Institut fuer Anorganische Chemie, Universitaet Stuttgart, Pfaffenwaldring 55, 70569 Stuttgart (Germany); Kotzyba, Gunter [Institut fuer Anorganische und Analytische Chemie, Westfaelische Wilhelms-Universitaet Muenster, Corrensstrasse 30, 48149 Muenster (Germany); Poettgen, Rainer, E-mail: pottgen@uni-muenster.d [Institut fuer Anorganische und Analytische Chemie, Westfaelische Wilhelms-Universitaet Muenster, Corrensstrasse 30, 48149 Muenster (Germany); Trill, Henning; Mosel, Bernd D. [Institut fuer Physikalische Chemie, Westfaelische Wilhelms-Universitaet Muenster, Corrensstrasse 30, 48149 Muenster (Germany); Schleid, Thomas, E-mail: schleid@iac.uni-stuttgart.d [Institut fuer Anorganische Chemie, Universitaet Stuttgart, Pfaffenwaldring 55, 70569 Stuttgart (Germany)

2009-11-15T23:59:59.000Z

168

Argentina-EU-UNDP Low Emission Capacity Building Programme (LECBP) | Open  

Open Energy Info (EERE)

Argentina-EU-UNDP Low Emission Capacity Building Programme (LECBP) Argentina-EU-UNDP Low Emission Capacity Building Programme (LECBP) Jump to: navigation, search Name Argentina-EU-UNDP Low Emission Capacity Building Programme (LECBP) Agency/Company /Organization The European Union (EU), United Nations Development Programme (UNDP), German Federal Ministry for the Environment, Nature Conservation and Nuclear Safety (BMU), Australian Department of Climate Change and Energy Efficiency (DCCEE), Australian Agency for International Development (AusAID) Partner Secretariat of Environment and Sustainable Development (SESD), Secretariat of Industry Sector Climate, Energy Focus Area Renewable Energy, Non-renewable Energy, Agriculture, Buildings, Economic Development, Energy Efficiency, Greenhouse Gas, Industry, - Industrial Processes

169

Costa Rica-EU-UNDP Climate Change Capacity Building Program | Open Energy  

Open Energy Info (EERE)

Costa Rica-EU-UNDP Climate Change Capacity Building Program Costa Rica-EU-UNDP Climate Change Capacity Building Program Jump to: navigation, search Name Costa Rica-EU-UNDP Climate Change Capacity Building Program Agency/Company /Organization The European Union (EU), United Nations Development Programme (UNDP) Partner Multiple Ministries Sector Climate, Energy Focus Area Renewable Energy, Agriculture, Biomass, Buildings, Energy Efficiency, Forestry, Geothermal, Greenhouse Gas, Industry, Land Use, Offsets and Certificates, People and Policy, Solar, Transportation, Water Power, Wind Topics Background analysis, Baseline projection, Co-benefits assessment, - Energy Access, - Environmental and Biodiversity, GHG inventory, Implementation, Low emission development planning, -LEDS, -NAMA, -Roadmap, -TNA, Policies/deployment programs, Resource assessment

170

Privilegierte europäische Nachbarschaft mit der Ukraine als Instrument der externalisierten EU-Grenz- und Migrationspolitik.  

E-Print Network [OSTI]

??Diese Arbeit untersucht die externalisierte EU-Grenz- und Migrationspolitik in der Ukraine. In diesem Rahmen wird in einem ersten Teil versucht einen Überblick über internationale Migration… (more)

Diedrich, Sabrina

2014-01-01T23:59:59.000Z

171

Influence of Eu doping on the microstructure and photoluminescence of CdS nanocrystals  

Science Journals Connector (OSTI)

The CdS:Eu nanocrystals with a strong white emission have been synthesized by solvothemal method using ethylene glycol as solvents. From X-ray diffraction (XRD) and high resolution transmission electron microscopy (HRTEM) analysis it was observed that the average diameter of the CdS:Eu nanocrystals is about 5 nm. The traces of groups adsorbed on CdS:Eu nanocrystals were confirmed via FT-IR spectra. UV–visible spectroscopy study was carried out to determine the band gap of the nanocrystals and the absorbance peaks showed blue shift with respect to the bulk CdS. From photoluminescence (PL) studies at ?ex = 398 nm, the PL emission intensity of CdS:Eu nanocrystals enhanced by doping Eu3+ ions. In addition, the synthesis parameters including the concentration of doped Eu3+ ions, the reaction time, and the reaction temperature have influence on the optical properties of CdS:Eu nanocrystals. The charge compensation agent is a decisive factor for PL emission intensity of CdS:Eu nanocrystals. Furthermore, the storage time and condition on the fluorescence of CdS:Eu nanocrystals were also investigated.

Kexin Zhang; Yaxin Yu; Shuqing Sun

2012-01-01T23:59:59.000Z

172

Economic and social rights within EU-Russia relations: a missed opportunity?.  

E-Print Network [OSTI]

??In recent years the EU’s strategy towards promoting human rights in Russia has been the focus of considerable internal and external attention, much of it… (more)

Bindman, Eleanor Frances

2013-01-01T23:59:59.000Z

173

Optical and structural stability of blue SrO:Eu{sup 2+} phosphor  

SciTech Connect (OSTI)

Chemical stability of 6-coodinated SrO is a fundamental problem when this is used for various applications. In this study, optical and chemical stabilities of 8-coordinated SrO:Eu{sup 2+} phosphor were investigated. SrO:Eu{sup 2+} phosphor was synthesized from thermal treatment of SrO:Eu powder located on a single crystalline MgO at 1500° C under reduction atmosphere. Obtained 8-coordinated SrO:Eu{sup 2+} phosphor exhibit strong blue luminescence and chemical stability in distilled water for 3 days. Our findings prove that obtained 8-coordinated SrO:Eu{sup 2+} possesses relative optical and chemical stabilities in water. - Graphical abstract: Obtained 8-coordinated SrO:Eu{sup 2+} phosphor exhibit strong blue luminescence in distilled water. Highlights: • We investigated optical and chemical stabilities of 8-coordinated SrO:Eu{sup 2+} phosphor in water. • Obtained 8-coordinated SrO:Eu{sup 2+} phosphor exhibit strong blue luminescence and chemical stability in distilled water for 3 days. • We found that the 8-coodrodinated SrO crystal structure changed to SrCO{sub 3} crystal structure after the 5 days immersion. • The obtained SrO:Eu{sup 2+} phosphor possesses high chemical stability under water, compared with commercial (6-coordinated) SrO.

Komatsu, Keiji, E-mail: Keiji_Komatsu@mst.nagaokaut.ac.jp [Department of Material Science and Technology, Nagaoka University of Technology, 1603-1 Kamitomioka, Nagaoka, Niigata 940-2188 (Japan); Nakamura, Atsushi [Department of Material Science and Technology, Nagaoka University of Technology, 1603-1 Kamitomioka, Nagaoka, Niigata 940-2188 (Japan); Chubu Chelest Co. Ltd., 3-3-3 Hinagahigashi, Yokkaichi, Mie 510-0886 (Japan); Ohshio, Shigeo; Toda, Ikumi; Muramatsu, Hiroyuki; Saitoh, Hidetoshi [Department of Material Science and Technology, Nagaoka University of Technology, 1603-1 Kamitomioka, Nagaoka, Niigata 940-2188 (Japan)

2013-08-15T23:59:59.000Z

174

E-Print Network 3.0 - augu eu degvielu Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

doluptat... num dolortinit dolor sum nullaoreet vel dolobore dolore eugue vullan vullan eui blan velessit eu Source: MacMillan, Andrew - Department of Biochemistry, University of...

175

Sorption of Eu(III) on Attapulgite Studied by Batch, XPS and EXAFS Techniques  

E-Print Network [OSTI]

The effects of pH, ionic strength and temperature on sorption of Eu(III) on attapulgite were investigated in the presence and absence of fulvic acid (FA) and humic acid (HA). The results indicated that the sorption of Eu(III) on attapulgite was strongly dependent on pH and ionic strength, and independent of temperature. In the presence of FA/HA, Eu(III) sorption was enhanced at pH 7. The X-ray photoelectron spectroscopy (XPS) analysis suggested that the sorption of Eu(III) might be expressed as ?X3Eu0 ?SwOHEu3+ and ?SOEu-OOC-/HA in the ternary Eu/HA/attapulgite system. The extended X-ray absorption fine structure (EXAFS) analysis of Eu-HA complexes indicated that the distances of d(Eu-O) decreased from 2.451 to 2.360 {\\AA} with increasing pH from 1.76 to 9.50, whereas the coordination number (N) decreased from ~9.94 to ~8.56. Different complexation species were also found for the different addition sequences of HA and Eu(III) to attapulgite suspension. The results are important to understand the influence of...

Fan, Q H; Li, J X; Wang, X K; Wu, W S; Montavon, Gilles

2009-01-01T23:59:59.000Z

176

A laser and molecular beam mass spectrometer study of low-pressure dimethyl ether flames  

SciTech Connect (OSTI)

The oxidation of dimethyl ether (DME) is studied in low-pressure flames using new molecular beam mass spectrometer and laser diagnostics. Two 30.0-Torr, premixed DME/oxygen/argon flames are investigated with stoichiometries of 0.98 and 1.20. The height above burner profiles of nine stable species and two radicals are measured. These results are compared to the detailed chemical reaction mechanism of Curran and coworkers. Generally good agreement is found between the model and data. The largest discrepancies are found for the methyl radical profiles where the model predicts qualitatively different trends in the methyl concentration with stoichiometry than observed in the experiment.

Andrew McIlroy; Toby D. Hain; Hope A. Michelsen; Terrill A. Cool

2000-12-15T23:59:59.000Z

177

High octane ethers from synthesis gas-derived alcohols. Quarterly technical progress report, April--June 1993  

SciTech Connect (OSTI)

The results shown in Figures 10 and 11 demonstrate that the formation of butenes was very sensitive to the alcohol partial pressure. A small elevation of the alcohol pressure suppressed the formation of butenes rather drastically at both 90 and 117{degree}C. The synthesis rates of DME, MIBE, and MTBE ethers were not significantly affected at 90{degree}C, although there was a trend to increase the space time yield of DME as the alcohol pressure was increased. At the reaction temperature of 117{degree}C, all of the ethers showed increasing productivities as the pressure of the reactants was increased (Figure 11). An isotope labelling experiment was carried out to provide mechanistic insight into the manner in which methanol and isobutanol react together to form DME, MIBE, and MTBE ethers and to determine if MTBE were derived from MIBE.

Klier, K.; Herman, R.G.; Menszak, J.; Johansson, M.A.; Feeley, O.C.; Kim, D.

1993-07-01T23:59:59.000Z

178

ASTRONOMY TO INSPIRE AND EDUCATE YOUNG CHILDREN EU-UNAWE Lorentz Center Workshop  

E-Print Network [OSTI]

ASTRONOMY TO INSPIRE AND EDUCATE YOUNG CHILDREN EU-UNAWE Lorentz Center Workshop Official Opening. Mitchell, MEP, Chair, EU Parliamentary Committee on Development Astronomy Research and Education in South Committee for Education, Culture and Science Video messages (5 min) Astronomy and Space collaborations

Galis, Frietson

179

Call for expression of interest EU-Brazil Technology and Innovation Forum  

E-Print Network [OSTI]

for Brazilian SMEs, Technological Parks and other innovation actors for cooperation with Europe (Tour of BrazilCall for expression of interest EU-Brazil Technology and Innovation Forum Participation to B2B targeting research and innovation actors. Among them, this year the EU-Brazil Technology and Innovation

180

An EIE/Altener project Co-funded by the EU Commission  

E-Print Network [OSTI]

of Biogas for Electricity and Heat Production in EU countries. Economic and Environmental Benefits of Biogas is to assess the economic, environmental and energy aspects of the biogas production by centralised co-digestion in selected areas of six EU countries, which have been slow to implement biogas technology. The assessment

Note: This page contains sample records for the topic "butyl ether eu" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Re-dispersible Li+ and Eu3+ co-doped CdS nanoparticles: Luminescence studies  

Science Journals Connector (OSTI)

Re-dispersible CdS, 5 at.% Eu3+-doped CdS, 2 at.% Li+ and 5 at.% Eu3+ co-doped CdS nanoparticles in organic solvent are prepared by ... at a low temperature of 170°C. CdS nanoparticles have spherical shape with a...

N. S. Gajbhiye; Raghumani Singh Ningthoujam; Asar Ahmed; D. K. Panda…

2008-02-01T23:59:59.000Z

182

Political and Economic Integration in the EU: The Case of Failed Tax Harmonization*  

E-Print Network [OSTI]

Political and Economic Integration in the EU: The Case of Failed Tax Harmonization* FABIO. That there was only a limited transfer of tax authority to the EU exemplifies the failure of political and fiscal integration. Using a political economy framework, this article analyzes why the heads of state rejected tax

Wolfe, Patrick J.

183

STYRIAN ACADEMY for Sustainable Energies | http://styrianacademy.eu Graz University of Technology  

E-Print Network [OSTI]

STYRIAN ACADEMY for Sustainable Energies | http://styrianacademy.eu Graz University of Technology sustainable energy systems. The STYRIAN ACADEMY taps into the know how of top-class scientists and entrepreneurs from the European Sustainable Energy Innovation Alliance (eseia) (www.eseia.eu). The 2011 STYRIAN

184

Sourcing seafood for the three major markets: The EU, Japan and the USA Wilf Swartz n  

E-Print Network [OSTI]

Sourcing seafood for the three major markets: The EU, Japan and the USA Wilf Swartz n , U. Rashid Accepted 27 June 2010 Keywords: Seafood consumption Global fisheries International trade Sustainability a b's major seafood markets (the EU, Japan and the USA) using a series of global maps indicating the likely

Pauly, Daniel

185

Selective separation of Eu{sup 3+} using polymer-enhanced ultrafiltration  

SciTech Connect (OSTI)

A process to selectively remove {sup 241}Am from liquid radioactive waste was investigated as an actinide separation method applicable to Hanford and other waste sites. The experimental procedures involved removal of Eu, a nonradioactive surrogate for Am, from aqueous solutions at pH 5 using organic polymers in conjunction with ultrafiltration. Commercially available polyacrylic acid (60,000 MW) and Pacific Northwest Laboratory`s (PNL) synthesized E3 copolymer ({approximately}10,000 MW) were tested. Test solutions containing 10 {mu}g/mL of Eu were dosed vath each polymer at various concentrations in order to bind Eu (i.e., by complexation and/or cation exchange) for subsequent rejection by an ultrafiltration coupon. Test solutions were filtered with and without polymer to determine if enhanced Eu separation could be achieved from polymer treatment. Both polymers significantly increased Eu removal. Optimum concentrations were 20 {mu}g/mL of polyacrylic acid and 100 {mu}g/mL of E3 for 100% Eu rejection by the Amicon PM10 membrane at 55 psi. In addition to enhancement of removal, the polymers selectively bound Eu over Na, suggesting that selective separation of Eu was possible. This suggests that polymer-enhanced ultrafiltration is a potential process for separation of {sup 241}Am from Hanford tank waste, further investigation of binding agents and membranes effective under very alkaline and high ionic strength is warranted. This process also has potential applications for selective separation of toxic metals from industrial process streams.

Norton, M.V.

1994-03-01T23:59:59.000Z

186

Cross Border Trading and Borrowing in the EU ETS A. Denny Ellerman* and Raphael Trotignon**  

E-Print Network [OSTI]

multi- national trading system, the European Union's CO2 Emissions Trading Scheme (EU ETS) provides** This paper exploits a little used data resource within the central registry of the European Union's Emissions Trading System (EU ETS) to analyze cross border trading and inter-year borrowing during the first trading

187

-News Home Help EU to go it alone on nuclear project, if no deal with Japan  

E-Print Network [OSTI]

-News Home Help EU to go it alone on nuclear project, if no deal with Japan 1 hour, 30 minutes ago of a pioneering nuclear energy project in France if talks with Japan, which also wants to host the facility, fail by the EU commission, which is holding talks with the five other partners in the project -- China, Japan

188

Annex A -Potential threats in EU Organism(s) Means of spread Control measures Control approaches being used in  

E-Print Network [OSTI]

Annex A - Potential threats in EU Organism(s) Means of spread Control measures Control approaches options Potential threats in EU keep out, knowledge of trade routes, awareness on nurseries, foresters

189

Commercial-scale demonstration of the Liquid Phase Methanol (LPMEOH{trademark}) Process. Peroxide formation of dimethyl ether in methanol mixtures  

SciTech Connect (OSTI)

Organic peroxides could form when dimethyl ether in methanol is stored for three to six months at a time. The objective of this work was to determine the level of peroxide formation from dimethyl ether in reagent grade methanol and raw methanol at room temperature under 3 atmospheres (45 psig) of air. Raw methanol is methanol made from syngas by the LPMEOH Process without distillation. Aliphatic ethers tend to react slowly with oxygen from the air to form unstable peroxides. However, there are no reports on peroxide formation from dimethyl ether. After 172 days of testing, dimethyl ether in either reagent methanol or raw methanol at room temperature and under 60--70 psig pressure of air does not form detectable peroxides. Lack of detectable peroxides suggests that dimethyl ether or dimethyl ether and methanol may be stored at ambient conditions. Since the compositions of {approximately} 1.3 mol% or {approximately} 4.5 mol% dimethyl ether in methanol do not form peroxides, these compositions can be considered for diesel fuel or an atmospheric turbine fuel, respectively.

Waller, F.J.

1997-11-01T23:59:59.000Z

190

Flash photolysis resonance fluorescence investigation of the gas-phase reactions of hydroxyl radicals with cyclic ethers  

SciTech Connect (OSTI)

Absolute rate constants were measured for the gas-phase reactions of hydroxyl radicals with a series of dioxanes and other cyclic ethers by using the flash photolysis resonance fluorescence technique. Kinetic data for 1,3-dioxane and 1,4-dioxane, reactions 1 and 2, over the temperature range 240-440 K were used to derive the Arrhenius expressions. These results are compared to our earlier measurements for aliphatic ethers and are discussed in terms of reaction mechanisms and the prediction of reaction rates for such compounds from group reactivity values.

Dagaut, P.; Liu, R.; Wallington, T.J.; Kurylo, M.J. (National Institute of Standards and Technology, Gaithersburg, MD (USA))

1990-03-08T23:59:59.000Z

191

Calixarene crown ether solvent composition and use thereof for extraction of cesium from alkaline waste solutions  

DOE Patents [OSTI]

A solvent composition and corresponding method for extracting cesium (Cs) from aqueous neutral and alkaline solutions containing Cs and perhaps other competing metal ions is described. The method entails contacting an aqueous Cs-containing solution with a solvent consisting of a specific class of lipophilic calix[4]arene-crown ether extractants dissolved in a hydrocarbon-based diluent containing a specific class of alkyl-aromatic ether alcohols as modifiers. The cesium values are subsequently recovered from the extractant, and the solvent subsequently recycled, by contacting the Cs-containing organic solution with an aqueous stripping solution. This combined extraction and stripping method is especially useful as a process for removal of the radionuclide cesium-137 from highly alkaline waste solutions which are also very concentrated in sodium and potassium. No pre-treatment of the waste solution is necessary, and the cesium can be recovered using a safe and inexpensive stripping process using water, dilute (millimolar) acid solutions, or dilute (millimolar) salt solutions. An important application for this invention would be treatment of alkaline nuclear tank wastes. Alternatively, the invention could be applied to decontamination of acidic reprocessing wastes containing cesium-137.

Moyer, Bruce A. (Oak Ridge, TN); Sachleben, Richard A. (Knoxville, TN); Bonnesen, Peter V. (Knoxville, TN); Presley, Derek J. (Ooltewah, TN)

2001-01-01T23:59:59.000Z

192

The Role of Domestic Factors in the Formation of Trade Unions: A Look at Turkey/EU Relations  

E-Print Network [OSTI]

studied Turkey and the European Union (EU). Turkey was officially admitted as a candidate country to the EU in 1997. Despite efforts to meet EU demands, Turkey’s admittance has been blocked. As recently as 2007 Turkey was denied membership, while...

Youngblood, Kristina Lynne

2008-08-19T23:59:59.000Z

193

EcoGrid EU (Smart Grid Project) | Open Energy Information  

Open Energy Info (EERE)

(Smart Grid Project) (Smart Grid Project) Jump to: navigation, search Project Name EcoGrid EU Country Denmark Headquarters Location Bornholm, Denmark Coordinates 55.160427°, 14.866884° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":55.160427,"lon":14.866884,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

194

EU in the struggle for global governance: geopolitical ethics  

Science Journals Connector (OSTI)

This article argues in favour of a coherent and active European Union foreign policy based on the idea of 'geopolitical ethics'. In the first part of the article, the situation of the international system since 1990 is outlined. It seems that after the financial crisis of 2008 the world has lost its global governor - the USA - and thus plunged into a non-polar structure. The second part of the article will present the concept of 'geopolitical ethics'. Namely, analogical to the personalistic 'ethics of responsibility', in which an individual is the primary focus, 'geopolitical ethics' considers the nation as the constituent unit in the international system. In the final section, two case studies, both involving the internal (policy making) and external (policy implementation) dimensions of the EU's grand strategy - 'geopolitical ethics', are presented.

Igor Kovač

2014-01-01T23:59:59.000Z

195

Russia's perceptions and misperceptions of the EU Eastern Partnership  

Science Journals Connector (OSTI)

Abstract This article is devoted to the problem of the reaction to the Eastern Partnership by Russia's both the political establishment and the expert community. The question of reactions to the Eastern Partnership in the target countries has been extensively posed in academic literature. However, the question of Russia's reaction to the Eastern Partnership, one of the most important actors of the region, has been rarely raised by the academic community. A wide array of factors impacted Russian elites' perception of the Eastern Partnership – from problematic issues in the EU-Russia relations to the post-Soviet states' political and economic transformation. Studying the dynamics and peculiarities of Russia's perspective on the Eastern Partnership makes it possible to draw meaningful conclusions on the nature of Russia's phobias that fuel its domestic and foreign policy.

Igor Gretskiy; Evgeny Treshchenkov; Konstantin Golubev

2014-01-01T23:59:59.000Z

196

Assessment of sustainable development in the EU 27 using aggregated SD index  

Science Journals Connector (OSTI)

Abstract In the European Union the sustainable development is a fundamental and overarchingobjective enshrined in the Treaty and measuring progress towards sustainable development is an integral part of the EU Sustainable Development Strategy. Eurostat produce a monitoring report every two years based on the EU set of sustainable development indicators (SDIs). The main objective of this paper is to create an aggregated index of the sustainable development from EU set of \\{SDIs\\} for each 27 EU country based on the PCA. The headline indicator economic growth was not involved because its increase is not expressly followed by positive change in other \\{SDIs\\} from social, economic and environmental fields. The aggregated SD index enables to get an overall picture about the position of each of the 27 EU countries and its development in terms of the sustainability over time as assumed in the EU Sustainable Development Strategy. Sweden, Denmark, Netherland, and Great Britain have repeatedly reached the highest value of aggregated SD index. The highest positive change in the aggregated SD index has occurred in countries with the lowest value of aggregated SD index. Moreover, we put this new aggregated index in relation with economic growth and found that there is a negative correlation between aggregated SD index and the economic growth for most of the 27 EU countries.

Paula Bolcárová; Stanislav Kološta

2015-01-01T23:59:59.000Z

197

Title: Decomposition of ethanol and dimethyl-ether during CVD synthesis of single-walled carbon nanotubes  

E-Print Network [OSTI]

of ethanol and dimethyl-ether during CVD synthesis of single-walled carbon nanotubes Author list: Bo Hou (single-walled carbon nanotubes) was investigated. Gas-phase thermal decomposition of ethanol and DME ethanol and DME decomposition, confirming expected reaction trends and primary byproducts. Peak

Maruyama, Shigeo

198

Itinerant and local-moment magnetism in EuCr2As2 single crystals  

Science Journals Connector (OSTI)

We report on the crystal structure, physical properties, and electronic structure calculations for the ternary pnictide compound EuCr2As2. X-ray diffraction studies confirmed that EuCr2As2 crystalizes in the ThCr2Si2-type tetragonal structure (space group I4/mmm). The Eu ions are in a stable divalent state in this compound. Eu moments in EuCr2As2 order magnetically below Tm = 21 K. A sharp increase in the magnetic susceptibility below Tm and the positive value of the paramagnetic Curie temperature obtained from the Curie-Weiss fit suggest dominant ferromagnetic interactions. The heat capacity exhibits a sharp ?-shape anomaly at Tm, confirming the bulk nature of the magnetic transition. The extracted magnetic entropy at the magnetic transition temperature is consistent with the theoretical value Rln(2S+1) for S=7/2 of the Eu2+ ion. The temperature dependence of the electrical resistivity ?(T) shows metallic behavior along with an anomaly at 21 K. In addition, we observe a reasonably large negative magnetoresistance (??24%) at lower temperature. Electronic structure calculations for EuCr2As2 reveal a moderately high density of states of Cr-3d orbitals at the Fermi energy, indicating that the nonmagnetic state of Cr is unstable against magnetic order. Our density functional calculations for EuCr2As2 predict a G-type AFM order in the Cr sublattice. The electronic structure calculations suggest a weak interlayer coupling of the Eu moments.

U. B. Paramanik; R. Prasad; C. Geibel; Z. Hossain

2014-04-25T23:59:59.000Z

199

Environmental actions of agrochemicals 2. Histological effects of the herbicide/insecticide dinoseb-acetate (2-sec-butyl-4,6-dinitrophenyl acetate) on the spider miteTetranychus urticae (Acari: Tetranychidae) reared on herbicidetreatedPhaseolus vulgaris  

Science Journals Connector (OSTI)

The pure herbicidal compound dinoseb-acetate (2-sec-butyl-4,6-dinitrophenyl acetate) and its commercial formulation Aretit® were tested for their effects on the spider miteTetranychus urticae L. (Acari, Tetranych...

Ursula Mothes-Wagner; Harald K. Reitze…

1990-10-01T23:59:59.000Z

200

Phase diagram of EuI{sub 2}-KI binary system  

SciTech Connect (OSTI)

The phase diagram of the EuI{sub 2}-KI binary system was studied by differential thermal analysis (DTA) and X-ray powder diffraction (XRD). The phase diagram of the EuI{sub 2}-KI system shows the existence of one congruently melting compound, KEu{sub 2}I{sub 5}, and one incongruently melting compound, K{sub 4}EuI{sub 6}. There are two eutectic points located at 465 C, 20 mol% KI and 439 C, 60 mol% KI, respectively.

Sun, Y. [Beijing Normal Univ. (China). Dept. of Chemistry] [Beijing Normal Univ. (China). Dept. of Chemistry; [Univ. of Science and Technology, Beijing (China). Dept. of Physical Chemistry; Wang, S.; Wang, M. [Beijing Normal Univ. (China). Dept. of Chemistry] [Beijing Normal Univ. (China). Dept. of Chemistry; Qiao, Z. [Univ. of Science and Technology, Beijing (China). Dept. of Physical Chemistry] [Univ. of Science and Technology, Beijing (China). Dept. of Physical Chemistry

1998-02-15T23:59:59.000Z

Note: This page contains sample records for the topic "butyl ether eu" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Densities and isobaric vapor-liquid equilibria of butyl esters (methanoate to butanoate) with ethanol at 101.32 kPa  

SciTech Connect (OSTI)

Vapor-liquid equilibrium and densities at 101.32 kPa have been determined for the binary systems formed by four butyl esters (from methanoate to butanoate) with ethanol. The four systems exhibit positive deviations from ideal behavior, and all data (p-T-x-y) were found to be thermodynamically consistent. The activity coefficients and the dimensionless function G{sup E}/RT of the solution were correlated with its concentration by different equations. Am azeotrope was found in the mixture butyl methanoate (1) + ethanol (2) at T = 350.9 K and x{sub 1} = y{sub 1} = 0.088. The group contribution models ASOG and modified UNIFAC gave fair predictions.

Gonzalez, E.; Ortega, J. [Univ. of Las Palmas de Gran Canaria (Spain)

1995-11-01T23:59:59.000Z

202

Direct hydro-liquefaction of sawdust in petroleum ether and comprehensive bio-oil products analysis  

Science Journals Connector (OSTI)

Abstract The effect of temperature, time, hydrogen pressure and amount of catalyst on production distribution and the bio-oil yield obtained from the direct liquefaction of sawdust in the petroleum ether (60–90 °C) are investigated. The highest sawdust conversion obtained was 72.32% with a bio-oil yield of 47.69% were obtained at 370 °C, 40 min and 5wt.% catalyst content with the initial H2 pressure of 3.0 MPa. Fourier transform ion cyclotron resonance mass spectrometry (FTICR-MS) approach was utilized to analyze the non-volatile fraction. In this study, the composition of bio-oil could be analyzed in an unprecedented detail through a combination of GC–MS and FT-ICR MS techniques.

Dong Liu; Linhua Song; Pingping Wu; Yan Liu; Qingyin Li; Zifeng Yan

2014-01-01T23:59:59.000Z

203

Process for the production of ethylidene diacetate from dimethyl ether using a heterogeneous catalyst  

DOE Patents [OSTI]

This invention relates to a process for producing ethylidene diacetate by the reaction of dimethyl ether, acetic acid, hydrogen and carbon monoxide at elevated temperatures and pressures in the presence of an alkyl halide and a heterogeneous, bifunctional catalyst that is stable to hydrogenation and comprises an insoluble polymer having pendant quaternized heteroatoms, some of which heteroatoms are ionically bonded to anionic Group VIII metal complexes, the remainder of the heteroatoms being bonded to iodide. In contrast to prior art processes, no accelerator (promoter) is necessary to achieve the catalytic reaction and the products are easily separated from the catalyst by filtration. The catalyst can be recycled for 3 consecutive runs without loss in activity.

Ramprasad, D.; Waller, F.J.

1998-04-28T23:59:59.000Z

204

Use of aluminum phosphate as the dehydration catalyst in single step dimethyl ether process  

DOE Patents [OSTI]

The present invention pertains to a process for the coproduction of methanol and dimethyl ether (DME) directly from a synthesis gas in a single step (hereafter, the "single step DME process"). In this process, the synthesis gas comprising hydrogen and carbon oxides is contacted with a dual catalyst system comprising a physical mixture of a methanol synthesis catalyst and a methanol dehydration catalyst. The present invention is an improvement to this process for providing an active and stable catalyst system. The improvement comprises the use of an aluminum phosphate based catalyst as the methanol dehydration catalyst. Due to its moderate acidity, such a catalyst avoids the coke formation and catalyst interaction problems associated with the conventional dual catalyst systems taught for the single step DME process.

Peng, Xiang-Dong (Allentown, PA); Parris, Gene E. (Coopersburg, PA); Toseland, Bernard A. (Allentown, PA); Battavio, Paula J. (Allentown, PA)

1998-01-01T23:59:59.000Z

205

Process for the production of ethylidene diacetate from dimethyl ether using a heterogeneous catalyst  

DOE Patents [OSTI]

This invention relates to a process for producing ethylidene diacetate by the reaction of dimethyl ether, acetic acid, hydrogen and carbon monoxide at elevated temperatures and pressures in the presence of an alkyl halide and a heterogeneous, bifunctional catalyst that is stable to hydrogenation and comprises an insoluble polymer having pendant quaternized heteroatoms, some of which heteroatoms are ionically bonded to anionic Group VIII metal complexes, the remainder of the heteroatoms being bonded to iodide. In contrast to prior art processes, no accelerator (promoter) is necessary to achieve the catalytic reaction and the products are easily separated from the catalyst by filtration. The catalyst can be recycled for 3 consecutive runs without loss in activity.

Ramprasad, Dorai (Allentown, PA); Waller, Francis Joseph (Allentown, PA)

1998-01-01T23:59:59.000Z

206

Using Heteropolyacids in the Anode Catalyst Layer of Dimethyl Ether PEM Fuel Cells  

SciTech Connect (OSTI)

In this study, polarization experiments were performed on a direct dimethyl ether fuel cell (DMEFC). The experimental setup allowed for independent control of water and DME flow rates. Thus the DME flow rate, backpressure, and water flow rate were optimized. Three heteropoly acids, phosphomolybdic acid (PMA), phosphotungstic acid (PTA), and silicotungstic acid (STA) were incorporated into the anode catalyst layer in combination with Pt/C. Both PTA-Pt and STA-Pt showed higher performance than the Pt control at 30 psig of backpressure. Anodic polarizations were also performed, and Tafel slopes were extracted from the data. The trends in the Tafel slope values are in agreement with the polarization data. The addition of phosphotungstic acid more than doubled the power density of the fuel cell, compared to the Pt control.

Ferrell III, J. R.; Turner, J. A.; Herring, A. M.

2008-01-01T23:59:59.000Z

207

Use of ferric sulfate: acid media for the desulfurization of model compounds of coal. [Dibenzothiophene, diphenyl sulfide, di-n-butyl sulfide  

SciTech Connect (OSTI)

The objective of this work has been to investigate the ability of ferric sulfate-acid leach systems to oxidize the sulfur in model compounds of coal. Ferric iron-acid leach systems have been shown to be quite effective at removal of inorganic sulfur in coal. In this study, the oxidative effect of ferric iron in acid-leach systems was studied using dibenzothiophene, diphenyl sulfide, and di-n-butyl sulfide as models of organic sulfur groups in coal. Nitrogen and oxygen, as well as various transition metal catalysts and oxidants, were utilized in this investigation. Dibenzothiophene was found to be quite refractory to oxidation, except in the case where metavanadate was added, where it appears that 40% oxidation to sulfone could have occurred per hour at 150/sup 0/C and mild oxygen pressure. Diphenyl sulfide was selectively oxidized to sulfoxide and sulfone in an iron and oxygen system. Approximately 15% conversion to sulfone occurred per hour under these conditions. Some of the di-n-butyl sulfide was cracked to 1-butene and 1-butanethiol under similar conditions. Zinc chloride and ferric iron were used at 200/sup 0/C in an attempt to desulfonate dibenzothiophene sulfone, diphenyl sulfone, and di-n-butyl sulfone. Di-n-butyl sulfone was completely desulfurized on one hour and fragmented to oxidized parafins, while dibenzothiophene sulfone and diphenyl sulfone were unaffected. These results suggest that an iron-acid leach process could only selectively oxidize aryl sulfides under mild conditions, representing only 20% of the organic sulfur in coal (8% of the total sulfur). Removal through desulfonation once selective sulfur oxidation had occurred was only demonstrated for alkyl sulfones, with severe oxidation of the fragmented paraffins also occurring in one hour.

Clary, L.R.; Vermeulen, T.; Lynn, S.

1980-12-01T23:59:59.000Z

208

Identification of volatile butyl rubber thermal-oxidative degradation products by cryofocusing gas chromatography/mass spectrometry (cryo-GC/MS).  

SciTech Connect (OSTI)

Chemical structure and physical properties of materials, such as polymers, can be altered as aging progresses, which may result in a material that is ineffective for its envisioned intent. Butyl rubber formulations, starting material, and additives were aged under thermal-oxidative conditions for up to 413 total days at up to 124 %C2%B0C. Samples included: two formulations developed at Kansas City Plant (KCP) (%236 and %2310), one commercially available formulation (%2321), Laxness bromobutyl 2030 starting material, and two additives (polyethylene AC-617 and Vanax MBM). The low-molecular weight volatile thermal-oxidative degradation products that collected in the headspace over the samples were preconcentrated, separated, and detected using cryofocusing gas chromatography mass spectrometry (cryo-GC/MS). The majority of identified degradation species were alkanes, alkenes, alcohols, ketones, and aldehydes. Observations for Butyl %2310 aged in an oxygen-18 enriched atmosphere (18O2) were used to verify when the source of oxygen in the applicable degradation products was from the gaseous environment rather than the polymeric mixture. For comparison purposes, Butyl %2310 was also aged under non-oxidative thermal conditions using an argon atmosphere.

Smith, Jonell Nicole; White, Michael Irvin; Bernstein, Robert; Hochrein, James Michael

2013-02-01T23:59:59.000Z

209

Site and local structure of activator Eu{sup 2+} in phosphor Ca{sub 10?x}(PO{sub 4}){sub 6}Cl{sub 2}:xEu{sup 2+}  

SciTech Connect (OSTI)

The site and local structure of activator Eu{sup 2+} in phosphor Ca{sub 10?x}(PO{sub 4}){sub 6}Cl{sub 2}:xEu{sup 2+} is investigated by experiment measurements, first-principle calculations and XAFS simulations. From first-principle calculations, the “local” structure [bond length L(M–O)?R(M{sup 2+})+R(O{sup 2?})] of host shows a significant deformation (expansion) when Ca{sup 2+} is substituted by Eu{sup 2+}, and Eu{sup 2+} should prefer 6h site to 4f site in the host. The d?f emission of Eu{sup 2+} at 4f site should show a longer wavelength than that of Eu{sup 2+} at 6h site. The XAFS measurement and simulations suggest that the Eu{sup 2+} in our Ca{sub 9.9}(PO{sub 4}){sub 6}Cl{sub 2}:0.1Eu{sup 2+} sample mainly locates at 6h site. In the emission spectrum, two emission profiles of Ca{sub 9.9}(PO{sub 4}){sub 6}Cl{sub 2}:0.1Eu{sup 2+} sample are obtained and assigned. The major one (2.71 eV?456 nm) should be the emission of Eu{sup 2+} at 6h site. The minor one (2.61 eV?465 nm) should be that of Eu{sup 2+} at 4f site. - Graphical abstract: The d?f emission of Eu{sup 2+} in Ca{sub 9.9}(PO{sub 4}){sub 6}Cl{sub 2}:0.1Eu{sup 2+} can be assigned as: emission profile at 2.71 eV and 2.61 eV are Eu{sup 2+} at 6h and 4f site, respectively. Display Omitted - Highlights: • Eu{sup 2+} in Ca{sub 10?x}(PO{sub 4}){sub 6}Cl{sub 2}:xEu{sup 2+} causes deformation to “local” structure. • Eu{sup 2+} should prefer 6h site to 4f site in the host from energy aspect. • Emission at 2.71 eV and 2.61 eV should be Eu{sup 2+} at 6h and 4f site.

