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Note: This page contains sample records for the topic "butyl ether ch" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

State Restrictions on Methyl Tertiary Butyl Ether (released in AEO2006)  

Reports and Publications (EIA)

By the end of 2005, 25 States had barred, or passed laws banning, any more than trace levels of MTBE in their gasoline supplies, and legislation to ban MTBE was pending in 4 others. Some State laws address only MTBE; others also address ethers such as ethyl tertiary butyl ether (ETBE) and tertiary amyl methyl ether (TAME). AEO2006 assumes that all State MTBE bans prohibit the use of all ethers for gasoline blending.

Information Center

2006-02-01T23:59:59.000Z

2

Refinery & Blenders Net Input of Methyl Tertiary Butyl Ether ...  

U.S. Energy Information Administration (EIA)

-No Data Reported; --= Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Notes: RBOB with Ether, RBOB ...

3

Enhanced diisobutene production in the presence of methyl tertiary butyl ether  

DOE Patents (OSTI)

In the liquid phase reaction of isobutene in the presence of resin cation exchange resins with itself in a C[sub 4] hydrocarbon stream to form dimers, the formation of higher polymers, oligomers, and co-dimer by-products is suppressed by the presence of 0.0001 to 1 mole per mole of isobutene of methyl tertiary butyl ether. 1 fig.

Smith, L.A. Jr.

1983-03-01T23:59:59.000Z

4

Ethyl-tertiary-butyl-ether (ETBE) as an aviation fuel: Eleventh international symposium on alcohol fuels  

DOE Green Energy (OSTI)

This paper discusses the preliminary flight testing of an aircraft using neat burning ethyl-tertiary-butyl-ether (ETBE) as a fuel. No additional changes were made to the fuel delivery systems which had previously been modified to provide the higher fuel flow rates required to operate the engine on neat ethanol. Air-fuel ratios were manually adjusted with the mixture control. This system allows the pilot to adjust the mixture to compensate for changes in air density caused by altitude, pressure and temperature. The engine was instrumented to measure exhaust gas temperatures (EGT), cylinder head temperatures (CHT), and fuel flows, while the standard aircraft instruments were used to collect aircraft performance data. Baseline engine data for ETBE and Avgas are compared. Preliminary data indicates the technical and economic feasibility of using ETBE as an aviation fuel for the piston engine fleet. Furthermore, the energy density of ETBE qualifies it as a candidate for a turbine engine fuel of which 16.2 billion gallons are used in the US each year.

Maben, G.D.; Shauck, M.E.; Zanin, M.G.

1996-12-31T23:59:59.000Z

5

Methyl tert-butyl ether (MTBE) is a volatile organic com-pound (VOC) derived from natural gas that is added to gas-  

E-Print Network (OSTI)

Methyl tert-butyl ether (MTBE) is a volatile organic com- pound (VOC) derived from natural gas Water in Urban and Agricultural Areas made from methanol, which is derived primarily from natural gas that is added to gas- oline either seasonally or year round in many parts of the United States to increase

6

Synthesis of octane enhancers during slurry-phase Fischer-Tropsch. [801Methyl tert-butyl ether  

DOE Green Energy (OSTI)

The objective of this project is to investigate three possible routes to the formation of ethers, in particular methyl tert-butyl ether (MTBE), during slurry phase Fischer-Tropsch reaction. The three reaction schemes to be investigated are: (1) Addition of isobutylene during the formation of methanol and/or higher alcohols directly from CO and H{sub 2} during slurry-phase Fischer-Tropsch. (2) Addition of isobutylene to FT liquid products including alcohols in a slurry-phase reactor containing an MTBE or other acid catalyst. (3) Addition of methanol to slurry phase FT synthesis making iso-olefins. During the sixth quarter we completed the construction of the slurry bubble column reactor (SBCR), conducted initial shake-down experiments in a cold-flow mode, and finalized the selection process of the acid catalysts for conversion of syngas-produced alcohols and isobutylene to MTBE (scheme 2). Tasks 3, 4, and 5 are awaiting complete implementation of the SBCR system.

Marcelin, G.

1992-06-24T23:59:59.000Z

7

Determination of Methyl tert-Butyl Ether and tert-Butyl Alcohol in Water by Solid-Phase Microextraction/Head Space Analysis in Comparison to EPA Method 5030/8260B  

DOE Green Energy (OSTI)

Methyl tert-butyl ether (MTBE) is now one of the most common groundwater contaminants in the United States. Groundwater contaminated with MTBE is also likely to be contaminated with tert-butyl alcohol (TBA), because TBA is a component of commercial grade MTBE, TBA can also be used as a fuel oxygenate, and TBA is a biodegradation product of MTBE. In California, MTBE is subject to reporting at concentrations greater than 3 {micro}g/L. TBA is classified as a ''contaminant of current interest'' and has a drinking water action level of 12 {micro}g/L. In this paper, we describe the development and optimization of a simple, automated solid phase microextraction (SPME) method for the analysis of MTBE and TBA in water and demonstrate the applicability of this method for monitoring MTBE and TBA contamination in groundwater, drinking water, and surface water. In this method, the headspace (HS) of a water sample is extracted with a carboxen/polydimethylsiloxane SPME fiber, the MTBE and TBA are desorbed into a gas chromatograph (GC), and detected using mass spectrometry (MS). The method is optimized for the routine analysis of MTBE and TBA with a level of quantitation of 0.3 {micro}g/L and 4 {micro}g/L, respectively, in water. MTBE quantitation was linear for over two orders of concentration (0.3 {micro}g/L -80 {micro}g/L). TBA was found to be linear within the range of 4 {micro}g/L-7,900 {micro}g/L. The lower level of detection for MTBE is 0.03 {micro}g/L using this method. This SPME method using headspace extraction was found to be advantageous over SPME methods requiring immersion of the fiber into the water samples, because it prolonged the life of the fiber by up to 400 sample analyses. This is the first time headspace extraction SPME has been shown to be applicable to the measurement of both MTBE and TBA at concentrations below regulatory action levels. This method was compared with the certified EPA Method 5030/8260B (purge-and-trap/GC/MS) using split samples from laboratory bioreactors treating MTBE contaminated water and applied to environmental samples collected throughout the East Bay area of California. Results from the SPME-HS/GC/MS method were directly comparable to the EPA Method 5030/8260B. This method provides an simple, inexpensive, accurate, and sensitive alternative to EPA Method 5030/8260B for the analysis of MTBE and TBA in water samples.

Oh, Keun-Chan; Stringfellow, William T.

2003-10-02T23:59:59.000Z

8

Experimental Pathology Laboratories, Inc. Ethyl-Tertiary-Butyl Ether  

E-Print Network (OSTI)

a plantation about 15-year-old in the Les Cedres area, near Montreal (45820H N, 73854H W). Trees in open

Bandettini, Peter A.

9

Removal of technetium from alkaline nuclear-waste media by a solvent-extraction process using crown ethers  

SciTech Connect

Crown ethers dissolved in suitably modified aliphatic kerosene diluents can be employed to extract technetium as pertechnetate anion (TcO{sub 4}{sup {minus}}) with good extraction ratios from realistic simulants of radioactive alkaline nitrate waste. The modifiers utilized are non-halogenated and non-volatile, and the technetium can be removed from the solvent by stripping using water. The crown ethers bis-4,4{prime}(5{prime})[(tert-butyl)cyclohexano]-18-crown-6 (di-t-BuCH18C6) and dicyclohexano-18-crown-6 (DCH18C6) provide stronger TcO{sub 4}{sup {minus}} extraction than dicyclohexano-21-crown-7 and 4-tert-butylcyclohexano 15-crown-5. Whereas DCH18C6 provides somewhat higher TcO{sub 4}{sup {minus}} extraction ratios than the more lipophilic di-t-BuCH18C6 derivative, the latter was selected for further study owing to its lower distribution to the aqueous phase. Particularly good extraction and stripping results were obtained with di-t-BuCH 18C6 at 0.02 M in a 2:1 vol/vol blend of tributyl phosphate and Isopar{reg_sign} M. Using this solvent, 98.9% of the technetium contained (at 6 {times} 10{sup {minus}5} M) in a Double-Shell Slurry Feed (DSSF) Hanford tank waste simulant was removed following two cross-current extraction contacts. Two cross-current stripping contacts with deionized water afforded removal of 99.1% of the technetium from the organic solvent.

Bonnesen, P.V.; Presley, D.J.; Haverlock, T.J.; Moyer, B.A. [Oak Ridge National Lab., TN (United States). Chemical and Analytical Sciences Div.

1995-07-01T23:59:59.000Z

10

Radiation chemistry of alternative fuel oxygenates -- Substituted ethers  

DOE Green Energy (OSTI)

The electron beam process, an advanced oxidation and reduction technology, is based in the field of radiation chemistry. Fundamental to the development of treatment processes is an understanding of the underlying chemistry. The authors have previously evaluated the bimolecular rate constants for the reactions of methyl tert-butyl ether (MTBE) and with this study have extended their studies to include ethyl tert-butyl ether (ETBE), di-isopropyl ether (DIPE) and tert-amyl methyl ether (TAME) with the hydroxyl radical, hydrogen atom and solvated electron using pulse radiolysis. For all of the oxygenates the reaction with the hydroxyl radical appears to be of primary interest in the destruction of the compounds in water. The rates with the solvated electron are limiting values as the rates appear to be relatively low. The hydrogen atom rate constants are relatively low, coupled with the low yield in radiolysis, they concluded that these are of little significance in the destruction of the alternative fuel oxygenates (and MTBE).

Mezyk, S. P.; Cooper, W. J.; Bartels, D. M.; Tobien, T.; O'Shea, K. E.

1999-11-15T23:59:59.000Z

11

Alkaline-side extraction of technetium from tank waste using crown ethers and other extractants  

SciTech Connect

The chemical development of a new crown-ether-based solvent-extraction process for the separation of (Tc) from alkaline tank-waste supernate is ready for counter-current testing. The process addresses a priority need in the proposed cleanup of Hanford and other tank wastes. This need has arisen from concerns due to the volatility of Tc during vitrification, as well as {sup 99}Tc`s long half-life and environmental mobility. The new process offers several key advantages that direct treatability--no adjustment of the waste composition is needed; economical stripping with water; high efficiency--few stages needed; non-RCRA chemicals--no generation of hazardous or mixed wastes; co-extraction of {sup 90}Sr; and optional concentration on a resin. A key concept advanced in this work entails the use of tandem techniques: solvent extraction offers high selectivity, while a subsequent column sorption process on the aqueous stripping solution serves to greatly concentrate the Tc. Optionally, the stripping solution can be evaporated to a small volume. Batch tests of the solvent-extraction and stripping components of the process have been conducted on actual melton Valley Storage Tank (MVST) waste as well as simulants of MVST and Hanford waste. The tandem process was demonstrated on MVST waste simulants using the three solvents that were selected the final candidates for the process. The solvents are 0.04 M bis-4,4{prime}(5{prime})[(tert-butyl)cyclohexano]-18-crown-6 (abbreviated di-t-BuCH18C6) in a 1:1 vol/vol blend of tributyl phosphate and Isopar{reg_sign} M (an isoparaffinic kerosene); 0.02 M di-t-BuCH18C6 in 2:1 vol/vol TBP/Isopar M and pure TBP. The process is now ready for counter-current testing on actual Hanford tank supernates.

Bonnesen, P.V.; Moyer, B.A.; Presley, D.J.; Armstrong, V.S.; Haverlock, T.J.; Counce, R.M.; Sachleben, R.A.

1996-06-01T23:59:59.000Z

12

PURIFICATION OF ETHER  

DOE Patents (OSTI)

BS>A process for removing peroxides from ethers by sorption on a strong- base anion exchange resin in its hydroxyl form is described. Incorporation of the resin for storage is also covered. (AEC)

Feinstein, R.N.

1961-10-01T23:59:59.000Z

13

Methane (CH4)  

NLE Websites -- All DOE Office Websites (Extended Search)

Methane (CH4) Gateway Pages to Methane Data Modern Records of Atmospheric Methane (CH4) and a 2000-year Ice-core Record from Law Dome, Antarctica 800,000-year Ice-Core Records of...

14

CH Packaging Operations Manual  

Science Conference Proceedings (OSTI)

This procedure provides instructions forassembling the following CH packaging payload: Drum payload assembly Standard Waste Box (SWB) assembly Ten-Drum Overpack (TDOP)

Washington TRU Solutions LLC

2007-11-29T23:59:59.000Z

15

CH Packaging Operations Manual  

SciTech Connect

Introduction - This procedure provides instructions for assembling the following CH packaging payload: - Drum payload assembly - Standard Waste Box (SWB) assembly - Ten-Drum Overpack (TDOP).

Washington TRU Solutions

2002-03-04T23:59:59.000Z

16

CH Packaging Operations Manual  

SciTech Connect

Introduction - This procedure provides instructions forassembling the following CH packaging payload: Drum payload assembly Standard Waste Box (SWB) assembly Ten-Drum Overpack (TDOP)

Washington TRU Solutions LLC

2006-12-18T23:59:59.000Z

17

CH Packaging Operations Manual  

SciTech Connect

This procedure provides instructions forassembling the following CH packaging payload: Drum payload assembly Standard Waste Box (SWB) assembly Ten-Drum Overpack (TDOP)

Washington TRU Solutions LLC

2007-08-22T23:59:59.000Z

18

CH Packaging Operations Manual  

Science Conference Proceedings (OSTI)

Introduction - This procedure provides instructions for assembling the following CH packaging payload: -Drum payload assembly -Standard Waste Box (SWB) assembly -Ten-Drum Overpack (TDOP).

Washington TRU Solutions LLC

2003-06-26T23:59:59.000Z

19

CH Packaging Operations Manual  

SciTech Connect

Introduction - This procedure provides instructions forassembling the following CH packaging payload: Drum payload assembly Standard Waste Box (SWB) assembly Ten-Drum Overpack (TDOP)

Washington TRU Solutions LLC

2007-05-15T23:59:59.000Z

20

Treatment of Methyl tert-Butyl Ether Vapors in Biotrickling Filters. 2.  

E-Print Network (OSTI)

will controlled by diffusion in the biofilm near the outlet of the reactor. A fundamental parameter and control in bioreactors equipped with some degree of instrumentation, fundamental knowledge for the proper handbook of physical-chemical properties and environmental fate for organic chemicals, Volume III. Volatile

Note: This page contains sample records for the topic "butyl ether ch" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Treatment of Methyl tert-Butyl Ether Vapors in Biotrickling Filters. 1.  

E-Print Network (OSTI)

, weed-eater, shovel, and a rake. A chipper, compost bin, or a large rented trash dumpster may be useful

22

CH Packaging Operations Manual  

Science Conference Proceedings (OSTI)

This procedure provides instructions for assembling the CH Packaging Drum payload assembly, Standard Waste Box (SWB) assembly, Abnormal Operations and ICV and OCV Preshipment Leakage Rate Tests on the packaging seals, using a nondestructive Helium (He) Leak Test.

Washington TRU Solutions LLC

2005-06-13T23:59:59.000Z

23

CATALYSTS FOR HIGH CETANE ETHERS AS DIESEL FUELS  

DOE Green Energy (OSTI)

A tungstena-zirconia (WZ) catalyst has been investigated for coupling methanol and isobutanol to unsymmetrical ethers, i.e. methyl isobutyl ether (MIBE) and compared with earlier studied sulfated-zirconia (SZ) and Nafion-H catalysts. In all cases, the ether synthesis mechanism is a dual site S{sub N}2 process involving competitive adsorption of reactants on proximal acid sites. At low reaction temperatures, methylisobutylether (MIBE) is the predominant product. However, at temperatures >135 C the WZ catalyst is very good for dehydration of isobutanol to isobutene. The surface acid sites of the WZ catalyst and a Nafion-H catalyst were diagnosed by high resolution X-ray photoelectron spectroscopy (XPS) of N 1s shifts after adsorption of amines. Using pyridine, ethylenediamine, and triethylamine, it is shown that WZ has heterogeneous strong Broensted acid sites. Theoretical study located the transition state of the alcohol coupling reaction on proximal Broensted acid sites and accounted well for XPS core-level shifts upon surface acid-base interactions. While computations have not been carried out with WZ, it is shown that the SZ catalyst is a slightly stronger acid than CF{sub 3}SO{sub 3}H (a model for Nafion-H) by 1.3-1.4 kcal/mol. A novel sulfated zirconia catalyst having proximal strong Broensted acid sites was synthesized and shown to have significantly enhanced activity and high selectivity in producing MIBE or isobutene from methanol/isobutanol mixtures. The catalyst was prepared by anchoring 1,2-ethanediol bis(hydrogen sulfate) salt precursor onto zirconium hydroxide, followed by calcination to remove the -(CH{sub 2}CH{sub 2})- bridging residues.

Kamil Klier; Richard G. Herman; Heock-Hoi Kwon; James G. C. Shen; Qisheng Ma; Robert A. Hunsicker; Andrew P. Butler; Scott J. Bollinger

2003-03-01T23:59:59.000Z

24

Aza crown ether compounds as anion receptors  

DOE Patents (OSTI)

A family of aza-ether based compounds including linear, multi-branched and aza-crown ethers is provided. When added to non-aqueous battery electrolytes, the new family of aza-ether based compounds acts as neutral receptors to complex the anion moiety of the electrolyte salt thereby increasing the conductivity and the transference number of LI{sup +} ion in alkali metal batteries. 3 figs.

Lee, H.S.; Yang, X.O.; McBreen, J.

1998-08-04T23:59:59.000Z

25

Aza crown ether compounds as anion receptors  

SciTech Connect

A family of aza-ether based compounds including linear, multi-branched and aza-crown ethers is provided. When added to non-aqueous battery electrolytes, the new family of aza-ether based compounds acts as neutral receptors to complex the anion moiety of the electrolyte salt thereby increasing the conductivity and the transference number of LI.sup.+ ion in alkali metal batteries.

Lee, Hung Sui (East Setauket, NY); Yang, Xiao-Oing (Port Jefferson Station, NY); McBreen, James (Bellport, NY)

1998-08-04T23:59:59.000Z

26

Catalytic distillation for the synthesis of tertiary butyl alcohol.  

E-Print Network (OSTI)

??Catalytic Distillation for the synthesis of tertiary butyl alcohol (TBA) is investigated in this thesis. The solvent, ethylene glycol, is proposed as a means of (more)

Safinski, Tomasz

2005-01-01T23:59:59.000Z

27

CH-TRU Waste Content Codes (CH-TRUCON)  

Science Conference Proceedings (OSTI)

The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments" (10-day shipping period).

Washington TRU Solutions LLC

2004-10-01T23:59:59.000Z

28

CH-TRU Waste Content Codes (CH-TRUCON)  

Science Conference Proceedings (OSTI)

The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments" (10-day shipping period).

Washington TRU Solutions LLC

2006-06-20T23:59:59.000Z

29

CH-TRU Waste Content Codes (CH-TRUCON)  

Science Conference Proceedings (OSTI)

The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments" (10-day shipping period).

Washington TRU Solutions LLC

2005-12-15T23:59:59.000Z

30

CH-TRU Waste Content Codes (CH-TRUCON)  

Science Conference Proceedings (OSTI)

The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments" (10-day shipping period).

Washington TRU Solutions LLC

2006-01-18T23:59:59.000Z

31

CH-TRU Waste Content Codes (CH-TRUCON)  

Science Conference Proceedings (OSTI)

The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments" (10-day shipping period).

Washington TRU Solutions LLC

2007-02-15T23:59:59.000Z

32

CH-TRU Waste Content Codes (CH-TRUCON)  

Science Conference Proceedings (OSTI)

The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments" (10-day shipping period).

Washington TRU Solutions LLC

2005-05-01T23:59:59.000Z

33

CH-TRU Waste Content Codes (CH-TRUCON)  

Science Conference Proceedings (OSTI)

The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments" (10-day shipping period).

Washington TRU Solutions LLC

2006-12-20T23:59:59.000Z

34

CH-TRU Waste Content Codes (CH-TRUCON)  

Science Conference Proceedings (OSTI)

The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments" (10-day shipping period).

Washington TRU Solutions LLC

2007-06-15T23:59:59.000Z

35

CH-TRU Waste Content Codes (CH-TRUCON)  

Science Conference Proceedings (OSTI)

The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments" (10-day shipping period).

Washington TRU Solutions LLC

2006-08-15T23:59:59.000Z

36

CH-TRU Waste Content Codes (CH-TRUCON)  

Science Conference Proceedings (OSTI)

The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments" (10-day shipping period).

Washington TRU Solutions LLC

2005-01-30T23:59:59.000Z

37

CH-TRU Waste Content Codes (CH-TRUCON)  

Science Conference Proceedings (OSTI)

The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments" (10-day shipping period).

Washington TRU Solutions LLC

2005-06-20T23:59:59.000Z

38

CH-TRU Waste Content Codes (CH-TRUCON)  

Science Conference Proceedings (OSTI)

The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments" (10-day shipping period).

Washington TRU Solutions LLC

2007-08-15T23:59:59.000Z

39

CH-TRU Waste Content Codes (CH-TRUCON)  

Science Conference Proceedings (OSTI)

The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments" (10-day shipping period).

Washington TRU Solutions LLC

2005-11-20T23:59:59.000Z

40

CH-TRU Content Codes (CH-TRUCON)  

Science Conference Proceedings (OSTI)

The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments" (10-day shipping period).

Washington TRU Solutions LLC

2005-10-15T23:59:59.000Z

Note: This page contains sample records for the topic "butyl ether ch" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

CH-TRU Waste Content Codes (CH TRUCON)  

Science Conference Proceedings (OSTI)

The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments" (10-day shipping period).

Washington TRU Solutions LLC

2004-12-01T23:59:59.000Z

42

CH-TRU Waste Content Codes (CH-TRUCON)  

Science Conference Proceedings (OSTI)

The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments" (10-day shipping period).

Washington TRU Solutions LLC

2007-09-20T23:59:59.000Z

43

CH-TRU Waste Content Codes (CH-TRUCON)  

Science Conference Proceedings (OSTI)

The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments" (10-day shipping period).

Washington TRU Solutions LLC

2006-09-15T23:59:59.000Z

44

CH-TRU Waste Content Codes (CH-TRUCON)  

Science Conference Proceedings (OSTI)

The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codesand corresponding shipping categories for "Controlled Shipments" (10-day shipping period).

Washington TRU Solutions LLC

2005-01-15T23:59:59.000Z

45

CH-TRU Waste Content Codes (CH-TRUCON)  

Science Conference Proceedings (OSTI)

The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments" (10-day shipping period).

Washington TRU Solutions LLC

2005-03-15T23:59:59.000Z

46

CH-TRU Waste Content Codes (CH-TRUCON)  

Science Conference Proceedings (OSTI)

The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments" (10-day shipping period).

Washington TRU Solutions LLC

2005-08-15T23:59:59.000Z

47

Whole-Genome Analysis of Methyl tert-Butyl Ether-Degrading Beta-Proteobacterium Methylibium petroleiphilum PM1  

E-Print Network (OSTI)

of benzene to phenol, catechol, and 1,2,3-trihydroxybenzeneof benzene to phenol (and catechol), and toluene toa multi-component PH, catechol 2,3-dioxygenase and the meta-

2007-01-01T23:59:59.000Z

48

IDENTIFYING THE USAGE PATTERNS OF METHYL TERT-BUTYL ETHER (MTBE) AND OTHER OXYGENATES IN GASOLINE USING GASOLINE  

E-Print Network (OSTI)

and Energy Research (NIPER), 2) the Motor Vehicle Manufacturers Association (MVMA), and 3) the U interested in fuel comparisons Thousands each year Motor Vehicle Manufacturers Association (MVMA) National gasoline survey Motor Vehicle Manufacturers Association 23 cities throughout the U.S. Summer of 1988

49

Whole-Genome Analysis of Methyl tert-Butyl Ether-Degrading Beta-Proteobacterium Methylibium petroleiphilum PM1  

E-Print Network (OSTI)

by pure cultures of butane-degrading bacteria. Appl.of K s values for MTBE by butane- degrading bacteria (52).

2007-01-01T23:59:59.000Z

50

CH 338 Winter 2008 CH 338 (CRN 21222)  

E-Print Network (OSTI)

Instructor: Dr. Michael E. Koscho 175 Onyx / 346-2924 koscho@uoregon.edu [please use CH 338 as the subject-line, finding immeasurable utility in our everyday lives. The isolation, preparation, purification times. The chemical laboratory is a safe place to work when everyone in the laboratory is dedicated

Richmond, Geraldine L.

51

Comparative Environmental Performance of Two-Diesel-Fuel Oxygenates: Dibutyl Maleate (DBM) and Triproplyene Glycol Monomethyl Ether (TGME)  

DOE Green Energy (OSTI)

Many studies have shown that the addition of oxygen bearing compounds to diesel fuel can significantly reduce particulate emissions. To assist in the evaluation of the environmental performance of diesel-fuel oxygenates, we have implemented a suite of diagnostic models for simulating the transport of compounds released to air, water, and soils/groundwater as well as regional landscapes. As a means of studying the comparative performance of DBM and TGME, we conducted a series of simulations for selected environmental media. Benzene and methyl tertiary butyl ether (MTBE) were also addressed because they represent benchmark fuel-related compounds that have been the subject of extensive environmental measurements and modeling. The simulations showed that DBM and TGME are less mobile in soil because of reduced vapor-phase transport and increased retention on soil particles. The key distinction between these two oxygenates is that DBM is predicted to have a greater potential than TGME for aerobic biodegradation, based on chemical structure.

Layton, D.W.; Marchetti, A.A.

2001-10-01T23:59:59.000Z

52

ChIP-PED enhances the analysis of ChIP-seq and ChIP-chip data  

Science Conference Proceedings (OSTI)

Motivation: Although chromatin immunoprecipitation coupled with high-throughput sequencing (ChIP-seq) or tiling array hybridization (ChIP-chip) is increasingly used to map genome-widebinding sites of transcription factors (TFs), it still ...

George Wu, Jason T. Yustein, Matthew N. McCall, Michael Zilliox, Rafael A. Irizarry, Karen Zeller, Chi V. Dang, Hongkai Ji

2013-05-01T23:59:59.000Z

53

Divinyl ether synthase gene and protein, and uses thereof  

DOE Patents (OSTI)

The present invention relates to divinyl ether synthase genes, proteins, and methods of their use. The present invention encompasses both native and recombinant wild-type forms of the synthase, as well as mutants and variant forms, some of which possess altered characteristics relative to the wild-type synthase. The present invention also relates to methods of using divinyl ether synthase genes and proteins, including in their expression in transgenic organisms and in the production of divinyl ether fatty acids, and to methods of suing divinyl ether fatty acids, including in the protection of plants from pathogens.

Howe, Gregg A. (East Lansing, MI); Itoh, Aya (Tsuruoka, JP)

2011-09-13T23:59:59.000Z

54

Separation of Dimethyl Ether from Syn-Gas Components by Poly(dimethylsiloxane) and Poly(4-methyl-1-pentene) Membranes  

Science Conference Proceedings (OSTI)

Permeability and selectivity in gas transport through poly(4-methyl-1-pentene) (TPX) and poly(dimethylsiloxane) (PDMS) using variable temperature mixed gas experiments is reported. Selected gases include H2, CO, CH4, CO2, and dimethyl ether (DME). The DME data is the first to be reported through these membranes. In this paper, the chosen polymers reflect both rubbery and crystalline materials. Rubbery polymers tend to be weakly size sieving, which, in this work, has resulted in larger permeabilities, lower separation factors, and lower activation energies of permeation (Ep). Conversely, the crystalline TPX membranes showed much greater sensitivity to penetrant size; although the gas condensability also played a role in transport.

Christopher J. Orme; Frederick F. Stewart

2011-05-01T23:59:59.000Z

55

SC-CH FACTS Customer Service  

NLE Websites -- All DOE Office Websites (Extended Search)

SC-CH FACTS SC-CH FACTS Customer Service Office of Communications P (630) 252-2110 F (630) 252-9473 Address 9800 South Cass Ave. Argonne, Illinois 60439 Websites Chicago Office www.ch.doe.gov Office of Science http://science.energy.gov/ U.S. Department of Energy http://energy.gov/ CH Factoids Who We Are ... Our Mission The Office of Science - Chicago Office (SC-CH) is a field office of the U.S. Department of Energy (DOE), a Cabinet-level agency with

56

Room Temperature Aging Study of Butyl O-rings  

Science Conference Proceedings (OSTI)

During testing under the Enhanced Surveillance Campaign in 2001, preliminary data detected a previously unknown and potentially serious concern with recently procured butyl o-rings. All butyl o-rings molded from a proprietary formulation throughout the period circa 1999 through 2001 had less than a full cure. Tests showed that sealing force values for these suspect o-rings were much lower than expected and their physical properties were very sensitive to further post curing at elevated temperatures. Further testing confirmed that these o-rings were approximately 50% cured versus the typical industry standard of > 90% cured. Despite this condition, all suspect o-rings fully conformed to their QC acceptance requirements, including their individual product drawing requirements.

Mark Wilson

2009-08-07T23:59:59.000Z

57

Process for producing dimethyl ether form synthesis gas  

DOE Green Energy (OSTI)

This invention pertains to a Fischer Tropsch process for converting synthesis gas to an oxygenated hydrocarbon with particular emphasis on dimethyl ether. Synthesis gas comprising carbon monoxide and hydrogen are converted to dimethyl ether by carrying out the reaction in the presence of an alkali metal-manganese-iron carbonyl cluster incorporated onto a zirconia-alumina support.

Pierantozzi, Ronald (Macungie, PA)

1985-01-01T23:59:59.000Z

58

Process for producing dimethyl ether from synthesis gas  

DOE Patents (OSTI)

This invention pertains to a Fischer Tropsch process for converting synthesis gas to an oxygenated hydrocarbon with particular emphasis on dimethyl ether. Synthesis gas comprising carbon monoxide and hydrogen are converted to dimethyl ether by carrying out the reaction in the presence of an alkali metal-manganese-iron carbonyl cluster incorporated onto a zirconia-alumina support.

Pierantozzi, R.

1985-06-04T23:59:59.000Z

59

Hydrogen production from the steam reforming of Dinethyl Ether and Methanol  

SciTech Connect

This study investigates dimethyl ether (DME) steam reforming for the generation of hydrogen rich fuel cell feeds for fuel cell applications. Methanol has long been considered as a fuel for the generation of hydrogen rich fuel cell feeds due to its high energy density, low reforming temperature, and zero impurity content. However, it has not been accepted as the fuel of choice due its current limited availability, toxicity and corrosiveness. While methanol steam reforming for the generation of hydrogen rich fuel cell feeds has been extensively studied, the steam reforming of DME, CH{sub 3}OCH{sub 3} + 3H{sub 2}O = 2CO{sub 2} + 6H{sub 2}, has had limited research effort. DME is the simplest ether (CH{sub 3}OCH{sub 3}) and is a gas at ambient conditions. DME has physical properties similar to those of LPG fuels (i.e. propane and butane), resulting in similar storage and handling considerations. DME is currently used as an aerosol propellant and has been considercd as a diesel substitute due to the reduced NOx, SOx and particulate emissions. DME is also being considered as a substitute for LPG fuels, which is used extensively in Asia as a fuel for heating and cooking, and naptha, which is used for power generation. The potential advantages of both methanol and DME include low reforming temperature, decreased fuel proccssor startup energy, environmentally benign, visible flame, high heating value, and ease of storage and transportation. In addition, DME has the added advantages of low toxicity and being non-corrosive. Consequently, DME may be an ideal candidate for the generation of hydrogen rich fuel cell feeds for both automotive and portable power applications. The steam reforming of DME has been demonstrated to occur through a pair of reactions in series, where the first reaction is DME hydration followed by MeOH steam reforming to produce a hydrogen rich stream.

Semelsberger, T. A. (Troy A.); Borup, R. L. (Rodney L.)

2004-01-01T23:59:59.000Z

60

CH Packaging Operations for High Wattage Waste  

Science Conference Proceedings (OSTI)

This document provides instructions for assembling the following CH packaging payload: Drum payload assembly Standard Waste Box (SWB) assembly Ten-Drum Overpack (TDOP)

Washington TRU Solutions LLC

2006-01-06T23:59:59.000Z

Note: This page contains sample records for the topic "butyl ether ch" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

AOCS Recommended Practice Ch 2a-94  

Science Conference Proceedings (OSTI)

trans Unsaturated Fatty Acids by Capillary Column Gas Chromatography AOCS Recommended Practice Ch 2a-94 Methods Methods and Analyses Analytical Chemistry Methods Downloads Methods Downloads AOCS DEFINITI

62

Solvent Effects on Metal Complexation with Crown Ethers from Liquid to Supercritical Fluids (DE-FG07-98ER 149 13)  

DOE Green Energy (OSTI)

The purpose of this project is to study the salvation effects of metal-crown ether complexation in different solvents. It has been suggested in the literature that supercritical fluid carbon dioxide (SF-CO2) is a tunable solvent because its salvation environment can be varied with the fluid density. In this project, spectroscopic techniques including nuclear magnetic resonance (NMR) and Fourier Transform Infrared (FTIR) were used to evaluate salvation effects of metal crown complexation in organic solvents and in SF-CO2. In most solvent extraction systems, water is often involved in the extraction processes. We have carried out extensive studies of water-crown ether interactions in different solvents and in SF-CO2 using NMR and FTIR techniques. Water molecules can be attached to crown ethers through hydrogen bonding of H-0-H to the oxygen atoms of crown ether cavities. This type of interaction is like a Lewis acid-Lewis base complexation. During the course of this project, we noticed that some CO2 soluble Lewis base such as tri-n-butyl-phosphate (TBP) can also form such Lewis acid-Lewis base complexes with water and other inorganic acids including nitric acid and hydrochloric acid. Inorganic acids (e.g. nitric acid) are normally not soluble in SF-CO2. However, because TBP is highly soluble in SF-CO2, an inorganic acid bound to TBP via hydrogen bonding becomes CO2 soluble. This Lewis acid-Lewis base complex approach provides a method of introducing inorganic acids into supercritical fluid CO2 for chemical reactions.

Wai, C.M.

2002-06-01T23:59:59.000Z

63

Crown Ethers in Nonaqueous Electrolytes for Lithium/Air Batteries  

SciTech Connect

The effects of three crown ethers, 12-crown-4, 15-crown-5, and 18-crown-6, as additives and co-solvents in non-aqueous electrolytes on the cell performance of primary Li/air batteries operated in a dry air environment were investigated. Crown ethers have large effects on the discharge performance of non-aqueous electrolytes in Li/air batteries. A small amount (normally less than 10% by weight or volume in electrolytes) of 12-Crown-4 and 15-crown-5 reduces the battery performance and a minimum discharge capacity appears at the crown ether content of ca. 5% in the electrolytes. However, when the content increases to about 15%, both crown ethers improve the capacity of Li/air cells by about 28% and 16%, respectively. 15-Crown-5 based electrolytes even show a maximum discharge capacity in the crown ether content range from 10% to 15%. On the other hand, the increase of 18-crown-6 amount in the electrolytes continuously lowers of the cell performance. The different battery performances of these three crown ethers in electrolytes are explained by the combined effects from the electrolytes contact angle, oxygen solubility, viscosity, ionic conductivity, and the stability of complexes formed between crown ether molecules and lithium ions.

Xu, Wu; Xiao, Jie; Wang, Deyu; Zhang, Jian; Zhang, Jiguang

2010-02-04T23:59:59.000Z

64

CH-TRU Waste Content Codes  

Science Conference Proceedings (OSTI)

The CH-TRU Waste Content Codes (CH-TRUCON) document describes the inventory of the U.S. Department of Energy (DOE) CH-TRU waste within the transportation parameters specified by the Contact-Handled Transuranic Waste Authorized Methods for Payload Control (CH-TRAMPAC). The CH-TRAMPAC defines the allowable payload for the Transuranic Package Transporter-II (TRUPACT-II) and HalfPACT packagings. This document is a catalog of TRUPACT-II and HalfPACT authorized contents and a description of the methods utilized to demonstrate compliance with the CH-TRAMPAC. A summary of currently approved content codes by site is presented in Table 1. The CH-TRAMPAC describes "shipping categories" that are assigned to each payload container. Multiple shipping categories may be assigned to a single content code. A summary of approved content codes and corresponding shipping categories is provided in Table 2, which consists of Tables 2A, 2B, and 2C. Table 2A provides a summary of approved content codes and corresponding shipping categories for the "General Case," which reflects the assumption of a 60-day shipping period as described in the CH-TRAMPAC and Appendix 3.4 of the CH-TRU Payload Appendices. For shipments to be completed within an approximately 1,000-mile radius, a shorter shipping period of 20 days is applicable as described in the CH-TRAMPAC and Appendix 3.5 of the CH-TRU Payload Appendices. For shipments to WIPP from Los Alamos National Laboratory (LANL), Nevada Test Site, and Rocky Flats Environmental Technology Site, a 20-day shipping period is applicable. Table 2B provides a summary of approved content codes and corresponding shipping categories for "Close-Proximity Shipments" (20-day shipping period). For shipments implementing the controls specified in the CH-TRAMPAC and Appendix 3.6 of the CH-TRU Payload Appendices, a 10-day shipping period is applicable. Table 2C provides a summary of approved content codes and corresponding shipping categories for "Controlled Shipments" (10-day shipping period).

Washington TRU Solutions LLC

2008-01-16T23:59:59.000Z

65

AOCS Official Method Ch 1-91  

Science Conference Proceedings (OSTI)

Preparation of Methyl Esters of Long-Chain Fatty Acids AOCS Official Method Ch 1-91 Methods Methods and Analyses Analytical Chemistry Methods Downloads Methods Downloads DEFINITION This method provides a means

66

AOCS Official Method Ch 2-91  

Science Conference Proceedings (OSTI)

Determination of Fatty Acids in Olive Oils by Capillary GLC AOCS Official Method Ch 2-91 Methods Methods and Analyses Analytical Chemistry Methods Downloads Methods Downloads DEFINITION This method is for the d

67

AOCS Official Method Ch 8-02  

Science Conference Proceedings (OSTI)

Determination of Wax Content by Capillary Column Gas-Liquid Chromatography AOCS Official Method Ch 8-02 Methods Methods and Analyses Analytical Chemistry Methods Downloads Methods Downloads DEFINITION Addition

68

AOCS Official Method Ch 6-91  

Science Conference Proceedings (OSTI)

Determination of the Composition of the Sterol Fraction of Animal and Vegetable Oils and Fats by TLC and Capillary GLC AOCS Official Method Ch 6-91 Methods Methods and Analyses Analytical Chemistry Methods Downloads Methods Downloads AOCS ...

69

AOCS Official Method Ch 7-09  

Science Conference Proceedings (OSTI)

International Trade Standard Applying to Olive and Olive-Pomace Oils AOCS Official Method Ch 7-09 Methods Methods and Analyses Analytical Chemistry Methods Downloads Methods Downloads DEFINITION These analytica

70

AOCS Official Method Ch 3-91  

Science Conference Proceedings (OSTI)

Determination of Fatty Acids in the 2-Position in the Triglycerides of Oils and Fats AOCS Official Method Ch 3-91 Methods Methods and Analyses Analytical Chemistry Methods Downloads Methods Downloads DEFINITION ...

71

Linear growth for Ch\\^atelet surfaces  

E-Print Network (OSTI)

An upper bound of the expected order of magnitude is established for the number of rational points of bounded height on Ch\\^atelet surfaces defined over the rationals.

Browning, T D

2009-01-01T23:59:59.000Z

72

AOCS Official Method Ch 4-91  

Science Conference Proceedings (OSTI)

Chlorophyll Pigments AOCS Official Method Ch 4-91 Methods Methods and Analyses Analytical Chemistry Methods Downloads Methods Downloads DEFINITION This method is used to determine mg/kg of chlorophyll-related p

73

AOCS Official Method Ch 5-91  

Science Conference Proceedings (OSTI)

Determination of Specific Extinction of Oils and Fats, Ultraviolet Absorption AOCS Official Method Ch 5-91 Methods Methods and Analyses Analytical Chemistry Methods Downloads Methods Downloads DEFINITION This m

74

NMR Study of the Dynamics of ILs with -CH2Si(CH3)3 vs CH2C(CH3)3  

NLE Websites -- All DOE Office Websites (Extended Search)

Magnetic Resonance Study of the Dynamics of Imidazolium Ionic Magnetic Resonance Study of the Dynamics of Imidazolium Ionic Liquids with -CH2Si(CH3)3 vs CH2C(CH3)3 Substituents S. H. Chung, R. Lopato, S. G. Greenbaum, H. Shirota, E. W. Castner, Jr. and J. F. Wishart J. Phys. Chem. B 111, 4885-4893 (2007). [Find paper at ACS Publications] or use ACS Articles on Request Abstract: Trimethylsilylmethyl (TMSiM)-substituted imidazolium bis(trifluoromethylsulfonyl)imide (NTf2-), and tetrafluoroborate (BF4-) ionic liquids (ILs) have lower room-temperature viscosities by factors of 1.6 and 7.4, respectively, than isostructural neopentylimidazolium ILs. In an attempt to account for the effects of silicon substitution in imidazolium RTILs and to investigate the ion dynamics, we report nuclear magnetic resonance (NMR) measurements of 1H (I = 1/2) and 19F (I = 1/2)

75

Dynamic Reduction of a CH4/Air Chemical Mechanism Appropriate...  

NLE Websites -- All DOE Office Websites (Extended Search)

Dynamic Reduction of a CH4Air Chemical Mechanism Appropriate for Investigating Vortex Flame Interactions Title Dynamic Reduction of a CH4Air Chemical Mechanism Appropriate for...

76

Multipodal coordination of a tetracarboxylic crown ether with NH 4 + : A vibrational spectroscopy and computational study  

Science Conference Proceedings (OSTI)

The elucidation of the structural requirements for molecular recognition by the crown ether (18crown6)-2

Paola Hurtado; Francisco Gmez; Said Hamad; Bruno MartnezHaya; Jeffrey D. Steill; Jos Oomens

2012-01-01T23:59:59.000Z

77

Direct synthesis of dimethyl ether (DME) from syngas  

Science Conference Proceedings (OSTI)

We have developed appropriate and excellent catalysts for direct DME synthesis. The catalysts, Cu-Zn/Al2O3 catalysts prepared by the sol-gel method, produce DME with high DME activity and high DME selectivity under milder reaction ... Keywords: DME, alumina, catalyst, clean fuel, copper, dimethyl ether, direct synthesis, hydrogen, sol-gel method, syngas

Kaoru Takeishi; Yoshimi Akaike

2010-02-01T23:59:59.000Z

78

www.ethz.ch Dear reader  

E-Print Network (OSTI)

and energy economy. With the necessary reduction in overall energy consumption, the demand for electricity in electrical energy technology, with the aim of gaining wider knowledge on high voltage net- works and energy emissions in electricity generation by 2050. Info: www.esc.ethz.ch #12;ElEkTRoTECHNoloGIE IN SHoRT FRESH FRo

79

Solvent extraction of technetium from alkaline waste media using bis-4,4{prime}(5{prime})[(tert-butyl)cyclohexano]-18-crown-6  

SciTech Connect

The crown ether bis-4,4`(5`)[(tert-butyl)cyclohexano]-18-crown-6 can be utilized in a solvent-extraction process for the removal of technetium as pertechnetate ion, TcO{sub 4}{sup {minus}} from solutions simulating highly radioactive alkaline defense wastes (``tank wastes``) stored at several sites in the United States. The process employs non-halogenated and non-volatile diluents and modifiers and includes an efficient stripping procedure using only water. More than 95% of the pertechnetate present at 6 {times} 10{sup {minus}5} M in Melton Valley (Oak Ridge, TN) and Hanford (Washington) tank-waste simulants was removed following two cross-current extraction contacts using 0.02 M bis-4,4`(5`)[(tertbutyl)cyclohexano]- 18-crown-6 in 2:1 vol/vol TBP/Isopar{reg_sign} M diluent at 25 C. Similarly, for both simulants, more than 98% of the pertechnetate contained in the solvent was back-extracted following two cross-current stripping contacts using deionized water.

Bonnesen, P.V.; Presley, D.J.; Moyer, B.A.

1995-07-01T23:59:59.000Z

80

Effects of simulant mixed waste on EPDM and butyl rubber  

Science Conference Proceedings (OSTI)

The authors have developed a Chemical Compatibility Testing Program for the evaluation of plastic packaging components which may be used in transporting mixed waste forms. In this program, they have screened 10 plastic materials in four liquid mixed waste simulants. These plastics were butadiene-acrylonitrile copolymer (Nitrile) rubber, cross-linked polyethylene, epichlorohydrin rubber, ethylene-propylene (EPDM) rubber, fluorocarbons (Viton and Kel-F{trademark}), polytetrafluoro-ethylene (Teflon), high-density polyethylene, isobutylene-isoprene copolymer (Butyl) rubber, polypropylene, and styrene-butadiene (SBR) rubber. The selected simulant mixed wastes were (1) an aqueous alkaline mixture of sodium nitrate and sodium nitrite; (2) a chlorinated hydrocarbon mixture; (3) a simulant liquid scintillation fluid; and (4) a mixture of ketones. The screening testing protocol involved exposing the respective materials to approximately 3 kGy of gamma radiation followed by 14-day exposures to the waste simulants at 60 C. The rubber materials or elastomers were tested using Vapor Transport Rate measurements while the liner materials were tested using specific gravity as a metric. The authors have developed a chemical compatibility program for the evaluation of plastic packaging components which may be incorporated in packaging for transporting mixed waste forms. From the data analyses performed to date, they have identified the thermoplastic, polychlorotrifluoroethylene, as having the greatest chemical compatibility after having been exposed to gamma radiation followed by exposure to the Hanford Tank simulant mixed waste. The most striking observation from this study was the poor performance of polytetrafluoroethylene under these conditions. In the evaluation of the two elastomeric materials they have concluded that while both materials exhibit remarkable resistance to these environmental conditions, EPDM has a greater resistance to this corrosive simulant mixed waste.

Nigrey, P.J.; Dickens, T.G.

1997-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "butyl ether ch" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

CH-ANL Report.indd  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

1 2.0 STATUS AND RESULTS ..................................................................... 1 3.0 CONCLUSIONS .................................................................................... 5 4.0 RATING ................................................................................................. 5 5.0 OPPORTUNITIES FOR IMPROVEMENT .......................................... 6 APPENDIX A: SUPPLEMENTAL INFORMATION ................................... 7 APPENDIX B: SITE-SPECIFIC FINDINGS ................................................. 8 Abbreviations Used in This Report ANL Argonne National Laboratory CH Offi ce of Science Chicago Offi ce CIC Classifi cation and Information Control DOE U.S. Department of Energy NNSA National Nuclear Security Administration

82

Enforcement Letter, CH2M Hill- October 4, 2004  

Energy.gov (U.S. Department of Energy (DOE))

Issued to CH2M Hill related to at a Lapse in Dosimetry Accreditation at the Separations Process Research Unit

83

The interactions of water and perfluorodiethyl ether on Ru(100)  

DOE Green Energy (OSTI)

We have studied the interactions of water and perfluorodiethyl ether on Ru(100) in order to model the effects of surface structure and humidity on the bonding and decomposition of perfluoroalkyl ether lubricants with metal surfaces. In order to understand the interactions on Ru(100), we have first investigated the interactions of each of these adsorbates alone on the clean surface. The interactions of water with Ru(100) have been studied using both thermal desorption spectroscopy (TDS) and electron energy loss spectroscopy (EELS). From these studies we conclude that a small amount of water dissociates on this surface (5--10% of a monolayer), but water is adsorbed in a predominantly molecular form on this surface with an increasing degree of hydrogen-bonding with increasing coverage. The effects of hydrogen and oxygen coadsorption on the interactions of water with this surface have also been studied using TDS. Finally, the interactions of coadsorbed water and perfluorodiethyl ether on Ru(100) have been investigated using TDS.

Leavitt, P.

1990-09-21T23:59:59.000Z

84

Chemical Engineering Education150 ChE department  

E-Print Network (OSTI)

Chemical Engineering Education150 ChE department ChE at... The University of Houston C hemical engineering at the Uni- versity of Houston has reflected the growth and diversification of the field: from. The Department of Chemical & Biomolecular Engineering (ChBE) at the University of Houston started as a program

Azevedo, Ricardo

85

Supported Room Temperature Ionic Liquid Membranes for CO{sub 2}/CH{sub 4} Separation  

SciTech Connect

Room temperature ionic liquids (RTILs) are organic salts which are liquid at or around room temperature. These compounds exhibit many outstanding physical properties such as great thermal stability and no measurable vapor pressure. In this work supported ionic liquid membranes (SILMs) were prepared by impregnating pores of ?-alumina inorganic supports with various ionic liquids. In addition to membranes prepared with pure RTILs we were able to synthesize membranes with RTIL mixtures using 1-aminopyridinium iodide dissolved in 1-butyl-4-methylpyridinium tetrafluoroborate or methyltrioctylammonium bis(trifluoromethylsulfonyl)imide. This combination of an RTIL with an organic salt containing an amine group dramatically improved the membrane separation properties. The SILMs displayed CO{sub 2} permeance on the order of 5 10{sup ?10} to 5 10{sup ?9} mol m{sup ?2} s{sup ?1} Pa{sup ?1} combined with CO{sub 2}/CH{sub 4} selectivity of 530. Although these values are comparable with the current systems for CO{sub 2} purification, CO{sub 2} permeance is still rather low for these compounds.