Wang, Chun-Hai, E-mail: chwang81@gmail.com [National Key Laboratory of Shock Wave and Detonation Physics, Institute of Fluid Physics, Mianyang 621900 (China); Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (China); School of Physics, Peking University, Beijing 100871 (China); Gui, Dong-Yun; Qin, Rui [National Key Laboratory of Shock Wave and Detonation Physics, Institute of Fluid Physics, Mianyang 621900 (China); Yang, Feng-Li [Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (China); Jing, Xi-Ping, E-mail: xpjing@pku.edu.cn [Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (China); Tian, Guang-Shan [School of Physics, Peking University, Beijing 100871 (China); Zhu, Wenjun [National Key Laboratory of Shock Wave and Detonation Physics, Institute of Fluid Physics, Mianyang 621900 (China)

2013-10-15T23:59:59.000Z

210

Bhutan-EU-UNDP Low Emission Capacity Building Programme (LECBP) | Open  

Open Energy Info (EERE)

Bhutan-EU-UNDP Low Emission Capacity Building Programme (LECBP) Bhutan-EU-UNDP Low Emission Capacity Building Programme (LECBP) Jump to: navigation, search Name Bhutan-EU-UNDP Low Emission Capacity Building Programme (LECBP) Agency/Company /Organization The European Union (EU), United Nations Development Programme (UNDP), German Federal Ministry for the Environment, Nature Conservation and Nuclear Safety (BMU), Australian Department of Climate Change and Energy Efficiency (DCCEE), Australian Agency for International Development (AusAID) Partner Multiple Ministries Sector Climate Focus Area Renewable Energy, Non-renewable Energy, Agriculture, Biomass, Buildings, Economic Development, Energy Efficiency, Forestry, Geothermal, Goods and Materials, Greenhouse Gas, Industry, Land Use, Offsets and Certificates, People and Policy, Solar, Transportation, Water Power, Wind

211

Tanzania-EU-UNDP Low Emission Capacity Building Programme (LECBP) | Open  

Open Energy Info (EERE)

Tanzania-EU-UNDP Low Emission Capacity Building Programme (LECBP) Tanzania-EU-UNDP Low Emission Capacity Building Programme (LECBP) Jump to: navigation, search Name Tanzania-EU-UNDP Low Emission Capacity Building Programme (LECBP) Agency/Company /Organization The European Union (EU), United Nations Development Programme (UNDP), German Federal Ministry for the Environment, Nature Conservation and Nuclear Safety (BMU), Australian Department of Climate Change and Energy Efficiency (DCCEE), Australian Agency for International Development (AusAID) Partner Multiple Ministries Sector Climate Focus Area Renewable Energy, Non-renewable Energy, Agriculture, Biomass, Buildings, Economic Development, Energy Efficiency, Forestry, Geothermal, Goods and Materials, Greenhouse Gas, Industry, Land Use, Offsets and Certificates, People and Policy, Solar, Transportation, Water Power, Wind

212

Vietnam-EU-UNDP Low Emission Capacity Building Programme (LECBP) | Open  

Open Energy Info (EERE)

Vietnam-EU-UNDP Low Emission Capacity Building Programme (LECBP) Vietnam-EU-UNDP Low Emission Capacity Building Programme (LECBP) Jump to: navigation, search Name Vietnam-EU-UNDP Low Emission Capacity Building Programme (LECBP) Agency/Company /Organization The European Union (EU), United Nations Development Programme (UNDP), German Federal Ministry for the Environment, Nature Conservation and Nuclear Safety (BMU), Australian Department of Climate Change and Energy Efficiency (DCCEE), Australian Agency for International Development (AusAID) Partner Multiple Ministries Sector Climate Focus Area Renewable Energy, Non-renewable Energy, Agriculture, Biomass, Buildings, Economic Development, Energy Efficiency, Forestry, Geothermal, Goods and Materials, Greenhouse Gas, Industry, Land Use, Offsets and Certificates, People and Policy, Solar, Transportation, Water Power, Wind

213

Chile-EU-UNDP Low Emission Capacity Building Programme (LECBP) | Open  

Open Energy Info (EERE)

Chile-EU-UNDP Low Emission Capacity Building Programme (LECBP) Chile-EU-UNDP Low Emission Capacity Building Programme (LECBP) Jump to: navigation, search Name Chile-EU-UNDP Low Emission Capacity Building Programme (LECBP) Agency/Company /Organization The European Union (EU), United Nations Development Programme (UNDP), German Federal Ministry for the Environment, Nature Conservation and Nuclear Safety (BMU), Australian Department of Climate Change and Energy Efficiency (DCCEE), Australian Agency for International Development (AusAID) Partner Multiple Ministries Sector Climate Focus Area Renewable Energy, Non-renewable Energy, Agriculture, Biomass, Buildings, Economic Development, Energy Efficiency, Forestry, Geothermal, Goods and Materials, Greenhouse Gas, Industry, Land Use, Offsets and Certificates, People and Policy, Solar, Transportation, Water Power, Wind

214

U.S. and EU Unite to Strengthen Economic Integration and Boost Jobs, Growth  

Broader source: Energy.gov (indexed) [DOE]

EU Unite to Strengthen Economic Integration and Boost EU Unite to Strengthen Economic Integration and Boost Jobs, Growth and Competitiveness U.S. and EU Unite to Strengthen Economic Integration and Boost Jobs, Growth and Competitiveness November 9, 2006 - 9:25am Addthis WASHINGTON, DC - Today, the Bush Administration hosted the second informal U.S.-EU economic ministerial meeting to discuss transatlantic economic integration and shared economic challenges. Commerce Secretary Carlos M. Gutierrez and Energy Secretary Samuel W. Bodman met with European Union Commission Vice President Günter Verheugen and Finnish Minister for Trade and Industry Mauri Pekkarinen to review joint progress in the most significant areas of the transatlantic economy, including innovation, intellectual property rights (IPR), regulatory cooperation, and energy

215

Philippines-EU-UNDP Low Emission Capacity Building Programme (LECBP) | Open  

Open Energy Info (EERE)

Philippines-EU-UNDP Low Emission Capacity Building Programme (LECBP) Philippines-EU-UNDP Low Emission Capacity Building Programme (LECBP) Jump to: navigation, search Name Philippines-EU-UNDP Low Emission Capacity Building Programme (LECBP) Agency/Company /Organization The European Union (EU), United Nations Development Programme (UNDP), German Federal Ministry for the Environment, Nature Conservation and Nuclear Safety (BMU), Australian Department of Climate Change and Energy Efficiency (DCCEE), Australian Agency for International Development (AusAID) Partner Multiple Ministries Sector Climate Focus Area Renewable Energy, Non-renewable Energy, Agriculture, Biomass, Buildings, Economic Development, Energy Efficiency, Forestry, Geothermal, Goods and Materials, Greenhouse Gas, Industry, Land Use, Offsets and Certificates, People and Policy, Solar, Transportation, Water Power, Wind

216

EU-UNDP Low Emission Capacity Building Programme (LECBP) | Open Energy  

Open Energy Info (EERE)

EU-UNDP Low Emission Capacity Building Programme (LECBP) EU-UNDP Low Emission Capacity Building Programme (LECBP) (Redirected from UNDP/EC-China-Climate Change Capacity Building Program) Jump to: navigation, search Name EU-UNDP Low Emission Capacity Building Programme (LECBP) Agency/Company /Organization The European Union (EU), United Nations Development Programme (UNDP), German Federal Ministry for the Environment, Nature Conservation and Nuclear Safety (BMU), Australian Department of Climate Change and Energy Efficiency (DCCEE), Australian Agency for International Development (AusAID) Partner Multiple Ministries Sector Climate Focus Area Renewable Energy, Non-renewable Energy, Agriculture, Biomass, Buildings, Economic Development, Energy Efficiency, Forestry, Geothermal, Goods and Materials, Greenhouse Gas, Industry, Land Use, Offsets and Certificates, People and Policy, Solar, Transportation, Water Power, Wind

217

Democratic Republic of Congo-EU-UNDP Climate Change Capacity Building  

Open Energy Info (EERE)

Democratic Republic of Congo-EU-UNDP Climate Change Capacity Building Democratic Republic of Congo-EU-UNDP Climate Change Capacity Building Program Jump to: navigation, search Name Democratic Republic of Congo-EU-UNDP Climate Change Capacity Building Program Agency/Company /Organization The European Union (EU), United Nations Development Programme (UNDP) Partner Multiple Ministries Sector Climate, Energy Focus Area Renewable Energy, Agriculture, Biomass, Buildings, Energy Efficiency, Forestry, Geothermal, Greenhouse Gas, Industry, Land Use, Offsets and Certificates, People and Policy, Solar, Transportation, Water Power, Wind Topics Background analysis, Baseline projection, Co-benefits assessment, - Energy Access, - Environmental and Biodiversity, GHG inventory, Implementation, Low emission development planning, -LEDS, -NAMA, -Roadmap, -TNA, Policies/deployment programs, Resource assessment

218

Ecuador-EU-UNDP Low Emission Capacity Building Programme (LECBP) | Open  

Open Energy Info (EERE)

Ecuador-EU-UNDP Low Emission Capacity Building Programme (LECBP) Ecuador-EU-UNDP Low Emission Capacity Building Programme (LECBP) Jump to: navigation, search Name Ecuador-EU-UNDP Low Emission Capacity Building Programme (LECBP) Agency/Company /Organization The European Union (EU), United Nations Development Programme (UNDP), German Federal Ministry for the Environment, Nature Conservation and Nuclear Safety (BMU), Australian Department of Climate Change and Energy Efficiency (DCCEE), Australian Agency for International Development (AusAID) Partner Multiple Ministries Sector Climate Focus Area Renewable Energy, Non-renewable Energy, Agriculture, Biomass, Buildings, Economic Development, Energy Efficiency, Forestry, Geothermal, Goods and Materials, Greenhouse Gas, Industry, Land Use, Offsets and Certificates, People and Policy, Solar, Transportation, Water Power, Wind

219

Egypt-EU-UNDP Low Emission Capacity Building Programme (LECBP) | Open  

Open Energy Info (EERE)

Egypt-EU-UNDP Low Emission Capacity Building Programme (LECBP) Egypt-EU-UNDP Low Emission Capacity Building Programme (LECBP) Jump to: navigation, search Name Egypt-EU-UNDP Low Emission Capacity Building Programme (LECBP) Agency/Company /Organization The European Union (EU), United Nations Development Programme (UNDP), German Federal Ministry for the Environment, Nature Conservation and Nuclear Safety (BMU), Australian Department of Climate Change and Energy Efficiency (DCCEE), Australian Agency for International Development (AusAID) Partner Multiple Ministries Sector Climate Focus Area Renewable Energy, Non-renewable Energy, Agriculture, Biomass, Buildings, Economic Development, Energy Efficiency, Forestry, Geothermal, Goods and Materials, Greenhouse Gas, Industry, Land Use, Offsets and Certificates, People and Policy, Solar, Transportation, Water Power, Wind

220

Colombia-EU-UNDP Low Emission Capacity Building Programme (LECBP) | Open  

Open Energy Info (EERE)

Colombia-EU-UNDP Low Emission Capacity Building Programme (LECBP) Colombia-EU-UNDP Low Emission Capacity Building Programme (LECBP) Jump to: navigation, search Name Colombia-EU-UNDP Low Emission Capacity Building Programme (LECBP) Agency/Company /Organization The European Union (EU), United Nations Development Programme (UNDP), German Federal Ministry for the Environment, Nature Conservation and Nuclear Safety (BMU), Australian Department of Climate Change and Energy Efficiency (DCCEE), Australian Agency for International Development (AusAID) Partner Multiple Ministries Sector Climate Focus Area Renewable Energy, Non-renewable Energy, Agriculture, Biomass, Buildings, Economic Development, Energy Efficiency, Forestry, Geothermal, Goods and Materials, Greenhouse Gas, Industry, Land Use, Offsets and Certificates, People and Policy, Solar, Transportation, Water Power, Wind

Note: This page contains sample records for the topic "butyl ether eu" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Trinidad and Tobago-EU-UNDP Low Emission Capacity Building Programme  

Open Energy Info (EERE)

Trinidad and Tobago-EU-UNDP Low Emission Capacity Building Programme Trinidad and Tobago-EU-UNDP Low Emission Capacity Building Programme (LECBP) Jump to: navigation, search Name Trinidad and Tobago-EU-UNDP Low Emission Capacity Building Programme (LECBP) Agency/Company /Organization The European Union (EU), United Nations Development Programme (UNDP), German Federal Ministry for the Environment, Nature Conservation and Nuclear Safety (BMU), Australian Department of Climate Change and Energy Efficiency (DCCEE), Australian Agency for International Development (AusAID) Partner Multiple Ministries Sector Climate Focus Area Renewable Energy, Non-renewable Energy, Agriculture, Biomass, Buildings, Economic Development, Energy Efficiency, Forestry, Geothermal, Goods and Materials, Greenhouse Gas, Industry, Land Use, Offsets and Certificates, People and Policy, Solar, Transportation, Water Power, Wind

222

Microsoft Word - EU-US Smart Grid assessment - final report -online version.docx  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

JRC 73070 JRC 73070 EUR 25522 EN Assessing Smart Grid Benefits and Impacts: EU and U.S. Initiatives Joint Report EC JRC - US DOE Vincenzo Giordano Steven Bossart European Commission US Department of Energy-DOE Joint Research Centre (JRC) Office of Electricity and Energy Reliability Institute for Energy and Transport 2012 2 European Commission Joint Research Centre (JRC) Institute for Energy and Transport (IET) Contact information Gianluca Fulli Address: Joint Research Centre, Westerduinweg 3, NL-1755 LE Petten E-mail: gianluca. fulli@ec.europa.eu Tel.: +00312245266 http://iet.jrc.ec.europa.eu/ http://www.jrc.ec.europa.eu/ Steven Bossart Address: US Department of Energy, National Energy Technology Laboratory,

223

Uganda-EU-UNDP Low Emission Capacity Building Programme (LECBP) | Open  

Open Energy Info (EERE)

Uganda-EU-UNDP Low Emission Capacity Building Programme (LECBP) Uganda-EU-UNDP Low Emission Capacity Building Programme (LECBP) Jump to: navigation, search Name Uganda-EU-UNDP Low Emission Capacity Building Programme (LECBP) Agency/Company /Organization The European Union (EU), United Nations Development Programme (UNDP), German Federal Ministry for the Environment, Nature Conservation and Nuclear Safety (BMU), Australian Department of Climate Change and Energy Efficiency (DCCEE), Australian Agency for International Development (AusAID) Partner Multiple Ministries Sector Climate Focus Area Renewable Energy, Non-renewable Energy, Agriculture, Biomass, Buildings, Economic Development, Energy Efficiency, Forestry, Geothermal, Goods and Materials, Greenhouse Gas, Industry, Land Use, Offsets and Certificates, People and Policy, Solar, Transportation, Water Power, Wind

224

Moldova-EU-UNDP Low Emission Capacity Building Programme (LECBP) | Open  

Open Energy Info (EERE)

Moldova-EU-UNDP Low Emission Capacity Building Programme (LECBP) Moldova-EU-UNDP Low Emission Capacity Building Programme (LECBP) Jump to: navigation, search Name Moldova-EU-UNDP Low Emission Capacity Building Programme (LECBP) Agency/Company /Organization The European Union (EU), United Nations Development Programme (UNDP), German Federal Ministry for the Environment, Nature Conservation and Nuclear Safety (BMU), Australian Department of Climate Change and Energy Efficiency (DCCEE), Australian Agency for International Development (AusAID) Partner Multiple Ministries Sector Climate Focus Area Renewable Energy, Non-renewable Energy, Agriculture, Biomass, Buildings, Economic Development, Energy Efficiency, Forestry, Geothermal, Goods and Materials, Greenhouse Gas, Industry, Land Use, Offsets and Certificates, People and Policy, Solar, Transportation, Water Power, Wind

225

Thailand-EU-UNDP Low Emission Capacity Building Programme (LECBP) | Open  

Open Energy Info (EERE)

Thailand-EU-UNDP Low Emission Capacity Building Programme (LECBP) Thailand-EU-UNDP Low Emission Capacity Building Programme (LECBP) Jump to: navigation, search Name Thailand-EU-UNDP Low Emission Capacity Building Programme (LECBP) Agency/Company /Organization The European Union (EU), United Nations Development Programme (UNDP), German Federal Ministry for the Environment, Nature Conservation and Nuclear Safety (BMU), Australian Department of Climate Change and Energy Efficiency (DCCEE), Australian Agency for International Development (AusAID) Partner Multiple Ministries Sector Climate Focus Area Renewable Energy, Non-renewable Energy, Agriculture, Biomass, Buildings, Economic Development, Energy Efficiency, Forestry, Geothermal, Goods and Materials, Greenhouse Gas, Industry, Land Use, Offsets and Certificates, People and Policy, Solar, Transportation, Water Power, Wind

226

Mexico-EU-UNDP Low Emission Capacity Building Programme (LECBP) | Open  

Open Energy Info (EERE)

Mexico-EU-UNDP Low Emission Capacity Building Programme (LECBP) Mexico-EU-UNDP Low Emission Capacity Building Programme (LECBP) Jump to: navigation, search Name Mexico-EU-UNDP Low Emission Capacity Building Programme (LECBP) Agency/Company /Organization The European Union (EU), United Nations Development Programme (UNDP), German Federal Ministry for the Environment, Nature Conservation and Nuclear Safety (BMU), Australian Department of Climate Change and Energy Efficiency (DCCEE), Australian Agency for International Development (AusAID) Partner Multiple Ministries Sector Climate Focus Area Renewable Energy, Non-renewable Energy, Agriculture, Biomass, Buildings, Economic Development, Energy Efficiency, Forestry, Geothermal, Goods and Materials, Greenhouse Gas, Industry, Land Use, Offsets and Certificates, People and Policy, Solar, Transportation, Water Power, Wind

227

Peru-EU-UNDP Low Emission Capacity Building Programme (LECBP) | Open Energy  

Open Energy Info (EERE)

Peru-EU-UNDP Low Emission Capacity Building Programme (LECBP) Peru-EU-UNDP Low Emission Capacity Building Programme (LECBP) Jump to: navigation, search Name Peru-EU-UNDP Low Emission Capacity Building Programme (LECBP) Agency/Company /Organization The European Union (EU), United Nations Development Programme (UNDP), German Federal Ministry for the Environment, Nature Conservation and Nuclear Safety (BMU), Australian Department of Climate Change and Energy Efficiency (DCCEE), Australian Agency for International Development (AusAID) Partner Multiple Ministries Sector Climate Focus Area Renewable Energy, Non-renewable Energy, Agriculture, Biomass, Buildings, Economic Development, Energy Efficiency, Forestry, Geothermal, Goods and Materials, Greenhouse Gas, Industry, Land Use, Offsets and Certificates, People and Policy, Solar, Transportation, Water Power, Wind

228

Brussels, 29 April 2005 EU-JAPAN Summit -2 May 2005  

E-Print Network [OSTI]

in Luxembourg on 2 May 2005. Alongside European Commission President José Manuel Durão Barroso and European. President Barroso said: "I am looking forward to my first Summit meeting with Prime Minister Koizumi. EU

229

Options introduction and volatility in the EU ETS1 Julien Chevallier 2  

E-Print Network [OSTI]

in the European Union Emissions Trading Scheme (EU ETS), the European Climate Exchange (ECX) has introduced option the introduction of options has increased or decreased volatility in the European Union Emissions Trading Sc

Paris-Sud XI, Université de

230

Fuel switching in the electricity sector under the EU ETS: Review and prospective  

SciTech Connect (OSTI)

The European Union has implemented the European Union emission trading scheme (EU ETS) as an instrument to facilitate greenhouse gas (GHG) emission abatement stipulated in the Kyoto protocol. Empirical data show that in the early stages of the EU ETS, the value of a ton of CO{sub 2} has already led to emission abatement through switching from coal to gas in the European electric power sector. In the second part of this paper, an electricity generation simulation model is used to perform simulations on the switching behavior in both the first and the second trading periods of the EU ETS. In 2005, the reduction in GHG emissions in the electric power sector due to EU ETS is estimated close to 88 Mton. For the second trading period, a European Union allowance (EUA) price dependent GHG reduction curve has been determined. The obtained switching potential turns out to be significant, up to 300 Mton/year, at sufficiently high EUA prices.

Delarue, E.; Voorspools, K.; D'haeseleer, W. [Katholieke University of Leuven, Heverlee (Belgium)

2008-06-15T23:59:59.000Z

231

CO2 Abatement in the UK Power Sector: Evidence from the EU ETS Trial Period  

E-Print Network [OSTI]

This paper provides an empirical assessment of CO2 emissions abatement in the UK power sector during the trial period of the EU ETS. Using an econometrically estimated model of fuel switching, it separates the impacts of ...

Ellerman, A. Denny

2008-01-01T23:59:59.000Z

232

Solar Thermal Energy Use in EU-27 Countries: Evolution and Promotion  

Science Journals Connector (OSTI)

Growth in the use of renewable energies in the 27 European Union (EU-27 ... past decade has been remarkable. Among these energies is solar thermal energy (STE). The average annual growth rate ... has reached almo...

María P. del Pablo-Romero; Antonio Sánchez-Braza; Enrique Lerma

2013-01-01T23:59:59.000Z

233

Nuclear-quadrupole optical hole burning in the stoichiometric material EuP5O14  

Science Journals Connector (OSTI)

Hole burning, which is attributed to optical pumping of nuclear-quadrupole levels, has been observed in the stoichiometric rare-earth compound, EuP5O14. The long...

Macfarlane, R M; Genack, A Z; Weitz, D A; Shelby, R M

1980-01-01T23:59:59.000Z

234

Malaysia-EU-UNDP Low Emission Capacity Building Programme (LECBP) | Open  

Open Energy Info (EERE)

Malaysia-EU-UNDP Low Emission Capacity Building Programme (LECBP) Malaysia-EU-UNDP Low Emission Capacity Building Programme (LECBP) Jump to: navigation, search Name Malaysia-EU-UNDP Low Emission Capacity Building Programme (LECBP) Agency/Company /Organization The European Union (EU), United Nations Development Programme (UNDP), German Federal Ministry for the Environment, Nature Conservation and Nuclear Safety (BMU), Australian Department of Climate Change and Energy Efficiency (DCCEE), Australian Agency for International Development (AusAID) Partner Multiple Ministries Sector Climate Focus Area Renewable Energy, Non-renewable Energy, Agriculture, Biomass, Buildings, Economic Development, Energy Efficiency, Forestry, Geothermal, Goods and Materials, Greenhouse Gas, Industry, Land Use, Offsets and Certificates, People and Policy, Solar, Transportation, Water Power, Wind

235

Zambia-EU-UNDP Low Emission Capacity Building Programme (LECBP) | Open  

Open Energy Info (EERE)

Zambia-EU-UNDP Low Emission Capacity Building Programme (LECBP) Zambia-EU-UNDP Low Emission Capacity Building Programme (LECBP) Jump to: navigation, search Name Zambia-EU-UNDP Low Emission Capacity Building Programme (LECBP) Agency/Company /Organization The European Union (EU), United Nations Development Programme (UNDP), German Federal Ministry for the Environment, Nature Conservation and Nuclear Safety (BMU), Australian Department of Climate Change and Energy Efficiency (DCCEE), Australian Agency for International Development (AusAID) Partner Multiple Ministries Sector Climate Focus Area Renewable Energy, Non-renewable Energy, Agriculture, Biomass, Buildings, Economic Development, Energy Efficiency, Forestry, Geothermal, Goods and Materials, Greenhouse Gas, Industry, Land Use, Offsets and Certificates, People and Policy, Solar, Transportation, Water Power, Wind

236

Morocco-EU-UNDP Low Emission Capacity Building Programme (LECBP) | Open  

Open Energy Info (EERE)

Morocco-EU-UNDP Low Emission Capacity Building Programme (LECBP) Morocco-EU-UNDP Low Emission Capacity Building Programme (LECBP) Jump to: navigation, search Name Morocco-EU-UNDP Low Emission Capacity Building Programme (LECBP) Agency/Company /Organization The European Union (EU), United Nations Development Programme (UNDP), German Federal Ministry for the Environment, Nature Conservation and Nuclear Safety (BMU), Australian Department of Climate Change and Energy Efficiency (DCCEE), Australian Agency for International Development (AusAID) Partner Multiple Ministries Sector Climate Focus Area Renewable Energy, Non-renewable Energy, Agriculture, Biomass, Buildings, Economic Development, Energy Efficiency, Forestry, Geothermal, Goods and Materials, Greenhouse Gas, Industry, Land Use, Offsets and Certificates, People and Policy, Solar, Transportation, Water Power, Wind

237

Kenya-EU-UNDP Low Emission Capacity Building Programme (LECBP) | Open  

Open Energy Info (EERE)

Kenya-EU-UNDP Low Emission Capacity Building Programme (LECBP) Kenya-EU-UNDP Low Emission Capacity Building Programme (LECBP) Jump to: navigation, search Name Kenya-EU-UNDP Low Emission Capacity Building Programme (LECBP) Agency/Company /Organization The European Union (EU), United Nations Development Programme (UNDP), German Federal Ministry for the Environment, Nature Conservation and Nuclear Safety (BMU), Australian Department of Climate Change and Energy Efficiency (DCCEE), Australian Agency for International Development (AusAID) Partner Multiple Ministries Sector Climate Focus Area Renewable Energy, Non-renewable Energy, Agriculture, Biomass, Buildings, Economic Development, Energy Efficiency, Forestry, Geothermal, Goods and Materials, Greenhouse Gas, Industry, Land Use, Offsets and Certificates, People and Policy, Solar, Transportation, Water Power, Wind

238

Investigation of metal binding sites on soil fulvic acid using Eu(III) luminescence spectroscopy  

SciTech Connect (OSTI)

The [sup 7]F[sub 0] [yields] [sup 5]D[sub 0] excitation spectra of Eu(III) complexed with soil fulvic acid (FA) were acquired over a range of solution pH (2.9-7.8) and FA concentrations (800-3200 mg L[sup [minus]1]) using a pulsed tunable dye laser system. The broad asymmetric excitation spectra were well-fitted to a sum of two conventional Lorentzian-shaped curves, revealing the existence of two types of carboxylate moieties for the binding of metal ions on FA which formed 1:1 (EuL[sup 2+]; L = carboxylate) and 1:2 complexes (EuL[sub 2][sup +]). The weaker binding species, EuL[sup 2+], seemed to be quite abundant and showed a rapid increase as the pH was raised from 2.9 to 6.3, but it was susceptible to hydrolysis at pH higher than 7 while the stronger binding species, EuL[sub 2][sup +], showed only a modest growth with an increase in pH. By contrast, on a more flexible synthetic linear polymer, poly(acrylic acid) (PAA) and poly(vinylbenzoic acid) (PVBA) as model polymers, EuL[sub 2][sup +] was seen as the dominant species except in acidic media. 28 refs., 10 figs., 3 tabs.

Yoon, T.H.; Moon, H. (Korea Advanced Inst. of Science and Technology, Taejun (Korea, Democratic People's Republic of)); Park, Y.J.; Park, K.K. (Korea Atomic Energy Research Inst., Taejun (Korea, Democratic People's Republic of))

1994-11-01T23:59:59.000Z

239

Sulfobutyl Ether b-Cyclodextrin (SBE-b-CD) in Eyedrops Improves the Tolerability of a Topically Applied Pilocarpine Prodrug in Rabbits  

E-Print Network [OSTI]

The effects of a novel, modified ?-cyclodextrin (SBE4-?-CD; a variably substituted sulfobutyl ether with an average degree of substitution of four) on eye irritation and miotic response of an ophthalmically applied pilocarpine ...

Stella, Valentino J.; Jä rvinen, Tomi; Jä rvinen, Kristina; Thompson, Diame; Urtti, Arto

1995-01-01T23:59:59.000Z

240

A violet emission in ZnS:Mn,Eu: Luminescence and applications for radiation detection  

SciTech Connect (OSTI)

We prepared manganese and europium co-doped zinc sulfide (ZnS:Mn,Eu) phosphors and used them for radiation detection. In addition to the red fluorescence at 583?nm due to the d-d transition of Mn ions, an intense violet emission at 420?nm is newly observed in ZnS:Mn,Eu phosphors. The emission is related to Eu{sup 2+} doping but only appears at certain Eu{sup 2+} concentrations. It is found that the intensity of the 420?nm violet fluorescence is X-ray does-dependent, while the red fluorescence of 583?nm is not. The ratio of fluorescence intensities at 420?nm and 583?nm has been monitored as a function of X-ray doses that exposed upon the ZnS:Mn,Eu phosphors. Empirical formulas are provided to estimate the doses of applied X-ray irradiation. Finally, possible mechanisms of X-ray irradiation induced fluorescence quenching are discussed. The intense 420?nm emission not only provides a violet light for solid state lighting but also offers a very sensitive method for radiation detection.

Ma, Lun; Chen, Wei, E-mail: weichen@uta.edu [Department of Physics and the SAVANT Center, The University of Texas at Arlington, Arlington, Texas 76019-0059 (United States); Jiang, Ke [Center for Biofrontiers Institute, University of Colorado at Colorado Springs, 1420 Austin Bluffs Pkwy., Colorado Springs, Colorado 80918 (United States); Liu, Xiao-tang [Department of Physics and the SAVANT Center, The University of Texas at Arlington, Arlington, Texas 76019-0059 (United States); Department of Applied Chemistry, College of Science, South China Agricultural University, Guangzhou 510642 (China)

2014-03-14T23:59:59.000Z

Note: This page contains sample records for the topic "butyl ether eu" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

The EU-Ukraine Association Agreement as a Framework of Integration between the Two Parties  

Science Journals Connector (OSTI)

Abstract The strengthening of relations between EU and Ukraine is of strategic significance to the two parties, both politically and economically, given the size and geographic position of the country under consideration and the fact that EU is already one of the major commercial partners of Ukraine. Towards this goal, the partnership and cooperation regime should be succeeded by an association regime joining the two sides. Negotiations for the conclusion of a pioneer Association Agreement (AA), the first with a country of Eastern Partnership, have been completed. However, its final signature depends upon the fulfillment, from the side of Ukraine, of specific terms related to the progress of internal reforms in the nation's political, economic and legal system. The AA will become the legal framework for the political association and economic integration between the contracting parties. Crucial component of the agreement is a deep and comprehensive free trade area (DCFTA), the establishment of which is expected to contribute in Ukraine's economic modernization and integration with EU's internal market, mainly by adopting the trade-related EU acquis. The aim of this paper is to examine the importance of the AA and in particular the rules governing the liberalization of bilateral trade, the implementation mechanisms laid down and the issues related to the perspective of Ukraine's accession to the EU.

Odysseas Spiliopoulos

2014-01-01T23:59:59.000Z

242

Solvent Extraction Behavior of Neptunium (IV) Ions between Nitric Acid and Diluted 30% Tri-butyl Phosphate in the Presence of Simple Hydroxamic Acids  

SciTech Connect (OSTI)

Formo- and aceto-hydroxamic acids are very effective reagents for stripping tetravalent actinide ions such as Np(IV) and Pu(IV) ions from a tri-butyl phosphate phase into nitric acid. Distribution data for Np(IV) in the presence of these hydroxamate ions have now been accumulated and trends established. Stability constants for aceto-hydroxamate complexes of Np(IV) and Np(V) ions have also been determined in a perchlorate medium, and these reaffirm the affinity of hydroxamate ligands for actinide (IV) ions over actinyl (V,VI) ions.

Taylor, Robin J.; Sinkov, Sergey I.; Choppin, Gregory R.; May, Iain

2008-01-15T23:59:59.000Z

243

An evaluation of the 3M Organic Vapor Monitor #3500 as a short term exposure limit sampling device for acetone, methyl ethyl ketone, and methyl iso butyl ketone  

E-Print Network [OSTI]

. An exploded view of the monitor is illustrated in Figure 1. The theory of diffusive sampling considers a concentration gra- dient between the ambient air and the adsorbent to be the driving force for sampling. For the adsorption to be controlled by diffu...AN EVALUATION OF THE 3M ORGANIC VAPOR MONITOR 43500 AS A SHOR'I TERM EXPOSURE LIMIT SAMPLING DEVICE FOR ACETONE, METHYL ETHYL KETONE, AND METHYL ISO BUTYL KETONE A Thesis by LLOYD B. ANDREW III Submitted to the Graduate College of Texas ASM...

Andrew, Lloyd B.

2012-06-07T23:59:59.000Z

244

A New Flow Control Technique Using Diluted Epinephrine in the N-butyl-2-cyanoacrylate Embolization of Visceral Artery Pseudoaneurysms Secondary to Chronic Pancreatitis  

SciTech Connect (OSTI)

Although n-butyl-2-cyanoacrylate (NBCA) has been used as an effective liquid embolization material, its indication for pseudoaneurysms has seemingly been limited because of the technical difficulties of using NBCA, such as reflux to the parent artery and causing significant infarction. Thus, considerable skill in using NBCA or a device to control blood flow during its polymerization is required to achieve embolization without severe complications. We report our new technique for controlling blood flow using diluted epinephrine in transcatheter arterial NBCA embolization of five pseudoaneurysms in four cases secondary to hemosuccus pancreaticus.

Morishita, Hiroyuki, E-mail: hmorif@koto.kpu-m.ac.jp [Japan Red Cross Kyoto Daiichi Hospital, Department of Diagnostic Radiology (Japan); Yamagami, Takuji [Kyoto Prefectural University of Medicine, Department of Radiology, Graduate School of Medical Science (Japan); Takeuchi, Yoshito [National Cancer Center, Division of Diagnostic Radiology (Japan); Matsumoto, Tomohiro; Asai, Shunsuke; Masui, Koji [Japan Red Cross Kyoto Daiichi Hospital, Department of Diagnostic Radiology (Japan); Sato, Hideki [Japan Red Cross Kyoto Daiichi Hospital, Department of Gastroenterology (Japan); Taniguchi, Fumihiro [Japan Red Cross Kyoto Daiichi Hospital, Department of Surgery (Japan); Sato, Osamu [Japan Red Cross Kyoto Daiichi Hospital, Department of Diagnostic Radiology (Japan); Nishimura, Tsunehiko [Kyoto Prefectural University of Medicine, Department of Radiology, Graduate School of Medical Science (Japan)

2012-08-15T23:59:59.000Z

245

Democratic Republic of Congo-EU-UNDP Low Emission Capacity Building  

Open Energy Info (EERE)

Page Page Edit with form History Facebook icon Twitter icon » Democratic Republic of Congo-EU-UNDP Low Emission Capacity Building Programme (LECBP) Jump to: navigation, search Name Democratic Republic of Congo-EU-UNDP Low Emission Capacity Building Programme (LECBP) Agency/Company /Organization The European Union (EU), United Nations Development Programme (UNDP), German Federal Ministry for the Environment, Nature Conservation and Nuclear Safety (BMU), Australian Department of Climate Change and Energy Efficiency (DCCEE), Australian Agency for International Development (AusAID) Partner Multiple Ministries Sector Climate Focus Area Renewable Energy, Non-renewable Energy, Agriculture, Biomass, Buildings, Economic Development, Energy Efficiency, Forestry, Geothermal, Goods and Materials, Greenhouse Gas, Industry, Land Use, Offsets and Certificates, People and Policy, Solar, Transportation, Water Power, Wind

246

Energy Department Partners with EU on Electric Vehicle and Smart Grid  

Broader source: Energy.gov (indexed) [DOE]

Partners with EU on Electric Vehicle and Smart Partners with EU on Electric Vehicle and Smart Grid Coordination Energy Department Partners with EU on Electric Vehicle and Smart Grid Coordination July 19, 2013 - 5:17pm Addthis Yesterday, representatives from the Energy Department, the European Commission and Argonne National Lab celebrated the launch of the Electric Vehicle-Smart Grid Interoperability Center. From left to right: Mr. Giovanni De Santi, Director of the JRC Institute for energy and transport (IET); Mr. Dominique Ristori, Director-General of the European Commission's Joint Research Centre (JRC); Dr. Phyllis Yoshida, DOE Deputy Assistant Secretary for Europe, Asia and the Americas; Dr. Eric Isaacs, Director of Argonne National Laboratory. | Photo courtesy of Argonne National Lab. Yesterday, representatives from the Energy Department, the European

247

Lebanon-EU-UNDP Low Emission Capacity Building Programme (LECBP) | Open  

Open Energy Info (EERE)

form form View source History View New Pages Recent Changes All Special Pages Semantic Search/Querying Get Involved Help Apps Datasets Community Login | Sign Up Search Page Edit with form History Facebook icon Twitter icon » Lebanon-EU-UNDP Low Emission Capacity Building Programme (LECBP) Jump to: navigation, search Name Lebanon-EU-UNDP Low Emission Capacity Building Programme (LECBP) Agency/Company /Organization The European Union (EU), United Nations Development Programme (UNDP), German Federal Ministry for the Environment, Nature Conservation and Nuclear Safety (BMU), Australian Department of Climate Change and Energy Efficiency (DCCEE), Australian Agency for International Development (AusAID) Partner Multiple Ministries Sector Climate Focus Area Renewable Energy, Non-renewable Energy, Agriculture, Biomass, Buildings, Economic Development, Energy Efficiency, Forestry, Geothermal, Goods and Materials, Greenhouse Gas, Industry, Land Use, Offsets and Certificates, People and Policy, Solar, Transportation, Water Power, Wind

248

Hetero-epitaxial EuO interfaces studied by analytic electron microscopy  

SciTech Connect (OSTI)

With nearly complete spin polarization, the ferromagnetic semiconductor europium monoxide could enable next-generation spintronic devices by providing efficient ohmic spin injection into silicon. Spin injection is greatly affected by the quality of the interface between the injector and silicon. Here, we use atomic-resolution scanning transmission electron microscopy in conjunction with electron energy loss spectroscopy to directly image and chemically characterize a series of EuO|Si and EuO|YAlO{sub 3} interfaces fabricated using different growth conditions. We identify the presence of europium silicides and regions of disorder at the EuO|Si interfaces, imperfections that could significantly reduce spin injection efficiencies via spin-flip scattering.

Mundy, Julia A. [School of Applied and Engineering Physics, Cornell University, Ithaca, New York 14853 (United States); Hodash, Daniel; Melville, Alexander; Held, Rainer [Department of Materials Science and Engineering, Cornell University, Ithaca, New York 14853 (United States); Mairoser, Thomas; Schmehl, Andreas [Zentrum für Elektronische Korrelationen und Magnetismus, Universität Augsburg, Universitätsstraße 1, D-86159 Augsburg (Germany); Muller, David A.; Kourkoutis, Lena F. [School of Applied and Engineering Physics, Cornell University, Ithaca, New York 14853 (United States); Kavli Institute at Cornell for Nanoscale Science, Ithaca, New York 14853 (United States); Schlom, Darrell G. [Department of Materials Science and Engineering, Cornell University, Ithaca, New York 14853 (United States); Kavli Institute at Cornell for Nanoscale Science, Ithaca, New York 14853 (United States)

2014-03-03T23:59:59.000Z

249

EU promises new biofuel rules won't harm the environment http://www.pr-inside.com/eu-promises-new-biofuel-rules-won-t-r385258.htm 1 of 2 1/16/2008 12:32 PM  

E-Print Network [OSTI]

EU promises new biofuel rules won't harm the environment http://www.pr-inside.com/eu-promises-new-biofuel promises new biofuel rules won't harm the environment © AP 2008-01-14 16:21:49 - BRUSSELS, Belgium (AP) - The European Union promised Monday that its new push to promote biofuels will try to prevent harming

250

Temperature dependent band offsets in PbSe/PbEuSe quantum well heterostructures  

SciTech Connect (OSTI)

The band offsets of PbSe/Pb{sub 1-x}Eu{sub x}Se multi-quantum wells grown by molecular beam epitaxy are determined as a function of temperature and europium content using temperature-modulated differential transmission spectroscopy. The confined quantum well states in the valence and conduction bands are analyzed using a k{center_dot}p model with envelope function approximation. From the fit of the experimental data, the normalized conduction band offset is determined as 0.45{+-}0.15 of the band gap difference, independently of Eu content up to 14% and temperature from 20 to 300 K.

Simma, M.; Bauer, G.; Springholz, G. [Institut fuer Halbleiter und Festkoerperphysik, Johannes Kepler Universitaet, A-4040 Linz (Austria)

2012-10-22T23:59:59.000Z

251

Ethoxyresorufin O-deethylase induction of polychlorinated diphenyl ethers in H4IIE cells  

SciTech Connect (OSTI)

The ethoxyresorufin O-deethylase (EROD) induction potencies of 29 polychlorinated diphenyl ethers were determined in the rat hepatoma H4IIE cell bioassay and compared with that of 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD). Two polychlorinated biphenyls (PCBs) were included as additional reference substances. PCDE congeners tested were PCDEs 47, 66, 77, 85, 99, 105, 118, 126, 128, 137, 138, 140, 147, 153, 154, 156, 157, 167, 170, 180, 181, 182, 190, 194, 195, 196, 197, 203 and 206. The purity of these congeners was > 99%. Because several of these congeners induced EROD activity when tested at high concentrations, the amount of PCDD and PCDF impurities of these active PCDEs was determined by gas chromatography/mass spectrometry. The activity of the active PCDEs was concluded to be mainly due to contamination with 2,3,7,8-chloro substituted PCDFS, because after an additional clean-up on a Florisil column, which removes PCDDs and PCDFs, only three PCDEs (156, 180, 194) remained active. The potencies of PCDEs 156, 180 and 194 (TEF {approximately} 10{sup {minus}6}), however, were about 100-fold less than that of PCB 77 (TEF {approximately} 10{sup {minus}4}). The poor induction potencies of the non- and mono-ortho-PCDEs indicates that PCDEs do not have structure-activity relationships analogous to those of PCBs. If the authors use EROD inducing potency in H4IIE cells as a relative measure of potential Ah receptor-mediated toxic potency, the PCDEs in the study would be expected to be less toxic than analogous PCBs and considerably less-toxic than certain PCDDs and PCDFs.