Iarikov, D. D.; Hacarlioglu, P.; Oyama, S. T.

2011-01-01T23:59:59.000Z

86

Comparison Between Dust Particle Generation In CH4 or CH4/N2 Mixing RF Plasmas  

SciTech Connect

Dust particles have been spontaneously generated either in pure CH4 or in CH4/N2 r.f. plasmas. The dust particle formation results from homogeneous nucleation in the plasma and is detected by laser light scattering (Ar+, {lambda} = 514.5 nm). The temporal and spatial behaviour of dust particles is studied. In pure methane gas, particles are trapped in well defined clouds at the plasma sheath boundaries. In a CH4/N2 mixture, the nitrogen addition leads to an expansion of the clouds. For nitrogen contents higher than 50%, the space between the electrodes is nearly completely filled with dust particles leading to plasma instabilities and a void appears in the center of the discharge. The particles are spherical with diameters in the range 0.8-2 {mu}m. For nitrogen-rich plasmas, the particles growth is improved and leads to a rough shape with an orange-peel-type surface texture.

Pereira, Jeremy; Massereau-Guilbaud, Veronique; Geraud-Grenier, Isabelle; Plain, Andre [LASEP, Faculte des Sciences, Universite d'Orleans, Site de Bourges, rue G.Berger, BP 4043, 18028 Bourges Cedex (France)

2005-10-31T23:59:59.000Z

87

Thermodynamics of Hydrogen Production from Dimethyl Ether Steam Reforming and Hydrolysis  

SciTech Connect

The thermodynamic analyses of producing a hydrogen-rich fuel-cell feed from the process of dimethyl ether (DME) steam reforming were investigated as a function of steam-to-carbon ratio (0-4), temperature (100 C-600 C), pressure (1-5 atm), and product species: acetylene, ethanol, methanol, ethylene, methyl-ethyl ether, formaldehyde, formic acid, acetone, n-propanol, ethane and isopropyl alcohol. Results of the thermodynamic processing of dimethyl ether with steam indicate the complete conversion of dimethyl ether to hydrogen, carbon monoxide and carbon dioxide for temperatures greater than 200 C and steam-to-carbon ratios greater than 1.25 at atmospheric pressure (P = 1 atm). Increasing the operating pressure was observed to shift the equilibrium toward the reactants; increasing the pressure from 1 atm to 5 atm decreased the conversion of dimethyl ether from 99.5% to 76.2%. The order of thermodynamically stable products in decreasing mole fraction was methane, ethane, isopropyl alcohol, acetone, n-propanol, ethylene, ethanol, methyl-ethyl ether and methanol--formaldehyde, formic acid, and acetylene were not observed. The optimal processing conditions for dimethyl ether steam reforming occurred at a steam-to-carbon ratio of 1.5, a pressure of 1 atm, and a temperature of 200 C. Modeling the thermodynamics of dimethyl ether hydrolysis (with methanol as the only product considered), the equilibrium conversion of dimethyl ether is limited. The equilibrium conversion was observed to increase with temperature and steam-to-carbon ratio, resulting in a maximum dimethyl ether conversion of approximately 68% at a steam-to-carbon ratio of 4.5 and a processing temperature of 600 C. Thermodynamically, dimethyl ether processed with steam can produce hydrogen-rich fuel-cell feeds--with hydrogen concentrations exceeding 70%. This substantiates dimethyl ether as a viable source of hydrogen for PEM fuel cells.

T.A. Semelsberger

2004-10-01T23:59:59.000Z

88

DIMETHYL ETHER (DME)-FUELED SHUTTLE BUS DEMONSTRATION PROJECT  

DOE Green Energy (OSTI)

The objectives of this research and demonstration program are to convert a campus shuttle bus to operation on dimethyl ether, a potential ultra-clean alternative diesel fuel. To accomplish this objective, this project includes laboratory evaluation of a fuel conversion strategy, as well as field demonstration of the DME-fueled shuttle bus. Since DME is a fuel with no lubricity (i.e., it does not possess the lubricating quality of diesel fuel), conventional fuel delivery and fuel injection systems are not compatible with dimethyl ether. Therefore, to operate a diesel engine on DME one must develop a fuel-tolerant injection system, or find a way to provide the necessary lubricity to the DME. In this project, they have chosen the latter strategy in order to achieve the objective with minimal need to modify the engine. The strategy is to blend DME with diesel fuel, to obtain the necessary lubricity to protect the fuel injection system and to achieve low emissions. Within the Combustion Laboratory of the Penn State Energy Institute, they have installed and equipped a Navistar V-8 direct-injection turbodiesel engine for measurement of gaseous and particulate emissions and examination of the impact of fuel composition on diesel combustion. They have also reconfigured a high-pressure viscometer for studies of the viscosity, bulk modulus (compressibility) and miscibility of blends of diesel fuel, dimethyl ether and lubricity additives. The results include baseline emissions, performance and combustion measurements on the Navistar engine for operation on a federal low sulfur diesel fuel (300 ppm S). Most recently, they have examined blends of an oxygenated fuel additive (a liquid fuel called CETANER{trademark}) produced by Air Products, for comparison with dimethyl ether blended at the same weight of oxygen addition, 2 wt.%. While they have not operated the engine on DME yet, they are now preparing to do so. A fuel system for delivery of DME/Diesel blends has been configured and initial investigations at low DME blend ratios (around 5-10 vol%) will begin shortly. They have also performed viscosity measurements on diesel fuel, DME and 50-50 blends of DME in diesel. These tests have verified that DME has a much lower viscosity than the diesel fuel and that the viscosity of the blended fuel is also much lower than the diesel base fuel. This has implications for the injection and atomization of the DME/diesel blends.

Elana M. Chapman; Shirish Bhide; Andre L. Boehman; David Klinikowski

2003-04-01T23:59:59.000Z

89

Independent Activity Report, CH2M Hill Plateau Remediation Company -  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Independent Activity Report, CH2M Hill Plateau Remediation Company Independent Activity Report, CH2M Hill Plateau Remediation Company - January 2011 Independent Activity Report, CH2M Hill Plateau Remediation Company - January 2011 January 2011 Review of the CH2M Hill Plateau Remediation Company Unreviewed Safety Question Procedure [ARPT-RL-2011-003] The U.S. Department of Energy Office of Independent Oversight, within the Office of Health, Safety and Security, during a site visit from January 10-14, 2011, presented the results of a technical review of the CH2M Hill Plateau Remediation Company (PRC) Unreviewed Safety Question (USQ) Procedure. Independent Activity Report, CH2M Hill Plateau Remediation Company - January 2011 More Documents & Publications CX-009415: Categorical Exclusion Determination Independent Activity Report, Richland Operations Office - January 2011

90

Interactions between Ether Phospholipids and Cholesterol as Determined by Scattering and Molecular Dynamics Simulations  

SciTech Connect

Cholesterol and ether lipids are ubiquitous in mammalian cell membranes, and their interactions are crucial in ether lipid mediated cholesterol trafficking. We report on cholesterol s molecular interactions with ether lipids as determined using a combination of small-angle neutron and Xray scattering, and all-atom molecular dynamics (MD) simulations. A scattering density profile model for an ether lipid bilayer was developed using MD simulations, which was then used to simultaneously fit the different experimental scattering data. From analysis of the data the various bilayer structural parameters were obtained. Surface area constrained MD simulations were also performed to reproduce the experimental data. This iterative analysis approach resulted in good agreement between the experimental and simulated form factors. The molecular interactions taking place between cholesterol and ether lipids were then determined from the validated MD simulations. We found that in ether membranes cholesterol primarily hydrogen bonds with the lipid headgroup phosphate oxygen, while in their ester membrane counterparts cholesterol hydrogen bonds with the backbone ester carbonyls. This different mode of interaction between ether lipids and cholesterol induces cholesterol to reside closer to the bilayer surface, dehydrating the headgroup s phosphate moiety. Moreover, the three-dimensional lipid chain spatial density distribution around cholesterol indicates anisotropic chain packing, causing cholesterol to tilt. These insights lend a better understanding of ether lipid-mediated cholesterol trafficking and the roles that the different lipid species have in determining the structural and dynamical properties of membrane associated biomolecules.

Pan, Jianjun [ORNL; Cheng, Xiaolin [ORNL; Heberle, Frederick A [ORNL; Mostofian, Barmak [ORNL; Kucerka, Norbert [Canadian Neutron Beam Centre and Comelius University (Slovakia); Drazba, Paul [ORNL; Katsaras, John [ORNL

2012-01-01T23:59:59.000Z

91

Dimethyl ether (DME): a clean fuel of the 21st century and catalysts for it  

Science Conference Proceedings (OSTI)

Dimethyl ether (DME) is a substitute of LNG and light oil. DME burns without particulate matters and SOx, so DME is a clean fuel. DME is a storage and carrier of hydrogen. For these usages, useful catalysts such as DME steam reforming catalysts and DME ... Keywords: DME, alumina, catalyst, clean fuel, copper, dimethyl ether, direct synthesis, hydrogen, sol-gel method, steam reforming

Kaoru Takeishi

2009-02-01T23:59:59.000Z

92

Catalysts for hydrogen production by steam reforming of dimethyl ether (DME)  

Science Conference Proceedings (OSTI)

Dimethyl ether (DME) is expected as one of clean fuels. We have been studying on DME steam reforming for hydrogen production. Copper alumina catalysts prepared by a sol-gel method produced large quantities of H2 with DME steam reforming. The reason was ... Keywords: DME, alumina, catalyst, clean fuel, copper, dimethyl ether, hydrogen, sol-gel method, steam reforming

Kaoru Takeishi

2010-02-01T23:59:59.000Z

93

Development of single type copper alumina catalysts for hydrogen production from dimethyl ether (DME)  

Science Conference Proceedings (OSTI)

Dimethyl ether (DME) is expected as one of clean fuels. We have been studying on DME steam reforming for hydrogen production. Copper alumina catalysts prepared by the sol-gel method produced large quantities of H2 with DME steam reforming. Aiming at ... Keywords: DME, alumina, catalyst, clean fuel, copper, dimethyl ether, hydrogen, sol-gel method, steam reforming

Kaoru Takeishi; Atsushi Ban

2010-02-01T23:59:59.000Z

94

High octane ethers from synthesis gas-derived alcohols  

SciTech Connect

The temperature dependence of ether synthesis, particularly unsymmetric methylisobutylether (MIBE), was carried out over the Nafion-H microsaddles (MS) catalyst. The principal product formed under the rather severe reaction conditions of 1100 psig pressure and temperatures in the range of 123--157{degree}C was the expected MIBE formed directly by coupling the methanol/isobutanol reactants. In addition, significantly larger quantities of the dimethylether (DME) and hydrocarbon products were observed than were obtained under milder reaction conditions. Deactivation of the Nafion-H MS catalyst was determined by periodically testing the catalyst under a given set of reaction conditions for the synthesis of MIBE and MTBE from methanol/isobutanol = 2/1, i.e. 123{degree}C, 1100 psig, and total GHSV = 248 mol/kg cat/hr. After carrying out various tests over a period of 2420 hr, with intermittant periods of standing under nitrogen at ambient conditions, the yields of MIBE and MTBE had decreased by 25% and 41%, respectively. In order to gain insight into the role of the surface acidity in promoting the selective coupling of the alcohols to form the unsymmetric ether, the strengths of the acid sites on the catalysts are still being probed by calorimetric titrations in non-aqueous solutions. 11 refs., 13 figs., 9 tabs.

Klier, K.; Herman, R.G.; DeTavernier, S.; Johannson, M.; Kieke, M.; Bastian, R.D.

1991-07-01T23:59:59.000Z

95

CH Packaging Operations for High Wattage Waste at LANL  

Science Conference Proceedings (OSTI)

This procedure provides instructions for assembling the following CH packaging payload: Drum payload assembly Standard Waste Box (SWB) assembly Ten-Drum Overpack (TDOP).

Washington TRU Solutions LLC

2005-04-13T23:59:59.000Z

96

CH Packaging Operations for High Wattage Waste at LANL  

Science Conference Proceedings (OSTI)

This procedure provides instructions for assembling the following CH packaging payload: Drum payload assembly Standard Waste Box (SWB) assembly Ten-Drum Overpack (TDOP).

Washington TRU Solutions LLC

2005-04-04T23:59:59.000Z

97

A CH-type Inequality For Real Experiments  

E-Print Network (OSTI)

We derive an efficient CH-type inequality. Quantum mechanics violates our proposed inequality independent of the detection-efficiency problem.

Afshin Shafiee

2004-01-06T23:59:59.000Z

98

Atmospheric CH4 Concentrations from the CSIRO GASLAB Flask Sampling...  

NLE Websites -- All DOE Office Websites (Extended Search)

CH4 Concentrations from the CSIRO GASLAB Flask Sampling Network image Alert, NWT, Canada Cape Ferguson, Australia Cape Grim, Australia Estevan Point, BC, Canada Macquarie...

99

Comb-shaped single ion conductors based on polyacrylate ethers and lithium  

NLE Websites -- All DOE Office Websites (Extended Search)

Comb-shaped single ion conductors based on polyacrylate ethers and lithium Comb-shaped single ion conductors based on polyacrylate ethers and lithium alkyl sulfonate Title Comb-shaped single ion conductors based on polyacrylate ethers and lithium alkyl sulfonate Publication Type Journal Article Year of Publication 2005 Authors Sun, Xiao-Guang, Jun Hou, and John B. Kerr Journal Electrochimica Acta Volume 50 Pagination 1139-1147 Keywords ionic conductivity, plasticizer, polyacrylate ethers, single ion conductor Abstract Comb-shaped single ion conductors have been synthesized by sulfonation of small molecule chloroethyleneglycols, which, after ion exchange to the Li+ salt were then converted to the acrylate by reaction with acryloyl chloride and copolymerized with polyethylene glycol monomethyl ether acrylate (Mn = 454, n = 8) (PAE8-co-E3SO3Li);

100

CH4 sources estimated from atmospheric observations of CH4 and its C-13/C-12 isotopic ratios: 2. Inverse modeling of CH4 fluxes from geographical regions  

E-Print Network (OSTI)

atmosphere, and CH 4 from fossil fuels such as coal andTermites Biomass burning Fossil Fuels Coal Natural gas andbiomass burning and fossil fuel source processes to the a

Mikaloff Fletcher, S.E.; Tans, P P; Bruhwiler, L M; Miller, J B; Heimann, M

2004-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "butyl ether ch" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Use of a Balloon and N-Butyl-2-Cyanoacrylate for Treatment of Arteriovenous Fistula  

Science Conference Proceedings (OSTI)

We report a patient who developed a large arteriovenous fistula in right lower extremity after gunshot injury. Because other endovascular methods failed, the patient was successfully treated with concomitant use of detachable latex balloon and N-butyl-2-cyanoacrylate (NBCA). The combination of detachable balloon and NBCA can be effectively used for endovascular treatment of peripheral arteriovenous fistulas in selected cases when effective embolization could not be achieved with other embolizing agents or their various combinations.

Doenmez, Halil, E-mail: hdonmez68@yahoo.com; Mavili, Ertugrul [Erciyes University Medical Faculty, Department of Radiology (Turkey); Toker, Birguel; Oztuerk, M. Halil; Soylu, Serra O.; Hekimoglu, Baki [SB Diskapi Yildirim Beyazit Egitim ve Arastirma Hastanesi, Department of Radiology (Turkey)

2008-07-15T23:59:59.000Z

102

Potential energy surfaces for CH bond cleavage reactions  

DOE Green Energy (OSTI)

Ab initio, multi-reference, configuration interaction calculations are reported for CH{sub 4}{leftrightarrow}CH{sub 3}+H, CH{sub 3}F{leftrightarrow}CH{sub 2}F+H, CH{sub 2}F{sub 2}{leftrightarrow}CHF{sub 2}+H, and CHF{sub 3}{leftrightarrow}CF{sub 3}+H. Two equivalent, barrier-less paths are found for the CH{sub 3}+H recombination, two inequivalent, barrier-less paths are found for the CH{sub 2}F+H and CHF{sub 2}+H recombinations (depending on which side of the radical the H atom approaches), and only one barrier-less path is found for the CF{sub 3}+H recombination. Minimum energy path for H atom approaching CF{sub 3} from the concave side is predicted to have a barrier of 27 kcal/mole. Both minimum energy path energies and transitional frequencies as function of R{sub CH} for all 4 reactions are predicted to be similar.

Harding, L.B.

1996-12-31T23:59:59.000Z

103

Comprehensive testing to measure the response of butyl rubber to Hanford tank waste simulant  

Science Conference Proceedings (OSTI)

This report presents the findings of the Chemical Compatibility Program developed to evaluate plastic packaging components that may be incorporated in packaging mixed-waste forms for transportation. Consistent with the methodology outlined in this report, the authors performed the second phase of this experimental program to determine the effects of simulant Hanford tank mixed wastes on packaging seal materials. That effort involved the comprehensive testing of five plastic liner materials in an aqueous mixed-waste simulant. The testing protocol involved exposing the materials to {approximately}143, 286, 571, and 3,670 krad of gamma radiation and was followed by 7-, 14-, 28-, 180-day exposures to the waste simulant at 18, 50, and 60 C. Butyl rubber samples subjected to the same protocol were then evaluated by measuring seven material properties: specific gravity, dimensional changes, mass changes, hardness, compression set, vapor transport rates, and tensile properties. From the analyses, they determined that butyl rubber has relatively good resistance to radiation, this simulant, and a combination of these factors. These results suggest that butyl rubber is a relatively good seal material to withstand aqueous mixed wastes having similar composition to the one used in this study.

NIGREY,PAUL J.

2000-05-01T23:59:59.000Z

104

Quantum ether: photons and electrons from a rotor model  

E-Print Network (OSTI)

We give an example of a purely bosonic model -- a rotor model on the 3D cubic lattice -- whose low energy excitations behave like massless U(1) gauge bosons and massless Dirac fermions. This model can be viewed as a ``quantum ether'': a medium that gives rise to both photons and electrons. It illustrates a general mechanism for the emergence of gauge bosons and fermions known as ``string-net condensation.'' Other, more complex, string-net condensed models can have excitations that behave like gluons, quarks and other particles in the standard model. This suggests that photons, electrons and other elementary particles may have a unified origin: string-net condensation in our vacuum.

Michael Levin; Xiao-Gang Wen

2005-07-13T23:59:59.000Z

105

Electron-Impact Dissociation of CD3+ and CH3+ Ions Producing CD2+, CH+ and C+ Fragment Ions  

Science Conference Proceedings (OSTI)

Using a crossed electron-ion beams method, we measured absolute cross sections for electron-impact dissociation of the CD3+ molecular ions producing CD2+ fragment ions and CH3+ ions yielding CH+ and C+ fragment ions over a collision energy range from a few eV up to 100 eV. The total experimental uncertainties are about 12% at the maximum of the curves of cross sections (peak of the cross section, for the CH+ channel). The obtained results suggest important roles played by pre-dissociation of bound states in the production of both the CH+ and C+ fragment ions. Good agreement is found with other results reported for the CH+ fragment, but some differences are found for the CD2+ and C+.

Bahati Musafiri, Eric [ORNL; Fogle, Jr., Michael R [ORNL; Vane, C Randy [ORNL; Bannister, Mark E [ORNL; Thomas, R. D. [Stockholm University, Stockholm, Sweden; Zhaunerchyk, Vitali [Stockholm University, Stockholm, Sweden

2009-01-01T23:59:59.000Z

106

CH2M HILL Plateau Remediation Company | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

CH2M HILL Plateau Remediation Company CH2M HILL Plateau Remediation Company CH2M HILL Plateau Remediation Company The Office of Hea1th, Safety and Security's Office of Enforcement and Oversight has evaluated the facts and circumstances of a series of radiological work deficiencies at the Plutonium Finishing Plant (PFP) and the 105 K-East Reactor Facility (105KE Reactor) by CH2M HILL Plateau Remediation Company (CHPRC). The radiological work deficiencies at PFP are documented in the April 29, 2011, Department of Energy Richland Operations Office (DOE-RL) Surveillance Report S-11-SED-CHP~C-PFP-002, Planning and Execution of Radiological Work. S-11-SED-CHPRC-PFP-002 documented four examples where inadequate hazard analysis resulted in airborne radioactivity that exceeded the limits of the controlling radiological work permit.

107

A parallel algorithm for computing the spectrum of CH5+  

Science Conference Proceedings (OSTI)

We present a parallelized contracted basis-iterative calculation of vibrational energy levels of CH$_5^+$ (a 12D calculation). We use Radau polyspherical coordinates and basis functions that are products of eigenfunctions of bend and stretch Hamiltonians. ...

Xiao-Gang Wang; Tucker Carrington

2009-06-01T23:59:59.000Z

108

Idaho Cleanup Project CH2M-WG Idaho, LLC | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Idaho Cleanup Project CH2M-WG Idaho, LLC Idaho Cleanup Project CH2M-WG Idaho, LLC Idaho Cleanup Project Idaho Cleanup Project CH2M-WG Idaho, LLC More Documents & Publications...

109

Analysis of the mouse embryonic stem cell regulatory networks obtained by ChIP-chip and ChIP-PET  

E-Print Network (OSTI)

Background: Genome-wide approaches have begun to reveal the transcriptional networks responsible for pluripotency in embryonic stem (ES) cells. Chromatin Immunoprecipitation (ChIP) followed either by hybridization to a ...

Mathur, Divya

110

Seasonal variation of CH4 emissions from central California  

NLE Websites -- All DOE Office Websites (Extended Search)

Seasonal variation of CH4 emissions from central California Seasonal variation of CH4 emissions from central California Title Seasonal variation of CH4 emissions from central California Publication Type Journal Article Year of Publication 2012 Authors Jeong, Seongeun, Chuanfeng Zhao, Arlyn E. Andrews, Laura Bianco, James M. Wilczak, and Marc L. Fischer Journal Journal of Geophysical Research - Atmospheres Volume 117 Issue D11 Keywords atmospheric transport, emission inventory, greenhouse gas, inverse model, methane Abstract We estimate seasonal variations in methane (CH4) emissions from central California from December 2007 through November 2008 by comparing CH4 mixing ratios measured at a tall tower with transport model predictions based on a global 1° a priori CH4emissions map (EDGAR32) and a 10 km seasonally varying California-specific map, calibrated to statewide by CH4emission totals. Atmospheric particle trajectories and surface footprints are computed using the Weather Research and Forecasting and Stochastic Time-Inverted Lagrangian Transport models. Uncertainties due to wind velocity and boundary layer mixing depth are evaluated using measurements from radar wind profilers. CH4signals calculated using the EDGAR32 emission model are larger than those based on the California-specific model and in better agreement with measurements. However, Bayesian inverse analyses using the California-specific and EDGAR32 maps yield comparable annually averaged posterior CH4emissions totaling 1.55 ± 0.24 times and 1.84 ± 0.27 times larger than the California-specific prior emissions, respectively, for a region of central California within approximately 150 km of the tower. If these results are applicable across California, state total CH4 emissions would account for approximately 9% of state total greenhouse gas emissions. Spatial resolution of emissions within the region near the tower reveal seasonality expected from several biogenic sources, but correlations in the posterior errors on emissions from both prior models indicate that the tower footprints do not resolve spatial structure of emissions. This suggests that including additional towers in a measurement network will improve the regional specificity of the posterior estimates.

111

Effect of CH4 and O2 variations on rates of CH4 oxidation and stable isotope fractionation in tropical rain forest soils  

Science Conference Proceedings (OSTI)

Methane-oxidizing bacteria are the primary sink for CH{sub 4} in reduced soils, and account for as much as 90 percent of all CH{sub 4} produced. Methanotrophic bacteria strongly discriminate against the heavy isotopes of carbon, resulting in CH{sub 4} emissions that are significantly more enriched in {sup 13}C than the original source material. Previous studies have used an isotope mass balance approach to quantify CH{sub 4} sources and sinks in the field, based on the assumption that the fractionation factor for CH{sub 4} oxidation is a constant. This study quantifies the effect of systematic variations in CH{sub 4} and O{sub 2} concentrations on rates of CH{sub 4} oxidation and stable isotope fractionation in tropical rain forest soils. Soils were collected from the 0-15 cm depth, and incubated with varying concentrations of CH{sub 4} (100 ppmv, 500 ppmv, 1000 ppmv, and 5000 ppmv) or O{sub 2} (3 percent, 5 percent, 10 percent, and 21 percent). The isotope fractionation factor for CH{sub 4} oxidation was calculated for each incubation using a Rayleigh fractionation model. Rates of CH{sub 4} oxidation varied significantly between CH{sub 4} treatments, with the 100 ppmv CH{sub 4} treatment showing the lowest rate of CH{sub 4} uptake, and the other 3 treatments showing similar rates of CH{sub 4} uptake. Rates of CH{sub 4} oxidation did not vary significantly between the different O{sub 2} treatments. The fractionation factor for CH{sub 4} oxidation varied significantly between the different CH{sub 4} treatments, with the 5000 ppmv CH{sub 4} treatment showing the largest {sup 13}C-enrichment of residual CH{sub 4}. In treatments where CH{sub 4} concentration was not rate-limiting (> 500 ppmv CH{sub 4}), the fractionation factor for CH{sub 4} oxidation was negatively correlated with CH{sub 4} oxidation rate (P activity or CH{sub 4} pool size.

Teh, Yit Arn; Conrad, Mark; Silver, Whendee L.; Carlson, Charlotte M.

2003-10-01T23:59:59.000Z

112

DIMETHYL ETHER (DME)-FUELED SHUTTLE BUS DEMONSTRATION PROJECT  

DOE Green Energy (OSTI)

The objectives of this research and demonstration program are to convert a campus shuttle bus to operation on dimethyl ether, a potential ultra-clean alternative diesel fuel. To accomplish this objective, this project includes laboratory evaluation of a fuel conversion strategy, as well as, field demonstration of the DME-fueled shuttle bus. Since DME is a fuel with no lubricity (i.e., it does not possess the lubricating quality of diesel fuel), conventional fuel delivery and fuel injection systems are not compatible with dimethyl ether. Therefore, to operate a diesel engine on DME one must develop a fuel-tolerant injection system, or find a way to provide the necessary lubricity to the DME. In this project, they have chosen the latter strategy in order to achieve the objective with minimal need to modify the engine. Their strategy is to blend DME with diesel fuel, to obtain the necessary lubricity to protect the fuel injection system and to achieve low emissions. The bulk of the efforts over the past year were focused on the conversion of the campus shuttle bus. This process, started in August 2001, took until April 2002 to complete. The process culminated in an event to celebrate the launching of the shuttle bus on DME-diesel operation on April 19, 2002. The design of the system on the shuttle bus was patterned after the system developed in the engine laboratory, but also was subjected to a rigorous failure modes effects analysis (FMEA, referred to by Air Products as a ''HAZOP'' analysis) with help from Dr. James Hansel of Air Products. The result of this FMEA was the addition of layers of redundancy and over-pressure protection to the system on the shuttle bus. The system became operational in February 2002. Preliminary emissions tests and basic operation of the shuttle bus took place at the Pennsylvania Transportation Institute's test track facility near the University Park airport. After modification and optimization of the system on the bus, operation on the campus shuttle route began in early June 2002. However, the work and challenges continued as it has been difficult to maintain operability of the shuttle bus due to fuel and component difficulties. In late June 2002, the pump head itself developed operational problems (loss of smooth function) leading to excessive stress on the magnetic coupling and excessive current draw to operate. A new pump head was installed on the system to alleviate this problem and the shuttle bus operated successfully on DME blends from 10-25 vol% on the shuttle bus loop until September 30, 2002. During the period of operation on the campus loop, the bus was pulled from service, operated at the PTI test track and real-time emissions measurements were obtained using an on-board emissions analyzer from Clean Air Technologies International, Inc. Particulate emissions reductions of 60% and 80% were observed at DME blend ratios of 12 vol.% and 25 vol.%, respectively, as the bus was operated over the Orange County driving cycle. Increases in NOx, CO and HC emissions were observed, however. In summary, the conversion of the shuttle bus was successfully accomplished, particulate emissions reductions were observed, but there were operational challenges in the field. Nonetheless, they were able to demonstrate reliable operation of the shuttle bus on DME-diesel blends.

Elana M. Chapman; Shirish Bhide; Jennifer Stefanik; Howard Glunt; Andre L. Boehman; Allen Homan; David Klinikowski

2003-04-01T23:59:59.000Z

113

Synthesis of Methanol and Dimethyl Ether from Syngas over Pd/ZnO/Al2O3 Catalysts  

SciTech Connect

A Pd/ZnO/Al2O3 catalyst was developed for the synthesis of methanol and dimethyl ether (DME) from syngas. Studied were temperatures of operation ranging from 250C to 380C. High temperatures (e.g. 380C) are necessary when combining methanol and DME synthesis with a methanol to gasoline (MTG) process in a single reactor bed. A commercial Cu/ZnO/Al2O3 catalyst, utilized industrially for the synthesis of methanol at 220-280C, suffers from a rapid deactivation when the reaction is conducted at high temperature (>320C). On the contrary, a Pd/ZnO/Al2O3 catalyst was found to be highly stable for methanol and DME synthesis at 380C. The Pd/ZnO/Al2O3 catalyst was thus further investigated for methanol and DME synthesis at P=34-69 bars, T= 250-380C, GHSV= 5 000-18 000 h-1, and molar feeds H2/CO= 1, 2, and 3. Selectivity to DME increased with decreasing operating temperature, and increasing operating pressure. Increased GHSVs and H2/CO syngas feed ratios also enhanced DME selectivity. Undesirable CH4 formation was observed, however, can be minimized through choice of process conditions and by catalyst design. By studying the effect of the Pd loading and the Pd:Zn molar ratio the formulation of the Pd/ZnO/Al2O3 catalyst was optimized. A catalyst with 5% Pd and a Pd:Zn molar ratio of 0.25:1 has been identified as the preferred catalyst. Results indicate that PdZn particles are more active than Pd particles for the synthesis of methanol and less active for CH4 formation. A correlation between DME selectivity and the concentration of acid sites of the catalysts has been established. Hence, two types of sites are required for the direct conversion of syngas to DME: 1) PdZn particles are active for the synthesis of methanol from syngas, and 2) acid sites which are active for the conversion of methanol to DME. Additionally, CO2 formation was problematic as PdZn was found to be active for the water-gas-shift (WGS) reaction, under all the conditions evaluated.

Lebarbier, Vanessa MC; Dagle, Robert A.; Kovarik, Libor; Lizarazo Adarme, Jair A.; King, David L.; Palo, Daniel R.

2012-10-01T23:59:59.000Z

114

CH2 Contorhaus Hansestadt Hamburg | Open Energy Information  

Open Energy Info (EERE)

CH2 Contorhaus Hansestadt Hamburg CH2 Contorhaus Hansestadt Hamburg Jump to: navigation, search Name CH2 Contorhaus Hansestadt Hamburg Place Hamburg, Germany Zip 20457 Sector Solar Product Germany-based firm that sets up closed-end funds for investor-capital market products and projects, including solar. Coordinates 53.553345°, 9.992455° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":53.553345,"lon":9.992455,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

115

Independent Oversight Review, Hanford Site CH2M Hill Plateau Remediation Company- November 2012  

Energy.gov (U.S. Department of Energy (DOE))

Review of the Hanford Site CH2M Hill Plateau Remediation Company Implementation Verification Review Processes

116

CH Packaging Operations for High Wattage Waste at LANL  

SciTech Connect

This procedure provides instructions for assembling the following contact-handled (CH) packaging payloads: - Drum payload assembly - Standard Waste Box (SWB) assembly - Ten-Drum Overpack (TDOP) In addition, this procedure also provides operating instructions for the TRUPACT-II CH waste packaging. This document also provides instructions for performing ICV and OCV preshipment leakage rate tests on the following packaging seals, using a nondestructive helium (He) leak test: - ICV upper main O-ring seal - ICV outer vent port plug O-ring seal - OCV upper main O-ring seal - OCV vent port plug O-ring seal.

Washington TRU Solutions LLC

2003-03-21T23:59:59.000Z

117

CH Packaging Operations for High Wattage Waste at LANL  

Science Conference Proceedings (OSTI)

This procedure provides instructions for assembling the following contact-handled (CH) packaging payloads: - Drum payload assembly - Standard Waste Box (SWB) assembly - Ten-Drum Overpack (TDOP) In addition, this procedure also provides operating instructions for the TRUPACT-II CH waste packaging. This document also provides instructions for performing ICV and OCV preshipment leakage rate tests on the following packaging seals, using a nondestructive helium (He) leak test: - ICV upper main O-ring seal - ICV outer vent port plug O-ring seal - OCV upper main O-ring seal - OCV vent port plug O-ring seal.

Washington TRU Solutions LLC

2002-12-18T23:59:59.000Z

118

CH Packaging Operations for High Wattage Waste at LANL  

Science Conference Proceedings (OSTI)

This procedure provides instructions for assembling the following contact-handled (CH) packaging payloads: - Drum payload assembly - Standard Waste Box (SWB) assembly - Ten-Drum Overpack (TDOP) In addition, this procedure also provides operating instructions for the TRUPACT-II CH waste packaging. This document also provides instructions for performing ICV and OCV preshipment leakage rate tests on the following packaging seals, using a nondestructive helium (He) leak test: - ICV upper main O-ring seal - ICV outer vent port plug O-ring seal - OCV upper main O-ring seal - OCV vent port plug O-ring seal.

Washington TRU Solutions LLC

2003-08-28T23:59:59.000Z

119

CH Packaging Operations for High Wattage Waste at LANL  

SciTech Connect

This procedure provides instructions for assembling the following contact-handled (CH) packaging payloads: - Drum payload assembly - Standard Waste Box (SWB) assembly - Ten-Drum Overpack (TDOP) In addition, this procedure also provides operating instructions for the TRUPACT-II CH waste packaging. This document also provides instructions for performing ICV and OCV preshipment leakage rate tests on the following packaging seals, using a nondestructive helium (He) leak test: - ICV upper main O-ring seal - ICV outer vent port plug O-ring seal - OCV upper main O-ring seal - OCV vent port plug O-ring seal.

Washington TRU Solutions LLC

2003-05-06T23:59:59.000Z

120

Twenty-Seventh Symposium (International) on Combustion/The Combustion Institute, 1998/pp. 615623 EXPERIMENTAL AND COMPUTATIONAL STUDY OF CH, CH*, AND OH* IN  

E-Print Network (OSTI)

and modeled. CH* and OH* number densities are deconvoluted from line-of-sight flame-emission mea- surements recognized as a key reactant in NOx formation through the prompt NO mechanism. Given that CH is a short-lived]. Despite the prevalence of CH* and OH* chemiluminescence, little quantitative work has been done either

Long, Marshall B.

Note: This page contains sample records for the topic "butyl ether ch" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Hydrogen Oxidation Catalysis by a Nickel Diphosphine Complex with Pendant tert-Butyl Amines  

DOE Green Energy (OSTI)

A bis-diphosphine nickel complex with t-butyl functionalized pendant amines [Ni(PCy2Nt-Bu2)2]2+ has been synthesized. It is a highly active electrocatalyst for the oxidation of hydrogen in the presence of base. The turn-over rate of 50 s 1 under 1.0 atm H2 at a potential of 0.77 V vs the ferrocene couple is 5 times faster than the rate reported heretofore for any other molecular H2 oxidation catalyst. This research was supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the US Department of Energy, Office of Science, Office of Basic Energy Sciences. Pacific Northwest National Laboratory is operated by Battelle for the US Department of Energy. Computational resources were provided by the Environmental Molecular Science Laboratory (EMSL) and the National Energy Research Scientific Computing Center (NERSC) at Lawrence Berkeley National Laboratory.

Yang, Jenny Y.; Chen, Shentan; Dougherty, William G.; Kassel, W. S.; Bullock, R. Morris; DuBois, Daniel L.; Raugei, Simone; Rousseau, Roger J.; Dupuis, Michel; Rakowski DuBois, Mary

2010-11-09T23:59:59.000Z

122

People's Physics Book Ch13-1 The Big Ideas  

E-Print Network (OSTI)

to the mismatched frame rates of the camera and TV screen.) Electrical current coming out of your plug is an examplePeople's Physics Book Ch13-1 The Big Ideas: The name electric current is given to the phenomenon that occurs when an electric field moves down a wire at close to the speed of light. Voltage is the electrical

California at Santa Cruz, University of

123

Ch.2 Solar Energy to Earth and the Seasons  

E-Print Network (OSTI)

Ch.2 Solar Energy to Earth and the Seasons #12;Learning Objective One: The Solar System Sun Earth,083,000 km #12;Learning Objective Two: The Solar Energy Solar Radiation #12;What is Solar Energy? Energy is the capacity of a physical system to do work. The unit is Joule (J). Solar energy is radiant energy (i

Pan, Feifei

124

People's Physics book Ch 2-1 The Big Idea  

E-Print Network (OSTI)

People's Physics book Ch 2-1 The Big Idea Energy is a measure of the amount of, or potential for, dynamical activity in something. The total amount of energy in the universe is always the same universe. A group of things (we'll use the word system) has a certain amount of energy. Energy can be added

California at Santa Cruz, University of

125

Ch.2 Solar Energy to Earth and the Seasons  

E-Print Network (OSTI)

? Pairs of hydrogen nuclei are joined, form helium, and emit large amount of energy. Solar energy-Output Energy=Storage Change #12;Learning Objective Four: The Seasons #12;The Seasons SeasonalityCh.2 Solar Energy to Earth and the Seasons #12;Learning Objective One: The Solar System #12;Milky

Pan, Feifei

126

HIGH-RESOLUTION CH OBSERVATIONS OF TWO TRANSLUCENT MOLECULAR CLOUDS  

SciTech Connect

We present high-resolution (1.'3 x 1.'6) observations of the CH {sup 2}{pi}{sub 1/2} (F = 1-1) emission line at 3335 MHz in two high-latitude translucent clouds, MBM 3 and 40. At the assumed cloud distances, the angular resolution corresponds to {approx}0.05 pc, nearly an order of magnitude better than previous studies. Comparisons of the CH emission with previously obtained CO(1-0) data are difficult to interpret: the CO and CH line emission correlates in MBM 40 but not in MBM 3. In both clouds, there is a spatial offset in the peak emission, and perhaps in velocity for MBM 40. The difference in emission characteristics for the two tracers are noticeable in these two nearby clouds because of the high spatial resolution. Since both CH and CO are deemed to be reliable tracers of H{sub 2}, our results indicate that more care should be taken when using one of these tracers to determine the mass of a nearby molecular cloud.

Chastain, Raymond J. [Department of Physics and Astronomy, Louisiana State University, 368 Nicholson Hall, Tower Dr. Baton Rouge, LA 70803 (United States); Cotten, David; Magnani, Loris [Department of Physics and Astronomy, University of Georgia, Athens, GA 30602 (United States)

2010-01-15T23:59:59.000Z

127

Effect of CH4 and O2 variations on rates of CH4 oxidation and stable isotope fractionation in tropical rain forest soils  

SciTech Connect

Methane-oxidizing bacteria are the primary sink for CH{sub 4} in reduced soils, and account for as much as 90 percent of all CH{sub 4} produced. Methanotrophic bacteria strongly discriminate against the heavy isotopes of carbon, resulting in CH{sub 4} emissions that are significantly more enriched in {sup 13}C than the original source material. Previous studies have used an isotope mass balance approach to quantify CH{sub 4} sources and sinks in the field, based on the assumption that the fractionation factor for CH{sub 4} oxidation is a constant. This study quantifies the effect of systematic variations in CH{sub 4} and O{sub 2} concentrations on rates of CH{sub 4} oxidation and stable isotope fractionation in tropical rain forest soils. Soils were collected from the 0-15 cm depth, and incubated with varying concentrations of CH{sub 4} (100 ppmv, 500 ppmv, 1000 ppmv, and 5000 ppmv) or O{sub 2} (3 percent, 5 percent, 10 percent, and 21 percent). The isotope fractionation factor for CH{sub 4} oxidation was calculated for each incubation using a Rayleigh fractionation model. Rates of CH{sub 4} oxidation varied significantly between CH{sub 4} treatments, with the 100 ppmv CH{sub 4} treatment showing the lowest rate of CH{sub 4} uptake, and the other 3 treatments showing similar rates of CH{sub 4} uptake. Rates of CH{sub 4} oxidation did not vary significantly between the different O{sub 2} treatments. The fractionation factor for CH{sub 4} oxidation varied significantly between the different CH{sub 4} treatments, with the 5000 ppmv CH{sub 4} treatment showing the largest {sup 13}C-enrichment of residual CH{sub 4}. In treatments where CH{sub 4} concentration was not rate-limiting (> 500 ppmv CH{sub 4}), the fractionation factor for CH{sub 4} oxidation was negatively correlated with CH{sub 4} oxidation rate (P < 0.003, r{sup 2} = 0.86). A multiple regression model that included initial CH{sub 4} concentration and CH{sub 4} oxidation rate as independent variables accounted for 94 percent of the variability in the isotope fractionation data, suggesting that both factors are important in determining the extent of isotopic fractionation (P < 0.002, r{sup 2} = 0.94). The fractionation factor for CH{sub 4} oxidation did not vary significantly between the different O{sub 2} treatments. These results challenge the assumption that the isotope fractionation factor for CH{sub 4} oxidation remains constant, regardless of metabolic activity or CH{sub 4} pool size.

Teh, Yit Arn; Conrad, Mark; Silver, Whendee L.; Carlson, Charlotte M.

2003-10-01T23:59:59.000Z

128

Lithium Hexamethyldisilazide-Mediated Ketone Enolization: The Influence of Hindered Dialkyl Ethers and Isostructural  

E-Print Network (OSTI)

Lithium Hexamethyldisilazide-Mediated Ketone Enolization: The Influence of Hindered Dialkyl Ethers of the enolization of 2-methylcyclohexanone mediated by lithium hexameth- yldisilazide (LiHMDS; TMS2NLi) solvated- bine to make lithium hexamethyldisilazide (LiHMDS) one of the most important Bro¨nsted bases in organic

Collum, David B.

129

Direct synthesis of dimethyl ether (DME) from syngas containing oxygen gas considering of biomass gasfication gas  

Science Conference Proceedings (OSTI)

We have developed appropriate and excellent catalysts for direct DME synthesis from syngas. The catalysts, Cu-Zn/Al2O3 catalysts prepared by the sol-gel method, produce DME with high DME activity and high DME selectivity with long ... Keywords: DME, biomass, catalyst, clean fuel, dimethyl ether, direct synthesis, gasification gas, hydrogen, sol-gel method, syngas

Kaoru Takeishi; Akane Arase

2010-02-01T23:59:59.000Z

130

DE-AC02-09CH11466  

NLE Websites -- All DOE Office Websites (Extended Search)

2-09CH11466 2-09CH11466 copies of the amendment; (b) By acknowledging receipt of this amendment on each copy of the offer submitted; or (c) By separate letter or telegram which includes a reference to the solicitation and amendment numbers. FAILURE OF YOUR ACKNOWLEDGEMENT TO BE RECEIVED AT THE PLACE DESIGNATED FOR THE RECEIPT OF OFFERS PRIOR TO THE HOUR AND DATE SPECIFIED MAY RESULT IN REJECTION OF YOUR OFFER. If by virtue of this amendment you desire to change an offer already submitted, such change may be made by telegram or letter, provided each telegram or letter makes reference to the solicitation and this amendment, and is received prior to the opening hour and date specified. Word Modification PRINCETON NJ 085442020 002484665 TRUSTEES OF PRINCETON UNIVERSITY, THE

131

Assessment of ether and alcohol fuels from coal. Volume 2. Technical report  

DOE Green Energy (OSTI)

A unique route for the indirect liquefaction of coal to produce transportation fuel has been evaluated. The resultant fuel includes alkyl tertiary alkyl ethers and higher alcohols, all in the gasoline boiling range. When blended into gasoline, the ether fuel provides several advantages over the lower alcohols: (1) lower chemical oxygen content, (2) less-severe water-separation problems, and (3) reduced front-end volatility effects. The ether fuel also has high-octane quality. Further, it can be utilized as a gasoline substitute in all proportions. Production of ether fuel combines several steps, all of which are or have been practiced on an industrial scale: (1) coal gasification, (2) gas cleanup and shift to desired H/sub 2/:CO ratio, (3) conversion of synthesis gas to isobutanol, methanol, and higher alcohols, (4) separation of alcohols, (5) chemical dehydration of isobutanol to isobutylene, and (6) etherification of isobutylene with methanol. A pilot-plant investigation of the isobutanol synthesis step was performed. Estimates of ether-fuel manufacturing costs indicate this process route is significantly more costly than synthesis of methanol. However, the fuel performance features provide incentive for developing the necessary process and catalyst improvements. Co-production of higher-molecular-weight co-solvent alcohols represents a less-drastic form of methanol modification to achieve improvement in the performance of methanol-gasoline blends. Costs were estimated for producing several proportions of methanol plus higher alcohols from coal. Estimated fuel selling price increases regularly but modestly with higher alcohol content.

Not Available

1983-03-01T23:59:59.000Z

132

Method for photochemical reduction of uranyl nitrate by tri-N-butyl phosphate and application of this method to nuclear fuel reprocessing  

DOE Patents (OSTI)

Uranyl ion in solution in tri-n-butyl phosphate is readily photochemically reduced to U(IV). The product U(IV) may effectively be used in the Purex process for treating spent nuclear fuels to reduce Pu(IV) to Pu(III). The Pu(III) is readily separated from uranium in solution in the tri-n-butyl phosphate by an aqueous strip.

De Poorter, Gerald L. (Los Alamos, NM); Rofer-De Poorter, Cheryl K. (Los Alamos, NM)

1978-01-01T23:59:59.000Z

133

DOE Selects CH2M Hill Plateau Remediation Company for Plateau...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

CH2M Hill Plateau Remediation Company for Plateau Remediation Contract at its Hanford Site DOE Selects CH2M Hill Plateau Remediation Company for Plateau Remediation Contract at its...

134

Enforcement Letter, CH2M Hill Mound, Inc - December 22, 2004...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Letter, CH2M Hill Mound, Inc - December 22, 2004 December 22, 2004 Issued to CH2M Hill Mound, Inc. related to a Radioactive Contamination Event during Remediation Activities at...

135

Salinity-induced hydrate dissociation: A mechanism for recent CH4 release on Mars  

SciTech Connect

Recent observations of CH4 in the Martian atmosphere suggest that CH4 has been added relatively recently. Several mechanisms for recent CH4 release have been proposed including subsurface biological methanogenesis, abiogenic hydrothermal and/or volcanic activity, dissociation of CH4 hydrates, atmospheric photolysis, or addition of organics via bolide impact. This study examines the effects of increasing salinity on gas hydrate stability and compares estimates of the Martian geothermal gradient to CH4 and CO2 hydrate stability fields in the presence of high salinity brines. The results demonstrate that salinity increases alone result in a significant decrease in the predicted hydrate stability zone within the Martian subsurface and may be a driving force in CH4 hydrate destabilization. Active thermal and/or pressure fluctuations are not required in order for CH4 hydrates to be the source of atmospheric CH4.

Madden, Megan Elwood [ORNL; Ulrich, Shannon M [ORNL; Onstott, Tullis [Princeton University; Phelps, Tommy Joe [ORNL

2007-01-01T23:59:59.000Z

136

Special Report Order, Issued to CH2M Hill Hanford Group, Inc.- October 22, 2001  

Energy.gov (U.S. Department of Energy (DOE))

Issued to CH2M Hill Hanford Group, Inc., related to Multiple Nuclear Safety Issues at the Hanford Site

137

Molecular Dynamics Simulation of Tri-n-Butyl-Phophate Liquid: A Force Field Comparative Study  

SciTech Connect

Molecular dynamics (MD) simulations were conducted to compare the performance of four force fields in predicting thermophysical properties of tri-n-butyl-phosphate (TBP) in the liquid phase. The intramolecular force parameters used were from the Assisted Model Building with Energy Refinement (AMBER) force field model. The van der Waals parameters were based on either the AMBER or the Optimized Potential for Liquid Simulation (OPLS) force fields. The atomic partial charges were either assigned by performing quantum chemistry calculations or utilized previously published data, and were scaled to approximate the average experimental value of the electric dipole moment. Canonical ensemble computations based on the aforementioned parameters were performed near the atmospheric pressure and temperature to obtain the electric dipole moment, mass density, and self-diffusion coefficient. In addition, the microscopic structure of the liquid was characterized via pair correlation functions between selected atoms. It has been demonstrated that the electric dipole moment can be approximated within 1% of the average experimental value by virtue of scaled atomic partial charges. The liquid mass density can be predicted within 0.5-1% of its experimentally determined value when using the corresponding charge scaling. However, in all cases the predicted self- diffusion coefficient is significantly smaller than a commonly quoted experimental measurement; this result is qualified by the fact that the uncertainty of the experimental value was not available.

Cui, Shengting [ORNL; de Almeida, Valmor F [ORNL; Hay, Benjamin [ORNL; Ye, Xianggui [ORNL; Khomami, Bamin [ORNL

2012-01-01T23:59:59.000Z

138

Initiation Temperature for Runaway Tri-n-Butyl Phosphate/Nitric Acid Reaction  

Science Conference Proceedings (OSTI)

During a review of the H-Canyon authorization basis, Defense Nuclear Facility Safety Board (DNFSB) staff members questioned the margin of safety associated with a postulated tri-n-butyl phosphate (TBP)/nitric acid runaway reaction due to the inadvertent heating of a canyon tank containing greater than 3000 lbs (1362 kg) of TBP. The margin of safety was partially based on experiments and calculations performed by the Actinide Technology Section (ATS) to support deletion of indication of tank agitation as a Safety Class System. In the technical basis for deletion of this system, ATS personnel conservatively calculated the equilibrium temperature distribution of a canyon tank containing TBP and nitric acid layers which were inadvertently heated by a steam jet left on following a transfer. The maximum calculated temperature (128 degrees C) was compared to the minimum initiation temperature for a runaway reaction (greater than 130 degrees C) documented by experimental work in the mid 195 0s. In this work, the initiation temperature as a function of nitric acid concentration was measured for 0 and 20 wt percent dissolved solids. The DNFSB staff members were concerned that data for 0 wt percent dissolved solids were not conservative given the facts that data for 20 wt percent dissolved solids show initiation temperatures at or below 130 degrees C and H-Canyon solutions normally contained a small amount of dissolved solids.

Rudisill, T.S.

2000-11-28T23:59:59.000Z

139

Efficiency of formation of CH{sub 3}O in the reaction of CH{sub 3}O{sub 2} with ClO  

SciTech Connect

Employing a discharge-flow apparatus the authors measure the branching ratio for the reaction of ClO with CH{sub 3}O{sub 2} to the formation of CH{sub 3}O. The CH{sub 3}O{sub 2} is formed in the stratosphere from the reaction of Cl with CH{sub 4}. This branching ratio is of interest to determine if a chain of reactions through it could be a contributor to the stratospheric decomposition of ozone.

Biggs, P.; Canosa-Mas, C.E.; Frachebound, J.M. [Physical Chemistry Laboratory, Oxford (United Kingdom)] [Physical Chemistry Laboratory, Oxford (United Kingdom)

1995-05-15T23:59:59.000Z

140

Methanogenic Conversion of CO2 Into CH4  

SciTech Connect

This SBIR project evaluated the potential to remediate geologic CO2 sequestration sites into useful methane gas fields by application of methanogenic bacteria. Such methanogens are present in a wide variety of natural environments, converting CO2 into CH4 under natural conditions. We conclude that the process is generally feasible to apply within many of the proposed CO2 storage reservoir settings. However, extensive further basic R&D still is needed to define the precise species, environments, nutrient growth accelerants, and economics of the methanogenic process. Consequently, the study team does not recommend Phase III commercial application of the technology at this early phase.

Stevens, S.H., Ferry, J.G., Schoell, M.

2012-05-06T23:59:59.000Z

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141

Process to convert biomass and refuse derived fuel to ethers and/or alcohols  

DOE Patents (OSTI)

A process for conversion of a feedstock selected from the group consisting of biomass and refuse derived fuel (RDF) to provide reformulated gasoline components comprising a substantial amount of materials selected from the group consisting of ethers, alcohols, or mixtures thereof, comprising: drying said feedstock; subjecting said dried feedstock to fast pyrolysis using a vortex reactor or other means; catalytically cracking vapors resulting from said pyrolysis using a zeolite catalyst; condensing any aromatic byproduct fraction; catalytically alkylating any benzene present in said vapors after condensation; catalytically oligomerizing any remaining ethylene and propylene to higher olefins; isomerizing said olefins to reactive iso-olefins; and catalytically reacting said iso-olefins with an alcohol to form ethers or with water to form alcohols.

Diebold, James P. (Lakewood, CO); Scahill, John W. (Evergreen, CO); Chum, Helena L. (Arvada, CO); Evans, Robert J. (Lakewood, CO); Rejai, Bahman (Lakewood, CO); Bain, Richard L. (Golden, CO); Overend, Ralph P. (Lakewood, CO)

1996-01-01T23:59:59.000Z

142

Process to convert biomass and refuse derived fuel to ethers and/or alcohols  

DOE Patents (OSTI)

A process is described for conversion of a feedstock selected from the group consisting of biomass and refuse derived fuel (RDF) to provide reformulated gasoline components comprising a substantial amount of materials selected from the group consisting of ethers, alcohols, or mixtures thereof, comprising: drying said feedstock; subjecting said dried feedstock to fast pyrolysis using a vortex reactor or other means; catalytically cracking vapors resulting from said pyrolysis using a zeolite catalyst; condensing any aromatic byproduct fraction; catalytically alkylating any benzene present in said vapors after condensation; catalytically oligomerizing any remaining ethylene and propylene to higher olefins; isomerizing said olefins to reactive iso-olefins; and catalytically reacting said iso-olefins with an alcohol to form ethers or with water to form alcohols. 35 figs.

Diebold, J.P.; Scahill, J.W.; Chum, H.L.; Evans, R.J.; Rejai, B.; Bain, R.L.; Overend, R.P.

1996-04-02T23:59:59.000Z

143

Modeling the Nanophase Structural Dynamics of Phenylated Sulfonated Poly Ether Ether Ketone Ketone (Ph-SPEEKK) Membranes as a Function of Hydration  

DOE Green Energy (OSTI)

Solvated phenylated sulfonated poly ether ether ketone ketone (Ph-SPEEKK) membranes in the presence of hydronium ions were modeled by classical molecular dynamics simulations. The characterization of the nanophase structure and dynamics of such membranes was carried out as a function of the water content lambda, where lambda is the number of water molecules per sulfonate group, for lambda values of 3.5, 6, 11, 25, and 40. Analysis of pair correlation functions supports the experimental observation of membrane swelling upon hydration as well the increase in water and hydronium ion diffusion with increasing lambda. While the average number of hydrogen bonds between hydronium ions and sulfonate groups is dramatically affected by the hydration level, the average lifetime of the hydrogen bonds remains essentially constant. The membrane is found to be relatively rigid and its overall flexibility shows little dependence on water content. Compared to Nafion, water and ion diffusion coefficients are considerably smaller at lower hydration levels and room temperature. However, at higher lambda values of 25 and 40 these coefficients are comparable to those in Nafion at a lambda value of 16. This study also shows that water diffusion in Ph-SPEEKK membranes at low hydration levels can be significantly improved by raising the temperature with important implications for proton conductivity.

Lins, Roberto D.; Devanathan, Ramaswami; Dupuis, Michel

2011-03-03T23:59:59.000Z

144

2' and 3' Carboranyl uridines and their diethyl ether adducts  

DOE Patents (OSTI)

There is disclosed a process for preparing carboranyl uridine nucleoside compounds and their diethyl ether adducts, which exhibit a tenfold increase in boron content over prior art boron containing nucleoside compounds. Said carboranyl uridine nucleoside compounds exhibit enhanced lipophilicity and hydrophilic properties adequate to enable solvation in aqueous media for subsequent incorporation of said compounds in methods for boron neutron capture therapy in mammalian tumor cells.

Soloway, Albert H. (Worthington, OH); Barth, Rolf F. (Columbus, OH); Anisuzzaman, Abul K. (Columbus, OH); Alam, Fazlul (Anaheim, CA); Tjarks, Werner (Columbus, OH)

1992-01-01T23:59:59.000Z

145

2[prime] and 3[prime] Carboranyl uridines and their diethyl ether adducts  

DOE Patents (OSTI)

A process is described for preparing carboranyl uridine nucleoside compounds and their diethyl ether adducts, which exhibit a tenfold increase in boron content over prior art boron containing nucleoside compounds. The carboranyl uridine nucleoside compounds exhibit enhanced lipophilicity and hydrophilic properties adequate to enable solvation in aqueous media for subsequent incorporation of the compounds in methods for boron neutron capture therapy in mammalian tumor cells. No Drawings

Soloway, A.H.; Barth, R.F.; Anisuzzaman, A.K.; Alam, F.; Tjarks, W.

1992-12-15T23:59:59.000Z

146

Butyl benzyl phthalate suppresses the ATP-induced cell proliferation in human osteosarcoma HOS cells  

Science Conference Proceedings (OSTI)

Butyl benzyl phthalate (BBP), an endocrine disruptor present in the environment, exerts its genomic effects via intracellular steroid receptors and elicits non-genomic effects by interfering with membrane ion-channel receptors. We previously found that BBP blocks the calcium signaling coupled with P2X receptors in PC12 cells (Liu and Chen, 2006). Osteoblast P2X receptors were recently reported to play a role in cell proliferation and bone remodeling. In this present study, the effects of BBP on ATP-induced responses were investigated in human osteosarcoma HOS cells. These receptors mRNA had been detected, named P2X4, P2X7, P2Y2, P2Y4, P2Y5, P2Y9, and P2Y11, in human osteosarcoma HOS cells by RT-PCR. The enhancement of cell proliferation and the decrease of cytoviability had both been shown to be coupled to stimulation via different concentrations of ATP. BBP suppressed the ATP-induced calcium influx (mainly coupled with P2X) and cell proliferation but not the ATP-induced intracellular calcium release (mainly coupled with P2Y) and cytotoxicity in human osteosarcoma HOS cells. Suramin, a common P2 receptor's antagonist, blocked the ATP-induced calcium signaling, cell proliferation, and cytotoxicity. We suggest that P2X is mainly responsible for cell proliferation, and P2Y might be partially responsible for the observed cytotoxicity. BBP suppressed the calcium signaling coupled with P2X, suppressing cell proliferation. Since the importance of P2X receptors during bone metastasis has recently become apparent, the possible toxic risk of environmental BBP during bone remodeling is a public problem of concern.

Liu, P.-S., E-mail: pslediting@mail.scu.edu.t [Department of Microbiology, Soochow University, Shihlin, Taipei, Taiwan (China); Chen, C.-Y. [Department of Microbiology, Soochow University, Shihlin, Taipei, Taiwan (China)

2010-05-01T23:59:59.000Z

147

Test Plan: WIPP bin-scale CH TRU waste tests  

SciTech Connect

This WIPP Bin-Scale CH TRU Waste Test program described herein will provide relevant composition and kinetic rate data on gas generation and consumption resulting from TRU waste degradation, as impacted by synergistic interactions due to multiple degradation modes, waste form preparation, long-term repository environmental effects, engineered barrier materials, and, possibly, engineered modifications to be developed. Similar data on waste-brine leachate compositions and potentially hazardous volatile organic compounds released by the wastes will also be provided. The quantitative data output from these tests and associated technical expertise are required by the WIPP Performance Assessment (PA) program studies, and for the scientific benefit of the overall WIPP project. This Test Plan describes the necessary scientific and technical aspects, justifications, and rational for successfully initiating and conducting the WIPP Bin-Scale CH TRU Waste Test program. This Test Plan is the controlling scientific design definition and overall requirements document for this WIPP in situ test, as defined by Sandia National Laboratories (SNL), scientific advisor to the US Department of Energy, WIPP Project Office (DOE/WPO). 55 refs., 16 figs., 19 tabs.

Molecke, M.A.

1990-08-01T23:59:59.000Z

148

ChEAS Data: The Chequamegon Ecosystem Atmosphere Study  

DOE Data Explorer (OSTI)

The ChEAS flux towers participate in AmeriFlux, and the region is an EOS-validation site. The WLEF tower is a NOAA-CMDL CO2 sampling site. ChEAS sites are primarily located within or near the Chequamegon-Nicolet National Forest in northern Wisconsin, with one site in the Ottawa National Forest in the upper peninsula of Michigan. Current studies observe forest/atmosphere exchange of carbon dioxide at canopy and regional scales, forest floor respiration, photosynthesis and transpiration at the leaf level and use models to scale to canopy and regional levels. EOS-validation studies quantitatively assess the land cover of the area using remote sensing and conduct extensive ground truthing of new remote sensing data (i.e. ASTER and MODIS). Atmospheric remote sensing work is aimed at understanding atmospheric boundary layer dynamics, the role of entrainment in regulating the carbon dioxide mixing ratio profiles through the lower troposphere, and feedback between boundary layer dynamics and vegetation (especially via the hydrologic cycle). Airborne studies have included include balloon, kite and aircraft observations of the CO2 profile in the troposphere.

Davis, Kenneth J. [Penn State

149

ChIP-seq Identification of Weakly Conserved Heart Enhancers  

SciTech Connect

Accurate control of tissue-specific gene expression plays a pivotal role in heart development, but few cardiac transcriptional enhancers have thus far been identified. Extreme non-coding sequence conservation successfully predicts enhancers active in many tissues, but fails to identify substantial numbers of heart enhancers. Here we used ChIP-seq with the enhancer-associated protein p300 from mouse embryonic day 11.5 heart tissue to identify over three thousand candidate heart enhancers genome-wide. Compared to other tissues studied at this time-point, most candidate heart enhancers are less deeply conserved in vertebrate evolution. Nevertheless, the testing of 130 candidate regions in a transgenic mouse assay revealed that most of them reproducibly function as enhancers active in the heart, irrespective of their degree of evolutionary constraint. These results provide evidence for a large population of poorly conserved heart enhancers and suggest that the evolutionary constraint of embryonic enhancers can vary depending on tissue type.

Blow, Matthew J.; McCulley, David J.; Li, Zirong; Zhang, Tao; Akiyama, Jennifer A.; Holt, Amy; Plajzer-Frick, Ingrid; Shoukry, Malak; Wright, Crystal; Chen, Feng; Afzal, Veena; Bristow, James; Ren, Bing; Black, Brian L.; Rubin, Edward M.; Visel, Axel; Pennacchio, Len A.

2010-07-01T23:59:59.000Z

150

Thermal desorption of CH4 retained in CO2 ice  

E-Print Network (OSTI)

CO2 ices are known to exist in different astrophysical environments. In spite of this, its physical properties (structure, density, refractive index) have not been as widely studied as those of water ice. It would be of great value to study the adsorption properties of this ice in conditions related to astrophysical environments. In this paper, we explore the possibility that CO2 traps relevant molecules in astrophysical environments at temperatures higher than expected from their characteristic sublimation point. To fulfil this aim we have carried out desorption experiments under High Vacuum conditions based on a Quartz Crystal Microbalance and additionally monitored with a Quadrupole Mass Spectrometer. From our results, the presence of CH4 in the solid phase above the sublimation temperature in some astrophysical scenarios could be explained by the presence of several retaining mechanisms related to the structure of CO2 ice.

R. Luna; C. Millan; M. Domingo; M. A. Satorre

2008-01-21T23:59:59.000Z

151

U.S. Department of Energy, Richland Operations Office And CH2M HILL Plateau  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

CH2M HILL CH2M HILL Plateau Remediation Company Partnering Charter For Partnering Performance Agreement U.S. Department of Energy, Richland Operations Office And CH2M HILL Plateau Remediation Company Partnering Charter For Partnering Performance Agreement The U.S. Department of Energy (DOE) Richland Operations Office (DOE-RL) and CH2M HILL Plateau Remediation Company (CHPRC) are committed to continuous improvement and will utilize principles of the DOE Environmental Management (DOE-EM) Partnering Policy to enhance teaming to further execute the Plateau Remediation Contract. U.S. Department of Energy, Richland Operations Office And CH2M HILL Plateau Remediation Company Partnering Charter For Partnering Performance Agreement More Documents & Publications CH2M HILL Plateau Remediation Company

152

Department of Justice: CH2M Hill Hanford Group Inc. Admits Criminal  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Department of Justice: CH2M Hill Hanford Group Inc. Admits Criminal Department of Justice: CH2M Hill Hanford Group Inc. Admits Criminal Conduct, Parent Company Agrees to Cooperate in Ongoing Investigation and Pay $18.5 Million to Resolve Civil and Criminal Allegations Department of Justice: CH2M Hill Hanford Group Inc. Admits Criminal Conduct, Parent Company Agrees to Cooperate in Ongoing Investigation and Pay $18.5 Million to Resolve Civil and Criminal Allegations March 7, 2013 - 12:00pm Addthis The Justice Department, in conjunction with the U.S. Attorney's Office for the Eastern District of Washington, announced today that Colorado-based CH2M Hill Hanford Group Inc. (CHG) and its parent company, CH2M Hill Companies Ltd. (CH2M Hill) have agreed that CHG committed federal criminal violations, defrauding the public by engaging in years of widespread time

153

DOE Selects CH2M Hill Plateau Remediation Company for Plateau Remediation  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

CH2M Hill Plateau Remediation Company for Plateau CH2M Hill Plateau Remediation Company for Plateau Remediation Contract at its Hanford Site DOE Selects CH2M Hill Plateau Remediation Company for Plateau Remediation Contract at its Hanford Site June 19, 2008 - 1:29pm Addthis WASHINGTON, DC - The U.S. Department of Energy (DOE) today announced that CH2M Hill Plateau Remediation Company has been selected as the plateau remediation contractor for DOE's Hanford Site in southeastern Washington State. The contract is a cost-plus award-fee contract valued at approximately $4.5 billion over ten years (a five-year base period with the option to extend it for another five years). CH2M Hill Plateau Remediation Company is a limited liability company formed by CH2M Hill Constructors, Inc. The team also includes AREVA Federal

154

Technical Standards, DOE-HDBK-1145-2001 (CH-1)- December 08, 2006  

Energy.gov (U.S. Department of Energy (DOE))

DOE-HDBK-1145-2001 (CH-1): Radiological Safety Training for Plutonium Facilities; Replaced by DOE-HDBK-1145-2008

155

TransCom model simulations of CH? and related species: linking transport, surface flux and chemical loss with CH? variability in the troposphere and lower stratosphere  

E-Print Network (OSTI)

A chemistry-transport model (CTM) intercomparison experiment (TransCom-CH?) has been designed to investigate the roles of surface emissions, transport and chemical loss in simulating the global methane distribution. Model ...

Patra, P. K.

156

The large-scale ionised outflow of CH Cygni  

E-Print Network (OSTI)

HST and ground-based [OII} and [NII] images obtained from 1996 to 1999 reveal the existence of a ionised optical nebula around the symbiotic binary CH Cyg extending out to 5000 A.U. from the central stars. The observed velocity range of the nebula, derived from long-slit echelle spectra, is of 130 km/s. In spite of its complex appearence, the velocity data show that the basic morphology of the inner regions of the optical nebula is that of a bipolar (or conical) outflow extending nearly along the plane of the sky out to some 2000 A.U. from the centre. Even if the extension of this bipolar outflow and its position angle are consistent with those of the radio jet produced in 1984 (extrapolated to the time of our optical imagery), no obvious counterpart is visible of the original, dense radio bullets ejected by the system. We speculate that the optical bipolar outflow might be the remannt of the interaction of the bullets with a relatively dense circumstellar medium.

Corradi, R L M; Livio, M; Mampaso, A; Gonalves, D R; Schwarz, H E; Corradi, Romano L.M.; Munari, Ulisse; Livio, Mario; Mampaso, Antonio; Goncalves, Denise R.

2001-01-01T23:59:59.000Z

157

The large-scale ionised outflow of CH Cygni  

E-Print Network (OSTI)

HST and ground-based [OII} and [NII] images obtained from 1996 to 1999 reveal the existence of a ionised optical nebula around the symbiotic binary CH Cyg extending out to 5000 A.U. from the central stars. The observed velocity range of the nebula, derived from long-slit echelle spectra, is of 130 km/s. In spite of its complex appearence, the velocity data show that the basic morphology of the inner regions of the optical nebula is that of a bipolar (or conical) outflow extending nearly along the plane of the sky out to some 2000 A.U. from the centre. Even if the extension of this bipolar outflow and its position angle are consistent with those of the radio jet produced in 1984 (extrapolated to the time of our optical imagery), no obvious counterpart is visible of the original, dense radio bullets ejected by the system. We speculate that the optical bipolar outflow might be the remannt of the interaction of the bullets with a relatively dense circumstellar medium.

Romano L. M. Corradi; Ulisse Munari; Mario Livio; Antonio Mampaso; Denise R. Goncalves; Hugo E. Schwarz

2001-09-04T23:59:59.000Z

158

Method of preparing (CH.sub.3).sub.3 SiNSO and byproducts thereof  

DOE Patents (OSTI)

(CH.sub.3).sub.3 SiNSO is produced by the reaction of ((CH.sub.3).sub.3 Si).sub.2 NH with SO.sub.2. Also produced in the reaction are ((CH.sub.3).sub.3 Si).sub.2 O and a new solid compound [NH.sub.4 ][(CH.sub.3).sub.3 SiOSO.sub.2 ]. Both (CH.sub.3).sub.3 SiNSO and [NH.sub.4 ][(CH.sub.3).sub.3 SiOSO.sub.2 ] have fluorescent properties. The reaction of the subject invention is used in a method of measuring the concentration of SO.sub.2 pollutants in gases. By the method, a sample of gas is bubbled through a solution of ((CH.sub.3).sub.3 Si).sub.2 NH, whereby any SO.sub.2 present in the gas will react to produce the two fluorescent products. The measured fluorescence of these products can then be used to calculate the concentration of SO.sub.2 in the original gas sample. The solid product [NH.sub.4 ][(CH.sub.3).sub.3 SiOSO.sub.2 ] may be used as a standard in solid state NMR spectroscopy.

Spicer, Leonard D. (Salt Lake City, UT); Bennett, Dennis W. (Clemson, SC); Davis, Jon F. (Salt Lake City, UT)

1984-01-01T23:59:59.000Z

159

Nano-Tera.CH: Nano-technologies for Tera-scale Problems Giovanni De Micheli  

E-Print Network (OSTI)

Nano-Tera.CH: Nano-technologies for Tera-scale Problems Giovanni De Micheli EPF Lausanne 1015, Switzerland ABSTRACT -- The Nano-Tera.CH initiative is a broad engineering program in Switzerland for health is rooted in advances in engineering nano-scale materials and their exploitation in a variety of systems

De Micheli, Giovanni

160

RESEARCH ARTICLE Greenhouse gas emissions (CO2, CH4, and N2O) from several  

E-Print Network (OSTI)

RESEARCH ARTICLE Greenhouse gas emissions (CO2, CH4, and N2O) from several perialpine and alpine investigated greenhouse gas emissions (CO2, CH4, and N2O) from reservoirs located across an altitude gradient in Switzerland. These are the first results of greenhouse gas emissions from reservoirs at high elevations

Wehrli, Bernhard

Note: This page contains sample records for the topic "butyl ether ch" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Hybrid CH&P PON-11-507 Page 1 of 19  

E-Print Network (OSTI)

Hybrid CH&P PON-11-507 Page 1 of 19 GRANT SOLICITATION CALIFORNIA ENERGY COMMISSION PON-11 and Power (DG/CHP/CCHP) Systems Research, Development and Demonstration PIER Renewable Energy and Advanced Generation APPLICATIONPACKAGE Date: January, 2012 EDMUND G. BROWN JR., Governor #12;Hybrid CH&P PON-11

162

Aquatic Sources and Sinks of CO2 and CH4 in the Polar Regions  

Science Conference Proceedings (OSTI)

The highest concentration and greatest seasonal amplitudes of atmospheric CO2 and CH4 occur at 6070N, outside the 3060N band where the main sources of anthropogenic CO2 and CH4 are located, indicating that the northern environment is a ...

I. P. Semiletov

1999-01-01T23:59:59.000Z

163

Commercial-scale demonstration of the Liquid Phase Methanol (LPMEOH{trademark}) Process. Peroxide formation of dimethyl ether in methanol mixtures  

DOE Green Energy (OSTI)

Organic peroxides could form when dimethyl ether in methanol is stored for three to six months at a time. The objective of this work was to determine the level of peroxide formation from dimethyl ether in reagent grade methanol and raw methanol at room temperature under 3 atmospheres (45 psig) of air. Raw methanol is methanol made from syngas by the LPMEOH Process without distillation. Aliphatic ethers tend to react slowly with oxygen from the air to form unstable peroxides. However, there are no reports on peroxide formation from dimethyl ether. After 172 days of testing, dimethyl ether in either reagent methanol or raw methanol at room temperature and under 60--70 psig pressure of air does not form detectable peroxides. Lack of detectable peroxides suggests that dimethyl ether or dimethyl ether and methanol may be stored at ambient conditions. Since the compositions of {approximately} 1.3 mol% or {approximately} 4.5 mol% dimethyl ether in methanol do not form peroxides, these compositions can be considered for diesel fuel or an atmospheric turbine fuel, respectively.

Waller, F.J.

1997-11-01T23:59:59.000Z

164

Research Article Rapeseed Oil Monoester of Ethylene Glycol Monomethyl Ether as a New Biodiesel  

E-Print Network (OSTI)

Copyright 2011 Jiang Dayong et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. A novel biodiesel named rapeseed oil monoester of ethylene glycol monomethyl ether is developed. This fuel has one more ester group than the traditional biodiesel. The fuel was synthesized and structurally identified through FT-IR and P 1P H NMR analyses. Engine test results show that when a tested diesel engine is fueled with this biodiesel in place of 0 # diesel fuel, engine-out smoke emissions can be decreased by 25.0%75.0%, CO emissions can be reduced by 50.0%, and unburned HC emissions are lessened significantly. However, NOx emissions generally do not change noticeably. In the area of combustion performance, both engine in-cylinder pressure and its changing rate with crankshaft angle are increased to some extent. Rapeseed oil monoester of ethylene glycol monomethyl ether has a much higher cetane number and shorter ignition delay, leading to autoignition 1.1 ? CA earlier than diesel fuel during engine operation. Because of certain amount of oxygen contained in the new biodiesel, the engine thermal efficiency is improved 13.5%20.4 % when fueled with the biodiesel compared with diesel fuel. 1.

Jiang Dayong; Wang Xuanjun; Liu Shuguang; Guo Hejun

2011-01-01T23:59:59.000Z

165

Calixarene crown ether solvent composition and use thereof for extraction of cesium from alkaline waste solutions  

DOE Patents (OSTI)

A solvent composition and corresponding method for extracting cesium (Cs) from aqueous neutral and alkaline solutions containing Cs and perhaps other competing metal ions is described. The method entails contacting an aqueous Cs-containing solution with a solvent consisting of a specific class of lipophilic calix[4]arene-crown ether extractants dissolved in a hydrocarbon-based diluent containing a specific class of alkyl-aromatic ether alcohols as modifiers. The cesium values are subsequently recovered from the extractant, and the solvent subsequently recycled, by contacting the Cs-containing organic solution with an aqueous stripping solution. This combined extraction and stripping method is especially useful as a process for removal of the radionuclide cesium-137 from highly alkaline waste solutions which are also very concentrated in sodium and potassium. No pre-treatment of the waste solution is necessary, and the cesium can be recovered using a safe and inexpensive stripping process using water, dilute (millimolar) acid solutions, or dilute (millimolar) salt solutions. An important application for this invention would be treatment of alkaline nuclear tank wastes. Alternatively, the invention could be applied to decontamination of acidic reprocessing wastes containing cesium-137.

Moyer, Bruce A. (Oak Ridge, TN); Sachleben, Richard A. (Knoxville, TN); Bonnesen, Peter V. (Knoxville, TN); Presley, Derek J. (Ooltewah, TN)

2001-01-01T23:59:59.000Z

166

Special Report Order, CH2M Hill Hanford Group, Inc. - October 22, 2001 |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

CH2M Hill Hanford Group, Inc. - October 22, CH2M Hill Hanford Group, Inc. - October 22, 2001 Special Report Order, CH2M Hill Hanford Group, Inc. - October 22, 2001 October 22, 2001 Special Report Order ssued to CH2M Hill Hanford Group, Inc., related to Multiple Nuclear Safety Issues at the Hanford Site On September 18, 2001, the Office of Price-Anderson Enforcement (OE) in coordination with the DOE Office of River Protection (ORP) conducted a review of the actions taken by CH2M Hill Hanford Group (CHG) in response to an Enforcement Letter dated April 24, 2001. This Enforcement Letter referenced three Noncompliance Tracking System (NTS) reports submitted by CHG which collectively suggested weaknesses in your nuclear safety operations related to (1) corrective action management, (2) worker training

167

U.S. Department of Energy, Richland Operations Office And CH2M HILL Plateau  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

U.S. Department of Energy, Richland Operations Office And CH2M HILL U.S. Department of Energy, Richland Operations Office And CH2M HILL Plateau Remediation Company Partnering Charter For Partnering Performance Agreement U.S. Department of Energy, Richland Operations Office And CH2M HILL Plateau Remediation Company Partnering Charter For Partnering Performance Agreement The U.S. Department of Energy (DOE) Richland Operations Office (DOE-RL) and CH2M HILL Plateau Remediation Company (CHPRC) are committed to continuous improvement and will utilize principles of the DOE Environmental Management (DOE-EM) Partnering Policy to enhance teaming to further execute the Plateau Remediation Contract. U.S. Department of Energy, Richland Operations Office And CH2M HILL Plateau Remediation Company Partnering Charter For Partnering Performance Agreement

168

Safety Evaluation Report of the Waste Isolation Pilot Plant Contact Handled (CH) Waste Documented Safety Analysis  

Science Conference Proceedings (OSTI)

This Safety Evaluation Report (SER) documents the Department of Energys (DOE's) review of Revision 9 of the Waste Isolation Pilot Plant Contact Handled (CH) Waste Documented Safety Analysis, DOE/WIPP-95-2065 (WIPP CH DSA), and provides the DOE Approval Authority with the basis for approving the document. It concludes that the safety basis documented in the WIPP CH DSA is comprehensive, correct, and commensurate with hazards associated with CH waste disposal operations. The WIPP CH DSA and associated technical safety requirements (TSRs) were developed in accordance with 10 CFR 830, Nuclear Safety Management, and DOE-STD-3009-94, Preparation Guide for U. S. Department of Energy Nonreactor Nuclear Safety Analysis Reports.

Washington TRU Solutions LLC

2005-09-01T23:59:59.000Z

169

Consent Order, CH2M Hill Hanford Group, Inc. - EA-2000-09 | Department of  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

M Hill Hanford Group, Inc. - EA-2000-09 M Hill Hanford Group, Inc. - EA-2000-09 Consent Order, CH2M Hill Hanford Group, Inc. - EA-2000-09 July 25, 2000 Price-Anderson Enforcement Consent Order issued to CH2M Hill Hanford Group, Inc., related to Quality Problems at the Hanford Site Tank Farms, (EA-2000-09) This letter refers to the Department of Energy's (DOE) evaluation of an internal investigation conducted by CH2M Hill Group, Inc. (CHG) in February 2000. The investigation examined the facts and circumstances surrounding quality problems with the procurement of safety class piping for the W-314 Project at the Tank Farm Waste Remediation System. Consent Order, CH2M Hill Hanford Group, Inc. - EA-2000-09 More Documents & Publications Consent Order, Fluor Federal Services - EA-2000-10 Special Report Order, CH2M Hill Hanford Group, Inc. - October 22, 2001

170

Enforcement Letter, CH2M Hill Hanford Group, Inc. - April 24, 2001 |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

CH2M Hill Hanford Group, Inc. - April 24, 2001 CH2M Hill Hanford Group, Inc. - April 24, 2001 Enforcement Letter, CH2M Hill Hanford Group, Inc. - April 24, 2001 April 24, 2001 Enforcement Letter issued to CH2M Hill Hanford Group, Inc., related to Nuclear Safety Management at the Hanford Site Tank Farms This letter refers to a recent investigation by the Department of Energy (DOE), regarding potential noncompliances with the requirements of 10 CFR 830, "Nuclear Safety Management," occurring at the Hanford Tank Farms. The investigation reviewed three issues that were reported into the Noncompliance Tracking System (NTS) by CH2M Hill Hanford Group, Inc. Two of the NTS reports involve the failure to perform the Technical Safety Requirement (TSR) for [ ] gas monitoring. The initial potential noncompliance occurred in January 2000, in which a Zip Cord was installed

171

Preliminary Notice of Violation, CH2M Hill Hanford Group, Inc. - EA-2003-06  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

CH2M Hill Hanford Group, Inc. - CH2M Hill Hanford Group, Inc. - EA-2003-06 Preliminary Notice of Violation, CH2M Hill Hanford Group, Inc. - EA-2003-06 August 29, 2003 Preliminary Notice of Violation issued to CH2M Hill Hanford Group, Inc., related to Quality Assurance Issues at the Hanford Site Tank Farms This letter refers to the Department of Energy's Office of Price-Anderson Enforcement (OE) investigation of the facts and circumstances concerning quality assurance issues affecting nuclear safety at the Hanford Tank Farms. These issues involve the inadvertent deenergization of annulus leak detectors, dilution tank overfills, and dome loading control, over the period August 2002 to November 2002. Preliminary Notice of Violation, CH2M Hill Hanford Group, Inc. - EA-2003-06 More Documents & Publications

172

Independent Oversight Review, Hanford Site CH2M Hill Plateau Remediation  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Site CH2M Hill Plateau Site CH2M Hill Plateau Remediation Company - November 2012 Independent Oversight Review, Hanford Site CH2M Hill Plateau Remediation Company - November 2012 November 2012 Review of the Hanford Site CH2M Hill Plateau Remediation Company Implementation Verification Review Processes This report documents the independent review of implementation verification review (IVR) processes at the Hanford Site CH2M Hill Plateau Remediation Company that were conducted by the Office of Enforcement and Oversight (Independent Oversight), which is within the U.S. Department of Energy (DOE) Office of Health, Safety and Security (HSS). The onsite review was performed by the HSS Office of Safety and Emergency Management Evaluations from August 13 to17, 2012. The objective of this assessment was to evaluate

173

Exhaust Emissions and Combustion Performances of Rapeseed Oil Monoester of Ethylene Glycol Monomethyl Ether as a Novel Biodiesel  

Science Conference Proceedings (OSTI)

In this paper, a novel biodiesel named rapeseed oil monoester of ethylene glycol monomethyl ether has been developed, which has one more ester group than traditional biodiesel. It was synthesized and structurally identified through FT-IR, 1H NMR analyses. ... Keywords: component, rapeseed oil monoester, synthesis, exhaust emissions, combustion performances

Jiang Dayong; Wang Xuanjun; Wang Wenguo; Han Qilong

2011-02-01T23:59:59.000Z

174

www.cepe.ethz.ch A Real Options Evaluation Model for the Diffusion Prospects of New Renewable Power Generation Technologies  

E-Print Network (OSTI)

www.cepe.ethz.ch A real options evaluation model for the diffusion prospects of new renewable power generation technologies

Grkan Kumbaroglu; Reinhard Madlener; Mustafa Demirel; Grkan Kumbaroglu; Reinhard Madlener; Mustafa Demirel

2004-01-01T23:59:59.000Z

175

Process for the production of ethylidene diacetate from dimethyl ether using a heterogeneous catalyst  

DOE Patents (OSTI)

This invention relates to a process for producing ethylidene diacetate by the reaction of dimethyl ether, acetic acid, hydrogen and carbon monoxide at elevated temperatures and pressures in the presence of an alkyl halide and a heterogeneous, bifunctional catalyst that is stable to hydrogenation and comprises an insoluble polymer having pendant quaternized heteroatoms, some of which heteroatoms are ionically bonded to anionic Group VIII metal complexes, the remainder of the heteroatoms being bonded to iodide. In contrast to prior art processes, no accelerator (promoter) is necessary to achieve the catalytic reaction and the products are easily separated from the catalyst by filtration. The catalyst can be recycled for 3 consecutive runs without loss in activity.

Ramprasad, D.; Waller, F.J.

1998-04-28T23:59:59.000Z

176

Process for the production of ethylidene diacetate from dimethyl ether using a heterogeneous catalyst  

DOE Patents (OSTI)

This invention relates to a process for producing ethylidene diacetate by the reaction of dimethyl ether, acetic acid, hydrogen and carbon monoxide at elevated temperatures and pressures in the presence of an alkyl halide and a heterogeneous, bifunctional catalyst that is stable to hydrogenation and comprises an insoluble polymer having pendant quaternized heteroatoms, some of which heteroatoms are ionically bonded to anionic Group VIII metal complexes, the remainder of the heteroatoms being bonded to iodide. In contrast to prior art processes, no accelerator (promoter) is necessary to achieve the catalytic reaction and the products are easily separated from the catalyst by filtration. The catalyst can be recycled for 3 consecutive runs without loss in activity.

Ramprasad, Dorai (Allentown, PA); Waller, Francis Joseph (Allentown, PA)

1998-01-01T23:59:59.000Z

177

Use of aluminum phosphate as the dehydration catalyst in single step dimethyl ether process  

DOE Green Energy (OSTI)

The present invention pertains to a process for the coproduction of methanol and dimethyl ether (DME) directly from a synthesis gas in a single step (hereafter, the "single step DME process"). In this process, the synthesis gas comprising hydrogen and carbon oxides is contacted with a dual catalyst system comprising a physical mixture of a methanol synthesis catalyst and a methanol dehydration catalyst. The present invention is an improvement to this process for providing an active and stable catalyst system. The improvement comprises the use of an aluminum phosphate based catalyst as the methanol dehydration catalyst. Due to its moderate acidity, such a catalyst avoids the coke formation and catalyst interaction problems associated with the conventional dual catalyst systems taught for the single step DME process.

Peng, Xiang-Dong (Allentown, PA); Parris, Gene E. (Coopersburg, PA); Toseland, Bernard A. (Allentown, PA); Battavio, Paula J. (Allentown, PA)

1998-01-01T23:59:59.000Z

178

Modern Records of Atmospheric Methane (CH4) and a 2000-year Ice-core Record  

NLE Websites -- All DOE Office Websites (Extended Search)

(CH4) » Ice Cores (CH4) » Ice Cores Modern Records of Atmospheric Methane (CH4) and a 2000-year Ice-core Record from Law Dome, Antarctica Introduction This page provides an introduction and links to records of atmospheric methane (CH4) over the last 2000 years, emphasizing large data bases each representing currently active stations. Records in recent decades (time period depending on location) have been obtained from samples of ambient-air at remote locations, which represent global atmospheric conditions rather than influences of local sources. The longer (2000-year) record is from the Law Dome ice core in Antarctica. The ice-core record has been merged with modern annual data from Cape Grim, Tasmania to provide a 2000-year record ending with the most recent data. A spline function has

179

Independent Oversight Review, Richland Operations Office and CH2M Hill  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

and CH2M and CH2M Hill Plateau Remediation Company and Mission Support Alliance - April 2012 Independent Oversight Review, Richland Operations Office and CH2M Hill Plateau Remediation Company and Mission Support Alliance - April 2012 April 2012 Review of Richland Operations Office and CH2M Hill Plateau Remediation Company and Mission Support Alliance Conduct of Operations The purpose of this independent oversight review by the U.S. Department of Energy (DOE) Office of Enforcement and Oversight, within the Office of Health, Safety and Security (HSS), was to observe and shadow1 a DOE Richland Operations Office (DOE-RL) assessment of its contractors at the Hanford Site. The HSS reviewer observed the implementation and effectiveness of the DOE-RL assessment of two of the contractors (CHPRC and

180

Preliminary Notice of Violation, CH2M Hill Hanford Group, Inc. - EA-2003-06  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Inc. - Inc. - EA-2003-06 Preliminary Notice of Violation, CH2M Hill Hanford Group, Inc. - EA-2003-06 August 29, 2003 Preliminary Notice of Violation issued to CH2M Hill Hanford Group, Inc., related to Quality Assurance Issues at the Hanford Site Tank Farms This letter refers to the Department of Energy's Office of Price-Anderson Enforcement (OE) investigation of the facts and circumstances concerning quality assurance issues affecting nuclear safety at the Hanford Tank Farms. These issues involve the inadvertent deenergization of annulus leak detectors, dilution tank overfills, and dome loading control, over the period August 2002 to November 2002. Preliminary Notice of Violation, CH2M Hill Hanford Group, Inc. - EA-2003-06 More Documents & Publications Preliminary Notice of Violation, CH2M Hill Hanford Group, Inc. - EA-2006-06

Note: This page contains sample records for the topic "butyl ether ch" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Preliminary Notice of Violation, CH2M-Washington Group Idaho, LLC -  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

CH2M-Washington Group Idaho, LLC - CH2M-Washington Group Idaho, LLC - EA-2007-03 Preliminary Notice of Violation, CH2M-Washington Group Idaho, LLC - EA-2007-03 June 14, 2007 Preliminary Notice of Violation issued to CH2M-Washington Group Idaho, LLC, related to Radiation Protection Program Deficiencies at the Radioactive Waste Management Complex - Accelerated Retrieval Project at the Idaho National Laboratory This letter refers to the investigation of events at the Radioactive Waste Management Complex - Accelerated Retrieval Project (ARP) by the Department of Energy's (DOE) Office of Enforcement. The investigation summary report, Multiple Radiological Protection Program Deficiencies and Safety Culture Concerns, was provided to you in a letter dated February 20, 2007. An enforcement conference to discuss these findings was held on March

182

Independent Oversight Review, Richland Operations Office and CH2M Hill  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Richland Operations Office and CH2M Richland Operations Office and CH2M Hill Plateau Remediation Company and Mission Support Alliance - April 2012 Independent Oversight Review, Richland Operations Office and CH2M Hill Plateau Remediation Company and Mission Support Alliance - April 2012 April 2012 Review of Richland Operations Office and CH2M Hill Plateau Remediation Company and Mission Support Alliance Conduct of Operations The purpose of this independent oversight review by the U.S. Department of Energy (DOE) Office of Enforcement and Oversight, within the Office of Health, Safety and Security (HSS), was to observe and shadow1 a DOE Richland Operations Office (DOE-RL) assessment of its contractors at the Hanford Site. The HSS reviewer observed the implementation and effectiveness of the DOE-RL assessment of two of the contractors (CHPRC and

183

800,000-year Ice-Core Records of Atmospheric Methane (CH4)  

NLE Websites -- All DOE Office Websites (Extended Search)

Methane (CH4) » Ice Cores Methane (CH4) » Ice Cores 800,000-year Ice-Core Records of Atmospheric Methane (CH4) This page introduces ice-core records of methane (CH4) extending back 800,000 years at Dome C, Antarctica and over 400,000 years at the Vostok site. Links are also provided to shorter records from other Antarctic locations. The 2000-year record from Law Dome, Antarctica, has been merged with modern records to create a long-term record to the present. These records are maintained by the World Data Center for Paleoclimatology, National Oceanic and Atmospheric Administration (NOAA), and have graciously been made freely available for access and distribution. The original investigators made the effort to obtain the data and assure their quality. To assure proper credit is given, please follow the citation instructions

184

Preliminary Notice of Violation, CH2M Hill Hanford Group, Inc - EA-2005-01  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

CH2M Hill Hanford Group, Inc - CH2M Hill Hanford Group, Inc - EA-2005-01 Preliminary Notice of Violation, CH2M Hill Hanford Group, Inc - EA-2005-01 March 10, 2005 Preliminary Notice of Violation issued to CH2M Hill Hanford Group, Inc., related to Radiological and Operational Events at the Hanford Tank Farms This letter refers to the recent investigation by the Department of Energy's (DOE) Office of Price-Anderson Enforcement (OE) at the Hanford Tank Farms of four radiological and operational events occurring during 2003 and 2004. The events included (1) the June 2003 multiple personnel contamination event at the [ ]; (2) the November 2003 Technical Safety Requirement violation during a cross-site waste transfer; (3) the November 2003 valve positioning error during S-112 waste retrieval operations; and

185

Preliminary Notice of Violation, CH2M-Washington Group Idaho, LLC- EA-2007-03  

Energy.gov (U.S. Department of Energy (DOE))

Preliminary Notice of Violation issued to CH2M-Washington Group Idaho, LLC, related to Radiation Protection Program Deficiencies at the Radioactive Waste Management Complex - Accelerated Retrieval Project at the Idaho National Laboratory

186

CH Activation and Oxidation of Methane to Methanol in High Yield...  

NLE Websites -- All DOE Office Websites (Extended Search)

CH Activation and Oxidation of Methane to Methanol in High Yield with Novel Pt Complexes Speaker(s): Roy Periana Date: April 27, 1999 - 12:00pm Location: Bldg. 90 Seminar Host...

187

C-H functionalisation through singlet chlorocarbenes insertions MP2 and DFT investigations  

Science Conference Proceedings (OSTI)

The insertion reactions of singlet mono and dichlorocarbenes (1CHCl and 1CCl2) into primary, secondary and tertiary C-H bonds of methane, ethane, propane, n-butane and iso-butane have been investigated at ...

M. Ramalingam; K. Ramasami; P. Venuvanalingam; V. Sethuraman

2006-05-01T23:59:59.000Z

188

Hydrogen Storage in Carbon Nanotubes Through Formation of C-H...  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen Storage in Carbon Nanotubes Through Formation of C-H Bonds Print Two of the major challenges for humanity in the next 20 years are the shrinking availability of fossil...

189

CH2M Hill Hanford Group Inc (CHG) Information Resource Management (IRM) Strategic Plan  

SciTech Connect

The CH2M Hill Hanford Group, Inc., Information Resource Management Strategic Plan is the top-level planning document for applying information and information resource management to achieve the CHG mission for the management of the River Protection Project

NELSON, R.L.

2000-05-08T23:59:59.000Z

190

DOE Cites CH2M Hill Hanford for Violating Nuclear Safety Rules | Department  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

for Violating Nuclear Safety Rules for Violating Nuclear Safety Rules DOE Cites CH2M Hill Hanford for Violating Nuclear Safety Rules March 10, 2005 - 10:44am Addthis Hanford Tank Farm Contractor Faces Fine of more than $300,000 WASHINGTON, DC - The Department of Energy (DOE) today notified the CH2M Hill Hanford Group, Inc. (CH2M Hill) - that it will fine the company $316,250 for violations of the department's nuclear safety requirements. CH2M Hill is the department's contractor responsible for storage of highly radioactive and hazardous liquid waste at the Hanford Tank Farms near Richland, Wash. The Preliminary Notice of Violation (PNOV) issued today, cites four events that took place in 2003 and 2004. These events include the contamination of several workers while removing equipment from a valve pit

191

Hybrid CH&P PON-11-507 Page 1 of 1  

E-Print Network (OSTI)

Hybrid CH&P PON-11-507 Page 1 of 1 ATTACHMENT I Prevailing Wage Special Condition Template Public this Agreement, the Recipient shall submit to the Energy Commission a certificate signed by the Recipient and all

192

Session 4: EER: Extended (or Enhanced) ER Model (CH-2 and 3)  

E-Print Network (OSTI)

Session 4: EER: Extended (or Enhanced) ER Model (CH-2 and 3) CSCI-585 , Cyrus Shahabi · Example ER to no subclass. EER-to-Relational Mapping · Option 1: One table for superclass + two tables for subclasses (one

Shahabi, Cyrus

193

Understanding the redox shuttle stability of 3,5-di-tert-butyl-1,2-dimethoxybenzene for overcharge protection of lithium-ion batteries.  

DOE Green Energy (OSTI)

3,5-di-tert-butyl-1,2-dimethoxybenzene (DBDB) has been synthesized as a new redox shuttle additive for overcharge protection of lithium-ion batteries. DBDB can easily dissolve in carbonate-based electrolytes, which facilitates its practical use in lithium-ion batteries; however, it has poor electrochemical stability compared to 2,5-di-tert-butyl-1,4-dimethoxybenzene (DDB). The structures of DBDB and DDB were investigated using X-ray crystallography and density functional calculations. The structures differ in the conformations of the alkoxy bonds probably due to the formation of an intramolecular hydrogen bond in the case of DBDB. We investigated reaction energies for decomposition pathways of neutral DBDB and DDB and their radical cations and found little difference in the reaction energies, although it is clear that kinetically, decomposition of DBDB is more favorable.

Zhang, Z.; Zhang, L.; Schlueter, J. A.; Redfern, P. C.; Curtiss, L.; Amine, K.

2010-01-01T23:59:59.000Z

194

Identification of volatile butyl rubber thermal-oxidative degradation products by cryofocusing gas chromatography/mass spectrometry (cryo-GC/MS).  

Science Conference Proceedings (OSTI)

Chemical structure and physical properties of materials, such as polymers, can be altered as aging progresses, which may result in a material that is ineffective for its envisioned intent. Butyl rubber formulations, starting material, and additives were aged under thermal-oxidative conditions for up to 413 total days at up to 124 %C2%B0C. Samples included: two formulations developed at Kansas City Plant (KCP) (%236 and %2310), one commercially available formulation (%2321), Laxness bromobutyl 2030 starting material, and two additives (polyethylene AC-617 and Vanax MBM). The low-molecular weight volatile thermal-oxidative degradation products that collected in the headspace over the samples were preconcentrated, separated, and detected using cryofocusing gas chromatography mass spectrometry (cryo-GC/MS). The majority of identified degradation species were alkanes, alkenes, alcohols, ketones, and aldehydes. Observations for Butyl %2310 aged in an oxygen-18 enriched atmosphere (18O2) were used to verify when the source of oxygen in the applicable degradation products was from the gaseous environment rather than the polymeric mixture. For comparison purposes, Butyl %2310 was also aged under non-oxidative thermal conditions using an argon atmosphere.