Koistinen, J.; Sanderson, J.T.; Giesy, J.P. [Michigan State Univ., East Lansing, MI (United States); Nevalainen, T.; Paasivirta, J. [Univ. of Jyvaskyla (Finland)

1995-12-31T23:59:59.000Z

252

Mechanistic Investigation of Acid-Catalyzed Cleavage of Aryl-Ether Linkages: Implications for Lignin Depolymerization  

SciTech Connect (OSTI)

Carbon-oxygen bonds are the primary inter-monomer linkages lignin polymers in plant cell walls, and as such, catalyst development to cleave these linkages is of paramount importance to deconstruct biomass to its constituent monomers for the production of renewable fuels and chemicals. For many decades, acid catalysis has been used to depolymerize lignin. Lignin is a primary component of plant cell walls, which is connected primarily by aryl-ether linkages, and the mechanism of its deconstruction by acid is not well understood, likely due to its heterogeneous and complex nature compared to cellulose. For effective biomass conversion strategies, utilization of lignin is of significant relevance and as such understanding the mechanisms of catalytic lignin deconstruction to constituent monomers and oligomers is of keen interest. Here, we present a comprehensive experimental and theoretical study of the acid catalysis of a range of dimeric species exhibiting the b-O-4 linkage, the most common inter-monomer linkage in lignin. We demonstrate that the presence of a phenolic species dramatically increases the rate of cleavage in acid at 150 degrees C. Quantum mechanical calculations on dimers with the para-hydroxyl group demonstrate that this acid-catalyzed pathway differs from the nonphenolic dimmers. Importantly, this result implies that depolymerization of native lignin in the plant cell wall will proceed via an unzipping mechanism wherein b-O-4 linkages will be cleaved from the ends of the branched, polymer chains inwards toward the center of the polymer. To test this hypothesis further, we synthesized a homopolymer of b-O-4 with a phenolic hydroxyl group, and demonstrate that it is cleaved in acid from the end containing the phenolic hydroxyl group. This result suggests that genetic modifications to lignin biosynthesis pathways in plants that will enable lower severity processes to fractionate lignin for upgrading and for easier access to the carbohydrate fraction of the plant cell wall.

Sturgeon, M. R.; Kim, S.; Chmely, S. C.; Foust, T. D.; Beckham, G. T.

2013-01-01T23:59:59.000Z

253

The lightness of being: mass, ether, and unification of the forces  

SciTech Connect (OSTI)

How can an electron be both a wave and a particle? At the same time? Because it is a quantum field. That key insight seems to be underappreciated, given the awe and mysticism that permeate most nontechnical discussions of modern physics. Perhaps the root of the problem is that most popularizations of quantum mechanics and of particle physics shy away from quantized fields, the natural language for microscopic phenomena. In 'The Lightness of Being: Mass, Ether, and the Unification of Forces', Frank Wilczek confronts quantum field theory head on, demystifying not only wave-particle duality but also the origin of mass for hadrons (that is, everyday matter). Wilczek is the Herman Feshbach Professor of Physics at MIT and a co-recipient of the 2004 Nobel Prize in Physics. His research has spanned almost all aspects of theoretical particle physics, with significant forays into condensed-matter physics and dense nuclear matter (condensed quark matter, one might say). Recurring themes are the richness of quantum chromodynamics (QCD) and the alluring ideas of unification. His breadth and depth make him a sought after speaker for colloquia and public lectures. Wilczek also contributes an occasional Reference Frame column to 'Physics Today'. The material in 'The Lightness of Being' reflects the scope of the author's research. The book consists of three parts: the quantum fields of QCD (the ether that makes mass), gravitation (the ether that feels mass), and unification. Part 1, which traces notions of mass from Isaac Newton's time through theoretical and computational results of the past 40 years, is the most substantial and original; it is rich, modern, and rooted in observed phenomena. Part 2 continues in the same vein as it connects gravity, also an observed phenomenon, to QCD. Part 3 is more conventional, for a popularization of particle physics, in its focus on speculative ideas that (still) await direct experimental tests. Readers of 'Physics Today' will know that Wilczek can write with wit, grace, and an uncanny facility for using lightweight language to express heavy-duty ideas. They will find much of that kind of writing in 'The Lightness of Being'. Wilczek addresses subtle ideas with vim and vigor. He avoids some of the jargon of quantum field theory; for example, he calls the vertex in a Feynman diagram a hub. In more ambitious terminology, he refers to space-filling, everfluctuating quantum fields--be they electrons, quarks, gluons, or gravity--as 'the Grid'. The term is supposed to be short and familiar, evoking the ubiquitous electric grid (and soon-to-beubiquitous computing grid). It also, for the expert, cleverly alludes to lattice gauge theory. Indeed, after vividly explaining how the dynamics of QCD and the constraints of Heisenberg uncertainty conspire to create mass from the Grid, Wilczek emphasizes that the picture is backed by lattice QCD computations of 'heroic' proportions. Unfortunately, too much of 'The Lightness' is laden with clunky affectation: silly names (a pulsed electron accelerator is called the 'ultrastroboscopic nanomicroscope'), sophomoric jokes ('hadron' is 'not a typo'), references to pop culture (Wilczek might have called quantum fields 'the Matrix, but the sequels tarnished that candidate'), and many pointless footnotes. In a public lecture the audience may guffaw at such jokes, but on the printed page they fall flat. Wilczek explains physics so well that the inappropriate humor is the biggest unexplained puzzle of the book. It is fine to be silly, even crude, as long as the reader's path to understanding is made easier. A joke can inform with an unexpected perspective or simply give the mind a pause to refresh. Some of the humor achieves such aims, but too many gags impede the pace of the otherwise fine exposition. Three appendices, a glossary, and a set of endnotes are crisp and sober. They are excellent. 'The Lightness of Being' is not unbearable, but it is weighed down with too much clutter to rank as a masterpiece. It's a pity: Wilczek's best writing--some of it in this book--is l

Kronfeld, Andreas S.

2009-03-01T23:59:59.000Z

254

EU could go it alone on nuclear fusion plant 29.11.2004 -10:02 CET | By Richard Carter  

E-Print Network [OSTI]

EU could go it alone on nuclear fusion plant 29.11.2004 - 10:02 CET | By Richard Carter The EU research ministers. Talks over the world's first nuclear fusion reactor have stalled because Japan apart, the fusion technique binds atoms together to produce energy. But to produce nuclear fusion

255

Full-Color Emission From In2S3 and In2S3:Eu3+ Nanoparticles....  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

From In2S3 and In2S3:Eu3+ Nanoparticles. Full-Color Emission From In2S3 and In2S3:Eu3+ Nanoparticles. Abstract: Blue (425 nm) and green (510 nm) emission is observed from In2S3...

256

Distribution of glycerol ether lipids in the oxygen minimum zone of the Eastern Tropical North Pacific Ocean  

Science Journals Connector (OSTI)

Abstract The distributions of microbial glycerol ether lipids in suspended particulate matter in the oxygen minimum zone (OMZ) of the Eastern Tropical North Pacific Ocean (ETNP) were investigated. Nine groups of glycerol ether core lipids were detected and quantified: isoprenoid glycerol dialkyl glycerol tetraethers (GDGTs) (iso-GDGTs), isoprenoid glycerol dialkanol diethers (iso-GDDs) and hydroxylated isoprenoid \\{GDGTs\\} and \\{GDDs\\} (OH-GDGTs and OH-GDDs) of archaeal origin; branched glycerol dialkyl glycerol tetraethers (br-GDGTs) of bacterial origin and overly branched \\{GDGTs\\} (OB-GDGTs), sparsely branched \\{GDGTs\\} (SB-GDGTs), hybrid isoprenoid/branched \\{GDGTs\\} (IB-GDGTs) and a tentatively assigned H-shaped GDGT (H-1020) of unknown biological origin. The archaeal iso-GDGTs were the most abundant core lipids (89% of total), followed by iso-GDDs (4%), br-GDGTs (2%) and OH-GDGTs (1%). Archaeal intact polar \\{GDGTs\\} (IP GDGTs), including both mono- and diglycosidic iso-GDGTs, had depth profiles similar to OH-GDGTs and OH-GDDs, with a maximum concentration in the upper OMZ and secondary peaks in the mid and lower OMZ, suggesting similar but multiple planktonic sources. Core lipids of iso-GDGTs and other glycerol ethers showed deviating concentration profiles compared with IP \\{GDGTs\\} and OH-GDGTs and were most abundant in the mid OMZ. This is the first report of OH-GDDs, OB-GDGTs, SB-GDGTs, IB-GDGTs and H-1020 in the marine water column and the distribution patterns of these “orphan lipids” suggest that anaerobic planktonic microbes are their main source.

Sitan Xie; Xiao-Lei Liu; Florence Schubotz; Stuart G. Wakeham; Kai-Uwe Hinrichs

2014-01-01T23:59:59.000Z

257

E-Print Network 3.0 - allyl methacrylate styrene Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Tetrachloroethylene () Cyclohexanol () Cyclohexanone ()1- 1-Butyl alcohol ()2... ;() Acrolein () Acrylic acid () Allyl zlcohol () Allyl chloride () Allyl glycidyl ether(AGE) ()2-...

258

TABLE33.CHP:Corel VENTURA  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

products are reported by the PAD District of entry. b Includes crude oil imported for storage in the Strategic Petroleum Reserve. c Includes ethyl tertiary butyl ether (ETBE),...

259

TABLE34.CHP:Corel VENTURA  

Gasoline and Diesel Fuel Update (EIA)

products are reported by the PAD District of entry. b Includes crude oil imported for storage in the Strategic Petroleum Reserve. c Includes ethyl tertiary butyl ether (ETBE),...

260

Appendix A MIT Joint Program Report 193 1 Appendix A: Sectoral Trading between the EU-ETS and Emerging Countries1  

E-Print Network [OSTI]

, sectoral trading could be used to extend the European Emission Trading Scheme (EU-ETS) to electricity.5 billion of carbon permits and the EU carbon price decreases by 88% in 2030. Sectoral trading has a small impact on Chinese electricity generation but reverses changes in EU electricity generation driven

Note: This page contains sample records for the topic "butyl ether eu" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Wednesday, November 17, 2004 EU proposes nuclear fusion plant without Japan if there's no accord  

E-Print Network [OSTI]

Wednesday, November 17, 2004 EU proposes nuclear fusion plant without Japan if there's no accord by itself in building a nuclear fusion plant if no agreement is reached with Japan, according to a report, the United States, Russia, China and South Korea are collaborating on the international nuclear fusion

262

pEtrolEuM EnginEEring College of Engineering and Mines  

E-Print Network [OSTI]

pEtrolEuM EnginEEring College of Engineering and Mines Department of Petroleum Engineering 907-474-7734 http://cem.uaf.edu/pete/ MS Degree Minimum Requirements for Degree: 30 ­ 36 credits Petroleum engineering offers a unique look at the challenging problems confronting the petroleum industry. This program

Hartman, Chris

263

Transmission Electron Microscopy Study of Eu-Doped Y2O3 Nanosheets and Nanotubes  

SciTech Connect (OSTI)

A hydrothermal method was used to synthesize high-purity Eu-doped Y{sub 2}O{sub 3} nanosheets and nanotubes with an approximate molar ratio of (0.1):(1.0) for Eu:Y. High-resolution transmission electron microscopy, energy dispersive X-ray spectroscopy analysis and synchrotron X-ray diffraction were used to characterize these nanomaterials. A body-centered cubic structure was confirmed for the nanotubes. The lattice parameter of Eu-doped Y{sub 2}O{sub 3} nanotubes were 0.12% larger as compared to that of pure Y{sub 2}O{sub 3} which was attributed to the larger ionic radius of Eu{sup 3+} (0.947 {angstrom}) than that of Y{sup 3+} (0.900 {angstrom}). The nanosheets had a similar structure. Nanosheets of approximate dimensions 600 to 800 nm length and width were obtained using a slightly lower pH value, and they were highly textured. The high resolution transmission electron microscopy images showed that the nanotubes are fully crystalline. The nanotubes were typically 1.5-3 {micro}m in length and 50-200 nm in diameter. Using a pH value of approximately 10, stable nanotubes were obtained. It is anticipated that nanosheets might have rolled to form more stable nanotubes.

H Sun; T Chaudhuri; E Kenik; H Zhu; Y Ma

2011-12-31T23:59:59.000Z

264

An EIE/Altener project Co-funded by the EU Commission  

E-Print Network [OSTI]

and energy aspects of the biogas production by centralised co-digestion in selected areas of six EU countries. The assessment will provide incentives for the implementation of biogas systems in those areas and will help-technical barriers for the implementation and development of biogas from centralised co-digestion in the studied

265

An EIE/Altener project Co-funded by the EU Commission  

E-Print Network [OSTI]

, environmental and energy aspects of the biogas production by centralised co-digestion in selected areas of six EU countries. The assessment will provide incentives for the implementation of biogas systems for the implementation and development of biogas from centralised co-digestion in the studied areas and to propose some

266

Water Research 39 (2005) 239247 Biosorption of La, Eu and Yb using Sargassum biomass  

E-Print Network [OSTI]

Water Research 39 (2005) 239­247 Biosorption of La, Eu and Yb using Sargassum biomass Vivian Diniz-loaded biomass was studied. The ion exchange sorption mechanism was confirmed by the release of calcium ions from the biomass that matched the total number of metal and protons removed from the solution. The metal binding

Volesky, Bohumil

267

Spectroscopy of Eu3+ ions in congruent strontium barium niobate crystals  

E-Print Network [OSTI]

Spectroscopy of Eu3+ ions in congruent strontium barium niobate crystals Ã?. Andresen, A.-N. Bahar properties of single crystals of strontium barium niobate, grown from the congruently melting composition, electro-optic, pho- torefractive, and dielectric properties, the solid solution strontium barium niobate

Osnabrück, Universität

268

The Political Business Cycles in the EU enlarged 1 Mathilde Maurel2  

E-Print Network [OSTI]

1 The Political Business Cycles in the EU enlarged 1 Mathilde Maurel2 1. Politics and business by limiting the room for political adjustment, others considered that the process of enlargement was a way that the process of monetary unification is an endogenous process. Once the political decision of entering a common

Paris-Sud XI, Université de

269

Nuclear forward scattering vs. conventional Mossbauer studies of atomically tailored Eu-based materials.  

SciTech Connect (OSTI)

With the decrease in size of devices, rapid characterization of nano-devices is an inevitable necessity. It is shown that Moessbauer spectroscopy using synchrotron radiation from the advanced photon source provides such a tool of investigation. Results are presented and compared for conventional Moessbauer and Nuclear Forward Scattering for {sup 151}Eu-doped magnesium sulfide as an example, especially at low concentrations.

Konjhodzic, A.; Adamczyk, A.; Hasan, Z.; Alp, E. E.; Sturhahn, W.; Zhao, J.; Carroll, J. J.; Vagizov, F.; Univ. of Philadelphia; Youngstown State Univ.

2006-01-01T23:59:59.000Z

270

MARKETING APPLICATIONS: International Marketing, Marketing in the EU and Tourism Marketing  

E-Print Network [OSTI]

MARKETING APPLICATIONS: International Marketing, Marketing in the EU and Tourism Marketing Summer Business Program 2012 Course Marketing Applications: International Marketing, Marketing in the European Union and Tourism Marketing Professors Juan L. Nicolau. University of Alicante. JL.Nicolau@ua.es María

Escolano, Francisco

271

From 1521 April 2002, the EU workshop ASCMAP (Analysis of Single Cells in Marine Phytoplankton)  

E-Print Network [OSTI]

From 15­21 April 2002, the EU workshop ASCMAP (Analysis of Single Cells in Marine Phytoplankton) took place at the Alfred Wegener Institute for Polar and Marine Research in Bremerhaven, Germany of photosynthetic picoplankton in marine wa- ters; EVK3-CT-1999-00021). The aim of the work- shop was to combine

272

Atomic geometry and electronic structure of the Si(100)2×3-Eu surface phase  

Science Journals Connector (OSTI)

The structural and electronic properties of the Eu-induced 2×3 reconstruction on Si(100) have been investigated by scanning tunneling microscopy (STM), scanning tunneling spectroscopy (STS), and high-resolution Si 2p core-level spectroscopy using synchrotron radiation. STM images of this reconstruction are found to be drastically dependent on the bias voltage and tunneling current. STS measurements show that the 2×3-Eu surface is semiconducting. Two occupied states at ?0.9 and ?1.75V and three unoccupied states at +0.35, +0.8, and +1.5V are identified in the (dI?dV)?(I?V) spectrum of this surface. The Si 2p core-level spectra taken at various photon energies and emission angles are revealed to include four surface-related components S1?S4 with core-level shifts of ?0.54, ?0.24, +0.21, and +0.51eV, respectively. The S1, S2, and S4 components are assigned to first-layer Si atoms in the 2×3-Eu structure and the S3 component is shown to arise from the second-layer Si atoms. The results are discussed in the context of structural models reported recently for other metal-induced Si(100)2×3 reconstructions. Finally, an atomic model is proposed for the 2×3-Eu phase.

M. Kuzmin; R. E. Perälä; P. Laukkanen; I. J. Väyrynen

2005-08-25T23:59:59.000Z

273

Evaluation of Large Volume SrI2(Eu) Scintillator Detectors  

SciTech Connect (OSTI)

There is an ever increasing demand for gamma-ray detectors which can achieve good energy resolution, high detection efficiency, and room-temperature operation. We are working to address each of these requirements through the development of large volume SrI{sub 2}(Eu) scintillator detectors. In this work, we have evaluated a variety of SrI{sub 2} crystals with volumes >10 cm{sup 3}. The goal of this research was to examine the causes of energy resolution degradation for larger detectors and to determine what can be done to mitigate these effects. Testing both packaged and unpackaged detectors, we have consistently achieved better resolution with the packaged detectors. Using a collimated gamma-ray source, it was determined that better energy resolution for the packaged detectors is correlated with better light collection uniformity. A number of packaged detectors were fabricated and tested and the best spectroscopic performance was achieved for a 3% Eu doped crystal with an energy resolution of 2.93% FWHM at 662keV. Simulations of SrI{sub 2}(Eu) crystals were also performed to better understand the light transport physics in scintillators and are reported. This study has important implications for the development of SrI{sub 2}(Eu) detectors for national security purposes.

Sturm, B W; Cherepy, N J; Drury, O B; Thelin, P A; Fisher, S E; Magyar, A F; Payne, S A; Burger, A; Boatner, L A; Ramey, J O; Shah, K S; Hawrami, R

2010-11-18T23:59:59.000Z

274

Promoting electricity from renewable energy sources -- lessons learned from the EU, U.S. and Japan  

E-Print Network [OSTI]

sustainable growth of the renewable energy industry. Thegrowth of QF capacity, which included renewables, was astounding, aided by California’s diverse and abundant renewable energyrenewable generation, the EU has assumed this role since 2002, mostly due to a rapid growth of wind energy.

Haas, Reinhard

2008-01-01T23:59:59.000Z

275

Sustainable SDI for EU noise mapping in NRW best practice for INSPIRE  

E-Print Network [OSTI]

Infrastructure GDI NRW. NRW provides for the first time statewide 3D geodata as features in CityGML via OGC Web, INSPIRE, web services, CityGML, GDI NRW 1. INTRODUCTION The Environmental Noise Directive of the European: sustainable use and enlargement of the Spatial Data Infrastructure GDI NRW for EU noise mapping. Web services

Behnke, Sven

276

GEE Workshop, Mnchen, 6 Juni 2008 The EU Policy Framework for the Promotion  

E-Print Network [OSTI]

production but also distribution and end-use pose enormous challenges ­ Hydrogen and fuel cells are still to hydrogen and fuel cell development ­ Regional dimension/cluster policy We therefore address the following questions ­ To what extent is the current EU policy framework conducive to hydrogen and fuel cell

277

Inventory logistics cost analysis model for the proposed EU intermodal loading unit -- A business case  

Science Journals Connector (OSTI)

This study focuses on the new initiative of the European Union (EU) which deals with simplifying the intermodal product shipment approach that may lead to improvement in the available transportation logistics infrastructure. The analysis involves determining ... Keywords: Intermodal loading unit, buffer stock, intermodal platforms, intermodal transportation, inventory in transit, logistics cost model, multimodal transportation

Sameer Kumar

2008-08-01T23:59:59.000Z

278

Ris DTU Dec.3 2009WindScanner.eu 1 Ris DTU, Technical University of Denmark  

E-Print Network [OSTI]

engulfing today's and tomorrows huge on and offshore wind turbines. - a brig less RI for renewable energy IWES (onshore sites, Alpha Ventus ­ FINO 1- 3 offshore) · Norway: SINTEF (offshore technology, floatingScanner.eu Envisioned new RI European Centre for Wind Energy Research in Atmospheric Turbulent Flow "The Wind

279

-News Home Help Chirac defends planned EU arms sales to China to nervous Japan  

E-Print Network [OSTI]

-News Home Help Chirac defends planned EU arms sales to China to nervous Japan Sun Mar 27,11:33 AM Union ( - ) arms embargo on China, telling a nervous Japan the move would not entail transfers ban, acknowledged that Japan was worried about arms sales to its neighbor and growing rival but said

280

Structural Properties of Eu-Doped GaN Investigated by Raman Spectroscopy  

SciTech Connect (OSTI)

Rare-earth (RE) impurities doped GaN are highly promising candidates for light emitting device applications due to their efficient electroluminescence properties at room temperature. Among those, Eu doped GaN has been identified as an excellent material for the red spectral region due to its strong emission at 620 nm. As a transition internal to the Eu doping atom (4f-4f), light emission originates in a much smaller complex than the more flexibly controllable quantum structures of wells, wires, and dots. This is thought to make the center less susceptible to structural defects and in particular radiation damage in the lattice host. Nevertheless, the lattice host is crucial for providing the excitation in from of free electrons and holes. In this respect, the actual lattice site Eu occupies in the host lattice, i.e. in GaN, is important. A large fraction of Eu atoms are typically inactive which must be attributed to their lattice site and local environment. GaN films implanted with Eu to concentrations of {approx}10{sup 18} cm{sup -3} were subjected to a highly directed beam of 500 keV He{sup +} at a dose of 5 x 10{sup 14} cm{sup -2}. By means of a shadow mask, irradiated and unexposed regions lie very close to each other on the same sample. We used optical and structural analysis to identify the exerted radiation damage. At the full radiation dose, photoluminescence intensity has decayed to {approx}0.01 of its initial value. From the dose dependence of the radiation decay we previously concluded, that this decay is in part due to the destruction of radiative Eu sites [J.W. Tringe, unpublished (2006)]. Along the transition from virgin to irradiated material we analyze the accumulated damage in terms of surface morphology (atomic force microscopy), crystallinity (x-ray diffraction), and phonon dispersion using micro-Raman spectroscopy. In addition to the well-studied E{sub 2}(high) mode, two new vibrational modes at 659 cm{sup -1} and 201 cm{sup -1} were observed in the Eu implanted and annealed sample, prior to He{sup +} irradiation. These modes are either remnants of the implantation damage or related to the Eu impurity. As such they can be indicative of the actual lattice site the Eu atom resides on. After irradiation, broad Raman modes at 300 cm-1 are being observed. This band indicates disorder activated Raman scattering (DARS) due to the radiation damage. An additional narrow mode appears at 672 cm{sup -1}, which can possibly be due to a nitrogen vacancy related vibrational mode. The continuous transition from irradiated to un-irradiated sample allows the direct evolution of radiation damage and its coordinated effects in structural, optical and vibrational properties. By its systematic correlation we anticipate to be able to elucidate the Eu lattice interaction and the processes of radiation damage.

Senawiratne, J; Xia, Y; Detchprohm, T; Tringe, J W; Stevens, C G; Wetzel, C

2006-06-20T23:59:59.000Z

Note: This page contains sample records for the topic "butyl ether eu" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Use of Nonionic Poly(Ethylene glycol) p-Isooctyl-Phenyl Ether (Triton X-100) Surfactant Mobile Phases in the Thin-Layer Chromatography of Heavy-Metal Cations  

Science Journals Connector (OSTI)

......Article The analytical potential of poly(ethylene glycol) p-isooctyl-phenyl ether...40, March 2002 Use of Nonionic Poly(Ethylene glycol) p-Isooctyl-Phenyl Ether...Bidlingmeyer, S.N. Deming, W.P. Price, B. Sachok, and M. Petrusek. Retention......

Ali Mohammad; Eram Iraqi; Iftkhar Alam Khan

2002-03-01T23:59:59.000Z

282

Chemical Recycling of Carbon Dioxide to Methanol and Dimethyl Ether: From Greenhouse Gas to Renewable, Environmentally Carbon Neutral Fuels and Synthetic Hydrocarbons  

Science Journals Connector (OSTI)

Chemical Recycling of Carbon Dioxide to Methanol and Dimethyl Ether: From Greenhouse Gas to Renewable, Environmentally Carbon Neutral Fuels and Synthetic Hydrocarbons ... (1, 3-6) Methanol and derived dimethyl ether (DME) are also excellent fuels in internal combustion engines (ICE) and in a new generation of direct oxidation methanol fuel cells (DMFC), as well as convenient starting materials for producing light olefins (ethylene and propylene) and subsequently practically any derived hydrocarbon product. ... Methanol produced this way was used in the 19th century for lighting, cooking, and heating purposes but was later replaced by cheaper fuels, especially kerosene. ...

George A. Olah; Alain Goeppert; G. K. Surya Prakash

2008-12-08T23:59:59.000Z

283

Scanning tunneling microscopy study of the Eu-induced Ge(111)-(3×2)?(3×4) reconstruction  

Science Journals Connector (OSTI)

Eu-induced (3×2) reconstruction of the Ge(111) surface has been investigated by scanning tunneling microscopy (STM). The empty-state STM images show the chainlike atomic structure that is similar to those of the metal-induced Si(111)-(3×2) surfaces with an adsorbate coverage of 1?6 monolayer (ML). The filled-state STM images combined with the empty-state images at the low bias voltage reveal that the Ge arrangement of Eu?Ge(111)-(3×2) can be well interpreted in terms of the honeycomb chain-channel (HCC) model with the characteristic Ge?Ge double bond and slightly modified Ge honeycomb chains which are similar to those of the 1?6-ML HCC structure of Si(111)-(3×2). In addition, the Eu?Ge(111)-(3×2) surface is found to have a local ×4 periodicity along Eu chains, which can be explained, based on the analysis of STM line profiles, with two nonequivalent adsorption sites occupied by the Eu atoms in the empty channels of the HCC structure. The structural modifications of the Ge honeycomb chains as well as the origin of the ×2 and ×4 chains of Eu atoms in the HCC structure on the Eu?Ge(111) surface are discussed.

M. Kuzmin; P. Laukkanen; R. E. Perälä; I. J. Väyrynen

2006-03-23T23:59:59.000Z

284

Power Europe: EU and the illegal, unreported and unregulated tuna fisheries regulation in the West and Central Pacific Ocean  

Science Journals Connector (OSTI)

Abstract Illegal, unreported and unregulated (IUU) fishing activities are widely considered a main cause of unsustainable fisheries across the globe. The EU has taken a leading role in the fight against IUU fishing, using both its market and normative power to advance its EU IUU Regulation (no. 1005/2008) and wider fisheries sustainability agenda outside its territory. This paper examines how successful the EU has been in using its market and normative power to influence regulatory strategies and frameworks governing tuna fisheries in the Pacific Islands region of the Western Pacific Ocean. The results indicate that while the market power of the EU remains an influential factor, the diminishing normative power of the EU in WCPO is weakening any attempts to implement its IUU fishing regulation and Pacific Island nations have promoted their own regulatory agenda. We conclude that the changing asymmetries between market and normative power has led to a differentiated geography of regulatory uptake, and while market power will remain a dominant strategy for the EU, normative power, when exercised should focus on cooperation rather than ‘teaching’ the benefits of an EU regulatory approach.

Alice M.M. Miller; Simon R. Bush; Arthur P.J. Mol

2014-01-01T23:59:59.000Z

285

Experimental investigation on thermal barrier coated diesel engine fueled with diesel-biodiesel-ethanol-diethyl ether blends  

Science Journals Connector (OSTI)

In the present work diesel-biodiesel-ethanol (DBE) and diesel-biodiesel-diethyl ether (DBD) fuels are tested with normal diesel engine and the diesel engine coated with the layers of aluminum oxide (Al 2O3) of 0.3?mm and yttria-stabilized zirconia of 0.2?mm. The various performance and emission parameters are analyzed and determined. The experimental work was carried out in a single cylinder water cooled engine coupled with eddy current dynamometer. The AVL make five gas analyzer and smoke meter were used to measure the different exhaust pollutants. The result shows that the brake thermal efficiency of coated engine is more than that of base diesel at high loads. The thermal barrier coated engine using fuel as diesel biodiesel and ethanol (TDBE) produces the lowest carbon monoxide (CO) emissions among all the fuels that are selected. In addition it produces the lowest carbon dioxide (CO2) at higher loads. Both the thermal barrier coated engine using fuel as diesel biodiesel and diethyl ether (TDBD) and TDBE have higher NOx emissions among almost all the fuels used. The TDBE and TDBD have higher smoke emissions at initial loads but eventually show lower smoke emissions at higher loads. The thermal barrier coated diesel engine fueled with DBE and DBD shows an increase in engine power and specific fuel consumption as well as significant improvements in exhaust gas emissions except NOx.

2013-01-01T23:59:59.000Z

286

EuAl2 at pressures up to 41 GPa: A localized magnet exhibiting highly nonlinear electronic effects  

Science Journals Connector (OSTI)

Eu151 Mössbauer studies under hydrostatic pressures up to 41 GPa coupled to x-ray diffraction measurements show that—contrary to expectations—the 4f electrons in EuAl2 remain fully localized even under a reduction of unit cell volume of ?30%. However, strongly nonlinear effects are observed for the conduction electron polarization, for the s-electron density ?(0) at the Eu151 nucleus, the Néel temperature TN, and the transferred hyperfine field hyperbolically; TN and Bthf connected to ?(0). The latter results can be described quantitatively within the RKKY formalism.

A. Gleissner; W. Potzel; J. Moser; G. M. Kalvius

1993-03-29T23:59:59.000Z

287

Modeling of the simultaneous extraction of nitric acid and uranyl nitrate with tri-n-butyl phosphate. Application to extraction operation  

SciTech Connect (OSTI)

A mathematical model developed for the equilibrium HNO{sub 3}-UO{sub 2}(NO{sub 3}){sub 2}-tri-n-butyl phosphate (TBP)-diluent is the basis of the computation of distribution isotherms. The isotherms are used to study the influence of TBP concentration on two chosen operation parameters, distribution coefficients and number of theoretical stages, for the selected flow sheets. It is established that an increase in TBP concentration leads to a decrease in the number of theoretical stages for the extraction flow sheets but to their increase for the striping flow sheets. Given diagrams can be used to determine the efficiency of extraction processes. Agreement with available literature calculations on the number of theoretical stages supports the use of the model in the computation of distribution isotherms, of the system quoted above, in a wide range of nitric acid, uranyl nitrate, and TBP concentrations.

Comor, J.J.; Tolic, A.S.; Kopecni, M.M.; Petkovic, D.M. [Vinca Inst. of Nuclear Sciences, Belgrade (Yugoslavia). Chemical Dynamics Lab.] [Vinca Inst. of Nuclear Sciences, Belgrade (Yugoslavia). Chemical Dynamics Lab.

1999-01-01T23:59:59.000Z

288

Tilting of the CuO6 octahedra in La1.83-xEu0.17SrxCuO4 as seen by Eu151 Mössbauer spectroscopy  

Science Journals Connector (OSTI)

Eu151 Mössbauer studies of La1.83-xEu0.17SrxCuO4 for 0<~x<~0.26 exhibit a quadrupole interaction at the Eu site whose magnitude eQVzz strongly depends on both the Sr content x and the temperature T. For a fixed temperature, a linear relationship is obtained between the quadrupole interaction and the averaged CuO6 octahedra tilting angle determined from diffraction studies. The unusually large temperature dependence of eQVzz strongly indicates a temperature dependence of the local structure. In contrast to recent studies of the local structure La2CuO4-type superconductors by means of x-ray-absorption and neutron-scattering techniques, our data give strong evidence that the local octahedra tilting in La1.83-xEu0.17SrxCuO4 corresponds well to the average tilting obtained by diffraction techniques.

C. Friedrich; B. Büchner; M. M. Abd-Elmeguid; H. Micklitz

1996-07-01T23:59:59.000Z

289

Level crossing investigation of the hyperfine splitting in thez 6 P 7/2-level of EuI  

Science Journals Connector (OSTI)

By means of a level crossing experiment the hyperfine structure constants of thez 6 P 7/2-level of Eu have been determined. The results areA=-6.51(6) MHz andB= 131....

W. Lange

1975-01-01T23:59:59.000Z

290

Over-allocation or abatement? : a preliminary analysis of the EU ETS based on the 2005 emission data  

E-Print Network [OSTI]

This paper provides an initial analysis of the EU ETS based on the installation-level data for verified emissions and allowance allocations in the first trading year. Those data, released on May 15, 2006, and subsequent ...

Ellerman, A. Denny

2006-01-01T23:59:59.000Z

291

The electronic structure and photoluminescence properties of BiOCl:Eu3+ from first-principles calculations  

Science Journals Connector (OSTI)

Abstract Europium-doped luminescent heavy metal bismuth oxychloride has been investigated by first-principles calculation, and the crystal structure, electronic structure, and optical properties of pure BiOCl and Eu-doped BiOCl have been examined and compared. Based on the calculated results, the luminescence properties and mechanism of Eu-doped BiOCl has been discussed. Owing to the unique layered structure, BiOCl host could produce enough separated electron–hole pairs, under UV-light excitation. Furthermore, because the energy levels (5D0) of Eu3+ is matched with the energy bands (the bottom of conduction band) of BiOCl, the energy transport and charge transfer from host to luminescence center can be efficiently carried out. Thus, the photoluminescence of Eu3+ could be enhanced in the matrix of BiOCl. These findings are helpful to understand previously published experimental results, and to improve novel luminescence materials.

Jun Yi; Zong-Yan Zhao

2014-01-01T23:59:59.000Z

292

Extension of EU Emissions Trading Scheme to Other Sectors and Gases: Consequences for Uncertainty of Total Tradable Amount  

Science Journals Connector (OSTI)

Emissions trading in the European Union (EU), covering...2...from combustion and selected industrial processes in large installations), began in 2005. During the first commitment period of the Kyoto Protocol (200...

S. Monni; S. Syri; R. Pipatti; I. Savolainen

2007-01-01T23:59:59.000Z

293

Extension of EU Emissions Trading Scheme to Other Sectors and Gases: Consequences for Uncertainty of Total Tradable Amount  

Science Journals Connector (OSTI)

Emissions trading in the European Union (EU), covering...2...from combustion and selected industrial processes in large installations), began in 2005. During the first commitment period of the Kyoto Protocol (200...

S. Monni; S. Syri; R. Pipatti; I. Savolainen

2007-09-01T23:59:59.000Z

294

Thermoanalytical Studies of Ga-substituted MBa2Cu3O7–? Superconducting Compounds Formation (M=Yb, Eu)  

Science Journals Connector (OSTI)

A thermoanalytical study in non-isothermal conditions was realized on Ga-substituted MBa2Cu3O7-? superconducting compounds formation (M=Yb, Eu). The presence of different oxides in the reaction mixtures leads to ...

R. Redac; M. Zaharescu

295

(2/94)(2-4,9/95)(7/97)(11,12/98)(1,9,11/99) Neuman Chapter 3 Haloalkanes, Alcohols, Ethers, and Amines  

E-Print Network [OSTI]

, Ethers, and Amines from Organic Chemistry by Robert C. Neuman, Jr. Professor of Chemistry, emeritus://web.chem.ucsb.edu/~neuman/orgchembyneuman/> Chapter Outline of the Book ************************************************************************************** I. Foundations 1. Organic Molecules and Chemical Bonding 2. Alkanes and Cycloalkanes 3. Haloalkanes

Reed, Christopher A.

296

Role of Endocytosis in the Action of Ether Lipids on WEHI-3B, HL60, and FDCP-Mix A4 Cells  

Science Journals Connector (OSTI)

...Lipid by WEHI-3B Cells Has an Energy- dependent and an Energy-independent Component. Uptake...protective agents, suggested that the energy-dependent component of ether...of ET-18-OCH., by FDCP-mix A4 cells was measured, it was...

G. W. Bazill and T. M. Dexter

1990-12-01T23:59:59.000Z

297

EU-UNDP Low Emission Capacity Building Programme (LECBP) | Open Energy  

Open Energy Info (EERE)

(LECBP) (LECBP) Jump to: navigation, search Name EU-UNDP Low Emission Capacity Building Programme (LECBP) Agency/Company /Organization The European Union (EU), United Nations Development Programme (UNDP), German Federal Ministry for the Environment, Nature Conservation and Nuclear Safety (BMU), Australian Department of Climate Change and Energy Efficiency (DCCEE), Australian Agency for International Development (AusAID) Partner Multiple Ministries Sector Climate Focus Area Renewable Energy, Non-renewable Energy, Agriculture, Biomass, Buildings, Economic Development, Energy Efficiency, Forestry, Geothermal, Goods and Materials, Greenhouse Gas, Industry, Land Use, Offsets and Certificates, People and Policy, Solar, Transportation, Water Power, Wind Topics Background analysis, Baseline projection, Co-benefits assessment, - Energy Access, - Environmental and Biodiversity, Finance, GHG inventory, Implementation, Low emission development planning, -LEDS, -NAMA, -Roadmap, Market analysis, Pathways analysis, Policies/deployment programs, Resource assessment

298

Dipole Relaxation, Aggregation, and X-Ray Effects in KCl Doped with Eu++, Yb++, or Sm++  

Science Journals Connector (OSTI)

The behavior of impurity-vacancy (I-V) dipoles has been studied in KCl single crystals doped with Eu++, Yb++, or Sm++, using the ionic-thermocurrents technique. The activation energies and frequency factors for dipole relaxation have been determined. The aggregation of these dipoles in KCl: Eu++ follows third-order kinetics in the temperature range 295-323 °K, and their decay rate is comparable to that of KCl: Sr++. The activation energy and frequency factor for the formation of trimers have also been determined. It has proved possible to destroy these rare-earth I-V dipolar systems by irradiation with x rays, and to recover them on subsequent heating or irradiation with a Xe-Hg lamp. This process is postulated to take place through charge conversion of the I-V dipole constituents.

S. Unger and M. M. Perlman

1972-11-15T23:59:59.000Z

299

Mapping cultural ecosystem services: A framework to assess the potential for outdoor recreation across the EU  

Science Journals Connector (OSTI)

Abstract Research on ecosystem services mapping and valuing has increased significantly in recent years. However, compared to provisioning and regulating services, cultural ecosystem services have not yet been fully integrated into operational frameworks. One reason for this is that transdisciplinarity is required to address the issue, since by definition cultural services (encompassing physical, intellectual, spiritual interactions with biota) need to be analysed from multiple perspectives (i.e. ecological, social, behavioural). A second reason is the lack of data for large-scale assessments, as detailed surveys are a main source of information. Among cultural ecosystem services, assessment of outdoor recreation can be based on a large pool of literature developed mostly in social and medical science, and landscape and ecology studies. This paper presents a methodology to include recreation in the conceptual framework for EU wide ecosystem assessments (Maes et al., 2013), which couples existing approaches for recreation management at country level with behavioural data derived from surveys and population distribution data. The proposed framework is based on three components: the ecosystem function (recreation potential), the adaptation of the Recreation Opportunity Spectrum framework to characterise the ecosystem service and the distribution of potential demand in the EU. Results show that 38% of the EU is characterised by a high outdoor recreation potential, which is easily accessible, and that such areas can host about 35.4% of potential demand for close-to-home trips (recreation potential as an ecosystem service to EU citizens, to describe through country profiles differences in ecosystem service provision at regional level, and can be used as an input to land use planning processes.

Maria Luisa Paracchini; Grazia Zulian; Leena Kopperoinen; Joachim Maes; Jan Philipp Schägner; Mette Termansen; Marianne Zandersen; Marta Perez-Soba; Paul A. Scholefield; Giovanni Bidoglio

2014-01-01T23:59:59.000Z

300

Emission Properties of Eu{sup 3+} Doped Different Chlorophosphate Glasses  

SciTech Connect (OSTI)

Absorption and emission spectra of 0.5 mol% of Eu{sup 3+} in different chlorophosphate glasses have been studied. Judd-Ofelt analysis was performed to evaluate the emission properties such as radiative transition probabilities (A{sub rad}), branching ratios ({beta}), radiative lifetimes ({tau}{sub R}) and emission cross-sections ({sigma}{sub P}) for observed emission transitions of emission spectra of these glass matrices.

Rao, K. Venkata; Seshadri, M.; Ratnakaram, Y. C. [Sri Venkateswara University, Tirupati, A.P. (India)

2011-07-15T23:59:59.000Z

Note: This page contains sample records for the topic "butyl ether eu" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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301

Anomalies in Ultra-High-Field Magnetic Superconductors (Eu1-xSnx)Mo6S8  

Science Journals Connector (OSTI)

Resistive behavior of three series of Chevrel phase, (Eu1-xSnx)Mo6S7, (Eu1-xSnx)Mo6S6.75 and (Eu1-xSnx)0.9Mo6S6.75, is studied in magnetic fields up to 90 kOe at temperatures down to 50 mK. Compounds with x>0.4 are usual ultra-high-field superconductors, while (Eu0.9Sn0.1)0.9Mo6S6.75 is a simple magnetic superconductor. Resistive behavior of the compounds between the above mentioned two sides is complicated, varying with the composition. For example, in (Eu0.8Sn0.2)Mo6S7 the resistance at high fields keeps roughly constant and the temperature dependence of Hc2 defined as a half of the resistance in the normal state is quite different with that defined at the appearance of the resistance. In (Eu0.85Sn0.15)Mo6S7 the superconductivity (=zero resistance) seems to reappear at high fields and at low temperatures.

Masahiro Isino; Norio Kobayashi; Yoshio Muto

1980-01-01T23:59:59.000Z

302

Reactions of 15-crown-5 and bis-15-crown-5 ethers with metal acetylacetonate ions in the gas phase  

SciTech Connect (OSTI)

A study was carried out on the ion-molecule reactions of ions arising in the dissociation of ferric, cobaltic, chromic, manganous, neodymium(II), gallium(III), and indium(III) acetylacetonates upon electron impact with 15-crown-5 and bis-15-crown-5. The ratio of the yields of (acac)x-1 /SUP M+L/ ions is determined by the case of reduction of M /SUP x+1+/ to M /SUP x+/ and for (acac)/sub 3/M complexes, this ratio decreases in the series Nd, In, GA > Cr > Fe, Co. The rate constant for the formation of acacCoL/sup +/ ions is greater than for acacFeL/sup +/ ions. The possibility of fixing transition metals in unstable oxidation states by crown ethers is demonstrated in the case of nickel.

Timofeev, O.S.; Bogatskii, A.V.; Gren, A.I.; Lobach, A.V.; Nekarsov, Y.S.; Zagorevskii, D.V.

1985-05-20T23:59:59.000Z

303

Single-Step Syngas-to-Distillates (S2D) Synthesis via Methanol and Dimethyl Ether Intermediates: Final Report  

SciTech Connect (OSTI)

The objective of the work was to enhance price-competitive, synthesis gas (syngas)-based production of transportation fuels that are directly compatible with the existing vehicle fleet (i.e., vehicles fueled by gasoline, diesel, jet fuel, etc.). To accomplish this, modifications to the traditional methanol-to-gasoline (MTG) process were investigated. In this study, we investigated direct conversion of syngas to distillates using methanol and dimethyl ether intermediates. For this application, a Pd/ZnO/Al2O3 (PdZnAl) catalyst previously developed for methanol steam reforming was evaluated. The PdZnAl catalyst was shown to be far superior to a conventional copper-based methanol catalyst when operated at relatively high temperatures (i.e., >300°C), which is necessary for MTG-type applications. Catalytic performance was evaluated through parametric studies. Process conditions such as temperature, pressure, gas-hour-space velocity, and syngas feed ratio (i.e., hydrogen:carbon monoxide) were investigated. PdZnAl catalyst formulation also was optimized to maximize conversion and selectivity to methanol and dimethyl ether while suppressing methane formation. Thus, a PdZn/Al2O3 catalyst optimized for methanol and dimethyl ether formation was developed through combined catalytic material and process parameter exploration. However, even after compositional optimization, a significant amount of undesirable carbon dioxide was produced (formed via the water-gas-shift reaction), and some degree of methane formation could not be completely avoided. Pd/ZnO/Al2O3 used in combination with ZSM-5 was investigated for direct syngas-to-distillates conversion. High conversion was achieved as thermodynamic constraints are alleviated when methanol and dimethyl are intermediates for hydrocarbon formation. When methanol and/or dimethyl ether are products formed separately, equilibrium restrictions occur. Thermodynamic relaxation also enables the use of lower operating pressures than what would be allowed for methanol synthesis alone. Aromatic-rich hydrocarbon liquid (C5+), containing a significant amount of methylated benzenes, was produced under these conditions. However, selectivity control to liquid hydrocarbons was difficult to achieve. Carbon dioxide and methane formation was problematic. Furthermore, saturation of the olefinic intermediates formed in the zeolite, and necessary for gasoline production, occurred over PdZnAl. Thus, yield to desirable hydrocarbon liquid product was limited. Evaluation of other oxygenate-producing catalysts could possibly lead to future advances. Potential exists with discovery of other types of catalysts that suppress carbon dioxide and light hydrocarbon formation. Comparative techno-economics for a single-step syngas-to-distillates process and a more conventional MTG-type process were investigated. Results suggest operating and capital cost savings could only modestly be achieved, given future improvements to catalyst performance. Sensitivity analysis indicated that increased single-pass yield to hydrocarbon liquid is a primary need for this process to achieve cost competiveness.

Dagle, Robert A.; Lebarbier, Vanessa MC; Lizarazo Adarme, Jair A.; King, David L.; Zhu, Yunhua; Gray, Michel J.; Jones, Susanne B.; Biddy, Mary J.; Hallen, Richard T.; Wang, Yong; White, James F.; Holladay, Johnathan E.; Palo, Daniel R.

2013-11-26T23:59:59.000Z

304

Single-Step Syngas-to-Dimethyl Ether Processes for Optimal Productivity, Minimal Emissions, and Natural Gas-Derived Syngas  

Science Journals Connector (OSTI)

Single-step conversion of synthesis gas (syngas, H2/CO mixture) to dimethyl ether (DME, CH3OCH3) is very attractive as a route for indirect coal liquefaction, natural gas utilization, and production of synthetic liquid fuels, fuel additives, and chemicals. ... The main driving force for developing a single-step syngas-to-DME process is to produce DME at a cost lower than that from the commercially available two-step process, namely, syngas-to-methanol followed by methanol dehydration in sequential reactors. ... Furthermore, the composition of most commercially available syngas (except that produced by a CO2?methane reformer) is not the optimal composition (1:1 H2:CO) for the syngas-to-DME reactor. ...

X. D. Peng; A. W. Wang; B. A. Toseland; P. J. A. Tijm

1999-09-28T23:59:59.000Z

305

ANNUAL TRILATERAL U.S. – EU – JAPAN CONFERENCE ON CRITICAL MATERIALS FOR A CLEAN ENERGY FUTURE, SEPTEMBER 8-9, 2014  

Broader source: Energy.gov [DOE]

Agenda from the fourth meeting of the Annual Trilateral U.S. – EU – Japan Conference on Critical Materials for a Clean Energy Future

306

Annual Trilateral U.S. – EU – Japan Conference on Critical Materials for a Clean Energy Future, October 4-5, 2011  

Broader source: Energy.gov [DOE]

Agenda from the first meeting of the Annual Trilateral U.S. – EU – Japan Conference on Critical Materials for a Clean Energy Future

307

Ethynyl terminated ethers. Synthesis and thermal characterization of 2,2 bis (ethynyl-4-phenylcarbonyl-4-phenoxy-4-phenyl) propane and 2,2 bis (ethynyl-4-phenylsulfonyl-4-phenoxy-4-phenyl) propane  

Science Journals Connector (OSTI)

Two ethynyl end-capped ethers 2,2 Bis [ethynyl-4-phenylsulfonyl-4-phenoxy-4-phenyl] propane and 2,2 Bis [ethynyl-4-phenylcarbonyl-4-phenoxy-4-phenyl] propane have been prepared by a three steps...

Georges Lucotte; Laurent Cormier; Bruno Delfort

1990-12-01T23:59:59.000Z

308

Efficient production of 5-hydroxymethylfurfural through the dehydration of sugars with caprolactam hydrogen sulfate ([CPL]HSO4) ionic liquid catalyst in a water/proprylene glycol monomethyl ether mixed solvent  

Science Journals Connector (OSTI)

Efficient production of 5-hydroxymethylfurfural (HMF) through the dehydration of sugars...4) ionic liquid or using metal halide as the co-catalyst in a new water/proprylene glycol monomethyl ether solvent system....

Pingzhen Huang; Aijuan Gu; Jinxing Wang

2014-04-01T23:59:59.000Z

309

Fluctuating micro-heterogeneity in water–tert-butyl alcohol mixtures and lambda-type divergence of the mean cluster size with phase transition-like multiple anomalies  

SciTech Connect (OSTI)

Water–tert-butyl alcohol (TBA) binary mixture exhibits a large number of thermodynamic and dynamic anomalies. These anomalies are observed at surprisingly low TBA mole fraction, with x{sub TBA} ? 0.03–0.07. We demonstrate here that the origin of the anomalies lies in the local structural changes that occur due to self-aggregation of TBA molecules. We observe a percolation transition of the TBA molecules at x{sub TBA} ? 0.05. We note that “islands” of TBA clusters form even below this mole fraction, while a large spanning cluster emerges above that mole fraction. At this percolation threshold, we observe a lambda-type divergence in the fluctuation of the size of the largest TBA cluster, reminiscent of a critical point. Alongside, the structure of water is also perturbed, albeit weakly, by the aggregation of TBA molecules. There is a monotonic decrease in the tetrahedral order parameter of water, while the dipole moment correlation shows a weak nonlinearity. Interestingly, water molecules themselves exhibit a reverse percolation transition at higher TBA concentration, x{sub TBA} ? 0.45, where large spanning water clusters now break-up into small clusters. This is accompanied by significant divergence of the fluctuations in the size of largest water cluster. This second transition gives rise to another set of anomalies around. Both the percolation transitions can be regarded as manifestations of Janus effect at small molecular level.

Banerjee, Saikat; Furtado, Jonathan; Bagchi, Biman, E-mail: bbagchi@sscu.iisc.ernet.in [SSCU, Indian Institute of Science, Bangalore 560012 (India)] [SSCU, Indian Institute of Science, Bangalore 560012 (India)

2014-05-21T23:59:59.000Z

310

Transport study of hafnium(IV) and zirconium(IV) ions mutual separation by using Tri-n-butyl phosphate-xylene-based supported liquid membranes  

SciTech Connect (OSTI)

A Hf transport study through supported liquid membranes has been carried out to determine flux and permeability data for this metal ion. Tri-n-butyl phosphate (TBP)-xylene-based liquid membranes supported in polypropylene hydrophobic microporous film have been used. These data for hafnium and the previous data for zirconium have furnished the Zr to Hf flux ratio (S) as a function of nitric acid and TBP concentrations of the order of 12 in a single stage at room temperature. Optimum conditions for the separation of these two metal ions appear to 5-6 TBP mol/dm{sup 3} HNO{sub 3}, concentrations {le} 2.93 mol/dm{sup 3}, and 10C. The value of S from an aqueous solution containing 2.4% Hf with respect to Zr has been found to be >125 at 10C and 1.78 mol/dm{sup 3} TBP concentration in the membrane. The technique appears to be feasible for purification of Zr respect to Hf or vice versa.

Chaudry, M.A.; Ahmed, B. (Pakistan Inst. of Nuclear Science and Technology, Islamabad (Pakistan))

1992-02-01T23:59:59.000Z

311

Low-temperature CVD of iron, cobalt, and nickel nitride thin films from bis[di(tert-butyl)amido]metal(II) precursors and ammonia  

SciTech Connect (OSTI)

Thin films of late transition metal nitrides (where the metal is iron, cobalt, or nickel) are grown by low-pressure metalorganic chemical vapor deposition from bis[di(tert-butyl)amido]metal(II) precursors and ammonia. These metal nitrides are known to have useful mechanical and magnetic properties, but there are few thin film growth techniques to produce them based on a single precursor family. The authors report the deposition of metal nitride thin films below 300?°C from three recently synthesized M[N(t-Bu){sub 2}]{sub 2} precursors, where M?=?Fe, Co, and Ni, with growth onset as low as room temperature. Metal-rich phases are obtained with constant nitrogen content from growth onset to 200?°C over a range of feedstock partial pressures. Carbon contamination in the films is minimal for iron and cobalt nitride, but similar to the nitrogen concentration for nickel nitride. X-ray photoelectron spectroscopy indicates that the incorporated nitrogen is present as metal nitride, even for films grown at the reaction onset temperature. Deposition rates of up to 18?nm/min are observed. The film morphologies, growth rates, and compositions are consistent with a gas-phase transamination reaction that produces precursor species with high sticking coefficients and low surface mobilities.

Cloud, Andrew N.; Abelson, John R., E-mail: abelson@illinois.edu [Department of Materials Science and Engineering, University of Illinois at Urbana-Champaign, 201 Materials Science and Engineering Building, 1304 W. Green St., Urbana, Illinois 61801 (United States); Davis, Luke M.; Girolami, Gregory S., E-mail: girolami@scs.illinois.edu [School of Chemical Sciences, University of Illinois at Urbana-Champaign, 600 S. Mathews Ave., Urbana, Illinois 61801 (United States)

2014-03-15T23:59:59.000Z

312

Fluctuating micro-heterogeneity in water - tert-butyl alcohol mixtures and lambda-type divergence of the mean cluster size with phase transition-like multiple anomalies  

E-Print Network [OSTI]

Water - tert-butyl alcohol (TBA) binary mixture exhibits a large number of thermodynamic and dynamic anomalies. These anomalies are observed at surprisingly low TBA mole fraction, with $x_{\\text{TBA}} \\approx 0.03 - 0.07$. We demonstrate here that the origin of the anomalies lies in the local structural changes that occur due to self-aggregation of TBA molecules. We observe a percolation transition of the TBA molecules at $x_{\\text{TBA}} \\approx 0.05$. We note that "islands" of TBA clusters form even below this mole fraction, while a large spanning cluster emerges above that mole fraction. At this percolation threshold, we observe a lambda-type divergence in the fluctuation of the size of the largest TBA cluster, reminiscent of a critical point. Alongside, the structure of water is also perturbed, albeit weakly, by the aggregation of TBA molecules. There is a monotonic decrease in the tetrahedral order parameter of water, while the dipole moment correlation shows a weak non-linearity. Interestingly, water molecules themselves exhibit a reverse percolation transition at higher TBA concentration, $x_{\\text{TBA}} \\approx 0.45$, where large spanning water clusters now break-up into small clusters. This is accompanied by significant divergence of the fluctuations in the size of largest water cluster. This second transition gives rise to another set of anomalies around. Both the percolation transitions can be regarded as manifestations of Janus effect at small molecular level.

Saikat Banerjee; Jonathan Furtado; Biman Bagchi

2014-02-20T23:59:59.000Z

313

EU-UNDP Climate Change Capacity Building Program | Open Energy Information  

Open Energy Info (EERE)

Building Program Building Program Jump to: navigation, search Name UNDP/EC Climate Change Capacity Building Program Agency/Company /Organization The European Union (EU), United Nations Development Programme (UNDP) Partner Multiple Ministries Sector Climate, Energy Focus Area Renewable Energy, Agriculture, Biomass, Buildings, Energy Efficiency, Forestry, Geothermal, Greenhouse Gas, Industry, Land Use, Offsets and Certificates, People and Policy, Solar, Transportation, Water Power, Wind Topics Background analysis, Baseline projection, Co-benefits assessment, - Energy Access, - Environmental and Biodiversity, GHG inventory, Implementation, Low emission development planning, -LEDS, -NAMA, -Roadmap, -TNA, Policies/deployment programs, Resource assessment Website http://www.lowemissiondevelopm

314

Beyond limits and efficiency, what? Assessing developments in EU water policy  

Science Journals Connector (OSTI)

This paper documents a transformation of EU water policy from a standard-based approach towards a more diverse policy combining ecological, economic and social elements with an emphasis on institutional and participatory aspects. This is marked in a new Water Framework Directive. Analysis is supported by a theoretical discussion of different approaches to sustainability and recognition of the deadlock of an ecological limit vs. economic efficiency dichotomy. While an approach originating from works in institutional and ecological economics and emphasising processes, justice and collective decisions seems to break this impasse, it is not without its own conceptual problems.

Giorgos Kallis

2005-01-01T23:59:59.000Z

315

Advances in the design of co-poly(ether-imide) membranes for CO2 separations. Influence of aromatic rigidity on crystallinity, phase segregation and gas transport  

Science Journals Connector (OSTI)

Abstract In our previous works, it was observed a clear relationship between the structure and the properties for different copoly(ether-imide)s, besides a good relation was found between SAXS characterization and permeability results. Here, a series of aliphatic aromatic copoly(ether-imide)s, based on an aromatic diamine (ODA), a diamine terminated poly(ethylene oxide) (PEO2000) of a molecular weight of 2000 g/mol and different aromatic dianhydrides (BPDA, BKDA (or BTDA) and PMDA) has been synthesized and characterized. The permeability for O2, N2, CO2 and CH4, increased with the rigidity of the monomers (BKDA CO2/N2 separation. This work gives indications on how to design advanced materials for this separation with the increasing possibilities of controlled structure and properties.

Alberto Tena; Ángel Marcos-Fernández; Mónica de la Viuda; Laura Palacio; Pedro Prádanos; Ángel E. Lozano; Javier de Abajo; Antonio Hernández

2015-01-01T23:59:59.000Z

316

Polybrominated Diphenyl Ethers in U.S. Sewage Sludges and Biosolids: Temporal and Geographical Trends and Uptake by Corn Following Land Application  

Science Journals Connector (OSTI)

Robert C. Hale *, Mark J. La Guardia , Ellen Harvey , Da Chen , Thomas M. Mainor , and Drew R. Luellen , ... An internal standard (decachlorodiphenyl ether) was added and the final extracts were analyzed by gas chromatography/mass spectrometry (GC/MS) with electron-capture negative chemical ionization (EC-NCI). ... This work surveyed PBDE in spruce needles and air (gaseous and particle-bound) over an annual cycle to model PBDE accumulation in vegetation. ...

Robert C. Hale; Mark J. La Guardia; Ellen Harvey; Da Chen; Thomas M. Mainor; Drew R. Luellen; Lakhwinder S. Hundal

2012-01-26T23:59:59.000Z

317

Design and synthesis of the next generation of crown ethers for waste separations: An inter-laboratory comprehensive proposal. 1998 annual progress report  

SciTech Connect (OSTI)

'The purpose of this task is to undertake the design, synthesis, and characterization of the next generation of crown ethers for metal-ion separations applicable to USDOE''s environmental needs. Target problems include: Li{sup +} ions leaching from burial sites at the Oak Ridge Y-12 Plant; fission products 90 Sr and {sup 137}Cs contaminating high-level tank wastes at Hanford, INEEL, and Savannah River; and radium in wastes at the Niagara Falls Storage Site. Unfortunately, the technologies needed to address these problems either do not exist or exhibit substantial deficiencies. Separation techniques such as solvent extraction and ion exchange promise to play a strong role, especially as enhanced with highly selective crown ethers and calixarenes. This project is midway through year 2 of a 3-year effort. Below is given a summary of progress in the approximate period September, 1997, to May, 1998, for each of the four co-investigators at Pacific Northwest National Laboratory (PNNL), Argonne National Laboratory (ANL), Oak Ridge National Laboratory (ORNL), and the University of Tennessee (UTK). The overall approach entails utilization of theory and molecular modeling (PNNL), organic synthesis of novel crown compounds (ORNL), solvent extraction studies (ORNL and ANL), and studies of polymer-immobilized crown ethers (UTK).'

Moyer, B.A.; Hay, B.P.; Dietz, M.L.; Alexandratos, S.D.; Sachleben, R.A.; Chiarizia, R.

1998-06-01T23:59:59.000Z

318

Contribution of human capital to economic growth from the education policy point of view – empirical analysis for EU economies  

Science Journals Connector (OSTI)

Our research presented in this article is based on the macroeconomics background and addresses the following two questions in case of 27 EU-member states: 1) 'To what extent does education contribute to human capital?'; 2) 'What is the contribution of human capital to economic growth?' The main part of the article is empirical analysis that consists from: 1) the empirical estimates on the amount of human capital for EU27; 2) the empirical estimation about the contribution of human capital to economic growth for EU27; 3) the empirical analysis on relationship between the contribution of human capital to economic growth and the amount of public expenditure on education. We find the 5.14% of GDP as the amount of public spending on education that maximises the contribution of human capital to economic growth.

Matjaz Novak; Primoz Dolenc; Igor Stubelj; Mateja Jerman

2011-01-01T23:59:59.000Z

319

Ecological improvement and sustainable development in European skiing resorts by adapting the EU-Eco-Audit  

E-Print Network [OSTI]

The range of environmental problems in European skiing resorts caused by winter sports, agriculture and summer tourism are all well known. The issues and management challenges relate to sensitive ecological conditions, construction activities, deficiencies in visitor management and an land use conflicts during summer. One new approach to manage these problems is the EU-Eco-Audit. In test sites in Switzerland, Liechtenstein and Austria a successful adaptation of the EU-Eco-Audit framework to ski resorts has been developed. The implementation of the Audit framework at these test sites led to positive effects concerning visitor and ecological management. One influencing factor for the future development is the positive public image concerning environmental aspects. Crucial to the implementation of the Eco-Audit-framework is whether it will assist ski resorts in their competition with other destiantions for hosting international events. Finally the acceptance of the certificates or awards by skiers is discussed. It will be argued that due to the increasing relevance of information provision and marketing of wintersport destinations via the internet, the auditing or award concept contributes to a positive image of these enterprises and destinations in the market place. 2

Ulrike Pröbstl

320

Risk formulation for the sonic effects of offshore wind farms on fish in the EU region  

Science Journals Connector (OSTI)

In 2007, European leaders agreed to source 20% of their energy needs from renewable energy; since that time, offshore wind farms have been receiving attention in the European Union (EU). In 2008, the European Community submitted a proposal to the United Nations Environment Program (UNEP) in order to combat marine noise pollution. In consideration of these facts, the present paper aims to deduce a preliminary hypothesis and its formulation for the effect of offshore wind farm noise on fish. The following general picture is drawn: the short-term potential impact during pre-construction; the short-term intensive impact during construction; and the physiological and/or masking effects that may occur over a long period while the wind farm is in operation. The EU’s proposal to UNEP includes noise databases that list the origins of man-made sounds; it is advisable that offshore wind farms should be listed in the noise databases in order to promote rational environment management.

Ryunosuke Kikuchi

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "butyl ether eu" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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321

Smart Grids in the EU with smart regulation: Experiences from the UK, Italy and Portugal  

Science Journals Connector (OSTI)

Abstract The paper describes the integration between what used to be a passive element of the energy value chain – the grid – and both upstream and downstream elements. The evolution of communications among the elements has permitted a more robust and adaptable structure that already is being implemented: the Smart Grid. The paper relates the evolution of EU policy concerning both the development and the rolling-out of solutions to exploit the potential of the Smart Grid concept and describes what has been done by the regulators of three countries that share the same goal but seek to attain it via distinct paths. The article starts with a justification of the need for more integrated networks and a definition of the Smart Grid. A second part covers the risks and difficulties of implementation within an established network, introducing the role of the regulator. The third part describes EU policy response and three different approaches by regulators in the UK, Italy and Portugal, showing how in each case policy is influenced by characteristics of their respective national electricity markets in terms of competition dynamics.

João Crispim; José Braz; Rui Castro; Jorge Esteves

2014-01-01T23:59:59.000Z

322

Nanocrystalline BaSO{sub 4}:Eu For Dosimetry of Proton Beams  

SciTech Connect (OSTI)

Nanocrystalline BaSO{sub 4} doped with Eu, was prepared by the Chemical Co-precipitation method. The particle size was calculated by the broadening of the XRD peaks using Scherrer's formula with particle size around 45 nm. Samples in the form of pellets were irradiated by 150 MeV proton beam with dose range of 0.1 Gy to 325 Gy. Thermoluminescence (TL) glow curves of the irradiated samples were recorded and studied. It has been found that there are two prominent TL glow peaks at 460 K and 495 K. The TL response is sublinear below 1 Gy, linear in the range 1 Gy to 200 Gy and then becomes supralinear for higher doses. The wider linear TL response of nanocrystalline BaSO{sub 4}:Eu and low fading makes it a superior candidate as a dosimeter to be used for detecting the doses of protons for its various applications in the field of space, therapy and research.

Bahl, Shaila; Kumar, Pratik [Medical Physics Unit, IRCH, AIIMS, New Delhi-110029 (India); Lochab, S. P. [Inter-University Accelerator Center, Aruna Asaf Ali Marg, New Delhi - 110067 (India); Pandey, Anant [Department of Physics, Sri Venkateswara College, New Delhi-110021 (India); Aleynikov, V. E.; Molokanov, A. [Joint Institute for Nuclear Research, Dubna - 141980 (Russian Federation)

2011-07-15T23:59:59.000Z

323

EU Energy Renewables Ltd now part of DeWind | Open Energy Information  

Open Energy Info (EERE)

Ltd now part of DeWind Ltd now part of DeWind Jump to: navigation, search Name EU Energy (Renewables) Ltd (now part of DeWind) Place Irvine, California Zip 92614 Sector Renewable Energy Product Previously a subsidiary of EU Energy plc focused on researching renewable energy technologies, until acquisition by Composite Technology Corporation in 2006. Coordinates 41.837752°, -79.268594° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":41.837752,"lon":-79.268594,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

324

Controlled synthesis and optical properties of BaFBr:Eu{sup 2+} crystals via ethanol/water solutions  

SciTech Connect (OSTI)

Graphical abstract: A facile and cost-effective approach for the controlled synthesis of BaFBr:Eu{sup 2+} crystals is introduced. The structures and morphologies of the obtained products are affected by the amount of water and ethanol in the solvent mixtures. Highlights: ? Precipitation route for preparing BaFBr nano and micro crystals in water/ethanol solvent mixtures. ? Controlled growth of BaFBr nano crystals by tuning the volume ratio of Ethanol/water. ? Luminescence properties after annealing at 200 °C are investigated. ? Short lifetimes of photoluminescence and photostimulated luminescence in BaFBr:Eu{sup 2+} nano crystals are presented. ? Shortened lifetimes in BaFBr:Eu{sup 2+} nano crystals demonstrate that they are promising materials for use in X-ray imaging systems. -- Abstract: BaFBr:Eu{sup 2+} crystals with different structures were successfully fabricated via a simple precipitation method using ethanol/water mixtures as solvents. The amount of ethanol in the solvent mixtures played a significant role in the formation of final products, enabling the well-controlled growth of the BaFBr crystals. A possible formation mechanism was proposed based on the results of controlled experiments. The phases and morphologies of the resulting samples were systematically investigated by X-ray diffraction (XRD), field-emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), high-resolution TEM (HRTEM), selected area electron diffraction (SAED) and elementary analysis. The optical properties of the annealed BaFBr:Eu{sup 2+} nano-cuboids were investigated using photoluminescence (PL), photo-stimulated luminescence spectroscopy (PSL) and kinetic decays. Faster decay behaviors demonstrate that these BaFBr:Eu{sup 2+} phosphors are promising materials for applications in optical storage fields. Furthermore, it is envisaged that this environmentally benign method can be extended to prepare other fluoride halides.

Liang, Qinghua [Technical Institute of Physics and Chemistry, Chinese Academy of Sciences (CAS), 29 zhongguancun East Road, Beijing 100190 (China) [Technical Institute of Physics and Chemistry, Chinese Academy of Sciences (CAS), 29 zhongguancun East Road, Beijing 100190 (China); Graduate University of Chinese Academy of Sciences, Beijing 10039 (China); Li, Zhi, E-mail: lizhi@mail.ipc.ac.cn [Technical Institute of Physics and Chemistry, Chinese Academy of Sciences (CAS), 29 zhongguancun East Road, Beijing 100190 (China)] [Technical Institute of Physics and Chemistry, Chinese Academy of Sciences (CAS), 29 zhongguancun East Road, Beijing 100190 (China); Ma, Wangjing; Shi, Yao [Technical Institute of Physics and Chemistry, Chinese Academy of Sciences (CAS), 29 zhongguancun East Road, Beijing 100190 (China)] [Technical Institute of Physics and Chemistry, Chinese Academy of Sciences (CAS), 29 zhongguancun East Road, Beijing 100190 (China); Yang, Xinmin, E-mail: xmyang@mail.ipc.ac.cn [Technical Institute of Physics and Chemistry, Chinese Academy of Sciences (CAS), 29 zhongguancun East Road, Beijing 100190 (China)] [Technical Institute of Physics and Chemistry, Chinese Academy of Sciences (CAS), 29 zhongguancun East Road, Beijing 100190 (China)

2012-09-15T23:59:59.000Z

325

Promoting effect of polyoxyethylene octylphenol ether on Cu/ZnO catalysts for low-temperature methanol synthesis  

Science Journals Connector (OSTI)

Cu/ZnO catalysts were prepared by the co-precipitation method with the addition of OP-10 (polyoxyethylene octylphenol ether) and were chemically and structurally characterized by means of XRD, BET, H2-TPR, CO-TPD and N2O-titration. The effect of OP-10 addition on the activity of Cu/ZnO for the slurry phase methanol synthesis at 150 °C was evaluated. The results showed that Cu/ZnO prepared with addition of 8% OP-10 (denoted as C8) exhibited the promoted activity for the methanol synthesis. The conversion of CO and the STY (space time yield) of methanol were 42.5% and 74.6% higher than those of Cu/ZnO prepared without addition of OP-10 (denoted as C0), respectively. The precursor of C8 contained more aurichalcite and rosasite, and the concerted effect of Cu-Zn in C8 was found to be stronger than that in C0. Compared with C0, C8 showed smaller particle size, lower reduction temperature and larger BET and Cu surface areas.

Ling Liu; Tiansheng Zhao; Qingxiang Ma; Yufang Shen

2009-01-01T23:59:59.000Z

326

Ethoxyresorufin-O-deethylase induction potency of polychlorinated diphenyl ethers in H4IIE rat hepatoma cells  

SciTech Connect (OSTI)

Polychlorinated diphenyl ethers (PCDEs) are structurally similar to polychlorinated biphenyls (PCBs), and some PCDE congeners have been reported to cause toxic responses similar to those caused by some of the non-ortho-substituted PCBs, which are mediated by the aryl hydrocarbon receptor (AhR). Twenty-nine PCDEs were tested for their potency as AhR agonists relative to 2,3,7,8-tetrachlorodibenzo-p-dioxin (2,3,7,8-TCDD) by measuring their ability to induce the cytochrome P-450 1A1-associated enzyme activity, ethoxyresorufin-O-deethylase (EROD), in the H4IIE rat hepatoma cell bioassay. All PCDE congeners tested were found to be inactive as EROD inducers except for PCDE 156, which was a weak EROD inducer with a 2,3,7,8-TCDD equivalency factor of about 1.2 {times} 10{sup {minus}5}. During this study the authors determined that small amounts of polychlorinated dibenzofurans (PCDFs) that occurred as impurities in the PCDE preparations were the cause of the apparent EROD induction initially measured in their experiments. Once the PCDF impurities were removed by purification on florisil, little or no activity could be attributed to the PCDEs.

Koistinen, J.; Sanderson, J.T.; Giesy, J.P. [Michigan State Univ., East Lansing, MI (United States); Nevalainen, T.; Paasivirta, J. [Univ. of Jyvaeskylae (Finland). Dept. of Chemistry

1996-11-01T23:59:59.000Z

327

Investigation of HCCI Combustion of Diethyl Ether and Ethanol Mixtures Using Carbon 14 Tracing and Numerical Simulations  

SciTech Connect (OSTI)

Despite the rapid combustion typically experienced in Homogeneous Charge Compression Ignition (HCCI), components in fuel mixtures do not ignite in unison or burn equally. In our experiments and modeling of blends of diethyl ether (DEE) and ethanol (EtOH), the DEE led combustion and proceeded further toward completion, as indicated by {sup 14}C isotope tracing. A numerical model of HCCI combustion of DEE and EtOH mixtures supports the isotopic findings. Although both approaches lacked information on incompletely combusted intermediates plentiful in HCCI emissions, the numerical model and {sup 14}C tracing data agreed within the limitations of the single zone model. Despite the fact that DEE is more reactive than EtOH in HCCI engines, they are sufficiently similar that we did not observe a large elongation of energy release or significant reduction in inlet temperature required for light-off, both desired effects for the combustion event. This finding suggests that, in general, HCCI combustion of fuel blends may have preferential combustion of some of the blend components.

Mack, J H; Dibble, R W; Buchholz, B A; Flowers, D L

2004-01-16T23:59:59.000Z

328

Calcitriol inhibits Ether-a go-go potassium channel expression and cell proliferation in human breast cancer cells  

SciTech Connect (OSTI)

Antiproliferative actions of calcitriol have been shown to occur in many cell types; however, little is known regarding the molecular basis of this process in breast carcinoma. Ether-a-go-go (Eag1) potassium channels promote oncogenesis and are implicated in breast cancer cell proliferation. Since calcitriol displays antineoplastic effects while Eag1 promotes tumorigenesis, and both factors antagonically regulate cell cycle progression, we investigated a possible regulatory effect of calcitriol upon Eag1 as a mean to uncover new molecular events involved in the antiproliferative activity of this hormone in human breast tumor-derived cells. RT real-time PCR and immunocytochemistry showed that calcitriol suppressed Eag1 expression by a vitamin D receptor (VDR)-dependent mechanism. This effect was accompanied by inhibition of cell proliferation, which was potentiated by astemizole, a nonspecific Eag1 inhibitor. Immunohistochemistry and Western blot demonstrated that Eag1 and VDR abundance was higher in invasive-ductal carcinoma than in fibroadenoma, and immunoreactivity of both proteins was located in ductal epithelial cells. Our results provide evidence of a novel mechanism involved in the antiproliferative effects of calcitriol and highlight VDR as a cancer therapeutic target for breast cancer treatment and prevention.

Garcia-Becerra, Rocio [Department of Reproductive Biology, Instituto Nacional de Ciencias Medicas y Nutricion Salvador Zubiran, Vasco de Quiroga No. 15, Tlalpan 14000 Mexico, D.F. (Mexico)] [Department of Reproductive Biology, Instituto Nacional de Ciencias Medicas y Nutricion Salvador Zubiran, Vasco de Quiroga No. 15, Tlalpan 14000 Mexico, D.F. (Mexico); Diaz, Lorenza, E-mail: lorenzadiaz@gmail.com [Department of Reproductive Biology, Instituto Nacional de Ciencias Medicas y Nutricion Salvador Zubiran, Vasco de Quiroga No. 15, Tlalpan 14000 Mexico, D.F. (Mexico)] [Department of Reproductive Biology, Instituto Nacional de Ciencias Medicas y Nutricion Salvador Zubiran, Vasco de Quiroga No. 15, Tlalpan 14000 Mexico, D.F. (Mexico); Camacho, Javier [Department of Pharmacology, Centro de Investigacion y de Estudios Avanzados, Instituto Politecnico Nacional, Av. Instituto Politecnico Nacional 2508, San Pedro Zacatenco 07360, Mexico, D.F. (Mexico)] [Department of Pharmacology, Centro de Investigacion y de Estudios Avanzados, Instituto Politecnico Nacional, Av. Instituto Politecnico Nacional 2508, San Pedro Zacatenco 07360, Mexico, D.F. (Mexico); Barrera, David; Ordaz-Rosado, David; Morales, Angelica [Department of Reproductive Biology, Instituto Nacional de Ciencias Medicas y Nutricion Salvador Zubiran, Vasco de Quiroga No. 15, Tlalpan 14000 Mexico, D.F. (Mexico)] [Department of Reproductive Biology, Instituto Nacional de Ciencias Medicas y Nutricion Salvador Zubiran, Vasco de Quiroga No. 15, Tlalpan 14000 Mexico, D.F. (Mexico); Ortiz, Cindy Sharon [Department of Pathology, Instituto Nacional de Ciencias Medicas y Nutricion Salvador Zubiran, Vasco de Quiroga No. 15, Tlalpan 14000 Mexico, D.F. (Mexico)] [Department of Pathology, Instituto Nacional de Ciencias Medicas y Nutricion Salvador Zubiran, Vasco de Quiroga No. 15, Tlalpan 14000 Mexico, D.F. (Mexico); Avila, Euclides [Department of Reproductive Biology, Instituto Nacional de Ciencias Medicas y Nutricion Salvador Zubiran, Vasco de Quiroga No. 15, Tlalpan 14000 Mexico, D.F. (Mexico)] [Department of Reproductive Biology, Instituto Nacional de Ciencias Medicas y Nutricion Salvador Zubiran, Vasco de Quiroga No. 15, Tlalpan 14000 Mexico, D.F. (Mexico); Bargallo, Enrique [Department of Breast Tumors, Instituto Nacional de Cancerologia, Av. San Fernando No. 22, Tlalpan 14080, Mexico, D.F. (Mexico)] [Department of Breast Tumors, Instituto Nacional de Cancerologia, Av. San Fernando No. 22, Tlalpan 14080, Mexico, D.F. (Mexico); Arrecillas, Myrna [Department of Pathology, Instituto Nacional de Cancerologia, Av. San Fernando No. 22, Tlalpan 14080, Mexico, D.F. (Mexico)] [Department of Pathology, Instituto Nacional de Cancerologia, Av. San Fernando No. 22, Tlalpan 14080, Mexico, D.F. (Mexico); Halhali, Ali; Larrea, Fernando [Department of Reproductive Biology, Instituto Nacional de Ciencias Medicas y Nutricion Salvador Zubiran, Vasco de Quiroga No. 15, Tlalpan 14000 Mexico, D.F. (Mexico)] [Department of Reproductive Biology, Instituto Nacional de Ciencias Medicas y Nutricion Salvador Zubiran, Vasco de Quiroga No. 15, Tlalpan 14000 Mexico, D.F. (Mexico)

2010-02-01T23:59:59.000Z

329

Monodisperse porous polymer particles containing macrocyclic ether as a new class of sorbent for SR(II) separation  

SciTech Connect (OSTI)

Strontium{sup 90} is one of the typical fission products that may be found in high level liquid waste (HLLW). Separation of Sr{sup 90} prior to the vitrification is beneficial to the final treatment of solid radioactive waste. In this study, a new class of sorbent for Sr(II) was developed by loading the macrocyclic ether DtBuCH18C6 into the monodisperse porous polymer particles (MPPPs). The MPPPs are well-known as a promising chromatographic material due to the uniform particle size, porous morphology, good compatibility with organic extractants, and rigid matrix. The structure and micro-morphology of the sorbent particles were characterized. The adsorption behavior towards Sr(II) in HNO{sub 3} media was investigated by both batch and column experiments. High adsorption efficiency and selective separation of Sr(II) was obtained. The sorbent particles can be recycled for at least several times before obvious lose of the adsorption ability. This kind of sorbent possesses the potential to be used for strontium separation in radioactive liquid waste.