Smith, Jonell Nicole; White, Michael Irvin; Bernstein, Robert; Hochrein, James Michael

2013-02-01T23:59:59.000Z

195

Ion imaging study of reaction dynamics in the N{sup +}+ CH{sub 4} system  

SciTech Connect

The velocity map ion imaging method is applied to the ion-molecule reactions of N{sup +} with CH{sub 4}. The velocity space images are collected at collision energies of 0.5 and 1.8 eV, providing both product kinetic energy and angular distributions for the reaction products CH{sub 4}{sup +}, CH{sub 3}{sup +}, and HCNH{sup +}. The charge transfer process is energy resonant and occurs by long-range electron transfer that results in minimal deflection of the products. The formation of the most abundant product, CH{sub 3}{sup +}, proceeds by dissociative charge transfer rather than hydride transfer, as reported in earlier publications. The formation of HCNH{sup +} by C-N bond formation appears to proceed by two different routes. The triplet state intermediates CH{sub 3}NH{sup +} and CH{sub 2}NH{sub 2}{sup +} that are formed as N{sup +}({sup 3}P) approaches CH{sub 4} may undergo sequential loss of two hydrogen atoms to form ground state HCNH{sup +} products on a spin-allowed pathway. However, the kinetic energy distributions for formation of HCNH{sup +} extend past the thermochemical limit to form HCNH{sup +}+ 2H, implying that HCNH{sup +} may also be formed in concert with molecular hydrogen, and requiring that intersystem crossing to the singlet manifold must occur in a significant ({approx}25%) fraction of reactive collisions. We also report GAUSSIAN G2 calculations of the energies and structures of important singlet and triplet [CNH{sub 4}{sup +}] complexes that serve as precursors to product formation.

Pei, Linsen; Farrar, James M. [Department of Chemistry, University of Rochester, Rochester, New York 14627 (United States)

2012-10-21T23:59:59.000Z

196

Polybrominated diphenyl ethers (PBDEs) in leachates from selected landfill sites in South Africa  

Science Conference Proceedings (OSTI)

The last few decades have seen dramatic growth in the scale of production and the use of polybrominated diphenyl ethers (PBDEs) as flame retardants. Consequently, PBDEs such as BDE -28, -47, -66, -71, -75, -77, -85, -99, -100, -119, -138, -153, -154, and -183 have been detected in various environmental matrices. Generally, in South Africa, once the products containing these chemicals have outlived their usefulness, they are discarded into landfill sites. Consequently, the levels of PBDEs in leachates from landfill sites may give an indication of the general exposure and use of these compounds. The present study was aimed at determining the occurrence and concentrations of most common PBDEs in leachates from selected landfill sites. The extraction capacities of the solvents were also tested. Spiked landfill leachate samples were used for the recovery tests. Separation and determination of the PBDE congeners were carried out with a gas chromatograph equipped with Ni{sup 63} electron capture detector. The mean percentage recoveries ranged from 63% to 108% (n = 3) for landfill leachate samples with petroleum ether giving the highest percentage extraction. The mean concentrations of PBDEs obtained ranged from ND to 2670 pg l{sup -1}, ND to 6638 pg l{sup -1}, ND to 7230 pg l{sup -1}, 41 to 4009 pg l{sup -1}, 90 to 9793 pg l{sup -1} for the Garankuwa, Hatherly, Kwaggarsrand, Soshanguve and Temba landfill sites, respectively. Also BDE -28, -47, -71 and BDE-77 were detected in the leachate samples from all the landfill sites; and all the congeners were detected in two of the oldest landfill sites. The peak concentrations were recorded for BDE-47 at three sites and BDE-71 and BDE-75 at two sites. The highest concentration, 9793 {+-} 1.5 pg l{sup -1}, was obtained for the Temba landfill site with the highest BOD value. This may suggest some influence of organics on the level of PBDEs. Considering the leaching characteristics of brominated flame retardants, there is a high possibility that with time these compounds may infiltrate into the groundwater around the sites since most of the sites are not adequately lined.

Odusanya, David O. [Department of Environmental, Water and Earth Sciences, Faculty of Science, Tshwane University of Technology, Private Bag X680, 175 Nelson Mandela Drive, Arcadia, Pretoria 0001 (South Africa); Okonkwo, Jonathan O. [Department of Environmental, Water and Earth Sciences, Faculty of Science, Tshwane University of Technology, Private Bag X680, 175 Nelson Mandela Drive, Arcadia, Pretoria 0001 (South Africa)], E-mail: OkonkwoOJ@tut.ac.za; Botha, Ben [Department of Environmental, Water and Earth Sciences, Faculty of Science, Tshwane University of Technology, Private Bag X680, 175 Nelson Mandela Drive, Arcadia, Pretoria 0001 (South Africa)

2009-01-15T23:59:59.000Z

197

Decrease of intracellular pH as possible mechanism of embryotoxicity of glycol ether alkoxyacetic acid metabolites  

SciTech Connect

Embryotoxicity of glycol ethers is caused by their alkoxyacetic acid metabolites, but the mechanism underlying the embryotoxicity of these acid metabolites is so far not known. The present study investigates a possible mechanism underlying the embryotoxicity of glycol ether alkoxyacetic acid metabolites using the methoxyacetic acid (MAA) metabolite of ethylene glycol monomethyl ether as the model compound. The results obtained demonstrate an MAA-induced decrease of the intracellular pH (pH{sub i}) of embryonic BALB/c-3T3 cells as well as of embryonic stem (ES)-D3 cells, at concentrations that affect ES-D3 cell differentiation. These results suggest a mechanism for MAA-mediated embryotoxicity similar to the mechanism of embryotoxicity of the drugs valproic acid and acetazolamide (ACZ), known to decrease the pH{sub i}in vivo, and therefore used as positive controls. The embryotoxic alkoxyacetic acid metabolites ethoxyacetic acid, butoxyacetic acid and phenoxyacetic acid also caused an intracellular acidification of BALB/c-3T3 cells at concentrations that are known to inhibit ES-D3 cell differentiation. Two other embryotoxic compounds, all-trans-retinoic acid and 5-fluorouracil, did not decrease the pH{sub i} of embryonic cells at concentrations that affect ES-D3 cell differentiation, pointing at a different mechanism of embryotoxicity of these compounds. MAA and ACZ induced a concentration-dependent inhibition of ES-D3 cell differentiation, which was enhanced by amiloride, an inhibitor of the Na{sup +}/H{sup +}-antiporter, corroborating an important role of the pH{sub i} in the embryotoxic mechanism of both compounds. Together, the results presented indicate that a decrease of the pH{sub i} may be the mechanism of embryotoxicity of the alkoxyacetic acid metabolites of the glycol ethers.

Louisse, Jochem, E-mail: jochem.louisse@wur.n [Division of Toxicology, Wageningen University, Tuinlaan 5, 6703 HE Wageningen (Netherlands); TNO Quality of Life, PO Box 360, 3700 AJ Zeist (Netherlands); WUR/TNO Centre for Innovative Toxicology, PO Box 8000, 6700 EA Wageningen (Netherlands); Bai Yanqing [Division of Toxicology, Wageningen University, Tuinlaan 5, 6703 HE Wageningen (Netherlands); Verwei, Miriam; Sandt, Johannes J.M. van de [TNO Quality of Life, PO Box 360, 3700 AJ Zeist (Netherlands); WUR/TNO Centre for Innovative Toxicology, PO Box 8000, 6700 EA Wageningen (Netherlands); Blaauboer, Bas J. [Institute for Risk Assessment Sciences (IRAS), Utrecht University, PO Box 80176, 3508 TD Utrecht (Netherlands); Rietjens, Ivonne M.C.M. [Division of Toxicology, Wageningen University, Tuinlaan 5, 6703 HE Wageningen (Netherlands); WUR/TNO Centre for Innovative Toxicology, PO Box 8000, 6700 EA Wageningen (Netherlands)

2010-06-01T23:59:59.000Z

198

Independent Oversight Review, URS CH2M Oak Ridge - June 2013 | Department  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

URS CH2M Oak Ridge - June 2013 URS CH2M Oak Ridge - June 2013 Independent Oversight Review, URS CH2M Oak Ridge - June 2013 June 2013 Review of Oak Ridge Environmental Management Radiological Controls Activity Level Implementation The purpose of this set of facility specific Independent Oversight targeted reviews is to evaluate the flowdown of occupational radiation protection requirements, as expressed in facility RPPs, to work planning, control, and execution processes, such as radiological work authorizations, including radiological work permits (RWPs) and other technical work documents (TWDs). This targeted review was performed at Oak Ridge during the period of March 3-22, 2013. This report discusses the background, scope, methodology, results, and conclusions of the review, as well as items identified for

199

Consent Order, CH2M-WG Idaho, LLC - WCO-2011-01 | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

M-WG Idaho, LLC - WCO-2011-01 M-WG Idaho, LLC - WCO-2011-01 Consent Order, CH2M-WG Idaho, LLC - WCO-2011-01 October 6, 2011 Consent Order issued to CH2M-WG Idaho, LLC related to a Hoisting Incident that occurred at the Sodium Bearing Waste Treatment Project at the Idaho National Laboratory The Office of Health Safety and Security's Office of Enforcement and Oversight has completed its investigation into the facts and circumstances associated with the October 4, 2010, hoisting incident that occurred when a telescopic hydraulic gantry system tipped while lifting a 7,800-pound shield plug at the Sodium Bearing Waste Treatment Project (SBWTP) located at the U.S. Department of Energy's Idaho National Laboratory. The results of the investigation were provided to CH2M-WG Idaho, LLC (CWI) in an Investigation Report, dated April 20, 2011, and

200

Enforcement Letter, CH2M Hill Hanford Group Inc, - September 6, 2007 |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Group Inc, - September 6, Group Inc, - September 6, 2007 Enforcement Letter, CH2M Hill Hanford Group Inc, - September 6, 2007 September 6, 2007 Enforcement Letter issued to CH2M Hill Hanford Group, Inc., related to Quality Improvement Deficiencies at the Hanford Tank Farms The Department of Energy (DOE) held an Enforcement Conference on August 29, 2006, with CH2M Hill Hanford Group (CHG) to discuss potential violations of nuclear safety requirements described in our Investigation Summary Report dated July 26, 2006. At that time, DOE elected to defer a decision on a potential quality improvement violation related to recurring radiological events and deficiencies in the identification and control of radiological hazards at the Tank Farms. This decision was based upon the fact that CHG senior management had initiated radiological work

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201

Enforcement Letter, CH2M-Washington Group Idaho LLC , - May 20, 2009 |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

M-Washington Group Idaho LLC , - May 20, M-Washington Group Idaho LLC , - May 20, 2009 Enforcement Letter, CH2M-Washington Group Idaho LLC , - May 20, 2009 May 20, 2009 Enforcement Letter issued to CH2M-Washington Group Idaho, LLC, for Electrical Safety Deficiencies at the Idaho National Laboratory In July 2008, the U.S. Department of Energy (DOE) Office of Health, Safety and Security's, Office of Enforcement was made aware of numerous, longstanding electrical safety deficiencies associated with electrical equipment located on the east side of the Idaho Nuclear Technology and Engineering Center (INTEC). The Office of Enforcement is also aware that shortly after electrical safety issues with this equipment were identified by a CH2M-Washington Group Idaho, LLC (CWI) worker in May 2007, CWI completed an Engineering Design File

202

Enforcement Letter, CH2M Oak Ridge, LLC - SEL-2012-01 | Department of  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

M Oak Ridge, LLC - SEL-2012-01 M Oak Ridge, LLC - SEL-2012-01 Enforcement Letter, CH2M Oak Ridge, LLC - SEL-2012-01 May 4, 2012 Issued to URS CH2M Oak Ridge, LLC, related to a Security Incident involving the Protection and Control of Classified Information at the East Tennessee Technology Park The Office of Health, Safety and Security's Office of Enforcement and Oversight has completed its evaluation of a security incident involving the protection and control of classified information at the East Tennessee Teclmology Park (ETTP) (Local Tracking System Report No. II-IOSC-0576-13). Based on this evaluation, the Department of Energy (DOE) identified concerns that warrant management attention by URS CH2M Oak Ridge, LLC (UCOR), the responsible contractor for ETTP. The specific concerns stem from the number of classified components that

203

Enforcement Letter, CH2M-WG Idaho - NEL-2011-02 | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

M-WG Idaho - NEL-2011-02 M-WG Idaho - NEL-2011-02 Enforcement Letter, CH2M-WG Idaho - NEL-2011-02 September 28, 2011 Issued to CH2M-WG Idaho, LLC related to Quality Assurance and Work Control Issues during Construction of the Sodium Bearing Waste Treatment Project at the Idaho National Laboratory The Office of Health, Safety and Security's Office of Enforcement and Oversight conducted an evaluation of the facts and circumstances associated with quality assurance and work control deficiencies that occurred during the construction of the Sodium Bearing Waste Treatment Project (SBWTP) at the U.S. Department of Energy's (DOE) Idaho National Laboratory. On February 9, 2011, CH2M-Washington Group Idaho, LLC (CWI) reported noncompliances associated with these deficiencies in DOE's Noncompliance Tracking System (NTS) in reports NTS-ID--CWI-IWTU-2010-0002

204

Preliminary Notice of Violation, CH2M HILL Hanford Group, Inc. -  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

HILL Hanford Group, Inc. - HILL Hanford Group, Inc. - NEA-2008-02 Preliminary Notice of Violation, CH2M HILL Hanford Group, Inc. - NEA-2008-02 June 5, 2008 Preliminary Notice of Violation issued to CH2M Hill Hanford Group, Inc., related to a Radioactive Waste Spill at the Hanford Site Tank Farms This letter refers to the Department of Energy's (DOE) investigation into the facts and circumstances associated with the July 27, 2007, spill of radioactive waste in the vicinity of the S-102 retrieval pump discharge at the Hanford Tank Farm. The results of the onsite investigation were provided in an Investigation Report dated March 5, 2008. Press Release Preliminary Notice of Violation, CH2M HILL Hanford Group, Inc. - NEA-2008-02 More Documents & Publications Preliminary Notice of Violation, Bechtel National, Inc. - NEA-2008-04

205

Enforcement Letter, CH2M Hill Hanford Group, Inc. - April 24, 2001 |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Inc. - April 24, 2001 Inc. - April 24, 2001 Enforcement Letter, CH2M Hill Hanford Group, Inc. - April 24, 2001 April 24, 2001 Enforcement Letter issued to CH2M Hill Hanford Group, Inc., related to Nuclear Safety Management at the Hanford Site Tank Farms This letter refers to a recent investigation by the Department of Energy (DOE), regarding potential noncompliances with the requirements of 10 CFR 830, "Nuclear Safety Management," occurring at the Hanford Tank Farms. The investigation reviewed three issues that were reported into the Noncompliance Tracking System (NTS) by CH2M Hill Hanford Group, Inc. Two of the NTS reports involve the failure to perform the Technical Safety Requirement (TSR) for [ ] gas monitoring. The initial potential noncompliance occurred in January 2000, in which a Zip Cord was installed

206

Observation of CH4 and other Non-CO2 Green House Gas Emissions from California  

Science Conference Proceedings (OSTI)

In 2006, California passed the landmark assembly bill AB-32 to reduce California's emissions of greenhouse gases (GHGs) that contribute to global climate change. AB-32 commits California to reduce total GHG emissions to 1990 levels by 2020, a reduction of 25 percent from current levels. To verify that GHG emission reductions are actually taking place, it will be necessary to measure emissions. We describe atmospheric inverse model estimates of GHG emissions obtained from the California Greenhouse Gas Emissions Measurement (CALGEM) project. In collaboration with NOAA, we are measuring the dominant long-lived GHGs at two tall-towers in central California. Here, we present estimates of CH{sub 4} emissions obtained by statistical comparison of measured and predicted atmospheric mixing ratios. The predicted mixing ratios are calculated using spatially resolved a priori CH{sub 4} emissions and surface footprints, that provide a proportional relationship between the surface emissions and the mixing ratio signal at tower locations. The footprints are computed using the Weather Research and Forecast (WRF) coupled to the Stochastic Time-Inverted Lagrangian Transport (STILT) model. Integral to the inverse estimates, we perform a quantitative analysis of errors in atmospheric transport and other factors to provide quantitative uncertainties in estimated emissions. Regressions of modeled and measured mixing ratios suggest that total CH{sub 4} emissions are within 25% of the inventory estimates. A Bayesian source sector analysis obtains posterior scaling factors for CH{sub 4} emissions, indicating that emissions from several of the sources (e.g., landfills, natural gas use, petroleum production, crops, and wetlands) are roughly consistent with inventory estimates, but livestock emissions are significantly higher than the inventory. A Bayesian 'region' analysis is used to identify spatial variations in CH{sub 4} emissions from 13 sub-regions within California. Although, only regions near the tower are significantly constrained by the tower measurements, CH{sub 4} emissions from the south Central Valley appear to be underestimated in a manner consistent with the under-prediction of livestock emissions. Finally, we describe a pseudo-experiment using predicted CH{sub 4} signals to explore the uncertainty reductions that might be obtained if additional measurements were made by a future network of tall-tower stations spread over California. These results show that it should be possible to provide high-accuracy estimates of surface CH{sub 4} emissions for multiple regions as a means to verify future emissions reductions.

Fischer, Marc L.; Zhao, Chuanfeng; Riley, William J.; Andrews, Arlyn C.

2009-01-09T23:59:59.000Z

207

Mechanistic Investigation of Acid-Catalyzed Cleavage of Aryl-Ether Linkages: Implications for Lignin Depolymerization  

SciTech Connect

Carbon-oxygen bonds are the primary inter-monomer linkages lignin polymers in plant cell walls, and as such, catalyst development to cleave these linkages is of paramount importance to deconstruct biomass to its constituent monomers for the production of renewable fuels and chemicals. For many decades, acid catalysis has been used to depolymerize lignin. Lignin is a primary component of plant cell walls, which is connected primarily by aryl-ether linkages, and the mechanism of its deconstruction by acid is not well understood, likely due to its heterogeneous and complex nature compared to cellulose. For effective biomass conversion strategies, utilization of lignin is of significant relevance and as such understanding the mechanisms of catalytic lignin deconstruction to constituent monomers and oligomers is of keen interest. Here, we present a comprehensive experimental and theoretical study of the acid catalysis of a range of dimeric species exhibiting the b-O-4 linkage, the most common inter-monomer linkage in lignin. We demonstrate that the presence of a phenolic species dramatically increases the rate of cleavage in acid at 150 degrees C. Quantum mechanical calculations on dimers with the para-hydroxyl group demonstrate that this acid-catalyzed pathway differs from the nonphenolic dimmers. Importantly, this result implies that depolymerization of native lignin in the plant cell wall will proceed via an unzipping mechanism wherein b-O-4 linkages will be cleaved from the ends of the branched, polymer chains inwards toward the center of the polymer. To test this hypothesis further, we synthesized a homopolymer of b-O-4 with a phenolic hydroxyl group, and demonstrate that it is cleaved in acid from the end containing the phenolic hydroxyl group. This result suggests that genetic modifications to lignin biosynthesis pathways in plants that will enable lower severity processes to fractionate lignin for upgrading and for easier access to the carbohydrate fraction of the plant cell wall.

Sturgeon, M. R.; Kim, S.; Chmely, S. C.; Foust, T. D.; Beckham, G. T.

2013-01-01T23:59:59.000Z

208

The lightness of being: mass, ether, and unification of the forces  

SciTech Connect

How can an electron be both a wave and a particle? At the same time? Because it is a quantum field. That key insight seems to be underappreciated, given the awe and mysticism that permeate most nontechnical discussions of modern physics. Perhaps the root of the problem is that most popularizations of quantum mechanics and of particle physics shy away from quantized fields, the natural language for microscopic phenomena. In 'The Lightness of Being: Mass, Ether, and the Unification of Forces', Frank Wilczek confronts quantum field theory head on, demystifying not only wave-particle duality but also the origin of mass for hadrons (that is, everyday matter). Wilczek is the Herman Feshbach Professor of Physics at MIT and a co-recipient of the 2004 Nobel Prize in Physics. His research has spanned almost all aspects of theoretical particle physics, with significant forays into condensed-matter physics and dense nuclear matter (condensed quark matter, one might say). Recurring themes are the richness of quantum chromodynamics (QCD) and the alluring ideas of unification. His breadth and depth make him a sought after speaker for colloquia and public lectures. Wilczek also contributes an occasional Reference Frame column to 'Physics Today'. The material in 'The Lightness of Being' reflects the scope of the author's research. The book consists of three parts: the quantum fields of QCD (the ether that makes mass), gravitation (the ether that feels mass), and unification. Part 1, which traces notions of mass from Isaac Newton's time through theoretical and computational results of the past 40 years, is the most substantial and original; it is rich, modern, and rooted in observed phenomena. Part 2 continues in the same vein as it connects gravity, also an observed phenomenon, to QCD. Part 3 is more conventional, for a popularization of particle physics, in its focus on speculative ideas that (still) await direct experimental tests. Readers of 'Physics Today' will know that Wilczek can write with wit, grace, and an uncanny facility for using lightweight language to express heavy-duty ideas. They will find much of that kind of writing in 'The Lightness of Being'. Wilczek addresses subtle ideas with vim and vigor. He avoids some of the jargon of quantum field theory; for example, he calls the vertex in a Feynman diagram a hub. In more ambitious terminology, he refers to space-filling, everfluctuating quantum fields--be they electrons, quarks, gluons, or gravity--as 'the Grid'. The term is supposed to be short and familiar, evoking the ubiquitous electric grid (and soon-to-beubiquitous computing grid). It also, for the expert, cleverly alludes to lattice gauge theory. Indeed, after vividly explaining how the dynamics of QCD and the constraints of Heisenberg uncertainty conspire to create mass from the Grid, Wilczek emphasizes that the picture is backed by lattice QCD computations of 'heroic' proportions. Unfortunately, too much of 'The Lightness' is laden with clunky affectation: silly names (a pulsed electron accelerator is called the 'ultrastroboscopic nanomicroscope'), sophomoric jokes ('hadron' is 'not a typo'), references to pop culture (Wilczek might have called quantum fields 'the Matrix, but the sequels tarnished that candidate'), and many pointless footnotes. In a public lecture the audience may guffaw at such jokes, but on the printed page they fall flat. Wilczek explains physics so well that the inappropriate humor is the biggest unexplained puzzle of the book. It is fine to be silly, even crude, as long as the reader's path to understanding is made easier. A joke can inform with an unexpected perspective or simply give the mind a pause to refresh. Some of the humor achieves such aims, but too many gags impede the pace of the otherwise fine exposition. Three appendices, a glossary, and a set of endnotes are crisp and sober. They are excellent. 'The Lightness of Being' is not unbearable, but it is weighed down with too much clutter to rank as a masterpiece. It's a pity: Wilczek's best writing--some of it in this book--is l

Kronfeld, Andreas S.

2009-03-01T23:59:59.000Z

209

A facility design for repackaging ORNL CH-TRU legacy waste in Building 3525  

Science Conference Proceedings (OSTI)

For the last 25 years, the Oak Ridge National Laboratory (ORNL) has conducted operations which have generated solid, contact-handled transuranic (CH-TRU) waste. At present the CH-TRU waste inventory at ORNL is about 3400 55-gal drums retrievably stored in RCRA-permitted, aboveground facilities. Of the 3400 drums, approximately 2600 drums will need to be repackaged. The current US Department of Energy (DOE) strategy for disposal of these drums is to transport them to the Waste Isolation Pilot Plant (WIPP) in New Mexico which only accepts TRU waste that meets a very specific set of criteria documented in the WIPP-WAC (waste acceptance criteria). This report describes activities that were performed from January 1994 to May 1995 associated with the design and preparation of an existing facility for repackaging and certifying some or all of the CH-TRU drums at ORNL to meet the WIPP-WAC. For this study, the Irradiated Fuel Examination Laboratory (IFEL) in Building 3525 was selected as the reference facility for modification. These design activities were terminated in May 1995 as more attractive options for CH-TRU waste repackaging were considered to be available. As a result, this document serves as a final report of those design activities.

Huxford, T.J.; Cooper, R.H. Jr.; Davis, L.E.; Fuller, A.B.; Gabbard, W.A.; Smith, R.B. [Oak Ridge National Lab., TN (United States); Guay, K.P. [S. M. Stroller Corp. (United States); Smith, L.C. [United Energy Services Corp. (United States)

1995-07-01T23:59:59.000Z

210

Louisiana oyster CuLtCh ProjeCt General Project DescriPtion  

E-Print Network (OSTI)

secondary production. estiMateD cost The estimated cost to implement the Louisiana Oyster Cultch Project is $15,582,600. (Estimated costs for some of the projects were updated from those provided in the DERPLouisiana oyster CuLtCh ProjeCt General Project DescriPtion The Louisiana Oyster Cultch Project

211

Applications of the InChI in cheminformatics with the CDK and Bioclipse  

E-Print Network (OSTI)

to enable exchange and linking of chemical information. The IUPAC Chemi- cal Identifier (InChI) [1] is such a standardized identifier for chemical structures, which lately has seen a great adoption in the cheminformatics community [2]. A recent special issue...

Spjuth, Ola; Berg, Arvid; Adams, Samuel; Willighagen, Egon L

2013-03-13T23:59:59.000Z

212

CH2M Hill Hanford Group Inc (CHG) Information Resource Management (IRM) Strategic Plan  

SciTech Connect

The CH2M HILL Hanford Group, Inc. (CHG), Information Resource Management Strategic Plan is the top-level planning document for applying information and information resource management to achieve the CHG mission for the management of the River Protection Project waste tank farm.

NELSON, R.L.

2000-06-06T23:59:59.000Z

213

Study on CO2 Reforming of CH4 by Dielectric Barrier Discharge  

Science Conference Proceedings (OSTI)

In this article it is demonstrated that DBD (dielectric barrier discharge) is an effective tool to convert CH4 and CO2 to synthesis gas (syngas, H2/CO) at low temperature and ambient pressure. The DBD is performed in the co-axial quartz cube by using ... Keywords: methane, carbon dioxide, syngas, dielectric barrier discharge

Zhao Yuhan

2011-03-01T23:59:59.000Z

214

Synthesis of Cyclic Aza-Ether Compounds and Studies of Their Use as Anion Receptors in Non-Aqueous Lithium Halide Salt Solutions  

DOE Green Energy (OSTI)

A series of new anion receptors, based on cyclic aza-ether compounds, have been synthesized. In all of these cyclic aza-ether compounds, the electron-withdrawing group CF{sub 3}SO{sub 2} was attached to each of the nitrogen atoms. When used as additives, all of them can significantly increase the ionic conductivity of lithium halide salts in THF solutions. This is due to the complexation between these compounds and halide anions. Ionic conductivity studies show that the complexation behavior is related to both the ring structure of the cyclic compounds and the characteristics of the halide anions. X-ray diffraction data show that the diffraction patterns of the complex crystals are different from the pure cyclic aza-ether compounds. New Bragg peaks representing a large d-spacing ({approx}15 {angstrom}) are observed for the complex crystals which provides a clear evidence for complexation.

Lee, H. S.; Sun, X.; Yang, X. Q.; McBreen, J.; Callahan, J. H.; Choi, L. S.

1999-11-01T23:59:59.000Z

215

ch_5  

NLE Websites -- All DOE Office Websites (Extended Search)

160 160 Environmental Consequences Under Clean Closure, radioactive and hazardous constituents would be removed from the site or treated so that residual contamination is no higher than background levels. This could require removal of all buildings, vaults, tanks, transfer piping, and contaminated soil. No post- closure monitoring would be required because potential sources of contamination would no longer be present. Unrestricted industrial use of clean-closed facilities and sites will be permissi- ble. Impacts to water resources would not be expected from the disposition of new facilities. For Performance-Based Closure, most above- ground structures would be razed and most below-ground structures (tanks, vaults, and transfer piping) would be decontaminated, stabi-

216

ch_3  

NLE Websites -- All DOE Office Websites (Extended Search)

47 47 DOE/EIS-0287 Idaho HLW & FD EIS has been provided to the public, committed DOE to restoring the existing contaminated groundwater plume outside the INTEC security fence to meet the current drinking water stan- dard of 4 millirem per year. A performance assessment would be developed for each facility or group of facilities under consideration for disposition, to determine which of the three disposition alternatives would be implemented. The performance assessment results would be used to identify the impact on the limited cumulative risk in the INTEC area resulting from residual contami- nation from all facilities. For facilities where a performance assessment is not necessary, resid- ual waste left in place would also be used to identify impacts on the limited cumulative risk

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10 10 Background 2.2 High-Level Waste Overview 2.2.1 HIGH-LEVEL WASTE DESCRIPTION According to Section 2(12) of the Nuclear Waste Policy Act (42 USC 10101), high-level radioac- tive waste means: In July 1999, DOE issued Order 435.1 Radioactive Waste Management. This Order and its associated Manual and Guidance set forth the authorities, responsibilities, and requirements for the management of DOE's inventory of HLW, transuranic waste, and low-level waste. Specific to HLW, DOE uses the Nuclear Waste Policy Act definition but has jurisdictional authority consistent with existing law to deter- mine if the waste requires permanent isolation as the appropriate disposal mechanism. This authority is based on enabling legislation in the Atomic Energy Act, sections 202(3) and 202(4)

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20 20 Affected Environment 4.6 Geology and Soils This section describes the geological, mineral resources, seismic, and volcanic characteristics of INEEL, INTEC, and surrounding areas. A more detailed description of geology at INEEL can be reviewed in the SNF & INEL EIS, Volume 2, Part A, Section 4.6 (DOE 1995). 4.6.1 GENERAL GEOLOGY INEEL occupies a relatively flat area on the northwestern edge of the Eastern Snake River Plain. Figure 4-4 shows important geological features of the INEEL area. The area consists of a broad plain that has been built up from the eruptions of multi- ple flows of basaltic lava, which is shown on Figure 4-5. The flows at the surface range in age from 1.2 million to 2,100 years. The Plain is bounded on the north and south by the north-to-north-

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HLW & FD EIS HLW & FD EIS 5-73 DOE/EIS-0287 tion dose to the nonin- volved worker and maximally exposed offsite individual and the collective dose to the population residing within 50 miles of INTEC. The radiation dose values for the var- ious alternatives were then multiplied by the dose-to-risk conversion factors, which are based on the 1993 Limitations of Exposure to Ionizing Radiation (NCRP 1993). DOE has adopted these risk fac- tors of 0.0005 and 0.0004 latent cancer fatality (LCF) for each person-rem of radiation exposure to the general public and worker popu- lation, respectively, for doses less than 20 rem. The factor for the population is slightly higher due to the presence of infants and children who are more sensitive to radiation than the adult worker population. DOE used radiation dose information provided

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45 45 DOE/EIS-0287 Idaho HLW & FD EIS 5.3.4.2 Existing Facilities Associated with High-Level Waste Management The facilities in this group are those that have historically been used at the INTEC to generate, treat, and store HLW. Because of the number of facilities involved, DOE has grouped them in functional groups for purposes of analysis (see Table 3-3). DOE analyzed the HLW tanks and bin sets for closure under all five disposition sce- narios; however, facilities that support the Tank Farm and bin sets were analyzed under a single disposition alternative. As shown in Table 3-3, the facility disposition alternative for most sup- porting facilities is Closure to Landfill Standards. (Two exceptions are the Liquid Effluent Treatment and Disposal Building and

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40 40 Affected Environment playas 15 to 20 miles northeast of INTEC, where the water infiltrates. The water in Birch Creek and the Little Lost River is diverted in summer months for irriga- tion prior to reaching INEEL. During periods of unusually high precipitation or rapid snow melt, water from Birch Creek and the Little Lost River may enter INEEL from the northwest and infil- trate the ground, recharging the underlying aquifer. 4.8.1.2 Local Drainage INTEC is located on an alluvial plain approxi- mately 200 feet from the Big Lost River channel near the channel intersection with Lincoln Boulevard on INEEL. INTEC is surrounded by a stormwater drainage ditch system (DOE 1998). Stormwater runoff from most areas of INTEC flows through the ditches to an abandoned gravel

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0 0 13.0 Index Index 13-1 DOE/EIS-0287 DOE/EIS-0287 13-2 Index A aesthetics - 3-54, 4-18, 4-35, 5-17, 5-18, 5-214, 5-232, 5-233, 9-9, 10-3, 10-7, C.2-4, C.8-13, C.8-32, C.8-46 airborne releases - 4-32, 4-71, 4-72, 5-48, 5-74, 5-87, 5-184, 5-225, C.2-13, C.2-17, C.8-16, C.8-36 aquifer - 2-30, 2-32, 2-33, 4-40, 4-47, 4-48, 4-49, 4-50, 4-51, 4-53, 4-54, 4-55, 4-56, 4-57, 4-72, 4-79, 5-2, 5-20, 5-44, 5-45, 5-107, 5-121, 5-122, 5-161, 5-165, 5-180, 5-212, 5-221, 5-222, 5-225, 5-227, 5-233, 5-234, 5-235, 6-15, 6-31, 6-32, 6-37, 7-3, 7-20, 7-24, 7-27, 7-29, 9-13, 9-14, 9-15, 11-18, 11-23, 11-24, 11-31, 11-54, 11-65, 11-73, 11-78, 11-79, 11-80, 11-82, 11-83, 11-84, 11-85, A-1, A-3, A-4, A-8, A-12, B-4, B-10, C.4-39, C.4-41, C.6-97, C.8-8, C.8-18, C.8-46, C.9-4, C.9-6, C.9-7, C.9-9, C.9-10,

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0 0 9.0 Re Re f f er er ences ences 9-1 DOE/EIS-0287 DOE/EIS-0287 9-2 References Chapter 1 DOE (U.S. Department of Energy), 1999, Record of Decision Idaho Nuclear Technology and Engineering Center Operable Unit 3-13, Idaho National Engineering and Environmental Laboratory, Idaho Falls, Idaho, DOE/ID-10660, Idaho Operations Office, Idaho Falls, Idaho, October. Kelly, K. B., 1999, State of Idaho, Office of Attorney General, Boise, Idaho, letter to B. Bowhan, U.S. Department of Energy, Idaho Operations Office, Idaho Falls, Idaho, transmitting "Third Modification to Consent Order," Idaho Code §39-4413, April 20. USDC (U.S. District Court for the District of Idaho), 1995, Public Service Company of Colorado v. Philip E. Batt, Civil No. 91-0035-S-EJL (Lead Case), Consent Order, October

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44 44 Environmental Consequences 5.2.7 WATER RESOURCES This section presents potential water resource impacts from implement- ing the proposed waste processing alternatives described in Chapter 3. Section 5.2.14 dis- cusses potential impacts to INEEL water resources from accidents or unusual natural phe- nomena such as earth- quakes. Appendix C.9 discusses potential long- term impacts to INEEL water resources from facility closure. Because the Minimum INEEL Processing Alternative would involve shipment of mixed HLW to the Hanford Site for treat- ment, possible impacts to water resources at Hanford were also evalu- ated (see Appendix C.8). Unless otherwise noted, however, the discussion of impacts presented in this section applies specifically to INEEL. 5.2.7.1 Methodology DOE assessed potential impacts by reviewing

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0 0 7.0 Glossar Glossar y y 7-1 DOE/EIS-0287 Terms in this glossary are defined based on the context in which they are to be used in this Environmental Impact Statement (EIS). - New Information - DOE/EIS-0287 7-2 Glossary 100-year flood A flood that occurs, on average, every 100 years (equates to a 1 percent probability of occurring in any given year). 500-year flood A flood that occurs, on average, every 500 years (equates to a 0.2 percent probability of occurring in any given year). accident An unplanned sequence of events that results in undesirable consequences. actinide Any of a series of chemically similar, mostly synthetic, radioactive elements with atomic numbers ranging from 89 (actinium-89) through 103 (lawrencium-103). Advanced Mixed Waste Treatment Project (AMWTP)

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47 47 DOE/EIS-0287 Idaho HLW & FD EIS 4.8.2 SUBSURFACE WATER Subsurface water at INEEL occurs in the under- lying Snake River Plain Aquifer and the vadose zone (area of unsaturated soil and material above the aquifer). This section describes the regional and local hydrogeology, vadose zone hydrology, perched water, and subsurface water quality. 4.8.2.1 Regional Hydrogeology INEEL overlies the Snake River Plain Aquifer as shown in Figure 4-12. This aquifer is the major source of drinking water for southeast- ern Idaho and has been desig- nated a Sole Source Aquifer by EPA. The aquifer flows to the south and southwest and covers an area of 9,611 square miles. Water storage in the aquifer is estimated at 2 billion acre-feet, and irrigation wells can yield 7,000 gallons per minute (DOE 1995). Depth to the

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0 0 11.0 Response Response to to P P ublic ublic Comment Comment 11-1 DOE/EIS-0287 11.1 Introduction This chapter provides responses from the U.S. Department of Energy (DOE) and the State of Idaho to public comments on the Draft Idaho High-Level Waste and Facilities Disposition Environmental Impact Statement (HLW & FD EIS) and identifies where those public comments led to changes to the EIS. The State of Idaho, a cooperating agency in the preparation of the EIS, participated in the process of reviewing, summarizing, and responding to comments. In addition, the State of Idaho responded to the comments that were directed specifically to the State. The following information identifies the opportunities for public comment and response format and provides information on how to find responses to each of the com-

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1998, INEEL 1998, INEEL contracts paid $1.4 million to the State of Idaho in Idaho sales taxes and an additional $0.9 million in Idaho franchise tax. 4.4 Cultural Resources 4.4.1 CULTURAL RESOURCE MANAGEMENT AND CONSULTATION AT INEEL Cultural resources at INEEL include archaeolog- ical and historic resources, such as prehistoric camp sites and historic buildings and trails, as well as the plants, animals, physical locations, and other features of INEEL environment impor- tant to the culture of the Shoshone-Bannock Tribes and to national, regional and local history. Several Federal laws, which are described in Chapter 6, govern the protection of archaeologi- cal and historic resources on lands managed by Federal agencies. These and other laws also require consultations among Federal agencies,

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0 0 3.0 Alterna Alterna tiv tiv es es 3-1 DOE/EIS-0287 This chapter describes the alternatives for waste processing and facility disposi- tion analyzed in this environmental impact statement (EIS) as well as alter- natives eliminated from detailed analy- sis. As required by the Council on Environmental Quality (CEQ) regula- tions implementing the National Environmental Policy Act (NEPA), a No Action alternative is also included. This chapter identifies the U.S. Department of Energy's (DOE's) Preferred Alternative as well as the State of Idaho's Preferred Alternative, which is different from that identified by DOE. Some of the alternatives include one or more options. The options are described in the context of the alternative(s) they fall under, but could be used or com-

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0 0 5.0 E E nvir nvir onmental onmental Consequences Consequences 5-1 DOE/EIS-0287 5.1 Introduction Chapter 5 describes the potential environ- mental consequences of implementing each of the alternatives described in Chapter 3. This Final EIS analyzes the alternatives in the Draft EIS and provides corrections and updates as needed. In addition, it analyzes the State of Idaho's Preferred Alternative, Direct Vitrification, and a new option of the Non-Separations Alternative, the Steam Reforming Option. Furthermore, the Minimum INEEL Processing Alternative has been modified, and other changes have been made to the analyses based on information received during the public comment period. DOE/EIS-0287 5-2 Environmental Consequences Environmental consequences of actions could include direct physical disturbance of resources,

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3-34 3-34 Alternatives transuranic waste/SBW. The EIS also presents the impacts for a grout facility (see Project P2001 in Appendix C.6) that could be used to treat the waste generated after 2005. For pur- poses of assessing transportation impacts, DOE assumed the grouted waste would be character- ized as remote-handled transuranic waste and transported to the Waste Isolation Pilot Plant for disposal (see Appendix C.5). 3.2 Facility Disposition Alternatives The waste processing alternatives described in Section 3.1 do not include any specific facility disposition alternatives except for those cases where facility disposition is an integral part of implementation of the option (e.g., disposal of low-level waste Class A or Class C type grout in the Tank Farm and bin sets). However, DOE

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4 4 Background 2.1.3 CURRENT MISSION The current INEEL mission is to develop, demonstrate, and deploy advanced engineering technology and systems to improve national competitiveness and security, to make the pro- duction and use of energy more efficient, and to improve the quality of the environment. Areas of primary emphasis at INEEL include waste management and waste minimization, environ- mental engineering and restoration, energy effi- ciency, renewable energy, national security and defense, nuclear technologies, and advanced technologies and methods. INEEL is the lead laboratory for the National Spent Nuclear Fuel Management Program, which sets standards for developing and maintaining the capability to safely manage DOE's spent nuclear fuel. DOE considers the Environmental Management

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0 0 12.0 Distribution Distribution List List - New Information - 12-1 DOE/EIS-0287 The U.S. Department of Energy (DOE) pro- vided copies of this Final Environmental Impact Statement (EIS) to Federal, state, and local elected and appointed officials and agencies of government; Native American groups; national, state, and local environmental and public interest groups; and other organizations and individuals list- ed below. In addition, DOE sent copies of the Final EIS to all persons who comment- ed on the Idaho High-Level Waste and Facilities Disposition Draft Environmental Impact Statement; these individuals are list- ed in the Index (Alphabetical List of Commentors by Name) in Chapter 11 of this Final EIS. Other groups that received copies of the Final EIS but are not listed

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71 71 DOE/EIS-0287 Idaho HLW & FD EIS university research programs and private con- tractors. Ongoing studies by the Centers for Disease Control and Prevention, an agency of the U.S. Department of Health and Human Services, also carefully tracks possible health effects from past activities at INEEL. 4.11.1.1 Radiological Health Risk Very low doses of radiation are not known to cause health effects in humans; however, extrapolation of the dose-response relationship from high doses indicates that statistical effects might be observed in large populations. The doses reported in this EIS from INEEL opera- tions are in this very low category. This EIS reports two values: col- lective dose (in person- rem) and the hypothetical number of latent cancer fatalities. For effects on

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0 0 6.0 Sta Sta tutes tutes , , Regula Regula tions tions , , Consulta Consulta tions tions , , and Other and Other Requir Requir ements ements 6-1 DOE/EIS-0287 This chapter discusses the consultations and coordination the U.S. Department of Energy (DOE) has had with various agen- cies during the preparation of this Environmental Impact Statement (EIS). This chapter also analyzes the complex regulatory issues that arise when consider- ing the various alternatives discussed pre- viously. When reviewing this chapter, it is impor- tant to remember the following: in the Purpose and Need discussion in Chapter 2 of this EIS, DOE has described the chal- lenges it faces with its mixed high-level waste (HLW) at the Idaho National Engineering and Environmental Laboratory (INEEL) and its additional

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22 22 5.2.6 AIR RESOURCES Air pollutant emissions associated with construction and operation of facilities to support the waste processing al- ternatives could affect the air resources in the region of the INEEL. DOE characterized air emission rates and calculated maximum consequences at onsite and offsite locations from projects associated with proposed waste processing alternatives. The assessments include emis- sions from stationary sources (facility stacks); fugitive sources from construction activities; and mobile sources (trucks, cranes, tractors, etc.) that would operate in sup- port of projects under each waste processing alternative. The types of emissions assessed are the same as those in the baseline assessment in Section 4.7, Air Resources, namely, radionuclides, criteria pollutants (carbon

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ansuranic w a s t e M i x e d tr ansuranic w a s t e LEGEND Mixed transuranic waste sodium-bearing waste Waste Isolation Pilot Plant Newly generated liquid waste NGLW SBW...

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S1W Naval Nuclear Reactor Prototype Project Officer 29 years; including experience in Nuclear Power Plant Operations and maintenance, radioactive and hazardous materials...

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near the site are Idaho Falls and Rexburg to the east, Blackfoot to the southeast, Atomic City to the south, Pocatello and the Fort Hall Indian Reservation to the...

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include Mud Lake and Terreton to the east; Arco, Butte City, and Howe to the west; and Atomic City to the south. The larger com- munities of Idaho Falls, Rexburg, Rigby,...

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While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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13 DOEEIS-0287 Idaho HLW & FD EIS except the pillar and panel tanks) would be full of mixed transuranic waste in approximately 2017. Other facilities depending on the capacity of...

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Lead Federal Agency: U.S. Department of Energy (DOE) Cooperating Agency: The State of Idaho Title: Contact: For additional information on this EIS and the tribal, agency and...

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of Energy (DOE) and its predecessor agencies reprocessed spent nuclear reac- tor fuel at the Idaho Chemical Processing Plant, located on the Snake River Plain in the desert...

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58 58 Affected Environment 4.9.1 PLANT COMMUNITIES AND ASSOCIATIONS INEEL lies within a cool desert ecosystem dom- inated by shrub-steppe vegetation. The area is relatively undisturbed, providing important habi- tat for species native to the region. Vegetation and habitat on INEEL can be grouped into six types: shrub-steppe, juniper woodlands, native grasslands, modified ephemeral playas, lava, and wetland-like areas. Figure 4-16 shows these areas. More than 90 percent of INEEL falls within the shrub-steppe vegetation type. The shrub-steppe vegetation type is dominated by sagebrush (Artemisia spp.), saltbush (Atriplex spp.), and rabbitbrush (Chrysothamnus spp.). Grasses found on INEEL include cheatgrass (Bromus tectorum), Indian ricegrass (Oryzopsis hymenoides), wheatgrass (Agropyron spp.), and

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25 25 DOE/EIS-0287 Idaho HLW & FD EIS 5.3 Facility Disposition Impacts Section 5.3 presents a discussion of potential impacts associated with the disposition of exist- ing HLW management facilities at INEEL and disposition of new facilities that would be built in support of the proposed waste processing alternatives. The discussion includes (1) the potential impacts of short-term actions in dispo- sitioning new and existing HLW management facilities, (2) the potential long-term impacts from the disposal of the grouted low-level waste fraction in either a new disposal facility at INTEC or in the Tank Farm and bin sets, and (3) the potential long-term impacts of residual con- tamination in closed HLW management facili- ties. The six facility disposition alternatives are

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towers that reach 250 feet. 4.5 Aesthetic and Scenic Resources This section describes a baseline visual character of INEEL and the surrounding area, including designated scenic...

247

xml version="1.0" encoding="UTF-8"?>

Note: This page contains sample records for the topic "butyl ether ch" from the National Library of EnergyBeta (NLEBeta).
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they are not comprehensive nor are they the most current set.
We encourage you to perform a
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261

Preliminary Notice of Violation, CH2M Hill Hanford Group, Inc - EA-2005-01  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Inc - Inc - EA-2005-01 Preliminary Notice of Violation, CH2M Hill Hanford Group, Inc - EA-2005-01 March 10, 2005 Preliminary Notice of Violation issued to CH2M Hill Hanford Group, Inc., related to Radiological and Operational Events at the Hanford Tank Farms This letter refers to the recent investigation by the Department of Energy's (DOE) Office of Price-Anderson Enforcement (OE) at the Hanford Tank Farms of four radiological and operational events occurring during 2003 and 2004. The events included (1) the June 2003 multiple personnel contamination event at the [ ]; (2) the November 2003 Technical Safety Requirement violation during a cross-site waste transfer; (3) the November 2003 valve positioning error during S-112 waste retrieval operations; and (4) the July 2004 extremity exposure during hermocouple removal activities.

262

New directions for QA in basic research: The Fermilab/DOE-CH experience  

SciTech Connect

This paper addresses the underlying problems involved in developing institution-wide QA programs at DOE funded basic research facilities, and suggests concrete ways in which QA professionals and basic researchers can find common ground in describing and analyzing those activities to the satisfaction of both communities. The paper is designed to be a springboard into workshop discussions which can define a path for developing institution-wide QA programs based on the experience gained with DOE-CH and Fermilab.

Bodnarczuk, M.