Leng, Yuxiao; Bai, Feifei [Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084 (China); Faculty of Chemical Science and Engineering, China University of Petroleum, Beijing 100084 (China); Ye, Gang; Wei, Jichao; Wang, Jianchen; Chen, Jing [Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084 (China)

2013-07-01T23:59:59.000Z

330

Synergistic effect of mixing dimethyl ether with methane, ethane, propane, and ethylene fuels on polycyclic aromatic hydrocarbon and soot formation  

SciTech Connect (OSTI)

Characteristics of polycyclic aromatic hydrocarbon (PAH) and soot formation in counterflow diffusion flames of methane, ethane, propane, and ethylene fuels mixed with dimethyl ether (DME) have been investigated. Planar laser-induced incandescence and fluorescence techniques were employed to measure relative soot volume fractions and PAH concentrations, respectively. Results showed that even though DME is known to be a clean fuel in terms of soot formation, DME mixture with ethylene fuel increases PAH and soot formation significantly as compared to the pure ethylene case, while the mixture of DME with methane, ethane, and propane decreases PAH and soot formation. Numerical calculations adopting a detailed kinetics showed that DME can be decomposed to produce a relatively large number of methyl radicals in the low-temperature region where PAH forms and grows; thus the mixture of DME with ethylene increases CH{sub 3} radicals significantly in the PAH formation region. Considering that the increase in the concentration of O radicals is minimal in the PAH formation region with DME mixture, the enhancement of PAH and soot formation in the mixture flames of DME and ethylene can be explained based on the role of methyl radicals in PAH and soot formation. Methyl radicals can increase the concentration of propargyls, which could enhance incipient benzene ring formation through the propargyl recombination reaction and subsequent PAH growth. Thus, the result substantiates the importance of methyl radicals in PAH and soot formation, especially in the PAH formation region of diffusion flames. (author)

Yoon, S.S. [Corporate Research and Development Division, Hyundai-Kia Motors, Gyeonggi-do 445-706 (Korea); Anh, D.H. [Korea Electric Power Research Institute, Daejeon 305-380 (Korea); Chung, S.H. [School of Mechanical and Aerospace Engineering, Seoul National University, Seoul 151-742 (Korea)

2008-08-15T23:59:59.000Z

331

Life cycle study of coal-based dimethyl ether as vehicle fuel for urban bus in China  

Science Journals Connector (OSTI)

With life cycle assessment (LCA) methodology, a life cycle model of coal-based dimethyl ether (CBDME) as a vehicle fuel is established for China. Its life cycle from well to wheel are divided into three phases. They are feedstock extraction, fuel production and fuel consumption in vehicle. The primary energy consumption (PEC) and global warming potential (GWP) of CBDME pathway are analyzed and compared with coal-based diesel (CBD) as a latent rival to replace conventional petroleum-based diesel (CPBD). This study demonstrates that the LCA methodology is very suitable and effective for the choice of vehicle fuels. One result is that the greenhouse gases (GHGs) emission of coal-based vehicle fuel pathways is usually concentrated on fuel production stage. The percentages of CBDME and CBD pathways both exceed 60%. The application of carbon capture and storage (CCS) is helpful for coal-based vehicle fuel pathways to improve their global warming effect dramatically. Compared with CBD pathway, CBDME pathway consumes less PEC and emits less \\{GHGs\\} emission as well. Even though the CCS and CH4-fired generation are used, the advantages of CBDME are still kept. For saving petroleum energy and reducing global warming effect, CBDME has greater potential than CBD to substitute CPBD under current fuel synthesis technologies. If the hurdles such as the maturity of engine and vehicle technologies, corresponding regulations and standards and infrastructures are reliably solved, CBDME will have better prospect in China.

Liang Zhang; Zhen Huang

2007-01-01T23:59:59.000Z

332

THE EFFECTS OF FLAME TEMPERATURE, PARTICLE SIZE AND EUROPIUM DOPING CONCENTRATION ON THE PROPERTIES OF Y2O3:EU PARTICLES FORMED IN A FLAME AEROSOL PROCESS  

E-Print Network [OSTI]

ix LIST OF FIGURES FIGURE Page 1 Schematic of flame spray pyrolysis apparatus... 2 O 3 :Eu 9, 10 . A number of methods may be used to synthesize Y 2 O 3 :Eu particles, including colloidal methods 11-13 , combustion in fuel-oxidizer mixture 14 , evaporation? condensation 15, 16 , furnace spray pyrolysis 17 . Flame aerosol...

Yim, Hoon

2010-07-14T23:59:59.000Z

333

XPS study of Eu(III) coordination compounds: Core levels binding energies in solid mixed-oxo-compounds EumXxOy  

Science Journals Connector (OSTI)

Literature is relatively sparse on XPS studies of europium compounds: it is essentially restricted to metallic compounds (EuM5, in which M is a transition metal) or to simple oxides. While particular interest have been devoted to understanding physical phenomenon in the beginning of “shake-down” and “shake-up” satellites evidenced on core-level regions of the lanthanides, few information on absolute binding energies (BE) was available. This paper reports an XPS binding energy data base for europium(III) compounds, in which Eu cation have various chemical environments: simple oxide Eu2O3, Eu mixed oxides with organic oxalate, acetylacetonate or inorganic sulfate, nitrate, carbonate ligands. The values of core-level BE (O1s, Eu3d and Eu4d) and the characteristics of shake-down satellites of Eu3d are reported, and their variations are attributed to ionicity/covalency changes. Such interpretation was already published for Group A mixed oxides and zeolites. These data are needed for determining Eu(III) species sorbed onto minerals in the presence of various ligands in the framework of retention studies for assessing the safety of future nuclear waste disposals.

F. Mercier; C. Alliot; L. Bion; N. Thromat; P. Toulhoat

2006-01-01T23:59:59.000Z

334

X-Ray Storage Luminescence of BaFCl:Eu2+ Single Crystals Nomadics, Inc., 1024 South InnoVation Way, Stillwater, Oklahoma 74074  

E-Print Network [OSTI]

X-Ray Storage Luminescence of BaFCl:Eu2+ Single Crystals Wei Chen* Nomadics, Inc., 1024 South InnoVed: January 18, 2005; In Final Form: March 22, 2005 Temperature behaviors of X-ray luminescence (XL might not be oxidized to Eu3+ upon X-ray or -irradiation. Instead, the color centers, Cl excitons

Chen, Reuven

335

Japan hopes for rapid accord with EU on nuclear reactor Japanese Prime Minister Junichiro Koizumi said Monday that he hopes to resolve a dispute with the  

E-Print Network [OSTI]

Japan hopes for rapid accord with EU on nuclear reactor 02/05/2005 Japanese Prime Minister. The 25-member EU wants ITER to be built in France, and has threatened to go it alone unless Japan drops support Japan's offer to build ITER in Rokkasho-mura, a northern Japanese village near the Pacific Ocean

336

EU, Japan call for dialogue amid row on breakthrough nuclear project The European Union and Japan each called Wednesday for dialogue among the six partners on  

E-Print Network [OSTI]

EU, Japan call for dialogue amid row on breakthrough nuclear project 01/12/2004 The European Union and Japan each called Wednesday for dialogue among the six partners on a multibillion-dollar nuclear energy project amid a deepening row over whether Japan or France will host the site. The EU, whose bid is backed

337

Solubility of carbon dioxide, nitrous oxide, ethane, and nitrogen in 1-butyl-1-methylpyrrolidinium and trihexyl(tetradecyl)phosphonium tris(pentafluoroethyl)trifluorophosphate (eFAP) ionic liquids  

Science Journals Connector (OSTI)

The density and viscosity of the ionic liquids 1-butyl-1-methylpyrrolidinium tris(pentafluoroethyl)trifluorophosphate [C1C4Pyrro][eFAP] and trihexyl(tetradecyl)phosphonium tris(pentafluoroethyl)trifluorophosphate [P66614][eFAP] were measured as a function of temperature and pressure and as a function of temperature, respectively. These two ionic liquids are more viscous than those based in the same anion associated to imidazolium cations. The effect of the addition of water on the density and viscosity of [P66614][eFAP] was studied at pressures close to atmospheric and as a function of the temperature. This ionic liquid is only partially miscible with water, its solubility being of around X H 2 O = 0.2 in the range of (303 to 315) K. Experimental values of the solubility of carbon dioxide, nitrous oxide, ethane, and nitrogen were obtained as a function of temperature and at pressures close to atmospheric. Carbon dioxide and nitrous oxide are the more soluble gases with mole fraction solubilities up to 7 · 10?2. Ethane is four times and 1.3 times less soluble than carbon dioxide in [C1C4Pyrro][eFAP] and [P66614][eFAP], respectively. Nitrogen is one order of magnitude less soluble than the others gases in the two ionic liquids studied. In order to understand behavior of the different gases with these ionic liquids, the thermodynamic functions of solvation such as enthalpy and entropy were calculated from the variation of the Henry’s law constant with temperature. It is shown that the more favorable interactions of the gases with the ionic liquid explain the larger solubility of carbon dioxide and nitrous oxide in [C1C4Pyrro][eFAP]. In the case of [P66614][eFAP], it is the less favorable entropic contribution that explains the lower solubility of ethane in this ionic liquid.

S. Stevanovic; M.F. Costa Gomes

2013-01-01T23:59:59.000Z

338

Synthesis and bio-functionalization of multifunctional magnetic Fe3O4@Y2O3:Eu nanocomposites  

E-Print Network [OSTI]

Synthesis and bio-functionalization of multifunctional magnetic Fe3O4@Y2O3:Eu nanocomposites Zhi Ya for the synthesis of multifunctional, magnetic, luminescent nanocomposites with Fe3O4 nanoparticles as the core is independent of particle size and hence mono- dispersity is less crucial, leading to lower synthesis costs

Hammock, Bruce D.

339

A Top-down and Bottom-up look at Emissions Abatement in Germany in response to the EU ETS  

E-Print Network [OSTI]

This paper uses top-down trend analysis and a bottom-up power sector model to define upper and lower boundaries on abatement in Germany in the first phase of the EU Emissions Trading Scheme (2005-2007). Long-term trend ...

Feilhauer, Stephan M. (Stephan Marvin)

2008-01-01T23:59:59.000Z

340

P\\procedure\\EU#7 Page 1 of 2 TITLE: PROCEDURE FOR RECORDING AND TRANSMITTING METER READINGS  

E-Print Network [OSTI]

P\\procedure\\EU#7 Page 1 of 2 TITLE: PROCEDURE FOR RECORDING AND TRANSMITTING METER READINGS FOR NEW METER SETS, METER REPLACEMENTS AND WHEN THE ACCOUNTABILITY FOR THE METERS USAGE CHANGES OBJECTIVE AND PURPOSE: To provide a timely and accurate method of capturing meter readings when a meter is changed out

Fernandez, Eduardo

Note: This page contains sample records for the topic "butyl ether eu" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

REFUEL: an EU road map for biofuels , E. Deurwaarder and S. Lensink, ECN policy Studies, the Netherlands  

E-Print Network [OSTI]

REFUEL: an EU road map for biofuels M. Londo1 , E. Deurwaarder and S. Lensink, ECN policy Studies), Poland K. Könighofer, Joanneum Research, Austria Abstract A successful mid-term development of biofuels calls for a robust road map. REFUEL assesses inter alia least-cost biofuel chain options, their benefits

342

Fair Weather Friends or Pillars of Support: Assessing the Sources of Legitimacy of EU Governance Among the Public Across Europe  

E-Print Network [OSTI]

of national institutions and priorities shaping the European Union’s response to the current fiscal and economic crisis flowing from the global “Great Recession”, is a growing concern for policy makers and scholars alike regarding the legitimacy of the EU...

Bastin, Mariah Margareta

2013-02-04T23:59:59.000Z

343

National Assembly for Wales Enterprise, Innovation and Networks Committee and Environment Planning and Countryside Committee Consultation on EU  

E-Print Network [OSTI]

) and of Integrated Coastal Zone Management. In the face of sustainability challenges, an integrated EU maritime generally, and sustainable energy supply). Need: ecological, legal, political and economic factors all: a European Vision for the oceans and seas RESPONSE FROM CENTRE FOR ENERGY AND ENVIRONMENTAL LAW AND ECONOMICS

Martin, Ralph R.

344

Calculation of electron densities for EuI 4f 7(8 S)6s7s  

Science Journals Connector (OSTI)

Using the non-relativistic Hartree-Fock computer code of Froese Fischer, calculations have been performed for all terms of the configuration 4f 7(8 S)6s7s of EuI. The results are c...

P. Aufmuth

1986-01-01T23:59:59.000Z

345

Extraction of Am and Eu with N,N?-substituted pyridine-2,6-dicarboxamides in fluorinated diluents  

Science Journals Connector (OSTI)

Extraction of Am and Eu with N,N?-substituted pyridine-2,6-dicarboxamides in fluorinated diluents was studied. N,N?-Diethyl-N,N?-di(p-tolyl)pyridine-2,6-dicarboxamide (EtTPDA) is readily soluble in fluorinated di...

V. A. Babain; M. Yu. Alyapyshev; I. V. Smirnov; A. Yu. Shadrin

346

"Japan and the EU in the global economy -challenges and opportunities" Graduate School of Economics, Kobe University  

E-Print Network [OSTI]

"Japan and the EU in the global economy - challenges and opportunities" Bruegel Graduate School and financial linkages between Europe and Japan: new evidence and scope for improvement André Sapir, Senior of Economics, Kobe University; Senior Research Fellow, Policy Research Institute, Ministry of Finance, Japan

Banbara, Mutsunori

347

EU marketing authorization review of orphan and non-orphan drugs does not differ  

Science Journals Connector (OSTI)

Marketing authorization application dossiers of 17 orphan drugs (ODs) and 51 non-ODs evaluated by the European Medicines Agency (EMA) in the period 2009–2010 were compared. We aimed to identify whether any differences existed between \\{ODs\\} and non-ODs in number and type of deficits brought forward during the EMA review, regarding the clinical development plan, clinical outcome and medical need and studied whether these deficits were similarly associated with marketing approval in the EU. In 71% of the \\{ODs\\} dossiers and 65% of the non-ODs dossiers marketing approval was granted. Differences in deficits were found, but similarities in the way \\{ODs\\} and non-ODs were reviewed and marketing approval decisions were taken, underline that regulatory standards are equally high.

M. Putzeist; A.K. Mantel-Teeuwisse; J. Llinares; C.C. Gispen-De Wied; A.W. Hoes; H.G.M. Leufkens

2013-01-01T23:59:59.000Z

348

Development of EU (European Union) energy market agenda and security of supply  

Science Journals Connector (OSTI)

Abstract The paper critically discusses the reform of the energy sector in the European Union from the beginnings of the liberalisation processes in 1996 until present. Through EU energy policies and relevant legislation the goals to achieve are sustainable development, security of supply and competitiveness, together with focussing on the needs of customers. The paper analyses all three above-mentioned pillars and customer protection requirements from the viewpoint: customers should have high quality energy delivered at affordable prices. We call for competitiveness to be further underlined by the market. Despite some concerns related to market models, with the latest impetus from the European institutions the market will, and is able to, develop and to integrate also renewable sources. Where the market does not deliver sufficiently, regulators have to ensure customer protection, especially for vulnerable customers in a period of increasing prices.

Marko Sencar; Viljem Pozeb; Tina Krope

2014-01-01T23:59:59.000Z

349

The impact of subsidies and carbon pricing on the wood biomass use for energy in the EU  

Science Journals Connector (OSTI)

Abstract This study examines how subsidies for wood-fired heat and power plants and wood with coal co-fired power plants influence the use of wood biomass for energy in the short (2020) to medium (2030) term in the EU (European Union). Analysis shows that without subsidies wood-fired electricity will take only a marginal market share due to limited availability of low-cost wood from logging residues. A high CO2 price of 100 €/t without subsidies results in 30 million m3 of industrial wood used for energy production, which is sourced from the reduction of 12 million m3 for wood products, 10 million m3 additional imports and 8 million m3 additional harvest. With a subsidy level of 30 €/MWh in the four EU member countries Denmark, Germany, Netherlands and UK, the total amount of industrial wood used for energy becomes 158 million m3. In the latter case, reduction of wood for wood-based products is 35 million m3, additional harvest in the EU is 21 million m3, and import to the EU is 102 million m3. Subsidies to wood-fired and especially coal with wood co-fired mills substantially increase the use of wood and especially industrial wood for energy. However, even with a high 100 €/tCO2 price and subsidy, mostly gas-fired electricity is projected to be displaced in 2030 by the increasing use of industrial wood, which is not beneficial regarding reducing the high CO2 emission from power production using coal. To a large extent, subsidies for wood co-firing maintain the coal power share, which will otherwise be reduced at high carbon emission price level. In addition, the model results show that the main sources of the growing use of industrial wood for energy are imports from regions outside of the EU, which thus creates considerable carbon leakages.

Alexander Moiseyev; Birger Solberg; A. Maarit I. Kallio

2014-01-01T23:59:59.000Z

350

Energy performances of intensive and extensive short rotation cropping systems for woody biomass production in the EU  

Science Journals Connector (OSTI)

Abstract One of the strategies to ensure energy security and to mitigate climate change in the European Union (EU) is the establishment and the use of short rotation woody crops (SRWCs) for the production of renewable energy. \\{SRWCs\\} are cultivated in the EU under different management systems. Addressing the energy security problems through \\{SRWCs\\} requires management systems that maximize the net energy yield per unit land area. We assembled and evaluated on-farm data from within the EU, (i) to understand the relationship between the SRWC yields and spatial distribution of precipitation, as well as the relationship between SRWC yield and the planting density, and (ii) to investigate whether extensively managed SRWC systems are more energy efficient than their intensively managed counterparts. We found that SRWC yield ranged from 1.3 to 24 t ha?1 y?1 (mean 9.3±4.2 t ha?1 y?1) across sites. We looked for, but did not find a relationship between yield and annual precipitation as well as between yield and planting density. The energy inputs of extensively managed SRWC systems ranged from 3 to 8 GJ ha?1 y?1 whereas the energy ratio (i.e. energy output to energy input ratio) varied from 9 to 29. Although energy inputs (3–16 GJ ha?1y?1) were larger in most cases than those of extensively managed SRWC systems, intensively managed SRWC systems in the EU had higher energy ratios, i.e. between 15 and 62. The low energy ratio of extensively managed SRWC systems reflected their lower biomass yield per unit area. Switching from intensively managed SRWC systems to extensively managed ones thus creates an energy gap, and will require more arable land to be brought into production to compensate for the yield loss. Consequently, extensification is not the most appropriate path to the success of the wide scale deployment of SRWC for bioenergy production in the EU.

S. Njakou Djomo; A. Ac; T. Zenone; T. De Groote; S. Bergante; G. Facciotto; H. Sixto; P. Ciria Ciria; J. Weger; R. Ceulemans

2015-01-01T23:59:59.000Z

351

Glass composition and excitation wavelength dependence of the luminescence of Eu{sup 3+} doped lead borate glass  

SciTech Connect (OSTI)

This work explores the relationship between the bandwidth of luminescence spectral features and their relative intensities, using glasses doped with europium, Eu{sup 3+}, over a wide composition range. Glasses of composition (B{sub 2}O{sub 3}){sub 70}(PbO){sub 29}(0.5Eu{sub 2}O{sub 3}){sub 1} and (B{sub 2}O{sub 3}){sub z}(PbO){sub 99.6-z}(0.5Eu{sub 2}O{sub 3}){sub 0.4}, (z = 20, 30, 40, 60, 70), were prepared by the melting-quenching technique. Variable-wavelength measurements by the prism-coupling method enabled interpolation of refractive index at selected wavelengths. Diffuse reflectance spectra confirmed the incorporation of Eu{sup 3+} into the glass, and scanning electron microscopy displayed that this was in a homogeneous manner. Vibrational spectra showed a change in boron coordination from BO{sub 3} to BO{sub 4} units with increase of PbO content in the glass. Multi-wavelength excited luminescence spectra were recorded for the glasses at temperatures down to 10 K and qualitative interpretations of spectral differences with change of B{sub 2}O{sub 3} content are given. The quantitative analysis of {sup 5}D{sub 0} luminescence intensity-bandwidth relations showed that although samples with higher boron content closely exhibit a simple proportional relationship with band intensity ratios, as expected from theory, the expression needs to be slightly modified for those with low boron content. The Judd-Ofelt intensity analysis of the {sup 5}D{sub 0} emission spectra under laser excitations at low temperature gives {Omega}{sub 2} values within the range from (3.9-6.5) x 10{sup -20} cm{sup 2}, and {Omega}{sub 4} in the range from (4.1-7.0) x 10{sup -20} cm{sup 2}, for different values of z. However, no clear monotonic relation was found between the parameter values and composition. The Judd-Ofelt parameters are compared with those from other systems doped with Eu{sup 3+} and are found to lie in the normal ranges for Eu{sup 3+}-doped glasses. The comparison of parameter values derived from the 10 K spectra with those from room temperature spectra for our glasses, which are fairly constant for different compositions, shows that site selection occurs at low temperature.

Wen Hongli; Duan, Chang-Kui; Jia Guohua; Tanner, Peter A. [Department of Biology and Chemistry, City University of Hong Kong, Tat Chee Avenue, Kowloon (Hong Kong); Brik, Mikhail G. [Institute of Physics, University of Tartu, Riia 142, Tartu 51014 (Estonia)

2011-08-01T23:59:59.000Z

352

Synthesis of Methanol and Dimethyl Ether from Syngas over Pd/ZnO/Al2O3 Catalysts  

SciTech Connect (OSTI)

A Pd/ZnO/Al2O3 catalyst was developed for the synthesis of methanol and dimethyl ether (DME) from syngas. Studied were temperatures of operation ranging from 250°C to 380°C. High temperatures (e.g. 380°C) are necessary when combining methanol and DME synthesis with a methanol to gasoline (MTG) process in a single reactor bed. A commercial Cu/ZnO/Al2O3 catalyst, utilized industrially for the synthesis of methanol at 220-280°C, suffers from a rapid deactivation when the reaction is conducted at high temperature (>320°C). On the contrary, a Pd/ZnO/Al2O3 catalyst was found to be highly stable for methanol and DME synthesis at 380°C. The Pd/ZnO/Al2O3 catalyst was thus further investigated for methanol and DME synthesis at P=34-69 bars, T= 250-380°C, GHSV= 5 000-18 000 h-1, and molar feeds H2/CO= 1, 2, and 3. Selectivity to DME increased with decreasing operating temperature, and increasing operating pressure. Increased GHSV’s and H2/CO syngas feed ratios also enhanced DME selectivity. Undesirable CH4 formation was observed, however, can be minimized through choice of process conditions and by catalyst design. By studying the effect of the Pd loading and the Pd:Zn molar ratio the formulation of the Pd/ZnO/Al2O3 catalyst was optimized. A catalyst with 5% Pd and a Pd:Zn molar ratio of 0.25:1 has been identified as the preferred catalyst. Results indicate that PdZn particles are more active than Pdº particles for the synthesis of methanol and less active for CH4 formation. A correlation between DME selectivity and the concentration of acid sites of the catalysts has been established. Hence, two types of sites are required for the direct conversion of syngas to DME: 1) PdZn particles are active for the synthesis of methanol from syngas, and 2) acid sites which are active for the conversion of methanol to DME. Additionally, CO2 formation was problematic as PdZn was found to be active for the water-gas-shift (WGS) reaction, under all the conditions evaluated.

Lebarbier, Vanessa MC; Dagle, Robert A.; Kovarik, Libor; Lizarazo Adarme, Jair A.; King, David L.; Palo, Daniel R.

2012-10-01T23:59:59.000Z

353

Proceedings: Cases in Sustainable Consumption and Production: Workshop of the Sustainable Consumption Research Exchange (SCORE!) Network, supported by the EU's 6th  

E-Print Network [OSTI]

1 Proceedings: Cases in Sustainable Consumption and Production: Workshop of the Sustainable Consumption Research Exchange (SCORE!) Network, supported by the EU's 6th Framework Program, Paris, 4-5 June

354

Identification of Eu oxidation states in a doped Sr5(PO4)3F phosphor by TOF-SIMS imaging  

Science Journals Connector (OSTI)

An Eu-doped Sr5(PO4)3F phosphor with a hexagonal apatite structure was prepared by a urea assisted combustion method. There was evidence of the...

Swart, H C; Nagpure, I M; Ntwaeaborwa, O M; Fisher, G L; Terblans, J J

2012-01-01T23:59:59.000Z

355

Nonlinear laser spectroscopy of Eu3+:Y2SiO5 and its application to time-domain optical memory  

Science Journals Connector (OSTI)

Linear- and nonlinear-optical properties of Eu3+:Y2SiO5 have been investigated. All the energy levels of the7F0,1,2,…...

Yano, Ryuzi; Mitsunaga, Masaharu; Uesugi, Naoshi

1992-01-01T23:59:59.000Z

356

Study of optical parameters of the Se-As chalcogenide semiconductor system containing EuF{sub 3} impurities  

SciTech Connect (OSTI)

Optical properties of chalcogenide vitreous semiconductors of composition Se{sub 95}As{sub 5} containing different amounts of rare-earth metal fluorides (EuF{sub 3}) are studied, and, on this basis, the fundamental parameters, such as the refractive index and extinction coefficient, are determined. The dependences of these parameters on the content of EuF{sub 3} molecules are nonmonotonic: the low content (below 0.25 at %) aids in decreasing the parameters, whereas the high content tends to increase them. From the analysis of the results with consideration for the structural features of chalcogenide vitreous semiconductors of the Se{sub 95}As{sub 5} system (the presence of ordered high-coordinated microregions separated from each other by regions with a lower atomic density), it is concluded that the optical properties of the chalcogenide vitreous semiconductor system under study can be described in the context of Penn's model.

Isayev, A. I.; Mekhtiyeva, S. I.; Garibova, S. N., E-mail: sgaribova@rambler.ru; Alekperov, R. I.; Zeynalov, V. Z. [Azerbaijan National Academy of Sciences, Abdullaev Institute of Physics (Azerbaijan)

2011-08-15T23:59:59.000Z

357

The potential impacts of border tax adjustments on imports of energy-intensive goods in the EU and USA markets  

Science Journals Connector (OSTI)

Government action to address climate change has been very varied and industries in the developed world, especially those that which are energy intensive, are increasingly concerned about the potential negative impacts of abatement measures on their international competitiveness. This paper looks at the potential impacts of one measure which has been proposed to address these competitiveness concerns – border tax adjustments (BTAs). It finds that the potential impacts of such measures may not justify the complexity of their imposition. The impacts on competitiveness are likely to be limited and potential negative side effects on some poor developing countries cannot be ruled out. The country most likely to be impacted by BTAs in the EU and USA markets is China, while the low-income countries most likely to be affected are Niger, Mozambique and Tadjikistan, in the EU market and Liberia, Tadjikistan, and Uzbekistan in the USA market.

Louise Curran

2010-01-01T23:59:59.000Z

358

High-resolution core-level photoemission study of Eu-induced (3×2)?(3×4) reconstruction on Ge(111)  

Science Journals Connector (OSTI)

We have investigated Eu-induced Ge(111)-(3×2)?(3×4) reconstruction by high-resolution core-level photoelectron spectroscopy using synchrotron radiation and low-energy electron diffraction. Recent scanning tunneling microscopy (STM) observations [Phys. Rev. B 73, 125332 (2006)] revealed that the Ge arrangement of this reconstruction can be well described in terms of the honeycomb chain-channel (HCC) geometry proposed earlier for metal/Si(111)-(3×1) and -(3×2) surfaces; the Eu atoms, however, were found to reside at two different adsorption sites in the Eu?Ge(111)-(3×2)?(3×4) reconstruction, in contrast to the equivalent adsorption sites (e.g., T4) occupied in the case of Si. The present photoemission results provide further information about the atomic arrangement of Eu?Ge(111)-(3×2)?(3×4). In particular, we show that the Ge 3d core-level data cannot be interpreted by the HCC structure with the Eu atoms adsorbed only on T4 sites, giving a spectroscopic support for the suggestions based on the earlier STM data. We consider here a modified HCC-based configuration for the Eu?Ge(111)-(3×2)?(3×4) surface where the Eu atoms occupy two different sites in the empty channel between the neighboring Ge honeycomb chains. The atomic models are discussed in the context of the Ge 3d and Eu 4f data as well as the previous results available in the literature. Finally, we propose a structural model that allows us to account for the present photoemission and earlier STM findings.

M. Kuzmin; R. E. Perälä; P. Laukkanen; M. Ahola-Tuomi; I. J. Väyrynen

2006-09-22T23:59:59.000Z

359

Structural phase transitions in EuFe[subscript 2]As[subscript 2] superconductor at low temperatures and high pressures  

SciTech Connect (OSTI)

The crystal structure of EuFe{sub 2}As{sub 2} has been studied up to a pressure of 35 GPa and down to a temperature of 8 K using temperature dependent x-ray diffraction in a diamond anvil cell at a synchrotron source. At 4.3 GPa, we have detected a structural phase transition from a high temperature tetragonal phase with I4/mmm space group to a low temperature orthorhombic phase with Fmmm space group around 120 K. With the application of pressure at a low temperature of 10 K, the orthorhombic phase is suppressed and a phase change to a collapsed tetragonal phase with I4/mmm space group is observed at 11 GPa. This collapsed tetragonal phase is similar to the one observed at ambient temperature and pressure above 8.5 GPa. We have shown that the collapsed tetragonal phase of EuFe{sub 2}As{sub 2} has the same pressure-volume (P-V) equation of state at ambient temperature and at 10 K, implying that the high pressure phase of EuFe{sub 2}As{sub 2} has a negligible thermal expansion coefficient.

Uhoya, Walter O.; Tsoi, Georgiy M.; Vohra, Yogesh K.; McGuire, Michael A.; Sefat, Athena S. (UAB); (ORNL)

2011-09-20T23:59:59.000Z

360

Electron nuclear double resonance study of photostimulated luminescence active centers in CsBr:Eu{sup 2+} medical imaging plates  

SciTech Connect (OSTI)

CsBr:Eu{sup 2+} needle image plates exhibit an electron-paramagnetic-resonance (EPR) spectrum at room temperature (RT), whose intensity is correlated with the photostimulated luminescence sensitivity of the plate. This EPR spectrum shows a strong temperature dependence: At RT it is owing to a single Eu{sup 2+} (S =7/2) center with axial symmetry, whereas at T<35 K the spectra can only be explained when two distinct centers are assumed to be present, a minority axial center and a majority center with nearly extremely rhombic symmetry. In this paper these low-temperature centers are studied with electron nuclear double resonance (ENDOR) spectroscopy, which reveals the presence of {sup 1}H nuclei close to the central Eu{sup 2+} ions in the centers. Analysis of the angular dependence of the ENDOR spectra allows to propose models for these centers, providing an explanation for the observed difference in intensity between the spectral components and for their temperature dependence.

Vrielinck, H.; Loncke, F.; Matthys, P.; Callens, F. [Department of Solid State Sciences, Ghent University, Krijgslaan 281-S1, B-9000 Gent (Belgium); Tahon, J.-P.; Leblans, P. [Agfa HealthCare NV, Septestraat 27, B-2640 Mortsel (Belgium)

2011-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "butyl ether eu" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Models of science–policy interaction: Exploring approaches to Bisphenol A management in the EU  

Science Journals Connector (OSTI)

Abstract This study investigated science–policy interaction models and their limitations under conditions of uncertainty. In detail, it looked at the management of the suspected endocrine-disrupting chemical Bisphenol A (BPA). Despite growing evidence that BPA is hazardous to human and environmental health, the level of scientific uncertainty is still high and, as a result, there is significant disagreement on the actual extent and type of risk. Analysis of decision-making processes at different regulatory levels (EU, Sweden, and the Swedish municipality of Gothenburg) exposed chemicals risk management and associated science–policy interaction under uncertainty. The results of the study show that chemicals management and associated science–policy interaction follow the modern model of science–policy interaction, where science is assumed to ‘speak truth to policy’ and highlights existing limitations of this model under conditions of uncertainty. The study not only explores alternative models (precautionary, consensus, science–policy demarcation. and extended participation) but also shows their limitations. The study concludes that all models come with their particular underlying assumptions, strengths, and limitations. At the same time, by exposing serious limitations of the modern model, the study calls for a rethinking of the relationship between science, policy, and management.

O. Udovyk

2014-01-01T23:59:59.000Z

362

Analysing future trends of renewable electricity in the EU in a low-carbon context  

Science Journals Connector (OSTI)

The aim of this paper is to analyse the situation and trends of electricity from renewable energy sources (RES-E) in the EU up to 2030, taking into account several drivers and barriers and different maturity levels for the renewable energy technologies. The methodology is based on the results of simulation models providing insights on future outlooks, complemented with an analysis of regulations and other drivers and barriers. Regarding the most mature renewable electricity technologies, the main drivers will be public policies (carbon prices and support schemes) and the expected up-ward trend in fossil-fuel prices and the main barriers are related to grid access, administrative procedures and the exhaustion of places with the best wind resource. For those already commercial but expensive technologies, the main driver is support schemes (but not carbon prices) allowing the exploitation of the large potential for investment cost reductions. Barriers are mostly related to their high investment costs. Finally, for those technologies which are emerging and immature, further technical improvements as a result of R&D efforts will be needed and they cannot be expected to significantly penetrate the European electricity market until 2030.

Pablo del Río

2011-01-01T23:59:59.000Z

363

Annual Energy Outlook 1999 - Acronyms  

Gasoline and Diesel Fuel Update (EIA)

acronyms.gif (3491 bytes) acronyms.gif (3491 bytes) AD - Associated/dissolved natural gas AEO98 - Annual Energy Outlook 1998 AEO99 - Annual Energy Outlook 1999 AFVs - Alternative-fuel vehicles AGA - American Gas Association API - American Petroleum Institute BTAB - BT Alex Brown CAAA90 - Clean Air Act Amendments of 1990 CCAP - Climate Change Action Plan CDM - Clean Development Mechanism CFCs - Chlorofluorocarbons CNG - Compressed natural gas CO - Carbon monoxide CO2 - Carbon dioxide DOE - U.S. Department of Energy DRI - DRI/McGraw-Hill EIA - Energy Information Administration EOR - Enhanced oil recovery EPA - U.S. Environmental Protection Agency EPACT - Energy Policy Act of 1992 ETBE - Ethyl tertiary butyl ether EU - European Union FERC - Federal Energy Regulatory Commission GDP - Gross domestic product

364

Bridgman Growth of Large SrI2:Eu2+ Single Crystals: A High-performance Scintillator for Radiation Detection Applications  

SciTech Connect (OSTI)

Single-crystal strontium iodide (SrI2) doped with relatively high levels (e.g., 3 - 6 %) of Eu2+ exhibits characteristics that make this material superior, in a number of respects, to other scintillators that are currently used for radiation detection. Specifically, SrI2:Eu2+ has a light yield that is significantly higher than LaBr3:Ce3+ -a currently employed commercial high-performance scintillator. Additionally, SrI2:Eu2+ is characterized by an energy resolution as high as 2.6% at the 137Cs gamma-ray energy of 662 keV, and there is no radioactive component in SrI2:Eu2+ - unlike LaBr3:Ce3+ that contains 138La. The Ce3+-doped LaBr3 decay time is, however, faster (30 nsec) than the 1.2 sec decay time of SrI2:Eu2+. Due to the relatively low melting point of strontium iodide (~515 oC), crystal growth can be carried out in quartz crucibles by the vertical Bridgman technique. Materials-processing and crystal-growth techniques that are specific to the Bridgman growth of europium-doped strontium iodide scintillators are described here. These techniques include the use of a porous quartz frit to physically filter the molten salt from a quartz antechamber into the Bridgman growth crucible and the use of a bent or bulb grain selector design to suppress multiple grain growth. Single crystals of SrI2:Eu2+ scintillators with good optical quality and scintillation characteristics have been grown in sizes up to 5.0 cm in diameter by applying these techniques. Other aspects of the SrI2:Eu2+ crystal-growth methods and of the still unresolved crystal-growth issues are described here.

Boatner, Lynn A [ORNL; Ramey, Joanne Oxendine [ORNL; Kolopus, James A [ORNL; Hawrami, Rastgo [Radiation Monitoring Devices, Watertown, MA; Higgins, William [Radiation Monitoring Devices, Watertown, MA; Van Loef, Edgar [Radiation Monitoring Devices, Watertown, MA; Glodo, J. [Radiation Monitoring Devices, Watertown, MA; Shah, Kanai [Radiation Monitoring Devices, Watertown, MA; Bhattacharya, P. [Fisk University, Nashville, TN; Tupitsyn, E [Fisk University, Nashville, TN; Groza, Michael [Fisk University, Nashville, TN; Burger, Arnold [Fisk University, Nashville, TN

2013-01-01T23:59:59.000Z

365

Enhanced Luminescence of NaY0.6–xCe0.1Gd0.3EuxF4 Nanorods by Energy Transfers between Ce3+, Gd3+, and Eu3+  

Science Journals Connector (OSTI)

Enhanced Luminescence of NaY0.6–xCe0.1Gd0.3EuxF4 Nanorods by Energy Transfers between Ce3+, Gd3+, and Eu3+ ... On the whole, the introduction of an elevated amount of Eu3+ dopants in the host lattice would decrease the Ce···Eu interatomic distance and thus shorten the average traveling distance for the excitation energies. ...

Bing Chen; Xvsheng Qiao; Dengfeng Peng; Xianping Fan

2014-12-02T23:59:59.000Z

366

On the possibility for Rb- and Eu-cation ordering in type-I clathrates: synthesis and homogeneity range of the novel compounds Rb8-xEux(In,Ge)46 (0.6 x 1.8)  

Science Journals Connector (OSTI)

Clathrates with the type-I structure are reported in the quaternary Rb-Eu-In-Ge system. Possible cation ordering is suggested.

Sch?fer, M.C.

2013-11-13T23:59:59.000Z

367

RE/ZrO{sub 2} (RE = Sm, Eu) composite oxide nano-materials: Synthesis and applications in photocatalysis  

SciTech Connect (OSTI)

Graphical abstract: - Highlights: • RE/ZrO{sub 2} (RE = Sm, Eu) nano-materials have been successfully synthesized. • Defect and electron structures determine the absorption properties on visible light. • Nano-sized Zr{sub 0.8}Sm{sub 0.2}O{sub 2??} has good visible-light-responsive photocatalytic activities. • In the future, it can be used in wastewater treatment and environmental protection. - Abstract: Zirconia modified by Samarium/Europium, RE/ZrO{sub 2} (RE = Sm, Eu), composite oxide nano-materials have been successfully synthesized by improved sol–gel method. Characterization results show that X-ray diffraction (XRD) peaks of products gradually shift to the lower angle with the increase of rare earth which implies that the lattice distances of RE/ZrO{sub 2} nano-materials are gradually enlarged. Moreover, the molar ratios between zirconium and rare earth are consistent with the chemical formula and both of them are uniformly distributed in samples. Optical properties indicate that defect structures and electron configurations of RE/ZrO{sub 2} (RE = Sm, Eu) with single phase determine their absorption properties on visible light. Photocatalytic experiments indicate Zr{sub 0.8}Sm{sub 0.2}O{sub 2??} nano-crystals have excellent visible-light-responsive photocatalytic activities on Methylene blue and Rhodamine B which results from the special defect structure, suitable electronic configuration, and larger specific surface area. It follows that Zr{sub 0.8}Sm{sub 0.2}O{sub 2??} nano-crystals are new visible-light-responsive photocatalysts which can be applied in dye wastewater treatment and environmental protection in the future.

Du, Weimin, E-mail: duweimin75@gmail.com [College of Chemistry and Chemical Engineering, Anyang Normal University, Anyang, Henan 455002 (China); Zhu, Zhaoqiang [College of Chemistry and Chemical Engineering, Anyang Normal University, Anyang, Henan 455002 (China); College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou, Henan 450001 (China); Zhang, Xiaofen; Wang, Dacheng; Liu, Donghe [College of Chemistry and Chemical Engineering, Anyang Normal University, Anyang, Henan 455002 (China); Qian, Xuefeng [School of Chemistry and Chemical Technology, Shanghai Jiao Tong University, Shanghai 200240 (China); Du, Jimin, E-mail: djm@aynu.edu.cn [College of Chemistry and Chemical Engineering, Anyang Normal University, Anyang, Henan 455002 (China)

2013-10-15T23:59:59.000Z

368

Computational analysis of modern HTGR fuel performance and fission product release during the HFR-EU1 irradiation experiment  

Science Journals Connector (OSTI)

Abstract Various countries engaged in the development and fabrication of modern HTGR fuel have initiated activities of modeling the fuel and fission product release behavior with the aim of predicting the fuel performance under HTGR operating and accident conditions. Verification and validation studies are conducted by code-to-code benchmarking and code-to-experiment comparisons as part of international exercises. The methodology developed in Germany since the 1980s represents valuable and efficient tools to describe fission product release from spherical fuel elements and TRISO fuel performance, respectively, under given conditions. Continued application to new results of irradiation and accident simulation testing demonstrates the appropriateness of the models in terms of a conservative estimation of the source term as part of interactions with HTGR licensing authorities. Within the European irradiation testing program for HTGR fuel and as part of the former EU RAPHAEL project, the HFR-EU1 irradiation experiment explores the potential for high performance of the presently existing German and newly produced Chinese fuel spheres under defined conditions up to high burnups. The fuel irradiation was completed in 2010. Test samples are prepared for further postirradiation examinations (PIE) including heatup simulation testing in the KÜFA-II furnace at the JRC-ITU, Karlsruhe, to be conducted within the on-going ARCHER Project of the European Commission. The paper will describe the application of the German computer models to the HFR-EU1 irradiation test and compare within the preliminary experimental results as well as with previously conducted, true predictive calculations. Furthermore, results will be compared with the German code development STACY that extends the earlier codes toward new features.

Karl Verfondern; André Xhonneux; Heinz Nabielek; Hans-Josef Allelein

2014-01-01T23:59:59.000Z

369

Estimating broad-brush rebound effects for household energy consumption in the EU 28 countries and Norway: some policy implications of Odyssee data  

Science Journals Connector (OSTI)

Abstract Currently there is a strong policy commitment in European Union (EU) and Organisation for Economic Co-operation and Development (OECD) countries to increase the energy efficiency of residential buildings, and it is widely assumed that this will naturally and automatically reduce domestic energy consumption. However, other factors such as fuel prices, wages, attitudes and lifestyles also influence energy consumption. This paper calculates broad-brush rebound effects based on changes in energy efficiency and energy consumption in each of the 28 EU countries plus Norway, for the years 2000–2011. In doing so, it tests how well the assumption of energy efficiency leading to energy reduction stands up to scrutiny in these lands. It uses the EU’s Odyssee database for efficiency and consumption figures and a commonly employed econometric definition of the rebound effect as an energy-efficiency elasticity. Most older EU lands show rebound effects in the expected range of 0–50%. However, the range for newer EU countries is 100–550%, suggesting that energy efficiency increases are not a good predictor of energy consumption. A more in-depth look at one country, Germany, suggests these results underestimate the rebound effect significantly. This also identifies research needs for specific energy consumption determinants in each country, to find more precisely what is driving consumption levels.

Ray Galvin

2014-01-01T23:59:59.000Z

370

Critical two- and three-spin correlations in EuS: An investigation with polarized neutrons  

SciTech Connect (OSTI)

The critical magnetic scattering has been investigated in EuS by means of small-angle scattering with polarized neutrons using an inclined magnetic field geometry, allowing the determination of three-spin correlation functions. Two contributions to the critical magnetic scattering I{sub {sigma}}(q)=I{sup {up_arrow}}(q)+I{sup {down_arrow}}(q) and {delta}I(q)=I{sup {up_arrow}}(q)-I{sup {down_arrow}}(q) were studied for temperatures near T{sub C}=16.52 K. The I{sup {up_arrow}}(q) and I{sup {down_arrow}}(q) are the scattering intensities for the incident neutron beam polarized along ({up_arrow}) and opposite ({down_arrow}) to the magnetic field. The symmetric contribution, namely I{sub {sigma}}(q), comes from the pair-spin correlation function. The scattering intensity is well described by the Ornstein-Zernike expression I{sub {sigma}}(q)=A(q{sup 2}+{kappa}{sup 2}){sup -1}, where {kappa}={xi}{sup -1} is the inverse correlation length of the critical fluctuations. The correlation length {xi} obeys the scaling law {xi}=a{sub 0}{tau}{sup -{nu}}, where {tau}=(T-T{sub C})/T{sub C} is the reduced temperature, a{sub 0}=0.17 nm, and {nu}=0.68{+-}0.01. The difference contribution {delta}I(q) is caused by the three-spin chiral dynamical spin fluctuations that represent the asymmetric part of the polarization dependent scattering. The q dependence of {delta}I(q) follows closely 1/q{sup 2}. {delta}I(q) depends on the temperature as {tau}{sup -{nu}} with {nu}=0.64{+-}0.05. The exponents {nu} as determined by means of the static measurements by {xi} and the dynamic measurements (using the chirality) are in excellent agreement with each other, demonstrating the internal consistency of the theory and the experiment. Therefore, our results confirm the principle of the critical factorization, which is known as Polyakov-Kadanoff-Wilson operator algebra.

Grigoriev, S.V.; Metelev, S.V.; Maleyev, S.V.; Okorokov, A.I. [Petersburg Nuclear Physics Institute, Gatchina, St. Petersburg 188300 (Russian Federation); Boeni, P.; Georgii, R.; Lamago, D. [TU-Munchen, Garching (Germany); Eckerlebe, H.; Pranzas, K. [GKSS Forschungszentrum, 21502 Geesthacht (Germany)

2005-12-01T23:59:59.000Z

371

Magnetization-induced enhancement of photoluminescence in core-shell CoFe{sub 2}O{sub 4}@YVO{sub 4}:Eu{sup 3+} composite  

SciTech Connect (OSTI)

After the core-shell CoFe{sub 2}O{sub 4}@YVO{sub 4}:Eu{sup 3+} composite synthesized through a facile sol-gel method was magnetized under an external magnetic field of 0.25?T for 4?h, an enhancement of ?56% in photoluminescence intensity was observed. The remanent magnetization of the CoFe{sub 2}O{sub 4} core increases the intensity of the excited charge transfer transition of VO{sub 4}{sup 3?} group in YVO{sub 4}:Eu{sup 3+} shell, which may enhance the probability related to the Eu{sup 3+} radiative transition {sup 5}D{sub 0}-{sup 7}F{sub 2}, yielding to a high photoluminescence. The obvious remanent-magnetization-induced enhancement in photoluminescence is helpful in developing excellent magnetic/luminescent material for the practical display devices.

Jia, Yanmin, E-mail: ymjia@zjnu.edu.cn, E-mail: wuzheng@zjnu.cn; Zhou, Zhihua; Wei, Yongbin [Department of Physics, Zhejiang Normal University, Jinhua 321004 (China); Wu, Zheng, E-mail: ymjia@zjnu.edu.cn, E-mail: wuzheng@zjnu.cn; Chen, Jianrong [College of Geography and Environmental Sciences, Zhejiang Normal University, Jinhua 321004 (China); Zhang, Yihe [School of Materials Science and Technology, China University of Geosciences, Beijing 100083 (China); Liu, Yongsheng [Department of Physics, Shanghai University of Electric Power, Shanghai 200090 (China)

2013-12-07T23:59:59.000Z

372

APPENDXD.CHP:Corel VENTURA  

Gasoline and Diesel Fuel Update (EIA)

Report The Form EIA-819, "Monthly Oxygenate Report" provides production data for fuel ethanol and methyl tertiary butyl ether (MTBE). End-of-month stock data held at ethanol...

373

The feasibility of ethanol production in Texas  

E-Print Network [OSTI]

Agricultural interests across Texas are looking at the possibility of an ethanol industry in Texas. Continued conflict in the Middle East, the ban of methyl tertiary butyl ether (MTBE) in California, and low commodity prices have all lead...

Herbst, Brian Keith

2012-06-07T23:59:59.000Z

374

Nanocrystalline K{sub 2}Ca{sub 2}(SO{sub 4}){sub 3}: Eu for proton beam dosimetry  

SciTech Connect (OSTI)

This paper investigates the Thermoluminescent response of nanocrystalline K{sub 2}Ca{sub 2}(SO{sub 4}){sub 3}: Eu, prepared by Co-precipitation technique to 150 MeV proton beam. The particle size was calculated to be 45 nm by the broadening of the XRD peaks using Scherrer's formula. Samples in the form of pellets were irradiated by 150 MeV proton beam with dose range of 0.1 Gy to 325 Gy. Thermoluminescence (TL) glow curves of the irradiated samples were recorded and studied. It has been found that the phosphor shows a characteristic single peak at around 420 K. The TL response is linear in the range upto 200 Gy and then saturates for higher doses. The wider linear TL response of nanocrystalline K{sub 2}Ca{sub 2}(SO{sub 4}){sub 3}: Eu and low fading makes it a superior candidate as a dosimeter to be used for detecting the doses of protons beams for its various applications in the field of space, therapy and research.

Bahl, Shaila; Lochab, S. P.; Pandey, A.; Aleynikov, V. E.; Molokanov, A.; Kumar, Pratik [Medical Physics Unit, IRCH, AIIMS, New Delhi-110029 (India); Inter-University Accelerator Center, Aruna Asaf Ali Marg, New Delhi - 110067 (India); Department of Physics, Sri Venkateswara College, New Delhi-110021 (India); Joint Institute for Nuclear Research, Dubna - 141980 (Russian Federation); Medical Physics Unit, IRCH, AIIMS, New Delhi-110029 (India)

2012-06-05T23:59:59.000Z

375

Glycothermal Synthesis of Scheelite-Type LiEuW2O8 Nanophosphors and Their Structural Characterization  

Science Journals Connector (OSTI)

The formation of LiEuW2O8 from a tungsten source and acetates of lithium and europium(III) by autoclave treatment in 1,4-butylene glycol, i.e., by a glycothermal reaction, was studied to explore a novel low-temperature wet chemical synthesis of scheelite-type tungstate compounds with WO4 units. When dodecatungstophosphoric acid hexahydrate (DPA) was chosen as a tungsten source, a glycothermal reaction at 300 ?C produced crystalline scheelite-type LiEuW2O8 (LEW) nanophosphors in a single phase. In contrast, phase-pure crystalline LEW was not obtained using the other tungsten sources. According to the results obtained by inductively coupled plasma atomic emission spectroscopy, infrared absorption spectroscopy, and Raman spectroscopy, the DPA-derived sample contained PO4 groups, which had probably substitutionally replaced WO4. PO4 groups could play a significant role in the nucleation of scheelite-type LEW, which is composed of WO4 groups. We also discuss the nonstoichiometric structural properties of the crystalline scheelite-type LEW. LEW nanophosphors, which are an alternative for organic dyes, may be one of promising materials because of their optical function of color conversion from near UV and blue to red.

Ryo Kasuya; Tetsuhiko Isobe; Shinobu Yamao

2007-01-01T23:59:59.000Z

376

ABC News: EU Threatens to Go It Alone on Nuclear Fusion http://abcnews.go.com/US/print?id=237927 1 of 2 11/9/04 8:33 AM  

E-Print Network [OSTI]

ABC News: EU Threatens to Go It Alone on Nuclear Fusion http://abcnews.go.com/US/print?id=237927 1 of 2 11/9/04 8:33 AM EU Threatens to Go It Alone on Nuclear Fusion Reuters Nov. 9, 2004 - The European Union warned on Tuesday it may go ahead and build the world's first nuclear fusion reactor with whatever

377

Yahoo! News -EU research chief to head to Japan next week to discu... http://news.yahoo.com/news?tmpl=story&cid=1540&u=/afp/200504... 1 of 1 4/7/05 11:34 AM  

E-Print Network [OSTI]

Yahoo! News - EU research chief to head to Japan next week to discu... http://news.yahoo.com/news users. News Home - Help EU research chief to head to Japan next week to discuss ITER 1 hour, 8 minutes reserved. The information contained in the AFP News report may not be published, broadcast, rewritten

378

JOURNAL DE PHYSIQUE Colloque C5, supplement aun 5, Tome 40, Mai 1979, page C5-393 Effects of carbon on the magnetism of EuB6  

E-Print Network [OSTI]

of carbon on the magnetism of EuB6 M. Kasaya (*), J. M. Tarascon, J. Etourneau and P. Hagenmuller antiferromagnétique. Pour des compositions intermédiaires, ils sont mictomagnétiques. Abstract. -- Magnetization has been measured as function of temperature and magnetic field for compounds of composition EuB6_xCx (0

Boyer, Edmond

379

EUbusiness -Japan vows no backing down to EU pressure on pionee... http://www.eubusiness.com/afp/041220030916.ykizqqm7 1 of 2 12/20/04 9:56 AM  

E-Print Network [OSTI]

EUbusiness - Japan vows no backing down to EU pressure on pionee... http://www.eubusiness.com/afp/041220030916.ykizqqm7 1 of 2 12/20/04 9:56 AM Japan vows no backing down to EU pressure on pioneering nuclear project 20/12/2004 Japan will not budge in talks to choose the site of a revolutionary nuclear reactor

380

Energy transfer and luminescent properties of a green-to-red color tunable Tb3+, Eu3+ co-doped K2Y(WO4)(PO4) phosphor  

Science Journals Connector (OSTI)

Abstract A color-tunable Tb3+, Eu3+ co-doped K2Y(WO4)(PO4) phosphor was prepared by solid-state method. The excitation peak wavelength of the resulting phosphor was 377 nm and the emission peak wavelengths were at 545 nm, attributed to the 5D4 ? 7F5 transition of Tb3+, and at 613 mm, attributed to the 5D0 ? 7F2 transition of Eu3+. Both cross relaxation and exchange interaction are responsible for the Tb3+ ? Eu3+ energy transfer in K2Y(WO4)(PO4): Tb3+, Eu3+ system. The intensity ratio of the two peaks could be freely controlled by varying the Eu/Tb ratio, allowing color to be tuned over a wide range from green to red.

Xinguo Zhang; Pei He; Liya Zhou; Jianxin Shi; Menglian Gong

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "butyl ether eu" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Synthesis, structures, and properties of novel aminodisilanes bearing bulky substituents: 1,2-bis(1,1,2-trimethylpropyl)-1,1,2,2-tetrakis(diethylamino) disilane and 1,2-di-tert-butyl-1,1,2,2-tetrakis(diethylamino) disilane  

Science Journals Connector (OSTI)

Two novel tetraaminodisilanes, 1,2-bis(1,1,2-trimethylpropyl)-1,1,2,2-tetrakis(diethylamino)disilane (1) and 1,2-di-tert-butyl-1,1,2,2-tetrakis(diethylamino)disilane (2) were synthesized and X-ray crystallography analyses of these compounds were carried out. Reflecting the steric congestion, the Si?Si bonds are very long: 2.539(2) Å for bis(1,1,2-trimethylpropyl)disilane, and 2.4764(9) Å for di-tert-butyl-disilane. UV spectra and oxidation potentials of several tetraaminodialkyldisilanes are compared and discussed. In addition, in the chlorination of 1 with HCl, 1,1,2,2-tetrachloro-1,2-bis(1,1,2-trimethylpropyl)disilane (6) was obtained with a 72% yield.

Masafumi Unno; Mina Saito; Hideyuki Matsumoto

1995-01-01T23:59:59.000Z

382

SPME in Environmental Analysis: Biotransformation Pathways  

Science Journals Connector (OSTI)

......SPMEGCMS to study the degradation of ethyl benzene using...methyl-t-butyl ether and its degradation products, t-butyl...food by determining degradation products and other released...Bitumen is a fossil fuel rich in sulfur, which...Aliquots of the cell suspension (2 mL......

Annamaria Halasz; Jalal Hawari

2006-08-01T23:59:59.000Z

383

Gas transport properties of reverse-selective poly(ether-b-amide6)/[Emim][BF4] gel membranes for CO2/light gases separation  

Science Journals Connector (OSTI)

Abstract The present research investigates deeply effect of 1-ethyl-3 methylimidazolium tetrafluoroborate ([Emim][BF4]) ionic liquid on separation performance and transport properties of poly(ether-b-amide6)(Pebax1657) at different operating pressures from 2 to 20 bar and temperatures from 25 to 65 °C. [Emim][BF4] showed interesting separation factor for CO2/light gases as a solvent and it was expected that its addition to Pebax1657 leads more amorphous structure, thereby diffusion and permeability of gases increase. [Emim][BF4] was added to the polymer solution up to 100 wt.% of Pebax1657 weight and permeation coefficients of CO2, H2, CH4 and N2 through the prepared membranes were measured. The results showed remarkable increment in permeation of all the tested gases, particularly CO2 and ideal selectivity of CO2/H2 enhanced significantly due to high solubility selectivity of the added compound. Effect of operating conditions on solubility coefficients were also investigated, thus sorption isotherms and activation energies of permeability, solubility and diffusion were calculated. In addition, the membranes were characterized by SEM, DSC, FT-IR spectroscopy and Tensile analysis to inspect changes in their physical and thermal properties, precisely.

Hesamoddin Rabiee; Ali Ghadimi; Toraj Mohammadi

2014-01-01T23:59:59.000Z

384

CONVNIOS, PROJETOS, COOPERAES INTERNACIONAIS 2012-2013: Projeto MCT/CNPq No. 066/2010 (FP7-2011-EU-Brazil) "Technology  

E-Print Network [OSTI]

/2010 (FP7-2011-EU-Brazil) "Technology platform for point-of-care diagnostics for tropical deseases. 2010 - 2014: Titulo: P116M100008 - Sustainable Energy and Aeronautical Engineering - U.S.-Brazil Higher of Pittsburgh; Brazil Lead: Universidade Federal de Itajuba & Brazil Partner: Federal University of Parana

Paraná, Universidade Federal do

385

Fiscal Year 2008 Phased Construction Completion Report for EU Z2-33 in Zone 2, East Tennessee Technology Park, Oak Ridge, Tennessee  

SciTech Connect (OSTI)

The Record of Decision for Soil, Buried Waste, and Subsurface Structure Actions in Zone 2, East Tennessee Technology Park, Oak Ridge, Tennessee (DOE/OR/01-2161&D2) (Zone 2 ROD) acknowledged that most of the 800 acres in Zone 2 were contaminated, but that sufficient data to confirm the levels of contamination were lacking. The Zone 2 ROD further specified that a sampling strategy for filling the data gaps would be developed. The Remedial Design Report/Remedial Action Work Plan for Zone 2 Soils, Slabs, and Subsurface Structures, East Tennessee Technology Park, Oak Ridge, Tennessee (DOE/OR/01-2224&D3) (Zone 2 RDR/RAWP) defined the sampling strategy as the Dynamic Verification Strategy (DVS), generally following the approach used for characterization of the Zone 1 exposure units (EUs). The Zone 2 ROD divided the Zone 2 area into seven geographic areas and 44 EUs. To facilitate the data quality objectives (DQOs) of the DVS process, the Zone 2 RDR/RAWP regrouped the 44 EUs into 12 DQO scoping EU groups. These groups facilitated the DQO process by placing similar facilities and their support facilities together and allowing identification of data gaps. The EU groups were no longer pertinent after DQO planning was completed and characterization was conducted as areas became accessible. As the opportunity to complete characterization became available, the planned DVS program and remedial actions (RAs) were completed for EU Z2-33. Remedial action was also performed at two additional areas in adjacent EU Z2-42 because of their close proximity and similar nature to a small surface soil RA in EU Z2-33. Remedial actions for building slabs performed in EU Z2-33 during fiscal year (FY) 2007 were reported in the Fiscal Year 2007 Phased Construction Completion Report for the Zone 2 Soils, Slabs, and Subsurface Structures at East Tennessee Technology Park, Oak Ridge, Tennessee (DOE/OR/01-2723&D1). Recommended RAs for EU Z2-42 were described in the Fiscal Year 2006 Phased Construction Completion Report for the Zone 2 Soils, Slabs, and Subsurface Structures at East Tennessee Technology Park, Oak Ridge, Tennessee (DOE/OR/01-2317&D2). Remedial actions performed in the Balance of Site (BOS) Laboratory Area of EU Z2-33 and two small areas in EU Z2-42 are described in Sects. 5 through 10 of this Phased Construction Completion Report (PCCR). The purpose of this PCCR is to address the following: (1) Document DVS characterization results for EU Z2-33; (2) Describe and document the risk evaluation and determine if the EU meets the Zone 2 ROD requirements for unrestricted industrial use to 10 ft bgs; (3) Identify additional areas not defined in the Zone 2 ROD that require remediation based on the DVS evaluation results; and (4) Describe RAs performed in the EU Z2-33 BOS Laboratory Area and two small areas in EU Z2-42. Approximately 18 acres in EU Z2-33 are addressed in this PCCR. Based on the results of the DVS evaluation and RAs performed, all 18 acres are recommended for unrestricted industrial use to 10 ft bgs. Three Federal Facility Agreement sites are addressed and recommended for no further action within this acreage, including: (1) K-1004-L Recirculating Cooling Water Lines Leak Sites; (2) K-1044 Heavy Equipment Repair Shop; and (3) K-1015-A Laundry Pit. Remedial actions for EU Z2-33 were developed in response to DVS characterization results described in the EU Z2-33 Technical Memorandum (Appendix A) and to support reindustrialization of the East Tennessee Technology Park as a commercial industrial park. Remediation criteria were designed for the protection of a future industrial worker who normally would not have the potential for exposure to soil below 10ft bgs. Accordingly, the Zone 2 ROD required land use controls to prevent disturbance of soils below 10 ft deep and to restrict future land use to industrial/commercial activities. In response to stakeholder comments, the U.S. Department of Energy agreed to re-evaluate the need for such land use restrictions. This document includes a screening evaluation to determine the likel

Bechtel Jacobs

2008-09-11T23:59:59.000Z

386

Proceedings: Cases in Sustainable Consumption and Production: Workshop of the Sustainable Consumption Research Exchange (SCORE!) Network, supported by the EU's 6th  

E-Print Network [OSTI]

1 Proceedings: Cases in Sustainable Consumption and Production: Workshop of the Sustainable Consumption Research Exchange (SCORE!) Network, supported by the EU's 6th Framework Program, Paris, 4-5 June. The environmental excise duty has resulted in considerable change in the patterns of consumption of cars

387

The European Forest Institute and the Finnish Forest Research Institute: The supply of woody biomass from the forests in the EU can be  

E-Print Network [OSTI]

Karelia in Eastern Finland showed that if the paying ability of a user of logging residues reduces 4, Finnish Forest Research Institute, tel. +358 50 391 3088, perttu.anttila @ metla.fi Final reports: http://ec.europa.eu/energy/renewables/studies/bioenergy

388

EU, U.S., Russia, Asian States Sign Nuclear-Fusion Reactor May 24 (Bloomberg) --The European Union, the U.S., Russia and Asian nations  

E-Print Network [OSTI]

Europe EU, U.S., Russia, Asian States Sign Nuclear-Fusion Reactor Pact May 24 (Bloomberg) -- The European Union, the U.S., Russia and Asian nations including China signed a treaty to build the first percent, China, India, South Korea and Russia 10 percent each and France 8 percent, #12;according

389

Magnetic and Transport Properties of the Magnetic Polaron: Application to Eu1xLaxB6 System Unjong Yu and B. I. Min  

E-Print Network [OSTI]

Magnetic and Transport Properties of the Magnetic Polaron: Application to Eu1ÿxLaxB6 System Unjong Yu and B. I. Min Department of Physics, Pohang University of Science and Technology, Pohang 790-784, Korea (Received 8 September 2004; published 22 March 2005) To understand the role of the magnetic

Min, Byung Il

390

Hydrothermal synthesis of Ln(OH)3 nanorods and the conversion to Ln2O3 (Ln = Eu, Nd, Dy) nanorods via annealing process  

Science Journals Connector (OSTI)

One-dimensional rare earth oxides and hydroxides are of importance in many applications due to their rich physicochemical properties. In this work, we synthesized Ln(OH)3 (Ln = Eu, Nd, Dy) nanorods by a hydrothermal method with the assistance ...

Yanhua Zhu, Xiang Zhai, Lingling Wang

2013-01-01T23:59:59.000Z

391

White light emission and energy transfer in Dy3+/Eu3+ co-doped BaLa2WO7 phosphors  

Science Journals Connector (OSTI)

Abstract Tunable full color emissive BaLa1.75 ? xWO7:0.25Dy3+, xEu3+ phosphors which peaked at 484 nm (blue), 572 nm (yellow), 593 nm (orange), and 617 nm (red) were synthesized by the traditional solid-state reaction method. The as-synthesized phosphors were characterized by X-ray power diffraction, diffused reflectance spectra, photoluminescence decay curves, photoluminescence excitation and emission spectra. The photoluminescence excitation spectra range from 200 to 500 nm, including an O2??W6+ charge transfer band and several 4f–4f transition peaks of Dy3+ and Eu3+. Co-doping with Eu3+ compensated the red emission component of the BaLa2WO7:Dy3+ phosphor. Furthermore, the energy transfer from Dy3+ to Eu3+ was confirmed based on the luminescence spectra and decay curves. The intense white light emissions are suggestive exploration for the potential phosphor for optical materials applications used in the ultraviolet excited white light emitting diodes.

Yaomin Deng; Shuangping Yi; Jun Huang; Jieqiang Xian; Weiren Zhao

2014-01-01T23:59:59.000Z

392

EU bids to force Japan's hand in nuclear haggle Europe is bidding to force Japan's hand in negotiations on a revolutionary nuclear  

E-Print Network [OSTI]

EU bids to force Japan's hand in nuclear haggle 25/11/2004 Europe is bidding to force Japan's hand in negotiations on a revolutionary nuclear energy project, by pledging to go it alone unless Japan gives over the choice of site, whether Japan or France. "The Commission will try to reach a positive

393

Is recycling technology innovation a major driver for technology shift in the automobile industry under an EU context?  

Science Journals Connector (OSTI)

A recent EU directive addresses End-of-Life Vehicles (ELV) as a waste-management problem to be faced on the basis of 'extended producer responsibility' and stipulates minimum reuse and recovery rates for end-of-life vehicles. The task of creating an economically robust recycling infrastructure involves a significant effort to develop systems and procedures that will have to meet requirements established by the ELV directive. In particular, recent innovations in automotive-shredder residue-separation technologies and subsequent materials recycling are a candidate to constitute an alternative strategy to classic component-dismantling procedures. This paper makes use of a systems dynamics model, applied to the Portuguese ELV-processing infrastructure, to evaluate how current practices under different recycling strategies depend on recycled materials markets and on car composition. The main objective is to discuss how far recycling technology innovation can be a major driver for technology shift in the automobile industry.

Jose Amaral; Paulo Ferrao; Catia Rosas

2006-01-01T23:59:59.000Z

394

Photodegradation of luminescence in organic-ligand-capped Eu{sup 3+}:LaF{sub 3} nano-particles  

SciTech Connect (OSTI)

The luminescence from europium doped lanthanum trifluoride (Eu{sup 3+}:LaF{sub 3}) nano-crystals can be greatly enhanced by capping with ?-diketonate organic ligands. Here, we report on photo-stability measurements for the case of nano-crystals capped with thenoyltrifluroacetone (TTA) and compared with those capped with an inactive ligand, oleic acid. With exposure to UV pump light, we observed significant decrease in fluorescence and change in emission spectrum of the TTA-capped nano-particles whilst the fluorescence lifetime remained approximately constant. After a dose of order 70?kJ?cm{sup ?2}, the luminescence level was similar to that of oleic acid capped nano-crystals. We discuss possible mechanisms.

King, Gavin G. G.; Taylor, Luke R.; Longdell, Jevon J., E-mail: jevon.longdell@otago.ac.nz [Department of Physics, University of Otago, P.O. Box 56, Dunedin 9054 (New Zealand); Clarke, David J.; Quilty, J. W. [Callaghan Innovation Research Limited, P.O. Box 31-310, Lower Hutt 5040 (New Zealand)

2014-01-28T23:59:59.000Z

395

Accelerator Quality HTS Dipole Magnet Demonstrator designs for the EuCARD-2, 5 Tesla 40 mm Clear Aperture Magnet  

E-Print Network [OSTI]

Future high-energy accelerators will need very high magnetic fields in the range of 20 T. The EuCARD-2 work-package-10 is a collaborative push to take HTS materials into an accelerator quality demonstrator magnet. The demonstrator will produce 5 T standalone and between 17 T and 20 T, when inserted into the 100 mm aperture of Fresca-2 high field out-sert magnet. The HTS magnet will demonstrate the field strength and field quality that can be achieved. An effective quench detection and protection system will have to be developed to operate with the HTS superconducting materials. This paper presents a ReBCO magnet design using multi strand Roebel cable that develops a stand-alone field of 5 T in a 40 mm clear aperture and discusses the challenges associated with good field quality using this type of material. A selection of magnet designs is presented as result of a first phase of development.

Kirby, G; Ballarino, A; Bottura, L; Chouika, N; Clement, S; Datskov, V; Fajardo, L; Fleiter, J; Gauthier, R; Lambert, L; Lopes, M; Perez, J; DeRijk, G; Rijllart, A; Rossi, L; Ten Kate, H; Durante, M; Fazilleau, P; Lorin, C; Haro, E; Stenvall, A; Caspi, S; Marchevsky, M; Goldacker, W; Kario, A

2014-01-01T23:59:59.000Z

396

Materials R&D for a timely DEMO: Key findings and recommendations of the EU Roadmap Materials Assessment Group  

Science Journals Connector (OSTI)

Abstract The findings of the EU Fusion Programme's ‘Materials Assessment Group’ (MAG), assessing readiness of Structural, Plasma Facing (PF) and High Heat Flux (HHF) materials for DEMO, are discussed. These are incorporated into the EU Fusion Power Roadmap [1], with a decision to construct DEMO in the early 2030s. The methodology uses project-based and systems-engineering approaches, the concept of Technology Readiness Levels, and considers lessons learned from Fission reactor material development. ‘Baseline’ materials are identified for each DEMO role, and the DEMO mission risks analysed from the known limitations, or unknown properties, associated with each baseline material. R&D programmes to address these risks are developed. The DEMO assessed has a phase I with a ‘starter blanket’: the blanket must withstand ?2 MW yr m?2 fusion neutron flux (equivalent to ?20 dpa front-wall steel damage). The baseline materials all have significant associated risks, so development of ‘Risk Mitigation Materials’ (RMM) is recommended. The R&D programme has parallel development of the baseline and RMM, up to ‘down-selection’ points to align with decisions on the DEMO blanket and divertor engineering definition. ITER licensing experience is used to refine the issues for materials nuclear testing, and arguments are developed to optimise scope of materials tests with fusion neutron (‘14 MeV’) spectra before DEMO design finalisation. Some 14  MeV testing is still essential, and the Roadmap requires deployment of a ?30 dpa (steels) testing capability by 2026. Programme optimisation by the pre-testing with fission neutrons on isotopically- or chemically-doped steels and with ion-beams is discussed along with the minimum 14 MeV testing programme, and the key role which fundamental and mission-oriented modelling can play in orienting the research.

Derek Stork; Pietro Agostini; Jean-Louis Boutard; Derek Buckthorpe; Eberhard Diegele; Sergei L. Dudarev; Colin English; Gianfranco Federici; Mark R. Gilbert; Sehila Gonzalez; Angel Ibarra; Christian Linsmeier; Antonella Li Puma; Gabriel Marbach; Lee W. Packer; Baldev Raj; Michael Rieth; Min Quang Tran; David J. Ward; Steven J. Zinkle

2014-01-01T23:59:59.000Z

397

Barrelane-like germanium clusters in Eu{sub 3}Ge{sub 5}: Crystal structure, chemical bonding and physical properties  

SciTech Connect (OSTI)

Formation and crystal structure of the binary germanide Eu{sub 3}Ge{sub 5} were investigated in detail. The compound forms peritectically at 1008deg. C and does not undergo any phase transition down to room temperature. The crystal structure was determined first from X-ray powder diffraction data and was later confirmed by single-crystal X-ray diffraction: structure type Pu{sub 3}Pd{sub 5}, space group Cmcm (no. 63), a=9.7675(4)A, b=7.9681(3)A, c=9.8562(3)A. The main building blocks are Ge{sub 5}{sup 6-} cluster anions surrounded by Eu{sup 2+} cations. The nearly tetragonal-pyramidal shape is suggested by the interatomic distances. Contrary to that, the bonding analysis with the electron localization function (ELF) reveals only two- and three-bonded germanium atoms forming a strongly distorted [1.1.1]-barrelane-like cluster. Despite the formal electron deficiency, compared to the barrelane C{sub 5}H{sub 8}, the electron counting in the cluster anion and its conformation cannot be interpreted applying the Wade's rules. In accordance with the calculated electronic density of states, Eu{sub 3}Ge{sub 5} shows a metal-like temperature dependence of the electrical resistivity with a sharp change of {rho}(T) slope at the Neel point. Above the Neel point the inverse magnetic susceptibility reveals Curie-Weiss behavior with an effective moment of 8.11{mu}{sub B} (Eu{sup 2+}, 4f{sup 7} configuration) in agreement with the analysis of the chemical bonding. The 4f{sup 7} electronic configuration of europium is confirmed by Eu-L{sub III} X-ray absorption spectroscopy.

Budnyk, Sergij [Max-Planck-Institut fuer Chemische Physik fester Stoffe, Noethnitzer Str. 40, 01187 Dresden (Germany); Weitzer, Franz [AG Neue Materialien, Universitaet Wien, Waehringerstr. 42, 1090 Vienna (Austria); Kubata, Christof [Laboratorium fuer Anorganische Chemie, ETH Hoenggerberg, HCI, 8093 Zurich (Switzerland); Collegium Helveticum, 3092 Zuerich (Switzerland); Prots, Yurii [Max-Planck-Institut fuer Chemische Physik fester Stoffe, Noethnitzer Str. 40, 01187 Dresden (Germany); Akselrud, Lev G. [Institut of Inorganic Chemistry, University of Lviv, Kyrylo and Methody Str. 6, 79005 Lviv (Ukraine); Schnelle, Walter [Max-Planck-Institut fuer Chemische Physik fester Stoffe, Noethnitzer Str. 40, 01187 Dresden (Germany); Hiebl, Kurt [AG Neue Materialien, Universitaet Wien, Waehringerstr. 42, 1090 Vienna (Austria); Nesper, Reinhard [Laboratorium fuer Anorganische Chemie, ETH Hoenggerberg, HCI, 8093 Zurich (Switzerland); Collegium Helveticum, 3092 Zurich (Switzerland); Wagner, Frank R. [Max-Planck-Institut fuer Chemische Physik fester Stoffe, Noethnitzer Str. 40, 01187 Dresden (Germany); Grin, Yuri [Max-Planck-Institut fuer Chemische Physik fester Stoffe, Noethnitzer Str. 40, 01187 Dresden (Germany)]. E-mail: grin@cpfs.mpg.de

2006-08-15T23:59:59.000Z

398

Fiscal Year 2009 Phased Construction Completion Report for EU Z2-36 in Zone 2, East Tennessee Technology Park, Oak Ridge, Tennessee  

SciTech Connect (OSTI)

The purpose of this Phased Construction Completion Report (PCCR) is to present fiscal year (FY) 2009 results of Dynamic Verification Strategy (DVS) characterization activities for exposure unit (EU) Z2-36 in Zone 2 at the East Tennessee technology Park (ETTP). The ETTP is located in the northwest corner of the US Department of Energy (DOE) Oak Ridge Reservation in Oak Ridge, Tennessee and encompasses approximately 5000 acres that have been subdivided into three zones--Zone 1 ({approx} 1400 acres), Zone 2 ({approx} 800 acres), and the Boundary Area ({approx} 2800 acres). Zone 2 comprises the highly industrial portion of ETTP and consists of all formerly secured areas of the facility, including the large processing buildings and direct support facilities; experimental laboratories and chemical and materials handling facilities; materials storage and waste disposal facilities; secure document records libraries; and shipping and receiving warehouses. The Record of Decision for Soil, Buried Waste, and Subsurface Structure Actions in Zone 2, East Tennessee Technology Park, Oak Ridge, Tennessee (DOE 2005) (Zone 2 ROD) specifies the future end use for Zone 2 acreage as uncontrolled industrial for the upper 10 ft of soils. Characterization activities in these areas were conducted in compliance with the Zone 2 ROD and the DVS and data quality objectives (DQOs) presented in the Main Plant Group DQO Scoping Package (July 2006) and the Remedial Design Report/Remedial Action Work Plan for Zone 2 Soils, Slabs, and Subsurface Structures, East Tennessee Technology Park, Oak Ridge, Tennessee (DOE 2007a) (Zone 2 RDR/RAWP). The purpose of this PCCR is to address the following: (1) Document EU Z2-36 DVS characterization results; (2) Describe and document the risk evaluation and determine if the EU meets the Zone 2 ROD requirements for unrestricted industrial use to 10 ft bgs, and (3) Identify additional areas not defined in the Zone 2 ROD that require remediation based on the DVS evaluation results. The Zone 2 ROD divided the area into 7 geographic areas and 44 EUs. To facilitate DQOs of the DVS process, the Zone 2 RDR/RAWP regrouped the 44 EUs into 12 DQO scoping EU groups. These groups facilitated the DqO process by placing similar facilities and their support facilities together and allowing identification of data gaps. The EU groups were no longer pertinent after DQO planning was completed, and characterization was conducted as EUs became accessible. As the opportunity to complete characterization became available, the planned DVS program was completed in FY 2009 for EU Z2-36.

Bechtel Jacobs

2009-02-10T23:59:59.000Z

399

Comment on “Tilting of the CuO6 octahedra in La1.83-xEu0.17SrxCuO4 as seen by 151Eu Mössbauer spectroscopy”  

Science Journals Connector (OSTI)

We discuss the different characteristic time scales of the x-ray absorption fine structure (XAFS), ?X, and Mössbauer spectroscopy (MS), ?MS, techniques for structural determination at small-length scales. We show that XAFS and MS can measure different local atomic arrangements in La1.83-xEu0.17SrxCuO4 provided the local structural units are dynamical. Combined knowledge from these complementary techniques is used to determine that the local tilts of the CuO6 octahedra do not vanish with temperature but are dynamic, with the oxygen atoms at the apex positions [O(2)] hopping among local minima of the energy’s surface. Evidence is found for a crossover between different time domains in which the hopping time, ?0, changes from ?0?MS. We conclude that the Mössbauer results [Phys. Rev. B 54, R800 (1996)], contrary to the authors’ conclusions, do not contradict our XAFS results [Phys. Rev. Lett. 76, 439 (1996)].

Daniel Haskel; Edward A. Stern; Hanan Shechter

1998-04-01T23:59:59.000Z

400

Space-charge-limited currents in an Se{sub 95}As{sub 5} chalcogenide glass-like semiconductor system containing EuF{sub 3} impurities  

SciTech Connect (OSTI)

It is established that charge carrier (hole) transport in the Al-Se{sub 95}As{sub 5} Left-Pointing-Angle-Bracket EuF{sub 3} Right-Pointing-Angle-Bracket -Te structure is effected by unipolar injection currents limited by space charges with the involvement of two capture trap groups. Shallow traps corresponding to charged intrinsic defects C{sub 1}{sup -} are related to broken selenium bonds. Deep traps corresponding to charged intrinsic defects P{sub 2}{sup -} are formed by arsenic atoms with broken coordination. It is shown that the EuF{sub 3} impurity strongly affects the concentration of the capture traps, especially those localized near the Fermi level.

Isayev, A. I.; Mekhtiyeva, S. I.; Qaribova, S. N., E-mail: sqaribova@rambler.ru [Azerbaijan National Academy of Sciences, Abdullaev Institute of Physics (Azerbaijan)

2011-12-15T23:59:59.000Z

Note: This page contains sample records for the topic "butyl ether eu" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Complexation of Lactate with Nd(III) and Eu(III) at Variable Temperatures: Studies by Potentiometry, Microcalorimetry, Optical Absorption and Luminescence Spectroscopy  

SciTech Connect (OSTI)

Complexation of neodymium(III) and europium(III) with lactate was studied at variable temperatures by potentiometry, absorption spectrophotometry, luminescence spectroscopy and microcalorimetry. Stability constants of three successive lactate complexes (ML{sup 2+}, ML{sup 2+} and ML{sub 3}(aq), where M stands for Nd and Eu, and L stands for lactate) at 10, 25, 40, 55 and 70 C were determined. The enthalpies of complexation at 25 C were determined by microcalorimetry. Thermodynamic data show that the complexation of trivalent lanthanides (Nd{sup 3+} and Eu{sup 3+}) with lactate is exothermic, and the complexation becomes weaker at higher temperatures. Results from optical absorption and luminescence spectroscopy suggest that the complexes are inner-sphere chelate complexes in which the protonated {alpha}-hydroxyl group of lactate participates in the complexation.