1989-09-01T23:59:59.000Z

263

Charge-Separation in Uranium Diazomethane Complexes Leading to C-H Activation and Chemical Transformation  

E-Print Network (OSTI)

Charge-Separation in Uranium Diazomethane Complexes Leading to C-H Activation and Chemical of diphenyldiazomethane with [((t-Bu ArO)3tacn)UIII ] (1) results in an 2 -bound diphenyldiazomethane uranium complex-shell ligand, [((t-Bu ArO)3tacn)UIV (2 -NNCPh2)] (2). Treating Ph2CN2 with a uranium complex that contains

Meyer, Karsten

264

Instructor's Name Email Address Office Hours Allen, Chris christopherallen@pdx.edu W 3:00-4:00pm CH 366  

E-Print Network (OSTI)

Instructor's Name Email Address Office Hours Office Location Allen, Chris christopherallen CH 361 Fall 2011 Instructor Office Hours #12;Pickett-Cooper, Patty pickettp@pdx.edu F 11:30-1:30pm CH

265

The Effect of Time dealumination and Solvent Concentration in Synthesis of Zeolite Catalyst and Catalytic Test for DiEthyl Ether Production Process  

Science Conference Proceedings (OSTI)

Ethanol is an alternative energy, but its has three distinct disadvantages as a transportation fuel. Its availability is currently limited, and it has a lower volumetric heating value and a lower Reid vapour pressure (RVP) than gasoline. This paper focuses for this disadvantages and to solve this problem can do with converts ethanol to DiEthyl Ether product. This research produced DiEthyl Ether by ethanol dehydration process with zeolite as catalyst. The catalyst synthesis from natural material from District Gunung Kidul, Indonesia. The catalyst produced with dealumination, neutralization, drying and calcination processes. The zeolite catalyst was analysed of Si/Al, X-ray Diffraction and specific surface area. The catalyst product then used for ethanol dehydration to produce DiEthyl Ether. The results shown the biggest surface area is 184,52 m{sup 2}/gram at catalyst production at 10 hours for time dealumination. The crystallite of catalyst product is similar like shown at diffractogram of XRD analysis. The ratio Si/Al biggest is 313.7 that obtaining at catalyst production with 7 hours for time dealumination. The catalytic test use fixed bed reactor with 1 inci diameter and ethanol fermentation both as feed. The operation condition is 150 deg. C at temperature and atmosphere pressure. The compounds product in liquid phase are diethyl ether, methanol and water.

Widayat [Department of Chemical Engineering, Faculty of Engineering Diponegoro University, Department of Chemical Engineering, Faculty of Industry Technology Institute of Technology Sepuluh Nopember Surabaya Indonesia, Kampus Sukolilo Surabaya Indonesia (Indonesia); Roesyadi, A.; Rachimoellah, M. [Department of Chemical Engineering, Faculty of Industry Technology Institute of Technology Sepuluh Nopember Surabaya Indonesia, Kampus Sukolilo Surabaya Indonesia (Indonesia)

2009-09-14T23:59:59.000Z

266

Instructor's Name Email Address Office Hours Alvarado, Jimena jimena@pdx.edu W 9:00-10:00am CH 368  

E-Print Network (OSTI)

:00-5:30pm CH 366 Olmsted, John (TA - Chris Harper) olmstedj@pdx.edu M 4:30-5:30pm CH 311 Spring 2011 Instructor Office Hours #12;Patka, Mazna (TA - Colleen Kidney) mpatka@pdx.edu TR 10:00-11:00am CH 367 Pickett

267

[(CH3)4N][(C5H5NH)0.8((CH3)3NH)0.2]U2Si9O23F4 (USH-8): An Organically Templated Open-Framework Uranium Silicate  

E-Print Network (OSTI)

-Framework Uranium Silicate Xiqu Wang, Jin Huang, and Allan J. Jacobson* Department of Chemistry, Uni pyramids we obtained also a number of open-framework uranium silicates.18,19 These new compounds were-framework uranium fluorosilicate [(CH3)4N][(C5H5NH)0.8((CH3)3NH)0.2]U2Si9O23F4 (USH- 8) that has been synthesized

Wang, Xiqu

268

U.S. Department of Energy, Oak Ridge Office and URS/CH2M Oak Ridge, LLC  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

U.S. Department of Energy, Oak Ridge Office and URS/CH2M Oak Ridge, U.S. Department of Energy, Oak Ridge Office and URS/CH2M Oak Ridge, LLC (UCOR) East Tennessee Technology Park (ETTP) Contract Partnering Agreement U.S. Department of Energy, Oak Ridge Office and URS/CH2M Oak Ridge, LLC (UCOR) East Tennessee Technology Park (ETTP) Contract Partnering Agreement The Partnering Team will complete the cleanup, reindustrialize ETTP and continue Environmental Management (EM) activities currently ongoing at ORNL and Y-12. This work will be accomplished in a safe and quality manner with a goal of completion under budget and ahead of schedule. U.S. Department of Energy, Oak Ridge Office and URS/CH2M Oak Ridge, LLC (UCOR) East Tennessee Technology Park (ETTP) Contract Partnering Agreement More Documents & Publications Contractor Fee Payments - Oak Ridge Operations

269

Joint Test Plan to Identify the Gaseous By-Products of CH3I Loading on AgZ  

SciTech Connect

The objective of this test plan is to describe research to determine the gaseous by-products of the adsorption of CH3I on hydrogen reduced silver exchanged mordenite (AgZ).

R. T. Jubin; N. R. Soelberg; D. M. Strachan; T. M. Nenoff; B. B. Spencer

2012-12-01T23:59:59.000Z

270

Mathematical simulation and X-ray diffraction investigation of the crystal structure of 1-phenyl-1-tert-butyl-3-methyl-1,3-dihydroisobenzofuran  

SciTech Connect

An algorithm for using a priori generation of crystal structures by the discrete modeling method for the interpretation of data obtained from single-crystal X-ray diffraction experiments is considered. The crystal structure of 1-phenyl-1-tert-butyl-3-methyl-1,3-dihydroisobenzofuran is mathematically simulated using the discrete modeling of molecular packings and studied by X-ray diffraction. The simulation is performed for two isomers of the initial chemical compound that are possible from the viewpoint of the mechanism of the chemical reaction used in the synthesis of this compound. Appropriate models that can serve as starting models for solving and refining the crystal structure with the use of X-ray diffraction data are chosen from a complete set of calculated structural models in accordance with specific criteria. The structure is solved using a starting model calculated using the discrete modeling method and refined by the full-matrix least-squares procedure.

Maleev, A. V., E-mail: andr_mal@mail.ru; Zhitkov, I. K.; Potekhin, K. A. [Vladimir State Pedagogical University (Russian Federation)

2008-07-15T23:59:59.000Z

271

Single-Step Syngas-to-Distillates (S2D) Synthesis via Methanol and Dimethyl Ether Intermediates: Final Report  

Science Conference Proceedings (OSTI)

The objective of the work was to enhance price-competitive, synthesis gas (syngas)-based production of transportation fuels that are directly compatible with the existing vehicle fleet (i.e., vehicles fueled by gasoline, diesel, jet fuel, etc.). To accomplish this, modifications to the traditional methanol-to-gasoline (MTG) process were investigated. In this study, we investigated direct conversion of syngas to distillates using methanol and dimethyl ether intermediates. For this application, a Pd/ZnO/Al2O3 (PdZnAl) catalyst previously developed for methanol steam reforming was evaluated. The PdZnAl catalyst was shown to be far superior to a conventional copper-based methanol catalyst when operated at relatively high temperatures (i.e., >300C), which is necessary for MTG-type applications. Catalytic performance was evaluated through parametric studies. Process conditions such as temperature, pressure, gas-hour-space velocity, and syngas feed ratio (i.e., hydrogen:carbon monoxide) were investigated. PdZnAl catalyst formulation also was optimized to maximize conversion and selectivity to methanol and dimethyl ether while suppressing methane formation. Thus, a PdZn/Al2O3 catalyst optimized for methanol and dimethyl ether formation was developed through combined catalytic material and process parameter exploration. However, even after compositional optimization, a significant amount of undesirable carbon dioxide was produced (formed via the water-gas-shift reaction), and some degree of methane formation could not be completely avoided. Pd/ZnO/Al2O3 used in combination with ZSM-5 was investigated for direct syngas-to-distillates conversion. High conversion was achieved as thermodynamic constraints are alleviated when methanol and dimethyl are intermediates for hydrocarbon formation. When methanol and/or dimethyl ether are products formed separately, equilibrium restrictions occur. Thermodynamic relaxation also enables the use of lower operating pressures than what would be allowed for methanol synthesis alone. Aromatic-rich hydrocarbon liquid (C5+), containing a significant amount of methylated benzenes, was produced under these conditions. However, selectivity control to liquid hydrocarbons was difficult to achieve. Carbon dioxide and methane formation was problematic. Furthermore, saturation of the olefinic intermediates formed in the zeolite, and necessary for gasoline production, occurred over PdZnAl. Thus, yield to desirable hydrocarbon liquid product was limited. Evaluation of other oxygenate-producing catalysts could possibly lead to future advances. Potential exists with discovery of other types of catalysts that suppress carbon dioxide and light hydrocarbon formation. Comparative techno-economics for a single-step syngas-to-distillates process and a more conventional MTG-type process were investigated. Results suggest operating and capital cost savings could only modestly be achieved, given future improvements to catalyst performance. Sensitivity analysis indicated that increased single-pass yield to hydrocarbon liquid is a primary need for this process to achieve cost competiveness.

Dagle, Robert A.; Lebarbier, Vanessa MC; Lizarazo Adarme, Jair A.; King, David L.; Zhu, Yunhua; Gray, Michel J.; Jones, Susanne B.; Biddy, Mary J.; Hallen, Richard T.; Wang, Yong; White, James F.; Holladay, Johnathan E.; Palo, Daniel R.

2013-11-26T23:59:59.000Z

272

Stability of metal nanowires at ultrahigh current densities C.-H. Zhang, J. Brki, and C. A. Stafford  

E-Print Network (OSTI)

. Stafford Department of Physics, University of Arizona, 1118 E. 4th Street, Tucson, Arizona 85721, USA by an effective one-dimensional potential C.-H. ZHANG, J. B?RKI AND C. A. STAFFORD PHYSICAL REVIEW B 71, 235404 of the wire. C.-H. ZHANG, J. B?RKI AND C. A. STAFFORD PHYSICAL REVIEW B 71, 235404 2005 235404-4 #12;GS = G0 k

Stafford, Charles

273

Thermal decomposition of CH{sub 3}CHO studied by matrix infrared spectroscopy and photoionization mass spectroscopy  

Science Conference Proceedings (OSTI)

A heated SiC microtubular reactor has been used to decompose acetaldehyde and its isotopomers (CH{sub 3}CDO, CD{sub 3}CHO, and CD{sub 3}CDO). The pyrolysis experiments are carried out by passing a dilute mixture of acetaldehyde (roughly 0.1%-1%) entrained in a stream of a buffer gas (either He or Ar) through a heated SiC reactor that is 2-3 cm long and 1 mm in diameter. Typical pressures in the reactor are 50-200 Torr with the SiC tube wall temperature in the range 1200-1900 K. Characteristic residence times in the reactor are 50-200 {mu}s after which the gas mixture emerges as a skimmed molecular beam at a pressure of approximately 10 {mu}Torr. The reactor has been modified so that both pulsed and continuous modes can be studied, and results from both flow regimes are presented. Using various detection methods (Fourier transform infrared spectroscopy and both fixed wavelength and tunable synchrotron radiation photoionization mass spectrometry), a number of products formed at early pyrolysis times (roughly 100-200 {mu}s) are identified: H, H{sub 2}, CH{sub 3}, CO, CH{sub 2}=CHOH, HC{identical_to}CH, H{sub 2}O, and CH{sub 2}=C=O; trace quantities of other species are also observed in some of the experiments. Pyrolysis of rare isotopomers of acetaldehyde produces characteristic isotopic signatures in the reaction products, which offers insight into reaction mechanisms that occur in the reactor. In particular, while the principal unimolecular processes appear to be radical decomposition CH{sub 3}CHO (+M) {yields} CH{sub 3}+ H + CO and isomerization of acetaldehyde to vinyl alcohol, it appears that the CH{sub 2}CO and HCCH are formed (perhaps exclusively) by bimolecular reactions, especially those involving hydrogen atom attacks.

Vasiliou, AnGayle K. [Department of Chemistry and Biochemistry, University of Colorado, Boulder, Colorado 80309-0215 (United States); National Renewable Energy Laboratory, 1617 Cole Blvd., Golden, Colorado 80401 (United States); Piech, Krzysztof M.; Reed, Beth; Ellison, G. Barney [Department of Chemistry and Biochemistry, University of Colorado, Boulder, Colorado 80309-0215 (United States); Zhang Xu [Jet Propulsion Laboratory, California Institute of Technology, 4800 Oak Grove Drive, Pasadena, California 91109-8099 (United States); Nimlos, Mark R. [National Renewable Energy Laboratory, 1617 Cole Blvd., Golden, Colorado 80401 (United States); Ahmed, Musahid; Golan, Amir; Kostko, Oleg [Chemical Sciences Division, LBNL MS 6R-2100, Berkeley, California 94720 (United States); Osborn, David L. [Combustion Research Facility, Sandia National Laboratories, P.O. Box 969 MS 9055, Livermore, California 94551-0969 (United States); David, Donald E. [Integrated Instrument Design Facility, CIRES, University of Colorado, Boulder, Colorado 80309-0216 (United States); Urness, Kimberly N.; Daily, John W. [Center for Combustion and Environmental Research, Department of Mechanical Engineering, University of Colorado at Boulder, Boulder, Colorado 80309-0427 (United States); Stanton, John F. [Institute for Theoretical Chemistry, Department of Chemistry, University of Texas, Austin, Texas 78712 (United States)

2012-10-28T23:59:59.000Z

274

Competition between C-C and C-H Activation in Reactions of Neutral Yttrium Atoms with Cyclopropane and Propene  

E-Print Network (OSTI)

Biology, Cornell UniVersity, Ithaca, New York 14853 ReceiVed: February 22, 2003; In Final Form: August 25, 2003 Branching ratios between C-C and C-H bond activation were measured for reactions of ground-state Y to or even lower than those for C-H insertion.8 For example, reactions of Fe+, Co+, and Ni+ with propane led

Davis, H. Floyd

275

Vibrational relaxation of matrix-isolated CH/sub 3/F and HCl  

SciTech Connect

Kinetic and spectroscopic studies have been performed on CH/sub 3/F and HCl as a function of host matrix and temperature. Temporally and spectrally resolved infrared fluorescence was used to monitor the populations of both the initially excited state and the lower lying levels which participate in the relaxation process. For CH/sub 3/F, relaxation from any of the levels near 3.5 ..mu.., i.e. the CH stretching fundamentals or bend overtones, occurs via rapid (< 5 ns) V ..-->.. V transfer to 2..nu../sub 3/ with subsequent relaxation of the ..nu../sub 3/ (CF stretch) manifold. Lifetimes of 2..nu../sub 3/ and ..nu../sub 3/ were determined through overtone, ..delta..V = 2, and fundamental fluorescence. These lifetimes show a dramatic dependence on host lattice, an increase of two orders of magnitude in going from Xe and Ar matrices. Lifetimes depend only weakly on temperature. The relaxation of 2..nu../sub 3/ and ..nu../sub 3/ is consistent with a model in which production of a highly rotationally excited guest via collisions with the repulsive wall of the host is the rate limiting step. For HCl, lifetimes of v = 1,2,3 have been determined. In all hosts, the relaxation is non-radiative. For a given vibrational state, v, the relaxation rate increases in the series k(Ar) < k(Kr) < k(Xe). The dependence of the relaxation rate; on v is superlinear in all matrices, the deviation from linearity increasng in the order Ar < Kr < Xe. The relaxation rates become more strongly temperature dependent with increasing vibrational excitation. The results are consistent with a mechanism in which complex formation introduces the anisotropy necessary to induce a near resonant V ..-->.. R transition in the rate limiting step.

Young, L.

1981-08-01T23:59:59.000Z

276

Ed Jascevsky Safety Division ChIcago Operations Office MIT CONTFACT INFCE"ATION  

Office of Legacy Management (LM)

;/:4,4 (; . 1.; ;/:4,4 (; . 1.; e octo: ' J : 18, 1976 Ed Jascevsky Safety Division ChIcago Operations Office MIT CONTFACT INFCE"ATION During the discussions on October 8, 1976, you iquired about information relative to work done by MIT as background infomation for survey planning. The enclosed information is parephrased frorc an unpublished history of program work carried out by the Process Eevclopncnt Group of the Dl.ti,si.on of Raw Katerids, I believe this work was done under contract nuder AT(30-1)956. Robert IE. Allen Process Facilities Safety Branch Division of Safety, Standards, and Compliance Fnclosure: As stated I I . ..--@q$?.. .... ............................................ ........ ..- .......................... . ... ... .- ................... .._ ................ .... ..__ ..............

277

The Radiative Transfer Of CH{sub 4}-N{sub 2} Plasma Arc  

Science Conference Proceedings (OSTI)

Any physical modelling of a circuit-breaker arc therefore requires an understanding of the radiated energy which is taken into account in the form of a net coefficient. The evaluation of the net emission coefficient is performed by the knowledge of the chemical plasma composition and the resolution of the radiative transfer equation. In this paper, the total radiation which escapes from a CH{sub 4}-N{sub 2} plasma is calculated in the temperature range between 5000 and 30000K on the assumption of a local thermodynamic equilibrium and we have studied the nitrogen effect in the hydrocarbon plasmas.

Benallal, R. [Theoretical physics Laboratory, Physics Department of University Aboubekr Belkaied Tlemcen 13000 (Algeria); Liani, B. [Science Faculty, Hassiba Benbouali University, Chlef 02000 (Algeria)

2008-09-23T23:59:59.000Z

278

The kaon mass in 2+1+1 flavor twisted mass Wilson ChPT  

E-Print Network (OSTI)

We construct the chiral low-energy effective theory for 2+1+1 flavor lattice QCD with twisted mass Wilson fermions. In contrast to existing results we assume a heavy charm quark mass such that the D mesons are too heavy to appear as degrees of freedom in the effective theory. As an application we compute the kaon mass to 1-loop order in the LCE regime. The result contains a chiral logarithm involving the neutral pion mass which has no analogue in continuum ChPT.

Bar, Oliver

2013-01-01T23:59:59.000Z

279

Hydrogen Storage in Carbon Nanotubes Through Formation of C-H Bonds  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen Storage in Carbon Nanotubes Through Formation of C-H Bonds Print Hydrogen Storage in Carbon Nanotubes Through Formation of C-H Bonds Print Two of the major challenges for humanity in the next 20 years are the shrinking availability of fossil fuels and the global warming and potential climate changes that result from their ever-increasing use. One possible solution to these problems is to use an energy carrier such as hydrogen, and ways to produce and store hydrogen in electric power plants and vehicles is a major research focus for materials scientists and chemists. To realize hydrogen-powered transport, for example, it is necessary to find ways to store hydrogen onboard vehicles efficiently and safely. Nanotechnology in the form of single-walled carbon nanotubes provides a candidate storage medium. A U.S., German, and Swedish collaboration led by researchers from the Stanford Synchrotron Radiation Laboratory (SSRL) used ALS Beamline 11.0.2 and SSRL Beamline 5-1 to investigate the chemical interaction of hydrogen with single-walled carbon nanotubes (SWCNs). Their findings demonstrate substantial hydrogen storage is both feasible and reversible.

280

Hydrogen Storage in Carbon Nanotubes Through Formation of C-H Bonds  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen Storage in Carbon Nanotubes Through Formation of C-H Bonds Print Hydrogen Storage in Carbon Nanotubes Through Formation of C-H Bonds Print Two of the major challenges for humanity in the next 20 years are the shrinking availability of fossil fuels and the global warming and potential climate changes that result from their ever-increasing use. One possible solution to these problems is to use an energy carrier such as hydrogen, and ways to produce and store hydrogen in electric power plants and vehicles is a major research focus for materials scientists and chemists. To realize hydrogen-powered transport, for example, it is necessary to find ways to store hydrogen onboard vehicles efficiently and safely. Nanotechnology in the form of single-walled carbon nanotubes provides a candidate storage medium. A U.S., German, and Swedish collaboration led by researchers from the Stanford Synchrotron Radiation Laboratory (SSRL) used ALS Beamline 11.0.2 and SSRL Beamline 5-1 to investigate the chemical interaction of hydrogen with single-walled carbon nanotubes (SWCNs). Their findings demonstrate substantial hydrogen storage is both feasible and reversible.

Note: This page contains sample records for the topic "butyl ether ch" from the National Library of EnergyBeta (NLEBeta).
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281

Hydrogen Storage in Carbon Nanotubes Through Formation of C-H Bonds  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen Storage in Carbon Hydrogen Storage in Carbon Nanotubes Through Formation of C-H Bonds Hydrogen Storage in Carbon Nanotubes Through Formation of C-H Bonds Print Wednesday, 28 June 2006 00:00 Two of the major challenges for humanity in the next 20 years are the shrinking availability of fossil fuels and the global warming and potential climate changes that result from their ever-increasing use. One possible solution to these problems is to use an energy carrier such as hydrogen, and ways to produce and store hydrogen in electric power plants and vehicles is a major research focus for materials scientists and chemists. To realize hydrogen-powered transport, for example, it is necessary to find ways to store hydrogen onboard vehicles efficiently and safely. Nanotechnology in the form of single-walled carbon nanotubes provides a candidate storage medium. A U.S., German, and Swedish collaboration led by researchers from the Stanford Synchrotron Radiation Laboratory (SSRL) used ALS Beamline 11.0.2 and SSRL Beamline 5-1 to investigate the chemical interaction of hydrogen with single-walled carbon nanotubes (SWCNs). Their findings demonstrate substantial hydrogen storage is both feasible and reversible.

282

Hydrogen Storage in Carbon Nanotubes Through Formation of C-H Bonds  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen Storage in Carbon Nanotubes Through Formation of C-H Bonds Print Hydrogen Storage in Carbon Nanotubes Through Formation of C-H Bonds Print Two of the major challenges for humanity in the next 20 years are the shrinking availability of fossil fuels and the global warming and potential climate changes that result from their ever-increasing use. One possible solution to these problems is to use an energy carrier such as hydrogen, and ways to produce and store hydrogen in electric power plants and vehicles is a major research focus for materials scientists and chemists. To realize hydrogen-powered transport, for example, it is necessary to find ways to store hydrogen onboard vehicles efficiently and safely. Nanotechnology in the form of single-walled carbon nanotubes provides a candidate storage medium. A U.S., German, and Swedish collaboration led by researchers from the Stanford Synchrotron Radiation Laboratory (SSRL) used ALS Beamline 11.0.2 and SSRL Beamline 5-1 to investigate the chemical interaction of hydrogen with single-walled carbon nanotubes (SWCNs). Their findings demonstrate substantial hydrogen storage is both feasible and reversible.

283

Hydrogen Storage in Carbon Nanotubes Through Formation of C-H Bonds  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen Storage in Carbon Nanotubes Through Formation of C-H Bonds Print Hydrogen Storage in Carbon Nanotubes Through Formation of C-H Bonds Print Two of the major challenges for humanity in the next 20 years are the shrinking availability of fossil fuels and the global warming and potential climate changes that result from their ever-increasing use. One possible solution to these problems is to use an energy carrier such as hydrogen, and ways to produce and store hydrogen in electric power plants and vehicles is a major research focus for materials scientists and chemists. To realize hydrogen-powered transport, for example, it is necessary to find ways to store hydrogen onboard vehicles efficiently and safely. Nanotechnology in the form of single-walled carbon nanotubes provides a candidate storage medium. A U.S., German, and Swedish collaboration led by researchers from the Stanford Synchrotron Radiation Laboratory (SSRL) used ALS Beamline 11.0.2 and SSRL Beamline 5-1 to investigate the chemical interaction of hydrogen with single-walled carbon nanotubes (SWCNs). Their findings demonstrate substantial hydrogen storage is both feasible and reversible.

284

Hydrogen Storage in Carbon Nanotubes Through Formation of C-H Bonds  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen Storage in Carbon Nanotubes Through Formation of C-H Bonds Print Hydrogen Storage in Carbon Nanotubes Through Formation of C-H Bonds Print Two of the major challenges for humanity in the next 20 years are the shrinking availability of fossil fuels and the global warming and potential climate changes that result from their ever-increasing use. One possible solution to these problems is to use an energy carrier such as hydrogen, and ways to produce and store hydrogen in electric power plants and vehicles is a major research focus for materials scientists and chemists. To realize hydrogen-powered transport, for example, it is necessary to find ways to store hydrogen onboard vehicles efficiently and safely. Nanotechnology in the form of single-walled carbon nanotubes provides a candidate storage medium. A U.S., German, and Swedish collaboration led by researchers from the Stanford Synchrotron Radiation Laboratory (SSRL) used ALS Beamline 11.0.2 and SSRL Beamline 5-1 to investigate the chemical interaction of hydrogen with single-walled carbon nanotubes (SWCNs). Their findings demonstrate substantial hydrogen storage is both feasible and reversible.

285

Estimation of mass transport parameters of gases for quantifying CH{sub 4} oxidation in landfill soil covers  

SciTech Connect

Methane (CH{sub 4}), which is one of the most abundant anthropogenic greenhouse gases, is produced from landfills. CH{sub 4} is biologically oxidized to carbon dioxide, which has a lower global warming potential than methane, when it passes through a cover soil. In order to quantify the amount of CH{sub 4} oxidized in a landfill cover soil, a soil column test, a diffusion cell test, and a mathematical model analysis were carried out. In the column test, maximum oxidation rates of CH{sub 4} (V{sub max}) showed higher values in the upper part of the column than those in the lower part caused by the penetration of O{sub 2} from the top. The organic matter content in the upper area was also higher due to the active microbial growth. The dispersion analysis results for O{sub 2} and CH{sub 4} in the column are counter-intuitive. As the upward flow rate of the landfill gas increased, the dispersion coefficient of CH{sub 4} slightly increased, possibly due to the effect of mechanical dispersion. On the other hand, as the upward flow rate of the landfill gas increased, the dispersion coefficient of O{sub 2} decreased. It is possible that the diffusion of gases in porous media is influenced by the counter-directional flow rate. Further analysis of other gases in the column, N{sub 2} and CO{sub 2}, may be required to support this hypothesis, but in this paper we propose the possibility that the simulations using the diffusion coefficient of O{sub 2} under the natural condition may overestimate the penetration of O{sub 2} into the soil cover layer and consequently overestimate the oxidation of CH{sub 4}.

Im, J.; Moon, S.; Nam, K.; Kim, Y.-J. [Department of Civil and Environmental Engineering, College of Engineering, Seoul National University, Seoul (Korea, Republic of); Kim, J.Y. [Department of Civil and Environmental Engineering, College of Engineering, Seoul National University, Seoul (Korea, Republic of)], E-mail: jaeykim@snu.ac.kr

2009-02-15T23:59:59.000Z

286

Ch P cage Operations and Regional Office 9800 South Cass Avenue  

Office of Legacy Management (LM)

artment of Energy artment of Energy Ch P cage Operations and Regional Office 9800 South Cass Avenue Argonne, Illinois 60439 OCT 2 1 1980 Ki.lliam E. Mott, Director Environmental Cinttol Technology Division, KC! SUBJECT I PREHIER MANUFACTURING - SPRINGDALE, PEhVSYLVA?UA A visit to Premier Manufacturing, 644 Garfield, Springdalc, Pennsylvania, was made en October 6, 1980, by Edward J. Jascewsky and Art Whitman, Department of Energy, and Walter R. Smith, Argonne National Laboratory. The group met with Edward McClesky, Premier Manufacturing and Bud Schnoor, PPG Industries, Inc. The purpose of the visit was to perform a cursory radiological survey of the facility at the above location. In addition, discussions were held with Mr. Schnoor whose family previously owned the facility and performed the

287

10 CFR Ch. III (1-1-11 Edition) Pt. 851, App. B  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

10 CFR Ch. III (1-1-11 Edition) Pt. 851, App. B must meet the applicable electrical safety codes and standards referenced in § 851.23. 11. NANOTECHNOLOGY SAFETY-RESERVED The Department has chosen to reserve this section since policy and procedures for nano- technology safety are currently being devel- oped. Once these policies and procedures have been approved, the rule will be amended to include them through a rulemaking con- sistent with the Administrative Procedure Act. 12. WORKPLACE VIOLENCE PREVENTION- RESERVED The Department has chosen to reserve this section since the policy and procedures for workplace violence prevention are currently being developed. Once these policies and pro- cedures have been approved, the rule will be amended to include them through a rule-

288

MASSACHUSETTS AVENUE ChMBRIDGE'39, MASSACHUSETTS TELEPHONE UNrvn.,,r,  

Office of Legacy Management (LM)

2, .* 2, .* -' .l-.; . . *' ,. .:, ,-i&CLEAR METALS, INC. MA ,y 155 MASSACHUSETTS AVENUE ChMBRIDGE'39, MASSACHUSETTS TELEPHONE UNrvn.,,r, 4-5200 blr. Saul Strauch Technical Liason Division United States Atomic Energy Commission New York Operations Office 70 Columbus Avenue New York 23, New York SUBJECT:- Program for Uranium Recovery (Ref: S. Strauch to A. R. Kaufmnnn, B/30/55) Dear Mr. Strauch: With reference to Mr. K. E. Field's confidential memorandum of August 22, 1956, this is to advise tha.t Nuclea,r l,':etals, Inc., has no facilities for scrap recovery. Also, our reply to Section III of the memorandum must be based .on our operations during the fiscal year recently ended. During that period, normal uranium 3cra.p material3 were returned to the i\'ational Lead Company of Ohio, and enriched scrap materials

289

Final Report for DOE Project DE-FC07-99CH11010  

DOE Green Energy (OSTI)

Department of Energy award number DE-FC07-99CH11010, Enhanced Utilization of Corn Based Biomaterials, supported a technology development program sponsored by Cargill Dow LLC from September 30, 1999 through June 30, 2003. The work involved fundamental scientific studies on poly lactic acid (PLA), a new environmentally benign plastic material from renewable resources. DOE funds supported academic research at the Colorado School of Mines and the National Renewable Energy Laboratory (NREL), and industry cost share was directed towards applied research into new product development utilizing the fundamental information generated by the academic partners. Under the arrangement of the grant, the fundamental information is published so that other companies can utilize it in evaluating the applicability of PLA in their own products. The overall project objective is to increase the utilization of PLA, a renewable resource based plastic, currently produced from fermented corn sugar.

Jed Randall; Robert Kean

2003-10-22T23:59:59.000Z

290

Quantitative Visualization of ChIP-chip Data by Using Linked Views  

SciTech Connect

Most analyses of ChIP-chip in vivo DNA binding have focused on qualitative descriptions of whether genomic regions are bound or not. There is increasing evidence, however, that factors bind in a highly overlapping manner to the same genomic regions and that it is quantitative differences in occupancy on these commonly bound regions that are the critical determinants of the different biological specificity of factors. As a result, it is critical to have a tool to facilitate the quantitative visualization of differences between transcription factors and the genomic regions they bind to understand each factor's unique roles in the network. We have developed a framework which combines several visualizations via brushing-and-linking to allow the user to interactively analyze and explore in vivo DNA binding data of multiple transcription factors. We describe these visualization types and also provide a discussion of biological examples in this paper.

Huang, Min-Yu; Weber, Gunther; Li, Xiao-Yong; Biggin, Mark; Hamann, Bernd

2010-11-05T23:59:59.000Z

291

Electrochemical Investigation of LiAl Anodes in Oligo(ethylene glycol) Dimethyl Ether/LiPF6  

DOE Green Energy (OSTI)

1 M LiPF{sub 6} dissolved in oligo(ethylene glycol) dimethyl ether with a molecular weight 500 g mol{sup -1} was investigated as a new electrolyte (OEGDME500, 1 M LiPF{sub 6}) for metal deposition and battery applications. At 25 C a conductivity of 0.48 x 10{sup -3} S cm{sup -1} was obtained and at 85 C, 3.78 x 10{sup -3} S cm{sup -1}. The apparent activation barrier for ionic transport was evaluated to be 30.7 kJ mol{sup -1}. OEGDME500, 1 M LiPF{sub 6} allows operating temperature above 100 C with very attractive conductivity. The electrolyte shows excellent performance at negative and positive potentials. With this investigation, we report experimental results obtained with aluminum electrodes using this electrolyte. At low current densities lithium ion reduction and re-oxidation can be achieved on aluminum electrodes at potentials about 280 mV more positive than on lithium electrodes. In situ X-ray diffraction measurements collected during electrochemical lithium deposition on aluminum electrodes show that the shift to positive potentials is due to the negative Gibbs free energy change of the Li-Al alloy formation reaction.

Zhou, Y.N.; Yang, X.; Wang, X.J.; Lee, H.S.; Nam, K.W.; Haas, O.

2010-11-01T23:59:59.000Z

292

Electrochemical Investigation of Li-Al Anodes in Oligo (ethylene glycol) Dimethyl ether/LiPF6  

DOE Green Energy (OSTI)

LiPF{sub 6} dissolved in oligo(ethylene glycol) dimethyl ether with a molecular weight 5 g mol{sup -1} was investigated as a new electrolyte (OEGDME5, 1 M LiPF{sub 6}) for metal deposition and battery applications. At 25 C a conductivity of .48 x 1{sup -3} S cm{sup -1} was obtained and at 85 C, 3.78 x 1{sup -3} S cm{sup -1}. The apparent activation barrier for ionic transport was evaluated to be 3.7 kJ mol{sup -1}. OEGDME5, 1 M LiPF{sub 6} allows operating temperature above 1 C with very attractive conductivity. The electrolyte shows excellent performance at negative and positive potentials. With this investigation, we report experimental results obtained with aluminum electrodes using this electrolyte. At low current densities lithium ion reduction and re-oxidation can be achieved on aluminum electrodes at potentials about 28 mV more positive than on lithium electrodes. In situ X-ray diffraction measurements collected during electrochemical lithium deposition on aluminum electrodes show that the shift to positive potentials is due to the negative Gibbs free energy change of the Li-Al alloy formation reaction.

Y Zhou; X Wang; H Lee; K Nam; X Yang; O Haas

2011-12-31T23:59:59.000Z

293

Heat Capacity Uncertainty Calculation for the Eutectic Mixture of Biphenyl/Diphenyl Ether Used as Heat Transfer Fluid: Preprint  

DOE Green Energy (OSTI)

The main objective of this study was to calculate the uncertainty at 95% confidence for the experimental values of heat capacity of the eutectic mixture of biphenyl/diphenyl ether (Therminol VP-1) determined from 300 to 370 degrees C. Twenty-five samples were evaluated using differential scanning calorimetry (DSC) to obtain the sample heat flow as a function of temperature. The ASTM E-1269-05 standard was used to determine the heat capacity using DSC evaluations. High-pressure crucibles were employed to contain the sample in the liquid state without vaporizing. Sample handling has a significant impact on the random uncertainty. It was determined that the fluid is difficult to handle, and a high variability of the data was produced. The heat capacity of Therminol VP-1 between 300 and 370 degrees C was measured to be equal to 0.0025T+0.8672 with an uncertainty of +/- 0.074 J/g.K (3.09%) at 95% confidence with T (temperature) in Kelvin.

Gomez, J. C.; Glatzmaier, G. C.; Mehos, M.

2012-09-01T23:59:59.000Z

294

Effect of Gradient Sequencing on Copolymer Order?Disorder Transitions: Phase Behavior of Styrene/n-Butyl Acrylate Block and Gradient Copolymers  

SciTech Connect

We investigate the effect of gradient sequence distribution in copolymers on order-disorder transitions, using rheometry and small-angle X-ray scattering to compare the phase behavior of styrene/n-butyl acrylate (S/nBA) block and gradient copolymers. Relative to block sequencing, gradient sequencing increases the molecular weight necessary to induce phase segregation by over 3-fold, directly consistent with previous predictions from theory. Results also suggest the existence of both upper and lower order-disorder transitions in a higher molecular weight S/nBA gradient copolymer, made accessible by the shift in order-disorder temperatures from gradient sequencing. The combination of transitions is speculated to be inaccessible in S/nBA block copolymer systems due to their overlap at even modest molecular weights and also their location on the phase diagram relative to the polystyrene glass transition temperature. Finally, we discuss the potential impacts of polydispersity and chain-to-chain monomer sequence variation on gradient copolymer phase segregation.

Mok, Michelle M.; Ellison, Christopher J.; Torkelson, John M. (NWU); (UMM)

2012-11-14T23:59:59.000Z

295

Liver Hypertrophy After Percutaneous Portal Vein Embolization: Comparison of N-Butyl-2-Cyanocrylate Versus Sodium Acrylate-Vinyl Alcohol Copolymer Particles in a Swine Model  

Science Conference Proceedings (OSTI)

Purpose: Percutaneous portal vein embolization (PPVE) induces hypertrophy of the future liver remnant before hepatic resection. The ideal embolic material has not yet been determined. We compared N-butyl-2-cyanocrylate (NBCA) with sodium acrylate-vinyl alcohol copolymer particles using a swine model. Materials and Methods: Twelve pigs underwent PPVE. Six pigs (group A) were embolized with NBCA, and 6 pigs (group B) were embolized with sodium acrylate-vinyl alcohol copolymer particles. Computed tomographic volumetry of the embolized lobe (EL) and the nonembolized lobe (NEL), along with liver function tests, was performed before and at 14 and 28 days after embolization. Tissue samples from both lobes were taken 14 and 28 days after PPVE. Results: NEL-volume and NEL-ratio increases were significantly higher in group A at 14 and 28 days after PPVE (78 and 52% and 91 and 66%, respectively) than in group B (32 and 12% and 28 and 10%, respectively) (p < 0.05). Percent change of the EL-volume was significantly higher for group A at 28 days after PPVE. No statistically significant difference was found between the groups regarding hepatocyte proliferation on the NEL and apoptosis on the EL at both time intervals. Conclusion: PPVE using NBCA is more efficient and causes more NEL hypertrophy than microspheres.

Tsoumakidou, Georgia, E-mail: gtsoumakidou@yahoo.com [National and Kapodistrian University of Athens, 2nd Department of Radiology, Medical School, General University Hospital Attikon (Greece); Theocharis, Stamatis, E-mail: theocharis@ath.forthnet.gr [National and Kapodistrian University of Athens, Department of Forensic Medicine and Toxicology, Medical School (Greece); Ptohis, Nikolaos, E-mail: nikptohis@yahoo.gr; Alexopoulou, Efthimia, E-mail: ealex64@hotmail.com [National and Kapodistrian University of Athens, 2nd Department of Radiology, Medical School, General University Hospital Attikon (Greece); Mantziaras, George, E-mail: gmantziaras@yahoo.com [Academy of Athens, Biomedical Research Foundation (Greece); Kelekis, Nikolaos L., E-mail: kelnik@med.uoa.gr; Brountzos, Elias N., E-mail: ebrountz@med.uoa.gr [National and Kapodistrian University of Athens, 2nd Department of Radiology, Medical School, General University Hospital Attikon (Greece)

2011-10-15T23:59:59.000Z

296

Rhodium-Catalyzed C-C Bond Formation via Heteroatom-Directed C-H Bond Activation  

SciTech Connect

Once considered the 'holy grail' of organometallic chemistry, synthetically useful reactions employing C-H bond activation have increasingly been developed and applied to natural product and drug synthesis over the past decade. The ubiquity and relative low cost of hydrocarbons makes C-H bond functionalization an attractive alternative to classical C-C bond forming reactions such as cross-coupling, which require organohalides and organometallic reagents. In addition to providing an atom economical alternative to standard cross - coupling strategies, C-H bond functionalization also reduces the production of toxic by-products, thereby contributing to the growing field of reactions with decreased environmental impact. In the area of C-C bond forming reactions that proceed via a C-H activation mechanism, rhodium catalysts stand out for their functional group tolerance and wide range of synthetic utility. Over the course of the last decade, many Rh-catalyzed methods for heteroatom-directed C-H bond functionalization have been reported and will be the focus of this review. Material appearing in the literature prior to 2001 has been reviewed previously and will only be introduced as background when necessary. The synthesis of complex molecules from relatively simple precursors has long been a goal for many organic chemists. The ability to selectively functionalize a molecule with minimal pre-activation can streamline syntheses and expand the opportunities to explore the utility of complex molecules in areas ranging from the pharmaceutical industry to materials science. Indeed, the issue of selectivity is paramount in the development of all C-H bond functionalization methods. Several groups have developed elegant approaches towards achieving selectivity in molecules that possess many sterically and electronically similar C-H bonds. Many of these approaches are discussed in detail in the accompanying articles in this special issue of Chemical Reviews. One approach that has seen widespread success involves the use of a proximal heteroatom that serves as a directing group for the selective functionalization of a specific C-H bond. In a survey of examples of heteroatom-directed Rh catalysis, two mechanistically distinct reaction pathways are revealed. In one case, the heteroatom acts as a chelator to bind the Rh catalyst, facilitating reactivity at a proximal site. In this case, the formation of a five-membered metallacycle provides a favorable driving force in inducing reactivity at the desired location. In the other case, the heteroatom initially coordinates the Rh catalyst and then acts to stabilize the formation of a metal-carbon bond at a proximal site. A true test of the utility of a synthetic method is in its application to the synthesis of natural products or complex molecules. Several groups have demonstrated the applicability of C-H bond functionalization reactions towards complex molecule synthesis. Target-oriented synthesis provides a platform to test the effectiveness of a method in unique chemical and steric environments. In this respect, Rh-catalyzed methods for C-H bond functionalization stand out, with several syntheses being described in the literature that utilize C-H bond functionalization in a key step. These syntheses are highlighted following the discussion of the method they employ.

Colby, Denise; Bergman, Robert; Ellman, Jonathan

2010-05-13T23:59:59.000Z

297

Plasma 2D modeling and diagnostics of DLC deposition on PET E. Amanatides, P. Gkotsis, Ch. Syndrevelis, D. Mataras *  

E-Print Network (OSTI)

dimensional (2D) emission spectra of short-lived excited species for estimating the uniformity of production substrates was investigated. Images of the a- balmer line of atomic hydrogen in CH4/H2 discharges were and fast way control and optimization of such processes. In this direction, the present work is focused

298

Physical and chemical properties of dust produced in a N{sub 2}-CH{sub 4} RF plasma discharge  

Science Conference Proceedings (OSTI)

Titan's atmospheric chemistry is simulated using a Capacitively Coupled Plasma discharge produced in a N{sub 2}-CH{sub 4} mixture. The produced solid particles are analysed ex-situ. Chemical properties are deduced from: elemental composition, FTIR and LTQ-Orbitrap mass spectrometer. Optical properties are deduced from reflectivity in visible and IR range.

Ouni, F.; Alcouffe, G.; Szopa, C.; Carrasco, N.; Cernogora, G. [Universite de Versailles St Quentin, Service d'Aeronomie, BP 3-91371 Verrieres le Buisson (France); Adande, G.; Thissen, R.; Quirico, E.; Brissaud, O. [LPG-BP 5338041 Grenoble Cedex 9 (France); Schmitz-Afonso, I.; Laprevote, O. [ICSN-CNRS Avenue de la Terrasse, 91198 Gif sur Yvette (France)

2008-09-07T23:59:59.000Z

299

PREPARED FOR THE U.S. DEPARTMENT OF ENERGY, UNDER CONTRACT DE-AC02-76CH03073  

E-Print Network (OSTI)

contract DE-AC02-76-CH03073. #12;03/26/01 External Distribution Plasma Research Laboratory, Australian, Reports Library, MTA KFKI-ATKI, Hungary Dr. P. Kaw, Institute for Plasma Research, India Ms. P.J. Pathak, Librarian, Insitute for Plasma Research, India Ms. Clelia De Palo, Associazione EURATOM-ENEA, Italy Dr. G

300

Assessment of kinetic modeling for lean H2/CH4/O2/diluent flames at high pressures  

E-Print Network (OSTI)

: Hydrogen; Methane; Syngas; Flame speed; Chemical mechanism 1. Introduction The H2/O2 reaction system CO, CO2, H2O, CH4 and other small hydrocarbons (synthetic gas or "syngas") from coal or biomass gasification [2]. Typical syngas mixtures can contain significant amounts of small molecular weight

Ju, Yiguang

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301

C-C and C-Heteroatom Bond Dissociation Energies in CH3R?C(OH)2: Energetics for Photocatalytic Processes of Organic Diolates on TiO2 Surfaces  

SciTech Connect

The bond energies of a range of gem-diols, CH3R?C(OH)2 (R? = H, F, Cl, Br, CN, NO2, CF3, CH3CH2, CH3CH2CH2, CH3CH2CH2CH2, ((CH3)2)CH, (CH3)3C, ((CH3)2CH)CH2, (CH3CH2)(CH3)CH, C6H5 (CH3CH2)(CH3)CH) which serve as models for binding to a surface have been studied with density functional theory (DFT) and the molecular orbital G3(MP2) methods to provide thermodynamic data for the analysis of the photochemistry of ketones on TiO2. The ultraviolet (UV) photon-induced photodecomposition of adsorbed acetone and 3,3-dimethylbutanone on the rutile TiO2 (110) surface have been investigated with photon stimulated desorption (PSD) and temperature programmed desorption (TPD). The C-CH3 and C-C(R?) bond dissociation energies in CH3R?C(OH)2 were predicted, and our calculated bond dissociation energies are in excellent agreement with the available experimental values. We used a series of isodemic reactions to provide small corrections to the various bond dissociation energies. The calculated bond dissociation energies are in agreement with the observed photodissociation processes except for R? = CF3, suggesting that these processes are under thermodynamic control. For R? = CF3, reaction dynamics also play a role in determining the photodissociation mechanism. The gas phase Brnsted acidities of the gem-diols were calculated. For three molecules, R? = Cl, Br, and NO2, loss of a proton leads to the formation of a complex of acetic acid with the anion Cl-, Br-, and NO2-. The acidities of these three species are very high with the former two having acidities comparable to CF3SO3H. The ketones (R?RC(=O)) are weak Lewis acids except where addition of OH- leads to the dissociation of the complex to form an anion bonded to acetic acid, R' = NO2, Cl, and Br. The X-C bond dissociation energies for a number of X-CO2- species were calculated and these should be useful in correlating with photochemical reactivity studies.

Wang, Tsang-Hsiu; Dixon, David A.; Henderson, Michael A.

2010-08-26T23:59:59.000Z

302

Auto-ignition during instationary jet evolution of dimethyl ether (DME) in a high-pressure atmosphere  

Science Conference Proceedings (OSTI)

The auto-ignition process during transient injection of gaseous dimethyl ether (DME) in a constant high-pressure atmosphere is studied experimentally by laser-optical methods and compared with numerical calculations. With different non-intrusive measurement techniques jet properties and auto-ignition are investigated at high temporal and spatial resolution. The open jet penetrates a constant pressure oxidative atmosphere of up to 4 MPa. During the transient evolution, the fuel jet entrains air at up to 720 K. The subsequent auto-ignition of the ignitable part of the jet occurs simultaneously over a wide spatial extension. The ignition delay times are not affected by variation of the nozzle exit velocity. Thus, the low-temperature oxidation is slow compared with the shorter time scales of mixing, so that chemical kinetics is dominating the process. The typical two-stage ignition is resolved optically with high-speed shadowgraphy at a sampling rate of 10 kHz. The 2D fields of jet velocity and transient mixture fraction are measured phase-coupled with Particle Image Velocimetry (PIV) and Tracer Laser Induced Fluorescence (LIF) during the time-frame of ignition. The instationary Probability Density Functions (PDF) of mixture fraction are described very well by Beta functions within the complete area of the open jet. Additional 1D flamelet simulations of the auto-ignition process are computed with a detailed reaction mechanism for DME [S. Fischer, F. Dryer, H. Curran, Int. J. Chem. Kinet. 32 (12) (2000) 713-740; H. Curran, S. Fischer, F. Dryer, Int. J. Chem. Kinet. 32 (12) (2000) 741-759]. Calculated ignition delay times are in very good agreement with the measured mean ignition delay times of 3 ms. Supplemental flamelet simulations address the influence of DME and air temperature, pressure and strain. Underneath a critical strain rate the air temperature is identified to be the most sensitive factor on ignition delay time. (author)

Fast, G.; Kuhn, D.; Class, A.G. [Institut fuer Kern- und Energietechnik, Forschungszentrum Karlsruhe GmbH, Weberstrasse 5, D-76133 Karlsruhe (Germany); Maas, U. [Institut fuer Technische Thermodynamik, Universitat Karlsruhe (TH), Kaiserstrasse 12, D-76128 Karlsruhe (Germany)

2009-01-15T23:59:59.000Z

303

Quantum computing applied to calculations of molecular energies: CH2 benchmark  

E-Print Network (OSTI)

Quantum computers are appealing for their ability to solve some tasks much faster than their classical counterparts. It was shown in [Aspuru-Guzik et al., Science 309, 1704 (2005)] that they, if available, would be able to perform the full configuration interaction (FCI) energy calculations with a polynomial scaling. This is in contrast to conventional computers where FCI scales exponentially. We have developed a code for simulation of quantum computers and implemented our version of the quantum full configuration interaction algorithm. We provide a detailed description of this algorithm and the results of the assessment of its performance on the four lowest lying electronic states of CH2 molecule. This molecule was chosen as a benchmark, since its two lowest lying 1A1 states exhibit a multireference character at the equilibrium geometry. It has been shown that with a suitably chosen initial state of the quantum register, one is able to achieve the probability amplification regime of the iterative phase estimation algorithm even in this case.