Tian, Guoxin; Martin, Leigh R.; Rao, Linfeng

2010-10-01T23:59:59.000Z

402

Luminescent properties of phosphor converted LED using an orange-emitting Rb{sub 2}CaP{sub 2}O{sub 7}:Eu{sup 2+} phosphor  

SciTech Connect (OSTI)

Graphical abstract: Display Omitted Highlights: ? Phase-pure Rb{sub 2}CaP{sub 2}O{sub 7}:Eu{sup 2+} powders were synthesized by a solid state reaction process. ? The optimum emission intensity was observed at the Eu{sup 2+} ion concentration of 0.006. ? The dipole–dipole interaction was the major concentration quenching mechanism. ? The pc-LED coated with Rb{sub 2}CaP{sub 2}O{sub 7}:Eu{sup 2+} had higher CRI than commercial red phosphor. -- Abstract: A series of orange-emitting Rb{sub 2}CaP{sub 2}O{sub 7}:Eu{sup 2+} phosphors were synthesized by a conventional solid-state reaction method. The as-prepared phosphors were characterized by X-ray powder diffraction (XRD), fluorescence spectroscopy, and spectroradiometry. XRD showed that all prepared samples exhibited a monoclinic Rb{sub 2}CaP{sub 2}O{sub 7} phase. Fluorescence spectroscopy showed that the photoluminescence efficiency of Rb{sub 2}Ca{sub 1?x}P{sub 2}O{sub 7}:Eu{sub x}{sup 2+} phosphors increased with increasing Eu{sup 2+} concentration until x = 0.006, then decreased at higher concentrations, due to a concentration quenching effect. The thermal activation energy was also measured to be 0.40 eV. Furthermore, a phosphor-converted LED (pc-LED) coated with Rb{sub 2}Ca{sub 0.994}P{sub 2}O{sub 7}:Eu{sub 0.006}{sup 2+} was fabricated, which exhibited bright orange emission under a forward bias, from 200 to 300 mA. The color rendering index (CRI) of pc-LED coated with Rb{sub 2}Ca{sub 0.994}P{sub 2}O{sub 7}:Eu{sub 0.006}{sup 2+} was higher than the CRI of pc-LED coated with commercial red phosphor, due to the broad emission band of Rb{sub 2}CaP{sub 2}O{sub 7}:Eu{sup 2+} phosphor. In applying with three-band pc-LEDs, moreover, white pc-LED using Rb{sub 2}CaP{sub 2}O{sub 7}:Eu{sup 2+} phosphor had a higher CRI, than using commercial phosphor. These results indicated that Rb{sub 2}CaP{sub 2}O{sub 7}:Eu{sup 2+} phosphor could be a good candidate for a near-UV based w-LED.

Song, Hee Jo; Yim, Dong Kyun [Department of Materials Science and Engineering, College of Engineering, Seoul National University, Daehak-dong, Gwanak-gu, Seoul 151-744 (Korea, Republic of)] [Department of Materials Science and Engineering, College of Engineering, Seoul National University, Daehak-dong, Gwanak-gu, Seoul 151-744 (Korea, Republic of); Cho, In-Sun [Department of Mechanical Engineering, Stanford University, CA 94305 (United States)] [Department of Mechanical Engineering, Stanford University, CA 94305 (United States); Roh, Hee-Suk; Kim, Ju Seong [Department of Materials Science and Engineering, College of Engineering, Seoul National University, Daehak-dong, Gwanak-gu, Seoul 151-744 (Korea, Republic of)] [Department of Materials Science and Engineering, College of Engineering, Seoul National University, Daehak-dong, Gwanak-gu, Seoul 151-744 (Korea, Republic of); Kim, Dong-Wan, E-mail: dwkim@ajou.ac.kr [Department of Materials Science and Engineering, Ajou University, Woncheon-dong, San 5, Yeongtong-gu, Suwon 443-749 (Korea, Republic of)] [Department of Materials Science and Engineering, Ajou University, Woncheon-dong, San 5, Yeongtong-gu, Suwon 443-749 (Korea, Republic of); Hong, Kug Sun, E-mail: kshongss@plaza.snu.ac.kr [Department of Materials Science and Engineering, College of Engineering, Seoul National University, Daehak-dong, Gwanak-gu, Seoul 151-744 (Korea, Republic of)

2012-12-15T23:59:59.000Z

403

Emission intensity in the visible and IR spectral ranges from Si-based structures formed by direct bonding with simultaneous doping with erbium (Er) and europium (Eu)  

SciTech Connect (OSTI)

The photo- and electroluminescence spectra of silicon-based structures formed by direct bonding with simultaneous doping with rare-earth metals are studied. It is shown that emission in the visible and IR spectral ranges can be obtained from n-Si:Er/p-Si and n-Si:Eu/p-Si structures fabricated by the method suggested in the study. The results obtained make this method promising for the fabrication of optoelectronic devices.

Mezdrogina, M. M., E-mail: margaret.m@mail.ioffe.ru; Kostina, L. S.; Beliakova, E. I.; Kuzmin, R. V. [Russian Academy of Sciences, Ioffe Physical-Technical Institute (Russian Federation)] [Russian Academy of Sciences, Ioffe Physical-Technical Institute (Russian Federation)

2013-09-15T23:59:59.000Z

404

Print Story: Japan has told EU it is giving up on nuclear reactor bid:... http://news.yahoo.com/s/afp/20050622/wl_asia_afp/japaneufrancenuc... 1 of 1 6/22/05 12:12 AM  

E-Print Network [OSTI]

Print Story: Japan has told EU it is giving up on nuclear reactor bid:... http://news.yahoo.com/s/afp/20050622/wl_asia_afp/japaneufrancenuc... 1 of 1 6/22/05 12:12 AM Back to Story - Help Japan has told EU it is giving up on nuclear reactor bid: report 1 hour, 51 minutes ago Japan has told the European Union

405

Fiscal Year 2010 Phased Construction Completion Report for EU Z2-32 in Zone 2, East Tennessee Technology Park, Oak Ridge, Tennessee  

SciTech Connect (OSTI)

The Record of Decision for Soil, Buried Waste, and Subsurface Structure Actions in Zone 2, East Tennessee Technology Park, Oak Ridge, Tennessee (DOEIORJO 1-2161 &D2) (Zone 2 ROD) acknowledged that most of the 800 acres in Zone 2 were contaminated, but that sufficient data to confirm the levels of contamination were lacking. The Zone 2 ROD further specified that a sampling strategy for filling the data gaps would be developed. The Remedial Design Report/Remedial Action Work Plan for Zone 2 Soils, Slabs, and Subsurface Structures, East Tennessee Technology Park, Oak Ridge, Tennessee (DOEIORIO 1 -2224&D3) (RDRJRAWP) defined the sampling strategy as the Dynamic Verification Strategy (DVS), generally following the approach used for characterization of the Zone I exposure units (EUs). The Zone 2 ROD divided the Zone 2 area into seven geographic areas and 44 EUs. To facilitate the data quality objectives (DQOs) of the DVS process, the RDR/RAWP regrouped the 44 EUs into 12 DQO scoping EU groups. These groups facilitated the DQO process by placing similar facilities and their support facilities together, which allowed identification of data gaps. The EU groups were no longer pertinent after DQO planning was completed and characterization was conducted as areas became accessible. As the opportunity to complete characterization became available, the planned DVS program was completed for the EU addressed in this document (EU Z2-32). The purpose of this Phased Construction Completion Report (PCCR) is to address the following: (1) Document DVS characterization results for EU Z2-32. (2) Describe and document the risk evaluation and determine if the EU meets the Zone 2 ROD requirements for unrestricted industrial use to 10 ft bgs. (3) Identify additional areas not defined in the Zone 2 ROD that require remediation based on the DVS evaluation results. (4) Describe the remedial action performed in the K-1066-G Yard in EU Z2-32. Approximately 18.4 acres are included in the EU addressed in this PCCR. Based on results of the DVS evaluation, all 18.4 acres are recommended for unrestricted industrial use to 10 ft bgs. There are no Federal Facility Agreement Sites included in Appendix A of the Zone 2 ROD in EU Z2-32. The Zone 2 ROD requires land use controls to prevent disturbance of soils below 10 ft deep and to restrict future land use to industrial/commercial activities. In response to stakeholder comments, the U.S. Department of Energy agreed to re-evaluate the need for such land use restrictions. This document includes a screening evaluation to determine the likelihood of land use controls in EU Z2-32 being modified to: (1) eliminate the restriction on disturbance of soils below 10 ft bgs where data indicate the absence of residual contamination at any depth that would result in an unacceptable risk to the future industrial worker, and (2) permit alternative land uses that would be protective of future site occupants. Results of this screening evaluation indicate a high probability that restrictions on disturbing soil below 10 ft bgs could be safely eliminated for EU Z2-32. A qualitative screening evaluation considered the likelihood of unrestricted land use being protective of future site occupants. Based on this qualitative assessment, all 18.4 acres addressed in this PCCR were assigned a high probability for consideration of release for unrestricted land use. This document contains the main text (Sects. 1 through 13) and one appendix. The main text addresses the purpose for this PCCR as described above. Additional supporting detail (e.g., field work and data summaries, graphics) is provided in the EU Z2-32 technical memorandum (Appendix A). Historical and DVS analytical data used in this PCCR are provided on a compact disc accompanying this document and can be accessed through the Oak Ridge Environmental Information System.

Bechtel Jacobs

2010-02-01T23:59:59.000Z

406

Integrated management of marine biodiversity in Europe: Perspectives from ICZM and the evolving EU Maritime Policy framework  

Science Journals Connector (OSTI)

Biological diversity, or biodiversity, is high on the international agenda for nature conservation. Marine and coastal ecosystems account for an important share of the biological diversity on Earth. As a consequence many international conventions, European legislation and national laws refer to marine biodiversity. The protection of marine biodiversity is a complex legal issue as it requires consideration of geographic (between land and sea), political (between conservation and exploitation), and economic (between fisheries, tourism, intellectual property and many other sectors) factors. Like Matryoshka dolls, marine biodiversity is a heterogeneous notion difficult to address as one discrete area in the development of policy agendas or juridical frameworks. In the past decade, the EU has been very active in Promoting Integrated Coastal Zone Management and in developing a framework for an Integrated Maritime Policy. This article reviews the status of marine biodiversity in the policy and legal initiatives of the European Union, a challenging issue to both the objectives of conservation and to the concept of integration.

Betty Queffelec; Valerie Cummins; Denis Bailly

2009-01-01T23:59:59.000Z

407

Luminescence properties of a blue-emitting phosphor: (Sr{sub 1?x}Eu{sub x})Si{sub 9}Al{sub 19}ON{sub 31} (0  

SciTech Connect (OSTI)

Blue-emitting Sr{sub 1?x}Eu{sub x}Si{sub 9}Al{sub 19}ON{sub 31} phosphors were synthesized at 1800 °C for 2 h under 1 MPa N{sub 2} by using the gas-pressure sintering method (GPS). The microstructure, photoluminescence (PL) properties of the prepared phosphors were investigated. Under the 290 nm excitation, broad PL emission bands with peak positions at 448–490 nm were detected. The concentration quenching was not observed owing to the large distance betweenEu{sup 2+} ions that made the nonradiative energy transfer between neighboring Eu{sup 2+} ions difficult. The blue phosphor generally showed a small thermal quenching at low Eu{sup 2+} concentrations. The absorption and external quantum efficiency of the synthesized Sr{sub 0.5}Eu{sub 0.5}Si{sub 9}Al{sub 19}ON{sub 31} were 85% and 62% upon the 365 nm excitation, respectively. The interesting PL results indicate that Sr{sub 1?x}Eu{sub x}Si{sub 9}Al{sub 19}ON{sub 31} has great potentials as a blue phosphor for white LEDs applications. - Graphical abstract: Sr{sub 0.7}Eu{sub 0.3}Si{sub 9}Al{sub 19}ON{sub 31} gives blue-emitting at 471 nm. Excitation spectrum is composed of five bands in the range of 250–450 nm, which are matching well with emission wavelength of UV LEDs. Display Omitted - Highlights: • Blue-emitting Sr{sub 1?x}Eu{sub x}Si{sub 9}Al{sub 19}ON{sub 31} phosphors were synthesized by gas-pressure sintering method. • The concentration quenching was not observed in this phosphor. • This blue phosphor generally showed a small thermal quenching at low Eu{sup 2+} concentrations. • The absorption and external quantum efficiency of the synthesized Sr{sub 0.5}Eu{sub 0.5}Si{sub 9}Al{sub 19}ON{sub 31} were 85% and 62% upon the 365 nm excitation.

Liu, Lihong [Structural and Functional Integration of Ceramics Group, The Division of Functional Materials and Nanodevices, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, Zhejiang 315201 (China); Xie, Rong-Jun, E-mail: XIE.Rong-Jun@nims.go.jp [Sialon Group, Sialon Unit, National Institute for Materials Science, Namiki 1-1, Tsukuba, Ibaraki 305-0044 (Japan); Hirosaki, Naoto; Dierre, Benjamin [Sialon Group, Sialon Unit, National Institute for Materials Science, Namiki 1-1, Tsukuba, Ibaraki 305-0044 (Japan); Sekiguchi, Takashi [Advanced Electronic Materials Center, National Institute for Materials Science, Namiki 1-1, Tsukuba, Ibaraki 305-0044 (Japan)

2013-11-15T23:59:59.000Z

408

Defect correlated fluorescent quenching and electron phonon coupling in the spectral transition of Eu{sup 3+} in CaTiO{sub 3} for red emission in display application  

SciTech Connect (OSTI)

This paper reports on the defect correlated self-quenching and spectroscopic investigation of calcium titanate (CaTiO{sub 3}) phosphors. A series of CaTiO{sub 3} phosphors doped with trivalent europium (Eu{sup 3+}) and codoped with potassium (K{sup +}) ions were prepared by the solid state reaction method. The X-ray diffraction results revealed that the obtained powder phosphors consisted out of a single-phase orthorhombic structure and it also indicated that the incorporation of the dopants/co-dopants did not affect the crystal structure. The scanning electron microscopy images revealed the irregular morphology of the prepared phosphors consisting out of ?m sized diameter particles. The Eu{sup 3+} doped phosphors illuminated with ultraviolet light showed the characteristic red luminescence corresponding to the {sup 5}D{sub 0}?{sup 7}F{sub J} transitions of Eu{sup 3+}. As a charge compensator, K{sup +} ions were incorporated into the CaTiO{sub 3}:Eu{sup 3+} phosphors, which enhanced the photoluminescence (PL) intensities depending on the doping concentration of K{sup +}. The concentration quenching of Eu{sup 3+} in this host is discussed in the light of ion-ion interaction, electron phonon coupling, and defect to ion energy transfer. The spectral characteristics and the Eu-O ligand behaviour were determined using the Judd-Ofelt theory from the PL spectra instead of the absorption spectra. The CIE (International Commission on Illumination) parameters were calculated using spectral energy distribution functions and McCamy's empirical formula. Photometric characterization indicated the suitability of K{sup +} compensated the CaTiO{sub 3}:Eu{sup 3+} phosphor for pure red emission in light-emitting diode applications.

Som, S., E-mail: sudipta.som@gmail.com, E-mail: swarthc@ufs.ac.za; Kumar, Vinod; Kumar, Vijay; Terblans, J. J.; Swart, H. C., E-mail: sudipta.som@gmail.com, E-mail: swarthc@ufs.ac.za [Department of Physics, University of the Free State, Box 339, Bloemfontein 9300 (South Africa); Kunti, A. K.; Dutta, S.; Chowdhury, M.; Sharma, S. K. [Department of Applied Physics, Indian School of Mines, Dhanbad 826004 (India)

2014-05-21T23:59:59.000Z

409

LANXESS Global Butyl Rubber Research Facility  

E-Print Network [OSTI]

Park, in partnership with Surface Science Western $10million City of London Investment in Fraunhofer- fraunhofer Agreement chosen to highlight celebrations for 40th Anniversary of Canada-Germany cooperation fuel cluster in Sarnia-Lambton, said Sarnia Mayor Mike Bradley, noting the Bioindustrial Innovation

Denham, Graham

410

High-Temperature Thermoelectric Properties of the Solid–Solution Zintl Phase Eu11Cd6Sb12–xAsx (x < 3)  

SciTech Connect (OSTI)

Zintl phases are compounds that have shown promise for thermoelectric applications. The title solid–solution Zintl compounds were prepared from the elements as single crystals using a tin flux for compositions x = 0, 1, 2, and 3. Eu11Cd6Sb12–xAsx (x < 3) crystallize isostructurally in the centrosymmetric monoclinic space group C2/m (no. 12, Z = 2) as the Sr11Cd6Sb12 structure type (Pearson symbol mC58). Efforts to make the As compositions for x exceeding ?3 resulted in structures other than the Sr11Cd6Sb12 structure type. Single-crystal X-ray diffraction indicates that As does not randomly substitute for Sb in the structure but is site specific for each composition. The amount of As determined by structural refinement was verified by electron microprobe analysis. Electronic structures and energies calculated for various model structures of Eu11Cd6Sb10As2 (x = 2) indicated that the preferred As substitution pattern involves a mixture of three of the six pnicogen sites in the asymmetric unit. In addition, As substitution at the Pn4 site opens an energy gap at the Fermi level, whereas substitution at the other five pnicogen sites remains semimetallic with a pseudo gap. Thermoelectric properties of these compounds were measured on hot-pressed, fully densified pellets. Samples show exceptionally low lattice thermal conductivities from room temperature to 775 K: 0.78–0.49 W/mK for x = 0; 0.72–0.53 W/mK for x = 1; and 0.70–0.56 W/mK for x = 2. Eu11Cd6Sb12 shows a high p-type Seebeck coefficient (from +118 to 153 ? V/K) but also high electrical resistivity (6.8 to 12.8 m?·cm). The value of zT reaches 0.23 at 774 K. The properties of Eu11Cd6Sb12–xAsx are interpreted in discussion with the As site substitution.

Kazem, Nasrin; Xie, Weiwei; Ohno, Saneyuki; Zevalkink, Alexandra; Miller, Gordon J.; Snyder, G. Jeffrey; Kauzlarich, Susan M.

2014-02-11T23:59:59.000Z

411

Binuclear complexes of La(III) and Eu(II) with the bridging naphthalene dianion. Synthesis and X-ray crystallographic analysis of [?2-?4:?4-C10H8][LaI2(THF)3]2 and [?2-?4:?4-C10H8][EuI(DME)2]2  

Science Journals Connector (OSTI)

The treatment of LaI3(THF)3 with equimolar amounts of Li and excess of C10H8 in THF results in the formation of [C10H8][LaI2(THF)3]2 (1) and the reaction of EuI2(THF)2 with Li and C10H8 in DME leads to [C10H8][EuI(DME)2]2 (2), which have been characterized by IR and UV-VIS spectroscopy as well as by X-ray crystallography. 1 is monoclinic, space group P21/c (No. 14), Z = 4, with a = 1314.2(6), b = 1256.7(5), c = 1697.2(4) pm, ? = 93.53(3)°. The structure was refined to R = 0.045 for 2377 observed reflections(F0 > 4?(F0)). 2 is monoclinic, space group P21/n, Z = 4 with a = 1015.1(3), b = 1389.8(4), c = 1269.8(3) pm, ? = 97.51(2)°. The structure was refined to R = 0.0408 for 2687 observed reflections (F0 > 4?(F0)). Both molecules contain two LaI2(THF) (1) or EuI(DME) moieties (2), bridged ?4 each by a non planar naphthalene with dihedral angles of 15° (1) and 6° (2) respectively.

Igor L. Fedushkin; Mikhail N. Bochkarev; Herbert Schumann; Lothar Esser

1995-01-01T23:59:59.000Z

412

Oxygen concentration of Eu sub 1 Ba sub 2 Cu sub 3 O sub 7 minus x in vacuum: An atom probe study  

SciTech Connect (OSTI)

Atom Probe mass analysis, at 85 K, using a wide-angle instrument was used to measure the oxygen content and metallic stoichiometry of the near-surface region of the superconducting ceramic oxide Eu{sub 1}Ba{sub 2}Cu{sub 3}O{sub 7{minus}{ital x}} ({ital x}{approx equal}0.1) after vacuum exposure at room temperature. Routine specimen preparation, handling, and field-ion imaging produced a specimen which had already lost oxygen such that its measured surface oxygen content corresponded to {ital x}=0.73 and the metallic stoichiometry of the surface was not the expected 1:2:3 but was enhanced in Ba and Eu. The specimen was subsequently exposed to vacuum for up to 80 h at room temperature and no additional loss of oxygen was detected. It was concluded that either (1) a stoichiometric low-oxygen surface also would not have lost oxygen or (2) the nonstoichiometric layer forms a barrier for subsequent oxygen loss.

Elswijk, H.B.; Melmed, A.J.; Camus, P.P. (National Institute of Standards and Technology, Surface Science Division, Gaithersburg, Maryland 20899 (US))

1989-12-18T23:59:59.000Z

413

Boosting medicine with nanotechnology to destroy cancers AnProN AnProN http://anpron.eu/?p=738[4/21/2011 11:41:09 AM  

E-Print Network [OSTI]

Boosting medicine with nanotechnology to destroy cancers « « AnProN AnProN http://anpron.eu/?p=738Org Posts Related to Boosting medicine with nanotechnology to destroy cancers » Nanoparticles With Honeycomb[4/21/2011 11:41:09 AM] AnProNAnalysis Prognosis News Home About AnProN Contacts Boosting medicine

Brinker, C. Jeffrey

414

The influence of auxiliary codopants on persistent phosphor Sr{sub 2}P{sub 2}O{sub 7}:Eu{sup 2+},R{sup 3+} (R = Y, La, Ce, Gd, Tb and Lu)  

SciTech Connect (OSTI)

Graphical abstract: Rare earth ions which close to the line are good codopants. - Highlights: • The persistent luminescence in Sr{sub 2}P{sub 2}O{sub 7}:Eu{sup 2+},R{sup 3+} was reported. • Sr{sub 2}P{sub 2}O{sub 7}:Eu{sup 2+},Lu{sup 3+} shows the best performance. • The influence of auxiliary codopants was discussed in terms of ionic potential and ionic radius. - Abstract: We investigate the persistent luminescence in europium-doped strontium pyrophosphate upon codoping with auxiliary rare earth ions. The persistent phosphors are synthesized via solid-state reaction method under flowing N{sub 2} + H{sub 2}. Under UV irradiation, broadband emission persistent luminescence located at 420 nm is observed in all of these phosphors at room temperature. The effects of auxiliary rare earth ions on Sr{sub 2}P{sub 2}O{sub 7}:Eu{sup 2+} are discussed according to the decay curves and thermoluminescence spectra. Sr{sub 2}P{sub 2}O{sub 7}:Eu{sup 2+},Lu{sup 3+} shows the best performance, while and La{sup 3+} and Ce{sup 3+} codoped samples are the weakest. The influence of auxiliary codopants is discussed in terms of ionic potential and ionic radius. We derive an empirical formula based on the experimental results.

Ju, Guifang; Hu, Yihua, E-mail: huyh@gdut.edu.cn; Chen, Li; Wang, Xiaojuan; Mu, Zhongfei

2013-11-15T23:59:59.000Z

415

Comparative Evaluation of a New Commercial Colorimetric Microdilution Assay (SensiQuattro Candida EU) With MIC Test Strip and EUCAST Broth Microdilution for Susceptibility Testing of Invasive Candida Isolates  

Science Journals Connector (OSTI)

...Assay (SensiQuattro Candida EU) With MIC Test Strip and EUCAST Broth Microdilution for...susceptibility testing to that of Liofilchem's MIC Test Strip and the EUCAST reference broth microdilution...Compared to the SensiQuattro panel, the MIC Test Strip exhibited a higher level of agreement...

Hedda Luise Koehling; Birgit Willinger; Jan Buer; Peter-Michael Rath; Joerg Steinmann

2014-11-12T23:59:59.000Z

416

Synthesis, structural characterization and properties of SrAl{sub 4?x}Ge{sub x}, BaAl{sub 4?x}Ge{sub x}, and EuAl{sub 4?x}Ge{sub x} (x?0.3–0.4)—Rare examples of electron-rich phases with the BaAl{sub 4} structure type  

SciTech Connect (OSTI)

Three solid solutions with the general formula AEAl{sub 4?x}Ge{sub x} (AE=Eu, Sr, Ba; 0.32(1)?x?0.41(1)) have been synthesized via the aluminum self-flux method, and their crystal structures have been established from powder and single-crystal X-ray diffraction. They are isotypic and crystallize with the well-known BaAl{sub 4} structure type, adopted by the three AEAl{sub 4} end members. In all structures, Ge substitutes Al only at the 4e Wyckoff site. Results from X-rays photoelectron spectroscopy on EuAl{sub 4?x}Ge{sub x} and EuAl{sub 4} indicate that the interactions between the Eu{sup 2+} cations and the polyanionic framework are enhanced in the Ge-doped structure, despite the slightly elevated Fermi level. Magnetic susceptibility measurements confirm the local moment magnetism, expected for the [Xe]4f{sup 7} electronic configuration of Eu{sup 2+} and suggest strong ferromagnetic interactions at cryogenic temperatures. Resistivity data from single-crystalline samples show differences between the title compounds, implying different bonding characteristics despite the close Debye temperatures. A brief discussion on the observed electron count and homogeneity ranges for AEAl{sub 4?x}Ge{sub x} (AE=Eu, Sr, Ba) is also presented. - Graphical abstract: AEAl{sub 4?x}Ge{sub x} (AE=Eu, Sr, Ba; 0.32(1)?x?0.41(1)), three “electron-rich” phases with BaAl{sub 4} structure type have been synthesized and characterized. Display Omitted - Highlights: • Three BaAl{sub 4}-type ternary aluminum germanides have been synthesized with Eu, Sr and Ba. • Eu, Sr and Ba cations have no apparent influence on the solubility of Ge. • The Ge atoms substitute Al on one of two framework sites, thereby strengthening the interactions between the cations and the polyanionic framework.

Zhang, Jiliang; Bobev, Svilen, E-mail: bobev@udel.edu

2013-09-15T23:59:59.000Z

417

Thermoelectric transport properties of CaMg2Bi2, EuMg2Bi2, and YbMg2Bi2  

SciTech Connect (OSTI)

The thermoelectric transport properties of CaMg{sub 2}Bi{sub 2}, EuMg{sub 2}Bi{sub 2}, and YbMg{sub 2}Bi{sub 2} were characterized between 2 and 650 K. As synthesized, the polycrystalline samples are found to have lower p-type carrier concentrations than single-crystalline samples of the same empirical formula. These low carrier concentration samples possess the highest mobilities yet reported for materials with the CaAl{sub 2}Si{sub 2} structure type, with a mobility of {approx}740 cm{sup 2}/V/s observed in EuMg{sub 2}Bi{sub 2} at 50 K. Despite decreases in the Seebeck coefficient ({alpha}) and electrical resistivity ({rho}) with increasing temperature, the power factor ({alpha}{sup 2}{rho}) increases for all temperatures examined. This behavior suggests a strong asymmetry in the conduction of electrons and holes. The highest figure of merit (zT) is observed in YbMg{sub 2}Bi{sub 2}, with zT approaching 0.4 at 600 K for two samples with carrier densities of approximately 2 x 10{sup 18} cm{sup -3} and 8 x 10{sup 18} cm{sup -3} at room temperature. Refinements of neutron powder diffraction data yield similar behavior for the structures of CaMg{sub 2}Bi{sub 2} and YbMg{sub 2}Bi{sub 2}, with smooth lattice expansion and relative expansion in c being {approx}35% larger than relative expansion in a at 973 K. First-principles calculations reveal an increasing band gap as Bi is replaced by Sb and then As, and subsequent Boltzmann transport calculations predict an increase in {alpha} for a given n associated with an increased effective mass as the gap opens. The magnitude and temperature dependence of {alpha} suggests higher zT is likely to be achieved at larger carrier concentrations, roughly an order of magnitude higher than those in the current polycrystalline samples, which is also expected from the detailed calculations.

May, Andrew F [ORNL; McGuire, Michael A [ORNL; Ma, Jie [ORNL; Delaire, Olivier A [ORNL; Huq, Ashfia [ORNL; Singh, David J [ORNL; Cai, Wei [ORNL; Wang, Hsin [ORNL

2012-01-01T23:59:59.000Z

418

Journal of Peasant Studies 37(4), 2010, forthcoming [version that was sent to the journal for production] Franco et al_EU biofuels_JPS_prodn-corr, 21/07/2010 Assumptions in the European Union biofuels policy:  

E-Print Network [OSTI]

The biofuel project is an agro-industrial development and politically contested policy process where governments increasingly become global actors. European Union (EU) biofuels policy rests upon arguments about societal benefits of three main kinds – namely, environmental protection (especially greenhouse gas savings), energy security and rural development, especially in the global South. Each argument involves optimistic assumptions about what the putative benefits mean and how they can be fulfilled. After examining those assumptions, we

unknown authors

419

The transport coefficients in (R1.5Ce0.5)RuSr2Cu2O10-5 (R=Gd,Eu) rutheno-cuprates  

E-Print Network [OSTI]

Page Table 1. The onset of superconductivity and the values for first and second superconducting temperatures, Tc and Tcg superconducting temperatures for Ru-1222(Eu) with different oxygen content..............................................61... Table 2. The onset of superconductivity, the values for first and second superconducting temperatures, Tc and Tcg determined from resistivity data and the superconducting temperatures TcS determined from thermopower data for Ru-1222(Gd) with different...

Anatska, Maryna Petrovna

2007-04-25T23:59:59.000Z

420

High Temperature, Low Relative Humidity, Polymer-type Membranes Based on Disulfonated Poly(arylene ether) Block and Random Copolymers Optionally Incorporating Protonic Conducting Layered Water insoluble Zirconium Fillers  

SciTech Connect (OSTI)

Our research group has been engaged in the past few years in the synthesis of biphenol based partially disulfonated poly(arylene ether sulfone) random copolymers as potential PEMs. This series of polymers are named as BPSH-xx, where BP stands for biphenol, S stands for sulfonated, H stands for acidified and xx represents the degree of disulfonation. All of these sulfonated copolymers phase separate to form nano scale hydrophilic and hydrophobic morphological domains. The hydrophilic phase containing the sulfonic acid moieties causes the copolymer to absorb water. Water confined in hydrophilic pores in concert with the sulfonic acid groups serve the critical function of proton (ion) conduction and water transport in these systems. Both Nafion and BPSH show high proton conductivity at fully hydrated conditions. However proton transport is especially limited at low hydration level for the BPSH random copolymer. It has been observed that the diffusion coefficients of both water and protons change with the water content of the pore. This change in proton and water transport mechanisms with hydration level has been attributed to the solvation of the acid groups and the amount of bound and bulk-like water within a pore. At low hydration levels most of the water is tightly associated with sulfonic groups and has a low diffusion coefficient. This tends to encourage isolated domain morphology. Thus, although there may be significant concentrations of protons, the transport is limited by the discontinuous morphological structure. Hence the challenge lies in how to modify the chemistry of the polymers to obtain significant protonic conductivity at low hydration levels. This may be possible if one can alter the chemical structure to synthesize nanophase separated ion containing block copolymers. Unlike the BPSH copolymers, where the sulfonic acid groups are randomly distributed along the chain, the multiblock copolymers will feature an ordered sequence of hydrophilic and hydrophobic segments. If, like in Nafion, connectivity is established between the hydrophilic domains in these multiblock copolymers, they will not need as much water, and hence will show much better protonic conductivity than the random copolymers (with similar degree of sulfonation, or IEC) at partially hydrated conditions. The goal of this research is to develop a material suitable for use as a polymer electrolyte membrane which by the year 2010 will meet all the performance requirements associated with fuel cell operation at high temperatures and low relative humidity, and will out-perform the present standard Nafion{reg_sign}. In particular, it is our objective to extend our previous research based on the use of thermally, oxidatively, and hydrolytically, ductile, high Tg ion containing polymers based on poly(arylene ethers) to the production of polymer electrolyte membranes which will meet all the performance requirements in addition to having an areal resistance of < 0.05 ohm-cm{sup 2} at a temperature of up to 120 C, relative humidity of 25 to 50%, and up to 2.5 atm total pressure. In many instances, our materials already out performs Nafion{reg_sign}, and it is expected that with some modification by either combining with conductive inorganic fillers and/or synthesizing as a block copolymer it will meet the performance criteria at high temperatures and low relative humidity. A key component in improving the performance of the membranes (and in particular proton conductivity) and meeting the cost requirements of $40/m{sup 2} is our development of a film casting process, which shows promise for generation of void free thin films of uniform thickness with controlled polymer alignment and configuration.

McGrath, James E.; Baird, Donald G.

2010-06-03T23:59:59.000Z

Note: This page contains sample records for the topic "butyl ether eu" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Enhanced luminescence intensity and color purity of the red emitting LnVO{sub 4}:Eu{sup 3+}@ SiO{sub 2} (Ln = Gd, Y and Gd/Y) powder phosphors  

SciTech Connect (OSTI)

Graphical abstract: Display Omitted Highlights: ? Tetragonal phase lanthanide vanadates doped with Eu{sup 3+} were synthesized. ? Luminescence enhancement was done by optimizing the host (Gd,Y) and SiO{sub 2} coatings. ? SiO{sub 2} coating was characterized by SEM-EDAX, FT-IR and PL techniques. ? {sup 5}D{sub 0} ? {sup 7}F{sub 2} domination over {sup 5}D{sub 0} ? {sup 7}F{sub 1} indicates the absence of an inversion symmetry. ? Y{sub 0.95}VO{sub 4}:Eu{sup 3+}@ SiO{sub 2}(10 vol.%) is found to be a novel enhanced red emitting phosphor. -- Abstract: An attempt was made to enhance the luminescence properties of LnVO{sub 4}:Eu{sup 3+}@ SiO{sub 2} (Ln = Gd, Y and Gd/Y) powder phosphors. Pure phase with tetragonal structure of the produced phosphors was confirmed by XRD profiles. Sub-micron sized phosphors have shown 35% more PL intensity than the bulk, which was further improved 20.22% with SiO{sub 2} shell coating. SiO{sub 2} shell coating was optimized by SEM-EDAX, FT-IR, PL and TEM measurements. Emission intensities of the transition, {sup 5}D{sub 0} ? {sup 7}F{sub 2} have dominated {sup 5}D{sub 0} ? {sup 7}F{sub 1}, which indicated the lowering of an inverse symmetry in the vicinity of Eu{sup 3+} ions. Luminescence intensity and color purity were enhanced with the host modification by substituting Gd{sup 3+} with Y{sup 3+} sites, followed by SiO{sub 2} coating. Based on the systematic investigations carried out, the phosphor Y{sub 0.95}VO{sub 4}:Eu{sup 3+}{sub 0.05}@ SiO{sub 2} is suggested to be a novel contender for its suitable red emission in certain displays or lighting.

Rambabu, U. [Centre for Materials for Electronics Technology (C-MET), IDA Phase-III, Cherlapally, Hyderabad 500051 (India)] [Centre for Materials for Electronics Technology (C-MET), IDA Phase-III, Cherlapally, Hyderabad 500051 (India); Han, Sang-Do, E-mail: sdhan@kier.re.kr [Korea Institute of Energy Research (KIER), Daejeon 305-343 (Korea, Republic of)] [Korea Institute of Energy Research (KIER), Daejeon 305-343 (Korea, Republic of)

2013-02-15T23:59:59.000Z

422

Simultaneous Efficiency, NOx, and Smoke Improvements through Diesel/Gasoline Dual-Fuel Operation in a Diesel Engine  

E-Print Network [OSTI]

or liquefied petroleum gas, natural gas, biogas, hydrogen, and alcohols such as methanol, ethanol, iso-propanol, and n-butanol), and fuel additives (MTBE or methyl tertiary-butyl ether, H2O2 or hydrogen peroxide, 2-EHN or ethylhexyl nitrate and DTBP or di...

Sun, Jiafeng

2014-08-05T23:59:59.000Z

423

Drinking Water Problems: MTBE  

E-Print Network [OSTI]

Methyl tertiary-butyl ether, a gasoline additive commonly known as MTBE, can contaminate ground water and cause health problems for those exposed to it for a long time. However, filtering devices can remove this and other additives from well water...

Dozier, Monty; Lesikar, Bruce J.

2008-08-28T23:59:59.000Z

424

Role of Volatilization in Changing TBA and MTBE Concentrations at  

E-Print Network [OSTI]

a low affinity for gasoline (low Kfw, Table 1). Therefore, minute amounts of TBA in the MTBE blended tertiary butyl ether (MTBE) added to gasoline. Frequent observations of high TBA, and especially rising TBA/MTBE concentration ratios, in groundwater at gasoline spill sites are generally attributed to microbial conversion

425

Water Research 37 (2003) 37563766 Seasonal and daily variations in concentrations of methyl-  

E-Print Network [OSTI]

by volume to gasoline from November to February, and blending 11% MTBE by volume during the rest of the year; accepted 24 March 2003 Abstract Methyl-tertiary-butyl ether (MTBE), an additive used to oxygenate gasoline of gasoline-powered watercraft. This paper documents and explains both seasonal and daily variations in MTBE

Toran, Laura

426

Critical Reviews in Environmental Science and Technology, 00(0):000000 (2001) 1064-3389/01/$.50  

E-Print Network [OSTI]

-3389/01/$.50 © 2001 by CRC Press LLC The Transport and Fate of Ethanol and BTEX in Groundwater Contaminated by Gasohol water contamination by methyl tert-butyl ether (MTBE) have made policymakers more cognizant of the need). It has been discovered that MTBE is a ubiquitous contaminant in surface and ground waters throughout

Alvarez, Pedro J.

427

UMass builds bugs to eat MTBE ByAuriaCimino  

E-Print Network [OSTI]

a toxic gasoline component might be just what the doctor ordered for Maine's con- taminated groundwater with methyl tertiary butyl ether (MTBE), which is found in gasoline. Once the first field trial is complete out of the reformulated gasoline pro- gram (RFG) .The gasoline, which con- tains 11 percent MTBE

Lovley, Derek

428

Motor Gasoline Outlook and State MTBE Bans  

Reports and Publications (EIA)

The U.S. is beginning the summer 2003 driving season with lower gasoline inventories and higher prices than last year. Recovery from this tight gasoline market could be made more difficult by impending state bans on the blending of methyl tertiary butyl ether (MTBE) into gasoline that are scheduled to begin later this year.

2003-01-01T23:59:59.000Z

429

Water Research Institute Annual Technical Report  

E-Print Network [OSTI]

Air Act mandated oxygenated gasoline containing methyl tert-butyl ether (MtBE) in certain areas percent. The State of Maine elected to use reformulated gasoline (RFG) that contained at least 11 percent and by 1995, oxygenated gasoline use was common in the northeast. Soon after the widespread use of gasoline

430

Mechanisms of gas permeation through polymer membranes. Progress report, July 1, 1985-May 31, 1986. [CH/sub 4/, C/sub 2/H/sub 6/, n-C/sub 4/H/sub 10/, CO/sub 2/ in poly(n-butyl methacrylate)  

SciTech Connect (OSTI)

The work described is concerned with the significant changes in these mechanisms in the glass-transition range. Permeability, diffusion, and solubility coefficients for CH/sub 4/, C/sub 2/H/sub 4/, C/sub 2/H/sub 6/, and n-C/sub 4/H/sub 10/ in poly(n-butyl methacrylate) (PnBMA) were determined at pressures up to 25 atm and from -14/sup 0/ to 50/sup 0/C. Solubility was also determined for CO/sub 2/ in PnBMA at pressures up to 25 atm and at -10/sup 0/ and 30/sup 0/C. No significant changes were observed in the pressure (or concentration) and temperature dependence of the permeability, diffusion, and solubility coefficients for CH/sub 4/, C/sub 2/H/sub 6/, and n-C/sub 4/H/sub 10/ in the glass-transition range of PnBMA, or when the temperature was lowered below T/sub g/. Moreover, these gas/polymer systems do not exhibit below T/sub g/ the usual ''dual-mode'' sorption behavior of gases in glassy polymers. The solubility isotherm for CO/sub 2/ in PnBMA at -10/sup 0/C and lower pressures suggests incipient dual-mode sorption. Results are exceptions to dual-mode sorption behavior and may be due to small difference in the coefficients of thermal expansion of PnBMA above and below T/sub g/. This indicates that the unrelaxed domains in glassy PnBMA are very small. A ''free-volume'' mechanism describes the dependence of C/sub 2/H/sub 6/ permeability on P, T both above and below the glass transition of PnBMA. Adsorption/desorption kinetics are Fickian.