Libor Veis; Ji? Pittner

2010-08-20T23:59:59.000Z

304

Call for Proposals for SystemsX.ch Projects In the Messages on Education, Research and Innovation for 2008-2011 and 2012, the Fed-  

E-Print Network (OSTI)

of the SystemsX.ch initiative. The Mes- sage on Education, Research and Innovation for 2013-2016 envisages- view, for the period of 2013-2016. Teams of scientists from all SystemsX.ch partner institu- tions ................................................................................................12 3.1.10 Annual Scientific and Financial Reporting

Glinz, Martin

305

Remote Sensing D/H Ratios in Methane Ice: Temperature-Dependent Absorption Coefficients of CH3D in Methane Ice and in Nitrogen Ice  

E-Print Network (OSTI)

The existence of strong absorption bands of singly deuterated methane (CH3D) at wavelengths where normal methane (CH4) absorbs comparatively weakly could enable remote measurement of D/H ratios in methane ice on outer solar system bodies. We performed laboratory transmission spectroscopy experiments, recording spectra at wavelengths from 1 to 6 \\mum to study CH3D bands at 2.47, 2.87, and 4.56 \\mum, wavelengths where ordinary methane absorption is weak. We report temperature-dependent absorption coefficients of these bands when the CH3D is diluted in CH4 ice and also when it is dissolved in N2 ice, and describe how these absorption coefficients can be combined with data from the literature to simulate arbitrary D/H ratio absorption coefficients for CH4 ice and for CH4 in N2 ice. We anticipate these results motivating new telescopic observations to measure D/H ratios in CH4 ice on Triton, Pluto, Eris, and Makemake.

Grundy, W M; Bovyn, M J; Tegler, S C; Cornelison, D M

2011-01-01T23:59:59.000Z

306

Is Embolization of the Pancreas Safe? Pancreatic Histological Changes after Selective Transcatheter Arterial Embolization with N-Butyl Cyanoacrylate in a Swine Model  

SciTech Connect

Purpose: This study was designed to evaluate the safety of selective transcatheter arterial embolization (TAE) with N-butyl cyanoacrylate (NBCA) in a swine model in terms of histological changes in the pancreas. Methods: Three groups of two female swine (58-64 kg) per group underwent TAE of the dorsal pancreatic artery, under anesthesia, with 1:1, 1:4, and 1:9 mixtures of NBCA and iodized oil. Blood parameters were evaluated at days 1, 4, and 10 after TAE, after which the animals were sacrificed and pancreatic tissues were examined under light microscopy. Results: All of the animals were asymptomatic and survived for 10 days. Cone beam computed tomographic angiography revealed occlusion of the dorsal pancreatic artery and no enhancement in the embolized area. The white blood cell count and C-reactive protein level were elevated slightly on day 1 after TAE (mean {+-} SD: 252.7 {+-} 27.8 Multiplication-Sign 10{sup 2}/{mu}l and 0.15 {+-} 0.07 mg/l, respectively), but they normalized or remained near the upper normal limit thereafter. The serum amylase and lipase levels also were elevated on day 1 (8831.7 {+-} 2169.2 U/l and 130 {+-} 53.4 U/l, respectively) but normalized thereafter. Histologically, necrosis and fibrosis were noted only in the embolized segment, and necrosis and acute inflammatory reactions were absent in the nonembolized segment. The border between both segments was well defined. Lymphocytic infiltration and foreign body reaction were noted around the embolized vessels. Conclusions: Selective TAE with NBCA in the pancreas caused localized ischemic necrosis without clinically significant pancreatitis; therefore, this procedure is tolerable in swine.

Okada, Takuya, E-mail: okabone@gmail.com; Yamaguchi, Masato [Kobe University Graduate School of Medicine, Department of Radiology (Japan); Takahashi, Takuya [Kobe Red Cross Hospital, Department of Pathology (Japan); Izaki, Kenta; Uotani, Kensuke; Sakamoto, Noriaki; Sugimura, Kazuro; Sugimoto, Koji [Kobe University Graduate School of Medicine, Department of Radiology (Japan)

2012-02-15T23:59:59.000Z

307

Enforcement Letter, September 6, 2007, CH2M Hill Hanford Group Potential Violations of Nuclear Safety Requirements  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

6, 2007 6, 2007 Mr. John Fulton Chief Executive Officer CH2M Hill Hanford Group, Inc. 2440 Stevens Drive Richland, Washington 99352 Dear Mr. Fulton: The Department of Energy (DOE) held an Enforcement Conference on August 29, 2006, with CH2M Hill Hanford Group (CHG) to discuss potential violations of nuclear safety requirements described in our Investigation Summary Report dated July 26, 2006. At that time, DOE elected to defer a decision on a potential quality improvement violation related to recurring radiological events and deficiencies in the identification and control of radiological hazards at the Tank Farms. This decision was based upon the fact that CHG senior management had initiated radiological work improvements but insufficient data was available to assess their effectiveness. On July 12, 2007, Office of Enforcement

308

NEPA REVIEW SCREENING FORM DOE/CX-00088 I. Project Title: CH2f"JHill Plateau Remediation Company -  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

10 Number: 10 Number: NEPA REVIEW SCREENING FORM DOE/CX-00088 I. Project Title: CH2f"JHill Plateau Remediation Company - Cleanup Actions, December 2012 to December 2013 II. Project Description and Location (including Time Period over which proposed action will occur and Project Dimensions. e.g., acres displaced/disturbed, excavation length/depth, area/location/number of buildings, etc.): CH2MHill Plateau Remediation Company (PRC) will be conducting cleanup actions on the Hanford Site in accordance with the categorical exclusion (CX) referenced in 10 CFR 1021, B, CX B6.1 ''Cleanup actions". PRC Projects include all those identified Sections . 3 and J.l4 of the PRC Contract, DE-AC06-08RL14788. Small-scale, short-term cleanup actions, under RCRA, Atomic Energy Act, or other

309

Altered cardiovascular reactivity and osmoregulation during hyperosmotic stress in adult rats developmentally exposed to polybrominated diphenyl ethers (PBDEs)  

Science Conference Proceedings (OSTI)

Polybrominated diphenyl ethers (PBDEs) and the structurally similar chemicals polychlorinated biphenyls (PCBs) disrupt the function of multiple endocrine systems. PCBs and PBDEs disrupt the secretion of vasopressin (VP) from the hypothalamus during osmotic activation. Since the peripheral and central vasopressinergic axes are critical for osmotic and cardiovascular regulation, we examined whether perinatal PBDE exposure could impact these functions during physiological activation. Rats were perinatally dosed with a commercial PBDE mixture, DE-71. Dams were given 0 (corn oil control), 1.7 (low dose) or 30.6 mg/kg/day (high dose) in corn oil from gestational day (GD) 6 through postnatal day (PND) 21 by oral gavage. In the male offspring exposed to high dose PBDE plasma thyroxine and triiodothyronine levels were reduced at PND 21 and recovered to control levels by PND 60 when thyroid stimulating hormone levels were elevated. At 14-18 months of age, cardiovascular responses were measured in four groups of rats: Normal (Oil, normosmotic condition), Hyper (Oil, hyperosmotic stress), Hyper PBDE low (1.7 mg/kg/day DE-71 perinatally, hyperosmotic stress), and Hyper PBDE high (30.6 mg/kg/day DE-71 perinatally, hyperosmotic stress). Systolic blood pressure (BP), diastolic BP, and heart rate (HR) were determined using tail cuff sphygmomanometry and normalized to pretreatment values (baseline) measured under basal conditions. Hyperosmotic treatment yielded significant changes in systolic BP in PBDE exposed rats only. Hyper PBDE low and high dose rats showed 36.1 and 64.7% greater systolic BP responses at 3 h post hyperosmotic injection relative to pretreatment baseline, respectively. No treatment effects were measured for diastolic BP and HR. Hyper and Hyper PBDE rats showed increased mean plasma osmolality values by 45 min after injection relative to normosmotic controls. In contrast to Hyper rats, Hyper PBDE (high) rats showed a further increase in mean plasma osmolality at 3 h (358.3 {+-} 12.4 mOsm/L) relative to 45 min post hyperosmotic injection (325.1 {+-} 11.4 mOsm/L). Impaired osmoregulation in PBDE-treated animals could not be attributed to decreased levels of plasma vasopressin. Our findings suggest that developmental exposure to PBDEs may disrupt cardiovascular reactivity and osmoregulatory responses to physiological activation in late adulthood. - Highlights: > We examined whether PBDE exposure could impact osmotic and cardiovascular regulation. > Hyperosmotic treatment yielded significant changes in systolic BP in PBDE exposed rats only. > PBDEs may disrupt cardiovascular and osmoregulatory responses to physiological activation.

Shah, Ashini [Department of Cell Biology and Neuroscience, University of California, Riverside, 92521 (United States); Coburn, Cary G. [Environmental Toxicology Graduate Program, University of California, Riverside, 92521 (United States); Watson-Siriboe, Abena; Whitley, Rebecca; Shahidzadeh, Anoush; Gillard, Elizabeth R.; Nichol, Robert [Department of Cell Biology and Neuroscience, University of California, Riverside, 92521 (United States); Leon-Olea, Martha [Neuromorfologia Funcional, Direccion de Investigaciones en Neurociencias, Instituto Nacional de Psiquiatria Ramon de la Fuente Muniz, Mexico City (Mexico); Gaertner, Mark [Department of Cell Biology and Neuroscience, University of California, Riverside, 92521 (United States); Kodavanti, Prasada Rao S. [Neurotoxicology Branch, NHEERL/ORD, U.S. Environmental Protection Agency, Research Triangle Park, NC (United States); Curras-Collazo, Margarita C., E-mail: margarita.curras@ucr.edu [Environmental Toxicology Graduate Program, University of California, Riverside, 92521 (United States); Department of Cell Biology and Neuroscience, University of California, Riverside, 92521 (United States)

2011-10-15T23:59:59.000Z

310

Review of the Hanford Site CH2M Hill Plateau Remediation Company Implementation Verification Review Processes, November 2012  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Independent Oversight Review Independent Oversight Review of the Hanford Site CH2M Hill Plateau Remediation Company Implementation Verification Review Processes November 2012 Office of Safety and Emergency Management Evaluations Office of Enforcement and Oversight Office of Health, Safety and Security U.S. Department of Energy Table of Contents 1.0 Purpose ................................................................................................................................................... 1 2.0 Background ............................................................................................................................................ 1 3.0 Scope...................................................................................................................................................... 2

311

Review of the Hanford Site CH2M Hill Plateau Remediation Company Implementation Verification Review Processes, November 2012  

NLE Websites -- All DOE Office Websites (Extended Search)

Independent Oversight Review Independent Oversight Review of the Hanford Site CH2M Hill Plateau Remediation Company Implementation Verification Review Processes November 2012 Office of Safety and Emergency Management Evaluations Office of Enforcement and Oversight Office of Health, Safety and Security U.S. Department of Energy Table of Contents 1.0 Purpose ................................................................................................................................................... 1 2.0 Background ............................................................................................................................................ 1 3.0 Scope...................................................................................................................................................... 2

312

Description of the FCUP code used to compute currents due to recoil protons from CH/sub 2/ foils  

Science Conference Proceedings (OSTI)

A computer code, FCUP, was developed at EG and G during the period from 1973 to the present to compute proton currents produced by a time- and energy-dependent neutron flux striking a CH/sub 2/ foil and knocking protons into a detector placed at an angle with respect to the target foil and the neutron beam. This report describes the methods of calculation used and the physical assumptions and limitations involved and suggests possibilities for improving the calculations.

Stelts, M.L.; Glasgow, D.W.; Wood, B.E.; Craft, A.D.

1982-07-01T23:59:59.000Z

313

Polyacetylene, (CH){sub x}, as an Emerging Material for Solar Cell Applications. Final Technical Report, March 19, 1979 - March 18, 1980  

DOE R&D Accomplishments (OSTI)

Despite great theoretical and technological interest in polyacetylene, (CH){sub x}, the basic features of its band structure have not been unambiguously resolved. Since photoconductivity and optical absorption data have frequently been used to infer information on the band structure of semiconductors, such measurements were carried out on (CH){sub x}. The main results of an extensive study of the photoconductivity (..delta.. sigma{sub ph}) and absorption coefficient (..cap alpha..) in (CH){sub x} are presented. The absence of photoconductivity in cis-(CH){sub x}, despite the similarity in optical properties indicates that ..delta.. sigma/sub ph/ in trans-(CH){sub x} is induced by isomerization. It is found that isomerization generates states deep inside the gap that act as safe traps for minority carriers and thereby enhance the photoconductivity. Compensation of trans-(CH){sub x} with ammonia appears to decrease the number of safe traps, whereas acceptor doping increases their number. Thus, chemical doping can be used to control the photoconductive response. The energy of safe traps inside the gap is independent of the process used to generate them; indicative of an intrinsic localized defect level in trans-(CH){sub x}. A coherent picture based on the soliton model can explain these results, including the safe trapping.

Heeger, A. J.; MacDiarmid, A. G.

1980-06-05T23:59:59.000Z

314

Enantiomeric recognition of organic ammonium salts by chiral crown ethers based on the pyridino-18-crown-6 structure  

SciTech Connect

Enantiomeric recognition by several chiral dimethyl-substituted macrocycles of the pyridino-18-crown-6 type for chiral organic ammonium salts has been studied by titration calorimetry in CH/sub 3/OH, temperature-dependent /sup 1/H NMR spectroscopy in CD/sub 2/CL/sub 2/, and selective crystallization. Results from the three procedures are consistent in demonstrating either host-guest recognition or nonrecognition in the systems investigated. Futhermore, enaniomeric recognition by one chiral host for a pair of chiral guests is correlated with X-ray crystallographic data for the same system. The chiral dimethyl-substituted ligands used in the study include three dimethyl diester pyridino-18-crown-6 ligands, dimethyl thiono diester pyridino-18-crown-6, and dimethyl-pyridino-18-crown-6 ligands. All of these ligands exhibited chiral recognition. Dimethylpyridino-18-crown-6 in complexation with (R)- and (S)-(..cap alpha..-(1-naphthyl)ethyl)ammonium perchlorate exhibited the largest ratio of ..delta..G/sub c/+ yet observed by the /sup 1/H NMR technique. A diphenyl-substituted diester pyridino-18-crown-6 where the phenyl substituents are in less rigid portion of the macrocycle failed to show chiral recognition.

Davidson, R.B.; Bradshaw, J.S.; Jones, B.A.; Dalley, N.K.; Christensen, J.J.; Izatt, R.M.

1984-01-27T23:59:59.000Z

315

Subtask 1.22 - Microbial Cycling of CH4, CO2, and N2O in a Wetlands Environment  

Science Conference Proceedings (OSTI)

Soil microbial metabolic activities play an important role in determining CO{sub 2}, CH{sub 4}, and N{sub 2}O fluxes from terrestrial ecosystems. To verify and evaluate CO{sub 2} sequestration potential by wetland restoration in the Prairie Pothole Region (PPR), as well as to address concern over restoration effects on CH{sub 4} and N{sub 2}O emissions, laboratory and in situ microcosm studies on microbial cycling of CO{sub 2}, CH{sub 4}, and N{sub 2}O were initiated. In addition, to evaluate the feasibility of the use of remote sensing to detect soil gas flux from wetlands, a remote-sensing investigation was also conducted. Results of the laboratory microcosm study unequivocally proved that restoration of PPR wetlands does sequester atmospheric CO{sub 2}. Under the experimental conditions, the simulated restored wetlands did not promote neither N{sub 2}O nor CH{sub 4} fluxes. Application of ammonia enhanced both N{sub 2}O and CH{sub 4} emission, indicating that restoration of PPR wetlands may reduce both N{sub 2}O and CH{sub 4} emission by cutting N-fertilizer input. Enhancement of CO{sub 2} emission by the N-fertilizer was observed, and this observation revealed an overlooked fact that application of N-fertilizer may potentially increase CO{sub 2} emission. In addition, the CO{sub 2} results also demonstrate that wetland restoration sequesters atmospheric carbon not only by turning soil conditions from aerobic to anoxic, but also by cutting N-fertilizer input that may enhance CO{sub 2} flux. The investigation on microbial community structure and population dynamics showed that under the experimental conditions restoration of the PPR wetlands would not dramatically increase population sizes of those microorganisms that produce N{sub 2}O and CH{sub 4}. Results of the in situ study proved that restoration of the PPR wetland significantly reduced CO{sub 2} flux. Ammonia enhanced the greenhouse gas emission and linearly correlated to the CO{sub 2} flux within the experimental rate range (46-200 kg N ha{sup -1}). The results also clarified that the overall reduction in global warming potential (GWP) by the PPR wetland restoration was mainly contributed from reduction in CO{sub 2} flux. These results demonstrate that restoration of currently farmed PPR wetlands will significantly reduce the overall GWP budget. Remote sensing investigations indicate that while the 15-meter resolution of the imagery was sufficient to delineate multiple zones in larger wetlands, it was not sufficient for correlation with the ground-based gas flux measurement data, which were collected primarily for smaller wetland sites (<250 meters) in the areas evaluated by this task. To better evaluate the feasibility of using satellite imagery to quantify wetland gas flux, either higher-resolution satellite imagery or gas flux data from larger wetland sites is needed.

Dingyi Ye; Bethany Kurz; Marc Kurz

2008-12-31T23:59:59.000Z

316

Modern Methods for Lipid AnalysisCh 6 Regiospecific Analysis of Triacylglycerols using Hi Performance Liquid Chromatography/AtmosphericPressure Chemical Ionization Mass Spectrometry  

Science Conference Proceedings (OSTI)

Modern Methods for Lipid Analysis Ch 6 Regiospecific Analysis of Triacylglycerols using Hi Performance Liquid Chromatography/AtmosphericPressure Chemical Ionization Mass Spectrometry Methods and Analyses eChapters Methods - Analyses Books

317

Dry etching of CoFe films using a CH{sub 4}/Ar inductively coupled plasma for magnetic random access memory application  

Science Conference Proceedings (OSTI)

In this study, the CoFe thin film was studied using an inductively coupled plasma system in CH{sub 4}-based gas chemistries. The etch rate of the CoFe thin film was systemically studied by the process parameters including the gas mixing ratio, the rf power, the dc-bias power, and the process pressure. The best gas composition for etching was in CH{sub 4} (20%)/Ar (80%) ratio. As the rf power and the dc-bias voltage were increased, the etch rate of the CoFe thin film increased in a CH{sub 4}/Ar inductively coupled plasma system. The best process pressure condition for etching was 10 mTorr in the CH{sub 4}/Ar inductively coupled plasma system. The changes in the components on the surface of the CoFe thin film were investigated with energy dispersive x ray.

Um, Doo-Seung; Kim, Dong-Pyo; Woo, Jong-Chang; Kim, Chang-Il; Lee, Sung-Kwon; Jung, Tae-Woo; Moon, Seung-Chan [School of Electrical and Electronics Engineering, Chung-Ang University, 221 Heukseok-Dong, Dongjak-Gu, Seoul 156-756 (Korea, Republic of); Hynix Semiconductor Inc., San 136-1, Ami-ri, Bubal-eub, Icheon-si, Kyoungki-do 467-701 (Korea, Republic of)

2009-07-15T23:59:59.000Z

318

Industrial Utilization of Surfactants: Principles & PracticeCh 4 Chemical Structure and Microenvironmental Effects on Surfactant Fundamental Properties/Related Performance Properties  

Science Conference Proceedings (OSTI)

Industrial Utilization of Surfactants: Principles & Practice Ch 4 Chemical Structure and Microenvironmental Effects on Surfactant Fundamental Properties/Related Performance Properties Surfactants and Detergents eChapters Surfactants - Dete

319

Dietary Fats and Risk of Chronic DiseaseCh 10 Suppression of Leukotriene B4 Generation by ex vivo Neutrophils Isolated from Asthma Patients  

Science Conference Proceedings (OSTI)

Dietary Fats and Risk of Chronic Disease Ch 10 Suppression of Leukotriene B4 Generation by ex vivo Neutrophils Isolated from Asthma Patients Health Nutrition Biochemistry eChapters Health - Nutrition - Biochemistry Press ...

320

Lipid Analysis and Lipidomics: New Techniques & Application-Ch 6Structural Analysis of Unsaturated Fatty Acid Methyl Ester Isomers with Acetonitrile Covalent Adduct Chemical Ionization  

Science Conference Proceedings (OSTI)

Lipid Analysis and Lipidomics: New Techniques & Application-Ch 6 Structural Analysis of Unsaturated Fatty Acid Methyl Ester Isomers with Acetonitrile Covalent Adduct Chemical Ionization Methods and Analyses eChapters Methods - Analyses Book

Note: This page contains sample records for the topic "butyl ether ch" from the National Library of EnergyBeta (NLEBeta).
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they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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321

Re-evaluation of the lifetimes of the major CFCs and CH[subscript 3]CCl[subscript 3] using atmospheric trends  

E-Print Network (OSTI)

Since the Montreal Protocol on Substances that Deplete the Ozone Layer and its amendments came into effect, growth rates of the major ozone depleting substances (ODS), particularly CFC-11, -12 and -113 and CH[subscript ...

O'Doherty, S.

322

Designing Soybeans for the 21st Century MarketsCh 15 High-Oleic, Low-Saturate Soybeans Offer a Sustainable and Nutritionally Enhanced Solution for Food Applications  

Science Conference Proceedings (OSTI)

Designing Soybeans for the 21st Century Markets Ch 15 High-Oleic, Low-Saturate Soybeans Offer a Sustainable and Nutritionally Enhanced Solution for Food Applications Biofuels and Bioproducts and Biodiesel Food Science Health Nutrition Bi

323

C?H Bond Activation by Pd-substituted CeO[subscript 2]: Substituted Ions versus Reduced Species  

Science Conference Proceedings (OSTI)

Substituted metal oxides containing ionic species have been attracting a great deal of attention because of their potential ability to reduce the usage of precious metals in heterogeneous catalysts. We investigate Pd-substituted CeO{sub 2} for C-H bond activation reactions including the partial oxidation and dry reforming of CH{sub 4}. This catalyst has been previously studied for CO oxidation, NO{sub x} reduction, and the water-gas shift reaction. Pd-substituted CeO{sub 2}, Ce{sub 1-x}Pd{sub x}O{sub 2-{delta}}, was prepared as a powder with high surface area and a hollow sphere morphology using ultrasonic spray pyrolysis. The catalysts were extensively characterized using synchrotron X-ray diffraction and other techniques, confirming phase pure samples up to 10 mol % Pd substitution. Ce{sub 0.95}Pd{sub 0.05}O{sub 2-{delta}} was found to be active for partial oxidation of CH{sub 4} around 500 C and higher. Our studies, including postcatalytic synchrotron diffraction, suggest that the single-phase Ce{sub 1-x}Pd{sub x}O{sub 2-{delta}} material is not the active species and that catalysis occurs instead over the reduced two-phase Pd{sup 0}/CeO{sub 2}. This observation has been further confirmed by verifying the activity of the reduced Pd{sup 0}/CeO{sub 2} catalysts for ethylene hydrogenation, a reaction that is known to require Pd{sup 0}.

Misch, Lauren M.; Kurzman, Joshua A.; Derk, Alan R.; Kim, Young-Il; Seshadri, Ram; Metiu, Horia; McFarland, Eric W.; Stucky, Galen D. (Yeungnam); (UCSB)

2012-02-07T23:59:59.000Z

324

MonChER: Monte-Carlo generator for CHarge Exchange Reactions. Version 1.1. Physics and Manual  

E-Print Network (OSTI)

MonChER is a Monte Carlo event generator for simulation of single and double charge exchange reactions in proton-proton collisions at energies from 0.9 to 14 TeV. Such reactions, $pp\\to n+X$ and $pp\\to n+X+n$, are characterized by leading neutron production. They are dominated by $\\pi^+$ exchange and could provide us with more information about total and elastic $\\pi^+ p$ and $\\pi^+\\pi^+$ cross sections and parton distributions in pions in the still unexplored kinematical region.

R. A. Ryutin; A. E. Sobol; V. A. Petrov

2011-06-10T23:59:59.000Z

325

li Aone+amth arfumionto itu%illti&% p?e~6a'&ionofthoChOmiQo  

Office of Legacy Management (LM)

li Aone+amth arfumionto itu%illti&% p?e~6a'&ionofthoChOmiQo li Aone+amth arfumionto itu%illti&% p?e~6a'&ionofthoChOmiQo SinaL report, pattisulerly dfh, raqmot b dto evaluation. 8. A eixdtoirth~atension primarily to inauro havlrg Chealeo &&able . fbroowultationonWtj0 ~itoevaluation~rkforthet&wto Bsddw Timoveoy ?lant, but 980 to keep Chemioo avsilable for dmelopm~t ark on the alternate oatbanatie mtoolaw leaoh proosa80 DIECDBfiIOH Be are requesting anamndcmntto o&end CoatmotAT(W&-1489 with the Chmaloal Qonstruobloon Cor;orhlon. 455 L(adloonAve., !JewYork, P, York. This lr a CPFF Coatmot primarily for reaenrgh and devolopnmt to prorLdo l proossr for our 'IFas% Reeldues Reomery Program. VIWZ haa beenpo3Qo~~urderbhllCo~tatthsLin&rm, RuuJerseylabomt.ory of the Cheaical ConatruotionCorporation mad at Chctnioal Construotlon

326

Laboratory Investigations of a Low-swirl Injector withH2 and CH4 at Gas  

NLE Websites -- All DOE Office Websites (Extended Search)

Investigations of a Low-swirl Injector withH2 and CH4 at Gas Investigations of a Low-swirl Injector withH2 and CH4 at Gas Turbine Conditions Title Laboratory Investigations of a Low-swirl Injector withH2 and CH4 at Gas Turbine Conditions Publication Type Journal Article Year of Publication 2009 Authors Cheng, Robert K., David Littlejohn, P. A. Strakey, and T. Sidwell Journal Science Direct Abstract Laboratory experiments were conducted at gas turbine and atmospheric conditions (0.101 < P0 < 0.810 MPa, 298 < T0 < 580K, 18 < U0 < 60 m/s) to characterize the overall behaviors and emissions of the turbulent premixed flames produced by a low-swirl injector (LSI) for gas turbines. The objective was to investigate the effects of hydrogen on the combustion processes for the adaptation to gas turbines in an IGCC power plant. The experiments at high pressures and temperatures showed that the LSI can operate with 100% H2 at up to f = 0.5 and has a slightly higher flashback tolerance than an idealized high-swirl design. With increasing H2 fuel concentration, the lifted LSI flame begins to shift closer to the exit and eventually attaches to the nozzle rim and assumes a different shape at 100% H2. The STP experiments show the same phenomena. The analysis of velocity data from PIV shows that the stabilization mechanism of the LSI remains unchanged up to 60% H2. The change in the flame position with increasing H2 concentration is attributed to the increase in the turbulent flame speed. The NOx emissions show a log linear dependency on the adiabatic flame temperature and the concentrations are similar to those obtained previously in a LSI prototype developed for natural gas. These results show that the LSI exhibits the same overall behaviors at STP and at gas turbine conditions. Such insight will be useful for scaling the LSI to operate at IGCC conditions.

327

Mixing Ratios of CO, CO2, CH4, and Isotope Ratios of Associated 13C, 18O,  

NLE Websites -- All DOE Office Websites (Extended Search)

Air Samples, Niwot Ridge, Colorado Air Samples, Niwot Ridge, Colorado Mixing Ratios of CO, CO2, CH4, and Isotope Ratios of Associated 13C, 18O, and 2H in Air Samples from Niwot Ridge, Colorado, and Montaña de Oro, California, USA (January 2004) image Abstract graphics Graphics data Data Investigator Stanley C. Tyler Department of Earth System Science University of California Irvine, CA DOI: 10.3334/CDIAC/atg.db1022 Description and Methods Air samples from Niwot Ridge, Colorado (41°N, 105°W) and Montaña de Oro, CA (35°N, 121°W) have been collected at approximately semi-monthly to monthly intervals since the mid 1990s. The beginning dates for each gas and isotope analyzed are as follows: GASLAB Flask Sampling Network Data Available (April 2003) Gas or isotope Niwot Ridge Montaña de Oro

328

ELECTRON IRRADIATION OF KUIPER BELT SURFACE ICES: TERNARY N{sub 2}-CH{sub 4}-CO MIXTURES AS A CASE STUDY  

Science Conference Proceedings (OSTI)

The space weathering of icy Kuiper Belt Objects was investigated in this case study by exposing methane (CH{sub 4}) and carbon monoxide (CO) doped nitrogen (N{sub 2}) ices at 10 K to ionizing radiation in the form of energetic electrons. Online and in situ Fourier transform infrared spectroscopy was utilized to monitor the radiation-induced chemical processing of these ices. Along with isocyanic acid (HNCO), the products could be mainly derived from those formed in irradiated binary ices of the N{sub 2}-CH{sub 4} and CO-CH{sub 4} systems: nitrogen-bearing products were found in the form of hydrogen cyanide (HCN), hydrogen isocyanide (HNC), diazomethane (CH{sub 2}N{sub 2}), and its radical fragment (HCN{sub 2}); oxygen-bearing products were of acetaldehyde (CH{sub 3}CHO), formyl radical (HCO), and formaldehyde (H{sub 2}CO). As in the pure ices, the methyl radical (CH{sub 3}) and ethane (C{sub 2}H{sub 6}) were also detected, as were carbon dioxide (CO{sub 2}) and the azide radical (N{sub 3}). Based on the temporal evolution of the newly formed products, kinetic reaction schemes were then developed to fit the temporal profiles of the newly formed species, resulting in numerical sets of rate constants. The current study highlights important constraints on the preferential formation of isocyanic acid (HNCO) over hydrogen cyanide (HCN) and hydrogen isocyanide (HNC), thus guiding the astrobiological and chemical evolution of those distant bodies.

Kim, Y. S.; Kaiser, R. I., E-mail: ralfk@hawaii.edu [Department of Chemistry, University of Hawaii at Manoa, Honolulu, HI 96822 (United States)

2012-10-10T23:59:59.000Z

329

Gulf Coast (PADD 3) Exports of Crude Oil and Petroleum Products  

U.S. Energy Information Administration (EIA)

Area: Period-Unit: Download Series History ... 51: 64: 59: 70: 70: 62: 2009-2013: Methyl Tertiary Butyl Ether (MTBE) 41: 44: 49: 61: 49: 50: 2004-2013: Other ...

330

U.S. Oxygenate Production - Energy Information Administration  

U.S. Energy Information Administration (EIA)

Area: Apr-13 May-13 Jun-13 Jul-13 Aug-13 Sep-13 View History; Fuel Ethanol: 855: 877: 891: 868: 849: 852: 1981-2013: Methyl Tertiary Butyl Ether (MTBE) 48: 55: 54: 51 ...

331

Radiation Chemistry of MTBE in Aqueous Solution  

NLE Websites -- All DOE Office Websites (Extended Search)

Methyl-tert-Butyl Ether (MTBE) in Aqueous Solution Stephen P. Mezyk, Jace Jones, William J. Cooper, Thomas Tobien, Michael G. Nickelsen, J. Wesley Adams, Kevin E. O'Shea, David M....

332

Preparations for Meeting New York and Connecticut MTBE Bans  

Reports and Publications (EIA)

In response to a Congressional request, EIA examined the progress being made to meet the bans on the use of methyl tertiary butyl ether (MTBE) being implemented in New York and Connecticut at the end of 2003.

Joanne Shore

2003-10-01T23:59:59.000Z

333

35461,"AECTRA REFG & MKTG",1,152,"MOTOR GAS, OTHER FINISHED"...  

U.S. Energy Information Administration (EIA) Indexed Site

TERTIARY BUTYL ETHER (MTBE)",2809,"SANFRANCISCO, CA","CALIFORNIA",5,515,"KOREA, REPUBLIC OF",32,0,0,"WICKLAND OIL CO","SELBY TERM","CA","CALIFORNIA",5...

334

Influence of the Particle Formation and Behavior on the Electrical Parameters in Low Pressure Radio-Frequency CH{sub 4}/N{sub 2} Discharges  

Science Conference Proceedings (OSTI)

The particle formation in low pressure radio-frequency (13.56 MHz) CH{sub 4}/N{sub 2} discharges results from the gas decomposition and from the sputtering of the powered electrode. The particle formation and behavior are strongly modified with the nitrogen amount increase in the mixture. The observation of the particles in the CH{sub 4}/N{sub 2} mixture containing 70% of N{sub 2} reveals a particular particle behavior. The particle behavior is correlated with the electrical parameters of the discharge.

Pereira, J.; Massereau-Guilbaud, V.; Geraud-Grenier, I.; Plain, A. [LASEP, Faculte des Sciences, Universite d'Orleans, Site de Bourges, rue G. Berger, BP 4043, 18028 BOURGES CEDEX (France)

2008-03-19T23:59:59.000Z

335

Annual Energy Outlook 2005-Acronyms  

Gasoline and Diesel Fuel Update (EIA)

AD AD Associated-dissolved (natural gas) AEO2004 Annual Energy Outlook 2004 AEO2005 Annual Energy Outlook 2005 Altos Altos Partners AMT Alternative Minimum Tax ANWR Arctic National Wildlife Refuge Btu British thermal unit CAFE Corporate average fuel economy CAMR Clean Air Mercury Rule CARB California Air Resources Board CBECS Commercial Buildings Energy Consumption Survey (EIA) CBO Congressional Budget Office CCCC Climate Change Credit Corporation CH 4 Methane CHP Combined heat and power CO 2 Carbon dioxide CTL Coal-to-liquids DB Deutsche Bank, A.G. E85 Fuel containing a blend of 70 to 85 percent ethanol and 30 to 15 percent gasoline by volume EEA Energy and Environmental Analysis, Inc. EIA Energy Information Administration EPA U.S. Environmental Protection Agency EPACT Energy Policy Act of 1992 ETBE Ethyl tertiary butyl ether EVA Energy Ventures Analysis, Incorporated FERC

336

Electrochemical Investigation of AlLi/LixFePO4 Cells in Oligo(ethylene glycol) Dimethyl Ether/LiPF6  

DOE Green Energy (OSTI)

1 M LiPF{sub 6} dissolved in oligo(ethylene glycol) dimethyl ether with a molecular weight, 500 g mol{sup -1} (OEGDME500, 1 M LiPF{sub 6}), was investigated as an electrolyte in experimental Al-Li/LiFePO{sub 4} cells. More than 60 cycles were achieved using this electrolyte in a Li-ion cell with an Al-Li alloy as an anode sandwiched between two Li x FePO{sub 4} electrodes (cathodes). Charging efficiencies of 96-100% and energy efficiencies of 86-89% were maintained during 60 cycles at low current densities. A theoretical investigation revealed that the specific energy can be increased up to 15% if conventional LiC{sub 6} anodes are replaced by Al-Li alloy electrodes. The specific energy and the energy density were calculated as a function of the active mass per electrode surface (charge density). The results reveal that for a charge density of 4 mAh cm{sup -2} about 160 mWh g{sup -1} can be reached with Al-Li/LiFePO{sub 4} batteries. Power limiting diffusion processes are discussed, and the power capability of Al-Li/LiFePO{sub 4} cells was experimentally evaluated using conventional electrolytes.

Wang, X.J.; Zhou, Y.N.; Lee, H.S.; Nam, K.W.; Yang, X.Q.; Haas, O.

2011-02-01T23:59:59.000Z

337

Books and book chapters (last 10 years only) 16. Clark, E. Ann. 2009. Ch. 5 (invited). Forages in Organic Crop-Livestock Systems. pp. 85-  

E-Print Network (OSTI)

Books and book chapters (last 10 years only) 16. Clark, E. Ann. 2009. Ch. 5 (invited). Forages, Agriculture, and Engineering Service, Cooperative Extension, Ithaca, N.Y. (Peer-reviewed book chapter) 12 Service, Cooperative Extension, Ithaca, N.Y. (Peer-reviewed book chapter) 11. Clark, E. Ann. 2004 . GM

Clark, E. Ann

338

The European land and inland water CO2, CO, CH4 and N2O balance between 2001 and 2005  

SciTech Connect

Globally, terrestrial ecosystems have absorbed about 30% of anthropogenic greenhouse gas emissions over the period 2000-2007 and inter-hemispheric gradients indicate that a significant fraction of terrestrial carbon sequestration must be north of the Equator. We present a compilation of the CO{sub 2}, CO, CH{sub 4} and N{sub 2}O balances of Europe following a dual constraint approach in which (1) a land-based balance derived mainly from ecosystem carbon inventories and (2) a land-based balance derived from flux measurements are compared to (3) the atmospheric data-based balance derived from inversions constrained by measurements of atmospheric GHG (greenhouse gas) concentrations. Good agreement between the GHG balances based on fluxes (1294 {+-} 545 Tg C in CO{sub 2}-eq yr{sup -1}), inventories (1299 {+-} 200 Tg C in CO{sub 2}-eq yr{sup -1}) and inversions (1210 {+-} 405 Tg C in CO{sub 2}-eq yr{sup -1}) increases our confidence that the processes underlying the European GHG budget are well understood and reasonably sampled. However, the uncertainty remains large and largely lacks formal estimates. Given that European net land to atmosphere exchanges are determined by a few dominant fluxes, the uncertainty of these key components needs to be formally estimated before efforts could be made to reduce the overall uncertainty. The net land-to-atmosphere flux is a net source for CO{sub 2}, CO, CH{sub 4} and N{sub 2}O, because the anthropogenic emissions by far exceed the biogenic sink strength. The dual-constraint approach confirmed that the European biogenic sink removes as much as 205 {+-} 72 Tg C yr{sup -1} from fossil fuel burning from the atmosphere. However, This C is being sequestered in both terrestrial and inland aquatic ecosystems. If the C-cost for ecosystem management is taken into account, the net uptake of ecosystems is estimated to decrease by 45% but still indicates substantial C-sequestration. However, when the balance is extended from CO{sub 2} towards the main GHGs, C-uptake by terrestrial and aquatic ecosystems is offset by emissions of non-CO{sub 2} GHGs. As such, the European ecosystems are unlikely to contribute to mitigating the effects of climate change.

Luyassaert, S [CEA-CNRS-UVSQ, LSCE; Abril, G [Laboratoire EPOC, CNRS; Andres, Robert Joseph [ORNL; Bastviken, D [Linkoping University; Bellassen, V [CEA-CNRS-UVSQ, LSCE; Bergamaschi, P [European Commission Joint Research Centre; Bousquet, P [CEA-CNRS-UVSQ, LSCE; Chevallier, F [CEA-CNRS-UVSQ, LSCE; Ciais, P. [LSCE/CEA, Gif-sur-Yvette, France; Corazza, M [European Commission Joint Research Centre; Dechow, R [Johann Heinrich von Thnen Institute; Erb, K-H [Alpen-Adria Universitaet Klagenfurt-Vienna-Graz; Etiope, G [Istituto Nazionale di Geofisica e Vulcanologia; Fortems-Cheiney, A [CEA-CNRS-UVSQ, LSCE; Grassi, G [European Commission Joint Research Centre; Hartmann, J [University of Hamburg; Jung, M. [Max Planck Institute for Biogeochemistry; Lathiere, J [CEA-CNRS-UVSQ, LSCE; Lohila, A [Finnish Meteorological institute; Mayorga, E [University of Washington; Moosdorf, N [University of Hamburg; Njakou, D [University of Antwerp; Otto, J [CEA-CNRS-UVSQ, LSCE; Papale, D. [University of Tuscia; Peters, W [Wageningen University and Research Centre, The Netherlands; Peylin, P [CEA-CNRS-UVSQ, LSCE; Raymond, Peter A [Yale School of Forestry and Environmental Studies; Rodenbeck, C [Max Planck Institute for Biogeochemistry; Saarnio, S [University of Eastern Finland; Schulze, E.-D. [Max Planck Institute for Biogeochemistry; Szopa, S [CEA-CNRS-UVSQ, LSCE; Thompson, R [CEA-CNRS-UVSQ, LSCE; Verkerk, P [European Forest Institute; Vuichard, N [CEA-CNRS-UVSQ, LSCE; Wang, R [Peking University; Wattenbach, M [Helmholtz Centre Potsdam GFZ German Research Centre For Geosciences; Zaehle, S [Max Planck Institute for Biogeochemistry

2012-01-01T23:59:59.000Z

339

THE DETECTION OF INTERSTELLAR ETHANIMINE (CH{sub 3}CHNH) FROM OBSERVATIONS TAKEN DURING THE GBT PRIMOS SURVEY  

SciTech Connect

We have performed reaction product screening measurements using broadband rotational spectroscopy to identify rotational transition matches between laboratory spectra and the Green Bank Telescope PRIMOS radio astronomy survey spectra in Sagittarius B2 North (Sgr B2(N)). The broadband rotational spectrum of molecules created in an electrical discharge of CH{sub 3}CN and H{sub 2}S contained several frequency matches to unidentified features in the PRIMOS survey that did not have molecular assignments based on standard radio astronomy spectral catalogs. Several of these transitions are assigned to the E- and Z-isomers of ethanimine. Global fits of the rotational spectra of these isomers in the range of 8-130 GHz have been performed for both isomers using previously published mm-wave spectroscopy measurements and the microwave measurements of the current study. Possible interstellar chemistry formation routes for E-ethanimine and Z-ethanimine are discussed. The detection of ethanimine is significant because of its possible role in the formation of alanine-one of the twenty amino acids in the genetic code.

Loomis, Ryan A.; Zaleski, Daniel P.; Steber, Amanda L.; Neill, Justin L.; Muckle, Matthew T.; Harris, Brent J.; Pate, Brooks H. [Department of Chemistry, University of Virginia, McCormick Road, Charlottesville, VA 22904 (United States); Hollis, Jan M. [NASA Goddard Space Flight Center, Greenbelt, MD 20771 (United States); Jewell, Philip R.; Remijan, Anthony J. [National Radio Astronomy Observatory, 520 Edgemont Road, Charlottesville, VA 22904-2475 (United States); Lattanzi, Valerio; Martinez, Oscar Jr.; McCarthy, Michael C. [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Lovas, Frank J. [National Institute of Standards and Technology, Gaithersburg, MD 20899 (United States); Corby, Joanna F. [Department of Astronomy, University of Virginia, McCormick Road, Charlottesville, VA 22904 (United States)

2013-03-01T23:59:59.000Z

340

Photoelectron imaging of atomic chlorine and bromine following photolysis of CH{sub 2}BrCl  

Science Conference Proceedings (OSTI)

Photoionization of chlorine and bromine atoms following photodissociation of CH{sub 2}BrCl was studied in the wavelength range of 231-238 nm by photoelectron imaging technique. Final state-specific speed and angular distributions of the photoelectron were recorded. Analysis of relative branching ratios to different levels of Cl{sup +} and Br{sup +} revealed that the final ion level distributions are generally dominated by the preservation of the ion-core configuration of the intermediate resonant state. Some J{sub c} numbers of the intermediate states were newly assigned according to this regulation. The configuration interaction between resonant states and the autoionization in the continuum were also believed to play an important role in the ionization process since some ions that deviate from the regulation mentioned ahead were observed. The angular distributions of the electrons were found to be well characterized by {beta}{sub 2} and {beta}{sub 4}, although the ionization process of chlorine and bromine atoms involves three photons.

Hua Linqiang; Shen Huan; Hu Changjin; Zhang Bing [State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wuhan Institute of Physics and Mathematics, Chinese Academy of Sciences, Wuhan 430071 (China) and Graduate School of the Chinese Academy of Sciences, Beijing 100039 (China)

2008-12-28T23:59:59.000Z

Note: This page contains sample records for the topic "butyl ether ch" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Polarization effects in low-energy electron-CH sub 4 elastic collisions in an exact exchange treatment  

Science Conference Proceedings (OSTI)

We have investigated the polarization effects in very-low-energy (below 1 eV) electron- CH{sub 4} collisions in an exact-exchange treatment. The two models of the parameter-free polarization potential are employed; one, the {ital V}{sub pol}{sup JT} potential, introduced by Jain and Thompson (J. Phys. B 15, L631 (1982)), is based on an approximate polarized-orbital method, and two, the correlation-polarization potential {ital V}{sub pol}{sup CP}, first proposed by O'Connel and Lane (Phys. Rev. A 27, 1893 (1983)), is given as a simple analytic form in terms of the charge density of the target. In this rather very low-energy region, the polarization effects play a decisive role, particularly in creating structure in the differential cross section (DCS) and producing the Ramsauer-Townsend minimum in the total cross section. Our DCS at 0.2, 0.4, and 0.6 eV are compared with recent measurements. We found that a local parameter-free approximation for the polarization potential is quite successful if it is determined under the polarized-orbital-type technique rather than based on the correlation-polarization approach.

Jain, A.; Weatherford, C.A. (Department of Physics, Box 981, Florida A M University, Tallahassee, Florida 32307 (USA)); Thompson, D.G.; McNaughten, P. (Department of Applied Mathematics and Theoretical Physics The Queen's University, Belfast, BT7 1NN, Northern (Ireland))

1989-12-01T23:59:59.000Z

342

Photochemistry in a dense manifold of electronic states: Photodissociation of CH{sub 2}ClBr  

Science Conference Proceedings (OSTI)

We report electronically nonadiabatic dynamics calculations including spin-orbit coupling for the photodissociation of CH{sub 2}ClBr to yield Cl({sup 2}P{sub 3/2}), Cl({sup 2}P{sub 1/2}), Br({sup 2}P{sub 3/2}), and Br({sup 2}P{sub 1/2}). The potential energy is a 24 Multiplication-Sign 24 matrix (divided up here into four 6 Multiplication-Sign 6 blocks in a first approximation to the problem), in a spin-coupled fully diabatic representation obtained by combining the spin-free fourfold way with single-center spin-orbit coupling constants. The spin-free calculations are carried out by multiconfiguration quasidegenerate perturbation theory, and the fully diabatic potentials including spin-orbit coupling are fit to a matrix reactive force field. The dynamics are carried out by the coherent switches with decay of mixing method in the diabatic representation. The results show qualitative agreement with experiment.

Valero, Rosendo [Department of Chemistry, University of Coimbra, Coimbra (Portugal); Truhlar, Donald G. [Department of Chemistry and Supercomputing Institute, University of Minnesota, Minneapolis, Minnesota 55455-0431 (United States)

2012-12-14T23:59:59.000Z

343

Standort Treibstoff Abteilung Inverkehrssetzung Verantwortlich E-Mail Telefon Einstellhalle Chemie Nr. 95 Benzin Synkologie 01.11.2000 Alexander Strauss alex.strauss@iee.unibe.ch 031 631 3035  

E-Print Network (OSTI)

Chemie Nr. 95 Benzin Synökologie 01.11.2000 Alexander Strauss alex.strauss@iee.unibe.ch 031 631 3035 3035 Einstellhalle Chemie Nr. 92 Diesel Evolutionsökologie 8.02 Eduard Jutzi eduard.wymann@iee.unibe.ch 031 631 9135 Einstellhalle Chemie ? Populationsgenetik ?? 13.9.05 Susanne Tellenbach susanne

Richner, Heinz

344

269_CH06.indd  

Science Conference Proceedings (OSTI)

AOCS Press, Urbana, IL 61802 2013 by AOCS Press. All rights reserved. No part of this PDF may be reproduced or transmitted in any form or by any means without written permission of the publisher. To order more AOCS prod-

345

CH Packaging Maintenance Manual  

SciTech Connect

This procedure provides instructions for performing inner containment vessel (ICV) and outer containment vessel (OCV) maintenance and periodic leakage rate testing on the following packaging seals and corresponding seal surfaces using a nondestructive helium (He) leak test. In addition, this procedure provides instructions for performing ICV and OCV structural pressure tests.

Washington TRU Solutions

2002-01-02T23:59:59.000Z

346

CH Packaging Program Guidance  

SciTech Connect

The purpose of this document is to provide the technical requirements for preparation for use, operation, inspection, and maintenance of a Transuranic Package Transporter Model II (TRUPACT-II), a HalfPACT Shipping Package, and directly related components. This document complies with the minimum requirements as specified in TRUPACT-II Safety Analysis Report for Packaging (SARP), HalfPACT SARP, and Nuclear Regulatory Commission (NRC) Certificates of Compliance (C of C) 9218 and 9279, respectively. In the event there is a conflict between this document and the SARP or C of C, the SARP and/or C of C shall govern. C of Cs state: ''each package must be prepared for shipment and operated in accordance with the procedures described in Chapter 7.0, Operating Procedures, of the application.'' They further state: ''each package must be tested and maintained in accordance with the procedures described in Chapter 8.0, Acceptance Tests and Maintenance Program of the Application.'' Chapter 9.0 of the SAR P charges the WIPP Management and Operation (M&O) contractor with assuring packaging is used in accordance with the requirements of the C of C. Because the packaging is NRC-approved, users need to be familiar with 10 CFR 71.11. Any time a user suspects or has indications that the conditions of approval in the C of C were not met, the Carlsbad Field Office (CBFO) shall be notified immediately. CBFO will evaluate the issue and notify the NRC if required. This document details the instructions to be followed to operate, maintain, and test the TRUPACT-II and HalfPACT packaging. The intent of these instructions is to standardize these operations. All users will follow these instructions or equivalent instructions that assure operations are safe and meet the requirements of the SARPs.

Washington TRU Solutions LLC

2002-03-04T23:59:59.000Z

347

CH Packaging Operations Manual  

Science Conference Proceedings (OSTI)

This document provides the user with instructions for assembling a payload. All the steps in Subsections 1.2, Preparing 55-Gallon Drum Payload Assembly; 1.3, Preparing "Short" 85-Gallon Drum Payload Assembly (TRUPACT-II and HalfPACT); 1.4, Preparing "Tall" 85-Gallon Drum Payload Assembly (HalfPACT only); 1.5, Preparing 100-Gallon Drum Payload Assembly; 1.6, Preparing SWB Payload Assembly; and 1.7, Preparing TDOP Payload Assembly, must be completed, but may be performed in any order as long as radiological control steps are not bypassed.

Washington TRU Solutions LLC

2005-02-28T23:59:59.000Z

348

CH Packaging Program Guidance  

Science Conference Proceedings (OSTI)

The purpose of this document is to provide the technical requirements for preparation for use, operation, inspection, and maintenance of a Transuranic Package Transporter Model II (TRUPACT-II), a HalfPACT shipping package, and directly related components. This document complies with the minimum requirements as specified in the TRUPACT-II Safety Analysis Report for Packaging (SARP), HalfPACT SARP, and Nuclear Regulatory Commission (NRC) Certificates of Compliance (C of C) 9218 and 9279, respectively. In the event of a conflict between this document and the SARP or C of C, the C of C shall govern. The C of Cs state: ''each package must be prepared for shipment and operated in accordance with the procedures described in Chapter 7.0, Operating Procedures, of the application.'' They further state: ''each package must be tested and maintained in accordance with the procedures described in Chapter 8.0, Acceptance Tests and Maintenance Program of the Application.'' Chapter 9.0 of the SARP charges the WIPP management and operating (M&O) contractor with assuring packaging is used in accordance with the requirements of the C of C. Because the packaging is NRC-approved, users need to be familiar with 10 CFR 71.11. Any time a user suspects or has indications that the conditions of approval in the C of C were not met, the Carlsbad Field Office (CBFO) shall be notified immediately. CBFO will evaluate the issue and notify the NRC if required. This document provides the instructions to be followed to operate, maintain, and test the TRUPACT-II and HalfPACT packaging. The intent of these instructions is to standardize operations. All users will follow these instructions or equivalent instructions that assure operations are safe and meet the requirements of the SARPs.

Washington TRU Solutions LLC

2003-04-30T23:59:59.000Z

349

CH Packaging Program Guidance  

Science Conference Proceedings (OSTI)

The purpose of this document is to provide the technical requirements for preparation for use, operation, inspection, and maintenance of a Transuranic Package Transporter Model II (TRUPACT-II), a HalfPACT shipping package, and directly related components. This document complies with the minimum requirements as specified in the TRUPACT-II Safety Analysis Report for Packaging (SARP), HalfPACT SARP, and U.S. Nuclear Regulatory Commission (NRC) Certificates of Compliance (C of C) 9218 and 9279, respectively. In the event of a conflict between this document and the SARP or C of C, the C of C shall govern. The C of Cs state: "each package must be prepared for shipment and operated in accordance with the procedures described in Chapter 7.0, Operating Procedures, of the application." They further state: "each package must be tested and maintained in accordance with the procedures described in Chapter 8.0, Acceptance Tests and Maintenance Program of the Application." Chapter 9.0 of the SARP charges the Waste Isolation Pilot Plant (WIPP) management and operating (M&O) contractor with assuring packaging is used in accordance with the requirements of the C of C. Because the packaging is NRC-approved, users need to be familiar with Title 10 Code of Federal Regulations (CFR) 71.8. Any time a user suspects or has indications that the conditions of approval in the C of C were not met, the Carlsbad Field Office (CBFO) shall be notified immediately. The CBFO will evaluate the issue and notify the NRC if required.

Washington TRU Solutions LLC

2005-02-28T23:59:59.000Z

350

Ch7_Appendix A  

Science Conference Proceedings (OSTI)

... enable Prototypes and pilot models of flat ... Distributed Multi-agent-based optimization Real-time Control ... a generic mathematical model of process ...

2002-07-26T23:59:59.000Z

351

Modeling of microwave discharges of H{sub 2} admixed with CH{sub 4} for diamond deposition  

Science Conference Proceedings (OSTI)

Microwave discharges of H{sub 2} admixed with CH{sub 4} in a moderate-pressure quartz bell jar reactor used for diamond deposition are studied numerically. Special attention was devoted to high-power densities which provide the most effective way for producing high-quality diamond films. First, a one-dimensional radial model describing the coupled phenomena of chemistry, energy transfer, as well as species and energy transport along the reactor's radial coordinate was developed. Species densities predicted with the model were compared with measurements with infrared tunable diode laser spectroscopy, resulting in validation of the model. Second, a one-dimensional axial model was used to describe the plasma flow along the reactor axis in a region between the reactor end wall and the substrate surface. This model was particularly useful for studying the plasma behavior in the vicinity of the substrate surface, where thermal and composition gradients are large. Both the radial and axial transport models are based on the same discharge model in which the plasma is described as a thermochemically nonequilibrium flow with different energy distributions for heavy species and electrons. The chemistry was described with a model containing 28 species and 131 reactions. The electron temperature, the gas temperature, and the species concentration were determined by solving a coupled set of equations. A wide range of experimental conditions used for diamond deposition was simulated, from low microwave power density (9 W cm{sup -3}, i.e., 600 W, 2500 Pa, and T{sub g}{approx}2200 K) to high-power density (30 W cm{sup -3}, i.e., 2 kW, 12 000 Pa, and T{sub g}{approx}3200 K). The main chemical paths were identified, and the major species, transport effects, and reaction pathways that govern diamond deposition plasmas are discussed.

Lombardi, G.; Hassouni, K.; Stancu, G.-D.; Mechold, L.; Roepcke, J.; Gicquel, A. [Laboratoire d'Ingenierie des Materiaux et des Hautes Pressions, Centre National de la Recherche Scientifique (CNRS) UPR 1311-Universite Paris 13-99, av. J.B. Clement, 93430 Villetaneuse (France); INP-Greifswald, Friedrich-Ludwig-Jahn-Strasse 19, 17489 Greifswald (Germany); Laser Components GmbH, 82140 Olching, Werner-von-Siemens-Strasse 15 (Germany); INP-Greifswald, Friedrich-Ludwig-Jahn-Strasse 19, 17489 Greifswald (Germany); Laboratoire d'Ingenierie des Materiaux et des Hautes Pressions, Centre National de la Recherche Scientifique (CNRS) UPR 1311-Universite Paris 13-99, av. J.B. Clement, 93430 Villetaneuse (France)

2005-09-01T23:59:59.000Z

352

Review of Richland Operations Office and CH2M Hill Plateau Remediation Company and Mission Support Alliance Conduct of Operations, April 2012  

NLE Websites -- All DOE Office Websites (Extended Search)

Independent Oversight Review of Independent Oversight Review of Richland Operations Office and CH2M HILL Plateau Remediation Company and Mission Support Alliance Conduct of Operations April 2012 Office of Safety and Emergency Management Evaluations Office of Enforcement and Oversight Office of Health, Safety and Security U.S. Department of Energy i Table of Contents 1.0 Purpose ................................................................................................................................................... 1 2.0 Background ............................................................................................................................................ 1 3.0 Scope ...................................................................................................................................................... 2

353

Review of Richland Operations Office and CH2M Hill Plateau Remediation Company and Mission Support Alliance Conduct of Operations, April 2012  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Oversight Review of Oversight Review of Richland Operations Office and CH2M HILL Plateau Remediation Company and Mission Support Alliance Conduct of Operations April 2012 Office of Safety and Emergency Management Evaluations Office of Enforcement and Oversight Office of Health, Safety and Security U.S. Department of Energy i Table of Contents 1.0 Purpose ................................................................................................................................................... 1 2.0 Background ............................................................................................................................................ 1 3.0 Scope ...................................................................................................................................................... 2

354

Carbon isotopes in peat, DOC, CO{sub 2}, and CH{sub 4} in a Holocene peatland on Dartmoor, southwest England  

Science Conference Proceedings (OSTI)

Carbon gases with younger {sup 14}C ages than those of the surrounding peat have been reported from continental boreal peatlands, a fact which suggests that significant movement of CO{sub 2}, CH{sub 4}, or DOC (dissolved organic carbon) and export of C via subsurface processes are not accounted for in most estimates of contributions to the C cycle. This paper tests the hypothesis that similar processes can occur in oceanic ombrotrophic mires where water and gas movement is theoretically minimal. Measurements of {sup 14}C and {delta}{sup 13}C in CO{sub 2}, CH{sub 4}, and DOC, and of tritium, are reported from depths to 250 cm at Tor Royal, a raised mire in southwest England. Radiocarbon ages of gases are 1,460 to 500 yr younger than those of peat from the same depths, and CO{sub 2} is consistently younger than CH{sub 4}. DOC is 1,260 to 830 yr younger than the peat, and significant amounts of tritium were found at all depths. Gas ages are mostly intermediate between the age of the peat and that of the DOC, which suggests that C is principally transported as DOC. However, some gases are younger than their associated DOC, which implies that movement of dissolved gases may also take place. {delta}{sup 13}C values in gases suggest that CO{sub 2} reduction is the major pathway for CH{sub 4} production. Transport of C in deep peats is likely to be a significant component in the overall C budget of ombrotrophic oceanic peatlands, and C export via discharge to ground or surface waters may be an important mechanism for gaseous C emissions.

Charman, D.J. [Univ. of Plymouth (United Kingdom). Dept. of Geographical Sciences; Aravena, R. [Univ. of Waterloo, Ontario (Canada). Dept. of Earth Sciences; Bryant, C.L.; Harkness, D.D. [Natural Environment Research Council Radiocarbon Lab., Glasgow (United Kingdom)

1999-06-01T23:59:59.000Z

355

Activity of tungsten and rhenium filaments in CH sub 4 /H sub 2 and C sub 2 H sub 2 /H sub 2 mixtures: Importance for diamond CVD  

DOE Green Energy (OSTI)

The resistance R, spectral emissivity {epsilon}, and power consumption of W and Re filaments heated to 2500 {degree}C in mixtures of CH{sub 4} or C{sub 2}H{sub 2} in H{sub 2} have been measured in a series of experiments focusing on the state of the filament activity, i.e., its ability to dissociate the reactant gases. It has been found that these properties of the filaments, as well as the partial pressures of CH{sub 4} and C{sub 2}H{sub 2} in the reaction chamber, depend critically on both the filament temperature and the reactant ratio, e.g., C{sub 2}H{sub 2}/H{sub 2}. Specifically, both W and Re filaments show sharp jumps in power consumption at essentially the same temperature, signaling strong increases in filament activity and, hence, production of atomic hydrogen. These results are proposed to be due to the removal of non-reactive carbon from the surface of the filament via etching by atomic hydrogen and are consistent with the predictions of our thermodynamic model for the C-H system. Evidence for gas phase reactions is presented and the role of thermal diffusion is discussed. The emissivities of the W and Re filaments are observed to have significantly different temperature dependences which are attributed to differences in the phase diagrams for the W-C and Re-C systems. The implications of these results for hot-filament diamond CVD are discussed.

Sommer, M.; Smith, F.W. (Department of Physics, The City College of the City University of New York, New York, NY (USA))

1990-11-01T23:59:59.000Z

356

Nitrogen effect on the dust presence and behavior in a radio frequency CH{sub 4}/N{sub 2} discharge  

Science Conference Proceedings (OSTI)

In this paper, we have studied the effects of the nitrogen percentage on particles generated in low pressure radio frequency CH{sub 4}/N{sub 2} discharges. The particle behavior has been analyzed by laser beam extinction and scattering. The nitrogen percentage in the mixture influences the particle presence, behavior, and size in the discharge. For nitrogen percentages greater than 50%, we have evidenced a particle multigeneration and oscillations in particle clouds. These oscillations have been correlated with the discharge electrical parameters.

Pereira, Jeremy; Massereau-Guilbaud, Veronique; Geraud-Grenier, Isabelle; Plain, Andre [LASEP, Faculte des Sciences, Universite d'Orleans, Site de Bourges, rue G. Berger, BP 4043, 18028 Bourges Cedex (France)

2008-02-01T23:59:59.000Z

357

Concentrations and fluxes of dissolved biogenic gases (DMS, CH{sub 4}, CO, CO{sub 2}) in the equatorial Pacific during the SAGA 3 experiment  

Science Conference Proceedings (OSTI)

The equatorial Pacific Ocean is a source of both sulfur and carbon to the atmosphere. In February and March 1990, as part of the Soviet-American Gases and Aerosols (SAGA 3) expedition, dimethylsulfide (DMS), methane (CH{sub 4}), carbon monoxide (CO), and carbon dioxide (CO{sub 2}) partial pressures were determined in both surface seawater and the overlying atmosphere of the central equatorial Pacific Ocean (15{degrees}N to 10{degrees}S, 145{degrees}W to 165{degrees}W). The partial pressures were used to calculate the net flux of these gases from the ocean to the atmosphere. The average regional DMS and CO fluxes were similar, 7.1 and 4.2 {mu}mol/m{sup 2}/d, respectively. The mixing ratio of CH{sub 4} in surface seawater was close to equilibrium with the overlying atmosphere and hence the average flux was only 0.39 {mu}mol/m{sup 2}/d. The flux of CO{sub 2} clearly dominated the air-sea carbon exchange with an average regional flux of 5.4 mmol/m{sup 2}/d. 64 refs., 6 figs., 1 tab.

Bates, T.S.; Johnson, J.E. [Pacific Marine Environmental Lab., Seattle, WA (United States)]|[Univ. of Washington, Seattle, WA (United States); Kelly, K.C. [Pacific Marine Environmental Lab., Seattle, WA (United States)

1993-09-20T23:59:59.000Z

358

Thermodynamic Studies of [H2Rh(diphosphine)2]+ and [HRh(diphosphine)2(CH3CN)]2+ Complexes in Acetonitrile  

DOE Green Energy (OSTI)

Thermodynamic studies of a series of [H2Rh(PP)2]+ and [HRh(PP)2(CH3CN)]2+ complexes have been carried out in acetonitrile. Seven different diphosphine (PP) ligands were selected to allow variation of the electronic properties of the ligand substituents, the cone angles, and the natural bite angles (NBAs). Oxidative addition of H2 to [Rh(PP)2]+ complexes is favored by diphosphine ligands with large NBAs, small cone angles, and electron donating substituents, with the NBA being the dominant factor. Large pKa values for [HRh(PP)2(CH3CN)]2+ complexes are favored by small ligand cone angles, small NBAs, and electron donating substituents with the cone angles playing a major role. The hydride donor abilities of [H2Rh(PP)2]+ complexes increase as the NBAs decrease, the cone angles decrease, and the electron donor abilities of the substituents increase. These results indicate that if solvent coordination is involved in hydride transfer or proton transfer reactions, the observed trends can be understood in terms of a combination of two different steric effects, NBAs and cone angles, and electron-donor effects of the ligand substituents.

Aaron D. Wilson; Alexander J. M. Miller; Daniel L. DuBois; Jay A. Labinger; John E. Bercaw

2011-04-01T23:59:59.000Z

359

Piloted jet flames of CH{sub 4}/H{sub 2}/air: Experiments on localized extinction in the near field at high Reynolds numbers  

SciTech Connect

Measurements of temperature and major species concentrations, based on the simultaneous line-imaged Raman/Rayleigh/CO-LIF technique, are reported for piloted jet flames of CH{sub 4}/H{sub 2} fuel with varying amounts of partial premixing with air (jet equivalence ratios of {phi}{sub j} = 3.2, 2.5, 2.1 corresponding to stoichiometric mixture fraction values of {xi}{sub st} = 0.35, 0.43, 0.50, respectively) and varying degrees of localized extinction. Each jet flame is operated at a fixed and relatively high exit Reynolds number (60,000 or 67,000), and the probability of localized extinction is increased in several steps by progressively decreasing the flow rate of the pilot flame. Dimensions of the piloted burner, originally developed at Sydney University, are the same as for previous studies. The present measurements complement previous results from piloted CH{sub 4}/air jet flames as targets for combustion model calculations by extending to higher Reynolds number, including more steps in the progression of each flame from a fully burning state to a flame with high probability of local extinction, and adding the degree of partial premixing as an experimental parameter. Local extinction in these flames occurs close to the nozzle near a downstream location of four times the jet exit diameter. Consequently, these data provide the additional modeling challenge of accurately representing the initial development of the reacting jet and the near-field mixing processes. (author)

Barlow, R.S. [Combustion Research Facility, Sandia National Laboratories, Livermore, CA 94551-0969 (United States); Ozarovsky, H.C.; Lindstedt, R.P. [Department of Mechanical Engineering, Imperial College London, Exhibition Road, London SW7-2AZ (United Kingdom); Karpetis, A.N. [Department of Aerospace Engineering, Texas A and M University, College Station, TX 778453-3141 (United States)

2009-11-15T23:59:59.000Z

360

Densities and viscosities for binary mixtures of N-methyldiethanolamine + triethylene glycol monomethyl ether from 25 C to 70 C and N-methyldiethanolamine + ethanol mixtures at 40 C  

Science Conference Proceedings (OSTI)

Recent studies done on the absorption and desorption of acid gases (CO{sub 2}, H{sub 2}S) from natural gas, petroleum, and ammonia synthesis streams have shown that aqueous solutions of N-methyldiethanolamine (MDEA) can be used effectively for the selective removal of H{sub 2}S. This paper reports the measured values of the density and viscosity of binary mixtures of N-methyldiethanolamine (MDEA) and triethylene glycol monomethyl ether (TEGMME) at five temperatures in the range 25 C to 70 C over the whole concentration range. The authors also report the density and viscosity of the binary mixture MDEA + ethanol at 40 C. The results are compared with data for aqueous mixtures and other alkanolamines when these are available. The derived excess molar volumes and viscosity deviations were correlated as a function of composition. The Grunberg-Nissan interaction energy constants are also reported.

Henni, A.; Maham, Y.; Tontiwachwuthikul, P.; Chakma, A.; Mather, A.E.

2000-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "butyl ether ch" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Spectroscopic diagnostics and modeling of Ar/H{sub 2}/CH{sub 4} microwave discharges used for nanocrystalline diamond deposition  

Science Conference Proceedings (OSTI)

In this paper Ar/H{sub 2}/CH{sub 4} microwave discharges used for nanocrystalline diamond chemical vapor deposition in a bell-jar cavity reactor were characterized by both experimental and modeling investigations. Discharges containing 1% CH{sub 4} and H{sub 2} percentages ranging between 2% and 7% were analyzed as a function of the input microwave power under a pressure of 200 mbar. Emission spectroscopy and broadband absorption spectroscopy were carried out in the UV-visible spectral range in order to estimate the gas temperature and the C{sub 2} density within the plasma. Infrared tunable diode laser absorption spectroscopy was achieved in order to measure the mole fractions of carbon-containing species such as CH{sub 4}, C{sub 2}H{sub 2}, and C{sub 2}H{sub 6}. A thermochemical model was developed and used in order to estimate the discharge composition, the gas temperature, and the average electron energy in the frame of a quasihomogeneous plasma assumption. Experiments and calculations yielded consistent results with respect to plasma temperature and composition. A relatively high gas temperature ranging between 3000 and 4000 K is found for the investigated discharge conditions. The C{sub 2} density estimated from both experiments and modeling are quite high compared with what is generally reported in the literature for the same kind of plasma system. It ranges between 10{sup 13} and 10{sup 14} cm{sup -3} in the investigated power range. Infrared absorption measurements and model predictions indicate quite low densities of methane and acetylene, while the atomic carbon density calculated by the model ranges between 10{sup 13} and 10{sup 15} cm{sup -3}. The methane and hydrogen introduced in the feed gas are subject to a strong dissociation, which results in a surprisingly high H-atom population with mole fraction ranging between 0.04 and 0.16. Result analysis shows that the power coupling efficiency would range between 70% and 90%, which may at least explain the relatively high values obtained, as compared with those reported in the literature for similar discharges, for gas temperature and C{sub 2} population. The high H-atom densities obtained in this work would indicate that growing nanocrystalline diamond films would experience a very high etching. Simulation results also confirm that sp species would play a key role in the surface chemistry that governs the diamond growth.

Lombardi, G.; Hassouni, K.; Benedic, F.; Mohasseb, F.; Roepcke, J.; Gicquel, A. [Laboratoire d'Ingenierie des Materiaux et des Hautes Pressions, UPR 1311 CNRS, Universite Paris 13, 99 Avenue J.B. Clement, 93430 Villetaneuse (France); INP Greifswald, Friedrich-Ludwig-Jahn-Strasse 19, 17489 Greifswald (Germany); Laboratoire d'Ingenierie des Materiaux et des Hautes Pressions, UPR 1311 CNRS, Universite Paris 13, 99 Avenue J.B. Clement, 93430 Villetaneuse (France)

2004-12-01T23:59:59.000Z

362

Ab initio wavenumber accurate spectroscopy : {sup 1}CH{sub 2} and HCN vibrational levels on automatically generated IMLS potential energy surfaces.  

SciTech Connect

We report here calculated J = 0 vibrational frequencies for {sup 1}CH{sub 2} and HCN with root-mean-square error relative to available measurements of 2.0 cm{sup -1} and 3.2 cm{sup -1}, respectively. These results are obtained with DVR calculations with a dense grid on ab initio potential energy surfaces (PESs). The ab initio electronic structure calculations employed are Davidson-corrected MRCI calculations with double-, triple-, and quadruple-{zeta} basis sets extrapolated to the complete basis set (CBS) limit. In the {sup 1}CH{sub 2} case, Full CI tests of the Davidson correction at small basis set levels lead to a scaling of the correction with the bend angle that can be profitably applied at the CBS limit. Core-valence corrections are added derived from CCSD(T) calculations with and without frozen cores. Relativistic and non-Born-Oppenheimer corrections are available for HCN and were applied. CBS limit CCSD(T) and CASPT2 calculations with the same basis sets were also tried for HCN. The CCSD(T) results are noticeably less accurate than the MRCI results while the CASPT2 results are much poorer. The PESs were generated automatically using the local interpolative moving least-squares method (L-IMLS). A general triatomic code is described where the L-IMLS method is interfaced with several common electronic structure packages. All PESs were computed with this code running in parallel on eight processors. The L-IMLS method provides global and local fitting error measures important in automatically growing the PES from initial ab initio seed points. The reliability of this approach was tested for {sup 1}CH{sub 2} by comparing DVR-calculated vibrational levels on an L-IMLS ab initio surface with levels generated by an explicit ab initio calculation at each DVR grid point. For all levels ({approx}200) below 20000 cm{sup -1}, the mean unsigned difference between the levels of these two calculations was 0.1 cm{sup -1}, consistent with the L-IMLS estimated mean unsigned fitting error of 0.3 cm{sup -1}. All L-IMLS PESs used in this work have comparable mean unsigned fitting errors, implying that fitting errors have a negligible role in the final errors of the computed vibrational levels with experiment. Less than 500 ab initio calculations of the energy and gradients are required to achieve this level of accuracy.

Dawes, R.; Wagner, A. F.; Thompson, D. L.; Chemical Sciences and Engineering Division; Univ. of Missouri at Columbia

2009-04-23T23:59:59.000Z

363

A description of NUEXS, an upgrade of the code FCUP used to compute proton recoil current from CH{sub 2} foils  

SciTech Connect

A computer code, FCUP, developed by A. Craft computes currents of recoil protons from a time- and energy-dependent neutron flux striking a CH{sub 2} foil. Three problem areas need to be addressed to extend the code`s usefulness. First, FCUP computes a response that is not time dependent; that is, only the input time bin is broadened to account for the finite time distribution of protons from a single neutron energy; second, the time coordinate of the signal predicted is translated arbitrarily rather than absolutely relative to the time of maximum neutron production in the source; and third, the code does not account for electron pickup by protons at low proton energies in the target and absorber foils. This report describes the changes in calculational method used to overcome these problems.

Stelts, M.L.; Wood, B.E.

1982-08-01T23:59:59.000Z

364

Measuring Diffusivity in Supercooled Liquid Nanoscale Films using Inert Gas Permeation: II. Diffusion of AR, KR, Xe, and CH4 through Methanol  

DOE Green Energy (OSTI)

We present an experimental technique to measure the diffusivity of supercooled liquids at temperatures near their Tg. The approach uses the permeation of inert gases through supercooled liquid overlayers as a measure of the diffusivity of the supercooled liquid itself. The desorption spectra of the probe gas is used to extract the low temperature supercooled liquid diffusivities. In the preceding companion paper, we derived equations using ideal model simulations from which the diffusivity could be extracted using the desorption peak times for isothermal or peak temperatures for TPD experiments. Here, we discuss the experimental conditions for which these equations are valid and demonstrate their utility using amorphous methanol with Ar, Kr, Xe, and CH4 as probe gases. The approach offers a new method by which the diffusivities of supercooled liquids can be measured in the experimentally challenging temperature regime near the glass transition temperature.

Matthiesen, Jesper; Smith, R. Scott; Kay, Bruce D.

2010-11-07T23:59:59.000Z

365

Projectile fragment emission in fragmentation of $^{56}$Fe on C, Al,and CH$_{2}$ targets at 471 A MeV  

E-Print Network (OSTI)

The emission angle and the transverse momentum distributions of projectile fragments produced in fragmentation of $^{56}$Fe on CH$_{2}$, C, and Al targets at 471 A MeV are measured. It is found that for the same target the average value and width of angular distribution decrease with increase of the projectile fragment charge, and for the same projectile fragment the average value of the distribution increases and the width of the distribution decreases with increasing the target charge number. The transverse momentum distribution of projectile fragment can be explained by a single Gaussian distribution and the averaged transverse momentum per nucleon decreases with the increase of the charge of projectile fragment. The cumulated squared transverse momentum distribution of projectile fragment can be well explained by a single Rayleigh distribution. The temperature parameter of emission source of projectile fragment, calculated from the cumulated squared transverse momentum distribution, decreases with the increase of the size of projectile fragment.

Y. J. Li; D. H. Zhang; S. W. Yan; L. C. Wang; J. X. Cheng; J. S. Li; S. Kodaira; N. Yasuda

2013-09-17T23:59:59.000Z

366

Real-Time Cardiac Imaging at 3 Tesla K.S. NAYAK, C.H. CUNNINGHAM, J.M. SANTOS, J.M. PAULY, AND D.G. NISHIMURA  

E-Print Network (OSTI)

Real-Time Cardiac Imaging at 3 Tesla K.S. NAYAK, C.H. CUNNINGHAM, J.M. SANTOS, J.M. PAULY, AND D are shown in Figure 2. Conclusions We have demonstrated real-time cardiac imaging at 3 Tesla with high SNR

Nayak, Krishna

367

Conversion of CH4/CO2 to syngas over Ni-Co/Al2O3-ZrO2 nanocatalyst synthesized via plasma assisted co-impregnation method: Surface properties and catalytic performance  

Science Conference Proceedings (OSTI)

Ni/Al2O3 catalyst promoted by Co and ZrO2 was prepared by co-impregnation method and treated with glow discharge plasma. The catalytic activity of the synthesized nanocatalysts has been tested toward conversion of CH4/CO2 to syngas. The physicochemical characterizations like XRD EDX

Nader Rahemi; Mohammad Haghighi; Ali Akbar Babaluo; Mahdi Fallah Jafari

2013-01-01T23:59:59.000Z

368

A theoretical analysis of the CH{sub 3} + H reaction : isotope effects, the high pressure limit, and transition state recrossing.  

DOE Green Energy (OSTI)

The reaction of methyl radicals with hydrogen atoms is studied with a combination of ab initio quantum chemistry, variational transition state theory, and classical trajectory simulations. The interaction between the two radicals, including the umbrella mode of the methyl radical, is examined at the CAS+1+2 level using an augmented correlation consistent polarized valence triple zeta basis set. The implementation of an analytic representation of the ab initio data within variable reaction coordinate transition state theory yields predictions for the zero-pressure limit isotopic exchange rate constants that are about 15% greater than the available experimental data. Trajectory simulations indicate that the transition state recrossing factor for the capture process is 0.90, essentially independent of temperature and isotope. The dynamically corrected theoretical prediction for the CH{sub 3} + H high pressure rate coefficient is well reproduced by the expression 1.32 x 10{sup -10}T{sup 0.153}exp(-15.1/RT) cm{sup 3}molecule{sup -1}s{sup -1}, where R = 1.987 cal mole{sup -1} K{sup -1}, for temperatures between 200 and 2400 K. This prediction is in good agreement with the converted experimental data for all but the one measurement at 200 K. Calculations for the triplet abstraction channel suggest that it is unimportant. Methyl umbrella mode variations have surprisingly little effect on the predicted rate coefficients.

Klippenstein, S. J.; Georgievskii, Y.; Harding, L.

2001-12-20T23:59:59.000Z

369

FCC LPG olefinicity and branching enhanced by octane catalysts  

SciTech Connect

Refiners are increasingly recognizing the downstream opportunities for fluid catalytic cracking LPG olefins for the production of methyl tertiary butyl ether (MTBE), ethyl tertiary butyl ether (ETBE, if the ethanol subsidy is extended to the production of ETBE), and as petrochemical feedstocks. Some of new gasoline FCC octane-enhancing catalysts can support those opportunities because their low non-framework alumina (low NFA) preserve both LPG olefinicity and promote branching of the LPG streams from the FCCU. The combined effect results in more isobutane for alkylate feed, more propylene in the propane/propylene stream, and more isobutene - which makes the addition of an MTBE unit very enticing.

Keyworth, D.A.; Reid, T.A.; Kreider, K.R.; Yatsu, C.A.

1989-05-29T23:59:59.000Z

370

LCLS_CDR-ch06  

NLE Websites -- All DOE Office Websites (Extended Search)

6 6 Injector TECHNICAL SYNOPSIS The injector for the LCLS is required to produce a single 150-MeV bunch of charge 1.0 nC and 100 A peak current at a repetition rate of 120 Hz with a normalized rms transverse emittance of 1.0 µm. The required emittance is about a factor of 2 lower than has been achieved to date. The design employs a solenoidal field near the cathode of a specially designed rf photocathode gun that allows the initial emittance growth due to space charge to be almost completely compensated by the end of the booster linac. Following the booster linac, the geometric emittance simply damps linearly with energy. PARMELA simulations show that this design will produce the desired normalized emittance. In addition to low emittance, there are two additional electron-beam requirements that pose

371

LCLS_CDR-ch10  

NLE Websites -- All DOE Office Websites (Extended Search)

0 0 0 Conventional Facilities TECHNICAL SYNOPSIS The LCLS takes advantage of the existing infrastructure at SLAC. It uses the last third of the existing 3 km linac including the existing enclosure and utilities. A new injector will be installed at sector 20 in the Off-Axis Injector Tunnel. This branch tunnel was constructed as part of the original construction at SLAC in the 1960s for just such an injector. The existing linac equipment including the klystrons and modulators will be used. The injector tunnel will require some modifications to bring it to current safety standards and to accommodate the specific requirements of the LCLS injector. Two short sections of linac will be removed to accommodate the magnets and vacuum chambers for the two pulse compressors. New systems to bring power and water to these

372

CB_Ch16.indd  

Science Conference Proceedings (OSTI)

AOCS Press, Urbana, IL 61802 2012 by AOCS Press. All rights reserved. No part of this PDF may be reproduced or transmitted in any form or by any means without written permission of the publisher. To order more AOCS products, please visit our web

373

CB_Ch05.indd  

Science Conference Proceedings (OSTI)

AOCS Press, Urbana, IL 61802 2012 by AOCS Press. All rights reserved. No part of this PDF may be reproduced or transmitted in any form or by any means without written permission of the publisher. To order more AOCS products, please visit our web

374

CB_Ch13.indd  

Science Conference Proceedings (OSTI)

AOCS Press, Urbana, IL 61802 2012 by AOCS Press. All rights reserved. No part of this PDF may be reproduced or transmitted in any form or by any means without written permission of the publisher. To order more AOCS products, please visit our web

375

CB_Ch03.indd  

Science Conference Proceedings (OSTI)

AOCS Press, Urbana, IL 61802 2012 by AOCS Press. All rights reserved. No part of this PDF may be reproduced or transmitted in any form or by any means without written permission of the publisher. To order more AOCS products, please visit our web

376

CB_Ch15.indd  

Science Conference Proceedings (OSTI)

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377

CB_Ch04.indd  

Science Conference Proceedings (OSTI)

AOCS Press, Urbana, IL 61802 2012 by AOCS Press. All rights reserved. No part of this PDF may be reproduced or transmitted in any form or by any means without written permission of the publisher. To order more AOCS products, please visit our web

378

ARM - Datastreams - nfov2ch  

NLE Websites -- All DOE Office Websites (Extended Search)

Shouxian, Anhui, China PGH M1 Browse Data ARIES Observatory, Nainital, Uttarkhand, India PVC M1 Browse Data Highland Center, Cape Cod MA; AMF 1 PYE M1 Browse Data Point Reyes, CA...

379

CB_Ch07.indd  

Science Conference Proceedings (OSTI)

AOCS Press, Urbana, IL 61802 2012 by AOCS Press. All rights reserved. No part of this PDF may be reproduced or transmitted in any form or by any means without written permission of the publisher. To order more AOCS products, please visit our web

380

CB_Ch08.indd  

Science Conference Proceedings (OSTI)

AOCS Press, Urbana, IL 61802 2012 by AOCS Press. All rights reserved. No part of this PDF may be reproduced or transmitted in any form or by any means without written permission of the publisher. To order more AOCS products, please visit our web

Note: This page contains sample records for the topic "butyl ether ch" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

CB_Ch14.indd  

Science Conference Proceedings (OSTI)

AOCS Press, Urbana, IL 61802 2012 by AOCS Press. All rights reserved. No part of this PDF may be reproduced or transmitted in any form or by any means without written permission of the publisher. To order more AOCS products, please visit our web

382

Ch. 33 Modeling: Computational Thermodynamics  

Science Conference Proceedings (OSTI)

This chapter considers methods and techniques for computational modeling for nuclear materials with a focus on fuels. The basic concepts for chemical thermodynamics are described and various current models for complex crystalline and liquid phases are illustrated. Also included are descriptions of available databases for use in chemical thermodynamic studies and commercial codes for performing complex equilibrium calculations.

Besmann, Theodore M [ORNL

2012-01-01T23:59:59.000Z

383

CB_Ch18.indd  

Science Conference Proceedings (OSTI)

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384

CB_Ch17.indd  

Science Conference Proceedings (OSTI)

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385

CB_Ch19.indd  

Science Conference Proceedings (OSTI)

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386

CB_Ch10.indd  

Science Conference Proceedings (OSTI)

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387

CB_Ch09.indd  

Science Conference Proceedings (OSTI)

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388

CB_Ch02.indd  

Science Conference Proceedings (OSTI)

AOCS Press, Urbana, IL 61802 2012 by AOCS Press. All rights reserved. No part of this PDF may be reproduced or transmitted in any form or by any means without written permission of the publisher. To order more AOCS products, please visit our web

389

CB_Ch01.indd  

Science Conference Proceedings (OSTI)

AOCS Press, Urbana, IL 61802 2012 by AOCS Press. All rights reserved. No part of this PDF may be reproduced or transmitted in any form or by any means without written permission of the publisher. To order more AOCS prod-

390

CB_Ch12.indd  

Science Conference Proceedings (OSTI)

AOCS Press, Urbana, IL 61802 2012 by AOCS Press. All rights reserved. No part of this PDF may be reproduced or transmitted in any form or by any means without written permission of the publisher. To order more AOCS products, please visit our web

391

CB_Ch20.indd  

Science Conference Proceedings (OSTI)

AOCS Press, Urbana, IL 61802 2012 by AOCS Press. All rights reserved. No part of this PDF may be reproduced or transmitted in any form or by any means without written permission of the publisher. To order more AOCS products, please visit our web

392

CB_Ch11.indd  

Science Conference Proceedings (OSTI)

AOCS Press, Urbana, IL 61802 2012 by AOCS Press. All rights reserved. No part of this PDF may be reproduced or transmitted in any form or by any means without written permission of the publisher. To order more AOCS products, please visit our web

393

ch07wrkg.doc  

NLE Websites -- All DOE Office Websites (Extended Search)

5 5 5 Work Breakdown Structure TECHNICAL SYNOPSIS The Work Breakdown Structure (WBS) is used for defining work packages and developing and tracking the cost and schedule for the project. The work is broken down into tasks, each of which has a manager, a responsible institution, costs and schedule, technical scope, and, to the extent possible, a specific geographic piece of the machine. Each level 3 element has a Task Manager who is responsible for the execution of the project plans for that element. The Task Manager is responsible for translating system performance requirements into design choices for the LCLS technical systems. He/she is also responsible for control of cost and schedule, quality and safety, and documentation. Performance requirements for systems at level 3 and below will be established and advocated

394

Quantum cascade laser investigations of CH{sub 4} and C{sub 2}H{sub 2} interconversion in hydrocarbon/H{sub 2} gas mixtures during microwave plasma enhanced chemical vapor deposition of diamond  

Science Conference Proceedings (OSTI)

CH{sub 4} and C{sub 2}H{sub 2} molecules (and their interconversion) in hydrocarbon/rare gas/H{sub 2} gas mixtures in a microwave reactor used for plasma enhanced diamond chemical vapor deposition (CVD) have been investigated by line-of-sight infrared absorption spectroscopy in the wavenumber range of 1276.5-1273.1 cm{sup -1} using a quantum cascade laser spectrometer. Parameters explored include process conditions [pressure, input power, source hydrocarbon, rare gas (Ar or Ne), input gas mixing ratio], height (z) above the substrate, and time (t) after addition of hydrocarbon to a pre-existing Ar/H{sub 2} plasma. The line integrated absorptions so obtained have been converted to species number densities by reference to the companion two-dimensional (r,z) modeling of the CVD reactor described in Mankelevich et al. [J. Appl. Phys. 104, 113304 (2008)]. The gas temperature distribution within the reactor ensures that the measured absorptions are dominated by CH{sub 4} and C{sub 2}H{sub 2} molecules in the cool periphery of the reactor. Nonetheless, the measurements prove to be of enormous value in testing, tensioning, and confirming the model predictions. Under standard process conditions, the study confirms that all hydrocarbon source gases investigated (methane, acetylene, ethane, propyne, propane, and butane) are converted into a mixture dominated by CH{sub 4} and C{sub 2}H{sub 2}. The interconversion between these two species is highly dependent on the local gas temperature and the H atom number density, and thus on position within the reactor. CH{sub 4}->C{sub 2}H{sub 2} conversion occurs most efficiently in an annular shell around the central plasma (characterized by 1400CH{sub 4} is favored in the more distant regions where T{sub gas}C{sub 2}H{sub 2} conversion, whereas the reverse C{sub 2}H{sub 2}->CH{sub 4} process only requires H atoms to drive the reactions; H atoms are not consumed by the overall conversion.

Ma Jie; Cheesman, Andrew; Ashfold, Michael N. R. [School of Chemistry, University of Bristol, Bristol BS8 1TS (United Kingdom); Hay, Kenneth G.; Wright, Stephen; Langford, Nigel; Duxbury, Geoffrey [Department of Physics, University of Strathclyde, John Anderson Building, 107 Rottenrow, Glasgow G4 0NG (United Kingdom); Mankelevich, Yuri A. [Skobel'tsyn Institute of Nuclear Physics, Moscow State University, Leninskie Gory, Moscow 119991 (Russian Federation)

2009-08-01T23:59:59.000Z

395

High Temperature, Low Relative Humidity, Polymer-type Membranes Based on Disulfonated Poly(arylene ether) Block and Random Copolymers Optionally Incorporating Protonic Conducting Layered Water insoluble Zirconium Fillers  

DOE Green Energy (OSTI)

Our research group has been engaged in the past few years in the synthesis of biphenol based partially disulfonated poly(arylene ether sulfone) random copolymers as potential PEMs. This series of polymers are named as BPSH-xx, where BP stands for biphenol, S stands for sulfonated, H stands for acidified and xx represents the degree of disulfonation. All of these sulfonated copolymers phase separate to form nano scale hydrophilic and hydrophobic morphological domains. The hydrophilic phase containing the sulfonic acid moieties causes the copolymer to absorb water. Water confined in hydrophilic pores in concert with the sulfonic acid groups serve the critical function of proton (ion) conduction and water transport in these systems. Both Nafion and BPSH show high proton conductivity at fully hydrated conditions. However proton transport is especially limited at low hydration level for the BPSH random copolymer. It has been observed that the diffusion coefficients of both water and protons change with the water content of the pore. This change in proton and water transport mechanisms with hydration level has been attributed to the solvation of the acid groups and the amount of bound and bulk-like water within a pore. At low hydration levels most of the water is tightly associated with sulfonic groups and has a low diffusion coefficient. This tends to encourage isolated domain morphology. Thus, although there may be significant concentrations of protons, the transport is limited by the discontinuous morphological structure. Hence the challenge lies in how to modify the chemistry of the polymers to obtain significant protonic conductivity at low hydration levels. This may be possible if one can alter the chemical structure to synthesize nanophase separated ion containing block copolymers. Unlike the BPSH copolymers, where the sulfonic acid groups are randomly distributed along the chain, the multiblock copolymers will feature an ordered sequence of hydrophilic and hydrophobic segments. If, like in Nafion, connectivity is established between the hydrophilic domains in these multiblock copolymers, they will not need as much water, and hence will show much better protonic conductivity than the random copolymers (with similar degree of sulfonation, or IEC) at partially hydrated conditions. The goal of this research is to develop a material suitable for use as a polymer electrolyte membrane which by the year 2010 will meet all the performance requirements associated with fuel cell operation at high temperatures and low relative humidity, and will out-perform the present standard Nafion{reg_sign}. In particular, it is our objective to extend our previous research based on the use of thermally, oxidatively, and hydrolytically, ductile, high Tg ion containing polymers based on poly(arylene ethers) to the production of polymer electrolyte membranes which will meet all the performance requirements in addition to having an areal resistance of < 0.05 ohm-cm{sup 2} at a temperature of up to 120 C, relative humidity of 25 to 50%, and up to 2.5 atm total pressure. In many instances, our materials already out performs Nafion{reg_sign}, and it is expected that with some modification by either combining with conductive inorganic fillers and/or synthesizing as a block copolymer it will meet the performance criteria at high temperatures and low relative humidity. A key component in improving the performance of the membranes (and in particular proton conductivity) and meeting the cost requirements of $40/m{sup 2} is our development of a film casting process, which shows promise for generation of void free thin films of uniform thickness with controlled polymer alignment and configuration.

McGrath, James E.; Baird, Donald G.

2010-06-03T23:59:59.000Z

396

Chandra ACIS Survey of M33 (ChASeM33): X-ray Imaging Spectroscopy of M33SNR21, the brightest X-ray Supernova Remnant in M33  

E-Print Network (OSTI)

We present and interpret new X-ray data for M33SNR21, the brightest X-ray supernova remnant (SNR) in M33. The SNR is in seen projection against (and appears to be interacting with) the bright Hii region NGC592. Data for this source were obtained as part of the Chandra ACIS Survey of M33 (ChASeM33) 1

Terrance J. Gaetz; William P. Blair; John P. Hughes; P. Frank Winkler; Knox S. Long; Thomas G; Benjamin Williams; Richard J. Edgar; Parviz Ghavamian; Paul P. Plucinsky; Manami Sasaki; Robert P. Kirshner; Miguel Avillez; Dieter Breitschwerdt

2007-01-01T23:59:59.000Z

397

Polybrominated dibenzo-p-dioxins/dibenzofurans and polybrominated diphenyl ethers in soil, vegetation, workshop-floor dust, and electronic shredder residue from an electronic waste recycling facility and in soils from a chemical industrial complex in eastern China  

SciTech Connect

In this study, 11 2,3,7,8-substituted PBDD/Fs and 10 polybrominated diphenyl ether (PBDE) congeners were determined in electronic shredder waste, workshop-floor dust, soil, and leaves (of plants on the grounds of the facility) from a large-scale electronic wastes (e-waste) recycling facility and in surface soil from a chemical-industrial complex (comprising a coke-oven plant, a coal-fired power plant, and a chlor-alkali plant) as well as agricultural areas in eastern China. Total PBDD/F concentrations in environmental samples were in the range of 113-818 pg/g dry wt (dw) for leaves, 392-18,500 pg/g dw for electronic shredder residues, 716-80,0000 pg/g dw for soil samples, and 89,600-14,3000 pg/g dw for workshop-floor dust from the e-waste recycling facility and in a range from nondetect (ND) to 427 pg/g dw in soil from the chemical-industrial complex. The highest mean concentrations of total PBDD/Fs were found in soil samples and workshop-floor dust from the e-waste recycling facility. The dioxin-like toxic equivalent (measured as TEQ) concentrations of PBDD/Fs were greater than the TEQs of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) reported in our previous study for the same set of samples. The concentrations of PBDFs were several orders of magnitude higher than the concentrations of PBDDs in samples from the e-waste facility or from soil from the chemical-industrial complex. A significant correlation was found between the concentrations of {Sigma}PBDD/Fs and {Sigma}PBDEs (r = 0.769, p < 0.01) and between SPBDD/Fs and the previously reported SPCDD/F concentrations (r = 0.805, p < 0.01). The estimated daily human intakes of TEQs contributed by PBDD/Fs via soil/dust ingestion and dermal exposures in e-waste recycling facilities were higher than the intakes of TEQs contributed by PCDD/Fs, calculated in our previous study. 45 refs., 2 figs., 2 tabs.

Jing Ma; Rudolf Addink; Sehun Yun; Jinping Cheng; Wenhua Wang; Kurunthachalam Kannan [Shanghai Jiao Tong University, Shanghai (China). School of Environmental Science and Engineering

2009-10-01T23:59:59.000Z

398

Development of Supported Polymeric Liquid Membrane Technology for Aqueous MTBE Mitigation  

Science Conference Proceedings (OSTI)

The use of MTBE (methyl tert-butyl ether) as a gasoline additive has generated a serious, widespread groundwater contamination problem in California. This study evaluated the use of supported polymeric liquid membrane technology in the remediation of MTBE contaminated groundwater.

2002-07-02T23:59:59.000Z

399

Motor Gasoline Outlook and State MTBE Bans  

Reports and Publications (EIA)

The U.S. is beginning the summer 2003 driving season with lower gasoline inventories and higher prices than last year. Recovery from this tight gasoline market could be made more difficult by impending State bans on the blending of methyl tertiary butyl ether (MTBE) into gasoline that are scheduled to begin later this year.

Information Center

2003-04-01T23:59:59.000Z

400

Ion Recognition Approach to Volume Reduction of Alkaline Tank ...  

Radiochemical Science and Engineering Group, ... R OH CF3 R = H, CH 3 ... and B. A. Moyer (Unpublished results). O O O O O O 0.05 M crown ether with or without ...

Note: This page contains sample records for the topic "butyl ether ch" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Development of alternative fuels from coal derived syngas. Topical report: Task 2.2, Demonstration of a one-step slurry-phase process for the production of dimethyl ether/methanol mixtures at the LaPorte Alternative Fuels Development Unit  

SciTech Connect

This report documents engineering, modification, and operations efforts of demonstration of dimethyl-ether/methanol coproduction in a slurry-phase reactor, carried out in a 2-ft diameter bubble column reactor. Equipment modifications made it possible to remove the product DME and by-product CO{sub 2} from the reactor effluent. Coproduction of dimethyl-ether (DME) and methanol (MeOH) was accomplished in the slurry reactor by physically mixing two different catalysts. The catalyst used to produce MeOH from syngas was manufactured by BASF (type S3-86); the catalyst used to convert MeOH to DME was Catapal {gamma}-alumina. Ratio of MeOH to DME catalysts determined the selectivity towards DME. The demonstration sought to study effect of cocatalyst ratio on product selectivity. Three different proportions of DME catalyst were examined: 0, 6.6, and 19.3 wt % alumina. At each catalyst proportion, the plant was operated at two different gas space velocities. Some process variables were maintained at fixed conditions; most important variables included: reactor temperature (482F), reactor pressure (750 psig), and reactor feed gas composition (35% H{sub 2}, 51% CO,13% CO{sub 2} 1% other, nominal-molar basis).

1993-06-01T23:59:59.000Z

402

Sealed Gravitational Capillary Viscometry of Dimethyl Ether ...  

Science Conference Proceedings (OSTI)

... Huber, and MO McLinden, NIST Standard Reference Database 23: Reference Fluid Thermodynamic and Transport Properties-REFPROP, Version ...

2012-11-26T23:59:59.000Z

403

Sealed Gravitational Capillary Viscometry of Dimethyl Ether ...  

Science Conference Proceedings (OSTI)

... RF Hafer, Viscosity of Fluorinated Propane Isomers. ... EW Lemmon, An Equation of State for the ... Dense Fluids, Plenum Press, New York and London ...

2013-12-11T23:59:59.000Z

404

Table Definitions, Sources, and Explanatory Notes  

Gasoline and Diesel Fuel Update (EIA)

Ethanol Plant Production Ethanol Plant Production Definitions Key Terms Definition Barrel A unit of volume equal to 42 U.S. gallons. Fuel Ethanol An anhydrous alcohol (ethanol with less than 1% water) intended for gasoline blending as described in the Oxygenates definition. Oxygenates Substances which, when added to gasoline, increase the amount of oxygen in that gasoline blend. Ethanol, Methyl Tertiary Butyl Ether (MTBE), Ethyl Tertiary Butyl Ether (ETBE), and methanol are common oxygenates. Fuel Ethanol: Blends of up to 10 percent by volume anhydrous ethanol (200 proof) (commonly referred to as the "gasohol waiver"). Methanol: Blends of methanol and gasoline-grade tertiary butyl alcohol (GTBA) such that the total oxygen content does not exceed 3.5 percent by weight and the ratio of methanol to GTBA is less than or equal to 1. It is also specified that this blended fuel must meet ASTM volatility specifications (commonly referred to as the "ARCO" waiver).