Stern, S.A.; Vakil, U.; Zhou, S.

1986-05-01T23:59:59.000Z

431

Table Definitions, Sources, and Explanatory Notes  

Gasoline and Diesel Fuel Update (EIA)

Ethanol Plant Production Ethanol Plant Production Definitions Key Terms Definition Barrel A unit of volume equal to 42 U.S. gallons. Fuel Ethanol An anhydrous alcohol (ethanol with less than 1% water) intended for gasoline blending as described in the Oxygenates definition. Oxygenates Substances which, when added to gasoline, increase the amount of oxygen in that gasoline blend. Ethanol, Methyl Tertiary Butyl Ether (MTBE), Ethyl Tertiary Butyl Ether (ETBE), and methanol are common oxygenates. Fuel Ethanol: Blends of up to 10 percent by volume anhydrous ethanol (200 proof) (commonly referred to as the "gasohol waiver"). Methanol: Blends of methanol and gasoline-grade tertiary butyl alcohol (GTBA) such that the total oxygen content does not exceed 3.5 percent by weight and the ratio of methanol to GTBA is less than or equal to 1. It is also specified that this blended fuel must meet ASTM volatility specifications (commonly referred to as the "ARCO" waiver).

432

Evidence of a Precursor Superconducting Phase at Temperatures as High as 180 K in RBa2Cu3O7-????(R=Y,Gd,Eu) Superconducting Crystals from Infrared Spectroscopy  

Science Journals Connector (OSTI)

We show that a multilayer analysis of the infrared c-axis response of RBa2Cu3O7-????(R=Y,Gd,Eu) provides important new information about the anomalous normal-state properties of underdoped cuprate high temperature superconductors. In addition to competing correlations which give rise to a pseudogap that depletes the low-energy electronic states below T*?Tc, it enables us to identify the onset of a precursor superconducting state below Tons>Tc. We map out the doping phase diagram of Tons which reaches a maximum of 180 K at strong underdoping and present magnetic field dependent data which confirm our conclusions.

A. Dubroka, M. Rössle, K. W. Kim, V. K. Malik, D. Munzar, D. N. Basov, A. A. Schafgans, S. J. Moon, C. T. Lin, D. Haug, V. Hinkov, B. Keimer, Th. Wolf, J. G. Storey, J. L. Tallon, and C. Bernhard

2011-01-27T23:59:59.000Z

433

Implementing the EU Renewables Directive  

E-Print Network [OSTI]

on technol o g y choice , priv ate sector actors would focus on the least-c o s t renewab l e energy technol o g i e s , curre n t l y on-sh o r e wind, bioma s s and biogas from sewage and landfill s . Cost of other renewable energy technologies, howeve r... to th e need for an additional 800km of transmis s i o n lines within Germany by 2015 (DENA 2005). Withou t guidan c e on the timing of invest me n t s in specific technologi e s , it is difficu l t for the technol o g y suppl y chain to inves...

Neuhoff, Karsten

434

The effect of temperature induced phase transitions in aqueous solutions of triblock copolymers and Triton X-100 on the EPR, magnetic relaxation and luminescent characteristics of Gd(III) and Eu(III) ions  

Science Journals Connector (OSTI)

The present report is inspired by the idea to develop novel spectroscopy based techniques to detect the phase transitions in solutions of triblock copolymers with the use of Gd(III) and Eu(III) ions as probes. The choice of (PEO)13(PPO)30(PEO)13 (L64), (PPO)14(PEO)24(PPO)14 (17R4), (PPO)8(PEO)22(PPO)8 (10R5) and Triton X-100 is conditioned by their phase transitions occurring in mild conditions. The cloud point extraction (CPE) data reveal the conditions (pH and chelating agent) where the binding of lanthanides with surfactant rich phase of triblock copolymers and Triton X-100 occurs. The effect of phase transitions in solutions of triblock copolymers on the temperature resolved line widths in EPR spectra of Gd(III) aqua ions and transverse relaxation rates of Gd(III) inner-sphere water protons depends on the architecture of triblock copolymers and pH conditions. The steady state luminescence of Eu(III) complexes with phosphine oxide in aqueous solutions of triblock copolymers and TX-100 is influenced by the temperature induced aggregation and phase separation in solutions of reverse triblock copolymers 17R4 and 10R5, while the effect of the aggregation is insignificant for L64.

Julia Elistratova; Asiya Mustafina; Alexey Litvinov; Vladimir Burilov; Antonina Khisametdinova; Vladimir Morozov; Rustem Amirov; Yevgeniya Burilova; Dmitry Tatarinov; Marsil Kadirov; Vladimir Mironov; Alexander Konovalov

2013-01-01T23:59:59.000Z

435

Characterization of photoluminescent (Y{sub 1{minus}x}Eu{sub x}){sub 2}O{sub 3} thin-films prepared by metallorganic chemical vapor deposition  

SciTech Connect (OSTI)

Europium doped yttrium oxide, (Y{sub 1{minus}x}Eu{sub x}){sub 2}O{sub 3}, thin-films were deposited on silicon and sapphire substrates by metallorganic chemical vapor deposition (MOCVD). The films were grown in a MOCVD chamber reacting yttrium and europium tris(2,2,6,6-tetramethyl-3,5,-heptanedionates) precursors in an oxygen atmosphere at low pressures (5 Torr) and low substrate temperatures (500--700 C). The films deposited at 500 C were flat and composed of nanocrystalline regions of cubic Y{sub 2}O{sub 3}, grown in a textured [100] or [110] orientation to the substrate surface. Films deposited at 600 C developed from the flat, nanocrystalline morphology into a plate-like growth morphology oriented in the [111] with increasing deposition time. Monoclinic Y{sub 2}O{sub 3}:Eu{sup 3+} was observed in x-ray diffraction for deposition temperatures {ge}600 C on both (111) Si and (001) sapphire substrates. This was also confirmed by the photoluminescent emission spectra.

McKittrick, J.; Bacalski, C.F.; Hirata, G.A. [Univ. of California, San Diego, La Jolla, CA (United States); Hubbard, K.M.; Pattillo, S.G.; Salazar, K.V.; Trkula, M. [Los Alamos National Lab., NM (United States). Materials Science and Technology Div.

1998-12-01T23:59:59.000Z

436

Synthesis and characterization of hybrid materials based on 1-butyl-3-methylimidazolium tetrafluoroborate ionic liquid and Dawson-type tungstophosphate K{sub 7}[H{sub 4}PW{sub 18}O{sub 62}].18H{sub 2}O and K{sub 6}[P{sub 2}W{sub 18}O{sub 62}].13H{sub 2}O  

SciTech Connect (OSTI)

In this study, we synthesized hybrid materials using well-Dawson polyoxometalates (POMs), K{sub 7}[H{sub 4}PW{sub 18}O{sub 62}].18H{sub 2}O or K{sub 6}[P{sub 2}W{sub 18}O{sub 62}].13H{sub 2}O and a room temperature ionic liquid 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIM][BF{sub 4}]). K, W, P and CHN elemental analysis showed that one mole of [H{sub 4}PW{sub 18}O{sub 62}]{sup 7-} reacts with 6 moles of BMIM{sup +} and one mole of [P{sub 2}W{sub 18}O{sub 62}]{sup 6-} reacts with 4 moles of BMIM{sup +} to form, respectively, K[BMIM]{sub 6}H{sub 4}PW{sub 18}O{sub 62} and K{sub 2}[BMIM]{sub 4}P{sub 2}W{sub 18}O{sub 62}. X-ray diffraction illustrated amorphous structure of the hybrid materials. FT-IR spectra showed the presence of both 1-butyl-3-methylimidazolium cation and the Dawson anion. TG analysis displayed a relative thermal stability of the hybrid materials compared to the parents Dawson POMs. Cyclic voltammetry showed that the reduction peak potentials of the Dawson anion in the hybrid materials shift towards negative values and the shift is more pronounced for K[BMIM]{sub 6}H{sub 4}PW{sub 18}O{sub 62} compared to K{sub 2}[BMIM]{sub 4}P{sub 2}W{sub 18}O{sub 62}. This was attributed to a decrease in the acidity of the Dawson POM anion in the hybrid material. -- Graphical abstract: Powder XRD patterns of (a) PW{sub 18}, (b) K[BMIM]{sub 6}H{sub 4}PW{sub 18}O{sub 62}, (c) P{sub 2}W{sub 18}, and (d) K{sub 2}[BMIM]{sub 4}P{sub 2}W{sub 18}O{sub 62}. Display Omitted Research highlights: {yields} 1-butyl-3-methylimidazolium tetrafluoroborate([BMIM][BF{sub 4}]) reacts with K{sub 7}[H{sub 4}PW{sub 18}O{sub 62}].18H{sub 2}O to form K[BMIM]{sub 6}H{sub 4}PW{sub 18}O{sub 62}. {yields} [BMIM][BF{sub 4}] reacts with K{sub 6}[P{sub 2}W{sub 18}O{sub 62}].13H{sub 2}O to form K{sub 2}[BMIM]{sub 4}P{sub 2}W{sub 18}O{sub 62}. {yields} K[BMIM]{sub 6}H{sub 4}PW{sub 18}O{sub 62} and K{sub 2}[BMIM]{sub 4}P{sub 2}W{sub 18}O{sub 62} displayed amorphous structures. {yields} K[BMIM]{sub 6}H{sub 4}PW{sub 18}O{sub 62} and K{sub 2}[BMIM]{sub 4}P{sub 2}W{sub 18}O{sub 62} illustrated low water content. {yields} K[BMIM]{sub 6}H{sub 4}PW{sub 18}O{sub 62} and K{sub 2}[BMIM]{sub 4}P{sub 2}W{sub 18}O{sub 62} showed improved thermal stability.

Ammam, Malika, E-mail: m78ammam@yahoo.f [Department of Metallurgy and Materials Engineering (MTM), K.U Leuven, Kasteelpark Arenberg 44, B-3001 Heverlee (Belgium); Fransaer, Jan [Department of Metallurgy and Materials Engineering (MTM), K.U Leuven, Kasteelpark Arenberg 44, B-3001 Heverlee (Belgium)

2011-04-15T23:59:59.000Z

437

Reactivity of the Quinone Methide of Butylated hydroxytoluene in Solution  

E-Print Network [OSTI]

BHT is a common antioxidant in pharmaceutical formulations and when oxidized it forms a quinone methide (QM). QM is a highly reactive electrophilic species which can undergo nucleophilic addition. This research investigated ...

Willcockson, Maren Gulsrud

2011-08-31T23:59:59.000Z

438

Effect of annealing on the kinetic properties and band parameters of Hg{sub 1?x?y}Cd{sub x}Eu{sub y}Se semiconductor crystals  

SciTech Connect (OSTI)

The results of studies of the kinetic properties of Hg{sub 1?x?y}Cd{sub x}Eu{sub y}Se semiconductor crystals in the ranges of temperatures T = 77–300 K and magnetic fields H = 0.5–5 kOe before and after heat treatment of the samples in Se vapors are reported. It is established that annealing of the samples in Se vapors induces a decrease in the electron concentration. From the concentration dependence of the electron effective mass at the Fermi level, the band gap, the matrix element of interband interaction, and the electron effective mass at the bottom of the conduction band are determined.

Kovalyuk, T. T., E-mail: tarik-1006@mail.ru; Maistruk, E. V.; Maryanchuk, P. D. [Chernivtsy National University (Ukraine)

2014-12-15T23:59:59.000Z

439

Ozone-forming potential of a series of oxygenated organic compounds  

SciTech Connect (OSTI)

An incremental reactivity approach has been used to assess the relative ozone-forming potentials of various important oxygenated fuels/fuel additives, i.e., tert-butyl alcohol (TBA), dimethyl ether (DME), diethyl ether (DEE), methyl tert-butyl ether (MTBE), and ethyl tert-butyl ether (ETBE), in a variety of environments. Calculations were performed using a single-cell trajectory model, combined with the Lurmann-Carter-Coyner chemical mechanism, with (NMOC)/(NO{sub x}) ratios ranging from 4 to 20. This work provides the first quantitative assessment of the air quality impact of release of these important oxygenated compounds. ETBE and DEE are the two most reactive compounds on a per carbon equivalent basis, while TBA is the least reactive species. At a (NMOC)/(NO{sub x}) ratio of 8, which is generally typical of polluted urban areas in the United States, TBA, DME, MTBE, and ETBE all have incremental reactivities less than or equal to that of the urban NMHC mix. Thus, use of these additives in fuels may have a beneficial impact on urban ozone levels.

Japar, S.M.; Wallington, T.J.; Rudy, S.J.; Chang, Tai Y. (Ford Motor Company, Dearborn, MI (USA))

1991-03-01T23:59:59.000Z

440

Structure of high pressure Ca(OD){sub 2} II from powder neutron diffraction: Relationship to the ZrO{sub 2} and EuI{sub 2} structures  

SciTech Connect (OSTI)

The {open_quotes}unquenchable{close_quotes} high pressure form of Ca(OD){sub 2} [Ca(OH){sub 2}II] has been synthesized at 9 GPa and 400{degrees}C and recovered to ambient pressure at cryogenic temperatures. The structure was determined from powder neutron diffraction data using the Rietveld technique. The symmetry is monoclinic P2{sub 1}/c with a = 5.3979(4) {angstrom}, b = 6.0931(4) {angstrom}, c = 5.9852(4) {angstrom}, {beta} = 103.581(6), Z = 4 at 1 atm and 11 K. R{sub wp} = 2.8%, R{sub p} = 1.9%, reduced {chi}{sup 2} = 6.6. for 117 variables. The calcium and oxygen substructure is intermediate between that in {alpha}-PbO{sub 2} and that in fluorite; it was previously described as isostructural with baddeleyite (ZrO{sub 2}), but it is more accurately described as isostructural with EuI{sub 2}. This structure is distinguished by the presence of a 3{sup 6} anion met parallel to (100). Only one of the two kinds of D atoms in the structure shows appreciable hydrogen bonding to O, with a second neighbor D...O distance of 1.91 {angstrom}, and an O-D...O angle of 153.2{degrees}; the other D atom has 3 second-neighbor oxygens near 2.6 {angstrom} away.

Leinenweber, K.; Partin, D.E.; Schuelke, U. [Arziona State Univ., Tempe, AZ (United States)] [and others] [Arziona State Univ., Tempe, AZ (United States); and others

1997-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "butyl ether eu" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Synthesis, structural characterization and Mössbauer study of LnV{sub 0.5}Fe{sub 0.5}O{sub 3} perovskites (Ln = Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho and Er)  

SciTech Connect (OSTI)

Graphical abstract: Mössbauer spectra taken at 200 K for the Y(V{sub 0.5}Fe{sub 0.5})O{sub 3} orthoferrivanadate synthesized by arc-melting. Highlights: ? LnFe{sub 0.5}V{sub 0.5}O{sub 3} were synthesized by the first time for most of the rare-earth elements. ? These orthoferrivanadates crystallize metastably with the perovskite structure. ? Iron and vanadium are trivalent stabilized in these solid solutions. ? The Mössbauer quadrupolar splitting is correlated with the tolerance factor. ? Below 100 K, these perovskites undergo a crystallographic phase transformation. -- Abstract: Perovskites LnV{sub 0.5}Fe{sub 0.5}O{sub 3} (Ln = Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho and Er) were synthesized by rapid solidification from arc-melted samples and characterized by the study of their crystal structure and hyperfine properties. These metastable solid solutions crystallized in the Pbnm symmetry, with the iron and vanadium cations randomly distributed in the transition metal octahedral sites. Depending on the lanthanide present at the A site of the perovskite, iron is present with two valences (i.e., Fe{sup 3+} and Fe{sup 2+}). The volume of the unit cell for these perovskites increases linearly with the lanthanide ionic radius, as the perovskite approaches its ideal structure. At room temperature, the quadrupolar splitting of the trivalent paramagnetic Mössbauer component works as an indirect measurement for the Goldshmidt tolerance factor. Close to or below 100 K, these perovskites undergo a crystallographic phase transformation, probably due to orbital ordering of the V{sup 3+} cations, originating two different magnetic iron sites.

Ivashita, Flávio F.; Biondo, Valdecir; Bellini, Jusmar V.; Paesano, Andrea [Departamento de Física, Universidade Estadual de Maringá, Av. Colombo 5790, 87.020-900 Maringá, PR (Brazil)] [Departamento de Física, Universidade Estadual de Maringá, Av. Colombo 5790, 87.020-900 Maringá, PR (Brazil); Blanco, M. Cecilia; Fuertes, Valeria C.; Pannunzio-Miner, Elisa V. [INFIQC-CONICET, Departamento de Fisicoquímica, Facultad de Ciencias Químicas, Universidad Nacional de Córdoba, X5000HUA Córdoba (Argentina)] [INFIQC-CONICET, Departamento de Fisicoquímica, Facultad de Ciencias Químicas, Universidad Nacional de Córdoba, X5000HUA Córdoba (Argentina); Carbonio, Raúl E., E-mail: carbonio@fcq.unc.edu.ar [INFIQC-CONICET, Departamento de Fisicoquímica, Facultad de Ciencias Químicas, Universidad Nacional de Córdoba, X5000HUA Córdoba (Argentina)

2012-09-15T23:59:59.000Z

442

Sorption of vapours and liquids in PDMS: novel data and analysis with the GAB model of multilayer adsorption  

Science Journals Connector (OSTI)

Abstract Novel data on the sorption of vapours and liquids in cross-linked poly(dimethylsiloxane) (PDMS) elastomer at 25–40 °C are reported together with the accurate and original way of parameterising the sorption isotherms by using the GAB (Guggenheim, Anderson and De Boer) model of multilayer adsorption. The GAB model has been found to provide a comparable or better representation of sorption isotherms than the Flory–Huggins model with a concentration-dependent interaction parameter and better than the ENSIC (Engaged Species Induced Clustering) model. This comparison holds true for poor solvents of PDMS (water, methanol), mild solvents (acetone, methyl acetate, dimethyl carbonate) and good solvents (tert-butyl methyl ether, tert-amyl methyl ether, cyclopentyl methyl ether). The GAB model provided a noticeably good assessment of the sorption of liquids and highly saturated vapours, which makes the model applicable within the entire activity range.

Ond?ej Vopi?ka; Alena Randová; Karel Friess

2014-01-01T23:59:59.000Z

443

P-SimonUS_EU-DOE  

Broader source: Energy.gov (indexed) [DOE]

Electrochemical Capacitors for Power Grid Storage Electrochemical Capacitors for Power Grid Storage technology: State of the art and next challenges" Trans-Atlantic Workshop on Storage Technologies for Power Grids Washington, October 19th-20th 2010 Trans-Atlantic Workshop on Storage technologies for Power Grids, October 19th-20th State of the art and next challenges" Patrice Simon Univ. Paul Sabatier, CIRIMAT, UMR 5085, Toulouse - FRANCE simon@chimie.ups-tlse.fr Electrochemical Capacitors performance between capacitors and batteries Electrochemical Capacitors: - high power (10-20 kW/kg) - medium energy density (5 Wh/kg) - time constant about 1 - 5 s Trans-Atlantic Workshop on Storage technologies for Power Grids, October 19th-20th Electrochemical Double Layer Capacitors (EDLCs) 95% of the commercialized cells high surface area carbons as active materials

444

Die Ukraine zwischen EU und Russländischer Föderation.  

E-Print Network [OSTI]

??In dieser Arbeit wird ein Überblick über die Demokratisierungsprozesse in der Ukraine mit einem besonderen Augenmerk auf den Zeitraum vom Ende der Kutschma-Präsidentschaft bis Dezember… (more)

Sarapkina, Nataliya

2014-01-01T23:59:59.000Z

445

De-Carbonizing California and the EU  

E-Print Network [OSTI]

environmental protection agency Sector specific instruments Energy and housing sector Green certificates Subsidy to windpower

Berck, Peter; Brannlund, Runar

2008-01-01T23:59:59.000Z

446

EU Energy Situations and Supply Security.  

E-Print Network [OSTI]

?? Energy supply security is a hot topic today. It highly influences energy market, national security and also residents’ daily lives. However, due to different… (more)

Xu, Chen

2008-01-01T23:59:59.000Z

447

EU agricultural reform fails on biodiversity  

Science Journals Connector (OSTI)

...growing a minimum of three different crops...cultivate at least two or three crops, respectively...table S4). Cultivating three crops on large, intensively...Development Regulation (Pillar 2), especially agri-environment-climate...improve agricultural sustainability. Yet the increased devolution...

G. Pe'er; L. V. Dicks; P. Visconti; R. Arlettaz; A. Báldi; T. G. Benton; S. Collins; M. Dieterich; R. D. Gregory; F. Hartig; K. Henle; P. R. Hobson; D. Kleijn; R. K. Neumann; T. Robijns; J. Schmidt; A. Shwartz; W. J. Sutherland; A. Turbé; F. Wulf; A. V. Scott

2014-06-06T23:59:59.000Z

448

Energy Market Regulation: Impacts of EU Research  

Science Journals Connector (OSTI)

European decisions in general, and in the energy field in particular, are often scientifically supported. Already before the formal “impact assessment”, which has to accompany all the major policy initiatives ...

Domenico Rossetti di Valdalbero

2005-01-01T23:59:59.000Z

449

Pesticide Regulation in the EU and California  

E-Print Network [OSTI]

coming from food (food poisoning was the most frequentlyfood and feed, the evaluation of the reporting of pesticide poisoning

Ansell, Chris

2008-01-01T23:59:59.000Z

450

The Value of the EU Public Domain  

E-Print Network [OSTI]

is as natural and necessary part of our research efforts as the study of copyright.1 1 Mead Fellow in Economics, Emmanuel College, University of Cambridge 2 Erasmus University Rotterdam and Austrian Society for Cultural Economics and Policy Studies 3 Adjunct... proximate but already public domain works. 30We can add and remove mass because the set of in-print public domain and in copyright books do not necessarily match. 31If one considers this over-generous it is worth considering that the various different Harry...

Pollock, Rufus; Stepan, Paul; Välimäki, Mikko

451

Marketing New Zealand lamb in the EU  

Science Journals Connector (OSTI)

This study replicates work published in 2002, exploring the use of country of origin images in the international marketing of six of New Zealand's primary industry products by agribusinesses. Specifically, this study examines and analyses the use of country of origin in the marketing strategies used by Meat & Wool New Zealand to market New Zealand lamb. Findings from the present study were well aligned with those of the 2002 study by Beaverland and Lindgreen. In particular, the New Zealand lamb-marketing scenario supported the heavy use of country of origin images by specialist marketing boards for niche products. Further, in support of past findings, the use of country of origin was a means of differentiating the product from others in the host market. History was also found to be a contributing factor to how lamb was marketed, though played an indirect role in shaping the attributes of the product that were accentuated by the use of country of origin marketing.

Phillip R. Clark; Teresa E. Dana

2007-01-01T23:59:59.000Z

452

Liquefied Dimethyl Ether: An Energy-Saving, Green Extraction Solvent  

Science Journals Connector (OSTI)

Extraction is an essential procedure in the fields of food, pharmacy, and renewable bio-fuels, and it affords the recovery of desired components and the removal of undesired components from the natural feedstock....

Peng Li; Hisao Makino

2014-01-01T23:59:59.000Z

453

Alternative Fuels lDimethyl Ether Rheology and Materials Studies  

Broader source: Energy.gov [DOE]

2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: The Pennsylvania State University

454

Alternative Fuels Data Center: Dimethyl Ether (DME): Fuel of...  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

The AFDC is a resource of the U.S. Department of Energy's Clean Cities program. Contacts | Web Site Policies | U.S. Department of Energy | USA.gov Content Last Updated: 01022015...

455

Alternative Fuels Data Center: Dimethyl Ether (DME) as a Transportatio...  

Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

similar to that of propane, in that both are required to be kept in pressurized storage tanks at ambient temperature. DME has several fuel properties that make it attractive for...

456

Surface Modification of Silicone Elastomer Using Perfluorinated Ether  

E-Print Network [OSTI]

of a silicone-coated substrate.29 In addition, higher molecular weight perfluoropolyethers have been included

Chaudhury, Manoj K.

457

Polybrominated Diphenyl Ether Flame Retardants in Virginia Freshwater Fishes (USA)  

Science Journals Connector (OSTI)

Robert C. Hale ,* Mark J. La Guardia , Ellen P. Harvey , T. Matteson Mainor , William H. Duff , and Michael O. Gaylor ... Following solvent exchange to hexane, the halogenated compounds in the purified extracts were separated on a gas chromatograph (GC; Varian 3400, Sugar Land, TX), equipped with a 60-m DB-5 column (J&W Scientific, Folsom, CA; 0.25 ?m film, 0.32 i.d.). ...

Robert C. Hale; Mark J. La Guardia; Ellen P. Harvey; T. Matteson Mainor; William H. Duff; Michael O. Gaylor

2001-10-30T23:59:59.000Z

458

The Ether Extract and the Chloroform Extract of Soils.  

E-Print Network [OSTI]

KNJJUG................................................................................................................Mailing Clerk STATE AGRICULTURAL EXPERIMENT STATIONS. H U M T 9 L 3L H G U . 9 Z R 11 3J X C I T P P T L I 0 Y uUM T 9 L U 9 0. B. A U P s S 3 D D ...................................................... Austin t 3 T S D T L . L D 1u U M T 9 L U 9 i 3 P P... n R r . 0 T J ......................................................Brownwood A U O O 3J J 3U L T 9 U o V H 9 3 I S P D S 9 T X Z w R dU L T ...................................................... Austin DIRECTOR OF EXPERIMENT STATIONS. B. l U...

Fraps, G. S.; Rather, J. B.

1913-01-01T23:59:59.000Z

459

Quantum-Gravity Phenomenology and the DSR Ether Theories  

E-Print Network [OSTI]

Guided primarily by versions of a theoretical framework called Doubly Special Relativity, or DSR, that are supposed to entail speeds of light that vary with energy while preserving the relativity of inertial frames, quantum-gravity phenomenologists have recently been seeking clues to quantum gravity, in hoped-for differing times of arrival, for light of differing energies, from cosmologically distant sources. However, it has long been known that signals, of arbitrarily high speed in opposing directions, could be used to observe the translational state of (absolute) rest, as could signals of a fixed speed different from c. Consequently, the above versions of DSR are nonviable.

Kenneth M. Sasaki

2010-09-20T23:59:59.000Z

460

Synthesis of Methanol and Dimethyl Ether from Syngas over Pd...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

are necessary when combining methanol and DME synthesis with a methanol to gasoline (MTG) process in a single reactor bed. A commercial CuZnOAl2O3 catalyst, utilized...

Note: This page contains sample records for the topic "butyl ether eu" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Extractant composition including crown ether and calixarene extractants  

DOE Patents [OSTI]

An extractant composition comprising a mixed extractant solvent consisting of calix[4] arene-bis-(tert-octylbenzo)-crown-6 ("BOBCalixC6"), 4',4',(5')-di-(t-butyldicyclo-hexano)-18-crown-6 ("DtBu18C6"), and at least one modifier dissolved in a diluent. The DtBu18C6 may be present at from approximately 0.01M to approximately 0.4M, such as at from approximately 0.086 M to approximately 0.108 M. The modifier may be 1-(2,2,3,3-tetrafluoropropoxy)-3-(4-sec-butylphenoxy)-2-propanol ("Cs-7SB") and may be present at from approximately 0.01M to approximately 0.8M. In one embodiment, the mixed extractant solvent includes approximately 0.15M DtBu18C6, approximately 0.007M BOBCalixC6, and approximately 0.75M Cs-7SB modifier dissolved in an isoparaffinic hydrocarbon diluent. The extractant composition further comprises an aqueous phase. The mixed extractant solvent may be used to remove cesium and strontium from the aqueous phase.

Meikrantz, David H. (Idaho Falls, ID); Todd, Terry A. (Aberdeen, ID); Riddle, Catherine L. (Idaho Falls, ID); Law, Jack D. (Pocalello, ID); Peterman, Dean R. (Idaho Falls, ID); Mincher, Bruce J. (Idaho Falls, ID); McGrath, Christopher A. (Blackfoot, ID); Baker, John D. (Blackfoot, ID)

2009-04-28T23:59:59.000Z

462

Polybrominated Diphenyl Ethers in the Sediments of the Great Lakes.  

E-Print Network [OSTI]

source of many pollutants, including PCBs and dioxins, to the Great Lakes. This has been particularly analysis demonstrated that the pattern of PBDEs in Lake Superior sediments differs from those in air from the point sources. Sediments are an important sink and reservoir of per- sistent pollutants

Rockne, Karl J.

463

Network Structure of Cellulose Ethers Used in Pharmaceutical Applications  

E-Print Network [OSTI]

, have studied these two processes (1,3­6). Significant models have been proposed by Peppas molecules dissolve in water and are released by diffusion. The processes of swelling, ero- sion, and drug mathematical models that include all interrelated parameters and that fit accurately the experimental results

Peppas, Nicholas A.

464

European-Scale Modeling of Concentrations and Distribution of Polybrominated Diphenyl Ethers in the Pentabromodiphenyl Ether Product  

Science Journals Connector (OSTI)

Department of Environmental Science, Institute of Environmental and Natural Sciences, Lancaster University, Lancaster LA1 4 YQ, United Kingdom ... Limited survey data in the Mediterranean (Cyprus) were surprisingly high (20); it was assumed that the advection into Europe from the south was probably lower, but this assumption needs to be tested by future field data. ... VP-derived EFs should be suited to solid?gas-phase releases (13) and may therefore describe outgassing of the lighter components of PeBDE under ambient temperatures from solid matrixes where they have been used as additives. ...

K. Prevedouros; K. C. Jones; A. J. Sweetman

2004-10-09T23:59:59.000Z

465

Internet: http://ue.eu.int E-mail: press.office@consilium.eu.int  

E-Print Network [OSTI]

-Minister-President and Minister for Economic Affairs, SMEs, Research and New Technologies (Walloon Region) Denmark : Mr Helge SANDER Minister for Science, Technology and Development Germany : Mr Wolf-Michael CATENHUSEN State COSTA CLIMENT Minister for Science and Technology Mr. Pedro MORENES EULATE State Secretary for Science

466

Anomalous Eu Valence State and Superconductivity in Undoped Eu3Bi2S4F4  

Science Journals Connector (OSTI)

We were not able to test the Meissner effect by dc magnetic susceptibility measurement due to the limit of the lowest temperature achieved. ...

Hui-Fei Zhai; Pan Zhang; Si-Qi Wu; Chao-Yang He; Zhang-Tu Tang; Hao Jiang; Yun-Lei Sun; Jin-Ke Bao; Israel Nowik; Israel Felner; Yue-Wu Zeng; Yu-Ke Li; Xiao-Feng Xu; Qian Tao; Zhu-An Xu; Guang-Han Cao

2014-10-14T23:59:59.000Z

467

Upconversion luminescence of Eu3+ and Mn2+ in ZnS:Mn2+, Eu3+...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

W Chen AG Joly JO Malm JO Bovin Capabilities: Spectroscopy and Diffraction NMR and EPR Facility: Radiochemistry Annex Science Theme: Energy Materials & Processes Terrestrial...

468

Publications  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

7 results: 7 results: BibTex RIS RTF XML Sort by: Author Title Type [ Year (Desc) ] Filters: Author is Elton J. Cairns [Clear All Filters] 2008 Shin, Joon Ho, Pratyay Basak, John B. Kerr, and Elton J. Cairns. "Rechargeable Li/LiFePO4 Cells Using N-Methyl-N-butyl pyrrolidinium Bis(trifluoromethane sulfonyl)imide-LiTFSI Electrolyte Incorporating Polymer Additives." Electrochimica Acta 54, no. 2 (2008): 410-414. Shin, Joon Ho, and Elton J. Cairns. "N-Methyl-(n-butyl)pyrrolidinium bis(trifluoromethanesulfonyl)imide-LiTFSI-poly(ethylene glycol) dimethyl ether mixture as a Li/S cell electrolyte." Journal of Power Sources 177 (2008): 537-545. 2007 Nakahara, Kentaro, Jiro Iriyama, Shigeyuki Iwasa, Masahiro Suguro, Masaharu Satoh, and Elton J. Cairns. "Al-laminated film packaged organic radical

469

Solubility of Solid tert-Butyl Mercaptan in Liquid Methane and an LNG Mixture  

Science Journals Connector (OSTI)

Knowledge of the solubility limit of heavy hydrocarbons in liquid methane is of practical interest in the liquefaction of natural gas. Data for several binary systems were given in previous publications [1,2].The...

G. P. Kuebler; C. McKinley

1980-01-01T23:59:59.000Z

470

The K-band microwave spectra of t-butyl halides  

E-Print Network [OSTI]

1954 Major Subjeet: Chemistry ACKNOWLEDGMENT The author wishes to express his appreciation to Dr. Fred W. Jensen for his help and encouragement during the oourse of this investigation. To the author's wife, Helen Louise, goes the credit for most...) as 100%. 10 Transition nvun.be r assignments and frequencies of the unperturbed rotational lines aa given abova ware calculated by Methods described in the following seotion. 11 DISCUSSION 12 The fundamental process of energy absorption...

Crook, George Hardy

2013-10-04T23:59:59.000Z

471

E-Print Network 3.0 - aluminum triso-ethylphosphonate butylate...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Resistance Advancements: Dr. Dragan CurcijaDr. Dragan Curcija Summary: -Expanded (EPS) Pine or Douglas Fir Frame Cavity Polyfoam tape Urethane Sealant Silicone...

472

THERMODYNAMICS OF EXTRACTION OF NITRIC ACID BY TRI-n-BUTYL PHOSPHATE--HYDROCARBON DILUENT SOLUTIONS  

E-Print Network [OSTI]

the mean act ivi ty coefficient T of TBP and TBP.H20 i n the acid-free, water-saturated organic phase

Wallace Davis

1961-01-01T23:59:59.000Z

473

Safe conditions for contacting nitric acid or nitrates with tri-n-butyl phosphate (TBP)  

SciTech Connect (OSTI)

In response to a request from DOE-SR, the current state of knowledge of the reactions between TBP and aqueous nitrate solutions is critically reviewed, and recommendations are made for the safe operation of SRS separations equipment in which this combination of chemicals may be present. The existing limits for evaporation are validated. Guidelines are presented for cases in which general limits do not apply. The rate of reaction between nitric acid and TBP appears to be controlled by the rate of TBP hydrolysis. The hydrolysis reaction produces dibutyl phosphate and n-butanol. The hydrolysis rate is a strong function of temperature, and becomes very fast at temperatures in the range 130{degrees} to 150{degrees}C. The resulting n-butanol is volatile at high temperatures, boiling at 117.5{degrees}C, but is also subject to exothermic oxidation by nitric acid or nitrates. If oxidation occurs before the n-butanol evaporates, the heat of oxidation may exceed local cooling by convection. The resulting heating will further accelerate the reaction, leading to an energetic runaway and possibly (in confined systems) an explosion. Extensive experiments and practice have shown that in a well-mixed and well-vented aqueous system such as an evaporator, at moderate acidities and temperatures below 130{degrees}C, the heat of reaction is adequately removed by vaporization of steam. In general, the heating will be so slow that natural processes provide adequate cooling at temperatures below 80{degrees}C. Above this temperature, care should be taken to ensure that adequate cooling is available for the amount of TBP that may be present. Experiments suggest that in well-ventilated systems n-butanol evaporation and convective cooling are sufficient to control the reaction at temperatures up to 120{degrees}C.

Hyder, M.L

1994-01-01T23:59:59.000Z

474

Optical fibers by butyl methacrylate reactive extrusion Berthet Romuald, Chalamet Yvan, Taha Mohamed*, Zerroukhi Amar  

E-Print Network [OSTI]

limitations. Reactive extrusion experiments were carried out in a twin-screw extruder and the effect optical fibbers, polymethacrylate. Introduction Twin screw extruders are playing an increasing role of reactive extrusion is explained by the different advantages offered by the use of the twin-screw extruders

Paris-Sud XI, Université de

475

E-Print Network 3.0 - acaricide tri-n-butyl tin Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of California, Davis; Seybold, Steven J. - Departments of Entomology and Forest Resources, University of Minnesota Collection: Biotechnology ; Environmental Sciences and...

476

Oxidative desulfurization of dibenzothiophene with tert-butyl hydro peroxide in a photochemical micro-reactor.  

E-Print Network [OSTI]

??Sulfur content in fuels is an increasingly critical environmental issue. Hydrodesulfurization removes sulfur from hydrocarbons; however, further desulfurization is necessary in fuels. New methods are… (more)

Hebert, Eilleen M.

2007-01-01T23:59:59.000Z

477

Frontside versus backside reactivity in electron transfer to oriented tert butyl bromide and methyl bromide  

E-Print Network [OSTI]

by bimolecular nucleophilic substitution (SN2) reactions, such as Cl CH3BrClCH3 Br . 1 These reactions proceedH9Br. © 2002 American Institute of Physics. DOI: 10.1063/1.1496477 I. INTRODUCTION Chemical reaction decreases the reaction rate by orders of magnitude because the larger CH3 groups impede the inversion

Brooks, Philip R.

478

Saponification rates of isomeric butyl esters in aqueous 1,4-dioxane  

E-Print Network [OSTI]

, "Handbuch der Organischen Chemie," l*th ed., Vol. II, J. Springer, Berlin, 1920 (see also 1st and 2nd supplements); %. Schlenk, Jr., Ann., 573, 1^2(1951). 26 V. 1,4-Dioxane. The 1,4-dioxane (Matheson Co.) used in this research was specified...

Ruhnke, Edward Vincent

2013-10-04T23:59:59.000Z

479

E-Print Network 3.0 - antioxidant butylated hydroxytoluene Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

University Collection: Environmental Sciences and Ecology ; Biology and Medicine 5 Evaluation of Potential Therapies for a Mouse Model of Human Age-Related Macular Degeneration...

480

E-Print Network 3.0 - acid t-butyl ester Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

at Berkeley Collection: Materials Science ; Chemistry 67 Management of Hazardous Waste A Policy and Procedures Manual Summary: . It can be substituted by...

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481

MTBE, Oxygenates, and Motor Gasoline (Released in the STEO October 1999)  

Reports and Publications (EIA)

The blending of methyl tertiary butyl ether (MTBE) into motor gasoline has increased dramatically since it was first produced 20 years ago. MTBE usage grew in the early 1980's in response to octane demand resulting initially from the phaseout of lead from gasoline and later from rising demand for premium gasoline. The oxygenated gasoline program stimulated an increase in MTBE production between 1990 and 1994. MTBE demand increased from 83,000 in 1990 to 161,000 barrels per day in 1994. The reformulated gasoline (RFG) program provided a further boost to oxygenate blending. The MTBE contained in motor gasoline increased to 269,000 barrels per day by 1997.

1999-01-01T23:59:59.000Z

482

Modification of Y Zeolite with Alkaline Treatment: Textural Properties and Catalytic Activity for Diethyl Carbonate Synthesis  

Science Journals Connector (OSTI)

(1) Compared to dimethyl carbonate (DMC) and ethanol, DEC has been proposed as a potential fuel oxygenate additive to replace methyl tert-butyl ether (MTBE) because of its high oxygen content (40.6 wt %) and favorable fuel/water partition coefficient. ... For CuY using untreated zeolite as a support, there were only two H2-comsumption peaks at 473 and 681 K, ascribed to the Cu+ located on sites III? and II. ... Dunn, B. C.; Guenneau, C.; Hilton, S. A.; Pahnke, J.; Eyring, E. M.Production of diethyl carbonate from ethanol and carbon monoxide over a heterogeneous catalyst Energy Fuels 2002, 16, 177– 181 ...

Shouying Huang; Pengzhen Chen; Bing Yan; Shengping Wang; Yongli Shen; Xinbin Ma

2013-04-20T23:59:59.000Z

483