405

Hydrogen for X-group exchange in CH3X, X = Cl, Br, I, OMe and NMe2 byMonomeric [1,2,4-(Me3C)3C5H2]2CeH: Experimental and Computational Support for a Carbenoid Mechanism  

DOE Green Energy (OSTI)

The reaction between [1,2,4-(Me3C)3C5H2]2CeH, referred to as Cp'2CeH, andCH3X where X is Cl, Br, I, OMe and NMe2, are described. The reactions fall intothree distinct classes. Class a, where X = Cl, Br and I rapidly form Cp'2CeX and CH4without formation of identifiable intermediates in the 1H NMR spectra. Class b, whereX = OMe proceeds rapidly to Cp'2Ce(eta2-CH2OMe) and H2 and then to Cp'2CeOMeand CH4. The methoxymethyl derivative is sufficiently stable to be isolated andcharacterized and it is rapidly converted to Cp'2CeOMe in presence of BPh3. Class c,where X = NMe2 does not result in formation of Cp'2CeNMe2, but deuterium labelingexperiments show that H for D exchange occurs in NMe3. Density functionalcalculations DFT(B3PW91) on the reaction of (C5H5)2CeH, referred to as Cp2CeH,and CH3X show that the barrier for alpha-CH activation, resulting in formation ofCp2Ce(eta2-CH2X), proceeds with a relatively low activation barrier (DeltaG++) but thesubsequent ejection of CH2 and trapping by H2 has a higher barrier; the height of thesecond barrier lies in the order F, Cl, Br, I< OMe<< NMe2, consistent with theexperimental studies. The DFT calculations also show that the two-step reaction,which proceeds through a carbenoid intermediate, has a lower barrier than a directone-step sigma bond metathesis mechanism. The reaction of Cp2CeCH2OMe and BPh3 is calculated to be a low barrier process and the ylide, CH2(+)BPh3(-), is a transition state and not an intermediate.

Werkema, Evan; Andersen, Richard; Yahia, Ahmed; Maron, Laurent; Eisenstein, Odile

2009-05-15T23:59:59.000Z

406

Adsorption and decomposition of Ru{sub 3}(CO){sub 9}(CH{sub 3}CN){sub 3} at platinum surfaces: An X-ray photoelectron spectroscopy and Fourier transform-infrared spectroscopy study  

Science Conference Proceedings (OSTI)

The direct methanol fuel cell (DMFC) is an attractive power source for mobile applications due to the high-energy density of methanol, the portability and ease of distribution of liquid rather than gaseous fuel, and elimination of the need for a bulky, power-consuming fuel reformer. There are several factors limiting the power output of polymer electrolyte DMFCs. One of the major factors is the slow kinetics of the methanol electrooxidation reaction on the conventional platinum catalyst material. A CH{sub 3}CN-modified triruthenium carbonyl cluster, Ru{sub 3}(CO){sub 9}(CH{sub 3}CN){sub 3}(I), has been adsorbed on platinum and platinum oxide surfaces from dichloromethane solutions. The modified surface has been characterized by X-ray photoelectron spectroscopy (XPS) and polarized grazing angle Fourier transform-infrared (FT-IR) microscopy. The proposed mechanism for the adsorption of I involves the chemisorption of the metal cluster at the platinum surface by losing the acetonitrile ligand. The original cluster, Ru{sub 3}(CO){sub 12}, could not be adsorbed under the same experimental conditions used for cluster I. The cluster-modified surface was treated with hydrogen for the reduction of the cluster to its metallic state on the Pt surface. This was done at different temperatures. The XPS results show the formation of a complex Ru-RuO{sub 2}-RuO{sub 3}/Pt surface.

Fachini, E.R.; Cabrera, C.R. [Univ. of Puerto Rico, San Juan (Puerto Rico). Dept. of Chemistry

1999-02-02T23:59:59.000Z

407

H{sub 2}(v = 0,1) + C{sup +}({sup 2} P) {yields} H+CH{sup +} STATE-TO-STATE RATE CONSTANTS FOR CHEMICAL PUMPING MODELS IN ASTROPHYSICAL MEDIA  

SciTech Connect

State-to-state rate constants for the title reaction are calculated using the electronic ground state potential energy surface and an accurate quantum wave-packet method. The calculations are performed for H{sub 2} in different rovibrational states, v = 0, 1 and J = 0 and 1. The simulated reaction cross section for v = 0 shows a rather good agreement with the experimental results of Gerlich et al., both with a threshold of 0.36 eV and within the experimental error of 20%. The total reaction rate coefficients simulated for v = 1 are two times smaller than those estimated by Hierl et al. from cross sections measured at different temperatures and neglecting the contribution from v > 1 with an uncertainty factor of two. Thus, part of the disagreement is attributed to the contributions of v > 1. The computed state-to-state rate coefficients are used in our radiative transfer model code applied to the conditions of the Orion Bar photodissociation region, and leads to an increase of the line fluxes of high-J lines of CH{sup +}. This result partially explains the discrepancies previously found with measurements and demonstrates that CH{sup +} excitation is mostly driven by chemical pumping.

Zanchet, Alexandre; Bulut, Niyazi; Roncero, Octavio [Instituto de Fisica Fundamental (IFF-CSIC), C.S.I.C., Serrano 123, E-28006 Madrid (Spain)] [Instituto de Fisica Fundamental (IFF-CSIC), C.S.I.C., Serrano 123, E-28006 Madrid (Spain); Godard, B.; Cernicharo, Jose [Centro de Astrobilogia, CSIC-INTA, Torrejon de Ardoz, Madrid (Spain)] [Centro de Astrobilogia, CSIC-INTA, Torrejon de Ardoz, Madrid (Spain); Halvick, Philippe, E-mail: octavio.roncero@csic.es [Institut des Sciences Moleculaires, Universite de Bordeaux, CNRS UMR 5255, 351 cours de la Liberation, F-33405 Talence Cedex (France)] [Institut des Sciences Moleculaires, Universite de Bordeaux, CNRS UMR 5255, 351 cours de la Liberation, F-33405 Talence Cedex (France)

2013-04-01T23:59:59.000Z

408

Comparison of Cobalt and Nickel Complexes with Sterically Demanding Cyclic Diphosphine Ligands: Electrocatalytic H2 Production by [Co(PtBu2NPh2)(CH3CN)3](BF4)2  

DOE Green Energy (OSTI)

The cyclic diphosphine ligands PtBu2NPh2 and PtBu2NBz2 have been synthesized and used to prepare new complexes of Co(II) and Ni(II) with the formula [M(PtBu2NR2)(CH3CN)n](BF4)2 (n = 2, 3). The products have been characterized by variable temperature NMR data, X-ray diffraction studies, and cyclic voltammetry, and properties of the new complexes have been compared with previously studied complexes containing PPh2NR2 ligands. The variation of either phosphorus or nitrogen substituents in these ligands can result in significant differences in the structure, electrochemistry and reactivity of the metal complexes. [Co(PtBu2NPh2)(CH3CN)3](BF4)2 is found to be an effective electrocatalyst for the formation of hydrogen using bromoanilinium tetrafluoroborate as the acid, with a turnover frequency of 62 s-1 and an overpotential of 160 mV, and these cobalt derivatives are a promising class of catalysts for further study and optimization. This work was supported by the US Department of Energy Basic Energy Sciences' Chemical Sciences, Geosciences & Biosciences Division. Pacific Northwest National Laboratory is operated by Battelle for the US Department of Energy. This material is based upon work supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the US Department of Energy, Office of Science, Office of Basic Energy Sciences.

Wiedner, Eric S.; Yang, Jenny Y.; Dougherty, William G.; Kassel, W. S.; Bullock, R. Morris; Rakowski DuBois, Mary; DuBois, Daniel L.

2010-11-08T23:59:59.000Z

409

Fabrication of ZnO photonic crystals by nanosphere lithography using inductively coupled-plasma reactive ion etching with CH{sub 4}/H{sub 2}/Ar plasma on the ZnO/GaN heterojunction light emitting diodes  

SciTech Connect

This article reports fabrication of n-ZnO photonic crystal/p-GaN light emitting diode (LED) by nanosphere lithography to further booster the light efficiency. In this article, the fabrication of ZnO photonic crystals is carried out by nanosphere lithography using inductively coupled plasma reactive ion etching with CH{sub 4}/H{sub 2}/Ar plasma on the n-ZnO/p-GaN heterojunction LEDs. The CH{sub 4}/H{sub 2}/Ar mixed gas gives high etching rate of n-ZnO film, which yields a better surface morphology and results less plasma-induced damages of the n-ZnO film. Optimal ZnO lattice parameters of 200 nm and air fill factor from 0.35 to 0.65 were obtained from fitting the spectrum of n-ZnO/p-GaN LED using a MATLAB code. In this article, we will show our recent result that a ZnO photonic crystal cylinder has been fabricated using polystyrene nanosphere mask with lattice parameter of 200 nm and radius of hole around 70 nm. Surface morphology of ZnO photonic crystal was examined by scanning electron microscope.

Chen, Shr-Jia; Chang, Chun-Ming; Kao, Jiann-Shiun; Chen, Fu-Rong; Tsai, Chuen-Horng [Engineering and System Science, National Tsing Hua University, Hsinchu, 30013 Taiwan (China); Instrument Technology Research Center, National Applied Research Laboratories, Hsinchu, 300 Taiwan (China); Engineering and System Science, National Tsing Hua University, Hsinchu, 30013 Taiwan (China)

2010-07-15T23:59:59.000Z

410

Exam 1, Chemistry 210, Dr. Rainer Glaser, W97, MU --1 --Chemistry 210Chemistry 210  

E-Print Network (OSTI)

,4-dimethyl-octane (4 points) 7-tert.-butyl-4-iso.-propyl-3,5-decadiene (3 pts) H O butanal (3 pts) O ethylmethylketone Condensed structural formula of n-butane. (2 pts) H3C-CH2-CH2-CH3 Bond line structure of butane. (2 pts) Newman projection of gauche butane along the central C2-C3 bond. (4 pts) H H Me Me H H

Glaser, Rainer

411

Spectroscopic determination of C{sub 2} in Ar/H{sub 2}/CH{sub 4} and Ar/H{sub 2}/C{sub 60} microwave plasmas for nanocrystalline diamond synthesis.  

DOE Green Energy (OSTI)

We have measured the steady state concentration of gas phase C{sub 2} in Ar/H{sub 2}/CH{sub 4} and Ar/H{sub 2}/C{sub 60} microwave plasmas used for the deposition of nanocrystalline diamond films. High sensitivity white light absorption spectroscopy is used to monitor the C{sub 2} density using the d{sup 3}II {l_arrow} A{sup 3}II (0,0) vibrational band of C{sub 2} as chamber pressure, microwave power, substrate temperature and feed gas mixtures are varied in both chemistries. Understanding how these parameters influence the C{sub 2} density in the plasma volume provides insight into discharge mechanisms relevant to the deposition of nanocrystalline diamond.

Goyette, A. N.; Lawler, J. E.; Anderson, L. W.; Gruen, D. M.; McCauley, T. G.; Zhou, D.; Krauss, A. R.

1998-02-05T23:59:59.000Z

412

Optical Properties of {beta}''-(ET){sub 2}SF{sub 5}CH{sub 2}CF{sub 2}SO{sub 3} : a novel superconductor with large discrete counterions.''  

DOE Green Energy (OSTI)

The optical spectra of the organic superconductor {beta}{double_prime}-(ET){sub 2}SF{sub 5}CH{sub 2}CF{sub 2}SO{sub 3} are measured over a wide spectral range (30-35000 cm{sup {minus}1}) as a function of temperature and polarization. The optical anisotropy is quite large compared with other ET-based organic superconductors, and the spectra are far from Drude-like over the full temperature range. A broad electronic band centered near 1000 cm{sup {minus}1} is observed at low temperature along the a axis, prior to the superconducting transition. The changes of vibrational features near 120 K are attributed to a weak reorientation of the counterion, which may affect hydrogen bonding in the material.

Dong, J.

1998-08-06T23:59:59.000Z

413

In-plane ESR microwave conductivity measurements and electronic band structure studies of the organic superconductor, {beta}'-(BEDT-TTF){sub 2}SF{sub 5}CH{sub 2}CF{sub 2}SO{sub 3}.  

SciTech Connect

The electronic structure of the organic superconductor {beta}''-(BEDT-TTF){sub 2}SF{sub 5}CH{sub 2}CF{sub 2}SO{sub 3} (BEDT-TTF is bis(ethylenedithio)tetrathiafulvalene) was characterized with the use of electron spin resonance (ESR) spectroscopy and electronic band structure calculations. The room-temperature ESR line width is 24-27 G in the plane of a donor molecule layer (i.e., in the ab-plane) and {approx}32 G along the normal to this plane (i.e., along the c*-direction). The ab-plane anisotropy of the microwave conductivity was extracted for the first time from the ESR Dysonian line shape analysis. The in-plane conductivity varies sinusoidally, is maximal along the interstack direction (b-axis), and is minimal along the donor stack direction (a-axis). The Fermi surfaces of the title compound consist of a 2D hole pocket and a pair of 1D wavy lines. The directions for the in-plane conductivity maximum and minimum are in excellent agreement with the electronic band structure calculated for {beta}''-(BEDT-TTF){sub 2}SF{sub 5}CH{sub 2}CF{sub 2}SO{sub 3}, and the origin of the in-plane conductivity anisotropy lies in the one-dimensional part of the Fermi surface. This is the first time that an organic conductor shows Dysonian ESR line shape due to its 2D and strongly metallic nature, yet the 1D character is revealed simultaneously through the in-plane conductivity anisotropy.

Wang, H. H.; VanZile, M. L.; Schlueter, J. A.; Geiser, U.; Kini, A. M.; Sche, P. P.; Koo, H.-J.; Whangbo, M.-H.; Nixon, P. G.; Winter, R. W.; Gard, G. L.; Chemistry; North Carolina State Univ.; Portland State Univ.

1999-07-01T23:59:59.000Z

414

Optical studies of the {beta}{double_prime}-(ET){sub 2}SF{sub 5}RSO{sub 3} R = CH{sub 2}CF{sub 2}, CHFCF{sub 2} and CHF system: Chemical tuning of the counterion  

SciTech Connect

The authors compare the polarized optical spectra of the organic metal {beta}{double_prime}-(ET){sub 2}SF{sub 5}CHFSO{sub 3} and the {beta}{double_prime}-ET{sub 2}SF{sub 5}CHFCF{sub 2}SO{sub 3} metal/insulator material with those of the first fully organic superconductor {beta}{double_prime}-ET{sub 2}SF{sub 5}CH{sub 2}SO{sub 3}. The small chemical modification of the counterion has a dramatic effect on the spectral and charge transport properties of these materials, and they discuss their electronic structure in terms of band structure, many-body effects, and disorder. Based on structural differences in the anion pocket of the three salts, they conclude that the unusual electronic excitations observed in the {beta}{double_prime}-(ET){sub 2}SF{sub 5}CHFCF{sub 2}SO{sub 3} metal/insulator material are caused by disorder-related localization.

Olejniczak, I.; Jones, B. R.; Dong, J.; Pigos, J. M.; Zhu, Z.; Garlach, A. D.; Musfeldt, J. L.; Koo, H.-J.; Whangbo, M.-H.; Schlueter, J. A.; Ward, B. H.; Morales, E.; Kini, A. M.; Winter, R. W.; Mohtasham, J.; Gard, G. L.

2000-07-24T23:59:59.000Z

415

Energetics of Adsorbed CH3 and CH on Pt(111) by Calorimetry: Dissociative Adsorption of CH3I  

E-Print Network (OSTI)

oxidation of methane, steam reforming, combustion and selective oxidations of methane and various other of formation, the enthalpy for the dissociation of adsorbed methane to adsorbed methyl coadsorbed + 2 Had was found to be uphill by between +4 and +23 kJ/mol. Measured methane yields (which require

Campbell, Charles T.

416

CH Last Name CH First Name CH Center Office name Alexander Tina (HQ) International and Interagency Relations  

E-Print Network (OSTI)

Director Bob Barto Sr. Inspector Doug McGinnis Sr. Inspector George Levinthal Project Manager Jeff Enge Sr. Inspector Mark Peppers Project Manager Peter Ryan Sr. Inspector Rick Whitehead Sr. Inspector Tom Haas Sr. Inspector Ray Aronson Associate Director Daniel Belding Project Manager Anne-Marie Nething Analyst 1 Dan

Christian, Eric

417

Microsoft Word - Final CSERD Ch 6.doc  

NLE Websites -- All DOE Office Websites (Extended Search)

AUGUST 2007 6-1 AUGUST 2007 6-1 6.0 REFERENCES CHAPTER 1 BACKGROUND Brown, P. 2004. Climate Fear as CO 2 Soars. The Guardian Unlimited, Guardian Newspapers Limited. Manchester, England. http://www.guardian.co.uk/guardianweekly/story/0,,1327452,00.html. October 15, 2004. Carbon Mitigation Initiative (CMI). 2007. CMI in Brief: Building the Stabilization Triangle. http://www.princeton.edu/pr/news/04/q3/0812-carbon/backgrounder.pdf. Email from Roberta Hotinski on August 1, 2007. Energy Information Administration (EIA). 2005. Annual Energy Outlook 2005 with Projections to 2025 (Early Release). U.S. Department of Energy. Report # DOE/EIS-0383(2005). January 2005. Energy Information Administration (EIA). 2004. Emissions of Greenhouse Gases in the United States

418

Microsoft Word - Final CSERD Ch 3.doc  

NLE Websites -- All DOE Office Websites (Extended Search)

AUGUST 2007 3-1 AUGUST 2007 3-1 3.0 ENVIRONMENTAL BASELINE INFORMATION 3.1 INTRODUCTION This chapter provides environmental baseline information for different regions and individual states within the U.S. that could potentially host carbon sequestration projects. The following aspects will be discussed in this chapter: atmospheric resources, geologic resources, surface water resources, biological resources, cultural resources, aesthetic and scenic resources, land use, materials and waste management, health and safety, socioeconomics and infrastructure. 3.2 ATMOSPHERIC RESOURCES The following section describes baseline air quality with respect to the states within the Regional Partnerships and U.S. climate. 3.2.1 National Context Atmosphere is defined as the mixture of gases surrounding any celestial object that has a gravitational

419

Microsoft Word - Final CSERD Ch 5.doc  

NLE Websites -- All DOE Office Websites (Extended Search)

5-1 5-1 5.0 SUBJECT INDEX A Acid Mine Drainage, 4-35 Advisory Council on Historic Preservation, 4-60, 4-61, 4-64 Allison Unit, 2-53, 2-54, 2-58, 3-55, 3-56 American Indian Religious Freedom Act (AIRFA), 3-87, 4-60, 4-63 Archeological Resources Protection Act of 1979, 3-87, 4-60, 4-62, 4-63, 4-65 B Basalt Formations, 2-1, 2-9, 2-26, 2-77, 2-78, 2-80, 3-31, 4-9, 4-21, 4-34, 4-35, 4-48, 4-68, 4-69, 4-76, 4- 79, 4-86, 4-90, 4-98, 4-110, 4-120, 4-127 Best Available Control Technology, 4-7, 4-8, 4-9, 4-13, 4-14 Best Management Practices, 3-32, 4-1, 4-2, 4-13, 4-16, 4-17, 4-18, 4-19, 4-20, 4-21, 4-22, 4-23, 4-25, 4- 26, 4-27, 4-32, 4-33, 4-34, 4-35, 4-36, 4-41, 4-42, 4-48, 4-49, 4-51, 4-52, 4-57, 4-76, 4-88, 4-89, 4-122, 4- 123 Big Horn, 3-57 Black Warrior Basin, 3-57

420

Microsoft Word - Final CSERD Ch 7.doc  

NLE Websites -- All DOE Office Websites (Extended Search)

7-1 7-1 7.0 GLOSSARY AND ACRONYMS ACRONYM OR TERM DEFINITION µg/m 3 microgram per cubic meter µg/mL microgram per milliliter 132 Xe Xenon 132 1-hour average ozone concentrations the EPA air quality standard for ozone is 0.12 part per million for a 1-hour average 20 Ne Neon 20 36 Ar Argon 36 84 Kr Krypton 84 8-hour average ozone concentrations the EPA air quality standard for ozone, designed to protect public health with an adequate margin of safety, is 0.085 parts per million (ppm), averaged over 8 hours ac acres ACHP Advisory Council on Historic Preservation AEP American Electric Power afforestation the conversion of bare or cultivated land into forest AGR acid gas removal AHPA Archeological and Historic Preservation Act AIH American Institute of Hydrology

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421

Microsoft Word - Ch1_PN_040611km  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Bandon-Rogue Transmission Line Bandon-Rogue Transmission Line Rebuild Project Finding of No Significant Impact May 2011 This page left intentionally blank. Bonneville Power Administration 1 Bandon-Rogue Transmission Line Rebuild Project DEPARTMENT OF ENERGY Bonneville Power Administration Finding of No Significant Impact (FONSI) and Floodplain Statement of Findings DOE EA-1739 Summary: Bonneville Power Administration (BPA) announces its environmental findings on the Bandon-Rogue Transmission Line Rebuild Project (Rebuild Project or Proposed Action). The Rebuild Project involves rebuilding the existing Bandon-Rogue 115-kilovolt (kV) transmission line. The 46-mile-long transmission line is located in Coos and Curry counties in Oregon, extending from the city of Bandon to near Nesika Beach.

422

CH-ANL Report.indd  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Awareness Annual Refresher Briefi ng and the computerized Annual Security and Counterintelligence Refresher Briefi ng, respectively. The briefing material concerning...

423

Microsoft Word - Final CSERD Ch 4.doc  

NLE Websites -- All DOE Office Websites (Extended Search)

mitigation may be the replacement of wetlands in another suitable location. Most of the waste materials generated by this facility would be disposed of offsite in licensed...

424

Activating unreactive C-H bonds  

SciTech Connect

The procedures tested to attempt to reactivate carbon-hydrogen bonds in completely saturated organic compounds are discussed. Saturated hydrocarbons appear in petroleum, coal, in synthetic fuels produced by liquefaction of coal and other fossil fuels, and in synthetic fuels produced by Fisher-Tropsch chemistry from syngas. Their potential use as feedstocks for the chemical industry requires that the hydrocarbons be functionalized. The use of transition-metal complexes for the 'activation' process is discussed.

Maugh, T.H. II

1983-06-17T23:59:59.000Z

425

Ch. 37, Inertial Fusion Energy Technology  

DOE Green Energy (OSTI)

Nuclear fission, nuclear fusion, and renewable energy (including biofuels) are the only energy sources capable of satisfying the Earth's need for power for the next century and beyond without the negative environmental impacts of fossil fuels. Substantially increasing the use of nuclear fission and renewable energy now could help reduce dependency on fossil fuels, but nuclear fusion has the potential of becoming the ultimate base-load energy source. Fusion is an attractive fuel source because it is virtually inexhaustible, widely available, and lacks proliferation concerns. It also has a greatly reduced waste impact, and no danger of runaway reactions or meltdowns. The substantial environmental, commercial, and security benefits of fusion continue to motivate the research needed to make fusion power a reality. Replicating the fusion reactions that power the sun and stars to meet Earth's energy needs has been a long-sought scientific and engineering challenge. In fact, this technological challenge is arguably the most difficult ever undertaken. Even after roughly 60 years of worldwide research, much more remains to be learned. the magnitude of the task has caused some to declare that fusion is 20 years away, and always will be. This glib criticism ignores the enormous progress that has occurred during those decades, progress inboth scientific understanding and essential technologies that has enabled experiments producing significant amounts of fusion energy. For example, more than 15 megawatts of fusion power was produced in a pulse of about half a second. Practical fusion power plants will need to produce higher powers averaged over much longer periods of time. In addition, the most efficient experiments to date have required using about 50% more energy than the resulting fusion reaction generated. That is, there was no net energy gain, which is essential if fusion energy is to be a viable source of electricity. The simplest fusion fuels, the heavy isotopes of hydrogen (deuterium and tritium), are derived from water and the metal lithium, a relatively abundant resource. The fuels are virtually inexhaustible and they are available worldwide. Deuterium from one gallon of seawater would provide the equivalent energy of 300 gallons of gasoline, or over a half ton of coal. This energy is released when deuterium and tritium nuclei are fused together to form a helium nucleus and a neutron. The neutron is used to breed tritium from lithium. The energy released is carried by the helium nucleus (3.5 MeV) and the neutron (14 MeV). The energetic helium nucleus heats the fuel, helping to sustain the fusion reaction. Once the helium cools, it is collected and becomes a useful byproduct. A fusion power plant would produce no climate-changing gases.

Moses, E

2010-06-09T23:59:59.000Z

426

Synthesis of octane enhancers during slurry-phase Fischer-Tropsch. Quarterly technical progress report No. 5, October 1, 1991--December 31, 1991  

DOE Green Energy (OSTI)

The objective of this project is to investigate three possible routes to the formation of ethers, in particular methyl tert-butyl ether (MTBE), during slurry phase Fischer-Tropsch reaction. The three reaction schemes to be investigated are: Addition of isobutylene during the formation of methanol and/or higher alcohols directly from CO and H{sub 2} during slurry-phase Fischer-Tropsch. Addition of isobutylene to FT liquid products including alcohols in a slurry-phase reactor containing an MTBE or other acid catalyst. Addition of methanol to slurry phase FT synthesis making iso-olefins.

Marcelin, G.

1992-06-10T23:59:59.000Z

427

Synthesis of octane enhancers during slurry-phase Fischer-Tropsch  

DOE Green Energy (OSTI)

The objective of this project is to investigate three possible routes to the formation of ethers, in particular methyl tert-butyl ether (MTBE), during slurry phase Fischer-Tropsch reaction. The three reaction schemes to be investigated are: Addition of isobutylene during the formation of methanol and/or higher alcohols directly from CO and H{sub 2} during slurry-phase Fischer-Tropsch. Addition of isobutylene to FT liquid products including alcohols in a slurry-phase reactor containing an MTBE or other acid catalyst. Addition of methanol to slurry phase FT synthesis making iso-olefins.

Marcelin, G.

1992-06-10T23:59:59.000Z

428

Adipose tissue stearoyl-CoA desaturase 1 index is increased and linoleic acid is decreased in obesity-prone rats fed a high-fat diet  

E-Print Network (OSTI)

in the adipose tissue and whether these changes occur simul- taneously across lipid fractions. It has previously been found that a HFD, especially a diet rich in SFA, decreases SCD expression in both rat liver and adipose tissue [33,34]. A HFD has also been shown... of petroleum ether containing 0.005% butylated hydroxytolvene after addition of 1.5 ml distilled water. The phases were separated after thorough mixing and centrifugation at 1500 g for 10 min. The petroleum ether phase was pipetted off and the solvent...

Cedernaes, Jonathan; Alsi, Johan; Vstermark, ke; Risrus, Ulf; Schith, Helgi B

2013-01-08T23:59:59.000Z

429

Assessing methane oxidation under landfill covers and its contribution to the above atmospheric CO{sub 2} levels: The added value of the isotope ({delta}{sup 13}C and {delta}{sup 18}O CO{sub 2}; {delta}{sup 13}C and {delta}D CH{sub 4}) approach  

Science Conference Proceedings (OSTI)

Highlights: Black-Right-Pointing-Pointer Comparison of the isotope and mass balance approaches to evaluate the level of methane oxidation within a landfill. Black-Right-Pointing-Pointer The level of methane oxidation is not homogenous under the landfill cover and is strongly correlated to the methane flux. Black-Right-Pointing-Pointer Isotope tracking of the contribution of the methane oxidation to the CO{sub 2} concentrations in the ambient air. - Abstract: We are presenting here a multi-isotope approach ({delta}{sup 13}C and {delta}{sup 18}O of CO{sub 2}; {delta}{sup 13}C and {delta}D of CH{sub 4}) to assess (i) the level(s) of methane oxidation during waste biodegradation and its migration through a landfill cover in Sonzay (France), and (ii) its contribution to the atmospheric CO{sub 2} levels above the surface. The isotope approach is compared to the more conventional mass balance approach. Results from the two techniques are comparable and show that the CH{sub 4} oxidation under the landfill cover is heterogenous, with low oxidation percentages in samples showing high biogas fluxes, which was expected in clay covers presenting fissures, through which CH{sub 4} is rapidly transported. At shallow depth, more immobile biogas pockets show a higher level of CH{sub 4} oxidation by the methanotrophic bacteria. {delta}{sup 13}C of CO{sub 2} samples taken at different heights (from below the cover up to 8 m above the ground level) were also used to identify and assess the relative contributions of its main sources both under the landfill cover and in the surrounding atmosphere.

Widory, D., E-mail: d.widory@brgm.fr [BRGM, 3 ave Claude Guillemin, 45000 Orleans (France); Proust, E.; Bellenfant, G. [BRGM, 3 ave Claude Guillemin, 45000 Orleans (France); Bour, O. [INERIS, Parc Technologique ALATA, 60550 Verneuil-en-Halatte (France)

2012-09-15T23:59:59.000Z

430

New concept for coal wettability evaluation and modulation. Technical progress report, October 1, 1993--December 31, 1993  

SciTech Connect

This project is concerned concept for coal surface wettability evaluation and modulation. The objective of the work are to study the fundamental surface chemistry feature about the evaluation of the surface of coal, pyrite and coal pyrite, and also establish a new separation strategy which could contribute to the advanced coal cleaning for premium fuel application. In this quarter, the capillary rise of three coals, colorado mineral pyrite, and coal pyrite in butanol, pentanol, and butyl ether have been tested. The test results shown that the kinetic wettability of the five samples in the alcohol homolog are dependent on the carbon chain length, as the length of the carbon chain is shorter, the surface wettability is the better. Another test results shown that the kinetic wettability of coals are better than mineral pyrite and coal pyrite in the butyl ether.

Hu, Weibai

1993-12-31T23:59:59.000Z

431

Two US markets, or one? How the MTBE-gasoline relationship is evolving  

SciTech Connect

This issue of Energy Detente features the price sensitivity of Methyl Tertiary Butyl Ether. Data is presented for US wholesale gasoline prices vs. MTBE for the 20-month period beginning in June 1994 and ending in January 1996, and the data is discussed. Also contained in this issue is the refining netback data and the fuel price/tax data for the period ending January 5, 1996.

1996-01-26T23:59:59.000Z

432

An approach to catalytic asymmetric electrocyclization  

E-Print Network (OSTI)

petroleum ether 40-60 Ph phenyl ppm parts per million Pr propyl q quartet Rf retention factor rt room temperature s singlet sept septet t triplet t tertiary TBAF tetrabutylammonium fluoride TBS tert... demonstrated by Nelson.73 In this case, we observed the formation of lactone 75 by vinyl nucleophile addition to the corresponding aldehydes 71 and 72. We require a less basic source of vinyl anion, or a bulkier ester such as tert-butyl, to prevent any...

Kothari, Abhishek

2010-02-09T23:59:59.000Z

433

Update of Summer Reformulated Gasoline Supply Assessment for New York and Connecticut  

Reports and Publications (EIA)

In October 2003, EIA published a review of the status of the methyl tertiary butyl ether (MTBE) ban transition in New York (NY) and Connecticut (CT) that noted significant uncertainties in gasoline supply for those States for the summer of 2004. To obtain updated information, EIA spoke to major suppliers to the two States over the past several months as the petroleum industry began the switch from winter- to summer-grade gasoline.

Information Center

2004-05-01T23:59:59.000Z

434

Chandra ACIS Survey of M33 (ChASeM33): X-ray Imaging Spectroscopy of M33SNR21, the Brightest X-ray Supernova Remnant in M33  

E-Print Network (OSTI)

We present and interpret new X-ray data for M33SNR21, the brightest X-ray supernova remnant (SNR) in M33. The SNR is in seen projection against (and appears to be interacting with) the bright HII region NGC592. Data for this source were obtained as part of the Chandra ACIS Survey of M33 (ChASeM33) Very Large Project. The nearly on-axis Chandra data resolve the SNR into a ~5" diameter (20 pc at our assumed M33 distance of 817+/-58 kpc) slightly elliptical shell. The shell is brighter in the east, which suggests that it is encountering higher density material in that direction. The optical emission is coextensive with the X-ray shell in the north, but extends well beyond the X-ray rim in the southwest. Modeling the X-ray spectrum with an absorbed sedov model yields a shock temperature of 0.46(+0.01,-0.02) keV, an ionization timescale of n_e t = $2.1 (+0.2,-0.3) \\times 10^{12}$ cm$^{-3}$ s, and half-solar abundances (0.45 (+0.12, -0.09)). Assuming Sedov dynamics gives an average preshock H density of 1.7 +/- 0.3 cm$^{-3}$. The dynamical age estimate is 6500 +/- 600 yr, while the best fit $n_e t$ value and derived $n_e$ gives 8200 +/- 1700 yr; the weighted mean of the age estimates is 7600 +/- 600 yr. We estimate an X-ray luminosity (0.25-4.5 keV) of (1.2 +/- 0.2) times $10^{37}$ ergs s$^{-1}$ (absorbed), and (1.7 +/- 0.3) times $10^{37}$ ergs s$^{-1}$ (unabsorbed), in good agreement with the recent XMM-Newton determination. No significant excess hard emission was detected; the luminosity $\\le 1.2\\times 10^{35}$ ergs s$^{-1}$ (2-8 keV) for any hard point source.

Terrance J. Gaetz; William P. Blair; John P. Hughes; P. Frank Winkler; Knox S. Long; Thomas G. Pannuti; Benjamin Williams; Richard J. Edgar; Parviz Ghavamian; Paul P. Plucinsky; Manami Sasaki; Robert P. Kirshner; Miguel Avillez; Dieter Breitschwerdt

2007-06-18T23:59:59.000Z

435

Weekly Petroleum Status Report  

U.S. Energy Information Administration (EIA) Indexed Site

5 5 Alcohol. The family name of a group of organic chemical compounds composed of carbon, hydrogen, and oxygen. The series of molecules vary in chain length and are composed of a hydrocarbon plus a hydroxyl group; CH3-(CH2)n-OH (e.g., methanol, ethanol, and tertiary butyl alcohol). Alkylate. The product of an alkylation reaction. It usually refers to the high octane product from alkylation units. This alkylate is used in

436

Self-induced unstable behaviors of CH4 and H2/CH4 flames in a...  

NLE Websites -- All DOE Office Websites (Extended Search)

Portillo, David Littlejohn, Scott M. Martin, and Robert K. Cheng Journal Combustion and Flame Volume 160 Issue 2 Pagination 307 - 321 Date Published 022013 ISSN 00102180 DOI...

437

BARTLT SUBROUTINE BARTLT (VAR,DF,N,CH2,CH2CDF ...  

Science Conference Proceedings (OSTI)

... EPS,IFLAG,CDFY) CDFX = 0.5*(1.0+SIGN(CDFY,X)) RETURN C END *CENSCL SUBROUTINE CENSCL (X,W,N1,N2,IOPT,ITER,P1TAIL,CENTER ...

2012-07-27T23:59:59.000Z

438

Plasma-enhanced and thermal atomic layer deposition of Al{sub 2}O{sub 3} using dimethylaluminum isopropoxide, [Al(CH{sub 3}){sub 2}({mu}-O{sup i}Pr)]{sub 2}, as an alternative aluminum precursor  

Science Conference Proceedings (OSTI)

The authors have been investigating the use of [Al(CH{sub 3}){sub 2}({mu}-O{sup i}Pr)]{sub 2} (DMAI) as an alternative Al precursor to [Al(CH{sub 3}){sub 3}] (TMA) for remote plasma-enhanced and thermal ALD over wide temperature ranges of 25-400 and 100-400 deg. C, respectively. The growth per cycle (GPC) obtained using in situ spectroscopic ellipsometry for plasma-enhanced ALD was 0.7-0.9 A/cycle, generally lower than the >0.9 A/cycle afforded by TMA. In contrast, the thermal process gave a higher GPC than TMA above 250 deg. C, but below this temperature, the GPC decreased rapidly with decreasing temperature. Quadrupole mass spectrometry data confirmed that both CH{sub 4} and HO{sup i}Pr were formed during the DMAI dose for both the plasma-enhanced and thermal processes. CH{sub 4} and HO{sup i}Pr were also formed during the H{sub 2}O dose but combustion-like products (CO{sub 2} and H{sub 2}O) were observed during the O{sub 2} plasma dose. Rutherford backscattering spectrometry showed that, for temperatures >100 deg. C and >200 deg. C for plasma-enhanced and thermal ALD, respectively, films from DMAI had an O/Al ratio of 1.5-1.6, a H content of {approx}5 at. % and mass densities of 2.7-3.0 g cm{sup -3}. The film compositions afforded from DMAI were comparable to those from TMA at deposition temperatures {>=}150 deg. C At lower temperatures, there were differences in O, H, and C incorporation. 30 nm thick Al{sub 2}O{sub 3} films from the plasma-enhanced ALD of DMAI were found to passivate n- and p-type Si floatzone wafers ({approx}3.5 and {approx}2 {Omega} cm, respectively) with effective carrier lifetimes comparable to those obtained using TMA. Surface recombination velocities of < 3 and < 6 cm s{sup -1} were obtained for the n- and p-type Si, respectively. Using these results, the film properties obtained using DMAI and TMA are compared and the mechanisms for the plasma-enhanced and thermal ALD using DMAI are discussed.

Potts, Stephen E.; Dingemans, Gijs; Lachaud, Christophe; Kessels, W. M. M. [Department of Applied Physics, Eindhoven University of Technology, P. O. Box 513, 5600 MB Eindhoven (Netherlands); Air Liquide Research and Development, 1 Chemin de la Porte des Loges, BP 126, 78345 Jouy-en-Josas (France); Department of Applied Physics, Eindhoven University of Technology, P. O. Box 513, 5600 MB Eindhoven (Netherlands)

2012-03-15T23:59:59.000Z

439

Extractant composition including crown ether and calixarene extractants  

SciTech Connect

An extractant composition comprising a mixed extractant solvent consisting of calix[4] arene-bis-(tert-octylbenzo)-crown-6 ("BOBCalixC6"), 4',4',(5')-di-(t-butyldicyclo-hexano)-18-crown-6 ("DtBu18C6"), and at least one modifier dissolved in a diluent. The DtBu18C6 may be present at from approximately 0.01M to approximately 0.4M, such as at from approximately 0.086 M to approximately 0.108 M. The modifier may be 1-(2,2,3,3-tetrafluoropropoxy)-3-(4-sec-butylphenoxy)-2-propanol ("Cs-7SB") and may be present at from approximately 0.01M to approximately 0.8M. In one embodiment, the mixed extractant solvent includes approximately 0.15M DtBu18C6, approximately 0.007M BOBCalixC6, and approximately 0.75M Cs-7SB modifier dissolved in an isoparaffinic hydrocarbon diluent. The extractant composition further comprises an aqueous phase. The mixed extractant solvent may be used to remove cesium and strontium from the aqueous phase.

Meikrantz, David H. (Idaho Falls, ID); Todd, Terry A. (Aberdeen, ID); Riddle, Catherine L. (Idaho Falls, ID); Law, Jack D. (Pocalello, ID); Peterman, Dean R. (Idaho Falls, ID); Mincher, Bruce J. (Idaho Falls, ID); McGrath, Christopher A. (Blackfoot, ID); Baker, John D. (Blackfoot, ID)

2009-04-28T23:59:59.000Z

440

CHEMICAL COMPOSITION OF THE ESSENTIAL OIL AND ETHER ...  

Science Conference Proceedings (OSTI)

essential oil from R. rugosum was investigated for further development and application. The chemical and class composition of the oils are presented in Table 1.

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441

Direct Dimethyl Ether Polymer Electrolyte Fuel Cells for Portable Applications  

E-Print Network (OSTI)

. Kosek, C. Cropley, and A. LaConti, in Proceedings of the 32nd Intersociety Energy Conversion Engineering

442

ESR studies of two new organic superconductors: {beta}``-(BEDT-TTF){sub 2}SF{sub 5}CH{sub 2}CF{sub 2}SO{sub 3} and {kappa}{sub L}`-(BEDT-TTF){sub 2}Cu(CF{sub 3}){sub 4}(DBCE)  

SciTech Connect

The normal-state ESR of two new organic superconductors, {beta}{double_prime}-(BEDT-TTF){sub 2}SF{sub 5}CH{sub 2}CF{sub 2}SO{sub 3} and {kappa}{sub L}{prime}-(BEDT-TTF){sub 2}Cu(CF{sub 3}){sub 4}(DBCE) are reported. Both compounds showed metallic properties below 140 K. The former gave ESR line widths and g-values of 23-34 G and 2.004-2.012. The latter gave line widths and g-values of 45-58 G and 2.006-2.012. Orientation-dependent line widths and g-values of the {kappa}{sub L}{prime}-phase were found to be similar to that of the {kappa}-(ET){sub 4}Hg{sub 3}Br{sub 8} but not to the {kappa}{sub L}-phases in general.

Wang, H.H.; VanZile, M.L.; Geiser, U. [and others

1996-10-01T23:59:59.000Z

443

Transfer between the cesium 6 {sup 2}P{sub 1/2} and 6 {sup 2}P{sub 3/2} levels induced by collisions with H{sub 2}, HD, D{sub 2}, CH{sub 4}, C{sub 2}H{sub 6}, CF{sub 4}, and C{sub 2}F{sub 6}  

SciTech Connect

The cross sections of spin-orbit energy exchange between the cesium 6 {sup 2}P{sub 1/2}{r_reversible}6 {sup 2}P{sub 3/2} states induced by collisions with N{sub 2}, H{sub 2}, HD, D{sub 2}, CH{sub 4}, C{sub 2}H{sub 6}, CF{sub 4}, and C{sub 2}F{sub 6} were obtained for pressures less than 100 Torr at room temperature by means of steady-state laser-induced fluorescence techniques. The spin-orbit energy exchange rate with N{sub 2}, H{sub 2}, HD, D{sub 2}, CH{sub 4}, C{sub 2}H{sub 6}, CF{sub 4}, and C{sub 2}F{sub 6}, have been measured as {sigma}{sub 21}(6 {sup 2}P{sub 3/2}{yields}6 {sup 2}P{sub 1/2})= 16.3, 34.1, 30.0, 22.7, 21.4, 65.6, 64.8, and 137 A{sup 2} and {sigma}{sub 12}(6 {sup 2}P{sub 1/2}{yields}6 {sup 2}P{sub 3/2})= 1.8, 4.4, 4.1, 3.0, 2.9, 13.3, 9.7, and 16.3 A{sup 2}, respectively. Correlations of the spin-orbit transfer probabilities with rotational-energy defect and vibrational-energy defect have been shown.

Pitz, Greg A.; Fox, Charles D.; Perram, Glen P. [Directed Energy Directorate, Air Force Research Labs, 3550 Aberdeen Ave. SE, Kirtland AFB, New Mexico 87117 (United States); Department of Engineering Physics, Air Force Institute of Technology, 2950 Hobson Way, WPAFB, Ohio 45433-7765 (United States)

2011-09-15T23:59:59.000Z

444

Comparative thermal-expansion study of {beta}"-(ET){sub 2}SF{sub 5}CH{sub 2}CF{sub 2}SO{sub 3} and {kappa}-(ET){sub 2}Cu(NCS){sub 2} : uniaxial pressure coeffcients of T{sub c} and upper critical fields.  

Science Conference Proceedings (OSTI)

We report high-resolution measurements of the coefficient of thermal expansion, {alpha}=l{sup -1}x({partial_derivative}l/{partial_derivative}T), on single crystals of the organic superconductors {beta}'-(ET){sub 2}SF{sub 5}CH{sub 2}CF{sub 2}SO{sub 3} and {kappa}-(ET){sub 2}Cu(NCS){sub 2}. For both salts we find large and highly anisotropic phase-transition anomalies at T{sub c}. Combining these data with literature results on the specific heat via the Ehrenfest relation, the uniaxial pressure coefficients of T{sub c} can be determined. Most remarkably, a strikingly similar in-plane vs out-of-plane anisotropy is found for both compounds: the strong suppression of T{sub c} observed in hydrostatic-pressure experiments is dominated by a huge negative uniaxial stress effect perpendicular to the conducting planes. Therefore we expect that an increase of T{sub c} in this class of superconductors can be obtained by enlarging the distance between the conducting layers. Application of magnetic fields perpendicular to the planes for the {beta}''-(ET){sub 2}SF{sub 5}CH{sub 2}CF{sub 2}SO{sub 3} salt were found to result in pronounced superconducting fluctuation effects and scaling behavior in {alpha}(T,B). Owing to the pronounced phase-transition anomalies in {alpha}(T,B) at T{sub c}, our measurements allow for an accurate determination of the upper critical fields. We find B{sub c{sub 2}}{sup {perpendicular}}(0)=(1.4{+-}0.2)T and B{sub c{sub 2}}{sup {parallel}}(0)=(10.4{+-}0.5)T for fields perpendicular and parallel to the conducting planes, respectively.

Muller, J.; Lang, M.; Steglich, F.; Schlueter, J. A.; Kini, A. M.; Geiser, U.; Nixon, P. G.; Winter, R. W.; Gard, G. L.; Sasaki, T.; Toyota, N.; Max-Planck Inst. for Chemical Physics of Solids; Portland State Univ.; Tohoku Univ.

2000-05-01T23:59:59.000Z

445

Lithium Diisopropylamide-Mediated Enolization: Catalysis by Hemilabile Ligands  

E-Print Network (OSTI)

Lithium Diisopropylamide-Mediated Enolization: Catalysis by Hemilabile Ligands Antonio Ramirez of a lithium diisopropylamide (LDA)-mediated ester enolization. Hemilabile amino ether MeOCH2CH2NMe2, binding-based catalysis are thwarted by the occlusion of the catalyst on the lithium salt products and byproducts (eq 1

Collum, David B.

446

Optical spectra and electronic band structure calculations of {beta}'-(ET){sub 2}SF{sub 5}RSO{sub 3} (R=CH{sub 2}CF{sub 2}, CHFCF{sub 2} and CHF) : changing electronic properties by chemical tuning of the counterion.  

SciTech Connect

We report the polarized infrared reflectance spectra, optical conductivity, and electronic band structure of metallic {beta}{prime}-(ET){sub 2}SF{sub 5}CHFSO{sub 3} and compare our results with those of the {beta}{prime}-(ET){sub 2}SF{sub 5}CH{sub 2}CF{sub 2}SO{sub 3} superconductor and the {beta}{prime}-(ET){sub 2}SF{sub 5}CHFCF{sub 2}SO{sub 3} metal/insulator material. We discuss the electronic structure of these organic molecular solids in terms of band structure, many-body effects, and disorder. On the basis of spectral similarities between the superconductor and metallic salts and structural differences in the anion pocket of all three, we conclude that the unusual electronic excitations observed in the {beta}{prime}-(ET){sub 2}SF{sub 5}CHFCF{sub 2}SO{sub 3} metal/insulator material are not caused by electron correlation but are due to disorder-related localization.

Jones, B. R.; Olejniczak, I.; Dong, J.; Pigos, J. M.; Zhu, Z.; Garlach, A. D.; Musfeldt, J. L.; Koo, H.-J.; Whangbo, M.-H.; Schlueter, J. A.; Ward, B. H.; Morales, E.; Kini, A. M.; Winter, R. W.; Mohtasham, J.; Gard, G. L.; State Univ. of New York at Binghamton; North Carolina State Univ.; Portland State Univ.

2000-08-01T23:59:59.000Z

447

Publications  

NLE Websites -- All DOE Office Websites (Extended Search)

7 results: 7 results: BibTex RIS RTF XML Sort by: Author Title Type [ Year (Desc) ] Filters: Author is Elton J. Cairns [Clear All Filters] 2008 Shin, Joon Ho, Pratyay Basak, John B. Kerr, and Elton J. Cairns. "Rechargeable Li/LiFePO4 Cells Using N-Methyl-N-butyl pyrrolidinium Bis(trifluoromethane sulfonyl)imide-LiTFSI Electrolyte Incorporating Polymer Additives." Electrochimica Acta 54, no. 2 (2008): 410-414. Shin, Joon Ho, and Elton J. Cairns. "N-Methyl-(n-butyl)pyrrolidinium bis(trifluoromethanesulfonyl)imide-LiTFSI-poly(ethylene glycol) dimethyl ether mixture as a Li/S cell electrolyte." Journal of Power Sources 177 (2008): 537-545. 2007 Nakahara, Kentaro, Jiro Iriyama, Shigeyuki Iwasa, Masahiro Suguro, Masaharu Satoh, and Elton J. Cairns. "Al-laminated film packaged organic radical